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Sample records for fe xxvi rrc

  1. Charge Exchange Induced X-ray Emission of Fe XXV and Fe XXVI via a Streamlined Model

    CERN Document Server

    Mullen, P D; Lyons, D; Stancil, P C

    2016-01-01

    Charge exchange is an important process for the modeling of X-ray spectra obtained by the Chandra, XMM-Newton, and Suzaku X-ray observatories, as well as the anticipated Astro-H mission. The understanding of the observed X-ray spectra produced by many astrophysical environments is hindered by the current incompleteness of available atomic and molecular data -- especially for charge exchange. Here, we implement a streamlined program set that applies quantum defect methods and the Landau-Zener theory to generate total, n-resolved, and nlS-resolved cross sections for any given projectile ion/ target charge exchange collision. Using this data in a cascade model for X-ray emission, theoretical spectra for such systems can be predicted. With these techniques, Fe25+ and Fe26+ charge exchange collisions with H, He, H2, N2, H2O, and CO are studied for single electron capture. These systems have been selected as they illustrate computational difficulties for high projectile charges. Further, Fe XXV and Fe XXVI emission...

  2. Charge Exchange-induced X-Ray Emission of Fe xxv and Fe xxvI via a Streamlined Model

    Science.gov (United States)

    Mullen, P. D.; Cumbee, R. S.; Lyons, D.; Stancil, P. C.

    2016-06-01

    Charge exchange (CX) is an important process for the modeling of X-ray spectra obtained by the Chandra, XMM-Newton, and Suzaku X-ray observatories, as well as the anticipated Astro-H mission. The understanding of the observed X-ray spectra produced by many astrophysical environments is hindered by the current incompleteness of available atomic and molecular data—especially for CX. Here, we implement a streamlined program set that applies quantum defect methods and the Landau-Zener theory to generate total, n-resolved, and n{\\ell }S-resolved cross sections for any given projectile ion/target CX collision. By using these data in a cascade model for X-ray emission, theoretical spectra for such systems can be predicted. With these techniques, Fe25+ and Fe26+ CX collisions with H, He, H2, N2, H2O, and CO are studied for single-electron capture (SEC). These systems have been selected because they illustrate computational difficulties for high projectile charges. Furthermore, Fe xxv and Fe xxvi emission lines have been detected in the Galactic center and Galactic ridge. Theoretical X-ray spectra for these collision systems are compared to experimental data generated by an electron-beam ion trap study. Several ℓ-distribution models have been tested for Fe25+ and Fe26+ SEC. Such analyses suggests that commonly used ℓ-distribution models struggle to accurately reflect the true distribution of electron capture as understood by more advanced theoretical methods.

  3. The Absolute Magnitude of RRc Variables From Statistical Parallax

    CERN Document Server

    Kollmeier, Juna A; Burns, Christopher R; Gould, Andrew; Thompson, Ian B; Preston, George W; Sneden, Christopher; Crane, Jeffrey D; Dong, Subo; Madore, Barry F; Morrell, Nidia; Prieto, Jose L; Shectman, Stephen; Simon, Joshua D; Villanueva, Edward

    2012-01-01

    We present the first definitive measurement of the absolute magnitude of RR Lyrae c-type variable stars (RRc) determined purely from statistical parallax. We use a sample of 247 RRc selected from the All Sky Automated Survey (ASAS) for which high-quality light curves, photometry and proper motions are available. We obtain high-resolution echelle spectra for these objects to determine radial velocities and abundances as part of the Carnegie RR Lyrae Survey (CARRS). We find that M_(V,RRc) = 0.52 +/- 0.11 at a mean metallicity of [Fe/H] = -1.59. This is to be compared with previous estimates for RRab stars (M_(V,RRab) = 0.75 +/- 0.13 and the only direct measurement of an RRc absolute magnitude (RZ Cephei, M_(V, RRc) = 0.27 +/- 0.17). We find the bulk velocity of the halo to be (W_pi, W_theta, W_z) = (10.9,34.9,7.2) km/s in the radial, rotational and vertical directions with dispersions (sigma_(W_pi), sigma_(W_theta), sigma_(W_z)) = (154.7, 103.6, 93.8) km/s. For the disk, we find (W_pi, W_theta, W_z) = (8.5, 213...

  4. THE ABSOLUTE MAGNITUDE OF RRc VARIABLES FROM STATISTICAL PARALLAX

    Energy Technology Data Exchange (ETDEWEB)

    Kollmeier, Juna A.; Burns, Christopher R.; Thompson, Ian B.; Preston, George W.; Crane, Jeffrey D.; Madore, Barry F.; Morrell, Nidia; Prieto, José L.; Shectman, Stephen; Simon, Joshua D.; Villanueva, Edward [Observatories of the Carnegie Institution of Washington, 813 Santa Barbara Street, Pasadena, CA 91101 (United States); Szczygieł, Dorota M.; Gould, Andrew [Department of Astronomy, The Ohio State University, 4051 McPherson Laboratory, Columbus, OH 43210 (United States); Sneden, Christopher [Department of Astronomy, University of Texas at Austin, TX 78712 (United States); Dong, Subo [Institute for Advanced Study, 500 Einstein Drive, Princeton, NJ 08540 (United States)

    2013-09-20

    We present the first definitive measurement of the absolute magnitude of RR Lyrae c-type variable stars (RRc) determined purely from statistical parallax. We use a sample of 242 RRc variables selected from the All Sky Automated Survey for which high-quality light curves, photometry, and proper motions are available. We obtain high-resolution echelle spectra for these objects to determine radial velocities and abundances as part of the Carnegie RR Lyrae Survey. We find that M{sub V,RRc} = 0.59 ± 0.10 at a mean metallicity of [Fe/H] = –1.59. This is to be compared with previous estimates for RRab stars (M{sub V,RRab} = 0.76 ± 0.12) and the only direct measurement of an RRc absolute magnitude (RZ Cephei, M{sub V,RRc} = 0.27 ± 0.17). We find the bulk velocity of the halo relative to the Sun to be (W{sub π}, W{sub θ}, W{sub z} ) = (12.0, –209.9, 3.0) km s{sup –1} in the radial, rotational, and vertical directions with dispersions (σ{sub W{sub π}},σ{sub W{sub θ}},σ{sub W{sub z}}) = (150.4, 106.1, 96.0) km s{sup -1}. For the disk, we find (W{sub π}, W{sub θ}, W{sub z} ) = (13.0, –42.0, –27.3) km s{sup –1} relative to the Sun with dispersions (σ{sub W{sub π}},σ{sub W{sub θ}},σ{sub W{sub z}}) = (67.7,59.2,54.9) km s{sup -1}. Finally, as a byproduct of our statistical framework, we are able to demonstrate that UCAC2 proper-motion errors are significantly overestimated as verified by UCAC4.

  5. Burkholderia cepacia XXVI siderophore with biocontrol capacity against Colletotrichum gloeosporioides.

    Science.gov (United States)

    de Los Santos-Villalobos, Sergio; Barrera-Galicia, Guadalupe Coyolxauhqui; Miranda-Salcedo, Mario Alberto; Peña-Cabriales, Juan José

    2012-08-01

    Colletotrichum gloeosporioides is the causal agent of anthracnose in mango. Burkholderia cepacia XXVI, isolated from mango rhizosphere and identified by 16S rDNA sequencing as a member of B. cepacia complex, was more effective than 6 other mango rhizosphere bacteria in inhibiting the model mango pathogen, C. gloeosporioides ATCC MYA 456. Biocontrol of this pathogen was demonstrated on Petri-dishes containing PDA by > 90 % reduction of surface colonization. The nature of the biocontrol metabolite(s) was characterized via a variety of tests. The inhibition was almost exclusively due to production of agar-diffusible, not volatile, metabolite(s). The diffusible metabolite(s) underwent thermal degradation at 70 and 121 °C (1 atm). Tests for indole acetic acid production and lytic enzyme activities (cellulase, glucanase and chitinase) by B. cepacia XXVI were negative, indicating that these metabolites were not involved in the biocontrol effect. Based on halo formation and growth inhibition of the pathogen on the diagnostic medium, CAS-agar, as well as colorimetric tests we surmised that strain XXVI produced a hydroxamate siderophore involved in the biocontrol effect observed. The minimal inhibitory concentration test showed that 0.64 μg ml(-1) of siderophore (Deferoxamine mesylate salt-equivalent) was sufficient to achieve 91.1 % inhibition of the pathogen growth on Petri-dishes containing PDA. The biocontrol capacity against C. gloeosporioides ATCC MYA 456 correlated directly with the siderophore production by B. cepacia XXVI: the highest concentration of siderophore production in PDB on day 7, 1.7 μg ml(-1) (Deferoxamine mesylate salt-equivalent), promoted a pathogen growth inhibition of 94.9 %. The growth of 5 additional strains of C. gloeosporioides (isolated from mango "Ataulfo" orchards located in the municipality of Chahuites, State of Oaxaca in Mexico) was also inhibited when confronted with B. cepacia XXVI. Results indicate that B. cepacia XXVI or its

  6. PULSATION PERIOD VARIATIONS IN THE RRc LYRAE STAR KIC 5520878

    Energy Technology Data Exchange (ETDEWEB)

    Hippke, Michael [Institute for Data Analysis, Luiter Str. 21b, D-47506 Neukirchen-Vluyn (Germany); Learned, John G. [High Energy Physics Group, Department of Physics and Astronomy, University of Hawaii, Manoa 327 Watanabe Hall, 2505 Correa Road, Honolulu, HI 96822 (United States); Zee, A. [Kavli Institute for Theoretical Physics, University of California, Santa Barbara, CA 93106 (United States); Edmondson, William H. [School of Computer Science, University of Birmingham, Birmingham B15 2TT (United Kingdom); Lindner, John F. [Physics Department, The College of Wooster, Wooster, OH 44691 (United States); Kia, Behnam; Ditto, William L. [Department of Physics and Astronomy, University of Hawai' i at Mānoa, Honolulu, HI 96822 (United States); Stevens, Ian R., E-mail: hippke@ifda.eu, E-mail: jgl@phys.hawaii.edu, E-mail: zee@kitp.ucsb.edu, E-mail: w.h.edmondson@bham.ac.uk, E-mail: jlindner@wooster.edu, E-mail: wditto@hawaii.edu, E-mail: behnam@hawaii.edu, E-mail: irs@star.sr.bham.ac.uk [School of Physics and Astronomy, University of Birmingham, Birmingham B15 2TT (United Kingdom)

    2015-01-01

    Learned et al. proposed that a sufficiently advanced extra-terrestrial civilization may tickle Cepheid and RR Lyrae variable stars with a neutrino beam at the right time, thus causing them to trigger early and jogging the otherwise very regular phase of their expansion and contraction. This would turn these stars into beacons to transmit information throughout the galaxy and beyond. The idea is to search for signs of phase modulation (in the regime of short pulse duration) and patterns, which could be indicative of intentional, omnidirectional signaling. We have performed such a search among variable stars using photometric data from the Kepler space telescope. In the RRc Lyrae star KIC 5520878, we have found two such regimes of long and short pulse durations. The sequence of period lengths, expressed as time series data, is strongly autocorrelated, with correlation coefficients of prime numbers being significantly higher (p = 99.8%). Our analysis of this candidate star shows that the prime number oddity originates from two simultaneous pulsation periods and is likely of natural origin. Simple physical models elucidate the frequency content and asymmetries of the KIC 5520878 light curve. Despite this SETI null result, we encourage testing of other archival and future time-series photometry for signs of modulated stars. This can be done as a by-product to the standard analysis, and can even be partly automated.

  7. Pulsation period variations in the RRc Lyrae star KIC 5520878

    CERN Document Server

    Hippke, Michael; Zee, A; Edmondson, William H; Steven, Ian R; Lindner, John F; Kia, Benham; Ditto, William L

    2014-01-01

    Learned et. al. proposed that a sufficiently advanced extra-terrestrial civilization may tickle Cepheid and RR Lyrae variable stars with a neutrino beam at the right time, thus causing them to trigger early and jogging the otherwise very regular phase of their expansion and contraction. This would turn these stars into beacons to transmit information throughout the galaxy and beyond. The idea is to search for signs of phase modulation (in the regime of short pulse duration) and patterns, which could be indicative of intentional, omnidirectional signaling. We have performed such a search among variable stars using photometric data from the Kepler space telescope. In the RRc Lyrae star KIC 5520878, we have found two such regimes of long and short pulse durations. The sequence of period lengths, expressed as time series data, is strongly auto correlated, with correlation coefficients of prime numbers being significantly higher ($p=99.8$\\%). Our analysis of this candidate star shows that the prime number oddity o...

  8. Dependable Distributed Computing for the International Telecommunication Union Regional Radio Conference RRC06

    CERN Document Server

    Moscicki, Jakub T; Lamanna, Massimo; Méndez, Patricia; Muraru, Adrian

    2009-01-01

    The International Telecommunication Union (ITU) Regional Radio Conference (RRC06) established in 2006 a new frequency plan for the introduction of digital broadcasting in European, African, Arab, CIS countries and Iran. The preparation of the plan involved complex calculations under short deadline and required dependable and efficient computing capability. The ITU designed and deployed in-situ a dedicated PC farm, in parallel to the European Organization for Nuclear Research (CERN) which provided and supported a system based on the EGEE Grid. The planning cycle at the RRC06 required a periodic execution in the order of 200,000 short jobs, using several hundreds of CPU hours, in a period of less than 12 hours. The nature of the problem required dynamic workload-balancing and low-latency access to the computing resources. We present the strategy and key technical choices that delivered a reliable service to the RRC06.

  9. Digital broadcasting set to transform communication landscape by 2015: RRC-06

    CERN Multimedia

    2006-01-01

    "The conclusion of ITU's Regional Radiocommuncation Conference (RRC-06) in Geneva saw the signing of a treaty agreement that is a major step in implementing World Summit on the Information Society objectives. The digitalization of broadcasting in Europe, Africa, Middle East and the Islamic Republic of Iran by 2015 represents a major landmark towards establishing a more equitable, just and people-centred Information Society." (2 pages)

  10. Kepler photometry of RRc stars: peculiar double-mode pulsations and period doubling

    CERN Document Server

    Moskalik, P; Kolenberg, K; Molnár, L; Kurtz, D W; Szabó, R; Benkő, J M; Nemec, J M; Chadid, M; Guggenberger, E; Ngeow, C -C; Jeon, Y -B; Kopacki, G; Kanbur, S M

    2014-01-01

    We present the analysis of four first overtone RR Lyrae stars observed with the Kepler space telescope, based on data obtained over nearly 2.5yr. All four stars are found to be multiperiodic. The strongest secondary mode with frequency f_2 has an amplitude of a few mmag, 20 - 45 times lower than the main radial mode with frequency f_1. The two oscillations have a period ratio of P_2/P_1 = 0.612 - 0.632 that cannot be reproduced by any two radial modes. Thus, the secondary mode is nonradial. Modes yielding similar period ratios have also recently been discovered in other variables of the RRc and RRd types. These objects form a homogenous group and constitute a new class of multimode RR Lyrae pulsators, analogous to a similar class of multimode classical Cepheids in the Magellanic Clouds. Because a secondary mode with P_2/P_1 ~ 0.61 is found in almost every RRc and RRd star observed from space, this form of multiperiodicity must be common. In all four Kepler RRc stars studied, we find subharmonics of f_2 at ~1/...

  11. Lemonade from lemons: a program response to RRC-determined probation.

    Science.gov (United States)

    Fassler; Dobkin; Horowitz; Morejon; Reilly; Civetta

    2000-07-01

    To assess resident satisfaction as a result of changes made to an integrated surgical residency in response to probation.The University of Connecticut Integrated General Surgery Residency (UCIGSR), which consists of 5 hospitals, 18 rotations, and has a complement of 44 residents, was placed on probation by the Residency Review Committee (RRC) in Surgery in November 1998. Among the deficiencies cited by the RRC were inadequate evaluation of the program, rotations, residents, and the faculty by the residents, along with inadequate documentation issues. Lack of organized educational conferences, lack of faculty involvement, excessive service responsibilities and work hours, and hospital environmental issues were also cited. It was also apparent that morale of the residents and faculty had significantly eroded. Rather than trying patchwork "fixes" of deficiencies, we used this opportunity to reengineer the program, rededicating ourselves to educating and developing future surgeons. Task forces, including joint faculty and resident participation, were set up to develop solutions, based on the answer to the question: "Do we want a residency or not?" This focus was especially helpful to create hospital administration and faculty support.A survey was created to assess the changes made in the program. The survey included 65 questions pertaining to the learning environment, hospital and departmental support, and balance between clinical and educational responsibilities and overall working environment. Each resident was asked to fill out 3 identical surveys, 1 just before the RRC report, and the other 2 at 6-month intervals after the probation announcement. A 4-point grading scale was used.Our results were reflective of resident perceptions of improvement and increased satisfaction. These data demonstrated that the changes implemented as a result of the RRC findings had a positive effect on the residency program, and they corresponded to the areas where changes were

  12. Discovery of Peculiar Double-Mode Pulsations and Period Doubling in KEPLER RRc Variables

    CERN Document Server

    Moskalik, P; Kolenberg, K; Nemec, J; Kunder, A; Chadid, M; Kopacki, G; Szabó, R; members, KEPLER WG#13

    2012-01-01

    We analyzed the Long Cadence photometry of 4 first overtone RR Lyr-type stars (RRc stars) observed by the KEPLER telescope. All studied variables are multiperiodic. The strongest secondary peak appears for f_2/f_1 = 1.58-1.63, or P_2/P_1 = 0.61-0.63. In each star we detect at least one subharmonic of f_2, either at ~1/2 f_2 or at ~3/2 f_2. The presence of subharmonics is a characteristic signature of a period doubling.

  13. Establishment of a new dynamic RRC model in smoke toxicity evaluation and engineering application

    Institute of Scientific and Technical Information of China (English)

    YANG Lizhong; FANG Tingyong; ZHOU Xiaodong; FENG Wenxing; HUANG Rui; ZHAI Guanglong; FAN Weicheng

    2005-01-01

    It is by now a well established fact that the overwhelming hazard from fire is smoke as far as the death of people in the fire is concerned. There are many methodologies for addressing the smoke toxicity component of fire hazard such as CO stochastic model,FED (fractional effective dose) model, FEC (fractional effective concentration) model, N-gas model and so on. None of these models can reflect spatio-temporal variation of the smoke concentration. A new dynamic smoke toxicity evaluation model, RRC (respiration, route and concentration) model, is proposed in this paper concerning the three decisive factors in real fire such as the respiration, movement route of people and the distribution of smoke concentration in the building. Furthermore, an example of the model is presented.

  14. MISCELLANEOUS BOTANICAL NOTES XXVI

    Directory of Open Access Journals (Sweden)

    C. G. G. J. VAN STEENIS

    2014-01-01

    Full Text Available Pertelaan polong dan pohon tipe Ormosia incerta Koord. (yang direduksi ke O. penangensis Ridl. dari Jawa diberikan. Trifidacanthus Merr. direduksi menjadi Desmodium dan suatu kombinasi baru diusulkan. Platyspermation Guillaumin, semula dimasukkan dalam Myrtaeeae, dipindah ke Saxifragaceae. Juncus bufonius L. direkam sebagai pendatang di G. Kinabalu. Dua Fimbristylis direkam dari Australia Utara dan Oreobolus kiikenthalii Steen.  direkam   dari  G.   Mulu   (Sarawak.

  15. LTE网络RRC连接问题的排查与分析%Analysis and solution of RRC connection problems in LTE network

    Institute of Scientific and Technical Information of China (English)

    徐娟

    2015-01-01

    During the period of LTE wireless network operation, network KPI is the concern of the operators. All kinds of operations of LTE test should also be in accordance with the standard specification to strictly carry out. Through the analysis of a high RRC connection drop rate case in an interoperability test caused by wrong operation, this paper provides a way to investigate invisible faults causes by using LTE professional network management, test and analysis software, labor participation and map to locate the problem area.%在LTE无线网络运营期间,网络KPI指标是目前运营商关注的重点,对LTE网络的各类操作测试也应按标准规范来严格开展。文章主要通过对一次互操作测试过程中因错误操作引起全网RRC连接掉话率过高案例的分析,提供一种利用LTE专业网管、测试分析软件、工参及地图来定位问题小区,以及排查隐形故障原因的方法。

  16. Fe K emission from active galaxies in the COSMOS field

    CERN Document Server

    Iwasawa, K; Brusa, M; Comastri, A; Gilli, R; Vignali, C; Hasinger, G; Sanders, D B; Cappelluti, N; Impey, C D; Koekemoer, A; Lanzuisi, G; Lusso, E; Merloni, A; Salvato, M; Taniguchi, Y; Trump, J R

    2011-01-01

    We present a rest-frame spectral stacking analysis of ~1000 X-ray sources detected in the XMM-COSMOS field in order to investigate the iron K line properties of active galaxies beyond redshift z~1. In Type I AGN that have a typical X-ray luminosity of Lx~1.5e44 erg/s and z~1.6, the cold Fe K at 6.4 keV is weak (EW~0.05keV), in agreement with the known trend. In contrast, high-ionization lines of Fe XXV and Fe XXVI are pronounced. These high-ionization Fe K lines appear to have a connection with high accretion rates. While no broad Fe emission is detected in the total spectrum, it might be present, albeit at low significance, when the X-ray luminosity is restricted to the range below 3e44 erg/s, or when an intermediate range of Eddington ratio around 0.1 is selected. In Type II AGN, both cold and high-ionzation lines become weak with increasing X-ray luminosity. However, strong high-ionization Fe K (EW~0.3 keV) is detected in the spectrum of objects at z>2, while no 6.4 keV line is found. It is then found that...

  17. The Solar Neighborhood. XXVI. AP Col: The Closest (8.4 pc) Pre-Main-Sequence Star

    CERN Document Server

    Riedel, Adric R; Henry, Todd J; Melis, Carl; Jao, Wei-Chun; Subasavage, John P; 10.1088/0004-6256/142/4/104

    2011-01-01

    We present the results of a multi-technique investigation of the M4.5Ve flare star AP Col, which we discover to be the nearest pre-main-sequence star. These include astrometric data from the CTIO 0.9m, from which we derive a proper motion of 342.0+/-0.5 mas yr^-1, a trigonometric parallax of 119.21+/-0.98 mas (8.39+/-0.07 pc), and photometry and photometric variability at optical wavelengths. We also provide spectroscopic data, including radial velocity (22.4+/-0.3 km s^-1), lithium Equivalent Width (EW) (0.28+/-0.02 A), H-alpha EW (-6.0 to -35 A), {\\it vsini} (11+/-1 km s^-1), and gravity indicators from the Siding Spring 2.3-m WiFeS, Lick 3-m Hamilton echelle, and Keck-I HIRES echelle spectrographs. The combined observations demonstrate that AP Col is the closer of only two known systems within 10 pc of the Sun younger than 100 Myr. Given its space motion and apparent age of 12-50 Myr, AP Col is likely a member of the recently proposed ~40 Myr old Argus/IC 2391 association.

  18. Dependence of the broad Fe K$\\alpha$ line on the physical parameters of AGN

    CERN Document Server

    Liu, Zhu; Lu, Youjun; Carrera, Francisco J; Falocco, Serena; Dong, Xiao-Bo

    2016-01-01

    In this paper, the dependence of the broad Fe K$\\alpha$ line on the physical parameters of AGN, such as the black hole mass $M_{BH}$, accretion rate (equivalently represented by Eddington ratio $\\lambda_{Edd}$), and optical classification, is investigated by applying the X-ray spectra stacking method to a large sample of AGN which have well measured optical parameters. A broad line feature is detected ($>3\\sigma$) in the stacked spectra of the high $\\lambda_{Edd}$ sub-sample ($\\log\\lambda_{Edd}>-0.9$). The profile of the broad line can be well fitted with relativistic broad line model, with the line energy consistent with highly ionized Fe K$\\alpha$ line (i.e. Fe xxvi). A model consisting of multiple narrow lines cannot be ruled out, however. We found hints that the Fe K line becomes broader as the $\\lambda_{Edd}$ increases. No broad line feature is shown in the sub-sample of broad-line Seyfert 1 (BLS1) galaxies and in the full sample, while a broad line might be present, though at low significance, in the su...

  19. Constraining RRc candidates using SDSS colours

    CERN Document Server

    Bányai, E; Molnár, L; Dobos, L; Szabó, R

    2016-01-01

    The light variations of first-overtone RR Lyrae stars and contact eclipsing binaries can be difficult to distinguish. The Catalina Periodic Variable Star catalog contains several misclassified objects, despite the classification efforts by Drake et al. (2014). They used metallicity and surface gravity derived from spectroscopic data (from the SDSS database) to rule out binaries. Our aim is to further constrain the catalog using SDSS colours to estimate physical parameters for stars that did not have spectroscopic data.

  20. On the Fe K absorption - accretion state connection in the Galactic center neutron star X-ray binary AX J1745.6-2901

    CERN Document Server

    Ponti, G; Munoz-Darias, T; DeMarco, B; Dwelly, T; Fender, R P; Nandra, K; Rea, N; Mori, K; Haggard, D; Heinke, C O; Degenaar, N; Aramaki, T; Clavel, M; Goldwurm, A; Hailey, C J; Israel, G L; Morris, M R; Rushton, A; Terrier, R

    2014-01-01

    AX J1745.6-2901 is a high-inclination (eclipsing) neutron star Low Mass X-ray Binary (LMXB) located less than ~1.5 arcmin from Sgr A*. Ongoing monitoring campaigns have targeted Sgr A* frequently and these observations also cover AX J1745.6-2901. We present here an X-ray analysis of AX J1745.6-2901 using a large dataset of 38 XMM-Newton observations, including eleven which caught AX J1745.6-2901 in outburst. Fe K absorption is clearly seen when AX J1745.6-2901 is in the soft state, but disappears during the hard state. The variability of these absorption features does not appear to be due to changes in the ionizing continuum. The small Kalpha/Kbeta ratio of the equivalent widths of the Fe xxv and Fe xxvi lines suggests that the column densities and turbulent velocities of the absorbing ionised plasma are in excess of N_H ~ 10^23 cm^-2 and v_turb >~ 500 km s^-1. These findings strongly support a connection between the wind (Fe K absorber) and the accretion state of the binary. These results reveal strong simil...

  1. Dante Alighieri, Purgatorio XXVI.139-148

    Directory of Open Access Journals (Sweden)

    Simone Marchesi

    2011-04-01

    Full Text Available Dante's famous ten lines on Arnaut Daniel, the "miglior fabbro," the best craftsman in the native tongue, are also the last lines of the canto, the most quoted in English (thanks to T.S. Eliot's citation in The Wasteland, the most extended stretch of non-Italian vernacular in the Commedia, the center of a reflection on the nature of language (Virgil-Arnaut-Adam and the center of a triangle of oc poets in the poem (between Bertran de Born in Inferno and Foulquet de Marseilles in Paradiso. The thematic triangle of poetic concealment, erotic fire, and affinar (purification derived from Arnaut's poetry is redeployed by Dante as a reflection on the nature of language and the promise of poetry.

  2. Evidence for Ultra-fast Outflows in Radio-quiet Active Galactic Nuclei. II. Detailed Photoionization Modeling of Fe K-shell Absorption Lines

    Science.gov (United States)

    Tombesi, F.; Cappi, M.; Reeves, J. N.; Palumbo, G. G. C.; Braito, V.; Dadina, M.

    2011-11-01

    X-ray absorption line spectroscopy has recently shown evidence for previously unknown Ultra-fast Outflows (UFOs) in radio-quiet active galactic nuclei (AGNs). These have been detected essentially through blueshifted Fe XXV/XXVI K-shell transitions. In the previous paper of this series we defined UFOs as those highly ionized absorbers with an outflow velocity higher than 10,000 km s-1 and assessed the statistical significance of the associated blueshifted absorption lines in a large sample of 42 local radio-quiet AGNs observed with XMM-Newton. The present paper is an extension of that work. First, we report a detailed curve of growth analysis of the main Fe XXV/XXVI transitions in photoionized plasmas. Then, we estimate an average spectral energy distribution for the sample sources and directly model the Fe K absorbers in the XMM-Newton spectra with the detailed Xstar photoionization code. We confirm that the frequency of sources in the radio-quiet sample showing UFOs is >35% and that the majority of the Fe K absorbers are indeed associated with UFOs. The outflow velocity distribution spans from ~10,000 km s-1 (~0.03c) up to ~100,000 km s-1 (~0.3c), with a peak and mean value of ~42,000 km s-1 (~0.14c). The ionization parameter is very high and in the range log ξ ~ 3-6 erg s-1 cm, with a mean value of log ξ ~ 4.2 erg s-1 cm. The associated column densities are also large, in the range N H ~ 1022-1024 cm-2, with a mean value of N H ~ 1023 cm-2. We discuss and estimate how selection effects, such as those related to the limited instrumental sensitivity at energies above 7 keV, may hamper the detection of even higher velocities and higher ionization absorbers. We argue that, overall, these results point to the presence of extremely ionized and possibly almost Compton-thick outflowing material in the innermost regions of AGNs. This also suggests that UFOs may potentially play a significant role in the expected cosmological feedback from AGNs and their study can

  3. Magnetic Properties and Microstructure of FeOx/Fe/FePt and FeOx/FePt Films

    Directory of Open Access Journals (Sweden)

    Jai-Lin Tsai

    2013-01-01

    Full Text Available The Fe(6 nm/FePt film with perpendicular magnetization was deposited on the glass substrate. To study the oxygen diffusion effect on the coupling of Fe/FePt bilayer, the plasma oxidation with 0.5~7% oxygen flow ratio was performed during sputtered part of Fe layer and formed the FeOx(3 nm/Fe(3 nm/FePt trilayer. Two-step magnetic hysteresis loops were found in trilayer with oxygen flow ratio above 1%. The magnetization in FeOx and Fe/FePt layers was decoupled. The moments in FeOx layer were first reversed and followed by coupled Fe/FePt bilayer. The trilayer was annealed again at 500°C and 800°C for 3 minutes. When the FeOx(3 nm/Fe(3 nm/FePt trilayer was annealed at 500°C, the layers structure was changed to FeOx(6 nm/FePt bilayer due to oxygen diffusion. The hard-magnetic FeOx(6 nm/FePt film was coupled with single switching field. The FeOx/(disordered FePt layer structure was observed with further annealing at 800°C and presented soft-magnetic loop. In summary, the coupling between soft-magnetic Fe, FeOx layer, and hard-magnetic L10 FePt layer can be controlled by the oxygen diffusion behavior, and the oxidation of Fe layer was tuned by the annealing temperature. The ordered L10 FePt layer was deteriorated by oxygen and became disordered FePt when the annealed temperature was up to 800°C.

  4. TAXONOMY OF CLADOSPORIUMIN CHINA XXVI.%中国枝孢属研究XXVI.

    Institute of Scientific and Technical Information of China (English)

    何永宏; 张中义

    2001-01-01

    本文报道枝孢属Cladosporium的二个新种:忍冬生枝孢C. lonicericola和山菅兰生枝孢C. dianellicola.新种提供了拉丁文简介、中文描述及形态图.模式标本收藏于云南农业大学真菌标本室(MHYAU).

  5. The weak neutral Fe fluorescence line and long-term X-ray evolution of the Compton-thick AGN in NGC 7674

    CERN Document Server

    Gandhi, P; Lansbury, G B; Stern, D; Alexander, D M; Bauer, F E; Bianchi, S; Boggs, S E; Boorman, P G; Brandt, W N; Brightman, M; Christensen, F E; Comastri, A; Craig, W W; Del Moro, A; Elvis, M; Guainazzi, M; Hailey, C J; Harrison, F A; Koss, M; Lamperti, I; Malaguti, G; Masini, A; Matt, G; Puccetti, S; Ricci, C; Rivers, E; Walton, D J; Zhang, W W

    2016-01-01

    We present NuSTAR X-ray observations of the active galactic nucleus (AGN) in NGC 7674. The source shows a flat X-ray spectrum, suggesting that it is obscured by Compton-thick gas columns. Based upon long-term flux dimming, previous work suggested the alternate possibility that the source is a recently switched-off AGN with the observed X-rays being the lagged echo from the torus. Our high-quality data show the source to be reflection-dominated in hard X-rays, but with a relatively weak neutral Fe Kalpha emission line (equivalent width [EW] of ~0.4 keV) and a strong Fe XXVI ionised line (EW~0.2 keV). We construct an X-ray light curve of NGC 7674 spanning 37 years and find that the observed 2-10 keV X-ray flux has remained constant for the past ~20 years. Light travel time arguments constrain the minimum radius of the reflector to be ~3.2 pc under the switched-off AGN scenario, ~30x larger than the expected dust sublimation radius, rendering this possibility unlikely. A combination of intrinsic fading and patch...

  6. An Fe XXIV Absorption Line in the Persistent Spectrum of the Dipping Low-Mass X-Ray Binary 1A 1744-361

    Science.gov (United States)

    Gavriil, Fotis P.; Strohmayer, Tod E.; Bhattacharyya, Sudip

    2012-01-01

    We report on Chandra X-ray Observatory (Chandra) High Energy Transmission Grating spectra of the dipping low-mass X-ray binary 1A 1744-361 during its 2008 July outburst. We find that its persistent emission is well modeled by a blackbody (kT approx. 1.0 keV) plus power law (Gamma approx. 1.7) with an absorption edge. In the residuals of the combined spectrum, we find a significant absorption line at 6.961 +/- 0.002 keV, consistent with the Fe xxvi (hydrogen-like Fe) 2-1 transition.We place an upper limit on the velocity of a redshifted flow of nu 103.6 erg cm/s. We discuss what implications the feature has on the system and its geometry. We also present Rossi X-ray Timing Explorer data accumulated during this latest outburst and, via an updated color-color diagram, clearly show that 1A 1744-361 is an "atoll" source

  7. Evidence for ultra-fast outflows in radio-quiet AGNs: I - detection and statistical incidence of Fe K-shell absorption lines

    CERN Document Server

    Tombesi, F; Reeves, J N; Palumbo, G G C; Yaqoob, T; Braito, V; Dadina, M

    2010-01-01

    We performed a blind search for narrow absorption features at energies greater than 6.4 keV in a sample of 42 radio-quiet AGNs observed with XMM-Newton. We detect 36 narrow absorption lines on a total of 101 XMM-Newton EPIC pn observations. The number of absorption lines at rest-frame energies E>7 keV is 22. Their global probability to be generated by random fluctuations is very low, less than 3x10^-8, and their detection have been independently confirmed by a spectral analysis of the MOS data, with associated random probability <10^-7. We identify the lines as Fe XXV and Fe XXVI K-shell resonant absorption. They are systematically blue-shifted, with a velocity distribution ranging from zero up to 0.3c, with a peak and mean value at 0.1c. We detect variability of the lines on both EWs and blue-shifted velocities among different observations even on time-scales as short as a few days, possibly suggesting somewhat compact absorbers. Moreover, we find no significant correlation between the cosmological red-sh...

  8. Fe atom exchange between aqueous Fe2+ and magnetite.

    Science.gov (United States)

    Gorski, Christopher A; Handler, Robert M; Beard, Brian L; Pasakarnis, Timothy; Johnson, Clark M; Scherer, Michelle M

    2012-11-20

    The reaction between magnetite and aqueous Fe(2+) has been extensively studied due to its role in contaminant reduction, trace-metal sequestration, and microbial respiration. Previous work has demonstrated that the reaction of Fe(2+) with magnetite (Fe(3)O(4)) results in the structural incorporation of Fe(2+) and an increase in the bulk Fe(2+) content of magnetite. It is unclear, however, whether significant Fe atom exchange occurs between magnetite and aqueous Fe(2+), as has been observed for other Fe oxides. Here, we measured the extent of Fe atom exchange between aqueous Fe(2+) and magnetite by reacting isotopically "normal" magnetite with (57)Fe-enriched aqueous Fe(2+). The extent of Fe atom exchange between magnetite and aqueous Fe(2+) was significant (54-71%), and went well beyond the amount of Fe atoms found at the near surface. Mössbauer spectroscopy of magnetite reacted with (56)Fe(2+) indicate that no preferential exchange of octahedral or tetrahedral sites occurred. Exchange experiments conducted with Co-ferrite (Co(2+)Fe(2)(3+)O(4)) showed little impact of Co substitution on the rate or extent of atom exchange. Bulk electron conduction, as previously invoked to explain Fe atom exchange in goethite, is a possible mechanism, but if it is occurring, conduction does not appear to be the rate-limiting step. The lack of significant impact of Co substitution on the kinetics of Fe atom exchange, and the relatively high diffusion coefficients reported for magnetite suggest that for magnetite, unlike goethite, Fe atom diffusion is a plausible mechanism to explain the rapid rates of Fe atom exchange in magnetite.

  9. Séminaire de probabilités XXVI

    CERN Document Server

    Yor, Marc; Meyer, Paul

    1992-01-01

    All the papers contained in the volume are original, fully refereed researchpapers. They represent a fairly broad spectrum of the research activity in probability theory, which was done internationally in 1990-1991, with particular emphasis on Markov processes and stochastic calculus. The latter subject keeps growing, and some important new developments, included in the volume, concern anticipative stochastic integrals, and new applications of the enlargements of filtrations to the study of zeros of martingales. FROM THE CONTENTS: R. Bass, D. Khoshnevisan: Stochastic calculus and the continuity of local times of Levy processes.- M.T. Barlow, P. Imkeller: On some sample path properties of Skorokhod integral processes.- T.S. Mountford: A critical function for the planar Brownian convex hull.- L. Dubins, M. Smorodinsky: The modified, discrete Levy transformation is Bernoulli.- M. Baxter: Markov processes on the boundary of the binary tree.- R. Abraham: Unarbre aleatoire infini associe a l'excursion brownienne.- ...

  10. Parnassiana nova : XXVI. Kritische Revision der Gattung Kailasius

    NARCIS (Netherlands)

    Eisner, C.

    1959-01-01

    Genus Kailasius Moore Kail. inopinatus inopinatus Kotzsch (Ent. Zeit. v. 54 Nr. 3 p. 18-21) Nordwest-Afghanistan, Firuskuhi-Montes, 1 ♂ Holotype, 1 ♀ Allotype, abg. Ent. Zeit. v. 54 Nr. 3 p. 18, 9 ♂, f. rubroanalis n.c. 2 ♂, 10 ♀, alle Paratypen ex c. Kotzsch; Marak, Afghanistan 1 ♂ ex c. Avinoff (C

  11. Milagro Contributions to XXVI International Cosmic Ray Conference

    Energy Technology Data Exchange (ETDEWEB)

    Hoffman, C.M.; Haines, T.J.; Sinnis, G.; Miller, R.S.; Thompson, N.T.

    1999-08-01

    Milagrito, a prototype for the Milagro detector, operated for 15 months in 1997--8 and collected 8.9 x 10{sup 9} events. It was the first extensive air shower (EAS) array sensitive to showers initiated by primaries with energy below 1 TeV. The shadows of the sun and moon observed with cosmic rays can be used to study systematic pointing shifts and measure the angular resolution of EAS arrays. Below a few TeV, the paths of cosmic rays coming toward the earth are bent by the helio- and geo-magnetic fields. This is expected to distort and displace the shadows of the sun and the moon. The moon shadow, offset from the nominal (unreflected) position, has been observed with high statistical significance in Milagrito. This can be used to establish energy calibrations, as well as to search for the anti-matter content of the VHE cosmic ray flux. The shadow of the sun has also been observed with high significance.

  12. An Overview of NWS Weather Support for the XXVI Olympiad.

    Science.gov (United States)

    Rothfusz, Lans P.; McLaughlin, Melvin R.; Rinard, Stephen K.

    1998-05-01

    The 1996 Centennial Olympic Games in Atlanta, Georgia, received weather support from the National Weather Service (NWS). The mandate to provide this support gave the NWS an unprecedented opportunity to employ in an operational setting several tools and practices similar to those planned for the "modernized" era of the NWS. The project also provided a glimpse of technology and practices not planned for the NWS modernization, but that might be valuable in the future. The underlying purpose of the project was to protect the life and property of the two million spectators, athletes, volunteers, and officials visiting and/or participating in the games. While there is no way to accurately account for lives and property that were protected by the NWS support, the absence of weather-related deaths, significant injuries, and damaged property during the games despite an almost daily occurrence of thunderstorms, high temperatures, and/or rain indicates that the project was a success. In fact, popular perception held that weather had no effect on the games. The 2000+ weather bulletins issued during the 6-week support period suggest otherwise. The authors describe the many facets of this demanding and successful project, with special attention given to aspects related to operational forecasting. A postproject survey completed by the Olympics forecasters, feedback provided by weather support customers, and experiences of the management team provide the bases for project observations and recommendations for future operational forecasting activities.

  13. Spin transition in [Fe

    Science.gov (United States)

    Garcia, Y.; Ksenofontov, V.; Campbell, S. J.; Lord, J. S.; Boland, Y.; Gütlich, P.

    2004-12-01

    The reversible thermal spin transition which occurs in [Fe(phen)2(NCS)2] around T1/2 177 K has been investigated by muon spin relaxation (μSR) (10-280 K). The depolarisation curves are well described by two Lorentzian lines represent fast and slow components in the decay curves, with the initial asymmetry parameter of the fast component found to track the spin transition in [Fe(phen)2(NCS)2]. Comparison of zero-field and transverse field (20 Oe) μSR measurements shows that diamagnetic muonic species occur over the entire temperature range.

  14. Magnetic structure of Fe-Fe oxide nanoparticles made by ...

    African Journals Online (AJOL)

    user

    cobalt oxide at the surface results in a magnetic system with unidirectional ... Fe / FeO particles were synthesized using laser pyrolysis by Dumitrache et al. ..... nanoparticles for magnetic targeted drug delivery and hyperthermia treatment.

  15. The Weak Fe Fluorescence Line and Long-Term X-Ray Evolution of the Compton-Thick Active Galactic Nucleus in NGC7674

    Science.gov (United States)

    Ghandi, P.; Annuar, A.; Lansbury, G. B.; Stern, D.; Alexander, D. M.; Bauer, F. E.; Bianchi, S.; Boggs, S. E.; Boorman, P. G.; Brandt, W. N.; hide

    2017-01-01

    We present NuSTAR X-ray observations of the active galactic nucleus (AGN) in NGC7674.The source shows a flat X-ray spectrum, suggesting that it is obscured by Compton-thick gas columns. Based upon long-term flux dimming, previous work suggested the alternate possibility that the source is a recently switched-off AGN with the observed X-rays being the lagged echo from the torus. Our high-quality data show the source to be reflection-dominated in hard X-rays, but with a relatively weak neutral Fe K(alpha) emission line (equivalent width [EW] of approximately 0.4 keV) and a strong Fe XXVI ionized line (EW approximately 0.2 keV).We construct an updated long-term X-ray light curve of NGC7674 and find that the observed 2-10 keV flux has remained constant for the past approximately 20 yr, following a high-flux state probed by Ginga. Light travel time arguments constrain the minimum radius of the reflector to be approximately 3.2 pc under the switched-off AGN scenario, approximately 30 times larger than the expected dust sublimation radius, rendering this possibility unlikely. A patchy Compton-thick AGN (CTAGN) solution is plausible, requiring a minimum line-of-sight column density (N(sub H)) of 3 x 10(exp 24) cm(exp -2) at present, and yields an intrinsic 2-10 keV luminosity of (3-5) x 10(exp 43) erg s(exp -1). Realistic uncertainties span the range of approximately (1-13) x 10(exp 43) erg s1. The source has one of the weakest fluorescence lines amongst bona fide CTAGN, and is potentially a local analogue of bolometrically luminous systems showing complex neutral and ionized Fe emission. It exemplifies the difficulty of identification and proper characterization of distant CTAGN based on the strength of the neutral Fe K line

  16. the Fe-N System

    Directory of Open Access Journals (Sweden)

    S. Matar

    1993-01-01

    of Fe2N for the two nitrides. The magnetization is low (0.95 μB/at. for Fe2N and vanishes for FeN. The decrease of the magnetization with increasing amount of N is assessed within the Fe-N system in a model derived from a Slater-Pauling type behavior. Accordingly, a trend from weak to strong ferromagnetism is suggested.

  17. Coupled perpendicular magnetization in Fe/Cu/Fe trilayers

    Energy Technology Data Exchange (ETDEWEB)

    Repetto, D. [Max Planck Institut fuer Festkoerperforschung, Heisenbergstr. 1, D-70569 Stuttgart (Germany)]. E-mail: D.Repetto@fkf.mpg.de; Enders, A. [Max Planck Institut fuer Festkoerperforschung, Heisenbergstr. 1, D-70569 Stuttgart (Germany); Kern, K. [Max Planck Institut fuer Festkoerperforschung, Heisenbergstr. 1, D-70569 Stuttgart (Germany)

    2006-05-15

    Ultrathin epitaxial Fe films on Cu(1 0 0) with perpendicular magnetization have been used as templates for the preparation of FCC Fe/Cu/Fe trilayers. The magnetic anisotropy and the coupling of these films have been studied by in-situ magneto optical Kerr effect measurements and Kerr microscopy. The magnetic coupling of both Fe layers is found to be dominated by magnetostatic interaction. Adsorbate-induced spin reorientation in the top layer also causes spin reorientation in the bottom layer. The governing role of the Fe-vacuum interface for the magnetism of the whole trilayer is demonstrated.

  18. New X-ray views of the Galactic center observed with Suzaku

    CERN Document Server

    Koyama, K; Inui, T; Koyama, Katsuji; Hyodo, Yoshiaki; Inui, Tatsuya

    2006-01-01

    We report the diffuse X-ray emissions from the Sgr A and B regions observed with Suzaku. From the Sgr A region, we found many K-shell transition lines of iron and nickel. The brightest are K alpha lines from FeI, FeXXV and FeXXVI at 6.4 keV, 6.7 keV and 6.9 keV. In addition, K alpha lines of NiI and NiXXVII, K beta of FeI, FeXXV and FeXXVI, and K gamma of FeXXV and FeXXVI are detected for the first time. The center energy of K alpha of FeXXV favors collisional excitation as the origin for this line emission. The ionization temperature determined from the flux ratio of K alpha of FeXXV and FeXXVI is similar to the electron temperature determined from the flux ratio of K alpha and K beta of FeXXV, which are in the range of 5-7 keV. Consequently, the Galactic Center diffuse X-rays (GCDX) are consistent with emission from a plasma nearly in ionization equilibrium. The radio complex Sgr B region also exhibits K alpha lines of FeI, FeXXV and FeXXVI. The 6.7 keV line (FeXXV) map exhibits a local excess at (l,b) = (0...

  19. Bottom and top AF/FM interfaces of NiFe/FeMn/NiFe trilayers

    Science.gov (United States)

    Nascimento, V. P.; Passamani, E. C.; Alvarenga, A. D.; Biondo, A.; Pelegrini, F.; Saitovitch, E. Baggio

    2008-01-01

    X-ray reflectivity analyses were performed in the Si/WTi (7 nm)/NiFe (30 nm)/FeMn (13 nm)/NiFe (10 nm)/WTi (7 nm) exchange-biased system prepared by magnetron sputtering under three different argon working pressures. Layer-by-layer analyses were realized in order to obtain the interfacial roughness parameters quantitatively. For a fixed argon pressure, the root-mean-square roughness (including the atomic grading) of the upper (FeMn/NiFe) interface are greater than that for the lower one in all studied samples. Argon working pressure also has severe influence over the NiFe/FeMn interfaces, being more pronounced at the upper interfaces.

  20. Missing Fe: hydrogenated iron nanoparticles

    CERN Document Server

    Bilalbegovic, G; Mohacek-Grosev, V

    2016-01-01

    Although it was found that the FeH lines exist in the spectra of some stars, none of the spectral features in the ISM have been assigned to this molecule. We suggest that iron atoms interact with hydrogen and produce Fe-H nanoparticles which sometimes contain many H atoms. We calculate infrared spectra of hydrogenated iron nanoparticles using density functional theory methods and find broad, overlapping bands. Desorption of H2 could induce spinning of these small Fe-H dust grains. Some of hydrogenated iron nanoparticles posses magnetic and electric moments and should interact with electromagnetic fields in the ISM. Fe_nH_m nanoparticles could contribute to the polarization of the ISM and the anomalous microwave emission. We discuss the conditions required to form FeH and Fe_nH_m in the ISM.

  1. Tunnel Magneto Resistance of Fe/Insulator/Fe

    Science.gov (United States)

    Aryee, Dennis; Seifu, Dereje

    Tri-layer thin films of Fe/Insulator/Fe were synthesized using magnetron DC/ RF sputtering with MgO insulator and Bi2Te3 topological insulators as middle buffer layer. The multi-layered samples thus produced were studied using in-house built magneto-optic Kerr effect (MOKE) instrument, vibrating sample magnetometer (VSM), torque magnetometer (TMM), AFM, MFM, and magneto-resistance (MR). This system, that is Fe/Insulator/Fe on MgO(100) substrate, is a well-known tunnel magneto resistance (TMR) structure often used in magnetic tunnel junction (MTJ) devices. TMR effect is a method by which MTJs are used in developing magneto-resistive random access memory (MRAM), magnetic sensors, and novel logic devices. The main purpose behind this research is to measure the magnetic anisotropy of Fe/Insulator /Fe structure and correlate it to magneto-resistance. In this presentation, we will present results from MOKE, VSM, TMM, AFM, MFM, and MR studies of Fe/Insulator/Fe on MgO(100). We would like to acknowledge support by NSF-MRI-DMR-1337339.

  2. Fractionation of Fe isotopes during Fe(II) oxidation by a marine photoferrotroph is controlled by the formation of organic Fe-complexes and colloidal Fe fractions

    Science.gov (United States)

    Swanner, Elizabeth D.; Wu, Wenfang; Schoenberg, Ronny; Byrne, James; Michel, F. Marc; Pan, Yongxin; Kappler, Andreas

    2015-09-01

    Much interest exists in finding mineralogical, organic, morphological, or isotopic biosignatures for Fe(II)-oxidizing bacteria (FeOB) that are retained in Fe-rich sediments, which could indicate the activity of these organisms in Fe-rich seawater, more common in the Precambrian Era. To date, the effort to establish a clear Fe isotopic signature in Fe minerals produced by Fe(II)-oxidizing metabolisms has been thwarted by the large kinetic fractionation incurred as freshly oxidized aqueous Fe(III) rapidly precipitates as Fe(III) (oxyhydr)oxide minerals at near neutral pH. The Fe(III) (oxyhydr)oxide minerals resulting from abiotic Fe(II) oxidation are isotopically heavy compared to the Fe(II) precursor and are not clearly distinguishable from minerals formed by FeOB isotopically. However, in marine hydrothermal systems and Fe(II)-rich springs the minerals formed are often isotopically lighter than expected considering the fraction of Fe(II) that has been oxidized and experimentally-determined fractionation factors. We measured the Fe isotopic composition of aqueous Fe (Feaq) and the final Fe mineral (Feppt) produced in batch experiment using the marine Fe(II)-oxidizing phototroph Rhodovulum iodosum. The δ56Feaq data are best described by a kinetic fractionation model, while the evolution of δ56Feppt appears to be controlled by a separate fractionation process. We propose that soluble Fe(III), and Fe(II) and Fe(III) extracted from the Feppt may act as intermediates between Fe(II) oxidation and Fe(III) precipitation. Based on 57Fe Mössbauer spectroscopy, extended X-ray absorption fine structure (EXAFS) spectroscopy, and X-ray total scattering, we suggests these Fe phases, collectively Fe(II/III)interm, may consist of organic-ligand bound, sorbed, and/or colloidal Fe(II) and Fe(III) mineral phases that are isotopically lighter than the final Fe(III) mineral product. Similar intermediate phases, formed in response to organic carbon produced by FeOB and inorganic

  3. Superconductivity in Fe-chalcogenides

    Energy Technology Data Exchange (ETDEWEB)

    Chang, C.C.; Chen, T.K. [Institute of Physics, Academia Sinica, Taipei, Taiwan (China); Lee, W.C. [Department of Physics, Applied Physics, and Astronomy, Binghamton University – SUNY (United States); Lin, P.H. [National Synchrotron Research Center, Hsinchu, Taiwan (China); Wang, M.J. [Institute of Astrophysics and Astronomy, Academia Sinica, Taipei, Taiwan (China); Wen, Y.C. [Institute of Physics, Academia Sinica, Taipei, Taiwan (China); Wu, P.M. [Deparment of Applied Physics and Geballe Laboratory for Advanced Materials, Stanford University, Stanford, CA (United States); Wu, M.K., E-mail: mkwu@mail.ndhu.edu.tw [Institute of Physics, Academia Sinica, Taipei, Taiwan (China); National Donghwa University, Hualien, Taiwan (China)

    2015-07-15

    FeSe, which has the simplest crystal structure among the Fe based superconductors, and related chalcogenide superconductors are ideal candidates for investigating the detailed mechanism of the iron-based superconductors. Here, we summarize recent studies on the Fe-chalcogenides, with the goal to address some unresolved questions such as what is the influence of chemical stoichiometry on the phase diagram, what is the exact parent phase of FeSe system, and why can T{sub c}s be so dramatically enhanced in FeSe based superconductors? Recent developments in novel synthesis to prepare chalcogenide crystals, nano-materials and thin films allow the community to begin to address these issues. Then we review physical properties of the Fe chalcogenides, specifically focusing on optical properties, scanning tunneling spectroscopy and angle-resolved photoemission spectroscopy (ARPES) results. These measurements along with recent theories provide a framework for better understanding the origin of superconductivity in FeSe and Fe-chalcogenides.

  4. Roles of Fe-Nx and Fe-Fe3C@C Species in Fe-N/C Electrocatalysts for Oxygen Reduction Reaction.

    Science.gov (United States)

    Kim, Jae Hyung; Sa, Young Jin; Jeong, Hu Young; Joo, Sang Hoon

    2017-03-22

    Iron and nitrogen codoped carbons (Fe-N/C) have emerged as promising nonprecious metal catalysts for the oxygen reduction reaction (ORR). While Fe-Nx sites have been widely considered as active species for Fe-N/C catalysts, very recently, iron and/or iron carbide encased with carbon shells (Fe-Fe3C@C) has been suggested as a new active site for the ORR. However, most of synthetic routes to Fe-N/C catalysts involve high-temperature pyrolysis, which unavoidably yield both Fe-Nx and Fe-Fe3C@C species, hampering the identification of exclusive role of each species. Herein, in order to establish the respective roles of Fe-Nx and Fe-Fe3C@C sites we rationally designed model catalysts via the phase conversion reactions of Fe3O4 nanoparticles supported on carbon nanotubes. The resulting catalysts selectively contained Fe-Nx, Fe-Fe3C@C, and N-doped carbon (C-Nx) sites. It was revealed that Fe-Nx sites dominantly catalyze ORR via 4-electron (4 e(-)) pathway, exerting a major role for high ORR activity, whereas Fe-Fe3C@C sites mainly promote 2 e(-) reduction of oxygen followed by 2 e(-) peroxide reduction, playing an auxiliary role.

  5. Dolo y mala fe

    Directory of Open Access Journals (Sweden)

    Carlos Arturo Gómez Pavajeau

    2010-12-01

    Full Text Available Se ha dicho por grandes penalistas que las tesis en nuestra disciplina son una eterna vuelta al pasado. Empero, debe constatarse, que ello se ha dicho en un sentido de lo clásico: una vuelta a lo que resulta digno de admirar en cualquier época, toda vez que las experiencias históricas negativas nos previenen de repetir el pasado, razón fundamental por la cual debemos conocerlo. En este escrito pretendemos mostrar cómo algunas tendencias actuales nos indican que épocas nefastas ya superadas pueden repetirse, lo cual particularmente sucede tanto con la noción de dolo como con la de mala fe, concepto que de imponerse destruiría, a la manera como se derrumba un castillo de naipes, el sólido edificio dogmático construido por el Derecho penal liberal.

  6. Fe II Diagnostic Tools for Quasars

    CERN Document Server

    Verner, E; Verner, D; Johansson, S; Kallman, T; Gull, T R

    2004-01-01

    The enrichment of Fe, relative to alpha-elements such as O and Mg, represents a potential means to determine the age of quasars and probe the galaxy formation epoch. To explore how \\ion{Fe}{2} emission in quasars is linked to physical conditions and abundance, we have constructed a 830-level \\ion{Fe}{2} model atom and investigated through photoionization calculations how \\ion{Fe}{2} emission strengths depend on non-abundance factors. We have split \\ion{Fe}{2} emission into three major wavelength bands, \\ion{Fe}{2} (UV), \\ion{Fe}{2}(Opt1), and \\ion{Fe}{2}(Opt2), and explore how the \\ion{Fe}{2}(UV)/\\ion{Mg}{2}, \\ion{Fe}{2}(UV)/\\ion{Fe}{2}(Opt1) and \\ion{Fe}{2}(UV)/\\ion{Fe}{2}(Opt2) emission ratios depend upon hydrogen density and ionizing flux in broad-line regions (BLR's) of quasars. Our calculations show that: 1) similar \\ion{Fe}{2}(UV)/\\ion{Mg}{2} ratios can exist over a wide range of physical conditions; 2) the \\ion{Fe}{2}(UV)/\\ion{Fe}{2}(Opt1) and \\ion{Fe}{2}(UV)/\\ion{Fe}{2}(Opt2) ratios serve to constrain...

  7. Magnetic properties of Fe1-xMnx/Fe nanocomposites

    DEFF Research Database (Denmark)

    Anhøj, Thomas Aarøe; Jacobsen, Claus Schelde; Mørup, Steen

    2004-01-01

    We have prepared nanocomposites of mixtures of ferromagnetic alpha-Fe and antiferromagnetic gamma-Fe50Mn50 nanoparticles, and studied their magnetic and structural properties by magnetization measurements, Mössbauer spectroscopy, and x-ray diffraction. A sample consisting of a 1:1 mixture...... of the two materials showed enhanced coercivity, but almost negligible exchange bias at room temperature after field cooling from 520 K. However, samples with higher content of gamma-Fe50Mn50 showed significant exchange bias. The mechanisms for exchange bias and enhanced coercivity in the system...

  8. Maturation of [FeFe]-hydrogenases: Structures and mechanisms

    Energy Technology Data Exchange (ETDEWEB)

    Nicolet, Yvain; Fontecilla-Camps, Juan C. [Laboratoire de Cristallographie et Cristallogenese des Proteines, Institut de Biologie Structurale J.P. Ebel, Universite Joseph Fourier, Grenoble, CNRS, UMR 5075, CEA, DSV/IBS, 41 rue J. Horowitz F-38027 Grenoble cedex 1 (France); Fontecave, Marc [Laboratoire de Chimie et Biologie des Metaux; Universite Joseph Fourier, Grenoble, CNRS, UMR 5249, CEA, DSV/iRTSV, 17 rue des Martyrs F-38054 Grenoble cedex 9 (France); College de France, 11 place Marcelin-Berthelot 75231 Paris cedex 05 (France)

    2010-10-15

    Maturation of [FeFe]-hydrogenases, consisting in the synthesis and assembly of a di-iron center with a dithiolate bridging ligand as well as CO and CN ligands, depends on the concerted action of three metalloproteins, HydE, HydF and HydG. HydE and HydG are ''Radical-SAM'' enzymes involved in the synthesis of the ligands. HydF is proposed to function as a scaffold protein in which the di-iron center is assembled before being transferred to the hydrogenase. Here we review the current knowledge regarding the structure of the three maturases and the mechanisms of synthesis and assembly of the di-iron center of [FeFe]-hydrogenases. (author)

  9. Effectiveness of FeEDDHA, FeEDDHMA, and FeHBED in Preventing Iron-Deficiency Chlorosis in Soybean

    NARCIS (Netherlands)

    Bin, Levi M.; Weng, Liping; Bugter, Marcel H.J.

    2016-01-01

    The performance of FeHBED in preventing Fe deficiency chlorosis in soybean (Glycine max (L.) Merr.) in comparison to FeEDDHA and FeEDDHMA was studied, as well as the importance of the ortho-ortho and ortho-para/rest isomers in defining the performance. To this end, chlorophyll production (SPAD),

  10. Effectiveness of FeEDDHA, FeEDDHMA, and FeHBED in Preventing Iron-Deficiency Chlorosis in Soybean

    NARCIS (Netherlands)

    Bin, Levi M.; Weng, Liping; Bugter, Marcel H.J.

    2016-01-01

    The performance of FeHBED in preventing Fe deficiency chlorosis in soybean (Glycine max (L.) Merr.) in comparison to FeEDDHA and FeEDDHMA was studied, as well as the importance of the ortho-ortho and ortho-para/rest isomers in defining the performance. To this end, chlorophyll production (SPAD),

  11. Missing Fe: hydrogenated iron nanoparticles

    Science.gov (United States)

    Bilalbegović, G.; Maksimović, A.; Mohaček-Grošev, V.

    2017-03-01

    Although it was found that the FeH lines exist in the spectra of some stars, none of the spectral features in the interstellar medium (ISM) have been assigned to this molecule. We suggest that iron atoms interact with hydrogen and produce Fe-H nanoparticles which sometimes contain many H atoms. We calculate infrared spectra of hydrogenated iron nanoparticles using density functional theory methods and find broad, overlapping bands. Desorption of H2 could induce spinning of these small Fe-H dust grains. Some of hydrogenated iron nanoparticles possess magnetic and electric moments and should interact with electromagnetic fields in the ISM. FenHm nanoparticles could contribute to the polarization of the ISM and the anomalous microwave emission. We discuss the conditions required to form FeH and FenHm in the ISM.

  12. Calculated oscillation periods of the interlayer coupling in Fe/Cr/Fe and Fe/Mo/Fe sandwiches

    DEFF Research Database (Denmark)

    Mirbt, S.; Niklasson, A.M.N.; Johansson, B.

    1996-01-01

    We have performed an ab initio study of the oscillation periods of the interlayer coupling in sandwiches of [100] layers of body centered cubic Cr, respectively, Mo, with up to 20 monolayers thickness embedded in an Fe host. Our derived values for the oscillation periods of the interlayer coupling...... the influence of the lattice constant on the interlayer coupling and also the dependence of the interlayer coupling amplitude on the Fe magnetic moment....

  13. Effects of Fe-deficient conditions on Fe uptake and utilization in P-efficient soybean.

    Science.gov (United States)

    Qiu, Wei; Dai, Jing; Wang, Nanqi; Guo, Xiaotong; Zhang, Xiaoli; Zuo, Yuanmei

    2017-03-01

    Phosphorus (P)-efficient soybean (Glycine max) plants absorb and utilize P with high efficiency. To investigate the effects of iron (Fe)-deficient conditions on the absorption and utilization of Fe in P-efficient soybean plants, two soybean cultivars with different P efficiency, the 03-3 (P-efficient variety) and Bd-2 (P-inefficient variety), were used in this study. The two soybean cultivars were grown in nutrient solution containing Fe concentrations of 0 (Fe0), 20 (Fe20), 40 (Fe40), or 80 (Fe80) μM for 7 days. The Fe reductase activity of roots was higher in 03-3 plants grown under the Fe0, Fe20, and Fe40 treatments than in Bd-2 plants and the total Fe uptake was greater in 03-3 plants under the Fe40 treatment. GmFRD3a was much more highly expressed in the stem of 03-3 than in that of Bd-2, and significantly more iron was transported to 03-3 plant shoots during Fe0 treatment. Chlorosis in young leaves caused by Fe deficiency under the Fe0 and Fe20 treatments was alleviated by increased Fe concentration in shoots. Increased levels of active Fe in young 03-3 leaves under Fe-deprivation conditions (Fe0) and maintenance of stable Fe concentrations in 03-3 shoots subjected to Fe20, Fe40, and Fe80 treatments suggested that the P-efficient 03-3 cultivar is also Fe-efficient. It is suggested that 03-3 soybean cultivar should be a good resource for application to farm field.

  14. [FeFe]-hydrogenase models assembled into vesicular structures.

    Science.gov (United States)

    Menzel, Kristin; Apfel, Ulf-Peter; Wolter, Nonio; Rüger, Ronny; Alpermann, Theodor; Steiniger, Frank; Gabel, Detlef; Förster, Stephan; Weigand, Wolfgang; Fahr, Alfred

    2014-03-01

    Compartmentalization is a major prerequisite for the origin of life on earth according to Wächtershäuser "Iron-Sulfur-World". The hypothesis is mainly based on an autocatalytic inorganic energy reproducing redox system consisting of iron and sulfur as requirement for the subsequent synthesis of complex organic structures. Here, we modified [FeFe]-hydrogenase models by means of covalent coupling to either oleic acid or the amphiphilic block copolymer polybutadiene-polyethyleneoxide (PB-PEO) and incorporated those into the membranes of vesicles composed of phospholipids (liposomes) or the unmodified amphiphilic polymer (polymersomes). We employed a [2Fe-2S] cluster as a hydrogenase model, since these structures are known to be suitable catalysts for the generation of H2 in the presence of weak acids. Successful incorporation was confirmed by spectrophotometric iron quantification and the vesicles formed were characterized by size determination (photon correlation spectroscopy (PCS)), and zeta potential as well as by cryo-transmission electron microscopy (Cryo-TEM). The modified models could be incorporated into liposomes or polymersomes up to molar proportions of 3.15% and 28%, respectively. Due to the immobilization in vesicular bilayers the [FeFe]-hydrogenase models can even exhibit catalytic action under the particular conditions of the intravesicular microenvironment. Our results suggest that the vesicular systems described may be applied as a nanoreactor for the reduction of encapsulated substances by generating hydrogen and thus as a minimal cell model.

  15. Isotopic fractionation associated with [NiFe]- and [FeFe]-hydrogenases

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Hui; Gandhi, Hasand; Cornish, Adam J.; Moran, James J.; Kreuzer, Helen W.; Ostrom, Nathaniel; Hegg, Eric L.

    2016-01-30

    Hydrogenases catalyze the reversible formation of H2 from electrons and protons with high efficiency. Understanding the relationships between H2 production, H2 uptake, and H2-H2O exchange can provide insight into the metabolism of microbial communities in which H2 is an essential component in energy cycling. In this manuscript, we used stable H isotopes (1H and 2H) to probe the isotope effects associated with three [FeFe]-hydrogenases and three [NiFe]-hydrogenases. All six hydrogenases displayed fractionation factors for H2 formation that were significantly less than 1, producing H2 that was severely depleted in 2H relative to the substrate, water. Consistent with differences in their active site structure, the fractionation factors for each class appear to cluster, with the three [NiFe]-hydrogenases (α = 0.27-0.40) generally having smaller values than the three [FeFe]-hydrogenases (α = 0.41-0.55). We also obtained isotopic fractionation factors associated with H2 uptake and H2-H2O exchange under conditions similar to those utilized for H2 production, providing us with a more complete picture of the three reactions catalyzed by hydrogenases. The fractionation factors determined in our studies can be used as signatures for different hydrogenases to probe their activity under different growth conditions and to ascertain which hydrogenases are most responsible for H2 production and/or uptake in complex microbial communities.

  16. Magnetic properties of Fe/NiO/Fe(001) trilayers

    Energy Technology Data Exchange (ETDEWEB)

    Biagioni, P. [INFM - Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milan (Italy)]. E-mail: paolo.biagioni@polimi.it; Brambilla, A. [INFM - Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milan (Italy); Portalupi, M. [INFM - Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milan (Italy); Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Rougemaille, N. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Schmid, A.K. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Lanzara, A. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Department of Physics, University of California at Berkeley, Berkeley, CA 94720 (United States); Vavassori, P. [INFM - Dipartimento di Fisica, Universita di Ferrara, Via Paradiso 12, 44100 Ferrara (Italy); Zani, M. [INFM - Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milan (Italy); Finazzi, M. [INFM - Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milan (Italy); Duo, L. [INFM - Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milan (Italy); Ciccacci, F. [INFM - Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milan (Italy)

    2005-04-15

    We have investigated the magnetic properties of epitaxially grown Fe/NiO/Fe(001) trilayers, for different thicknesses of the NiO spacer. Magneto Optical Kerr Effect has been exploited to study the in-plane magnetization reversal processes in the iron layers. We found that the NiO thickness t{sub AFM} has a critical value t{sub C} for the magnetic coupling between the Fe layers: for t{sub AFM}

  17. Neutron quantum well states in Fe/Co/Fe trilayers

    Science.gov (United States)

    Feygenson, M.; Toperverg, B. P.; Rücker, U.; Kentzinger, E.; Brückel, Th.

    2004-07-01

    We report on neutron quantum well states in Fe/Co/Fe trilayers, in which the reflection potential exhibits a quantum well for both spin states of the neutron. It is shown, that the resonance state in such a system exists and manifests itself as a dip in the reflectivity plateau below the critical angle of total reflection. The range of trilayer parameters was numerically analyzed to find optimal experimental conditions for the enhancement of the neutron wave field in the Co spacer. Enhancement of the wave field by a resonance is suggested as a way to substantially increase the off-specular scattering signal from lateral domains in buried layers of Co.

  18. Neutron quantum well states in Fe/Co/Fe trilayers

    Energy Technology Data Exchange (ETDEWEB)

    Feygenson, M.; Toperverg, B.P.; Ruecker, U.; Kentzinger, E.; Brueckel, Th

    2004-07-15

    We report on neutron quantum well states in Fe/Co/Fe trilayers, in which the reflection potential exhibits a quantum well for both spin states of the neutron. It is shown, that the resonance state in such a system exists and manifests itself as a dip in the reflectivity plateau below the critical angle of total reflection. The range of trilayer parameters was numerically analyzed to find optimal experimental conditions for the enhancement of the neutron wave field in the Co spacer. Enhancement of the wave field by a resonance is suggested as a way to substantially increase the off-specular scattering signal from lateral domains in buried layers of Co.

  19. Influence of an Fe cap layer on the structural and magnetic properties of Fe49Pt51/Fe bi-layers

    Institute of Scientific and Technical Information of China (English)

    Duan Chao-Yang; Ma Bin; Wei Fu-Lin; Zhang zong-Zhi; Jin Qing-Yuan

    2009-01-01

    The influences of an Fe cap layer on the structural and magnetic properties of FePt/Fe bi-layers are investigated.Compared with single FePt alloy films, a thin Fe layer can affect the crystalline orientation and improve the chemical ordering of L10 FePt films. Moreover, the coercivity increases when a thin Fe layer covers the FePt layer. Beyond a critical thickness, however, the Fe cover layer quickens the magnetization reversal of Fe49Pt51/Fe bi-layers by their exchange coupling.

  20. Effects of metal ions on the reactivity and corrosion electrochemistry of Fe/FeS nanoparticles.

    Science.gov (United States)

    Kim, Eun-Ju; Kim, Jae-Hwan; Chang, Yoon-Seok; Turcio-Ortega, David; Tratnyek, Paul G

    2014-04-01

    Nano-zerovalent iron (nZVI) formed under sulfidic conditions results in a biphasic material (Fe/FeS) that reduces trichloroethene (TCE) more rapidly than nZVI associated only with iron oxides (Fe/FeO). Exposing Fe/FeS to dissolved metals (Pd(2+), Cu(2+), Ni(2+), Co(2+), and Mn(2+)) results in their sequestration by coprecipitation as dopants into FeS and FeO and/or by electroless precipitation as zerovalent metals that are hydrogenation catalysts. Using TCE reduction rates to probe the effect of metal amendments on the reactivity of Fe/FeS, it was found that Mn(2+) and Cu(2+) decreased TCE reduction rates, while Pd(2+), Co(2+), and Ni(2+) increased them. Electrochemical characterization of metal-amended Fe/FeS showed that aging caused passivation by growth of FeO and FeS phases and poisoning of catalytic metal deposits by sulfide. Correlation of rate constants for TCE reduction (kobs) with electrochemical parameters (corrosion potentials and currents, Tafel slopes, and polarization resistance) and descriptors of hydrogen activation by metals (exchange current density for hydrogen reduction and enthalpy of solution into metals) showed the controlling process changed with aging. For fresh Fe/FeS, kobs was best described by the exchange current density for activation of hydrogen, whereas kobs for aged Fe/FeS correlated with electrochemical descriptors of electron transfer.

  1. Electrocatalytic activity of porous nanostructured Fe/Pt-Fe electrode for methanol electrooxidation in alkaline media

    Institute of Scientific and Technical Information of China (English)

    Javad Hosseini; Mehdi Abdolmaleki; Hamid Reza Pouretedal; Mohammad Hossein Keshavarz

    2015-01-01

    An electrochemical approach to fabricate a nanostructured Fe/Pt-Fe catalyst through electrodepo-sition followed by galvanic replacement is presented. An Fe/Pt-Fe nanostructured electrode was prepared by deposition of Fe-Zn onto a Fe electrode surface, followed by replacement of the Zn by Pt at open-circuit potential in a Pt-containing alkaline solution. Scanning electron microscopy and energy-dispersive X-ray techniques reveal that the Fe/Pt-Fe electrode is porous and contains Pt. The electrocatalytic activity of the Fe/Pt-Fe electrode for oxidation of methanol was examined by cyclic voltammetry and chronoamperometry. The electrooxidation current on the Fe/Pt-Fe catalyst is much higher than that on flat Pt and smooth Fe catalysts. The onset potential and peak potential on the Fe/Pt-Fe catalyst are more negative than those on flat Pt and smooth Fe electrodes for methanol electrooxidation. All results show that this nanostructured Fe/Pt-Fe electrode is very attractive for integrated fuel cell applications in alkaline media.

  2. Preparation of magnetic recoverable nanosize Cu-Fe2O3/Fe photocatalysts.

    Science.gov (United States)

    Kang, Hsu-Ya; Wang, H Paul

    2013-07-02

    Iron based catalysts generally have the advantage of the easily operated magnetically recovery from application sites. In the present work, paramagnetic iron and copper core-shell nanoparticles having the iron fractions (X(Fe) = Fe/(Cu+Fe)) of 0.33-1.0 were prepared and characterized by in situ synchrotron X-ray absorption and scattering spectroscopy. During the temperature-programmed carbonization (TPC) of Cu(2+)- and Fe(3+)-β-cyclodextrin (CD) complexes, a rapid reduction of Cu(II) occurs at about 453 K together with a growth of the metallic copper (Cu). Iron proceeds in the distinct growth path. At 453-513 K, the Fe(III) → Fe(II) → Fe consecutive reduction is observed. The unreduced Fe(III) (7-13%) is coated on the surfaces of the Fe nanoparticles (as Fe2O3/Fe). Growth of the Fe nanoparticle is inhibited by the surface Fe2O3, while the steady growth in Cu is observed. The Cu has a size range of 14-18 nm in diameter, compared to the small Fe2O3/Fe ones (3-6 nm). Under the UV-visible light irradiation for four hours, methylene blue can be photocatalytically degraded (>90%) by the (Cu-Fe2O3/Fe)@C. The (Cu-Fe2O3/Fe)@C photocatalysts can effectively oxidize dye molecules, providing a promising alternative for dye degradation using solar energy. Recovery of the (Cu-Fe2O3/Fe)@C photocatalysts can be attained by applying external magnetic field to trap the ferromagnetic Cu-Fe2O3/Fe nanoparticles, which suggests an economically attractive process, especially applied in photocatalytic degradation of dye-contaminated wastewater.

  3. Equilibrium Fe isotope fractionation between inorganic aqueous Fe(III) and the siderophore complex, Fe(III)-desferrioxamine B

    DEFF Research Database (Denmark)

    Dideriksen, Knud; Baker, Joel A.; Stipp, Susan Louise Svane

    2008-01-01

    In oxic oceans, most of the dissolved iron (Fe) exists as complexes with siderophore-like, strongly coordinating organic ligands. Thus, the isotope composition of the little amount of free inorganic Fe that is available for precipitation and preservation in the geological record may largely...... differently complexed Fe(III) pools were separated by addition of Na2CO3, which led to immediate precipitation of the inorganic Fe without causing significant dissociation of Fe-desferrioxamine complexes. Experiments using enriched 57Fe tracer showed that isotopic equilibration between the 57Fe......(III)-bearing environments, such as soils and rivers, and may, for example, largely control the Fe isotope composition of marine Fe–Mn crusts....

  4. Asymmetric interfaces in Fe/Ag and Ag/Fe bilayers prepared by molecular beam evaporation

    Energy Technology Data Exchange (ETDEWEB)

    Tunyogi, A. [KFKI Research Institute for Particle and Nuclear Physics, P.O. Box 49, H-1525 Budapest (Hungary)]. E-mail: tunyogi@rmki.kfki.hu; Paszti, F. [KFKI Research Institute for Particle and Nuclear Physics, P.O. Box 49, H-1525 Budapest (Hungary); Osvath, Z. [MTA Research Institute for Technical Physics and Materials Science, P.O. Box 49, H-1525 Budapest (Hungary); Tancziko, F. [KFKI Research Institute for Particle and Nuclear Physics, P.O. Box 49, H-1525 Budapest (Hungary); Major, M. [KFKI Research Institute for Particle and Nuclear Physics, P.O. Box 49, H-1525 Budapest (Hungary); Szilagyi, E. [KFKI Research Institute for Particle and Nuclear Physics, P.O. Box 49, H-1525 Budapest (Hungary)

    2006-08-15

    Single layers of Fe and Ag, as well as Fe/Ag (iron deposited first) and Ag/Fe bilayers were prepared by molecular beam evaporation onto Si. The samples were investigated with backscattering spectrometry (BS) and atomic force microscopy (AFM). BS spectra of Fe/Ag and Ag/Fe indicate a significant difference at the interface. In the case of Fe/Ag the Ag peak has a long tail at the interface, while for Ag/Fe the interface is abrupt. The tail in the Fe/Ag spectrum is too large to be caused by double or plural scattering. According to AFM, the effect of surface roughness is also negligible. In spite of the fact that Fe and Ag are completely immiscible in equilibrium, this tail, however, suggests that some Ag is located in the Fe layer. After annealing, both samples show mixing between the two layers; this is much larger again for Fe/Ag.

  5. Preparation of DyFe2 and TbFe2 by Reduction-Diffusion Process

    Institute of Scientific and Technical Information of China (English)

    Guangsi GUO; Guangtai WANG; Zhitong SUI

    2004-01-01

    The pure intermetallic compounds (Tb1-xDyx)Fe2 are super-magnetostriction materials, which were produced from DyFe2and TbFe2 in this paper. The thermodynamic possibility and kinetic feasible conditions for DyFe2 and TbFe2 preparation by reduction-diffusion in Ca-Dy2O3-Fe and Ca-Tb4O7-Fe systems were analyzed and the products of DyFe2 and TbFe2 were confirmed by XRD. The contracting core model was applied to describe the reduction-diffusion process in which the diffusion is a rate-controlled step. The apparent activation energies of DyFe2 and TbFe2 processes are 45 and 39 k J/mol respectively.

  6. Spin structure of exchange biased heterostructures. Fe/MnF{sub 2} and Fe/FeF{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Sahoo, B.

    2006-12-18

    In this work, the {sup 57}Fe probe layer technique is used in order to investigate the depth- and temperature-dependent Fe-layer spin structure of exchange biased Fe/MnF{sub 2} and Fe/FeF{sub 2} (pseudo-twinned) antiferromagnetic (AFM) systems by conversion electron Moessbauer spectroscopy (CEMS) and nuclear resonant scattering (NRS) of synchrotron radiation. Two kinds of samples with a 10 A {sup 57}Fe probe layer directly at or 35 A away from the interface, labeled as interface and center sample, respectively, were studied in this work. The results obtained by CEMS for Fe/MnF{sub 2} suggests that, at 80 K, i.e., above T{sub N}=67 K of MnF{sub 2}, the remanent state Fe-layer spin structure of the two studied samples are slightly different due to their different microstructure. In the temperature range from 300 K to 80 K, the Fe-layer spin structure does not change just by zero-field cooling the sample in remanence. For Fe/FeF{sub 2}, a continuous non-monotonic change of the remanent-state Fe spin structure was observed by cooling from 300 K to 18 K. NRS of synchrotron radiation was used to investigate the temperature- and depth-dependent Fe-layer spin structure during magnetization reversal in pseudo-twinned Fe/MnF{sub 2}. A depthdependent Fe spin structure in an applied magnetic field (applied along the bisector of the twin domains) was observed at 10 K, where the Fe spins closer to the interface are not aligned along the field direction. The depth-dependence disappears at 150 K. (orig.)

  7. Thermodynamics of Fe(II)Fe(III) oxide systems I. Hydrothermal Fe3O4

    Science.gov (United States)

    Bartel, J.J.; Westrum, E.F.; Haas, J.L.

    1976-01-01

    The heat capacity of a hydrothermally-prepared polycrystalline sample of Fe3O4 was measured from 53 to 350 K, primarily to study the thermophysics of the Verwey transitions. Although the bifurcation of the transition was confirmed, the sample was found to contain traces of manganese. The observed transition temperatures of 117.0 and 123.0 K are 3.7 and 4.2 K higher respectively than those found in pure Fe3O4. Ancillary analytical results are consistent and indicate a stoichiometry of Mn0.008Fe2.992O4 for this material. Characteristics in the transition region are ascribed to dopant effects. ?? 1976.

  8. Single Crystals (M = Fe, Co)

    Science.gov (United States)

    Cabrera-Baez, M.; Magnavita, E. Thizay; Ribeiro, Raquel A.; Avila, Marcos A.

    2014-06-01

    FeGa3 and related compounds have been subjects of recent investigation for their interesting thermoelectric, electronic, and magnetic behaviors. Here, single crystals of FeGa3- y Ge y were grown by the self-flux technique with effective y = 0, 0.09(1), 0.11(1), and 0.17(1) in order to investigate the evolution of the diamagnetic semiconducting compound FeGa3 into a ferromagnetic metal, which occurs through the electron doping and band structure modifications that result from substitution of Ge for Ga. Heat capacity and magnetization measurements reveal non-Fermi liquid behavior in the vicinity of the transition from a paramagnetic to ferromagnetic ground state, suggesting the presence of a ferromagnetic quantum critical point (FMQCP). We also present the first results of hole doping in this system by the growth of FeGa3- y Zn y single crystals, and electron- and hole doping of the related compound CoGa3 by CoGa3- y Ge y and CoGa3- y Zn y crystal growths, aiming to search for further routes to band structure and charge carrier tuning, thermoelectric optimization, and quantum criticality in this family of compounds. The ability to tune the charge carrier type warrants further investigation of the MGa3 system's thermoelectric properties above room temperature.

  9. CNOOC Cooperates with Santa Fe

    Institute of Scientific and Technical Information of China (English)

    Cao Sanyong; Wang Keyu

    1997-01-01

    @@ China National Offshore Oil Corporatian (CNOOC) signed the Petroleum Contract for 15/34 Block in the Pearl River Mouth Basin of South China Sea and the Petroleum Contract for 23/28 Block in the Beibu Gulf of South China Sea with Santa Fe Resources Inc. of the United States in Beijing on January 16, 1997.

  10. Presence of 60Fe in eucrite Piplia Kalan: A new perspective to the initial 60Fe/ 56Fe in the early solar system

    Digital Repository Service at National Institute of Oceanography (India)

    Rudraswami, N.G.; Sahijpal, S.; Bhandari, N.

    - formed on Fe-rich silicate phases of chondrule and troilite from unequilibrated ordinary chondrites (UOCs) 4,8–10 provided an initial 60 Fe/ 56 Fe from (1–10) × 10 –7 . The wide range does not allow us to constrain the initial 60 Fe/ 56 Fe values... metamorphic grade did have a widespread distribution of initial 60 Fe/ 56 Fe. In fact, the spread in the initial 60 Fe/ 56 Fe does seem to gain support for the heterogeneous distribution in the solar system, unlike that of 26 Al. Whether 60 Fe...

  11. Atom exchange between aqueous Fe(II) and structural Fe in clay minerals.

    Science.gov (United States)

    Neumann, Anke; Wu, Lingling; Li, Weiqiang; Beard, Brian L; Johnson, Clark M; Rosso, Kevin M; Frierdich, Andrew J; Scherer, Michelle M

    2015-03-03

    Due to their stability toward reductive dissolution, Fe-bearing clay minerals are viewed as a renewable source of Fe redox activity in diverse environments. Recent findings of interfacial electron transfer between aqueous Fe(II) and structural Fe in clay minerals and electron conduction in octahedral sheets of nontronite, however, raise the question whether Fe interaction with clay minerals is more dynamic than previously thought. Here, we use an enriched isotope tracer approach to simultaneously trace Fe atom movement from the aqueous phase to the solid ((57)Fe) and from the solid into the aqueous phase ((56)Fe). Over 6 months, we observed a significant decrease in aqueous (57)Fe isotope fraction, with a fast initial decrease which slowed after 3 days and stabilized after about 50 days. For the aqueous (56)Fe isotope fraction, we observed a similar but opposite trend, indicating that Fe atom movement had occurred in both directions: from the aqueous phase into the solid and from the solid into aqueous phase. We calculated that 5-20% of structural Fe in clay minerals NAu-1, NAu-2, and SWa-1 exchanged with aqueous Fe(II), which significantly exceeds the Fe atom layer exposed directly to solution. Calculations based on electron-hopping rates in nontronite suggest that the bulk conduction mechanism previously demonstrated for hematite1 and suggested as an explanation for the significant Fe atom exchange observed in goethite2 may be a plausible mechanism for Fe atom exchange in Fe-bearing clay minerals. Our finding of 5-20% Fe atom exchange in clay minerals indicates that we need to rethink how Fe mobility affects the macroscopic properties of Fe-bearing phyllosilicates and its role in Fe biogeochemical cycling, as well as its use in a variety of engineered applications, such as landfill liners and nuclear repositories.

  12. De nuevo sobre la serie RRC 235 de SEX•POM

    Directory of Open Access Journals (Sweden)

    Luis Amela Valverde

    2015-12-01

    Full Text Available Within the coinage of the gens Pompeia, the first and one of the most interesting series was made by Sextus Pompeius, grandfather of Pompey the Great, who issued a denarius, dated in the year 137 BC, in which Romulus and Remus are suckled by a she-wolf. Rather than expressing a legendary genealogy, this is related to the internal politics of Rome.

  13. 75 FR 7209 - Airworthiness Directives; Rolls-Royce Corporation (RRC) AE 3007A Series Turbofan Engines

    Science.gov (United States)

    2010-02-18

    ... field data to have a causal link to a manufacturing process that led to incomplete shot peening on the... data, views, or arguments regarding this proposal. Send your comments to an address listed under... States, on the relationship between the national Government and the States, or on the distribution...

  14. El áureo de Cn. Pompeyo Magno (RRC 402/1

    Directory of Open Access Journals (Sweden)

    Luis Amela Valverde

    2010-01-01

    Full Text Available La aparición de un quinto ejemplar del raro áureo de Cn. Pompeyo Magno (cos. I 70 a.C. nos ha llevado a retomar esta amonedación, de claro carácter triunfal, que se ha relacionado con cada uno de los tres triunfos de Pompeyo, celebrados respectivamente en los años 81, 71 y 61 a.C. De hecho, este áureo parece relacionarse con las campañas orientales de Pompeyo y su iconografía muestra tanto sus deseos de celebrar su triunfo como su célebre imitatio Alexandri.The discovery of a fifth copy of the rare aureus of Gnaeus Pompeius Magnus (cos. I 70 BC caused us to take up again this coining, with a clear triumphant nature, celebrated respectively in 81, 71 and 61 BC. In fact, this aureus seems to be in relation with the eastern campaigns of Pompeius, and its iconography shows his wishes of a triumph celebration as well as his imitatio Alexandri.

  15. El áureo de Cn. Pompeyo Magno (RRC 402/1)

    OpenAIRE

    Amela Valverde, Luis

    2010-01-01

    La aparición de un quinto ejemplar del raro áureo de Cn. Pompeyo Magno (cos. I 70 a.C.) nos ha llevado a retomar esta amonedación, de claro carácter triunfal, que se ha relacionado con cada uno de los tres triunfos de Pompeyo, celebrados respectivamente en los años 81, 71 y 61 a.C. De hecho, este áureo parece relacionarse con las campañas orientales de Pompeyo y su iconografía muestra tanto sus deseos de celebrar su triunfo como su célebre imitatio Alexandri. ...

  16. Profile of a leader: pioneer government advisor: Laura Holland, RN, RRC, CBE, LLD (1883 - 1956).

    Science.gov (United States)

    Paulson, E; Zilm, G; Warbinek, E

    2000-01-01

    Laura Holland, nurse and social worker, became one of Canada's first official "nurse advisors" to government when she was appointed Advisor to the B.C. Ministry of Health and Welfare from 1938 to 1945. Before that appointment, she had served, with distinction, as a Nursing Sister in World War I, brought innovative Red Cross and public health advances to northern Ontario, reformed Children's Aid services in Vancouver and B.C., and started a new department that combined nursing/social work in the field during the Great Depression of the 1930s. She was an extraordinary leader.

  17. Biogeochemical speciation of Fe in ocean water

    NARCIS (Netherlands)

    Hiemstra, T.; Riemsdijk, van W.H.

    2006-01-01

    The biogeochemical speciation of Fe in seawater has been evaluated using the consistent Non-Ideal Competitive Adsorption model (NICA¿Donnan model). Two types of data sets were used, i.e. Fe-hydroxide solubility data and competitive ligand equilibration/cathodic stripping voltammetry (CLE/CSV) Fe

  18. Magnetostrictive GMR spin valves with composite FeGa/FeCo free layers

    OpenAIRE

    Luping Liu; Qingfeng Zhan; Huali Yang; Huihui Li; Shuanglan Zhang; Yiwei Liu; Baomin Wang; Xiaohua Tan; Run-Wei Li

    2016-01-01

    We have fabricated strain-sensitive spin valves on flexible substrates by utilizing the large magnetostrictive FeGa alloy to promote the strain sensitivity and the composite free layer of FeGa/FeCo to avoid the drastic reduction of giant magnetoresistance (GMR) ratio. This kind of spin valve (SV-FeGa/FeCo) displays a MR ratio about 5.9%, which is comparable to that of the conventional spin valve (SV-FeCo) with a single FeCo free layer. Different from the previously reported works on magnetost...

  19. Process and genes for expression and overexpression of active [FeFe] hydrogenases

    Science.gov (United States)

    Seibert, Michael; King, Paul W; Ghirardi, Maria Lucia; Posewitz, Matthew C; Smolinski, Sharon L

    2014-09-16

    A process for expression of active [FeFe]-hydrogenase in a host organism that does not contain either the structural gene(s) for [FeFe]-hydrogenases and/or homologues for the maturation genes HydE, HydF and HyG, comprising: cloning the structural hydrogenase gene(s) and/or the maturation genes HydE, HydF and HydG from an organisms that contains these genes into expression plasmids; transferring the plasmids into an organism that lacks a native [FeFe]-hydrogenase or that has a disrupted [FeFe]-hydrogenase and culturing it aerobically; and inducing anaerobiosis to provide [FeFe] hydrogenase biosynthesis and H?2#191 production.

  20. Process and genes for expression and overexpression of active [FeFe] hydrogenases

    Energy Technology Data Exchange (ETDEWEB)

    Seibert, Michael; King, Paul W; Ghirardi, Maria Lucia; Posewitz, Matthew C; Smolinski, Sharon L

    2014-09-16

    A process for expression of active [FeFe]-hydrogenase in a host organism that does not contain either the structural gene(s) for [FeFe]-hydrogenases and/or homologues for the maturation genes HydE, HydF and HyG, comprising: cloning the structural hydrogenase gene(s) and/or the maturation genes HydE, HydF and HydG from an organisms that contains these genes into expression plasmids; transferring the plasmids into an organism that lacks a native [FeFe]-hydrogenase or that has a disrupted [FeFe]-hydrogenase and culturing it aerobically; and inducing anaerobiosis to provide [FeFe] hydrogenase biosynthesis and H?2#191 production.

  1. Fe-Ni-O体系中Fe/Ni的还原行为%Reduction behavior of Fe/Ni in the Fe-Ni-O system

    Institute of Scientific and Technical Information of China (English)

    魏文洁; 张延玲; 魏芬绒; 杨小刚; 胡晓军

    2013-01-01

    取电阻炉实验和热重分析等手段,探讨了Fe-Ni-O体系中不同条件下的产物组成及Fe/Ni的还原行为.结果表明:五种样品的还原难度由低到高依次为NiO<Fe2O3+Ni<Fe2O3+NiO<NiFe2O4 <Fe2O3; Ni元素能够促进铁氧化物还原,其促进作用由Ni元素的初始状态决定,单质Ni>氧化物NiO>NiFe2O4中的Ni;NiFe2O4的还原过程中各产物由低温到高温依次出现的次序为Fe3O4、Ni、(Fe,Ni)、Fe和Fe0.64Ni0.36.根据实验结果,对五种氧化物体系的还原过程进行了探讨,并获得了活化能、控速环节等重要参数及相关反应机理.%The product composition under different conditions and the reduction behavior of Fe and Ni in the Fe-Ni-O system were studied by electric resistance furnace experiments and thermogravimetric analysis. The order of difficult degree for reducing Fe/Ni oxides in five systems is NiONiO>Ni released from NiFe2O4. As the temperature increases, the reduction products of NiFe2O4 are in order of Fe3O4, Ni, (Fe, Ni), Fe, and Fe0.64Ni0.36- Based on these experimental results, the reduction processes and the kinetics such as activation energy and rate-controlling step for reducing the five oxides were analyzed and discussed.

  2. Rapid degradation of dyes in water by magnetic Fe(0)/Fe3O4/graphene composites.

    Science.gov (United States)

    Chong, Shan; Zhang, Guangming; Tian, Huifang; Zhao, He

    2016-06-01

    Magnetic Fe(0)/Fe3O4/graphene has been successfully synthesized by a one-step reduction method and investigated in rapid degradation of dyes in this work. The material was characterized by N2 sorption-desorption, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), vibrating-sample magnetometer (VSM) measurements and X-ray photoelectron spectroscopy (XPS). The results indicated that Fe(0)/Fe3O4/graphene had a layered structure with Fe crystals highly dispersed in the interlayers of graphene, which could enhance the mass transfer process between Fe(0)/Fe3O4/graphene and pollutants. Fe(0)/Fe3O4/graphene exhibited ferromagnetism and could be easily separated and re-dispersed for reuse in water. Typical dyes, such as Methyl Orange, Methylene Blue and Crystal Violet, could be decolorized by Fe(0)/Fe3O4/graphene rapidly. After 20min, the decolorization efficiencies of methyl orange, methylene blue and crystal violet were 94.78%, 91.60% and 89.07%, respectively. The reaction mechanism of Fe(0)/Fe3O4/graphene with dyes mainly included adsorption and enhanced reduction by the composite. Thus, Fe(0)/Fe3O4/graphene prepared by the one-step reduction method has excellent performance in removal of dyes in water.

  3. Mechanochemical synthesis of nanocrystalline Fe and Fe-B magnetic alloys

    Science.gov (United States)

    Mohammadi, Majid; Ghasemi, Ali; Tavoosi, Majid

    2016-12-01

    Mechanochemical synthesis and magnetic characterization of nanocrystalline Fe and Fe-B magnetic alloys was the goal of this study. In this regard, different Fe2O3-B2O3 powder mixtures with sufficient amount of CaH2 were milled in a planetary ball mill in order to produce nanocrystalline Fe, Fe95B5 and Fe85B15 alloys. The produced samples were characterized using X-ray diffraction (XRD), differential scanning calorimetry (DSC), scanning electron microscopy (SEM) and vibrating sample magnetometer (VSM). The results showed that, nanocrystalline Fe, Fe95B5 and Fe85B15 alloys can be successfully synthesized by the reduction reaction of Fe2O3 and B2O3 with CaH2 during mechanical alloying. The structure of produced Fe95B5 and Fe85B15 alloys was a combination of Fe and Fe2B phases with average crystallite sizes of about 15 and 10 nm, respectively. The produced nanocrystalline alloys exhibited soft magnetic properties with the coercivity and saturation of magnetization in the range of 170-240 Oe and 9-28 emu/g, respectively. Increasing the boron content has a destructive effect on soft magnetic properties of Fe-B alloys.

  4. The effect of FeF{sub 2} on the magneto-optic response in FeF{sub 2}/Fe/FeF{sub 2} sandwiches

    Energy Technology Data Exchange (ETDEWEB)

    Pistora, J; Lesnak, M [Institute of Physics, VSB-Technical University of Ostrava (Czech Republic); Liskova, E; Visnovsky, S [Institute of Physics, Charles University, Prague (Czech Republic); Harward, I; Maslankiewicz, P; Balin, K; Celinski, Z [Center for Magnetism and Magnetic Nanostructures, University of Colorado at Colorado Springs, Colorado Springs, CO 80918 (United States); MistrIk, J; Yamaguchi, T [Research Institute of Electronics, Shizuoka University, Hamamatsu (Japan); Lopusnik, R [Seagate Technology, 7801 Computer Ave., Bloomington, MN 55435 (United States); Vlcek, J, E-mail: jaromir.pistora@vsb.c [Department of Mathematics and Descriptive Geometry, VSB-Technical University of Ostrava (Czech Republic)

    2010-04-21

    The room temperature optical constants n and k of MBE grown FeF{sub 2} films are reported. Because of poor chemical stability, FeF{sub 2} had to be coated with a protective Au layer. Reflection spectral ellipsometry in the photon energy range between 1.3 and 5.2 eV was performed on structures with a typical profile Au(0.5 nm)/FeF{sub 2}(120 nm)/Au(30 nm)/Ag(20 nm)/Fe(0.6 nm) grown on GaAs(0 0 1) substrate. The spectra of n and k in FeF{sub 2} were subsequently employed in the design of FeF{sub 2}/Fe/FeF{sub 2} sandwiches considered as magneto-optic (MO) sensors for weak microwave currents. Their MO response was evaluated using reflection MO (Kerr) spectroscopy at polar magnetization. The present results may be of interest in MO studies of magnetic nanostructures with Fe/FeF{sub 2}/Fe, including MO magnetometry and MO magnetic domain imaging.

  5. Bias voltage effects on tunneling magnetoresistance in Fe/MgAl2O4/Fe (001 ) junctions: Comparative study with Fe/MgO/Fe(001) junctions

    Science.gov (United States)

    Masuda, Keisuke; Miura, Yoshio

    2017-08-01

    We investigate bias voltage effects on the spin-dependent transport properties of Fe/MgAl 2O 4 /Fe(001) magnetic tunneling junctions (MTJs) by comparing them with those of Fe/MgO/Fe(001) MTJs. By means of the nonequilibrium Green's function method and the density functional theory, we calculate bias voltage dependencies of magnetoresistance (MR) ratios in both the MTJs. We find that in both the MTJs, the MR ratio decreases as the bias voltage increases and finally vanishes at a critical bias voltage Vc. We also find that the critical bias voltage Vc of the MgAl 2O 4 -based MTJ is clearly larger than that of the MgO-based MTJ. Since the in-plane lattice constant of the Fe/MgAl 2O 4 /Fe(001) supercell is twice that of the Fe/MgO/Fe(001) one, the Fe electrodes in the MgAl 2O 4 -based MTJs have an identical band structure to that obtained by folding the Fe band structure of the MgO-based MTJs in the Brillouin zone of the in-plane wave vector. We show that such a difference in the Fe band structure is the origin of the difference in the critical bias voltage Vc between the MgAl 2O 4 - and MgO-based MTJs.

  6. Mechanochemical synthesis of Fe-S materials

    DEFF Research Database (Denmark)

    Jiang, Jianzhong; Larsen, R.K.; Lin, R.

    1998-01-01

    Powder mixtures of metallic iron and sulfur have been milled in a high-energy planetary ball mill and the formation of iron sulfides has been studied by x-ray diffraction, Mossbauer spectroscopy, and scanning electron microscopy. For Fe:S ratios of 1:1 and 1:2 the final products are FeS with the ......Powder mixtures of metallic iron and sulfur have been milled in a high-energy planetary ball mill and the formation of iron sulfides has been studied by x-ray diffraction, Mossbauer spectroscopy, and scanning electron microscopy. For Fe:S ratios of 1:1 and 1:2 the final products are Fe......S with the modified NiAs structure and FeS2 (pyrite), respectively. No other iron sulfides were formed for any of the Fe:S ratios studied. The FeS phase has been tested as an electrode material in lithium batteries....

  7. Fe II emission in AGN

    Directory of Open Access Journals (Sweden)

    M. Joly

    2008-01-01

    Full Text Available El espectro óptico de las galaxias Seyfert 1 muestra una gran variedad de líneas de emisión producidas por FeII. Damos tres ejemplos e investigamos la formación de estas líneas con el fin de determinar las condiciones físicas de las regiones en donde se emiten.

  8. 2009 Santa Fe Bone symposium.

    Science.gov (United States)

    Lewiecki, E Michael; Bilezikian, John P; Laster, Andrew J; Miller, Paul D; Recker, Robert R; Russell, R Graham G; Whyte, Michael P

    2010-01-01

    Osteoporosis is a common skeletal disease with serious clinical consequences because of fractures. Despite the availability of clinical tools to diagnose osteoporosis and assess fracture risk, and drugs proven to reduce fracture risk, it remains a disease that is underdiagnosed and undertreated. When treatment is started, it is commonly not taken correctly or long enough to be effective. Recent advances in understanding of the regulators and mediators of bone remodeling have led to new therapeutic targets and the development of drugs that may offer advantages over current agents in reducing the burden of osteoporotic fractures. Many genetic factors that play a role in the pathogenesis of osteoporosis and metabolic bone disease have now been identified. At the 2009 Santa Fe Bone Symposium, held in Santa Fe, New Mexico, USA, the links between advances in genetics, basic bone science, recent clinical trials, and new and emerging therapeutic agents were presented and explored. Socioeconomic challenges and opportunities in the care of osteoporosis were discussed. This is a collection of medical essays based on key presentations at the 2009 Santa Fe Bone Symposium.

  9. Magnetostriction of FM/TbFe (FM=Fe, Py-permalloy, FeCo) coupled bilayer

    Energy Technology Data Exchange (ETDEWEB)

    Li Jianjun, E-mail: ljj8081@tom.com [National Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Harbin Institute of Technology, Harbin150080 (China); Laboratoire de Magnetisme de Bretagne-CNRS FRE 3117, Universite de Bretagne Occidentale, 6, Avenue le Gorgeu C.S. 93837, 29238 Brest Cedex 3 (France)

    2012-04-15

    Choosing TbFe as the magnetostrictive layer and using soft ferromagnetic materials (FM=Fe, Py-permalloy, FeCo) as the inductive layer, we report the magnetization and magnetostriction of the S/FM(10 nm)/TbFe(10 nm) coupled bilayer (S-glass substrate). The magnetization of the coupled bilayer is attributed to the soft ferromagnetic layer and there is no contribution from the TbFe layer. Interfacial exchange interaction plays an important role in determining the magnetostriction of the coupled bilayer. The effect coming from the deposition Argon pressure on the magnetostriction of the coupled bilayer was also investigated. - Highlights: Black-Right-Pointing-Pointer Choosing TbFe as magnetostrictive layer and with soft ferromagnetic material (FM=Fe, Py-permalloy, FeCo) as inductive layer. Black-Right-Pointing-Pointer We report the magnetization and magnetostriction of the S/FM(10 nm)/TbFe(10 nm) coupled bilayer (S-glass substrate). Black-Right-Pointing-Pointer The magnetization of coupled bilayer is attributed to soft ferromagnetic layer and there is no contribution from TbFe layer. Black-Right-Pointing-Pointer Interfacial exchange interaction plays an important role in determining the magnetostriction of the coupled bilayer.

  10. Efficient use of Fe metal as an electron transfer agent in a heterogeneous Fenton system based on Fe0/Fe3O4 composites.

    Science.gov (United States)

    Moura, Flávia C C; Araujo, Maria Helena; Costa, Regina C C; Fabris, José D; Ardisson, José D; Macedo, Waldemar A A; Lago, Rochel M

    2005-08-01

    In this work a novel heterogeneous Fenton system based on Fe(0)/Fe3O4 composites is described. The composites with several Fe(0)/Fe3O4 ratios were prepared by two different methods, i.e. mechanical alloying of Fe(0) and Fe3O4 powders and controlled reduction of Fe3O4 with H2. Reaction studies and detailed Conversion Electron Mössbauer surface characterization of the composites Fe(0)/Fe3O4, Fe(0), Fe3O4, alpha-Fe2O3 and gamma-Fe2O3 suggested that Fe2+surf species are essential to produce an active Fenton system. Kinetic studies for the oxidation of the dye methylene blue, used as an organic model molecule, and for the peroxide decomposition suggest that the reactions proceed via HO* radicals generated from Fe2+surf species and H2O2 in a Fenton like mechanism. The increase in activity caused by the addition of Fe(0) is discussed in terms of a creation of Fe2+surf species during the preparation of the composite and by an electron transfer mechanism from Fe(0) to Fe3+surf during the Fenton reaction to regenerate the Fe2+surf active species.

  11. Effect of Fe Particle on the Surface Peeling in Cu-Fe-P Lead Frame

    Institute of Scientific and Technical Information of China (English)

    SU Juanhua; LIU Ping; DONG Qiming; LI Hejun; TIAN Baohong

    2006-01-01

    Under the surface peeling of Cu-Fe-P lead frame alloy larger Fe particles were observed by energy dispersive spectroscopy. By using the large strain two-dimension plane strain model and elastic-plastic finite element method, the cause for peeling damage of Cu-Fe-P lead frame alloy was investigated. The results show that when the content of Fe particles is more than 30% at local Fe-rich area the intense stress concentration in the Fe particle would make the Fe particle broken up. The high equivalent stress mutation and the mismatch of equivalent strain 10% at the two sides of interface make it easy to develop the crack and peeling damage on finish rolling. The larger Fe particles in the Cu-Fe-P alloy should be avoided.

  12. Magnetostrictive GMR spin valves with composite FeGa/FeCo free layers

    Directory of Open Access Journals (Sweden)

    Luping Liu

    2016-03-01

    Full Text Available We have fabricated strain-sensitive spin valves on flexible substrates by utilizing the large magnetostrictive FeGa alloy to promote the strain sensitivity and the composite free layer of FeGa/FeCo to avoid the drastic reduction of giant magnetoresistance (GMR ratio. This kind of spin valve (SV-FeGa/FeCo displays a MR ratio about 5.9%, which is comparable to that of the conventional spin valve (SV-FeCo with a single FeCo free layer. Different from the previously reported works on magnetostrictive spin valves, the SV-FeGa/FeCo displays an asymmetric strain dependent GMR behavior. Upon increasing the lateral strain, the MR ratio for the ascending branch decreases more quickly than that for the descending branch, which is ascribed to the formation of a spiraling spin structure around the FeGa/FeCo interface under the combined influences of both magnetic field and mechanical strain. A strain sensitivity of GF = 7.2 was achieved at a magnetic bias field of -30 Oe in flexible SV-FeGa/FeCo, which is significantly larger than that of SV-FeCo.

  13. Magnetostrictive GMR spin valves with composite FeGa/FeCo free layers

    Science.gov (United States)

    Liu, Luping; Zhan, Qingfeng; Yang, Huali; Li, Huihui; Zhang, Shuanglan; Liu, Yiwei; Wang, Baomin; Tan, Xiaohua; Li, Run-Wei

    2016-03-01

    We have fabricated strain-sensitive spin valves on flexible substrates by utilizing the large magnetostrictive FeGa alloy to promote the strain sensitivity and the composite free layer of FeGa/FeCo to avoid the drastic reduction of giant magnetoresistance (GMR) ratio. This kind of spin valve (SV-FeGa/FeCo) displays a MR ratio about 5.9%, which is comparable to that of the conventional spin valve (SV-FeCo) with a single FeCo free layer. Different from the previously reported works on magnetostrictive spin valves, the SV-FeGa/FeCo displays an asymmetric strain dependent GMR behavior. Upon increasing the lateral strain, the MR ratio for the ascending branch decreases more quickly than that for the descending branch, which is ascribed to the formation of a spiraling spin structure around the FeGa/FeCo interface under the combined influences of both magnetic field and mechanical strain. A strain sensitivity of GF = 7.2 was achieved at a magnetic bias field of -30 Oe in flexible SV-FeGa/FeCo, which is significantly larger than that of SV-FeCo.

  14. Moessbauer-spectroscopic study of structure and magnetism of the exchange-coupled layer systems Fe/FeSn{sub 2}, and Fe/FeSi/Si and the ion-implanted diluted magnetic semiconductor SiC(Fe); Moessbauerspektroskopische Untersuchung von Struktur und Magnetismus der austauschgekoppelten Schichtsysteme Fe/FeSn{sub 2} und Fe/FeSi/Si und des ionenimplantierten verduennten magnetischen Halbleiters SiC(Fe)

    Energy Technology Data Exchange (ETDEWEB)

    Stromberg, Frank

    2009-07-07

    In line with this work the structural and magnetic properties of the exchange coupled layered systems Fe/FeSn{sub 2} and Fe/FeSi/Si and of the Fe ion implanted diluted magnetic semiconductor (DMS) SiC(Fe) were investigated. The main measuring method was the isotope selective {sup 57}Fe conversion electron Moessbauer spectroscopy (CEMS), mostly in connection with the {sup 57}Fe tracer layer technique, in a temperature range from 4.2 K to 340 K. Further measurement techniques were X-ray diffraction (XRD), electron diffraction (LEED, RHEED), SQUID magnetometry and FMR (Ferromagnetic Resonance). In the first part of this work the properties of thin AF FeSn{sub 2}(001) films and of the exchange-bias system Fe/FeSn{sub 2}(001) on InSb(001) were investigated. With the application of {sup 57}Fe-tracer layers and CEMS both the Fe-spin structure and the temperature dependence of the magnetic hyperfine field (B{sub hf}) of FeSn{sub 2} could be examined. The evaporation of Fe films on the FeSn{sub 2} films produced in the latter ones a high perpendicular spin component at the Fe/FeSn{sub 2} interface. In some distance from the interface the Fe spins rotate back into the sample plane. Furthermore {sup 57}Fe-CEMS provided a correlation between the absolute value of the exchange field vertical stroke He vertical stroke and the amount of magnetic defects within the FeSn{sub 2}. Temperature dependent CEMS-measurements yielded informations about the spin dynamics within the AF. The transition temperatures T{sub B}{sup *}, which were interpreted as superparamagnetic blocking temperatures, obtain higher values compared to the temperatures T{sub B} of the exchange-bias effect, obtained with magnetometry measurements. The second part of this work deals with the indirect exchange coupling within Fe/FeSi/Si/FeSi/Fe multilayers and FeSi diffusion barriers. The goal was to achieve Fe free Si interlayers. The CEMS results show that starting from a thickness of t{sub FeSi}=10-12 A of the

  15. Interstitial Fe in MgO

    CERN Document Server

    Mølholt, T E; Gunnlaugsson, H P; Svane, A; Masenda, H; Naidoo, D; Bharuth-Ram, K; Fanciulli, M; Gislason, H P; Johnston, K; Langouche, G; Ólafsson, S; Sielemann, R; Weyer, G

    2014-01-01

    Isolated Fe-57 atoms were studied in MgO single-crystals by emission Mossbauer spectroscopy following implantation of Mn-57 decaying to Fe-57. Four Mossbauer spectral components were found corresponding to different Fe lattice positions and/or charge states. Two components represent Fe atoms substituting Mg as Fe2+ and Fe3+, respectively; a third component is due to Fe in a strongly implantation-induced disturbed region. The fourth component, which is the focus of this paper, can be assigned to Fe at an interstitial site. Comparison of its measured isomer shift with ab initio calculations suggests that the interstitial Fe is located on, or close to, the face of the rock-salt MgO structure. To harmonize such an assignment with the measured near-zero quadrupole interaction a local motion process (cage motion) of the Fe has to be stipulated. The relation of such a local motion as a starting point for long range diffusion is discussed.

  16. Redox cycling of Fe(II) and Fe(III) in magnetite by Fe-metabolizing bacteria

    Science.gov (United States)

    Byrne, James M.; Klueglein, Nicole; Pearce, Carolyn; Rosso, Kevin M.; Appel, Erwin; Kappler, Andreas

    2015-03-01

    Microorganisms are a primary control on the redox-induced cycling of iron in the environment. Despite the ability of bacteria to grow using both Fe(II) and Fe(III) bound in solid-phase iron minerals, it is currently unknown whether changing environmental conditions enable the sharing of electrons in mixed-valent iron oxides between bacteria with different metabolisms. We show through magnetic and spectroscopic measurements that the phototrophic Fe(II)-oxidizing bacterium Rhodopseudomonas palustris TIE-1 oxidizes magnetite (Fe3O4) nanoparticles using light energy. This process is reversible in co-cultures by the anaerobic Fe(III)-reducing bacterium Geobacter sulfurreducens. These results demonstrate that Fe ions bound in the highly crystalline mineral magnetite are bioavailable as electron sinks and electron sources under varying environmental conditions, effectively rendering magnetite a naturally occurring battery.

  17. Synthesis of high magnetization Fe and FeCo nanoparticles by high temperature chemical reduction

    Energy Technology Data Exchange (ETDEWEB)

    Kandapallil, B; Colborn, RE; Bonitatibus, PJ; Johnson, F

    2015-03-15

    Fe and FeCo ferromagnetic nanoparticles in the 5-10 nm size regimes featuring high magnetization were synthesized using a modified chemical reduction method. The structure and morphology of these nanoparticles were confirmed by XRD and TOM analysis. These small, monodisperse and phase pure nanoparticles exhibited magnetic saturation of 210 emu/g (Fe) and 220 emu/g (Fe+Co) for Fe and FeCo nanoparticles respectively. The magnetization was found to be dependent on the temperature at which the reducing agent was introduced. (C) 2014 Elsevier B.V. All rights reserved,

  18. Effect of Iron Fe (II and Fe (III in a Binary System Evaluated Bioluminescent Method

    Directory of Open Access Journals (Sweden)

    Elena Sorokina

    2013-01-01

    Full Text Available The effect of iron ions Fe2+ and Fe3+ on the bioluminescent recombinant strain of Escherichia coli in a single-component and binary system. Found that for the bacteria E. coli Fe3+ ions are more toxic than Fe2+. Under the combined effect of iron toxicity increases, the percentage of luminescence quenching increases, but the value is much less than the sum of the indicator for the Fe2+ and Fe3+. The biological effect of insertion of iron is not proportional to their content in the mixture.

  19. Fe3O4/MgO/Fe Heteroepitaxial Structures for Magnetic Tunnel Junctions

    Energy Technology Data Exchange (ETDEWEB)

    Orna, J. [University of Zaragoza, Spain; Morellon, Luis [University of Zaragoza, Spain; Algarabel, Pedro A. [University of Zaragoza, Spain; Pardo, J. A. [University of Zaragoza, Spain; Sangiao, S [Instituto de Nanociencia de Aragón, Universidad de Zaragoza, Zaragoza, 50009 Spain; Magen, C [Oak Ridge National Laboratory (ORNL); Snoeck, E. [CEMES-CNRS, Toulouse, France; De Teresa, J M [Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-CSIC, Zaragoza, 50009 Spain; Ibarra, M. Ricardo [University of Zaragoza, Spain

    2008-01-01

    In this work we report the growth and structural and magnetic characterization of heteroepitaxial Fe O/MgO/Fe junctions. All three layers have been deposited by pulsed laser deposition. Combining High Resolution Transmission Electron Microscopy and X-ray results, we have obtained for the heterostructure the epitaxy relation MgO(001) [100]//Fe O(001)[100]/MgO(001) [100]/Fe(001)[110]. All interfaces appear very sharp with relatively small root-mean square (rms) roughness, 0.2 nm. The magnetic coupling between Fe O and Fe electrodes is also very small, 0.03 mJ/

  20. Nature of impurities in fertilizers containing EDDHMA/Fe(3+), EDDHSA/Fe(3+), and EDDCHA/Fe(3+) chelates.

    Science.gov (United States)

    Alvarez-Fernández, Ana; Cremonini, Mauro A; Sierra, Miguel A; Placucci, Giuseppe; Lucena, Juan J

    2002-01-16

    Iron chelates derived from ethylenediaminedi(o-hydroxyphenylacetic) acid (EDDHA), ethylenediaminedi(o-hydroxy-p-methylphenylacetic) acid (EDDHMA), ethylenediaminedi(2-hydroxy-5-sulfophenylacetic) acid (EDDHSA), and ethylenediaminedi(5-carboxy-2-hydroxyphenylacetic) acid (EDDCHA) are remarkably efficient in correcting iron chlorosis in plants growing in alkaline soils. This work reports the determination of impurities in commercial samples of fertilizers containing EDDHMA/Fe(3+), EDDHSA/Fe(3+), and EDDCHA/Fe(3+). The active components (EDDHMA/Fe(3+), EDDHSA/Fe(3+), and EDDCHA/Fe(3+)) were separated easily from other compounds present in the fertilizers by HPLC. Comparison of the retention times and the UV-visible spectra of the peaks obtained from commercial EDDHSA/Fe(3+) and EDDCHA/Fe(3+) samples with those of standard solutions showed that unreacted starting materials (p-hydroxybenzenesulfonic acid and p-hydroxybenzoic acid, respectively) were always present in the commercial products. 1D and 2D NMR experiments showed that commercial fertilizers based on EDDHMA/Fe(3+) contained impurities having structures tentatively assigned to iron chelates of two isomers of EDDHMA. These findings suggest that current production processes of iron chelates used in agriculture need to be improved.

  1. Effects of Fe fine powders doping on hot deformed NdFeB magnets

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Min, E-mail: linm@nimte.ac.cn [Ningbo Institute of Material Technology & Engineering Chinese Academy of Science, Ningbo 315201 (China); Wang, Huijie [Ningbo Jinji Strong Magnetic Material Company, Ningbo 315041 (China); Zheng, Jingwu [Zhejiang University of Technology, Hangzhou 310014 (China); Yan, Aru [Ningbo Institute of Material Technology & Engineering Chinese Academy of Science, Ningbo 315201 (China)

    2015-04-01

    The composite NdFeB magnets with blending melt-spun flakes and Fe fine powders were prepared by the hot-pressed and hot-deformed route. Characterizations of the hot-deformed NdFeB magnets affected by the doped Fe powders were tested. The doped Fe powders decrease the hot-deformed pressure when the strain is between 15 and 50%. XRD patterns show that the doped Fe powders have little influence on the c-axis alignment of hot-deformed NdFeB magnets in the press direction. The B{sub r} and the (BH){sub max} get improved when the doped Fe powders are less than 3 wt%. The doped Fe of hot-deformed NdFeB magnets exists in the elongated state and the spherical state surrounded by the Nd-rich phase. With the Fe fraction increasing, the potential of magnet moves to the positive direction and the diameter of the Nyquist arc becomes larger, which indicate that the corrosion resistance improved effectively. The bending strength was enhanced by the elongated α-Fe phase embedded in the matrix 2:14:1 phase. - Highlights: • The doped Fe powders have little influence on the c-axis alignment of magnets. • The elongated Fe powders are more than the spherical Fe powders in the magnets. • The corrosion resistance is improved effectively with the increasing Fe fraction. • The bending strength is enhanced by the elongated α-Fe phase embedded in the matrix.

  2. Lattice locations and properties of Fe in Co/Fe co-implanted ZnO

    DEFF Research Database (Denmark)

    Gunnlaugsson, H.P.; Johnston, K.; Mølholt, T.E.;

    2012-01-01

    The lattice locations and electronic configurations of Fe in 57Co/57Fe implanted ZnO (to (5‐6) × 1014 Fe/cm−2) have been studied by 57Fe Mössbauer emission spectroscopy. The spectra acquired upon room temperature implantation show ∼20% of the probe atoms as Fe2+ on perturbed Zn sites and the rema...... likely takes place at relatively low temperatures, thus explaining some of the discrepancies in the literature regarding magnetic properties of 3d metal‐doped ZnO.......The lattice locations and electronic configurations of Fe in 57Co/57Fe implanted ZnO (to (5‐6) × 1014 Fe/cm−2) have been studied by 57Fe Mössbauer emission spectroscopy. The spectra acquired upon room temperature implantation show ∼20% of the probe atoms as Fe2+ on perturbed Zn sites...... and the remaining fraction as Fe2+ in damage sites of interstitial character. After annealing at 773 K, ∼20% remain on crystalline sites, while the damage fraction has partly disappeared and instead a ∼30% fraction occurs as high‐spin Fe3+, presumably in precipitates. This suggests that precipitation of Co/Fe in ZnO...

  3. Recombinant antibodies for specific detection of clostridial [Fe-Fe] hydrogenases

    Science.gov (United States)

    Mangayil, Rahul; Karp, Matti; Lamminmäki, Urpo; Santala, Ville

    2016-01-01

    Biological hydrogen production is based on activity of specific enzymes called hydrogenases. Hydrogenases are oxygen sensitive metalloenzymes containing Ni and/or Fe atoms at the active site, catalyzing reversible reduction of protons. Generally, [Fe-Fe] hydrogenases prefer proton reduction to molecular hydrogen, a potential energy carrier molecule that can be produced by bioprocesses in sustainable manner. Thus, monitoring tools have been developed to study the relationship between [Fe-Fe] hydrogenases and biohydrogen production in bioreactors at DNA and RNA levels. In the present study, novel molecular tools are introduced for quantitative monitoring of clostridial [Fe-Fe] hydrogenases at the protein level. Aerobic and anaerobic biopanning (for inactive and active [Fe-Fe] hydrogenase, respectively) of phage displayed single-chain variable fragment (scFv) antibody libraries aided in isolating nine potential scFvs. The enriched antibodies demonstrated high specificity towards Clostridium spp. [Fe-Fe] hydrogenases allowing detection from pure and mixed cultures. Additionally, the antibodies showed different binding characteristics towards hydrogenase catalytic states, providing a possible means for functional detection of clostridial [Fe-Fe] hydrogenases. From hydrogenase-antibody interaction studies we observed that though antibody binding reduced the enzyme catalytic activity, it facilitated to retain hydrogen evolution from oxygen exposed hydrogenases. PMID:27786270

  4. Recombinant antibodies for specific detection of clostridial [Fe-Fe] hydrogenases.

    Science.gov (United States)

    Mangayil, Rahul; Karp, Matti; Lamminmäki, Urpo; Santala, Ville

    2016-10-27

    Biological hydrogen production is based on activity of specific enzymes called hydrogenases. Hydrogenases are oxygen sensitive metalloenzymes containing Ni and/or Fe atoms at the active site, catalyzing reversible reduction of protons. Generally, [Fe-Fe] hydrogenases prefer proton reduction to molecular hydrogen, a potential energy carrier molecule that can be produced by bioprocesses in sustainable manner. Thus, monitoring tools have been developed to study the relationship between [Fe-Fe] hydrogenases and biohydrogen production in bioreactors at DNA and RNA levels. In the present study, novel molecular tools are introduced for quantitative monitoring of clostridial [Fe-Fe] hydrogenases at the protein level. Aerobic and anaerobic biopanning (for inactive and active [Fe-Fe] hydrogenase, respectively) of phage displayed single-chain variable fragment (scFv) antibody libraries aided in isolating nine potential scFvs. The enriched antibodies demonstrated high specificity towards Clostridium spp. [Fe-Fe] hydrogenases allowing detection from pure and mixed cultures. Additionally, the antibodies showed different binding characteristics towards hydrogenase catalytic states, providing a possible means for functional detection of clostridial [Fe-Fe] hydrogenases. From hydrogenase-antibody interaction studies we observed that though antibody binding reduced the enzyme catalytic activity, it facilitated to retain hydrogen evolution from oxygen exposed hydrogenases.

  5. Magnetic properties of ball-milled TbFe2 and TbFe2B

    Indian Academy of Sciences (India)

    J Arout Chelvane; S Kasiviswanathan; M V Rao; G Markandeyulu

    2004-04-01

    The magnetic properties of ball-milled TbFe2 and TbFe2B were studied by magnetization measurements. X-ray diffraction studies on TbFe2B showed that boron occupied interstitial position in the crystal structure, just as hydrogen did. The value of the saturation magnetization of TbFe2B was found to be smaller than that of TbFe2. This is explained on the basis of a charge transfer between the boron atoms and the 3d band of Fe. The anisotropy of TbFe2B was found to be large compared to that of TbFe2. X-ray diffractograms for the ball milled samples showed that after 80 h of milling, a predominantly amorphous phase was obtained. TbFe2B was found to undergo easy amorphization compared to TbFe2. Magnetization of TbFe2 was found to decrease rapidly with initial milling hours and was found to be constant with further hours of milling. TbFe2B exhibited an anomalous behaviour with an increase in moment with milling hours and this may be due to the segregation of -Fe.

  6. Charge stripe structure in FeTe

    Energy Technology Data Exchange (ETDEWEB)

    Kawashima, Y., E-mail: yukik@eng.hokudai.ac.jp [Department of Applied Physics, Hokkaido University, Sapporo 060-8628 (Japan); Ichimura, K. [Department of Applied Physics, Hokkaido University, Sapporo 060-8628 (Japan); Center of Education and Research for Topological Science and Technology, Hokkaido University, Sapporo 060-8628 (Japan); Ishioka, J. [Department of Applied Physics, Hokkaido University, Sapporo 060-8628 (Japan); Kurosawa, T. [Department of Physics, Hokkaido University, Sapporo 060-0810 (Japan); Oda, M. [Center of Education and Research for Topological Science and Technology, Hokkaido University, Sapporo 060-8628 (Japan); Department of Physics, Hokkaido University, Sapporo 060-0810 (Japan); Yamaya, K. [Department of Applied Physics, Hokkaido University, Sapporo 060-8628 (Japan); Tanda, S. [Department of Applied Physics, Hokkaido University, Sapporo 060-8628 (Japan); Center of Education and Research for Topological Science and Technology, Hokkaido University, Sapporo 060-8628 (Japan)

    2012-06-01

    We report the STM study on a single-crystalline sample of FeTe at 7.8 K. FeTe is one of the iron-based superconductor. We measured the resistivity and the magnetization of FeTe. FeTe shows SDW transition at 58 K on these measurements. We study the electronic state of FeTe by using STM/STS for observing FeTe from a microscopic viewpoint. We observed the iron layer and the tellurium layer with atomic resolution. Moreover, we discover the charge stripe structure on STM/STS measurement. We find the charge stripe structure is caused by iron atoms from the analysis. The gap structure of 9 meV was observed in tunneling spectra. This gap size is consistent with the SDW gap which is expected from mean field theory with T{sub N}=58 K.

  7. [Fe IV] Emission in Ionized Nebulae

    Directory of Open Access Journals (Sweden)

    M. Rodríguez

    2003-01-01

    Full Text Available Se presentan los resultados de un análisis de la emisión en [Fe IV] en varias nebulosas ionizadas, basado en nuevas identificaciones y medidas anteriores de líneas de [Fe IV]. Las abundancias de Fe obtenidas al sumar las abundancias de los iones relevantes (principalmente Fe++ y Fe3+ resultan ser menores, por factores en el rango 2.6-5.9, que las abundancias implicadas por las líneas de [Fe III] y un factor de corrección por la ionizacion obtenido con modelos de ionizacion. Se discuten las posibles razones de esta discrepancia así como las implicaciones que tiene para nuestro entendimiento tanto de la evolución del polvo en nebulosas ionizadas como de la historia química de galaxias de baja metalicidad.

  8. Preparation of γ-Fe2O3/Ni2O3/FeCl3(FeCl2 Composite Nanoparticles by Hydrothermal Process Useful for Ferrofluids

    Directory of Open Access Journals (Sweden)

    Qingmei Zhang

    2011-01-01

    Full Text Available Using a hydrothermal process in FeCl2 solution, γ-Fe2O3/Ni2O3/FeCl3(FeCl2 composite nanoparticles were obtained from the FeOOH/Ni(OH2 precursor prepared by coprecipitation. The precursor and the as-prepared nanoparticles were investigated by vibrating sample magnetometer (VSM, X-ray diffraction (XRD, energy disperse X-ray spectroscopy (EDX, X-ray photoelectron spectroscopy (XPS, and transmission electron microscopy (TEM. The experimental results showed that the paramagnetic amorphous precursor, in which Ni(OH2 is formed outside FeOOH, is transformed to ferrimagnetic γ-Fe2O3/Ni2O3 composite when it is processed in FeCl2 solution (0.25, 0.50, 1.00 M in an autoclave at 100°C for 1 hr. In addition, the dismutation reaction of FeCl2 produces FeCl3 and Fe. Some FeCl3 and little FeCl2 can be absorbed to form γ-Fe2O3/Ni2O3/FeCl3(FeCl2 composite nanoparticles in which Ni2O3 forms outside the γ-Fe2O3 core and the outermost layer is FeCl3 (FeCl2. The content of FeCl3 (FeCl2 in the particles increased, and the magnetization of the particles decreased with the concentration of FeCl2 solution increasing in the hydrothermal process. The FeCl3 (FeCl2 surface is chemically passive and nonmagnetic (paramagnetic. Accordingly, the composite nanoparticles are chemically stable, and their aggregation is prevented. The specific saturation magnetization of such composite nanoparticles can get to 57.4–62.2 emu/g and could be very suitable for synthesizing ferrofluids.

  9. [FeFe]-hydrogenase gene quantification and melting curve analysis from hydrogen-fermenting bioreactor samples

    Energy Technology Data Exchange (ETDEWEB)

    Tolvanen, Katariina E.S.; Santala, Ville P.; Karp, Matti T. [Department of Chemistry and Bioengineering, Tampere University of Technology, P.O. Box 541, FI-33101 Tampere (Finland)

    2010-04-15

    In this study, quantitative PCR (qPCR) was used to quantify [FeFe]-hydrogenases and subsequently melting curves were analyzed from hydrogen-fermenting, mixed-culture bioreactor samples. Denaturing gradient gel electrophoresis (DGGE) analysis was also performed to the reactor samples revealing a clostridial dominance in the reactor. Primers targeting [FeFe]-hydrogenases were designed based on known clostridial [FeFe]-hydrogenase gene sequences and tested with several clostridial strains. The results show that amplification efficiencies of four different clostridia are highly similar and melting curves of the clostridial strains were within 1 C of each other. We compared the melting curves to the hydrogen percentage and observed a correlation between the results. The closer the melting curves were to those of clostridia, the better the hydrogen production. Based on these results, the primers and melting curve analysis of [FeFe]-hydrogenase amplicons can be used for analysing hydrogenase genes from bioreactor samples. (author)

  10. Synthesis and characterization of magnetic Fe/CNTs composites with controllable Fe nanoparticle concentration

    Energy Technology Data Exchange (ETDEWEB)

    Zhao Fan; Duan Hongyan; Wang Weigao [Department of Physics, Ningbo University, Ningbo, Zhejiang 315211 (China); Wang Jun, E-mail: wjnaf@ustc.edu [Department of Physics, Ningbo University, Ningbo, Zhejiang 315211 (China)

    2012-07-01

    Fe/CNTs composites, with different concentrations of Fe nanoparticles (NPs) on carbon nanotube (CNT) surfaces, were successfully fabricated via a facile solvothermal method. The lengths of CNTs are up to 10 {mu}m and the mean diameter of the Fe nanoparticles is about 25 nm. The structures, composition and magnetic properties of the Fe/CNTs were characterized by XRD, FTIR, FE-SEM, TEM and PPMS. We found that the concentrations of Fe nanoparticles depositing on the CNTs could be controlled by adjusting the initial mass ratio of ferrocene to CNTs. The Fe/CNTs composites display good ferromagnetic properties at room temperature, with a saturation magnetization of 125 emu/g-Fe and a coercivity of 276 Oe. The Curie temperature of the sample is about 1038 K, slightly lower than that (1043 K) of the bulk iron.

  11. Fe-V redox flow batteries

    Science.gov (United States)

    Li, Liyu; Kim, Soowhan; Yang, Zhenguo; Wang, Wei; Zhang, Jianlu; Chen, Baowei; Nie, Zimin; Xia, Guanguang

    2014-07-08

    A redox flow battery having a supporting solution that includes Cl.sup.- anions is characterized by an anolyte having V.sup.2+ and V.sup.3+ in the supporting solution, a catholyte having Fe.sup.2+ and Fe.sup.3+ in the supporting solution, and a membrane separating the anolyte and the catholyte. The anolyte and catholyte can have V cations and Fe cations, respectively, or the anolyte and catholyte can each contain both V and Fe cations in a mixture. Furthermore, the supporting solution can contain a mixture of SO.sub.4.sup.2- and Cl.sup.- anions.

  12. Fe nanowire encapsulated in boron nitride nanotubes

    Science.gov (United States)

    Koi, Naruhiro; Oku, Takeo; Nishijima, Masahiko

    2005-11-01

    Boron nitride (BN) nanotubes, nanohorns, nanocoils were synthesized by annealing Fe 4N and B powders at 1000 °C for 1 h in nitrogen gas atmosphere. Especially, Fe-filled BN nanotubes were produced, and investigated by high-resolution electron microscopy, high-angle annular dark-field scanning transmission electron microscopy, electron diffraction and energy dispersive X-ray spectroscopy, which indicates that the [110] of Fe is parallel to the BN nanotube axis. Formation mechanism of Fe-filled BN nanotube was speculated based on these results.

  13. Thermal electric effects in Fe|GaAs|Fe tunnel junctions

    Directory of Open Access Journals (Sweden)

    Xintao Jia

    2012-12-01

    Full Text Available We study the spin polarized thermoelectric effects on Fe|GaAs|Fe tunnel junction using a generalized Landauer-Büttiker formalism, where the energy flow is described on the same footing as the electric current. The Seebeck coefficient of tunnel junction will change sign as the GaAs thickness increases. We demonstrate the thermally induced STT on Fe|GaAs|Fe tunnel junction is robust against the interfacial defects and is non-negligible.

  14. Iron Isotope Fractionations Reveal a Finite Bioavailable Fe Pool for Structural Fe(III) Reduction in Nontronite.

    Science.gov (United States)

    Shi, Bingjie; Liu, Kai; Wu, Lingling; Li, Weiqiang; Smeaton, Christina M; Beard, Brian L; Johnson, Clark M; Roden, Eric E; Van Cappellen, Philippe

    2016-08-16

    We report on stable Fe isotope fractionation during microbial and chemical reduction of structural Fe(III) in nontronite NAu-1. (56)Fe/(54)Fe fractionation factors between aqueous Fe(II) and structural Fe(III) ranged from -1.2 to +0.8‰. Microbial (Shewanella oneidensis and Geobacter sulfurreducens) and chemical (dithionite) reduction experiments revealed a two-stage process. Stage 1 was characterized by rapid reduction of a finite Fe(III) pool along the edges of the clay particles, accompanied by a limited release to solution of Fe(II), which partially adsorbed onto basal planes. Stable Fe isotope compositions revealed that electron transfer and atom exchange (ETAE) occurred between edge-bound Fe(II) and octahedral (structural) Fe(III) within the clay lattice, as well as between aqueous Fe(II) and structural Fe(III) via a transient sorbed phase. The isotopic fractionation factors decreased with increasing extent of reduction as a result of the depletion of the finite bioavailable Fe(III) pool. During stage 2, microbial reduction was inhibited while chemical reduction continued. However, further ETAE between aqueous Fe(II) and structural Fe(III) was not observed. Our results imply that the pool of bioavailable Fe(III) is restricted to structural Fe sites located near the edges of the clay particles. Blockage of ETAE distinguishes Fe(III) reduction of layered clay minerals from that of Fe oxyhydroxides, where accumulation of structural Fe(II) is much more limited.

  15. Ab initio calculations of the Fe(II) and Fe(III) isotopic effects in citrates, nicotianamine, and phytosiderophore, and new Fe isotopic measurements in higher plants

    Science.gov (United States)

    Moynier, Frédéric; Fujii, Toshiyuki; Wang, Kun; Foriel, Julien

    2013-05-01

    Iron is one of the most abundant transition metal in higher plants and variations in its isotopic compositions can be used to trace its utilization. In order to better understand the effect of plant-induced isotopic fractionation on the global Fe cycling, we have estimated by quantum chemical calculations the magnitude of the isotopic fractionation between different Fe species relevant to the transport and storage of Fe in higher plants: Fe(II)-citrate, Fe(III)-citrate, Fe(II)-nicotianamine, and Fe(III)-phytosiderophore. The ab initio calculations show firstly, that Fe(II)-nicotianamine is ˜3‰ (56Fe/54Fe) isotopically lighter than Fe(III)-phytosiderophore; secondly, even in the absence of redox changes of Fe, change in the speciation alone can create up to ˜1.5‰ isotopic fractionation. For example, Fe(III)-phytosiderophore is up to 1.5‰ heavier than Fe(III)-citrate2 and Fe(II)-nicotianamine is up to 1‰ heavier than Fe(II)-citrate. In addition, in order to better understand the Fe isotopic fractionation between different plant components, we have analyzed the iron isotopic composition of different organs (roots, seeds, germinated seeds, leaves and stems) from six species of higher plants: the dicot lentil (Lens culinaris), and the graminaceous monocots Virginia wild rye (Elymus virginicus), Johnsongrass (Sorghum halepense), Kentucky bluegrass (Poa pratensis), river oat (Uniola latifolia), and Indian goosegrass (Eleusine indica). The calculations may explain that the roots of strategy-II plants (Fe(III)-phytosiderophore) are isotopically heavier (by about 1‰ for the δ56Fe) than the upper parts of the plants (Fe transported as Fe(III)-citrate in the xylem or Fe(II)-nicotianamine in the phloem). In addition, we suggest that the isotopic variations observed between younger and older leaves could be explained by mixing of Fe received from the xylem and the phloem.

  16. Experimental constraints on Fe isotope fractionation during magnetite and Fe carbonate formation coupled to dissimilatory hydrous ferric oxide reduction

    Science.gov (United States)

    Johnson, Clark M.; Roden, Eric E.; Welch, Susan A.; Beard, Brian L.

    2005-02-01

    Iron isotope fractionation between aqueous Fe(II) and biogenic magnetite and Fe carbonates produced during reduction of hydrous ferric oxide (HFO) by Shewanella putrefaciens, Shewanella algae, and Geobacter sulfurreducens in laboratory experiments is a function of Fe(III) reduction rates and pathways by which biogenic minerals are formed. High Fe(III) reduction rates produced 56Fe/ 54Fe ratios for Fe(II) aq that are 2-3‰ lower than the HFO substrate, reflecting a kinetic isotope fractionation that was associated with rapid sorption of Fe(II) to HFO. In long-term experiments at low Fe(III) reduction rates, the Fe(II) aq-magnetite fractionation is -1.3‰, and this is interpreted to be the equilibrium fractionation factor at 22°C in the biologic reduction systems studied here. In experiments where Fe carbonate was the major ferrous product of HFO reduction, the estimated equilibrium Fe(II) aq-Fe carbonate fractionations were ca. 0.0‰ for siderite (FeCO 3) and ca. +0.9‰ for Ca-substituted siderite (Ca 0.15Fe 0.85CO 3) at 22°C. Formation of precursor phases such as amorphous nonmagnetic, noncarbonate Fe(II) solids are important in the pathways to formation of biogenic magnetite or siderite, particularly at high Fe(III) reduction rates, and these solids may have 56Fe/ 54Fe ratios that are up to 1‰ lower than Fe(II) aq. Under low Fe(III) reduction rates, where equilibrium is likely to be attained, it appears that both sorbed Fe(II) and amorphous Fe(II)(s) components have isotopic compositions that are similar to those of Fe(II) aq. The relative order of δ 56Fe values for these biogenic minerals and aqueous Fe(II) is: magnetite > siderite ≈ Fe(II) aq > Ca-bearing Fe carbonate, and this is similar to that observed for minerals from natural samples such as Banded Iron Formations (BIFs). Where magnetite from BIFs has δ 56Fe >0‰, the calculated δ 56Fe value for aqueous Fe(II) suggests a source from midocean ridge (MOR) hydrothermal fluids. In contrast

  17. The spectrum of Fe II

    CERN Document Server

    Nave, Gillian

    2012-01-01

    The spectrum of singly-ionized iron (Fe II) has been recorded using high-resolution Fourier transform and grating spectroscopy over the wavelength range 900 {\\AA} to 5.5 {\\mu}m. The spectra were observed in high-current continuous and pulsed hollow cathode discharges using Fourier transform (FT) spectrometers at the Kitt Peak National Observatory, Tucson, AZ and Imperial College, London and with the 10.7 m Normal Incidence Spectrograph at the National Institute of Standards and Technology. Roughly 12 900 lines were classified using 1027 energy levels of Fe II that were optimized to measured wavenumbers. The wavenumber uncertainties of lines in the FT spectra range from 10-4 cm-1 for strong lines around 4 {\\mu}m to 0.05 cm-1 for weaker lines around 1500 {\\AA}. The wavelength uncertainty of lines in the grating spectra is 0.005 {\\AA}. The ionization energy of (130 655.4+-0.4) cm-1 was estimated from the 3d6(5D)5g and 3d6(5D)6h levels.

  18. THE SPECTRUM OF Fe II

    Energy Technology Data Exchange (ETDEWEB)

    Nave, Gillian [National Institute of Standards and Technology, Gaithersburg, MD 20899-8422 (United States); Johansson, Sveneric, E-mail: gillian.nave@nist.gov [Lund Observatory, University of Lund, Box 43, SE-22100 Lund (Sweden)

    2013-01-15

    The spectrum of singly ionized iron (Fe II) has been recorded using high-resolution Fourier transform (FT) and grating spectroscopy over the wavelength range 900 A to 5.5 {mu}m. The spectra were observed in high-current continuous and pulsed hollow cathode discharges using FT spectrometers at the Kitt Peak National Observatory, Tucson, AZ and Imperial College, London and with the 10.7 m Normal Incidence Spectrograph at the National Institute of Standards and Technology. Roughly 12,900 lines were classified using 1027 energy levels of Fe II that were optimized to measured wavenumbers. The wavenumber uncertainties of lines in the FT spectra range from 10{sup -4} cm{sup -1} for strong lines around 4 {mu}m to 0.05 cm{sup -1} for weaker lines around 1500 A. The wavelength uncertainty of lines in the grating spectra is 0.005 A. The ionization energy of (130,655.4 {+-} 0.4) cm{sup -1} was estimated from the 3d{sup 6}({sup 5}D)5g and 3d{sup 6}({sup 5}D)6h levels.

  19. Magnetic and magnetostrictive properties of amorphous TbFe/FeAl multilayer thin film

    Institute of Scientific and Technical Information of China (English)

    WANG Wei; MI Yiming; QIAN Shiqiang; ZHOU Xiying

    2008-01-01

    Exchange coupling multilayer thin films, which combined giant magnetostriction and soft magnetic properties, were of growing interest for applications. The TbFe/FeAl multilayer thin films were prepared by dc magnetron sputtering onto glass substrates. The microstructure, magnetic, and magnetostrictive properties of TbFe/FeAl multilayer thin film was investigated at different annealing temperatures. The results indicated that the soft magnetic and magnetostrictive properties for TbFe/FeAl multilayer thin film compared with TbFe single layer film were obviously improved. In comparison with the intrinsic coercivity JHc of 59.2 kA/m for TbFe single layer film, the intrinsic coercivity JHc for TbFe/FeAl multilayer thin films rapidly dropped to 29.6 kA/m. After optimal annealing (350 ℃×60 min), magnetic properties of Hs=96 kA/m and JHc=16 kA/m were obtained, and magnetostrictive coefficient could reach to 574×10-6 under an external magnetic field of 400 kA·m-1 for the TbFe/FeAl multilayer thin film.

  20. Modeling thermodynamics of Fe-N phases; characterisation of e-Fe2N1-z

    DEFF Research Database (Denmark)

    Pekelharing, M.I.; Böttger, A.; Somers, Marcel A.J.

    1999-01-01

    In order to arrive at modeling the thermodynamics of Fe-N phases, including long-range (LRO) and short-range ordering (SRO) of the N atoms, it is important to understand the role of N interstitially dissolved in an Fe-host lattice. The crystal structure of -Fe2N1-z consists of an h.c.p. iron...

  1. Origin of Fe3+ in Fe-containing, Al-free Mantle Silicate Perovskite

    CERN Document Server

    Xu, Shenzhen; Morgan, Dane

    2016-01-01

    We have studied the ferrous (Fe2+) and ferric (Fe3+) iron concentrations in Al-free Fe containing Mg-silicate perovskite (Mg-Pv) at pressure (P), temperature (T), and oxygen fugacity (fO2) conditions related to the lower mantle using a thermodynamic model based on ab-initio calculations. We consider the oxidation reaction and the charge disproportionation reaction, both of which can produce Fe3+ in Mg-Pv. The model shows qualitatively good agreement with available experimental data on Fe3+/{\\Sigma}Fe ({\\Sigma}Fe = total Fe in system), spin transitions, and equations of state. We predict that under lower-mantle conditions Fe3+/{\\Sigma}Fe determined by the charge disproportionation is estimated to be 0.01-0.07 in Al-free Mg-Pv, suggesting that low Al Mg-Pv in the uppermost pyrolitic mantle (where majoritic garnet contains most of the Al) and in the harzburgitic heterogeneities throughout the lower mantle contains very little Fe3+. We find that the volume reduction by the spin transition of the B-site Fe3+ leads...

  2. Perpendicular Magnetic Anisotropy of Tb/Fe and Gd/Fe Multilayers Studied with Torque Magnetometer

    Science.gov (United States)

    Chowdhury, Ataur

    Perpendicular magnetic anisotropy (PMA) of multilayers critically depend on the magnetic and structural ordering of the interface. To study the effect of interface on PMA, Tb/Fe and Gd/Fe multilayers with varying Fe (0.8-9.0 nm) and Gd (0.5-2.8 nm) or Tb (0.3-6.3 nm) layer thicknesses were fabricated by planar magnetron sputtering. The magnetometer results of spin orientation clearly reveals that samples with Gd or Tb layer thickness of more than 1.2 nm display no PMA, regardless of the Fe layer thickness. Tb/Fe and Gd/Fe multilayers with thin (<1.2 nm) Tb or Gd layers display large PMA, but no PMA is observed when the Fe layer thickness is increased to 4.0 nm and higher. The bulk magnetization and anisotropy energy constant of the samples are found to increase with increasing Fe layer thickness. Torque measurement also reveals that there are two distinctly different axes of spin alignment at different energy. Tb/Fe and Gd/Fe multilayers with similar composition reveal similar magnetic and structural characteristics, and it may imply that single-ion-anisotropy of rare-earth element, which is quite large for Tb ions and very small for Gd ions, may not be the dominating cause of PMA in Td/Fe and Gd/Fe multilayers. A detailed explanation of the results will be provided based on exchange interaction at the interface.

  3. Deposition and Magnetic Properties of Fe3O4/Fe/Fe3O4Tri-layer Films

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The Fe3O4/Fe/Fe3O4 (MIM) tri-layer films (200 nm/12~93 nm/200 nm) were prepared on Si(100) by DC-magnetron reactive-sputtering followed by air- or vacuum-annealing at 280~400℃ for 1.5 h, respectively. Magnetic properties and phases under different sandwich and annealing conditions were studied. In MIM structure, the incorporation of the interlayer iron does increase the magnetization measured under 8 kOe (M8K), but reduce coercivity (Hc). The Hc of as deposited films decreases from 354 Oe to 74 Oe; while M8K increases from 254 to 392 emu/cc. By annealing in air, the whole MIM tri-layer film becomes γ-Fe2Oa, Hc is about 550 Oe and M8K is around 250 emu/cc. The coercivity mechanism of as-deposited and annealed MIM tri layer films belongs to domain-wall pinning type. δM plots show that when the interlayer Fe thickness is 12 nm, the Fe and Fe3O4 layers are decoupled in the as-deposited and annealed states; while it is coupled in the as deposited state when the Fe thickness increases to 23 nm. Vacuum annealing of the MIM films leads to increase in both coercivity and magnetization, and to enhance the exchange coupling between layers.

  4. Seeded preparation of ultrathin FeS2 nanosheets from Fe3O4 nanoparticles

    Science.gov (United States)

    Li, Tingting; Liu, Huiwen; Wu, Zhennan; Liu, Yi; Guo, Zuoxing; Zhang, Hao

    2016-06-01

    FeS2 nanomaterials with two-dimensional features hold great promise for electrochemical and photovoltaic applications. However, the preparation of ultrathin FeS2 nanosheets is still challenging because of the lack of a tailor-made approach. In this work, FeS2 nanosheets with a thickness of 2.1 nm are prepared through a Fe3O4-seeded approach. Uniform Fe3O4 nanoparticles are foremost synthesized via the standard method in organic media. The injection of a S solution leads to the replacement of O in Fe3O4 through anion-exchange, which generates (110) facet-enriched FeS2 nuclei. The subsequent (110) facet-mediated oriented attachment and fusion of FeS2 nuclei produce ultrathin FeS2 nanosheets. As catalysts in the hydrogen evolution reaction, FeS2 nanosheets exhibit good electrochemical activity.FeS2 nanomaterials with two-dimensional features hold great promise for electrochemical and photovoltaic applications. However, the preparation of ultrathin FeS2 nanosheets is still challenging because of the lack of a tailor-made approach. In this work, FeS2 nanosheets with a thickness of 2.1 nm are prepared through a Fe3O4-seeded approach. Uniform Fe3O4 nanoparticles are foremost synthesized via the standard method in organic media. The injection of a S solution leads to the replacement of O in Fe3O4 through anion-exchange, which generates (110) facet-enriched FeS2 nuclei. The subsequent (110) facet-mediated oriented attachment and fusion of FeS2 nuclei produce ultrathin FeS2 nanosheets. As catalysts in the hydrogen evolution reaction, FeS2 nanosheets exhibit good electrochemical activity. Electronic supplementary information (ESI) available: EDX, AFM images, small-angle XRD pattern, SAED pattern, and TEM images of FeS2 nanosheets. See DOI: 10.1039/c6nr02211a

  5. Iron and Nickel Line Diagnostics for the Galactic Center Diffuse Emission

    CERN Document Server

    Koyama, K; Inui, T; Nakajima, H; Matsumoto, H; Tsuru, T G; Takahashi, T; Maeda, Y; Yamazaki, N; Murakami, H; Yamauchi, S; Tsuboi, Y; Senda, A; Kataoka, J; Takahashi, H; Holt, S S; Brown, G V; Koyama, Katsuji; Hyodo, Yoshiaki; Inui, Tatsuya; Nakajima, Hiroshi; Matsumoto, Hironori; Tsuru, Takeshi Go; Takahashi, Tadayuki; Maeda, Yoshitomo; Yamazaki, Noriko; Murakami, Hiroshi; Yamauchi, Shigeo; Tsuboi, Yohko; Senda, Atsushi; Kataoka, Jun; Takahashi, Hiromitsu; Holt, Stephen S; Brown, Gregory V

    2006-01-01

    We have observed the diffuse X-ray emission from the Galactic center (GC) using the X-ray Imaging Spectrometer (XIS) on Suzaku. The high-energy resolution and the low-background orbit provide excellent spectra of the GC diffuse X-rays (GCDX). The XIS found many emission lines in the GCDX near the energy of K-shell transitions of iron and nickel. The most pronounced features are FeI K alpha at 6.4 keV and K-shell absorption edge at 7.1 keV, which are from neutral and/or low ionization states of iron, and the K-shell lines at 6.7 keV and 6.9 keV from He-like (FeXXV K alpha) and hydrogenic (FeXXVI Ly alpha) ions of iron. In addition, K alpha lines from neutral or low ionization nickel (NiI K alpha) and He-like nickel (NiXXVII K alpha), and FeI K beta, FeXXV K beta, FeXXVI Ly beta, FeXXV K gamma and FeXXVI Ly gamma are detected for the first time. The line center energies and widths of FeXXV K alpha and FeXXVI Ly alpha favor a collisional excitation (CE) plasma for the origin of the GCDX. The electron temperature...

  6. Equilibrium Fe isotope fractionation between inorganic aqueous Fe(III) and the siderophore complex, Fe(III)-desferrioxamine B

    DEFF Research Database (Denmark)

    Dideriksen, Knud; Baker, Joel A.; Stipp, Susan Louise Svane

    2008-01-01

    be controlled by isotope fractionation between the free and complexed iron.We have determined the equilibrium Fe isotope fractionation induced by organic ligand activity in experiments with solutions having co-existing inorganic Fe(III) species and siderophore complexes, Fedesferrioxamine B (at pH 2). The two......In oxic oceans, most of the dissolved iron (Fe) exists as complexes with siderophore-like, strongly coordinating organic ligands. Thus, the isotope composition of the little amount of free inorganic Fe that is available for precipitation and preservation in the geological record may largely...... for the slower stage, indicating that approximately 40% reequilibration may take place during the separation of the two pools. To further test if the induced precipitation leads to experimental artefacts, the fractionation during precipitation of inorganic Fe was determined. Assuming a Rayleigh...

  7. Exchange biased FeNi/FeMn bilayers with coercivity and switching field enhanced by FeMn surface oxidation

    Directory of Open Access Journals (Sweden)

    A. V. Svalov

    2013-09-01

    Full Text Available FeNi/FeMn bilayers were grown in a magnetic field and subjected to heat treatments at temperatures of 50 to 350 °C in vacuum or in a gas mixture containing oxygen. In the as-deposited state, the hysteresis loop of 30 nm FeNi layer was shifted. Low temperature annealing leads to a decrease of the exchange bias field. Heat treatments at higher temperatures in gas mixture result in partial oxidation of 20 nm thick FeMn layer leading to a nonlinear dependence of coercivity and a switching field of FeNi layer on annealing temperature. The maximum of coercivity and switching field were observed after annealing at 300 °C.

  8. Sustaining reactivity of Fe(0) for nitrate reduction via electron transfer between dissolved Fe(2+) and surface iron oxides.

    Science.gov (United States)

    Han, Luchao; yang, Li; Wang, Haibo; Hu, Xuexiang; Chen, Zhan; Hu, Chun

    2016-05-05

    The mechanism of the effects of Fe(2+)(aq) on the reduction of NO3(-) by Fe(0) was investigated. The effects of initial pH on the rate of NO3(-) reduction and the Fe(0) surface characteristics revealed Fe(2+)(aq) and the characteristics of minerals on the surface of Fe(0) played an important role in NO3(-) reduction. Both NO3(-) reduction and the decrease of Fe(2+)(aq) exhibited similar kinetics and were promoted by each other. This promotion was associated with the types of the surface iron oxides of Fe(0). Additionally, further reduction of NO3(-) produced more surface iron oxides, supplying more active sites for Fe(2+)(aq), resulting in more electron transfer between Fe(2+) and surface iron oxides and a higher reaction rate. Using the isotope specificity of (57)Fe Mossbauer spectroscopy, it was verified that the Fe(2+)(aq) was continuously converted into Fe(3+) oxides on the surface of Fe(0) and then converted into Fe3O4 via electron transfer between Fe(2+) and the pre-existing surface Fe(3+) oxides. Electrochemistry measurements confirmed that the spontaneous electron transfer between the Fe(2+) and structural Fe(3+) species accelerated the interfacial electron transfer between the Fe species and NO3(-). This study provides a new insight into the interaction between Fe species and contaminants and interface electron transfer. Copyright © 2016 Elsevier B.V. All rights reserved.

  9. Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster

    NARCIS (Netherlands)

    Lichtenberg, C.; Viciu, L.; Vogt, M.; Rodríguez-Lugo, R.E.; Adelhardt, M.; Sutter, J.; Khusniyarov, M.M.; Meyer, K.; de Bruin, B.; Bill, E.; Grützmacher, H.

    2015-01-01

    A low-valent trinuclear iron complex with an unusual linear Fe(I)-Fe(II)-Fe(I) unit is presented. It is accessed in a rational approach using a salt metathesis reaction between a new anionic Fe(I) containing heterocycle and FeCl2. Its electronic structure was studied by single crystal XRD analysis,

  10. Composition and size dependence of magnetic properties of FePt/Fe exchange-spring films

    Energy Technology Data Exchange (ETDEWEB)

    Song, Yu; Zhang, Zhe; Duan, Nian; Wang, Jiawei; Chen, Yuang; Tong, Bei; Yang, Xiaofei; Zhang, Yue, E-mail: yue-zhang@mail.hust.edu.cn

    2014-12-15

    The composition and size dependence of the magnetic properties of FePt/Fe exchange-spring bilayer films was studied using micromagnetic simulation. Based on the simulated hysteresis loops for composite layers with an identical thickness of 20 nm and different composition ratios, it can be observed that when the thickness ratio of Fe is 10%, an exchange-spring effect with a negative nucleation field appears; the switching field is greatly reduced compared to the rigid magnetic FePt, and the squareness ratio reaches its maximum value. When the thickness ratio of Fe is 25% and more, the nucleation fields become positive; meanwhile, the coercivity is smaller than the switching field, and the squareness ratio decreases because of the increase in the thickness of the Fe film. In addition, at a fixed thickness ratio and total volume, the switching field of the FePt/Fe bilayer films is further reduced, accompanied by a decrease in the squareness ratio due to an increase in the thickness of the Fe layer. - Highlights: • Exchange-spring behavior of FePt/Fe multi-layers was studied via micro-magnetic simulation. • As total thickness is 20 nm, optimal magnetic property is shown when the thickness ratio of Fe is 10%. • As total thickness is 20 nm, nucleation fields are positive when the thickness ratio of Fe is 25% and larger. • As total thickness is 20 nm, coercivity is greatly reduced when the thickness ratio of Fe is 25% and larger. • Under fixed volume and the thickness ratio of Fe (10%), switching field can be reduced by reducing the bottom size.

  11. Structural and magnetic properties of Ce/Fe and Ce/FeCoV multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Tixier, S.; Boeni, P. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Mannix, D.; Stirling, W.G. [Liverpool Univ. (United Kingdom); Lander, G.H.

    1997-09-01

    Ce/Fe and Ce/FeCoV multilayers have been grown by magnetron sputtering. The interfaces are well defined and the layers are crystalline down to an individual layer thickness of 20 A. Ce/FeCoV multilayers show sharper interfaces than Ce/Fe but some loss of crystallinity is observed. Hysteresis loops obtained by SQUID show different behaviour of the bulk magnetisation as a function of the layer thickness. Fe moments are found by Moessbauer spectroscopy to be perpendicular to the interfaces for multilayers with small periodicity. (author) 2 figs., 2 refs.

  12. Bias dependent inversion of tunneling magnetoresistance in Fe/GaAs/Fe tunnel junctions

    OpenAIRE

    Moser, J.; Zenger, M.; Gerl, C.; Schuh, D.; Meier, R.; Chen, P.; Bayreuther, G.; Wegscheider, W.; Weiss, D; Lai, C. -H.; Huang, R. -T.; Kosuth, M.; Ebert, H.

    2006-01-01

    We investigated spin dependent transport through Fe/GaAs/Fe tunnel junctions. The tunneling magnetoresistance effect (TMR) was probed for different types of Fe/GaAs interfaces. For interfaces cleaned by hydrogen plasma the TMR effect is increased and observable at room temperature. If an epitaxial Fe/GaAs(001) interface is involved, the tunnel junction exhibits a bias dependent inversion of the TMR effect. This is a first experimental signature for band structure effects at a Fe/GaAs interfac...

  13. STUDY ON DETERMINATION OF TRACE Fe BY Fe(Ⅱ)-VA THIN LAYER RESIN PHASE SPECTROPHOTOMETRY

    Institute of Scientific and Technical Information of China (English)

    SONG Huanyu; YAN Yongsheng; WANG Yun

    2006-01-01

    A new method for the determination of Fe by thin layer resin phase spectrophotometry in alkali condition was reported. The complex anion formed by Fe(Ⅱ) and VA was absorbed on the 717#resin and Fe was determined by making thin layer. This method had a high sensitivity (ε620=3.0×105 L/mol·cm), which was 15 times higher than that of liquid phase spectrophotometry. It had been proved a satisfactory precision (5.0μg Fe, n=6, RSD=1.8%). The trace Fe in natural water was determined and the recovery was 97%.

  14. Mechanical alloying of Fe-Mn and Fe-Mn-Si

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    The ball milling of Fe-24Mn and Fe-24Mn-6Si mixed powders has been performed by the high energy ball milling technique.By employing X-ray diffraction and Moessbauer measurements.The ccmposition evolution during the milling process has been investigated.The results indicate the formation of paramagnetic Fe-Mn or Fe-Mn-Si alloys with a metastable fcc phase as final products.which imply that the Fe and Mn proceed a co-diffusion meenanism through the surface of fragmented powders.The thermal stability and composition evolution of the as-milled alloys were discussed comparing with the bulk alloy,.

  15. Origin of magnetostriction in Fe-Ga

    DEFF Research Database (Denmark)

    Mudivarthi, Chaitanya; Laver, Mark; Cullen, James

    2010-01-01

    This paper investigates the origin of large magnetostriction in Fe-Ga alloys using small-angle neutron scattering (SANS) and Kerr microscopy. The SANS data for a single-crystal, electron irradiated, and quenched Fe81Ga19 sample under externally applied magnetic and elastic fields revealed...

  16. Hard molecule-based magnet of Fe

    Science.gov (United States)

    Vaz, M. G. F.; Ardisson, J. D.; Stumpf, H. O.; Macedo, W. A. A.

    2001-05-01

    A new molecule-based magnet containing Fe 2+, Fe 3+, Cu(opba) 2- and Bu 4N +, with opba=ortho-phenylenebis(oxamato) and Bu 4N +=tetra-n-butylammonium, was synthesized. The samples were characterized by infrared spectroscopy, elemental analysis, atomic absorption, vibrating sample magnetometry and 57Fe Mössbauer spectroscopy. The magnetic measurements show that the compound presents a magnetic transition around 25 K and a high coercivity, around 1.3 T. Above the transition temperature, the Mössbauer spectrum is dominated by a broad doublet characteristic of Fe 2+. At 20 K, the spectrum shows clear magnetic splitting and at least two non-equivalent Fe sites can be identified. To the best of our knowledge, this compound presents the highest coercive field observed for an iron-based molecular magnetic system.

  17. Hard molecule-based magnet of Fe

    Energy Technology Data Exchange (ETDEWEB)

    Vaz, M.G.F. E-mail: vaz@urano.cdtn.br; Ardisson, J.D.; Stumpf, H.O.; Macedo, W.A.A

    2001-05-01

    A new molecule-based magnet containing Fe{sup 2+}, Fe{sup 3+}, Cu(opba){sup 2-} and Bu{sub 4}N{sup +}, with opba=ortho-phenylenebis(oxamato) and Bu{sub 4}N{sup +}=tetra-n-butylammonium, was synthesized. The samples were characterized by infrared spectroscopy, elemental analysis, atomic absorption, vibrating sample magnetometry and {sup 57}Fe Moessbauer spectroscopy. The magnetic measurements show that the compound presents a magnetic transition around 25 K and a high coercivity, around 1.3 T. Above the transition temperature, the Moessbauer spectrum is dominated by a broad doublet characteristic of Fe{sup 2+}. At 20 K, the spectrum shows clear magnetic splitting and at least two non-equivalent Fe sites can be identified. To the best of our knowledge, this compound presents the highest coercive field observed for an iron-based molecular magnetic system.

  18. Thermodynamic Properties of $^{56,57}$Fe

    CERN Document Server

    Algin, E; Guttormsen, M; Larsen, A C; Mitchell, G E; Rekstad, J; Schiller, A; Siem, S; Voinov, A

    2008-01-01

    Nuclear level densities for $^{56,57}$Fe have been extracted from the primary $\\gamma$-ray spectra using ($^3$He,$^3$He$^{\\prime}\\gamma$) and ($^3$He,$\\alpha \\gamma$) reactions. Nuclear thermodynamic properties for $^{56}$Fe and $^{57}$Fe are investigated using the experimental level densities. These properties include entropy, Helmholtz free energy, caloric curves, chemical potential, and heat capacity. In particular, the breaking of Cooper pairs and single-quasiparticle entropy are discussed and shown to be important concepts for describing nuclear level density. Microscopic model calculations are performed for level densities of $^{56,57}$Fe. The experimental and calculated level densities are compared. The average number of broken Cooper pairs and the parity distribution are extracted as a function of excitation energy for $^{56,57}$Fe from the model calculations.

  19. Availability and toxicity of Fe(Ⅱ) and Fe(Ⅲ) in Caco-2 cells

    Institute of Scientific and Technical Information of China (English)

    Wan-ling HE; Ying FENG; Xiao-li LI; Yan-yan WEI; Xiao-e YANG

    2008-01-01

    The objective of the present study was to compare the toxicity and availability of Fe(Ⅱ) and Fe(Ⅲ) to Caco-2 cells.Cellular damage was studied by measuring cell proliferation and lactate dehydrogenase (LDH) release. The activities of two major antioxidative enzymes [superoxide dismutase (SOD) and glutathione peroxidase (GPx)] and differentiation marker (alkaline phosphatase) were determined after the cells were exposed to different levels of iron salts. The cellular iron concentration was investigated to evaluate iron bioavailability. The results show that iron uptake of the cells treated with Fe(Ⅱ) is significantly higher than that of the cells treated with Fe(Ⅲ) (P<0.05). Fe(Ⅱ) at a concentration>1.5 mmol/L was found to be more effective in reducing cellular viability than Fe(Ⅲ). LDH release investigation suggests that Fe(Ⅱ) can reduce stability of the cell membrane. The activities of SOD and GPx of the cells treated with Fe(Ⅱ) were higher than those of the cells treated with Fe(Ⅲ), although both of them increased with raising iron supply levels. The results indicate that both Fe(Ⅱ) and Fe(Ⅲ) could reduce the cellular antioxidase gene expression at high levels.

  20. Photochemical Formation of Fe(II) in the Aqueous Solutions of Fe(III)- Dicarboxylates

    Science.gov (United States)

    Okada, K.; Arakaki, T.

    2007-12-01

    Although there have been many studies reporting the photochemical formation of Fe(II) in various aqueous-phase such as rain, cloud waters, seawater and aerosols, the detailed formation mechanisms are not well understood. To better understand the mechanisms of Fe(II) formation, we attempted to determine the molar absorptivity and the quantum yield of Fe(II) photoformation for individual Fe(III)-dicarboxylate species. The concentrations of Fe(II) and total dissolved Fe were measured by a Ferrozine-HPLC method. The Visual MINTEQ computer program was used to calculate the equilibrium concentrations of chemical species in the solutions of Fe(III)-dicarboxylate complexes. The molar absorptivity and the product of the quantum yield and the molar absorptivity of Fe(III)- dicarboxylate complex can be analysed by UV-VIS spectrophotometer and photochemical experiments, and these experimental data were combined with the calculated equilibrium Fe(III) speciation to determine individual molar absorptivity and quantum yield of Fe(II) photoformation for a specific Fe(III)-dicarboxylate complex. Preliminary results, using an oxalate whose quantum yield has been previously reported, indicate that this approach gives lower quantum yield values in air saturated solutions than previously reported.

  1. Moessbauer and XRD study of pulse plated Fe-P and Fe-Ni thin layers

    Energy Technology Data Exchange (ETDEWEB)

    Miko, Annamaria [Bay Zoltan Institute for Material Science (Hungary); Kuzmann, Erno, E-mail: kuzmann@para.chem.elte.hu [Eoetvoes Lorand University, Research Group for Nuclear Methods in Structural Chemistry, Hungarian Academy of Sciences, Department of Nuclear Chemistry (Hungary); Lakatos-Varsanyi, Magda [Bay Zoltan Institute for Material Science (Hungary); Kakay, Attila [Research Institute for Solid State Physics and Optics (Hungary); Nagy, Ferenc [Eoetvoes Lorand University, Research Group for Nuclear Methods in Structural Chemistry, Hungarian Academy of Sciences, Department of Nuclear Chemistry (Hungary); Varga, Lajos Karoly [Research Institute for Solid State Physics and Optics (Hungary)

    2005-09-15

    {sup 57}Fe conversion electron Moessbauer spectroscopy, X-ray diffraction, electrochemical and magnetic measurements were used to study pulse electroplated Fe-P and Ni-Fe coatings. XRD and {sup 57}Fe CEMS measurements revealed the amorphous character of the novel pulse plated Fe-P alloys. CEM spectra indicated significant differences in the short range order and in the magnetic anisotropy between the Fe-P deposits pulse plated at medium long deposition time (t{sub on} = 2 ms), with short relaxation time (t{sub off} = 9 ms) and low current density (I{sub p} = 0.05 Acm{sup -2}) or at short deposition time (t{sub on} = 1 ms) with long relaxation time (t{sub off} = 250 ms) and high current density (I{sub p} = 1.0 Acm{sup -2}). The broad peaks centred around the fcc reflections in XRD of the pulse plated Ni-22 wt.% Fe deposit reflected a microcrystalline Ni-Fe alloy with a very fine, 5-8 nm, grain size. The CEM spectrum of the pulse plated Ni-22 wt.% Fe coating corresponded to a highly disordered solid solution alloy containing a minute amount of ferrihydrite. Extreme favourable soft magnetic properties were observed with these Ni-Fe and Fe-P pulse plated thin layers.

  2. Anomalous spin state of Fe in double perovskite oxide Sr 2FeWO 6

    Science.gov (United States)

    Kawanaka, H.; Hase, I.; Toyama, S.; Nishihara, Y.

    2000-07-01

    In the series of Sr 2FeTO 6 (T=4d or 5d), the valence of Fe is 3+ in most of the compounds. However, recently we have found that the Sr 2FeWO 6 has Fe 2+ state. Sr 2FeWO 6 is an insulator with an antiferromagnetic transition temperature of 37 K. From the Mössbauer experiment, below ∼20 K, a center shift of +1.2 mm/ s relative to metallic iron and a quadrupole splitting of 1.9 mm/ s are obtained. The quadrupole splitting has strong temperature dependence. The hyperfine field is ∼110 kOe which seems to be quite small. We concluded that the iron ground state of Sr 2FeWO 6 is Fe 2+ high-spin ( S=2) state.

  3. Gas phase synthesis of core-shell Fe@FeO x magnetic nanoparticles into fluids

    Science.gov (United States)

    Aktas, Sitki; Thornton, Stuart C.; Binns, Chris; Denby, Phil

    2016-12-01

    Sorbitol, short chain molecules, have been used to stabilise of Fe@FeO x nanoparticles produced in the gas phase under the ultra-high vacuum (UHV) conditions. The sorbitol coated Fe@FeO x nanoparticles produced by our method have a narrow size distribution with a hydrodynamic diameter of 35 nm after NaOH is added to the solution. Magnetisation measurement shows that the magnetic nanoparticles are superparamagnetic at 100 K and demonstrate hysteresis at 5 K with an anisotropy constant of 5.31 × 104 J/m3 (similar to bulk iron). Also, it is shown that sorbitol is only suitable for stabilising the Fe@FeO x suspensions, and it does not prevent further oxidation of the metallic Fe core. According to MRI measurement, the nanoparticles have a high transverse relaxation rate of 425 mM-1 s-1.

  4. Preparation and Properties of Amorphous NiFe/Cu/NiFe Thin Films

    Institute of Scientific and Technical Information of China (English)

    YE Yun; JIANG Ya-dong; HU Wen-cheng; ZENG Hong-juan

    2004-01-01

    The amorphous of Permalloy on the copper subtract was studied using composite electroplating method. A portion of hydrogen brings the counteraction on the surface of cathode leading nickel-iron alloys to be anomalous in the process of co-depositing. The results of X-ray diffraction (XRD) show that the Ni-Fe alloys layer is amorphous. The Giant Magneto -Impedance (GMI) effect of Ni-Fe alloys was obtained under the optimal conditions, dependence on the soft magnetic property of Ni-Fe amorphous thin film. As a result, the ratios△ Z/Z of NiFe/Cu/NiFe amorphous thin film are 30% at 40 kHz which is in low frequency. Furthermore, the GMI value of NiFe/Cu/NiFe amorphous thin film with a sandwich structure is higher than that of single-layer ferromagnetic films of the same thickness.

  5. High Pressure Behavior of FeOOH

    Science.gov (United States)

    Reagan, M. M.; Gleason, A. E.; Mao, W. L.

    2013-12-01

    Understanding the stability and properties of simple hydroxides at high pressures and temperatures offers an important first step toward quantifying more complex hydrogen-bearing compounds relevant to the Earth's interior. We focus on iron-oxy-hydroxides because they may be an important Fe and water bearing component in the deep Earth. Goethite (α-FeOOH) transforms to a high-pressure phase, ɛ-FeOOH, which is isostructural with δ-AlOOH, a material which may transport hydrogen to the core-mantle boundary. Here we present XES spectroscopy data of powder samples of synthesized alpha-FeOOH, beta-FeOOH and gamma-FeOOH monitoring their electronic spin transition. The samples was loaded into a Beryllium gasket, where a 50 micron hole served as the sample chamber with 300 micron culet diamond paired with a beveled 150 micron diamond in a diamond-anvil cell (DAC) without a pressure transmitting medium. Pressure was determined using ruby fluorescence (Mao et al. 1978). Using the incident X-ray energy centered at 11.3 KeV from the Advanced Photon Source, beam line HPCAT 16-ID-D, we measured Fe K-β 13 emission to pressures greater than 73 GPa. For alpha-FeOOH, we saw a clear shift in the main peak to lower energy, and an increasingly diminishing K beta prime peak intensity, indicating the sample was undergoing an electronic spin transition. The K beta prime peak completely disappeared at a pressure greater than 73 GPa. Beta-FeOOH showed no evidence of the beginnings of a spin transition, while gamma- FeOOH underwent an incomplete transition.

  6. Spin polarization effect for Fe2 molecule

    Institute of Scientific and Technical Information of China (English)

    Yan Shi-Ying; Zhu Zheng-He

    2006-01-01

    This paper uses the density functional theory (DFT)(B3p86) of Gaussian03 to optimize the structure of Fe2 molecule. The result shows that the ground state for Fe2 molecule is a 9-multiple state, which shows spin polarization effect of Fe2 molecule of transition metal elements for the first time. Meanwhile, we have not found any spin pollution because the wavefunction of the ground state does not mingle with wavefunctions with higher energy states. So, that the ground state for Fe2 molecule is a 9-multiple state is indicative of the spin polarization effect of Fe2 molecule of transition metal elements. That is, there exist 8 parallel spin electrons. The non-conjugated electron is greatest in number. These electrons occupy different spacious tracks, so that the energy of the Fe2 molecule is minimized. It can be concluded that the effect of parallel spin of the Fe2 molecule is larger than the effect of the conjugated molecule, which is obviously related to the effect of electron d delocalization. In addition, the Murrell-Sorbie potential functions with the parameters for the ground state and other states of Fe2 molecule are derived. Dissociation energy De for the ground state of Fe2 molecule is 2.8586ev, equilibrium bond length Re is 0.2124nm, vibration frequency ωe is 336.38 cm-1. Its force constants f2, f3, and f4 are 1.8615aJ·nm-2, -8.6704a J·nm-3, 29.1676aJ·nm-4 respectively. The other spectroscopic data for the ground state of Fe2 moleculeωeχe, Be, αe are 1.5461 cm-1, 0.1339 cm-1, 7.3428×10-4 cm-1 respectively.

  7. A method for determination of [Fe3+]/[Fe2+] ratio in superparamagnetic iron oxide

    Science.gov (United States)

    Jiang, Changzhao; Yang, Siyu; Gan, Neng; Pan, Hongchun; Liu, Hong

    2017-10-01

    Superparamagnetic iron oxide nanoparticles (SPION), as a kind of nanophase materials, are widely used in biomedical application, such as magnetic resonance imaging (MRI), drug delivery, and magnetic field assisted therapy. The magnetic property of SPION has close connection with its crystal structure, namely it is related to the ratio of Fe3+ and Fe2+ which form the SPION. So a simple way to determine the content of the Fe3+ and Fe2+ is important for researching the property of SPION. This review covers a method for determination of the Fe3+ and Fe2+ ratio in SPION by UV-vis spectrophotometry based the reaction of Fe2+ and 1,10-phenanthroline. The standard curve of Fe with R2 = 0.9999 is used for determination the content of Fe2+ and total iron with 2.5 mL 0.01% (w/v) SPION digested by HCl, pH = 4.30 HOAc-NaAc buffer 10 mL, 0.01% (w/v) 1,10-phenanthroline 5 mL and 10% (w/v) ascorbic acid 1 mL for total iron determine independently. But the presence of Fe3+ interfere with obtaining the actual value of Fe2+ (the error close to 9%). We designed a calibration curve to eliminate the error by devising a series of solution of different ratio of [Fe3+]/[Fe2+], and obtain the calibration curve. Through the calibration curve, the error between the measured value and the actual value can be reduced to 0.4%. The R2 of linearity of the method is 0.99441 and 0.99929 for Fe2+ and total iron respectively. The error of accuracy of recovery and precision of inter-day and intra-day are both lower than 2%, which can prove the reliability of the determination method.

  8. Magnetic nanowires (Fe, Fe-Co, Fe-Ni – magnetic moment reorientation in respect of wires composition

    Directory of Open Access Journals (Sweden)

    Kalska-Szostko Beata

    2015-03-01

    Full Text Available Magnetic nanowires of Fe, Fe-Co, and Fe-Ni alloy and layered structure were prepared by electrochemical alternating current (AC deposition method. The morphology of the nanowires in and without the matrix was studied by energy dispersive X-ray spectroscopy (EDX, scanning electron microscopy (SEM, and X-ray diffraction (XRD, respectively. The wires either show strong dependence on the combination of elements deposition (alloy or layered or chemical composition (Co or Ni. The magnetic properties of the nanostructures were determined on the basis of Mössbauer spectroscopy (MS.

  9. Ordering phenomena in FeCo-films and Fe/Cr-multilayers: an X-ray and neutron scattering study

    Energy Technology Data Exchange (ETDEWEB)

    Nickel, B.

    2001-07-01

    The following topics are covered: critical phenomena in thin films, critical adsorption, finite size scaling, FeCo Ising model, kinematical scattering theory for thin films, FeCo thin films, growth and characterisation of single crystal FeCo thin films, X-ray study of ordering in FeCo films, antiferromagnetic coupling in Fe/Cr multilayers, neutron scattering on Fe/Cr multilayers (WL)

  10. Fe stable isotope fractionation in modern and ancient hydrothermal Fe-Si deposits

    Science.gov (United States)

    Moeller, K.; Schoenberg, R.; Thorseth, I. H.; Øvreås, L.; Pedersen, R.

    2010-12-01

    Modern iron-silica deposits of small yellow to rust coloured mounds and chimney-like structures were found in a low-temperature venting area distal to a white smoker type hydrothermal vent site at the south-western part of the Mohns Ridge, North Atlantic. Individual stratified mm to cm thick laminated layers within these structures are largely composed of branching, twisted filaments resembling encrusted stalks of Fe-oxidising bacteria. DNA analyses have confirmed the presence of both Fe-oxidising (Mariprofundus ferrooxidans and other ζ-Proteobacteria) and Fe-reducing bacteria (Shewanellaceae). Similar morphologic features, such as several mm thick red hematite-rich laminae and micron-scale filamentous structures concentrated in discrete laminae, have also been found in Early Ordovician volcanogenic massive sulphide (VMS) hosted jasper deposits in the Løkken-Høydal area, Norway [1]. These filamentous structures are believed to be formed by Fe-oxidising bacteria similar to Mariprofundus ferrooxidans [2]. Here, we compare the Fe isotope composition of these two different types of Fe-Si deposits with the aim to gain further information about deposition mechanisms and the role of microorganisms in Fe redox cycling of deep-sea hydrothermal systems. Fe isotope compositions of the modern biogenic Fe-Si deposit vary between -2.09 and -0.66 ‰ in δ56Fe values, a range that is comparable to late Archaean to early Proterozoic banded iron formations. The ~490 Ma old Løkken jaspers show a similar variation, but with significantly higher δ56Fe values ranging from -0.39 to +0.89 ‰. The Fe isotopic composition of the Løkken jaspers clearly correlates with morphological features with the lowest δ56Fe values in layered and the highest ones in brecciform jaspers. Our data demonstrate that variations in Fe isotope compositions of the modern Fe-Si deposit cannot be explained by a single process, but rather reflect the full complexity of Fe redox cycling within deep

  11. Ge doping of FeGa3

    Science.gov (United States)

    Alvarez-Quiceno, J. C.; Cabrera-Baez, M.; Munévar, J.; Micklitz, H.; Bittar, E. M.; Baggio-Saitovitch, E.; Ribeiro, R. A.; Avila, M. A.; Dalpian, G. M.; Osorio-Guillén, J. M.

    2015-03-01

    The intermetallic narrow-gap semiconductor FeGa3 is one of the few Fe-based diamagnetic materials. Experimentally, Ge doping induces a ferromagnetic (FM) state. The mechanism responsible for this FM response is still unestablished, but there are proposals of itinerant magnetism to explain this behavior. Our DFT simulations show that inserting holes induces a delocalized FM response, while inserting electrons induces a localized FM response around some Fe atoms. We also modeled different distributions of Ge substitution and observe that the FM response depends on the Ge concentration and also on the Ge distribution on the Ga sites. We observed that the extra electrons become localized in some specific Fe atoms, rather than delocalized over the entire crystal lattice, as expected from an itinerant model. For experimental probing of this scenario, we have performed 57Fe Mössbauer spectroscopy on flux-grown singlecrystalline samples. The resulting resonance peak shape supports a localized model for ferromagnetism, since it is possible to resolve the presence of two distinct Fe isomer shifts (despite a single crystallographic site), expected to correspond to Fe atoms with high and low magnetic moments. The authors thank Capes, CNPQ and FAPESP for financial support.

  12. Change of Electronic Structure and Magnetic Properties with MgO and Fe Thicknesses in Fe/MgO/Fe Magnetic Tunnel Junction

    Institute of Scientific and Technical Information of China (English)

    YANG Fan; BI Xiao-fang

    2006-01-01

    The effects of the thickness of MgO and Fe on the electronic structure and magnetic properties of Fe/MgO/Fe magnetic tunnel junction was studied using the first principle method. Two series of models with MgO of different thicknesses: Fe(3)MgO(t)Fe(3) (t=1,3,5,7) and with Fe of varied thicknesses: Fe(t)MgO(3)Fe(t) (t=3,4,5,6,7) were established. Calculated results show that in all the models the magnetic moment of Fe increases at the Fe/MgO interface and surface as compared with that of the inner layers. The magnetic moment of each Fe layer was found to be independent of MgO thicknesses, while the spin-polarization of Fe layer at the interface shows a slight change in function of the MgO thicknesses. The tunneling magnetoresistance (TMR) ratio estimated by the Julliere model has the same change tendency as the spin-polarization has, and the largest value is obtained at the MgO thickness of 5 atomic layers. When the Fe thickness increases, the spin-polarization of interface Fe layer follows up an increase with a decrease. The highest TMR value is achieved when the Fe thickness is of 4 atomic layers.

  13. Fe(II)EDTA-NO reduction coupled with Fe(II)EDTA oxidation by a nitrate- and Fe(III)-reducing bacterium.

    Science.gov (United States)

    Dong, Xiyang; Zhang, Yu; Zhou, Jiti; Chen, Mingxiang; Wang, Xiaojun; Shi, Zhuang

    2013-06-01

    The nitrate- and Fe(III)-reducing bacterium Paracoccus versutus LYM was characterized in terms of its ability to perform Fe(II)EDTA-NO reduction coupled with Fe(II)EDTA oxidation (NO-dependent Fe(II)EDTA oxidation, NDFO). It experienced a single anaerobic FeEDTA redox cycling through NDFO and dissimilatory Fe(III)EDTA reduction in FeEDTA culture. The increase in the Fe(II)EDTA concentration contributed to the ascending Fe(II)EDTA-NO reduction rate. The amount of glucose controlled the rate and extent of Fe(II) oxidation during NDFO. Without glucose addition, Fe(II)EDTA-NO reduction rate was at a rather slow rate even in presence of relatively sufficient Fe(II)EDTA. Unlike aqueous Fe(2+) and solid-phase Fe(II), Fe(II)EDTA could prevent cells from encrustations. These findings suggested the occurrence of NDFO preferred being beneficial via a mixotrophic physiology in the presence of an organic cosubstrate to being out of consideration for metabolic strategy.

  14. High-resolution photoelectron imaging spectroscopy of cryogenically cooled Fe4O- and Fe5O-

    Science.gov (United States)

    Weichman, Marissa L.; DeVine, Jessalyn A.; Neumark, Daniel M.

    2016-08-01

    We report high-resolution photodetachment spectra of the cryogenically cooled iron monoxide clusters Fe4O- and Fe5O- obtained with slow photoelectron velocity-map imaging (cryo-SEVI). Well-resolved vibrational progressions are observed in both sets of spectra, and transitions to low-lying excited states of both species are seen. In order to identify the structural isomers, electronic states, and vibrational modes that contribute to the cryo-SEVI spectra of these clusters, experimental results are compared with density functional theory calculations and Franck-Condon simulations. The main bands observed in the SEVI spectra are assigned to the 15A2←16B2 photodetachment transition of Fe4O- and the 17A'←18A″ photodetachment transition of Fe5O-. We report electron affinities of 1.6980(3) eV for Fe4O and 1.8616(3) eV for Fe5O, although there is some uncertainty as to whether the 15A2 state is the true ground state of Fe4O. The iron atoms have a distorted tetrahedral geometry in Fe4O0/- and a distorted trigonal-bipyramidal arrangement in Fe5O0/-. For both neutral and anionic species, the oxygen atom preferably binds in a μ2-oxo configuration along the cluster edge. This finding is in contrast to prior predictions that Fe5O0/- exhibits a μ3 face-bound structure.

  15. Fe-aminoclay-entrapping electrospun polyacrylonitrile nanofibers (FeAC-PAN NFs) for environmental engineering applications

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jae Young [Korea Railroad Research Institute, Uiwang (Korea, Republic of); Choi, Saehae [Korea Research Institute of Bioscience and Biotechnology, Daejeon (Korea, Republic of); Park, Seung Bin [KAIST, Daejeon (Korea, Republic of); Kim, Mooon Il; Lee, Young Chul [Gachon Univ., Seongnam (Korea, Republic of); Lee, Go Woon [KIER, Daejeon (Korea, Republic of); Lee, Hyun Uk [Korea Basic Science Institute, Daejeon (Korea, Republic of)

    2015-09-15

    Electrospun polyacrylonitrile nanofibers (PAN NFs) with entrapped water-soluble Fe-aminoclay (FeAC) [FeAC-PAN NFs] were prepared. Slow dropwise addition of water-soluble FeAC into a PAN solution, less aggregated of FeAC into electrospun PAN NFs was one-pot evolved without FeAC post-decoration onto as-prepared PAN NFs. Taking into consideration both the Fe{sup 3+} source in FeAC and the improved surface hydrophilicity, the feasibility of Fentonlike reaction for decolorization of cationic model dye methylene blue (MB) under 6 hrs UV-light irradiation was established. In the case where FeAC-PAN NFs were enhanced by hydrogen peroxide (H{sub 2}O{sub 2}) injection, the apparent kinetic reaction rates were increased relative to those for the PAN NFs. Thus, our flexible FeAC-PAN NF mats can be effectively utilized in water/waste treatment and other environmental engineering applications.

  16. Biomineralization associated with microbial reduction of Fe3+ and oxidation of Fe2+ in solid minerals

    Science.gov (United States)

    Zhang, G.; Dong, H.; Jiang, H.; Kukkadapu, R.K.; Kim, J.; Eberl, D.; Xu, Z.

    2009-01-01

    Iron-reducing and oxidizing microorganisms gain energy through reduction or oxidation of iron, and by doing so play an important role in the geochemical cycling of iron. This study was undertaken to investigate mineral transformations associated with microbial reduction of Fe3+ and oxidation of Fe2+ in solid minerals. A fluid sample from the 2450 m depth of the Chinese Continental Scientific Drilling project was collected, and Fe3+-reducing and Fe2+-oxidizing microorganisms were enriched. The enrichment cultures displayed reduction of Fe3+ in nontronite and ferric citrate, and oxidation of Fe2+ in vivianite, siderite, and monosulfide (FeS). Additional experiments verified that the iron reduction and oxidation was biological. Oxidation of FeS resulted in the formation of goethite, lepidocrocite, and ferrihydrite as products. Although our molecular microbiological analyses detected Thermoan-aerobacter ethanolicus as a predominant organism in the enrichment culture, Fe3+ reduction and Fe2+ oxidation may be accomplished by a consortia of organisms. Our results have important environmental and ecological implications for iron redox cycling in solid minerals in natural environments, where iron mineral transformations may be related to the mobility and solubility of inorganic and organic contaminants.

  17. Effect of oxidation rate and Fe(II) state on microbial nitrate-dependent Fe(III) mineral formation.

    Science.gov (United States)

    Senko, John M; Dewers, Thomas A; Krumholz, Lee R

    2005-11-01

    A nitrate-dependent Fe(II)-oxidizing bacterium was isolated and used to evaluate whether Fe(II) chemical form or oxidation rate had an effect on the mineralogy of biogenic Fe(III) (hydr)oxides resulting from nitrate-dependent Fe(II) oxidation. The isolate (designated FW33AN) had 99% 16S rRNA sequence similarity to Klebsiella oxytoca. FW33AN produced Fe(III) (hydr)oxides by oxidation of soluble Fe(II) [Fe(II)sol] or FeS under nitrate-reducing conditions. Based on X-ray diffraction (XRD) analysis, Fe(III) (hydr)oxide produced by oxidation of FeS was shown to be amorphous, while oxidation of Fe(II)sol yielded goethite. The rate of Fe(II) oxidation was then manipulated by incubating various cell concentrations of FW33AN with Fe(II)sol and nitrate. Characterization of products revealed that as Fe(II) oxidation rates slowed, a stronger goethite signal was observed by XRD and a larger proportion of Fe(III) was in the crystalline fraction. Since the mineralogy of Fe(III) (hydr)oxides may control the extent of subsequent Fe(III) reduction, the variables we identify here may have an effect on the biogeochemical cycling of Fe in anoxic ecosystems.

  18. Interactions Between Fe(III)-oxides and Fe(III)-phyllosilicates During Microbial Reduction 2: Natural Subsurface Sediments

    Energy Technology Data Exchange (ETDEWEB)

    Wu, T.; Griffin, A. M.; Gorski, C. A.; Shelobolina, E. S.; Xu, H.; Kukkadapu, R. K.; Roden, E. E.

    2016-04-19

    Dissimilatory microbial reduction of solid-phase Fe(III)-oxides and Fe(III)-bearing phyllosilicates (Fe(III)-phyllosilicates) is an important process in anoxic soils, sediments, and subsurface materials. Although various studies have documented the relative extent of microbial reduction of single-phase Fe(III)-oxides and Fe(III)-phyllosilicates, detailed information is not available on interaction between these two processes in situations where both phases are available for microbial reduction. The goal of this research was to use the model dissimilatory iron-reducing bacterium (DIRB) Geobacter sulfurreducens to study Fe(III)-oxide vs. Fe(III)-phyllosilicate reduction in a range of subsurface materials and Fe(III)-oxide stripped versions of the materials. Low temperature (12K) Mossbauer spectroscopy was used to infer changes in the relative abundances of Fe(III)-oxide, Fe(III)-phyllosilicate, and phyllosilicate-associated Fe(II) (Fe(II)-phyllosilicate). A Fe partitioning model was employed to analyze the fate of Fe(II) and assess the potential for abiotic Fe(II)-catalyzed reduction of Fe(III)-phyllosilicates. The results showed that in most cases Fe(III)- oxide utilization dominated (70-100 %) bulk Fe(III) reduction activity, and that electron transfer from oxide-derived Fe(II) played only a minor role (ca. 10-20 %) in Fe partitioning. In addition, the extent of Fe(III)-oxide reduction was positively correlated to surface area-normalized cation exchange capacity and the phyllosilicate-Fe(III)/total Fe(III) ratio, which suggests that the phyllosilicates in the natural sediments promoted Fe(III)-oxide reduction by binding of oxide-derived Fe(II), thereby enhancing Fe(III)-oxide reduction by reducing or delaying the inhibitory effect that Fe(II) accumulation on oxide and DIRB cell surfaces has on Fe(III)-oxide reduction. In general our results suggest that although Fe(III)-oxide reduction is likely to dominate bulk Fe(III) reduction in most subsurface sediments, Fe

  19. The effects of FeCl₃ and Fe-EDTA on the development of psoriasis.

    Science.gov (United States)

    Shi, Qiang; Yang, Xiao-qian; Cui, Xi

    2011-04-01

    The effects of FeCl₃ and Fe-EDTA on the development of psoriasis were studied in the mouse model of vaginal epithelium and tail epidermis. The mitoses of vaginal epithelial cell in female mice of their estrogenic stage and the formation of granular cell layers in male mouse tail scale were observed. Mice were randomly divided into eight groups and treated with normal saline, methotrexate, and different doses of two iron forms, FeCl₃ and Fe-EDTA, respectively, for 10 days. To explore the influence of FeCl₃ and Fe-EDTA on the excretion of Cu, Fe, Zn, Ca, Mg, Mn, and Se, the concentration of those elements in liver and kidney was analyzed by atomic absorption spectrometry. The different doses of FeCl₃ or Fe-EDTA could obviously inhibit the mitoses of vaginal epithelial cell (pEDTA, and between experimental groups and methotrexate group acted as the positive control (p>0.05). Compared with the negative group, the concentrations of Cu, Fe, Zn, Ca, Mg, Mn, and Se in liver and kidney of experimental groups and positive control group were not significantly changed (p > 0.05). FeCl₃ and Fe-EDTA are as effective as methotrexate on inhibiting hyperplasia of epidermal cells and increasing the formation of granular cell layers, and the concentrations of Cu, Fe, Zn, Ca, Mg, Mn, and Se in liver and kidney of experimental groups and positive control group were not significantly changed compared with the negative group, possibly retarding the development of psoriasis.

  20. Fe Protein-Independent Substrate Reduction by Nitrogenase MoFe Protein Variants

    Energy Technology Data Exchange (ETDEWEB)

    Danyal, Karamatullah; Rasmussen, Andrew J.; Keable, Stephen M.; Inglet, Boyd S.; Shaw, Sudipta; Zadvornyy, Oleg; Duval, Simon S.; Dean, Dennis R.; Raugei, Simone; Peters, John W.; Seefeldt, Lance C.

    2015-04-21

    The reduction of substrates catalyzed by nitrogenase normally requires nucleotide-dependent Fe protein delivery of electrons to the MoFe protein, which contains the active site FeMo-cofactor. Here, it is reported that independent substitution of three amino acids (ß-98Tyr→His, α-64Tyr→His, and ß-99Phe→His) located between the P cluster and FeMo-cofactor within the MoFe protein endows it with the ability to reduce protons to H2, azide to ammonia, and hydrazine to ammonia without the need for Fe protein or ATP. Instead, electrons can be provided by the low potential reductant polyaminocarboxylate ligated Eu(II) (Em -1.1 to -0.84 V vs NHE). The crystal structure of the ß-98Tyr→His variant MoFe protein was determined, revealing only small changes near the amino acid substitution that affect the solvent structure and immediate vicinity between the P cluster and the FeMo-cofactor, with no global conformational changes observed. Computational normal mode analysis on the nitrogenase complex reveal coupling in the motions of the Fe protein and the region of the MoFe protein with these three amino acids, which suggests a possible mechanism for how Fe protein might communicate deep within the MoFe protein subtle changes that profoundly affect intramolecular electron transfer and substrate reduction. This work was supported by a grant from the National Science Foundation (MCB-1330807) to JWP and LCS. This material is based upon work supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences (DE-SC0010687 and DE-SC0010834 to LCS and DRD) and the Division of Chemical Sciences, Geosciences, and Bio-Sciences (SR). The coordinates for the ß-98His MoFe protein were deposited with the Protein Data Bank (PDB 4XPI).

  1. Curie temperature rising by fluorination for Sm2Fe17

    Directory of Open Access Journals (Sweden)

    Matahiro Komuro

    2013-02-01

    Full Text Available Fluorine atoms can be introduced to Sm2Fe17 using XeF2 below 423 K. The resulting fluorinated Sm2Fe17 powders have ferromagnetic phases containing Sm2Fe17FY1(0Fe17FY2 (1Fe17, and α-Fe. The unit cell for Sm2Fe17 is elongated by the fluorination. The largest unit cell volume among the rhombohedral Sm2Fe17 compounds is 83.8 nm3, which is 5.8% larger than Sm2Fe17. The rhombohedral Sm2Fe17 with the largest unit cell volume is dissociated above 873 K, and fluorination increases Curie temperature from 403 K for Sm2Fe17 to 675 K. This increase can be explained by the magneto-volume effect.

  2. Biosynthesis of Nitrogenase FeMoco

    OpenAIRE

    Hu, Yilin; Ribbe, Markus W.

    2011-01-01

    Biosynthesis of nitrogenase FeMoco is a highly complex process that requires, minimally, the participation of nifS, nifU, nifB, nifE, nifN, nifV, nifH, nifD and nifK gene products. Previous genetic analyses have identified the essential factors for the assembly of FeMoco; however, the exact functions of these factors and the precise sequence of events during the assembly process had remained unclear until recently, when a number of the biosynthetic intermediates of FeMoco were identified and ...

  3. Mössbauer spectroscopic studies in U-Fe and U-Fe-Zr alloys

    Energy Technology Data Exchange (ETDEWEB)

    Panda, Alaka; Singh, L. Herojit; Rajagopalan, S.; Govindaraj, R., E-mail: govind@igcar.gov.in; Ramachandran, Renjith; Kalavathi, S.; Amarendra, G. [Materials Science Group, Indira Gandhi Centre for Atomic Research, Kalpakkam (India)

    2016-05-23

    {sup 57}Fe Mössbauer studies have been carried out in an alloy of U and Fe with atomic percentage in the ratio of 68%:32% in order to understand the local structure and valence of Fe atoms associated with different phases that may get formed. The effect of changes in the hyperfine parameters such as isomer shift and quadrupole splitting at Fe sites due to additional alloying of Zr has been studied in an alloy of U, Fe and Zr in the ratio of 44%:33%:23% respectively with respect to that of the U-Fe alloy chosen in the present study. Possible effect of solute clustering in these systems has been addressed in an analogous alloy of uranium and zirconium using positron lifetime spectroscopy.

  4. Fe and N diffusion in nitrogen-rich FeN measured using neutron reflectometry

    Indian Academy of Sciences (India)

    Mukul Gupta; A Gupta; A Wildes; T Gutberlet

    2008-11-01

    Grazing incidence neutron reflectometry provides an opportunity to measure the depth profile of a thin film sample with a resolution <1 nm, in a non-destructive way. In this way the diffusion across the interfaces can also be measured. In addition, neutrons have contrast among the isotopes, making it feasible to measure the self-diffusion. In the present work, the isotope multilayers of [FeN/57 FeN]10 and [FeN/Fe15N]10 were prepared using magnetron sputtering and self-diffusion of Fe and N was investigated. It was found that N diffusion is slower compared to Fe and does not follow the atomic size dependence.

  5. SPIN-DEPENDENT TUNNELING MAGNETORESISTANCE IN Fe-O/AlOx/Fe-O FILMS

    Institute of Scientific and Technical Information of China (English)

    L.Q. Pan; H. Qiu; F.P. Wang; P. Wu; Y. Tian; S. Luo

    2002-01-01

    Fe-O/AlOx/Fe-O tunnel junctions were prepared by reactive magnetron sputteringunder mixed working gas Ar+2%O2. The insulating AlOx layer of 1-2nm thicknesswas sputtered directly from Al2O3 target. Electrode layers were made of 80at.% ironand 20at.% oxygen. Bottom Fe-O electrode deposited on glass substrate annealedat 473K at the pressure of 3× 10-4Pa for an hour shows disparate crystalline grainstructure, lower electrical resistance and coercivity compared to the as-deposited topelectrode. Only crystalline structrure of α-Fe is observed in both electrodes. Largetunnel magnetoresistance in large Fe-O/AlOx/Fe-O junctions of 1cm2 is observed atroom temperature and the Ⅰ-Ⅴ characteristic curve of the junction shows that thebarrier of the junction is of high quality.

  6. PTA clad (Cr,Fe)7C3/γ-Fe in situ ceramal composite coating

    Institute of Scientific and Technical Information of China (English)

    Junbo Liu; Limei Wang; Jihua Huang

    2006-01-01

    A wear-resistant (Cr, Fe)7C3/γ-Fe in situ ceramal composite coating was fabricated on the substrate of 0.45wt%C carbon steel by a plasma-transferred arc cladding process using the Fe-Cr-C elemental powder blends. The microstructure, microhardness, and dry-sliding wear resistance of the coating were evaluated. The results indicate that the microstructure of the coating, which was composed of (Cr, Fe)7C3 primary phase uniformly distributed in the γ-Fe, and the (Cr, Fe)7C3 eutectic matrix was metallurgically bonded to the 0.45wt%C carbon steel substrate. From substrate to coating, the microstructure of the coating exhibited an evident epitaxial growth character. The coating, indehiscent and tack-free, had high hardness and appropriate gradient. It had excellent wear resistance under the dry sliding wear test condition.

  7. Reaction mechanism of methanol to formaldehyde over Fe- and FeO-modified graphene.

    Science.gov (United States)

    Thivasasith, Anawat; Sirijaraensre, Jakkapan; Khongpracha, Pipat; Warakulwit, Chompunuch; Jansang, Bavornpon; Limtrakul, Jumras

    2015-04-07

    We employed periodic DFT calculations (PBE-D2) to investigate the catalytic conversion of methanol over graphene embedded with Fe and FeO. Two possible pathways of dehydrogenation to formaldehyde and dehydration to dimethyl ether (DME) over these catalysts were examined. Both processes are initiated with the activation of methanol over the catalytic center through O-H cleavage. As a result, a methoxo-containing intermediate is formed. Subsequently, H-transfer from the methoxy to the adjacent ligand leads to the formation of formaldehyde. Conversely, the activation of the second methanol over the intermediate gives DME and H2O. Over Fe/graphene, the dehydration process is kinetically and thermodynamically preferable. Unlike Fe/graphene, FeO/graphene is predicted to be an efficient catalyst for the dehydrogenation process. Oxidative dehydrogenation over FeO/graphene takes place through two steps with free energy barriers of 5.7 and 10.2 kcal mol(-1).

  8. ESPERA, ESPERANZA, FE Y TURISMO

    Directory of Open Access Journals (Sweden)

    Anna María Fernández Poncela

    2013-06-01

    Full Text Available El texto revisa los conceptos y sentimientos relacionados con la espera y la esperanza. El estudio se centra en espacios de turismo religioso. Espacios donde el tiempo parece detenido y los devotos depositan su fe y los turistas visitan también. En concreto en Zapopan, municipio junto a la ciudad de Guadalajara, Jalisco, México. En una época donde el turismo busca lo auténtico, la experiencia y las emociones, el turismo religioso aumenta y algunos lugares son más populares que nunca.This text reviews the some concepts and feelings related to the wait and hope. The study focuses on spaces of religious tourism. Spaces where the time seems stopped and devotees deposited their faith and tourists also visit this spaces too. In particular in Zapopan, a municipality near the city of Guadalajara, Jalisco, Mexico. Today tourism looking for authentic, experience and emotions, religious tourism increases and some places are more popular than ever.

  9. Effect of Fe2P in LiFePO4/Fe2P composite on electrochemical properties synthesized by MA and control of heat condition

    Institute of Scientific and Technical Information of China (English)

    PARK Jong Suk; LEE Kyung Tae; LEE Kyung Sub

    2006-01-01

    In order to control the size and distribution of the high conductive Fe2P in LiFePO4/Fe2P composite, two different cooling rates (Fast: 15 ℃·min-1, Slow: 2 ℃·min-1) were employed after mechanical alloying.The discharge capacity of the fast cooled was 83 mAh·g-1 and the slow cooled 121 mAh·g-1.The particle size of the synthesized powder was examined by transmission electron microscopy and distribution of Fe2P was characterized using scanning electron microscopy (SEM).In addition, two-step heat treatment was carried out for better distribution of Fe2P.X-ray diffraction (XRD) and Rietveld refinement reveal that LiFePO4/Fe2P composite consists of 95.77% LiFePO4 and 4.33% of Fe2P.

  10. High Temperature Magnetic Properties of Indirect Exchange Spring FePt/M(Cu,C/Fe Trilayer Thin Films

    Directory of Open Access Journals (Sweden)

    Anabil Gayen

    2013-01-01

    Full Text Available We report the investigation of temperature dependent magnetic properties of FePt and FePt(30/M(Cu,C/Fe(5 trilayer thin films prepared by using magnetron sputtering technique at ambient temperature and postannealed at different temperatures. L10 ordering, hard magnetic properties, and thermal stability of FePt films are improved with increasing postannealing temperature. In FePt/M/Fe trilayer, the formation of interlayer exchange coupling between magnetic layers depends on interlayer materials and interface morphology. In FePt/C/Fe trilayer, when the C interlayer thickness was about 0.5 nm, a strong interlayer exchange coupling between hard and soft layers was achieved, and saturation magnetization was enhanced considerably after using interlayer exchange coupling with Fe. In addition, incoherent magnetization reversal process observed in FePt/Fe films changes into coherent switching process in FePt/C/Fe films giving rise to a single hysteresis loop. High temperature magnetic studies up to 573 K reveal that the effective reduction in the coercivity decreases largely from 34 Oe/K for FePt/Fe film to 13 Oe/K for FePt/C(0.5/Fe film demonstrating that the interlayer exchange coupling seems to be a promising approach to improve the stability of hard magnetic properties at high temperatures, which is suitable for high-performance magnets and thermally assisted magnetic recording media.

  11. Ex situ synthesis of magnetically exchange coupled SrFe12O19/Fe-Co composites

    Science.gov (United States)

    Xu, Xia; Hong, Yang-Ki; Park, Jihoon; Lee, Woncheol; Lane, Alan M.

    2016-05-01

    Magnetically exchange coupled SrFe12O19/Fe-Co composites with different mass percentage of Fe-Co were synthesized through an ex situ process. The morphology, magnetic properties, and crystallization of SrFe12O19/Fe-Co composites were investigated. Lower mass percentage of Fe-Co presented an even distribution of Fe-Co nanoparticles on the surface of SrFe12O19, and effective magnetic exchange coupling between Fe-Co and SrFe12O19. Higher mass percentage of Fe-Co leads to an agglomeration of Fe-Co nanoparticles on SrFe12O19 surface, and a weak magnetic exchange coupling between Fe-Co and SrFe12O19. This ex situ process proposed a new method to synthesize magnetically exchange coupled SrFe12O19/Fe-Co core/shell composites with precise control of the magnetic properties. This method can also be potentially used for other hard/soft magnetic composite synthesis.

  12. Ex situ synthesis of magnetically exchange coupled SrFe12O19/Fe-Co composites

    Directory of Open Access Journals (Sweden)

    Xia Xu

    2016-05-01

    Full Text Available Magnetically exchange coupled SrFe12O19/Fe-Co composites with different mass percentage of Fe-Co were synthesized through an ex situ process. The morphology, magnetic properties, and crystallization of SrFe12O19/Fe-Co composites were investigated. Lower mass percentage of Fe-Co presented an even distribution of Fe-Co nanoparticles on the surface of SrFe12O19, and effective magnetic exchange coupling between Fe-Co and SrFe12O19. Higher mass percentage of Fe-Co leads to an agglomeration of Fe-Co nanoparticles on SrFe12O19 surface, and a weak magnetic exchange coupling between Fe-Co and SrFe12O19. This ex situ process proposed a new method to synthesize magnetically exchange coupled SrFe12O19/Fe-Co core/shell composites with precise control of the magnetic properties. This method can also be potentially used for other hard/soft magnetic composite synthesis.

  13. Production of nearly monodisperse Fe3O4 and Fe@Fe3O4 nanoparticles in aqueous medium and their surface modification for biomedical applications

    Science.gov (United States)

    Tegafaw, Tirusew; Xu, Wenlong; Lee, Sang Hyup; Chae, Kwon Seok; Chang, Yongmin; Lee, Gang Ho

    2017-02-01

    Iron (Fe)-based nanoparticles are extremely valuable in biomedical applications owing to their low toxicity and high magnetization values at room temperature. In this study, we synthesized nearly monodisperse iron oxide (Fe3O4) and Fe@Fe3O4 (core: Fe, shell: Fe3O4) nanoparticles in aqueous medium under argon flow and then, coated them with various biocompatible ligands and silica. In this study, eight types of surface-modified nanoparticles were investigated, namely, Fe3O4@PAA (PAA = polyacrylic acid; Mw of PAA = 5100 amu and 15,000 amu), Fe3O4@PAA-FA (FA = folic acid; Mw of PAA = 5100 amu and 15,000 amu), Fe3O4@PEI-fluorescein (PEI = polyethylenimine; Mw of PEI = 1300 amu), Fe@Fe3O4@PEI (Mw of PEI = 10,000 amu), Fe3O4@SiO2 and Fe@Fe3O4@SiO2 nanoparticles. We characterized the prepared surface-modified nanoparticles using high-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), Fourier transform infrared (FT-IR) absorption spectroscopy, a superconducting quantum interference device (SQUID), X-ray photoelectron spectroscopy (XPS), photoluminescence (PL) spectroscopy and confocal microscopy. Finally, we measured the cytotoxicity of the samples. The results indicate that the surface-modified nanoparticles are biocompatible and are potential candidates for various biomedical applications.

  14. Abiotic oxidation of Fe(II) by reactive nitrogen species in cultures of the nitrate-reducing Fe(II) oxidizer Acidovorax sp. BoFeN1 - questioning the existence of enzymatic Fe(II) oxidation.

    Science.gov (United States)

    Klueglein, N; Kappler, A

    2013-03-01

    Nitrate-reducing, Fe(II)-oxidizing bacteria were suggested to couple with enzymatic Fe(II) oxidation to nitrate reduction. Denitrification proceeds via intermediates (NO2 -, NO) that can oxidize Fe(II) abiotically at neutral and particularly at acidic pH. Here, we present a revised Fe(II) quantification protocol preventing artifacts during acidic Fe extraction and evaluate the contribution of abiotic vs. enzymatic Fe(II) oxidation in cultures of the nitrate-reducing, Fe(II) oxidizer Acidovorax sp. BoFeN1. Sulfamic acid used instead of HCl reacts with nitrite and prevents abiotic Fe(II) oxidation during Fe extraction. Abiotic experiments without sulfamic acid showed that acidification of oxic Fe(II) nitrite samples leads to 5.6-fold more Fe(II) oxidation than in anoxic samples because the formed NO becomes rapidly reoxidized by O(2) , therefore leading to abiotic oxidation and underestimation of Fe(II). With our revised protocol using sulfamic acid, we quantified oxidation of approximately 7 mm of Fe(II) by BoFeN1 within 4 days. Without addition of sulfamic acid, the same oxidation was detected within only 2 days. Additionally, abiotic incubation of Fe(II) with nitrite in the presence of goethite as surface catalyst led to similar abiotic Fe(II) oxidation rates as observed in growing BoFeN1 cultures. BoFeN1 growth was observed on acetate with N(2) O as electron acceptor. When adding Fe(II), no Fe(II) oxidation was observed, suggesting that the absence of reactive N intermediates (NO2 -, NO) precludes Fe(II) oxidation. The addition of ferrihydrite [Fe(OH)(3) ] to acetate/nitrate BoFeN1 cultures led to growth stimulation equivalent to previously described effects on growth by adding Fe(II). This suggests that elevated iron concentrations might provide a nutritional effect rather than energy-yielding Fe(II) oxidation. Our findings therefore suggest that although enzymatic Fe(II) oxidation by denitrifiers cannot be fully ruled out, its contribution to the observed Fe

  15. Physical properties of the superconducting spin-valve Fe/Cu/Fe/In heterostructure

    Science.gov (United States)

    Leksin, P. V.; Garif'yanov, N. N.; Garifullin, I. A.; Schumann, J.; Kataev, V.; Schmidt, O. G.; Büchner, B.

    2012-01-01

    We report on structural, magnetic, and superconducting properties of the spin-valve multilayer system CoOx/Fe1/Cu/Fe2/In. For most of the thicknesses of the second iron layer dFe2 up to 2 nm, we have observed a full spin-valve effect for the superconducting current, i.e., a complete transition from the normal to the superconducting state by changing the mutual orientation of the magnetizations of the Fe1 and Fe2 layers. For dFe2<1 nm, the superconducting transition temperature TcP for the parallel orientation of magnetizations of the Fe1 and Fe2 layers is smaller than that for the antiparallel orientation TcAP, which corresponds to the direct spin-valve effect. For dFe2⩾1 nm, we have found the inverse spin-valve effect with ΔTc=TcAP-TcP<0. Further, in samples with a fixed thickness of the In layer, we have observed an oscillating dependence of its superconducting transition temperature Tc on dFe2. The analysis of the Tc(dFe2) dependence using the theory of the superconducting-ferromagnetic proximity effect has enabled determination of all microscopic parameters of the studied system. With these parameters, a satisfactory description of the sign-changing oscillating behavior of the spin-valve effect ΔTc(dFe2) has been obtained using a recent theory by Fominov [Ya. V. Fominov , Pis'ma Zh. Eksp. Teor. Fiz. 91, 329 (2010) [JETP Lett.JTPLA20021-364010.1134/S002136401006010X 91, 308 (2010)

  16. Efficient NO adsorption and release at Fe3+ sites in Fe/TiO2 nanoparticles

    NARCIS (Netherlands)

    Wu, Qingping; Mul, Guido; Krol, van de Roel

    2011-01-01

    The adsorption and release of nitrogen oxide (NO) molecules at the surface of Fe-doped TiO2 nanoparticles, made by a template-free sol–gel process, has been studied. Fe3+ ions are found to be highly effective NO adsorption sites in Fe/TiO2. Up to [similar]89 μmol g−1 of the adsorbed NO can be releas

  17. Summary of Fe opacity measurement platform

    Energy Technology Data Exchange (ETDEWEB)

    Nagayama, Taisuke

    2016-05-01

    This powerpoint presentation goes over the Fe opacity measurement platform, including how the experiment works, what can be gathered from the measurements, what can be gathered from the simulations, and the limitations of the experiment.

  18. Nanophase Fe0 in lunar soils

    Indian Academy of Sciences (India)

    Abhijit Basu

    2005-06-01

    Back scattered electron and transmission electron imaging of lunar soil grains reveal an abundance of submicrometer-sized pure Fe00 globules that occur in the rinds of many soil grains and in the submillimeter sized vesicular glass-cemented grains called agglutinates. Grain rinds are amorphous silicates that were deposited on grains exposed at the lunar surface from transient vapors produced by hypervelocity micrometeorite impacts. Fe0 may have dissociated from Fe-compounds in a high temperature (< 3000°C) vapor phase and then condensed as globules on grain surfaces. The agglutinitic glass is a quenched product of silicate melts, also produced by micrometeorite impacts on lunar soils. Reduction by solar wind hydrogen in agglutinitic melts may have produced immiscible droplets that solidified as globules. The exact mechanism of formation of such Fe0 globules in lunar soils remains unresolved.

  19. Biosynthesis of Nitrogenase FeMoco.

    Science.gov (United States)

    Hu, Yilin; Ribbe, Markus W

    2011-05-01

    Biosynthesis of nitrogenase FeMoco is a highly complex process that requires, minimally, the participation of nifS, nifU, nifB, nifE, nifN, nifV, nifH, nifD and nifK gene products. Previous genetic analyses have identified the essential factors for the assembly of FeMoco; however, the exact functions of these factors and the precise sequence of events during the assembly process had remained unclear until recently, when a number of the biosynthetic intermediates of FeMoco were identified and characterized by combined biochemical, spectroscopic and structural analyses. This review gives a brief account of the recent progress toward understanding the assembly process of FeMoco, which has identified some important missing pieces of this biosynthetic puzzle.

  20. FeCl3 catalyzed diarylmethanes formations

    Institute of Scientific and Technical Information of China (English)

    Zhong Xian Li; Zheng Duan; Yang Jie Wu

    2009-01-01

    Under mild condition,using FeCl3 as catalyst,a series of functionalized diarylmethanes were prepared efficiently from the reactions of arenes with paraformaldehyde.This catalytic system is not sensitive to air and moisture.

  1. Structures and energies of Cu clusters on Fe and Fe3C surfaces from density functional theory computation.

    Science.gov (United States)

    Tian, Xinxin; Wang, Tao; Yang, Yong; Li, Yong-Wang; Wang, Jianguo; Jiao, Haijun

    2014-12-28

    Spin-polarized density functional theory computations have been carried out to study the stable adsorption configurations of Cun (n = 1-7, 13) on Fe and Fe3C surfaces for understanding the initial stages of copper promotion in catalysis. At low coverage, two-dimensional aggregation is more preferred over dispersion and three-dimensional aggregation on the Fe(110) and Fe(100) surfaces as well as the metallic Fe3C(010) surfaces, while dispersion is more favorable over aggregation on the Fe(111) surface. On the Fe3C(001) and Fe3C(100) surfaces with exposed iron and carbon atoms, the adsorbed Cu atoms prefer dispersion at low coverage, while aggregation along the iron regions at high coverage. On the iron surfaces, the adsorption energies of Cun (n = 2-7) are highest on Fe(111), medium on Fe(100) and lowest on Fe(110). On the Fe3C surfaces, the adsorption energies of Cun (n = 1-3) are highest on Fe3C(100), medium on Fe3C(010) and lowest on Fe3C(001), while, for n = 4-7 and 13, Fe3C(010) has stronger adsorption than Fe3C(100). On the basis of their differences in electronegativity, the adsorbed Cu atoms can oxidize the metallic Fe(110), Fe(100) and Fe3C(010) surfaces and become negatively charged. On the Fe3C(001) and Fe3C(100) surfaces with exposed iron and carbon atoms, the adsorbed Cu atoms interacting with surface carbon atoms are oxidized and positively charged. Unlike the most stable Fe(110) and Fe3C(001) surfaces, where the Fe(110) surface has stronger Cu affinity than the Fe3C(001) surface, which is in agreement with the experimental finding, the less and least stable Fe3C(010) and Fe3C(100) surfaces have stronger Cu affinities than the Fe(110) and Fe(100) surfaces. Since less stable facets are not preferably formed thermodynamically, it is crucial to prepare such surfaces to explore Cu adsorption and promotion, and this provides challenges to surface sciences.

  2. Microwave Magnetic Permeability of Fe304 Nanoparticles

    Institute of Scientific and Technical Information of China (English)

    ZHENG Hong; YANG Yong; WEN Fu-Sheng; YI Hai-Bo; ZHOU Dong; LI Fa-Shen

    2009-01-01

    Well-dispersed Fe304 nanoparticles are synthesized via an oxidization method with NANO2 as oxidant. The microwave magnetic properties of the composites are studied with different volume fractions of Fe3O4 nanoparti-cles. It is found that a lower volume fraction corresponds to a higher magnetic resonance frequency. This could be ascribed to the enhancement of exchange interaction with a weakened dipolar interaction when the volume fraction decreases.

  3. FeII/MgII, [Fe/Mg] Ratios and High-z Quasars

    CERN Document Server

    Korista, K; Corbin, M R; Freudling, W; Korista, Kirk; Kodituwakku, Nalaka; Corbin, Michael; Freudling, Wolfram

    2003-01-01

    It has been suggested in the literature that the (Fe/alpha) abundance ratio may be used as a chronometer, due to a delay in this ratio reaching its solar value as predicted by galactic chemical evolution models. Using grids of photoionization models along a sequence of the (Fe/Mg) abundance ratio vs.\\ metallicity with time in a giant elliptical starburst scenario, we investigate the relationship between the (Fe/Mg) abundance ratio and the FeII/MgII emission line flux ratio under the assumption that these lines originate in photoionized clouds within the broad emission line regions of quasars.

  4. Studies on the valence electronic structure of Fe and Ni in FeNi1- alloys

    Indian Academy of Sciences (India)

    D K Basa; S Raj; H C Padhi; M Polasik; F Pawlowski

    2002-05-01

    -to- X-ray intensity ratios of Fe and Ni in pure metals and in FeNi1- alloys ( = 0.20, 0.50, 0.58) exhibiting similar crystalline structure have been measured following excitation by 59.54 keV -rays from a 241Am point source, to understand as to why the properties of permalloy Fe0.2Ni0.8 is distinct from other alloy compositions. It is observed that the valence electronic structure of Fe0.2Ni0.8 alloy is totally different from other alloys which may be attributed to its special magnetic properties.

  5. Magnetic structure of molecular magnet Fe[Fe(CN)6]·4H2O

    Indian Academy of Sciences (India)

    Amit Kumar; S M Yusuf

    2004-08-01

    We have studied the magnetic structure of Fe[Fe(CN)6]·4H2O, prepared by precipitation method, using neutron diffraction technique. Temperature dependent DC magnetization study down to 4.2 K shows that the compound undergoes from a high temperature disordered (paramagnetic) to an ordered magnetic phase transition at 22.6 K. Rietveld analysis of neutron diffraction pattern at 60 K (in its paramagnetic phase) revealed a face centred cubic structure with space group Fm3m. The structure contains three-dimensional network of straight Fe3+ –C≡N–Fe3+ chains along the edges of the unit cell cube. Fe3+ ions occupy 4 (0, 0, 0) and 4 (1/2, 1/2, 1/2) positions. Fe3+ (0, 0, 0) is surrounded octahedrally by six nitrogen atoms and Fe3+ (1/2, 1/2, 1/2) is surrounded octahedrally by six carbon atoms. Magnetic Rietveld refinement of neutron diffraction data at 11 K shows a ferromagnetic coupling between the two inequivalent Fe3+ sites. Refinement yielded an ordered moment of 4.4(6) and 0.8(6) B per Fe ion located at (0, 0, 0) and (1/2, 1/2, 1/2), respectively. Ordered moments are found to align along the face diagonal. The observed net moment from low temperature neutron diffraction study is consistent with DC magnetization results.

  6. Thermodynamic Assessments of the Fe-Si-Cr and Fe-Si-Mg Systems

    Science.gov (United States)

    Cui, Senlin; Jung, In-Ho

    2017-09-01

    Thermodynamic assessments for the Fe-Si-Cr and Fe-Si-Mg ternary systems were conducted based on the critically evaluated and optimized thermodynamic and phase diagram data in the literature. The Gibbs energy of the liquid phase was described using the modified quasi-chemical model in pair approximation. The obtained thermodynamic descriptions of the Fe-Si-Cr and Fe-Si-Mg systems can be used to calculate any sections of the phase diagrams and thermodynamic properties of these two systems with high accuracy from room temperature to above the melting temperature.

  7. Investigation of correlation effects in FeSe and FeTe by LDA + U method

    Energy Technology Data Exchange (ETDEWEB)

    Lohani, H.; Mishra, P.; Sekhar, B.R., E-mail: sekhar@iopb.res.in

    2015-05-15

    Highlights: • Comparative study of the influence of U and J in FeSe and FeTe. • We found correlation effects are strong in Fe-3d orbitals in FeSe and FeTe. • Correlation effects are orbital selective in nature. - Abstract: We present a comparative study of the influence of Coulomb interaction and Hund’s coupling on the electronic structure of FeSe and FeTe. Our calculations are based on density functional theory (DFT) with local density approximation (LDA + U) framework employed in TB-LMTO ASA code. We found the correlation effects are orbital selective due to the strength of interorbital hybridization among the different Fe-3d orbitals mediated via the chalcogen (Se/Te-p) orbitals and are different in both the compounds. The Coulomb interaction is screened significantly by Te-p bands in FeTe. Similarly the orbital selection is different in both the compounds because of the difference in the chalcogen height.

  8. Mechanical properties and electronic structures of Fe-Al intermetallic

    Energy Technology Data Exchange (ETDEWEB)

    Liu, YaHui; Chong, XiaoYu; Jiang, YeHua, E-mail: jiangyehua@kmust.edu.cn; Zhou, Rong; Feng, Jing, E-mail: jingfeng@kmust.edu.cn

    2017-02-01

    Using the first-principles calculations, the elastic properties, anisotropy properties, electronic structures, Debye temperature and stability of Fe-Al (Fe{sub 3}Al, FeAl, FeAl{sub 2}, Fe{sub 2}Al{sub 5} and FeAl{sub 3}) binary compounds were calculated. The formation enthalpy and cohesive energy of these Fe-Al compounds are negative, and show they are thermodynamically stable structures. Fe{sub 2}Al{sub 5} has the lowest formation enthalpy, which shows the Fe{sub 2}Al{sub 5} is the most stable of Fe-Al binary compounds. These Fe-Al compounds display disparate anisotropy due to the calculated different shape of the 3D curved surface of the Young’s modulus and anisotropic index. Fe{sub 3}Al has the biggest bulk modulus with the value 233.2 GPa. FeAl has the biggest Yong’s modulus and shear modulus with the value 296.2 GPa and 119.8 GPa, respectively. The partial density of states, total density of states and electron density distribution maps of the binary Fe-Al binary compounds are analyzed. The bonding characteristics of these Fe-Al binary compounds are mainly combination by covalent bond and metallic bonds. Meanwhile, also exist anti-bond effect. Moreover, the Debye temperatures and sound velocity of these Fe-Al compounds are explored.

  9. Magnetism in bcc and fcc Fe with carbon and manganese

    Energy Technology Data Exchange (ETDEWEB)

    Medvedeva, N I [Institute of Solid State Chemistry, Yekaterinburg 620990 (Russian Federation); Van Aken, D [Department of Materials Science and Engineering, Missouri University of Science and Technology, Rolla, MO 65409 (United States); Medvedeva, J E [Department of Physics, Missouri University of Science and Technology, Rolla, MO 65409 (United States)

    2010-08-11

    Density functional theory calculations were performed to study the structure and magnetic properties of bcc ({alpha}) and fcc ({gamma}) Fe with 3 at.% carbon and manganese impurities. We find that all bcc-based Fe, Fe-C and Fe-Mn-C phases exhibit a ferromagnetic (FM) ground state, while the antiferromagnetic double-layer (AFMD) state is lowest in energy within the collinear spin approach in fcc Fe, Fe-C and Fe-Mn-C phases. However, the carbon and manganese impurities affect the local magnetic interactions significantly. The states with opposite manganese magnetic moments are quasi-degenerate in bcc Fe-Mn alloy, whereas octa-site carbon stabilizes ferromagnetic coupling of the nearest manganese atom with the Fe host. We demonstrate that the antiferromagnetic (AFM) fcc Fe-C and Fe-Mn-C alloys are intrinsically inhomogeneous magnetic systems. Carbon frustrates the local magnetic order by reorientation of magnetic moments of the nearest Mn and Fe atoms, and favors their ferromagnetic coupling. The competition between ferromagnetic and antiferromagnetic Fe-Fe and Fe-Mn interactions and the local magnetovolume instability near carbon may give rise to the spin-glass-like regions observed in austenitic Fe-Mn-C alloys.

  10. Magnetism in bcc and fcc Fe with carbon and manganese.

    Science.gov (United States)

    Medvedeva, N I; Van Aken, D; Medvedeva, J E

    2010-08-11

    Density functional theory calculations were performed to study the structure and magnetic properties of bcc (α) and fcc (γ) Fe with 3 at.% carbon and manganese impurities. We find that all bcc-based Fe, Fe-C and Fe-Mn-C phases exhibit a ferromagnetic (FM) ground state, while the antiferromagnetic double-layer (AFMD) state is lowest in energy within the collinear spin approach in fcc Fe, Fe-C and Fe-Mn-C phases. However, the carbon and manganese impurities affect the local magnetic interactions significantly. The states with opposite manganese magnetic moments are quasi-degenerate in bcc Fe-Mn alloy, whereas octa-site carbon stabilizes ferromagnetic coupling of the nearest manganese atom with the Fe host. We demonstrate that the antiferromagnetic (AFM) fcc Fe-C and Fe-Mn-C alloys are intrinsically inhomogeneous magnetic systems. Carbon frustrates the local magnetic order by reorientation of magnetic moments of the nearest Mn and Fe atoms, and favors their ferromagnetic coupling. The competition between ferromagnetic and antiferromagnetic Fe-Fe and Fe-Mn interactions and the local magnetovolume instability near carbon may give rise to the spin-glass-like regions observed in austenitic Fe-Mn-C alloys.

  11. Mechanical properties and electronic structures of Fe-Al intermetallic

    Science.gov (United States)

    Liu, YaHui; Chong, XiaoYu; Jiang, YeHua; Zhou, Rong; Feng, Jing

    2017-02-01

    Using the first-principles calculations, the elastic properties, anisotropy properties, electronic structures, Debye temperature and stability of Fe-Al (Fe3Al, FeAl, FeAl2, Fe2Al5 and FeAl3) binary compounds were calculated. The formation enthalpy and cohesive energy of these Fe-Al compounds are negative, and show they are thermodynamically stable structures. Fe2Al5 has the lowest formation enthalpy, which shows the Fe2Al5 is the most stable of Fe-Al binary compounds. These Fe-Al compounds display disparate anisotropy due to the calculated different shape of the 3D curved surface of the Young's modulus and anisotropic index. Fe3Al has the biggest bulk modulus with the value 233.2 GPa. FeAl has the biggest Yong's modulus and shear modulus with the value 296.2 GPa and 119.8 GPa, respectively. The partial density of states, total density of states and electron density distribution maps of the binary Fe-Al binary compounds are analyzed. The bonding characteristics of these Fe-Al binary compounds are mainly combination by covalent bond and metallic bonds. Meanwhile, also exist anti-bond effect. Moreover, the Debye temperatures and sound velocity of these Fe-Al compounds are explored.

  12. In situ study on the formation of FeTe

    DEFF Research Database (Denmark)

    Grivel, Jean-Claude; Wulff, Anders Christian; Yue, Zhao;

    2011-01-01

    The formation of the FeTe compound from a mixture of Fe and Te powders was studied in situ by means of high-energy synchrotron X-ray diffraction. FeTe does not form directly from the starting elements; instead, FeTe2 forms as an intermediate product. During a 2 °C/min heating ramp, Te first reacts...

  13. Electron-ion Recombination of Fe X forming Fe IX and of Fe XI forming Fe X: Laboratory Measurements and Theoretical Calculations

    CERN Document Server

    Lestinsky, M; Bernhardt, D; Grieser, M; Hoffmann, J; Lukić, D; Müller, A; Orlov, D A; Repnow, R; Savin, D W; Schmidt, E W; Schnell, M; Schippers, S; Wolf, A; Yu, D

    2009-01-01

    We have measured electron-ion recombination for Fe$^{9+}$ forming Fe$^{8+}$ and for Fe$^{10+}$ forming Fe$^{9+}$ using merged beams at the TSR heavy-ion storage-ring in Heidelberg. The measured merged beams recombination rate coefficients (MBRRC) for relative energies from 0 to 75 eV are presented, covering all dielectronic recombination (DR) resonances associated with 3s->3p and 3p->3d core transitions in the spectroscopic species Fe X and Fe XI, respectively. We compare our experimental results to multi-configuration Breit-Pauli (MCBP) calculations and find significant differences. From the measured MBRRC we have extracted the DR contributions and transform them into plasma recombination rate coefficients (PRRC) for astrophysical plasmas with temperatures from 10^2 to 10^7 K. This spans across the regimes where each ion forms in photoionized or in collisionally ionized plasmas. For both temperature regimes the experimental uncertainties are 25% at a 90% confidence level. The formerly recommended DR data sev...

  14. Growth and magnetic properties of ultrathin epitaxial FeO films and Fe/FeO bilayers on MgO(001)

    Energy Technology Data Exchange (ETDEWEB)

    Kozioł-Rachwał, A., E-mail: akoziol@agh.edu.pl [Faculty of Physics and Applied Computer Science, AGH University of Science and Technology, al. Mickiewicza 30, 30-059 Kraków (Poland); National Institute of Advanced Industrial Science and Technology, Spintronics Research Center, Tsukuba, Ibaraki 305-8568 (Japan); Ślęzak, T. [Faculty of Physics and Applied Computer Science, AGH University of Science and Technology, al. Mickiewicza 30, 30-059 Kraków (Poland); Nozaki, T.; Yuasa, S. [National Institute of Advanced Industrial Science and Technology, Spintronics Research Center, Tsukuba, Ibaraki 305-8568 (Japan); Korecki, J. [Faculty of Physics and Applied Computer Science, AGH University of Science and Technology, al. Mickiewicza 30, 30-059 Kraków (Poland); Jerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, ul. Niezapominajek 8, 30-239 Kraków (Poland)

    2016-01-25

    Ultrathin FeO(001) films were grown via molecular beam epitaxy on MgO(001) using reactive deposition of Fe. The growth conditions were adjusted toward stabilization of the wüstite phase, the existence of which was confirmed by means of conversion electron Mössbauer spectroscopy. It was shown how the metallic Fe overlayer modified the chemical state and the magnetic properties of the FeO oxide. Finally, we observed the exchange bias for an epitaxial Fe/FeO bilayer grown on MgO(001)

  15. Physical conditions in CaFe interstellar clouds

    CERN Document Server

    Gnacinski, P

    2007-01-01

    Interstellar clouds that exhibit strong Ca I and Fe I lines were called CaFe clouds. The ionisation equilibrium equations were used to model the column densities of Ca II, Ca I, K I, Na I, Fe I and Ti II in CaFe clouds. The chemical composition of CaFe clouds is that of the Solar System and no depletion of elements onto dust grains is seen. The CaFe clouds have high electron densities n=1 cm^-3 that leads to high column densities of neutral Ca and Fe.

  16. Research progress and influence of Fe2P impurity on performance of LiFePO4%Fe2P杂质对LiFePO4性能影响的研究进展

    Institute of Scientific and Technical Information of China (English)

    曾晖; 王康平

    2016-01-01

    综述了在合成LiFePO4的过程中,Fe2P杂质的形成对LiFePO4相关性能的影响.对LiFePO4的煅烧气氛与Fe2P的形成机理之间的关联性进行了总结和探讨,并对含有Fe2P杂质的LiFePO4材料的相关性能进行了研究.

  17. Physical conditions in CaFe interstellar clouds

    OpenAIRE

    Gnacinski, P.; Krogulec, M.

    2007-01-01

    Interstellar clouds that exhibit strong Ca I and Fe I lines were called CaFe clouds. The ionisation equilibrium equations were used to model the column densities of Ca II, Ca I, K I, Na I, Fe I and Ti II in CaFe clouds. The chemical composition of CaFe clouds is that of the Solar System and no depletion of elements onto dust grains is seen. The CaFe clouds have high electron densities n=1 cm^-3 that leads to high column densities of neutral Ca and Fe.

  18. Dopant concentration dependent growth of Fe:ZnO nanostructures

    Science.gov (United States)

    Sahai, Anshuman; Goswami, Navendu

    2016-05-01

    Systematic investigations of structural properties of 1-10% Fe doped ZnO nanostructure (Fe:ZnO NS) prepared via chemical precipitation method have been reported. Structural properties were probed thoroughly employing scanning electron microscope (SEM) and transmission electron microscope (TEM), energy dispersive X-ray (EDAX) analysis and X-ray diffraction (XRD). Morphological transformation of nanostructures (NS) with Fe incorporation is evident in SEM/TEM images. Nanoparticles (NP) obtained with 1% Fe, evolve to nanorods (NR) for 3% Fe; NR transform to nanocones (NC) (for 5% and 7% Fe) and finally NC transform to nanoflakes (NF) at 10% Fe. Morover, primary phase of Zn1-xFexO along with secondary phases of ZnFe2O4 and Fe2O3 were also revealed through XRD measurements. Based on collective XRD, SEM, TEM, and EDAX interpretations, a model for morphological evolution of NS was proposed and the pivotal role of Fe dopant was deciphered.

  19. First Principles Study on FeAs Single Layers

    Institute of Scientific and Technical Information of China (English)

    Jun Dai; Zhenyu Li; Jin-long Yang

    2009-01-01

    FeAs- single layer is tested as a simple model for LaFeAsO and BaFe2As2 based on firstprinciples calculations using generalized gradient approximation (GGA) and GGA+U. The calculated single-layer geometric and electronic structures are inconsistent with that of bulk materials. The bulk collinear antiferromagnetic ground state failed to be obtained in the FeAs- single layer. The monotonous behavior of the Fe-As distance in z direction upon electron or hole doping is also in contrast with bulk materials. The results indicate that,in LaFeAsO and BaFe2As2, interactions between FeAs layer and other layers beyond simple charge doping are important, and a single FeAs layer may not represent a good model for Fe based superconducting materials.

  20. Environmental embrittlement of intermetallic compounds in Fe-Al alloys

    Institute of Scientific and Technical Information of China (English)

    张建民; 张瑞林; S.H.YU; 余瑞璜

    1996-01-01

    First,it is proposed that hydrogen atoms occupy the interstitial sites in Fe3Al and FeAl.Then the environmental embrittlement of intermetallic compounds in Fe-Al alloys is studied in the light of calculated valence electron structures and bond energy of Fe3Al and FeAl containing hydrogen atoms.From the analyses it is found that the states of metal atoms will change,in which more lattice electrons will become covalent electrons to bond with hydrogen atoms when the atomic hydrogen diffuses into the intermetallic compounds in Fe-Al alloys,which will result in the decrease of local metallicity in Fe3Al and FeAl.Meanwhile,it is found that the crystal will easily cleave since solute hydrogen bonds with metal atoms and severely anisotropic bonds form.As a conclusion,these factors result in the environmental embrittlement of Fe3Al and FeAl.

  1. The Atlas3D project - XXVI. HI discs in real and simulated fast and slow rotators

    CERN Document Server

    Serra, Paolo; Krajnovic, Davor; Naab, Thorsten; Oosterloo, Tom; Morganti, Raffaella; Cappellari, Michele; Emsellem, Eric; Young, Lisa M; Blitz, Leo; Davis, Timothy A; Duc, Pierre-Alain; Hirschmann, Michaela; Weijmans, Anne-Marie; Alatalo, Katherine; Bayet, Estelle; Bois, Maxime; Bournaud, Frederic; Bureau, Martin; Davies, Roger L; de Zeeuw, P T; Khochfar, Sadegh; Kuntschner, Harald; Lablanche, Pierre-Yves; McDermid, Richard M; Sarzi, Marc; Scott, Nicholas

    2014-01-01

    One quarter of all nearby early-type galaxies (ETGs) outside Virgo host a disc/ring of HI with size from a few to tens of kpc and mass up to ~1e+9 solar masses. Here we investigate whether this HI is related to the presence of a stellar disc within the host making use of the classification of ETGs in fast and slow rotators (FR/SR). We find a large diversity of HI masses and morphologies within both families. Surprisingly, SRs are detected as often, host as much HI and have a similar rate of HI discs/rings as FRs. Accretion of HI is therefore not always linked to the growth of an inner stellar disc. The weak relation between HI and stellar disc is confirmed by their frequent kinematical misalignment in FRs, including cases of polar and counterrotating gas. In SRs the HI is usually polar. This complex picture highlights a diversity of ETG formation histories which may be lost in the relative simplicity of their inner structure and emerges when studying their outer regions. We find that LCDM hydrodynamical simul...

  2. XXVI Annual Conference of the European Academy of Management and Business Economics (AEDEM)

    CERN Document Server

    Gil-Lafuente, Jaime; Merigó-Lindahl, José; Soft Computing in Management and Business Economics

    2012-01-01

    This book is a collection of selected papers presented at the Annual Meeting of the European Academy of Management and Business Economics (AEDEM), held at the Faculty of Economics and Business of the University of Barcelona, 05 – 07 June, 2012. This edition of the conference has been presented with the slogan “Creating new opportunities in an uncertain environment”. There are different ways for assessing uncertainty in management but this book mainly focused on soft computing theories and their role in assessing uncertainty in a complex world. The present book gives a comprehensive overview of general management topics and discusses some of the most recent developments in all the areas of business and management including management, marketing, business statistics, innovation and technology, finance, sports and tourism. This book might be of great interest for anyone working in the area of management and business economics and might be especially useful for scientists and graduate students doing researc...

  3. Planck intermediate results. XXVI. Optical identification and redshifts of Planck clusters with the RTT150 telescope

    CERN Document Server

    Ade, P A R; Arnaud, M; Ashdown, M; Aumont, J; Baccigalupi, C; Banday, A J; Barreiro, R B; Barrena, R; Bartolo, N; Battaner, E; Benabed, K; Benoit-Lévy, A; Bernard, J -P; Bersanelli, M; Bielewicz, P; Bikmaev, I; Böhringer, H; Bonaldi, A; Bonavera, L; Bond, J R; Borrill, J; Bouchet, F R; Burenin, R; Burigana, C; Butler, R C; Calabrese, E; Carvalho, P; Catalano, A; Chamballu, A; Chiang, H C; Chon, G; Christensen, P R; Churazov, E; Clements, D L; Colombo, L P L; Comis, B; Couchot, F; Curto, A; Cuttaia, F; Dahle, H; Danese, L; Davies, R D; Davis, R J; de Bernardis, P; de Rosa, A; de Zotti, G; Delabrouille, J; Diego, J M; Dole, H; Doré, O; Douspis, M; Ducout, A; Dupac, X; Efstathiou, G; Elsner, F; Enßlin, T A; Eriksen, H K; Finelli, F; Flores-Cacho, I; Forni, O; Frailis, M; Franceschi, E; Frejsel, A; Fromenteau, S; Galeotta, S; Ganga, K; Génova-Santos, R T; Giard, M; Gilfanov, M; Giraud-Héraud, Y; Gjerløw, E; González-Nuevo, J; Górski, K M; Gruppuso, A; Hansen, F K; Hanson, D; Harrison, D L; Hempel, A; Henrot-Versillé, S; Hernández-Monteagudo, C; Herranz, D; Hildebrandt, S R; Hivon, E; Holmes, W A; Hornstrup, A; Hovest, W; Huffenberger, K M; Hurier, G; Jaffe, T R; Jones, W C; Juvela, M; Keihanen, E; Keskitalo, R; Khamitov, I; Kisner, T S; Kneissl, R; Knoche, J; Kunz, M; Kurki-Suonio, H; Lagache, G; Lasenby, A; Lattanzi, M; Lawrence, C R; Leonardi, R; Levrier, F; Liguori, M; Lilje, P B; Linden-Vørnle, M; López-Caniego, M; Lubin, P M; Mac\\'\\ias-Pérez, J F; Maino, D; Mandolesi, N; Maris, M; Martin, P G; Mart\\'\\inez-González, E; Masi, S; Matarrese, S; Mazzotta, P; Melin, J -B; Mendes, L; Mennella, A; Migliaccio, M; Miville-Deschenes, M -A; Moneti, A; Montier, L; Morgante, G; Mortlock, D; Munshi, D; Murphy, J A; Naselsky, P; Nati, F; Natoli, P; Nørgaard-Nielsen, H U; Novikov, D; Novikov, I; Oxborrow, C A; Pagano, L; Pajot, F; Paoletti, D; Pasian, F; Perdereau, O; Perotto, L; Perrotta, F; Pettorino, V; Piacentini, F; Piat, M; Pietrobon, D; Plaszczynski, S; Pointecouteau, E; Polenta, G; Popa, L; Pratt, G W; Prunet, S; Puget, J -L; Rachen, J P; Reinecke, M; Remazeilles, M; Renault, C; Ricciardi, S; Ristorcelli, I; Rocha, G; Roman, M; Rosset, C; Rossetti, M; Roudier, G; Rubiño-Mart\\'\\in, J A; Rusholme, B; Sandri, M; Scott, D; Spencer, L D; Stolyarov, V; Sudiwala, R; Sunyaev, R; Sutton, D; Suur-Uski, A -S; Sygnet, J -F; Tauber, J A; Terenzi, L; Toffolatti, L; Tomasi, M; Tristram, M; Tucci, M; Valenziano, L; Valiviita, J; Van Tent, B; Vibert, L; Vielva, P; Villa, F; Wade, L A; Wandelt, B D; Wehus, I K; Yvon, D; Zacchei, A; Zonca, A

    2014-01-01

    We present the results of approximately three years of observations of Planck Sunyaev-Zeldovich (SZ) sources with the Russian-Turkish 1.5-m telescope (RTT150), as a part of the optical follow-up programme undertaken by the Planck collaboration. During this time period approximately 20% of all dark and grey clear time available at the telescope was devoted to observations of Planck objects. Some observations of distant clusters were also done at the 6-m Bolshoy Telescope Azimutal'ny (BTA) of the Special Astrophysical Observatory of the Russian Academy of Sciences. In total, deep, direct images of more than one hundred fields were obtained in multiple filters. We identified 47 previously unknown galaxy clusters, 41 of which are included in the Planck catalogue of SZ sources. The redshifts of 65 Planck clusters were measured spectroscopically and 14 more were measured photometrically. We discuss the details of cluster optical identifications and redshift measurements. We also present new spectroscopic redhifts f...

  4. XXVI Annual Conference of the European Academy of Management and Business Economics (AEDEM)

    CERN Document Server

    Gil-Lafuente, Jaime; Merigó-Lindahl, José; Soft Computing in Management and Business Economics

    2012-01-01

    This book is a collection of selected papers presented at the Annual Meeting of the European Academy of Management and Business Economics (AEDEM), held at the Faculty of Economics and Business of the University of Barcelona, 05 – 07 June, 2012. This edition of the conference has been presented with the slogan “Creating new opportunities in an uncertain environment”. There are different ways for assessing uncertainty in management but this book mainly focused on soft computing theories and their role in assessing uncertainty in a complex world. The present book gives a comprehensive overview of general management topics and discusses some of the most recent developments in all the areas of business and management including management, marketing, business statistics, innovation and technology, finance, sports and tourism. This book might be of great interest for anyone working in the area of management and business economics and might be especially useful for scientists and graduate students doing researc...

  5. Planck 2015 results. XXVI. The Second Planck Catalogue of Compact Sources

    CERN Document Server

    Ade, P.A.R.; Argueso, F.; Arnaud, M.; Ashdown, M.; Aumont, J.; Baccigalupi, C.; Banday, A.J.; Barreiro, R.B.; Bartolo, N.; Battaner, E.; Beichman, C.; Benabed, K.; Benoit, A.; Benoit-Levy, A.; Bernard, J.P.; Bersanelli, M.; Bielewicz, P.; Bock, J.J.; Bohringer, H.; Bonaldi, A.; Bonavera, L.; Bond, J.R.; Borrill, J.; Bouchet, F.R.; Boulanger, F.; Bucher, M.; Burigana, C.; Butler, R.C.; Calabrese, E.; Cardoso, J.F.; Carvalho, P.; Catalano, A.; Challinor, A.; Chamballu, A.; Chary, R.R.; Chiang, H.C.; Christensen, P.R.; Clemens, M.; Clements, D.L.; Colombi, S.; Colombo, L.P.L.; Combet, C.; Couchot, F.; Coulais, A.; Crill, B.P.; Curto, A.; Cuttaia, F.; Danese, L.; Davies, R.D.; Davis, R.J.; de Bernardis, P.; de Rosa, A.; de Zotti, G.; Delabrouille, J.; Desert, F.X.; Dickinson, C.; Diego, J.M.; Dole, H.; Donzelli, S.; Dore, O.; Douspis, M.; Ducout, A.; Dupac, X.; Efstathiou, G.; Elsner, F.; Ensslin, T.A.; Eriksen, H.K.; Falgarone, E.; Fergusson, J.; Finelli, F.; Forni, O.; Frailis, M.; Fraisse, A.A.; Franceschi, E.; Frejsel, A.; Galeotta, S.; Galli, S.; Ganga, K.; Giard, M.; Giraud-Heraud, Y.; Gjerlow, E.; Gonzalez-Nuevo, J.; Gorski, K.M.; Gratton, S.; Gregorio, A.; Gruppuso, A.; Gudmundsson, J.E.; Hansen, F.K.; Hanson, D.; Harrison, D.L.; Helou, G.; Henrot-Versille, S.; Hernandez-Monteagudo, C.; Herranz, D.; Hildebrandt, S.R.; Hivon, E.; Hobson, M.; Holmes, W.A.; Hornstrup, A.; Hovest, W.; Huffenberger, K.M.; Hurier, G.; Jaffe, A.H.; Jaffe, T.R.; Jones, W.C.; Juvela, M.; Keihanen, E.; Keskitalo, R.; Kisner, T.S.; Kneissl, R.; Knoche, J.; Kunz, M.; Kurki-Suonio, H.; Lagache, G.; Lahteenmaki, A.; Lamarre, J.M.; Lasenby, A.; Lattanzi, M.; Lawrence, C.R.; Leahy, J.P.; Leonardi, R.; Leon-Tavares, J.; Lesgourgues, J.; Levrier, F.; Liguori, M.; Lilje, P.B.; Linden-Vornle, M.; Lopez-Caniego, M.; Lubin, P.M.; Macias-Perez, J.F.; Maggio, G.; Maino, D.; Mandolesi, N.; Mangilli, A.; Maris, M.; Marshall, D.J.; Martin, P.G.; Martinez-Gonzalez, E.; Masi, S.; Matarrese, S.; McGehee, P.; Meinhold, P.R.; Melchiorri, A.; Mendes, L.; Mennella, A.; Migliaccio, M.; Mitra, S.; Miville-Deschenes, M.A.; Moneti, A.; Montier, L.; Morgante, G.; Mortlock, D.; Moss, A.; Munshi, D.; Murphy, J.A.; Naselsky, P.; Nati, F.; Natoli, P.; Negrello, M.; Netterfield, C.B.; Norgaard-Nielsen, H.U.; Noviello, F.; Novikov, D.; Novikov, I.; Oxborrow, C.A.; Paci, F.; Pagano, L.; Pajot, F.; Paladini, R.; Paoletti, D.; Partridge, B.; Pasian, F.; Patanchon, G.; Pearson, T.J.; Perdereau, O.; Perotto, L.; Perrotta, F.; Pettorino, V.; Piacentini, F.; Piat, M.; Pierpaoli, E.; Pietrobon, D.; Plaszczynski, S.; Pointecouteau, E.; Polenta, G.; Pratt, G.W.; Prezeau, G.; Prunet, S.; Puget, J.L.; Rachen, J.P.; Reach, W.T.; Rebolo, R.; Reinecke, M.; Remazeilles, M.; Renault, C.; Renzi, A.; Ristorcelli, I.; Rocha, G.; Rosset, C.; Rossetti, M.; Roudier, G.; Rowan-Robinson, M.; Rubino-Martin, J.A.; Rusholme, B.; Sandri, M.; Sanghera, H.S.; Santos, D.; Savelainen, M.; Savini, G.; Scott, D.; Seiffert, M.D.; Shellard, E.P.S.; Spencer, L.D.; Stolyarov, V.; Sudiwala, R.; Sunyaev, R.; Sutton, D.; Suur-Uski, A.S.; Sygnet, J.F.; Tauber, J.A.; Terenzi, L.; Toffolatti, L.; Tomasi, M.; Tornikoski, M.; Tristram, M.; Tucci, M.; Tuovinen, J.; Turler, M.; Umana, G.; Valenziano, L.; Valiviita, J.; Van Tent, B.; Vielva, P.; Villa, F.; Wade, L.A.; Walter, B.; Wandelt, B.D.; Wehus, I.K.; Yvon, D.; Zacchei, A.; Zonca, A.

    2016-01-01

    The Second Planck Catalogue of Compact Sources is a catalogue of sources detected in single-frequency maps from the full duration of the Planck mission and supersedes previous versions of the Planck compact source catalogues. It consists of compact sources, both Galactic and extragalactic, detected over the entire sky. Compact sources detected in the lower frequency channels are assigned to the PCCS2, while at higher frequencies they are assigned to one of two sub-catalogues, the PCCS2 or PCCS2E, depending on their location on the sky. The first of these catalogues covers most of the sky and allows the user to produce subsamples at higher reliabilities than the target 80% integral reliability of the catalogue. The PCCS2E contains sources detected in sky regions where the diffuse emission makes it difficult to quantify the reliability of the detections. Both the PCCS2 and PCCS2E include polarization measurements, in the form of polarized flux densities, or upper limits, and orientation angles for all seven pol...

  6. Planck 2015 results: XXVI. The Second Planck Catalogue of Compact Sources

    DEFF Research Database (Denmark)

    Ade, P. A R; Aghanim, N.; Arguëso, F.;

    2016-01-01

    The Second Planck Catalogue of Compact Sources is a list of discrete objects detected in single-frequency maps from the full duration of the Planck mission and supersedes previous versions. It consists of compact sources, both Galactic and extragalactic, detected over the entire sky. Compact sour...

  7. Planck 2013 results. XXVI. Background geometry and topology of the Universe

    CERN Document Server

    Ade, P.A.R.; Armitage-Caplan, C.; Arnaud, M.; Ashdown, M.; Atrio-Barandela, F.; Aumont, J.; Baccigalupi, C.; Banday, A.J.; Barreiro, R.B.; Bartlett, J.G.; Battaner, E.; Benabed, K.; Benoit, A.; Benoit-Levy, A.; Bernard, J.P.; Bersanelli, M.; Bielewicz, P.; Bobin, J.; Bock, J.J.; Bonaldi, A.; Bonavera, L.; Bond, J.R.; Borrill, J.; Bouchet, F.R.; Bridges, M.; Bucher, M.; Burigana, C.; Butler, R.C.; Cardoso, J.F.; Catalano, A.; Challinor, A.; Chamballu, A.; Chiang, L.Y.; Chiang, H.C.; Christensen, P.R.; Church, S.; Clements, D.L.; Colombi, S.; Colombo, L.P.L.; Couchot, F.; Coulais, A.; Crill, B.P.; Curto, A.; Cuttaia, F.; Danese, L.; Davies, R.D.; Davis, R.J.; de Bernardis, P.; de Rosa, A.; de Zotti, G.; Delabrouille, J.; Delouis, J.M.; Desert, F.X.; Diego, J.M.; Dole, H.; Donzelli, S.; Dore, O.; Douspis, M.; Dupac, X.; Efstathiou, G.; Ensslin, T.A.; Eriksen, H.K.; Finelli, F.; Forni, O.; Frailis, M.; Franceschi, E.; Galeotta, S.; Ganga, K.; Giard, M.; Giardino, G.; Giraud-Heraud, Y.; Gonzalez-Nuevo, J.; Gorski, K.M.; Gratton, S.; Gregorio, A.; Gruppuso, A.; Hansen, F.K.; Hanson, D.; Harrison, D.; Henrot-Versille, S.; Hernandez-Monteagudo, C.; Herranz, D.; Hildebrandt, S.R.; Hivon, E.; Hobson, M.; Holmes, W.A.; Hornstrup, A.; Hovest, W.; Huffenberger, K.M.; Jaffe, T.R.; Jaffe, A.H.; Jones, W.C.; Juvela, M.; Keihanen, E.; Keskitalo, R.; Kisner, T.S.; Knoche, J.; Knox, L.; Kunz, M.; Kurki-Suonio, H.; Lagache, G.; Lahteenmaki, A.; Lamarre, J.M.; Lasenby, A.; Laureijs, R.J.; Lawrence, C.R.; Leahy, J.P.; Leonardi, R.; Leroy, C.; Lesgourgues, J.; Liguori, M.; Lilje, P.B.; Linden-Vornle, M.; Lopez-Caniego, M.; Lubin, P.M.; Macias-Perez, J.F.; Maffei, B.; Maino, D.; Mandolesi, N.; Maris, M.; Marshall, D.J.; Martin, P.G.; Martinez-Gonzalez, E.; Masi, S.; Matarrese, S.; Matthai, F.; Mazzotta, P.; McEwen, J.D.; Melchiorri, A.; Mendes, L.; Mennella, A.; Migliaccio, M.; Mitra, S.; Miville-Deschenes, M.A.; Moneti, A.; Montier, L.; Morgante, G.; Mortlock, D.; Moss, A.; Munshi, D.; Naselsky, P.; Nati, F.; Natoli, P.; Netterfield, C.B.; Norgaard-Nielsen, H.U.; Noviello, F.; Novikov, D.; Novikov, I.; Osborne, S.; Oxborrow, C.A.; Paci, F.; Pagano, L.; Pajot, F.; Paoletti, D.; Pasian, F.; Patanchon, G.; Peiris, H.V.; Perdereau, O.; Perotto, L.; Perrotta, F.; Piacentini, F.; Piat, M.; Pierpaoli, E.; Pietrobon, D.; Plaszczynski, S.; Pointecouteau, E.; Pogosyan, D.; Polenta, G.; Ponthieu, N.; Popa, L.; Poutanen, T.; Pratt, G.W.; Prezeau, G.; Prunet, S.; Puget, J.L.; Rachen, J.P.; Rebolo, R.; Reinecke, M.; Remazeilles, M.; Renault, C.; Riazuelo, A.; Ricciardi, S.; Riller, T.; Ristorcelli, I.; Rocha, G.; Rosset, C.; Roudier, G.; Rowan-Robinson, M.; Rusholme, B.; Sandri, M.; Santos, D.; Savini, G.; Scott, D.; Seiffert, M.D.; Shellard, E.P.S.; Spencer, L.D.; Starck, J.L.; Stolyarov, V.; Stompor, R.; Sudiwala, R.; Sureau, F.; Sutton, D.; Suur-Uski, A.S.; Sygnet, J.F.; Tauber, J.A.; Tavagnacco, D.; Terenzi, L.; Toffolatti, L.; Tomasi, M.; Tristram, M.; Tucci, M.; Tuovinen, J.; Valenziano, L.; Valiviita, J.; Van Tent, B.; Varis, J.; Vielva, P.; Villa, F.; Vittorio, N.; Wade, L.A.; Wandelt, B.D.; Yvon, D.; Zacchei, A.; Zonca, A.

    2014-01-01

    Planck CMB temperature maps allow detection of large-scale departures from homogeneity and isotropy. We search for topology with a fundamental domain nearly intersecting the last scattering surface (comoving distance $\\chi_r$). For most topologies studied the likelihood maximized over orientation shows some preference for multi-connected models just larger than $\\chi_r$. This effect is also present in simulated realizations of isotropic maps and we interpret it as the alignment of mild anisotropic correlations with chance features in a single realization; such a feature can also exist, in milder form, when the likelihood is marginalized over orientations. Thus marginalized, the limits on the radius $R_i$ of the largest sphere inscribed in a topological domain (at log-likelihood-ratio -5) are: in a flat Universe, $R_i>0.9\\chi_r$ for the cubic torus (cf. $R_i>0.9\\chi_r$ at 99% CL for a matched-circles search); $R_i>0.7\\chi_r$ for the chimney; $R_i>0.5\\chi_r$ for the slab; in a positively curved Universe, $R_i>1...

  8. Planck 2013 results. XXVI. Background geometry and topology of the Universe

    DEFF Research Database (Denmark)

    Planck Collaboration,; Ade, P. A. R.; Aghanim, N.

    2013-01-01

    -scale anomalies seen in Planck data. However, the cosmological parameters are in strong disagreement with those found from CMB anisotropy data alone. In the physically motivated setting where the Bianchi parameters are fitted simultaneously with the standard cosmological parameters, we find no evidence...... realization; such a feature can also be present, in milder form, when the likelihood is marginalized over orientations. Thus marginalized, the limits on the radius R_i of the largest sphere inscribed in a topological domain (at log-likelihood-ratio -5) are: in a flat Universe, R_i>0.9X_r for the cubic torus...... (cf. R_i>0.9X_r at 99% CL for the matched-circles search); R_i>0.7X_r for the chimney; R_i>0.5X_r for the slab; in a positively curved Universe, R_i>1.0X_r for the dodecahedron; R_i>1.0X_r for the truncated cube; and R_i>0.9X_r for the octahedron. We perform a Bayesian search for an anisotropic...

  9. Planck intermediate results. XXVI. Optical identification and redshifts of Planck clusters with the RTT150 telescope

    DEFF Research Database (Denmark)

    Ade, P. A. R.; Aghanim, N.; Arnaud, M.;

    2015-01-01

    We present the results of approximately three years of observations of Planck Sunyaev-Zeldovich (SZ) sources with the Russian-Turkish 1.5m telescope (RTT150), as a part of the optical follow-up programme undertaken by the Planck collaboration. During this time period approximately 20% of all dark...

  10. Comparison of Microstructural and Morphological Properties of Electrodeposited Fe-Cu Thin Films with Low and High Fe : Cu Ratio

    Directory of Open Access Journals (Sweden)

    Umut Sarac

    2013-01-01

    Full Text Available Fe-Cu films with low and high Fe : Cu ratio have been produced from the electrolytes with different Fe ion concentrations at a constant deposition potential of −1400 mV versus saturated calomel electrode (SCE by electrodeposition technique onto indium tin oxide (ITO coated conducting glass substrates. It was observed that the variation of Fe ion concentration in the electrolyte had a very strong influence on the compositional, surface morphological, and microstructural properties of the Fe-Cu films. An increase in the Fe ion concentration within the plating bath increased the Fe content, consequently Fe : Cu ratio within the films. The crystallographic structure analysis showed that the Fe-Cu films had a mixture of face-centered cubic (fcc Cu and body centered cubic (bcc α-Fe phases. The average crystallite size decreased with the Fe ion concentration. The film electrodeposited from the electrolyte with low Fe ion concentration exhibited a morphology consisting of dendritic structures. However, the film morphology changed from dendritic structure to cauliflower-like structure at high Fe ion concentration. The surface roughness and grain size were found to decrease significantly with increasing Fe ion concentration in the electrolyte. The significant differences observed in the microstructural and morphological properties caused by the change of Fe ion concentration in the electrolyte were ascribed to the change of Fe : Cu ratio within the films.

  11. Shewanella putrefaciens produces an Fe(III)-solubilizing organic ligand during anaerobic respiration on insoluble Fe(III) oxides.

    Science.gov (United States)

    Taillefert, Martial; Beckler, Jordon S; Carey, Elizabeth; Burns, Justin L; Fennessey, Christine M; DiChristina, Thomas J

    2007-11-01

    The mechanism of Fe(III) reduction was investigated using voltammetric techniques in anaerobic incubations of Shewanella putrefaciens strain 200 supplemented with Fe(III) citrate or a suite of Fe(III) oxides as terminal electron acceptor. Results indicate that organic complexes of Fe(III) are produced during the reduction of Fe(III) at rates that correlate with the reactivity of the Fe(III) phase and bacterial cell density. Anaerobic Fe(III) solubilization activity is detected with either Fe(III) oxides or Fe(III) citrate, suggesting that the organic ligand produced is strong enough to destabilize Fe(III) from soluble or solid Fe(III) substrates. Results also demonstrate that Fe(III) oxide dissolution is not controlled by the intrinsic chemical reactivity of the Fe(III) oxides. Instead, the chemical reaction between the endogenous organic ligand is only affected by the number of reactive surface sites available to S. putrefaciens. This report describes the first application of voltammetric techniques to demonstrate production of soluble organic-Fe(III) complexes by any Fe(III)-reducing microorganism and is the first report of a Fe(III)-solubilizing ligand generated by a metal-reducing member of the genus Shewanella.

  12. Online spectrophotometric determination of Fe(II) and Fe(III) by flow injection combined with low pressure ion chromatography

    Science.gov (United States)

    Chen, Shujuan; Li, Nan; Zhang, Xinshen; Yang, Dongjing; Jiang, Heimei

    2015-03-01

    A simple and new low pressure ion chromatography combined with flow injection spectrophotometric procedure for determining Fe(II) and Fe(III) was established. It is based on the selective adsorption of low pressure ion chromatography column to Fe(II) and Fe(III), the online reduction reaction of Fe(III) and the reaction of Fe(II) in sodium acetate with phenanthroline, resulting in an intense orange complex with a suitable absorption at 515 nm. Various chemical (such as the concentration of colour reagent, eluant and reductive agent) and instrumental parameters (reaction coil length, reductive coil length and wavelength) were studied and were optimized. Under the optimum conditions calibration graph of Fe(II)/Fe(III) was linear in the Fe(II)/Fe(III) range of 0.040-1.0 mg/L. The detection limit of Fe(III) and Fe(II) was respectively 3.09 and 1.55 μg/L, the relative standard deviation (n = 10) of Fe(II) and Fe(III) 1.89% and 1.90% for 0.5 mg/L of Fe(II) and Fe(III) respectively. About 2.5 samples in 1 h can be analyzed. The interfering effects of various chemical species were studied. The method was successfully applied in the determination of water samples.

  13. In situ observation of the formation of FeSe

    DEFF Research Database (Denmark)

    Grivel, Jean-Claude; Wulff, Anders Christian; Yue, Zhao;

    2011-01-01

    The formation of the FeSe compound from a mixture of Fe and Se powders encased in a composite Cu/Nb sheath was studied in situ by means of high-energy synchrotron x-ray diffraction. Tetragonal beta-FeSe does not seem to form directly from the starting elements. Instead, a sequence of FeSe2, Fe3Se4...

  14. Fe-Impregnated Mineral Colloids for Peroxide Activation: Effects of Mineral Substrate and Fe Precursor.

    Science.gov (United States)

    Li, Yue; Machala, Libor; Yan, Weile

    2016-02-02

    Heterogeneous iron species at the mineral/water interface are important catalysts for the generation of reactive oxygen species at circumneutral pH. One significant pathway leading to the formation of such species arises from deposition of dissolved iron onto mineral colloids due to changes in redox conditions. This study investigates the catalytic properties of Fe impregnated on silica, alumina, and titania nanoparticles (as prototypical mineral colloids). Fe impregnation was carried out by immersing the mineral nanoparticles in dilute Fe(II) or Fe(III) solutions at pH 6 and 3, respectively, in an aerobic environment. The uptake of iron per unit surface area follows the order of nTiO2 > nAl2O3 > nSiO2 for both types of Fe precursors. Impregnation of mineral particles in Fe(II) solutions results in predominantly Fe(III) species due to efficient surface-mediated oxidation. The catalytic activity of the impregnated solids to produce hydroxyl radical (·OH) from H2O2 decomposition was evaluated using benzoic acid as a probe compound under dark conditions. Invariably, the rates of benzoic acid oxidation with different Fe-laden particles increase with the surface density of Fe until a critical density above which the catalytic activity approaches a plateau, suggesting active Fe species are formed predominantly at low surface loadings. The critical surface density of Fe varies with the mineral substrate as well as the aqueous Fe precursor. Fe impregnated on TiO2 exhibits markedly higher activity than its Al2O3 and SiO2 counterparts. The speciation of interfacial Fe is analyzed with diffuse reflectance UV-vis analysis and interpretation of the data in the context of benzoic oxidation rates suggests that the surface activity of the solids for ·OH generation correlates strongly with the isolated (i.e., mononuclear) Fe species. Therefore, iron dispersed on mineral colloids is a significant form of reactive iron surfaces in the aquatic environment.

  15. Fe biomineralization mirrors individual metabolic activity in a nitrate-dependent Fe(II-oxidizer

    Directory of Open Access Journals (Sweden)

    Jennyfer eMIOT

    2015-09-01

    Full Text Available Microbial biomineralization sometimes leads to periplasmic encrustation, which is predicted to enhance microorganism preservation in the fossil record. Mineral precipitation within the periplasm is however thought to induce death, as a result of permeability loss preventing nutrient and waste transit across the cell wall. This hypothesis had however never been investigated down to the single cell level. Here, we cultured the nitrate reducing Fe(II oxidizing bacteria Acidovorax sp. strain BoFeN1 that have been previously shown to promote the precipitation of a diversity of Fe minerals (lepidocrocite, goethite, Fe phosphate encrusting the periplasm. We investigated the connection of Fe biomineralization with carbon assimilation at the single cell level, using a combination of electron microscopy and Nano-Secondary Ion Mass Spectrometry (NanoSIMS. Our analyses revealed strong individual heterogeneities of Fe biomineralization. Noteworthy, a small proportion of cells remaining free of any precipitate persisted even at advanced stages of biomineralization. Using pulse chase experiments with 13C-acetate, we provide evidences of individual phenotypic heterogeneities of carbon assimilation, correlated with the level of Fe biomineralization. Whereas non- and moderately encrusted cells were able to assimilate acetate, higher levels of periplasm encrustation prevented any carbon incorporation. Carbon assimilation only depended on the level of Fe encrustation and not on the nature of Fe minerals precipitated in the cell wall. Carbon assimilation decreased exponentially with increasing cell-associated Fe content. Persistence of a small proportion of non-mineralized and metabolically active cells might constitute a strategy of survival in highly ferruginous environments. Eventually, our results suggest that periplasmic Fe biomineralization may provide a signature of individual metabolic status, which could be looked for in the fossil record and in modern

  16. Redox reactions of [FeFe]-hydrogenase models containing an internal amine and a pendant phosphine.

    Science.gov (United States)

    Zheng, Dehua; Wang, Mei; Chen, Lin; Wang, Ning; Sun, Licheng

    2014-02-03

    A diiron dithiolate complex with a pendant phosphine coordinated to one of the iron centers, [(μ-SCH2)2N(CH2C6H4-o-PPh2){Fe2(CO)5}] (1), was prepared and structurally characterized. The pendant phosphine is dissociated together with a CO ligand in the presence of excess PMe3, to afford [(μ-SCH2)2N(CH2C6H4-o-PPh2){Fe(CO)2(PMe3)}2] (2). Redox reactions of 2 and related complexes were studied in detail by in situ IR spectroscopy. A series of new Fe(II)Fe(I) ([3](+) and [6](+)), Fe(II)Fe(II) ([4](2+)), and Fe(I)Fe(I) (5) complexes relevant to Hox, Hox(CO), and Hred states of the [FeFe]-hydrogenase active site were detected. Among these complexes, the molecular structures of the diferrous complex [4](2+) with the internal amine and the pendant phosphine co-coordinated to the same iron center and the triphosphine diiron complex 5 were determined by X-ray crystallography. To make a comparison, the redox reactions of an analogous complex, [(μ-SCH2)2N(CH2C6H5){Fe(CO)2(PMe3)}2] (7), were also investigated by in situ IR spectroscopy in the absence or presence of extrinsic PPh3, which has no influence on the oxidation reaction of 7. The pendant phosphine in the second coordination sphere makes the redox reaction of 2 different from that of its analogue 7.

  17. Fe biomineralization mirrors individual metabolic activity in a nitrate-dependent Fe(II)-oxidizer

    Science.gov (United States)

    Miot, Jennyfer; Remusat, Laurent; Duprat, Elodie; Gonzalez, Adriana; Pont, Sylvain; Poinsot, Mélanie

    2015-01-01

    Microbial biomineralization sometimes leads to periplasmic encrustation, which is predicted to enhance microorganism preservation in the fossil record. Mineral precipitation within the periplasm is, however, thought to induce death, as a result of permeability loss preventing nutrient and waste transit across the cell wall. This hypothesis had, however, never been investigated down to the single cell level. Here, we cultured the nitrate reducing Fe(II) oxidizing bacteria Acidovorax sp. strain BoFeN1 that have been previously shown to promote the precipitation of a diversity of Fe minerals (lepidocrocite, goethite, Fe phosphate) encrusting the periplasm. We investigated the connection of Fe biomineralization with carbon assimilation at the single cell level, using a combination of electron microscopy and Nano-Secondary Ion Mass Spectrometry. Our analyses revealed strong individual heterogeneities of Fe biomineralization. Noteworthy, a small proportion of cells remaining free of any precipitate persisted even at advanced stages of biomineralization. Using pulse chase experiments with 13C-acetate, we provide evidence of individual phenotypic heterogeneities of carbon assimilation, correlated with the level of Fe biomineralization. Whereas non- and moderately encrusted cells were able to assimilate acetate, higher levels of periplasmic encrustation prevented any carbon incorporation. Carbon assimilation only depended on the level of Fe encrustation and not on the nature of Fe minerals precipitated in the cell wall. Carbon assimilation decreased exponentially with increasing cell-associated Fe content. Persistence of a small proportion of non-mineralized and metabolically active cells might constitute a survival strategy in highly ferruginous environments. Eventually, our results suggest that periplasmic Fe biomineralization may provide a signature of individual metabolic status, which could be looked for in the fossil record and in modern environmental samples. PMID

  18. Sound velocities of Fe and Fe-Si alloy in the Earth's core.

    Science.gov (United States)

    Mao, Zhu; Lin, Jung-Fu; Liu, Jin; Alatas, Ahmet; Gao, Lili; Zhao, Jiyong; Mao, Ho-Kwang

    2012-06-26

    Compressional wave velocity-density (V(P)--ρ) relations of candidate Fe alloys at relevant pressure-temperature conditions of the Earth's core are critically needed to evaluate the composition, seismic signatures, and geodynamics of the planet's remotest region. Specifically, comparison between seismic V(P)--ρ profiles of the core and candidate Fe alloys provides first-order information on the amount and type of potential light elements--including H, C, O, Si, and/or S-needed to compensate the density deficit of the core. To address this issue, here we have surveyed and analyzed the literature results in conjunction with newly measured V(P)--ρ results of hexagonal closest-packed (hcp) Fe and hcp-Fe(0.85)Si(0.15) alloy using in situ high-energy resolution inelastic X-ray scattering and X-ray diffraction. The nature of the Fe-Si alloy where Si is readily soluble in Fe represents an ideal solid-solution case to better understand the light-element alloying effects. Our results show that high temperature significantly decreases the V(P) of hcp-Fe at high pressures, and the Fe-Si alloy exhibits similar high-pressure V(P)--ρ behavior to hcp-Fe via a constant density offset. These V(P)--ρ data at a given temperature can be better described by an empirical power-law function with a concave behavior at higher densities than with a linear approximation. Our new datasets, together with literature results, allow us to build new V(P)--ρ models of Fe alloys in order to determine the chemical composition of the core. Our models show that the V(P)--ρ profile of Fe with 8 wt % Si at 6,000 K matches well with the Preliminary Reference Earth Model of the inner core.

  19. Electronic Properties of LiFePO4 and Li doped LiFePO4

    Energy Technology Data Exchange (ETDEWEB)

    Allen, J.L.; Zhuang, G.V.; Ross, P.N.; Guo, J.-H.; Jow, T.R.

    2006-05-31

    LiFePO{sub 4} has several potential advantages in comparison to the transition metal oxide cathode materials used in commercial lithium-ion batteries. However, its low intrinsic electronic conductivity ({approx} 10{sup -9} S/cm) is problematic. We report here a study by soft x-ray absorption/emission spectroscopy of the electronic properties of undoped LiFePO{sub 4} and Li-doped LiFePO{sub 4} in which Li{sup +} ions are substituted for Fe{sup 2+} ions in an attempt to increase the intrinsic electronic conductivity. The conductivities of the Li{sub 1+x}Fe{sub 1-x}PO{sub 4} samples were, however, essentially unchanged from that of the undoped LiFePO{sub 4}. Nonetheless, evidence for changing the electronic properties of LiFePO{sub 4} by doping with excess Li+ was observed by the XAS/XES spectroscopy. New pre-edge features the O-1s XAS spectrum of Li{sub 1.05}Fe{sub 0.95}PO4 is a direct indication that the charge compensation for substitution of Fe{sup 2+} by Li{sup +} resides in the unoccupied O-2p orbitals. A charge transfer (CT) excitation was also observed in the doped material implying that the unoccupied O-2p orbitals created by doping are strongly hybridized with unoccupied Fe-3d orbitals of neighboring sites. However, the strong covalent bonding within the (PO{sub 4}){sup 3-} anions and the large separation of the Fe cations means that the charge created by doping is not delocalized in the manner of electrons or holes in a semiconductor.

  20. Directional alignment of FeCo crystallites in Si/NiFe/Ru/FeCoB multilayer with high anisotropy field above 500 Oe.

    Science.gov (United States)

    Hirata, Ken-Ichiro; Gomi, Shunsuke; Nakagawa, Shigeki

    2011-03-01

    In-plane magnetic anisotropy and crystal structure of FeCoB layer on Si/NiFe/Ru underlayer were investigated by using X-Ray Diffraction (XRD) measurement. A pole-figure measurement of XRD showed directionally tilted alignment of FeCo crystallites in Si/NiFe/Ru/FeCoB multilayered film with high in-plane anisotropy field H(k) but no directional alignment was found in FeCoB single layered film. The higher H(k) appeared in the Si/NiFe/Ru/FeCoB multilayered configuration with the thicker FeCoB layer. Since Ru crystallites in a multiunderlayer configuration exhibited no directional alignment, the surface structure of underlayer should be no main reason for the directional alignment of FeCo crystallites deposited on it. The dependence of hickness of FeCoB layer in Si/NiFe/Ru/FeCoB film on H(k) indicated that the in-plane magnetic anisotropy is caused by not only the structure of Ru underlayer but also oblique incidence effect of sputtered particles, which is attained in configuration of Facing Targets Sputtering (FTS) system. From these experimental results, remarkably high H(k) of 540 Oe was obtained.

  1. Effect of Cu surface segregation on the exchange coupling field of NiFe/FeMn bilayers

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The NiFe/FeMn bilayers with different buffer layers (Ta or Ta/Cu) were prepared by magnetron sputtering.Results show that the exchange coupling field of NiFe/FeMn films with Ta buffer is higher than that of the films with Ta/ Cu buffer. We analysed the reasons by investigating the crystallographic texture, surface roughness and surface segregation of both films, respectively. We found that the decrease of the exchange coupling fields of NiFe/FeMn films with Ta/Cu buffer layers was mainly caused by the Cu surface segregation on NiFe surface.

  2. Role of PO4 tetrahedron in LiFePO4 and FePO4 system.

    Science.gov (United States)

    Zeng, Yuewu

    2015-06-01

    Using high resolution transmission electron microscopy with image simulation and Fourier analysis, the Li1- x FePO4 (x LiFePO4 and FePO4 resulting from spinodal decomposition which promote Li ion easily getting into the particle due to uphill diffusion, (3) the particles of FePO4 formed in charging have heavily distorted lattice and contain some isolated LiFePO4 , (4) interface between LiFePO4 and FePO4 and between amorphous and crystal region provides the lattice distortion of small polarons.

  3. Fe ii fluorescence in symbiotic stars

    Directory of Open Access Journals (Sweden)

    M. Eriksson

    2004-01-01

    Full Text Available Se ha investigado la uorescencia por PAR del ion Fe II en ocho estrellas simbi oticas con muy diversos valores de la temperatura de la componente caliente y del per odo orbital. Los datos empleados son espectros de archivo del IUE. Todas las l neas de bombeo estudiadas se encuentran en la regi on (1200-2000 A del IUE, excepto He II 1084.942 y O VI 1032.041. Las l neas de uorescencia del Fe II est an principalmente en la regi on Fe II, pero algunas caen en la regi on de las l neas de bombeo. Nuestro objetivo es entender las condiciones optimas para la formaci on de l neas de uorescencia por PAR del Fe II. Tres de los sistemas estudiados, RR Tel, AG Peg and V1016 Cyg, presentan 10-30 canales activos del Fe II. Dos condiciones relacionan a estos sistemas. La componente caliente es una enana blanca de temperatura extrema (80 103-150 103 K, y los tres sistemas son novas simbi oticas, que han tenido erupciones en los ultimos 150 a~nos. Los sistemas AG Dra, RW Hya and R Aqr tienen s olo 2-3 canales activos del Fe II. Los dos sistemas restantes, CI Cyg and T CrB, no mostraron l neas de uorescencia del Fe II. Estos sistemas tienen en com un que la intensidad de emisi on de los elementos altamente ionizados es menor que en la mayor a de los sistemas simbi oticos, y que la componente caliente puede ser una estrella de secuencia principal con acreci on, en vez de una enana blanca.

  4. Accumulation of Fe oxyhydroxides in the Peruvian oxygen deficient zone implies non-oxygen dependent Fe oxidation

    Science.gov (United States)

    Heller, Maija I.; Lam, Phoebe J.; Moffett, James W.; Till, Claire P.; Lee, Jong-Mi; Toner, Brandy M.; Marcus, Matthew A.

    2017-08-01

    Oxygen minimum zones (OMZs) have been proposed to be an important source of dissolved iron (Fe) into the interior ocean. However, previous studies in OMZs have shown a sharp decrease in total dissolved Fe (dFe) and/or dissolved Fe(II) (dFe(II)) concentrations at the shelf-break, despite constant temperature, salinity and continued lack of oxygen across the shelf-break. The loss of both total dFe and dFe(II) suggests a conversion of the dFe to particulate form, but studies that have coupled the reduction-oxidation (redox) speciation of both dissolved and particulate phases have not previously been done. Here we have measured the redox speciation and concentrations of both dissolved and particulate forms of Fe in samples collected during the U.S. GEOTRACES Eastern tropical Pacific Zonal Transect (EPZT) cruise in 2013 (GP16). This complete data set allows us to assess possible mechanisms for loss of dFe. We observed an offshore loss of dFe(II) within the oxygen deficient zone (ODZ), where dissolved oxygen is undetectable, accompanied by an increase in total particulate Fe (pFe). Total pFe concentrations were highest in the upper ODZ. X-ray absorption spectroscopy revealed that the pFe maximum was primarily in the Fe(III) form as Fe(III) oxyhydroxides. The remarkable similarity in the distributions of total particulate iron and nitrite suggests a role for nitrite in the oxidation of dFe(II) to pFe(III). We present a conceptual model for the rapid redox cycling of Fe that occurs in ODZs, despite the absence of oxygen.

  5. Antiferromagnetic coupling between spinel ferrite and {alpha}-Fe layers in Fe{sub 3-{delta}O4}/MgO/Fe(0 0 1) epitaxial films

    Energy Technology Data Exchange (ETDEWEB)

    Yanagihara, Hideto; Toyoda, Yuta; Kita, Eiji [Institute of Applied Physics, University of Tsukuba, Ibaraki 305-8573 (Japan)

    2011-02-16

    We have investigated interlayer exchange coupling (IEC) in epitaxial films of both Fe{sub 3}O{sub 4}/MgO/Fe(0 0 1) and {gamma}-Fe{sub 2}O{sub 3}/MgO/Fe(0 0 1). Depending on the thickness of the MgO spacer, both systems exhibit strong antiferromagnetic IEC of -1 to -2 erg cm{sup -2}. The {gamma}-Fe{sub 2}O{sub 3}/MgO/Fe(0 0 1) trilayer exhibits the strongest IEC when the thickness of the MgO spacer is approximately 7 A, whereas the Fe{sub 3}O{sub 4}/MgO/Fe(0 0 1) trilayer exhibits the strongest IEC when the thickness of the MgO spacer is zero. The results suggest that two different types of exchange coupling exist in the magnetic trilayers which consist of metallic iron and spinel ferrite layers.

  6. Fe hydroxyphosphate precipitation and Fe(II) oxidation kinetics upon aeration of Fe(II) and phosphate-containing synthetic and natural solutions

    Science.gov (United States)

    van der Grift, B.; Behrends, T.; Osté, L. A.; Schot, P. P.; Wassen, M. J.; Griffioen, J.

    2016-08-01

    Exfiltration of anoxic Fe-rich groundwater into surface water and the concomitant oxidative precipitation of Fe are important processes controlling the transport of phosphate (PO4) from agricultural areas to aquatic systems. Here, we explored the relationship between solution composition, reaction kinetics, and the characteristics of the produced Fe hydroxyphosphate precipitates in a series of aeration experiments with anoxic synthetic water and natural groundwater. A pH stat device was used to maintain constant pH and to record the H+ production during Fe(II) oxidation in the aeration experiments in which the initial aqueous P/Fe ratios ((P/Fe)ini), oxygen concentration and pH were varied. In general, Fe(II) oxidation proceeded slower in the presence of PO4 but the decrease of the PO4 concentration during Fe(II) oxidation due to the formation of Fe hydroxyphosphates caused additional deceleration of the reaction rate. The progress of the reaction could be described using a pseudo-second-order rate law with first-order dependencies on PO4 and Fe(II) concentrations. After PO4 depletion, the Fe(II) oxidation rates increased again and the kinetics followed a pseudo-first-order rate law. The first-order rate constants after PO4 depletion, however, were lower compared to the Fe(II) oxidation in a PO4-free solution. Hence, the initially formed Fe hydroxyphosphates also affect the kinetics of continuing Fe(II) oxidation after PO4 depletion. Presence of aqueous PO4 during oxidation of Fe(II) led to the formation of Fe hydroxyphosphates. The P/Fe ratios of the precipitates ((P/Fe)ppt) and the recorded ratio of H+ production over decrease in dissolved Fe(II) did not change detectably throughout the reaction despite a changing P/Fe ratio in the solution. When (P/Fe)ini was 0.9, precipitates with a (P/Fe)ppt ratio of about 0.6 were formed. In experiments with (P/Fe)ini ratios below 0.6, the (P/Fe)ppt decreased with decreasing (P/Fe)ini and pH value. Aeration experiments with

  7. Magnetic properties of the nanocomposite CoFe2O4/FeCo-FeO at a high H/T regime

    Science.gov (United States)

    Machado, F. L. A.; Soares, J. M.; Conceição, O. L. A.; Choi, E. S.; Balicas, L.

    2017-02-01

    The low temperature magnetic properties of nanopowders of CoFe2O4 and of CoFe2O4/FeCo-FeO with average particle size of about 6 nm were investigated for temperatures down to 5 K and for applied magnetic fields up to 350 kOe. Highly enhanced coercive fields were obtained for the CoFe2O4 nanoparticles. The values of the saturation magnetization MS and of the anisotropy constant K1 were also found to be enhanced for the nanocomposite powder sample. The overall results are discussed in terms of a particle model which takes into account a thin amorphous layer present in the CoFe2O4 particles and due to a FeCo-FeO layer grown during an annealing procedure. Moreover, the temperature dependence of K1 was found to be in good agreement with a model proposed by Tachiki.

  8. Triple-stranded ferric helices: a π-π interaction-driven structural hierarchy of Fe5, Fe7, and Fe17 clusters.

    Science.gov (United States)

    Shiga, Takuya; Noguchi, Mao; Sato, Hiroki; Matsumoto, Takuto; Newton, Graham N; Oshio, Hiroki

    2013-12-07

    Three polypyridine ligand-supported multinuclear iron complexes, [Fe5], [Fe7] and [Fe17], were synthesized and their physical properties were investigated. The complexes had triple-stranded helical structures with pseudo threefold symmetry, and were stabilized by varying degrees of intramolecular π-π stacking. The pentanuclear iron complex consisted of two Fe(II) and three Fe(III) ions, supported by three ligands, while the heptanuclear complex comprised four Fe(II) centres, three Fe(III) ions, and six ligands, and the heptadecanuclear complex contained seventeen Fe(III) ions and nine ligands. Electrochemical studies revealed that the pentanuclear and heptanuclear iron complexes showed pseudo-reversible three- and five-step redox behaviours, respectively. Magnetic measurements conducted on the pentanuclear and heptanuclear complexes revealed that antiferromagnetic interactions were operative between neighbouring iron ions through the oxo- and pyrazole-bridges.

  9. Thermoelectricity and disorder of FeCo/MgO/FeCo magnetic tunnel junctions

    NARCIS (Netherlands)

    Wang, S.Z.; Xia, K.; Bauer, G.E.W.

    2014-01-01

    We compute the thermoelectric transport parameterized by the Seebeck coefficient and thermal/electric conductance of random-alloy FeCo/MgO/FeCo(001) magnetic tunnel junctions (MTJs) from first principles using a generalized Landauer-Büttiker formalism. The thermopower is found to be typically smalle

  10. Thermal Spin Transfer in Fe-MgO-Fe Tunnel Junctions

    NARCIS (Netherlands)

    Jia, X.; Xia, K.; Bauer, G.E.W.

    2011-01-01

    We compute thermal spin transfer (TST) torques in Fe-MgO-Fe tunnel junctions using a first principles wave-function-matching method. At room temperature, the TST in a junction with 3 MgO monolayers amounts to 10-7  J/m2/K, which is estimated to cause magnetization reversal for temperature difference

  11. Plasma nitrogenation of Pr2Fe17 and Sm2Fe17

    Science.gov (United States)

    Ardisson, Jose D.; Macedo, Waldemar A. A.; Araujo, Roberto C.; Gama, Sergio

    2000-05-01

    The effect of plasma nitrogenation on the structural and magnetic properties of Pr2Fe17 and Sm2Fe17 compounds was investigated by Mössbauer spectroscopy, thermomagnetic measurements, optical metallography, and electronic microprobe analysis. Samples were prepared starting from Pr2Fe17 and Sm2Fe17 commercial powders with 20 μm granulometry, submitted to nitrogenation treatment at 400 °C in 10 Torr atmosphere of 80%H2-20%N2 during periods up to 8 h. Our results show the formation of R2Fe17N3 and metallic Fe and indicate the existence of two other phases. The Mössbauer parameters of the latter are characterized by magnetic hyperfine fields (peak values) of 21 (24) and 3 (4) T and isomer shifts of 0.17 and 0.24 (0.24 and 0.29) mm/s for Pr (Sm). Their magnetic-phase transitions were determined to be close to 250 and 90 °C. Our results suggest that these 2:17 phases present stoichiometries close to R2Fe17N8 and R2Fe17N11, respectively.

  12. A synthetic system links FeFe-hydrogenases to essential E. coli sulfur metabolism

    Directory of Open Access Journals (Sweden)

    Grandl Gerald

    2011-05-01

    Full Text Available Abstract Background FeFe-hydrogenases are the most active class of H2-producing enzymes known in nature and may have important applications in clean H2 energy production. Many potential uses are currently complicated by a crucial weakness: the active sites of all known FeFe-hydrogenases are irreversibly inactivated by O2. Results We have developed a synthetic metabolic pathway in E. coli that links FeFe-hydrogenase activity to the production of the essential amino acid cysteine. Our design includes a complementary host strain whose endogenous redox pool is insulated from the synthetic metabolic pathway. Host viability on a selective medium requires hydrogenase expression, and moderate O2 levels eliminate growth. This pathway forms the basis for a genetic selection for O2 tolerance. Genetically selected hydrogenases did not show improved stability in O2 and in many cases had lost H2 production activity. The isolated mutations cluster significantly on charged surface residues, suggesting the evolution of binding surfaces that may accelerate hydrogenase electron transfer. Conclusions Rational design can optimize a fully heterologous three-component pathway to provide an essential metabolic flux while remaining insulated from the endogenous redox pool. We have developed a number of convenient in vivo assays to aid in the engineering of synthetic H2 metabolism. Our results also indicate a H2-independent redox activity in three different FeFe-hydrogenases, with implications for the future directed evolution of H2-activating catalysts.

  13. Molecular characterization and homologous overexpression of [FeFe]-hydrogenase in Clostridium tyrobutyricum JM1

    Energy Technology Data Exchange (ETDEWEB)

    Jo, Ji Hye [Biosciences Center, National Renewable Energy Laboratory, 1617 Cole Blvd, Golden, CO 80401-3393 (United States); Jeon, Che Ok [Department of Life Science, Chung-Ang University, Seoul 156-756 (Korea); Lee, Seung Yoon [K-water Research Institute, Korea Water Resources Corporation, 462-1, Jeonmin-dong, Yuseong-gu, Daejon 305-703 (Korea); Lee, Dae Sung [Department of Environmental Engineering, Kyungpook National University, 1370 Sankyuk-dong, Buk-gu, Daegu 702-701 (Korea); Park, Jong Moon [Department of Chemical Engineering, Pohang University of Science and Technology, San 31, Hyoja-dong, Nam-gu, Pohang, Gyeongbuk 790-784 (Korea)

    2010-02-15

    The H{sub 2}-evoving [FeFe]-hydrogenase in Clostridium tyrobutyricum JM1 was isolated to elucidate molecular characterization and modular structure of the hydrogenase. Then, homologous overexpression of the hydrogenase gene was for the first time performed to enhance hydrogen production. The hydA open reading frame (ORF) was 1734-bp, encodes 577 amino acids with a predicted molecular mass of 63,970 Da, and presents 80% and 75% identity at the amino acid level with the [FeFe]-hydrogenase genes of Clostridium kluyveri DSM 555 and Clostridium acetobutylicum ATCC 824, respectively. One histidine residue and 19 cysteine residues, known to fasten one [2Fe-2S] cluster, three [4Fe-4S] clusters and one H-cluster, were conserved in hydA of C. tyrobutyricum. A 2327-bp DNA region containing the ORF and the putative promoter region was amplified and subcloned into a pJIR418 shuttle vector. The gene transfer of the recombinant plasmid into C. tyrobutyricum JM1 was performed by a modified electrotransformation method. Homologous overexpression of the [FeFe]-hydrogenase gene resulted in a 1.7-fold and 1.5-fold increase in hydrogenase activity and hydrogen yield concomitant with the shift of metabolic pathway. (author)

  14. Mossbauer Study of Mechanica Aloying Fe-Ti and Fe-Ti-N Alloys

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Mossbauer spectrometry was used to study the peculiarity of formation of nonequilibrium phase in Fe-Ti and Fe-Ti-N systems by mechanical alloying. Mossbauer spectra of powders show the formation of nonequilibrium crystalline phase and intermetallic compounds during a mechanical alloying process depending on the alloy composition and the milling time.

  15. Quantum-well states and induced magnetism in Fe/CuN/Fe bcc (001) trilayers

    DEFF Research Database (Denmark)

    Niklasson, A.M.N.; Mirbt, S.; Skriver, Hans Lomholt

    1996-01-01

    We have used a first-principles Green's function technique to investigate the formation of magnetic moments in Fe/Cu-N/Fe bcc (001) trilayers. We show that the magnetic moment in the paramagnetic spacer material to a first approximation may be described as a linear superposition of the magnetic...

  16. Site occupancy of Fe in ternary Ni75-Fe+Al25- alloys

    Indian Academy of Sciences (India)

    B Annie D'Santhoshini; S N Kaul

    2003-03-01

    The results of a detailed structural and magnetic study clearly indicate that regardless of the thermal history of the samples, Fe has a strong preference for the Ni sites in Ni-poor (non-stoichiometric) Ni75Al25 alloys. Fe substitution has a profound effect on the nature of magnetism in Ni75Al25.

  17. A cell-free microtiter plate screen for improved [FeFe] hydrogenases.

    Directory of Open Access Journals (Sweden)

    James A Stapleton

    Full Text Available BACKGROUND: [FeFe] hydrogenase enzymes catalyze the production and dissociation of H(2, a potential renewable fuel. Attempts to exploit these catalysts in engineered systems have been hindered by the biotechnologically inconvenient properties of the natural enzymes, including their extreme oxygen sensitivity. Directed evolution has been used to improve the characteristics of a range of natural catalysts, but has been largely unsuccessful for [FeFe] hydrogenases because of a lack of convenient screening platforms. METHODOLOGY/PRINCIPAL FINDINGS: Here we describe an in vitro screening technology for oxygen-tolerant and highly active [FeFe] hydrogenases. Despite the complexity of the protocol, we demonstrate a level of reproducibility that allows moderately improved mutants to be isolated. We have used the platform to identify a mutant of the Chlamydomonas reinhardtii [FeFe] hydrogenase HydA1 with a specific activity approximately 4 times that of the wild-type enzyme. CONCLUSIONS/SIGNIFICANCE: Our results demonstrate the feasibility of using the screen presented here for large-scale efforts to identify improved biocatalysts for energy applications. The system is based on our ability to activate these complex enzymes in E. coli cell extracts, which allows unhindered access to the protein maturation and assay environment.

  18. Photocatalytic hydrogen production from a simple water-soluble [FeFe]-hydrogenase model system.

    Science.gov (United States)

    Cao, Wei-Ning; Wang, Feng; Wang, Hong-Yan; Chen, Bin; Feng, Ke; Tung, Chen-Ho; Wu, Li-Zhu

    2012-08-21

    Combined with a simple water soluble [FeFe]-hydrogenase mimic 1, Ru(bpy)(3)(2+) and ascorbic acid enable hydrogen production photocatalytically. More than 88 equivalents of H(2) were achieved in water, which is much better than that obtained in an organic solvent or a mixture of organic solvent and water.

  19. Efficacy of an inactivated FeLV vaccine compared to a recombinant FeLV vaccine in minimum age cats following virulent FeLV challenge.

    Science.gov (United States)

    Stuke, Kristin; King, Vickie; Southwick, Kendra; Stoeva, Mira I; Thomas, Anne; Winkler, M Teresa C

    2014-05-07

    The aim of the study was to determine the efficacy of an inactivated feline leukemia virus (FeLV) vaccine (Versifel(®) FeLV, Zoetis.) compared to a recombinant FeLV vaccine (Purevax(®) FeLV, Merial Animal Health) in young cats, exposed under laboratory conditions to a highly virulent challenge model. The study was designed to be consistent with the general immunogenicity requirements of the European Pharmacopoeia 6.0 Monograph 01/2008:1321-Feline Leukaemia Vaccine (Inactivated) with the exception that commercial-strength vaccines were assessed. Fifty seronegative cats (8-9 weeks old) were vaccinated subcutaneously on two occasions, three weeks apart, with either placebo (treatment group T01), Versifel FeLV Vaccine (treatment group T02), or Purevax FeLV Vaccine (treatment group T03) according to the manufacturer's directions. Cats were challenged three weeks after the second vaccination with a virulent FeLV isolate (61E strain). Persistent FeLV antigenemia was determined from 3 to 15 weeks postchallenge. Bone marrow samples were tested for the presence of FeLV proviral DNA to determine FeLV latent infection. At week 15 after challenge with the virulent FeLV 61E strain, the Versifel FeLV Vaccine conferred 89.5% protection against FeLV persistent antigenemia and 94.7% protection against FeLV proviral DNA integration in bone marrow cells. In comparison, the Purevax FeLV Vaccine conferred 20% protection against FeLV persistent antigenemia and 35% protection against FeLV proviral DNA integration in bone marrow cells following challenge. The data from this study show that the Versifel FeLV Vaccine was efficacious in preventing both FeLV persistent p27 antigenemia and FeLV proviral DNA integration in bone marrow cells of cats challenged with this particular challenge model under laboratory conditions and provided better protection than Purevax FeLV in this experimental challenge model with highly virulent FeLV.

  20. [{sup 18}F]FE-SUPPY and [{sup 18}F]FE-SUPPY:2 - metabolic considerations

    Energy Technology Data Exchange (ETDEWEB)

    Haeusler, Daniela [Dept. of Nuclear Medicine, Medical Univ. of Vienna, A-1090 Vienna (Austria); Dept. of Pharmaceutical Technology and Biopharmaceutics, Univ. of Vienna, A-1090 Vienna (Austria); Nics, Lukas [Dept. of Nuclear Medicine, Medical Univ. of Vienna, A-1090 Vienna (Austria); Dept. of Nutritional Sciences, Univ. of Vienna, A-1090 Vienna (Austria); Mien, Leonhard-Key [Dept. of Nuclear Medicine, Medical Univ. of Vienna, A-1090 Vienna (Austria); Dept. of Pharmaceutical Technology and Biopharmaceutics, Univ. of Vienna, A-1090 Vienna (Austria); Ungersboeck, Johanna [Dept. of Nuclear Medicine, Medical Univ. of Vienna, A-1090 Vienna (Austria); Dept. of Inorganic Chemistry, Univ. of Vienna, A-1090 Vienna (Austria); Lanzenberger, Rupert R. [Dept. of Psychiatry and Psychotherapy, Medical Univ. of Vienna, A-1090 Vienna (Austria); Shanab, Karem [Dept. of Drug and Natural Product Synthesis, Univ. of Vienna, A-1090 Vienna (Austria); Sindelar, Karoline M. [Dept. of Nuclear Medicine, Medical Univ. of Vienna, A-1090 Vienna (Austria); Viernstein, Helmut [Dept. of Pharmaceutical Technology and Biopharmaceutics, Univ. of Vienna, A-1090 Vienna (Austria); Wagner, Karl-Heinz [Dept. of Nutritional Sciences, Univ. of Vienna, A-1090 Vienna (Austria); Dudczak, Robert; Kletter, Kurt [Dept. of Nuclear Medicine, Medical Univ. of Vienna, A-1090 Vienna (Austria); Wadsak, Wolfgang [Dept. of Nuclear Medicine, Medical Univ. of Vienna, A-1090 Vienna (Austria); Dept. of Inorganic Chemistry, Univ. of Vienna, A-1090 Vienna (Austria); Mitterhauser, Markus [Dept. of Nuclear Medicine, Medical Univ. of Vienna, A-1090 Vienna (Austria); Dept. of Pharmaceutical Technology and Biopharmaceutics, Univ. of Vienna, A-1090 Vienna (Austria); Hospital Pharmacy of the General Hospital of Vienna, A-1090 Vienna (Austria)], E-mail: markus.mitterhauser@meduniwien.ac.at

    2010-05-15

    Introduction: Recently, [{sup 18}F]FE-SUPPY and [{sup 18}F]FE-SUPPY:2 were introduced as the first positron emission tomography (PET) tracers for the adenosine A{sub 3} receptor. Thus, aim of the present study was the metabolic characterization of the two adenosine A{sub 3} receptor PET tracers. Methods: In vitro carboxylesterase (CES) experiments were conducted using incubation mixtures containing different concentrations of the two substrates, porcine CES and phosphate-buffered saline. Enzymatic reactions were stopped by adding acetonitrile/methanol (10:1) after various time points and analyzed by a high-performance liquid chromatography (HPLC) standard protocol. In vivo experiments were conducted in male wild-type rats; tracers were injected through a tail vein. Rats were sacrificed after various time points (n=3), and blood and brain samples were collected. Sample cleanup was performed by an HPLC standard protocol. Results: The rate of enzymatic hydrolysis by CES demonstrated Michaelis-Menten constants in a micromolar range (FE-SUPPY, 20.15 {mu}M, and FE-SUPPY:2, 13.11 {mu}M) and limiting velocities of 0.035 and 0.015 {mu}M/min for FE-SUPPY and FE-SUPPY:2, respectively. Degree of metabolism in blood showed the following: 15 min pi 47.7% of [{sup 18}F]FE-SUPPY was intact compared to 33.1% of [{sup 18}F]FE-SUPPY:2; 30 min pi 30.3% intact [{sup 18}F]FE-SUPPY was found compared to 15.6% [{sup 18}F]FE-SUPPY:2. In brain, [{sup 18}F]FE-SUPPY:2 formed an early hydrophilic metabolite, whereas metabolism of [{sup 18}F]FE-SUPPY was not observed before 30 min pi Conclusion: Knowing that metabolism in rats is several times faster than in human, we conclude that [{sup 18}F]FE-SUPPY should be stable for the typical time span of a clinical investigation. As a consequence, from a metabolic point of view, one would tend to decide in favor of [{sup 18}F]FE-SUPPY.

  1. Magneto Seebeck effect in Co-Fe-B/MgO/Co-Fe-B tunnel junctions

    Energy Technology Data Exchange (ETDEWEB)

    Walter, Marvin; Walowski, Jakob; Zbarsky, Vladyslav; Muenzenberg, Markus [I. Physikalisches Institut, Universitaet Goettingen (Germany); Drewello, Volker; Ebke, Daniel; Reiss, Guenter; Thomas, Andy [Department of Physics, Bielefeld University (Germany); Peretzki, Patrick; Seibt, Michael [IV. Physikalisches Institut, Universitaet Goettingen (Germany); Czerner, Michael; Bachmann, Michael; Heiliger, Christian [I. Physikalisches Institut, Universitaet Giessen (Germany)

    2011-07-01

    Co-Fe-B/MgO/Co-Fe-B devices showing a giant TMR effect are possible candidates for the generation of spin-currents by thermal heating. We present the observation of a magneto Seebeck effect in Co-Fe-B/MgO/Co-Fe-B magnetic tunnel junctions (MTJs). The effects could be used for thermal spin-injection and thermally driven spin-transfer torque. The samples presented in this work consist of a minimal pseudo-spin-valve stack with sputtered Ta and Co-Fe-B layers and an e-beam evaporated MgO barrier. The MTJs are heated by a diode laser which achieves powers of up to 100 mW and is focused onto the sample in a standard confocal microscope setup. The heating is simulated by finite element methods and the experimental results are compared with ab initio calculations of the magneto-thermoelectric power and of the spin-Seebeck coefficient.

  2. Highly Crystalline FeCO3 Microparticle Synthesis by Hydrothermal Decomposition of Fe-EDTA Complex

    Science.gov (United States)

    Chirita, M.; Banica, R.; Ieta, A.; Bucur, A.; Sfiarloaga, P.; Ursu, D. H.; Grozescu, I.

    2010-08-01

    In this article, we present an experimental procedure to synthesize highly crystalline FeCO3 by hydrothermal decomposition of Fe(III)-EDTA complex, starting from Ferric Ammonium Sulfate and Na4EDTA main precursors in urea presence. The structure, morphology and composition of the powders were obtained using X-ray powder diffraction and scanning electron microscopy. The peaks were founded, indicate that the synthesized products autoclaved 22 h at 250 °C are pure FeCO3, which was well proved experimentally from EDAX further investigated. The size with appreciatively 100 μm was evaluated by SEM images. Magnetic characterization confirmed the magnetic characteristics of FeCO3. This procedure allowed the FeCO3 microparticles formation with good and stabile crystallographic characteristics.

  3. Condutividade da Polianilina e Poliacrilonitrila Dopadas com Fe(II e Fe(III

    Directory of Open Access Journals (Sweden)

    Yonis Fornazier Filho

    2015-01-01

    Full Text Available In this work we report O estudo da interação de íons Fe(II com a polianilina foi feito através da obtenção deste polímero na forma de salthe studies on Polyaniline Emeraldine (PANI-ES and Polyacrilonitrile (PAN doped with salt of Fe (II and Fe(III. We used the techniques of conductivity measurements with aplicação de pressão.application of pressure.  The results showed that conductivity of PANI-ES increase with pressure of range of 1.73 MPa until 20.0 MPa and PAN also increase with maximum of 6.0 mPa except to samples PAN-2-TT-FeIII and PAN-2-TTAA-FeIII.

  4. Properties of porous FeAlO/FeAl ceramic matrix composite influenced by mechanical activation of FeAl powder

    Indian Academy of Sciences (India)

    V Usoltsev; S Tikhov; A Salanov; V Sadykov; G Golubkova; O Lomovskii

    2013-12-01

    Porous ceramic matrix composites FeAlO/FeAl with incorporated metal inclusions (cermets) were synthesized by pressureless method, which includes hydrothermal treatment of mechanically alloyed FeAl powder followed by calcination. Their main structural, textural and mechanical features are described. Variation of FeAl powder alloying time results in non-monotonous changes of the porosity and mechanical strength. Details of the cermet microstructure and its relation to the mechanical properties are discussed.

  5. Chemical consequences of the nuclear reactions 58Fe(n,γ)59Fe and 57Co(EC)57Fe in soluble Prussian Blue

    DEFF Research Database (Denmark)

    Fenger, Jes; Maddock, A. G.; Siekierska, K. E.

    1970-01-01

    KFe[Fe(CN)6],H2O was prepared with 58Fe in either the cation or the complex, and both samples were neutron-irradiated and analysed for free and complexed 59Fe. Parallel experiments were performed on K4[Fe(CN)6],3H2O. In Prussian Blue the retention in the hexacyano-complex is ca. 5% and can be inc...

  6. Synthesis of magnetically exchange coupled SrFe12O19/FeCo composites through cryogenic ball milling

    Science.gov (United States)

    Pang, Ning; Ye, Feng; Jiang, Ying

    2017-07-01

    SrFe12O19/FeCo composite particles with different mass ratios of SrFe12O19 to FeCo were synthesized through a cryogenic ball milling process. The corresponding products were characterized with scanning electron microscopy (SED), transmission electron microscopy (TEM), x-ray diffraction (XRD) and vibrating sample magnetometer (VSM) for crystal morphology, elemental distribution, crystal phases, and magnetic properties. The results showed that when the mass percentage of FeCo was less than 15%, smooth magnetic hysteresis loops could be obtained from SrFe12O19/FeCo composite particles, indicating effective magnetic exchange coupling between the SrFe12O19 and FeCo particles. A further FeCo mass increase resulted in kinks in the magnetic hysteresis loop and destroyed the magnetic exchange coupling. As a comparison, room temperature ball milling of SrFe12O19/FeCo (95/5 wt%) cannot achieve magnetic exchange coupling between SrFe12O19 and FeCo due to FeCo nanoparticle agglomeration.

  7. Identification of a Catalytic Iron-Hydride at the H-Cluster of [FeFe]-Hydrogenase

    Energy Technology Data Exchange (ETDEWEB)

    Mulder, David W.; Guo, Yisong; Ratzloff, Michael W.; King, Paul W.

    2017-01-11

    Hydrogenases couple electrochemical potential to the reversible chemical transformation of H2 and protons, yet the reaction mechanism and composition of intermediates are not fully understood. In this Communication we describe the biophysical properties of a hydride-bound state (Hhyd) of the [FeFe]-hydrogenase from Chlamydomonas reinhardtii. The catalytic H-cluster of [FeFe]-hydrogenase consists of a [4Fe-4S] subcluster ([4Fe-4S]H) linked by a cysteine thiol to an azadithiolate-bridged 2Fe subcluster ([2Fe]H) with CO and CN- ligands. Mossbauer analysis and density functional theory (DFT) calculations show that Hhyd consists of a reduced [4Fe-4S]H+ coupled to a diferrous [2Fe]H with a terminally bound Fe-hydride. The existence of the Fe-hydride in Hhyd was demonstrated by an unusually low Mossbauer isomer shift of the distal Fe of the [2Fe]H subcluster. A DFT model of Hhyd shows that the Fe-hydride is part of a H-bonding network with the nearby bridging azadithiolate to facilitate fast proton exchange and catalytic turnover.

  8. Perpendicular Magnetic Anisotropy and High Spin Polarization in Tetragonal Fe4N /BiFeO3 Heterostructures

    Science.gov (United States)

    Yin, Li; Mi, Wenbo; Wang, Xiaocha

    2016-12-01

    The tetragonal Fe4N /BiFeO3(001 ) heterostructures aimed at simultaneously gaining the perpendicular magnetic anisotropy (PMA) and high spin polarization have been investigated by the first-principles method. It is found that Fe4N with FeAFeB termination is better for achieving interfacial and inner PMA simultaneously than (FeB)2N termination. When the positions of interfacial FeA and FeB relative to Fe in BiFeO3 are changed, the PMA in Fe4N transforms into the in-plane magnetic anisotropy. Especially, PMA in Fe4N near the heterointerfaces depends on the direction of ferroelectric polarization in BiFeO3 . Finally, the interfacial and inner PMA of Fe4N along with high spin polarization appear in the stable FeAFeB/Fe -O2 case owing to the 3 d -3 d orbital hybridization. These results provide the opportunities for developing multifunctional spintronic devices.

  9. Fabrication and physical properties of [Fe/Fe4N]N multilayers with high saturation magnetization

    Directory of Open Access Journals (Sweden)

    B. Yu

    2016-05-01

    Full Text Available [Fe/Fe4N]N multilayers with high saturation magnetization were prepared on MgO(200 substrate, by the DC reactive magnetron sputtering and then annealed at higher temperature. Their structural and magnetic properties were investigated. Epitaxial growth of α-Fe and γ’-Fe4N were demonstrated on MgO, and then excellent [Fe/Fe4N]N was obtained. Though the saturation magnetizations of the as-deposited [Fe/Fe4N]N are slightly below the average value of those of α-Fe and γ’-Fe4N, the saturation magnetization of the annealed [Fe(3.04 nm/Fe4N(3.04 nm]5 increases up to 1850 emu/cc, 32 % larger than that of α-Fe film. N atom diffusion from the γ’-Fe4N to the α-Fe layer at high temperature greatly improves the saturation magnetization.

  10. FeGa/BTO/FeGa层状复合结构中的磁电效应%Magnetoelectric effect in laminate composites FeGa/BTO/FeGa

    Institute of Scientific and Technical Information of China (English)

    王蕾; 杜兆富; 范崇飞; 徐立红; 张洪平; 赵栋梁

    2011-01-01

    After prepared in argon by induction melting, polycrystal FeGa alloy rods were prepared in directionalsolidification furnace. Magnetostrictive behabior has been measured by using standard strain gauges. Layered composites FeGa/BTO/FeGa were fabricated by bonding the discs of the BaTiO3 and FeGa. The magnetoelectric (ME) effect have been characterized for the transversely magnetized and transversely polarized transversetransverse (T-T) mode. Near the natural resonant frequency (ca. 95 kHz) of laminate, the ME effect were found to be dramatically increased,7-10 larger than the properties in low frequency. The ME voltage varied evidently with magnetic bias and there existed an optimized magnetic bias 5.97×104A/m, due to the change of FeGa piezomagnetic coefficient q with the bias field. A linear coupling between the measured ME coefficient and Hac for laminate was observed for various magnetic biases. In addition, higher magnetoelectric coefficient can be obtained by decreasing thickness of the BTO layer.%采用区域熔炼法制备了FeGa磁致伸缩材料并测量了其磁致伸缩性能.利用该材料制备了FeGa/BTO/FeGa层状复合结构,并对该样品的磁电性能进行了系统研究.结果表明,该材料在共振频率95kHz下,磁电性能高于低频下性能7~10倍.磁电电压随直流偏磁场的变化发生明显变化,出现5.97×104A/m的优化偏置场,这主要是由FeGa层的压磁系数q随偏磁场的变化所致.3层复合材料的磁电系数与交流驱动场变化呈线性关系.另外,较薄的BTO压电层可以提高压应力,从而获得较高的磁电性能.

  11. High Magnetization FeCo/Pd multilayers

    Science.gov (United States)

    Walock, Michael; Klose, Frank; Chshiev, Mairbek; Mankey, Gary; Butler, William

    2007-03-01

    A high saturation magnetization is advantageous in magnetic recording. Currently, the peak of the Slater-Pauling curve is the BCC FeCo system with a saturation magnetization of 2.45 T. Recently, a magnetization of 2.57 T in the FeCo layers of a [40 nm Fe30Co70 /1.7 nm Pd]x25 superlattice has been reported [1, 2]. This behavior may be attributed to an enhanced Fe moment in the expanded FCC matrix, and an accompanying induced moment in the Pd. Our theoretical calculations show an atomic moment enhancement, but this is not great enough to overcome the overall magnetization density reduction caused by the incorporation of Pd in the matrix. The overall effect is a reduced magnetization. Through variation of the FeCo composition and Pd layer thickness, and the combinatorial methods of structural and magnetic characterization, we will gain insight into the magnetic structure of this tertiary thin film system. [1] K. Noma, M. Matsuoka, H. Kanai, Y. Uehara, K. Nomura, and N. Awaji. IEEE Trans. Magn. 42, 140 (2006). [2] ibid. 41, 2920 (2005).

  12. Electronic structure in a one-Fe Brillouin zone of the iron pnictide superconductors CsFe2As2 and RbFe2As2

    Science.gov (United States)

    Kong, S.; Liu, D. Y.; Cui, S. T.; Ju, S. L.; Wang, A. F.; Luo, X. G.; Zou, L. J.; Chen, X. H.; Zhang, G. B.; Sun, Z.

    2015-11-01

    Using angle-resolved photoemission spectroscopy, we studied the electronic structures of CsFe2As2 and RbFe2As2 . Contrary to other iron-based superconductors where the band structures are usually depicted in the two-Fe Brillouin zone (BZ), we found that the distribution of electronic spectral weight in CsFe2As2 and RbFe2As2 follows the one-Fe BZ, and that the emerging band structure is qualitatively consistent with theoretical band calculations of the one-Fe BZ except for some shadow band effect. Our data suggest that the interlayer separation is an important tuning factor for the physics of FeAs layers, the increase of which can reduce the coupling between Fe and As and lead to the emergence of the electronic structure in accord with the one-Fe symmetry of the Fe square lattice. Our finding puts strong constraints on the theoretical models constructed on the basis of the one-Fe BZ.

  13. Exchange-coupled fct-FePd/α-Fe nanocomposite magnets converted from Pd/Fe3O4 core/shell nanoparticles.

    Science.gov (United States)

    Liu, Fei; Dong, Yunhe; Yang, Wenlong; Yu, Jing; Xu, Zhichuan; Hou, Yanglong

    2014-11-10

    We report the controlled synthesis of exchange-coupled face-centered tetragonal (fct) FePd/α-Fe nanocomposite magnets with variable Fe concentration. The composite was converted from Pd/Fe3O4 core/shell nanoparticles through a high-temperature annealing process in a reducing atmosphere. The shell thickness of core/shell Pd/Fe3O4 nanoparticles could be readily tuned, and subsequently the concentration of Fe in nanocomposite magnets was controlled. Upon annealing reduction, the hard magnetic fct-FePd phase was formed by the interdiffusion between reduced α-Fe and face-centered cubic (fcc) Pd, whereas the excessive α-Fe remained around the fct-FePd grains, realizing exchange coupling between the soft magnetic α-Fe and hard magnetic fct-FePd phases. Magnetic measurements showed variation in the magnetic properties of the nanocomposite magnets with different compositions, indicating distinct exchange coupling at the interfaces. The coercivity of the exchange-coupled nanocomposites could be tuned from 0.7 to 2.8 kOe and the saturation magnetization could be controlled from 93 to 160 emu g(-1). This work provides a bottom-up approach using exchange-coupled nanocomposites for engineering advanced permanent magnets with controllable magnetic properties.

  14. Inulin affects iron dialyzability from FeSO4 and FeEDTA solutions but does not alter Fe uptake by Caco-2 cells

    Science.gov (United States)

    The in vitro effects of inulin on the fluxes of Fe (FFe), uptake by Caco-2 cells from FeSO4 and FeEDTA which are commonly used for food fortification, were evaluated. For an element to be absorbed it is necessary that it should be soluble in the gastrointestinal tract, thus, changes in FFe diffussio...

  15. Diffusion mechanisms in the Fe3Si alloys

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    In this paper, the possible reasons for the high thermal vacancy concentration and the low migration barriers for the Fe atom diffusion in the stoichiometric D03 structure Fe3Si have been discussed. The high thermal vacancy concentration was attributed to the compression of Fe-Fe atomic pairs and the tension of Fe-Si atomic pairs in Fe75Si25. The deformations (compression or tension) of the atompairs increase the interatomic potentials and thus decrease the enthalpies of vacancy formation. The low migration barriers for the Fe atom diffusion in Fe75Si25 were related to the symmetric property of the triangular barriers. Additionally, it was considered that the Si atoms in Fe3Si could probably migrate via nearest-neighbour jumps without disturbing the long-range order of atomic arrangements, provided that during the diffusion process the residence time on the antistructure sites is very short.

  16. Kinetics of Fe3O4 formation by air oxidation

    Institute of Scientific and Technical Information of China (English)

    杨喜云; 龚竹青; 刘丰良

    2004-01-01

    The kinetics of Fe3O4 formation by air oxidation of slightly acidic suspension of Fe(OH)2 was studied. The effects of initial concentration of Fe(Ⅱ), temperature, partial pressure of oxygen, air flow rate and stirring rate on the oxidation rate were investigated. The results show that Fe3O4 formation is composed of two-step reaction, the first step is the formation of Fe(OH)+2 by oxidation of Fe(OH)+ complex ions, the second step is the formation of magnetite by dehydration and deprotonation of Fe(OH)+ and Fe(OH)+2. The oxidation reaction is zero-order with respect to the concentration of Fe(Ⅱ) and around 0.5-order with respect to partial pressure of oxygen, and oxygen transfer process is rate-limiting step of oxidation reaction with apparent activation energy of 2.74 kJ·mol-1.

  17. Phase relations in the Fe-Fe3C-Fe3N system at 7.8 GPa and 1350 °C: Implications for carbon and nitrogen hosts in Fe0-saturated upper mantle

    Science.gov (United States)

    Sokol, Alexander G.; Kruk, Alexey N.; Seryotkin, Yurii V.; Korablin, Alexander A.; Palyanov, Yury N.

    2017-04-01

    Phase relations in the Fe-Fe3C-Fe3N system are studied in high-pressure experiments at 7.8 GPa and 1350 °C using a split-sphere multi-anvil apparatus. The starting mixtures consisting of Fe, Fe3C and Fe3N are loaded into ceramic or graphite capsules. Contamination with trace amounts of oxygen leads to the appearance of wüstite in the system retaining oxygen fugacity (fO2) near the iron-wüstite (IW) buffer. The metal melt rich in carbon and nitrogen has a large stability field in the central part of the phase diagram, and this field at 1350 °C is tangent to the Fe-Fe3C side of the Fe-Fe3C-Fe3N triangle at the point of the Fe-Fe3C eutectics. Iron nitride ε-Fe3N (space group P6322 or P63/mmc) contains variable amounts of C and N: up to 2.0-2.5 wt% C and 6.0-7.3 wt% N in equilibrium with a C- and N-rich melt and as little as 1.0 wt% C and 3.2 wt% N in equilibrium with γ- Fe. The limit C and N contents in γ-Fe equilibrated with the C- and N-rich melt is about 1.0 wt%, while the N solubility in cementite (Fe3C) does not exceed 0.5 wt%. The obtained data make basis for the isothermal section of the Fe-Fe3C-Fe3N system. The metal melt phase is inferred to be the main host of carbon and nitrogen in the Fe0-saturated (0.1 wt%) mantle at a depth of ∼250 km. In particular, C- and N-bearing austenite (γ-Fe) and metal melts host carbon and nitrogen in the mantle depleted in volatiles (20 ppm C and 1 ppm N), whereas carbon and nitrogen in the mantle with high concentrations of volatiles (250 ppm C and 100 ppm N) reside in C- and N-rich melts with a minor amount of iron carbide (Fe3C). The presence of nickel and sulphur in metal are expected to inhibit the formation of iron carbide and increases the melt phase stability. Redox freezing of N-rich carbonate melts from subduction slabs in Fe0-saturated mantle may produce iron melts supersaturated with nitrogen and stable ε-Fe3N.

  18. Hydrogenation of nanocrystalline Zr-Fe-H powder

    Energy Technology Data Exchange (ETDEWEB)

    Roupcova, P. [Institute of Materials Engineering, Brno University of Technology, Technicka 2, 616 69 Brno (Czech Republic) and Institute of Physics of Materials, AS CR, Zizkova 22, 616 62 Brno (Czech Republic)]. E-mail: roupcova@ipm.cz; Schneeweiss, O. [Institute of Physics of Materials, AS CR, Zizkova 22, 616 62 Brno (Czech Republic); Zhu, M. [Department of Mechano-Electrical Engineering, South China University of Technology, Guangzhou, 510640 Guangdong (China)

    2005-12-08

    Changes in the phase composition of nanocrystalline Zr-Fe powders prepared by spark synthesis were investigated in dependence of the heat treatment in vacuum and hydrogen atmosphere. Mossbauer spectroscopy, X-ray diffraction and magnetic measurements were applied for phase analysis. {alpha}-Fe, Fe embedded in ZrO{sub 2}, ZrO{sub 2}, and iron oxides were found in the as-prepared powder. After annealing in hydrogen, {alpha}-Fe and ZrO{sub 2} dominate and minor Fe atoms embedded in ZrO{sub 2} and Fe{sub 2}Zr were detected. Zr-Fe phases were transformed gradually into the {alpha}-Fe and ZrO{sub 2} during the repeated annealing in vacuum and hydrogen. The ability of hydrogen absorption is decreasing with the annealing steps and is connected with the decrease of the Fe{sub 2}Zr phase content.

  19. Sulphur deprivation limits Fe-deficiency responses in tomato plants.

    Science.gov (United States)

    Zuchi, Sabrina; Cesco, Stefano; Varanini, Zeno; Pinton, Roberto; Astolfi, Stefania

    2009-06-01

    The aim of this work was to clarify the role of S supply in the development of the response to Fe depletion in Strategy I plants. In S-sufficient plants, Fe-deficiency caused an increase in the Fe(III)-chelate reductase activity, 59Fe uptake rate and ethylene production at root level. This response was associated with increased expression of LeFRO1 [Fe(III)-chelate reductase] and LeIRT1 (Fe2+ transporter) genes. Instead, when S-deficient plants were transferred to a Fe-free solution, no induction of Fe(III)-chelate reductase activity and ethylene production was observed. The same held true for LeFRO1 gene expression, while the increase in 59Fe2+ uptake rate and LeIRT1 gene over-expression were limited. Sulphur deficiency caused a decrease in total sulphur and thiol content; a concomitant increase in 35SO4(2-) uptake rate was observed, this behaviour being particularly evident in Fe-deficient plants. Sulphur deficiency also virtually abolished expression of the nicotianamine synthase gene (LeNAS), independently of the Fe growth conditions. Sulphur deficiency alone also caused a decrease in Fe content in tomato leaves and an increase in root ethylene production; however, these events were not associated with either increased Fe(III)-chelate reductase activity, higher rates of 59Fe uptake or over-expression of either LeFRO1 or LeIRT1 genes. Results show that S deficiency could limit the capacity of tomato plants to cope with Fe-shortage by preventing the induction of the Fe(III)-chelate reductase and limiting the activity and expression of the Fe2+ transporter. Furthermore, the results support the idea that ethylene alone cannot trigger specific Fe-deficiency physiological responses in a Strategy I plant, such as tomato.

  20. Atomic model of liquid pure Fe

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Using a θ-θX-ray diffractometer, the liquid structure of pure Fewas investigated and the diffraction intensity, structure factor, pair distribution function as well as the coordination number and atomic distance were obtained. The experimental results showed that there was also a pre-peak on the curve of the structure factor of liquid pure Fe. The pre-peak is a mark of medium-range order in melts. According to the characteristics of pre-peak, an atomic model of liquid pure Fe is constructed, namely, the structure of liquid pure Fe is a combination of clusters consisting of bcc cells with shared vertexes and other atoms with random dense atom distribution.

  1. Magnetostatic Interaction in Fe-Co Nanowires

    Directory of Open Access Journals (Sweden)

    Laura Elbaile

    2012-01-01

    Full Text Available Arrays of Fe-Co alloy nanowires with diameter around 35 nm and several micrometers in length have been synthesized by codepositing Fe and Co into porous anodic alumina. The morphology, structure, and magnetic properties of the nanowires (hysteresis loops and remanence curves were characterized by SEM, TEM, X-ray diffraction (XRD, and VSM, respectively. The XRD patterns indicate that the Fe-Co nanowires present a body-centered cubic (bcc structure and a preferred (110 orientation perpendicular to the template surface. From the hysteresis loops obtained with the magnetic field applied in the axis direction of the nanowires, we can observe that the coercive field slightly decreases when the nanowire length increases. This magnetic behaviour is analyzed considering the shape anisotropy and the dipolar interactions among nanowires.

  2. Catalytic Methane Decomposition over Fe-Al2O3

    KAUST Repository

    Zhou, Lu

    2016-05-09

    The presence of a Fe-FeAl2O4 structure over an Fe-Al2O3 catalysts is demonstrated to be vital for the catalytic methane decomposition (CMD) activity. After H2 reduction at 750°C, Fe-Al2O3 prepared by means of a fusion method, containing 86.5wt% FeAl2O4 and 13.5wt% Fe0, showed a stable CMD activity at 750°C for as long as 10h. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  3. Magnetic interaction in oxygenated alpha Fe-phthalocyanines

    Energy Technology Data Exchange (ETDEWEB)

    Kuzmann, Ernő, E-mail: kuzmann@caesar.elte.hu; Homonnay, Zoltán; Horváth, Attila [Institute of Chemistry, Eötvös Loránd University, P.O. Box 32, 1512 Budapest (Hungary); Pechousek, Jiri; Cuda, Jan; Machala, Libor; Zoppellaro, Giorgio; Zboril, Radek [Regional Centre of Advanced Technologies and Materials, Departments of Experimental Physics and Physical Chemistry, Faculty of Science Palacky University, 17. Listopadu 1192/12, 771 46 Olomouc (Czech Republic); Yin, Houping; Wei, Yen [Department of Chemistry, Drexel University, Philadelphia, PA 19104 (United States); Klencsár, Zoltán [Research Centre for Natural Sciences, Hungarian Academy of Sciences, Budapest, 1117 (Hungary); Kubuki, Shiro [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachi-Oji, Tokyo 192-0397 (Japan); Nath, Amar [Department of Chemistry, University of North Carolina, Asheville, NC 28804 (United States)

    2014-10-27

    Alpha iron phthalocyanines (α-FePc) oxygenated at low temperatures were investigated with the help of {sup 57}Fe Mössbauer spectroscopy, magnetization measurements (SQUID) and X-ray diffractometry (XRD). Mössbauer spectroscopy revealed that upon oxygenation of α-FePc, new species were formed which could be associated with Fe{sup III}Pc oxygen adducts. Unexpectedly, magnetically split spectrum of oxygenated α-FePc was observed below 20 K. In-field Mössbauer spectra in a 5 T external magnetic field at 5K and magnetization measurements indicate antiferromagnetic coupling in oxygenated α-FePc.

  4. Evidence for weak electronic correlations in Fe-pnictides

    Energy Technology Data Exchange (ETDEWEB)

    Yang, W.L.

    2010-04-29

    Using x-ray absorption and resonant inelastic x-ray scattering, charge dynamics at and near the Fe L edges is investigated in Fe pnictide materials, and contrasted to that measured in other Fe compounds. It is shown that the XAS and RIXS spectra for 122 and 1111 Fe pnictides are each qualitatively similar to Fe metal. Cluster diagonalization, multiplet, and density-functional calculations show that Coulomb correlations are much smaller than in the cuprates, highlighting the role of Fe metallicity and strong covalency in these materials. Best agreement with experiment is obtained using Hubbard parameters U {approx}< 2eV and J {approx} 0.8eV.

  5. Evidence for weak electronic correlations in Fe-Pnictides

    Energy Technology Data Exchange (ETDEWEB)

    Yang, W. L.; Sorini, A. P.; Chen, C-C.; Moritz, B.; Lee, W.-S.; Vernay, F.; Olalde-Velasco, P.; Denlinger, J. D.; Delley, B.; Chu, J.-H.; Analytis, J.G.; Fisher, I. R.; Ren, Z. A.; Yang, J.; Lu, W.; Zhao, Z. X.; van den Brink, J.; Hussain, Z.; Shen, Z.-X.; Devereaux, T. P.

    2009-06-11

    Using x-ray absorption and resonant inelastic x-ray scattering, charge dynamics at and near the Fe L edges is investigated in Fe pnictide materials, and contrasted tothat measured in other Fe compounds. It is shown that the XAS and RIXS spectra for 122 and 1111 Fe pnictides are each qualitatively similar to Fe metal. Cluster diagonalization, multiplet, and density-functional calculations show that Coulomb correlations are much smaller than in the cuprates, highlighting the role of Fe metallicity and strong covalency in these materials. Best agreement with experiment is obtained using Hubbard parameters U<~;; 2eV and J ~;; 0.8eV.

  6. Low hysteresis FeMn-based top spin valve.

    Science.gov (United States)

    Ustinov, V V; Krinitsina, T P; Milyaev, M A; Naumova, L I; Proglyado, V V

    2012-09-01

    FeMn-based top spin valves Ta/[FeNi/CoFe]/Cu/CoFe/FeMn/Ta with different Cu and FeMn layers thicknesses were prepared by DC magnetron sputtering at room temperature. It was shown that low field hysteresis due to free layer magnetization reversal can be reduced down to (0.1 divided by 0.2) Oe keeping the GMR ratio higher 8% by using both layers thicknesses optimization and non-collinear geometry of magnetoresistance measurements. Dependence of low field hysteresis and GMR ratio on the angle between applied magnetic field and pinning direction are presented.

  7. Comp ositionally Graded Microstructure for Ag-Fe Nanoparticles

    Institute of Scientific and Technical Information of China (English)

    Chandan Srivastava∗; K. V. L. Sushma

    2012-01-01

    Ag-Fe nanoparticles with a highly Ag rich average composition were synthesized by the sono-chemical route. Silver-iron system exhibits a wide miscibility gap in the bulk materials. Interestingly, a graded compositional profile along the nanoparticle radius was observed. Regions at and near the surface of the nanoparticle contained both Ag and Fe atoms. The composition got relatively deficient Fe towards the center of the particle with particle core made up of pure Ag. Alloying of Ag and Fe is confirmed by the absence of diffraction signal corresponding to pure Fe phase and presence of a paramagnetic phase in nanoparticles containing a diamagnetic (Ag) and ferromagnetic (Fe) elements.

  8. Nb and Fe K-edges XAFS study on the structure of supported Fe-NbN catalysts

    Science.gov (United States)

    Ichikuni, N.; Wakai, Y.; Hara, T.; Shimazu, S.

    2009-11-01

    SiO2-Supported Fe-NbN catalysts were prepared by temperature programmed reaction (TPR) method from Fe-Nb/SiO2 oxide precursor under a N2-H2 gas stream. As raising the intermediate temperature-maintaining (ITM) step temperature during the TPR, Fe species in the Fe-Nb/SiO2 catalyst was reduced to zero-valent, confirmed by Fe K-edge XAFS analysis. Although the Fe-Fe coordination number increased by elevating ITM temperature, the size of Fe cluster was still small. The Nb-N coordination number became larger, as higher the ITM temperature. The reduced Fe species effectively assisted the nitridation process of Nb.

  9. Oxidation of Fe(II)-EDTA by nitrite and by two nitrate-reducing Fe(II)-oxidizing Acidovorax strains.

    Science.gov (United States)

    Klueglein, N; Picardal, F; Zedda, M; Zwiener, C; Kappler, A

    2015-03-01

    The enzymatic oxidation of Fe(II) by nitrate-reducing bacteria was first suggested about two decades ago. It has since been found that most strains are mixotrophic and need an additional organic co-substrate for complete and prolonged Fe(II) oxidation. Research during the last few years has tried to determine to what extent the observed Fe(II) oxidation is driven enzymatically, or abiotically by nitrite produced during heterotrophic denitrification. A recent study reported that nitrite was not able to oxidize Fe(II)-EDTA abiotically, but the addition of the mixotrophic nitrate-reducing Fe(II)-oxidizer, Acidovorax sp. strain 2AN, led to Fe(II) oxidation (Chakraborty & Picardal, 2013). This, along with other results of that study, was used to argue that Fe(II) oxidation in strain 2AN was enzymatically catalyzed. However, the absence of abiotic Fe(II)-EDTA oxidation by nitrite reported in that study contrasts with previously published data. We have repeated the abiotic and biotic experiments and observed rapid abiotic oxidation of Fe(II)-EDTA by nitrite, resulting in the formation of Fe(III)-EDTA and the green Fe(II)-EDTA-NO complex. Additionally, we found that cultivating the Acidovorax strains BoFeN1 and 2AN with 10 mM nitrate, 5 mm acetate, and approximately 10 mM Fe(II)-EDTA resulted only in incomplete Fe(II)-EDTA oxidation of 47-71%. Cultures of strain BoFeN1 turned green (due to the presence of Fe(II)-EDTA-NO) and the green color persisted over the course of the experiments, whereas strain 2AN was able to further oxidize the Fe(II)-EDTA-NO complex. Our work shows that the two used Acidovorax strains behave very differently in their ability to deal with toxic effects of Fe-EDTA species and the further reduction of the Fe(II)-EDTA-NO nitrosyl complex. Although the enzymatic oxidation of Fe(II) cannot be ruled out, this study underlines the importance of nitrite in nitrate-reducing Fe(II)- and Fe(II)-EDTA-oxidizing cultures and demonstrates that Fe(II)-EDTA cannot

  10. Electrodeposition of Fe powder from acid electrolytes

    Directory of Open Access Journals (Sweden)

    VESNA M. MAKSIMOVIC

    2008-08-01

    Full Text Available Polarization characteristics of the electrodeposition processes of Fe powders from sulfate and chloride electrolytes and the morphology of the obtained powders were investigated. The morphology depended on the anion presence in the electrolyte but not on the current density in the investigated range. A characteristic feature of the dendritic powder with cauliflower endings obtained from sulfate electrolyte is the presence of cone-like cavities and the crystallite morphology of the powders surface. On the other hand, Fe powders electrodeposited from chloride electrolyte appear in the form of agglomerates. A soap solution treatment applied as a method of washing and drying provides good protection from oxidation of the powders.

  11. Tyrosine, cysteine, and S-adenosyl methionine stimulate in vitro [FeFe] hydrogenase activation.

    Directory of Open Access Journals (Sweden)

    Jon M Kuchenreuther

    Full Text Available BACKGROUND: [FeFe] hydrogenases are metalloenzymes involved in the anaerobic metabolism of H(2. These proteins are distinguished by an active site cofactor known as the H-cluster. This unique [6Fe-6S] complex contains multiple non-protein moieties and requires several maturation enzymes for its assembly. The pathways and biochemical precursors for H-cluster biosynthesis have yet to be elucidated. PRINCIPAL FINDINGS: We report an in vitro maturation system in which, for the first time, chemical additives enhance [FeFe] hydrogenase activation, thus signifying in situ H-cluster biosynthesis. The maturation system is comprised of purified hydrogenase apoprotein; a dialyzed Escherichia coli cell lysate containing heterologous HydE, HydF, and HydG maturases; and exogenous small molecules. Following anaerobic incubation of the Chlamydomonas reinhardtii HydA1 apohydrogenase with S-adenosyl methionine (SAM, cysteine, tyrosine, iron, sulfide, and the non-purified maturases, hydrogenase activity increased 5-fold relative to incubations without the exogenous substrates. No conditions were identified in which addition of guanosine triphosphate (GTP improved hydrogenase maturation. SIGNIFICANCE: The in vitro system allows for direct investigation of [FeFe] hydrogenase activation. This work also provides a foundation for studying the biosynthetic mechanisms of H-cluster biosynthesis using solely purified enzymes and chemical additives.

  12. Theoretical simulations of emission spectra of Fe7+ and Fe8+

    Institute of Scientific and Technical Information of China (English)

    Zeng Jiao-Long; Wang Yan-Gui; Zhao Gang; Yuan Jian-Min

    2006-01-01

    The energy levels, oscillator strengths, spontaneous radiative decay rates, and electron impact collision strengths are calculated for Fe Ⅷ and Fe Ⅸ using the recently developed flexible atomic code (FA3. These atomic data are used to analyse the emission spectra of both laboratory and astrophysical plasmas. The nf-3d emission lines have been simulated for Fe Ⅷ and Fe Ⅸ in a wavelength range of 6-14 nm. For Fe Ⅷ, the predicted relative intensities of lines are insensitive to temperature. For Fe Ⅸ, however, the intensity ratios are very sensitive to temperature, implying that the information of temperature in the experiment can be inferred. Detailed line analyses have also been carried out in a wavelength range of 60-80 nm for Fe Ⅷ, where the solar ultraviolet measurements of emitted radiation spectrometer records a large number of spectra. More lines can be identified with the aid of present atomic data. A complete dataset is available electronically from http://www.astrnomy.csdb.cn/EIE/.

  13. Mössbauer investigations of Fe and Fe3O4 magnetic nanoparticles for hyperthermia applications

    Science.gov (United States)

    Kamzin, A. S.

    2016-03-01

    Magnetic nanoparticles of magnetite Fe3O4 and Fe synthesized by physical vapor deposition with a fast highly effective method using a solar energy have been studied. Targets have been prepared from tablets pressed from Fe3O4 or Fe powders. Relationships between the structure of nanoparticles and their magnetic properties have been investigated in order to understand principles of the control of the parameters of magnetic nanoparticles. Mössbauer investigations have revealed that the nanoparticles synthesized from tablets of both pure iron and Fe3O4 consist of two phases: pure iron and iron oxides (γ-Fe2O3 and Fe3O4). The high iron oxidability suggests that the synthesized nanoparticles have a core/shell structure, where the core is pure iron and the shell is an oxidized iron layer. Magnetite nanoparticles synthesized at a pressure of 80 Torr have the best parameters for hyperthermia due to their core/shell structure and core-to-shell volume ratio.

  14. Explosive consolidation of Sm-Fe-N and Sm-Fe-N/(Ni, Co) magnetic powders

    Energy Technology Data Exchange (ETDEWEB)

    Chiba, A. [Faculty of Engineering, Kumamoto University, Kumamoto, Kumamoto 860-8555 (Japan)]. E-mail: chiba@gpo.kumamoto-u.ac.jp; Hokamoto, K. [Shock Wave and Condensed Matter Research Center, Kumamoto University, Kumamoto, Kumamoto 860-8555 (Japan); Sugimoto, S. [Graduate School of Engineering, Tohoku University, Sendai, Miyagi, 980-0845 (Japan); Kozuka, T. [Faculty of Engineering, Kumamoto University, Kumamoto, Kumamoto 860-8555 (Japan); Mori, A. [Shock Wave and Condensed Matter Research Center, Kumamoto University, Kumamoto, Kumamoto 860-8555 (Japan); Kakimoto, E. [Explosive R and D Center, Explosive Division, Asahi Kasei Co., 5447 Yamane, Chikushino-City, Fukuoka 813-0003 (Japan)

    2007-03-15

    Explosive consolidation of Sm{sub 2}Fe{sub 17}N{sub x} and Sm{sub 2}Fe{sub 17}N{sub x}/(Ni or Co) magnetic powders were attempted to consolidate fully dense magnetic compacts. Dense Sm{sub 2}Fe{sub 17}N{sub x} and Sm{sub 2}Fe{sub 17}N{sub x}/(Ni or Co) bulk materials were obtained by cylindrical explosive consolidation technique using water as a pressure transmitting medium. The values of (BH){sub max} of Sm{sub 2}Fe{sub 17}N{sub x}, Sm{sub 2}Fe{sub 17}N{sub x}-5wt%Ni and Sm{sub 2}Fe{sub 17}N{sub x}-30wt%Co magnets obtained were 23.8, 16.3 and 17.5MGOe (190, 130 and 140kJ/m{sup 3}), respectively.

  15. Ion-irradiation induced chemical ordering of FePt and FePtAu nanoparticles

    Science.gov (United States)

    Seetala, Naidu V.; Harrell, J. W.; Lawson, Jeremy; Nikles, David E.; Williams, John R.; Isaacs-Smith, Tamara

    2005-12-01

    We have studied the effect of ion-beam irradiation on reducing the ordering temperature of FePt and FePtAu nanoparticles. FePt and FePt(Au14%) 4 nm particles dispersed on a Si-substrate were irradiated by 300 keV Al-ions with a dose of 1 × 1016 ions/cm2 at 43 °C using a water-cooled flange in order to minimize the vacancy migration and voids formation within the collision cascades. Partial chemical ordering has been observed in as-irradiated particles with coercivity of 60-130 Oe. Post-irradiation annealing at 220 °C enhanced chemical ordering in FePt nanoparticles with coercivity of 3500 Oe, magnetic anisotropy of 1.5 × 107 erg/cc, and thermal stability factor of 130. A much higher 375 °C post-irradiation annealing was required in FePtAu, presumably because Au atoms were trapped at Fe/Pt lattice sites at lower temperatures. As the annealing temperature increased, anomalous features in the magnetization reversal curves were observed that disappeared at higher annealing temperatures.

  16. Ion-irradiation induced chemical ordering of FePt and FePtAu nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Seetala, Naidu V. [Department of Physics, Grambling State University, RWE Jones Drive, Carver Hall 81, Grambling, LA 71245 (United States)]. E-mail: naidusv@gram.edu; Harrell, J.W. [MINT Center, University of Alabama, Tuscaloosa, AL 35487 (United States); Lawson, Jeremy [MINT Center, University of Alabama, Tuscaloosa, AL 35487 (United States); Nikles, David E. [MINT Center, University of Alabama, Tuscaloosa, AL 35487 (United States); Williams, John R. [Department of Physics, Auburn University, Auburn, AL 36849 (United States); Isaacs-Smith, Tamara [Department of Physics, Auburn University, Auburn, AL 36849 (United States)

    2005-12-15

    We have studied the effect of ion-beam irradiation on reducing the ordering temperature of FePt and FePtAu nanoparticles. FePt and FePt(Au14%) 4 nm particles dispersed on a Si-substrate were irradiated by 300 keV Al-ions with a dose of 1 x 10{sup 16} ions/cm{sup 2} at 43 {sup o}C using a water-cooled flange in order to minimize the vacancy migration and voids formation within the collision cascades. Partial chemical ordering has been observed in as-irradiated particles with coercivity of 60-130 Oe. Post-irradiation annealing at 220 {sup o}C enhanced chemical ordering in FePt nanoparticles with coercivity of 3500 Oe, magnetic anisotropy of 1.5 x 10{sup 7} erg/cc, and thermal stability factor of 130. A much higher 375 {sup o}C post-irradiation annealing was required in FePtAu, presumably because Au atoms were trapped at Fe/Pt lattice sites at lower temperatures. As the annealing temperature increased, anomalous features in the magnetization reversal curves were observed that disappeared at higher annealing temperatures.

  17. Electronic State of Fe in Double Perovskite Oxide Sr 2FeWO 6

    Science.gov (United States)

    Kawanaka, Hirofumi; Hase, Izumi; Toyama, Shunichiro; Nishihara, Yoshikazu

    1999-09-01

    The magnetic properties of double perovskite oxide Sr2FeWO6 have been reported. The magnetic susceptibility and Mössbauer effect of 57Fe show that this compound is an antiferromagnet with T N=37 K. The Mössbauer parameters below ˜20 K are the center shift of +1.2 mm/s relative to metallic iron, the quadrupole splitting of 1.9 mm/s and the hyperfine field of ˜110 kOe. The quadrupole splitting has a strong temperature dependence. From these data, we conclude that Fe in Sr2FeWO6 is in the Fe2+ high-spin state, while the hyperfine field seems to be quite small. The cell volume shows a large increase compared to other Sr2FeTO6 ( T= Mo, Re, etc.), which is in the Fe3+ high-spin state. These results suggest that these compounds have a strongly coupled charge and lattice systems.

  18. First principles calculations of interlayer exchange coupling in bcc Fe/Cu/Fe structures

    Energy Technology Data Exchange (ETDEWEB)

    Kowalewski, M.; Heninrich, B. [Simon Fraser Univ., Burnaby, British Columbia (Canada); Schulthess, T.C.; Butler, W.H. [Oak Ridge National Lab., TN (United States)

    1998-01-01

    The authors report on theoretical calculations of interlayer exchange coupling between two Fe layers separated by a modified Cu spacer. These calculations were motivated by experimental investigations of similar structures by the SFU group. The multilayer structures of interest have the general form: Fe/Cu(k)/Fe and Fe/Cu(m)/X(1)/Cu(n)/Fe where X indicates one AL (atomic layer) of foreign atoms X (Cr, Ag, or Fe) and k, m, n represent the number of atomic layers of Cu. The purpose of the experimental and theoretical work was to determine the effect of modifying the pure Cu spacer by replacing the central Cu atomic layer with the atomic layer of foreign atoms X. The first principles calculation were performed using the Layer Korringa-Kohn-Rostoker (LKKR) method. The theoretical thickness dependence of the exchange coupling between two semi-infinite Fe layers was calculated for pure Cu spacer thicknesses in the range of 0 < k < 16. The effect of the foreign atoms X on the exchange coupling was investigated using the structure with 9 AL Cu spacer as a reference sample. The calculated changes in the exchange coupling are in qualitative agreement with experiment.

  19. Fast defluorination and removal of norfloxacin by alginate/Fe@Fe3O4 core/shell structured nanoparticles.

    Science.gov (United States)

    Niu, Hongyun; Dizhang; Meng, Zhaofu; Cai, Yaqi

    2012-08-15

    Alginate-Fe(2+)/Fe(3+) polymer coated Fe(3)O(4) magnetic nanoparticles (Fe(3)O(4)@ALG/Fe MNPs) with core/shell structure are prepared and used as heterogeneous Fenton nanocatalyst to degrade norfloxacin (NOF). The Fenton-like process based on Fe(3)O(4)@ALG/Fe shows much higher efficiency on NOF degradation. Compared with Fe(3)O(4) nanoparticle-H(2)O(2) system, NOF degradation in Fe(3)O(4)@AlG/Fe-H(2)O(2) system can be conducted in a wide pH range (pH 3.5-6.5) and independent on temperature. With 0.98 mM H(2)O(2) and 0.4 g L(-1) Fe(3)O(4)@ALG/Fe, 100% of NOF and 90% of TOC is removed within 60 min, and the fluorine element in NOF molecule changes into F(-) ions within 1 min, indicating that NOF degradation in this Fenton-like reaction is performed through direct defluorination pathway. XPS analysis shows that TOC removal in reaction solution mainly results from the adsorption of NOF degradation intermediates on catalyst. Due to the paramagneticity and high saturation magnetization of Fe(3)O(4)@ALG/Fe, the used catalyst with adsorbed NOF intermediate is collected from aqueous solution by applying an external magnetic field, leading to complete removal of NOF from water samples. As being composed of inorganic materials and biopolymer, Fe(3)O(4)@ALG/Fe MNPs are robust, thermo-stable, nontoxic and environmentally friendly. These attractive features endow Fe(3)O(4)@ALG/Fe as a potent Fenton-like catalyst for fluoroquinolones degradation. Copyright © 2012 Elsevier B.V. All rights reserved.

  20. Texture of Nanocomposite Nd2Fe14B/α-Fe Melt Spun Ribbons

    Institute of Scientific and Technical Information of China (English)

    姜忠良; 陈秀云; 白飞明; 马春来; 朱静

    2004-01-01

    Highly textured nanocomposite Nd9Fe84.5Nb0.5B6 ribbons were obtained by rapid solidification at wheel speeds from 15 to 20 m·s-1.X-ray diffraction(XRD)shows that these ribbons are preferentially orientated with the c axis of Nd2Fe14B phase perpendicular to the surface of the ribbons.The texture of Nd2Fe14B phase on the free surface is stronger than that on the contact surface and decreases with increase of wheel speed.The texture of Nd2Fe14B phase seems to be caused by the preferential growth of the crystal nuclei favorable orientation with their c-axes along the temperature gradient during rapid solidification,which can be explained by a growth circular cone(GCC).The intensity of the anisotropy can be expressed by the magnitude of the cone generating angle.The supercooling velocity and wheel speed will influence the cone generating angle,which in turn influences the anisotropy.The remanence and maximum energy product in the direction perpendicular to the ribbon surface is much higher than that in the direction parallel with the ribbon surface.High remanence and maximum energy product can be obtained in the direction perpendicular to the ribbon surface.The texture of Nd2Fe14B phase decreases gradually after annealing above 600 ℃,which is mainly attributed to the precipitation of new α-Fe from Nd2Fe14B phase with super-saturated Fe.Decreasing the annealing temperature or reducing the annealing time is beneficial for preserving the anisotropy of Nd2Fe14B phase after annealing.

  1. Protected Fe valence in quasi-two-dimensional α-FeSi2

    Science.gov (United States)

    Miiller, W.; Tomczak, J. M.; Simonson, J. W.; Smith, G.; Kotliar, G.; Aronson, M. C.

    2015-05-01

    We report the first comprehensive study of the high temperature form (α-phase) of iron disilicide. Measurements of the magnetic susceptibility, magnetization, heat capacity and resistivity were performed on well characterized single crystals. With a nominal iron d6 configuration and a quasi-two-dimensional crystal structure that strongly resembles that of LiFeAs, α-FeSi2 is a potential candidate for unconventional superconductivity. Akin to LiFeAs, α-FeSi2 does not develop any magnetic order and we confirm its metallic state down to the lowest temperatures (T = 1.8 K). However, our experiments reveal that paramagnetism and electronic correlation effects in α-FeSi2 are considerably weaker than in the pnictides. Band theory calculations yield small Sommerfeld coefficients of the electronic specific heat γ = Ce/T that are in excellent agreement with experiment. Additionally, realistic many-body calculations further corroborate that quasi-particle mass enhancements are only modest in α-FeSi2. Remarkably, we find that the natural tendency to vacancy formation in the iron sublattice has little influence on the iron valence and the density of states at the Fermi level. Moreover, Mn doping does not significantly change the electronic state of the Fe ion. This suggests that the iron valence is protected against hole doping and indeed the substitution of Co for Fe causes a rigid-band like response of the electronic properties. As a key difference from the pnictides, we identify the smaller inter-iron layer spacing, which causes the active orbitals near the Fermi level to be of a different symmetry in α-FeSi2. This change in orbital character might be responsible for the lack of superconductivity in this system, providing constraints on pairing theories in the iron based pnictides and chalcogenides.

  2. Insights into Resistance to Fe Deficiency Stress from a Comparative Study of In Vitro-Selected Novel Fe-Efficient and Fe-Inefficient Potato Plants

    Directory of Open Access Journals (Sweden)

    Georgina A. Boamponsem

    2017-09-01

    Full Text Available Iron (Fe deficiency induces chlorosis (IDC in plants and can result in reduced plant productivity. Therefore, development of Fe-efficient plants is of great interest. To gain a better understanding of the physiology of Fe-efficient plants, putative novel plant variants were regenerated from potato (Solanum tubersosum L. var. ‘Iwa’ callus cultures selected under Fe deficient or low Fe supply (0–5 μM Fe. Based on visual chlorosis rating (VCR, 23% of callus-derived regenerants were classified as Fe-efficient (EF and 77% as Fe-inefficient (IFN plant lines when they were grown under Fe deficiency conditions. Stem height was found to be highly correlated with internodal distance, leaf and root lengths in the EF plant lines grown under Fe deficiency conditions. In addition, compared to the IFN plant lines and control parental biotype, the EF plants including the lines named A1, B2, and B9, exhibited enhanced formation of lateral roots and root hairs as well as increased expression of ferritin (fer3 in the leaf and iron-regulated transporter (irt1 in the root. These morphological adaptations and changes in expression the fer3 and irt1 genes of the selected EF potato lines suggest that they are associated with resistance to low Fe supply stress.

  3. Study of CoFeB thickness and composition dependence in a modified CoFeB/MgO/CoFeB perpendicular magnetic tunnel junction

    Science.gov (United States)

    Zhu, M.; Chong, H.; Vu, Q. B.; Brooks, R.; Stamper, H.; Bennett, S.

    2016-02-01

    We studied the CoFeB thickness and composition dependence of tunneling magnetoresistance (TMR) and resistance-area product (RA) in a modified CoFeB/MgO/CoFeB perpendicular magnetic tunnel junction (MTJ), in which the bottom CoFeB is coupled to an in-plane exchange biased magnetic layer. This stack structure allows us to measure TMR and RA of the MTJs in sheet film format without patterning them, using current-in-plane-tunneling (CIPT) technique. The thickness ranges for both top and bottom CoFeB to exhibit perpendicular magnetic anisotropy are similar to what are seen in each single magnetic film stack. However, CIPT measurement revealed that there exists an optimal thickness for both top and bottom CoFeB to achieve the highest TMR value. Magnetic hysteresis loops also suggest the thickness-dependent coupling between the top and bottom CoFeB layers. We studied MTJs with two CoFeB compositions (Co40Fe40B20 and Co20Fe60B20) and found that Co20Fe60B20 MTJs give higher TMR and also wider perpendicular thickness range when used at the top layer.

  4. The ferrimagnetic structure of Fe2Mo3O12: dependence of Fe-O-O-Fe supersuperexchange couplings on geometry

    Science.gov (United States)

    Ehrenberg, H.; Bramnik, K. G.; Muessig, E.; Buhrmester, T.; Weitzel, H.; Ritter, C.

    2003-05-01

    The magnetic structure of Fe2Mo3O12 was determined by neutron powder diffraction and magnetization studies. The magnetic unit cell is identical with the monoclinic chemical one (Z=8), and the magnetic space group is P21/a. The magnetic moments are ferromagnetically aligned along the b-axis for each sublattice corresponding to each Fe-site. There are four different Fe-sites, and the magnetic moments are parallel within two of them, but antiparallel to those of the other two sublattices, so that a ferrimagnetic structure results. The dominant antiferromagnetic supersuperexchange couplings are those along Fe-O-O-Fe paths with the two bridging oxygens belonging to one [MoO4]-tetrahedron and forming large Fe-O-O and O-O-Fe angles.

  5. The ferrimagnetic structure of Fe{sub 2}Mo{sub 3}O{sub 12}: dependence of Fe-O-O-Fe supersuperexchange couplings on geometry

    Energy Technology Data Exchange (ETDEWEB)

    Ehrenberg, H. E-mail: ehrenberg@tu-darmstadt.de; Bramnik, K.G.; Muessig, E.; Buhrmester, T.; Weitzel, H.; Ritter, C

    2003-05-01

    The magnetic structure of Fe{sub 2}Mo{sub 3}O{sub 12} was determined by neutron powder diffraction and magnetization studies. The magnetic unit cell is identical with the monoclinic chemical one (Z=8), and the magnetic space group is P2{sub 1}/a. The magnetic moments are ferromagnetically aligned along the b-axis for each sublattice corresponding to each Fe-site. There are four different Fe-sites, and the magnetic moments are parallel within two of them, but antiparallel to those of the other two sublattices, so that a ferrimagnetic structure results. The dominant antiferromagnetic supersuperexchange couplings are those along Fe-O-O-Fe paths with the two bridging oxygens belonging to one [MoO{sub 4}]-tetrahedron and forming large Fe-O-O and O-O-Fe angles.

  6. One-pot synthesis of urchin-like FePd-Fe3O4 and their conversion into exchange-coupled L1(0)-FePd-Fe nanocomposite magnets.

    Science.gov (United States)

    Yu, Yongsheng; Sun, Kewei; Tian, Yuan; Li, X-Z; Kramer, M J; Sellmyer, D J; Shield, J E; Sun, Shouheng

    2013-10-09

    We report a one-pot synthesis of urchin-like FePd-Fe3O4 nanocomposites, spherical clusters of FePd nanoparticles (NPs) with spikes of Fe3O4 nanorods (NRs), via controlled thermal decomposition of Fe(CO)5 and reduction of Pd(acac)2. The FePd NPs with sizes between 6 and 9 nm self-aggregate into 60 nm superparticles (SPs), and Fe3O4 NRs grow on the surface of these SPs. Reductive annealing at 500 °C converts the FePd-Fe3O4 into exchange-coupled nanocomposites L1(0)-FePd-Fe with their Hc tunable from 0.8 to 2.6 kOe and Ms controlled from 90 to 190 emu/g. The work provides a general approach to L1(0)-FePd-Fe nanocomposite magnets for understanding exchange coupling at the nanoscale. The concept may be extended to other magnetic nanocomposite systems and may help to build superstrong magnets for magnetic applications.

  7. Ferromagnetic resonance on oxideless magnetic Fe and FeRh nanoparticles; Ferromagnetische Resonanz an oxidfreien magnetischen Fe und FeRh Nanopartikeln

    Energy Technology Data Exchange (ETDEWEB)

    Trunova, Anastasia

    2009-05-25

    This work is dedicated to investigations of structural and magnetic properties of the colloidal Fe/Fe{sub x}O{sub y} nanocubes (13 nm) and the Fe{sub x}Rh{sub 100-x} core/shell nanoparticles (2 nm). As compared with other works, where the measurements on oxidized nanoparticles were carried out, we additionally performed investigations on nanoparticles in an oxide free state. In order to make the measurements on oxide free particles possible, oxygen- and hydrogenplasma was used to remove the ligands and reduce the oxide shell of the Fe nanocubes. The oxide free Fe nanocubes were covered with a Ag/Pt protective coating to prevent them from new oxidation. This method allowed carrying out the magnetic measurements on oxide free Fe nanocubes. Micromagnetic simulations as well as simulations of the high frequency susceptibility were used for the data analysing. It was found that both the g-factor g=2.09{+-}0.01 and the anisotropy constant K{sub 4}=(4.8{+-}0.5).10{sup 4} J/m{sup 3} coincide with that of bulk iron. However, the saturation magnetization M{sub S}(5 K)=(1.2{+-}0.12).10{sup 6} A/m differs from the bulk value by 30%. The reduction by 30% compared to the bulk value in the case of nanoparticles may be caused by the following possible reasons: a) the presence of inner oxide layer (approx. 10 at.%) that cannot be reduced; b) the anti-parallel order between magnetic moments of iron core and magnetic moments of antiferomagnetic iron oxide; c) some structural changes of the surface after plasma treatment. The obtained damping parameter {alpha}=0.03{+-}0.005 is ten times larger than that of the Fe layers as it is known for nanoparticles systems in general. The core/shell Fe{sub x}Rh{sub 100-x} nanoparticles (x=80,50) were produced under Ar-atmosphere and were sealed into a quartz tube to prevent oxidation. The analysis of g-factors shows that the value for the FePh nanoparticles with Fe-rich core is larger (g=2.08{+-}0.01) than that for the nanoparticles with Rh

  8. Chemical synthesis of Nd2Fe14B/Fe3B nanocomposites.

    Science.gov (United States)

    Yu, L Q; Zhang, Y P; Yang, Z; He, J D; Dong, K T; Hou, Y

    2016-07-14

    High exchange-coupled Nd2Fe14B/Fe3B nanocomposites were synthesized by an integrative procedure of thermal decomposition and reductive annealing processes. The molar ratio of the resulting products of Nd/Fe/B can be tuned by adjusting the raw material proportion. The as-prepared nanocomposites exhibited an exchanged coupled effect with a large coercivity of 11 100 Gs, enhanced remanence Mr of 42.0 emu g(-1), and Mr/M3T of 0.59.

  9. {sup 57}Fe Mossbauer spectroscopy of NpFeGa{sub 5} in magnetic field

    Energy Technology Data Exchange (ETDEWEB)

    Homma, Y. [Institute for Materials Research, Tohoku University, Oarai, Ibaraki 311-1313 (Japan)]. E-mail: yhomma@imr.tohoku.ac.jp; Nasu, S. [Advance Science Research Center, Japan Atomic Energy Agency, Tokai, Ibaraki 319-1195 (Japan); Nakamura, A. [Advance Science Research Center, Japan Atomic Energy Agency, Tokai, Ibaraki 319-1195 (Japan); Aoki, D. [Institute for Materials Research, Tohoku University, Oarai, Ibaraki 311-1313 (Japan); Haga, Y. [Advance Science Research Center, Japan Atomic Energy Agency, Tokai, Ibaraki 319-1195 (Japan); Metoki, N. [Advance Science Research Center, Japan Atomic Energy Agency, Tokai, Ibaraki 319-1195 (Japan); Sakai, H. [Advance Science Research Center, Japan Atomic Energy Agency, Tokai, Ibaraki 319-1195 (Japan); Ikeda, S. [Advance Science Research Center, Japan Atomic Energy Agency, Tokai, Ibaraki 319-1195 (Japan); Shiokawa, Y. [Institute for Materials Research, Tohoku University, Oarai, Ibaraki 311-1313 (Japan); Advance Science Research Center, Japan Atomic Energy Agency, Tokai, Ibaraki 319-1195 (Japan); Onuki, Y. [Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan); Advance Science Research Center, Japan Atomic Energy Agency, Tokai, Ibaraki 319-1195 (Japan)

    2007-03-15

    {sup 57}Fe Mossbauer measurements of NpFeGa{sub 5} has been carried out in external field H{sub ex}=0,10kOe. The negative quadrupole splitting QS was enhanced between 70 and 110K. Negligibly small QS in the paramagnetic state was verified by a measurement of the spectrum in the applied field of 10kOe. A correlation between the magnetic state and the electric field gradient implies that the origin of H{sub hf} is not only due to the dipole field from magnetic Np atoms, but also from magnetic Fe atoms.

  10. Ammonia synthesis on Au modified Fe(111) and Ag and Cu modified Fe(100) surfaces

    DEFF Research Database (Denmark)

    Lytken, Ole; Waltenburg, Hanne Neergaard; Chorkendorff, Ib

    2003-01-01

    In order to investigate any influence of steps and possible positive effects of making surface alloys the ammonia synthesis has been investigated over Au modified Fe(111) and Ag and Cu modified Fe(100) single crystals in the temperature range 603-773 K, using a system combining ultra-high vacuum...... and a high-pressure cell. Ammonia was synthesized from a stoichiometric (N-2:3H(2)) gas mixture at a pressure of 2 bar. By deposition of small amounts of An, the ammonia production activity of the Fe(1 1 1) surface can be enhanced. More important, for the gold modified surface, the reaction order in ammonia...

  11. Hyperfine and magnetic properties of Fe-Cu clusters and Fe precipitates embedded in a Cu matrix

    Energy Technology Data Exchange (ETDEWEB)

    Klautau, A B [Faculdade de Fisica, Universidade Federal do Para, 66075-110, Belem, PA (Brazil); Socolovsky, L M [Laboratorio de Solidos Amorfos, INTECIN, Facultad de Ingenieria, Universidad de Buenos Aires, C1063ACV, Buenos Aires (Argentina); Nogueira, R N [Faculdade Taboao da Serra, 06768-000, Taboao da Serra, SP (Brazil); Petrilli, H M, E-mail: aklautau@ufpa.b [Instituto de Fisica, Universidade de Sao Paulo, CP 66318, 05315-970 Sao Paulo, SP (Brazil)

    2009-12-16

    Using the first-principles real-space linear muffin-tin orbital method within the atomic sphere approximation (RS-LMTO-ASA) we study hyperfine and local magnetic properties of substituted pure Fe and Fe-Cu clusters in an fcc Cu matrix. Spin and orbital contributions to magnetic moments, hyperfine fields and the Moessbauer isomer shifts at the Fe sites in Fe precipitates and Fe-Cu alloy clusters of sizes up to 60 Fe atoms embedded in the Cu matrix are calculated and the influence of the local environment on these properties is discussed.

  12. PERANAN ASEAN DALAM MENGATASI KONFLIK ANTARA REPUBLIK RAKYAT CINA (RRC) DENGAN NEGARA-NEGARA ANGGOTA ASEAN TERKAIT PENDAKUAN REPUBLIK RAKYAT CINA (RRC) ATAS SELURUH WILAYAH PERAIRAN LAUT CINA SELATAN

    OpenAIRE

    JELA, REIGER MAHULE JELA

    2014-01-01

    The title of this study is “ASEAN Role in Overcoming the Conflict Between the People's Republic of China (PRC) with ASEAN Member Countries in Relevant to People’s Republic of China (PRC) Claimants on the Whole Waters Area of South China Sea”. The purpose of this study was to determine the role of ASEAN in conflict resolution efforts in the South China Sea. This research is a normative legal research that focuses on secondary data that serve as the primary legal materials con...

  13. Preparation and Characterization of Novel Porous Fe-Si Alloys

    Institute of Scientific and Technical Information of China (English)

    WANG Jiefeng; HE Yuehui; JIANG Yao; GAO Hanyan; YANG Junsheng; GAO Lin

    2016-01-01

    Porous Fe-Si alloys with different nominal compositions ranging from Fe-10wt% Si to Fe-50wt% Si were fabricated through a reactive synthesis of Fe and Si elemental powder mixtures. The effects of Si contents on the pore structure of porous Fe-Si alloy were investigated in detail. The results showed that the open porosity, gas permeability and maximum pore size of the porous Fe-Si alloys increased with increasing Si contents, indicating that the porosity and pore size can be tailored by changing the Si contents. The pore structure parameter including the open porosity, gas permeability, maximum pore size obeyed the Hagen-Poiseuille formula with the constant G=0.035 m-1Pa-1s-1 for the reactively synthesized porous Fe-Si alloys. The mechanical property of the porous Fe-Si alloys showed applicability in the ifltration industries.

  14. Uranium and Iron XRF distribution and Fe speciation results

    Data.gov (United States)

    U.S. Environmental Protection Agency — Dataset 1: XRF image of U and Fe distribution Dataset 2: Fe linear combination fitting data. This dataset is associated with the following publication: Koster van...

  15. [2Fe-2S] Proteins in chlorosomes

    DEFF Research Database (Denmark)

    Johnson, T. Wade; Li, Hui; Frigaard, Niels-Ulrik;

    2013-01-01

    The chlorosome envelope of Chlorobaculum tepidum contains 10 polypeptides, three of which, CsmI, CsmJ, and CsmX, have an adrenodoxin-like domain harboring a single [2Fe-2S] cluster. Mutants that produced chlorosomes containing two, one, or none of these Fe-S proteins were constructed [Li, H., et al....... (2013) Biochemistry 52, preceding paper in this issue ( DOI: 10.1021/bi301454g )]. The electron paramagnetic resonance (EPR) spectra, g values, and line widths of the Fe-S clusters in individual CsmI, CsmJ, and CsmX proteins were obtained from studies with isolated chlorosomes. The Fe-S clusters...... in these proteins were characterized by EPR and could be differentiated on the basis of their g values and line widths. The EPR spectrum of wild-type chlorosomes could be simulated by a 1:1 admixture of the CsmI and CsmJ spectra. No contribution of CsmX to the EPR spectrum of chlorosomes was observed because of its...

  16. Superparamagnetic relaxation in alpha-Fe particles

    DEFF Research Database (Denmark)

    Bødker, Franz; Mørup, Steen; Pedersen, Michael Stanley;

    1998-01-01

    The superparamagnetic relaxation time of carbon-supported alpha-Fe particles with an average size of 3.0 Mm has been studied over a large temperature range by the use of Mossbauer spectroscopy combined with AC and DC magnetization measurements. It is found that the relaxation time varies with tem...

  17. Laser alloyed Al-Ni-Fe coatings

    CSIR Research Space (South Africa)

    Pityana, SL

    2008-10-01

    Full Text Available analysed by menas of X-ray diffraction (XRD), optical and scanning electron microscopy (SEM). It was found that when alloying with Fe-rich mixtures, the thin surface layers contained a number of cracks in the heat affected zones (HAZ). Alloying with Ni...

  18. Santa Fe Junior College, Gainesville, Florida.

    Science.gov (United States)

    Caudill, Rowlett and Scott, Architects, Houston, TX.

    The design of Santa Fe Junior College is examined, beginning with the development of an educational philosophy. Subsequent design decisions are based largely upon this philosophy which emphasizes the development of the individual student and the fulfillment of his needs. Further, the need for flexibility is recognized and is an important aspect of…

  19. Exchange bias in sputtered FeNi/FeMn systems: Effect of short low-temperature heat treatments

    Energy Technology Data Exchange (ETDEWEB)

    Savin, Peter, E-mail: peter.savin@urfu.ru [Department of Magnetism and Magnetic Nanomaterials, Laboratory of Magnetic Sensors, Ural Federal University, 620002 Ekaterinburg (Russian Federation); Guzmán, Jorge [Instituto de Ciencia de Materiales de Madrid-CSIC, 28049 Madrid (Spain); Lepalovskij, Vladimir [Department of Magnetism and Magnetic Nanomaterials, Laboratory of Magnetic Sensors, Ural Federal University, 620002 Ekaterinburg (Russian Federation); Svalov, Andrey; Kurlyandskaya, Galina [Department of Magnetism and Magnetic Nanomaterials, Laboratory of Magnetic Sensors, Ural Federal University, 620002 Ekaterinburg (Russian Federation); Departamento de Electricidad y Electrónica, Universidad del País Vasco (UPV/EHU), 48940 Leioa, Vizcaya (Spain); Asenjo, Agustina [Instituto de Ciencia de Materiales de Madrid-CSIC, 28049 Madrid (Spain); Vas’kovskiy, Vladimir [Department of Magnetism and Magnetic Nanomaterials, Laboratory of Magnetic Sensors, Ural Federal University, 620002 Ekaterinburg (Russian Federation); Vazquez, Manuel [Department of Magnetism and Magnetic Nanomaterials, Laboratory of Magnetic Sensors, Ural Federal University, 620002 Ekaterinburg (Russian Federation); Instituto de Ciencia de Materiales de Madrid-CSIC, 28049 Madrid (Spain)

    2016-03-15

    Short (5 min) post-deposition thermal treatments under magnetic field at low temperature (up to 200 °C) performed in exchange-coupled FeNi(40 nm)/FeMn(20 nm) bilayer thin films prepared by magnetron sputtering are shown to be effective to significantly modify their exchange field (from around 40 Oe down to 27 Oe) between FeNi and FeMn layers. A similar exchange field decrease was observed for the first deposited FeNi layer of the FeNi(40 nm)/FeMn(20 nm)/FeNi(40 nm) trilayer films after the same thermal treatments. The exchange field value for the second FeNi layer was not substantially changed. The X-ray diffraction patterns indicates that such a heat treatment has no effect on the grain size and crystalline texture of the films, while atomic force microscope studies reveal an increase of the surface roughness after the treatment which is more noticeable in the case of the trilayer film. Analysis of the experimental results leads us to conclude that the variations of the exchange field after heat treatment are likely caused by a modification of interfacial roughness and/or interfacial magnetic structure, but unlikely by the changes in the microstructure and/or changes of composition of the antiferromagnetic FeMn layer. - Highlights: • FeNi/FeMn bilayers and FeNi/FeMn/FeNi trilayers were prepared by magnetron sputtering. • Post-deposition heat treatments at the temperatures below 200 °C during 5 min were made. • Annealing reduces the exchange field for the first FeNi layer in trilayers. • The exchange field value for the second FeNi layer was not substantially changed. • Exchange field changes are most likely caused by a modification of interface roughness.

  20. Fe3+-Doped TiO2 Nanotube Arrays on Ti-Fe Alloys for Enhanced Photoelectrocatalytic Activity

    Directory of Open Access Journals (Sweden)

    Jiangdong Yu

    2016-06-01

    Full Text Available Highly ordered, vertically oriented Fe3+-doped TiO2 nanotube arrays (Fe-TNTs were prepared on Ti-Fe alloy substrates with different Fe contents by the electrochemical anodization method. The as-prepared Fe-TNTs were characterized by scanning electron microscope (SEM, transmission electron microscopy (TEM, X-ray diffraction (XRD, X-ray photoelectron spectroscopy (XPS and related electrochemical techniques. XPS results demonstrated that Fe3+ ions were successfully doped into TiO2 nanotubes. The photoelectrochemical activity of Fe-TNTs was compared with that of pure TiO2 nanotube arrays (TNTs. The results showed that Fe-TNTs grown on low concentration (0.5 wt %–1 wt % Fe Ti-Fe alloys possessed higher photocurrent density than TNTs. The Fe-TNTs grown on Ti-Fe alloy containing 0.8 wt % Fe exhibited the highest photoelectrochemical activity and the photoelectrocatalytic degradation rate of methylene blue (MB aqueous solution was significantly higher than that of TNTs.

  1. Preparation of LiFePO4 for lithium ion battery using Fe2P2O7 as precursor

    Institute of Scientific and Technical Information of China (English)

    HU Guo-rong; XIAO Zheng-wei; PENG Zhong-dong; DU Ke; DENG Xin-rong

    2008-01-01

    In order to obtain a new precursor for LiFePO4, Fe2P2O7 with high purity was prepared through solid phase reaction at 650 ℃ using starting materials of FeC2O4 and NH4H2PO4 in an argon atmosphere. Using the as-prepared Fe2P2O7, Li2CO3 and glucose as raw materials, pure LiFePO4 and LiFePO4/C composite materials were respectively synthesized by solid state reaction at 700 ℃ in an argon atmosphere. X-ray diffractometry and scanning electron microscopy(SEM) were employed to characterize the as-prepared Fe2P2O7, LiFePO4 and LiFePO4/C. The as-prepared Fe2P2O7 crystallizes in the c1 space group and belongs to β-Fe2P2O7 for crystal phase. The particle size distribution of Fe2P2O7 observed by SEM is 0.4-3.0μm. During the Li+ ion chemical intercalation, radical P2O4-O7 is disrupted into two PO3-4 ions in the presence of O2-, thus providing a feasible technique to dispose this poor dissolvable pyrophosphate. LiFePO4/C composite exhibits initial charge and discharge capacities of 154 and 132 mA·h/g, respectively.

  2. Measured level lifetimes for the coronal transitions of Fe X and Fe XIV.

    Energy Technology Data Exchange (ETDEWEB)

    Moehs, D. P.; Church, D. A.; Physics; Texas A& M Univ.

    1999-05-01

    In a laboratory study, the lifetimes of the {sup 2}P levels producting the coronal transitions of Fe X and Fe XIV have been measured. The fluorescence from the metastable levels, which were populated when the ions wre produced in a source of multiply charged ions, was studied from the selected ions were injected into an electrostatic ion trap. The results are {tau}(FeX, 3s{sup 2}3p{sup 5} {sup 2}P{sup 0}{sub 1/2})=13.64{+-}0.25 ms and {tau}(Fe XIV, 3s{sup 2}3p{sup 2}P{sup 0}{sub 1/2})=17.52{+-}0.29 ms. The data significantly reduce the uncertainty of the lifetimes when compared with existing theory.

  3. {sup 237}Np and {sup 57}Fe Moessbauer study of NpFeGa{sub 5}

    Energy Technology Data Exchange (ETDEWEB)

    Homma, Y., E-mail: yhomma@imr.tohoku.ac.jp [Tohoku University, Institute for Materials Research (Japan); Nakada, M. [Japan Atomic Energy Research Institute, Nuclear Science and Engineering Directorate (Japan); Nakamura, A. [Japan Atomic Energy Research Institute, Advance Science Research Center (Japan); Nasu, S.; Aoki, D. [Tohoku University, Institute for Materials Research (Japan); Sakai, H.; Ikeda, S.; Yamamoto, E.; Haga, Y.; Onuki, Y. [Japan Atomic Energy Research Institute, Advance Science Research Center (Japan); Shiokawa, Y. [Tohoku University, Institute for Materials Research (Japan)

    2006-02-15

    {sup 57}Fe and {sup 237}Np Moessbauer Omeasurements have been performed for NpFeGa{sub 5}, which is one of the so-called neptunium 1-1-5 compounds. The {sup 57}Fe Moessbauer spectra below T{sub N} = 118 K show the magnetically ordered state. The magnitude of the hyperfine magnetic field at the {sup 57}Fe nucleus is determined to be 1.98 {+-} 0.05 T at 10 K. From the {sup 237}Np Moessbauer spectrum at 10 K, the hyperfine magnetic field at the {sup 237}Np nucleus is 203 T and the hyperfine coupling constant is determined to be 237 T/{mu}{sub B} using the Np atomic magnetic moment of 0.86 {mu}{sub B} determined by the neutron diffraction study.

  4. Thermal Stability of CoFe/Cu/CoFe/IrMn Top Spin Valve

    Institute of Scientific and Technical Information of China (English)

    ZHOU Guang-Hong; WANG Yin-Gang; QI Xian-Jin

    2009-01-01

    We present a study of thermal stability of the top spin valve with a structure of seed Ta (5nm)/Co75Fe25 (5nm)/Cu (2.5nm)/Co75Fe25n (5nm)/Ir20 Mn80 (12nm)/cap Ta (8nm) deposited at room temperature by magnetron sputtering. A vibrating sample magnetometer fixed with a heater was used to record the magnetic hysteresis loops at variational temperatures and x-ray diffraction was performed to characterize the structure of the multilayer.The exchange field Hex and the coercivity of the pinned CoFe layer Hcp decrease monotonically with increasing temperature.The coercivity of the free CoFe layer Hcf in the spin valve shows a maximum at 498K.The temperature dependences of Hex,Hcp and Hcf have also been discussed.

  5. Microwave switching behaviors of Fe/Ag/Fe/Ag epitaxial films

    Energy Technology Data Exchange (ETDEWEB)

    Hung, D.-S. [Department of Information and Telecommunications Engineering, Ming Chuan University, Taipei, Taiwan (China)]. E-mail: dshung@mcu.edu.tw; Tsai, C.S. [Department of Electrical and Computer Engineering, University of California, Irvine, CA (United States); Yu, C.-C. [Institute of Physics, Academia Sinica, Taipei, Taiwan (China); Liou, Y. [Institute of Physics, Academia Sinica, Taipei, Taiwan (China); Lee, Shang-Fan [Institute of Physics, Academia Sinica, Taipei, Taiwan (China); Chiang, P.-C. [Department of Chemical Engineering, Tunghai University, Taichung, Taiwan (China); Ho, C.-S. [Department of Chemical Engineering, Tunghai University, Taichung, Taiwan (China); Yao, Y.-D. [Institute of Physics, Academia Sinica, Taipei, Taiwan (China)

    2006-09-15

    In this study, Fe/Ag/Fe/Ag ferromagnetic structures were epitaxially grown on a GaAs(1 0 0) substrate. Using the Network Analyzer (Agilent 8510C), FMR (ferromagnetic resonant) signals were observed in samples as the in-plane magnetic field was applied to either hard- or easy-axes. Of interest was that our sample demonstrated a FMR-switching behavior in hard-axis but not in easy-axis. The detecting data showed that the switch magnetic field was much smaller than what has been stated previously in Fe/Cu/Fe systems by other laboratories. In addition to the frequency switch in FMR, we also observed a magnetic reversal behavior in its M-H curve. Data presented that both of the FMR and magnetic reverse took place in the same direction (hard-axis)

  6. Incommensurate magnetism in FeAs strips: neutron scattering from CaFe(4)As(3).

    Science.gov (United States)

    Nambu, Yusuke; Zhao, Liang L; Morosan, Emilia; Kim, Kyoo; Kotliar, Gabriel; Zajdel, Pawel; Green, Mark A; Ratcliff, William; Rodriguez-Rivera, Jose A; Broholm, Collin

    2011-01-21

    Magnetism in the orthorhombic metal CaFe(4)As(3) was examined through neutron diffraction for powder and single crystalline samples. Incommensurate [q(m) ≈ (0.37-0.39) × b*] and predominantly longitudinally (|| b) modulated order develops through a 2nd order phase transition at TN = 89.63(6) K with a 3D Heisenberg-like critical exponent β = 0.365(6). A 1st order transition at T2 = 25.6(9)  K is associated with the development of a transverse component, locking q(m) to 0.375(2)b*, and increasing the moments from 2.1(1) to 2.2(3)  μ B for Fe2+ and from 1.3(3) to 2.4(4)  μB for Fe+. The ab initio Fermi surface is consistent with a nesting instability in cross-linked FeAs strips.

  7. Angular dependence of demagnetization processes in Fe-FePt perpendicular exchange-spring bilayers

    Energy Technology Data Exchange (ETDEWEB)

    Solzi, M. [Dipartimento di Fisica, Universita di Parma and CNISM, V.le G.P. Usberti 7/A, 43100 Parma (Italy)]. E-mail: solzi@fis.unipr.it; Pernechele, C. [Dipartimento di Fisica, Universita di Parma and CNISM, V.le G.P. Usberti 7/A, 43100 Parma (Italy); Pellicelli, R. [Dipartimento di Fisica, Universita di Parma and CNISM, V.le G.P. Usberti 7/A, 43100 Parma (Italy); Ghidini, M. [Dipartimento di Fisica, Universita di Parma and CNISM, V.le G.P. Usberti 7/A, 43100 Parma (Italy); Albertini, F. [IMEM-CNR, Parco Area delle Scienze 37/A, 43010 Parma (Italy); Casoli, F. [IMEM-CNR, Parco Area delle Scienze 37/A, 43010 Parma (Italy)

    2007-09-15

    The angular dependence of hysteresis loops of exchange-spring (ES) bilayers constituted by a Fe layer as the soft phase and a hard layer of L1{sub 0} Fe{sub 53}Pt{sub 47} is presented. FePt thin films of nominal thickness 10 nm have been prepared by RF sputtering on MgO (1 0 0) substrates in order to achieve the epitaxial growth with the c-axis perpendicular to the film plane. The Fe soft layers have been deposited at RT with various thicknesses (from 2 to 10 nm). The angular dependence of the bilayers' magnetic properties is studied by SQUID magnetometry varying the angle between the easy axis of the hard phase and the direction of the applied field from 0 to {pi}/2. The magnetic behavior at different angles is analyzed by a one-dimensional micromagnetic model specifically extended to the case of perpendicular magnetic anisotropy (PMA)

  8. Activities of liquid Fe-As and Fe-Sb alloys saturated with carbon

    Institute of Scientific and Technical Information of China (English)

    Leandro Voisin; Kimio Itagaki

    2006-01-01

    A solid iron base alloy of the so-called furnace residue is often formed as a by-product in reduction smelting of lead sinter and scraps with high contents of arsenic and antimony. The use of phase separation into a liquid iron-rich alloy and a liquid lead-rich alloy in lead-iron-arsenic and lead-iron-antimony systems saturated with carbon at relatively low temperatures of about 1200℃ was proposed in a new process for treating the furnace residue to recover valuable elements into the lead-rich alloy and fix toxic arsenic into the iron-rich alloy. As a fundamental study for the proposed process, the activity coefficients and interaction parameters of the Fe-As and Fe-Sb systems saturated with carbon at 1200℃ were derived in this study, based on the determined phase relations in the Fe-Pb-As and Fe-Pb-Sb systems saturated with carbon.

  9. Efficient spin injection and giant magnetoresistance in Fe / MoS 2 / Fe junctions

    KAUST Repository

    Dolui, Kapildeb

    2014-07-02

    We demonstrate giant magnetoresistance in Fe/MoS2/Fe junctions by means of ab initio transport calculations. We show that junctions incorporating either a monolayer or a bilayer of MoS2 are metallic and that Fe acts as an efficient spin injector into MoS2 with an efficiency of about 45%. This is the result of the strong coupling between the Fe and S atoms at the interface. For junctions of greater thickness, a maximum magnetoresistance of ∼300% is obtained, which remains robust with the applied bias as long as transport is in the tunneling limit. A general recipe for improving the magnetoresistance in spin valves incorporating layered transition metal dichalcogenides is proposed. © 2014 American Physical Society.

  10. Investigation of correlation effects in FeSe and FeTe by LDA + U method

    Science.gov (United States)

    Lohani, H.; Mishra, P.; Sekhar, B. R.

    2015-05-01

    We present a comparative study of the influence of Coulomb interaction and Hund's coupling on the electronic structure of FeSe and FeTe. Our calculations are based on density functional theory (DFT) with local density approximation (LDA + U) framework employed in TB-LMTO ASA code. We found the correlation effects are orbital selective due to the strength of interorbital hybridization among the different Fe-3d orbitals mediated via the chalcogen (Se/Te-p) orbitals and are different in both the compounds. The Coulomb interaction is screened significantly by Te-p bands in FeTe. Similarly the orbital selection is different in both the compounds because of the difference in the chalcogen height.

  11. Suppression of Superconductivity by Twin Boundaries in FeSe

    OpenAIRE

    Hoffman, Jenny Eve; Song, Can-Li; Wang, Yi-Lin; Jiang, Ye-Ping; Wang, Lili; He, Ke; Chen, Xi; Ma, Xu-Cun; Xue, Qi-Kun

    2012-01-01

    Low-temperature scanning tunneling microscopy and spectroscopy are employed to investigate twin boundaries in stoichiometric FeSe films grown by molecular beam epitaxy. Twin boundaries can be unambiguously identified by imaging the 90{\\deg} change in the orientation of local electronic dimers from Fe site impurities on either side. Twin boundaries run at approximately 45{\\deg} to the Fe-Fe bond directions, and noticeably suppress the superconducting gap, in contrast with the recent experiment...

  12. Fe(II)-catalyzed recrystallization of goethite revisited.

    Science.gov (United States)

    Handler, Robert M; Frierdich, Andrew J; Johnson, Clark M; Rosso, Kevin M; Beard, Brian L; Wang, Chongmin; Latta, Drew E; Neumann, Anke; Pasakarnis, Timothy; Premaratne, W A P J; Scherer, Michelle M

    2014-10-01

    Results from enriched (57)Fe isotope tracer experiments have shown that atom exchange can occur between structural Fe in Fe(III) oxides and aqueous Fe(II) with no formation of secondary minerals or change in particle size or shape. Here we derive a mass balance model to quantify the extent of Fe atom exchange between goethite and aqueous Fe(II) that accounts for different Fe pool sizes. We use this model to reinterpret our previous work and to quantify the influence of particle size and pH on extent of goethite exchange with aqueous Fe(II). Consistent with our previous interpretation, substantial exchange of goethite occurred at pH 7.5 (≈ 90%) and we observed little effect of particle size between nanogoethite (average size of 81 × 11 nm; ≈ 110 m(2)/g) and microgoethite (average size of 590 × 42 nm; ≈ 40 m(2)/g). Despite ≈ 90% of the bulk goethite exchanging at pH 7.5, we found no change in mineral phase, average particle size, crystallinity, or reactivity after reaction with aqueous Fe(II). At a lower pH of 5.0, no net sorption of Fe(II) was observed and significantly less exchange occurred accounting for less than the estimated proportion of surface Fe atoms in the particles. Particle size appears to influence the amount of exchange at pH 5.0 and we suggest that aggregation and surface area may play a role. Results from sequential chemical extractions indicate that (57)Fe accumulates in extracted Fe(III) goethite components. Isotopic compositions of the extracts indicate that a gradient of (57)Fe develops within the goethite with more accumulation of (57)Fe occurring in the more easily extracted Fe(III) that may be nearer to the surface.

  13. Fe-catalyzed thermal conversion of sodium lignosulfonate to graphene

    Science.gov (United States)

    Sung Phil Mun; Zhiyong Cai; Jilei Zhang

    2013-01-01

    Sodium lignosulfonate (LS) from sulfite pulping processing was used as a carbon source to synthesize graphene. LS was mixed with Fe nanoparticles (FeNPs) as a catalyst and thermally treated at 1000 °C for 1 h. The Raman spectrum and X-ray diffraction pattern suggested that graphene sheets were formed in LS thermally treated with FeNPs (Fe-HTLS). Scanning...

  14. Rapid thermal annealing of FePt and FePt/Cu thin films

    Energy Technology Data Exchange (ETDEWEB)

    Brombacher, Christoph

    2011-01-10

    Chemically ordered FePt is one of the most promising materials to reach the ultimate limitations in storage density of future magnetic recording devices due to its high uniaxial magnetocrystalline anisotropy and a corrosion resistance superior to rare-earth based magnets. In this study, FePt and FePt/Cu bilayers have been sputter deposited at room temperature onto thermally oxidized silicon wafers, glass substrates and self-assembled arrays of spherical SiO{sub 2} particles with diameters down to 10 nm. Millisecond flash lamp annealing, as well as conventional rapid thermal annealing was employed to induce the phase transformation from the chemically disordered A1 phase into the chemically ordered L1{sub 0} phase. The influence of the annealing temperature, annealing time and the film thickness on the ordering transformation and (001) texture evolution of FePt films with near equiatomic composition was studied. Whereas flash lamp annealed FePt films exhibit a polycrystalline morphology with high chemical L1{sub 0} order, rapid thermal annealing can lead to the formation of chemically ordered FePt films with (001) texture on amorphous SiO{sub 2}/Si substrates. The resultant high perpendicular magnetic anisotropy and large coercivities up to 40 kOe are demonstrated. Simultaneously to the ordering transformation, rapid thermal annealing to temperatures exceeding 600 C leads to a break up of the continuous FePt film into separated islands. This dewetting behavior was utilized to create regular arrays of FePt nanostructures on SiO{sub 2} particle templates with periods down to 50 nm. The addition of Cu improves the (001) texture formation and chemical ordering for annealing temperatures T{sub a} {<=}600 C. In addition, the magnetic anisotropy and the coercivity of the ternary FePtCu alloy can be effectively tailored by adjusting the Cu content. The prospects of FePtCu based exchange spring media, as well as the magnetic properties of FePtCu nanostructures fabricated

  15. Submicron R2Fe14B particles

    Directory of Open Access Journals (Sweden)

    O. Koylu-Alkan

    2016-05-01

    Full Text Available Mechanochemical synthesis of submicron R2Fe14B particles with R = Dy, Nd, Pr has been performed successfully via high energy ball milling of rare-earth oxides, iron oxide and boron oxide in the presence of a reducing agent (Ca and a dispersant material (CaO, followed by annealing at 800 - 900 °C. In the R = Nd system, we were able to fabricate particles embedded in a CaO matrix with coercivity (Hc of 10.3 kOe after annealing at 900 °C for 5 min. After washing off the dispersant, the Hc was decreased to below 1 kOe because of hydrogen absorption that leads to the formation of the hydrated R2Fe14BHx phase that has a lower anisotropy. Upon removal of the hydrogen the coercivity was increased to 3.3 kOe. The average size of the Nd2Fe14B particles increases from 100 nm in a sample synthesized at 800 °C to 158 nm at 900 °C. The isotropic Dy2Fe14B particles showed a higher coercivity of 21 kOe in washed samples after annealing at 900 °C for 5 min. An average size of 71 nm is measured in samples synthesized at 800 °C and 107 nm at 900 °C. Fitting the high field M(H measurements in Nd2Fe14B to the law of approach to saturation gave values for the magnetocrystalline anisotropy for the washed sample 2.23 × 107 erg/cm3 and for the vacuum annealed sample 4.15 × 107 erg/cm3, both of which are lower than the bulk values. This would explain the lower values of Hc observed in the particles.

  16. Lyophilization protects [FeFe]-hydrogenases against O2-induced H-cluster degradation

    OpenAIRE

    Jens Noth; Ramona Kositzki; Kathrin Klein; Martin Winkler; Michael Haumann; Thomas Happe

    2015-01-01

    Nature has developed an impressive repertoire of metal-based enzymes that perform complex chemical reactions under moderate conditions. Catalysts that produce molecular hydrogen (H2) are particularly promising for renewable energy applications. Unfortunately, natural and chemical H2-catalysts are often irreversibly degraded by molecular oxygen (O2). Here we present a straightforward procedure based on freeze-drying (lyophilization), that turns [FeFe]-hydrogenases, which are excellent H2-produ...

  17. Removal of indigo blue using clinoptilolite-Fe; Remocion de azul indigo utilizando clinoptilolita-Fe

    Energy Technology Data Exchange (ETDEWEB)

    Gutierrez S, E. E.; Colin C, A. [Universidad Autonoma del Estado de Mexico, Facultad de Quimica, Paseo Tollocan esquina Paseo Colon s/n, Toluca 50180, Estado de Mexico (Mexico); Solache R, M. J. [ININ, Carretera Mexico-Toluca s/n, Ocoyoacac 52750, Estado de Mexico (Mexico)], e-mail: edithgs77@yahoo.com.mx

    2008-07-01

    The removal of indigo blue from aqueous solutions was evaluated using modified clinoptilolite with Fe (Z-Fe) which was characterized by SEM, EDS analysis and specific area (BET). The process followed the kinetics of pseudo-second order and Langmuir isotherm. Sorption capacity obtained was 18 mg g{sup -1} and a solid-liquid ratio 10 g L{sup -1}. (Author)

  18. Immiscibility in the Fe3O4-FeCr2O4 Spinel Binary

    Energy Technology Data Exchange (ETDEWEB)

    S.E. Ziemniak; R.A. Castelli

    2003-03-20

    A recent thermodynamic model of mixing in spinel binaries, based on changes in cation disordering (x) between tetrahedral and octahedral sites, is investigated for applicability to the Fe{sub 3}O{sub 4}-FeCr{sub 2}O{sub 4} system under conditions where incomplete mixing occurs. Poor agreement with measured consolute solution temperature and solvus is attributed to neglect of: (1) ordering of magnetic moments of cations in the tetrahedral sublattice antiparallel to the moments of those in the octahedral sublattice and (2) pair-wise electron hopping between octahedral site Fe{sup 3+} and Fe{sup 2+} ions. Disordering free energies ({Delta}G{sub D}), from which free energies of mixing are calculated, are modeled by {Delta}G{sub D} = {alpha}{chi} + {beta}{chi}{sup 2} - T(S{sub c} + {chi}{sigma}{sub el} + {gamma}{chi}{sigma}{sup mag}) where the previously-neglected effects are accommodated by: (1) adding a non-configurational entropy term to provide coupling between cation disordering and magnetic ordering and (2) revising the configurational entropy (S{sub c}) analysis. Applying the constraint {alpha} = -(2/3){beta} and regressing the existing database for Fe{sup 2+} ion disorder in Fe{sub 3}O{sub 4} gives: {beta} = -31,020 {+-} 1050 J mol{sup -1}, {sigma}{sub el}/R = -0.730 {+-} 0.081 and {gamma}, the coupling parameter between cation disordering and magnetic ordering, = -0.664 {+-} 0.075. The revised mixing model predicts a consolute solution temperature (T{sub cs}) = 600 C and a solvus at 500 C of n = 0.05 and 0.70 for the Fe(Fe{sub 1-n}Cr{sub n}){sub 2}O{sub 4} spinel binary.

  19. MR imaging differentiation of Fe(2+) and Fe(3+) based on relaxation and magnetic susceptibility properties.

    Science.gov (United States)

    Dietrich, Olaf; Levin, Johannes; Ahmadi, Seyed-Ahmad; Plate, Annika; Reiser, Maximilian F; Bötzel, Kai; Giese, Armin; Ertl-Wagner, Birgit

    2017-04-01

    The aim of this study is to evaluate the MR imaging behavior of ferrous (Fe(2+)) and ferric (Fe(3+)) iron ions in order to develop a noninvasive technique to quantitatively differentiate between both forms of iron. MRI was performed at 3 T in a phantom consisting of 21 samples with different concentrations of ferrous and ferric chloride solutions (between 0 and 10 mmol/L). A multi-echo spoiled gradient-echo pulse sequence with eight echoes was used for both T 2* and quantitative susceptibility measurements. The transverse relaxation rate, R 2* = 1/T 2*, was determined by nonlinear exponential fitting based on the mean signals in each sample. The susceptibilities, χ, of the samples were calculated after phase unwrapping and background field removal by fitting the spatial convolution of a unit dipole response to the measured internal field map. Relaxation rate changes, ΔR 2*(c Fe), and susceptibility changes, Δχ(c Fe), their linear slopes, as well as the ratios ΔR 2*(c Fe) / Δχ(c Fe) were determined for all concentrations. The linear slopes of the relaxation rate were (12.5 ± 0.4) s(-1)/(mmol/L) for Fe(3+) and (0.77 ± 0.09) s(-1)/(mmol/L) for Fe(2+) (significantly different, z test P relaxation behaviors in MRI but similar susceptibility patterns. These properties can be used to differentiate ferrous and ferric samples.

  20. Tetrachloroethene degradation by reducing-agent enhanced Fe(II)/Fe(III) catalyzed percarbonate

    Science.gov (United States)

    Miao, Z.; Brusseau, M. L.; Lu, S.; Gu, X.; Yan, N.; Qiu, Z.; Sui, Q.

    2015-12-01

    This project investigated the effect of reducing agents on the degradation of tetrachloroethene(PCE) by Fe(II)/Fe(III) catalyzed sodium percarbonate (SPC). SPC possesses similar function as liquid H2O2, such that free H2O2 is released into solution when percarbonate is mixed with water. The addition of reducing agents, including hydroxylamine hydrochloride, sodium sulfite, ascorbic acid and sodium ascorbate, accelerated the Fe(III)/Fe(II) redoxcycle, leading to a relatively steady Fe(II) concentration and higher production of free radicals. This, in turn, resulted in enhanced PCE oxidation by SPC, with almost complete PCE removal obtained for appropriate Fe and SPC concentrations.The results of chemical probe tests, using nitrobenzene and carbon tetrachloride, demonstrated that HO● was the predominant radical in the system and that O2●-played a minor role. This was further confirmed by the results of electron paramagnetic resonance measurements and salicylic acid hydroxylationanalysis by high performance liquid chromatography(HPLC). PCE degradation decreased significantly with the addition of isopropanol, a strong HO● scavenger, supporting the hypothesis that HO● was primarily responsible for PCE degradation. It should be noted that the release of Cl- was slightly delayed in the first 20 mins, indicating that intermediate products were produced. However, gas chromatography mass spectrometry (GC/MS) analysis did not detect any chlorinated organic compound except PCE, indicating these intermediates were quickly degraded, which resulted in the complete conversion of PCE to CO2. In conclusion, the use of reducing agents to enhance Fe(II)/Fe(III) catalyzed SPC oxidation appears to be a promising approach for the rapid degradation of organic contaminants in groundwater.

  1. Low 60Fe abundance in Semarkona and Sahara 99555

    CERN Document Server

    Tang, Haolan

    2015-01-01

    Iron-60 (t1/2=2.62 Myr) is a short-lived nuclide that can help constrain the astrophysical context of solar system formation and date early solar system events. A high abundance of 60Fe (60Fe/56Fe= 4x10-7) was reported by in situ techniques in some chondrules from the LL3.00 Semarkona meteorite, which was taken as evidence that a supernova exploded in the vicinity of the birthplace of the Sun. However, our previous MC-ICPMS measurements of a wide range of meteoritic materials, including chondrules, showed that 60Fe was present in the early solar system at a much lower level (60Fe/56Fe=10-8). The reason for the discrepancy is unknown but only two Semarkona chondrules were measured by MC-ICPMS and these had Fe/Ni ratios below ~2x chondritic. Here, we show that the initial 60Fe/56Fe ratio in Semarkona chondrules with Fe/Ni ratios up to ~24x chondritic is 5.4x10-9. We also establish the initial 60Fe/56Fe ratio at the time of crystallization of the Sahara 99555 angrite, a chronological anchor, to be 1.97x10-9. The...

  2. The multilayer Fe/Hf studied with slow positron beam

    Science.gov (United States)

    Murashige, Y.; Tashiro, M.; Nakajyo, T.; Koizumi, T.; Kanazawa, I.; Komori, F.; Ito, Y.

    1997-04-01

    The positron annihilation parameter versus the incident positron energy is measured in the thin Fe films and the Fe/Hf bilayer on silica substrate, by means of the variable energetic slow-positron beam technique. We have analyzed the change in open-volume spaces and vacancy-type defects among the Fe microcrystals in these thin films with the deposition temperature.

  3. Infrared [Fe II] Emission Lines from Radiative Atomic Shocks

    CERN Document Server

    Koo, Bon-Chul; Kim, Hyun-Jeong

    2016-01-01

    [Fe II] emission lines are prominent in the infrared (IR), and they are important diagnostic tools for radiative atomic shocks. We investigate the emission characteristics of [Fe II] lines using a shock code developed by Raymond (1979) with updated atomic parameters. We first review general characteristics of IR [Fe II] emission lines from shocked gas, and derive [Fe II] line fluxes as a function of shock speed and ambient density. We have compiled the available IR [Fe II] line observations of interstellar shocks and compare them to the ratios predicted from our model. The sample includes both young and old supernova remnants in the Galaxy and the Large Magellanic Cloud and several Herbig-Haro objects. We find that the observed ratios of IR [Fe II] lines generally fall on our grid of shock models, but the ratios of some mid-infrared lines, e.g., [Fe II] 35.35 um/[Fe II] 25.99 um, [Fe II] 5.340 um/[Fe II] 25.99 um, and [Fe II] 5.340 um/[Fe II] 17.94 um, are significantly offset from our model grid. We discuss ...

  4. Evolutionary analysis of iron (Fe) acquisition system in Marchantia polymorpha.

    Science.gov (United States)

    Lo, Jing-Chi; Tsednee, Munkhtsetseg; Lo, Ying-Chu; Yang, Shun-Chung; Hu, Jer-Ming; Ishizaki, Kimitsune; Kohchi, Takayuki; Lee, Der-Chuen; Yeh, Kuo-Chen

    2016-07-01

    To acquire appropriate iron (Fe), vascular plants have developed two unique strategies, the reduction-based strategy I of nongraminaceous plants for Fe(2+) and the chelation-based strategy II of graminaceous plants for Fe(3+) . However, the mechanism of Fe uptake in bryophytes, the earliest diverging branch of land plants and dominant in gametophyte generation is less clear. Fe isotope fractionation analysis demonstrated that the liverwort Marchantia polymorpha uses reduction-based Fe acquisition. Enhanced activities of ferric chelate reductase and proton ATPase were detected under Fe-deficient conditions. However, M. polymorpha did not show mugineic acid family phytosiderophores, the key components of strategy II, or the precursor nicotianamine. Five ZIP (ZRT/IRT-like protein) homologs were identified and speculated to be involved in Fe uptake in M. polymorpha. MpZIP3 knockdown conferred reduced growth under Fe-deficient conditions, and MpZIP3 overexpression increased Fe content under excess Fe. Thus, a nonvascular liverwort, M. polymorpha, uses strategy I for Fe acquisition. This system may have been acquired in the common ancestor of land plants and coopted from the gametophyte to sporophyte generation in the evolution of land plants. © 2016 The Authors. New Phytologist © 2016 New Phytologist Trust.

  5. Thermodynamic assessment of the La-Fe-O system

    DEFF Research Database (Denmark)

    Povoden-Karadeniz, E.; Grundy, A.N.; Chen, Ming

    2009-01-01

    The La-Fe and the La-Fe-O systems are assessed using the Calphad approach, and the Gibbs energy functions of ternary oxides are presented. Oxygen and mutual La and Fe solubilities in body-centered cubic (bcc) and face-centered cubic (fcc) structured metallic phases are considered in the modeling....

  6. Fe(z+) (z = 1-6) generation from ferrocene.

    Science.gov (United States)

    Yatsuhashi, Tomoyuki; Murakami, Eri; Nakashima, Nobuaki

    2011-03-14

    Multiply charged iron atoms up to Fe(6+) with few carbon ions were produced from ferrocene under intense femtosecond laser fields. The production of Fe(4+) and Fe(5+) from ferrocene requires much less laser intensity than theoretically expected for iron atoms. The dissociation of ferrocene and the generation mechanism of multiply charged iron atoms are discussed.

  7. ELECTROLYSIS OF SWINE MANURE EFFLUENTS USING THREE DIFFERENT ELECTRODES Fe-Fe, Al-Al AND Fe-Al

    Directory of Open Access Journals (Sweden)

    S. Rahman

    2014-01-01

    Full Text Available Swine effluent with high organic strength need to be treated to make it suitable for applying to crop/pasture fields, or discharging to any waterways. Electrocoagulation is a relatively simpler and cheaper technique over biological and chemical treatment methods currently used to treat high-strength industrial and municipal wastewater. The performance of an electrocoagulation system mainly depends on the pH, Electrical Conductivity (EC of the medium, Chemical Oxygen Demand (COD loading rates and catalytic activity of the electrodes used. In this research, a study was conducted to compare the pollutant removal efficiencies of three electrodes (Fe-Fe, Al-Al and Fe-Al with three electric current levels (500, 1000 and 2000 mA while treating swine manure effluents. The electrochemical cell consisted of two parallel rectangular plates (90×25×1.5 mm of Iron (Fe-Fe, Aluminum (Al-Al and Iron-Aluminum (Fe-Al, later on described as hybrid electrodes; immersed in a beaker with 550 mL swine effluents and powered by a Direct Current (DC supply. All studies were conducted in batches at room temperature. In general, removal efficiencies were increased with increasing current densities and electrolysis times for electrodes evaluated. Aluminum electrodes outperformed iron and hybrid (iron-aluminum electrodes in removing Total Phosphorus (TP at all current density levels tested. Overall, use of hybrid electrodes resulted in better COD removal. For the same treatment times (1200 s at higher current density (21 mA cm-2, hybrid electrodes removed about 100% COD, which are about 1.9 and 1.3 times higher than those of aluminum and iron electrodes, respectively. Iron electrodes showed the highest removal efficiency (85% for Total Organic Carbon (TOC at 21 mA cm-2 current density and 1200 s treatment time. Overall, lower Specific Electrical Energy Consumptions (SEECs per kg of Pollutants (TP, COD and TOC were estimated for the aluminum

  8. The Property of Phonon Gap in Iron-Based Superconductors FeSe, LiFeAs and SrFeAsF

    Science.gov (United States)

    Wang, Wei; Li, Bin; He, Junqi; Sun, Jiafa

    2017-03-01

    First-principles calculations are performed for iron-based superconductors FeSe, LiFeAs and SrFeAsF, and the reasons of generation and loss of the phonon gaps in them are analyzed by analogy with electronic energy band theory. In iron-based superconductors FeSe and LiFeAs, lattice vibrations are affected by so strong changes in the periodic potential that the phonon spectra open a full gap. After considering electron-spin interactions, the enhancement of the periodic potential results in a broadening of the gap. From binary FeSe to ternary LiFeAs to quaternary SrFeAsF, the full phonon gap undergoes the process from decrease to disappearance, which is closely related to the frequencies overlapping of different atoms by vibrations. The fewer the material components and the larger the atomic number ratio, the more possible the production of the full phonon gap or the appearance of wider gap. In addition, the phonon gaps of FeSe and LiFeAs locate around the frequency of 10^{12} Hz, whose filtering properties for elastic waves are hopefully to be applied in quantum acoustics.

  9. The Property of Phonon Gap in Iron-Based Superconductors FeSe, LiFeAs and SrFeAsF

    Science.gov (United States)

    Wang, Wei; Li, Bin; He, Junqi; Sun, Jiafa

    2016-12-01

    First-principles calculations are performed for iron-based superconductors FeSe, LiFeAs and SrFeAsF, and the reasons of generation and loss of the phonon gaps in them are analyzed by analogy with electronic energy band theory. In iron-based superconductors FeSe and LiFeAs, lattice vibrations are affected by so strong changes in the periodic potential that the phonon spectra open a full gap. After considering electron-spin interactions, the enhancement of the periodic potential results in a broadening of the gap. From binary FeSe to ternary LiFeAs to quaternary SrFeAsF, the full phonon gap undergoes the process from decrease to disappearance, which is closely related to the frequencies overlapping of different atoms by vibrations. The fewer the material components and the larger the atomic number ratio, the more possible the production of the full phonon gap or the appearance of wider gap. In addition, the phonon gaps of FeSe and LiFeAs locate around the frequency of 10^{12} Hz, whose filtering properties for elastic waves are hopefully to be applied in quantum acoustics.

  10. Magnetic Properties and Nanostructures of FePtCu:C Thin Films with FePt Underlayers

    Institute of Scientific and Technical Information of China (English)

    JIN Ling-Fang; YAN Ming-Lang

    2007-01-01

    Magnetic properties and nanostructures of FePtCu:C thin films with FePt underlayers (ULs) are studied. The effect of FePt ULs on the orientation and magnetic properties of the thin films are investigated by adjusting FePt UL thicknesses from 2nm to 14nm. X-ray diffraction (XRD) scans reveal that the orientation of the films is dependent on FePt UL thickness. For a 5-nm FePtCu:C nanocomposite thin film with a 2-nm FePt UL, the coercivity is 6.5 KOe, the correlation length is 59nm, the desired face-centred-tetragonal (fct) ordered structure [L10 phase] is formed and the c axis normal to the film plane [(001) texture] is obtained. These results indicate that the better orientation and magnetic properties of the films can be tuned by decreasing the thickness of the FePt UL.

  11. Magnetism and site exchange in CuFeAs and CuFeSb: A microscopic and theoretical investigation

    Science.gov (United States)

    Kamusella, Sirko; Klauss, Hans-Henning; Thakur, Gohil S.; Haque, Zeba; Gupta, Laxmi C.; Ganguli, Ashok K.; Kraft, Inga; Burkhardt, Ulrich; Rosner, Helge; Luetkens, Hubertus; Lynn, Jeffrey W.; Zhao, Yang

    2017-03-01

    We have investigated the magnetic ground state of CuFeAs and CuFeSb by means of 57Fe-Mössbauer spectroscopy, muon spin rotation/relaxation (μ SR ), neutron diffraction, and electronic structure calculations. Both materials share the 111-LiFeAs crystal structure and are closely related to the class of iron-based superconductors. In both materials there is a considerable occupancy of the Cu site by Fe, which leads to ferromagnetic moments, which are magnetically strongly coupled to the regular Fe site magnetism. Our study shows that CuFeAs is close to an antiferromagnetic instability, whereas a ferromagnetic ground state is observed in CuFeSb, supporting theoretical models of anion height driven magnetism.

  12. Thermodynamic Description Of Ternary Fe-B-X Systems. Part 2: Fe-B-Ni

    Directory of Open Access Journals (Sweden)

    Miettinen J.

    2014-06-01

    Full Text Available Przedstawiono termodynamiczny opis trójskładnikowego układu Fe-B-Ni w kontekście nowej bazy danych dla układów Fe-B-X (X = Cr, Ni, Mn, Si, Ti, V, C. Parametry termodynamiczne dwuskładnikowych stopów Fe-B. Fe-Ni i B-Ni zostały są zaczerpnięte z wcześniejszych opracowań, przy tym opis B-Ni został nieznacznie zmodyfikowany. Parametry dla układu Fe-B-Ni zostały zoptymalizowane w tej pracy w oparciu o eksperymentalne równowagi fazowe i dane termodynamiczne zaczerpnięte z literatury. Roztwory stałe w układzie Fe-B-Ni opisano przy użyciu modelu roztworu substytucyjnego, a borki traktowane są jako fazy stechiometryczne lub półstechiometryczne typu (A.BpCq opisane przy użyciu modelu dwu podsieci.

  13. Wear resistant Fe-base alloys with niobium carbide; Verschleissbestaendige Fe-Basislegierungen mit Niobkarbid

    Energy Technology Data Exchange (ETDEWEB)

    Theisen, W. [Lehrstuhl Werkstofftechnik, Institut fuer Werkstoffe, Fakultaet fuer Maschinenbau, Ruhr-Universitaet Bochum (Germany)

    2004-06-01

    Martensitic Fe-base alloys from the system Fe-Cr-C are widely used as chilled cast irons and tool steels. Because of the low hardness of their FeCr-carbides this paper reports about new alloys with primarily solidified harder niobium carbides. It focuses on a secondary hardenable welding alloy, a coating material for composite castings, a chilled casting and a corrosion resistant cold work tool steel, which are investigated with respect to their process related microstructure and abrasive wear behaviour. (Abstract Copyright [2004], Wiley Periodicals, Inc.) [German] Martensitische Fe-Basislegierungen des Systems Fe-Cr-C finden heute als Hartguss und Werkzeugstahl vielfaeltige Anwendung. Da ihre FeCr-Karbide ueber eine relativ geringe Haerte verfuegen, wird in diesem Beitrag ueber neue Legierungen mit primaer ausgeschiedenen haerteren Niobkarbiden berichtet. Im Mittelpunkt stehen eine sekundaer haertende, rissfrei aufschweissbare Hartlegierung, eine warmfester Schichtwerkstoff fuer Verbundguss, ein weisses Gusseisen und ein korrosionsbestaendiger Kaltarbeitsstahl, die hinsichtlich ihrer herstellungsbedingten Gefuege analysiert und bezueglich Furchungsverschleiss untersucht wurden. (Abstract Copyright [2004], Wiley Periodicals, Inc.)

  14. Spin-valve magnetization reversal obtained by N-doping in Fe/insulator/Fe trilayers

    Energy Technology Data Exchange (ETDEWEB)

    Georgieva, M T [Joule Physics Laboratory, Institute for Materials Research, University of Salford, Salford (United Kingdom); Telling, N D [Joule Physics Laboratory, Institute for Materials Research, University of Salford, Salford (United Kingdom); Jones, G A [Joule Physics Laboratory, Institute for Materials Research, University of Salford, Salford (United Kingdom); Grundy, P J [Joule Physics Laboratory, Institute for Materials Research, University of Salford, Salford (United Kingdom); Hase, T P A [Department of Physics, University of Durham, South Road, Durham (United Kingdom); Tanner, B K [Department of Physics, University of Durham, South Road, Durham (United Kingdom)

    2003-02-05

    The effect of N-doping on the microstructure and coercivity of the 'free' Fe layer in Fe/insulator/Fe trilayers has been examined. It was found that N-doping leads to a magnetic softening of the Fe layer and a corresponding reduction in the grain size. Hard/soft spin-valve trilayers, showing good independent layer reversal, were obtained using N-doped and undoped Fe layers. Ferromagnetic interlayer coupling was found in these trilayers that could be well described by a Neel coupling mechanism. Nonuniform reversal of the harder Fe layer, once incorporated in the trilayer, was also observed and could be reproduced using a simple model in which local variations in the interlayer coupling energy are considered. Such variations are likely to be caused by structural inhomogeneity in the films. N-doping is potentially important as a method for tailoring the coercivity of the 'free' layer in spin-valves comprising high-polarization magnetic materials.

  15. Corrosion performance of Fe-Cr-Al and Fe aluminide alloys in complex gas environments

    Energy Technology Data Exchange (ETDEWEB)

    Natesan, K. [Argonne National Lab., IL (United States); Johnson, R.N. [Pacific Northwest Lab., Richland, WA (United States)

    1995-05-01

    Alumina-forming structural alloys can offer superior resistance to corrosion in the presence of sulfur-containing environments, which are prevalent in coal-fired fossil energy systems. Further, Fe aluminides are being developed for use as structural materials and/or cladding alloys in these systems. Extensive development has been in progress on Fe{sub 3}Al-based alloys to improve their engineering ductility. In addition, surface coatings of Fe aluminide are being developed to impart corrosion resistance to structural alloys. This paper describes results from an ongoing program that is evaluating the corrosion performance of alumina-forming structural alloys, Fe-Al and Fe aluminide bulk alloys, and Fe aluminide coatings in environments typical of coal-gasification and combustion atmospheres. Experiments were conducted at 650-1000{degrees}C in simulated oxygen/sulfur gas mixtures. Other aspects of the program are corrosion evaluation of the aluminides in the presence of HCl-containing gases. Results are used to establish threshold Al levels in the alloys for development of protective alumina scales and to determine the modes of corrosion degradation that occur in the materials when they are exposed to S/Cl-containing gaseous environments.

  16. An evaluation of the Fe-N phase diagram considering long-range order of N atoms in gamma'-Fe4N1-x and epsilon-Fe2N1-z

    NARCIS (Netherlands)

    Kooi, BJ; Somers, MAJ; Mittemeijer, EJ

    1996-01-01

    The chemical potential of nitrogen was described asa function of nitrogen content for the Fe-N phases alpha-FE[N], gamma'-Fe4N1-x, and epsilon-Fe2N1-x. For alpha-Fe[N], an ideal random distribution of the nitrogen atoms over the octahedral interstices of the bcc iron lattice was assumed; for gamma'-

  17. Exchange coupling behavior in bimagnetic CoFe{sub 2}O{sub 4}/CoFe{sub 2} nanocomposite

    Energy Technology Data Exchange (ETDEWEB)

    Leite, G.C.P. [Instituto de Fisica, Universidade Federal de Mato Grosso, 78060-900 Cuiaba-MT (Brazil); Chagas, E.F., E-mail: efchagas@fisica.ufmt.br [Instituto de Fisica, Universidade Federal de Mato Grosso, 78060-900 Cuiaba-MT (Brazil); Pereira, R.; Prado, R.J. [Instituto de Fisica, Universidade Federal de Mato Grosso, 78060-900 Cuiaba-MT (Brazil); Terezo, A.J. [Departamento de Quimica, Universidade Federal do Mato Grosso, 78060-900 Cuiaba-MT (Brazil); Alzamora, M.; Baggio-Saitovitch, E. [Centro Brasileiro de Pesquisas Fisicas, Rua Xavier Sigaud 150 Urca, Rio de Janeiro (Brazil)

    2012-09-15

    In this work we report a study of the magnetic behavior of ferrimagnetic oxide CoFe{sub 2}O{sub 4} and ferrimagnetic oxide/ferromagnetic metal CoFe{sub 2}O{sub 4}/CoFe{sub 2} nanocomposite. The latter compound is a good system to study hard ferrimagnet/soft ferromagnet exchange coupled. Two steps were followed to synthesize the bimagnetic CoFe{sub 2}O{sub 4}/CoFe{sub 2} nanocomposite: (i) first, preparation of CoFe{sub 2}O{sub 4} nanoparticles using a simple hydrothermal method, and (ii) second, reduction reaction of cobalt ferrite nanoparticles using activated charcoal in inert atmosphere and high temperature. The phase structures, particle sizes, morphology, and magnetic properties of CoFe{sub 2}O{sub 4} nanoparticles were investigated by X-Ray diffraction (XRD), Mossbauer spectroscopy (MS), transmission electron microscopy (TEM), and vibrating sample magnetometer (VSM) with applied field up to 3.0 kOe at room temperature and 50 K. The mean diameter of CoFe{sub 2}O{sub 4} particles is about 16 nm. Mossbauer spectra revealed two sites for Fe{sup 3+}. One site is related to Fe in an octahedral coordination and the other one to the Fe{sup 3+} in a tetrahedral coordination, as expected for a spinel crystal structure of CoFe{sub 2}O{sub 4}. TEM measurements of nanocomposite showed the formation of a thin shell of CoFe{sub 2} on the cobalt ferrite and indicate that the nanoparticles increase to about 100 nm. The magnetization of the nanocomposite showed a hysteresis loop that is characteristic of exchange coupled systems. A maximum energy product (BH){sub max} of 1.22 MGOe was achieved at room temperature for CoFe{sub 2}O{sub 4}/CoFe{sub 2} nanocomposites, which is about 115% higher than the value obtained for CoFe{sub 2}O{sub 4} precursor. The exchange coupling interaction and the enhancement of product (BH){sub max} in nanocomposite CoFe{sub 2}O{sub 4}/CoFe{sub 2} are discussed. - Highlights: Black-Right-Pointing-Pointer CoFe{sub 2}O{sub 4}/CoFe{sub 2} nanocomposite

  18. Recent experimental and analytical results on hydrogen combustion at RRC {open_quotes}Kurchatov Institute{close_quotes}

    Energy Technology Data Exchange (ETDEWEB)

    Dorofeev, S.B.; Efimenko, A.A.; Kochurko, A.S.; Sidorov, V.P. [Kurchatov Institute, Moscow (Russian Federation)

    1996-03-01

    A review of hydrogen combustion research at Kurchatov Institute is presented. Criterion for spontaneous detonation onset possibility and its application to severe accidents in a nuclear power plant is discussed. Theoretical and experimental results on spontaneous detonation onset conditions are summarized. Three series of large scale turbulent jet initiation experiments have been carried out in KOPER facility (50 m{sup 3} and 150 m{sup 3}). Series of jet initiation experiments in initially confined H{sub 2} - air mixtures have been carried out in KOPER facility (20-46 m{sup 3}). Turbulent deflagration/DDT experiments were carried out in large scale confined volume of 480 m{sup 3} in RUT facility. Results showed, that the characteristic volume size should be used for conservative estimates in accident analysis. Series of experiments on detonation transition from one mixture to another of lower sensitivity has been carried in DRIVER facility. The experiments were aimed on the estimation of the minimum size of a detonation kernel. The received results are in a good agreement with the 7 cell width criterion. Results of combined hydrogen injection/ignition experiments are presented. The experiments are aimed on the investigation of possible consequences of deliberate ignition at dynamic conditions. Analysis of the experimental data showed applicability of 7 cell width criterion to dynamic conditions. The sum of the results on the scaling of spontaneous detonations is discussed in connection with the strategy of hydrogen mitigation at severe accidents.

  19. Modes of planetary-scale Fe isotope fractionation

    Science.gov (United States)

    Schoenberg, Ronny; Blanckenburg, Friedhelm von

    2006-12-01

    A comprehensive set of high-precision Fe isotope data for the principle meteorite types and silicate reservoirs of the Earth is used to investigate iron isotope fractionation at inter- and intra-planetary scales. 14 chondrite analyses yield a homogeneous Fe isotope composition with an average δ56Fe/ 54Fe value of - 0.015 ± 0.020‰ (2 SE) relative to the international iron standard IRMM-014. Eight non-cumulate and polymict eucrite meteorites that sample the silicate portion of the HED (howardite-eucrite-diogenite) parent body yield an average δ56Fe/ 54Fe value of - 0.001 ± 0.017‰, indistinguishable to the chondritic Fe isotope composition. Fe isotope ratios that are indistinguishable to the chondritic value have also been published for SNC meteorites. This inner-solar system homogeneity in Fe isotopes suggests that planetary accretion itself did not significantly fractionate iron. Nine mantle xenoliths yield a 2 σ envelope of - 0.13‰ to + 0.09‰ in δ56Fe/ 54Fe. Using this range as proxy for the bulk silicate Earth in a mass balance model places the Fe isotope composition of the outer liquid core that contains ca. 83% of Earth's total iron to within ± 0.020‰ of the chondritic δ56Fe/ 54Fe value. These calculations allow to interprete magmatic iron meteorites ( δ56Fe/ 54Fe = + 0.047 ± 0.016‰; N = 8) to be representative for the Earth's inner metallic core. Eight terrestrial basalt samples yield a homogeneous Fe isotope composition with an average δ56Fe/ 54Fe value of + 0.072 ± 0.016‰. The observation that terrestrial basalts appear to be slightly heavier than mantle xenoliths and that thus partial mantle melting preferentially transfers heavy iron into the melt [S. Weyer, A.D. Anbar, G.P. Brey, C. Munker, K. Mezger and A.B. Woodland, Iron isotope fractionation during planetary differentiation, Earth and Planetary Science Letters 240(2), 251-264, 2005.] is intriguing, but also raises some important questions: first it is questionable whether the

  20. Spectroscopic evidence for Fe(II)-Fe(III) electron transfer at clay mineral edge and basal sites.

    Science.gov (United States)

    Neumann, Anke; Olson, Tyler L; Scherer, Michelle M

    2013-07-02

    Despite the importance of Fe redox cycling in clay minerals, the mechanism and location of electron transfer remain unclear. More specifically, there is some controversy whether electron transfer can occur through both basal and edge surfaces. Here we used Mössbauer spectroscopy combined with selective chemical extractions to study electron transfer from Fe(II) sorbed to basal planes and edge OH-groups of clay mineral NAu-1. Fe(II) sorbed predominantly to basal planes at pH values below 6.0 and to edge OH-groups at pH value 7.5. Significant electron transfer occurred from edge OH-group bound Fe(II) at pH 7.5, whereas electron transfer from basal plane-sorbed Fe(II) to structural Fe(III) in clay mineral NAu-1 at pH 4.0 and 6.0 occurred but to a much lower extent than from edge-bound Fe(II). Mössbauer hyperfine parameters for Fe(II)-reacted NAu-1 at pH 7.5 were consistent with structural Fe(II), whereas values found at pH 4.0 and 6.0 were indicative of binding environments similar to basal plane-sorbed Fe(II). Reference experiments with Fe-free synthetic montmorillonite SYn-1 provided supporting evidence for the assignment of the hyperfine parameters to Fe(II) bound to basal planes and edge OH-groups. Our findings demonstrate that electron transfer to structural Fe in clay minerals can occur from Fe(II) sorbed to both basal planes and edge OH-groups. These findings require us to reassess the mechanisms of abiotic and microbial Fe reduction in clay minerals as well as the importance of Fe-bearing clay minerals as a renewable source of redox equivalents in subsurface environments.

  1. Standard molar enthalpy of formation of FeGe(s) and FeGe{sub 2}(s) intermetallic compounds

    Energy Technology Data Exchange (ETDEWEB)

    Phapale, S. [Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India); Mishra, R., E-mail: mishrar@barc.gov.in [Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India); Chattaraj, D.; Samui, P. [Product Development Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India); Sengupta, P. [Material Science Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India); Mishra, P.K. [Technical Physics Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India)

    2014-04-05

    Highlights: • FeGe(s) and FeGe{sub 2}(s) have been synthesized and characterized. • The heat of dissolutions of Fe(s), Ge(s), FeGe(s) and FeGe2(s) in liquid tin have been measured. • Δ{sub f}H{sub 298}{sup °} of FeGe, FeGe{sub 2} were found to be to −15.56 ± 0.92 and −36.89 ± 1.17 kJ mol{sup −1}, respectively. -- Abstract: Thermodynamics plays an important role in predicting long term stability of the materials under different reactive conditions. The present paper describes determination of standard molar enthalpies of formation of FeGe(s) and FeGe{sub 2}(s) compounds employing a high temperature solution calorimeter. The reaction enthalpies of Fe(s), Ge(s), FeGe(s) and FeGe{sub 2}(s) in liquid Sn at 986 K were measured using a Calvet calorimeter. The standard molar enthalpy of formation of the compounds at 298 K (Δ{sub f}H{sub 298}{sup °}) were calculated using the measured reaction enthalpy data. The values of Δ{sub f}H{sub 298}{sup °} of FeGe(s) and FeGe{sub 2}(s) at 298 K were found to −15.56 ± 0.92 and −36.89 ± 1.17 kJ mol{sup −1}, respectively. The standard molar enthalpy of formation of FeGe(s) and FeGe{sub 2}(s) at 298 K obtained experimentally has been compared with the calculated values derived using Vienna ab initio simulation package (VASP)

  2. New redox states observed in [FeFe] hydrogenases reveal redox coupling within the H-cluster.

    Science.gov (United States)

    Adamska-Venkatesh, Agnieszka; Krawietz, Danuta; Siebel, Judith; Weber, Katharina; Happe, Thomas; Reijerse, Edward; Lubitz, Wolfgang

    2014-08-13

    Active [FeFe] hydrogenases can be obtained by expressing the unmaturated enzyme in Escherichia coli followed by incubation with a synthetic precursor of the binuclear [2Fe] subcluster, namely: [NEt4]2[Fe2(adt)(CO)4(CN)2] (adt = [S-CH2-NH-CH2-S](2-)). The binuclear subsite Fe2(adt)(CO)3(CN)2 is attached through a bridging cysteine side chain to a [4Fe-4S] subcluster already present in the unmaturated enzyme thus yielding the intact native "H-cluster". We present FTIR electrochemical studies of the [FeFe] hydrogenase from Chlamydomonas reinhardtii, CrHydA1, maturated with the precursor of the native cofactor [Fe2(adt)(CO)4(CN)2](2-) as well as a non-natural variant [Fe2(pdt)(CO)4(CN)2](2-) in which the bridging amine functionality is replaced by CH2. The obtained active enzyme CrHydA1(adt) shows the same redox states in the respective potential range as observed for the native system (E(ox/red) = -400 mV, E(red/sred) = -470 mV). For the Hox → Hred transition the reducing equivalent is stored on the binuclear part, ([4Fe-4S](2+)Fe(II)Fe(I) → [4Fe-4S](2+)Fe(I)Fe(I)), while the Hred → Hsred transition is characterized by a reduction of the [4Fe-4S] part of the H-cluster ([4Fe-4S](2+)Fe(I)Fe(I) → [4Fe-4S](+)Fe(I)Fe(I)). A similar transition is reported here for the CO inhibited state of the H-cluster: ([4Fe-4S](2+)Fe(I)Fe(II)CO → [4Fe-4S](+)Fe(I)Fe(II)CO). An FTIR electrochemical study of the inactive variant with the pdt ligand, CrHydA1(pdt), identified two redox states H(pdt)-ox and H(pdt)-"red". Both EPR and FTIR spectra of H(pdt)-ox are virtually identical to those of the H(adt)-ox and the native Hox state. The H(pdt)-"red" state is also characterized by a reduced [4Fe-4S] subcluster. In contrast to CrHydA1(adt), the H(pdt)-ox state of CrHydA1(pdt) is stable up to rather high potentials (+200 mV). This study demonstrates the distinct redox coupling between the two parts of the H-cluster and confirms that the [4Fe-4S]H subsite is also redox active and as

  3. Low 60Fe Abundance in Semarkona and Sahara 99555

    Science.gov (United States)

    Tang, Haolan; Dauphas, Nicolas

    2015-03-01

    Iron-60 (t1/2 = 2.62 Myr) is a short-lived nuclide that can help constrain the astrophysical context of Solar System formation and date early Solar System events. A high abundance of 60Fe(60Fe/56Fe ≈ 4 × 10-7) was reported by in situ techniques in some chondrules from the LL3.00 Semarkona meteorite, which was taken as evidence that a supernova exploded in the vicinity of the birthplace of the Sun. However, our previous multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS) measurements of a wide range of meteoritic materials, including chondrules, showed that 60Fe was present in the early Solar System at a much lower level (60Fe/56Fe ≈ 10-8). The reason for the discrepancy is unknown but only two Semarkona chondrules were measured by MC-ICPMS and these had Fe/Ni ratios below ˜2× chondritic. Here, we show that the initial 60Fe/56Fe ratio in Semarkona chondrules with Fe/Ni ratios up to ˜24× chondritic is (5.39 ± 3.27) × 10-9. We also establish the initial 60Fe/56Fe ratio at the time of crystallization of the Sahara 99555 angrite, a chronological anchor, to be (1.97 ± 0.77) × 10-9. These results demonstrate that the initial abundance of 60Fe at Solar System birth was low, corresponding to an initial 60Fe/56Fe ratio of (1.01 ± 0.27) × 10-8.

  4. LOW {sup 60}FE ABUNDANCE IN SEMARKONA AND SAHARA 99555

    Energy Technology Data Exchange (ETDEWEB)

    Tang, Haolan; Dauphas, Nicolas, E-mail: haolantang@ucla.edu [Origins Lab, Department of the Geophysical Sciences and Enrico Fermi Institute, The University of Chicago, 5734 South Ellis Avenue, Chicago IL 60637 (United States)

    2015-03-20

    Iron-60 (t{sub 1/2} = 2.62 Myr) is a short-lived nuclide that can help constrain the astrophysical context of Solar System formation and date early Solar System events. A high abundance of {sup 60}Fe({sup 60}Fe/{sup 56}Fe ≈ 4 × 10{sup −7}) was reported by in situ techniques in some chondrules from the LL3.00 Semarkona meteorite, which was taken as evidence that a supernova exploded in the vicinity of the birthplace of the Sun. However, our previous multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS) measurements of a wide range of meteoritic materials, including chondrules, showed that {sup 60}Fe was present in the early Solar System at a much lower level ({sup 60}Fe/{sup 56}Fe ≈ 10{sup −8}). The reason for the discrepancy is unknown but only two Semarkona chondrules were measured by MC-ICPMS and these had Fe/Ni ratios below ∼2× chondritic. Here, we show that the initial {sup 60}Fe/{sup 56}Fe ratio in Semarkona chondrules with Fe/Ni ratios up to ∼24× chondritic is (5.39 ± 3.27) × 10{sup −9}. We also establish the initial {sup 60}Fe/{sup 56}Fe ratio at the time of crystallization of the Sahara 99555 angrite, a chronological anchor, to be (1.97 ± 0.77) × 10{sup −9}. These results demonstrate that the initial abundance of {sup 60}Fe at Solar System birth was low, corresponding to an initial {sup 60}Fe/{sup 56}Fe ratio of (1.01 ± 0.27) × 10{sup −8}.

  5. Using in vitro maturation and cell-free expression to explore [FeFe] hydrogenase activation and protein scaffolding requirements

    Energy Technology Data Exchange (ETDEWEB)

    Swartz, James [Stanford Univ., CA (United States)

    2017-01-25

    Final Project Report describing work to elucidate mechanisms for the activation of [FeFe]-hydrogenases and to explore the impact of the polypeptide scaffolding on the function of the Fe-S redox and catalytic centers with emphasis on improving oxygen tolerance.

  6. Physiological responses in roots of the grapevine rootstock 140 Ruggeri subjected to Fe deficiency and Fe-heme nutrition.

    Science.gov (United States)

    López-Rayo, Sandra; Di Foggia, Michele; Rodrigues Moreira, Erica; Donnini, Silvia; Bombai, Giuseppe; Filippini, Gianfranco; Pisi, Annamaria; Rombolà, Adamo D

    2015-11-01

    Iron (Fe)-heme containing fertilizers can effectively prevent Fe deficiency. This paper aims to investigate root physiological responses after a short period of Fe-heme nutrition and Fe deficiency under two pH conditions (with or without HEPES) in the Fe chlorosis-tolerant grapevine rootstock 140 Ruggeri. Organic acids in root exudates, Fe reduction capacity, both roots and root exudates contributions, together with other physiological parameters associated to plant Fe status were evaluated in plants grown in hydroponics. Analyses of root tips by SEM, and Raman and IR spectra of the precipitates of Fe-heme fertilizers were performed. The physiological responses adopted by the tolerant 140 Ruggeri to the application of Fe-heme indicated an increased Fe reduction capacity of the roots. This is the first report showing oxalic, tartaric, malic and ascorbic as major organic acids in Vitis spp. root exudates. Plants reacted to Fe deficiency condition exuding a higher amount of ascorbic acid in the rhizosphere. The presence of HEPES in the medium favoured the malic acid exudation. The lowest concentration of oxalic acid was found in exudates of plants subjected to Fe-heme and could be associated to a higher accumulation in their root tips visualized by SEM analysis. Copyright © 2015 Elsevier Masson SAS. All rights reserved.

  7. Effect of Fe(Ⅲ) impurity on the electrochemical performance of LiFePO4 prepared by hydrothermal process

    Institute of Scientific and Technical Information of China (English)

    OU XiuQin; XU ShengZhao; LIANG GuangChuan; WANG Li; ZHAO Xia

    2009-01-01

    Lithium iron phosphate (LiFePO4) was synthesized from LiOH, FeSO4 and HaPO4 by a hydrothermal process at 180℃. The samples were characterized by X-ray diffraction, scanning electron microscopy and chemical analysis. Electrochemical performance of the samples was tested in terms of charge-discharge capacity and cycling behavior. The results indicated that Fe(Ⅲ) impurity had obvi-ously effect on the electrochemical properties of LiFePO4, and the formation of Fe3+ was caused by the oxidation of Fe2+ in the dissolving and feeding processes accompanying the increase of pH value. It was found that the precipitation separation was effective in decreasing the content of Fe3+ in the solu-tion of FeSO4 and the sealed feeding was useful in preventing the conversion of Fe2+ to Fe3+. When the content of Fe3+ < 0.5 wt%, the hydrothermaUy synthesized LiFePO4 calcined at 750℃ with sucrose as.

  8. The activation mechanism of Fe-based olefin metathesis catalysts

    Science.gov (United States)

    Poater, Albert; Pump, Eva; Vummaleti, Sai Vikrama Chaitanya; Cavallo, Luigi

    2014-08-01

    Density functional theory calculations have been used to describe the first turnover for olefin metathesis reaction of a homogenous Fe-based catalyst bearing a N-heterocyclic carbene ligand with methoxyethene as a substrate. Equal to conventional Ru-based catalysts, the activation of its Fe congener occurs through a dissociative mechanism, however with a more exothermic reaction energy profile. Predicted upper energy barriers were calculated to be on average ∼2 kcal/mol more beneficial for Fe catalyzed metathesis. Overall, this present computational study emphasises on advantages of Fe-based metathesis and gives a potential recipe for the design of an efficient Fe-based olefin metathesis catalysts.

  9. Electrical studies of Fe-related defect complexes in silicon

    Energy Technology Data Exchange (ETDEWEB)

    Tang, Chi Kwong

    2012-09-15

    Iron (Fe) is an important impurity in solar-grade silicon which contributes substantially in degrading the efficiency of solar cells. The degradation is mainly caused by the Fe atoms situating at an unperturbed tetrahedral interstitial sites (Fei) in the silicon crystal, consequently acting as a recombination center. By altering the position and the neighbouring environment at which the Fe atoms reside, there are opportunities in minimizing or neutralizing the electrical activity of Fe. Furthermore, utilizing the high mobility of Fe, one can increase the performance of a device by accumulating the Fe atoms from critical regions into regions where Fe can be tolerated. These approaches can help in realizing high efficient solar cells based on cheap and highly Fe-contaminated silicon. In this work, we have investigated the interaction between Fe and defects relevant to solar cells, using mainly electrical characterization methods such as capacitance-voltage measurement, deep level transient spectroscopy and admittance spectroscopy. From the study of potential hydrogen passivation of Fe, hydrogen was introduced through wet chemical etching and further driven to a defined region. Using depth profiles, it is found that incorporation of hydrogen stimulates the dissociation of the iron-boron (Fe-B) pair, releasing and resulting in the unwanted Fei. At the same time, no passivation of Fe by hydrogen has been observed. On the investigation of the mechanism of phosphorus gettering of metal impurities, vacancies have been generated through proton-irradiation. The resulting irradiation-induced defects were examined for reactions with Fe after heat treatments. Based on the evolution of defect concentrations by isochronal annealings, it is found that Fe interacts with the divacancy and the vacancy-oxygen complexes, forming deep levels of 0.28 eV and 0.34 eV above the valence band edge (EV), respectively. In the search for substitutional Fe to investigate its electrical activity

  10. Magnetic properties of nanostructural γ-Ni-28Fe alloy

    Institute of Scientific and Technical Information of China (English)

    LIU Yin; QIN Xiao-ying; QIU Tai

    2006-01-01

    Nanostructural γ-Ni-28Fe alloy (nano γ-Ni-28Fe) was successfully prepared by mechanochemical alloying(MCA). The relationship between the microstructure and the synthesis conditions was investigated by using XRD, TEM, SEM as well as BET analyzer. The results show that nano γ-Ni-28Fe alloy is composed ora gamma phase (FCC structure). Its grain size is about 20 nm at reduction temperature below 600 ℃. The magnetic measurements indicate that the saturation magnetization ofnano γ-Ni-28Fe alloy to its decrease of the grain size and chemical composition in nano γ-Ni-28Fe alloy.

  11. Anomalous Hall effect in epitaxially grown ferromagnetic FeGa/Fe3Ga hybrid structure: Evidence of spin carrier polarized by clusters

    Science.gov (United States)

    Duc Dung, Dang; Cho, Sunglae

    2013-05-01

    The anomalous Hall resistance relative with magnetic anisotropy of clusters Fe3Ga in Fe3Ga/Fe-Ga hybrid structural epitaxial was reported. The out-of-plane magnetic anisotropy was obtained for Fe3Ga/Fe-Ga hybrid structure, while in-plane magnetic anisotropy is shown in the single Fe-Ga phase epitaxial on GaAs(001). The observation of trend of saturation Hall resistance in Fe3Ga/Fe-Ga hybrid structural is compared with the Fe-Ga single crystal, which is solid evidence for spin polarization by local magnetic clusters.

  12. Peptide-based FeS4 complexes: the zinc ribbon fold is unsurpassed to stabilize both the FeII and FeIII states.

    Science.gov (United States)

    Jacques, Aurélie; Latour, Jean-Marc; Sénèque, Olivier

    2014-03-14

    Whereas Zn(Cys)4 zinc fingers exist with different protein folds, only the zinc ribbon fold is found in rubredoxin Fe(Cys)4 sites. To assess the significance of this observation, we have investigated the binding and stability of Fe(2+) and Fe(3+) ions by a set of four peptides designed to model Zn(Cys)4 zinc fingers with various folds, i.e. zinc ribbon, treble clef and a loosened zinc ribbon fold. All peptides were shown by means of UV-Vis and CD spectroscopies to form stable 1 : 1 Fe(II)/peptide complexes with binding constants higher than 10(7) M(-1) at pH 7. Their oxidation into Fe(III) complexes and the stability of the latter were compared. The UV-Vis absorption and CD spectroscopic properties of the Fe(II) and Fe(III) complexes were analysed with respect to the structures of the zinc analogues in order to get insight into the local arrangement of the Fe(Cys)4 core around the metal ion. The chemical stability of these complexes was rationalized according to the shielding from the solvent provided by the various peptide folds to the FeS4 core. In addition, we showed that whereas UV-visible spectra inform only on the FeS4, the information derived from the corresponding CD spectra extend to the Cβ orientation and the peptide fold. The results presented here demonstrate that while the zinc ribbon fold is not strictly required to obtain a Fe(Cys)4 site, it affords a drastically superior protection of the site toward external redox agents. This finding brings new clues to engineer stable and redox-active Fe(Cys)4 sites in de novo proteins.

  13. Magnetic ordering in Fe/Co sandwiches on Cu(100).

    Science.gov (United States)

    Razee, S S A; Staunton, J B; Szunyogh, L

    2009-07-01

    We investigate magnetic correlations and local magnetic moments at finite temperatures of some Fe and Co multilayers on Cu(100) substrates, such as Co(m)Fe(n)Co(m)/Cu(100) and Fe(m)Co(n)Fe(m)/Cu(100). We use an ab initio mean-field theory of magnetic fluctuations for layered materials based on the first-principles local spin-density functional theory implemented through the screened Korringa-Kohn-Rostoker method. We find that the presence of Fe layers in the neighbourhood of a Co layer always leads to a reduction in the magnetic moment of the Co atoms, whereas that of the Fe atoms is enhanced. Of particular interest is the lack of local moment formation on the single fcc-Co layer sandwiched between two fcc-Fe layers. However, a Co layer completely immersed in a Cu environment remains ferromagnetic. The Curie temperature of the Co(m)Fe(n)Co(m)/Cu(100) system oscillates as the Fe layer thickness is increased whereas that of the Fe(m)Co(n)Fe(m)/Cu(100) system increases almost monotonically with Co layer thickness.

  14. Does CO poison Fe-based catalysts for ORR?

    Energy Technology Data Exchange (ETDEWEB)

    Birry, Laurent; Dodelet, Jean-Pol [INRS-Energie, Materiaux et Telecommunications, 1650, boulevard Lionel Boulet, Varennes, Que. (Canada); Zagal, Jose H. [Facultad de Quimica y Biologia, Universidad de Santiago de Chile, Casilla 40, Correo 33, Santiago (Chile)

    2010-05-15

    Catalysts for the oxygen reduction reaction (ORR) were prepared on carbon black (C) using Fe{sup II}phthalocyanine (FePc) and Cl-Fe{sup III}tetramethoxyphenylporphyrin (ClFeTMPP), as Fe precursors with and without a pyrolysis step at 800 C. CO poisoning of the ORR catalytic sites for all these Fe/N/C electrocatalysts was attempted at pH 1 and 13, but to no avail, even if an iron ion is known to occupy the center of the active sites in at least the unpyrolyzed FePc/C or ClFeTMPP/C. The exact nature of the active center of these Fe-based heat-treated catalysts may still be a subject of debate but, in light of the absence of CO poisoning for unpyrolyzed FePc/C and ClFeTMPP/C, resistance to CO poisoning by the heat-treated catalysts cannot be used as evidence that the active center of their catalytic site is devoid of iron. (author)

  15. Physiology, Fe(II oxidation, and Fe mineral formation by a marine planktonic cyanobacterium grown under ferruginous conditions

    Directory of Open Access Journals (Sweden)

    Elizabeth D. Swanner

    2015-10-01

    Full Text Available Evidence for Fe(II oxidation and deposition of Fe(III-bearing minerals from anoxic or redox-stratified Precambrian oceans has received support from decades of sedimentological and geochemical investigation of Banded Iron Formations (BIF. While the exact mechanisms of Fe(II oxidation remains equivocal, reaction with O2 in the marine water column, produced by cyanobacteria or early oxygenic phototrophs, was likely. In order to understand the role of cyanobacteria in the deposition of Fe(III minerals to BIF, we must first know how planktonic marine cyanobacteria respond to ferruginous (anoxic and Fe(II-rich waters in terms of growth, Fe uptake and homeostasis, and Fe mineral formation. We therefore grew the common marine cyanobacterium Synechococcus PCC 7002 in closed bottles that began anoxic, and contained Fe(II concentrations that span the range of possible concentrations in Precambrian seawater. These results, along with cell suspension experiments, indicate that Fe(II is likely oxidized by this strain via chemical oxidation with oxygen produced during photosynthesis, and not via any direct enzymatic or photosynthetic pathway. Imaging of the cell-mineral aggregates with scanning electron microscopy (SEM and confocal laser scanning microscopy (CLSM are consistent with extracellular precipitation of Fe(III (oxyhydroxide minerals, but that >10% of Fe(III sorbs to cell surfaces rather than precipitating. Proteomic experiments support the role of reactive oxygen species (ROS in Fe(II toxicity to Synechococcus PCC 7002. The proteome expressed under low Fe conditions included multiple siderophore biosynthesis and siderophore and Fe transporter proteins, but most siderophores are not expressed during growth with Fe(II. These results provide a mechanistic and quantitative framework for evaluating the geochemical consequences of perhaps life’s greatest metabolic innovation, i.e. the evolution and activity of oxygenic photosynthesis, in ferruginous

  16. Physiology, Fe(II) oxidation, and Fe mineral formation by a marine planktonic cyanobacterium grown under ferruginous conditions

    Science.gov (United States)

    Swanner, Elizabeth; Wu, Wenfang; Hao, Likai; Wuestner, Marina; Obst, Martin; Moran, Dawn; McIlvin, Matthew; Saito, Mak; Kappler, Andreas

    2015-10-01

    Evidence for Fe(II) oxidation and deposition of Fe(III)-bearing minerals from anoxic or redox-stratified Precambrian oceans has received support from decades of sedimentological and geochemical investigation of Banded Iron Formations (BIF). While the exact mechanisms of Fe(II) oxidation remains equivocal, reaction with O2 in the marine water column, produced by cyanobacteria or early oxygenic phototrophs, was likely. In order to understand the role of cyanobacteria in the deposition of Fe(III) minerals to BIF, we must first know how planktonic marine cyanobacteria respond to ferruginous (anoxic and Fe(II)-rich) waters in terms of growth, Fe uptake and homeostasis, and Fe mineral formation. We therefore grew the common marine cyanobacterium Synechococcus PCC 7002 in closed bottles that began anoxic, and contained Fe(II) concentrations that span the range of possible concentrations in Precambrian seawater. These results, along with cell suspension experiments, indicate that Fe(II) is likely oxidized by this strain via chemical oxidation with oxygen produced during photosynthesis, and not via any direct enzymatic or photosynthetic pathway. Imaging of the cell-mineral aggregates with scanning electron microscopy (SEM) and confocal laser scanning microscopy (CLSM) are consistent with extracellular precipitation of Fe(III) (oxyhydr)oxide minerals, but that >10% of Fe(III) sorbs to cell surfaces rather than precipitating. Proteomic experiments support the role of reactive oxygen species (ROS) in Fe(II) toxicity to Synechococcus PCC 7002. The proteome expressed under low Fe conditions included multiple siderophore biosynthesis and siderophore and Fe transporter proteins, but most siderophores are not expressed during growth with Fe(II). These results provide a mechanistic and quantitative framework for evaluating the geochemical consequences of perhaps life’s greatest metabolic innovation, i.e. the evolution and activity of oxygenic photosynthesis, in ferruginous

  17. [Determination of Total Iron and Fe2+ in Basalt].

    Science.gov (United States)

    Liu, Jian-xun; Chen, Mei-rong; Jian, Zheng-guo; Wu, Gang; Wu, Zhi-shen

    2015-08-01

    Basalt is the raw material of basalt fiber. The content of FeO and Fe2O3 has a great impact on the properties of basalt fibers. ICP-OES and dichromate method were used to test total Fe and Fe(2+) in basalt. Suitable instrument parameters and analysis lines of Fe were chosen for ICP-OES. The relative standard deviation (RSD) of ICP-OES is 2.2%, and the recovery is in the range of 98%~101%. The method shows simple, rapid and highly accurate for determination of total Fe and Fe(2+) in basalt. The RSD of ICP-OES and dichromate method is 0.42% and 1.4%, respectively.

  18. Investigation of the formation of Fe-filled carbon nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Reuther, H [Forschungszentrum Dresden-Rossendorf, PO Box 510119, D-01314 Dresden (Germany); Mueller, C; Leonhardt, A; Kutz, M C, E-mail: reuther@fzd.d [Leibniz-Institute of Solid State and Materials Research Dresden, PO Box 270116, D-01171 Dresden (Germany)

    2010-03-01

    The formation of Fe-filled carbon nanotubes by thermal decomposition of ferrocene combined with a Fe-catalyst-nanostructuring on an oxidized Si substrate is investigated in the temperature range of 1015 - 1200 K. The optimal growth conditions for aligned and homogeneous carbon nanotubes are found at 1103 K. Moessbauer spectroscopy (both in transmission geometry and CEMS) was used to analyze and quantify the different formed Fe-phases. In general, {alpha}-Fe, {gamma}-Fe and Fe{sub 3}C are found to form within the carbon nanotubes. Depending on the growth conditions their fractions vary strongly. Moreover, an alignment of the {alpha}-Fe in the tubes could be detected.

  19. Characterization of phases in the Fe-Nb system

    Science.gov (United States)

    Raposo, M. T.; Ardisson, J. D.; Persiano, A. I. C.; Mansur, R. A.

    1994-12-01

    The Fe-Nb system was investigated by means of X-ray diffraction and Mössbauer spectroscopy (at 300 and 77 K), in the range from 1 to 66.7 at%. We have found that the limit of solubility of Fe in Nb at 1100°C is between 3 and 4 at% Fe, and observed the coexistence of the Nb solid solution (Nbss) phase and Fe21Nb19 in the range from 4 to 40 at% Fe. The Mössbauer parameters of all the single phases are reported. The lattice parameters of Nbss phase present no significant variation with the Nb content. The X-ray pattern for the Fe21Nb19 phase could not be solved. The Laves phase Fe2Nb presents Mössbauer and X-ray parameters that agree with the literature.

  20. Speciation of Fe in ambient aerosol and cloudwater

    Energy Technology Data Exchange (ETDEWEB)

    Siefert, Ronald Lyn [California Inst. of Technology (CalTech), Pasadena, CA (United States)

    1996-08-15

    Atmospheric iron (Fe) is thought to play an important role in cloudwater chemistry (e.g., S(IV) oxidation, oxidant production, etc.), and is also an important source of Fe to certain regions of the worlds oceans where Fe is believed to be a rate-limiting nutrient for primary productivity. This thesis focuses on understanding the chemistry, speciation and abundance of Fe in cloudwater and aerosol in the troposphere, through observations of Fe speciation in the cloudwater and aerosol samples collected over the continental United States and the Arabian Sea. Different chemical species of atmospheric Fe were measured in aerosol and cloudwater samples to help assess the role of Fe in cloudwater chemistry.

  1. High-valent iron (Fe(VI), Fe(V), and Fe(IV)) species in water: characterization and oxidative transformation of estrogenic hormones.

    Science.gov (United States)

    MachalováŠišková, Karolína; Jančula, Daniel; Drahoš, Bohuslav; Machala, Libor; Babica, Pavel; Alonso, Paula Godoy; Trávníček, Zdeněk; Tuček, Jiří; Maršálek, Blahoslav; Sharma, Virender K; Zbořil, Radek

    2016-07-28

    This paper presents solid state synthesis and characterization of tetra-oxy iron(iv) and iron(v) species in their salt forms (Na4FeO4-Fe(IV) and K3FeO4-Fe(V)). Stability of the synthesized salts, commonly called ferrates, in water was determined by applying the (57)Fe Mössbauer spectroscopy technique. Within 2 s in water, Fe(IV) converted into Fe(III) while Fe(V) transformed into Fe(VI) and Fe(III) at pH = 8.2. Comparatively, Fe(VI) (bought as K2FeO4) remained stable in aqueous solution during the short time period. The oxidative removal efficiency of the high-valent iron species was then tested against five environmentally important estrogenic hormones (estron (E1), 17-β-estradiol (E2), estriol (E3), 17-α-ethinylestradiol (EE2), and diethylstibestrol (DES)) in effluent water of a wastewater treatment plant. Three dosages of iron species (1, 10, and 100 mg L(-1)) were applied to the effluent water. An increase in the concentration of dosages enhanced the removal of estrogens. Both Fe(V) and Fe(VI) were effective in degrading estrogens, but Fe(IV) showed limited oxidation capacity to transform estrogens. The oxidized products of the estrogens were analyzed using Raman spectroscopy and high-performance liquid chromatography-mass spectrometry (HPLC-MS) techniques. Results demonstrated the transformation of estrogens into low molecular weight oxygenated compounds such as quinone-like and opened-aromatic ring species. A detailed study on E1 by using excess Fe(VI) showed the mineralization of the parent compound. The results demonstrate great potential of high-valent iron species in the degradation of endocrine disruptor chemicals like estrogens with several superior aspects including fast reactions, complete degradation and/or formation of benign organic species, and environmentally-acceptable iron oxide by-products.

  2. Chemistry of the Fe2O3/BiFeO3 Interface in BiFeO3 Thin Film Heterostructures

    Directory of Open Access Journals (Sweden)

    Valanoor Nagarajan

    2010-12-01

    Full Text Available We investigate the interfacial chemistry of secondary Fe2O3 phases formed in a BiFeO3 (BFO layer in BFO/ La0.67Sr0.33MnO3 (LSMO/SrTiO3 (STO heterostructures. A combination of high-resolution spherical aberration corrected scanning TEM and spectroscopy results, reveals that specific chemical and crystallographic similarities between Fe2O3 and BFO, enable the BFO layer to form a facile host for Fe2O3.

  3. Superconducting gap structure of FeSe.

    Science.gov (United States)

    Jiao, Lin; Huang, Chien-Lung; Rößler, Sahana; Koz, Cevriye; Rößler, Ulrich K; Schwarz, Ulrich; Wirth, Steffen

    2017-03-07

    The microscopic mechanism governing the zero-resistance flow of current in some iron-based, high-temperature superconducting materials is not well understood up to now. A central issue concerning the investigation of these materials is their superconducting gap symmetry and structure. Here we present a combined study of low-temperature specific heat and scanning tunnelling microscopy measurements on single crystalline FeSe. The results reveal the existence of at least two superconducting gaps which can be represented by a phenomenological two-band model. The analysis of the specific heat suggests significant anisotropy in the gap magnitude with deep gap minima. The tunneling spectra display an overall "U"-shaped gap close to the Fermi level away as well as on top of twin boundaries. These results are compatible with the anisotropic nodeless models describing superconductivity in FeSe.

  4. Electronic structure of Fe-based superconductors

    Indian Academy of Sciences (India)

    Kalobaran Maiti

    2015-06-01

    Fe-based superconductors have drawn much attention during the last decade due to the presence of superconductivity in materials containing the magnetic element, Fe, and the coexistence of superconductivity and magnetism. Extensive study of the electronic structure of these systems suggested the dominant role of states in their electronic properties, which is significantly different from the cuprate superconductors. In this article, some of our studies of the electronic structure of these fascinating systems employing high-resolution photoemission spectroscopy is reviewed. The combined effect of electron correlation and covalency reveals an interesting scenario in their electronic structure. The contribution of ligand states at the Fermi level is found to be much more significant than indicated in earlier studies. Temperature evolution of the energy bands reveals the signature of transition akin to Lifshitz transition in these systems.

  5. Forging of FeAl intermetallic compounds

    Energy Technology Data Exchange (ETDEWEB)

    Flores, O.; Juarez, J.; Campillo, B.; Martinez, L. [UNAM, Cuernavaca (Mexico). Lab. de Cuernavaca; Schneibel, J.H. [Oak Ridge National Lab., TN (United States)

    1994-09-01

    Much activity has been concentrated on the development of intermetallic compounds with the aim of improving tensile ductility, fracture toughness and high notch sensitivity in order to develop an attractive combination of properties for high and low temperature applications. This paper reports experience in processing and forging of FeAl intermetallic of B2 type. During the experiments two different temperatures were employed, and the specimens were forged after annealing in air, 10{sup {minus}2} torr vacuum and argon. From the results it was learned that annealing FeAl in argon atmosphere prior to forging resulted in better deformation behavior than for the other two environments. For the higher forging temperature used in the experiments (700C), the as-cast microstructure becomes partially recrystallized.

  6. El auto de fe de 1606

    Directory of Open Access Journals (Sweden)

    María Isabel Pérez de Colosía Rodríguez

    1994-01-01

    Full Text Available La relación del auto de fe de 1606, está dividida en los siguientes siete apartados: Relajados en persona, Relajados en estatua, Reconciliados por la secta de Mahoma, Reconciliados por la ley de Moisés, Reconciliados por la secta Luterana, Penintenciados con abjuración de behementi y Penitenciados con abjuración de levi.

  7. Thermodynamic measurements of Fe-Rh alloys.

    Science.gov (United States)

    Cooke, David W; Hellman, F; Baldasseroni, C; Bordel, C; Moyerman, S; Fullerton, E E

    2012-12-21

    FeRh undergoes an unusual antiferromagnetic-to-ferromagnetic (AFM-FM) transition just above room temperature (T(AFM>FM)) that can be tuned or even completely suppressed with small changes in composition. The underlying temperature-dependent entropy difference between the competing AFM and FM states that drives this transition is measured by specific heat as a function of temperature from 2 to 380 K on two nearly equiatomic epitaxial Fe-Rh films, one with a ferromagnetic ground state (Fe-rich) and the other with an antiferromagnetic ground state (Rh-rich). The FM state shows an excess heat capacity near 100 K associated with magnetic excitations that are not present in the AFM state. The integrated entropy and enthalpy differences between the two alloys up to T(AFM>FM) agree with the previously measured entropy of the transition (ΔS = 17 ± 3 J/kg/K) and yield a T=0 energy difference of 3.4 J/g, consistent with literature calculations and experimental data; this agreement supports the use of the Fe-rich FM sample as a proxy for the (unstable) FM state of the AFM Rh-rich sample. From the low-temperature specific heat, along with sound velocity and photoemission measurements, the lattice contribution to the difference (ΔS(latt) = -33 ± 9 J/kg/K) and electronic contribution (ΔS(el) = 8 ± 1 J/kg/K) to the difference in entropy are calculated, from which the excess heat capacity in the FM phase and the resulting entropy difference are shown to be dominated by magnetic fluctuations (ΔS(mag) = 43 ± 9 J/kg/K). The excess magnetic heat capacity is dominated by the magnetic heat capacity of the FM phase, which can be fit to a Schottky-like anomaly with an energy splitting of 16 ± 1 meV and a multiplicity of 1 per unit cell.

  8. Fe XVII Emission from Hot, Collisional Plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Beiersdorfer, P; Bitter, M; von Goeler, S; Hill, K W

    2004-12-03

    The ratios of the Fe XVII 3s {yields} 2p transitions to that of the dominant 3d {yields} 2p transition measured in high-temperature tokamak plasmas are compared to solar and astrophysical observations. Good agreement is found, indicating that the collisional line formation processes active in opacity-free, low-density, high-temperature laboratory plasmas are a good description of those found in astrophysical plasmas.

  9. Microstructures of NiFe/nonmagnetic metal spacer/FeMn films and their influences on exchange coupling

    Institute of Scientific and Technical Information of China (English)

    LI; Minghua(李明华); YU; Guanghua(于广华); ZHU; Fengwu(朱逢吾); HE; Ke(何珂); LAI; Wuyan(赖武彦)

    2003-01-01

    Ta/NiFe/nonmagnetic metal spacer/FeMn films were prepared by magnetron sputtering. The dependences of the exchange coupling field (Hex) between an antiferromagnetic FeMn layer and a ferromagnetic NiFe layer on the thickness of nonmagnetic metal spacer layers were systematically studied. The results show that the Hex dramatically decreases with the increase in the thicknesses of Bi and Ag spacer layers. However, it gradually decreases with the increase in the thickness of a Cu spacer layer. For a Cu space layer, its crystalline structure is the same as that of NiFe and the lattice parameters of them are close to each other. The Cu layer and FeMn layer will epitaxially grow on the NiFe layer in succession, so the (111) texture of the FeMn layer will not be damaged. As a result, the Hex gradually decreases with the deposition thickness of a Cu layer. For an Ag space layer, its crystalline structure is the same as that of NiFe, but its lattice parameter is very different from that of NiFe. Thus, neither an Ag nor an FeMn layer will epitaxially grow on the NiFe layer and the (111) texture of the FeMn layer will be damaged. The Hex rapidly decreases with the increase in the deposition thickness of an Ag layer. For a Bi spacer layer, not only its crystalline structure but also its lattice parameter is greatly different from that of NiFe. For the same reason, the Bi and FeMn layer cannot epitaxially grow on the NiFe layer. The texture of the FeMn layer will also be damaged. Therefore, the Hex rapidly decreases with the increase in the deposition thickness of a Bi layer as well. However, the research result of X-ray photoelectron spectroscopy indicates that a very small amount of surfactant Bi atoms will migrate to the FeMn layer surface when they are deposited on the NiFe/FeMn interface. Thus, the Hex will hardly decrease.

  10. Search for pressure-induced superconductivity in CeFeAsO and CeFePO iron pnictides

    Energy Technology Data Exchange (ETDEWEB)

    Zocco, D. A. [University of California, San Diego; Baumbach, R. E. [University of California, San Diego; Hamlin, J. J. [University of California, San Diego; Janoschek, M. [University of California, San Diego; Lum, I. K. [University of California, San Diego; McGuire, Michael A [ORNL; Safa-Sefat, Athena [ORNL; Sales, Brian C [ORNL; Jin, Rongying [ORNL; Mandrus, David [ORNL; Jeffries, J. R. [Lawrence Livermore National Laboratory (LLNL); Weir, S. T. [Lawrence Livermore National Laboratory (LLNL); Vohra, Y. K. [University of Alabama, Birmingham; Maple, M. B. [University of California, San Diego

    2011-01-01

    The CeFeAsO and CeFePO iron pnictide compounds were studied via electrical transport measurements under high pressure. In CeFeAsO polycrystals, the magnetic phases involving the Fe and Ce ions coexist for hydrostatically applied pressures up to 15 GPa, and with no signs of pressure-induced superconductivity up to 50 GPa for the less hydrostatic pressure techniques. For the CeFePO single crystals, pressure further stabilizes the Kondo screening of the Ce 4f-electron magnetic moments.

  11. Fe-Ni/NiFe2O4纳米复合颗粒的制备与磁性研究∗%The preparation and magnetic characterization of Fe-Ni/NiFe2 O4 nanocomposite particles

    Institute of Scientific and Technical Information of China (English)

    杨柳; 何峻; 安静; 赵栋梁

    2015-01-01

    结合共沉淀法和氢气还原法成功制备出Fe-Ni/NiFe2 O4纳米复合颗粒,所制备的纳米复合颗粒包含NiFe2 O4和 Fe-Ni 合金,其中 Fe-Ni 合金具有体心立方和面心立方两种结构。用 XRD 和 TEM对所得样品进行结构分析。用 SQUID 测量样品在室温时的磁滞回线,发现 Fe-Ni/NiFe2 O4纳米复合颗粒的矫顽力和饱和磁化强度与制备态 NiFe2 O4纳米颗粒相比随着退火时间的增加呈现出逐渐增加的趋势。为了进一步研究所制备的纳米复合颗粒的磁性特征,测量退火时间相同而退火温度不同的两个样品在零磁场冷却(ZFC)和带磁场冷却(FC)条件下的M-T 曲线。%NiFe2 O4 nanoparticles were synthesized by the co-precipitation method and Fe-Ni/NiFe2 O4 nanocom-posite particles were obtained by reducing NiFe2 O4 nanoparticles under hydrogen atmosphere.The as-prepared nanoparticles contain NiFe2 O4 with spinel phase and Fe-Ni alloy with body centered cubic and face-centered cu-bic phase.The structure and morphology of Fe-Ni/NiFe2 O4 nanocomposite particles were characterized by X-ray diffraction and transmission electron microscopy.The room temperature magnetization was analyzed by SQUID. We found that with the increase of annealing time,the coercivity and saturation magnetization of Fe-Ni/NiFe2 O4 nanocomposite particles exhibit a gradually increasing trend compared with as-quenched NiFe2 O4 nano-particles.In order to further study magnetic characteristics of as-prepared nanoparticles,we measured the M-T curves under the condition of zero field cooling (ZFC)and field cooling (FC)of two different samples which have different annealing temperature but the same annealing time.

  12. As diffusion in ferromagnetic {alpha}-Fe

    Energy Technology Data Exchange (ETDEWEB)

    Perez, R.A.; Dyment, F. [Comision Nacional de Energia Atomica (CNEA), Departamento de Materiales, Buenos Aires (Argentina); Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), Buenos Aires (Argentina); Torres, D.N. [Comision Nacional de Energia Atomica (CNEA), Departamento de Materiales, Buenos Aires (Argentina)

    2009-11-15

    Diffusion of As in {alpha}-Fe was studied. Diffusion couples were formed by ion implantation; measurements were made in the 673-1073 K temperature range using the heavy ion Rutherford backscattering (HIRBS) technique as the analysis tool. A curved Arrhenius plot was obtained, as a product of the ferromagnetism effect on diffusion; the previously developed model for diffusion of non-magnetic impurities in ferromagnetic Fe fits the data perfectly well. As diffusion is, on average, two orders of magnitude faster than self-diffusion given its smaller atomic radius (110 pm against 140 pm for Fe). Assuming a total increment in the activation energy due to the ferromagnetic alignment {alpha}Q=40 kJ mol{sup -1}, diffusion parameters for the paramagnetic region could be extrapolated, these being the pre-exponential factor D{sub 0} {sup p}=10{sup -5} m{sup 2}s{sup -1} and the activation energy Q{sup p}=197 kJ mol{sup -1}. (orig.)

  13. VERY LATE PHOTOMETRY OF SN 2011fe

    Energy Technology Data Exchange (ETDEWEB)

    Kerzendorf, W. E. [Department of Astronomy and Astrophysics, University of Toronto, 50 Saint George Street, Toronto, ON M5S 3H4 (Canada); Taubenberger, S.; Seitenzahl, I. R.; Ruiter, A. J., E-mail: wkerzendorf@gmail.com [Max-Planck-Institut für Astrophysik, Karl-Schwarzschild-Straße 1, D-85748 Garching (Germany)

    2014-12-01

    The Type Ia supernova SN 2011fe is one of the closest supernovae of the past decades. Due to its proximity and low dust extinction, this object provides a very rare opportunity to study the extremely late time evolution (>900 days) of thermonuclear supernovae. In this Letter, we present our photometric data of SN 2011fe taken at an unprecedented late epoch of ≈930 days with GMOS-N mounted on the Gemini North telescope (g = 23.43 ± 0.28, r = 24.14 ± 0.14, i = 23.91 ± 0.18, and z = 23.90 ± 0.17) to study the energy production and retention in the ejecta of SN 2011fe. Together with previous measurements by other groups, our result suggests that the optical supernova light curve can still be explained by the full thermalization of the decay positrons of {sup 56}Co. This is in spite of theoretical predicted effects (e.g., infrared catastrophe, positron escape, and dust) that advocate a substantial energy redistribution and/or loss via various processes that result in a more rapid dimming at these very late epochs.

  14. Fe-Oxides in Water Remediation Technologies

    Science.gov (United States)

    Vaclavikova, M.; Stefusova, K.; Gallios, G. P.

    Water is essential for life, a strategic resource for every country and population. Its availability and sanitary safety is highly connected with the health and economic status of a population. The burden of disease due to polluted water is a major public health problem throughout the world. Many pollutants in water streams have been identified as toxic and harmful to the environment and human health, and among them arsenic, mercury and cadmium are considered those with the highest priority. Iron is the fourth most abundant element in the Earth's crust, and reactions involving iron play a major role in the environmental cycling of a range of important contaminants. Our earlier research has shown that Fe oxides/oxyhydroxides are particularly effective adsorbents of a range of contaminants (toxic metals), due to their high (reactive) specific surface area. It has been proven that Fe is particularly effective in As removal as a chemical bond is created on Fe surface and As is stabilised and can be safely deposited. Removal of contaminants from waste streams through precipitation with (hydrous) ferric oxides is an established methodology in a number of industrial processes (high density sludge systems for arsenic control in effluents from the mining industry, and in the treatment of textile dye effluent).

  15. Very late photometry of SN 2011fe

    CERN Document Server

    Kerzendorf, W E; Seitenzahl, I R; Ruiter, A J

    2014-01-01

    The Type Ia supernova SN 2011fe is one of the closest supernovae of the past decades. Due to its proximity and low dust extinction, this object provides a very rare opportunity to study the extremely late time evolution (> 900 d) of thermonuclear supernovae. These late stages allow for a direct measurement of the decay processes of nuclei synthesized in the core of the explosion. In this paper, we present our photometric data of SN 2011fe taken at an unprecedentedly late epoch of ~ 930 d with GMOS-N mounted on the Gemini North telescope (g=23.37+/- 0.25, r=24.03 +/- 0.09, i=23.90 +/- 0.15, and z=23.74 +/- 0.16) to study the energy production and retention in the ejecta of SN 2011fe. Together with previous measurements by other groups, our result suggests that the optical supernova light curve can still be explained by the full thermalization of the decay positrons of 56Co. This is in spite of several theoretical predictions that advocate a substantial energy redistribution and/or loss via various processes wh...

  16. Spectromicroscopy of Fe distributions in clay microcrystals

    Energy Technology Data Exchange (ETDEWEB)

    Grundl, T. [Univ. of Wisconsin, Milwaukee, WI (United States); Cerasari, S.; Garcia, A. [Lawrence Berkeley National Lab., CA (United States)] [and others

    1997-04-01

    Clays are ubiquitous crystalline particles found in nature that are responsible for contributing to a wide range of chemical reactions in soils. The structure of these mineral particles changes when the particle is hydrated ({open_quotes}wet{close_quotes}), from that when it is dry. This makes a study of the microscopic distribution of chemical content of these nanocrystals difficult using standard techniques that require vacuum. In addition to large structural changes, it is likely that chemical changes accompany the drying process. As a result, spectroscopic measurements on dried clay particles may not accurately reflect the actual composition of the material as found in the environment. In this work, the authors extend the use of the ALS Spectromicroscopy Facility STXM to high spectral and spatial resolution studies of transition metal L-edges in environmental materials. The authors are studying mineral particles of montmorillonite, which is an Fe bearing clay which can be prepared with a wide distribution of Fe concentrations, and with Fe occupying different substitutional sites.

  17. Influence of the surface topography, morphology and structure on magnetic properties of ion beam sputtered iron layers, Fe/Cr/Fe- and Fe/MgO/Fe multilayers; Untersuchung der Morphologie und magnetische Eigenschaften von ionenstrahl-gesputterten Eisen-Einzelschichten, Fe/Cr/Fe- und Fe/MgO/Fe-Schichtsystemen

    Energy Technology Data Exchange (ETDEWEB)

    Steeb, Alexandra

    2007-04-05

    In this PhD Thesis, the influence of the surface topography, morphology and structure on magnetic properties of ion beam sputtered iron layers on GaAs is examined. To analyze the structure of the produced iron films, low energy electron diffraction and scanning tunneling microscopy is employed. The utilized methods to investigate the magnetic properties are Kerr- and SQUID-magnetometry and ferromagnetic resonance. It is demonstrated that on untreated as well as on presputtered and heated GaAs substrates the sputtered iron films grow epitaxially. The least surface roughness of 1 A exhibit iron films grown on untreated GaAs, while iron films on heated GaAs have the highest roughness of 30 A. The largest crystal anisotropy constant is found for the presputtered GaAs/Fe-System. For this preparation method, two monolayers of iron are determined to be magnetically dead layers. At a film thickness of 100 A, 83% of the value for saturation magnetization of bulk iron are achieved. The small observed FMR-linewidths confirm the good bulk properties of the ion beam sputtered iron. Furthermore, an antiferromagnetic interlayer exchange coupling in sputtered Fe/Cr/Fe-films was achieved. For a thickness of 12 to 17 A of the chrome interlayer, a coupling strength up to 0.2 mJ/m{sup 2} is found. To account for the small coupling strength, a strong intermixing at the interface is assumed. Finally, epitaxial Fe/MgO/Fe/FeMn multilayers are deposited on GaAs. After the structuring, it is possible to detect tunneling processes in the tunneling contacts with current-voltage measurements. The tunnel magneto resistance values of 2% are small, which can be explained by the absence of sharp, well-defined interfaces between the Fe/FeMn and the Fe/MgO interfaces. These results demonstrate, that analog to MBE the ion beam sputtering method realizes good magnetic bulk properties. However, interface sensitive phenomena are weakened because of a strong intermixing at the interfaces. (orig.)

  18. Low Gilbert damping in Co2FeSi and Fe2CoSi films

    Science.gov (United States)

    Sterwerf, Christian; Paul, Soumalya; Khodadadi, Behrouz; Meinert, Markus; Schmalhorst, Jan-Michael; Buchmeier, Mathias; Mewes, Claudia K. A.; Mewes, Tim; Reiss, Günter

    2016-08-01

    Thin highly textured Fe1+xCo2-xSi (0 ≤ x ≤ 1) films were prepared on MgO (001) substrates by magnetron co-sputtering. Magneto-optic Kerr effect (MOKE) and ferromagnetic resonance (FMR) measurements were used to investigate the composition dependence of the magnetization, the magnetic anisotropy, the gyromagnetic ratio, and the relaxation of the films. Both MOKE and FMR measurements reveal a pronounced fourfold anisotropy for all films. In addition, we found a strong influence of the stoichiometry on the anisotropy as the cubic anisotropy strongly increases with increasing Fe concentration. The gyromagnetic ratio is only weakly dependent on the composition. We find low Gilbert damping parameters for all films with values down to 0.0012 ±0.00010.0007 for Fe1.75Co1.25Si. The effective damping parameter for Co2FeSi is found to be 0.0018 ±0.00040.0034 . We also find a pronounced anisotropic relaxation, which indicates significant contributions of two-magnon scattering processes that is strongest along the easy axes of the films. This makes thin Fe1+xCo2-xSi films ideal materials for the application in spin transfer-torque magnetic RAM (STT-MRAM) devices.

  19. Influence of roughness at interfaces on tunneling magnetoresistance in Fe/MgO/Fe

    Energy Technology Data Exchange (ETDEWEB)

    Edalati Boostan, Saeideh [I. Physikalisches Institut, Justus Liebig University Giessen, D-35392 (Germany); Department of Physics, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad (Iran, Islamic Republic of); Moradi, Hosein [Department of Physics, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad (Iran, Islamic Republic of); Heiliger, Christian [I. Physikalisches Institut, Justus Liebig University Giessen, D-35392 (Germany)

    2010-07-01

    We propose a theoretical model for magnetic tunnel junction devices with rough interfaces based on a single-band tight-binding approximation. The high tunneling magnetoresistance (TMR) for crystalline MgO barrier was observed at room temperature which is desirable for magnetic random access memory (MRAM) applications. In real junctions the Fe and MgO atoms are interdiffused at interfaces and the numbers of diffused Fe and MgO atoms are not the same. The interface disorder is modeled by considering replacement of MgO sites by Fe atoms with a probability of n>0.5. The non-equilibrium Green's function formalism is used to calculate transport in Fe/MgO/Fe junctions. We investigate the voltage dependencies of TMR and current densities for parallel and anti-parallel configurations for majority and minority spins. The results show that the roughness decreases the TMR. The current density for the parallel (antiparallel) orientations of magnetizations decreases (increases) by including roughness at the interface.

  20. Incorporation of oxidized uranium into Fe (hydr)oxides during Fe(II) catalyzed remineralization

    Energy Technology Data Exchange (ETDEWEB)

    Nico, Peter S.; Stewart, Brandy D.; Fendorf, Scott

    2009-07-01

    The form of solid phase U after Fe(II) induced anaerobic remineralization of ferrihydrite in the presence of aqueous and absorbed U(VI) was investigated under both abiotic batch and biotic flow conditions. Experiments were conducted with synthetic ground waters containing 0.168 mM U(VI), 3.8 mM carbonate, and 3.0 mM Ca{sup 2+}. In spite of the high solubility of U(VI) under these conditions, appreciable removal of U(VI) from solution was observed in both the abiotic and biotic systems. The majority of the removed U was determined to be substituted as oxidized U (U(VI) or U(V)) into the octahedral position of the goethite and magnetite formed during ferrihydrite remineralization. It is estimated that between 3% and 6% of octahedral Fe(III) centers in the new Fe minerals were occupied by U(VI). This site specific substitution is distinct from the non-specific U co-precipitation processes in which uranyl compounds, e.g. uranyl hydroxide or carbonate, are entrapped with newly formed Fe oxides. The prevalence of site specific U incorporation under both abiotic and biotic conditions and the fact that the produced solids were shown to be resistant to both extraction (30 mM KHCO{sub 3}) and oxidation (air for 5 days) suggest the potential importance of sequestration in Fe oxides as a stable and immobile form of U in the environment.

  1. The [FeFe] hydrogenase of Nyctotherus ovalis has a chimeric origin

    Directory of Open Access Journals (Sweden)

    Jouany Jean-Pierre

    2007-11-01

    Full Text Available Abstract Background The hydrogenosomes of the anaerobic ciliate Nyctotherus ovalis show how mitochondria can evolve into hydrogenosomes because they possess a mitochondrial genome and parts of an electron-transport chain on the one hand, and a hydrogenase on the other hand. The hydrogenase permits direct reoxidation of NADH because it consists of a [FeFe] hydrogenase module that is fused to two modules, which are homologous to the 24 kDa and the 51 kDa subunits of a mitochondrial complex I. Results The [FeFe] hydrogenase belongs to a clade of hydrogenases that are different from well-known eukaryotic hydrogenases. The 24 kDa and the 51 kDa modules are most closely related to homologous modules that function in bacterial [NiFe] hydrogenases. Paralogous, mitochondrial 24 kDa and 51 kDa modules function in the mitochondrial complex I in N. ovalis. The different hydrogenase modules have been fused to form a polyprotein that is targeted into the hydrogenosome. Conclusion The hydrogenase and their associated modules have most likely been acquired by independent lateral gene transfer from different sources. This scenario for a concerted lateral gene transfer is in agreement with the evolution of the hydrogenosome from a genuine ciliate mitochondrion by evolutionary tinkering.

  2. Nano-sized magnetic instabilities in Fe/NiO/Fe(001) epitaxial thin films

    Energy Technology Data Exchange (ETDEWEB)

    Brambilla, A. [Dipartimento di Fisica-Politecnico di Milano, P.za Leonardo da Vinci 32, 20133 Milan (Italy)]. E-mail: alberto.brambilla@polimi.it; Biagioni, P. [Dipartimento di Fisica-Politecnico di Milano, P.za Leonardo da Vinci 32, 20133 Milan (Italy); Rougemaille, N. [National Center for Electron Microscopy, Lawrence Berkeley National Lab, Berkeley, CA 94720 (United States); Schmid, A.K. [National Center for Electron Microscopy, Lawrence Berkeley National Lab, Berkeley, CA 94720 (United States); Lanzara, A. [Department of Physics, University of California at Berkeley, Berkeley, CA 94720 (United States); Duo, L. [Dipartimento di Fisica-Politecnico di Milano, P.za Leonardo da Vinci 32, 20133 Milan (Italy); Ciccacci, F. [Dipartimento di Fisica-Politecnico di Milano, P.za Leonardo da Vinci 32, 20133 Milan (Italy); Finazzi, M. [Dipartimento di Fisica-Politecnico di Milano, P.za Leonardo da Vinci 32, 20133 Milan (Italy)

    2006-10-25

    We report on a magnetic imaging study of the Fe/NiO/Fe(001) trilayer structure, by means of X-ray photoemission electron microscopy (XPEEM) and spin-polarised low-energy electron microscopy (SPLEEM). Two different magnetic couplings between the Fe layers are observed depending on the NiO thickness being greater or smaller than a critical value. Very small magnetic domains and domain walls are observed in the top Fe layer. They are dramatically smaller than those observed in the Fe substrate, and have a convoluted topology. Furthermore they seem to be unstable with respect to an applied magnetic field for any NiO thickness except that corresponding to the transition between the different coupling regimes. The phenomenology of such magnetic nano-structures and the dependence of the magnetic behaviour of the layered structure on the NiO spacer thickness are discussed on the basis of the experimental results and of state-of-the-art theoretical models.

  3. Incorporation of oxidized uranium into Fe (hydr)oxides during Fe(II) catalyzed remineralization

    Energy Technology Data Exchange (ETDEWEB)

    Nico, Peter S.; Stewart, Brandy D.; Fendorf, Scott

    2009-07-01

    The form of solid phase U after Fe(II) induced anaerobic remineralization of ferrihydrite in the presence of aqueous and absorbed U(VI) was investigated under both abiotic batch and biotic flow conditions. Experiments were conducted with synthetic ground waters containing 0.168 mM U(VI), 3.8 mM carbonate, and 3.0 mM Ca{sup 2+}. In spite of the high solubility of U(VI) under these conditions, appreciable removal of U(VI) from solution was observed in both the abiotic and biotic systems. The majority of the removed U was determined to be substituted as oxidized U (U(VI) or U(V)) into the octahedral position of the goethite and magnetite formed during ferrihydrite remineralization. It is estimated that between 3% and 6% of octahedral Fe(III) centers in the new Fe minerals were occupied by U(VI). This site specific substitution is distinct from the non-specific U co-precipitation processes in which uranyl compounds, e.g. uranyl hydroxide or carbonate, are entrapped with newly formed Fe oxides. The prevalence of site specific U incorporation under both abiotic and biotic conditions and the fact that the produced solids were shown to be resistant to both extraction (30 mM KHCO{sub 3}) and oxidation (air for 5 days) suggest the potential importance of sequestration in Fe oxides as a stable and immobile form of U in the environment.

  4. Influence of Fe underlayers on stress evolution of Ti in Ti/Fe multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Wan, Li; Thompson, Gregory, E-mail: gthompson@eng.ua.edu [Department of Metallurgical Engineering, The University of Alabama, Tuscaloosa, Alabama 35487-0202 (United States)

    2016-11-15

    A series of 40–2 nm bilayer spacing Ti/Fe multilayers were sputter-deposited. As the length scale of individual Ti layers equaled to 2 nm, Ti phase transforms from a hexagonal close packed (hcp)-to-body centered cubic (bcc) crystal structures for equal layer thicknesses in Ti/Fe multilayers. Further equal reductions in bilayer spacing to less than 1 nm resulted in an additional transformation from a crystalline to amorphous structure. Atom probe tomography reveals significant intermixing between layers which contributes to the observed phase transformations. Real-time, intrinsic growth stress measurements were also performed to relate the adatom mobility to these phase transformations. For the hcp Ti/bcc Fe multilayers of equivalent volume fractions, the multilayers undergo an overall tensile stress state to a compressive stress state with decreasing bilayer thickness for the multilayers. When the above phase transformations occurred, a modest reduction in the overall compressive stress of the multilayer was noted. Depending on the Fe thickness, the Ti growth was observed to be a tensile to compressive growth change to a purely compressive growth for thinner bilayer spacing. Fe retained a tensile growth stress regardless of the bilayer spacing studied.

  5. Modeling thermodynamics of Fe-N phases; characterisation of e-Fe2N1-z

    DEFF Research Database (Denmark)

    Pekelharing, M.I.; Böttger, A.; Somers, Marcel A.J.

    1999-01-01

    In order to arrive at modeling the thermodynamics of Fe-N phases, including long-range (LRO) and short-range ordering (SRO) of the N atoms, it is important to understand the role of N interstitially dissolved in an Fe-host lattice. The crystal structure of -Fe2N1-z consists of an h.c.p. iron...... sublattice and a hexagonal nitrogen sublattice formed by octahedral interstices of the Fe sublattice [1]. Two ground-state structures have been proposed for the ordered arrangement of the N atoms on their own sublattice [1], which were shown to be thermodynamically favourable [2]: configuration A for Fe2N1...... investigated with X-ray diffraction (XRD) and Mössbauer spectroscopy. A thermodynamic model accounting for the two configurations of LRO of the N atoms [2,3] was fitted to the N-absorption isotherm at 723 K and resulted in the occupancies of the sites of the nitrogen sublattice. A miscibility gap between...

  6. Searching for high magnetization density in bulk Fe: the new metastable Fe6 phase

    Science.gov (United States)

    Umemoto, Koichiro; Himmetoglu, Burak; Wang, Jian-Ping; Wentzcovitch, Renata M.; Cococcioni, Matteo

    2015-01-01

    We report the discovery of a new allotrope of iron by first principles calculations. This phase has Pmn21 symmetry, a six-atom unit cell (hence the name Fe6), and the highest magnetization density (Ms) among all the known crystalline phases of iron. Obtained from the structural optimizations of the Fe3C-cementite crystal upon carbon removal, Pmn21 Fe6 is shown to result from the stabilization of a ferromagnetic FCC phase, further strained along the Bain path. Although metastable from 0 to 50 GPa, the new phase is more stable at low pressures than the other well-known HCP and FCC allotropes and smoothly transforms into the FCC phase under compression. If stabilized to room temperature, for example, by interstitial impurities, Fe6 could become the basis material for high Ms rare-earth-free permament magnets and high-impact applications such as light-weight electric engine rotors or high-density recording media. The new phase could also be key to explaining the enigmatic high Ms of Fe16N2, which is currently attracting intense research activity.

  7. Synthesis and magnetic properties of core/shell FeO/Fe3O4 nano-octopods

    Science.gov (United States)

    Khurshid, Hafsa; Chandra, Sayan; Li, Wanfeng; Phan, M. H.; Hadjipanayis, G. C.; Mukherjee, P.; Srikanth, H.

    2013-05-01

    We report the synthesis and magnetic properties of core/shell FeO/Fe3O4 nanoparticles with an average size of 30 nm in a complex quasi-octopod shape. FeO nanoparticles were synthesized by a wet chemical synthesis route followed by partial oxidation to form core/shell structured FeO/Fe3O4 octopods. X-ray diffraction and transmission electron microscopy confirmed the presence of iron oxide phases and the formed core/shell FeO/Fe3O4 morphology. Magnetic measurements revealed two distinct temperatures corresponding to the thermally activated Verwey transition (TV ˜ 120 K) of the ferrimagnetic Fe3O4 shell and the Neel temperature (TN ˜ 230 K) of the antiferromagnetic FeO core. The nanoparticles exhibited a strong horizontal shift in the field-cooled hysteresis loop (the so-called exchange bias (EB) effect) accompanied by enhanced coercivity. The Meiklejohn-Bean model has been implemented to quantify the amount of frozen spins that locate at the interface between FeO and Fe3O4 and are responsible for the observed EB effect.

  8. Ethylene is critical to the maintenance of primary root growth and Fe homeostasis under Fe stress in Arabidopsis.

    Science.gov (United States)

    Li, Guangjie; Xu, Weifeng; Kronzucker, Herbert J; Shi, Weiming

    2015-04-01

    Iron (Fe) is an essential microelement but is highly toxic when in excess. The response of plant roots to Fe toxicity and the nature of the regulatory pathways engaged are poorly understood. Here, we examined the response to excess Fe exposure in Arabidopsis wild type and ethylene mutants with a focus on primary root growth and the role of ethylene. We showed that excess Fe arrested primary root growth by decreasing both cell elongation and division, and principally resulteds from direct external Fe contact at the root tip. Pronounced ethylene, but not abscisic acid, evolution was associated with excess Fe exposure. Ethylene antagonists intensified root growth inhibition in the wild type, while the inhibition was significantly reduced in ethylene-overproduction mutants. We showed that ethylene plays a positive role in tissue Fe homeostasis, even in the absence of iron-plaque formation. Ethylene reduced Fe concentrations in the stele, xylem, and shoot. Furthermore, ethylene increased the expression of genes encoding Fe-sequestering ferritins. Additionally, ethylene significantly enhanced root K(+) status and upregulated K(+)-transporter (HAK5) expression. Our findings highlight the important role of ethylene in tissue Fe and K homeostasis and primary root growth under Fe stress in Arabidopsis.

  9. Fe2+-Ti4+ vs. Fe2+-Fe3+ charge-transfer and short-range order in single chains of face-sharing octahedra: ellenbergerite and dumortierite

    Science.gov (United States)

    Chopin, C.; Langer, K.; Khomenko, V.

    2009-04-01

    In zoned pyrope megacrysts from the Dora-Maira UHP terrane, new, dark-violet colour varieties of the hexagonal, high-pressure silicate ellenbergerite extend the range of known Fe contents for this mineral from 0-0.1 to 0-0.4 atom pfu, for Ti contents commonly in the range 0.2-0.4 pfu. The new varieties show an extremely intense pleochroism, colourless for E perpendicular to c to deep Prussian blue for E//c, as compared to colourless to lilac or reddish purple for classical Fe-poor ellenbergerite. These features were the incentive for an electronic absorption spectroscopic study and a reappraisal of the interpretation of the charge transfers (CT), colour and ordering schemes in this group and the structurally related borosilicate dumortierite. Both structures are characterized by the presence of infinite single chains of face-sharing, partly vacant octahedra along the 6-fold screw axis and pseudo-hexad axis, respectively, in which the Fe and Ti atoms are partitioned. In the spectra of Fe-poor ellenbergerite, the presence of a single Fe2+-Ti4+ CT band near 19000 cm˘1 was taken as evidence for complete short-range ordering of Mg(Fe), Ti and vacancies in the octahedral single chain [1]. The E//c spectra of Fe-rich ellenbergerite show the same absorption band near 19000 cm˘1 but consistently flanked by another CT band near 14000 cm˘1 , the intensity of which increases with total Fe content. The latter is similar to the 12400 cm˘1 CT band observed as the single feature in E//c spectra of the isotructural (Ti-free and Fe-bearing) phosphoellenbergerite, and clearly assigned to Fe2+-Fe3+ CT in the octahedral single chain [1]. The same colour pattern occurs in the dumortierite group, with red Fe-poor, Ti-rich crystals showing a single CT band near 20000 cm˘1, blue Ti-poor crystals showing a single CT band near 16500 cm˘1, and violet Fe- and Ti-rich crystals showing a combination of the two bands [2]. In the light of the new data, we reinterpret the dumortierite colour

  10. Effects of milling and crystallization conditions on microstructure of Nd2Fe14B/α-Fe powder

    Institute of Scientific and Technical Information of China (English)

    WANG Ying; WANG Er-de

    2007-01-01

    Effects of milling and crystallization conditions on microstructure, such as amorphous phase and nanocrystalline phase, were investigated by X-ray diffractometry(XRD), differential scanning calorimetry(DSC), and transmission electron microscopy (TEM), respectively. The results show that nanocomposite Nd2Fe14B/α-Fe powder can be prepared by mechanical milling in argon atmosphere and a subsequent vacuum annealing treatment. The grain sizes of both Nd2Fe14B and α-Fe phase decrease drastically with increasing milling time. After milling for 5 h, the as-milled material consists of α-Fe nanocomposite phases with the grain size of 10 nm, and some amorphous phases, which can be turned into Nd2Fe14B/α-Fe nanocomposite phases by the subsequent annealing treatment. Milling energy of mechanical milling after 5 h by theoretical calculation is 6 154.25 kJ/g.

  11. Fe3S4 and Fe3O4 magnetic nanocrystals: magneto-optical and Mössbauer spectroscopy study

    Science.gov (United States)

    Lin, C.-R.; Tseng, Y.-T.; Ovchinnikov, S. G.; Ivantsov, R. D.; Edelman, I. S.; Fedorov, A. S.; Kuzubov, A. A.; Fedorov, D. A.; Starchikov, S. S.; Lyubutin, I. S.

    2014-04-01

    Iron oxide magnetite (Fe3O4) should be a reasonable analog for conception and understanding of the magnetic properties of iron sulfide greigite (Fe3S4)—one of the most required magnetic materials having numerous applications but being far from the complete understanding now. We present here a comparative study of the Mössbauer effect (ME) and the magnetic circular dichroism (MCD) spectroscopy of Fe3O4 and Fe3S4 nanoparticles. The ME spectrum parameters of Fe3S4 are shown to distinguish strongly from that of Fe3O4, and the MCD spectrum shapes are shown to be absolutely different for two compounds. To clarify the origin of the Fe3S4 MCD spectrum we have performed ab initio band structure calculations and identified the MCD spectrum features with the transitions between calculated energy states.

  12. Preparation and microwave properties of lamellar Fe/BaFeO2.5 composite particles with hydrogen-thermal reduction method

    Science.gov (United States)

    Gong, Yuanxun; Zhou, Zhongxiang; Jiang, Jiantang; Zhao, Hongjie

    2016-06-01

    Fe/BaFeO2.5 laminated composite particles were successfully prepared by hydrogen-thermal reducing BaFe12O19 particles. The average diameter of Fe/BaFeO2.5 composite particles is about 1 μm and the lamellar thickness is about 100 nm. The effective permittivity and permeability of Fe/BaFeO2.5 laminated composite particles were measured and EMA performance was evaluated. Compared with Fe particles with a similar diameter, the permeability of Fe/BaFeO2.5 composite particles is remarkably improved by the induction of insulator BaFeO2.5 phase. Due to the unique 2-dimension shape characteristic, ε‧ and μ‧ of Fe/BaFeO2.5 laminated composite particles is obviously higher than that of Fe/BaFeO2.5 composite particles without lamellar structure. EMA performance of coating containing Fe/BaFeO2.5 laminated composite particles as fillers is excellent, and a maximum reflection loss (RLmax) up to -29.94 dB was achieved in a coating of 1.36 mm. Meanwhile, the operation frequency band of coating containing Fe/BaFeO2.5 laminated composite particles as fillers covers completely X-band and Ku-band, which considerably wider than most of reported EMA coatings.

  13. Influence of Fe2 P on the Performance of LiFePO4/C Composite Material%Fe2 P对LiFePO4/C复合材料性能的影响

    Institute of Scientific and Technical Information of China (English)

    易惠华; 戴永年; 胡成林; 姚耀春

    2009-01-01

    Pure LiFePO4 and LiFePO4/C composite cathode materials were synthesized by solid-state method and effect of carbon coat-ing on the performance of LiFePO4 was studied. The XRD pattern of the pure LiFePO4 shows a siagh-phase olivine, but the ones of LiFePO4/C composite materials show a impurity phase Fe2P with high electronic conductivity. From the SEM images, it can be seen that the particle sizes of the samples are less than 1 μm. Though the carbon-coated samples have smaller particle sizes, some of them are in the form of particle agglomerates. The first cycle discharge capacity of the pure LiFePO4 reaches 136. 6 mAh/g, then the electro-conductive Fe2 P among LiFePO4/C increases the performance of them at high rate charge/discharge.%采用固相法合成LiFePO4和LiFePO4/C复合材料,研究了蔗糖分解的碳包覆对LiFePO4材料性能的影响.XRD检测纯LiFePO4为单一的橄榄石相,而LiFePO4/C复合材料中出现高导电物质Fe2P相;SEM显示样品的粒径均在1μm以下,包覆碳样品的晶粒更小,但出现团聚现象.此方法合成的纯LiFePO4初始容量高达136.6 mAh/g.Fe2P的存在使LiFePO4材料的大电流放电能力得到提高.

  14. On the transition rates of the Fe X and Fe XIV corona lines

    Energy Technology Data Exchange (ETDEWEB)

    Trabert, E

    2003-11-20

    Despite a considerable scatter of the theoretical predictions of the M1/E2 transition rate of the ''red iron line'' (FeX) in the solar corona, there is disagreement of all the results with the single measurement that used an electrostatic ion trap. Employing a heavy-ion storage ring for measuring the same transition in isoelectronic ions of Co, Ni, and Cu, the situation has been clarified, and a new data point for FeX can be determined by extrapolation. This result agrees with the basic atomic structure prediction for the line strength in combination with the experimental transition energy. For the ''green iron line'' (FeXIV), a recent measurement with an electron beam ion trap has resolved similar discrepancies.

  15. Extraordinary Hall effect on Fe-rich amorphous thin films and Fe-rich/Cu multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Michea, S. [Universidad de Santiago de Chile, Avda. Ecuador, 3493, Estacion Central, Santiago (Chile); Denardin, J.C., E-mail: juliano.denardin@usach.cl [Universidad de Santiago de Chile, Avda. Ecuador, 3493, Estacion Central, Santiago (Chile); Gamino, M.; Dorneles, L.S. [Departamento de Fisica, Universidade Federal de Santa Maria, Santa Maria 97105-900, RS (Brazil); Correa, M.A. [Departamento de Fisica Teorica e Experimental, Universidade Federal do Rio Grande do Norte, Campus Universitario Lagoa Seca, 59072-970 - Natal, RN - Brazil (Brazil)

    2012-08-15

    In this study we investigated the magnetic and transport properties of thin Fe-rich amorphous films and Fe-rich/Cu multilayers. We compared the extraordinary Hall effect in these two types of samples and discussed it in terms of thickness and sample structure. The thicker films exhibited a strong in-plane magnetic anisotropy, and by decreasing film thickness both saturated Hall resistivity and Hall sensitivity increase. A Hall resistivity value of 20 {mu} Ohm-Sign cm is observed in 100 nm thick Fe-rich films at 12 K and a sensitivity of 1.3 Ohm-Sign /T is obtained at room temperature. Electrical conductance increases and Hall resistivity decreases when the films are sandwiched with Cu.

  16. Characterization of the Fe-rich corner of Al-Fe-Si-Ti.

    Science.gov (United States)

    Marker, Martin C J; Duarte, Liliana I; Leinenbach, Christian; Richter, Klaus W

    2013-08-01

    The quaternary system Al-Fe-Si-Ti was studied in the iron-rich corner for sections at 50, 60 and 70 at.% Fe at 900 °C. Isothermal phase equilibria were investigated by a combination of optical microscopy, X-ray powder diffraction (XRD) followed by Rietveld refinement and Electron Probe Microanalysis (EPMA). Phase boundaries of the phases, in particular of the Laves phase (Fe2Ti) and of the extended phase field of A2/B2/D03, were investigated. Selected samples containing the Laves phase and the B2 phase were characterized by microhardness measurements at different compositions throughout the quaternary homogeneity range of the phases.

  17. Interfacial electronic transport phenomena in single crystalline Fe-MgO-Fe thin barrier junctions

    Energy Technology Data Exchange (ETDEWEB)

    Gangineni, R. B., E-mail: rameshg.phy@pondiuni.edu.in [Department of Physics, School of Physical, Chemical and Applied Sciences, Pondicherry University, R. V. Nagar, Kalapet, Pondicherry 605 014 (India); SPINTEC, UMR 8191 CEA/CNRS/UJF-Grenoble 1/Grenoble INP, INAC, 17 rue des Martyrs, F-38054 Grenoble Cedex (France); Bellouard, C., E-mail: christine.bellouard@ijl.nancy-universite.fr; Duluard, A. [Institut Jean Lamour, UMR 7198, CNRS-Université de Lorraine, BP 239, 54506 Vandoeuvre (France); Negulescu, B. [Institut Jean Lamour, UMR 7198, CNRS-Université de Lorraine, BP 239, 54506 Vandoeuvre (France); UFR de Sciences et Techniques, Matériaux, microélectronique, acoustique, nanotechnologies (GREMAN), University François Rabelais, Parc de Grandmont, 37200 Tours (France); Baraduc, C.; Gaudin, G. [SPINTEC, UMR 8191 CEA/CNRS/UJF-Grenoble 1/Grenoble INP, INAC, 17 rue des Martyrs, F-38054 Grenoble Cedex (France); Tiusan, C., E-mail: coriolan.tiusan@phys.utcluj.ro [Institut Jean Lamour, UMR 7198, CNRS-Université de Lorraine, BP 239, 54506 Vandoeuvre (France); Department of Physics and Chemistry, Center of Superconductivity, Spintronics and Surface Science, Technical University of Cluj Napoca, Str. Memorandumului No. 28, RO-400114 Cluj-Napoca (Romania)

    2014-05-05

    Spin filtering effects in nano-pillars of Fe-MgO-Fe single crystalline magnetic tunnel junctions are explored with two different sample architectures and thin MgO barriers (thickness: 3–8 monolayers). The two architectures, with different growth and annealing conditions of the bottom electrode, allow tuning the quality of the bottom Fe/MgO interface. As a result, an interfacial resonance states (IRS) is observed or not depending on this interface quality. The IRS contribution, observed by spin polarized tunnel spectroscopy, is analyzed as a function of the MgO barrier thickness. Our experimental findings agree with theoretical predictions concerning the symmetry of the low energy (0.2 eV) interfacial resonance states: a mixture of Δ{sub 1}-like and Δ{sub 5}-like symmetries.

  18. Na4Fe2+Fe3+(PO43, a new synthetic NASICON-type phosphate

    Directory of Open Access Journals (Sweden)

    Frédéric Hatert

    2009-04-01

    Full Text Available This paper reports the crystal structure of tetrasodium diiron tris(phosphate, Na4Fe2+Fe3+(PO43, which has been synthesized hydrothermally at 773 K and 0.1 GPa. The crystal structure has been refined in the space group Roverline{3}c and is identical to that of γ-NASICON. The heteropolyhedral framework is based on a regular alternation, in three dimensions, of corner-sharing PO4 tetrahedra and FeO6 octahedra, constituting so-called `lantern units' stacked along the c axis. The Na+ cations are distributed over two crystallographic sites: the six-coordinated Na1 site which lies between two `lantern units', and the eight-coordinated Na2 site which lies at the same z value as the P site.

  19. Ubiquitous high-FeO silicates in enstatite chondrites

    Science.gov (United States)

    Lusby, David; Scott, Edward R. D.; Keil, Klaus

    1987-01-01

    SEM and EMPA were used to determine the mineral contents of four EH3 chondrites. All four showed the dominant enstatite peak, Fs 0-5, with 4-8 percent of FeO-rich pyroxene with Fs 5-20. Among the 542 objects found to contain high-FeO silicates, 18 were chondrules, 381 were rimmed or unrimmed grains, and 143 were aggregates. The high-FeO silicates in these objects are very largely pyroxene with Fs 5-23. Large grains of both FeO-rich and FeO-poor silicates were found to be present in the FeO-rich chondrules. This fact, together with the absence of clasts of FeO-rich chondritic material in the EH3 chondrites, suggests that FeO-rich grains were introduced before or during chondrule formation. It is concluded that FeO-rich and FeO-poor silicates were both present in the nebular region where E chondrites originated.

  20. The wettability of Fe based alloy on TiO

    Institute of Scientific and Technical Information of China (English)

    李庆奎; 钟海云; 钟晖; 戴艳阳

    2002-01-01

    For developing TiO based imitated gold materials, the wettabilities of Fe and Fe-Cr-Ni-Ti on TiO were studied. The results indicated that the wettabilities of Fe and Fe-Cr on TiO were poor, and their wetting angles were about 90° at melting point. The wetting angles reduced with the increase of wetting temperature, but the influence of temperature was small. Fe and Fe-Cr containing Cr 50% or less could react with TiO on the interface to form Fe2Ti and Ti2O3, but this did not improve the wettability effectively. When Ni-Ti was added into Fe-Cr alloy, Ni3Ti was formed on the interface, which can reduce the interface energy, improve the wettability, and prevent the formation of Fe2Ti and Ti2O3. The wetting angles could go down to about 40° when 3% Ni-Ti was added to Fe-Cr alloy.

  1. The transcriptional response of Arabidopsis leaves to Fe deficiency

    Directory of Open Access Journals (Sweden)

    Jorge eRodriguez-Celma

    2013-07-01

    Full Text Available Due to its ease to donate or accept electrons, iron (Fe plays a crucial role in respiration and metabolism, including tetrapyrrole synthesis, in virtually all organisms. In plants, Fe is a component of the photosystems and thus essential for photosynthesis. Fe deficiency compromises chlorophyll (Chl synthesis, leading to interveinal chlorosis in developing leaves and decreased photosynthetic activity. To gain insights into the responses of photosynthetically active cells to Fe deficiency, we conducted transcriptional profiling experiments on leaves from Fe-sufficient and Fe-deficient plants using the RNA-seq technology. As anticipated, genes associated with photosynthesis and tetrapyrrole metabolism were dramatically down-regulated by Fe deficiency. A sophisticated response comprising the down-regulation of HEMA1 and NYC1, which catalyze the first committed step in tetrapyrrole biosynthesis and the conversion of Chl b to Chl a at the commencement of Chl breakdown, respectively, and the up-regulation of CGLD27, which is conserved in plastid-containing organisms and putatively involved in xanthophyll biosynthesis, indicates a carefully orchestrated balance of potentially toxic tetrapyrrole intermediates and functional end products to avoid photo-oxidative damage. Comparing the responses to Fe deficiency in leaves to that in roots confirmed subgroup 1b bHLH transcription factors and POPEYE/BRUTUS as important regulators of Fe homeostasis in both leaf and root cells, and indicated six novel players with putative roles in Fe homeostasis that were highly expressed in leaves and roots and greatly induced by Fe deficiency. The data further revealed down-regulation of organ-specific subsets of genes encoding ribosomal proteins, which may be indicative of a change in ribosomal composition that could bias translation. It is concluded that Fe deficiency causes a massive reorganization of plastid activity, which is adjusting leaf function to the availability

  2. The transcriptional response of Arabidopsis leaves to Fe deficiency.

    Science.gov (United States)

    Rodríguez-Celma, Jorge; Pan, I Chun; Li, Wenfeng; Lan, Ping; Buckhout, Thomas J; Schmidt, Wolfgang

    2013-01-01

    Due to its ease to donate or accept electrons, iron (Fe) plays a crucial role in respiration and metabolism, including tetrapyrrole synthesis, in virtually all organisms. In plants, Fe is a component of the photosystems and thus essential for photosynthesis. Fe deficiency compromises chlorophyll (Chl) synthesis, leading to interveinal chlorosis in developing leaves and decreased photosynthetic activity. To gain insights into the responses of photosynthetically active cells to Fe deficiency, we conducted transcriptional profiling experiments on leaves from Fe-sufficient and Fe-deficient plants using the RNA-seq technology. As anticipated, genes associated with photosynthesis and tetrapyrrole metabolism were dramatically down-regulated by Fe deficiency. A sophisticated response comprising the down-regulation of HEMA1 and NYC1, which catalyze the first committed step in tetrapyrrole biosynthesis and the conversion of Chl b to Chl a at the commencement of Chl breakdown, respectively, and the up-regulation of CGLD27, which is conserved in plastid-containing organisms and putatively involved in xanthophyll biosynthesis, indicates a carefully orchestrated balance of potentially toxic tetrapyrrole intermediates and functional end products to avoid photo-oxidative damage. Comparing the responses to Fe deficiency in leaves to that in roots confirmed subgroup 1b bHLH transcription factors and POPEYE/BRUTUS as important regulators of Fe homeostasis in both leaf and root cells, and indicated six novel players with putative roles in Fe homeostasis that were highly expressed in leaves and roots and greatly induced by Fe deficiency. The data further revealed down-regulation of organ-specific subsets of genes encoding ribosomal proteins, which may be indicative of a change in ribosomal composition that could bias translation. It is concluded that Fe deficiency causes a massive reorganization of plastid activity, which is adjusting leaf function to the availability of Fe.

  3. Diatom proteomics reveals unique acclimation strategies to mitigate Fe limitation.

    Directory of Open Access Journals (Sweden)

    Brook L Nunn

    Full Text Available Phytoplankton growth rates are limited by the supply of iron (Fe in approximately one third of the open ocean, with major implications for carbon dioxide sequestration and carbon (C biogeochemistry. To date, understanding how alteration of Fe supply changes phytoplankton physiology has focused on traditional metrics such as growth rate, elemental composition, and biophysical measurements such as photosynthetic competence (Fv/Fm. Researchers have subsequently employed transcriptomics to probe relationships between changes in Fe supply and phytoplankton physiology. Recently, studies have investigated longer-term (i.e. following acclimation responses of phytoplankton to various Fe conditions. In the present study, the coastal diatom, Thalassiosira pseudonana, was acclimated (10 generations to either low or high Fe conditions, i.e. Fe-limiting and Fe-replete. Quantitative proteomics and a newly developed proteomic profiling technique that identifies low abundance proteins were employed to examine the full complement of expressed proteins and consequently the metabolic pathways utilized by the diatom under the two Fe conditions. A total of 1850 proteins were confidently identified, nearly tripling previous identifications made from differential expression in diatoms. Given sufficient time to acclimate to Fe limitation, T. pseudonana up-regulates proteins involved in pathways associated with intracellular protein recycling, thereby decreasing dependence on extracellular nitrogen (N, C and Fe. The relative increase in the abundance of photorespiration and pentose phosphate pathway proteins reveal novel metabolic shifts, which create substrates that could support other well-established physiological responses, such as heavily silicified frustules observed for Fe-limited diatoms. Here, we discovered that proteins and hence pathways observed to be down-regulated in short-term Fe starvation studies are constitutively expressed when T. pseudonana is

  4. New Insights into Fe Localization in Plant Tissues

    Directory of Open Access Journals (Sweden)

    Hannetz eRoschzttardtz

    2013-09-01

    Full Text Available Deciphering cellular iron (Fe homeostasis requires having access to both quantitative and qualitative information on the subcellular pools of Fe in tissues and their dynamics within the cells. We have taken advantage of the Perls/DAB Fe staining procedure to perform a systematic analysis of Fe distribution in roots, leaves and reproductive organs of the model plant Arabidopsis thaliana, using wild-type and mutant genotypes affected in iron transport and storage. Roots of soil-grown plants accumulate iron in the apoplast of the central cylinder, a pattern that is strongly intensified when the citrate effluxer FRD3 is not functional, thus stressing the importance of citrate in the apoplastic movement of Fe. In leaves, Fe level is low and only detected in and around vascular tissues. In contrast, Fe staining in leaves of iron-treated plants extends in the surrounding mesophyll cells where Fe deposits, likely corresponding to Fe-ferritin complexes, accumulate in the chloroplasts. The loss of ferritins in the fer1,3,4 triple mutant provoked a massive accumulation of Fe in the apoplastic space, suggesting that in the absence of iron buffering in the chloroplast, cells activate iron efflux and/or repress iron influx to limit the amount of iron in the cell. In flowers, Perls/DAB staining has revealed a major sink for Fe in the anthers. In particular, developing pollen grains accumulate detectable amounts of Fe in small-size intracellular bodies that aggregate around the vegetative nucleus at the binuclear stage and that were identified as amyloplasts. In conclusion, using the Perls/DAB procedure combined to selected mutant genotypes, this study has established a reliable atlas of Fe distribution in the main Arabidopsis organs, proving and refining long-assumed intracellular locations and uncovering new ones. This iron map of Arabidopsis will serve as a basis for future studies of possible actors of iron movement in plant tissues and cell compartments.

  5. Elastic anharmonicity of bcc Fe and Fe-based random alloys from first-principles calculations

    Science.gov (United States)

    Li, Xiaoqing; Schönecker, Stephan; Zhao, Jijun; Vitos, Levente; Johansson, Börje

    2017-01-01

    We systematically investigate elastic anharmonic behavior in ferromagnetic body-centered cubic (bcc) Fe and Fe1 -xMx (M =Al , V, Cr, Co, or Ni) random alloys by means of density-functional simulations. To benchmark computational accuracy, three ab initio codes are used to obtain the complete set of second- and third-order elastic constants (TOECs) for bcc Fe. The TOECs of Fe1 -xMx alloys are studied employing the first-principles alloy theory formulated within the exact muffin-tin orbital method in combination with the coherent-potential approximation. It is found that the alloying effects on C111,C112 , and C123, which are governed by normal strains only, are more pronounced than those on C144,C166 , and C456, which involve shear strains. Remarkably, the magnitudes of all TOECs but C123 decrease upon alloying with Al, V, Cr, Co, or Ni. Using the computed TOECs, we study compositional effects on the pressure derivatives of the effective elastic constants (d Bi j/d P ), bulk (d K /d P ), and shear moduli (d G /d P ) and derive longitudinal acoustic nonlinearity parameters (β ). Our predictions show that the pressure derivatives of K and G decrease with x for all solute elements and reveal a strong correlation between the compositional trends on d K /d P and d G /d P arising from the fact that alloying predominantly alters d B11/d P . The sensitivity of d B11/d P to composition is attributed to intrinsic alloying effects as opposed to lattice parameter changes accompanying solute addition. For Fe and the considered Fe-based alloys, β along high-symmetry directions orders as β [111 ]>β [100 ]>β [110 ] , and alloying increases the directional anisotropy of β but reduces its magnitude.

  6. Magnetoelectric effect in FeCo/PMN-PT/FeCo trilayers prepared by electroless deposition of FeCo on PMN-PT crystals with various orientations

    Energy Technology Data Exchange (ETDEWEB)

    Shen, H.Q.; Wang, Y.G., E-mail: yingang.wang@nuaa.edu.cn; Xie, D.; Cheng, J.H.

    2014-10-15

    Highlights: • The composites FeCo/PMN-PT/FeCo were prepared by electroless deposition. • The influence of the crystal cut of PMN-PT on ME coupling is discussed. • Optimizing the crystal cut of the piezoelectric substrate, proper resonant frequency and ME effect could be obtained. - Abstract: The magnetoelectric (ME) effect was studied in the FeCo/PMN-PT/FeCo trilayer composites prepared by electroless deposition of the FeCo layers on the single crystal PMN-PT substrates with various crystal cuts. X-ray diffraction reveals that the orientation of PMN-PT substrate has no effect on the growth of FeCo layer. The structures with PMN-PT crystals of various orientations have different acoustic resonance frequencies. FeCo/PMN-PT/FeCo composites with PMN-PT of 〈0 0 1〉{sup L} × 〈01{sup ‾}1〉{sup W} × 〈0 1 1〉{sup T} crystal cut shows superior ME performance, which is due to the highest piezoelectric module of PMN-PT.

  7. Reduced-temperature ordering of FePt nanoparticle assembled films by Fe30Pt70/Fe3O4 core/shell structure

    Institute of Scientific and Technical Information of China (English)

    He Shu-Li; Peng Yin; Liu Li-Li; Jiang Hong-Wei; Liu Li-Feng; Zheng Wu; Wang Ai-Ling

    2007-01-01

    In this paper, Fe3oPt70/Fe3O4 core/shell nanoparticles were synthesized by chemical routine and the layered polycthylenimine (PEI)-Fe30Pt70/Fe3O4 structure was constructed by molecule-mediated self-assembly technique. The dimension of core/shell structured nanoparticles was that of 4nm core and 2 nm shell. After annealing under a flow of forming gas (50%Ar2%%30%H2) for 1h at or above 400℃, the iron oxide shell was reduced to Fe and diffused to Pt-rich core, which leaded to the formation of L10 phase FePt at low temperature. The x-ray diffraction results and magnetic properties measurement showed that the chemical ordering temperature of Fe30Pt70/Fe3O4 core/shell nanoparticles assembly can be reduced to as low as 400℃. The sample annealed at 400℃ showed the coercivity of 4 KOe with the applied field of 1.5T. The core/shell structure was suggested to be an effective way to reduce the ordering temperature obviously.

  8. New insights into [FeFe] hydrogenase activation and maturase function.

    Directory of Open Access Journals (Sweden)

    Jon M Kuchenreuther

    Full Text Available [FeFe] hydrogenases catalyze H(2 production using the H-cluster, an iron-sulfur cofactor that contains carbon monoxide (CO, cyanide (CN(-, and a dithiolate bridging ligand. The HydE, HydF, and HydG maturases assist in assembling the H-cluster and maturing hydrogenases into their catalytically active form. Characterization of these maturases and in vitro hydrogenase activation methods have helped elucidate steps in the H-cluster biosynthetic pathway such as the HydG-catalyzed generation of the CO and CN(- ligands from free tyrosine. We have refined our cell-free approach for H-cluster synthesis and hydrogenase maturation by using separately expressed and purified HydE, HydF, and HydG. In this report, we illustrate how substrates and protein constituents influence hydrogenase activation, and for the first time, we show that each maturase can function catalytically during the maturation process. With precise control over the biomolecular components, we also provide evidence for H-cluster synthesis in the absence of either HydE or HydF, and we further show that hydrogenase activation can occur without exogenous tyrosine. Given these findings, we suggest a new reaction sequence for the [FeFe] hydrogenase maturation pathway. In our model, HydG independently synthesizes an iron-based compound with CO and CN(- ligands that is a precursor to the H-cluster [2Fe](H subunit, and which we have termed HydG-co. We further propose that HydF is a transferase that stabilizes HydG-co and also shuttles the complete [2Fe](H subcluster to the hydrogenase, a translocation process that may be catalyzed by HydE. In summary, this report describes the first example of reconstructing the [FeFe] hydrogenase maturation pathway using purified maturases and subsequently utilizing this in vitro system to better understand the roles of HydE, HydF, and HydG.

  9. Morphological evolution of prussian yellow Fe[Fe(CN)6] colloidal nanospheres

    Science.gov (United States)

    Gu, Jianmin; Fu, Shaoyan; Jin, Cuihong; Liu, Xin; Gao, Yahui; Wu, Jingxiao; Bian, Zhenpan; Tian, Hua; Wang, Lin; Gao, Faming

    2016-07-01

    A simple hydrothermal system was developed for controllable morphologies of the Prussian yellow Fe[Fe(CN)6] nanostructures in the presence of organic additives. Hollow and solid nanospheres of the Prussian yellow materials were successfully synthesized with suitable experimental conditions. It is found that the amounts of organic additives CTAB could result in the formation of the spherical nanocrystals and the hydrolysis of phosphate in the solution could play a role in the final morphology of the products. A possible formation mechanism of the Prussian yellow nanostructures is proposed.

  10. Anisotropies in sputtered FeCoV films and FeCoV/Ti:N multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Clemens, D.; Vananti, A.; Terrier, C.; Boeni, P.; Schnyder, B.; Tixier, S.; Horisberger, M. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-09-01

    SQUID and MOKE magnetometry as well as mechanical and X-ray stress analysis have been used in order to prove the magnetostrictive nature of the anisotropy in Fe{sub 0.50}Co{sub 0.48}V{sub 0.02} films and Fe{sub 0.50}Co{sub 0.48}V{sub 0.02} /Ti:N multilayers. The investigation stresses on the dependence on the sputter gas pressure and on the thickness of the deposited layer. (author) 1 fig., 6 refs.

  11. Electrical switching in Fe/V/MgO/Fe tunnel junctions

    Science.gov (United States)

    Najjari, N.; Halley, D.; Bowen, M.; Majjad, H.; Henry, Y.; Doudin, B.

    2010-05-01

    Bipolar hysteretic resistance switching in epitaxial Fe/V/MgO/Fe magnetic tunnel junctions is observed in highly reproducible I(V) curves and found to be modified by the frequency of the bias voltage sweep. Observation of slow relaxation of the resistance state values is reported. A model is proposed that takes into account the incidence of time-dependent electric-field-induced migration of atomic species on the effective barrier thickness. This model provides a good qualitative agreement with experimental data.

  12. Electrical switching in Fe /Cr/MgO/Fe magnetic tunnel junctions

    Science.gov (United States)

    Halley, D.; Majjad, H.; Bowen, M.; Najjari, N.; Henry, Y.; Ulhaq-Bouillet, C.; Weber, W.; Bertoni, G.; Verbeeck, J.; Van Tendeloo, G.

    2008-05-01

    Hysteretic resistance switching is observed in epitaxial Fe /Cr/MgO/Fe magnetic tunnel junctions under bias voltage cycling between negative and positive values of about 1V. The junctions switch back and forth between high- and low-resistance states, both of which depend on the device bias history. A linear dependence is found between the magnitude of the tunnel magnetoresistance and the crafted resistance of the junctions. To explain these results, a model is proposed that considers electron transport both by elastic tunneling and by defect-assisted transmission.

  13. Phase Transformations in Low-Fe Alloys of the Al-Cu-Fe System

    Institute of Scientific and Technical Information of China (English)

    Liming Zhang

    2004-01-01

    Microstructure and phase transformation in the Al-Cu-Fe alloys of the approximate compositional range of 20 -50 at.% Cu and 2 - 10 Fe at.% have been investigated from samples quenched from their respective temperatures by means of different thermal analysis, magnetothermal analysis, scanning electron microscopy, electron probe analysis and powder X-ray diffraction. Representative phase transformations categorized as polymorphic, discontinuous precipitation,quasi-binary eutectoid, and ternary transitional U-type phase transformation are presented. These phase transformations were found to have a common feature which consumes the β phase and appears the φ phase. A schematic diagram was proposed to demonstrate the transition processes with decreasing temperature.

  14. High-temperature ferromagnetism in heavily Fe-doped ferromagnetic semiconductor (Ga,Fe)Sb

    Energy Technology Data Exchange (ETDEWEB)

    Tu, Nguyen Thanh [Department of Electrical Engineering and Information Systems, The University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo 113-8656 (Japan); Department of Physics, Ho Chi Minh City University of Pedagogy, 280, An Duong Vuong Street, District 5, Ho Chi Minh City 748242 (Viet Nam); Hai, Pham Nam [Department of Electrical Engineering and Information Systems, The University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo 113-8656 (Japan); Department of Physical Electronics, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro, Tokyo 152-0033 (Japan); Center for Spintronics Research Network (CSRN), The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan); Anh, Le Duc [Department of Electrical Engineering and Information Systems, The University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo 113-8656 (Japan); Tanaka, Masaaki [Department of Electrical Engineering and Information Systems, The University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo 113-8656 (Japan); Center for Spintronics Research Network (CSRN), The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

    2016-05-09

    We show high-temperature ferromagnetism in heavily Fe-doped ferromagnetic semiconductor (Ga{sub 1−x},Fe{sub x})Sb (x = 23% and 25%) thin films grown by low-temperature molecular beam epitaxy. Magnetic circular dichroism spectroscopy and anomalous Hall effect measurements indicate intrinsic ferromagnetism of these samples. The Curie temperature reaches 300 K and 340 K for x = 23% and 25%, respectively, which are the highest values reported so far in intrinsic III-V ferromagnetic semiconductors.

  15. Fe(III)EDTA and Fe(II)EDTA-NO reduction by a sulfate reducing bacterium in NO and SO₂ scrubbing liquor.

    Science.gov (United States)

    Chen, Mingxiang; Zhou, Jiti; Zhang, Yu; Wang, Xiaojun; Shi, Zhuang; Wang, Xiaowei

    2015-03-01

    A viable process concept, based on NO and SO2 absorption into an alkaline Fe(II)EDTA (EDTA: ethylenediaminetetraacetic acid) solution in a scrubber combined with biological reduction of the absorbed SO2 utilizing sulfate reducing bacteria (SRB) and regeneration of the scrubbing liquor in a single bioreactor, was developed. The SRB, Desulfovibrio sp. CMX, was used and its sulfate reduction performances in FeEDTA solutions and Fe(II)EDTA-NO had been investigated. In this study, the detailed regeneration process of Fe(II)EDTA solution, which contained Fe(III)EDTA and Fe(II)EDTA-NO reduction processes in presence of D. sp. CMX and sulfate, was evaluated. Fe(III)EDTA and Fe(II)EDTA-NO reduction processes were primarily biological, even if Fe(III)EDTA and Fe(II)EDTA-NO could also be chemically convert to Fe(II)EDTA by biogenic sulfide. Regardless presence or absence of sulfate, more than 87 % Fe(III)EDTA and 98 % Fe(II)EDTA-NO were reduced in 46 h, respectively. Sulfate and Fe(III)EDTA had no affection on Fe(II)EDTA-NO reduction. Sulfate enhanced final Fe(III)EDTA reduction. Effect of Fe(III)EDTA on Fe(II)EDTA-NO reduction rate was more obvious than effect of sulfate on Fe(II)EDTA-NO reduction rate before 8 h. To overcome toxicity of Fe(II)EDTA-NO on SRB, Fe(II)EDTA-NO was reduced first and the reduction of Fe(III)EDTA and sulfate occurred after 2 h. First-order Fe(II)EDTA-NO reduction rate and zero-order Fe(III)EDTA reduction rate were detected respectively before 8 h.

  16. Al/Fe isomorphic substitution versus Fe{sub 2}O{sub 3} clusters formation in Fe-doped aluminosilicate nanotubes (imogolite)

    Energy Technology Data Exchange (ETDEWEB)

    Shafia, Ehsan [Politecnico di Torino, Department of Applied Science and Technology and INSTM Unit of Torino-Politecnico (Italy); Esposito, Serena [Università degli Studi di Cassino e del Lazio Meridionale, Department of Civil and Mechanical Engineering (Italy); Manzoli, Maela; Chiesa, Mario [Università di Torino, Dipartimento di Chimica and Centro Interdipartimentale NIS (Italy); Tiberto, Paola [Electromagnetism, I.N.Ri.M. (Italy); Barrera, Gabriele [Università di Torino, Dipartimento di Chimica and Centro Interdipartimentale NIS (Italy); Menard, Gabriel [Harvard University, Department of Chemistry and Chemical Biology (United States); Allia, Paolo, E-mail: paolo.allia@polito.it [Politecnico di Torino, Department of Applied Science and Technology and INSTM Unit of Torino-Politecnico (Italy); Freyria, Francesca S. [Massachusetts Institute of Technology, Department of Chemistry (United States); Garrone, Edoardo; Bonelli, Barbara, E-mail: barbara.bonelli@polito.it [Politecnico di Torino, Department of Applied Science and Technology and INSTM Unit of Torino-Politecnico (Italy)

    2015-08-15

    Textural, magnetic and spectroscopic properties are reported of Fe-doped aluminosilicate nanotubes (NTs) of the imogolite type, IMO, with nominal composition (OH){sub 3}Al{sub 2−x}Fe{sub x}O{sub 3}SiOH (x = 0, 0.025, 0.050). Samples were obtained by either direct synthesis (Fe-0.025-IMO, Fe-0.050-IMO) or post-synthesis loading (Fe-L-IMO). The Fe content was either 1.4 wt% (both Fe-0.050-IMO and Fe-L-IMO) or 0.7 wt% (Fe-0.025-IMO). Textural properties were characterized by High-Resolution Transmission Electron Microscopy, X-ray diffraction and N{sub 2} adsorption/desorption isotherms at 77 K. The presence of different iron species was studied by magnetic moment measurements and three spectroscopies: Mössbauer, UV–Vis and electron paramagnetic resonance, respectively. Fe{sup 3+}/Al{sup 3+} isomorphic substitution (IS) at octahedral sites at the external surface of NTs is the main process occurring by direct synthesis at low Fe loadings, giving rise to the formation of isolated high-spin Fe{sup 3+} sites. Higher loadings give rise, besides IS, to the formation of Fe{sub 2}O{sub 3} clusters. IS occurs up to a limit of Al/Fe atomic ratio of ca. 60 (corresponding to x = 0.032). A fraction of the magnetism related to NCs is pinned by the surface anisotropy; also, clusters are magnetically interacting with each other. Post-synthesis loading leads to a system rather close to that obtained by direct synthesis, involving both IS and cluster formations. Slightly larger clusters than with direct synthesis samples, however, are formed. The occurrence of IS indicates a facile cleavage/sealing of Al–O–Al bonds: this opens the possibility to exchange Al{sup 3+} ions in pre-formed IMO NTs, a much simpler procedure compared with direct synthesis.

  17. Expression of a clostridial [FeFe]-hydrogenase in Chlamydomonas reinhardtii prolongs photo-production of hydrogen from water splitting

    Energy Technology Data Exchange (ETDEWEB)

    Noone, Seth; Ratcliff, Kathleen; Davis, ReAnna; Subramanian, Venkataramanan; Meuser, Jonathan; Posewitz, Matthew C.; King, Paul W.; Ghirardi, Maria L.

    2017-03-01

    The high oxygen (O2) sensitivity of green algal [FeFe]-hydrogenases is a significant limitation for the sustained production of hydrogen gas (H2) from photosynthetic water splitting. To address this limitation we replaced the native [FeFe]-hydrogenases with a more O2-tolerant clostridial [FeFe]-hydrogenase CaI in Chlamydomonas reinhardtii strain D66..delta..HYD (hydA1-hydA2-) that contains insertionally inactivated [FeFe]-hydrogenases genes. Expression and translocation of CaI in D66..delta..HYD led to the recovery of H2 photoproduction at ~ 20% of the rates of the wild-type parent strain D66. We show for the first time that a bacterial [FeFe]-hydrogenase can be expressed, localized and matured to a catalytically active form that couples to photosynthetic electron transport in the green alga C. reinhardtii. The lower rates of O2 inactivation of CaI led to more sustained H2 photoproduction when cultures were challenged with O2 or kept under prolonged illumination at solar intensities. These results provide new insights into the requisites for attaining photobiological H2 production from water splitting using a more O2-tolerant hydrogenase.

  18. Non-collinear exchange coupling in Fe/Mn/Fe(0 0 1): insight from scanning tunneling microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Pierce, D.T. E-mail: daniel.pierce@nist.gov; Davies, A.D.; Stroscio, J.A.; Tulchinsky, D.A.; Unguris, J.; Celotta, R.J

    2000-12-01

    The film growth and morphology of epitaxial Mn films grown on Fe(0 0 1) single-crystal whiskers measured with scanning tunneling microscopy (STM) provides insight into the mechanism of interlayer exchange coupling in Fe/Mn/Fe(0 0 1) trilayers. The proximity model of Slonczewski for exchange coupling through an antiferromagnet predicts that the coupling angle between the ferromagnetic layers will oscillate around a mean value of 90 deg. with an amplitude that is very sensitive to the width of the thickness distribution of the spacer layer. We measure the thickness distribution with the STM and find that the coupling angle variation predicted by the proximity model is qualitatively consistent with the actual coupling angle variations in Fe/Mn/Fe(0 0 1) measured with scanning electron microscopy with polarization analysis (SEMPA). Going beyond the proximity model and allowing for a non-uniform magnetization of the thin Fe overlayer provides an improved explanation of the results. We contrast the behavior of Fe/Mn/Fe(0 0 1), where the proximity model appears applicable, to coupling through antiferro-magnetic Cr in Fe/Cr/Fe(0 0 1), where it is not, and discuss possible reasons for the difference.

  19. Thick CoFeB with perpendicular magnetic anisotropy in CoFeB-MgO based magnetic tunnel junction

    Directory of Open Access Journals (Sweden)

    V. B. Naik

    2012-12-01

    Full Text Available We have investigated the effect of an ultra-thin Ta insertion in the CoFeB (CoFeB/Ta/CoFeB free layer (FL on magnetic and tunneling magnetoresistance (TMR properties of a CoFeB-MgO system with perpendicular magnetic anisotropy (PMA. It is found that the critical thickness (tc to sustain PMA is doubled (tc = 2.6 nm in Ta-inserted CoFeB FL as compared to single CoFeB layer (tc = 1.3 nm. While the effective magnetic anisotropy is found to increase with Ta insertion, the saturation magnetization showed a slight reduction. As the CoFeB thickness increasing, the thermal stability of Ta inserted structure is significantly increased by a factor of 2.5 for total CoFeB thickness less than 2 nm. We have observed a reasonable value of TMR for a much thicker CoFeB FL (thickness = 2-2.6 nm with Ta insertion, and without significant increment in resistance-area product. Our results reveal that an ultra-thin Ta insertion in CoFeB might pay the way towards developing the high-density memory devices with enhanced thermal stability.

  20. Effect of Selective Co Addition on Magnetic Properties of Nd2(FeCo)14B/alpha-Fe Nanocomposite Magnets

    Science.gov (United States)

    2012-12-13

    uta.edu Received 17 July 2012, in final form 11 October 2012 Published 13 December 2012 Online at stacks.iop.org/JPhysD/46/045001 Abstract Nd2Fe14B /α-Fe...obtained in the isotropic Nd2(FeCo)14B/α-(FeCo) nanocomposite magnets compared with 15 MG Oe of Nd2Fe14B /α-Fe nanocomposite magnets prepared under the...The effect of Co addition on magnetic properties of the Nd2Fe14B single phase has been extensively studied since the initial discovery of the Nd–Fe

  1. Core-Shell Nanostructure of α-Fe2O3/Fe3O4: Synthesis and Photocatalysis for Methyl Orange

    OpenAIRE

    Yang Tian; Di Wu; Xiao Jia; Binbin Yu; Sihui Zhan

    2011-01-01

    Fe3O4 nanoparticle was synthesized in the solution involving water and ethanol. Then, α-Fe2O3 shell was produced in situ on the surface of the Fe3O4 nanoparticle by surface oxidation in molten salts, forming α-Fe2O3/Fe3O4 core-shell nanostructure. It was showed that the magnetic properties transformed from ferromagnetism to superparamagnetism after the primary Fe3O4 nanoparticles were oxidized. Furthermore, the obtained α-Fe2O3/Fe3O4 core-shell nanoparticles were used to photocatalyse solutio...

  2. Flooding impairs Fe uptake and distribution in Citrus due to the strong down-regulation of genes involved in Strategy I responses to Fe deficiency in roots.

    Directory of Open Access Journals (Sweden)

    Mary-Rus Martínez-Cuenca

    Full Text Available This work determines the ffects of long-term anoxia conditions--21 days--on Strategy I responses to iron (Fe deficiency in Citrus and its impact on Fe uptake and distribution. The study was carried out in Citrus aurantium L. seedlings grown under flooding conditions (S and in both the presence (+Fe and absence of Fe (-Fe in nutritive solution. The results revealed a strong down-regulation (more than 65% of genes HA1 and FRO2 coding for enzymes proton-ATPase and Ferric-Chelate Reductase (FC-R, respectively, in -FeS plants when compared with -Fe ones. H+-extrusion and FC-R activity analyses confirmed the genetic results, indicating that flooding stress markedly repressed acidification and reduction responses to Fe deficiency (3.1- and 2.0-fold, respectively. Waterlogging reduced by half Fe concentration in +FeS roots, which led to 30% up-regulation of Fe transporter IRT1, although this effect was unable to improve Fe absorption. Consequently, flooding inhibited 57Fe uptake in +Fe and -Fe seedlings (29.8 and 66.2%, respectively and 57Fe distribution to aerial part (30.6 and 72.3%, respectively. This evidences that the synergistic action of both enzymes H+-ATPase and FC-R is the preferential regulator of the Fe acquisition system under flooding conditions and, hence, their inactivation implies a limiting factor of citrus in their Fe-deficiency tolerance in waterlogged soils.

  3. Cd Mobility in Anoxic Fe-Mineral-Rich Environments - Potential Use of Fe(III)-Reducing Bacteria in Soil Remediation

    Science.gov (United States)

    Muehe, E. M.; Adaktylou, I. J.; Obst, M.; Schröder, C.; Behrens, S.; Hitchcock, A. P.; Tylsizczak, T.; Michel, F. M.; Krämer, U.; Kappler, A.

    2014-12-01

    Agricultural soils are increasingly burdened with heavy metals such as Cd from industrial sources and impure fertilizers. Metal contaminants enter the food chain via plant uptake from soil and negatively affect human and environmental health. New remediation approaches are needed to lower soil metal contents. To apply these remediation techniques successfully, it is necessary to understand how soil microbes and minerals interact with toxic metals. Here we show that microbial Fe(III) reduction initially mobilizes Cd before its immobilization under anoxic conditions. To study how microbial Fe(III) reduction influences Cd mobility, we isolated a new Cd-tolerant, Fe(III)-reducing Geobacter sp. from a heavily Cd-contaminated soil. In lab experiments, this Geobacter strain first mobilized Cd from Cd-loaded Fe(III) hydroxides followed by precipitation of Cd-bearing mineral phases. Using Mössbauer spectroscopy and scanning electron microscopy, the original and newly formed Cd-containing Fe(II) and Fe(III) mineral phases, including Cd-Fe-carbonates, Fe-phosphates and Fe-(oxyhydr)oxides, were identified and characterized. Using energy-dispersive X-ray spectroscopy and synchrotron-based scanning transmission X-ray microscopy, Cd was mapped in the Fe(II) mineral aggregates formed during microbial Fe(III) reduction. Microbial Fe(III) reduction mobilizes Cd prior to its precipitation in Cd-bearing mineral phases. The mobilized Cd could be taken up by phytoremediating plants, resulting in a net removal of Cd from contaminated sites. Alternatively, Cd precipitation could reduce Cd bioavailability in the environment, causing less toxic effects to crops and soil microbiota. However, the stability and thus bioavailability of these newly formed Fe-Cd mineral phases needs to be assessed thoroughly. Whether phytoremediation or immobilization of Cd in a mineral with reduced Cd bioavailability are feasible mechanisms to reduce toxic effects of Cd in the environment remains to be

  4. Enhanced dechlorination of 2,4-dichlorophenol by recoverable Ni/Fe-Fe3O4 nanocomposites.

    Science.gov (United States)

    Xu, Cancan; Liu, Rui; Chen, Lvjun; Tang, Jialu

    2016-10-01

    Ni/Fe-Fe3O4 nanocomposites were synthesized for dechlorination of 2,4-dichlorophenol (2,4-DCP). The effects of the Ni content in Ni/Fe-Fe3O4 nanocomposites, solution pH, and common dissolved ions on the dechlorination efficiency were investigated, in addition to the reusability of the nanocomposites. The results showed that increasing content of Ni in Ni/Fe-Fe3O4 nanocomposites, from 1 to 5wt.%, greatly increased the dechlorination efficiency; the Ni/Fe-Fe3O4 nanocomposites had much higher dechlorination efficiency than bare Ni/Fe nanoparticles. Ni content of 5wt.% and initial pH below 6.0 was found to be the optimal conditions for the catalytic dechlorination of 2,4-DCP. Both 2,4-DCP and the intermediate product 2-chlorophenol (2-CP) were completely removed, and the concentration of the final product phenol was close to the theoretical phenol production from complete dechlorination of 20mg/L of 2,4-DCP, after 3hr reaction at initial pH value of 6.0, 3g/L Ni/Fe-Fe3O4, 5wt.% Ni content in the composite, and temperature of 22°C. 2,4-DCP dechlorination was enhanced by Cl(-) and inhibited by NO3(-) and SO4(2-). The nanocomposites were easily separated from the solution by an applied magnetic field. When the catalyst was reused, the removal efficiency of 2,4-DCP was almost 100% for the first seven uses, and gradually decreased to 75% in cycles 8-10. Therefore, the Ni/Fe-Fe3O4 nanocomposites can be considered as a potentially effective tool for remediation of pollution by 2,4-DCP.

  5. Effect of Post Annealing on the Microstructure and Magnetic Properties of NdFeB/α-Fe/NdFeB Thin Films

    Institute of Scientific and Technical Information of China (English)

    Zhang Lina; Zhang Mingang; Yi Meiqing

    2007-01-01

    A series of nanocomposite thin films, composed of Nd2Fe14B and α-Fe, has been prepared by DC-magnetron sputtering combined ion beam sputtering onto Si (100) substrates. The effects of post annealing on the microstructure and magnetic properties of [NdFeB/α-Fe/NdFeB]-type thin films have been investigated. The X-ray diffraction (XRD) study showed that annealing of the films for 30min at temperatures 550,600,650,700℃ resulted in the appearance of diffraction peaks, characteristic for Nd2Fe14B tetragonal structure, α-Fe and Nd2O3 phases. The investigation using the Vibrating Sample Magnetometer (VSM) with a maximum applied field of 2 T indicated that with the increase of the annealing temperature, the magnetic properties of the multilayer films were improved and reached peak value at 650℃ (Hci=41.72kA·m-1, Mr/Ms=0.4, (BH)max=30.35kJ·m-3), after which the magnetic properties were decreased greatly. Along with the increase of the thickness of α-Fe layer from Tα-Fe16nm, the coercivity Hci, saturation magnetization Ms, and remanence ratio Mr/Ms all declined. As the Atomic Force Microscope (AFM) indicated, after being annealed at 650℃ for 30min, the sample was showed fine surface morphology with grain size 60nm≤dα-Fe≤80nm and 100nm≤dNdFeB≤150nm.

  6. Speciative Determination of Dissolved Inorganic Fe(II, Fe(III and Total Fe in Natural Waters by Coupling Cloud Point Extraction with FAAS

    Directory of Open Access Journals (Sweden)

    Ramazan GÜRKAN

    2013-12-01

    Full Text Available A new cloud point extraction (CPE method for the preconcentration of trace iron speciation in natural waters prior to determination by flame atomic absorption spectrometry (FAAS was developed in the present study. In this method, Fe(II sensitively and selectively reacts with Calcon carboxylic acid (CCA in presence of cetylpyridinium chloride (CPC yielding a hydrophobic complex at pH 10.5, which is then entrapped in surfactant-rich phase. Total Fe was accurately and reliably determined after the reduction of Fe(III to Fe(II with sulfite. The amount of Fe(III in samples was determined from the difference between total Fe and Fe(II. CPC was used not only as an auxiliary ligand in CPE, but also as sensitivity enhancement agent in FAAS. The nonionic surfactant, polyethylene glycol tert-octylphenyl ether (Triton X-114 was used as an extracting agent. The analytical variables affecting CPE efficiency were investigated in detail. The preconcentration/enhancement factors of 50 and 82 respectively, were obtained for the preconcentration of Fe(II with 50 mL solution. Under the optimized conditions, the detection limit of Fe(II in linear range of 0.2-60 μg L-1 was 0.06 μg L-1. The relative standard deviation was 2.7 % (20 μg L-1, N: 5, recoveries for Fe(II were in range of 99.0-102.0% for all water samples including certified reference materials (CRMs. In order to verify its accuracy, two CRMs were analyzed and the results obtained were statistically in good agreement with the certified values.

  7. Superconductivity in Co-doped SmFeAsO

    Energy Technology Data Exchange (ETDEWEB)

    Qi Yanpeng; Gao Zhaoshun; Wang Lei; Wang Dongliang; Zhang Xianping; Ma Yanwei [Key Laboratory of Applied Superconductivity, Institute of Electrical Engineering, Chinese Academy of Sciences, PO Box 2703, Beijing 100190 (China)], E-mail: ywma@mail.iee.ac.cn

    2008-11-15

    Here we report the synthesis and characterizations of SmFe{sub 1-x}Co{sub x}AsO (x = 0.10, 0.15) for the first time. The parent compound SmFeAsO itself is not superconducting but shows an antiferromagnetic order near 150 K, which must be suppressed by doping before superconductivity emerges. With Co doping in the FeAs planes, antiferromagnetic order is destroyed and superconductivity occurs at 15.2 K. Similar to LaFe{sub 1-x}Co{sub x}AsO, the SmFe{sub 1-x}Co{sub x}AsO system appears to tolerate considerable disorder in the FeAs planes. This result is important, suggesting a different mechanism for cuprate superconductors compared to the iron-based arsenide ones.

  8. Magnetization and neutron diffraction studies on FeCrP

    Indian Academy of Sciences (India)

    Sudhish Kumar; Anjali Krishnamurthy; Bipin K Srivastava; A Das; S K Paranjpe

    2004-08-01

    Crystal structure and magnetic behaviour of FeCrP have been investigated using magnetization and neutron diffraction measurements. FeCrP crystallizes in orthorhombic FeZrP type structure (nma space group, = 4) in which Cr atoms occupy the pyramidal site and Fe atoms occupy the tetrahedral site with total preference. Structural parameters including positional parameters have been refined. The refined values of positional parameters for Fe and Cr are quite different from those in FeZrP. The nature of magnetization{temperature curve is suggestive of antiferromagnetic nature with N = 280 (± 10) K. Preliminary analysis of neutron diffraction pattern at 13 K is indicative of a rather complicated magnetic structure.

  9. Fe doped Magnetic Nanodiamonds made by Ion Implantation.

    Science.gov (United States)

    Chen, ChienHsu; Cho, I C; Jian, Hui-Shan; Niu, H

    2017-02-09

    Here we present a simple physical method to prepare magnetic nanodiamonds (NDs) using high dose Fe ion-implantation. The Fe atoms are embedded into NDs through Fe ion-implantation and the crystal structure of NDs are recovered by thermal annealing. The results of TEM and Raman examinations indicated the crystal structure of the Fe implanted NDs is recovered completely. The SQUID-VSM measurement shows the Fe-NDs possess room temperature ferromagnetism. That means the Fe atoms are distributed inside the NDs without affecting NDs crystal structure, so the NDs can preserve the original physical and chemical properties of the NDs. In addition, the ion-implantation-introduced magnetic property might make the NDs to become suitable for variety of medical applications.

  10. Isothermal corrosion Fe3Si alloy in liquid zinc

    Institute of Scientific and Technical Information of China (English)

    Wen jun Wang; Junping Lin; Yanli Wang; Guoliang Chen

    2007-01-01

    The isothermal corrosion testing,microscopic examination and the performance of Fe3Si alloy as materials of construction for bath hardware in continuous hot-dipping lines were studied.The corrosion of Fe3Si alloy in molten zinc was controlled by attacking the grain boundaries preferentially.Aluminum reacted with iron of Fe3Si alloy firstly while the samples were immersed in molten zinc,although aluminum contents in the molten zinc were very low.The phase of reaction product was thought to be Fe2Al5.The corrosion rate of the Fe3Si alloy in molten zinc was determined to be approximately 2.9×10-3 mm/h,therefore the liquid zinc corrosion resistance of Fe3Si alloy was very weak.

  11. Fabrication of FeSi and Fe{sub 3}Si compounds by electron beam induced mixing of [Fe/Si]{sub 2} and [Fe{sub 3}/Si]{sub 2} multilayers grown by focused electron beam induced deposition

    Energy Technology Data Exchange (ETDEWEB)

    Porrati, F.; Sachser, R.; Huth, M. [Physikalisches Institut, Goethe-Universität, Max-von-Laue-Str. 1, D-60438 Frankfurt am Main (Germany); Gazzadi, G. C. [S3 Center, Nanoscience Institute-CNR, Via Campi 213/a, 41125 Modena (Italy); Frabboni, S. [S3 Center, Nanoscience Institute-CNR, Via Campi 213/a, 41125 Modena (Italy); FIM Department, University of Modena and Reggio Emilia, Via G. Campi 213/a, 41125 Modena (Italy)

    2016-06-21

    Fe-Si binary compounds have been fabricated by focused electron beam induced deposition by the alternating use of iron pentacarbonyl, Fe(CO){sub 5}, and neopentasilane, Si{sub 5}H{sub 12} as precursor gases. The fabrication procedure consisted in preparing multilayer structures which were treated by low-energy electron irradiation and annealing to induce atomic species intermixing. In this way, we are able to fabricate FeSi and Fe{sub 3}Si binary compounds from [Fe/Si]{sub 2} and [Fe{sub 3}/Si]{sub 2} multilayers, as shown by transmission electron microscopy investigations. This fabrication procedure is useful to obtain nanostructured binary alloys from precursors which compete for adsorption sites during growth and, therefore, cannot be used simultaneously.

  12. Synthesis of BiFeO3 by carbonate precipitation

    Indian Academy of Sciences (India)

    V Kothai; Rajeev Ranjan

    2012-04-01

    Magnetoelectric multiferroic BiFeO3 (BFO) was synthesized by a simple carbonate precipitation technique of metal nitrate solutions. X-ray powder diffraction and thermo-gravimetric analysis (TGA) revealed that the precipitate consists of an intimate mixture of crystalline bismuth carbonate and an amorphous hydroxide of iron. The precipitate yielded BiFeO3 at an optimal calcination temperature of ∼560°C. Energy dispersive X-ray (EDX) analysis showed 1:1 ratio between Bi and Fe in the oxide. X-ray photoelectron spectroscopy (XPS) studies confirmed that Fe to be in +3 oxidation states both in the precipitated powder and BiFeO3. The synthesized BFO exhibits a very weak ferromagnetic correlation at room temperature and the degree of which increases slightly on cooling down to 10 K suggesting alteration in the long range spatial modulation of the spins arrangement as compared to the bulk BiFeO3.

  13. Atomic scale structure investigations of epitaxial Fe/Cr multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Kąc, M., E-mail: malgorzata.kac@ifj.edu.pl [The Henryk Niewodniczański Institute of Nuclear Physics PAN, ul. Radzikowskiego 152, 31-342 Kraków (Poland); Morgiel, J. [Institute of Metallurgy and Materials Science PAN, 25 Reymonta St., 30-059 Kraków (Poland); Polit, A.; Zabila, Y.; Marszałek, M. [The Henryk Niewodniczański Institute of Nuclear Physics PAN, ul. Radzikowskiego 152, 31-342 Kraków (Poland)

    2014-06-01

    Fe/Cr multilayers were deposited by molecular beam epitaxy on the MgO(1 0 0) substrate. Structural properties of the samples were analyzed by low energy electron diffraction, high resolution transmission electron microscopy (HRTEM), as well as by X-ray reflectivity, conversion electron Mössbauer spectroscopy (CEMS) and Auger electron spectroscopy. Investigations revealed multilayered system built of well-ordered Fe and Cr thin films with (1 0 0) orientation. A high geometrical perfection of the system, i.e. planar form of interfaces and reproducible thickness of layers, was also proven. Fe/Cr interface roughness was determined to be 2–3 atomic layers. CEMS studies allowed to analyze at atomic scale the structure of buried Fe/Cr interfaces, as well as to distinguish origin of interface roughness. Roughnesses resulting from interface corrugations and from the Fe–Cr interdiffusion at interfaces were observed. Fe/Cr multilayers showed strong antiferromagnetic coupling of Fe layers.

  14. EXAFS study of ion beam mixed Fe/Al multilayers

    CERN Document Server

    Arcon, I; Zalar, A; Kodre, A; Jagielski, J

    2003-01-01

    Composition and structure of Fe/Al multilayer coatings after ion beam mixing at different temperatures are studied. Samples were prepared by consecutive sputter deposition of Fe and Al on well-polished silicon substrate. The samples were ion beam mixed with 330 keV Ar ions at the dose of 3x10 sup 1 sup 5 ions/cm sup 2 in the temperature range between room temperature and 400 deg. C. AES depth profiles showed that mixing between Fe and Al layers started at 100 deg. C and was complete at 400 deg. C. Fe K-edge EXAFS, however, reveals that Fe bcc metallic phase is still present at all temperatures. The amount of an additional Fe-Al phase is about 20% up to 300 deg. C, increasing to 50% at 400 deg. C.

  15. Fe doped Magnetic Nanodiamonds made by Ion Implantation

    Science.gov (United States)

    Chen, Chienhsu; Cho, I. C.; Jian, Hui-Shan; Niu, H.

    2017-02-01

    Here we present a simple physical method to prepare magnetic nanodiamonds (NDs) using high dose Fe ion-implantation. The Fe atoms are embedded into NDs through Fe ion-implantation and the crystal structure of NDs are recovered by thermal annealing. The results of TEM and Raman examinations indicated the crystal structure of the Fe implanted NDs is recovered completely. The SQUID-VSM measurement shows the Fe-NDs possess room temperature ferromagnetism. That means the Fe atoms are distributed inside the NDs without affecting NDs crystal structure, so the NDs can preserve the original physical and chemical properties of the NDs. In addition, the ion-implantation-introduced magnetic property might make the NDs to become suitable for variety of medical applications.

  16. Room temperature luminescence and ferromagnetism of AlN:Fe

    Directory of Open Access Journals (Sweden)

    H. Li

    2016-06-01

    Full Text Available AlN:Fe polycrystalline powders were synthesized by a modified solid state reaction (MSSR method. Powder X-ray diffraction and transmission electron microscopy results reveal the single phase nature of the doped samples. In the doped AlN samples, Fe is in Fe2+ state. Room temperature ferromagnetic behavior is observed in AlN:Fe samples. Two photoluminescence peaks located at about 592 nm (2.09 eV and 598 nm (2.07 eV are observed in AlN:Fe samples. Our results suggest that AlN:Fe is a potential material for applications in spintronics and high power laser devices.

  17. Redox cycling of Fe(II) and Fe(III) in magnetite by Fe-metabolizing bacteria

    Energy Technology Data Exchange (ETDEWEB)

    Byrne, James; Klueglein, Nicole; Pearce, Carolyn I.; Rosso, Kevin M.; Appel, Erwin; Kappler, Andreas

    2015-03-26

    Despite the regular occurrence of both magnetite and iron-metabolizing bacteria in the same environments, it is currently unknown whether the iron(II) and iron(III) in magnetite can be cycled between different bacteria and whether or how magnetic properties are affected by this metabolic activity. We show through magnetic and spectroscopic measurements that the phototrophic Fe(II)-oxidizer Rhodopseudomonas palustris TIE-1 can oxidize solid-phase magnetite nanoparticles using light energy, leading to a decrease in the measured magnetic susceptibility (MS). This process likely occurs at the surface and is reversible in the dark by the Fe(III)-reducer Geobacter sulfurreducens resulting in an increase in MS. These results show that iron ions bound in highly crystalline mineral magnetite are bioavailable as electron stores and electron sinks under varying environmental conditions, making magnetite a potential “biogeobattery” during day/night cycles. These findings are relevant for environmental studies and reinforce the impact of microbial redox processes on the global iron cycle.

  18. PLLA- Fe3O4 nanocomposites

    Science.gov (United States)

    Albano, Carmen; Gonzalez, Gema; Naranjo, Claudio

    2012-07-01

    In the present work magnetite nanoparticules and PLLA- Fe3O4 nanocomposites were prepared by high frequency ultrasound. The influence of pH on nanoparticle size was studied, showing that the particle size decreased as the pH increased. In the composites an interaction between the magnetite nanoparticles and the PLLA matrix was observed by FTIR. Magnetic properties were studied using a VSM, and a superparamegnetic behavior was observed for magnetite nanoparticles, but for the composite a magnetic attenuation was observed due to the polymeric matrix.

  19. Standardization of (55)Fe by tracing method.

    Science.gov (United States)

    Koskinas, M F; Pires, C A; Yamazaki, I M; Silva, E A; Dias, M S

    2008-01-01

    This work describes the procedure followed by the Laboratório de Metrologia Nuclear (LMN) for the standardization of (55)Fe by the tracing method. This technique was applied using two radionuclides, which decay by the electron capture process followed by a prompt gamma-ray, namely (51)Cr and (54)Mn, as tracers. The calibration was performed in a 4pibeta-gamma coincidence system. The efficiency was obtained by selecting a gamma-ray window set at the 320keV total absorption peak for (51)Cr and at 834keV for (54)Mn.

  20. Fe doped Magnetic Nanodiamonds made by Ion Implantation

    CERN Document Server

    Chen, ChienHsu; Jian, Hui-Shan; Niu, H

    2016-01-01

    Here we present a simple physical method to produce magnetic nanodiamonds (NDs) using high dose Fe ion-implantation. The Fe atoms are distributed inside the NDs without affecting their crystal structure. So the NDs can be still functionalized through surface modification for targeted chemotherapy and the added magnetic property will make the NDs suitable for localized thermal treatment for cancer cells without the toxicity from the Fe atoms being directly in contact with the living tissue.

  1. Graphyne-supported single Fe atom catalysts for CO oxidation.

    Science.gov (United States)

    Wu, Ping; Du, Pan; Zhang, Hui; Cai, Chenxin

    2015-01-14

    Single atom catalysts (SACs) are highly desirable for the effort to maximize the efficiency of metal atom use. However, the synthesis of SACs is a major challenge that largely depends on finding an appropriate supporting substrate to achieve a well-defined and highly dispersed single atom. This work demonstrates that, based on the density functional theory (DFT) calculation, graphyne is a good substrate for single Fe atom catalysts. The Fe atom can be tightly embedded in a graphyne sheet with a high binding energy of ∼4.99 eV and a high diffusion energy barrier of ∼1.0 eV. The graphyne-supported Fe (Fe-graphyne) SAC shows high catalytic activity towards CO oxidation, which is often regarded as a prototype reaction for designing atomic-scale catalysts. We studied the adsorption characteristics of CO and O2 on Fe-graphyne SACs, and simulated the reaction mechanism of CO oxidation involving Fe-graphyne. The simulation results indicate that O2 binding on Fe-graphyne is much stronger than that of CO, and the adsorbed O2 prior to occupy the Fe atoms as the co-existence of O2 and CO. The reaction of CO oxidation by adsorbed O2 on Fe-graphyne SACs favors to proceed via the Eley-Rideal (ER) mechanism with the energy barrier of as low as ∼0.21 eV in the rate-limiting step. Calculation of the electronic density of states (DOS) of each reaction step demonstrates that the strong interaction of the O2 and Fe adatom promotes the CO oxidation on Fe-graphyne SACs. The results presented here suggest that graphyne could provide a unique platform to synthesize SACs, and the Fe-graphyne SACs could find potential use in solving the growing environmental problems caused by CO emission from automobiles and industrial processes, in removing CO contamination from vehicle exhaust and in fuel cells.

  2. Comparing Ru and Fe-catalyzed olefin metathesis.

    Science.gov (United States)

    Poater, Albert; Chaitanya Vummaleti, Sai Vikrama; Pump, Eva; Cavallo, Luigi

    2014-08-01

    Density functional theory calculations have been used to explore the potential of Fe-based complexes with an N-heterocyclic carbene ligand, as olefin metathesis catalysts. Apart from a less endothermic reaction energy profile, a small reduction in the predicted upper energy barriers (≈ 2 kcal mol(-1)) is calculated in the Fe catalyzed profile with respect to the Ru catalysed profile. Overall, this study indicates that Fe-based catalysts have the potential to be very effective olefin metathesis catalysts.

  3. Magnetotransport studies of FeSe under hydrostatic pressure

    Science.gov (United States)

    Tiwari, Brajesh; Jha, Rajveer; Awana, V. P. S.

    2014-06-01

    The discoveries of iron-based superconductors with relatively high transition temperature are under intense experimental and theoretical investigation. Here we present magnetotransport measurements on FeSe superconductor under hydrostatic pressure. We show that in Fe-deficient tetragonal FeSe binary compound, the onset of superconducting transition is almost doubled under 1.98 GPa pressure and the estimated upper critical field of 26.7 Tesla is increased to 47.5 Tesla.

  4. Coupled extremely light Ca and Fe isotopes in peridotites

    Science.gov (United States)

    Zhao, Xinmiao; Zhang, Zhaofeng; Huang, Shichun; Liu, Yufei; Li, Xin; Zhang, Hongfu

    2017-07-01

    Large metal stable isotopic variations have been observed in both extraterrestrial and terrestrial samples. For example, Ca exhibits large mass-dependent isotopic variation in terrestrial igneous rocks and mantle minerals (on the order of ∼2‰ variation in 44Ca/40Ca). A thorough assessment and understanding of such isotopic variations in peridotites provides important constraints on the evolution and compositon of the Earth's mantle. In order to better understand the Ca and Fe isotopic variations in terrestrial silicate rocks, we report Ca isotopic compositions in a set of peridotitic xenoliths from North China Craton (NCC), which have been studied for Fe isotopes. These NCC peridotites have large Ca and Fe isotopic variations, with δ44/40Ca ranging from -0.08 to 0.92 (delta value relative to SRM915a) and δ57/54Fe (delta value relative to IRMM-014) ranging from -0.61 to 0.16, and these isotopic variations are correlated with large Mg# (100 × Mg/(Mg + Fe) molar ratio) variation, ranging from 80 to 90. Importantly, NCC Fe-rich peridotites have the lowest 44Ca/40Ca and 57Fe/54Fe ratios in all terrestrial silicate rocks. In contrast, although ureilites, mantle rocks from a now broken differentiated asteroid(s), have large Mg# variation, from 70 to 92, they have very limited δ57Fe/54Fe variation (0.03-0.21, delta value relative to IRMM-014). Our model calculations show that the coupled extremely light Ca-Fe isotopic signatures in NCC Fe-rich peridotites most likely reflect kinetic isotopic fractionation during melt-peridotite reaction on a timescale of several to 104 years. In addition, our new data and compiled literature data show a possible compositional effect on the inter-mineral Ca isotopic fractionation between co-existing clinopyroxene and orthopyroxene pairs.

  5. Seasonal changes in Fe species and soluble Fe concentration in the atmosphere in the Northwest Pacific region based on the analysis of aerosols collected in Tsukuba, Japan

    Directory of Open Access Journals (Sweden)

    Y. Takahashi

    2013-08-01

    Full Text Available Atmospheric iron (Fe can be a significant source of nutrition for phytoplankton inhabiting remote oceans, which in turn has a large influence on the Earth's climate. The bioavailability of Fe in aerosols depends mainly on the fraction of soluble Fe (= [FeSol]/[FeTotal], where [FeSol] and [FeTotal] are the atmospheric concentrations of soluble and total Fe, respectively. However, the numerous factors affecting the soluble Fe fraction have not been fully understood. In this study, the Fe species, chemical composition, and soluble Fe concentrations in aerosols collected in Tsukuba, Japan were investigated over a year (nine samples from December 2002 to October 2003 to identify the factors affecting the amount of soluble Fe supplied into the ocean. The soluble Fe concentration in aerosols is correlated with those of sulfate and oxalate originated from anthropogenic sources, suggesting that soluble Fe is mainly derived from anthropogenic sources. Moreover, the soluble Fe concentration is also correlated with the enrichment factors of vanadium and nickel emitted by fossil fuel combustion. These results suggest that the degree of Fe dissolution is influenced by the magnitude of anthropogenic activity, such as fossil fuel combustion. X-ray absorption fine structure (XAFS spectroscopy was performed in order to identify the Fe species in aerosols. Fitting of XAFS spectra coupled with micro X-ray fluorescence analysis (μ-XRF showed the main Fe species in aerosols in Tsukuba to be illite, ferrihydrite, hornblende, and Fe(III sulfate. Moreover, the soluble Fe fraction in each sample measured by leaching experiments is closely correlated with the Fe(III sulfate fraction determined by the XAFS spectrum fitting, suggesting that Fe(III sulfate is the main soluble Fe in the ocean. Another possible factor that can control the amount of soluble Fe supplied into the ocean is the total Fe(III concentration in the atmosphere, which was high in spring due to the high

  6. Seasonal changes in Fe species and soluble Fe concentration in the atmosphere in the Northwest Pacific region based on the analysis of aerosols collected in Tsukuba, Japan

    Directory of Open Access Journals (Sweden)

    Y. Takahashi

    2013-03-01

    Full Text Available Atmospheric iron (Fe can be a significant source of nutrition for phytoplankton inhabiting remote oceans, which in turn has a large influence on the Earth's climate. The bioavailability of Fe in aerosols depends mainly on the fraction of soluble Fe (= [FeSol]/[FeTotal], where [FeSol] and [FeTotal] are the atmospheric concentrations of soluble and total Fe, respectively. However, the numerous factors affecting the soluble Fe fraction have not been fully understood. In this study, the Fe species, chemical composition, and soluble Fe concentrations in aerosols collected in Tsukuba, Japan were investigated over a year (nine samples from December 2002 to October 2003 to identify the factors affecting the amount of soluble Fe supplied into the ocean. The soluble Fe concentration in aerosols is correlated with those of sulfate and oxalate originated from anthropogenic sources, suggesting that soluble Fe is mainly derived from anthropogenic sources. Moreover, the soluble Fe concentration is also correlated with the enrichment factors of vanadium and nickel emitted by fossil fuel combustion. These results suggest that the degree of Fe dissolution is influenced by the magnitude of anthropogenic activity, such as fossil fuel combustion. X-ray absorption fine structure (XAFS spectroscopy was performed in this study to identify the Fe species in aerosols. The fitting of XAFS spectra coupled with micro X-ray fluorescence analysis (XRF determined the main Fe species in aerosols in Tsukuba to be illite, ferrihydrite, hornblende, and Fe(III sulfate. Moreover, the soluble Fe fraction in each sample measured by leaching experiments is closely correlated with the Fe(III sulfate fraction determined by the XAFS spectrum fitting, suggesting that Fe(III sulfate is the main soluble Fe in the ocean. Another possible factor that can control the amount of soluble Fe supplied into the ocean is the total Fe(III concentration in the atmosphere, which was high in spring due to

  7. Optimized over-expression of [FeFe] hydrogenases with high specific activity in Clostridium acetobutylicum

    Energy Technology Data Exchange (ETDEWEB)

    von Abendroth, Gregory; Stripp, Sven; Happe, Thomas [Ruhr-Universitaet Bochum, Lehrstuhl fuer Biochemie der Pflanzen, AG Photobiotechnologie, 44780 Bochum (Germany); Silakov, Alexey [Max-Planck-Institut fuer Bioanorganische Chemie, 45470 Muelheim an der Ruhr (Germany); Croux, Christian; Soucaille, Philippe; Girbal, Laurence [UMR5504, UMR792 Ingenierie des Systemes Biologiques et des Procedes, CNRS, INRA, INSA, 31400 Toulouse (France)

    2008-11-15

    It was previously shown that Clostridium acetobutylicum is capable to over-express various [FeFe] hydrogenases although the protein yield was low. In this study we report on doubling the yield of the clostridial hydrogenase by replacing the native gene hydA1{sub Ca} with a recombinant one via homologous recombination. The purified protein HydA1{sub Ca} shows an unexpected high specific activity (up to 2257 {mu}mol H{sub 2} min{sup -1} mg{sup -1}) for hydrogen evolution. Furthermore, the highly active green algal hydrogenase HydA1{sub Cr} from Chlamydomonas reinhardtii was heterologously expressed in C. acetobutylicum, and purified with increased yield (1 mg protein per liter of cells) and high activity (625 {mu}mol H{sub 2} min{sup -1} mg{sup -1}). EPR studies demonstrate intact H-clusters for homologously and heterologously expressed [FeFe] hydrogenases in the CO-inhibited oxidized redox state, and prove the high efficiency of the C. acetobutylicum expression system. (author)

  8. Biomimetic peptide-based models of [FeFe]-hydrogenases: utilization of phosphine-containing peptides.

    Science.gov (United States)

    Roy, Souvik; Nguyen, Thuy-Ai D; Gan, Lu; Jones, Anne K

    2015-09-07

    Two synthetic strategies for incorporating diiron analogues of [FeFe]-hydrogenases into short peptides via phosphine functional groups are described. First, utilizing the amine side chain of lysine as an anchor, phosphine carboxylic acids can be coupled via amide formation to resin-bound peptides. Second, artificial, phosphine-containing amino acids can be directly incorporated into peptides via solution phase peptide synthesis. The second approach is demonstrated using three amino acids each with a different phosphine substituent (diphenyl, diisopropyl, and diethyl phosphine). In total, five distinct monophosphine-substituted, diiron model complexes were prepared by reaction of the phosphine-peptides with diiron hexacarbonyl precursors, either (μ-pdt)Fe2(CO)6 or (μ-bdt)Fe2(CO)6 (pdt = propane-1,3-dithiolate, bdt = benzene-1,2-dithiolate). Formation of the complexes was confirmed by UV/Vis, FTIR and (31)P NMR spectroscopy. Electrocatalysis by these complexes is reported in the presence of acetic acid in mixed aqueous-organic solutions. Addition of water results in enhancement of the catalytic rates.

  9. Characterization of FePt nanoparticles in FePt/C multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Barradas, N.P. E-mail: nunoni@itn.mces.pt; Alves, E.; Babonneau, D

    2004-06-01

    The areal density growth of recording media is expected to reach 100 Gbit/in.{sup 2} within a few years. Such high densities require magnetic grain sizes of 10 nm or less, which is close to the superparamagnetic limit of current media. Therefore, in order to retain thermal stability, it is essential to use a magnetic material with high anisotropy energy. Ordered metallic phases such as FePt and CoPt, which have very large magnetocrystalline anisotropy, are regarded as attractive candidates. We have deposited at different temperatures by ion beam sputtering C/(FePt/C){sub x20} multilayers, with nominal thickness t{sub C}=4 nm and t{sub FePt}=1 nm. The FePt consists of nanoparticles embedded in the C matrix. Using Rutherford backscattering at grazing angles of incidence, we determined the stoichiometry of the nanoparticles, the multilayer periodicity and the nanoparticle height. We compare the results with X-ray reflectivity, grazing incidence small-angle X-ray scattering, and transmission electron microscopy results.

  10. Exponentially decaying magnetic coupling in sputtered thin film FeNi/Cu/FeCo trilayers

    Energy Technology Data Exchange (ETDEWEB)

    Wei, Yajun, E-mail: yajun.wei@angstrom.uu.se; Akansel, Serkan; Thersleff, Thomas; Brucas, Rimantas; Lansaker, Pia; Leifer, Klaus; Svedlindh, Peter [Department of Engineering Sciences, Uppsala University, 75121 Uppsala (Sweden); Harward, Ian; Celinski, Zbigniew [Department of Physics, University of Colorado, Colorado Springs, Colorado 80918 (United States); Ranjbar, Mojtaba; Dumas, Randy K. [Department of Physics, University of Gothenburg, 41296 Gothenburg (Sweden); Jana, Somnath; Pogoryelov, Yevgen; Karis, Olof [Department of Physics and Astronomy, Uppsala University, 75120 Uppsala (Sweden); Åkerman, Johan [Department of Physics, University of Gothenburg, 41296 Gothenburg (Sweden); Department of Applied Physics and Microelectronics, Royal Institute of Technology, 10044 Kista (Sweden)

    2015-01-26

    Magnetic coupling in trilayer films of FeNi/Cu/FeCo deposited on Si/SiO{sub 2} substrates have been studied. While the thicknesses of the FeNi and FeCo layers were kept constant at 100 Å, the thickness of the Cu spacer was varied from 5 to 50 Å. Both hysteresis loop and ferromagnetic resonance results indicate that all films are ferromagnetically coupled. Micromagnetic simulations well reproduce the ferromagnetic resonance mode positions measured by experiments, enabling the extraction of the coupling constants. Films with a thin Cu spacer are found to be strongly coupled, with an effective coupling constant of 3 erg/cm{sup 2} for the sample with a 5 Å Cu spacer. The strong coupling strength is qualitatively understood within the framework of a combined effect of Ruderman-Kittel-Kasuya-Yosida and pinhole coupling, which is evidenced by transmission electron microscopy analysis. The magnetic coupling constant surprisingly decreases exponentially with increasing Cu spacer thickness, without showing an oscillatory thickness dependence. This is partially connected to the substantial interfacial roughness that washes away the oscillation. The results have implications on the design of multilayers for spintronic applications.

  11. FeGa/MgO/Fe/GaAs(001) magnetic tunnel junction: Growth and magnetic properties

    Energy Technology Data Exchange (ETDEWEB)

    Gobaut, B., E-mail: benoit.gobaut@elettra.eu [Sincrotrone Trieste S.C.p.A., S.S. 14-km 163.5, Area Science Park, 34012 Trieste (Italy); Ciprian, R.; Salles, B.R.; Krizmancic, D. [Laboratorio TASC, IOM-CNR, S.S. 14-km 163.5, Basovizza, 34149 Trieste (Italy); Rossi, G. [Laboratorio TASC, IOM-CNR, S.S. 14-km 163.5, Basovizza, 34149 Trieste (Italy); Dipartimento di Fisica, Università di Milano, via Celoria 16, 20133 Milano (Italy); Panaccione, G. [Laboratorio TASC, IOM-CNR, S.S. 14-km 163.5, Basovizza, 34149 Trieste (Italy); Eddrief, M.; Marangolo, M. [Sorbonne Universites, UPMC Univ Paris 06, UMR 7588, INSP, 4 place Jussieu, 75005 Paris (France); CNRS, UMR 7588, Institut des NanoSciences de Paris, 4 place Jussieu, 75005 Paris (France); Torelli, P. [Laboratorio TASC, IOM-CNR, S.S. 14-km 163.5, Basovizza, 34149 Trieste (Italy)

    2015-06-01

    Research on spintronics and on multiferroics leads now to the possibility of combining the properties of these materials in order to develop new functional devices. Here we report the integration of a layer of magnetostrictive material into a magnetic tunnel junction. A FeGa/MgO/Fe heterostructure has been grown on a GaAs(001) substrate by molecular beam epitaxy (MBE) and studied by X-ray magnetic circular dichroism (XMCD). The comparison between magneto optical Kerr effect (MOKE) measurements and hysteresis performed in total electron yield allowed distinguishing the ferromagnetic hysteresis loop of the FeGa top layer from that of the Fe buried layer, evidencing a different switching field of the two layers. This observation indicates an absence of magnetic coupling between the two ferromagnetic layers despite the thickness of the MgO barrier of only 2.5 nm. The in-plane magnetic anisotropy has also been investigated. Overall results show the good quality of the heterostructure and the general feasibility of such a device using magnetostrictive materials in magnetic tunnel junction.

  12. Integration of an [FeFe]-hydrogenase into the anaerobic metabolism of Escherichia coli

    Science.gov (United States)

    Kelly, Ciarán L.; Pinske, Constanze; Murphy, Bonnie J.; Parkin, Alison; Armstrong, Fraser; Palmer, Tracy; Sargent, Frank

    2015-01-01

    Biohydrogen is a potentially useful product of microbial energy metabolism. One approach to engineering biohydrogen production in bacteria is the production of non-native hydrogenase activity in a host cell, for example Escherichia coli. In some microbes, hydrogenase enzymes are linked directly to central metabolism via diaphorase enzymes that utilise NAD+/NADH cofactors. In this work, it was hypothesised that heterologous production of an NAD+/NADH-linked hydrogenase could connect hydrogen production in an E. coli host directly to its central metabolism. To test this, a synthetic operon was designed and characterised encoding an apparently NADH-dependent, hydrogen-evolving [FeFe]-hydrogenase from Caldanaerobacter subterranus. The synthetic operon was stably integrated into the E. coli chromosome and shown to produce an active hydrogenase, however no H2 production was observed. Subsequently, it was found that heterologous co-production of a pyruvate::ferredoxin oxidoreductase and ferredoxin from Thermotoga maritima was found to be essential to drive H2 production by this system. This work provides genetic evidence that the Ca.subterranus [FeFe]-hydrogenase could be operating in vivo as an electron-confurcating enzyme. PMID:26839796

  13. Integration of an [FeFe]-hydrogenase into the anaerobic metabolism of Escherichia coli

    Directory of Open Access Journals (Sweden)

    Ciarán L. Kelly

    2015-12-01

    Full Text Available Biohydrogen is a potentially useful product of microbial energy metabolism. One approach to engineering biohydrogen production in bacteria is the production of non-native hydrogenase activity in a host cell, for example Escherichia coli. In some microbes, hydrogenase enzymes are linked directly to central metabolism via diaphorase enzymes that utilise NAD+/NADH cofactors. In this work, it was hypothesised that heterologous production of an NAD+/NADH-linked hydrogenase could connect hydrogen production in an E. coli host directly to its central metabolism. To test this, a synthetic operon was designed and characterised encoding an apparently NADH-dependent, hydrogen-evolving [FeFe]-hydrogenase from Caldanaerobacter subterranus. The synthetic operon was stably integrated into the E. coli chromosome and shown to produce an active hydrogenase, however no H2 production was observed. Subsequently, it was found that heterologous co-production of a pyruvate::ferredoxin oxidoreductase and ferredoxin from Thermotoga maritima was found to be essential to drive H2 production by this system. This work provides genetic evidence that the Ca.subterranus [FeFe]-hydrogenase could be operating in vivo as an electron-confurcating enzyme.

  14. Reactively sputtered Fe3O4-based films for spintronics

    Institute of Scientific and Technical Information of China (English)

    Li Peng; Jin Chao; Mi Wen-Bo; Bai Hai-Li

    2013-01-01

    Half metallic polycrystalline,epitaxial Fe3O4 films and Fe3O4-based heterostructures for spintronics were fabricated by DC reactive magnetron sputtering.Large tunneling magnetoresistance was found in the polycrystalline Fe3O4 films and attributed to the insulating grain boundaries.The pinning effect of the moments at the grain boundaries leads to a significant exchange bias.Frozen interfacial/surface moments induce weak saturation of the high-field magnetoresistance.The films show a moment rotation related butterfly-shaped magnetoresistance.It was found that in the films,natural growth defects,antiphase boundaries,and magnetocrystaltine anisotropy play important roles in high-order anisotropic magnetoresistance.Spin injection from Fe3O4 films to semiconductive Si and ZnO was measured to be 45% and 28.5%,respectively.The positive magnetoresistance in the Fe3O4-based heterostructures is considered to be caused by a shift of the Fe3O4 eg ↑ band near the interface.Enhanced magnetization was observed in Fe3O4/BiFeO3 heterostructures experimentally and further proved by first principle calculations.The enhanced magnetization can be explained by spin moments of the thin BiFeO3 layer substantially reversing into a ferromagnetic arrangement under a strong coupling that is principally induced by electronic orbital reconstruction at the interface.

  15. α-Fe/Nd2Fe14B复合纳米晶合金的X射线定量相分析%X-ray quantitative phase analysis of α-Fe/Nd2Fe14B nanocomposite crystalline alloy

    Institute of Scientific and Technical Information of China (English)

    孙宏宇; 李晓红; 张湘义

    2004-01-01

    采用联立方程组确立了α-Fe/Nd2Fe14B复合纳米晶合金中相含量的计算方法.该方法运用最小二乘回归法和抛弃平均法消除病态方程组.将其应用于α-Fe/Nd2Fe14B复合纳米晶合金的相含量计算,所得结果与直接对比法一致.

  16. Formation and Oxidation Behavior of Al-Cu-Fe Quasicrystal

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Al62.5Cu25Fe12.5 alloy was prepared by arc melting. It was found that the formation of quasicrystalline phase is related to the condition of annealing, such as temperature and duration. Weight gain of Al-Cu-Fe quasicrystal during the oxidation at 700 and 800 C in dry air was measured by means of thermal balance. The oxidation kinetics showed that the quasicrystal has good oxidation resistance. Only α-Al2O3 was formed on Al62.5Cu25Fe12.5 quasicrystal. The surface morphologies of Al-Cu-Fe quasicrystal after isothermal oxidation for different times were observed.

  17. Degradation Studies on LiFePO4 cathode

    DEFF Research Database (Denmark)

    Scipioni, Roberto; Jørgensen, Peter Stanley; Hjelm, Johan

    2015-01-01

    In this paper we examine a laboratory LiFePO4 (LFP) cathode and propose a simple model that predicts the electrode capacity as function of C-rate, number of cycles and calendar time. Microcracks were found in Li1-xFePO4 particles in a degraded LFP electrode and low-acceleration voltage (1 kV) FIB....../SEM analysis allowed us to obtain phase contrast between FePO4 and LiFePO4. The evolution of micro-cracks is expected to increase the concentration of LFP particles which are not electronically accessible and thus cause a loss in capacity....

  18. Anisotropic Morphological Changes in Goethite during Fe(2+)-Catalyzed Recrystallization.

    Science.gov (United States)

    Joshi, Prachi; Gorski, Christopher A

    2016-07-19

    When goethite is exposed to aqueous Fe(2+), rapid and extensive Fe atom exchange can occur between solid-phase Fe(3+) and aqueous Fe(2+) in a process referred to as Fe(2+)-catalyzed recrystallization. This process can lead to the structural incorporation or release of trace elements, which has important implications for contaminant remediation and nutrient biogeochemical cycling. Prior work found that the process did not cause major changes to the goethite structure or morphology. Here, we further investigated if and how goethite morphology and aggregation behavior changed temporally during Fe(2+)-catalyzed recrystallization. On the basis of existing literature, we hypothesized that Fe(2+)-catalyzed recrystallization of goethite would not result in changes to individual particle morphology or interparticle interactions. To test this, we reacted nanoparticulate goethite with aqueous Fe(2+) at pH 7.5 over 30 days and used transmission electron microscopy (TEM), cryogenic TEM, and (55)Fe as an isotope tracer to observe changes in particle dimensions, aggregation, and isotopic composition over time. Over the course of 30 days, the goethite particles substantially recrystallized, and the particle dimensions changed anisotropically, resulting in a preferential increase in the mean particle width. The temporal changes in goethite morphology could not be completely explained by a single mineral-transformation mechanism but rather indicated that multiple transformation mechanisms occurred concurrently. Collectively, these results demonstrate that the morphology of goethite nanoparticles does change during recrystallization, which is an important step toward identifying the driving force(s) of recrystallization.

  19. Crystal structure of the Fe-member of usovite

    Directory of Open Access Journals (Sweden)

    Matthias Weil

    2015-06-01

    Full Text Available Crystals of the title compound, with the idealized composition Ba2CaFeAl2F14, dibarium calcium iron(II dialuminium tetradecafluoride, were obtained serendipitously by reacting a mixture of the binary fluorides BaF2, CaF2 and AlF3 in a leaky steel reactor. The compound crystallizes in the usovite structure type (Ba2CaMgAl2F14, with Fe2+ cations replacing the Mg2+ cations. The principal building units are distorted [CaF8] square-antiprisms (point group symmetry 2, [FeF6] octahedra (point group symmetry -1 and [AlF6] octahedra that are condensed into undulating 2∞[CaFeAl2F14]4− layers parallel (100. The Ba2+ cations separate the layers and exhibit a coordination number of 12. Two crystal structure models with a different treatment of the disordered Fe site [mixed Fe/Ca occupation, model (I, versus underoccupation of Fe, model (II], are discussed, leading to different refined formulae Ba2Ca1.310 (15Fe0.690 (15Al2F14 [model (I] and Ba2CaFe0.90 (1Al2F14 [model (II].

  20. Anomalous Hall effect in Fe/Gd bilayers

    KAUST Repository

    Xu, W. J.

    2010-04-01

    Non-monotonic dependence of anomalous Hall resistivity on temperature and magnetization, including a sign change, was observed in Fe/Gd bilayers. To understand the intriguing observations, we fabricated the Fe/Gd bilayers and single layers of Fe and Gd simultaneously. The temperature and field dependences of longitudinal resistivity, Hall resistivity and magnetization in these films have also been carefully measured. The analysis of these data reveals that these intriguing features are due to the opposite signs of Hall resistivity/or spin polarization and different Curie temperatures of Fe and Gd single-layer films. Copyright (C) EPLA, 2010

  1. A new combustion route to -Fe2O3 synthesis

    Indian Academy of Sciences (India)

    A Venkataraman; Vijay A Hiremath; S K Date; S D Kulkarni

    2001-12-01

    A new combustion route for the synthesis of -Fe2O3 is reported by employing purified -Fe2O3 as aprecursor in the present investigation. This synthesis which is similar to a self propagation combustion reaction, involves fewer steps, a shorter overall processing time, is a low energy reaction without the need of any explosives, and also the reaction is completed in a single step yielding magnetic iron oxide i.e. -Fe2O3. The as synthesized -Fe2O3 is characterized employing thermal, XRD, SEM, magnetic hysteresis, and density measurements. The effect of ball-milling on magnetic properties is also presented.

  2. Electrical discharge machining studies on reactive sintered FeAl

    Indian Academy of Sciences (India)

    A K Khanra; S Patra; M M Godkhindi

    2006-06-01

    Electrical discharge machining (EDM) studies on reactive sintered FeAl were carried out with different process parameters. The metal removal rate and tool removal rate were found to increase with the applied pulse on-time. The surface roughness of machined surface also changed with the applied pulse on-time. XRD analysis of machined surface of sintered FeAl showed the formation of Fe3C phase during the EDM process. The debris analysis was used to identify the material removal mechanism occurring during the EDM of sintered FeAl.

  3. Exchange coupling across quasi-amorphous Zr-Fe spacer

    Energy Technology Data Exchange (ETDEWEB)

    Smardz, L. [Institute of Molecular Physics, Polish Academy of Sciences, M. Smoluchowskiego 17, 60-179 Poznan (Poland); Smardz, K. [Institute of Materials Sciences and Engineering, Poznan University of Technology, M. Currie 5 Sq., 60-965 Poznan (Poland); Niedoba, H. [LMOV de l' Universite de Versailles, 45, av. Des Etas - Unis, 78035 Versailles (France)

    2006-01-01

    Fe/Zr/Fe trilayers with wedge-shaped Zr interlayer were prepared using UHV (5 x 10{sup -10} mbar) DC/RF magnetron sputtering. The planar growth and interface alloying of the Fe and Zr layers was confirmed in-situ by X-ray photoelectron spectroscopy. For a Zr layer thickness (d{sub Zr}) from 1 to 3 nm we have observed patch domains characteristic for antiferromagnetic interlayer exchange coupling. Results showed that the Fe sublayers are very weakly exchange coupled or decoupled for d{sub Zr}>3 nm. (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  4. Electronic origin of structural transition in 122 Fe based superconductors

    Science.gov (United States)

    Ghosh, Haranath; Sen, Smritijit; Ghosh, Abyay

    2017-03-01

    Direct quantitative correlations between the orbital order and orthorhombicity is achieved in a number of Fe-based superconductors of 122 family. The former (orbital order) is calculated from first principles simulations using experimentally determined doping and temperature dependent structural parameters while the latter (the orthorhombicity) is taken from already established experimental studies; when normalized, both the above quantities quantitatively corresponds to each other in terms of their doping as well as temperature variations. This proves that the structural transition in Fe-based materials is electronic in nature due to orbital ordering. An universal correlations among various structural parameters and electronic structure are also obtained. Most remarkable among them is the mapping of two Fe-Fe distances in the low temperature orthorhombic phase, with the band energies Edxz, Edyz of Fe at the high symmetry points of the Brillouin zone. The fractional co-ordinate zAs of As which essentially determines anion height is inversely (directly) proportional to Fe-As bond distances (with exceptions of K doped BaFe2As2) for hole (electron) doped materials as a function of doping. On the other hand, Fe-As bond-distance is found to be inversely (directly) proportional to the density of states at the Fermi level for hole (electron) doped systems. Implications of these results to current issues of Fe based superconductivity are discussed.

  5. The mechanism of Fe (Ⅲ)-catalyzed ozonation of phenol

    Institute of Scientific and Technical Information of China (English)

    竹湘锋; 徐新华

    2004-01-01

    Fe (Ⅲ)-catalyzed ozonation yielded better degradation rate and extent of COD (Chemical Oxygen Demand) or oxalic acid as compared with oxidation by ozone alone. Two parameters with strong effects on the efficiency of ozonation are pH of the solution and the catalyst (Fe3+) dosage. The existence of a critical pH value determining the catalysis of Fe (Ⅲ) in acid conditions was observed in phenol and oxalic acid systems. The best efficiency of catalysis was obtained at a moderate concentration of the catalyst. A reasonable mechanism of Fe (Ⅲ)-catalyzed ozonation of phenol was obtained based on the results and literature.

  6. LiFePO_4/C via fluoride doping

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    Non-stoichiometric compound fluoride-doped LiFePO4/C cathode materials were synthesized via solid-state reaction using MgF2 and AlF3 as dopant. The fluoride-doped LiFePO4/C samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and electrochemical testing. The results show that the materials are well crystallized and fluoride doping cannot change the space structure of LiFePO4. Slight amounts of Fe2O3 with no fluoride impurity were ...

  7. The electronic configuration of substitutional Fe in silicon

    CERN Document Server

    Weyer, G; Fanciulli, M; Fedosseev, V; Gunnlaugsson, H P; Mishin, V I; Sielemann, R

    1999-01-01

    Ion implantations of radioactive /sup 57/Mn/sup +/ into differently doped silicon single crystals held at 300-600 K have been utilized for /sup 57/Fe Mossbauer studies of interstitial and substitutional Fe. Site and charge state assignments have been made on the basis of the determined hyperfine interaction parameters and Debye temperatures. Substantial fractions of substitutional /sup 57/Mn probe atoms are proposed to occur due to annealing reactions. This site is maintained in the subsequent decay to /sup 57/Fe by Fe atoms, the remainder is displaced by recoil effects into interstitial sites. (19 refs).

  8. Electrochemical alkaline Fe(VI) water purification and remediation.

    Science.gov (United States)

    Licht, Stuart; Yu, Xingwen

    2005-10-15

    Fe(VI) is an unusual and strongly oxidizing form of iron, which provides a potentially less hazardous water-purifying agent than chlorine. A novel on-line electrochemical Fe(VI) water purification methodology is introduced. Fe(VI) addition had been a barrier to its effective use in water remediation, because solid Fe(VI) salts require complex (costly) syntheses steps and solutions of Fe(VI) decompose. Online electrochemical Fe(VI) water purification avoids these limitations, in which Fe(VI) is directly prepared in solution from an iron anode as the FeO42- ion, and is added to the contaminant stream. Added FeO42- decomposes, by oxidizing a wide range of water contaminants including sulfides (demonstrated in this study) and other sulfur-containing compounds, cyanides (demonstrated in this study), arsenic (demonstrated in this study), ammonia and other nitrogen-containing compounds (previously demonstrated), a wide range of organics (phenol demonstrated in this study), algae, and viruses (each previously demonstrated).

  9. Synthesis and Characterization of Nanostructured Fe-Ni Alloy Whisker

    Institute of Scientific and Technical Information of China (English)

    DONG Guo-jun; WANG Gui-xiang; ZHANG Mi-lin; LI Ru-Min; WANG Jun

    2002-01-01

    The nanocrystalline γ-(Fe,Ni) alloy whiskers have been prepared by chemical reduction of Fe2+ and Ni2+ ions with potassium borohydride under the function of a dispersant agent PE followed by heat treatment at 600℃ under the protection of nitrogen.Conditions, such as quantity of NaOH, concentration of salts, and species of surfactants, of preparation of Fe-Ni alloy have been discussed. X-ray diffraction(XRD), transmission electron microscopy(TEM) and vibrating sample magnetometer(VSM) characterized the synthesized Fe-Ni alloy. Character, capability and use of the materials have been summarized.

  10. Fe/Ni ratio in the Ant Nebula Mz 3

    CERN Document Server

    Zhang, Y

    2006-01-01

    We have analyzed the [Fe II] and [Ni II] emission lines in the bipolar planetary nebula Mz~3. We find that the [Fe II] and [Ni II] lines arise exclusively from the central regions. Fluorescence excitation in the formation process of these lines is negligible for this low-excitation nebula. From the [Fe II]/[Ni II] ratio, we obtain a higher Fe/Ni abundance ratio with respect to the solar value. The current result provides further supporting evidence for Mz 3 as a symbiotic Mira.

  11. Pembuatan Bonded Anisotropi Magnet NdFeB dan Karakterisasinya

    OpenAIRE

    Nuraini, Siti

    2015-01-01

    Research on fabrications of bonded magnets NdFeB type MQA-37-16 with polivynil chloride binder has been done. The purpose of this study the effect of field strength and orientation on the physical and magnetic properties in the manufacture of bonded magnets NdFeB. Preparation process by dry mixing powder magnets NdFeB and polivynil chloride binder bi using Shaker Mill. For each sample takes 4 grams total mass of bonded magnet NdFeB. Printing is done isotropic and anisotropy using a magnetic f...

  12. Presence of magnetic excitations in SmFeAsO

    Science.gov (United States)

    Pelliciari, Jonathan; Dantz, Marcus; Huang, Yaobo; Strocov, Vladimir N.; Xing, Lingyi; Wang, Xiancheng; Jin, Changqing; Schmitt, Thorsten

    2016-09-01

    We measured dispersive spin excitations in SmFeAsO, a parent compound of SmFeAsO1 -xFx and one of the highest temperature superconductors of Fe pnictides (TC ≈ 55 K). We determine the magnetic excitations to disperse with a bandwidth energy of ca 170 meV at (0.47, 0) and (0.34, 0.34), which merges into the elastic line approaching the Γ point. Comparing our results with other parent Fe pnictides, we show the importance of structural parameters for the magnetic excitation spectrum, with small modifications of the tetrahedron angles and As height strongly affecting the magnetism.

  13. Frataxin and Mitochondrial FeS Cluster Biogenesis*

    Science.gov (United States)

    Stemmler, Timothy L.; Lesuisse, Emmanuel; Pain, Debkumar; Dancis, Andrew

    2010-01-01

    Friedreich ataxia is an inherited neurodegenerative disease caused by frataxin deficiency. Frataxin is a conserved mitochondrial protein that plays a role in FeS cluster assembly in mitochondria. FeS clusters are modular cofactors that perform essential functions throughout the cell. They are synthesized by a multistep and multisubunit mitochondrial machinery that includes the scaffold protein Isu for assembling a protein-bound FeS cluster intermediate. Frataxin interacts with Isu, iron, and the cysteine desulfurase Nfs1, which supplies sulfide, thus placing it at the center of mitochondrial FeS cluster biosynthesis. PMID:20522547

  14. Gd3Fe5O12 near the compensation temperature

    DEFF Research Database (Denmark)

    Hansen, Britt Rosendahl; Kuhn, Luise Theil; Bahl, Christian Robert Haffenden;

    2010-01-01

    Applying a magnetic eld to a magnetic material will usually cause a change in the magnetic entropy of the material. If done adiabatically, the temperature of the material will change - this is the magnetocaloric eect. Gadolinium Iron Garnet (GdIG, Gd3Fe5O12) is a complex magnetic system with three...... magnetic sublattices, one Gd and two Fe. The Fe sites are strongly coupled antiferromagnetically, i.e. the magnetic moments are anti-parallel, while the Gd magnetic moment is weakly coupled antiferromagnetically to the resulting Fe moment. This results in a compensation temperature, where the total...

  15. Core-Shell Nanostructure of α-Fe2O3/Fe3O4: Synthesis and Photocatalysis for Methyl Orange

    Directory of Open Access Journals (Sweden)

    Yang Tian

    2011-01-01

    Full Text Available Fe3O4 nanoparticle was synthesized in the solution involving water and ethanol. Then, α-Fe2O3 shell was produced in situ on the surface of the Fe3O4 nanoparticle by surface oxidation in molten salts, forming α-Fe2O3/Fe3O4 core-shell nanostructure. It was showed that the magnetic properties transformed from ferromagnetism to superparamagnetism after the primary Fe3O4 nanoparticles were oxidized. Furthermore, the obtained α-Fe2O3/Fe3O4 core-shell nanoparticles were used to photocatalyse solution of methyl orange, and the results revealed that α-Fe2O3/Fe3O4 nanoparticles were more efficient than the self-prepared α-Fe2O3 nanoparticles. At the same time, the photocatalyzer was recyclable by applying an appropriate magnetic field.

  16. Dependence of coercivity on phase distribution and grain size in nanocomposite Nd2Fe14B/α-Fe magnets

    Institute of Scientific and Technical Information of China (English)

    Feng Wei-Cun; Gao Ru-Wei; Li Wei; Han Guang-Bing; Sun Yan

    2005-01-01

    The dependence of coercivity on the grain size in nanocomposite Nd2Fe14B/α-Fe magnets with different distributions of magnetically soft and hard phases is investigated by means of statistical mean. The calculations show that when there exists no soft phase, the coercivity of magnets decreases monotonically with hard grain size reducing. For a given volume fraction of hard phase, the coercivity of nanocomposite Nd2Fe14B/α-Fe magnets with a random distribution of soft and hard grains shows a peak value as a function of hard grain size. When the hard grain size is larger than an optimum value of soft grain size (15nm), the nanocomposite Nd2Fe14B/α-Fe magnets with the multilayer structure of soft and hard grains can possess a higher coercivity than that with the random distribution of soft and hard grains.

  17. Structure and magnetocaloric effect in melt-spun La(Fe,Si)13 and MnFePGe compounds

    Institute of Scientific and Technical Information of China (English)

    YAN Aru

    2006-01-01

    The magnetocaloric properties of melt-spun La(Fe,Si) 13 and MnFePGe compounds were investigated. Very large value of magnetic entropy change |ΔS|=31 and 35.4J·(kg·K)-1 under 5 T were obtained at 201 K in LaFe11.8Si1.2 melt-spun ribbons and at around 317 K in Mn1.1Fe0.9P0.76Ge0.24 melt-spun ribbons, respectively. The large magnetocaloric effect results from a more homogenous element distribution related to the very high cooling rate during melt-spinning. The excellent MCE properties, the low materials cost and the accelerated aging regime make the melt-spun-type La(Fe,Si)13 and MnFePGe materials an excellent candidate for magnetic refrigerant applications.

  18. Selection of Chelated Fe (III)/Fe (II) Catalytic Oxidation Agents for Desulfurization Based on Iron Complexation Method

    Institute of Scientific and Technical Information of China (English)

    Luo Ying; Liu Youzhi; Qi Guisheng; Guo Huidong; Zhu Zhengfeng

    2014-01-01

    Optimization of factors inlfuencing the experiments on reactions involving 8 different chelating agents and sol-uble Fe (III)/Fe (II) salts was carried out to yield chelated iron complexes. A combination of optimized inlfuencing factors has resulted in a Fe chelating capacity of the iron-based desulfurization solution to be equal to 6.83-13.56 g/L at a redox potential of 0.185-0.3. The desulfurization performance of Fe (III)/Fe (II) chelating agents was investigated on a simulated sulfur-containing industrial gas composed of H2S and N2 in a cross-lfow rotating packed bed. Test results have revealed that the proposed iron-based desulfurization solution showed a sulfur removal efifciency of over 99%along with a Fe chelating capacity exceeding 1.35 g/L. This desulfurization technology which has practical application prospect is currently in the phase of commercial scale-up study.

  19. Uptake and Release of Cerium During Fe-Oxide Formation and Transformation in Fe(II) Solutions

    DEFF Research Database (Denmark)

    Nedel, Sorin; Dideriksen, Knud; Christiansen, Bo C.

    2010-01-01

    microscopy revealed that it formed discrete nanocrystals of CeO2(s). These results demonstrate that Fe-oxide interaction with radionuclides is likely to depend strongly on the local redox conditions. By analogy with Ce, the trivalent actinides are not expected to be sequestered by preformed GR in anoxic......Fe-oxides are ubiquitous in soils and sediments and form during Fe(0) corrosion. Depending on redox conditions and solution composition, Fe-oxides such as ferrihydrite, goethite, magnetite, and green rust (GR) may form. These phases typically have high surface area and large affinity for adsorption...... of trace components. Further, Fe(II)-Fe(III) (hydr)oxides are redox active. Cerium, a member of the lanthanide family, can be used as an analogue for the tri- and tetra-valent actinides found in radioactive waste, expected to be stored in subsurface repositories. In experiments with ferrihydrite, Ce...

  20. A sensitive nonenzymatic hydrogen peroxide sensor based on Fe3O4–Fe2O3 nanocomposites

    Indian Academy of Sciences (India)

    Guang Sheng Cao; Peilong Wang; Xin Li; Yue Wang; Guilong Wang; Junping Li

    2015-02-01

    The Fe3O4–Fe2O3 nanocomposites were prepared by the co-precipitation method and followed by calcination process. The products were synthesized and characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and energy-dispersive X-ray analysis. The obtained Fe3O4–Fe2O3 nanocomposites were then applied to study the electrocatalytic reduction of hydrogen peroxide (H2O2) in 0.01 M pH 7.0 phosphate buffer medium. Then the Fe3O4–Fe2O3 nanocomposites were used as active electrode material of electrochemical sensors for H2O2 detection The detection sensitivity of the sensor was 20.325 A mM-1, and the detection limit was estimated to be about 0.2 mM.

  1. Effect of FeGa{sub 3} powder addition on the magnetic properties of NdFeB sintered magnets

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, T.S.; Kim, Y.B.; Jeung, W.Y.

    1999-09-01

    NdFeB sintered magnets with the addition of various amounts of FeGa{sub 3} powder were prepared by blending during the ball milling process. The magnetic properties and microstructure of the NdFeB magnets were studied. It was found that the addition of 0.1--0.2 wt.% FeGa{sub 3} powder increases the coercivity of the magnets without reducing the remanence. The improvement in coercivity by the addition of FeGa{sub 3} powder may be related to the formation of a Nd{sub 6}Fe{sub 14{minus}x}Ga{sub x} (x {approx{underscore}equal} 1) intergranular phase in the magnets.

  2. The SPASIBA Force Field for Studying Iron-Tannins Interactions : Application to Fe3+ /Fe2+ Catechol Complexe

    Directory of Open Access Journals (Sweden)

    G. Vergoten

    2007-03-01

    Full Text Available The SPASIBA force field parameters have been obtained for Fe3+ /Fe2+ -Oxygeninteractions occuring between non-heminic iron and hydroxyl groups of polyphenols foundin tannins. These parameters were derived from normal modes analyses based on quantumchemical calculations using the Density Functional Theory (DFT. Four models involvingcomplexation of iron with water ([Fe(H2O6]3+ , [Fe(H2O6]2+ and with cathechol molecules([Fe(cat2(H2O2]-1, [Fe(cat2(H2O2]-2 were studied using the Density Functional Theoryand the B3LYP hybrid functional under high spin states of iron.

  3. Coupling Hollow Fe3O4-Fe Nanoparticles with Graphene Sheets for High-Performance Electromagnetic Wave Absorbing Material.

    Science.gov (United States)

    Qu, Bin; Zhu, Chunling; Li, Chunyan; Zhang, Xitian; Chen, Yujin

    2016-02-17

    We developed a strategy for coupling hollow Fe3O4-Fe nanoparticles with graphene sheets for high-performance electromagnetic wave absorbing material. The hollow Fe3O4-Fe nanoparticles with average diameter and shell thickness of 20 and 8 nm, respectively, were uniformly anchored on the graphene sheets without obvious aggregation. The minimal reflection loss RL values of the composite could reach -30 dB at the absorber thickness ranging from 2.0 to 5.0 mm, greatly superior to the solid Fe3O4-Fe/G composite and most magnetic EM wave absorbing materials recently reported. Moreover, the addition amount of the composite into paraffin matrix was only 18 wt %.

  4. The Influence of FeO on the Reaction between Fe-Al-Ca Alloy and Al2O3-CaO-FeO Oxide during Heat Treatment at 1473 K

    National Research Council Canada - National Science Library

    Chengsong Liu; Shufeng Yang; Jingshe Li; Hongwei Ni; Xueliang Zhang

    2017-01-01

    .... To clarify the influence of FeO on the solid-state reactions between Al2O3-CaO-FeO oxide and Fe-Al-Ca alloy during heat treatment at 1473 K, three diffusion couples with different FeO concentrations...

  5. [FeFe]-hydrogenase maturation: insights into the role HydE plays in dithiomethylamine biosynthesis.

    Science.gov (United States)

    Betz, Jeremiah N; Boswell, Nicholas W; Fugate, Corey J; Holliday, Gemma L; Akiva, Eyal; Scott, Anna G; Babbitt, Patricia C; Peters, John W; Shepard, Eric M; Broderick, Joan B

    2015-03-10

    HydE and HydG are radical S-adenosyl-l-methionine enzymes required for the maturation of [FeFe]-hydrogenase (HydA) and produce the nonprotein organic ligands characteristic of its unique catalytic cluster. The catalytic cluster of HydA (the H-cluster) is a typical [4Fe-4S] cubane bridged to a 2Fe-subcluster that contains two carbon monoxides, three cyanides, and a bridging dithiomethylamine as ligands. While recent studies have shed light on the nature of diatomic ligand biosynthesis by HydG, little information exists on the function of HydE. Herein, we present biochemical, spectroscopic, bioinformatic, and molecular modeling data that together map the active site and provide significant insight into the role of HydE in H-cluster biosynthesis. Electron paramagnetic resonance and UV-visible spectroscopic studies demonstrate that reconstituted HydE binds two [4Fe-4S] clusters and copurifies with S-adenosyl-l-methionine. Incorporation of deuterium from D2O into 5'-deoxyadenosine, the cleavage product of S-adenosyl-l-methionine, coupled with molecular docking experiments suggests that the HydE substrate contains a thiol functional group. This information, along with HydE sequence similarity and genome context networks, has allowed us to redefine the presumed mechanism for HydE away from BioB-like sulfur insertion chemistry; these data collectively suggest that the source of the sulfur atoms in the dithiomethylamine bridge of the H-cluster is likely derived from HydE's thiol containing substrate.

  6. Interface characterization of epitaxial Fe/MgO/Fe magnetic tunnel junctions.

    Science.gov (United States)

    Wang, S G; Ward, R C C; Hesjedal, T; Zhang, X G; Wang, C; Kohn, A; Ma, Q L; Zhang, Jia; Liu, H F; Han, X F

    2012-02-01

    Following predictions by first-principles theory of a huge tunnel magnetoresistance (TMR) effect in epitaxial Fe/MgO/Fe magnetic tunnel junctions (MTJs), measured magnetoresistance (MR) ratios of about 200% at room temperature (RT) have been reported in MgO-based epitaxial MTJs. Recently, a MR ratio of about 600% has been reported at RT in MgO-based MTJs prepared by magnetron sputtering, using amorphous CoFeB as the ferromagnetic electrode. These MTJs show great potential for application in spintronic devices. Fully epitaxial MTJs are excellent model systems that enhance our understanding of the spin-dependent tunneling process as the interface is well defined and can be fully characterized. Both theoretical calculations and experimental results clearly indicate that the interfacial structure plays a crucial role in the coherent tunneling across a single crystal MgO barrier, especially in epitaxial MgO-based MTJs grown by molecular beam epitaxy (MBE). Surface X-ray diffraction, Auger electron spectroscopy, X-ray absorption spectra, and X-ray magnetic circular dichroism techniques have been reported previously for interface characterization. However, no consistent viewpoint has been reached on the interfacial structures (such as FeO layer formation at the bottom Fe/MgO interface), and it is still an open issue. In this article, our recent studies on the interface characterization of MgO-based epitaxial MTJs by X-ray photoelectron spectroscopy, high resolution transmission electron microscopy, and spin-dependent tunneling spectroscopy, will be presented.

  7. Geometrically frustrated Fe2P-like systems: beyond the Fe-trimer approximation

    Science.gov (United States)

    Florez, J. M.; Negrete, O. A.; Vargas, P.; Ross, C. A.

    2015-07-01

    Fe2 P-like structures can be strongly frustrated magnets due to their Kagome/triangular intercalated-layer structure. A complete magnetic solution of the complex spin architecture, and hence the full potential of the magnetic phenomena in Fe2 P-like material prototypes, is yet to be found. A previous magnetic model for a representative FeCrAs-like system used a mean-field effective-spin to describe the 3g-Wyckoff located Fe-triangles. Such an approach demonstrated the outstanding magnetocaloric properties of the material but left the question of whether the intra-trimer interaction could lead to new physical phenomena and therefore more potentially useful properties. In this work Monte Carlo simulations are employed in order to understand both the influence of the additional degrees of freedom introduced by the Fe-trimers and the changes caused by all the possible exchange couplings between them. Complex scenarios arise, in which FM coupling in the trimers gives rise to both in-plane and out-of-plane inter-layer AFM states; whereas AFM exchange in the trimers gives rise to three distinct states, i.e. AFM-canted layers, a non-collinear superposition of ferromagnetic Kagome/triangular orderings, and tilted inter-planar AFM order. These last three configurations generate a double bifurcated magnetic phase diagram while the first one mimics the behavior seen in a model that treats the trimer as an effective-spin under an applied magnetic field.

  8. Optimized Expression and Purification for High-Activity Preparations of Algal [FeFe]-Hydrogenase

    Energy Technology Data Exchange (ETDEWEB)

    Yacoby, I.; Tegler, L. T.; Pochekailov, S.; Zhang, S.; King, P. W.

    2012-04-01

    Recombinant expression and purification of metallo-enzymes, including hydrogenases, at high-yields is challenging due to complex, and enzyme specific, post-translational maturation processes. Low fidelities of maturation result in preparations containing a significant fraction of inactive, apo-protein that are not suitable for biophysical or crystallographic studies. We describe the construction, overexpression and high-yield purification of a fusion protein consisting of the algal [2Fe2S]-ferredoxin PetF (Fd) and [FeFe]-hydrogenase HydA1. The maturation of Fd-HydA1 was optimized through improvements in culture conditions and media components used for expression. We also demonstrated that fusion of Fd to the N-terminus of HydA1, in comparison to the C-terminus, led to increased expression levels that were 4-fold higher. Together, these improvements led to enhanced HydA1 activity and improved yield after purification. The strong binding-affinity of Fd for DEAE allowed for two-step purification by ion exchange and StrepTactin affinity chromatography. In addition, the incorporation of a TEV protease site in the Fd-HydA1 linker allowed for the proteolytic removal of Fd after DEAE step, and purification of HydA1 alone by StrepTactin. In combination, this process resulted in HydA1 purification yields of 5 mg L{sup -1} of culture from E. coli with specific activities of 1000 U (U = 1 {micro}mol hydrogen evolved mg{sup -1} min{sup -1}). The [FeFe]-hydrogenases are highly efficient enzymes and their catalytic sites provide model structures for synthetic efforts to develop robust hydrogen activation catalysts. In order to characterize their structure-function properties in greater detail, and to use hydrogenases for biotechnological applications, reliable methods for rapid, high-yield expression and purification are required.

  9. Fe@Fe2O3 promoted electrochemical mineralization of atrazine via a triazinon ring opening mechanism.

    Science.gov (United States)

    Ding, Xing; Wang, Shengyao; Shen, Wanqiu; Mu, Yi; Wang, Li; Chen, Hao; Zhang, Lizhi

    2017-04-01

    In this study, an electrochemical/electro-Fenton oxidation (EC/EF) system was designed to degrade atrazine, by utilizing boron-doped diamond (BDD) and Fe@Fe2O3 core-shell nanowires loaded active carbon fiber (Fe@Fe2O3/ACF) as the anode and the cathode, respectively. This EC/EF system exhibited much higher degradation rate, decholorination and mineralization efficiency of atrazine than the electrochemical (EC) and electrochemical/traditional electro-Fenton (EC/TEF) oxidation counterpart systems without Fe@Fe2O3 core-shell nanowires. Active species trapping experiment revealed that Fe@Fe2O3 could activate molecular oxygen to produce more OH through Fenton reaction, which favored the atrazine degradation. High performance liquid chromatography, high performance liquid chromatography-mass spectrometry and gas chromatography-mass spectrometry were applied to probe the decomposition and mineralization of atrazine during this novel EC/EF process, which revealed that two intermediates of triazinons (the isomerization of hydroxylated atrazine) were generated during the electrochemical/electro-Fenton oxidation of atrazine in the presence of Fe@Fe2O3 core-shell nanowires. The experimental and theoretical calculation results suggested that atrazine might be degraded via a triazinon ring opening mechanism, while the presence of Fe@Fe2O3 notably accelerated the decholorination process, and produced more hydroxylated products to promote the generation of trazinons and the subsequent ring cleavage as well as the final complete mineralization. This work provides a deep insight into the triazine ring opening mechanism and the design of efficient electrochemical advanced oxidation technologies (EAOTs) for persistent organic pollutant removal. Copyright © 2017 Elsevier Ltd. All rights reserved.

  10. Spectroelectrochemical characterization of the active site of the [FeFe] hydrogenase HydA1 from Chlamydomonas reinhardtii.

    Science.gov (United States)

    Silakov, Alexey; Kamp, Christina; Reijerse, Eduard; Happe, Thomas; Lubitz, Wolfgang

    2009-08-25

    Hydrogenases catalyze the reversible oxidation of molecular hydrogen. The active site of the [FeFe] hydrogenases (H-cluster) contains a catalytically active binuclear subcluster ([2Fe](H)) connected to a "cubane" [4Fe4S](H) subcluster. Here we present an IR spectroelectrochemical study of the [FeFe] hydrogenase HydA1 isolated from the green alga Chlamydomonas reinhardtii. The enzyme shows IR bands similar to those observed for bacterial [FeFe] hydrogenases. They are assigned to the stretching vibrations of the CN(-) and CO ligands on both irons of the [2Fe](H) subcluster. By following changes in frequencies of the IR bands during electrochemical titrations, two one-electron redox processes of the active enzyme could be distinguished. The reduction of the oxidized state (H(ox)) occurred at a midpoint potential of -400 mV vs NHE (H(ox)/H(red) transition) and relates to a change of the formal oxidation state of the binuclear subcluster. A subsequent reduction (H(red)/H(sred) transition) was determined to have a midpoint potential of -460 mV vs NHE. On the basis of the IR spectra, it is suggested that the oxidation state of the binuclear subcluster does not change in this transition. Tentatively, a reduction of the [4Fe4S](H) cluster has been proposed. In contrast to the bacterial [FeFe] hydrogenases, where the bridging CO ligand becomes terminal when going from H(ox) to H(red), in HydA1 the bridging CO is present in both the H(ox) and H(red) state. The removal of the bridging CO moiety has been observed in the H(red) to H(sred) transition. The significance of this result for the hydrogen conversion mechanism of this class of enzymes is discussed.

  11. Dissolved Fe and Fe binding ligand concentrations at the hydrothermal vent fields in the Coriolis Troughs, New Hebrides Island Arc

    Science.gov (United States)

    Kleint, C.; Hawkes, J. A.; Sander, S. G.; Koschinsky, A.

    2016-02-01

    It is globally accepted that hydrothermal vent fluids are highly enriched in Fe compared to the surrounding seawater and for long it was believed that the majority of the dissolved Fe is precipitated either directly out of the fluid with seawater contact or from the plume within a short distance. Recent research at other deep-sea hydrothermal vents has shown, however, that organic ligands are able to keep Fe soluble and therefore facilitating its transport into the open ocean. This is important since Fe is also considered a limiting factor for primary production in large parts of the world`s surface ocean. The New Hebrides Island Arc is not studied well with respect to the fluid chemistry of its numerous vents. Up until now, no data is published for the crucial micronutrient Fe in these fluids. Several hydrothermal vent fluids, divided into mixing zone, outlet and pure fluid as well as one hydrothermal plume from the Coriolis Troughs have been analyzed with respect to total dissolved Fe (dFe) and Fe binding ligands (FeL), using competitive ligand exchange - adsorptive cathodic stripping voltammetry (CLE - AdCSV) with Salicylaldoxime as the artificial ligand. Our dFe data for the hydrothermal plume show concentrations ranging from 9.6 nM to 30.1 nM, being highly enriched compared to the surrounding seawater. Good correlation is observed between dFe and turbidity, which can be used as a proxy for hydrothermal plumes. Hydrothermal fluid samples collected near and directly from the vent outlet show total dissolved Fe concentrations varying from 0.46 µM up to 380 µM, respectively. We find enriched organic ligand concentrations in the plume samples as well as in the samples taken near the hydrothermal vent outlets. Pure hydrothermal fluid samples with an in-situ temperature of up to 370 °C show different ligand properties than low to mid temperature samples.

  12. On synthesis of BaFe12O19, SrFe12O19, and PbFe12O19 hexagonal ferrite ceramics with multiferroid properties

    Science.gov (United States)

    Kostishin, V. G.; Panina, L. V.; Kozhitov, L. V.; Timofeev, A. V.; Zyuzin, A. K.; Kovalev, A. N.

    2015-08-01

    We analyze the possibility of obtaining M-type hexagonal ferrites of barium, strontium, and lead with multiferroid properties with the help of ceramic technology. Using the modified ceramic technology (especially pure initial raw materials, admixture of B2O3, and sintering in the oxygen atmosphere), we obtained for the first time the BaFe12O19 and SrFe12O19 samples with intense multiferroid properties at room temperature. At the same time, the employed technology does not make it possible to obtain PbFe12O19 samples exhibiting ferroelectricity. The multiferroid characteristics of experimental samples are compared with the characteristics of classical high-temperature multiferroic BiFeO3 and with the characteristics of BaFe12O19, SrFe12O19, and PbFe12O19 ferrite ceramics obtained in accordance with polymer precursor technology. We propose a mechanism explaining multiferroid properties of the hexagonal ferrite ceramic samples and note the importance of our results for applications.

  13. Desalination of Water Using ZVI (Fe0

    Directory of Open Access Journals (Sweden)

    David D. J. Antia

    2015-07-01

    Full Text Available Batch treatment of water (0.2 to 240 L using Fe0 (44,000–77,000 nm in a diffusion environment operated (at −8 to 25 °C using: (a no external energy; (b pressurized (<0.1 MPa air; (c pressurized (<0.1 MPa acidic gas (CO2; (d pressurized (<0.1 MPa anoxic gas (N2; (e pressurized (<0.1 MPa anoxic, acidic, reducing gas (H2 + CO + CO2 + CH4 + N2, reduces the salinity of water. Desalination costs increase with increasing NaCl removal. The cost of reducing water salinity from: (i 2.65 to 1.55 g·L−1 (over 1–24 h is $0.002–$0.026 m−3; (ii 38.6 to 0.55 g·L−1 (over 210 days is $67.6–$187.2 m−3. Desalination is accompanied by the removal, from the water, of one or more of: nitrate, chloride, fluoride, sulphate, phosphate, As, B, Ba, Ca, Cd, Co, Cu, Fe, Mg, Mn, Na, Ni, P, S, Si, Sr, Zn. The rate of desalination is enhanced by increasing temperatures and increasing HCO3−/CO32− concentrations. The rate of desalination decreases with increasing SO42− removal under acidic, or pH neutral, operating conditions.

  14. A Fe K Line in GRB 970508

    Science.gov (United States)

    Protassov, R.; van Dyk, D.; Connors, A.; Kashyap, V.; Siemiginowska, A.

    2000-12-01

    We examine the x-ray spectrum of the afterglow of GRB 970508, analyzed for Fe line emission by Piro et al (1999, ApJL, 514, L73). This is a difficult and extremely important measurement: the detection of x-ray afterglows from γ -ray bursts is at best a tricky business, relying on near-real satellite time response to unpredictable events; and a great deal of luck in catching a burst bright enough for a useful spectral analysis. Detecting a clear atomic (or cyclotron) line in the generally smooth and featureless afterglow (or burst) emission not only gives one of the few very specific keys to the physics local to the emission region, but also provides clues or confirmation of its distance (via redshift). Unfortunately, neither the likelihood ratio test or the related F-statistic commonly used to detect spectral lines adhere to their nominal Chi square and F-distributions. Thus we begin by calibrating the F-statistic used in Piro et al (1999, ApJL, 514, L73) via a simulation study. The simulation study relies on a completely specified source model, i.e. we do Monte Carlo simulations with all model parameters fixed (so--called ``parametric bootstrapping''). Second, we employ the method of posterior predictive p-values to calibrate a LRT statistic while accounting for the uncertainty in the parameters of the source model. Our analysis reveals evidence for the Fe K line.

  15. Dissimilatory Fe(III) and Mn(IV) reduction.

    Science.gov (United States)

    Lovley, Derek R; Holmes, Dawn E; Nevin, Kelly P

    2004-01-01

    Dissimilatory Fe(III) and Mn(IV) reduction has an important influence on the geochemistry of modern environments, and Fe(III)-reducing microorganisms, most notably those in the Geobacteraceae family, can play an important role in the bioremediation of subsurface environments contaminated with organic or metal contaminants. Microorganisms with the capacity to conserve energy from Fe(III) and Mn(IV) reduction are phylogenetically dispersed throughout the Bacteria and Archaea. The ability to oxidize hydrogen with the reduction of Fe(III) is a highly conserved characteristic of hyperthermophilic microorganisms and one Fe(III)-reducing Archaea grows at the highest temperature yet recorded for any organism. Fe(III)- and Mn(IV)-reducing microorganisms have the ability to oxidize a wide variety of organic compounds, often completely to carbon dioxide. Typical alternative electron acceptors for Fe(III) reducers include oxygen, nitrate, U(VI) and electrodes. Unlike other commonly considered electron acceptors, Fe(III) and Mn(IV) oxides, the most prevalent form of Fe(III) and Mn(IV) in most environments, are insoluble. Thus, Fe(III)- and Mn(IV)-reducing microorganisms face the dilemma of how to transfer electrons derived from central metabolism onto an insoluble, extracellular electron acceptor. Although microbiological and geochemical evidence suggests that Fe(III) reduction may have been the first form of microbial respiration, the capacity for Fe(III) reduction appears to have evolved several times as phylogenetically distinct Fe(III) reducers have different mechanisms for Fe(III) reduction. Geobacter species, which are representative of the family of Fe(III) reducers that predominate in a wide diversity of sedimentary environments, require direct contact with Fe(III) oxides in order to reduce them. In contrast, Shewanella and Geothrix species produce chelators that solubilize Fe(III) and release electron-shuttling compounds that transfer electrons from the cell surface to

  16. Effect of titanium addition on the magnetic property of Nd2Fe14B/α-Fe nanocomposite alloys

    Institute of Scientific and Technical Information of China (English)

    ZHANG

    2010-01-01

    Rapidly solidified nanocrystalline α-Fe/Nd2Fe14B alloys with enhanced coercivity were obtained by melt spinning.The effects of Ti addition on the microstructore and magnetic properties of the nanocomposite α-Fe/Nd2Fe14B alloys were investigated by X-ray diffraction(XRD)and superconducting quantum interference device(SQUID)magnetometer.The analysis of XRD showed that Vα-Fe estimated to be about 35.3% in the Ti-free α-Fe/Nd2Fe14B nanocomposites decreased down to 26.5% as the addition of was 5 at.% Ti.Accordingly,adding Ti resulted in relevant improvements of magnetic properties,especially of the coercivity Hc from 595 kA/m up to 1006 kA/m.The dependence of Mirrev(H)/2Mr on the reverse field H indicated that nucleation was the dominating mechanism for the magnetization reversal in these nanocomposites.The analysis of the temperature dependence of the demagnetization curve in the α-Fe/Nd2Fe14B nanocomposite magnets indicated that a reduction of αex could play a leading role in an increase in the coercivity of Ti-doped sample.

  17. Synergetic crystallization in a Nd2Fe14B/α-Fe nanocomposite under electron beam exposure conditions.

    Science.gov (United States)

    Tian, Haidong; Zhang, Yinfeng; Han, Jingzhi; Xu, Zhuang; Zhang, Xiaodong; Liu, Shunquan; Wang, Changsheng; Yang, Yingchang; Han, Li; Yang, Jinbo

    2016-10-27

    Nd2Fe14B/α-Fe nanocomposite magnets are prepared through electron beam exposure with a greatly reduced annealing time of 0.1 s. This is by far the most effective approach due to the effect of an extremely high heating rate featuring a rapid thermal process. The impact that the rapid thermal process has on crystallization is expounded by the introduction of the Landau model and Langevin dynamical simulations. The change of crystallization sequence from the α-Fe phase preceding the Nd2Fe14B phase under conventional annealing conditions, to synergetic crystallization under electron beam conditions is investigated. Synergetic crystallization results in more intense interaction between the α-Fe phase and the Nd2Fe14B phase in order to refine the microstructure as the fraction of Fe increases within our addition range. Improved uniformity, and shifts in the microstructure and distribution of the α-Fe phase contribute to the improvement of the magnetic properties. Compared with conventional furnace annealing ones, the magnetic properties of samples under electron beam exposure conditions are improved. For the Nd10Fe83.3B6.2Nb0.2Ga0.3 alloy, coercivity is enhanced from 4.56 kOe to 6.73 kOe, remanence ratio increases from 0.75 to 0.79, and a superior squareness of the hysteresis loop is achieved.

  18. Formation of hard magnetic L1{sub 0}-FePt/FePd monolayers from elemental multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Goo, Nam Hoon

    2007-06-18

    In this thesis, ordered L1{sub 0}-FePt and FePd films of different nominal compositions are prepared from Fe/Pt and Fe/Pd multilayers by annealing. In case of the L1{sub 0}-FePt films the composition of the films is modified by changing the individual elemental layer thicknesses in the multilayer precursors. This simple variation of the composition is the great advantage of the multilayer approach compared to sputtering single alloy layer from an alloy target. The formation mechanism of the fct phase from the multilayers and the microstructural properties are investigated. The characteristics of the hysteresis loop (coercivity {mu}{sub 0}H{sub c}, remanence J{sub r}) and of the intrinsic magnetic properties (anisotropy constant K{sub l}, spontaneous polarization J{sub s}, exchange constant A) of the ordered L1{sub 0}-FePt and FePd films are studied. The effects of the composition of the L1{sub 0}-FePt films on the microstructural and magnetic properties are investigated. The microstructure of these ordered L1{sub 0}-FePt films are then correlated to the magnetic properties with microstructural parameters by investigating the temperature dependence of the coercivity. (orig.)

  19. Spin and orbital magnetic moments of Fe in the n-type ferromagnetic semiconductor (In,Fe)As

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, M., E-mail: masakik@post.kek.jp; Oshima, M. [Department of Applied Chemistry, School of Engineering, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan); Synchrotron Radiation Research Organization, University of Tokyo, 1-490-2 Kouto, Sayo-cho, Tatsuno, Hyogo 679-5165 (Japan); Anh, L. D.; Hai, P. N.; Tanaka, M. [Department of Electrical Engineering and Information Systems, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan); Takeda, Y.; Okane, T.; Saitoh, Y.; Yamagami, H. [Synchrotron Radiation Research Unit, Japan Atomic Energy Agency, Sayo-gun, Hyogo 679-5148 (Japan); Sakamoto, S.; Kadono, T.; Fujimori, A. [Department of Physics, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan); Harada, Y. [Synchrotron Radiation Research Organization, University of Tokyo, 1-490-2 Kouto, Sayo-cho, Tatsuno, Hyogo 679-5165 (Japan); Institute for Solid State Physics, The University of Tokyo, 1-1-1 Koto, Sayo, Hyogo 679-5198 (Japan)

    2014-07-21

    The electronic and magnetic properties of Fe atoms in the ferromagnetic semiconductor (In,Fe)As codoped with Be have been studied by x-ray absorption spectroscopy (XAS) and x-ray magnetic circular dichroism (XMCD) at the Fe L{sub 2,3} edge. The XAS and XMCD spectra showed simple spectral line shapes similar to Fe metal, but the ratio of the orbital and spin magnetic moments (M{sub orb}/M{sub spin}) estimated using the XMCD sum rules was significantly larger than that of Fe metal, indicating a significant orbital moment of Fe 3d electrons in (In,Fe)As:Be. The positive value of M{sub orb}/M{sub spin} implies that the Fe 3d shell is more than half-filled, which arises from the hybridization of the Fe{sup 3+} (d{sup 5}) state with the charge-transfer d{sup 6}L{sub ¯} states, where L{sub ¯} is a ligand hole in the host valence band. The XMCD intensity as a function of magnetic field indicated hysteretic behavior of the superparamagnetic-like component due to discrete ferromagnetic domains.

  20. Moessbauer analysis and magnetic properties of Invar Fe-Ni-C and Fe-Ni-Mn-C alloys

    Energy Technology Data Exchange (ETDEWEB)

    Nadutov, V. M., E-mail: nadvl@imp.kiev.ua; Svystunov, Ye. O.; Kosintsev, S. G.; Tatarenko, V. A. [G.V. Kurdyumov Institute for Metal Physics of the National Academy of Sciences of Ukraine (Ukraine)

    2006-02-15

    The saturation magnetization and the hyperfine magnetic field of different f.c.c. Fe-Ni based alloys containing nearby 29 at .% Ni were studied as a function of temperature and for different Carbon and Manganese contents. We have observed abnormal behaviors that are explained in terms of mixed exchange interactions between atomic spins: J{sub NiNi}(r{sub i}) < 0, J{sub FeFe}(r{sub i}) > 0, J{sub NiFe}(r{sub i}) < 0.