WorldWideScience

Sample records for first-order functional programs

  1. RKR1: A computer program implementing the first-order RKR method for determining diatomic molecule potential energy functions

    Science.gov (United States)

    Le Roy, Robert J.

    2017-01-01

    This paper describes computer program RKR1, which implements the first-order semiclassical Rydberg-Klein-Rees procedure for determining the potential energy function for a diatomic molecule from a knowledge of the dependence of the molecular vibrational energies Gv and inertial rotation constants Bv on the vibrational quantum number v. RKR1 allows the vibrational energies and rotational constants to be defined in terms of: (i) conventional Dunham polynomial expansions, (ii) near-dissociation expansions (NDE's), or (iii) the mixed Dunham/NDE "MXR" functions introduced by Tellinghuisen [J Chem Phys 2003; 118: 3532]. Internal convergence tests ascertain and report on the precision of the resulting turning points. For cases in which only vibrational data are available, RKR1 also allows an overall potential to be constructed by combining directly-calculated well widths with inner turning points generated from a Morse function. It can also automatically smooth over irregular or unphysical behavior of the steep inner wall of the potential.

  2. First order solutions in conic programming

    NARCIS (Netherlands)

    Dür, Mirjam; Jargalsaikhan, Bolor; Still, Georg

    2015-01-01

    We study the order of maximizers in linear conic programming (CP) as well as stability issues related to this. We do this by taking a semi-infinite view on conic programs: a linear conic problem can be formulated as a special instance of a linear semi-infinite program (SIP), for which characterizati

  3. Phase fluctuations and first-order correlation functions of dissipative Bose-Einstein condensates

    NARCIS (Netherlands)

    De Leeuw, A. W.; Stoof, H. T C; Duine, R. A.

    2014-01-01

    We investigate the finite-lifetime effects on first-order correlation functions of dissipative Bose-Einstein condensates. By taking into account the phase fluctuations up to all orders, we show that the finite-lifetime effects are negligible for the spatial first-order correlation functions, but hav

  4. Uniqueness of solutions of the Cauchy problems for first order partial differential-functional equations

    Directory of Open Access Journals (Sweden)

    Danuta Jaruszewska-Walczak

    1994-05-01

    Full Text Available We formulate a criterion of uniqueness of solutions of a Cauchy problem using the comparison function of the Kamke type. This will be a generalization of classical results concerning first order equations with partial derivatives. We prove that the uniqueness criteria of Perron and Kamke type for differential-function problems are equivalent if given functions are continuous.

  5. Uniqueness of solutions of the Cauchy problems for first order partial differential-functional equations

    OpenAIRE

    Danuta Jaruszewska-Walczak

    1994-01-01

    We formulate a criterion of uniqueness of solutions of a Cauchy problem using the comparison function of the Kamke type. This will be a generalization of classical results concerning first order equations with partial derivatives. We prove that the uniqueness criteria of Perron and Kamke type for differential-function problems are equivalent if given functions are continuous.

  6. First order magneto-structural transition in functional magnetic materials: phase-coexistence and metastability

    Indian Academy of Sciences (India)

    S B Roy; M K Chattopadhyay; M A Manekar; K J S Sokhey; P Chaddah

    2006-11-01

    First order magneto-structural transition plays an important role in the functionality of various magnetic materials of current interest like manganese oxide systems showing colossal magnetoresistance, Gd5(Ge, Si)4 alloys showing giant magnetocaloric effects and magnetic shape memory alloys. The key features of this magneto-structural transition are phase-coexistence and metastability. This generality is highlighted with experimental results obtained in a particular class of materials. A generalized framework of disorder influenced first order phase transition is introduced to understand the interesting experimental results which have some bearing on the functionality of the concerned materials.

  7. Maximum Principles and Boundary Value Problems for First-Order Neutral Functional Differential Equations

    Directory of Open Access Journals (Sweden)

    Domoshnitsky Alexander

    2009-01-01

    Full Text Available We obtain the maximum principles for the first-order neutral functional differential equation where , and are linear continuous operators, and are positive operators, is the space of continuous functions, and is the space of essentially bounded functions defined on . New tests on positivity of the Cauchy function and its derivative are proposed. Results on existence and uniqueness of solutions for various boundary value problems are obtained on the basis of the maximum principles.

  8. Boundary Value Problems for First-Order Impulsive Functional q-Integrodifference Equations

    Directory of Open Access Journals (Sweden)

    Jessada Tariboon

    2014-01-01

    Full Text Available We discuss the existence and uniqueness of solutions for a first-order boundary value problem for impulsive functional qk-integrodifference equations. The main results are obtained with the aid of some classical fixed point theorems. Illustrative examples are also presented.

  9. Invariant Functions, Symmetries and Primary Branch Solutions of First Order Autonomous Systems

    Science.gov (United States)

    Lou, Sen-Yue; Yao, Ruo-Xia

    2017-07-01

    An invariant function (IF) is defined as a multiplier of a symmetry that means a symmetry multiplied by an IF is still a symmetry. Primary branch solutions of arbitrary first order scalar systems can be obtained by means of the IF and its related symmetry approach. Especially, one recursion operator and some sets of infinitely many high order symmetries are also explicitly given for arbitrary (1+1)-dimensional first order autonomous systems. Because of the intrusion of the arbitrary function, various implicit special exact solutions can be found by fixing the arbitrary functions and selecting different seed solutions. Supported by the National Natural Science Foundations of China under Grant Nos. 11435005, 11471004, 11175092, and 11205092, Shanghai Knowledge Service Platform for Trustworthy Internet of Things No. ZF1213 and K. C. Wong Magna Fund in Ningbo University

  10. Wave Function of the Universe from a Matrix Valued First-Order Formalism

    CERN Document Server

    Kruglov, Sergey I

    2014-01-01

    In this paper, we obtain the wave function of the universe for a universe filled with a constant energy density and radiation. First, the Wheeler-DeWitt equation for this model in minisuperspace approximation is considered. Then, we represent the Wheeler-DeWitt equation in a matrix valued first-order formalism. We note that the Wheeler-DeWitt equation can be expressed as an eigenvalue equation in this formalism. So, projection operators for the Wheeler-DeWitt equation are constructed. Using these projection operators we obtain a solution for the Wheeler-DeWitt equation.

  11. Periodic solutions of first-order functional differential equations in population dynamics

    CERN Document Server

    Padhi, Seshadev; Srinivasu, P D N

    2014-01-01

    This book provides cutting-edge results on the existence of multiple positive periodic solutions of first-order functional differential equations. It demonstrates how the Leggett-Williams fixed-point theorem can be applied to study the existence of two or three positive periodic solutions of functional differential equations with real-world applications, particularly with regard to the Lasota-Wazewska model, the Hematopoiesis model, the Nicholsons Blowflies model, and some models with Allee effects. Many interesting sufficient conditions are given for the dynamics that include nonlinear characteristics exhibited by population models. The last chapter provides results related to the global appeal of solutions to the models considered in the earlier chapters. The techniques used in this book can be easily understood by anyone with a basic knowledge of analysis. This book offers a valuable reference guide for students and researchers in the field of differential equations with applications to biology, ecology, a...

  12. Stability analysis of a PFTR reactor for a first order kinetic reaction using the Lyapunov functionals

    Directory of Open Access Journals (Sweden)

    Héctor Armando Durán Peralta

    2010-04-01

    Full Text Available The stability of reactors having encompassing concentration and temperature parameters, such as continuous flow stirred tank reactors (CSTR, has been widely explored in the literature; however, there are few papers about the stability of tubular reactor having distributed spatial concentration and temperature parameters such as the plow flow tubular reactor (PFTR. This paper analyses the stability of isothermal and non-isothermal PFTR reactors using the Lyapunov functional method. The first order kinetic reaction was selected because one of this paper’s oblectives was to apply Lyapunov functionals to stability analysis of distributed parameter reactors (technique used in electrical engineering systems’ stability analysis. The stability analysis revealed asymptotically stable tempe- rature and concentration profiles for isothermal PFTR, non-isothermal PFTR with kinetic constant independent of temperature and adiabatic non-isothermal PFTR. Analysis revealed an asymptotically stability region for the heat exchange reactor and an uncertain region where it may have oscillations.

  13. Uniqueness of solutions of a generalized Cauchy problem for a system of first order partial functional differential equations

    Directory of Open Access Journals (Sweden)

    Milena Netka

    2009-01-01

    Full Text Available The paper is concerned with weak solutions of a generalized Cauchy problem for a nonlinear system of first order differential functional equations. A theorem on the uniqueness of a solution is proved. Nonlinear estimates of the Perron type are assumed. A method of integral functional inequalities is used.

  14. First-order model for durability of Hanford waste glasses as a function of composition

    Energy Technology Data Exchange (ETDEWEB)

    Hrma, P.; Piepel, G.F.; Schweiger, M.J.; Smith, D.E.

    1992-04-01

    Two standard chemical durability tests, the static leach test MCC-1 and product consistency test PCT, were conducted on simulated borosilicate glasses that encompass the expected range of compositions to be produced in the Hanford Waste Vitrification Plant (HWVP). A first-order empirical model was fitted to the data from each test method. The results indicate that glass durability is increased by addition of Al{sub 2}O{sub 3}, moderately increased by addition of ZrO{sub 2} and SiO{sub 2}, and decreased by addition of Li{sub 2}O, Na{sub 2}O, B{sub 2}O{sub 3}, and MgO. Addition of Fe{sub 2}O{sub 3} and CaO produce an indifferent or reducing effect on durability according to the test method. This behavior and a statistically significant lack of fit are attributed to the effects of multiple chemical reactions occurring during glass-water interaction. Liquid-liquid immiscibility is suspected to be responsible for extremely low durability of some glasses.

  15. First order non-homogeneous q-difference equation for Stieltjes function characterizing q-orthogonal polynomials

    CERN Document Server

    Arvesú, J

    2012-01-01

    In this paper we give a characterization of some classical q-orthogonal polynomials in terms of a difference property of the associated Stieltjes function, i.e this function solves a first order non-homogeneous q-difference equation. The solutions of the aforementioned q-difference equation (given in terms of hypergeometric series) for some canonical cases, namely, q-Charlier, q-Kravchuk, q-Meixner and q-Hahn are worked out.

  16. Modified Current Differencing Unit and its Application for Electronically Reconfigurable Simple First-order Transfer Function

    Directory of Open Access Journals (Sweden)

    SOTNER, R.

    2015-02-01

    Full Text Available Modified current differencing unit (MCDU and its simple filtering application are introduced in this paper. Modification of the well-known current differencing unit consists in weighted difference of both input currents controlled by adjustable current gain, controllable intrinsic resistance of both current input terminals, and availability of additional voltage terminal(s. Definition of MCDU therefore requires four adjustable parameters (B1, B2, Rp, Rn. A presented active element offers and combines benefits of electronically controllable current conveyor of second generation and current differencing unit and allows synthesis of interesting adjustable applications, which are not available by classical approaches based on simple elements. MCDU brings variability of the transfer function into the structure. It provides several transfer types without necessity of input or output node change by simple electronic tuning. A presented structure represents so-called reconnection-less reconfigurable current-mode filter for realization of all-pass, inverting high-pass, low-pass and direct transfer response. Behavioral model of the MCDU was prepared and carefully tested in filtering application. Spice simulations and measurements confirmed theoretical assumptions.

  17. Buckling of Functionally Graded Nanobeams Based on the Nonlocal New First-Order Shear Deformation Beam Theory

    Directory of Open Access Journals (Sweden)

    Houari M.S.A.

    2014-04-01

    Full Text Available In this work, the size-dependent buckling behavior of functionally graded (FG nanobeams is investigated on the basis of the nonlocal continuum model. The material properties of FG nanobeams are assumed to vary through the thickness according to the power law. In addition, Poisson’s ratio is assumed constant in the current model. The nanobeams is modelled according to the new first order shear beam theory with small deformation and the equilibrium equations are derived using the Hamilton’s principle. The Naviertype solution is developed for simply-supported boundary conditions, and exact formulas are proposed for the buckling load. The effects of nonlocal parameter, aspect ratio, various material compositions on the stability responses of the FG nanobeams are discussed.

  18. Moving-Horizon Modulating Functions-Based Algorithm for Online Source Estimation in a First Order Hyperbolic PDE

    KAUST Repository

    Asiri, Sharefa M.

    2017-08-22

    In this paper, an on-line estimation algorithm of the source term in a first order hyperbolic PDE is proposed. This equation describes heat transport dynamics in concentrated solar collectors where the source term represents the received energy. This energy depends on the solar irradiance intensity and the collector characteristics affected by the environmental changes. Control strategies are usually used to enhance the efficiency of heat production; however, these strategies often depend on the source term which is highly affected by the external working conditions. Hence, efficient source estimation methods are required. The proposed algorithm is based on modulating functions method where a moving horizon strategy is introduced. Numerical results are provided to illustrate the performance of the proposed estimator in open and closed loops.

  19. First-order inflation

    Energy Technology Data Exchange (ETDEWEB)

    Kolb, E.W. (Fermi National Accelerator Lab., Batavia, IL (USA) Chicago Univ., IL (USA). Enrico Fermi Inst.)

    1990-09-01

    In the original proposal, inflation occurred in the process of a strongly first-order phase transition. This model was soon demonstrated to be fatally flawed. Subsequent models for inflation involved phase transitions that were second-order, or perhaps weakly first-order; some even involved no phase transition at all. Recently the possibility of inflation during a strongly first-order phase transition has been revived. In this talk I will discuss some models for first-order inflation, and emphasize unique signatures that result in inflation is realized in a first-order transition. Before discussing first-order inflation, I will briefly review some of the history of inflation to demonstrate how first-order inflation differs from other models. 58 refs., 3 figs.

  20. Free vibration of functionally graded beams based on both classical and first-order shear deformation beam theories

    Institute of Scientific and Technical Information of China (English)

    李世荣; 万泽青; 张静华

    2014-01-01

    The free vibration of functionally graded material (FGM) beams is studied based on both the classical and the first-order shear deformation beam theories. The equations of motion for the FGM beams are derived by considering the shear deforma-tion and the axial, transversal, rotational, and axial-rotational coupling inertia forces on the assumption that the material properties vary arbitrarily in the thickness direction. By using the numerical shooting method to solve the eigenvalue problem of the coupled ordinary differential equations with different boundary conditions, the natural frequen-cies of the FGM Timoshenko beams are obtained numerically. In a special case of the classical beam theory, a proportional transformation between the natural frequencies of the FGM and the reference homogenous beams is obtained by using the mathematical similarity between the mathematical formulations. This formula provides a simple and useful approach to evaluate the natural frequencies of the FGM beams without dealing with the tension-bending coupling problem. Approximately, this analogous transition can also be extended to predict the frequencies of the FGM Timoshenko beams. The numerical results obtained by the shooting method and those obtained by the analogous transformation are presented to show the effects of the material gradient, the slenderness ratio, and the boundary conditions on the natural frequencies in detail.

  1. MRI pulse sequence design with first-order gradient moment nulling in arbitrary directions by solving a polynomial program.

    Science.gov (United States)

    Majewski, Kurt; Heid, Oliver; Kluge, Thomas

    2010-06-01

    We suggest a polynomial program for the calculation of optimized gradient waveforms for magnetic resonance tomography pulse sequences. Such non-linear mathematical programs can describe gradient system capabilities, meet k-space trajectory specifications, and capture sequence timing conditions. Moreover they allow the incorporation of gradient moment nulling constraints in one or several arbitrary spatial directions, which can reduce flow motion artifacts in the images. We report first experiences in solving such automatic pulse sequence design programs with the interior point solver Ipopt.

  2. Neutron diffraction evidence for kinetic arrest of first order magneto-structural phase transitions in some functional magnetic materials.

    Science.gov (United States)

    Siruguri, V; Babu, P D; Kaushik, S D; Biswas, Aniruddha; Sarkar, S K; Krishnan, Madangopal; Chaddah, P

    2013-12-11

    Neutron diffraction measurements, performed in the presence of an external magnetic field, have been used to show structural evidence for the kinetic arrest of the first order phase transition from (i) the high temperature austenite phase to the low temperature martensite phase in the magnetic shape memory alloy Ni37Co11Mn42.5Sn9.5, (ii) the higher temperature ferromagnetic phase to the lower temperature antiferromagnetic phase in the half-doped charge ordered compound La0.5Ca0.5MnO3 and (iii) the formation of glass-like arrested states in both compounds. The cooling and heating under unequal fields protocol has been used to establish phase coexistence of metastable and equilibrium states, and also to demonstrate the devitrification of the arrested metastable states in the neutron diffraction patterns. We also explore the field–temperature dependent kinetic arrest line TK(H), through the transformation of the arrested phase to the equilibrium phase. This transformation has been observed isothermally in reducing H, as also on warming in constant H. TK is seen to increase as H increases in both cases, consistent with the low-T equilibrium phase having lower magnetization.

  3. On functional bases of the first-order differential invariants for non-conjugate subgroups of the Poincaré group $P(1,4$

    Directory of Open Access Journals (Sweden)

    V.M. Fedorchuk

    2008-11-01

    Full Text Available It is established which functional bases of the first-order differential invariants of the splitting and non-splitting subgroups of the Poincaré group $P(1,4$ are invariant under the subgroups of the extended Galilei group $widetilde G(1,3 subset P(1,4$. The obtained sets of functional bases are classified according to dimensions.

  4. A first order Tsallis theory

    Science.gov (United States)

    Ferri, Gustavo L.; Plastino, Angel; Rocca, Mario C.; Zamora, Dario J.

    2017-03-01

    We investigate first-order approximations to both (i) Tsallis' entropy Sq and (ii) the Sq-MaxEnt solution (called q-exponential functions eq). We use an approximation/expansion for q very close to unity. It is shown that the functions arising from the procedure (ii) are the MaxEnt solutions to the entropy emerging from (i). Our present treatment is motivated by the fact it is FREE of the poles that, for classic quadratic Hamiltonians, appear in Tsallis' approach, as demonstrated in [A. Plastimo, M.C. Rocca, Europhys. Lett. 104, 60003 (2013)]. Additionally, we show that our treatment is compatible with extant date on the ozone layer.

  5. On the reduction of the multidimensional stationary Schroedinger equation to a first-order equation and its relation to the pseudoanalytic function theory

    Energy Technology Data Exchange (ETDEWEB)

    Kravchenko, Vladislav V [Departmento de Telecomunicaciones, SEPI, Escuela Superior de IngenierIa Mecanica y Electrica, Instituto Politecnico Nacional, CP 07738 Mexico DF (Mexico)

    2005-01-28

    Given a particular solution of a one-dimensional stationary Schroedinger equation this equation of second order can be reduced to a first-order linear ordinary differential equation. This is done with the aid of an auxiliary Riccati differential equation. In the present work we show that the same fact is true in a multidimensional situation also. For simplicity we consider the case of two or three independent variables. One particular solution of the stationary Schroedinger equation allows us to reduce this second-order equation to a linear first-order quaternionic differential equation. As in the one-dimensional case this is done with the aid of an auxiliary quaternionic Riccati equation. The resulting first-order quaternionic equation is equivalent to the static Maxwell system and is closely related to the Dirac equation. In the case of two independent variables it is the well-known Vekua equation from theory of pseudoanalytic (or generalized analytic) functions. Nevertheless, we show that even in this case it is very useful to consider not only complex valued functions, solutions of the Vekua equation, but complete quaternionic functions. In this way the first-order quaternionic equation represents two separate Vekua equations, one of which gives us solutions of the Schroedinger equation and the other one can be considered as an auxiliary equation of a simpler structure. Moreover for the auxiliary equation we always have the corresponding Bers generating pair (F, G), the base of the Bers theory of pseudoanalytic functions, and what is very important, the Bers derivatives of solutions of the auxiliary equation give us solutions of the main Vekua equation and as a consequence of the Schroedinger equation. Based on this fact we obtain an analogue of the Cauchy integral theorem for solutions of the stationary Schroedinger equation. Other results from theory of pseudoanalytic functions can be written for solutions of the Schroedinger equation. Moreover, for an ample

  6. On generalized entropy solutions of the Cauchy problem for a first-order quasilinear equation in the class of locally summable functions

    Energy Technology Data Exchange (ETDEWEB)

    Panov, E Yu [Novgorod State University, Novgorod (Russian Federation)

    2002-12-31

    We construct a theory of locally summable generalized entropy solutions (g.e. solutions) of the Cauchy problem for a first-order non-homogeneous quasilinear equation with continuous flux vector satisfying a linear restriction on its growth. We prove the existence of greatest and least g.e. solutions, suggest sufficient conditions for uniqueness of g.e. solutions, prove several versions of the comparison principle, and obtain estimates for the L{sup p}-norms of solution with respect to the space variables. We establish the uniqueness of g.e. solutions in the case when the input data are periodic functions of the space variables.

  7. First-order formative rules

    OpenAIRE

    Fuhs, Carsten; Kop, C.

    2014-01-01

    This paper discusses the method of formative rules for first-order term rewriting, which was previously defined for a higher-order setting. Dual to the well-known usable rules, formative rules allow dropping some of the term constraints that need to be solved during a termination proof. Compared to the higher-order definition, the first-order setting allows for significant improvements of the technique.

  8. Vibrational spectroscopic studies, normal co-ordinate analysis, first order hyperpolarizability, HOMO-LUMO of midodrine by using density functional methods.

    Science.gov (United States)

    Shahidha, R; Al-Saadi, Abdulaziz A; Muthu, S

    2015-01-05

    The FTIR (4000-400 cm(-1)), FT-Raman (4000-100 cm(-1)) and UV-Visible (400-200 nm) spectra of midodrine were recorded in the condensed state. The complete vibrational frequencies, optimized geometry, intensity of vibrational bands and atomic charges were obtained by using Density Functional Theory (DFT) with the help of 6-311++G(d,p) basis set. The first order hyperpolarizability (β) and related properties (μ, α and Δα) of this molecular system were calculated by using DFT/6-311++G(d,p) method based on the finite-field approach. The assignments of the vibrational spectra have been carried out with the help of Normal Co-ordinate Analysis (NCA) following the scaled quantum mechanical force methodology. Stability of the molecule arising from hyper conjugative interactions, charge delocalization has been analyzed using NBO analysis. From the recorded UV-Visible spectrum, the electronic properties such as excitation energies, oscillator strength and wavelength are calculated by DFT in water and gas methods using 6-311++G(d,p) basis set. The calculated HOMO and LUMO energies confirm that charge transfer occurs within the molecule. Besides MEP, NLO and thermodynamic properties were also calculated and interpreted. The electron density-based local reactivity descriptor such as Fukui functions was calculated to explain the chemical selectivity or reactivity site in midodrine. Copyright © 2014 Elsevier B.V. All rights reserved.

  9. Molecular structure, vibrational spectra, NBO, UV and first order hyperpolarizability, analysis of 4-Chloro-dl-phenylalanine by density functional theory.

    Science.gov (United States)

    Govindarasu, K; Kavitha, E

    2014-12-10

    The Fourier transform infrared (4000-400cm(-1)) and Fourier transform Raman (3500-50cm(-1)) spectra of 4-Chloro-dl-phenylalanine (4CLPA) were recorded and analyzed. The equilibrium geometry, bonding features and harmonic vibrational wavenumbers were investigated with the help of density functional theory (DFT) method using B3LYP/6-31G(d,p) as basis set. The observed vibrational wavenumbers were compared with the calculated results. Natural bond orbital analysis confirms the presence of intramolecular charge transfer and the hydrogen bonding interaction. Predicted electronic absorption spectra from TD-DFT calculation have been analyzed comparing with the UV-Vis (200-800nm) spectrum. The effects of chlorine and ethylene group substituent in benzene ring in the vibrational wavenumbers have been analyzed. The HOMO-LUMO energy gap explains the charge interaction taking place within the molecule. The first order hyperpolarizability (β0) and related properties (β, α0 and Δα) of 4CLPA were calculated. The Chemical reactivity and chemical potential of 4CLPA is calculated. In addition, molecular electrostatic potential (MEP), frontier molecular orbital (FMO) analysis were investigated using theoretical calculations. Published by Elsevier B.V.

  10. Molecular structure, vibrational spectra, NBO, UV and first order hyperpolarizability, analysis of 4-Chloro-DL-phenylalanine by density functional theory

    Science.gov (United States)

    Govindarasu, K.; Kavitha, E.

    2014-12-01

    The Fourier transform infrared (4000-400 cm-1) and Fourier transform Raman (3500-50 cm-1) spectra of 4-Chloro-DL-phenylalanine (4CLPA) were recorded and analyzed. The equilibrium geometry, bonding features and harmonic vibrational wavenumbers were investigated with the help of density functional theory (DFT) method using B3LYP/6-31G(d,p) as basis set. The observed vibrational wavenumbers were compared with the calculated results. Natural bond orbital analysis confirms the presence of intramolecular charge transfer and the hydrogen bonding interaction. Predicted electronic absorption spectra from TD-DFT calculation have been analyzed comparing with the UV-Vis (200-800 nm) spectrum. The effects of chlorine and ethylene group substituent in benzene ring in the vibrational wavenumbers have been analyzed. The HOMO-LUMO energy gap explains the charge interaction taking place within the molecule. The first order hyperpolarizability (β0) and related properties (β, α0 and Δα) of 4CLPA were calculated. The Chemical reactivity and chemical potential of 4CLPA is calculated. In addition, molecular electrostatic potential (MEP), frontier molecular orbital (FMO) analysis were investigated using theoretical calculations.

  11. First-Order Twistor Lifts

    Directory of Open Access Journals (Sweden)

    Simões BrunoAscenso

    2010-01-01

    Full Text Available The use of twistor methods in the study of Jacobi fields has proved quite fruitful, leading to a series of results. L. Lemaire and J. C. Wood proved several properties of Jacobi fields along harmonic maps from the two-sphere to the complex projective plane and to the three- and four-dimensional spheres, by carefully relating the infinitesimal deformations of the harmonic maps to those of the holomorphic data describing them. In order to advance this programme, we prove a series of relations between infinitesimal properties of the map and those of its twistor lift. Namely, we prove that isotropy and harmonicity to first order of the map correspond to holomorphicity to first order of its lift into the twistor space, relatively to the standard almost complex structures and . This is done by obtaining first-order analogues of classical twistorial constructions.

  12. First-order density matrix as a functional of the ground-state electron density for harmonic confinement of two electrons which also interact harmonically

    Energy Technology Data Exchange (ETDEWEB)

    March, N.H

    2002-12-30

    The first-order density matrix {gamma}(r{sub 1},r{sub 2}) for the ground-state of a model two-electron atom is explicitly constructed from the electron density {rho}(r). The model has harmonic confinement plus interparticle harmonic interactions. {gamma}(r{sub 1},r{sub 2}) and {rho}(r) are related non-locally, even though no density gradients and no quadratures appear.

  13. First-Order Logical Duality

    CERN Document Server

    Awodey, Steve

    2010-01-01

    From a logical point of view, Stone duality for Boolean algebras relates theories in classical propositional logic and their collections of models. The theories can be seen as presentations of Boolean algebras, and the collections of models can be topologized in such a way that the theory can be recovered from its space of models. The situation can be cast as a formal duality relating two categories of syntax and semantics, mediated by homming into a common dualizing object, in this case $2$. In the present work, we generalize the entire arrangement from propositional to first-order logic. Boolean algebras are replaced by Boolean categories presented by theories in first-order logic, and spaces of models are replaced by topological groupoids of models and their isomorphisms. A duality between the resulting categories of syntax and semantics, expressed first in the form of a contravariant adjunction, is established by homming into a common dualizing object, now $\\Sets$, regarded once as a boolean category, and...

  14. First-Order Hybrid Logic

    DEFF Research Database (Denmark)

    Braüner, Torben

    2011-01-01

    Hybrid logic is an extension of modal logic which allows us to refer explicitly to points of the model in the syntax of formulas. It is easy to justify interest in hybrid logic on applied grounds, with the usefulness of the additional expressive power. For example, when reasoning about time one...... often wants to build up a series of assertions about what happens at a particular instant, and standard modal formalisms do not allow this. What is less obvious is that the route hybrid logic takes to overcome this problem often actually improves the behaviour of the underlying modal formalism....... For example, it becomes far simpler to formulate proof-systems for hybrid logic, and completeness results can be proved of a generality that is simply not available in modal logic. That is, hybridization is a systematic way of remedying a number of known deficiencies of modal logic. First-order hybrid logic...

  15. Multipoint normal differential operators of first order

    Directory of Open Access Journals (Sweden)

    Zameddin I. Ismailov

    2009-01-01

    Full Text Available In this paper we discuss all normal extensions of a minimal operator generated by a linear multipoint differential-operator expression of first order in the Hilbert space of vector-functions on the finite interval in terms of boundary and interior point values. Later on, we investigate the structure of the spectrum, its discreteness and the asymptotic behavior of the eigenvalues at infinity for these extensions.

  16. Novel SVPWM based on first order equation

    Directory of Open Access Journals (Sweden)

    Ahmed A. Mansour

    2015-09-01

    Full Text Available PWM plays an important role in generating sinusoidal waveform for variable voltage variable frequency drives (VVVFD's with a minimum harmonic level. PWM techniques have many methods in implementation ranging from a relatively simple method such as modulating sine wave to the advanced Space Vector PWM technique SVPWM. The SVPWM has a dense calculation that requires considerable processor time for execution. The proposed technique requires simple calculations and can be implemented using simple microcontrollers. The calculations of the proposed SVPWM are based on first order equations rather than trigonometric functions requiring either huge lookup tables for fetching or too many instruction cycles for calculation on a digital controller.

  17. The use of the first order system transfer function in the analysis of proboscis extension learning of honey bees, Apis mellifera L., exposed to pesticides.

    Science.gov (United States)

    Abramson, Charles I; Stepanov, Igor I

    2012-04-01

    No attempts have been made to apply a mathematical model to the learning curve in honey bees exposed to pesticides. We applied a standard transfer function in the form Y = B3*exp(- B2 * (X - 1)) + B4 * (1 - exp(- B2 * (X - 1))), where X is the trial number; Y is proportion of correct responses, B2 is the learning rate, B3 is readiness to learn and B4 is ability to learn. Reanalyzing previously published data on the effect of insect growth regulators tebufenozide and diflubenzuron on the classical conditioning of proboscis extension, the model revealed additional effects not detected with standard statistical tests of significance.

  18. The First Order Transfer Function in the Analysis of Agrochemical Data in Honey Bees (Apis Mellifera L.: Proboscis Extension Reflex (PER Studies

    Directory of Open Access Journals (Sweden)

    Lisa A. De Stefano

    2014-01-01

    Full Text Available This paper describes a mathematical model of the learning process suitable for studies of conditioning using the proboscis extension reflex (PER in honey bees when bees are exposed to agrochemicals. Although procedural variations exist in the way laboratories use the PER paradigm, proboscis conditioning is widely used to investigate the influence of pesticides and repellents on honey bee learning. Despite the availability of several mathematical models of the learning process, no attempts have been made to apply a mathematical model to the learning curve in honey bees exposed to agrochemicals. Our model is based on the standard transfer function in the form Y=B3 e-B2 (X-1 +B4(1-e-B2 (X-1 where X is the trial number, Y is the proportion of correct responses, B2 is the learning rate, B3 is readiness to learn, and B4 is ability to learn. We reanalyze previously published data on the effect of several classes of agrochemicals including: (1 those that are considered harmless to bees (e.g., pymetrozine, essential oils, dicofol; (2 sublethal exposure to pesticides known to harm honey bees (e.g., coumaphos, cyfluthrin, fluvalinate, permethrin; and (3 putative repellents of honey bees (e.g., butyric acid, citronella. The model revealed additional effects not detected with standard statistical tests of significance.

  19. A functional quantum programming language

    CERN Document Server

    Altenkirch, T; Altenkirch, Thorsten; Grattage, Jonathan

    2004-01-01

    We introduce the language QML, a functional language for quantum computations on finite types. Its design is guided by its categorical semantics: QML programs are interpreted by morphisms in the category FQC of finite quantum computations, which provides a constructive semantics of irreversible quantum computations realizable as quantum gates. QML integrates reversible and irreversible quantum computations in one language, using first order strict linear logic to make weakenings explicit. Strict programs are free of decoherence and hence preserve entanglement which is essential for quantum parallelism.

  20. An Adequate First Order Logic of Intervals

    DEFF Research Database (Denmark)

    Chaochen, Zhou; Hansen, Michael Reichhardt

    1998-01-01

    This paper introduces left and right neighbourhoods as primitive interval modalities to define other unary and binary modalities of intervals in a first order logic with interval length. A complete first order logic for the neighbourhood modalities is presented. It is demonstrated how the logic c...

  1. Chemical Dosing and First-Order Kinetics

    Science.gov (United States)

    Hladky, Paul W.

    2011-01-01

    College students encounter a variety of first-order phenomena in their mathematics and science courses. Introductory chemistry textbooks that discuss first-order processes, usually in conjunction with chemical kinetics or radioactive decay, stop at single, discrete dose events. Although single-dose situations are important, multiple-dose events,…

  2. First-order Dyson coordinates and geometry.

    Science.gov (United States)

    Hermes, Matthew R; Hirata, So

    2013-08-15

    The mathematical constructs of the Dyson coordinates and geometry are introduced. The former are a unitary transformation of the normal coordinates and the anharmonic vibrational counterpart of the Dyson orbitals in electronic structure theory. The first-order Dyson coordinates bring the sums of the harmonic force constants and their first-order diagrammatic perturbation corrections (the first-order Dyson self-energy) to a diagonal form. The first-order Dyson geometry has no counterpart in electronic structure theory. It is the point on the potential energy surface at which the sums of the energy gradients and their first-order diagrammatic perturbation corrections vanish. It agrees with the vibrationally averaged geometry of vibrational self-consistent field (VSCF) theory in the bulk limit. These constructs provide a unified view of the relationship of VSCF and its diagrammatically size-consistent modifications as well as the self-consistent phonon method widely used in solid-state physics.

  3. Functional Python programming

    CERN Document Server

    Lott, Steven

    2015-01-01

    This book is for developers who want to use Python to write programs that lean heavily on functional programming design patterns. You should be comfortable with Python programming, but no knowledge of functional programming paradigms is needed.

  4. First-order partial differential equations

    CERN Document Server

    Rhee, Hyun-Ku; Amundson, Neal R

    2001-01-01

    Second volume of a highly regarded two-volume set, fully usable on its own, examines physical systems that can usefully be modeled by equations of the first order. Examples are drawn from a wide range of scientific and engineering disciplines. The book begins with a consideration of pairs of quasilinear hyperbolic equations of the first order and goes on to explore multicomponent chromatography, complications of counter-current moving-bed adsorbers, the adiabatic adsorption column, and chemical reaction in countercurrent reactors. Exercises appear at the end of most sections. Accessible to any

  5. Symmetries and first order ODE patterns

    Science.gov (United States)

    Cheb-Terrab, E. S.; Roche, A. D.

    1998-10-01

    A scheme for determining symmetries for certain families of first order ODEs, without solving any differential equations, and based mainly in matching an ODE to patterns of invariant ODE families, is presented. The scheme was implemented in Maple, in the framework of the ODEtools package and its ODE-solver. A statistics of the performance of this approach in solving the first order ODE examples of Kamke's book (E. Kamke, Differentialgleichungen: Lösungsmethoden und Lösungen (Chelsea, New York, 1959)) is shown.

  6. A definability theorem for first order logic

    NARCIS (Netherlands)

    Butz, C.; Moerdijk, I.

    2001-01-01

    In this paper we will present a definability theorem for first order logic This theorem is very easy to state and its proof only uses elementary tools To explain the theorem let us first observe that if M is a model of a theory T in a language L then clearly any definable subset S M ie a subset S

  7. First-Order Logic According to Harrison

    DEFF Research Database (Denmark)

    Jensen, Alexander Birch; Schlichtkrull, Anders; Villadsen, Jørgen

    2017-01-01

    We present a certified declarative first-order prover with equality based on John Harrison’s Handbook of Practical Logic and Automated Reasoning, Cambridge University Press, 2009. ML code reflection is used such that the entire prover can be executed within Isabelle as a very simple interactive...

  8. Spectroscopic studies (FT-IR, FT-Raman, UV-Visible), normal co-ordinate analysis, first-order hyperpolarizability and HOMO, LUMO studies of 3,4-dichlorobenzophenone by using Density Functional Methods.

    Science.gov (United States)

    Venkata Prasad, K; Samatha, K; Jagadeeswara Rao, D; Santhamma, C; Muthu, S; Mark Heron, B

    2015-01-01

    The vibrational frequencies of 3,4-dichlorobenzophenone (DCLBP) were obtained from the FT-IR and Raman spectral data, and evaluated based on the Density Functional Theory using the standard method B3LYP with 6-311+G(d,p) as the basis set. On the basis of potential energy distribution together with the normal-co-ordinate analysis and following the scaled quantum mechanical force methodology, the assignments for the various frequencies were described. The values of the electric dipole moment (μ) and the first-order hyperpolarizability (β) of the molecule were computed. The UV-absorption spectrum was also recorded to study the electronic transitions. The calculated HOMO and LUMO energies show that charge transfer occurs within the molecule. The NBO analysis, to study the intramolecular hyperconjugative interactions, was carried out. Mulliken's net charges were evaluated. The MEP and thermodynamic properties were also calculated. The electron density-based local reactivity descriptor, such as Fukui functions, was calculated to explain the chemical selectivity or reactivity site in 3,4-dichlorobenzophenone. Copyright © 2015 Elsevier B.V. All rights reserved.

  9. A First-Order One-Pass CPS Transformation

    DEFF Research Database (Denmark)

    Danvy, Olivier; Nielsen, Lasse Reichstein

    2002-01-01

    We present a new transformation of call-by-value lambdaterms into continuation-passing style (CPS). This transformation operates in one pass and is both compositional and first-order. Because it operates in one pass, it directly yields compact CPS programs that are comparable to what one would...

  10. Degenerate spacetimes in first order gravity

    CERN Document Server

    Kaul, Romesh K

    2016-01-01

    We present a systematic framework to obtain the most general solutions of the equations of motion in first order gravity theory with degenerate tetrads. There are many possible solutions. Generically, these exhibit non-vanishing torsion even in the absence of any matter coupling. These solutions are shown to contain a special set of eight configurations which are associated with the homogeneous model three-geometries of Thurston.

  11. First-order partial differential equations

    CERN Document Server

    Rhee, Hyun-Ku; Amundson, Neal R

    2001-01-01

    This first volume of a highly regarded two-volume text is fully usable on its own. After going over some of the preliminaries, the authors discuss mathematical models that yield first-order partial differential equations; motivations, classifications, and some methods of solution; linear and semilinear equations; chromatographic equations with finite rate expressions; homogeneous and nonhomogeneous quasilinear equations; formation and propagation of shocks; conservation equations, weak solutions, and shock layers; nonlinear equations; and variational problems. Exercises appear at the end of mo

  12. Continuous first order logic and local stability

    CERN Document Server

    Yaacov, Itaï Ben

    2008-01-01

    We develop continuous first order logic, a variant of the logic described in \\cite{Chang-Keisler:ContinuousModelTheory}. We show that this logic has the same power of expression as the framework of open Hausdorff cats, and as such extends Henson's logic for Banach space structures. We conclude with the development of local stability, for which this logic is particularly well-suited.

  13. Intuitionistic Completeness of First-Order Logic

    CERN Document Server

    Constable, Robert

    2011-01-01

    We establish completeness for intuitionistic first-order logic, iFOL, showing that is a formula is provable if and only if it is uniformly valid under the Brouwer Heyting Kolmogorov (BHK) semantics, the intended semantics of iFOL. Our proof is intuitionistic and provides an effective procedure Prf that converts uniform evidence into a formal first-order proof. We have implemented Prf . Uniform validity is defined using the intersection operator as a universal quantifier over the domain of discourse and atomic predicates. Formulas of iFOL that are uniformly valid are also intuitionistically valid, but not conversely. Our strongest result requires the Fan Theorem; it can also be proved classically by showing that Prf terminates using K\\"onig's Theorem. The fundamental idea behind our completeness theorem is that a single evidence term evd witnesses the uniform validity of a minimal logic formula F. Finding even one uniform realizer guarantees validity because Prf (F, evd) builds a first-order proof of F, establ...

  14. Molecular structure, vibrational spectroscopic (FT-IR, FT-Raman), UV-vis spectra, first order hyperpolarizability, NBO analysis, HOMO and LUMO analysis, thermodynamic properties of benzophenone 2,4-dicarboxylic acid by ab initio HF and density functional method.

    Science.gov (United States)

    Chaitanya, K

    2012-02-01

    The FT-IR (4000-450 cm(-1)) and FT-Raman spectra (3500-100 cm(-1)) of benzophenone 2,4-dicarboxylic acid (2,4-BDA) have been recorded in the condensed state. Density functional theory calculation with B3LYP/6-31G(d,p) basis set have been used to determine ground state molecular geometries (bond lengths and bond angles), harmonic vibrational frequencies, infrared intensities, Raman activities and bonding features of the title compounds. The assignments of the vibrational spectra have been carried out with the help of normal co-ordinate analysis (NCA) following the scaled quantum mechanical force field (SQMFF) methodology. The first order hyperpolarizability (β0) and related properties (β, α0 and Δα) of 2,4-BDA is calculated using HF/6-31G(d,p) method on the finite-field approach. The stability of molecule has been analyzed by using NBO analysis. The calculated first hyperpolarizability shows that the molecule is an attractive molecule for future applications in non-linear optics. The calculated HOMO and LUMO energies show that charge transfer occurs within these molecules. Mulliken population analysis on atomic charges is also calculated. Because of vibrational analyses, the thermodynamic properties of the title compound at different temperatures have been calculated. Finally, the UV-vis spectra and electronic absorption properties were explained and illustrated from the frontier molecular orbitals.

  15. Purely Functional Structured Programming

    OpenAIRE

    Obua, Steven

    2010-01-01

    The idea of functional programming has played a big role in shaping today's landscape of mainstream programming languages. Another concept that dominates the current programming style is Dijkstra's structured programming. Both concepts have been successfully married, for example in the programming language Scala. This paper proposes how the same can be achieved for structured programming and PURELY functional programming via the notion of LINEAR SCOPE. One advantage of this proposal is that m...

  16. Meshfree First-order System Least Squares

    Institute of Scientific and Technical Information of China (English)

    Hugh R.MacMillan; Max D.Gunzburger; John V.Burkardt

    2008-01-01

    We prove convergence for a meshfree first-order system least squares (FOSLS) partition of unity finite element method (PUFEM). Essentially, by virtue of the partition of unity, local approximation gives rise to global approximation in H(div)∩ H(curl). The FOSLS formulation yields local a posteriori error estimates to guide the judicious allotment of new degrees of freedom to enrich the initial point set in a meshfree dis-cretization. Preliminary numerical results are provided and remaining challenges are discussed.

  17. Optimum sensitivity derivatives of objective functions in nonlinear programming

    Science.gov (United States)

    Barthelemy, J.-F. M.; Sobieszczanski-Sobieski, J.

    1983-01-01

    The feasibility of eliminating second derivatives from the input of optimum sensitivity analyses of optimization problems is demonstrated. This elimination restricts the sensitivity analysis to the first-order sensitivity derivatives of the objective function. It is also shown that when a complete first-order sensitivity analysis is performed, second-order sensitivity derivatives of the objective function are available at little additional cost. An expression is derived whose application to linear programming is presented.

  18. Functional Programming in R

    DEFF Research Database (Denmark)

    Mailund, Thomas

    2017-01-01

    Master functions and discover how to write functional programs in R. In this book, you'll make your functions pure by avoiding side-effects; you’ll write functions that manipulate other functions, and you’ll construct complex functions using simpler functions as building blocks. In Functional...... functions by combining simpler functions. You will: Write functions in R including infix operators and replacement functions Create higher order functions Pass functions to other functions and start using functions as data you can manipulate Use Filer, Map and Reduce functions to express the intent behind...... code clearly and safely Build new functions from existing functions without necessarily writing any new functions, using point-free programming Create functions that carry data along with them...

  19. Magnetocaloric materials and first order phase transitions

    DEFF Research Database (Denmark)

    Neves Bez, Henrique

    of the properties of such materials.The experimental characterization of these materials is done through various different methods, such as X-ray diffraction, magnetometry, calorimetry, direct measurements of entropy change, capacitance dilatometry, scanning electron microscopy,energy-dispersive X-ray spectrometry......This thesis studies the first order phase transitions of the magnetocaloric materials La0.67Ca0.33MnO3 and La(Fe,Mn,Si)13Hz trying to overcome challenges that these materials face when applied in active magnetic regenerators. The study is done through experimental characterization and modelling...... and magnetocaloric regenerative tests. The magnetic, thermal and structural properties obtained from such measurements are then evaluated through different models, i.e. the Curie-Weiss law, the Bean-Rodbell model, the free electron model and the Debye model.The measured magnetocaloric properties of La0.67Ca0.33MnO3...

  20. First order gravity on the light front

    CERN Document Server

    Alexandrov, Sergei

    2014-01-01

    We study the canonical structure of the real first order formulation of general relativity on a null foliation. We use a tetrad decomposition which allows to elegantly encode the nature of the foliation in the norm of a vector in the fibre bundle. The resulting constraint structure shows some peculiarities. In particular, the dynamical Einstein equations propagating the physical degrees of freedom appear in this formalism as second class tertiary constraints, which puts them on the same footing as the Hamiltonian constraint of the Ashtekar's connection formulation. We also provide a framework to address the issue of zero modes in gravity, in particular, to study the non-perturbative fate of the zero modes of the linearized theory. Our results give a new angle on the dynamics of general relativity and can be used to quantize null hypersurfaces in the formalism of loop quantum gravity or spin foams.

  1. Total variation projection with first order schemes.

    Science.gov (United States)

    Fadili, Jalal M; Peyre, Gabriel

    2011-03-01

    This article proposes a new algorithm to compute the projection on the set of images whose total variation is bounded by a constant. The projection is computed through a dual formulation that is solved by first order non-smooth optimization methods. This yields an iterative algorithm that applies iterative soft thresholding to the dual vector field, and for which we establish convergence rate on the primal iterates. This projection algorithm can then be used as a building block in a variety of applications such as solving inverse problems under a total variation constraint, or for texture synthesis. Numerical results are reported to illustrate the usefulness and potential applicability of our TV projection algorithm on various examples including denoising, texture synthesis, inpainting, deconvolution and tomography problems. We also show that our projection algorithm competes favorably with state-of-the-art TV projection methods in terms of convergence speed.

  2. Multidimensional First-Order Dominance Comparisons of Population Wellbeing

    DEFF Research Database (Denmark)

    Siersbæk, Nikolaj; Østerdal, Lars Peter; Arndt, Channing

    2017-01-01

    This chapter conveys the concept of first-order dominance (FOD) with particular focus on applications to multidimensional population welfare comparisons. It gives an account of the fundamental equivalent definitions of FOD both in the one-dimensional and multidimensional setting, illustrated...... with simple numerical examples. An implementable method for detecting dominances that relies on linear programming is explained along with a bootstrapping procedure that yields additional information relative to what can be obtained from dominance comparisons alone. The chapter discusses strengths...

  3. A First-Order One-Pass CPS Transformation

    DEFF Research Database (Denmark)

    Danvy, Olivier; Nielsen, Lasse Reichstein

    2002-01-01

    We present a new transformation of call-by-value lambdaterms into continuation-passing style (CPS). This transformation operates in one pass and is both compositional and first-order. Because it operates in one pass, it directly yields compact CPS programs that are comparable to what one would...... write by hand. Because it is compositional, it allows proofs by structural induction. Because it is first-order, reasoning about it does not require the use of a logical relation. This new CPS transformation connects two separate lines of research. It has already been used to state a new and simpler...... correctness proof of a direct-style transformation, and to develop a new and simpler CPS transformation of control-flow information....

  4. First order formalism for the holographic duals of defect CFTs

    Energy Technology Data Exchange (ETDEWEB)

    Korovin, Yegor [KdV Institute for Mathematics, Institute for Theoretical Physics, Science Park 904, 1090 GL Amsterdam (Netherlands); School of Mathematical Sciences and STAG Research Centre, University of Southampton,Southampton SO17 1BJ (United Kingdom)

    2014-04-24

    We develop a first order formalism for constructing gravitational duals of conformal defects in a bottom up approach. Similarly as for the flat domain walls a single function specifies the solution completely. Using this formalism we construct several novel families of analytic solutions dual to conformal interfaces and boundaries. As a sample application we study the boundary OPE and entanglement entropy for one of the found defects.

  5. Monadic Functional Reactive Programming

    NARCIS (Netherlands)

    Ploeg, A.J. van der; Shan, C

    2013-01-01

    Functional Reactive Programming (FRP) is a way to program reactive systems in functional style, eliminating many of the problems that arise from imperative techniques. In this paper, we present an alternative FRP formulation that is based on the notion of a reactive computation: a monadic computatio

  6. Fast Computation of First-Order Feature-Bispectrum Corrections

    CERN Document Server

    Adshead, Peter

    2012-01-01

    Features in the inflaton potential that are traversed in much less than an e-fold of the expansion can produce observably large non-Gaussianity. In these models first order corrections to the curvature mode function evolution induce effects at second order in the slow roll parameters that are generically greater than ~ 10% and can reach order unity for order unity power spectrum features. From a complete first order expression in generalized slow-roll, we devise a computationally efficient method that is as simple to evaluate as the leading order one and implements consistency relations in a controlled fashion. This expression matches direct numerical computation for step potential models of the dominant bispectrum configurations to better than 1% when features are small and 10% when features are order unity.

  7. A first-order thermal model for building design

    Energy Technology Data Exchange (ETDEWEB)

    Mathews, E.H. [Centre for Experimental and Numerical Thermoflow, Univ. of Pretoria (South Africa); Richards, P.G. [Centre for Experimental and Numerical Thermoflow, Univ. of Pretoria (South Africa); Lombard, C. [Centre for Experimental and Numerical Thermoflow, Univ. of Pretoria (South Africa)

    1994-12-31

    Simplified thermal models of buildings can successfully be applied in building design. This paper describes the derivation and validation of a first-order thermal model which has a clear physical interpretation, is based on uncomplicated calculation procedures and requires limited input information. Because extensive simplifications and assumptions are inherent in the development of the model, a comprehensive validation study is reported. The validity of the thermal model was proven with 70 validation studies in 32 buildings comprising a wide range of thermal characteristics. The accuracy of predictions compares well with other sophisticated programs. The proposed model is considered to be eminently suitable for incorporation in an efficient design tool. (orig.)

  8. A first order system model of fracture healing

    Institute of Scientific and Technical Information of China (English)

    WANG Xiao-ping; ZHANG Xian-long; LI Zhu-guo; YU Xin-gang

    2005-01-01

    A first order system model is proposed for simulating the influence of stress stimulation on fracture strength during fracture healing. To validate the model, the diaphyses of bilateral tibiae in 70 New Zealand rabbits were osteotomized and fixed with rigid plates and stress-relaxation plates, respectively. Stress shielding rate and ultimate bending strength of the healing bone were measured at 2 to 48 weeks postoperatively. Ratios of stress stimulation and fracture strength of the healing bone to those of intact bone were taken as the system input and output. The assumed first order system model can approximate the experimental data on fracture strength from the input of stress stimulation over time, both for the rigid plate group and the stress-relaxation plate group, with different system parameters of time constant and gain. The fitting curve indicates that the effect of mechanical stimulus occurs mainly in late stages of healing. First order system can model the stress adaptation process of fracture healing. This approach presents a simple bio-mathematical model of the relationship between stress stimulation and fracture strength, and has the potential to optimize planning of functional exercises and conduct parametric studies.

  9. Functional Programming Using F#

    DEFF Research Database (Denmark)

    Hansen, Michael Reichhardt; Rischel, Hans

    This comprehensive introduction to the principles of functional programming using F# shows how to apply basic theoretical concepts to produce succinct and elegant programs. It demonstrates the role of functional programming in a wide spectrum of applications including databases and systems....... Coverage also includes advanced features in the .NET library, the imperative features of F# and topics such as text processing, sequences, computation expressions and asynchronous computation. With a broad spectrum of examples and exercises, the book is perfect for courses in functional programming...... and for self-study. Enhancing its use as a text is an accompanying website with downloadable programs, lecture slides, a mini-projects and links to further F# sources....

  10. Functional Programming Using F#

    DEFF Research Database (Denmark)

    Hansen, Michael Reichhardt; Rischel, Hans

    This comprehensive introduction to the principles of functional programming using F# shows how to apply basic theoretical concepts to produce succinct and elegant programs. It demonstrates the role of functional programming in a wide spectrum of applications including databases and systems....... Coverage also includes advanced features in the .NET library, the imperative features of F# and topics such as text processing, sequences, computation expressions and asynchronous computation. With a broad spectrum of examples and exercises, the book is perfect for courses in functional programming...... and for self-study. Enhancing its use as a text is an accompanying website with downloadable programs, lecture slides, a mini-projects and links to further F# sources....

  11. Natural Bond Orbital (NBO) Population Analysis, First Order Hyperpolarizabilities and Thermodynamic Properties of Cyclohexanone.

    Science.gov (United States)

    Gangadharan, Rubarani P; Krishnan, S Sampath

    2015-06-01

    The molecular structure of cyclohexanone was calculated by the B3LYP density functional model with 6-31G(d, p) and 6-311++G(d,p) basis set by Gaussian program. The results from natural bond orbital (NBO) analysis have been analyzed in terms of the hybridization of atoms and the electronic structure of the title molecule. The electron density based local reactivity descriptors such as Fukui functions were calculated. The dipole moment (μ) and polarizability (a), anisotropy polarizability (Δα) and first order hyperpolarizability (β(tot)) of the molecule have been reported. Thermodynamic properties of the title compound were calculated at different temperatures.

  12. Natural Bond Orbital (NBO) Population Analysis,First Order Hyperpolarizabilities and Thermodynamic Properties of Cyclohexanone

    Institute of Scientific and Technical Information of China (English)

    Rubarani P Gangadharan; S Sampat H Krishnan

    2015-01-01

    The molecular structure of cyclohexanone was calculated by the B3LYP density functional model with 6‐31G(d ,p) and 6‐311+ +G(d ,p) basis set by Gaussian program .The results from natural bond orbital (NBO) analysis have been analyzed in terms of the hybridization of atoms and the electronic structure of the ti‐tle molecule .The electron density based local reactivity descriptors such as Fukui functions were calculated . The dipole moment (μ) and polarizability (α) ,anisotropy polarizability (Δα) and first order hyperpolarizability (βtot ) of the molecule have been reported .Thermodynamic properties of the title compound were calculated at different temperatures .

  13. Axiomatization of Special Relativity in First Order Logic

    Science.gov (United States)

    Luo, Yi-Chen; Chen, Lei; He, Wan-Ting; Ma, Yong-Ge; Zhang, Xin-Yu

    2016-07-01

    The axiomatization of physical theories is a fundamental issue of science. The first-order axiomatic system SpecRel for special relativity proposed recently by Andréka et al. is not enough to explain all the main results in the theory, including the twin paradox and energy-mass relation. In this paper, from a four-dimensional space-time perspective, we introduce the concepts of world-line, proper time and four-momentum to our axiomatic system SpecRel+. Then we introduce an axiom of mass (AxMass) and take four-momentum conservation as an axiom (AxCFM) in SpecRel+. It turns out that the twin paradox and energy-mass relation can be derived from SpecRel+ logically. Hence, as an extension of SpecRel, SpecRel+ is a suitable first-order axiomatic system to describe the kinematics and dynamics of special relativity. Supported by the National Science Foundation of China under Grant Nos. 11235003 and 11475023, National Social Sciences Foundation of China under Grant No. 14BZX078 and the Research Fund for the Doctoral Program of Higher Education of China, and the Undergraduate Training Program of Beijing

  14. The Monte Carlo Program KoralW version 1.51 and The Concurrent Monte Carlo KoralW\\&YFSWW3 with All Background Graphs and First Order Corrections to W-Pair Production

    CERN Document Server

    Jadach, Stanislaw; Skrzypek, Maciej; Ward, B F L; Was, Zbigniew

    2001-01-01

    The version 1.51 of the Monte Carlo (MC) program KoralW for all $e^+e^-\\to f_1\\bar f_2 f_3\\bar f_4$ processes is presented. The most important change since the previous version 1.42 is the facility for writing MC events on the mass storage device and re-processing them later on. In the re-processing one may modify parameters of the Standard Model in order to fit them to experimental data. Another important new feature is a possibility of including complete ${\\cal O}(\\alpha)$ corrections to double-resonant W-pair component-processes in addition to all background (non-WW) graphs. The inclusion is done with the help of the YFSWW3 MC event generator for fully exclusive differential distributions (event-per-event). Technically, it is done in such a way that YFSWW3 runs concurrently with KoralW as a separate slave process, reading momenta of the MC event generated by KoralW and returning the correction weight to KoralW. KoralW introduces the ${\\cal O}(\\alpha)$ correction using this weight, and finishes processing t...

  15. EXACT AND ADIABATIC INVARIANTS OF FIRST-ORDER LAGRANGE SYSTEMS

    Institute of Scientific and Technical Information of China (English)

    陈向炜; 尚玫; 梅凤翔

    2001-01-01

    A system of first-order differential equations is expressed in the form of first-order Lagrange equations. Based on the theory of symmetries and conserved quantities of first-order Lagrange systems, the perturbation to the symmetries and adiabatic invariants of first-order Lagrange systems are discussed. Firstly, the concept of higher-order adiabatic invariants of the first-order Lagrange system is proposed. Then, conditions for the existence of the exact and adiabatic invariants are proved, and their forms are given. Finally, an example is presented to illustrate these results.

  16. Constraint Propagation for Extended First-Order Logic

    CERN Document Server

    Wittocx, Johan; Bruynooghe, Maurice

    2010-01-01

    Constraint propagation is one of the basic forms of inference in many logic-based reasoning systems. In this paper, we investigate constraint propagation for first-order logic (FO), a suitable language to express a wide variety of constraints. We present an algorithm with polynomial time data-complexity for constraint propagation in the context of an FO theory and a finite structure. We show that constraint propagation in this manner can be represented by a datalog program and that the algorithm can be executed symbolically, i.e., independent of a finite structure. Next, we extend the algorithm to an extension of FO with inductive definitions and aggregates. Finally, we discuss several applications.

  17. Optimization Based Efficiencies in First Order Reliability Analysis

    Science.gov (United States)

    Peck, Jeffrey A.; Mahadevan, Sankaran

    2003-01-01

    This paper develops a method for updating the gradient vector of the limit state function in reliability analysis using Broyden's rank one updating technique. In problems that use commercial code as a black box, the gradient calculations are usually done using a finite difference approach, which becomes very expensive for large system models. The proposed method replaces the finite difference gradient calculations in a standard first order reliability method (FORM) with Broyden's Quasi-Newton technique. The resulting algorithm of Broyden updates within a FORM framework (BFORM) is used to run several example problems, and the results compared to standard FORM results. It is found that BFORM typically requires fewer functional evaluations that FORM to converge to the same answer.

  18. Kinetics of first-order phase transitions with correlated nuclei

    Science.gov (United States)

    Rickman, J. M.; Barmak, K.

    2017-02-01

    We demonstrate that the time evolution of a first-order phase transition may be described quite generally in terms of the statistics of point processes, thereby providing an intuitive framework for visualizing transition kinetics. A number of attractive and repulsive nucleation scenarios is examined followed by isotropic domain growth at a constant rate This description holds for both uncorrelated and correlated nuclei, and may be employed to calculate the nonequilibrium, n -point spatiotemporal correlations that characterize the transition. Furthermore, it is shown that the interpretation of the one-point function in terms of a stretched-exponential, Kolmogorov-Johnson-Mehl-Avrami result is problematic in the case of correlated nuclei, but that the calculation of higher-order correlation functions permits one to distinguish among various nucleation scenarios.

  19. Field Method for Integrating the First Order Differential Equation

    Institute of Scientific and Technical Information of China (English)

    JIA Li-qun; ZHENG Shi-wang; ZHANG Yao-yu

    2007-01-01

    An important modern method in analytical mechanics for finding the integral, which is called the field-method, is used to research the solution of a differential equation of the first order. First, by introducing an intermediate variable, a more complicated differential equation of the first order can be expressed by two simple differential equations of the first order, then the field-method in analytical mechanics is introduced for solving the two differential equations of the first order. The conclusion shows that the field-method in analytical mechanics can be fully used to find the solutions of a differential equation of the first order, thus a new method for finding the solutions of the first order is provided.

  20. Molecular structure, spectroscopic (FT-IR, FT-Raman, NMR, UV) studies and first-order molecular hyperpolarizabilities of 1,2-bis(3-methoxy-4-hydroxybenzylidene)hydrazine by density functional method

    Science.gov (United States)

    Subramanian, N.; Sundaraganesan, N.; Jayabharathi, J.

    2010-07-01

    Quantum chemical calculations of energies, geometrical structure and vibrational wavenumbers of 1,2-bis(3-methoxy-4-hydroxybenzylidene)hydrazine [vanillin azine (VA)] were carried out by using density functional (DFT/B3LYP) method with 6-31G(d) as basis set. The optimized geometrical parameters obtained by DFT calculations are in good agreement with single crystal XRD data. The vibrational spectral data obtained from solid phase FT-IR and FT-Raman spectra are assigned based on the results of the theoretical calculations. The observed spectra are found to be in good agreement with calculated values. The electric dipole moment ( μ) and the first hyperpolarizability ( β) values of the investigated molecule have been computed using ab initio quantum mechanical calculations. The calculation results also show that the VA molecule might have microscopic nonlinear optical (NLO) behavior with non-zero values. A detailed interpretation of the infrared and Raman spectra of VA was also reported. The energy and oscillator strength calculated by time-dependent density functional theory (TD-DFT) results complements with the experimental findings. The calculated HOMO and LUMO energies show that charge transfer occurs within the molecule. The theoretical NMR chemical shifts complement with experimentally measured ones.

  1. Renormalization group analysis of the random first-order transition.

    Science.gov (United States)

    Cammarota, Chiara; Biroli, Giulio; Tarzia, Marco; Tarjus, Gilles

    2011-03-18

    We consider the approach describing glass formation in liquids as a progressive trapping in an exponentially large number of metastable states. To go beyond the mean-field setting, we provide a real-space renormalization group (RG) analysis of the associated replica free-energy functional. The present approximation yields in finite dimensions an ideal glass transition similar to that found in the mean field. However, we find that along the RG flow the properties associated with metastable glassy states, such as the configurational entropy, are only defined up to a characteristic length scale that diverges as one approaches the ideal glass transition. The critical exponents characterizing the vicinity of the transition are the usual ones associated with a first-order discontinuity fixed point.

  2. Dynamic finite-size scaling at first-order transitions

    Science.gov (United States)

    Pelissetto, Andrea; Vicari, Ettore

    2017-07-01

    We investigate the dynamic behavior of finite-size systems close to a first-order transition (FOT). We develop a dynamic finite-size scaling (DFSS) theory for the dynamic behavior in the coexistence region where different phases coexist. This is characterized by an exponentially large time scale related to the tunneling between the two phases. We show that, when considering time scales of the order of the tunneling time, the dynamic behavior can be described by a two-state coarse-grained dynamics. This allows us to obtain exact predictions for the dynamical scaling functions. To test the general DFSS theory at FOTs, we consider the two-dimensional Ising model in the low-temperature phase, where the external magnetic field drives a FOT, and the 20-state Potts model, which undergoes a thermal FOT. Numerical results for a purely relaxational dynamics fully confirm the general theory.

  3. Synthesis, structural, spectral (FT-IR, 1H and 13C NMR and UV-Vis), NBO and first order hyperpolarizability analysis of N-(4-nitrophenyl)-2, 2-dibenzoylacetamide by density functional theory

    Science.gov (United States)

    Yalçın, Şerife Pınar; Ceylan, Ümit; Sarıoğlu, Ahmet Oral; Sönmez, Mehmet; Aygün, Muhittin

    2015-10-01

    The title compound, C22H16N2O5, was synthesized and characterized by experimental techniques (FT-IR, 1H NMR, 13C NMR, UV-Vis and X-Ray single crystal determination) and theoretical calculations. The molecular geometry, vibrational frequencies, molecular electrostatic potential (MEP), thermodynamic properties, the dipole moments, HOMO-LUMO energy has been calculated by using the Density Functional Theory (DFT) method with 6-311G(d,p) and 6-311++G(d,p) basis sets. 1H and 13C NMR chemical shifts show good agreement with experimental values. According to calculated results, the 6-311G(d,p) and 6-311++G(d,p) basis sets have showed similar results. The optimized geometry can well reproduce the crystal structure parameters.

  4. A first-order Lyapunov robustness method for linear systems with uncertain parameters

    Science.gov (United States)

    Leal, M. A.; Gibson, J. S.

    1990-01-01

    A method for stability-robustness analysis based on a quadratic Liapunov function that varies linearly with uncertainty parameters is derived. Linear time-invariant systems with structured uncertainties are discussed. The Liapunov function is optimized numerically to maximize the robustness region in parameter space. Numerical results are given for four examples in which the first-order method is compared to previous Liapunov methods. While the zero-order method is slightly better than the first-order method for one example, the first-order method is clearly superior in the other three (more realistic) examples. The first-order method is especially superior for the active control of flexible structures, where robustness with respect to (1) unmodeled coupling between modeled modes and (2) unmodeled modes is important. For such applications, the first-order method is much better at detecting the increased robustness associated with increased separation between frequencies.

  5. A first-order Lyapunov robustness method for linear systems with uncertain parameters

    Science.gov (United States)

    Leal, M. A.; Gibson, J. S.

    1990-01-01

    A method for stability-robustness analysis based on a quadratic Liapunov function that varies linearly with uncertainty parameters is derived. Linear time-invariant systems with structured uncertainties are discussed. The Liapunov function is optimized numerically to maximize the robustness region in parameter space. Numerical results are given for four examples in which the first-order method is compared to previous Liapunov methods. While the zero-order method is slightly better than the first-order method for one example, the first-order method is clearly superior in the other three (more realistic) examples. The first-order method is especially superior for the active control of flexible structures, where robustness with respect to (1) unmodeled coupling between modeled modes and (2) unmodeled modes is important. For such applications, the first-order method is much better at detecting the increased robustness associated with increased separation between frequencies.

  6. Testing First-Order Logic Axioms in AutoCert

    Science.gov (United States)

    Ahn, Ki Yung; Denney, Ewen

    2009-01-01

    AutoCert [2] is a formal verification tool for machine generated code in safety critical domains, such as aerospace control code generated from MathWorks Real-Time Workshop. AutoCert uses Automated Theorem Provers (ATPs) [5] based on First-Order Logic (FOL) to formally verify safety and functional correctness properties of the code. These ATPs try to build proofs based on user provided domain-specific axioms, which can be arbitrary First-Order Formulas (FOFs). These axioms are the most crucial part of the trusted base, since proofs can be submitted to a proof checker removing the need to trust the prover and AutoCert itself plays the part of checking the code generator. However, formulating axioms correctly (i.e. precisely as the user had really intended) is non-trivial in practice. The challenge of axiomatization arise from several dimensions. First, the domain knowledge has its own complexity. AutoCert has been used to verify mathematical requirements on navigation software that carries out various geometric coordinate transformations involving matrices and quaternions. Axiomatic theories for such constructs are complex enough that mistakes are not uncommon. Second, adjusting axioms for ATPs can add even more complexity. The axioms frequently need to be modified in order to have them in a form suitable for use with ATPs. Such modifications tend to obscure the axioms further. Thirdly, speculating validity of the axioms from the output of existing ATPs is very hard since theorem provers typically do not give any examples or counterexamples.

  7. A First-Order One-Pass CPS Transformation

    DEFF Research Database (Denmark)

    Danvy, Olivier; Nielsen, Lasse Reichstein

    2001-01-01

    We present a new transformation of λ-terms into continuation-passing style (CPS). This transformation operates in one pass and is both compositional and first-order. Previous CPS transformations only enjoyed two out of the three properties of being first-order, one-pass, and compositional...

  8. A First-Order One-Pass CPS Transformation

    DEFF Research Database (Denmark)

    Danvy, Olivier; Nielsen, Lasse Reichstein

    2003-01-01

    We present a new transformation of λ-terms into continuation-passing style (CPS). This transformation operates in one pass and is both compositional and first-order. Previous CPS transformations only enjoyed two out of the three properties of being first-order, one-pass, and compositional...

  9. Gravitational waves from first-order cosmological phase transitions

    Science.gov (United States)

    Kosowsky, Arthur; Turner, Michael S.; Watkins, Richard

    1992-01-01

    A first-order cosmological phase transition that proceeds through the nucleation and collision of true-vacuum bubbles is a potent source of gravitational radiation. Possibilities for such include first-order inflation, grand-unified-theory-symmetry breaking, and electroweak-symmetry breaking. We have calculated gravity-wave production from the collision of two scalar-field vacuum bubbles, and, using an approximation based upon these results, from the collision of 20 to 30 vacuum bubbles. We present estimates of the relic background of gravitational waves produced by a first-order phase transition.

  10. The computation of first order moments on junction trees

    CERN Document Server

    Djuric, Milos B; Stankovic, Miomir S

    2012-01-01

    We review some existing methods for the computation of first order moments on junction trees using Shafer-Shenoy algorithm. First, we consider the problem of first order moments computation as vertices problem in junction trees. In this way, the problem is solved using the memory space of an order of the junction tree edge-set cardinality. After that, we consider two algorithms, Lauritzen-Nilsson algorithm, and Mau\\'a et al. algorithm, which computes the first order moments as the normalization problem in junction tree, using the memory space of an order of the junction tree leaf-set cardinality.

  11. Innovative first order elimination kinetics working model for easy learning

    Directory of Open Access Journals (Sweden)

    Navin Budania

    2016-06-01

    Conclusions: First order elimination kinetics is easily understood with the help of above working model. More and more working models could be developed for teaching difficult topics. [Int J Basic Clin Pharmacol 2016; 5(3.000: 862-864

  12. Quantifier hierarchies over the first-Order definable tree languages

    Institute of Scientific and Technical Information of China (English)

    沈云付

    1996-01-01

    Using Boolean operations and concatenation product w.r.t special trees,quantifier hierarchies are given by way of alternate existential and universal quantifiers for the first-order definable tree languages.

  13. First-order partial differential equations in classical dynamics

    Science.gov (United States)

    Smith, B. R.

    2009-12-01

    Carathèodory's classic work on the calculus of variations explores in depth the connection between ordinary differential equations and first-order partial differential equations. The n second-order ordinary differential equations of a classical dynamical system reduce to a single first-order differential equation in 2n independent variables. The general solution of first-order partial differential equations touches on many concepts central to graduate-level courses in analytical dynamics including the Hamiltonian, Lagrange and Poisson brackets, and the Hamilton-Jacobi equation. For all but the simplest dynamical systems the solution requires one or more of these techniques. Three elementary dynamical problems (uniform acceleration, harmonic motion, and cyclotron motion) can be solved directly from the appropriate first-order partial differential equation without the use of advanced methods. The process offers an unusual perspective on classical dynamics, which is readily accessible to intermediate students who are not yet fully conversant with advanced approaches.

  14. Optimal value functions of generalized semi-infinite min-max programming on a noncompact set

    Institute of Scientific and Technical Information of China (English)

    WANG; Changyu; YANG; Xiaoqi; YANG; Xinmin

    2005-01-01

    In this paper, we study optimal value functions of generalized semi-infinite min-max programming problems on a noncompact set. Directional derivatives and subdifferential characterizations of optimal value functions are given. Using these properties,we establish first order optimality conditions for unconstrained generalized semi-infinite programming problems.

  15. First-order study of property/composition relationships for Hanford Waste Vitrification Plant glasses

    Energy Technology Data Exchange (ETDEWEB)

    Piepel, G.F.; Hrma, P.R.; Bates, S.O.; Schweiger, M.J.; Smith, D.E.

    1993-01-01

    A first-order composition variability study (CVS-I) was conducted for the Hanford Waste Vitrification Plant (HWVP) program to preliminarily characterize the effects on key glass properties of variations i selected glass (waste and frit) components. The components selected were Si0{sub 2},B{sub 2}O{sub 3},A1{sub 2}O{sub 3}, Fe{sub 2}O{sub 3}, ZrO{sub 2}, Na{sub 2}O,Li{sub 2}O,CaO,MgO, and Others (all remaining waste components). A glass composition region was selected for study based on the expected range of glass compositions and the results of a previous series of scoping and solubility studies. Then, a 23-glass statistically-designed mixture experiment was conducted and data obtained for viscosity, electrical conductivity, glass transition temperature, thermal expansion, crystallinity, and durability [Materials Characterization Center (MCC-1) 28-day leach test and the 7-day Product Consistency Test (PCT)]. These data were modeled using first-order functions of composition, and the models were used to investigate the effects of the components on glass and melt properties. The CVS-I data and models will also be used to support the second-order composition variability study (CVS-II).

  16. First-order study of property/composition relationships for Hanford Waste Vitrification Plant glasses

    Energy Technology Data Exchange (ETDEWEB)

    Piepel, G.F.; Hrma, P.R.; Bates, S.O.; Schweiger, M.J.; Smith, D.E.

    1993-01-01

    A first-order composition variability study (CVS-I) was conducted for the Hanford Waste Vitrification Plant (HWVP) program to preliminarily characterize the effects on key glass properties of variations i selected glass (waste and frit) components. The components selected were Si0[sub 2],B[sub 2]O[sub 3],A1[sub 2]O[sub 3], Fe[sub 2]O[sub 3], ZrO[sub 2], Na[sub 2]O,Li[sub 2]O,CaO,MgO, and Others (all remaining waste components). A glass composition region was selected for study based on the expected range of glass compositions and the results of a previous series of scoping and solubility studies. Then, a 23-glass statistically-designed mixture experiment was conducted and data obtained for viscosity, electrical conductivity, glass transition temperature, thermal expansion, crystallinity, and durability [Materials Characterization Center (MCC-1) 28-day leach test and the 7-day Product Consistency Test (PCT)]. These data were modeled using first-order functions of composition, and the models were used to investigate the effects of the components on glass and melt properties. The CVS-I data and models will also be used to support the second-order composition variability study (CVS-II).

  17. First-order Nilpotent Minimum Logics: first steps

    CERN Document Server

    Bianchi, Matteo

    2011-01-01

    First-order Nilpotent Minimum Logic was introduced in [EG01]; in [Gis03] it is showed that every finite NM-chain with negation fixpoint is complete w.r.t. the logic NM. In this paper we will show that this last result, in the first-order case, does not hold. We will study the sets of first-order tautologies of some subalgebras of [0,1]_NM: in particular finite NM-chains and other four infinite NM-chains (with and without negation fixpoint). Moreover we will find a connection between the validity, in an NM-chain, of certain first-order formulas and its order type. Finally, we will analyze axiomatization, undecidability and the monadic fragments. We will conclude with some remarks, future directions of research and open problems. This paper has been inspired by the work done, for first-order G\\"odel logic, in [BPZ07] and [BCF07]: when possible, we will point out the analogies and the differences with the G\\"odel's case.

  18. Geometry of Lagrangian First-order Classical Field Theories

    CERN Document Server

    Echeverría-Enríquez, A; Román-Roy, N; Echeverr\\'ia-Enr\\'iquez, Arturo; Muñoz-Lecanda, Miguel C.; Román-Roy, Narciso

    1996-01-01

    We construct a lagrangian geometric formulation for first-order field theories using the canonical structures of first-order jet bundles, which are taken as the phase spaces of the systems in consideration. First of all, we construct all the geometric structures associated with a first-order jet bundle and, using them, we develop the lagrangian formalism, defining the canonical forms associated with a lagrangian density and the density of lagrangian energy, obtaining the {\\sl Euler-Lagrange equations} in two equivalent ways: as the result of a variational problem and developing the {\\sl jet field formalism} (which is a formulation more similar to the case of mechanical systems). A statement and proof of Noether's theorem is also given, using the latter formalism. Finally, some classical examples are briefly studied.

  19. Gravitational waves from cosmological first order phase transitions

    CERN Document Server

    Hindmarsh, Mark; Rummukainen, Kari; Weir, David

    2015-01-01

    First order phase transitions in the early Universe generate gravitational waves, which may be observable in future space-based gravitational wave observatiories, e.g. the European eLISA satellite constellation. The gravitational waves provide an unprecedented direct view of the Universe at the time of their creation. We study the generation of the gravitational waves during a first order phase transition using large-scale simulations of a model consisting of relativistic fluid and an order parameter field. We observe that the dominant source of gravitational waves is the sound generated by the transition, resulting in considerably stronger radiation than earlier calculations have indicated.

  20. Formalization of the Resolution Calculus for First-Order Logic

    DEFF Research Database (Denmark)

    Schlichtkrull, Anders

    2016-01-01

    A formalization in Isabelle/HOL of the resolution calculus for first-order logic is presented. Its soundness and completeness are formally proven using the substitution lemma, semantic trees, Herbrand’s theorem, and the lifting lemma. In contrast to previous formalizations of resolution, it consi......A formalization in Isabelle/HOL of the resolution calculus for first-order logic is presented. Its soundness and completeness are formally proven using the substitution lemma, semantic trees, Herbrand’s theorem, and the lifting lemma. In contrast to previous formalizations of resolution...

  1. Equivalent linearization finds nonzero frequency corrections beyond first order

    CERN Document Server

    Chattopadhyay, Rohitashwa

    2016-01-01

    We show that the equivalent linearization technique, when used properly, enables us to calculate frequency corrections of weakly nonlinear oscillators beyond the first order in nonliearity. We illustrate the method by applying it to the cubic anharmonic oscillator and the Van der Pol oscillator that are respectively paradigmatic systems for modeling center-type oscillatory states and limit cycle type oscillatory states. The choice of these systems is also prompted by the fact that first order frequency corrections vanish for both these oscillators, thereby rendering the calculation of the higher order corrections rather important. The method presented herein is very general in nature and, hence, in principle applicable to any arbitrary periodic oscillator.

  2. Exploring first-order phase transitions with population annealing

    Science.gov (United States)

    Barash, Lev Yu.; Weigel, Martin; Shchur, Lev N.; Janke, Wolfhard

    2017-03-01

    Population annealing is a hybrid of sequential and Markov chain Monte Carlo methods geared towards the efficient parallel simulation of systems with complex free-energy landscapes. Systems with first-order phase transitions are among the problems in computational physics that are difficult to tackle with standard methods such as local-update simulations in the canonical ensemble, for example with the Metropolis algorithm. It is hence interesting to see whether such transitions can be more easily studied using population annealing. We report here our preliminary observations from population annealing runs for the two-dimensional Potts model with q > 4, where it undergoes a first-order transition.

  3. An Analysis of the First Order Form of Gauge Theories

    CERN Document Server

    Kiriushcheva, N; McKeon, D G C

    2011-01-01

    The first order form of a Maxwell theory and U(1) gauge theory in which a gauge invariant mass term appears is analyzed using the Dirac procedure. The form of the gauge transformation which leaves the action invariant is derived from the constraints present. A non-Abelian generalization is similarly analyzed. This first order three dimensional massive gauge theory is rewritten in terms of two interacting vector fields. The constraint structure when using light-cone coordinates is considered. The relationship between first and second order forms of the two-dimensional Einstein-Hilbert action is explored where a Lagrange multiplier is used to ensure their equivalence.

  4. First-order Convex Optimization Methods for Signal and Image Processing

    DEFF Research Database (Denmark)

    Jensen, Tobias Lindstrøm

    2012-01-01

    In this thesis we investigate the use of first-order convex optimization methods applied to problems in signal and image processing. First we make a general introduction to convex optimization, first-order methods and their iteration complexity. Then we look at different techniques, which can...... be used with first-order methods such as smoothing, Lagrange multipliers and proximal gradient methods. We continue by presenting different applications of convex optimization and notable convex formulations with an emphasis on inverse problems and sparse signal processing. We also describe the multiple......-description problem. We finally present the contributions of the thesis. The remaining parts of the thesis consist of five research papers. The first paper addresses non-smooth first-order convex optimization and the trade-off between accuracy and smoothness of the approximating smooth function. The second and third...

  5. Functional Programming in Computer Science

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, Loren James [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Davis, Marion Kei [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-01-19

    We explore functional programming through a 16-week internship at Los Alamos National Laboratory. Functional programming is a branch of computer science that has exploded in popularity over the past decade due to its high-level syntax, ease of parallelization, and abundant applications. First, we summarize functional programming by listing the advantages of functional programming languages over the usual imperative languages, and we introduce the concept of parsing. Second, we discuss the importance of lambda calculus in the theory of functional programming. Lambda calculus was invented by Alonzo Church in the 1930s to formalize the concept of effective computability, and every functional language is essentially some implementation of lambda calculus. Finally, we display the lasting products of the internship: additions to a compiler and runtime system for the pure functional language STG, including both a set of tests that indicate the validity of updates to the compiler and a compiler pass that checks for illegal instances of duplicate names.

  6. Multidimensional first-order dominance comparisons of population wellbeing

    DEFF Research Database (Denmark)

    Arndt, Thomas Channing; Siersbæk, Nikolaj; Østerdal, Lars Peter Raahave

    In this paper, we convey the concept of first-order dominance (FOD) with particular focus on applications to multidimensional population welfare comparisons. We give an account of the fundamental equivalent definitions of FOD, illustrated with simple numerical examples. An implementable method fo...

  7. The Resolution Calculus for First-Order Logic

    DEFF Research Database (Denmark)

    Schlichtkrull, Anders

    2016-01-01

    This theory is a formalization of the resolution calculus for first-order logic. It is proven sound and complete. The soundness proof uses the substitution lemma, which shows a correspondence between substitutions and updates to an environment. The completeness proof uses semantic trees, i.e. trees...

  8. Oscillation criteria for first-order forced nonlinear difference equations

    OpenAIRE

    Grace Said R; Agarwal Ravi P.; Smith Tim

    2006-01-01

    Some new criteria for the oscillation of first-order forced nonlinear difference equations of the form Δx(n)+q1(n)xμ(n+1) = q2(n)xλ(n+1)+e(n), where λ, μ are the ratios of positive odd integers 0 <μ < 1 and λ > 1, are established.

  9. Probabilistic peak detection for first-order chromatographic data

    NARCIS (Netherlands)

    Lopatka, M.; Vivó-Truyols, G.; Sjerps, M.J.

    2014-01-01

    We present a novel algorithm for probabilistic peak detection in first-order chromatographic data. Unlike conventional methods that deliver a binary answer pertaining to the expected presence or absence of a chromatographic peak, our method calculates the probability of a point being affected by suc

  10. Code Generation for a Simple First-Order Prover

    DEFF Research Database (Denmark)

    Villadsen, Jørgen; Schlichtkrull, Anders; Halkjær From, Andreas

    2016-01-01

    We present Standard ML code generation in Isabelle/HOL of a sound and complete prover for first-order logic, taking formalizations by Tom Ridge and others as the starting point. We also define a set of so-called unfolding rules and show how to use these as a simple prover, with the aim of using...

  11. Landau Theory in the Region of First Order Phase Transitions

    Directory of Open Access Journals (Sweden)

    O.G. Medvedovskaya

    2014-04-01

    Full Text Available For the case when the line of the first order phase transitions does not transform into the line of the second order phase transitions, i.e. not as ends with the tricritical point but not with a critical one: critical lines, limiting the region of metastable states, by using the Landau theory of phase transitions were determined.

  12. First Order Actions for New Massive Dual Gravities

    CERN Document Server

    Bracho, Alexangel

    2013-01-01

    We present a first order formulation for the fourth order action of the new massive dual gravity in four dimensions. This proposal is easily generalized to arbitrary dimension. Also, we obtain the dual actions for massless and massive Curtright fields in D dimensions.

  13. Studies on magnetic-field-induced first-order transitions

    Indian Academy of Sciences (India)

    P Chaddah

    2006-07-01

    We shall discuss magnetization and transport measurements in materials exhibiting a broad first-order transition. The phase transitions would be caused by varying magnetic field as well as temperature, and we concentrate on ferro- to antiferromagnetic transitions in magnetic materials. We distinguish between metastable supercooled phases and metastable glassy phase.

  14. MAGNETIC FIELD INDUCED FIRST-ORDER TRANSITIONS IN DYSPROSIUM ORTHOFERRITE

    OpenAIRE

    Eremenko, V.; Gnatchenko, S.; Kharchenko, N.; Lebedev, P.; Piotrowski, K; Szymczak, H.; Szymczak, R.

    1988-01-01

    New type of magnetic first-order phase transition induced by external magnetic field applied in the ab-plane in DyFeO3 is investigated using different magnetooptic techniques. The phenomenological model of this transition is proposed. The phase diagram in H-T plane has been obtained for various H orientation in the ab-plane.

  15. Methylmercury toxicity and functional programming

    DEFF Research Database (Denmark)

    Grandjean, Philippe

    2007-01-01

    PURPOSE: Adverse health effects of developmental toxicants may induce abnormal functional programming that leads to lasting functional deficits. This notion is considered from epidemiological evidence using developmental methylmercury neurotoxicity as an example. MOST IMPORTANT FINDINGS...... of certain brain functions, thereby causing confounding bias. The functional deficits caused by prenatal methylmercury exposure appear to be permanent, and their extent may depend on the joint effect of toxicants and nutrients. PRINCIPAL CONCLUSIONS: The lasting functional changes caused...... by neurodevelopmental methylmercury toxicity fit into the pattern of functional programming, with effects opposite to those linked to beneficial stimuli....

  16. FIRST-ORDER METHODS FOR SOLVING THE OPTIMAL STATIC H∞-SYNTHESIS PROBLEM

    Institute of Scientific and Technical Information of China (English)

    EI-Sayed M.E. Mostafa

    2007-01-01

    In this paper, we consider the static output feedback (SOF) H∞-synthesis problem posed as a nonlinear semi-definite programming (NSDP) problem. Two numerical algorithms are developed to tackle the NSDP problem by solving the corresponding KarushKuhn-Tucker first-order necessary optimality conditions iteratively. Numerical results for various benchmark problems illustrating the performance of the proposed methods are given.

  17. Equivalent linearization finds nonzero frequency corrections beyond first order

    Science.gov (United States)

    Chattopadhyay, Rohitashwa; Chakraborty, Sagar

    2017-06-01

    We show that the equivalent linearization technique, when used properly, enables us to calculate frequency corrections of weakly nonlinear oscillators beyond the first order in nonlinearity. We illustrate the method by applying it to the conservative anharmonic oscillators and the nonconservative van der Pol oscillator that are respectively paradigmatic systems for modeling center-type oscillatory states and limit cycle type oscillatory states. The choice of these systems is also prompted by the fact that first order frequency corrections may vanish for both these types of oscillators, thereby rendering the calculation of the higher order corrections rather important. The method presented herein is very general in nature and, hence, in principle applicable to any arbitrary periodic oscillator.

  18. First-order asymptotic corrections to the meanfield limit

    Energy Technology Data Exchange (ETDEWEB)

    Christandl, Matthias [Institute for Theoretical Physics, ETH Zuerich, Wolfgang-Pauli-Strasse 27, CH-8093 Zuerich (Switzerland); Matjeschk, Robert; Werner, Reinhard [Leibniz Universitaet Hannover (Germany); Trimborn, Friederike [Leibniz Universitaet Hannover (Germany); Bundesministerium fuer Bildung und Forschung (Germany)

    2014-07-01

    We derive a complete algebraic theory for treating permutation invariant problems beyond separability to first order in the asymptotics. Our work builds on a C{sup *}-algebraic theory for permutation invariant operators on n-particles, with an algebraic description of the limit n→∞ (the mean-field limit). We use the fluctuation ansatz, a version of a non-commutative central limit, and derive a continuous-variable algebra (the fluctuation algebra) that asymptotically describes the 1/n-corrections to this meanfield limit. Using the fluctuation algebra, we derive a method for estimating the ground-state energy of mean-field models up to first order, and for estimating the time-evolution of correlations between different particles. Moreover, we show that the mean-field ground-state problem is closely related to the finite de Finetti problem and therefore obtain a lower bound, complementing recent results in this direction.

  19. A First-Order One-Pass CPS Transformation

    DEFF Research Database (Denmark)

    Danvy, Olivier; Nielsen, Lasse Reichstein

    2001-01-01

    We present a new transformation of λ-terms into continuation-passing style (CPS). This transformation operates in one pass and is both compositional and first-order. Previous CPS transformations only enjoyed two out of the three properties of being first-order, one-pass, and compositional......, but the new transformation enjoys all three properties. It is proved correct directly by structural induction over source terms instead of indirectly with a colon translation, as in Plotkin's original proof. Similarly, it makes it possible to reason about CPS-transformed terms by structural induction over...... source terms, directly.The new CPS transformation connects separately published approaches to the CPS transformation. It has already been used to state a new and simpler correctness proof of a direct-style transformation, and to develop a new and simpler CPS transformation of control-flow information....

  20. A First-Order One-Pass CPS Transformation

    DEFF Research Database (Denmark)

    Danvy, Olivier; Nielsen, Lasse Reichstein

    2003-01-01

    We present a new transformation of λ-terms into continuation-passing style (CPS). This transformation operates in one pass and is both compositional and first-order. Previous CPS transformations only enjoyed two out of the three properties of being first-order, one-pass, and compositional......, but the new transformation enjoys all three properties. It is proved correct directly by structural induction over source terms instead of indirectly with a colon translation, as in Plotkin's original proof. Similarly, it makes it possible to reason about CPS-transformed terms by structural induction over...... source terms, directly.The new CPS transformation connects separately published approaches to the CPS transformation. It has already been used to state a new and simpler correctness proof of a direct-style transformation, and to develop a new and simpler CPS transformation of control-flow information....

  1. Gravitational radiation from first-order phase transitions

    Energy Technology Data Exchange (ETDEWEB)

    Child, Hillary L.; Giblin, John T. Jr., E-mail: childh@kenyon.edu, E-mail: giblinj@kenyon.edu [Department of Physics, Kenyon College, 201 North College Road, Gambier, OH 43022 (United States)

    2012-10-01

    It is believed that first-order phase transitions at or around the GUT scale will produce high-frequency gravitational radiation. This radiation is a consequence of the collisions and coalescence of multiple bubbles during the transition. We employ high-resolution lattice simulations to numerically evolve a system of bubbles using only scalar fields, track the anisotropic stress during the process and evolve the metric perturbations associated with gravitational radiation. Although the radiation produced during the bubble collisions has previously been estimated, we find that the coalescence phase enhances this radiation even in the absence of a coupled fluid or turbulence. We comment on how these simulations scale and propose that the same enhancement should be found at the Electroweak scale; this modification should make direct detection of a first-order electroweak phase transition easier.

  2. Gravitational Radiation from First-Order Phase Transitions

    CERN Document Server

    Child, Hillary L

    2012-01-01

    It is believed that first order phase transitions at or around the GUT scale will produce high-frequency gravitational radiation. This radiation is a consequence of the collisions and coalescence of multiple bubbles during the transition. We employ high-resolution lattice simulations to numerically evolve a system of bubbles, track the anisotropic stress during the process and evolve the metric perturbations associated with gravitational radiation. Although the radiation produced during the bubble collisions has previously been estimated, we find that the coalescence phase that greatly enhances this radiation even in the absence of turbulence. We comment on how these simulations scale and propose that the same enhancement should be found at the Electroweak scale; this modification should make direct detection of a first-order electroweak phase transition easier.

  3. Brake subharmonic solutions of first order Hamiltonian systems

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    In this paper,we mainly use the Galerkin approximation method and the iteration inequalities of the L-Maslov type index theory to study the properties of brake subharmonic solutions for the first order non-autonomous Hamiltonian systems.We prove that when the positive integers j and k satisfy the certain conditions,there exists a jT-periodic nonconstant brake solution zj such that zj and zkj are distinct.

  4. TTVFaster: First order eccentricity transit timing variations (TTVs)

    Science.gov (United States)

    Agol, Eric; Deck, Katherine

    2016-04-01

    TTVFaster implements analytic formulae for transit time variations (TTVs) that are accurate to first order in the planet-star mass ratios and in the orbital eccentricities; the implementations are available in several languages, including IDL, Julia, Python and C. These formulae compare well with more computationally expensive N-body integrations in the low-eccentricity, low mass-ratio regime when applied to simulated and to actual multi-transiting Kepler planet systems.

  5. Multidimensional first-order dominance comparisons of population wellbeing

    DEFF Research Database (Denmark)

    Arndt, Thomas Channing; Siersbæk, Nikolaj; Østerdal, Lars Peter Raahave

    In this paper, we convey the concept of first-order dominance (FOD) with particular focus on applications to multidimensional population welfare comparisons. We give an account of the fundamental equivalent definitions of FOD, illustrated with simple numerical examples. An implementable method...... for detecting dominances is explained along with a bootstrapping procedure that yields additional information relative to what can be obtained from dominance comparisons alone. We discuss strengths and weaknesses of FOD, compared to other multidimensional population comparison concepts, and describe practical...

  6. First-order optimality condition of basis pursuit denoise problem

    Institute of Scientific and Technical Information of China (English)

    朱玮; 舒适; 成礼智

    2014-01-01

    A new first-order optimality condition for the basis pursuit denoise (BPDN) problem is derived. This condition provides a new approach to choose the penalty param-eters adaptively for a fixed point iteration algorithm. Meanwhile, the result is extended to matrix completion which is a new field on the heel of the compressed sensing. The numerical experiments of sparse vector recovery and low-rank matrix completion show validity of the theoretic results.

  7. Subharmonic solutions for first-order Hamiltonian systems

    Directory of Open Access Journals (Sweden)

    Mohsen Timoumi

    2013-09-01

    Full Text Available In this article, we study the existence of periodic and subharmonic solutions for a class of non-autonomous first-order Hamiltonian systems such that the nonlinearity has a growth at infinity faster than $|x|^{\\alpha}$, $0\\leq\\alpha < 1$. We also study the minimality of periods for such solutions. Our results are illustrated by specific examples. The proofs are based on the least action principle and a generalized saddle point theorem.

  8. First-order framework for flat brane with auxiliary fields

    CERN Document Server

    Bazeia, D; Menezes, R

    2014-01-01

    This work deals with braneworld models in the presence of auxiliary fields. We investigate the case where Einstein's equation is modified with the inclusion of extra, non-dynamical terms. We show that the model supports first-order differential equations that solve the equations of motion, but the standard braneworld scenario changes under the presence of the parameter that controls the non-dynamical or auxiliary fields that modifies Einstein's equation.

  9. Multilevel first-order system least squares for PDEs

    Energy Technology Data Exchange (ETDEWEB)

    McCormick, S.

    1994-12-31

    The purpose of this talk is to analyze the least-squares finite element method for second-order convection-diffusion equations written as a first-order system. In general, standard Galerkin finite element methods applied to non-self-adjoint elliptic equations with significant convection terms exhibit a variety of deficiencies, including oscillations or nonmonotonicity of the solution and poor approximation of its derivatives, A variety of stabilization techniques, such as up-winding, Petrov-Galerkin, and stream-line diffusion approximations, have been introduced to eliminate these and other drawbacks of standard Galerkin methods. Yet, although significant progress has been made, convection-diffusion problems remain among the more difficult problems to solve numerically. The first-order system least-squares approach promises to overcome these deficiencies. This talk develops ellipticity estimates and discretization error bounds for elliptic equations (with lower order terms) that are reformulated as a least-squares problem for an equivalent first-order system. The main results are the proofs of ellipticity and optimal convergence of multiplicative and additive solvers of the discrete systems.

  10. Stability and Performance of First-Order Linear Time-Delay Feedback Systems: An Eigenvalue Approach

    Directory of Open Access Journals (Sweden)

    Shu-An He

    2011-01-01

    Full Text Available Linear time-delay systems with transcendental characteristic equations have infinitely many eigenvalues which are generally hard to compute completely. However, the spectrum of first-order linear time-delay systems can be analyzed with the Lambert function. This paper studies the stability and state feedback stabilization of first-order linear time-delay system in detail via the Lambert function. The main issues concerned are the rightmost eigenvalue locations, stability robustness with respect to delay time, and the response performance of the closed-loop system. Examples and simulations are presented to illustrate the analysis results.

  11. PSsolver: A Maple implementation to solve first order ordinary differential equations with Liouvillian solutions

    Science.gov (United States)

    Avellar, J.; Duarte, L. G. S.; da Mota, L. A. C. P.

    2012-10-01

    We present a set of software routines in Maple 14 for solving first order ordinary differential equations (FOODEs). The package implements the Prelle-Singer method in its original form together with its extension to include integrating factors in terms of elementary functions. The package also presents a theoretical extension to deal with all FOODEs presenting Liouvillian solutions. Applications to ODEs taken from standard references show that it solves ODEs which remain unsolved using Maple's standard ODE solution routines. New version program summary Program title: PSsolver Catalogue identifier: ADPR_v2_0 Program summary URL: http://cpc.cs.qub.ac.uk/summaries/ADPR_v2_0.html Program obtainable from: CPC Program Library, Queen's University, Belfast, N. Ireland Licensing provisions: Standard CPC licence, http://cpc.cs.qub.ac.uk/licence/licence.html No. of lines in distributed program, including test data, etc.: 2302 No. of bytes in distributed program, including test data, etc.: 31962 Distribution format: tar.gz Programming language: Maple 14 (also tested using Maple 15 and 16). Computer: Intel Pentium Processor P6000, 1.86 GHz. Operating system: Windows 7. RAM: 4 GB DDR3 Memory Classification: 4.3. Catalogue identifier of previous version: ADPR_v1_0 Journal reference of previous version: Comput. Phys. Comm. 144 (2002) 46 Does the new version supersede the previous version?: Yes Nature of problem: Symbolic solution of first order differential equations via the Prelle-Singer method. Solution method: The method of solution is based on the standard Prelle-Singer method, with extensions for the cases when the FOODE contains elementary functions. Additionally, an extension of our own which solves FOODEs with Liouvillian solutions is included. Reasons for new version: The program was not running anymore due to changes in the latest versions of Maple. Additionally, we corrected/changed some bugs/details that were hampering the smoother functioning of the routines. Summary

  12. First-order corrections to random-phase approximation GW calculations in silicon and diamond

    Science.gov (United States)

    Ummels, R. T. M.; Bobbert, P. A.; van Haeringen, W.

    1998-05-01

    We report on ab initio calculations of the first-order corrections in the screened interaction W to the random-phase approximation polarizability and to the GW self-energy, using a noninteracting Green's function, for silicon and diamond. It is found that the first-order vertex and self-consistency corrections to the polarizability largely compensate each other. This does not hold, however, for the first-order corrections to the GW gap. For silicon the compensation between the first-order vertex and self-consistency correction contributions to the gap is only about 35%, while for diamond it is even absent. The resulting gap values are significantly and systematically too large, the direct gaps for silicon and diamond being 0.4 eV and 0.7 eV larger than their GW values, respectively. The success of GW in predicting electronic properties of, e.g., silicon and diamond can therefore apparently not be understood in terms of ``small'' corrections to GW to first order in W using a noninteracting Green's function.

  13. Programming Scala Scalability = Functional Programming + Objects

    CERN Document Server

    Wampler, Dean

    2009-01-01

    Learn how to be more productive with Scala, a new multi-paradigm language for the Java Virtual Machine (JVM) that integrates features of both object-oriented and functional programming. With this book, you'll discover why Scala is ideal for highly scalable, component-based applications that support concurrency and distribution. Programming Scala clearly explains the advantages of Scala as a JVM language. You'll learn how to leverage the wealth of Java class libraries to meet the practical needs of enterprise and Internet projects more easily. Packed with code examples, this book provides us

  14. ON THE HYPERBOLIC OBSTACLE PROBLEM OF FIRST ORDER

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    This paper presents new results for strong solutions and their coincidence sets of the obstacle problem for linear hyperbolic operators of first order. An inequality similar to the LewyStampacchia ones for elliptic and parabolic problems is shown. Under nondegeneracy conditions the stability of the coincidence set is shown with respect to the variation of the data and with respect to approximation by semilinear hyperbolic problems. These results are applied to the asymptotic stability of the evolution problem with respect to the stationary coercive problem with obstacle.

  15. Coulomb interaction and first-order superconductor-insulator transition.

    Science.gov (United States)

    Syzranov, S V; Aleiner, I L; Altshuler, B L; Efetov, K B

    2010-09-24

    The superconductor-insulator transition (SIT) in regular arrays of Josephson junctions is studied at low temperatures. We derived an imaginary time Ginzburg-Landau-type action properly describing the Coulomb interaction. The renormalization group analysis at zero temperature T=0 in the space dimensionality d=3 shows that the SIT is always of the first order. At finite T, a tricritical point separates the lines of the first- and second-order phase transitions. The same conclusion holds for d=2 if the mutual capacitance is larger than the distance between junctions.

  16. First order tune shift calculations for transverse betatron dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Garavaglia, T.

    1991-09-01

    An effective Hamiltonian, with non-linear magnetic multipole terms and momentum dispersion contributions, is used to obtain the first order tune-shift results for transverse betatron motion for protons in the Superconducting Super Collider (SSC). This Hamiltonian is represented in terms of action angle variables, and analytical results are obtained using symbolic algebra methods. Mathematical derivations of the transverse multipole expansion and of the transverse betatron equations, using an invariant action and curvilinear coordinates, are given in the appendices. Numerical and graphical tune-space results are given that illustrate the dependence of tune-shifts on injection amplitude and momentum spread. 10 refs., 7 figs.

  17. First-order allpass filter using multi-input OTA

    Science.gov (United States)

    Iqbal, S. Z.; Psychalinos, C.; Parveen, N.

    2013-10-01

    A novel first-order allpass filter, operating in voltage-mode, is introduced in this article. Compared with the corresponding already proposed structures, attractive offered benefits are the capability for simultaneous offering a minimum number of active and passive components, and the absence of any realisability restriction. These have been achieved by employing a multiple-input operational transconductance amplifier as active element. The performance of the proposed circuits has been evaluated through simulation results, utilising the Analog Design Environment of Cadence software.

  18. A first-order Temporal Logic for Actions

    CERN Document Server

    Schwind, Camilla

    2007-01-01

    We present a multi-modal action logic with first-order modalities, which contain terms which can be unified with the terms inside the subsequent formulas and which can be quantified. This makes it possible to handle simultaneously time and states. We discuss applications of this language to action theory where it is possible to express many temporal aspects of actions, as for example, beginning, end, time points, delayed preconditions and results, duration and many others. We present tableaux rules for a decidable fragment of this logic.

  19. Temporal aggregation in first order cointegrated vector autoregressive

    DEFF Research Database (Denmark)

    la Cour, Lisbeth Funding; Milhøj, Anders

    2006-01-01

    We study aggregation - or sample frequencies - of time series, e.g. aggregation from weekly to monthly or quarterly time series. Aggregation usually gives shorter time series but spurious phenomena, in e.g. daily observations, can on the other hand be avoided. An important issue is the effect of ...... of aggregation on the adjustment coefficient in cointegrated systems. We study only first order vector autoregressive processes for n dimensional time series Xt, and we illustrate the theory by a two dimensional and a four dimensional model for prices of various grades of gasoline....

  20. Temporal aggregation in first order cointegrated vector autoregressive models

    DEFF Research Database (Denmark)

    La Cour, Lisbeth Funding; Milhøj, Anders

    We study aggregation - or sample frequencies - of time series, e.g. aggregation from weekly to monthly or quarterly time series. Aggregation usually gives shorter time series but spurious phenomena, in e.g. daily observations, can on the other hand be avoided. An important issue is the effect of ...... of aggregation on the adjustment coefficient in cointegrated systems. We study only first order vector autoregressive processes for n dimensional time series Xt, and we illustrate the theory by a two dimensional and a four dimensional model for prices of various grades of gasoline...

  1. Instantons and surface tension at a first-order transition

    Science.gov (United States)

    Gupta, Sourendu

    1994-04-01

    We study the dynamics of the first-order phase transition in the two-dimensional 15-state Potts model, both at and off equilibrium. We find that phase changes take place through nucleation in both cases, and finite volume effects are described well through an instanton computation. Thus a dynamical measurement of the surface tension is possible. We find that the order-disorder surface tension is compatible with perfect wetting. An accurate treatment of fluctuations about the instanton solution is seen to be of great importance. Current Address: Theory Group, TIFR, Homi Bhabha Road, Bombay 400005, India.

  2. Multilevel solvers of first-order system least-squares for Stokes equations

    Energy Technology Data Exchange (ETDEWEB)

    Lai, Chen-Yao G. [National Chung Cheng Univ., Chia-Yi (Taiwan, Province of China)

    1996-12-31

    Recently, The use of first-order system least squares principle for the approximate solution of Stokes problems has been extensively studied by Cai, Manteuffel, and McCormick. In this paper, we study multilevel solvers of first-order system least-squares method for the generalized Stokes equations based on the velocity-vorticity-pressure formulation in three dimensions. The least-squares functionals is defined to be the sum of the L{sup 2}-norms of the residuals, which is weighted appropriately by the Reynolds number. We develop convergence analysis for additive and multiplicative multilevel methods applied to the resulting discrete equations.

  3. Colored Noise in First-order-like Phase Transition of a Laser System

    Institute of Scientific and Technical Information of China (English)

    HE Ying; ZHU Shiqun; LING Yinsheng

    2002-01-01

    The decoupling theory is employed to analyze the multiplicative colored noise in a single mode laser system. Steady state intensity distribution function is derived when colored noise is included in the laser system. The first-order-like phase transition driven by multiplicative colored noise is investigated and compared with the case of multiplicative white noise. It is shown that the noise correlation time can affect the parameter plane of the first-order-like phase transition. The steady state intensity distributions in a laser system is changed greatly with noise correlation time τ.

  4. First Order Deceptive Problem of ACO and Its Performance Analysis

    Directory of Open Access Journals (Sweden)

    Ling Chen

    2009-12-01

    Full Text Available Ant colony optimization(ACO, which is one of the intelligential optimization algorithm, has been widely used to solve combinational optimization problems. Deceptive problems have been considered difficult for ant colony optimization. It was believed that ACO will fail to converge to global optima of deceptive problems. This paper proves that the first order deceptive problem of ant colony algorithm satisfies value convergence under certain initial pheromone distribution, but does not satisfy solution convergence. We also present a first attempt towards the value-convergence time complexity analysis of ACO on the first-order deceptive systems taking the n-bit trap problem as the test instance. We prove that time complexity of MMAS, which is an ACO with limitations of the pheromone on each edge, on n-bit trap problem is O(n2m.log n, here n is the size of the problem and m is the number of artificial ants. Our experimental results confirm the correctness of our analysis.

  5. Design and Simulation of First Order Sigma-Delta Modulator Using LT spice Tool

    Directory of Open Access Journals (Sweden)

    Prince Kumar Pandey

    2014-07-01

    Full Text Available A switched-capacitor single-stage Sigma-Delta ADC with a first-order modulator is proposed. Efficient low power first Order 1-Bit Sigma-Delta ADC designed which accepts input signal bandwidth of 10 MHz. This circuitry performs the function of an analog-to-digital converter. A first-order 1-Bit Sigma-Delta (Σ-Δ modulator is designed, simulated and analyzed using LTspice standard 250nm CMOS technology power supply of 1.8V. The modulator is proved to be robustness, the high performance in stability. The simulations are compared with those from a traditional analog-to-digital converter to prove that Sigma-Delta is performing better with low power and area.

  6. Topological first-order vortices in a gauged CP(2 model

    Directory of Open Access Journals (Sweden)

    R. Casana

    2017-05-01

    Full Text Available We study time-independent radially symmetric first-order solitons in a CP(2 model interacting with an Abelian gauge field whose dynamics is controlled by the usual Maxwell term. In this sense, we develop a consistent first-order framework verifying the existence of a well-defined lower bound for the corresponding energy. We saturate such a lower bound by focusing on those solutions satisfying a particular set of coupled first-order differential equations. We solve these equations numerically using appropriate boundary conditions giving rise to regular structures possessing finite-energy. We also comment the main features these configurations exhibit. Moreover, we highlight that, despite the different solutions we consider for an auxiliary function β(r labeling the model (therefore splitting our investigation in two a priori distinct branches, all resulting scenarios engender the very same phenomenology, being physically equivalent.

  7. Topological first-order vortices in a gauged CP(2) model

    Science.gov (United States)

    Casana, R.; Dias, M. L.; da Hora, E.

    2017-05-01

    We study time-independent radially symmetric first-order solitons in a CP (2) model interacting with an Abelian gauge field whose dynamics is controlled by the usual Maxwell term. In this sense, we develop a consistent first-order framework verifying the existence of a well-defined lower bound for the corresponding energy. We saturate such a lower bound by focusing on those solutions satisfying a particular set of coupled first-order differential equations. We solve these equations numerically using appropriate boundary conditions giving rise to regular structures possessing finite-energy. We also comment the main features these configurations exhibit. Moreover, we highlight that, despite the different solutions we consider for an auxiliary function β (r) labeling the model (therefore splitting our investigation in two a priori distinct branches), all resulting scenarios engender the very same phenomenology, being physically equivalent.

  8. On a First-Order Quantum Phase Transition in a Finite System

    CERN Document Server

    Leviatan, A

    2006-01-01

    We examine the dynamics at the critical-point of a general first-order quantum phase transition in a finite system. Suitable Hamiltonians are constructed whose spectra exhibit coexistence of states corresponding to two degenerate minima in the energy surface separated by an arbitrary barrier. Explicit expressions are derived for wave functions and obesrvables at the critical-point.

  9. Implementation of an optimal first-order method for strongly convex total variation regularization

    DEFF Research Database (Denmark)

    Jensen, Tobias Lindstrøm; Jørgensen, Jakob Heide; Hansen, Per Christian;

    2012-01-01

    We present a practical implementation of an optimal first-order method, due to Nesterov, for large-scale total variation regularization in tomographic reconstruction, image deblurring, etc. The algorithm applies to μ-strongly convex objective functions with L-Lipschitz continuous gradient...

  10. Reduction of static field equation of Faddeev model to first order PDE

    Energy Technology Data Exchange (ETDEWEB)

    Hirayama, Minoru [Department of Mathematics and Physics, Shanghai University of Electric Power, Pinglian road 2103, Shanghai 200090 (China); Shi Changguang [Department of Mathematics and Physics, Shanghai University of Electric Power, Pinglian road 2103, Shanghai 200090 (China)], E-mail: shichangguang@shiep.edu.cn

    2007-09-06

    A method to solve the static field equation of the Faddeev model is presented. For a special combination of the concerned field, we adopt a form which is compatible with the field equation and involves two arbitrary complex functions. As a result, the static field equation is reduced to a set of first order partial differential equations.

  11. Defect Formation in First Order Phase Transitions with Damping

    CERN Document Server

    Ferrera, A

    1998-01-01

    Within the context of first order phase transitions in the early universe, we study the influence of a coupling between the (global U(1)) scalar driving the transition and the rest of the matter content of the theory. The effect of the coupling on the scalar is simulated by introducing a damping term in its equations of motion, as suggested by recent results in the electroweak phase transition. After a preceeding paper, in which we studied the influence that this coupling has in the dynamics of bubble collisions and topological defect formation, we proceed in this paper to quantify the impact of this new effects on the probability of defect creation per nucleating bubble.

  12. A theory of first order dissipative superfluid dynamics

    CERN Document Server

    Bhattacharya, Jyotirmoy; Minwalla, Shiraz; Yarom, Amos

    2014-01-01

    We determine the most general form of the equations of relativistic superfluid hydrodynamics consistent with Lorentz invariance, the Onsager principle and the second law of thermodynamics at first order in the derivative expansion. Once parity is violated, either because the U(1) symmetry is anomalous or as a consequence of a different parity-breaking mechanism, our results deviate from the standard textbook analysis of superfluids. Our general equations require the specification of twenty parameters (such as the viscosity and conductivity). In the limit of small relative superfluid velocities we find a seven parameter set of equations. In the same limit, we have used the AdS/CFT correspondence to compute the parity odd contributions to the superfluid equations of motion for a generic holographic model and have verified that our results are consistent.

  13. FIRST-ORDER PARTICLE ACCELERATION IN MAGNETICALLY DRIVEN FLOWS

    Energy Technology Data Exchange (ETDEWEB)

    Beresnyak, Andrey [Naval Research Laboratory, Washington, DC 20375 (United States); Li, Hui [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    2016-03-10

    We demonstrate that particles are regularly accelerated while experiencing curvature drift in flows driven by magnetic tension. Some examples of such flows include spontaneous turbulent reconnection and decaying magnetohydrodynamic turbulence, where a magnetic field relaxes to a lower-energy configuration and transfers part of its energy to kinetic motions of the fluid. We show that this energy transfer, which normally causes turbulent cascade and heating of the fluid, also results in a first-order acceleration of non-thermal particles. Since it is generic, this acceleration mechanism is likely to play a role in the production of non-thermal particle distribution in magnetically dominant environments such as the solar chromosphere, pulsar magnetospheres, jets from supermassive black holes, and γ-ray bursts.

  14. First-order chemistry in the surface-flux layer

    DEFF Research Database (Denmark)

    Kristensen, L.; Andersen, C.E.; Ejsing Jørgensen, Hans

    1997-01-01

    process, The analytic flux solution showed a clear deviation from the constant flux, characterizing a conserved scalar in the surface-flux layer. It decreases with height and is reduced by an order of magnitude of the surface flux at a height equal to about the typical mean distance a molecule can travel...... before destruction. The predicted mean concentration profile, however, shows only a small deviation from the logarithmic behavior of a conserved scalar. The solution is consistent with assuming a flux-gradient relationship with a turbulent diffusivity corrected by the Damkohler ratio, the ratio...... of a characteristic turbulent time scale and the scalar mean lifetime. We show that if we use only first-order closure and neglect the effect of the Damkohler ratio on the turbulent diffusivity we obtain another analytic solution for the profiles of the flux and the mean concentration which, from an experimental...

  15. Basic first-order model theory in Mizar

    Directory of Open Access Journals (Sweden)

    Marco Bright Caminati

    2010-01-01

    Full Text Available The author has submitted to Mizar Mathematical Library a series of five articles introducing a framework for the formalization of classical first-order model theory.In them, Goedel's completeness and Lowenheim-Skolem theorems have also been formalized for the countable case, to offer a first application of it and to showcase its utility.This is an overview and commentary on some key aspects of this setup.It features exposition and discussion of a new encoding of basic definitions and theoretical gears needed for the task, remarks about the design strategies and approaches adopted in their implementation, and more general reflections about proof checking induced by the work done.

  16. Subphase transitions in first-order aggregation processes

    Science.gov (United States)

    Koci, Tomas; Bachmann, Michael

    2017-03-01

    In this paper, we investigate the properties of aggregation transitions in the context of generic coarse-grained homopolymer systems. By means of parallel replica-exchange Monte Carlo methods, we perform extensive simulations of systems consisting of up to 20 individual oligomer chains with five monomers each. Using the tools of the versatile microcanonical inflection-point analysis, we show that the aggregation transition is a first-order process consisting of a sequence of subtransitions between intermediate structural phases. We unravel the properties of these intermediate phases by collecting and analyzing their individual contributions towards the density of states of the system. The central theme of this systematic study revolves around translational entropy and its role in the striking phenomena of missing intermediate phases. We conclude with a brief discussion of the scaling properties of the transition temperature and the latent heat.

  17. Scattering from elastic sea beds: first-order theory.

    Science.gov (United States)

    Jackson, D R; Ivakin, A N

    1998-01-01

    A perturbation model for high-frequency sound scattering from an irregular elastic sea bed is considered. The sea bed is assumed homogeneous on the average and two kinds of irregularities are assumed to cause scattering: roughness of the water-sea bed interface and volume inhomogeneities of the sediment mass density and the speeds of compressional and shear waves. The first-order small perturbation approximation is used to obtain expressions for the scattering amplitude and bistatic scattering strength. The angular dependence of the scattering strength is calculated for sedimentary rock and the influence of shear elasticity is examined by comparison with the case of a fluid bottom. Shear effects are shown to be strong and complicated.

  18. Second- and First-Order Phase Transitions in CDT

    CERN Document Server

    Ambjorn, J; Jurkiewicz, J; Loll, R

    2012-01-01

    Causal Dynamical Triangulations (CDT) is a proposal for a theory of quantum gravity, which implements a path-integral quantization of gravity as the continuum limit of a sum over piecewise flat spacetime geometries. We use Monte Carlo simulations to analyse the phase transition lines bordering the physically interesting de Sitter phase of the four-dimensional CDT model. Using a range of numerical criteria, we present strong evidence that the so-called A-C transition is first order, while the B-C transition is second order. The presence of a second-order transition may be related to an ultraviolet fixed point of quantum gravity and thus provide the key to probing physics at and possibly beyond the Planck scale.

  19. On First Order Optimality Conditions for Vector Optimization

    Institute of Scientific and Technical Information of China (English)

    L.M. Gra(n)a Drummond; A.N. Iusem; B.F. Svaiter

    2003-01-01

    We develop first order optimality conditions for constrained vector optimization. The partial orders for the objective and the constraints are induced by closed and convex cones with nonempty interior.After presenting some well known existence results for these problems, based on a scalarization approach, we establish necessity of the optimality conditions under a Slater-like constraint qualification, and then sufficiency for the K-convex case. We present two alternative sets of optimality conditions, with the same properties in connection with necessity and sufficiency, but which are different with respect to the dimension of the spaces to which the dual multipliers belong. We introduce a duality scheme, with a point-to-set dual objective, for which strong duality holds. Some examples and open problems for future research are also presented.

  20. Kinetics and thermodynamics of first-order Markov chain copolymerization

    Science.gov (United States)

    Gaspard, P.; Andrieux, D.

    2014-07-01

    We report a theoretical study of stochastic processes modeling the growth of first-order Markov copolymers, as well as the reversed reaction of depolymerization. These processes are ruled by kinetic equations describing both the attachment and detachment of monomers. Exact solutions are obtained for these kinetic equations in the steady regimes of multicomponent copolymerization and depolymerization. Thermodynamic equilibrium is identified as the state at which the growth velocity is vanishing on average and where detailed balance is satisfied. Away from equilibrium, the analytical expression of the thermodynamic entropy production is deduced in terms of the Shannon disorder per monomer in the copolymer sequence. The Mayo-Lewis equation is recovered in the fully irreversible growth regime. The theory also applies to Bernoullian chains in the case where the attachment and detachment rates only depend on the reacting monomer.

  1. Tracking control for first-order multi-agent systems

    Institute of Scientific and Technical Information of China (English)

    Yang LIU; Yingmin JIA

    2008-01-01

    In this paper,the conventional tracking control problem is expanded to first-order multi-agent systerns,which can be solved by directly guiding any agent in the group.The following three kinds of desired motions are considered for all agents to track:1)stillness in space,2)variable motion with known acceleration,3) variable motion with partly unknown acceleration.Specifically,fixed networks with time delays and switching networks without delays are both considered in case 1).Switching networks with and without time delays are both studied in case 2),while for 3),switching networks without delays are mainly investigated.A numerical simulation example is included to illustrate the results.

  2. First-Order-Like Transition for Dispersive Optical Bistability

    Institute of Scientific and Technical Information of China (English)

    HE Ying; ZHU Shi-Qun

    2003-01-01

    The first-order-like phase transition (FOLT) in the dispersive optical bistability is investigated when the fluctuation in the incident light field is considered as colored noise. A unified colored-noise approximation is applied to obtain the steady state distribution (SSD) when either the intensity or phase fluctuations of the incident field are included in the system. For intensity fluctuations only, the curve of SSD is changed from single extreme to two extremes, and then to three extremes. The colored nature of the noise can reduce the fluctuation in the system. However, for phase fluctuations only, the FOLT is mainly induced by the colored nature of the noise. The curve of SSD is changed from single extreme to three extremes directly. There is no FOLT existing for white noise.

  3. Experimental and theoretical investigation of the first-order hyperpolarizability of a class of triarylamine derivatives

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Daniel L., E-mail: dlsilva.physics@gmail.com, E-mail: deboni@ifsc.usp.br [Departamento de Ciências da Natureza, Matemática e Educação, Universidade Federal de São Carlos, Rod. Anhanguera–Km 174, 13600-970 Araras, SP (Brazil); Instituto de Física, Universidade de São Paulo, CP 66318, 05314-970 São Paulo, SP (Brazil); Fonseca, Ruben D.; Mendonca, Cleber R.; De Boni, Leonardo, E-mail: dlsilva.physics@gmail.com, E-mail: deboni@ifsc.usp.br [Instituto de Física de São Carlos, Universidade de São Paulo, Caixa Postal 369, 13560-970 São Carlos, SP (Brazil); Vivas, Marcelo G. [Instituto de Ciência de Tecnologia, Universidade Federal de Alfenas, Cidade Universitária - BR 267 Km 533, 37715-400 Poços de Caldas, MG (Brazil); Ishow, E. [CEISAM–UMR CNRS 6230, Université de Nantes, 2 rue de la Houssinière, 44322 Nantes (France); Canuto, Sylvio [Instituto de Física, Universidade de São Paulo, CP 66318, 05314-970 São Paulo, SP (Brazil)

    2015-02-14

    This paper reports on the static and dynamic first-order hyperpolarizabilities of a class of push-pull octupolar triarylamine derivatives dissolved in toluene. We have combined hyper-Rayleigh scattering experiment and the coupled perturbed Hartree-Fock method implemented at the Density Functional Theory (DFT) level of theory to determine the static and dynamic (at 1064 nm) first-order hyperpolarizability (β{sub HRS}) of nine triarylamine derivatives with distinct electron-withdrawing groups. In four of these derivatives, an azoaromatic unit is inserted and a pronounceable increase of the first-order hyperpolarizability is reported. Based on the theoretical results, the dipolar/octupolar character of the derivatives is determined. By using a polarizable continuum model in combination with the DFT calculations, it was found that although solvated in an aprotic and low dielectric constant solvent, due to solvent-induced polarization and the frequency dispersion effect, the environment substantially affects the first-order hyperpolarizability of all derivatives investigated. This statement is supported due to the solvent effects to be essential for the better agreement between theoretical results and experimental data concerning the dynamic first-order hyperpolarizability of the derivatives. The first-order hyperpolarizability of the derivatives was also modeled using the two- and three-level models, where the relationship between static and dynamic first hyperpolarizabilities is given by a frequency dispersion model. Using this approach, it was verified that the dynamic first hyperpolarizability of the derivatives is satisfactorily reproduced by the two-level model and that, in the case of the derivatives with an azoaromatic unit, the use of a damped few-level model is essential for, considering also the molecular size of such derivatives, a good quantitative agreement between theoretical results and experimental data to be observed.

  4. Experimental and theoretical investigation of the first-order hyperpolarizability of a class of triarylamine derivatives

    Science.gov (United States)

    Silva, Daniel L.; Fonseca, Ruben D.; Vivas, Marcelo G.; Ishow, E.; Canuto, Sylvio; Mendonca, Cleber R.; De Boni, Leonardo

    2015-02-01

    This paper reports on the static and dynamic first-order hyperpolarizabilities of a class of push-pull octupolar triarylamine derivatives dissolved in toluene. We have combined hyper-Rayleigh scattering experiment and the coupled perturbed Hartree-Fock method implemented at the Density Functional Theory (DFT) level of theory to determine the static and dynamic (at 1064 nm) first-order hyperpolarizability (βHRS) of nine triarylamine derivatives with distinct electron-withdrawing groups. In four of these derivatives, an azoaromatic unit is inserted and a pronounceable increase of the first-order hyperpolarizability is reported. Based on the theoretical results, the dipolar/octupolar character of the derivatives is determined. By using a polarizable continuum model in combination with the DFT calculations, it was found that although solvated in an aprotic and low dielectric constant solvent, due to solvent-induced polarization and the frequency dispersion effect, the environment substantially affects the first-order hyperpolarizability of all derivatives investigated. This statement is supported due to the solvent effects to be essential for the better agreement between theoretical results and experimental data concerning the dynamic first-order hyperpolarizability of the derivatives. The first-order hyperpolarizability of the derivatives was also modeled using the two- and three-level models, where the relationship between static and dynamic first hyperpolarizabilities is given by a frequency dispersion model. Using this approach, it was verified that the dynamic first hyperpolarizability of the derivatives is satisfactorily reproduced by the two-level model and that, in the case of the derivatives with an azoaromatic unit, the use of a damped few-level model is essential for, considering also the molecular size of such derivatives, a good quantitative agreement between theoretical results and experimental data to be observed.

  5. Novel Resistorless First-Order Current-Mode Universal Filter Employing a Grounded Capacitor

    Directory of Open Access Journals (Sweden)

    R. Arslanalp

    2011-09-01

    Full Text Available In this paper, a new bipolar junction transistor (BJT based configuration for providing first-order resistorless current-mode (CM all-pass, low-pass and high-pass filter responses from the same configuration is suggested. The proposed circuit called as a first-order universal filter possesses some important advantages such as consisting of a few BJTs and a grounded capacitor, consuming very low power and having electronic tunability property of its pole frequency. Additionally, types of filter response can be obtained only by changing the values of current sources. The suggested circuit does not suffer from disadvantages of use of the resistors in IC process. The presented first-order universal filter topology does not need any passive element matching constraints. Moreover, as an application example, a second-order band-pass filter is obtained by cascading two proposed filter structures which are operating as low-pass filter and high-pass one. Simulations by means of PSpice program are accomplished to demonstrate the performance and effectiveness of the developed first-order universal filter.

  6. Experimental and theoretical (FT-IR, FT-Raman, UV-vis, NMR) spectroscopic analysis and first order hyperpolarizability studies of non-linear optical material: (2E)-3-[4-(methylsulfanyl) phenyl]-1-(4-nitrophenyl) prop-2-en-1-one using density functional theory.

    Science.gov (United States)

    Kumar, Amit; Deval, Vipin; Tandon, Poonam; Gupta, Archana; Deepak D'silva, E

    2014-09-15

    A combined experimental and theoretical investigation on FT-IR, FT-Raman, NMR, UV-vis spectra of a chalcone derivative (2E)-3-[4-(methylsulfanyl) phenyl]-1-(4-nitrophenyl) prop-2-en-1-one (4N4MSP) has been reported. 4N4MSP has two planar rings connected through conjugated double bond and it provides a necessary configuration to show non-linear optical (NLO) response. The molecular structure, fundamental vibrational frequencies and intensity of the vibrational bands are interpreted with the aid of structure optimizations and normal coordinate force field calculations based on density functional theory (DFT) with B3LYP functional and 6-311++G(d,p) basis set combination. The analysis of the fundamental modes was made with the help of potential energy distribution (PED). Molecular electrostatic potential (MEP) surface was plotted over the geometry primarily for predicting sites and relative reactivities towards electrophilic and nucleophilic attack. The delocalization of electron density of various constituents of the molecule has been discussed with the aid of NBO analysis. The electronic properties, such as excitation energies, oscillator strength, wavelengths, HOMO and LUMO energies, were calculated by time-dependent density functional theory (TD-DFT) and the results complement the experimental findings. The recorded and calculated 1H chemical shifts in gas phase and MeOD solution are gathered for reliable calculations of magnetic properties. Thermodynamic properties like heat capacity (C°p,m), entropy (S°m), enthalpy (H°m) have been calculated for the molecule at the different temperatures. Based on the finite-field approach, the non-linear optical (NLO) parameters such as dipole moment, mean polarizability, anisotropy of polarizability and first order hyperpolarizability of 4N4MSP molecule are calculated. The predicted first hyperpolarizability shows that the molecule has a reasonably good nonlinear optical (NLO) behavior.

  7. A First-order Augmented Lagrangian Method for Compressed Sensing

    CERN Document Server

    Aybat, Necdet Serhat

    2010-01-01

    In this paper, we propose a first-order augmented Lagrangian algorithm (FAL) that solves the basis pursuit problem min{|x|_1: Ax = b} by inexactly solving a sequence of problems of the form min{lambda(k) |x|_1+ |Ax-b-lambda(k)theta(k)|_2^2}, for an appropriately chosen sequence of multipliers {lambda(k),theta(k)}. Each of these subproblems are solved using Algorithm 3 in [19] by Paul Tseng wherein each update reduces to "shrinkage" [12] or constrained "shrinkage". We show that FAL converges to an optimal solution x* of the basis pursuit problem, i.e. x*=argmin{|x|_1: Ax= b} and that there exist a priori fixed sequence {lambda(k)} such that for all epsilon>0, iterates x(k) computed by FAL are epsilon-feasible, i.e. |Ax(k) - b|_2 <= epsilon, and epsilon-optimal, | |x(k)|_1 - |x*|_1 | <= epsilon, after O(1/epsilon) iterations, where the complexity of each iteration is O(n log(n)). We also report the results of numerical experiments comparing the performance of FAL with SPA [1], NESTA [18], FPC [10, 11], FP...

  8. Nonequilibrium gap collapse near a first-order Mott transition

    Science.gov (United States)

    Sandri, Matteo; Fabrizio, Michele

    2015-03-01

    We study the nonequilibrium dynamics of a simple model for V2O3 that consists of a quarter-filled Hubbard model for two orbitals that are split by a weak crystal field. Peculiarities of this model are (1) a Mott insulator whose gap corresponds to transferring an electron from the occupied lower orbital to the empty upper one, rather than from the lower to the upper Hubbard subbands; (2) a Mott transition generically of first order even at zero temperature. We simulate by means of time-dependent Gutzwiller approximation the evolution within the insulating phase of an initial state endowed by a nonequilibrium population of electrons in the upper orbital and holes in the lower one. We find that the excess population may lead, above a threshold, to a gap collapse and drive the insulator into the metastable metallic phase within the coexistence region around the Mott transition. This result foresees a nonthermal pathway to revert a Mott insulator into a metal. Even though this physical scenario is uncovered in a very specific toy model, we argue it might apply to other Mott insulating materials that share similar features.

  9. First order reversal curves diagrams for describing ferroelectric switching characteristics

    Directory of Open Access Journals (Sweden)

    Liliana Mitoseriu

    2009-06-01

    Full Text Available First Order Reversal Curves (FORC are polarization-field dependences described between saturation field Esat and a variable reversal field Er∈(-Esat, Esat. The FORC diagrams were proposed to describe some characteristics of the switching process in ferroelectrics. The approach is related to the Preisach model which considers the distribution of the elementary switchable units over their coercive and bias fields. The influence of the anisotropic porosity in Pb(Zr,TiO3 bulk ceramics on the FORC distributions demonstrated the existence of a positive/negative bias as a result of the confinement induced by anisotropy. The reducing of grain size in Ba(Zr,TiO3 ceramics causes an increase of the ratio of the reversible/irreversible components of the polarization on the FORC distribution indicating the tendency of system towards the superparaelectric state. The FORC method demonstrates to provide a kind of ‘fingerprinting’ of various types of switching characteristics in ferroic systems.

  10. A first-order approach to conformal gravity

    CERN Document Server

    Zlosnik, T G

    2016-01-01

    We investigate whether a spontaneously-broken gauge theory of the group $SU(2,2)$ may be a genuine competitor to General Relativity. The basic ingredients of the theory are an $SU(2,2)$ gauge field $A_{\\mu}$ and a Higgs field $W$ in the adjoint representation of the group with the Higgs field producing the symmetry breaking $SU(2,2)\\rightarrow SO(1,3)\\times SO(1,1)$. The action for gravity is polynomial in $\\{A_{\\mu},W\\}$ and the field equations are first-order in derivatives of these fields. The new $SO(1,1)$ symmetry in the gravitational sector is interpreted in terms of an emergent scale symmetry and the recovery of conformalized General Relativity and fourth-order Weyl conformal gravity as limits of the theory- following imposition of Lagrangian constraints- is demonstrated. Maximally symmetric spacetime solutions to the full theory are found and stability of the theory around these solutions is investigated; it is shown that regions of the theory's parameter space describe perturbations identical to that...

  11. A test of first order scaling in Nf=2 QCD

    CERN Document Server

    Cossu, G; Di Giacomo, A; Pica, C

    2007-01-01

    We complete our analysis of Nf=2 QCD based on the lattice staggered fermion formulation. Using a series of Monte Carlo simulations at fixed (amq*Ls^yh) one is able to test the universality class with given critical exponent yh. This strategy has been used to test the O(4) universality class and it has been presented at the previous Lattice conferences. No agreement was found with simulations in the mass range amq=[0.01335,0.15] using lattices with Ls=16 up to 32 and Lt=4. With the same strategy, we now investigate the possibility of a first order transition using a new set of Monte Carlo data corresponding to yh=3 in the same mass and volume range as the one used for O(4). A substantial agreement is observed both in the specific heat scaling and in the scaling of the chiral condensate, while the chiral susceptibilities still presents visible deviation from scaling in the mass range explored.

  12. Energy in first order 2+1 gravity

    CERN Document Server

    Corichi, Alejandro

    2015-01-01

    We consider \\Lambda=0 three dimensional gravity with asymptotically flat boundary conditions. This system was studied by Ashtekar and Varadarajan within the second order formalism -with metric variables- who showed that the Regge-Teitelboim formalism yields a consistent Hamiltonian description where, surprisingly, the energy is bounded from below and from above. The energy of the spacetime is, however, determined up to an arbitrary constant. The natural choice was to fix that freedom such that Minkowski spacetime has zero energy. More recently, Marolf and Pati\\~no started from the Einstein-Hilbert action supplemented with the Gibbons-Hawking term and showed that, in the 2+1 decomposition of the theory, the energy is shifted from the Ashtekar-Varadarajan analysis in such a way that Minkowski spacetime possesses a negative energy. In this contribution we consider the first order formalism, where the fundamental variables are a so(2,1) connection $\\omega_a{^I}_J$ and a triad $e_a^I$. We consider two actions. A n...

  13. First order Bragg grating filters in silicon on insulator waveguides

    Science.gov (United States)

    Waugh, Peter Michael

    2008-08-01

    The subject of this project is the design; analysis, fabrication and characterisation of first order Bragg Grating optical filters in Silicon-on-Insulator (SOI) planar waveguides. It is envisaged that this work will result in the possibility of Bragg Grating filters for use in Silicon Photonics. It is the purpose of the work to create as far as is possible flat surface waveguides so as to facilitate Thermo-Optic tuning and also the incorporation into rib-waveguide Silicon Photonics. The spectral response of the shallow Bragg Gratings was modelled using Coupled Mode Theory (CMT) by way of RSoft Gratingmod TM. Also the effect of having a Bragg Grating with alternate layers of refractive index of 1.5 and 3.5 was simulated in order to verify that Silica and Silicon layered Bragg Gratings could be viable. A series of Bragg Gratings were patterned on 1.5 micron SOI at Philips in Eindhoven, Holland to investigate the variation of grating parameters with a) the period of the gratings b) the mark to space ratio of the gratings and c) the length of the region converted to Bragg Gratings (i.e. the number of grating period repetitions). One set of gratings were thermally oxidised at Philips in Eindhoven and another set were ion implanted with Oxygen ions at the Ion Beam Facility, University of Surrey, England. The gratings were tested and found to give transmission minima at approximately 1540 nanometres and both methods of creating flat surfaces were found to give similar minima. Atomic Force Microscopy was applied to the grating area of the as-implanted samples in the Advanced Technology Institute, University of Surrey, which were found to have surface undulations in the order of 60 nanometres.

  14. Deterministic sensitivity analysis for first-order Monte Carlo simulations: a technical note.

    Science.gov (United States)

    Geisler, Benjamin P; Siebert, Uwe; Gazelle, G Scott; Cohen, David J; Göhler, Alexander

    2009-01-01

    Monte Carlo microsimulations have gained increasing popularity in decision-analytic modeling because they can incorporate discrete events. Although deterministic sensitivity analyses are essential for interpretation of results, it remains difficult to combine these alongside Monte Carlo simulations in standard modeling packages without enormous time investment. Our purpose was to facilitate one-way deterministic sensitivity analysis of TreeAge Markov state-transition models requiring first-order Monte Carlo simulations. Using TreeAge Pro Suite 2007 and Microsoft Visual Basic for EXCEL, we constructed a generic script that enables one to perform automated deterministic one-way sensitivity analyses in EXCEL employing microsimulation models. In addition, we constructed a generic EXCEL-worksheet that allows for use of the script with little programming knowledge. Linking TreeAge Pro Suite 2007 and Visual Basic enables the performance of deterministic sensitivity analyses of first-order Monte Carlo simulations. There are other potentially interesting applications for automated analysis.

  15. On First Order Interpolation Inequalities with Weights on the Heisenberg Group

    Institute of Scientific and Technical Information of China (English)

    Ya Zhou HAN; Peng Cheng NIU; Shu Tao ZHANG

    2011-01-01

    In this paper,sufficient and necessary conditions for the first order interpolation inequalities with weights on the Heisenberg group are given.The necessity is discussed by polar coordinates changes of the Heisenberg group.Establishing a class of Hardy type inequalities via a new representation formula for functions and Hardy-Sobolev type inequalities by interpolation,we derive the sufficiency.Finally,sharp constants for Hardy type inequalities are determined.

  16. First-order decomposition of thermal light in terms of a statistical mixture of pulses

    OpenAIRE

    Chenu, Aurélia; Brańczyk, Agata M.; J.E. Sipe

    2014-01-01

    We investigate the connection between thermal light and coherent pulses, constructing mixtures of single pulses that yield the same first-order, equal-space-point correlation function as thermal light. We present mixtures involving (i) pulses with a Gaussian lineshape and narrow bandwidths, and (ii) pulses with a coherence time that matches that of thermal light. We characterize the properties of the mixtures and pulses. Our results introduce an alternative description of thermal light in ter...

  17. Functional Programming in C# Classic Programming Techniques for Modern Projects

    CERN Document Server

    Sturm, Oliver

    2011-01-01

    Take advantage of the growing trend in functional programming. C# is the number-one language used by .NET developers and one of the most popular programming languages in the world. It has many built-in functional programming features, but most are complex and little understood. With the shift to functional programming increasing at a rapid pace, you need to know how to leverage your existing skills to take advantage of this trend. Functional Programming in C# leads you along a path that begins with the historic value of functional ideas. Inside, C# MVP and functional programming expert Oli

  18. Determining the first order perturbation of a polyharmonic operator on admissible manifolds

    Science.gov (United States)

    Assylbekov, Yernat M.; Yang, Yang

    2017-01-01

    We consider the inverse boundary value problem for the first order perturbation of the polyharmonic operator L g , X , q, with X being a W 1 , ∞ vector field and q being an L∞ function on compact Riemannian manifolds with boundary which are conformally embedded in a product of the Euclidean line and a simple manifold. We show that the knowledge of the Dirichlet-to-Neumann map determines X and q uniquely. The method is based on the construction of complex geometrical optics solutions using the Carleman estimate for the Laplace-Beltrami operator due to Dos Santos Ferreira, Kenig, Salo and Uhlmann. Notice that the corresponding uniqueness result does not hold for the first order perturbation of the Laplace-Beltrami operator.

  19. Dynamic Off-Equilibrium Transition in Systems Slowly Driven across Thermal First-Order Phase Transitions

    Science.gov (United States)

    Pelissetto, Andrea; Vicari, Ettore

    2017-01-01

    We study the off-equilibrium behavior of systems with short-range interactions, slowly driven across a thermal first-order transition, where the equilibrium dynamics is exponentially slow. We consider a dynamics that starts in the high-T phase at time t =ti0 in the low-T phase, with a time-dependent temperature T (t )/Tc≈1 -t /ts, where ts is the protocol time scale. A general off-equilibrium scaling (OS) behavior emerges in the limit of large ts. We check it at the first-order transition of the two-dimensional q -state Potts model with q =20 and 10. The numerical results show evidence of a dynamic transition, where the OS functions show a spinodal-like singularity. Therefore, the general mean-field picture valid for systems with long-range interactions is qualitatively recovered, provided the time dependence is appropriately (logarithmically) rescaled.

  20. Stromatoporoid biometrics using image analysis software: A first order approach

    Science.gov (United States)

    Wolniewicz, Pawel

    2010-04-01

    Strommetric is a new image analysis computer program that performs morphometric measurements of stromatoporoid sponges. The program measures 15 features of skeletal elements (pillars and laminae) visible in both longitudinal and transverse thin sections. The software is implemented in C++, using the Open Computer Vision (OpenCV) library. The image analysis system distinguishes skeletal elements from sparry calcite using Otsu's method for image thresholding. More than 150 photos of thin sections were used as a test set, from which 36,159 measurements were obtained. The software provided about one hundred times more data than the current method applied until now. The data obtained are reproducible, even if the work is repeated by different workers. Thus the method makes the biometric studies of stromatoporoids objective.

  1. Spectroscopic studies (FTIR, FT-Raman and UV-Visible), normal coordinate analysis, NBO analysis, first order hyper polarizability, HOMO and LUMO analysis of (1R)-N-(Prop-2-yn-1-yl)-2,3-dihydro-1H-inden-1-amine molecule by ab initio HF and density functional methods.

    Science.gov (United States)

    Muthu, S; Ramachandran, G

    2014-01-01

    The Fourier transform infrared (FT-IR) and FT-Raman of (1R)-N-(Prop-2-yn-1-yl)-2,3-dihydro-1H-inden-1-amine (1RNPDA) were recorded in the regions 4000-400 cm(-1) and 4000-100 cm(-1) respectively. A complete assignment and analysis of the fundamental vibrational modes of the molecule were carried out. The observed fundamental modes have been compared with the harmonic vibrational frequencies computed using HF method by employing 6-31G(d,p) basis set and DFT(B3LYP) method by employing 6-31G(d,p) basis set. The vibrational studies were interpreted in terms of Potential Energy Distribution (PED). The complete vibrational frequency assignments were made by Normal Co-ordinate Analysis (NCA) following the scaled quantum mechanical force field methodology (SQMFF). The first order hyper polarizability (β0) of this molecular system and related properties (α, μ, and Δα) are calculated using B3LYP/6-31G(d,p) method based on the finite-field approach. The thermodynamic functions of the title compound were also performed at the above methods and basis set. A detailed interpretation of the infrared and Raman spectra of 1RNPDA is reported. The (1)H and (13)C nuclear magnetic resonance (NMR) chemical shifts of the molecule were calculated using the GIAO method confirms with the experimental values. Stability of the molecule arising from hyper-conjugative interactions and charge delocalization has been analyzed using Natural Bond Orbital (NBO) analysis. UV-vis spectrum of the compound was recorded and electronic properties such as excitation energies, oscillator strength and wavelength were performed by TD-DFT/B3LYP using 6-31G(d,p) basis set. The HOMO and LUMO energy gap reveals that the energy gap reflects the chemical activity of the molecule. The observed and calculated wave numbers are formed to be in good agreement. The experimental spectra also coincide satisfactorily with those of theoretically constructed spectra. Copyright © 2013 Elsevier B.V. All rights reserved.

  2. Wave splitting for first-order systems of equations

    Directory of Open Access Journals (Sweden)

    G. Caviglia

    2002-01-01

    Fourier-transform domain, thus considering frequency-dependent functions of the space variable. The characterization is given for the direction of propagation and applications are developed to some cases of physical interest.

  3. First Order Dominance Analysis: Child Wellbeing in the Democratic Republic of Congo.

    Science.gov (United States)

    Nanivazo, Malokele

    This paper performs a multidimensional first order dominance analysis of child wellbeing in the Democratic Republic of Congo (DRC). This methodology allows the ordinal ranking of the 11 provinces of the DRC in terms of their wellbeing based upon the probability of their domination. This empirical application obviates the need to adopt a weighting scheme for the deprivation indicators or to rely on the signs of other cross-derivatives for comparison. We execute a bootstrap linear programming algorithm on seven deprivation indicators for three age groups of children derived from the DRC 2007 Standard Demographic and Health Survey. The results reveal widespread disparities in child wellbeing in the DRC.

  4. Multidimensional Poverty Indices and First Order Dominance Techniques: An Empirical Comparison of Different Approaches

    DEFF Research Database (Denmark)

    Hussain, M. Azhar; Permanyer, Iñaki

    2017-01-01

    In this paper we contrast different perspectives to the measurement of multidimensional poverty. Using data from 38 Demographic and Health Surveys around the developing world, we have compared the performance of two broad approaches: multidimensional poverty indices and first order dominance...... techniques (FOD). Our empirical findings suggest that the FOD approach might be a reasonable cost-effective alternative to the United Nations Development Program (UNDP)’s flagship poverty indicator: the Multidimensional Poverty Index (MPI). To the extent that the FOD approach is able to uncover the socio...

  5. A PSPACE-Complete First Order Fragment of Computability Logic

    CERN Document Server

    Bauer, Matthew S

    2012-01-01

    In a recently launched research program for developing logic as a formal theory of (interactive) computability, several very interesting logics have been introduced and axiomatized. These fragments of the larger Computability Logic aim not only to describe "what" can be computed, but also provide a mechanism for extracting computational algorithms from proofs. Among the most expressive and fundamental of these is CL4, known to be (constructively) sound and complete with respect to the underlying computational semantics. Furthermore, the fragment of CL4 not containing blind quantifiers was shown to be decidable in polynomial space. The present work extends this result and proves that this fragment is, in fact, PSPACE-complete.

  6. Finite size scaling and first-order phase transition in a modified XY model

    Science.gov (United States)

    Sinha, Suman; Roy, Soumen Kumar

    2010-02-01

    Monte Carlo simulation has been performed in a two-dimensional modified XY -model first proposed by Domany [Phys. Rev. Lett. 52, 1535 (1984)] The cluster algorithm of Wolff has been used and multiple histogram reweighting is performed. The first-order scaling behavior of the quantities such as specific heat and free-energy barrier are found to be obeyed accurately. While the lowest-order correlation function was found to decay to zero at long distance just above the transition, the next-higher-order correlation function shows a nonzero plateau.

  7. Electromagnetic field at finite temperature: A first order approach

    Science.gov (United States)

    Casana, R.; Pimentel, B. M.; Valverde, J. S.

    2006-10-01

    In this work we study the electromagnetic field at finite temperature via the massless DKP formalism. The constraint analysis is performed and the partition function for the theory is constructed and computed. When it is specialized to the spin 1 sector we obtain the well-known result for the thermodynamic equilibrium of the electromagnetic field.

  8. Identification of Nonlinear Times Series from First Order Cumulative Characteristics.

    Science.gov (United States)

    1991-08-01

    were generated using the Gaussian random number generator of Marsaglia and Tsang (1984). The number of samples in each run was 5000. Table 1 gives...629-642. Marsaglia , G. and Tsang, W. W. (1984). A fast, easily implemented method for sampling from decreasing or symmetric unimodal density functions

  9. First order mean field games - explicit solutions, perturbations and connection with classical mechanics

    KAUST Repository

    Gomes, Diogo A.

    2016-01-06

    We present recent developments in the theory of first-order mean-field games (MFGs). A standard assumption in MFGs is that the cost function of the agents is monotone in the density of the distribution. This assumption leads to a comprehensive existence theory and to the uniqueness of smooth solutions. Here, our goals are to understand the role of local monotonicity in the small perturbation regime and the properties of solutions for problems without monotonicity. Under a local monotonicity assumption, we show that small perturbations of MFGs have unique smooth solutions. In addition, we explore the connection between first-order MFGs and classical mechanics and KAM theory. Next, for non-monotone problems, we construct non-unique explicit solutions for a broad class of first-order mean-field games. We provide an alternative formulation of MFGs in terms of a new current variable. These examples illustrate two new phenomena: the non-uniqueness of solutions and the breakdown of regularity.

  10. Selfadjoint singular differential operators of first order and their spectrum

    Directory of Open Access Journals (Sweden)

    Zameddin I. Ismailov

    2016-01-01

    Full Text Available Based on Calkin-Gorbachuk method, we describe all selfadjoint extensions of the minimal operator generated by linear multipoint singular symmetric differential-operator, as a direct sum of weighted Hilbert space of vector-functions. Another approach to the investigation of this problem has been done by Everitt, Zettl and Markus. Also we study the structure of spectrum of these extensions.

  11. Glucocorticoid programming of neuroimmune function.

    Science.gov (United States)

    Walker, David J; Spencer, Karen A

    2017-07-17

    Throughout life physiological systems strive to maintain homeostasis and these systems are susceptible to exposure to maternal or environmental perturbations, particularly during embryonic development. In some cases, these perturbations may influence genetic and physiological processes that permanently alter the functioning of these physiological systems; a process known as developmental programming. In recent years, the neuroimmune system has garnered attention for its fundamental interactions with key hormonal systems, such as the hypothalamic pituitary adrenal (HPA) axis. The ultimate product of this axis, the glucocorticoid hormones, play a key role in modulating immune responses within the periphery and the CNS as part of the physiological stress response. It is well-established that elevated glucocorticoids induced by developmental stress exert profound short and long-term physiological effects, yet there is relatively little information of how these effects are manifested within the neuroimmune system. Pre and post-natal periods are prime candidates for manipulation in order to uncover the physiological mechanisms that underlie glucocorticoid programming of neuroimmune responses. Understanding the potential programming role of glucocorticoids may be key in uncovering vulnerable windows of CNS susceptibility to stressful experiences during embryonic development and improve our use of glucocorticoids as therapeutics in the treatment of neurodegenerative diseases. Crown Copyright © 2017. Published by Elsevier Inc. All rights reserved.

  12. First order linear ordinary differential equations in associative algebras

    Directory of Open Access Journals (Sweden)

    Gordon Erlebacher

    2004-01-01

    Full Text Available In this paper, we study the linear differential equation $$ frac{dx}{dt}=sum_{i=1}^n a_i(t x b_i(t + f(t $$ in an associative but non-commutative algebra $mathcal{A}$, where the $b_i(t$ form a set of commuting $mathcal{A}$-valued functions expressed in a time-independent spectral basis consisting of mutually annihilating idempotents and nilpotents. Explicit new closed solutions are derived, and examples are presented to illustrate the theory.

  13. Synthesis of models for order-sorted first-order theories using linear algebra and constraint solving

    Directory of Open Access Journals (Sweden)

    Salvador Lucas

    2015-12-01

    Full Text Available Recent developments in termination analysis for declarative programs emphasize the use of appropriate models for the logical theory representing the program at stake as a generic approach to prove termination of declarative programs. In this setting, Order-Sorted First-Order Logic provides a powerful framework to represent declarative programs. It also provides a target logic to obtain models for other logics via transformations. We investigate the automatic generation of numerical models for order-sorted first-order logics and its use in program analysis, in particular in termination analysis of declarative programs. We use convex domains to give domains to the different sorts of an order-sorted signature; we interpret the ranked symbols of sorted signatures by means of appropriately adapted convex matrix interpretations. Such numerical interpretations permit the use of existing algorithms and tools from linear algebra and arithmetic constraint solving to synthesize the models.

  14. Pressure effects on first-order magnetic Raman scattering in NiO

    CERN Document Server

    Mita, Y; Kobayashi, M; Endo, S

    2002-01-01

    The pressure dependence of first-order magnetic Raman peak of NiO single crystal was studied up to 20 GPa at room temperature. At ambient pressure, an unknown peak is also observed at nearly the same position as the one-magnon one and their separation becomes remarkable with increasing pressure. Pressure coefficients of the one-magnon peak and the other peak are obtained as 0.4 and 1.5 cm sup - sup 1 GPa sup - sup 1 , respectively. The next-nearest-neighbour antiferromagnetic exchange constant J sub 2 is obtained as a function of the lattice constant.

  15. First-order systems of linear partial differential equations: normal forms, canonical systems, transform methods

    Directory of Open Access Journals (Sweden)

    Heinz Toparkus

    2014-04-01

    Full Text Available In this paper we consider first-order systems with constant coefficients for two real-valued functions of two real variables. This is both a problem in itself, as well as an alternative view of the classical linear partial differential equations of second order with constant coefficients. The classification of the systems is done using elementary methods of linear algebra. Each type presents its special canonical form in the associated characteristic coordinate system. Then you can formulate initial value problems in appropriate basic areas, and you can try to achieve a solution of these problems by means of transform methods.

  16. Transadmittance Mode First Order LP/HP/AP Filter and its Application as an Oscillator

    Science.gov (United States)

    Nand, Deva; Pandey, Neeta

    2017-08-01

    In this paper new transadmittance mode first order low pass, high pass and all pass filter topologies using operational floating current conveyor (OFCC) is proposed and its application as an oscillator is also put forward. This proposal offers all filter functions at high impedance. Only two OFCCs, two resistors and one grounded capacitor are employed for realization. Workability is verified through SPICE simulations and results conform to the theoretical predictions very well. The proposed circuit is prototyped and tested experimentally for its application as an oscillator.

  17. Study of First-Order Thermal Sigma-Delta Architecture for Convective Accelerometers

    CERN Document Server

    Nouet, Pascal; Latorre, Laurent; Nouet, Pascal

    2008-01-01

    This paper presents the study of an original closed-loop conditioning approach for fully-integrated convective inertial sensors. The method is applied to an accelerometer manufactured on a standard CMOS technology using an auto-aligned bulk etching step. Using the thermal behavior of the sensor as a summing function, a first order sigma-delta modulator is built. This "electro-physical" modulator realizes an analog-to-digital conversion of the signal. Besides the feedback scheme should improve the sensor performance.

  18. First-order layering and critical wetting transitions in nonadditive hard-sphere mixtures.

    Science.gov (United States)

    Hopkins, Paul; Schmidt, Matthias

    2011-05-01

    Using fundamental-measure density functional theory we investigate entropic wetting in an asymmetric binary mixture of hard spheres with positive nonadditivity. We consider a general planar hard wall, where preferential adsorption is induced by a difference in closest approach of the different species and the wall. Close to bulk fluid-fluid coexistence, the phase rich in the minority component adsorbs either through a series of first-order layering transitions, where an increasing number of liquid layers adsorbs sequentially, or via a critical wetting transition, where a thick film grows continuously.

  19. Teaching object-oriented programming on top of functional programming

    DEFF Research Database (Denmark)

    Kristensen, Jens Thyge; Hansen, Michael Reichhardt; Richel, Hans

    2001-01-01

    In the Informatics Programme at the Technical University of Denmark, the authors base the first course in object-oriented programming (using the Java language) on a preceding course in functional programming (using the SML language). The students may hence exploit concepts from functional program...

  20. First-Order-Like Phase Transition Induced by Two Different Kinds of Noise in Dispersive Optical Bistability

    Institute of Scientific and Technical Information of China (English)

    HE Ying; ZHU Shi-Qun

    2003-01-01

    With unified colored noise approximation, the steady state distribution function in dispersive opticalbistability including both intensity and phase fluctuations is obtained. The parameter plane of the first-order-like phasetransition is also derived with numerical method. It is found that the number of extremes at non-zero values of theoutput field in the steady state distribution function is changed from zero, two to four. It is shown that the strengths of the intensity fluctuation and the phase fluctuation have great effect on the first-order-like phase transition.

  1. First-Order-Like Phase Transition Induced by Two Different Kinds of Noise in Dispersive Optical Bistability

    Institute of Scientific and Technical Information of China (English)

    HEYing; ZHUShi-Qun

    2003-01-01

    With unified colored noise approximation, the steady state distribution function in dispersive optical bistability including both intensity and phase fluctuations is obtained. The parameter plane of the first-order-like phase transition is a/so derived with numerical method. It is found that the number of extremes at non-zero values of the output field in the steady state distribution function is changed from zero, two to four. It is shown that the strengths of the intensity fluctuation and the phase fluctuation have great effect on the first-order-fike phase transition.

  2. Biotransformation of trace organic chemicals during groundwater recharge: How useful are first-order rate constants?

    KAUST Repository

    Regnery, J.

    2015-05-29

    This study developed relationships between the attenuation of emerging trace organic chemicals (TOrC) during managed aquifer recharge (MAR) as a function of retention time, system characteristics, and operating conditions using controlled laboratory-scale soil column experiments simulating MAR. The results revealed that MAR performance in terms of TOrC attenuation is primarily determined by key environmental parameters (i.e. redox, primary substrate). Soil columns with suboxic and anoxic conditions performed poorly (i.e. less than 30% attenuation of moderately degradable TOrC) in comparison to oxic conditions (on average between 70-100% attenuation for the same compounds) within a residence time of three days. Given this dependency on redox conditions, it was investigated if key parameter-dependent rate constants are more suitable for contaminant transport modeling to properly capture the dynamic TOrC attenuation under field-scale conditions. Laboratory-derived first-order removal kinetics were determined for 19 TOrC under three different redox conditions and rate constants were applied to MAR field data. Our findings suggest that simplified first-order rate constants will most likely not provide any meaningful results if the target compounds exhibit redox dependent biotransformation behavior or if the intention is to exactly capture the decline in concentration over time and distance at field-scale MAR. However, if the intention is to calculate the percent removal after an extended time period and subsurface travel distance, simplified first-order rate constants seem to be sufficient to provide a first estimate on TOrC attenuation during MAR.

  3. A survey of functional programming language principles

    Science.gov (United States)

    Holloway, C. M.

    1986-01-01

    Research in the area of functional programming languages has intensified in the 8 years since John Backus' Turing Award Lecture on the topic was published. The purpose of this paper is to present a survey of the ideas of functional programming languages. The paper assumes the reader is comfortable with mathematics and has knowledge of the basic principles of traditional programming languages, but does not assume any prior knowledge of the ideas of functional languages. A simple functional language is defined and used to illustrate the basic ideas. Topics discussed include the reasons for developing functional languages, methods of expressing concurrency, the algebra of functional programming languages, program transformation techniques, and implementations of functional languages. Existing functional languages are also mentioned. The paper concludes with the author's opinions as to the future of functional languages. An annotated bibliography on the subject is also included.

  4. Magnetic relaxation dynamics driven by the first-order character of magnetocaloric La(Fe,Mn,Si)13.

    Science.gov (United States)

    Lovell, Edmund; Bratko, Milan; Caplin, A David; Barcza, Alexander; Katter, Matthias; Ghivelder, Luis; Cohen, Lesley F

    2016-08-13

    Here, we study the temporal evolution of the magnetic field-driven paramagnetic to ferromagnetic transition in the La(Fe,Mn,Si)13 material family. Three compositions are chosen that show varying strengths of the first-order character of the transition, as determined by the relative magnitude of their magnetic hysteresis and temperature separation between the zero-field transition temperature Tc and the temperature Tcrit, where the transition becomes continuous. Systematic variations in the fixed field, isothermal rate of relaxation are observed as a function of temperature and as a function of the degree of first-order character. The relaxation rate is reduced in more weakly first-order compositions and is also reduced as the temperature is increased towards Tcrit At temperatures above Tcrit, the metastability of the transition vanishes along with its associated temporal dynamics.This article is part of the themed issue 'Taking the temperature of phase transitions in cool materials'.

  5. Classical solutions of mixed problems for quasilinear first order PFDEs on a cylindrical domain

    Directory of Open Access Journals (Sweden)

    Wojciech Czernous

    2014-01-01

    Full Text Available We abandon the setting of the domain as a Cartesian product of real intervals, customary for first order PFDEs (partial functional differential equations with initial boundary conditions. We give a new set of conditions on the possibly unbounded domain \\(\\Omega\\ with Lipschitz differentiable boundary. Well-posedness is then reliant on a variant of the normal vector condition. There is a neighbourhood of \\(\\partial\\Omega\\ with the property that if a characteristic trajectory has a point therein, then its every earlier point lies there as well. With local assumptions on coefficients and on the free term, we prove existence and Lipschitz dependence on data of classical solutions on \\((0,c\\times\\Omega\\ to the initial boundary value problem, for small \\(c\\. Regularity of solutions matches this domain, and the proof uses the Banach fixed-point theorem. Our general model of functional dependence covers problems with deviating arguments and integro-differential equations.

  6. A First-order Prediction-Correction Algorithm for Time-varying (Constrained) Optimization: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Dall-Anese, Emiliano [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-07-25

    This paper focuses on the design of online algorithms based on prediction-correction steps to track the optimal solution of a time-varying constrained problem. Existing prediction-correction methods have been shown to work well for unconstrained convex problems and for settings where obtaining the inverse of the Hessian of the cost function can be computationally affordable. The prediction-correction algorithm proposed in this paper addresses the limitations of existing methods by tackling constrained problems and by designing a first-order prediction step that relies on the Hessian of the cost function (and do not require the computation of its inverse). Analytical results are established to quantify the tracking error. Numerical simulations corroborate the analytical results and showcase performance and benefits of the algorithms.

  7. Discovering a First-Order Phase Transition in the Li-CeO2 System.

    Science.gov (United States)

    Li, Kaikai; Zhou, Xiaoye; Nie, Anmin; Sun, Sheng; He, Yan-Bing; Ren, Wei; Li, Baohua; Kang, Feiyu; Kim, Jang-Kyo; Zhang, Tong-Yi

    2017-02-08

    An in-depth understanding of (de)lithiation induced phase transition in electrode materials is crucial to grasp their structure-property relationships and provide guidance to the design of more desirable electrodes. By operando synchrotron XRD (SXRD) measurement and Density Functional Theory (DFT) based calculations, we discover a reversible first-order phase transition for the first time during (de)lithiation of CeO2 nanoparticles. The LixCeO2 compound phase is identified to possess the same fluorite crystal structure with FM3M space group as that of the pristine CeO2 nanoparticles. The SXRD determined lattice constant of the LixCeO2 compound phase is 0.551 nm, larger than that of 0.541 nm of the pristine CeO2 phase. The DFT calculations further reveal that the Li induced redistribution of electrons causes the increase in the Ce-O covalent bonding, the shuffling of Ce and O atoms, and the jump expansion of lattice constant, thereby resulting in the first-order phase transition. Discovering the new phase transition throws light upon the reaction between lithium and CeO2, and provides opportunities to the further investigation of properties and potential applications of LixCeO2.

  8. Deterministic simulation of first-order scattering in virtual X-ray imaging

    Energy Technology Data Exchange (ETDEWEB)

    Freud, N. E-mail: nicolas.freud@insa-lyon.fr; Duvauchelle, P.; Pistrui-Maximean, S.A.; Letang, J.-M.; Babot, D

    2004-07-01

    A deterministic algorithm is proposed to compute the contribution of first-order Compton- and Rayleigh-scattered radiation in X-ray imaging. This algorithm has been implemented in a simulation code named virtual X-ray imaging. The physical models chosen to account for photon scattering are the well-known form factor and incoherent scattering function approximations, which are recalled in this paper and whose limits of validity are briefly discussed. The proposed algorithm, based on a voxel discretization of the inspected object, is presented in detail, as well as its results in simple configurations, which are shown to converge when the sampling steps are chosen sufficiently small. Simple criteria for choosing correct sampling steps (voxel and pixel size) are established. The order of magnitude of the computation time necessary to simulate first-order scattering images amounts to hours with a PC architecture and can even be decreased down to minutes, if only a profile is computed (along a linear detector). Finally, the results obtained with the proposed algorithm are compared to the ones given by the Monte Carlo code Geant4 and found to be in excellent accordance, which constitutes a validation of our algorithm. The advantages and drawbacks of the proposed deterministic method versus the Monte Carlo method are briefly discussed.

  9. Laboratory automation in a functional programming language.

    Science.gov (United States)

    Runciman, Colin; Clare, Amanda; Harkness, Rob

    2014-12-01

    After some years of use in academic and research settings, functional languages are starting to enter the mainstream as an alternative to more conventional programming languages. This article explores one way to use Haskell, a functional programming language, in the development of control programs for laboratory automation systems. We give code for an example system, discuss some programming concepts that we need for this example, and demonstrate how the use of functional programming allows us to express and verify properties of the resulting code.

  10. The logic of adaptive behavior knowledge representation and algorithms for adaptive sequential decision making under uncertainty in first-order and relational domains

    CERN Document Server

    Van Otterlo, M

    2009-01-01

    Markov decision processes have become the de facto standard in modeling and solving sequential decision making problems under uncertainty. This book studies lifting Markov decision processes, reinforcement learning and dynamic programming to the first-order (or, relational) setting.

  11. Critical dynamical properties of a first-order dissipative phase transition

    Science.gov (United States)

    Casteels, W.; Fazio, R.; Ciuti, C.

    2017-01-01

    We theoretically investigate the critical properties of a single driven-dissipative nonlinear photon mode. In a well-defined thermodynamical limit of large excitation numbers, the exact quantum solution describes a first-order phase transition in the regime where semiclassical theory predicts optical bistability. We study the behavior of the complex spectral gap associated with the Liouvillian superoperator of the corresponding master equation. We show that in this limit the Liouvillian gap vanishes exponentially and that the bimodality of the photon Wigner function disappears. The connection between the considered thermodynamical limit of large photon numbers for the single-mode cavity and the thermodynamical limit of many cavities for a driven-dissipative Bose-Hubbard system is discussed.

  12. Thermodynamics of rotating black branes in gravity with first order string corrections

    Directory of Open Access Journals (Sweden)

    M. H. Dehghani

    2005-09-01

    Full Text Available   In this paper, the rotating black brane solutions with zero curvature horizon of classical gravity with first order string corrections are introduced. Although these solutions are not asymptotically anti de Sitter, one can use the counterterm method in order to compute the conserved quantities of these solutions. Here, by reviewing the counterterm method for asymptotically anti de Sitter spacetimes, the conserved quantities of these rotating solutions are computed. Also a Smarr-type formula for the mass as a function of the entropy and the angular momenta is obtained, and it is shown that the conserved and thermodynamic quantities satisfy the first law of thermodynamics. Finally, a stability analysis in the canonical ensemble is performed, and it is shown that the system is thermally stable. This is in commensurable with the fact that there is no Hawking-Page phase transition for black object with zero curvature horizon.

  13. Studies on the first-order hyperpolarizability and terahertz generation in 3-nitroaniline

    Science.gov (United States)

    Krishnakumar, V.; Nagalakshmi, R.

    2008-05-01

    Single crystals of 3-nitroaniline (C 6H 6N 2O 2) also called as m-nitroaniline ( m-NA) have been grown by adopting slow evaporation solution growth technique at room temperature using methanol as a solvent. To reveal the microscopic nonlinear optical properties, the first-order hyperpolarizability ( β) was evaluated by using the density functional theory (DFT) quantum chemical calculations at B3LYP/3-21 G (d,p) level. According to the results of DFT calculations, the grown crystals exhibit non-zero β values and it might have microscopic nonlinear optical behavior which is seven times more than that of urea. Terahertz (1 THz=10 12 Hz) radiation was also generated in the title organic nonlinear optical crystal using ultra short femtosecond laser.

  14. First-order system least squares for the pure traction problem in planar linear elasticity

    Energy Technology Data Exchange (ETDEWEB)

    Cai, Z.; Manteuffel, T.; McCormick, S.; Parter, S.

    1996-12-31

    This talk will develop two first-order system least squares (FOSLS) approaches for the solution of the pure traction problem in planar linear elasticity. Both are two-stage algorithms that first solve for the gradients of displacement, then for the displacement itself. One approach, which uses L{sup 2} norms to define the FOSLS functional, is shown under certain H{sup 2} regularity assumptions to admit optimal H{sup 1}-like performance for standard finite element discretization and standard multigrid solution methods that is uniform in the Poisson ratio for all variables. The second approach, which is based on H{sup -1} norms, is shown under general assumptions to admit optimal uniform performance for displacement flux in an L{sup 2} norm and for displacement in an H{sup 1} norm. These methods do not degrade as other methods generally do when the material properties approach the incompressible limit.

  15. First-order coil-globule transition driven by vibrational entropy.

    Science.gov (United States)

    Maffi, Carlo; Baiesi, Marco; Casetti, Lapo; Piazza, Francesco; De Los Rios, Paolo

    2012-01-01

    By shifting the balance between conformational entropy and internal energy, polymers modify their shape under external stimuli, such as changes in temperature. Prominent among such transformations is the coil-globule transition, whereby a polymer can switch from an entropy-dominated coil conformation to a globular one, governed by energy. The nature of the coil-globule transition has remained elusive, with evidence for both continuous and discontinuous transitions, with the two-state behaviour of proteins as an instance of the latter. Theoretical models mostly predict second-order transitions. Here we introduce a model that takes into consideration hitherto neglected features common to any polymer. We show that a first-order phase transition smoothly appears as a function of the model parameters. Our results can relieve part of the conflicts between theory and experiments in the field of protein folding, in the wake of recent studies tracing back the remarkable properties of proteins to basic polymer physics.

  16. A boundary field induced first-order transition in the 2D Ising model: numerical study

    Energy Technology Data Exchange (ETDEWEB)

    Bittner, Elmar; Janke, Wolfhard [Institut fuer Theoretische Physik and Centre for Theoretical Sciences (NTZ), Universitaet Leipzig, Postfach 100 920, D-04009 Leipzig (Germany)], E-mail: elmar.bittner@itp.uni-leipzig.de, E-mail: Wolfhard.janke@itp.uni-leipzig.de

    2008-10-03

    In a recent paper, Clusel and Fortin (2006 J. Phys. A: Math. Gen. 39 995) presented an analytical study of a first-order transition induced by an inhomogeneous boundary magnetic field in the two-dimensional Ising model. They identified the transition that separates the regime where the interface is localized near the boundary from that where it propagates inside the bulk. Inspired by these results, we measured the interface tension by using multimagnetic simulations combined with parallel tempering to determine the phase transition and the location of the interface. Our results are in very good agreement with the theoretical predictions. Furthermore, we studied the spin-spin correlation function for which no analytical results are available.

  17. Application of finite difference method in the study of diffusion with chemical kinetics of first order

    Directory of Open Access Journals (Sweden)

    Beltrán-Prieto Juan Carlos

    2016-01-01

    Full Text Available The mathematical modelling of diffusion of a bleaching agent into a porous material is studied in the present paper. Law of mass conservation was applied to analize the mass transfer of a reactant from the bulk into the external surface of a solid geometrically described as a flat plate. After diffusion of the reactant, surface reaction following kinetics of first order was considered to take place. The solution of the differential equation that described the process leaded to an equation that represents the concentration profile in function of distance, porosity and Thiele modulus. The case of interfacial mass resistance is also discused. In this case, finite difference method was used for the solution of the differential equation taking into account the respective boundary conditions. The profile of concentration can be obtained after numerical especification of Thiele modulus and Biot number.

  18. Efficient robust control of first order scalar conservation laws using semi-analytical solutions

    KAUST Repository

    Li, Yanning

    2014-01-01

    This article presents a new robust control framework for transportation problems in which the state is modeled by a first order scalar conservation law. Using an equivalent formulation based on a Hamilton-Jacobi equation, we pose the problem of controlling the state of the system on a network link, using initial density control and boundary flow control, as a Linear Program. We then show that this framework can be extended to arbitrary control problems involving the control of subsets of the initial and boundary conditions. Unlike many previously investigated transportation control schemes, this method yields a globally optimal solution and is capable of handling shocks (i.e. discontinuities in the state of the system). We also demonstrate that the same framework can handle robust control problems, in which the uncontrollable components of the initial and boundary conditions are encoded in intervals on the right hand side of inequalities in the linear program. The lower bound of the interval which defines the smallest feasible solution set is used to solve the robust LP/MILP. Since this framework leverages the intrinsic properties of the Hamilton-Jacobi equation used to model the state of the system, it is extremely fast. Several examples are given to demonstrate the performance of the robust control solution and the trade-off between the robustness and the optimality.

  19. Modeling of metamagnetism in metallic-based materials with first-order transitions

    Energy Technology Data Exchange (ETDEWEB)

    Yi Jin, E-mail: yijin@gwmail.gwu.edu [Institute for Magnetics Research, George Washington University, Washington DC 20052 (United States); Gu Shuo; Della Torre, Edward; Bennett, Lawrence H. [Institute for Magnetics Research, George Washington University, Washington DC 20052 (United States); Provenzano, Virgil [Metallurgy Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States)

    2012-05-01

    During the past decade, the magnetic properties of metallic-based materials with first-order transitions have been extensively studied, motivated in part by the observation of large magnetocaloric effect (MCE) peaks displayed by these materials near room temperature. These large peaks are believed to be the result of the materials' magnetic properties at the metamagnetic region, characterized by (i) the thermal-induced transition from the ferromagnetic state (FM) to the paramagnetic state (PM) near the Curie temperature (T{sub C}) and (ii) the field-induced transition from PM state to FM state above T{sub C}. We developed a phenomenological model that utilizes the materials' mixed-state probability function to model the materials' complex hysteretic and properties at metamagnetic region. The approximate probability functions are obtained from the first and second derivatives of the magnetization curve. The probability functions are used to separate the materials' magnetization into a FM state component and a PM state component. The applicability of the model is demonstrated for a metallic-based metamagnetic material, Gd{sub 5}Si{sub 2}Ge{sub 2} compound, where the modeled behaviors show remarkable agreement with the experimental data at the metamagnetic region and provide new physical insights in this mixed-state region. Specifically, in the region of metamagnetic transition, the PM state component is non-reversible and is a function of the FM state component.

  20. Analytic expressions for first order correction to inviscid unsteady forces due to surrounding particles in a multiphase flow

    Science.gov (United States)

    Annamalai, Subramanian; Balachandar, S.; Mehta, Yash

    2015-11-01

    The various inviscid and viscous forces experienced by an isolated spherical particle situated in a compressible fluid have been widely studied in literature and are well established. Further, these force expressions are used even in the context of particulate (multiphase) flows with appropriate empirical correction factors that depend on local particle volume fraction. Such approach can capture the mean effect of the neighboring particles, but fails to capture the effect of the precise arrangement of the neighborhood of particles. To capture this inherent dependence of force on local particle arrangement a more accurate evaluation of the drag forces proves necessary. Towards this end, we consider an acoustic wave of a given frequency to impinge on a sphere. Scattering due to this particle (reference) is computed and termed ``scattering coefficients.'' The effect of the reference particle on another particle in its vicinity, is analytically computed via the above mentioned ``scattering coefficients'' and as a function of distance between particles. In this study, we consider only the first-order scattering effect. Moreover, this theory is extended to compressible spheres and used to compute the pressure in the interior of the sphere and to shock interaction over an array of spheres. We would like to thank the center for compressible multiphase turbulence (CCMT) and acknowledge support from the U.S. Department of Energy, National Nuclear Security Administration, Advanced Simulation and Computing Program.

  1. On new solutions of linear system of first -order fuzzy differential equations with fuzzy coefficient

    Directory of Open Access Journals (Sweden)

    A. Karimi Dizicheh

    2016-03-01

    Full Text Available In this paper, we firstly introduce system of first order fuzzy differential equations. Then, we convert the problem to two crisp systems of first order differential equations. For numerical aspects, we apply exponentially fitted Runge Kutta method to solve the fuzzy problems. We solve some well-known examples in order to demonstrate the applicability and accuracy of results.

  2. POSITIVE SOLUTIONS TO SYSTEMS OF SECOND ORDER NONLOCAL BOUNDARY VALUE PROBLEMS WITH FIRST ORDER DERIVATIVES

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    This paper investigates the existence of positive solutions to systems of second order nonlocal boundary value problems with first order derivatives, in which the nonlinear term is not required to be continuous and involves first order derivatives. The main tool used in this paper is a fixed point index theory in a cone.

  3. Buckling analysis of laminated plates using the extended Kantorovich method and a system of first-order differential equations

    Energy Technology Data Exchange (ETDEWEB)

    Singhatanadgid, Pairod; Jommalai, Panupan [Chulalongkorn University, Bangkok (Thailand)

    2016-05-15

    The extended Kantorovich method using multi-term displacement functions is applied to the buckling problem of laminated plates with various boundary conditions. The out-of-plane displacement of the buckled plate is written as a series of products of functions of parameter x and functions of parameter y. With known functions in parameter x or parameter y, a set of governing equations and a set of boundary conditions are obtained after applying the variational principle to the total potential energy of the system. The higher order differential equations are then transformed into a set of first-order differential equations and solved for the buckling load and mode. Since the governing equations are first-order differential equations, solutions can be obtained analytically with the out-of-plane displacement written in the form of an exponential function. The solutions from the proposed technique are verified with solutions from the literature and FEM solutions. The bucking loads correspond very well to other available solutions in most of the comparisons. The buckling modes also compare very well with the finite element solutions. The proposed solution technique transforms higher-order differential equations to first-order differential equations, and they are analytically solved for out-of-plane displacement in the form of an exponential function. Therefore, the proposed solution technique yields a solution which can be considered as an analytical solution.

  4. MatLab Script and Functional Programming

    Science.gov (United States)

    Shaykhian, Gholam Ali

    2007-01-01

    MatLab Script and Functional Programming: MatLab is one of the most widely used very high level programming languages for scientific and engineering computations. It is very user-friendly and needs practically no formal programming knowledge. Presented here are MatLab programming aspects and not just the MatLab commands for scientists and engineers who do not have formal programming training and also have no significant time to spare for learning programming to solve their real world problems. Specifically provided are programs for visualization. The MatLab seminar covers the functional and script programming aspect of MatLab language. Specific expectations are: a) Recognize MatLab commands, script and function. b) Create, and run a MatLab function. c) Read, recognize, and describe MatLab syntax. d) Recognize decisions, loops and matrix operators. e) Evaluate scope among multiple files, and multiple functions within a file. f) Declare, define and use scalar variables, vectors and matrices.

  5. 趣谈Functional Programming

    Institute of Scientific and Technical Information of China (English)

    恶魔

    2004-01-01

    本文的下半部分不乏枯燥的数学理论知识和哲学思想,然而这些真正的“基本思想”才是Functional Programming的核心所在。如果您足够耐心,相信您将通过本文受益匪浅。

  6. Reliability Estimation of the Pultrusion Process Using the First-Order Reliability Method (FORM)

    Science.gov (United States)

    Baran, Ismet; Tutum, Cem C.; Hattel, Jesper H.

    2013-08-01

    In the present study the reliability estimation of the pultrusion process of a flat plate is analyzed by using the first order reliability method (FORM). The implementation of the numerical process model is validated by comparing the deterministic temperature and cure degree profiles with corresponding analyses in the literature. The centerline degree of cure at the exit (CDOCE) being less than a critical value and the maximum composite temperature ( T max) during the process being greater than a critical temperature are selected as the limit state functions (LSFs) for the FORM. The cumulative distribution functions of the CDOCE and T max as well as the correlation coefficients are obtained by using the FORM and the results are compared with corresponding Monte-Carlo simulations (MCS). According to the results obtained from the FORM, an increase in the pulling speed yields an increase in the probability of T max being greater than the resin degradation temperature. A similar trend is also seen for the probability of the CDOCE being less than 0.8.

  7. Fuzzy stochastic generalized reliability studies on embankment systems based on first-order approximation theorem

    Institute of Scientific and Technical Information of China (English)

    Wang Yajun; Zhang Wohua; Jin Weiliang; Wu Changyu; Ren Dachun

    2008-01-01

    In order to address the complex uncertainties caused by interfacing between the fuzziness and randomness of the safety problem for embankment engineering projects, and to evaluate the safety of embankment engineering projects more scientifically and reasonably, this study presents the fuzzy logic modeling of the stochastic finite element method (SFEM) based on the harmonious finite element (HFE) technique using a first-order approximation theorem. Fuzzy mathematical models of safety repertories were introduced into the SFEM to analyze the stability of embankments and foundations in order to describe the fuzzy failure procedure for the random safety performance function. The fuzzy models were developed with membership functions with half depressed gamma distribution, half depressed normal distribution, and half depressed echelon distribution. The fuzzy stochastic mathematical algorithm was used to comprehensively study the local failure mechanism of the main embankment section near Jingnan in the Yangtze River in terms of numerical analysis for the probability integration of reliability on the random field affected by three fuzzy factors. The result shows that the middle region of the embankment is the principal zone of concentrated failure due to local fractures. There is also some local shear failure on the embankment crust. This study provides a referential method for solving complex multi-uncertainty problems in engineering safety analysis.

  8. Nonlinear first order PDEs reducible to autonomous form polynomially homogeneous in the derivatives

    Science.gov (United States)

    Gorgone, Matteo; Oliveri, Francesco

    2017-03-01

    It is proved a theorem providing necessary and sufficient conditions enabling one to map a nonlinear system of first order partial differential equations, polynomial in the derivatives, to an equivalent autonomous first order system polynomially homogeneous in the derivatives. The result is intimately related to the symmetry properties of the source system, and the proof, involving the use of the canonical variables associated to the admitted Lie point symmetries, is constructive. First order Monge-Ampère systems, either with constant coefficients or with coefficients depending on the field variables, where the theorem can be successfully applied, are considered.

  9. C-band fundamental/first-order mode converter based on multimode interference coupler on InP substrate

    Science.gov (United States)

    Limeng, Zhang; Dan, Lu; Zhaosong, Li; Biwei, Pan; Lingjuan, Zhao

    2016-12-01

    The design, fabrication and characterization of a fundamental/first-order mode converter based on multimode interference coupler on InP substrate were reported. Detailed optimization of the device parameters were investigated using 3D beam propagation method. In the experiments, the fabricated mode converter realized mode conversion from the fundamental mode to the first-order mode in the wavelength range of 1530-1565 nm with excess loss less than 3 dB. Moreover, LP01 and LP11 fiber modes were successfully excited from a few-mode fiber by using the device. This InP-based mode converter can be a possible candidate for integrated transceivers for future mode-division multiplexing system. Project supported by the National Basic Research Program of China (No. 2014CB340102) and in part by the National Natural Science Foundation of China (Nos. 61274045, 61335009).

  10. Analytical First-Order Molecular Properties and Forces within the Adiabatic Connection Random Phase Approximation.

    Science.gov (United States)

    Burow, Asbjörn M; Bates, Jefferson E; Furche, Filipp; Eshuis, Henk

    2014-01-14

    The random phase approximation (RPA) is an increasingly popular method for computing molecular ground-state correlation energies within the adiabatic connection fluctuation-dissipation theorem framework of density functional theory. We present an efficient analytical implementation of first-order RPA molecular properties and nuclear forces using the resolution-of-the-identity (RI) approximation and imaginary frequency integration. The centerpiece of our approach is a variational RPA energy Lagrangian invariant under unitary transformations of occupied and virtual reference orbitals, respectively. Its construction requires the solution of a single coupled-perturbed Kohn-Sham equation independent of the number of perturbations. Energy gradients with respect to nuclear displacements and other first-order properties such as one-particle densities or dipole moments are obtained from partial derivatives of the Lagrangian. Our RPA energy gradient implementation exhibits the same [Formula: see text] scaling with system size N as a single-point RPA energy calculation. In typical applications, the cost for computing the entire gradient vector with respect to nuclear displacements is ∼5 times that of a single-point RPA energy calculation. Derivatives of the quadrature nodes and weights used for frequency integration are essential for RPA gradients with an accuracy consistent with RPA energies and can be included in our approach. The quality of RPA equilibrium structures is assessed by comparison to accurate theoretical and experimental data for covalent main group compounds, weakly bonded dimers, and transition metal complexes. RPA outperforms semilocal functionals as well as second-order Møller-Plesset (MP2) theory, which fails badly for the transition metal compounds. Dipole moments of polarizable molecules and weakly bound dimers show a similar trend. RPA harmonic vibrational frequencies are nearly of coupled cluster singles, doubles, and perturbative triples quality

  11. Functional Logic Programming with Generalized Circular Coinduction

    CERN Document Server

    de Haan, Ronald

    2012-01-01

    We propose a method to adapt functional logic programming to deal with reasoning on coinductively interpreted programs as well as on inductively interpreted programs. In order to do so, we consider a class of objects interesting for this coinductive interpretation, namely regular terms. We show how the usual data structures can be adapted to capture these objects. We adapt the operational semantics of Curry to interpret programs coinductively. We illustrate this method with several examples that show the working of our method and several cases in which it could be useful. Finally, we suggest how the declarative semantics can be adapted suitably.

  12. A first-order matrix approach to the analysis of electron beam emittance growth caused by coherent synchrotron radiation

    CERN Document Server

    Hajima, R

    2003-01-01

    A first-order transform matrix is proposed for calculating electron beam emittance dilution arising from coherent synchrotron radiation (CSR) in a next-generation light source based on an energy-recovery linac. The matrix approach enables us to scan numerous parameters for the design of achromatic cells of minimum emittance dilution. The emittance dilution can be minimized when the envelope of CSR wake dispersion matches the betatron function envelope at the achromatic cell exit. (author)

  13. Quantum adiabatic algorithm and scaling of gaps at first-order quantum phase transitions.

    Science.gov (United States)

    Laumann, C R; Moessner, R; Scardicchio, A; Sondhi, S L

    2012-07-20

    Motivated by the quantum adiabatic algorithm (QAA), we consider the scaling of the Hamiltonian gap at quantum first-order transitions, generally expected to be exponentially small in the size of the system. However, we show that a quantum antiferromagnetic Ising chain in a staggered field can exhibit a first-order transition with only an algebraically small gap. In addition, we construct a simple classical translationally invariant one-dimensional Hamiltonian containing nearest-neighbor interactions only, which exhibits an exponential gap at a thermodynamic quantum first-order transition of essentially topological origin. This establishes that (i) the QAA can be successful even across first-order transitions but also that (ii) it can fail on exceedingly simple problems readily solved by inspection, or by classical annealing.

  14. Propagators of Generalized Schrödinger Equations Related by First-order Supersymmetry

    Directory of Open Access Journals (Sweden)

    A. Schulze-Halberg

    2011-01-01

    Full Text Available We construct an explicit relation between propagators of generalized Schrödinger equations that are linked by a first-order supersymmetric transformation. Our findings extend and complement recent results on the conventional case [1].

  15. Existence and attractivity results for nonlinear first order random differential equations

    Directory of Open Access Journals (Sweden)

    Bapurao C. Dhage

    2010-01-01

    Full Text Available In this paper, the existence and attractivity results are proved for nonlinear first order ordinary random differential equations. Two examples are provided to demonstrate the realization of the abstract developed theory.

  16. Discrete Methods Based on First Order Reversal Curves to Identify Preisach Model of Smart Materials

    Institute of Scientific and Technical Information of China (English)

    LI Fan; ZHAO Jian-hui

    2007-01-01

    Preisach model is widely used in modeling of smart materials. Although first order reversal curves (FORCs) have often found applications in the fields of physics and geology, they are able to serve to identify Preisach model. In order to clarify the relationship between the Preisach model and the first order reversal curves, this paper is directed towards: (1) giving the reason a first order reversal curve is introduced; (2) presenting, for identifying Preisach model, two discrete methods, which are analytically based on first order reversal curves. Herein also is indicated the solution's uniqueness of these two identifying methods. At last, the validity of these two methods is verified by simulating a real smart actuator both methods have been applied to.

  17. Existential Second Order Logic Expression With Horn First Order for Max Clique (Decision Version)

    CERN Document Server

    Manyem, Prabhu

    2010-01-01

    We will show that the maximum clique problem (decision version) can be expressed in existential second order (ESO) logic, where the first order part is a Horn formula in second-order quantified predicates.

  18. First-order phase transition in $1d$ Potts model with long-range interactions

    OpenAIRE

    Uzelac, K.; Glumac, Z.

    1998-01-01

    The first-order phase transition in the one-dimensional $q$-state Potts model with long-range interactions decaying with distance as $1/r^{1+\\sigma}$ has been studied by Monte Carlo numerical simulations for $0 2$. On the basis of finite-size scaling analysis of interface free energy $\\Delta F_L$, specific heat and Binder's fourth order cumulant, we obtain the first-order transition which occurs for $\\sigma$ below a threshold value $\\sigma_c(q)$.

  19. Metamaterial-Inspired First-Order Probe for Spherical Near-Field Antenna Measurements

    DEFF Research Database (Denmark)

    Kim, Oleksiy S.; Breinbjerg, Olav

    2011-01-01

    A first-order probe based on a two-element split ring resonator (SRR) array is presented. The probe is applicable at low frequencies due to its small size and excellent mode content.......A first-order probe based on a two-element split ring resonator (SRR) array is presented. The probe is applicable at low frequencies due to its small size and excellent mode content....

  20. A first-order dynamical model of hierarchical triple stars and its application

    CERN Document Server

    Xu, Xingbo; Fu, Yanning

    2015-01-01

    For most hierarchical triple stars, the classical double two-body model of zeroth-order cannot describe the motions of the components under the current observational accuracy. In this paper, Marchal's first-order analytical solution is implemented and a more efficient simplified version is applied to real triple stars. The results show that, for most triple stars, the proposed first-order model is preferable to the zeroth-order model either in fitting observational data or in predicting component positions.

  1. The metatheory of first-order logic: a contribution to a defence of Principia Mathematica

    CERN Document Server

    Boyce, Stephen

    2010-01-01

    This paper presents evidence that Principia Mathematica's account of first-order logic may be superior to currently accepted classical rivals. It is shown firstly that difficulties arise if one attempts to express the metatheory of contemporary first-order logic in a first-order set theory equivalent to NBG set theory since the notion of a domain of interpretation (of the a first-order language) cannot be a class (proper or otherwise). This is a pressing problem, since if the metatheory is left informal it appears that one can define absurd entities in the metatheory - such as the domain D of an interpretation M of a first-order language L that contains a domain E of an interpretation N of L if and only if E is not identical with any individual in E (hence D is identical with some individual in D if and only if it is not). An alternative view of first-order logic, derived from Principia, is then presented. It is shown that Principia avoids the problem just discussed and that a number of widely accepted critic...

  2. On the BICM Capacity - Part I: Binary Labelings, Arbitrary Input Distributions, and First-Order Asymptotics

    CERN Document Server

    Alvarado, Alex

    2010-01-01

    In this semitutorial paper (Part I of a two-part paper), the capacity of bit-interleaved coded modulation (BICM) is analyzed. We introduce a general model for BICM which considers all the variables affecting the BICM capacity: the binary labeling, the input distribution, and the signal set. We show that the relation between the BICM capacity and Eb/N0 is not always a one-to-one function, we analyze how to increase the BICM capacity by modifying the input symbol distribution, and we develop first-order asymptotics of the BICM capacity for constellations with arbitrary input distributions, dimensions, mean, variance, and binary labeling. For 8-ary pulse amplitude modulation (PAM) and around Es/N0=0 dB (0.75 bit/symbol), the folded binary code (FBC) results in a higher capacity than the binary reflected gray code (BRGC) and the natural binary code (NBC). For the same SNR, the 1 dB gap between the additive white Gaussian noise (AWGN) capacity and the BICM capacity can be reduced to 0.2 dB if the input symbol dist...

  3. Modified landfill gas generation rate model of first-order kinetics and two-stage reaction

    Institute of Scientific and Technical Information of China (English)

    Jiajun CHEN; Hao WANG; Na ZHANG

    2009-01-01

    This investigation was carried out to establish a new domestic landfill gas (LFG) generation rate model that takes into account the impact ofleachate recirculation. The first-order kinetics and two-stage reaction (FKTSR) model of the LFG generation rate includes mechanisms of the nutrient balance for biochemical reaction in two main stages. In this study, the FKTSR model was modified by the introduction of the outflow function and the organic acid conversion coefficient in order to represent the in-situ condition of nutrient loss through leachate. Laboratory experiments were carried out to simulate the impact of leachate recirculation and verify the modified FKTSR model. The model calibration was then calculated by using the experimental data. The results suggested that the new model was in line with the experimental data. The main parameters of the modified FKTSR model, including the LFG production potential (L0), the reaction rate constant in the first stage (K1), and the reaction rate constant in the second stage (K2) of 64.746 L, 0.202 d-1, and 0.338 d-1,respectively, were comparable to the old ones of 42.069 L,0.231 d-1, and 0.231 d-1. The new model is better able to explain the mechanisms involved in LFG generation.

  4. First-order quantum phase transitions: Test ground for emergent chaoticity, regularity and persisting symmetries

    Energy Technology Data Exchange (ETDEWEB)

    Macek, M., E-mail: mmacek@Racah.phys.huji.ac.il; Leviatan, A., E-mail: ami@phys.huji.ac.il

    2014-12-15

    We present a comprehensive analysis of the emerging order and chaos and enduring symmetries, accompanying a generic (high-barrier) first-order quantum phase transition (QPT). The interacting boson model Hamiltonian employed, describes a QPT between spherical and deformed shapes, associated with its U(5) and SU(3) dynamical symmetry limits. A classical analysis of the intrinsic dynamics reveals a rich but simply-divided phase space structure with a Hénon–Heiles type of chaotic dynamics ascribed to the spherical minimum and a robustly regular dynamics ascribed to the deformed minimum. The simple pattern of mixed but well-separated dynamics persists in the coexistence region and traces the crossing of the two minima in the Landau potential. A quantum analysis discloses a number of regular low-energy U(5)-like multiplets in the spherical region, and regular SU(3)-like rotational bands extending to high energies and angular momenta, in the deformed region. These two kinds of regular subsets of states retain their identity amidst a complicated environment of other states and both occur in the coexistence region. A symmetry analysis of their wave functions shows that they are associated with partial U(5) dynamical symmetry (PDS) and SU(3) quasi-dynamical symmetry (QDS), respectively. The pattern of mixed but well-separated dynamics and the PDS or QDS characterization of the remaining regularity, appear to be robust throughout the QPT. Effects of kinetic collective rotational terms, which may disrupt this simple pattern, are considered.

  5. Agricultural herbicide transport in a first-order intermittent stream, Nebraska, USA

    Science.gov (United States)

    Vogel, J.R.; Linard, J.I.

    2011-01-01

    The behavior of herbicides in surface waters is a function of many variables, including scale of the watershed, physical and chemical properties of the herbicide, physical and chemical properties of the soil, rainfall intensity, and time of year. In this study, the transport of 6 herbicides and 12 herbicide degradates was examined during the 2004 growing season in an intermediate-scale agricultural watershed (146 ha) that is drained by a first-order intermittent stream, and the mass load for each herbicide in the stream was estimated. The herbicide load during the first week of storm events after application ranged from 17% of annual load for trifluralin to 84% of annual load for acetochlor. The maximum weekly herbicide load in the stream was generally within the first 3 weeks after application for those compounds that were applied within the watershed during 2004, and later for herbicides not applied within the watershed during 2004 but still detected in the stream. The apparent dominant mode of herbicide transport in the stream-determined by analysis amongst herbicide and conservative ion concentrations at different points in the hydrograph and in base flow samples-was either overland runoff or shallow subsurface flow, depending on the elapsed time after application and type of herbicide. The load as a percentage of use (LAPU) for the parent compounds in this study was similar to literature values for those compounds applied by the farmer within the watershed, but smaller for those herbicides that had rainfall as their only source within the watershed.

  6. First-order reversal curve (FORC) diagrams of natural and cultured biogenic magnetic particles

    Science.gov (United States)

    Chen, Amy P.; Egli, Ramon; Moskowitz, Bruce M.

    2007-08-01

    First-order reversal curve (FORC) diagrams are rapidly becoming a standard tool for characterizing magnetic particles because they simultaneously incorporate information regarding magnetostatic interaction and domain states. The simplest interpretation of FORC diagrams of single-domain (SD) particles is based on the Neel interpretation of Preisach theory, which predicts that the FORC function is the product of a coercivity and an interaction field distribution. Although the underlying assumptions of this interpretation are not correct, a strictly quantitative model of weakly interacting SD grains proves that the distributions of coercivities and interaction fields can be retrieved from a FORC diagram. To test this model, we present the possibility of a quantitative interpretation of FORC diagrams, and we present measurements of samples containing magnetosomes from cultures of magnetotactic bacteria and from a lake sediment. Two samples are investigated under the electron microscope to characterize the geometrical arrangement of the particles. We find that the clustering of otherwise similar particles has a strong influence on FORC diagrams. We also obtained a crude estimate of packing densities form the FORC diagrams, which were consistent with transmission electron microscopy observations and measurements of the anhysteretic remanent magnetization.

  7. Mechanically clamped PZT ceramics investigated by First-order reversal curves diagram

    Directory of Open Access Journals (Sweden)

    Laurentiu Stoleriu

    2010-09-01

    Full Text Available The First Order Reversal Curves (FORC diagrams method was developed for characterizing the switching properties of ferroelectrics. In the present paper, the FORC method was applied for hard Pb(Zr,TiO3 ceramics with symmetric and asymmetric clamping. An ideal high-oriented single-crystalline ferroelectric with rectangular P(E loop would be characterised by a delta-function FORC distribution, while real ferroelectrics and mostly the polycrystalline ceramics show dispersed FORC distributions. All the investigated ceramics show FORC distributions with non-Gaussian shape, slightly elongated along the coercitive axis, meaning a high dispersion of the energy barriers separating the two bi-stable polarizations ±P. The degree of dispersion is enhanced by clamping. The maximum FORC coercivity is located at ~ (1.9-2 MV/m for all the hard ceramics. The FORC cycling experiment causes the reversal of the initial poling and result in a positive/negative bias on the FORC diagrams. According to the observed features, it results that FORC coercivity is more related to the nature of the material, while the bias field is more sensitive to the electrical and mechanical boundary conditions in which the ferroelectric ceramics evolves while switching.

  8. Generalized ensemble method applied to study systems with strong first order transitions

    Science.gov (United States)

    Małolepsza, E.; Kim, J.; Keyes, T.

    2015-09-01

    At strong first-order phase transitions, the entropy versus energy or, at constant pressure, enthalpy, exhibits convex behavior, and the statistical temperature curve correspondingly exhibits an S-loop or back-bending. In the canonical and isothermal-isobaric ensembles, with temperature as the control variable, the probability density functions become bimodal with peaks localized outside of the S-loop region. Inside, states are unstable, and as a result simulation of equilibrium phase coexistence becomes impossible. To overcome this problem, a method was proposed by Kim, Keyes and Straub [1], where optimally designed generalized ensemble sampling was combined with replica exchange, and denoted generalized replica exchange method (gREM). This new technique uses parametrized effective sampling weights that lead to a unimodal energy distribution, transforming unstable states into stable ones. In the present study, the gREM, originally developed as a Monte Carlo algorithm, was implemented to work with molecular dynamics in an isobaric ensemble and coded into LAMMPS, a highly optimized open source molecular simulation package. The method is illustrated in a study of the very strong solid/liquid transition in water.

  9. A time series model: First-order integer-valued autoregressive (INAR(1))

    Science.gov (United States)

    Simarmata, D. M.; Novkaniza, F.; Widyaningsih, Y.

    2017-07-01

    Nonnegative integer-valued time series arises in many applications. A time series model: first-order Integer-valued AutoRegressive (INAR(1)) is constructed by binomial thinning operator to model nonnegative integer-valued time series. INAR (1) depends on one period from the process before. The parameter of the model can be estimated by Conditional Least Squares (CLS). Specification of INAR(1) is following the specification of (AR(1)). Forecasting in INAR(1) uses median or Bayesian forecasting methodology. Median forecasting methodology obtains integer s, which is cumulative density function (CDF) until s, is more than or equal to 0.5. Bayesian forecasting methodology forecasts h-step-ahead of generating the parameter of the model and parameter of innovation term using Adaptive Rejection Metropolis Sampling within Gibbs sampling (ARMS), then finding the least integer s, where CDF until s is more than or equal to u . u is a value taken from the Uniform(0,1) distribution. INAR(1) is applied on pneumonia case in Penjaringan, Jakarta Utara, January 2008 until April 2016 monthly.

  10. The Core Method: Connectionist Model Generation for First-Order Logic Programs

    NARCIS (Netherlands)

    Bader, S.; Hitzler, P.; Hölldobler, S.; Witzel, A.; Hammer, B.; Hitzler, P.

    2007-01-01

    Knowledge based artificial networks networks have been applied quite successfully to propositional knowledge representation and reasoning tasks. However, as soon as these tasks are extended to structured objects and structure-sensitive processes it is not obvious at all how neural symbolic systems s

  11. PID controller tuning for the first-order-plus-dead-time process model via Hermite-Biehler theorem.

    Science.gov (United States)

    Roy, Anindo; Iqbal, Kamran

    2005-07-01

    This paper discusses PID stabilization of a first-order-plus-dead-time (FOPDT) process model using the stability framework of the Hermite-Biehler theorem. The FOPDT model approximates many processes in the chemical and petroleum industries. Using a PID controller and first-order Padé approximation for the transport delay, the Hermite-Biehler theorem allows one to analytically study the stability of the closed-loop system. We derive necessary and sufficient conditions for stability and develop an algorithm for selection of stabilizing feedback gains. The results are given in terms of stability bounds that are functions of plant parameters. Sensitivity and disturbance rejection characteristics of the proposed PID controller are studied. The results are compared with established tuning methods such as Ziegler-Nichols, Cohen-Coon, and internal model control.

  12. Classical and quantum Reissner-Nordström black hole thermodynamics and first order phase transition

    Science.gov (United States)

    Ghaffarnejad, Hossein

    2016-01-01

    First we consider classical Reissner-Nordström black hole (CRNBH) metric which is obtained by solving Einstein-Maxwell metric equation for a point electric charge e inside of a spherical static body with mass M. It has 2 interior and exterior horizons. Using Bekenstein-Hawking entropy theorem we calculate interior and exterior entropy, temperature, Gibbs free energy and heat capacity at constant electric charge. We calculate first derivative of the Gibbs free energy with respect to temperature which become a singular function having a singularity at critical point Mc=2|e|/√{3} with corresponding temperature Tc=1/24π√{3|e|}. Hence we claim first order phase transition is happened there. Temperature same as Gibbs free energy takes absolutely positive (negative) values on the exterior (interior) horizon. The Gibbs free energy takes two different positive values synchronously for 0< T< Tc but not for negative values which means the system is made from two subsystem. For negative temperatures entropy reaches to zero value at Tto-∞ and so takes Bose-Einstein condensation single state. Entropy increases monotonically in case 0< T< Tc. Regarding results of the work presented at Wang and Huang (Phys. Rev. D 63:124014, 2001) we calculate again the mentioned thermodynamical variables for remnant stable final state of evaporating quantum Reissner-Nordström black hole (QRNBH) and obtained results same as one in case of the CRNBH. Finally, we solve mass loss equation of QRNBH against advance Eddington-Finkelstein time coordinate and derive luminosity function. We obtain switching off of QRNBH evaporation before than the mass completely vanishes. It reaches to a could Lukewarm type of RN black hole which its final remnant mass is m_{final}=|e| in geometrical units. Its temperature and luminosity vanish but not in Schwarzschild case of evaporation. Our calculations can be take some acceptable statements about information loss paradox (ILP).

  13. Functional Localization of Genetic Network Programming

    Science.gov (United States)

    Eto, Shinji; Hirasawa, Kotaro; Hu, Jinglu

    According to the knowledge of brain science, it is suggested that there exists cerebral functional localization, which means that a specific part of the cerebrum is activated depending on various kinds of information human receives. The aim of this paper is to build an artificial model to realize functional localization based on Genetic Network Programming (GNP), a new evolutionary computation method recently developed. GNP has a directed graph structure suitable for realizing functional localization. We studied the basic characteristics of the proposed system by making GNP work in a functionally localized way.

  14. Improved first-order uncertainty method for water-quality modeling

    Science.gov (United States)

    Melching, C.S.; Anmangandla, S.

    1992-01-01

    Uncertainties are unavoidable in water-quality modeling and subsequent management decisions. Monte Carlo simulation and first-order uncertainty analysis (involving linearization at central values of the uncertain variables) have been frequently used to estimate probability distributions for water-quality model output due to their simplicity. Each method has its drawbacks: Monte Carlo simulation's is mainly computational time; and first-order analysis are mainly questions of accuracy and representativeness, especially for nonlinear systems and extreme conditions. An improved (advanced) first-order method is presented, where the linearization point varies to match the output level whose exceedance probability is sought. The advanced first-order method is tested on the Streeter-Phelps equation to estimate the probability distribution of critical dissolved-oxygen deficit and critical dissolved oxygen using two hypothetical examples from the literature. The advanced first-order method provides a close approximation of the exceedance probability for the Streeter-Phelps model output estimated by Monte Carlo simulation using less computer time - by two orders of magnitude - regardless of the probability distributions assumed for the uncertain model parameters.

  15. On the Dirichlet Problem for First Order Linear Hyperbolic PDEs on Bounded Domains with Mere Inflow Boundary

    CERN Document Server

    März, Thomas

    2010-01-01

    Here we study the Dirichlet problem for first order linear and quasi-linear hyperbolic PDEs on a simply connected bounded domain of $\\R^2$, where the domain has an interior outflow set and a mere inflow boundary. By means of a Lyapunov function we show the existence of a unique solution in the space of functions of bounded variation and its continuous dependence on all the data of the linear problem. Finally, we conclude the existence of a solution to the quasi-linear case by utilizing the Schauder fixed point theorem. This type of problems considered here appears in applications such as transport based image inpainting.

  16. Mass and Angular Momentum of Black Holes in Three Dimensional Gravity Theories with First Order Formalism

    CERN Document Server

    Nam, Soonkeon

    2016-01-01

    We apply the Wald formalism to obtain masses and angular momenta of black holes in three dimensional gravity theories using first order formalism. Wald formalism suggests mass and angular momentum of black hole as an integration of some charge variation form at its boundary. The action of the three dimensional gravity theories can be represented by the form including some auxiliary fields. As well-known examples we have calculated mass and angular momentum of some black holes in topologically massive gravity and new massive gravity theories using first order formalism. We have also calculated mass and angular momentum of BTZ black hole and new type black hole in minimal massive gravity theory with the action represented by first order formalism.

  17. Windowed phase unwrapping using a first-order dynamic system following iso-phase contours.

    Science.gov (United States)

    Estrada, Julio C; Vargas, Javier; Flores-Moreno, J Mauricio; Quiroga, J Antonio

    2012-11-01

    In this work, we show a windowed phase-unwrapping technique that uses a first-order dynamic system and scans the phase following its iso-phase contours. In previous works, we have shown that low-pass first-order dynamic systems are very robust and useful in phase-unwrapping problems. However, it is well known that all phase-unwrapping methods have a minimum signal-to-noise ratio that they tolerate. This paper shows that scanning the phase within local windows and using a path following strategy, the first-order unwrapping method increases its tolerance to noise. In this way, using the improved approach, we can unwrap phase maps where the basic dynamic phase-unwrapping system fails. Tests and results are given, as well as the source code in order to show the performance of the proposed method.

  18. Verifying Functional Behaviour of Concurrent Programs

    NARCIS (Netherlands)

    Zaharieva, M.; Huisman, Marieke; Blom, Stefan; Pearce, D.

    Specifying the functional behaviour of a concurrent program can often be quite troublesome: it is hard to provide a stable method contract that can not be invalidated by other threads. In this paper we propose a novel modular technique for specifying and verifying behavioural properties in

  19. Magnetic unmixing of first-order reversal curve diagrams using principal component analysis

    Science.gov (United States)

    Lascu, Ioan; Harrison, Richard J.; Li, Yuting; Muraszko, Joy R.; Channell, James E. T.; Piotrowski, Alexander M.; Hodell, David A.

    2015-09-01

    We describe a quantitative magnetic unmixing method based on principal component analysis (PCA) of first-order reversal curve (FORC) diagrams. For PCA, we resample FORC distributions on grids that capture diagnostic signatures of single-domain (SD), pseudosingle-domain (PSD), and multidomain (MD) magnetite, as well as of minerals such as hematite. Individual FORC diagrams are recast as linear combinations of end-member (EM) FORC diagrams, located at user-defined positions in PCA space. The EM selection is guided by constraints derived from physical modeling and imposed by data scatter. We investigate temporal variations of two EMs in bulk North Atlantic sediment cores collected from the Rockall Trough and the Iberian Continental Margin. Sediments from each site contain a mixture of magnetosomes and granulometrically distinct detrital magnetite. We also quantify the spatial variation of three EM components (a coarse silt-sized MD component, a fine silt-sized PSD component, and a mixed clay-sized component containing both SD magnetite and hematite) in surficial sediments along the flow path of the North Atlantic Deep Water (NADW). These samples were separated into granulometric fractions, which helped constrain EM definition. PCA-based unmixing reveals systematic variations in EM relative abundance as a function of distance along NADW flow. Finally, we apply PCA to the combined data set of Rockall Trough and NADW sediments, which can be recast as a four-EM mixture, providing enhanced discrimination between components. Our method forms the foundation of a general solution to the problem of unmixing multicomponent magnetic mixtures, a fundamental task of rock magnetic studies.

  20. First-order approximation for the pressure-flow relationship of spontaneously contracting lymphangions.

    Science.gov (United States)

    Quick, Christopher M; Venugopal, Arun M; Dongaonkar, Ranjeet M; Laine, Glen A; Stewart, Randolph H

    2008-05-01

    To return lymph to the great veins of the neck, it must be actively pumped against a pressure gradient. Mean lymph flow in a portion of a lymphatic network has been characterized by an empirical relationship (P(in) - P(out) = -P(p) + R(L)Q(L)), where P(in) - P(out) is the axial pressure gradient and Q(L) is mean lymph flow. R(L) and P(p) are empirical parameters characterizing the effective lymphatic resistance and pump pressure, respectively. The relation of these global empirical parameters to the properties of lymphangions, the segments of a lymphatic vessel bounded by valves, has been problematic. Lymphangions have a structure like blood vessels but cyclically contract like cardiac ventricles; they are characterized by a contraction frequency (f) and the slopes of the end-diastolic pressure-volume relationship [minimum value of resulting elastance (E(min))] and end-systolic pressure-volume relationship [maximum value of resulting elastance (E(max))]. Poiseuille's law provides a first-order approximation relating the pressure-flow relationship to the fundamental properties of a blood vessel. No analogous formula exists for a pumping lymphangion. We therefore derived an algebraic formula predicting lymphangion flow from fundamental physical principles and known lymphangion properties. Quantitative analysis revealed that lymph inertia and resistance to lymph flow are negligible and that lymphangions act like a series of interconnected ventricles. For a single lymphangion, P(p) = P(in) (E(max) - E(min))/E(min) and R(L) = E(max)/f. The formula was tested against a validated, realistic mathematical model of a lymphangion and found to be accurate. Predicted flows were within the range of flows measured in vitro. The present work therefore provides a general solution that makes it possible to relate fundamental lymphangion properties to lymphatic system function.

  1. Full correspondence between asymmetric filling of slits and first-order phase transition lines

    Directory of Open Access Journals (Sweden)

    Leszek Szybisz

    2011-12-01

    Full Text Available Adsorption on single planar walls and filling of slits with identical planar walls are investigated in the frame of the density functional theory. In this sort of slits the external potential is symmetric with respect to its central plane. Calculations were carried out by applying both the canonical and grand canonical ensembles (CE and GCE, respectively. The behavior is analyzed by varying the strength of the adsorbate-substrate attraction, the temperature T, and the coverage Γℓ. Results obtained for physisorption of Xe on alkaline surfaces are reported in the present work. Prewetting (PW lines and wetting temperatures, Tw, are determined from the analysis of adsorption on single walls. The filling of slits is analyzed for temperatures T > Tw. It is found that whenever for a given Xe-substrate combination the adsorption on a single wall exhibits a first-order wetting transition then asymmetric profiles that break the left-right symmetry of the external potential appear in the filling of an equivalent slit. These spontaneously symmetry breaking (SSB solutions occur in a restricted range of Γℓ with a T-dependent width. In the case of closed slits analyzed in the CE scheme, the obtained asymmetric profiles exhibit lower Helmholtz free energies than the symmetric species and, therefore, could be stabilized in this geometry. For open slits, the GCE scheme yields all the symmetric and SSB states in the corresponding convex regimes of the free energy. It is shown that both the CE and the GCE frames yield three coexistent states, two symmetric and one asymmetric twofold degenerate. Both a PW line and the related SSB effect terminate at the same temperature. For rather strongly attractive surfaces reentrant SSB states are found at a fixed value of T.

  2. Full correspondence between asymmetric filling of slits and first-order phase transition lines

    Science.gov (United States)

    Szybisz, Leszek; Sartarelli, Salvador A.

    2011-12-01

    Adsorption on single planar walls and filling of slits with identical planar walls are investigated in the frame of the density functional theory. In this sort of slits the external potential is symmetric with respect to its central plane. Calculations were carried out by applying both the canonical and grand canonical ensembles (CE and GCE, respectively). The behavior is analyzed by varying the strength of the adsorbate-substrate attraction, the temperature T, and the coverage Γℓ. Results obtained for physisorption of Xe on alkaline surfaces are reported in the present work. Prewetting (PW) lines and wetting temperatures, Tw, are determined from the analysis of adsorption on single walls. The filling of slits is analyzed for temperatures T > Tw. It is found that whenever for a given Xe-substrate combination the adsorption on a single wall exhibits a first-order wetting transition then asymmetric profiles that break the left-right symmetry of the external potential appear in the filling of an equivalent slit. These spontaneously symmetry breaking (SSB) solutions occur in a restricted range of Γℓ with a T-dependent width. In the case of closed slits analyzed in the CE scheme, the obtained asymmetric profiles exhibit lower Helmholtz free energies than the symmetric species and, therefore, could be stabilized in this geometry. For open slits, the GCE scheme yields all the symmetric and SSB states in the corresponding convex regimes of the free energy. It is shown that both the CE and the GCE frames yield three coexistent states, two symmetric and one asymmetric twofold degenerate. Both a PW line and the related SSB effect terminate at the same temperature. For rather strongly attractive surfaces reentrant SSB states are found at a fixed value of T.

  3. Theory of First Order Chemical Kinetics at the Critical Point of Solution.

    Science.gov (United States)

    Baird, James Kern; Lang, Joshua R

    2017-09-27

    Liquid mixtures, which have a phase diagram exhibiting a miscibility gap ending in a critical point of solution, have been used as solvents for chemical reactions. The reaction rate in the forward direction has often been observed to slow down as a function of temperature in the critical region. Theories based upon the Gibbs free energy of reaction as the driving force for chemical change have been invoked to explain this behavior. With the assumption that the reaction is proceeding under relaxation conditions, these theories expand the free energy in a Taylor series about the position of equilibrium. Since the free energy is zero at equilibrium, the leading term in the Taylor series is proportional to the first derivative of the free energy with respect to the extent of reaction. To analyze the critical behavior of this derivative, the theories invoke the principle of critical point isomorphism, which is thought to govern all critical phenomena. They find that the derivative goes to zero in the critical region, which accounts for the slowing down observed in the reaction rate. As has been pointed out, however, most experimental rate investigations have been carried out under irreversible conditions as opposed to relaxation conditions [Shen et al. J. Phys. Chem. A 2015, 119, 8784 - 8791]. Below, we consider a reaction governed by first order kinetics and invoke transition state theory to take into account the irreversible conditions. We express the apparent activation energy in terms of thermodynamic derivatives evaluated under standard conditions as well as the pseudo-equilibrium conditions associated with the reactant and the activated complex. We show that these derivatives approach infinity in the critical region. The apparent activation energy follows this behavior, and its divergence accounts for the slowing down of the reaction rate.

  4. Statistical mechanics of random geometric graphs: Geometry-induced first-order phase transition.

    Science.gov (United States)

    Ostilli, Massimo; Bianconi, Ginestra

    2015-04-01

    Random geometric graphs (RGGs) can be formalized as hidden-variables models where the hidden variables are the coordinates of the nodes. Here we develop a general approach to extract the typical configurations of a generic hidden-variables model and apply the resulting equations to RGGs. For any RGG, defined through a rigid or a soft geometric rule, the method reduces to a nontrivial satisfaction problem: Given N nodes, a domain D, and a desired average connectivity 〈k〉, find, if any, the distribution of nodes having support in D and average connectivity 〈k〉. We find out that, in the thermodynamic limit, nodes are either uniformly distributed or highly condensed in a small region, the two regimes being separated by a first-order phase transition characterized by a O(N) jump of 〈k〉. Other intermediate values of 〈k〉 correspond to very rare graph realizations. The phase transition is observed as a function of a parameter a∈[0,1] that tunes the underlying geometry. In particular, a=1 indicates a rigid geometry where only close nodes are connected, while a=0 indicates a rigid antigeometry where only distant nodes are connected. Consistently, when a=1/2 there is no geometry and no phase transition. After discussing the numerical analysis, we provide a combinatorial argument to fully explain the mechanism inducing this phase transition and recognize it as an easy-hard-easy transition. Our result shows that, in general, ad hoc optimized networks can hardly be designed, unless to rely to specific heterogeneous constructions, not necessarily scale free.

  5. Dynamical scaling for underdamped strain order parameters quenched below first-order phase transitions

    Science.gov (United States)

    Shankaraiah, N.; Dubey, Awadhesh K.; Puri, Sanjay; Shenoy, Subodh R.

    2016-12-01

    In the conceptual framework of phase ordering after temperature quenches below transition, we consider the underdamped Bales-Gooding-type "momentum conserving" dynamics of a 2D martensitic structural transition from a square-to-rectangle unit cell. The one-component or NOP=1 order parameter is one of the physical strains, and the Landau free energy has a triple well, describing a first-order transition. We numerically study the evolution of the strain-strain correlation, and find that it exhibits dynamical scaling, with a coarsening length L (t ) ˜tα . We find at intermediate and long times that the coarsening exponent sequentially takes on respective values close to α =2 /3 and 1 /2 . For deep quenches, the coarsening can be arrested at long times, with α ≃0 . These exponents are also found in 3D. To understand such behavior, we insert a dynamical-scaling ansatz into the correlation function dynamics to give, at a dominant scaled separation, a nonlinear kinetics of the curvature g (t )≡1 /L (t ) . The curvature solutions have time windows of power-law decays g ˜1 /tα , with exponent values α matching simulations, and manifestly independent of spatial dimension. Applying this curvature-kinetics method to mass-conserving Cahn-Hilliard dynamics for a double-well Landau potential in a scalar NOP=1 order parameter yields exponents α =1 /4 and 1 /3 for intermediate and long times. For vector order parameters with NOP≥2 , the exponents are α =1 /4 only, consistent with previous work. The curvature kinetics method could be useful in extracting coarsening exponents for other phase-ordering dynamics.

  6. Robust stabilizing first-order controllers for a class of time delay systems.

    Science.gov (United States)

    Saadaoui, Karim; Testouri, Sana; Benrejeb, Mohamed

    2010-07-01

    In this paper, stabilizing regions of a first-order controller for an all poles system with time delay are computed via parametric methods. First, the admissible ranges of one of the controller's parameters are obtained. Then, for a fixed value of this parameter, stabilizing regions in the remaining two parameters are determined using the D-decomposition method. Phase and gain margin specifications are then included in the design. Finally, robust stabilizing first-order controllers are determined for uncertain plants with an interval type uncertainty in the coefficients. Examples are given to illustrate the effectiveness of the proposed method.

  7. The mass transfer approach to multivariate discrete first order stochastic dominance

    DEFF Research Database (Denmark)

    Østerdal, Lars Peter Raahave

    2010-01-01

    A fundamental result in the theory of stochastic dominance tells that first order dominance between two finite multivariate distributions is equivalent to the property that the one can be obtained from the other by shifting probability mass from one outcome to another that is worse a finite number...... of times. This paper provides a new and elementary proof of that result by showing that starting with an arbitrary system of mass transfers, whenever the resulting distribution is first order dominated one can gradually rearrange transfers, according to a certain decentralized procedure, and obtain...... a system of transfers all shifting mass to outcomes that are worse....

  8. Kinetics of the First Order Autocatalytic Decomposition Reaction of Nitrocellulose (13.86% N)

    Institute of Scientific and Technical Information of China (English)

    GUO,Peng-Jiang(郭鹏江); HU,Rong-Zu(胡荣祖); NING,Bin-Ke(宁斌科); YANG,Zheng-Quan(杨正权); SONG,Ji-Rong(宋纪蓉); SHI,Qi-Zhen(史启祯); LU,Gui-E(路桂娥); JIANG,Jin-You(江劲勇)

    2004-01-01

    The kinetics of the first order autocatalytic decomposition reaction of nitrocellulose (NC, 13.86% N) was studied by using DSC. The results show that the DSC curve for the initial 50% of conversion degree of NC can be described by the first order autocatalytic equation dy/dt=-1016.3exp(-181860/RT)y-1016.7exp(-173050)y(1-y) and that for the latter 50% conversion degree of NC described by the reaction equations dy/dt=-1016.4exp(-154820/RT)y(n=1) and dy/dt=-1016.9exp(-155270/RT)y2.80(n≠1).

  9. Titration Calorimetry Applied to the Thermokinetics Study of Consecutive First-order Reactions

    Institute of Scientific and Technical Information of China (English)

    SHI Jing-Yan; LI Jie; WANG Zhi-Yong; LIU Yu-Wen; WANG Cun-Xin

    2008-01-01

    The thermokinetic mathematical models for consecutive first-order reactions in titration period and the stopped-titration reaction period were proposed for titration calorimetry, based on which, thermodynamic parameters (reaction enthalpies, △rHm1 and △rHm2) and kinetic parameters (rate constants, k1 and k2) of the consecutive first-order reactions could be obtained by directly simulating the calorimetric curve from a single experiment with the method of nonlinear least squares regression (NLLS).The reliability of the model has been verified by investigating the reaction of the saponification of diethyl succinate in an aqueous ethanol solvent.

  10. On entropy change measurements around first order phase transitions in caloric materials

    Science.gov (United States)

    Caron, Luana; Doan, Nguyen Ba; Ranno, Laurent

    2017-02-01

    In this work we discuss the measurement protocols for indirect determination of the isothermal entropy change associated with first order phase transitions in caloric materials. The magneto-structural phase transitions giving rise to giant magnetocaloric effects in Cu-doped MnAs and FeRh are used as case studies to exemplify how badly designed protocols may affect isothermal measurements and lead to incorrect entropy change estimations. Isothermal measurement protocols which allow correct assessment of the entropy change around first order phase transitions in both direct and inverse cases are presented.

  11. Simple empirical order parameter for a first-order quantum phase transition in atomic nuclei.

    Science.gov (United States)

    Bonatsos, Dennis; McCutchan, E A; Casten, R F; Casperson, R J

    2008-04-11

    A simple, empirical, easy-to-measure effective order parameter of a first-order phase transition in atomic nuclei is presented, namely, the ratio of the energies of the first excited 6+ and 0+ states, distinguishing between first- and second-order transitions, and taking on a special value in the critical region, as data in Nd-Dy show. In the large NB limit of the interacting boson approximation model, a repeating degeneracy between alternate yrast and successive 0+ states is found in the critical region around the line of a first-order phase transition, pointing to a possible underlying symmetry.

  12. First-Order Equations of Motion for Heterotic String Field Theory

    CERN Document Server

    Kunitomo, Hiroshi

    2014-01-01

    We consider the equations of motion of the full heterotic string field theory including both the Neveu-Schwarz and the Ramond sectors. It is shown that they can be formulated in the form of an infinite number of first-order equations for an infinite number of independent string fields. We prove that the conventional equations of motion are obtaned by solving the extra equations for the extra string fields with a certain assumptions at the linearized level. The conventional gauge transformations are also obtained from those in this first-order formulation, which is clarified by deriving some lower oder transformations explicitly.

  13. Damper placement for seismic control of super-long-span suspension bridges based on the first-order optimization method

    Institute of Scientific and Technical Information of China (English)

    Billie; F; SPENCER

    2010-01-01

    To ensure the anti-earthquake performances of super-long-span suspension bridges, effective devices should be employed to control the seismic response of key sections. In this paper, four kinds of assessment functions for seismic response control effect are formulated based on the mechanism of seismic response control with dampers and the seismic response characteristics of long-span suspension bridges. A new optimal placement method of dampers using penalty function and first-order optimization theory is then proposed. Runyang suspension bridge (RSB) with a main span of 1490 m is then taken as an example. After seismic response time-history analyses on RSB using different placements of dampers, the analysis results are optimized by employing the optimal placement method and the optimal placements of dampers with the four assessment functions are then achieved respectively. Comparison of the four optimal control effects show that different assessment functions can lead to different optimal placements when the number of dampers is certain, but all placements of dampers can reduce the seismic response of RSB significantly. The selection of assessment functions and damper optimal placement should be determined by the structural characteristics and by what is considered in the structures. Results also show that the first-order optimization is an effective method on determining the optimal placement of dampers.

  14. Prenatal programming of neuroendocrine reproductive function.

    Science.gov (United States)

    Evans, Neil P; Bellingham, Michelle; Robinson, Jane E

    2016-07-01

    It is now well recognized that the gestational environment can have long-lasting effects not only on the life span and health span of an individual but also, through potential epigenetic changes, on future generations. This article reviews the "prenatal programming" of the neuroendocrine systems that regulate reproduction, with a specific focus on the lessons learned using ovine models. The review examines the critical roles played by steroids in normal reproductive development before considering the effects of prenatal exposure to exogenous steroid hormones including androgens and estrogens, the effects of maternal nutrition and stress during gestation, and the effects of exogenous chemicals such as alcohol and environment chemicals. In so doing, it becomes evident that, to maximize fitness, the regulation of reproduction has evolved to be responsive to many different internal and external cues and that the GnRH neurosecretory system expresses a degree of plasticity throughout life. During fetal life, however, the system is particularly sensitive to change and at this time, the GnRH neurosecretory system can be "shaped" both to achieve normal sexually differentiated function but also in ways that may adversely affect or even prevent "normal function". The exact mechanisms through which these programmed changes are brought about remain largely uncharacterized but are likely to differ depending on the factor, the timing of exposure to that factor, and the species. It would appear, however, that some afferent systems to the GnRH neurons such as kisspeptin, may be critical in this regard as it would appear to be sensitive to a wide variety of factors that can program reproductive function. Finally, it has been noted that the prenatal programming of neuroendocrine reproductive function can be associated with epigenetic changes, which would suggest that in addition to direct effects on the exposed offspring, prenatal programming could have transgenerational effects on

  15. Imaging of first-order surface-related multiples by reverse-time migration

    Science.gov (United States)

    Liu, Xuejian; Liu, Yike; Hu, Hao; Li, Peng; Khan, Majid

    2017-02-01

    Surface-related multiples have been utilized in the reverse-time migration (RTM) procedures, and additional illumination for subsurface can be provided. Meanwhile, many cross-talks are generated from undesired interactions between forward- and backward-propagated seismic waves. In this paper, subsequent to analysing and categorizing these cross-talks, we propose RTM of first-order multiples to avoid most undesired interactions in RTM of all-order multiples, where only primaries are forward-propagated and crosscorrelated with the backward-propagated first-order multiples. With primaries and multiples separated during regular seismic data processing as the input data, first-order multiples can be obtained by a two-step scheme: (1) the dual-prediction of higher-order multiples; and (2) the adaptive subtraction of predicted higher-order multiples from all-order multiples within local offset-time windows. In numerical experiments, two synthetic and a marine field data sets are used, where different cross-talks generated by RTM of all-order multiples can be identified and the proposed RTM of first-order multiples can provide a very interpretable image with a few cross-talks.

  16. Object-dependent cloaking in the first-order Born approximation

    NARCIS (Netherlands)

    Setälä, Tero; Hakkarainen, Timo; Friberg, Ari T.; Hoenders, Bernhard J.; Setälä, Tero

    2010-01-01

    We consider the cloaking of a slab object in scalar wave theory within the first-order Born approximation. We show that in the forward direction cloaking is achieved for any transversally invariant, positively refracting, and absorbing object by using a lossy, negative-index metamaterial cloak. Cloa

  17. Lagrange's early contributions to the theory of first-order partial differential equations

    NARCIS (Netherlands)

    Engelsman, S.B.

    1980-01-01

    In 1776, J. L. Lagrange gave a definition of the concept of a “complete solution” of a first-order partial differential equation. This definition was entirely different from the one given earlier by Euler. One of the sources for Lagrange's reformulation of this concept can be found in his attempt to

  18. The logic of propagation strategies : Axiomatizing a fragment of organizational ecology in first-order logic

    NARCIS (Netherlands)

    Peli, G; Masuch, M

    1997-01-01

    As a part of a larger effort to apply formal logic to organization science, we axiomatize the theory of propagation strategies (life history strategies) of Organization Ecology. We provide an axiomatic system in first-order logic that derives the theory's predictions as theorems from a set of underl

  19. Local classification of stable geometric solutions of systems of quasilinear first-order PDE

    Institute of Scientific and Technical Information of China (English)

    LI; Bing(李兵); LI; Yangcheng(李养成)

    2002-01-01

    Systems of quasilinear first order PDE are studied in the framework of contact manifold. All of the local stable geometric solutions of such systems are classified by using versal deformation and the classification of stable map germs of type ∑1 in singularity theory.

  20. Cascadable Current-Mode First-Order and Second-Order Multifunction Filters Employing Grounded Capacitors

    Directory of Open Access Journals (Sweden)

    Jiun-Wei Horng

    2012-01-01

    Full Text Available A configuration for realizing low input and high output impedances current-mode multifunction filters using multiple output second-generation current conveyors (MOCCIIs is presented. From the proposed circuit configuration, first-order allpass, highpass, lowpass and second-order allpass, notch, bandpass filters can be obtained. The simulation results confirm the theoretical analysis.

  1. Reliability Estimation of the Pultrusion Process Using the First-Order Reliability Method (FORM)

    NARCIS (Netherlands)

    Baran, Ismet; Tutum, Cem C.; Hattel, Jesper H.

    2013-01-01

    In the present study the reliability estimation of the pultrusion process of a flat plate is analyzed by using the first order reliability method (FORM). The implementation of the numerical process model is validated by comparing the deterministic temperature and cure degree profiles with correspond

  2. The First-Order Euler-Lagrange equations and some of their uses

    CERN Document Server

    Adam, C

    2016-01-01

    In many nonlinear field theories, relevant solutions may be found by reducing the order of the original Euler-Lagrange equations, e.g., to first order equations (Bogomolnyi equations, self-duality equations, etc.). Here we generalise, further develop and apply one particular method for the order reduction of nonlinear field equations which, despite its systematic and versatile character, is not widely known.

  3. Explicit solutions of one-dimensional, first-order, stationary mean-field games with congestion

    KAUST Repository

    Gomes, Diogo A.

    2017-01-05

    Here, we consider one-dimensional first-order stationary mean-field games with congestion. These games arise when crowds face difficulty moving in high-density regions. We look at both monotone decreasing and increasing interactions and construct explicit solutions using the current formulation. We observe new phenomena such as discontinuities, unhappiness traps and the non-existence of solutions.

  4. Nature of the first-order magnetic phase transition in giant-magnetocaloric materials

    NARCIS (Netherlands)

    Yibole

    2016-01-01

    This thesis reports on advanced characterizations of giant magnetocaloric materials that show a first order magnetic phase transition (FOMT). The results are of great interest not only for the design of new magnetic refrigerants, but also for a better understanding of the FOMT. This thesis paves the

  5. Thermodynamics around the first-order ferromagnetic phase transition of Fe2P single crystals

    NARCIS (Netherlands)

    Hudl, M.; Campanini, D.; Caron, L.; Höglin, V.; Sahlberg, M.; Nordblad, P.; Rydh, A.

    2014-01-01

    The specific heat and thermodynamics of Fe2P single crystals around the first-order paramagnetic to ferromagnetic (FM) phase transition at TC≃217K are empirically investigated. The magnitude and direction of the magnetic field relative to the crystal axes govern the derived H−T phase diagram. Striki

  6. Algorithms and software for total variation image reconstruction via first-order methods

    DEFF Research Database (Denmark)

    Dahl, Joahim; Hansen, Per Christian; Jensen, Søren Holdt

    2010-01-01

    This paper describes new algorithms and related software for total variation (TV) image reconstruction, more specifically: denoising, inpainting, and deblurring. The algorithms are based on one of Nesterov's first-order methods, tailored to the image processing applications in such a way that...

  7. Implications of reactor type and conditions on first-order hydrolysis rate assessment of maize silage.

    Science.gov (United States)

    Pabón Pereira, C P; Zeeman, G; Zhao, J; Ekmekci, B; van Lier, J B

    2009-01-01

    The biodegradability and first-order hydrolysis coefficient of maize silage have been assessed from batch experiments using different types of inoculum and substrate to inocula (S/I) ratios, and from CSTRs working at different hydraulic retention times (HRTs). In the batch experiments, the assessed maximum biodegradability of the maize silage was 68 (+/-2.7)% and 73(+/-2.9)% while the first order hydrolysis was 0.26 (+/-0.01) and 0.27(+/-0.02) d(-1), using granular and a mixture of granular and suspended inoculum, respectively. In the CSTR experiment biodegradability ranged from 41-65% depending on the HRT applied whereas the calculated first order hydrolysis coefficient was 0.32 d(-1). It is concluded that batch experiments can be used to assess first order hydrolysis constants and biodegradability provided that a well balanced inoculum is guaranteed. Further, it is shown that CSTR reactors digesting maize silage and operating at HRTs as low as 20 days can attain 88% of maximum biodegradability as long as pH fluctuations are minimized. 2 mmol NaHCO3 per gram maize silage was calculated to suffice for the purpose.

  8. Nonequilibrium and nonhomogeneous phenomena around a first-order quantum phase transition

    Science.gov (United States)

    Del Re, Lorenzo; Fabrizio, Michele; Tosatti, Erio

    2016-03-01

    We consider nonequilibrium phenomena in a very simple model that displays a zero-temperature first-order phase transition. The quantum Ising model with a four-spin exchange is adopted as a general representative of first-order quantum phase transitions that belong to the Ising universality class, such as for instance the order-disorder ferroelectric transitions, and possibly first-order T =0 Mott transitions. In particular, we address quantum quenches in the exactly solvable limit of infinite connectivity and show that, within the coexistence region around the transition, the system can remain trapped in a metastable phase, as long as it is spatially homogeneous so that nucleation can be ignored. Motivated by the physics of nucleation, we then study in the same model static but inhomogeneous phenomena that take place at surfaces and interfaces. The first-order nature implies that both phases remain locally stable across the transition, and with that the possibility of a metastable wetting layer showing up at the surface of the stable phase, even at T =0 . We use mean-field theory plus quantum fluctuations in the harmonic approximation to study quantum surface wetting.

  9. Expressing First-Order π-Calculus in Higher-Order Calculus of Communicating Systems

    Institute of Scientific and Technical Information of China (English)

    Xian Xu

    2009-01-01

    In the study of process calculi, encoding between different calculi is an effective way to compare the expressive power of calculi and can shed light on the essence of where the difference lies. Thomsen and Sangiorgi have worked on the higher-order calculi (higher-order Calculus of Communicating Systems (CCS) and higher-order It-calculus, respectively) and the encoding from and to first-order π-calculus. However a fully abstract encoding of first-order π-calculus with higher-order CCS is not available up-today. This is what we intend to settle in this paper. We follow the encoding strategy, first proposed by Thomsen, of translating first-order π-calculus into Plain CHOCS. We show that the encoding strategy is fully abstract with respect to early bisimilarity (first-order π-calculus) and wired bisimilarity (Plain CHOCS) (which is a bisimulation defined on wired processes only sending and receiving wires), that is the core of the encoding strategy. Moreover from the fact that the wired bisimilarity is contained by the well-established context bisimilarity, we secure the soundness of the encoding, with respect to early bisimilarity and context bisimilarity. We use index technique to get around all the technical details to reach these main results of this paper. Finally, we make some discussion on our work and suggest some future work.

  10. A POSTERIORI ERROR ESTIMATE OF THE DSD METHOD FOR FIRST-ORDER HYPERBOLIC EQUATIONS

    Institute of Scientific and Technical Information of China (English)

    康彤; 余德浩

    2002-01-01

    A posteriori error estimate of the discontinuous-streamline diffusion method for first-order hyperbolic equations was presented, which can be used to adjust space mesh reasonably. A numerical example is given to illustrate the accuracy and feasibility of this method.

  11. Variations in the Solution of Linear First-Order Differential Equations. Classroom Notes

    Science.gov (United States)

    Seaman, Brian; Osler, Thomas J.

    2004-01-01

    A special project which can be given to students of ordinary differential equations is described in detail. Students create new differential equations by changing the dependent variable in the familiar linear first-order equation (dv/dx)+p(x)v=q(x) by means of a substitution v=f(y). The student then creates a table of the new equations and…

  12. Limiting First Order Phase Transitions in Dark Gauge Sectors from Gravitational Waves experiments

    CERN Document Server

    Addazi, Andrea

    2016-01-01

    We discuss the possibility to indirectly test First Order Phase Transitions of hidden sectors. We study the interesting example of a {\\it dark standard model} with a deformed parameter space in the Higgs potential. A dark electroweak phase transition can be limited from next future experiments like eLISA and DECIGO.

  13. EXISTENCE OF EXTREME SOLUTION TO FIRST-ORDER IMPULSIVE DIFFERENTIAL EQUATIONS WITH NONLINEAR BOUNDARY CONDITIONS

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    This paper is concerned with the existence of extreme solutions to three-point boundary value problems with nonlinear boundary conditions for a class of first order impulsive differential equations. We obtain suficient conditions for the existence of extreme solutions by the upper and lower solutions method coupled with a monotone iterative technique.

  14. The gravitational waves from the first-order phase transition with a dimension-six operator

    Science.gov (United States)

    Cai, Rong-Gen; Sasaki, Misao; Wang, Shao-Jiang

    2017-08-01

    We investigate in details the gravitational wave (GW) from the first-order phase transition (PT) in the extended standard model of particle physics with a dimension-six operator, which is capable of exhibiting the recently discovered slow first-order PT in addition to the usually studied fast first-order PT. To simplify the discussion, it is sufficient to work with an example of a toy model with the sextic term, and we propose an unified description for both slow and fast first-order PTs. We next study the full one-loop effective potential of the model with fixed/running renormalization-group (RG) scales. Compared to the prediction of GW energy density spectrum from the fixed RG scale, we find that the presence of running RG scale could amplify the peak amplitude by amount of one order of magnitude while shift the peak frequency to the lower frequency regime, and the promising regime of detection within the sensitivity ranges of various space-based GW detectors shrinks down to a lower cut-off value of the sextic term rather than the previous expectation.

  15. Asymptotic and Oscillatory Behavior of Solutions of First Order Neutral Differential Equations

    Institute of Scientific and Technical Information of China (English)

    王其如; 李黎

    1993-01-01

    This paper has made researches on first order neutral differential equations with varia-ble coefficients and several deviations.The asymptotic behavior of nonoscillatory solutions of the equations are discussed.Necessary and sufficient conditions and several sufficient conditions for the oscillations of the equations are obtained.The relevent results in [1-3] are improved and genera-lized.

  16. First-order phase transitions in rotating hybrid stars and pulsar glitches

    Institute of Scientific and Technical Information of China (English)

    Fei Xiao; Chun-Mei Pi; Shu-Hua Yang; Ai-Zhi Zhou; Xiao-Ping Zheng

    2011-01-01

    The first order deconfinement phase transitions in rotating hybrid stars are studied and it is found that if the surface tension is sufficiently large, the transition from metastable hadron matter to stable mixed hadron-quark matter during the spindown history of a hybrid star can cause a glitch.

  17. OSCILLATORY AND ASYMPTOTIC BEHAVIOR OF A CLASS OF FIRST ORDER NEUTRALDIFFERENTIAL EQUATION WITH PIECEWISE CONSTANT DELAY

    Institute of Scientific and Technical Information of China (English)

    冯月才

    2004-01-01

    The oscillatory and asymptotic behavior of a class of first order nonlinear neutral differential equation with piecewise constant delay and with diverse deviating arguments are considered. We prove that all solutions of the equation are nonoscillatory and give sufficient criteria for asymptotic behavior of nonoscillatory solutions of equation.

  18. Picone's identity for a system of first-order nonlinear partial differential equations

    Directory of Open Access Journals (Sweden)

    Jaroslav Jaros

    2013-06-01

    Full Text Available We established a Picone identity for systems of nonlinear partial differential equations of first-order. With the help of this formula, we obtain qualitative results such as an integral inequality of Wirtinger type and the existence of zeros for the first components of solutions in a given bounded domain.

  19. Compensation Tuning of Analog and Digital Controllers for First Order Plus Time Delay Plants

    Directory of Open Access Journals (Sweden)

    Miluše VÍTEČKOVÁ

    2011-06-01

    Full Text Available The article is devoted to the simple compensation tuning of analog and digital PI and PID controllers for the first order plus time delay plants. The described method makes controller tuning possible so that the control process is non-oscillatory without an overshoot for all input variables. The use is shown in the example.

  20. Fluctuation effects in first-order phase transitions: Theory and model for martensitic transformations

    DEFF Research Database (Denmark)

    Lindgård, Per-Anker; Mouritsen, Ole G.

    1990-01-01

    -dimensional Monte Carlo simulation, showing clear precursor phenomena near the first-order transition and spontaneous nucleation. The kinetics of the domain growth is studied and found to be exceedingly slow. The results are applicable for martensitic transformations and structural surface...

  1. Provable first-order transitions for nonlinear vector and gauge models with continuous symmetries

    NARCIS (Netherlands)

    Enter, Aernout C.D. van; Shlosman, Senya B.

    2005-01-01

    We consider various sufficiently nonlinear vector models of ferromagnets, of nematic liquid crystals and of nonlinear lattice gauge theories with continuous symmetries. We show, employing the method of Reflection Positivity and Chessboard Estimates, that they all exhibit first-order transitions in t

  2. ON THE BOREL SUMMABILITY OF FORMAL SOLUTIONS FOR SOME FIRST ORDER SINGULAR PDES WITH IRREGULAR SINGULARITY

    Institute of Scientific and Technical Information of China (English)

    Chen Hua; Zhang Zhixiong

    2005-01-01

    In this paper the authors consider the summability of formal solutions for some first order singular PDEs with irregular singularity. They prove that in this case the formal solutions will be divergent, but except a enumerable directions, the formal solutions are Borel summable.

  3. Determination of astaxanthin in Haematococcus pluvialis by first-order derivative spectrophotometry.

    Science.gov (United States)

    Liu, Xiao Juan; Juan, Liu Xiao; Wu, Ying Hua; Hua, Wu Ying; Zhao, Li Chao; Chao, Zhao Li; Xiao, Su Yao; Yao, Xiao Su; Zhou, Ai Mei; Mei, Zhou Ai; Liu, Xin; Xin, Liu

    2011-01-01

    A highly selective, convenient, and precise method, first-order derivative spectrophotometry, was applied for the determination of astaxanthin in Haematococcus pluvialis. Ethyl acetate and ethanol (1:1, v/v) were found to be the best extraction solvent tested due to their high efficiency and low toxicity compared with nine other organic solvents. Astaxanthin coexisting with chlorophyll and beta-carotene was analyzed by first-order derivative spectrophotometry in order to optimize the conditions for the determination of astaxanthin. The results show that when detected at 432 nm, the interfering substances could be eliminated. The dynamic linear range was 2.0-8.0 microg/mL, with a correlation coefficient of 0.9916. The detection threshold was 0.41 microg/mL. The RSD for the determination of astaxanthin was in the range of 0.01-0.06%; the results of recovery test were 98.1-108.0%. The statistical analysis between first-order derivative spectrophotometry and HPLC by T-testing did not exceed their critical values, revealing no significant differences between these two methods. It was proved that first-order derivative spectrophotometry is a rapid and convenient method for the determination of astaxanthin in H. pluvialis that can eliminate the negative effect resulting from the coexistence of astaxanthin with chlorophyll and beta-carotene.

  4. Parameterization of entrainment in a sheared convective boundary layer using a first-order jump model

    NARCIS (Netherlands)

    Kim, S.W.; Park, S.U.; Pino, D.; Vilà-Guerau de Arellano, J.

    2006-01-01

    Basic entrainment equations applicable to the sheared convective boundary layer (CBL) are derived by assuming an inversion layer with a finite depth, i.e., the first-order jump model. Large-eddy simulation data are used to determine the constants involved in the parameterizations of the entrainment

  5. The first-order Euler-Lagrange equations and some of their uses

    Energy Technology Data Exchange (ETDEWEB)

    Adam, C.; Santamaria, F. [Departamento de Física de Partículas and Instituto Galego de Física de Altas Enerxias (IGFAE),Campus Vida, E-15782 Santiago de Compostela (Spain)

    2016-12-13

    In many nonlinear field theories, relevant solutions may be found by reducing the order of the original Euler-Lagrange equations, e.g., to first order equations (Bogomolnyi equations, self-duality equations, etc.). Here we generalise, further develop and apply one particular method for the order reduction of nonlinear field equations which, despite its systematic and versatile character, is not widely known.

  6. A test of first order scaling in Nf =2 QCD: a progress report

    CERN Document Server

    Bonati, C; D'Elia, M; Di Giacomo, A; Pica, C

    2008-01-01

    We present the status of our analysis on the order of the finite temperature transition in QCD with two flavors of degenerate fermions. Our new simulations on large lattices support the hypothesis of the first order nature of the transition, showing a preliminary two state signal. We will discuss the implications and the next steps in our analysis.

  7. A NEW OSCILLATION CRITERION FOR FIRST ORDER NEUTRAL DELAY DIFFERENTIAL EQUATION

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    In this paper, a new sufficient condition for the oscillation of all solutions of first order neutral delay differential equations is obtained. Secondly, the result can also be extended to a general neutral differential equation, and many known results in the literatures are improved.

  8. Implications of reactor type and conditions on first-order hydrolysis rate assessment of maize

    NARCIS (Netherlands)

    Pabon Pereira, C.P.; Zeeman, G.; Zhao, R.; Ekmekci, B.; Lier, van J.B.

    2009-01-01

    The biodegradability and first-order hydrolysis coefficient of maize silage have been assessed from batch experiments using different types of inoculum and substrate to inocula (S/I) ratios, and from CSTRs working at different hydraulic retention times (HRTs). In the batch experiments, the assessed

  9. First-order fire effects models for land Management: Overview and issues

    Science.gov (United States)

    Elizabeth D. Reinhardt; Matthew B. Dickinson

    2010-01-01

    We give an overview of the science application process at work in supporting fire management. First-order fire effects models, such as those discussed in accompanying papers, are the building blocks of software systems designed for application to landscapes over time scales from days to centuries. Fire effects may be modeled using empirical, rule based, or process...

  10. From functional programming to multicore parallelism: A case study based on Presburger Arithmetic

    DEFF Research Database (Denmark)

    Dung, Phan Anh; Hansen, Michael Reichhardt

    2011-01-01

    The overall goal of this work is studying parallelization of functional programs with the specific case study of decision procedures for Presburger Arithmetic (PA). PA is a first order theory of integers accepting addition as its only operation. Whereas it has wide applications in different areas......, we are interested in using PA in connection with the Duration Calculus Model Checker (DCMC) [5]. There are effective decision procedures for PA including Cooper’s algorithm and the Omega Test; however, their complexity is extremely high with doubly exponential lower bound and triply exponential upper...... in the SMT-solver Z3 [8] which has the capability of solving Presburger formulas. Functional programming is well-suited for the domain of decision procedures, and its immutability feature helps to reduce parallelization effort. While Haskell has progressed with a lot of parallelismrelated research [6], we...

  11. Exit from inflation with a first-order phase transition and a gravitational wave blast

    Directory of Open Access Journals (Sweden)

    Amjad Ashoorioon

    2015-07-01

    Full Text Available In double-field inflation, which exploits two scalar fields, one of the fields rolls slowly during inflation whereas the other field is trapped in a meta-stable vacuum. The nucleation rate from the false vacuum to the true one becomes substantial enough that triggers a first order phase transition and ends inflation. We revisit the question of first order phase transition in an “extended” model of hybrid inflation, realizing the double-field inflationary scenario, and correctly identify the parameter space that leads to a first order phase transition at the end of inflation. We compute the gravitational wave profile which is generated during this first order phase transition. Assuming instant reheating, the peak frequency falls in the 1 GHz to 10 GHz frequency band and the amplitude varies in the range 10−11≲ΩGWh2≲10−8, depending on the value of the cosmological constant in the false vacuum. For a narrow band of vacuum energies, the first order phase transition can happen after the end of inflation via the violation of slow-roll, with a peak frequency that varies from 1 THz to 100 THz. For smaller values of cosmological constant, even though inflation can end via slow-roll violation, the universe gets trapped in a false vacuum whose energy drives a second phase of eternal inflation. This range of vacuum energies do not lead to viable inflationary models, unless the value of the cosmological constant is compatible with the observed value, M∼10−3 eV.

  12. Link between travelling waves and first order nonlinear ordinary differential equation with a sixth-degree nonlinear term

    Energy Technology Data Exchange (ETDEWEB)

    Huang Dingjiang [Department of Applied Mathematics, Dalian University of Technology, Dalian 116024 (China)]. E-mail: hdj8116@163.com; Zhang Hongqing [Department of Applied Mathematics, Dalian University of Technology, Dalian 116024 (China)

    2006-08-15

    Many travelling wave solutions of nonlinear evolution equations can be written as a polynomial in several elementary or special functions which satisfy a first order nonlinear ordinary differential equation with a sixth-degree nonlinear term. From that property, we deduce an algebraic method for constructing those solutions by determining only a finite number of coefficients. Being concise and straightforward, the method is applied to three nonlinear evolution equations. As a result, many exact travelling wave solutions are obtained which include new bell and kink profile solitary wave solutions, triangular periodic wave solutions and singular solutions.

  13. Decentralized Identification and Control in Real-Time of a Robot Manipulator via Recurrent Wavelet First-Order Neural Network

    Directory of Open Access Journals (Sweden)

    Luis A. Vázquez

    2015-01-01

    Full Text Available A decentralized recurrent wavelet first-order neural network (RWFONN structure is presented. The use of a wavelet Morlet activation function allows proposing a neural structure in continuous time of a single layer and a single neuron in order to identify online in a series-parallel configuration, using the filtered error (FE training algorithm, the dynamics behavior of each joint for a two-degree-of-freedom (DOF vertical robot manipulator, whose parameters such as friction and inertia are unknown. Based on the RWFONN subsystem, a decentralized neural controller is designed via backstepping approach. The performance of the decentralized wavelet neural controller is validated via real-time results.

  14. Armstrong Laboratory Space Visual Function Tester Program

    Science.gov (United States)

    Oneal, Melvin R.; Task, H. Lee; Gleason, Gerald A.

    1992-01-01

    Viewgraphs on space visual function tester program are presented. Many astronauts and cosmonauts have commented on apparent changes in their vision while on-orbit. Comments have included descriptions of earth features and objects that would suggest enhanced distance visual acuity. In contrast, some cosmonaut observations suggest a slight loss in their object discrimination during initial space flight. Astronauts have also mentioned a decreased near vision capability that did not recover to normal until return to earth. Duntley space vision experiment, USSR space vision experiments, and visual function testers are described.

  15. Functional programming in JavaScript

    CERN Document Server

    Mantyla, Dan

    2015-01-01

    If you are a JavaScript developer interested in learning functional programming, looking for the quantum leap towards mastering the JavaScript language, or just want to become a better programmer in general, then this book is ideal for you. It is aimed at programmers involved in developing reactive frontend apps, server-side apps that wrangle with reliability and concurrency, and everything in between.

  16. Study of the first-order transition in the spin-1 Blume–Capel model by using effective-field theory

    Energy Technology Data Exchange (ETDEWEB)

    Costabile, Emanuel [Departamento de Física, Universidade Federal do Amazonas, 3000, Japiim, 69077-000, Manaus, AM (Brazil); Amazonas, Marcio A. [Departamento de Física, Universidade Federal do Amazonas, 3000, Japiim, 69077-000, Manaus, AM (Brazil); Instituto Federal de Educação, Ciência e Tecnologia do Amazonas, 1975, Sete de Setembro, 69020-120, Manaus, AM (Brazil); Viana, J. Roberto [Departamento de Física, Universidade Federal do Amazonas, 3000, Japiim, 69077-000, Manaus, AM (Brazil); Sousa, J. Ricardo de, E-mail: jsousa@ufam.edu.br.br [Departamento de Física, Universidade Federal do Amazonas, 3000, Japiim, 69077-000, Manaus, AM (Brazil); National Institute of Science and Technology for Complex Systems, Universidade Federal do Amazonas, 3000, Japiim, 69077-000, Manaus, AM (Brazil)

    2012-10-01

    The spin-1 Blume–Capel model on a square lattice is studied by using an effective-field theory (EFT) with correlation. We propose an expression for the free energy within the EFT. The phase diagram is constructed in the temperature (T) and single-ion anisotropy amplitude (D) plane. The first-order transition line is obtained by Maxwell construction (comparison between free energies). Our results predict first-order transitions at low temperatures and large anisotropy strengths, which correspond in the phase diagram to the existence of a tricritical point (TCP). We compare our results with mean-field approximation (MFA), that show a qualitative correct behavior for the phase diagram. -- Highlights: ► In this Letter we have studied the spin-1 Blume–Capel model by using effective-field theory (EFT). ► The first-order line is obtained for the first time. ► The model presents second and first-order phase transitions. ► We propose a functional to treat the first-order line. ► We discuss other alternative by using EFT to study first-order line.

  17. 750 GeV diphoton excess and strongly first-order electroweak phase transition

    Science.gov (United States)

    Perelstein, Maxim; Tsai, Yu-Dai

    2016-07-01

    A new scalar particle, coupled to photons and gluons via loops of vectorlike quarks, provides a simple theoretical interpretation of the 750 GeV diphoton excess reported by the experiments at the Large Hadron Collider (LHC). In this paper, we show that this model contains a large, phenomenologically viable parameter space region in which the electroweak phase transition (EWPT) is strongly first order, opening the possibility that the electroweak baryogenesis mechanism can be realized in this context. A large coupling between the Higgs doublet and the heavy scalar, required for a strongly first-order EWPT, can arise naturally in composite Higgs models. The scenario makes robust predictions that will be tested in near-future experiments. The cross section of resonant di-Higgs production at the 13 TeV LHC is predicted to be at least 20 fb, while the Higgs cubic self-coupling is enhanced by 40% or more with respect to its Standard Model (SM) value.

  18. A Maple package to find first order differential invariants of 2ODEs via a Darboux approach

    Science.gov (United States)

    Avellar, J.; Duarte, L. G. S.; da Mota, L. A. C. P.

    2014-01-01

    Here we present an implementation of a semi-algorithm to find elementary first order differential invariants (elementary first integrals) of a class of rational second order ordinary differential equations (rational 2ODEs). The algorithm was developed in Duarte and da Mota (2009) [18]; it is based on a Darboux-type procedure, and it is an attempt to construct an analog (generalization) of the method built by Prelle and Singer (1983) [6] for rational first order ordinary differential equations (rational 1ODEs). to deal, this time, with 2ODEs. The FiOrDi package presents a set of software routines in Maple for dealing with rational 2ODEs. The package presents commands permitting research investigations of some algebraic properties of the ODE that is being studied.

  19. Anomalous critical slowdown at a first order phase transition in single polymer chains

    Science.gov (United States)

    Zhang, Shuangshuang; Qi, Shuanhu; Klushin, Leonid I.; Skvortsov, Alexander M.; Yan, Dadong; Schmid, Friederike

    2017-08-01

    Using Brownian dynamics, we study the dynamical behavior of a polymer grafted onto an adhesive surface close to the mechanically induced adsorption-stretching transition. Even though the transition is first order (in the infinite chain length limit, the stretching degree of the chain jumps discontinuously), the characteristic relaxation time is found to grow according to a power law as the transition point is approached. We present a dynamic effective interface model which reproduces these observations and provides an excellent quantitative description of the simulation data. The generic nature of the theoretical model suggests that the unconventional mixing of features that are characteristic for first-order transitions (a jump in an order parameter) and features that are characteristic of critical points (an anomalous slowdown) may be a common phenomenon in force-driven phase transitions of macromolecules.

  20. Discrete gravity as a local theory of the Poincare group in the first-order formalism

    Energy Technology Data Exchange (ETDEWEB)

    Gionti, Gabriele [Vatican Observatory Research Group, Steward Observatory, 933 North Cherry Avenue, University of Arizona, Tucson, AZ 85721 (United States); Specola Vaticana, V-00120 Citta Del Vaticano (Vatican City State, Holy See,)

    2005-10-21

    A discrete theory of gravity, locally invariant under the Poincare group, is considered as in a companion paper. We define a first-order theory, in the sense of Palatini, on the metric-dual Voronoi complex of a simplicial complex. We follow the same spirit as the continuum theory of general relativity in the Cartan formalism. The field equations are carefully derived taking in account the constraints of the theory. They look very similar to first-order Einstein continuum equations in the Cartan formalism. It is shown that in the limit of small deficit angles these equations have Regge calculus, locally, as the only solution. A quantum measure is easily defined which does not suffer the ambiguities of Regge calculus, and a coupling with fermionic matter is easily introduced.

  1. Constraint-preserving boundary conditions in the 3+1 first-order approach

    CERN Document Server

    Bona, C

    2010-01-01

    A set of stable energy-momentum constraint-preserving boundary conditions are proposed for the first-order Z4 case. No linear modes appear in the robust stability test. Also, a modified finite-differences stencil for boundary points is presented, which avoids the corner and vertex points even in cartesian-like grids. Moreover, the proposed boundary conditions are tested in a strong field scenario, the Gowdy waves metric, showing that the accumulated amount of energy-momentum constraint violations is of the same order of magnitude than the one generated by either periodic or reflection conditions, which are exact in the Gowdy waves case. As a side result, a new symmetrizer is explicitly given, which extends the parametric domain of symmetric hyperbolicity for the Z4 formalism. The aplication of these results to first-order BSSN-like formalisms is also considered.

  2. Verication of an LCF-Style First-Order Prover with Equality

    DEFF Research Database (Denmark)

    Jensen, Alexander Birch; Schlichtkrull, Anders; Villadsen, Jørgen

    2016-01-01

    We formalize in Isabelle/HOL the kernel of an LCF-style prover for first-order logic with equality from John Harrison’s Handbook of Practical Logic and Automated Reasoning. We prove the kernel sound and generate Standard ML code from the formalization. The generated code can then serve as a verif......We formalize in Isabelle/HOL the kernel of an LCF-style prover for first-order logic with equality from John Harrison’s Handbook of Practical Logic and Automated Reasoning. We prove the kernel sound and generate Standard ML code from the formalization. The generated code can then serve...... as a verified kernel. By doing this we also obtain verified components such as derived rules, a tableau prover, tactics, and a small declarative interactive theorem prover. We test that the kernel and the components give the same results as Harrison’s original on all the examples from his book...

  3. First-order D-type Iterative Learning Control for Nonlinear Systems with Unknown Relative Degree

    Institute of Scientific and Technical Information of China (English)

    SONGZhao-Qing; MAOJian-Qin; DAIShao-Wu

    2005-01-01

    The classical D-type iterative learning control law depends crucially on the relative degree of the controlled system, high order differential iterative learning law must be taken for systems with high order relative degree. It is very difficult to ascertain the relative degree of the controlled system for uncertain nonlinear systems. A first-order D-type iterative learning control design method is presented for a class of nonlinear systems with unknown relative degree based on dummy model in this paper. A dummy model with relative degree 1 is constructed for a class of nonlinear systems with unknown relative degree. A first-order D-type iterative learning control law is designed based on the dummy model, so that the dummy model can track the desired trajectory perfectly, and the controlled system can track the desired trajectory within a certain error. The simulation example demonstrates the feasibility and effectiveness of the presented method.

  4. Determining the first-order character of La (Fe,Mn ,Si ) 13

    Science.gov (United States)

    Bratko, Milan; Lovell, Edmund; Caplin, A. David; Basso, Vittorio; Barcza, Alexander; Katter, Matthias; Cohen, Lesley F.

    2017-02-01

    Definitive determination of first-order character of the magnetocaloric magnetic transition remains elusive. Here we use a microcalorimetry technique in two modes of operation to determine the contributions to entropy change from latent heat and heat capacity separately in an engineered set of La (Fe,Mn ,Si ) 13 samples. We compare the properties extracted by this method with those determined using magnetometry and propose a model-independent parameter that would allow the degree of first-order character to be defined across different families of materials. The microcalorimetry method is sufficiently sensitive to allow observation at temperatures just above the main magnetic transition of an additional peak feature in the low field heat capacity associated with the presence of Mn in these samples. The feature is of magnetic origin but is insensitive to magnetic field, explicable in terms of inhomogeneous occupancy of Mn within the lattice resulting in antiferromagnetic ordered Mn clusters.

  5. Scattering potentials with LS-terms from first-order Casimir operators

    Energy Technology Data Exchange (ETDEWEB)

    Levay, P. [Inst. of Phys., Tech. Univ. Budapest (Hungary)

    1995-10-21

    Using a first-order Casimir operator calculated in a non-standard realization for the so(3,1) algebra, we obtain a one-dimensional scattering problem with LS-type interaction terms. It is shown that for this realization the square of this operator can be expressed in terms of the usual quadratic Casimir. Due to this constraint the scattering states are completely specified by restricting the possible set of eigenvalues accordingly. The results show that the use of extra Casimir operators can provide additional insight into the group theoretical structure of the scattering problem. A generalization for the so(2n-1,1), n>2 case is also given. The underlying supersymmetry of the resulting Schrodinger equations is pointed out. The supersymmetric charge operators are related to our first-order Casimir operators. (author)

  6. Will electrical cyber-physical interdependent networks undergo first-order transition under random attacks?

    Science.gov (United States)

    Ji, Xingpei; Wang, Bo; Liu, Dichen; Dong, Zhaoyang; Chen, Guo; Zhu, Zhenshan; Zhu, Xuedong; Wang, Xunting

    2016-10-01

    Whether the realistic electrical cyber-physical interdependent networks will undergo first-order transition under random failures still remains a question. To reflect the reality of Chinese electrical cyber-physical system, the "partial one-to-one correspondence" interdependent networks model is proposed and the connectivity vulnerabilities of three realistic electrical cyber-physical interdependent networks are analyzed. The simulation results show that due to the service demands of power system the topologies of power grid and its cyber network are highly inter-similar which can effectively avoid the first-order transition. By comparing the vulnerability curves between electrical cyber-physical interdependent networks and its single-layer network, we find that complex network theory is still useful in the vulnerability analysis of electrical cyber-physical interdependent networks.

  7. First-order magnetic transition in Yb2Ti2O7

    Science.gov (United States)

    Lhotel, E.; Giblin, S. R.; Lees, M. R.; Balakrishnan, G.; Chang, L. J.; Yasui, Y.

    2014-06-01

    The very nature of the ground state of the pyrochlore compound Yb2Ti2O7 is much debated, because experimental results demonstrate evidence for either a disordered ground state or a long-range ordered ground state. Indeed, the delicate balance of exchange interactions and anisotropy is believed to lead to competing states, such as a quantum spin liquid state or a ferromagnetic state which may originate from an Anderson-Higgs transition. We present a detailed magnetization study demonstrating a first-order ferromagnetic transition at 245 and 150 mK in a powder and a single-crystal sample, respectively. Its first-order character is preserved up to applied fields of ˜200 Oe. The transition stabilizes a ferromagnetic component and involves slow dynamics in the magnetization. Residual fluctuations are also evidenced, the presence of which might explain some of the discrepancies between previously published data for Yb2Ti2O7.

  8. First-order correction to the Casimir force within an inhomogeneous medium

    CERN Document Server

    Bao, Fanglin; He, Sailing

    2015-01-01

    For the Casimir piston filled with an inhomogeneous medium, the Casimir energy is regularized and expressed with cylinder kernel coefficients by using the first-order perturbation theory. When the refraction index of the medium is smoothly inhomogeneous (i.e., derivatives of all orders exist), logarithmically cutoff-dependent term in Casimir energy is found. We show that in the piston model this term vanishes in the force and thus the Casimir force is always cutoff-independent, but this term will remain in the force in the half-space model and must be removed by additional regularization. We investigate the inhomogeneity of an exponentially decaying profile, and give the first-order corrections to both free Casimir energy and Casimir force. The present method can be extended to other inhomogeneous profiles. Our results should be useful for future relevant calculations and experimental studies.

  9. A new class of group field theories for first order discrete quantum gravity

    Energy Technology Data Exchange (ETDEWEB)

    Oriti, D [Institute for Theoretical Physics and Spinoza Institute, Utrecht University, Leuvenlaan 4, Utrecht 3584 TD (Netherlands); Tlas, T [Department of Applied Mathematics and Theoretical Physics, Centre for Mathematical Sciences, University of Cambridge, Wilberforce Road, Cambridge CB3 0WA (United Kingdom)], E-mail: d.oriti@phys.uu.nl, E-mail: t.tlas@damtp.cam.ac.uk

    2008-04-21

    Group field theories, a generalization of matrix models for 2D gravity, represent a second quantization of both loop quantum gravity and simplicial quantum gravity. In this paper, we construct a new class of group field theory models, for any choice of spacetime dimension and signature, whose Feynman amplitudes are given by path integrals for clearly identified discrete gravity actions, in first order variables. In the three-dimensional case, the corresponding discrete action is that of first order Regge calculus for gravity (generalized to include higher order corrections), while in higher dimensions, they correspond to a discrete BF theory (again, generalized to higher order) with an imposed orientation restriction on hinge volumes, similar to that characterizing discrete gravity. This new class of group field theories may represent a concrete unifying framework for loop quantum gravity and simplicial quantum gravity approaches.

  10. Destruction of first-order phase transition in a random-field Ising model

    Energy Technology Data Exchange (ETDEWEB)

    Crokidakis, Nuno; Nobre, Fernando D [Centro Brasileiro de Pesquisas Fisicas, Rua Xavier Sigaud 150, 22290-180, Rio de Janeiro-RJ (Brazil)], E-mail: nuno@if.uff.br, E-mail: fdnobre@cbpf.br

    2008-04-09

    The phase transitions that occur in an infinite-range-interaction Ising ferromagnet in the presence of a double Gaussian random magnetic field are analyzed. Such random fields are defined as a superposition of two Gaussian distributions, presenting the same width {sigma}. It is argued that this distribution is more appropriate for a theoretical description of real systems than other simpler cases, i.e. the bimodal ({sigma} = 0) and single Gaussian distributions. It is shown that a low-temperature first-order phase transition may be destroyed for increasing values of {sigma}, similarly to what happens in the compound Fe{sub x}Mg{sub 1-x}Cl{sub 2}, whose finite-temperature first-order phase transition is presumably destroyed by an increase in the field randomness.

  11. Supplementary First-Order All-Pass Filters with Two Grounded Passive Elements Using FDCCII

    Directory of Open Access Journals (Sweden)

    K. Pal

    2011-06-01

    Full Text Available In this study, two novel first-order all-pass filters are proposed using only one grounded resistor and one grounded capacitor along with a fully differential current conveyor (FDCCII. There is no element-matching restriction. The presented all-pass filter circuits can be made electronically tunable due to the electronic resistors. Furthermore, the presented circuits enjoy high-input impedance for easy cascadability. The theoretical results are verified with SPICE simulations.

  12. Large time behavior of weakly coupled systems of first-order Hamilton-Jacobi equations

    CERN Document Server

    Camilli, Fabio; Loreti, Paola; Nguyen, Vinh Duc

    2011-01-01

    We show a large time behavior result for class of weakly coupled systems of first-order Hamilton-Jacobi equations in the periodic setting. We use a PDE approach to extend the convergence result proved by Namah and Roquejoffre (1999) in the scalar case. Our proof is based on new comparison, existence and regularity results for systems. An interpretation of the solution of the system in terms of an optimal control problem with switching is given.

  13. Nonlinear boundary value problems for first order impulsive integro-differential equations

    Directory of Open Access Journals (Sweden)

    Xinzhi Liu

    1989-01-01

    Full Text Available In this paper, we investigate a class of first order impulsive integro-differential equations subject to certain nonlinear boundary conditions and prove, with the help of upper and lower solutions, that the problem has a solution lying between the upper and lower solutions. We also develop monotone iterative technique and show the existence of multiple solutions of a class of periodic boundary value problems.

  14. Double-wave solutions to quasilinear hyperbolic systems of first-order PDEs

    Science.gov (United States)

    Curró, C.; Manganaro, N.

    2017-10-01

    A reduction procedure for determining double-wave exact solutions to first-order hyperbolic systems of PDEs is proposed. The basic idea is to reduce the integration of the governing hyperbolic set of N partial differential equations to that of a 2 × 2 reduced hyperbolic model along with a further differential constraint. Therefore, the method of differential constraints is used in order to solve the auxiliary 2 × 2 system. An example of interest to viscoelasticity is presented.

  15. Impulsive Boundary Value Problems for First-order Ordinary Differential Inclusions

    Institute of Scientific and Technical Information of China (English)

    Yi-cheng Liu; Jun Wu; Zhi-xiang Li

    2007-01-01

    In this paper, we investigate the existence of solutions for impulsive first order ordinary differential inclusions which admitting nonconvex valued right hand side. We present two classes of results. In the first one, we rely on a fixed point theorem for contraction multivalued maps due to Covitz and Nadler, and for the second one, we use Schaefer's fixed point theorem combined with lower semi-continuous multivalued operators with decomposable values under weaker conditions.

  16. First Order Linear Homogeneous Ordinary Differential Equation in Fuzzy Environment Based On Laplace Transform

    Directory of Open Access Journals (Sweden)

    Sankar Prasad Mondal

    Full Text Available In this paper the First Order Linear Ordinary Differential Equations (FOLODE are described in fuzzy environment. Here coefficients and /or initial condition of FOLODE are taken as Generalized Triangular Fuzzy Numbers (GTFNs.The solution procedure of the FOLODE is developed by Laplace transform. It is illustrated by numerical examples. Finally imprecise bank account problem and concentration of drug in blood problem are described.

  17. On the existence of touch points for first-order state inequality constraints

    Science.gov (United States)

    Seywald, Hans; Cliff, Eugene M.

    1993-01-01

    The appearance of touch points in state constrained optimal control problems with general vector-valued control is studied. Under the assumption that the Hamiltonian is regular, touch points for first-order state inequalities are shown to exist only under very special conditions. In many cases of practical importance these conditions can be used to exclude touch points a priori without solving an optimal control problem. The results are demonstrated on a simple example.

  18. On decidability and model checking for a first order modal logic for value-passing processes

    Institute of Scientific and Technical Information of China (English)

    薛锐; 林惠民

    2003-01-01

    A semantic interpretation of a first order extension of Hennessy-Milner logic for value-passing processes, named HML(FO), is presented. The semantics is based on symbolic transitiongraphs with assignment. It is shown that the satisfiability of the two-variable sub-logic HML(FO2) ofHML(FO) is decidable, and the complexity discussed. Finally, a decision procedure for model checkingthe value-passing processes with respect to HML(FO2) is obtained.

  19. Thermodynamic parameters of the first order in low-concentration binary alloys

    Science.gov (United States)

    Bol'shov, L. A.; Korneichuk, S. K.

    2015-12-01

    Thermodynamic parameters of the first order (Wagner interaction parameter ɛ 2 (2) , enthalpy, and entropy parameter σ 2 (2) ) in low-concentration liquid binary alloys are considered. The values of these parameters for 32 binary systems are estimated from experimental data. A system of classification is proposed for the obtained data. These data are compared to similar data for aqueous solutions of nonelectrolytes. A qualitative explanation of the obtained differences is given.

  20. Gravitational waves from the first order phase transition of the Higgs field at high energy scales

    Science.gov (United States)

    Jinno, Ryusuke; Nakayama, Kazunori; Takimoto, Masahiro

    2016-02-01

    In a wide class of new physics models, there exist scalar fields that obtain vacuum expectation values of high energy scales. We study the possibility that the standard model Higgs field has experienced first order phase transition at the high energy scale due to the couplings with these scalar fields. We estimate the amount of gravitational waves produced by the phase transition, and discuss observational consequences.

  1. Modeling Pluto-Charon mutual eclipse events. I. First-order models

    Energy Technology Data Exchange (ETDEWEB)

    Dunbar, R.S.; Tedesco, E.F.

    1986-11-01

    The present first order analytical and numerical models of light curves due to mutual events between close planetary binaries, the effects of shadowing are included. Attention is given to the case of the Pluto-Charon system. The results of the analytical and numerical approaches agree to well within the expected light curve measurement error. The model predicts that the current mutual eclipse event series will end by November 1990. 12 references.

  2. Conformal invariance and Hojman conserved quantities of first order Lagrange systems

    Institute of Scientific and Technical Information of China (English)

    Chen Xiang-Wei; Liu Chang; Mei Feng-Xiang

    2008-01-01

    In this paper the conformal invaxiance by infinitesimal transformations of first order Lagrange systems is discussed in detail.The necessary and sufficient conditions of conformal invariance and Lie symmetry simultaneously by the action of infinitesimal transformations are given.Then it gets the Hojman conserved quantities of conformal invariance by the infinitesimal transformations.Finally an example is given to illustrate the application of the results.

  3. A Model for Sequential First Order Phage Transitions Occurring in the Underpotential Deposition of Metals,

    Science.gov (United States)

    1991-04-29

    22217-5000 1 1 1 11. TITLE (incde Securiy Clasicaton) A MODEL FOR SEQUENTIAL FIRST ORDER PHAGE TRANSITIONS OCCURRING IN THE UNDERPOTENTIAL DEPOSITION ...block number) FIELD GROUP SUB-GROUP 3 RACT (Continue on reverse if necessary and identify by block number) A model for the underpotential deposition of...this application we study the underpotential deposition of Cu on a Au(III) surface in the presence of sulfate ions. The voltammogram of the

  4. Simultaneous transport of parent and daughter compounds in aquifers with linear first-order sorption kinetics

    Science.gov (United States)

    Lindstrom, F. T.; Boersma, L.

    1991-06-01

    In soils, daughter compounds may be generated from a parent compound by microbial metabolism, chemical reactions, radioactive decay, or other mechanisms. These daughter compounds are also acted upon by soil physical, chemical and biological processes. A system often referred to as a cascade or chain of compounds system results. While a great deal of attention has been given to this problem with the linear equilibrium assumption applied uniformly to all transport and reacting compounds, little attention has been given to the simultaneous transport and fate of a parent-daughter chain with a first-order rate assumed for the adsorption-desorption kinetics of each compound and with the soil partitioned into three sorption classes. A general one-dimensional cascade or chain model for the simultaneous transport of parent and daughter compounds in sorbing, homogeneous, water table aquifers is presented. The model is based on an advective-dispersive mass accounting formulation for both compounds and includes: (a) first-order rate of conversion of parent to daughter; (2) first-order rates of loss of either parent or daughter or both due to metabolism, chemical reaction and/or irreversible processes; (3) partitioning of the aquifer material into three sorption classes, namely mildly sorbing, strongly sorbing and organic matter; (4) linear first-order kinetic rules for adsorption and desorption operating on each of the sorbing soil fractions for each compound; (5) constantly emitting sources of rectangular shape of parent compound; and (6) mass accounting boundary conditions; and a tailorable initial distribution on [0, ∞). Mathematical analysis yields a coupled, linear system of equations including two transport and fate equations, initial and boundary data, and six kinetic rules, namely three each for parent and daughter compound. A numerical scheme for solving the system of equations was developed using readily available procedures since analytical solutions could not be

  5. PMD compensation based on a new type dynamic first-order PMD compensator

    Institute of Scientific and Technical Information of China (English)

    Jiajun Wang; Shilong Pan; Jia Jia; Yanfu Yang; Caiyun Lou

    2006-01-01

    @@ A dynamic first-order polarization mode dispersion (PMD) compensator based on garnet and yttrium vanadate crystal has been proposed and implemented. Consisting of a differential group delay (DGD) generator and a Faraday rotator (FR), this PMD compensator has only two degrees of freedom. Feedback control and compensation algorithm are both very simple. Experimental results reveal the compensator behaviors to be excellent for PMD compensation in 40-Gb/s optical time domain multiplexing (OTDM)system.

  6. First-order derivative spectrophotometric estimation of nabumetone and paracetamol in tablet dosage form

    OpenAIRE

    Rote, Ambadas R.; Bhalerao, Swapnil R.

    2011-01-01

    Aim: To develop and validate a simple, precise and accurate spectrophotometric method for the simultaneous estimation of nabumetone and paracetamol in their combined tablet dosage form. This method is based on first-order derivative spectroscopy. Materials and Methods: For determination of sampling wavelengths, each of nabumetone and paracetamol were scanned in the wavelength range of 200–400 nm in the spectrum mode and sampling wavelengths were selected at 261 nm (zero crossing of nabumetone...

  7. First-order formalism for twinlike models with several real scalar fields

    CERN Document Server

    Bazeia, D; Losano, L; Menezes, R

    2014-01-01

    We investigate the presence of twinlike models in theories described by several real scalar fields. We focus on the first-order formalism, and we show how to build distinct scalar field theories that support the same extended solution, with the same energy density and the very same linear stability. The results are valid for two distinct classes of generalized models, that include the standard model and cover a diversity of generalized models of current interest in high energy physics.

  8. Classical field theories of first order and lagrangian submanifolds of premultisymplectic manifolds

    CERN Document Server

    Campos, Cédric M; Marrero, Juan Carlos

    2011-01-01

    A description of classical field theories of first order in terms of Lagrangian submanifolds of premultisymplectic manifolds is presented. For this purpose, a Tulczyjew's triple associated with a fibration is discussed. The triple is adapted to the extended Hamiltonian formalism. Using this triple, we prove that Euler-Lagrange and Hamilton-De Donder-Weyl equations are the local equations defining Lagrangian submanifolds of a premultisymplectic manifold.

  9. A universal first order formula defining the ring of integers in a number field

    CERN Document Server

    Park, Jennifer

    2012-01-01

    We show that the complement of the ring of integers in a number field K is Diophantine. This means the set of ring of integers in K can be written as {t in K | for all x_1, ..., x_N in K, f(t,x_1, ..., x_N) is not 0}. We will use global class field theory and generalize the ideas originating from Koenigsmann's recent result giving a universal first order formula for Z in Q.

  10. Gravitational Waves from the First Order Phase Transition of the Higgs Field at High Energy Scales

    CERN Document Server

    Jinno, Ryusuke; Takimoto, Masahiro

    2015-01-01

    In a wide class of new physics models, there exist scalar fields which obtain vacuum expectation values of high energy scales. We study the possibility that the standard model Higgs field has experienced first-order phase transition at the high energy scale due to the couplings with these scalar fields.We estimate the amount of gravitational waves produced by the phase transition, and discuss observational consequences.

  11. NUMERICAL SOLUTIONS OF DISCONTINUOUS BOUNDARY VALUE PROBLEMS FOR GENERAL ELLIPTIC COMPLEX EQUATIONS OF FIRST ORDER

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    In this paper,authors discuss the numerical methods of general discontinuous boundary value problems for elliptic complex equations of first order.They first give the well posedness of general discontinuous boundary value problems,reduce the discontinuousboundary value problems to a variation problem,and then find the numerical solutions ofabove problem by the finite element method.Finally authors give some error-estimates of the foregoing numerical solutions.

  12. Duality for Multitime Multiobjective Ratio Variational Problems on First Order Jet Bundle

    Directory of Open Access Journals (Sweden)

    Mihai Postolache

    2012-01-01

    Full Text Available We consider a new class of multitime multiobjective variational problems of minimizing a vector of quotients of functionals of curvilinear integral type. Based on the efficiency conditions for multitime multiobjective ratio variational problems, we introduce a ratio dual of generalized Mond-Weir-Zalmai type, and under some assumptions of generalized convexity, duality theorems are stated. We prove our weak duality theorem for efficient solutions, showing that the value of the objective function of the primal cannot exceed the value of the dual. Direct and converse duality theorems are stated, underlying the connections between the values of the objective functions of the primal and dual programs. As special cases, duality results of Mond-Weir-Zalmai type for a multitime multiobjective variational problem are obtained. This work further develops our studies in (Pitea and Postolache (2011.

  13. Phase conversion in a weakly first-order quark-hadron transition

    CERN Document Server

    Bessa, A; Mintz, B W

    2008-01-01

    We investigate the process of phase conversion in a thermally-driven {\\it weakly} first-order quark-hadron transition. This scenario is physically appealing even if the nature of this transition in equilibrium proves to be a smooth crossover for vanishing baryonic chemical potential. We construct an effective potential by combining the equation of state obtained within Lattice QCD for the partonic sector with that of a gas of resonances in the hadronic phase, and present numerical results on bubble profiles, nucleation rates and time evolution, including the effects from reheating on the dynamics for different expansion scenarios. Our findings confirm the standard picture of a cosmological first-order transition, in which the process of phase conversion is entirely dominated by nucleation, also in the case of a weakly first-order transition. On the other hand, we show that, even for expansion rates much lower than those expected in high-energy heavy ion collisions, nucleation is very unlikely, indicating that...

  14. Motion aftereffect of combined first-order and second-order motion.

    Science.gov (United States)

    van der Smagt, M J; Verstraten, F A; Vaessen, E B; van Londen, T; van de Grind, W A

    1999-01-01

    When, after prolonged viewing of a moving stimulus, a stationary (test) pattern is presented to an observer, this results in an illusory movement in the direction opposite to the adapting motion. Typically, this motion aftereffect (MAE) does not occur after adaptation to a second-order motion stimulus (i.e. an equiluminous stimulus where the movement is defined by a contrast or texture border, not by a luminance border). However, a MAE of second-order motion is perceived when, instead of a static test pattern, a dynamic test pattern is used. Here, we investigate whether a second-order motion stimulus does affect the MAE on a static test pattern (sMAE), when second-order motion is presented in combination with first-order motion during adaptation. The results show that this is indeed the case. Although the second-order motion stimulus is too weak to produce a convincing sMAE on its own, its influence on the sMAE is of equal strength to that of the first-order motion component, when they are adapted to simultaneously. The results suggest that the perceptual appearance of the sMAE originates from the site where first-order and second-order motion are integrated.

  15. Formulation of a universal first-order rate constant for enzymatic reactions.

    Science.gov (United States)

    Imoto, Taiji

    2013-01-01

    It is a common practice to employ k(cat)[E]₀/K(m) as a first-order rate constant for the analysis of an enzymatic reaction, where [E]₀ is the total enzyme concentration. I describe in this report a serious shortcoming in analyzing enzymatic reactions when kcat[E]₀/K(m) is employed and show that k(cat)[E]₀/K(m) can only be applied under very limited conditions. I consequently propose the use of a more universal first-order rate constant, k(cat)[ES](K)/[S]₀, where [ES](K) is the initial equilibrium concentration of the ES-complex derived from [E]₀, [S]₀ and K(m). Employing k(cat)[ES](K)/[S]₀ as the first-order rate constant enables all enzymatic reactions to be reasonably simulated under a wide range of conditions, and the catalytic and binding contributions to the rate constant of any enzyme can be determined under any and all conditions.

  16. First order coupled dynamic model of flexible space structures with time-varying configurations

    Science.gov (United States)

    Wang, Jie; Li, Dongxu; Jiang, Jianping

    2017-03-01

    This paper proposes a first order coupled dynamic modeling method for flexible space structures with time-varying configurations for the purpose of deriving the characteristics of the system. The model considers the first time derivative of the coordinate transformation matrix between the platform's body frame and the appendage's floating frame. As a result it can accurately predict characteristics of the system even if flexible appendages rotate with complex trajectory relative to the rigid part. In general, flexible appendages are fixed on the rigid platform or forced to rotate with a slow angular velocity. So only the zero order of the transformation matrix is considered in conventional models. However, due to neglecting of time-varying terms of the transformation matrix, these models introduce severe error when appendages, like antennas, for example, rotate with a fast speed relative to the platform. The first order coupled dynamic model for flexible space structures proposed in this paper resolve this problem by introducing the first time derivative of the transformation matrix. As a numerical example, a central core with a rotating solar panel is considered and the results are compared with those given by the conventional model. It has been shown that the first order terms are of great importance on the attitude of the rigid body and dynamic response of the flexible appendage.

  17. Neural heterogeneities determine response characteristics to second-, but not first-order stimulus features.

    Science.gov (United States)

    Metzen, Michael G; Chacron, Maurice J

    2015-02-18

    Neural heterogeneities are seen ubiquitously, but how they determine neural response properties remains unclear. Here we show that heterogeneities can either strongly, or not at all, influence neural responses to a given stimulus feature. Specifically, we recorded from peripheral electroreceptor neurons, which display strong heterogeneities in their resting discharge activity, in response to naturalistic stimuli consisting of a fast time-varying waveform (i.e., first-order) whose amplitude (i.e., second-order or envelope) varied slowly in the weakly electric fish Apteronotus leptorhynchus. Although electroreceptors displayed relatively homogeneous responses to first-order stimulus features, further analysis revealed two subpopulations with similar sensitivities that were excited or inhibited by increases in the envelope, respectively, for stimuli whose frequency content spanned the natural range. We further found that a linear-nonlinear cascade model incorporating the known linear response characteristics to first-order features and a static nonlinearity accurately reproduced experimentally observed responses to both first- and second-order features for all stimuli tested. Importantly, this model correctly predicted that the response magnitude is independent of either the stimulus waveform's or the envelope's frequency content. Further analysis of our model led to the surprising prediction that the mean discharge activity can be used to determine whether a given neuron is excited or inhibited by increases in the envelope. This prediction was validated by our experimental data. Thus, our results provide key insight as to how neural heterogeneities can determine response characteristics to some, but not other, behaviorally relevant stimulus features.

  18. Hardware efficient implementation of DFT using an improved first-order moments based cyclic convolution structure

    Science.gov (United States)

    Xiong, Jun; Liu, J. G.; Cao, Li

    2015-12-01

    This paper presents hardware efficient designs for implementing the one-dimensional (1D) discrete Fourier transform (DFT). Once DFT is formulated as the cyclic convolution form, the improved first-order moments-based cyclic convolution structure can be used as the basic computing unit for the DFT computation, which only contains a control module, a barrel shifter and (N-1)/2 accumulation units. After decomposing and reordering the twiddle factors, all that remains to do is shifting the input data sequence and accumulating them under the control of the statistical results on the twiddle factors. The whole calculation process only contains shift operations and additions with no need for multipliers and large memory. Compared with the previous first-order moments-based structure for DFT, the proposed designs have the advantages of less hardware consumption, lower power consumption and the flexibility to achieve better performance in certain cases. A series of experiments have proven the high performance of the proposed designs in terms of the area time product and power consumption. Similar efficient designs can be obtained for other computations, such as DCT/IDCT, DST/IDST, digital filter and correlation by transforming them into the forms of the first-order moments based cyclic convolution.

  19. Data fusion in cyber security: first order entity extraction from common cyber data

    Science.gov (United States)

    Giacobe, Nicklaus A.

    2012-06-01

    The Joint Directors of Labs Data Fusion Process Model (JDL Model) provides a framework for how to handle sensor data to develop higher levels of inference in a complex environment. Beginning from a call to leverage data fusion techniques in intrusion detection, there have been a number of advances in the use of data fusion algorithms in this subdomain of cyber security. While it is tempting to jump directly to situation-level or threat-level refinement (levels 2 and 3) for more exciting inferences, a proper fusion process starts with lower levels of fusion in order to provide a basis for the higher fusion levels. The process begins with first order entity extraction, or the identification of important entities represented in the sensor data stream. Current cyber security operational tools and their associated data are explored for potential exploitation, identifying the first order entities that exist in the data and the properties of these entities that are described by the data. Cyber events that are represented in the data stream are added to the first order entities as their properties. This work explores typical cyber security data and the inferences that can be made at the lower fusion levels (0 and 1) with simple metrics. Depending on the types of events that are expected by the analyst, these relatively simple metrics can provide insight on their own, or could be used in fusion algorithms as a basis for higher levels of inference.

  20. Closed form solutions and dominant elimination pathways of simultaneous first-order and Michaelis-Menten kinetics.

    Science.gov (United States)

    Wu, Xiaotian; Li, Jun; Nekka, Fahima

    2015-04-01

    The current study aims to provide the closed form solutions of one-compartment open models exhibiting simultaneous linear and nonlinear Michaelis-Menten elimination kinetics for single- and multiple-dose intravenous bolus administrations. It can be shown that the elimination half-time ([Formula: see text]) has a dose-dependent property and is upper-bounded by [Formula: see text] of the first-order elimination model. We further analytically distinguish the dominant role of different elimination pathways in terms of model parameters. Moreover, for the case of multiple-dose intravenous bolus administration, the existence and local stability of the periodic solution at steady state are established. The closed form solutions of the models are obtained through a newly introduced function motivated by the Lambert W function.

  1. First-order system least-squares for second-order elliptic problems with discontinuous coefficients: Further results

    Energy Technology Data Exchange (ETDEWEB)

    Bloechle, B.; Manteuffel, T.; McCormick, S.; Starke, G.

    1996-12-31

    Many physical phenomena are modeled as scalar second-order elliptic boundary value problems with discontinuous coefficients. The first-order system least-squares (FOSLS) methodology is an alternative to standard mixed finite element methods for such problems. The occurrence of singularities at interface corners and cross-points requires that care be taken when implementing the least-squares finite element method in the FOSLS context. We introduce two methods of handling the challenges resulting from singularities. The first method is based on a weighted least-squares functional and results in non-conforming finite elements. The second method is based on the use of singular basis functions and results in conforming finite elements. We also share numerical results comparing the two approaches.

  2. The Widom-Rowlinson mixture on a sphere: elimination of exponential slowing down at first-order phase transitions.

    Science.gov (United States)

    Fischer, T; Vink, R L C

    2010-03-17

    Computer simulations of first-order phase transitions using 'standard' toroidal boundary conditions are generally hampered by exponential slowing down. This is partly due to interface formation, and partly due to shape transitions. The latter occur when droplets become large such that they self-interact through the periodic boundaries. On a spherical simulation topology, however, shape transitions are absent. We expect that by using an appropriate bias function, exponential slowing down can be largely eliminated. In this work, these ideas are applied to the two-dimensional Widom-Rowlinson mixture confined to the surface of a sphere. Indeed, on the sphere, we find that the number of Monte Carlo steps needed to sample a first-order phase transition does not increase exponentially with system size, but rather as a power law τ α V(α), with α≈2.5, and V the system area. This is remarkably close to a random walk for which α(RW) = 2. The benefit of this improved scaling behavior for biased sampling methods, such as the Wang-Landau algorithm, is investigated in detail.

  3. A Polarimetric First-Order Model of Soil Moisture Effects on the DInSAR Coherence

    Directory of Open Access Journals (Sweden)

    Simon Zwieback

    2015-06-01

    Full Text Available Changes in soil moisture between two radar acquisitions can impact the observed coherence in differential interferometry: both coherence magnitude |Υ| and phase Φ are affected. The influence on the latter potentially biases the estimation of deformations. These effects have been found to be variable in magnitude and sign, as well as dependent on polarization, as opposed to predictions by existing models. Such diversity can be explained when the soil is modelled as a half-space with spatially varying dielectric properties and a rough interface. The first-order perturbative solution achieves–upon calibration with airborne L band data–median correlations ρ at HH polarization of 0.77 for the phase Φ, of 0.50 for |Υ|, and for the phase triplets ≡ of 0.56. The predictions are sensitive to the choice of dielectric mixing model, in particular the absorptive properties; the differences between the mixing models are found to be partially compensatable by varying the relative importance of surface and volume scattering. However, for half of the agricultural fields the Hallikainen mixing model cannot reproduce the observed sensitivities of the phase to soil moisture. In addition, the first-order expansion does not predict any impact on the HV coherence, which is however empirically found to display similar sensitivities to soil moisture as the co-pol channels HH and VV. These results indicate that the first-order solution, while not able to reproduce all observed phenomena, can capture some of the more salient patterns of the effect of soil moisture changes on the HH and VV DInSAR signals. Hence it may prove useful in separating the deformations from the moisture signals, thus yielding improved displacement estimates or new ways for inferring soil moisture.

  4. Can a first-order exponential decay model fit heart rate recovery after resistance exercise?

    Science.gov (United States)

    Bartels-Ferreira, Rhenan; de Sousa, Élder D; Trevizani, Gabriela A; Silva, Lilian P; Nakamura, Fábio Y; Forjaz, Cláudia L M; Lima, Jorge Roberto P; Peçanha, Tiago

    2015-03-01

    The time-constant of postexercise heart rate recovery (HRRτ ) obtained by fitting heart rate decay curve by a first-order exponential fitting has being used to assess cardiac autonomic recovery after endurance exercise. The feasibility of this model was not tested after resistance exercise (RE). The aim of this study was to test the goodness of fit of the first-order exponential decay model to fit heart rate recovery (HRR) after RE. Ten healthy subjects participated in the study. The experimental sessions occurred in two separated days and consisted of performance of 1 set of 10 repetitions at 50% or 80% of the load achieved on the one-repetition maximum test [low-intensity (LI) and high-intensity (HI) sessions, respectively]. Heart rate (HR) was continuously registered before and during exercise and also for 10 min of recovery. A monoexponential equation was used to fit the HRR curve during the postexercise period using different time windows (i.e. 30, 60, 90, … 600 s). For each time window, (i) HRRτ was calculated and (ii) variation of HR explained by the model (R(2) goodness of fit index) was assessed. The HRRτ showed stabilization from 360 and 420 s on LI and HI, respectively. Acceptable R(2) values were observed from the 360 s on LI (R(2) > 0.65) and at all tested time windows on HI (R(2) > 0.75). In conclusion, this study showed that using a minimum length of monitoring (~420 s) HRR after RE can be adequately modelled by a first-order exponential fitting. © 2014 Scandinavian Society of Clinical Physiology and Nuclear Medicine. Published by John Wiley & Sons Ltd.

  5. The nature of the first order isostructural transition in GdRhSn

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, Sachin [Department of Physics, Indian Institute of Technology Bombay, Mumbai 400076 (India); Suresh, K.G., E-mail: suresh@phy.iitb.ac.in [Department of Physics, Indian Institute of Technology Bombay, Mumbai 400076 (India); Nigam, A.K. [Tata Institute of Fundamental Research, Homi Bhabha Road, Mumbai 400005 (India); Mudryk, Y.; Paudyal, D. [Ames Laboratory, Iowa State University, Ames, IA 50011-3020 (United States); Pecharsky, V.K.; Gschneidner, K.A. [Ames Laboratory, Iowa State University, Ames, IA 50011-3020 (United States); Department of Materials Science and Engineering, Iowa State University, Ames, IA 50011-2300 (United States)

    2014-11-15

    Highlights: • GdRhSn has been studied by means of different measurements and shows an iso-structural transition in paramagnetic regime. • Experimental and theoretical studies confirm the iso-structural transition in paramagnetic regime. • The change in unit cell volume is discontinuous which reveals the first order nature of iso-structural transition. • The compound also shows considerable MCE around its ordering temperature. - Abstract: We present structural, magnetic, thermal, magnetocaloric, and electrical transport properties of polycrystalline GdRhSn. Magnetization data show that it orders antiferromagnetically at T{sub N} = 16.2 K. The compound has the ZrNiAl type hexagonal crystal structure at room temperature and undergoes a first order iso-structural transition in the paramagnetic state at 245 K. The unit cell volume change at the transition is small (−0.07%) but discontinuous, in agreement with the first-order nature of the transition observed by magnetic, transport, and heat capacity measurements. The anisotropic changes of the lattice parameters are Δa/a = 0.28% and Δc/c = −0.64% on cooling. A substantial change in the 4f and conduction electron hybridization, giving rise to an increased integrated DOS, occurs when the high temperature phase transforms to the low temperature phase. A moderate magnetocaloric effect at T{sub N} (ΔS{sub M} = −6.5 J/kg K and ΔT{sub ad} = 4.5 K for ΔH = 50 kOe) has been measured using both magnetization and heat capacity data.

  6. Application of first order kinetics to characterize MTBE natural attenuation in groundwater.

    Science.gov (United States)

    Metcalf, Meredith J; Stevens, Graham J; Robbins, Gary A

    2016-04-01

    Methyl tertiary butyl ether (MTBE) was a gasoline oxygenate that became widely used in reformulated gasoline as a means to reduce air pollution in the 1990s. Unfortunately, many of the underground storage tanks containing reformulated gasoline experienced subsurface releases which soon became a health concern given the increase in public and private water supplies containing MTBE. Many states responded to this by banning the use of MTBE as an additive, including Connecticut. Although MTBE dissipates by natural attenuation, it continues to be prevalent in groundwater long after the Connecticut ban in 2004. This study estimated the rate of the natural attenuation in groundwater following the Connecticut ban by evaluating the MTBE concentration two years prior to and two years after the MTBE ban at eighty-three monitoring wells from twenty-two retail gasoline stations where MTBE contamination was observed. Sites chosen for this study had not undergone active remediation ensuring no artificial influence to the natural attenuation processes that controls the migration and dissipation of MTBE. Results indicate that MTBE has dissipated in the natural environment, at more than 80% of the sites and at approximately 82% of the individual monitoring wells. In general, dissipation approximated first order kinetics. Dissipation half-lives, calculated using concentration data from the two year period after the ban, ranged from approximately three weeks to just over seven years with an average half-life of 7.3 months with little variability in estimates for different site characteristics. The accuracy of first order estimates to predict further MTBE dissipation were tested by comparing predicted concentrations with those observed after the two year post-ban period; the predicted concentrations closely match the observed concentrations which supports the use of first order kinetics for predictions of this nature.

  7. First-Order Transitions and the Magnetic Phase Diagram of CeSb

    DEFF Research Database (Denmark)

    Lebech, Bente; Clausen, Kurt Nørgaard; Vogt, O.

    1980-01-01

    The high-temperature (14-17K) low-magnetic field (0-0.8 T) region of the phase diagram of the anomalous antiferromagnet CeSb has been reinvestigated by neutron diffraction in an attempt to locate a possible tricritical point. Previous neutron diffraction studies indicated that a tricritical point...... might exist in the magnetic phase diagram of CeSb at 16K for a field of approximately 0.3 T. The present study concludes that the transitions from the paramagnetic to the magnetically ordered states are of first order for fields below 0.8 T. Within the experimental accuracy no change has been observed...

  8. Poverty mapping based on first order dominance with an example from Mozambique

    DEFF Research Database (Denmark)

    Arndt, Channing; Hussain, Azhar; Salvucci, Vincenzo

    We explore a novel first order dominance (FOD) approach to poverty mapping and compare its properties to small area estimation. The FOD approach uses census data directly; is straightforward to implement; is multidimensional allowing for a broad conception of welfare; and accounts rigorously...... for welfare distributions in both levels and trends. An application to Mozambique highlights the value of the approach, including its advantages in the monitoring and evaluation of public expenditures. We conclude that the FOD approach to poverty mapping constitutes a useful addition to the toolkit of policy...

  9. Poverty Mapping Based on First-Order Dominance with an Example from Mozambique

    DEFF Research Database (Denmark)

    Arndt, Channing; Hussain, Azhar; Salvucci, Vincenzo

    2016-01-01

    We explore a novel first-order dominance (FOD) approach to poverty mapping and compare its properties to small-area estimation. The FOD approach uses census data directly, is straightforward to implement, is multidimensional allowing for a broad conception of welfare and accounts rigorously...... for welfare distributions in both levels and trends. An application to Mozambique highlights the value of the approach, including its advantages in the monitoring and evaluation of public expenditures. We conclude that the FOD approach to poverty mapping constitutes a useful addition to the toolkit of policy...

  10. New Gain Controllable Resistor-less Current-mode First Order Allpass Filter and its Application

    Directory of Open Access Journals (Sweden)

    W. Jaikla

    2012-04-01

    Full Text Available New first order allpass filter (APF in current mode, constructed from 2 CCCCTAs and grounded capacitor, is presented. The current gain and phase shift can be electronically /orthogonally controlled. Low input and high output impedances are achieved which make the circuit to be easily cascaded to the current-mode circuit without additional current buffers. The operation of the proposed filter has been verified through simulation results which confirm the theoretical analysis. The application example as current-mode quadrature oscillator with non-interactive current control for both of oscillation condition and oscillation frequency is included to show the usability of the proposed filter.

  11. Some New First-Order All-Pass Realizations Using CCII

    Directory of Open Access Journals (Sweden)

    Kirat Pal

    2004-01-01

    Full Text Available Some new first-order all-pass filters using a second-generation current conveyor are reported. Two circuits have higher input impedance than reported very recently and use a grounded capacitor. Additionally two more circuits have been reported, one of which has minimum passive and active components and has the facility of single resistance tuning. The other circuit has high input impedance and uses two current conveyors but has one passive component less than the similar circuits reported earlier.

  12. Evolution of order and chaos across a first-order quantum phase transition

    Energy Technology Data Exchange (ETDEWEB)

    Leviatan, A., E-mail: ami@phys.huji.ac.il [Racah Institute of Physics, Hebrew University, Jerusalem 91904 (Israel); Macek, M., E-mail: mmacek@phys.huji.ac.il [Racah Institute of Physics, Hebrew University, Jerusalem 91904 (Israel)

    2012-07-24

    We study the evolution of the dynamics across a generic first-order quantum phase transition in an interacting boson model of nuclei. The dynamics inside the phase coexistence region exhibits a very simple pattern. A classical analysis reveals a robustly regular dynamics confined to the deformed region and well separated from a chaotic dynamics ascribed to the spherical region. A quantum analysis discloses regular bands of states in the deformed region, which persist to energies well above the phase-separating barrier, in the face of a complicated environment. The impact of kinetic collective rotational terms on this intricate interplay of order and chaos is investigated.

  13. Evolution of order and chaos across a first-order quantum phase transition

    CERN Document Server

    Leviatan, A

    2012-01-01

    We study the evolution of the dynamics across a generic first order quantum phase transition in an interacting boson model of nuclei. The dynamics inside the phase coexistence region exhibits a very simple pattern. A classical analysis reveals a robustly regular dynamics confined to the deformed region and well separated from a chaotic dynamics ascribed to the spherical region. A quantum analysis discloses regular bands of states in the deformed region, which persist to energies well above the phase-separating barrier, in the face of a complicated environment. The impact of kinetic collective rotational terms on this intricate interplay of order and chaos is investigated.

  14. Regularity and chaos at critical points of first-order quantum phase transitions

    CERN Document Server

    Macek, Michal

    2011-01-01

    We study the interplay between regular and chaotic dynamics at the critical point of a first order quantum shape-phase transition in an interacting boson model of nuclei. A classical analysis reveals a distinct behavior of the coexisting phases in a broad energy range. The dynamics is completely regular in the deformed phase while it becomes strongly chaotic in the spherical phase. A quantum analysis of the spectra separates the regular states from the irregular ones, assigns them to particular phases and discloses persisting regular rotational bands in the deformed region.

  15. Order, Chaos and Quasi Symmetries in a First-Order Quantum Phase Transition

    CERN Document Server

    Leviatan, A

    2014-01-01

    We study the competing order and chaos in a first-order quantum phase transition with a high barrier. The boson model Hamiltonian employed, interpolates between its U(5) (spherical) and SU(3) (deformed) limits. A classical analysis reveals regular (chaotic) dynamics at low (higher) energy in the spherical region, coexisting with a robustly regular dynamics in the deformed region. A quantum analysis discloses, amidst a complicated environment, persisting regular multiplets of states associated with partial U(5) and quasi SU(3) dynamical symmetries.

  16. Polarization Switching in Ferroelectric Thin Films Undergoing First-Order Phase Transitions

    Directory of Open Access Journals (Sweden)

    L. A. Bakaleinikov

    2010-01-01

    Full Text Available The main switching properties in ferroelectrics undergoing first-order phase transitions are simulated within the framework of the extended Ishibashi dipole-lattice model including the dipole-dipole interaction in a two-dimensional case for ferroelectric nanoscale objects. The peculiarities of the temperature dependence of the switching rate and the pyroelectric coefficient are discussed in the range of coexistence of the metastable states. The used coefficients of the long-range and short-range interactions between the dipoles are taken from the dielectric and structure measurements in BaTiO3.

  17. Relativistic transport theory for simple fluids at first order in the gradients: a stable picture

    CERN Document Server

    Sandoval-Villalbazo, A; García-Colin, L S

    2008-01-01

    In this paper we show how using a relativistic kinetic equation. The ensuing expression for the heat flux can be casted in the form required by Classical Irreversible Thermodynamics. Indeed, it is linearly related to the temperature and number density gradients and not to the acceleration as the so called first order in the gradients theories contend. Since the specific expressions for the transport coefficients are irrelevant for our purposes, the BGK form of the kinetic equation is used. Moreover, from the resulting hydrodynamic equations it is readily seen that no instabilities are present in the transverse hydrodynamic velocity mode of the simple relativistic fluid.

  18. Independent Component Analysis of Complex Valued Signals Based on First-order Statistics

    Directory of Open Access Journals (Sweden)

    P.C. Xu

    2013-12-01

    Full Text Available This paper proposes a novel method based on first-order statistics, aims to solve the problem of the independent component extraction of complex valued signals in instantaneous linear mixtures. Single-step and iterative algorithms are proposed and discussed under the engineering practice. Theoretical performance analysis about asymptotic interference-to-signal ratio (ISR and probability of correct support estimation (PCE are accomplished. Simulation examples validate the theoretic analysis, and demonstrate that the single-step algorithm is extremely effective. Moreover, the iterative algorithm is more efficient than complex FastICA under certain circumstances.

  19. Analytic Tableaux for Simple Type Theory and its First-Order Fragment

    CERN Document Server

    Brown, Chad E

    2010-01-01

    We study simple type theory with primitive equality (STT) and its first-order fragment EFO, which restricts equality and quantification to base types but retains lambda abstraction and higher-order variables. As deductive system we employ a cut-free tableau calculus. We consider completeness, compactness, and existence of countable models. We prove these properties for STT with respect to Henkin models and for EFO with respect to standard models. We also show that the tableau system yields a decision procedure for three EFO fragments.

  20. Some remarks on real numbers induced by first-order spectra

    DEFF Research Database (Denmark)

    Jakobsen, Sune; Simonsen, Jakob Grue

    2016-01-01

    The spectrum of a first-order sentence is the set of natural numbers occurring as the cardinalities of finite models of the sentence. In a recent survey, Durand et al. introduce a new class of real numbers, the spectral reals, induced by spectra and pose two open problems associated to this class...... may occur, and (iv) every right-computable real number between 0 and 1 occurs as the subword entropy of a spectral real. In addition, Durand et al. note that the set of spectral reals is not closed under addition or multiplication. We extend this result by showing that the class of spectral reals...

  1. Statistical properties of first-order bang-bang Pll with nonzero loop delay

    OpenAIRE

    Chun, Byungjin; Kennedy, Michael Peter

    2008-01-01

    A method to solve the stationary state probability is presented for the first-order bang-bang phase-locked loop (BBPLL) with nonzero loop delay. This is based on a delayed Markov chain model and a state How diagram for tracing the state history due to the loop delay. As a result, an eigenequation is obtained, and its closed form solutions are derived for some cases. After obtaining the state probability, statistical characteristics such as mean gain of the binary phase detector and timing err...

  2. First Order Electroweak Phase Transition from (Non)Conformal Extensions of the Standard Model

    DEFF Research Database (Denmark)

    Sannino, Francesco; Virkajärvi, Jussi

    2015-01-01

    We analyse and compare the finite-temperature electroweak phase transition properties of classically (non)conformal extensions of the Standard Model. In the classically conformal scenarios the breaking of the electroweak symmetry is generated radiatively. The models feature new scalars coupled...... conformally to the Higgs sector as well as new fermions. We uncover the parameter space leading to a first order phase transition with(out) the Veltman conditions. We also discuss dark (matter) aspects of some of the models and compare with existing literature when appropriate. We observe that to accommodate...

  3. Single MIMO-OTA and single-grounded-capacitor-based first-order allpass filter design

    Science.gov (United States)

    Psychalinos, C.; Pal, K.; Khanday, F. A.

    2014-12-01

    A novel first-order voltage-mode allpass (AP) filter employing a single multiple-input-multiple-output operational-transconductance-amplifier (MIMO-OTA) and a single grounded capacitor is introduced in this article. Compared to the corresponding already published topologies, the offered benefits are as follows: it employs minimum number of active and passive components; the only capacitor is grounded, which is good for a monolithic integration of an IC; and the absence of any matching condition for its realisability. The performance of the proposed circuit has been evaluated through simulation results, utilising the analogue design environment of Cadence software.

  4. Superdirective dual-polarized first-order probe for SNF measurements at low frequencies

    DEFF Research Database (Denmark)

    Kim, Oleksiy S.

    2016-01-01

    A design of a dual linearly polarized superdirective array of electrically small self-resonant magnetic dipole elements is presented. The array exhibits the bandwidth of 12 MHz at 435 MHz central frequency with the directivity exceeding 9 dBi and the parasitic azimuthal modes suppressed below −45 d......B. With these characteristics the array can effectively be used as a compact and light-weight first-order probe in spherical near-field (SNF) antenna measurements at low frequencies....

  5. Strongly first-order electroweak phase transition and classical scale invariance

    Science.gov (United States)

    Farzinnia, Arsham; Ren, Jing

    2014-10-01

    In this work, we examine the possibility of realizing a strongly first-order electroweak phase transition within the minimal classically scale-invariant extension of the standard model (SM), previously proposed and analyzed as a potential solution to the hierarchy problem. By introducing one complex gauge-singlet scalar and three (weak scale) right-handed Majorana neutrinos, the scenario was successfully rendered capable of achieving a radiative breaking of the electroweak symmetry (by means of the Coleman-Weinberg mechanism), inducing nonzero masses for the SM neutrinos (via the seesaw mechanism), presenting a pseudoscalar dark matter candidate (protected by the CP symmetry of the potential), and predicting the existence of a second CP-even boson (with suppressed couplings to the SM content) in addition to the 125 GeV scalar. In the present treatment, we construct the full finite-temperature one-loop effective potential of the model, including the resummed thermal daisy loops, and demonstrate that finite-temperature effects induce a first-order electroweak phase transition. Requiring the thermally driven first-order phase transition to be sufficiently strong at the onset of the bubble nucleation (corresponding to nucleation temperatures TN˜100-200 GeV) further constrains the model's parameter space; in particular, an O(0.01) fraction of the dark matter in the Universe may be simultaneously accommodated with a strongly first-order electroweak phase transition. Moreover, such a phase transition disfavors right-handed Majorana neutrino masses above several hundreds of GeV, confines the pseudoscalar dark matter masses to ˜1-2 TeV, predicts the mass of the second CP-even scalar to be ˜100-300 GeV, and requires the mixing angle between the CP-even components of the SM doublet and the complex singlet to lie within the range 0.2≲sinω ≲0.4. The obtained results are displayed in comprehensive exclusion plots, identifying the viable regions of the parameter space

  6. Boundary field induced first-order transition in the 2D Ising model: exact study

    Energy Technology Data Exchange (ETDEWEB)

    Clusel, Maxime [Institut Laue-Langevin, 6 rue Horowitz BP156 X, 38042 Grenoble Cedex (France); Fortin, Jean-Yves [Laboratoire Poncelet, 119002, Bolshoy Vlasyevskiy Pereulok 11, Moscow (Russian Federation)

    2006-02-03

    We present in this paper an exact study of a first-order transition induced by an inhomogeneous boundary magnetic field in the 2D Ising model. From a previous analysis of the interfacial free energy in the discrete case (Clusel and Fortin 2005 J. Phys. A: Math. Gen. 38 2849) we identify, using an asymptotic expansion in the thermodynamic limit, the line of transition that separates the regime where the interface is localized near the boundary from the one where it is propagating inside the bulk. In particular, the transition line has a strong dependence on the aspect ratio of the lattice.

  7. EXACT CONTROLLABILITY FOR FIRST ORDER QUASILINEAR HYPERBOLIC SYSTEMS WITH VERTICAL CHARACTERISTICS

    Institute of Scientific and Technical Information of China (English)

    Li Tatsien; Rao Bopeng

    2009-01-01

    We consider first order quasilinear hyperbolic systems with vertical charac-teristics. It was shown in [4] that such systems can be exactly controllable with the help of internal controls applied to the equations corresponding to zero eigenvalues. However, it is possible that, for physical or engineering reasons, we can not put any control on the equations corresponding to zero eigenvalues. In this paper, we will establish the ex-act controllability only by means of physically meaningful internal controls applied to the equations corresponding to non-zero eigenvalues. We also show the exact controllability for a very simplified model by means of switching controls.

  8. The first-order deviation of superpolynomial in an arbitrary representation from the special polynomial

    CERN Document Server

    Morozov, Anton

    2012-01-01

    Like all other knot polynomials, the superpolynomials should be defined in arbitrary representation R of the gauge group in (refined) Chern-Simons theory. However, not a single example is yet known of a superpolynomial beyond symmetric or antisymmetric representations. We consider the expansion of the superpolynomial around the special polynomial in powers of (q-1) and (t-1) and suggest a simple formula for the first-order deviation, which is presumably valid for arbitrary representation. This formula can serve as a crucial lacking test of various formulas for non-trivial superpolynomials, which will appear in the literature in the near future.

  9. Self-Organized Bistability Associated with First-Order Phase Transitions

    Science.gov (United States)

    di Santo, Serena; Burioni, Raffaella; Vezzani, Alessandro; Muñoz, Miguel A.

    2016-06-01

    Self-organized criticality elucidates the conditions under which physical and biological systems tune themselves to the edge of a second-order phase transition, with scale invariance. Motivated by the empirical observation of bimodal distributions of activity in neuroscience and other fields, we propose and analyze a theory for the self-organization to the point of phase coexistence in systems exhibiting a first-order phase transition. It explains the emergence of regular avalanches with attributes of scale invariance that coexist with huge anomalous ones, with realizations in many fields.

  10. Spin-down of compact stars and energy release of a first-order phase transition

    CERN Document Server

    Miao, Kang; Na-Na, Pan

    2007-01-01

    The deconfinement phase transition from hadronic matter to quark matter can continuously occur during spins down of neutron stars. It will lead to the release of latent heat if the transition is the first-order one. We have investigated the energy release of such deconfinement phase transition for rotating hybrid stars model which include mixed phase of hadronic matter and quark matter. The release of latent heat per baryon is calculated through studying a randomly process of infinitesimal compressing. Finally, we can self-consistently get the heating luminosity of deconfinement phase transition by imputing the EOS of mixed phase, and based on the equation of rotation structure of stars.

  11. Investigation of the switching characteristics in ferroelectrics by first-order reversal curve diagrams

    Energy Technology Data Exchange (ETDEWEB)

    Stancu, Alexandru [Solid State and Theoretical Physics Department, Al. I. Cuza University, Blvd. Carol 11, Iasi 700506 (Romania)]. E-mail: alstancu@uaic.ro; Mitoseriu, Liliana [Solid State and Theoretical Physics Department, Al. I. Cuza University, Blvd. Carol 11, Iasi 700506 (Romania); Stoleriu, Laurentiu [Solid State and Theoretical Physics Department, Al. I. Cuza University, Blvd. Carol 11, Iasi 700506 (Romania); Piazza, Daniele [CNR-ISTEC, Via Granarolo 64, I-48018 Faenza (Italy); Galassi, Carmen [CNR-ISTEC, Via Granarolo 64, I-48018 Faenza (Italy); Ricinschi, Dan [Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531 (Japan); Okuyama, Masanori [Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531 (Japan)

    2006-02-01

    First-order reversal curves (FORC) diagrams are proposed for describing the switching properties in ferroelectric materials. The method is applied for Pb(Zr,Ti)O{sub 3} (PZT) ferroelectric ceramics and films with different P(E) hysteresis and microstructural characteristics. The separation of the reversible and irreversible contributions to the ferroelectric polarization is explained in terms of microstructural characteristics of the investigated samples. The influence of parameters as field frequency, crystallite orientation, ferroelectric fatigue and porosity degree on the FORC diagrams is discussed.

  12. A high-order accurate embedded boundary method for first order hyperbolic equations

    Science.gov (United States)

    Mattsson, Ken; Almquist, Martin

    2017-04-01

    A stable and high-order accurate embedded boundary method for first order hyperbolic equations is derived. Where the grid-boundaries and the physical boundaries do not coincide, high order interpolation is used. The boundary stencils are based on a summation-by-parts framework, and the boundary conditions are imposed by the SAT penalty method, which guarantees linear stability for one-dimensional problems. Second-, fourth-, and sixth-order finite difference schemes are considered. The resulting schemes are fully explicit. Accuracy and numerical stability of the proposed schemes are demonstrated for both linear and nonlinear hyperbolic systems in one and two spatial dimensions.

  13. First-order correction terms in the weak-field asymptotic theory of tunneling ionization

    DEFF Research Database (Denmark)

    Trinh, Vinh H.; Tolstikhin, Oleg I.; Madsen, Lars Bojer

    2013-01-01

    The weak-field asymptotic theory (WFAT) of tunneling ionization in a static electric field is developed to the next order in field. The first-order corrections to the ionization rate and transverse momentum distribution of the ionized electrons are derived. This extends the region of applicability...... of the WFAT at the quantitative level toward stronger fields, practically up to the boundary between tunneling and over-the-barrier regimes of ionization. The results apply to any atom or molecule treated in the single-active-electron and frozen-nuclei approximations. The theory is illustrated by calculations...... for hydrogen and noble-gas atoms....

  14. Weak first-order orientational transition in the Lebwohl-Lasher model for liquid crystals

    DEFF Research Database (Denmark)

    Zhang, Zhengping; Mouritsen, Ole G.; Zuckermann, Martin J.

    1992-01-01

    The nature of the orientational phase transition in the three-dimensional Lebwohl-Lasher model of liquid crystals has been studied by computer simulation using reweighting techniques and finite-size scaling analysis. Unambiguous numerical evidence is found in favor of a weak first-order transition...... and the presence of pseudospinodal points, T±*, which are extremely close to the equilibrium transition temperature, ‖Tc-T±*‖/Tc≲0.5×10-3, in good agreement with experimental data for the nematic-isotropic transition....

  15. First-order correction terms in the weak-field asymptotic theory of tunneling ionization

    DEFF Research Database (Denmark)

    Trinh, Vinh H.; Tolstikhin, Oleg I.; Madsen, Lars Bojer;

    2013-01-01

    The weak-field asymptotic theory (WFAT) of tunneling ionization in a static electric field is developed to the next order in field. The first-order corrections to the ionization rate and transverse momentum distribution of the ionized electrons are derived. This extends the region of applicability...... of the WFAT at the quantitative level toward stronger fields, practically up to the boundary between tunneling and over-the-barrier regimes of ionization. The results apply to any atom or molecule treated in the single-active-electron and frozen-nuclei approximations. The theory is illustrated by calculations...

  16. First-order reversal curve probing of spatially resolved polarization switching dynamics in ferroelectric nanocapacitors.

    Science.gov (United States)

    Kim, Yunseok; Kumar, Amit; Ovchinnikov, Oleg; Jesse, Stephen; Han, Hee; Pantel, Daniel; Vrejoiu, Ionela; Lee, Woo; Hesse, Dietrich; Alexe, Marin; Kalinin, Sergei V

    2012-01-24

    Spatially resolved polarization switching in ferroelectric nanocapacitors was studied on the sub-25 nm scale using the first-order reversal curve (FORC) method. The chosen capacitor geometry allows both high-veracity observation of the domain structure and mapping of polarization switching in a uniform field, synergistically combining microstructural observations and probing of uniform-field polarization responses as relevant to device operation. A classical Kolmogorov-Avrami-Ishibashi model has been adapted to the voltage domain, and the individual switching dynamics of the FORC response curves are well approximated by the adapted model. The comparison with microstructures suggests a strong spatial variability of the switching dynamics inside the nanocapacitors.

  17. On first-order theorem proving using generalized odd-superpositions Ⅱ

    Institute of Scientific and Technical Information of China (English)

    吴尽昭; 刘卓军

    1996-01-01

    It is shown that the proof system using odd-superpositions Ⅱ is not complete.The reason leading to this incompleteness is that the use of idempotency rule is neglected.By defining the superpositions of first-order polynomials and zero,the concept of odd-superpositions Ⅱ is extended,and a complete proof system using the extended odd-superpositions Ⅱ is developed.In addition,this proof system is an improvement on remainder method;its completeness demonstrates actually that the remainder method using semantic strategy is still complete.

  18. No First-Order Phase Transition in the Gross-Neveu Model?

    CERN Document Server

    Brzoska, A; Brzoska, Andrej; Thies, Michael

    2002-01-01

    Within a variational calculation we investigate the role of baryons for the structure of dense matter in the Gross-Neveu model. We construct a trial ground state at finite baryon density which breaks translational invariance. Its scalar potential interpolates between widely spaced kinks and antikinks at low density and the value zero at infinite density. Its energy is lower than the one of the standard Fermi gas at all densities considered. This suggests that the discrete gamma_5 symmetry of the Gross-Neveu model does not get restored in a first order phase transition at finite density, at variance with common wisdom.

  19. First-order formalism for flat branes in generalized N-field models

    CERN Document Server

    Bazeia, D; Losano, L; Menezes, R

    2013-01-01

    This work deals with braneworld scenarios obtained from N real scalar fields, whose dynamics is generalized to include higher order power in the derivative of the fields. For the scalar fields being driven by nonstandard dynamics, we show how a first-order formalism can be obtained for flat brane in the presence of several fields. We then illustrate our findings investigating distinct potentials with one and two fields, obtaining stable standard and compact solutions in the braneworld theory. In particular, we have found different models describing the very same warp factor.

  20. Numerical simulations with a first order BSSN formulation of Einstein's field equations

    CERN Document Server

    Brown, J David; Field, Scott E; Hesthaven, Jan S; Herrmann, Frank; Mroué, Abdul H; Schnetter, Erik; Tiglio, Manuel; Wagman, Michael

    2012-01-01

    We present a new fully first order strongly hyperbolic representation of the BSSN formulation of Einstein's equations with optional constraint damping terms. We describe the characteristic fields of the system, discuss its hyperbolicity properties, and present two numerical implementations and simulations: one using finite differences, adaptive mesh refinement and in particular binary black holes, and another one using the discontinuous Galerkin method in spherical symmetry. The results of this paper constitute a first step in an effort to combine the robustness of BSSN evolutions with very high accuracy numerical techniques, such as spectral collocation multi-domain or discontinuous Galerkin methods.

  1. Interrupted Magnetic First Order Transitions and Kinetic Arrest probed with In-field Neutron Diffraction

    Science.gov (United States)

    Siruguri, V.; Kaushik, S. D.; Rayaprol, S.; Babu, P. D.; Chaddah, P.; Sampathkumaran, E. V.; Hoser, A.; Ritter, C.

    2016-09-01

    In-field neutron diffraction studies were carried out on two compounds that exhibit magnetic first order phase transitions (FOPT). It is shown that the FOPT can be interrupted by an external magnetic field, resulting in a coexistence of kinetically arrested metastable states and equilibrium phases. Use of a novel protocol CHUF (Cooling and Heating under Unequal Fields) helps to determine the coexisting phase fractions and also to observe the devitrification of the kinetically arrested phase into the equilibrium phase, in a manner similar to that found in structural glassy systems.

  2. Probabilistic modelling of combined sewer overflow using the First Order Reliability Method

    DEFF Research Database (Denmark)

    Thorndahl, Søren; Schaarup-Jensen, Kjeld; Jensen, Jacob Birk

    2007-01-01

    This paper presents a new and alternative method (in the context of urban drainage) for probabilistic hydrodynamical analysis of drainage systems in general and especially prediction of combined sewer overflow. Using a probabilistic shell it is possible to implement both input and parameter...... uncertainties on an application of the commercial urban drainage model MOUSE combined with the probabilistic First Order Reliability Method (FORM). Applying statistical characteristics on several years of rainfall, it is possible to derive a parameterization of the rainfall input and the failure probability...

  3. Probabilistic Modelling of Combined Sewer Overflow Using the First Order Reliability Method

    DEFF Research Database (Denmark)

    Thorndahl, Søren; Schaarup-Jensen, Kjeld; Jensen, Jacob Birk

    2008-01-01

    This paper presents a new and alternative method (in the context of urban drainage) for probabilistic hydrodynamical analysis of drainage systems in general and especially prediction of combined sewer overflow. Using a probabilistic shell it is possible to implement both input and parameter...... uncertainties on an application of the commercial urban drainage model MOUSE combined with the probabilistic First Order Reliability Method (FORM). Applying statistical characteristics on several years of rainfall, it is possible to derive a parameterization of the rainfall input and the failure probability...

  4. A comprehensive comparison between thermodynamic perturbation theory and first-order mean spherical approximation: Based on discrete potentials with hard core

    Science.gov (United States)

    Zhou, Shiqi; Zhou, Run

    2017-08-01

    Using the TL (Tang and Lu, 1993) method, Ornstein-Zernike integral equation is solved perturbatively under the mean spherical approximation (MSA) for fluid with potential consisting of a hard sphere plus square-well plus square-shoulder (HS + SW + SS) to obtain first-order analytic expressions of radial distribution function (RDF), second-order direct correlation function, and semi-analytic expressions for common thermodynamic properties. A comprehensive comparison between the first-order MSA and high temperature series expansion (HTSE) to third-, fifth- and seventh-order is performed over a wide parameter range for both a HS + SW and the HS + SW + SS model fluids by using corresponding ;exact; Monte Carlo results as a reference; although the HTSE is carried out up to seventh-order, and not to the first order as the first-order MSA the comparison is considered fair from a calculation complexity perspective. It is found that the performance of the first-order MSA is dramatically model-dependent: as target potentials go from the HS + SW to the HS + SW + SS, (i) there is a dramatic dropping of performance of the first-order MSA expressions in calculating the thermodynamic properties, especially both the excess internal energy and constant volume excess heat capacity of the HS + SW + SS model cannot be predicted even qualitatively correctly. (ii) One tendency is noticed that the first-order MSA gets more reliable with increasing temperatures in dealing with the pressure, excess Helmholtz free energy, excess enthalpy and excess chemical potential. (iii) Concerning the RDF, the first-order MSA is not as disappointing as it displays in the cases of thermodynamics. (iv) In the case of the HS + SW model, the first-order MSA solution is shown to be quantitatively correct in calculating the pressure and excess chemical potential even if the reduced temperatures are as low as 0.8. On the other hand, the seventh-order HTSE is less model-dependent; in most cases of the HS + SW

  5. Gummel Symmetry Test on charge based drain current expression using modified first-order hyperbolic velocity-field expression

    Science.gov (United States)

    Singh, Kirmender; Bhattacharyya, A. B.

    2017-03-01

    Gummel Symmetry Test (GST) has been a benchmark industry standard for MOSFET models and is considered as one of important tests by the modeling community. BSIM4 MOSFET model fails to pass GST as the drain current equation is not symmetrical because drain and source potentials are not referenced to bulk. BSIM6 MOSFET model overcomes this limitation by taking all terminal biases with reference to bulk and using proper velocity saturation (v -E) model. The drain current equation in BSIM6 is charge based and continuous in all regions of operation. It, however, adopts a complicated method to compute source and drain charges. In this work we propose to use conventional charge based method formulated by Enz for obtaining simpler analytical drain current expression that passes GST. For this purpose we adopt two steps: (i) In the first step we use a modified first-order hyperbolic v -E model with adjustable coefficients which is integrable, simple and accurate, and (ii) In the second we use a multiplying factor in the modified first-order hyperbolic v -E expression to obtain correct monotonic asymptotic behavior around the origin of lateral electric field. This factor is of empirical form, which is a function of drain voltage (vd) and source voltage (vs) . After considering both the above steps we obtain drain current expression whose accuracy is similar to that obtained from second-order hyperbolic v -E model. In modified first-order hyperbolic v -E expression if vd and vs is replaced by smoothing functions for the effective drain voltage (vdeff) and effective source voltage (vseff), it will as well take care of discontinuity between linear to saturation regions of operation. The condition of symmetry is shown to be satisfied by drain current and its higher order derivatives, as both of them are odd functions and their even order derivatives smoothly pass through the origin. In strong inversion region and technology node of 22 nm the GST is shown to pass till sixth

  6. Measurement of fMCG Signals using an Axial Type First-Order SQUID Gradiometer System

    Energy Technology Data Exchange (ETDEWEB)

    Yu, K. K.; Kim, K.; Kang, C. S.; Kim, J. M.; Lee, Y. H. [Korea Research Institute of Standards and Science, Daejeon (Korea, Republic of)

    2009-04-15

    We have fabricated a low-noise 61-channel axial-type first-order gradiometer system for measuring fetal magnetocardiography(MCG) signals. Superconducting quantum interference device(SQUID) sensor was based on double relaxation oscillation SQUID(DROS) for detecting biomagnetic signal, such as MCG, magnetoencphalogram(MEG) and fetal-MCG. The SQUID sensor detected axial component of fetal MCG signal. The pickup coil of SQUID sensor was wound with 120 {mu}m NbTi wire on bobbin(20 mm diameter) and was a first-order gradiometer to reject the environment noise. The sensors have low white noise of 3 fT/Hz{sup 1/2} at 100 Hz on average. The fetal MCG was measured from 24 - 36 weeks fetus in a magnetically shielded room(MSR) with shielding factor of 35 dB at 0.1 Hz and 80 dB at 100 Hz(comparatively mild shielding). The MCG signal contained maternal and fetal MCG. Fetal MCG could be distinguished relatively easily from maternal MCG by using independent component analysis(ICA) filter. In addition, we could observe T peak as well as QRS wave, respectively. It will be useful in detecting fetal cardiac diseases.

  7. The reversibility and first-order nature of liquid-liquid transition in a molecular liquid

    Science.gov (United States)

    Kobayashi, Mika; Tanaka, Hajime

    2016-11-01

    Liquid-liquid transition is an intriguing phenomenon in which a liquid transforms into another liquid via the first-order transition. For molecular liquids, however, it always takes place in a supercooled liquid state metastable against crystallization, which has led to a number of serious debates concerning its origin: liquid-liquid transition versus unusual nano-crystal formation. Thus, there have so far been no single example free from such debates, to the best of our knowledge. Here we show experimental evidence that the transition is truly liquid-liquid transition and not nano-crystallization for a molecular liquid, triphenyl phosphite. We kinetically isolate the reverse liquid-liquid transition from glass transition and crystallization with a high heating rate of flash differential scanning calorimetry, and prove the reversibility and first-order nature of liquid-liquid transition. Our finding not only deepens our physical understanding of liquid-liquid transition but may also initiate a phase of its research from both fundamental and applications viewpoints.

  8. The nature of the first order isostructural transition in GdRhSn

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, Sachin [Indian Institute of Technology Bombay; Suresh, K G [Indian Institute of Technology Bombay; Nigam, A K [Tara Institute of Fundamental Resarch; Mudryk, Y [Ames Laboratory; Paudyal, D [Ames Laboratory; Pecharsky, V K [Ames Laboratory; Gschneidner, Karl A [Ames Laboratory

    2014-11-01

    We present structural, magnetic, thermal, magnetocaloric, and electrical transport properties of polycrystalline GdRhSn. Magnetization data show that it orders antiferromagnetically at TN = 16.2 K. The compound has the ZrNiAl type hexagonal crystal structure at room temperature and undergoes a first order iso-structural transition in the paramagnetic state at 245 K. The unit cell volume change at the transition is small (-0.07 %) but discontinuous, in agreement with the first-order nature of the transition observed by magnetic, transport, and heat capacity measurements. The anisotropic changes of the lattice parameters are Δa/a = 0.28 % and Δc/c = -0.64 % on cooling. A substantial change in the 4f and conduction electron hybridization, giving rise to an increased integrated DOS, occurs when the high temperature phase transforms to the low temperature phase. A moderate magnetocaloric effect at TN (ΔSM = -6.5 J/kg K and ΔTad = 4.5 K for ΔH= 50 kOe) has been measured using both magnetization and heat capacity data

  9. First order resonance overlap and the stability of close two planet systems

    CERN Document Server

    Deck, Katherine M; Holman, Matthew J

    2013-01-01

    Motivated by the population of multi-planet systems with orbital period ratios 1first order mean motion resonance can be reduced to a one degree of freedom problem (Sessin & Ferraz Mello (1984), Wisdom (1986), Henrard et al. (1986)). Using this analytically tractable Hamiltonian, we apply the resonance overlap criterion to predict the onset of large scale chaotic motion in close two planet systems. The reduced Hamiltonian has only a weak dependence on the planetary mass ratio, and hence the overlap criterion is independent of the planetary mass ratio at lowest order. Numerical integrations confirm that the planetary mass ratio has little effect on the structure of the chaotic phase space for close orbits in the low eccentricity (e <~0.1) regime. We show numerically that orbits in the chaotic web produced primarily by first order reso...

  10. Echoes of inflationary first-order phase transitions in the CMB

    Directory of Open Access Journals (Sweden)

    Hongliang Jiang

    2017-02-01

    Full Text Available Cosmological phase transitions (CPTs, such as the Grand Unified Theory (GUT and the electroweak (EW ones, play a significant role in both particle physics and cosmology. In this letter, we propose to probe the first-order CPTs, by detecting gravitational waves (GWs which are generated during the phase transitions through the cosmic microwave background (CMB. If happened around the inflation era, the first-order CPTs may yield low-frequency GWs due to bubble dynamics, leaving imprints on the CMB. In contrast to the nearly scale-invariant primordial GWs caused by vacuum fluctuation, these bubble-generated GWs are scale dependent and have non-trivial B-mode spectra. If decoupled from inflaton, the EWPT during inflation may serve as a probe for the one after reheating where the baryon asymmetry could be generated via EW baryogenesis (EWBG. The CMB thus provides a potential way to test the feasibility of the EWBG, complementary to the collider measurements of Higgs potential and the direct detection of GWs generated during EWPT.

  11. Constraint-preserving boundary conditions in the 3+1 first-order approach

    Science.gov (United States)

    Bona, C.; Bona-Casas, C.

    2010-09-01

    A set of energy-momentum constraint-preserving boundary conditions is proposed for the first-order Z4 case. The stability of a simple numerical implementation is tested in the linear regime (robust stability test), both with the standard corner and vertex treatment and with a modified finite-differences stencil for boundary points which avoids corners and vertices even in Cartesian-like grids. Moreover, the proposed boundary conditions are tested in a strong-field scenario, the Gowdy waves metric, showing the expected rate of convergence. The accumulated amount of energy-momentum constraint violations is similar or even smaller than the one generated by either periodic or reflection conditions, which are exact in the Gowdy waves case. As a side theoretical result, a new symmetrizer is explicitly given, which extends the parametric domain of symmetric hyperbolicity for the Z4 formalism. The application of these results to first-order Baumgarte-Shapiro-Shibata-Nakamura-like formalisms is also considered.

  12. 750 GeV Di-photon Excess and Strongly First-Order Electroweak Phase Transition

    CERN Document Server

    Perelstein, Maxim

    2016-01-01

    A new scalar particle, coupled to photons and gluons via loops of vector-like quarks, provides a simple theoretical interpretation of the 750 GeV di-photon excess reported by the experiments at the Large Hadron Collider (LHC). In this paper, we show that this model contains a large, phenomenologically viable parameter space region in which the electroweak phase transition (EWPT) is strongly first-order, opening the possibility that electroweak baryogenesis mechanism can be realized in this context. A large coupling between the Higgs doublet and the heavy scalar, required for a strongly first-order EWPT, can arise naturally in composite Higgs models. The scenario makes robust predictions that will be tested in near-future experiments. The cross section of resonant di-Higgs production at the 13 TeV LHC is predicted to be at least 20 fb, while the Higgs cubic self-coupling is enhanced by 40% or more with respect to its Standard Model (SM) value.

  13. Numerical study of Potts models with aperiodic modulations: influence on first-order transitions

    Science.gov (United States)

    Branco, Nilton; Girardi, Daniel

    2012-02-01

    We perform a numerical study of Potts models on a rectangular lattice with aperiodic interactions along one spatial direction. The number of states q is such that the transition is a first-order one for the uniform model. The Wolff algorithm is employed, for many lattice sizes, allowing for a finite-size scaling analyses to be carried out. Three different self-dual aperiodic sequences are employed, such that the exact critical temperature is known: this leads to precise results for the exponents. We analyze models with q=6 and 15 and show that the Harris-Luck criterion, originally introduced in the study of continuous transitions, is obeyed also for first-order ones. The new universality class that emerges for relevant aperiodic modulations depends on the number of states of the Potts model, as obtained elsewhere for random disorder, and on the aperiodic sequence. We determine the occurrence of log-periodic behavior, as expected for models with aperiodic modulated interactions.

  14. A First-Order Electroweak Phase Transition in the Standard Model from Varying Yukawas

    CERN Document Server

    Baldes, Iason; Servant, Geraldine

    2016-01-01

    We show that the dynamics responsible for the variation of the Yukawa couplings of the Standard Model fermions generically leads to a very strong first-order electroweak phase transition, assuming that the Yukawa couplings are large and of order 1 before the electroweak phase transition and reach their present value afterwards. There are good motivations to consider that the flavour structure could emerge during electroweak symmetry breaking, for example if the Froggatt-Nielsen field dynamics were linked to the Higgs field. In this paper, we do not need to assume any particular theory of flavour and show in a model-independent way how the nature of the electroweak phase transition is completely changed when the Standard Model Yukawas vary at the same time as the Higgs is acquiring its vacuum expectation value. The thermal contribution of the fermions creates a barrier between the symmetric and broken phase minima of the effective potential, leading to a first-order phase transition. This offers new routes for...

  15. Numerical simulations of acoustically generated gravitational waves at a first order phase transition

    Science.gov (United States)

    Hindmarsh, Mark; Huber, Stephan J.; Rummukainen, Kari; Weir, David J.

    2015-12-01

    We present details of numerical simulations of the gravitational radiation produced by a first order thermal phase transition in the early Universe. We confirm that the dominant source of gravitational waves is sound waves generated by the expanding bubbles of the low-temperature phase. We demonstrate that the sound waves have a power spectrum with a power-law form between the scales set by the average bubble separation (which sets the length scale of the fluid flow Lf) and the bubble wall width. The sound waves generate gravitational waves whose power spectrum also has a power-law form, at a rate proportional to Lf and the square of the fluid kinetic energy density. We identify a dimensionless parameter Ω˜GW characterizing the efficiency of this "acoustic" gravitational wave production whose value is 8 π Ω˜GW≃0.8 ±0.1 across all our simulations. We compare the acoustic gravitational waves with the standard prediction from the envelope approximation. Not only is the power spectrum steeper (apart from an initial transient) but the gravitational wave energy density is generically larger by the ratio of the Hubble time to the phase transition duration, which can be 2 orders of magnitude or more in a typical first order electroweak phase transition.

  16. Dynamics of a first-order transition to an absorbing state

    Science.gov (United States)

    Néel, Baptiste; Rondini, Ignacio; Turzillo, Alex; Mujica, Nicolás; Soto, Rodrigo

    2014-04-01

    A granular system confined in a quasi-two-dimensional box that is vertically vibrated can transit to an absorbing state in which all particles bounce vertically in phase with the box, with no horizontal motion. In principle, this state can be reached for any density lower than the one corresponding to one complete monolayer, which is then the critical density. Below this critical value, the transition to the absorbing state is of first order, with long metastable periods, followed by rapid transitions driven by homogeneous nucleation. Molecular dynamics simulations and experiments show that there is a dramatic increase on the metastable times far below the critical density; in practice, it is impossible to observe spontaneous transitions close to the critical density. This peculiar feature is a consequence of the nonequilibrium nature of this first-order transition to the absorbing state. A Ginzburg-Landau model, with multiplicative noise, describes qualitatively the observed phenomena and explains the macroscopic size of the critical nuclei. The nuclei become of small size only close to a second critical point where the active phase becomes unstable via a saddle node bifurcation. It is only close to this second critical point that experiments and simulations can evidence spontaneous transitions to the absorbing state while the metastable times grow dramatically moving away from it.

  17. Renormalization-group theory for cooling first-order phase transitions in Potts models.

    Science.gov (United States)

    Liang, Ning; Zhong, Fan

    2017-03-01

    We develop a dynamic field-theoretic renormalization-group (RG) theory for cooling first-order phase transitions in the Potts model. It is suggested that the well-known imaginary fixed points of the q-state Potts model for q>10/3 in the RG theory are the origin of the dynamic scaling found recently from numerical simulations, apart from logarithmic corrections. This indicates that the real and imaginary fixed points of the Potts model are both physical and control the scalings of the continuous and discontinuous phase transitions, respectively, of the model. Our one-loop results for the scaling exponents are already not far away from the numerical results. Further, the scaling exponents depend on q only slightly, consistent with the numerical results. Therefore, the theory is believed to provide a natural explanation of the dynamic scaling including the scaling exponents and their scaling laws for various observables in the cooling first-order phase transition of the Potts model.

  18. Backstepping Synthesis for Feedback Control of First-Order Hyperbolic PDEs with Spatial-Temporal Actuation

    Directory of Open Access Journals (Sweden)

    Xin Yu

    2014-01-01

    Full Text Available This paper deals with the stabilization problem of first-order hyperbolic partial differential equations (PDEs with spatial-temporal actuation over the full physical domains. We assume that the interior actuator can be decomposed into a product of spatial and temporal components, where the spatial component satisfies a specific ordinary differential equation (ODE. A Volterra integral transformation is used to convert the original system into a simple target system using the backstepping-like procedure. Unlike the classical backstepping techniques for boundary control problems of PDEs, the internal actuation can not eliminate the residual term that causes the instability of the open-loop system. Thus, an additional differential transformation is introduced to transfer the input from the interior of the domain onto the boundary. Then, a feedback control law is designed using the classic backstepping technique which can stabilize the first-order hyperbolic PDE system in a finite time, which can be proved by using the semigroup arguments. The effectiveness of the design is illustrated with some numerical simulations.

  19. Renormalization-group theory for cooling first-order phase transitions in Potts models

    Science.gov (United States)

    Liang, Ning; Zhong, Fan

    2017-03-01

    We develop a dynamic field-theoretic renormalization-group (RG) theory for cooling first-order phase transitions in the Potts model. It is suggested that the well-known imaginary fixed points of the q -state Potts model for q >10 /3 in the RG theory are the origin of the dynamic scaling found recently from numerical simulations, apart from logarithmic corrections. This indicates that the real and imaginary fixed points of the Potts model are both physical and control the scalings of the continuous and discontinuous phase transitions, respectively, of the model. Our one-loop results for the scaling exponents are already not far away from the numerical results. Further, the scaling exponents depend on q only slightly, consistent with the numerical results. Therefore, the theory is believed to provide a natural explanation of the dynamic scaling including the scaling exponents and their scaling laws for various observables in the cooling first-order phase transition of the Potts model.

  20. A First-Order Analytical Theory for Optimal Low-Thrust Limited-Power Transfers between Arbitrary Elliptical Coplanar Orbits

    Directory of Open Access Journals (Sweden)

    Sandro da Silva Fernandes

    2008-01-01

    Full Text Available A complete first-order analytical solution, which includes the short periodic terms, for the problem of optimal low-thrust limited-power transfers between arbitrary elliptic coplanar orbits in a Newtonian central gravity field is obtained through canonical transformation theory. The optimization problem is formulated as a Mayer problem of optimal control theory with Cartesian elements—position and velocity vectors—as state variables. After applying the Pontryagin maximum principle and determining the maximum Hamiltonian, classical orbital elements are introduced through a Mathieu transformation. The short periodic terms are then eliminated from the maximum Hamiltonian through an infinitesimal canonical transformation built through Hori method. Closed-form analytical solutions are obtained for the average canonical system by solving the Hamilton-Jacobi equation through separation of variables technique. For transfers between close orbits a simplified solution is straightforwardly derived by linearizing the new Hamiltonian and the generating function obtained through Hori method.

  1. Containment Control for First-Order Multi-Agent Systems with Time-Varying Delays and Uncertain Topologies

    Science.gov (United States)

    Wang, Fu-Yong; Yang, Hong-Yong; Zhang, Shu-Ning; Han, Fu-Jun

    2016-08-01

    Containment control of first-order multi-agent systems with uncertain topologies and communication time-delays is studied. Suppose system topologies are dynamically changed, a containment control algorithm with time-varying delays is presented. The stability of the control algorithm is studied under the assumption that communication topologies are jointly-connected, and constraint condition of distributed containment control for delayed multi-agent systems is derived with the aid of Lyapunov-Krasovskii function. Simulation results are provided to prove the correctness and effectiveness of the conclusion. Supported by the National Natural Science Foundation of China under Grant Nos. 61273152, 61304052, 51407088, the Science Foundation of Education Office of Shandong Province of China under Grant Nos. ZR2011FM07, BS2015DX018

  2. First-order superconducting transition in the inter-band model

    Energy Technology Data Exchange (ETDEWEB)

    Gomes da Silva, M. [Universidade Federal do Amazonas, Departamento de Física, 3000, Japiim, 69077-00 Manaus, AM (Brazil); Instituto Federal de Educação Ciência e Tecnologia do Amazonas, Av. 7 de Setembro, 1975 - Centro, Manaus, AM 69020-120 (Brazil); Dinóla Neto, F., E-mail: dinola@ufam.edu.br [Universidade Federal do Amazonas, Departamento de Física, 3000, Japiim, 69077-00 Manaus, AM (Brazil); Padilha, I.T. [Universidade Federal do Amazonas, Departamento de Física, 3000, Japiim, 69077-00 Manaus, AM (Brazil); Ricardo de Sousa, J. [Universidade Federal do Amazonas, Departamento de Física, 3000, Japiim, 69077-00 Manaus, AM (Brazil); National Institute of Science and Technology for Complex Systems, Universidade Federal do Amazonas, 3000, Japiim, 69077-000 Manaus, AM (Brazil); Continentino, M.A. [Centro Brasileiro de Pesquisas Físicas, 22290-180 Rio de Janeiro, RJ (Brazil)

    2014-04-01

    The comprehension about the theoretical features of superconductivity is an interesting and fundamental topic in condensed matter physics. Several theoretical proposals were considered to describe the new classes of superconducting compounds and alloys. In this work we propose to study a non-conventional superconducting system where the Cooper pairs are formed by fermions from different bands described via two band model with hybridization. In this inter-band scenario we find a first-order phase transition at low temperatures and we observe a tricritical point in the phase diagram. In our description, the control parameter is the hybridization that can be tuned by external pressure. This fact indicates the possibility to observe discontinuities in the SC gap amplitude through applying pressure on the system.

  3. Microscopic formulation of medium contributions to the first-order optical potential

    Science.gov (United States)

    Chinn, C. R.; Elster, Ch.; Thaler, R. M.

    1993-12-01

    A refinement of the first-order optical potential is introduced, consistent with multiple scattering theory and the spectator expansion. A systematic formalism is presented to treat medium contributions associated with the difference between the effective NN t matrix as required by multiple scattering theory and the free NN t matrix. A mean field potential is used to represent the action of the residual (A-1) nucleus upon the struck target nucleon (medium effects). We calculate elastic proton and neutron scattering from 40Ca, using the full Bonn interaction and two different mean field potentials taken from realistic and proven nuclear structure models. Results indicate that the medium contributions are insignificant at energies above 300 MeV and provide a significant improvement of the theoretical predictions for laboratory energies between 48 and 200 MeV.

  4. Microscopic formulation of medium contributions to the first-order optical potential

    Energy Technology Data Exchange (ETDEWEB)

    Chinn, C.R. (Department of Physics and Astronomy, Vanderbilt University, Nashville, Tennessee 37235 (United States) Center for Computationally Intensive Physics, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)); Elster, C. (Institute of Nuclear and Particle Physics and Department of Physics, Ohio University, Athens, Ohio 45701 (United States)); Thaler, R.M. (Department of Physics and Astronomy, Vanderbilt University, Nashville, Tennessee 37235 (United States) Case Western Reserve University, Cleveland, Ohio 44106 (United States))

    1993-12-01

    A refinement of the first-order optical potential is introduced, consistent with multiple scattering theory and the spectator expansion. A systematic formalism is presented to treat medium contributions associated with the difference between the effective [ital NN] [ital t] matrix as required by multiple scattering theory and the free [ital NN] [ital t] matrix. A mean field potential is used to represent the action of the residual ([ital A][minus]1) nucleus upon the struck target nucleon (medium effects). We calculate elastic proton and neutron scattering from [sup 40]Ca, using the full Bonn interaction and two different mean field potentials taken from realistic and proven nuclear structure models. Results indicate that the medium contributions are insignificant at energies above 300 MeV and provide a significant improvement of the theoretical predictions for laboratory energies between 48 and 200 MeV.

  5. First-order differential calculi over multi-braided quantum groups

    CERN Document Server

    Durdevic, M

    1996-01-01

    A differential calculus of the first order over multi-braided quantum groups is developed. In analogy with the standard theory, left/right-covariant and bicovariant differential structures are introduced and investigated. Furthermore, antipodally covariant calculi are studied. The concept of the *-structure on a multi-braided quantum group is formulated, and in particular the structure of left-covariant *-covariant calculi is analyzed. A special attention is given to differential calculi covariant with respect to the action of the associated braid system. In particular it is shown that the left/right braided-covariance appears as a consequence of the left/right-covariance relative to the group action. Braided counterparts of all basic results of the standard theory are found.

  6. Partial differential equations of first order and their applications to physics

    CERN Document Server

    López, Gustavo

    2012-01-01

    This book tries to point out the mathematical importance of the Partial Differential Equations of First Order (PDEFO) in Physics and Applied Sciences. The intention is to provide mathematicians with a wide view of the applications of this branch in physics, and to give physicists and applied scientists a powerful tool for solving some problems appearing in Classical Mechanics, Quantum Mechanics, Optics, and General Relativity. This book is intended for senior or first year graduate students in mathematics, physics, or engineering curricula. This book is unique in the sense that it covers the applications of PDEFO in several branches of applied mathematics, and fills the theoretical gap between the formal mathematical presentation of the theory and the pure applied tool to physical problems that are contained in other books. Improvements made in this second edition include corrected typographical errors; rewritten text to improve the flow and enrich the material; added exercises in all chapters; new applicati...

  7. Quasi first-order Hermite Gaussian beam for enhanced sensitivity in Sagnac interferometer photothermal deflection spectroscopy.

    Science.gov (United States)

    Shiokawa, Naoyuki; Tokunaga, Eiji

    2016-05-30

    The detection sensitivity of a Sagnac interferometer photothermal deflection spectroscopy was enhanced by changing the probe beam pattern from zero-order to a quasi-first-order Hermite Gaussian (QHG) beam. The nature of the higher order HG mode, where the beam pattern is preserved during propagation with an increased field gradient, is utilized to enhance the measurement sensitivity. In this spectroscopy, the lateral beam deflection due to the photothermal effect is sensitively detected as a change in the interference light intensity. The change in intensity is amplified due to the higher field gradient of the QHG(1,0) beam at the photodetector. This amplification effect was both numerically and experimentally demonstrated to obtain twofold improvement in the signal-to-noise ratio.

  8. A framework for simulating ultrasound imaging based on first order nonlinear pressure–velocity relations

    DEFF Research Database (Denmark)

    Du, Yigang; Fan, Rui; Li, Yong

    2016-01-01

    An ultrasound imaging framework modeled with the first order nonlinear pressure–velocity relations (NPVR) based simulation and implemented by a half-time staggered solution and pseudospectral method is presented in this paper. The framework is capable of simulating linear and nonlinear ultrasound...... propagation and reflections in a heterogeneous medium with different sound speeds and densities. It can be initialized with arbitrary focus, excitation and apodization for multiple individual channels in both 2D and 3D spatial fields. The simulated channel data can be generated using this framework......, and ultrasound image can be obtained by beamforming the simulated channel data. Various results simulated by different algorithms are illustrated for comparisons. The root mean square (RMS) errors for each compared pulses are calculated. The linear propagation is validated by an angular spectrum approach (ASA...

  9. Investigation of non-first-order TSC peaks with non-constant recombination lifetime

    Energy Technology Data Exchange (ETDEWEB)

    Dorendrajit Singh, S.; Gartia, R.K. (Manipur Univ. (India). Dept. of Physics)

    1994-04-14

    Thermally stimulated current peaks corresponding to saturated (completely filled) and non-saturated (partially filled) non-first-order thermoluminescence with non-constant recombination lifetime are investigated. The variation of peak temperature and peak shape are studied as trap filling continues to increase until saturation. A set of expressions based on the shape of the peak has been derived, which in principle can be used to evaluate activation energy of such thermally stimulated current peaks. The coefficients involved in the expression are presented for certain kinetic orders, namely 1.5, 2.0 and 2.5. The validity of this peak shape method as well as the method of various heating rates have been checked by considering some numerically computed thermally stimulated current peaks. (Author).

  10. A stochastic Galerkin method for first-order quasilinear hyperbolic systems with uncertainty

    Science.gov (United States)

    Wu, Kailiang; Tang, Huazhong; Xiu, Dongbin

    2017-09-01

    This paper is concerned with generalized polynomial chaos (gPC) approximation for first-order quasilinear hyperbolic systems with uncertainty. The one-dimensional (1D) hyperbolic system is first symmetrized with the aid of left eigenvector matrix of the Jacobian matrix. Then the gPC stochastic Galerkin method is applied to derive a provably symmetrically hyperbolic equations for the gPC expansion coefficients. The resulting deterministic gPC Galerkin system is discretized by a path-conservative finite volume WENO scheme in space and a third-order total variation diminishing Runge-Kutta method in time. The method is further extended to two-dimensional (2D) quasilinear hyperbolic system with uncertainty, where the symmetric hyperbolicity of the one-dimensional gPC Galerkin system is carried over via an operator splitting technique. Several numerical experiments are conducted to demonstrate the accuracy and effectiveness of the proposed gPC stochastic Galerkin method.

  11. Reasoning in the OWL 2 Full Ontology Language using First-Order Automated Theorem Proving

    CERN Document Server

    Schneider, Michael

    2011-01-01

    OWL 2 has been standardized by the World Wide Web Consortium (W3C) as a family of ontology languages for the Semantic Web. The most expressive of these languages is OWL 2 Full, but to date no reasoner has been implemented for this language. Consistency and entailment checking are known to be undecidable for OWL 2 Full. We have translated a large fragment of the OWL 2 Full semantics into first-order logic, and used automated theorem proving systems to do reasoning based on this theory. The results are promising, and indicate that this approach can be applied in practice for effective OWL reasoning, beyond the capabilities of current Semantic Web reasoners. This is an extended version of a paper with the same title that has been published at CADE 2011, LNAI 6803, pp. 446-460. The extended version provides appendices with additional resources that were used in the reported evaluation.

  12. A Modified Weighted Symmetric Estimator for a Gaussian First-order Autoregressive Model with Additive Outliers

    Directory of Open Access Journals (Sweden)

    Wararit PANICHKITKOSOLKUL

    2012-09-01

    Full Text Available Guttman and Tiao [1], and Chang [2] showed that the effect of outliers may cause serious bias in estimating autocorrelations, partial correlations, and autoregressive moving average parameters (cited in Chang et al. [3]. This paper presents a modified weighted symmetric estimator for a Gaussian first-order autoregressive AR(1 model with additive outliers. We apply the recursive median adjustment based on an exponentially weighted moving average (EWMA to the weighted symmetric estimator of Park and Fuller [4]. We consider the following estimators: the weighted symmetric estimator (, the recursive mean adjusted weighted symmetric estimator ( proposed by Niwitpong [5], the recursive median adjusted weighted symmetric estimator ( proposed by Panichkitkosolkul [6], and the weighted symmetric estimator using adjusted recursive median based on EWMA (. Using Monte Carlo simulations, we compare the mean square error (MSE of estimators. Simulation results have shown that the proposed estimator, , provides a MSE lower than those of , and  for almost all situations.

  13. First-order superconducting phase transition in CeCoIn5.

    Science.gov (United States)

    Bianchi, A; Movshovich, R; Oeschler, N; Gegenwart, P; Steglich, F; Thompson, J D; Pagliuso, P G; Sarrao, J L

    2002-09-23

    The superconducting phase transition in heavy fermion CeCoIn5 (T(c)=2.3 K in zero field) becomes first order when the magnetic field H parallel [001] is greater than 4.7 T, and the transition temperature is below T0 approximately 0.31T(c). The change from second order at lower fields is reflected in strong sharpening of both specific heat and thermal expansion anomalies associated with the phase transition, a strong magnetocaloric effect, and a steplike change in the sample volume. This effect is due to Pauli limiting in a type-II superconductor, and was predicted theoretically in the mid-1960s.

  14. The magnetocaloric effect at the first-order magneto-elastic phase transition.

    Science.gov (United States)

    Basso, Vittorio

    2011-06-08

    This paper presents a study of the magnetocaloric effect at the first-order magneto-elastic phase transition. The entropy change Δs at the transition temperature is given by the sum of the magnetic and the structural contributions. By using a thermodynamic model, it is shown that the sign and amplitude of the structural contribution to Δs are determined by the dimensionless parameter ζ (zeta) which depends on β, the steepness of the change of exchange forces with volume, and on α(p), the thermal expansion coefficient of the structural lattice. For ζ magnetocaloric effect. For 0 1 the structural entropy dominates and a transition occurs upon heating from a low temperature paramagnet to a high temperature ferromagnet.

  15. Oscillator strengths, first-order properties, and nuclear gradients for local ADC(2)

    Energy Technology Data Exchange (ETDEWEB)

    Schütz, Martin, E-mail: martin.schuetz@chemie.uni-regensburg.de [Institute of Physical and Theoretical Chemistry, University of Regensburg, Universitätsstraße 31, D-93040 Regensburg (Germany)

    2015-06-07

    We describe theory and implementation of oscillator strengths, orbital-relaxed first-order properties, and nuclear gradients for the local algebraic diagrammatic construction scheme through second order. The formalism is derived via time-dependent linear response theory based on a second-order unitary coupled cluster model. The implementation presented here is a modification of our previously developed algorithms for Laplace transform based local time-dependent coupled cluster linear response (CC2LR); the local approximations thus are state specific and adaptive. The symmetry of the Jacobian leads to considerable simplifications relative to the local CC2LR method; as a result, a gradient evaluation is about four times less expensive. Test calculations show that in geometry optimizations, usually very similar geometries are obtained as with the local CC2LR method (provided that a second-order method is applicable). As an exemplary application, we performed geometry optimizations on the low-lying singlet states of chlorophyllide a.

  16. Evaluation of Transverse Thermal Stresses in Composite Plates Based on First-Order Shear Deformation Theory

    Science.gov (United States)

    Rolfes, R.; Noor, A. K.; Sparr, H.

    1998-01-01

    A postprocessing procedure is presented for the evaluation of the transverse thermal stresses in laminated plates. The analytical formulation is based on the first-order shear deformation theory and the plate is discretized by using a single-field displacement finite element model. The procedure is based on neglecting the derivatives of the in-plane forces and the twisting moments, as well as the mixed derivatives of the bending moments, with respect to the in-plane coordinates. The calculated transverse shear stiffnesses reflect the actual stacking sequence of the composite plate. The distributions of the transverse stresses through-the-thickness are evaluated by using only the transverse shear forces and the thermal effects resulting from the finite element analysis. The procedure is implemented into a postprocessing routine which can be easily incorporated into existing commercial finite element codes. Numerical results are presented for four- and ten-layer cross-ply laminates subjected to mechanical and thermal loads.

  17. First order phase transition in the height of a meniscus in a tapered capillary

    Science.gov (United States)

    Pettersen, Michael; Rolley, Etienne

    2008-03-01

    When a fluid rises in a capillary of non-uniform cross section, additional terms arise in the balance of capillary forces, compared to the case of a capillary of uniform cross section, due to the changing area of the meniscus. Recently, it has been pointed out that this can lead to a first order phase transition, resulting in a discontinuous jump in the equilibrium position of the meniscus. We present the results of an experiment using isopropanol and silicone oil in cones with apex upwards of different opening angles. The cone is slowly lowered into the liquid using a translation stage. We have measured the capillary rise in this geometry, and observed the predicted phase transition.

  18. Observer-Based Bilinear Control of First-Order Hyperbolic PDEs: Application to the Solar Collector

    KAUST Repository

    Mechhoud, Sarra

    2015-12-18

    In this paper, we investigate the problem of bilinear control of a solar collector plant using the available boundary and solar irradiance measurements. The solar collector is described by a first-order 1D hyperbolic partial differential equation where the pump volumetric flow rate acts as the plant control input. By combining a boundary state observer and an internal energy-based control law, a nonlinear observer based feedback controller is proposed. With a feed-forward control term, the effect of the solar radiation is cancelled. Using the Lyapunov approach we prove that the proposed control guarantees the global exponential stability of both the plant and the tracking error. Simulation results are provided to illustrate the performance of the proposed method.

  19. Analytically solvable chaotic oscillator based on a first-order filter.

    Science.gov (United States)

    Corron, Ned J; Cooper, Roy M; Blakely, Jonathan N

    2016-02-01

    A chaotic hybrid dynamical system is introduced and its analytic solution is derived. The system is described as an unstable first order filter subject to occasional switching of a set point according to a feedback rule. The system qualitatively differs from other recently studied solvable chaotic hybrid systems in that the timing of the switching is regulated by an external clock. The chaotic analytic solution is an optimal waveform for communications in noise when a resistor-capacitor-integrate-and-dump filter is used as a receiver. As such, these results provide evidence in support of a recent conjecture that the optimal communication waveform for any stable infinite-impulse response filter is chaotic.

  20. MASS TRANSFER EFFECTS ON ACCELERATED VERTICAL PLATE IN A ROTATING FLUID WITH FIRST ORDER CHEMICAL REACTION

    Directory of Open Access Journals (Sweden)

    R. Muthucumaraswamy

    2012-12-01

    Full Text Available The precise analysis of the rotation effects on the unsteady flow of an incompressible fluid past a uniformly accelerated infinite vertical plate with variable temperature and mass diffusion has been undertaken, in the presence of a homogeneous first order chemical reaction. The dimensionless governing equations are solved using the Laplace-transform technique. The plate temperature as well as the concentration near the plate increase linearly with time. The velocity profiles, temperature and concentration are studied for different physical parameters, like the chemical reaction parameter, thermal Grashof number, mass Grashof number, Schmidt number, Prandtl number and time. It is observed that the velocity increases with increasing values of thermal Grashof number or mass Grashof number. It is also observed that the velocity increases with decreasing rotation parameter Ω.

  1. Disturbance attenuation over a first-order moving average Gaussian noise channel

    Science.gov (United States)

    Xu, Guang-Hui; He, Ding-Xin; Guan, Zhi-Hong; Zhang, Ding-Xue; Zhang, Xian-He

    2015-12-01

    In this paper, the problem of disturbance attenuation has been studied for a linear time-invariant feedback control system with a first-order moving average Gaussian noise channel. By applying the concept of entropy power, a lower bound of signal-to-noise ratio has been achieved which is necessary for stabilisation of a system with the limited channel input power constraint. Moreover, the problem of minimising the influence of a stochastic disturbance on the output has also been investigated, and the controller design method has been obtained by using Youla parameterisation and H2 theory. It is shown that the minimum variance of the system output depends not only on the disturbance variance, noise variance and unstable poles, but also on the non-minimum phase zeros and channel parameter. Finally, the effectiveness of the proposed results is illustrated by a numerical example.

  2. On the micro-to-macro limit for first-order traffic flow models on networks

    CERN Document Server

    Cristiani, Emiliano

    2015-01-01

    Connections between microscopic follow-the-leader and macroscopic fluid-dynamics traffic flow models are already well understood in the case of vehicles moving on a single road. Analogous connections in the case of road networks are instead lacking. This is probably due to the fact that macroscopic traffic models on networks are in general ill-posed, since the conservation of the mass is not sufficient alone to characterize a unique solution at junctions. This ambiguity makes more difficult to find the right limit of the microscopic model, which, in turn, can be defined in different ways near the junctions. In this paper we show that a natural extension of the first-order follow-the-leader model on networks corresponds, as the number of vehicles tends to infinity, to the LWR-based multi-path model introduced in [Bretti et al., Discrete Contin. Dyn. Syst. Ser. S, 7 (2014)] and [Briani and Cristiani, Netw. Heterog. Media, 9 (2014)].

  3. Beyond the PI Controllers in First-Order Time-Delay Systems

    CERN Document Server

    Martelli, Gianpasquale

    2007-01-01

    In this paper the following three control systems for first-order time-delay plants are studied and compared: the feedback proportional-integral controller (PI), the Smith Predictor (SP) and a proposed variable structure consisting of two blocks. This structure acts as an open-loop proportional controller, after a setpoint change, and as a closed-loop integrating controller, when the error enters in a preset band. A chart, provided with the borderlines of the stability zone and with the curves of two design parameters, is implemented for each controller. The first parameter is the overshoot of the controlled variable, evaluated during a step change of the setpoint and made equal to a preset value. The second parameter, only for the PI and SP controllers, is the integral of the squared error (ISE), which must have the minimum allowable value. The ISE is also assumed as comparison index and the proposed controller appears as the best.

  4. Actions, topological terms and boundaries in first order gravity: A review

    CERN Document Server

    Corichi, Alejandro; Vukasinac, Tatjana

    2016-01-01

    In this review we consider first order gravity in four dimensions. In particular, we focus our attention in formulations where the fundamental variables are a tetrad $e_a^I$ and a SO(3,1) connection ${\\omega_{aI}}^J$. We study the most general action principle compatible with diffeomorphism invariance. This implies, in particular, considering besides the standard Einstein-Hilbert-Palatini term, other terms that either do not change the equations of motion, or are topological in nature. Having a well defined action principle sometimes involves the need for additional boundary terms, whose detailed form may depend on the particular boundary conditions at hand. In this work, we consider spacetimes that include a boundary at infinity, satisfying asymptotically flat boundary conditions and/or an internal boundary satisfying isolated horizons boundary conditions. We focus on the covariant Hamiltonian formalism where the phase space $\\Gamma$ is given by solutions to the equations of motion. For each of the possible ...

  5. Understanding the use of two integration methods on separable first order differential equations

    CERN Document Server

    Black, Katrina E

    2009-01-01

    We present evidence from three student interactions in which two types of common solution methods for solving simple first-order differential equations are used. We describe these using the language of resources, considering epistemic games as particular pathways of solutions along resource graphs containing linked procedural and conceptual resources. Using transcript data, we define several procedural resources, show how they can be organized into two facets of a previously described epistemic game, and produce a resource graph that allows visualization of this portion of the epistemic games. By representing two correct mathematical procedures in terms of shared resources, we help clarify the types of thinking in which students engage when learning to apply mathematical reasoning to physics and illustrate how a "failure to connect" two ideas often hinders students' successful problem solving.

  6. Analytically solvable chaotic oscillator based on a first-order filter

    Energy Technology Data Exchange (ETDEWEB)

    Corron, Ned J.; Cooper, Roy M.; Blakely, Jonathan N. [Charles M. Bowden Laboratory, Aviation and Missile Research, Development and Engineering Center, U.S. Army RDECOM, Redstone Arsenal, Alabama 35898 (United States)

    2016-02-15

    A chaotic hybrid dynamical system is introduced and its analytic solution is derived. The system is described as an unstable first order filter subject to occasional switching of a set point according to a feedback rule. The system qualitatively differs from other recently studied solvable chaotic hybrid systems in that the timing of the switching is regulated by an external clock. The chaotic analytic solution is an optimal waveform for communications in noise when a resistor-capacitor-integrate-and-dump filter is used as a receiver. As such, these results provide evidence in support of a recent conjecture that the optimal communication waveform for any stable infinite-impulse response filter is chaotic.

  7. Pose and Motion Estimation from Vision Based on the First-Order Interpolation Filter

    Institute of Scientific and Technical Information of China (English)

    WUXuedong; WANGYaonan

    2004-01-01

    Determination of relative threedimensional (3D) position, orientation, and relative motion between two reference frames is an important problem in robotic guidance, manipulation, and assembly as well as in other fields such as photogrammetry. A solution to this problem that uses Two-dimensional (2D) intensity images from a single camera is desirable for real-time applications. The difficulty in performing this measurement is the process of projecting 3D object features to 2D images, a nonlinear transformation. Modeling the 3D transformation as a nonlinear stochastic system, and using a new set of filtering which are based on the first-order interpolation approximations of the nonlinear transformations as estimator, this paper presents solutions to the remote measurement problem given a sequence of 2D intensity images of an object. The method has been implemented with simulated data, and the simulation result has shown that the proposed method has good convergence.

  8. Gravitational waves from deflagration bubbles in first-order phase transitions

    CERN Document Server

    Megevand, Ariel

    2008-01-01

    The walls of bubbles in a first-order phase transition can propagate either as detonations, with a velocity larger than the speed of sound, or deflagrations, which are subsonic. We calculate the gravitational radiation produced during a phase transition via deflagration bubbles. We take into account the fact that the deflagration wall is preceded by a shock front which distributes the latent heat throughout space and influences other bubbles. We show that turbulence can induce maximum values of $\\Omega_{GW}h^2$ as high as $\\sim 10^{-10}$. We discuss the possibility of detecting at LISA gravitational waves produced at the electroweak phase transition with wall velocities $v_w\\lesssim 10^{-1}$, which favor electroweak baryogenesis.

  9. Dynamo onset as a first-order transition: lessons from a shell model for magnetohydrodynamics.

    Science.gov (United States)

    Sahoo, Ganapati; Mitra, Dhrubaditya; Pandit, Rahul

    2010-03-01

    We carry out systematic and high-resolution studies of dynamo action in a shell model for magnetohydrodynamic (MHD) turbulence over wide ranges of the magnetic Prandtl number PrM and the magnetic Reynolds number ReM. Our study suggests that it is natural to think of dynamo onset as a nonequilibrium first-order phase transition between two different turbulent, but statistically steady, states. The ratio of the magnetic and kinetic energies is a convenient order parameter for this transition. By using this order parameter, we obtain the stability diagram (or nonequilibrium phase diagram) for dynamo formation in our MHD shell model in the (PrM-1,ReM) plane. The dynamo boundary, which separates dynamo and no-dynamo regions, appears to have a fractal character. We obtain a hysteretic behavior of the order parameter across this boundary and suggestions of nucleation-type phenomena.

  10. The Canonical Structure of the First-Order Einstein-Hilbert Action

    Science.gov (United States)

    McKeon, D. G. C.

    The Dirac constraint formalism is used to analyze the first-order form of the Einstein-Hilbert action in d > 2 dimensions. Unlike previous treatments, this is done without eliminating fields at the outset by solving equations of motion that are independent of time derivatives when they correspond to first class constraints. As anticipated by the way in which the affine connection transforms under a diffeomorphism, not only primary and secondary but also tertiary first class constraints arise. These leave d(d-3) degrees of freedom in phase space. The gauge invariance of the action is discussed, with special attention being paid to the gauge generators of Henneaux, Teitelboim and Zanelli and of Castellani.

  11. The Canonical Structure of the First Order Einstein-Hilbert Action

    CERN Document Server

    McKeon, D G C

    2010-01-01

    The Dirac constraint formalism is used to analyze the first order form of the Einstein-Hilbert action in d > 2 dimensions. Unlike previous treatments, this is done without eliminating fields at the outset by solving equations of motion that are independent of time derivatives when they correspond to first class constraints. As anticipated by the way in which the affine connection transforms under a diffeomorphism, not only primary and secondary but also tertiary first class constraints arise. These leave d(d - 3) degrees of freedom in phase space. The gauge invariance of the action is discussed, with special attention being paid to the gauge generators of Henneaux, Teitelboim and Zanelli and of Castellani.

  12. First-order phase transitions in spin-glass models with multiple paramagnetic solutions

    Energy Technology Data Exchange (ETDEWEB)

    Lozza, H.F. [Departamento de Fisica, FCEyN, Universidad de Buenos Aires, Pab. I, Ciudad Universitaria - (1428) Buenos Aires (Argentina)]. E-mail: homero@df.uba.ar

    2004-12-31

    The paramagnetic and the one-step replica-symmetry-breaking spin-glass solutions of a p-spin-glass model in the presence of a transverse field are studied in the neighborhood of the phase transition curve. Two qualitatively different regions are found in the phase diagram. For a transition temperature higher than a certain value Tc, the thermodynamic transition is of second order, otherwise it is of first order with latent heat. The temperature Tc is joined to a point in the phase diagram where a transition between two paramagnetic solutions happens. A discussion about the order of the thermodynamic-phase transition in the quantum random orthogonal model is presented.

  13. First-order phase transitions in spin-glass models with multiple paramagnetic solutions

    Science.gov (United States)

    Lozza, H. F.

    2004-12-01

    The paramagnetic and the one-step replica-symmetry-breaking spin-glass solutions of a p-spin-glass model in the presence of a transverse field are studied in the neighborhood of the phase transition curve. Two qualitatively different regions are found in the phase diagram. For a transition temperature higher than a certain value Tc, the thermodynamic transition is of second order, otherwise it is of first order with latent heat. The temperature Tc is joined to a point in the phase diagram where a transition between two paramagnetic solutions happens. A discussion about the order of the thermodynamic-phase transition in the quantum random orthogonal model is presented.

  14. First-order reversal curves acquired by a high precision ac induction magnetometer.

    Science.gov (United States)

    Béron, F; Soares, G; Pirota, K R

    2011-06-01

    We present a setup allowing to characterize the local irreversible behavior of soft magnetic samples. It is achieved by modifying a conventional ac induction magnetometer in order to measure first-order reversal curves (FORCs), a magnetostatic characterization technique. The required modifications were performed on a home-made setup allowing high precision measurement, with sensibility less than 0.005 Oe for the applied field and 10(-6) emu for the magnetization. The main crucial point for the FORCs accuracy is the constancy of the applied field sweep rate, because of the magnetic viscosity. Therefore, instead of the common way to work at constant frequency, each FORC is acquired at a slightly different frequency, in order to keep the field variation constant in time. The obtained results exhibit the consequences of magnetic viscosity, thus opening up the path of studying this phenomenon for soft magnetic materials.

  15. First-order Derivative Spectrophotometry for the Determination of Vitamin C in Medicament

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    A novel method for the determination of vitamin C(Vc) is proposed in this article. After the reaction with Folin-Ciocalteau reagent at ambient temperature, Vc solution was scanned at 750-1100 nm, and its first-order derivative spectrum were obtained from the original spectrum. The values of derivative selected at 995 nm were used for determination. It was proved that Vc could quickly react with Folin-Ciocalteau reagent within 5 min and the product was quite stable for a long time. The conditions required for this method is not very complicated, its precision and accuracy are similar to those of the iodometric titration described in Chinese Pharmacopoeia, and the limit of detection is 0.312μg/mL. The determination of the results of vitamin C tablet, pill, and injection demonstrates that this method has wide pharmaceutical applications.

  16. Collective influence maximization in threshold models of information cascading with first-order transitions

    CERN Document Server

    Pei, Sen; Shaman, Jeffrey; Morone, Flaviano; Makse, Hernán A

    2016-01-01

    In spreading dynamics in social networks, there exists an optimal set of influencers whose activation can induce a global-scale cascade of information. To find the optimal, or minimal, set of spreaders, a method based on collective influence theory has been proposed for spreading dynamics with a continuous phase transition that can be mapped to optimal percolation. However, when it comes to diffusion processes exhibiting a first-order, or discontinuous transition, identifying the set of optimal spreaders with a linear algorithm for large-scale networks still remains a challenging task. Here we address this issue by exploring the collective influence in general threshold models of opinion cascading. Our analysis reveals that the importance of spreaders is fixed by the subcritical paths along which cascades propagate: the number of subcritical paths attached to each spreader determines its contribution to global cascades. The concept of subcritical path allows us to introduce a linearly scalable algorithm for m...

  17. A Framework for Incorporating General Domain Knowledge into Latent Dirichlet Allocation using First-Order Logic

    Energy Technology Data Exchange (ETDEWEB)

    Andrzejewski, D; Zhu, X; Craven, M; Recht, B

    2011-01-18

    Topic models have been used successfully for a variety of problems, often in the form of application-specific extensions of the basic Latent Dirichlet Allocation (LDA) model. Because deriving these new models in order to encode domain knowledge can be difficult and time-consuming, we propose the Fold-all model, which allows the user to specify general domain knowledge in First-Order Logic (FOL). However, combining topic modeling with FOL can result in inference problems beyond the capabilities of existing techniques. We have therefore developed a scalable inference technique using stochastic gradient descent which may also be useful to the Markov Logic Network (MLN) research community. Experiments demonstrate the expressive power of Fold-all, as well as the scalability of our proposed inference method.

  18. Gravitational waves from the sound of a first order phase transition

    CERN Document Server

    Hindmarsh, Mark; Rummukainen, Kari; Weir, David J

    2014-01-01

    We report on the first 3-dimensional numerical simulations of first-order phase transitions in the early universe to include the cosmic fluid as well as the scalar field order parameter. We calculate the gravitational wave (GW) spectrum resulting from the nucleation, expansion and collision of bubbles of the low-temperature phase, paying particular attention to those sourced by the fluid. We find that the fluid continues to be a source of GWs long after the bubbles have merged, a new effect not taken into account in previous modelling of the GW source based on the envelope approximation. The kinetic energy of the fluid is in the form of compression waves: the main source of the GWs after a phase transition is therefore the sound the bubbles make.

  19. Gravitational Waves from the Sound of a First Order Phase Transition

    Science.gov (United States)

    Hindmarsh, Mark; Huber, Stephan J.; Rummukainen, Kari; Weir, David J.

    2014-01-01

    We report on the first three-dimensional numerical simulations of first-order phase transitions in the early Universe to include the cosmic fluid as well as the scalar field order parameter. We calculate the gravitational wave (GW) spectrum resulting from the nucleation, expansion, and collision of bubbles of the low-temperature phase, for phase transition strengths and bubble wall velocities covering many cases of interest. We find that the compression waves in the fluid continue to be a source of GWs long after the bubbles have merged, a new effect not taken properly into account in previous modeling of the GW source. For a wide range of models, the main source of the GWs produced by a phase transition is, therefore, the sound the bubbles make.

  20. Non-local first-order modelling of crowd dynamics: a multidimensional framework with applications

    CERN Document Server

    Bruno, Luca; Tricerri, Paolo; Venuti, Fiammetta

    2010-01-01

    In this work a physical modelling framework is presented, describing the intelligent, non-local, and anisotropic behaviour of pedestrians. Its phenomenological basics and constitutive elements are detailed, and a qualitative analysis is provided. Within this common framework, two first-order mathematical models, along with related numerical solution techniques, are derived. The models are oriented to specific real world applications: a one-dimensional model of crowd-structure interaction in footbridges and a two-dimensional model of pedestrian flow in an underground station with several obstacles and exits. The noticeable heterogeneity of the applications demonstrates the significance of the physical framework and its versatility in addressing different engineering problems. The results of the simulations point out the key role played by the physiological and psychological features of human perception on the overall crowd dynamics.

  1. First order devices, hybrid memristors, and the frontiers of nonlinear circuit theory

    CERN Document Server

    Riaza, Ricardo

    2010-01-01

    Several devices exhibiting memory effects have shown up in nonlinear circuit theory in recent years. Among others, these circuit elements include Chua's memristors, as well as memcapacitors and meminductors. These and other related devices seem to be beyond the, say, classical scope of circuit theory, which is formulated in terms of resistors, capacitors, inductors, and voltage and current sources. We explore in this paper the potential extent of nonlinear circuit theory by classifying such mem-devices in terms of the variables involved in their constitutive relations and the notions of the differential- and the state-order of a device. Within this framework, the frontier of first order circuit theory is defined by so-called hybrid memristors, which are proposed here to accommodate a characteristic relating all four fundamental circuit variables. Devices with differential order two and mem-systems are discussed in less detail. We allow for fully nonlinear characteristics in all circuit elements, arriving at a...

  2. Arguing on entropic and enthalpic first-order phase transitions in strongly interacting matter

    CERN Document Server

    Wunderlich, Falk; Kampfer, Burkhard

    2016-01-01

    The pattern of isentropes in the vicinity of a first-order phase transition is proposed as a key for a sub-classification. While the confinement--deconfinement transition, conjectured to set in beyond a critical end point in the QCD phase diagram, is often related to an entropic transition and the apparently settled gas-liquid transition in nuclear matter is an enthalphic transition, the conceivable local isentropes w.r.t.\\ "incoming" or "outgoing" serve as another useful guide for discussing possible implications, both in the presumed hydrodynamical expansion stage of heavy-ion collisions and the core-collapse of supernova explosions. Examples, such as the quark-meson model and two-phase models, are shown to distinguish concisely the different transitions.

  3. The first order phase-transition of polycrystal solid surfaces with nanothickness

    Institute of Scientific and Technical Information of China (English)

    Y.A. Minaev

    2006-01-01

    The fundamental equations of thermodynamics of a film have been used for describing a fundamental property of solid crystalline materials i.e. the first-order phase transition on the grain boundaries by the formation of two-dimensional liquid. The generalized equation that is obtained is used for calculating the premelting temperature of any metal, which has a value in the range of 0.55-0.86 of the melting point. The experimental diffusion coefficient of nitrogen in steel at premelting temperature is the same as in the liquid phase. The described phenomenon of phase transition on the grain boundaries decreases in case of radical modification of the existing process engineering of handling metals. It also provides a precise physical explanation to the super plasticity of fine-structure metal alloys.

  4. Building a first order wave equation for the electromagnetic field: new perspectives on Dirac's equation

    CERN Document Server

    Duarte, Celso de Araujo

    2015-01-01

    Traditionally, the electromagnetic theory dictates the well-known second order differential equation for the components of the scalar and the vector potentials, or in other words, for the four-vector electromagnetic potential $\\phi^{\\mu}$. But the second order is not obligatory at least with respect to the electromagnetic radiation fields: actually, a heuristic first order differential equation can be constructed to describe the electromagnetic radiation, supported on the phenomenology of its electric and magnetic fields. Due to a formal similarity, such an equation suggests a direct comparative analysis with Dirac's equation for half spin fermions, conducting to the finding that the Dirac's spinor field $\\Psi$ for massive or massless fermions is equivalent to a set of two potential-like four vector fields $\\psi^{\\mu}$ and $\\chi^{\\mu}$. Under this point of view, striking similarities with the electromagnetic theory emerge with a category of "pseudo electric'' and "pseudo magnetic'' vector fermionic fields.

  5. Mapping and Visiting in Functional and Object-oriented Programming

    DEFF Research Database (Denmark)

    Nørmark, Kurt; Thomsen, Bent; Thomsen, Lone Leth

    2008-01-01

    Mapping and visiting represent different programming styles for traversals of collections of data.  Mapping is rooted in the functional programming paradigm, and visiting is rooted in the object-oriented programming paradigm.  This paper explores the similarities and differences between mapping...... and visiting, seen across the traditions in the two different programming paradigms. The paper is concluded with recommendations for mapping and visiting in programming languages that support both the functional and the object-oriented paradigms....

  6. Tne stiffness of first-order and second-order modules assembled with extracortical clamp devices

    Directory of Open Access Journals (Sweden)

    F. K. Sabirov

    2015-01-01

    Full Text Available The extracortical clamp device (ECD is a tool used in external fixation which unlike the K-wires and half-pins don’t perforate cortical bone. The use of ECD is prospective for the treatment of periprosthetic femoral fractures and in the lengthening over nail and bone transport over nail. The data on the bench tests of the osteosynthesis rigidity by the external fixation first-order and second-order modules on the base of extracortical clamp devices are observed in the article. Materials and methods. The authors made 240 bench tests using torsional-vibration machine, Indicators measuring linear displacements with a scale of 0.01 mm, bone simulators («Sawbones», calibrated load, Ilizarov’s apparatus и extracortical fixators. The statistical analysis was performed with use software «STATISTICA» (ver. 6.0. The data obtained are presented in graphs «Box and Whisker Plot». Results. Among the investigated variants of first-order modules the better results of osteosynthesis rigidity were found in the module based on two ECD inserted at angle 60 degrees to each other and at distance of 10 cm from each other. Among the investigated second-order modules, better results of osteosynthesis rigidity were found in the module based on two ECD inserted at an angle 60 degrees to each other at distance of 10 cm from each other. Conclusion. Thus the tested modules can be used in practice in assemblies of external fixation devices in periprosthetic fractures, lengthening and bone transport over the nail.

  7. First-order phase transitions in spinor Bose gases and frustrated magnets

    Science.gov (United States)

    Debelhoir, T.; Dupuis, N.

    2016-11-01

    We show that phase transitions in spin-1 Bose gases and stacked triangular Heisenberg antiferromagnets—an example of frustrated magnets with competing interactions—are described by the same Landau-Ginzburg-Wilson Hamiltonian with O (3 )×O (2 ) symmetry. In agreement with previous nonperturbative-renormalization-group studies of the three-dimensional O (3 )×O (2 ) model, we find that the transition from the normal phase to the superfluid ferromagnetic phase in a spin-1 Bose gas is weakly first order and shows pseudoscaling behavior. The (nonuniversal) pseudoscaling exponent ν is fully determined by the scattering lengths a0 and a2. We provide estimates of ν in 87Rb,41K, and 7Li atom gases which can be tested experimentally. We argue that pseudoscaling comes from either a crossover phenomenon due to proximity of the O(6) Wilson-Fisher fixed point (87Rb and 41K) or the existence of two unphysical fixed points (with complex coordinates) which slow down the RG flow (7Li). These unphysical fixed points are a remnant of the chiral and antichiral fixed points that exist in the O (N )×O (2 ) model when N is larger than Nc≃5.3 (the transition being then second order and controlled by the chiral fixed point). Finally, we discuss a O (2 )×O (2 ) lattice model and show that our results, even though we find the transition to be first order, are compatible with Monte Carlo simulations yielding an apparent second-order transition.

  8. Kinematic first-order calving law implies potential for abrupt ice-shelf retreat

    Science.gov (United States)

    Levermann, A.; Albrecht, T.; Winkelmann, R.; Martin, M. A.; Haseloff, M.; Joughin, I. R.

    2012-12-01

    Recently observed large-scale disintegration of Antarctic ice shelves has moved their fronts closer towards grounded ice. In response, ice-sheet discharge into the ocean has accelerated, contributing to global sea-level rise and emphasizing the importance of calving-front dynamics. The position of the ice front strongly influences the stress field within the entire sheet-shelf-system and thereby the mass flow across the grounding line. While theories for an advance of the ice-front are readily available, no general rule exists for its retreat, making it difficult to incorporate the retreat in predictive models. Here we extract the first-order large-scale kinematic contribution to calving which is consistent with large-scale observation. We emphasize that the proposed equation does not constitute a comprehensive calving law but represents the first-order kinematic contribution which can and should be complemented by higher order contributions as well as the influence of potentially heterogeneous material properties of the ice. When applied as a calving law, the equation naturally incorporates the stabilizing effect of pinning points and inhibits ice shelf growth outside of embayments. It depends only on local ice properties which are, however, determined by the full topography of the ice shelf. In numerical simulations the parameterization reproduces multiple stable fronts as observed for the Larsen A and B Ice Shelves including abrupt transitions between them which may be caused by localized ice weaknesses. We also find multiple stable states of the Ross Ice Shelf at the gateway of the West Antarctic Ice Sheet with back stresses onto the sheet reduced by up to 90% compared to the present state. Eigencalving: Universal kinematic contribution to iceberg calving of ice shelves. Calving rate C is proportional to the eigenvalues of the horizontal spreading rate tensor.

  9. In situ and laboratory determined first-order degradation rate constants of specific organic compounds in an aerobic aquifer

    DEFF Research Database (Denmark)

    Nielsen, P.H.; Bjerg, P.L.; Nielsen, P.;

    1996-01-01

    experiments. First-order degradation rate constants for aromatic and phenolic hydrocarbons ranged between 0.01 and 0.9 day(-1). Local variations in first-order degradation rates and variations between rate constants determined by ISM and LBM were generally with in a factor of 5, but no systematic differences...

  10. Translating landfill methane generation parameters among first-order decay models.

    Science.gov (United States)

    Krause, Max J; Chickering, Giles W; Townsend, Timothy G

    2016-11-01

    Landfill gas (LFG) generation is predicted by a first-order decay (FOD) equation that incorporates two parameters: a methane generation potential (L0) and a methane generation rate (k). Because non-hazardous waste landfills may accept many types of waste streams, multiphase models have been developed in an attempt to more accurately predict methane generation from heterogeneous waste streams. The ability of a single-phase FOD model to predict methane generation using weighted-average methane generation parameters and tonnages translated from multiphase models was assessed in two exercises. In the first exercise, waste composition from four Danish landfills represented by low-biodegradable waste streams was modeled in the Afvalzorg Multiphase Model and methane generation was compared to the single-phase Intergovernmental Panel on Climate Change (IPCC) Waste Model and LandGEM. In the second exercise, waste composition represented by IPCC waste components was modeled in the multiphase IPCC and compared to single-phase LandGEM and Australia's Solid Waste Calculator (SWC). In both cases, weight-averaging of methane generation parameters from waste composition data in single-phase models was effective in predicting cumulative methane generation from -7% to +6% of the multiphase models. The results underscore the understanding that multiphase models will not necessarily improve LFG generation prediction because the uncertainty of the method rests largely within the input parameters. A unique method of calculating the methane generation rate constant by mass of anaerobically degradable carbon was presented (kc) and compared to existing methods, providing a better fit in 3 of 8 scenarios. Generally, single phase models with weighted-average inputs can accurately predict methane generation from multiple waste streams with varied characteristics; weighted averages should therefore be used instead of regional default values when comparing models. Translating multiphase first-order

  11. Gregarious versus individualistic behavior in Vicsek swarms and the onset of first-order phase transitions

    Science.gov (United States)

    Baglietto, Gabriel; Albano, Ezequiel V.; Candia, Julián

    2013-08-01

    The standard Vicsek model (SVM) is a minimal non-equilibrium model of self-propelled particles that appears to capture the essential ingredients of critical flocking phenomena. In the SVM, particles tend to align with each other and form ordered flocks of collective motion; however, perturbations controlled by a noise term lead to a noise-driven continuous order-disorder phase transition. In this work, we extend the SVM by introducing a parameter α that allows particles to be individualistic instead of gregarious, i.e. to choose a direction of motion independently of their neighbors. By focusing on the small-noise regime, we show that a relatively small probability of individualistic motion (around 10%) is sufficient to drive the system from a Vicsek-like ordered phase to a disordered phase. Despite the fact that the α-extended model preserves the O(n) symmetry and the interaction range, as well as the dimensionality of the underlying SVM, this novel phase transition is found to be discontinuous (first order), an intriguing manifestation of the richness of the non-equilibrium flocking/swarming phenomenon.

  12. Euclidean Dynamical Triangulation revisited: is the phase transition really first order?

    CERN Document Server

    Rindlisbacher, Tobias

    2014-01-01

    The transition between the two phases of 4D Euclidean Dynamical Triangulation [1] was long believed to be of second order until in 1996 first order behavior was found for sufficiently large systems [3,4]. However, one may wonder if this finding was affected by the numerical methods used: to control volume fluctuations, in both studies [3,4] an artificial harmonic potential was added to the action; in [4] measurements were taken after a fixed number of accepted instead of attempted moves which introduces an additional error. Finally the simulations suffer from strong critical slowing down which may have been underestimated. In the present work, we address the above weaknesses: we allow the volume to fluctuate freely within a fixed interval; we take measurements after a fixed number of attempted moves; and we overcome critical slowing down by using an optimized parallel tempering algorithm [6]. With these improved methods, on systems of size up to 64k 4-simplices, we confirm that the phase transition is first o...

  13. Modified Inverse First Order Reliability Method (I-FORM) for Predicting Extreme Sea States.

    Energy Technology Data Exchange (ETDEWEB)

    Eckert-Gallup, Aubrey Celia; Sallaberry, Cedric Jean-Marie; Dallman, Ann Renee; Neary, Vincent Sinclair

    2014-09-01

    Environmental contours describing extreme sea states are generated as the input for numerical or physical model simulation s as a part of the stand ard current practice for designing marine structure s to survive extreme sea states. Such environmental contours are characterized by combinations of significant wave height ( ) and energy period ( ) values calculated for a given recurrence interval using a set of data based on hindcast simulations or buoy observations over a sufficient period of record. The use of the inverse first - order reliability method (IFORM) i s standard design practice for generating environmental contours. In this paper, the traditional appli cation of the IFORM to generating environmental contours representing extreme sea states is described in detail and its merits and drawbacks are assessed. The application of additional methods for analyzing sea state data including the use of principal component analysis (PCA) to create an uncorrelated representation of the data under consideration is proposed. A reexamination of the components of the IFORM application to the problem at hand including the use of new distribution fitting techniques are shown to contribute to the development of more accurate a nd reasonable representations of extreme sea states for use in survivability analysis for marine struc tures. Keywords: In verse FORM, Principal Component Analysis , Environmental Contours, Extreme Sea State Characteri zation, Wave Energy Converters

  14. Strong first order electroweak phase transition in the CP-conserving 2HDM revisited

    Science.gov (United States)

    Basler, P.; Krause, M.; Mühlleitner, M.; Wittbrodt, J.; Wlotzka, A.

    2017-02-01

    The discovery of the Higgs boson by the LHC experiments ATLAS and CMS has marked a milestone for particle physics. Yet, there are still many open questions that cannot be answered within the Standard Model (SM). For example, the generation of the observed matter-antimatter asymmetry in the universe through baryogenesis can only be explained qualitatively in the SM. A simple extension of the SM compatible with the current theoretical and experimental constraints is given by the 2-Higgs-Doublet Model (2HDM) where a second Higgs doublet is added to the Higgs sector. We investigate the possibility of a strong first order electroweak phase transition in the CP-conserving 2HDM type I and type II where either of the CP-even Higgs bosons is identified with the SM-like Higgs boson. The renormalisation that we apply on the loop-corrected Higgs potential allows us to efficiently scan the 2HDM parameter space and simultaneously take into account all relevant theoretical and up-to-date experimental constraints. The 2HDM parameter regions found to be compatible with the applied constraints and a strong electroweak phase transition are analysed systematically. Our results show that there is a strong interplay between the requirement of a strong phase transition and collider phenomenology with testable implications for searches at the LHC.

  15. Polarization induced water molecule dissociation below the first-order electronic-phase transition temperature.

    Science.gov (United States)

    Das Arulsamy, Andrew; Kregar, Zlatko; Eleršič, Kristina; Modic, Martina; Subramani, Uma Shankar

    2011-09-01

    Hydrogen produced from the photocatalytic splitting of water is one of the reliable alternatives to replace the polluting fossil and the radioactive nuclear fuels. Here, we provide unequivocal evidence for the existence of blue- and red-shifting O-H covalent bonds within a single water molecule adsorbed on the MgO surface as a result of asymmetric displacement polarizabilities. The adsorbed H-O-H on MgO gives rise to one weaker H-O bond, while the other O-H covalent bond from the same adsorbed water molecule compensates this effect with a stronger bond. The weaker bond (nearest to the surface), the interlayer tunneling electrons and the silver substrate are shown to be the causes for the smallest dissociative activation energy on the MgO monolayer. The origin that is responsible to initiate the splitting mechanism is proven to be due to the changes in the polarizability of an adsorbed water molecule, which are further supported by the temperature-dependent static dielectric constant measurements for water below the first-order electronic-phase transition temperature.

  16. The Emergence of Life as a First-Order Phase Transition

    Science.gov (United States)

    Mathis, Cole; Bhattacharya, Tanmoy; Imari Walker, Sara

    2017-03-01

    It is well known that life on Earth alters its environment over evolutionary and geological timescales. An important open question is whether this is a result of evolutionary optimization or a universal feature of life. In the latter case, the origin of life would be coincident with a shift in environmental conditions. Here we present a model for the emergence of life in which replicators are explicitly coupled to their environment through the recycling of a finite supply of resources. The model exhibits a dynamic, first-order phase transition from nonlife to life, where the life phase is distinguished by selection on replicators. We show that environmental coupling plays an important role in the dynamics of the transition. The transition corresponds to a redistribution of matter in replicators and their environment, driven by selection on replicators, exhibiting an explosive growth in diversity as replicators are selected. The transition is accurately tracked by the mutual information shared between replicators and their environment. In the absence of successfully repartitioning system resources, the transition fails to complete, leading to the possibility of many frustrated trials before life first emerges. Often, the replicators that initiate the transition are not those that are ultimately selected. The results are consistent with the view that life's propensity to shape its environment is indeed a universal feature of replicators, characteristic of the transition from nonlife to life. We discuss the implications of these results for understanding life's emergence and evolutionary transitions more broadly.

  17. The unified equation for the evaluation of degenerated first-order reactions in dynamic electrophoresis.

    Science.gov (United States)

    Trapp, Oliver

    2006-08-01

    An analytical solution for the unified equation for degenerated (pseudo-) first-order reactions, e.g., enantiomerization processes, in dynamic CE is presented, and validated with a dataset of 31 250 elution profiles covering typical experimental parameters. The unified equation was applied to determine the enantiomerization barrier of the hypnotic glutarimide derivative thalidomide (Contergan(R)) by dynamic capillary electrokinetic chromatography (DEKC). The enantiomer separation of thalidomide was performed in an aqueous 50 mM sodium borate buffer at pH 9.3 in the presence of the chiral mobile phase additive carboxymethyl-beta-CD. Interconversion profiles featuring pronounced plateau formation were observed. Activation parameters DeltaH( not equal) and DeltaS( not equal) were obtained from temperature-dependent measurements between 20.0 and 37.5 degrees C in 2.5K steps. From the activation parameters the enantiomerization barrier of thalidomide at 37 degrees C under basic conditions were calculated to be DeltaG( not equal) = 93.2 kJ/mol. Comparison of the kinetic data with results obtained at pH 8.0 reveals the catalytic influence of the base on the enantiomerization barrier.

  18. The unified equation for the evaluation of first order reactions in dynamic electrophoresis.

    Science.gov (United States)

    Trapp, Oliver

    2006-02-01

    The unified equation was validated for first order reactions in dynamic CE with a data set of 31 250 elution profiles. Comparison with the results from conventional iterative computer simulation revealed that the unified equation is superior in terms of success rate and precision. The unified equation was applied to determine the cis-trans isomerization rate constants of the angiotensin converting enzyme inhibitor captopril. The separation of the rotational cis-trans isomeric drug has been performed in an aqueous 66 mM citric acid/Tris buffer at pH 3.0 in a 50 cm polyacrylamide-coated fused-silica capillary. Interconversion profiles featuring pronounced plateau formation and peak broadening were observed. Activation parameters DeltaH not equal and DeltaS not equal were obtained from temperature-dependent measurements between 10 and 25 degrees C in 2.5 K steps. From the activation parameters the isomerization barriers of captopril at 37 degrees C under acidic conditions were calculated to be DeltaG not equal trans-->cis=90.6 kJ/mol and DeltaG not equal cis-->trans=84.6 kJ/mol. By comparison of the kinetic data with the results obtained under basic conditions (pH 9.3) a mechanism of isomerization could be proposed.

  19. A generalized cellular automata approach to modeling first order enzyme kinetics

    Indian Academy of Sciences (India)

    Abhishek Dutta; Saurajyoti Kar; Advait Apte; Ingmar Nopens; Denis Constales

    2015-04-01

    Biochemical processes occur through intermediate steps which are associated with the formation of reaction complexes. These enzyme-catalyzed biochemical reactions are inhibited in a number of ways such as inhibitors competing for the binding site directly, inhibitors deforming the allosteric site or inhibitors changing the structure of active substrate. Using an in silico approach, the concentration of various reaction agents can be monitored at every single time step, which are otherwise difficult to analyze experimentally. Cell-based models with discrete state variables, such as Cellular Automata (CA) provide an understanding of the organizational principles of interacting cellular systems to link the individual cell (microscopic) dynamics wit a particular collective (macroscopic) phenomenon. In this study, a CA model representing a first order enzyme kinetics with inhibitor activity is formulated. The framework of enzyme reaction rules described in this study is probabilistic. An extended von Neumann neighborhood with periodic boundary condition is implemented on a two-dimensional (2D) lattice framework. The effect of lattice-size variation is studied followed by a sensitivity analysis of the model output to the probabilistic parameters which represent various kinetic reaction constants in the enzyme kinetic model. This provides a deeper insight into the sensitivity of the CA model to these parameters. It is observed that cellular automata can capture the essential features of a discrete real system, consisting of space, time and state, structured with simple local rules without making complex implementations but resulting in complex but explainable patterns.

  20. First-order quantum phase transitions: test ground for emergent chaoticity, regularity and persisting symmetries

    CERN Document Server

    Macek, M

    2014-01-01

    We present a comprehensive analysis of the emerging order and chaos and enduring symmetries, accompanying a generic (high-barrier) first-order quantum phase transition (QPT). The interacting boson model Hamiltonian employed, describes a QPT between spherical and deformed shapes, associated with its U(5) and SU(3) dynamical symmetry limits. A~classical analysis of the intrinsic dynamics reveals a rich but simply-divided phase space structure with a H\\'enon-Heiles type of chaotic dynamics ascribed to the spherical minimum and a robustly regular dynamics ascribed to the deformed minimum. The simple pattern of mixed but well-separated dynamics persists in the coexistence region and traces the crossing of the two minima in the Landau potential. A quantum analysis discloses a number of regular low-energy U(5)-like multiplets in the spherical region, and regular SU(3)-like rotational bands extending to high energies and angular momenta, in the deformed region. These two kinds of regular subsets of states retain thei...

  1. First order simulations on time measurements using inorganic scintillators for PET applications

    Energy Technology Data Exchange (ETDEWEB)

    Joly, B.; Montarou, G.; Pauna, N

    2008-07-01

    Time measurements based on scintillating crystals are used in many different experimental sets-up in high energy physics, nuclear physics and medical imaging (e.g. PET). Time of Flight (TOF) positron emission tomography (PET) is based on the measurement of the difference between the detection times of the two gamma arising from positrons decays. The fundamental improvement of TOF is an increase in signal to noise ratio which translates into sensitivity improvement. Conventional method for time measurements is based on the detection of first photoelectrons. Recently, in LHC experiments and more particularly for electromagnetic calorimeter, a fully digital method based on optimal filtering that considers samples of the entire signal was successfully applied. Since such a method allows ultimately time resolutions of about a few tens of picoseconds, for this report, first order simulations were performed using a simplified model of a detection block made of a PMT coupled to a LYSO or LaBr{sub 3} crystal. These simulations were achieved to estimate time resolutions with the conventional method (first photoelectrons detection with CFD) or the optimal filtering. A hybrid method is also tested to be applied with fast running front-end electronics. These simulations will be the basis for experimental future studies. (authors)

  2. First-order phase transitions in repulsive rigid k-mers on two-dimensional lattices

    Science.gov (United States)

    Pasinetti, P. M.; Romá, F.; Ramirez-Pastor, A. J.

    2012-02-01

    In a previous paper [F. Romá, A. J. Ramirez-Pastor, and J. L. Riccardo, Phys. Rev. B 72, 035444 (2005)], the critical behavior of repulsive rigid rods of length k (k-mers) on a square lattice at half coverage has been studied by using Monte Carlo (MC) simulations. The obtained results indicated that (1) the phase transition occurring in the system is a second-order phase transition for all adsorbate sizes k; and (2) the universality class of the transition changes from 2D Ising-type for monomers (k = 1) to an unknown universality class for k ≥ 2. In the present work, we revisit our previous results together with further numerical evidences, resulting from new extensive MC simulations based on an efficient exchange algorithm and using high-performance computational capabilities. In contrast to our previous conclusions (1) and (2), the new numerical calculations clearly support the occurrence of a first-order phase transition for k ≥ 2. In addition, a similar scenario was found for k-mers adsorbed on the triangular lattice at coverage k/(2k+1).

  3. Black string first order flow in N=2, d=5 abelian gauged supergravity

    CERN Document Server

    Klemm, Dietmar; Rabbiosi, Marco

    2016-01-01

    We derive both BPS and non-BPS first-order flow equations for magnetically charged black strings in five-dimensional N=2 abelian gauged supergravity, using the Hamilton-Jacobi formalism. This is first done for the coupling to vector multiplets only and U(1) Fayet-Iliopoulos (FI) gauging, and then generalized to the case where also hypermultiplets are present, and abelian symmetries of the quaternionic hyperscalar target space are gauged. We then use these results to derive the attractor equations for near-horizon geometries of extremal black strings, and solve them explicitely for the case where the constants appearing in the Chern-Simons term of the supergravity action satisfy an adjoint identity. This allows to compute in generality the central charge of the two-dimensional conformal field theory that describes the black strings in the infrared, in terms of the magnetic charges, the CY intersection numbers and the FI constants. Finally, we extend the r-map to gauged supergravity and use it to relate our flo...

  4. Spin–orbit precession for eccentric black hole binaries at first order in the mass ratio

    Science.gov (United States)

    Akcay, Sarp; Dempsey, David; Dolan, Sam R.

    2017-04-01

    We consider spin–orbit (‘geodetic’) precession for a compact binary in strong-field gravity. Specifically, we compute ψ, the ratio of the accumulated spin-precession and orbital angles over one radial period, for a spinning compact body of mass m 1 and spin s 1, with {{s}1}\\ll Gm12/c , orbiting a non-rotating black hole. We show that ψ can be computed for eccentric orbits in both the gravitational self-force and post-Newtonian frameworks, and that the results appear to be consistent. We present a post-Newtonian expansion for ψ at next-to-next-to-leading order, and a Lorenz-gauge gravitational self-force calculation for ψ at first order in the mass ratio. The latter provides new numerical data in the strong-field regime to inform the effective one-body model of the gravitational two-body problem. We conclude that ψ complements the Detweiler redshift z as a key invariant quantity characterizing eccentric orbits in the gravitational two-body problem.

  5. First Order Phase Transition of Plaquette Ordering in SU(4) Antiferromagnets

    Science.gov (United States)

    Mishra, Anup; Ma, Michael; Zhang, Fu-Chun

    2002-03-01

    Spin systems with orbital degeneracy may have an ideal limit with SU(4) degeneracy(Phys. Rev. Lett 81,3527 (1998)). Based on MFT and variational calculations, it was proposed that the ground state of the SU(4) system in 2D is a spin and orbital liquid. Finite-sized numerical calculations on square lattice further support this proposition(Eur. Phys. J. B17,367 (2000)). The numerical work also suggests the ground state to be 4-fold degenerate. We propose that the 4-fold degeneracy is due to spontaneous formation of plaquettes with alternating plaquettes of strong and weak correlations. Using fermion MFT on square and triangular lattice, we find at zero temperature that the ground state is a state of disconnected plaquettes. The discrete symmetry of plaquette ordering allows for a finite temperature phase transition from the disordered phase to the ordered phase even in 2D. Within MFT, the transition is found to be first order for both the square and triangular lattice. Nevertheless, there are important differences between the transitions on the two lattices.

  6. Non-definability of languages by generalized first-order formulas over (N,+)

    CERN Document Server

    Krebs, Andreas

    2012-01-01

    We consider first-order logic with monoidal quantifiers over words. We show that all languages with a neutral letter, definable using the addition numerical predicate are also definable with the order predicate as the only numerical predicate. Let S be a subset of monoids. Let LS be the logic closed under quantification over the monoids in S and N be the class of neutral letter languages. Then we show that: LS[<,+] cap N = LS[<] Our result can be interpreted as the Crane Beach conjecture to hold for the logic LS[<,+]. As a corollary of our result we get the result of Roy and Straubing that FO+MOD[<,+] collapses to FO+MOD[<]. For cyclic groups, we answer an open question of Roy and Straubing, proving that MOD[<,+] collapses to MOD[<]. Our result also shows that multiplication is necessary for Barrington's theorem to hold. All these results can be viewed as separation results for very uniform circuit classes. For example we separate FO[<,+]-uniform CC0 from FO[<,+]-uniform ACC0.

  7. Spin-orbit precession for eccentric black hole binaries at first order in the mass ratio

    CERN Document Server

    Akcay, Sarp; Dolan, Sam

    2016-01-01

    We consider spin-orbit ("geodetic") precession for a compact binary in strong-field gravity. Specifically, we compute $\\psi$, the ratio of the accumulated spin-precession and orbital angles over one radial period, for a spinning compact body orbiting a non-rotating black hole. We show that $\\psi$ can be computed for eccentric orbits in both the gravitational self-force and post-Newtonian frameworks, and that the results appear to be consistent. We present a post-Newtonian expansion for $\\psi$ at next-to-next-to-leading order, and a Lorenz-gauge gravitational self-force calculation for $\\psi$ at first order in the mass ratio. The latter provides new numerical data in the strong-field regime to inform the Effective One-Body model of the gravitational two-body problem. We conclude that $\\psi$ complements the Detweiler redshift $z$ as a key invariant quantity characterizing eccentric orbits in the gravitational two-body problem.

  8. Vortex-Antivortex Pair Production in a First Order Phase Transition

    CERN Document Server

    Digal, S; Srivastava, A M; Digal, Sanatan; Sengupta, Supratim; Srivastava, Ajit M.

    1997-01-01

    We carry out numerical simulation of a first order phase transition in 2+1 dimensions by randomly nucleating bubbles, and study the formation of global U(1) vortices. Bubbles grow and coalesce and vortices are formed at junctions of bubbles via standard Kibble mechanism as well as due to a new mechanism, recently proposed by us, where defect-antidefect pairs are produced due to field oscillations. We make a comparative study of the contribution of both of these mechanisms for vortex production. We find that, for high nucleation rate of bubbles, vortex-antivortex pairs produced via the new mechanism have overlapping configurations, and annihilate quickly; so only those vortices survive till late which are produced via the Kibble mechanism. However, for low nucleation rates, bubble collisions are energetic enough to lead to many well separated vortex-antivortex pairs being produced via the new mechanism. For example, in a simulation involving nucleation of 20 bubbles, a total of 14 non-overlapping vortices and ...

  9. The Jump Set under Geometric Regularization. Part 1: Basic Technique and First-Order Denoising

    KAUST Repository

    Valkonen, Tuomo

    2015-01-01

    © 2015 Society for Industrial and Applied Mathematics. Let u ∈ BV(Ω) solve the total variation (TV) denoising problem with L2-squared fidelity and data f. Caselles, Chambolle, and Novaga [Multiscale Model. Simul., 6 (2008), pp. 879-894] have shown the containment Hm-1 (Ju \\\\Jf) = 0 of the jump set Ju of u in that of f. Their proof unfortunately depends heavily on the co-area formula, as do many results in this area, and as such is not directly extensible to higher-order, curvature-based, and other advanced geometric regularizers, such as total generalized variation and Euler\\'s elastica. These have received increased attention in recent times due to their better practical regularization properties compared to conventional TV or wavelets. We prove analogous jump set containment properties for a general class of regularizers. We do this with novel Lipschitz transformation techniques and do not require the co-area formula. In the present Part 1 we demonstrate the general technique on first-order regularizers, while in Part 2 we will extend it to higher-order regularizers. In particular, we concentrate in this part on TV and, as a novelty, Huber-regularized TV. We also demonstrate that the technique would apply to nonconvex TV models as well as the Perona-Malik anisotropic diffusion, if these approaches were well-posed to begin with.

  10. Consensus problems of first-order dynamic multi-agent systems with multiple time delays

    Institute of Scientific and Technical Information of China (English)

    Ji Liang-Hao; Liao Xiao-Feng

    2013-01-01

    Consensus problems of first-order multi-agent systems with multiple time delays are investigated in this paper.We discuss three cases:1) continuous,2) discrete,and 3) a continuous system with a proportional plus derivative controller.In each case,the system contains simultaneous communication and input time delays.Supposing a dynamic multi-agent system with directed topology that contains a globally reachable node,the sufficient convergence condition of the system is discussed with respect to each of the three cases based on the generalized Nyquist criterion and the frequency-domain analysis approach,yielding conclusions that are either less conservative than or agree with previously published results.We know that the convergence condition of the system depends mainly on each agent's input time delay and the adjacent weights but is independent of the communication delay between agents,whether the system is continuous or discrete.Finally,simulation examples are given to verify the theoretical analysis.

  11. Discrete-ordinate radiative transfer in a stratified medium with first-order rotational Raman scattering

    Energy Technology Data Exchange (ETDEWEB)

    Spurr, Robert [RT Solutions Inc., 9 Channing Street, Cambridge, MA 02138 (United States)], E-mail: rtsolutions@verizon.net; Haan, Johan de; Oss, Roeland van [KNMI, de Bilt (Netherlands); Vasilkov, Alexander [SSAI, Lanham, MD (United States)

    2008-02-15

    Rotational Raman scattering (RRS) by air molecules in the Earth's atmosphere is predominantly responsible for the Ring effect: Fraunhofer and absorption-feature filling-in observed in UV/visible backscatter spectra. Accurate determination of RRS effects requires detailed radiative transfer (RT) treatment. In this paper, we demonstrate that the discrete-ordinate RT equations may be solved analytically in a multi-layer multiple scattering atmosphere in the presence of RRS treated as a first-order perturbation. Based on this solution, we develop a generic pseudo-spherical RT model LIDORT-RRS for the determination of backscatter radiances with RRS included; the model will generate output at arbitrary viewing geometry and optical thickness. Model comparisons with measured RRS filling-in effects from OMI observations show very good agreement. We examine telluric RRS filling-in effects for satellite-view backscatter radiances in a spectral range covering the ozone Huggins absorption bands. The model is also used to investigate calcium H and K Fraunhofer filling-in through cloud layers in the atmosphere.

  12. The gravitational Hamiltonian, first order action, Poincar\\'e charges and surface terms

    CERN Document Server

    Corichi, Alejandro

    2015-01-01

    We consider the issue of attaining a consistent Hamiltonian formulation, after a 3+1 splitting, of a well-defined action principle for asymptotically flat gravity. More precisely, our starting point is the gravitational first order Holst action with surface terms and fall-off conditions that make the variational principle and the covariant phase space formulation well-defined for asymptotically flat spacetimes. Keeping all surface terms and paying due attention to subtleties that arise from the different cut-offs at infinity, we give a derivation of the gravitational Hamiltonian starting from this action. The 3+1 decomposition and time gauge fixing results in a well-defined Hamiltonian action and a well-defined Hamiltonian formulation for the standard -and more general- asymptotic ADM conditions. Unlike the case of the Einstein-Hilbert action with Gibbons-Hawking-York or Hawking-Horowitz terms, here we {\\it {do}} recover the ADM energy-momentum from the covariant surface term also when more general variations...

  13. Macroinvertebrates associated with bryophyta in a first-order Atlantic Forest stream

    Directory of Open Access Journals (Sweden)

    Beatriz F. J. V. Rosa

    2011-06-01

    Full Text Available This study describes the composition and structure of the benthic community associated with bryophytes in a first-order stream, located in a biological reserve of the Atlantic Forest, during two seasons. During three months of the dry season of 2007 and three months of the rainy season of 2008, samples of bryophytes attached to stones were collected randomly, along a 100 m stream reach. The structure of the community was analyzed through the mean density of individuals, Shannon's diversity index, Pielou's evenness, family richness, dominance index, and the percentage of Ephemeroptera, Plecoptera and Trichoptera (% EPT. Chironomidae larvae were dominant in the two periods of study, followed by Ceratopogonidae in the rainy season, and Naididae in the dry season. The orders EPT contributed 14 families. The results showed that bryophytes constitute suitable habitat which is able to shelter an abundant and diversified benthic fauna in a small extension of the stream. This habitat provides refuge during spates, and thus minimizes downstream transport of the macroinvertebrate fauna.

  14. First-order-reversal-curve analysis of Pr-Fe-B-based nanocomposites

    Science.gov (United States)

    Cornejo, D. R.; Peixoto, T. R. F.; Reboh, S.; Fichtner, P. F. P.; de Franco, V. C.; Villas-Boas, V.; Missell, F. P.

    2010-04-01

    Ribbons of nominal composition (Pr9.5Fe84.5B6)0.96Cr0.01(TiC)0.03 were produced by arc-melting and melt-spinning the alloys on a Cu wheel. X-ray diffraction reveals two main phases, one based upon α-Fe and the other upon Pr2Fe14B. The ribbons show exchange spring behavior with Hc=12.5 kOe and (BH)max=13.6 MGOe when these two phases are well coupled. Transmission electron microscopy revealed that the coupled behavior is observed when the microstructure consists predominantly of α-Fe grains (diameter ˜100 nm.) surrounded by hard material containing Pr2Fe14B. A first-order-reversal-curve (FORC) analysis was performed for both a well-coupled sample and a partially-coupled sample. The FORC diagrams show two strong peaks for both the partially-coupled sample and for the well-coupled material. In both cases, the localization of the FORC probability suggests demagnetizing interactions between particles. Switching field distributions were calculated and are consistent with the sample microstructure.

  15. First-order phase transition during displacement of amphiphilic biomacromolecules from interfaces by surfactant molecules.

    Science.gov (United States)

    Ettelaie, Rammile; Dickinson, Eric; Pugnaloni, Luis

    2014-11-19

    The adsorption of surfactants onto a hydrophobic interface, already laden with a fixed number of amphiphilic macromolecules, is studied using the self consistent field calculation method of Scheutjens and Fleer. For biopolymers having unfavourable interactions with the surfactant molecules, the adsorption isotherms show an abrupt jump at a certain value of surfactant bulk concentration. Alternatively, the same behaviour is exhibited when the number of amphiphilic chains on the interface is decreased. We show that this sudden jump is associated with a first-order phase transition, by calculating the free energy values for the stable and the metastable states at both sides of the transition point. We also observe that the transition can occur for two approaching surfaces, from a high surfactant coverage phase to a low surfactant coverage one, at sufficiently close separation distances. The consequence of this finding for the steric colloidal interactions, induced by the overlap of two biopolymer + surfactant films, is explored. In particular, a significantly different interaction, in terms of its magnitude and range, is predicted for these two phases. We also consider the relevance of the current study to problems involving the competitive displacement of proteins by surfactants in food colloid systems.

  16. Numerical simulations of acoustically generated gravitational waves at a first order phase transition

    CERN Document Server

    Hindmarsh, Mark; Rummukainen, Kari; Weir, David J

    2015-01-01

    We present details of numerical simulations of the gravitational radiation produced by a first order {thermal} phase transition in the early universe. We confirm that the dominant source of gravitational waves is sound waves generated by the expanding bubbles of the low-temperature phase. We demonstrate that the sound waves have a power spectrum with power-law form between the scales set by the average bubble separation (which sets the length scale of the fluid flow $L_\\text{f}$) and the bubble wall width. The sound waves generate gravitational waves whose power spectrum also has a power-law form, at a rate proportional to $L_\\text{f}$ and the square of the fluid kinetic energy density. We identify a dimensionless parameter $\\tilde\\Omega_\\text{GW}$ characterising the efficiency of this "acoustic" gravitational wave production whose value is $8\\pi\\tilde\\Omega_\\text{GW} \\simeq 0.8 \\pm 0.1$ across all our simulations. We compare the acoustic gravitational waves with the standard prediction from the envelope appr...

  17. Magnetic Fields at First Order Phase Transition: A Threat to Electroweak Baryogenesis

    CERN Document Server

    De Simone, Andrea; Quiros, Mariano; Riotto, Antonio

    2011-01-01

    The generation of the observed baryon asymmetry may have taken place during the electroweak phase transition, thus involving physics testable at LHC, a scenario dubbed electroweak baryogenesis. In this paper we point out that the magnetic field which is produced in the bubbles of a first order phase transition endangers the baryon asymmetry produced in the bubble walls. The reason being that the produced magnetic field couples to the sphaleron magnetic moment and lowers the sphaleron energy; this strengthens the sphaleron transitions inside the bubbles and triggers a more effective wash out of the baryon asymmetry. We apply this scenario to the Minimal Supersymmetric extension of the Standard Model (MSSM) where, in the absence of a magnetic field, successful electroweak baryogenesis requires the lightest CP-even Higgs and the right-handed stop masses to be lighter than about 127 GeV and 120 GeV, respectively. We show that even for moderate values of the magnetic field, the Higgs mass required to preserve the ...

  18. A field methodology for quantifying phosphorus transfer and delivery to streams in first order agricultural catchments

    Science.gov (United States)

    Deasy, C.; Heathwaite, A. L.; Brazier, R. E.

    2008-02-01

    SummaryAn understanding of the relative importance of different hydrological pathways in phosphorus delivery from land to water is currently constrained by a lack of appropriate methods available to quantify the delivery process. New monitoring tools are needed which will provide a framework for understanding phosphorus (P) transfer and delivery at a range of scales in agricultural catchments. A field methodology incorporating the techniques of event-based, on-site observation and sampling within a flexible, non-plot based structure is described and applied to a first order stream catchment in Southern England, UK. The results show that P transfers to the stream reach monitored were dominated by inputs from one field drain, and that overland flow inputs, despite being directly connected to the stream and containing higher P concentrations (maximum 3708 μg l -1), contributed less to the stream P flux. The processes of P transfer and delivery to the stream were complex, changing both within flow pathways and temporally over an event.

  19. Posttreatment Functioning of Alcoholic Patients: Its Relation to Program Participation

    Science.gov (United States)

    Bromet, Evelyn; And Others

    1977-01-01

    Assessed posttreatment functioning of 429 alcoholic patients selected from five different types of treatment facilities. Substantial improvement in three areas of functioning (drinking, occupational, and psychological) occurred among patients in each program, although there were significant differences among programs in level of functioning at…

  20. Cost Functions for Airframe Production Programs.

    Science.gov (United States)

    1982-07-01

    VIII. RESULTS AND AIRFORCE APPLICATIONS. ........... 164 Introduction Understanding Production Scheduling Program Management and Monitoring Cost...Program Management and Monitoring In addition to contributing to our general understanding of production scheduling, the revised model can be used for...202 38. Womer, N. K. "Learning Curves, Production Rate, and Program Costs." Management Science, Vol. XXV (April, 1979), 312-19. 39. Warer , N. K