Radiation decomposition of humic substances in landfill disposal leachate

International Nuclear Information System (INIS)

Sawai, Takeshi; Sawai, Teruko; Shimokawa, Toshinari

1979-01-01

The leachate generated from landfill contains humic substances such as humic acid and fluvic acid. It shows, in general, high chemical oxygen demand (COD) and biological oxygen demand (BOD), and colors in dark brown. When the leachate collected on the No. 15 landfill in Tokyo Bay was irradiated by γ-rays from a 60 Co source in bubbling air, the total organic carbon (TOC) decreased with increasing dose and the brown color was bleached. The effects of pH, flow rate, and dose rate on the decrease of TOC, the variations of UV spectrum, and the formation of carbon dioxide by the irradiation were examined. The decreasing rate of TOC increased with an increase of the flow rate up to -- 11/min and showed a maximum value in the region of pH 4 - 6. It was also dependent on the dose rate and increased with a decrease of the dose rate. The radiation chemical yield, G(-TOC), reached 162 at low dose rate of 1.3 x 10 4 rad/h. This result suggests that a radiation-induced chain reaction occurred. The amount of TOC decreased was almost equal to that of carbon dioxide formed. This result shows that the organic substances were decomposed by irradiation to carbon dioxide as a final product and it was ejected from the solution. (author)

Growth, biomass production and ions accumulation in Atriplex nummularia Lindl grown under abiotic stress

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Hidelblandi F. de Melo

2016-02-01

Full Text Available ABSTRACT Atriplex nummularia is a halophyte of great importance in the recovery of saline soils and is considered as a model plant to study biosaline scenarios. This study aimed to evaluate biometric parameters, biomass production and the accumulation of ions in A. nummularia grown under abiotic stresses. Cultivation was carried out in a Fluvic Neosol for 100 days, adopting two water regimes: 37 and 70% of field capacity. Plants were irrigated with saline solutions containing two types of salts (NaCl and a mixture of NaCl, KCl, MgCl2 and CaCl2 at six levels of electrical conductivity: 0, 5, 10, 20, 30 and 40 dS m-1, arranged in a 6 x 2 x 2 factorial with 4 replicates, forming 96 plots. At the end of the experiment, plants were divided into leaves, stem and roots, for the determination of fresh matter (FM, dry matter (DM and estimated leaf area (LA, besides the contents of Ca2+, Mg2+, Na+, K+ and Cl-. The type of salt did not influence plant growth or biomass production; however, it influenced the levels of Ca2+, Mg2+, Na+ and Cl- in the leaves and Mg2+, K+ and Cl- in the roots. Increase in salinity reduced the contents of Ca2+, Mg2+, Na+, K+ and Cl- for all treatments.

Teor de zinco, cádmio e chumbo em plantas de arroz em solos incubados com resíduo siderúrgico Contents of zinc, cadmium and lead in rice plants in soils incubated with slag

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André F. M. de Andrade

2010-10-01

Full Text Available Os efeitos da aplicação de resíduo siderúrgico, proveniente da concentração de Zn em lama de altos fornos siderúrgicos, como fonte de Zn às plantas de arroz e a toxicidade de Cd e Pb no resíduo, foram avaliados em experimento. O material de solo usado proveio do horizonte superficial dos solos Latossolo Vermelho Amarelo (LVA; Neossolo Flúvico (RU e Argissolo Vermelho Amarelo (PVA, coletados no município de Pinheiral, Estado do Rio de Janeiro; utilizou se a variedade de arroz (Oryza sativa L. BRS Curinga. As plantas foram coletadas aos 145 dias após a semeadura; aquelas crescidas no Neossolo Flúvico apresentaram a maior produção de matéria seca e a maior acumulação de zinco, mas a menor de cádmio, enquanto as desenvolvidas no Argissolo Vermelho Amarelo indicaram a menor produção de matéria seca, menor acumulação de zinco, mas maior de chumbo e de cádmio. O extrator DTPA foi alvo de correlações elevadas e significativas com as concentrações de chumbo, cádmio e zinco, nas raízes e na parte aérea e, com a quantidade acumulada nas plantas, mostrando se bom indicador da biodisponibilidade desses três metais. Pelas características apresentadas nos solos estudados e pelas concentrações fitotóxicas do chumbo e do cádmio encontradas nas plantas desenvolvidas no PVA, não é recomendável a utilização desse resíduo como fonte de zinco para a cultura do arroz.The effects of the application of slag, from the concentration of Zn in the mud of steel slag, as a source of Zn for rice plants and the toxicity of Cd and Pb in the residue were studied in a greenhouse during the period from April 2005 to March 2006. The material used came from the surface horizon of a Red Yellow Oxisol (LVA; Fluvic Entisol (RU and Red Yellow ultisol (PVA, collected in the municipality of Pinheiral, in the State of Rio de Janeiro. The variety of rice (Oryza sativa L. BRS Joker was used. Plants were harvested at 145 days after sowing; those

Obtention of charcoal briquettes from rice husks using low compaction pressure; Obtencao de briquetes de carvao vegetal de cascas de arroz utilizando baixa pressao de compactacao

Energy Technology Data Exchange (ETDEWEB)

Morais, Marcia R.; Seye, Omar; Freitas, Katrina T. de; Rodrigues, Monica; Santos, Eyde C.S. dos; Souza, Rubem C.R. [Universidade Federal do Amazonas (CDEAM/UFAM), Manaus, AM (Brazil). Centro de Desenvolvimento Energetico Amazonico

2006-07-01

This work consists of the preparation of briquette from carbonized rice's husks in low pressure. The results demonstrate are necessary a fine granulation of the rice's husks coal to obtainment of briquettes. The ultimate analysis of the briquette did not detect the presence of nitrogen and sulfur, and that prevents the formation and emission of acid gases that can produce corrosion in the equipment and pollute the atmosphere. The performance of the briquette production was superior to 80%. The briquettes present high heating value (HHV) 17,73 MJ/kg and adequate mechanic resistance for the use in gasifier-engine system. (author)

Phytogeographical patterns of dry forests sensu stricto in northern Minas Gerais State, Brazil.

Science.gov (United States)

Arruda, Daniel M; Ferreira-Júnior, Walnir G; Duque-Brasil, Reinaldo; Schaefer, Carlos E R

2013-01-01

The Deciduous Complex that occurs in northern Minas Gerais State, Brazil, raises questions about the floristic affinities of these formations in relation to neighboring phytogeographical domains. Little is known about the identity of the seasonal forest formations that comprise this complex, or about its relationships to abiotic components, such as soils, topography and climate. This study aimed to recognize the patterns of floristic similarity of all studied fragments of dry forest of northern Minas Gerais with soil and climate attributes, based on the available database. Cluster analysis indicated the existence of two floristic groups that had clear associations with either the Koppen's BSh (semi-arid) or Aw (seasonal tropical) climates. Likewise, the subdivisions of these groups showed clear associations with the dominant soil classes in the region. The Red-Yellow Latosol is the dominant soil classes in the BSh climatic domain, seconded by alluvial areas associated with Fluvic Neosols. The Aw domain comprised a much varied set of soils: Nitosols, Argisols, Cambisols and Litholic Neosols, most derived from the Bambuí limestone/slate formation. The ecotonal nature of northern Minas Gerais State provides a complex interaction between the flora of neighboring phytogeographical domains. This, allied to pedogeomorphological factors, allowed a better understanding of the effects of late Quaternary climate changes for the Deciduous Complex evolution. We conclude that the Latosols under present-day semi-arid climates (BSh) are relicts of former wetter climates, during which humid forest (semideciduous) expansion took place. Later, these semideciduous forests were subjected to a much drier climate, when selection for deciduousness led to the present-days Deciduous Complex scenario.

Application of portable nuclear gauge to the control of soil, asphalt and concrete compaction; A aplicacao dos medidores nucleares portateis no controle de compactacao de solos, asfalto e concreto

Energy Technology Data Exchange (ETDEWEB)

Castro, Bruno Almeida Cunha de [PATTROL, Pavimentos, Tracados e Obras Ltda. (Brazil)

1999-07-01

This paper presents an overview on the density and humidity determination methodology by using nuclear techniques, describing the different process phases and demonstrating their advantages compared to the traditional methods.

Diferentes fontes de P no desenvolvimento do meloeiro e disponibilidade de fósforo no solo Use of biofertilizantes phosphated of the development of the melon and readiness of phosphorus

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Michelangelo de Oliveira Silva

2011-06-01

Full Text Available Avaliou-se o desenvolvimento da cultura do melão, como também a disponibilidade de fósforo nos solos com o uso de biofertilizante fosfatado após três ciclos da cultura. Os tratamentos foram distribuídos em blocos casualizados com três repetições, arranjados num fatorial 2 x 3 x 7, correspondente a dois tipos de solos (Latossolo Amarelo e Neossolo Flúvico; três fontes de fósforo (superfosfato triplo, biofertilizante fosfatado e a rocha fosfatada; e sete níveis de fósforo (0; 0,5; 1,0; 1,5; 2,0; 2,5; 3,0 do recomendado para a cultura e para cada solo. Os fertilizantes superfosfato triplo, biofertilizante de rocha fosfatada e rocha fosfatada não apresentaram diferenças significativas na produção de matéria seca, porém o biofertilizante foi o que mais disponibilizou P nos dois solos estudados após três ciclos da mesma cultura.This work assessed the development of melon crops,and the availability of phosphorus in the soil with the use of biofertilizer phosphate after three cycles of culture. The treatments were distributed into randomized block design with three repetitions, arranged in a factorial 2 x 3 x 7, corresponding to two types of soils (Yellow Latossol and Fluvic Neosol; three sources of phosphorus (triple superphosphate, bio-fertilizer phosphate and rocks and seven levels of phosphorus (0; 0.5; 1.0; 1.5; 2.0; 2.5; 3.0 of recommended for the culture and for each soil. The triple superphosphate fertilizer, biofertilizer rock phosphate and rock phosphate showed no significant differences in dry matter production, but the biofertilizer was the most available P in both soils after three cycles of the same culture.

Phyto extraction of 99Tc on soil cores with aged contamination

International Nuclear Information System (INIS)

Massoura, S.T.; Echevarria, G.; Morel, J.L.; Massoura, S.T.; Leclerc-Cessac, E.; Denys, D.

2004-01-01

99 Tc is an artificial radionuclide which is found in high-activity and long-lived nuclear waste. This work was designed to study the phyto-extraction of 99 Tc in soils that had received aged contamination and to monitor the resulting 99 Tc concentrations in the soil solution of undisturbed soil cores in a greenhouse. Undisturbed soil cores had been sampled previously from a Rendzic Leptosol (R), a Fluvic cambisol (F) and a Dystric cambisol (D), using 0.5-m diameter PVC tubing (3 samples/soil type) without disturbing soil structure (1). Each core was equipped with two nylon porous cups (respectively 20 and 35 cm deep) and a final leachate collector. A 99 TcNO 3 solution had been supplied at the soil surface of each core during the two previous years (4200 kBq in total) in which maize and wheat had been successively cropped. These two crops had already removed 30-65% of total contamination before the present study. After the second year no more 99 Tc was added to the cores. Thereafter, Lolium perenne was cultivated for 20 successive months. 99 Tc was determined in both plant aerial parts and water samples (from both cups and collectors), and the balance of 99 Tc in the system was established after phyto-extraction. Results showed that transfer of 99 Tc to plants vary among soils: 7% on soil R to 11% on soil D. Concentration of 99 Tc in the porous cups dramatically decreased in all soils. The plants maintained low and stable concentration levels of 99 Tc in the soil solution which decreased the potential migration of the radionuclide through the cores: The leaching of 99 Tc in the final collectors of the R soil cores decreased from 18 to 1.7 Bq mL -1 . (author)

Availability of 99Tc in undisturbed soil cores

International Nuclear Information System (INIS)

Denys, Sebastien; Echevarria, Guillaume; Florentin, Louis; Leclerc-Cessac, Elisabeth; Morel, Jean-Louis

2003-01-01

Models for safety assessment of radioactive waste repositories need accurate values of the soil-to-plant transfer of radionuclides. In oxidizing environments, 99 Tc is expected to occur as pertechnetate ( 99 TcO 4 - ). Due to its high mobility, leaching of this element in the field might be important, potentially affecting the reliability of estimated transfer parameters of 99 Tc as measured in closed experimental systems such as hydroponics or pot experiments. The aim of this experiment was to measure the leaching of 99 Tc in undisturbed irrigated soil cores under cultivation as well as plant uptake and to study the possible competition between the two transfer pathways. Undisturbed soil cores (50x50 cm) were sampled from a Rendzic Leptosol (R), a colluvial Fluvic Cambisol (F) and a Dystric Cambisol (D) using PVC tubes (three cores sampled per soil type). Each core was equipped with a leachate collector at the bottom, allowing the monitoring of 99 Tc leaching through the cores. Cores were placed in a greenhouse and maize (Zea mays L., cv. DEA, Pioneer[reg]) was sown. After 135 d, maize was harvested and radioactivity determined in both plant and water samples. Results showed that during the growing period, leaching of 99 Tc was limited, due to the high evapotranspiration rate of maize. After harvest, leaching of 99 Tc went on because of the absence of evapotranspiration. Effective uptake (EU) of 99 Tc in leaves and grains was calculated. EU reached 70% of the input in the leaves and was not significantly different among soils. These results confirmed those obtained from pot experiments, even though leaching was allowed to occur in close-to-reality hydraulical conditions. As a consequence, it was concluded that pot experiments are an adequate surrogate for more complex 'close-to-reality' experimental systems for measuring transfer factors

Mechanical behaviour of AlSiC nano composites produced by ball milling and spark plasma sintering =

Science.gov (United States)

Buchheim, Claudia Sofia de Andrade Redondo Murilhas

Neste trabalho foram produzidos nanocompositos de AlSiC misturando aluminio puro com nano particulas de SiC com diâmetro de 45 - 55 nm, usando, de forma sequencial, a tecnica da metalurgia do po e a compactacao por "Spark Plasma Sintering". O composito obtido apresentava graos com 100 nm de diâmetro, encontrandose as particulas de SiC localizadas, principalmente, nas fronteiras de grao. O nanocomposito sob a forma de provetes cilindricos foi submetido a testes de compressao uniaxial e a testes de nanoindentacao para analisar a influencia das nanoparticulas de SiC, da fracao volumica de acido estearico e do tempo de moagem, nas propriedades mecânicas do material. Para efeitos de comparacao, utilizouse o comportamento mecânico do Al puro processado em condicoes similares e da liga de aluminio AA1050O. A tensao limite de elasticidade do nanocomposito com 1% Vol./Vol. de SiC e dez vezes superior a do AA1050. O refinamento de grao a escala nano constitui o principal mecanismo de aumento de resistencia mecânica. Na realidade, o Al nanocristalino sem reforco de particulas de SiC, apresenta uma tensao limite de elasticidade sete vezes superior a da liga AA1050O. A adicao de 0,5 % Vol./Vol. e de 1 % Vol./Vol. de SiC conduzem, respetivamente, ao aumento da tensao limite de elasticidade em 47 % e 50%. O aumento do tempo de moagem e a adicao de acido estearico ao po durante a moagem conduzem apenas a um pequeno aumento da tensao de escoamento. A dureza do material medida atraves de testes de nanoindentacao confirmaram os dados anteriores. A estabilidade das microestruturas do aluminio puro e do nanocomposito AlSiC, foi testada atraves de recozimento de restauracao realizado as temperaturas de 150 °C e 250 °C durante 2 horas. Aparentemente, o tratamento termico nao influenciou as propriedades mecânicas dos materiais, excepto do nanocomposito com 1 % Vol./Vol. de SiC restaurado a temperatura de 250 °C, para o qual se observou uma reducao da tensao limite de elasticidade

Aspectos florísticos da vegetação de restinga no litoral de Pernambuco Floristics aspects of restinga vegetation in the coast of Pernambuco - Brazil

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Ana Cláudia Sacramento

2007-12-01

Full Text Available As zonas costeiras acolhem quadros de alta riqueza e relevância ecológica que as qualificam como importante ecossistema para conservação. O objetivo deste estudo foi listar as espécies que compõem a restinga da praia do Paiva e descrever a sua fisionomia. A área de restinga compreende 147 ha, situa-se no Município do Cabo de Santo Agostinho, PE, sob as coordenadas 08º07'30"S e 35º00'55"W. As coletas florísticas foram realizadas durante 28 meses, em todos os estratos. O solo foi classificado como Neossolo Quartzarênico; foram determinadas duas fisionomias: a floresta não-inundável e o fruticeto aberto não-inundável. Foram listadas 124 espécies, distribuídas em 103 gêneros e 55 famílias. As famílias com maior número de espécies foram Myrtaceae, com 11 espécies, Cyperaceae (10, Fabaceae (8, Euphorbiaceae (7, Rubiaceae (6 e Asteraceae (5. As espécies Anacardium occidentale, Tapirira guianensis, Chamaecrista ramosa, Protium heptaphyllum, Byrsonima sericea, Myrcia rotundifolia e Marlierea schotti são encontradas na maioria das restingas do Nordeste. No entanto, devido à incipiência dos estudos na Região não foram verificadas espécies endêmicas.The high biodiversity and richness of the coastal zone make it an important ecosystem to be preserved. The aim of this study is to list the species composition of the restinga area (147 ha. of Paiva beach, in Cabo de Santo Agostinho-Pernambuco (08º07'30"S and 35º00'55"W and describe the physiognomies. Floristic survey was carried out for 28 months for all strata. The soil was classified as Quartzarenic Neosoil and two physiognomies were determined: unflooded forest and unflooded open shrubby vegetation. One hundred-twenty-four species were recorded, distributed in 103 genera and 55 families. The families with the highest number of species were: Myrtaceae (11, Cyperaceae (10, Fabaceae (8, Euphorbiaceae (7, Rubiaceae (6 and Asteraceae (5. Anacardium occidentale, Byrsonima sericea

Availability of {sup 99}Tc in undisturbed soil cores

Energy Technology Data Exchange (ETDEWEB)

Denys, Sebastien; Echevarria, Guillaume E-mail: guillaume.echevarria@ensaia.inpl-nancy.fr; Florentin, Louis; Leclerc-Cessac, Elisabeth; Morel, Jean-Louis

2003-07-01

Models for safety assessment of radioactive waste repositories need accurate values of the soil-to-plant transfer of radionuclides. In oxidizing environments, {sup 99}Tc is expected to occur as pertechnetate ({sup 99}TcO{sub 4}{sup -}). Due to its high mobility, leaching of this element in the field might be important, potentially affecting the reliability of estimated transfer parameters of {sup 99}Tc as measured in closed experimental systems such as hydroponics or pot experiments. The aim of this experiment was to measure the leaching of {sup 99}Tc in undisturbed irrigated soil cores under cultivation as well as plant uptake and to study the possible competition between the two transfer pathways. Undisturbed soil cores (50x50 cm) were sampled from a Rendzic Leptosol (R), a colluvial Fluvic Cambisol (F) and a Dystric Cambisol (D) using PVC tubes (three cores sampled per soil type). Each core was equipped with a leachate collector at the bottom, allowing the monitoring of {sup 99}Tc leaching through the cores. Cores were placed in a greenhouse and maize (Zea mays L., cv. DEA, Pioneer[reg]) was sown. After 135 d, maize was harvested and radioactivity determined in both plant and water samples. Results showed that during the growing period, leaching of {sup 99}Tc was limited, due to the high evapotranspiration rate of maize. After harvest, leaching of {sup 99}Tc went on because of the absence of evapotranspiration. Effective uptake (EU) of {sup 99}Tc in leaves and grains was calculated. EU reached 70% of the input in the leaves and was not significantly different among soils. These results confirmed those obtained from pot experiments, even though leaching was allowed to occur in close-to-reality hydraulical conditions. As a consequence, it was concluded that pot experiments are an adequate surrogate for more complex 'close-to-reality' experimental systems for measuring transfer factors.

MERCURY CONCENTRATION IN MARGIN SOIL OF THE MADEIRA RIVER

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Déborah Pereira Linhares

2005-05-01

Full Text Available The extraction of gold in the Amazon, since 1970, has grown fast from a politic that was resulted in the creation of gold extraction reserves in this region. In the Madeira River the gold exploration is noticeable because of the deposition of mercury in the environment. This metal is toxic and it resists to degradation process, transforming itself chemically, till it gets to its organic form, known as very toxic. Its extensive usage in the gold recover has caused impacts to the environment and consequently to the population, according to studies already done. This study has as its goal to value the pollution by Hg in soils and the variation according to soil fractions. The soils were collected by profiles in 10 areas in the Madeira River. The determination of organic matter was done, according (BRASIL, 1999.To Hg determination it was selected the fraction <200 mesh (<74ım, analyzed by atomic absorption spectrophotometer coupled vapor cold generation (Bastos et. al, 1998. Soils of the kind Latosols and hydromorphic were identified. The Latosols presented from 288 to 641g.Kg-1 of clay and from 266 to 111 g.Kg-1 of thin send, from the horizon A1 (superficial to B2 (sub-superficial. The increase of values of clay makes the function of organic matter in the superficial horizon better (from 20,2 to 19.0 %. The Hg concentration in these horizons varies from 25,5 to 641,4 ıg.Kg-1in the superficial horizon. The hydromorphic, especially, the Fluvic Neosols, present thin area, 396 to 57 g.Kg-1 and clay from 254 to 654 g.Kg-1 from A1 to A2. The horizon A2 presents 467 g.Kg-1 of silt, 13,6 % of OM and 147,31 ıgHg.Kg-1.Among the soils groups of the studied area, it is noticed more Hg concentration with the increase of values of silt and clay, that consequently presents more tenor of OM, and that subsidizes the organic mercury forming.

Spectral characterization of the fluorescent components present in humic substances, fulvic acid and humic acid mixed with pure benzo(a)pyrene solution

Science.gov (United States)

El Fallah, Rawa; Rouillon, Régis; Vouvé, Florence

2018-06-01

The fate of benzo(a)pyrene (BaP), a ubiquitous contaminant reported to be persistent in the environment, is largely controlled by its interactions with the soil organic matter. In the present study, the spectral characteristics of fluorophores present in the physical fractions of the soil organic matter were investigated in the presence of pure BaP solution. After extraction of humic substances (HSs), and their fractionation into fluvic acid (FA) and humic acid (HA), two fluorescent compounds (C1 and C2) were identified and characterized in each physical soil fraction, by means of fluorescence excitation-emission matrices (FEEMs) and Parallel Factor Analysis (PARAFAC). Then, to each type of fraction having similar DOC content, was added an increasing volume of pure BaP solution in attempt to assess the behavior of BaP with the fluorophores present in each one. The application of FEEMs-PARAFAC method validated a three-component model that consisted of the two resulted fluorophores from HSs, FA and HA (C1 and C2) and a BaP-like fluorophore (C3). Spectral modifications were noted for components C2HSs (C2 in humic substances fraction) (λex/λem: 420/490-520 nm), C2FA (C2 in fulvic acid fraction) (λex/λem: 400/487(517) nm) and C1HA (C1 in humic acid fraction) (λex/λem: 350/452(520) nm). We explored the impact of increasing the volume of the added pure BaP solution on the scores of the fluorophores present in the soil fractions. It was found that the scores of C2HSs, C2FA, and C1HA increased when the volume of the added pure BaP solution increased. Superposition of the excitation spectra of these fluorophores with the emission spectrum of BaP showed significant overlaps that might explain the observed interactions between BaP and the fluorescent compounds present in SOM physical fractions.

Mobilidade do ametryn em solos da região semiárida do Rio Grande do Norte Ametryn mobility in soils of Rio Grande do Norte semiarid region

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F.C.L. Freitas

2012-09-01

profundidade. O método do bioensaio com pepino como planta indicadora pode ser utilizado em estudos de lixiviação desse herbicida, em substituição ao método cromatográfico.This work aimed to evaluate ametryn mobility in four types of soils, three from the semiarid region of the state of Rio Grande do Norte (Cambisol ; Fluvic Neosol; Latosolic Dystrophic Red-Yellow Argisol and one from the state of Minas Gerais (Red-Yellow Latosol. Ametryn mobility was evaluated using PVC columns of 10 cm in diameter and 50 cm long. The experiment was conducted in a split-plot in a completely randomized design with four replications. The plots were composed by the columns, filled with the four types of soils and the subplots by 10 depths at intervals of 5 cm (0-5, 5-10, 10-15, 15-20, 20-25, 25-30 , 30-35, 35-40, 40-45 and 45-50 cm. Ametryn was applied on top of the columns (4 kg ha-1 and, 12 hours later, rainfall was simulated at the intensity of 60 mm. After 72 hours of simulated rain, the columns were placed in a horizontal position and opened longitudinally, divided into sections of 5.0 cm. At the center of each section, soil samples were collected for subsequent herbicide extraction and quantification through analysis by liquid chromatography (HPLC. Five seeds of cucumber (Cucumis sativus were sown as bio-indicators of the presence of the herbicide. Ametryn mobility at the columns was influenced by the physical and chemical characteristics of the soil,(soil texture, organic matter, and pH. The Rio Grande do Norte semiarid region soils had higher ametryn mobility potential, being detected at up to 25, 20, and 15 cm depth in Latosolic Dystrophic Red- Yellow Argisol, Cambisol, and Fluvic Neosol, respectively. Ametryn mobility was restricted to 5 cm depth in the Red Yellow Latosol, with higher organic matter content and pH 4.7. The bioassay method was more efficient to confirm ametryn leaching than liquid chromatography.

Genesis and classification of the soils developed from the sediments of the former Oleszek mill pond basin (the Chełmińskie Lakeland, N Poland / Geneza i pozycja systematyczna gleb wykształconych z osadów niecki dawnego stawu młyńskiego Oleszek (Pojezierze Chełmińskie

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Mendyk Łukasz

2015-03-01

Full Text Available Budowa i funkcjonowanie młynów wodnych znacznie wpłynęły na przekształcenie środowiska przyrodniczego w ich otoczeniu, przede wszystkim na zmiany rzeźby terenu i warunków wodnych. Obszar badañ obejmuje nieckę dawnego stawu młyńskiego Oleszek w okolicach wsi Borówno, w zachodniej części Pojezierza Chełmińskiego, około 20 km na północny wschód od Torunia. Celem badañ było określenie genezy gleb wykształconych z osadów zakumulowanych w niecce dawnego stawu młyńskiego Oleszek. Pięć profili glebowych w transekcie o długości około 550 m zlokalizowanym wzdłuż Strugi Rychnowskiej stanowiącej oś podłużną niecki. Wszystkie przeanalizowane gleby zbudowane są z osadów wypełniających nieckę dawnego stawu młyńskiego. Gleby w opisywanej niecce powstały w wyniku wielu nakładających się procesów, takich jak: proces mułotwórczy, aluwialny, koluwialny oraz glejowy. Dwa z analizowanych profili glebowych (profile 3 i 4 spełniaj¹ kryteria wydzielania gleb organicznych limnowych typowych (Systematyka gleb Polski 2011. Jako pozycję systematyczną kolejnych dwóch gleb (profile 2 i 5 zaproponowano gleby mułowate. W związku z problemami klasyfikacyjnymi dotyczącymi tego typu gleb, przy opracowaniu aktualizacji Systematyki gleb Polski należałoby wprowadzić w typie gleb glejowych podtyp gleb mułowatych lub mułowato-glejowych, obejmuj¹cy gleby wytworzone z mineralno-organicznych utworów aluwialno-mułowych. Cztery wymienione powyżej profile zostały zaklasyfikowane jako Histosols (3 i 4 i Gleysols (2 i 5 według klasyfikacji WRB (2014. Jednostki glebowe wykształcone z osadów aluwialnych (mady wg SgP 2011 lub Fluvic Phaeozems wg WRB 2014 występują w proksymalnej części stawu (cofce.

Fatores de retardamento e coeficientes de dispersão-difusão de fosfato, potássio e amônio em solos de Minas Gerais Retardation factors and dispersion-diffusion coefficients of phosphate, potassium and ammonium in soils of Minas Gerais - Brazil

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Ermelinda M. M. Oliveira

2004-12-01

Full Text Available Através deste estudo objetivou-se comparar os fatores de retardamento (R e os coeficientes de dispersão-difusão (D do fosfato, potássio e amônio, determinados em cinco solos de Minas Gerais (um Neossolo Quartzarênico órtico - RQo; três Latossolos Vermelhos distróficos - LVd1, LVd2 e LVd3; e um Latossolo Vermelho-Amarelo distrófico - LVAd. O experimento foi realizado utilizando-se colunas de percolação, que receberam aplicações de uma das soluções resultantes das oito possíveis combinações de duas concentrações de fosfato, potássio e amônio (15 e 60 mg L-1 de P, 75 e 300 mg L-1 de K e 15 e 60 mg L-1 de N. Valores menores de R para o potássio e o amônio, foram observados, quando comparados com os do fosfato. O R para fosfato foi menor no solo mais arenoso (RQo e maior no mais oxídico (LVd2, enquanto nos Latossolos os maiores valores do R para potássio e amônio estiveram relacionados com o incremento do teor de argila, sem tendência definida quanto á concentração do íon em estudo ou do íon acompanhante. Não se evidenciou relação nítida entre as concentrações de fosfato, potássio e amônio e os D desses íons nos solos estudados.The objective of this study was to compare the retardation factors (R, and dispersion-diffusion coefficients (D of phosphate, potassium and ammonium, determined in five Brazilian soils from Minas Gerais State (Orthic Quartzarenic Neosoil, RQo; three distrophic Red Latosols, LVd1, LVd2 and LVd3; and a distrophic Yellow-Red Latosol, LVAd. The experiment used percolation columns, applying one of the eight possible solutions resulting from the mixture of two phosphate, potassium and ammonium concentrations (15 and 60 mg L-1 P, 75 and 300 mg L-1 K, and 15 and 60 mgL-1 N. Lower values of R were observed for potassium and ammonium compared to phosphate. The value of R for phosphate was the lowest in the most sandy soil (RQo and highest in the most oxidic soil (LVd2. The highest Latosol

Fitorremediação de solos contaminados com arsênio (As utilizando braquiária Phytoremediation of arsenic-contaminated soils using Brachiaria grass

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Alessandra Silveira Antunes Araújo

2011-02-01

Full Text Available Conduziu-se este trabalho, com o objetivo de avaliar o potencial fitoextrator de arsênio (As da Brachiaria decumbens Stapf., cultivada em casa de vegetação, utilizando-se seis solos: Latossolo Amarelo Distrófico (LAd, Latossolo Vermelho Distrófico (LVd, Neossolo Flúvico (RU, Neossolo Quartzarênico (RQ, Gleissolo Háplico (GX e Gleissolo Melânico (GM. O As foi adicionado aos solos na forma de arsenato de sódio heptahidratado nas doses 0, 25, 50, 200 e 800 mg kg-1. As plantas foram coletadas 55 dias após a semeadura, separadas em parte aérea e raiz e, após secagem do material em estufa, o mesmo foi digerido segundo o método 3051 da USEPA, sendo o teor de As determinado por espectrofotometria de absorção atômica (EEA com forno de grafite. Observou-se redução no desenvolvimento da braquiária de forma diferenciada nas seis classes de solo. Houve baixa translocação do As, da raiz para a parte aérea, sendo essa espécie considerada tolerante ao elemento e não hiperacumuladora, podendo ser utilizada em programas de revegetação de áreas contaminadas pelo elemento.This work evaluated the phytoextraction potential of arsenic (As by Brachiaria decumbens growing under greenhouse conditions in six soils: a Dystrophic Yellow Latosol (LAd, a Dystrophic Red Latosol (LVd, a Fluvic Neosol (RU, a Quartzenic Neosol (RQ, a Haplic Gleysol (GX, and a Melanic Gleysol (GM. Arsenic was added to the soils as sodium arsenate heptahydrate (Na2HAsO4.7H2O at the following doses: 0, 25, 50, 200, and 800 mg kg-1. The plants were collected 55 days after planting for determination of shoot and root dry matter production. Arsenic shoot and root contents were evaluated after digestion according to the USEPA 3051A method, following analysis by graphite furnace atomic absorption spectroscopy. Plant development was differently affected by As in the six different soil classes. There was low translocation of As and consequently most of the As was detected in the

Yield Response of Spring Maize to Inter-Row Subsoiling and Soil Water Deficit in Northern China.

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Liu, Zhandong; Qin, Anzhen; Zhao, Ben; Ata-Ul-Karim, Syed Tahir; Xiao, Junfu; Sun, Jingsheng; Ning, Dongfeng; Liu, Zugui; Nan, Jiqin; Duan, Aiwang

2016-01-01

Long-term tillage has been shown to induce water stress episode during crop growth period due to low water retention capacity. It is unclear whether integrated water conservation tillage systems, such asspringdeepinter-row subsoiling with annual or biennial repetitions, can be developed to alleviate this issue while improve crop productivity. Experimentswere carried out in a spring maize cropping system on Calcaric-fluvicCambisolsatJiaozuoexperimentstation, northern China, in 2009 to 2014. Effects of threesubsoiling depths (i.e., 30 cm, 40 cm, and 50 cm) in combination with annual and biennial repetitionswasdetermined in two single-years (i.e., 2012 and 2014)againstthe conventional tillage. The objectives were to investigateyield response to subsoiling depths and soil water deficit(SWD), and to identify the most effective subsoiling treatment using a systematic assessment. Annualsubsoiling to 50 cm (AS-50) increased soil water storage (SWS, mm) by an average of8% in 0-20 cm soil depth, 19% in 20-80 cm depth, and 10% in 80-120 cm depth, followed by AS-40 and BS-50, whereas AS-30 and BS-30 showed much less effects in increasing SWS across the 0-120 cm soil profile, compared to the CK. AS-50 significantly reduced soil water deficit (SWD, mm) by an average of123% during sowing to jointing, 318% during jointing to filling, and 221% during filling to maturity, compared to the CK, followed by AS-40 and BS-50. An integrated effect on increasing SWS and reducing SWD helped AS-50 boost grain yield by an average of 31% and biomass yield by 30%, compared to the CK. A power function for subsoiling depth and a negative linear function for SWD were used to fit the measured yields, showing the deepest subsoiling depth (50 cm) with the lowest SWD contributed to the highest yield. Systematic assessment showed that AS-50 received the highest evaluation index (0.69 out of 1.0) among all treatments. Deepinter-row subsoilingwith annual repetition significantly boosts yield by

Sintering of nanopowders of ZrO{sub 2} (Y{sub 2}O{sub 3}): Effect of compaction pressure on densification; Sinterizacao de pos nanoparticulados de ZrO{sub 2} (Y{sub 2}O{sub 3}): efeito da pressao de compactacao na densificacao

Energy Technology Data Exchange (ETDEWEB)

Palmeira, Alexandre Alvarenga; Magnago, Roberto de Oliveira; Pereira, Glayce Cassaro [Centro Universitario de Volta Redonda (UNIFOA), Volta Redonda, RJ (Brazil); Bondioli, Marcelo Jose; Strecker, Kurt [Universidade Federal Sao Joao Del-Rey (UFSJ), MG (Brazil); Santos, Claudinei dos [Universidade do Estado do Rio de Janeiro (UERJ), RJ (Brazil)

2014-06-15

In this work studied the powders (nano) sintered of ZrO{sub 2} (Y{sub 2}O{sub 3}) by dilatometry. Was identified the effect of compaction pressure variation in the final results of densification of materials. Powders were compacted at different compaction pressures. The compacts were subjected to temperatures of 1250°C to 1400°C with sintering levels ranging from 0 to 8 hours. Samples were characterized by X-ray diffraction and relative density using Archimedes method. The results were compared with powders (micro) of similar composition in order to compare the effect of particle size on densification parameters. The samples were further subjected to microstructural characterization in order to identify the average grain size of the sintering under each condition used in both materials. (author)

Effects on the work of a direct ethanol fuel cell as function of compacting force applied to the cell; Efeitos no funcionamento de uma celula a combustivel com alimentacao direta de etanol (CCADE) em funcao da forca de compactacao aplicada a celula

Energy Technology Data Exchange (ETDEWEB)

Belchior, P.M.; Forte, M.M.C. [UFRGS - Universidade Federal do Rio Grande do Sul, Porto Alegre, RS (Brazil); Serafin, R.; Fusiger, V.; Carpenter, D. [FURB - Fundacao Universidade Regional de Blumenau, SC (Brazil)

2010-07-01

This experiment aimed to verify the influence due to the variation of the compacting force applied to a DEFC. According to the tests, as the increase of cell compacting, the performance improves significantly. According applied tests, when the high electrical conductivity components are used, small differences of the cell compacting can generate a large difference on the total ohmic resistance. Through the tests one can conclude that with the increase of cell compacting, the contact probably increase among the distribution of reagents and the diffuser layer, improving the cell performance. (author)

Levantamento do meio físico das Estações Ecológica e Experimental de Itirapina, São Paulo, Brasil. Physical environment of Itirapina Ecological and Experimental Stations, São Paulo State, Brazil.

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Dimas Antonio da SILVA

2005-06-01

, interpretation of aerial photographs andfield works. The study area bears a year average airtemperature and precipitation of 21.9ºC and1,458.9 mm, respectively Two morphologicalgroups are presented: wide hills and alluvial fans.Wide hills, covered by cerrado and plantation ofPinus spp. and Eucalyptus spp., consist ofsandstones from Botucatu Formation over whichQuartzarenics Neosoils are primarily developed.Most sharp coastal cliffs are fragile to erosionprocesses. Alluvial fans are characterized by plainland formed by recent sediments, originatingGleisoils and Organosoils. Its original vegetationis the wetland. Drainage ways are subject to flood,and rivers aggradations. Drainage ways are formedby two rivers (Itaqueri and Lobo, which target theLobo dam. It was concluded that hills and alluvialfans’ sections bearing higher degree of vegetationconservation, and particularly susceptible to linearerosion and alluvial dynamics, should integrate thezones of more restricted use. However, moremodified areas may compose recovering zones orzones of higher use intensity, considering soilconservation measures.

Condicionadores químicos e orgânicos na recuperação de solo salino-sódico em casa de vegetação Chemical and organic amendments in reclamation of saline-sodic soil in greenhouse

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Marcelo A. Miranda

2011-05-01

Full Text Available A salinização vem promovendo a degradação de solos no Semiárido do Brasil, os quais precisam ser recuperados para que possam ter utilização agrícola. Este trabalho teve como objetivo avaliar o efeito de condicionadores orgânicos e químicos em atributos físico-hídricos de um Neossolo Flúvico salino-sódico, no Sertão de Pernambuco. O experimento foi instalado em colunas de solo, sendo aplicados 10 tratamentos: esterco ovino, esterco bovino, gesso, seis doses de polímero sintético e a testemunha, em delineamento em blocos casualizados. As colunas foram submetidas a lixiviação durante 70 dias e analisadas as soluções percoladas aos sete e 70 dias e os solos após a lixiviação. Nos lixiviados foram medidos o pH e a CE e determinados os teores de Na+, K+ e Cl-; no solo foram medidos o pH e a CE e determinado o teor de Na+ do extrato de saturação, o teor de Na+ trocável e a CTC, para cálculo da PST, além das variáveis físico-hídricas do solo. Os resultados foram submetidos a análise de variância e teste de Scott Knott a 0,05 de probabilidade. Os tratamentos, especialmente os estercos, o gesso e o polímero na menor concentração, diminuíram a CE, a PST e o Na+ solúvel, aumentando a condutividade hidráulica do solo.The salinization is degrading Brazilian semi-arid soils, which need to be reclaimed for agricultural utilization. This work aimed to evaluate use of organic and chemical amendments in a Fluvic Entisol having saline-sodic properties in Pernambuco's semi-arid region. Soil experiment was conducted in soil columns, with 10 treatments: sheep manure, cow manure, gypsum, synthetic polymer in six concentrations and the control, in randomized block design. The columns were submitted to leaching during 70 days, being analyzed the leachates collected at 7 and 70 days and the soil after leaching. In leachates, the pH, EC and concentration of Na+, K+ and Cl- were determined; in the saturation extract, pH and EC were

Características hidráulicas e perdas de solo e água sob cultivo do feijoeiro no semi-árido Hydraulic characteristics and soil and water losses under bean cultivation in the semiarid

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Thais E. M. dos Santos

2009-06-01

Full Text Available A região semi-árida apresenta chuvas escassas, irregulares e de secas freqüentes, sendo usual a ocorrência de eventos de alta intensidade. Os solos são pedregosos e rasos, dificultam a prática regular da agropecuária, comprometem freqüentemente a produtividade e tornam esses ambientes vulneráveis à erosão. Objetivou-se avaliar o desempenho de práticas conservacionistas sob a cultura do feijoeiro, no controle de perdas de solo e água por erosão hídrica, em Neossolo Flúvico do semi-árido, com cultivo de sequeiro. Chuvas simuladas com intensidades de 60 mm h-1 foram aplicadas sobre os seguintes tratamentos: cultivo em nível (N1 com barramentos de pedra entre cada fileira de plantio, no espaçamento de 0,5 m; cultivo em nível (N2 com barramentos de pedra no espaçamento de 1,0 m; cultivo morro abaixo (MA; cultivo em nível com cobertura morta (CM, de palha de feijão; parcelas desmatadas (D e com cobertura natural (CN. Dentre os tratamentos avaliados, verificou-se que a adoção de cobertura morta permitiu, em média, redução nas perdas de solo de 86,91% em relação à parcela sem cobertura, com valores próximos ao da condição ideal de cobertura, que é a condição natural, durante todo o ciclo da cultura.The semiarid zone presents scarce and irregular rainfall with frequent droughts, with the occurrence of high intensity events being usual. The soils are shallow and stony, which limits regular agriculture practice, usually reducing productivity and turning this environment susceptible to erosion. The objective of this study was to evaluate the influence of conservation practices, under bean crop, upon soil and water losses by the hydric erosion, in a Fluvic Neossol in the semiarid zone, with rainfed crop. Simulated rainfall has been applied with 60 mm h-1 intensity under the following treatments: cultivation in contour lines (N1 with rock barriers between each row of plantation, spacing 0.5 m; cultivation in contour lines

Uncertainties and Solutions Related to Use of WRB (2007) in the Boreo-nemoral zone, Case of Latvia

Science.gov (United States)

Kasparinskis, Raimonds; Nikodemus, Olgerts; Rolavs, Nauris

2014-05-01

Relatively high diversity of soils groups according to the WRB (2007) classification is observed in forest ecosystems in the boreo-nemoral zone in Latvia. This is due to the geological genesis of area and environmental conditions (Kasparinskis, Nikodemus, 2012), as well as historical land use and management (Nikodemus et al., 2013). Due to the relatively young soils, Albic, Spodic and Cambic horizons are relatively weakly expressed in many cases. Relatively well developed Albic horizons occur in sandy forest soils, but unusually well expressed Spodic features are observed. In some cases there is a Cambic horizon, however location of Cambisols in the WRB (2007) soil classification sequence does not provide an opportunity to classify these soils as Cambisols, but they are classified as Arenosols. This sequence does not reflect the logical sheme of soil development, and therefore raises the question about location of Podzols, Arenosols and Cambisols in the sequence of WRB (2007) soil classification. Soils with two parent materials (abrupt textural change) are relatively common in Latvia, where conceptually on the small scale mapping results in classification as the soil group Planosols, but in many cases there is occurrence of Fluvic materials, as parent material in the upper part of the soil profile is formed by Baltic Ice lake sandy sediments - this leads to question about the location of Fluvisols and Planosols in the sequence of the WRB (2007) soil classification. Soil research has found cases, where a relatively well developed Spodic horizon was established as the result of ground water table depth in areas of abrupt textural change. In this case the profile corresponds to the soil group of Podzols, however in some cases - Gleysols not Planosols due to a high ground water table. Therefore there is a need for discussion also about the location of Podzols and Planosols in the sequence of the WRB (2007) soil classification. The above mentioned questions raise

Resistência hidráulica da crosta formada em solos submetidos a chuvas simuladas Crust hydraulic resistance in soils under simulated rain

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Viviane dos Santos Brandão

2006-02-01

Full Text Available Para avaliar a redução da taxa de infiltração em solos sujeitos ao encrostamento decorrente da aplicação de chuvas simuladas, foi realizado um experimento em esquema fatorial 5 x 6, sendo cinco solos (Argissolo Vermelho, Argissolo Vermelho-Amarelo, Latossolo Vermelho-Amarelo, Neossolo Flúvico e Neossolo Quartzarênico e seis energias cinéticas de chuva (0, 525, 1051, 2102, 3153 e 4204 J m-2, com três repetições. A partir dos dados de taxa de infiltração da água no solo e da espessura da crosta, determinadas por micromorfometria, calcularam-se a condutividade e a resistência hidráulica da crosta. Todos os solos apresentaram redução da taxa de infiltração, quando a energia cinética de chuva simulada aplicada aumentou. A resistência hidráulica da crosta aumentou com a energia cinética (especialmente para os solos Argissolos Vermelho-Amarelos e Vermelho até atingir um valor máximo, a partir do qual ocorreu diminuição, atribuída ao desgaste erosivo da crosta provocado pelo aumento do escoamento superficial, associado aos maiores valores de energia cinética da chuva simulada. Por meio de análise de regressão múltipla, foram determinadas a relação da resistência hidráulica da crosta com a energia cinética da chuva e as características químicas e físicas de cada solo. A variável resistência hidráulica da crosta mostrou-se adequada a ser utilizada nos modelos infiltração da água no solo para descrever a influência do encrostamento neste processo.To evaluate the decrease in infiltration rate in crusting soils an experiment was carried out using a rainfall simulator. Treatments were distributed in a factorial schedule 5 x 6, using five soils (Red Ultisol, Red-Yellow Ultisol, Red-Yellow Oxisol, Fluvic Entisol and Arenic Entisol and six rainfall kinetic energies (0, 525, 1051, 2102, 3153, and 4204 J m-2 with three replications. According to the water infiltration rate and crust thickness, as determined by

Organic residue, limestone, gypsum, and phosphorus adsorption by lowland soils Resíduo orgânico, calcário e gesso e a adsorção de fósforo por solos de várzea

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Alex Teixeira Andrade

2002-06-01

Full Text Available Organic residue application is a low cost alternative to reduce the use of inorganic fertilizers and correctives. In order to study the effect of organic residues, limestone and gypsum application on phosphorus adsorption by lowland soils, four experiments were carried out. A Mesic Organosol (OY, a Melanic Gleysol (MG, a Haplic Gleysol (GX, and a Fluvic Neosol (RU were used in a completely randomized design and factorial scheme (3 x 2, with five replicates: three soil amendment practices (limestone, gypsum and no corrective and two levels of organic residue (with and without corral manure. Soil samples were incubated for 60 days, with and without organic residue incorporation. After this period, we applied the corrective and incubated the soil for 30 days, then P and basic fertilization (macro and micronutrients were applied and the soil was incubated for additional 60 days. Equilibrium phosphorus, maximum phosphate adsorption capacity, pH, exchangeable Al and phosphorus-buffering index were measured. Organic residue and limestone application increased soil pH and reduced exchangeable Al, decreasing P adsorption. Gypsum application did not increase the pH but reduced exchangeable Al and P adsorption.A aplicação de resíduo orgânico é uma alternativa de baixo custo para reduzir a aplicação de fertilizantes inorgânicos e corretivos. Com objetivo de estudar a relação da aplicação de resíduo orgânico, calcário e gesso com adsorção de fósforo em solos de várzea conduziram-se simultaneamente quatro experimentos com os solos Organossolo Mésico (OY, Gleissolo Melânico (GM, Gleissolo Háplico (GX e Neossolo Flúvico (RU. O delineamento experimental utilizado foi o inteiramente casualizado, em esquema fatorial 3x2, com cinco repetições, sendo três práticas de correção do solo (calcário, gesso e sem corretivo e dois níveis de resíduo orgânico com e sem esterco de curral curtido. Amostras dos solos foram incubadas por 60 dias

Efeitos da compactação do solo e do manejo da água sobre os componentes de produção e a produtividade de grãos de arroz Effects of soil compaction and water management upon yield components and rice grain yields

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Roberto Dantas de Medeiros

2005-10-01

. The results stressed that soil compaction tends to reduce the number os panicles per pot, sterility of spikelets and grain yield. At moderate compaction levels, there was an increase of the number of filled grain per panicle, taking into account the three water management. Moisture favored production components: the number of panicles per pot, the number of filled grain per panicle and spikelet sterility, contributing toward increased yield. Thus, it follows that soil moisture was more determinant than compaction as a limiting factor to grain yield and, that, for Fluvic Neosol, compaction per si is not a factor limiting to a possible adoption of the no-tillage system with lowland rice.

Teor de arsênio e adsorção competitiva arsênio/fosfato e arsênio/sulfato em solos de Minas Gerais, Brasil Arsenate content, and arsenate/phosphate and arsenate/sulphate competitive adsorption in soils from Minas Gerais, Brazil

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Mari Lucia Campos

2013-06-01

Full Text Available A alta toxicidade de As para homens e animais gera a necessidade de estudos do comportamento químico do arsenato nos solos que possam auxiliar na mitigação de áreas contaminadas com arsênio. Este trabalho teve por objetivo avaliar o teor total e a adsorção de As na ausência e presença dos ânions fosfato e sulfato em seis diferentes classes de solos do estado de Minas Gerais, Brasil. Os solos alvo deste estudo são: o Neossolo Flúvico (RU, Gleissolo Háplico (GX, Gleissolo Melânico (GM, Latossolo Vermelho Distrófico (LVd, coletados em Lavras; Neossolo Quartzarênico (RQ, coletado em Itutinga e o Latossolo Amarelo Distrófico (LAd, coletado em Rosário, no estado de Minas Gerais. As amostras de solo foram secas, moídas e peneiradas em peneira de 2,0mm para execução do teste de adsorção e peneiradas em peneira plástica com malha de 1,5mm para determinação do teor de As, o qual foi determinado pelo método 3051A. A adsorção de As foi avaliada na dose de1500µmol L-1 de As, 1500µmol L-1 de As + 1500µmol L-1 de P e 1500µmol L-1 de As + 750µmolL-1 de S, em relação solo:solução final de 1:100, a pH 5,5 e força iônica de 15mmol L-1. Os seis solos apresentaram teor médio de As entre 0,14 e 9,3mgkg-1. A porcentagem adsorvida de arsênio na ausência dos outros ânions seguiu a sequência GM>LVd=RU=LAd=GX=RQ. A adição de fosfato e sulfato reduziu a porcentagem de arsênio adsorvido e, por consequência, houve um aumentou na concentração de arsênio disponível na solução do solo.The high toxicity of arsenic to humans and animals creates the need to study the chemical behavior of arsenate in soils that can help in the mitigation of areas contaminated with arsenic. This work aimed to evaluate the total content and adsorption in the absence and presence of phosphate and sulfate anions in six different soil classes in the state of Minas Gerais, Brazil. Soils aim of this study are: Fluvic Neosol (RU, Haplic Gleysol (GX

Solos do topo da Serra São José (Minas Gerais e suas relações com o paleoclima no Sudeste do Brasil Soils of the São José Hills (Minas Gerais State, Brazil and their relationship with palaeoclimate in Southeastern Brazil

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A. C. Silva

2004-06-01

sand layers, were identified in P1. Three layers in P1 (20-30, 70-80, and 100-110 cm depth with an organic C content of 0,5, 7, and 1 dag kg-1, respectively, present radiocarbon (14C ages < 40, 180 ± 60, and 350 ± 80 years BP, respectively, and deposition rates of 0.177 cm year-1 at depths between 110 and 170 cm and of 0.357 cm year-1 between 70 and 20 cm layer. In P2, the layers enriched with organic matter are thicker (between 10 and 130 mm, with abrupt discontinuity. They lie between 20-30, 80-90 110-120, and 170-180 cm deep, have a C content of 3, 2.5, 21, and 1.5 dag kg-1, and a 14 C age of 3580 ± 80, 3750 ± 80, 21210 ± 180, and 24060 ± 130 year-1 BP, respectively. Their deposition rates are 0.352 cm year-1 between 20 and 80 cm, 0.002 cm year-1 between 80 and 110 cm and 0.021 cm year-1 at depths between 110 and 170 cm. In both soil profiles, the C/N ratio increases with depth and age. The amount of Ti and Zr, elements of low mobility, are higher in the oldest profile layers, while Cu and Pb are more concentrated in the layers higher in organic matter. A plant fragment (diameter 5 cm, 62 cm long found at the bottom of P2 dated back to 32220 ± 290 years BP, and is associated with the beginning of this profile formation. The soils at the summit of São José Hills had its origin in the Tiradentes Formation without contribution of other geologic material. Rain water is the main factor that adds energy to this environmental energy. Therefore, soil formation is related to climate attributes. P1 is a holocenic (Fluvic Entisol soil, formed by episodic depositions of sand, alternated with sand enriched with organic matter. The formation of P2 (Paleosol began in the Pleistocene and lasted until the Holocene. The morphology of its buried peat layers is related to oscillations of the water surface of a lake, reflecting drier and more humid climate phases. The assessed radiocarbonic ages are related to Pleistocene and Holocene climate alternations in P2 and holocenic in