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Sample records for finely distributed metallic

  1. Irregular distribution of metal ions in ferrites prepared by co-precipitation technique structure analysis of Mn-Zn ferrite using extended X-ray absorption fine structure

    International Nuclear Information System (INIS)

    Jeyadevan, B.; Tohji, K.; Nakatsuka, K.; Narayanasamy, A.

    2000-01-01

    The tetrahedral/octahedral site occupancy of non-magnetic zinc ion, added to maximize the net magnetic moment of mixed ferrites has been found to depend on the method of preparation. In this paper, we qualitatively analyze the metal ion distribution in Mn-Zn ferrite particles prepared by co-precipitation and ceramic methods using extended X-ray absorption fine structure (EXAFS) technique. The results suggest that the differences observed in the magnetic properties of the samples prepared by different methods are not only due to the difference in particle size but also due to the difference in cation distribution. The difference in cation distributions between ferrites of similar composition prepared differently has been found to depend on the crystal field stability energies of the metal ion of interest and associated cations

  2. Concentration levels and spatial distribution of sulphur and metals in fine-grained sediments in western Finland

    Directory of Open Access Journals (Sweden)

    M. ÅSTRÖM

    2008-12-01

    Full Text Available On the coastal plains of Finland, widespread Holocene marine and lacustrine sediments have developed into acid sulphate soil as a result of extensive artificial drainage for agricultural purposes. This has caused a variety of environmental problems. The aim of this study was to determine the concentration levels and spatial distribution of sulphur, carbon and metals [titanium, vanadium, chromium, manganese (Mn, iron, cobalt (Co, nickel (Ni, copper (Cu, zinc (Zn] in these sediments, in order to increase the geochemical understanding of the parent materials from which acid sulphate soil develops. Sediment samples were collected at 317 sites from a depth of 1.5–3 m. While the sediments have high S (sulphide concentrations (median = 0.54% and thus a strong acidification potential, they carry transition metals mainly in smallsized silicates close to “background concentrations” far below contamination limits. The previously documented extensive release of Co, Cu, Mn, Ni and Zn from oxidised and acidified layers of these sediments (i.e. acid sulphate soil is thus not explained by anomalously high natural or anthropogenic metal concentrations of the soils/sediments, but by an inherent highly mobile metal pool. Spatial-distribution maps highlight areas of elevated S and Mn concentrations, where it is likely that ditching and subsequent oxidation will result in an exceptionally large release of protons and Mn respectively.;

  3. Radiation effects in fine metal media

    International Nuclear Information System (INIS)

    Zaikin, Yu. A.; Aliev, A.B.

    1999-01-01

    The report discusses condition and perspectives of theoretical and experimental research of metal powder material radiation processing influence on their caking, recrystallization and formation of metal and alloy structure obtained by powder metallurgy methods. Radiation processing of metal powders under determined modes causes forming of homogeneous fine metal structure and helps to considerably improve their running abilities (strength, endurance, corrosion resistance) and caking technological conditions

  4. Preparation and utilization of metal oxide fine powder

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Joon Soo; Jang, Hee Dong; Lim, Young Woong; Kim, Sung Don; Lee, Hi Sun; Lee, Hoo In; Kim, Chul Joo; Shim, Gun Joo; Jang, Dae Kyu [Korea Inst. of Geology Mining and Materials, Taejon (Korea, Republic of)

    1995-12-01

    Metal oxide fine powders finds many applications in industry as new materials. It is very much necessary for the development of such powders to improve the domestic industry. The purpose of present research is to develop a process for the preparation and utilization of metal oxide fine powder. This project is consisted of two main subjects. (1) Production of ultrafine metal oxide powder: Ultrafine metal oxide powder is defined as a metal oxide powder of less than 100 nanometer in particle size. Experiments for the control of particle size and distributions in the various reaction system and compared with results of (2 nd year research). Various reaction systems were adopted for the development of feasible process. Ultrafine particles could be prepared even higher concentration of TiCl{sub 4} and lower gas flowrate compared to TiCl{sub 4}-O{sub 2} system in the TiCl{sub 4}-Air-H{sub 2}O system. Ultrafine Al{sub 2}O{sub 3} powders also prepared with the change of concentration and gas flowrate. Experiments on the treatment of surface characteristics of ultrafine TiO{sub 2} powders were investigated using esterification and surface treating agents. A mathematical model that can predict the particle size and distribution was also developed. (2) Preparation of cerium oxide for high-grade polishing powder: Used cerium polishing powder was recycled for preparation of high grade cerium oxide polishing powder. Also, cerium hydroxide which was generated as by-product in processing of monazite ore was used as another material. These two materials were leached respectively by using acid, and the precipitate was gained in each leached solution by adjusting pH of the solution, and by selective crystallization. These precipitates were calcined to make high grade cerium oxide polishing powder. The effect of several experimental variables were investigated, and the optimum conditions were obtained through the experiments. (author). 81 refs., 49 figs., 27 tabs.

  5. Process for the preparation of fine grain metal carbide powders

    International Nuclear Information System (INIS)

    Gortsema, F.P.

    1976-01-01

    Fine grain metal carbide powders are conveniently prepared from the corresponding metal oxide by heating in an atmosphere of methane in hydrogen. Sintered articles having a density approaching the theoretical density of the metal carbide itself can be fabricated from the powders by cold pressing, hot pressing or other techniques. 8 claims, no drawings

  6. Pulsed high energy synthesis of fine metal powders

    Science.gov (United States)

    Witherspoon, F. Douglas (Inventor); Massey, Dennis W. (Inventor)

    1999-01-01

    Repetitively pulsed plasma jets generated by a capillary arc discharge at high stagnation pressure (>15,000 psi) and high temperature (>10,000 K) are utilized to produce 0.1-10 .mu.m sized metal powders and decrease cost of production. The plasma jets impact and atomize melt materials to form the fine powders. The melt can originate from a conventional melt stream or from a pulsed arc between two electrodes. Gas streams used in conventional gas atomization are replaced with much higher momentum flux plasma jets. Delivering strong incident shocks aids in primary disintegration of the molten material. A series of short duration, high pressure plasma pulses fragment the molten material. The pulses introduce sharp velocity gradients in the molten material which disintegrates into fine particles. The plasma pulses have peak pressures of approximately one kilobar. The high pressures improve the efficiency of disintegration. High gas flow velocities and pressures are achieved without reduction in gas density. Repetitively pulsed plasma jets will produce powders with lower mean size and narrower size distribution than conventional atomization techniques.

  7. Fine Coining of Bulk Metal Formed Parts in Digital Environment

    International Nuclear Information System (INIS)

    Pepelnjak, T.; Kuzman, K.; Krusic, V.

    2007-01-01

    At present the production of bulk metal formed parts in the automotive industry must increasingly fulfil demands for narrow tolerance fields. The final goal of the million parts production series is oriented towards zero defect production. This is possible by achieving production tolerances which are even tighter than the prescribed ones. Different approaches are used to meet this demanding objective affected by many process parameters. Fine coining as a final forming operation is one of the processes which enables the production of good manufacturing tolerances and high process stability. The paper presents the analyses of the production of the inner race and a digital evaluation of manufacturing tolerances caused by different material parameters of the workpiece. Digital optimisation of the fine coining with FEM simulations was performed in two phases. Firstly, fine coining of the inner racer in a digital environment was comparatively analysed with the experimental work in order to verify the accuracy and reliability of digitally calculated data. Secondly, based on the geometrical data of a digitally fine coined part, tool redesign was proposed in order to tighten production tolerances and increase the process stability of the near-net-shaped cold formed part

  8. Insights into metals in individual fine particles from municipal solid waste using synchrotron radiation-based micro-analytical techniques

    Institute of Scientific and Technical Information of China (English)

    Yumin Zhu; Hua Zhang; Liming Shao; Pinjing He

    2015-01-01

    Excessive inter-contamination with heavy metals hampers the application of biological treatment products derived from mixed or mechanically-sorted municipal solid waste (MSW).In this study,we investigated fine particles of <2 mm,which are small fractions in MSW but constitute a significant component of the total heavy metal content,using bulk detection techniques.A total of 17 individual fine particles were evaluated using synchrotron radiation-based micro-X-ray fluorescence and micro-X-ray diffraction.We also discussed the association,speciation and source apportionment of heavy metals.Metals were found to exist in a diffuse distribution with heterogeneous intensities and intense hot-spots of <10 μm within the fine particles.Zn-Cu,Pb-Fe and Fe-Mn-Cr had significant correlations in terms of spatial distribution.The overlapped enrichment,spatial association,and the mineral phases of metals revealed the potential sources of fine particles from size-reduced waste fractions (such as scraps of organic wastes or ceramics) or from the importation of other particles.The diverse sources of heavy metal pollutants within the fine particles suggested that separate collection and treatment of the biodegradable waste fraction (such as food waste) is a preferable means of facilitating the beneficial utilization of the stabilized products.

  9. Laser Indirect Shock Welding of Fine Wire to Metal Sheet.

    Science.gov (United States)

    Wang, Xiao; Huang, Tao; Luo, Yapeng; Liu, Huixia

    2017-09-12

    The purpose of this paper is to present an advanced method for welding fine wire to metal sheet, namely laser indirect shock welding (LISW). This process uses silica gel as driver sheet to accelerate the metal sheet toward the wire to obtain metallurgical bonding. A series of experiments were implemented to validate the welding ability of Al sheet/Cu wire and Al sheet/Ag wire. It was found that the use of a driver sheet can maintain high surface quality of the metal sheet. With the increase of laser pulse energy, the bonding area of the sheet/wire increased and the welding interfaces were nearly flat. Energy dispersive spectroscopy (EDS) results show that the intermetallic phases were absent and a short element diffusion layer which would limit the formation of the intermetallic phases emerging at the welding interface. A tensile shear test was used to measure the mechanical strength of the welding joints. The influence of laser pulse energy on the tensile failure modes was investigated, and two failure modes, including interfacial failure and failure through the wire, were observed. The nanoindentation test results indicate that as the distance to the welding interface decreased, the microhardness increased due to the plastic deformation becoming more violent.

  10. Characterization of road runoff with regard to seasonal variations, particle size distribution and the correlation of fine particles and pollutants.

    Science.gov (United States)

    Hilliges, R; Endres, M; Tiffert, A; Brenner, E; Marks, T

    2017-03-01

    Urban runoff is known to transport a significant pollutant load consisting of e.g. heavy metals, salts and hydrocarbons. Interactions between solid and dissolved compounds, proper understanding of particle size distribution, dissolved pollutant fractions and seasonal variations is crucial for the selection and development of appropriate road runoff treatment devices. Road runoff at an arterial road in Augsburg, Germany, has been studied for 3.5 years. A strong seasonal variation was observed, with increased heavy metal concentrations with doubled and tripled median concentrations for heavy metals during the cold season. Correlation analysis showed that de-icing salt is not the only factor responsible for increased pollutant concentrations in winter. During the cold period, the fraction of dissolved metals was lower compared to the warm season. In road dust, the highest metal concentrations were measured for fine particles. Metals in road runoff were found to show a significant correlation to fine particles SS63 (removal rates.

  11. Bioavailability of very finely distributed metallic platinum in the lungs and first orienting studies on effects. Part 1; Bioverfuegbarkeit von feinstverteiltem metallischem Platin in der Lunge und erste orientierende Wirkungsuntersuchungen (VPT 09; 1. Teil)

    Energy Technology Data Exchange (ETDEWEB)

    Artelt, S [Fraunhofer-Institut fuer Toxikologie und Aerosolforschung, Hannover (Germany)

    1998-12-31

    Projects 07 VPT 08 and 07 VPT 08A revealed that platinum from automotive catalytic converters are largely emitted in metallic form as bound to the support material (aluminium oxide). Platinum emissions from this source are on the order of ng per km. The aim of the still ongoing project 07 VPT 09 is to estimate any health hazards that might grow from the deposition in the human lung by inhalation of very fine platinum particles. To answer this question it is necessary to have sufficient quantities of abraded material at one`s disposal. [Deutsch] Im Rahmen des Projektes 07 VPT 08 und 07 VPT 08A wurde festgestellt, dass Platin aus Automobilabgaskatalysatoren zum ueberwiegenden Teil in metallischer Form, gebunden an Traegermaterial (Aluminiumoxid), emittiert wird. Dabei liegt die Platinemission in der Groessenordnung von ng Platin/km. Im noch laufenden Vorhaben 07 VPT 09 soll ein eventuell auftretendes gesundheitliches Risiko, das durch die inhalative Aufnahme von sehr feinen Platinpartikeln in die Lunge des Menschen entstehen koennte, abgeschaetzt werden. Versuche zur Beantwortung dieser Frage setzen voraus, dass eine genuegend grosse Menge an Abriebmaterial zur Verfuegung steht. (orig.)

  12. Bioavailability of very finely distributed metallic platinum in the lungs and first orienting studies on effects. Part 1; Bioverfuegbarkeit von feinstverteiltem metallischem Platin in der Lunge und erste orientierende Wirkungsuntersuchungen (VPT 09; 1. Teil)

    Energy Technology Data Exchange (ETDEWEB)

    Artelt, S. [Fraunhofer-Institut fuer Toxikologie und Aerosolforschung, Hannover (Germany)

    1997-12-31

    Projects 07 VPT 08 and 07 VPT 08A revealed that platinum from automotive catalytic converters are largely emitted in metallic form as bound to the support material (aluminium oxide). Platinum emissions from this source are on the order of ng per km. The aim of the still ongoing project 07 VPT 09 is to estimate any health hazards that might grow from the deposition in the human lung by inhalation of very fine platinum particles. To answer this question it is necessary to have sufficient quantities of abraded material at one`s disposal. [Deutsch] Im Rahmen des Projektes 07 VPT 08 und 07 VPT 08A wurde festgestellt, dass Platin aus Automobilabgaskatalysatoren zum ueberwiegenden Teil in metallischer Form, gebunden an Traegermaterial (Aluminiumoxid), emittiert wird. Dabei liegt die Platinemission in der Groessenordnung von ng Platin/km. Im noch laufenden Vorhaben 07 VPT 09 soll ein eventuell auftretendes gesundheitliches Risiko, das durch die inhalative Aufnahme von sehr feinen Platinpartikeln in die Lunge des Menschen entstehen koennte, abgeschaetzt werden. Versuche zur Beantwortung dieser Frage setzen voraus, dass eine genuegend grosse Menge an Abriebmaterial zur Verfuegung steht. (orig.)

  13. Insights into metals in individual fine particles from municipal solid waste using synchrotron radiation-based micro-analytical techniques.

    Science.gov (United States)

    Zhu, Yumin; Zhang, Hua; Shao, Liming; He, Pinjing

    2015-01-01

    Excessive inter-contamination with heavy metals hampers the application of biological treatment products derived from mixed or mechanically-sorted municipal solid waste (MSW). In this study, we investigated fine particles of heavy metal content, using bulk detection techniques. A total of 17 individual fine particles were evaluated using synchrotron radiation-based micro-X-ray fluorescence and micro-X-ray diffraction. We also discussed the association, speciation and source apportionment of heavy metals. Metals were found to exist in a diffuse distribution with heterogeneous intensities and intense hot-spots of metals revealed the potential sources of fine particles from size-reduced waste fractions (such as scraps of organic wastes or ceramics) or from the importation of other particles. The diverse sources of heavy metal pollutants within the fine particles suggested that separate collection and treatment of the biodegradable waste fraction (such as food waste) is a preferable means of facilitating the beneficial utilization of the stabilized products. Copyright © 2014. Published by Elsevier B.V.

  14. A quantitative analysis of fine scale distribution of intertidal meiofauna in response to food resources

    Digital Repository Service at National Institute of Oceanography (India)

    Ansari, Z.A.; Gauns, M.

    Fine scale vertical and spatial distribution of meiofauna in relation to food abundance was studied in the intertidal sediment at Dias Beach. The major abiotic factors showed significant changes and progressive fine scale decrease in vertical...

  15. Heavy metal accumulation and phytostabilisation potential of tree fine roots in a contaminated soil

    International Nuclear Information System (INIS)

    Brunner, Ivano; Luster, Joerg; Guenthardt-Goerg, Madeleine S.; Frey, Beat

    2008-01-01

    Root systems of Norway spruce (Picea abies) and poplar (Populus tremula) were long-term exposed to metal-contaminated soils in open-top chambers to investigate the accumulation of the heavy metals in the fine roots and to assess the plants suitability for phytostabilisation. The heavy metals from the contaminated soil accumulated in the fine roots about 10-20 times more than in the controls. The capacity to bind heavy metals already reached its maximum after the first vegetation period. Fine roots of spruce tend to accumulate more heavy metals than poplar. Copper and Zinc were mainly detected in the cell walls with larger values in the epidermis than in the cortex. The heavy metals accumulated in the fine roots made up 0.03-0.2% of the total amount in the soils. We conclude that tree fine roots adapt well to conditions with heavy metal contamination, but their phytostabilisation capabilities seem to be very low. - Long-term exposed fine roots of trees are well adapted to soils with high heavy metal contents, but their phytostabilisation capabilities are rather low

  16. Heavy metal pollution in sediment from Sisimiut, Greenland. Adsorption to organic matter and fine particles

    DEFF Research Database (Denmark)

    Ottosen, Lisbeth M.; Villumsen, Arne

    2006-01-01

    . The pollution could be linked to human activities in Sisimiut, a link that have not been investigated previously in Greenland. Except from the most polluted samples there was good correlation between heavy metal concentration and organic matter. Also some relation between fine fraction and heavy metal...

  17. Distribution of metal and adsorbed guest species in zeolites

    Energy Technology Data Exchange (ETDEWEB)

    Chmelka, B.F.

    1989-12-01

    Because of their high internal surface areas and molecular-size cavity dimensions, zeolites are used widely as catalysts, shape- selective supports, or adsorbents in a variety of important chemical processes. For metal-catalyzed reactions, active metal species must be dispersed to sites within the zeolite pores that are accessible to diffusing reactant molecules. The distribution of the metal, together with transport and adsorption of reactant molecules in zeolite powders, are crucial to ultimate catalyst performance. The nature of the metal or adsorbed guest distribution is known, however, to be dramatically dependent upon preparatory conditions. Our objective is to understand, at the molecular level, how preparatory treatments influence the distribution of guest species in zeolites, in order that macroscopic adsorption and reaction properties of these materials may be better understood. The sensitivity of xenon to its adsorption environment makes {sup 129}Xe NMR spectroscopy an important diagnostic probe of metal clustering and adsorbate distribution processes in zeolites. The utility of {sup 129}Xe NMR depends on the mobility of the xenon atoms within the zeolite-guest system, together with the length scale of the sample heterogeneity being studied. In large pore zeolites containing dispersed guest species, such as Pt--NaY, {sup 129}Xe NMR is insensitive to fine structural details at room temperature.

  18. Distribution of metal and adsorbed guest species in zeolites

    International Nuclear Information System (INIS)

    Chmelka, B.F.

    1989-12-01

    Because of their high internal surface areas and molecular-size cavity dimensions, zeolites are used widely as catalysts, shape- selective supports, or adsorbents in a variety of important chemical processes. For metal-catalyzed reactions, active metal species must be dispersed to sites within the zeolite pores that are accessible to diffusing reactant molecules. The distribution of the metal, together with transport and adsorption of reactant molecules in zeolite powders, are crucial to ultimate catalyst performance. The nature of the metal or adsorbed guest distribution is known, however, to be dramatically dependent upon preparatory conditions. Our objective is to understand, at the molecular level, how preparatory treatments influence the distribution of guest species in zeolites, in order that macroscopic adsorption and reaction properties of these materials may be better understood. The sensitivity of xenon to its adsorption environment makes 129 Xe NMR spectroscopy an important diagnostic probe of metal clustering and adsorbate distribution processes in zeolites. The utility of 129 Xe NMR depends on the mobility of the xenon atoms within the zeolite-guest system, together with the length scale of the sample heterogeneity being studied. In large pore zeolites containing dispersed guest species, such as Pt--NaY, 129 Xe NMR is insensitive to fine structural details at room temperature

  19. Distribution spatiale intra-urbaine des particules fines : monitoring ...

    African Journals Online (AJOL)

    SARAH

    30 sept. 2014 ... En outre, l'accumulation des particules fines est faible pendant un mois pluvieux par rapport à un mois sec ..... benjamina, et la structure (tige, branches) des arborées ... par Zhang et al., (2006) sur des feuilles de Pinus pumila.

  20. Modelling the fine and coarse fraction of heavy metals in Spain

    Science.gov (United States)

    García Vivanco, Marta; González, M. Angeles

    2014-05-01

    Heavy metals, such as cadmium, lead, nickel, arsenic, copper, chrome, zinc and selenium, are present in the air due to natural and anthropogenic emissions, normally joined to particles. These metals can affect life organisms via inhalation or ingestion, causing damages in human health and ecosystems. Small particles are inhaled and embebed in lungs and alveolus more easily than coarse particles. The CHIMERE model is a eulerian air quality model extensively used in air quality modelling. Metals have been recently included in this model in a special version developed in the CIEMAT (Madrid, Spain) modelling group. Vivanco et al. (2011) and González et al. (2012) showed the model performance for some metals in Spain and Europe. However, in these studies, metals were considered as fine particles. Some studies based on observed heavy metals air concentration indicate the presence of metals also in the coarse fraction, in special for Cu and Zn. For this reason, a new attempt of modelling metals considering a fine (Arsenic, Lead, Cadmium and Nickel Ambient Air Concentrations in Spain, 2011. Proceedings of the 11 th International Conference on Computational Science and Its Applications (ICCSA 11) 243-246 - González, Ma Vivanco, Marta; Palomino, Inmaculada; Garrido, Juan; Santiago, Manuel; Bessagnet, Bertrand Modelling Some Heavy Metals Air Concentration in Europe. // Water, Air & Soil Pollution;Sep2012, Vol. 223 Issue 8, p5227

  1. Ultra-fine metal gate operated graphene optical intensity modulator

    Science.gov (United States)

    Kou, Rai; Hori, Yosuke; Tsuchizawa, Tai; Warabi, Kaori; Kobayashi, Yuzuki; Harada, Yuichi; Hibino, Hiroki; Yamamoto, Tsuyoshi; Nakajima, Hirochika; Yamada, Koji

    2016-12-01

    A graphene based top-gate optical modulator on a standard silicon photonic platform is proposed for the future optical telecommunication networks. On the basis of the device simulation, we proposed that an electro-absorption light modulation can be realized by an ultra-narrow metal top-gate electrode (width less than 400 nm) directly located on the top of a silicon wire waveguide. The designed structure also provides excellent features such as carrier doping and waveguide-planarization free fabrication processes. In terms of the fabrication, we established transferring of a CVD-grown mono-layer graphene sheet onto a CMOS compatible silicon photonic sample followed by a 25-nm thick ALD-grown Al2O3 deposition and Source-Gate-Drain electrodes formation. In addition, a pair of low-loss spot-size converter for the input and output area is integrated for the efficient light source coupling. The maximum modulation depth of over 30% (1.2 dB) is observed at a device length of 50 μm, and a metal width of 300 nm. The influence of the initial Fermi energy obtained by experiment on the modulation performance is discussed with simulation results.

  2. Removal of metals from landfill leachate by sorption to activated carbon, bone meal and iron fines.

    Science.gov (United States)

    Modin, Hanna; Persson, Kenneth M; Andersson, Anna; van Praagh, Martijn

    2011-05-30

    Sorption filters based on granular activated carbon, bone meal and iron fines were tested for their efficiency of removing metals from landfill leachate. Removal of Al, As, Ca, Cd, Co, Cr, Cu, Fe, Hg, Mg, Mn, Mo, Ni, Pb, Sr and Zn were studied in a laboratory scale setup. Activated carbon removed more than 90% of Co, Cr, Cu, Fe, Mn and Ni. Ca, Pb, Sr and Zn were removed but less efficiently. Bone meal removed over 80% of Cr, Fe, Hg, Mn and Sr and 20-80% of Al, Ca, Cu, Mo, Ni, Pb and Zn. Iron fines removed most metals (As, Ca, Co, Cr, Cu, Fe, Mg, Mn, Pb, Sr and Zn) to some extent but less efficiently. All materials released unwanted substances (metals, TOC or nutrients), highlighting the need to study the uptake and release of a large number of compounds, not only the target metals. To remove a wide range of metals using these materials two or more filter materials may need to be combined. Sorption mechanisms for all materials include ion exchange, sorption and precipitation. For iron fines oxidation of Fe(0) seems to be important for metal immobilisation. Copyright © 2011 Elsevier B.V. All rights reserved.

  3. Fine-scale spatial distribution of plants and resources on a sandy soil in the Sahel

    NARCIS (Netherlands)

    Rietkerk, M.G.; Ouedraogo, T.; Kumar, L.; Sanou, S.; Langevelde, F. van; Kiema, A.; Koppel, J. van de; Andel, J. van; Hearne, J.; Skidmore, A.K.; Ridder, N. de; Stroosnijder, L.; Prins, H.H.T.

    2002-01-01

    We studied fine-scale spatial plant distribution in relation to the spatial distribution of erodible soil particles, organic matter, nutrients and soil water on a sandy to sandy loam soil in the Sahel. We hypothesized that the distribution of annual plants would be highly spatially autocorrelated

  4. Studies of helium distribution in metal tritides

    International Nuclear Information System (INIS)

    Bowman, R.C. Jr.; Attalla, A.

    1976-01-01

    The distribution of helium ( 3 He) in LiT, TiT 2 , and UT 3 , which are regarded as representative metal tritides, was investigated using pulse nuclear magnetic resonance (NMR) techniques. Analyses of the NMR lineshapes and nuclear relaxation times indicate the 3 He atoms are trapped in microscopic gas bubbles for each tritide. The effects of concentration and temperature on the 3 He distributions were investigated as well

  5. Coarse and fine root plants affect pore size distributions differently

    OpenAIRE

    Bodner, G.; Leitner, D.; Kaul, H.-P.

    2014-01-01

    Aims Small scale root-pore interactions require validation of their impact on effective hydraulic processes at the field scale. Our objective was to develop an interpretative framework linking root effects on macroscopic pore parameters with knowledge at the rhizosphere scale. Methods A field experiment with twelve species from different families was conducted. Parameters of Kosugi?s pore size distribution (PSD) model were determined inversely from tension infiltrometer data. Measured root tr...

  6. The heavy metal partition in size-fractions of the fine particles in agricultural soils contaminated by waste water and smelter dust

    International Nuclear Information System (INIS)

    Zhang, Haibo; Luo, Yongming; Makino, Tomoyuki; Wu, Longhua; Nanzyo, Masami

    2013-01-01

    Highlights: ► A continuous flow ultra-centrifugation method has been developed to obtain fine particles from polluted agricultural soil. ► Pollution source affected the heavy metal fractionation in size-fractions by changing soil particle properties. ► The iron oxides affected the distribution of lead species more than other metals in the smelter dust polluted particles. -- Abstract: The partitioning of pollutant in the size-fractions of fine particles is particularly important to its migration and bioavailability in soil environment. However, the impact of pollution sources on the partitioning was seldom addressed in the previous studies. In this study, the method of continuous flow ultra-centrifugation was developed to separate three size fractions (<1 μm, <0.6 μm and <0.2 μm) of the submicron particles from the soil polluted by wastewater and smelter dust respectively. The mineralogy and physicochemical properties of each size-fraction were characterized by X-ray diffraction, transmission electron microscope etc. Total content of the polluted metals and their chemical speciation were measured. A higher enrichment factor of the metals in the fractions of <1 μm or less were observed in the soil contaminated by wastewater than by smelter dust. The organic substance in the wastewater and calcite from lime application were assumed to play an important role in the metal accumulation in the fine particles of the wastewater polluted soil. While the metal accumulation in the fine particles of the smelter dust polluted soil is mainly associated with Mn oxides. Cadmium speciation in both soils is dominated by dilute acid soluble form and lead speciation in the smelter dust polluted soil is dominated by reducible form in all particles. This implied that the polluted soils might be a high risk to human health and ecosystem due to the high bioaccessblity of the metals as well as the mobility of the fine particles in soil

  7. The heavy metal partition in size-fractions of the fine particles in agricultural soils contaminated by waste water and smelter dust

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Haibo, E-mail: hbzhang@yic.ac.cn [Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003 (China); Luo, Yongming, E-mail: ymluo@yic.ac.cn [Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003 (China); Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008 (China); Makino, Tomoyuki [National Institute for Agro-Environmental Sciences, Tsukuba 3058604 (Japan); Wu, Longhua [Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008 (China); Nanzyo, Masami [Tohoku University, Sendai 9808576 (Japan)

    2013-03-15

    Highlights: ► A continuous flow ultra-centrifugation method has been developed to obtain fine particles from polluted agricultural soil. ► Pollution source affected the heavy metal fractionation in size-fractions by changing soil particle properties. ► The iron oxides affected the distribution of lead species more than other metals in the smelter dust polluted particles. -- Abstract: The partitioning of pollutant in the size-fractions of fine particles is particularly important to its migration and bioavailability in soil environment. However, the impact of pollution sources on the partitioning was seldom addressed in the previous studies. In this study, the method of continuous flow ultra-centrifugation was developed to separate three size fractions (<1 μm, <0.6 μm and <0.2 μm) of the submicron particles from the soil polluted by wastewater and smelter dust respectively. The mineralogy and physicochemical properties of each size-fraction were characterized by X-ray diffraction, transmission electron microscope etc. Total content of the polluted metals and their chemical speciation were measured. A higher enrichment factor of the metals in the fractions of <1 μm or less were observed in the soil contaminated by wastewater than by smelter dust. The organic substance in the wastewater and calcite from lime application were assumed to play an important role in the metal accumulation in the fine particles of the wastewater polluted soil. While the metal accumulation in the fine particles of the smelter dust polluted soil is mainly associated with Mn oxides. Cadmium speciation in both soils is dominated by dilute acid soluble form and lead speciation in the smelter dust polluted soil is dominated by reducible form in all particles. This implied that the polluted soils might be a high risk to human health and ecosystem due to the high bioaccessblity of the metals as well as the mobility of the fine particles in soil.

  8. Heavy metals in recovered fines from construction and demolition debris recycling facilities in Florida.

    Science.gov (United States)

    Townsend, Timothy; Tolaymat, Thabet; Leo, Kevin; Jambeck, Jenna

    2004-10-01

    A major product recovered from the processing and recycling of construction and demolition (C&D) debris is screened soil, also referred to as fines. A proposed reuse option for C&D debris fines is fill material, typically in construction projects as a substitute for natural soil. Waste material that is reused in a manner similar to soil must first be characterized to examine potential risks to human health and the environment. In Florida, samples of C&D debris fines from 13 C&D debris recycling facilities were characterized for 11 total and leachable heavy metal concentrations. Total metal concentration results (mg/kg) were compared to existing data on background Florida soil concentrations and to Florida's risk-based soil cleanup target levels (SCTLs). All of the detected metals were found to be elevated with respect to background. The 95% upper confidence level of arsenic from 99 samples was 3.2 mg/kg; arsenic presented the greatest limitation to reuse when compared to the SCTLs. Lead was not found to pose a major problem, likely because of the relatively new building infrastructure in Florida, which results in less demolition debris and less material impacted by lead-based paint. The results of batch leaching tests conducted using simulated rainwater (mg/l) were compared directly to risk-based groundwater levels for Florida and were found not to pose a risk using existing risk assessment policies.

  9. Heavy metals in recovered fines from construction and demolition debris recycling facilities in Florida

    International Nuclear Information System (INIS)

    Townsend, Timothy; Tolaymat, Thabet; Leo, Kevin; Jambeck, Jenna

    2004-01-01

    A major product recovered from the processing and recycling of construction and demolition (C and D) debris is screened soil, also referred to as fines. A proposed reuse option for C and D debris fines is fill material, typically in construction projects as a substitute for natural soil. Waste material that is reused in a manner similar to soil must first be characterized to examine potential risks to human health and the environment. In Florida, samples of C and D debris fines from 13 C and D debris recycling facilities were characterized for 11 total and leachable heavy metal concentrations. Total metal concentration results (mg/kg) were compared to existing data on background Florida soil concentrations and to Florida's risk-based soil cleanup target levels (SCTLs). All of the detected metals were found to be elevated with respect to background. The 95% upper confidence level of arsenic from 99 samples was 3.2 mg/kg; arsenic presented the greatest limitation to reuse when compared to the SCTLs. Lead was not found to pose a major problem, likely because of the relatively new building infrastructure in Florida, which results in less demolition debris and less material impacted by lead-based paint. The results of batch leaching tests conducted using simulated rainwater (mg/l) were compared directly to risk-based groundwater levels for Florida and were found not to pose a risk using existing risk assessment policies

  10. Sediment studies at Bikini Atoll part 1. distribution of fine and coarse components in surface sediments

    International Nuclear Information System (INIS)

    Noshkin, V. E.; Eagle, R.J.; Robison, W.L.

    1997-01-01

    In 1979, 21 years after the moratorium on nuclear testing in the Marshall Islands, surface sediment samples (to depths of 2 and 4 cm) were collected from 87 locations over the floor of Bikini lagoon. The main purpose for the collections was to map the distribution of long- lived man-made radionuclides associated with the bottom material. In addition the samples were processed to estimate the fraction of fine and coarse components to show what modifications occurred since the sediment composition was first described in samples collected before testing in 1946. In this report a comparison is made of the amount and distribution of fine material associated with the lagoon surface sediment before and after the testing of nuclear devices. Nuclear testing produced more finely divided material in-the surface sediment layer over large areas of the lagoon and especially in regions of the lagoon and reef adjacent to test sites. Five cratering events at Bikini Atoll generated sufficient material to account for the inventory of new fine material found over the bottom surface of the lagoon. Although the fraction of fine material in the bottom sediments was altered by the nuclear events, the combined processes of formation, transport and deposition were not sufficiently dynamic to alter the geographical features of the major sedimentary components over most of the lagoon floor

  11. Sediment studies at Bikini Atoll part 1. distribution of fine and coarse components in surface sediments

    Energy Technology Data Exchange (ETDEWEB)

    Noshkin, V. E.; Eagle, R.J.; Robison, W.L.

    1997-01-01

    In 1979, 21 years after the moratorium on nuclear testing in the Marshall Islands, surface sediment samples (to depths of 2 and 4 cm) were collected from 87 locations over the floor of Bikini lagoon. The main purpose for the collections was to map the distribution of long- lived man-made radionuclides associated with the bottom material. In addition the samples were processed to estimate the fraction of fine and coarse components to show what modifications occurred since the sediment composition was first described in samples collected before testing in 1946. In this report a comparison is made of the amount and distribution of fine material associated with the lagoon surface sediment before and after the testing of nuclear devices. Nuclear testing produced more finely divided material in-the surface sediment layer over large areas of the lagoon and especially in regions of the lagoon and reef adjacent to test sites. Five cratering events at Bikini Atoll generated sufficient material to account for the inventory of new fine material found over the bottom surface of the lagoon. Although the fraction of fine material in the bottom sediments was altered by the nuclear events, the combined processes of formation, transport and deposition were not sufficiently dynamic to alter the geographical features of the major sedimentary components over most of the lagoon floor.

  12. Particulate trace metals in Cochin backwaters: Distribution of seasonal indices

    Digital Repository Service at National Institute of Oceanography (India)

    Sankaranarayanan, V.N.; Jayalakshmy, K.V.; Joseph, T.

    that surface distribution pattern of the trace metal concentration of cobalt, nickel and iron was almost similar at the four stations thereby stressing the fact that seasonal fluctuations contributed a major part in the surface distribution of these metals...

  13. PM2.5-bound metal metabolic distribution and coupled lipid abnormality at different developmental windows.

    Science.gov (United States)

    Ku, Tingting; Zhang, Yingying; Ji, Xiaotong; Li, Guangke; Sang, Nan

    2017-09-01

    Atmospheric fine particulate matter (PM 2.5 ) is a serious threat to human health. As a toxicant constituent, metal leads to significant health risks in a population, but exposure to PM 2.5 -bound metals and their biological impacts are not fully understood. In this study, we determined the metal contents of PM 2.5 samples collected from a typical coal-burning city and then investigated the metabolic distributions of six metals (Zn, Pb, Mn, As, Cu, and Cd) following PM 2.5 inhalation in mice in different developmental windows. The results indicate that fine particles were mainly deposited in the lung, but PM 2.5 -bound metals could reach and gather in secondary off-target tissues (the lung, liver, heart and brain) with a developmental window-dependent property. Furthermore, elevations in triglycerides and cholesterol levels in sensitive developmental windows (the young and elderly stages) occurred, and significant associations between metals (Pb, Mn, As and Cd) and cholesterol in the heart, brain, liver and lung were observed. These findings suggest that PM 2.5 inhalation caused selective metal metabolic distribution in tissues with a developmental window-dependent property and that the effects were associated with lipid alterations. This provides a foundation for the underlying systemic toxicity following PM 2.5 exposure based on metal components. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. Enhancement of room-temperature plasticity in a bulk metallic glass by finely dispersed porosity

    International Nuclear Information System (INIS)

    Wada, Takeshi; Inoue, Akihisa; Greer, Alan Lindsay

    2005-01-01

    Melts of Pd 42.5 Cu 30 Ni 7.5 P 20 (at. %) held under pressurized hydrogen are cast into bulk metallic glass (BMG) rods with fine (20-30 μm diameter) pores uniformly dispersed. The low overall porosities ( -3 , compared to 16 MJ m -3 for the pore-free BMG. The pores force the proliferation of shear bands below the overall failure stress, a process of interest for toughening BMGs, materials for which shear localization in deformation restricts structural applications

  15. A Modelling Approach on Fine Particle Spatial Distribution for Street Canyons in Asian Residential Community

    Science.gov (United States)

    Ling, Hong; Lung, Shih-Chun Candice; Uhrner, Ulrich

    2016-04-01

    Rapidly increasing urban pollution poses severe health risks.Especially fine particles pollution is considered to be closely related to respiratory and cardiovascular disease. In this work, ambient fine particles are studied in street canyons of a typical Asian residential community using a computational fluid dynamics (CFD) dispersion modelling approach. The community is characterised by an artery road with a busy traffic flow of about 4000 light vehicles (mainly cars and motorcycles) per hour at rush hours, three streets with hundreds light vehicles per hour at rush hours and several small lanes with less traffic. The objective is to study the spatial distribution of the ambient fine particle concentrations within micro-environments, in order to assess fine particle exposure of the people living in the community. The GRAL modelling system is used to simulate and assess the emission and dispersion of the traffic-related fine particles within the community. Traffic emission factors and traffic situation is assigned using both field observation and local emissions inventory data. High resolution digital elevation data (DEM) and building height data are used to resolve the topographical features. Air quality monitoring and mobile monitoring within the community is used to validate the simulation results. By using this modelling approach, the dispersion of fine particles in street canyons is simulated; the impact of wind condition and street orientation are investigated; the contributions of car and motorcycle emissions are quantified respectively; the residents' exposure level of fine particles is assessed. The study is funded by "Taiwan Megacity Environmental Research (II)-chemistry and environmental impacts of boundary layer aerosols (Year 2-3) (103-2111-M-001-001-); Spatial variability and organic markers of aerosols (Year 3)(104-2111-M-001 -005 -)"

  16. Metal Distribution and Mobility under alkaline conditions

    International Nuclear Information System (INIS)

    Dario, Maarten

    2004-01-01

    The adsorption of an element, expressed as its distribution between liquid (aquatic) and solid phases in the bio geosphere, largely determines its mobility and transport properties. This is of fundamental importance in the assessment of the performance of e.g. geologic repositories for hazardous elements like radionuclides. Geologic repositories for low and intermediate level nuclear waste will most likely be based on concrete constructions in a suitable bedrock, leading to a local chemical environment with pH well above 12. At this pH metal adsorption is very high, and thus the mobility is hindered. Organic complexing agents, such as natural humic matter from the ground and in the groundwater, as well as components in the waste (cleaning agents, degradation products from ion exchange resins and cellulose, cement additives etc.) would affect the sorption properties of the various elements in the waste. Trace element migration from a cementitious repository through the pH- and salinity gradient created around the repository would be affected by the presence and creation of particulate matter (colloids) that may serve as carriers that enhance the mobility. The objective of this thesis was to describe and quantify the sorption of some selected elements representative of spent nuclear fuel (Eu, Am) and other heavy metals (Zn, Cd, Hg) in a clay/cement environment (pH 10-13) and in the pH-gradient outside this environment. The potential of organic complexing agents and colloids to enhance metal migration was also investigated. It was shown that many organic ligands are able to reduce trace metal sorption under these conditions. It was not possible to calculate the effect of well-defined organic ligands on the metal sorption in a cement environment by using stability constants from the literature. A simple method for comparing the effect of different complexing agents on metal sorption is, however, suggested. The stability in terms of the particle size of suspended

  17. Metal composition of fine particulate air pollution and acute changes in cardiorespiratory physiology

    International Nuclear Information System (INIS)

    Cakmak, Sabit; Dales, Robert; Kauri, Lisa Marie; Mahmud, Mamun; Van Ryswyk, Keith; Vanos, Jennifer; Liu, Ling; Kumarathasan, Premkumari; Thomson, Errol; Vincent, Renaud; Weichenthal, Scott

    2014-01-01

    Background: Studying the physiologic effects of components of fine particulate mass (PM 2.5 ) could contribute to a better understanding of the nature of toxicity of air pollution. Objectives: We examined the relation between acute changes in cardiovascular and respiratory function, and PM 2.5 -associated-metals. Methods: Using generalized linear mixed models, daily changes in ambient PM 2.5 -associated metals were compared to daily changes in physiologic measures in 59 healthy subjects who spent 5-days near a steel plant and 5-days on a college campus. Results: Interquartile increases in calcium, cadmium, lead, strontium, tin, vanadium and zinc were associated with statistically significant increases in heart rate of 1–3 beats per minute, increases of 1–3 mmHg in blood pressure and/or lung function decreases of up to 4% for total lung capacity. Conclusion: Metals contained in PM 2.5 were found to be associated with acute changes in cardiovascular and respiratory physiology. - Highlights: • We measured daily lung function, heart rate and blood pressure in 61 subjects. • Study sites were adjacent to a steel plant and on a college campus. • PM 2.5 -associated metal concentrations were measured daily at each site. • On days of higher metal concentrations, physiologic variables slightly deteriorated. • Some metal components may contribute to the toxicity of PM 2.5 . - Several PM 2.5 metals were associated with acute changes in cardiovascular or respiratory physiology. Given the evidence of source specificity, our study provides novel information

  18. Predictive Modelling to Identify Near-Shore, Fine-Scale Seabird Distributions during the Breeding Season.

    Science.gov (United States)

    Warwick-Evans, Victoria C; Atkinson, Philip W; Robinson, Leonie A; Green, Jonathan A

    2016-01-01

    During the breeding season seabirds are constrained to coastal areas and are restricted in their movements, spending much of their time in near-shore waters either loafing or foraging. However, in using these areas they may be threatened by anthropogenic activities such as fishing, watersports and coastal developments including marine renewable energy installations. Although many studies describe large scale interactions between seabirds and the environment, the drivers behind near-shore, fine-scale distributions are not well understood. For example, Alderney is an important breeding ground for many species of seabird and has a diversity of human uses of the marine environment, thus providing an ideal location to investigate the near-shore fine-scale interactions between seabirds and the environment. We used vantage point observations of seabird distribution, collected during the 2013 breeding season in order to identify and quantify some of the environmental variables affecting the near-shore, fine-scale distribution of seabirds in Alderney's coastal waters. We validate the models with observation data collected in 2014 and show that water depth, distance to the intertidal zone, and distance to the nearest seabird nest are key predictors in the distribution of Alderney's seabirds. AUC values for each species suggest that these models perform well, although the model for shags performed better than those for auks and gulls. While further unexplained underlying localised variation in the environmental conditions will undoubtedly effect the fine-scale distribution of seabirds in near-shore waters we demonstrate the potential of this approach in marine planning and decision making.

  19. Predictive Modelling to Identify Near-Shore, Fine-Scale Seabird Distributions during the Breeding Season.

    Directory of Open Access Journals (Sweden)

    Victoria C Warwick-Evans

    Full Text Available During the breeding season seabirds are constrained to coastal areas and are restricted in their movements, spending much of their time in near-shore waters either loafing or foraging. However, in using these areas they may be threatened by anthropogenic activities such as fishing, watersports and coastal developments including marine renewable energy installations. Although many studies describe large scale interactions between seabirds and the environment, the drivers behind near-shore, fine-scale distributions are not well understood. For example, Alderney is an important breeding ground for many species of seabird and has a diversity of human uses of the marine environment, thus providing an ideal location to investigate the near-shore fine-scale interactions between seabirds and the environment. We used vantage point observations of seabird distribution, collected during the 2013 breeding season in order to identify and quantify some of the environmental variables affecting the near-shore, fine-scale distribution of seabirds in Alderney's coastal waters. We validate the models with observation data collected in 2014 and show that water depth, distance to the intertidal zone, and distance to the nearest seabird nest are key predictors in the distribution of Alderney's seabirds. AUC values for each species suggest that these models perform well, although the model for shags performed better than those for auks and gulls. While further unexplained underlying localised variation in the environmental conditions will undoubtedly effect the fine-scale distribution of seabirds in near-shore waters we demonstrate the potential of this approach in marine planning and decision making.

  20. Particle size distribution and property of bacteria attached to carbon fines in drinking water treatment

    Directory of Open Access Journals (Sweden)

    Wang Leilei

    2008-06-01

    Full Text Available The quantitative change and size distribution of particles in the effluents from a sand filter and a granular activated carbon (GAC filter in a drinking water treatment plant were investigated. The average total concentration of particles in the sand filter effluent during a filter cycle was 148 particles/mL, 27 of which were larger than 2 µm in size. The concentration in the GAC effluent (561 particles/mL was significantly greater than that in the sand filter effluent. The concentration of particles larger than 2 µm in the GAC filter effluent reached 201 particles/mL, with the amount of particles with sizes between 2 µm and 15 µm increasing. The most probable number (MPN of carbon fines reached 43 unit/L after six hours and fines between 0.45 µm and 8.0 µm accounted for more than 50%. The total concentration of outflowing bacteria in the GAC filter effluent, 350 CFU (colony-forming units/mL, was greater than that in the sand filter effluent, 210 CFU/mL. The desorbed bacteria concentration reached an average of 310 CFU/mg fines. The disinfection efficiency of desorbed bacteria was lower than 40% with 1.5 mg/L of chlorine. The disinfection effect showed that the inactivation rate with 2.0 mg/L of chloramine (90% was higher than that with chlorine (70%. Experimental results indicated that the high particle concentration in raw water and sedimentation effluent led to high levels of outflowing particles in the sand filter effluent. The activated carbon fines in the effluent accounted for a small proportion of the total particle amount, but the existing bacteria attached to carbon fines may influence the drinking water safety. The disinfection efficiency of desorbed bacteria was lower than that of free bacteria with chlorine, and the disinfection effect on bacteria attached to carbon fines with chloramine was better than that with only chlorine.

  1. Briquetting of coal fines and sawdust - effect of particle-size distribution

    Energy Technology Data Exchange (ETDEWEB)

    Patil, D.P.; Taulbee, D.; Parekh, B.K.; Honaker, R. [University of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

    2009-07-01

    The coal industry usually discards fine-size (-150 microns) coal because of its high-moisture content and handling problems. One avenue for utilization is to either pelletize or briquette this material. However, industry has not adopted this route due in large part to significant drying and binder costs. In an effort to reduce these costs, compacting and briquetting studies were conducted to determine the effect of combining a coarse (1.18x0.15mm) spiral separator product with a fine coal flotation product (-150microns), with and without adding sawdust. Maximizing the packing density of the coal and wood waste mixture could potentially reduce the binder requirement by minimizing the void space as well as reducing shipping costs. Accordingly, work reported here focused on evaluating the impact of the particle-size distribution of different blends of fine and coarse coal, with and without sawdust and/or binder. The modified Proctor density of compacted blends along with the porosity and compressive strengths of briquettes made from each blend were determined. For the coal-only blends, the packing density was maximized by a relatively high (70% to 80%) coarse coal content. However, the packing density did not correlate with the compressive strength of the briquette that instead maximized with 100% fine flotation coal and continuously decreased as higher proportions of coarse coal were added. Similar compaction and compressive-strength results were obtained with mixtures of sawdust and varying proportions of coarse and fine coal. With the addition of a binder, the highest strengths were no longer obtained with 100% fine coal but instead maximized between 20% and 50% coarse coal addition depending on how long the briquettes were cured.

  2. Size distribution of chemical elements and their source apportionment in ambient coarse, fine, and ultrafine particles in Shanghai urban summer atmosphere.

    Science.gov (United States)

    Lü, Senlin; Zhang, Rui; Yao, Zhenkun; Yi, Fei; Ren, Jingjing; Wu, Minghong; Feng, Man; Wang, Qingyue

    2012-01-01

    Ambient coarse particles (diameter 1.8-10 microm), fine particles (diameter 0.1-1.8 microm), and ultrafine particles (diameter Source apportionment of the chemical elements was analyzed by means of an enrichment factor method. Our results showed that the average mass concentrations of coarse particles, fine particles and ultrafine particles in the summer air were 9.38 +/- 2.18, 8.82 +/- 3.52, and 2.02 +/- 0.41 microg/m3, respectively. The mass percentage of the fine particles accounted for 51.47% in the total mass of PM10, indicating that fine particles are the major component in the Shanghai ambient particles. SEM/EDX results showed that the coarse particles were dominated by minerals, fine particles by soot aggregates and fly ashes, and ultrafine particles by soot particles and unidentified particles. SRXRF results demonstrated that crustal elements were mainly distributed in the coarse particles, while heavy metals were in higher proportions in the fine particles. Source apportionment revealed that Si, K, Ca, Fe, Mn, Rb, and Sr were from crustal sources, and S, Cl, Cu, Zn, As, Se, Br, and Pb from anthropogenic sources. Levels of P, V, Cr, and Ni in particles might be contributed from multi-sources, and need further investigation.

  3. Nonparametric Fine Tuning of Mixtures: Application to Non-Life Insurance Claims Distribution Estimation

    Science.gov (United States)

    Sardet, Laure; Patilea, Valentin

    When pricing a specific insurance premium, actuary needs to evaluate the claims cost distribution for the warranty. Traditional actuarial methods use parametric specifications to model claims distribution, like lognormal, Weibull and Pareto laws. Mixtures of such distributions allow to improve the flexibility of the parametric approach and seem to be quite well-adapted to capture the skewness, the long tails as well as the unobserved heterogeneity among the claims. In this paper, instead of looking for a finely tuned mixture with many components, we choose a parsimonious mixture modeling, typically a two or three-component mixture. Next, we use the mixture cumulative distribution function (CDF) to transform data into the unit interval where we apply a beta-kernel smoothing procedure. A bandwidth rule adapted to our methodology is proposed. Finally, the beta-kernel density estimate is back-transformed to recover an estimate of the original claims density. The beta-kernel smoothing provides an automatic fine-tuning of the parsimonious mixture and thus avoids inference in more complex mixture models with many parameters. We investigate the empirical performance of the new method in the estimation of the quantiles with simulated nonnegative data and the quantiles of the individual claims distribution in a non-life insurance application.

  4. Fine Metal Mask 3-Dimensional Measurement by using Scanning Digital Holographic Microscope

    Science.gov (United States)

    Shin, Sanghoon; Yu, Younghun

    2018-04-01

    For three-dimensional microscopy, fast and high axial resolution are very important. Extending the depth of field for digital holographic is necessary for three-dimensional measurements of thick samples. We propose an optical sectioning method for optical scanning digital holography that is performed in the frequency domain by spatial filtering of a reconstructed amplitude image. We established a scanning dual-wavelength off-axis digital holographic microscope to measure samples that exhibit a large amount of coherent noise and a thickness larger than the depth of focus of the objective lens. As a demonstration, we performed a three-dimensional measurement of a fine metal mask with a reconstructed sectional phase image and filtering with a reconstructed amplitude image.

  5. DNA analysis of soil extracts can be used to investigate fine root depth distribution of trees

    Science.gov (United States)

    Bithell, Sean L.; Tran-Nguyen, Lucy T. T.; Hearnden, Mark N.; Hartley, Diana M.

    2015-01-01

    Understanding the root distribution of trees by soil coring is time-consuming as it requires the separation of roots from soil and classification of roots into particular size classes. This labour-intensive process can limit sample throughput and therefore sampling intensity. We investigated the use of quantitative polymerase chain reaction (qPCR) on soil DNA extractions to determine live fine root DNA density (RDD, mg DNA m−2) for mango (Mangifera indica) trees. The specificity of the qPCR was tested against DNA extracted from 10 mango cultivars and 14 weed species. All mango cultivars and no weeds were detected. Mango DNA was successfully quantified from control soil spiked with mango roots and weed species. The DNA yield of mango root sections stored in moist soil at 23–28 °C declined after 15 days to low concentrations as roots decayed, indicating that dead root materials in moist soil would not cause false-positive results. To separate large roots from samples, a root separation method for field samples was used to target the root fragments remaining in sieved (minimum 2 mm aperture) soil for RDD comparisons. Using this method we compared the seasonal RDD values of fine roots for five mango rootstock cultivars in a field trial. The mean cultivar DNA yields by depth from root fragments in the sieved soil samples had the strongest relationship (adjusted multiple R2 = 0.9307, P < 0.001) with the dry matter (g m−2) of fine (diameter <0.64 mm) roots removed from the soil by sieving. This method provides a species-specific and rapid means of comparing the distribution and concentration of live fine roots of trees in orchards using soil samples up to 500 g. PMID:25552675

  6. Fine-Scale Spatial Heterogeneity in the Distribution of Waterborne Protozoa in a Drinking Water Reservoir.

    Science.gov (United States)

    Burnet, Jean-Baptiste; Ogorzaly, Leslie; Penny, Christian; Cauchie, Henry-Michel

    2015-09-23

    The occurrence of faecal pathogens in drinking water resources constitutes a threat to the supply of safe drinking water, even in industrialized nations. To efficiently assess and monitor the risk posed by these pathogens, sampling deserves careful design, based on preliminary knowledge on their distribution dynamics in water. For the protozoan pathogens Cryptosporidium and Giardia, only little is known about their spatial distribution within drinking water supplies, especially at fine scale. Two-dimensional distribution maps were generated by sampling cross-sections at meter resolution in two different zones of a drinking water reservoir. Samples were analysed for protozoan pathogens as well as for E. coli, turbidity and physico-chemical parameters. Parasites displayed heterogeneous distribution patterns, as reflected by significant (oo)cyst density gradients along reservoir depth. Spatial correlations between parasites and E. coli were observed near the reservoir inlet but were absent in the downstream lacustrine zone. Measurements of surface and subsurface flow velocities suggest a role of local hydrodynamics on these spatial patterns. This fine-scale spatial study emphasizes the importance of sampling design (site, depth and position on the reservoir) for the acquisition of representative parasite data and for optimization of microbial risk assessment and monitoring. Such spatial information should prove useful to the modelling of pathogen transport dynamics in drinking water supplies.

  7. Using Moss to Detect Fine-Scaled Deposition of Heavy Metals in Urban Environments

    Science.gov (United States)

    Jovan, S.; Donovan, G.; Demetrios, G.; Monleon, V. J.; Amacher, M. C.

    2017-12-01

    Mosses are commonly used as bio-indicators of heavy metal deposition to forests. Their application in urban airsheds is relatively rare. Our objective was to develop fine-scaled, city-wide maps for heavy metals in Portland, Oregon, to identify pollution "hotspots" and serve as a screening tool for more effective placement of air quality monitoring instruments. In 2013 we measured twenty-two elements in epiphytic moss sampled on a 1km x1km sampling grid (n = 346). We detected large hotspots of cadmium and arsenic in two neighborhoods associated with stained glass manufacturers. Air instruments deployed by local regulators measured cadmium concentrations 49 times and arsenic levels 155 times the state health benchmarks. Moss maps also detected a large nickel hotspot in a neighborhood near a forge where air instruments later measured concentrations 4 times the health benchmark. In response, the facilities implemented new pollution controls, air quality improved in all three affected neighborhoods, revision of regulations for stained glass furnace emissions are underway, and Oregon's governor launched an initiative to develop health-based (vs technology-based) regulations for air toxics in the state. The moss maps also indicated a couple dozen smaller hotspots of heavy metals, including lead, chromium, and cobalt, in Portland neighborhoods. Ongoing follow-up work includes: 1) use of moss sampling by local regulators to investigate source and extent of the smaller hotspots, 2) use of lead isotopes to determine origins of higher lead levels observed in moss collected from the inner city, and 3) co-location of air instruments and moss sampling to determine accuracy, timeframe represented, and seasonality of heavy metals in moss.

  8. Nutrients and heavy metal distribution in thermally treated pig manure

    DEFF Research Database (Denmark)

    Kuligowski, Ksawery; Poulsen, Tjalfe G.; Stoholm, Peder

    2008-01-01

    Ash from pig manure treated by combustion and thermal gasification was characterized and compared in terms of nutrient, i.e., potassium (K), phosphorus (P) and heavy metal, i.e., cadmium (Cd), chromium (Cr), copper (Cu), nickel (Ni) and zinc (Zn) contents. Total nutrient and metal concentrations...... that ash from gasified manure contained more water-extractable K in comparison with combusted manure whereas the opposite was the case with respect to P. Heavy metals Ni, Cr and Cd were present in higher concentrations in the fine particle size fractions (

  9. Fine scale distribution constrains cadmium accumulation rates in two geographical groups of Franciscana dolphin from Argentina

    International Nuclear Information System (INIS)

    Polizzi, P.S.; Chiodi Boudet, L.N.; Romero, M.B.; Denuncio, P.E.; Rodríguez, D.H.

    2013-01-01

    Highlights: • Fine scale distribution of two Argentine stocks constrains the Cd accumulation rates. • Cadmium levels and accumulation patterns were different between geographic groups. • Marine diet has a major influence than the impact degree of origin environment. • Engraulis anchoita is the main Cd vector species in Argentine shelf for Franciscana. • Information is valuable for the conservation of Franciscana, a vulnerable species. -- Abstract: Franciscana dolphin is an endemic cetacean in the southwestern Atlantic Ocean and is classified as Vulnerable A3d by the International Union for Conservation of Nature. Cadmium accumulation was assessed in two geographic groups from Argentina; one inhabits the La Plata River estuary, a high anthropogenic impacted environment, and the other is distributed in marine coastal, with negligible pollution. Despite the environment, marine dolphins showed an increase of renal Cd concentrations since trophic independence; while in estuarine dolphins was from 6 years. This is associated with dietary Argentine anchovy which was absent in the diet of estuarine dolphins, being a trophic vector of cadmium in shelf waters of Argentina. Cluster analysis also showed high levels of cd in association with the presence of anchovy in the stomach. The difference in the fine scale distribution of species influences dietary exposure to Cd and, along with other data, indicates two stocks in Argentina

  10. Procedure for the conversion of a metal oxide powder to a fine grained ceramic material

    International Nuclear Information System (INIS)

    Ferrell, L.J.

    1978-01-01

    A procedure for sintering metal oxides is described which gives a product with significantly smaller grain size and better grain size distribution than previous processes. The procedure is presented as applied to aluminium oxide, but it is also stated to be applicable to uranium dioxide. A pellet density of within 1/2 percent of the theoretical maximum can be obtained. No grinding or surface treatment of the pellets is necessary. (JIW)

  11. Settling fluxes and ecotoxicological risk assessment of fine sedimentary metals in Tema Harbour (Ghana).

    Science.gov (United States)

    Botwe, Benjamin O; Nyarko, Elvis; Lens, Piet N L

    2018-01-01

    Sediment traps were deployed in the Tema Harbour to estimate the settling fluxes of silt-clay particles and associated metals (Fe, Mn, Pb, Cr, Cu, Zn, Ni, Hg, Sn and As) and characterise their potential ecotoxicological risks. The mean daily settling fluxes of the silt-clay particles and associated metals ranged from 42.7 to 85.0gm -2 d -1 and 1.3×10 -2 to 49.4mgm -2 d -1 , respectively, and were characterised by large fluctuations at each station. The silt-clay and metal fluxes strongly correlated, indicating the important role of the silt-clay particles in metal transport and distribution in the harbour. Geochemical indices indicated anthropogenic influences on the harbour as the Pb, Cr, Zn, Hg, Sn and As content in the settling silt-clay particles exceeded their average crustal concentrations. Sediment quality guidelines indicated these metals pose appreciable ecotoxicological risks, particularly As. Increasing temporal trends in As necessitates increased pollution control efforts at the harbour. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. Distribution and Potential Toxicity of Trace Metals in the Surface Sediments of Sundarban Mangrove Ecosystem, Bangladesh

    Science.gov (United States)

    Kumar, A.; Ramanathan, A.; Mathukumalli, B. K. P.; Datta, D. K.

    2014-12-01

    The distribution, enrichment and ecotoxocity potential of Bangladesh part of Sundarban mangrove was investigated for eight trace metals (As, Cd, Cr, Cu, Fe, Mn, Pb and Zn) using sediment quality assessment indices. The average concentration of trace metals in the sediments exceeded the crustal abundance suggesting sources other than natural in origin. Additionally, the trace metals profile may be a reflection of socio-economic development in the vicinity of Sundarban which further attributes trace metals abundance to the anthropogenic inputs. Geoaccumulation index suggests moderately polluted sediment quality w.r.t. Ni and As and background concentrations for Al, Fe, Mn, Cu, Zn, Pb, Co, As and Cd. Contamination factor analysis suggested low contamination by Zn, Cr, Co and Cd, moderate by Fe, Mn, Cu and Pb while Ni and As show considerable and high contamination, respectively. Enrichment factors for Ni, Pb and As suggests high contamination from either biota or anthropogenic inputs besides natural enrichment. As per the three sediment quality guidelines, Fe, Mn, Cu, Ni, Co and As would be more of a concern with respect to ecotoxicological risk in the Sundarban mangroves. The correlation between various physiochemical variables and trace metals suggested significant role of fine grained particles (clay) in trace metal distribution whereas owing to low organic carbon content in the region the organic complexation may not be playing significant role in trace metal distribution in the Sundarban mangroves.

  13. Environmental and health impacts of fine and ultrafine metallic particles: Assessment of threat scores

    Energy Technology Data Exchange (ETDEWEB)

    Goix, Sylvaine [Université de Toulouse, INP-ENSAT, Av. Agrobiopôle, 31326 Castanet-Tolosan (France); UMR 5245 CNRS-INP-UPS, EcoLab (Laboratoire d' écologie fonctionnelle), Avenue de l' Agrobiopôle, BP 32607, 31326 Castanet-Tolosan (France); Lévêque, Thibaut [Université de Toulouse, INP-ENSAT, Av. Agrobiopôle, 31326 Castanet-Tolosan (France); UMR 5245 CNRS-INP-UPS, EcoLab (Laboratoire d' écologie fonctionnelle), Avenue de l' Agrobiopôle, BP 32607, 31326 Castanet-Tolosan (France); ADEME (French Agency for Environment and Energy Management), 20 Avenue du Grésillé, BP 90406, 49004 Angers Cedex 01 (France); Xiong, Tian-Tian [Université de Toulouse, INP-ENSAT, Av. Agrobiopôle, 31326 Castanet-Tolosan (France); UMR 5245 CNRS-INP-UPS, EcoLab (Laboratoire d' écologie fonctionnelle), Avenue de l' Agrobiopôle, BP 32607, 31326 Castanet-Tolosan (France); Schreck, Eva [Géosciences Environnement Toulouse (GET), Observatoire Midi Pyrénées, Université de Toulouse, CNRS, IRD, 14 Avenue E. Belin, F-31400 Toulouse (France); and others

    2014-08-15

    This study proposes global threat scores to prioritize the harmfulness of anthropogenic fine and ultrafine metallic particles (FMP) emitted into the atmosphere at the global scale. (Eco)toxicity of physicochemically characterized FMP oxides for metals currently observed in the atmosphere (CdO, CuO, PbO, PbSO{sub 4}, Sb{sub 2}O{sub 3}, and ZnO) was assessed by performing complementary in vitro tests: ecotoxicity, human bioaccessibility, cytotoxicity, and oxidative potential. Using an innovative methodology based on the combination of (eco)toxicity and physicochemical results, the following hazard classification of the particles is proposed: CdCl{sub 2}∼CdO>CuO>PbO>ZnO>PbSO{sub 4}>Sb{sub 2}O{sub 3}. Both cadmium compounds exhibited the highest threat score due to their high cytotoxicity and bioaccessible dose, whatever their solubility and speciation, suggesting that cadmium toxicity is due to its chemical form rather than its physical form. In contrast, the Sb{sub 2}O{sub 3} threat score was the lowest due to particles with low specific area and solubility, with no effects except a slight oxidative stress. As FMP physicochemical properties reveal differences in specific area, crystallization systems, dissolution process, and speciation, various mechanisms may influence their biological impact. Finally, this newly developed and global approach could be widely used in various contexts of pollution by complex metal particles and may improve risk management. - Highlights: • Seven micro- and nano- monometallic characterized particles were studied as references. • Bioaccessibility, eco and cytotoxicity, and oxidative potential assays were performed. • According to calculated threat scores: CdCl{sub 2}∼CdO>CuO>PbO>ZnO>PbSO{sub 4}>Sb{sub 2}O{sub 3}.

  14. Peculiarities of the point radiation defects accumulation in the fine- and ultra-disperse metallic media

    International Nuclear Information System (INIS)

    Aliev, B.A.; Zajkin, Yu.A.; Potapov, A.S.

    2004-01-01

    Fine-dispersive powders are a samples of solid systems. In which under irradiation the particle surface layers defect structure changes and has mostly an effect on structural transformations. Theoretical calculations and experimental data show, that the increased interstitials atoms concentration near particles surface during irradiation by either electrons or gamma quanta with energy about 1 MeV give rise to intensive pores healing. At the same time as the dense surface layer formation the pores healing leads to the brachiate borders system formation. The borders serve as pathways for accelerated diffusion. Sintering process and a metal recrystallization are stimulating as well. Both processes lead to the ordered super-structure formation which contributes the additional contribution in an improvement of the mechanical properties of a metal. A liner sizes of the ordered net depend on both the powder sizes and the irradiation conditions. The especial interest present a conditions for such superstructure formation (when the particle sizes are becoming so small (∼1 μm), that effect has being resulted on a defect-formation in the whole volume of a powder particle). In the considered case the point radiation defects accumulation kinetics in the metallic particle is analyzed on the ground of the equation system for atomic concentrations both interstitial atoms and vacancies. The numerical solution of this equation system shows, that particles sizes decline leads to considerable micro-pores healing increase and improvement of conditions for net strengthening. In dependence on irradiation conditions (temperature, dose and dose rate) the forming super-structure could have micro- and nano-sizes

  15. Winter-time size distribution and source apportionment of total suspended particulate matter and associated metals in Delhi

    Science.gov (United States)

    Srivastava, Arun; Gupta, Sandeep; Jain, V. K.

    2009-03-01

    A study of the winter time size distribution and source apportionment of total suspended particulate matter (TSPM) and associated heavy metal concentrations have been carried out for the city of Delhi. This study is important from the point of view of implementation of compressed natural gas (CNG) as alternate of diesel fuel in the public transport system in 2001 to reduce the pollution level. TSPM were collected using a five-stage cascade impactor at six sites in the winters of 2005-06. The results of size distribution indicate that a major portion (~ 40%) of TSPM concentration is in the form of PM0.7 (heavy metals associated with various size fractions of TSPM. A very good correlation between coarse and fine size fraction of TSPM was observed. It was also observed that the metals associated with coarse particles have more chances of correlation with other metals; rather they are associated with fine particles. Source apportionment was carried out separately in coarse and fine size modes of TSPM by Chemical Mass Balance Receptor Model (CMB8) as well as by Principle Component Analysis (PCA) of SPSS. Source apportionment by PCA reveals that there are two major sources (possibly vehicular and crustal re-suspension) in both coarse and fine size fractions. Results obtained by CMB8 show the dominance of vehicular pollutants and crustal dust in fine and coarse size mode respectively. Noticeably the dominance of vehicular pollutants are now confined to fine size only whilst during pre CNG era it dominated both coarse and fine size mode. An increase of 42.5, 44.4, 48.2, 38.6 and 38.9% in the concentrations of TSPM, PM10.9, coarse particles, fine particles and lead respectively was observed during pre (2001) to post CNG (2005-06) period.

  16. Mercury speciation and fine particle size distribution on combustion of Chinese coals

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Lei; Wang, Shuxiao; Hao, Jiming [Tsinghua Univ., Beijing (China). Dept. of Environmental Science and Engineering and State Key Joint Lab. of Environment Simulation and Pollution Control; Daukoru, Michael; Torkamani, Sarah; Biswas, Pratim [Washington Univ., St. Louis, MO (United States). Aerosol and Air Quality Research Lab.

    2013-07-01

    Coal combustion is the dominant anthropogenic mercury emission source of the world. Electrostatic precipitator (ESP) can remove almost all the particulate mercury (Hg{sub p}), and wet flue gas desulfurization (WFGD) can retain a large part of the gaseous oxidized mercury (Hg{sup 2+}). Only a small percentage of gaseous elemental mercury (Hg{sup 0}) can be abated by the air pollution control devices (APCDs). Therefore, the mercury behavior across APCDs largely depends on the mercury speciation in the flue gas exhausting from the coal combustor. To better understand the formation process of three mercury species, i.e. Hg{sup 0}, Hg{sup 2+} and Hg{sub p}, in gaseous phase and fine particles, bench-scale measurements for the flue gas exhausting from combustion of different types of coal in a drop-tube furnace set-up, were carried out. It was observed that with the limitation of reaction kinetics, higher mercury concentration in flue gas will lead to lower Hg{sup 2+} proportion. The concentration of chlorine has the opposite effect, not as significantly as that of mercury though. With the chlorine concentration increasing, the proportion of Hg{sup 2+} increases. Combusting the finer coal powder results in the formation of more Hg{sup 2+}. Mineral composition of coal and coal particle size has a great impact on fine particle formation. Al in coal is in favor of finer particle formation, while Fe in coal can benefit the formation of larger particles. The coexistence of Al and Si can strengthen the particle coagulation process. This process can also be improved by the feeding of more or finer coal powder. The oxy-coal condition can make for both the mercury oxidation process and the metal oxidation in the fine particle formation process.

  17. Metals distribution in Kumkol deposit petroleum

    International Nuclear Information System (INIS)

    Musaeva, Z.G.; Nadirov, A.N.; Ajdarbaev, A.S.

    1997-01-01

    Metals content in samples of Kumkol deposit petroleum is determined by the method of X-ray diffraction and neutron activation analysis. Specific consideration was devoted to nickel and vanadium. It is possible, that sources of these metals are various petroleum formation as well as both the absorbed or the got in stratum microelements. (author)

  18. Characterization of Fine Metal Particles Derived from Shredded WEEE Using a Hyperspectral Image System: Preliminary Results

    Science.gov (United States)

    Candiani, Gabriele; Picone, Nicoletta; Pompilio, Loredana; Pepe, Monica; Colledani, Marcello

    2017-01-01

    Waste of electric and electronic equipment (WEEE) is the fastest-growing waste stream in Europe. The large amount of electric and electronic products introduced every year in the market makes WEEE disposal a relevant problem. On the other hand, the high abundance of key metals included in WEEE has increased the industrial interest in WEEE recycling. However, the high variability of materials used to produce electric and electronic equipment makes key metals’ recovery a complex task: the separation process requires flexible systems, which are not currently implemented in recycling plants. In this context, hyperspectral sensors and imaging systems represent a suitable technology to improve WEEE recycling rates and the quality of the output products. This work introduces the preliminary tests using a hyperspectral system, integrated in an automatic WEEE recycling pilot plant, for the characterization of mixtures of fine particles derived from WEEE shredding. Several combinations of classification algorithms and techniques for signal enhancement of reflectance spectra were implemented and compared. The methodology introduced in this study has shown characterization accuracies greater than 95%. PMID:28505070

  19. Number size distribution of fine and ultrafine fume particles from various welding processes.

    Science.gov (United States)

    Brand, Peter; Lenz, Klaus; Reisgen, Uwe; Kraus, Thomas

    2013-04-01

    Studies in the field of environmental epidemiology indicate that for the adverse effect of inhaled particles not only particle mass is crucial but also particle size is. Ultrafine particles with diameters below 100 nm are of special interest since these particles have high surface area to mass ratio and have properties which differ from those of larger particles. In this paper, particle size distributions of various welding and joining techniques were measured close to the welding process using a fast mobility particle sizer (FMPS). It turned out that welding processes with high mass emission rates (manual metal arc welding, metal active gas welding, metal inert gas welding, metal inert gas soldering, and laser welding) show mainly agglomerated particles with diameters above 100 nm and only few particles in the size range below 50 nm (10 to 15%). Welding processes with low mass emission rates (tungsten inert gas welding and resistance spot welding) emit predominantly ultrafine particles with diameters well below 100 nm. This finding can be explained by considerably faster agglomeration processes in welding processes with high mass emission rates. Although mass emission is low for tungsten inert gas welding and resistance spot welding, due to the low particle size of the fume, these processes cannot be labeled as toxicologically irrelevant and should be further investigated.

  20. Distribution of metals and extent of contamination in sediments from the south-eastern Baltic Sea (Lithuanian zone

    Directory of Open Access Journals (Sweden)

    Nijolė Remeikaitė-Nikienė

    2018-04-01

    Full Text Available Summary: The distribution of metals (Pb, Cu, Cd, Ni, Cr, Zn in surface sediments and the potential pollution sources in the south-eastern part (SE of the Baltic Sea (Lithuanian zone were investigated in relation to the environmental characteristics (amount of fine-grained particles, TOC content in sediments, origin of sedimentary organic matter, salinity, water depth in 2011–2014. The higher metal concentrations were measured in sediments of the Curonian Lagoon and in the open waters. An approach using various environmental indices (enrichment factor EF, geoaccumulation index Igeo and contamination factor CF was used to quantitatively assess a contamination degree. The principal component analysis (PCA was applied in order to further scrutinize pollution from metal sources. The values of the contamination indices showed no/very low sediment contamination with Ni and Cr, minor–moderate contamination with Cu, Zn and Pb and moderate–considerable pollution with Cd. The strong relationships among metals suggested their similar distribution pattern and a combination of natural and anthropogenic sources. The higher metal concentrations coincided with an increasing amount of fine-grained fraction and organic carbon. In the territorial waters, the distribution of elements was related to the water depth. In addition, the binding of metals with insoluble iron sulphides might explain their high concentrations at the most remote and deepest stations. Keywords: Metals, Enrichment factor, Geoaccumulation index, Contamination factor, The Baltic Sea, The Curonian Lagoon

  1. Changes in fine-root production, phenology and spatial distribution in response to N application in irrigated sweet cherry trees.

    Science.gov (United States)

    Artacho, Pamela; Bonomelli, Claudia

    2016-05-01

    Factors regulating fine-root growth are poorly understood, particularly in fruit tree species. In this context, the effects of N addition on the temporal and spatial distribution of fine-root growth and on the fine-root turnover were assessed in irrigated sweet cherry trees. The influence of other exogenous and endogenous factors was also examined. The rhizotron technique was used to measure the length-based fine-root growth in trees fertilized at two N rates (0 and 60 kg ha(-1)), and the above-ground growth, leaf net assimilation, and air and soil variables were simultaneously monitored. N fertilization exerted a basal effect throughout the season, changing the magnitude, temporal patterns and spatial distribution of fine-root production and mortality. Specifically, N addition enhanced the total fine-root production by increasing rates and extending the production period. On average, N-fertilized trees had a length-based production that was 110-180% higher than in control trees, depending on growing season. Mortality was proportional to production, but turnover rates were inconsistently affected. Root production and mortality was homogeneously distributed in the soil profile of N-fertilized trees while control trees had 70-80% of the total fine-root production and mortality concentrated below 50 cm depth. Root mortality rates were associated with soil temperature and water content. In contrast, root production rates were primarily under endogenous control, specifically through source-sink relationships, which in turn were affected by N supply through changes in leaf photosynthetic level. Therefore, exogenous and endogenous factors interacted to control the fine-root dynamics of irrigated sweet cherry trees. © The Author 2016. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

  2. HEAVY METALS IN RECOVERED FINES FOR CONSTRUCTION AND DEMOLITION DEBRIS RECYCLING FACILITIES IN FLORIDA

    Science.gov (United States)

    A major product recovered from the processing and recycling of construction and demolition (C&D) debris is screened soil, also referred to as fines. A proposed reuse option for C&D debris fines is fill material, typically in construction projects as a substitute for natural soil....

  3. Fine Structure of Tibetan Kefir Grains and Their Yeast Distribution, Diversity, and Shift

    Science.gov (United States)

    Lu, Man; Wang, Xingxing; Sun, Guowei; Qin, Bing; Xiao, Jinzhou; Yan, Shuling; Pan, Yingjie; Wang, Yongjie

    2014-01-01

    Tibetan kefir grains (TKGs), a kind of natural starter for fermented milk in Tibet, China, host various microorganisms of lactic acid bacteria, yeasts, and occasionally acetic acid bacteria in a polysaccharide/protein matrix. In the present study, the fine structure of TKGs was studied to shed light on this unusual symbiosis with stereomicroscopy and thin sections. The results reveal that TKGs consist of numerous small grain units, which are characterized by a hollow globular structure with a diameter between 2.0 and 9.0 mm and a wall thickness of approximately 200 µm. A polyhedron-like net structure, formed mainly by the bacteria, was observed in the wall of the grain units, which has not been reported previously to our knowledge. Towards the inside of the grain unit, the polyhedron-like net structures became gradually larger in diameter and fewer in number. Such fine structures may play a crucial role in the stability of the grains. Subsequently, the distribution, diversity, and shift of yeasts in TKGs were investigated based on thin section, scanning electron microscopy, cloning and sequencing of D1/D2 of the 26S rRNA gene, real-time quantitative PCR, and in situ hybridization with specific fluorescence-labeled oligonucleotide probes. These show that (i) yeasts appear to localize on the outer surface of the grains and grow normally together to form colonies embedded in the bacterial community; (ii) the diversity of yeasts is relatively low on genus level with three dominant species – Saccharomyces cerevisiae, Kluyveromyces marxianus, and Yarrowia lipolytica; (iii) S. cerevisiae is the stable predominant yeast species, while the composition of Kluyveromyces and Yarrowia are subject to change over time. Our results indicate that TKGs are relatively stable in structure, and culture conditions to some extent shape the microbial community and interaction in kefir grains. These findings pave the way for further study of the specific symbiotic associations between S

  4. Fine structure of Tibetan kefir grains and their yeast distribution, diversity, and shift.

    Directory of Open Access Journals (Sweden)

    Man Lu

    Full Text Available Tibetan kefir grains (TKGs, a kind of natural starter for fermented milk in Tibet, China, host various microorganisms of lactic acid bacteria, yeasts, and occasionally acetic acid bacteria in a polysaccharide/protein matrix. In the present study, the fine structure of TKGs was studied to shed light on this unusual symbiosis with stereomicroscopy and thin sections. The results reveal that TKGs consist of numerous small grain units, which are characterized by a hollow globular structure with a diameter between 2.0 and 9.0 mm and a wall thickness of approximately 200 µm. A polyhedron-like net structure, formed mainly by the bacteria, was observed in the wall of the grain units, which has not been reported previously to our knowledge. Towards the inside of the grain unit, the polyhedron-like net structures became gradually larger in diameter and fewer in number. Such fine structures may play a crucial role in the stability of the grains. Subsequently, the distribution, diversity, and shift of yeasts in TKGs were investigated based on thin section, scanning electron microscopy, cloning and sequencing of D1/D2 of the 26S rRNA gene, real-time quantitative PCR, and in situ hybridization with specific fluorescence-labeled oligonucleotide probes. These show that (i yeasts appear to localize on the outer surface of the grains and grow normally together to form colonies embedded in the bacterial community; (ii the diversity of yeasts is relatively low on genus level with three dominant species--Saccharomyces cerevisiae, Kluyveromyces marxianus, and Yarrowia lipolytica; (iii S. cerevisiae is the stable predominant yeast species, while the composition of Kluyveromyces and Yarrowia are subject to change over time. Our results indicate that TKGs are relatively stable in structure, and culture conditions to some extent shape the microbial community and interaction in kefir grains. These findings pave the way for further study of the specific symbiotic

  5. Concentrations and size distributions of fine aerosol particles measured at roof level in urban zone

    Science.gov (United States)

    Despiau, S.; Croci, D.

    2007-05-01

    During the experimental Field Experiments to Constrain Models of Atmospheric Pollution and Transport of Emissions (ESCOMPTE) campaign in June-July 2001, concentrations and size distributions of fine particles (14-722 nm) were measured at roof level in downtown Marseille (France). Part of the campaign was dedicated to the study of aerosol behavior in relation to strong photochemical events (which were identified as "IOP" days) and their regional modeling. The analysis of the concentration variations and the evolution of average diurnal size distribution showed that an "IOP day" is not characterized by a specific concentration or its variation, nor by a specific evolution of the average size distribution. The morning traffic rush is detected at roof level by a net increase in particle concentration over the whole size range measured, indicating a production of ultrafine particles by the traffic but also the raising to roof level of particles of the accumulation mode. The increase is observed about 1 hour after the traffic peak at street level, which is characterized by strong increases in NOx and CO concentrations. The corresponding flux of particles at roof level has been estimated around 3 × 104 cm-2 s-1. A specific signature characterized by a strong and rapid burst of concentration (factor 2 to 4 in 15 min) of particles between 25 and 50 nm, independent of the traffic source, has been detected on six occasions during the campaign. These events occur systematically around noon, in cases of strong radiation, low relative humidity, and common wind direction. Despite the high-diameter value of these particles, it is suggested that they could result from a specific "secondary aerosol process" event involving ozone, biogenic, and/or anthropogenic gas precursors like iodine and VOCs.

  6. Distribution of heavy metals in Tamshui mangrove forest ecosystem

    Energy Technology Data Exchange (ETDEWEB)

    Chiu, C Y; Chou, C H

    1990-06-01

    Tamsui estuary area is one of the few places in Taiwan where mangrove is still growing. Heavy metals, carried by the water of the Tamsui river, are accumulated in the estuary soil. Most heavy metals in soil, however, are immobile under reducing conditions and are fixed in the large amount of organic matter present. Heavy metals are distributed at different concentrations in various tissues of Kandelia candel as well as grasses of Phragmites communis, Imperata cylindrica, and Cyperus malaccensis growing in the swamp area. The concentration of heavy metals was significantly higher root than in stems and leaves. The absorption of heavy metals by the plants was less in soil that was frequently submerged. Kandelia candel seems to have no special tolerance to copper and zinc. The soil environment which favors reduced availability of heavy metals may help Kandelia candel adapt to growth in the polluted estuary.

  7. NOx, FINE PARTICLE AND TOXIC METAL EMISSIONS FROM THE COMBUSTION OF SEWAGE SLUDGE/COAL MIXTURES: A SYSTEMATIC ASSESSMENT

    Energy Technology Data Exchange (ETDEWEB)

    Jost O.L. Wendt

    2002-08-15

    This research project focuses on pollutants from the combustion of mixtures of dried municipal sewage sludge (MSS) and coal. The objective is to determine the relationship between (1) fraction sludge in the sludge/coal mixture, and (2) combustion conditions on (a) NOx concentrations in the exhaust, (b) the size segregated fine and ultra-fine particle composition in the exhaust, and (c) the partitioning of toxic metals between vapor and condenses phases, within the process. The proposed study will be conducted in concert with an existing ongoing research on toxic metal partitioning mechanisms for very well characterized pulverized coals alone. Both high NOx and low NOx combustion conditions will be investigated (unstaged and staged combustion). Tradeoffs between CO2 control, NOx control, and inorganic fine particle and toxic metal emissions will be determined. Previous research has yielded data on trace metal partitioning for MSS by itself, with natural gas assist, for coal plus MSS combustion together, and for coal alone. We have re-evaluated the inhalation health effects of ash aerosol from combustion of MSS both by itself and also together with coal. We have concluded that ash from the co-combustion of MSS and coal is very much worse from an inhalation health point of view, than ash from either MSS by itself or coal by itself. The reason is that ZnO is not the ''bad actor'' as had been suspected before, but the culprit is, rather, sulfated Zn. The MSS supplies the Zn and the coal supplies the sulfur, and so it is the combination of coal and MSS that makes that process environmentally bad. If MSS is to be burned, it should be burned without coal, in the absence of sulfur.

  8. Use of spatially distributed time-integrated sediment sampling networks and distributed fine sediment modelling to inform catchment management.

    Science.gov (United States)

    Perks, M T; Warburton, J; Bracken, L J; Reaney, S M; Emery, S B; Hirst, S

    2017-11-01

    Under the EU Water Framework Directive, suspended sediment is omitted from environmental quality standards and compliance targets. This omission is partly explained by difficulties in assessing the complex dose-response of ecological communities. But equally, it is hindered by a lack of spatially distributed estimates of suspended sediment variability across catchments. In this paper, we demonstrate the inability of traditional, discrete sampling campaigns for assessing exposure to fine sediment. Sampling frequencies based on Environmental Quality Standard protocols, whilst reflecting typical manual sampling constraints, are unable to determine the magnitude of sediment exposure with an acceptable level of precision. Deviations from actual concentrations range between -35 and +20% based on the interquartile range of simulations. As an alternative, we assess the value of low-cost, suspended sediment sampling networks for quantifying suspended sediment transfer (SST). In this study of the 362 km 2 upland Esk catchment we observe that spatial patterns of sediment flux are consistent over the two year monitoring period across a network of 17 monitoring sites. This enables the key contributing sub-catchments of Butter Beck (SST: 1141 t km 2 yr -1 ) and Glaisdale Beck (SST: 841 t km 2 yr -1 ) to be identified. The time-integrated samplers offer a feasible alternative to traditional infrequent and discrete sampling approaches for assessing spatio-temporal changes in contamination. In conjunction with a spatially distributed diffuse pollution model (SCIMAP), time-integrated sediment sampling is an effective means of identifying critical sediment source areas in the catchment, which can better inform sediment management strategies for pollution prevention and control. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Metal induced crystallization of amorphous silicon thin films studied by x-ray absorption fine structure spectroscopy

    International Nuclear Information System (INIS)

    Naidu, K Lakshun; Mohiddon, Md Ahamad; Dalba, G; Krishna, M Ghanashyam; Rocca, F

    2013-01-01

    The role of thin metallic layer (Chromium or Nickel) in the crystallization of a-Si film has been studied using X-ray absorption fine structure spectroscopy (XAFS). The films were grown at different substrate temperatures in two different geometrical structures : (a) a 200 nm metal layer (Cr or Ni) was deposited on fused silica (FS) followed by 400 nm of a-Si and (b) the 400 nm a-Si layer was deposited on FS followed by 200 nm of metal layer. XAFS measurements at Cr K-edge and Ni K-edge were done at BM08 – GILDA beamline of the European Synchrotron Research Facility (ESRF, Grenoble, F) in fluorescence mode. To understand the evolution of the local structure of Cr/Ni diffusing from bottom to top and from top to bottom, total reflection and higher incidence angles were employed. The relative content of metal, metal oxide and metal silicides compounds on the upper surface and/or in the bulk of different films has been evaluated as a function of thermal treatment.

  10. Changes in the Fine Structure of Stochastic Distributions as a Consequence of Space-Time Fluctuations

    Directory of Open Access Journals (Sweden)

    Shnoll S. E.

    2006-04-01

    Full Text Available This is a survey of the fine structure stochastic distributions in measurements obtained by me over 50 years. It is shown: (1 The forms of the histograms obtained at each geographic point (at each given moment of time are similar with high probability, even if we register phenomena of completely different nature --- from biochemical reactions to the noise in a gravitational antenna, or alpha-decay. (2 The forms of the histograms change with time. The iterations of the same form have the periods of the stellar day (1.436 min, the solar day (1.440 min, the calendar year (365 solar days, and the sidereal year (365 solar days plus 6 hours and 9 min. (3 At the same instants of the local time, at different geographic points, the forms of the histograms are the same, with high probability. (4 The forms of the histograms depend on the locations of the Moon and the Sun with respect to the horizon. (5 All the facts are proof of the dependance of the form of the histograms on the location of the measured objects with respect to stars, the Sun, and the Moon. (6 At the instants of New Moon and the maxima of solar eclipses there are specific forms of the histograms. (7 It is probable that the observed correlations are not connected to flow power changes (the changes of the gravity force --- we did not find the appropriate periods in changes in histogram form. (8 A sharp anisotropy of space was discovered, registered by alpha-decay detectors armed with collimators. Observations at 54 North (the collimator was pointed at the Pole Star showed no day-long periods, as was also the case for observations at 82 North, near the Pole. Histograms obtained by observations with an Easterly-directed collimator were determined every 718 minutes (half stellar day and with observations using a Westerly-directed collimator. (9 Collimators rotating counter-clockwise, in parallel with the celestial equator, gave the probability of changes in histograms as the number of the

  11. Changes in the Fine Structure of Stochastic Distributions as a Consequence of Space-Time Fluctuations

    Directory of Open Access Journals (Sweden)

    Shnoll S. E.

    2006-04-01

    Full Text Available This is a survey of the fine structure stochastic distributions in measurements obtained by me over 50 years. It is shown: (1 The forms of the histograms obtained at each geographic point (at each given moment of time are similar with high probability, even if we register phenomena of completely different nature — from biochemical reactions to the noise in a gravitational antenna, or α-decay. (2 The forms of the histograms change with time. The iterations of the same form have the periods of the stellar day (1.436 min, the solar day (1.440 min, the calendar year (365 solar days, and the sidereal year (365 solar days plus 6 hours and 9 min. (3 At the same instants of the local time, at different geographic points, the forms of the histograms are the same, with high probability. (4 The forms of the histograms depend on the locations of the Moon and the Sun with respect to the horizon. (5 All the facts are proof of the dependance of the form of the histograms on the location of the measured objects with respect to stars, the Sun, and the Moon. (6 At the instants of New Moon and the maxima of solar eclipses there are specific forms of the histograms. (7 It is probable that the observed correlations are not connected to flow power changes (the changes of the gravity force — we did not find the appropriate periods in changes in histogram form. (8 A sharp anisotropy of space was discovered, registered by α-decay detectors armed with collimators. Observations at 54◦ North (the collimator was pointed at the Pole Star showed no day-long periods, as was also the case for observations at 82◦ North, near the Pole. Histograms obtained by observations with an Easterly-directed collimator were determined every 718 minutes (half stellar day and with observations using a Westerly-directed collimator. (9 Collimators rotating counter-clockwise, in parallel with the celestial equator, gave the probability of changes in histograms as the number of the

  12. Heavy metal distribution in a spruce ecosystem in the Solling mountains

    International Nuclear Information System (INIS)

    Schultz, R.; Lamersdorf, N.

    1989-01-01

    In this investigation the distribution of Cr, Co, Cu, Zn, Cd and Pb was studied in a spruce forest. Heavy metal content was analysed in different compartments of the ecosystem. Inventory of these elements was calculated for tree layer, humus layer and upper soil. A decrease in meter concentration in wood from root to shoot showed strong immobilization of heavy metals in roots. Increasing content of Cu in wood of branches can be explained as storage of this micronutrient. Atmospherically deposited Cr, Cu and Pb were strongly adsorbed to organic substances and accumulate in bark, dead fine roots and humus layer. On the other hand Zn and Cd are more mobile in the ecosystem. High amounts of these elements were found in biomass. Accumulation in bark probably can be a strategy of the tree to store these elements in physiologically inactive forms. Increasing mobilization of Zn, Cd and Co in soil led to intensified root uptake and to higher seepage output. (orig.)

  13. DISTRIBUTION OF METALS IN PARTICLE SIZE FRACTIONS IN SOILS OF TWO FORESTED CATENAS (SMOLENSK-MOSCOW UPLAND

    Directory of Open Access Journals (Sweden)

    Olga Samonova

    2013-01-01

    Full Text Available The concentrations and distribution of Fe, Ti, Zr, Mn, Cu. Ni, Co, Cr, Pb, and Zn associated with various particle size fractions have been analyzed in soils of two forested catenas located in the middle Protva River basin on the Smolensk-Moscow Upland. The results showed that concentration of metals in a particular size fraction was defined by a complex of factors: element chemical properties, soil type, genesis of a soil horizon, and position in the catena. A clearly defined relationship between the fraction size and metal concentrations was found for Ti and Zr. The highest levels of Ti were found in coarse and medium silt, while Zr had its highest values only in coarse silt and, in some cases, in fine sand. Such metals as Fe, Mn, Co, Cu and Pb had high concentrations in sand, fine silt, and clay fractions depending on a soil type and a genetic horizon. The maximum load of Cr, Zn, and Ni (in the majority of cases was found in clay fraction. The minimum loads of Fe, Mn, Co, Cu, and Ni were found in the coarse silt fraction. Variation in concentrations of heavy metals differed depending on particle size. For most metals, the variations were decreasing from coarser to finer fractions.Key words: soils, heavy metals, grain-size fractionation, vertical and lateral distribution patterns

  14. Microfocus study of metal distribution and speciation in tissue extracted from revised metal on metal hip implants

    International Nuclear Information System (INIS)

    Hart, Alister J; Sandison, Ann; Quinn, Paul; Mosselmans, J Frederick W; Sampson, Barry; Atkinson, Kirk D; Skinner, John A; Goode, Angela; Powell, Jonathan J

    2009-01-01

    Unexplained tissue inflammation in metal-on-metal hip replacements is suspected to be caused by implant-derived nanoparticles. The aim of this study was to investigate the nature of the metal particles in tissue surrounding metal-on-metal (MOM) hips that has been extracted during revision. Mapping of tissue surrounding the failed MOM hips was performed using microfocus X-ray Fluorescence (XRF). This revealed mainly Cr which was localized to the cellular regions. There was co-localisation of Co, were present, to areas of high Cr abundance. XANES of the tissue and appropriate standards revealed that the most common species were Cr(III) and Co(II). EXAFS analysis of the tissue and various metal standards revealed that the most abundant implant-related species was Cr(III) phosphate. Different tissue preparation methods, including frozen sectioning, were examined but were found not to affect the distribution or speciation of the metals in the tissue.

  15. Microfocus study of metal distribution and speciation in tissue extracted from revised metal on metal hip implants

    Energy Technology Data Exchange (ETDEWEB)

    Hart, Alister J [Department of Orthopaedic Surgery, Imperial College and Imperial College Healthcare NHS Trust, Charing Cross Hospital Campus, Fulham Palace Rd, London W6 8RF (United Kingdom); Sandison, Ann [Department of Histopathology, Imperial College and Imperial College Healthcare NHS Trust, Charing Cross Hospital Campus, Fulham Palace Rd, London W6 8RF (United Kingdom); Quinn, Paul; Mosselmans, J Frederick W [Science Division, Diamond Light Source, Harwell Science and Innovation Campus, Didcot, Oxon, OX11 0DE (United Kingdom); Sampson, Barry [Department of Clinical Biochemistry, Imperial College and Imperial College Healthcare NHS Trust, Charing Cross Hospital Campus, Fulham Palace Rd, London W6 8RF (United Kingdom); Atkinson, Kirk D [8 Nuclear Department Defence Academy College of Management and Technology HMS Sultan Military Road Gosport PO12 3BY (United Kingdom); Skinner, John A [Department of Orthopaedics, Royal National Orthopaedic Hospital, HA7 4LP (United Kingdom); Goode, Angela [Dept of Materials, Imperial College London, SW7 2AZ (United Kingdom); Powell, Jonathan J, E-mail: Paul.Quinn@diamond.ac.u [Medical Research Council Human Nutrition Research Centre, Cambridge CB1 9NL (United Kingdom)

    2009-11-15

    Unexplained tissue inflammation in metal-on-metal hip replacements is suspected to be caused by implant-derived nanoparticles. The aim of this study was to investigate the nature of the metal particles in tissue surrounding metal-on-metal (MOM) hips that has been extracted during revision. Mapping of tissue surrounding the failed MOM hips was performed using microfocus X-ray Fluorescence (XRF). This revealed mainly Cr which was localized to the cellular regions. There was co-localisation of Co, were present, to areas of high Cr abundance. XANES of the tissue and appropriate standards revealed that the most common species were Cr(III) and Co(II). EXAFS analysis of the tissue and various metal standards revealed that the most abundant implant-related species was Cr(III) phosphate. Different tissue preparation methods, including frozen sectioning, were examined but were found not to affect the distribution or speciation of the metals in the tissue.

  16. Study of particle size and trace metal distribution in atmospheric aerosols of islamabad

    International Nuclear Information System (INIS)

    Shah, M.H.; Shaheen, N.

    2009-01-01

    Atmospheric aerosol samples were collected on glass fibre filters using high volume air samplers Half of each aerosol sample was solubilized in nitric acid/hydrochloric acid based wet digestion method and the concentration of trace metals was determined through flame atomic absorption spectrophotometer. Among the eight trace metals analyzed, mean concentration recorded for Zn (844 ng/m3), Fe (642 ng/m3) and Pb (253 ng/m3), was found to be higher than mean levels of Mn, Cr and Co. The size distribution of the collected particulate samples was carried out on mastersizer, which revealed PM/sub 100-10/ as the major fraction (55 %) followed by PM/sub 2.5-10/ (28 %). The correlation study evidenced a strong tendency of trace metals to be associated with fine particulate fractions. The atmospheric trace metal levels showed that the mean metal concentrations in the atmosphere of Islamabad are far higher than background and European urban sites mainly due to the anthropogenic emissions. (author)

  17. Hyperfine field distribution of Fe83B17 glassy metal

    International Nuclear Information System (INIS)

    Miglierini, M.; Sitek, J.

    1990-01-01

    Convolutions of Gaussian and Lorentzian lines are proposed to fit the Moessbauer spectrum of Fe 83 B 17 metallic glass. The hyperfine field distribution is constructed from three Gaussian lines corresponding to the individual line pairs. (author). 1 fig., 7 refs

  18. Distribution of inert gases in fines from the Cayley-Descartes region

    Science.gov (United States)

    Walton, J. R.; Lakatos, S.; Heymann, D.

    1973-01-01

    The inert gases in 14 different fines and in one sample of 2 to 4 mm fines from Apollo 16 were measured by mass spectroscopy with respect to trapped solar wind gases, cosmogenic gases, and 'parentless' Ar-40. Such studies are helpful for the understanding of regolith evolution, of transport of regolith fines, and of the lunar atmosphere. The Apollo 16 soils are unique because they represent, after Luna 20, the second and much more extensive record from the lunar highlands. The landing site presents the problem of materials from the Cayley Formation vs those from the Descartes Formation. There are two large, relatively fresh craters in the area, North Ray and South Ray, whose ejecta patterns may be recognized in the inert-gas record.

  19. Origin and spatial distribution of metals in agricultural soils

    International Nuclear Information System (INIS)

    Mohammadpour, Gh.A.; Karbassi, A.R.; Baghvand, A.

    2016-01-01

    Presence of toxic metals in agricultural soils can impose adverse health impact on consumers. The main purpose of this study was to determine spatial distribution of elements Fe, Sb, Mn in agriculture soils and crops of Hamedan Province in Iran. Soil samples (0-20 cm depth) were collected from an area of 2831 km 2 . Iron, Antimony and Manganese in samples of soil and agricultural crops were extracted and their amount was determined using atomic absorption spectrometer. The spatial distribution map of the studied elements was developed using Kriging method. The main concentration of Fe, Sb and Mn in the soil of the study area is about 3.8%, 2.5 and 403 mg/kg, respectively. According to chemical partitioning studies, the anthropogenic share of Fe, Sb and Mn is about 28.51%, 34.83% and 30.35%, respectively. Results of comparison of heavy metals pollution intensity in the agricultural soil with geoaccumulation index and also pollution index, illustrated that iron and manganese are classified in the Non-polluted class and antimony is in the moderately polluted class. Analysis of zoning map of pollution index showed that Fe, Sb and Mn are of geological sources. In fact, these metals are naturally found in soil. However, anthropogenic activities have led to more accumulation of these metals in the soil. The obtained health risk for metals in agricultural crops is indicative of safe value for consumers.

  20. Distribution of heavy metals from flue gas in algal bioreactor

    Science.gov (United States)

    Napan, Katerine

    Flue gas from coal-fired power plants is a major source of CO2 to the atmosphere. Microalgae can use this enriched form of CO2 as carbon source and in turn the biomass can be used to produce food, feed, fertilizer and biofuels. However, along with CO2, coal-based flue gas will inevitably introduce heavy metals, which have a high affinity to bind algal cells, could be toxic to the organisms and if transferred to the products could limit their uses. This study seeks to address the distribution and impact of heavy metals present in flue gas on microalgae production systems. To comprehend its effects, algae Scenedesmus obliquus was grown in batch reactors in a multimetal system. Ten heavy metals (Cu, Co, Zn, Pb, As, Se, Cr, Hg, Ni and Cd) were selected and were evaluated at four concentrations (1X, 2X, 5X and 10X). Results show that most heavy metals accumulated mainly in biomass and were found in very low concentrations in media. Hg was shown to be lost from the culture, with low amounts present in the biomass. An upper limit for As uptake was observed, suggesting its likelihood to build-up in the system during medium recycle. The As limited bioaccumulation was overcome by addition of sulfur to the algal medium. Heavy metal at 2X, 5X and 10X inhibited both growth and lipid production, while at the reference concentration both biomass and lipids yields were increased. Heavy metal concentrations in the medium and biomass were time dependent, and at the end of the cultivation most heavy metals in the supernatant solution complied with the recommendations for irrigation water, while biomass was below limits for cattle and poultry feed, fertilizer, plastic and paper. This research shows that bioremediation of CO2 and heavy metals in combination with energy production can be integrated, which is an environmentally friendly form of biotechnology.

  1. [Fine mesh metal endoprostheses for treatment of extensive cervical and intrathoracic tracheomalacia].

    Science.gov (United States)

    Wilmes, E; Berger, H; Dienemann, H; Jolk, A

    1994-01-01

    The treatment of tracheal stenoses caused by tracheomalacia is mainly carried out by means of sleeve resection, tracheopexy with ring support or other tracheoplastic operative procedures. If patients cannot be treated by surgical operative strategies, conventional stents are usually used to dilate the trachea. The use of a self-expanding elastic metal prosthesis in 5 patients with tracheal airway obstruction caused by tracheomalacia proved to be a true alternative in the therapy of tracheobronchial stenoses. We report on the long term use of 5 patients with tracheal stenoses treated by implantation of elastic metal wallstents. The implantation of the stents resulted in immediate improvement in respiratory function in all 5 patients. None of the patients experienced complications secondary to the stent placement. The stents were well tolerated (long-time follow-up 26 months). The implantation of self-expanding metal stents type "wallstent" seems to offer alternative possibilities for the treatment of tracheomalacia.

  2. Model of bidirectional reflectance distribution function for metallic materials

    International Nuclear Information System (INIS)

    Wang Kai; Zhu Jing-Ping; Liu Hong; Hou Xun

    2016-01-01

    Based on the three-component assumption that the reflection is divided into specular reflection, directional diffuse reflection, and ideal diffuse reflection, a bidirectional reflectance distribution function (BRDF) model of metallic materials is presented. Compared with the two-component assumption that the reflection is composed of specular reflection and diffuse reflection, the three-component assumption divides the diffuse reflection into directional diffuse and ideal diffuse reflection. This model effectively resolves the problem that constant diffuse reflection leads to considerable error for metallic materials. Simulation and measurement results validate that this three-component BRDF model can improve the modeling accuracy significantly and describe the reflection properties in the hemisphere space precisely for the metallic materials. (paper)

  3. Model of bidirectional reflectance distribution function for metallic materials

    Science.gov (United States)

    Wang, Kai; Zhu, Jing-Ping; Liu, Hong; Hou, Xun

    2016-09-01

    Based on the three-component assumption that the reflection is divided into specular reflection, directional diffuse reflection, and ideal diffuse reflection, a bidirectional reflectance distribution function (BRDF) model of metallic materials is presented. Compared with the two-component assumption that the reflection is composed of specular reflection and diffuse reflection, the three-component assumption divides the diffuse reflection into directional diffuse and ideal diffuse reflection. This model effectively resolves the problem that constant diffuse reflection leads to considerable error for metallic materials. Simulation and measurement results validate that this three-component BRDF model can improve the modeling accuracy significantly and describe the reflection properties in the hemisphere space precisely for the metallic materials.

  4. Nonequilibrium approach regarding metals from a linearised kappa distribution

    Science.gov (United States)

    Domenech-Garret, J. L.

    2017-10-01

    The widely used kappa distribution functions develop high-energy tails through an adjustable kappa parameter. The aim of this work is to show that such a parameter can itself be regarded as a function, which entangles information about the sources of disequilibrium. We first derive and analyse an expanded Fermi-Dirac kappa distribution. Later, we use this expanded form to obtain an explicit analytical expression for the kappa parameter of a heated metal on which an external electric field is applied. We show that such a kappa index causes departures from equilibrium depending on the physical magnitudes. Finally, we study the role of temperature and electric field on such a parameter, which characterises the electron population of a metal out of equilibrium.

  5. Identification of metals into fine particles (PM2.5) during the dry cold season in the Toluca City

    International Nuclear Information System (INIS)

    Martinez P, A. A.; Aldape U, F.

    2008-01-01

    To know the elemental content of fine particles PM 2.5 that can affect people in the Toluca City, such as metals and another, it was made a campaign collection of fine particles during dry-cold ( November 2006-March 2007). The aerosol samples were collected on Teflon filters with an equipment BGI model PQ200 mark authorized by the Environment Protection Agency (EPA), every other day with a time resolution of 24 h. The determination of the elemental composition of the samples was performed by means of the technique Particle Induced X-Ray Emission (PIXE). The results of the analysis showed consistently 13 elements S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, as, throughout the collection period. We calculated the enrich factor that separates the elements of the natural component of the anthropogenic component. The correlation matrix shows the pairs of elements that are contained in the same air mass as Vanadium and Nickel. From the results it is concluded that the sources that gave rise to these particles are the burning of fossil fuels in motor vehicles, lubricants, additives and burning tires wear of automotive vehicles, besides the products used in agricultural activities. (Author)

  6. METALLICITY DISTRIBUTION FUNCTIONS OF FOUR LOCAL GROUP DWARF GALAXIES

    Energy Technology Data Exchange (ETDEWEB)

    Ross, Teresa L.; Holtzman, Jon [Department of Astronomy, New Mexico State University, P.O. Box 30001, MSC 4500, Las Cruces, NM 88003-8001 (United States); Saha, Abhijit [NOAO, 950 Cherry Avenue, Tucson, AZ 85726-6732 (United States); Anthony-Twarog, Barbara J., E-mail: rosst@nmsu.edu, E-mail: holtz@nmsu.edu, E-mail: bjat@ku.edu [Department of Physics and Astronomy, University of Kansas, Lawrence, KS 66045-7582 (United States)

    2015-06-15

    We present stellar metallicities in Leo I, Leo II, IC 1613, and Phoenix dwarf galaxies derived from medium (F390M) and broad (F555W, F814W) band photometry using the Wide Field Camera 3 instrument on board the Hubble Space Telescope. We measured metallicity distribution functions (MDFs) in two ways, (1) matching stars to isochrones in color–color diagrams and (2) solving for the best linear combination of synthetic populations to match the observed color–color diagram. The synthetic technique reduces the effect of photometric scatter and produces MDFs 30%–50% narrower than the MDFs produced from individually matched stars. We fit the synthetic and individual MDFs to analytical chemical evolution models (CEMs) to quantify the enrichment and the effect of gas flows within the galaxies. Additionally, we measure stellar metallicity gradients in Leo I and II. For IC 1613 and Phoenix our data do not have the radial extent to confirm a metallicity gradient for either galaxy. We find the MDF of Leo I (dwarf spheroidal) to be very peaked with a steep metal-rich cutoff and an extended metal-poor tail, while Leo II (dwarf spheroidal), Phoenix (dwarf transition), and IC 1613 (dwarf irregular) have wider, less peaked MDFs than Leo I. A simple CEM is not the best fit for any of our galaxies; therefore we also fit the “Best Accretion Model” of Lynden-Bell. For Leo II, IC 1613, and Phoenix we find similar accretion parameters for the CEM even though they all have different effective yields, masses, star formation histories, and morphologies. We suggest that the dynamical history of a galaxy is reflected in the MDF, where broad MDFs are seen in galaxies that have chemically evolved in relative isolation and narrowly peaked MDFs are seen in galaxies that have experienced more complicated dynamical interactions concurrent with their chemical evolution.

  7. Distribution of heavy metals in urban soils - a case study of Danang-Hoian area (Vietnam)

    Energy Technology Data Exchange (ETDEWEB)

    Thuy, H.T.T.; Tobschall, H.J. [Erlangen-Nuernberg Univ., Erlangen (Germany). Inst. fuer Geologie und Mineralogie; An, P.V. [Univ. of Mining and Geology, Hanoi (Viet Nam)

    2000-04-01

    This work is part of a research study which is intended to study the degree of anthropogenic influences of the trace metal distribution of soils from Danang-Hoian area (Vietnam). Cu, Ni, Zn and Zr show significant effects in most of the cultivated soil categories, especially in the industrial soils. Extremely high levels of Pb (up to 742 {mu}g/g) are observed in the industrial soil category, which shows an enrichment factor 114 as compared to rural soils. Cd shows only a relative local enrichment with the maximum level of 4.6 {mu}g/g in urban soils. Sequential extraction was performed in selected samples to evaluate the geochemical trace metals. The result indicates that Zn and Cr are mainly found in the crystal and amorphous Fe oxide bounded forms. The contents of Cr in these fractions comprise more than 94% of total extractable Cr. In the case of Zn, 85% of total extractable Zn is in fractions F{sub V} and F{sub VI}. Cu is mainly found in the organic fraction at an average of 39.3% of total extractable content. On the other hand, heavy metal contents show an increasing tendency in the fine fraction (slit and clay). (orig.)

  8. Metallic nickel nano- and fine particles induce JB6 cell apoptosis through a caspase-8/AIF mediated cytochrome c-independent pathway

    Directory of Open Access Journals (Sweden)

    Castranova Vincent

    2009-04-01

    Full Text Available Abstract Background Carcinogenicity of nickel compounds has been well documented. However, the carcinogenic effect of metallic nickel is still unclear. The present study investigates metallic nickel nano- and fine particle-induced apoptosis and the signal pathways involved in this process in JB6 cells. The data obtained from this study will be of benefit for elucidating the pathological and carcinogenic potential of metallic nickel particles. Results Using 3-(4,5-dimethylthiazol-2-yl-2,5-diphenyltetrazolium bromide (MTT assay, we found that metallic nickel nanoparticles exhibited higher cytotoxicity than fine particles. Both metallic nickel nano- and fine particles induced JB6 cell apoptosis. Metallic nickel nanoparticles produced higher apoptotic induction than fine particles. Western-blot analysis showed an activation of proapoptotic factors including Fas (CD95, Fas-associated protein with death domain (FADD, caspase-8, death receptor 3 (DR3 and BID in apoptotic cells induced by metallic nickel particles. Immunoprecipitation (IP western blot analysis demonstrated the formation of the Fas-related death-inducing signaling complex (DISC in the apoptotic process. Furthermore, lamin A and beta-actin were cleaved. Moreover, we found that apoptosis-inducing factor (AIF was up-regulated and released from mitochondria to cytoplasm. Interestingly, although an up-regulation of cytochrome c was detected in the mitochondria of metallic nickel particle-treated cells, no cytochrome c release from mitochondria to cytoplasm was found. In addition, activation of antiapoptotic factors including phospho-Akt (protein kinase B and Bcl-2 was detected. Further studies demonstrated that metallic nickel particles caused no significant changes in the mitochondrial membrane permeability after 24 h treatment. Conclusion In this study, metallic nickel nanoparticles caused higher cytotoxicity and apoptotic induction than fine particles in JB6 cells. Apoptotic cell death

  9. [Correlation of fine structures of distributions of amplitudes of a photomultiplier dark current fluctuations with the Earth rotations about its axis].

    Science.gov (United States)

    Fedorov, M V; Belousov, L V; Voeĭkov, V L; Zenchenko, K I; Zenchenko, T A; Konradov, A A; Shnol', S E

    2001-01-01

    The fine structures of distributions of photomultiplier dark current fluctuations measured in two laboratories 2000 km distant from other: in the international Institute of Biophysics (Neuss, Germany) and in the Moscow State University (Moscow, Russia) were compared. It is shown that similar forms of appropriate histograms are apparently more often realized at both locations at the same local time. This confirms the previous conclusion that the fine structure of distributions correlates with rotation of the Earth about its axis.

  10. Fine-scale distribution of zooplankton is linked to phytoplankton species composition and abundance in a North Norwegian fjord system

    Science.gov (United States)

    Norrbin, F.; Priou, P. D.; Varela, A. P.

    2016-02-01

    We studied the influence of dense layers of phytoplankton and aggregates on shaping the vertical distribution of zooplankton in a North Norwegian fjord using a Video Plankton Recorder (VPR). This instrument provided fine-scale vertical distribution (cm-m scale) of planktonic organisms as well as aggregates of marine snow in relation to environmental conditions. At the height - later stage of the spring phytoplankton bloom in May, the outer part of the fjord was dominated by Phaeocystis pouchetii, while diatoms (Chaetoceros spp.) were dominating in the innermost basin. Small copepods species like Pseudocalanus spp., Microsetella norvegica, and Oithona spp. prevailed over larger copepod species in the inner part of the fjord whereas the outer part was dominated by large copepods like Calanus finmarchicus. While the zooplankton where spread out over the water column during the early stage of the bloom, in May they were linked to the phytoplankton vertical distribution and in the winter situation they were found in deeper waters. Herbivorous zooplankton species were affected by phytoplankton species composition; C. finmarchicus and Pseudocalanus spp. avoided the dense layer of P. pouchetii while herbivorous zooplankton matched the distribution of the diatom-dominated bloom. Small, omnivorous copepod species like Microsetella sp., Oithona sp. and Pseudocalanus sp. were often associated with dense layers of snow aggregates. This distribution may provide a shelter from predators as well as a food source. Natural or anthropogenic-induced changes in phytoplankton composition and aggregate distribution may thus influence food-web interactions.

  11. Compression behavior of cellular metals with inhomogeneous mass distribution

    International Nuclear Information System (INIS)

    Foroughi, B.

    2001-05-01

    Mechanical behavior of two types of closed cell metals (ALULIGHT and ALPORAS) is investigated experimentally and numerically. Compressive tests performed on prismatic specimens indicate that inhomogeneities in the mass density distribution are a key factor in the deformation behavior of cellular metals. The three dimensional cellular structure of the investigated specimens is recorded using x-ray medical computed tomography (CT). A special procedure called density mapping method has been used to transfer the recorded CT data into a continuum by averaging over a certain domain (averaging domain). This continuum model is implemented using finite elements to study the effect of variations in local mass densities. The finite element model is performed by a simple regular discretization of a specimen's volume with elements which have constant edge length. Mechanical properties derived from compression tests of ALPORAS samples are assigned to the corresponding mesoscopic density value of each element. The effect of averaging domain size is studied to obtain a suitable dimension which fulfils the homogenization requirements and allows the evaluation of inhomogenities in the specimens. The formation and propagation of deformation band(s) and stress-strain responses of tested cellular metals are modeled with respect to their mass distribution. It is shown that the inhomogeneous density distribution leads to plastic strain localization and causes a monotonically increase of the stress in the plateau regime although no hardening response was considered for homogeneous material in this regime. The simulated plastic strain localization and the calculated stress-strain responses are compared with the experimental results. The stiffness values of experiment and simulation agree very well for both cellular materials. The values of plateau strength as well, but it differs in some cases of ALULIGHT samples, where the hardening response can be predicted at least qualitatively

  12. A fine-tuned Metal-Organic Framework for Autonomous Indoor Moisture Control .

    KAUST Repository

    Abdul Halim, Racha Ghassan

    2017-06-29

    Conventional adsorbents, namely zeolites and silica gel, are often used to control humidity by adsorbing water; however, adsorbents capable of dual functionality of humidification and dehumidification, offering the desired control of the moisture level at room temperature, has yet to be explored. Here we report Y-shp-MOF-5, a hybrid microporous highly-connected Rare-Earth based metal-organic framework (MOF), with dual functionality for moisture control within the recommended range of relative humidity (45% to 65% RH) set by the American Society of Heating, Refrigerating, and Air-Conditioning Engineers (ASHRAE). Y-shp-MOF-5 exhibits exceptional structural integrity, robustness and unique humidity-control performance as confirmed by the large number (thousand) of conducted water vapor adsorption-desorption cycles. The retained structural integrity and the mechanism of water sorption were corroborated using in situ single crystal X-ray diffraction (SCXRD) studies. The resultant working water uptake of 0.45 g.g-1 is solely regulated by a simple adjustment of the relative humidity, positioning this hydrolytically stable MOF as a prospective adsorbent for humidity control in confined spaces such as space shuttles, aircraft cabins and air-conditioned buildings.

  13. Laboratory study on metal attenuation capacity of fine grained soil near ash pond site.

    Science.gov (United States)

    Ghosh, Sudipta; Mukherjee, Somnath; Sarkar, Sujoy; Kumar, Sunil

    2008-10-01

    Waste settling tanks of earthen containment nature are common in India for disposal of solid waste in slurry form. For a large pond system, e.g. ash slurry disposal tank of coal base thermal power plant, leachate generation and its migration pose a serious problem. A natural attenuation of controlling the migratory leachate is to use locally available clay material as lining system due to the adsorption properties of soil for reducing some metallic ions. The present investigation was carried out to explore the Ni2+ and Cr6+ removal capacity of surrounding soil of the ash pond site of Super Thermal Power Plant in West Bengal, India through some laboratory scale and field studies. The soil and water samples collected from the site showed the existence of Ni2+ and Cr6+ in excess to permissible limit. A two-dimensional adsorption behaviour of these pollutants through soil was assessed. The results showed that more than 80% of nickel and 72% of chromium were found to be sorbed by the soil corresponding to initial concentrations of two ions, i.e. 1.366 mg/L and 0.76 mg/L respectively. The batch adsorption data are tested Langmuir and Freundlich isotherm models and found reasonably fit. Breakthrough adsorption study uptake also showed a good adsorption capacity of the soil. The experimental results found to fit well with the existing two dimensional (2D) mathematical models as proposed by Fetter (1999).

  14. Demonstrating the Uneven Importance of Fine-Scale Forest Structure on Snow Distributions using High Resolution Modeling

    Science.gov (United States)

    Broxton, P. D.; Harpold, A. A.; van Leeuwen, W.; Biederman, J. A.

    2016-12-01

    Quantifying the amount of snow in forested mountainous environments, as well as how it may change due to warming and forest disturbance, is critical given its importance for water supply and ecosystem health. Forest canopies affect snow accumulation and ablation in ways that are difficult to observe and model. Furthermore, fine-scale forest structure can accentuate or diminish the effects of forest-snow interactions. Despite decades of research demonstrating the importance of fine-scale forest structure (e.g. canopy edges and gaps) on snow, we still lack a comprehensive understanding of where and when forest structure has the largest impact on snowpack mass and energy budgets. Here, we use a hyper-resolution (1 meter spatial resolution) mass and energy balance snow model called the Snow Physics and Laser Mapping (SnowPALM) model along with LIDAR-derived forest structure to determine where spatial variability of fine-scale forest structure has the largest influence on large scale mass and energy budgets. SnowPALM was set up and calibrated at sites representing diverse climates in New Mexico, Arizona, and California. Then, we compared simulations at different model resolutions (i.e. 1, 10, and 100 m) to elucidate the effects of including versus not including information about fine scale canopy structure. These experiments were repeated for different prescribed topographies (i.e. flat, 30% slope north, and south-facing) at each site. Higher resolution simulations had more snow at lower canopy cover, with the opposite being true at high canopy cover. Furthermore, there is considerable scatter, indicating that different canopy arrangements can lead to different amounts of snow, even when the overall canopy coverage is the same. This modeling is contributing to the development of a high resolution machine learning algorithm called the Snow Water Artificial Network (SWANN) model to generate predictions of snow distributions over much larger domains, which has implications

  15. Distributions of alkali metals, alkaline earth metals and halogens in cabbage leaves

    International Nuclear Information System (INIS)

    Tsukada, Hirofumi; Takeda, Akira; Hasegawa, Hidenao

    2007-01-01

    The distributions of stable elements in plant components provide useful information for understanding the behavior of radionuclides in plants. An entire cabbage plant sample was collected from an experimental field, and the distributions of alkali metals (K, Rb and Cs), alkaline earth metals (Ca, Sr and Ba) and halogens (Cl and I) were determined for cabbage leaves at different positions. The concentration of Cs in outer (older) cabbage leaves was higher than that in inner (younger) leaves, but the distributions of K and Rb concentrations were relatively similar in cabbage leaves, independent of leaf positions. The concentration of Sr in older cabbage leaves was one order of magnitude higher than that in younger leaves. The distributions of Ca, Ba and Sr concentrations in the plant followed a similar pattern. The concentrations of halogens were also very rich in the outer leaves. The percentage distributions of Cs, Sr, Cl and I in the inedible (extreme outer) leaves were 77, 91, 93 and 96% of the total content in the leaf part, respectively. These results show that the inedible plant components are important for understanding the transfer of the radioactive Cs, Sr Cl and I in soil-plant systems. (author)

  16. Hydrocarbons and heavy metals in fine particulates in oil field air: possible impacts on production of natural silk.

    Science.gov (United States)

    Devi, Gitumani; Devi, Arundhuti; Bhattacharyya, Krishna Gopal

    2016-02-01

    Analyses of fine particulates (PM2.5) from the upper Assam oil fields of India indicated considerable presence of higher hydrocarbons (C22-C35) and heavy metals, Cd, Co, Cr, Cu, Ni, Pb, and Zn. This has raised serious concern for the sustainability of the exotic Muga (Antheraea assama) silk production, which has been a prime activity of a large number of people living in the area. The Muga worm feeds on the leaves of Machilus bombycina plant, and the impacts of air quality on its survival were further investigated by analyzing the leaves of the plant, the plantation soil, and the Muga cocoons. PM2.5 content in the air was much more during the winter due to near calm conditions and high humidity. Fourier transform infrared (FTIR), thermogravimetric analysis (TGA), and gas chromatography-mass spectrometer (GC-MS) analysis of PM2.5 showed the presence of higher alkanes (C22-C35) that could be traced to crude oil. Cr, Ni, and Zn were found in higher concentrations in PM2.5, M. bombycina leaves, and the plantation soil indicating a common origin. The winter has been the best period for production of the silk cocoons, and the unhealthy air during this period is likely to affect the production, which is already reflected in the declining yield of Muga cocoons from the area. SEM and protein analyses of the Muga silk fiber produced in the oil field area have exhibited the deteriorating quality of the silk. This is the first report from India on hydrocarbons and associated metals in PM2.5 collected from an oil field and on their possible effects on production of silk by A. assama.

  17. Evaluation of local power distribution with fine-mesh core model for the HTTR

    International Nuclear Information System (INIS)

    Murata, Isao; Yamashita, Kiyonobu; Maruyama, So; Shindo, Ryuichi; Fujimoto, Nozomu; Sudo, Yukio; Nakata, Tetsuo.

    1991-01-01

    An evaluation method of the local power distribution was developed considering the radial and axial heterogeneity caused by fuel rods, BP rods and block end graphite for the High Temperature Engineering Test Reactor (HTTR) in Japan Atomic Energy Research Institute (JAERI). The evaluation method was verified through the analyses of critical assembly experiments. A good agreement was obtained between calculations and measurements and the difference was less than 3 % on the power distribution. This method was applied to the core design for the HTTR to evaluate the maximum fuel temperature. From these results, it was confirmed that this evaluation method has an enough accuracy and is able to predict the detailed power distribution of the HTTR. (author)

  18. FINE PARTICAL AND TOXIC METAL EMISSIONS FROM THE COMBUSTION OF SEWAGE SLUDGE/COAL MIXTURES: A SYSTEMATIC ASSESSMENT

    Energy Technology Data Exchange (ETDEWEB)

    Jost O.L. Wendt; Wayne S. Seames; Art Fernandez

    2003-09-21

    This research project focuses on pollutants from the combustion of mixtures of dried municipal sewage sludge (MSS) and pulverized coal. The objective was to determine potential tradeoffs between CO{sub 2} mitigation through using a CO{sub 2} neutral fuel, such as municipal sewage sludge, and the emergence of other potential problems such as the emission of toxic fly ash particles. The work led to new insight into mechanisms governing the partitioning of major and trace metals from the combustion of sewage sludge, and mixtures of coal and sewage sludge. The research also showed that the co-combustion of coal and sewage sludge emitted fine particulate matter that might potentially cause greater lung injury than that from the combustion of either coal alone or municipal sewage sludge alone. The reason appeared to be that the toxicity measured required the presence of large amounts of both zinc and sulfur in particles that were inhaled. MSS provided the zinc while coal provided the sulfur. Additional research showed that the toxic effects could most likely be engineered out of the process, through the introduction of kaolinite sorbent downstream of the combustion zone, or removing the sulfur from the fuel. These results are consequences of applying ''Health Effects Engineering'' to this issue. Health Effects Engineering is a new discipline arising out of this work, and is derived from using a collaboration of combustion engineers and toxicologists to mitigate the potentially bad health effects from combustion of this biomass fuel.

  19. Fine-scale hydrodynamics influence the spatio-temporal distribution of harbour porpoises at a coastal hotspot

    Science.gov (United States)

    Jones, A. R.; Hosegood, P.; Wynn, R. B.; De Boer, M. N.; Butler-Cowdry, S.; Embling, C. B.

    2014-11-01

    The coastal Runnelstone Reef, off southwest Cornwall (UK), is characterised by complex topography and strong tidal flows and is a known high-density site for harbour porpoise (Phocoena phocoena); a European protected species. Using a multidisciplinary dataset including: porpoise sightings from a multi-year land-based survey, Acoustic Doppler Current Profiling (ADCP), vertical profiling of water properties and high-resolution bathymetry; we investigate how interactions between tidal flow and topography drive the fine-scale porpoise spatio-temporal distribution at the site. Porpoise sightings were distributed non-uniformly within the survey area with highest sighting density recorded in areas with steep slopes and moderate depths. Greater numbers of sightings were recorded during strong westward (ebbing) tidal flows compared to strong eastward (flooding) flows and slack water periods. ADCP and Conductivity Temperature Depth (CTD) data identified fine-scale hydrodynamic features, associated with cross-reef tidal flows in the sections of the survey area with the highest recorded densities of porpoises. We observed layered, vertically sheared flows that were susceptible to the generation of turbulence by shear instability. Additionally, the intense, oscillatory near surface currents led to hydraulically controlled flow that transitioned from subcritical to supercritical conditions; indicating that highly turbulent and energetic hydraulic jumps were generated along the eastern and western slopes of the reef. The depression and release of isopycnals in the lee of the reef during cross-reef flows revealed that the flow released lee waves during upslope currents at specific phases of the tidal cycle when the highest sighting rates were recorded. The results of this unique, fine-scale field study provide new insights into specific hydrodynamic features, produced through tidal forcing, that may be important for creating predictable foraging opportunities for porpoises at a

  20. Resource selection models are useful in predicting fine-scale distributions of black-footed ferrets in prairie dog colonies

    Science.gov (United States)

    Eads, David A.; Jachowski, David S.; Biggins, Dean E.; Livieri, Travis M.; Matchett, Marc R.; Millspaugh, Joshua J.

    2012-01-01

    Wildlife-habitat relationships are often conceptualized as resource selection functions (RSFs)—models increasingly used to estimate species distributions and prioritize habitat conservation. We evaluated the predictive capabilities of 2 black-footed ferret (Mustela nigripes) RSFs developed on a 452-ha colony of black-tailed prairie dogs (Cynomys ludovicianus) in the Conata Basin, South Dakota. We used the RSFs to project the relative probability of occurrence of ferrets throughout an adjacent 227-ha colony. We evaluated performance of the RSFs using ferret space use data collected via postbreeding spotlight surveys June–October 2005–2006. In home ranges and core areas, ferrets selected the predicted "very high" and "high" occurrence categories of both RSFs. Count metrics also suggested selection of these categories; for each model in each year, approximately 81% of ferret locations occurred in areas of very high or high predicted occurrence. These results suggest usefulness of the RSFs in estimating the distribution of ferrets throughout a black-tailed prairie dog colony. The RSFs provide a fine-scale habitat assessment for ferrets that can be used to prioritize releases of ferrets and habitat restoration for prairie dogs and ferrets. A method to quickly inventory the distribution of prairie dog burrow openings would greatly facilitate application of the RSFs.

  1. Surface-Emitting Distributed Feedback Terahertz Quantum-Cascade Lasers in Metal-Metal Waveguides

    Science.gov (United States)

    Kumar, Sushil; Williams, Benjamin S.; Qin, Qi; Lee, Alan W. M.; Hu, Qing; Reno, John L.

    2007-01-01

    Single-mode surface-emitting distributed feedback terahertz quantumcascade lasers operating around 2.9 THz are developed in metal-metal waveguides. A combination of techniques including precise control of phase of reflection at the facets, and u e of metal on the sidewalls to eliminate higher-order lateral modes allow robust single-mode operation over a range of approximately 0.35 THz. Single-lobed far-field radiation pattern is obtained using a pi phase-shift in center of the second-order Bragg grating. A grating device operating at 2.93 THz lased up to 149 K in pulsed mode and a temperature tuning of 19 .7 GHz was observed from 5 K to 147 K. The same device lased up to 78 K in continuous-wave (cw) mode emitting more than 6 m W of cw power at 5 K. ln general, maximum temperature of pulsed operation for grating devices was within a few Kelvin of that of multi-mode Fabry-Perot ridge lasers

  2. On flotation separation of oxo-anions of transition metals by the use of fine-emulsified solutions of cationic collector in non-polar liquids

    International Nuclear Information System (INIS)

    Skrylev, L.D.; Purich, A.N.; Babinets, S.K.

    1980-01-01

    Experimentally shown is a principle possibility of flotation separation of oxo-anions of transition metals by the use of fine-emulsified solutions of cationic collector in non-polar liquids. Ammonium vanadate and sodium tuno.state solutions have been the objects of study. Hexadezilamine has been used as collector. The collector has been introduced in the form of hexadecylamine emulsions in n-decane, in tetrachloromethane or alcohol. Optimum pH value ranges are determined for separation processes

  3. Fine chemistry

    International Nuclear Information System (INIS)

    Laszlo, P.

    1988-01-01

    The 1988 progress report of the Fine Chemistry laboratory (Polytechnic School, France) is presented. The research programs are centered on the renewal of the organic chemistry most important reactions and on the invention of new, highly efficient and highly selective reactions, by applying low cost reagents and solvents. An important research domain concerns the study and fabrication of new catalysts. They are obtained by means of the reactive sputtering of the metals and metal oxydes thin films. The Monte Carlo simulations of the long-range electrostatic interaction in a clay and the obtention of acrylamides from anhydrous or acrylic ester are summarized. Moreover, the results obtained in the field of catalysis are also given. The published papers and the congress communications are included [fr

  4. Autoradiographic techniques to determine noble metal distribution in automotive catalyst substrates

    International Nuclear Information System (INIS)

    Lange, W.H.

    1976-01-01

    The distribution of noble metals in the ceramic substrates of automotive catalytic converter systems is important to the functional characteristics of the systems. A radiotracer technique involving microtomy of bead substrate samples and autoradiography using the resultant thin sections was developed to produce detailed images of the metal distributions. The method is particularly valuable to determine the distribution of one metal in the presence of another to aid in the development of more efficient systems

  5. PIXE identification of fine and coarse particles of aerosol samples and their distribution across Beirut

    Energy Technology Data Exchange (ETDEWEB)

    Roumie, M., E-mail: mroumie@cnrs.edu.lb [Accelerator Laboratory, Lebanese Atomic Energy Commission, National Council for Scientific Research, P.O. Box 11-8281, Beirut (Lebanon); Saliba, N., E-mail: ns30@aub.edu.lb [Department of Chemistry, Faculty of Arts and Sciences, American University of Beirut, Beirut (Lebanon); Nsouli, B., E-mail: bnsouli@cnrs.edu.lb [Accelerator Laboratory, Lebanese Atomic Energy Commission, National Council for Scientific Research, P.O. Box 11-8281, Beirut (Lebanon); Younes, M., E-mail: myriam_younis@hotmail.com [Accelerator Laboratory, Lebanese Atomic Energy Commission, National Council for Scientific Research, P.O. Box 11-8281, Beirut (Lebanon); Noun, M., E-mail: manale_noun@hotmail.com [Accelerator Laboratory, Lebanese Atomic Energy Commission, National Council for Scientific Research, P.O. Box 11-8281, Beirut (Lebanon); Massoud, R., E-mail: rm84@aub.edu.lb [Department of Chemistry, Faculty of Arts and Sciences, American University of Beirut, Beirut (Lebanon)

    2011-12-15

    This study is the first national attempt to assess the levels of PMs in Beirut city and consequently understand air pollution distribution. Aerosol sampling was carried out using three PM{sub 10} and three PM{sub 2.5} samplers which were installed at three locations lying along the SE-NW direction over Beirut. The sampling of PM{sub 10} and PM{sub 2.5} was done during a period extending from May till December 2009. The random collection of the particles (1 in 6 days) was carried out on Teflon filters, for a period of 24-h. The elemental analysis of particulate matter was performed using proton induced X-ray emission technique PIXE at the Lebanese 1.7 MV Tandem-Pelletron accelerator of Beirut. Na, Mg, Al, Si, P, S and Cl were quantified using 1 MeV proton beam, while K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn and Pb were determined using 3 MeV-energy of proton beam.

  6. Fine tuning of transmission features in nanoporous anodic alumina distributed Bragg reflectors

    Science.gov (United States)

    Lim, Siew Yee; Law, Cheryl Suwen; Santos, Abel

    2018-01-01

    This study introduces an innovative apodisation strategy to tune the filtering features of distributed Bragg reflectors based on nanoporous anodic alumina (NAA-DBRs). The effective medium of NAA-DBRs, which is modulated in a stepwise fashion by a pulse-like anodisation approach, is apodised following a logarithmic negative function to engineer the transmission features of NAA-DBRs. We investigate the effect of various apodisation parameters such as apodisation amplitude difference, anodisation period, current density offset and pore widening time, to tune and optimise the optical properties of NAA-DBRs in terms of central wavelength position, full width at half maximum and quality of photonic stop band. The transmission features of NAA-DBRs are shown to be fully controllable with precision across the spectral regions by means of the apodisation parameters. Our study demonstrates that an apodisation strategy can significantly narrow the width and enhance the quality of the characteristic photonic stop band of NAA-DBRs. This rationally designed anodisation approach based on the combination of apodisation and stepwise pulse anodisation enables the development of optical filters with tuneable filtering features to be integrated into optical technologies acting as essential photonic elements in devices such as optical sensors and biosensors.

  7. Fine structure and distribution pattern of antennal sensilla of Lutzomyia longipalpis (Diptera: Psychodidae) sand flies.

    Science.gov (United States)

    Fernandes, Fernando de Freitas; Bahia-Nascimento, Ana Cristina; Pinto, Luciana Conceição; Leal, Cynthia de Sousa; Secundino, Nágila Francinete Costa; Pimenta, Paulo Filemon Paolucci

    2008-11-01

    The specific aims of this work were to examine the antennal sensilla of Lutzomyia longipalpis (Lutz & Neiva 1912) (Diptera: Psychodidae) adults and to characterize their typology and topography, with special attention to olfactory sensilla. The surfaces of the antennal segments of Lu. longipalpis males and females were studied by scanning electron microscopy (SEM). Lu. longipalpis used in the current study were obtained from a colony originating from Lapinha Cave, Minas Gerais state, Brazil. Microtrichiae and 11 subtypes of sensilla were observed and characterized according to the following categories: five subtypes of trichoid sensilla (short, medium, long blunt-tipped, long pointed-tipped, and apical), two coeloconic sensilla (grooved and praying hands), and campaniform, chaetic, basiconic, and squamiform sensilla. SEM analyses showed few differences between males and females in the typology, topography, and quantity of antennal sensilla described. The current study is the first to identify several categories of antennal sensilla of the genus Lutzomyia and their distribution patterns. The identification of these sensillar types may be important in planning future electrophysiological studies to develop alternative measures of control and monitoring of Lu. longipalpis.

  8. Fine-scale tracking and diet information of a marine predator reveals the origin and contrasting spatial distribution of prey

    Science.gov (United States)

    Alonso, Hany; Granadeiro, José P.; Dias, Maria P.; Catry, Teresa; Catry, Paulo

    2018-03-01

    The distribution of many marine organisms is still poorly understood, particularly in oceanic regions. Seabirds, as aerial predators which cover extensive areas across the oceans, can potentially be used to enhance our knowledge on the distribution and abundance of their prey. In this study, we combined tracking data and dietary data from individual Cory's shearwaters Calonectris borealis (n = 68) breeding in Selvagens archipelago, Madeira, Portugal, during the chick-rearing periods of 2011 and 2016, in order to infer prey origin within shearwaters' main foraging areas. The digestion state of each prey item in the diet was assessed and classified; and compared to digestion states from known prey items fed to captive birds. In a novel approach, we combined tracking data with information on the prey digestion duration and data on the transit times from foraging grounds to the colony to estimate the location of prey capture. We found a consistent heterogeneity in prey distribution across four different marine domains: Selvagens, deep-sea, seamounts, and continental shelf. In oceanic areas, the chub mackerel Scomber colias, the main prey of Cory's shearwaters, was strongly associated with seamounts and insular shelves, whereas oceanic species like pilot-fish, flying-squid, flying-fish were clearly associated with deep-sea waters. Sardines Sardina pilchardus, anchovies Engraulis encrasicolus and other coastal species were associated with the African shelf. Prey origin assignment was robust across three different sets of assumptions, and was also supported by information on the digestion state of prey collected over a large independent sampling period (671 samples, collected in 2008-2010). The integration of fine-scale dietary and foraging trip data from marine predators provides a new framework to gain insights into the distribution and abundance of prey species in poorly known oceanic areas.

  9. The GALAH Survey: Stellar streams and how stellar velocity distributions vary with Galactic longitude, hemisphere and metallicity

    Science.gov (United States)

    Quillen, Alice C.; De Silva, Gayandhi; Sharma, Sanjib; Hayden, Michael; Freeman, Ken; Bland-Hawthorn, Joss; Žerjal, Maruša; Asplund, Martin; Buder, Sven; D'Orazi, Valentina; Duong, Ly; Kos, Janez; Lin, Jane; Lind, Karin; Martell, Sarah; Schlesinger, Katharine; Simpson, Jeffrey D.; Zucker, Daniel B.; Zwitter, Tomaz; Anguiano, Borja; Carollo, Daniela; Casagrande, Luca; Cotar, Klemen; Cottrell, Peter L.; Ireland, Michael; Kafle, Prajwal R.; Horner, Jonathan; Lewis, Geraint F.; Nataf, David M.; Ting, Yuan-Sen; Watson, Fred; Wittenmyer, Rob; Wyse, Rosemary

    2018-04-01

    Using GALAH survey data of nearby stars, we look at how structure in the planar (u, v) velocity distribution depends on metallicity and on viewing direction within the Galaxy. In nearby stars with distance d ≲ 1 kpc, the Hercules stream is most strongly seen in higher metallicity stars [Fe/H]>0.2. The Hercules stream peak v value depends on viewed galactic longitude, which we interpret as due to the gap between the stellar stream and more circular orbits being associated with a specific angular momentum value of about 1640 km s-1 kpc. The association of the gap with a particular angular momentum value supports a bar resonant model for the Hercules stream. Moving groups previously identified in Hipparcos observations are easiest to see in stars nearer than 250 pc, and their visibility and peak velocities in the velocity distributions depends on both viewing direction (galactic longitude and hemisphere) and metallicity. We infer that there is fine structure in local velocity distributions that varies over distances of a few hundred pc in the Galaxy.

  10. Fine-scale spatial distribution of orchid mycorrhizal fungi in the soil of host-rich grasslands.

    Science.gov (United States)

    Voyron, Samuele; Ercole, Enrico; Ghignone, Stefano; Perotto, Silvia; Girlanda, Mariangela

    2017-02-01

    Mycorrhizal fungi are essential for the survival of orchid seedlings under natural conditions. The distribution of these fungi in soil can constrain the establishment and resulting spatial arrangement of orchids at the local scale, but the actual extent of occurrence and spatial patterns of orchid mycorrhizal (OrM) fungi in soil remain largely unknown. We addressed the fine-scale spatial distribution of OrM fungi in two orchid-rich Mediterranean grasslands by means of high-throughput sequencing of fungal ITS2 amplicons, obtained from soil samples collected either directly beneath or at a distance from adult Anacamptis morio and Ophrys sphegodes plants. Like ectomycorrhizal and arbuscular mycobionts, OrM fungi (tulasnelloid, ceratobasidioid, sebacinoid and pezizoid fungi) exhibited significant horizontal spatial autocorrelation in soil. However, OrM fungal read numbers did not correlate with distance from adult orchid plants, and several of these fungi were extremely sporadic or undetected even in the soil samples containing the orchid roots. Orchid mycorrhizal 'rhizoctonias' are commonly regarded as unspecialized saprotrophs. The sporadic occurrence of mycobionts of grassland orchids in host-rich stands questions the view of these mycorrhizal fungi as capable of sustained growth in soil. © 2016 The Authors. New Phytologist © 2016 New Phytologist Trust.

  11. Fine-Scale Distributions of Zooplankton in the Northern San Francisco Estuary

    Directory of Open Access Journals (Sweden)

    Wim Kimmerer

    2016-10-01

    Full Text Available doi: http://dx.doi.org/10.15447/sfews.2016v14iss3art2 We studied zooplankton distributions in the upper San Francisco Estuary at nested scales of tens to thousands of meters. The purposes of the study were to assess how well the Interagency Ecological Program (IEP zooplankton monitoring represents abundance, and to investigate the variability of plankton on scales similar to those of foraging by fish. Samples were taken at three sites in the western Sacramento–San Joaquin Delta. We took 18 sets of six samples each with a plankton net along transects from near shore to center channel, and six sets of ten samples in the vicinity of a drifter either in mid-channel or near shore. Sampling took place in June–July 2014 during neap and spring tides, ebb and flood, day and night (transects only. Analysis focused on three common copepod species. Transect samples showed little consistent variation along transects, except that Pseudodiaptomus forbesi was less abundant nearshore than offshore by day at Big Break, the most landward site. The ratio of adults to adults + copepodites was strongly and positively related to turbidity by day but not by night, indicating demersal behavior. Drifter samples showed a minimum standard deviation of log10 sample counts of about 0.1, indicating that about two-thirds of replicate abundance values were within 80 % to 125% of the mean. A measure of difference between plankton samples at pairs of sample points was unrelated to distance between sample points for drifter samples, weakly related along transects for Limnoithona spp. stages, and strongly related for P. forbesi mainly because of the along-transect gradients at Big Break. The IEP sampling program is representative of plankton abundance except for demersal organisms, which can be ten-fold more abundant by night than by day. Small planktivorous fish could forage in patches of up to ~25% higher abundance than the mean.

  12. heavy metals and cyanide distribution in the villages surrounding ...

    African Journals Online (AJOL)

    detection limit) were higher in the wells closest to the Tailing Storage Facility ... Key Words: Heavy metals pollution, Total cyanide, ground water pollution and ..... cyanide, heavy metals and probably other hazardous substances, leakage of.

  13. Numerical simulations of the metallicity distribution in dwarf spheroidal galaxies

    NARCIS (Netherlands)

    Ripamonti, E.; Tolstoy, E.; Helmi, A.; Battaglia, G.; Abel, T.

    2006-01-01

    Abstract: Recent observations show that the number of stars with very low metallicities in the dwarf spheroidal satellites of the Milky Way is low, despite the low average metallicities of stars in these systems. We undertake numerical simulations of star formation and metal enrichment of dwarf

  14. Wigner Distribution Functions as a Tool for Studying Gas Phase Alkali Metal Plus Noble Gas Collisions

    Science.gov (United States)

    2014-03-27

    WIGNER DISTRIBUTION FUNCTIONS AS A TOOL FOR STUDYING GAS PHASE ALKALI METAL PLUS NOBLE GAS COLLISIONS THESIS Keith A. Wyman, Second Lieutenant, USAF...the U.S. Government and is not subject to copyright protection in the United States. AFIT-ENP-14-M-39 WIGNER DISTRIBUTION FUNCTIONS AS A TOOL FOR...APPROVED FOR PUBLIC RELEASE; DISTRIBUTION UNLIMITED AFIT-ENP-14-M-39 WIGNER DISTRIBUTION FUNCTIONS AS A TOOL FOR STUDYING GAS PHASE ALKALI METAL PLUS

  15. Spatial distribution of trace metals in sediments from urban streams of Semarang, Central Java, Indonesia.

    NARCIS (Netherlands)

    Widianarko, B.; Verweij, R.A.; van Gestel, C.A.M.; van Straalen, N.M.

    2000-01-01

    Elevated environmental concentrations of metals are usually associated with the impact of urbanization. The present study is focused on metal contamination in urban sediments. A field survey was carried out to determine the distribution of four metals, i.e., cadmium (Cd), lead (Pb), copper (Cu), and

  16. Development of novel micro swirl mixer for producing fine metal oxide nanoparticles by continuous supercritical hydrothermal method.

    Science.gov (United States)

    Kawasaki, Shin-ichiro; Sue, Kiwamu; Ookawara, Ryuto; Wakashima, Yuichiro; Suzuki, Akira

    2010-01-01

    Novel micro swirl mixers were developed to synthesize nanoparticles, and the effect of their mixing performance on the characteristics of the synthesized nanoparticles was determined. The results were compared with those obtained using simple T-shaped mixers under the same reaction conditions. The synthesis of NiO, whose characteristics depend on the mixing performance of the mixer, was chosen as a model reaction. Initial investigations highlighted that the average particle size decreased from 32 to 23 to 20 nm as the inner diameter of the swirl mixers was decreased from 3.2 mm (Swirl mixer, SM-3.2) to 0.8 mm (Micro swirl mixer, MSM-0.8) to 0.5 mm (Micro swirl mixer, MSM-0.5), respectively. On the other hand, a similar decrease in the average particle size from 34 to 20 nm was observed with a decrease in the inner diameter of the T-shaped mixers from 1.3 mm (Tee union, T-1.3) to 0.3 mm (Micro tee union, T-0.3), respectively. Further, narrow particle size distributions were observed with a decrease in the inner diameter of each mixer. Furthermore, a computational fluid dynamics (CFD) simulation indicated an excellent mixing mechanism, which contributed to the improvement in the heating rate and the formation of nanoparticles of smaller size with a narrow particle size distribution. The result presented here indicates that the micro swirl mixers produce high-quality metal oxide nanoparticles. The size of the obtained particles with improved size distributions was comparable to that of the particles obtained using the T-shaped mixers, although the inner diameter of the swirl mixers was larger. Therefore, preliminary evidence suggests that the swirl flow mixers have the ability to produce rapid and homogeneous fluid mixing, thus controlling the particle size.

  17. Distributions and natural levels of related metals in a trophic pathway

    International Nuclear Information System (INIS)

    Lemons, J.D.

    1976-06-01

    The first objective was to test the hypothesis that metal distributions and trends in organisms are, in part, a function of metal positions in the periodic table in unpolluted ecosystems. The data have shown that large soil crustal abundance differences of related elements (e.g. alkali metals) are proportionately approximated in higher organisms. Concentration factors for related nutritious and nonessential and toxic metals were determined along a trophic pathway. When the concentration factors were reported as the concentration of a particular metal by itself, all metal concentrations increased along the trophic pathway. The second objective of this study was to test the hypothesis that distributions and natural levels of chemically related nonessential and toxic metals can better be known when the metals are reported as a ratio, in ash, of the nonessential or toxic metal to its chemically related nutritious metal (e.g. strontium/calcium) as the metals are transferred through trophic pathways. The data have shown that when this method of reporting metal abundances in trophic levels is used, nonessential and toxic metals are discriminated against, relative to their chemically related nutritious metal, as the metals are transferred through the trophic pathway levels. The third objective was designed to test the hypothesis that surface deposition of toxic metals upon plants influences the trends of metal abundances through trophic pathways. This study indicates that metal pollution in the form of deposition upon plant surfaces bypasses the discrimination mechanisms in plants, and consequently elevates the total body burden in herbivores. It is likely that there is no herbivore defense for this type of metal exposure, because herbivores have probably come to rely, in part, upon the discriminatory mechanism of plants throughout the course of evolutionary history to keep toxic metal burdens low

  18. Method of pyrolytic decomposition and coking of a mixture of finely distributed solid or semisolid carbonaceous material and hydrocarbon oils

    Energy Technology Data Exchange (ETDEWEB)

    1933-09-09

    A method of pyrolytic decomposition and coking of a mixture of finely distributed of solid or semi-solid carbonaceous material and hydrocarbon oils is disclosed whereby the mixture is exposed to a decomposition temperature and later is brought into the zone of decomposition where vapors are separated from the unvaporized residue and the vapors are exposed to fractional condensation for the purpose of obtaining a light product of distillation. The method is characterized by the mixture being exposed to heating by means of indirect exchange of heat in a heating zone or by means of a direct addition of a hot heat-conducting medium, or by means of both the mentioned indirect exchange of heat and direct heat under such conditions that the unvaporized residue obtained from the thus-heated mixture in the decomposition zone is transformed to solid coke in this zone by being heated to coking temperature in a comparatively thin layer on the surface of the decomposition zone that has been heated to a high temperature.

  19. About the Distribution of Metal Objects in Prepalatial Crete

    Directory of Open Access Journals (Sweden)

    Borja Legarra Herrero

    2004-11-01

    Full Text Available Although metal objects have been used as evidence in different interpretations of the socioeconomic changes identified in Prepalatial Crete (c.3100-1900 BC, they constitute an understudied category of material. This paper argues that metal objects on Crete were subject to complex processes regarding the creation of meaning; a more comprehensive appraisal of metal objects on the island may cast new light on these issues. Copper-based, gold, lead and silver objects are investigated from their ore extraction locations outside Crete to their final deposition, linking the different steps of the process of creating an artefact with different layers of meanings for the metal and, subsequently, for the finished objects. This study evaluates differences in the use of metals, with a particular focus on their intra-island depositional patterns. It seeks to identify differences in the roles of metals within Cretan communities as well as regional fashions in the use of metal objects. It is suggested that metals had different characters since their depositional patterns vary, and that people consciously chose certain metals to make specific objects and also used metal objects in different ways, reflecting the socio-economic context for each region.

  20. Fine-root growth in a forested bog is seasonally dynamic, but shallowly distributed in nutrient-poor peat

    Science.gov (United States)

    Colleen M. Iversen; Joanne Childs; Richard J. Norby; Todd A. Ontl; Randall K. Kolka; Deanne J. Brice; Karis J. McFarlane; Paul J. Hanson

    2017-01-01

    Background and aims. Fine roots contribute to ecosystem carbon, water, and nutrient fluxes through resource acquisition, respiration, exudation, and turnover, but are understudied in peatlands. We aimed to determine how the amount and timing of fine-root growth in a forested, ombrotrophic bog varied across gradients of vegetation density, peat...

  1. DISTRIBUTION OF HEAVY METALS AMONG THE COMPONENTS OF FRESHWATER ECOSYSTEMS (REVIEW)

    OpenAIRE

    N. Kolesnyk

    2014-01-01

    Purpose. To review scientific sources on the distribution of heavy metals among the components of freshwater ecosystems. Findings. The review of the works of many scientists showed that heavy metals are widespread in the biotic and abiotic components of freshwater ecosystems. The article highlights the distribution of heavy metals in water, bottom sediments, natural food base, fish organs and tissues. It has been shown that as a result of global pollution of the ecosystem, the majority of...

  2. Influence of fine process particles enriched with metals and metalloids on Lactuca sativa L. leaf fatty acid composition following air and/or soil-plant field exposure

    International Nuclear Information System (INIS)

    Schreck, Eva; Laplanche, Christophe; Le Guédard, Marina; Bessoule, Jean-Jacques; Austruy, Annabelle; Xiong, Tiantian; Foucault, Yann; Dumat, Camille

    2013-01-01

    We investigate the effect of both foliar and root uptake of a mixture of metal(loid)s on the fatty acid composition of plant leaves. Our objectives are to determine whether both contamination pathways have a similar effect and whether they interact. Lactuca sativa L. were exposed to fine process particles enriched with metal(loid)s in an industrial area. Data from a first experiment were used to conduct an exploratory statistical analysis which findings were successfully cross-validated by using the data from a second one. Both foliar and root pathways impact plant leaf fatty acid composition and do not interact. Z index (dimensionless quantity), weighted product of fatty acid concentration ratios was built up from the statistical analyses. It provides new insights on the mechanisms involved in metal uptake and phytotoxicity. Plant leaf fatty acid composition is a robust and fruitful approach to detect and understand the effects of metal(loid) contamination on plants. -- Highlights: •The study compares foliar and root transfers of metal(loid)s and their effects on plants. •Field experiments are performed combining ecotoxicological and statistical analyses. •The use of leaf fatty acid composition is a relevant indicator of exposure pathway. •The uptake pathways are independent, with an additive effect in terms of phytotoxicity. -- Metal uptake via both foliar and root pathways alters in a distinctive manner the fatty acid composition of lettuce leaves

  3. Fine-grained sediment spatial distribution on the basis of a geostatistical analysis: Example of the eastern Bay of the Seine (France)

    Science.gov (United States)

    Méar, Y.; Poizot, E.; Murat, A.; Lesueur, P.; Thomas, M.

    2006-12-01

    The eastern Bay of the Seine (English Channel) was the subject in 1991 of a sampling survey of superficial sediments. Geostatistic tools were used to examine the complexity of the spatial distribution of the fine-grained fraction (discussed. Within this sedimentary unit, the distribution of the fine fraction is very heterogeneous, with mud patches of less than 4000 m diameter; the boundary between these mud patches and their substratum is very sharp. The distribution of this fine fraction appears to be controlled by an anticyclonic eddy located off the Pays de Caux. Under the influence of this, the suspended material expelled from the Seine estuary moves along the coast and swings off Antifer harbour, towards the NW. It is trapped within this eddy because of the settling of suspended particulate matter. Both at a general scale and a local scale the morphology (whether inherited or due to modern processes) has a strong influence on the spatial distribution of the fine fraction. At the general scale, the basin-like shape of the area facilitates the silting, and the presence of the submarine dunes, called "Ridins d'Antifer", clearly determines the northern limit of the muddy zone. At a local scale, the same influence is obvious: paleovalleys trap the fine sediments, whereas isolated sand dunes and ripples limit the silting. This duality of role of the morphology is therefore one of the reasons why the muddy surface is extremely heterogeneous spatially. The presence of an important population of suspension feeding echinoderm, the brittle-star Ophiothrix fragilis Abildgaard, has led to a local increase in the silting, and to the modification of the physicochemical and sedimentological parameters. A complex relationship is shown to occur between the amount of fine fraction and the number of brittle-stars (ind. m -2). Classical statistical methods are not appropriate to study the spatial distribution of the mud fraction, because the spatial component of the percentage of

  4. Occurrence and distribution of heavy metals in indoor settled ...

    African Journals Online (AJOL)

    The results showed widespread heavy metals contamination especially Fe and Zn, which were present as the highest concentration while Cd was the lowest in the settled particles (dust). The order of occurrence of heavy metals in settled particles (dust) collected indoor in 2007 and 2008 respectively were as follows, ...

  5. Sewage sludge pyrolysis - the distribution of heavy metals

    Energy Technology Data Exchange (ETDEWEB)

    Kistler, R.; Widmer, F.; Brunner, P.

    1986-01-01

    The paper informs about the heavy metal contents of sewage sludges and discusses the origin of household, industry and surface sewerage of the respective heavy metals. The study aimed at assessing whether and in how far heavy metal volatility may be checked by reducing the temperature during sewage sludge pyrolysis. The testing equipment used was made of glass/silica glass. Instead of in particles heavy metals were precipitated in the gaseous state. Except from mercury heavy metals are retained by the ashes up to temperatures from 450 to 555/sup 0/C. Due to the persistence of mercury care should be taken to keep the sewerage clear of it from the very beginning. Emissions caused by reactor materials can be avoided by choosing appropriate pyrolysis reactors.

  6. Visualizing Metal Content and Intracellular Distribution in Primary Hippocampal Neurons with Synchrotron X-Ray Fluorescence.

    Directory of Open Access Journals (Sweden)

    Robert A Colvin

    Full Text Available Increasing evidence suggests that metal dyshomeostasis plays an important role in human neurodegenerative diseases. Although distinctive metal distributions are described for mature hippocampus and cortex, much less is known about metal levels and intracellular distribution in individual hippocampal neuronal somata. To solve this problem, we conducted quantitative metal analyses utilizing synchrotron radiation X-Ray fluorescence on frozen hydrated primary cultured neurons derived from rat embryonic cortex (CTX and two regions of the hippocampus: dentate gyrus (DG and CA1. Comparing average metal contents showed that the most abundant metals were calcium, iron, and zinc, whereas metals such as copper and manganese were less than 10% of zinc. Average metal contents were generally similar when compared across neurons cultured from CTX, DG, and CA1, except for manganese that was larger in CA1. However, each metal showed a characteristic spatial distribution in individual neuronal somata. Zinc was uniformly distributed throughout the cytosol, with no evidence for the existence of previously identified zinc-enriched organelles, zincosomes. Calcium showed a peri-nuclear distribution consistent with accumulation in endoplasmic reticulum and/or mitochondria. Iron showed 2-3 distinct highly concentrated puncta only in peri-nuclear locations. Notwithstanding the small sample size, these analyses demonstrate that primary cultured neurons show characteristic metal signatures. The iron puncta probably represent iron-accumulating organelles, siderosomes. Thus, the metal distributions observed in mature brain structures are likely the result of both intrinsic neuronal factors that control cellular metal content and extrinsic factors related to the synaptic organization, function, and contacts formed and maintained in each region.

  7. Coarse- and fine-scale patterns of distribution and habitat selection places an Amazonian floodplain curassow in double jeopardy

    Directory of Open Access Journals (Sweden)

    Gabriel A. Leite

    2018-05-01

    Full Text Available Patterns of habitat selection are influenced by local productivity, resource availability, and predation risk. Species have taken millions of years to hone the macro- and micro-habitats they occupy, but these may now overlap with contemporary human threats within natural species ranges. Wattled Curassow (Crax globulosa, an endemic galliform species of the western Amazon, is threatened by both hunting and habitat loss, and is restricted to white-water floodplain forests of major Amazonian rivers. In this study conducted along the Juruá River, Amazonas, Brazil, we quantified the ranging ecology and fine-scale patterns of habitat selection of the species. We estimated the home range size of C. globulosa using conventional VHF telemetry. To estimate patterns of habitat selection, we used geo-locations of day ranges to examine the extent and intensity of use across the floodplain, which were then compared to a high-resolution flood map of the study area. We captured two females and one male, which we monitored for 13 months between September 2014 and September 2015. Average home range size was 283 ha, based on the 95% aLoCoH estimator. Wattled Curassows selected areas of prolonged flood pulses (six to eight months/year and had a consistent tendency to be near open water, usually in close proximity to river banks and lakes, especially during the dry season. Amazonian floodplains are densely settled, and the small portions of floodplain habitat used by Wattled Curassows are both the most accessible to hunters and most vulnerable to deforestation. As a result, the geographic and ecological distribution of Wattled Curassows places them at much higher extinction risk at multiple spatial scales, highlighting the need to consider habitat preferences within their conservation strategy.

  8. Dietary toxicity of field-contaminated invertebrates to marine fish: effects of metal doses and subcellular metal distribution.

    Science.gov (United States)

    Dang, Fei; Rainbow, Philip S; Wang, Wen-Xiong

    2012-09-15

    There is growing awareness of the toxicological effects of metal-contaminated invertebrate diets on the health of fish populations in metal-contaminated habitats, yet the mechanisms underlying metal bioaccumulation and toxicity are complex. In the present study, marine fish Terapon jurbua terepon were fed a commercial diet supplemented with specimens of the polychaete Nereis diversicolor or the clam Scrobicularia plana, collected from four metal-impacted estuaries (Tavy, Restronguet Creek, West Looe, Gannel) in southwest England, as environmentally realistic metal sources. A comparative toxicological evaluation of both invertebrates showed that fish fed S. plana for 21 d exhibited evident mortality compared to those fed N. diversicolor. Furthermore, a spatial effect on mortality was observed. Differences in metal doses rather than subcellular metal distributions between N. diversicolor and S. plana appeared to be the cause of such different mortalities. Partial least squares regression was used to evaluate the statistical relationship between multiple-metal doses and fish mortality, revealing that Pb, Fe, Cd and Zn in field-collected invertebrates co-varied most strongly with the observed mortality. This study provides a step toward exploring the underlying mechanism of dietary toxicity and identifying the potential causality in complex metal mixture exposures in the field. Copyright © 2012 Elsevier B.V. All rights reserved.

  9. Investigation of the origin and distribution of heavy metals around ...

    African Journals Online (AJOL)

    2010-04-28

    Apr 28, 2010 ... JS Ogola1*, HR Mundalamo1 and G Brandl2. 1Department of Mining and ..... CSIR, Environmental Services, Pretoria,. South Africa. ... chemical orientation studies and the platinum potential of Jamaica. Trans. Inst. Min. Metall.

  10. Distributed Bragg grating frequency control in metallic nano lasers

    NARCIS (Netherlands)

    Marell, M.J.H.; Hill, M.T.

    2010-01-01

    We show that Bragg gratings can be readily incorporated into metallic nano-lasers which exploit waveguides with semiconductor cores, via modulation of the waveguide width. This provides a simple way to implement laser wavelength control.

  11. Distribution of Heavy Metals in Organs of Freshwater Fishes from ...

    African Journals Online (AJOL)

    MBI

    2015-12-24

    Dec 24, 2015 ... indicate that the concentrations of the heavy metals in the samples are generally well above the respective recommended ... weathering processes on rocks and soils (Babel and. Opiso ..... Source apportionment of suspended.

  12. Seasonal and spatial distribution of metals in surface sediment of an urban estuary

    International Nuclear Information System (INIS)

    Buggy, Conor J.; Tobin, John M.

    2008-01-01

    Aquatic pollution by metals is of concern because of various toxic effects to marine life. The Tolka Estuary, Co. Dublin, Ireland, is a typical Irish urban estuary. It has a significant metal loading originating from the urban environment. Results of a 25 month analysis of cadmium, copper, lead and zinc spatial and temporal distribution over 10 sample locations in this estuary are presented in this paper. Metal concentrations were analysed using differential pulse polarography. Significant seasonal and spatial trends in metal distribution were observed over the 25 months. Sediment metal concentrations gradually increased (30-120%) in spring to a maximum at the end of summer which was followed by a decrease in winter months (30-60%). Sediment organic matter (OM) concentrations exhibited similar seasonal trends and a positive correlation between OM and metal distributions was observed, implying OM had an influence on metal distributions over time. - Assessment and correlation of the seasonal and spatial distribution of metals and organic matter in surface sediment of an urban estuary

  13. Heavy metals distribution in the Dead Sea black mud, Jordan

    International Nuclear Information System (INIS)

    Momani, K.; El-Hasan, T.; Auaydeh, S.

    2009-01-01

    The concentrations of trace metals (Fe, Mn, Ni, Zn, Co, Cr, Cu and Pb) were investigated in the Dead Sea black mud and river sediments in the northern basin of the Dead Sea region, Jordan. The pH of the mud was slightly above 8 while it was around 6 for the seawater. All analyzed heavy metal content in the black mud, except Pb, was less than their contents in other types of mud. Tlis might be due to the effect of the mildly acideic pH of seawater, which would enhance the metal solubility or incorporation within salt mineral structure, rather than precipitation. The sequential extraction results showed that Ni and Co transferred into the carbonate fraction, Mn is found mostly as manganese-iron oxide, and the residual phase contained Cr, Cu, Fe,and Pb. This study illustrated that the black mud had low heavy metal contents, thus indicating low toxicity. additionally, it shows insignificance effect of the mixing of freshwater with seawater on the heavy metal contents in the black mud. (authors).

  14. Distribution and risk assessment of trace metals in sediments from Yangtze River estuary and Hangzhou Bay, China.

    Science.gov (United States)

    Li, Feipeng; Mao, Lingchen; Jia, Yubao; Gu, Zhujun; Shi, Weiling; Chen, Ling; Ye, Hua

    2018-01-01

    The Yangtze River estuary (YRE) and Hangzhou Bay (HZB) is of environmental significance because of the negative impact from industrial activities and rapid development of aquaculture on the south bank of HZB (SHZB) in recent years. This study investigated the distribution and risk assessments of trace metals (Cr, Cu, Zn, Hg, Pb, and Cd) accumulated in surface sediments by sampling in YRE, outer and south HZB. Copper and Zn concentration (avg. 35.4 and 98.7 mg kg -1 , respectively) in surface sediments were generally higher than the background suggesting a widespread of Cu and Zn in the coastal area of Yangtze River Delta. High concentrations of Cu (~ 42 mg kg -1 ), Zn (~ 111 mg kg -1 ), Cd (~ 0.27 mg kg -1 ), and Hg (~ 0.047 mg kg -1 ) were found in inner estuary of YRE and decreased offshore as a result of terrestrial input and dilution effect of total metal contents by "cleaner" sediments from the adjacent sea. In outer HZB, accumulation of terrestrial derived metal has taken place near the Zhoushan Islands. Increase in sediment metal concentration from the west (inner) to the east (outer) of SHZB gave rise to the input of fine-grained sediments contaminated with metals from outer bay. According the results from geoaccumulation index, nearly 75% of samples from YRE were moderately polluted (1.0 < I geo  < 2.0) by Cd. Cadmium and Hg contributed for 80~90% to the potential ecological risk index in the YRE and HZB, with ~ 72% sites in HZB under moderate risk (150 ≤ RI < 300) especially near Zhoushan Islands.

  15. THE STELLAR METALLICITY DISTRIBUTION FUNCTION OF THE GALACTIC HALO FROM SDSS PHOTOMETRY

    International Nuclear Information System (INIS)

    An, Deokkeun; Beers, Timothy C.; Johnson, Jennifer A.; Pinsonneault, Marc H.; Lee, Young Sun; Bovy, Jo; Ivezić, Željko; Carollo, Daniela; Newby, Matthew

    2013-01-01

    We explore the stellar metallicity distribution function of the Galactic halo based on SDSS ugriz photometry. A set of stellar isochrones is calibrated using observations of several star clusters and validated by comparisons with medium-resolution spectroscopic values over a wide range of metal abundance. We estimate distances and metallicities for individual main-sequence stars in the multiply scanned SDSS Stripe 82, at heliocentric distances in the range 5-8 kpc and |b| > 35°, and find that the in situ photometric metallicity distribution has a shape that matches that of the kinematically selected local halo stars from Ryan and Norris. We also examine independent kinematic information from proper-motion measurements for high Galactic latitude stars in our sample. We find that stars with retrograde rotation in the rest frame of the Galaxy are generally more metal poor than those exhibiting prograde rotation, which is consistent with earlier arguments by Carollo et al. that the halo system comprises at least two spatially overlapping components with differing metallicity, kinematics, and spatial distributions. The observed photometric metallicity distribution and that of Ryan and Norris can be described by a simple chemical evolution model by Hartwick (or by a single Gaussian distribution); however, the suggestive metallicity-kinematic correlation contradicts the basic assumption in this model that the Milky Way halo consists primarily of a single stellar population. When the observed metallicity distribution is deconvolved using two Gaussian components with peaks at [Fe/H] ≈ –1.7 and –2.3, the metal-poor component accounts for ∼20%-35% of the entire halo population in this distance range.

  16. Influence of fine process particles enriched with metals and metalloids on Lactuca sativa L. leaf fatty acid composition following air and/or soil-plant field exposure.

    Science.gov (United States)

    Schreck, Eva; Laplanche, Christophe; Le Guédard, Marina; Bessoule, Jean-Jacques; Austruy, Annabelle; Xiong, Tiantian; Foucault, Yann; Dumat, Camille

    2013-08-01

    We investigate the effect of both foliar and root uptake of a mixture of metal(loid)s on the fatty acid composition of plant leaves. Our objectives are to determine whether both contamination pathways have a similar effect and whether they interact. Lactuca sativa L. were exposed to fine process particles enriched with metal(loid)s in an industrial area. Data from a first experiment were used to conduct an exploratory statistical analysis which findings were successfully cross-validated by using the data from a second one. Both foliar and root pathways impact plant leaf fatty acid composition and do not interact. Z index (dimensionless quantity), weighted product of fatty acid concentration ratios was built up from the statistical analyses. It provides new insights on the mechanisms involved in metal uptake and phytotoxicity. Plant leaf fatty acid composition is a robust and fruitful approach to detect and understand the effects of metal(loid) contamination on plants. Copyright © 2013 Elsevier Ltd. All rights reserved.

  17. Heavy Metallic Element Distribution in Cisadane River Estuary's Water and Sediment

    Directory of Open Access Journals (Sweden)

    M. Taufik Kaisupy

    2006-04-01

    Full Text Available Observation of heavy metallic elements in Cisadane River Estuary has been done in July and November 2005. The results show that heavy metallic elements content in seawater is lower and still below the treshold value stated by government for fisheries. There was an indication of heavy metallic elements on sediment. Distribution of Pb on July and of Cu on November 2005 were found higher near the coast and decrease towards the sea, and commonly were found in front of estuary such as Cisadane, Muara Saban and Tanjung Pasir. High Pb and Zn distributions on November 2005 were found only in front of Cisadane estuary. Cd distribution of Cisadane estuary was constant at all station but did not show any correlation with the distance of station and estuary. The Cd content on July and November 2005 is lower than 0,001 ppm. Generally, heavy metallic elements content have a uniform distribution at all stations inspite of its distance to estuary.

  18. Distribution of six heavy metals in contaminated clay soils before and after extractive cleaning

    NARCIS (Netherlands)

    Tuin, B.J.W.; Tels, M.

    1990-01-01

    A sequential extraction procedure according to Tessier et al. is carried out to compare the distribution of six metals (Cd, Cr, Cu, Ni, Pb and Zn) in contaminated clay soils before and after extractive cleaning. Extraction of metals from the ‘soil fractions’ with 0.1 N HC1 or 0.1 M EDTA becomes more

  19. 12 Trace Metals Distribution in Fish Tissues, Bottom Sediments and ...

    African Journals Online (AJOL)

    `123456789jkl''''#

    Abstract. Water samples, bottom sediments, Tilapia, and Cat Fish from Okumeshi River in Delta state of Nigeria were analysed ... Keywords: Trace metals, Fish Tissues, Water, Bottom sediments, Okumeshi River. Introduction ..... Grey Mangroove Avicemmia marina (Forsk). ... sewage treatment plant oulet pipe extension on.

  20. Studies on the occurrence and distribution of heavy metals in ...

    African Journals Online (AJOL)

    The bacteria isolated and identified were. Bacillus subtilis, Bacillus licheniformis, Arthrobacter sp and Achromobacter sp. Fungi isolated were Saccharomyces cerevisiae, Candida utilissima and Sporobolomyces sp. The values for heavy metals for all zones are of public health significance and pose a threat to the survival of ...

  1. Metal Distribution and Bioaccumulation in Water and Fish of a ...

    African Journals Online (AJOL)

    A study was conducted to investigate the metal (copper, zinc and manganese) concentrations in the surface water and fish of a man-made lake receiving agricultural and domestic effluents in Ibadan, Nigeria. The lake (Main Lake, IITA) is a site of drinking water abstraction and the major water source for the surrounding ...

  2. Advanced analysis of metal distributions in human hair

    International Nuclear Information System (INIS)

    Kempson, Ivan M.; Skinner, William M.

    2006-01-01

    A variety of techniques (secondary electron microscopy with energy dispersive X-ray analysis, time-of-flight-secondary ion mass spectrometry, and synchrotron X-ray fluorescence) were utilized to distinguish metal contamination occurring in hair arising from endogenous uptake from an individual exposed to a polluted environment, in this case a lead smelter. Evidence was sought for elements less affected by contamination and potentially indicative of biogenic activity. The unique combination of surface sensitivity, spatial resolution, and detection limits used here has provided new insight regarding hair analysis. Metals such as Ca, Fe, and Pb appeared to have little representative value of endogenous uptake and were mainly due to contamination. Cu and Zn, however, demonstrate behaviors worthy of further investigation into relating hair concentrations to endogenous function.

  3. THE BIMODAL METALLICITY DISTRIBUTION OF THE COOL CIRCUMGALACTIC MEDIUM AT z ∼< 1

    International Nuclear Information System (INIS)

    Lehner, N.; Howk, J. C.; Tripp, T. M.; Tumlinson, J.; Thom, C.; Fox, A. J.; Prochaska, J. X.; Werk, J. K.; O'Meara, J. M.; Ribaudo, J.

    2013-01-01

    We assess the metal content of the cool (∼10 4 K) circumgalactic medium (CGM) about galaxies at z ∼ H I ∼ H I selection avoids metallicity biases inherent in many previous studies of the low-redshift CGM. We compare the column densities of weakly ionized metal species (e.g., O II, Si II, Mg II) to N H I in the strongest H I component of each absorber. We find that the metallicity distribution of the LLS (and hence the cool CGM) is bimodal with metal-poor and metal-rich branches peaking at [X/H] ≅ –1.6 and –0.3 (or about 2.5% and 50% solar metallicities). The cool CGM probed by these LLS is predominantly ionized. The metal-rich branch of the population likely traces winds, recycled outflows, and tidally stripped gas; the metal-poor branch has properties consistent with cold accretion streams thought to be a major source of fresh gas for star forming galaxies. Both branches have a nearly equal number of absorbers. Our results thus demonstrate there is a significant mass of previously undiscovered cold metal-poor gas and confirm the presence of metal enriched gas in the CGM of z ∼< 1 galaxies.

  4. The impact of the Fermi-Dirac distribution on charge injection at metal/organic interfaces.

    Science.gov (United States)

    Wang, Z B; Helander, M G; Greiner, M T; Lu, Z H

    2010-05-07

    The Fermi level has historically been assumed to be the only energy-level from which carriers are injected at metal/semiconductor interfaces. In traditional semiconductor device physics, this approximation is reasonable as the thermal distribution of delocalized states in the semiconductor tends to dominate device characteristics. However, in the case of organic semiconductors the weak intermolecular interactions results in highly localized electronic states, such that the thermal distribution of carriers in the metal may also influence device characteristics. In this work we demonstrate that the Fermi-Dirac distribution of carriers in the metal has a much more significant impact on charge injection at metal/organic interfaces than has previously been assumed. An injection model which includes the effect of the Fermi-Dirac electron distribution was proposed. This model has been tested against experimental data and was found to provide a better physical description of charge injection. This finding indicates that the thermal distribution of electronic states in the metal should, in general, be considered in the study of metal/organic interfaces.

  5. Modelling Deep Water Habitats to Develop a Spatially Explicit, Fine Scale Understanding of the Distribution of the Western Rock Lobster, Panulirus cygnus

    Science.gov (United States)

    Hovey, Renae K.; Van Niel, Kimberly P.; Bellchambers, Lynda M.; Pember, Matthew B.

    2012-01-01

    Background The western rock lobster, Panulirus cygnus, is endemic to Western Australia and supports substantial commercial and recreational fisheries. Due to and its wide distribution and the commercial and recreational importance of the species a key component of managing western rock lobster is understanding the ecological processes and interactions that may influence lobster abundance and distribution. Using terrain analyses and distribution models of substrate and benthic biota, we assess the physical drivers that influence the distribution of lobsters at a key fishery site. Methods and Findings Using data collected from hydroacoustic and towed video surveys, 20 variables (including geophysical, substrate and biota variables) were developed to predict the distributions of substrate type (three classes of reef, rhodoliths and sand) and dominant biota (kelp, sessile invertebrates and macroalgae) within a 40 km2 area about 30 km off the west Australian coast. Lobster presence/absence data were collected within this area using georeferenced pots. These datasets were used to develop a classification tree model for predicting the distribution of the western rock lobster. Interestingly, kelp and reef were not selected as predictors. Instead, the model selected geophysical and geomorphic scalar variables, which emphasise a mix of terrain within limited distances. The model of lobster presence had an adjusted D2 of 64 and an 80% correct classification. Conclusions Species distribution models indicate that juxtaposition in fine scale terrain is most important to the western rock lobster. While key features like kelp and reef may be important to lobster distribution at a broad scale, it is the fine scale features in terrain that are likely to define its ecological niche. Determining the most appropriate landscape configuration and scale will be essential to refining niche habitats and will aid in selecting appropriate sites for protecting critical lobster habitats. PMID

  6. Modelling deep water habitats to develop a spatially explicit, fine scale understanding of the distribution of the western rock lobster, Panulirus cygnus.

    Directory of Open Access Journals (Sweden)

    Renae K Hovey

    Full Text Available BACKGROUND: The western rock lobster, Panulirus cygnus, is endemic to Western Australia and supports substantial commercial and recreational fisheries. Due to and its wide distribution and the commercial and recreational importance of the species a key component of managing western rock lobster is understanding the ecological processes and interactions that may influence lobster abundance and distribution. Using terrain analyses and distribution models of substrate and benthic biota, we assess the physical drivers that influence the distribution of lobsters at a key fishery site. METHODS AND FINDINGS: Using data collected from hydroacoustic and towed video surveys, 20 variables (including geophysical, substrate and biota variables were developed to predict the distributions of substrate type (three classes of reef, rhodoliths and sand and dominant biota (kelp, sessile invertebrates and macroalgae within a 40 km(2 area about 30 km off the west Australian coast. Lobster presence/absence data were collected within this area using georeferenced pots. These datasets were used to develop a classification tree model for predicting the distribution of the western rock lobster. Interestingly, kelp and reef were not selected as predictors. Instead, the model selected geophysical and geomorphic scalar variables, which emphasise a mix of terrain within limited distances. The model of lobster presence had an adjusted D(2 of 64 and an 80% correct classification. CONCLUSIONS: Species distribution models indicate that juxtaposition in fine scale terrain is most important to the western rock lobster. While key features like kelp and reef may be important to lobster distribution at a broad scale, it is the fine scale features in terrain that are likely to define its ecological niche. Determining the most appropriate landscape configuration and scale will be essential to refining niche habitats and will aid in selecting appropriate sites for protecting critical

  7. Modelling deep water habitats to develop a spatially explicit, fine scale understanding of the distribution of the western rock lobster, Panulirus cygnus.

    Science.gov (United States)

    Hovey, Renae K; Van Niel, Kimberly P; Bellchambers, Lynda M; Pember, Matthew B

    2012-01-01

    The western rock lobster, Panulirus cygnus, is endemic to Western Australia and supports substantial commercial and recreational fisheries. Due to and its wide distribution and the commercial and recreational importance of the species a key component of managing western rock lobster is understanding the ecological processes and interactions that may influence lobster abundance and distribution. Using terrain analyses and distribution models of substrate and benthic biota, we assess the physical drivers that influence the distribution of lobsters at a key fishery site. Using data collected from hydroacoustic and towed video surveys, 20 variables (including geophysical, substrate and biota variables) were developed to predict the distributions of substrate type (three classes of reef, rhodoliths and sand) and dominant biota (kelp, sessile invertebrates and macroalgae) within a 40 km(2) area about 30 km off the west Australian coast. Lobster presence/absence data were collected within this area using georeferenced pots. These datasets were used to develop a classification tree model for predicting the distribution of the western rock lobster. Interestingly, kelp and reef were not selected as predictors. Instead, the model selected geophysical and geomorphic scalar variables, which emphasise a mix of terrain within limited distances. The model of lobster presence had an adjusted D(2) of 64 and an 80% correct classification. Species distribution models indicate that juxtaposition in fine scale terrain is most important to the western rock lobster. While key features like kelp and reef may be important to lobster distribution at a broad scale, it is the fine scale features in terrain that are likely to define its ecological niche. Determining the most appropriate landscape configuration and scale will be essential to refining niche habitats and will aid in selecting appropriate sites for protecting critical lobster habitats.

  8. The distribution of metal elements in plant leaf. Second report

    International Nuclear Information System (INIS)

    Ohnishi, Toshiyuki; Masuko, Shoji; Noya, Youichi; Kasahara, Shigeru

    2002-01-01

    We have reported in first report as to metal elements containing in some leaf such as clethra, bamboo and maple. This time, we measured the contents zinc, cesium and cobalt about clethra, maple in root, blanch and anthotaxy. As to cesium, the density contained in anthotaxy of clethra was 1.5 times as much as that of soil. In the same manner, the density of cobalt contained in the blanch of clethra was 10 times as much as that of maple. As to zinc, the difference contained root, blanch and leaf between clethra and maple were small. (author)

  9. Occurrence and distribution of selected heavy metals in the surface sediments of South Brittany coastal waters: An assessment using pollution indicators

    Science.gov (United States)

    Ong, M. C.; Menier, D.; Noor Azhar, M. S.; Dupont, V.; Révillon, S.

    2012-04-01

    In order to avoid the pollution of heavy metals in South Brittany water, it is necessary to establish the data and understand the mechanisms influencing the distribution of heavy metals of the area. One of the aims of this work was to assess heavy metals contamination in Gulf of Morbihan and Quiberon Bay. Another aim was to use interpolation surfaces per metals to assess the contamination separately per metal. A total of 196 bottom sediment samples were collected from the coastal waters in order to determine the spatial concentration of Cr, Mn, Co, Cu, Zn, Cd and Pb by Inductively Coupled Plasma Mass Spectrometry (ICPMS) after acid digestion. The average heavy metal concentrations are ranked as follows: Mn>Zn>Cr>Pb>Cu>Cu>Cd. In the gulf, metal enrichments observed compared to the bay environment may due river run-off from three major river (Auray, Le Marle and Novalo rivers) which carried municipal waste and maritime activities along the coastal area within the gulf. Beside those factors, the natural factors such as the sheltered basin morphology itself, fine sediment and low hydrodynamic regime which favour the in situ accumulation of pollutants. The level of pollution levels attributed to heavy metals was evaluated using several pollution indicators in order to determine anthropogenically derived sediment contamination. Comparison to sediment quality guidelines (SQGs), enrichment factors (EFs), index of geoaccumulation (Igeo) and contamination factors (CF) based on reference element and background value to compensate for the influence of the natural variability in sediment mineralogy and to assess whether the concentration observed in surface sediment represent background and contaminated levels and visualize using ArcGIS software. These analyses validated that the bottom sediment only enriched in Pb and the other metals in most sample are not due to artificial contamination. Overall, geochemistry of the samples show the effect of both natural and anthropogenic

  10. [Effects of neighbor competition on growth, fine root morphology and distribution of Schima superba and Cunninghamia lanceolata in different nutrient environments].

    Science.gov (United States)

    Yao, Jia Bao; Chu, Xiu Li; Zhou, Zhi Chun; Tong, Jian She; Wang, Hui; Yu, Jia Zhong

    2017-05-18

    Taking Schima superba and Cunninghamia lanceolata as test materials, a pot experiment was conducted to simulate the heterogeneous and homogeneous forest soil nutrient environments, and design three planting modes including single plant, two-strain pure plant and two-strain mixed ones to reason the promotion in mixed S. superba and C. lanceolata plantation and the competitive advantage of S. superba. Results showed that compared with the homogeneous nutrient environment, both S. superba and C. lanceolata had the higher seedling height and dry matter accumulation, when mixed in the heterogeneous nutrient environment, S. superba displayed the obviously competitive advantage, which related to its root plasticity. The fine root of S. superba mixed in each diameter class showed a lot of hyperplasia, and the root total length, surface area and volume of which were 80%-180% higher than that of C. lanceolata. S. superba took the advantage of the compensatory growth strategy of vertical direction in fine roots, namely, they still multiplied to gain greater competitive advantage in low nutrient patches, besides occupying eutrophic surface. The different soil colonization and niche differentiation in fine root of S. superba and C. lanceolata alleviated the strong competition for nutrients of the roots of the two species, and improved the mixed-plantation production. Pure plantation of S. superba harvested the lower yield, which due to the root self-recognition inhibited the growth of root system. Fine roots staggered and evenly distributed on the space might be a reason for stable structure of pure S. superba plantation. So, it was recommended that block surface layer soil preparation and fertilization are used to improve the soil nutrient distribution, and the mixed plantation is constructed to promote the growth of S. superba and C. lanceolata, at the same time, the stand density is regulated to promote tree growth for the pure artificial S. superba plantation which had

  11. Vegetation and Cold Trapping Modulating Elevation-dependent Distribution of Trace Metals in Soils of a High Mountain in Eastern Tibetan Plateau.

    Science.gov (United States)

    Bing, Haijian; Wu, Yanhong; Zhou, Jun; Li, Rui; Luo, Ji; Yu, Dong

    2016-04-07

    Trace metals adsorbed onto fine particles can be transported long distances and ultimately deposited in Polar Regions via the cold condensation effect. This study indicated the possible sources of silver (Ag), cadmium (Cd), copper (Cu), lead (Pb), antimony (Sb) and zinc (Zn) in soils on the eastern slope of Mt. Gongga, eastern Tibetan Plateau, and deciphered the effects of vegetation and mountain cold condensation on their distributions with elevation. The metal concentrations in the soils were comparable to other mountains worldwide except the remarkably high concentrations of Cd. Trace metals with high enrichment in the soils were influenced from anthropogenic contributions. Spatially, the concentrations of Cu and Zn in the surface horizons decreased from 2000 to 3700 m a.s.l., and then increased with elevation, whereas other metals were notably enriched in the mid-elevation area (approximately 3000 m a.s.l.). After normalization for soil organic carbon, high concentrations of Cd, Pb, Sb and Zn were observed above the timberline. Our results indicated the importance of vegetation in trace metal accumulation in an alpine ecosystem and highlighted the mountain cold trapping effect on trace metal deposition sourced from long-range atmospheric transport.

  12. Size distribution and source identification of total suspended particulate matter and associated heavy metals in the urban atmosphere of Delhi.

    Science.gov (United States)

    Srivastava, Arun; Jain, V K

    2007-06-01

    A study of the atmospheric particulate size distribution of total suspended particulate matter (TSPM) and associated heavy metal concentrations has been carried out for the city of Delhi. Urban particles were collected using a five-stage impactor at six sites in three different seasons, viz. winter, summer and monsoon in the year 2001. Five samples from each site in each season were collected. Each sample (filter paper) was extracted with a mixture of nitric acid, hydrochloric acid and hydrofluoric acid. The acid solutions of the samples were analysed in five-particle fractions by atomic absorption spectrometry (AAS). The impactor stage fractionation of particles shows that a major portion of TSPM concentration is in the form of PM0.7 (i.e. metal mass viz. Mn, Cr, Cd, Pb, Ni, and Fe are also concentrated in the PM0.7 mode. The only exceptions are size distributions pertaining to Cu and Ca. Though, Cu is more in PM0.7 mode, its presence in size intervals 5.4-1.6microm and 1.6-0.7microm is also significant, whilst in case of Ca there is no definite pattern in its distribution with size of particles. The average PM10.9 (i.e. Source apportionment reveals that there are two sources of TSPM and PM10.9, while three and four sources were observed for PM1.6 (i.e. <1.6microm) and PM0.7, respectively. Results of regression analyses show definite correlations between PM10.9 and other fine size fractions, suggesting PM10.9 may adequately act as a surrogate for both PM1.6 and PM0.7, while PM1.6 may adequately act as a surrogate for PM0.7.

  13. Spatial distribution of heavy metals in surficial sediments from Guanabara Bay: Rio de Janeiro, Brazil

    Science.gov (United States)

    Neto, José Antônio Baptista; Gingele, Franz Xaver; Leipe, Thomas; Brehme, Isa

    2006-04-01

    Ninety-two surface sediment samples were collected in Guanabara Bay, one of the most prominent urban bays in SE Brazil, to investigate the spatial distribution of anthropogenic pollutants. The concentrations of heavy metals, organic carbon and particle size were examined in all samples. Large spatial variations of heavy metals and particle size were observed. The highest concentrations of heavy metals were found in the muddy sediments from the north western region of the bay near the main outlets of the most polluted rivers, municipal waste drainage systems and one of the major oil refineries. Another anomalous concentration of metals was found adjacent to Rio de Janeiro Harbour. The heavy metal concentrations decrease to the northeast, due to intact rivers and the mangrove systems in this area, and to the south where the sand fraction and open-marine processes dominate. The geochemical normalization of metal data to Li or Al has also demonstrated that the anthropogenic input of heavy metals have altered the natural sediment heavy metal distribution.

  14. Air quality in the Kootenays: fine particulate (PM10) airborne metals and sulphur dioxide levels, 1993-1999

    International Nuclear Information System (INIS)

    2000-09-01

    Air quality monitoring data collected in the Kootenays over a seven year period from 1993 to 1999 are summarized in an effort to inform the public about air quality in the Kootenays and to assist them in understanding air quality monitoring results. Data includes hourly (TEOM) and weekly (NAPS) data for particulate matter (PM 1 0) airborne metals (arsenic, cadmium, lead and zinc) and sulphur dioxide. Analysis of monitoring data showed that particulate matter levels remained constant in most communities, with Johnson Lake and Slocan reporting the lowest levels, while Golden had the highest values during this period. Trail-Butler Park showed a clear declining trend in PM 1 0. Airborne metals and sulphur dioxide levels have decreased in the Kootenays during the seven year period, with only occasional exceedances of both Level A and B air quality objectives in some communities. The report includes a detailed description of the sampling methodology and the analyzed results for PM 1 0, airborne metals and sulphur dioxide for 10 communities in the region. 6 refs., 1 tab., 16 figs., 1 map

  15. The Distribution of Heavy Metal Pollutants in Suez Bay Using Geographic Information System (GIS)

    International Nuclear Information System (INIS)

    Hassan, H.B.; Mohamed, W.M.

    2017-01-01

    Suez city represents the southern entrance of the Suez Canal. As a result of the rapid development of industrialization and anthropogenic activities of Suez city may be entered containments such as heavy metals through Suez bay boundaries. The geographical information system (Arc GIS 9.1) is used to study the spatial distribution of heavy metals concentrations (Cd, Mn, Fe, Ni, Pb, Cu and Zn) of water samples which were collected in four different sampling sites (I, II, III and IV) from Suez bay. In this study, tabular data representation of the spatial distribution was developed using the inverse distance weighted (IDW) interpolation method. The GIS technique was applied to transfer the information into a final map illustrating the spatial distribution of heavy metals within the studied area. GIS models showed the high concentrations of heavy metals in some sites in the Suez city affecting by their activities. An overall distribution map of heavy metals is observed from GIS special analysis. Site (IV) in Suez City demonstrated the highest polluted are a in the overall distribution map

  16. DISTRIBUTION OF HEAVY METALS AMONG THE COMPONENTS OF FRESHWATER ECOSYSTEMS (REVIEW

    Directory of Open Access Journals (Sweden)

    N. Kolesnyk

    2014-09-01

    Full Text Available Purpose. To review scientific sources on the distribution of heavy metals among the components of freshwater ecosystems. Findings. The review of the works of many scientists showed that heavy metals are widespread in the biotic and abiotic components of freshwater ecosystems. The article highlights the distribution of heavy metals in water, bottom sediments, natural food base, fish organs and tissues. It has been shown that as a result of global pollution of the ecosystem, the majority of Ukrainian rivers belong to polluted and very polluted. Of special interest are the studies of the distribution of heavy metals in phytoplankton, zooplankton, and zoobenthos because these components occupy a certain position in fish food chain. The presence of heavy metals in the natural food base showed that, on one hand, it could accumulate heavy metals in large amounts in such a way cleaning the water; and on the other hand, the heavy metals could migrate in the food web and contaminate fish. Ones of objects, which should be given attention when assessing toxicologic pollution, are aquatic plants, in particular phytoplankton. Studies showed that the accumulation of heavy metals in plants occurred first of all by their adsorption on the cellular wall. It explains the maximum adsorption of heavy metals by plants immediately after introduction of heavy metals into their culture. Fish as a rule occupy in the food web of water bodies one of the last places. They actively move in the aquatic environment and accumulating heavy metals at the same time they provide the most integrated and precise estimate of environmental pollution. By analyzing the distribution of heavy metals in fish organs and tissues, depending on their ability to accumulate them, it can be noted that the accumulation is the most intensive in such organs as gills, liver, and kidneys. Usually, their lowest content is observed in muscles that is important for human life because they are the main

  17. Farms, pastures and woodlands: the fine-scale distribution of Palearctic Culicoides spp. biting midges along an agro-ecological gradient.

    Science.gov (United States)

    Rigot, T; Drubbel, M Vercauteren; Delécolle, J-C; Gilbert, M

    2013-03-01

    The spatial epidemiology of Bluetongue virus (BTV) at the landscape level relates to the fine-scale distribution and dispersal capacities of its vectors, midges belonging to the genus Culicoides Latreille (Diptera: Ceratopogonidae). Although many previous researches have carried out Culicoides sampling on farms, little is known of the fine-scale distribution of Culicoides in the landscape immediately surrounding farms. The aim of this study was to gain a better understanding of Culicoides populations at increasing distances from typical dairy farms in north-west Europe, through the use of eight Onderstepoort-type black-light traps positioned along linear transects departing from farms, going through pastures and entering woodlands. A total of 16 902 Culicoides were collected in autumn 2008 and spring 2009. The majority were females, of which more than 97% were recognized as potential vectors. In pastures, we found decreasing numbers of female Culicoides as a function of the distance to the farm. This pattern was modelled by leptokurtic models, with parameters depending on season and species. By contrast, the low number of male Culicoides caught were homogeneously distributed along the transects. When transects entered woodlands, we found a higher abundance of Culicoides than expected considering the distance of the sampling sites to the farm, although this varied according to species. © 2012 The Authors. Medical and Veterinary Entomology © 2012 The Royal Entomological Society.

  18. Determination of 114Pd cumulative yield and investigation of the fine-structure at light peak in mass distribution of 252Cf spontaneous fission

    International Nuclear Information System (INIS)

    Yu Runlan; Li Xueliang; Cui Anzhi; Guo Jingru; Yan Shuhen; Tang Peijia; Liu Daming

    1991-07-01

    A rapid radiochemical procedure for Pd separation was developed. It was the first time to use radiochemical techniques to determine 114 Pd cumulative yield (2.50 ± 0.14)% in 252 Cf spontaneous fission. The cumulative yields of (3.50 ± 0.13)% and (3.70 ± 0.11)% for 112 Pd and 113g Ag were also obtained. These are in agreement with Skovorodkin's results. The cumulative yields determined show that there is a fine-structure at light peak of mass number A = 113 in the mass distribution of 252 Cf spontaneous fission

  19. Distribution of metals in vacuum residuums, asphaltenes and maltenes by PIXE

    International Nuclear Information System (INIS)

    Romero G, E.T.; Camacho M, V.; Sanchez B, A.C.; Lopez M, J.; Ramirez T, J.J.; Villasenor S, P.; Aspiazu F, J.A.

    2001-01-01

    The PIXE technique for determining directly the distribution and abundance of trace metals in vacuum residuum, asphaltenes and maltenes separated with n-alkanes (C 5 -C 8 ) is used. The metal content of petroleum derivatives revealed that the vacuum residuum contains iron, aluminium, vanadium and nickel mainly, while that the asphaltenes and maltenes maintain inside of their composition only preferably the vanadium and nickel as majority elements. (Author)

  20. Trace metal distributions in Posidonia oceanica and sediments from Taranto Gulf (Ionian Sea, Southern Italy

    Directory of Open Access Journals (Sweden)

    A. DI LEO

    2013-03-01

    Full Text Available Distribution of metals (Hg, Pb, Sn, Cu, Cd and Zn was determined in sediments and in different tissues of Posidonia oceanica collected from San Pietro Island, Taranto Gulf (Ionian Sea, Southern Italy. In seagrass, results, compared with metal concentrations in sediments, showed that the highest concentrations of Hg, Pb, Sn and Cu were found in the roots, while in the green leaves were found the highest levels of Cd and Zn. Instead the lowest metal concentrations were found in the basal part of the leaf. Levels of  metals in the leaves were similar to those found by other authors in uncontaminated areas of the Mediterranean Sea. Mercury levels in roots were correlated to levels in sediments. This could demonstrate the plant memorizes sediments contamination . This study reinforces the usefulness and the relevance of Posidonia oceanica as an indicator of spatial metal contamination and an interesting tool for environmental quality evaluation.

  1. Heavy metal distribution and bioaccumulation in Chihuahuan Desert Rough Harvester ant (Pogonomyrmex rugosus) populations

    International Nuclear Information System (INIS)

    Del Toro, I.; Floyd, K.; Gardea-Torresdey, J.; Borrok, D.

    2010-01-01

    Heavy metal contamination can negatively impact arid ecosystems; however a thorough examination of bioaccumulation patterns has not been completed. We analyzed the distribution of As, Cd, Cu, Pb and Zn in soils, seeds and ant (Pogonomyrmex rugosus) populations of the Chihuahuan Desert near El Paso, TX, USA. Concentrations of As, Cd, Cu, and Pb in soils, seeds and ants declined as a function of distance from a now inactive Cu and Pb smelter and all five metals bioaccumulated in the granivorous ants. The average bioaccumulation factors for the metals from seeds to ants ranged from 1.04x (As) to 8.12x (Cd). The findings show bioaccumulation trends in linked trophic levels in an arid ecosystem and further investigation should focus on the impacts of heavy metal contamination at the community level. - Heavy metals bioaccumulate in desert ants.

  2. [The use of polymer gel dosimetry to measure dose distribution around metallic implants].

    Science.gov (United States)

    Nagahata, Tomomasa; Yamaguchi, Hajime; Monzen, Hajime; Nishimura, Yasumasa

    2014-10-01

    A semi-solid polymer dosimetry system using agar was developed to measure the dose distribution close to metallic implants. Dosimetry of heterogeneous fields where electron density markedly varies is often problematic. This prompted us to develop a polymer gel dosimetry technique using agar to measure the dose distribution near substance boundaries. Varying the concentration of an oxygen scavenger (tetra-hydroxymethyl phosphonium chloride) showed the absorbed dose and transverse relaxation rate of the magnetic resonance signal to be linear between 3 and 12 Gy. Although a change in the dosimeter due to oxidization was observed in room air after 24 hours, no such effects were observed in the first 4 hours. The dose distribution around the metal implants was measured using agar dosimetry. The metals tested were a lead rod, a titanium hip joint, and a metallic stent. A maximum 30% dose increase was observed near the lead rod, but only a 3% increase in the absorbed dose was noted near the surface of the titanium hip joint and metallic stent. Semi-solid polymer dosimetry using agar thus appears to be a useful method for dosimetry around metallic substances.

  3. The use of polymer gel dosimetry to measure dose distribution around metallic implants

    International Nuclear Information System (INIS)

    Nagahata, Tomomasa; Yamaguchi, Hajime; Monzen, Hajime; Nishimura, Yasumasa

    2014-01-01

    A semi-solid polymer dosimetry system using agar was developed to measure the dose distribution close to metallic implants. Dosimetry of heterogeneous fields where electron density markedly varies is often problematic. This prompted us to develop a polymer gel dosimetry technique using agar to measure the dose distribution near substance boundaries. Varying the concentration of an oxygen scavenger (tetra-hydroxymethyl phosphonium chloride) showed the absorbed dose and transverse relaxation rate of the magnetic resonance signal to be linear between 3 and 12 Gy. Although a change in the dosimeter due to oxidization was observed in room air after 24 hours, no such effects were observed in the first 4 hours. The dose distribution around the metal implants was measured using agar dosimetry. The metals tested were a lead rod, a titanium hip joint, and a metallic stent. A maximum 30% dose increase was observed near the lead rod, but only a 3% increase in the absorbed dose was noted near the surface of the titanium hip joint and metallic stent. Semi-solid polymer dosimetry using agar thus appears to be a useful method for dosimetry around metallic substances. (author)

  4. Heavy Metallic Element Distribution in Cisadane River Estuary's Water and Sediment

    OpenAIRE

    M. Taufik Kaisupy; Abdul Rozak; Endang Rochyatun

    2006-01-01

    Observation of heavy metallic elements in Cisadane River Estuary has been done in July and November 2005. The results show that heavy metallic elements content in seawater is lower and still below the treshold value stated by government for fisheries. There was an indication of heavy metallic elements on sediment. Distribution of Pb on July and of Cu on November 2005 were found higher near the coast and decrease towards the sea, and commonly were found in front of estuary such as Cisadane, Mu...

  5. Uptake and distribution of soil-applied labelled heavy metals in cereal plants and products

    International Nuclear Information System (INIS)

    Oberlaender, H.E.; Roth, K.

    1983-01-01

    In the present paper investigations are described on the uptake, distribution and translocation of mercury, cadmium, chromium and zinc by spring and winter varieties of wheat, rye and barley. Pot experiments were carried out at low concentrations of the heavy metals in order to avoid growth interference during the uptake. Using radioisotopes the pathway of the metals was traced through different organs into the milling products. An ion-exchanger was added to the soils and its efficiency of reducing the uptake of the metals by the plants was tested

  6. Fate and Distribution of Heavy Metals in Wastewater Irrigated Calcareous Soils

    Science.gov (United States)

    Stietiya, Mohammed Hashem; Duqqah, Mohammad; Udeigwe, Theophilus; Zubi, Ruba; Ammari, Tarek

    2014-01-01

    Accumulation of heavy metals in Jordanian soils irrigated with treated wastewater threatens agricultural sustainability. This study was carried out to investigate the environmental fate of Zn, Ni, and Cd in calcareous soils irrigated with treated wastewater and to elucidate the impact of hydrous ferric oxide (HFO) amendment on metal redistribution among soil fractions. Results showed that sorption capacity for Zarqa River (ZR1) soil was higher than Wadi Dhuleil (WD1) soil for all metals. The order of sorption affinity for WD1 was in the decreasing order of Ni > Zn > Cd, consistent with electrostatic attraction and indication of weak association with soil constituents. Following metal addition, Zn and Ni were distributed among the carbonate and Fe/Mn oxide fractions, while Cd was distributed among the exchangeable and carbonate fractions in both soils. Amending soils with 3% HFO did not increase the concentration of metals associated with the Fe/Mn oxide fraction or impact metal redistribution. The study suggests that carbonates control the mobility and bioavailability of Zn, Ni, and Cd in these calcareous soils, even in presence of a strong adsorbent such as HFO. Thus, it can be inferred that in situ heavy metal remediation of these highly calcareous soils using iron oxide compounds could be ineffective. PMID:24723833

  7. Assessment of spatial distribution of soil heavy metals using ANN-GA, MSLR and satellite imagery.

    Science.gov (United States)

    Naderi, Arman; Delavar, Mohammad Amir; Kaboudin, Babak; Askari, Mohammad Sadegh

    2017-05-01

    This study aims to assess and compare heavy metal distribution models developed using stepwise multiple linear regression (MSLR) and neural network-genetic algorithm model (ANN-GA) based on satellite imagery. The source identification of heavy metals was also explored using local Moran index. Soil samples (n = 300) were collected based on a grid and pH, organic matter, clay, iron oxide contents cadmium (Cd), lead (Pb) and zinc (Zn) concentrations were determined for each sample. Visible/near-infrared reflectance (VNIR) within the electromagnetic ranges of satellite imagery was applied to estimate heavy metal concentrations in the soil using MSLR and ANN-GA models. The models were evaluated and ANN-GA model demonstrated higher accuracy, and the autocorrelation results showed higher significant clusters of heavy metals around the industrial zone. The higher concentration of Cd, Pb and Zn was noted under industrial lands and irrigation farming in comparison to barren and dryland farming. Accumulation of industrial wastes in roads and streams was identified as main sources of pollution, and the concentration of soil heavy metals was reduced by increasing the distance from these sources. In comparison to MLSR, ANN-GA provided a more accurate indirect assessment of heavy metal concentrations in highly polluted soils. The clustering analysis provided reliable information about the spatial distribution of soil heavy metals and their sources.

  8. Fate and Distribution of Heavy Metals in Wastewater Irrigated Calcareous Soils

    Directory of Open Access Journals (Sweden)

    Mohammed Hashem Stietiya

    2014-01-01

    Full Text Available Accumulation of heavy metals in Jordanian soils irrigated with treated wastewater threatens agricultural sustainability. This study was carried out to investigate the environmental fate of Zn, Ni, and Cd in calcareous soils irrigated with treated wastewater and to elucidate the impact of hydrous ferric oxide (HFO amendment on metal redistribution among soil fractions. Results showed that sorption capacity for Zarqa River (ZR1 soil was higher than Wadi Dhuleil (WD1 soil for all metals. The order of sorption affinity for WD1 was in the decreasing order of Ni > Zn > Cd, consistent with electrostatic attraction and indication of weak association with soil constituents. Following metal addition, Zn and Ni were distributed among the carbonate and Fe/Mn oxide fractions, while Cd was distributed among the exchangeable and carbonate fractions in both soils. Amending soils with 3% HFO did not increase the concentration of metals associated with the Fe/Mn oxide fraction or impact metal redistribution. The study suggests that carbonates control the mobility and bioavailability of Zn, Ni, and Cd in these calcareous soils, even in presence of a strong adsorbent such as HFO. Thus, it can be inferred that in situ heavy metal remediation of these highly calcareous soils using iron oxide compounds could be ineffective.

  9. Interpretation of aerosol trace metal particle size distributions

    International Nuclear Information System (INIS)

    Johansson, T.B.; Van Grieken, R.E.; Winchester, J.W.

    1974-01-01

    Proton-induced X-ray emission (PIXE) analysis is capable of rapid routine determination of 10--15 elements present in amounts greater than or equal to 1 ng simultaneously in aerosol size fractions as collected by single orifice impactors over short periods of time. This enables detailed study of complex relationships between elements detected. Since absolute elemental concentrations may be strongly influenced by meteorological and topographical conditions, it is useful to normalize to a reference element. Comparison between the ratios of concentrations with aerosol and corresponding values for anticipated sources may lead to the identification of important sources for the elements. Further geochemical insights may be found through linear correlation coefficients, regression analysis, and cluster analysis. By calculating correlations for elemental pairs, an indication of the degree of covariance between the elements is obtained. Preliminary results indicate that correlations may be particle size dependent. A high degree of covariance may be caused either by a common source or may only reflect the conservative nature of the aerosol. In a regression analysis, by plotting elemental pairs and estimating the regression coefficients, we may be able to conclude if there is more than one source operating for a given element in a certain size range. Analysis of clustering of several elements, previously investigated for aerosol filter samples, can be applied to the analysis of aerosol size fractions. Careful statistical treatment of elemental concentrations as a function of aerosol particle size may thus yield significant information on the generation, transport and deposition of trace metals in the atmosphere

  10. Effect of metal ion on the structure and function of LiPDF: The study of the fine structure around the metal site using XANES

    International Nuclear Information System (INIS)

    Wang Yu; Chu Wangsheng; Yang Feifei; Yu Meijuan; Zhao Haifeng; Gong Weimin; Dong Yuhui; Xie Yaning; Wu, Ziyu

    2010-01-01

    We used X-ray absorption near edge structure (XANES) spectroscopy to investigate the metal-dependent enzymatic activity of the peptide deformylase from Leptospira interrogans (LiPDF). Ab initio full multiple scattering calculations performed by MXAN are applied to obtain the local structure of the cobalt-containing LiPDF (Co-LiPDF) and zinc-containing LiPDF (Zn-LiPDF) around the metal sites in pH9.0 buffer solution. The result shows the cobalt-wat1 (the bond water molecule) distance of Co-LiPDF is 1.89 A, much shorter than that of Zn-LiPDF, 2.50 A. That is an essential factor for its low catalytic activity.

  11. Effect of metal ion on the structure and function of LiPDF: The study of the fine structure around the metal site using XANES

    Energy Technology Data Exchange (ETDEWEB)

    Wang Yu [Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (China); Chu Wangsheng, E-mail: cws@ihep.ac.c [Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Yang Feifei; Yu Meijuan; Zhao Haifeng [Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Gong Weimin [National Laboratory of Biomacromolecules, Institute of Biophysics, Chinese Academy of Sciences, Beijing 100101 (China); Dong Yuhui; Xie Yaning [Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Wu, Ziyu, E-mail: wuzy@ustc.edu.c [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (China); Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)

    2010-07-21

    We used X-ray absorption near edge structure (XANES) spectroscopy to investigate the metal-dependent enzymatic activity of the peptide deformylase from Leptospira interrogans (LiPDF). Ab initio full multiple scattering calculations performed by MXAN are applied to obtain the local structure of the cobalt-containing LiPDF (Co-LiPDF) and zinc-containing LiPDF (Zn-LiPDF) around the metal sites in pH9.0 buffer solution. The result shows the cobalt-wat1 (the bond water molecule) distance of Co-LiPDF is 1.89 A, much shorter than that of Zn-LiPDF, 2.50 A. That is an essential factor for its low catalytic activity.

  12. Spatiotemporal distribution of airborne particulate metals and metalloids in a populated arid region

    Science.gov (United States)

    Prabhakar, Gouri; Sorooshian, Armin; Toffol, Emily; Arellano, Avelino F.; Betterton, Eric A.

    2014-08-01

    A statistical analysis of data from the Interagency Monitoring of Protected Visual Environments (IMPROVE) network of aerosol samplers has been used to study the spatial and temporal concentration trends in airborne particulate metals and metalloids for southern Arizona. The study region is a rapidly growing area in southwestern North America characterized by high fine soil concentrations (among the highest in the United States), anthropogenic emissions from an area within the fastest growing region in the United States, and a high density of active and abandoned mining sites. Crustal tracers in the region are most abundant in the summer (April-June) followed by fall (October-November) as a result of dry meteorological conditions which favor dust emissions from natural and anthropogenic activity. A distinct day-of-week cycle is evident for crustal tracer mass concentrations, with the greatest amplitude evident in urban areas. There have been significant reductions since 1988 in the concentrations of toxic species that are typically associated with smelting and mining. Periods with high fine soil concentrations coincide with higher concentrations of metals and metalloids in the atmosphere, with the enhancement being higher at urban sites.

  13. Distribution and accumulation of heavy metals in the sediments of Akkaya Dam, Nigde, Turkey.

    Science.gov (United States)

    Keskin, Şeref

    2012-01-01

    Twenty-one surface sediment samples were collected from Akkaya Dam. Heavy metal concentrations (Mo, Cu, Pb, Zn, Ni, Co, Mn, Fe, Cr, As, V and Cd), grain size, organic carbon and carbonate contents were studied in order to assess the extent of environmental pollution and to discuss the origin of these contaminants in sediments of dam. The sediments in the study area are mostly very fine sands. However, mud was observed in the northeast of the dam. Sediment pollution assessment was carried out using enrichment factor. The calculation of enrichment factors showed that Mo is depleted by 1.0 whereas Cu, Pb, Zn, Ni, Co, Mn, As, V, Cr and Cd are enriched by 3, 5.4, 7, 2.7, 2.2, 3.4, 42.3, 2.1, 1.8 and 7.2, respectively. Relatively high concentrations heavy metals occurred in north (textile industry area) and east (Karasu River) due to enrichment controlled by anthropogenic wastes. The results of correlation analysis show low-medium positive and negative correlations among metals, grain size, carbonate contents and organic carbon and indicate that heavy metals in sediments of the Akkaya Dam have different anthropogenic sources.

  14. Angular distribution of atoms ejected by laser ablation of different metals

    International Nuclear Information System (INIS)

    Konomi, I.; Motohiro, T.; Asaoka, T.

    2009-01-01

    Angular distributions of 13 different metals ejected by laser ablation using fourth harmonics (wavelength=266 nm) of neodymium doped yttrium aluminum garnet laser and a fluence close to near-threshold value (2.3 J/cm 2 ) have been investigated with a high angular resolution. The angular distribution which is characterized by the exponent n of cos n θ distribution showed very broad range of values between 3 and 24 for different metals. A simple relation that the exponent n is proportional to the square root of particle atomic weight as reported previously has not been observed. Instead, a general trend has been found that the metals with higher sublimation energy such as Ta and Zr show narrower angular distribution than those with lower sublimation energy such as Sn and In. While the sublimation energy of metals has a great influence on the angular distribution of ejected atoms, a simple consideration suggests that their thermal conductivity and specific heat have little effect on it.

  15. Fine-scale population structure and riverscape genetics of brook trout (Salvelinus fontinalis) distributed continuously along headwater channel networks

    Science.gov (United States)

    Kanno, Yoichiro; Vokoun, Jason C.; Letcher, Benjamin H.

    2011-01-01

    Linear and heterogeneous habitat makes headwater stream networks an ideal ecosystem in which to test the influence of environmental factors on spatial genetic patterns of obligatory aquatic species. We investigated fine-scale population structure and influence of stream habitat on individual-level genetic differentiation in brook trout (Salvelinus fontinalis) by genotyping eight microsatellite loci in 740 individuals in two headwater channel networks (7.7 and 4.4 km) in Connecticut, USA. A weak but statistically significant isolation-by-distance pattern was common in both sites. In the field, many tagged individuals were recaptured in the same 50-m reaches within a single field season (summer to fall). One study site was characterized with a hierarchical population structure, where seasonal barriers (natural falls of 1.5–2.5 m in height during summer base-flow condition) greatly reduced gene flow and perceptible spatial patterns emerged because of the presence of tributaries, each with a group of genetically distinguishable individuals. Genetic differentiation increased when pairs of individuals were separated by high stream gradient (steep channel slope) or warm stream temperature in this site, although the evidence of their influence was equivocal. In a second site, evidence for genetic clusters was weak at best, but genetic differentiation between individuals was positively correlated with number of tributary confluences. We concluded that the population-level movement of brook trout was limited in the study headwater stream networks, resulting in the fine-scale population structure (genetic clusters and clines) even at distances of a few kilometres, and gene flow was mitigated by ‘riverscape’ variables, particularly by physical barriers, waterway distance (i.e. isolation-by-distance) and the presence of tributaries.

  16. THE BIMODAL METALLICITY DISTRIBUTION OF THE COOL CIRCUMGALACTIC MEDIUM AT z {approx}< 1

    Energy Technology Data Exchange (ETDEWEB)

    Lehner, N.; Howk, J. C. [Department of Physics, University of Notre Dame, 225 Nieuwland Science Hall, Notre Dame, IN 46556 (United States); Tripp, T. M. [Department of Astronomy, University of Massachusetts, Amherst, MA 01003 (United States); Tumlinson, J.; Thom, C.; Fox, A. J. [Space Telescope Science Institute, Baltimore, MD 21218 (United States); Prochaska, J. X.; Werk, J. K. [UCO/Lick Observatory, University of California, Santa Cruz, CA (United States); O' Meara, J. M. [Department of Physics, Saint Michael' s College, Vermont, One Winooski Park, Colchester, VT 05439 (United States); Ribaudo, J. [Department of Physics, Utica College, 1600 Burrstone Road, Utica, New York 13502 (United States)

    2013-06-20

    We assess the metal content of the cool ({approx}10{sup 4} K) circumgalactic medium (CGM) about galaxies at z {approx}< 1 using an H I-selected sample of 28 Lyman limit systems (LLS; defined here as absorbers with 16.2 {approx}< log N{sub H{sub I}} {approx}< 18.5) observed in absorption against background QSOs by the Cosmic Origins Spectrograph on board the Hubble Space Telescope. The N{sub H{sub I}} selection avoids metallicity biases inherent in many previous studies of the low-redshift CGM. We compare the column densities of weakly ionized metal species (e.g., O II, Si II, Mg II) to N{sub H{sub I}} in the strongest H I component of each absorber. We find that the metallicity distribution of the LLS (and hence the cool CGM) is bimodal with metal-poor and metal-rich branches peaking at [X/H] {approx_equal} -1.6 and -0.3 (or about 2.5% and 50% solar metallicities). The cool CGM probed by these LLS is predominantly ionized. The metal-rich branch of the population likely traces winds, recycled outflows, and tidally stripped gas; the metal-poor branch has properties consistent with cold accretion streams thought to be a major source of fresh gas for star forming galaxies. Both branches have a nearly equal number of absorbers. Our results thus demonstrate there is a significant mass of previously undiscovered cold metal-poor gas and confirm the presence of metal enriched gas in the CGM of z {approx}< 1 galaxies.

  17. Investigating the Relationships between Canopy Characteristics and Snow Depth Distribution at Fine Scales: Preliminary Results from the SnowEX TLS Campaign

    Science.gov (United States)

    Glenn, N. F.; Uhlmann, Z.; Spaete, L.; Tennant, C.; Hiemstra, C. A.; McNamara, J.

    2017-12-01

    Predicting changes in forested seasonal snowpacks under altered climate scenarios is one of the most pressing hydrologic challenges facing today's society. Airborne- and satellite-based remote sensing methods hold the potential to transform measurements of terrestrial water stores in snowpack, improve process representations of snowpack accumulation and ablation, and to generate high quality predictions that inform potential strategies to better manage water resources. While the effects of forest on snowpack are well documented, many of the fine-scale processes influenced by the forest-canopy are not directly accounted for because most snow models don't explicitly represent canopy structure and canopy heterogeneity. This study investigates the influence of forest canopy on snowpack distribution at fine scales and quantifies the influence of canopy heterogeneity on snowpack accumulation and ablation processes. We use terrestrial laser scanning (TLS) data collected during the SnowEX campaign to discover how the relationships between canopy and snow distributions change across scales. Our sample scales range from individual trees to patches of trees across the Grand Mesa, CO, SnowEx site.

  18. Multiple Scattering Effects in EXAFS (Extended X-Ray Absorption Fine Structure): Comparison between Theory and Experiment for Pt Metal.

    Science.gov (United States)

    1984-05-29

    radial distribution and inverse transform of this range. The region commonly used for the inverse transform usually corresponds to the first or second...r-space and comparing it with the corresponding model function. Figure 5 shows the filtered spectra (k weighting), where the pe. 48 allowed inverse ... transform range was successively increased from the radial distance corresponding to the first shell to all the first four shells. There are no multiple

  19. Distribution and health risk assessment to heavy metals near smelting and mining areas of Hezhang, China.

    Science.gov (United States)

    Briki, Meryem; Zhu, Yi; Gao, Yang; Shao, Mengmeng; Ding, Huaijian; Ji, Hongbing

    2017-08-19

    Mining and smelting areas in Hezhang have generated a large amount of heavy metals into the environment. For that cause, an evaluative study on human exposure to heavy metals including Co, Ni, Cu, Zn, Cr, As, Cd, Pb, Sb, Bi, Be, and Hg in hair and urine was conducted for their concentrations and correlations. Daily exposure and non-carcinogenic and carcinogenic risk were estimated. Sixty-eight scalp hair and 66 urine samples were taken from participants of different ages (6-17, 18-40, 41-60, and ≥ 65 years) living in the vicinity of an agricultural soil near mine and smelting areas. The results compared to the earlier studies showed an elevated concentration of Pb, Be, Bi, Co, Cr, Ni, Sb, and Zn in hair and urine. These heavy metals were more elevated in mining than in smelting. Considering gender differences, females were likely to be more affected than male. By investigating age differences in this area, high heavy metal concentrations in male's hair and urine existed in age of 18-40 and ≥ 66, respectively. However, females did not present homogeneous age distribution. Hair and urine showed a different distribution of heavy metals in different age and gender. In some cases, significant correlation was found between heavy metals in hair and urine (P > 0.05 and P > 0.01) in mining area. The estimated average daily intake of heavy metals in vegetables showed a great contribution compared to the soil and water. Non-carcinogenic and carcinogenic risk values of total pathways in mining and smelting areas were higher than 1 and exceeded the acceptable levels. Thus, the obtained data might be useful for further studies. They can serve as a basis of comparison and assessing the effect of simultaneous exposure from heavy metals in mining and smelting areas, and potential health risks from exposure to heavy metals in vegetables need more consideration.

  20. A comprehensive study of metal distribution in three main classes of seaweed

    International Nuclear Information System (INIS)

    Ryan, Siobhan; McLoughlin, Peter; O'Donovan, Orla

    2012-01-01

    This paper provides one of the most comprehensive studies of metal distributions in three main macroalgae species. In this novel study, levels of total, intracellular and surface bound Pb, Zn, As, Cd, Co, Cr, Cu, Mn and Ni associated with Polysiphonia lanosa (L) Tandy, Ascophyllum nodosum (L) Le Jolis, Fucus vesiculosus (L) and Ulva sp. were determined. Additionally, water and sediment metal levels were analysed to gain an insight into the relative uptake efficiencies of different macroalgal species. Samples were collected from a clean site in Fethard-on-Sea, Wexford, Ireland (52°11′53.68′N, 6°49′34.64′W), in May 2008. Results demonstrated that total, intracellular and surface bound metal levels varied according to metal and seaweed species, with the highest proportion of metals found to be intracellular. Inhibition of Mn uptake by Zn was indicated for P. lanosa. Furthermore, P. lanosa had enhanced bioaccumulation ability, with the highest Concentration Factor reported of any seaweed to date. - Highlights: ► Three main classes of seaweed were collected from the South-East coast of Ireland. ► Metal levels (total, intracellular and surface-bound) in four seaweed species were determined. ► Metal levels of seawater and sediment samples collected from the same location were quantified. ► The Concentration Factors for P. lanosa, A. nodosum, F. vesiculosus and Ulva sp., were calculated. ► Interspecies variations in seaweed metal concentrations were demonstrated. - This study, reports the most comprehensive uptake efficiencies and distributions of metals in four main seaweed sps., with P. lanosa demonstrating excellent bioaccumulation ability.

  1. Distribution of Heavy Metals in the Different Parts of Cerithidea Obtusa and the Relationships between Metal Distribution and Allometric Parameters of the Snail

    Directory of Open Access Journals (Sweden)

    Chee Kong YAP

    2010-07-01

    Full Text Available The intertidal gastropod, Cerithidea obtusa were obtained from Bako and Sematan (Sarawak and Deralik (Perak. Besides the shell, the snails were dissected into five different soft tissues. The soft tissues and the shell were then analysed for heavy metals. It was found that the highest concentrations of Cu (112 - 178 μg/g dw and Zn (117 - 161 μg/g dw were found in the tentacle; the highest concentrations of Cd (4.41 - 5.37 μg/g dw, Pb (53.2 - 63.8 μg/g dw and Ni (26.1 - 27.9 μg/g dw were found in the shell. On the other hand, the highest Fe concentrations (910 - 2921 μg/g dw were found in the operculum. The Spearman's correlation coefficient and multiple stepwise linear regression also revealed that the allometric parameters can influence the distribution of heavy metals in some of the different parts. From the present findings indicated that the heavy metals accumulated by the C. obtusa from the environment might affect its physical growth, which was shown by the negative correlations found between the metals in the different parts with the allometric parameters.

  2. Distribution and ecological relevance of fine sediments in organic-enriched lagoons: The case study of the Cabras lagoon (Sardinia, Italy)

    Energy Technology Data Exchange (ETDEWEB)

    Magni, P. [CNR-IAMC, National Research Council - Institute for Coastal Marine Environment Localita Sa Mardini, Torregrande, 09072 Oristano (Italy); International Marine Centre, Localita Sa Mardini, Torregrande, 09072 Oristano (Italy)], E-mail: paolo.magni@iamc.cnr.it; De Falco, G. [CNR-IAMC, National Research Council - Institute for Coastal Marine Environment Localita Sa Mardini, Torregrande, 09072 Oristano (Italy); International Marine Centre, Localita Sa Mardini, Torregrande, 09072 Oristano (Italy); Como, S. [International Marine Centre, Localita Sa Mardini, Torregrande, 09072 Oristano (Italy); Casu, D. [Dip. di Botanica ed Ecologia vegetale, Universita di Sassari, 07100 Sassari (Italy); Floris, A. [Dip. di Zoologia e Genetica evoluzionistica, Universita di Sassari, 07100 Sassari (Italy); Petrov, A.N. [Institute of Biology of the Southern Seas NASU, 99011 Sevastopol (Ukraine); Castelli, A. [Dip. di Biologia, Universita di Pisa, 56126 Pisa (Italy); Perilli, A. [CNR-IAMC, National Research Council - Institute for Coastal Marine Environment Localita Sa Mardini, Torregrande, 09072 Oristano (Italy); International Marine Centre, Localita Sa Mardini, Torregrande, 09072 Oristano (Italy)

    2008-03-15

    In organic-enriched sedimentary systems, like many Mediterranean coastal lagoons, a detailed analysis of sediment grain size composition and partitioning within the muds is crucial to investigate sedimentological trends related to both hydrodynamic energy and basin morphology. In these systems, sediment dynamics are particularly important because the partitioning and transport of fine sediments can strongly influence the redistribution and accumulation of large amounts of organic matter, and consequently the distribution of benthic assemblages and the trophic status and functioning of a lagoon. Nevertheless, studies on benthic-sediment relationships have been based mainly on a rather coarse analysis of sediment grain size features. In muddy systems, however, this approach may impede a proper evaluation of the relationships and effects of the distribution of fine sediment and organic matter on the biotic benthic components. Here we show that the distribution of sedimentary organic matter (OM) and total organic carbon (TOC) in the Cabras lagoon (Sardinia, Italy) can be explained (i.e., predicted) as a function of a nonlinear increase in the amount of the cohesive fraction of sediments ({<=}8 {mu}m grain size particles) and that this fraction strongly influences the structure, composition and distribution of macrobenthic assemblages. Even in such a homogeneously muddy system, characterized by 'naturally' occurring impoverished communities, impaired benthic assemblages were found at {<=}8 {mu}m, OM, TOC contents of about 77%, 11% and 3.5%, respectively. A review of studies conducted in Mediterranean coastal lagoons highlighted a lack of direct integrated analysis of sediment features and the biotic components. We suggest that, especially in organic-enriched coastal lagoons, monitoring programs should primarily investigate and consider the cohesive fraction of sediments in order to allow a better assessment of benthic-sediment relationships and ecological

  3. Individual and cumulative effects of agriculture, forestry and metal mining activities on the metal and phosphorus content of fluvial fine-grained sediment; Quesnel River Basin, British Columbia, Canada.

    Science.gov (United States)

    Smith, Tyler B; Owens, Philip N

    2014-10-15

    The impact of agriculture, forestry and metal mining on the quality of fine-grained sediment (sediment were collected monthly during the snow-free season in 2008 using time-integrated samplers at replicate sites representative of agriculture, forestry and mining activities in the basin (i.e. "impacted" sites). Samples were also collected from replicate reference sites and also from the main stem of the Quesnel River at the downstream confluence with the Fraser River. Generally, metal(loid) and phosphorus (P) concentrations for "impacted" sites were greater than for reference sites. Furthermore, concentrations of copper (forestry and mining sites), manganese (agriculture and forestry sites) and selenium (agriculture, forestry and mining sites) exceeded upper sediment quality guideline (SQG) thresholds. These results suggest that agriculture, forestry and metal mining activities are having an influence on the concentrations of sediment-associated metal(loid)s and P in the Quesnel basin. Metal(loid) and P concentrations of sediment collected from the downstream site were not significantly greater than values for the reference sites, and were typically lower than the values for the impacted sites. This suggests that the cumulative effects of agriculture, forestry and mining activities in the QRB are presently not having a measureable effect at the river basin-scale. The lack of a cumulative effect at the basin-scale is thought to reflect: (i) the relatively recent occurrence of land use disturbances in this basin; (ii) the dominance of sediment contributions from natural forest and agriculture; and (iii) the potential for storage of contaminants on floodplains and other storage elements between the locations of disturbance activities and the downstream sampling site, which may be attenuating the disturbance signal. Copyright © 2014 Elsevier B.V. All rights reserved.

  4. Tissue distribution patterns of solubilized metals from internalized tungsten alloy in the F344 rat

    Directory of Open Access Journals (Sweden)

    Vernieda B. Vergara

    2016-06-01

    Full Text Available Because of its unique physical and chemical properties, tungsten has been increasingly utilized in a variety of civilian and military applications. This expanded use also raises the risk of human exposure through internalization by various routes. In most cases the toxicological and carcinogenic properties of these tungsten-based compounds are not known nor are the dissolution biokinetics and ultimate fate of the associated metals. Using a laboratory rodent model system designed to assess the health effects of embedded metals, and a tungsten alloy comprised of tungsten (91.1%, nickel (6.0%, and cobalt (2.9%, we investigated the tissue distribution patterns of the metals over a six month period. Despite its perceived insolubility, tungsten rapidly solubilized from the implanted metal fragments, as did nickel and cobalt. All three metals distributed systemically over time with extremely elevated levels of all three metals found in kidney, liver, and spleen. Unexpectedly, tungsten was found to cross the blood-brain and blood-testis barriers and localize in those tissues. These results, along with recent reports suggesting that tungsten is a tumor promoter, raises serious concerns as to the long-term health effects of exposure to tungsten and tungsten-based compounds.

  5. Ion activity and distribution of heavy metals in acid mine drainage polluted subtropical soils

    International Nuclear Information System (INIS)

    Li Yongtao; Becquer, Thierry; Dai Jun; Quantin, Cecile; Benedetti, Marc F.

    2009-01-01

    The oxidative dissolution of mine wastes gives rise to acidic, metal-enriched mine drainage (AMD) and has typically posed an additional risk to the environment. The poly-metallic mine Dabaoshan in South China is an excellent test site to understand the processes affecting the surrounding polluted agricultural fields. Our objectives were firstly to investigate metal ion activity in soil solution, distribution in solid constituents, and spatial distribution in samples, secondly to determine dominant environment factors controlling metal activity in the long-term AMD-polluted subtropical soils. Soil Column Donnan Membrane Technology (SC-DMT) combined with sequential extraction shows that unusually large proportion of the metal ions are present as free ion in the soil solutions. The narrow range of low pH values prevents any pH effects during the binding onto oxides or organic matter. The differences in speciation of the soil solutions may explain the different soil degradation observed between paddy and non-paddy soils. - First evidence of the real free metal ion concentrations in acid mine drainage context in tropical systems

  6. Real-time distribution of pelagic fish: combining hydroacoustics, GIS and spatial modelling at a fine spatial scale.

    Science.gov (United States)

    Muška, Milan; Tušer, Michal; Frouzová, Jaroslava; Mrkvička, Tomáš; Ricard, Daniel; Seďa, Jaromír; Morelli, Federico; Kubečka, Jan

    2018-03-29

    Understanding spatial distribution of organisms in heterogeneous environment remains one of the chief issues in ecology. Spatial organization of freshwater fish was investigated predominantly on large-scale, neglecting important local conditions and ecological processes. However, small-scale processes are of an essential importance for individual habitat preferences and hence structuring trophic cascades and species coexistence. In this work, we analysed the real-time spatial distribution of pelagic freshwater fish in the Římov Reservoir (Czechia) observed by hydroacoustics in relation to important environmental predictors during 48 hours at 3-h interval. Effect of diurnal cycle was revealed of highest significance in all spatial models with inverse trends between fish distribution and predictors in day and night in general. Our findings highlighted daytime pelagic fish distribution as highly aggregated, with general fish preferences for central, deep and highly illuminated areas, whereas nighttime distribution was more disperse and fish preferred nearshore steep sloped areas with higher depth. This turnover suggests prominent movements of significant part of fish assemblage between pelagic and nearshore areas on a diel basis. In conclusion, hydroacoustics, GIS and spatial modelling proved as valuable tool for predicting local fish distribution and elucidate its drivers, which has far reaching implications for understanding freshwater ecosystem functioning.

  7. Urbanization effects on sediment and trace metals distribution in an urban winter pond (Netanya, Israel)

    NARCIS (Netherlands)

    Zohar, I.; Teutsch, N.; Levin, N.; Mackin, G.; de Stigter, H.; Bookman, R.

    2017-01-01

    PurposeThis paper aims to elucidate urban development-induced processes affecting the sediment and the distribution of contaminating metals in a seasonal pond located in the highly populated Israeli Coastal Plain. The paper demonstrates how an integrated approach, including geochemical,

  8. Metallicity and the spectral energy distribution and spectral types of dwarf O-stars

    NARCIS (Netherlands)

    Mokiem, MR; Martin-Hernandez, NL; Lenorzer, A; de Koter, A; Tielens, AGGA

    We present a systematic study of the effect of metallicity on the stellar spectral energy distribution (SED) of 0 main sequence (dwarf) stars, focussing on the hydrogen and helium ionizing continua, and on the optical and near-IR lines used for spectral classification. The spectra are based on

  9. Metallicity and the spectral energy distribution and spectral types of dwarf O-stars

    NARCIS (Netherlands)

    Mokiem, M.R.; Martín-Hernández, N.L.; Lenorzer, A.; de Koter, A.; Tielens, A.G.G.M.

    2004-01-01

    We present a systematic study of the effect of metallicity on the stellar spectral energy distribution (SED) of O main sequence (dwarf) stars, focussing on the hydrogen and helium ionizing continua, and on the optical and near-IR lines used for spectral classification. The spectra are based on

  10. Analysis of the distribution of heavy metals in the soils of Bagega ...

    African Journals Online (AJOL)

    Uncontrolled exploitation and degradation in the environment over the past few decades as the result of urbanization and poverty has caused a serious damage to lives and properties. The study analysed the spatial distribution of heavy metal (Fe, Cu and Zn) in Bagega, Zamfara state. Three mapping units were identified ...

  11. Determination of size and shape distributions of metal and ceramic powders

    International Nuclear Information System (INIS)

    Jovanovic, DI.

    1961-01-01

    For testing the size and shape distributions of metal and ceramic uranium oxide powders the following method for analysing the grain size of powders were developed and implemented: microscopic analysis and sedimentation method. A gravimetry absorption device was constructed for determining the specific surfaces of powders

  12. Distribution of toxic metals, Hg, Cd and Pb in zooplankton along the Indian coasts

    Digital Repository Service at National Institute of Oceanography (India)

    Sengupta, R.; Kureishy, T.W.

    Distribution of toxic metals such as Hg, Cd and Pb in zooplankton is assessed with a view to correlate it with the prevalent environmental conditions along the Indian coast. While Hg could not be detected in zooplankton the concentrations of Cd...

  13. Distribution of uranium and some selected trace metals in human scalp hair from Balkans.

    Science.gov (United States)

    Zunic, Z S; Tokonami, S; Mishra, S; Arae, H; Kritsananuwat, R; Sahoo, S K

    2012-11-01

    The possible consequences of the use of depleted uranium (DU) used in Balkan conflicts in 1995 and 1999 for the people and the environment of this reason need attention. The heavy metal content in human hair may serve as a good indicator of dietary, environmental and occupational exposures to the metal compounds. The present work summarises the distribution of uranium and some selected trace metals such as Mn, Ni, Cu, Zn, Sr, Cd and Cs in the scalp hair of inhabitants from Balkans exposed to DU directly and indirectly, i.e. Han Pijesak, Bratoselce and Gornja Stubla areas. Except U and Cs, all other metals were compared with the worldwide reported values of occupationally unexposed persons. Uranium concentrations show a wide variation ranging from 0.9 ± 0.05 to 449 ± 12 µg kg(-1). Although hair samples were collected from Balkan conflict zones, uranium isotopic measurement ((235)U/(238)U) shows a natural origin rather than DU.

  14. SIZE DISTRIBUTION AND RATE OF PRODUCTION OF AIRBORNE PARTICULATE MATTER GENERATED DURING METAL CUTTING

    International Nuclear Information System (INIS)

    Ebadian, M.A.; Dua, S.K.; Hillol Guha

    2001-01-01

    During deactivation and decommissioning activities, thermal cutting tools, such as plasma torch, laser, and gasoline torch, are used to cut metals. These activities generate fumes, smoke and particulates. These airborne species of matter, called aerosols, may be inhaled if suitable respiratory protection is not used. Inhalation of the airborne metallic aerosols has been reported to cause ill health effects, such as acute respiratory syndrome and chromosome damage in lymphocytes. In the nuclear industry, metals may be contaminated with radioactive materials. Cutting these metals, as in size reduction of gloveboxes and tanks, produces high concentrations of airborne transuranic particles. Particles of the respirable size range (size < 10 microm) deposit in various compartments of the respiratory tract, the fraction and the site in the respiratory tract depending on the size of the particles. The dose delivered to the respiratory tract depends on the size distribution of the airborne particulates (aerosols) and their concentration and radioactivity/toxicity. The concentration of airborne particulate matter in an environment is dependent upon the rate of their production and the ventilation rate. Thus, measuring aerosol size distribution and generation rate is important for (1) the assessment of inhalation exposures of workers, (2) the selection of respiratory protection equipment, and (3) the design of appropriate filtration systems. Size distribution of the aerosols generated during cutting of different metals by plasma torch was measured. Cutting rates of different metals, rate of generation of respirable mass, as well as the fraction of the released kerf that become respirable were determined. This report presents results of these studies. Measurements of the particles generated during cutting of metal plates with a plasma arc torch revealed the presence of particles with mass median aerodynamic diameters of particles close to 0.2 micro

  15. Grain Size Distribution and Health Risk Assessment of Metals in Outdoor Dust in Chengdu, Southwestern China.

    Science.gov (United States)

    Chen, Mengqin; Pi, Lu; Luo, Yan; Geng, Meng; Hu, Wenli; Li, Zhi; Su, Shijun; Gan, Zhiwei; Ding, Sanglan

    2016-04-01

    A total of 27 outdoor dust samples from roads, parks, and high spots were collected and analyzed to investigate the contamination of 11 metals (Cr, Mn, Co, Ni, Cu, Zn, As, Sr, Cd, Sb, and Pb) in Chengdu, China. The results showed that the samples from the high spots exhibited the highest heavy metal level compared with those from the roads and the parks, except for Ni, Cu, and Pb. The dust was classified into five grain size fractions. The mean loads of each grain size fraction of 11 determined metals displayed similar distribution, and the contribution of median size (63-125, 125-250, 250-500 μm) fractions accounted for more than 70% of overall heavy metal loads. The health risk posed by the determined metals to human via dust ingestion, dermal contact, and inhalation was investigated. Oral and respiratory bioaccessible parts of the metals in dust were extracted using simulated stomach solution and composite lung serum. The mean bioaccessibilities of 11 investigated metals in the gastric solution were much higher than those in the composite lung serum, especially Zn, Cd, and Pb. Ingestion was the most important exposure pathway with percentage greater than 70% for both children and adults. Risk evaluation results illustrated that children in Chengdu might suffer noncarcinogenic risk when exposed to outdoor dust. Given that the cancer risk values of Pb and Cr larger than 1 × 10(-4), potential carcinogenic risk might occur for Chengdu residents through outdoor dust intake.

  16. Size distribution, characteristics and sources of heavy metals in haze episode in Beijing.

    Science.gov (United States)

    Duan, Jingchun; Tan, Jihua; Hao, Jiming; Chai, Fahe

    2014-01-01

    Size segragated samples were collected during high polluted winter haze days in 2006 in Beijing, China. Twenty nine elements and 9 water soluble ions were determined. Heavy metals of Zn, Pb, Mn, Cu, As, Cr, Ni, V and Cd were deeply studied considering their toxic effect on human being. Among these heavy metals, the levels of Mn, As and Cd exceeded the reference values of National Ambient Air Quality Standard (GB3095-2012) and guidelines of World Health Organization. By estimation, high percentage of atmospheric heavy metals in PM2.5 indicates it is an effective way to control atmospheric heavy metals by PM2.5 controlling. Pb, Cd, and Zn show mostly in accumulation mode, V, Mn and Cu exist mostly in both coarse and accumulation modes, and Ni and Cr exist in all of the three modes. Considering the health effect, the breakthrough rates of atmospheric heavy metals into pulmonary alveoli are: Pb (62.1%) > As (58.1%) > Cd (57.9%) > Zn (57.7%) > Cu (55.8%) > Ni (53.5%) > Cr (52.2%) > Mn (49.2%) > V (43.5%). Positive matrix factorization method was applied for source apportionment of studied heavy metals combined with some marker elements and ions such as K, As, SO4(2-) etc., and four factors (dust, vehicle, aged and transportation, unknown) are identified and the size distribution contribution of them to atmospheric heavy metals are discussed.

  17. Distribution of metals between particulate and gaseous forms in a volcanic plume

    Science.gov (United States)

    Hinkley, T.K.

    1991-01-01

    In order to gain information on the distribution of metals between particles and gaseous forms in the plume of Kilauea volcano, a filter designed to collect metals associated with particles was followed in series by two other collectors intended to trap metals present in gaseous (atomic, molecular, or complexed) form: first an acid-bubbler bath and then a cold trap. Of the six metals measured, all of the In, Tl and Bi, and almost all of the Cd, Pb and Cu were found on the filter. None of any of the metals was detected in the acid-bubbler bath. Masses equivalent to 0.3% of the amount of Cd on the filter, 0.4% of the amount of Pb, and 9.3% of the Cu, were measured in the cold trap. The results indicate that all or nearly all of the six metals were partitioned to the particulate portion of the physical mixture of gases and particles that constitutes a volcanic plume, but that there may be systematic differences between chalcophile metals in the ways they are partitioned between particulate and gaseous phases in a cooled plume, and possibly differences in the acidity or other chemical properties of the molecular phases. ?? 1991 Springer-Verlag.

  18. Pollution distribution of heavy metals in surface soil at an informal electronic-waste recycling site.

    Science.gov (United States)

    Fujimori, Takashi; Takigami, Hidetaka

    2014-02-01

    We studied distribution of heavy metals [lead (Pb), copper (Cu) and zinc (Zn)] in surface soil at an electronic-waste (e-waste) recycling workshop near Metro Manila in the Philippines to evaluate the pollution size (spot size, small area or the entire workshop), as well as to assess heavy metal transport into the surrounding soil environment. On-site length-of-stride-scale (~70 cm) measurements were performed at each surface soil point using field-portable X-ray fluorescence (FP-XRF). The surface soil at the e-waste recycling workshop was polluted with Cu, Zn and Pb, which were distributed discretely in surface soil. The site was divided into five areas based on the distance from an entrance gate (y-axis) of the e-waste recycling workshop. The three heavy metals showed similar concentration gradients in the y-axis direction. Zn, Pb and Cu concentrations were estimated to decrease to half of their maximum concentrations at ~3, 7 and 7 m from the pollution spot, respectively, inside the informal e-waste recycling workshop. Distance from an entrance may play an important role in heavy metal transport at the soil surface. Using on-site FP-XRF, we evaluated the metal ratio to characterise pollution features of the solid surface. Variability analysis of heavy metals revealed vanishing surficial autocorrelation over metre ranges. Also, the possibility of concentration prediction at unmeasured points using geostatistical kriging was evaluated, and heavy metals had a relative "small" pollution scales and remained inside the original workshop compared with toxic organohalogen compounds. Thus, exposure to heavy metals may directly influence the health of e-waste workers at the original site rather than the surrounding habitat and environmental media.

  19. Theoretical analysis of nuclear reactors (Phase I), I-V, Part V, Determining the fine flux distribution

    International Nuclear Information System (INIS)

    Pop-Jordanov, J.

    1962-07-01

    Mono energetic neutron transport equation was solved by Carlson numerical method in cylindrical geometry. S n code was developed for the digital computer ZUSE Z23. Neutron flux distribution was determined for the RA reactor cell by applying S 4 approximation. Reactor cell was treated as D 2 O-U-D 2 O system. Time of iteration was 185 s [sr

  20. Determination of the size distribution of metallic nanoparticles by optical extinction spectroscopy

    International Nuclear Information System (INIS)

    Pena, Ovidio; Rodriguez-Fernandez, Luis; Rodriguez-Iglesias, Vladimir; Kellermann, Guinther; Crespo-Sosa, Alejandro; Cheang-Wong, Juan Carlos; Silva-Pereyra, Hector Gabriel; Arenas-Alatorre, Jesus; Oliver, Alicia

    2009-01-01

    A method is proposed to estimate the size distribution of nearly spherical metallic nanoparticles (NPs) from optical extinction spectroscopy (OES) measurements based on Mie's theory and an optimization algorithm. The described method is compared against two of the most widely used techniques for the task: transmission electron microscopy (TEM) and small-angle x-ray scattering (SAXS). The size distribution of Au and Cu NPs, obtained by ion implantation in silica and a subsequent thermal annealing in air, was determined by TEM, grazing-incidence SAXS (GISAXS) geometry, and our method, and the average radius obtained by all the three techniques was almost the same for the two studied metals. Concerning the radius dispersion (RD), OES and GISAXS give very similar results, while TEM considerably underestimates the RD of the distribution

  1. Biogeochemical and hydrological controls on fate and distribution of trace metals in oiled Gulf salt marshes

    Science.gov (United States)

    Keevan, J.; Natter, M.; Lee, M.; Keimowitz, A.; Okeke, B.; Savrda, C.; Saunders, J.

    2011-12-01

    On April 20, 2010, the drilling rig Deepwater Horizon exploded in the Gulf of Mexico, resulting in the release of approximately 5 million barrels of crude oil into the environment. Oil and its associated trace metals have been demonstrated to have a detrimental effect on coastal wetland ecosystems. Wetlands are particularly susceptible to oil contamination because they are composed largely of fine-grained sediments, which have a high capacity to adsorb organic matter and metals. The biogeochemical cycling of trace metals can be strongly influenced by microbial activity, specifically those of sulfate- and iron-reducing bacteria. Microbial activity may be enhanced by an increase in amounts of organic matter such as oil. This research incorporates an assessment of levels of trace metals and associated biogeochemical changes from ten coastal marshes in Alabama, Mississippi, and Louisiana. These sampling sites range in their pollution levels from pristine to highly contaminated. A total digestion analysis of wetland sediments shows higher concentrations of certain trace metals (e.g., Ni, Cu, Pb, Zn, Sr, Co, V, Ba, Hg, As) in heavily-oiled areas compared to less-affected and pristine sites. Due to chemical complexation among organic compounds and metals, crude oils often contain elevated levels (up to hundreds of mg/kg) of trace metals At the heavily-oiled Louisiana sites (e.g., Bay Jimmy, Bayou Dulac, Bay Batiste), elevated levels of metals and total organic carbon have been found in sediments down to depths of 30 cm. Clearly the contamination is not limited to shallow sediments and oil, along with various associated metals, may be invading into deeper (pre-industrial) portions of the marsh sediments. Pore-waters extracted from contaminated sediments are characterized by very high levels of reduced sulfur (up to 80 mg/kg), in contrast to fairly low ferrous iron concentrations (<0.02 mg/kg). The influx of oil into the wetlands might provide the initial substrate and

  2. Distribution of heavy metals in cocoa farm soils in the Western Region of Ghana

    International Nuclear Information System (INIS)

    Ackah, Justice Edusei

    2012-10-01

    Western Region is the largest cocoa producer in Ghana. Cocoa farmlands have over the past decades received heavy doses of agrochemical application to boost cocoa production. These agrochemicals, however, may contain heavy metals and it is therefore likely that the metals may have accumulated in the soils. Evaluating the total concentrations and understanding the distribution characteristics of heavy metals in cocoa growing soils can aid environmental managers and even help regulate the rate of agrochemical application. A study was therefore, carried out on some selected soils of major cocoa growing areas in Western Region of Ghana to determine the levels of cadmium (Cd), chromium (Cr), copper (Cu), iron (Fe), manganese (Mn), nickel (Ni), lead (Pb) and zinc (Zn) in the soils and also to determine some of the soil factors that control the distribution of the heavy metals in the soil. Eight soils (two Haplic Luvisols, three Ferric Acrisols, one Haplic Ferrasol and two Dystric Fluvisols) and their accompanying pristine soils as control were taken from adjacent natural forests sampled at depths of 0 – 10 cm, 10 – 30 cm, 30 – 50 cm, 50 – 80 cm and 80 – 100 cm. These soils were analysed for their particle size distribution, pH, organic carbon, cation exchange capacity, exchangeable bases, and total and bio-available Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn. The study indicated that the ΔpH which is pH_K_C_l – pH_H_2_O were all negative indicating that the soils generally had net negative charges on their colloidal surface. For all soils, clay content and pH increased with depth indicating co-migration of the two soil parameters whilst total organic carbon content decreased with depth. Cation exchange capacity, however, did not show any clear pattern with depth in the soils. The average abundance of heavy metals determined in these soils decreased as follows: Fe > Mn > Cr > Zn > Cu > Cd > Pb > Ni. The soils had low metal contents, less than or within the range of

  3. Distribution of heavy metals in sediments of the Ciujung watersheds Banten

    International Nuclear Information System (INIS)

    Th Rina Mulyaningsih; Alfian; Sutisna

    2012-01-01

    Decrease of Ciujung river quality due to industry and community activities. leading to decreased quality of the river. As a result, river designation for raw drinking water, irrigation and fisheries are not suitable. Monitoring the quality of the river is one of the strategies for the environmental protection; therefore a suitable data should be required by government in a regional planning. A study of heavy metal distribution in the watershed Ciujung was carried out to determine its quality. Number of sediment samples was taken from several sampling points in the watershed, based on its pollutant sources identification. Sampling should be limited on main river (not including tributaries) from upstream to downstream river, there are 3] sampling points. Metal was analyzed using neutron activation analysis technique and AAS. The results showed that the distribution of metals Co, As, Sb, Cr, Fe, Mn, Zn, Pb, Cu, Ni and Cd fluctuate depending on the location. The highest concentrations of metals were found in downstream and industries-] area. Evaluation based on the enrichment factor, contamination factor and index of geo accumulation, ware concluded that the quality of upstream is still good has not contaminated / polluted. Industrial-], industrial-2 area and the downstream ware contaminated by Cd metal source from human activity (anthropogenic). Evaluation based on pollution load index indicates that the river has not been contaminated, but the downstream, industry-] and 2 areas has a value almost close IBT baseline level, therefore water quality monitoring in the future remains to be carried out. (author)

  4. Spatial Distribution, Sources Apportionment and Health Risk of Metals in Topsoil in Beijing, China

    Directory of Open Access Journals (Sweden)

    Chunyuan Sun

    2016-07-01

    Full Text Available In order to acquire the pollution feature and regularities of distribution of metals in the topsoil within the sixth ring road in Beijing, a total of 46 soil samples were collected, and the concentrations of twelve elements (Nickel, Ni, Lithium, Li, Vanadium, V, Cobalt, Co, Barium, Ba, Strontium, Sr, Chrome, Cr, Molybdenum, Mo, Copper, Cu, Cadmium, Cd, Zinc, Zn, Lead, Pb were analyzed. Geostatistics and multivariate statistics were conducted to identify spatial distribution characteristics and sources. In addition, the health risk of the analyzed heavy metals to humans (adult was evaluated by an U.S. Environmental Protection Agency health risk assessment model. The results indicate that these metals have notable variation in spatial scale. The concentration of Cr was high in the west and low in the east, while that of Mo was high in the north and low in the south. High concentrations of Cu, Cd, Zn, and Pb were found in the central part of the city. The average enrichment degree of Cd is 5.94, reaching the standard of significant enrichment. The accumulation of Cr, Mo, Cu, Cd, Zn, and Pb is influenced by anthropogenic activity, including vehicle exhaustion, coal burning, and industrial processes. Health risk assessment shows that both non-carcinogenic and carcinogenic risks of selected heavy metals are within the safety standard and the rank of the carcinogenic risk of the four heavy metals is Cr > Co > Ni > Cd.

  5. Spatial Distribution, Sources Apportionment and Health Risk of Metals in Topsoil in Beijing, China.

    Science.gov (United States)

    Sun, Chunyuan; Zhao, Wenji; Zhang, Qianzhong; Yu, Xue; Zheng, Xiaoxia; Zhao, Jiayin; Lv, Ming

    2016-07-20

    In order to acquire the pollution feature and regularities of distribution of metals in the topsoil within the sixth ring road in Beijing, a total of 46 soil samples were collected, and the concentrations of twelve elements (Nickel, Ni, Lithium, Li, Vanadium, V, Cobalt, Co, Barium, Ba, Strontium, Sr, Chrome, Cr, Molybdenum, Mo, Copper, Cu, Cadmium, Cd, Zinc, Zn, Lead, Pb) were analyzed. Geostatistics and multivariate statistics were conducted to identify spatial distribution characteristics and sources. In addition, the health risk of the analyzed heavy metals to humans (adult) was evaluated by an U.S. Environmental Protection Agency health risk assessment model. The results indicate that these metals have notable variation in spatial scale. The concentration of Cr was high in the west and low in the east, while that of Mo was high in the north and low in the south. High concentrations of Cu, Cd, Zn, and Pb were found in the central part of the city. The average enrichment degree of Cd is 5.94, reaching the standard of significant enrichment. The accumulation of Cr, Mo, Cu, Cd, Zn, and Pb is influenced by anthropogenic activity, including vehicle exhaustion, coal burning, and industrial processes. Health risk assessment shows that both non-carcinogenic and carcinogenic risks of selected heavy metals are within the safety standard and the rank of the carcinogenic risk of the four heavy metals is Cr > Co > Ni > Cd.

  6. Distribution of metals and metalloids in dried seaweeds and health risk to population in southeastern China.

    Science.gov (United States)

    Chen, Qing; Pan, Xiao-Dong; Huang, Bai-Fen; Han, Jian-Long

    2018-02-23

    Concern about metals and metalloids, especially heavy metals in seaweeds has risen due to potential health risk. This study investigated the distribution of 10 metals and metalloids in 295 dried seaweeds (brown and red) and estimated the possible health risk via hazard index (HI). Elements in seaweeds can be sequenced in descending order by mean values: Al > Mn > As > Cu > Cr > Ni > Cd > Se > Pb > Hg. The levels of Cd, Cu, Mn and Ni in red seaweeds were significantly higher than those in brown seaweeds (P < 0.01). Correlation analysis showed contents of Ni-Cr (r = 0.59, P < 0.01) in seaweeds had moderate positive correlations. Seaweeds from different geographical origins had diverse element distribution. Risk assessment showed that HI at mean level was less than the threshold of 1. It indicates that for the general people there is low health risk to these elements by the intake of seaweeds. Furthermore, in terms of the confirmative toxicity of some metals, such as Cd, Pb and Hg, surveillance of metals in seaweeds should be performed continuously.

  7. Fractionation And Distribution Of Heavy Metals In street Dust In Amman, Jordan

    International Nuclear Information System (INIS)

    Jaradat, Q.

    2002-01-01

    Different types of street dust: major streets, minor streets, gas stations, traffic lights and car parks in Amman were subjected to size-fractionation into three sizes: 500-125μm , 125-53μm, and <53μm. Sequential extraction was also performed on the non-fractionated samples using Tessier procedure. The sequentially extracted and the fractionated samples were analyzed for Pb, Cd, Zn and Mn using flame atomic absorption. The silt fraction ( <53μm particles ) contains the highest concentrations of all elements in most types of street dust samples followed by the fine fraction ( 125-53μm particles). From the sequential extraction data, the highest concentrations of heavy metals were : Pb, Cd, Zn and in Fe-Mn oxide fraction, and Cu in the organic fraction. (author). 29 refs., 2 figs., 4 tabs

  8. Speciation dynamics of metals in dispersion of nanoparticles with discrete distribution of charged binding sites.

    Science.gov (United States)

    Polyakov, Pavel D; Duval, Jérôme F L

    2014-02-07

    We report a comprehensive theory to evaluate the kinetics of complex formation between metal ions and charged spherical nanoparticles. The latter consist of an ion-impermeable core surrounded by a soft shell layer characterized by a discrete axisymmetric 2D distribution of charged sites that bind metal ions. The theory explicitly integrates the conductive diffusion of metal ions from bulk solution toward the respective locations of the reactive sites within the particle shell volume. The kinetic constant k for outer-sphere nanoparticle-metal association is obtained from the sum of the contributions stemming from all reactive sites, each evaluated from the corresponding incoming flux of metal ions derived from steady-state Poisson-Nernst-Planck equations. Illustrations are provided to capture the basic intertwined impacts of particle size, overall particle charge, spatial heterogeneity in site distribution, type of particle (hard, core-shell or porous) and concentration of the background electrolyte on k. As a limit, k converges with predictions from previously reported analytical expressions derived for porous particles with low and high charge density, cases that correspond to coulombic and mean-field (smeared-out) electrostatic treatments, respectively. The conditions underlying the applicability of these latter approaches are rigorously identified in terms of (i) the extent of overlap between electric double layers around charged neighbouring sites, and (ii) the magnitude of the intraparticulate metal concentration gradient. For the first time, the proposed theory integrates the differentiated impact of the local potential around the charged binding sites amidst the overall particle field, together with that of the so-far discarded intraparticulate flux of metal ions.

  9. Distribution of Rare Earth Metals in Technogenic Wastes of Energy Enterprises (Results of the Laboratory Studies)

    OpenAIRE

    Alexandr Ivanovich Khanchuk; Aleksandr Alekseevich Yudakov; Mikhail Azaryevich Medkov; Leonid Nikolayevich Alekseyko; Andrey Vasilyevich Taskin; Sergey Igorevich Ivannikov

    2016-01-01

    The results of the research interaction between ash and slag samples from Vladivostok TPP’s landfills saturated with underburning and ammonium hydrodifluoride were given. It was found out that the reactions of the main components of a concentrate with NH4HF2 are flowing with creation of complex ammonium fluoro-metalate. It is shown that the distribution of REM (rare earth metals) between foam and heavier products is going during the flotation process of carbon-containing ash and slag samples ...

  10. Distribution, relationship, and risk assessment of toxic heavy metals in walnuts and growth soil.

    Science.gov (United States)

    Han, Yongxiang; Ni, Zhanglin; Li, Shiliang; Qu, Minghua; Tang, Fubin; Mo, Runhong; Ye, Caifen; Liu, Yihua

    2018-04-14

    Walnut is one of the most popular nuts worldwide and contains various mineral nutrients. Little is known, however, about the relationship between toxic heavy metals in walnuts and growth soil. In this study, we investigated the distribution, relationship, and risk assessment of five toxic heavy metals-lead (Pb), arsenic (As), chromium (Cr), cadmium (Cd), and mercury (Hg)-in walnuts and growth soil in the main production areas of China. The results showed that the main heavy metal pollution in walnut and soil was Pb and Cd. Regionally, positive relationships existed between heavy metals and the pH and organic matter of soil. In addition, we observed a notable uptake effect between walnut and growth soil. In this study, we found a significant correlation (r = 0.786, P toxic heavy metal pollution in walnuts and growth soil could be helpful to screen suitable planting sites to prevent and control heavy metal pollution and improve the quality and safety of walnut.

  11. Spatial distribution and risk assessment of heavy metals in sediments of Shuangtaizi estuary, China

    International Nuclear Information System (INIS)

    Li, Chen; Song, Chengwen; Yin, Yanyan; Sun, Menghan; Tao, Ping; Shao, Mihua

    2015-01-01

    Highlights: • Five heavy metals are analyzed in the sediments from Shuangtaizi estuary. • Particle size of the sediment effects the concentration of heavy metals. • Pb, Cu, Zn and Hg pose low ecological risks in the Shuangtaizi estuary. • Heavy metal pollution in Shuangtaizi estuary is mainly dominated by Cd. - Abstract: In order to evaluate the spatial distribution and potential ecological risk of Pb, Cu, Zn, Cd, and Hg, the surface sediments were collected from 18 sites in the Shuangtaizi estuary. The concentrations of Pb, Cu, Zn, Cd, and Hg were analyzed by atomic absorption spectrophotometry and atomic fluorescence spectrometry after digestion. The particle sizes of the sediments were analyzed using a laser diffraction particle size analyzer. The results show that the heavy metal contents in the sediments are observed in the following order: Zn (18.25–126.75 mg/kg) > Pb (4.38–9.65 mg/kg) > Cu (1.80–17.68 mg/kg) > Cd (0.241–0.764 mg/kg) > Hg (0.007–0.021 mg/kg). In comparison with the concentrations of heavy metals in other regions, the concentrations of Pb, Cu, and Zn in the Shuangtaizi estuary are generally low, and the Cd concentrations are close to those reported in other regions. Both the potential ecological risk index and the geoaccumulation index reveal that the heavy metal pollution in Shuangtaizi estuary is mainly dominated by Cd

  12. Levy's distributions for statistical description of fractal structures; discontinuous metal films on dielectric substrates

    International Nuclear Information System (INIS)

    Dobierzewska-Mozrzymas, E.; Szymczak, G.; Bieganski, P.; Pieciul, E.

    2003-01-01

    The ranges of statistical description of the systems may be determined on the basis of the inverse power law of the Mandelbrot. The slope of the straight line representing the power law in a double-logarithmic plot, determined as -1/μ (μ being a critical exponent), characterizes the distribution of elements in the system. In this paper, the inverse power law is used to describe the statistical distribution of discontinuous metal films with higher coverage coefficients (near percolation threshold). For these films the critical exponent μ∼1, both the mean value and the variance are infinite. The objects with such microstructure are described according to the Levy distribution; Cauchy, inverse Gauss and inverse gamma distribution, respectively. The experimental histograms are compared with the calculated ones. Inhomogeneous metal films were obtained experimentally, their microstructures were examined by means of electron microscope. On the basis of electron micrographs, the fractal dimensions were determined for the metal films with coverage coefficient ranging from 0.35 to 1.00

  13. Assessment of heavy metals in loose deposits in drinking water distribution system.

    Science.gov (United States)

    Liu, Quanli; Han, Weiqiang; Han, Bingjun; Shu, Min; Shi, Baoyou

    2018-06-09

    Heavy metal accumulation and potential releases from loose deposits in drinking water distribution system (DWDS) can have critical impacts on drinking water safety, but the associated risks have not been sufficiently evaluated. In this work, the potential biological toxicity of heavy metals in loose deposits was calculated based on consensus-based sediment quality guidelines, and the effects of some of the main water quality parameters, such as the pH and bicarbonate and phosphate content, on the release behaviors of pre-accumulated heavy metals were investigated. The results showed that heavy metals (Cu, As, Cr, Pb, and Cd) significantly accumulated in all the samples, but the contents of the heavy metals were multiple magnitudes lower than the Fe and Mn contents. The potential biotoxicity of As and Cu was relatively high, but the biotoxicity of Cd was negligible. The water quality can significantly influence the release of heavy metals from loose deposits. As the pH increased from 7.0 to 9.0, the release of As and Cr obviously increased. The release of As, Cu, Pb, and Cr also accelerated with the addition of phosphate (from 1 to 5 mg/L). In contrast to the trends for the pH and phosphate, variations in the bicarbonate content did not have a significant influence on the release of As and Cr. The release ratios of heavy metals in the samples were very low, and there was not a correlation between the release rate of the heavy metals in the loose deposits and their potential biotoxicity.

  14. Distribution of Heavy Metal Pollution in Surface Soil Samples in China: A Graphical Review.

    Science.gov (United States)

    Duan, Qiannan; Lee, Jianchao; Liu, Yansong; Chen, Han; Hu, Huanyu

    2016-09-01

    Soil pollution in China is one of most wide and severe in the world. Although environmental researchers are well aware of the acuteness of soil pollution in China, a precise and comprehensive mapping system of soil pollution has never been released. By compiling, integrating and processing nearly a decade of soil pollution data, we have created cornerstone maps that illustrate the distribution and concentration of cadmium, lead, zinc, arsenic, copper and chromium in surficial soil across the nation. These summarized maps and the integrated data provide precise geographic coordinates and heavy metal concentrations; they are also the first ones to provide such thorough and comprehensive details about heavy metal soil pollution in China. In this study, we focus on some of the most polluted areas to illustrate the severity of this pressing environmental problem and demonstrate that most developed and populous areas have been subjected to heavy metal pollution.

  15. Spatial distribution and pollution evaluation of heavy metals in Yangtze estuary sediment.

    Science.gov (United States)

    Liu, Ruimin; Men, Cong; Liu, Yongyan; Yu, Wenwen; Xu, Fei; Shen, Zhenyao

    2016-09-15

    To analyze the spatial distribution patterns and ecological risks of heavy metals, 30 sediment samples were taken in the Yangtze River Estuary (YRE) in May 2011. The content of Al, As, Cr, Cu, Fe, Mn, Ni and Pb increased as follows: inner-regionpollutants. What is more, the greatest contaminated area appeared at the river mouth of the south branch of YRE. In Tucker 3, considering the fractions of metals, Mn turned to be the severest pollutant and As did not contribute too much to the contamination of the YRE. That was most probably because that Mn was closely related to the carbonate-associated (CARB) and As was related to organic-associated (OM) which is more stable than CARB. The fractions played an important role in the contamination assessment of heavy metals. Copyright © 2016 Elsevier Ltd. All rights reserved.

  16. Heavy metals concentration and distribution in soils and vegetation at Korle Lagoon area in Accra, Ghana

    DEFF Research Database (Denmark)

    Fosu-Mensah, Benedicta Yayra; Addae, Emmanuel; Yirenya-Tawiah, Dzidzo

    2017-01-01

    The call for reclamation of land around Korle Lagoon in Accra, Ghana, where burning of E-waste and cultivation of vegetables takes place, make risk assessment of heavy metal contaminations important. This study aimed at evaluating the levels and risk of heavy metal contamination in soils...... and vegetation around the Korle lagoon area in Accra. Geoaccumulation index, enrichment factor and pollution load index were determined to assess the risk of contamination. The levels and distribution of nine heavy metals (Pb, Hg, Cd, As, Zn, Sn, Ni, Cu and Cr) in soil (0 – 20 cm) and common vegetation (Panicum...... was significantly different (p burning of e-waste should be enforced and animals...

  17. Geochemical distribution of trace metals and organochlorine contaminants of a lake ontario shoreline marsh

    Energy Technology Data Exchange (ETDEWEB)

    Glooschenko, W A; Capocianco, J; Coburn, J; Glooschenko, V

    1981-02-01

    Rattray Marsh, an 8 ha marsh on the Lake Ontario shoreline at Mississauga, Ontario, is an important local habitat for waterfowl and shorebirds during spring and fall migration. A study was conducted to determine the distribution of nutrients (carbon, nitrogen, and phosphorus) and potential trace metal and organochlorine pollutants in the marsh as evidenced by the sedimentary concentrations of these compounds. Generally, copper, zinc, lead, and mercury were higher in concentration in local soils than in Lake Ontario sediments. Metals and organic carbon levels did not correlate, and the metals appeared to be associated with silts and clays. Organochlorine contaminants include p,p1-DDE, p,p1-DDD, p,p1-DDT, alpha-chlordane, PCB, mirex, and HCB.

  18. Distribution and mobility of metals in contaminated sites. chemometric investigation of pollutant profiles.

    Science.gov (United States)

    Abollino, Ornella; Aceto, Maurizio; Malandrino, Mery; Mentasti, Edoardo; Sarzanini, Corrado; Barberis, Renzo

    2002-01-01

    The distribution and mobility of heavy metals in the soils of two contaminated sites in Piedmont (Italy) was investigated, evaluating the horizontal and vertical profiles of 15 metals, namely Al, Cd, Cu, Cr, Fe. La, Mn, Ni, Pb, Sc, Ti, V, Y, Zn and Zr. The concentrations in the most polluted areas of the sites were higher than the acceptable limits reported in Italian and Dutch legislations for soil reclamation. Chemometric elaboration of the results by pattern recognition techniques allowed us to identify groups of samples with similar characteristics and to find correlations among the variables. The pollutant mobility was studied by extraction with water, dilute acetic acid and EDTA and by applying Tessier's procedure. The fraction of mobile species, which potentially is the most harmful for the environment, was found to be higher than the one normally present in unpolluted soils, where heavy metals are, to a higher extent, strongly bound to the matrix.

  19. Spatial heavy metals Zn and Cr distribution in soil samples taken from Tatra Mountains

    International Nuclear Information System (INIS)

    Stobinski, M.; Misiak, R.; Kubica, B.

    2008-03-01

    The basic issue of presented report is showing the spatial heavy metals (Zn and Cr) distribution in soil samples taken from High Mts area. The expertise was done using two analytical techniques: AAS (atomic absorption spectroscopy) and micro-PIXIE (proton induced X-ray emission).Given heavy metals concentration were originated either from soil surface (10 cm depth) or from the whole soil profile. Our evaluation indicates that the Zn and Cr levels measured for mountains region were comparable to the data presented by other authors. Furthermore, the amount of heavy metals is strongly correlated with its natural concentration in parental rock.We also observed that zinc was prone to accumulate in surface, rich in organic matter, soil levels. (author)

  20. Angular and mass resolved energy distribution measurements with a gallium liquid metal ion source

    International Nuclear Information System (INIS)

    Marriott, Philip

    1987-06-01

    Ionisation and energy broadening mechanisms relevant to liquid metal ion sources are discussed. A review of experimental results giving a picture of source operation and a discussion of the emission mechanisms thought to occur for the ionic species and droplets emitted is presented. Further work is suggested by this review and an analysis system for angular and mass resolved energy distribution measurements of liquid metal ion source beams has been constructed. The energy analyser has been calibrated and a series of measurements, both on and off the beam axis, of 69 Ga + , Ga ++ and Ga 2 + ions emitted at various currents from a gallium source has been performed. A comparison is made between these results and published work where possible, and the results are discussed with the aim of determining the emission and energy spread mechanisms operating in the gallium liquid metal ion source. (author)

  1. Influence of Flue Gas Desulfurization Gypsum Amendments on Heavy Metal Distribution in Reclaimed Sodic Soils

    Science.gov (United States)

    Chen, Qun; Wang, Shujuan; Li, Yan; Zhang, Ning; Zhao, Bo; Zhuo, Yuqun; Chen, Changhe

    2015-01-01

    Abstract Although flue gas desulfurization (FGD) gypsum has become an effective soil amendment for sodic soil reclamation, it carries extra heavy metal contamination into the soil environment. The fate of heavy metals introduced by FGD gypsum in sodic or saline–alkali soils is still unclear. This work aims to investigate the effects of FGD gypsum addition on the heavy metal distributions in a sodic soil. Original soil samples were collected from typical sodic land in north China. Soil column leaching tests were conducted to investigate the influence of FGD gypsum addition on the soil properties, especially on distribution profiles of the heavy metals (Pb, Cd, Cr, As, and Hg) in the soil layers. Results showed that pH, electrical conductivity, and exchangeable sodium percentage in amended soils were significantly reduced from 10.2 to 8.46, 1.8 to 0.2 dS/m, and 18.14% to 1.28%, respectively. As and Hg concentrations in the soils were found to be positively correlated with FGD gypsum added. The amount of Hg in the leachate was positively correlated with FGD gypsum application ratio, whereas a negative correlation was observed between the Pb concentration in the leachate and the FGD gypsum ratio. Results revealed that heavy metal concentrations in soils complied well with Environmental Quality Standard for Soils in China (GB15618-1995). This work helps to understand the fate of FGD gypsum-introduced heavy metals in sodic soils and provides a baseline for further environmental risk assessment associated with applying FGD gypsum for sodic soil remediation. PMID:26064038

  2. Influence of Flue Gas Desulfurization Gypsum Amendments on Heavy Metal Distribution in Reclaimed Sodic Soils.

    Science.gov (United States)

    Chen, Qun; Wang, Shujuan; Li, Yan; Zhang, Ning; Zhao, Bo; Zhuo, Yuqun; Chen, Changhe

    2015-06-01

    Although flue gas desulfurization (FGD) gypsum has become an effective soil amendment for sodic soil reclamation, it carries extra heavy metal contamination into the soil environment. The fate of heavy metals introduced by FGD gypsum in sodic or saline-alkali soils is still unclear. This work aims to investigate the effects of FGD gypsum addition on the heavy metal distributions in a sodic soil. Original soil samples were collected from typical sodic land in north China. Soil column leaching tests were conducted to investigate the influence of FGD gypsum addition on the soil properties, especially on distribution profiles of the heavy metals (Pb, Cd, Cr, As, and Hg) in the soil layers. Results showed that pH, electrical conductivity, and exchangeable sodium percentage in amended soils were significantly reduced from 10.2 to 8.46, 1.8 to 0.2 dS/m, and 18.14% to 1.28%, respectively. As and Hg concentrations in the soils were found to be positively correlated with FGD gypsum added. The amount of Hg in the leachate was positively correlated with FGD gypsum application ratio, whereas a negative correlation was observed between the Pb concentration in the leachate and the FGD gypsum ratio. Results revealed that heavy metal concentrations in soils complied well with Environmental Quality Standard for Soils in China (GB15618-1995). This work helps to understand the fate of FGD gypsum-introduced heavy metals in sodic soils and provides a baseline for further environmental risk assessment associated with applying FGD gypsum for sodic soil remediation.

  3. Concentrations and distributions of metals associated with dissolved organic matter from the Suwannee River (GA, USA)

    Science.gov (United States)

    Kuhn, M. Keshia; Neubauer, Elisabeth; Hofmann, Thilo; von der Kammer, Frank; Aiken, George R.; Maurice, Patricia A.

    2015-01-01

    Concentrations and distributions of metals in Suwannee River (SR) raw filtered surface water (RFSW) and dissolved organic matter (DOM) processed by reverse osmosis (RO), XAD-8 resin (for humic and fulvic acids [FA]), and XAD-4 resin (for “transphilic” acids) were analyzed by asymmetrical flow field-flow fractionation (AsFlFFF). SR samples were compared with DOM samples from Nelson's Creek (NLC), a wetland-draining stream in northern Michigan; previous International Humic Substances Society (IHSS) FA and RO samples from the SR; and an XAD-8 sample from Lake Fryxell (LF), Antarctica. Despite application of cation exchange during sample processing, all XAD and RO samples contained substantial metal concentrations. AsFlFFF fractograms allowed metal distributions to be characterized as a function of DOM component molecular weight (MW). In SR RFSW, Fe, Al, and Cu were primarily associated with intermediate to higher than average MW DOM components. SR RO, XAD-8, and XAD-4 samples from May 2012 showed similar MW trends for Fe and Al but Cu tended to associate more with lower MW DOM. LF DOM had abundant Cu and Zn, perhaps due to amine groups that should be present due to its primarily algal origins. None of the fractograms showed obvious evidence for mineral nanoparticles, although some very small mineral nanoparticles might have been present at trace concentrations. This research suggests that AsFlFFF is important for understanding how metals are distributed in different DOM samples (including IHSS samples), which may be key to metal reactivity and bioavailability.

  4. Concentrations, Distribution, and Ecological Risk Assessment of Heavy Metals in Daya Bay, China

    Directory of Open Access Journals (Sweden)

    Huijuan Tang

    2018-06-01

    Full Text Available Surface sediment samples were collected from 19 sites throughout Daya Bay, China to study the concentrations, spatial distributions, potential ecological risk, and possible sources of heavy, including metals copper (Cu, zinc (Zn, arsenic (As, cadmium (Cd, nickel (Ni, lead (Pb, mercury (Hg, and chromium (Cr. The mean concentrations of the eight heavy metals were 24, 109, 6.5, 0.09, 35.3, 26.8, 0.07, and 109 µg g−1, respectively. The concentrations of most heavy metals were within range of those recorded in previous years. The spatial distribution pattern of most heavy metals were similar, with lowest values recorded along the southeast coast and the open sea area; the highest values were recorded in the northern Daya Bay, especially the northwest. Cu, Zn, As, Cd, Pb, and Hg were classified as Class I, and Ni and Cr were classified as Class II according to the Sediment Quality Guidelines (SQGs of China. The potential ecological risk (Eif indices of Cu, Zn, As, Pb, Ni, and Cr specify that these metals pose low risk to the ecosystem of the Bay, whereas Cd and Hg pose a very high risk in some sites. The geoaccumulation indices (Igeo of Cu, Zn, As, Ni, and Cr specify weak or no pollution in Daya Bay, whereas those of Pb, Cd, and Hg in some sites indicate moderate or even high pollution. Spatial distribution, carbon/nitrogen analysis, Pearson correlation, and principal components analysis indicated that Cu, Zn, As, Pb, Ni, Cr, total organic carbon (TOC, and total nitrogen (TN originated from the same sources. Ballast water or sewage from the cargo ships that park at the harbors or anchor in the Bay were the important sources for Cu, Zn, As, Pb, Ni, Cr, TOC, and TN. Other anthropogenic sources, such as agricultural runoff and aquaculture, might also be responsible, whereas Hg and Cd originated from other point sources.

  5. Mathematical modelling for distribution of heavy metals in estuary area of Red River (Vietnam)

    Science.gov (United States)

    Nguyen, N. T. T.; Volkova, I. V.

    2018-05-01

    In this paper, the authors studied the features of spatial distribution of some heavy metals (Pb, Hg, As) in the system “suspended substance - bottom sediments” in the mouth area of the Red River (Vietnam). A mathematical modelling for diffusion processes of heavy metals in a suspended form, in bottom sediments and the spatial analysis for the results of these models were proposed and implemented. The studies were carried out during main hydrological seasons of 2014 - 2016 (during the flood and inter-natal periods). The propagation of heavy metals was modeled by solving the equation of turbulent diffusion. A spatial analysis of the content of heavy metals in the suspended form and in the bottom sediments was implemented by using the interpolation model in ArcGIS 10.2.2. The distribution of Pb, Hg, As concentration of the suspended form and bottom sediment phases in the estuary area of the Red River was characterized by maximum in the mouths of the branches and general decreasing gradient towards the sea. Maximum concentrations of Pb, Hg in suspended forms were observed in the surface layer of water at the river-sea barrier. The content of Hg and As in the estuary region of the Red River was observed in the following order: SSsurfBS.

  6. Heavy Metal Distribution in Opportunistic Beach Nourishment: A Case Study in Greece

    Directory of Open Access Journals (Sweden)

    Spyros Foteinis

    2013-01-01

    Full Text Available The existence and distribution of persistent pollutants, such as heavy metals, in coastal sediment used for opportunistic beach nourishment, is a problem that has not received much attention. Here, we assessed the coastal sediments in one restoration project for the occurrence and distribution of heavy metals, by utilizing an Energy Dispersive X-Ray Fluorescence (EDXRF system. Heavy metal point sources included (i the effluents of small industries (tanneries, (ii wastewater treatment plant effluents, and (iii paint and oil scraps from substandard ship maintenance activities that take place on ports breakwaters. A few neighboring beaches were found to have similar heavy metal concentrations, with mean values of Cu, Zn, and Pb ranging from 80 to 130, 15 to 25, and 25 to 40 mg/kg, respectively. Existing legislation regarding dredging activities in Greece appears insufficient for sustainable and environmentally friendly nourishment. We conclude that before opportunistic beach restoration projects materialize with material borrowed from ports and harbors the quality of the dredged material needs to be assessed.

  7. Anne Fine

    Directory of Open Access Journals (Sweden)

    Philip Gaydon

    2015-04-01

    Full Text Available An interview with Anne Fine with an introduction and aside on the role of children’s literature in our lives and development, and our adult perceptions of the suitability of childhood reading material. Since graduating from Warwick in 1968 with a BA in Politics and History, Anne Fine has written over fifty books for children and eight for adults, won the Carnegie Medal twice (for Goggle-Eyes in 1989 and Flour Babies in 1992, been a highly commended runner-up three times (for Bill’s New Frock in 1989, The Tulip Touch in 1996, and Up on Cloud Nine in 2002, been shortlisted for the Hans Christian Andersen Award (the highest recognition available to a writer or illustrator of children’s books, 1998, undertaken the positon of Children’s Laureate (2001-2003, and been awarded an OBE for her services to literature (2003. Warwick presented Fine with an Honorary Doctorate in 2005. Philip Gaydon’s interview with Anne Fine was recorded as part of the ‘Voices of the University’ oral history project, co-ordinated by Warwick’s Institute of Advanced Study.

  8. Surficial and vertical distribution of heavy metals in different estuary wetlands in the Pearl river, South China

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Honggang; Cui, Baoshan [State Key Joint Laboratory of Environmental Simulation and Pollution Control, School of Environment, Beijing Normal University, Beijing (China); Zhang, Kejiang [Xinjiang Research Center of Water and Wastewater Treatment, Xinjiang Deland Co., LTD., Urumqi (China)

    2012-10-15

    A total of 87 soil profiles sampled from five types of wetlands in the Pearl River estuary were analyzed to investigate the surficial and vertical distributions of heavy metals (Cd, Cr, Cu, Ni, Pb, and Zn). The results show that wetlands directly connected with rivers (e.g., riparian wetlands, estuarine wetlands, and mangrove wetlands) has much higher metal concentrations than those indirectly connected with rivers (e.g., pond wetlands and reclaimed wetlands). The river water is the major pollution source for all investigated heavy metals. The vertical distribution of heavy metals can be classified into three patterns: (i) linear distribution pattern. The concentration of heavy metals gradually decreases with an increase in soil depth (for riparian and estuarine wetlands); (ii) irregular and stable pattern (for pond and reclaimed wetlands); and (iii) middle enrichment pattern (for mangrove wetlands). In addition to river-borne inputs, a variety of vegetation composition, hydraulic conditions, and human activities also contribute to the variation in distribution of heavy metals in different wetlands. Soil properties (e.g., particle size, pH, salinity, and SOM) also affect the distribution of trace metals in each soil layer. The major pollution source of heavy metals is industrial wastewater. Other sources include agriculture and domestic premises, and atmospheric deposition. This study provides a sound basis for the risk assessment of heavy metals in the studied wetlands and for wetland conservation in general. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  9. Distribution of particulate trace metals in the western Bay of Bengal

    Digital Repository Service at National Institute of Oceanography (India)

    Satyanarayana, D.; Murty, P.V.S.P.; Sarma, V.V.

    continuous increase from surface to bottom in the case ofFe, Ni, which appeared to be related to a combination offactors suchas authigenicprecipita tion/scavenging, rcsuspension of bottom rich sediments, and diffusion followed by precipitation at sedimcnt... ), most of these studies do not provide information onthe interaction of trace elements with particulate matter. The present study deals with the distribution of particulate trace metals (Fe, Mn, Co, Ni, Cu, Pb, Zn and Cd) and their possible interactions...

  10. STATISTICAL DISTRIBUTION PATTERNS IN MECHANICAL AND FATIGUE PROPERTIES OF METALLIC MATERIALS

    OpenAIRE

    Tatsuo, SAKAI; Masaki, NAKAJIMA; Keiro, TOKAJI; Norihiko, HASEGAWA; Department of Mechanical Engineering, Ritsumeikan University; Department of Mechanical Engineering, Toyota College of Technology; Department of Mechanical Engineering, Gifu University; Department of Mechanical Engineering, Gifu University

    1997-01-01

    Many papers on the statistical aspect of materials strength have been collected and reviewed by The Research Group for Statistical Aspects of Materials Strength.A book of "Statistical Aspects of Materials Strength" was written by this group, and published in 1992.Based on the experimental data compiled in this book, distribution patterns of mechanical properties are systematically surveyed paying an attention to metallic materials.Thus one can obtain the fundamental knowledge for a reliabilit...

  11. The distribution of heavy metals in the red abalone, haliotis rufescens, on the california coast

    Energy Technology Data Exchange (ETDEWEB)

    Anderlini, V.

    1974-01-01

    The gills, mantle, digestive gland, and foot muscle of 74 specimens of the red abalone, haliotis rufescens, from five localities on the california coast are analyzed for eight heavy metals. The distribution of these elements in the abalones appears to be non-normal. High lead concentrations in the la jolla-long beach area seem to reflect pollutant inputs; elsewhere lead levels appear to derive from natural sources. (1 graph, 1 map, 31 references, 1 table)

  12. The Particle Distribution in Liquid Metal with Ceramic Particles Mould Filling Process

    Science.gov (United States)

    Dong, Qi; Xing, Shu-ming

    2017-09-01

    Adding ceramic particles in the plate hammer is an effective method to increase the wear resistance of the hammer. The liquid phase method is based on the “with the flow of mixed liquid forging composite preparation of ZTA ceramic particle reinforced high chromium cast iron hammer. Preparation method for this system is using CFD simulation analysis the particles distribution of flow mixing and filling process. Taking the 30% volume fraction of ZTA ceramic composite of high chromium cast iron hammer as example, by changing the speed of liquid metal viscosity to control and make reasonable predictions of particles distribution before solidification.

  13. Temporal variations in metallothionein concentration and subcellular distribution of metals in gills and digestive glands of the oyster Crassostrea angulata

    Directory of Open Access Journals (Sweden)

    Chiara Trombini

    2010-11-01

    Full Text Available The metallothionein levels and metal concentrations in whole body, digestive gland and gills of Crassostrea angulata were analyzed in field samples collected from the River Guadalquivir estuary over several years following a mining waste spill upstream. The subcellular distribution of metals was analyzed to determine the mechanisms involved in the detoxification process. The highest metallothionein levels were reported in the digestive gland shortly after the mining contamination event. In this organ, metals are stored preferentially in the non-cytosolic fraction when increased bioaccumulation takes place. In the cytosol of the gills, metals are associated with metallothionein, whereas in the digestive gland, the distribution of metals between metallothioneins and high molecular weight proteins is similar. Metallothionein variation cannot be explained by metals alone; other abiotic factors must be taken into account. In order to use metallothionein as a metal exposure biomarker in field studies, natural variability needs to be taken into account for the correct interpretation of results.

  14. Distribution and Analysis of Heavy Metals Contamination in Soil, Perlis, Malaysia

    Science.gov (United States)

    Nihla Kamarudzaman, Ain; Woo, Yee Shan; Jalil, Mohd Faizal Ab

    2018-03-01

    The concentration of six heavy metals such as Cu, Cr, Ni, Cd, Zn and Mn were studied in the soils around Perlis. The aim of the study is to assess the heavy metals contamination distribution due to industrialisation and agricultural activities. Soil samples were collected at depth of 0 - 15 cm in five stations around Perlis. The soil samples are subjected to soil extraction and the concentration of heavy metals was determined via ICP - OES. Overall concentrations of Cr, Cu, Zn, Ni, Cd and Mn in the soil samples ranged from 0.003 - 0.235 mg/L, 0.08 - 41.187 mg/L, 0.065 - 45.395 mg/L, 0.031 - 2.198 mg/L, 0.01 - 0.174 mg/L and 0.165 - 63.789 mg/L respectively. The concentration of heavy metals in the soil showed the following decreasing trend, Mn > Zn > Cu > Ni > Cr > Cd. From the result, the level of heavy metals in the soil near centralised Chuping industrial areas gives maximum value compared to other locations in Perlis. As a conclusion, increasing anthropogenic activities have influenced the environment, especially in increasing the pollution loading.

  15. The spatial and temporal distribution of heavy metals in sediments of Victoria Harbour, Hong Kong

    International Nuclear Information System (INIS)

    Tang, Chloe Wing-yee; Ip, Carman Ching-man; Zhang Gan; Shin, Paul K.S.; Qian Peiyuan; Li Xiangdong

    2008-01-01

    Victoria Harbour has received substantial loadings of pollutants from industrial and municipal wastewater discharged since the 1950s. Inputs of contaminants have declined dramatically during the last two decades as a result of better controls at the source and improved wastewater treatment facilities. To assess the spatial and temporal changes of metal contaminants in sediments in Victoria Harbour, core and grab sediments were collected. The central harbour areas were generally contaminated with heavy metals. The spatial distribution of trace metals can probably be attributed to the proximity of major urban and industrial discharge points, and to the effect of tidal flushing in the harbour. In the sediment cores, the highest concentrations of trace metals were observed to have accumulated during the 1950s-1980s, corresponding with the period of rapid urban and industrial development in Hong Kong. From the late 1980s, there has been a major decline in the concentrations of trace metals, due to a reduction in industrial activities and to the enactment of wastewater pollution controls in the territory. The Pb isotopic compositions of the sediments revealed the anthropogenic inputs of Pb to the harbour. The 206 Pb/ 207 Pb ratios varied from 1.154 to 1.190, which were lower than those of background geological materials in Hong Kong ( 206 Pb/ 207 Pb: 1.201-1.279). The data also indicated that the Pb in the harbour sediments most likely originated from mixed sources, including the leaded gasoline used in the past and other anthropogenic sources

  16. Heavy metal concentrations and distribution in surface soils of the Bassa Industrial Zone 1, Douala, Cameroon

    International Nuclear Information System (INIS)

    Asaah, Victor A.; Abimbola, Akinlolu F.; Suh, Cheo E.

    2006-01-01

    Partial extraction was carried out on 33 soil samples collected from the Bassa Industrial Zone 1, Douala, Cameroon. From the samples analyzed the following metal concentrations (range) were obtained (in ppm): Ag (0-1.3), As (0-64), Cd(0-7.3), Co(0-31), Cr(34-423), Cu(12-909), Mn(55-3282), Mo(0-81.6), Ni(9-284), Pb (0-3320), Sb (0-30), Sc (0.6-7.5), V (26-110), Zn (30-3782) and Fe (in wt%) (1.50-47.31). Results obtained reveal background and anomalous populations for most of the metals except Sc and V, which have only background populations. Multi-element geochemical anomalies occur within the vicinity of industries, waste dump sites, metal workshops and mechanical workshops. R-mode factor analysis reveals three element associations and two singular elements (As, Cd) accounting for 94% of the total data variance. The three associations are: Ag-Cu-Cr-Fe-Mn-Mo-Ni-Sb; Co-Cu-Pb-Sb-Zn and Sc-V. The geoaccumulation indices show that soils in the Bassa Industrial Zone are moderately to very highly pollute. These metal-laden soils constitute a major health risk to the local population and a cause for concern. This study successfully relates the concentration and distribution of toxic metals in the soils of Bassa Industrial Zone to urban effluents generated mainly from industrial activities. (author)

  17. Effects of sulfate on heavy metal release from iron corrosion scales in drinking water distribution system.

    Science.gov (United States)

    Sun, Huifang; Shi, Baoyou; Yang, Fan; Wang, Dongsheng

    2017-05-01

    Trace heavy metals accumulated in iron corrosion scales within a drinking water distribution system (DWDS) could potentially be released to bulk water and consequently deteriorate the tap water quality. The objective of this study was to identify and evaluate the release of trace heavy metals in DWDS under changing source water conditions. Experimental pipe loops with different iron corrosion scales were set up to simulate the actual DWDS. The effects of sulfate levels on heavy metal release were systemically investigated. Heavy metal releases of Mn, Ni, Cu, Pb, Cr and As could be rapidly triggered by sulfate addition but the releases slowly decreased over time. Heavy metal release was more severe in pipes transporting groundwater (GW) than in pipes transporting surface water (SW). There were strong positive correlations (R 2  > 0.8) between the releases of Fe and Mn, Fe and Ni, Fe and Cu, and Fe and Pb. When switching to higher sulfate water, iron corrosion scales in all pipe loops tended to be more stable (especially in pipes transporting GW), with a larger proportion of stable constituents (mainly Fe 3 O 4 ) and fewer unstable compounds (β-FeOOH, γ-FeOOH, FeCO 3 and amorphous iron oxides). The main functional iron reducing bacteria (IRB) communities were favorable for the formation of Fe 3 O 4 . The transformation of corrosion scales and the growth of sulfate reducing bacteria (SRB) accounted for the gradually reduced heavy metal release with time. The higher metal release in pipes transporting GW could be due to increased Fe 6 (OH) 12 CO 3 content under higher sulfate concentrations. Copyright © 2017 Elsevier Ltd. All rights reserved.

  18. Distribution of the solvent-extractable organic compounds in fine (PM1) and coarse (PM1-10) particles in urban, industrial and forest atmospheres of Northern Algeria.

    Science.gov (United States)

    Ladji, Riad; Yassaa, Noureddine; Balducci, Catia; Cecinato, Angelo; Meklati, Brahim Youcef

    2009-12-20

    The distribution of the solvent-extractable organic components in the fine (PM(1)) and coarse (PM(1-10)) fractions of airborne particulate was studied for the first time in Algeria. That was done during October 2006 concurrently in a big industrial district, a busy urban area, and a forest national park located in Algiers, Boumerdes, Blida, respectively, which are the three biggest provinces of Northern Algeria. Most of the organic matter identified in both particle size ranges consisted of n-alkanes and n-alkanoic acids, with minor contributions coming from polycyclic aromatic hydrocarbons (PAHs), nitrated polycyclic aromatic hydrocarbons (NPAHs), oxygenated PAHs, and other polar compounds (e.g., caffeine and nicotine). The potential emission sources of airborne contaminants were reconciled by combining the values of n-alkane carbon preference index (CPI) and selected diagnostic ratios of PAHs, calculated in both size ranges. The mean cumulative concentrations of PAHs reached 3.032 ng m(-3) at the Boumerdes site, urban, 80% of which (i.e. 2.246 ng m(-3)) in the PM(1) fraction, 6.462 ng m(-3) at Rouiba-Réghaia, industrial district, (5.135 ng m(-3) or 80% in PM(1)), and 0.512 ng m(-3) at Chréa, forested mountains (0.370 ng m(-3) or 72% in PM(1)). Similar patterns were shown by all organic groups, which resulted overall enriched in the fine particles at the three sites. Carcinogenic and mutagenic potencies associated to PAHs were evaluated by multiplying the concentrations of "toxic" compounds times the corresponding potency factors normalized vs. benzo(a)pyrene (BaP), and were found to be both acceptable.

  19. [Heavy metals distribution characteristics and ecological risk evaluation in surface sediments of dammed Jinshan lake].

    Science.gov (United States)

    Zhou, Xiao-Hong; Liu, Long-Mei; Chen, Xi; Chen, Zhi-Gang; Zhang, Jin-Ping; Li, Yi-Min; Liu, Biao

    2014-11-01

    In order to reveal the pollution loading of heavy metals in Dammed Jinshan lake, six heavy metals (As, Cu, Pb, Cd, Zn, Cr) from 18 sediment samples were analyzed using ICP, and the distribution characteristics of heavy metals in the sediment were comprehensively evaluated through concentration coefficient, geo-acumulation indexes, potential ecological risk evaluation and traceability analysis. The results showed that (1) the average contents of As, Pb, Cu, Zn, Cr, Cd were 23.22, 26.20, 24.42, 143.12, 245.30 and 0.67 mg x kg(-1), respectively, in the surface sediments of dammed Jinshan Lake. The average contents of Pb and Cu were lower than the primary standard and secondary standards of soil environmental quality standards. The average contents of Zn and Cr were lower than the primary standard and higher than the secondary standards of soil environmental quality standards. The average contents of As and Cd were higher than the primary and secondary standards of soil environmental quality standards. From the spatial distribution, the contents of Pb and Zn were the highest at sampling site No. 1, which was located at the Beigushan Square. The contents of As,Cu, Cr, Cd were the highest at sampling sites Nos. 12, 3, 14, and 7, respectively; (2) The order of concentration coefficient was As > Cr > Cd > Pb > Zn > Cu, which indicated that the enrichment amount of As was the highest and that of Cu was the lowest; (3) Based on the geo-acumulation indexes, the Cu is clean and Pb, Zn, Cd is the light pollution and As, Cr moderate pollution; (4) The order of Potential ecological risk coefficient was Cd > As > Cr > Pb > Cu > Zn, Cr, Pb, Cu, Zn were of light ecological risk and As, Cd were of medium ecological risk. From the spatial distribution, the sampling sites Nos. 1, 6, 7 and 12 had medium potential ecological risk, and the rest sample points had slight potential ecological risk; (5) The principal component analysis (PCA) revealed that the main reason for the differences

  20. A STUDY OF LEAKAGE OF TRACE METALS FROM CORROSION OF THE MUNICIPAL DRINKING WATER DISTRIBUTION SYSTEM

    Directory of Open Access Journals (Sweden)

    M.R SHA MANSOURI

    2003-09-01

    Full Text Available Introduction: A high portion of lead and copper concentration in municipal drinking water is related to the metallic structure of the distribution system and facets. The corrosive water in pipes and facets cause dissolution of the metals such as Pb, Cu, Cd, Zn, Fe and Mn into the water. Due to the lack of research work in this area, a study of the trace metals were performed in the drinking water distribution system in Zarin Shahr and Mobareke of Isfahan province. Methods: Based on the united states Environmental protection Agency (USEPA for the cities over than 50,000 population such as Zarin Shahr and Mobareke, 30 water samples from home facets with the minimum 6 hours retention time of water in pipes, were collected. Lead and cadmium concentration were determined using flameless Atomic Absorption. Cupper, Zinc, Iron and Manganese were determined using Atomic Absorption. Results: The average concentration of Pb, Cd, Zn, Fe and Mn in water distribution system fo Zarin Shahr were 5.7, 0.1, 80, 3042, 23065 and in Mobareke were 7.83, 0.8,210,3100, 253, 17µg respectively. The cocentration of Pb, Cd and Zn were zero at the beginning of the water samples from the municipal drinking water distribution system for both cities. Conclusion: The study showed that the corrosion by products (such as Pb, Cd and Zn was the results of dissolution of the galvanized pipes and brass facets. Lead concentration in over that 10 percent of the water samples in zarin shahr exceeded the drinking water standard level, which emphasize the evaluation and control of corrosion in drinking water distribution systems.

  1. Spatial distribution and pollution assessment of heavy metals in urban soils from southwest China

    Institute of Scientific and Technical Information of China (English)

    Guanghui Guo; FengchangWu; Fazhi Xie; Ruiqing Zhang

    2012-01-01

    To identify the concentrations and sources of heavy metals,and to assess soil environmental quality,63 soil samples were collected in Yibin City,Sichuan Province,China.Mean concentrations of As,Pb,Zn,and Cu were 10.55,61.23,138.88 and 56.35 mg/kg,respectively.As concentrations were comparable to background values,while Pb,Zn,and Cu concentrations were higher than their corresponding background values.Industrial areas exhibited the highest concentrations of As,Pb,Zn,and Cu,while the lowest concentrations occurred in parks.Statistical analysis was performed and two cluster groups of metals were identified with Pb,Zn,and Cu in one group and As in the other.Spatial distribution maps indicated that Pb,Zn,and Cu were mainly controlled by anthropogenic activities,whereas As could be mainly accounted for by soil parent materials.Pollution index values of As,Pb,Zn,and Cu varied in the range of 0.24-1.93,0.66-7.24,0.42-4.19,and 0.62-5.25,with mean values of 0.86,1.98,1.61,and 1.78,respectively.The integrated pollution index(IPI)values of these metals varied from 0.82 to 3.54,with a mean of 1.6 and more than 90% of soil samples were moderately or highly contaminated with heavy metals.The spatial distribution of IPI showed that newer urban areas displayed relatively lower heavy metal contamination in comparison with older urban areas.

  2. High-resolution insight into the competitive adsorption of heavy metals on natural sediment by site energy distribution.

    Science.gov (United States)

    Huang, Limin; Jin, Qiang; Tandon, Puja; Li, Aimin; Shan, Aidang; Du, Jiajie

    2018-04-01

    Investigating competitive adsorption on river/lake sediments is valuable for understanding the fate and transport of heavy metals. Most studies have studied the adsorption isotherms of competitive heavy metals, which mainly comparing the adsorption information on the same concentration. However, intrinsically, the concentration of each heavy metal on competitive adsorption sites is different, while the adsorption energy is identical. Thus, this paper introduced the site energy distribution theory to increase insight into the competitive adsorption of heavy metals (Cu, Cd and Zn). The site energy distributions of each metal with and without other coexisting heavy metals were obtained. It illustrated that site energy distributions provide much more information than adsorption isotherms through screening of the full energy range. The results showed the superior heavy metal in each site energy area and the influence of competitive metals on the site energy distribution of target heavy metal. Site energy distributions can further help in determining the competitive sites and ratios of coexisting metals. In particular, in the high-energy area, which has great environmental significance, the ratios of heavy metals in the competitive adsorption sites obtained for various competitive systems were as follows: slightly more than 3:1 (Cu-Cd), slightly less than 3:1 (Cu-Zn), slightly more than 1:1 (Cd-Zn), and nearly 7:2:2 (Cu-Cd-Zn). The results from this study are helpful to deeply understand competitive adsorption of heavy metals (Cu, Cd, Zn) on sediment. Therefore, this study was effective in presenting a general pattern for future reference in competitive adsorption studies on sediments. Copyright © 2018 Elsevier Ltd. All rights reserved.

  3. Spatial distribution and potential sources of trace metals in insoluble particles of snow from Urumqi, China.

    Science.gov (United States)

    Li, Xiaolan; Jiang, Fengqing; Wang, Shaoping; Turdi, Muyesser; Zhang, Zhaoyong

    2015-01-01

    The purpose of this work is to characterize trace elements in snow in urban-suburb gradient over Urumqi city, China. The spatial distribution patterns of 11 trace metals in insoluble particulate matters of snow were revealed by using 102 snow samples collected in and around urban areas of Urumqi, a city suffering from severe wintertime air pollution in China. Similar spatial distribution for Mn, Cu, Zn, Ni, and Pb was found and their two significant high-value areas located in the west and east, respectively, and a high-value area in the south, which were correlated with factory emissions, traffic activities, and construction fugitive dust. The high-value areas of Cr, Ni, and V occurred in the northeast corner and along main traffic paths, which were linked to oil refinery and vehicular emissions. High value of Be presented in the west of the city. The high-value area of Co in the northeast could be related to local soil. Cd and U displayed relatively even spatial patterns in the urban area. In view of distance from the urban center, e.g., from the first circular belt to the fourth circular belt, except Be, V, Cd, and U, the contents of other metals generally decreased from the first circular belt to the forth circular belt, implying the effect of human activity clearly. Additionally, prevailing northwesterly winds and occasionally southeasterly winds in winter were associated with decreased, generally, concentrations of trace metal in snow from the urban center to the southern suburb along a northwest and southeast transect. The information on concentrations and spatial distributions of these metals in insoluble particles of snow in winter will be valuable for further environmental protection and planning.

  4. Partial Discharge Monitoring on Metal-Enclosed Switchgear with Distributed Non-Contact Sensors

    Directory of Open Access Journals (Sweden)

    Chongxing Zhang

    2018-02-01

    Full Text Available Metal-enclosed switchgear, which are widely used in the distribution of electrical energy, play an important role in power distribution networks. Their safe operation is directly related to the reliability of power system as well as the power quality on the consumer side. Partial discharge detection is an effective way to identify potential faults and can be utilized for insulation diagnosis of metal-enclosed switchgear. The transient earth voltage method, an effective non-intrusive method, has substantial engineering application value for estimating the insulation condition of switchgear. However, the practical application effectiveness of TEV detection is not satisfactory because of the lack of a TEV detection application method, i.e., a method with sufficient technical cognition and analysis. This paper proposes an innovative online PD detection system and a corresponding application strategy based on an intelligent feedback distributed TEV wireless sensor network, consisting of sensing, communication, and diagnosis layers. In the proposed system, the TEV signal or status data are wirelessly transmitted to the terminal following low-energy signal preprocessing and acquisition by TEV sensors. Then, a central server analyzes the correlation of the uploaded data and gives a fault warning level according to the quantity, trend, parallel analysis, and phase resolved partial discharge pattern recognition. In this way, a TEV detection system and strategy with distributed acquisition, unitized fault warning, and centralized diagnosis is realized. The proposed system has positive significance for reducing the fault rate of medium voltage switchgear and improving its operation and maintenance level.

  5. Partial Discharge Monitoring on Metal-Enclosed Switchgear with Distributed Non-Contact Sensors.

    Science.gov (United States)

    Zhang, Chongxing; Dong, Ming; Ren, Ming; Huang, Wenguang; Zhou, Jierui; Gao, Xuze; Albarracín, Ricardo

    2018-02-11

    Metal-enclosed switchgear, which are widely used in the distribution of electrical energy, play an important role in power distribution networks. Their safe operation is directly related to the reliability of power system as well as the power quality on the consumer side. Partial discharge detection is an effective way to identify potential faults and can be utilized for insulation diagnosis of metal-enclosed switchgear. The transient earth voltage method, an effective non-intrusive method, has substantial engineering application value for estimating the insulation condition of switchgear. However, the practical application effectiveness of TEV detection is not satisfactory because of the lack of a TEV detection application method, i.e., a method with sufficient technical cognition and analysis. This paper proposes an innovative online PD detection system and a corresponding application strategy based on an intelligent feedback distributed TEV wireless sensor network, consisting of sensing, communication, and diagnosis layers. In the proposed system, the TEV signal or status data are wirelessly transmitted to the terminal following low-energy signal preprocessing and acquisition by TEV sensors. Then, a central server analyzes the correlation of the uploaded data and gives a fault warning level according to the quantity, trend, parallel analysis, and phase resolved partial discharge pattern recognition. In this way, a TEV detection system and strategy with distributed acquisition, unitized fault warning, and centralized diagnosis is realized. The proposed system has positive significance for reducing the fault rate of medium voltage switchgear and improving its operation and maintenance level.

  6. [Distribution of Urban Soil Heavy Metal and Pollution Evaluation in Different Functional Zones of Yinchuan City].

    Science.gov (United States)

    Wang, You-qi; Bai, Yi-ru; Wang, Jian-yu

    2016-02-15

    Surface soil samples (0-20 cm) from eight different functional areas in Yinchuan city were collected. There were 10 samples respectively in each functional area. The urban soil heavy metals (Zn, Cd, Pb, Mn, Cu and Cr) pollution characteristics and sources in eight different functional areas were evaluated by mathematical statistics and geostatistical analysis method. Meanwhile, the spatial distributions of heavy metals based on the geography information system (GIS) were plotted. The average values of total Zn, Cd, Pb, Mn, Cu and Cr were 74.87, 0.15, 29.02, 553.55, 40.37 and 80.79 mg x kg(-1), respectively. The results showed that the average value of soil heavy metals was higher than the soil background value of Ningxia, which indicated accumulation of the heavy metals in urban soil. The single factor pollution index of soil heavy metals was in the sequence of Cu > Pb > Zn > Cr > Cd > Mn. The average values of total Zn, Cd, Pb and Cr were higher in north east, south west and central city, while the average values of Mn and Cu were higher in north east and central city. There was moderate pollution in road and industrial area of Yinchuan, while the other functional areas showed slight pollution according to Nemoro synthesis index. The pollution degree of different functional areas was as follows: road > industrial area > business district > medical treatment area > residential area > public park > development zone > science and education area. The results indicated that the soil heavy metal pollution condition in Yinchuan City has been affected by human activities with the development of economy.

  7. [Effects of Fulvic Acid on Absorption and Form Distribution of Heavy Metals on Sediments].

    Science.gov (United States)

    Li, Yu-qing; He, Jiang; Lü, Chang-wei; Fan, Ming-de; Wang, Wei; Zhang, Rui-qing; Xie, Zhi- lei; Wang, Jing-hua; Yu, Bo; En, He; Ding, Tao

    2016-03-15

    Based on the extracted fulvic acid (FA) from Lake Wuliangsuhai sediments by sequential alkali extraction, this work studied the effects of FA on the adsorption and fraction distribution of heavy metals (HM) on sediments using original sediments and sediments treated with 30% H₂O₂ as adsorbents. The results showed both organic matter and FA had effects on the HM adsorption onto sediments; The treatments of FA-free conditions and the sediments treated by H₂O₂ showed relatively strong influence on Cu²⁺ adsorption, which decreased the Cu²⁺ adsorption by 17.85%. With the increasing FA addition, the adsorption percentage of HM on both types of sediments showed gradually decreasing trends, with the order of Cu²⁺ > Cd²⁺ > Zn²⁺ > Pb²⁺; when the FA content was more than 5% , FA became the governing factor on the decreasing adsorption percentage of HM. With increasing FA addition, forms distribution of HM showed significant changes in both types of sediments; i. e. FA additions showed significant negative and positive correlations with percentages of metals bound to carbonates and organic matter, respectively, since the FA addition increased the H⁺ concentration of the system, in which H⁺ could activate the metals bound to carbonate from the sediments. As an organophilic weak element, the fraction percentage of Cd bound to organic matter was the lowest with the minimal changes.

  8. Distribution of Heavy Metal Content Hg and Cr of Environmental Samples at Surabaya Area

    International Nuclear Information System (INIS)

    Agus Taftazani

    2007-01-01

    Determination of Hg and Cr content of Surabaya river and coastal environmental samples using Instrumental Neutron Activation Analysis (INAA) have been done. The environmental samples were water, sediment, Eichhornia crassipes (Mart) Solmms, Rhizophora stylosa, Johnius (Johnieops) borneensis fish, and Moolgarda delicate fish at 12 locations selected of Surabaya area. Dry powder of sediment and biotic samples and concentrate water samples was irradiated by neutron flux 1.05 x 10 11 n.cm -2 .det -1 during 12 hours. The analytical result showed that the concentration of the heavy metals of river water are smaller than Perda Surabaya City No. 02/2004 for the 4 th level water which are Hg (0.005 ppm) and Cr (1.000 ppm). All locations coastal water samples have Hg and Cr concentrations are higher than Kepmen LH No.51/2004 Hg (0.001 ppm) and Cr (0.005 ppm). The Hg concentration of fish samples have exceeded the threshold according to Kep. Dirjen POM No.03725/B/SK/VII/89 about the maximum concentration of metal pollution in food. The concentration of heavy metals in sediment, Eichhornia crassipes (Mart) Solmms and Rhizophora stylosa are not regulated, so then heavy metals pollution can not be referred to. The concentration of Hg and Cr elements of water samples are smaller than that of biotic and sediment samples. The distribution factor (F d ) is bigger than bioaccumulation factor (F b ). (author)

  9. Spatial distribution of metals in soil samples from Zona da Mata, Pernambuco, Brazil using XRF technique

    International Nuclear Information System (INIS)

    Fernandez, Zahily Herrero; Santos Junior, Jose Araujo dos; Amaral, Romilton dos Santos; Menezes, Romulo Simoes Cezar; Santos, Josineide Marques do Nascimento; Bezerra, Jairo Dias; Damascena, Kennedy Francys Rodrigues; Silva, Edvane Borges da; Silva, Alberto Antonio da

    2015-01-01

    Soil contamination is today one of the most important environmental issues for society. In the past, soil pollution was not considered as important as air and water contamination, because this was more difficult to be controlled, becoming an important topic in studies of environmental protection worldwide. Based on this, this paper provides information on the determination of metals in soil samples collected in Zona da Mata, Pernambuco, Brazil, where normally the application of pesticides, insecticides and other agricultural additives are used in a disorderly manner and without control. A total of 24 sampling points were monitored. The analysis of Mn, Fe, Ni, Zn, Br, Rb, Sr, Pb, Ti, La, Al, Si and P were performed using Energy Dispersive X-Ray Fluorescence. In order to assess the development of analytical method, inorganic Certified Reference Materials (IAEA-SOIL-7 and SRM 2709) were analyzed. In each sampling site, the geoaccumulation index were calculated to estimate the level of metal contamination in the soil, this was made taking into account the resolution 460 of the National Environmental Council (CONAMA in Portuguese). The elemental distribution patterns obtained for each metal were associated with different pollution sources. This assessment provides an initial description of pollution levels presented by metals in soils from several areas of Zona da Mata, providing quantitative evidence and demonstrating the need to improve the regulation of agricultural and industrial activities. (author)

  10. Metal distributions in complexes with Chlorella vulgaris in seawater and wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Pascucci, P.R.; Kowalak, A.D.

    1999-10-01

    Divalent cadmium (Cd), copper (Cu), iron (Fe), nickel (Ni), lead (Pb), and zinc (Zn) simultaneous complexes with an algal biomass Chlorella vulgaris were studied for bioremediation purposes in various aqueous media: distilled-deionized water (DDIW), seawater, nuclear-reactor pool water, and process wastewater. Reactions were monitored using various dry masses of algae at constant temperature and constant metal concentrations for reaction times ranging from 0 to 150 minutes. Complexes occurred within 30 minutes and reached a steady state after 80 to 120 minutes. Distribution constants (K{prime}{sub d}) were calculated for the complexes and relative orders of K{prime}{sub d} were reported. The K{prime}{sub d} are used to evaluate relative efficiency of metal remediation from waters. Lead, Cu, and Ni complexes had the greatest K{prime}{sub d} values and those metals were most efficiently removed from these waters. Zinc and Fe formed the most labile complexes. The order of K{prime}{sub d} values for complexes in DDIW was Pb > Cu > Cd > Zn, then Cu > Cd > Zn in seawater, Cd > Cu > Zn in reactor pool water, and Ni > Cd > Cu > Zn > Fe in wastewater. C. vulgaris biomass may potentially be used as an alternative to traditional water treatment methods for simultaneous extraction of metals from seawater, process wastewater, or drinking water.

  11. Speciation and Distribution of Trace Metals and Organic Matter in Marine Lake as In Situ Laboratory

    Science.gov (United States)

    Mlakar, M.; Fiket, Ž.; Cuculić, V.; Cukrov, N.; Geček, S.

    2016-02-01

    Marine lakes are unique, isolated marine systems, also recognized as in situ "laboratories" in which geochemical processes on a different scale compared to the open sea, can be observed. Impact of organic matter cycling on distribution of trace metals in the marine lake Mir, located on Dugi Otok Island, in the central part of the eastern Adriatic Sea, was investigated. Intense spatial and seasonal variations of physico-chemical parameters and organic matter concentrations in the water column of the Lake are governed predominantly by natural processes. Enhanced oxygen consumption in the Lake during summer season, high organic carbon concentrations and low redox potential result in occasional occurrence of anoxic conditions in the bottom layers. Speciation modelling showed that dissolved trace metals Cu, Pb and Zn, are mostly bound to organic matter, while Cd, Co and Ni are present predominantly as free ions and inorganic complexes. Trace metals removal from the water column and their retention in the sediment was found to depend on the nature of the relationship between specific metal and high proportion of organic matter (up to 9%) and inorganic phases, Fe-oxyhydroxydes or biogenic calcite. Surrounding karstic background, with occasional occurrences of red soil characterize deposited sediments as coarse grained and carbonate rich, whose elemental composition is affected by bathymetry of the basin and overall biological production.

  12. Spatial distribution of metals in soil samples from Zona da Mata, Pernambuco, Brazil using XRF technique

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez, Zahily Herrero; Santos Junior, Jose Araujo dos; Amaral, Romilton dos Santos; Menezes, Romulo Simoes Cezar; Santos, Josineide Marques do Nascimento; Bezerra, Jairo Dias; Damascena, Kennedy Francys Rodrigues, E-mail: zahily1985@gmail.com, E-mail: jaraujo@ufpe.br, E-mail: romilton@ufpe.br, E-mail: rmenezes@ufpe.br, E-mail: neideden@hotmail.com, E-mail: jairo.dias@ufpe.br, E-mail: kennedy.eng.ambiental@gmail.com [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Centro de Tecnologia e Geociencias. Departamento de Energia Nuclear; Alvarez, Juan Reinaldo Estevez, E-mail: jestevez@ceaden.cu [Centro de Aplicaciones Tecnologicas y Desarrollo Nuclear (CEADEN), Havana (Cuba); Silva, Edvane Borges da, E-mail: edvane.borges@pq.cnpq.br [Universidade Federal de Pernambuco (UFPE), Vitoria de Santo Antao, PE (Brazil). Nucleo de Biologia; Franca, Elvis Joacir de; Farias, Emerson Emiliano Gualberto de, E-mail: ejfranca@cnen.gov.br, E-mail: emersonemiliano@yahoo.com.br [Centro Regional de Ciencias Nucleares do Nordeste (CRCN-NE/CNEN-PE), Recife, PE (Brazil); Silva, Alberto Antonio da, E-mail: alberto.silva@barreiros.ifpe.edu.br [Instituto Federal de Educacao, Ciencia e Tecnologia de Pernambuco (IFPE), Barreiros, PE (Brazil)

    2015-07-01

    Soil contamination is today one of the most important environmental issues for society. In the past, soil pollution was not considered as important as air and water contamination, because this was more difficult to be controlled, becoming an important topic in studies of environmental protection worldwide. Based on this, this paper provides information on the determination of metals in soil samples collected in Zona da Mata, Pernambuco, Brazil, where normally the application of pesticides, insecticides and other agricultural additives are used in a disorderly manner and without control. A total of 24 sampling points were monitored. The analysis of Mn, Fe, Ni, Zn, Br, Rb, Sr, Pb, Ti, La, Al, Si and P were performed using Energy Dispersive X-Ray Fluorescence. In order to assess the development of analytical method, inorganic Certified Reference Materials (IAEA-SOIL-7 and SRM 2709) were analyzed. In each sampling site, the geoaccumulation index were calculated to estimate the level of metal contamination in the soil, this was made taking into account the resolution 460 of the National Environmental Council (CONAMA in Portuguese). The elemental distribution patterns obtained for each metal were associated with different pollution sources. This assessment provides an initial description of pollution levels presented by metals in soils from several areas of Zona da Mata, providing quantitative evidence and demonstrating the need to improve the regulation of agricultural and industrial activities. (author)

  13. The distribution of star formation and metals in the low surface brightness galaxy UGC 628

    Science.gov (United States)

    Young, J. E.; Kuzio de Naray, Rachel; Wang, Sharon X.

    2015-09-01

    We introduce the MUSCEL Programme (MUltiwavelength observations of the Structure, Chemistry and Evolution of LSB galaxies), a project aimed at determining the star-formation histories of low surface brightness galaxies. MUSCEL utilizes ground-based optical spectra and space-based UV and IR photometry to fully constrain the star-formation histories of our targets with the aim of shedding light on the processes that led low surface brightness galaxies down a different evolutionary path from that followed by high surface brightness galaxies, such as our Milky Way. Here we present the spatially resolved optical spectra of UGC 628, observed with the VIRUS-P IFU at the 2.7-m Harlen J. Smith Telescope at the McDonald Observatory, and utilize emission-line diagnostics to determine the rate and distribution of star formation as well as the gas-phase metallicity and metallicity gradient. We find highly clustered star formation throughout UGC 628, excluding the core regions, and a log(O/H) metallicity around -4.2, with more metal-rich regions near the edges of the galactic disc. Based on the emission-line diagnostics alone, the current mode of star formation, slow and concentrated in the outer disc, appears to have dominated for quite some time, although there are clear signs of a much older stellar population formed in a more standard inside-out fashion.

  14. FY 1999 report on the results of the technology development of super metal (R and D of the undersea oil production support system). Development of technology of aluminum-base high corrosion resistant fine structure controlling metal materials; 1999 nendo super metal no gijutsu kaihatsu seika hokokusho. Kaitei sekiyu seisan shien system kenkyu kaihatsu (aluminium kei kotaishokusei bisai kozo seigyo kinzoku zairyo gijutsu kaihtsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    For the purpose of developing aluminum materials excellent in industrial characteristics, a study was conducted to create large-sized aluminum materials having mesoscopic crystal structure, and the FY 1999 results were summarized. In this fiscal year, to create the fine crystal grain structure, the following were conducted: fundamental study of high strain accumulation process, study of a mechanism of fine crystal grain formation, development of the processing method, and development of evaluation technology. In the study of high strain accumulation process, effects were examined of conditions of molten metal rolling on castability. Fundamental studies were also made of innovative technologies such as ECAP method, pre-forged structure controlling rolling, accumulative roll bonding and thermomechanical treatment. In the study of the mechanism of fine crystal grain structure formation, the following were conducted: Al-Mn base alloys produced by molten metal rolling, 6061 alloys by warm rolling with different peripheral speed rolling, and 7000 group alloys by warm rolling. As to the processing method, study was made on low-temperature rolling technology and rapid heat treatment technology. As to the evaluation technology, study was made on evaluation of crystal grain diameter by EBSP. (NEDO)

  15. Evidence for the distortion product frequency place as a source of distribution product otoacoustic emission (DPOAE) fine structure in humans : I. Fine structure and higher-order DPOAE as a function of the frequency ratio f2/f1

    NARCIS (Netherlands)

    Mauermann, M; Uppenkamp, S; van Hengel, P.W.J.; Kollmeier, B

    1999-01-01

    Critical experiments were performed in order to validate the two-source hypothesis of distortion product otoacoustic emissions (DPOAE) generation. Measurements of the spectral fine structure of DPOAE in response to stimulation with two sinusoids have been:performed with normal-hearing subjects. The

  16. Size distribution and concentrations of heavy metals in atmospheric aerosols originating from industrial emissions as predicted by the HYSPLIT model

    Science.gov (United States)

    Chen, Bing; Stein, Ariel F.; Maldonado, Pabla Guerrero; Sanchez de la Campa, Ana M.; Gonzalez-Castanedo, Yolanda; Castell, Nuria; de la Rosa, Jesus D.

    2013-06-01

    This study presents a description of the emission, transport, dispersion, and deposition of heavy metals contained in atmospheric aerosols emitted from a large industrial complex in southern Spain using the HYSPLIT model coupled with high- (MM5) and low-resolution (GDAS) meteorological simulations. The dispersion model was configured to simulate eight size fractions (17 μm) of metals based on direct measurements taken at the industrial emission stacks. Twelve stacks in four plants were studied and the stacks showed considerable differences for both emission fluxes and size ranges of metals. We model the dispersion of six major metals; Cr, Co, Ni, La, Zn, and Mo, which represent 77% of the total mass of the 43 measured elements. The prediction shows that the modeled industrial emissions produce an enrichment of heavy metals by a factor of 2-5 for local receptor sites when compared to urban and rural background areas in Spain. The HYSPLIT predictions based on the meteorological fields from MM5 show reasonable consistence with the temporal evolution of concentrations of Cr, Co, and Ni observed at three sites downwind of the industrial area. The magnitude of concentrations of metals at two receptors was underestimated for both MM5 (by a factor of 2-3) and GDAS (by a factor of 4-5) meteorological runs. The model prediction shows that heavy metal pollution from industrial emissions in this area is dominated by the ultra-fine (<0.66 μm) and fine (<2.5 μm) size fractions.

  17. Spherical electron momentum density distribution and Bayesian analysis of the renormalization parameter in Li metal

    International Nuclear Information System (INIS)

    Dobrzynski, Ludwik

    2000-01-01

    The Bayesian analysis of the spherical part of the electron momentum density was carried out with the goal of finding the best estimation of the spherically averaged renormalization parameter, z , quantifying the discontinuity in the electron momentum density distribution in Li metal. Three models parametrizing the electron momentum density were considered and nuisance parameters integrated out. The analysis show that the most likely value of z following from the data of Sakurai et al is in the range of 0.45-0.50, while 0.55 is obtained for the data of Schuelke et al . In the maximum entropy reconstruction of the spherical part of the electron momentum density three different algorithms were used. It is shown that all of them produce essentially the same results. The paper shows that the accurate Compton scattering experiments are capable of bringing information on this very important Fermiological aspect of the electron gas in a metal. (author)

  18. Impact of Saw Dust Application on the Distribution of Potentially Toxic Metals in Contaminated Soil.

    Science.gov (United States)

    Awokunmi, Emmmanuel E

    2017-12-01

    The need to develop an approach for the reclamation of contaminated site using locally available agricultural waste has been considered. The present study investigated the application of sawdust as an effective amendment in the immobilization of potentially toxic metals (PTMs) by conducting a greenhouse experiment on soil collected from an automobile dumpsite. The amended and non-amended soil samples were analyzed for their physicochemical parameters and sequential extraction of PTMs. The results revealed that application of amendment had positive impact on the physicochemical parameters as organic matter content and cation exchange capacity increased from 12.1% to 12.8% and 16.4 to 16.8 meq/100 g respectively. However, the mobility and bioavalability of these metals was reduced as they were found to be distributed mostly in the non-exchangeable phase of soil. Therefore, application of sawdust successfully immobilized PTMs and could be applied for future studies in agricultural soil reclamation.

  19. Distribution of heavy metals (Cu and Fe in sea water of Gresik coastal area

    Directory of Open Access Journals (Sweden)

    Nindyapuspa Ayu

    2018-01-01

    Full Text Available The improvement of industrial activities at Gresik Regency will increase the heavy metals concentration on the seawater at Gresik Regency. Therefore, the research of Fe and Cr distribution on the seawater at Gresik Regency has been conducted. Methods that were used is sampling by Nansen water sampler at three sampling points (housing in northern coastal Gresik Regency, Maspion V Industrial Estate, and Petrokimia Port. Samples were analyzed by Atomic Absorption Spectrophotometry (AAS to determine the concentration of heavy metals. The results showed that the highest Fe and Cr concentration are located at Maspion V Industrial Estate (0.452 mg/L and 0.081 mg/L respectively. Meanwhile, Fe and Cr concentrations at the housing in northern coastal are (0.408 mg/L and 0.081 mg/L respectively. The concentration of Fe and Cr at Petrokimia Port are 0.174 mg/L and 0.021 mg/L respectively.

  20. Pore size distribution, strength, and microstructure of portland cement paste containing metal hydroxide waste

    Energy Technology Data Exchange (ETDEWEB)

    Majid, Z.A.; Mahmud, H.; Shaaban, M.G.

    1996-12-31

    Stabilization/solidification of hazardous wastes is used to convert hazardous metal hydroxide waste sludge into a solid mass with better handling properties. This study investigated the pore size development of ordinary portland cement pastes containing metal hydroxide waste sludge and rice husk ash using mercury intrusion porosimetry. The effects of acre and the addition of rice husk ash on pore size development and strength were studied. It was found that the pore structures of mixes changed significantly with curing acre. The pore size shifted from 1,204 to 324 {angstrom} for 3-day old cement paste, and from 956 to 263 {angstrom} for a 7-day old sample. A reduction in pore size distribution for different curing ages was also observed in the other mixtures. From this limited study, no conclusion could be made as to any correlation between strength development and porosity. 10 refs., 6 figs., 3 tabs.

  1. Distribution, provenance and early diagenesis of major and trace metals in sediment cores from the Mandovi estuary, western India

    Digital Repository Service at National Institute of Oceanography (India)

    Prajith, A.; Rao, V.P.; Chakraborty, P.

    Major elements and trace metals were analyzed in four sediment cores recovered along a transect in the Mandovi estuary for their distribution, provenance and early diagenesis. The sediments were clayey silts in cores from the upper/lower estuary...

  2. Distribution and seasonal variation of trace metals in surface sediments of the Mandovi estuary, west coast of India

    Digital Repository Service at National Institute of Oceanography (India)

    Alagarsamy, R.

    The concentration and distribution of selected trace metals in surface sediments of the Mandovi estuary were studied to determine the extent of anthropogenic inputs from mining activities and to estimate the effects of monsoon on geochemical...

  3. Heavy metals seasonal variability and distribution in Lake Qaroun sediments, El-Fayoum, Egypt

    Science.gov (United States)

    Redwan, Mostafa; Elhaddad, Engy

    2017-10-01

    This study was carried out to investigate the seasonal variability and distribution of heavy metals ;HMs; (Fe, Mn, Co, Cr, Cu, Ni, Pb, Zn and V) in the bottom sediments of Lake Qaroun, in Egypt. The samples were collected from 10 sites in summer and winter seasons in 2015. Total metals concentrations were measured using inductively coupled plasma spectrometer. Multivariate techniques were applied to analyse the distribution and potential source of heavy metals. The mean seasonal concentrations follow a descending order of Fe > Mn > V > Zn > Cr > Ni > Cu > Co > Pb. The mean concentrations of HMs in sediments during summer were higher than the concentrations during winter and above the average world shale values, except for Pb, suggesting potential adverse toxicity to aquatic organisms. All metals showed enrichment during summer and winter at sites S3 and S5 in the southeastern parts of the lake due to the heavy discharge of contaminants from El-Bats and El-Wadi drains. Principal component analysis results suggested two principal components controlling HMs variability in sediments, which accounted for 63.9% (factor 1: Co, Cr, Cu, Ni, Zn, Pb and V), 15.9% (factor 2: Mn and Fe) during summer, and 76.7% (factor 1: Fe, Co, Cr, Cu, Ni, Zn, Pb and V), 13.8% (factor 2: Mn) during winter of the total variance. Geo-accumulation index (Igeo) showed some pollution risk at the southeastern and southern parts (sites S3 and S5). Dilution during winter, concentration during summer, impact of non-point sources from different agricultural, industrial, municipal sewage and fish farms in the southern part of Lake Qaroun, adsorption and salt dissolution reactions and lithogenic sources are the main controlling factors for HMs in the study area. Monitoring of contaminant discharge at Lake Qaroun should be introduced for future remediation and management strategies.

  4. Distribution, correlation and risk assessment of selected metals in urban soils from Islamabad, Pakistan

    International Nuclear Information System (INIS)

    Iqbal, Javed; Shah, Munir H.

    2011-01-01

    Highlights: → Water-extract and acid-extract of the soils were analysed for selected metals. → The soils were anthropogenically polluted by Cd, Pb, Co, Cr, Cu, Li, Zn and Mn. → Moderate to heavy contamination for Pb and Cd was indicated by I geo and C f . → Most of the metals showed random distribution and diverse correlations. → Overall, considerable degree of contamination was observed in both seasons. - Abstract: Urban soil samples were analyzed for Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Pb, Sr and Zn by atomic absorption spectrophotometric method. Multivariate statistical approach was used to study the apportionment of selected metals in the soil samples during summer and winter. The degree of contamination along with the geoaccumulation index, enrichment factor and contamination factor was also evaluated. In water-extract of the soil samples, relatively higher levels were noted for Na, Ca, K, Fe, Mg, and Pb with average concentrations of 56.38, 33.82, 12.53, 7.127, 5.994, and 1.045 mg/kg during summer, while the mean metal levels during winter were 76.45, 38.05, 3.928, 0.627, 8.726, and 0.878 mg/kg, respectively. In case of acid-extract of the soils, Ca, Fe, Mg, Na, K, Mn and Sr were found at 27,531, 12,784, 2769, 999.9, 737.9, 393.5, and 115.1 mg/kg, during summer and 23,386, 3958, 3206, 254.6, 1511, 453.6, and 53.30 mg/kg, during winter, respectively. Most of the metals showed random distribution with diverse correlations in both seasons. Principal component analysis and cluster analysis revealed significant anthropogenic intrusions of Cd, Pb, Co, Cr, Cu, Li, Zn and Na in the soils. Geoaccumulation indices and contamination factors indicated moderate to heavy contamination for Pb and Cd in the soils, while enrichment factor exhibited significant enrichment (EF > 5) of Cd, Pb, Ca, Co, Li, Mn and Zn by anthropogenic activities. Overall, on the average basis, considerable degree of contamination (C deg > 16) was observed in both seasons, although

  5. The spatial and temporal distribution of heavy metals in sediments of Victoria Harbour, Hong Kong

    Energy Technology Data Exchange (ETDEWEB)

    Tang, Chloe Wing-yee; Ip, Carman Ching-man [Department of Civil and Structural Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon (Hong Kong); Zhang Gan [State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China); Shin, Paul K.S. [Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon (Hong Kong); Qian Peiyuan [Department of Biology and Coastal Marine Laboratory, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong); Li Xiangdong [Department of Civil and Structural Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon (Hong Kong)], E-mail: cexdli@polyu.edu.hk

    2008-07-01

    Victoria Harbour has received substantial loadings of pollutants from industrial and municipal wastewater discharged since the 1950s. Inputs of contaminants have declined dramatically during the last two decades as a result of better controls at the source and improved wastewater treatment facilities. To assess the spatial and temporal changes of metal contaminants in sediments in Victoria Harbour, core and grab sediments were collected. The central harbour areas were generally contaminated with heavy metals. The spatial distribution of trace metals can probably be attributed to the proximity of major urban and industrial discharge points, and to the effect of tidal flushing in the harbour. In the sediment cores, the highest concentrations of trace metals were observed to have accumulated during the 1950s-1980s, corresponding with the period of rapid urban and industrial development in Hong Kong. From the late 1980s, there has been a major decline in the concentrations of trace metals, due to a reduction in industrial activities and to the enactment of wastewater pollution controls in the territory. The Pb isotopic compositions of the sediments revealed the anthropogenic inputs of Pb to the harbour. The {sup 206}Pb/{sup 207}Pb ratios varied from 1.154 to 1.190, which were lower than those of background geological materials in Hong Kong ({sup 206}Pb/{sup 207}Pb: 1.201-1.279). The data also indicated that the Pb in the harbour sediments most likely originated from mixed sources, including the leaded gasoline used in the past and other anthropogenic sources.

  6. Distribution of heavy metals in peri-urban agricultural areas soils

    International Nuclear Information System (INIS)

    Iram, S.; Ahmad, I.; Akhtar, S.

    2012-01-01

    In industry oriented peri-urban areas, the heavy metals accumulation in soils caused by industrialization has become a potential threat. The top soil sample from 48 agricultural fields were collected from a typical industry based peri-urban areas (Lahore, Faisalabad, Multan, Kasur, Islamabad, Wah Cantt.) of Punjab, Pakistan to study the accumulation and distribution of heavy metals (Pb, Cd, Cr, Cu, Ni and Zn) by atomic absorption spectrophotometer. The aim of the study was to investigate influence of an industrialized environment on the accumulation of heavy metals in peri-urban agricultural soils. The results of the study showed that the Pb content in the soil ranged from 17.24 to 126.4 mg/kg and the highest Pb content was observed in Islamabad soil samples, and the lowest in that of Multan area. The Cd content ranged from 1.1 to 4.0 mg/kg in Lahore while the highest Cr concentration level was 210.2 mg/kg and it was observed in Kasur and lowest 30.60 in that of Multan. The Cu content ranged from 31.2 to 127.9 mg/kg (Kasur-Lahore). The highest Ni concentration (82.0 mg/kg) was observed in Lahore from the urban area and the lowest level of 12.15 mg/kg was observed in Multan. The Zn content ranged from 42.5 to 267.7 mg/kg (Faisalabad-Wah Cantt). The study concluded that the concentration level of the heavy metals (Pb, Cd, Cu, Ni, Cr, Zn) in the studied peri-urban areas was higher as compared to heavy metal content of normal Dutch soil. High automobile traffic and industrial waste both are the most likely sources of the contamination of the peri urban areas of Pakistan. (author)

  7. Enhancement of light absorption in polyazomethines due to plasmon excitation on randomly distributed metal nanoparticles

    Science.gov (United States)

    Wróbel, P.; Antosiewicz, T. J.; Stefaniuk, T.; Ciesielski, A.; Iwan, A.; Wronkowska, A. A.; Wronkowski, A.; Szoplik, T.

    2015-05-01

    In photovoltaic devices, metal nanoparticles embedded in a semiconductor layer allow the enhancement of solar-toelectric energy conversion efficiency due to enhanced light absorption via a prolonged optical path, enhanced electric fields near the metallic inclusions, direct injection of hot electrons, or local heating. Here we pursue the first two avenues. In the first, light scattered at an angle beyond the critical angle for reflection is coupled into the semiconductor layer and confined within such planar waveguide up to possible exciton generation. In the second, light is trapped by the excitation of localized surface plasmons on metal nanoparticles leading to enhanced near-field plasmon-exciton coupling at the peak of the plasmon resonance. We report on results of a numerical experiment on light absorption in polymer- (fullerene derivative) blends, using the 3D FDTD method, where exact optical parameters of the materials involved are taken from our recent measurements. In simulations we investigate light absorption in randomly distributed metal nanoparticles dispersed in polyazomethine-(fullerene derivative) blends, which serve as active layers in bulkheterojunction polymer solar cells. In the study Ag and Al nanoparticles of different diameters and fill factors are diffused in two air-stable aromatic polyazomethines with different chemical structures (abbreviated S9POF and S15POF) mixed with phenyl-C61-butyric acid methyl ester (PCBM) or [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM). The mixtures are spin coated on a 100 nm thick Al layer deposited on a fused silica substrate. Optical constants of the active layers are taken from spectroscopic ellipsometry and reflectance measurements using a rotating analyzer type ellipsometer with auto-retarder performed in the wavelength range from 225 nm to 2200 nm. The permittivities of Ag and Al particles of diameters from 20 to 60 nm are assumed to be equal to those measured on 100 to 200 nm thick metal films.

  8. The compaction of a random distribution of metal cylinders by the discrete element method

    DEFF Research Database (Denmark)

    Redanz, Pia; Fleck, N. A.

    2001-01-01

    -linear springs. The initial packing of the particles is generated by the ballistic deposition method. Salient micromechanical features of closed die and isostatic powder compaction are elucidated for both frictionless and sticking contacts. It is found that substantial rearrangement of frictionless particles......The cold compaction of a 2D random distribution of metal circular cylinders has been investigated numerically by the discrete element method. Each cylindrical particle is located by a node at its centre and the plastic indentation of the contacts between neighbouring particles is represented by non...

  9. Distributions of traces of metals on sorption from solutions of vanadium(V)

    International Nuclear Information System (INIS)

    Evseeva, N.K.; Turnaov, A.N.; Telegin, G.F.; Kremenskaya, I.N.

    1983-01-01

    A study is made of the distributions of traces of metals between aqueous solutions of vanadium(V) and a solid reagent made by introducing di-2-ethylhexylphosphoric acid into an inert matrix: a nonionic macroporous copolymer of polystyrene with divinyl benzene (wofatit Y 29). As regards degree of extraction, the trace components fall in the series zinc > cadmium > manganese > copper > cobalt, which resemble the extractability series. The vanadium content of the solution and the concentrations of the trace components have virtually no effect on the sorption. The process is effective in concentrating trace components from solutions containing vanadium(V)

  10. Distribution of microimpurities of metals at their sorption from vanadium (5) solutions

    International Nuclear Information System (INIS)

    Evseeva, N.K.; Turanov, A.N.; Telegin, G.F.; Kremenskaya, I.N.

    1983-01-01

    Distribution of metal microimpurities (Zn, Mn, Cu, Co, Fe) between aqueous solutions of vanadium (5) and solid extracting agent, prepared by means of introduction of di-2-ethylhexylphosphoric acid into inert matrix-nonionogeneous macropore copolymer of polystyrene with divinylbenzene (vofatit Y-29), has been studied. Accroding to the degree of extraction the microimpurities are arranged in the series: zinc > cadmium > manganese > copper > cobalt, which is similar to the series of extractability. Vanadium content in solution and concentration of microimpurities practically does not affect the sorption. It has been established that the process is effective for microimpurities concentration from solutions containing vanadium (5)

  11. Distribution of microimpurities of metals at their sorption from vanadium (5) solutions

    Energy Technology Data Exchange (ETDEWEB)

    Evseeva, N.K.; Turanov, A.N.; Telegin, G.F.; Kremenskaya, I.N.

    1983-01-01

    Distribution of metal microimpurities (Zn, Mn, Cu, Co, Fe) between aqueous solutions of vanadium (5) and solid extracting agent, prepared by means of introduction of di-2-ethylhexylphosphoric acid into inert matrix-nonionogeneous macropore copolymer of polystyrene with divinylbenzene (vofatit Y-29), has been studied. According to the degree of extraction the microimpurities are arranged in the series: zinc > cadmium > manganese > copper > cobalt, which is similar to the series of extractability. Vanadium content in solution and concentration of microimpurities practically does not affect the sorption. It has been established that the process is effective for microimpurities concentration from solutions containing vanadium (5).

  12. Distribution, enrichment and accumulation of heavy metals in coastal sediments of Alang-Sosiya ship scrapping yard, India.

    Science.gov (United States)

    Reddy, M Srinivasa; Basha, Shaik; Sravan Kumar, V G; Joshi, H V; Ramachandraiah, G

    2004-06-01

    Since its inception in 1982, the Alang-Sosiya yard has become the largest ship scrapping works in the world. Several hundreds of ships arrive every year. The degree of heavy metal contamination has been studied in bulk and fine sediments from the intertidal zone of this ship scrapping yard, two stations, one on either side at 5 km distance and one reference station 60 km distance near Mahuva, towards the south. The samples have been subjected to a total digestion technique and analysed for elements: Cd, Co, Cu, Cr, Fe, Mn, Ni, Pb, Zn and Al, and %TOC. The absolute metal concentrations reflected variations in BF and FF sediment samples with organic matter content. Enrichment factors (EF) and geoaccumulation indices (Igeo) have been calculated and the relative contamination levels are assessed at these sites. At Alang-Sosiya, the enrichment of heavy metals has been observed to be relatively high.

  13. Distribution of heavy metals in riverine soils and sediments of the Turia River basin.

    Science.gov (United States)

    Andreu, Vicente; Gimeno-García, Eugenia; Pascual, Juan Antonio

    2014-05-01

    Water is a scarce and contested good, and a primary need for the population all over. Rivers are one of the mainsources of freshwater to people but, in the same way, receive both point source and difuse pollution, usually frorm wastewaters and agriculture. However, they are not independent bodies but they influence different associated ecosystems that compound the catchment. Soils of the river banks often acts as the last phase of the diffuse contamination pathways, favouring the contaminants input to the river waters. In this sense, the fluvial sedimentary phase usually acts as a sink of pollutants. Sediments can work as resevoirs that accumulate contaminants fixing them or allowing their decomposition or metabolization. However, environmental or human induced, such as variations in water pH, increases in the turbulence or intensity of the water flow, etc.could favour their release to the environment. In this work, the incidence and distribution of seven heavy metals was monitored in riverine soils and sediments of the Turia River. Along the river course, 22 zones were selected for sampling according different lithologies, land uses, size of populations and the proximity to waste waters treatment plants (WWTPs), from the headwaters to the mouth. The selected metals (Cd, Co, Cr, Cu, Pb, Ni and Zn) were analysed to determine its total and extractable contents in the sediments. Total content of metals was extracted by microwave acid digestion and the extractable fraction by treatment with EDTA. Atomic Absorption Spectrometry, using graphite furnace when necessary, was used for the determination of all metals. Highest values for sediments were mainly observed in zones 10 and 22, close to urban areas, reaching values of 172.86 mg/kg for Pb, or 58.34 mg/kg for Cr. However, zone 2 near in the headwaters of the Alfambra River and supposedly of reference for the River authorities shows the highest values of zinc with 96.96 mg/kg. Regarding the available

  14. Effect of variable soil texture, metal saturation of soil organic matter (SOM) and tree species composition on spatial distribution of SOM in forest soils in Poland.

    Science.gov (United States)

    Gruba, Piotr; Socha, Jarosław; Błońska, Ewa; Lasota, Jarosław

    2015-07-15

    In this study we investigated the effect of fine (ϕclay (FF) content in soils, site moisture, metal (Al and Fe) of soil organic matter (SOM) and forest species composition on the spatial distribution of carbon (C) pools in forest soils at the landscape scale. We established 275 plots in regular 200×200m grid in a forested area of 14.4km(2). Fieldwork included soil sampling of the organic horizon, mineral topsoil and subsoil down to 40cm deep. We analysed the vertical and horizontal distribution of soil organic carbon (SOC) stocks, as well as the quantity of physically separated fractions including the free light (fLF), occluded light (oLF) and mineral associated fractions (MAF) in the mineral topsoil (A, AE) horizons. Distribution of C in soils was predominantly affected by the variation in the FF content. In soils richer in the FF more SOC was accumulated in mineral horizons and less in the organic horizons. Accumulation of SOC in mineral soil was also positively affected by the degree of saturation of SOM with Al and Fe. The increasing share of beech influenced the distribution of C stock in soil profiles by reducing the depth of O horizon and increasing C stored in mineral soil. The content of FF was positively correlated with the content of C in MAF and fLF fractions. The content of oLF and MAF fractions was also positively influenced by a higher degree of metal saturation, particularly Al. Our results confirmed that Al plays an important role in the stabilization of SOM inside aggregates (CoLF) and as in CMAF fractions. We also found a significant, positive effect of beech on the CfLF and fir on the CoLF content. Copyright © 2015 Elsevier B.V. All rights reserved.

  15. A study of the distribution of rare-metals in kuroko-type ore

    Energy Technology Data Exchange (ETDEWEB)

    Murao, S. [Commonwealth Scientific and Industrial Research Organisation (CSIRO), North Ryde, NSW (Australia). Div. of Exploration Geoscience]|[Geological Survey of Japan, Tsukuba, Ibaraki (Japan); Sie, S.H.; Suter, G.F. [Commonwealth Scientific and Industrial Research Organisation (CSIRO), North Ryde, NSW (Australia). Div. of Exploration Geoscience

    1996-12-31

    We have performed PIXE analysis of kuroko-type ore from the JADE hydrothermal site of the Okinawa Trough, Japan using the proton microprobe (PIXEPROBE). We analysed five kinds of ores dredged from the sea floor: (I) barite ore with small sulfide dissemination; (2) sphalerite-pyrite chimney; (3) pyrite ore; (4) sulfide veinlets in strongly altered rock; and (5) pyrite megacrystals in strongly altered rock. The analyses revealed that the trace element distribution is regulated by the occurrence mode of the ore, and within each ore, by the crystal structure. The distribution suggests that the hydrothermal system for kuroko ore formation is quite heterogeneous and its chemistry is controlled by local factors such as difference in temperature, and that in-situ PIXE analyses are essential for effective beneficiation strategy for the rare-metals from kuroko-type ore. (authors). 10 refs., 1 tab.

  16. A study of the distribution of rare-metals in kuroko-type ore

    Energy Technology Data Exchange (ETDEWEB)

    Murao, S [Commonwealth Scientific and Industrial Research Organisation (CSIRO), North Ryde, NSW (Australia). Div. of Exploration Geoscience; [Geological Survey of Japan, Tsukuba, Ibaraki (Japan); Sie, S H; Suter, G F [Commonwealth Scientific and Industrial Research Organisation (CSIRO), North Ryde, NSW (Australia). Div. of Exploration Geoscience

    1997-12-31

    We have performed PIXE analysis of kuroko-type ore from the JADE hydrothermal site of the Okinawa Trough, Japan using the proton microprobe (PIXEPROBE). We analysed five kinds of ores dredged from the sea floor: (I) barite ore with small sulfide dissemination; (2) sphalerite-pyrite chimney; (3) pyrite ore; (4) sulfide veinlets in strongly altered rock; and (5) pyrite megacrystals in strongly altered rock. The analyses revealed that the trace element distribution is regulated by the occurrence mode of the ore, and within each ore, by the crystal structure. The distribution suggests that the hydrothermal system for kuroko ore formation is quite heterogeneous and its chemistry is controlled by local factors such as difference in temperature, and that in-situ PIXE analyses are essential for effective beneficiation strategy for the rare-metals from kuroko-type ore. (authors). 10 refs., 1 tab.

  17. A study of the distribution of rare-metals in kuroko-type ore

    International Nuclear Information System (INIS)

    Murao, S.; Sie, S.H.; Suter, G.F.

    1996-01-01

    We have performed PIXE analysis of kuroko-type ore from the JADE hydrothermal site of the Okinawa Trough, Japan using the proton microprobe (PIXEPROBE). We analysed five kinds of ores dredged from the sea floor: (I) barite ore with small sulfide dissemination; (2) sphalerite-pyrite chimney; (3) pyrite ore; (4) sulfide veinlets in strongly altered rock; and (5) pyrite megacrystals in strongly altered rock. The analyses revealed that the trace element distribution is regulated by the occurrence mode of the ore, and within each ore, by the crystal structure. The distribution suggests that the hydrothermal system for kuroko ore formation is quite heterogeneous and its chemistry is controlled by local factors such as difference in temperature, and that in-situ PIXE analyses are essential for effective beneficiation strategy for the rare-metals from kuroko-type ore. (authors). 10 refs., 1 tab

  18. Impact of implanted metal plates on radiation dose distribution in vivo

    International Nuclear Information System (INIS)

    Liu Ming; Li Xingde; Niu Qingguo; Zhai Fushan

    2010-01-01

    Objective: To investigate the impact of metal plate on radiation dose distribution in surrounding tissues in cadaver specimens. Methods: Stainless steel plate, titanium plate, and muscle strip were implanted into the left thigh of a corpse, respectively. All the specimens were irradiated with 6 MV X-ray , SSD = 100 cm. The absorbed dose of surface was measured by thermoluminescent elements. Results: Surface dose distributions differed significantly among the three different materials (F = 57.35, P < 0.01), with the amounts of 1.18 Gy ± 0.04 Gy (stainless steel plate), 1.12 Gy ± 0.04 Gy (titanium plate) and 0.97 Gy ± 0.03 Gy (muscle strip), respectively. The surface absorbed doses on incident plane of stainless steel plate and titanium plate were significantly increased by 21.65% and 15.46% respectively as compared with that of muscle strip. The absorbed doses on the exit surface of stainless steel plate, titanium plate and muscle strip were 0.87 Gy ± 0.03 Gy, 0.90 Gy ± 0.02 Gy and 0.95 Gy ± 0.04 Gy, respectively (F =13.37, P <0.01). The doses on the exit surface of stainless steel plate and titanium plate were significantly lowered by 8.42% and 5.26% when compared with that of muscle strip. Using treatment planning system,the differences between dose distribution with and without metal plate were compared. Within 1 cm away from the incident plate, there was an obvious increase in the absorbed dose, while the influence was less than 5% 1 cm outside the surface. The effect of dose distribution on exit surface was less than 2%. Conclusions: The influence of metal plate on the radiotherapy dose distribution is significant. The deviations ranges from 5% to 29%. Under the same condition, the impact of stainless steel plate is much more than that of titanium alloy plate. (authors)

  19. Production of titanium alloys with uniform distribution of heat resisting metals

    International Nuclear Information System (INIS)

    Reznichenko, V.A.; Goncharenko, T.V.; Khalimov, F.B.; Vojtechova, E.A.

    1976-01-01

    Consideration is given to the process of the formation of a titanium sponge alloyed with niobium or tantalum, in the joint metallic reduction of titanium, niobium and tantanum chlorides. A percentage composition of the phases observed and the structure of the alloyed sponge have been studied. It is shown that after one remelting operation of the alloyed sponge the alloys of titanium with niobium and tantalum have a uniform component distribution. At the stage of chloride reduction there appear solid solutions based on titanium and an alloying component. The stage of vacuum separation of the reaction mass is associated with a mutual dissolution of the primary phases and the formation of the solid solutions of the alloyed titanium sponge, which, by their composition, are close to the desired alloy composition. The principal features of the formation of a titanium sponge alloyed with niobium and tantalum are in a perfect agreemet with those typical of Ti-Mo and Ti-W sponges, therefore it can be assumed that these features will be also common to the other cases of the metallic reduction of titanium and refractory metals chlorides

  20. Production of titanium alloys with uniform distribution of heat resisting metals

    Energy Technology Data Exchange (ETDEWEB)

    Reznichenko, V A; Goncharenko, T V; Khalimov, F B; Voitechova, E A

    1976-01-01

    Consideration is given to the process of the formation of a titanium sponge alloyed with niobium or tantalum, in the joint metallic reduction of titanium, niobium and tantanum chlorides. A percentage composition of the phases observed and the structure of the alloyed sponge have been studied. It is shown that after one remelting operation of the alloyed sponge the alloys of titanium with niobium and tantalum have a uniform component distribution. At the stage of chloride reduction there appear solid solutions based on titanium and an alloying component. The stage of vacuum separation of the reaction mass is associated with a mutual dissolution of the primary phases and the formation of the solid solutions of the alloyed titanium sponge, which, by their composition, are close to the desired alloy composition. The principal features of the formation of a titanium sponge alloyed with niobium and tantalum are in a perfect agreemet with those typical of Ti-Mo and Ti-W sponges, therefore it can be assumed that these features will be also common to the other cases of the metallic reduction of titanium and refractory metals chlorides.

  1. Strong links between metal contamination, habitat modification and estuarine larval fish distributions

    Energy Technology Data Exchange (ETDEWEB)

    McKinley, Andrew C., E-mail: andrew.mckinley@hotmail.com [Evolution and Ecology Research Centre, School of Biological, Earth and Environmental Sciences, University of New South Wales, Sydney, New South Wales 2052 (Australia); Miskiewicz, Anthony [Environment and Recreation, Wollongong City Council, 41 Burelli Street, Wollongong, New South Wales 2500 (Australia); Taylor, Matthew D.; Johnston, Emma L. [Evolution and Ecology Research Centre, School of Biological, Earth and Environmental Sciences, University of New South Wales, Sydney, New South Wales 2052 (Australia)

    2011-06-15

    Changes to larval fish assemblages may have far reaching ecological impacts. Correlations between habitat modification, contamination and marine larval fish communities have rarely been assessed in situ. We investigated links between the large-scale distribution of stressors and larval fish assemblages in estuarine environments. Larval fish communities were sampled using a benthic sled within the inner and outer zones of three heavily modified and three relatively unmodified estuaries. Larval abundances were significantly greater in modified estuaries, and there were trends towards greater diversity in these systems. Differences in larval community composition were strongly related to sediment metal levels and reduced seagrass cover. The differences observed were driven by two abundant species, Paedogobius kimurai and Ambassis jacksoniensis, which occurred in large numbers almost exclusively in highly contaminated and pristine locations respectively. These findings suggest that contamination and habitat alteration manifest in substantial differences in the composition of estuarine larval fish assemblages. - Highlights: > We examine contamination/habitat modification impacts on larval fish. > Larvae communities differ between modified/unmodified estuaries. > Larvae are more abundant/diverse in modified areas. > Trends are strongly related to sediment metals/seagrass cover. > Larval impacts have wider ecological importance. - We describe strong links between sediment metals contamination, habitat modification and substantial differences in the composition of the estuarine larval fish assemblage.

  2. Strong links between metal contamination, habitat modification and estuarine larval fish distributions

    International Nuclear Information System (INIS)

    McKinley, Andrew C.; Miskiewicz, Anthony; Taylor, Matthew D.; Johnston, Emma L.

    2011-01-01

    Changes to larval fish assemblages may have far reaching ecological impacts. Correlations between habitat modification, contamination and marine larval fish communities have rarely been assessed in situ. We investigated links between the large-scale distribution of stressors and larval fish assemblages in estuarine environments. Larval fish communities were sampled using a benthic sled within the inner and outer zones of three heavily modified and three relatively unmodified estuaries. Larval abundances were significantly greater in modified estuaries, and there were trends towards greater diversity in these systems. Differences in larval community composition were strongly related to sediment metal levels and reduced seagrass cover. The differences observed were driven by two abundant species, Paedogobius kimurai and Ambassis jacksoniensis, which occurred in large numbers almost exclusively in highly contaminated and pristine locations respectively. These findings suggest that contamination and habitat alteration manifest in substantial differences in the composition of estuarine larval fish assemblages. - Highlights: → We examine contamination/habitat modification impacts on larval fish. → Larvae communities differ between modified/unmodified estuaries. → Larvae are more abundant/diverse in modified areas. → Trends are strongly related to sediment metals/seagrass cover. → Larval impacts have wider ecological importance. - We describe strong links between sediment metals contamination, habitat modification and substantial differences in the composition of the estuarine larval fish assemblage.

  3. Planar Indium Tin Oxide Heater for Improved Thermal Distribution for Metal Oxide Micromachined Gas Sensors

    Directory of Open Access Journals (Sweden)

    M. Cihan Çakır

    2016-09-01

    Full Text Available Metal oxide gas sensors with integrated micro-hotplate structures are widely used in the industry and they are still being investigated and developed. Metal oxide gas sensors have the advantage of being sensitive to a wide range of organic and inorganic volatile compounds, although they lack selectivity. To introduce selectivity, the operating temperature of a single sensor is swept, and the measurements are fed to a discriminating algorithm. The efficiency of those data processing methods strongly depends on temperature uniformity across the active area of the sensor. To achieve this, hot plate structures with complex resistor geometries have been designed and additional heat-spreading structures have been introduced. In this work we designed and fabricated a metal oxide gas sensor integrated with a simple square planar indium tin oxide (ITO heating element, by using conventional micromachining and thin-film deposition techniques. Power consumption–dependent surface temperature measurements were performed. A 420 °C working temperature was achieved at 120 mW power consumption. Temperature distribution uniformity was measured and a 17 °C difference between the hottest and the coldest points of the sensor at an operating temperature of 290 °C was achieved. Transient heat-up and cool-down cycle durations are measured as 40 ms and 20 ms, respectively.

  4. Planar Indium Tin Oxide Heater for Improved Thermal Distribution for Metal Oxide Micromachined Gas Sensors.

    Science.gov (United States)

    Çakır, M Cihan; Çalışkan, Deniz; Bütün, Bayram; Özbay, Ekmel

    2016-09-29

    Metal oxide gas sensors with integrated micro-hotplate structures are widely used in the industry and they are still being investigated and developed. Metal oxide gas sensors have the advantage of being sensitive to a wide range of organic and inorganic volatile compounds, although they lack selectivity. To introduce selectivity, the operating temperature of a single sensor is swept, and the measurements are fed to a discriminating algorithm. The efficiency of those data processing methods strongly depends on temperature uniformity across the active area of the sensor. To achieve this, hot plate structures with complex resistor geometries have been designed and additional heat-spreading structures have been introduced. In this work we designed and fabricated a metal oxide gas sensor integrated with a simple square planar indium tin oxide (ITO) heating element, by using conventional micromachining and thin-film deposition techniques. Power consumption-dependent surface temperature measurements were performed. A 420 °C working temperature was achieved at 120 mW power consumption. Temperature distribution uniformity was measured and a 17 °C difference between the hottest and the coldest points of the sensor at an operating temperature of 290 °C was achieved. Transient heat-up and cool-down cycle durations are measured as 40 ms and 20 ms, respectively.

  5. The distribution and extent of heavy metal accumulation in song sparrows along Arizona's upper Santa Cruz River

    Science.gov (United States)

    Lester, Michael B.; van Riper, Charles

    2014-01-01

    Heavy metals are persistent environmental contaminants, and transport of metals into the environment poses a threat to ecosystems, as plants and wildlife are susceptible to long-term exposure, bioaccumulation, and potential toxicity. We investigated the distribution and cascading extent of heavy metal accumulation in southwestern song sparrows (Melospiza melodia fallax), a resident riparian bird species that occurs along the US/Mexico border in Arizona’s upper Santa Cruz River watershed. This study had three goals: (1) quantify the degree of heavy metal accumulation in sparrows and determine the distributional patterns among study sites, (2) compare concentrations of metals found in this study to those found in studies performed prior to a 2009 international wastewater facility upgrade, and (3) assess the condition of song sparrows among sites with differing potential levels of exposure. We examined five study sites along with a reference site that reflect different potential sources of contamination. Body mass residuals and leukocyte counts were used to assess sparrow condition. Birds at our study sites typically had higher metal concentrations than birds at the reference site. Copper, mercury, nickel, and selenium in song sparrows did exceed background levels, although most metals were below background concentrations determined from previous studies. Song sparrows generally showed lower heavy metal concentrations compared to studies conducted prior to the 2009 wastewater facility upgrade. We found no cascading effects as a result of metal exposure.

  6. Review of algorithms for modeling metal distribution equilibria in liquid-liquid extraction processes

    Directory of Open Access Journals (Sweden)

    Lozano, L. J.

    2005-10-01

    Full Text Available This work focuses on general guidelines to be considered for application of least-squares routines and artificial neural networks (ANN in the estimation of metal distribution equilibria in liquid-liquid extraction process. The goal of the procedure in the statistical method is to find the values of the equilibrium constants (Kj for the reactions involved in the metal extraction which minimizes the differences between experimental distribution coefficient (Dexp and theoretical distribution coefficients according to the mechanism proposed (Dtheor- In the first part of the article, results obtained with the most frequently routine reported in the bibliography are compared with those obtained using the algorithms previously discussed. In the second part, the main features of a single back-propagation neural network for the same purpose are discussed, and the results obtained are compared with those obtained with the classical methods.

    El trabajo presenta las líneas generales a considerar para la estimación del equilibrio de distribución de metales en procesos de extracción líquido-líquido, según dos métodos: algoritmo clásico de mínimos cuadrados y redes neuronales artificiales. El objetivo del procedimiento, en el caso del método estadístico, es encontrar los valores de las constantes de equilibrio (Kj para las reacciones involucradas en la extracción del metal, que minimizan las diferencias entre el coeficiente de distribución experimental y el coeficiente de distribución teórico, de acuerdo al mecanismo propuesto. En la primera parte del artículo se comparan los resultados obtenidos a partir de los algoritmos usados más habitualmente en la bibliografía, con los datos obtenidos mediante el algoritmo previamente descrito. En la segunda parte, se presentan las características fundamentales para aplicar una red neuronal sencilla con algoritmo back-propagation y los

  7. Regional distribution and pollution evaluation of heavy metal pollution in topsoils of the Chengdu plain

    International Nuclear Information System (INIS)

    Li Bing; Wang Changquan; Yang Juan; Tan Ting; Li Huanxiu; Li Qiquan; Yuan Quan

    2009-01-01

    197 farm field samples were designated by GPS and the spatial distribution characteristic and pollution evaluation of Cd, Pb, Cr and Hg in the soils were studied. Compared to the background investigated 20 years ago, the content of Cd in Guanghan, Xindu, Qionglai increased 1, 1.26 and 2 times; respectively; and the content of Pb in Xinjin, Deyang, Guanghan, Xindu increased 1.1 and 3.3 times. However, the content of Cr and Hg in most regions changed much smaller. The results of Kriging interpolation analysis of the heavy metals showed that the content of Cd was grandly decreased followed with the direction from northeast to southwest, the content of other elements exhibited the regional characteristics. The geoaccumulation index was used to evaluate the heavy metals pollution and results indicated that nearly 50% of the soils was polluted by Pb and Cd in different degrees influenced by men activities. With the key contaminated area of Xindu, Guanghan, Xinjing, Deyang the pollution ranks of Pb in soils was in 1 to 4. The Cd pollution although small, but still ranks in 1 to 2 level, the pollution area was bigger, mainly distributed in Xindu, Deyang, Guanghan, Shuangliu, Xinjing, Pengzhou. Only a small number of samples was contaminated by Cr or Hg. (authors)

  8. [Distribution and pollution assessment of heavy metals in soil of relocation areas from the Danjiangkou Reservoir].

    Science.gov (United States)

    Zhang, Lei; Qin, Yan-Wen; Zheng, Bing-Hui; Shi, Yao; Han, Chao-Nan

    2013-01-01

    The aim of this article is to explore the pollution level and potential ecological risk of heavy metals in soil of the relocation areas from the Danjiangkou Reservoir. The contents and spatial distribution of Cd, Pb, Cu, Zn, Cr and As in soil of the relocation areas from the Danjiangkou Reservoir were analyzed. The integrated pollution index and potential ecological risk index were used to evaluate the contamination degree and potential ecological risk of these elements. The results indicated that the average contents of Cd, Pb, Cu, Zn, Cr and As in the samples were 0.61, 23.11, 58.25, 22.65, 58.99 and 16.95 mg x kg(-1), respectively. Compared with the background value of soils from Henan province, all these 6 elements except Zn were enriched to some extent, especially Cd. Similar patterns were observed for the spatial distribution of Cu, Zn, and Pb. Compared with the contents of heavy metals in surface sediments of the typical domestic reservoirs, Cd and As in soil of the relocation areas from the Danjiangkou Reservoir were heavily accumulated. The correlation analysis showed that there were significant positive correlations among Pb, Cu, and Zn. And there was also significant positive correlation between Cr and Pb. In contrast, negative correlation was found between Cr and As. To sum up, the comprehensive assessment results showed that Cd was the primary element with high ecological risk.

  9. Difference in metallic wear distribution released from commercially pure titanium compared with stainless steel plates.

    Science.gov (United States)

    Krischak, G D; Gebhard, F; Mohr, W; Krivan, V; Ignatius, A; Beck, A; Wachter, N J; Reuter, P; Arand, M; Kinzl, L; Claes, L E

    2004-03-01

    Stainless steel and commercially pure titanium are widely used materials in orthopedic implants. However, it is still being controversially discussed whether there are significant differences in tissue reaction and metallic release, which should result in a recommendation for preferred use in clinical practice. A comparative study was performed using 14 stainless steel and 8 commercially pure titanium plates retrieved after a 12-month implantation period. To avoid contamination of the tissue with the elements under investigation, surgical instruments made of zirconium dioxide were used. The tissue samples were analyzed histologically and by inductively coupled plasma atomic emission spectrometry (ICP-AES) for accumulation of the metals Fe, Cr, Mo, Ni, and Ti in the local tissues. Implant corrosion was determined by the use of scanning electron microscopy (SEM). With grades 2 or higher in 9 implants, steel plates revealed a higher extent of corrosion in the SEM compared with titanium, where only one implant showed corrosion grade 2. Metal uptake of all measured ions (Fe, Cr, Mo, Ni) was significantly increased after stainless steel implantation, whereas titanium revealed only high concentrations for Ti. For the two implant materials, a different distribution of the accumulated metals was found by histological examination. Whereas specimens after steel implantation revealed a diffuse siderosis of connective tissue cells, those after titanium exhibited occasionally a focal siderosis due to implantation-associated bleeding. Neither titanium- nor stainless steel-loaded tissues revealed any signs of foreign-body reaction. We conclude from the increased release of toxic, allergic, and potentially carcinogenic ions adjacent to stainless steel that commercially pure Ti should be treated as the preferred material for osteosyntheses if a removal of the implant is not intended. However, neither material provoked a foreign-body reaction in the local tissues, thus cpTi cannot be

  10. A stochastic differential equations approach for the description of helium bubble size distributions in irradiated metals

    Science.gov (United States)

    Seif, Dariush; Ghoniem, Nasr M.

    2014-12-01

    A rate theory model based on the theory of nonlinear stochastic differential equations (SDEs) is developed to estimate the time-dependent size distribution of helium bubbles in metals under irradiation. Using approaches derived from Itô's calculus, rate equations for the first five moments of the size distribution in helium-vacancy space are derived, accounting for the stochastic nature of the atomic processes involved. In the first iteration of the model, the distribution is represented as a bivariate Gaussian distribution. The spread of the distribution about the mean is obtained by white-noise terms in the second-order moments, driven by fluctuations in the general absorption and emission of point defects by bubbles, and fluctuations stemming from collision cascades. This statistical model for the reconstruction of the distribution by its moments is coupled to a previously developed reduced-set, mean-field, rate theory model. As an illustrative case study, the model is applied to a tungsten plasma facing component under irradiation. Our findings highlight the important role of stochastic atomic fluctuations on the evolution of helium-vacancy cluster size distributions. It is found that when the average bubble size is small (at low dpa levels), the relative spread of the distribution is large and average bubble pressures may be very large. As bubbles begin to grow in size, average bubble pressures decrease, and stochastic fluctuations have a lessened effect. The distribution becomes tighter as it evolves in time, corresponding to a more uniform bubble population. The model is formulated in a general way, capable of including point defect drift due to internal temperature and/or stress gradients. These arise during pulsed irradiation, and also during steady irradiation as a result of externally applied or internally generated non-homogeneous stress fields. Discussion is given into how the model can be extended to include full spatial resolution and how the

  11. A stochastic differential equations approach for the description of helium bubble size distributions in irradiated metals

    International Nuclear Information System (INIS)

    Seif, Dariush; Ghoniem, Nasr M.

    2014-01-01

    A rate theory model based on the theory of nonlinear stochastic differential equations (SDEs) is developed to estimate the time-dependent size distribution of helium bubbles in metals under irradiation. Using approaches derived from Itô’s calculus, rate equations for the first five moments of the size distribution in helium–vacancy space are derived, accounting for the stochastic nature of the atomic processes involved. In the first iteration of the model, the distribution is represented as a bivariate Gaussian distribution. The spread of the distribution about the mean is obtained by white-noise terms in the second-order moments, driven by fluctuations in the general absorption and emission of point defects by bubbles, and fluctuations stemming from collision cascades. This statistical model for the reconstruction of the distribution by its moments is coupled to a previously developed reduced-set, mean-field, rate theory model. As an illustrative case study, the model is applied to a tungsten plasma facing component under irradiation. Our findings highlight the important role of stochastic atomic fluctuations on the evolution of helium–vacancy cluster size distributions. It is found that when the average bubble size is small (at low dpa levels), the relative spread of the distribution is large and average bubble pressures may be very large. As bubbles begin to grow in size, average bubble pressures decrease, and stochastic fluctuations have a lessened effect. The distribution becomes tighter as it evolves in time, corresponding to a more uniform bubble population. The model is formulated in a general way, capable of including point defect drift due to internal temperature and/or stress gradients. These arise during pulsed irradiation, and also during steady irradiation as a result of externally applied or internally generated non-homogeneous stress fields. Discussion is given into how the model can be extended to include full spatial resolution and how the

  12. A stochastic differential equations approach for the description of helium bubble size distributions in irradiated metals

    Energy Technology Data Exchange (ETDEWEB)

    Seif, Dariush, E-mail: dariush.seif@iwm-extern.fraunhofer.de [Fraunhofer Institut für Werkstoffmechanik, Freiburg 79108 (Germany); Department of Mechanical and Aerospace Engineering, University of California, Los Angeles, CA 90095-1597 (United States); Ghoniem, Nasr M. [Department of Mechanical and Aerospace Engineering, University of California, Los Angeles, CA 90095-1597 (United States)

    2014-12-15

    A rate theory model based on the theory of nonlinear stochastic differential equations (SDEs) is developed to estimate the time-dependent size distribution of helium bubbles in metals under irradiation. Using approaches derived from Itô’s calculus, rate equations for the first five moments of the size distribution in helium–vacancy space are derived, accounting for the stochastic nature of the atomic processes involved. In the first iteration of the model, the distribution is represented as a bivariate Gaussian distribution. The spread of the distribution about the mean is obtained by white-noise terms in the second-order moments, driven by fluctuations in the general absorption and emission of point defects by bubbles, and fluctuations stemming from collision cascades. This statistical model for the reconstruction of the distribution by its moments is coupled to a previously developed reduced-set, mean-field, rate theory model. As an illustrative case study, the model is applied to a tungsten plasma facing component under irradiation. Our findings highlight the important role of stochastic atomic fluctuations on the evolution of helium–vacancy cluster size distributions. It is found that when the average bubble size is small (at low dpa levels), the relative spread of the distribution is large and average bubble pressures may be very large. As bubbles begin to grow in size, average bubble pressures decrease, and stochastic fluctuations have a lessened effect. The distribution becomes tighter as it evolves in time, corresponding to a more uniform bubble population. The model is formulated in a general way, capable of including point defect drift due to internal temperature and/or stress gradients. These arise during pulsed irradiation, and also during steady irradiation as a result of externally applied or internally generated non-homogeneous stress fields. Discussion is given into how the model can be extended to include full spatial resolution and how the

  13. NUPEC BWR Full-size Fine-mesh Bundle Test (BFBT) Benchmark. Volume II: uncertainty and sensitivity analyses of void distribution and critical power - Specification

    International Nuclear Information System (INIS)

    Aydogan, F.; Hochreiter, L.; Ivanov, K.; Martin, M.; Utsuno, H.; Sartori, E.

    2010-01-01

    experimental cases from the BFBT database for both steady-state void distribution and steady-state critical power uncertainty analyses. In order to study the basic thermal-hydraulics in a single channel, where the concern regarding the cross-flow effect modelling could be removed, an elemental task is proposed, consisting of two sub-tasks that are placed in each phase of the benchmark scope as follows: - Sub-task 1: Void fraction in elemental channel benchmark; - Sub-task 2: Critical power in elemental channel benchmark. The first task can also be utilised as an uncertainty analysis exercise for fine computational fluid dynamics (CFD) models for which the full bundle sensitivity or uncertainty analysis is more difficult. The task is added to the second volume of the specification as an optional exercise. Chapter 2 of this document provides the definition of UA/SA terms. Chapter 3 provides the selection and characterisation of the input uncertain parameters for the BFBT benchmark and the description of the elemental task. Chapter 4 describes the suggested approach for UA/SA of the BFBT benchmark. Chapter 5 provides the selection of data sets for the uncertainty analysis and the elemental task from the BFBT database. Chapter 6 specifies the requested output for void distribution and critical power uncertainty analyses (Exercises I-4 and II-3) as well as for the elemental task. Chapter 7 provides conclusions. Appendix 1 discusses the UA/SA methods. Appendix 2 presents the Phenomena Identification Ranking Tables (PIRT) developed at PSU for void distribution and critical power predictions in order to assist participants in selecting the most sensitive/uncertain code model parameters

  14. Distributing Characteristics of Heavy Metal Elements in A Tributary of Zhedong River in Laowangzhai Gold Deposit, Yunnan (China): An Implication to Environmentology from Sediments

    Science.gov (United States)

    Yang, Shuran; Danĕk, Tomáš; Yang, Xiaofeng; Cheng, Xianfeng

    2016-10-01

    Five heavy metal contents from five sediments and seven sediment profiles in an upstream reach of Zhedong river in Laowangzhai gold deposit were investigated in this research, along with analysis of the horizontal distribution, the surface distribution, the vertical distribution and the interlayer distribution of five heavy metal contents: arsenic (As), mercury (Hg), copper (Cu), lead (Pb) and zinc (Zn). The potential ecological risk of five heavy metals was evaluated to help understanding pollution control of Laowangzhai deposit.

  15. Trace metal distribution in the Arosa estuary (N.W. Spain): The application of a recently developed sequential extraction procedure for metal partitioning

    International Nuclear Information System (INIS)

    Santamaria-Fernandez, Rebeca; Cave, Mark R.; Hill, Steve J.

    2006-01-01

    A study of the trace metal distribution in sediment samples from the Galician coast (Spain) has been performed. A multielement extraction method optimised via experimental design has been employed. The method uses centrifugation to pass the extractant solution at varying pH, through the sediment sample. The sequential leaches were collected and analysed by ICP-AES. Chemometric approaches were utilised to identify the composition of the physico-chemical components in order to characterise the sample. The samples collected at different sites could be classified according to their differences in metal bio-availability and important information regarding element distribution within the physico-chemical components is given. The method has proved to be a quick and reliable way to evaluate sediment samples for environmental geochemistry analysis. In addition, this approach has potential as fast screening method for the bio-availability of metals in the environment

  16. Content and distribution of trace metals in pristine permafrost environments of Northeastern Siberia, Russia

    Science.gov (United States)

    Antcibor, I.; Eschenbach, A.; Kutzbach, L.; Bolshiyanov, D.; Pfeiffer, E.-M.

    2012-04-01

    Arctic regions are one of the most sensitive areas with respect to climatic changes and human impacts. Research is required to discover how the function of permafrost soils as a buffering system for metal pollutants could change in response to the predicted changes. The goal of this work is to determine the background levels of trace metals in the pristine arctic ecosystems of the Lena River Delta in Northeastern Siberia and to evaluate the possible effect of human impacts on this arctic region. The Lena River Delta represents areas with different dominating geomorphologic processes that can generally be divided between accumulation and erosion sites. Frequent changes of the river water level create different periods of sedimentation and result in the formation of stratified soils and sediment layers which are dominated either by mineral substrates with allochthonous organic matter or pure autochthonous peat. The deposited sediments that have formed the delta islands are mostly composed of sand fractions; therefore the buffering effects of clay materials can be neglected. Samoylov Island is representative of the south-central and eastern modern delta surfaces of the Lena River Delta and is selected as a pilot study site. We determined total element contents of Fe, Mn, Zn, Cd, Ni, Cu, As, Pb, Co and Hg in soil horizons from different polygonal elevated rims, polygonal depressed centers and the middle floodplain. High gravimetric concentrations (related to dry mass of soil material) of Mn and Fe are found within all soil profiles and vary from 0.14 to 1.39 g kg-1 and from 10.7 to 41.2 g kg-1, respectively. While the trace element concentrations do not exceed typical crustal abundances, the maximum values of most of the metals are observed within the soil profile situated at the middle floodplain. This finding suggests that apart from the parent material the second potential source of trace metals is due to allochthonous substance input during annual flooding of the

  17. Heavy metals in Semarang`s urban streams: Spatial distribution and bioindication using the guppy (Lepistes reticulatus)

    Energy Technology Data Exchange (ETDEWEB)

    Widianarko, B. [Universitas Katolik Soegijapranata, Semarang (Indonesia)

    1996-12-31

    A field survey on cadmium, lead, copper, and zinc was performed in Semarang, the fifth largest city in Indonesia. Water, sediment, and fish samples were collected from 101 grids of 2 x 2 km. The objectives of the study were (1) to identify the spatial distribution of metals in the sediments of the greater Semarang area, (2) to estimate the background concentrations of the metals present in Semarang, (3) to provide a simple tool for deriving standards for metals in the sediment, and (4) to explore the potential use of the guppy (Lebistes reticulatus) as a bioindicator of urban metal pollution. To map the spatial distribution of the metals, concentrations of each metal in sediment were plotted against the corresponding city coordinate. On the basis of these plots, background concentrations of the metals were estimated. A combined pollution index can be derived thereafter by calculating the difference between metals concentrations from a particular grid and their respective background concentrations. Potential use of the guppy as a bioindicator is assessed, based on a comparison on several demographic parameters (i.e., size structure, sex ratio, reproductive success and energetic status) between unpolluted and heavily polluted populations. 31 refs., 11 figs., 1 tab.

  18. Distribution and Identification of Sources of Heavy Metals in the Voghji River Basin Impacted by Mining Activities (Armenia

    Directory of Open Access Journals (Sweden)

    A. V. Gabrielyan

    2018-01-01

    Full Text Available The objective of this research is to assess the distribution of heavy metals in the waters and sediments of the Voghji River and its tributaries impacted by mining activity and to reveal the real source of each of the heavy metals in the environment for assessing the pollution level of heavy metals. Voghji River with two main tributaries (Geghi and Norashenik drain two mining regions. To identify distribution and pollution sources of heavy metals, the water and sediment samples were collected from eight sampling sites. The results of statistical analysis based on data sets of the period 2014–2016 showed that, after the influence of drainage water and wastewater of mining regions, heavy metal contents in the Voghji River basin dramatically increased. The waters of the Voghji River were highly polluted by Mn, Co, Cu, Zn, Mo, Cd, and Pb. The relation of metals content was highly changed due to anthropogenic impact disturbing the geochemical balance of the Voghji River. The water quality based on only heavy metal contents in the source of the Voghji River belongs to “good” chemical status, and in the sources of Geghi and Norashenik Rivers it is “moderate.” The water quality of Voghji and Norashenik Rivers is sharply worsening after the influence of mining activity, becoming “bad” chemical status. The research revealed the pollution sources of each metal.

  19. Implication of heavy metals distribution for a municipal solid waste management system - a case study in Shanghai

    International Nuclear Information System (INIS)

    Zhang Hua; He Pinjing; Shao Liming

    2008-01-01

    Heavy metal contamination in municipal solid waste (MSW) is of increasing concern. The occurrence and distribution of heavy metals in MSW and their implications for the integrated MSW management system in mega-cities have been investigated by means of material flow analysis based on a case study of Shanghai in China. A good statistical basis was provided through a one-year monitoring program on the mass and metals composition of the waste from three MSW treatment facilities. The results showed that the main heavy metals in the MSW were Zn, Cr, Cu, and Pb (on average > 100 mg kg -1 ), followed by Ni, Cd, and Hg. The MSW contained higher levels of Cu and Ni in metals, Cr and Pb in plastics, and Pb and Zn in the inorganic fractions. Regardless of the sources, the statistically similar heavy metal contents in the organic fractions indicated that effective blending and diffusion of heavy metals had taken place throughout the MSW collection, transfer, transportation, and storage, leading to cross-contamination of the waste fractions. PU (composed of putrescible waste and miscellaneous indistinguishable particles) contributed the majority of the heavy metals to the MSW, followed by plastics, as a result of the predominance in the overall composition of PU and plastics rather than from differences in their heavy metal contents. Therefore, manual or mechanical separation of some significantly heavy metal-rich fractions alone is not sufficient to reduce the heavy metal contents in the MSW. Source separation of organic waste and the diversion of tailored inorganic waste such as hazardous components, construction and demolition waste, etc., are proposed to control the heavy metal contamination in MSW. For the mixed MSW management system, physicochemical fractionation to exclude particles containing high levels of heavy metals can be conducted

  20. Implication of heavy metals distribution for a municipal solid waste management system - a case study in Shanghai

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Hua [State Key Laboratory of Pollution Control and Resources Reuse, Key Laboratory of Yangtze River Water Environment, Ministry of Education, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China); He Pinjing [State Key Laboratory of Pollution Control and Resources Reuse, Key Laboratory of Yangtze River Water Environment, Ministry of Education, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China)], E-mail: solidwaste@mail.tongji.edu.cn; Shao Liming [State Key Laboratory of Pollution Control and Resources Reuse, Key Laboratory of Yangtze River Water Environment, Ministry of Education, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China)

    2008-09-01

    Heavy metal contamination in municipal solid waste (MSW) is of increasing concern. The occurrence and distribution of heavy metals in MSW and their implications for the integrated MSW management system in mega-cities have been investigated by means of material flow analysis based on a case study of Shanghai in China. A good statistical basis was provided through a one-year monitoring program on the mass and metals composition of the waste from three MSW treatment facilities. The results showed that the main heavy metals in the MSW were Zn, Cr, Cu, and Pb (on average > 100 mg kg{sup -1}), followed by Ni, Cd, and Hg. The MSW contained higher levels of Cu and Ni in metals, Cr and Pb in plastics, and Pb and Zn in the inorganic fractions. Regardless of the sources, the statistically similar heavy metal contents in the organic fractions indicated that effective blending and diffusion of heavy metals had taken place throughout the MSW collection, transfer, transportation, and storage, leading to cross-contamination of the waste fractions. PU (composed of putrescible waste and miscellaneous indistinguishable particles) contributed the majority of the heavy metals to the MSW, followed by plastics, as a result of the predominance in the overall composition of PU and plastics rather than from differences in their heavy metal contents. Therefore, manual or mechanical separation of some significantly heavy metal-rich fractions alone is not sufficient to reduce the heavy metal contents in the MSW. Source separation of organic waste and the diversion of tailored inorganic waste such as hazardous components, construction and demolition waste, etc., are proposed to control the heavy metal contamination in MSW. For the mixed MSW management system, physicochemical fractionation to exclude particles containing high levels of heavy metals can be conducted.

  1. Atmospheric quality and distribution of heavy metals in Argentina employing Tillandsia capillaris as a biomonitor.

    Science.gov (United States)

    Pignata, M L; Gudiño, G L; Wannaz, E D; Plá, R R; González, C M; Carreras, H A; Orellana, L

    2002-01-01

    The atmospheric quality and distribution of heavy metals were evaluated throughout a wide region of Argentina. In addition, the biomonitor performance of Tillandsia capillaris Ruiz & Pav. f. capillaris was studied in relation to the accumulation of heavy metals and to its physiologic response to air pollutants. A sampling area of 50,000 km2 was selected in the central region of the Argentine Republic. This area was subdivided into grids of 25 x 25 km. Pools of T. capillaris, where present, were collected at each intersection point. From each pool three sub-samples were analyzed independently. Furthermore, five replicates were collected at 20% of the points in order to analyze the variability within the site. The content of Co, Cu, Fe, Ni, Mn, Pb and Zn was determined by Atomic Absorption Spectrometry. Chemical-physiological parameters were also determined to detect symptoms of foliar damage. Chlorophylls, phaeophytins, hydroperoxy conjugated dienes, malondialdehyde and sulfur were quantified in T. capillaris. Some of these parameters were used to calculate a foliar damage index. Data sets were evaluated by one-way ANOVA, correlation analysis, principal component analysis and mapping. Geographical distribution patterns were obtained for the different metals reflecting the contribution of natural and anthropogenic emission sources. According to our results it can be inferred that Fe, Mn and Co probably originated in the soil. For Pb, the highest values were found in the mountainous area, which can be attributed to the presence of Pb in the granitic rocks. Ni showed mainly an anthropogenic origin, with higher values found in places next to industrial centers. For Zn the highest values were in areas of agricultural development. The same was observed for Cu, whose presence could be related to the employment of pesticides. The foliar damage index distribution map showed that the central and southeastern zones were the ones where the major damage in the bioindicator was

  2. The effects of pH and concentration on heavy metal speciation and mobility, and its relation to heavy metal hyperaccumulation and distribution in selected native Australian flora

    International Nuclear Information System (INIS)

    Menon, D.D.; McPhail, D.C.; Hallam, N.

    2000-01-01

    Full text: The purpose of this research is to establish a clearer understanding of the relations that exist between heavy metal activity, speciation, bioavailability and their uptake and spatial distribution into plants. A combination of experimental modeling and pot trials using toxic heavy metals (cadmium, lead, mercury, copper, chromium and zinc) will be carried out. In the experiments, selected native Australian flora (Eucalyptus, Acacia, Atriplex) adapted to adverse environmental conditions will be used. Varying external factors such as pH, and metal concentration altered the composition of heavy metal speciation in the soil solution. Mathematical and geochemical (PHREEQC) models were used to vary these factors and emulate the conditions under which experimentation will be taking place. These variations help determine the possible heavy metal speciation that would occur in both soil and hydroponic based experiments under given conditions. The rhizosphere, soil solution and the plant material will be analysed by Inductively Coupled Plasma Mass Spectroscopy (ICPMS). Proton Ion X-ray Emission (PIXE) and Secondary Ion Mass spectrometry will help ascertain the distribution, concentration of heavy metal taken up into plant tissues. Information derived from these data will be used to determine and understand how varying such environmental conditions and hence heavy metal speciation affect their bioavailability in the medium, and how their acceptance, accumulation and storage within the selected flora. Preliminary experimentation showed that, for lead and cadmium, the variation in soil solution pH affected the quantity of heavy metal accumulated into selected native Australian flora. ICP-MS analysis of plants subjected to a known soil solution spiked with 200 μmol of lead and cadmium showed that the quantities of lead and cadmium accumulated into plant sections (roots, stems and leaves) varied in the selected woody species. A. heteroclita, A. saligna, and A

  3. [Distribution of heavy metals in waters and pollution assessment in thallium contaminated area of Yunfu, Guangdong].

    Science.gov (United States)

    Li, Xiang-ping; Qi, Jian-ying; Wang, Chun-lin; Chen, Yong-heng

    2011-05-01

    Distribution of Thallium(T1), Cadmium( Cd), Chromium (Cr), Lead (Pb), Nickel (Ni), Arsenic (As), Copper (Cu), Zinc (Zn) in water and sediments of Yunfu pyrite mine area was studied. The environmental risk assessment was conducted systematically using Sediment Quality Guidelines (SQGs) and Hakanson potential ecological risk index. The results indicated that concentration range of Tl in stream water was 0.19-65.25 microg/L, which is higher than the environmental quality standards for surface water. Concentration ranges of Tl, Zn, As, Cd, Pb in sediments were 5.89-63.0 mg/kg, 1215-5754 mg/kg, 208.4-1327 mg/kg, 4.20-17.5 mg/kg, 282-13,770 mg/kg. According to Sediments Quality Guidelines, sediments was moderately to severe level of pollution since concentrations of Tl, Cd, Cr, Pb, Ni, As, Cu, Zn were much higher than LEL (lowest effect level) values, and the concentrations of Pb, As, Zn were higher than SEL (severe effect level) values, the others were partly higher than SEL values, which may result in severe negative biota effects in the watersheds. Compared to soil background values of Guangdong province, the metals in stream sediment showed strong to severe strong ecological risk, and the ecological risk of heavy metals in the descending order of Tl, Cd, As, Pb, Cr, Ni, Zn and Cu. Besides, the sediments were severe contained by toxic element thallium and cadmium. Besides, the mainly ecological risk of heavy metal is thallium. More emphasis should be placed on thallium and cadmium control and disposal in

  4. Heavy metal distribution at dump-field Ľubietová – Podlipa

    Directory of Open Access Journals (Sweden)

    Peter Andráš

    2009-09-01

    Full Text Available The article present the results of the environmental study at the Ľubietová Podlipa dump-field. The distribution of the selectedelements and heavy metals is unequal and depend on the geochemical behaviour of the elements (mainly on their migration ability.The present natural sorbents are predominantly the clay minerals (illite, muscovite, caolinite, smectite and hydrogoethite. The clay mineralsare good sorbents of K, Na, Li, Al, Rb, Sr, Hf, V, Cr, Ti, W, Zr, Nb, Ta a Th and at the hydrogoethite of Cu, Zn, Mo, Mn, Mg, P (± Fe, Cd,Co, Ca. In the case of the Fe, As, Sb, Ag, Pb, Zn, Mn, Mo, Bi, U was proved also the free sorption capacity.

  5. Mass spectrometric probes of metal cluster distributions and metastable ion decay

    International Nuclear Information System (INIS)

    Parks, E.K.; Liu, K.; Cole, S.K.; Riley, S.J.

    1988-01-01

    The study of metal clusters has provided both an opportunity and a challenge to the application of mass spectrometry. These days the most often-used technique for cluster generation - laser vaporization - leads to extensive distributions of cluster sizes, from one to perhaps thousands of atoms, and most studies reported to date use excimer laser ionization and time-of-flight mass spectrometry for cluster detection. Our apparatus is a simple one-stage TOF design employing Wiley-McLauren spatial focusing and a one-meter drift tube. In a second apparatus employing a pulsed valve in the cluster source, we see asymmetric broadening of niobium cluster mass peaks under multiphoton ionization conditions, indicating metastable decay of parent cluster ions. Other studies of niobium clusters have shown no such asymmetric peaks. 2 figs

  6. A geometrical optics polarimetric bidirectional reflectance distribution function for dielectric and metallic surfaces.

    Science.gov (United States)

    Hyde, M W; Schmidt, J D; Havrilla, M J

    2009-11-23

    A polarimetric bidirectional reflectance distribution function (pBRDF), based on geometrical optics, is presented. The pBRDF incorporates a visibility (shadowing/masking) function and a Lambertian (diffuse) component which distinguishes it from other geometrical optics pBRDFs in literature. It is shown that these additions keep the pBRDF bounded (and thus a more realistic physical model) as the angle of incidence or observation approaches grazing and better able to model the behavior of light scattered from rough, reflective surfaces. In this paper, the theoretical development of the pBRDF is shown and discussed. Simulation results of a rough, perfect reflecting surface obtained using an exact, electromagnetic solution and experimental Mueller matrix results of two, rough metallic samples are presented to validate the pBRDF.

  7. MATERIAL DEPENDENCE OF TEMPERATURE DISTRIBUTION IN MULTI-LAYER MULTI-METAL COOKWARE

    Directory of Open Access Journals (Sweden)

    MOHAMMADREZA SEDIGH

    2017-09-01

    Full Text Available Laminated structure is becoming more popular in cookware markets; however, there seems to be a lack of enough scientific studies to evaluate its pros and cons, and to show that how it functions. A numerical model using a finite element method with temperature-dependent material properties has been performed to investigate material and layer dependence of temperature distribution in multi-layer multi-metal plate exposed to irregular heating. Behavior of two parameters including mean temperature value and uniformity on the inner surface of plate under variations of thermal properties and geometrical conditions have been studied. The results indicate that conductive metals used as first layer in bi-layer plates have better thermal performance than those used in the second layer. In addition, since cookware manufacturers increasingly prefer to use all-clad aluminium plate, recently, this structure is analysed in the present study as well. The results show all-clad copper and aluminum plate possesses lower temperature gradient compared with single layer aluminum and all-clad aluminum core plates.

  8. Metallicity Distribution of Disk Stars and the Formation History of the Milky Way

    Science.gov (United States)

    Toyouchi, Daisuke; Chiba, Masashi

    2018-03-01

    We investigate the formation history of the stellar disk component in the Milky Way (MW) based on our new chemical evolution model. Our model considers several fundamental baryonic processes, including gas infall, reaccretion of outflowing gas, and radial migration of disk stars. Each of these baryonic processes in the disk evolution is characterized by model parameters that are determined by fitting to various observational data of the stellar disk in the MW, including the radial dependence of the metallicity distribution function (MDF) of the disk stars, which has recently been derived in the APOGEE survey. We succeeded to obtain the best set of model parameters that well reproduces the observed radial dependences of the mean, standard deviation, skewness, and kurtosis of the MDFs for the disk stars. We analyze the basic properties of our model results in detail to gain new insights into the important baryonic processes in the formation history of the MW. One of the remarkable findings is that outflowing gas, containing many heavy elements, preferentially reaccretes onto the outer disk parts, and this recycling process of metal-enriched gas is a key ingredient for reproducing the observed narrower MDFs at larger radii. Moreover, important implications for the radial dependence of gas infall and the influence of radial migration on the MDFs are also inferred from our model calculation. Thus, the MDF of disk stars is a useful clue for studying the formation history of the MW.

  9. Distribution and temporal variation of trace metal enrichment in surface sediments of San Jorge Bay, Chile.

    Science.gov (United States)

    Valdés, Jorge; Román, Domingo; Guiñez, Marcos; Rivera, Lidia; Morales, Tatiana; Morales, Tomás; Avila, Juan; Cortés, Pedro

    2010-08-01

    Cu, Pb, and Hg concentrations were determined in surface sediment samples collected at three sites in San Jorge Bay, northern Chile. This study aims to evaluate differences in their spatial distribution and temporal variability. The highest metal concentrations were found at the site "Puerto", where minerals (Cu and Pb) have been loaded for more than 60 years. On the other hand, Hg does not pose a contamination problem in this bay. Cu and Pb concentrations showed significant variations from 1 year to another. These variations seem to be a consequence of the combination of several factors, including changes in the loading and/or storage of minerals in San Jorge Bay, the dredging of bottom sediments (especially at Puerto), and seasonal changes in physical-chemical properties of the water column that modify the exchange of metals at the sediment-water interface. Differences in the contamination factor and geoaccumulation index suggest that pre-industrial concentrations measured in marine sediments of this geographical zone, were better than geological values (average shale, continental crust average) for evaluating the degree of contamination in this coastal system. Based on these last two indexes, San Jorge Bay has a serious problem of Cu and Pb pollution at the three sampling locations. However, only Cu exceeds the national maximum values used to evaluate ecological risk and the health of marine environments. It is suggested that Chilean environmental legislation for marine sediment quality--presently under technical discussion--is not an efficient tool for protecting the marine ecosystem.

  10. Distribution and contamination of metals in the soil of Guandu Watershed

    Directory of Open Access Journals (Sweden)

    Aldo Pacheco Ferreira

    2015-11-01

    Full Text Available Coastal areas provide important benefits to humans in terms of food resources and ecosystem services. At the same time, human activities can have significant negative impacts on ecosystem health. Thus, control of watershed pollution is both necessary and essential in order to reduce and systematically eliminate the detrimental consequences that are evident in marine and estuarine ecosystems. The present study investigated the distribution of metals at the Guandu Watershed. Five sampling sites were selected for the soil analysis. Samples were collected from February 2013 to December 2014 and analysed for concentrations of As, Cd, Zn, Cu, Pb, Cr, Ni, and Co, using ICP. For control, some samples were used in uncontaminated areas outside the direct effect of chemical industries. The data indicate the presence of metals at the research sites. While the levels of contamination are still slightly below the peak concentrations established by Brazilian legislation, they are approaching levels of concern, particularly with regard to As, Cd, Pb and Cr. The results indicate that the use of water from the Guandu Watershed for recreational purposes and fishing is harmful to both human health and the environment.

  11. Distribution of trace metals at Hopewell Furnace National Historic Site, Berks and Chester Counties, Pennsylvania

    Science.gov (United States)

    Sloto, Ronald A.; Reif, Andrew G.

    2011-01-01

    Hopewell Furnace, located approximately 50 miles northwest of Philadelphia, was a cold-blast, charcoal iron furnace that operated for 113 years (1771 to 1883). The purpose of this study by the U.S. Geological Survey, in cooperation with the National Park Service, was to determine the distribution of trace metals released to the environment from an historical iron smelter at Hopewell Furnace National Historic Site (NHS). Hopewell Furnace used iron ore from local mines that contained abundant magnetite and accessory sulfide minerals enriched in arsenic, cobalt, copper, and other metals. Ore, slag, cast iron furnace products, soil, groundwater, stream base flow, streambed sediment, and benthic macroinvertebrates were sampled for this study. Soil samples analyzed in the laboratory had concentrations of trace metals low enough to meet Pennsylvania Department of Environmental Protection standards for non-residential use. Groundwater samples from the supply well met U.S. Environmental Protection Agency drinking-water regulations. Concentrations of metals in surface-water base flow at the five stream sampling sites were below continuous concentration criteria for protection of aquatic organisms. Concentrations of metals in sediment at the five stream sites were below probable effects level guidelines for protection of aquatic organisms except for copper at site HF-3. Arsenic, copper, lead, zinc, and possibly cobalt were incorporated into the cast iron produced by Hopewell Furnace. Manganese was concentrated in slag along with iron, nickel, and zinc. The soil near the furnace has elevated concentrations of chromium, copper, iron, lead, and zinc compared to background soil concentrations. Concentrations of toxic elements were not present at concentrations of concern in water, soil, or stream sediments, despite being elevated in ore, slag, and cast iron furnace products. The base-flow surface-water samples indicated good overall quality. The five sampled sites generally had

  12. Spatial distribution and sources of heavy metals in natural pasture soil around copper-molybdenum mine in Northeast China.

    Science.gov (United States)

    Wang, Zhiqiang; Hong, Chen; Xing, Yi; Wang, Kang; Li, Yifei; Feng, Lihui; Ma, Silu

    2018-06-15

    The characterization of the content and source of heavy metals are essential to assess the potential threat of metals to human health. The present study collected 140 topsoil samples around a Cu-Mo mine (Wunugetushan, China) and investigated the concentrations and spatial distribution pattern of Cr, Ni, Zn, Cu, Mo and Cd in soil using multivariate and geostatistical analytical methods. Results indicated that the average concentrations of six heavy metals, especially Cu and Mo, were obviously higher than the local background values. Correlation analysis and principal component analysis divided these metals into three groups, including Cr and Ni, Cu and Mo, Zn and Cd. Meanwhile, the spatial distribution maps of heavy metals indicated that Cr and Ni in soil were no notable anthropogenic inputs and mainly controlled by natural factors because their spatial maps exhibited non-point source contamination. The concentrations of Cu and Mo gradually decreased with distance away from the mine area, suggesting that human mining activities may be crucial in the spreading of contaminants. Soil contamination of Zn were associated with livestock manure produced from grazing. In addition, the environmental risk of heavy metal pollution was assessed by geo-accumulation index. All the results revealed that the spatial distribution of heavy metals in soil were in agreement with the local human activities. Investigating and identifying the origin of heavy metals in pasture soil will lay the foundation for taking effective measures to preserve soil from the long-term accumulation of heavy metals. Copyright © 2018 Elsevier Inc. All rights reserved.

  13. Particle size distribution and characteristics of heavy metals in road-deposited sediments from Beijing Olympic Park.

    Science.gov (United States)

    Li, Haiyan; Shi, Anbang; Zhang, Xiaoran

    2015-06-01

    Due to rapid urbanization and industrialization, heavy metals in road-deposited sediments (RDSs) of parks are emitted into the terrestrial, atmospheric, and water environment, and have a severe impact on residents' and tourists' health. To identify the distribution and characteristic of heavy metals in RDS and to assess the road environmental quality in Chinese parks, samples were collected from Beijing Olympic Park in the present study. The results indicated that particles with small grain size (Pb>Cu>Zn. This study analyzed the mobility of heavy metals in sediments using partial sequential extraction with the Tessier procedure. The results revealed that the apparent mobility and potential metal bioavailability of heavy metals in the sediments, based on the exchangeable and carbonate fractions, decreased in the order: Cd>Zn≈Pb>Cu. Copyright © 2015. Published by Elsevier B.V.

  14. A preliminary investigation of the distribution of heavy metals in surface sediments of the Cona tidal marsh (Venice Lagoon)

    International Nuclear Information System (INIS)

    Bernardi, S.; Costa, F.; Vazzoler, S.; Zonta, R.

    1988-01-01

    Data are from the two series of surface sediment sampling in an interface area between the Venice Lagoon and the mainland. The distribution of heavy metals gives a correlation with polluted sourcesites-identified in the channel systems with a highly polluted input-and allows us to identify the localities of accumulation. Restricted to the estuary of the river tributary transporting a high concentration of pollutants into a tidal marsh area of the lagoon, the study shows the effect of the fresh water forcing to distribute heavy metals on surface sediments. Within the scope of this preliminary investigation, indications from sampling identify a sector of the 'palude of Cona' in this estuary, which is highly suitable for detailed studies on precesses affecting heavy-metal distributions in bottom surface sediments of shallow-water areas

  15. Fine Root Growth and Vertical Distribution in Response to Elevated CO2, Warming and Drought in a Mixed Heathland–Grassland

    DEFF Research Database (Denmark)

    Arndal, Marie Frost; Tolver, Anders; Larsen, Klaus Steenberg

    2018-01-01

    in single-factor experiments. In a Danish heathland ecosystem, we investigated both individual and combined effects of elevated CO2, warming and drought on fine root length, net production and standing biomass by the use of minirhizotrons, ingrowth cores and soil coring. Warming increased the net root...... production from ingrowth cores, but decreased fine root number and length in minirhizotrons, whereas there were no significant main effects of drought. Across all treatments and soil depths, CO2 stimulated both the total fine root length (+44%) and the number of roots observed (+39%), with highest relative......Belowground plant responses have received much less attention in climate change experiments than aboveground plant responses, thus hampering a holistic understanding of climate change effects on plants and ecosystems. In addition, responses of plant roots to climate change have mostly been studied...

  16. On the distribution of metals deposited onto the limiter and the liner of tokamaks after long-term operation

    International Nuclear Information System (INIS)

    Wolff, H.; Grote, H.; Herrmann, A.; Hildebrandt, D.; Laux, M.; Pech, P.; Reiner, H.D.; Ziegenhagen, G.; Chicherov, V.M.; Grashin, S.A.; Kopecky, V.; Jakubka, K.

    1987-01-01

    Three inspections of the inner parts of the discharge vessels of T-10 and TM1-MH after long-term operation revealed that metals originating from the various construction materials are distributed inhomogeneously over the first wall of these tokamaks. This partially allows one to identify local metal sources and to indicate anisotropies of the transport. Different materials from inner structures, even if they were only used in earlier experiments, are observed at all limiter surfaces and as components of the debris consisting of macroparticles of different size, shape and elemental composition. There are metallic deposits of the form of structured films or of solidified droplets. (orig.)

  17. Enhanced chlorine dioxide decay in the presence of metal oxides: Relevance to drinking water distribution systems

    KAUST Repository

    Liu, Chao; von Gunten, Urs; Croue, Jean-Philippe

    2013-01-01

    Chlorine dioxide (ClO2) decay in the presence of typical metal oxides occurring in distribution systems was investigated. Metal oxides generally enhanced ClO2 decay in a second-order process via three pathways: (1) catalytic disproportionation with equimolar formation of chlorite and chlorate, (2) reaction to chlorite and oxygen, and (3) oxidation of a metal in a reduced form (e.g., cuprous oxide) to a higher oxidation state. Cupric oxide (CuO) and nickel oxide (NiO) showed significantly stronger abilities than goethite (α-FeOOH) to catalyze the ClO2 disproportionation (pathway 1), which predominated at higher initial ClO2 concentrations (56-81 μM). At lower initial ClO2 concentrations (13-31 μM), pathway 2 also contributed. The CuO-enhanced ClO2 decay is a base-assisted reaction with a third-order rate constant of 1.5 × 10 6 M-2 s-1 in the presence of 0.1 g L -1 CuO at 21 ± 1 C, which is 4-5 orders of magnitude higher than in the absence of CuO. The presence of natural organic matter (NOM) significantly enhanced the formation of chlorite and decreased the ClO 2 disproportionation in the CuO-ClO2 system, probably because of a higher reactivity of CuO-activated ClO2 with NOM. Furthermore, a kinetic model was developed to simulate CuO-enhanced ClO 2 decay at various pH values. Model simulations that agree well with the experimental data include a pre-equilibrium step with the rapid formation of a complex, namely, CuO-activated Cl2O4. The reaction of this complex with OH- is the rate-limiting and pH-dependent step for the overall reaction, producing chlorite and an intermediate that further forms chlorate and oxygen in parallel. These novel findings suggest that the possible ClO2 loss and the formation of chlorite/chlorate should be carefully considered in drinking water distribution systems containing copper pipes. © 2013 American Chemical Society.

  18. Enhanced chlorine dioxide decay in the presence of metal oxides: Relevance to drinking water distribution systems

    KAUST Repository

    Liu, Chao

    2013-07-19

    Chlorine dioxide (ClO2) decay in the presence of typical metal oxides occurring in distribution systems was investigated. Metal oxides generally enhanced ClO2 decay in a second-order process via three pathways: (1) catalytic disproportionation with equimolar formation of chlorite and chlorate, (2) reaction to chlorite and oxygen, and (3) oxidation of a metal in a reduced form (e.g., cuprous oxide) to a higher oxidation state. Cupric oxide (CuO) and nickel oxide (NiO) showed significantly stronger abilities than goethite (α-FeOOH) to catalyze the ClO2 disproportionation (pathway 1), which predominated at higher initial ClO2 concentrations (56-81 μM). At lower initial ClO2 concentrations (13-31 μM), pathway 2 also contributed. The CuO-enhanced ClO2 decay is a base-assisted reaction with a third-order rate constant of 1.5 × 10 6 M-2 s-1 in the presence of 0.1 g L -1 CuO at 21 ± 1 C, which is 4-5 orders of magnitude higher than in the absence of CuO. The presence of natural organic matter (NOM) significantly enhanced the formation of chlorite and decreased the ClO 2 disproportionation in the CuO-ClO2 system, probably because of a higher reactivity of CuO-activated ClO2 with NOM. Furthermore, a kinetic model was developed to simulate CuO-enhanced ClO 2 decay at various pH values. Model simulations that agree well with the experimental data include a pre-equilibrium step with the rapid formation of a complex, namely, CuO-activated Cl2O4. The reaction of this complex with OH- is the rate-limiting and pH-dependent step for the overall reaction, producing chlorite and an intermediate that further forms chlorate and oxygen in parallel. These novel findings suggest that the possible ClO2 loss and the formation of chlorite/chlorate should be carefully considered in drinking water distribution systems containing copper pipes. © 2013 American Chemical Society.

  19. Effect of dimensional error of metallic bipolar plate on the GDL pressure distribution in the PEM fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Dong' an; Peng, Linfa; Lai, Xinmin [State Key Laboratory of Mechanical System and Vibration, Shanghai Jiao Tong University, Dongchuan Road 800, Shanghai 200240 (China)

    2009-01-15

    Recently, the metallic bipolar plate (BPP) has received considerable attention because of its advantageous electrical and mechanical properties. In this study, a methodology based on FEA model and Monte Carlo simulation is developed to investigate the effect of dimensional error of the metallic BPP on the pressure distribution of gas diffusion layer (GDL). At first, a parameterized FEA model of metallic BPP/GDL assembly is established, and heights of the channel and rib are considered to be randomly varying parameters of normal distribution due to the dimensional error. Then, GDL pressure distributions with different dimensional errors are obtained respectively based on the Monte Carlo simulation, and the desirability function method is employed to evaluate them. At last, a regression equation between the GDL pressure distribution and the dimensional error is modeled. With the regression equation, the allowed maximum dimensional error for the metallic BPP is calculated. The methodology in this study can be applied to guide the design and manufacturing of the metallic BPP. (author)

  20. Determination of distribution pattern of the heavy metal concentrations in the potable network of Gachsaran by Geographical Information System (GIS

    Directory of Open Access Journals (Sweden)

    G Paraham

    2013-12-01

    . Methods: In this descriptive, cross-sectional study, samples were taken from11 spots of the drinking water distribution network and tested for concentration of 10 metals by Inductivity Coupled Ions Plasma (ICP method in summer of 2010. The research data were compared with national and international water standards. Then the distribution map of heavy metals concentrations in the drinking water wells of the region was prepared by using the Geographical Information System (GIS software. Data were analyzed by the Kruskal-Wallis tests. Results: In all samples, the average concentration of heavy metals were: Arsenic 0.54, Cadmium 0.05, Zinc 55.9, Lead 0.18, Copper .82, Chromium 1.6, Barium 36.5, Selenium0.5, Mercury 0.1 and Silver 0.05 micrograms per liter and was less than the water quality standard. Conclusion: Based on the results obtained, it can be concluded that concentrations of heavy metals in Gachsaran’s drinking water distribution network are not higher than national and international standards and therefore not harmful for people. Key words: Heavy metals, Distribution network, Gachsaran, geographical information system (GIS

  1. Nonlinear Color–Metallicity Relations of Globular Clusters. VII. Nonlinear Absorption-line Index versus Metallicity Relations and Bimodal Index Distributions of NGC 5128 Globular Clusters

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sooyoung; Yoon, Suk-Jin, E-mail: sjyoon0691@yonsei.ac.kr [Department of Astronomy and Center for Galaxy Evolution Research, Yonsei University, Seoul 120-749 (Korea, Republic of)

    2017-07-01

    Spectroscopy on the globular cluster (GC) system of NGC 5128 revealed bimodality in absorption-line index distributions of its old GCs. GC division is a widely observed and studied phenomenon whose interpretation has depicted host galaxy formation and evolution such that it harbors two distinct metallicity groups. Such a conventional view of GC bimodality has mainly been based on photometry. The recent GC photometric data, however, presented an alternative perspective in which the nonlinear metallicity-to-color transformation is responsible for color bimodality of GC systems. Here we apply the same line of analysis to the spectral indices and examine the absorption-line index versus metallicity relations for the NGC 5128 GC system. NGC 5128 GCs display nonlinearity in the metallicity-index planes, most prominently for the Balmer lines and by a non-negligible degree for the metallicity-sensitive magnesium line. We demonstrate that the observed spectroscopic division of NGC 5128 GCs can be caused by the nonlinear nature of the metallicity-to-index conversions and thus one does not need to resort to two separate GC subgroups. Our analysis incorporating this nonlinearity provides a new perspective on the structure of NGC 5128's GC system, and a further piece to the global picture of the formation of GC systems and their host galaxies.

  2. Calculation of the fine neutron flux distribution in the multi-zone reactor cell by spherical harmonics method; Odredjivanje fine raspodele fluksa u viseregionalnoj celiji reaktora primenom metode sfernih harmonika

    Energy Technology Data Exchange (ETDEWEB)

    Jockovic, M; Stefanovic, D; Barucija, M [The Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Yugoslavia)

    1965-07-01

    This presentation contains development and application of method for calculating the neutron flux distribution by P{sub 3} approximation. A computer codes was developed for the ZUSE-Z-23 computer. Some typical results are included.

  3. Determination of fine neutron flux distribution in multi-region reactor cell by applying spherical harmonics method; Odredjivanje fine rspodele fluksa u viseregionalnoj celiji reaktora primenom metode sfernih harmonika

    Energy Technology Data Exchange (ETDEWEB)

    Jockovic, M; Stefanovic, D; Barucija, M [Institut za nuklearne nauke Boris Kidric, Vinca, Beograd (Yugoslavia)

    1964-07-01

    Neutron distribution in space, direction of movement, energy and time is described by Boltzmann equation. This paper describes the adaptation of method for calculating the neutron flux distribution in P{sub 3} approximation and the computer code written for the ZUSE-Z-23 computer. Some results for a few typical reactor cells are included. The number of regions in the reactor cell treated by the code is limited only by the capacity of the computer.

  4. Effect of cadmium exposure on lipids, lipid peroxidation and metal distribution in rat brain regions

    Energy Technology Data Exchange (ETDEWEB)

    Hussain, T; Ali, M M; Chandra, S V

    1985-01-01

    Effect of cadmium treatment on brain lipids, lipid peroxidation and distribution of Zn, Cu and Fe in rat brain regions was investigated. Adult male rats were exposed to Cd (100 ppm Cd as cadmium acetate) in drinking water for 30 days. The Cd exposure resulted in a significant decrease in the phospholipid content and an increase in the lipid peroxidation in the cerebral cortex and cerebellum. The total lipid content was not affected in any of the regions but a significant decrease in cholesterol and cerebroside contents were observed only in the cerebral cortex. A positive correlation between the increase in lipid peroxidation and decrease in the phospholipid content in the cerebral cortex and cerebellum was observed. A maximum accumulation of Cd occurred in the cerebral cortex. The Cu and Fe contents were significantly increased but the Zn levels decreased in the Cd-treated rats in all but the midbrain region. Results suggest that the increased peroxidation decomposition of structural lipids and the altered distribution of the essential trace metals in brain may play a significant role in Cd-induced neurotoxicity. 27 references, 2 tables.

  5. Spatial distribution of heavy metals in solid adjacent to the Naples-Salerno motor way

    International Nuclear Information System (INIS)

    Imperato, M.; Monetti, V.; Naimo, D.; Stanzione, D.

    1999-01-01

    This work analyses the distribution of heavy metal in soil adjacent to the Naples-Salerno motor way, an area which typically contains volcanic products from Somma-Vesuvio. The various concentrations of Pb, Cd, Zn, Mn, Cu and Cr found in different portions of the motor way (embankment, road cut, field level) are reported. The data obtained indicate high level of pollution in soil adjacent to the motor way fencing, with maximum concentrations of 1220 ppm Pb, 1.9 ppm Cd and 341 ppm Zn. Gradients of decreasing pollution with distance from the fencing and with altitude from the road surface are highest for Zn followed by Pb and Cd. The presence of these three materials in depth follows an averagely constant falling gradient, with minimum detected values at 50 cm depth. The spatial distribution of Cr does not reveal any significant differences. Relatively big levels are due to the presence in the soil of Chromium-rich minerals such as augite and olivine. Mn and Cu are found, due to local contribution, probably as a consequence of the use of copper compounds in agriculture [it

  6. Distribution of rare-earth (Y, La, Ce) and other heavy metals in the profiles of the podzolic soil group

    Science.gov (United States)

    Vodyanitskii, Yu. N.; Goryachkin, S. V.; Savichev, A. T.

    2011-05-01

    Along with Fe and Al, many heavy metals (Mn, Cr, Zn, Cu, and Ni) show a markedly pronounced eluvial-illuvial redistribution in the profiles of soils of the podzolic group. The intensity of the redistribution of the bulk forms of these metals is comparable with that of Fe and exceeds that of Al. Although the podzolic soils are depleted of rare-earth metals, the latter respond readily to soil podzolization. The inactive participation of Al is explained by an insignificant portion of the active reaction-capable fraction. Podzolization does not influence the profile distribution of Sr and Ba. The leaching degree of heavy metals such as Mn, Cr, Zn, Ni, and Zr is noticeably higher in the sandy podzols than in the loamy podzolic soils. Leaching of heavy metals from the podzolic horizons is of geochemical importance, whereas the depletion of metals participating in plant nutrition and biota development is of ecological importance. The leaching of heavy metals is related to the destruction of clay particles in the heavy-textured podzolic soils; the effect of the soil acidity on the leaching of heavy metals is less significant.

  7. Pb, Cu, and Zn distributions at humic acid-coated metal-oxide surfaces

    Science.gov (United States)

    Wang, Yingge; Michel, F. Marc; Choi, Yongseong; Eng, Peter J.; Levard, Clement; Siebner, Hagar; Gu, Baohua; Bargar, John R.; Brown, Gordon E.

    2016-09-01

    (II) mobilized from the ESHA coatings onto the α-Al2O3 (1 -1 0 2) surfaces increased from 40% (no added Ca) to 58% (with 2 mM Ca) after 72 h of reaction time, possibly due to displacement of Pb(II) by Ca(II) from binding sites in the ESHA coatings. In contrast, Pb(II), Cu(II), and Zn(II) present in the ESHA coatings were found to be unreactive with the α-Al2O3 (0 0 0 1) surface. The observed reactivities of the three ESHA-coated metal-oxide surfaces with respect to metal-ion sorption are consistent with the trend observed for the uncoated metal-oxide surfaces: α-Fe2O3 (0 0 0 1) > α-Al2O3 (1 -1 0 2) > α-Al2O3 (0 0 0 1). In addition, Pb(II) partitioning onto α-Al2O3 (1 -1 0 2) surfaces increased with increasing pH from 4.0 to 9.0 as a result of the increasingly negative surface charge. These results show that intrinsic properties (nature of binding sites, binding affinities, and surface charge) of the ESHA coatings and metal-oxide surfaces, as well as external parameters such as pH and competing ions, are key factors governing the distribution and speciation of metal ions at complex NOM/mineral interfaces.

  8. Fine scale population genetic structure and within tree distribution of mating types of Venturia effusa, cause of pecan scab in the USA

    Science.gov (United States)

    Scab (caused by Venturia effusa) is the major disease of pecan in the southeastern USA. There is no information available on the fine scale population genetic diversity. Four cv. Wichita trees (populations) were sampled hierarchically. Within each tree canopy, 4 approximately evenly spaced terminals...

  9. Analysis of the Elastic Large Deflection Behavior for Metal Plates under Nonuniformly Distributed Lateral Pressure with In-Plane Loads

    Directory of Open Access Journals (Sweden)

    Jeom Kee Paik

    2012-01-01

    Full Text Available The Galerkin method is applied to analyze the elastic large deflection behavior of metal plates subject to a combination of in-plane loads such as biaxial loads, edge shear and biaxial inplane bending moments, and uniformly or nonuniformly distributed lateral pressure loads. The motive of the present study was initiated by the fact that metal plates of ships and ship-shaped offshore structures at sea are often subjected to non-uniformly distributed lateral pressure loads arising from cargo or water pressure, together with inplane axial loads or inplane bending moments, but the current practice of the maritime industry usually applies some simplified design methods assuming that the non-uniform pressure distribution in the plates can be replaced by an equivalence of uniform pressure distribution. Applied examples are presented, demonstrating that the current plate design methods of the maritime industry may be inappropriate when the non-uniformity of lateral pressure loads becomes more significant.

  10. Trace metal distribution in sediments of the Pearl River Estuary and the surrounding coastal area, South China

    International Nuclear Information System (INIS)

    Ip, Carman C.M.; Li Xiangdong; Zhang Gan; Wai, Onyx W.H.; Li, Y.-S.

    2007-01-01

    Surface sediments and sediment cores collected at the Pearl River Estuary (PRE) and its surrounding coastal area were analysed for total metal concentrations, chemical partitioning, and Pb isotopic compositions. The distribution of Cu, Cr, Pb, and Zn demonstrated a typical diffusion pattern from the land to the direction of the sea. Two hotspots of trace metal contamination were located at the mixed zone between freshwater and marine waters. The enrichment of metals in the sediments could be attributed to the deposition of the dissolved and particulate trace metals in the water column at the estuarine area. The similar Pb isotopic signatures of the sediments at the PRE and its surrounding coastal area offered strong evidence that the PRE was a major source of trace metals to the adjacent coastal area. Slightly lower 206 Pb/ 207 Pb ratios in the coastal sediments may indicate other inputs of Pb in addition to the PRE sources, including the inputs from Hong Kong and other parts of the region. - The distribution of trace metals in sediments reflected contaminant sources, physical and chemical deposition processes

  11. Spatial Distribution and Pollution Characteristics of Heavy Metals in Soil of Mentougou Mining Area of Beijing City, China

    Directory of Open Access Journals (Sweden)

    XING Yu-xin

    2016-11-01

    Full Text Available The pollution characteristics and spatial distribution of soil heavy metals around mine-concentrated area in Mentougou were comprehensive studied using ArcGIS carried by inverse distance weighted interpolation mathematical model and SPSS multivariate statistical analysis. The ecological risk assessment was carried out by the potential ecological risk index. The results showed that the spatial distribution of soil heavy metal concentrations increased gradually from the west to the east of study area. Harmful degrees of heavy metals decreased in the order of Hg > Cd > Pb > Cr > Zn > Cu > Ni > As. Combination of coal mining and human activity caused the strongest risk, while the risks caused by heavy metals from sandstone minerals was relatively weak. The potential ecological risk indexes(RI of eight heavy metals were between 67.81 and 668.53. The order of the potential ecological risk was Hg > Cd > As > Pb > Ni > Cu > Cr > Zn. In summary, the heavy metals in soil of the study area were harmful. Because the study area is located in the ecological conservation district of Beijing, the ecological harm should not be overlooked, and needs to be evaluated and repaired.

  12. Spatial distribution of heavy metals in sediments from the Gulf of Paria, Trinidad

    International Nuclear Information System (INIS)

    Norville, W.

    2005-01-01

    The Gulf of Paria receives heavy metal input from urban runoff, industrial and agricultural activity, sewage and domestic wastes: both from the west coast and from inland areas of Trinidad. Non-residual concentrations of nine metals, as well as total mercury concentrations, were used to determine spatial distributions of heavy metals in sediments in the Gulf of Paria. Surficial sediment samples were collected at 37 stations, which included the mouths of 11 major rivers that flow into the Gulf of Paria. Stations were sampled twice during the wet season (July 1998 and November/ December 1998) and twice during the dry season (March 1999 and April 1999). Sediments were analyzed for aluminium (Al), cadmium (Cd), chromium (Cr), copper (Cu), iron (Fe), lead (Pb), manganese (Mn), nickel (Ni), zinc (Zn) and mercury (Hg). Total Organic Carbon (TOC) and grain size analyses were also performed on the sediments. Principal component analysis showed that sediments from river mouths subject to greatest land use and anthropogenic input, were distinct from other sediments in the Gulf of Paria. This was due to higher Pb, Zn, Cu and Hg concentrations (3.53-73.30 μ g-', 45.8-313.9 μg g-', 8.43-39.71 μg g' and 0.03-0.10 μg g-', respectively). Sediments further from the coast were also distinct due to their higher Al, Fe, Cr and Mn concentrations (1.37-3.16 mg g-', 9.51-18.91 mg g-',17.22-28.41 μg g-' and 323.6--1,564.2 pg g-', respectively). Cd and Pb were higher in the wet season while Ni was higher in the dry season. Pb, Zn, Cu and Hg were correlated with each other and with TOC. Correlation was also observed between Al, Fe, Cr, Mn and Ni. Al, Fe, Cr and Mn were correlated with percentage clay in sediments. The results suggest that Pb, Zn, Cu and Hg are preferentially removed by organic matter, which settles at the river-mouths, while Al, Fe, Cr, Mn, and Ni become associated with clay minerals and are transported away from the coast.(From the author) [es

  13. [Distribution patterns and pollution assessments of heavy metals in the Spartina alterniflora salt-marsh wetland of Rudong, Jiangsu province].

    Science.gov (United States)

    Zhang, Long-Hui; Du, Yong-Fen; Wang, Dan-Dan; Gao, Shu; Gao, Wen-Hua

    2014-06-01

    To understand the ecological impact of Spartina alterniflora on the coastal wetland environment, field survey was carried out in July, 2010, over the intertidal areas of Rudong coast, Jiangsu province; sediment samples were collected from a series of stations with different conditions of vegetation cover and S. alterniflora growth. The contents of eight heavy metals, together with sediment composition and total organic carbon were analyzed to reveal the distribution patterns of the heavy metals. Environmental quality status was evaluated using both the index of geoaccumulation (I(geo)) and the index of the Håkanson ecological risk. The analytical results showed that the average contents of Pb, Cd, As, Hg, Cr, Cu, Ni and Zn were below the standard for the Category I sediment quality, among which Cd, Hg, Ni and Zn exceeded the sediment background value of the region. On the whole, the contents of eight heavy metals in vegetation areas were higher than those associated with the adjacent bare flat areas. These data sets indicate a non-polluted condition in term of I(geo) estimation; however, a critical state of low to moderate degrees of pollution and a low level of risk were deduced according to the index of the Håkanson potential ecological risk. Both indices suggested that the pollution level of Hg and Cd were the highest among the eight metals measured. Along the transection from seaward to landward, the contents of As, Cu and Hg, their indices of I(geo) and Håkanson ecological risk all showed an increasing tread, in accordance with the condition of vegetation cover. Along the coastline with S. alterniflora being distributed in patchiness, all metal contents and their ecological risk level values for the marshes were higher than those for the unvegetated sediments nearby; moreover, except for Hg, other seven metals exhibited relatively low values than those in the shore-normal section with a better S. alterniflora growth. These findings indicate that S

  14. Modelling chemical abundance distributions for dwarf galaxies in the Local Group: the impact of turbulent metal diffusion

    Science.gov (United States)

    Escala, Ivanna; Wetzel, Andrew; Kirby, Evan N.; Hopkins, Philip F.; Ma, Xiangcheng; Wheeler, Coral; Kereš, Dušan; Faucher-Giguère, Claude-André; Quataert, Eliot

    2018-02-01

    We investigate stellar metallicity distribution functions (MDFs), including Fe and α-element abundances, in dwarf galaxies from the Feedback in Realistic Environment (FIRE) project. We examine both isolated dwarf galaxies and those that are satellites of a Milky Way-mass galaxy. In particular, we study the effects of including a sub-grid turbulent model for the diffusion of metals in gas. Simulations that include diffusion have narrower MDFs and abundance ratio distributions, because diffusion drives individual gas and star particles towards the average metallicity. This effect provides significantly better agreement with observed abundance distributions in dwarf galaxies in the Local Group, including small intrinsic scatter in [α/Fe] versus [Fe/H] of ≲0.1 dex. This small intrinsic scatter arises in our simulations because the interstellar medium in dwarf galaxies is well mixed at nearly all cosmic times, such that stars that form at a given time have similar abundances to ≲0.1 dex. Thus, most of the scatter in abundances at z = 0 arises from redshift evolution and not from instantaneous scatter in the ISM. We find similar MDF widths and intrinsic scatter for satellite and isolated dwarf galaxies, which suggests that environmental effects play a minor role compared with internal chemical evolution in our simulations. Overall, with the inclusion of metal diffusion, our simulations reproduce abundance distribution widths of observed low-mass galaxies, enabling detailed studies of chemical evolution in galaxy formation.

  15. Distribution and behaviour of selected heavy metals and other elements in various components of the southern Baltic ecosystem

    International Nuclear Information System (INIS)

    Szefer, P.

    1998-01-01

    The concentrations and discrimination of selected heavy metals in biota from the southern Baltic indicate that a large group of the Baltic organisms bioaccumulates Fe and Pb but discriminates against U. There appears to be no significant transfer of heavy metals along successive levels of the food chain. The distribution of the heavy metals in the associated sediments is a result of the anthropogenic input of Zn, Pb, Cd, Ag, P and Cu. It is suggested that Pb is introduced to the Polish sector of the Baltic Sea mainly by atmospheric transport whereas other heavy-metal pollutants are introduced mainly from the Vistula River. (Copyright (c) 1998 Elsevier Science B.V., Amsterdam. All rights reserved.)

  16. Influence of heavy metals on the formation and the distribution behavior of PAH and PCDD/F during simulated fires.

    Science.gov (United States)

    Wobst, M; Wichmann, H; Bahadir, M

    2003-04-01

    Combustion experiments were performed with an artificial fire load (polystyrene and quartz powder) in a laboratory scale incinerator in the presence of gaseous HCl to simulate accidental fire conditions. The aim of this investigation was to trace back the alterations of the formation and the distribution behavior of PAH and PCDD/PCDF to the presence of CuO or a mixture of metal oxides (CdO, CuO, Fe(2)O(3), PbO, MoO(3), ZnO). The total amount of the 16 PAH target compounds was reduced by the factor of 5-9 when the mixture of metal oxides was present rather than merely CuO. PAH patterns as well as their distribution behavior were significantly influenced by these oxides. In general, transportation inside the installation was enhanced for most of the 16 analyzed PAH. Only fluorene and dibenzo[a,h]anthracene were transported to a smaller extent. In contrast to PAH, total concentrations of PCDD were increased by factor 9 and of PCDF by factor 10, respectively, when CuO was present. Adding the mixture of metal oxides resulted in an increase of PCDD by factor 14 and of PCDF by factor 7. CuO and the mixture of metal oxides had a different influence on the PCDD/F homologue patterns. For instance, the HxCDF to OCDF ratio after incineration without any metal oxide was 1 to 6, whereas addition of CuO or the mixture of the metal oxides shifted the HxCDF to OCDF ratios towards 1 to 40 or 1 to 17, respectively. Combustion along with CuO increased transportation of higher chlorinated PCDF congeners, whereas the mixture of the metal oxides caused a strong decrease of PCDF distribution throughout the system.

  17. THE EATING HABITS OF MILKY WAY-MASS HALOS: DESTROYED DWARF SATELLITES AND THE METALLICITY DISTRIBUTION OF ACCRETED STARS

    International Nuclear Information System (INIS)

    Deason, Alis J.; Mao, Yao-Yuan; Wechsler, Risa H.

    2016-01-01

    We study the mass spectrum of destroyed dwarfs that contribute to the accreted stellar mass of Milky Way (MW)-mass (M vir  ∼ 10 12.1 M ⊙ ) halos using a suite of 45 zoom-in dissipationless simulations. Empirical models are employed to relate (peak) subhalo mass to dwarf stellar mass, and we use constraints from z = 0 observations and hydrodynamical simulations to estimate the metallicity distribution of the accreted stellar material. The dominant contributors to the accreted stellar mass are relatively massive dwarfs with M star  ∼ 10 8 –10 10 M ⊙ . Halos with more quiescent accretion histories tend to have lower mass progenitors (10 8 –10 9 M ⊙ ), and lower overall accreted stellar masses. Ultra-faint mass (M star  < 10 5 M ⊙ ) dwarfs contribute a negligible amount (≪1%) to the accreted stellar mass and, despite having low average metallicities, supply a small fraction (∼2%–5%) of the very metal-poor stars with [Fe/H] < −2. Dwarfs with masses 10 5  < M star /M ⊙  < 10 8 provide a substantial amount of the very metal-poor stellar material (∼40%–80%), and even relatively metal-rich dwarfs with M star  > 10 8 M ⊙ can contribute a considerable fraction (∼20%–60%) of metal-poor stars if their metallicity distributions have significant metal-poor tails. Finally, we find that the generic assumption of a quiescent assembly history for the MW halo seems to be in tension with the mass spectrum of its surviving dwarfs. We suggest that the MW could be a “transient fossil”; a quiescent halo with a recent accretion event(s) that disguises the preceding formation history of the halo

  18. Modelling the fine and coarse fraction of Pb, Cd, As and Ni air concentration in Spain

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, M. A.; Vivanco, M. G.

    2015-07-01

    Lead, cadmium, arsenic and nickel are present in the air due to natural and anthropogenic emissions, normally joined to particles. Human health and ecosystems can be damaged by high atmospheric levels of these metals, since they can be introduced in organisms via inhalation or ingestion. Small particles are inhaled and embebed in lungs and alveolus more easily than coarse particles. The CHIMERE model is a eulerian air quality model extensively used in air quality modelling. Metals have been recently included in this model in a special version developed in the CIEMAT modelling group (Madrid, Spain). Vivanco et al. (2011) and Gonzalez et al. (2012) showed an evaluation of the model performance for some metals in Spain and Europe. In these studies, metals were considered as fine particles. Nevertheless there is some observational evidence of the presence of some metals also in the coarse fraction. For this reason, a new attempt of modelling metals considering a fine (<2.5 μm) and coarse (2.5-10 μm) fraction has been done. Measurements of metal concentration in PM10, PM2.5 and PM1 recorded in Spain were used to obtain the new metal particle distribution size. On the other hand, natural emissions, not considered in the above mentioned studies, were implemented in the model, by considering metal emissions associated to dust resuspensiont. An evaluation of the new version is presented and discussed for two domains in Spain, centered on Barcelona and Huelva respectively. (Author)

  19. Modelling the fine and coarse fraction of Pb, Cd, As and Ni air concentration in Spain

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, M.A.; Vivanco, M.

    2015-07-01

    Lead, cadmium, arsenic and nickel are present in the air due to natural and anthropogenic emissions, normally joined to particles. Human health and ecosystems can be damaged by high atmospheric levels of these metals, since they can be introduced in organisms via inhalation or ingestion. Small particles are inhaled and embebed in lungs and alveolus more easily than coarse particles. The CHIMERE model is a eulerian air quality model extensively used in air quality modelling. Metals have been recently included in this model in a special version developed in the CIEMAT modelling group (Madrid, Spain). Vivanco et al. (2011) and González et al. (2012) showed an evaluation of the model performance for some metals in Spain and Europe. In these studies, metals were considered as fine particles. Nevertheless there is some observational evidence of the presence of some metals also in the coarse fraction. For this reason, a new attempt of modelling metals considering a fine (<2.5 μm) and coarse (2.5-10 μm) fraction has been done. Measurements of metal concentration in PM10, PM2.5 and PM1 recorded in Spain were used to obtain the new metal particle distribution size. On the other hand, natural emissions, not considered in the above mentioned studies, were implemented in the model, by considering metal emissions associated to dust resuspensiont. An evaluation of the new version is presented and discussed for two domains in Spain, centered on Barcelona and Huelva respectively. (Author)

  20. Modelling the fine and coarse fraction of Pb, Cd, As and Ni air concentration in Spain

    International Nuclear Information System (INIS)

    Gonzalez, M. A.; Vivanco, M. G.

    2015-01-01

    Lead, cadmium, arsenic and nickel are present in the air due to natural and anthropogenic emissions, normally joined to particles. Human health and ecosystems can be damaged by high atmospheric levels of these metals, since they can be introduced in organisms via inhalation or ingestion. Small particles are inhaled and embebed in lungs and alveolus more easily than coarse particles. The CHIMERE model is a eulerian air quality model extensively used in air quality modelling. Metals have been recently included in this model in a special version developed in the CIEMAT modelling group (Madrid, Spain). Vivanco et al. (2011) and Gonzalez et al. (2012) showed an evaluation of the model performance for some metals in Spain and Europe. In these studies, metals were considered as fine particles. Nevertheless there is some observational evidence of the presence of some metals also in the coarse fraction. For this reason, a new attempt of modelling metals considering a fine (<2.5 μm) and coarse (2.5-10 μm) fraction has been done. Measurements of metal concentration in PM10, PM2.5 and PM1 recorded in Spain were used to obtain the new metal particle distribution size. On the other hand, natural emissions, not considered in the above mentioned studies, were implemented in the model, by considering metal emissions associated to dust resuspensiont. An evaluation of the new version is presented and discussed for two domains in Spain, centered on Barcelona and Huelva respectively. (Author)

  1. Structure and nature of the metal-support interface: characterization of iridium clusters on magnesium oxide by extended x-ray absorption fine structure spectroscopy

    NARCIS (Netherlands)

    Zon, van F.B.M.; Maloney, S.D.; Gates, B.C.; Koningsberger, D.C.

    1993-01-01

    X-ray absorption spectroscopy was used to characterize the metal-support interface in catalysts consisting of very small Ir clusters of nearly uniform nuclearity on the surface of MgO powder. [Ir4(CO)12] on MgO was converted in high yield into [HIr4(CO)11]- and sep. into [Ir6(CO)15]2-. EXAFS data

  2. Angular distribution of scattered electron and medium energy electron spectroscopy for metals

    International Nuclear Information System (INIS)

    Oguri, Takeo; Ishioka, Hisamichi; Fukuda, Hisashi; Irako, Mitsuhiro

    1986-01-01

    The angular distribution (AD) of scattered electrons produced by medium energy incident electrons (E P = 50 ∼ 300 eV) from polycrystalline Ti, Fe, Ni, Cu and Au were obtained by the angle-resolved medium energy electron spectrometer. The AD of the energy loss peaks are similar figures to AD of the elastically reflected electron peaks. Therefore, the exchanged electrons produced by the knock-on collision between the incident electrons and those of metals without momentum transfer are observed as the energy loss spectra (ELS). This interpretation differs from the inconsequent interpretation by the dielectric theory or the interband transition. The information depth and penetration length are obtained from AD of the Auger electron peaks. The contribution of the surface to spectra is 3 % at the maximum for E P = 50 eV. The true secondary peaks representing the secondary electron emission spectroscopy (SES) are caused by the emissions of the energetic electrons (kT e ≥ 4 eV), and SES is the inversion of ELS. The established fundamental view is that the medium energy electron spectra represent the total bulk density of states. (author)

  3. Thermocouple and Infrared Sensor-Based Measurement of Temperature Distribution in Metal Cutting

    Directory of Open Access Journals (Sweden)

    Abdil Kus

    2015-01-01

    Full Text Available In metal cutting, the magnitude of the temperature at the tool-chip interface is a function of the cutting parameters. This temperature directly affects production; therefore, increased research on the role of cutting temperatures can lead to improved machining operations. In this study, tool temperature was estimated by simultaneous temperature measurement employing both a K-type thermocouple and an infrared radiation (IR pyrometer to measure the tool-chip interface temperature. Due to the complexity of the machining processes, the integration of different measuring techniques was necessary in order to obtain consistent temperature data. The thermal analysis results were compared via the ANSYS finite element method. Experiments were carried out in dry machining using workpiece material of AISI 4140 alloy steel that was heat treated by an induction process to a hardness of 50 HRC. A PVD TiAlN-TiN-coated WNVG 080404-IC907 carbide insert was used during the turning process. The results showed that with increasing cutting speed, feed rate and depth of cut, the tool temperature increased; the cutting speed was found to be the most effective parameter in assessing the temperature rise. The heat distribution of the cutting tool, tool-chip interface and workpiece provided effective and useful data for the optimization of selected cutting parameters during orthogonal machining.

  4. Thermocouple and infrared sensor-based measurement of temperature distribution in metal cutting.

    Science.gov (United States)

    Kus, Abdil; Isik, Yahya; Cakir, M Cemal; Coşkun, Salih; Özdemir, Kadir

    2015-01-12

    In metal cutting, the magnitude of the temperature at the tool-chip interface is a function of the cutting parameters. This temperature directly affects production; therefore, increased research on the role of cutting temperatures can lead to improved machining operations. In this study, tool temperature was estimated by simultaneous temperature measurement employing both a K-type thermocouple and an infrared radiation (IR) pyrometer to measure the tool-chip interface temperature. Due to the complexity of the machining processes, the integration of different measuring techniques was necessary in order to obtain consistent temperature data. The thermal analysis results were compared via the ANSYS finite element method. Experiments were carried out in dry machining using workpiece material of AISI 4140 alloy steel that was heat treated by an induction process to a hardness of 50 HRC. A PVD TiAlN-TiN-coated WNVG 080404-IC907 carbide insert was used during the turning process. The results showed that with increasing cutting speed, feed rate and depth of cut, the tool temperature increased; the cutting speed was found to be the most effective parameter in assessing the temperature rise. The heat distribution of the cutting tool, tool-chip interface and workpiece provided effective and useful data for the optimization of selected cutting parameters during orthogonal machining.

  5. Metal leaching in drinking water domestic distribution system: an Italian case study.

    Science.gov (United States)

    Sorlini, Sabrina; Gialdini, Francesca; Collivignarelli, Carlo

    2014-01-01

    The objective of this study was to evaluate metal contamination of tap water in seven public buildings in Brescia (Italy). Two monitoring periods were performed using three different sampling methods (overnight stagnation, 30-min stagnation, and random daytime). The results show that the water parameters exceeding the international standards (Directive 98/83/EC) at the tap were lead (max = 363 μg/L), nickel (max = 184 μg/L), zinc (max = 4900 μg/L), and iron (max = 393 μg/L). Compared to the total number of tap water samples analyzed (122), the values higher than limits of Directive 98/83/EC were 17% for lead, 11% for nickel, 14% for zinc, and 7% for iron. Three buildings exceeded iron standard while five buildings exceeded the standard for nickel, lead, and zinc. Moreover, there is no evident correlation between the leaching of contaminants in the domestic distribution system and the age of the pipes while a significant influence is shown by the sampling methods.

  6. Thermocouple and Infrared Sensor-Based Measurement of Temperature Distribution in Metal Cutting

    Science.gov (United States)

    Kus, Abdil; Isik, Yahya; Cakir, M. Cemal; Coşkun, Salih; Özdemir, Kadir

    2015-01-01

    In metal cutting, the magnitude of the temperature at the tool-chip interface is a function of the cutting parameters. This temperature directly affects production; therefore, increased research on the role of cutting temperatures can lead to improved machining operations. In this study, tool temperature was estimated by simultaneous temperature measurement employing both a K-type thermocouple and an infrared radiation (IR) pyrometer to measure the tool-chip interface temperature. Due to the complexity of the machining processes, the integration of different measuring techniques was necessary in order to obtain consistent temperature data. The thermal analysis results were compared via the ANSYS finite element method. Experiments were carried out in dry machining using workpiece material of AISI 4140 alloy steel that was heat treated by an induction process to a hardness of 50 HRC. A PVD TiAlN-TiN-coated WNVG 080404-IC907 carbide insert was used during the turning process. The results showed that with increasing cutting speed, feed rate and depth of cut, the tool temperature increased; the cutting speed was found to be the most effective parameter in assessing the temperature rise. The heat distribution of the cutting tool, tool-chip interface and workpiece provided effective and useful data for the optimization of selected cutting parameters during orthogonal machining. PMID:25587976

  7. Metal contamination in campus dust of Xi'an, China: A study based on multivariate statistics and spatial distribution

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Hao [School of Tourism and Environment, Shaanxi Normal University, Xi' an 710062 (China); Lu, Xinwei, E-mail: luxinwei@snnu.edu.cn [School of Tourism and Environment, Shaanxi Normal University, Xi' an 710062 (China); Li, Loretta Y., E-mail: lli@civil.ubc.ca [Department of Civil Engineering, University of British Columbia, Vancouver V6T 1Z4 (Canada); Gao, Tianning; Chang, Yuyu [School of Tourism and Environment, Shaanxi Normal University, Xi' an 710062 (China)

    2014-06-01

    The concentrations of As, Ba, Co, Cr, Cu, Mn, Ni, Pb, V and Zn in campus dust from kindergartens, elementary schools, middle schools and universities of Xi'an, China were determined by X-ray fluorescence spectrometry. Correlation coefficient analysis, principal component analysis (PCA) and cluster analysis (CA) were used to analyze the data and to identify possible sources of these metals in the dust. The spatial distributions of metals in urban dust of Xi'an were analyzed based on the metal concentrations in campus dusts using the geostatistics method. The results indicate that dust samples from campuses have elevated metal concentrations, especially for Pb, Zn, Co, Cu, Cr and Ba, with the mean values of 7.1, 5.6, 3.7, 2.9, 2.5 and 1.9 times the background values for Shaanxi soil, respectively. The enrichment factor results indicate that Mn, Ni, V, As and Ba in the campus dust were deficiently to minimally enriched, mainly affected by nature and partly by anthropogenic sources, while Co, Cr, Cu, Pb and Zn in the campus dust and especially Pb and Zn were mostly affected by human activities. As and Cu, Mn and Ni, Ba and V, and Pb and Zn had similar distribution patterns. The southwest high-tech industrial area and south commercial and residential areas have relatively high levels of most metals. Three main sources were identified based on correlation coefficient analysis, PCA, CA, as well as spatial distribution characteristics. As, Ni, Cu, Mn, Pb, Zn and Cr have mixed sources — nature, traffic, as well as fossil fuel combustion and weathering of materials. Ba and V are mainly derived from nature, but partly also from industrial emissions, as well as construction sources, while Co principally originates from construction. - Highlights: • Metal content in dust from schools was determined by XRF. • Spatial distribution of metals in urban dust was focused on campus samples. • Multivariate statistic and spatial distribution were used to identify metal

  8. Metal contamination in campus dust of Xi'an, China: A study based on multivariate statistics and spatial distribution

    International Nuclear Information System (INIS)

    Chen, Hao; Lu, Xinwei; Li, Loretta Y.; Gao, Tianning; Chang, Yuyu

    2014-01-01

    The concentrations of As, Ba, Co, Cr, Cu, Mn, Ni, Pb, V and Zn in campus dust from kindergartens, elementary schools, middle schools and universities of Xi'an, China were determined by X-ray fluorescence spectrometry. Correlation coefficient analysis, principal component analysis (PCA) and cluster analysis (CA) were used to analyze the data and to identify possible sources of these metals in the dust. The spatial distributions of metals in urban dust of Xi'an were analyzed based on the metal concentrations in campus dusts using the geostatistics method. The results indicate that dust samples from campuses have elevated metal concentrations, especially for Pb, Zn, Co, Cu, Cr and Ba, with the mean values of 7.1, 5.6, 3.7, 2.9, 2.5 and 1.9 times the background values for Shaanxi soil, respectively. The enrichment factor results indicate that Mn, Ni, V, As and Ba in the campus dust were deficiently to minimally enriched, mainly affected by nature and partly by anthropogenic sources, while Co, Cr, Cu, Pb and Zn in the campus dust and especially Pb and Zn were mostly affected by human activities. As and Cu, Mn and Ni, Ba and V, and Pb and Zn had similar distribution patterns. The southwest high-tech industrial area and south commercial and residential areas have relatively high levels of most metals. Three main sources were identified based on correlation coefficient analysis, PCA, CA, as well as spatial distribution characteristics. As, Ni, Cu, Mn, Pb, Zn and Cr have mixed sources — nature, traffic, as well as fossil fuel combustion and weathering of materials. Ba and V are mainly derived from nature, but partly also from industrial emissions, as well as construction sources, while Co principally originates from construction. - Highlights: • Metal content in dust from schools was determined by XRF. • Spatial distribution of metals in urban dust was focused on campus samples. • Multivariate statistic and spatial distribution were used to identify metal sources.

  9. Effect of preemptive weld overlay sequence on residual stress distribution for dissimilar metal weld of Kori nuclear power plant pressurizer

    Energy Technology Data Exchange (ETDEWEB)

    Bae, Hong Yeol; Song, Tae Kwang; Chun, Yun Bae; Oh, Chang Young; Kim, Yun Jae [Korea Univ., Seoul (Korea, Republic of); Lee, Kyoung Soo; Park, Chi Yong [Korea Electric Power Research Institute, Daejeon (Korea, Republic of)

    2008-07-01

    Weld overlay is one of the residual stress mitigation method which arrest crack. An overlay weld sued in this manner is termed a Preemptive Weld OverLay(PWOL). PWOL was good for distribution of residual stress of Dissimilar Metal Weld(DMW) by previous research. Because range of overlay welding is wide relatively, residual stress distribution on PWR is affected by welding sequence. In order to examine the effect of welding sequence, PWOL was applied to a specific DMW of KORI nuclear power plant by finite element analysis method. As a result, the welding direction that from nozzle to pipe is better good for residual stress distribution on PWR.

  10. The mechanical behavior of metal alloys with grain size distribution in a wide range of strain rates

    Science.gov (United States)

    Skripnyak, V. A.; Skripnyak, V. V.; Skripnyak, E. G.

    2017-12-01

    The paper discusses a multiscale simulation approach for the construction of grain structure of metals and alloys, providing high tensile strength with ductility. This work compares the mechanical behavior of light alloys and the influence of the grain size distribution in a wide range of strain rates. The influence of the grain size distribution on the inelastic deformation and fracture of aluminium and magnesium alloys is investigated by computer simulations in a wide range of strain rates. It is shown that the yield stress depends on the logarithm of the normalized strain rate for light alloys with a bimodal grain distribution and coarse-grained structure.

  11. Effect of preemptive weld overlay sequence on residual stress distribution for dissimilar metal weld of Kori nuclear power plant pressurizer

    International Nuclear Information System (INIS)

    Bae, Hong Yeol; Song, Tae Kwang; Chun, Yun Bae; Oh, Chang Young; Kim, Yun Jae; Lee, Kyoung Soo; Park, Chi Yong

    2008-01-01

    Weld overlay is one of the residual stress mitigation method which arrest crack. An overlay weld sued in this manner is termed a Preemptive Weld OverLay(PWOL). PWOL was good for distribution of residual stress of Dissimilar Metal Weld(DMW) by previous research. Because range of overlay welding is wide relatively, residual stress distribution on PWR is affected by welding sequence. In order to examine the effect of welding sequence, PWOL was applied to a specific DMW of KORI nuclear power plant by finite element analysis method. As a result, the welding direction that from nozzle to pipe is better good for residual stress distribution on PWR

  12. Spatial distribution of heavy metals in sediments from the Gulf of Paria,Trinidad

    Directory of Open Access Journals (Sweden)

    Wendy Norville

    2005-05-01

    Full Text Available The Gulf of Paria receives heavy metal input from urban runoff,industrial and agricultural activity, sewage and domestic wastes:both from the west coast and from inland areas of Trinidad.Non-residual concentrations of nine metals,as well as total mercury concentrations,were used to determine spatial distributions of heavy metals in sediments in the Gulf of Paria.Surficial sediment samples were collected at 37 stations,which included the mouths of 11 major rivers that flow into the Gulf of Paria.Stations were sampled twice during the wet season (July 1998 and November/December 1998and twice during the dry season (March 1999 and April 1999.Sediments were analyzed for aluminium (Al,cadmium (Cd,chromium (Cr,copper (Cu,iron (Fe, lead (Pb,manganese (Mn,nickel (Ni,zinc (Znand mercury (Hg.Total Organic Carbon (TOCand grain size analyses were also performed on the sediments.Principal component analysis showed that sediments from river mouths subject to greatest land use and anthropogenic input,were distinct from other sediments in the Gulf of Paria.This was due to higher Pb,Zn,Cu and Hg concentrations (3.53-73.30 µg g-1 ,45.8-313.9 µg g-1 ,8.43-39.71 µg g-1 and 0.03-0.10 µg g-1 ,respectively.Sediments further from the coast were also distinct due to their higher Al,Fe,Cr and Mn concentrations (1.37-3.16 mg g-1 ,9.51-18.91 mg g-1 ,17.22-28.41 µg g-1 and 323.6 -1,564.2 µg g-1 ,respectively.Cd and Pb were higher in the wet season while Ni was higher in the dry season.Pb,Zn,Cu and Hg were correlated with each other and with TOC.Correlation was also observed between Al,Fe,Cr,Mn and Ni.Al,Fe,Cr and Mn were correlated with percentage clay in sediments.The results suggest that Pb,Zn, Cu and Hg are preferentially removed by organic matter,which settles at the river-mouths,while Al,Fe,Cr,Mn, and Ni become associated with clay minerals and are transported away from the coast.El Golfo de Paria recibe metales pesados de zonas urbanas,industriales y agr

  13. Assessment of heavy metal pollution in vegetables and relationships with soil heavy metal distribution in Zhejiang province, China.

    Science.gov (United States)

    Ye, Xuezhu; Xiao, Wendan; Zhang, Yongzhi; Zhao, Shouping; Wang, Gangjun; Zhang, Qi; Wang, Qiang

    2015-06-01

    There are increasing concerns on heavy metal contaminant in soils and vegetables. In this study, we investigated heavy metal pollution in vegetables and the corresponding soils in the main vegetable production regions of Zhejiang province, China. A total of 97 vegetable samples and 202 agricultural soil samples were analyzed for the concentrations of Cd, Pb, As, Hg, and Cr. The average levels of Cd, Pb, and Cr in vegetable samples [Chinese cabbage (Brassica campestris spp. Pekinensis), pakchoi (Brassica chinensis L.), celery (Apium graveolens), tomato (Lycopersicon esculentum), cucumber (Colletotrichum lagenarium), cowpea (Vigna unguiculata), pumpkin (Cucurbita pepo L.), and eggplant (Solanum melongena)] were 0.020, 0.048, and 0.043 mg kg(-1), respectively. The Pb and Cr concentrations in all vegetable samples were below the threshold levels of the Food Quality Standard (0.3 and 0.5 mg kg(-1), respectively), except that two eggplant samples exceeded the threshold levels for Cd concentrations (0.05 mg kg(-1)). As and Hg contents in vegetables were below the detection level (0.005 and 0.002 mg kg(-1), respectively). Soil pollution conditions were assessed in accordance with the Chinese Soil Quality Criterion (GB15618-1995, Grade II); 50 and 68 soil samples from the investigated area exceeded the maximum allowable contents for Cd and Hg, respectively. Simple correlation analysis revealed that there were significantly positive correlations between the metal concentrations in vegetables and the corresponding soils, especially for the leafy and stem vegetables such as pakchoi, cabbage, and celery. Bio-concentration factor values for Cd are higher than those for Pb and Cr, which indicates that Cd is more readily absorbed by vegetables than Pb and Cr. Therefore, more attention should be paid to the possible pollution of heavy metals in vegetables, especially Cd.

  14. Scattering influences in quantitative fission neutron radiography for the in situ analysis of hydrogen distribution in metal hydrides

    Energy Technology Data Exchange (ETDEWEB)

    Börries, S., E-mail: stefan.boerries@hzg.de [Helmholtz-Zentrum Geesthacht, Centre for Materials and Coastal Research, Max-Planck-Strasse 1, D-21502 Geesthacht (Germany); Metz, O.; Pranzas, P.K. [Helmholtz-Zentrum Geesthacht, Centre for Materials and Coastal Research, Max-Planck-Strasse 1, D-21502 Geesthacht (Germany); Bücherl, T. [ZTWB Radiochemie München (RCM), Technische Universität München (TUM), Walther-Meissner-Str. 3, D-85748 Garching (Germany); Söllradl, S. [Forschungs-Neutronenquelle Heinz Maier-Leibnitz (FRMII), Technische Universität München (TUM), Lichtenbergstr. 1, D-85748 Garching (Germany); Dornheim, M.; Klassen, T.; Schreyer, A. [Helmholtz-Zentrum Geesthacht, Centre for Materials and Coastal Research, Max-Planck-Strasse 1, D-21502 Geesthacht (Germany)

    2015-10-11

    In situ neutron radiography allows for the time-resolved study of hydrogen distribution in metal hydrides. However, for a precise quantitative investigation of a time-dependent hydrogen content within a host material, an exact knowledge of the corresponding attenuation coefficient is necessary. Additionally, the effect of scattering has to be considered as it is known to violate Beer's law, which is used to determine the amount of hydrogen from a measured intensity distribution. Within this study, we used a metal hydride inside two different hydrogen storage tanks as host systems, consisting of steel and aluminum. The neutron beam attenuation by hydrogen was investigated in these two different setups during the hydrogen absorption process. A linear correlation to the amount of absorbed hydrogen was found, allowing for a readily quantitative investigation. Further, an analysis of scattering contributions on the measured intensity distributions was performed and is described in detail.

  15. Heavy metals distribution in soils surrounding an abandoned mine in NW Madrid (Spain) and their transference to wild flora.

    Science.gov (United States)

    Moreno-Jiménez, Eduardo; Peñalosa, Jesús M; Manzano, Rebeca; Carpena-Ruiz, Ramón O; Gamarra, Roberto; Esteban, Elvira

    2009-03-15

    The present work concerns the distribution and mobility of heavy metals (Fe, Mn, Cu, Zn and Cd) in the surrounding soils of a mine site and their transfer to wild flora. Thus, soils and plants were sampled from a mining valley in NW Madrid (Spain), and total and extractable heavy metals were analysed. Soils affected by mining activities presented total Cd, Cu and Zn concentrations above toxic thresholds. The percentage of extractable element was highest for Cd and lowest for Cu. A highly significant correlation was observed between the total and extractable concentrations of metals in soils, indicating that, among the factors studied, total metals concentration is the most relevant for heavy metals extractability in these soils. (NH(4))(2)SO(4)-extractable metal concentrations in soils are correlated better with metal concentrations in several plant species than total metals in soils, and thus can be used as a suitable and robust method for the estimation of the phytoavailable fraction present in soils. Twenty-five vascular plant species (3 ferns and 22 flowering plants) were analysed, in order to identify exceptional characteristics that would be interesting for soil phytoremediation and/or reclamation. High Cd and Zn concentrations have been found in the aerial parts of Hypericum perforatum (Cd), Salix atrocinerea (Cd, Zn) and Digitalis thapsi (Cd, Zn). The present paper is, to the best of our knowledge, the first report of the metal accumulation ability of the two latter plant species. The phytoremediation ability of S. atrocinerea for Cd and Zn was estimated, obtaining intervals of time that could be considered suitable for the phytoextraction of polluted soils.

  16. Real-Time Measurement of Electronic Cigarette Aerosol Size Distribution and Metals Content Analysis.

    Science.gov (United States)

    Mikheev, Vladimir B; Brinkman, Marielle C; Granville, Courtney A; Gordon, Sydney M; Clark, Pamela I

    2016-09-01

    Electronic cigarette (e-cigarette) use is increasing worldwide and is highest among both daily and nondaily smokers. E-cigarettes are perceived as a healthier alternative to combustible tobacco products, but their health risk factors have not yet been established, and one of them is lack of data on aerosol size generated by e-cigarettes. We applied a real-time, high-resolution aerosol differential mobility spectrometer to monitor the evolution of aerosol size and concentration during puff development. Particles generated by e-cigarettes were immediately delivered for analysis with minimal dilution and therefore with minimal sample distortion, which is critically important given the highly dynamic aerosol/vapor mixture inherent to e-cigarette emissions. E-cigarette aerosols normally exhibit a bimodal particle size distribution: nanoparticles (11-25nm count median diameter) and submicron particles (96-175nm count median diameter). Each mode has comparable number concentrations (10(7)-10(8) particles/cm(3)). "Dry puff" tests conducted with no e-cigarette liquid (e-liquid) present in the e-cigarette tank demonstrated that under these conditions only nanoparticles were generated. Analysis of the bulk aerosol collected on the filter showed that e-cigarette emissions contained a variety of metals. E-cigarette aerosol size distribution is different from that of combustible tobacco smoke. E-cigarettes generate high concentrations of nanoparticles and their chemical content requires further investigation. Despite the small mass of nanoparticles, their toxicological impact could be significant. Toxic chemicals that are attached to the small nanoparticles may have greater adverse health effects than when attached to larger submicron particles. The e-cigarette aerosol size distribution is different from that of combustible tobacco smoke and typically exhibits a bimodal behavior with comparable number concentrations of nanoparticles and submicron particles. While vaping the e

  17. Utilidade do pente metálico com dentes microcanaliculados no diagnóstico da pediculose Metal microchanelled fine-toothed comb use in the diagnosis of pediculosis

    Directory of Open Access Journals (Sweden)

    Patricia Elena Neira

    2009-12-01

    Full Text Available FUNDAMENTOS: Os métodos para diagnosticar Pediculus humanus var. capitis são controvertidos e a maioria dos estudos tem usado o exame visual direto. OBJETIVOS: O objetivo deste estudo foi comparar a eficácia no diagnóstico do exame visual direto em contraposição ao uso do pente metálico de aço com dentes microcanaliculados. MÉTODOS: Investigaram-se 946 crianças e adolescentes de quatro a 19 anos. O cabelo de cada criança foi examinado duas vezes, para detectar infestação pelos diferentes estádios, por meio da observação visual direta e com o pente metálico. RESULTADOS: O diagnóstico visual apontou infestação em 30,7% dos casos, enquanto que o pente metálico indicou um resultado de 51,5%. O sexo feminino foi o mais acometido, de acordo com ambos os métodos. As formas parasitárias detectadas com o exame visual direto foram: somente piolhos (adultos e/ou ninfas; 1,4%; somente lêndeas vivas, 64,8%; e lêndeas vivas mais piolhos, 33,8%; com o pente metálico, foram 6,4%, 23,6% e 70%, respectivamente. A média de tempo para descobrir um piolho foi de 57 segundos com o pente metálico e de 116,4 segundos com a observação visual direta. CONCLUSÕES: O diagnóstico é duas vezes mais rápido e 3,6 vezes mais eficiente com o pente metálico microcanaliculado. O método visual leva a uma subestimação das infestações ativas e revela as passadas não ativas.BACKGROUND: Methods for the diagnosis of Pediculus humanus var. capitis are controversial and most studies are based on direct visual exam. OBJECTIVE: The objective of this study was to compare the diagnosis efficacy of both direct visual exam and the use of a metal microchanelled fine-toothed comb. METHODS: 946 children and teenagers 4 to 19 years of age were examined. Each individual’s hair was examined twice to determine whether there was infestation by lice or nits, through direct visual exam and the use of a metal microchanelled fine-toothed comb. RESULTS: The visual

  18. Tin Oxide Crystals Exposed by Low-Energy {110} Facets for Enhanced Electrochemical Heavy Metal Ions Sensing: X-ray Absorption Fine Structure Experimental Combined with Density-Functional Theory Evidence.

    Science.gov (United States)

    Jin, Zhen; Yang, Meng; Chen, Shao-Hua; Liu, Jin-Huai; Li, Qun-Xiang; Huang, Xing-Jiu

    2017-02-21

    Herein, we revealed that the electrochemical behaviors on the detection of heavy metal ions (HMIs) would largely rely on the exposed facets of SnO 2 nanoparticles. Compared to the high-energy {221} facet, the low-energy {110} facet of SnO 2 possessed better electrochemical performance. The adsorption/desorption tests, density-functional theory (DFT) calculations, and X-ray absorption fine structure (XAFS) studies showed that the lower barrier energy of surface diffusion on {110} facet was critical for the superior electrochemical property, which was favorable for the ions diffusion on the electrode, and further leading the enhanced electrochemical performance. Through the combination of experiments and theoretical calculations, a reliable interpretation of the mechanism for electroanalysis of HMIs with nanomaterials exposed by different crystal facets has been provided. Furthermore, it provides a deep insight into understanding the key factor to improve the electrochemical performance for HMIs detection, so as to design high-performance electrochemical sensors.

  19. Direct observation of radial distribution change during tensile deformation of metallic glass by high energy X-ray diffraction method

    Energy Technology Data Exchange (ETDEWEB)

    Nasu, Toshio, E-mail: nasu@kekexafs.kj.yamagata-u.ac.j [Faculty of Education, Arts and Science, Yamagata University, 1-4-12 Kojirakawa, Yamagata, Yamagata, 990-8560 (Japan); Sasaki, Motokatsu [Faculty of Education, Arts and Science, Yamagata University, 1-4-12 Kojirakawa, Yamagata, Yamagata, 990-8560 (Japan); Usuki, Takeshi; Sekine, Mai [Faculty of Science, Yamagata University, Yamagata 990-8560 (Japan); Takigawa, Yorinobu; Higashi, Kenji [Graduate School of Engineering, Osaka Prefecture University, Sakai 599-8531 (Japan); Kohara, Shinji [Japan Synchrotron Radiation Research Institute, Harima Science Garden City, Sayo town, Hyogo 679-5198 (Japan); Sakurai, Masaki; Wei Zhang; Inoue, Akihisa [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan)

    2009-08-26

    The purpose of this research is to investigate the micro-mechanism of deformation behavior of metallic glasses. We report the results of direct observations of short-range and medium-range structural change during tensile deformation of metallic glasses by high energy X-ray diffraction method. Cu{sub 50}Zr{sub 50} and Ni{sub 30}Zr{sub 70} metallic glass samples in the ribbon shape (1.5 mm width and 25 mum) were made by using rapid quenching method. Tensile deformation added to the sample was made by using special equipment adopted for measuring the high energy X-ray diffraction. The peaks in pair distribution function g(r) for Cu{sub 50}Zr{sub 50} and N{sub 30}iZr{sub 70} metallic glasses move zigzag into front and into rear during tensile deformation. These results of direct observation on atomic distribution change for Cu{sub 50}Zr{sub 50} and Ni{sub 30}Zr{sub 70} metallic glass ribbons during tensile deformation suggest that the micro-relaxations occur.

  20. Heavy metal in sediments of Ziya River in northern China: distribution, potential risks, and source apportionment.

    Science.gov (United States)

    Zhu, Xiaolei; Shan, Baoqing; Tang, Wenzhong

    2016-12-01

    The concentration partitioning between the sediment particle and the interstitial water phase plays an important role in controlling the toxicity of heavy metals in aquatic systems. The aim of this study was to assess the sediment quality in a polluted area of the Ziya River, Northern China. The contamination potential and bioavailability of six metals were determined from the concentrations of total metals and the bioavailable fractions. The results showed that the concentrations of Cr, Cu, Ni, Zn, and Pb exceeded the probable effect concentration at several sites. The high geoaccumulation indices showed that the sediments were seriously contaminated by Cd. The ratio of acid-volatile sulfide (AVS) to simultaneously extracted metal (SEM) was higher than 1, which indicated that the availability of metals in sediments was low. The risk assessment of interstitial waters confirmed that there was little chance of release of metals associated with acid-volatile sulfide into the water column. Values of the interstitial water criteria toxicity unit indicated that none of the concentrations of the studied metals exceeded the corresponding water quality thresholds of the US Environmental Protection Agency. Positive matrix factorization showed that the major sources of metals were related to anthropogenic activities. Further, if assessments are based on total heavy metal concentrations, the toxicity of heavy metals in sediment may be overestimated.

  1. Heavy metal distributions in Peru Basin surface sediments in relation to historic, present and disturbed redox environments

    Science.gov (United States)

    Koschinsky, Andrea

    Heavy metal distributions in deep-sea surface sediments and pore water profiles from five areas in the Peru Basin were investigated with respect to the redox environment and diagenetic processes in these areas. The 10-20-cm-thick Mn oxide-rich and minor metal-rich top layer is underlain by an increase in dissolved Mn and Ni concentrations resulting from the reduction of the MnO 2 phase below the oxic zone. The mobilised associated metals like Co, Zn and Cu are partly immobilised by sorption on clay, organic or Fe compounds in the post-oxic environment. Enrichment of dissolved Cu, Zn, Ni, Co, Pb, Cd, Fe and V within the upper 1-5 cm of the oxic zone can be attributed to the degradation of organic matter. In a core from one area at around 22-25 cm depth, striking enrichments of these metals in dissolved and solid forms were observed. Offset distributions between oxygen penetration and Mn reduction and the thickness of the Mn oxide-rich layer indicate fluctuations of the Mn redox boundary on a short-term time scale. Within the objectives of the German ATESEPP research programme, the effect of an industrial impact such as manganese nodule mining on the heavy metal cycle in the surface sediment was considered. If the oxic surface were to be removed or disturbed, oxygen would penetrate deep into the formerly suboxic sediment and precipitate Mn 2+ and metals like Ni and Co which are preferably scavenged by MnO 2. The solid enrichments of Cd, V, and other metals formed in post-oxic environments would move downward with the new redox boundary until a new equilibrium between oxygen diffusion and consumption is reached.

  2. Investigation of exposure rates and radionuclide and trace metal distributions along the Hanford Reach of the Columbia River

    International Nuclear Information System (INIS)

    Cooper, A.T.; Woodruff, R.K.

    1993-09-01

    Studies have been conducted to investigate exposure rates, and radionuclide and trace metal distributions along the Columbia River where it borders the Hanford Site. The last major field study was conducted in 1979. With recently renewed interest in various land use and resource protection alternatives, it is important to have data that represent current conditions. Radionuclides and trace metals were surveyed in Columbia River shoreline soils along the Hanford Site (Hanford Reach). The work was conducted as part of the Surface Environmental Surveillance Project, Pacific Northwest Laboratory. The survey consisted of taking exposure rate measurements and soil samples primarily at locations known or expected to have elevated exposure rates

  3. NEW RARE EARTH ELEMENT ABUNDANCE DISTRIBUTIONS FOR THE SUN AND FIVE r-PROCESS-RICH VERY METAL-POOR STARS

    International Nuclear Information System (INIS)

    Sneden, Christopher; Lawler, James E.; Den Hartog, Elizabeth A.; Cowan, John J.; Ivans, Inese I.

    2009-01-01

    We have derived new abundances of the rare earth elements Pr, Dy, Tm, Yb, and Lu for the solar photosphere and for five very metal-poor, neutron-capture r-process-rich giant stars. The photospheric values for all five elements are in good agreement with meteoritic abundances. For the low-metallicity sample, these abundances have been combined with new Ce abundances from a companion paper, and reconsideration of a few other elements in individual stars, to produce internally consistent Ba, rare earth, and Hf (56 ≤ Z ≤ 72) element distributions. These have been used in a critical comparison between stellar and solar r-process abundance mixes.

  4. Hazardous Heavy metal distribution in Dahuofang catchment, Fushun, Liaoning, an important industry city in China: a case study

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Gang [State Key Laboratory of Urban and Regional Ecology, Research Center for Eco-environmental Sciences, Chinese Academy of Sciences, Bejing (China); The CAS/Shandong Provincial Key Laboratory of Coastal Environmental Process, Yantai Institute of Coastal Zone Research, Yantai Institute of Costal Zone Research, Chinese Academy of Sciences, Yantai (China); Wu, Ji-You [State Key Laboratory of Urban and Regional Ecology, Research Center for Eco-environmental Sciences, Chinese Academy of Sciences, Bejing (China); Graduate University of Chinese Academy of Sciences, Beijing (China); Shao, Hong-Bo [The CAS/Shandong Provincial Key Laboratory of Coastal Environmental Process, Yantai Institute of Coastal Zone Research, Yantai Institute of Costal Zone Research, Chinese Academy of Sciences, Yantai (China); Institute for Life Sciences, Qingdao University of Science and Technology (QUST), Qingdao (China)

    2012-12-15

    Located in Liaoning Province, one of the traditional heavy industrial areas in China, Dahuofang Reservoir provides drinking water for nearly 30 000 000 citizens, as well as industrial and agricultural water for dozens of several cities and rural areas. The distribution of hazardous heavy metals is described in several types of soil, crops, and in different industrial or mining areas and main sewage irrigation areas. Five possible reasons that may cause the pollution are analyzed and listed. Also we provide some pragmatic suggestions for the remediation of heavy metals in contaminated soils. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  5. Theoretical analysis of nuclear reactors (Phase I), I-V, Part V, Determining the fine flux distribution; Razrada metoda teorijske analize nuklearnih reaktora (I faza) I-V, V Deo, Odredjivanje fine raspodele fluksa

    Energy Technology Data Exchange (ETDEWEB)

    Pop-Jordanov, J [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

    1962-07-15

    Mono energetic neutron transport equation was solved by Carlson numerical method in cylindrical geometry. S{sub n} code was developed for the digital computer ZUSE Z23. Neutron flux distribution was determined for the RA reactor cell by applying S{sub 4} approximation. Reactor cell was treated as D{sub 2}O-U-D{sub 2}O system. Time of iteration was 185 s. Resena je transportna monoenergetska jednacina numerickom metodom Carlsona u cilindricnoj geometriji. Razvijanje S{sub n} kod za digitalnu masinu ZUSE-Z 23. Odredjena je raspodela fluksa u celiji reaktora RA S{sub 4} aproksimacijom. Celija je tretirana kao D{sub 2}O-U-D{sub 2}O. Vreme iteracije je 185 sec (author)

  6. Air quality in the Kootenays: fine particulate (PM{sub 1}0) airborne metals and sulphur dioxide levels, 1993-1999

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-09-01

    Air quality monitoring data collected in the Kootenays over a seven year period from 1993 to 1999 are summarized in an effort to inform the public about air quality in the Kootenays and to assist them in understanding air quality monitoring results. Data includes hourly (TEOM) and weekly (NAPS) data for particulate matter (PM{sub 1}0) airborne metals (arsenic, cadmium, lead and zinc) and sulphur dioxide. Analysis of monitoring data showed that particulate matter levels remained constant in most communities, with Johnson Lake and Slocan reporting the lowest levels, while Golden had the highest values during this period. Trail-Butler Park showed a clear declining trend in PM{sub 1}0. Airborne metals and sulphur dioxide levels have decreased in the Kootenays during the seven year period, with only occasional exceedances of both Level A and B air quality objectives in some communities. The report includes a detailed description of the sampling methodology and the analyzed results for PM{sub 1}0, airborne metals and sulphur dioxide for 10 communities in the region. 6 refs., 1 tab., 16 figs., 1 map.

  7. Theoretical analysis of nuclear reactors (Phase II), I-V, Part V, Determining the fine neutron flux distribution by Pn method; Razrada metoda teorijske analize nuklearnih reaktora (II faza) I-V, V Deo, Odredjivanje fine raspodele fluksa Pn metodom

    Energy Technology Data Exchange (ETDEWEB)

    Pop-Jordanov, J [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

    1962-10-15

    Expression for spherical harmonic moments were applied. They were obtained by spherical harmonics expansion of monoenergetic transport equation. This report presents the procedure for calculating the neutron flux distribution in the nine-zone reactor cell of the RA reactor in Vinca. The procedure was modelled for digital computer ZUSE Z-23 by expansion of the diagram of the automated P{sub 3} code, which is adequate for P{sub n} code with minor changes. The needed subroutines were developed. The most important ones were those for modified first and second order Bessel functions of n-th order. Computer Z-23 was operating only 15 hours during three months, and thus only the subroutines for modified Bessel functions could be tested and the obtained results were excellent. For the mentioned reason the neutron flux distribution will be calculated in the forthcoming period. Koriscen je izraz za svernoharmonicne momente koji se dobija razvijanjem monoenergetske transportne jednacine u sverne harmonike. Dat je postupak za odredjivanje raspodele neutronskog fluksa u devet medijalnoj celiji reaktora RA u Vinci. Gornji postupak je logicki organizovan na digitalnoj masini ZUSE Z-23 razvijanjem tekuceg dijagrama automatskog P{sub 3} koda, koji sa malim izmenama odgovara Pn kodu. Razvijene su potrebne osnovne subrutine, medju kojima su najznacajnije one za modificirane Beselove funkcije prve i druge vrste n - tog reda. Masina ZUSE Z-23 bila je u radu svega 15 zasova u toku tri meseca, te sam stigao da testiram samo subrutine za modificirane Beselove funkcije koje su dale odlicne rezultate. Iz ovoga razloga nije se mogla dobiti trazena raspodela fluksa. To ce biti ucinjeno u narednom periodu posto cemo moci koristiti masinu Z-23 (author)

  8. PANCHROMATIC HUBBLE ANDROMEDA TREASURY. XII. MAPPING STELLAR METALLICITY DISTRIBUTIONS IN M31

    Energy Technology Data Exchange (ETDEWEB)

    Gregersen, Dylan; Seth, Anil C. [Department of Physics and Astronomy, University of Utah, Salt Lake City, UT 84112 (United States); Williams, Benjamin F.; Dalcanton, Julianne J.; Johnson, L. C.; Lewis, Alexia R. [Department of Astronomy, Box 351580, University of Washington, Seattle, WA 98195 (United States); Lang, Dustin [McWilliams Center for Cosmology, Department of Physics, Carnegie Mellon University, Pittsburgh, PA 15213 (United States); Girardi, Leó [Osservatorio Astronomico di Padova—INAF, Vicolo dell’Osservatori 5, I-35122 Padova (Italy); Skillman, Evan D. [Minnesota Institute for Astrophysics, University of Minnesota, Minneapolis, MN 55455 (United States); Bell, Eric [Department of Astronomy, University of Michigan, 500 Church Street, Ann Arbor, MI 48109 (United States); Dolphin, Andrew E. [Raytheon, 1151 E. Hermans Road, Tucson, AZ 85706 (United States); Fouesneau, Morgan [MPIA, Koenigstuhl 17, D-69117 Heidelberg (Germany); Guhathakurta, Puragra; Hamren, Katherine M. [UCO/Lick Observatory, University of California at Santa Cruz, 1156 High Street, Santa Cruz, CA 95064 (United States); Kalirai, Jason [Department of Physics and Astronomy, Johns Hopkins University, 3400 North Charles Street, Baltimore, MD 21218 (United States); Monachesi, Antonela [MPA, Garching (Germany); Olsen, Knut, E-mail: dylan.gregersen@utah.edu, E-mail: aseth@astro.utah.edu [NOAO, Tucson, AZ 85719 (United States)

    2015-12-15

    We present a study of spatial variations in the metallicity of old red giant branch stars in the Andromeda galaxy. Photometric metallicity estimates are derived by interpolating isochrones for over seven million stars in the Panchromatic Hubble Andromeda Treasury (PHAT) survey. This is the first systematic study of stellar metallicities over the inner 20 kpc of Andromeda’s galactic disk. We see a clear metallicity gradient of −0.020 ± 0.004 dex kpc{sup −1} from ∼4–20 kpc assuming a constant red giant branch age. This metallicity gradient is derived after correcting for the effects of photometric bias and completeness and dust extinction, and is quite insensitive to these effects. The unknown age gradient in M31's disk creates the dominant systematic uncertainty in our derived metallicity gradient. However, spectroscopic analyses of galaxies similar to M31 show that they typically have small age gradients that make this systematic error comparable to the 1σ error on our metallicity gradient measurement. In addition to the metallicity gradient, we observe an asymmetric local enhancement in metallicity at radii of 3–6 kpc that appears to be associated with Andromeda’s elongated bar. This same region also appears to have an enhanced stellar density and velocity dispersion.

  9. Chemical activation of molecules by metals: Experimental studies of electron distributions and bonding

    International Nuclear Information System (INIS)

    Lichtenberger, D.L.

    1991-10-01

    The formal relationship between measured molecular ionization energies and thermodynamic bond dissociation energies has been developed into a single equation which unifies the treatment of covalent bonds, ionic bonds, and partially ionic bonds. This relationship has been used to clarify the fundamental thermodynamic information relating to metal-hydrogen, metal-alkyl, and metal-metal bond energies. We have been able to obtain a direct observation and measurement of the stabilization energy provided by the agostic interaction of the C-H bond with the metal. The ionization energies have also been used to correlate the rates of carbonyl substitution reactions of (η 5 -C 5 H 4 X)Rh(CO) 2 complexes, and to reveal the electronic factors that control the stability of the transition state. The extent that the electronic features of these bonding interactions transfer to other chemical systems is being investigated in terms of the principle of additivity of ligand electronic effects. Specific examples under study include metal- phosphines, metal-halides, and metallocenes. Especially interesting has been the recent application of these techniques to the characterization of the soccer-ball shaped C 60 molecule, buckminsterfullerene, and its interaction with a metal surface. The high-resolution valence ionizations in the gas phase reveal the high symmetry of the molecule, and studies of thin films of C 60 reveal weak intermolecular interactions. Scanning tunneling and atomic force microscopy reveal the arrangement of spherical molecules on gold substrates, with significant delocalization of charge from the metal surface. 21 refs

  10. THE DISTRIBUTION OF COMMERCIAL CROWN ETHER DC18C6 AND THE EXTRACTION STUDY OF ALKALI AND EARTH ALKALI METALS

    Directory of Open Access Journals (Sweden)

    Bambang Rusdiarso

    2010-06-01

    Full Text Available Distribution of A and B isomers of crown-ether DC18C6 on their organic and water phases (chloride, nitrate and sulphocyanide salts and extraction of alkali and earth alkali metals has been studied. In LiCl 0.1 M environment, lithium extraction could be ignored. The presence of extracted potassium metal may affect the crown ether DC18C6 distribution albeit only a little. In KNO3 0.1 M environment, the distribution coefficient values (d were 6.1 and 10.3 for A and B isomers, respectively ; while in KCl  0.1 M environment the values were 4.9 and 11.8, respectively. In KSCN 0.1 M, d values for A and B isomers were 40.4 and 36.6, respectively, which were higher than the value obtained from both KNO3 and KCl  0.1 M environments. Caesium metal extraction using DC18C6 occurred weakly, up to only 5%. Strontium extraction using DC18C6 achieved better yield than the caesium extraction. The percentage of extraction increased under organic solvent according to the following: toluene (4% < chloroform (28% < TBP (35%.   Keywords: distribution, crown-ether DC18C6, extraction.

  11. The metallicity distribution of H I systems in the EAGLE cosmological simulations

    Science.gov (United States)

    Rahmati, Alireza; Oppenheimer, Benjamin D.

    2018-06-01

    The metallicity of strong H I systems, spanning from damped Lyman α absorbers (DLAs) to Lyman-limit systems (LLSs), is explored between z = 5 → 0 using the EAGLE high-resolution cosmological hydrodynamic simulation of galaxy formation. The metallicities of LLSs and DLAs steadily increase with time in agreement with observations. DLAs are more metal rich than LLSs, although the metallicities in the LLS column density range (N_{H I }≈ 10^{17}-10^{20} cm^{-2}) are relatively flat, evolving from a median H I-weighted metallicity of {Z}≲ 10^{-2} Z_{⊙} at z = 3 to ≈10-0.5 Z⊙ by z = 0. The metal content of H I systems tracks the increasing stellar content of the Universe, holding ≈ 5 {per cent} of the integrated total metals released from stars at z = 0. We also consider partial LLS (pLLS, N_{H I}≈ 10^{16}-10^{17} cm^{-2}) metallicities, and find good agreement with Wotta et al. for the fraction of systems above (37 per cent) and below (63 per cent) 0.1 Z⊙. We also find a large dispersion of pLLS metallicities, although we do not reproduce the observed metallicity bimodality and instead we make the prediction that a larger sample will yield more pLLSs around 0.1 Z⊙. We underpredict the median metallicity of strong LLSs, and predict a population of Z 3 that are not observed, which may indicate more widespread early enrichment in the real Universe compared to EAGLE.

  12. Effect of Grain Boundary Character Distribution on the Impact Toughness of 410NiMo Weld Metal

    DEFF Research Database (Denmark)

    Divya, M.; Das, Chitta Ranjan; Chowdhury, Sandip Ghosh

    2016-01-01

    Grain boundary character distributions in 410NiMo weld metal were studied in the as-welded, first-stage, and second-stage postweld heat treatment (PWHT) conditions, and these were correlated with the Charpy-V impact toughness values of the material. The high impact toughness values in the weld...... metal in the as-welded and first-stage PWHT conditions compared to that in the second-stage condition are attributed to the higher fraction of low-energy I pound boundaries. A higher volume fraction of retained austenite and coarser martensite after second-stage PWHT accompanied by the formation...... in the impact toughness. In addition to this, grain refinement during 4-hour PWHT in the second stage also increased the toughness of the weld metal....

  13. The distribution of some rare metals in the process of separation of organic matter from Estonian dictyonema argillite

    International Nuclear Information System (INIS)

    Palvadre, R.; Ahelik, V.

    1993-01-01

    The distribution of rare metals Mo, U and V in the process of separation of organic matter from Maardu and Toolse argillite s is discussed. The beneficiation process of argillite consists of the hydro cycling treatment, in the course of which organic matter is separated as a light fraction, followed by direct flotation of organic matter and pyrite concentrates. Determinations of Mo and U were made by X-ray fluorescence, V by titration and pyrite by titration of iron. It can be concluded that rare metals Mo, U and V were concentrating in organic matter, their recovery in pyrite and quartz was negligible, depending on the degree of pyrite separation. The recovery of rare metals, especially that of V in the mineral phase, was more considerable in the processing of Maardu argillite, whose content of clay minerals was higher than that of Toolse argillite. 4 tabs., 6 refs

  14. Spatial distribution of trace metals in water resources impacted by PGM activities

    CSIR Research Space (South Africa)

    Walters, Chavon R

    2012-05-01

    Full Text Available the aquatic environment from natural and anthropogenic sources (such as industrial effluents and mining wastes). Trace metals can accumulate in fish (which are often at the top of the aquatic food chain) either through water or the food chain (1), and metals...

  15. Metals distribution in Kumkol deposit petroleum; Raspredelenie metallov v nefti Kumkol`skogo mestorozhdeniya

    Energy Technology Data Exchange (ETDEWEB)

    Musaeva, Z G; Nadirov, A N; Ajdarbaev, A S

    1997-11-04

    Metals content in samples of Kumkol deposit petroleum is determined by the method of X-ray diffraction and neutron activation analysis. Specific consideration was devoted to nickel and vanadium. It is possible, that sources of these metals are various petroleum formation as well as both the absorbed or the got in stratum microelements. (author) 10 refs., 1 tab. Suppl. Neft` i gaz Kazakhstana

  16. Altitudinal patterns and controls of trace metal distribution in soils of a remote high mountain, Southwest China.

    Science.gov (United States)

    Li, Rui; Bing, Haijian; Wu, Yanhong; Zhou, Jun; Xiang, Zhongxiang

    2018-02-01

    The aim of this study is to reveal the effects of regional human activity on trace metal accumulation in remote alpine ecosystems under long-distance atmospheric transport. Trace metals (Cd, Pb, and Zn) in soils of the Mt. Luoji, Southwest China, were investigated along a large altitudinal gradient [2200-3850 m above sea level (a.s.l.)] to elaborate the key factors controlling their distribution by Pb isotopic composition and statistical models. The concentrations of Cd, Pb, and Zn in the surface soils (O and A horizons) were relatively low at the altitudes of 3500-3700 m a.s.l. The enrichment factors of trace metals in the surface soils increased with altitude. After normalization for soil organic matter, the concentrations of Cd still increased with altitude, whereas those of Pb and Zn did not show a clear altitudinal trend. The effects of vegetation and cold trapping (CTE) (pollutant enrichment by decreasing temperature with increasing altitude) mainly determined the distribution of Cd and Pb in the O horizon, whereas CTE and bedrock weathering (BW) controlled that of Zn. In the A horizon, the distribution of Cd and Pb depended on the vegetation regulation, whereas that of Zn was mainly related to BW. Human activity, including ores mining and fossil fuels combustion, increased the trace metal deposition in the surface soils. The anthropogenic percentage of Cd, Pb, and Zn quantified 92.4, 67.8, and 42.9% in the O horizon, and 74.5, 33.9, and 24.9% in the A horizon, respectively. The anthropogenic metals deposited at the high altitudes of Mt. Luoji reflected the impact of long-range atmospheric transport on this remote alpine ecosystem from southern and southwestern regions.

  17. [Study on distribution of five heavy metal elements in different parts of Cordyceps sinensis by microwave digestion ICP-MS].

    Science.gov (United States)

    Zhou, Li; Hao, Qing-Xiu; Wang, Sheng; Yang, Quan; Kang, Chuan-Zhi; Yang, Wan-Zhen; Guo, Lan-Ping

    2017-08-01

    The contents of five heavy metals (Cu, Pb, As, Cd, Hg) in 17 batches of Cordyceps sinensis were determined by microwave digestion-ICP-MS, and their distribution in C. sinensis were analyzed. The results showed that the contents of Cu, Pb, Cd and Hg in all batches were in accordance with the international standards of Chinese Medicine-Chinese Herbal Medicine Heavy Metal Limit, with their contents in the stroma higher than that in the caterpillar body, and the excess rate of As, which mainly concentrated in the caterpillar body part of C. sinensis, was 88.24%, as the content of As in the caterpillar body was 7 to 12 fold of that in the stroma. In this study, the distribution of five heavy metals in C. sinensis was clarified, and the existing problems of arsenic limit of heavy metal in C. sinensis were analyzed, and some suggestions were put forward. It is hoped that the reference standard can be provided for the limited standard of arsenic in C. sinensis. Copyright© by the Chinese Pharmaceutical Association.

  18. The Eating Habits of Milky Way-mass Halos: Destroyed Dwarf Satellites and the Metallicity Distribution of Accreted Stars

    Science.gov (United States)

    Deason, Alis J.; Mao, Yao-Yuan; Wechsler, Risa H.

    2016-04-01

    We study the mass spectrum of destroyed dwarfs that contribute to the accreted stellar mass of Milky Way (MW)-mass (Mvir ˜ 1012.1 M⊙) halos using a suite of 45 zoom-in dissipationless simulations. Empirical models are employed to relate (peak) subhalo mass to dwarf stellar mass, and we use constraints from z = 0 observations and hydrodynamical simulations to estimate the metallicity distribution of the accreted stellar material. The dominant contributors to the accreted stellar mass are relatively massive dwarfs with Mstar ˜ 108-1010M⊙. Halos with more quiescent accretion histories tend to have lower mass progenitors (108-109 M⊙), and lower overall accreted stellar masses. Ultra-faint mass (Mstar 108 M⊙ can contribute a considerable fraction (˜20%-60%) of metal-poor stars if their metallicity distributions have significant metal-poor tails. Finally, we find that the generic assumption of a quiescent assembly history for the MW halo seems to be in tension with the mass spectrum of its surviving dwarfs. We suggest that the MW could be a “transient fossil” a quiescent halo with a recent accretion event(s) that disguises the preceding formation history of the halo.

  19. Distributions and contamination assessment of heavy metals in the surface sediments of western Laizhou Bay: Implications for the sources and influencing factors.

    Science.gov (United States)

    Zhang, Pan; Hu, Rijun; Zhu, Longhai; Wang, Peng; Yin, Dongxiao; Zhang, Lianjie

    2017-06-15

    Heavy metals (Cu, Pb, Cr, Cd and As) contents in surface sediments from western Laizhou Bay were analysed to evaluate the spatial distribution pattern and their contamination level. As was mainly concentrated in the coastal area near the estuaries and the other metals were mainly concentrated in the central part of the study area. The heavy metals were present at unpolluted levels overall evaluated by the sediment quality guidelines and geoaccumulation index. Principal component analysis suggest that Cu, Pb and Cd were mainly sourced from natural processes and As was mainly derived from anthropogenic inputs. Meanwhile, Cr originated from both natural processes and anthropogenic contributions. Tidal currents, sediments and human activities were important factors affecting the distribution of heavy metals. The heavy metal environment was divided into four subareas to provide a reference for understanding the distribution and pollution of heavy metals in the estuary-bay system. Copyright © 2017 Elsevier Ltd. All rights reserved.

  20. Distribution of stable and radioactive metals among the biomass compartments of the macrophytes of the Yenisei river and estimation of the dose rate

    International Nuclear Information System (INIS)

    Zotina, T.A.; Bolsunovskiy, A.Ya.; Sukovatyj, A.G.

    2008-01-01

    Artificial radioactive metals are annually detected in the biomass of submerged macrophytes in the zone radioactive contamination of the Yenisei river. It has been shown by other authors that metals are not uniformly distributed in the biomass of aquatic macrophytes. In this research the distribution of stable and radioactive isotopes of metals was investigated among the biomass compartments of the macrophytes from the Yenisei river with chemical fractionation technique. Dose rates from the intra- and extracellular radionuclides have been estimated. According to the data obtained the distribution of metals among intra- and extracellular compartments was different. The major portion of Co, Mn and Zn was accumulated in the biomass in more mobile form, than Cr and Fe. Artificial radioactive isotopes were detected in the same compartments as stable metals. Essential portion of artificial radionuclides and stable metals was detected in the particles of seston, attached to the surface of the macrophytes.

  1. Comparison of the stress distribution in the metallic layers of flexible pipes using two alternative Bflex formulations

    OpenAIRE

    Shi, Yunzhu

    2014-01-01

    Axisymmetric load is the most common load acting on flexible pipe. Modelling axisymmetric load correctly is very important to estimate the strength of a flexible pipe. The purpose of the thesis is to compare the stress distribution in metallic layers under three load case, i.e. tension, internal pressure and external pressure. Literature study and discussion to mechanical properties of flexible pipe and finite element modelling method are included in the thesis. The modelling program is BFLEX...

  2. Marine lake as in situ laboratory for studies of organic matter influence on speciation and distribution of trace metals

    Science.gov (United States)

    Mlakar, Marina; Fiket, Željka; Geček, Sunčana; Cukrov, Neven; Cuculić, Vlado

    2015-07-01

    Karst marine lakes are unique marine systems, also recognized as in situ "laboratories" in which geochemical processes on a different scale compared to the open sea, can be observed. In this study, organic matter cycle and its impact on distribution of trace metals in the marine lake Mir, located on Dugi Otok Island, in the central part of the eastern Adriatic Sea, was investigated for the first time. Studied marine lake is small, isolated, shallow basin, with limited communication with the open sea. Intense spatial and seasonal variations of organic matter, dissolved and particulate (DOC, POC), and dissolved trace metals concentrations in the water column of the Lake are governed predominantly by natural processes. Enhanced oxygen consumption in the Lake during summer season, high DOC and POC concentrations and low redox potential result in occasional occurrence of anoxic conditions in the bottom layers with appearance of sulfur species. Speciation modeling showed that dissolved trace metals Cu, Pb and Zn, are mostly bound to organic matter, while Cd, Co and Ni are present predominantly as free ions and inorganic complexes. Trace metals removal from the water column and their retention in the sediment was found to depend on the nature of the relationship between specific metal and organic or inorganic phases, sulfides, Fe-oxyhydroxydes or biogenic calcite. The above is reflected in the composition of the sediments, which are, in addition to influence of karstic background and bathymetry of the basin, significantly affected by accumulation of detritus at the bottom of the Lake.

  3. Speciation and distribution characteristics of heavy metals and pollution assessments in the sediments of Nashina Lake, Heilongjiang, China.

    Science.gov (United States)

    Li, Miao; Zang, Shuying; Xiao, Haifeng; Wu, Changshan

    2014-05-01

    Sediment core samples from Nashina Lake, Heilongjiang, China were collected using a gravity sampler. The cores were sliced horizontally at 1 cm each to determine the particle size, total concentrations and speciation of Cd, Cr, Cu, Mn, Ni, Pb, and Zn. Total concentrations of heavy metals were extracted using an acid mixture (containing hydro fluoric acid, nitric acid, and sulphuric acid) and analyzed using an inductively coupled plasma spectrometry. A sequential extraction procedure was employed to separate chemical species. Analysis of results indicate that the concentrations of heavy metals in the sediments of Nashina Lake in descending order are Mn, Cr, Zn, Pb, Ni, Cu, and Cd. The ratios of the average concentrations of four heavy metals (e.g.Cr, Cu, Ni, Zn) to their background values were >1; and those of Mn, Cd, and Pb were >1. Moreover, some toxic metals were mainly distributed in bioavailable fractions. For instance, both Cd and Mn were typically found in Acid-extractable species or Fe-Mn oxide species, and thus can be easily remobilized and enter the food chain. Finally, the analysis of geo-accumulation index showed that anthropogenic pollution levels of Cr, Cu, Mn, Ni, Zn were low, but those of Pb and Cd were at the moderate level. As both Pb and Cd are toxic metals, it is highly necessary to prohibit their transformation and accumulation in the sediments.

  4. Spatial distribution and risk assessment of heavy metals and As pollution in the sediments of a shallow lake.

    Science.gov (United States)

    Deng, Jiancai; Wang, Yuansheng; Liu, Xin; Hu, Weiping; Zhu, Jinge; Zhu, Lin

    2016-05-01

    The concentrations and spatial distributions of eight heavy metals in surface sediments and sediment core samples from a shallow lake in China were investigated to evaluate the extent of the contamination and potential ecological risks. The results showed that the heavy metal concentrations were higher in the northern and southwestern lake zones than those in the other lake zones, with lower levels of As, Hg, Zn, Cu, Pb, Cr, and Ni primarily observed in the central and eastern lake regions and Cd primarily confined to areas surrounding the lake. The concentrations of the eight heavy metals in the sediment profiles tended to decrease with increasing sediment depth. The contents of Ni, Cu, Zn, Pb, and Cd in the surface sediment were approximately 1.23-18.41-fold higher than their background values (BVs), whereas the contents of Cr, As, and Hg were nearly identical to their BVs. The calculated pollution load index (PLI) suggested that the surface sediments of this lake were heavily polluted by these heavy metals and indicated that Cd was a predominant contamination factor. The comprehensive potential ecological risk index (PERI) in the surface sediments ranged from 99.2 to 2882.1, with an average of 606.1. Cd contributed 78.7 % to the PERI, and Hg contributed 8.4 %. Multivariate statistical analyses revealed that the surface sediment pollution with heavy metals mainly originated from industrial wastewater discharged by rivers located in the western and northwestern portion of the lake.

  5. Spatial distribution and source identification of heavy metals in surface soils in a typical coal mine city, Lianyuan, China.

    Science.gov (United States)

    Liang, Jie; Feng, Chunting; Zeng, Guangming; Gao, Xiang; Zhong, Minzhou; Li, Xiaodong; Li, Xin; He, Xinyue; Fang, Yilong

    2017-06-01

    In this study, we investigated the pollution degree and spatial distribution of heavy metals and determined their sources in topsoil in a typical coal mine city, Lianyuan, Hunan Province, China. We collected 6078 soil surface samples in different land use types. And the concentrations of Zn, Cd, Cu, Hg, Pb, Sb, As, Mo, V, Mn, Fe and Cr were measured. The average contents of all heavy metals were lower than their corresponding Grade II values of Chinese Soil Quality Standard with the exception of Hg. However, average contents of twelve heavy metals, except for Mn, exceeded their background level in soils in Hunan Province. Based on one-way analysis of variance (ANOVA), the contents of Cu, Zn, Cd, Pb, Hg, Mo and V were related to the anthropogenic source and there were statistically significant differences in their concentrations among different land use patterns. The spatial variation of heavy metal was visualized by GIS. The PMF model was used to ascertain contamination sources of twelve heavy metals and apportion their source contributions in Lianyuan soils. The results showed that the source contributions of the natural source, atmospheric deposition, industrial activities and agricultural activities accounted for 33.6%, 26.05%, 23.44% and 16.91%, respectively. Copyright © 2017 Elsevier Ltd. All rights reserved.

  6. POPULATION EFFECTS ON THE METALLICITY DISTRIBUTION FUNCTION DERIVED FROM THE RED GIANT BRANCH

    International Nuclear Information System (INIS)

    Ordoñez, Antonio J.; Sarajedini, Ata

    2015-01-01

    We have tested the reliability of the red giant branch (RGB) as a metallicity indicator accounting for observational errors as well as the complexity of star formation histories and chemical evolution histories observed in various stellar systems. We generate model color–magnitude diagrams (CMDs) produced with a variety of evolutionary histories and compare the resultant metallicity estimates from the colors and magnitudes of RGB stars to the true input metallicities. We include realistic models for photometric errors and completeness in our synthetic CMDs. As expected, for simple simple stellar populations dominated by old stars, the RGB provides a very accurate estimate of the modular metallicity value for a population. An error in the age of a system targeted for this type of study may produce metallicity errors of a few tenths of a dex. The size of this metallicity error depends linearly on the age error, and we find this dependence to be stronger with more precise photometry. If the population has experienced any significant star formation within the last ∼6 Gyr, the metallicity estimates, [M/H], derived from the RGB may be in error by up to ∼0.5 dex. Perhaps the most important consideration for this technique is an accurate, independent estimate of the average age for the target stellar system, especially if it is probable that a significant fraction of the population formed less than ∼6 Gyr ago

  7. Distribution and source apportionment studies of heavy metals in soil of cotton/wheat fields.

    Science.gov (United States)

    Rafique, Nazia; Tariq, Saadia R

    2016-05-01

    Heavy metals enriched agricultural soils have been the subject of great concern because these metals have potential to be transferred to the soil solution and afterward accumulated in food chain. To study the trace metal persistence in crop soil, 90 representative soil samples were collected and analyzed for heavy metal (As, Cd, Cu, Fe, Mn, Ni, Pb, and Zn) and anions (chloride, nitrates, phosphates and sulfates). Cluster and factor analysis techniques were used for the source identification of these excessive heavy metal levels and ecological risk was determined with potential ecological risk assessment. The degree of enrichment of eight studied heavy metals in comparison with the corresponding background levels decreased in order: Cd > Pb > Fe > Ni > Mn > As > Cu ~ Zn. Arsenic and cadmium exhibited 1.30- and 1.64-fold exceeded levels than threshold limits set by National environment quality standards, respectively. Cd in cotton field's soil may lead to higher potential risk than other heavy metals. On overall basis, the cumulative mean potential ecological risk for the district (207.75) corresponded to moderate risk level with higher contributions from As and Pb especially from Cd. Cadmium formed strong positive correlation with phosphate content of soil at p < 0.01. Cluster analysis indicated that Cluster 1 (extremely polluted) probably originated from anthropogenic inputs of phosphate fertilizer and past usage of arsenical pesticides.

  8. Particle-size dependence on metal(loid) distributions in mine wastes: Implications for water contamination and human exposure

    Science.gov (United States)

    Kim, C.S.; Wilson, K.M.; Rytuba, J.J.

    2011-01-01

    The mining and processing of metal-bearing ores has resulted in contamination issues where waste materials from abandoned mines remain in piles of untreated and unconsolidated material, posing the potential for waterborne and airborne transport of toxic elements. This study presents a systematic method of particle size separation, mass distribution, and bulk chemical analysis for mine tailings and adjacent background soil samples from the Rand historic mining district, California, in order to assess particle size distribution and related trends in metal(loid) concentration as a function of particle size. Mine tailings produced through stamp milling and leaching processes were found to have both a narrower and finer particle size distribution than background samples, with significant fractions of particles available in a size range (???250 ??m) that could be incidentally ingested. In both tailings and background samples, the majority of trace metal(loid)s display an inverse relationship between concentration and particle size, resulting in higher proportions of As, Cr, Cu, Pb and Zn in finer-sized fractions which are more susceptible to both water- and wind-borne transport as well as ingestion and/or inhalation. Established regulatory screening levels for such elements may, therefore, significantly underestimate potential exposure risk if relying solely on bulk sample concentrations to guide remediation decisions. Correlations in elemental concentration trends (such as between As and Fe) indicate relationships between elements that may be relevant to their chemical speciation. ?? 2011 Elsevier Ltd.

  9. Distribution of heavy metals in the coastal area of Abu Dhabi in the United Arab Emirates.

    Science.gov (United States)

    Al Rashdi, Saeed; Arabi, Alya A; Howari, Fares M; Siad, Abdi

    2015-08-15

    Fifty-seven sediment samples were collected from Abu Dhabi coastal area, United Arab Emirates (UAE). The concentrations of heavy metals including antimony, arsenic, barium, cadmium, cobalt, copper, mercury, lead, molybdenum, nickel and zinc were obtained using Inductively Coupled Plasma-Mass Spectroscopy (ICP-MS) and X-ray fluorescence. Heavy metal contaminations in Abu Dhabi had increased since 2004. Nevertheless, the enrichment factors, geoaccumulation indices and the pollution load index of 0.3 showed no pollution with any of the measured metals except arsenic. Copyright © 2015 Elsevier Ltd. All rights reserved.

  10. Photoinduced charge transfer in a transition metal complex investigated by time-resolved X-ray absorption fine structure spectroscopy. Setup and experiment

    International Nuclear Information System (INIS)

    Goeries, Dennis

    2015-02-01

    In the framework of this thesis the development of a time-resolved X-ray absorption spectroscopy experiment and its application to fac-Ir(ppy) 3 is described. Such experiments require a very stable setup in terms of spatial and temporal accuracy. Therefore, the stability properties of the present installation were investigated in detail and continuously improved, in particular the synchronization of the ultrashort pulse laser system to the storage ring as well as the spatial stability of both X-ray and laser beam. Experiments utilizing the laser pump and X-ray probe configuration were applied on the green phosphorescence emitter complex fac-Ir(ppy) 3 dissolved in dimethyl sulfoxide. Structural and electronic changes were triggered by photoexcitation of the metal-to-ligand charge transfer band with ultrashort laser pulses at a wavelength of 343 nm. The excited triplet state spectrum was extracted from the measured pump-probe X-ray absorption spectrum using an ionic approximation. The results con rm the anticipated metal-to-ligand charge transfer as shown by an ionization potential shift of the iridium atom. The symmetry of the complex was found to be pseudo-octahedral. This allowed the first experimental determination of the bond length of fac-Ir(ppy) 3 in an octahedral approximation and revealed a decrease of bond length of the first coordination shell in the triplet state. The first and second-order decay kinetics of the triplet state were investigated in a combination of X-ray and laser based experiments and revealed self-quenching as well as triplet-triplet annihilation rate constants.

  11. Spatial distribution, temporal variation, and sources of heavy metal pollution in groundwater of a century-old nonferrous metal mining and smelting area in China.

    Science.gov (United States)

    Gong, Xing; Chen, Zhihua; Luo, Zhaohui

    2014-12-01

    This study first presents the spatial distribution, temporal variation, and sources of heavy metal pollution in groundwater of a nonferrous metal mine area in China. Unconfined groundwater was polluted by Pb, Zn, As, and Cu, in order, while confined karst water in the mines showed pollution in the following sequence: Zn, Cd, Cu, Pb, and As. Pollution by Pb was widespread, while Zn, As, Cu, and Cd were found to be high in the north-central industrial region and to decrease gradually with distance from smelters and tailings. Vertically, more Pb, Zn, Cu, and Cd have accumulated in shallow Quaternary groundwater, while more As have migrated into the deeper fracture groundwater in the local discharge area. Zn, Cd, and Cu concentrations in groundwater along the riverside diminished owing to reduced wastewater drainage since 1977, while samples in the confluence area were found to have increasing contents of Pb, Zn, As, Cu, and Cd since industrialization began in the 1990s. Sources of heavy metals in groundwater were of anthropogenic origin except for Cr. Pb originated primarily from airborne volatile particulates, wastewater, and waste residues and deposited continuously, while Zn, Cd, and Cu were derived from the wastewater of smelters and leakage of tailings, which corresponded to the related soil and surface residue researches. Elevated As values around factories might be the result of chemical reactions. Flow patterns in different hydrogeological units and adsorption capability of from Quaternary sediments restricted their cross-border diffusion.

  12. THE EATING HABITS OF MILKY WAY-MASS HALOS: DESTROYED DWARF SATELLITES AND THE METALLICITY DISTRIBUTION OF ACCRETED STARS

    Energy Technology Data Exchange (ETDEWEB)

    Deason, Alis J.; Mao, Yao-Yuan; Wechsler, Risa H., E-mail: adeason@stanford.edu [Kavli Institute for Particle Astrophysics and Cosmology and Physics Department, Stanford University, Stanford, CA 94305 (United States)

    2016-04-10

    We study the mass spectrum of destroyed dwarfs that contribute to the accreted stellar mass of Milky Way (MW)-mass (M{sub vir} ∼ 10{sup 12.1} M{sub ⊙}) halos using a suite of 45 zoom-in dissipationless simulations. Empirical models are employed to relate (peak) subhalo mass to dwarf stellar mass, and we use constraints from z = 0 observations and hydrodynamical simulations to estimate the metallicity distribution of the accreted stellar material. The dominant contributors to the accreted stellar mass are relatively massive dwarfs with M{sub star} ∼ 10{sup 8}–10{sup 10}M{sub ⊙}. Halos with more quiescent accretion histories tend to have lower mass progenitors (10{sup 8}–10{sup 9} M{sub ⊙}), and lower overall accreted stellar masses. Ultra-faint mass (M{sub star} < 10{sup 5} M{sub ⊙}) dwarfs contribute a negligible amount (≪1%) to the accreted stellar mass and, despite having low average metallicities, supply a small fraction (∼2%–5%) of the very metal-poor stars with [Fe/H] < −2. Dwarfs with masses 10{sup 5} < M{sub star}/M{sub ⊙} < 10{sup 8} provide a substantial amount of the very metal-poor stellar material (∼40%–80%), and even relatively metal-rich dwarfs with M{sub star} > 10{sup 8} M{sub ⊙} can contribute a considerable fraction (∼20%–60%) of metal-poor stars if their metallicity distributions have significant metal-poor tails. Finally, we find that the generic assumption of a quiescent assembly history for the MW halo seems to be in tension with the mass spectrum of its surviving dwarfs. We suggest that the MW could be a “transient fossil”; a quiescent halo with a recent accretion event(s) that disguises the preceding formation history of the halo.

  13. Spatial and temporal distribution of metals in suspended particulate matter of the Kali estuary, India

    Science.gov (United States)

    Suja, S.; Kessarkar, Pratima M.; Fernandes, Lina L.; Kurian, Siby; Tomer, Arti

    2017-09-01

    Major (Al, Fe, Mn, Ti, Mg) and trace (Cu, Zn, Pb, Cr, Ni, Co, Zr, Rb, Sr, Ba, Li, Be, Sc, V, Ga, Nb, Mo, Sn, Sb, Cs, Hf, Ta, Bi, Th, U) elements and particulate organic carbon (POC) concentrations in surface suspended particulate matter (SPM) of the Kali estuary, (central west coast of India) were studied during the pre-monsoon, monsoon and post monsoon seasons to infer estuarine processes, source of SPM and Geoaccumulation Index (Igeo) assigned pollutionIgeo levels. Distribution of SPM indicates the presence of the estuarine turbidity maximum (ETM) during all three seasons near the river mouth and a second ETM during the post monsoon time in the upstream associated with salinities gradient. The SPM during the monsoon is finer grained (avg. 53 μm), characterized by uniformly low normalized elemental concentration, whereas the post and pre monsoon are characterized by high normalized elemental concentration with coarser grain size (avg. 202 μm and 173 μm respectively) with highest ratios in the upstream estuary. The elemental composition and principal component analysis for the upstream estuary SPM support more contribution from the upstream catchment area rocks during the monsoon season; there is additional contribution from the downstream catchment area during the pre and post monsoon period due to the tidal effect. The Kali estuarine SPM has higher Al, Fe, Mn, Ti, Mg, Ni, Co, Ba, Li and V with respect to Average World River SPM (WRSPM). Igeo values for the SPM indicate Kali Estuary to be severely enriched with Mn and moderately enriched with Cu, Zn, Ni, Co, U and Mo in the upstream estuary during pre and post monsoon seasons. Seasonal changes in salinity gradient (reduced freshwater flow due to closing of the dam gates), reduced velocity at meandering region of the estuary and POC of 1.6-2.3% resulted in co-precipitation of trace elements that were further fortified by flocculation and coagulation throughout the water column resulting in metal trapping in the

  14. Seasonal Distribution of Trace Metals in Ground and Surface Water of Golaghat District, Assam, India

    Directory of Open Access Journals (Sweden)

    M. Boarh

    2010-01-01

    Full Text Available A study has been carried out on the quality of ground and surface water with respect to chromium, manganese, zinc, copper, nickel, cadmium and arsenic contamination from 28 different sources in the predominantly rural Golaghat district of Assam (India. The metals were analysed by using atomic absorption spectrometer. Water samples were collected from groundwater and surface water during the dry and wet seasons of 2008 from the different sources in 28 locations (samples. The results are discussed in the light of possible health hazards from the metals in relation to their maximum permissible limits. The study shows the quality of ground and surface water in a sizeable number of water samples in the district not to be fully satisfactory with respect to presence of the metals beyond permissible limits of WHO. The metal concentration of groundwater in the district follows the trend As>Zn>Mn>Cr>Cu>Ni>Cd in both the seasons.

  15. Distribution of Heavy Metals in the Soils Associated with the Commonly Used Pesticides in Cotton Fields

    Directory of Open Access Journals (Sweden)

    Saadia Rashid Tariq

    2016-01-01

    Full Text Available Agricultural soils contain both heavy metals and pesticides originating from various agricultural practices. It is quite important to study the relationships between these two classes of compounds. To accomplish this, 52 soil samples were collected from cotton fields and analyzed for their metal contents (Ni, Cu, Co, Pb, Cr, and Cd and levels of most commonly used pesticides (imidacloprid, acetamiprid, and emamectin. FAAS was used for metal estimation and the pesticides were determined by HPLC equipped with UV detector. The results of the study revealed slightly enhanced levels of Ni and Cd in these samples while the rest of the metals were present within tolerable range. Acetamiprid residues in soil were strongly positively correlated with Cu and negatively correlated with Cr. Similarly, imidacloprid in soil was negatively correlated with Ni. Thus it was evidenced that Cu stabilizes acetamiprid while Cr and Ni facilitate the degradation of acetamiprid and imidacloprid in the soil.

  16. Concentration distribution and potential health risk of heavy metals in Mactra veneriformis from Bohai Bay, China

    International Nuclear Information System (INIS)

    Li, Yuhu; Liu, Hui; Zhou, Hailong; Ma, Wandong; Han, Qian; Diao, Xiaoping; Xue, Qinzhao

    2015-01-01

    Highlights: • Mn was dominant in the heavy metals, followed by Zn, and Pb was the lowest. • THQs of Co were the highest at three sections and the others were less than 1. • Heavy metal concentration in clam was affected by pollution sources, and itself. • Consumer should be aware of their health risks associated with the consuming clam. - Abstract: To investigate the pollution level and evaluate the potential health risks of heavy metals, the concentrations of chromium (Cr), manganese (Mn), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), arsenic (As), selenium (Se), molybdenum (Mo), cadmium (Cd), antimony (Sb), and lead (Pb) were determined by inductively coupled plasma-mass spectrometry (ICP-MS) in 198 clams (Mactra veneriformis) collected from 11 sites of the Bohai Bay. The results showed that heavy metal concentrations in the clams were different at different sites (p < 0.05). Mn was dominant with a percentage of 22.08–77.03% in heavy metals, followed by Zn with 12.66–57.11%, and the concentration of Pb was the lowest with 0.45–1.04%. The potential health risk to consumers was evaluated by the target hazard quotient (THQ) and the maximum daily consumption rate (CR max ). The results indicated that the THQs of Co were the highest with the values of 1.125, 1.665, and 1.144 at three sections; the values of other individual metals were <1, which indicated that consumption of clams from the study areas caused health risks due to Co. Moreover, the CR max values also indicated the potential health risk caused by Co in clams consumed in this area. Pearson correlation analysis and principal component analysis (PCA) indicated that there were significantly positive or negative correlations between the heavy metals (p < 0.05), and the studied metals were divided into four groups. The results indicated that the concentrations of heavy metals in clams were affected not only by pollution sources but also by the characteristics of clams that could absorb

  17. Spatial distribution of heavy metals in soil, water, and vegetables of farms in Sanandaj, Kurdistan, Iran.

    Science.gov (United States)

    Maleki, Afshin; Amini, Hassan; Nazmara, Shahrokh; Zandi, Shiva; Mahvi, Amir Hossein

    2014-01-01

    Heavy metals are ubiquitous elsewhere in nature and their measurement in environment is necessary to develop health management strategies. In this study, we aimed to find out concentrations and spatial patterns of heavy metals in main farms of Sanandaj in Kurdistan, Iran. Over May to October 2012, six farms were selected to analyze concentrations and spatial patterns of several heavy metals, namely aluminum (Al), arsenic (As), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), nickel (Ni), lead (Pb), and zinc (Zn) in their soil, irrigation water, and edible vegetables. Overall, 36 samples of soil and water and 72 samples of vegetables including coriander (Coriandrum sativum), dill (Anethum graveolens), radish (Raphanus sativus) root and radish leaf were collected. The concentrations of metals were determined by inductively coupled plasma optical emission spectrometry. The spatial surfaces of heavy metals were created using geospatial information system. The order of metals in soil was Al > Zn > Ni > Cu > Cr > Pb > Co > As > Cd while in water it was Cr > Co > Zn > Pb > Cu > Ni > Al = As = Cd. The order of heavy metals in vegetables was Al > Zn > Cu > Cr > Ni > Pb > Co > As > Cd. Totally, the minimum concentrations of Al, Cu, Pb, and Zn were found in radish root while the maximum of Al, Co, Cr, and Ni were found in radish leaf. The minimum concentrations of Cd and Cr and maximum concentrations of Cu and Zn were also deciphered in dill. Noteworthy, coriander had the minimum concentrations of Co and Ni. The concentrations of Cr and Pb in vegetables were more than maximum allowable limits of the Food and Agriculture Organization (FAO) and the World Health Organization (WHO). In summary, albeit the concentrations of heavy metals in soil and water samples were below FAO and the WHO standards, vegetables were contaminated by chromium and lead.

  18. Pollution distribution and health risk assessment of heavy metals in indoor dust in Anhui rural, China.

    Science.gov (United States)

    Lin, Yuesheng; Fang, Fengman; Wang, Fei; Xu, Minglu

    2015-09-01

    Zn, Pb, Cu, Cr, V, Ni, Co, and As concentrations of indoor dust in Anhui rural were determined by inductively coupled plasma-optical emission spectroscopy (ICP-OES). The degrees of metal pollution in indoor dust ranked as follows: Zn > Pb > Cr > Cu > V > Ni > Co > As, on average. The arithmetic means of Zn, Pb, Cu, Cr, V, Ni, Co, and As were 427.17, 348.73, 107.05, 113.68, 52.64, 38.93, 10.29, and 4.46 mg/kg, respectively. These were higher than background values of Anhui soil for Zn, Pb, Cu, Cr, and Ni, especially for Pb with the mean value of 13.21 times the background value. Heavy metal concentrations of indoor dust were different from different rural areas. House type (bungalows or storied house), sweeping frequency, and external environment around the house (such as the road grade) affected heavy metal concentrations in indoor dust. The results of factor analysis and correlation analysis indicated that Cu, Cr, Ni, Zn, and Co concentrations were mainly due to interior paint, metal objects, and building materials. Pb and As concentrations were due to vehicle emissions. V concentration was mainly of natural source. Average daily doses for the exposure pathway of the studied heavy metals decreased in children in the following order: hand-to-mouth ingestion > dermal contact > inhalation. The non-carcinogenic risks of heavy metals ranked as Pb > V > Cr > Cu > Zn > As > Co > Ni, and the carcinogenic risks of metals decreased in the order of Cr > Co > As > Ni. The non-carcinogenic hazard indexes and carcinogenic risks of metals in indoor dust were both lower than the safe values.

  19. Study of Selected Metals Distribution, Source Apportionment, and Risk Assessment in Suburban Soil, Pakistan

    OpenAIRE

    Iqbal, Javed; Shah, Munir H.

    2015-01-01

    Composite soil samples collected from suburban areas were analyzed for Cd, Co, Cr, Cu, Fe, Mn, Pb, Sr, and Zn by atomic absorption spectrophotometry. Based on pseudototal metal analysis, Fe, Mn, Sr, and Zn were the prevailing metals while Cd, Co, Cr, and Pb were the least participants. However, based on bioavailability, Cd, Co, Pb, and Sr were easily leachable and might pose adverse effects to soil biota. In ecological risk assessment, contamination factor demonstrated moderate contamination ...

  20. PRELIMINARY RESULTS ON THE DISTRIBUTION AND SOLUBILITY OF HEAVY METALS IN URBAN AND SUBURBAN SOILS OF RAVENNA

    Directory of Open Access Journals (Sweden)

    Marina Gatti

    2009-12-01

    Full Text Available Three location types with of different environmental impacts were considered in the district of Ravenna, a city park, a suburban pinewood and arable fields. In this paper we report the preliminary results about the relationship between land use and soil management with chemical fractionation of heavy metals. The distribution and solubility of Cr, Ni, Cu, Zn, Cd and Pb was determined by water and LMWOAs extraction procedures in horizons A1 and A2 of 13 soils. In general the maximum potentially toxic element concentrations were associated with soil collected from the pinewood, and they tended to decrease with depth. The upper layer enrichment of the pinewood soils clearly revealed an anthropogenic origin of pollution. Under the pinewood, the extraction power by the single extraction procedures showed a pattern quite similar in terms of ranking of metals extracted, except that Zn and Ni were more dissolved than Cu by the use of LMWOAs. Under the pinewood, the metal levels presented a rather similar distribution pattern in terms of ranking of extractive power by the single extraction procedures, with Zn and Ni being more dissolved than Cu by the use of LMWOAs extractant. However, both readily available pools were demonstrated to be more enriched in Ni, Zn, Cd and Pb compared those of city park and arable soils. City park and arable soils had high contents of  Cu. The highest concentrations were particularly shown by the arable soil under orchard, due to frequent fungicide applications. Single extractions were compared to metals dissoved in aqua regia by bivariate correlations. By comparison, pinewood soils showed higher positive relationships between pseudo-total contents determined by aqua regia and metal concentrations from single extraction procedures than city park and arable soils. The highest correlation coefficients were found for Zn and Cd by water extraction, and for Cu and Pb by LMWOAs extraction. Both water and LMWOAs pools exhibited

  1. [Accumulation, distribution and pollution assessment of heavy metals in surface sediment of Caohai plateau wetland, Guizhou province].

    Science.gov (United States)

    Zhang, Qing-Hai; Lin, Chang-Hu; Tan, Hong; Lin, Shao-Xia; Yang, Hong-Bo

    2013-03-01

    The objective of this paper is to investigate the concentrations and distribution characteristics of heavy metals in surface sediments of different areas in the Caohai plateau wetland. 16 samples of surface sediments were collected and 7 heavy metals were analyzed. Heavy metal pollution in surface sediments of different areas in the Caohai plateau wetland was estimated by the Tomlinson Pollution Load Index (PLI) method. The analyzed results indicated that the average contents of Cd, Hg, As, Pb, Cr, Cu, Zn were 0.985, 0.345, 15.8, 38.9, 38.6, 22.8 and 384 mg x kg(-1), respectively. The heavy metal distributions varied with regional environment changes, the order of average contents of Cd and Hg in different regions was E (the eastern region) > S (the southern region) > N (the northern region), the order of the average content of Pb was N > E > S, and that of Zn was S > E > N. The results also suggested a medium heavy metal pollution level in the surface sediment of the Caohai plateau wetland with the PLI(zone) reaching 1.17. The order of pollution level in surface sediments of different regions was E > S > N. The results showed medium pollution levels in E and Hg which reached the extreme intensity pollution level were also the major polluted elements in surface sediments of the Caohai plateau wetland. And also, results showed medium pollution levels of Cd and Pb in surface sediments of Caohai plateau wetland. Cluster analysis results showed similar pollution sources of Cd, Zn, Pb and Hg, which should be attached great importance in terms of the prevention of the Caohai plateau wetland.

  2. Electron dose distributions caused by the contact-type metallic eye shield: Studies using Monte Carlo and pencil beam algorithms.

    Science.gov (United States)

    Kang, Sei-Kwon; Yoon, Jai-Woong; Hwang, Taejin; Park, Soah; Cheong, Kwang-Ho; Han, Tae Jin; Kim, Haeyoung; Lee, Me-Yeon; Kim, Kyoung Ju; Bae, Hoonsik

    2015-01-01

    A metallic contact eye shield has sometimes been used for eyelid treatment, but dose distribution has never been reported for a patient case. This study aimed to show the shield-incorporated CT-based dose distribution using the Pinnacle system and Monte Carlo (MC) calculation for 3 patient cases. For the artifact-free CT scan, an acrylic shield machined as the same size as that of the tungsten shield was used. For the MC calculation, BEAMnrc and DOSXYZnrc were used for the 6-MeV electron beam of the Varian 21EX, in which information for the tungsten, stainless steel, and aluminum material for the eye shield was used. The same plan was generated on the Pinnacle system and both were compared. The use of the acrylic shield produced clear CT images, enabling delineation of the regions of interest, and yielded CT-based dose calculation for the metallic shield. Both the MC and the Pinnacle systems showed a similar dose distribution downstream of the eye shield, reflecting the blocking effect of the metallic eye shield. The major difference between the MC and the Pinnacle results was the target eyelid dose upstream of the shield such that the Pinnacle system underestimated the dose by 19 to 28% and 11 to 18% for the maximum and the mean doses, respectively. The pattern of dose difference between the MC and the Pinnacle systems was similar to that in the previous phantom study. In conclusion, the metallic eye shield was successfully incorporated into the CT-based planning, and the accurate dose calculation requires MC simulation. Copyright © 2015 American Association of Medical Dosimetrists. Published by Elsevier Inc. All rights reserved.

  3. Global direct pressures on biodiversity by large-scale metal mining: Spatial distribution and implications for conservation.

    Science.gov (United States)

    Murguía, Diego I; Bringezu, Stefan; Schaldach, Rüdiger

    2016-09-15

    Biodiversity loss is widely recognized as a serious global environmental change process. While large-scale metal mining activities do not belong to the top drivers of such change, these operations exert or may intensify pressures on biodiversity by adversely changing habitats, directly and indirectly, at local and regional scales. So far, analyses of global spatial dynamics of mining and its burden on biodiversity focused on the overlap between mines and protected areas or areas of high value for conservation. However, it is less clear how operating metal mines are globally exerting pressure on zones of different biodiversity richness; a similar gap exists for unmined but known mineral deposits. By using vascular plants' diversity as a proxy to quantify overall biodiversity, this study provides a first examination of the global spatial distribution of mines and deposits for five key metals across different biodiversity zones. The results indicate that mines and deposits are not randomly distributed, but concentrated within intermediate and high diversity zones, especially bauxite and silver. In contrast, iron, gold, and copper mines and deposits are closer to a more proportional distribution while showing a high concentration in the intermediate biodiversity zone. Considering the five metals together, 63% and 61% of available mines and deposits, respectively, are located in intermediate diversity zones, comprising 52% of the global land terrestrial surface. 23% of mines and 20% of ore deposits are located in areas of high plant diversity, covering 17% of the land. 13% of mines and 19% of deposits are in areas of low plant diversity, comprising 31% of the land surface. Thus, there seems to be potential for opening new mines in areas of low biodiversity in the future. Copyright © 2016 Elsevier Ltd. All rights reserved.

  4. Electron dose distributions caused by the contact-type metallic eye shield: Studies using Monte Carlo and pencil beam algorithms

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Sei-Kwon; Yoon, Jai-Woong; Hwang, Taejin; Park, Soah; Cheong, Kwang-Ho; Jin Han, Tae; Kim, Haeyoung; Lee, Me-Yeon; Ju Kim, Kyoung, E-mail: kjkim@hallym.or.kr; Bae, Hoonsik

    2015-10-01

    A metallic contact eye shield has sometimes been used for eyelid treatment, but dose distribution has never been reported for a patient case. This study aimed to show the shield-incorporated CT-based dose distribution using the Pinnacle system and Monte Carlo (MC) calculation for 3 patient cases. For the artifact-free CT scan, an acrylic shield machined as the same size as that of the tungsten shield was used. For the MC calculation, BEAMnrc and DOSXYZnrc were used for the 6-MeV electron beam of the Varian 21EX, in which information for the tungsten, stainless steel, and aluminum material for the eye shield was used. The same plan was generated on the Pinnacle system and both were compared. The use of the acrylic shield produced clear CT images, enabling delineation of the regions of interest, and yielded CT-based dose calculation for the metallic shield. Both the MC and the Pinnacle systems showed a similar dose distribution downstream of the eye shield, reflecting the blocking effect of the metallic eye shield. The major difference between the MC and the Pinnacle results was the target eyelid dose upstream of the shield such that the Pinnacle system underestimated the dose by 19 to 28% and 11 to 18% for the maximum and the mean doses, respectively. The pattern of dose difference between the MC and the Pinnacle systems was similar to that in the previous phantom study. In conclusion, the metallic eye shield was successfully incorporated into the CT-based planning, and the accurate dose calculation requires MC simulation.

  5. Distribution of heavy metals in muscles and internal organs of Korean cephalopods and crustaceans: risk assessment for human health.

    Science.gov (United States)

    Mok, Jong Soo; Kwon, Ji Young; Son, Kwang Tae; Choi, Woo Seok; Shim, Kil Bo; Lee, Tae Seek; Kim, Ji Hoe

    2014-12-01

    Samples of seven species of cephalopods and crustaceans were collected from major fish markets on the Korean coast and analyzed for mercury (Hg) using a direct Hg analyzer and for the metals cadmium (Cd), lead (Pb), chromium, silver, nickel, copper, and zinc using inductively coupled plasma mass spectrometry. The distributions of heavy metals in muscles, internal organs, and whole tissues were determined, and a risk assessment was conducted to provide information concerning consumer safety. The heavy metals accumulated to higher levels (P octopus (relatively large cephalopods), red snow crab, and snow crab exceeded the European Union limits. The estimated dietary intake of Cd, Pb, and Hg for each part of all species accounted for 1.73 to 130.57%, 0.03 to 0.39%, and 0.93 to 1.67%, respectively, of the provisional tolerable daily intake adopted by the Joint Food and Agriculture Organization and World Health Organization Expert Committee on Food Additives; the highest values were found in internal organs. The hazard index (HI) is recognized as a reasonable parameter for assessing the risk of heavy metal consumption associated with contaminated food. Because of the high HI (>1.0) of the internal organs of cephalopods and the maximum HI for whole tissue of 0.424, consumers eating internal organs or whole tissues of cephalopods could be at risk of high heavy metal exposure. Therefore, the internal organs of relatively large cephalopods and crabs (except blue crab) are unfit for consumption. However, consumption of flesh after removing internal organs is a suitable approach for decreasing exposure to harmful metals.

  6. Ultra-Fine Bubble Distributions in a Plant Factory Observed by Transmission Electron Microscope with a Freeze-Fracture Replica Technique

    Directory of Open Access Journals (Sweden)

    Tsutomu Uchida

    2018-03-01

    Full Text Available Water containing ultra-fine bubbles (UFB may promote plant growth. But, as UFBs are too small to distinguish from other impurities in a nutrient solution, it is not known if UFBs survive transport from the water source to the rhizosphere. Here we use the freeze-fracture replica method and a transmission electron microscope (TEM to observe UFBs in the nutrient solutions used in a crop-growing system known as a plant factory. In this factory, TEM images taken from various points in the supply line indicate that the concentration of UFBs in the nutrient solution is conserved, starting from their addition to the nutrient solution in the buffer tank, through the peat-moss layer, all the way to the rhizosphere. Measurements also show that a thin film formed on the surface of UFBs in the nutrient solution, with greater film thickness at the rhizosphere. This film is considered to be made from the accumulation of impurities coming from solute and the peat-moss layer.

  7. Characterization of metallic micro sieves for gas purification on the example of fine dedusting of exhaust gases of wood burning firing systems; Charakterisierung metallischer Mikrosiebe zur Gasreinigung am Beispiel der Feinentstaubung von Holzfeuerungsabgasen

    Energy Technology Data Exchange (ETDEWEB)

    Stahl, Esther

    2011-07-15

    Metallic micro sieves are a promising filter media for fine particulate-removal from gas streams due to their flexible and precisely adaptable pore geometry and their material properties. A current field of application is the particle removal from exhaust gas from biomass heating appliances. The generated aerosol particles are considerably smaller than 1 {mu}m. As a consequence they pose a significant health risk. In order to promote new developments in the field of gas cleaning, this study explores the filtration characteristics of metallic micro sieves theoretically and practically. For the purpose of the design layout of micro sieve filters, the fundamental process of the filtration kinetics, that is the time-dependent development of filtration efficiency and pressure drop, were displayed in a physically based and algebraically solvable calculation model. The filtration kinetics is subdivided in three parts: The flow and the capture of particles in micro sieves (instant of time 0), the dynamic accrue of the pores due to captured particles (phase 1) and the build-up of a filter cake (phase 2). Each section was covered by the formulation of separate mathematic solutions or by further development respectively adaption of existing models. Both the section models and the total model were in good compliance with experimental results. The model as well as the experimental results were used to assess possible applications in the field of the removal of fine particulate matter from exhaust gases of wood fired heating appliances. Exemplary for a wood fired heating appliance with a heating capacity of 100 kW, the required filter surface and achievable filtration efficiencies were calculated. Due to present high particle concentrations, relatively big pore diameters between 15 and 20 {mu}m are sufficient to obtain significant filtration efficiencies above 99 % after a short operation time. Adequate micro sieve porosities of more than 5 % are available. Thus, the realization

  8. Spatial distribution of heavy metal contamination in soils near a primitive e-waste recycling site.

    Science.gov (United States)

    Quan, Sheng-Xiang; Yan, Bo; Yang, Fan; Li, Ning; Xiao, Xian-Ming; Fu, Jia-Mo

    2015-01-01

    The total concentrations of 12 heavy metals in surface soils (SS, 0-20 cm), middle soils (MS, 30-50 cm) and deep soils (DS, 60-80 cm) from an acid-leaching area, a deserted paddy field and a deserted area of Guiyu were measured. The results showed that the acid-leaching area was heavily contaminated with heavy metals, especially in SS. The mean concentrations of Ni, Cu, Zn, Cd, Sn, Sb and Pb in SS from the acid-leaching area were 278.4, 684.1, 572.8, 1.36, 3,472, 1,706 and 222.8 mg/kg, respectively. Heavy metal pollution in the deserted paddy field was mainly concentrated in SS and MS. The average values of Sb in SS and MS from the deserted paddy field were 16.3 and 20.2 mg/kg, respectively. However, heavy metal contamination of the deserted area was principally found in the DS. Extremely high concentrations of heavy metals were also observed at some special research sites, further confirming that the level of heavy metal pollution was very serious. The geoaccumulation index (Igeo) values revealed that the acid-leaching area was severely polluted with heavy metals in the order of Sb > Sn > Cu > Cd > Ni > Zn > Pb, while deserted paddy field was contaminated predominately by metals in the order of Sb > Sn > Cu. It was obvious that the concentrations of some uncommon contaminants, such as Sb and Sn, were higher than principal contaminants, such as Ni, Cu, Zn and Pb, suggesting that particular attention should be directed to Sn and Sb contamination in the future research of heavy metals in soils from e-waste-processing areas. Correlation analysis suggested that Li and Be in soils from the acid-leaching area and its surrounding environment might have originated from other industrial activities and from batteries, whereas Ni, Cu, Zn, Cd, Pb, Sn and Sb contamination was most likely caused by uncontrolled electronic waste (e-waste) processing. These results indicate the significant need for optimisation of e-waste-dismantling technologies and remediation of polluted soil

  9. Heavy metal distribution frequency in Iranian and imported rice varieties marketed in central Iran, Yazd, 2012

    Directory of Open Access Journals (Sweden)

    Reza Morekian

    2013-01-01

    Full Text Available Aims: This study aimed to determine the concentration of heavy metals including lead (Pb, cadmium (Cd, and arsenic (As in rice samples in Yazd markets. Materials and Methods: In this study, 108 rice samples were collected from 36 different brands including 26 imported and 10 Iranian rice varieties from July-December 2011. Determination of heavy metals was carried out by wet ashing and digestion methods following graphite furnace atomic absorption spectrometry and hydride generation atomic absorption spectrometry. Results: The average concentrations of lead in both Iranian and imported samples were 328.3 ± 81.44 and 254.55 ± 77.2 μg/kg, respectively, well above the safe limit set by Iranian standard, whereas mean concentrations of cadmium and arsenic were both below their permissible limit. In homemade rice samples, their concentration levels were shown to be 37.25 ± 23.39 and 33.5 ± 18.35 μg/kg, respectively. However, for imported products, their levels were 43.71 ± 13.74 and 87.55 ± 72.99 μg/kg, respectively. Conclusion: Deterministic estimation of exposure to heavy metals from rice showed that there was no health issue concerning exposure to toxic metals through rice intake in Iran when potential risk of each heavy metal is considered individually, cumulative risk assessment must be applied in future studies.

  10. Spatial distribution of heavy metals in urban dust from Ensenada, Baja California, Mexico

    Directory of Open Access Journals (Sweden)

    José L. Cortés

    2017-01-01

    Full Text Available E n Ensenada, Baja California, los barcos y vehículos emiten partículas con metales pesados. Las partículas se transportan con el viento y se depositan en el suelo, donde se mezclan con él dando lugar a los polvos urbanos. Los metales pesados pueden afectar la salud de la población, por lo que se requiere un diagnóstico rápido para encontrar soluciones. El objetivo de este trabajo fue identificar las zonas con mayor contaminación en la ciudad. Se tomaron 86 muestras de polvo urbano sobre diferentes sustratos (suelo, cemento y asfalto. Los metales se analizaron mediante f luorescencia de rayos X. Las diferencias entre los sustratos se identificaron mediante un análisis de varianza. Por otra parte, se hizo un análisis para conocer la distribución espacial de los metales pesados, utilizando la interpolación con kriging ordinario. El asfalto contiene las mayores concentraciones de Cr, Ni, Pb y Zn; el cemento contiene mayores concentracions de Cu y V; y el suelo es el que más Rb contiene. El mapa que integra las clases de mayor concentración de metales indica que la zona suroeste, donde se localiza el puerto y pasa la carretera transpeninsular, es la más contaminada.

  11. Parametric analysis of plastic strain and force distribution in single pass metal spinning

    International Nuclear Information System (INIS)

    Choudhary, Shashank; Tejesh, Chiruvolu Mohan; Regalla, Srinivasa Prakash; Suresh, Kurra

    2013-01-01

    Metal spinning also known as spin forming is one of the sheet metal working processes by which an axis-symmetric part can be formed from a flat sheet metal blank. Parts are produced by pressing a blunt edged tool or roller on to the blank which in turn is mounted on a rotating mandrel. This paper discusses about the setting up a 3-D finite element simulation of single pass metal spinning in LS-Dyna. Four parameters were considered namely blank thickness, roller nose radius, feed ratio and mandrel speed and the variation in forces and plastic strain were analysed using the full-factorial design of experiments (DOE) method of simulation experiments. For some of these DOE runs, physical experiments on extra deep drawing (EDD) sheet metal were carried out using En31 tool on a lathe machine. Simulation results are able to predict the zone of unsafe thinning in the sheet and high forming forces that are hint to the necessity for less-expensive and semi-automated machine tools to help the household and small scale spinning workers widely prevalent in India

  12. Parametric analysis of plastic strain and force distribution in single pass metal spinning

    Science.gov (United States)

    Choudhary, Shashank; Tejesh, Chiruvolu Mohan; Regalla, Srinivasa Prakash; Suresh, Kurra

    2013-12-01

    Metal spinning also known as spin forming is one of the sheet metal working processes by which an axis-symmetric part can be formed from a flat sheet metal blank. Parts are produced by pressing a blunt edged tool or roller on to the blank which in turn is mounted on a rotating mandrel. This paper discusses about the setting up a 3-D finite element simulation of single pass metal spinning in LS-Dyna. Four parameters were considered namely blank thickness, roller nose radius, feed ratio and mandrel speed and the variation in forces and plastic strain were analysed using the full-factorial design of experiments (DOE) method of simulation experiments. For some of these DOE runs, physical experiments on extra deep drawing (EDD) sheet metal were carried out using En31 tool on a lathe machine. Simulation results are able to predict the zone of unsafe thinning in the sheet and high forming forces that are hint to the necessity for less-expensive and semi-automated machine tools to help the household and small scale spinning workers widely prevalent in India.

  13. ICP-MS: suitable method to study the metals distribution in estuarine regions

    International Nuclear Information System (INIS)

    Vasconcelos, Danilo C.; Oliveira, Arno H.; Santos, Silvio J. dos; Brito, Veronica F.O.; Severo, Maria Isabel G.

    2005-01-01

    Anthropogenic inputs of pollutants such as heavy metals into the marine environment have increased their levels to large extents within past a few decades. These pollutants tend to accumulate in the bottom sediments. As a result, ecosystems such as seaports or other industrialized coastal areas that have chronic inputs of metals have highly contaminated sediments. This characteristic has led to concerns over the ecological effects that may be associated with sediment quality. Of particular concern are toxic effects and the potential for bioaccumulation of metals in biota exposed to the sediments. The bivalves Crassostrea rhizophorae, Lucina pectinata and Mytella falcata have been used as biomonitors of trace metal contamination in two estuaries from Ilheus city, Bahia state, in Brazil. Bivalves, sediment and water samples were collected in March 2004 in Acuipe and Rio do Engenho mangroves. The proposed technique to analyze the studied matrices was the inductively coupled plasma mass spectrometry (ICP-MS). The results suggested that the studied molluscs are bioaccumulators of metals and showed the Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) as an adequate technique to determine a large range of inorganic elements, because its high sensibility and low detection limits. (author)

  14. [Distribution Characteristics of Heavy Metals in Environmental Samples Around Electroplating Factories and the Health Risk Assessment].

    Science.gov (United States)

    Guo, Peng-ran; Lei, Yong-qian; Zhou, Qiao-li; Wang, Chang; Pan, Jia-chuan

    2015-09-01

    This study aimed to investigate the pollution degree and human health risk of heavy metals in soil and air samples around electroplating factories. Soil, air and waste gas samples were collected to measure 8 heavy metals (As, Cd, Cr, Cu, Hg, Ni, Pb and Zn) in two electroplating factories, located in Baiyun district of Guangzhou city. Geoaccumulation index and USEPA Risk Assessment Guidance for Superfund (RAGS) were respectively carried out. Results showed that concentrations of Hg and Pb in waste gas and Cr in air samples were higher than limits of the corresponding quality standards, and concentrations of Cd, Hg and Zn in soil samples reached the moderate pollution level. The HQ and HI of exposure by heavy metals in air and soil samples were both lower than 1, indicating that there was no non-carcinogen risk. CRAs and CRCr in soil samples were beyond the maximum acceptable level of carcinogen risk (10(-4)), and the contribution rate of CRCr to TCR was over 81%. CRCr, CRNi and TCR in air samples were in range of 10(-6) - 10(-4), indicating there was possibly carcinogen risk but was acceptable risk. CR values for children were higher than adults in soils, but were higher for adults in air samples. Correlation analysis revealed that concentrations of heavy metals in soils were significantly correlated with these in waste gas samples, and PCA data showed pollution sources of Cd, Hg and Zn in soils were different from other metals.

  15. Parametric analysis of plastic strain and force distribution in single pass metal spinning

    Energy Technology Data Exchange (ETDEWEB)

    Choudhary, Shashank, E-mail: shashankbit08@gmail.com, E-mail: mohantejesh93@gmail.com, E-mail: regalla@hyderabad.bits-pilani.ac.in, E-mail: ksuresh@hyderabad.bits-pilani.ac.in; Tejesh, Chiruvolu Mohan, E-mail: shashankbit08@gmail.com, E-mail: mohantejesh93@gmail.com, E-mail: regalla@hyderabad.bits-pilani.ac.in, E-mail: ksuresh@hyderabad.bits-pilani.ac.in; Regalla, Srinivasa Prakash, E-mail: shashankbit08@gmail.com, E-mail: mohantejesh93@gmail.com, E-mail: regalla@hyderabad.bits-pilani.ac.in, E-mail: ksuresh@hyderabad.bits-pilani.ac.in; Suresh, Kurra, E-mail: shashankbit08@gmail.com, E-mail: mohantejesh93@gmail.com, E-mail: regalla@hyderabad.bits-pilani.ac.in, E-mail: ksuresh@hyderabad.bits-pilani.ac.in [Department of Mechanical Engineering, BITS-Pilani, Hyderabad Campus, Shamirpet, Hyderabad, 500078, Andhra Pradesh (India)

    2013-12-16

    Metal spinning also known as spin forming is one of the sheet metal working processes by which an axis-symmetric part can be formed from a flat sheet metal blank. Parts are produced by pressing a blunt edged tool or roller on to the blank which in turn is mounted on a rotating mandrel. This paper discusses about the setting up a 3-D finite element simulation of single pass metal spinning in LS-Dyna. Four parameters were considered namely blank thickness, roller nose radius, feed ratio and mandrel speed and the variation in forces and plastic strain were analysed using the full-factorial design of experiments (DOE) method of simulation experiments. For some of these DOE runs, physical experiments on extra deep drawing (EDD) sheet metal were carried out using En31 tool on a lathe machine. Simulation results are able to predict the zone of unsafe thinning in the sheet and high forming forces that are hint to the necessity for less-expensive and semi-automated machine tools to help the household and small scale spinning workers widely prevalent in India.

  16. Distribution of oxides in a Zr-Cu-Ni-Al-Nb-Si bulk metallic glass

    Energy Technology Data Exchange (ETDEWEB)

    Heinrich, Jochen; Busch, Ralf [Chair of Metallic Materials, Saarland University, PO Box 151150, 66041 Saarbruecken (Germany); Mueller, Frank; Huefner, Stefan [Chair of Experimental Physics, Saarland University, PO Box 151150, 66041 Saarbruecken (Germany)

    2010-07-01

    The course of oxide presence with distance from the sample surface and bonding partner was studied for the bulk metallic glass with the nominal composition Zr{sub 57.9}Cu{sub 15.4}Ni{sub 12.7}Al{sub 10.2}Nb{sub 2.8}Si{sub 1} (at%) by X-ray photoelectron spectroscopy (XPS). Investigated specimens are taken from vacuum quench-cast rods subjected to oxidation at room temperature and atmosphere. Binding energies were determined in various depths using ion beam ablation of up to 100 nanometers. XPS spectra confirm oxidation primarily of the pure zirconium and aluminum constituents, all other peaks correspond to metallic bonds. While the surface area shows a passivating zirconia layer a few nanometers thick, oxygen is bonded predominantly with aluminum inside the bulk. Since the concentration of oxygen is a crucial factor in the crystallization behavior of bulk metallic glass forming liquids on basis of oxygen affine metals, so far only high purity materials were thought to be suitable. The findings in this study, however, are promising for alloys with industrial grade elements with sufficient glass forming ability. Comparisons of the alloy with differing oxygen content support the conclusion that aluminum acts as an appropriate scavenger for both adsorbed and large amounts of intrinsic oxygen in zirconium based amorphous metals.

  17. Finite element analysis of the combined fine blanking and extrusion process

    Science.gov (United States)

    Zheng, Peng-Fei

    The combined fine blanking and extrusion process is such a metal forming process that fine blanking and forward extrusion are carried out on sheet metal material at the same time. There are two typical characteristics in this process, one is the fine blanking whose deformation mechanism is different from conventional blanking; the other is the sheet metal extrusion, which is different from the conventional extrusion. Even though fine blanking has been used in industry for many years, only limited literature can be found which deals with the theoretical analysis of it. On the other hand, no publications on the theoretical analysis of the sheet metal extrusion have been found. Intensive work should be carried out to reveal the mechanism of both fine blanking process and sheet metal extrusion process, and further the combined fine blanking and extrusion process. The scope of this thesis is to study the mechanics of fine blanking, sheet metal extrusion, and combined fine blanking and extrusion process one by one with the rigid-plastic finite element method. All of above processes are typical unsteady ones, especially the fine blanking process in which extremely severe and localized deformation occurs. Therefore, commercial programs can not be used to solve these problems up till now. Owing to this reason, a rigid-plastic finite element program was developed for simulating these processes where remeshing and mesh tracing techniques as well as the golden section method were adopted according to the characteristics of these processes in this thesis. Moreover, a permissible kinematic velocity field was adopted as the initial velocity field for simulating extrusion process successfully. Results from the simulation included the distorted mesh, the field of material flow, the stress and the strain distributions at various moments of deformation. Results under different deformation conditions such as different blanking clearances, different diameters of the extrusion punch and

  18. Distribution of heavy metals in internal organs and tissues of Korean molluscan shellfish and potential risk to human health.

    Science.gov (United States)

    Mok, Jong Soo; Kwon, Ji Young; Son, Kwang Tae; Choi, Woo Seok; Kim, Poong Ho; Lee, Tae Seek; Kim, Ji Hoe

    2015-09-01

    Molluscan shellfish (gastropods and bivalves) were collected from major fish markets on the Korean coast and analyzed for mercury by direct Hg analyzer and for other metals, such as cadmium, lead, chromium, silver, nickel, copper and zinc, using inductively coupled plasma mass spectrometry. Distribution of heavy metals in muscles, internal organs and whole tissues were determined and a potential risk assessment was conducted to evaluate their hazard for human consumption. Heavy metals were accumulated significantly higher (P hazardous metals (Cd, Pb, and Hg) in all internal-organ samples were above the regulatory limit of Korea and the mean level in whole tissue samples of the selected gastropod species, bay scallop and comb pen shell, exceeded the limit (except in a few cases). The sum of the estimated dietary intake of Cd, Pb and Hg for each part of all tested species accounted for 1.59-16.94, 0.02-0.36, and 0.07-0.16% respectively, of the provisional tolerable daily intake adopted by the Joint FAO/WHO Expert Committee on Food Additives. The hazard index for each part of gastropods and bivalves was below 1.0, however, the maximum HI for internal organs of all analysed species was quite high (0.71). These results suggest that consumption of flesh after removing the internal organs of some molluscan shellfish (all gastropod species, bay scallop and comb pen shell) is a suitable way for reducing Cd exposure.

  19. Distributions and concentrations of thallium in surface waters of a region impacted by historical metal mining (Cornwall, UK).

    Science.gov (United States)

    Tatsi, Kristi; Turner, Andrew

    2014-03-01

    Thallium is a highly toxic heavy metal whose concentrations and distributions in the aquatic environment are poorly defined. In this study, concentrations of aqueous and total Tl have been measured in water samples from a variety of rivers and effluents (the latter related to historical metal mining) in the county of Cornwall, SW England. Aqueous concentrations ranged from about 13 ng L(-1) in a river whose catchment contained no metal mines to 2,640 ng L(-1) in water abstracted directly from an abandoned mine shaft. Concentrations of Tl in rivers were greatest in the vicinity of mine-related effluents, with a maximum value measured of about 770 ng L(-1). Thallium was not efficiently removed by the conventional, active treatment of mine water, and displayed little interaction with suspended particles. Its mobility in surface waters, coupled with concentrations that are close to a quality guideline of 800 ng L(-1), is cause for concern. Accordingly, we recommend that the metal is more closely monitored in this and other regions impacted by mining activities. Copyright © 2013 Elsevier B.V. All rights reserved.

  20. Heavy metals distribution and risk assessment in soil from an informal E-waste recycling site in Lagos State, Nigeria.

    Science.gov (United States)

    Isimekhai, Khadijah A; Garelick, Hemda; Watt, John; Purchase, Diane

    2017-07-01

    Informal E-waste recycling can pose a risk to human health and the environment which this study endeavours to evaluate. The distribution of a number of heavy metals in soil from an informal recycling site in the largest market for used and new electronics and electrical equipment in West Africa was investigated. The potential bioavailability of heavy metals, extent of contamination, potential risk due to the recycling activities and impact of external factors such as rainfall were also assessed. The concentrations of all the heavy metals tested were higher in the area where burning of the waste occurred than at the control site, suggesting an impact of the recycling activities on the soil. The order of total metal concentrations was Cu > Pb > Zn > Mn > Ni > Sb > Cr > Cd for both the dry and wet seasons. The total concentrations of Cd, Cu, Mn, Ni and Zn were all significantly higher (p  Sb > Zn > Cu > Ni > Pb > Cr. When the risk was assessed using the Potential Ecological Risk Index (PERI), Cu was found to contribute the most to the potential ecological risk and Cd gave rise to the greatest concern due to its high toxic-response factor within the study site. Similarly, utilising the Risk Assessment Code (RAC) suggested that Cd posed the most risk in this site. This research establishes a high level of contamination in the study site and underscores the importance of applying the appropriate chemical speciation in risk assessment.

  1. Stable isotopes and heavy metal distribution in Dreissena polymorpha (Zebra Mussels) from western basin of Lake Erie, Canada

    Energy Technology Data Exchange (ETDEWEB)

    Al-Aasm, I.S.; Clarke, J.D.; Fryer, B.J. [Windsor Univ., ON (Canada). Dept. of Earth Sciences

    1998-02-01

    Dreissena polymorpha is an exotic freshwater bivalve species which was introduced into the Great Lakes system in the fall of 1985 through the release of ballast water from European freighters. Utilizing individual growth rings of the shells, the stable isotope distribution ({delta}{sup 18}O and {delta}{sup 13}C) was determined for the life history of selected samples which were collected from the western basin of Lake Erie. These bivalves deposit their shell in near equilibrium with the ambient water and thus reflect any annual variation of the system in the isotopic records held within their shells. Observed values for {delta}{sup 18}O range from -6.64 to -9.46 permille with an average value of -7.69 permille PDB, while carbon values ranged from -0.80 to -4.67 permille with an average value of -1.76 permille PDB. Dreissena polymorpha shells incorporate metals into their shells during growth. Individual shell growth increments were analyzed for Pb, Fe, Mg, Mn, Cd, Cu, and V concentrations. The shells show increased uptake of certain metals during periods of isotopic enrichment which correspond with warmer water temperatures. Since metals are incorporated into the shells, the organism may be useful as a biomonitor of metal pollution within aquatic environments. (orig.)

  2. [Pollution Assessment and Spatial Distribution Characteristics of Heavy Metals in Soils of Coal Mining Area in Longkou City].

    Science.gov (United States)

    Liu, Shuo; Wu, Quan-yuan; Cao, Xue-jiang; Wang, Ji-ning; Zhang, Long-long; Cai, Dong-quan; Zhou, Li-yuan; Liu, Na

    2016-01-15

    The present paper takes the coal mining area of Longkou City as the research area. Thirty-six topsoil (0-20 cm) samples were collected and the contents of 5 kinds of heavy metals were determined, including Cd, As, Ni, Ph, Cr. Geo-statistics analysis was used to analyze the spatial distribution of heavy metals. Principal component analysis (PCA) was used to explore the pollution sources of heavy metals and the degree of heavy metals pollution was evaluated by weighted average comprehensive pollution evaluation method. The results showed that enrichment phenomenon was significant for the 5 kinds of heavy metals. Taking secondary standard of National Environment Quality Standard for Soil as the background value, their exceed standard rates were 72.22%, 100%, 100%, 91.67%, 100%, respectively. Average contents of heavy metals in the soil samples were all over the national standard level two and were 1.53, 11.86, 2.40, 1.31, 4.09 times of the background value. In addition, the average contents were much higher than the background value of the topsoil in the eastern part of Shandong Province and were 9.85, 39.98, 8.85, 4.29, 12.71 times of the background value. According to the semivariogram model, we obtained the nugget-effects of 5 kinds of heavy metals and their values were in the order of As (0.644) > Cd (0.627) > Cr (0.538) > Ni (0.411) > Pb (0.294), all belonging to moderate spatial correlation. On the whole, the central part of the Sangyuan Coal Mine and its surrounding areas were the most seriously polluted, while the pollution of heavy metals in the east and west of the study area was relatively light. Principal component analysis suggested that the enrichment of Cd, As, Ni, Cr was due to irrigation of wastewater, the discharge of industry and enterprise, and the industrial activity. Automobile exhaust and coal combustion were the main pollution sources of Pb. The single-factor assessment of heavy metals pollution showed that the degree of different heavy metals

  3. Lead (Pb) and other metals in New York City community garden soils: factors influencing contaminant distributions.

    Science.gov (United States)

    Mitchell, Rebecca G; Spliethoff, Henry M; Ribaudo, Lisa N; Lopp, Donna M; Shayler, Hannah A; Marquez-Bravo, Lydia G; Lambert, Veronique T; Ferenz, Gretchen S; Russell-Anelli, Jonathan M; Stone, Edie B; McBride, Murray B

    2014-04-01

    Urban gardens provide affordable fresh produce to communities with limited access to healthy food but may also increase exposure to lead (Pb) and other soil contaminants. Metals analysis of 564 soil samples from 54 New York City (NYC) community gardens found at least one sample exceeding health-based guidance values in 70% of gardens. However, most samples (78%) did not exceed guidance values, and medians were generally below those reported in NYC soil and other urban gardening studies. Barium (Ba) and Pb most frequently exceeded guidance values and along with cadmium (Cd) were strongly correlated with zinc (Zn), a commonly measured nutrient. Principal component analysis suggested that contaminants varied independently from organic matter and geogenic metals. Contaminants were associated with visible debris and a lack of raised beds; management practices (e.g., importing uncontaminated soil) have likely reduced metals concentrations. Continued exposure reduction efforts would benefit communities already burdened by environmental exposures. Copyright © 2014 Elsevier Ltd. All rights reserved.

  4. Dose distribution close to metal implants in Gamma Knife Radiosurgery: A Monte Carlo study

    International Nuclear Information System (INIS)

    Cheung, Joel Y.C.; Yu, K.N.; Chan, Josie F.K.; Ho, Robert T.K.; Yu, C.P.

    2003-01-01

    Materials with high atomic numbers favor the occurrence of the photoelectric effect when they are irradiated with gamma rays. Therefore, the photoelectric effects of metal implants within the target regions in Gamma Knife Radiosurgery are worth studying. In the present work, Monte Carlo simulations using EGS4 were employed to investigate the resulting dose enhancements. A dose enhancement as high as 10% was observed close to a platinum implant along the x and y axes, while no significant dose enhancements were observed for silver, stainless steel 301, and titanium ones. A dose enhancement as high as 20% was observed close to the platinum implant along the z axis at the superior position of the metal-phantom interface and was 10% higher for other metal implants

  5. Distribution and risk evaluation of heavy metals in agricultural soils of southeastern Zunyi city, China

    International Nuclear Information System (INIS)

    Chen Hongliang; Xu Huajie; Song Yuping; Tan Hong; Xie Feng; He Jinlin

    2008-01-01

    The pollution of heavy metals (As, Pb, Cd, Cr, and Hg) in agricultural soils of Southeastern Zunyi, Guizhou Province were investigated and assessed in this paper. The results showed that the average contents of heavy metals in the soils were As 11.39mg/kg, Pb 38.75mg/kg, Cd 0.34mg/kg, Cr 40.45mg/kg, Hg 0.21mg/kg. The Cd is the main contamination element, with an average single pollution index of 1.13, and an average single ecological risk index of 50.85, showing this area is in medium ecological risk class. The highest pollution index is 1.43 in Zunyi County, with an average single ecological risk index of 64.35. The results also indicated that Cd and Hg had caused some relevant ecological risk by comparing the pollution index with the ecological risk index of heavy metals. (authors)

  6. Applications of Total Scattering & Pair Distribution Function Analysis in Metal-Organic Framework Materials

    DEFF Research Database (Denmark)

    Xu, Hui; Birgisson, Steinar; Sommer, Sanna

    structure. At the same time, there is an ongoing debate on whether the SBU is present prior, or during MOF crystallization in MOF chemistry. However, little is known about MOFs formation mechanism. Currently techniques to study the in situ MOF formation process mainly focused on after......-crystallization process, for example in situ XRD and SAXS/WAXS study on MOF formation. However, the pre-crystallization process in the early stage of MOF formation is still unexplored. In this project, total scattering and PDF study will be carried out to explore the MOF formation process in early stage. This includes......Metal-Organic Frameworks (MOFs) is constructed by metal-oxide nodes and organic ligands. The formation of different structures of metal-oxide nodes (also called secondary building units, SBU) is crucial for MOF final structures, because the connectivity of SBU greatly influence the final MOF...

  7. Lead (Pb) and other metals in New York City community garden soils: factors influencing contaminant distributions

    Science.gov (United States)

    Mitchell, Rebecca G.; Spliethoff, Henry M.; Ribaudo, Lisa N.; Lopp, Donna M.; Shayler, Hannah A.; Marquez-Bravo, Lydia G.; Lambert, Veronique T.; Ferenz, Gretchen S.; Russell-Anelli, Jonathan M.; Stone, Edie B.; McBride, Murray B.

    2014-01-01

    Urban gardens provide affordable fresh produce to communities with limited access to healthy food but may also increase exposure to lead (Pb) and other soil contaminants. Metals analysis of 564 soil samples from 54 New York City (NYC) community gardens found at least one sample exceeding health-based guidance values in 70% of gardens. However, most samples (78%) did not exceed guidance values, and medians were generally below those reported in NYC soil and other urban gardening studies. Barium (Ba) and Pb most frequently exceeded guidance values and along with cadmium (Cd) were strongly correlated with zinc (Zn), a commonly measured nutrient. Principal component analysis suggested that contaminants varied independently from organic matter and geogenic metals. Contaminants were associated with visible debris and a lack of raised beds; management practices (e.g., importing uncontaminated soil) have likely reduced metals concentrations. Continued exposure reduction efforts would benefit communities already burdened by environmental exposures. PMID:24502997

  8. Signatures of non-adiabatic dynamics in the fine-structure state distributions of the OH(X{sup ~}/A{sup ~}) products in the B-band photodissociation of H{sub 2}O

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, Linsen [Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Institute of Theoretical and Computational Chemistry, Nanjing University, Nanjing 210093 (China); Xie, Daiqian, E-mail: dqxie@nju.edu.cn, E-mail: hguo@unm.edu [Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Institute of Theoretical and Computational Chemistry, Nanjing University, Nanjing 210093 (China); Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China); Guo, Hua, E-mail: dqxie@nju.edu.cn, E-mail: hguo@unm.edu [Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, New Mexico 87131 (United States)

    2015-03-28

    A detailed quantum mechanical characterization of the photodissociation dynamics of H{sub 2}O at 121.6 nm is presented. The calculations were performed using a full-dimensional wave packet method on coupled potential energy surfaces of all relevant electronic states. Our state-to-state model permits a detailed analysis of the OH(X{sup ~}/A{sup ~}) product fine-structure populations as a probe of the non-adiabatic dissociation dynamics. The calculated rotational state distributions of the two Λ-doublet levels of OH(X{sup ~}, v = 0) exhibit very different characteristics. The A′ states, produced mostly via the B{sup ~}→X{sup ~} conical intersection pathway, have significantly higher populations than the A″ counterparts, which are primarily from the B{sup ~}→A{sup ~} Renner-Teller pathway. The former features a highly inverted and oscillatory rotational state distribution, while the latter has a smooth distribution with much less rotational excitation. In good agreement with experiment, the calculated total OH(X{sup ~}) rotational state distribution and anisotropy parameters show clear even-odd oscillations, which can be attributed to a quantum mechanical interference between waves emanating from the HOH and HHO conical intersections in the B{sup ~}→X{sup ~} non-adiabatic pathway. On the other hand, the experiment-theory agreement for the OH(A{sup ~}) fragment is also satisfactory, although some small quantitative differences suggest remaining imperfections of the ab initio based potential energy surfaces.

  9. Signatures of non-adiabatic dynamics in the fine-structure state distributions of the OH(X~/A~) products in the B-band photodissociation of H2O

    International Nuclear Information System (INIS)

    Zhou, Linsen; Xie, Daiqian; Guo, Hua

    2015-01-01

    A detailed quantum mechanical characterization of the photodissociation dynamics of H 2 O at 121.6 nm is presented. The calculations were performed using a full-dimensional wave packet method on coupled potential energy surfaces of all relevant electronic states. Our state-to-state model permits a detailed analysis of the OH(X ~ /A ~ ) product fine-structure populations as a probe of the non-adiabatic dissociation dynamics. The calculated rotational state distributions of the two Λ-doublet levels of OH(X ~ , v = 0) exhibit very different characteristics. The A′ states, produced mostly via the B ~ →X ~ conical intersection pathway, have significantly higher populations than the A″ counterparts, which are primarily from the B ~ →A ~ Renner-Teller pathway. The former features a highly inverted and oscillatory rotational state distribution, while the latter has a smooth distribution with much less rotational excitation. In good agreement with experiment, the calculated total OH(X ~ ) rotational state distribution and anisotropy parameters show clear even-odd oscillations, which can be attributed to a quantum mechanical interference between waves emanating from the HOH and HHO conical intersections in the B ~ →X ~ non-adiabatic pathway. On the other hand, the experiment-theory agreement for the OH(A ~ ) fragment is also satisfactory, although some small quantitative differences suggest remaining imperfections of the ab initio based potential energy surfaces

  10. Signatures of non-adiabatic dynamics in the fine-structure state distributions of the OH( X ˜ / A ˜ ) products in the B-band photodissociation of H2O

    Science.gov (United States)

    Zhou, Linsen; Xie, Daiqian; Guo, Hua

    2015-03-01

    A detailed quantum mechanical characterization of the photodissociation dynamics of H2O at 121.6 nm is presented. The calculations were performed using a full-dimensional wave packet method on coupled potential energy surfaces of all relevant electronic states. Our state-to-state model permits a detailed analysis of the OH( X ˜ / A ˜ ) product fine-structure populations as a probe of the non-adiabatic dissociation dynamics. The calculated rotational state distributions of the two Λ-doublet levels of OH( X ˜ , v = 0) exhibit very different characteristics. The A' states, produced mostly via the B ˜ → X ˜ conical intersection pathway, have significantly higher populations than the A″ counterparts, which are primarily from the B ˜ → A ˜ Renner-Teller pathway. The former features a highly inverted and oscillatory rotational state distribution, while the latter has a smooth distribution with much less rotational excitation. In good agreement with experiment, the calculated total OH( X ˜ ) rotational state distribution and anisotropy parameters show clear even-odd oscillations, which can be attributed to a quantum mechanical interference between waves emanating from the HOH and HHO conical intersections in the B ˜ → X ˜ non-adiabatic pathway. On the other hand, the experiment-theory agreement for the OH( A ˜ ) fragment is also satisfactory, although some small quantitative differences suggest remaining imperfections of the ab initio based potential energy surfaces.

  11. Signatures of non-adiabatic dynamics in the fine-structure state distributions of the OH(X̃/Ã) products in the B-band photodissociation of H2O.

    Science.gov (United States)

    Zhou, Linsen; Xie, Daiqian; Guo, Hua

    2015-03-28

    A detailed quantum mechanical characterization of the photodissociation dynamics of H2O at 121.6 nm is presented. The calculations were performed using a full-dimensional wave packet method on coupled potential energy surfaces of all relevant electronic states. Our state-to-state model permits a detailed analysis of the OH(X̃/Ã) product fine-structure populations as a probe of the non-adiabatic dissociation dynamics. The calculated rotational state distributions of the two Λ-doublet levels of OH(X̃, v = 0) exhibit very different characteristics. The A' states, produced mostly via the B̃→X̃ conical intersection pathway, have significantly higher populations than the A″ counterparts, which are primarily from the B̃→Ã Renner-Teller pathway. The former features a highly inverted and oscillatory rotational state distribution, while the latter has a smooth distribution with much less rotational excitation. In good agreement with experiment, the calculated total OH(X̃) rotational state distribution and anisotropy parameters show clear even-odd oscillations, which can be attributed to a quantum mechanical interference between waves emanating from the HOH and HHO conical intersections in the B̃→X̃ non-adiabatic pathway. On the other hand, the experiment-theory agreement for the OH(Ã) fragment is also satisfactory, although some small quantitative differences suggest remaining imperfections of the ab initio based potential energy surfaces.

  12. Metal distribution in urban soil around steel industry beside Queen Alia Airport, Jordan.

    Science.gov (United States)

    Al-Khashman, Omar A; Shawabkeh, Reyad A

    2009-12-01

    The objective of this study was to assess the extent and severity of metal contamination in urban soil around Queen Alia Airport, Jordan. Thirty-two soil samples were collected around steel manufacturing plants located in the Al-Jiza area, south Jordan, around the Queen Alia Airport. The samples were obtained at two depths, 0-10 and 10-20 cm, and were analyzed by atomic absorption spectrophotometry for lead (Pb), zinc (Zn), cadmium (Cd), iron (Fe), copper (Cu) and chromium (Cr) levels. The physicochemical factors believed to affect the mobility of metals in the soil of the study area were also examined, including pH, electrical conductivity, total organic matter, calcium carbonate (CaCO(3)) content and cation exchange capacity. The high concentrations of Pb, Zn and Cd in the soil samples were found to be related to anthropogenic sources, such as the steel manufacturing plants, agriculture and traffic emissions, with the highest concentrations of these metals close to the site of the steel plants; in contrast the concentration of Cr was low in the soil sampled close to the steel plants. The metals were concentrated in the surface soil, and concentrations decreased with increasing depth, reflecting the physical properties of the soil and its alkaline pH. The mineralogical composition of the topsoil, identified by X-ray diffraction, was predominantly quartz, calcite, dolomite and minor minerals, such as gypsum and clay minerals. Metal concentrations were compared using one-way analysis of variance (ANOVA) to compute the statistical significance of the mean. The results of the ANOVA showed significant differences between sites for Pb, Cd and Cu, but no significant differences for the remaining metals tested. Factor analysis revealed that polluted soil occurs predominantly at sites around the steel plants and that there is no significant variation in the characteristics of the unpolluted soil, which are uniform in the study area.

  13. Distribution and accumulation of metals in tadpoles inhabiting the metalliferous streams of eastern Chalkidiki, northeast Greece.

    Science.gov (United States)

    Kelepertzis, Efstratios; Argyraki, Ariadne; Valakos, Efstratios; Daftsis, Emmanouil

    2012-10-01

    The present study investigates the accumulation of heavy metals [copper (Cu), lead (Pb), zinc (Zn), magnesium (Mn), cadmium (Cd), nickel (Ni), and chromium (Cr)] in tadpoles inhabiting the metalliferous streams flowing within the Asprolakkas River basin (northeast Chalkidiki peninsula, Greece) and the effect of potentially harmful elements in stream water and sediment on the corresponding levels in their tissue. Animals were collected from six sampling sites influenced by a wide range of surface water and stream sediment trace element concentrations. The results of the chemical analyses showed that tadpoles accumulated significant levels of all of the examined metals. The range of whole-body mean measured concentrations were (in dry mass) as follows: Cu (46-182 mg/kg), Pb (103-4,490 mg/kg), Zn (494-11,460 mg/kg), Mn (1,620-13,310 mg/kg), Cd (1.2-82 mg/kg), Ni (57-163 mg/kg), and Cr (38-272 mg/kg). The mean concentrations of Pb, Zn, Mn, Ni, Cr, and Cd in Kokkinolakkas stream, which drains a currently active mining area, were the highest ever reported in tadpoles. Our results indicate that whole-body levels of Pb, Zn, Cu, and Cd increase with stream sediment concentrations and that these organisms tend to accumulate metals bound to Fe and Mn oxides. In addition, high dissolved concentrations and significant concentrations associated with more labile geochemical phases of sediments for specific metals were contributing factors determining whole-body levels. Given the observed bioconcentration factors, as well as the correlation with sediment concentrations, it is proposed that these organisms could be considered as bioindicators of environmental contamination and may be used for monitoring purposes within this metal-rich zone and, perhaps, within other rivers affected by metal mining.

  14. Temporal variations and spatial distributions of heavy metals in a wastewater-irrigated soil-eggplant system and associated influencing factors.

    Science.gov (United States)

    Ai, Shiwei; Liu, Bailin; Yang, Ying; Ding, Jian; Yang, Wenzhi; Bai, Xiaojuan; Naeem, Sajid; Zhang, Yingmei

    2018-05-30

    Heavy metal pollution in farmlands is highly concerned as crops' easy-uptake of heavy metal can ultimately affect consumers. In order to offer suggestions on cultivating safe quality vegetable, specifically eggplant which is widely consumed for its nutritional value and antioxidant activity, a field study was undertaken to investigate the temporal variations and spatial distributions of heavy metals in a wastewater-irrigated soil-eggplant system. In the present study, eggplants were planted in the farmlands of Weichuan village (WC) (relatively unpolluted field), Liangzhuang village (LZ) (moderately polluted field) and Minqin village (MQ) (seriously polluted field) to elucidate their temporal uptake processes of heavy metals described by the sigmoid model. Eggplant tissues from severely polluted farmlands were found with higher heavy metal concentrations and lower yields compared with other two groups. What is more, 25 farmlands along the Dongdagou stream (heavy metals polluted stream) were chosen to analyze the spatial distribution of heavy metals in soils and eggplants. Heavy metal concentrations in eggplants decreased with the decline of heavy metal concentrations in soil from upstream (pollution source) to downstream. Moreover, several methods were employed to assess bioavailability of heavy metals in soils. All the bioavailable heavy metals were found in linear positive correlations with heavy metal concentrations. Meanwhile, linear correlations were found between heavy metals in soils and eggplants. At last, redundancy analysis was used to investigate the effects of soil properties (pH, organic matter and texture of soils) and heavy metals on eggplants' uptake. The results indicated that soil heavy metals had a dominant impact on their accumulations in eggplant fruit, with a variance contribution of 78.0%, while soil properties had a regulatory effect, with a variance contribution of 5.2%. Copyright © 2018 Elsevier Inc. All rights reserved.

  15. Using of fluidized-bed jet mill to a super fine comminution of steel composite

    Directory of Open Access Journals (Sweden)

    D. Urbaniak

    2015-01-01

    Full Text Available In many industries the demand for very fine material increases. In the metallurgical industry, for example, there is increasing use of the production of high density metal elements with the use of metallurgical powder composites. The use of powder composites requires prior their grinding. Unfortunately, the very fine grinding is not an easy process. The using for this purpose fluidized-bed jet mill was proposed in the paper. The attempts of grinding of metallurgical powder were carried out in the fluidized-bed jet mill. After the experiment analyses of particle size distribution of grinding products were performed. The results are presented in graphs. Analyses of the obtained results concluded that the grinding of very fine metallurgical composite is possible and produces positive results.

  16. Dense cermets containing fine grained ceramics and their manufacture

    International Nuclear Information System (INIS)

    King, H.L.

    1986-01-01

    This patent describes a method of producing a ceramic-metal composite (cermet) containing boride-oxide ceramic having components of a first metal boride and a second metal oxide, which ceramic is in mixture in the cermet with elemental metal of the second metal, wherein the cermet is produced by sintering a reaction mixture of the first metal oxide, boron oxide and the elemental second metal. The improvement consists of: combining for the reaction mixture; A. (a) first metal oxide; (b) boron oxide; (c) ceramic component in very finely divided form; and (d) elemental second metal in very finely divided form and in an amount of at least a 100 percent molar excess beyond that amount stoichiometrically required to produce the second metal oxide during sintering; and B. sintering the reaction mixture in inert gas atmosphere

  17. Heavy metal distribution in organic and siliceous marine sponge tissues measured by square wave anodic stripping voltammetry.

    Science.gov (United States)

    Illuminati, S; Annibaldi, A; Truzzi, C; Scarponi, G

    2016-10-15

    May sponge spicules represent a "tank" to accumulate heavy metals? In this study we test this hypothesis determining the distribution of Cd, Pb and Cu concentrations between organic and siliceous tissues in Antarctic Demospongia (Sphaerotylus antarcticus, Kirkpatrikia coulmani and Haliclona sp.) and in the Mediterranean species Petrosia ficiformis. Results show that although, in these sponges, spicules represent about 80% of the mass content, the accumulation of pollutant is lower in the spicules than in the corresponding organic fraction. The contribution of tissues to the total sponge content of Cd, Pb and Cu is respectively 99%, 82% and 97% for Antarctic sponges and 96%, 95% and 96% for P. ficiformis, similar in polar and temperate organisms. These results pave the way to a better understanding of the role of marine sponges in uptaking heavy metals and to their possible use as monitor of marine ecosystems, recommend by the Water Framework Directive. Copyright © 2016 Elsevier Ltd. All rights reserved.

  18. Controlling the length scale and distribution of the ductile phase in metallic glass composites through friction stir processing.

    Science.gov (United States)

    Arora, Harpreet Singh; Mridha, Sanghita; Grewal, Harpreet Singh; Singh, Harpreet; Hofmann, Douglas C; Mukherjee, Sundeep

    2014-06-01

    We demonstrate the refinement and uniform distribution of the crystalline dendritic phase by friction stir processing (FSP) of titanium based in situ ductile-phase reinforced metallic glass composite. The average size of the dendrites was reduced by almost a factor of five (from 24 μ m to 5 μ m) for the highest tool rotational speed of 900 rpm. The large inter-connected dendrites become more fragmented with increased circularity after processing. The changes in thermal characteristics were measured by differential scanning calorimetry. The reduction in crystallization enthalpy after processing suggests partial devitrification due to the high strain plastic deformation. FSP resulted in increased hardness and modulus for both the amorphous matrix and the crystalline phase. This is explained by interaction of shear bands in amorphous matrix with the strain-hardened dendritic phase. Our approach offers a new strategy for microstructural design in metallic glass composites.

  19. [Spatial distribution and ecological significance of heavy metals in soils from Chatian mercury mining deposit, western Hunan province].

    Science.gov (United States)

    Sun, Hong-Fei; Li, Yong-Hu; Ji, Yan-Fang; Yang, Lin-Sheng; Wang, Wu-Yi

    2009-04-15

    Ores, waste tailings and slag, together with three typical soil profiles (natural soil profiles far from mine entrance and near mine entrance, soil profile under slag) in Chatian mercury mining deposit (CMD), western Hunan province were sampled and their concentrations of mercury (Hg), arsenic (As), lead (Pb), cadmium (Cd), zinc (Zn) were determined by HG-ICP-AES and ICP-MS. Enrichment factor and correlation analysis were taken to investigate the origins, distribution and migration of Hg, as well as other heavy metals in the CMD. The results show that Hg is enriched in the bottom of the soil profile far from mine entrance but accumulated in the surface of soil profiles near mine entrance and under slag. The soil profiles near mine entrance and under slag are both contaminated by Hg, while the latter is contaminated more heavily. In the soil profile under slag, Hg concentration in the surface soil, Hg average concentration in the total profile, and the leaching depth of soil Hg are 640 microg x g(-1), (76.74 +/- 171.71) microg x g(-1), and more than 100 cm, respectively; while 6.5 microg x g(-1), (2.74 +/- 1.90) microg x g(-1), and 40 cm, respectively, are found in the soil profile near mine entrance. Soil in the mercury mine area is also polluted by Cd, As, Pb, Zn besides metallogenic element Hg, among which Cd pollution is relatively heavier than others. The mobility of the studied heavy metals in soil follows the order as Hg > Cd > As > Zn approximately equal to Pb. The leaching depth of the heavy metals is influenced by total concentration in the surface soil and soil physico-chemical parameters. The origins, distribution and migration of heavy metals in soil profile in the mining area are related to primary geological environment, and strongly influenced by human mining activities.

  20. The spatial thickness distribution of metal films produced by large area pulsed laser deposition

    DEFF Research Database (Denmark)

    Pryds, Nini; Schou, Jørgen; Linderoth, Søren

    2007-01-01

    Thin films of metals have been deposited in the large-area Pulsed Laser Deposition (PLD) Facility at Riso National Laboratory. Thin films of Ag and Ni were deposited with laser pulses from an excimer laser at 248 nm with a rectangular beam spot at a fluence of 10 J/cm(2) on glass substrates of 127...

  1. [Distribution characteristics of heavy metals along an elevation gradient of montane forest].

    Science.gov (United States)

    Wan, Jia-rong; Nie, Ming; Zou, Qin; Hu, Shao-chang; Chen, Jia-kuan

    2011-12-01

    In the present paper, the concentrations of fourteen heavy metals (Fe, Al, Ti, Cu, Cr, Mn, V, Zn, Ni, Co, Pb, Se, Cd and As) were determined by ICP-AES and atomic absorption spectroscopy along an elevation gradient of montane forest. The results show that the elevation gradient had significant effects on the concentrations of Fe, Al, Ti, V, Pb and As. And the concentrations of Cu, Cr, Mn, Zn, Ni, Co, Se and Cd were not significantly affected by the elevation gradient. Because the studying area is red soil, the elevation gradient had significant effects on the concentrations of Fe, Al and Ti which are characteristic heavy metals of red soil, suggesting that the red soil at different elevations has different intensities of weathering desilication and bioaccumulation. Other heavy metals have different relationships with the elevation gradient, such as the concentrations of Cr, Zn and Cd were high at relatively high elevation and Pb and As were high at relatively low elevation. These results suggest that the different elevations of montane forest soils were polluted by differently types of heavy metals.

  2. Processes affecting the distribution and speciation of heavy metals in the Rhine/Meuse estuary

    NARCIS (Netherlands)

    Paalman, M.A.A.

    1997-01-01

    When rivers drain areas with a high population density the sediments are often contaminated with heavy metals, such as chromium, cobalt, nickel, copper, zinc, cadmium, mercury and lead. The extent and seriousness of sediment contamination is most pronounced in the lower reaches of rivers, where

  3. Mapping the Spatial Distribution of Metal-Bearing Oxides in VY Canis Majoris

    Science.gov (United States)

    Burkhardt, Andrew; Booth, S. Tom; Remijan, Anthony; Carroll, Brandon; Ziurys, Lucy M.

    2015-06-01

    The formation of silicate-based dust grains is not well constrained. Despite this, grain surface chemistry is essential to modern astrochemical formation models. In carbon-poor stellar envelopes, such as the red hypergiant VY Canis Majoris (VY CMa), metal-bearing oxides, the building blocks of silicate grains, dominate the grain formation, and thus are a key location to study dust chemistry. TiO_2, which was only first detected in the radio recently (Kaminski et al., 2013a), has been proposed to be a critical molecule for silicate grain formation, and not oxides containing more abundant metals (eg. Si, Fe, and Mg) (Gail and Sedlmayr, 1998). In addition, other molecules, such as SO_2, have been found to trace shells produced by numerous outflows pushing through the expanding envelope, resulting in a complex velocity structure (Ziurys et al., 2007). With the advanced capabilities of ALMA, it is now possible to individually resolve the velocity structure of each of these outflows and constrain the underlying chemistry in the region. Here, we present high resolution maps of rotational transitions of several metal-bearing oxides in VY CMa from the ALMA Band 7 and Band 9 Science Verification observations. With these maps, the physical parameters of the region and the formation chemistry of metal-bearing oxides will be studied.

  4. Chemical activation of molecules by metals: Experimental studies of electron distributions and bonding

    International Nuclear Information System (INIS)

    Lichienberger, D.L.

    1990-10-01

    This quarter has witnessed further progress both in our experimental methods of photoelectron spectroscopy and in our understanding the fundamental relationships between ionization energies and the chemistry of transition metal species. Progress continues on the new gas phase photoelectron spectrometer that combine improved capabilities for HeI/HeII UPS, XPS, and Auger investigations of organometallic molecules. Several measurements have been accomplished this year that were not possible previously. We have published the formal relationship between measured molecular ionization energies and thermodynamic bond dissociation energies, and applied the relationships to homonuclear and heteronuclear diatomic molecules, multiple bonds, and metal-ligand bonds. Studies of C-H bond activation have continued with examination of different degrees of Si-H bond addition to metals. the electronic effects of intermolecular interactions have been observed by comparing the ionizations of metal complexes in the gas phase with the ionizations of monolayer solid organometallic films prepared in ultra-high vacuum. The orientations of the molecules have been determined by scanning tunneling microscopy. Especially interesting has been the recent application of these techniques to the characterization of the soccer-ball shaped C 60 molecule, buckminsterfullerene. Studies of the following complexes are described : Fe, Os, Nb, Mo, Rh, Re, Al, and Mn. 19 refs

  5. WITNESSING GAS MIXING IN THE METAL DISTRIBUTION OF THE HICKSON COMPACT GROUP HCG 31

    International Nuclear Information System (INIS)

    Torres-Flores, S.; Alfaro-Cuello, M.; De Oliveira, C. Mendes; Amram, P.; Carrasco, E. R.; De Mello, D. F.

    2015-01-01

    We present for the first time direct evidence that in a merger of disk galaxies, the pre-existing central metallicities will mix as a result of gas being transported in the merger interface region along the line that joins the two coalescing nuclei. This is shown using detailed two-dimensional kinematics as well as metallicity measurements for the nearby ongoing merger in the center of the compact group HCG 31. We focus on the emission line gas, which is extensive in the system. The two coalescing cores display similar oxygen abundances. While in between the two nuclei, the metallicity changes smoothly from one nucleus to the other indicating a mix of metals in this region, which is confirmed by the high-resolution Hα kinematics (R = 45,900). This nearby system is especially important because it involves the merging of two fairly low-mass and clumpy galaxies (LMC-like galaxies), making it an important system for comparison with high-redshift galaxies

  6. WITNESSING GAS MIXING IN THE METAL DISTRIBUTION OF THE HICKSON COMPACT GROUP HCG 31

    Energy Technology Data Exchange (ETDEWEB)

    Torres-Flores, S.; Alfaro-Cuello, M. [Departamento de Física, Universidad de La Serena, Av. Cisternas 1200, La Serena (Chile); De Oliveira, C. Mendes [Instituto de Astronomia, Geofísica e Ciências Atmosféricas da Universidade de São Paulo, Cidade Universitária, CEP:05508-900, São Paulo, SP (Brazil); Amram, P. [Aix Marseille Université, CNRS, LAM (Laboratoire d' Astrophysique de Marseille) UMR 7326, F-13388, Marseille (France); Carrasco, E. R. [Gemini Observatory/AURA, Southern Operations Center, Casilla 603, La Serena (Chile); De Mello, D. F., E-mail: storres@dfuls.cl [Catholic University of America, Washington, DC 20064 (United States)

    2015-01-01

    We present for the first time direct evidence that in a merger of disk galaxies, the pre-existing central metallicities will mix as a result of gas being transported in the merger interface region along the line that joins the two coalescing nuclei. This is shown using detailed two-dimensional kinematics as well as metallicity measurements for the nearby ongoing merger in the center of the compact group HCG 31. We focus on the emission line gas, which is extensive in the system. The two coalescing cores display similar oxygen abundances. While in between the two nuclei, the metallicity changes smoothly from one nucleus to the other indicating a mix of metals in this region, which is confirmed by the high-resolution Hα kinematics (R = 45,900). This nearby system is especially important because it involves the merging of two fairly low-mass and clumpy galaxies (LMC-like galaxies), making it an important system for comparison with high-redshift galaxies.

  7. Distribution and Ecological Risk Assessment of Heavy Metals in Arable Soils in Bijiang Watershed, China

    Directory of Open Access Journals (Sweden)

    HUANG Wei-heng

    2017-08-01

    Full Text Available It has been paid much attention to soil heavy metal pollution in the Bijiang watershed caused by the Lanping lead-zinc mine. We collected 35 arable soil samples along Bijiang, then sampled and tested the contents of As, Cu, Zn, Cd, Pb, Hg. And then with Nemerow Multi-Factor Index and the Potential Ecological Risk Index method, we evaluated the heavy metal pollution risk. The results showed:(1The accumulation of Pb, Zn, Cd was in a relatively high level, the average was 1 146.97, 579.15, 4.85 mg·kg-1 respectively, which was seriously polluted; the average accumulation of As was 26.85 mg·kg-1; but Cu, Hg was slightly polluted. (2Statistical analysis showed that Lanping area was a main point source pollution of As, Zn, Pb, Cd, while Cu, Hg was pollution caused by different non-point source pollution.(3Within this basin, the Nemerow index was 17.69, which was serious heavy metal pollution, while the comprehensive potential ecological risk index was 773.38, which was a strong potential ecological risk. The contribution of pollutants was Cd > Pb > Zn> As> Hg > Cu. (4As a whole, the soil heavy metal pollution of paddy field was higher than of the dry land.

  8. Benthic foraminifera and heavy metals distribution: A case study from the Naples Harbour (Tyrrhenian Sea, Southern Italy)

    International Nuclear Information System (INIS)

    Ferraro, L.; Sprovieri, M.; Alberico, I.; Lirer, F.; Prevedello, L.; Marsella, E.

    2006-01-01

    The analysis of 90 surficial sediments from three docks of the Naples Harbour (Levante, Granili, and Diaz) permits to compare the distribution modes of heavy metals with grain sizes, total organic carbon content (TOC) and distribution patterns of benthic foraminifera. Foraminiferal density and species richness decrease with the increasing toxic elements concentrations from the Levante to the Diaz dock. Median concentrations of Ni, Pb, Zn, and Hg (medians of 21.43 mg/kg, 270.24 mg/kg, 489.65 mg/kg, and 1.18 mg/kg, respectively) were reported for the Diaz dock where foraminifera are absent, thus suggesting a possible impact of toxic elements on the benthic ecosystem balance. Compared to the unpolluted marine sediments of the Granili dock, the Levante area shows higher heavy metals levels and a quasi-oligotypic benthic assemblage. This is dominated by the tolerant species Ammonia tepida that may be used as bio-indicator of pollution of anthropised marine sediments. - Benthic foraminiferal density and species distribution may be used as pollution indicators

  9. Fluorescence extended X-ray absorption fine structure analysis of half-metallic ferromagnet 'zinc-blende CrAs' grown on GaAs by molecular beam epitaxy

    CERN Document Server

    Ofuchi, H; Ono, K; Oshima, M; Akinaga, H; Manago, T

    2003-01-01

    In this work, geometric structures for a half-metallic ferromagnet 'zinc-blende CrAs', which showed ferromagnetic behavior beyond room temperature, were investigated using fluorescence extended X-ray absorption fine structure (EXAFS) measurement. The EXAFS measurements revealed that As atoms around Cr atoms in the 2 nm CrAs film grown on a GaAs(0 0 1) substrate were coordinated tetrahedrally, indicating formation of zinc-blende CrAs. The Cr-As bond length in the zinc-blende CrAs is 2.49 A. This value is close to that which was estimated from the lattice constant (5.82 A) of ferromagnetic zinc-blende CrAs calculated by full-potential linearized augmented-plane wave method. The EXAFS analysis show that the theoretically predicted zinc-blende CrAs can be fabricated on GaAs(0 0 1) substrate by low-temperature molecular-beam epitaxy.

  10. Fluorescence extended X-ray absorption fine structure analysis of half-metallic ferromagnet 'zinc-blende CrAs' grown on GaAs by molecular beam epitaxy

    International Nuclear Information System (INIS)

    Ofuchi, H.; Mizuguchi, M.; Ono, K.; Oshima, M.; Akinaga, H.; Manago, T.

    2003-01-01

    In this work, geometric structures for a half-metallic ferromagnet 'zinc-blende CrAs', which showed ferromagnetic behavior beyond room temperature, were investigated using fluorescence extended X-ray absorption fine structure (EXAFS) measurement. The EXAFS measurements revealed that As atoms around Cr atoms in the 2 nm CrAs film grown on a GaAs(0 0 1) substrate were coordinated tetrahedrally, indicating formation of zinc-blende CrAs. The Cr-As bond length in the zinc-blende CrAs is 2.49 A. This value is close to that which was estimated from the lattice constant (5.82 A) of ferromagnetic zinc-blende CrAs calculated by full-potential linearized augmented-plane wave method. The EXAFS analysis show that the theoretically predicted zinc-blende CrAs can be fabricated on GaAs(0 0 1) substrate by low-temperature molecular-beam epitaxy

  11. Theoretical analysis of nuclear reactors (Phase II), I-V, Part V, Determining the fine neutron flux distribution by Pn method

    International Nuclear Information System (INIS)

    Pop-Jordanov, J.

    1962-10-01

    Expression for spherical harmonic moments were applied. They were obtained by spherical harmonics expansion of monoenergetic transport equation. This report presents the procedure for calculating the neutron flux distribution in the nine-zone reactor cell of the RA reactor in Vinca. The procedure was modelled for digital computer ZUSE Z-23 by expansion of the diagram of the automated P 3 code, which is adequate for P n code with minor changes. The needed subroutines were developed. The most important ones were those for modified first and second order Bessel functions of n-th order. Computer Z-23 was operating only 15 hours during three months, and thus only the subroutines for modified Bessel functions could be tested and the obtained results were excellent. For the mentioned reason the neutron flux distribution will be calculated in the forthcoming period [sr

  12. Not to put too fine a point on it - does increasing precision of geographic referencing improve species distribution models for a wide-ranging migratory bat?

    Science.gov (United States)

    Hayes, Mark A.; Ozenberger, Katharine; Cryan, Paul M.; Wunder, Michael B.

    2015-01-01

    Bat specimens held in natural history museum collections can provide insights into the distribution of species. However, there are several important sources of spatial error associated with natural history specimens that may influence the analysis and mapping of bat species distributions. We analyzed the importance of geographic referencing and error correction in species distribution modeling (SDM) using occurrence records of hoary bats (Lasiurus cinereus). This species is known to migrate long distances and is a species of increasing concern due to fatalities documented at wind energy facilities in North America. We used 3,215 museum occurrence records collected from 1950–2000 for hoary bats in North America. We compared SDM performance using five approaches: generalized linear models, multivariate adaptive regression splines, boosted regression trees, random forest, and maximum entropy models. We evaluated results using three SDM performance metrics (AUC, sensitivity, and specificity) and two data sets: one comprised of the original occurrence data, and a second data set consisting of these same records after the locations were adjusted to correct for identifiable spatial errors. The increase in precision improved the mean estimated spatial error associated with hoary bat records from 5.11 km to 1.58 km, and this reduction in error resulted in a slight increase in all three SDM performance metrics. These results provide insights into the importance of geographic referencing and the value of correcting spatial errors in modeling the distribution of a wide-ranging bat species. We conclude that the considerable time and effort invested in carefully increasing the precision of the occurrence locations in this data set was not worth the marginal gains in improved SDM performance, and it seems likely that gains would be similar for other bat species that range across large areas of the continent, migrate, and are habitat generalists.

  13. Incidence and distribution of heavy metals in soils of a Mediterranean coastal wetland (L'Albufera de Valencia, Spain)

    Science.gov (United States)

    Andreu, V.; Gimeno, E.; Fernandez-Despiau, E.; Pascual, J. A.

    2012-04-01

    One of the most important issues in environmental conservation nowadays is the preservation of wetlands, mainly the coastal ones. This becomes more imperative in the Mediterranean. These particular ecosystems have suffered during the last decades an increasing human pressure. This has been reflected through the intensification of agriculture and construction of infrastructures in their surroundings or even draining part of them. As a result, the density of population and its residues affect them in a first place. This work has been developed in the Natural Park of La Albufera (Valencia, Spain), which includes a coastal lagoon, marshlands, dunes and pinewoods, surrounded by rice fields in its not urbanized part. In spite of this great ecological value, it suffers impacts derived from the high human and industrial occupation, and of the hydrological contributions from the connected irrigation systems. In addition, this park is one of the most important wetland in Europe, included in the RAMSAR agreement, being a key point for migratory birds and contains in its area one of the most important zones on rice production in Europe. In the park area, 28 sampling zones were selected to determine the degree of heavy metals incidence in soils. Total concentrations of Cd, Co, Cr, Cu, Ni, Pb, and Zn were evaluated. Their distribution in the surficial and sub-surficial horizons was determined together with their spatial distribution, and the possible sources of contamination. Zn, Cr and Cu show the highest concentrations in all land uses and zones. Cr is the metal that present maximum concentration in the studied area (254.93 ppm), being almost the only metal studied that exceeds the limits established by the Spanish an EU legislation. Co and Ni shows a tendency to accumulate below the 30 cm depth, the other metal studied continue with the cumulative trend in surface horizons. All the studied metals, except Co have highly significant correlations with the available phosphorous

  14. Assessing spatial distribution, sources, and potential ecological risk of heavy metals in surface sediments of the Nansi Lake, Eastern China

    International Nuclear Information System (INIS)

    Jianshu Lv; Bin Dai; Zulu Zhang; Yuanyuan Sun; Shuang Li; Yang Liu

    2014-01-01

    The study is conducted to investigate the spatial distribution, sources and ecological risk of seven heavy metals in surface sediments of Nansi Lake, Eastern China. A total of 29 samples were collected in surface sediments of Nansi Lake, and were analyzed for three nutrients (TN, TOC and TP), two major metals (Al and Fe), as well as seven trace metals (As, Cd, Cr, Cu, Hg, Pb and Zn). The mean concentrations of As, Cd, Cr, Cu, Hg, Pb, Zn, Fe and Al were 14.41, 0.22, 71.10, 30.1, 0.048, 29.14, 90.2, 30,816 and 70,653 mg kg -1 , respectively, and the mean contents of these metals were higher than the background values with the exception of Cu and Fe. The spatial distribution indicated that the contents of all seven heavy metals were characterized by relatively higher contents in the upper lake than the lower lake. The hotspots with high values of As, Cd and Hg were associated with the river mouths, and the hotspots of Pb were mainly located around the dam in the central part, while no significant associations were displayed between spatial distribution of Cr, Cu, Zn and the river mouths. The mean enrichment factor (EF) values of As, Cd, Hg and Pb were 2.03, 2.93, 3.21 and 2.18, respectively, showing their moderate enrichment, while Cr, Cu and Zn with mean EF values of 1.19, 0.89 and 1.01 were deficiency to minimal enrichment. Multivariate and geostatistical analyses suggested that PC1 controlled by Cr, Cu and Zn was a lithogenic component, and come from parent rocks leaching. PC2 including Cd and partially Hg represented the factor from industrial wastewater discharge. PC3 showed elevated loadings of As and partially Cd, and could be attributed to the agricultural practices. While PC4 including Pb and partially Hg, was dominated by coal combustion. The results of potential ecological risk suggested that sediment environment of Nansi Lake suffered from high ecological risk. (author)

  15. Distribution and Potential Mobility of Selected Heavy Metals in a Fluvial Environment Under the Influence of Tanneries

    Directory of Open Access Journals (Sweden)

    Rodrigues M. L. K.

    2013-04-01

    Full Text Available In this study we evaluated the occurrence of heavy metals in a fluvial environment under the influence of tanneries – the Cadeia and Feitoria rivers basin (RS, south Brazil, highlighting the distribution and potential mobility of the selected elements. Every three months, over one year-period, selected heavy metals and ancillary parameters were analyzed in water and sediment samples taken at ten sites along the rivers. Water analyses followed APHA recommendations, and sediment analyses were based on methods from USEPA (SW846 and European Community (BCR sequential extraction. The determinations were performed by ICP/OES, except for Hg (CV/ETA. Statistical factor analysis was applied to water and sediment data sets, in order to obtain a synthesis of the environmental diagnosis. The results revealed that water quality decreased along the rivers, and mainly on the dry period (January, showing the influence of tannery plants vicinity and flow variations. Except for Fe, Al, and eventually Mn, heavy metal contents in water were in agreement with Brazilian standards. Concerning sediments, Al, Cu, Fe, Ni, Mn, Ti, and Zn concentrations appeared to reflect the base levels, while Cr and Hg were enriched in the deposits from the lower part of the basin. The partition of heavy metals among the sediment geochemical phases showed higher mobility of Mn along the sampling sites, followed by Cr in the lower reach of the basin, most affected by tanneries. Since Cr was predominantly associated to the oxidizable fraction, its potential mobilization from contaminated sediments would be associated to redox conditions. The detection of Hg in the tissue of a bottom-fish species indicated that the environmental conditions are apparently favoring the remobilization of this metal from contaminated sediments.

  16. Concentrations, spatial distribution, and risk assessment of soil heavy metals in a Zn-Pb mine district in southern China.

    Science.gov (United States)

    Qi, Jianying; Zhang, Hailong; Li, Xiangping; Lu, Jian; Zhang, Gaosheng

    2016-07-01

    China is one of the largest producers and consumers of lead and zinc in the world. Lead and zinc mining and smelting can release hazardous heavy metals such as Cd, Pb, Zn, and As into soils, exerting health risks to human by chronic exposure. The concentrations of Cd, Zn, Pb, and As in soil samples collected from a Pb-Zn mining area with exploitation history of 60 years were investigated. Health risks of the heavy metals in soil were evaluated using US Environmental Protection Agency (US EPA) recommended method. A geo-statistical technique (Kriging) was used for the interpolation of heavy metals pollution and Hazard Index (HI). The results indicated that the long-term Pb/Zn mining activities caused the serious pollution in the local soil. The concentrations of Cd, As, Pb, and Zn in topsoil were 40.3 ± 6.3, 103.7 ± 37.3, 3518.4 ± 896.1, and 10,413 ± 2973.2 mg/kg dry weight, respectively. The spatial distribution of the four metals possessed similar patterns, with higher concentrations around Aayiken (AYK), Maseka (MSK), and Kuangshan (KS) area and more rapidly dropped concentrations at upwind direction than those at downwind direction. The main pollutions of Cd and Zn were found in the upper 60 cm, the Pb was found in the upper 40 cm, and the As was in the upper 20 cm. The mobility of metals in soil profile of study area was classed as Cd > Zn ≫ Pb > As. Results indicated that there was a higher health risk (child higher than adult) in the study area. Pb contributed to the highest Hazard Quotient (57.0 ~ 73.9 %) for the Hazard Index.

  17. The Distribution and Health Risk Assessment of Metals in Soils in the Vicinity of Industrial Sites in Dongguan, China

    Directory of Open Access Journals (Sweden)

    Chao Liu

    2016-08-01

    Full Text Available Exponential industrialization and rapid urbanization have resulted in contamination of soil by metals from anthropogenic sources in Dongguan, China. The aims of this research were to determine the concentration and distribution of various metals (arsenic (As, cadmium (Cd, chromium (Cr, copper (Cu, mercury (Hg, nickel (Ni, lead (Pb and zinc (Zn in soils and identify their potential health risks for local residents. A total of 106 soil samples were collected from the vicinity of industrial sites in Dongguan. Two types of samples were collected from each site: topsoil (0–20 cm, TS and shallow soil (20–50 cm, SS. Results showed that the soils were contaminated by metals and pollution was mainly focused on TS. The geoaccumulation index (Igeo and pollution indexes (PI implied that there was a slight increase in the concentrations of Cd, Cu, Hg, Ni, and Pb, but the metal pollution caused by industrial activities was less severe, and elements of As and Cr exhibited non-pollution level. The risk assessment results suggested that there was a potential health risk associated with As and Cr exposure for residents because the carcinogenic risks of As and Cr via corresponding exposure pathways exceeded the safety limit of 10−6 (the acceptable level of carcinogenic risk for humans. Furthermore, oral ingestion and inhalation of soil particles are the main exposure pathways for As and Cr to enter the human body. This study may provide basic information of metal pollution control and human health protection in the vicinity of industrial regions.

  18. SEISMIC PICTURE OF A FAULT ZONE. WHAT CAN BE GAINED FROM THE ANALYSIS OF FINE PATTERNS OF SPATIAL DISTRIBUTION OF WEAK EARTHQUAKE CENTERS?

    Directory of Open Access Journals (Sweden)

    Gevorg G. Kocharyan

    2010-01-01

    for the purpose of partial stress release. The obtained results suggest that the region, wherein active deformation takes place during preparation of medium earthquakes (M≤6.5÷7.0, includes a number of local «strips», each about 100 m in width. The latter size is comparable to a scope of technogenic capabilities of producing an impact on geo-environment. It is hoped that studies of both fine spatial and temporal patterns of seismicity in the vicinity of fault zones will allow to find reliable pinpoints for definition of both place and time for implementation of technogenic impacts.In our opinion, the implemented study demonstrates the burning need to establish test sites with dense and wellequipped local seismic networks in Russia.

  19. Spatial Distribution of Heavy Metals and the Environmental Quality of Soil in the Northern Plateau of Spain by Geostatistical Methods.

    Science.gov (United States)

    Santos-Francés, Fernando; Martínez-Graña, Antonio; Zarza, Carmelo Ávila; Sánchez, Antonio García; Rojo, Pilar Alonso

    2017-05-26

    The environmental quality of soil in the central part of the Northern Plateau of Spain has been analyzed by studying the heavy metal content of 166 samples belonging to the horizons A, B and C of 89 soil profiles. The analysis to assess the environmental risk of heavy metals in the soil was carried out by means of the spatial distribution of nine heavy metals and the use of several pollution indices. The results showed that the concentration values of heavy metals (x ± S) in the superficial soil horizons were the following: With a total of 6.71 ± 3.51 mg kg -1, the contents of Cd is 0.08 ± 0.06 mg kg-1, Co is 6.49 ± 3.21 mg kg-1, Cu is 17.19 ± 10.69 mg kg-1, Cr is 18.68 ± 12.28 mg kg-1, Hg is 0.083 ± 0.063 mg kg-1, Ni is 12.05 ± 6.76 mg kg-1, Pb is 14.10 ± 11.32 mg kg-1 and Zn is 35.31 ± 14.63 mg kg-1. These nine metals exceed the values of the natural geological background level of Tertiary period sediments and rocks that form part of the Northern Plateau in Spain. Nemerow and Potential Ecological Risk indices were calculated, with the "improved" Nemerow index allowing pollution within the soil superficial horizons to be determined. The data obtained indicated that the majority of the soil (54.61%) showed low to moderate contamination, 22.31% showed moderate contamination and 21.54% of the samples were not contaminated. If we consider the Potential of Ecological Risk Index (RI), the largest percentage of soil samples showed low (70.79%) to moderate (25.38%) ecological risk of potential contamination, where the rest of the soil presented a considerable risk of contamination. The nine trace elements were divided into three principal components: PC1 (Cu, Cr, Ni, Co and Zn), PC2 (As and Hg) and PC3 (Cd). All metals accumulated in the soil came from parent rock, agricultural practices and the run-off of residual waters towards rivers and streams caused by industrial development and an increase in population density. Finally, cartography of the spatial

  20. Distribution and pollution assessment of heavy metals in surface sediments in the Yellow Sea.

    Science.gov (United States)

    Jiang, Xin; Teng, Ankang; Xu, Wenzhe; Liu, Xiaoshou

    2014-06-15

    Heavy metal concentrations in surface sediments at 56 stations during two cruises in the Yellow Sea in summer and winter, 2011 were analyzed by inductively coupled plasma-mass spectrometry. The pollution status was assessed via the Geoaccumulation index and Hankanson potential ecological risk index. Higher concentrations of heavy metals (except for Mn) were found in the central Southern Yellow Sea and the western Northern Yellow Sea. The higher contents of Mn were much closer to Shandong Peninsula. Correlation analyses indicated that Pb, Cu, Fe, Ni, Zn and Co probably had the same origin and were controlled by grain size and total organic carbon. Pollution assessment showed that most areas of the Yellow Sea were not or lowly contaminated with the exception of the northwest and south parts of the Southern Yellow Sea showing Cd-contamination. The pollution status of the Yellow Sea in summer was worse than that in winter. Copyright © 2014 Elsevier Ltd. All rights reserved.

  1. Spatial distribution and ecological risk assessment of metals in sediments of Baiyangdian wetland ecosystem

    DEFF Research Database (Denmark)

    Su, Liya; Liu, Jingling; Christensen, Per

    2011-01-01

    is the biggest wetland in Northeast China. We apply three methodologies. The first is literature analysis comparing total concentrations of heavy metals with other water bodies around world. The second is Chinese Environmental Quality Standard for Soils (EQSS), National Environmental Protection Agency of China...... 1995, and the third is Soil and Aquatic Sediment Guidelines and Standards issued by New York Department of Environmental Conservation (NYSDEC). The results show that compared to other water bodies around the world, the seven heavy metals are low. However, Cd was found in the most polluting level...... of EQSS near a village and was second grade some distance from it. The village was also the most polluted site of Zn, which was in the second grade. When assessed by NYSDEC, Cu, Cr, and As contaminated the sediment and with moderate impacts on benthic life while Pb, Hg, and Zn were found at tolerable...

  2. Lead (Pb) and other metals in New York City community garden soils: Factors influencing contaminant distributions

    International Nuclear Information System (INIS)

    Mitchell, Rebecca G.; Spliethoff, Henry M.; Ribaudo, Lisa N.; Lopp, Donna M.; Shayler, Hannah A.; Marquez-Bravo, Lydia G.; Lambert, Veronique T.; Ferenz, Gretchen S.; Russell-Anelli, Jonathan M.; Stone, Edie B.; McBride, Murray B.

    2014-01-01

    Urban gardens provide affordable fresh produce to communities with limited access to healthy food but may also increase exposure to lead (Pb) and other soil contaminants. Metals analysis of 564 soil samples from 54 New York City (NYC) community gardens found at least one sample exceeding health-based guidance values in 70% of gardens. However, most samples (78%) did not exceed guidance values, and medians were generally below those reported in NYC soil and other urban gardening studies. Barium (Ba) and Pb most frequently exceeded guidance values and along with cadmium (Cd) were strongly correlated with zinc (Zn), a commonly measured nutrient. Principal component analysis suggested that contaminants varied independently from organic matter and geogenic metals. Contaminants were associated with visible debris and a lack of raised beds; management practices (e.g., importing uncontaminated soil) have likely reduced metals concentrations. Continued exposure reduction efforts would benefit communities already burdened by environmental exposures. - Highlights: • We measured metals concentrations in soil from 54 New York City community gardens. • Pb and Ba exceeded health-based guidance values in 9%–12% of garden beds. • Pb concentrations were similar to those in other studies of urban garden soils. • Pb and Ba were associated with Zn, with visible debris, and with non-raised beds. • Observable details can help gardeners focus testing and exposure reduction efforts. - Pb and Ba, which exceeded health-based guidance values in 10–14% of NYC community garden soil samples, are associated with non-raised beds, visible debris, higher pH and Zn

  3. Spatial Distributions of Metal Atoms During Carbon SWNTs Formation: Measurements and Modelling

    Science.gov (United States)

    Cau, M.; Dorval, N.; Attal-Tretout, B.; Cochon, J. L.; Loiseau, A.; Farhat, S.; Hinkov, I.; Scott, C. D.

    2004-01-01

    Experiments and modelling have been undertaken to clarify the role of metal catalysts during single-wall carbon nanotube formation. For instance, we wonder whether the metal catalyst is active as an atom, a cluster, a liquid or solid nanoparticle [1]. A reactor has been developed for synthesis by continuous CO2-laser vaporisation of a carbon-nickel-cobalt target in laminar helium flow. The laser induced fluorescence technique [2] is applied for local probing of gaseous Ni, Co and CZ species throughout the hot carbon flow of the target heated up to 3500 K. A rapid depletion of C2 in contrast to the spatial extent of metal atoms is observed in the plume (Fig. 1). This asserts that C2 condenses earlier than Ni and Co atoms.[3, 4]. The depletion is even faster when catalysts are present. It may indicate that an interaction b