WorldWideScience

Sample records for exciton formation rates

  1. Exciton Formation in Disordered Semiconductors

    DEFF Research Database (Denmark)

    Klochikhin, A.; Reznitsky, A.; Permogorov, S.

    1999-01-01

    Stationary luminescence spectra of disordered solid solutions can be accounted by the model of localized excitons. Detailed analysis of the long time decay kinetics of luminescence shows that exciton formation in these systems is in great extent due to the bimolecular reaction of separated carrie...

  2. Exciton formation and stability in semiconductor heterostructures

    Science.gov (United States)

    Siggelkow, S.; Hoyer, W.; Kira, M.; Koch, S. W.

    2004-02-01

    The formation and stability of excitons in semiconductors is studied on the basis of a microscopic model that includes Coulomb interacting fermionic electrons and holes as well as phonons. Whereas quasiequilibrium calculations predict substantial exciton fractions coexisting with an electron-hole plasma at low temperatures and densities, dynamic calculations reveal that the exciton formation times under these conditions exceed the characteristic lifetimes. At elevated densities, good agreement between dynamical and quasiequilibrium calculations is obtained.

  3. Triplet exciton formation in organic photovoltaics

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Xudong; Westenhoff, Sebastian; Howard, Ian; Ford, Thomas; Friend, Richard; Hodgkiss, Justin; Greenham, Neil [Cavendish Laboratory, University of Cambridge (United Kingdom)

    2009-07-01

    We have recently found that the formation of triplet excitons can be an important loss mechanism in organic photovoltaics, particularly in donor-acceptor blends designed to have high open-circuit voltages. This can occur when the intrachain triplet state lies lower in energy than the charge-transfer state formed at the heterojunction. We find that in a blend based on the polyfluorene derivatives F8BT and PFB, triplet excitons are formed after photoexcitation with much higher efficiency than in the component polymers. We use transient absorption spectroscopy to study the dynamics of charges and triplet excitons on timescales from picoseconds to microseconds. This allows us to determine a characteristic time of {proportional_to} 40 ns for intersystem crossing in the charge-separated state, and to estimate that as many as 75% of photoexcitations lead to the formation of triplet states. To avoid losses to triplet excitons in photovoltaic devices, it is necessary to separate charge pairs before intersystem crossing can occur. We also present photophysical measurements of saturation and relaxation of the triplet excited state absorption used to quantify triplet populations.

  4. Observation of rapid exciton-exciton annihilation in monolayer molybdenum disulfide.

    Science.gov (United States)

    Sun, Dezheng; Rao, Yi; Reider, Georg A; Chen, Gugang; You, Yumeng; Brézin, Louis; Harutyunyan, Avetik R; Heinz, Tony F

    2014-10-08

    Monolayer MoS2 is a direct-gap two-dimensional semiconductor that exhibits strong electron-hole interactions, leading to the formation of stable excitons and trions. Here we report the existence of efficient exciton-exciton annihilation, a four-body interaction, in this material. Exciton-exciton annihilation was identified experimentally in ultrafast transient absorption measurements through the emergence of a decay channel varying quadratically with exciton density. The rate of exciton-exciton annihilation was determined to be (4.3 ± 1.1) × 10(-2) cm(2)/s at room temperature.

  5. Exciton Formation in Semiconductors and the Influence of a Photonic Environment

    Science.gov (United States)

    Kira, M.; Hoyer, W.; Stroucken, T.; Koch, S. W.

    2001-10-01

    A fully microscopic theory is presented for interacting electrons, holes, photons, and phonons in semiconductor heterostructures. The formation dynamics and statistics of incoherent excitons are analyzed for different densities, lattice temperatures, and photonic environments. Luminescence experiments are shown to depend strongly on the photonic environment in contrast to suggested terahertz absorption measurements. Whereas luminescence in free space is dominated by plasma contributions, terahertz absorption should be able to directly measure excitonic populations.

  6. Terahertz signatures of the exciton formation dynamics in non-resonantly excited semiconductors

    Science.gov (United States)

    Kira, M.; Hoyer, W.; Koch, S. W.

    2004-03-01

    A microscopic theory for the induced terahertz (THz) absorption of semiconductors is applied to study the time-dependent system response after non-resonant optical excitation. The formation of excitonic populations from an interacting electron-hole plasma is analyzed and the characteristic THz signatures are computed. Good qualitative agreement with recent experiments is obtained.

  7. Decoupling degradation in exciton formation and recombination during lifetime testing of organic light-emitting devices

    Science.gov (United States)

    Hershey, Kyle W.; Suddard-Bangsund, John; Qian, Gang; Holmes, Russell J.

    2017-09-01

    The analysis of organic light-emitting device degradation is typically restricted to fitting the overall luminance loss as a function of time or the characterization of fully degraded devices. To develop a more complete understanding of degradation, additional specific data are needed as a function of luminance loss. The overall degradation in luminance during testing can be decoupled into a loss in emitter photoluminescence efficiency and a reduction in the exciton formation efficiency. Here, we demonstrate a method that permits separation of these component efficiencies, yielding the time evolution of two additional specific device parameters that can be used in interpreting and modeling degradation without modification to the device architecture or introduction of any additional post-degradation characterization steps. Here, devices based on the phosphor tris[2-phenylpyridinato-C2,N]iridium(III) (Ir(ppy)3) are characterized as a function of initial luminance and emissive layer thickness. The overall loss in device luminance is found to originate primarily from a reduction in the exciton formation efficiency which is exacerbated in devices with thinner emissive layers. Interestingly, the contribution to overall degradation from a reduction in the efficiency of exciton recombination (i.e., photoluminescence) is unaffected by thickness, suggesting a fixed exciton recombination zone width and degradation at an interface.

  8. Rates of star formation

    International Nuclear Information System (INIS)

    Larson, R.B.

    1977-01-01

    It is illustrated that a theoretical understanding of the formation and evolution of galaxies depends on an understanding of star formation, and especially of the factors influencing the rate of star formation. Some of the theoretical problems of star formation in galaxies, some approaches that have been considered in models of galaxy evolution, and some possible observational tests that may help to clarify which processes or models are most relevant are reviewed. The material is presented under the following headings: power-law models for star formation, star formation processes (conditions required, ways of achieving these conditions), observational indications and tests, and measures of star formation rates in galaxies. 49 references

  9. Many-body dynamics and exciton formation studied by time-resolved photoluminescence

    Science.gov (United States)

    Hoyer, W.; Ell, C.; Kira, M.; Koch, S. W.; Chatterjee, S.; Mosor, S.; Khitrova, G.; Gibbs, H. M.; Stolz, H.

    2005-08-01

    The dynamics of exciton and electron-hole plasma populations is studied via time-resolved photoluminescence after nonresonant excitation. By comparing the peak emission at the exciton resonance with the emission of the continuum, it is possible to experimentally identify regimes where the emission originates predominantly from exciton and/or plasma populations. The results are supported by a microscopic theory which allows one to extract the fraction of bright excitons as a function of time.

  10. Formation of plasmon pulses in the cooperative decay of excitons of quantum dots near a metal surface

    Energy Technology Data Exchange (ETDEWEB)

    Shesterikov, A. B.; Gubin, M. Yu. [Vladimir State University (Russian Federation); Gladush, M. G. [Russian Academy of Sciences, Institute of Spectroscopy (Russian Federation); Prokhorov, A. V., E-mail: avprokhorov33@mail.ru [Vladimir State University (Russian Federation)

    2017-01-15

    The formation of pulses of surface electromagnetic waves at a metal–dielectric boundary is considered in the process of cooperative decay of excitons of quantum dots distributed near a metal surface in a dielectric layer. It is shown that the efficiency of exciton energy transfer to excited plasmons can, in principle, be increased by selecting the dielectric material with specified values of the complex permittivity. It is found that in the mean field approximation, the semiclassical model of formation of plasmon pulses in the system under study is reduced to the pendulum equation with the additional term of nonlinear losses.

  11. Application of the theory of excitons to study the formation of positronium and optical transition in matter

    Science.gov (United States)

    Pietrow, M.

    2018-04-01

    Considerable similarity between a positronium atom and an exciton in a quantum dot is indicated. Following this, we apply the calculation regime from the theory of excitons to describe an electron - positron pair near a free volume in matter where the positronium is created. It is shown that, in general, this actual confined state cannot be equated to a classical atom in vacuum. Besides the release of the energy of the pair in the phononic way during the Ps formation, we analyse the possibility of photonic deexcitation and show the way of calculation of its probability. The optical transitions speculated here are dependent on the electronic properties of the matter and, if detected, could allow improving experimental studies of solid matter properties with positron techniques.

  12. Biexciton formation and exciton coherent coupling in layered GaSe

    Science.gov (United States)

    Dey, P.; Paul, J.; Moody, G.; Stevens, C. E.; Glikin, N.; Kovalyuk, Z. D.; Kudrynskyi, Z. R.; Romero, A. H.; Cantarero, A.; Hilton, D. J.; Karaiskaj, D.

    2015-06-01

    Nonlinear two-dimensional Fourier transform (2DFT) and linear absorption spectroscopy are used to study the electronic structure and optical properties of excitons in the layered semiconductor GaSe. At the 1s exciton resonance, two peaks are identified in the absorption spectra, which are assigned to splitting of the exciton ground state into the triplet and singlet states. 2DFT spectra acquired for co-linear polarization of the excitation pulses feature an additional peak originating from coherent energy transfer between the singlet and triplet. At cross-linear polarization of the excitation pulses, the 2DFT spectra expose a new peak likely originating from bound biexcitons. The polarization dependent 2DFT spectra are well reproduced by simulations using the optical Bloch equations for a four level system, where many-body effects are included phenomenologically. Although biexciton effects are thought to be strong in this material, only moderate contributions from bound biexciton creation can be observed. The biexciton binding energy of ˜2 meV was estimated from the separation of the peaks in the 2DFT spectra. Temperature dependent absorption and 2DFT measurements, combined with "ab initio" theoretical calculations of the phonon spectra, indicate strong interaction with the A1 ' phonon mode. Excitation density dependent 2DFT measurements reveal excitation induced dephasing and provide a lower limit for the homogeneous linewidth of the excitons in the present GaSe crystal.

  13. Biexciton formation and exciton coherent coupling in layered GaSe

    Energy Technology Data Exchange (ETDEWEB)

    Dey, P.; Paul, J.; Stevens, C. E.; Glikin, N.; Karaiskaj, D., E-mail: karaiskaj@usf.edu [Department of Physics, University of South Florida, 4202 East Fowler Ave., Tampa, Florida 33620 (United States); Moody, G. [National Institute of Standards and Technology, 325 Broadway, Boulder, Colarado 80305 (United States); Kovalyuk, Z. D.; Kudrynskyi, Z. R. [Chernivtsi Department, Frantsevich Institute of Material Sciences Problems, The National Academy of Sciences of Ukraine, 5, Iryna Vilde St., 58001 Chernivtsi (Ukraine); Romero, A. H. [Physics Department, West Virginia University, Morgantown, West Virginia 26506-6315 (United States); Cantarero, A. [Materials Science Institute, University of Valencia, P.O. Box 2205, 46071 Valencia (Spain); Hilton, D. J. [Department of Physics, University of Alabama at Birmingham, Birmingham, Alabama 35294 (United States)

    2015-06-07

    Nonlinear two-dimensional Fourier transform (2DFT) and linear absorption spectroscopy are used to study the electronic structure and optical properties of excitons in the layered semiconductor GaSe. At the 1s exciton resonance, two peaks are identified in the absorption spectra, which are assigned to splitting of the exciton ground state into the triplet and singlet states. 2DFT spectra acquired for co-linear polarization of the excitation pulses feature an additional peak originating from coherent energy transfer between the singlet and triplet. At cross-linear polarization of the excitation pulses, the 2DFT spectra expose a new peak likely originating from bound biexcitons. The polarization dependent 2DFT spectra are well reproduced by simulations using the optical Bloch equations for a four level system, where many-body effects are included phenomenologically. Although biexciton effects are thought to be strong in this material, only moderate contributions from bound biexciton creation can be observed. The biexciton binding energy of ∼2 meV was estimated from the separation of the peaks in the 2DFT spectra. Temperature dependent absorption and 2DFT measurements, combined with “ab initio” theoretical calculations of the phonon spectra, indicate strong interaction with the A{sub 1}{sup ′} phonon mode. Excitation density dependent 2DFT measurements reveal excitation induced dephasing and provide a lower limit for the homogeneous linewidth of the excitons in the present GaSe crystal.

  14. Biexciton formation and exciton coherent coupling in layered GaSe

    International Nuclear Information System (INIS)

    Dey, P.; Paul, J.; Stevens, C. E.; Glikin, N.; Karaiskaj, D.; Moody, G.; Kovalyuk, Z. D.; Kudrynskyi, Z. R.; Romero, A. H.; Cantarero, A.; Hilton, D. J.

    2015-01-01

    Nonlinear two-dimensional Fourier transform (2DFT) and linear absorption spectroscopy are used to study the electronic structure and optical properties of excitons in the layered semiconductor GaSe. At the 1s exciton resonance, two peaks are identified in the absorption spectra, which are assigned to splitting of the exciton ground state into the triplet and singlet states. 2DFT spectra acquired for co-linear polarization of the excitation pulses feature an additional peak originating from coherent energy transfer between the singlet and triplet. At cross-linear polarization of the excitation pulses, the 2DFT spectra expose a new peak likely originating from bound biexcitons. The polarization dependent 2DFT spectra are well reproduced by simulations using the optical Bloch equations for a four level system, where many-body effects are included phenomenologically. Although biexciton effects are thought to be strong in this material, only moderate contributions from bound biexciton creation can be observed. The biexciton binding energy of ∼2 meV was estimated from the separation of the peaks in the 2DFT spectra. Temperature dependent absorption and 2DFT measurements, combined with “ab initio” theoretical calculations of the phonon spectra, indicate strong interaction with the A 1 ′ phonon mode. Excitation density dependent 2DFT measurements reveal excitation induced dephasing and provide a lower limit for the homogeneous linewidth of the excitons in the present GaSe crystal

  15. Formation of an order in a system of exciton condensed phase islands in quantum wells

    OpenAIRE

    Sugakov, V. I.

    2004-01-01

    A theory of exciton condensed phase creation in two-dimensional system is presented. The theory is applied to explain the appearance of the periodical fragmentation which was observed last years in luminescence from the ring around laser spot in crystal with double quantum wells.

  16. Relaxation of nonthermal hh and lh excitons in ZnSe quantum wells

    DEFF Research Database (Denmark)

    Kalt, H.; Hoffmann, J.; Umlauff, M.

    1998-01-01

    The strong exciton-LO phonon coupling in ZnSe QWs gives a direct access to the relaxation dynamics of nonthermal, free heavy-hole and light-hole excitons. Narrow hot-exciton distributions can be generated by LO-phonon assisted exciton formation. The thermalization of these excitons is monitored...

  17. Exciton dynamics and annihilation in WS2 2D semiconductors.

    Science.gov (United States)

    Yuan, Long; Huang, Libai

    2015-04-28

    We systematically investigate the exciton dynamics in monolayered, bilayered, and trilayered WS2 two-dimensional (2D) crystals by time-resolved photoluminescence (TRPL) spectroscopy. The exciton lifetime when free of exciton annihilation was determined to be 806 ± 37 ps, 401 ± 25 ps, and 332 ± 19 ps for WS2 monolayer, bilayer, and trilayer, respectively. By measuring the fluorescence quantum yields, we also establish the radiative and nonradiative lifetimes of the direct and indirect excitons. The exciton decay in monolayered WS2 exhibits a strong excitation density-dependence, which can be described using an exciton-exciton annihilation (two-particle Auger recombination) model. The exciton-exciton annihilation rate for monolayered, bilayered, and trilayered WS2 was determined to be 0.41 ± 0.02, (6.00 ± 1.09) × 10(-3) and (1.88 ± 0.47) × 10(-3) cm(2) s(-1), respectively. Notably, the exciton-exciton annihilation rate is two orders of magnitude faster in the monolayer than in the bilayer and trilayer. We attribute the much slower exciton-exciton annihilation rate in the bilayer and trilayer to reduced many-body interaction and phonon-assisted exciton-exciton annihilation of indirect excitons.

  18. Triplet exciton dynamics

    International Nuclear Information System (INIS)

    Strien, A.J. van.

    1981-01-01

    Results are presented of electron spin echo experiments combined with laser flash excitation on triplet states of aromatic molecules. Some of the theoretical and experimental aspects of the photoexcited triplet state are discussed in detail and the electron spin echo spectrometers and laser systems are described. All the experiments described in this thesis were performed at liquid helium temperatures. An account is given of the ESE experiments performed on the photoexcited, non-radiative, triplet state of pentacene in napthalene. This is an example of the ESE technique being used to ascertain the zero-field splitting parameters, the populating and depopulating rates, and the orientation of the pentacene molecules in the naphthalene host. A combination of high resolution laser flash excitation and electron-spin echoes in zero-magnetic field allowed the author to observe directly k(vector)→k(vector)' exciton scattering processes in the one-dimensional triplet excitons in tetrachlorobenzene for the first time. Additional experimental data about exciton scattering is provided and a study of the orientational dependence of the spin-lattice relaxation of the triplet excitons in an external magnetic field is described. (Auth.)

  19. Charge separation of dense two-dimensional electron-hole gases: mechanism for exciton ring pattern formation.

    Science.gov (United States)

    Rapaport, R; Chen, Gang; Snoke, D; Simon, Steven H; Pfeiffer, Loren; West, Ken; Liu, Y; Denev, S

    2004-03-19

    We report on new experiments and theory that unambiguously resolve the recent puzzling observation of large diameter exciton emission halos around a laser excitation spot in two dimensional systems. We find a novel separation of plasmas of opposite charge with emission from the sharp circular boundary between these two regions. This charge separation allows for cooling of initially hot optically generated carriers as they dwell in the charge reservoirs for very long times.

  20. Spatially indirect excitons in coupled quantum wells

    Energy Technology Data Exchange (ETDEWEB)

    Lai, Chih-Wei Eddy [Univ. of California, Berkeley, CA (United States)

    2004-03-01

    observed. The spatial and energy distributions of optically active excitons were used as thermodynamic quantities to construct a phase diagram of the exciton system, demonstrating the existence of distinct phases. Optical and electrical properties of the CQW sample were examined thoroughly to provide deeper understanding of the formation mechanisms of these cold exciton systems. These insights offer new strategies for producing cold exciton systems, which may lead to opportunities for the realization of BEC in solid-state systems.

  1. Radiative recombination of excitons in amorphous semiconductors

    International Nuclear Information System (INIS)

    Singh, Jai

    2005-01-01

    A theory for calculating the radiative lifetime of excitons in amorphous semiconductors is presented. Four possibilities of excitonic radiative recombination are considered and the corresponding rates are derived at thermal equilibrium. The radiative lifetime is calculated from the inverse of the maximum rate for all the four possibilities. Results agree very well with experiments

  2. Frequency dependence of the radiative decay rate of excitons in self-assembled quantum dots: Experiment and theory

    DEFF Research Database (Denmark)

    Stobbe, Søren; Johansen, Jeppe; Kristensen, Philip Trøst

    2009-01-01

    We analyze time-resolved spontaneous emission from excitons confined in self-assembled InAs quantum dots placed at various distances to a semiconductor-air interface. The modification of the local density of optical states due to the proximity of the interface enables unambiguous determination...... furthermore discuss three models of quantum dot strain and compare the measured wave-function overlap to these models. The observed frequency dependence of the wave-function overlap can be understood qualitatively in terms of the different compressibility of electrons and holes originating from...

  3. Formation rate of natural gas hydrate

    Energy Technology Data Exchange (ETDEWEB)

    Mork, Marit

    2002-07-01

    The rate of methane hydrate and natural gas hydrate formation was measured in a 9.5 litre stirred tank reactor of standard design. The experiments were performed to better understand the performance and scale-up of a reactor for continuous production of natural gas hydrates. The hydrate formation rate was measured at steady-state conditions at pressures between 70 and 90 bar and temperatures between 7 and 15 deg C. Between 44 and 56 % of the gas continuously supplied to the reactor was converted to hydrate. The experimental results show that the rate of hydrate formation is strongly influenced by gas injection rate and pressure. The effect of stirring rate is less significant and subcooling has no observable effect on the formation rate. Hydrate crystal concentration and gas composition do not influence the hydrate formation rate. Observations of produced hydrate crystals indicate that the crystals are elongated, about 5 micron in diameter and 10 micron long. Analysis of the results shows that the rate of hydrate formation is dominated by gas-liquid mass transfer. A mass transfer model, the bubble-to-crystal model, was developed for the hydrate formation rate in a continuous stirred tank reactor, given in terms of concentration driving force and an overall mass transfer coefficient. The driving force is the difference between the gas concentration at the gas-liquid interface and at the hydrate crystal surface. These concentrations correspond to the solubility of gas in water at experimental temperature and pressure and the solubility of gas at hydrate equilibrium temperature and experimental pressure, respectively. The overall mass transfer coefficient is expressed in terms of superficial gas velocity and impeller power consumption, parameters commonly used in study of stirred tank reactors. Experiments and modeling show that the stirred tank reactor has a considerable potential for increased production capacity. However, at higher hydrate production rates the

  4. Suppressing Energy Loss due to Triplet Exciton Formation in Organic Solar Cells: The Role of Chemical Structures and Molecular Packing

    KAUST Repository

    Chen, Xiankai

    2017-04-21

    In the most efficient solar cells based on blends of a conjugated polymer (electron donor) and a fullerene derivative (electron acceptor),ultrafast formation of charge-transfer (CT) electronic states at the donor-acceptor interfaces and efficient separation of these CT states into free charges, lead to internal quantum efficiencies near 100%. However, there occur substantial energy losses due to the non-radiative recombinations of the charges, mediated by the loweset-energy (singlet and triplet) CT states; for example, such recombinations can lead to the formation of triplet excited electronic states on the polymer chains, which do not generate free charges. This issue remains a major factor limiting the power conversion efficiencies (PCE) of these devices. The recombination rates are, however, difficult to quantify experimentally. To shed light on these issues, here, an integrated multi-scale theoretical approach that combines molecular dynamics simulations with quantum chemistry calculations is employed in order to establish the relationships among chemical structures, molecular packing, and non-radiative recombination losses mediated by the lowest-energy charge-transfer states.

  5. Influence of fluorosurfactants on hydrate formation rates

    Energy Technology Data Exchange (ETDEWEB)

    Kim, C.U.; Jeong, K.E.; Chae, H.J.; Jeong, S.Y. [Korea Reasearch Inst. of Chemical Technology, Alternative Chemicals/Fuel Research Center, Yuseong-Gu, Daejon (Korea, Republic of)

    2008-07-01

    Gas hydrates, or clathrates, are ice-like solids that forms when natural gas is in contact with liquid water or ice under high pressure and low temperature. There is significant interest in studying the storage and transportation of gas in the form of hydrates. However, a critical problem impacting the industrial application of gas hydrates for storage and transportation of natural gas is the slow formation rate of natural gas hydrate. Researchers have previously reported on the promotion effect of some additives on gas hydrate formation and hydrate gas content. Fluorosurfactants are significantly superior to nonfluorinated surfactants in wetting action, as well as stability in harsh environments, both thermal and chemical. This paper discussed an experimental investigation into the effects of fluorosurfactants with different ionic types on the formation of methane hydrate. The surfactants used were FSN-100 of DuPont Zonyl as non-ionic surfactant and FC-143 of DuPont as anionic surfactant. The paper discussed the experimental apparatus for methane hydrate formation. It also discussed hydrate formation kinetics and the series of hydrate formation experiments that were conducted in the presence of fluorosurfactants. Last, the paper explored the results of the study. It was concluded that anionic fluorosurfactant of FC-143 had a better promoting effect on methane hydrate formation compared with nonionic surfactant of FSN-100. 8 refs., 2 tabs., 2 figs.

  6. Confined exciton spectroscopy

    International Nuclear Information System (INIS)

    Torres, Clivia M.S.

    1998-01-01

    Full text: In this work, the exciton is considered as a sensor of the electronic and optical properties of materials such as semiconductors, which have size compared to the exciton De Broglie wavelength, approximately 20 nm, depending on the semiconductor. Examples of electron-phonon, electron-electron, photon-electron, exciton-polariton, phonon-plasmon, are presented, under different confinement conditions such as quantum wells, superlattices

  7. Exciton Dynamics, Transport, and Annihilation in Atomically Thin Two-Dimensional Semiconductors.

    Science.gov (United States)

    Yuan, Long; Wang, Ti; Zhu, Tong; Zhou, Mingwei; Huang, Libai

    2017-07-20

    Large binding energy and unique exciton fine structure make the transition metal dichalcogenides (TMDCs) an ideal platform to study exciton behaviors in two-dimensional (2D) systems. While excitons in these systems have been extensively researched, there currently lacks a consensus on mechanisms that control dynamics. In this Perspective, we discuss extrinsic and intrinsic factors in exciton dynamics, transport, and annihilation in 2D TMDCs. Intrinsically, dark and bright exciton energy splitting is likely to play a key role in modulating the dynamics. Extrinsically, defect scattering is prevalent in single-layer TMDCs, which leads to rapid picosecond decay and limits exciton transport. The exciton-exciton annihilation process in single-layer TMDCs is highly efficient, playing an important role in the nonradiative recombination rate in the high exciton density regime. Future challenges and opportunities to control exciton dynamics are discussed.

  8. Atomic lattice excitons: from condensates to crystals

    International Nuclear Information System (INIS)

    Kantian, A; Daley, A J; Toermae, P; Zoller, P

    2007-01-01

    We discuss atomic lattice excitons (ALEs), bound particle-hole pairs formed by fermionic atoms in two bands of an optical lattice. Such a system provides a clean set-up, with tunable masses and interactions, to study fundamental properties of excitons including exciton condensation. We also find that for a large effective mass ratio between particles and holes, effective long-range interactions can mediate the formation of an exciton crystal, for which superfluidity is suppressed. Using a combination of mean-field treatments, bosonized theory based on a Born-Oppenheimer approximation, and one-dimensional (1D) numerical computation, we discuss the properties of ALEs under varying conditions, and discuss in particular their preparation and measurement

  9. Atomic lattice excitons: from condensates to crystals

    Energy Technology Data Exchange (ETDEWEB)

    Kantian, A [Institute for Quantum Optics and Quantum Information of the Austrian Academy of Sciences, A-6020 Innsbruck (Austria); Daley, A J [Institute for Quantum Optics and Quantum Information of the Austrian Academy of Sciences, A-6020 Innsbruck (Austria); Toermae, P [Nanoscience Center, Department of Physics, University of Jyvaeskylae, PO Box 35, FIN-40014 (Finland); Zoller, P [Institute for Quantum Optics and Quantum Information of the Austrian Academy of Sciences, A-6020 Innsbruck (Austria)

    2007-11-15

    We discuss atomic lattice excitons (ALEs), bound particle-hole pairs formed by fermionic atoms in two bands of an optical lattice. Such a system provides a clean set-up, with tunable masses and interactions, to study fundamental properties of excitons including exciton condensation. We also find that for a large effective mass ratio between particles and holes, effective long-range interactions can mediate the formation of an exciton crystal, for which superfluidity is suppressed. Using a combination of mean-field treatments, bosonized theory based on a Born-Oppenheimer approximation, and one-dimensional (1D) numerical computation, we discuss the properties of ALEs under varying conditions, and discuss in particular their preparation and measurement.

  10. Model of fragmentation of the exciton inner ring in semiconductor quantum wells

    OpenAIRE

    Chernyuk, A. A.; Sugakov, V. I.; Tomylko, V. V.

    2016-01-01

    The appearance of the non-homogeneous structures of the indirect exciton density distribution in the region of the quantum well (in the region of the inner ring) is explained. The structure (the fragmentation) occurs due to the exciton condensed phase formation because of interaction between excitons. The formation of the structure is related with the non-equalibrity of the system, which is caused by the exciton finite lifetime and the presence of the pumpimg. The structure emerges in the sha...

  11. Physical theory of excitons in conducting polymers.

    Science.gov (United States)

    Brazovskii, Serguei; Kirova, Natasha

    2010-07-01

    In this tutorial review, we cover the solid state physics approach to electronic and optical properties of conducting polymers. We attempt to bring together languages and advantages of the solid state theory for polymers and of the quantum chemistry for monomers. We consider polymers as generic one-dimensional semiconductors with features of strongly correlated electronic systems. Our model combines the long range electron-hole Coulomb attraction with a specific effect of strong intra-monomer electronic correlations, which results in effective intra-monomer electron-hole repulsion. Our approach allows to go beyond the single-chain picture and to compare excitons for polymers in solutions and in films. The approach helps connecting such different questions as shallow singlet and deep triplet excitons, stronger binding of interchain excitons in films, crossings of excitons' branches, 1/N energies shifts in oligomers. We describe a strong suppression of the luminescence from free charge carriers by long-range Coulomb interactions. Main attention is devoted to the most requested in applications phenyl based polymers. The specifics of the benzene ring monomer give rise to existence of three possible types of excitons: Wannier-Mott, Frenkel and intermediate ones. We discuss experimental manifestations of various excitons and of their transformations. We touch effects of the time-resolved self-trapping by libron modes leading to formation of torsion polarons.

  12. Excitonic processes at organic heterojunctions

    Science.gov (United States)

    He, ShouJie; Lu, ZhengHong

    2018-02-01

    Understanding excitonic processes at organic heterojunctions is crucial for development of organic semiconductor devices. This article reviews recent research on excitonic physics that involve intermolecular charge transfer (CT) excitons, and progress on understanding relationships between various interface energy levels and key parameters governing various competing interface excitonic processes. These interface excitonic processes include radiative exciplex emission, nonradiative recombination, Auger electron emission, and CT exciton dissociation. This article also reviews various device applications involving interface CT excitons, such as organic light-emitting diodes (OLEDs), organic photovoltaic cells, organic rectifying diodes, and ultralow-voltage Auger OLEDs.

  13. Exciton dephasing and biexciton binding in CdSe/ZnSe islands

    DEFF Research Database (Denmark)

    Wagner, Hans Peter; Tranitz, H.-P.; Preis, H

    1999-01-01

    The dephasing of excitons and the formation of biexcitons in self-organized CdSe/ZnSe islands grown by molecular-beam epitaxy is investigated using spectrally resolved four-wave mixing. A distribution of exciton-exciton scattering efficiencies and dephasing times in the range of 0.5-10 ps are obs...

  14. Dynamics of charge-transfer excitons in type-II semiconductor heterostructures

    Science.gov (United States)

    Stein, M.; Lammers, C.; Richter, P.-H.; Fuchs, C.; Stolz, W.; Koch, M.; Vänskä, O.; Weseloh, M. J.; Kira, M.; Koch, S. W.

    2018-03-01

    The formation, decay, and coherence properties of charge-transfer excitons in semiconductor heterostructures are investigated by applying four-wave-mixing and terahertz spectroscopy in combination with a predictive microscopic theory. A charge-transfer process is identified where the optically induced coherences decay directly into a charge-transfer electron-hole plasma and exciton states. It is shown that charge-transfer excitons are more sensitive to the fermionic electron-hole substructure than regular excitons.

  15. Excitonic Photoluminescence in Semiconductor Quantum Wells: Plasma versus Excitons

    Science.gov (United States)

    Chatterjee, S.; Ell, C.; Mosor, S.; Khitrova, G.; Gibbs, H. M.; Hoyer, W.; Kira, M.; Koch, S. W.; Prineas, J. P.; Stolz, H.

    2004-02-01

    Time-resolved photoluminescence spectra after nonresonant excitation show a distinct 1s resonance, independent of the existence of bound excitons. A microscopic analysis identifies exciton and electron-hole plasma contributions. For low temperatures and low densities, the excitonic emission is extremely sensitive to details of the electron-hole-pair population making it possible to identify even minute fractions of optically active excitons.

  16. Exciton-Exciton Annihilation Is Coherently Suppressed in H-Aggregates, but Not in J-Aggregates

    NARCIS (Netherlands)

    Tempelaar, Roel; Jansen, Thomas L. C.; Knoester, Jasper

    2017-01-01

    We theoretically demonstrate a strong dependence of the annihilation rate between (singlet) excitons on the sign of dipole-dipole couplings between molecules. For molecular H-aggregates, where this sign is positive, the phase relation of the delocalized two-exciton wave functions causes a

  17. Bound Exciton Complexes

    Science.gov (United States)

    Meyer, B. K.

    In the preceding chapter, we concentrated on the properties of free excitons. These free excitons may move through the sample and hit a trap, a nonradiative or a radiative recombination center. At low temperatures, the latter case gives rise to either deep center luminescence, mentioned in Sect. 7.1 and discussed in detail in Chap. 9, or to the luminescence of bound exciton complexes (BE or BEC). The chapter continues with the most prominent of these BECs, namely A-excitons bound to neutral donors. The next aspects are the more weakly BEs at ionized donors. The Sect. 7.4 treats the binding or localization energies of BEC from a theoretical point of view, while Sect. 7.5 is dedicated to excited states of BECs, which contain either holes from deeper valence bands or an envelope function with higher quantum numbers. The last section is devoted to donor-acceptor pair transitions. There is no section devoted specifically to excitons bound to neutral acceptors, because this topic is still partly controversially discussed. Instead, information on these A0X complexes is scattered over the whole chapter, however, with some special emphasis seen in Sects. 7.1, 7.4, and 7.5.

  18. Photoluminescence dynamics of weakly confined excitons in GaAs thin films

    International Nuclear Information System (INIS)

    Kanno, Atsushi; Katouf, Redouane; Kojima, Osamu; Ishi-Hayase, Junko; Sasaki, Masahide; Tsuchiya, Masahiro; Isu, Toshiro

    2008-01-01

    We investigate the dynamics of weakly confined excitons in GaAs thin films measured by time-resolved photoluminescence (PL) technique. When excitation energy was above the resonant energy of the exciton, a long PL rise time of about 200 ps was observed. It is considered that an exciton formation process from excited continuum energy states to discrete energy states of the exciton in the thin film causes the slow PL rise. The observed PL decay time constant was about 14 ns due to high quality fabricated samples. The observed population dynamics can be surely ascribed to the specific features of weakly confined excitons

  19. Exciton emissions in alkali cyanides

    International Nuclear Information System (INIS)

    Weid, J.P. von der.

    1979-10-01

    The emissions of Alkali Cyanides X irradiated at low temperature were measured. In addition to the molecular (Frenkel Type) exciton emissions, another emitting centre was found and tentatively assigned to a charge transfer self trapped exciton. The nature of the molecular exciton emitting state is discussed. (Author) [pt

  20. Exciton Transfer in Carbon Nanotube Aggregates for Energy Harvesting Applications

    Science.gov (United States)

    Davoody, Amirhossein; Karimi, Farhad; Knezevic, Irena

    Carbon nanotubes (CNTs) are promising building blocks for organic photovoltaic devices, owing to their tunable band gap, mechanical and chemical stability. We study intertube excitonic energy transfer between pairs of CNTs with different orientations and band gaps. The optically bright and dark excitonic states in CNTs are calculated by solving the Bethe-Salpeter equation. We calculate the exciton transfer rates due to the direct and exchange Coulomb interactions, as well as the second-order phonon-assisted processes. We show the importance of phonons in calculating the transfer rates that match the measurements. In addition, we discuss the contribution of optically inactive excited states in the exciton transfer process, which is difficult to determine experimentally. Furthermore, we study the effects of sample inhomogeneity, impurities, and temperature on the exciton transfer rate. The inhomogeneity in the CNT sample dielectric function can increase the transfer rate by about a factor of two. We show that the exciton confinement by impurities has a detrimental effect on the transfer rate between pairs of similar CNTs. The exciton transfer rate increases monotonically with increasing temperature. Support by the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering under Award DE-SC0008712.

  1. Exciton multiplication from first principles.

    Science.gov (United States)

    Jaeger, Heather M; Hyeon-Deuk, Kim; Prezhdo, Oleg V

    2013-06-18

    Third-generation photovolatics require demanding cost and power conversion efficiency standards, which may be achieved through efficient exciton multiplication. Therefore, generating more than one electron-hole pair from the absorption of a single photon has vast ramifications on solar power conversion technology. Unlike their bulk counterparts, irradiated semiconductor quantum dots exhibit efficient exciton multiplication, due to confinement-enhanced Coulomb interactions and slower nonradiative losses. The exact characterization of the complicated photoexcited processes within quantum-dot photovoltaics is a work in progress. In this Account, we focus on the photophysics of nanocrystals and investigate three constituent processes of exciton multiplication, including photoexcitation, phonon-induced dephasing, and impact ionization. We quantify the role of each process in exciton multiplication through ab initio computation and analysis of many-electron wave functions. The probability of observing a multiple exciton in a photoexcited state is proportional to the magnitude of electron correlation, where correlated electrons can be simultaneously promoted across the band gap. Energies of multiple excitons are determined directly from the excited state wave functions, defining the threshold for multiple exciton generation. This threshold is strongly perturbed in the presence of surface defects, dopants, and ionization. Within a few femtoseconds following photoexcitation, the quantum state loses coherence through interactions with the vibrating atomic lattice. The phase relationship between single excitons and multiple excitons dissipates first, followed by multiple exciton fission. Single excitons are coupled to multiple excitons through Coulomb and electron-phonon interactions, and as a consequence, single excitons convert to multiple excitons and vice versa. Here, exciton multiplication depends on the initial energy and coupling magnitude and competes with electron

  2. Quasienergy Spectroscopy of Excitons

    DEFF Research Database (Denmark)

    Johnsen, Kristinn; Jauho, Antti-Pekka

    1999-01-01

    We theoretically study nonlinear optics of excitons under intense THz irradiation. In particular, the linear near-infrared absorption and resonantly enhanced nonlinear sideband generation are described. We predict a rich structure in the spectra which an be interpreted in terms of the quasienergy...

  3. Ultrafast exciton transport in organic nanotubes

    NARCIS (Netherlands)

    Pugzlys, A; Hania, R; Didraga, C; Malyshev, V.A.; Knoester, J; Duppen, K; Kobayashi, T; Okada, T; Kobayashi, T; Nelson, KA; DeSilvestri, S

    2005-01-01

    The dynamics of exciton transport between the inner and outer walls of double-layer cylindrical aggregates is measured. Downhill transport is fast (275 A) and excitation intensity independent. Uphill transport is much slower (3.5 ps), but this rate increases when the excitation density is raised.

  4. Quantum-dot excitons in nanostructured environments

    DEFF Research Database (Denmark)

    Hvam, Jørn Märcher; Stobbe, Søren; Lodahl, Peter

    2010-01-01

    determined the oscillator strength, quantum efficiency and spin-flip rates of QD excitons as well as their dependencies on emission wavelength and QD size. Enhancement and inhibition of QD spontaneous emission in photonic crystal membranes (PCMs) is observed. Efficient coupling to PCM waveguides...

  5. Quantum-dot excitons in nanostructured environments

    DEFF Research Database (Denmark)

    Hvam, Jørn Märcher; Stobbe, Søren; Lodahl, Peter

    2011-01-01

    determined the oscillator strength, quantum efficiency and spin-flip rates of QD excitons as well as their dependencies on emission wavelength and QD size. Enhancement and inhibition of QD spontaneous emission in photonic crystal membranes (PCMs) is observed. Efficient coupling to PCM waveguides...

  6. Two-exciton excited states of J-aggregates in the presence of exciton–exciton annihilation

    International Nuclear Information System (INIS)

    Levinsky, B.; Fainberg, B.D.; Nesterov, L.A.; Rosanov, N.N.

    2016-01-01

    We study decay of two-exciton states of a J-aggregate that is collective in nature. We use mathematical formalism based on effective non-Hermitian Hamiltonian suggested in nuclear theory. We show that decay of two-exciton states is strongly affected by the interference processes in the exciton–exciton annihilation. Our evaluations of the imaginary part of the effective Hamiltonian show that it exceeds the spacing between real energies of the two-exciton states that gives rise to the transition to the regime of overlapping resonances supplying the system by the new collectivity – the possibility of coherent decay in the annihilation channel. The decay of two-exciton states varies from twice bimolecular decay rate to the much smaller values that is associated with population trapping. We have also considered the corresponding experiment in the framework of our approach, the picture of which appears to be more complex and richer than it was reasoned before.

  7. Highly mobile charge-transfer excitons in two-dimensional WS2/tetracene heterostructures

    Science.gov (United States)

    Zhu, Tong; Yuan, Long; Zhao, Yan; Zhou, Mingwei; Wan, Yan; Mei, Jianguo; Huang, Libai

    2018-01-01

    Charge-transfer (CT) excitons at heterointerfaces play a critical role in light to electricity conversion using organic and nanostructured materials. However, how CT excitons migrate at these interfaces is poorly understood. We investigate the formation and transport of CT excitons in two-dimensional WS2/tetracene van der Waals heterostructures. Electron and hole transfer occurs on the time scale of a few picoseconds, and emission of interlayer CT excitons with a binding energy of ~0.3 eV has been observed. Transport of the CT excitons is directly measured by transient absorption microscopy, revealing coexistence of delocalized and localized states. Trapping-detrapping dynamics between the delocalized and localized states leads to stretched-exponential photoluminescence decay with an average lifetime of ~2 ns. The delocalized CT excitons are remarkably mobile with a diffusion constant of ~1 cm2 s−1. These highly mobile CT excitons could have important implications in achieving efficient charge separation. PMID:29340303

  8. Excitonic effects in the luminescence of quantum wells

    International Nuclear Information System (INIS)

    Deveaud, B.; Kappei, L.; Berney, J.; Morier-Genoud, F.; Portella-Oberli, M.T.; Szczytko, J.; Piermarocchi, C.

    2005-01-01

    We report on the origin of the excitonic luminescence in quantum wells. This study is carried out by time-resolved photoluminescence experiments performed on a very high-quality InGaAs quantum well sample in which the photoluminescence contributions at the energy of the exciton and at the band edge can be clearly separated and traced over a broad range of times and densities. This allows us to compare the two conflicting theoretical approaches to the question of the origin of the excitonic luminescence in quantum wells: the model of the exciton population and the model of the Coulomb correlated plasma. We measure the exciton formation time and we show the fast exciton formation and its dependence with carrier density. We are also able to give the boundaries of the Mott transition in our system, and to show the absence of observable renormalization of the gap below the onset of this transition. We detail the characteristics of the trion formation and evidence the possible formation of both positive and negative trions in the absence of any resident free carrier populations

  9. Synthesis and Exciton Dynamics of Triplet Sensitized Conjugated Polymers

    KAUST Repository

    Andernach, Rolf

    2015-07-22

    We report the synthesis of a novel polythiophene-based host-guest copolymer incorporating a Pt-porphyrin complex (TTP-Pt) into the backbone for efficient singlet to triplet polymer exciton sensitization. We elucidated the exciton dynamics in thin films of the material by means of Transient Absorption Spectrosopcy (TAS) on multiple timescales and investigated the mechanism of triplet exciton formation. During sensitization, single exciton diffusion is followed by exciton transfer from the polymer backbone to the complex where it undergoes intersystem crossing to the triplet state of the complex. We directly monitored the triplet exciton back transfer from the Pt-porphyrin to the polymer and find that 60% of the complex triplet excitons are transferred with a time constant of 1087 ps. We propose an equilibrium between polymer and porphyrin triplet states as a result of the low triplet diffusion length in the polymer backbone and hence an increased local triplet population resulting in increased triplet-triplet annihilation. This novel system has significant implications for the design of novel materials for triplet sensitized solar cells and up-conversion layers.

  10. Tunable excitons in bilayer graphene

    Science.gov (United States)

    Ju, Long; Wang, Lei; Cao, Ting; Taniguchi, Takashi; Watanabe, Kenji; Louie, Steven G.; Rana, Farhan; Park, Jiwoong; Hone, James; Wang, Feng; McEuen, Paul L.

    2017-11-01

    Excitons, the bound states of an electron and a hole in a solid material, play a key role in the optical properties of insulators and semiconductors. Here, we report the observation of excitons in bilayer graphene (BLG) using photocurrent spectroscopy of high-quality BLG encapsulated in hexagonal boron nitride. We observed two prominent excitonic resonances with narrow line widths that are tunable from the mid-infrared to the terahertz range. These excitons obey optical selection rules distinct from those in conventional semiconductors and feature an electron pseudospin winding number of 2. An external magnetic field induces a large splitting of the valley excitons, corresponding to a g-factor of about 20. These findings open up opportunities to explore exciton physics with pseudospin texture in electrically tunable graphene systems​.

  11. Star-formation rates of cluster galaxies: nature versus nurture

    Science.gov (United States)

    Laganá, Tatiana F.; Ulmer, M. P.

    2018-03-01

    We analysed 17 galaxy clusters, and investigated, for the first time, the dependence of the star formation rate (SFR) and specific star formation rate (sSFR) as a function of projected distance (as a proxy for environment) and stellar mass for cluster galaxies in an intermediate-to-high redshift range (0.4 cluster galaxies at an intermediate-to-high redshift range, mass is the primary characteristic that drives SFR.

  12. Exciton-Exciton Annihilation Is Coherently Suppressed in H-Aggregates, but Not in J-Aggregates.

    Science.gov (United States)

    Tempelaar, Roel; Jansen, Thomas L C; Knoester, Jasper

    2017-12-21

    We theoretically demonstrate a strong dependence of the annihilation rate between (singlet) excitons on the sign of dipole-dipole couplings between molecules. For molecular H-aggregates, where this sign is positive, the phase relation of the delocalized two-exciton wave functions causes a destructive interference in the annihilation probability. For J-aggregates, where this sign is negative, the interference is constructive instead; as a result, no such coherent suppression of the annihilation rate occurs. As a consequence, room temperature annihilation rates of typical H- and J-aggregates differ by a factor of ∼3, while an order of magnitude difference is found for low-temperature aggregates with a low degree of disorder. These findings, which explain experimental observations, reveal a fundamental principle underlying exciton-exciton annihilation, with major implications for technological devices and experimental studies involving high excitation densities.

  13. Bright triplet excitons in caesium lead halide perovskites

    Science.gov (United States)

    Becker, Michael A.; Vaxenburg, Roman; Nedelcu, Georgian; Sercel, Peter C.; Shabaev, Andrew; Mehl, Michael J.; Michopoulos, John G.; Lambrakos, Samuel G.; Bernstein, Noam; Lyons, John L.; Stöferle, Thilo; Mahrt, Rainer F.; Kovalenko, Maksym V.; Norris, David J.; Rainò, Gabriele; Efros, Alexander L.

    2018-01-01

    Nanostructured semiconductors emit light from electronic states known as excitons. For organic materials, Hund’s rules state that the lowest-energy exciton is a poorly emitting triplet state. For inorganic semiconductors, similar rules predict an analogue of this triplet state known as the ‘dark exciton’. Because dark excitons release photons slowly, hindering emission from inorganic nanostructures, materials that disobey these rules have been sought. However, despite considerable experimental and theoretical efforts, no inorganic semiconductors have been identified in which the lowest exciton is bright. Here we show that the lowest exciton in caesium lead halide perovskites (CsPbX3, with X = Cl, Br or I) involves a highly emissive triplet state. We first use an effective-mass model and group theory to demonstrate the possibility of such a state existing, which can occur when the strong spin–orbit coupling in the conduction band of a perovskite is combined with the Rashba effect. We then apply our model to CsPbX3 nanocrystals, and measure size- and composition-dependent fluorescence at the single-nanocrystal level. The bright triplet character of the lowest exciton explains the anomalous photon-emission rates of these materials, which emit about 20 and 1,000 times faster than any other semiconductor nanocrystal at room and cryogenic temperatures, respectively. The existence of this bright triplet exciton is further confirmed by analysis of the fine structure in low-temperature fluorescence spectra. For semiconductor nanocrystals, which are already used in lighting, lasers and displays, these excitons could lead to materials with brighter emission. More generally, our results provide criteria for identifying other semiconductors that exhibit bright excitons, with potential implications for optoelectronic devices.

  14. Exciton center-of-mass localization and dielectric environment effect in monolayer WS2

    Science.gov (United States)

    Hichri, Aïda; Ben Amara, Imen; Ayari, Sabrine; Jaziri, Sihem

    2017-06-01

    The ultrathin transition metal dichalcogenides (TMDs) have emerged as promising materials for various applications using two dimensional semiconductors. They have attracted increasing attention due to their unique optical properties originate from neutral and charged excitons. In this paper, we study the strong localization of exciton center-of-mass motion within random potential fluctuations caused by the monolayer defects. Here, we report negatively charged exciton formation in monolayer TMDs, notably tungsten disulfide WS2. Our theory is based on an effective mass model of neutral and charged excitons, parameterized by ab-initio calculations. Taking into the account the strong correlation between the monolayer WS2 and the surrounding dielectric environment, our theoretical results are in good agreement with one-photon photoluminescence (PL) and reflectivity measurements. We also show that the exciton state with p-symmetry, experimentally observed by two-photon PL emission, is energetically below the 2s-state. We use the equilibrium mass action law, to quantify the relative weight of exciton and trion PL. We show that exciton and trion emission can be tuned and controlled by external parameters like temperature, pumping, and injection electrons. Finally, in comparison with experimental measurements, we show that exciton emission in monolayer tungsten dichalcogenides is substantially reduced. This feature suggests that free exciton can be trapped in disordered potential wells to form a localized exciton and therefore offers a route toward novel optical properties.

  15. Exciton dynamics in cuprous oxide

    NARCIS (Netherlands)

    Fishman, D. A.; Revcolevschi, A.; van Loosdrecht, P. H. M.; Stutzmann, M

    2006-01-01

    This work addresses the mid-infrared properties of cuprous oxide and in particular induced absorption due to the presence of excitons. We probe the population of the non-radiative ground state of para-excitons via laser-induced changes of the transmission in the "hydrogenic" 1s-2p/1s-3p transition

  16. Effect of alteration phase formation on the glass dissolution rate

    Energy Technology Data Exchange (ETDEWEB)

    Ebert, W.L. [Argonne National Laboratory, Chemical Technology Div. (United States)

    1997-07-01

    The dissolution rates of many glasses have been observed to increase upon the formation of certain alteration phases. While simulations have predicted the accelerating effect of formation of certain phases, the phases predicted to form in computer simulations are usually different than those observed to form in experiments. This is because kinetically favored phases form first in experiments, while simulations predict the thermodynamically favored phases. Static dissolution tests with crushed glass have been used to measure the glass dissolution rate after alteration phases form. Because glass dissolution rates are calculated on a per area basis, an important effect in tests conducted with crushed glass is the decrease in the surface area of glass that is available for reaction as the glass dissolves. This loss of surface area must be taken into account when calculating the dissolution rate. The phases that form and their effect on the dissolution rate are probably related to the glass composition. The impact of phase formation on the glass dissolution rate also varies according to the solubility products of the alteration phases and how the orthocilicic acid activity is affected. Insight into the relationship between the glass dissolution rate, solution chemistry and alteration phase formation is provided by the results of accelerated dissolution tests.

  17. Formation rate of water masses in the Japan Sea

    International Nuclear Information System (INIS)

    Kawamura, Hideyuki; Ito, Toshimichi; Yoon, Jong-Hwan

    2007-01-01

    Water masses in the subsurface and the intermediate layer are actively formed due to strong winter convection in the Japan Sea. It is probable that some fraction of pollution is carried into the layer below the sea surface together with these water masses, so it is important to estimate the formation rate and turnover time of water masses to study the fate of pollutants. The present study estimates the annual formation rate and the turnover time of water masses using a three-dimensional ocean circulation model and a particle chasing method. The total annual formation rate of water masses below the sea surface amounted to about 3.53±0.55 Sv in the Japan Sea. Regarding representative intermediate water masses, the annual formation rate of the Upper portion of the Japan Sea Proper Water (UJSPW) and the Japan Sea Intermediate Water (JSIW) were estimated to be about 0.38±0.11 and 1.43±0.16 Sv, respectively, although there was little evidence of the formation of deeper water masses below a depth of about 1500 m in a numerical experiment. An estimate of turnover time shows that the UJSPW and the JSIW circulate in the intermediate layer of the Japan Sea with timescales of about 22.1 and 2.2 years, respectively. (author)

  18. Star-formation rate in compact star-forming galaxies

    Science.gov (United States)

    Izotova, I. Y.; Izotov, Y. I.

    2018-03-01

    We use the data for the Hβ emission-line, far-ultraviolet (FUV) and mid-infrared 22 μm continuum luminosities to estimate star formation rates averaged over the galaxy lifetime for a sample of about 14000 bursting compact star-forming galaxies (CSFGs) selected from the Data Release 12 (DR12) of the Sloan Digital Sky Survey (SDSS). The average coefficient linking and the star formation rate SFR0 derived from the Hβ luminosity at zero starburst age is found to be 0.04. We compare s with some commonly used SFRs which are derived adopting a continuous star formation during a period of {˜} 100 Myr, and find that the latter ones are 2-3 times higher. It is shown that the relations between SFRs derived using a geometric mean of two star-formation indicators in the UV and IR ranges and reduced to zero starburst age have considerably lower dispersion compared to those with single star-formation indicators. We suggest that our relations for determination are more appropriate for CSFGs because they take into account a proper temporal evolution of their luminosities. On the other hand, we show that commonly used SFR relations can be applied for approximate estimation within a factor of {˜} 2 of the averaged over the lifetime of the bursting compact galaxy.

  19. The excitonic insulator route through a dynamical phase transition induced by an optical pulse

    Energy Technology Data Exchange (ETDEWEB)

    Brazovskii, S., E-mail: brazov@lptms.u-psud.fr [Université Paris-Saclay, LPTMS, CNRS, Univ. Paris-sud (France); Kirova, N. [Université Paris-Saclay, LPS, CNRS, Univ. Paris-sud (France)

    2016-03-15

    We consider a dynamical phase transition induced by a short optical pulse in a system prone to thermodynamical instability. We address the case of pumping to excitons whose density contributes directly to the order parameter. To describe both thermodynamic and dynamic effects on equal footing, we adopt a view of the excitonic insulator for the phase transition and suggest a formation of the Bose condensate for the pumped excitons. The work is motivated by experiments in donor–acceptor organic compounds with a neutral- ionic phase transition coupled to the spontaneous lattice dimerization and to charge transfer excitons. The double nature of the ensemble of excitons leads to an intricate time evolution, in particular, to macroscopic quantum oscillations from the interference between the Bose condensate of excitons and the ground state of the excitonic insulator. The coupling of excitons and the order parameter also leads to self-trapping of their wave function, akin to self-focusing in optics. The locally enhanced density of excitons can surpass a critical value to trigger the phase transformation, even if the mean density is below the required threshold. The system is stratified in domains that evolve through dynamical phase transitions and sequences of merging. The new circumstances in experiments and theory bring to life, once again, some remarkable inventions made by L.V. Keldysh.

  20. The excitonic insulator route through a dynamical phase transition induced by an optical pulse

    Science.gov (United States)

    Brazovskii, S.; Kirova, N.

    2016-03-01

    We consider a dynamical phase transition induced by a short optical pulse in a system prone to thermodynamical instability. We address the case of pumping to excitons whose density contributes directly to the order parameter. To describe both thermodynamic and dynamic effects on equal footing, we adopt a view of the excitonic insulator for the phase transition and suggest a formation of the Bose condensate for the pumped excitons. The work is motivated by experiments in donor-acceptor organic compounds with a neutral- ionic phase transition coupled to the spontaneous lattice dimerization and to charge transfer excitons. The double nature of the ensemble of excitons leads to an intricate time evolution, in particular, to macroscopic quantum oscillations from the interference between the Bose condensate of excitons and the ground state of the excitonic insulator. The coupling of excitons and the order parameter also leads to self-trapping of their wave function, akin to self-focusing in optics. The locally enhanced density of excitons can surpass a critical value to trigger the phase transformation, even if the mean density is below the required threshold. The system is stratified in domains that evolve through dynamical phase transitions and sequences of merging. The new circumstances in experiments and theory bring to life, once again, some remarkable inventions made by L.V. Keldysh.

  1. Tailorable Exciton Transport in Doped Peptide–Amphiphile Assemblies

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, Lee A. [Center; Sykes, Matthew E. [Center; Wu, Yimin A. [Center; Schaller, Richard D. [Center; Department; Wiederrecht, Gary P. [Center; Fry, H. Christopher [Center

    2017-08-29

    Light-harvesting biomaterials are an attractive target in photovoltaics, photocatalysis, and artificial photosynthesis. Through peptide self-assembly, complex nanostructures can be engineered to study the role of chromophore organization during light absorption and energy transport. To this end, we demonstrate the one-dimensional transport of excitons along naturally occurring, light-harvesting, Zn-protoporphyrin IX chromophores within self-assembled peptide-amphiphile nanofibers. The internal structure of the nanofibers induces packing of the porphyrins into linear chains. We find that this peptide assembly can enable long-range exciton diffusion, yet it also induces the formation of excimers between adjacent molecules, which serve as exciton traps. Electronic coupling between neighboring porphyrin molecules is confirmed by various spectroscopic methods. The exciton diffusion process is then probed through transient photoluminescence and absorption measurements and fit to a model for one-dimensional hopping. Because excimer formation impedes exciton hopping, increasing the interchromophore spacing allows for improved diffusivity, which we control through porphyrin doping levels. We show that diffusion lengths of over 60 nm are possible at low porphyrin doping, representing an order of magnitude improvement over the highest doping fractions.

  2. Effect of localized surface-plasmon mode on exciton transport and radiation emission in carbon nanotubes.

    Science.gov (United States)

    Roslyak, Oleksiy; Cherqui, Charles; Dunlap, David H; Piryatinski, Andrei

    2014-07-17

    We report on a general theoretical approach to study exciton transport and emission in a single-walled carbon nanotube (SWNT) in the presence of a localized surface-plasmon (SP) mode within a metal nanoparticle interacting via near-field coupling. We derive a set of quantum mechanical equations of motion and approximate rate equations that account for the exciton, SP, and the environmental degrees of freedom. The material equations are complemented by an expression for the radiated power that depends on the exciton and SP populations and coherences, allowing for an examination of the angular distribution of the emitted radiation that would be measured in experiment. Numerical simulations for a (6,5) SWNT and cone-shaped Ag metal tip (MT) have been performed using this methodology. Comparison with physical parameters shows that the near-field interaction between the exciton-SP occurs in a weak coupling regime, with the diffusion processes being much faster than the exciton-SP population exchange. In such a case, the effect of the exciton population transfer to the MT with its subsequent dissipation (i.e., the Förster energy transfer) is to modify the exciton steady state distribution while reducing the equilibration time for excitons to reach a steady sate distribution. We find that the radiation distribution is dominated by SP emission for a SWNT-MT separation of a few tens of nanometers due to the fast SP emission rate, whereas the exciton-SP coherences can cause its rotation.

  3. Connecting Galaxies, Halos, and Star Formation Rates Across Cosmic Time

    Energy Technology Data Exchange (ETDEWEB)

    Conroy, Charlie; Wechsler, Risa H.

    2008-06-02

    A simple, observationally-motivated model is presented for understanding how halo masses, galaxy stellar masses, and star formation rates are related, and how these relations evolve with time. The relation between halo mass and galaxy stellar mass is determined by matching the observed spatial abundance of galaxies to the expected spatial abundance of halos at multiple epochs--i.e. more massive galaxies are assigned to more massive halos at each epoch. This 'abundance matching' technique has been shown previously to reproduce the observed luminosity- and scale-dependence of galaxy clustering over a range of epochs. Halos at different epochs are connected by halo mass accretion histories estimated from N-body simulations. The halo-galaxy connection at fixed epochs in conjunction with the connection between halos across time provides a connection between observed galaxies across time. With approximations for the impact of merging and accretion on the growth of galaxies, one can then directly infer the star formation histories of galaxies as a function of stellar and halo mass. This model is tuned to match both the observed evolution of the stellar mass function and the normalization of the observed star formation rate--stellar mass relation to z {approx} 1. The data demands, for example, that the star formation rate density is dominated by galaxies with M{sub star} {approx} 10{sup 10.0-10.5} M{sub {circle_dot}} from 0 < z < 1, and that such galaxies over these epochs reside in halos with M{sub vir} {approx} 10{sup 11.5-12.5} M{sub {circle_dot}}. The star formation rate--halo mass relation is approximately Gaussian over the range 0 < z < 1 with a mildly evolving mean and normalization. This model is then used to shed light on a number of issues, including (1) a clarification of 'downsizing', (2) the lack of a sharp characteristic halo mass at which star formation is truncated, and (3) the dominance of star formation over merging to the stellar

  4. The creation of defects in ammonium halides by excitons

    International Nuclear Information System (INIS)

    Kim, L.M.

    2002-01-01

    The ammonium halides crystals and alkali halides crystals are analogous by kind chemical bonds and crystalline lattices. The anionic sublattice is identical in this crystals. It is known the main mechanism of defect creation by irradiation is radiationless decay of excitons in alkali halides crystals. The F-, H-centers are formation in this processes. However, F, H-centres are not detected in ammonium halides. The goal of this work is investigation the creation of defects in ammonium halides by excitons. We established that excitons in ammonium chlorides and bromides are similar to excitons in alkali halides. It is known excitons are self-trapped and have identical parameters of the exciton-phonon interaction in both kind crystals. It is supposed, that processes of radiationless disintegration of excitons are identical in ammonium and alkali halides. It is necessary to understand why F-, H-centers are absent in ammonium halides. V k -centres are created by the excitation of the ammonium halides crystals in the absorption band of excitons. It was established by thermoluminescence and spectrums of absorption. The V k -centers begin to migrate at 110-120 K in ammonium chlorides and bromides. The curve of thermoluminescence have peak with maximum at this temperatures. It is known V k -centers in ammonium chlorides have the absorption band at 380 nm. We discovered this absorption band after irradiation of crystals by ultra-violet. In alkali halides F-center is anionic vacancy with electron. The wave function of electron are spread ed at the cations around anionic vacancy. We established the cation NH 4 + in ammonium halides can to capture electron. The ion NH 4 2+ is unsteady. It is disintegrated to NH 3 + and H + . We suppose that excitons in ammonium and alkali halides are disintegrated identically. When cation NH 4 + capture electron, in the anionic sublattice the configuration are created in a direction (100) The indicated configuration is unsteady in relation to a

  5. Scaling laws of Rydberg excitons

    Science.gov (United States)

    Heckötter, J.; Freitag, M.; Fröhlich, D.; Aßmann, M.; Bayer, M.; Semina, M. A.; Glazov, M. M.

    2017-09-01

    Rydberg atoms have attracted considerable interest due to their huge interaction among each other and with external fields. They demonstrate characteristic scaling laws in dependence on the principal quantum number n for features such as the magnetic field for level crossing or the electric field of dissociation. Recently, the observation of excitons in highly excited states has allowed studying Rydberg physics in cuprous oxide crystals. Fundamentally different insights may be expected for Rydberg excitons, as the crystal environment and associated symmetry reduction compared to vacuum give not only optical access to many more states within an exciton multiplet but also extend the Hamiltonian for describing the exciton beyond the hydrogen model. Here we study experimentally and theoretically the scaling of several parameters of Rydberg excitons with n , for some of which we indeed find laws different from those of atoms. For others we find identical scaling laws with n , even though their origin may be distinctly different from the atomic case. At zero field the energy splitting of a particular multiplet n scales as n-3 due to crystal-specific terms in the Hamiltonian, e.g., from the valence band structure. From absorption spectra in magnetic field we find for the first crossing of levels with adjacent principal quantum numbers a Br∝n-4 dependence of the resonance field strength, Br, due to the dominant paramagnetic term unlike for atoms for which the diamagnetic contribution is decisive, resulting in a Br∝n-6 dependence. By contrast, the resonance electric field strength shows a scaling as Er∝n-5 as for Rydberg atoms. Also similar to atoms with the exception of hydrogen we observe anticrossings between states belonging to multiplets with different principal quantum numbers at these resonances. The energy splittings at the avoided crossings scale roughly as n-4, again due to crystal specific features in the exciton Hamiltonian. The data also allow us to

  6. Rate of star formation in normal disk galaxies

    Energy Technology Data Exchange (ETDEWEB)

    Kennicutt, R.C. Jr.

    1983-09-01

    Photometry of the integrated H..cap alpha.. emission in a large sample of field spiral and irregular galaxies has been used to obtain quantitative estimates of the total star formation rate (SFR) in the galaxies. The photoionization properties of a stellar population have been modeled for a variety of choices for the initial mass function (IMF). The observed UBV colors and H..cap alpha.. emission equivalent widths place tight constraints on the slope of the IMF between 1 M /sub sun/ and 50 M /sub sun/ in the galaxies; excellent agreement with the observed galaxy colors and H..cap alpha.. emission is obtained with models using an IMF slope close to Salpeter's original value. The properties of late-type galaxies are not well reproduced by the Miller-Scalo solar neighborhood IMF. The extinction-corrected star formation rates are large, as high as 20 M /sub sun/ yr/sup -1/ in giant Sc galaxies (H/sub 0/ = 50 km s/sup -1/ Mpc/sup -1/). The current rates in late-type galaxies are comparable to the past rates averaged over the age of the disk; late-type disk galaxies have evolved at a nearly constant rate, confirming earlier models by Searle, Sargent, and Bagnuolo. Little evidence is found for a strong correlation between the SFR and average gas density; if the SFR proportional rho/sup n/, then the exponent n must be much less than 1, corroborating earlier studies of star formation in the solar neighborhood by Miller, Scalo, and Twarog. Comparison of the present SFRs with the remaining supply of interstellar gas yields consumption time scales of only a few times 10/sup 9/ years in most cases, in agreement with the model estimates of Larson, Tinsley, and Caldwell.

  7. Bone Formation Rate in Experimental Disuse Osteoporosis in Monkeys

    Science.gov (United States)

    Cann, Christopher; Young, Donald R.

    1976-01-01

    Specific mechanisms underlying weightless and hypodynamic bone loss are obscure. A principal relationship which must be affected is the balance between bone formation and bone resorption rates. In order to better define the influence of those parameters on bone loss, and also to develop measurements in other species as a useful adjunct to human research, studies were undertaken with experimental monkeys. Tests were conducted with a total of 6 adult male monkeys, weighing 10-13 kg, and approximately 10-12 yrs. of age to evaluate specifically bone formation rate during the development of disuse osteoporosis and osteopenia. Three animals were restrained in a semi-recumbent position for six months; three animals served as normal caged controls. Food intake (Purina) was held relatively constant at 200g/day for each animal. Using a Norland Bone Mineral Analyzer, bone mineral losses of 3.5 to 6% were seen in the mid-shaft of the tibia and in the distal radius. Bone loss was confirmed radiographically, with observation of thinning of the proximal tibial cortex and trabeculae in the calcaneus. Bone formation rate was determined using standard Ca-47 kinetics under metabolic balance conditions. After six months of restraint, accretion was 7.2-13.2 mg Ca/kg/day, compared to 3.2-4.1 mg Ca/kg/day in caged controls and 3-8 mg Ca/kg/day in normal adult humans. Fecal and urine calcium was 25-40% higher in restrained animals than in controls. Dietary calcium absorption decreases during restraint, and calcium turnover increases, implying a rise in bone resorption rate concommitant with the observed rise in bone accretion rate. Further studies dealing specifically with bone resorption are underway to define this more fully.

  8. Singlet Exciton Lifetimes in Conjugated Polymer Films for Organic Solar Cells

    KAUST Repository

    Dimitrov, Stoichko

    2016-01-13

    The lifetime of singlet excitons in conjugated polymer films is a key factor taken into account during organic solar cell device optimization. It determines the singlet exciton diffusion lengths in polymer films and has a direct impact on the photocurrent generation by organic solar cell devices. However, very little is known about the material properties controlling the lifetimes of singlet excitons, with most of our knowledge originating from studies of small organic molecules. Herein, we provide a brief summary of the nature of the excited states in conjugated polymer films and then present an analysis of the singlet exciton lifetimes of 16 semiconducting polymers. The exciton lifetimes of seven of the studied polymers were measured using ultrafast transient absorption spectroscopy and compared to the lifetimes of seven of the most common photoactive polymers found in the literature. A plot of the logarithm of the rate of exciton decay vs. the polymer optical bandgap reveals a medium correlation between lifetime and bandgap, thus suggesting that the Energy Gap Law may be valid for these systems. This therefore suggests that small bandgap polymers can suffer from short exciton lifetimes, which may limit their performance in organic solar cell devices. In addition, the impact of film crystallinity on the exciton lifetime was assessed for a small bandgap diketopyrrolopyrrole co-polymer. It is observed that the increase of polymer film crystallinity leads to reduction in exciton lifetime and optical bandgap again in agreement with the Energy Gap Law.

  9. Plasmonic, excitonic and exciton-plasmonic photoinduced nanocomposites

    Science.gov (United States)

    Bityurin, N.; Ermolaev, N.; Smirnov, A. A.; Afanasiev, A.; Agareva, N.; Koryukina, T.; Bredikhin, V.; Kamensky, V.; Pikulin, A.; Sapogova, N.

    2016-03-01

    UV irradiation of materials consisting of a polymer matrix that possesses precursors of different kinds can result in creation of nanoparticles within the irradiated domains. Such photoinduced nanocomposites are promising for photonic applications due to the strong alteration of their optical properties compared to initial non-irradiated materials. We report our results on the synthesis and investigation of plasmonic, excitonic and exciton-plasmonic photoinduced nanocomposites. Plasmonic nanocomposites contain metal nanoparticles of noble metals with a pronounced plasmon resonance. Excitonic nanocomposites possess semiconductor nanoclusters (quantum dots). We consider the CdS-Au pair because the luminescent band of CdS nanoparticles enters the plasmon resonance band of gold nanoparticles. The obtaining of such particles within the same composite materials is promising for the creation of media with exciton-plasmon resonance. We demonstrate that it is possible to choose appropriate precursor species to obtain the initially transparent poly(methyl methacrylate) (PMMA) films containing both types of these molecules either separately or together. Proper irradiation of these materials by a light-emitting diode operating at the wavelength of 365 nm provides material alteration demonstrating light-induced optical absorption and photoluminescent properties typical for the corresponding nanoparticles. Thus, an exciton-plasmonic photoinduced nanocomposite is obtained. It is important that here we use the precursors that are different from those usually employed.

  10. Spectral properties of excitons in the bilayer graphene

    Science.gov (United States)

    Apinyan, V.; Kopeć, T. K.

    2018-01-01

    In this paper, we consider the spectral properties of the bilayer graphene with the local excitonic pairing interaction between the electrons and holes. We consider the generalized Hubbard model, which includes both intralayer and interlayer Coulomb interaction parameters. The solution of the excitonic gap parameter is used to calculate the electronic band structure, single-particle spectral functions, the hybridization gap, and the excitonic coherence length in the bilayer graphene. We show that the local interlayer Coulomb interaction is responsible for the semimetal-semiconductor transition in the double layer system, and we calculate the hybridization gap in the band structure above the critical interaction value. The formation of the excitonic band gap is reported as the threshold process and the momentum distribution functions have been calculated numerically. We show that in the weak coupling limit the system is governed by the Bardeen-Cooper-Schrieffer (BCS)-like pairing state. Contrary, in the strong coupling limit the excitonic condensate states appear in the semiconducting phase, by forming the Dirac's pockets in the reciprocal space.

  11. Probing long-lived dark excitons in self-assembled quantum dots

    DEFF Research Database (Denmark)

    Johansen, Jeppe; Julsgaard, Brian; Stobbe, Søren

    2010-01-01

    Long-lived dark exciton states are formed in self-assembled quantum dots due to the combination of the angular momentum of electrons and holes. The lifetime of dark excitons are determined by spin-flip processes that transfer dark excitons into radiative bright excitons. We employ time......-resolved spontaneous emission measurements in a modified local density of optical states to unambiguously record the spin-flip rate. Pronounced variations in the spin-flip rate with the quantum dot emission energy are observed demonstrating that the exciton storage time can be extended by controlling the quantum dot...... size. The energy dependence is compared to a recent model from the literature, in which the spin flip is due to the combined action of short-range exchange interaction and acoustic phonons. We furthermore observe a pronounced enhancement of the spin-flip rate close to semiconductor-air interfaces...

  12. Charge recombination and exciton annihilation reactions in conjugated polymer blends.

    Science.gov (United States)

    Howard, Ian A; Hodgkiss, Justin M; Zhang, Xinping; Kirov, Kiril R; Bronstein, Hugo A; Williams, Charlotte K; Friend, Richard H; Westenhoff, Sebastian; Greenham, Neil C

    2010-01-13

    Bimolecular interactions between excitations in conjugated polymer thin films are important because they influence the efficiency of many optoelectronic devices that require high excitation densities. Using time-resolved optical spectroscopy, we measure the bimolecular interactions of charges, singlet excitons, and triplet excitons in intimately mixed polyfluorene blends with band-edge offsets optimized for photoinduced electron transfer. Bimolecular charge recombination and triplet-triplet annihilation are negligible, but exciton-charge interactions are efficient. The annihilation of singlet excitons by charges occurs on picosecond time-scales and reaches a rate equivalent to that of charge transfer. Triplet exciton annihilation by charges occurs on nanosecond time-scales. The surprising absence of nongeminate charge recombination is shown to be due to the limited mobility of charge carriers at the heterojunction. Therefore, extremely high densities of charge pairs can be maintained in the blend. The absence of triplet-triplet annihilation is a consequence of restricted triplet diffusion in the blend morphology. We suggest that the rate and nature of bimolecular interactions are determined by the stochastic excitation distribution in the polymer blend and the limited connectivity between the polymer domains. A model based on these assumptions quantitatively explains the effects. Our findings provide a comprehensive framework for understanding bimolecular recombination and annihilation processes in nanostructured materials.

  13. Strong blue excitonic emission from CdS nanocrystallites prepared by LB technique

    International Nuclear Information System (INIS)

    Mandal, P.; Talwar, S.S.; Major, S.S.; Srinivasa, R.S.

    2009-01-01

    CdS nanocrystallites formed in ordered fatty acid LB multilayers exhibited strong surface states emission ∝550 nm and weak excitonic emission ∝400 nm. Treatment with aqueous CdCl 2 resulted in the suppression of surface states emission and enhancement of the blue excitonic emission. Subsequent annealing in air at 200 C caused an order of magnitude enhancement of excitonic emission. The growth of nanocrystallites during annealing as seen from the red-shift of excitonic absorption and emission is suppressed by the CdCl 2 treatment. The hindered growth of nanocrystallites, the significant enhancement of excitonic emission from CdS, and the suppression of surface states emission are attributed to surface passivation of CdS nanocrystallites by surface oxide formation. (orig.)

  14. LOCAL ENERGETIC DISORDER IN MOLECULAR AGGREGATES PROBED BY THE ONE-EXCITON TO 2-EXCITON TRANSITION

    NARCIS (Netherlands)

    DURRANT, [No Value; KNOESTER, J; WIERSMA, DA

    1994-01-01

    We demonstrate a novel approach to probing the magnitude and degree of spatial correlation of local (molecular or atomic) energetic disorder in delocalized exciton systems. The approach is based on measuring the correlation between the ground state to one-exciton and the one-exciton to two-exciton

  15. Bose-Einstein condensation and superfluidity of dipolar excitons in a phosphorene double layer

    Science.gov (United States)

    Berman, Oleg L.; Gumbs, Godfrey; Kezerashvili, Roman Ya.

    2017-07-01

    We study the formation of dipolar excitons and their superfluidity in a phosphorene double layer. The analytical expressions for the single dipolar exciton energy spectrum and wave function are obtained. It is predicted that a weakly interacting gas of dipolar excitons in a double layer of black phosphorus exhibits superfluidity due to the dipole-dipole repulsion between the dipolar excitons. In calculations are employed the Keldysh and Coulomb potentials for the interaction between the charge carriers to analyze the influence of the screening effects on the studied phenomena. It is shown that the critical velocity of superfluidity, the spectrum of collective excitations, concentrations of the superfluid and normal component, and mean-field critical temperature for superfluidity are anisotropic and demonstrate the dependence on the direction of motion of dipolar excitons. The critical temperature for superfluidity increases if the exciton concentration and the interlayer separation increase. It is shown that the dipolar exciton binding energy and mean-field critical temperature for superfluidity are sensitive to the electron and hole effective masses. The proposed experiment to observe a directional superfluidity of excitons is addressed.

  16. Binding energy of the barbell exciton

    Science.gov (United States)

    Peeters, F. M.; Golub, J. E.

    1991-02-01

    The exciton binding energy in asymmetric coupled double quantum wells is calculated. As the system is electrically tuned from type I to type II, the exciton binding energy decreases from that of a two-dimensional exciton to the binding energy of a spatially separated electron-hole pair, i.e., the barbell exciton.$-- We compare our theoretical results with a recent experiment and find good agreement.

  17. Calibration of Star Formation Rates Across the Electromagnetic Spectrum

    Science.gov (United States)

    Cardiff, Ann H.

    2011-01-01

    Measuring and mapping star-forming activity in galaxies is a key element for our understanding of their broad- band spectra, and their structure and evolution in our local, as well as the high-redshift Universe. The main tool we use for these measurements is the observed luminosity in various spectral lines and/or continuum bands. However, the available star-formation rate (SFR) indicators are often discrepant and subject to physical biases and calibration uncertainties. We are organizing a special session at the 2012 IAU General Assembly in Beijing, China (August 20-31, 2012) in order to bring together theoreticians and observers working in different contexts of star-formation to discuss the status of current SFR indicators, to identify open issues and to define a strategic framework for their resolution. The is an ideal time to synthesize information from the current golden era of space astrophysics and still have influence on the upcoming missions that will broaden our view of star-formation. We will be including high-energy constraints on SFR in the program and encourage participation from the high energy astrophysics community.

  18. Exciton-dopant and exciton-charge interactions in electronically doped OLEDs

    International Nuclear Information System (INIS)

    Williams, Christopher; Lee, Sergey; Ferraris, John; Zakhidov, A. Anvar

    2004-01-01

    The electronic dopants, like tetrafluorocyanoquinodimethane (F 4 -TCNQ) molecules, used for p-doping of hole transport layers in organic light-emitting diodes (OLEDs) are found to quench the electroluminescence (EL) if they diffuse into the emissive layer. We observed EL quenching in OLED with F 4 -TCNQ doped N,N'-diphenyl-N'N'-bis(1-naphthyl)-1,1'-biphenyl-4,4'-diamine hole transport layer at large dopant concentrations, >5%. To separate the effects of exciton-dopant quenching, from exciton-polaron quenching we have intentionally doped the emissive layer of (8-tris-hydroxyquinoline) with three acceptors (A) of different electron affinities: F 4 -TCNQ, TCNQ, and C 60 , and found that C 60 is the strongest EL-quencher, while F 4 -TCNQ is the weakest, contrary to intuitive expectations. The new effects of charge transfer and usually considered energy transfer from exciton to neutral (A) and charged acceptors (A - ) are compared as channels for non-radiative Ex-A decay. At high current loads the EL quenching is observed, which is due to decay of Ex on free charge carriers, hole polarons P + . We consider contributions to Ex-P + interaction by short-range charge transfer and describe the structure of microscopic charge transfer (CT)-processes responsible for it. The formation of metastable states of 'charged excitons' (predicted and studied by Agranovich et al. Chem. Phys. 272 (2001) 159) by electron transfer from a P to an Ex is pointed out, and ways to suppress non-radiative Ex-P decay are suggested

  19. α-helix formation rate of oligopeptides at subzero temperatures

    Science.gov (United States)

    Qin, Zhi-jie; Shimizu, Akio; Li, Jinsong; Ikeguchi, Masamichi; Shinjo, Masaji; Kihara, Hiroshi

    2014-01-01

    In 1999, Clarke et al. ((1999) Proc. Natl. Acad. Sci. USA 96, 7232–7237) reported that the nucleation rate of α-helix of oligopeptide AK16 is as slow as 60 ms. In the present study, we measured the nucleation rate of oligopeptide, C17 (DLTDDIMCVKKILDKVG, corresponding to α-helical region of 84th to 100th amino acids of bovine α-lactalbumin) using the same method as Clarke et al. We found only initial bursts of the increase of α-helices at temperatures higher than −50°C in the presence of 70% methanol. The result with AK16 was the same as Clarke et al. reported. We also found that the folding rate of polyglutamic acid is too fast to be detected by the stopped-flow apparatus at 4°C. These results demonstrate that the α-helix formation rates in C17, AK16 and polyglutamic acid are shorter than the dead time of the stopped-flow apparatus (6 ms). PMID:27493493

  20. Correlation effect of Rabi oscillations of excitons in quantum dots

    International Nuclear Information System (INIS)

    Ishi-Hayase, J.; Akahane, K.; Yamamoto, Y.; Kujiraoka, M.; Ema, K.; Sasaki, M.

    2008-01-01

    We performed a transient four-wave mixing experiment on a strain-compensated InAs quantum dot (QD) ensemble over a wide range of excitation intensities. Under the resonant excitation of an exciton ground state, an extremely long dephasing time of 1 ns was found. By increasing the areas of the excitation pulses, Rabi oscillations of excitonic polarizations were clearly observed. The corresponding Rabi frequency is three orders of magnitude higher than the measured dephasing rate. For larger pulse areas, we found that the deviation of experimental data from two-level predictions became significant. The deviations cannot be explained by taking into account, as has been suggested in other research, excitation density-dependent dephasing or Hartree-Fock-type Coulomb interactions between excitons

  1. Energy transfer of excitons between quantum wells separated by a wide barrier

    International Nuclear Information System (INIS)

    Lyo, S. K.

    2000-01-01

    We present a microscopic theory of the excitonic Stokes and anti-Stokes energy-transfer mechanisms between two widely separated unequal quantum wells with a large energy mismatch (Δ) at low temperatures (T). Several important intrinsic energy-transfer mechanisms have been examined, including dipolar coupling, real and virtual photon-exchange coupling, and over-barrier ionization of the excitons via exciton-exciton Auger processes. The transfer rate is calculated as a function of T and the center-to-center distance d between the wells. The rates depend sensitively on T for plane-wave excitons. For localized excitons, the rates depend on T only through the T dependence of the exciton localization radius. For Stokes energy transfer, the dominant energy transfer occurs through a photon-exchange interaction, which enables the excitons from the higher-energy wells to decay into free electrons and holes in the lower-energy wells. The rate has a slow dependence on d, yielding reasonable agreement with recent data from GaAs/Al x Ga 1-x As quantum wells. The dipolar rate is about an order of magnitude smaller for large d (e.g., d=175Aa) with a stronger range dependence proportional to d -4 . However, the latter can be comparable to the radiative rate for small d (e.g., d≤80Aa). For anti-Stokes transfer through exchange-type (e.g., dipolar and photon-exchange) interactions, we show that thermal activation proportional to exp(-Δ/k B T) is essential for the transfer, contradicting a recent nonactivated result based on the Fo''rster-Dexter's spectral-overlap theory. Phonon-assisted transfer yields a negligibly small rate. On the other hand, energy transfer through over-barrier ionization of excitons via Auger processes yields a significantly larger nonactivated rate which is independent of d. The result is compared with recent data

  2. Entangled exciton states in quantum dot molecules

    Science.gov (United States)

    Bayer, Manfred

    2002-03-01

    Currently there is strong interest in quantum information processing(See, for example, The Physics of Quantum Information, eds. D. Bouwmeester, A. Ekert and A. Zeilinger (Springer, Berlin, 2000).) in a solid state environment. Many approaches mimic atomic physics concepts in which semiconductor quantum dots are implemented as artificial atoms. An essential building block of a quantum processor is a gate which entangles the states of two quantum bits. Recently a pair of vertically aligned quantum dots has been suggested as optically driven quantum gate(P. Hawrylak, S. Fafard, and Z. R. Wasilewski, Cond. Matter News 7, 16 (1999).)(M. Bayer, P. Hawrylak, K. Hinzer, S. Fafard, M. Korkusinski, Z.R. Wasilewski, O. Stern, and A. Forchel, Science 291, 451 (2001).): The quantum bits are individual carriers either on dot zero or dot one. The different dot indices play the same role as a "spin", therefore we call them "isospin". Quantum mechanical tunneling between the dots rotates the isospin and leads to superposition of these states. The quantum gate is built when two different particles, an electron and a hole, are created optically. The two particles form entangled isospin states. Here we present spectrocsopic studies of single self-assembled InAs/GaAs quantum dot molecules that support the feasibility of this proposal. The evolution of the excitonic recombination spectrum with varying separation between the dots allows us to demonstrate coherent tunneling of carriers across the separating barrier and the formation of entangled exciton states: Due to the coupling between the dots the exciton states show a splitting that increases with decreasing barrier width. For barrier widths below 5 nm it exceeds the thermal energy at room temperature. For a given barrier width, we find only small variations of the tunneling induced splitting demonstrating a good homogeneity within a molecule ensemble. The entanglement may be controlled by application of electromagnetic field. For

  3. Excitons and interconfigurational transitions in CaF{sub 2}:Yb{sup 2+} crystals

    Energy Technology Data Exchange (ETDEWEB)

    Hughes-Currie, Rosa B.; Salkeld, Alexander J. [Department of Physics and Astronomy, University of Canterbury, PB 4800, Christchurch 8140 (New Zealand); Ivanovskikh, Konstantin V. [ANK Service Ltd., PB 58, Novouralsk 624131, Sverdlovsk region (Russian Federation); Ural Federal University, 19 Mira st., Ekaterinburg 620002 (Russian Federation); Reid, Michael F., E-mail: mike.reid@canterbury.ac.nz [Department of Physics and Astronomy, University of Canterbury, PB 4800, Christchurch 8140 (New Zealand); MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Canterbury, PB 4800, Christchurch 8140 (New Zealand); Wells, Jon-Paul R. [Department of Physics and Astronomy, University of Canterbury, PB 4800, Christchurch 8140 (New Zealand); Reeves, Roger J. [Department of Physics and Astronomy, University of Canterbury, PB 4800, Christchurch 8140 (New Zealand); MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Canterbury, PB 4800, Christchurch 8140 (New Zealand)

    2015-02-15

    A time-resolved VUV spectroscopic study of emission and excitation spectra of CaF{sub 2}:Yb{sup 2+} has been performed to investigate excitation and relaxation mechanisms of both impurity-trapped excitons and intrinsic excitons in CaF{sub 2}. Host-to-impurity energy transfer mechanisms leading to formation of impurity-trapped excitons have been discussed. The change in free exciton excitation peak position with increasing lattice temperature has been measured and is well approximated by Viña's expression for the temperature shift of a semiconductor band gap. The 4f{sup 14}→4f{sup 13}5d CaF{sub 2}:Yb{sup 2+} absorption bands are successfully modeled with a semi-empirical effective Hamiltonian calculation. - Highlights: • We present VUV emission and excitation spectra of CaF{sub 2}:Yb{sup 2+}. • Formation of free excitons leads to emission from intrinsic and extrinsic excitons. • Temperature shifts of semiconductor band gaps apply to the intrinsic exciton peak. • 4f{sup 14}→4f{sup 13}5dYb{sup 2+} absorption is modeled by a semi-empirical Hamiltonian.

  4. Star formation rate in Holmberg IX dwarf galaxy

    Directory of Open Access Journals (Sweden)

    Anđelić M.M.

    2011-01-01

    Full Text Available In this paper we use previously determined Hα fluxes for dwarf galaxy Holmberg IX (Arbutina et al. 2009 to calculate star formation rate (SFR in this galaxy. We discuss possible contaminations of Hα flux and, for the first time, we take into account optical emission from supernova remnants (SNRs as a possible source of contamination of Hα flux. Derived SFR for Holmberg IX is 3:4 x 10-4M.yr-1. Our value is lower then in previous studies, due to luminous shock-heated source M&H 9-10, possible hypernova remnant, which we excluded from the total Hα flux in our calculation of SFR.

  5. Binary interactions on the calibrations of star formation rate

    Science.gov (United States)

    Zhang, Fenghui; Li, Lifang; Zhang, Yu; Kang, Xiaoyu; Han, Zhanwen

    2012-03-01

    Using the Yunnan evolutionary population synthesis (EPS) models with and without binary interactions, we present the luminosity of Hα recombination line (LHα), the luminosity of [O II] λ3727 forbidden line doublet (?), the ultraviolet (UV) fluxes at 1500 and 2800 Å (Li, UV) and far-infrared flux (LFIR) for burst, S0, Sa-Sd and Irr galaxies, and present the calibrations of star formation rate (SFR) in terms of these diagnostics. By comparison, we find that binary interactions lower the SFR versus LHα and SFR versus ? conversion factors by ˜0.2 dex. The main reason is that binary interactions raise the UV flux (shortwards of the Lyman limit) of the stellar population (SP) in the age range 6.7 Aarseth-Hurley, Kroupa-Tout-Gilmore and Miller-Scalo IMFs, partly caused by the difference in the IMF), respectively. At last, we give the conversion coefficients between SFR and these diagnostics for all models.

  6. Magnetic exciton dispersion in praseodymium

    DEFF Research Database (Denmark)

    Rainford, B. D.; Houmann, Jens Christian Gylden

    1971-01-01

    Measurements of the dispersion of magnetic excitons have been made in a single crystal of praseodymium metal using inelastic neutron scattering. A preliminary analysis of the data yields the first detailed information about the exchange interactions and the crystal field splittings in the light...

  7. Exciton size and quantum transport in nanoplatelets

    Energy Technology Data Exchange (ETDEWEB)

    Pelzer, Kenley M., E-mail: kpelzer@anl.gov; Gray, Stephen K. [Center for Nanoscale Materials, Argonne National Laboratory, 9700 Cass Ave., Argonne, Illinois 60439 (United States); Darling, Seth B. [Center for Nanoscale Materials, Argonne National Laboratory, 9700 Cass Ave., Argonne, Illinois 60439 (United States); Institute for Molecular Engineering, University of Chicago, 5747 S. Ellis Ave., Chicago, Illinois 60637 (United States); Schaller, Richard D. [Center for Nanoscale Materials, Argonne National Laboratory, 9700 Cass Ave., Argonne, Illinois 60439 (United States); Department of Chemistry, Northwestern University, 2145 Sheridan Rd., Evanston, Illinois 60208 (United States)

    2015-12-14

    Two-dimensional nanoplatelets (NPLs) are an exciting class of materials with promising optical and energy transport properties. The possibility of efficient energy transport between nanoplatelets raises questions regarding the nature of energy transfer in these thin, laterally extended systems. A challenge in understanding exciton transport is the uncertainty regarding the size of the exciton. Depending on the material and defects in the nanoplatelet, an exciton could plausibly extend over an entire plate or localize to a small region. The variation in possible exciton sizes raises the question how exciton size impacts the efficiency of transport between nanoplatelet structures. Here, we explore this issue using a quantum master equation approach. This method goes beyond the assumptions of Förster theory to allow for quantum mechanical effects that could increase energy transfer efficiency. The model is extremely flexible in describing different systems, allowing us to test the effect of varying the spatial extent of the exciton. We first discuss qualitative aspects of the relationship between exciton size and transport and then conduct simulations of exciton transport between NPLs for a range of exciton sizes and environmental conditions. Our results reveal that exciton size has a strong effect on energy transfer efficiency and suggest that manipulation of exciton size may be useful in designing NPLs for energy transport.

  8. Model of fragmentation of the exciton inner ring in semiconductor quantum wells

    Science.gov (United States)

    Chernyuk, A. A.; Sugakov, V. I.; Tomylko, V. V.

    2014-11-01

    The appearance of nonhomogeneous structures of the indirect exciton density distribution in the region of the quantum well (in the region of the inner ring) is explained. The structure (the fragmentation) occurs due to the exciton condensed phase formation because of the interaction between excitons. The formation of the struc-ture is related with the nonequalibrity of the system, which is caused by the exciton finite lifetime and the presence of the pumping. The structure emerges in the shape of a set of islands or circles of the condensed phase. The structure type depends on the pumping intensity, the size of the laser spot, and disappears with increasing the temperature. The merging of two structures, created by different laser spots, is investigated at decreasing the distance between the centers of the spots.

  9. CALIBRATING UV STAR FORMATION RATES FOR DWARF GALAXIES FROM STARBIRDS

    Energy Technology Data Exchange (ETDEWEB)

    McQuinn, Kristen B. W.; Skillman, Evan D.; Mitchell, Noah P. [Minnesota Institute for Astrophysics, University of Minnesota, 116 Church Street, S.E., Minneapolis, MN 55455 (United States); Dolphin, Andrew E., E-mail: kmcquinn@astro.umn.edu [Raytheon Company, 1151 E. Hermans Road, Tucson, AZ 85756 (United States)

    2015-08-01

    Integrating our knowledge of star formation (SF) traced by observations at different wavelengths is essential for correctly interpreting and comparing SF activity in a variety of systems and environments. This study compares extinction corrected integrated ultraviolet (UV) emission from resolved galaxies with color–magnitude diagram (CMD) based star formation rates (SFRs) derived from resolved stellar populations and CMD fitting techniques in 19 nearby starburst and post-starburst dwarf galaxies. The data sets are from the panchromatic Starburst Irregular Dwarf Survey and include deep legacy GALEX UV imaging, Hubble Space Telescope optical imaging, and Spitzer MIPS imaging. For the majority of the sample, the integrated near-UV fluxes predicted from the CMD-based SFRs—using four different models—agree with the measured, extinction corrected, integrated near-UV fluxes from GALEX images, but the far-UV (FUV) predicted fluxes do not. Furthermore, we find a systematic deviation between the SFRs based on integrated FUV luminosities and existing scaling relations, and the SFRs based on the resolved stellar populations. This offset is not driven by different SF timescales, variations in SFRs, UV attenuation, nor stochastic effects. This first comparison between CMD-based SFRs and an integrated FUV emission SFR indicator suggests that the most likely cause of the discrepancy is the theoretical FUV–SFR calibration from stellar evolutionary libraries and/or stellar atmospheric models. We present an empirical calibration of the FUV-based SFR relation for dwarf galaxies, with uncertainties, which is ∼53% larger than previous relations.

  10. Solution Phase Exciton Diffusion Dynamics of a Charge-Transfer Copolymer PTB7 and a Homopolymer P3HT

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Sung; Rolczynski, Brian S.; Xu, Tao; Yu, Luping; Chen, Lin X.

    2015-06-18

    Using ultrafast polarization-controlled transient absorption (TA) measurements, dynamics of the initial exciton states were investigated on the time scale of tens of femtoseconds to about 80 ps in two different types of conjugated polymers extensively used in active layers of organic photovoltaic devices. These polymers are poly(3-fluorothienothiophenebenzodithiophene) (PTB7) and poly-3-hexylthiophene (P3HT), which are charge-transfer polymers and homopolymers, respectively. In PTB7, the initial excitons with excess vibrational energy display two observable ultrafast time constants, corresponding to coherent exciton diffusion before the vibrational relaxation, and followed by incoherent exciton diffusion processes to a neighboring local state after the vibrational relaxation. In contrast, P3HT shows only one exciton diffusion or conformational motion time constant of 34 ps, even though its exciton decay kinetics are multiexponential. Based on the experimental results, an exciton dynamics mechanism is conceived taking into account the excitation energy and structural dependence in coherent and incoherent exciton diffusion processes, as well as other possible deactivation processes including the formation of the pseudo-charge-transfer and charge separate states, as well as interchain exciton hopping or coherent diffusion.

  11. Colloquium: Excitons in atomically thin transition metal dichalcogenides

    Science.gov (United States)

    Wang, Gang; Chernikov, Alexey; Glazov, Mikhail M.; Heinz, Tony F.; Marie, Xavier; Amand, Thierry; Urbaszek, Bernhard

    2018-04-01

    Atomically thin materials such as graphene and monolayer transition metal dichalcogenides (TMDs) exhibit remarkable physical properties resulting from their reduced dimensionality and crystal symmetry. The family of semiconducting transition metal dichalcogenides is an especially promising platform for fundamental studies of two-dimensional (2D) systems, with potential applications in optoelectronics and valleytronics due to their direct band gap in the monolayer limit and highly efficient light-matter coupling. A crystal lattice with broken inversion symmetry combined with strong spin-orbit interactions leads to a unique combination of the spin and valley degrees of freedom. In addition, the 2D character of the monolayers and weak dielectric screening from the environment yield a significant enhancement of the Coulomb interaction. The resulting formation of bound electron-hole pairs, or excitons, dominates the optical and spin properties of the material. Here recent progress in understanding of the excitonic properties in monolayer TMDs is reviewed and future challenges are laid out. Discussed are the consequences of the strong direct and exchange Coulomb interaction, exciton light-matter coupling, and influence of finite carrier and electron-hole pair densities on the exciton properties in TMDs. Finally, the impact on valley polarization is described and the tuning of the energies and polarization observed in applied electric and magnetic fields is summarized.

  12. Experimental particle formation rates spanning tropospheric sulfuric acid and ammonia abundances, ion production rates, and temperatures

    CERN Document Server

    Kürten, Andreas; Almeida, Joao; Kupiainen-Määttä, Oona; Dunne, Eimear M.; Duplissy, Jonathan; Williamson, Christina; Barmet, Peter; Breitenlechner, Martin; Dommen, Josef; Donahue, Neil M.; Flagan, Richard C.; Franchin, Alessandro; Gordon, Hamish; Hakala, Jani; Hansel, Armin; Heinritzi, Martin; Ickes, Luisa; Jokinen, Tuija; Kangasluoma, Juha; Kim, Jaeseok; Kirkby, Jasper; Kupc, Agnieszka; Lehtipalo, Katrianne; Leiminger, Markus; Makhmutov, Vladimir; Onnela, Antti; Ortega, Ismael K.; Petäjä, Tuukka; Praplan, Arnaud P.; Riccobono, Francesco; Rissanen, Matti P.; Rondo, Linda; Schnitzhofer, Ralf; Schobesberger, Siegfried; Smith, James N.; Steiner, Gerhard; Stozhkov, Yuri; Tomé, António; Tröstl, Jasmin; Tsagkogeorgas, Georgios; Wagner, Paul E.; Wimmer, Daniela; Ye, Penglin; Baltensperger, Urs; Carslaw, Ken; Kulmala, Markku; Curtius, Joachim

    2016-01-01

    Binary nucleation of sulfuric acid and water as well as ternary nucleation involving ammonia arethought to be the dominant processes responsible for new particle formation (NPF) in the cold temperaturesof the middle and upper troposphere. Ions are also thought to be important for particle nucleation inthese regions. However, global models presently lack experimentally measured NPF rates under controlledlaboratory conditions and so at present must rely on theoretical or empirical parameterizations. Here withdata obtained in the European Organization for Nuclear Research CLOUD (Cosmics Leaving OUtdoor Droplets)chamber, we present the first experimental survey of NPF rates spanning free tropospheric conditions. Theconditions during nucleation cover a temperature range from 208 to 298 K, sulfuric acid concentrationsbet ween 5 × 105and 1 × 109cm3, and ammonia mixing ratios from zero added ammonia, i.e., nominally purebinary, to a maximum of ~1400 parts per trillion by volume (pptv). We performed nucleation s...

  13. Exciton Binding Energy of Monolayer WS2

    Science.gov (United States)

    Zhu, Bairen; Chen, Xi; Cui, Xiaodong

    2015-03-01

    The optical properties of monolayer transition metal dichalcogenides (TMDC) feature prominent excitonic natures. Here we report an experimental approach to measuring the exciton binding energy of monolayer WS2 with linear differential transmission spectroscopy and two-photon photoluminescence excitation spectroscopy (TP-PLE). TP-PLE measurements show the exciton binding energy of 0.71 +/- 0.01 eV around K valley in the Brillouin zone.

  14. Exciton liquid in coupled quantum wells.

    Science.gov (United States)

    Stern, Michael; Umansky, Vladimir; Bar-Joseph, Israel

    2014-01-03

    Excitons in semiconductors may form correlated phases at low temperatures. We report the observation of an exciton liquid in gallium arsenide/aluminum gallium arsenide-coupled quantum wells. Above a critical density and below a critical temperature, the photogenerated electrons and holes separate into two phases: an electron-hole plasma and an exciton liquid, with a clear sharp boundary between them. The two phases are characterized by distinct photoluminescence spectra and by different electrical conductance. The liquid phase is formed by the repulsive interaction between the dipolar excitons and exhibits a short-range order, which is manifested in the photoluminescence line shape.

  15. Exciton circular dichroism in channelrhodopsin.

    Science.gov (United States)

    Pescitelli, Gennaro; Kato, Hideaki E; Oishi, Satomi; Ito, Jumpei; Maturana, Andrés Daniel; Nureki, Osamu; Woody, Robert W

    2014-10-16

    Channelrhodopsins (ChRs) are of great interest currently because of their important applications in optogenetics, the photostimulation of neurons. The absorption and circular dichroism (CD) spectra of C1C2, a chimera of ChR1 and ChR2 of Chlamydomonas reinhardtii, have been studied experimentally and theoretically. The visible absorption spectrum of C1C2 shows vibronic fine structure in the 470 nm band, consistent with the relatively nonpolar binding site. The CD spectrum has a negative band at 492 nm (Δε(max) = -6.17 M(-1) cm(-1)) and a positive band at 434 nm (Δε(max) = +6.65 M(-1) cm(-1)), indicating exciton coupling within the C1C2 dimer. Time-dependent density functional theory (TDDFT) calculations are reported for three models of the C1C2 chromophore: (1) the isolated protonated retinal Schiff base (retPSB); (2) an ion pair, including the retPSB chromophore, two carboxylate side chains (Asp 292, Glu 162), modeled by acetate, and a water molecule; and (3) a hybrid quantum mechanical/molecular mechanical (QM/MM) model depicting the binding pocket, in which the QM part consists of the same ion pair as that in (2) and the MM part consists of the protein residues surrounding the ion pair within 10 Å. For each of these models, the CD of both the monomer and the dimer was calculated with TDDFT. For the dimer, DeVoe polarizability theory and exciton calculations were also performed. The exciton calculations were supplemented by calculations of the coupling of the retinal transition with aromatic and peptide group transitions. For the dimer, all three methods and three models give a long-wavelength C2-axis-polarized band, negative in CD, and a short-wavelength band polarized perpendicular to the C2 axis with positive CD, differing in wavelength by 1-5 nm. Only the retPSB model gives an exciton couplet that agrees qualitatively with experiment. The other two models give a predominantly or solely positive band. We further analyze an N-terminal truncated mutant

  16. Continuum contribution to excitonic four-wave mixing due to interaction-induced nonlinearities: A numerical study

    DEFF Research Database (Denmark)

    Sayed, Karim El; Birkedal, Dan; Vadim, Lyssenko

    1997-01-01

    of the exciton line in the FWM spectrum and in the decay of the time-resolved FWM signal in real time are governed by the intrinsic excitonic dephasing rate. It is shown that for pulse durations of similar to 100 fs (for GaAs quantum wells) this behavior can be explained as the influence of the Coulomb exchange...

  17. Radiationless decay, fission and fusion of excitons in irradiated molecular crystals

    International Nuclear Information System (INIS)

    Klein, Gerard.

    1977-01-01

    The creation and evolution of excited states in ionizing particle tracks were investigated. The passage of high energy ionizing particles in molecular crystals results in the formation of highly excited states which energy is generally above the molecular ionization potential. The theory of non radiative transitions, which describes the transitions from the highly excited states to the lowest singlet and triplet excitons S 1 and T 1 is developed. Among these non radiative transitions, the fission of singlet excitons into two singlet or triplet excitons of lower energies is studied experimentally. These results and a kinematics study of the S 1 and T 1 excitons in ionizing particle tracks were used to get a complete description of the scintillation. These results are in good agreement with the experimental measurements on the scintillation [fr

  18. The microstructure of foreign exchange rate and foreign exchange rate formation

    Directory of Open Access Journals (Sweden)

    Vučković Vladimir

    2005-01-01

    Full Text Available The subject matter of market microstructure analysis are processes through which investor activities are transferred to quantities and prices. This direction indicates the fact that has been unjustifiably neglected in fundamental theories – foreign exchange rate results from the interactions between market participants. Spot foreign exchange market can best be described as a decentralised market with a number of dealers. There is no organised physical place (stock exchange where dealers meet their clients nor is there an electronic system which enables quotations of all dealers in a currency market to be simultaneously shown on the screen. The theory of order flows has resulted from the answer to the essential question of market microstructure: do trading mechanisms affect the price formation process of the trading subject, and how do they affect it. Information is scattered and not available to all subjects in an aggregate form, which is the consequence of a decentralised structure, lack of regulations and nontransparent trading on the foreign exchange market. In such a setting, market participants are incessantly aggregating signals based on scattered information, and no sooner than collective orders for foreign currency sales and purchases are formed do they build into the foreign exchange rate in the process of new information trading. are a good explanation for changes in the foreign exchange rate. Several studies have shown that order flows.

  19. Features of exciton dynamics in molecular nanoclusters (J-aggregates): Exciton self-trapping (Review Article)

    Science.gov (United States)

    Malyukin, Yu. V.; Sorokin, A. V.; Semynozhenko, V. P.

    2016-06-01

    We present thoroughly analyzed experimental results that demonstrate the anomalous manifestation of the exciton self-trapping effect, which is already well-known in bulk crystals, in ordered molecular nanoclusters called J-aggregates. Weakly-coupled one-dimensional (1D) molecular chains are the main structural feature of J-aggregates, wherein the electron excitations are manifested as 1D Frenkel excitons. According to the continuum theory of Rashba-Toyozawa, J-aggregates can have only self-trapped excitons, because 1D excitons must adhere to barrier-free self-trapping at any exciton-phonon coupling constant g = ɛLR/2β, wherein ɛLR is the lattice relaxation energy, and 2β is the half-width of the exciton band. In contrast, very often only the luminescence of free, mobile excitons would manifest in experiments involving J-aggregates. Using the Urbach rule in order to analyze the low-frequency region of the low-temperature exciton absorption spectra has shown that J-aggregates can have both a weak (g 1) exciton-phonon coupling. Moreover, it is experimentally demonstrated that under certain conditions, the J-aggregate excited state can have both free and self-trapped excitons, i.e., we establish the existence of a self-trapping barrier for 1D Frenkel excitons. We demonstrate and analyze the reasons behind the anomalous existence of both free and self-trapped excitons in J-aggregates, and demonstrate how exciton-self trapping efficiency can be managed in J-aggregates by varying the values of g, which is fundamentally impossible in bulk crystals. We discuss how the exciton-self trapping phenomenon can be used as an alternate interpretation of the wide band emission of some J-aggregates, which has thus far been explained by the strongly localized exciton model.

  20. Influence of excitons interaction with charge carriers on photovoltaic parameters in organic solar cells

    Science.gov (United States)

    Głowienka, Damian; Szmytkowski, Jędrzej

    2018-03-01

    We report on theoretical analysis of excitons annihilation on charge carriers in organic solar cells. Numerical calculations based on transient one-dimensional drift-diffusion model have been carried out. An impact of three quantities (an annihilation rate constant, an exciton mobility and a recombination reduction factor) on current density and concentrations of charge carriers and excitons is investigated. Finally, we discuss the influence of excitons interaction with electrons and holes on four photovoltaic parameters (a short-circuit current, an open-circuit voltage, a fill factor and a power conversion efficiency). The conclusion is that the annihilation process visibly decreases the efficiency of organic photocells, if the annihilation rate constant is greater than 10-15m3s-1 .

  1. Excitons in van der Waals heterostructures

    DEFF Research Database (Denmark)

    Latini, Simone; Olsen, Thomas; Thygesen, Kristian Sommer

    2015-01-01

    -dimensional (2D) excitons is still lacking. Here we provide a critical assessment of a widely used 2D hydrogenic exciton model, which assumes a dielectric function of the form epsilon(q) = 1 + 2 pi alpha q, and we develop a quasi-2D model with a much broader applicability. Within the quasi-2D picture, electrons...

  2. Photonic Crystal Architecture for Room-Temperature Equilibrium Bose-Einstein Condensation of Exciton Polaritons

    Directory of Open Access Journals (Sweden)

    Jian-Hua Jiang

    2014-08-01

    Full Text Available We describe photonic crystal microcavities with very strong light-matter interaction to realize room-temperature, equilibrium, exciton-polariton Bose-Einstein condensation (BEC. This goal is achieved through a careful balance between strong light trapping in a photonic band gap (PBG and large exciton density enabled by a multiple quantum-well (QW structure with a moderate dielectric constant. This approach enables the formation of a long-lived, dense 10-μm-1-cm- scale cloud of exciton polaritons with vacuum Rabi splitting that is roughly 7% of the bare exciton-recombination energy. We introduce a woodpile photonic crystal made of Cd_{0.6}  Mg_{0.4}Te with a 3D PBG of 9.2% (gap-to-central-frequency ratio that strongly focuses a planar guided optical field on CdTe QWs in the cavity. For 3-nm QWs with 5-nm barrier width, the exciton-photon coupling can be as large as ℏΩ=55  meV (i.e., a vacuum Rabi splitting of 2ℏΩ=110  meV. The exciton-recombination energy of 1.65 eV corresponds to an optical wavelength of 750 nm. For N=106 QWs embedded in the cavity, the collective exciton-photon coupling per QW (ℏΩ/sqrt[N]=5.4  meV is much larger than the state-of-the-art value of 3.3 meV, for the CdTe Fabry-Pérot microcavity. The maximum BEC temperature is limited by the depth of the dispersion minimum for the lower polariton branch, over which the polariton has a small effective mass of approximately 10^{−5}m_{0}, where m_{0} is the electron mass in vacuum. By detuning the bare exciton-recombination energy above the planar guided optical mode, a larger dispersion depth is achieved, enabling room-temperature BEC. The BEC transition temperature ranges as high as 500 K when the polariton density per QW is increased to (11a_{B}^{−2}, where a_{B}≃3.5  nm is the exciton Bohr radius and the exciton-cavity detuning is increased to 30 meV. A high-quality PBG can suppress exciton radiative decay and enhance the polariton

  3. Correlated Pair States Formed by Singlet Fission and Exciton-Exciton Annihilation.

    Science.gov (United States)

    Scholes, Gregory D

    2015-12-24

    Singlet fission to form a pair of triplet excitations on two neighboring molecules and the reverse process, triplet-triplet annihilation to upconvert excitation, have been extensively studied. Comparatively little work has sought to examine the properties of the intermediate state in both of these processes-the bimolecular pair state. Here, the eigenstates constituting the manifold of 16 bimolecular pair excitations and their relative energies in the weak-coupling regime are reported. The lowest-energy states obtained from the branching diagram method are the triplet pairs with overall singlet spin |X1⟩ ≈ (1)[TT] and quintet spin |Q⟩ ≈ (5)[TT]. It is shown that triplet pair states can be separated by a triplet-triplet energy-transfer mechanism to give a separated, yet entangled triplet pair (1)[T···T]. Independent triplets are produced by decoherence of the separated triplet pair. Recombination of independent triplets by exciton-exciton annihilation to form the correlated triplet pair (i.e., nongeminate recombination) happens with 1/3 of the rate of either triplet migration or recombination of the separated correlated triplet pair (geminate recombination).

  4. Instantaneous Rayleigh scattering from excitons localized in monolayer islands

    DEFF Research Database (Denmark)

    Langbein, Wolfgang; Leosson, Kristjan; Jensen, Jacob Riis

    2000-01-01

    We show that the initial dynamics of Rayleigh scattering from excitons in quantum wells can be either instantaneous or delayed, depending on the exciton ensemble studied. For excitation of the entire exciton resonance, a finite rise time given by the inverse inhomogeneous broadening: of the exciton...

  5. History of the Milky Way star formation rate from the white dwarf luminosity function

    Energy Technology Data Exchange (ETDEWEB)

    Noh, Hyerim; Scalo, J. (Texas Univ., Austin (USA))

    1990-04-01

    Consideration is given to the use of the white dwarf luminosity function (WDLF) to study the history of the star formation rate in the Galaxy. It is shown that the WDLF is much more sensitive to the star formation rate than to variations in the initial mass function. A marginal feature in the WDLF at log(L/solar L) = -2 is found to represent the burst of star formation which occurred 300 million yrs ago, as proposed by Barry (1988) and Scalo (1987, 1988). Observations are used to limit the ratio of recent to past average star formation rates for smoothly decreasing and increasing star formation rates. The star formation rate histories derived from the results of Twarog (1980) and Barry (1988) are compared. 34 refs.

  6. History of the Milky Way star formation rate from the white dwarf luminosity function

    Science.gov (United States)

    Noh, Hye-Rim; Scalo, John

    1990-04-01

    Consideration is given to the use of the white dwarf luminosity function (WDLF) to study the history of the star formation rate in the Galaxy. It is shown that the WDLF is much more sensitive to the star formation rate than to variations in the initial mass function. A marginal feature in the WDLF at log(L/solar L) = -2 is found to represent the burst of star formation which occurred 300 million yrs ago, as proposed by Barry (1988) and Scalo (1987, 1988). Observations are used to limit the ratio of recent to past average star formation rates for smoothly decreasing and increasing star formation rates. The star formation rate histories derived from the results of Twarog (1980) and Barry (1988) are compared.

  7. Dark excitons in transition metal dichalcogenides

    Science.gov (United States)

    Malic, Ermin; Selig, Malte; Feierabend, Maja; Brem, Samuel; Christiansen, Dominik; Wendler, Florian; Knorr, Andreas; Berghäuser, Gunnar

    2018-01-01

    Monolayer transition metal dichalcogenides (TMDs) exhibit a remarkably strong Coulomb interaction that manifests in tightly bound excitons. Due to the complex electronic band structure exhibiting several spin-split valleys in the conduction and valence band, dark excitonic states can be formed. They are inaccessibly by light due to the required spin-flip and/or momentum transfer. The relative position of these dark states with respect to the optically accessible bright excitons has a crucial impact on the emission efficiency of these materials and thus on their technological potential. Based on the solution of the Wannier equation, we present the excitonic landscape of the most studied TMD materials including the spectral position of momentum- and spin-forbidden excitonic states. We show that the knowledge of the electronic dispersion does not allow to conclude about the nature of the material's band gap since excitonic effects can give rise to significant changes. Furthermore, we reveal that an exponentially reduced photoluminescence yield does not necessarily reflect a transition from a direct to a nondirect gap material, but can be ascribed in most cases to a change of the relative spectral distance between bright and dark excitonic states.

  8. Excitons in conjugated polymers: Do we need a paradigma change?

    Energy Technology Data Exchange (ETDEWEB)

    Beenken, Wichard J.D. [Department of Theoretical Physics I, Ilmenau University of Thechnology (Germany)

    2009-12-15

    We have previously shown that both, polymer conformation and dynamics are crucial for the exciton transport in conjugated polymers. Thereby we found that the usual Foerster-type hopping transfer model - even if one applies the line-dipole approximation - falls short in one crucial aspect: the nature of the sites the excitons are transferred between is still unclear. We found that the simple model of spectroscopic units defined as segments of the polymer chains separated by structural defects breaking the {pi}-conjugation is only justified for chemical defects like hydrogenated double bonds, or extreme gauche (90 ) torsions between the monomers. Both defects are far too rare in a well-prepared conjugated polymer to explain the mean spectroscopic-unit length of typically 6-7 monomers. Meanwhile, also the concept of dynamical formation of the spectroscopic units, we had previously suggested, has also failed. Thus the question of a paradigma change concerning the exciton transport in conjugated polymers appears on the agenda. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

  9. Photoluminescence and Confinement of Excitons in Disordered Porous Films

    Energy Technology Data Exchange (ETDEWEB)

    Bondar, N. V., E-mail: jbond@iop.kiev.ua; Brodin, M. S. [National Academy of Sciences of Ukraine, Institute of Physics (Ukraine); Brodin, A. M. [National Technical University of Ukraine “KPI” (Ukraine); Matveevskaya, N. A. [National Academy of Sciences of Ukraine, Institute for Single Crystals (Ukraine)

    2016-03-15

    The exciton confinement effect in quantum dots at the surface of SiO{sub 2} spheres and the percolation phase transition in films based on a mixture of pure SiO{sub 2} spheres and spheres covered by CdS quantum dots (SiO{sub 2}/CdS nanoparticles) are studied. It is found that, due to the high surface energy of spheres, the quantum dots deposited onto their surface are distorted, which modifies the exciton confinement effect: the effect is retained only in one direction, the direction normal to the surface of the spheres. As a result, the energy of the exciton ground state exhibits a complex dependence on both the quantum-dot radius and sphere size. In the optical spectra of films based on this mixture, the clustering of small-sized nanoparticles and then, at a critical concentration of nanoparticles of ~60%, the formation of a percolation cluster are detected for the first time. The critical concentration is twice higher than the corresponding quantity given by the model of geometrical “colored percolation”, which is a consequence of interaction between submicrometer nanoparticles. The relation between the basic parameters of the percolation transition, such as the film porosity, coordination number, and the quantity defining the number of particles in the percolation cluster, is obtained and analyzed.

  10. Heart rate differences in small sided games in formative basketball

    Directory of Open Access Journals (Sweden)

    Fernando Gracia

    2014-03-01

    Full Text Available The aim of this study was to determine and learn the heart rate responses of basketball players in small-sided or modified games, in order to develop a more effective workout plan in the future. The study sample consisted of 19 basketball players from a National Championship Club, 12 of them in the U’14 category and the remaining 7 belonging to the U’16 category. Small-sided games were 3x3 and 4x4 with a duration of 4 minutes and an active break of 3 minutes. Significant differences (p<0.05 were found referring to the relations established between 3x3 without feedback and 3x3 with feedback in vigorous exercise; in 3x3 without feedback and 3x3 with feedback in moderate exercise; in 3x3 and 3x3 with average heart rate; in 4x4 and 4x4 with average heart rate and in 4x4 and 4x4 with average heart rate related to game categories.Keywords:

  11. Characteristics of SF{sub 6} gas hydrate formation mechanisms (kinetics) and surfactants effects on hydrate formation rate

    Energy Technology Data Exchange (ETDEWEB)

    Lee, B.; Lee, H.; Kim, Y.D. [Pusan National Univ., Busan (Korea, Republic of). School of Materials Science and Engineering; Kim, Y.S.; Lee, J.D. [Korea Inst. of Industrial Technology, Busan (Korea, Republic of). Advanced Energy Resource Development Team

    2008-07-01

    Sulfur hexafluoride (SF{sub 6}) is used as an insulating gas in a variety of industrial applications, and is a potent greenhouse gas (GHG). Gas hydrates are stable crystalline compounds formed by water and natural gas molecules that have relatively large cavities that can be occupied by guest molecules. SF{sub 6} gas is able to form hydrates at relatively mild conditions. This study investigated the hydrate formation mechanisms of SF{sub 6} gas, and presented a potential hydration treatment for the gas. The effects of surface active agents on SF{sub 6} gas hydrate formation were examined experimentally using Tween 20, sodium dodecyl sulfate (SDS) and linear alkyl benzene sulfonate (LABS). The surfactants showed promoter behaviour for SF{sub 6} gas hydrate formation. Formation rates occurred in 2 stages, with rates rapidly increasing during the second phase. The inflection point occurred approximately 30 minutes after the hydrate nucleation point. Results indicated the existence of a critical concentration of surfactants. It was concluded that SF{sub 6} gas hydrate formation rates were increased by the addition of surfactants. Further studies are needed to investigate 2-stage hydrate formation rates. 18 refs., 4 figs.

  12. Local energetic disorder in molecular aggregates probed by the one-exciton to two-exciton transition

    NARCIS (Netherlands)

    Durrant, James R.; Knoester, Jasper; Wiersma, Douwe A.

    1994-01-01

    We demonstrate a novel approach to probing the magnitude and degree of spatial correlation of local (molecular or atomic) energetic disorder in delocalized exciton systems. The approach is based on measuring the correlation between the ground state to one-exciton and the one-exciton to two-exciton

  13. Exciton-relaxation dynamics in lead halides

    International Nuclear Information System (INIS)

    Iwanaga, Masanobu; Hayashi, Tetsusuke

    2003-01-01

    We survey recent comprehensive studies of exciton relaxation in the crystals of lead halides. The luminescence and electron-spin-resonance studies have revealed that excitons in lead bromide spontaneously dissociate and both electrons and holes get self-trapped individually. Similar relaxation has been also clarified in lead chloride. The electron-hole separation is ascribed to repulsive correlation via acoustic phonons. Besides, on the basis of the temperature profiles of self-trapped states, we discuss the origin of luminescence components which are mainly induced under one-photon excitation into the exciton band in lead fluoride, lead chloride, and lead bromide

  14. The Origin and Evolution of the Galaxy Star Formation Rate-Stellar Mass Correlation

    Science.gov (United States)

    Gawiser, Eric; Iyer, Kartheik

    2018-01-01

    The existence of a tight correlation between galaxies’ star formation rates and stellar masses is far more surprising than usually noted. However, a simple analytical calculation illustrates that the evolution of the normalization of this correlation is driven primarily by the inverse age of the universe, and that the underlying correlation is one between galaxies’ instantaneous star formation rates and their average star formation rates since the Big Bang.Our new Dense Basis method of SED fitting (Iyer & Gawiser 2017, ApJ 838, 127) allows star formation histories (SFHs) to be reconstructed, along with uncertainties, for >10,000 galaxies in the CANDELS and 3D-HST catalogs at 0.5formation rates, providing new constraints on the level of stochasticity in galaxy formation.

  15. Solid formation in piperazine rate-based simulation

    DEFF Research Database (Denmark)

    Gaspar, Jozsef; Thomsen, Kaj; von Solms, Nicolas

    2014-01-01

    of view but also from a modeling perspective. The present work develops a rate-based model for CO2 absorption and desorption modeling for gas-liquid-solid systems and it is demonstrated for the piperazine CO2 capture process. This model is an extension of the DTU CAPCO2 model to precipitating systems....... It uses the extended UNIQUAC thermodynamic model for phase equilibria and thermal properties estimation. The mass and heat transfer phenomena is implemented in a film model approach, based on second order reactions kinetics. The transfer fluxes are calculated using the concentration of the dissolved...

  16. Regolith Formation Rates and Evolution from the Diviner Lunar Radiometer

    Science.gov (United States)

    Hayne, P. O.; Ghent, R. R.; Bandfield, J. L.; Vasavada, A. R.; Williams, J. P.; Siegler, M. A.; Lucey, P. G.; Greenhagen, B. T.; Elder, C. M.; Paige, D. A.

    2015-12-01

    Fragmentation and overturn of lunar surface materials produces a layer of regolith, which increases in thickness through time. Experiments on the lunar surface during the Apollo era, combined with remote sensing, found that the upper 10's of cm of regolith exhibit a rapid increase in density and thermal conductivity with depth. This is interpreted to be the signature of impact gardening, which operates most rapidly in the uppermost layers. Gravity data from the GRAIL mission showed that impacts have also extensively fractured the deeper crust. The breakdown and mixing of crustal materials is therefore a central process to lunar evolution and must be understood in order to interpret compositional information from remote sensing and sample analysis. Recently, thermal infrared data from the Lunar Reconnaissance Orbiter (LRO) Diviner radiometer were used to provide the first remote observational constraints on the rate of ejecta breakdown around craters L., Campbell, B. A., Allen, C. C., Carter, L. M., & Paige, D. A. (2014). Constraints on the recent rate of lunar ejecta breakdown and implications for crater ages. Geology, 42(12), 1059-1062.

  17. Rates of formation of modern phosphorite off western Mexico

    Science.gov (United States)

    Schuffert, J. D.; Jahnke, R. A.; Kastner, M.; Leather, J.; Sturz, A.; Wing, M. R.

    1994-11-01

    Phosphorite deposition represents a significant but poorly constrained sink in the marine P cycle. This study establishes conclusively that phosphorite forms today throughout a widespread region along the upper continental slope off southern Baja California, Mexico. In this region, O 2-depleted (5-50 μM) bottomwater overlies the seafloor, and a narrow range of suboxic to anoxic redox conditions prevail in the modern (0-18,000 yr old), near-surface (0-50 cm), organic-C-rich (2-10 wt%) sediment. Interstitial gradients of total alkalinity (TA) and inferred effects of organic-matter decay correlate directly with sedimentation rates calculated from 14C dating. Other porewater and solid-phase data indicate that francolite currently precipitates authigenically at each of five study sites. Moderately high concentrations (20-100 μM) of dissolved inorganic phosphate (DIP) produced in the upper 5 cm of sediment sustain francolite growth at slightly greater depths, while the necessary F - diffuses into the sediment from above. Neither organic-matter decay nor fish-bone dissolution seem capable of producing the steep, near-surface gradients of DIP measured in this study. At some sites, DIP production coincides spatially with the reversible production of dissolved Fe 2+, but thorough evaluation of the possible link between these processes requires further study. The mechanism responsible for the near-surface enrichment of interstitial DIP thus remains unidentified. Box cores from each site contain an unreworked sequence of up to six thin (1-3 cm), discrete, francolite-rich horizons, several of which qualify as true phosphorite (≥ 50 wt% francolite). Estimated diffusional burial fluxes of inorganic P and F range respectively from 2-40 μg cm -2 y -1 and 4-12 μg cm -2 y -1, or the equivalent in francolite of 16-260 μg cm -2 y -1. These present-day accumulation rates lie within the range of those determined for several ancient phosphorite deposits and for the extensively

  18. Excitonic properties of graphene-based materials.

    Science.gov (United States)

    Wang, Min; Li, Chang Ming

    2012-02-21

    First-principle density functional theory (DFT) calculations with quasiparticle corrections and many body effects are performed to study the electronic and optical properties of graphene-based materials. This review summarizes the excitonic properties including optical transition spectra and the distribution of exciton wavefunctions, thus providing the theoretical knowledge and predictions for promising optical applications of graphene materials. This journal is © The Royal Society of Chemistry 2012

  19. Effect of three representative surfactants on methane hydrate formation rate and induction time

    Directory of Open Access Journals (Sweden)

    Mostafa keshavarz Moraveji

    2017-06-01

    Full Text Available The effects of three types of surfactants on methane hydrate formation process were investigated. Three different classes of surfactants involving anionic (sodium dodecyl sulfonate, cationic (hexadecyl trimethyl ammonium bromide and non-ionic (poly oxy ethylene (40 octyl phenyl ether have been used. Thermodynamics of hydrate formation, formation rate, kinetic constants and induction time in the presence of surfactants with various concentrations were analyzed. Critical micelle concentrations (CMCs of these surfactants in water were determined by induction time measurements in various concentrations under methane hydrate formation conditions. The critical micelle concentration (CMC at the methane hydrate formation conditions for SDS, HTABr and TritonX-405 solutions were obtained at 450, 380 and 950 ppm, respectively. The experimental results indicated that hydrate formation rate increased with the use of surfactants for all concentrations and induction time decreased. It was found that for surfactants, CMC at hydrate formation conditions was less than CMC at ambient conditions.

  20. Exciton Resonances in Novel Silicon Carbide Polymers

    Science.gov (United States)

    Burggraf, Larry; Duan, Xiaofeng

    2015-05-01

    A revolutionary technology transformation from electronics to excitionics for faster signal processing and computing will be advantaged by coherent exciton transfer at room temperature. The key feature required of exciton components for this technology is efficient and coherent transfer of long-lived excitons. We report theoretical investigations of optical properties of SiC materials having potential for high-temperature excitonics. Using Car-Parinello simulated annealing and DFT we identified low-energy SiC molecular structures. The closo-Si12C12 isomer, the most stable 12-12 isomer below 1100 C, has potential to make self-assembled chains and 2-D nanostructures to construct exciton components. Using TDDFT, we calculated the optical properties of the isomer as well as oligomers and 2-D crystal formed from the isomer as the monomer unit. This molecule has large optical oscillator strength in the visible. Its high-energy and low-energy transitions (1.15 eV and 2.56 eV) are nearly pure one-electron silicon-to-carbon transitions, while an intermediate energy transition (1.28 eV) is a nearly pure carbon-to-silicon one-electron charge transfer. These results are useful to describe resonant, coherent transfer of dark excitons in the nanostructures. Research supported by the Air Force Office of Scientific Research.

  1. The mean star formation rates of unobscured QSOs: searching for evidence of suppressed or enhanced star formation

    NARCIS (Netherlands)

    Stanley, F.; Alexander, D. M.; Harrison, C. M.; Rosario, D. J.; Wang, L.; Aird, J. A.; Bourne, N.; Dunne, L.; Dye, S.; Eales, S.; Knudsen, K. K.; Michałowski, M. J.; Valiante, E.; De Zotti, G.; Furlanetto, C.; Ivison, R.; Maddox, S.; Smith, M. W. L.

    2017-01-01

    We investigate the mean star formation rates (SFRs) in the host galaxies of ˜3000 optically selected quasi-stellar objects (QSOs) from the Sloan Digital Sky Survey within the Herschel-ATLAS fields, and a radio-luminous subsample covering the redshift range of z = 0.2-2.5. Using Wide-field Infrared

  2. Formation of hydrogen bonds precedes the rate-limiting formation of persistent structure in the folding of ACBP

    DEFF Research Database (Denmark)

    Teilum, K; Kragelund, B B; Knudsen, J

    2000-01-01

    of eight conserved hydrophobic residues at the interface between the two N and C-terminal helices. Previous mutation studies have shown that the formation of this structure is rate limiting for the final folding of ACBP. The burst phase structures observed in ACBP are different from the previously reported...

  3. Strong coupling in porphyrin J-aggregate excitons and plasmons in nano-void arrays

    Science.gov (United States)

    Ferdele, Stefano; Jose, Bincy; Foster, Robert; Keyes, Tia E.; Rice, James H.

    2017-10-01

    Active plasmonic nano-void arrays made through colloidal lithography (a cost effective and rapid process) potentially offers opportunities for scalable device design. In this work we demonstrate strong coupling between Bragg-like quadrupole surface plasmon modes in nano-void substrate designs with Frankel excitons in a molecular J-aggregate layer though angular tuning. The enhanced exciton-plasmon coupling creates a Fano like line shape in the differential reflection spectra associated with the formation of new hybrid states, leading to anti-crossing of the upper and lower polaritons with a Rabi frequency of 120 meV.

  4. Excitonic polaritons of zinc diarsenide single crystals

    Energy Technology Data Exchange (ETDEWEB)

    Syrbu, N.N., E-mail: sirbunn@yahoo.com [Technical University of Moldova, Chisinau, Republic of Moldova (Moldova, Republic of); Stamov, I.G. [T.G. Shevchenko State University of Pridnestrovie, Tiraspol, Republic of Moldova (Moldova, Republic of); Zalamai, V.V. [Institute of Applied Physics, Academy of Sciences of Moldova, Chisinau, Republic of Moldova (Moldova, Republic of); Dorogan, A. [Technical University of Moldova, Chisinau, Republic of Moldova (Moldova, Republic of)

    2017-02-01

    Excitonic polaritons of ZnAs{sub 2} single crystals had been investigated. Parameters of singlet excitons with Г{sub 2}¯(z) symmetry and orthoexcitons 2Г{sub 1}¯(y)+Г{sub 2}¯(x) had been determined. Spectral dependencies of ordinary and extraordinary dispersion of refractive index had been calculated using interferential reflection and transmittance spectra. It was shown, that A excitonic series were due to hole (V{sub 1}) and electron (C{sub 1}) bands. The values of effective masses of electrons (m{sub c}{sup *}=0.10 m{sub 0}) and holes (m{sub v1}{sup *}=0.89 m{sub 0}) had been estimated. It was revealed that the hole mass m{sub v1}{sup *} changes from 1.03 m{sub 0} to 0.55 m{sub 0} at temperature increasing from 10 K up to 230 K and that the electron mass m{sub c}{sup *} does not depend on temperature. The integral absorption A (eV cm{sup −1}) of the states n=1, 2 and 3 of Г{sub 2}¯(z) excitons depends on the A{sub n}≈n{sup −3} equality, which it is characteristic for S-type excitonic functions. Temperature dependences of the integral absorption of ground states for Г{sub 2}¯(z) and Г{sub 2}¯(Ñ…) excitons differ. The ground states of B and C excitons formed by V{sub 3} – C{sub 1} and V{sub 4} – C{sub 1} bands and its parameters had been determined.

  5. Evidence for a topological excitonic insulator in InAs/GaSb bilayers.

    Science.gov (United States)

    Du, Lingjie; Li, Xinwei; Lou, Wenkai; Sullivan, Gerard; Chang, Kai; Kono, Junichiro; Du, Rui-Rui

    2017-12-07

    Electron-hole pairing can occur in a dilute semimetal, transforming the system into an excitonic insulator state in which a gap spontaneously appears at the Fermi surface, analogous to a Bardeen-Cooper-Schrieffer (BCS) superconductor. Here, we report optical spectroscopic and electronic transport evidence for the formation of an excitonic insulator gap in an inverted InAs/GaSb quantum-well system at low temperatures and low electron-hole densities. Terahertz transmission spectra exhibit two absorption lines that are quantitatively consistent with predictions from the pair-breaking excitation dispersion calculated based on the BCS gap equation. Low-temperature electronic transport measurements reveal a gap of ~2 meV (or ~25 K) with a critical temperature of ~10 K in the bulk, together with quantized edge conductance, suggesting the occurrence of a topological excitonic insulator phase.

  6. Excitonic effects in two-dimensional semiconductors: Path integral Monte Carlo approach

    Energy Technology Data Exchange (ETDEWEB)

    Velizhanin, Kirill A.; Saxena, Avadh

    2015-11-01

    One of the most striking features of novel two-dimensional semiconductors (e.g., transition metal dichalcogenide monolayers or phosphorene) is a strong Coulomb interaction between charge carriers resulting in large excitonic effects. In particular, this leads to the formation of multicarrier bound states upon photoexcitation (e.g., excitons, trions, and biexcitons), which could remain stable at near-room temperatures and contribute significantly to the optical properties of such materials. In the present work we have used the path integral Monte Carlo methodology to numerically study properties of multicarrier bound states in two-dimensional semiconductors. Specifically, we have accurately investigated and tabulated the dependence of single-exciton, trion, and biexciton binding energies on the strength of dielectric screening, including the limiting cases of very strong and very weak screening. The results of this work are potentially useful in the analysis of experimental data and benchmarking of theoretical and computational models.

  7. Muon cycling rate in D/T mixture including doubly muonic molecule formation

    Directory of Open Access Journals (Sweden)

    M. R. Eskandari

    2002-06-01

    Full Text Available   In the present work, the fundamental behavior of four body molecule formations of pt μμ , pd μμ , dt μμ , tt μμ , and pp μμ in a D/T fusion are considered. Their higher fusion rate, specially the available data for dt μμ , encouraged us to study the muon cycling rate in D/T fusion in the temperature range of (100-1400 K, density and deuterium-tritium concentration ratio. For this purpose, various values for the doubly muonic molecule formation are chosen and with the comparison to the experimental results, the doubly muonic formation rate of 109 s-1 is predicted theoretically. Our calculated cycling rate has shown that having not considered the doubly muonic formation in previous calculations had made no serious changes in the previously calculated values.

  8. Dose-rate effects for apoptosis and micronucleus formation in gamma-irradiated human lymphocytes

    International Nuclear Information System (INIS)

    Boreham, D.R.; Dolling, J.-A.; Maves, S.R.; Siwarungsun, N.; Mitchel, R.E.J.

    2000-01-01

    We have compared dose-rate effects for γ-radiation-induced apoptosis and micronucleus formation in human lymphocytes. Long-term assessment of individual radiation-induced apoptosis showed little intraindividual variation but significant interindividual variation. The effectiveness of radiation exposure to cause apoptosis or micronucleus formation was reduced by low-dose-rate exposures, but the reduction was apparent at different dose rates for these two end points. Micronucleus formation showed a dose-rate effect when the dose rate was lowered to 0.29 cGy/min, but there was no accompanying cell cycle delay. A further increase in the dose-rate effect was seen at 0.15 cGy/min, but was now accompanied by cell cycle delay. There was no dose-rate effect for the induction of apoptosis until the dose rate was reduced to 0.15 cGy/min, indicating that the mechanisms or signals for processing radiation-induced lesions for these two end points must be different at least in part. There appear to be two mechanisms that contribute to the dose-rate effect for micronucleus formation. One of these does not affect binucleate cell frequency and occurs at dose rates higher than that required to produce a dose-rate effect for apoptosis, and one affects binucleate cell frequency, induced only at the very low dose rate which coincidentally produces a dose-rate effect for apoptosis. Since the dose rate at which cells showed reduced apoptosis as well as a further reduction in micronucleus formation was very low, we conclude that the processing of the radiation-induced lesions that induce apoptosis, and some micronuclei, is very slow in quiescent and PHA-stimulated lymphocytes, respectively. (author)

  9. Dose-rate effects for apoptosis and micronucleus formation in gamma-irradiated human lymphocytes

    Energy Technology Data Exchange (ETDEWEB)

    Boreham, D.R.; Dolling, J.-A.; Maves, S.R. [Atomic Energy of Canada Limited, Chalk River, Ontario (Canada); Siwarungsun, N. [Chulalongkorn Univ., Bangkok (Thailand); Mitchel, R.E.J. [Atomic Energy of Canada Limited, Chalk River, Ontario (Canada)

    2000-07-01

    We have compared dose-rate effects for {gamma}-radiation-induced apoptosis and micronucleus formation in human lymphocytes. Long-term assessment of individual radiation-induced apoptosis showed little intraindividual variation but significant interindividual variation. The effectiveness of radiation exposure to cause apoptosis or micronucleus formation was reduced by low-dose-rate exposures, but the reduction was apparent at different dose rates for these two end points. Micronucleus formation showed a dose-rate effect when the dose rate was lowered to 0.29 cGy/min, but there was no accompanying cell cycle delay. A further increase in the dose-rate effect was seen at 0.15 cGy/min, but was now accompanied by cell cycle delay. There was no dose-rate effect for the induction of apoptosis until the dose rate was reduced to 0.15 cGy/min, indicating that the mechanisms or signals for processing radiation-induced lesions for these two end points must be different at least in part. There appear to be two mechanisms that contribute to the dose-rate effect for micronucleus formation. One of these does not affect binucleate cell frequency and occurs at dose rates higher than that required to produce a dose-rate effect for apoptosis, and one affects binucleate cell frequency, induced only at the very low dose rate which coincidentally produces a dose-rate effect for apoptosis. Since the dose rate at which cells showed reduced apoptosis as well as a further reduction in micronucleus formation was very low, we conclude that the processing of the radiation-induced lesions that induce apoptosis, and some micronuclei, is very slow in quiescent and PHA-stimulated lymphocytes, respectively. (author)

  10. Exciton Absorption Spectra by Linear Response Methods:Application to Conjugated Polymers

    Energy Technology Data Exchange (ETDEWEB)

    Mosquera, Martin A.; Jackson, Nicholas E.; Fauvell, Thomas J.; Kelley, Matthew S.; Chen, Lin X.; Schatz, George C.; Ratner, Mark A.

    2017-01-01

    The theoretical description of the timeevolution of excitons requires, as an initial step, the calculation of their spectra, which has been inaccessible to most users due to the high computational scaling of conventional algorithms and accuracy issues caused by common density functionals. Previously (J. Chem. Phys. 2016, 144, 204105), we developed a simple method that resolves these issues. Our scheme is based on a two-step calculation in which a linear-response TDDFT calculation is used to generate orbitals perturbed by the excitonic state, and then a second linear-response TDDFT calculation is used to determine the spectrum of excitations relative to the excitonic state. Herein, we apply this theory to study near-infrared absorption spectra of excitons in oligomers of the ubiquitous conjugated polymers poly(3-hexylthiophene) (P3HT), poly(2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene) (MEH-PPV), and poly(benzodithiophene-thieno[3,4-b]thiophene) (PTB7). For P3HT and MEH-PPV oligomers, the calculated intense absorption bands converge at the longest wavelengths for 10 monomer units, and show strong consistency with experimental measurements. The calculations confirm that the exciton spectral features in MEH-PPV overlap with those of the bipolaron formation. In addition, our calculations identify the exciton absorption bands in transient absorption spectra measured by our group for oligomers (1, 2, and 3 units) of PTB7. For all of the cases studied, we report the dominant orbital excitations contributing to the optically active excited state-excited state transitions, and suggest a simple rule to identify absorption peaks at the longest wavelengths. We suggest our methodology could be considered for further evelopments in theoretical transient spectroscopy to include nonadiabatic effects, coherences, and to describe the formation of species such as charge-transfer states and polaron pairs.

  11. Plasmon-excitonic polaritons in superlattices

    Science.gov (United States)

    Kosobukin, V. A.

    2017-05-01

    A theory for propagation of polaritons in superlattices with resonant plasmon-exciton coupling is presented. A periodical superlattice consists of a finite number of cells with closely located a quantum well and a monolayer of metal nanoparticles. Under study is the spectrum of hybrid modes formed of the quasitwo- dimensional excitons of quantum wells and the dipole plasmons of metal particles. The problem of electrodynamics is solved by the method of Green's functions with taking account of the resonant polarization of quantum wells and nanoparticles in a self-consistent approximation. The effective polarizability of spheroidal particles occupying a square lattice is calculated with taking into consideration the local-field effect of dipole plasmons of the layer and their images caused by the excitonic polarization of nearest quantum well. Optical reflection spectra of superlattices with GaAs/AlGaAs quantum wells and silver particles are numerically analyzed. Special attention is paid to the superradiant regime originated in the Bragg diffraction of polaritons in superlattice. Superradiance is investigated separately for plasmons and excitons, and then for hybrid plasmonexcitonic polaritons. It is demonstrated that the broad spectrum of reflectance associated with plasmons depends on the number of cells in superlattice, and it has a narrow spectral dip in the range of plasmon-excitonic Rabi splitting.

  12. Numerical modeling of exciton-polariton Bose-Einstein condensate in a microcavity

    Science.gov (United States)

    Voronych, Oksana; Buraczewski, Adam; Matuszewski, Michał; Stobińska, Magdalena

    2017-06-01

    A novel, optimized numerical method of modeling of an exciton-polariton superfluid in a semiconductor microcavity was proposed. Exciton-polaritons are spin-carrying quasiparticles formed from photons strongly coupled to excitons. They possess unique properties, interesting from the point of view of fundamental research as well as numerous potential applications. However, their numerical modeling is challenging due to the structure of nonlinear differential equations describing their evolution. In this paper, we propose to solve the equations with a modified Runge-Kutta method of 4th order, further optimized for efficient computations. The algorithms were implemented in form of C++ programs fitted for parallel environments and utilizing vector instructions. The programs form the EPCGP suite which has been used for theoretical investigation of exciton-polaritons. Catalogue identifier: AFBQ_v1_0 Program summary URL:http://cpc.cs.qub.ac.uk/summaries/AFBQ_v1_0.html Program obtainable from: CPC Program Library, Queen's University, Belfast, N. Ireland Licensing provisions: BSD-3 No. of lines in distributed program, including test data, etc.: 2157 No. of bytes in distributed program, including test data, etc.: 498994 Distribution format: tar.gz Programming language: C++ with OpenMP extensions (main numerical program), Python (helper scripts). Computer: Modern PC (tested on AMD and Intel processors), HP BL2x220. Operating system: Unix/Linux and Windows. Has the code been vectorized or parallelized?: Yes (OpenMP) RAM: 200 MB for single run Classification: 7, 7.7. Nature of problem: An exciton-polariton superfluid is a novel, interesting physical system allowing investigation of high temperature Bose-Einstein condensation of exciton-polaritons-quasiparticles carrying spin. They have brought a lot of attention due to their unique properties and potential applications in polariton-based optoelectronic integrated circuits. This is an out-of-equilibrium quantum system confined

  13. Identification of effective exciton-exciton annihilation in squaraine-squaraine copolymers.

    Science.gov (United States)

    Hader, Kilian; May, Volkhard; Lambert, Christoph; Engel, Volker

    2016-05-11

    Ultrafast time-resolved transient absorption spectroscopy is able to monitor the fate of the excited state population in molecular aggregates or polymers. Due to many competing decay processes, the identification of exciton-exciton annihilation (EEA) is difficult. Here, we use a microscopic model to describe exciton annihilation processes in squaraine-squaraine copolymers. Transient absorption time traces measured at different laser powers exhibit an unusual time-dependence. The analysis points towards dynamics taking place on three time-scales. Immediately after laser-excitation a localization of excitons takes place within the femtosecond time-regime. This is followed by exciton-exciton annihilation which is responsible for a fast decay of the exciton population. At later times, excitations being localized on units which are not directly connected remain so that diffusion dominates the dynamics and leads to a slower decay. We thus provide evidence for EEA tracked by time-resolved spectroscopy which has not been reported that clearly before.

  14. Bose-Einstein condensation and indirect excitons: a review.

    Science.gov (United States)

    Combescot, Monique; Combescot, Roland; Dubin, François

    2017-06-01

    We review recent progress on Bose-Einstein condensation (BEC) of semiconductor excitons. The first part deals with theory, the second part with experiments. This Review is written at a time where the problem of exciton Bose-Einstein condensation has just been revived by the understanding that the exciton condensate must be dark because the exciton ground state is not coupled to light. Here, we theoretically discuss this missed understanding before providing its experimental support through experiments that scrutinize indirect excitons made of spatially separated electrons and holes. The theoretical part first discusses condensation of elementary bosons. In particular, the necessary inhibition of condensate fragmentation by exchange interaction is stressed, before extending the discussion to interacting bosons with spin degrees of freedom. The theoretical part then considers composite bosons made of two fermions like semiconductor excitons. The spin structure of the excitons is detailed, with emphasis on the crucial fact that ground-state excitons are dark: indeed, this imposes the exciton Bose-Einstein condensate to be not coupled to light in the dilute regime. Condensate fragmentations are then reconsidered. In particular, it is shown that while at low density, the exciton condensate is fully dark, it acquires a bright component, coherent with the dark one, beyond a density threshold: in this regime, the exciton condensate is 'gray'. The experimental part first discusses optical creation of indirect excitons in quantum wells, and the detection of their photoluminescence. Exciton thermalisation is also addressed, as well as available approaches to estimate the exciton density. We then switch to specific experiments where indirect excitons form a macroscopic fragmented ring. We show that such ring provides efficient electrostatic trapping in the region of the fragments where an essentially-dark exciton Bose-Einstein condensate is formed at sub-Kelvin bath

  15. Non-conservation of excitons in finite molecular chain

    International Nuclear Information System (INIS)

    Tosic, Bratislav; Sajfert, Vjekoslav; Maskovic, Ljiljana; Bednar, Nikola

    2010-01-01

    We have analyzed a linear molecular chain with exciton excitations when the number of excitons is not conserved. The dispersion law depends on two independent variables and it is surfaced in a 3D plot. The same conclusion is valid for the concentrations of excitons and exciton pairs. As it was expected, physical characteristics of the finite chain depend on spatial coordinates. All results are compared to the corresponding results of an infinite chain.

  16. Trapping effects in exciton motion in the framework of CTRW

    International Nuclear Information System (INIS)

    Barvik, I.; Herman, P.

    1990-10-01

    Influence of a trap (sink) on an exciton transfer in molecular aggregates is investigated. Pausing time distribution functions φ p m (t) and probability densities Q mn (t) on the continuous time random walk theory are calculated from memory functions entering the generalized master equations. The presence of the sink changes their analytical form. We used trimmer as example to show that only for large trapping rates pausing time distribution functions become nonnegative. Only in this case they could be used in Monte Carlo modelling. (author). 14 refs, 2 figs

  17. Role of Fe substitution and quenching rate on the formation of ...

    Indian Academy of Sciences (India)

    Unknown

    Role of Fe substitution and quenching rate on the formation of various quasicrystalline and related phases. VARSHA .... Yet another remarkable observation is that at lower quenching rate, there is no trace of icosahedral ... is remarkable and first of its kind in Al–Cu–Cr system because in this system decagonal phase is ...

  18. Electrical pumping and tuning of exciton-polaritons in carbon nanotube microcavities

    Science.gov (United States)

    Graf, Arko; Held, Martin; Zakharko, Yuriy; Tropf, Laura; Gather, Malte C.; Zaumseil, Jana

    2017-09-01

    Exciton-polaritons are hybrid light-matter particles that form upon strong coupling of an excitonic transition to a cavity mode. As bosons, polaritons can form condensates with coherent laser-like emission. For organic materials, optically pumped condensation was achieved at room temperature but electrically pumped condensation remains elusive due to insufficient polariton densities. Here we combine the outstanding optical and electronic properties of purified, solution-processed semiconducting (6,5) single-walled carbon nanotubes (SWCNTs) in a microcavity-integrated light-emitting field-effect transistor to realize efficient electrical pumping of exciton-polaritons at room temperature with high current densities (>10 kA cm-2) and tunability in the near-infrared (1,060 nm to 1,530 nm). We demonstrate thermalization of SWCNT polaritons, exciton-polariton pumping rates ~104 times higher than in current organic polariton devices, direct control over the coupling strength (Rabi splitting) via the applied gate voltage, and a tenfold enhancement of polaritonic over excitonic emission. This powerful material-device combination paves the way to carbon-based polariton emitters and possibly lasers.

  19. Exciton dynamics in suspended monolayer and few-layer MoS₂ 2D crystals.

    Science.gov (United States)

    Shi, Hongyan; Yan, Rusen; Bertolazzi, Simone; Brivio, Jacopo; Gao, Bo; Kis, Andras; Jena, Debdeep; Xing, Huili Grace; Huang, Libai

    2013-02-26

    Femtosecond transient absorption spectroscopy and microscopy were employed to study exciton dynamics in suspended and Si₃N₄ substrate-supported monolayer and few-layer MoS₂ 2D crystals. Exciton dynamics for the monolayer and few-layer structures were found to be remarkably different from those of thick crystals when probed at energies near that of the lowest energy direct exciton (A exciton). The intraband relaxation rate was enhanced by more than 40 fold in the monolayer in comparison to that observed in the thick crystals, which we attributed to defect assisted scattering. Faster electron-hole recombination was found in monolayer and few-layer structures due to quantum confinement effects that lead to an indirect-direct band gap crossover. Nonradiative rather than radiative relaxation pathways dominate the dynamics in the monolayer and few-layer MoS₂. Fast trapping of excitons by surface trap states was observed in monolayer and few-layer structures, pointing to the importance of controlling surface properties in atomically thin crystals such as MoS₂ along with controlling their dimensions.

  20. Excitonic dynamical Franz-Keldysh effect

    DEFF Research Database (Denmark)

    Nordstrøm, K.B.; Johnsen, Kristinn; Allen, S.J.

    1998-01-01

    The dynamical Franz-Keldysh effect is exposed by exploring near-band-gap absorption in the presence of intense THz electric fields. It bridges the gap between the de Franz-Keldysh effect and multiphoton absorption and competes with the THz ac Stark effect in shifting the energy of the excitonic...... resonance. A theoretical model which includes the strong THz field nonperturbatively via a nonequilibrium Green functions technique is able to describe the dynamical Franz-Keldysh effect in the presence of excitonic absorption....

  1. Excitonic recombination in delta-doped GaAs/AlAs type-II superlattices

    CERN Document Server

    Zhuravlev, K S; Gilinskij, A M; Braginskij, L S; Toropov, A I; Bakarov, A K

    2002-01-01

    An experimental study of excitonic recombination in delta-doped GaAs/AlAs type-II superlattices has been carried out. t is found that the increase in the impurity density of delta-layers from 2 x 10 sup 1 sup 0 to 7.5 x 10 sup 1 sup 1 cm sup - sup 2 results in (4-6)-fold decline in the integral superlattice photoluminescence intensity and in a significant decrease of excitonic photoluminescence intensity (70-80 times as much) accompanied by an increase in the exciton radiative recombination rate. It is concluded that built-in electric fields induced by ionized impurities are the principle reason for quenching the impurity photoluminescence

  2. Crystalline Nanoporous Frameworks: a Nanolaboratory for Probing Excitonic Device Concepts.

    Energy Technology Data Exchange (ETDEWEB)

    Allendorf, Mark D.; Azoulay, Jason; Ford, Alexandra Caroline; Foster, Michael E.; El Gabaly Marquez, Farid; Leonard, Francois Leonard; Leong-Hau, Kirsty; Stavila, Vitalie; Talin, Albert Alec; Wong, Brian M.; Brumbach, Michael T.; Van Gough, D.; Lambert, Timothy N.; Rodriguez, Mark A.; Spoerke, Erik David; Wheeler, David Roger; Deaton, Joseph C.; Centrone, Andrea; Haney, Paul; Kinney, R.; Szalai, Veronika; Yoon, Heayoung P.

    2014-09-01

    Electro-optical organic materials hold great promise for the development of high-efficiency devices based on exciton formation and dissociation, such as organic photovoltaics (OPV) and organic light-emitting devices (OLEDs). However, the external quantum efficiency (EQE) of both OPV and OLEDs must be improved to make these technologies economical. Efficiency rolloff in OLEDs and inability to control morphology at key OPV interfaces both reduce EQE. Only by creating materials that allow manipulation and control of the intimate assembly and communication between various nanoscale excitonic components can we hope to first understand and then engineer the system to allow these materials to reach their potential. The aims of this proposal are to: 1) develop a paradigm-changing platform for probing excitonic processes composed of Crystalline Nanoporous Frameworks (CNFs) infiltrated with secondary materials (such as a complimentary semiconductor); 2) use them to probe fundamental aspects of excitonic processes; and 3) create prototype OPVs and OLEDs using infiltrated CNF as active device components. These functional platforms will allow detailed control of key interactions at the nanoscale, overcoming the disorder and limited synthetic control inherent in conventional organic materials. CNFs are revolutionary inorganic-organic hybrid materials boasting unmatched synthetic flexibility that allow tuning of chemical, geometric, electrical, and light absorption/generation properties. For example, bandgap engineering is feasible and polyaromatic linkers provide tunable photon antennae; rigid 1-5 nm pores provide an oriented, intimate host for triplet emitters (to improve light emission in OLEDs) or secondary semiconducting polymers (creating a charge-separation interface in OPV). These atomically engineered, ordered structures will enable critical fundamental questions to be answered concerning charge transport, nanoscale interfaces, and exciton behavior that are inaccessible

  3. A new balance formula to estimate new particle formation rate: reevaluating the effect of coagulation scavenging

    OpenAIRE

    Cai, Runlong; Jiang, Jingkun

    2017-01-01

    A new balance formula to estimate new particle formation rate is proposed. It was derived from aerosol general dynamic equation in the discrete form and then converted into an approximately continuous form for analysing data from new particle formation (NPF) field campaigns. The new formula corrects the underestimation of the coagulation scavenging effect occurred in previously used formulae. It also clarifies the criterions in determining upper size bound in measured aerosol size distributio...

  4. Exciton-exciton annihilation and relaxation pathways in semiconducting carbon nanotubes.

    Science.gov (United States)

    Chmeliov, Jevgenij; Narkeliunas, Jonas; Graham, Matt W; Fleming, Graham R; Valkunas, Leonas

    2016-01-21

    We present a thorough analysis of one- and two-color transient absorption measurements performed on single- and double-walled semiconducting carbon nanotubes. By combining the currently existing models describing exciton-exciton annihilation-the coherent and the diffusion-limited ones-we are able to simultaneously reproduce excitation kinetics following both E11 and E22 pump conditions. Our simulations revealed the fundamental photophysical behavior of one-dimensional coherent excitons and non-trivial excitation relaxation pathways. In particular, we found that after non-linear annihilation a doubly-excited exciton relaxes directly to its E11 state bypassing the intermediate E22 manifold, so that after excitation resonant with the E11 transition, the E22 state remains unpopulated. A quantitative explanation for the observed much faster excitation kinetics probed at E22 manifold, comparing to those probed at the E11 band, is also provided.

  5. An Analytical Solution for Exciton Generation, Reaction, and Diffusion in Nanotube and Nanowire-Based Solar Cells.

    Science.gov (United States)

    Bellisario, Darin O; Paulson, Joel A; Braatz, Richard D; Strano, Michael S

    2016-07-21

    Excitonic solar cells based on aligned or unaligned networks of nanotubes or nanowires offer advantages with respect of optical absorption, and control of excition and electrical carrier transport; however, there is a lack of predictive models of the optimal orientation and packing density of such devices to maximize efficiency. Here-in, we develop a concise analytical framework that describes the orientation and density trade-off on exciton collection computed from a deterministic model of a carbon nanotube (CNT) photovoltaic device under steady-state operation that incorporates single- and aggregate-nanotube photophysics published earlier (Energy Environ Sci, 2014, 7, 3769). We show that the maximal film efficiency is determined by a parameter grouping, α, representing the product of the network density and the effective exciton diffusion length, reflecting a cooperativity between the rate of exciton generation and the rate of exciton transport. This allows for a simple, master plot of EQE versus film thickness, parametric in α allowing for optimal design. This analysis extends to any excitonic solar cell with anisotropic transport elements, including polymer, nanowire, quantum dot, and nanocarbon photovoltaics.

  6. Excitonic optical bistability in n-type doped semiconductors

    International Nuclear Information System (INIS)

    Nguyen Ba An; Le Thi Cat Tuong

    1991-07-01

    A resonant monochromatic pump laser generates coherent excitons in an n-type doped semiconductor. Both exciton-exciton and exciton-donor interactions come into play. The former interaction can give rise to the appearance of optical bistability which is heavily influenced by the latter one. When optical bistability occurs at a fixed laser frequency both its holding intensity and hysteresis loop size are shown to decrease with increasing donor concentration. Two possibilities are suggested for experimentally determining one of the two parameters of the system - the exciton-donor coupling constant and the donor concentration, if the other parameter is known beforehand. (author). 36 refs, 2 figs

  7. Let's go formative: continuous student ratings with Web 2.0 application Twitter.

    Science.gov (United States)

    Stieger, Stefan; Burger, Christoph

    2010-04-01

    Student ratings have been a controversial but important method for the improvement of teaching quality during the past several decades. Most universities rely on summative evaluations conducted at the end of a term or course. A formative approach in which each course unit is evaluated may be beneficial for students and teachers but has rarely been applied. This is most probably due to the time constraints associated with various procedures inherent in formative evaluation (numerous evaluations, high amounts of aggregated data, high administrative investment). In order to circumvent these disadvantages, we chose the Web 2.0 Internet application Twitter as evaluation tool and tested whether it is useful for the implementation of a formative evaluation. After a first pilot and subsequent experimental study, the following conclusions were drawn: First, the formative evaluation did not come to the same results as the summative evaluation at the end of term, suggesting that formative evaluations tap into different aspects of course evaluation than summative evaluations do. Second, the results from an offline (i.e., paper-pencil) summative evaluation were identical with those from an online summative evaluation of the same course conducted a week later. Third, the formative evaluation did not influence the ratings of the summative evaluation at the end of the term. All in all, we can conclude that Twitter is a useful tool for evaluating a course formatively (i.e., on a weekly basis). Because of Twitter's simple use and the electronic handling of data, the administrative effort remains small.

  8. Probe Measurements of Ash Deposit Formation Rate and Shedding in a Biomass Suspension-Fired boiler

    DEFF Research Database (Denmark)

    Shafique Bashir, Muhammad; Jensen, Peter Arendt; Frandsen, Flemming

    The aim of this study was to investigate ash deposit formation rate, heat uptake reduction and deposit removal by using advanced online ash deposition and sootblowing probes in a 350 MWth suspension-fired boiler, utilizing wood and straw pellets as fuel. The influence of fuel type (straw share...... in wood), probe exposure time, probe surface temperature (500, 550 and 600 oC) and flue gas temperature (600 - 1050 oC) on ash deposit formation rate, heat uptake by the probe, the fly ash and deposit characteristics, and deposit removal have been investigated. The results indicated that increase in flue...... gas temperature increased the ash deposit formation rate. It was also found that probe heat uptake reduction was not strongly sensitive to the deposit mass load on the probe. This indicated that the heat transfer from the flue gas to the probe was dominated by the rear side, where little material...

  9. Bright monolayer tungsten disulfide via exciton and trion chemical modulations.

    Science.gov (United States)

    Tao, Ye; Yu, Xuechao; Li, Jiewei; Liang, Houkun; Zhang, Ying; Huang, Wei; Wang, Qi Jie

    2018-04-05

    Atomically thin transition metal dichalcogenides (TMDCs) with exceptional electrical and optical properties have drawn tremendous attention for use in novel optoelectronic applications as photodetectors, transistors, light emitters, etc. However, electron bound trions formed through the combination of neutral excitons and electrons significantly decrease the photoluminescence (PL) efficiency of TMDCs. In this study, we report a simple yet efficient chemical doping strategy to modulate the optical properties of monolayer tungsten disulfide (WS2). As a demonstrative example, a chemically doped monolayer of WS2 exhibits remarkable PL enhancement of about one order of magnitude higher than that of pristine WS2. This outstanding PL enhancement is attributed to the fact that excess electrons, which promote the formation of electron-bound trions, are reduced in number through charge transfer from WS2 to the chemical dopant. Furthermore, an improved degree of circular polarization from ∼9.0% to ∼41.5% was also observed in the chemically doped WS2 monolayer. This work describes a feasible strategy to manipulate the optical properties of TMDCs via exciton modulation, making TMDCs promising candidates for versatile semiconductor-based photonic devices.

  10. Electrical Control of Excitons in Semiconductor Nanostructures

    DEFF Research Database (Denmark)

    Kirsanské, Gabija

    The scope of this thesis covers investigation of the exciton Mott transition in coupled quantum wells, fabrication of photonic-crystal structures with embedded self-assembled quantum dots, and tuning of their properties by means of an external electric field. In the first part of the thesis the f...

  11. Phonon-Driven Oscillatory Plasmonic Excitonic Nanomaterials

    Energy Technology Data Exchange (ETDEWEB)

    Kirschner, Matthew S. [Department; Ding, Wendu [Department; Li, Yuxiu [Center; College; Chapman, Craig T. [Department; Lei, Aiwen [College; Lin, Xiao-Min [Center; Chen, Lin X. [Department; Chemical; Schatz, George C. [Department; Schaller, Richard D. [Department; Center

    2017-12-08

    We demonstrate that coherent acoustic phonons derived from plasmonic nanoparticles can modulate electronic interactions with proximal excitonic molecular species. A series of gold bipyramids with systematically varied aspect ratios and corresponding localized surface plasmon resonance energies, functionalized with a J-aggregated thiacarbocyanine dye molecule, produce two hybridized states that exhibit clear anti-crossing behavior with a Rabi splitting energy of 120 meV. In metal nanoparticles, photoexcitation generates coherent acoustic phonons that cause oscillations in the plasmon resonance energy. In the coupled system, these photo-generated oscillations alter the metal nanoparticle’s energetic contribution to the hybridized system and, as a result, change the coupling between the plasmon and exciton. We demonstrate that such modulations in the hybridization is consistent across a wide range of bipyramid ensembles. We also use Finite-Difference Time Domain calculations to develop a simple model describing this behavior. Such oscillatory plasmonic-excitonic nanomaterials (OPENs) offer a route to manipulate and dynamically-tune the interactions of plasmonic/excitonic systems and unlock a range of potential applications.

  12. Conjugated “Molecular Wire” for Excitons

    Energy Technology Data Exchange (ETDEWEB)

    Shibano, Y.; Miller, J.; Imahori, H.; Sreearunothai, P.; Cook, A.R.

    2010-05-06

    We have synthesized new conjugated, rigid rod oligomers of fluorene, F{sub n}(C{sub 60}){sub 2}, n = 4, 8, 12, and 16. These pure compounds have F{sub n} chains up to 140 {angstrom} long. The C{sub 60} groups covalently attached at both ends serve as traps for excitons created in the F{sub n} chains. Excitons created in the chains by photoexcitation reacted rapidly with the C{sub 60} groups with decays described well by the sum of two exponentials. Mean reaction times were 2.3, 5.5, and 10.4 ps for n = 8, 12, and 16. In F{sub 16}(C{sub 60}){sub 2}, the 10.4 ps reaction time was 40 times faster than that found in earlier reports on molecules of slightly longer length. The simplest possible model, that of one-dimensional diffusion of excitonic polarons that react whenever they encounter the end of a chain, fits the results to obtain diffusion coefficients. Deviations of those fits from the data may point to the need for alternative pictures or may just indicate that diffusion is not ideal. The definite lengths of these molecules enable a stringent test for theories. These results reveal that exciton transport can be much faster than previously believed, a finding that could, along with appropriate nanoassembly, enable new kinds of high-efficiency organic photovoltaics.

  13. Effective models for excitons in carbon nanotubes

    DEFF Research Database (Denmark)

    Cornean, Horia; Duclos, Pierre; Ricaud, Benjamin

    We analyse the low lying spectrum of a model of excitons in carbon nanotubes. Consider two particles with a Coulomb self-interaction, placed on an infinitely long cylinder. If the cylinder radius becomes small, the low lying spectrum is well described by a one-dimensional effective Hamiltonian...

  14. Effective models for excitons in carbon nanotubes

    DEFF Research Database (Denmark)

    Cornean, Horia; Duclos, Pierre; Ricaud, Benjamin

    2007-01-01

    We analyse the low lying spectrum of a model of excitons in carbon nanotubes. Consider two particles with opposite charges and a Coulomb self-interaction, placed on an infinitely long cylinder. If the cylinder radius becomes small, the low lying spectrum of their relative motion is well described...

  15. Coherent quantum dynamics of excitons in monolayer transition metal dichalcogenides

    KAUST Repository

    Moody, Galan

    2016-03-14

    Transition metal dichalcogenides (TMDs) have garnered considerable interest in recent years owing to their layer thickness-dependent optoelectronic properties. In monolayer TMDs, the large carrier effective masses, strong quantum confinement, and reduced dielectric screening lead to pronounced exciton resonances with remarkably large binding energies and coupled spin and valley degrees of freedom (valley excitons). Coherent control of valley excitons for atomically thin optoelectronics and valleytronics requires understanding and quantifying sources of exciton decoherence. In this work, we reveal how exciton-exciton and exciton-phonon scattering influence the coherent quantum dynamics of valley excitons in monolayer TMDs, specifically tungsten diselenide (WSe2), using two-dimensional coherent spectroscopy. Excitation-density and temperature dependent measurements of the homogeneous linewidth (inversely proportional to the optical coherence time) reveal that exciton-exciton and exciton-phonon interactions are significantly stronger compared to quasi-2D quantum wells and 3D bulk materials. The residual homogeneous linewidth extrapolated to zero excitation density and temperature is ~1:6 meV (equivalent to a coherence time of 0.4 ps), which is limited only by the population recombination lifetime in this sample. © (2016) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.

  16. The self-trapping of anion excitons in alkali halides at elastic deformation

    International Nuclear Information System (INIS)

    Tulepbergenov, S.K.; Dzhumanov, S.; Spivak-Lavrov, I.F.; Shunkeev, K.Sh.

    2001-01-01

    The self-trapping of electronic excitations (EE) (excitons, holes and electrons) in alkali halides (AH), fluorides and oxides plays an important roles in luminescence and defect formation. Therein the specific features of self-trapping of EE in various materials are essentially different. In particular, the self-trapping of excitons in some AH (i.e. alkali iodides and bromides) occurs with overcoming of the potential barrier and in other AH (e.g. alkali fluorides and chlorides) such a barrier is absent. Here we develop the continuum theory of self-trapping of within the adiabatic approximation elastically stressed AH. In the continuum model of solids the functional of the total energy of are interacting exciton-phonon system in the deformed ionic crystal just as in the undeformed crystal depends on the dilation Δ(r) described by the deformation potential of acoustic phonon, the electrostatic potential φ[r) due to the lattice polarization at optical lattice vibrations and the wave function of exciton chosen for hydro statically and uniaxially stressed 3D crystals. The functionals of the total energy of the interfacing exciton-phonon system E{Δ(r),φ(r),ψ(r)} are minimized relative to Δ, φ and ψ for the cases of isotropic and anisotropic 3D crystals. As a result, we obtained the functionals depending on μ and determined their possible extremum. We have show that the linear deformations under the hydrostatic and uniaxial stress at 80 K lead to the decreasing of the self trapping barrier for exciton and to the increasing of the luminescence of self-trapped excitons (STE). While the nonlinear deformations under the such stress at 80 K lead to the increasing of the self-trapping barrier for excitons and to the decreasing at the STE luminescence in AH. At T=0 K the small hydrostatic and uniaxial pressures lead to the same effects. Further at hydrostatic and uniaxial compressions of AH the minimums of the adiabatic potentials of quasifree and STE are shifted to

  17. Kiloparsec-scale Simulations of Star Formation in Disk Galaxies. IV. Regulation of Galactic Star Formation Rates by Stellar Feedback

    Energy Technology Data Exchange (ETDEWEB)

    Butler, Michael J. [Max Planck Institute for Astronomy, Königstuhl 17, D-69117 Heidelberg (Germany); Tan, Jonathan C. [Departments of Astronomy and Physics, University of Florida, Gainesville, FL 32611 (United States); Teyssier, Romain; Nickerson, Sarah [Institute for Computational Science, University of Zurich, 8049 Zurich (Switzerland); Rosdahl, Joakim [Leiden Observatory, Leiden University, P.O. Box 9513, NL-2300 RA Leiden (Netherlands); Van Loo, Sven [School of Physics and Astronomy, University of Leeds, Leeds LS2 9JT (United Kingdom)

    2017-06-01

    Star formation from the interstellar medium of galactic disks is a basic process controlling the evolution of galaxies. Understanding the star formation rate (SFR) in a local patch of a disk with a given gas mass is thus an important challenge for theoretical models. Here we simulate a kiloparsec region of a disk, following the evolution of self-gravitating molecular clouds down to subparsec scales, as they form stars that then inject feedback energy by dissociating and ionizing UV photons and supernova explosions. We assess the relative importance of each feedback mechanism. We find that H{sub 2}-dissociating feedback results in the largest absolute reduction in star formation compared to the run with no feedback. Subsequently adding photoionization feedback produces a more modest reduction. Our fiducial models that combine all three feedback mechanisms yield, without fine-tuning, SFRs that are in excellent agreement with observations, with H{sub 2}-dissociating photons playing a crucial role. Models that only include supernova feedback—a common method in galaxy evolution simulations—settle to similar SFRs, but with very different temperatures and chemical states of the gas, and with very different spatial distributions of young stars.

  18. Kiloparsec-scale Simulations of Star Formation in Disk Galaxies. IV. Regulation of Galactic Star Formation Rates by Stellar Feedback

    International Nuclear Information System (INIS)

    Butler, Michael J.; Tan, Jonathan C.; Teyssier, Romain; Nickerson, Sarah; Rosdahl, Joakim; Van Loo, Sven

    2017-01-01

    Star formation from the interstellar medium of galactic disks is a basic process controlling the evolution of galaxies. Understanding the star formation rate (SFR) in a local patch of a disk with a given gas mass is thus an important challenge for theoretical models. Here we simulate a kiloparsec region of a disk, following the evolution of self-gravitating molecular clouds down to subparsec scales, as they form stars that then inject feedback energy by dissociating and ionizing UV photons and supernova explosions. We assess the relative importance of each feedback mechanism. We find that H 2 -dissociating feedback results in the largest absolute reduction in star formation compared to the run with no feedback. Subsequently adding photoionization feedback produces a more modest reduction. Our fiducial models that combine all three feedback mechanisms yield, without fine-tuning, SFRs that are in excellent agreement with observations, with H 2 -dissociating photons playing a crucial role. Models that only include supernova feedback—a common method in galaxy evolution simulations—settle to similar SFRs, but with very different temperatures and chemical states of the gas, and with very different spatial distributions of young stars.

  19. PREFACE: International Conference on Optics of Excitons in Confined Systems

    Science.gov (United States)

    Viña, Luis; Tejedor, Carlos; Calleja, José M.

    2010-01-01

    The OECS11 (International Conference on Optics of Excitons in Confined Systems) was the eleventh of a very successful series of conferences that started in 1987 in Rome (Italy). Afterwards the conference was held at Naxos (Sicily, Italy, 1991), Montpellier (France, 1993), Cortona (Italy, 1995), Göttingen (Germany, 1997), Ascona (Switzerland, 1999), Montpellier (France, 2001), Lecce (Italy, 2003), Southampton (UK, 2005) and Patti (Sicily, Italy, 2007). It is addressed to scientists who lead fundamental and applied research on the optical properties of excitons in novel condensed-matter nanostructures. The 2009 meeting (7-11 September 2009) has brought together a large representation of the world leading actors in this domain, with the aim of stimulating the exchange of ideas, promoting international collaborations, and coordinating research on the newest exciton-related issues such as quantum information science and exciton quantum-collective phenomena. The meeting has included invited lectures, contributed oral presentations and posters, covering the following general topics: low-dimensional heterostructures: quantum wells, quantum wires and quantum dots polaritons quantum optics with excitons and polaritons many-body effects under coherent and incoherent excitation coherent optical spectroscopy quantum coherence and quantum-phase manipulation Bose-Einstein condensation and other collective phenomena excitons in novel materials The OECS 11 was held at the campus of the Universidad Autónoma de Madrid in Cantoblanco. The scientific program was composed of more than 200 contributions divided into 16 invited talks, 44 oral contributions and 3 poster sessions with a total of 150 presentations. The scientific level of the presentations was guaranteed by a selection process where each contribution was rated by three members of the Program Committee. The Conference has gathered 238 participants from 21 different countries, with the following distribution: Germany (43

  20. Direct rate assessment of laccase catalysed radical formation in lignin by electron paramagnetic resonance spectroscopy

    DEFF Research Database (Denmark)

    Munk, Line; Andersen, Mogens Larsen; Meyer, Anne S.

    2017-01-01

    Laccases (EC 1.10.3.2) catalyse removal of an electron and a proton from phenolic hydroxyl groups, including phenolic hydroxyls in lignins, to form phenoxy radicals during reduction of O2. We employed electron paramagnetic resonance spectroscopy (EPR) for real time measurement of such catalytic...... to suspensions of the individual lignin samples produced immediate time and enzyme dose dependent increases in intensity in the EPR signal with g-values in the range 2.0047–2.0050 allowing a direct quantitative monitoring of the radical formation and thus allowed laccase enzyme kinetics assessment on lignin...... formation than the Tv laccase on all three types of lignin substrates. When comparing the equal laccase dose rates on the three lignin substrates the enzymatic radical formation rate on the wheat straw lignin residue was consistently higher than those of the organosolv lignins. The pH-temperature optimum...

  1. Rheokinetics and effect of shear rate on the kinetics of linear polyurethane formation

    NARCIS (Netherlands)

    Navarchian, AH; Picchioni, F; Janssen, LPBM

    In this article, the rheokinetics of polyurethane formation and the influence of shear rate on its kinetics have been studied. Two different linear polyurethane systems with 0% and 100% hard segments are examined in a cone and plate rheometer. The isothermal increase of viscosity during polyurethane

  2. Exciton-polariton in graphene nano-ribbon embedded In semiconductor microcavity

    Energy Technology Data Exchange (ETDEWEB)

    Shojaei, S., E-mail: s_shojaei@tabrizu.ac.ir; Imannezhad, S.

    2016-03-15

    In this paper, we investigated coupling of confined photons in the semiconductor microcavity consists of Distributed Bragg Reflectors (DBR) (Si{sub 3}N{sub 4}/SiO{sub 2} and AlAs/Al{sub 0.1}Ga{sub 0.9}As) with excitons of gapped Armchair Graphene NanoRibbon (A-GNR) that placed at the maximum of electric field amplitude inside the semiconductor microcavity. Our calculations show that the coupling between GNR's exciton and confined photon modes and appearance of vacuum Rabi splitting (VRS), is possible. By the means of Transfer Matrix Method (TMM) we obtain angle dependent reflectance spectrum and Upper, Lower Polariton Branches (UPB&LPB) for the structure. Clear anticrossing between the neutral exciton and the cavity modes with a splitting of about 3 meV obtained that can be enhanced in double-GNR. While, our calculations certify the formation of graphene based exciton-polariton, propose the enhancement of VRS by optimization of relevant parameters to implement the graphene based cavity polaritons in optoelectronic devices.

  3. Annihilation of the triplet excitons in the nanoporous glass matrices

    International Nuclear Information System (INIS)

    Afanasyev, D.A.; Ibrayev, N.Kh.; Saletsky, A.M.; Starokurov, Y.V.; Gun'ko, V.M.; Mikhalovsky, S.V.

    2013-01-01

    The spectra and kinetics of fluorescence decay of 1,2-benzanthracene (1,2-BA) molecular clusters adsorbed in nanoporous borosilicate glasses were investigated. It has been shown that the type of the decay kinetics of delayed fluorescence is determined by the annihilation of triplet excitons in crystalline and percolation clusters. The influence of an external magnetic field on the annihilation rate constant of triplet excitons in the adsorbed 1,2-BA molecules has been studied. The response of the molecular clusters to the magnetic field strongly depends on temperature, pore size and time scale of the observation. Clusters with the crystal structure dominate in the decay kinetics of triplet–triplet annihilation (TTA) and delayed fluorescence in the initial microsecond period of time after excitation. Amorphous clusters determine the form of decay kinetics of delayed fluorescence in the millisecond range. The increase in the pore size and concentration of the adsorbate lead to the dominance of crystalline components. The results presented here can be used to develop techniques for probing the structure of the adsorbed layer in nanoporous systems examining the effect of an external magnetic field on the annihilation delayed fluorescence (ADF) kinetics. Highlights: ► Molecular clusters of 1,2-benzanthracene adsorbed in nanoporous borosilicate glasses. ► Form of decay kinetics of delayed fluorescence. ► Magnetic field effects depend on temperature, pore size and observation time range. ► Clusters with crystal structure and amorphous clusters form in porous glasses

  4. The Reliability of [C II] as a Star Formation Rate Indicator

    Directory of Open Access Journals (Sweden)

    De Looze Ilse

    2011-09-01

    Full Text Available We present a calibration of the star formation rate (SFR as a function of the [C II] 157.74 μm luminosity for a sample of 24 star-forming galaxies in the nearby universe. In order to calibrate the SFR against the line luminosity, we rely on both GALEX FUV data, which is an ideal tracer of the unobscured star formation, and Spitzer MIPS 24 μm, to probe the dust-enshrouded fraction of star formation. For this sample of normal star-forming galaxies, the [C II] luminosity correlates well with the star formation rate. However, the extension of this relation to more quiescent (Hα EW≤10 Å or ultra luminous galaxies (LTIR ≥1012 L⊙ should be handled with caution, since these objects show a non-linearity in the L[C II]-to-LFIR ratio as a function of LFIR (and thus, their star formation activity. Two possible scenarios can be invoked to explain the tight correlation between the [C II] emission and the star formation activity on a global galaxy-scale. The first interpretation could be that the [C II] emission from photo dissociation regions arises from the immediate surroundings of actively star-forming regions and contributes a more or less constant fraction on a global galaxy-scale. Alternatively, we consider the possibility that the [C II] emission is associated to the cold interstellar medium, which advocates an indirect link with the star formation activity in a galaxy through the Schmidt law.

  5. Excitonic singlet-triplet ratios in molecular and polymeric organic materials

    Science.gov (United States)

    Baldo, Marc; Agashe, Shashank; Forrest, Stephen

    2002-03-01

    A simple technique is described for the determination of the internal efficiency and excitonic singlet-triplet formation statistics of electroluminescent organic thin films. The internal efficiency is measured by optically exciting a luminescent film within an electroluminescent device under reverse bias. This gives minimum singlet fractions of (0.20+/-0.03) and (0.19+/-0.04) for tris(8-hydroxyquinoline) aluminum (Alq3) and poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), respectively. These results are discussed in terms of the current understanding of exciton formation within organic materials. We also present measurements of the out-coupling fraction, or the fraction of photons emitted in the forward direction, as a function of the position of the emitting layer within a microcavity.

  6. Effects of non-exciton components excited by broadband pulses on quantum beats in a GaAs/AlAs multiple quantum well

    Science.gov (United States)

    Kojima, Osamu; Iwasaki, Yuki; Kita, Takashi; Akahane, Kouichi

    2017-01-01

    In this study, we report the effect of the excitation of non-exciton components caused by broadband pulses on quantum beat oscillation. Using a spectrally controlled pump pulse, a long-lived oscillation is clearly observed, and the pump-power dependence shows the suppression of the dephasing rate of the oscillation. Our results from incoherent carrier generation using a continuous wave laser demonstrate that the non-exciton components behaving as free carriers increase the oscillation dephasing rate.

  7. Excitonic and photonic processes in materials

    CERN Document Server

    Williams, Richard

    2015-01-01

    This book is expected to present state-of-the-art understanding of a selection of excitonic and photonic processes in useful materials from semiconductors to insulators to metal/insulator nanocomposites, both inorganic and organic.  Among the featured applications are components of solar cells, detectors, light-emitting devices, scintillators, and materials with novel optical properties.  Excitonic properties are particularly important in organic photovoltaics and light emitting devices, as also in questions of the ultimate resolution and efficiency of new-generation scintillators for medical diagnostics,  border security, and nuclear nonproliferation.  Novel photonic and optoelectronic applications benefit from new material combinations and structures to be discussed.

  8. Exciton Polaritons in Microcavities New Frontiers

    CERN Document Server

    Sanvitto, Daniele

    2012-01-01

    In the past decade, there has been a burst of new and fascinating physics associated to the unique properties of two-dimensional exciton polaritons, their recent demonstration of condensation under non-equilibrium conditions and all the related quantum phenomena, which have stimulated extensive research work. This monograph summarizes the current state of the art of research on exciton polaritons in microcavities: their interactions, fast dynamics, spin-dependent phenomena, temporal and spatial coherence, condensation under non-equilibrium conditions, related collective quantum phenomena and most advanced applications. The monograph is written by the most active authors who have strongly contributed to the advances in this area. It is of great interests to both physicists approaching this subject for the first time, as well as a wide audience of experts in other disciplines who want to be updated on this fast moving field.

  9. COSMOLOGICAL EVOLUTION OF LONG GAMMA-RAY BURSTS AND THE STAR FORMATION RATE

    Energy Technology Data Exchange (ETDEWEB)

    Petrosian, Vahé [Department of Physics and KIPAC, Stanford University, Stanford, CA 94305 (United States); Kitanidis, Ellie [Department of Physics, UC Berkeley, Berkeley, CA (United States); Kocevski, Daniel [NASA Goddard Space Flight Center, College Park, MD (United States)

    2015-06-10

    Gamma-ray bursts (GRBs), by virtue of their high luminosities, can be detected up to very high redshifts and therefore can be excellent probes of the early universe. This task is hampered by the fact that most of their characteristics have a broad range, so we first need to obtain an accurate description of the distribution of these characteristics and, especially, their cosmological evolution. We use a sample of about 200 Swift long GRBs with known redshifts to determine the evolution of the luminosity, formation rate, and the general shape of the luminosity function (LF). In contrast to most other forward-fitting methods of treating this problem, we use the Efron–Petrosian methods, which allow a non-parametric determination of the above quantities. We find a relatively strong luminosity evolution, an LF that can be fitted to a broken power law, and an unusually high formation rate at low redshifts, a rate more than one order of magnitude higher than the star formation rate (SFR). On the other hand, our results seem to agree with the almost constant SFR in redshifts 1–3 and the decline above this redshift.

  10. Excitonic transitions in homoepitaxial GaN

    Energy Technology Data Exchange (ETDEWEB)

    Martinez-Criado, G.; Cros, A.; Cantarero, A. [Materials Science Inst. and Dept. of Applied Physics, Univ. of Valencia (Spain); Miskys, C.R.; Ambacher, O.; Stutzmann, M. [Technische Univ. Muenchen, Garching (Germany). Walter-Schottky-Inst. fuer Physikalische Grundlagen der Halbleiterelektronik

    2001-11-08

    The photoluminescence spectrum of a high quality homoepitaxial GaN film has been measured as a function of temperature. As temperature increases the recombination of free excitons dominates the spectra. Their energy shift has successfully fitted in that temperature range by means of the Bose-Einstein expression instead of Varshni's relationship. Values for the parameters of both semi-empirical relations describing the energy shift are reported and compared with the literature. (orig.)

  11. Chiral topological excitons in a Chern band insulator

    Science.gov (United States)

    Chen, Ke; Shindou, Ryuichi

    2017-10-01

    A family of semiconductors called Chern band insulators are shown to host exciton bands with nonzero topological Chern integers and chiral exciton edge modes. Using a prototypical two-band Chern insulator model, we calculate a cross-correlation function to obtain the exciton bands and their Chern integers. The lowest exciton band acquires Chern integers such as ±1 and ±2 in the electronic Chern insulator phase. The nontrivial topology can be experimentally observed both by a nonlocal optoelectronic response of exciton edge modes and by a phase shift in the cross-correlation response due to the bulk mode. Our result suggests that magnetically doped HgTe, InAs/GaSb quantum wells, and (Bi,Sb)2Te3 thin films are promising candidates for a platform of topological excitonics.

  12. Excitons in atomically thin 2D semiconductors and their applications

    Directory of Open Access Journals (Sweden)

    Xiao Jun

    2017-06-01

    Full Text Available The research on emerging layered two-dimensional (2D semiconductors, such as molybdenum disulfide (MoS2, reveals unique optical properties generating significant interest. Experimentally, these materials were observed to host extremely strong light-matter interactions as a result of the enhanced excitonic effect in two dimensions. Thus, understanding and manipulating the excitons are crucial to unlocking the potential of 2D materials for future photonic and optoelectronic devices. In this review, we unravel the physical origin of the strong excitonic effect and unique optical selection rules in 2D semiconductors. In addition, control of these excitons by optical, electrical, as well as mechanical means is examined. Finally, the resultant devices such as excitonic light emitting diodes, lasers, optical modulators, and coupling in an optical cavity are overviewed, demonstrating how excitons can shape future 2D optoelectronics.

  13. Exciton Mapping at Subwavelength Scales in Two-Dimensional Materials

    KAUST Repository

    Tizei, Luiz H. G.

    2015-03-01

    Spatially resolved electron-energy-loss spectroscopy (EELS) is performed at diffuse interfaces between MoS2 and MoSe2 single layers. With a monochromated electron source (20 meV) we successfully probe excitons near the interface by obtaining the low loss spectra at the nanometer scale. The exciton maps clearly show variations even with a 10 nm separation between measurements; consequently, the optical band gap can be measured with nanometer-scale resolution, which is 50 times smaller than the wavelength of the emitted photons. By performing core-loss EELS at the same regions, we observe that variations in the excitonic signature follow the chemical composition. The exciton peaks are observed to be broader at interfaces and heterogeneous regions, possibly due to interface roughness and alloying effects. Moreover, we do not observe shifts of the exciton peak across the interface, possibly because the interface width is not much larger than the exciton Bohr radius.

  14. Exciton–Exciton Annihilation Is Coherently Suppressed in H-Aggregates, but Not in J-Aggregates

    Science.gov (United States)

    2017-01-01

    We theoretically demonstrate a strong dependence of the annihilation rate between (singlet) excitons on the sign of dipole–dipole couplings between molecules. For molecular H-aggregates, where this sign is positive, the phase relation of the delocalized two-exciton wave functions causes a destructive interference in the annihilation probability. For J-aggregates, where this sign is negative, the interference is constructive instead; as a result, no such coherent suppression of the annihilation rate occurs. As a consequence, room temperature annihilation rates of typical H- and J-aggregates differ by a factor of ∼3, while an order of magnitude difference is found for low-temperature aggregates with a low degree of disorder. These findings, which explain experimental observations, reveal a fundamental principle underlying exciton–exciton annihilation, with major implications for technological devices and experimental studies involving high excitation densities. PMID:29190421

  15. Excitons confined in quantum dots spheroidal prolate; Excitones confinados en puntos cuanticos esferoidales prolatos

    Energy Technology Data Exchange (ETDEWEB)

    Corella M, A.; Rosas, R.A.; Marin, J.L.; Riera, R. [Depto. de Fisica, Universidad de Sonora, A.P. 1626, Hermosillo, Sonora (Mexico)

    2004-07-01

    The variational method is used to solve in approximately way the Schroedinger wave equation associated to a Wannier-Mott exciton confined within a spheroidal quantum dot. The confinement effect on the ground-state energy of the electron-hole pair trapped inside a crystallite with this geometry, and with soft or hard walls, is analyzed. The walls can be modeled as finite or infinite potential barriers with suitable border conditions, which will depend on the considered case. The results of this work are compared with those obtained by other authors through more sophisticated methods. A comparison with experimental data of CdS crystallites embedded in materials of different composition is made, too. For a finite potential barrier, a critical size of the crystallite from which the exciton escapes of the quantum dot, is predicted. This is in opposition with the infinite potential barrier model where the exciton never can leave the region where it is confined. (Author)

  16. Microtwin formation in the α phase of duplex titanium alloys affected by strain rate

    International Nuclear Information System (INIS)

    Lin, Yi-Hsiang; Wu, Shu-Ming; Kao, Fang-Hsin; Wang, Shing-Hoa; Yang, Jer-Ren; Yang, Chia-Chih; Chiou, Chuan-Sheng

    2011-01-01

    Research highlights: → The long and dense twins in α phase of SP700 alloy occurring at lower strain rates promote a good ductility. → The deformation in SP700 alloy changed to micro twins-controlled mechanism in α as the strain rate decreases. → The material has time to redistribute the deformed strain between α and β as the strain rate decreases. - Abstract: The effect of tensile strain rate on deformation microstructure was investigated in Ti-6-4 (Ti-6Al-4V) and SP700 (Ti-4.5Al-3V-2Mo-2Fe) of the duplex titanium alloys. Below a strain rate of 10 -2 s -1 , Ti-6-4 alloy had a higher ultimate tensile strength than SP700 alloy. However, the yield strength of SP700 was consistently greater than Ti-6-4 at different strain rates. The ductility of SP700 alloy associated with twin formation (especially at the slow strain rate of 10 -4 s -1 ), always exceeded that of Ti-6-4 alloy at different strain rates. It is caused by a large quantity of deformation twins took place in the α phase of SP700 due to the lower stacking fault energy by the β stabilizer of molybdenum alloying. In addition, the local deformation more was imposed on the α grains from the surrounding β-rich grains by redistributing strain as the strain rate decreased in SP700 duplex alloy.

  17. A sampling approach to biases in conditional probability judgments: beyond base rate neglect and statistical format.

    Science.gov (United States)

    Fiedler, K; Brinkmann, B; Betsch, T; Wild, B

    2000-09-01

    Conditional probability judgments of rare events are often inflated. Early accounts assumed a general deficit in using statistical base rates. More recent approaches predict improvement when problems are presented in frequency format or refer to natural categories. The present theory focuses on sampling processes. Experiment 1 showed that a seeming advantage of frequency over probability formats is due to a confounded factor, the need to mentally transform stimulus samples. An information search paradigm was used in Experiment 2. When sampling by the predictor, the probability to be estimated, p(criterion/predictor), was conserved in the samples and judgments were quite accurate. However, when sampling by the criterion, the low base-rate event was strongly overrepresented, accounting for the entire bias. Judgments were quite sensitive to the sampled data, but failed to take sampling constraints into account, as shown in Experiments 3 and 4.

  18. THE ESTIMATION OF STAR FORMATION RATES AND STELLAR POPULATION AGES OF HIGH-REDSHIFT GALAXIES FROM BROADBAND PHOTOMETRY

    International Nuclear Information System (INIS)

    Lee, Seong-Kook; Ferguson, Henry C.; Somerville, Rachel S.; Wiklind, Tommy; Giavalisco, Mauro

    2010-01-01

    We explore methods to improve the estimates of star formation rates and mean stellar population ages from broadband photometry of high-redshift star-forming galaxies. We use synthetic spectral templates with a variety of simple parametric star formation histories to fit broadband spectral energy distributions. These parametric models are used to infer ages, star formation rates, and stellar masses for a mock data set drawn from a hierarchical semi-analytic model of galaxy evolution. Traditional parametric models generally assume an exponentially declining rate of star formation after an initial instantaneous rise. Our results show that star formation histories with a much more gradual rise in the star formation rate are likely to be better templates, and are likely to give better overall estimates of the age distribution and star formation rate distribution of Lyman break galaxies (LBGs). For B- and V-dropouts, we find the best simple parametric model to be one where the star formation rate increases linearly with time. The exponentially declining model overpredicts the age by 100% and 120% for B- and V-dropouts, on average, while for a linearly increasing model, the age is overpredicted by 9% and 16%, respectively. Similarly, the exponential model underpredicts star formation rates by 56% and 60%, while the linearly increasing model underpredicts by 15% and 22%, respectively. For U-dropouts, the models where the star formation rate has a peak (near z ∼ 3) provide the best match for age-overprediction is reduced from 110% to 26%-and star formation rate-underprediction is reduced from 58% to 22%. We classify different types of star formation histories in the semi-analytic models and show how the biases behave for the different classes. We also provide two-band calibration formulae for stellar mass and star formation rate estimations.

  19. Exciton management in organic photovoltaic multidonor energy cascades.

    Science.gov (United States)

    Griffith, Olga L; Forrest, Stephen R

    2014-05-14

    Multilayer donor regions in organic photovoltaics show improved power conversion efficiency when arranged in decreasing exciton energy order from the anode to the acceptor interface. These so-called "energy cascades" drive exciton transfer from the anode to the dissociating interface while reducing exciton quenching and allowing improved overlap with the solar spectrum. Here we investigate the relative importance of exciton transfer and blocking in a donor cascade employing diphenyltetracene (D1), rubrene (D2), and tetraphenyldibenzoperiflanthene (D3) whose optical gaps monotonically decrease from D1 to D3. In this structure, D1 blocks excitons from quenching at the anode, D2 accepts transfer of excitons from D1 and blocks excitons at the interface between D2 and D3, and D3 contributes the most to the photocurrent due to its strong absorption at visible wavelengths, while also determining the open circuit voltage. We observe singlet exciton Förster transfer from D1 to D2 to D3 consistent with cascade operation. The power conversion efficiency of the optimized cascade OPV with a C60 acceptor layer is 7.1 ± 0.4%, which is significantly higher than bilayer devices made with only the individual donors. We develop a quantitative model to identify the dominant exciton processes that govern the photocurrent generation in multilayer organic structures.

  20. Measurement of Exciton Binding Energy of Monolayer WS2

    Science.gov (United States)

    Chen, Xi; Zhu, Bairen; Cui, Xiaodong

    Excitonic effects are prominent in monolayer crystal of transition metal dichalcogenides (TMDCs) because of spatial confinement and reduced Coulomb screening. Here we use linear differential transmission spectroscopy and two-photon photoluminescence excitation spectroscopy (TP-PLE) to measure the exciton binding energy of monolayer WS2. Peaks for excitonic absorptions of the direct gap located at K valley of the Brillouin zone and transitions from multiple points near Γ point of the Brillouin zone, as well as trion side band are shown in the linear absorption spectra of WS2. But there is no gap between distinct excitons and the continuum of the interband transitions. Strong electron-phonon scattering, overlap of excitons around Γ point and the transfer of the oscillator strength from interband continuum to exciton states make it difficult to resolve the electronic interband transition edge even down to 10K. The gap between excited states of the band-edge exciton and the single-particle band is probed by TP-PLE measurements. And the energy difference between 1s exciton and the single-particle gap gives the exciton binding energy of monolayer WS2 to be about 0.71eV. The work is supported by Area of excellency (AoE/P-04/08), CRF of Hong Kong Research Grant Council (HKU9/CRF/13G) and SRT on New Materials of The University of Hong Kong.

  1. Exciton transport phenomena in monolayer MoS2

    Science.gov (United States)

    Onga, Masaru; Zhang, Yijin; Ideue, Toshiya; Iwasa, Yoshihiro

    Monolayer transition metal dichalcogenides exhibit unique optical phenomena owing to the two-dimensional structure and valley degree of freedom. Many researchers have revealed that excitonic states play an important role in optical response, and have observed the diffusion transport of excitons in this system at room temperature. Here we report exciton transport phenomena in monolayer MoS2 at low temperature through photoluminescence mapping. Our results can provide us a new platform for exciton-based optoelectronics with valley degrees of freedom.

  2. The effect of clouds on photolysis rates and ozone formation in the unpolluted troposphere

    Science.gov (United States)

    Thompson, A. M.

    1984-01-01

    The photochemistry of the lower atmosphere is sensitive to short- and long-term meteorological effects; accurate modeling therefore requires photolysis rates for trace gases which reflect this variability. As an example, the influence of clouds on the production of tropospheric ozone has been investigated, using a modification of Luther's two-stream radiation scheme to calculate cloud-perturbed photolysis rates in a one-dimensional photochemical transport model. In the unpolluted troposphere, where stratospheric inputs of odd nitrogen appear to represent the photochemical source of O3, strong cloud reflectance increases the concentration of NO in the upper troposphere, leading to greatly enhanced rates of ozone formation. Although the rate of these processes is too slow to verify by observation, the calculation is useful in distinguishing some features of the chemistry of regions of differing mean cloudiness.

  3. The Formation Rate of Short Gamma-Ray Bursts and Gravitational Waves

    Science.gov (United States)

    Zhang, G. Q.; Wang, F. Y.

    2018-01-01

    In this paper, we study the luminosity function and formation rate of short gamma-ray bursts (sGRBs). First, we derive the {E}p{--}{L}p correlation using 16 sGRBs with redshift measurements and determine the pseudo redshifts of 284 Fermi sGRBs. Then, we use the Lynden-Bell c‑ method to study the luminosity function and formation rate of sGRBs without any assumptions. A strong evolution of luminosity L{(z)\\propto (1+z)}4.47 is found. After removing this evolution, the luminosity function is {{\\Psi }}(L)\\propto {L}0-0.29+/- 0.01 for dim sGRBs and \\psi (L)\\propto {L}0-1.07+/- 0.01 for bright sGRBs, with the break point 8.26× {10}50 erg s‑1. We also find that the formation rate decreases rapidly at zLIGO and Virgo is {0.85}-0.56+4.82 events yr‑1 for an NS–NS binary.

  4. Effect of potential barrier growth of auto-localized excitons decay on radiation defects in AHC at low lattice symmetry

    International Nuclear Information System (INIS)

    Shunkeev, K.; Sagimbaeva, Sh.; Shunkeev, S.

    2007-01-01

    Effect of auto-localized excitons (ALE) luminescence strengthening is conditioned by two mechanisms: either decrease of potential barrier divided of quasi-free states and auto-localized states or decrease of emission-less channel effectiveness of exciton decay on primary radiation defects. In considered range (80 K) all excitons are only in auto-localized state. Therefore a realization of the first mechanism is improbable, For instant, in KI crystal at 80-100 K luminescence of free exciton is completely putting out, and ALE luminescence has maximal intensity. It is known that in the temperature range when ALE luminescence putting out is beginning an effectiveness of radiation defects is beginning to grow. This effect is related with predominating at that time emission-less exciton decay on radiation defects (F-H pairs). Experimentally by luminescence spectroscopy method activation energy of temperature putting out of ALE in AHC under uniaxial deformation. It is revealed, that increase of activation energy value has observed in a number of crystals: KBr→NaCl→KI→Na Br→CsBr→RbI. It is concluded, that effect of ALE intensity building-up and decrease of effectiveness of radiation defect formation are interpreted by growth of potential barrier of ALE decay into radiation defects under low symmetry of AHC lattice of low-temperature uniaxial deformation

  5. Multiphonon resonant Raman scattering in the semimagnetic semiconductor Cd sub 1 sub - sub x Mn sub x Te: Froehlich and deformation potential exciton-phonon interaction

    CERN Document Server

    Riera, R; Marin, J L; Bergues, J M; Campoy, G

    2003-01-01

    A theory describing multiphonon resonant Raman scattering (MPRRS) processes in wide-gap diluted magnetic semiconductors is presented, with Cd sub 1 sub - sub x Mn sub x Te as an example. The incident radiation frequency omega sub l is taken above the fundamental absorption region. The photoexcited electron and hole make real transitions through the LO phonon, when one considers Froehlich (F) and deformation potential (DP) interactions. The strong exchange interaction, typical of these materials, leads to a large spin splitting of the exciton states in the magnetic field. Neglecting Landau quantization, this Zeeman splitting gives rise to the formation of eight bands (two conduction and six valence ones) and ten different exciton states according to the polarization of the incident light. Explicit expressions for the MPRRS intensity of second and third order, the indirect creation and annihilation probabilities, the exciton lifetime, and the probabilities of transition between different exciton states and diff...

  6. Charge transport through exciton shelves in cadmium chalcogenide quantum dot-DNA nano-bioelectronic thin films

    Energy Technology Data Exchange (ETDEWEB)

    Goodman, Samuel M.; Singh, Vivek [Department of Chemical and Biological Engineering, University of Colorado Boulder, 3415 Colorado Avenue, Boulder, Colorado 80303 (United States); Noh, Hyunwoo [Department of Chemical and Biological Engineering, University of Colorado Boulder, 3415 Colorado Avenue, Boulder, Colorado 80303 (United States); Materials Science and Engineering Program and Department of Nanoengineering, University of California, 9500 Gilman Drive, La Jolla, San Diego, California 92093 (United States); Cha, Jennifer N. [Department of Chemical and Biological Engineering, University of Colorado Boulder, 3415 Colorado Avenue, Boulder, Colorado 80303 (United States); Materials Science and Engineering Program and Department of Nanoengineering, University of California, 9500 Gilman Drive, La Jolla, San Diego, California 92093 (United States); Materials Science and Engineering, University of Colorado Boulder, 3415 Colorado Avenue, Boulder, Colorado 80303 (United States); Nagpal, Prashant, E-mail: pnagpal@colorado.edu [Department of Chemical and Biological Engineering, University of Colorado Boulder, 3415 Colorado Avenue, Boulder, Colorado 80303 (United States); Materials Science and Engineering, University of Colorado Boulder, 3415 Colorado Avenue, Boulder, Colorado 80303 (United States); BioFrontiers Institute, University of Colorado Boulder, 3415 Colorado Avenue, Boulder, Colorado 80303 (United States); Renewable and Sustainable Energy Institute, University of Colorado Boulder, 2445 Kittredge Loop, Boulder, Colorado 80309 (United States)

    2015-02-23

    Quantum dot (QD), or semiconductor nanocrystal, thin films are being explored for making solution-processable devices due to their size- and shape-tunable bandgap and discrete higher energy electronic states. While DNA has been extensively used for the self-assembly of nanocrystals, it has not been investigated for the simultaneous conduction of multiple energy charges or excitons via exciton shelves (ES) formed in QD-DNA nano-bioelectronic thin films. Here, we present studies on charge conduction through exciton shelves, which are formed via chemically coupled QDs and DNA, between electronic states of the QDs and the HOMO-LUMO levels in the complementary DNA nucleobases. While several challenges need to be addressed in optimizing the formation of devices using QD-DNA thin films, a higher charge collection efficiency for hot-carriers and our detailed investigations of charge transport mechanism in these thin films highlight their potential for applications in nano-bioelectronic devices and biological transducers.

  7. Final Report, DOE grant DE-FG02-99ER45780, "Indirect Excitons in Coupled Quantum Wells"

    Energy Technology Data Exchange (ETDEWEB)

    Snoke, david W. [University of Pittsburgh

    2014-07-21

    The is the final technical report for this project, which was funded by the DOE from 1999 to 2012. The project focused on experimental studies of spatially indirect excitons in coupled quantum wells, with the aim of understanding the quantum physics of these particles, including such effects as pattern formation due to electron-hole charge separation, the Mott plasma-insulator transition, luminescence up-conversion through field-assisted tunneling, luminescence line shifts due to many-body renormalization and magnetic field effects on tunneling, and proposed effects such as Bose-Einstein condensation of indirect excitons and phase separation of bright and dark indirect excitons. Significant results are summarized here and the relation to other work is discussed.

  8. OH{sup +} in astrophysical media: state-to-state formation rates, Einstein coefficients and inelastic collision rates with He

    Energy Technology Data Exchange (ETDEWEB)

    Gómez-Carrasco, Susana [Facultad de Química, Unidad Asociada CSIC-USAL, Universidad de Salamanca, E-37008 Salamanca (Spain); Godard, Benjamin [LERMA, CNRS UMR 8112, Observatoire de Paris, F-92195 Meudon (France); Lique, François [LOMC-UMR 6294, CNRS-Université du Havre, 25 rue Philippe Lebon, BP 540, F-76058 Le Havre (France); Bulut, Niyazi [Department of Physics, Firat University, 23169 Elazig (Turkey); Kłos, Jacek [Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742-2021 (United States); Roncero, Octavio [Instituto de Física Fundamental (IFF-CSIC), C.S.I.C., Serrano 123, E-28006 Madrid (Spain); Aguado, Alfredo [Facultad de Ciencias, Unidad Asociada de Química-Física Aplicada CSIC-UAM, Universidad Autónoma de Madrid, E-28049 Madrid (Spain); Aoiz, F. Javier; Castillo, Jesús F. [Departamento de Química Física I, Unidad Asociada de Química-Física CSIC-UCM, Facultad de Química, Universidad Complutense de Madrid, E-28040 Madrid (Spain); Goicoechea, Javier R.; Etxaluze, Mireya; Cernicharo, José, E-mail: octavio.roncero@csic.es [Instituto de Ciencia de Materiales (ICMM-CSIC), C.S.I.C., Sor Juana Inés de la Cruz, 3, Cantoblanco, E-28049 Madrid (Spain)

    2014-10-10

    The rate constants required to model the OH{sup +} observations in different regions of the interstellar medium have been determined using state of the art quantum methods. First, state-to-state rate constants for the H{sub 2}(v = 0, J = 0, 1) + O{sup +}({sup 4} S) → H + OH{sup +}(X {sup 3}Σ{sup –}, v', N) reaction have been obtained using a quantum wave packet method. The calculations have been compared with time-independent results to assess the accuracy of reaction probabilities at collision energies of about 1 meV. The good agreement between the simulations and the existing experimental cross sections in the 0.01-1 eV energy range shows the quality of the results. The calculated state-to-state rate constants have been fitted to an analytical form. Second, the Einstein coefficients of OH{sup +} have been obtained for all astronomically significant rovibrational bands involving the X {sup 3}Σ{sup –} and/or A {sup 3}Π electronic states. For this purpose, the potential energy curves and electric dipole transition moments for seven electronic states of OH{sup +} are calculated with ab initio methods at the highest level, including spin-orbit terms, and the rovibrational levels have been calculated including the empirical spin-rotation and spin-spin terms. Third, the state-to-state rate constants for inelastic collisions between He and OH{sup +}(X {sup 3}Σ{sup –}) have been calculated using a time-independent close coupling method on a new potential energy surface. All these rates have been implemented in detailed chemical and radiative transfer models. Applications of these models to various astronomical sources show that inelastic collisions dominate the excitation of the rotational levels of OH{sup +}. In the models considered, the excitation resulting from the chemical formation of OH{sup +} increases the line fluxes by about 10% or less depending on the density of the gas.

  9. Research on Mixed Data Rate and Format Transmission in WDM Networks

    Directory of Open Access Journals (Sweden)

    LI Hong-an

    2013-03-01

    Full Text Available To meet the growing data traffic demands in the telecommunication applications, the number of wavelengths is to be increased in a fiber-optic backbone of the telecommunication network. The exponential growth of internet services, transmission capacity is a tremendous challenge to networks.   Nowadays, 10 Gb/s transmission systems are being used for commercial applications.  At the same time, the non-linear effects such as FWM, SRS, XPM, SPM, and Dispersion are also increased, when the number of wavelengths passing through the single fiber is increased. The analysis of efficient modulation formats for   DWDM system and    long-haul transmission system, we go for various modulations for DWDM system. The maimum data rate for NRZ-OOK modulation format is 10 Gb/s. For RZ-OOK the maximum rate is 50 Gb/s.  Since RZ-OOK modulation uses twice the band width when compared to NRZ-OOK modulation. The modulation format is partially upgraded from OOK to PSK, the influence of OOK signals on the updated PSK signals must be considered when using multi-channel wavelength conversion. The PSK modulation is also analyzed.

  10. Symmetry of learning rate in synaptic plasticity modulates formation of flexible and stable memories.

    Science.gov (United States)

    Park, Youngjin; Choi, Woochul; Paik, Se-Bum

    2017-07-18

    Spike-timing-dependent plasticity (STDP) is considered critical to learning and memory functions in the human brain. Across various types of synapse, STDP is observed as different profiles of Hebbian and anti-Hebbian learning rules. However, the specific roles of diverse STDP profiles in memory formation still remain elusive. Here, we show that the symmetry of the learning rate profile in STDP is crucial to determining the character of stored memory. Using computer simulations, we found that an asymmetric learning rate generates flexible memory that is volatile and easily overwritten by newly appended information. Moreover, a symmetric learning rate generates stable memory that can coexist with newly appended information. In addition, by combining these two conditions, we could realize a hybrid memory type that operates in a way intermediate between stable and flexible memory. Our results demonstrate that various attributes of memory functions may originate from differences in the synaptic stability.

  11. Optical studies of charged excitons in II-VI semiconductor quantum wells

    CERN Document Server

    Kossacki, P

    2003-01-01

    A brief review is given of optical studies of doped II-VI quantum wells. The properties of exciton states, neutral as well as positively and negatively charged, are discussed. A wide range of optical measurements is presented: CW as well as picosecond and femtosecond time-resolved absorption, photoluminescence (PL) and PL excitation. The experiments were performed at various carrier concentrations (> 10 sup 1 sup 1 cm sup - sup 2) and temperatures (up to a few tens of kelvins). This review is limited to zero or low magnetic fields, used only to polarize spins of carriers. We discuss the obtained values of various fundamental parameters of the excitonic states: energies, optical transition probabilities and characteristic times of their formation, thermalization and decay. (topical review)

  12. Exciton–exciton annihilation and biexciton stimulated emission in graphene nanoribbons

    Science.gov (United States)

    Soavi, Giancarlo; Dal Conte, Stefano; Manzoni, Cristian; Viola, Daniele; Narita, Akimitsu; Hu, Yunbin; Feng, Xinliang; Hohenester, Ulrich; Molinari, Elisa; Prezzi, Deborah; Müllen, Klaus; Cerullo, Giulio

    2016-01-01

    Graphene nanoribbons display extraordinary optical properties due to one-dimensional quantum-confinement, such as width-dependent bandgap and strong electron–hole interactions, responsible for the formation of excitons with extremely high binding energies. Here we use femtosecond transient absorption spectroscopy to explore the ultrafast optical properties of ultranarrow, structurally well-defined graphene nanoribbons as a function of the excitation fluence, and the impact of enhanced Coulomb interaction on their excited states dynamics. We show that in the high-excitation regime biexcitons are formed by nonlinear exciton–exciton annihilation, and that they radiatively recombine via stimulated emission. We obtain a biexciton binding energy of ≈250 meV, in very good agreement with theoretical results from quantum Monte Carlo simulations. These observations pave the way for the application of graphene nanoribbons in photonics and optoelectronics. PMID:26984281

  13. Southern Ocean frontal structure and sea-ice formation rates revealed by elephant seals

    Science.gov (United States)

    Charrassin, J.-B.; Hindell, M.; Rintoul, S. R.; Roquet, F.; Sokolov, S.; Biuw, M.; Costa, D.; Boehme, L.; Lovell, P.; Coleman, R.; Timmermann, R.; Meijers, A.; Meredith, M.; Park, Y.-H.; Bailleul, F.; Goebel, M.; Tremblay, Y.; Bost, C.-A.; McMahon, C. R.; Field, I. C.; Fedak, M. A.; Guinet, C.

    2008-01-01

    Polar regions are particularly sensitive to climate change, with the potential for significant feedbacks between ocean circulation, sea ice, and the ocean carbon cycle. However, the difficulty in obtaining in situ data means that our ability to detect and interpret change is very limited, especially in the Southern Ocean, where the ocean beneath the sea ice remains almost entirely unobserved and the rate of sea-ice formation is poorly known. Here, we show that southern elephant seals (Mirounga leonina) equipped with oceanographic sensors can measure ocean structure and water mass changes in regions and seasons rarely observed with traditional oceanographic platforms. In particular, seals provided a 30-fold increase in hydrographic profiles from the sea-ice zone, allowing the major fronts to be mapped south of 60°S and sea-ice formation rates to be inferred from changes in upper ocean salinity. Sea-ice production rates peaked in early winter (April–May) during the rapid northward expansion of the pack ice and declined by a factor of 2 to 3 between May and August, in agreement with a three-dimensional coupled ocean–sea-ice model. By measuring the high-latitude ocean during winter, elephant seals fill a “blind spot” in our sampling coverage, enabling the establishment of a truly global ocean-observing system. PMID:18695241

  14. Modeling the Effect of Finite-Rate Hydrogen Diffusion on Porosity Formation in Aluminum Alloys

    Science.gov (United States)

    Carlson, Kent D.; Lin, Zhiping; Beckermann, Christoph

    2007-08-01

    A volume-averaged model for finite-rate diffusion of hydrogen in the melt is developed to predict pore formation during the solidification of aluminum alloys. The calculation of the micro-/macro-scale gas species transport in the melt is coupled with a model for the feeding flow and pressure field. The rate of pore growth is shown to be proportional to the local level of gas supersaturation in the melt, as well as various microstructural parameters. Parametric studies of one-dimensional solidification under an imposed temperature gradient and cooling rate illustrate that the model captures important phenomena observed in porosity formation in aluminum alloys. The transition from gas to shrinkage dominated porosity and the effects of different solubilities of hydrogen in the eutectic solid, capillary pressures at pore nucleation, and pore number densities are investigated in detail. Comparisons between predicted porosity percentages and previous experimental measurements show good correspondence, although some uncertainties remain regarding the extent of impingement of solid on the pores.

  15. Optics of exciton-plasmon nanomaterials

    Science.gov (United States)

    Sukharev, Maxim; Nitzan, Abraham

    2017-11-01

    This review provides a brief introduction to the physics of coupled exciton-plasmon systems, the theoretical description and experimental manifestation of such phenomena, followed by an account of the state-of-the-art methodology for the numerical simulations of such phenomena and supplemented by a number of FORTRAN codes, by which the interested reader can introduce himself/herself to the practice of such simulations. Applications to CW light scattering as well as transient response and relaxation are described. Particular attention is given to so-called strong coupling limit, where the hybrid exciton-plasmon nature of the system response is strongly expressed. While traditional descriptions of such phenomena usually rely on analysis of the electromagnetic response of inhomogeneous dielectric environments that individually support plasmon and exciton excitations, here we explore also the consequences of a more detailed description of the molecular environment in terms of its quantum density matrix (applied in a mean field approximation level). Such a description makes it possible to account for characteristics that cannot be described by the dielectric response model: the effects of dephasing on the molecular response on one hand, and nonlinear response on the other. It also highlights the still missing important ingredients in the numerical approach, in particular its limitation to a classical description of the radiation field and its reliance on a mean field description of the many-body molecular system. We end our review with an outlook to the near future, where these limitations will be addressed and new novel applications of the numerical approach will be pursued.

  16. Molecular weight dependence of exciton diffusion in poly(3-hexylthiophene)

    DEFF Research Database (Denmark)

    Masri, Zarifi; Ruseckas, Arvydas; Emelianova, Evguenia V.

    2013-01-01

    A joint experimental and theoretical study of singlet exciton diffusion in spin-coated poly(3-hexylthiophene) (P3HT) films and its dependence on molecular weight is presented. The results show that exciton diffusion is fast along the co-facial π–π aggregates of polymer chromophores and about 100...

  17. Exciton ionization in multilayer transition-metal dichalcogenides

    DEFF Research Database (Denmark)

    Pedersen, Thomas Garm; Latini, Simone; Thygesen, Kristian Sommer

    2016-01-01

    Photodetectors and solar cells based on materials with strongly bound excitons rely crucially on field-assisted exciton ionization. We study the ionization process in multilayer transition-metal dichalcogenides (TMDs) within the Mott-Wannier model incorporating fully the pronounced anisotropy...

  18. Bose Condensation of Interwell Excitons in Double Quantum Wells

    DEFF Research Database (Denmark)

    Larionov, A. V.; Timofeev, V. B.; Ni, P. A.

    2002-01-01

    in the domain. With a rise in temperature, this line disappears from the spectrum (Tc 3.4 K). The observed phenomenon is attributed to Bose–Einstein condensation in a quasi-two-dimensional system of interwell excitons. In the temperature range studied (1.5–3.4 K), the critical exciton density and temperature...

  19. Exciton dephasing in ZnSe quantum wires

    DEFF Research Database (Denmark)

    Wagner, Hans Peter; Langbein, Wolfgang Werner; Hvam, Jørn Märcher

    1998-01-01

    The homogeneous linewidths of excitons in wet-etched ZnSe quantum wires of lateral sizes down to 23 nm are studied by transient four-wave mixing. The low-density dephasing time is found to increase with decreasing wire width. This is attributed mainly to a reduction of electron-exciton scattering...

  20. Directing energy transport in organic photovoltaic cells using interfacial exciton gates.

    Science.gov (United States)

    Menke, S Matthew; Mullenbach, Tyler K; Holmes, Russell J

    2015-04-28

    Exciton transport in organic semiconductors is a critical, mediating process in many optoelectronic devices. Often, the diffusive and subdiffusive nature of excitons in these systems can limit device performance, motivating the development of strategies to direct exciton transport. In this work, directed exciton transport is achieved with the incorporation of exciton permeable interfaces. These interfaces introduce a symmetry-breaking imbalance in exciton energy transfer, leading to directed motion. Despite their obvious utility for enhanced exciton harvesting in organic photovoltaic cells (OPVs), the emergent properties of these interfaces are as yet uncharacterized. Here, directed exciton transport is conclusively demonstrated in both dilute donor and energy-cascade OPVs where judicious optimization of the interface allows exciton transport to the donor-acceptor heterojunction to occur considerably faster than when relying on simple diffusion. Generalized systems incorporating multiple exciton permeable interfaces are also explored, demonstrating the ability to further harness this phenomenon and expeditiously direct exciton motion, overcoming the diffusive limit.

  1. Bistable Topological Insulator with Exciton-Polaritons

    Science.gov (United States)

    Kartashov, Yaroslav V.; Skryabin, Dmitry V.

    2017-12-01

    The functionality of many nonlinear and quantum optical devices relies on the effect of optical bistability. Using microcavity exciton-polaritons in a honeycomb arrangement of microcavity pillars, we report the resonance response and bistability of topological edge states. A balance between the pump, loss, and nonlinearity ensures a broad range of dynamical stability and controls the distribution of power between counterpropagating states on the opposite edges of the honeycomb lattice stripe. Tuning energy and polarization of the pump photons, while keeping their momentum constant, we demonstrate control of the propagation direction of the dominant edge state. Our results facilitate the development of practical applications of topological photonics.

  2. Mercury's Hollows: Depths, Estimation of Formation Rates, and the Nature of the Bright Haloes

    Science.gov (United States)

    Blewett, D. T.; Stadermann, A. C.; Chabot, N. L.; Denevi, B. W.; Ernst, C. M.; Xiao, Z.; Solomon, S. C.

    2015-12-01

    Mercury's hollows are shallow depressions, often with high-reflectance interiors and haloes. The fresh appearance of hollows indicates that they are relatively young features. Their morphology is suggestive of formation via sublimation-like loss of a volatile-bearing phase through solar heating, destruction by UV photolysis, contact with molten rock, or bombardment by micrometeoroids and/or ions. Hollows are found within the low-reflectance material (LRM) color unit. Following an examination of all MESSENGER images with pixel sizes hollows. The mean depth is 24 ± 16 m. The narrow range of depths, despite formation within LRM units that are of much greater and more variable thickness, could result from development of a protective lag as the volatile-bearing phase is lost. The rate at which hollows form may be estimated as follows. The size-frequency distribution of Mercury rayed craters >4 km in diameter gives absolute model ages of 110 to 689 Ma, depending on the crater production model. The 41-km-diameter rayed crater Balanchine has a density of superposed craters similar to the average for all rayed craters, so we take Balanchine's age to be the population average. Hollows on Balanchine's floor are ~300 m wide. The average rate of hollows formation by horizontal scarp retreat for a 110 Ma model age would be 1 cm per 3700 Earth years. If Balanchine formed 689 Ma ago, then the average growth rate would be 1 cm per 23,000 yr. We also consider the mechanisms by which hollows form bright haloes. Calculations show that comet-style lofting of dust by sublimating gas is not important given Mercury's high surface gravitational acceleration. Instead, the bright haloes may form by condensation of sublimated material or by physical modification or chemical alteration of the surface by re-deposited sublimation products.

  3. Continuum contribution to excitonic four-wave mixing due to interaction-induced nonlinearities: A numerical study

    Science.gov (United States)

    El Sayed, K.; Birkedal, D.; Lyssenko, V. G.; Hvam, J. M.

    1997-01-01

    We present a theoretical investigation of ultrafast transient four-wave mixing (FWM) of GaAs quantum wells for coherent excitation of excitons and a large number of continuum states. It is shown that in this case the line shape of the FWM signal is drastically altered due to an interaction-induced coupling of the exciton to all the excited continuum states. The signal is dominantly emitted at the spectral position of the exciton and decays, as a function of delay, on a time scale set by the duration of the laser pulse rather than by the intrinsic dephasing time. Nevertheless, the spectral width of the exciton line in the FWM spectrum and in the decay of the time-resolved FWM signal in real time are governed by the intrinsic excitonic dephasing rate. It is shown that for pulse durations of ~ 100 fs (for GaAs quantum wells) this behavior can be explained as the influence of the Coulomb exchange interaction, while for even shorter pulses this behavior is dominantly caused by nonlinear polarization decay.

  4. Rate of formation of neutron stars in the galaxy estimated from stellar statistics

    International Nuclear Information System (INIS)

    Endal, A.S.

    1979-01-01

    Stellar statistics and stellar evolution models can be used to estimate the rate of formation of neutron stars in the Galaxy. A recent analysis by Hills suggests that the mean interval between neutron-star births is greater than 27 years. This is incompatible with estimates based on pulsar statistics. However, a closer examination of the stellar data shows that Hill's result is incorrect. A mean interval between neutron-star births as short as 4 years is consistent with (though certainly not required by) stellar evolution theory

  5. The empirical role of the exchange rate on the crude-oil price formation

    International Nuclear Information System (INIS)

    Yousefi, A.; Wirjanto, T.S.; University of Waterloo, Ont.

    2004-01-01

    This paper adopts a novel empirical approach to the crude-oil price formation for the purpose of understanding the price reactions of OPEC member countries to changes in the exchange rate of the US dollar against other major currencies and prices of other members. The results are broadly consistent with the view of the absence of a unified OPEC determined price in the international crude market literature. In addition, the results also highlight a cross regional dimension of the crude oil market. (author)

  6. Supernova Driving. IV. The star-formation rate of molecular clouds

    DEFF Research Database (Denmark)

    Padoan, Paolo; Haugbølle, Troels; Nordlund, Åke

    2017-01-01

    We compute the star-formation rate (SFR) in molecular clouds (MCs) that originate ab initio in a new, higher-resolution simulation of supernova-driven turbulence. Because of the large number of well-resolved clouds with self-consistent boundary and initial conditions, we obtain a large range...... simulations, and compare a revised version of our turbulent fragmentation model with the numerical results. The dependences on Mach number, ℳ, gas to magnetic pressure ratio, β, and compressive to solenoidal power ratio, χ at fixed αvir are not well constrained, because of random scatter due to time and cloud...

  7. Excitons in single-walled carbon nanotubes: environmental effect

    International Nuclear Information System (INIS)

    Smyrnov, O.A.

    2010-01-01

    The properties of excitons in semiconducting single-walled carbon nanotubes (SWCNTs) isolated in vacuum or a medium and their contributions to the optical spectra of nanotubes are studied within the elementary potential model, in which an exciton is represented as a bound state of two oppositely charged quasiparticles confined to the nanotube surface. The emphasis is given on the influence of the dielectric environment surrounding a nanotube on the exciton spectra. For nanotubes in the environment with a permittivity less than ∼ 1:8; the ground-state exciton binding energies exceed the respective energy gaps, whereas the obtained binding energies of excitons in nanotubes in a medium with permittivity greater than ∼ 4 are in good accordance with the corresponding experimental data and consistent with the known scaling relation for the environmental effect. The stabilization of a single-electron spectrum in SWCNTs in media with rather low permittivities is discussed.

  8. Similar star formation rate and metallicity variability timescales drive the fundamental metallicity relation

    Science.gov (United States)

    Torrey, Paul; Vogelsberger, Mark; Hernquist, Lars; McKinnon, Ryan; Marinacci, Federico; Simcoe, Robert A.; Springel, Volker; Pillepich, Annalisa; Naiman, Jill; Pakmor, Rüdiger; Weinberger, Rainer; Nelson, Dylan; Genel, Shy

    2018-03-01

    The fundamental metallicity relation (FMR) is a postulated correlation between galaxy stellar mass, star formation rate (SFR), and gas-phase metallicity. At its core, this relation posits that offsets from the mass-metallicity relation (MZR) at a fixed stellar mass are correlated with galactic SFR. In this Letter, we use hydrodynamical simulations to quantify the timescales over which populations of galaxies oscillate about the average SFR and metallicity values at fixed stellar mass. We find that Illustris and IllustrisTNG predict that galaxy offsets from the star formation main sequence and MZR oscillate over similar timescales, are often anti-correlated in their evolution, evolve with the halo dynamical time, and produce a pronounced FMR. Our models indicate that galaxies oscillate about equilibrium SFR and metallicity values - set by the galaxy's stellar mass - and that SFR and metallicity offsets evolve in an anti-correlated fashion. This anti-correlated variability of the metallicity and SFR offsets drives the existence of the FMR in our models. In contrast to Illustris and IllustrisTNG, we speculate that the SFR and metallicity evolution tracks may become decoupled in galaxy formation models dominated by feedback-driven globally-bursty SFR histories, which could weaken the FMR residual correlation strength. This opens the possibility of discriminating between bursty and non-bursty feedback models based on the strength and persistence of the FMR - especially at high redshift.

  9. Formation of sulfuric and nitric acid in the atmosphere during long-rate transport

    Energy Technology Data Exchange (ETDEWEB)

    Rodhe, H. (University of Stockholm (Sweden)); Crutzen, P. (Max-Plank Institut fuer Chemie, Mainz (Germany, F.R.)); Vanderpol, A. (Metereology Research Inc., Atladena, CA (USA))

    1981-04-01

    A simple photochemical model has been used to simulate the formation of sulfuric acid and nitric acid during long-range transport through the atmosphere. Comparisons have been made with observations of sulfate and nitrate in precipitation at various distances from the source areas in northern Europe. Both observations and model calculations indicate that HNO/sub 3/ is formed at a faster rate than H/sub 2/SO/sub 4/ and that the long-range transport of HNO/sub 3/ is thus somewhat less than that of H/sub 2/SO/sub 4/. Mainly because of the common dependence of the oxidation of SO/sub 2/ and NO/sub x/ on the concentration of the OH radical, the concentration of NO/sub x/ has a significant influence on the rate of formation of H/sub 2/SO/sub 4/: A higher emission of NO/sub x/ tends to reduce the levels of OH and H/sub 2/O/sub 2/ close to the source area thereby delaying and decreasing the transformation of SO/sub 2/ to H/sub 2/SO/sub 4/. Because of the interactions of the chemical species, the dependence of the concentrations on emission rates is not linear. Our model suggests that the concentrations of H/sub 2/SO/sub 4/ at travel distances up to a few tens of hours should have increased significantly less over the last 20 years then the rates of emissions of SO/sub 2/. This also seems to be brought out by observations of sulfate in precipitation.

  10. Scoring rules and rating formats of Self-report Depression Questionnaires: a comparison of approaches.

    Science.gov (United States)

    Zimmerman, Mark; D'Avanzato, Catherine; Attiullah, Naureen; Friedman, Michael; Toba, Cristina; Boerescu, Daniela A

    2014-08-15

    Self-report measures of depression differ in their construction and scoring rules. In the present study from the Rhode Island Methods to Improve Diagnostic Assessment and Services (MIDAS) project we tested the hypothesis that the loss of information due to scoring rules or rating formats reduces the validity of depression severity assessment. One hundred fifty-three outpatients with DSM-IV major depressive disorder (MDD) who presented for treatment or who were in ongoing treatment and had their medication changed due to lack of efficacy completed the Clinically Useful Depression Outcome Scale (CUDOS), Quick Inventory of Depressive Symptomatology (QIDS) and Remission from Depression Questionnaire (RDQ) at the initiation of treatment and 4 month follow-up. The patients were evaluated with the 17-item Hamilton Depression scale (HAMD). The CUDOS and RDQ were equally highly correlated with the HAMD at baseline and follow-up. There was no significant difference in the correlations between the modified and original scoring algorithms of the QIDS with the HAMD at baseline and the follow-up. On each scale, the patients showed significant levels of improvement from baseline to 4 months, and the effect sizes were similar. These findings suggest that the loss of information due to the scoring rules of the QIDS or the rating format of the RDQ did not reduce the validity of depression severity assessment. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.

  11. Free energy of cluster formation and a new scaling relation for the nucleation rate

    International Nuclear Information System (INIS)

    Tanaka, Kyoko K.; Tanaka, Hidekazu; Diemand, Jürg; Angélil, Raymond

    2014-01-01

    Recent very large molecular dynamics simulations of homogeneous nucleation with (1 − 8) × 10 9 Lennard-Jones atoms [J. Diemand, R. Angélil, K. K. Tanaka, and H. Tanaka, J. Chem. Phys. 139, 074309 (2013)] allow us to accurately determine the formation free energy of clusters over a wide range of cluster sizes. This is now possible because such large simulations allow for very precise measurements of the cluster size distribution in the steady state nucleation regime. The peaks of the free energy curves give critical cluster sizes, which agree well with independent estimates based on the nucleation theorem. Using these results, we derive an analytical formula and a new scaling relation for nucleation rates: ln J ′ /η is scaled by ln S/η, where the supersaturation ratio is S, η is the dimensionless surface energy, and J ′ is a dimensionless nucleation rate. This relation can be derived using the free energy of cluster formation at equilibrium which corresponds to the surface energy required to form the vapor-liquid interface. At low temperatures (below the triple point), we find that the surface energy divided by that of the classical nucleation theory does not depend on temperature, which leads to the scaling relation and implies a constant, positive Tolman length equal to half of the mean inter-particle separation in the liquid phase

  12. PbSe Nanocrystal Excitonic Solar Cells

    KAUST Repository

    Choi, Joshua J.

    2009-11-11

    We report the design, fabrication, and characterization of colloidal PbSe nanocrystal (NC)-based photovoltaic test structures that exhibit an excitonic solar cell mechanism. Charge extraction from the NC active layer is driven by a photoinduced chemical potential energy gradient at the nanostructured heterojunction. By minimizing perturbation to PbSe NC energy levels and thereby gaining insight into the "intrinsic" photovoltaic properties and charge transfer mechanism of PbSe NC, we show a direct correlation between interfacial energy level offsets and photovoltaic device performance. Size dependent PbSe NC energy levels were determined by cyclic voltammetry and optical spectroscopy and correlated to photovoltaic measurements. Photovoltaic test structures were fabricated from PbSe NC films sandwiched between layers of ZnO nanoparticles and PEDOT:PSS as electron and hole transporting elements, respectively. The device current-voltage characteristics suggest a charge separation mechanism that Is distinct from previously reported Schottky devices and consistent with signatures of excitonic solar cells. Remarkably, despite the limitation of planar junction structure, and without film thickness optimization, the best performing device shows a 1-sun power conversion efficiency of 3.4%, ranking among the highest performing NC-based solar cells reported to date. © 2009 American Chemical Society.

  13. Exciton coherence in semiconductor quantum dots

    International Nuclear Information System (INIS)

    Ishi-Hayase, Junko; Akahane, Kouichi; Yamamoto, Naokatsu; Sasaki, Masahide; Kujiraoka, Mamiko; Ema, Kazuhiro

    2009-01-01

    The coherent dynamics of excitons in InAs quantum dots (QDs) was investigated in the telecommunication wavelength range using a transient four-wave mixing technique. The sample was fabricated on an InP(311)B substrate using strain compensation to control the emission wavelength. This technique also enabled us to fabricate a 150-layer stacked QD structure for obtaining a high S/N in the four-wave mixing measurements, although no high-sensitive heterodyne detection was carried out. The dephasing time and transition dipole moment were precisely estimated from the polarization dependence of signals, taking into account their anisotropic properties. The population lifetimes of the excitons were also measured by using a polarization-dependent pumpprobe technique. A quantitative comparison of these anisotropies demonstrates that in our QDs, non-radiative population relaxation, polarization relaxation and pure dephasing are considerably smaller than the radiative relaxation. A comparison of the results of the four-wave mixing and pump-probe measurements revealed that the pure dephasing could be directly estimated with an accuracy of greater than 0.1 meV by comparing the results of four-wave mixing and pump-probe measurements. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  14. LOFAR/H-ATLAS: the low-frequency radio luminosity-star formation rate relation

    Science.gov (United States)

    Gürkan, G.; Hardcastle, M. J.; Smith, D. J. B.; Best, P. N.; Bourne, N.; Calistro-Rivera, G.; Heald, G.; Jarvis, M. J.; Prandoni, I.; Röttgering, H. J. A.; Sabater, J.; Shimwell, T.; Tasse, C.; Williams, W. L.

    2018-04-01

    Radio emission is a key indicator of star formation activity in galaxies, but the radio luminosity-star formation relation has to date been studied almost exclusively at frequencies of 1.4 GHz or above. At lower radio frequencies, the effects of thermal radio emission are greatly reduced, and so we would expect the radio emission observed to be completely dominated by synchrotron radiation from supernova-generated cosmic rays. As part of the LOFAR Surveys Key Science project, the Herschel-ATLAS NGP field has been surveyed with LOFAR at an effective frequency of 150 MHz. We select a sample from the MPA-JHU catalogue of Sloan Digital Sky Survey galaxies in this area: the combination of Herschel, optical and mid-infrared data enable us to derive star formation rates (SFRs) for our sources using spectral energy distribution fitting, allowing a detailed study of the low-frequency radio luminosity-star formation relation in the nearby Universe. For those objects selected as star-forming galaxies (SFGs) using optical emission line diagnostics, we find a tight relationship between the 150 MHz radio luminosity (L150) and SFR. Interestingly, we find that a single power-law relationship between L150 and SFR is not a good description of all SFGs: a broken power-law model provides a better fit. This may indicate an additional mechanism for the generation of radio-emitting cosmic rays. Also, at given SFR, the radio luminosity depends on the stellar mass of the galaxy. Objects that were not classified as SFGs have higher 150-MHz radio luminosity than would be expected given their SFR, implying an important role for low-level active galactic nucleus activity.

  15. Power penalties for multi-level PAM modulation formats at arbitrary bit error rates

    Science.gov (United States)

    Kaliteevskiy, Nikolay A.; Wood, William A.; Downie, John D.; Hurley, Jason; Sterlingov, Petr

    2016-03-01

    There is considerable interest in combining multi-level pulsed amplitude modulation formats (PAM-L) and forward error correction (FEC) in next-generation, short-range optical communications links for increased capacity. In this paper we derive new formulas for the optical power penalties due to modulation format complexity relative to PAM-2 and due to inter-symbol interference (ISI). We show that these penalties depend on the required system bit-error rate (BER) and that the conventional formulas overestimate link penalties. Our corrections to the standard formulas are very small at conventional BER levels (typically 1×10-12) but become significant at the higher BER levels enabled by FEC technology, especially for signal distortions due to ISI. The standard formula for format complexity, P = 10log(L-1), is shown to overestimate the actual penalty for PAM-4 and PAM-8 by approximately 0.1 and 0.25 dB respectively at 1×10-3 BER. Then we extend the well-known PAM-2 ISI penalty estimation formula from the IEEE 802.3 standard 10G link modeling spreadsheet to the large BER case and generalize it for arbitrary PAM-L formats. To demonstrate and verify the BER dependence of the ISI penalty, a set of PAM-2 experiments and Monte-Carlo modeling simulations are reported. The experimental results and simulations confirm that the conventional formulas can significantly overestimate ISI penalties at relatively high BER levels. In the experiments, overestimates up to 2 dB are observed at 1×10-3 BER.

  16. Theoretical and Shock Tube Study of the Rate Constants for Hydrogen Abstraction Reactions of Ethyl Formate.

    Science.gov (United States)

    Wu, Junjun; Khaled, Fethi; Ning, Hongbo; Ma, Liuhao; Farooq, Aamir; Ren, Wei

    2017-08-24

    We report a systematic chemical kinetics study of the H atom abstractions from ethyl formate (EF) by H, O( 3 P), CH 3 , OH, and HO 2 radicals. The geometry optimization and frequency calculation of all the species were conducted using the M06 method and the cc-pVTZ basis set. The one-dimensional hindered rotor treatment of the reactants and transition states and the intrinsic reaction coordinate analysis were also performed at the M06/cc-pVTZ level of theory. The relative electronic energies were calculated at the CCSD(T)/cc-pVXZ (where X = D, T) level of theory and further extrapolated to the complete basis set limit. Rate constants for the tittle reactions were calculated over the temperature range 500-2500 K by the transition state theory (TST) in conjunction with the asymmetric Eckart tunneling effect. In addition, the rate constants of H-abstraction by hydroxyl radical were measured in shock tube experiments at 900-1321 K and 1.4-2.0 atm. Our theoretical rate constants of OH + EF → products agree well with the experimental results within 15% over the experimental temperature range of 900-1321 K. Branching ratios for the five types of H-abstraction reactions were also determined from their individual site-specific rate constants.

  17. Replication Rate, Framing, and Format Affect Attitudes and Decisions about Science Claims

    Science.gov (United States)

    Barnes, Ralph M.; Tobin, Stephanie J.; Johnston, Heather M.; MacKenzie, Noah; Taglang, Chelsea M.

    2016-01-01

    A series of five experiments examined how the evaluation of a scientific finding was influenced by information about the number of studies that had successfully replicated the initial finding. The experiments also tested the impact of frame (negative, positive) and numeric format (percentage, natural frequency) on the evaluation of scientific findings. In Experiments 1 through 4, an attitude difference score served as the dependent measure, while a measure of choice served as the dependent measure in Experiment 5. Results from a diverse sample of 188 non-institutionalized U.S. adults (Experiment 2) and 730 undergraduate college students (Experiments 1, 3, and 4) indicated that attitudes became more positive as the replication rate increased and attitudes were more positive when the replication information was framed positively. The results also indicate that the manner in which replication rate was framed had a greater impact on attitude than the replication rate itself. The large effect for frame was attenuated somewhat when information about replication was presented in the form of natural frequencies rather than percentages. A fifth study employing 662 undergraduate college students in a task in which choice served as the dependent measure confirmed the framing effect and replicated the replication rate effect in the positive frame condition, but provided no evidence that the use of natural frequencies diminished the effect. PMID:27920743

  18. Theoretical and Shock Tube Study of the Rate Constants for Hydrogen Abstraction Reactions of Ethyl Formate

    KAUST Repository

    Wu, Junjun

    2017-08-03

    We report a systematic chemical kinetics study of the H-atom abstractions from ethyl formate (EF) by H, O(3P), CH3, OH, and HO2 radicals. The geometry optimization and frequency calculation of all the species were conducted using the M06 method and the cc-pVTZ basis set. The one-dimensional hindered rotor treatment of the reactants and transition states and the intrinsic reaction coordinate analysis were also performed at the M06/cc-pVTZ level of theory. The relative electronic energies were calculated at the CCSD(T)/cc-pVXZ (where X = D, T) level of theory and further extrapolated to the complete basis set limit. Rate constants for the tittle reactions were calculated over the temperature range of 500‒2500 K by the transition state theory (TST) in conjunction with asymmetric Eckart tunneling effect. In addition, the rate constants of H-abstraction by hydroxyl radical were measured in shock tube experiments at 900‒1321 K and 1.4‒2.0 atm. Our theoretical rate constants of OH + EF → Products agree well with the experimental results within 15% over the experimental temperature range of 900‒1321 K. Branching ratios for the five types of H-abstraction reactions were also determined from their individual site-specific rate constants.

  19. An evolutionary model for collapsing molecular clouds and their star formation activity. II. Mass dependence of the star formation rate

    Energy Technology Data Exchange (ETDEWEB)

    Zamora-Avilés, Manuel; Vázquez-Semadeni, Enrique [Centro de Radioastronomía y Astrofísica, Universidad Nacional Autónoma de México, Apdo. Postal 3-72, Morelia, Michoacán 58089 (Mexico)

    2014-10-01

    We discuss the evolution and dependence on cloud mass of the star formation rate (SFR) and efficiency (SFE) of star-forming molecular clouds (MCs) within the scenario that clouds are undergoing global collapse and that the SFR is controlled by ionization feedback. We find that low-mass clouds (M {sub max} ≲ 10{sup 4} M {sub ☉}) spend most of their evolution at low SFRs, but end their lives with a mini-burst, reaching a peak SFR ∼10{sup 4} M {sub ☉} Myr{sup –1}, although their time-averaged SFR is only (SFR) ∼ 10{sup 2} M {sub ☉} Myr{sup –1}. The corresponding efficiencies are SFE{sub final} ≲ 60% and (SFE) ≲ 1%. For more massive clouds (M {sub max} ≳ 10{sup 5} M {sub ☉}), the SFR first increases and then reaches a plateau because the clouds are influenced by stellar feedback since earlier in their evolution. As a function of cloud mass, (SFR) and (SFE) are well represented by the fits (SFR) ≈ 100(1 + M {sub max}/1.4 × 10{sup 5} M {sub ☉}){sup 1.68} M {sub ☉} Myr{sup –1} and (SFE) ≈ 0.03(M {sub max}/2.5 × 10{sup 5} M {sub ☉}){sup 0.33}, respectively. Moreover, the SFR of our model clouds follows closely the SFR-dense gas mass relation recently found by Lada et al. during the epoch when their instantaneous SFEs are comparable to those of the clouds considered by those authors. Collectively, a Monte Carlo integration of the model-predicted SFR(M) over a Galactic giant molecular cloud mass spectrum yields values for the total Galactic SFR that are within half an order of magnitude of the relation obtained by Gao and Solomon. Our results support the scenario that star-forming MCs may be in global gravitational collapse and that the low observed values of the SFR and SFE are a result of the interruption of each SF episode, caused primarily by the ionizing feedback from massive stars.

  20. Intrinsic optical bistability of thin films of linear molecular aggregates : The two-exciton approximation

    NARCIS (Netherlands)

    Klugkist, Joost; Malyshev, Victor; Knoester, Jasper

    2008-01-01

    We generalize our recent work on the optical bistability of thin films of molecular aggregates [J. A. Klugkist et al., J. Chem. Phys. 127, 164705 (2007)] by accounting for the optical transitions from the one-exciton manifold to the two-exciton manifold as well as the exciton-exciton annihilation of

  1. Ionosphere influence on success rate of GPS ambiguity resolution in a satellite formation flying

    Science.gov (United States)

    Baroni, Leandro

    2015-10-01

    Satellite formation flying is one of the most promising technologies for future space missions. The distribution of sensors and payloads among different satellites provides more redundancy, flexibility, improved communication coverage, among other advantages. One of the fundamental issues in spacecraft formation flying is precise position and velocity determination between satellites. For missions in low Earth orbits, GPS system can meet the precision requirement in relative positioning, since the satellite dynamics is modeled properly. The key for high accuracy GPS relative positioning is to resolve the ambiguities to their integer values. Ambiguities resolved successfully can improve the positioning accuracy to decimetre or even millimetre-level. So, integer carrier phase ambiguity resolution is often a prerequisite for high precision GPS positioning. The determination of relative position was made using an extended Kalman filter. The filter must take into account imperfections in dynamic modeling of perturbations affecting the orbital flight, and changes in solar activity that affects the GPS signal propagation, for mitigating these effects on relative positioning accuracy. Thus, this work aims to evaluate the impact of ionosphere variation, caused by changes in solar activity, in success rate of ambiguity resolution. Using the Ambiguity Dilution of Precision (ADOP) concept, the ambiguity success rate is analyzed and the expected precision of the ambiguity-fixed solution is calculated. Evaluations were performed using actual data from GRACE mission and analyzed for their performance in real scenarios. Analyses were conducted in different configurations of relative position and during different levels of solar activity. Results bring the impact of various disturbances and modeling of solar activity level on the success rate of ambiguity resolution.

  2. Prediction of terrestrial gamma dose rate based on geological formations and soil types in the Johor State, Malaysia.

    Science.gov (United States)

    Saleh, Muneer Aziz; Ramli, Ahmad Termizi; bin Hamzah, Khaidzir; Alajerami, Yasser; Moharib, Mohammed; Saeed, Ismael

    2015-10-01

    This study aims to predict and estimate unmeasured terrestrial gamma dose rate (TGDR) using statistical analysis methods to derive a model from the actual measurement based on geological formation and soil type. The measurements of TGDR were conducted in the state of Johor with a total of 3873 measured points which covered all geological formations, soil types and districts. The measurements were taken 1 m above the soil surface using NaI [Ti] detector. The measured gamma dose rates ranged from 9 nGy h(-1) to 1237 nGy h(-1) with a mean value of 151 nGy h(-1). The data have been normalized to fit a normal distribution. Tests of significance were conducted among all geological formations and soil types, using the unbalanced one way ANOVA. The results indicated strong significant differences due to the different geological formations and soil types present in Johor State. Pearson Correlation was used to measure the relations between gamma dose rate based on geological formation and soil type (D(G,S)) with the gamma dose rate based on geological formation (D(G)) or soil type (D(s)). A very good correlation was found between D(G,S) and D(G) or D(G,S) and D(s). A total of 118 pairs of geological formations and soil types were used to derive the statistical contribution of geological formations and soil types to gamma dose rates. The contribution of the gamma dose rate from geological formation and soil type were found to be 0.594 and 0.399, respectively. The null hypotheses were accepted for 83% of examined data, therefore, the model could be used to predict gamma dose rates based on geological formation and soil type information. Copyright © 2015 Elsevier Ltd. All rights reserved.

  3. Polaronic exciton behavior in gas-phase water

    Science.gov (United States)

    Udal'tsov, Alexander V.

    2018-03-01

    Features of the absorption spectrum of gas-phase water in the energy range 7-10 eV have been considered applying polaronic exciton theory. The interaction of the incident photon generating polaronic exciton in water is described taking into account angular momentum of the electron so that polaronic exciton radii have been estimated in dependence on spin-orbit coupling under proton sharing. The suggested approach admits an estimate of kinetic and rotation energies of the polaronic exciton. As a result sixteen steps of half Compton wavelength, λC/2 = h/(2mec) changing polaronic exciton radius were found consistent with local maxima and shoulders in the spectrum. Thus, the absorption of gas-phase water in the energy range 8.5-10 eV has been interpreted in terms of polaronic exciton rotation mainly coupled with the proton sharing. The incident photon interaction with water is also considered in terms of Compton interaction, when the rotation energy plays a role like the energy loss of the incident photon under Compton scattering. The found symmetry and the other evidence allowed to conclude about polaronic exciton migration under the interaction angle 90°.

  4. Excitons in InP/InAs inhomogeneous quantum dots

    International Nuclear Information System (INIS)

    Assaid, E; Feddi, E; Khamkhami, J El; Dujardin, F

    2003-01-01

    Wannier excitons confined in an InP/InAs inhomogeneous quantum dot (IQD) have been studied theoretically in the framework of the effective mass approximation. A finite-depth potential well has been used to describe the effect of the quantum confinement in the InAs layer. The exciton binding energy has been determined using the Ritz variational method. The spatial correlation between the electron and the hole has been taken into account in the expression for the wavefunction. It has been shown that for a fixed size b of the IQD, the exciton binding energy depends strongly on the core radius a. Moreover, it became apparent that there are two critical values of the core radius, a crit and a 2D , for which important changes of the exciton binding occur. The former critical value, a crit , corresponds to a minimum of the exciton binding energy and may be used to distinguish between tridimensional confinement and bidimensional confinement. The latter critical value, a 2D , corresponds to a maximum of the exciton binding energy and to the most pronounced bidimensional character of the exciton

  5. Transport of Indirect Excitons in High Magnetic Fields

    Science.gov (United States)

    Dorow, C. J.; Kuznetsova, Y. Y.; Calman, E. V.; Butov, L. V.; Wilkes, J.; Campman, K. L.; Gossard, A. C.

    Spatially- and spectrally-resolved photoluminescence measurements of indirect excitons in high magnetic fields are presented. The high magnetic field regime for excitons is realized when the cyclotron splitting compares to the exciton binding energy. Due to small mass and binding energy, the high magnetic field regime for excitons is achievable in lab, requiring a few Tesla. Long indirect exciton lifetimes allow large exciton transport distances before recombination, giving an opportunity to study transport and relaxation kinetics of indirect magnetoexcitons via optical imaging. Indirect excitons in several Landau level states are realized. 0e -0h indirect magnetoexcitons (formed from electrons and holes at zeroth Landau levels) travel over large distances and form an emission ring around the excitation spot. In contrast, the 1e -1h and 2e -2h states do not exhibit long transport distances, and the spatial profiles of the emission closely follow the laser excitation. The 0e -0h indirect magnetoexciton transport distance reduces with increasing magnetic field. Accompanying theoretical work explains these effects in terms of magnetoexciton energy relaxation and effective mass enhancement. Supported by NSF Grant No. 1407277. J.W. was supported by the EPSRC (Grant EP/L022990/1). C.J.D. was supported by the NSF Graduate Research Fellowship Program under Grant No. DGE-1144086.

  6. Exciton binding energy in a pyramidal quantum dot

    Science.gov (United States)

    Anitha, A.; Arulmozhi, M.

    2018-05-01

    The effects of spatially dependent effective mass, non-parabolicity of the conduction band and dielectric screening function on exciton binding energy in a pyramid-shaped quantum dot of GaAs have been investigated by variational method as a function of base width of the pyramid. We have assumed that the pyramid has a square base with area a× a and height of the pyramid H=a/2. The trial wave function of the exciton has been chosen according to the even mirror boundary condition, i.e. the wave function of the exciton at the boundary could be non-zero. The results show that (i) the non-parabolicity of the conduction band affects the light hole (lh) and heavy hole (hh) excitons to be more bound than that with parabolicity of the conduction band, (ii) the dielectric screening function (DSF) affects the lh and hh excitons to be more bound than that without the DSF and (iii) the spatially dependent effective mass (SDEM) affects the lh and hh excitons to be less bound than that without the SDEM. The combined effects of DSF and SDEM on exciton binding energy have also been calculated. The results are compared with those available in the literature.

  7. Impact of star formation inhomogeneities on merger rates and interpretation of LIGO results

    International Nuclear Information System (INIS)

    O'Shaughnessy, R; Kopparapu, R K; Belczynski, K

    2012-01-01

    Within the next decade, ground based gravitational-wave detectors are in principle capable of determining the compact object merger rate per unit volume of the local universe to better than 20% with more than 30 detections. These measurements will constrain our models of stellar, binary and star cluster evolution in the nearby present-day and ancient universe. We argue that the stellar models are sensitive to heterogeneities (in age and metallicity at least) in such a way that the predicted merger rates are subject to an additional 30-50% systematic errors unless these heterogeneities are taken into account. Without adding new electromagnetic constraints on massive binary evolution or relying on more information from each merger (e.g., binary masses and spins), as few as the 5 merger detections could exhaust the information available in a naive comparison to merger rate predictions. As a concrete example immediately relevant to analysis of initial and enhanced LIGO results, we use a nearby-universe catalog to demonstrate that no one tracer of stellar content can be consistently used to constrain merger rates without introducing a systematic error of order O(30%) at 90% confidence (depending on the type of binary involved). For example, though binary black holes typically take many Gyr to merge, binary neutron stars often merge rapidly; different tracers of stellar content are required for these two types. More generally, we argue that theoretical binary evolution can depend sufficiently sensitively on star-forming conditions-even assuming no uncertainty in binary evolution model-that the distribution of star-forming conditions must be incorporated to reduce the systematic error in merger rate predictions below roughly 40%. We emphasize that the degree of sensitivity to star-forming conditions depends on the binary evolution model and on the amount of relevant variation in star-forming conditions. For example, if after further comparison with electromagnetic and

  8. GALAXY EVOLUTION AT HIGH REDSHIFT: OBSCURED STAR FORMATION, GRB RATES, COSMIC REIONIZATION, AND MISSING SATELLITES

    Energy Technology Data Exchange (ETDEWEB)

    Lapi, A.; Mancuso, C.; Celotti, A.; Danese, L. [SISSA, Via Bonomea 265, I-34136 Trieste (Italy)

    2017-01-20

    We provide a holistic view of galaxy evolution at high redshifts z ≳ 4, which incorporates the constraints from various astrophysical/cosmological probes, including the estimate of the cosmic star formation rate (SFR) density from UV/IR surveys and long gamma-ray burst (GRBs) rates, the cosmic reionization history following the latest Planck measurements, and the missing satellites issue. We achieve this goal in a model-independent way by exploiting the SFR functions derived by Mancuso et al. on the basis of an educated extrapolation of the latest UV/far-IR data from HST / Herschel , and already tested against a number of independent observables. Our SFR functions integrated down to a UV magnitude limit M {sub UV} ≲ −13 (or SFR limit around 10{sup −2} M {sub ⊙} yr{sup −1}) produce a cosmic SFR density in excellent agreement with recent determinations from IR surveys and, taking into account a metallicity ceiling Z ≲ Z {sub ⊙}/2, with the estimates from long GRB rates. They also yield a cosmic reionization history consistent with that implied by the recent measurements of the Planck mission of the electron scattering optical depth τ {sub es} ≈ 0.058; remarkably, this result is obtained under a conceivable assumption regarding the average value f {sub esc} ≈ 0.1 of the escape fraction for ionizing photons. We demonstrate via the abundance-matching technique that the above constraints concurrently imply galaxy formation becoming inefficient within dark matter halos of mass below a few 10{sup 8} M {sub ⊙}; pleasingly, such a limit is also required so as not to run into the missing satellites issue. Finally, we predict a downturn of the Galaxy luminosity function faintward of M {sub UV} ≲ −12, and stress that its detailed shape, to be plausibly probed in the near future by the JWST , will be extremely informative on the astrophysics of galaxy formation in small halos, or even on the microscopic nature of the dark matter.

  9. Engineering excitonic dynamics and environmental stability of post-transition metal chalcogenides by pyridine functionalization technique.

    Science.gov (United States)

    Meng, Xiuqing; Pant, Anupum; Cai, Hui; Kang, Jun; Sahin, Hasan; Chen, Bin; Wu, Kedi; Yang, Sijie; Suslu, Aslihan; Peeters, F M; Tongay, Sefaattin

    2015-10-28

    Owing to their strong photon emission, low excitonic binding energies, and nearly-ideal band offset values for water splitting reactions, direct gap quasi-2D gallium chalcogenides are potential candidates for applications in energy harvesting, optoelectronics, and photonics. Unlike other 2D materials systems, chemical functionalization of gallium chalcogenides is still at its seminal stages. Here, we propose vapor phase pyridine intercalation technique to manipulate optical properties of gallium chalcogenides. After functionalization, the excitonic dynamics of quasi-2D GaSe change significantly as evidenced by an increase in integrated PL intensity and emergence of a new emission feature that is below the band edge. Based on our DFT calculations, we attribute these to formation of bound exciton complexes at the trap sites introduced by chemical reaction between pyridine and GaSe. On the contrary, pyridine functionalization does not impact the optical properties of GaTe, instead treats GaTe surface to prevent oxidization of tellurium atoms. Overall, results suggest novel ways to control properties of gallium chalcogenides on demand and unleash their full potential for a range of applications in photonics and optoelectronics.

  10. Quanty for core level spectroscopy - excitons, resonances and band excitations in time and frequency domain

    International Nuclear Information System (INIS)

    Haverkort, Maurits W.

    2016-01-01

    Depending on the material and edge under consideration, core level spectra manifest themselves as local excitons with multiplets, edge singularities, resonances, or the local projected density of states. Both extremes, i.e., local excitons and non-interacting delocalized excitations are theoretically well under control. Describing the intermediate regime, where local many body interactions and band-formation are equally important is a challenge. Here we discuss how Quanty , a versatile quantum many body script language, can be used to calculate a variety of different core level spectroscopy types on solids and molecules, both in the frequency as well as the time domain. The flexible nature of Quanty allows one to choose different approximations for different edges and materials. For example, using a newly developed method merging ideas from density renormalization group and quantum chemistry [1-3], Quanty can calculate excitons, resonances and band-excitations in x-ray absorption, photoemission, x-ray emission, fluorescence yield, non-resonant inelastic x-ray scattering, resonant inelastic x-ray scattering and many more spectroscopy types. Quanty can be obtained from: http://www.quanty.org. (paper)

  11. [N-arachidonoyl dopamine is a possible factor of the rate of tentacle formation in freshwater hydra].

    Science.gov (United States)

    Markova, L N; Ostroumova, T V; Akimov, M G; Bezuglov, V V

    2008-01-01

    The effect of N-arachidonoyl dopamine, haloperidol, and their mixture on the rate of tentacle formation was studied during regeneration of the gastral and basal fragments of freshwater hydra. Some concentrations of haloperidol inhibited the tentacle formation, which was more pronounced in the basal fragment. N-arachidonoyl dopamine accelerated the tentacle formation in both fragments, particularly, in the basal one (an inversion of the natural difference in the rate of tentacle formation between the gastral and basal fragments). After the exposure to the mixture of these drugs, the effects of each of them were observed. Mass spectrometry assay has demonstrated endogenous N-arachidonoyl dopamine in the intact hydra homogenate. The possible involvement of this acyl-neurotransmitter in the regulation of the rate of tentacle formation in regenerating hydra is discussed.

  12. Physical origin of the large-scale conformity in the specific star formation rates of galaxies

    Science.gov (United States)

    Kauffmann, Guinevere

    2015-12-01

    Two explanations have been put forward to explain the observed conformity between the colours and specific star formation rates (SFR/M*) of galaxies on large scales: (1) the formation times of their surrounding dark matter haloes are correlated (commonly referred to as `assembly bias'), (2) gas is heated over large scales at early times, leading to coherent modulation of cooling and star formation between well-separated galaxies (commonly referred to as `pre-heating'). To distinguish between the pre-heating and assembly bias scenarios, we search for relics of energetic feedback events in the neighbourhood of central galaxies with different specific SFRs. We find a significant excess of very high mass (log M* > 11.3) galaxies out to a distance of 2.5 Mpc around low SFR/M* central galaxies compared to control samples of higher SFR/M* central galaxies with the same stellar mass and redshift. We also find that very massive galaxies in the neighbourhood of low-SFR/M* galaxies have much higher probability of hosting radio-loud active galactic nuclei (AGN). The radio-loud AGN fraction in neighbours with log M* > 11.3 is four times higher around passive, non star-forming centrals at projected distances of 1 Mpc and two times higher at projected distances of 4 Mpc. Finally, we carry out an investigation of conformity effects in the recently publicly released Illustris cosmological hydrodynamical simulation, which includes energetic input both from quasars and from radio mode accretion on to black holes. We do not find conformity effects of comparable amplitude on large scales in the simulations and we propose that gas needs to be pushed out of dark matter haloes more efficiently at high redshifts.

  13. THE OBSERVED RELATION BETWEEN STELLAR MASS, DUST EXTINCTION, AND STAR FORMATION RATE IN LOCAL GALAXIES

    Energy Technology Data Exchange (ETDEWEB)

    Zahid, H. J.; Kewley, L. J.; Kudritzki, R. P. [Institute for Astronomy, University of Hawaii at Manoa, 2680 Woodlawn Dr., Honolulu, HI 96822 (United States); Yates, R. M. [Max-Planck-Institute for Astrophysics, Karl-Schwarzschild-Str. 1, D-85741 Garching (Germany)

    2013-02-15

    In this study, we investigate the relation between stellar mass, dust extinction, and star formation rate (SFR) using {approx}150,000 star-forming galaxies from SDSS DR7. We show that the relation between dust extinction and SFR changes with stellar mass. For galaxies at the same stellar mass, dust extinction is anti-correlated with the SFR at stellar masses <10{sup 10} M {sub Sun }. There is a sharp transition in the relation at a stellar mass of 10{sup 10} M {sub Sun }. At larger stellar masses, dust extinction is positively correlated with the SFR for galaxies at the same stellar mass. The observed relation between stellar mass, dust extinction, and SFR presented in this study helps to confirm similar trends observed in the relation between stellar mass, metallicity, and SFR. The relation reported in this study provides important new constraints on the physical processes governing the chemical evolution of galaxies. The correlation between SFR and dust extinction for galaxies with stellar masses >10{sup 10} M {sub Sun} is shown to extend to the population of quiescent galaxies suggesting that the physical processes responsible for the observed relation between stellar mass, dust extinction, and SFR may be related to the processes leading to the shutdown of star formation in galaxies.

  14. THE OBSERVED RELATION BETWEEN STELLAR MASS, DUST EXTINCTION, AND STAR FORMATION RATE IN LOCAL GALAXIES

    International Nuclear Information System (INIS)

    Zahid, H. J.; Kewley, L. J.; Kudritzki, R. P.; Yates, R. M.

    2013-01-01

    In this study, we investigate the relation between stellar mass, dust extinction, and star formation rate (SFR) using ∼150,000 star-forming galaxies from SDSS DR7. We show that the relation between dust extinction and SFR changes with stellar mass. For galaxies at the same stellar mass, dust extinction is anti-correlated with the SFR at stellar masses 10 M ☉ . There is a sharp transition in the relation at a stellar mass of 10 10 M ☉ . At larger stellar masses, dust extinction is positively correlated with the SFR for galaxies at the same stellar mass. The observed relation between stellar mass, dust extinction, and SFR presented in this study helps to confirm similar trends observed in the relation between stellar mass, metallicity, and SFR. The relation reported in this study provides important new constraints on the physical processes governing the chemical evolution of galaxies. The correlation between SFR and dust extinction for galaxies with stellar masses >10 10 M ☉ is shown to extend to the population of quiescent galaxies suggesting that the physical processes responsible for the observed relation between stellar mass, dust extinction, and SFR may be related to the processes leading to the shutdown of star formation in galaxies.

  15. The Ultraviolet and Infrared Star Formation Rates of Compact Group Galaxies: An Expanded Sample

    Science.gov (United States)

    Lenkic, Laura; Tzanavaris, Panayiotis; Gallagher, Sarah C.; Desjardins, Tyler D.; Walker, Lisa May; Johnson, Kelsey E.; Fedotov, Konstantin; Charlton, Jane; Cardiff, Ann H.; Durell, Pat R.

    2016-01-01

    Compact groups of galaxies provide insight into the role of low-mass, dense environments in galaxy evolution because the low velocity dispersions and close proximity of galaxy members result in frequent interactions that take place over extended time-scales. We expand the census of star formation in compact group galaxies by Tzanavaris et al. (2010) and collaborators with Swift UVOT, Spitzer IRAC and MIPS 24 m photometry of a sample of 183 galaxies in 46 compact groups. After correcting luminosities for the contribution from old stellar populations, we estimate the dust-unobscured star formation rate (SFRUV) using the UVOT uvw2 photometry. Similarly, we use the MIPS 24 m photometry to estimate the component of the SFR that is obscured by dust (SFRIR). We find that galaxies which are MIR-active (MIR-red), also have bluer UV colours, higher specific SFRs, and tend to lie in Hi-rich groups, while galaxies that are MIR-inactive (MIR-blue) have redder UV colours, lower specific SFRs, and tend to lie in Hi-poor groups. We find the SFRs to be continuously distributed with a peak at about 1 M yr1, indicating this might be the most common value in compact groups. In contrast, the specific SFR distribution is bimodal, and there is a clear distinction between star-forming and quiescent galaxies. Overall, our results suggest that the specific SFR is the best tracer of gas depletion and galaxy evolution in compact groups.

  16. Relation between Silver Nanoparticle Formation Rate and Antioxidant Capacity of Aqueous Plant Leaf Extracts

    Directory of Open Access Journals (Sweden)

    Azat Akbal

    2016-01-01

    Full Text Available Correlation between the antioxidant capacity and silver nanoparticle formation rates of pomegranate (Punica granatum, quince (Cydonia oblonga, chestnut (Castanea sativa, fig (Ficus carica, walnut (Juglans cinerea, black mulberry (Morus nigra, and white mulberry (Morus alba leaf extracts is investigated at a fixed illumination. Silver nanoparticles formed in all plant leaf extracts possess round shapes with average particle size of 15 to 25 nm, whereas corresponding surface plasmon resonance peak wavelengths vary between 422 nm and 451 nm. Cupric reducing antioxidant capacity technique is used as a reference method to determine total antioxidant capacity of the plant leaf extracts. Integrated absorbance over the plasmon resonance peaks exhibits better linear relation with antioxidant capacities of various plant leaf extracts compared to peak absorbance values, with correlation coefficient values of 0.9333 and 0.7221, respectively.

  17. Ordered Dissipative Structures in Exciton Systems in Semiconductor Quantum Wells

    Directory of Open Access Journals (Sweden)

    Andrey A. Chernyuk

    2006-02-01

    Full Text Available A phenomenological theory of exciton condensation in conditions of inhomogeneous excitation is proposed. The theory is applied to the study of the development of an exciton luminescence ring and the ring fragmentation at macroscopical distances from the central excitation spot in coupled quantum wells. The transition between the fragmented and the continuous ring is considered. With assumption of a defect in the structure, a possibility of a localized island of the condensed phase in a fixed position is shown. Exciton density distribution is also analyzed in the case of two spatially separated spots of the laser excitation.

  18. Transport of indirect excitons in high magnetic fields

    Science.gov (United States)

    Kuznetsova, Y. Y.; Dorow, C. J.; Calman, E. V.; Butov, L. V.; Wilkes, J.; Muljarov, E. A.; Campman, K. L.; Gossard, A. C.

    2017-03-01

    We present spatially and spectrally resolved photoluminescence measurements of indirect excitons in high magnetic fields. Long indirect exciton lifetimes give the opportunity to measure magnetoexciton transport by optical imaging. Indirect excitons formed from electrons and holes at zeroth Landau levels (0e-0h indirect magnetoexcitons) travel over large distances and form a ring emission pattern around the excitation spot. In contrast, the spatial profiles of 1e-1h and 2e-2h indirect magnetoexciton emission closely follow the laser excitation profile. The 0e-0h indirect magnetoexciton transport distance reduces with increasing magnetic field. These effects are explained in terms of magnetoexciton energy relaxation and effective mass enhancement.

  19. Photogenerated Exciton Dissociation in Highly Coupled Lead Salt Nanocrystal Assemblies

    KAUST Repository

    Choi, Joshua J.

    2010-05-12

    Internanocrystal coupling induced excitons dissociation in lead salt nanocrystal assemblies is investigated. By combining transient photoluminescence spectroscopy, grazing incidence small-angle X-ray scattering, and time-resolved electric force microscopy, we show that excitons can dissociate, without the aid of an external bias or chemical potential gradient, via tunneling through a potential barrier when the coupling energy is comparable to the exciton binding energy. Our results have important implications for the design of nanocrystal-based optoelectronic devices. © 2010 American Chemical Society.

  20. Ultrafast electric phase control of a single exciton qubit

    Science.gov (United States)

    Widhalm, Alex; Mukherjee, Amlan; Krehs, Sebastian; Sharma, Nandlal; Kölling, Peter; Thiede, Andreas; Reuter, Dirk; Förstner, Jens; Zrenner, Artur

    2018-03-01

    We report on the coherent phase manipulation of quantum dot excitons by electric means. For our experiments, we use a low capacitance single quantum dot photodiode which is electrically controlled by a custom designed SiGe:C BiCMOS chip. The phase manipulation is performed and quantified in a Ramsey experiment, where ultrafast transient detuning of the exciton energy is performed synchronous to double pulse π/2 ps laser excitation. We are able to demonstrate electrically controlled phase manipulations with magnitudes up to 3π within 100 ps which is below the dephasing time of the quantum dot exciton.

  1. Energy and Information Transfer Via Coherent Exciton Wave Packets

    Science.gov (United States)

    Zang, Xiaoning

    Electronic excitons are bound electron-hole states that are generated when light interacts with matter. Such excitations typically entangle with phonons and rapidly decohere; the resulting electronic state dynamics become diffusive as a result. However, if the exciton-phonon coupling can be reduced, it may be possible to construct excitonic wave packets that offer a means of efficiently transmitting information and energy. This thesis is a combined theory/computation investigation to design condensed matter systems which support the requisite coherent transport. Under the idealizing assumption that exciton-phonon entanglement could be completely suppressed, the majority of this thesis focuses on the creation and manipulation of exciton wave packets in quasi-one-dimensional systems. While each site could be a silicon quantum dot, the actual implementation focused on organic molecular assemblies for the sake of computational simplicity, ease of experimental implementation, potential for coherent transport, and promise because of reduced structural uncertainty. A laser design was derived to create exciton wave packets with tunable shape and speed. Quantum interference was then exploited to manipulate these packets to block, pass, and even dissociate excitons based on their energies. These developments allow exciton packets to be considered within the arena of quantum information science. The concept of controllable excitonic wave packets was subsequently extended to consider molecular designs that allow photons with orbital angular momentum to be absorbed to create excitons with a quasi-angular momentum of their own. It was shown that a well-defined measure of topological charge is conserved in such light-matter interactions. Significantly, it was also discovered that such molecules allow photon angular momenta to be combined and later emitted. This amounts to a new way of up/down converting photonic angular momentum without relying on nonlinear optical materials. The

  2. Exciton transfer under dichotomic noise: GME treatment

    International Nuclear Information System (INIS)

    Barvik, I.; Warns, C.; Reineker, P.

    1995-08-01

    The exciton energy transfer between molecules in a dimer is investigated using a model, in which the influence of the phonons is described by a dichotomic stochastic process with colored noise giving rise to modulations of the molecular excitation energies. The solution of equations of motion for the density matrix of the system (obtained algebraically on a computer) is used to determine (also algebraically) the form of the memory functions which enter the Generalized Master Equation. The behaviour of the roots and their weights in the memory function is discussed thoroughly. Connection of the so called coherence time to stochastic parameters is treated analytically. Different limiting cases are investigated. (author). 14 refs, 9 figs

  3. Fragmented-condensate solid of dipolar excitons

    Science.gov (United States)

    Andreev, S. V.

    2017-05-01

    We discuss a possible link between the recently observed macroscopic ordering of ultracold dipolar excitons (MOES) and the phenomenon of supersolidity. In the dilute limit we predict a stable supersolid state for a quasi-one-dimensional system of bosonic dipoles characterized by two- and three-body contact repulsion. We phenomenologically extend our theory to the strongly-correlated regime and find a critical value of the contact interaction parameter at which the supersolid exhibits a quantum phase transition to a fragmented state. The wavelength of the fragmented-condensate solid is defined by the balance between the quantum pressure and the entropy due to fluctuations of the relative phases between the fragments. Our model appears to be in good agreement with the relevant experimental data, including the very recent results on commensurability effect and wavelength of the MOES.

  4. Formation Rates of Black Hole Accretion Disk Gamma-Ray Bursts

    International Nuclear Information System (INIS)

    Fryer, Chris L.; Woosley, S. E.; Hartmann, Dieter H.

    1999-01-01

    The cosmological origin of at least an appreciable fraction of classical gamma-ray bursts (GRBs) is now supported by redshift measurements for a half-dozen faint host galaxies. Still, the nature of the central engine (or engines) that provide the burst energy remains unclear. While many models have been proposed, those currently favored are all based upon the formation of and/or rapid accretion into stellar-mass black holes. Here we discuss a variety of such scenarios and estimate the probability of each. Population synthesis calculations are carried out using a Monte Carlo approach in which the many uncertain parameters intrinsic to such calculations are varied. We estimate the event rate for each class of model as well as the propagation distances for those having significant delay between formation and burst production, i.e., double neutron star (DNS) mergers and black hole-neutron star (BH/NS) mergers. One conclusion is a 1-2 order of magnitude decrease in the rate of DNS and BH/NS mergers compared to that previously calculated using invalid assumptions about common envelope evolution. Other major uncertainties in the event rates and propagation distances include the history of star formation in the universe, the masses of the galaxies in which merging compact objects are born, and the radii of the hydrogen-stripped cores of massive stars. For reasonable assumptions regarding each, we calculate a daily event rate in the universe for (1) merging neutron stars: ∼100 day-1; (2) neutron star-black hole mergers: ∼450 day-1; (3) collapsars: ∼104 day-1; (4) helium star black hole mergers: ∼1000 day-1; and (5) white dwarf-black hole mergers: ∼20 day-1. The range of uncertainty in these numbers, however, is very large, typically 2-3 orders of magnitude. These rates must additionally be multiplied by any relevant beaming factor (f Ω <1) and sampling fraction (if the entire universal set of models is not being observed). Depending upon the mass of the host

  5. Extra- and intra-cellular ice formation of red seabream (Pagrus major) embryos at different cooling rates.

    Science.gov (United States)

    Li, J; Zhang, L L; Liu, Q H; Xu, X Z; Xiao, Z Z; Ma, D Y; Xu, S H; Xue, Q Z

    2009-08-01

    The ice crystal formation is assumed as the most lethal factor for the failure of fish embryo cryopreservation and intracellular ice formation (IIF) plays a central role in cell injury during cooling. The objectives were to observe the morphological changes of red seabream (Pagrus major) embryo during the cooling-thawing process, and to examine the effect of cryoprotectant and cooling rate on the temperatures of oil globule ice formation (T(OIF)), extra-cellular ice formation (T(EIF)) and intracellular ice formation (T(IIF)) using cryomicroscope. After thawing, the morphological changes of embryos were observed and recorded by the video attachment and monitor under the microscope. During the cooling process, three representative phenomena were observed: oil globule gradually turned bright firstly, then the whole field of view flashed and the embryo blackened. Cooling rate affect the temperature of both extra- and intra-cellular ice formations. T(EIF) and T(IIF) at high cooling rate were much lower than that at low cooling rate. And the value of T(EIF)-T(IIF) increased from 0.45 to 11.11 degrees C with the increase of cooling rate from 3 to130 degrees C/min. Taken together, our results suggested that high cooling rate with proper cryoprotectant would be a good option for red seabream embryo cryopreservation.

  6. Mapping of exciton-exciton annihilation in MEH-PPV by time-resolved spectroscopy: experiment and microscopic theory.

    Science.gov (United States)

    Hader, Kilian; Consani, Cristina; Brixner, Tobias; Engel, Volker

    2017-12-06

    Transient absorption traces taken on samples of the polymer MEH-PPV are measured as a function of the laser intensity. In increasing the laser power, different decay dynamics of the signal are obtained. This suggests that effective exciton-exciton annihilation takes place. The signals are interpreted using a microscopic quantum mechanical model. The analysis points at an ultrafast excitonic decay via interchain and intrachain annihilation, where the latter process is roughly thirty times slower. Afterwards, diffusion-induced annihilation and relaxation become effective and thus determine the long-time behavior of the excited-state decay.

  7. Evaporation Rate Study and NDMA Formation from UDMH/NO2 Reaction Products

    Science.gov (United States)

    Buchanan, Vanessa D.; Dee, Louis A.; Baker, David L.

    2003-01-01

    Laboratory samples of uns-dimethylhydrazine (UDMH) fuel/oxidizer (nitrogen dioxide) non-combustion reaction products (UFORP) were prepared using a unique permeation tube technology. Also, a synthetic UFORP was prepared from UDMH, N-nitrosodimethylamine (NDMA), dimethylammonium nitrate, sodium nitrite and purified water. The evaporation rate of UFORP and synthetic UFORP was determined under space vacuum (approx 10(exp -3) Torr) at -40 ?C and 0 ?C. The material remaining was analyzed and showed that the UFORP weight and NDMA concentration decreased over time; however, NDMA had not completely evaporated. Over 85% of the weight was removed by subjecting the UFORP to 10(-3) Torr for 7 hours at -40 ?C and 4 hours at 0 ?C. A mixture of dimethylammonium nitrate and sodium nitrite formed NDMA at a rapid rate in a moist air environment. A sample of UFORP residue was analyzed for formation of NDMA under various conditions. It was found that NDMA was not formed unless nitrite was added.

  8. A CORRELATION BETWEEN STAR FORMATION RATE AND AVERAGE BLACK HOLE ACCRETION IN STAR-FORMING GALAXIES

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Chien-Ting J.; Hickox, Ryan C. [Department of Physics and Astronomy, Dartmouth College, 6127 Wilder Laboratory, Hanover, NH 03755 (United States); Alberts, Stacey; Pope, Alexandra [Department of Astronomy, University of Massachusetts, Amherst, MA 01003 (United States); Brodwin, Mark [Department of Physics and Astronomy, University of Missouri, 5110 Rockhill Road, Kansas City, MO 64110 (United States); Jones, Christine; Forman, William R.; Goulding, Andrew D. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Murray, Stephen S. [Department of Physics and Astronomy, Johns Hopkins University, 3400 N. Charles Street, Baltimore, MD 21218 (United States); Alexander, David M.; Mullaney, James R. [Department of Physics, Durham University, South Road, Durham DH1 3LE (United Kingdom); Assef, Roberto J.; Gorjian, Varoujan [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109 (United States); Brown, Michael J. I. [School of Physics, Monash University, Clayton 3800, Victoria (Australia); Dey, Arjun; Jannuzi, Buell T. [National Optical Astronomy Observatory, Tucson, AZ 85726 (United States); Le Floc' h, Emeric, E-mail: ctchen@dartmouth.edu [Laboratoire AIM-Paris-Saclay, CEA/DSM/Irfu-CNRS-Universite Paris Diderot, CE-Saclay, pt courrier 131, F-91191 Gif-sur-Yvette (France)

    2013-08-10

    We present a measurement of the average supermassive black hole accretion rate (BHAR) as a function of the star formation rate (SFR) for galaxies in the redshift range 0.25 < z < 0.8. We study a sample of 1767 far-IR-selected star-forming galaxies in the 9 deg{sup 2} Booetes multi-wavelength survey field. The SFR is estimated using 250 {mu}m observations from the Herschel Space Observatory, for which the contribution from the active galactic nucleus (AGN) is minimal. In this sample, 121 AGNs are directly identified using X-ray or mid-IR selection criteria. We combined these detected AGNs and an X-ray stacking analysis for undetected sources to study the average BHAR for all of the star-forming galaxies in our sample. We find an almost linear relation between the average BHAR (in M{sub Sun} yr{sup -1}) and the SFR (in M{sub Sun} yr{sup -1}) for galaxies across a wide SFR range 0.85 < log SFR < 2.56: log BHAR = (- 3.72 {+-} 0.52) + (1.05 {+-} 0.33)log SFR. This global correlation between SFR and average BHAR is consistent with a simple picture in which SFR and AGN activity are tightly linked over galaxy evolution timescales.

  9. Electron, hole and exciton self-trapping in germanium doped silica glass from DFT calculations with self-interaction correction

    International Nuclear Information System (INIS)

    Du Jincheng; Rene Corrales, L.; Tsemekhman, Kiril; Bylaska, Eric J.

    2007-01-01

    Density functional theory (DFT) calculations were employed to understand the refractive index change in germanium doped silica glasses for the trapped states of electronic excitations induced by UV irradiation. Local structure relaxation and excess electron density distribution were calculated upon self-trapping of an excess electron, hole, and exciton in germanium doped silica glass. The results show that both the trapped exciton and excess electron are highly localized on germanium ion and, to some extent, on its oxygen neighbors. Exciton self-trapping is found to lead to the formation of a Ge E' center and a non-bridging hole center. Electron trapping changes the GeO 4 tetrahedron structure into trigonal bi-pyramid with the majority of the excess electron density located along the equatorial line. The self-trapped hole is localized on bridging oxygen ions that are not coordinated to germanium atoms that lead to elongation of the Si-O bonds and change of the Si-O-Si bond angles. We carried out a comparative study of standard DFT versus DFT with a hybrid PBE0 exchange and correlation functional. The results show that the two methods give qualitatively similar relaxed structure and charge distribution for electron and exciton trapping in germanium doped silica glass; however, only the PBE0 functional produces the self-trapped hole

  10. A study of soil formation rates using 10Be in the wet-dry tropics of northern Australia

    Directory of Open Access Journals (Sweden)

    Tims S.G.

    2012-10-01

    Full Text Available A catchment level study to obtain soil formation rates using beryllium-10 (10Be tracers has been undertaken in the Daly River Basin in the wet-dry tropics of northern Australia. Three soil cores have been collected to bedrock, with depths ranging from ~1-3.5 m. Due to agricultural practices, modern soil loss rates can be significantly higher than long-term soil formation rates, but establishing soil formation rates has proved to be a difficult problem. At long-term equilibrium, however, soil formation from the underlying rock is balanced by soil loss from the surface. This long-term rate at which soil is being lost can be determined using the cosmogenic tracer 10Be, created in spallation of atmospheric nitrogen and oxygen by cosmic rays. Since the annual fallout rate of 10Be is known, the complete 10Be inventory over the depth of the top soil can be used to establish the soil formation rates.

  11. Prediction of terrestrial gamma dose rate based on geological formations and soil types in the Johor State, Malaysia

    International Nuclear Information System (INIS)

    Saleh, Muneer Aziz; Ramli, Ahmad Termizi; Hamzah, Khaidzir bin; Alajerami, Yasser; Moharib, Mohammed; Saeed, Ismael

    2015-01-01

    This study aims to predict and estimate unmeasured terrestrial gamma dose rate (TGDR) using statistical analysis methods to derive a model from the actual measurement based on geological formation and soil type. The measurements of TGDR were conducted in the state of Johor with a total of 3873 measured points which covered all geological formations, soil types and districts. The measurements were taken 1 m above the soil surface using NaI [Ti] detector. The measured gamma dose rates ranged from 9 nGy h −1 to 1237 nGy h −1 with a mean value of 151 nGy h −1 . The data have been normalized to fit a normal distribution. Tests of significance were conducted among all geological formations and soil types, using the unbalanced one way ANOVA. The results indicated strong significant differences due to the different geological formations and soil types present in Johor State. Pearson Correlation was used to measure the relations between gamma dose rate based on geological formation and soil type (D G,S ) with the gamma dose rate based on geological formation (D G ) or soil type (D s ). A very good correlation was found between D G,S and D G or D G,S and D s . A total of 118 pairs of geological formations and soil types were used to derive the statistical contribution of geological formations and soil types to gamma dose rates. The contribution of the gamma dose rate from geological formation and soil type were found to be 0.594 and 0.399, respectively. The null hypotheses were accepted for 83% of examined data, therefore, the model could be used to predict gamma dose rates based on geological formation and soil type information. - Highlights: • A very good correlation coefficient was found between D G,S and D G or D G,S and D s . • The contribution of the gamma dose rate from geological formation (GDR) is 0.594. • The contribution of the GDR from soil type was found to be 0.399. • A 83% of examined data were accepted the null hypotheses. • The model

  12. Hopping approach towards exciton dissociation in conjugated polymers

    International Nuclear Information System (INIS)

    Emelianova, E. V.; Auweraer, M. van der; Baessler, H.

    2008-01-01

    By employing random walk an analytic theory for the dissociation of singlet excitons in a random organic solid, for instance, a conjugated polymer, has been developed. At variance of conventional three-dimensional Onsager theory, it is assumed that an exciton with finite lifetime can first transfer endothermically an electron to an adjacent site, thereby generating a charge transfer state whose energy is above the energy of that of the initial exciton. In a second step the latter can fully dissociate in accordance with Onsager's concept Brownian motion. The results indicate that, depending of the energy required for the first jump, the first jump contributes significantly to the field dependence of the dissociation yield. Disorder weakens the temperature dependence of the yield dramatically and precludes extracting information on the exciton binding energy from it

  13. Spin-excitons in heavy-fermion semimetals

    Energy Technology Data Exchange (ETDEWEB)

    Riseborough, Peter S., E-mail: prisebor@temple.edu [Temple University, Philadelphia (United States); Magalhaes, S.G. [Univ. Federal, Fluminense, Niteroi, Rio de Janeiro (Brazil)

    2016-02-15

    Spin-excitons are sharp and dispersive magnetic fluctuations in paramagnetic semiconductors where the dispersion relation lies within the semiconducting gap. Spin-excitons are found in the vicinity of magnetic quantum critical points in semiconductors, much the same as antiparamagnons are precursor fluctuations for quantum critical points in metals. Here we show that this concept of spin-exciton excitations can be extended to heavy-fermion semimetals and provides a natural explanation of the magnetic modes found by inelastic neutron scattering experiments on paramagnetic CeFe{sub 2}Al{sub 10}. - Highlights: • We discuss the theory of spin excitons in heavy-fermion semiconductors as precritical fluctuations. • We show that relatively sharp magnetic in-gap excitations can also occur in semiconductors. • The magnetic excitations are only sharp for a restricted range of center of mass momenta. • They may merge with the quasi-elastic peak associated with incommensurate nesting of electron and hole pockets.

  14. Excitonic condensation in systems of strongly correlated electrons

    Czech Academy of Sciences Publication Activity Database

    Kuneš, Jan

    2015-01-01

    Roč. 27, č. 33 (2015), s. 333201 ISSN 0953-8984 Institutional support: RVO:68378271 Keywords : electronic correlations * exciton * Bose-Einstein condensation Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.209, year: 2015

  15. Growth Rates and Mechanisms of Magmatic Orbicule Formation: Insights from Calcium Isotopes

    Science.gov (United States)

    Antonelli, M. A.; Watkins, J. M.; DePaolo, D. J.

    2017-12-01

    Orbicular diorites and granites are rare plutonic rock textures that remain enigmatic despite a century of study. Orbicules consist of a rounded core (xenolith, xenocryst, or autolith) surrounded by a variable number of concentric rings defined by different modal mineralogies and textures. Recent work suggests that the alternating layers of mineral growth are a consequence of either changes in external conditions of the magma (e.g. temperature, magma composition due to mixing, changes in volatile abundances), or rapid growth of one mineral phase (e.g plagioclase) creating a depleted boundary layer that then promotes precipitation of an alternative mineral phase (e.g. pyroxene). This process can be repeated to produce multiple layers. The rates at which orbicules grow is also of interest and relates to the mechanisms. Studies of orbicular diorites from the northern Sierra Nevada suggest exceptionally high growth rates (McCarthy et al., 2016). Ca isotopes can offer a unique perspective on orbicule formation, as diffusive isotope fractionation should be substantial when growth rates are high, and they are also sensitive to the nature of the growth medium (silicate liquid or supercritical fluid phase). We present δ44Ca measurements and chemistry for a transect of a dioritic orbicule collected from Emerald Lake, California (Sierra Nevada), where the growth layers are defined by variations in plagioclase/pyroxene ratio, grain size, and texture. Ca concentration varies from 5-13 wt%, and d44Ca values oscillate between -0.5 to 0.0‰ relative to BSE, correlating with changes in mineralogy and texture. Zones of plagioclase comb texture are associated with negative δ44Ca excursions of -0.2 to -0.4‰, consistent with diffusive isotope fractionation during rapid mineral growth. Assuming a 10‰ difference in diffusivity for 44Ca vs. 40Ca in dioritic liquids (Watson et al., 2016), and using the models of Watson and Muller (2009) as a guide, these small fractionations

  16. One dimensional models of excitons in carbon nanotubes

    DEFF Research Database (Denmark)

    Cornean, Horia Decebal; Duclos, P.; Pedersen, Thomas Garm

    Excitons in carbon nanotubes may be modeled by two oppositely charged particles living on the surface of a cylinder. We derive three one dimensional effective Hamiltonians which become exact as the radius of the cylinder vanishes. Two of them are solvable.......Excitons in carbon nanotubes may be modeled by two oppositely charged particles living on the surface of a cylinder. We derive three one dimensional effective Hamiltonians which become exact as the radius of the cylinder vanishes. Two of them are solvable....

  17. Optical properties of localized excitons in semiconductor nanostructures

    DEFF Research Database (Denmark)

    Leosson, Kristjan; Hvam, Jørn Märcher; Langbein, Wolfgang Werner

    2002-01-01

    -dannede kvantepunkter. Optiske spektre af GaAs/AlAs kvantebrønde med grænseflader, der er ru på forskellige længdeskalaer, er blevet undersøgt for indvirkningen af exciton lokalisering i planen. Exciton lokalisering er også blevet studeret med stor rumlig opløsning ved hjælp af mikro-fotoluminescens. Rumligt...

  18. Decoherence suppression of excitons by bang-bang control

    International Nuclear Information System (INIS)

    Kishimoto, T.; Hasegawa, A.; Mitsumori, Y.; Ishi-Hayase, J.; Sasaki, M.; Minami, F.

    2007-01-01

    We report the demonstration of decoherence control of excitons on a layered compound semiconductor GaSe by using successive three femtosecond pulses, i.e., the six-wave mixing configuration. The second pulse acts as a π pulse which reverses the time evolution of non-Markovian dynamics. By changing the pulse interval conditions, we confirmed for the first time the suppression of exciton decoherence by π pulse irradiation

  19. Coherent secondary emission from resonantly excited two-exciton states

    DEFF Research Database (Denmark)

    Birkedal, Dan

    2000-01-01

    of the secondary emission from quantum wells following ultrafast resonant excitation and find that it provides information on not only the bound biexcitons but also the biexciton continuum. Due to the heterodyne nature of the experimental technique we obtain both amplitude and phase of the coherent emission....... This allow us to present our data using the Wiegner-function formalism and compare directly with recent theoretical results for the contribution to the nonlinear susceptibility from exciton-exciton correlation in semiconductor quantum wells....

  20. Rating Scale Items: A Brief Review of Nomenclature, Components, and Formatting to Inform the Development of Direct Behavior Rating (DBR)

    Science.gov (United States)

    Christ, Theodore J.; Boice, Christina

    2009-01-01

    Ratings scales are a common component of many multisource, multimethod frameworks for socioemotional and behavior assessment of children. There is a modest literature base to support the use of attitudinal, behavioral, and personality rating scales. Much of that historic literature focuses on the characteristics and interpretations of specific…

  1. Exciton-plasmon coupling interactions: from principle to applications

    Science.gov (United States)

    Cao, En; Lin, Weihua; Sun, Mengtao; Liang, Wenjie; Song, Yuzhi

    2018-01-01

    The interaction of exciton-plasmon coupling and the conversion of exciton-plasmon-photon have been widely investigated experimentally and theoretically. In this review, we introduce the exciton-plasmon interaction from basic principle to applications. There are two kinds of exciton-plasmon coupling, which demonstrate different optical properties. The strong exciton-plasmon coupling results in two new mixed states of light and matter separated energetically by a Rabi splitting that exhibits a characteristic anticrossing behavior of the exciton-LSP energy tuning. Compared to strong coupling, such as surface-enhanced Raman scattering, surface plasmon (SP)-enhanced absorption, enhanced fluorescence, or fluorescence quenching, there is no perturbation between wave functions; the interaction here is called the weak coupling. SP resonance (SPR) arises from the collective oscillation induced by the electromagnetic field of light and can be used for investigating the interaction between light and matter beyond the diffraction limit. The study on the interaction between SPR and exaction has drawn wide attention since its discovery not only due to its contribution in deepening and broadening the understanding of SPR but also its contribution to its application in light-emitting diodes, solar cells, low threshold laser, biomedical detection, quantum information processing, and so on.

  2. Bose condensation of interwell excitons in double quantum wells

    CERN Document Server

    Larionov, A V; Ni, P A; Dubonos, S V; Hvam, I; Soerensen, K

    2002-01-01

    The luminescence of the interwell excitons in the GaAs/AlGaAs double quantum wells, containing large-scale fluctuations of the random potential in the heteroboundary planes, is studied. The properties of the excitons, wherein the excited electron and hole are spatially separated between the neighboring quantum wells by the density and temperature variation within the domain limits of the scale below one micron, are investigated. The interwell excitons by low pumping (below 50 mW) are strongly localized due to the small-scale fluctuations of the random potential. The localized excitons line grows by increase in the resonance excitation capacity through the threshold method. With the temperature growth this line disappears in the spectrum (T sub c <= 3.4 K). The above phenomenon is related to the Bose-Einstein condensation in the quasi-two-dimensional system of the interwell excitons. The critical values of the exciton density and temperature in the studied temperature range (1.5-3.4 K) grow according to the...

  3. Acousto-exciton interaction in a gas of 2D indirect dipolar excitons in the presence of disorder

    Energy Technology Data Exchange (ETDEWEB)

    Kovalev, V. M.; Chaplik, A. V., E-mail: chaplik@isp.nsc.ru [Russian Academy of Sciences, Rzhanov Institute of Semiconductor Physics, Siberian Branch (Russian Federation)

    2016-03-15

    A theory for the linear and quadratic responses of a 2D gas of indirect dipolar excitons to an external surface acoustic wave perturbation in the presence of a static random potential is considered. The theory is constructed both for high temperatures, definitely greater than the exciton gas condensation temperature, and at zero temperature by taking into account the Bose–Einstein condensation effects. The particle Green functions, the density–density correlation function, and the quadratic response function are calculated by the “cross” diagram technique. The results obtained are used to calculate the absorption of Rayleigh surface waves and the acoustic exciton gas drag by a Rayleigh wave. The damping of Bogoliubov excitations in an exciton condensate due to theirs scattering by a random potential has also been determined.

  4. The effect of argon gas pressure on ice ball size and rate of formation.

    Science.gov (United States)

    Sprenkle, Preston C; Mirabile, Gabriella; Durak, Evren; Edelstein, Andrew; Gupta, Mantu; Hruby, Gregory W; Okhunov, Zhamshid; Landman, Jaime

    2010-09-01

    Contemporary cryoablation technology utilizes the Joule-Thomson effect, defined as a change in temperature that results from expansion of a nonideal gas through an orifice or other restriction. We evaluated the effect of initial gas tank pressures on freezing dynamics in a single-probe model and in a multiprobe model using contemporary cryoablation technology. Cryoablation trials were performed in a standardized system of transparent gelatin molds at 25°C. Two sets of trials were performed. The first trial evaluated temperature and ice ball size for a given tank pressure when a single needle was deployed. The second trial recorded ice ball temperatures for each probe when multiple probes were fired simultaneously. Trial 1: The rate of temperature change is directly related to the initial pressure of the gas being released, and the group with the highest starting pressures reached the lowest mean temperature and had the largest mean ice ball size (p probe ablation did not affect the rate of temperature change or final temperature compared with firing a single probe (p > 0.7). In accordance with the Joule-Thomson effect, higher initial gas pressures used for cryoablation in a transparent gel model demonstrate statistically significant lower temperatures, faster decreases in temperature, and formation of larger ice balls than lower gas pressures do. With contemporary technology, multiple simultaneous cryoprobe deployment does not compromise individual probe efficacy. The use of higher initial tank pressures will theoretically help future cryoprobes be more effective, creating a greater volume of cell necrosis and a smaller indeterminate zone.

  5. The radio continuum-star formation rate relation in WSRT sings galaxies

    International Nuclear Information System (INIS)

    Heesen, Volker; Brinks, Elias; Leroy, Adam K.; Heald, George; Braun, Robert; Bigiel, Frank; Beck, Rainer

    2014-01-01

    We present a study of the spatially resolved radio continuum-star formation rate (RC-SFR) relation using state-of-the-art star formation tracers in a sample of 17 THINGS galaxies. We use SFR surface density (Σ SFR ) maps created by a linear combination of GALEX far-UV (FUV) and Spitzer 24 μm maps. We use RC maps at λλ22 and 18 cm from the WSRT SINGS survey and Hα emission maps to correct for thermal RC emission. We compare azimuthally averaged radial profiles of the RC and FUV/mid-IR (MIR) based Σ SFR maps and study pixel-by-pixel correlations at fixed linear scales of 1.2 and 0.7 kpc. The ratio of the integrated SFRs from the RC emission to that of the FUV/MIR-based SF tracers is R int =0.78±0.38, consistent with the relation by Condon. We find a tight correlation between the radial profiles of the radio and FUV/MIR-based Σ SFR for the entire extent of the disk. The ratio R of the azimuthally averaged radio to FUV/MIR-based Σ SFR agrees with the integrated ratio and has only quasi-random fluctuations with galactocentric radius that are relatively small (25%). Pixel-by-pixel plots show a tight correlation in log-log diagrams of radio to FUV/MIR-based Σ SFR , with a typical standard deviation of a factor of two. Averaged over our sample we find (Σ SFR ) RC ∝(Σ SFR ) hyb 0.63±0.25 , implying that data points with high Σ SFR are relatively radio dim, whereas the reverse is true for low Σ SFR . We interpret this as a result of spectral aging of cosmic-ray electrons (CREs), which are diffusing away from the star formation sites where they are injected into the interstellar medium. This is supported by our finding that the radio spectral index is a second parameter in pixel-by-pixel plots: those data points dominated by young CREs are relatively radio dim, while those dominated by old CREs are slightly more RC bright than what would be expected from a linear extrapolation. We studied the ratio R of radio to FUV/MIR-based integrated SFR as a function of

  6. PANCHROMATIC ESTIMATION OF STAR FORMATION RATES IN BzK GALAXIES AT 1 < z < 3

    Energy Technology Data Exchange (ETDEWEB)

    Kurczynski, Peter; Gawiser, Eric [Department of Physics and Astronomy, Rutgers University, Piscataway, NJ 08854 (United States); Huynh, Minh [International Centre for Radio Astronomy Research, University of Western Australia M468, 35 Stirling Highway, Crawley, WA 6009 (Australia); Ivison, Rob J. [UK Astronomy Technology Centre, Royal Observatory, Blackford Hill, Edinburgh EH9 3HJ (United Kingdom); Treister, Ezequiel [Institute for Astronomy, University of Hawaii, 2680 Woodlawn Drive, Honolulu, HI 96822 (United States); Smail, Ian [Institute for Computational Cosmology, Department of Physics, Durham University, South Road, Durham DH1 3LE (United Kingdom); Blanc, Guillermo A. [Department of Astronomy, The University of Texas at Austin, Austin, TX (United States); Cardamone, Carolin N. [Physics Department, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States); Greve, Thomas R.; Schinnerer, Eva; Van der Werf, Paul [MPI for Astronomy, Koenigstuhl 17, 69117 Heidelberg (Germany); Urry, Meg [Department of Physics, Yale University, P.O. Box 208121, New Haven, CT 06520-8121 (United States)

    2012-05-10

    We determine star formation rates (SFRs) in a sample of color-selected, star-forming (sBzK) galaxies (K{sub AB} < 21.8) in the Extended Chandra Deep Field-South. To identify and avoid active galactic nuclei, we use X-ray, IRAC color, and IR/radio flux ratio selection methods. Photometric redshift-binned, average flux densities are measured with stacking analyses in Spitzer-MIPS IR, BLAST and APEX/LABOCA submillimeter, VLA and GMRT radio, and Chandra X-ray data. We include averages of aperture fluxes in MUSYC UBVRIz'JHK images to determine UV-through-radio spectral energy distributions. We determine the total IR luminosities and compare SFR calibrations from FIR, 24 {mu}m, UV, radio, and X-ray wavebands. We find consistency with our best estimator, SFR{sub IR+UV}, to within errors for the preferred radio SFR calibration. Our results imply that 24 {mu}m only and X-ray SFR estimates should be applied to high-redshift galaxies with caution. Average IR luminosities are consistent with luminous infrared galaxies. We find SFR{sub IR+UV} for our stacked sBzKs at median redshifts 1.4, 1.8, and 2.2 to be 55 {+-} 6 (random error), 74 {+-} 8, and 154 {+-} 17 M{sub Sun} yr{sup -1}, respectively, with additional systematic uncertainty of a factor of {approx}2.

  7. A Multiwavelength Approach to the Star Formation Rate Estimation in Galaxies at Intermediate Redshifts

    Science.gov (United States)

    Cardiel, N.; Elbaz, D.; Schiavon, R. P.; Willmer, C. N. A.; Koo, D. C.; Phillips, A. C.; Gallego, J.

    2003-02-01

    We use a sample of seven starburst galaxies at intermediate redshifts (z~0.4 and 0.8) with observations ranging from the observed ultraviolet to 1.4 GHz, to compare the star formation rate (SFR) estimators that are used in the different wavelength regimes. We find that extinction-corrected Hα underestimates the SFR, and the degree of this underestimation increases with the infrared luminosity of the galaxies. Galaxies with very different levels of dust extinction as measured with SFRIR/SFR(Hα, uncorrected for extinction) present a similar attenuation A[Hα], as if the Balmer lines probed a different region of the galaxy than the one responsible for the bulk of the IR luminosity for large SFRs. In addition, SFR estimates derived from [O II] λ3727 match very well those inferred from Hα after applying the metallicity correction derived from local galaxies. SFRs estimated from the UV luminosities show a dichotomic behavior, similar to that previously reported by other authors in galaxies at zfinancial support of the W. M. Keck Foundation. Based in part on observations with the NASA/ESA Hubble Space Telescope, obtained at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS 5-26555. Based in part on observations with the Infrared Space Observatory (ISO), an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, Netherlands, and United Kingdom) with the participation of ISAS and NASA.

  8. A Model Connecting Galaxy Masses, Star Formation Rates, and Dust Temperatures across Cosmic Time

    Science.gov (United States)

    Imara, Nia; Loeb, Abraham; Johnson, Benjamin D.; Conroy, Charlie; Behroozi, Peter

    2018-02-01

    We investigate the evolution of dust content in galaxies from redshifts z = 0 to z = 9.5. Using empirically motivated prescriptions, we model galactic-scale properties—including halo mass, stellar mass, star formation rate, gas mass, and metallicity—to make predictions for the galactic evolution of dust mass and dust temperature in main-sequence galaxies. Our simple analytic model, which predicts that galaxies in the early universe had greater quantities of dust than their low-redshift counterparts, does a good job of reproducing observed trends between galaxy dust and stellar mass out to z ≈ 6. We find that for fixed galaxy stellar mass, the dust temperature increases from z = 0 to z = 6. Our model forecasts a population of low-mass, high-redshift galaxies with interstellar dust as hot as, or hotter than, their more massive counterparts; but this prediction needs to be constrained by observations. Finally, we make predictions for observing 1.1 mm flux density arising from interstellar dust emission with the Atacama Large Millimeter Array.

  9. Current denudation rates in dolostone karst from central Spain: Implications for the formation of unroofed caves

    Science.gov (United States)

    Krklec, Kristina; Domínguez-Villar, David; Carrasco, Rosa M.; Pedraza, Javier

    2016-07-01

    depth, we consider that this is a more reliable denudation rate for the studied location during the studied period. The calculated weathering rate suggests that denudation has a limited contribution to the thinning of bedrock over caves at this site. Therefore, we consider that the formation of unroofed caves in this region most likely results from the thinning of bedrock cover over caves due to collapse of blocks from their ceilings.

  10. Impact of charge-transfer excitons in regioregular polythiophene on the charge separation at polythiophene-fullerene heterojunctions

    Science.gov (United States)

    Polkehn, M.; Tamura, H.; Burghardt, I.

    2018-01-01

    This study addresses the mechanism of ultrafast charge separation in regioregular oligothiophene-fullerene assemblies representative of poly-3-hexylthiophene (P3HT)-[6,6]-phenyl-C61 butyric acid methyl ester (PCBM) heterojunctions, with special emphasis on the inclusion of charge transfer excitons in the oligothiophene phase. The formation of polaronic inter-chain charge separated species in highly ordered oligothiophene has been demonstrated in recent experiments and could have a significant impact on the net charge transfer to the fullerene acceptor. The present approach combines a first-principles parametrized multi-site Hamiltonian, based on time-dependent density functional theory calculations, with accurate quantum dynamics simulations using the multi-layer multi-configuration time-dependent Hartree method. Quantum dynamical studies are carried out for up to 182 electronic states and 112 phonon modes. The present analysis follows up on our previous study of (Huix-Rotllant et al 2015 J. Phys. Chem. Lett. 6 1702) and significantly expands the scope of this analysis by including the dynamical role of charge transfer excitons. Our investigation highlights the pronounced mixing of photogenerated Frenkel excitons with charge transfer excitons in the oligothiophene domain, and the opening of new transfer channels due the creation of such charge-separated species. As a result, it turns out that the interfacial donor/acceptor charge transfer state can be largely circumvented due to the presence of charge transfer excitons. However, the latter states in turn act as a trap, such that the free carrier yield observed on ultrafast time scales is tangibly reduced. The present analysis underscores the complexity of the transfer pathways at P3HT-PCBM type junctions.

  11. Rate of formation and dissolution of mercury sulfide nanoparticles: The dual role of natural organic matter

    Science.gov (United States)

    Slowey, Aaron J.

    2010-01-01

    Mercury is a global contaminant of concern due to its transformation by microorganisms to form methylmercury, a toxic species that accumulates in biological tissues. The effect of dissolved organic matter (DOM) isolated from natural waters on reactions between mercury(II) (Hg) and sulfide (S(-II)) to form HgS(s) nanoparticles across a range of Hg and S(-II) concentrations was investigated. Hg was equilibrated with DOM, after which S(-II) was added. Dissolved Hg (Hgaq) was periodically quantified using ultracentrifugation and chemical analysis following the addition of S(-II). Particle size and identity were determined using dynamic light scattering and X-ray absorption spectroscopy. S(-II) reacts with Hg to form 20 to 200nm aggregates consisting of 1-2 nm HgS(s) subunits that are more structurally disordered than metacinnabar in the presence of 2 x 10-9 to 8 x 10-6M Hg and 10 (mg C)L-1 DOM. Some of the HgS(s) nanoparticle aggregates are subsequently dissolved by DOM and (re)precipitated by S(-II) over periods of hours to days. At least three fractions of Hg-DOM species were observed with respect to reactivity toward S(-II): 0.3 μmol reactive Hg per mmol C (60 percent), 0.1 μmol per mmol C (20 percent) that are kinetically hindered, and another 0.1 μmol Hg per mmol C (20 percent) that are inert to reaction with S(-II). Following an initial S(-II)-driven precipitation of HgS(s), HgS(s) was dissolved by DOM or organic sulfur compounds. HgS(s) formation during this second phase was counterintuitively favored by lower S(-II) concentrations, suggesting surface association of DOM moieties that are less capable of dissolving HgS(s). DOM partially inhibits HgS(s) formation and mediates reactions between Hg and S(-II) such that HgS(s) is susceptible to dissolution. These findings indicate that Hg accessibility to microorganisms could be controlled by kinetic (intermediate) species in the presence of S(-II) and DOM, undermining the premise that equilibrium Hg species

  12. Probing the Interlayer Exciton Physics in a MoS2/MoSe2/MoS2 van der Waals Heterostructure.

    Science.gov (United States)

    Baranowski, M; Surrente, A; Klopotowski, L; Urban, J M; Zhang, N; Maude, D K; Wiwatowski, K; Mackowski, S; Kung, Y C; Dumcenco, D; Kis, A; Plochocka, P

    2017-10-11

    Stacking atomic monolayers of semiconducting transition metal dichalcogenides (TMDs) has emerged as an effective way to engineer their properties. In principle, the staggered band alignment of TMD heterostructures should result in the formation of interlayer excitons with long lifetimes and robust valley polarization. However, these features have been observed simultaneously only in MoSe 2 /WSe 2 heterostructures. Here we report on the observation of long-lived interlayer exciton emission in a MoS 2 /MoSe 2 /MoS 2 trilayer van der Waals heterostructure. The interlayer nature of the observed transition is confirmed by photoluminescence spectroscopy, as well as by analyzing the temporal, excitation power, and temperature dependence of the interlayer emission peak. The observed complex photoluminescence dynamics suggests the presence of quasi-degenerate momentum-direct and momentum-indirect bandgaps. We show that circularly polarized optical pumping results in long-lived valley polarization of interlayer exciton. Intriguingly, the interlayer exciton photoluminescence has helicity opposite to the excitation. Our results show that through a careful choice of the TMDs forming the van der Waals heterostructure it is possible to control the circular polarization of the interlayer exciton emission.

  13. Burst Format Design for Optimum Joint Estimation of Doppler-Shift and Doppler-Rate in Packet Satellite Communications

    Directory of Open Access Journals (Sweden)

    Luca Giugno

    2007-05-01

    Full Text Available This paper considers the problem of optimizing the burst format of packet transmission to perform enhanced-accuracy estimation of Doppler-shift and Doppler-rate of the carrier of the received signal, due to relative motion between the transmitter and the receiver. Two novel burst formats that minimize the Doppler-shift and the Doppler-rate Cramér-Rao bounds (CRBs for the joint estimation of carrier phase/Doppler-shift and of the Doppler-rate are derived, and a data-aided (DA estimation algorithm suitable for each optimal burst format is presented. Performance of the newly derived estimators is evaluated by analysis and by simulation, showing that such algorithms attain their relevant CRBs with very low complexity, so that they can be directly embedded into new-generation digital modems for satellite communications at low SNR.

  14. Burst Format Design for Optimum Joint Estimation of Doppler-Shift and Doppler-Rate in Packet Satellite Communications

    Directory of Open Access Journals (Sweden)

    Zanier Francesca

    2007-01-01

    Full Text Available This paper considers the problem of optimizing the burst format of packet transmission to perform enhanced-accuracy estimation of Doppler-shift and Doppler-rate of the carrier of the received signal, due to relative motion between the transmitter and the receiver. Two novel burst formats that minimize the Doppler-shift and the Doppler-rate Cramér-Rao bounds (CRBs for the joint estimation of carrier phase/Doppler-shift and of the Doppler-rate are derived, and a data-aided (DA estimation algorithm suitable for each optimal burst format is presented. Performance of the newly derived estimators is evaluated by analysis and by simulation, showing that such algorithms attain their relevant CRBs with very low complexity, so that they can be directly embedded into new-generation digital modems for satellite communications at low SNR.

  15. Characterization and refinement of carbide coating formation rates and dissolution kinetics in the Ta-C system

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez, Patrick James [Univ. of New Mexico, Albuquerque, NM (United States)

    1996-10-01

    The interaction between carbide coating formation rates and dissolution kinetics in the tantalum-carbon system was investigated. The research was driven by the need to characterize carbide coating formation rates. The characterization of the carbide coating formation rates was required to engineer an optimum processing scheme for the fabrication of the ultracorrosion-resistant composite, carbon-saturated tantalum. A packed-bed carburization process was successfully engineered and employed. The packed-bed carburization process produced consistent, predictable, and repeatable carbide coatings. A digital imaging analysis measurement process for accurate and consistent measurement of carbide coating thicknesses was developed. A process for removing the chemically stable and extremely hard tantalum-carbide coatings was also developed in this work.

  16. Exciton condensation and perfect Coulomb drag.

    Science.gov (United States)

    Nandi, D; Finck, A D K; Eisenstein, J P; Pfeiffer, L N; West, K W

    2012-08-23

    Coulomb drag is a process whereby the repulsive interactions between electrons in spatially separated conductors enable a current flowing in one of the conductors to induce a voltage drop in the other. If the second conductor is part of a closed circuit, a net current will flow in that circuit. The drag current is typically much smaller than the drive current owing to the heavy screening of the Coulomb interaction. There are, however, rare situations in which strong electronic correlations exist between the two conductors. For example, double quantum well systems can support exciton condensates, which consist of electrons in one well tightly bound to holes in the other. 'Perfect' drag is therefore expected; a steady transport current of electrons driven through one quantum well should be accompanied by an equal current of holes in the other. Here we demonstrate this effect, taking care to ensure that the electron-hole pairs dominate the transport and that tunnelling of charge between the quantum wells, which can readily compromise drag measurements, is negligible. We note that, from an electrical engineering perspective, perfect Coulomb drag is analogous to an electrical transformer that functions at zero frequency.

  17. On the reversal of star formation rate-density relation at z = 1: Insights from simulations

    International Nuclear Information System (INIS)

    Tonnesen, Stephanie; Cen, Renyue

    2014-01-01

    Recent surveys have found a reversal of the star formation rate (SFR)-density relation at z = 1 from that at z = 0, while the sign of the slope of the color-density relation remains unchanged. We use adaptive mesh refinement cosmological hydrodynamic simulations of a 21 × 24 × 20 h –3 Mpc 3 region to examine the SFR-density and color-density relations of galaxies at z = 0 and z = 1. The local environmental density is defined by the dark matter mass in spheres of radius 1 h –1 Mpc, and we probe two decades of environmental densities. Our simulations produce a large increase of SFR with density at z = 1, as in the Elbaz et al. observations. We also find a significant evolution to z = 0, where the SFR-density relation is much flatter. The simulated color-density relation is consistent from z = 1 to z = 0, in agreement with observations. We find that the increase in SFR with local density at z = 1 is due to a growing population of star-forming galaxies in higher-density environments. At z = 0 and z = 1 both the SFR and cold gas mass are correlated with the galaxy halo mass, and therefore the correlation between median halo mass and local density is an important cause of the SFR-density relation at both redshifts. However, at z = 0 the local density on 1 h –1 Mpc scales affects galaxy SFRs as much as halo mass. Finally, we find indications that while at z = 0 high-density environments depress galaxy SFRs, at z = 1 high-density environments tend to increase SFRs.

  18. Bit-rate-transparent optical RZ-to-NRZ format conversion based on linear spectral phase filtering

    DEFF Research Database (Denmark)

    Maram, Reza; Da Ros, Francesco; Guan, Pengyu

    2017-01-01

    We propose a novel and strikingly simple design for all-optical bit-rate-transparent RZ-to-NRZ conversion based on optical phase filtering. The proposed concept is experimentally validated through format conversion of a 640 Gbit/s coherent RZ signal to NRZ signal.......We propose a novel and strikingly simple design for all-optical bit-rate-transparent RZ-to-NRZ conversion based on optical phase filtering. The proposed concept is experimentally validated through format conversion of a 640 Gbit/s coherent RZ signal to NRZ signal....

  19. Comparison of intelligent systems, artificial neural networks and neural fuzzy model for prediction of gas hydrate formation rate

    Directory of Open Access Journals (Sweden)

    Mohammad Javad Jalalnezhad

    2014-05-01

    Full Text Available The main objective of this study was to present a novel approach for predication of gas hydrate formation rate based on the Intelligent Systems. Using a data set including about 470 data obtained from flow tests in a mini-loop apparatus, different predictive models were developed. From the results predicted by these models, it can be pointed out that the developed models can be used as powerful tools for prediction of gas hydrate formation rate with total errors of less than 4%.

  20. Formation rate of ammonium nitrate in the off-gas line of SRAT and SME in DWPF

    International Nuclear Information System (INIS)

    Lee, L.

    1992-01-01

    A mathematical model for the formation rate of ammonium nitrate in the off-gas line of the Sludge Receipt and Adjustment Tank (SRAT) and the Slurry Mixed Evaporator (SME) in DWPF has been developed. The formation rate of ammonium nitrate in the off-gas line depends on pH, temperature, volume and total concentration of ammonia and ammonium ion. Based on a typical SRAT and SME cycle in DWPF, this model predicts the SRAT contributes about 50 lbs of ammonium nitrate while SME contributes about 60 lbs of ammonium nitrate to the off-gas line

  1. Excitons in coupled type-II double quantum wells under electric and magnetic fields: InAs/AlSb/GaSb

    Energy Technology Data Exchange (ETDEWEB)

    Lyo, S. K., E-mail: sklyo@uci.edu [Department of Physics and Astronomy, University of California, Irvine, California 92697 (United States); Pan, W. [Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States)

    2015-11-21

    We calculate the wave functions and the energy levels of an exciton in double quantum wells under electric (F) and magnetic (B) fields along the growth axis. The result is employed to study the energy levels, the binding energy, and the boundary on the F–B plane of the phase between the indirect exciton ground state and the semiconductor ground state for several typical structures of the type-II quasi-two-dimensional quantum wells such as InAs/AlSb/GaSb. The inter-well inter-band radiative transition rates are calculated for exciton creation and recombination. We find that the rates are modulated over several orders of magnitude by the electric and magnetic fields.

  2. Rate of Iron Transfer Through the Horse Spleen Ferritin Shell Determined by the Rate of Formation of Prussian Blue and Fe-desferrioxamine Within the Ferritin Cavity

    Science.gov (United States)

    Zhang, Bo; Watt, Richard K.; Galvez, Natividad; Dominquez-Vera, Jose M.; Watt, Gerald D.

    2005-01-01

    Iron (2+ and 3+) is believed to transfer through the three-fold channels in the ferritin shell during iron deposition and release in animal ferritins. However, the rate of iron transit in and out through these channels has not been reported. The recent synthesis of [Fe(CN)(sub 6)](3-), Prussian Blue (PB) and desferrioxamine (DES) all trapped within the horse spleen ferritin (HoSF) interior makes these measurements feasible. We report the rate of Fe(2+) penetrating into the ferritin interior by adding external Fe(2+) to [Fe(CN)(sub 6)](3-) encapsulated in the HoSF interior and measuring the rate of formation of the resulting encapsulated PB. The rate at which Fe(2+) reacts with [Fe(CN)(sub 6)](3-) in the HoSF interior is much slower than the formation of free PB in solution and is proceeded by a lag period. We assume this lag period and the difference in rate represent the transfer of Fe(2+) through the HoSF protein shell. The calculated diffusion coefficient, D approx. 5.8 x 10(exp -20) square meters per second corresponds to the measured lag time of 10-20 s before PB forms within the HoSF interior. The activation energy for Fe(2+) transfer from the outside solution through the protein shell was determined to be 52.9 kJ/mol by conducting the reactions at 10 to approximately 40 C. The reaction of Fe(3+) with encapsulated [Fe(CN)6](4-) also readily forms PB in the HoSF interior, but the rate is faster than the corresponding Fe(2+) reaction. The rate for Fe(3+) transfer through the ferritin shell was confirmed by measuring the rate of the formation of Fe-DES inside HoSF and an activation energy of 58.4 kJ/mol was determined. An attempt was made to determine the rate of iron (2+ and 3+) transit out from the ferritin interior by adding excess bipyridine or DES to PB trapped within the HoSF interior. However, the reactions are slow and occur at almost identical rates for free and HoSF-encapsulated PB, indicating that the transfer of iron from the interior through the

  3. Modulating Excitonic Recombination Effects through One-Step Synthesis of Perovskite Nanoparticles for Light-Emitting Diodes.

    Science.gov (United States)

    Kulkarni, Sneha A; Muduli, Subas; Xing, Guichuan; Yantara, Natalia; Li, Mingjie; Chen, Shi; Sum, Tze Chien; Mathews, Nripan; White, Tim J; Mhaisalkar, Subodh G

    2017-10-09

    The primary advantages of halide perovskites for light-emitting diodes (LEDs) are solution processability, direct band gap, good charge-carrier diffusion lengths, low trap density, and reasonable carrier mobility. The luminescence in 3 D halide perovskite thin films originates from free electron-hole bimolecular recombination. However, the slow bimolecular recombination rate is a fundamental performance limitation. Perovskite nanoparticles could result in improved performance but processability and cumbersome synthetic procedures remain challenges. Herein, these constraints are overcome by tailoring the 3 D perovskite as a near monodisperse nanoparticle film prepared through a one-step in situ deposition method. Replacing methyl ammonium bromide (CH 3 NH 3 Br, MABr) partially by octyl ammonium bromide [CH 3 (CH 2 ) 7 NH 3 Br, OABr] in defined mole ratios in the perovskite precursor proved crucial for the nanoparticle formation. Films consisting of the in situ formed nanoparticles displayed signatures associated with excitonic recombination, rather than that of bimolecular recombination associated with 3 D perovskites. This transition was accompanied by enhanced photoluminescence quantum yield (PLQY≈20.5 % vs. 3.40 %). Perovskite LEDs fabricated from the nanoparticle films exhibit a one order of magnitude improvement in current efficiency and doubling in luminance efficiency. The material processing systematics derived from this study provides the means to control perovskite morphologies through the selection and mixing of appropriate additives. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Electrically Controlled Coherent Excitonic Steady States in Semiconductor Bilayers

    Science.gov (United States)

    Xie, Ming; MacDonald, Allan

    Spatially indirect excitons are long lived bosonic quasiparticles that can form quasi-equilibrium condensed states. Optical access to these excitons has been limited by their small optical matrix elements. Here we propose a promising electrical process that can be used both to populate and to probe fluids of indirect excitons, and is analogous to the crossed Andreev reflection (CAR) process of Cooper pairs in superconductors. We consider vertically stacked multilayer heterostructures containing two transition metal dichalcogenide (TMD) layers that host the indirect excitons, graphene layers on the top and the bottom of the heterostructure, and hBN tunnel barrier layers of variable thickness. When the bias voltage between the graphene leads is smaller than the indirect gap, tunneling between the graphene leads and the TMD hetero-bilayer is possible only through the CAR process. Both DC and low frequency AC bias cases are explored and establish that electrical measurements can be used to determine crucial properties such as the condensate density, interaction strength and CAR tunneling amplitudes. We have also proposed a way to electrically manipulate another type of bosonic quasiparticles, cavity exciton-polaritons, in a laterally contacted structure.

  5. Effect of disorder on exciton dissociation in conjugated polymers

    International Nuclear Information System (INIS)

    Feng Yuwen; Zhao Hui; Chen Yuguang; Yan Yonghong

    2017-01-01

    By using a multi-configurational time-dependent Hartree–Fock (MCTDHF) method for the time-dependent Schrödinger equation and a Newtonian equation of motion for lattice, we investigate the disorder effects on the dissociation process of excitons in conjugated polymer chains. The simulations are performed within the framework of an extended version of the Su–Schrieffer–Heeger model modified to include on-site disorder, off-diagonal, electron–electron interaction, and an external electric field. Our results show that Coulomb correlation effects play an important role in determining the exciton dissociation process. The electric field required to dissociate an exciton can practically impossibly occur in a pure polymer chain, especially in the case of triplet exciton. However, when the on-site disorder effects are taken into account, this leads to a reduction in mean dissociation electric fields. As the disorder strength increases, the dissociation field decreases effectively. On the contrary, the effects of off-diagonal disorder are negative in most cases. Moreover, the dependence of exciton dissociation on the conjugated length is also discussed. (paper)

  6. Excitons in InP/InAs inhomogeneous quantum dots

    CERN Document Server

    Assaid, E; Khamkhami, J E; Dujardin, F

    2003-01-01

    Wannier excitons confined in an InP/InAs inhomogeneous quantum dot (IQD) have been studied theoretically in the framework of the effective mass approximation. A finite-depth potential well has been used to describe the effect of the quantum confinement in the InAs layer. The exciton binding energy has been determined using the Ritz variational method. The spatial correlation between the electron and the hole has been taken into account in the expression for the wavefunction. It has been shown that for a fixed size b of the IQD, the exciton binding energy depends strongly on the core radius a. Moreover, it became apparent that there are two critical values of the core radius, a sub c sub r sub i sub t and a sub 2 sub D , for which important changes of the exciton binding occur. The former critical value, a sub c sub r sub i sub t , corresponds to a minimum of the exciton binding energy and may be used to distinguish between tridimensional confinement and bidimensional confinement. The latter critical value, a ...

  7. Inverse Funnel Effect of Excitons in Strained Black Phosphorus

    Directory of Open Access Journals (Sweden)

    Pablo San-Jose

    2016-09-01

    Full Text Available We study the effects of strain on the properties and dynamics of Wannier excitons in monolayer (phosphorene and few-layer black phosphorus (BP, a promising two-dimensional material for optoelectronic applications due to its high mobility, mechanical strength, and strain-tunable direct band gap. We compare the results to the case of molybdenum disulphide (MoS_{2} monolayers. We find that the so-called funnel effect, i.e., the possibility of controlling exciton motion by means of inhomogeneous strains, is much stronger in few-layer BP than in MoS_{2} monolayers and, crucially, is of opposite sign. Instead of excitons accumulating isotropically around regions of high tensile strain like in MoS_{2}, excitons in BP are pushed away from said regions. This inverse funnel effect is moreover highly anisotropic, with much larger funnel distances along the armchair crystallographic direction, leading to a directional focusing of exciton flow. A strong inverse funnel effect could enable simpler designs of funnel solar cells and offer new possibilities for the manipulation and harvesting of light.

  8. Star Formation at Low Rates: How a Lack of Massive Stars Impacts the Evolution of Dwarf Galaxies

    Science.gov (United States)

    Hensler, Gerhard

    2017-01-01

    In recent years dedicated observations have uncovered star formation at extremely low rates in dwarf galaxies, tidal tails, ram-pressure stripped gas clouds, and the outskirts of galactic disks. At the same time, numerical simulations of galaxy evolution have advanced to higher spatial and mass resolutions, but have yet to account for the underfilling of the uppermost mass bins of stellar initial mass function (IMF) at low star-formation rates. In such situations, simulations may simply scale down the IMF, without realizing that this unrealistically results infractions of massive stars, along with fractions of massive star feedback energy (e.g., radiation and SNII explosions). Not properlyaccounting for such parameters has consequences for the self-regulation of star formation, the energetics of galaxies, as well as for the evolution of chemical abundances.Here we present numerical simulations of dwarf galaxies with low star-formation rates allowing for two extreme cases of the IMF: a "filled" case with fractional massive stars vs. a truncated IMF, at which the IMF is built bottom-up until the gas reservoir allows the formation of a last single star at an uppermost mass. The aim of the study is to demonstrate the different effects on galaxy evolution with respect to self-regulation, feedback, and chemistry. The case of a stochastic sampled IMF is situated somewhere in between these extremes.

  9. Exciton diffusion in WSe2 monolayers embedded in a van der Waals heterostructure

    Science.gov (United States)

    Cadiz, F.; Robert, C.; Courtade, E.; Manca, M.; Martinelli, L.; Taniguchi, T.; Watanabe, K.; Amand, T.; Rowe, A. C. H.; Paget, D.; Urbaszek, B.; Marie, X.

    2018-04-01

    We have combined spatially resolved steady-state micro-photoluminescence with time-resolved photoluminescence to investigate the exciton diffusion in a WSe2 monolayer encapsulated with hexagonal boron nitride. At 300 K, we extract an exciton diffusion length of LX = 0.36 ± 0.02 μm and an exciton diffusion coefficient of DX = 14.5 ± 2 cm2/s. This represents a nearly 10-fold increase in the effective mobility of excitons with respect to several previously reported values on nonencapsulated samples. At cryogenic temperatures, the high optical quality of these samples has allowed us to discriminate the diffusion of the different exciton species: bright and dark neutral excitons, as well as charged excitons. The longer lifetime of dark neutral excitons yields a larger diffusion length of LXD=1.5 ±0.02 μ m.

  10. Alternative approaches to electronic damage by ion-beam irradiation: Exciton models

    Energy Technology Data Exchange (ETDEWEB)

    Agullo-Lopez, F.; Munoz-Martin, A.; Zucchiatti, A. [Centro de Micro-Analisis de Materiales, Universidad Autonoma de Madrid, 28049, Madrid (Spain); Climent-Font, A. [Centro de Micro-Analisis de Materiales, Universidad Autonoma de Madrid, 28049, Madrid (Spain); Departamento de Fisica Aplicada, Universidad Autonoma de Madrid, 28049, Madrid (Spain)

    2016-11-15

    The paper briefly describes the main features of the damage produced by swift heavy ion (SHI) irradiation. After a short revision of the widely used thermal spike concept, it focuses on cumulative mechanisms of track formation which are alternative to those based on lattice melting (thermal spike models). These cumulative mechanisms rely on the production of point defects around the ion trajectory, and their accumulation up to a final lattice collapse or amorphization. As to the formation of point defects, the paper considers those mechanisms relying on direct local conversion of the excitation energy into atomic displacements (exciton models). A particular attention is given to processes based on the non-radiative recombination of excitons that have become self-trapped as a consequence of a strong electron-phonon interaction (STEs). These mechanisms, although operative under purely ionizing radiation in some dielectric materials, have been rarely invoked, so far, to discuss SHI damage. They are discussed in this paper together with relevant examples to materials such as Cu{sub 3}N, alkali halides, SiO{sub 2}, and LiNbO{sub 3}. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  11. Star formation rate and extinction in faint z ∼ 4 Lyman break galaxies

    Energy Technology Data Exchange (ETDEWEB)

    To, Chun-Hao; Wang, Wei-Hao [Institute of Astronomy and Astrophysics, Academia Sinica, No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan (China); Owen, Frazer N. [National Radio Astronomy Observatory, P.O. Box 0, Socorro, NM 87801 (United States)

    2014-09-10

    We present a statistical detection of 1.5 GHz radio continuum emission from a sample of faint z ∼ 4 Lyman break galaxies (LBGs). To constrain their extinction and intrinsic star formation rate (SFR), we combine the latest ultradeep Very Large Array 1.5 GHz radio image and the Hubble Space Telescope Advanced Camera for Surveys (ACS) optical images in the GOODS-N. We select a large sample of 1771 z ∼ 4 LBGs from the ACS catalog using B {sub F435W}-dropout color criteria. Our LBG samples have I {sub F775W} ∼ 25-28 (AB), ∼0-3 mag fainter than M{sub UV}{sup ⋆} at z ∼ 4. In our stacked radio images, we find the LBGs to be point-like under our 2'' angular resolution. We measure their mean 1.5 GHz flux by stacking the measurements on the individual objects. We achieve a statistical detection of S {sub 1.5} {sub GHz} = 0.210 ± 0.075 μJy at ∼3σ for the first time on such a faint LBG population at z ∼ 4. The measurement takes into account the effects of source size and blending of multiple objects. The detection is visually confirmed by stacking the radio images of the LBGs, and the uncertainty is quantified with Monte Carlo simulations on the radio image. The stacked radio flux corresponds to an obscured SFR of 16.0 ± 5.7 M {sub ☉} yr{sup –1}, and implies a rest-frame UV extinction correction factor of 3.8. This extinction correction is in excellent agreement with that derived from the observed UV continuum spectral slope, using the local calibration of Meurer et al. This result supports the use of the local calibration on high-redshift LBGs to derive the extinction correction and SFR, and also disfavors a steep reddening curve such as that of the Small Magellanic Cloud.

  12. Digestion of high rate activated sludge coupled to biochar formation for soil improvement in the tropics.

    Science.gov (United States)

    Nansubuga, Irene; Banadda, Noble; Ronsse, Frederik; Verstraete, Willy; Rabaey, Korneel

    2015-09-15

    High rate activated sludge (HRAS) is well-biodegradable sludge enabling energy neutrality of wastewater treatment plants via anaerobic digestion. However, even through successful digestion a notable residue still remains. Here we investigated whether this residue can be converted to biochar, for its use as a fertilizer or as a solid fuel, and assessed its characteristics and overall process efficiency. In a first phase, HRAS was anaerobicaly digested under mesophilic conditions at a sludge retention time of 20 days. HRAS digested well (57.9 ± 6.2% VS degradation) producing on average 0.23 ± 0.04 L CH4 per gram VS fed. The digestate particulates were partially air-dried to mimic conditions used in developing countries, and subsequently converted to biochar by fixed-bed slow pyrolysis at a residence time of 15 min and at highest heating temperatures (HHT) of 300 °C, 400 °C and 600 °C. Subsequently, the produced chars were characterized by proximate analysis, CHN-elemental analysis, pH in solution and bomb calorimetry for higher heating value. The yield and volatile matter decreased with increasing HHT while ash content and fixed carbon increased with increasing HHT. The produced biochar showed properties optimal towards soil amendment when produced at a temperature of 600 °C with values of 5.91 wt%, 23.75 wt%, 70.35% on dry basis (db) and 0.44 for volatile matter, fixed carbon, ash content and H/C ratio, respectively. With regard to its use for energy purposes, the biochar represented a lower calorific value than the dried HRAS digestate likely due to high ash content. Based on these findings, it can be concluded that anaerobic digestion of HRAS and its subsequent biochar formation at HHT of 600 °C represents an attractive route for sludge management in tropic settings like in Uganda, coupling carbon capture to energy generation, carbon sequestration and nutrient recovery. Copyright © 2015 Elsevier Ltd. All rights reserved.

  13. Measurement of the spin and temperature dependence of the ddμ-molecule formation rate in solid and liquid deuterium

    International Nuclear Information System (INIS)

    Demin, D.L.; Drebushko, A.E.; Dzhelepov, V.P.

    1996-01-01

    Ddμ molecule formation rates have been measured from the two hyperfine states of the dμ-atom in the temperature range of T=5-30 K. Results are consistent with the measurement of the TRIUMF group at T=3 K and contradict theoretical predictions. The work was performed on the JINR phasotron (Dubna). 23 refs., 10 figs.; 2 tabs

  14. Reconfigurable Digital Coherent Receiver for Metro-Access Networks Supporting Mixed Modulation Formats and Bit-rates

    DEFF Research Database (Denmark)

    Caballero Jambrina, Antonio; Guerrero Gonzalez, Neil; Arlunno, Valeria

    2013-01-01

    A single, reconfigurable, digital coherent receiver is proposed and experimentally demonstrated for converged wireless and optical fiber transport. The capacity of reconstructing the full transmitted optical field allows for the demodulation of mixed modulation formats and bit-rates. We performed...

  15. Optical control of charged exciton states in tungsten disulfide

    Energy Technology Data Exchange (ETDEWEB)

    Currie, M.; Hanbicki, A. T.; Jonker, B. T. [Naval Research Laboratory, Washington, DC 20375 (United States); Kioseoglou, G. [University of Crete, Heraklion, Crete 71003 (Greece); Institute of Electronic Structure and Laser (IESL), Foundation for Research and Technology Hellas (FORTH), Heraklion, Crete 71110 (Greece)

    2015-05-18

    A method is presented for optically preparing WS{sub 2} monolayers to luminescence from only the charged exciton (trion) state–completely suppressing the neutral exciton. When isolating the trion state, we observed changes in the Raman A{sub 1g} intensity and an enhanced feature on the low energy side of the E{sup 1}{sub 2g} peak. Photoluminescence and optical reflectivity measurements confirm the existence of the prepared trion state. This technique also prepares intermediate regimes with controlled luminescence amplitudes of the neutral and charged exciton. This effect is reversible by exposing the sample to air, indicating the change is mitigated by surface interactions with the ambient environment. This method provides a tool to modify optical emission energy and to isolate physical processes in this and other two-dimensional materials.

  16. Excitons in van der Waals Heterostructures: A theoretical study

    DEFF Research Database (Denmark)

    Latini, Simone

    in a generalized hydrogenic model to compute exciton binding energies in isolated, supported, or encapsulated 2D semiconductors. The non-locality of the dielectric screening is inherently included in our method and we can successfully describe the non-hydrogenic Rydberg series of low-dimensional systems......)electronics devices, e.g. light emitting diodes, solar cells, ultra-fast photodetectors, transistors etc., have been successfully fabricated. It is well established that for isolated 2D semiconductors and vdWHs the optical response is governed by excitonic effects. While it is understood that the reduced amount...... limitations of standard ab-initio methods. In this thesis first-principles models that overcome the limitations of standard ab-initio techniques are developed for the description of dielectric, electronic and excitonic properties in isolated 2D materials and vdWHs. The main contribution is a multi...

  17. Exciton absorption of entangled photons in semiconductor quantum wells

    Science.gov (United States)

    Rodriguez, Ferney; Guzman, David; Salazar, Luis; Quiroga, Luis; Condensed Matter Physics Group Team

    2013-03-01

    The dependence of the excitonic two-photon absorption on the quantum correlations (entanglement) of exciting biphotons by a semiconductor quantum well is studied. We show that entangled photon absorption can display very unusual features depending on space-time-polarization biphoton parameters and absorber density of states for both bound exciton states as well as for unbound electron-hole pairs. We report on the connection between biphoton entanglement, as quantified by the Schmidt number, and absorption by a semiconductor quantum well. Comparison between frequency-anti-correlated, unentangled and frequency-correlated biphoton absorption is addressed. We found that exciton oscillator strengths are highly increased when photons arrive almost simultaneously in an entangled state. Two-photon-absorption becomes a highly sensitive probe of photon quantum correlations when narrow semiconductor quantum wells are used as two-photon absorbers. Research funds from Facultad de Ciencias, Universidad de los Andes

  18. Calcite growth-rate inhibition by fulvic acid and magnesium ion—Possible influence on biogenic calcite formation

    Science.gov (United States)

    Reddy, Michael M.

    2012-01-01

    Increases in ocean surface water dissolved carbon dioxide (CO2) concentrations retard biocalcification by reducing calcite supersaturation (Ωc). Reduced calcification rates may influence growth-rate dependent magnesium ion (Mg) incorporation into biogenic calcite modifying the use of calcifying organisms as paleoclimate proxies. Fulvic acid (FA) at biocalcification sites may further reduce calcification rates. Calcite growth-rate inhibition by FA and Mg, two common constituents of seawater and soil water involved in the formation of biogenic calcite, was measured separately and in combination under identical, highly reproducible experimental conditions. Calcite growth rates (pH=8.5 and Ωc=4.5) are reduced by FA (0.5 mg/L) to 47% and by Mg (10−4 M) to 38%, compared to control experiments containing no added growth-rate inhibitor. Humic acid (HA) is twice as effective a calcite growth-rate inhibitor as FA. Calcite growth rate in the presence of both FA (0.5 mg/L) and Mg (10−4 M) is reduced to 5% of the control rate. Mg inhibits calcite growth rates by substitution for calcium ion at the growth site. In contrast, FA inhibits calcite growth rates by binding multiple carboxylate groups on the calcite surface. FA and Mg together have an increased affinity for the calcite growth sites reducing calcite growth rates.

  19. Red-shifted carrier multiplication energy threshold and exciton recycling mechanisms in strongly interacting silicon nanocrystals.

    Science.gov (United States)

    Marri, Ivan; Govoni, Marco; Ossicini, Stefano

    2014-09-24

    We present density functional theory calculations of carrier multiplication properties in a system of strongly coupled silicon nanocrystals. Our results suggest that nanocrystal-nanocrystal interaction can lead to a reduction of the carrier multiplication energy threshold without altering the carrier multiplication efficiency at high energies, in agreement with experiments. The time evolution of the number of electron-hole pairs generated in a system of strongly interacting nanocrystals upon absorption of high-energy photons is analyzed by solving a system of coupled rate equations, where exciton recycling mechanisms are implemented. We reconsider the role played by Auger recombination which is here accounted also as an active, nondetrimental process.

  20. INFLUENCE OF MORTGAGE RATES PRICE FORMATION ON THE PRIMARY HOUSING MARKET

    Directory of Open Access Journals (Sweden)

    Nikolay I. Kornilov

    2015-01-01

    Full Text Available The article considers relationship of pricesin the primary market, depending on theregional origin and type of home, with thevalue of mortgage rates. Assesses thestrength of such a relationship and thepossible effects of changes in such rates.

  1. Coherent dynamics of interwell excitons in GaAs/AlxGa1-xAs superlattices

    DEFF Research Database (Denmark)

    Mizeikis, V.; Birkedal, Dan; Langbein, Wolfgang Werner

    1997-01-01

    of them, the Is heavy-hole exciton, is almost identical to the same state in noninteracting quantum wells, while the other, the heavy-hole interwell exciton, is composed of an electron and a heavy hole in adjacent wells. The interwell exciton leads to a resonant enhancement in the four-wave mixing spectra...

  2. Role of Fe substitution and quenching rate on the formation of ...

    Indian Academy of Sciences (India)

    Unknown

    At higher quenching rates (wheel speed ~ 25 m/sec) all the alloys exhibit icosahedral phase. For. Al65Cu20Cr12Fe3 alloy, however, both the icosahedral and even the decagonal phases get formed at higher quenching rates. At higher quenching rate, alloy having Fe 3 at% exhibits two bcc phases, bccI (a = 8⋅9 Å) and.

  3. One-dimensional models of excitons in carbon nanotubes

    DEFF Research Database (Denmark)

    Cornean, Horia Decebal; Duclos, Pierre; Pedersen, Thomas Garm

    2004-01-01

    Excitons in carbon nanotubes may be modeled by two oppositely charged particles living on the surface of a cylinder. We derive three one-dimensional effective Hamiltonians which become exact as the radius of the cylinder vanishes. Two of them are solvable.......Excitons in carbon nanotubes may be modeled by two oppositely charged particles living on the surface of a cylinder. We derive three one-dimensional effective Hamiltonians which become exact as the radius of the cylinder vanishes. Two of them are solvable....

  4. Defect Structure of Localized Excitons in a WSe2 Monolayer

    KAUST Repository

    Zhang, Shuai

    2017-07-26

    The atomic and electronic structure of intrinsic defects in a WSe2 monolayer grown on graphite was revealed by low temperature scanning tunneling microscopy and spectroscopy. Instead of chalcogen vacancies that prevail in other transition metal dichalcogenide materials, intrinsic defects in WSe2 arise surprisingly from single tungsten vacancies, leading to the hole (p-type) doping. Furthermore, we found these defects to dominate the excitonic emission of the WSe2 monolayer at low temperature. Our work provided the first atomic-scale understanding of defect excitons and paved the way toward deciphering the defect structure of single quantum emitters previously discovered in the WSe2 monolayer.

  5. Realization of an all optical exciton-polariton router

    International Nuclear Information System (INIS)

    Marsault, Félix; Nguyen, Hai Son; Tanese, Dimitrii; Lemaître, Aristide; Galopin, Elisabeth; Sagnes, Isabelle; Amo, Alberto; Bloch, Jacqueline

    2015-01-01

    We report on the experimental realization of an all optical router for exciton-polaritons. This device is based on the design proposed by Flayac and Savenko [Appl. Phys. Lett. 103, 201105 (2013)], in which a zero-dimensional island is connected through tunnel barriers to two periodically modulated wires of different periods. Selective transmission of polaritons injected in the island, into either of the two wires, is achieved by tuning the energy of the island state across the band structure of the modulated wires. We demonstrate routing of ps polariton pulses using an optical control beam which controls the energy of the island quantum states, thanks to polariton-exciton interactions

  6. Exciton dynamics in solid-state green fluorescent protein

    Science.gov (United States)

    Dietrich, Christof P.; Siegert, Marie; Betzold, Simon; Ohmer, Jürgen; Fischer, Utz; Höfling, Sven

    2017-01-01

    We study the decay characteristics of Frenkel excitons in solid-state enhanced green fluorescent protein (eGFP) dried from solution. We further monitor the changes of the radiative exciton decay over time by crossing the phase transition from the solved to the solid state. Complex interactions between protonated and deprotonated states in solid-state eGFP can be identified from temperature-dependent and time-resolved fluorescence experiments that further allow the determination of activation energies for each identified process.

  7. Bimolecular Recombination Kinetics of an Exciton-Trion Gas

    Science.gov (United States)

    2015-07-01

    particles are created and annihilated in pairs so that there is no accumulation of charge. However, this approach is rigorously correct only for a...8 ~ ( )22 23.75 10 photons/ cm s× ⋅ . A quantum yield for electron-hole pair creation of 0.004 would create a generation flux G within the...hole pairs , magenta—excitons, and blue—trions. The final parameter of interest is Q, which controls the creation of excitons by electron–hole

  8. Incomplete Exciton Harvesting from Fullerenes in Bulk Heterojunction Solar Cells

    KAUST Repository

    Burkhard, George F.

    2009-12-09

    We investigate the internal quantum efficiencies (IQEs) of high efficiency poly-3-hexylthiophene:[6,6]-phenyl-C61-butyric acid methyl ester (P3HT:PCBM) solar cells and find them to be lower at wavelengths where the PCBM absorbs. Because the exciton diffusion length in PCBM is too small, excitons generated in PCBM decay before reaching the donor-acceptor interface. This result has implications for most state of the art organic solar cells, since all of the most efficient devices use fullerenes as electron acceptors. © 2009 American Chemical Society.

  9. Impacts of glycolate and formate radiolysis and thermolysis on hydrogen generation rate calculations for the Savannah River Site tank farm

    Energy Technology Data Exchange (ETDEWEB)

    Crawford, C. L. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); King, W. D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2017-08-14

    Savannah River Remediation (SRR) personnel requested that the Savannah River National Laboratory (SRNL) evaluate available data and determine its applicability to defining the impact of planned glycolate anion additions to Savannah River Site (SRS) High Level Waste (HLW) on Tank Farm flammability (primarily with regard to H2 production). Flammability evaluations of formate anion, which is already present in SRS waste, were also needed. This report describes the impacts of glycolate and formate radiolysis and thermolysis on Hydrogen Generation Rate (HGR) calculations for the SRS Tank Farm.

  10. Effects of Wavelength of Ultraviolet Ray on the Formation Rate of Pre-vitamin D_2 From Ergosterol

    OpenAIRE

    高村, 一知; 星野, 浩子; 豊増, 哲郎; 田中, 徳夫; 中沢, 武; タカムラ, カズノリ; ホシノ, ヒロコ; トヨマス, テツオ; タナカ, ノリオ; ナカザワ, タケシ; KAZUNORI, TAKAMURA; HIROKO, HOSHINO; TETSUO, TOYOMASU; NORIO, TANAKA; TAKESHI, NAKAZAWA

    1996-01-01

    In the ultraviolet (hereafter called UV) irradiation of ergosterol, the effects of wavelength (UV irradiation lamp 254nm and 310nm) were investigated on the formation of pre-vitamin D_2. The determination of pre-vitamin D_2 used high performance liquid chromatography. The results were as follows: (19 The precursor of vitamin D_2 is pre-vitamin D_2. It was formed when ergosterol (solution alcohol) was exposed to UV irradiation (254nm and 310nm). (2) The formation rate of pre-vitamin D_2 with t...

  11. Quantitative physiology and aroma formation of a dairy Lactococcus lactis at near-zero growth rates

    NARCIS (Netherlands)

    Mastrigt, van Oscar; Abee, Tjakko; Lillevang, Søren K.; Smid, Eddy J.

    2018-01-01

    During food fermentation processes like cheese ripening, lactic acid bacteria (LAB) encounter long periods of nutrient limitation leading to slow growth. Particular LAB survive these periods while still contributing to flavour formation in the fermented product. In this study the dairy Lactococcus

  12. Star-formation rates in the nuclei of violently interacting galaxies

    International Nuclear Information System (INIS)

    Bushouse, H.A.

    1986-01-01

    Spectrophotometry has been obtained of the nuclear regions of a large sample of violently interacting spiral galaxies. The sample galaxies were chosen to include only those systems having tails, plumes, or other morphological features consistent with strong tidal interactions involving disk galaxies. The interacting galaxies are found to exhibit a wide range of nuclear optical emission-line strengths, but show a significantly higher overall level in both Hα emission-line equivalent width and luminosity than samples of field spirals observed in a similar fashion. While galaxy-galaxy interactions can lead to large nuclear star-formation bursts, this is not a ubiquitous phenomenon. A large fraction (approx.30%) of the nuclei show only weak or no detectable optical emission lines and are characterized by stellar absorption spectra of old, elliptical galaxy-like stellar populations, thus indicating little recent or continuing star-formation activity. These circumstances can occur even in instances where the nucleus of the other component has a large population of young stars. While exhaustion of a galaxy's gas supply during the later phases of interaction can account for post-burst systems, it cannot explain systems that have experienced no significant star-formation activity throughout the entire interaction process. Seyfert and low-ionization nuclei also are rare in violently interacting systems which, coupled with the large number of nuclei found to have little star-formation activity, suggests either an initial lack of near-nuclear gas or that gas is present but in inappropriate forms to support star formation or fuel nuclear activity

  13. Role of Fe substitution and quenching rate on the formation of ...

    Indian Academy of Sciences (India)

    At higher quenching rates (wheel speed ∼ 25 m/sec) all the alloys exhibit icosahedral phase. For Al65Cu20Cr12Fe3 alloy, however, both the icosahedral and even the decagonal phases get formed at higher quenching rates. At higher quenching rate, alloy having Fe 3 at% exhibits two bcc phases, bccI ( = 8.9 Å) and bccII ...

  14. Temperature-dependent exciton recombination in asymmetrical ZnCdSe/ZnSe double quantum wells

    CERN Document Server

    Yu Guang You; Zhang, J Y; Zheng, Z H; Yang, B J; Zhao Xiao Wei; Shen De Zhen; Kong Xiang Gui

    1999-01-01

    Temperature-dependent exciton recombination in asymmetrical ZnCdSe/ZnSe double quantum wells is studied by recording photoluminescence spectra and photoluminescence decay spectra. The exciton tunnelling from the wide well to the narrow well and the thermal dissociation of excitons are two factors that influence the exciton recombination in this structure. In the narrow well, both of the two processes decrease the emission intensity, whereas, in the wide well, these two processes have contrary influences on the exciton density. The change of the emission intensity depends on which is the stronger one. (author)

  15. Decay of orientational grating of weakly confined excitons in GaAs thin films

    International Nuclear Information System (INIS)

    Kojima, O.; Isu, T.; Ishi-Hayase, J.; Kanno, A.; Katouf, R.; Sasaki, M.; Tsuchiya, M.

    2008-01-01

    We report the dynamical properties of the exciton orientation in GaAs thin films using the orientational grating (OG) technique. From the results of excitation-power dependence of OG signal, we confirmed that the OG signal comes from the optical nonlinearity of weakly confined excitons. In addition, the OG-decay time decreases with an increase of excitation power due to exciton-exciton interaction, and the shortest decay time is below 1 ps. Our results may imply the potential application of optical nonlinearity of weakly confined exciton to ultrafast switching devices operating at 1 Tbit/s

  16. Simple Screened Hydrogen Model of Excitons in Two-Dimensional Materials

    DEFF Research Database (Denmark)

    Olsen, Thomas; Latini, Simone; Rasmussen, Filip Anselm

    2016-01-01

    We present a generalized hydrogen model for the binding energies (EB) and radii of excitons in two-dimensional (2D) materials that sheds light on the fundamental differences between excitons in two and three dimensions. In contrast to the well-known hydrogen model of three-dimensional (3D) excitons......, the description of 2D excitons is complicated by the fact that the screening cannot be assumed to be local. We show that one can consistently define an effective 2D dielectric constant by averaging the screening over the extend of the exciton. For an ideal 2D semiconductor this leads to a simple expression for EB...

  17. Strongly Enhanced Free-Exciton Luminescence in Microcrystalline CsPbBr3 Films

    Science.gov (United States)

    Kondo, Shin-ichi; Kakuchi, Mitsugu; Masaki, Atsushi; Saito, Tadaaki

    2003-07-01

    The luminescence properties of CsPbBr3 films prepared via the amorphous phase by crystallization are dominated by free-exciton emission, and only a weak trace of emission due to trapped excitons was observed, in contrast to the case of bulk CsPbBr3 crystals. In particular, the films in the microcrystalline state show by more than an order of magnitude stronger free-exciton emission than in the polycrystalline state. The enhanced free-exciton emission is suggestive of excitonic superradiance.

  18. Marine snow derived from abandoned larvacean houses: Sinking rates, particle content and mechanisms of aggregate formation

    DEFF Research Database (Denmark)

    Hansen, J.L.S.; Kiørboe, Thomas; Alldredge, A.L.

    1996-01-01

    The dynamics and formation mechanisms of marine snow aggregates from abandoned larvacean houses were examined by laboratory experiments and field sampling during a spring diatom bloom in a shallow fjord on the west coast of the USA. Intact aggregates were sampled both from sediment traps and dire......The dynamics and formation mechanisms of marine snow aggregates from abandoned larvacean houses were examined by laboratory experiments and field sampling during a spring diatom bloom in a shallow fjord on the west coast of the USA. Intact aggregates were sampled both from sediment traps...... assemblages were observed in aggregates collected in the water column and in sediment traps. Most of the fecal pellets found in the houses were most Likely produced by the larvaceans themselves. Numbers of diatoms per house corresponded with the diatom concentrations in the ambient water and, on average, each...

  19. Prognostic value of heart rate variability indexes with regard to acute postinfarction aneurysm of left ventricle formation

    Directory of Open Access Journals (Sweden)

    S. M. Kyselov

    2017-12-01

    Full Text Available Prediction of Q-wave myocardial infarction complications in acute period is an actual problem of modern cardiology. Aim: to determine the prognostic value of heart rate variability indices with regard to acute left ventricular aneurysm development in patients with Q-wave myocardial infarction. Materials and мethods: time and spectral parameters of heart rate variability, number of arrhythmias and ischemia were investigated by daily monitoring of electrocardiogram in 238 patients with acute Q-wave myocardial infarction. ROC analysis with the characteristic curve construction was used to determine prognostically significant parameters. Predictive significance of indicators with regard to left ventricular aneurysms formation was assessed at a relative risk with a confidence interval of 95 %. Stepwise multivariate regression analysis of Cox proportional hazards to independent predictors of acute post-infarction left ventricular aneurysm formation determination was used. Results. In patients with Q-wave myocardial infarction and aneurysm of left ventricle it has been shown a reduction in time parameters of heart rate variability, the sympathetic-parasympathetic balance shift towards the sympathetic component activation and parasympathetic influence decreasing, increasing number of ventricular arrhythmias by means of life-threatening arrhythmias, and longer duration of corrected QT interval. The analysis of associations has made it possible to establish a close relationship between left ventricular aneurysm formation and parameters of electrocardiogram daily monitoring. With the help of ROC analysis we identified prognostically significant indicators of electrocardiogram daily monitoring with regard to acute postinfarction left ventricular aneurysm formation. Analysis of Cox proportional hazards has allowed the establishing of left ventricle aneurysm formation independent predictors. Conclusions. It has been revealed an increase in sympathetic

  20. Estimating the carbon sequestration capacity of shale formations using methane production rates.

    Science.gov (United States)

    Tao, Zhiyuan; Clarens, Andres

    2013-10-01

    Hydraulically fractured shale formations are being developed widely for oil and gas production. They could also represent an attractive repository for permanent geologic carbon sequestration. Shales have a low permeability, but they can adsorb an appreciable amount of CO2 on fracture surfaces. Here, a computational method is proposed for estimating the CO2 sequestration capacity of a fractured shale formation and it is applied to the Marcellus shale in the eastern United States. The model is based on historical and projected CH4 production along with published data and models for CH4/CO2 sorption equilibria and kinetics. The results suggest that the Marcellus shale alone could store between 10.4 and 18.4 Gt of CO2 between now and 2030, which represents more than 50% of total U.S. CO2 emissions from stationary sources over the same period. Other shale formations with comparable pressure-temperature conditions, such as Haynesville and Barnett, could provide significant additional storage capacity. The mass transfer kinetic results indicate that injection of CO2 would proceed several times faster than production of CH4. Additional considerations not included in this model could either reinforce (e.g., leveraging of existing extraction and monitoring infrastructure) or undermine (e.g., leakage or seismicity potential) this approach, but the sequestration capacity estimated here supports continued exploration into this pathway for producing carbon neutral energy.

  1. Chiral Modes at Exceptional Points in Exciton-Polariton Quantum Fluids.

    Science.gov (United States)

    Gao, T; Li, G; Estrecho, E; Liew, T C H; Comber-Todd, D; Nalitov, A; Steger, M; West, K; Pfeiffer, L; Snoke, D W; Kavokin, A V; Truscott, A G; Ostrovskaya, E A

    2018-02-09

    We demonstrate the generation of chiral modes-vortex flows with fixed handedness in exciton-polariton quantum fluids. The chiral modes arise in the vicinity of exceptional points (non-Hermitian spectral degeneracies) in an optically induced resonator for exciton polaritons. In particular, a vortex is generated by driving two dipole modes of the non-Hermitian ring resonator into degeneracy. Transition through the exceptional point in the space of the system's parameters is enabled by precise manipulation of real and imaginary parts of the closed-wall potential forming the resonator. As the system is driven to the vicinity of the exceptional point, we observe the formation of a vortex state with a fixed orbital angular momentum (topological charge). This method can be extended to generate higher-order orbital angular momentum states through coalescence of multiple non-Hermitian spectral degeneracies. Our Letter demonstrates the possibility of exploiting nontrivial and counterintuitive properties of waves near exceptional points in macroscopic quantum systems.

  2. Chiral Modes at Exceptional Points in Exciton-Polariton Quantum Fluids

    Science.gov (United States)

    Gao, T.; Li, G.; Estrecho, E.; Liew, T. C. H.; Comber-Todd, D.; Nalitov, A.; Steger, M.; West, K.; Pfeiffer, L.; Snoke, D. W.; Kavokin, A. V.; Truscott, A. G.; Ostrovskaya, E. A.

    2018-02-01

    We demonstrate the generation of chiral modes-vortex flows with fixed handedness in exciton-polariton quantum fluids. The chiral modes arise in the vicinity of exceptional points (non-Hermitian spectral degeneracies) in an optically induced resonator for exciton polaritons. In particular, a vortex is generated by driving two dipole modes of the non-Hermitian ring resonator into degeneracy. Transition through the exceptional point in the space of the system's parameters is enabled by precise manipulation of real and imaginary parts of the closed-wall potential forming the resonator. As the system is driven to the vicinity of the exceptional point, we observe the formation of a vortex state with a fixed orbital angular momentum (topological charge). This method can be extended to generate higher-order orbital angular momentum states through coalescence of multiple non-Hermitian spectral degeneracies. Our Letter demonstrates the possibility of exploiting nontrivial and counterintuitive properties of waves near exceptional points in macroscopic quantum systems.

  3. Rating

    OpenAIRE

    Karas, Vladimír

    2006-01-01

    Charakteristika ratingu. Dělení a druhy ratingu (rating emise × rating emitenta; dlouhodobý rating × krátkodobý rating; mezinárodní rating × lokální rating). Obecné požadavky kladené na rating. Proces tvorby ratingu. Vyžádaný rating. Nevyžádaný rating. Ratingový proces na bázi volně přístupných informací. Uplatňované ratingové systémy. Ratingová kriteria. Využití a interpretace ratingové známky. Funkce ratingu. Rating v souvislosti s BASEL II. Rating v souvislosti s hospodářskými krizemi....

  4. Determination of the stability constants of a number of metal fluoride complexes and their rates of formation

    International Nuclear Information System (INIS)

    Hammer, R.R.

    1979-08-01

    The stability constants of the fluoride complexes of Al +3 , H 3 BO 3 , Cr +3 , Cr +6 , Fe +3 , Gd +3 , Nb +5 , UO 2 +2 , and Zr +4 were determined in 0.96 and 2.88 M HNO 3 solutions in the temperature range 25 to 60 0 C with a fluoride specific ion electrode. These data can be used to calculate the concentration of chemical species in solution and will be used to correlate solution properties with solution composition. The solubilities of some fluoride precipitates were also measured in nitric acid solutions. The rates of formation of the fluoborates, aluminum fluoride, and zirconium fluoride complexes were measured with a fluoride specific ion electrode at 25, 35, and 45 0 C. The rates of formation of all complexes, except BF 4 - , AlF +2 , and a fluoride complex with aluminum containing more than three fluorides associated with it, were too fast to measure with the instrumentation used

  5. Nonmonotonic energy harvesting efficiency in biased exciton chains

    NARCIS (Netherlands)

    Vlaming, S.M.; Malyshev, V.A.; Knoester, J.

    2007-01-01

    We theoretically study the efficiency of energy harvesting in linear exciton chains with an energy bias, where the initial excitation is taking place at the high-energy end of the chain and the energy is harvested (trapped) at the other end. The efficiency is characterized by means of the average

  6. Luminescence and decay of excitons in lead tungstate crystals

    Czech Academy of Sciences Publication Activity Database

    Laguta, V. V.; Nikl, Martin; Zazubovich, S.

    2007-01-01

    Roč. 42, - (2007), s. 515-520 ISSN 1350-4487 Grant - others:Estonian Science Foundation(EE) 6548 Institutional research plan: CEZ:AV0Z10100521 Keywords : luminescence * excitons defects, * lead tungstate Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.054, year: 2007

  7. Excitonic magnetism in d.sup.6./sup. perovskites

    Czech Academy of Sciences Publication Activity Database

    Afonso, J.F.; Kuneš, Jan

    2017-01-01

    Roč. 95, č. 11 (2017), s. 1-8, č. článku 115131. ISSN 2469-9950 EU Projects: European Commission(XE) 646807 - EXMAG Institutional support: RVO:68378271 Keywords : excitonic magnetism * cobaltites Subject RIV: BM - Solid Matter Physics ; Magnetism OBOR OECD: Condensed matter physics (including formerly solid state physics, supercond.) Impact factor: 3.836, year: 2016

  8. The Aharonov-Bohm effect for an exciton

    Science.gov (United States)

    Römer, R. A.; Raikh, M. E.

    2000-03-01

    We study theoretically the exciton absorption (luminescence) of a ring-like quantum dot shreded by a magnetic flux. We consider the limit when the width of the ring is smaller than the excitonic Bohr radius a_B. We demonstrate that, despite the electrical neutrality of the exciton, both the spectral position of the exciton peak in the absorption (luminescence), and the corresponding oscillator strength oscillate with magnetic flux with a period Φ0 --- the universal flux quantum. Assuming that the attraction between electron and hole is short-ranged we find analytically the functional form of these oscillations for both quantities.^1 This enables us to trace the magnitude of the effect with changing the ratio 2 π R/aB where R is the radius of the ring. Physically, the origin of the oscillations is the finite probability for electron and hole, created by a photon at the same point, to tunnel in the opposite directions and meet each other on the opposite side of the ring. Possible candidates for the experimental observation of the effect are recently discovered self-assembled quantum ring-like structures of InAs embedded in GaAs.^2,3 ^1R.A. Römer and M.E. Raikh, preprint cond-mat/9906314. ^2A. Lorke et al., Microelectronic Engeneering 47, 95 (1999). ^3H. Petterson et al., Proceedings of EP2DS-13, to be published in Physica E, (1999).

  9. Exciton-polariton condensation in transition metal dichalcogenide bilayer heterostructure

    Science.gov (United States)

    Lee, Ki Hoon; Jeong, Jae-Seung; Min, Hongki; Chung, Suk Bum

    For the bilayer heterostructure system in an optical microcavity, the interplay of the Coulomb interaction and the electron-photon coupling can lead to the emergence of quasiparticles consisting of the spatially indirect exciton and cavity photons known as dipolariton, which can form the Bose-Einstein condensate above a threshold density. Additional physics comes into play when each layer of the bilayer system consists of the transition metal dichalcogenide (TMD) monolayer. The TMD monolayer band structure in the low energy spectrum has two valley components with nontrivial Berry phase, which gives rise to a selection rule in the exciton-polariton coupling, e.g. the exciton from one (the other) valley can couple only to the clockwise (counter-clockwise) polarized photon. We investigate possible condensate phases of exciton-polariton in the bilayer TMD microcavity changing relevant parameters such as detuning, excitation density and interlayer distance. This work was supported in part by the Institute for Basic Science of Korea (IBS) under Grant IBS-R009-Y1 and by the National Research Foundation of Korea (NRF) under the Basic Science Research Program Grant No. 2015R1D1A1A01058071.

  10. Direct measurement of exciton dissociation energy in polymers

    Czech Academy of Sciences Publication Activity Database

    Toušek, J.; Toušková, J.; Chomutová, R.; Paruzel, Bartosz; Pfleger, Jiří

    2017-01-01

    Roč. 7, č. 1 (2017), s. 1-6, č. článku 015113. ISSN 2158-3226 Institutional support: RVO:61389013 Keywords : exciton dissociation energy * polymers * SCR Subject RIV: CD - Macromolecular Chemistry OBOR OECD: Polymer science Impact factor: 1.568, year: 2016

  11. On the possibility of excitonic magnetism in Ir double perovskites

    Czech Academy of Sciences Publication Activity Database

    Pajskr, K.; Novák, Pavel; Pokorný, Vladislav; Kolorenč, Jindřich; Arita, R.; Kuneš, Jan

    2016-01-01

    Roč. 93, č. 3 (2016), 1-6, č. článku 035129. ISSN 1098-0121 R&D Projects: GA ČR GA13-25251S Institutional support: RVO:68378271 Keywords : spin-orbit coupling * double perovskite * excitonic magnetism Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.736, year: 2014

  12. Exciton Recombination in Formamidinium Lead Triiodide : Nanocrystals versus Thin Films

    NARCIS (Netherlands)

    Fang, Hong-Hua; Protesescu, Loredana; Balazs, Daniel M.; Adjokatse, Sampson; Kovalenko, Maksym V.; Loi, Maria Antonietta

    2017-01-01

    The optical properties of the newly developed near-infrared emitting formamidinium lead triiodide (FAPbI(3)) nanocrystals (NCs) and their polycrystalline thin film counterpart are comparatively investigated by means of steady-state and time-resolved photoluminescence. The excitonic emission is

  13. Optical absorption of charged excitons in semiconducting carbon nanotubes

    DEFF Research Database (Denmark)

    Rønnow, Troels Frimodt; Pedersen, Thomas Garm; Cornean, Horia

    2012-01-01

    In this article we examine the absorption coefficient of charged excitons in carbon nanotubes. We investigate the temperature and damping dependence of the absorption spectra. We show that the trion peak in the spectrum is asymmetric for temperatures greater than approximately 1 K whereas...

  14. Cascaded exciton energy transfer in a monolayer semiconductor lateral heterostructure assisted by surface plasmon polariton.

    Science.gov (United States)

    Shi, Jinwei; Lin, Meng-Hsien; Chen, I-Tung; Mohammadi Estakhri, Nasim; Zhang, Xin-Quan; Wang, Yanrong; Chen, Hung-Ying; Chen, Chun-An; Shih, Chih-Kang; Alù, Andrea; Li, Xiaoqin; Lee, Yi-Hsien; Gwo, Shangjr

    2017-06-26

    Atomically thin lateral heterostructures based on transition metal dichalcogenides have recently been demonstrated. In monolayer transition metal dichalcogenides, exciton energy transfer is typically limited to a short range (~1 μm), and additional losses may be incurred at the interfacial regions of a lateral heterostructure. To overcome these challenges, here we experimentally implement a planar metal-oxide-semiconductor structure by placing a WS 2 /MoS 2 monolayer heterostructure on top of an Al 2 O 3 -capped Ag single-crystalline plate. We find that the exciton energy transfer range can be extended to tens of microns in the hybrid structure mediated by an exciton-surface plasmon polariton-exciton conversion mechanism, allowing cascaded exciton energy transfer from one transition metal dichalcogenides region supporting high-energy exciton resonance to a different transition metal dichalcogenides region in the lateral heterostructure with low-energy exciton resonance. The realized planar hybrid structure combines two-dimensional light-emitting materials with planar plasmonic waveguides and offers great potential for developing integrated photonic and plasmonic devices.Exciton energy transfer in monolayer transition metal dichalcogenides is limited to short distances. Here, Shi et al. fabricate a planar metal-oxide-semiconductor structure and show that exciton energy transfer can be extended to tens of microns, mediated by an exciton-surface-plasmon-polariton-exciton conversion mechanism.

  15. Numerical Modeling of Variable Fluid Injection-Rate Modes on Fracturing Network Evolution in Naturally Fractured Formations

    Directory of Open Access Journals (Sweden)

    Yu Wang

    2016-05-01

    Full Text Available In this study, variable injection-rate technology was numerically investigated in a pre-existing discrete fracture network (DFN formation, the Tarim Basin in China. A flow-stress-damage (FSD coupling model has been used in an initial attempt towards how reservoir response to variable injection-rates at different hydraulic fracturing stages. The established numerical model simultaneously considered the macroscopic and microscopic heterogeneity characteristics. Eight numerical cases were studied. Four cases were used to study the variable injection-rate technology, and the other four cases were applied for a constant injection-rate in order to compare with the variable injection-rate technology. The simulation results show that the variable injection-rate technology is a potentially good method to a form complex fracturing networks. The hydraulic fracturing effectiveness when increasing the injection-rate at each stage is the best, also, the total injected fluid is at a minimum. At the initial stage, many under-fracturing points appear around the wellbore with a relatively low injection-rate; the sudden increase of injection rate drives the dynamic propagation of hydraulic fractures along many branching fracturing points. However, the case with decreasing injection rate is the worst. By comparing with constant injection-rate cases, the hydraulic fracturing effectiveness with variable flow rate technology is generally better than those with constant injection-rate technology. This work strongly links the production technology and hydraulic fracturing effectiveness evaluation and aids in the understanding and optimization of hydraulic fracturing simulations in naturally fractured reservoirs.

  16. Stark shift and electric-field-induced dissociation of excitons in monolayer MoS2 and hBN/MoS2 heterostructures

    DEFF Research Database (Denmark)

    Haastrup, Sten; Latini, Simone; Bolotin, Kirill

    2016-01-01

    of an applied in-plane electric field. The dissociation rates are obtained as the inverse lifetime of the resonant states of a two-dimensional hydrogenic Hamiltonian which describes the exciton within the Mott-Wannier model. The resonances are computed using complex scaling, and the effective masses...

  17. Permanent Rabi oscillations in coupled exciton-photon systems with PT-symmetry.

    Science.gov (United States)

    Chestnov, Igor Yu; Demirchyan, Sevak S; Alodjants, Alexander P; Rubo, Yuri G; Kavokin, Alexey V

    2016-01-21

    We propose a physical mechanism which enables permanent Rabi oscillations in driven-dissipative condensates of exciton-polaritons in semiconductor microcavities subjected to external magnetic fields. The method is based on stimulated scattering of excitons from the incoherent reservoir. We demonstrate that permanent non-decaying oscillations may appear due to the parity-time symmetry of the coupled exciton-photon system realized in a specific regime of pumping to the exciton state and depletion of the reservoir. At non-zero exciton-photon detuning, robust permanent Rabi oscillations occur with unequal amplitudes of exciton and photon components. Our predictions pave way to realization of integrated circuits based on exciton-polariton Rabi oscillators.

  18. Multi-exciton emission from solitary dopant states of carbon nanotubes.

    Science.gov (United States)

    Ma, Xuedan; Hartmann, Nicolai F; Velizhanin, Kirill A; Baldwin, Jon K S; Adamska, Lyudmyla; Tretiak, Sergei; Doorn, Stephen K; Htoon, Han

    2017-11-02

    By separating the photons from slow and fast decays of single and multi-exciton states in a time gated 2 nd order photon correlation experiment, we show that solitary oxygen dopant states of single-walled carbon nanotubes (SWCNTs) allow emission of photon pairs with efficiencies as high as 44% of single exciton emission. Our pump dependent time resolved photoluminescence (PL) studies further reveal diffusion-limited exciton-exciton annihilation as the key process that limits the emission of multi-excitons at high pump fluences. We further postulate that creation of additional permanent exciton quenching sites occurring under intense laser irradiation leads to permanent PL quenching. With this work, we bring out multi-excitonic processes of solitary dopant states as a new area to be explored for potential applications in lasing and entangled photon generation.

  19. A Review of the Application of Rate Theory to Simulate Vacancy Cluster Formation and Interstitial Defect Formation in Reactor Pressure Vessel Steel

    Directory of Open Access Journals (Sweden)

    Fallon Laliberte

    2015-10-01

    Full Text Available The beltline region of the reactor pressure vessel (RPV is subject to an extreme radiation, temperature, and pressure environment over several decades of operation; therefore it is necessary to understand the mechanisms through which radiation damage occurs and how it affects the mechanical and chemical properties of the RPV steel. Chemical rate theory is a mean field rate theory simulation model which applies chemistry to the evaluation of irradiation-induced embrittlement. It presents one method of analysis that may be coupled to other distinct methods, in order to analyze defect formation, ultimately providing useful information on strength, ductility, toughness and dimensional stability changes for effects such as embrittlement, reduction in ductility and toughness, void swelling, hardening, irradiation creep, stress corrosion cracking, etc. over time as materials are subjected to reactor operational irradiation. This paper serves as a brief review of rate theory fundamentals and presents several examples of research that exemplify the application and importance of rate theory in examining the effects of radiation damage on RPV steel.

  20. Estimation of the Star Formation Rate (sfr) Through Data Analysis of Swift's - GRBs from 2008 TO 2017

    Science.gov (United States)

    Elías Chavez, M.; Martínez Bravo, O.

    2017-10-01

    This work presents a research about the Star Formation Rate (SFR), using data analyzing of a sample from 2008 to 2017 of Gamma Ray Bursts (GRBs) submitted by Swift Gamma-Ray Burst Mission, This work is based on the empirical model proposed by Yuksel, Kistler & Beacom. (2008), basically the SFR is measured using long-GRBs considering a core-collapsed model of high rotating massive stars with low metallicity. Studying ɛ(z) which accounts the production rate of long-GRBs with additional evolutive effects, parameterizing of the form ɛ(z)=ɛ_{ 0 }(1+z)^{δ}, where ɛ_{0} is a unknown constant which include the total conversion of the SFR rate to GRB rate in a luminosity range given, finally we discuss the possible effect in the chemical evolution of galaxies at high redshift.

  1. Age- and gender-specific estimates of partnership formation and dissolution rates in the Seattle sex survey.

    Science.gov (United States)

    Nelson, Sara J; Hughes, James P; Foxman, Betsy; Aral, Sevgi O; Holmes, King K; White, Peter J; Golden, Matthew R

    2010-04-01

    Partnership formation and dissolution rates are primary determinants of sexually transmitted infection (STI) transmission dynamics. The authors used data on persons' lifetime sexual experiences from a 2003-2004 random digit dialing survey of Seattle residents aged 18-39 years (N=1,194) to estimate age- and gender-specific partnership formation and dissolution rates. Partnership start and end dates were used to estimate participants' ages at the start of each partnership and partnership durations, and partnerships not enumerated in the survey were imputed. Partnership formation peaked at age 19 at 0.9 (95% confidence interval [CI]: 0.76-1.04) partnerships per year and decreased to 0.1 to 0.2 after age 30 for women and peaked at age 20 at 1.4 (95% CI: 1.08-1.64) and declined to 0.5 after age 30 for men. Nearly one fourth (23.7%) of partnerships ended within 1 week and more than one half (51.2%) ended within 12 weeks. Most (63.5%) individuals 30 to 39 years of age had not formed a new sexual partnership in the past 3 years. A large proportion of the heterosexual population is no longer at substantial STI risk by their early 30s, but similar analyses among high-risk populations may give insight into reasons for the profound disparities in STI rates across populations. Copyright (c) 2010 Elsevier Inc. All rights reserved.

  2. A comprehensive mathematical model for estimating oil drainage rate in SAGD process considering wellbore/formation coupling effect

    Science.gov (United States)

    Cheng, Linsong; Gu, Hao; Huang, Shijun

    2017-05-01

    The aim of this work is to present a comprehensive mathematical model for estimating oil drainage rate in Steam-assisted gravity drainage (SAGD) process, more importantly, wellbore/formation coupling effect is considered. Firstly, mass and heat transfer in vertical and horizontal wellbores are described briefly. Then, a function of steam chamber height is introduced and the expressions for oil drainage rate in rising and expanding steam chamber stages are derived in detail. Next, a calculation flowchart is provided and an example is given to introduce how to use the proposed method. Finally, after the mathematical model is validated, the effects of wellhead steam injection rate on simulated results are further analyzed. The results indicate that heat injection power per meter reduces gradually along the horizontal wellbore, which affects both steam chamber height and oil drainage rate in the SAGD process. In addition, when production time is the same, the calculated oil drainage rate from the new method is lower than that from Butler's method. Moreover, the paper shows that when wellhead steam injection rate is low enough, the steam chamber is not formed at the horizontal well's toe position and enhancing the wellhead steam injection rate can increase the oil drainage rate.

  3. Frequency non-degenerate sequential excitation of the impurity trapped exciton in strontium fluoride crystals doped with ytterbium

    Energy Technology Data Exchange (ETDEWEB)

    Senanayake, Pubudu S.; Hughes-Currie, Rosa B. [Department of Physics and Astronomy, University of Canterbury, PB 4800, Christchurch 8410 (New Zealand); Wells, Jon-Paul R., E-mail: jon-paul.wells@canterbury.ac.nz [The Dodd-Walls Centre for Photonic and Quantum Technologies and Department of Physics and Astronomy, University of Canterbury, PB 4800, Christchurch 8140 (New Zealand); Reid, Michael F. [MacDiarmid Institute for Advanced Materials and Nanotechnology and Department of Physics and Astronomy, University of Canterbury, PB 4800, Christchurch 8140 (New Zealand); Berden, Giel [Radboud University Nijmegen, Institute for Molecules and Materials, FELIX Facility, Toernooiveld 7, 6525 ED Nijmegen (Netherlands); Reeves, Roger J. [Department of Physics and Astronomy, University of Canterbury, PB 4800, Christchurch 8410 (New Zealand); MacDiarmid Institute for Advanced Materials and Nanotechnology and Department of Physics and Astronomy, University of Canterbury, PB 4800, Christchurch 8140 (New Zealand); Meijerink, Andries [Debye Institute for NanoMaterials Science, University of Utrecht, P.O. Box 80000, TA 3508 Utrecht (Netherlands)

    2015-04-07

    We model the dynamic behaviour observed for impurity-trapped excitons in SrF{sub 2}:Yb{sup 2+} using transient photoluminescence enhancement induced via a two-frequency, sequential excitation process employing an UV optical parametric amplifier synchronized to an IR free electron laser (FEL). We observe sharp transitions interpreted as a change of state of the localized hole and broad bands interpreted as a change of state of the delocalized electron. Our modeling indicates that the 4f crystal-field interaction is 25% smaller than in CaF{sub 2}. The photoluminescence enhancement transients are analyzed across a range of excitation frequencies using a system of rate equations. The temporal behavior is explained in terms of intra-excitonic relaxation, local lattice heating by the FEL, and liberation of electrons from trap states.

  4. Strange Quark Stars in Binaries: Formation Rates, Mergers, and Explosive Phenomena

    Science.gov (United States)

    Wiktorowicz, G.; Drago, A.; Pagliara, G.; Popov, S. B.

    2017-09-01

    Recently, the possible coexistence of a first family composed of “normal” neutron stars (NSs) with a second family of strange quark stars (QSs) has been proposed as a solution of problems related to the maximum mass and to the minimal radius of these compact stellar objects. In this paper, we study the mass distribution of compact objects formed in binary systems and the relative fractions of quark and NSs in different subpopulations. We incorporate the strange QS formation model provided by the two-families scenario, and we perform a large-scale population synthesis study in order to obtain the population characteristics. According to our results, the main channel for strange QS formation in binary systems is accretion from a secondary companion on an NS. Therefore, a rather large number of strange QSs form by accretion in low-mass X-ray binaries and this opens the possibility of having explosive GRB-like phenomena not related to supernovae and not due to the merger of two NSs. The number of double strange QS systems is rather small, with only a tiny fraction that merge within a Hubble time. This drastically limits the flux of strangelets produced by the merger, which turns out to be compatible with all limits stemming from Earth and lunar experiments. Moreover, this value of the flux rules out at least one relevant channel for the transformation of all NSs into strange QSs by strangelets’ absorption.

  5. Accelerating FRET between Near-Infrared Emitting Quantum Dots Using a Molecular J-Aggregate as an Exciton Bridge.

    Science.gov (United States)

    Wang, Chen; Weiss, Emily A

    2017-09-13

    Fast energy transfer (EnT) among quantum dots (QDs) with near-infrared (NIR) emission is essential for fully exploiting their light harvesting and photon downconversion (multiexciton generation) abilities. This paper demonstrates a relayed EnT mechanism that accelerates the migration of NIR excitons between PbS QDs by a factor of 20 from that of one-step EnT through a polyelectrolyte and even a factor of ∼2 from that of one-step EnT between QDs in direct contact, by employing a J-aggregate (J-agg) of a cyanine dye as an exciton bridge. The donor QDs, acceptor QDs, and J-agg are electrostatically assembled into a sandwich structure with layer-by-layer deposition. Estimates of EnT rate and yield from transient and steady-state absorption and photoluminescence spectroscopies show that the rate-limiting step in the relay is EnT from the donor QD to the J-agg, while EnT from the J-agg to the acceptor QD occurs in J-agg with more intermolecular order. This work demonstrates the viability of relayed EnT through a molecular bridge as a strategy for accelerating long-distance exciton migration in assemblies of QDs, in particular in the near-infrared.

  6. Efficient quantum-classical method for computing thermal rate constant of recombination: application to ozone formation.

    Science.gov (United States)

    Ivanov, Mikhail V; Babikov, Dmitri

    2012-05-14

    Efficient method is proposed for computing thermal rate constant of recombination reaction that proceeds according to the energy transfer mechanism, when an energized molecule is formed from reactants first, and is stabilized later by collision with quencher. The mixed quantum-classical theory for the collisional energy transfer and the ro-vibrational energy flow [M. Ivanov and D. Babikov, J. Chem. Phys. 134, 144107 (2011)] is employed to treat the dynamics of molecule + quencher collision. Efficiency is achieved by sampling simultaneously (i) the thermal collision energy, (ii) the impact parameter, and (iii) the incident direction of quencher, as well as (iv) the rotational state of energized molecule. This approach is applied to calculate third-order rate constant of the recombination reaction that forms the (16)O(18)O(16)O isotopomer of ozone. Comparison of the predicted rate vs. experimental result is presented.

  7. CONNECTING THE GAMMA RAY BURST RATE AND THE COSMIC STAR FORMATION HISTORY: IMPLICATIONS FOR REIONIZATION AND GALAXY EVOLUTION

    Energy Technology Data Exchange (ETDEWEB)

    Robertson, Brant E.; Ellis, Richard S., E-mail: brant@astro.caltech.edu [Astronomy Department, California Institute of Technology, MC 249-17, 1200 East California Boulevard, Pasadena, CA 91125 (United States)

    2012-01-10

    The contemporary discoveries of galaxies and gamma ray bursts (GRBs) at high redshift have supplied the first direct information on star formation when the universe was only a few hundred million years old. The probable origin of long duration GRBs in the deaths of massive stars would link the universal GRB rate to the redshift-dependent star formation rate (SFR) density, although exactly how is currently unknown. As the most distant GRBs and star-forming galaxies probe the reionization epoch, the potential reward of understanding the redshift-dependent ratio {Psi}(z) of the GRB rate to SFR is significant and includes addressing fundamental questions such as incompleteness in rest-frame UV surveys for determining the SFR at high redshift and time variations in the stellar initial mass function. Using an extensive sample of 112 GRBs above a fixed luminosity limit drawn from the Second Swift Burst Alert Telescope catalog and accounting for uncertainty in their redshift distribution by considering the contribution of 'dark' GRBs, we compare the cumulative redshift distribution N(< z) of GRBs with the star formation density {rho}-dot{sub *}(z) measured from UV-selected galaxies over 0 < z <4. Strong evolution (e.g., {Psi}(z){proportional_to}(1 + z){sup 1.5}) is disfavored (Kolmogorov-Smirnov test P < 0.07). We show that more modest evolution (e.g., {Psi}(z){proportional_to}(1 + z){sup 0.5}) is consistent with the data (P Almost-Equal-To 0.9) and can be readily explained if GRBs occur primarily in low-metallicity galaxies which are proportionally more numerous at earlier times. If such trends continue beyond z {approx_equal} 4, we find that the discovery rate of distant GRBs implies an SFR density much higher than that inferred from UV-selected galaxies. While some previous studies of the GRB-SFR connection have concluded that GRB-inferred star formation at high redshift would be sufficient to maintain cosmic reionization over 6

  8. Microaneurysm formation rate as a predictive marker for progression to clinically significant macular edema in nonproliferative diabetic retinopathy.

    Science.gov (United States)

    Haritoglou, Christos; Kernt, Marcus; Neubauer, Aljoscha; Gerss, Joachim; Oliveira, Carlos Manta; Kampik, Anselm; Ulbig, Michael

    2014-01-01

    To evaluate the predictive value of microaneurysm (MA) formation rate concerning the development of clinically significant macular edema (CSME) in patients with mild-to-moderate nonproliferative diabetic retinopathy as evaluated by an automated analysis of central field fundus 30° photographs. Two hundred and eighty-seven eyes were included in the study. Photographs obtained at Day 0, at 6, and 12 months were analyzed using the RetmarkerDR software (Critical Health SA) in a masked manner, and the MA formation rate was documented. A threshold of a calculated MA formation rate of 2 or more was chosen to consider a patient "positive." The ability to predict CSME development was then calculated for a period of up to 5 years. HbA1c values, blood pressure, or duration of diabetes were also evaluated. The study population consisted of 89 male and 59 female patients with a mean age of 57.6 years, a mean HbA1c of 7.8, and a mean duration of diabetes of 12.3 years. Forty-seven of 287 eyes (16.4%) developed CSME during follow-up. An increased MA formation rate of >2 MA was clearly associated with development of CSME. Using the automated analysis and a threshold of 2 or more new MA, the authors were able to identify 70.2% of the eyes that developed CSME during follow-up ("true positive") and using a threshold of up to 2 new MA, 71.7% of the patients that did not develop CSME ("true negative"). No significant differences concerning baseline and 1-year HbA1c levels within patient eyes that developed CSME compared with patient eyes below or over the calculated threshold of 2 MA (P = 0.554 and P = 0.890, respectively) were seen. The positive and negative predictive value was calculated to be 33% versus 92.5%, sensitivity was 70%, and specificity was 72%. Using the RetmarkerDR software, the authors were able to identify patients with higher risk to develop CSME during follow-up using a threshold of 2 or more MA formation rate. Together with the high negative predictive value, the

  9. Length-scale and strain rate-dependent mechanism of defect formation and fracture in carbon nanotubes under tensile loading

    Science.gov (United States)

    Javvaji, Brahmanandam; Raha, S.; Mahapatra, D. Roy

    2017-02-01

    Electromagnetic and thermo-mechanical forces play a major role in nanotube-based materials and devices. Under high-energy electron transport or high current densities, carbon nanotubes fail via sequential fracture. The failure sequence is governed by certain length scale and flow of current. We report a unified phenomenological model derived from molecular dynamic simulation data, which successfully captures the important physics of the complex failure process. Length-scale and strain rate-dependent defect nucleation, growth, and fracture in single-walled carbon nanotubes with diameters in the range of 0.47 to 2.03 nm and length which is about 6.17 to 26.45 nm are simulated. Nanotubes with long length and small diameter show brittle fracture, while those with short length and large diameter show transition from ductile to brittle fracture. In short nanotubes with small diameters, we observe several structural transitions like Stone-Wales defect initiation, its propagation to larger void nucleation, formation of multiple chains of atoms, conversion to monatomic chain of atoms, and finally complete fracture of the carbon nanotube. Hybridization state of carbon-carbon bonds near the end cap evolves, leading to the formation of monatomic chain in short nanotubes with small diameter. Transition from ductile to brittle fracture is also observed when strain rate exceeds a critical value. A generalized analytical model of failure is established, which correlates the defect energy during the formation of atomic chain with aspect ratio of the nanotube and strain rate. Variation in the mechanical properties such as elastic modulus, tensile strength, and fracture strain with the size and strain rate shows important implications in mitigating force fields and ways to enhance the life of electronic devices and nanomaterial conversion via fracture in manufacturing.

  10. The impact of star formation and gamma-ray burst rates at high redshift on cosmic chemical evolution and reionization

    Science.gov (United States)

    Vangioni, Elisabeth; Olive, Keith A.; Prestegard, Tanner; Silk, Joseph; Petitjean, Patrick; Mandic, Vuk

    2015-03-01

    Recent observations in the total luminosity density have led to significant progress in establishing the star formation rate (SFR) at high redshift. Concurrently observed gamma-ray burst rates have also been used to extract the SFR at high redshift. The SFR in turn can be used to make a host of predictions concerning the ionization history of the Universe, the chemical abundances, and supernova rates. We compare the predictions made using a hierarchical model of cosmic chemical evolution based on three recently proposed SFRs: two based on extracting the SFR from the observed gamma-ray burst rate at high redshift, and one based on the observed galaxy luminosity function at high redshift. Using the WMAP/Planck data on the optical depth and epoch of reionization, we find that only the SFR inferred from gamma-ray burst data at high redshift suffices to allow a single mode (in the initial mass function - IMF) of star formation which extends from z = 0 to redshifts >10. For the case of the SFR based on the observed galaxy luminosity function, the reionization history of the Universe requires a bimodal IMF which includes at least a coeval high- (or intermediate-) mass mode of star formation at high redshift (z > 10). Therefore, we also consider here a more general bimodal case which includes an early-forming high-mass mode as a fourth model to test the chemical history of the Universe. We conclude that observational constraints on the global metallicity and optical depth at high redshift favour unseen faint but active star-forming galaxies as pointed out in many recent studies.

  11. Length-scale and strain rate-dependent mechanism of defect formation and fracture in carbon nanotubes under tensile loading

    Energy Technology Data Exchange (ETDEWEB)

    Javvaji, Brahmanandam [Indian Institute of Science, Department of Aerospace Engineering (India); Raha, S. [Indian Institute of Science, Department of Computational and Data Sciences (India); Mahapatra, D. Roy, E-mail: droymahapatra@aero.iisc.ernet.in [Indian Institute of Science, Department of Aerospace Engineering (India)

    2017-02-15

    Electromagnetic and thermo-mechanical forces play a major role in nanotube-based materials and devices. Under high-energy electron transport or high current densities, carbon nanotubes fail via sequential fracture. The failure sequence is governed by certain length scale and flow of current. We report a unified phenomenological model derived from molecular dynamic simulation data, which successfully captures the important physics of the complex failure process. Length-scale and strain rate-dependent defect nucleation, growth, and fracture in single-walled carbon nanotubes with diameters in the range of 0.47 to 2.03 nm and length which is about 6.17 to 26.45 nm are simulated. Nanotubes with long length and small diameter show brittle fracture, while those with short length and large diameter show transition from ductile to brittle fracture. In short nanotubes with small diameters, we observe several structural transitions like Stone-Wales defect initiation, its propagation to larger void nucleation, formation of multiple chains of atoms, conversion to monatomic chain of atoms, and finally complete fracture of the carbon nanotube. Hybridization state of carbon-carbon bonds near the end cap evolves, leading to the formation of monatomic chain in short nanotubes with small diameter. Transition from ductile to brittle fracture is also observed when strain rate exceeds a critical value. A generalized analytical model of failure is established, which correlates the defect energy during the formation of atomic chain with aspect ratio of the nanotube and strain rate. Variation in the mechanical properties such as elastic modulus, tensile strength, and fracture strain with the size and strain rate shows important implications in mitigating force fields and ways to enhance the life of electronic devices and nanomaterial conversion via fracture in manufacturing.

  12. Influence of composition and rate heating on formation of black core in bodies obtained with red ceramic

    International Nuclear Information System (INIS)

    Santana, L.N.L.; Goncalves, W.P.; Silva, B.J. da; Macedo, R.S.; Santos, R.C.; Lisboa, D.

    2011-01-01

    In the heating of pieces of red pottery can the defect known as black core, this may deteriorate the technical and aesthetic characteristics of the final product. This study evaluated the influence of chemical composition and heating rate on the formation of black core in bodies red ceramic. The masses were treated and samples were extruded, dried, sintered at 900 °C, with heating rates of 5, 10, 15, 20 and 30 °C / min. and determined the following properties: water absorption, linear shrinkage and flexural strength. The pieces made with the mass containing lower content of iron oxide showed better resistance to bending when subjected to rapid heating. The presence of the black core was identified through visual analysis of the pieces after the break, being more apparent in parts subject to rates above 5 °C / min. (author)

  13. Exciton-Induced Degradation of Carbazole-Based Host Materials and Its Role in the Electroluminescence Spectral Changes in Phosphorescent Organic Light Emitting Devices with Electrical Aging.

    Science.gov (United States)

    Yu, Hyeonghwa; Zhang, Yingjie; Cho, Yong Joo; Aziz, Hany

    2017-04-26

    We investigate the origins of the long-wavelength bands that appear in the emission spectra of carbazole-based host materials and play a role in the electroluminescence (EL) spectral changes of phosphorescent organic light emitting devices (PhOLEDs) with electrical aging. 4,4'-Bis(carbazol-9-yl)biphenyl (CBP) is used as a model carbazole host material and is studied using photoluminescence, EL, and atomic force microscopy measurements under various stress scenarios in both single and bilayer devices and in combination with various electron transport layer (ETL) materials. Results show that exciton-induced morphological aggregation of CBP is behind the appearance of those long-wavelength bands and that complexation between the aggregated CBP molecules and ETL molecules plays a role in this phenomenon. Comparisons between the effects of exciton and thermal stress suggest that exciton-induced aggregation may be limited to short-range molecular ordering or pairing (e.g., dimer or trimer species formation) versus longer-range ordering (crystallization) in the case of thermal stress. The findings provide new insights into exciton-induced degradation in wide band gap host materials and its role in limiting the stability of PhOLEDs.

  14. Excitonic complexes in GaN/(Al,Ga)N quantum dots

    International Nuclear Information System (INIS)

    Elmaghraoui, D; Triki, M; Jaziri, S; Muñoz-Matutano, G; Leroux, M; Martinez-Pastor, J

    2017-01-01

    Here we report a theoretical investigation of excitonic complexes in polar GaN/(Al,Ga)N quantum dots (QDs). A sum rule between the binding energies of charged excitons is used to calculate the biexciton binding energy. The binding energies of excitonic complexes in GaN/AlN are shown to be strongly correlated to the QD size. Due to the large hole localization, the positively charged exciton energy is found to be always blueshifted compared to the exciton one. The negatively charged exciton and the biexciton energy can be blueshifted or redshifted according to the QD size. Increasing the size of GaN/AlN QDs makes the identification of charged excitons difficult, and the use of an Al 0.5 Ga 0.5 N barrier can be advantageous for clear identification. Our theoretical results for the binding energy of exciton complexes are also confronted with values deduced experimentally for InAs/GaAs QDs, confirming our theoretical prediction for charged excitonic complexes in GaN/(Al,Ga)N QDs. Finally, we realize that the trends of excitonic complexes in QDs are significantly related to competition between the local charge separation (whatever its origin) and the correlation effect. Following our findings, entangled photons pairs can be produced in QDs with careful control of their size in order to obtain zero exciton–biexciton energy separation. (paper)

  15. Pressure shifts of valence and core exciton peaks in potassium iodide

    International Nuclear Information System (INIS)

    Yamada, Akio; Fukutani, Hirohito; Miyabe, Masabumi; Yagi, Kazutoshi; Kato, Hiroo; Koide, Tsuneharu; Shidara, Tetsuo; Miyahara, Tsuneaki; Sato, Shigeru.

    1985-01-01

    Hydrostatic pressure shifts of valence and core exciton peaks in KI are measured with a modulation method at about 120 K. The pressure coefficients are determined to be, in units of 10 -3 meV/bar, 17.0 and 4.7 for the valence excitons at 5.73 and 7.22 eV, and 18.8, 17.0 and -38.7 for the core excitons at 19.95, 20.20 and 21.05 eV, respectively. The pressure shifts of the lowest exciton at 5.73 eV and the core excitons are discussed with a simple model of localized transitions. Experimental results for the lowest exciton and the core excitons at 19.95 and 20.20 eV are explained well in this model, but the shift of the core exciton at 21.05 eV does not agree with the theoretical expectation. The exciton-phonon interaction term contributing to thermal shifts of the excitons is deduced from the present pressure coefficients. (author)

  16. Exciton-polariton dynamics in quantum dot-cavity system

    Energy Technology Data Exchange (ETDEWEB)

    Neto, Antonio F.; Lima, William J.; Villas-Boas, Jose M. [Universidade Federal de Uberlandia (UFU), MG (Brazil). Inst. de Fisica

    2012-07-01

    Full text: One of the basic requirement for quantum information processing systems is the ability to completely control the state of a single qubit. This imply in know all sources of decoherence and elaborate ways to avoid them. In recent work, A. Laucht et al. [1] presented detailed theoretical and experimental investigations of electrically tunable single quantum dot (QD) - photonic crystal (PhC) nanocavity systems operating in the strong coupling regime of the light matter interaction. Unlike previous studies, where the exciton-cavity spectral detuning was varied by changing the lattice temperature, or by the adsorption of inert gases at low temperatures, they employ the quantum confined Stark-effect to electro-optically control the exciton-cavity detuning. The new built device enabled them to systematically probe the emission spectrum of the strongly coupled system as a function of external control parameters, as for example the incoherent excitation power density or the lattice temperature. Those studies reveal for the first time insights in dephasing mechanisms of 0D exciton polaritons [1]. In another study [2], using a similar device, they investigate the coupling between two different QDs with a single cavity mode. In both works, incoherent pumping was used, but for quantum information, coherent and controlled excitations are necessary. Here, we theoretically investigate the dynamics a single quantum dot inside a cavity under coherent pulse excitation and explore a wide range of parameters, as for example, the exciton-cavity detunings, the excitation power, the spontaneous decay, and pure dephasing. We use density matrix formalism in the Lindblad form, and we solve it numerically. Our results show that coherent excitation can be used to probe strong coupling between exciton and cavity mode by monitoring the exciton Rabi oscillation as function of the cavity detuning. This can give new insights for future experimental measurement focusing on quantum

  17. Effect of game format on heart rate, activity profile, and player involvement in elite and recreational youth players

    DEFF Research Database (Denmark)

    Randers, M B; Andersen, T. Bull; Rasmussen, L S

    2014-01-01

    and 11v11 (20 min) games. Activity profile, heart rate (HR), and technical actions were measured during all games using 10 Hz GPS, video filming, and HR monitors. For U10, no difference was found in total distance covered (1754 ± 237 vs 1771 ± 314 m, P = 0.650, d = 0.06), whereas mean HR (174 ± 10 vs 168......The purpose of this study was to evaluate activity profile, aerobic load, and player involvement in two game formats of recreational and elite youth football for two age groups. A total of 152 youth players participated, with 45 U10 players playing 5v5 and 8v8 games, and 41 U13 players playing 8v8...... game format. Playing with fewer players on smaller pitches results...

  18. On the number density of interstellar comets as a constraint on the formation rate of planetary systems

    International Nuclear Information System (INIS)

    Stern, S.A.

    1990-01-01

    The importance of detecting interstellar comets as an indirect indicator of the rate of planetary formation in the galaxy is discussed. The tie between interstellar comet (ISC) detection and planetary-system detection rests on the assumptions (1) that interstellar comets result from dynamical losses from planetary systems, (2) that comets are a natural product of planetary-system formation, (3) that comets are neither created nor destroyed in the interstellar medium, and (4) that the distribution of comets in interstellar space is approximately homogeneous. It is found that the present constraint on the space density of interstellar comets, if valid, is not far from constraining the statistical frequency and average population of extrasolar Oort clouds. An efficient method for dedicated ISC searches is briefly described. 10 refs

  19. Polyaspartic Acid Concentration Controls the Rate of Calcium Phosphate Nanorod Formation in High Concentration Systems

    Energy Technology Data Exchange (ETDEWEB)

    Krogstad, Daniel V. [Biosystems and; Wang, Dongbo [Biosystems and; Lin-Gibson, Sheng [Biosystems and

    2017-08-31

    Polyelectrolytes are known to greatly affect calcium phosphate (CaP) mineralization. The reaction kinetics as well as the CaP phase, morphology and aggregation state depend on the relative concentrations of the polyelectrolyte and the inorganic ions in a complex, nonlinear manner. This study examines the structural evolution and kinetics of polyaspartic acid (pAsp) directed CaP mineralization at high concentrations of polyelectrolytes, calcium, and total phosphate (19–30 mg/mL pAsp, 50–100 mM Ca2+, Ca/P = 2). Using a novel combination of characterization techniques including cryogenic transmission electron microscopy (cryo-TEM), spectrophotometry, X-ray total scattering pair distribution function analysis, and attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), it was determined that the CaP mineralization occurred over four transition steps. The steps include the formation of aggregates of pAsp stabilized CaP spherical nanoparticles (sNP), crystallization of sNP, oriented attachment of the sNP into nanorods, and further crystallization of the nanorods. The intermediate aggregate sizes and the reaction kinetics were found to be highly polymer concentration dependent while the sizes of the particles were not concentration dependent. This study demonstrates the complex role of pAsp in controlling the mechanism as well as the kinetics of CaP mineralization.

  20. The stellar mass, star formation rate and dark matter halo properties of LAEs at z ˜ 2

    Science.gov (United States)

    Kusakabe, Haruka; Shimasaku, Kazuhiro; Ouchi, Masami; Nakajima, Kimihiko; Goto, Ryosuke; Hashimoto, Takuya; Konno, Akira; Harikane, Yuichi; Silverman, John D.; Capak, Peter L.

    2018-01-01

    We present average stellar population properties and dark matter halo masses of z ˜ 2 Lyα emitters (LAEs) from spectral energy distribution fitting and clustering analysis, respectively, using ≃ 1250 objects (NB387≤25.5) in four separate fields of ≃ 1 deg2 in total. With an average stellar mass of 10.2 ± 1.8 × 108 M⊙ and star formation rate of 3.4 ± 0.4 M⊙ yr-1, the LAEs lie on an extrapolation of the star-formation main sequence (MS) to low stellar mass. Their effective dark matter halo mass is estimated to be 4.0_{-2.9}^{+5.1} × 10^{10}{ }M_{⊙} with an effective bias of 1.22^{+0.16}_{-0.18}, which is lower than that of z ˜ 2 LAEs (1.8 ± 0.3) obtained by a previous study based on a three times smaller survey area, with a probability of 96%. However, the difference in the bias values can be explained if cosmic variance is taken into account. If such a low halo mass implies a low H I gas mass, this result appears to be consistent with the observations of a high Lyα escape fraction. With the low halo masses and ongoing star formation, our LAEs have a relatively high stellar-to-halo mass ratio (SHMR) and a high efficiency of converting baryons into stars. The extended Press-Schechter formalism predicts that at z = 0 our LAEs are typically embedded in halos with masses similar to that of the Large Magellanic Cloud (LMC); they will also have similar SHMRs to the LMC, if their star formation rates are largely suppressed after z ˜ 2 as some previous studies have reported for the LMC itself.

  1. Rate of Biochemical oxygen demand during formation of hypoxia in Amur Bay, Sea of Japan

    Science.gov (United States)

    Tishchenko, P. P.; Tishchenko, P. Ya.; Zvalinskii, V. I.; Semkin, P. Yu.

    2014-12-01

    In May 2011, a Water Quality Monitor (WQM) hydrological station was maintained in the hypoxia area of Amur Bay one meter above the bottom, at the depth of 19 m. The temperature, electric conductivity, pressure, and content of dissolved oxygen were registered every four hours for more than three months. On the basis of these data, it was found that the period of hypoxia at the observation point lasted 93 days and a model of calculation of the rate of biochemical oxygen demand and the velocity of ventilation of the bottom waters is suggested.

  2. Nanoscopic Approach to Quantification of Equilibrium and Rate Constants of Complex Formation at Single-Molecule Level.

    Science.gov (United States)

    Zhang, Xuzhu; Sisamakis, Evangelos; Sozanski, Krzysztof; Holyst, Robert

    2017-12-07

    Equilibrium and rate constants are key descriptors of complex-formation processes in a variety of chemical and biological reactions. However, these parameters are difficult to quantify, especially in the locally confined, heterogeneous, and dynamically changing living matter. Herein, we address this challenge by combining stimulated emission depletion (STED) nanoscopy with fluorescence correlation spectroscopy (FCS). STED reduces the length-scale of observation to tens of nanometres (2D)/attoliters (3D) and the time-scale to microseconds, with direct, gradual control. This allows one to distinguish diffusional and binding processes of complex-formation, even at reaction rates higher by an order of magnitude than in confocal FCS. We provide analytical autocorrelation formulas for probes undergoing diffusion-reaction processes under STED condition. We support the theoretical analysis of experimental STED-FCS data on a model system of dye-micelle, where we retrieve the equilibrium and rates constants. Our work paves a promising way toward quantitative characterization of molecular interactions in vivo.

  3. What controls Rayleigh-Taylor instability growth rate and the formation of bubbles?

    Science.gov (United States)

    Yizengaw, E.; Moldwin, M.; Zesta, E.; Damtie, B.; Rabiu, B.; Valladares, C. E.; Stoneback, R.

    2014-12-01

    According to the Rayleigh-Taylor instability (RTI) growth rate mathematical expression, the vertical drift is supposed to be the primary component that controls the RTI growth rate. However, in the African sector that does not seem to be the case. In this paper we present independent ground- and space-based observations that consistently show weaker vertical drift (both dayside and evening sector) in the African sector compared with the American sector. On the other hand, observations from both satellite and recently deployed ground-based instruments have shown that the African sector is home to stronger and year-round ionospheric bubbles/irregularities and scintillations compared to the American and Asian sectors. The question is if the drift is weaker in the African sector, what causes these strong bubbles that have been observed in the African sector almost throughout the night and during all seasons? Are there other mechanisms that initiate RTI growth other than vertical drift? Would it be the neutral winds that cause the long lasting bubbles in Africa? If it is the neutral wind, why are the winds unique in terms of orientation and magnitude in the African sector compared to other longitudinal sectors?

  4. Sowing Date and Rate Effect on Winter Oilseed Rape (Brassica napus L. Yield Components’ Formation

    Directory of Open Access Journals (Sweden)

    Balodis Oskars

    2016-12-01

    Full Text Available Crop yield per area is the product of plant density and productivity of an individual plant. Plant density and the time of winter oilseed rape sowing influences yield components (parameters of individual plant productivity, such as pod number per plant, seed number per pod, plant productivity, seed weight, and plant branching. The aim of this three-year (2008–2010 study was to investigate winter oilseed rape yield components depending on sowing date (five sowing dates and sowing rate (four sowing rates for each variety as initial cause of plant density at harvest for two type winter oilseed rape varieties (open pollinated ‘Californium’ and hybrid ‘Excalibur’. Field trials were carried out at the Research and Study Farm “Vecauce” of the Latvia University of Agriculture. Winter oilseed rape yield components (pod number per plant and seed number per pod, plant productivity (seed number per plant and plant productivity in g as well as the number of primary branches per plant were affected (p 0.05, but sowing date influenced this component significantly (p < 0.05. A yield compensation mechanism was demonstrated by significant (p < 0.05 negative correlations between plant density at harvest and parameters of individual plant productivity.

  5. Shorter Exciton Lifetimes via an External Heavy-Atom Effect: Alleviating the Effects of Bimolecular Processes in Organic Light-Emitting Diodes.

    Science.gov (United States)

    Einzinger, Markus; Zhu, Tianyu; de Silva, Piotr; Belger, Christian; Swager, Timothy M; Van Voorhis, Troy; Baldo, Marc A

    2017-10-01

    Multiexcited-state phenomena are believed to be the root cause of two exigent challenges in organic light-emitting diodes; namely, efficiency roll-off and degradation. The development of novel strategies to reduce exciton densities under heavy load is therefore highly desirable. Here, it is shown that triplet exciton lifetimes of thermally activated delayed-fluorescence-emitter molecules can be manipulated in the solid state by exploiting intermolecular interactions. The external heavy-atom effect of brominated host molecules leads to increased spin-orbit coupling, which in turn enhances intersystem crossing rates in the guest molecule. Wave function overlap between the host and the guest is confirmed by combined molecular dynamics and density functional theory calculations. Shorter triplet exciton lifetimes are observed, while high photoluminescence quantum yields and essentially unaltered emission spectra are maintained. A change in the intersystem crossing rate ratio due to increased dielectric constants leads to almost 50% lower triplet exciton densities in the emissive layer in the steady state and results in an improved onset of the photoluminescence quantum yield roll-off at high excitation densities. Efficient organic light-emitting diodes with better roll-off behavior based on these novel hosts are fabricated, demonstrating the suitability of this concept for real-world applications. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Formation Rate-Limited Pharmacokinetics of Biologically Active Epoxy Transformers of Prodrug Treosulfan.

    Science.gov (United States)

    Romański, Michał; Kasprzyk, Anna; Karbownik, Agnieszka; Szałek, Edyta; Główka, Franciszek K

    2016-05-01

    A prodrug treosulfan (TREO) is being evaluated in clinical trials as a myeloablative agent before hematopoietic stem cell transplantation. The active derivatives of TREO, monoepoxide (EBDM), and diepoxide (DEB) are formed in a pH-dependent nonenzymatic reaction. The aim of the study was to investigate pharmacokinetics of the TREO epoxy transformers in a rabbit model and explain the causes of low plasma concentrations of EBDM and DEB observed in patients receiving high-dose TREO before hematopoietic stem cell transplantation. New Zealand white rabbits (n = 5 per cohort) received an intravenous infusion of TREO (group I), injection of DEB (group II), and injection of a solution containing EBDM (group III). When EBDM and DEB were administered to the rabbits, they underwent a very rapid elimination (half-life 0.069 and 0.046 h) associated with a high systemic clearance (10.0 and 14.0 L h(-1) kg(-1)). After administration of TREO, the t1/2 of EBDM was statistically equal to the t1/2 of the prodrug (1.6 h). To conclude, after administration of TREO, its epoxy transformers demonstrate a formation-limited elimination. Then EBDM and DEB have the same elimination half-life as TREO, but the levels of EBDM and DEB in the body, including plasma, are much lower than TREO on account of their inherently high clearance. Copyright © 2016 American Pharmacists Association®. Published by Elsevier Inc. All rights reserved.

  7. Estimating Star Formation Rates from Infrared and Radio Luminosities: The Origin of the Radio-Infrared Correlation

    OpenAIRE

    Bell, Eric F.

    2002-01-01

    I have assembled a diverse sample of galaxies from the literature with far-ultraviolet (FUV), optical, infrared (IR) and radio luminosities to explore the calibration of radio-derived and IR-derived star formation (SF) rates, and the origin of the radio-IR correlation. By comparing the 8-1000 micron IR, which samples dust-reprocessed starlight, with direct stellar FUV emission, I show that the IR traces most of the SF in luminous L* galaxies but traces only a small fraction of the SF in faint...

  8. Dimethylarsenate (DMA) exposure influences germination rates, arsenic uptake and arsenic species formation in wheat.

    Science.gov (United States)

    Duncan, Elliott G; Maher, William A; Foster, Simon D; Krikowa, Frank; O'Sullivan, Cathryn A; Roper, Margaret M

    2017-08-01

    The contamination of cereals with arsenic (As) is a global health and agronomic concern. This study compared the physiological response, As uptake and As speciation in the grains and above ground tissues of 20 wheat cultivars exposed to 5 mg As kg -1 soil as either arsenate (As V ) or dimethylarsenate (DMA) under glasshouse conditions. Germination rates for the majority of cultivars exceeded 80% for the majority of cultivars when exposed to As V , but fell significantly to 20-40% when exposed to DMA. For a number of cultivars, grain yields were 20-50% lower when plants were exposed to DMA compared to As V . Grain As concentrations were between 0.6 and 1.6 μg As g -1 grain across the twenty cultivars when exposed to As V , whereas grain As concentrations were much higher (2.2-4.6 μg As g -1 grain) when exposed to DMA. When plants were exposed to As V , 100% of the As present in the grain was found as inorganic As while in plants exposed to DMA, 70-90% of As was present as DMA with the remainder found as inorganic As. DMA is believed to be incorporated by plants via silica (Si) acid channels and assessment of grain Si concentrations demonstrated that up to 40% less Si was accumulated in grains when plants were exposed to DMA. The decreased germination rates and grain yields in the presence of DMA is similar to the symptoms described for straight head disease in rice, which has been linked to DMA exposure. The results presented here indicate some analogous processes occur in wheat to those described in rice. We hypothesise that exposure to DMA may have inhibited Si-metabolism and translocation which resulted in both developmental impairment and possibly an increased susceptibility to soil pathogens. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Determination of the Rate of Formation of Hydroceramic Waste Forms made with INEEL Calcined Wastes

    Energy Technology Data Exchange (ETDEWEB)

    Barry Scheetz; Johnson Olanrewaju

    2001-10-15

    conductivity, pH and analytical concentration measured as a function of time decrease exponentially. In some cases nitrate, sulfate, chloride and fluoride ion concentrations increased with time and processing temperature with respect to the reference sample. The increasing concentration of these ions was due to the lack of formation of crystalline phases that can incorporate them in their structures, especially cancrinite. Another plausible explanations for their increase was due to the continuous withdrawal of cations with time, for example sodium to form zeolites, thereby increase their concentrations.

  10. Linewidths in excitonic absorption spectra of cuprous oxide

    Science.gov (United States)

    Schweiner, Frank; Main, Jörg; Wunner, Günter

    2016-02-01

    We present a theoretical calculation of the absorption spectrum of cuprous oxide (Cu2O ) based on the general theory developed by Y. Toyozawa. An inclusion not only of acoustic phonons but also of optical phonons and of specific properties of the excitons in Cu2O like the central-cell corrections for the 1 S exciton allows us to calculate the experimentally observed linewidths in experiments by T. Kazimierczuk et al. [T. Kazimierczuk, D. Fröhlich, S. Scheel, H. Stolz, and M. Bayer, Nature (London) 514, 343 (2014), 10.1038/nature13832] within the same order of magnitude, which demonstrates a clear improvement in comparison to earlier work on this topic. We also discuss a variety of further effects, which explain the still observable discrepancy between theory and experiment but can hardly be included in theoretical calculations.

  11. Marrying Excitons and Plasmons in Monolayer Transition-Metal Dichalcogenides

    Science.gov (United States)

    Van Tuan, Dinh; Scharf, Benedikt; Žutić, Igor; Dery, Hanan

    2017-10-01

    Just as photons are the quanta of light, plasmons are the quanta of orchestrated charge-density oscillations in conducting media. Plasmon phenomena in normal metals, superconductors, and doped semiconductors are often driven by long-wavelength Coulomb interactions. However, in crystals whose Fermi surface is comprised of disconnected pockets in the Brillouin zone, collective electron excitations can also attain a shortwave component when electrons transition between these pockets. In this work, we show that the band structure of monolayer transition-metal dichalcogenides gives rise to an intriguing mechanism through which shortwave plasmons are paired up with excitons. The coupling elucidates the origin for the optical sideband that is observed repeatedly in monolayers of WSe2 and WS2 but not understood. The theory makes it clear why exciton-plasmon coupling has the right conditions to manifest itself distinctly only in the optical spectra of electron-doped tungsten-based monolayers.

  12. Jointly Tuned Plasmonic–Excitonic Photovoltaics Using Nanoshells

    KAUST Repository

    Paz-Soldan, Daniel

    2013-04-10

    Recent advances in spectrally tuned, solution-processed plasmonic nanoparticles have provided unprecedented control over light\\'s propagation and absorption via engineering at the nanoscale. Simultaneous parallel progress in colloidal quantum dot photovoltaics offers the potential for low-cost, large-area solar power; however, these devices suffer from poor quantum efficiency in the more weakly absorbed infrared portion of the sun\\'s spectrum. Here, we report a plasmonic-excitonic solar cell that combines two classes of solution-processed infrared materials that we tune jointly. We show through experiment and theory that a plasmonic-excitonic design using gold nanoshells with optimized single particle scattering-to-absorption cross-section ratios leads to a strong enhancement in near-field absorption and a resultant 35% enhancement in photocurrent in the performance-limiting near-infrared spectral region. © 2013 American Chemical Society.

  13. Two-Dimensional Superfluidity of Exciton Polaritons Requires Strong Anisotropy

    Directory of Open Access Journals (Sweden)

    Ehud Altman

    2015-02-01

    Full Text Available Fluids of exciton polaritons, excitations of two-dimensional quantum wells in optical cavities, show collective phenomena akin to Bose condensation. However, a fundamental difference from standard condensates stems from the finite lifetime of these excitations, which necessitates continuous driving to maintain a steady state. A basic question is whether a two-dimensional condensate with long-range algebraic correlations can exist under these nonequilibrium conditions. Here, we show that such driven two-dimensional Bose systems cannot exhibit algebraic superfluid order except in low-symmetry, strongly anisotropic systems. Our result implies, in particular, that recent apparent evidence for Bose condensation of exciton polaritons must be an intermediate-scale crossover phenomenon, while the true long-distance correlations fall off exponentially. We obtain these results through a mapping of the long-wavelength condensate dynamics onto the anisotropic Kardar-Parisi-Zhang equation.

  14. Non-Hermitian exciton dynamics in a photosynthetic unit system

    Science.gov (United States)

    Thilagam, A.

    2012-02-01

    The non-Hermitian quantum dynamics of excitonic energy transfer in photosynthetic systems is investigated using a dissipative two-level dimer model. The approach is based on Green's function formalism which permits consideration of decoherence and intersite transfer processes on comparable terms. The results indicate a combination of coherent and incoherent behavior at higher temperatures with the possibility of exceptional points occurring at the coherent-incoherent crossover regime at critical temperatures. When each dimer site is coupled equally to the environmental sources of dissipation, the excitonic wavepacket evolves with time with a coherent component, which can be attributed to the indistinguishability of the sources of dissipation. The time evolution characteristics of the B850 Bchls dimer system is analysed using typical parameter estimates in photosynthetic systems, and the quantum brachistochrone passage times are obtained for a range of parameters.

  15. Self-trapped excitonic green emission from layered semiconductors

    International Nuclear Information System (INIS)

    Miah, M. Idrish

    2009-01-01

    Crystals of layered semiconductor are grown by Bridgman technique and are studied them under two-photon excitation by a Q-switched 20-ns pulse laser. The photoluminescence (PL) emission spectra of the crystals are measured at various pumping powers and temperatures. The PL spectra appear broad and structureless emissions with their peaks in the green spectral region. The characteristic emissions are from self-trapped excitons of the crystals. An analysis of the spectra measured at various pumping powers shows a quadratic dependence of the PL peak intensity on the power, confirming a biphotonic process of the two-photon pumping. The temperature dependence shows an enhancement of the nonlinear response at low temperatures. The activation energy is estimated and found to be 2.4 meV. The roles of the bound excitons in the observed PL are discussed briefly.

  16. Self-trapped excitonic green emission from layered semiconductors

    Energy Technology Data Exchange (ETDEWEB)

    Miah, M. Idrish, E-mail: m.miah@griffith.edu.au [Nanoscale Science and Technology Centre, Griffith University, Nathan, Brisbane, QLD 4111 (Australia); School of Biomolecular and Physical Sciences, Griffith University, Nathan, Brisbane, QLD 4111 (Australia); Department of Physics, University of Chittagong, Chittagong 4331 (Bangladesh)

    2009-08-15

    Crystals of layered semiconductor are grown by Bridgman technique and are studied them under two-photon excitation by a Q-switched 20-ns pulse laser. The photoluminescence (PL) emission spectra of the crystals are measured at various pumping powers and temperatures. The PL spectra appear broad and structureless emissions with their peaks in the green spectral region. The characteristic emissions are from self-trapped excitons of the crystals. An analysis of the spectra measured at various pumping powers shows a quadratic dependence of the PL peak intensity on the power, confirming a biphotonic process of the two-photon pumping. The temperature dependence shows an enhancement of the nonlinear response at low temperatures. The activation energy is estimated and found to be 2.4 meV. The roles of the bound excitons in the observed PL are discussed briefly.

  17. Magnetic dependence of exciton levels in diluted magnetic semiconductor heterostructures

    International Nuclear Information System (INIS)

    Naumenko, A.V.; Sugakov, V.I.

    1994-01-01

    Energy levels of Wannier exciton in a semi magnetic quantum well structures in external magnetic field are calculated with the use of a variational approach. We consider two heterojunctions: Cd Mr Te/Cd Te/Cd Mn Te and Cd Mn Te/Cd Zn Te/Cd Mn Te. Dependences of the lowest interband transitions energies on the well width are qualitatively different for these two systems. In the first case energy splitting of σ + and σ - transitions in the magnetic field decreases as the well width increases, in the second case it increases. It is connected with the more significant role of exchange interaction between exciton and magnetic ions in the case when the well is doped by magnetic impurities (the first case) than in that one when barriers are doped by these impurities (the second case) because of exponential decay of wave functions in barriers. (author). 5 refs., 6 figs

  18. Nonlinear spectroscopy of excitons and biexcitons in ZnS

    International Nuclear Information System (INIS)

    Pavlov, L.I.; Paskov, P.P.; Lalov, I.J.

    1989-01-01

    Four- photon spectroscopy on exciton and biexciton states in ZnS is reported at T = 10 K. The Nd:YAG laser is used as a fundamental source in the experimental setup. Second harmonic radiation ω 2 pumps the dye laser of ω 1 tunable frequency. The ZnS single crystal is placed in an optical cryostat for resonant spectroscopy at low temperature. Four-photon mixing ω 3 = 2ω 1 -ω 2 signal is separated by MDR-23 monochromator and is registered by a laser photometer. The hexagonal ZnS crystal is experimentally investigated when the waves ω 1 and ω 2 propagate colinear with the optical axis. The crystal is cut along the (1120) plane. The photon 2ℎω 1 energy scans over the range 3.895-3.940 eV. The dispersion of I 3 (ω 3 ) upon 2ℎω 1 is obtained. Three resonances are registered E M = 3.8964, E B 1 = 3.9010 and E B 2 = 3.9311 eV. The recorded low temperature resonance in dispersion of nonlinearity χ (3) are identified with B 1 s and B 2 s excitons as well as with biexciton in ZnS which is observed for the first time in this crystal. An experimental dependence of the signal I 3 (ω 3 ) intensity upon the pump I 1 (ω 1 ) is obtained. The E M resonance is saturated with the I 1 (ω 1 ) enhancement while the E B 1 resonance increases. Authors explain such a behaviour by the fact that the recombination probability of the biexcitons to excitons increases with the pump level growth. Estimations for the exciton density and the bounding energy are given. (author)

  19. Effect of bore fluid flow rate on formation and properties of hollow fibers

    Science.gov (United States)

    Alobaidy, Asrar A.; Sherhan, Bashir Y.; Barood, Areej D.; Alsalhy, Qusay F.

    2017-12-01

    In this work, for high performance and wide range of ultrafiltration applications, the effects of the most widely used values of internal coagulant flow rates (ICFR) (i.e., 2.6, 3.6, 4, 5, 7, 9, 11, and 13 ml/min) on the different features of the polyvinylchloride hollow fiber have been investigated. Both the idealized straight and the cylindrical pore with small effect of tortuosity were approximately obtained through the effect of ICFR. Atomic force microscope (AFM), scanning electron microscope (SEM), and ultrafiltration measurements were utilized to characterize the hollow fibers. The SEM and AFM results indicated that the cross-sectional morphology of the fibers is changed significantly with various ICFR. The structure of the inner surface was also changed from an open cellular structure to a porous structure by means of high pore density and small pore diameter. In addition, the membrane thickness was reduced by 314% with an increase in the ICFR from 2.6 to 13 ml/min. The pure water permeation flux was improved 17 times when ICFR was increased to 13 ml/min, while the BSA rejection remained within the acceptable range (from 93.4 to 90.4) when the ICFR was increased from 2.6 to 9 ml/min.

  20. Spatially resolved and time-resolved imaging of transport of indirect excitons in high magnetic fields

    Science.gov (United States)

    Dorow, C. J.; Hasling, M. W.; Calman, E. V.; Butov, L. V.; Wilkes, J.; Campman, K. L.; Gossard, A. C.

    2017-06-01

    We present the direct measurements of magnetoexciton transport. Excitons give the opportunity to realize the high magnetic-field regime for composite bosons with magnetic fields of a few tesla. Long lifetimes of indirect excitons allow the study of kinetics of magnetoexciton transport with time-resolved optical imaging of exciton photoluminescence. We performed spatially, spectrally, and time-resolved optical imaging of transport of indirect excitons in high magnetic fields. We observed that an increasing magnetic field slows down magnetoexciton transport. The time-resolved measurements of the magnetoexciton transport distance allowed for an experimental estimation of the magnetoexciton diffusion coefficient. An enhancement of the exciton photoluminescence energy at the laser excitation spot was found to anticorrelate with the exciton transport distance. A theoretical model of indirect magnetoexciton transport is presented and is in agreement with the experimental data.

  1. Exciton spectra of mixed LiH1-xDx crystals

    International Nuclear Information System (INIS)

    Plekhanov, V.G.

    1989-01-01

    The results of low-tempertaure experimental investigation of exciton spectra of pure surface of mixed crystals LiH 1-x d x forming the continuous series of a solved solution are presented. The long-wave reflection spectra is formed, as in pure crystals, by excitons of a large radius. The developed structure of spectra of exciton luminiscence consisting mainly of LO-lines, testifies to the intraband Frelich mechanism of free exciton scattering by LO-phonos, playing the considerable role in renormalization of the exciton Rydberg and the energy of interband transitions. Increase of the concentration of deuterium in mixed crystals causes a short-wave shift in the reflection spectrum and luminescence and continuous decrease of LO-phonon energy together with the increase of Rydberg exciton

  2. Ultrafast quantum beats of anisotropic excitons in atomically thin ReS2.

    Science.gov (United States)

    Sim, Sangwan; Lee, Doeon; Trifonov, Artur V; Kim, Taeyoung; Cha, Soonyoung; Sung, Ji Ho; Cho, Sungjun; Shim, Wooyoung; Jo, Moon-Ho; Choi, Hyunyong

    2018-01-24

    Quantum beats, periodic oscillations arising from coherent superposition states, have enabled exploration of novel coherent phenomena. Originating from strong Coulomb interactions and reduced dielectric screening, two-dimensional transition metal dichalcogenides exhibit strongly bound excitons either in a single structure or hetero-counterpart; however, quantum coherence between excitons is barely known to date. Here we observe exciton quantum beats in atomically thin ReS 2 and further modulate the intensity of the quantum beats signal. Surprisingly, linearly polarized excitons behave like a coherently coupled three-level system exhibiting quantum beats, even though they exhibit anisotropic exciton orientations and optical selection rules. Theoretical studies are also provided to clarify that the observed quantum beats originate from pure quantum coherence, not from classical interference. Furthermore, we modulate on/off quantum beats only by laser polarization. This work provides an ideal laboratory toward polarization-controlled exciton quantum beats in two-dimensional materials.

  3. Exciton diffusion coefficient measurement in ZnO nanowires under electron beam irradiation

    Science.gov (United States)

    Donatini, Fabrice; Pernot, Julien

    2018-03-01

    In semiconductor nanowires (NWs) the exciton diffusion coefficient can be determined using a scanning electron microscope fitted with a cathodoluminescence system. High spatial and temporal resolution cathodoluminescence experiments are needed to measure independently the exciton diffusion length and lifetime in single NWs. However, both diffusion length and lifetime can be affected by the electron beam bombardment during observation and measurement. Thus, in this work the exciton lifetime in a ZnO NW is measured versus the electron beam dose (EBD) via a time-resolved cathodoluminescence experiment with a temporal resolution of 50 ps. The behavior of the measured exciton lifetime is consistent with our recent work on the EBD dependence of the exciton diffusion length in similar NWs investigated under comparable SEM conditions. Combining the two results, the exciton diffusion coefficient in ZnO is determined at room temperature and is found constant over the full span of EBD.

  4. The natural emergence of the correlation between H2 and star formation rate surface densities in galaxy simulations

    Science.gov (United States)

    Lupi, Alessandro; Bovino, Stefano; Capelo, Pedro R.; Volonteri, Marta; Silk, Joseph

    2018-03-01

    In this study, we present a suite of high-resolution numerical simulations of an isolated galaxy to test a sub-grid framework to consistently follow the formation and dissociation of H2 with non-equilibrium chemistry. The latter is solved via the package KROME, coupled to the mesh-less hydrodynamic code GIZMO. We include the effect of star formation (SF), modelled with a physically motivated prescription independent of H2, supernova feedback and mass-losses from low-mass stars, extragalactic and local stellar radiation, and dust and H2 shielding, to investigate the emergence of the observed correlation between H2 and SF rate surface densities. We present two different sub-grid models and compare them with on-the-fly radiative transfer (RT) calculations, to assess the main differences and limits of the different approaches. We also discuss a sub-grid clumping factor model to enhance the H2 formation, consistent with our SF prescription, which is crucial, at the achieved resolution, to reproduce the correlation with H2. We find that both sub-grid models perform very well relative to the RT simulation, giving comparable results, with moderate differences, but at much lower computational cost. We also find that, while the Kennicutt-Schmidt relation for the total gas is not strongly affected by the different ingredients included in the simulations, the H2-based counterpart is much more sensitive, because of the crucial role played by the dissociating radiative flux and the gas shielding.

  5. The nature of singlet excitons in oligoacene molecular crystals

    KAUST Repository

    Yamagata, H.

    2011-01-01

    A theory for polarized absorption in crystalline oligoacenes is presented, which includes Frenkel exciton coupling, the coupling between Frenkel and charge-transfer (CT) excitons, and the coupling of all neutral and ionic excited states to the dominant ring-breathing vibrational mode. For tetracene, spectra calculated using all Frenkel couplings among the five lowest energy molecular singlet states predict a Davydov splitting (DS) of the lowest energy (0-0) vibronic band of only -32cm-1, far smaller than the measured value of 631cm-1 and of the wrong sign-a negative sign indicating that the polarizations of the lower and upper Davydov components are reversed from experiment. Inclusion of Frenkel-CT coupling dramatically improves the agreement with experiment, yielding a 0-0 DS of 601cm-1 and a nearly quantitative reproduction of the relative spectral intensities of the 0-n vibronic components. Our analysis also shows that CT mixing increases with the size of the oligoacenes. We discuss the implications of these results on exciton dissociation and transport. © 2011 American Institute of Physics.

  6. THE BURSTY STAR FORMATION HISTORIES OF LOW-MASS GALAXIES AT 0.4 < z < 1 REVEALED BY STAR FORMATION RATES MEASURED FROM H β AND FUV

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Yicheng; Faber, S. M.; Koo, David C.; Krumholz, Mark R.; Barro, Guillermo; Yesuf, Hassen [UCO/Lick Observatory, Department of Astronomy and Astrophysics, University of California, Santa Cruz, CA (United States); Rafelski, Marc; Gardner, Jonathan P.; Pacifici, Camilla [Goddard Space Flight Center, Code 665, Greenbelt, MD (United States); Trump, Jonathan R. [Department of Astronomy and Astrophysics and Institute for Gravitation and the Cosmos, Pennsylvania State University, University Park, PA (United States); Willner, S. P. [Harvard-Smithsonian Center for Astrophysics, Cambridge, MA (United States); Amorín, Ricardo [INAF-Osservatorio Astronomico di Roma, Monte Porzio Catone (Italy); Bell, Eric F. [Department of Astronomy, University of Michigan, Ann Arbor, MI (United States); Gawiser, Eric [Department of Physics and Astronomy, Rutgers University, New Brunswick, NJ (United States); Hathi, Nimish P. [Aix Marseille Université, CNRS, LAM (Laboratoire d’Astrophysique de Marseille) UMR 7326, Marseille (France); Koekemoer, Anton M.; Ravindranath, Swara [Space Telescope Science Institute, Baltimore, MD (United States); Pérez-González, Pablo G. [Departamento de Astrofísica, Facultad de CC. Físicas, Universidad Complutense de Madrid, E-28040 Madrid (Spain); Reddy, Naveen [Department of Physics and Astronomy, University of California, Riverside, CA (United States); Teplitz, Harry I., E-mail: ycguo@ucolick.org [Infrared Processing and Analysis Center, Caltech, Pasadena, CA 91125 (United States)

    2016-12-10

    We investigate the burstiness of star formation histories (SFHs) of galaxies at 0.4 <  z  < 1 by using the ratio of star formation rates (SFRs) measured from H β and FUV (1500 Å) (H β -to-FUV ratio). Our sample contains 164 galaxies down to stellar mass ( M {sub *}) of 10{sup 8.5} M {sub ⊙} in the CANDELS GOODS-N region, where Team Keck Redshift Survey Keck/DEIMOS spectroscopy and Hubble Space Telescope /WFC3 F275W images from CANDELS and Hubble Deep UV Legacy Survey are available. When the ratio of H β - and FUV-derived SFRs is measured, dust extinction correction is negligible (except for very dusty galaxies) with the Calzetti attenuation curve. The H β -to-FUV ratio of our sample increases with M {sub *} and SFR. The median ratio is ∼0.7 at M {sub *} ∼ 10{sup 8.5} M {sub ⊙} (or SFR ∼ 0.5 M {sub ⊙} yr{sup −1}) and increases to ∼1 at M {sub *} ∼ 10{sup 10} M {sub ⊙} (or SFR ∼ 10 M {sub ⊙} yr{sup −1}). At M {sub *} < 10{sup 9.5} M {sub ⊙}, our median H β -to-FUV ratio is lower than that of local galaxies at the same M {sub *}, implying a redshift evolution. Bursty SFH on a timescale of a few tens of megayears on galactic scales provides a plausible explanation for our results, and the importance of the burstiness increases as M {sub *} decreases. Due to sample selection effects, our H β -to-FUV ratio may be an upper limit of the true value of a complete sample, which strengthens our conclusions. Other models, e.g., non-universal initial mass function or stochastic star formation on star cluster scales, are unable to plausibly explain our results.

  7. THE PROJECTED RATE OF COMPETENCE FORMATION AS A TOOL OF EDUCATIONAL MANAGEMENT OF ADVANCED LEVEL OF EDUCATION

    Directory of Open Access Journals (Sweden)

    L. V. Lvov

    2017-01-01

    Full Text Available Introduction. Specially organized complex of the scientific research directed to obtaining the reliable advancing information about development of pedagogical members is necessary for the development of educational policy, the strategy of development for educational systems, and methods of management of quality of pedagogical activity at different stages of education. The result of the educational management of professional and educational process is caused by the quality of pedagogical design. In turn, the quality of pedagogical forecasting is a factor determining the overall effectiveness of management through the pedagogical design.The aim of this article is to describe the model that allows applying the rate of competence formation as a tool of educational management and providing the advanced level of education. Methodology and research methods are based on pre-competence and context approach, which supposes the content selection as a set of competencies and designing the educational and professional process with the use of the rate of formation of ability and readiness (competency as a tool of teaching management.Results. The author states socio-pedagogical contradiction, which is in acute shortage of predictive tools in the management of the educational process. The article describes terminology and empirical mathematical models that underpin pedagogical management of the educational and professional training of students that provides the advanced level of formation of organizational and managerial competence.Scientific novelty. The author clarifies the concept of the advanced level of education; introduces the term of the rate of formation of competency; proposes a new model to solve the problem of predicting learning outcomes and timely management influence by managers of education at all stages of the design and functioning of the educational system in the conditions of implementation of competence-based approach in the higher school

  8. Vitamin C supplementation enhances compact morulae formation but reduces the hatching blastocyst rate of bovine somatic cell nuclear transfer embryos.

    Science.gov (United States)

    Li, Qian; Wang, Yong-Sheng; Wang, Li-Jun; Zhang, Hui; Li, Rui-Zhe; Cui, Chen-Chen; Li, Wen-Zhe; Zhang, Yong; Jin, Ya-Ping

    2014-08-01

    Vitamin C, an antioxidant that reduces reactive oxygen species (ROS) in cells, is capable of significantly improving the developmental competence of porcine and mouse somatic cell nuclear transfer (SCNT) embryos, both in vitro and in vivo. In the present study, the effects of vitamin C on the developmental competence of bovine SCNT embryos were investigated. The results indicated that vitamin C (40 μg/mL) positively affected the scavenging of intracellular ROS, cleavage rate at 24 h (76.67 vs. 68.26%, pvitamin C supplementation did not significantly affect the blastocyst formation rate and proportion of inner cell mass over total cells per blastocyst on day 7. Moreover, vitamin C supplementation obviously impaired the total cell numbers per blastocyst (97.20 ± 11.35 vs. 88.57 ± 10.43, pVitamin C supplementation preferentially improved the viability of bovine SCNT embryos prior to the blastocyst stage, but did not enhance the formation and quality of blastocysts in vitro. In conclusion, the effect of vitamin C on the development of bovine SCNT embryos is complex, and vitamin C is not a suitable antioxidant chemical for the in vitro culture of bovine SCNT embryos.

  9. Collective Behavior of a Spin-Aligned Gas of Interwell Excitons in Double Quantum Wells

    DEFF Research Database (Denmark)

    Larionov, A. V.; Bayer, M.; Hvam, Jørn Märcher

    2005-01-01

    The kinetics of a spin-aligned gas of interwell excitons in GaAs/AlGaAs double quantum wells (n–i–n heterostructure) is studied. The temperature dependence of the spin relaxation time for excitons, in which a photoexcited electron and hole are spatially separated between two adjacent quantum well...... is associated with indirect evidence of the coherence of the collective phase of interwell excitons at temperatures below the critical value....

  10. Spatial mapping of exciton lifetimes in single ZnO nanowires

    Directory of Open Access Journals (Sweden)

    J. S. Reparaz

    2013-07-01

    Full Text Available We investigate the spatial dependence of the exciton lifetimes in single ZnO nanowires. We have found that the free exciton and bound exciton lifetimes exhibit a maximum at the center of nanowires, while they decrease by 30% towards the tips. This dependence is explained by considering the cavity-like properties of the nanowires in combination with the Purcell effect. We show that the lifetime of the bound-excitons scales with the localization energy to the power of 3/2, which validates the model of Rashba and Gurgenishvili at the nanoscale.

  11. Plasmonic Structure Enhanced Exciton Generation at the Interface between the Perovskite Absorber and Copper Nanoparticles

    Directory of Open Access Journals (Sweden)

    Sheng Hsiung Chang

    2014-01-01

    Full Text Available The refractive index and extinction coefficient of a triiodide perovskite absorber (TPA were obtained by fitting the transmittance spectra of TPA/PEDOT:PSS/ITO/glass using the transfer matrix method. Cu nanoplasmonic structures were designed to enhance the exciton generation in the TPA and to simultaneously reduce the film thickness of the TPA. Excitons were effectively generated at the interface between TPA and Cu nanoparticles, as observed through the 3D finite-difference time-domain method. The exciton distribution is advantageous for the exciton dissociation and carrier transport.

  12. Plasmonic Structure Enhanced Exciton Generation at the Interface between the Perovskite Absorber and Copper Nanoparticles

    Science.gov (United States)

    Lin, Kuen-Feng; Chiang, Chien-Hung; Wu, Chun-Guey

    2014-01-01

    The refractive index and extinction coefficient of a triiodide perovskite absorber (TPA) were obtained by fitting the transmittance spectra of TPA/PEDOT:PSS/ITO/glass using the transfer matrix method. Cu nanoplasmonic structures were designed to enhance the exciton generation in the TPA and to simultaneously reduce the film thickness of the TPA. Excitons were effectively generated at the interface between TPA and Cu nanoparticles, as observed through the 3D finite-difference time-domain method. The exciton distribution is advantageous for the exciton dissociation and carrier transport. PMID:25295290

  13. Energetic disorder and exciton states of individual molecular rings

    International Nuclear Information System (INIS)

    Herman, Pavel; Barvik, Ivan; Zapletal, David

    2006-01-01

    Exciton states in molecular rings (resembling, e.g. the B850 ring from LH2 complexes of purple bacterium Rhodopseudomonas acidophila) with strong intermolecular interaction are still a question of interest [V. Sundstrom, T. Pullerits, R. van Grondelle, J. Phys. Chem. B 103 (1999) 2327]. In our theoretical model we use the ring of two-level systems, simulating, e.g., the bacteriochlorophylls B850. The dynamical aspects in ensemble of rings are reflected in optical line shapes of electronic transitions. The observed linewidths reflect the combined influence of different types of static and dynamic disorder. To avoid the broadening of lines due to ensemble averaging one uses the single-molecule spectroscopy technique to obtain a fluorescence-excitation spectrum. For zero disorder the exciton manifold features two non-degenerate and eight pairwise degenerate states. In the presence of energetic disorder the degeneracy of the exciton states is lifted and oscillator strength is redistributed among the exciton states. A satisfactory understanding of the nature of static disorder in light-harvesting systems has not been reached [S. Jang, S.F. Dempster, R.J. Silbey, J. Phys. Chem. B 105 (2001) 6655]. In the local site basis, there can be present static disorder in both diagonal and off-diagonal Hamiltonian matrix elements. Silbey et al. [J. Phys. Chem. B 105 (2001) 6655] pointed out several questions: is former enough or the latter should be included as well? If both are considered, then there remains a question about whether they are independent or correlated. The distribution of the energetic separation E(k=+/-1) and relative orientation of the transition-dipole moments has been recently investigated [S. Jang, et al., J. Phys. Chem. B 105 (2001) 6655; C. Hofmann, T.J. Aartsma, J. Koehler, Chem. Phys. Lett. 395 (2004) 373]. In our present contribution we have extended such a type of investigation to four models of noncorrelated static disorder: (A) Gaussian disorder in the

  14. 4P-NPD ultra-thin films as efficient exciton blocking layers in DBP/C70 based organic solar cells

    Science.gov (United States)

    Patil, Bhushan R.; Liu, Yiming; Qamar, Talha; Rubahn, Horst-Günter; Madsen, Morten

    2017-09-01

    Exciton blocking effects from ultra-thin layers of N,N‧-di-1-naphthalenyl-N,N‧-diphenyl [1,1‧:4‧,1″:4″,1‴-quaterphenyl]-4,4‴-diamine (4P-NPD) were investigated in small molecule-based inverted organic solar cells (OSCs) using tetraphenyldibenzoperiflanthene as the electron donor material and fullerene (C70) as the electron acceptor material. The short-circuit current density (J SC) and power conversion efficiency (PCE) of the optimized OSCs with 0.7 nm thick 4P-NPD were approximately 16% and 24% higher, respectively, compared to reference devices without exciton blocking layers (EBLs). Drift diffusion-based device modeling was conducted to model the full current density-voltage (JV) characteristics and external quantum efficiency spectrum of the OSCs, and photoluminescence measurements were conducted to investigate the exciton blocking effects with increasing thicknesses of the 4P-NPD layer. Importantly, coupled optical and electrical modeling studies of the device behaviors and exciton generation rates and densities in the active layer for different 4P-NPD layer thicknesses were conducted, in order to gain a complete understanding of the observed increase in PCE for 4P-NPD layer thicknesses up to 1 nm, and the observed decrease in PCE for layer thicknesses beyond 1 nm. This work demonstrates a route for guiding the integration of EBLs in OSC devices.

  15. Growth Rate and Biofilm Formation Ability of Clinical and Laboratory-Evolved Colistin-Resistant Strains of Acinetobacter baumannii

    Directory of Open Access Journals (Sweden)

    Zahra Farshadzadeh

    2018-02-01

    Full Text Available Two different mechanisms of resistance to colistin in Acinetobacter baumannii have been described. The first involves the total loss of lipopolysaccharide (LPS due to mutations in the lpxACD operon, which is involved in the lipid A biosynthesis pathway. The second entails the addition of ethanolamine to the lipid A of the LPS resulting from mutations in the PmrAB two-component system. To evaluate the impact of colistin resistance-associated mutations on antimicrobial resistance and virulence properties, four pairs of clinical and laboratory-evolved colistin-susceptible/colistin-resistant (ColS/ColR A. baumannii isolates were used. Antimicrobial susceptibility, surface motility, in vitro and in vivo biofilm-forming capacity, in vitro and in vivo expression levels of biofilm-associated genes, and in vitro growth rate were analyzed in these strains. Growth rate, in vitro and in vivo biofilm formation ability, as well as expression levels of biofilm-associated gene were reduced in ColR LPS-deficient isolate (the lpxD mutant when compared with its ColS partner, whereas there were not such differences between LPS-modified isolates (the pmrB mutants and their parental isolates. Mutation in lpxD was accompanied by a greater reduction in minimum inhibitory concentrations of azithromycin, vancomycin, and rifampin than mutation in pmrB. Besides, loss of LPS was associated with a significant reduction in surface motility without any change in expression of type IV pili. Collectively, colistin resistance through loss of LPS causes a more considerable cost in biological features such as growth rate, motility, and biofilm formation capacity relative to LPS modification. Therefore, ColR LPS-modified strains are more likely to spread and transmit from one patient to another in hospital settings, which results in more complex treatment and control.

  16. Magnetic field effect on the energy levels of an exciton in a GaAs quantum dot: Application for excitonic lasers.

    Science.gov (United States)

    Jahan, K Luhluh; Boda, A; Shankar, I V; Raju, Ch Narasimha; Chatterjee, Ashok

    2018-03-22

    The problem of an exciton trapped in a Gaussian quantum dot (QD) of GaAs is studied in both two and three dimensions in the presence of an external magnetic field using the Ritz variational method, the 1/N expansion method and the shifted 1/N expansion method. The ground state energy and the binding energy of the exciton are obtained as a function of the quantum dot size, confinement strength and the magnetic field and compared with those available in the literature. While the variational method gives the upper bound to the ground state energy, the 1/N expansion method gives the lower bound. The results obtained from the shifted 1/N expansion method are shown to match very well with those obtained from the exact diagonalization technique. The variation of the exciton size and the oscillator strength of the exciton are also studied as a function of the size of the quantum dot. The excited states of the exciton are computed using the shifted 1/N expansion method and it is suggested that a given number of stable excitonic bound states can be realized in a quantum dot by tuning the quantum dot parameters. This can open up the possibility of having quantum dot lasers using excitonic states.

  17. Formation of coffee-stain patterns at the nanoscale: The role of nanoparticle solubility and solvent evaporation rate

    Science.gov (United States)

    Zhang, Jianguo; Milzetti, Jasmin; Leroy, Frédéric; Müller-Plathe, Florian

    2017-03-01

    When droplets of nanoparticle suspension evaporate from surfaces, they leave behind a deposit of nanoparticles. The mechanism of evaporation-induced pattern formation in the deposit is studied by molecular dynamics simulations for sessile nanodroplets. The influence of the interaction between nanoparticles and liquid molecules and the influence of the evaporation rate on the final deposition pattern are addressed. When the nanoparticle-liquid interaction is weaker than the liquid-liquid interaction, an interaction-driven or evaporation-induced layer of nanoparticles appears at the liquid-vapor interface and eventually collapses onto the solid surface to form a uniform deposit independently of the evaporation rate. When the nanoparticle-liquid and liquid-liquid interactions are comparable, the nanoparticles are dispersed inside the droplet and evaporation takes place with the contact line pinned at a surface defect. In such a case, a pattern with an approximate ring-like shape is found with fast evaporation, while a more uniform distribution is observed with slower evaporation. When the liquid-nanoparticle interaction is stronger than the liquid-liquid interaction, evaporation always occurs with receding contact line. The final deposition pattern changes from volcano-like to pancake-like with decreasing evaporation rate. These findings might help to design nanoscale structures like nanopatterns or nanowires on surface through controlled solvent evaporation.

  18. Verification of Radicals Formation in Ethanol-Water Mixture Based Solution Plasma and Their Relation to the Rate of Reaction.

    Science.gov (United States)

    Sudare, Tomohito; Ueno, Tomonaga; Watthanaphanit, Anyarat; Saito, Nagahiro

    2015-12-03

    Our previous research demonstrated that using ethanol-water mixture as a liquid medium for the synthesis of gold nanoparticles by the solution plasma process (SPP) could lead to an increment of the reaction rate of ∼35.2 times faster than that in pure water. This drastic change was observed when a small amount of ethanol, that is, at an ethanol mole fraction (χethanol) of 0.089, was added in the system. After this composition, the reaction rate decreased continuously. To better understand what happens in the ethanol-water mixture-based SPP, in this study, effect of the ethanol content on the radical formation in the system was verified. We focused on detecting the magnetic resonance of electronic spins using electron spin resonance spectroscopy to determine the type and quantity of the generated radicals at each χethanol. Results indicated that ethanol radicals were generated in the ethanol-water mixtures and exhibited maximum quantity at the xethanol of 0.089. Relationship between the ethanol radical yield and the rate of reaction, along with possible mechanism responsible for the observed phenomenon, is discussed in this paper.

  19. Formation of coffee-stain patterns at the nanoscale: The role of nanoparticle solubility and solvent evaporation rate.

    Science.gov (United States)

    Zhang, Jianguo; Milzetti, Jasmin; Leroy, Frédéric; Müller-Plathe, Florian

    2017-03-21

    When droplets of nanoparticle suspension evaporate from surfaces, they leave behind a deposit of nanoparticles. The mechanism of evaporation-induced pattern formation in the deposit is studied by molecular dynamics simulations for sessile nanodroplets. The influence of the interaction between nanoparticles and liquid molecules and the influence of the evaporation rate on the final deposition pattern are addressed. When the nanoparticle-liquid interaction is weaker than the liquid-liquid interaction, an interaction-driven or evaporation-induced layer of nanoparticles appears at the liquid-vapor interface and eventually collapses onto the solid surface to form a uniform deposit independently of the evaporation rate. When the nanoparticle-liquid and liquid-liquid interactions are comparable, the nanoparticles are dispersed inside the droplet and evaporation takes place with the contact line pinned at a surface defect. In such a case, a pattern with an approximate ring-like shape is found with fast evaporation, while a more uniform distribution is observed with slower evaporation. When the liquid-nanoparticle interaction is stronger than the liquid-liquid interaction, evaporation always occurs with receding contact line. The final deposition pattern changes from volcano-like to pancake-like with decreasing evaporation rate. These findings might help to design nanoscale structures like nanopatterns or nanowires on surface through controlled solvent evaporation.

  20. MEASURING GALAXY STAR FORMATION RATES FROM INTEGRATED PHOTOMETRY: INSIGHTS FROM COLOR-MAGNITUDE DIAGRAMS OF RESOLVED STARS

    International Nuclear Information System (INIS)

    Johnson, Benjamin D.; Weisz, Daniel R.; Dalcanton, Julianne J.; Johnson, L. C.; Williams, Benjamin F.; Dale, Daniel A.; Dolphin, Andrew E.; Gil de Paz, Armando; Kennicutt, Robert C. Jr.; Lee, Janice C.; Skillman, Evan D.; Boquien, Mèdèric

    2013-01-01

    We use empirical star formation histories (SFHs), measured from Hubble-Space-Telescope-based resolved star color-magnitude diagrams, as input into population synthesis codes to model the broadband spectral energy distributions (SEDs) of 50 nearby dwarf galaxies (6.5 * /M ☉ < 8.5, with metallicities ∼10% solar). In the presence of realistic SFHs, we compare the modeled and observed SEDs from the ultraviolet (UV) through near-infrared and assess the reliability of widely used UV-based star formation rate (SFR) indicators. In the FUV through i bands, we find that the observed and modeled SEDs are in excellent agreement. In the Spitzer 3.6 μm and 4.5 μm bands, we find that modeled SEDs systematically overpredict observed luminosities by up to ∼0.2 dex, depending on treatment of the TP-AGB stars in the synthesis models. We assess the reliability of UV luminosity as a SFR indicator, in light of independently constrained SFHs. We find that fluctuations in the SFHs alone can cause factor of ∼2 variations in the UV luminosities relative to the assumption of a constant SFH over the past 100 Myr. These variations are not strongly correlated with UV-optical colors, implying that correcting UV-based SFRs for the effects of realistic SFHs is difficult using only the broadband SED. Additionally, for this diverse sample of galaxies, we find that stars older than 100 Myr can contribute from <5%-100% of the present day UV luminosity, highlighting the challenges in defining a characteristic star formation timescale associated with UV emission. We do find a relationship between UV emission timescale and broadband UV-optical color, though it is different than predictions based on exponentially declining SFH models. Our findings have significant implications for the comparison of UV-based SFRs across low-metallicity populations with diverse SFHs.

  1. MEASURING GALAXY STAR FORMATION RATES FROM INTEGRATED PHOTOMETRY: INSIGHTS FROM COLOR-MAGNITUDE DIAGRAMS OF RESOLVED STARS

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, Benjamin D. [Institute d' Astrophysique de Paris, CNRS, UPMC, 98bis Bd Arago, F-75014 Paris (France); Weisz, Daniel R.; Dalcanton, Julianne J.; Johnson, L. C.; Williams, Benjamin F. [Department of Astronomy, Box 351580, University of Washington, Seattle, WA 98195 (United States); Dale, Daniel A. [Department of Physics and Astronomy, University of Wyoming, Laramie, WY 82071 (United States); Dolphin, Andrew E. [Raytheon, 1151 E. Hermans Road, Tucson, AZ 85756 (United States); Gil de Paz, Armando [CEI Campus Moncloa, UCM-UPM, Departamento de Astrofisica y CC. de la Atmosfera, Facultad de CC. Fisicas, Universidad Complutense de Madrid, Avda. Complutense s/n, E-28040 Madrid (Spain); Kennicutt, Robert C. Jr. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 0HA (United Kingdom); Lee, Janice C. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Skillman, Evan D. [Department of Astronomy, University of Minnesota, 116 Church Street SE, Minneapolis, MN 55455 (United States); Boquien, Mederic [Marseille Universite, CNRS, LAM (Laboratoire d' Astrophysique de Marseille) UMR 7326, F-13388 Marseille (France)

    2013-07-20

    We use empirical star formation histories (SFHs), measured from Hubble-Space-Telescope-based resolved star color-magnitude diagrams, as input into population synthesis codes to model the broadband spectral energy distributions (SEDs) of 50 nearby dwarf galaxies (6.5 < log M{sub *}/M{sub Sun} < 8.5, with metallicities {approx}10% solar). In the presence of realistic SFHs, we compare the modeled and observed SEDs from the ultraviolet (UV) through near-infrared and assess the reliability of widely used UV-based star formation rate (SFR) indicators. In the FUV through i bands, we find that the observed and modeled SEDs are in excellent agreement. In the Spitzer 3.6 {mu}m and 4.5 {mu}m bands, we find that modeled SEDs systematically overpredict observed luminosities by up to {approx}0.2 dex, depending on treatment of the TP-AGB stars in the synthesis models. We assess the reliability of UV luminosity as a SFR indicator, in light of independently constrained SFHs. We find that fluctuations in the SFHs alone can cause factor of {approx}2 variations in the UV luminosities relative to the assumption of a constant SFH over the past 100 Myr. These variations are not strongly correlated with UV-optical colors, implying that correcting UV-based SFRs for the effects of realistic SFHs is difficult using only the broadband SED. Additionally, for this diverse sample of galaxies, we find that stars older than 100 Myr can contribute from <5%-100% of the present day UV luminosity, highlighting the challenges in defining a characteristic star formation timescale associated with UV emission. We do find a relationship between UV emission timescale and broadband UV-optical color, though it is different than predictions based on exponentially declining SFH models. Our findings have significant implications for the comparison of UV-based SFRs across low-metallicity populations with diverse SFHs.

  2. Effect of game format on heart rate, activity profile, and player involvement in elite and recreational youth players.

    Science.gov (United States)

    Randers, M B; Andersen, T B; Rasmussen, L S; Larsen, M N; Krustrup, P

    2014-08-01

    The purpose of this study was to evaluate activity profile, aerobic load, and player involvement in two game formats of recreational and elite youth football for two age groups. A total of 152 youth players participated, with 45 U10 players playing 5v5 and 8v8 games, and 41 U13 players playing 8v8 and 11v11 (20 min) games. Activity profile, heart rate (HR), and technical actions were measured during all games using 10 Hz GPS, video filming, and HR monitors. For U10, no difference was found in total distance covered (1754 ± 237 vs 1771 ± 314 m, P = 0.650, d = 0.06), whereas mean HR (174 ± 10 vs 168 ± 12 bpm, P = 0.001, d = 0.59) and number of technical actions (65.1 ± 24.0 vs 36.9 ± 20.4, P    0.001, d = 1.27) were higher in 5v5 than in 8v8. For U13, lower total distance covered (1821 ± 325 vs 2038 ± 328 m, P game format. Playing with fewer players on smaller pitches results in minor changes to the physical loading but elevates the technical involvement of youth players both at elite level and recreational level. © 2014 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  3. Local anti-correlation between star-formation rate and gas-phase metallicity in disk galaxies

    Science.gov (United States)

    Sánchez Almeida, J.; Caon, N.; Muñoz-Tuñón, C.; Filho, M.; Cerviño, M.

    2018-02-01

    Using a representative sample of 14 star-forming dwarf galaxies in the local Universe, we show the existence of a spaxel-to-spaxel anti-correlation between the index N2 ≡ log ([NII]λ6583/Hα) and the Hα flux. These two quantities are commonly employed as proxies for gas-phase metallicity and star formation rate (SFR), respectively. Thus, the observed N2 to Hα relation may reflect the existence of an anti-correlation between the metallicity of the gas forming stars and the SFR it induces. Such an anti-correlation is to be expected if variable external metal-poor gas fuels the star-formation process. Alternatively, it can result from the contamination of the star-forming gas by stellar winds and SNe, provided that intense outflows drive most of the metals out of the star-forming regions. We also explore the possibility that the observed anti-correlation is due to variations in the physical conditions of the emitting gas, other than metallicity. Using alternative methods to compute metallicity, as well as previous observations of HII regions and photoionization models, we conclude that this possibility is unlikely. The radial gradient of metallicity characterizing disk galaxies does not produce the correlation either.

  4. NON-EQUILIBRIUM H{sub 2} FORMATION IN THE EARLY UNIVERSE: ENERGY EXCHANGES, RATE COEFFICIENTS, AND SPECTRAL DISTORTIONS

    Energy Technology Data Exchange (ETDEWEB)

    Coppola, C. M.; Longo, S. [Dipartimento di Chimica, Universita degli Studi di Bari, Via Orabona 4, I-70126 Bari (Italy); D' Introno, R. [Dipartimento di Fisica, Universita degli Studi di Bari, Via Amendola 173, I-70126 Bari (Italy); Galli, D. [INAF-Osservatorio Astrofisico di Arcetri, Largo E. Fermi 5, I-50125 Firenze (Italy); Tennyson, J., E-mail: carla.coppola@chimica.uniba.it [Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom)

    2012-03-01

    Energy exchange processes play a crucial role in the early universe, affecting the thermal balance and the dynamical evolution of the primordial gas. In the present work we focus on the consequences of a non-thermal distribution of the level populations of H{sub 2}: first, we determine the excitation temperatures of vibrational transitions and the non-equilibrium heat transfer; second, we compare the modifications to chemical reaction rate coefficients with respect to the values obtained assuming local thermodynamic equilibrium; and third, we compute the spectral distortions to the cosmic background radiation generated by the formation of H{sub 2} in vibrationally excited levels. We conclude that non-equilibrium processes cannot be ignored in cosmological simulations of the evolution of baryons, although their observational signatures remain below current limits of detection. New fits to the equilibrium and non-equilibrium heat transfer functions are provided.

  5. 3D-HST emission line galaxies at z ∼ 2: discrepancies in the optical/UV star formation rates

    Energy Technology Data Exchange (ETDEWEB)

    Zeimann, Gregory R.; Ciardullo, Robin; Gebhardt, Henry; Gronwall, Caryl; Schneider, Donald P.; Hagen, Alex; Bridge, Joanna S.; Trump, Jonathan R. [Department of Astronomy and Astrophysics, The Pennsylvania State University, University Park, PA 16802 (United States); Feldmeier, John [Department of Physics and Astronomy, Youngstown State University, Youngstown, OH 44555 (United States)

    2014-08-01

    We use Hubble Space Telescope near-IR grism spectroscopy to examine the Hβ line strengths of 260 star-forming galaxies in the redshift range 1.90 < z < 2.35. We show that at these epochs, the Hβ star formation rate (SFR) is a factor of ∼1.8 higher than what would be expected from the systems' rest-frame UV flux density, suggesting a shift in the standard conversion between these quantities and SFR. We demonstrate that at least part of this shift can be attributed to metallicity, as Hβ is more enhanced in systems with lower oxygen abundance. This offset must be considered when measuring the SFR history of the universe. We also show that the relation between stellar and nebular extinction in our z ∼ 2 sample is consistent with that observed in the local universe.

  6. Exciton self-trapping in bulk polyethylene

    International Nuclear Information System (INIS)

    Ceresoli, D; Righi, M C; Tosatti, E; Scandolo, S; Santoro, G; Serra, S

    2005-01-01

    We studied the behaviour of an injected electron-hole pair in crystalline polyethylene theoretically. Time-dependent adiabatic evolution by ab initio molecular dynamics simulations show that the pair will become self-trapped in the perfect crystal, with a trapping energy of about 0.38 eV, with formation of a pair of trans-gauche conformational defects, three C 2 H 4 units apart on the same chain. The electron is confined in the interchain pocket created by a local, 120 0 rotation of the chain between the two defects, while the hole resides on the chain and is much less bound. Despite the large energy stored in the trapped excitation, there does not appear to be a direct non-radiative channel for electron-hole recombination. This suggests that intrinsic self-trapping of electron-hole pairs inside the ideal quasi-crystalline fraction of polyethylene might not be directly relevant for electrical damage in high-voltage cables

  7. Appropriateness of a load-management agreement as the rate format for customer thermal storage: why a closeout sale on off-peak electricity should be adopted

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, S.H.

    1980-03-01

    This report demonstrates why a load-management agreement is the best rate format for customer thermal energy storage (TES) from electricity. The first section presents the basic operating and cost characteristics of TES systems as well as potential problems that affect rate setting. Then, the criteria for choosing a rate structure are put forth, and the various rate formats available are analyzed considering the above information. Finally, the means of achieving the maximum social benefits using a load-management agreement are explored.

  8. Polarons and excitons in insulators: insight from computer simulations

    Science.gov (United States)

    Shluger, Alexander

    2010-03-01

    Localization of electrons and holes as well as excitons in insulators is a ubiquitous phenomenon which controls carrier mobility, luminescence and radiation damage of many materials. When such localization takes place in a perfect lattice it is called self-trapping, however in many cases it is facilitated by perturbation induced by intrinsic defects and impurities. Whatever the mechanism, it is hard to prove experimentally and especially theoretically. I will first review briefly the established models of self-trapped polarons and excitons (STE) in alkali halides and cubic oxides and will demonstrate how they are linked to the mechanisms of photo-induced desorption of these materials [1]. I will then discuss the results of our modeling, which extend these models further to more complex oxides forming so called electrides -- materials where electrons serve as anions [2], and to a qualitatively new type of electron trapping at grain boundaries in polycrystalline materials with negative electron affinity [3]. Combining periodic and embedded cluster methods we can explain and sometimes predict the properties of polarons and excitons in a range of insulators, such as amorphous SiO2 [4], and polycrystalline HfO2 [5] and HfSiO4. I will discuss the applicability of different techniques to studying localization problems in insulators and will compare the predictions of periodic plane wave and embedded cluster DFT calculations. [4pt] [1] W. P. Hess, et al. J. Phys. Chem. B, 109, 19563 (2005) [0pt] [2] P. V. Sushko et al. J. Amer. Chem. Soc., 129, 942 (2007) [0pt] [3] K. P. McKenna and A. L. Shluger, Nature Materials, 7, 859 (2008) [0pt] [4] A. V. Kimmel, et al. J. Non-Cryst. Sol., 353, 599 (2007) [0pt] [5] D. Munoz Ramo, et al. Phys. Rev. Lett. 99, 155504 (2007)

  9. Preequilibrium decay in the exciton model for nuclear potential with a finite depth

    International Nuclear Information System (INIS)

    Bogila, Ye.A.; Kolomiets, V.M.; Sanzhur, A.I.; Shlomo, S.

    1995-01-01

    The spectra of preequilibrium particles, taking into account the energy dependence of the single-particle level density, are calculated using the particle-hole (exciton) level density. We demonstrate the significant effect of the finite depth of the potential well (continuum effect) on partial emission spectra for configurations with a small exciton number

  10. Radiation effects from first principles : the role of excitons in electronic-excited processes.

    Energy Technology Data Exchange (ETDEWEB)

    Wong, Bryan Matthew

    2009-09-01

    Electron-hole pairs, or excitons, are created within materials upon optical excitation or irradiation with X-rays/charged particles. The ability to control and predict the role of excitons in these energetically-induced processes would have a tremendous impact on understanding the effects of radiation on materials. In this report, the excitonic effects in large cycloparaphenylene carbon structures are investigated using various first-principles methods. These structures are particularly interesting since they allow a study of size-scaling properties of excitons in a prototypical semi-conducting material. In order to understand these properties, electron-hole transition density matrices and exciton binding energies were analyzed as a function of size. The transition density matrices allow a global view of electronic coherence during an electronic excitation, and the exciton binding energies give a quantitative measure of electron-hole interaction energies in these structures. Based on overall trends in exciton binding energies and their spatial delocalization, we find that excitonic effects play a vital role in understanding the unique photoinduced dynamics in these systems.

  11. Magneto-optical quantum interferences in a system of spinor excitons

    Science.gov (United States)

    Kuan, Wen-Hsuan; Gudmundsson, Vidar

    2018-04-01

    In this work we investigate magneto-optical properties of two-dimensional semiconductor quantum-ring excitons with Rashba and Dresselhaus spin-orbit interactions threaded by a magnetic flux perpendicular to the plane of the ring. By calculating the excitonic Aharonov-Bohm spectrum, we study the Coulomb and spin-orbit effects on the Aharonov-Bohm features. From the light-matter interactions of the excitons, we find that for scalar excitons, there are open channels for spontaneous recombination resulting in a bright photoluminescence spectrum, whereas the forbidden recombination of dipolar excitons results in a dark photoluminescence spectrum. We investigate the generation of persistent charge and spin currents. The exploration of spin orientations manifests that by adjusting the strength of the spin-orbit interactions, the exciton can be constructed as a squeezed complex with specific spin polarization. Moreover, a coherently moving dipolar exciton acquires a nontrivial dual Aharonov-Casher phase, creating the possibility to generate persistent dipole currents and spin dipole currents. Our study reveals that in the presence of certain spin-orbit generated fields, the manipulation of the magnetic field provides a potential application for quantum-ring spinor excitons to be utilized in nano-scaled magneto-optical switches.

  12. The dynamical frustration of interlayer excitons delocalizing in bilayer quantum antiferromagnets

    NARCIS (Netherlands)

    Rademaker, L.; Wu, K.; Hilgenkamp, H.; Zaanen, J.

    2012-01-01

    Using the self-consistent Born approximation we study the delocalization of interlayer excitons in the bilayer Heisenberg quantum antiferromagnet. Under realistic conditions we find that the coupling between the exciton motion and the spin system is strongly enhanced as compared to the case of a

  13. Ultrafast dynamics of confined and localised excitons and biexcitons in low-dimensional semiconductors

    DEFF Research Database (Denmark)

    Hvam, Jørn Märcher; Langbein, Wolfgang; Borri, Paola

    1999-01-01

    Coherent optical spectroscopy in the form of nonlinear transient four-wave mixing (TFWM) and linear resonant Rayleigh scattering (RRS) has been applied to investigate the exciton dynamics of low-dimensional semiconductor heterostructures. The dephasing times of excitons are determined from...

  14. Observation of Frenkel and charge transfer excitons in pentacene single crystals using spectroscopic generalized ellipsometry

    NARCIS (Netherlands)

    Qi, Dongchen; Su, Haibin; Bastjan, M.; Jurchescu, O. D.; Palstra, T. M.; Wee, Andrew T. S.; Ruebhausen, M.; Rusydi, A.; Rübhausen, M.

    2013-01-01

    We report on the emerging and admixture of Frenkel and charge transfer (CT) excitons near the absorption onset in pentacene single crystals. Using high energy-resolution spectroscopic generalized ellipsometry with in-plane polarization dependence, the excitonic nature of three lowest lying

  15. Optical nonlinearity due to nonbosonity of Wannier-Mott excitons in highly excited semiconductors

    International Nuclear Information System (INIS)

    Nguyen Ba An; Hoang Xuan Nguyen

    1990-01-01

    Shown that the nonbosonity of Wannier-Mott excitons leads to the energy level blue shift which might result in optical bistability. The dependences of the complex dielectric function on both exciton density and pump laser intensity are considered and numerically evaluated for CdS. (author). 10 refs., 5 figs

  16. Direct measurement of the triplet exciton diffusion length in organic semiconductors

    NARCIS (Netherlands)

    Mikhnenko, O.V.; Ruiter, R.; Blom, P.W.M.; Loi, M.A.

    2012-01-01

    We present a new method to measure the triplet exciton diffusion length in organic semiconductors. N,N′-di-[(1-naphthyl)-N,N′-diphenyl]-1,1′-biphenyl)-4,4′-diamine (NPD) has been used as a model system. Triplet excitons are injected into a thin film of NPD by a phosphorescent thin film, which is

  17. Thermalization of Hot Free Excitons in ZnSe-Based Quantum Wells

    DEFF Research Database (Denmark)

    Hoffmann, J.; Umlauff, M.; Kalt, H.

    1997-01-01

    Thermalization of hot-exciton populations in ZnSe quantum wells occurs on a time scale of 100 ps. Strong exciton-phonon coupling in II-VI semiconductors leads to a direct access to the thermalization dynamics via time-resolved spectroscopy of phonon-assisted luminescence. The experimental spectra...

  18. Real-Time Tracking of Singlet Exciton Diffusion in Organic Semiconductors

    NARCIS (Netherlands)

    Kozlov, Oleg V.; de Haan, Foppe; Kerner, Ross A.; Rand, Barry P.; Cheyns, David; Pshenichnikov, Maxim S.

    2016-01-01

    Exciton diffusion in organic materials provides the operational basis for functioning of such devices as organic solar cells and light-emitting diodes. Here we track the exciton diffusion process in organic semiconductors in real time with a novel technique based on femtosecond photoinduced

  19. THE ALFALFA H α SURVEY. I. PROJECT DESCRIPTION AND THE LOCAL STAR FORMATION RATE DENSITY FROM THE FALL SAMPLE

    International Nuclear Information System (INIS)

    Sistine, Angela Van; Salzer, John J.; Janowiecki, Steven; Sugden, Arthur; Giovanelli, Riccardo; Haynes, Martha P.; Jaskot, Anne E.; Wilcots, Eric M.

    2016-01-01

    The ALFALFA H α survey utilizes a large sample of H i-selected galaxies from the ALFALFA survey to study star formation (SF) in the local universe. ALFALFA H α contains 1555 galaxies with distances between ∼20 and ∼100 Mpc. We have obtained continuum-subtracted narrowband H α images and broadband R images for each galaxy, creating one of the largest homogeneous sets of H α images ever assembled. Our procedures were designed to minimize the uncertainties related to the calculation of the local SF rate density (SFRD). The galaxy sample we constructed is as close to volume-limited as possible, is a robust statistical sample, and spans a wide range of galaxy environments. In this paper, we discuss the properties of our Fall sample of 565 galaxies, our procedure for deriving individual galaxy SF rates, and our method for calculating the local SFRD. We present a preliminary value of log(SFRD[ M _⊙ yr"−"1 Mpc"−"3]) = −1.747 ± 0.018 (random) ±0.05 (systematic) based on the 565 galaxies in our Fall sub-sample. Compared to the weighted average of SFRD values around z ≈ 2, our local value indicates a drop in the global SFRD of a factor of 10.2 over that lookback time.

  20. THE ALFALFA H α SURVEY. I. PROJECT DESCRIPTION AND THE LOCAL STAR FORMATION RATE DENSITY FROM THE FALL SAMPLE

    Energy Technology Data Exchange (ETDEWEB)

    Sistine, Angela Van [Department of Physics, University of Wisconsin-Milwaukee, Milwaukee, WI 53211 (United States); Salzer, John J.; Janowiecki, Steven [Department of Astronomy, Indiana University, Bloomington, IN 47405 (United States); Sugden, Arthur [Department of Endocrinology, Beth Israel Deaconess Medical Center, Harvard Medical School, Boston, MA 02115 (United States); Giovanelli, Riccardo; Haynes, Martha P. [Center for Astrophysics and Planetary Science, Cornell University, Ithaca, NY 14853 (United States); Jaskot, Anne E. [Department of Astronomy, Smith College, Northampton, MA 01063 (United States); Wilcots, Eric M. [Department of Astronomy, University of Wisconsin-Madison, Madison, WI 53706 (United States)

    2016-06-10

    The ALFALFA H α survey utilizes a large sample of H i-selected galaxies from the ALFALFA survey to study star formation (SF) in the local universe. ALFALFA H α contains 1555 galaxies with distances between ∼20 and ∼100 Mpc. We have obtained continuum-subtracted narrowband H α images and broadband R images for each galaxy, creating one of the largest homogeneous sets of H α images ever assembled. Our procedures were designed to minimize the uncertainties related to the calculation of the local SF rate density (SFRD). The galaxy sample we constructed is as close to volume-limited as possible, is a robust statistical sample, and spans a wide range of galaxy environments. In this paper, we discuss the properties of our Fall sample of 565 galaxies, our procedure for deriving individual galaxy SF rates, and our method for calculating the local SFRD. We present a preliminary value of log(SFRD[ M {sub ⊙} yr{sup −1} Mpc{sup −3}]) = −1.747 ± 0.018 (random) ±0.05 (systematic) based on the 565 galaxies in our Fall sub-sample. Compared to the weighted average of SFRD values around z ≈ 2, our local value indicates a drop in the global SFRD of a factor of 10.2 over that lookback time.

  1. The ALFALFA Hα Survey. I. Project Description and The Local Star-formation Rate Density from the Fall Sample

    Science.gov (United States)

    Van Sistine, Angela; Salzer, John J.; Sugden, Arthur; Giovanelli, Riccardo; Haynes, Martha P.; Janowiecki, Steven; Jaskot, Anne E.; Wilcots, Eric M.

    2016-06-01

    The ALFALFA Hα survey utilizes a large sample of H I-selected galaxies from the ALFALFA survey to study star formation (SF) in the local universe. ALFALFA Hα contains 1555 galaxies with distances between ˜20 and ˜100 Mpc. We have obtained continuum-subtracted narrowband Hα images and broadband R images for each galaxy, creating one of the largest homogeneous sets of Hα images ever assembled. Our procedures were designed to minimize the uncertainties related to the calculation of the local SF rate density (SFRD). The galaxy sample we constructed is as close to volume-limited as possible, is a robust statistical sample, and spans a wide range of galaxy environments. In this paper, we discuss the properties of our Fall sample of 565 galaxies, our procedure for deriving individual galaxy SF rates, and our method for calculating the local SFRD. We present a preliminary value of log(SFRD[M ⊙ yr-1 Mpc-3]) = -1.747 ± 0.018 (random) ±0.05 (systematic) based on the 565 galaxies in our Fall sub-sample. Compared to the weighted average of SFRD values around z ≈ 2, our local value indicates a drop in the global SFRD of a factor of 10.2 over that lookback time.

  2. Relaxation process of self-trapping exciton in C60

    International Nuclear Information System (INIS)

    Sun, X.; Zhang, G.P.; Ma, Y.S.; Fu, R.L.

    1995-09-01

    When C 60 is photoexcited, a self-trapping exciton (STE) is formed. The bond structure is distorted while the states A 1u and A 2u are pulled into the energy gap from HOMO and LUMO respectively. A dynamical scheme is employed to simulate the relaxation of STE. The evolutions of both bond structure and electronic states show that the relaxation time for STE is about 100 fs. It is noticed that this relaxation time is much shorter than that of the charge transfer in C 60 , and the origin for this big difference is discussed. (author). 13 refs, 4 figs

  3. Exciton and Hole-Transfer Dynamics in Polymer: Fullerene Blends

    Directory of Open Access Journals (Sweden)

    van Loosdrecht P. H. M.

    2013-03-01

    Full Text Available Ultrafast hole transfer dynamics from fullerene derivative to polymer in bulk heterojunction blends are studied with visible-pump - IR-probe spectroscopy. The hole transfer process is found to occur in 50/300 fs next to the interface, while a longer 15-ps time is attributed to exciton diffusion towards interface in PC71BM domains. High polaron generation efficiency in P3HT blends indicates excellent intercalation between the polymer and the fullerene even at highest PC71BM concentration thereby yielding a valuable information on the blend morphology.

  4. Defect production at exciton decay in ionic crystals

    International Nuclear Information System (INIS)

    Lushchik, Ch.B.

    1984-01-01

    On the example of alkali halide crystals experimentally detected phenomenon of structural point defect production in wide-gap nonmetallic solids at low-temperature radiationless decay of self-localizing excitons and recombination of electrons with self-localized holes is considered. Factors promoting radiationless transformation of electron excitations to not small oscillations of many atoms (heat release), but to separate ion large shifts, that determine one of the most important mechanisms of radiation instability of solids, used, in particular, for data recording, are discussed

  5. InAs Band-Edge Exciton Fine Structure

    Science.gov (United States)

    2015-07-29

    with a 100x near- infrared corrected long working distance objective (Mi- tutoyo, Plan Apo NIR), using a 640 nm pulsed diode laser for excitation...Fernée, M. J.; Louyer, Y.; Tamarat, P.; Lounis, B. Comment on “Spin-Flip Limited Exciton Dephasing in CdSe/ ZnS Colloidal Quantum Dots”. Phys. Rev. Lett... Spectroscopy of single nanocrystals. Chem. Soc. Rev. 2014, 43, 1311–1337. [10] Bruns, O. T.; Bischof, T. S.; Harris, D. K.; Shi, Y.; Riedemann, L.; Reiberger

  6. Excitonic Coherence in Semiconductor Nanostructures Measured by Speckle Analysis

    DEFF Research Database (Denmark)

    Langbein, Wolfgang; Hvam, Jørn Märcher

    1999-01-01

    A new method to measure the time-dependent coherence of optical excitations in solids is presented, in which the coherence degree of light emission is deduced from its intensity fluctuations over the emission directions (speckles). With this method the decays of intensity and coherence...... are determined separately, thus distinguishing lifetime from pure dephasing. In particular, the secondary emission of excitons in semiconductor quantum wells is investigated. Here, the combination of static disorder and inelastic scattering leads to a partially coherent emission. The temperature dependence...

  7. Spin-exciton interaction and related micro-photoluminescence spectra of ZnSe:Mn DMS nanoribbon.

    Science.gov (United States)

    Hou, Lipeng; Zhou, Weichang; Zou, Bingsuo; Zhang, Yu; Han, Junbo; Yang, Xinxin; Gong, Zhihong; Li, Jingbo; Xie, Sishen; Shi, Li-Jie

    2017-03-10

    For their spintronic applications the magnetic and optical properties of diluted magnetic semiconductors (DMS) have been studied widely. However, the exact relationships between the magnetic interactions and optical emission behaviors in DMS are not well understood yet due to their complicated microstructural and compositional characters from different growth and preparation techniques. Manganese (Mn) doped ZnSe nanoribbons with high quality were obtained by using the chemical vapor deposition (CVD) method. Successful Mn ion doping in a single ZnSe nanoribbon was identified by elemental energy-dispersive x-ray spectroscopy mapping and micro-photoluminescence (PL) mapping of intrinsic d-d optical transition at 580 nm, i.e. the transition of 4 T 1 ( 4 G) →  6 A 1 ( 6 s),. Besides the d-d transition PL peak at 580 nm, two other PL peaks related to Mn ion aggregates in the ZnSe lattice were detected at 664 nm and 530 nm, which were assigned to the d-d transitions from the Mn 2+ -Mn 2+ pairs with ferromagnetic (FM) coupling and antiferromagnetic (AFM) coupling, respectively. Moreover, AFM pair formation goes along with strong coupling with acoustic phonon or structural defects. These arguments were supported by temperature-dependent PL spectra, power-dependent PL lifetimes, and first-principle calculations. Due to the ferromagnetic pair existence, an exciton magnetic polaron (EMP) is formed and emits at 460 nm. Defect existence favors the AFM pair, which also can account for its giant enhancement of spin-orbital coupling and the spin Hall effect observed in PRL 97, 126603(2006) and PRL 96, 196404(2006). These emission results of DMS reflect their relation to local sp-d hybridization, spin-spin magnetic coupling, exciton-spin or phonon interactions covering structural relaxations. This kind of material can be used to study the exciton-spin interaction and may find applications in spin-related photonic devices besides spintronics.

  8. Orientation-Dependent Exciton-Plasmon Coupling in Embedded Organic/Metal Nanowire Heterostructures.

    Science.gov (United States)

    Li, Yong Jun; Hong, Yan; Peng, Qian; Yao, Jiannian; Zhao, Yong Sheng

    2017-10-24

    The excitation of surface plasmons by optical emitters based on exciton-plasmon coupling is important for plasmonic devices with active optical properties. It has been theoretically demonstrated that the orientation of exciton dipole can significantly influence the coupling strength, yet systematic study of the coupling process in nanostructures is still hindered by the lack of proper material systems. In this work, we have experimentally investigated the orientation-dependent exciton-plasmon coupling in a rationally designed organic/metal nanowire heterostructure system. The heterostructures were prepared by inserting silver nanowires into crystalline organic waveguides during the self-assembly of dye molecules. Structures with different exciton orientations exhibited varying coupling efficiencies. The near-field exciton-plasmon coupling facilitates the design of nanophotonic devices based on the directional surface plasmon polariton propagations.

  9. Excitons in semiconducting quantum filaments of CdS and CdSe with dielectric barriers

    CERN Document Server

    Dneprovskij, V S; Shalygina, O A; Lyaskovskij, V L; Mulyarov, E A; Gavrilov, S A; Masumoto, I

    2002-01-01

    The peculiarities of the luminescence spectra obtained by different polarization and intensity of the pumping excitation and luminescence kinetics of the CdS and CdSe nanocrystals are explained by the exciton transitions in the semiconducting quantum threads with dielectric barriers. The exciton transition energies correspond to the calculated ones with an account of both their dimensional quantization and the effect of the excitons dielectric intensification. It is shown that the excitons transition energies do not change by the change in the quantum threads diameter within the wide range, while the increase in the one-dimensional forbidden zone width of quantum thread by the decrease in its diameter is compensated through the decrease in the excitons binding energy

  10. Stark effect of excitons in corrugated lateral surface superlattices: effect of centre-of-mass quantization

    International Nuclear Information System (INIS)

    Hong Sun

    1998-11-01

    The quantum confined Stark effect (QCSE) of excitons in GaAs/AlAs corrugated lateral surface superlattices (CLSSLs) is calculated. Blue and red shifts in the exciton energies are predicted for the heavy- and light-excitons in the CLSSLs, respectively, comparing with those in the unmodulated quantum well due to the different effective hole masses in the parallel direction. Sensitive dependence of the QCSE on the hole effective mass in the parallel direction is expected because of the ''centre-of-mass'' quantization (CMQ) induced by the periodic corrugated interfaces of the CLSSLs. The effect of the CMQ on the exciton mini-bands and the localization of the excitons in the CLSSLs is discussed. (author)

  11. Subsurface electric field effect on excitonic reflection spectra of CdSe monocrystals

    International Nuclear Information System (INIS)

    Batyrev, A.S.; Novikov, B.V.; Cherednichenko, A.E.

    1981-01-01

    Changes in exciton reflection spectra of CdSe monocrystals under bombardment with 2-3.5 keV electrons at T=4.2 K have been experimentally investigated. Under the same conditions measured was a relative value of surface photo e.m.f. depending on a dose of electron bombardment. A structure, resulted from the Stark well for excitons near surface and bound state in it - mechanical surface exciton, has been detected in nonirradiated crystals. Correlation between changes in the value of photo e.m.f. and the exciton reflection spectrum contour in the process of irradiation has been traced. It is shown that a number of peculiarities in experimental exciton reflection spectra is not explained with the model of the Thomas and Hopfield ''dead layer''. The Kiselev model is used to explain the results [ru

  12. A protocol for adult somatic cell nuclear transfer in medaka fish (Oryzias latipes) with a high rate of viable clone formation.

    Science.gov (United States)

    Bubenshchikova, Ekaterina; Kaftanovskaya, Elena; Adachi, Tomoko; Hashimoto, Hisashi; Kinoshita, Masato; Wakamatsu, Yuko

    2013-12-01

    Previously, we successfully generated fully grown, cloned medaka (the Japanese rice fish, Oryzias latipes) using donor nuclei from primary culture cells of adult caudal fin tissue and nonenucleated recipient eggs that were heat shock-treated to induce diploidization of the nuclei. However, the mechanism of clone formation using this method is unknown, and the rate of adult clone formation is not high enough for studies in basic and applied sciences. To gain insight into the mechanism and increase the success rate of this method of clone formation, we tested two distinct nuclear transfer protocols. In one protocol, the timing of transfer of donor nuclei was changed, and in the other, the size of the donor cells was changed; each protocol was based on our original methodology. Ultimately, we obtained an unexpectedly high rate of adult clone formation using the protocol that differed with respect to the timing of donor nuclei transfer. Specifically, 17% of the transplants that developed to the blastula stage ultimately developed into adult clones. The success rate with this method was 13 times higher than that obtained using the original method. Analyses focusing on the reasons for this high success rate of clone formation will help to elucidate the mechanism of clone formation that occurs with this method.

  13. Using formative evaluation in an implementation project to increase vaccination rates in high-risk veterans: QUERI Series

    Directory of Open Access Journals (Sweden)

    Legro Marcia W

    2008-04-01

    Full Text Available Abstract Background Implementation of research into practice in health care systems is a challenging and often unsuccessful endeavor. The United States Department of Veterans Affairs (VA Quality Enhancement Research Initiative (QUERI research teams include formative evaluations (FE in their action-oriented VA implementation projects to identify critical information about the processes of implementation that can guide adjustments to project activities, in order to better meet project goals. This article describes the development and use of FE in an action-oriented implementation research project. Methods This two-year action-oriented implementation research project was conducted at 23 VA Spinal Cord Injury (SCI Centers, and targeted patients, staff and the system of care, such as administration and information technology. Data for FE were collected by electronic and paper surveys, semi-structured and open-ended interviews, notes during conference calls, and exchange of e-mail messages. Specific questions were developed for each intervention (designed to improve vaccination rates for influenza in veterans with spinal cord injury and disorder; informants were selected for their knowledge of interventions and their use in SCI Centers. Results Data from FE were compiled separately for each intervention to describe barriers to progress and guide adjustments to implementation activities. These data addressed the processes of implementing the interventions, problem-solving activities and the status of interventions at SCI Centers. Conclusion Formative evaluations provided the project team with a broad view of the processes of implementing multi-targeted interventions as well as the evolving status of the related best practice. Using FE was useful, although the challenges of conducting FE for non-field researchers should be addressed. Work is needed to develop methods for conducting FE across multiple sites, as well as acknowledging variations in local

  14. Using formative evaluation in an implementation project to increase vaccination rates in high-risk veterans: QUERI Series.

    Science.gov (United States)

    Wallace, Carolyn M; Legro, Marcia W

    2008-04-22

    Implementation of research into practice in health care systems is a challenging and often unsuccessful endeavor. The United States Department of Veterans Affairs (VA) Quality Enhancement Research Initiative (QUERI) research teams include formative evaluations (FE) in their action-oriented VA implementation projects to identify critical information about the processes of implementation that can guide adjustments to project activities, in order to better meet project goals. This article describes the development and use of FE in an action-oriented implementation research project. This two-year action-oriented implementation research project was conducted at 23 VA Spinal Cord Injury (SCI) Centers, and targeted patients, staff and the system of care, such as administration and information technology. Data for FE were collected by electronic and paper surveys, semi-structured and open-ended interviews, notes during conference calls, and exchange of e-mail messages. Specific questions were developed for each intervention (designed to improve vaccination rates for influenza in veterans with spinal cord injury and disorder); informants were selected for their knowledge of interventions and their use in SCI Centers. Data from FE were compiled separately for each intervention to describe barriers to progress and guide adjustments to implementation activities. These data addressed the processes of implementing the interventions, problem-solving activities and the status of interventions at SCI Centers. Formative evaluations provided the project team with a broad view of the processes of implementing multi-targeted interventions as well as the evolving status of the related best practice. Using FE was useful, although the challenges of conducting FE for non-field researchers should be addressed. Work is needed to develop methods for conducting FE across multiple sites, as well as acknowledging variations in local contexts that affect implementation of interventions.

  15. On the evolution of the star formation rate function of massive galaxies: constraints at 0.4 MUSIC catalogue

    Science.gov (United States)

    Fontanot, Fabio; Cristiani, Stefano; Santini, Paola; Fontana, Adriano; Grazian, Andrea; Somerville, Rachel S.

    2012-03-01

    We study the evolution of the star formation rate function (SFRF) of massive (M★ > 1010 M⊙) galaxies over the 0.4 observations included in the Great Observatories Origins Deep Survey-Multiwavelength Southern Infrared Catalog (GOODS-MUSIC) catalogue, which provides a suitable coverage of the spectral region from 0.3 to 24 ?m and either spectroscopic or photometric redshifts for each object. Individual SFRs have been obtained by combining ultraviolet and 24-?m observations, when the latter were available. For all other sources a 'spectral energy distribution (SED) fitting' SFR estimate has been considered. We then define a stellar mass limited sample, complete in the M★ > 1010 M⊙ range and determine the SFRF using the 1/Vmax algorithm. We thus define simulated galaxy catalogues based on the predictions of three different state-of-the-art semi-analytical models (SAMs) of galaxy formation and evolution, and compare them with the observed SFRF. We show that the theoretical SFRFs are well described by a double power law functional form and its redshift evolution is approximated with high accuracy by a pure evolution of the typical SFR (SFR★). We find good agreement between model predictions and the high-SFR end of the SFRF, when the observational errors on the SFR are taken into account. However, the observational SFRF is characterized by a double-peaked structure, which is absent in its theoretical counterparts. At z > 1.0 the observed SFRF shows a relevant density evolution, which is not reproduced by SAMs, due to the well-known overprediction of intermediate-mass galaxies at z˜ 2. SAMs are thus able to reproduce the most intense SFR events observed in the GOODS-MUSIC sample and their redshift distribution. At the same time, the agreement at the low-SFR end is poor: all models overpredict the space density of SFR ˜ 1 M⊙ yr-1 and no model reproduces the double-peaked shape of the observational SFRF. If confirmed by deeper infrared observations, this

  16. The Star Formation Rate and Gas Surface Density Relation in the Milky Way: Implications for Extragalactic Studies

    Science.gov (United States)

    Heiderman, Amanda L.; Evans, N. J., II; Allen, L. E.; Huard, T.; Heyer, M.

    2011-01-01

    We investigate the relation between star formation rate (SFR) and gas surface densities in Galactic star forming regions using a sample of YSOs and massive clumps. Our YSO sample consists of objects located in 20 molecular clouds from the Spitzer c2d and Gould's Belt surveys. We estimate the gas surface density (Sigma_gas) from Av maps and YSO SFR surface densities (Sigma_SFR) from the number of YSOs, assuming a mean mass and lifetime. We also divide the clouds into contour levels of Av, counting only the youngest Class I and Flat SED YSOs. For a sample of massive star forming clumps, we derive SFRs from the infrared luminosity and use HCN gas maps to estimate Sigma_gas. We find that Galactic clouds lie above the extragalactic relations (e.g., Kennicutt-Schmidt Law) by factors up to 17. Cloud regions with high Sigma_gas lie above extragalactic relations up to a factor of 54 and overlap with massive clumps. We use 12CO and 13CO gas maps of the Perseus and Ophiuchus clouds to estimate Sigma_gas and compare to Sigma_gas from Av maps. We find that 13CO, underestimates the Av-based mass by factors of 4-5. 12CO may underestimate the total gas mass at Sigma_gas > 200 Msun pc^-2 by > 30%; however, this does not explain the large discrepancy between Galactic and extragalactic relations. We find evidence for a threshold of star formation (Sigma_th) at 129+-14 Msun pc^-2. At Sigma_gas > Sigma_th, the Galactic relation is linear. A possible reason for the difference between Galactic and extragalactic relations is that all the CO-emitting gas, including Sigma_gas below Sigma_th, is measured in extragalactic studies. If the Kennicutt-Schmidt relation (Sigma_SFR Sigma_gas^1.4) and a linear relation between dense gas and star formation is assumed, the fraction of dense gas (f_dense) increases as Sigma_gas^0.4. When Sigma_gas reaches 300Sigma_th, f_dense is 1.

  17. Excitonic effects in ZnO nanowires and hollow nanotubes

    Science.gov (United States)

    Willander, M.; Lozovik, Y. E.; Zhao, Q. X.; Nur, O.; Hu, Q.-H.; Klason, P.

    2007-02-01

    Energy levels and wave functions of ground and excited states of an exciton are calculated by the method of imaginary time. Energy levels as functions of radius of single and double wall nanotube are studied. Asymptotic behavior of energy levels at large and small values of the radius using perturbation theory and adiabatic approximation is considered. Spatially indirect exciton in semiconductor nanowire is also investigated. Experimental result from high quality reproducible ZnO nanowires grown by low temperature chemical engineering is presented. State of the art high brightness white light emitting diodes (HB-LEDs) are demonstrated from the grown ZnO nano-wires. The color temperature and color rendering index (CRI) of the HB-LEDs values was found to be (3250 K, 82), and (14000 K, 93), for the best LEDs, which means that the quality of light is superior to one obtained from GaN LEDs available on the market today. The role of V Zn and V ° on the emission responsible for the white light band as well as the peak position of this important wide band is thoroughly investigated in a systematic way.

  18. Exciton fine structure in CdSe nanoclusters

    International Nuclear Information System (INIS)

    Leung, K.; Pokrant, S.; Whaley, K.B.

    1998-01-01

    The fine structure in the CdSe nanocrystal absorption spectrum is computed by incorporating two-particle electron-hole interactions and spin-orbit coupling into a tight-binding model, with an expansion in electron-hole single-particle states. The exchange interaction and spin-orbit coupling give rise to dark, low-lying states that are predominantly triplet in character, as well as to a manifold of exciton states that are sensitive to the nanocrystal shape. Near the band gap, the exciton degeneracies are in qualitative agreement with the effective mass approximation (EMA). However, instead of the infinite lifetimes for dark states characteristic of the EMA, we obtain finite radiative lifetimes for the dark states. In particular, for the lowest, predominantly triplet, states we obtain radiative lifetimes of microseconds, in qualitative agreement with the experimental measured lifetimes. The resonant Stokes shifts obtained from the splitting between the lowest dark and bright states are also in good agreement with experimental values for larger crystallites. Higher-lying states exhibit significantly more complex behavior than predicted by EMA, due to extensive mixing of electron-hole pair states. copyright 1998 The American Physical Society

  19. Direct measurement of exciton valley coherence in monolayer WSe2

    KAUST Repository

    Hao, Kai

    2016-02-29

    In crystals, energy band extrema in momentum space can be identified by a valley index. The internal quantum degree of freedom associated with valley pseudospin indices can act as a useful information carrier, analogous to electronic charge or spin. Interest in valleytronics has been revived in recent years following the discovery of atomically thin materials such as graphene and transition metal dichalcogenides. However, the valley coherence time—a crucial quantity for valley pseudospin manipulation—is difficult to directly probe. In this work, we use two-dimensional coherent spectroscopy to resonantly generate and detect valley coherence of excitons (Coulomb-bound electron–hole pairs) in monolayer WSe2 (refs ,). The imposed valley coherence persists for approximately one hundred femtoseconds. We propose that the electron–hole exchange interaction provides an important decoherence mechanism in addition to exciton population recombination. This work provides critical insight into the requirements and strategies for optical manipulation of the valley pseudospin for future valleytronics applications.

  20. Symposium GC: Nanoscale Charge Transport in Excitonic Solar Cells

    Energy Technology Data Exchange (ETDEWEB)

    Bommisetty, Venkat [Univ. of South Dakota, Vermillion, SD (United States)

    2011-06-23

    This paper provides a summary only and table of contents of the sessions. Excitonic solar cells, including all-organic, hybrid organic-inorganic and dye-sensitized solar cells (DSSCs), offer strong potential for inexpensive and large-area solar energy conversion. Unlike traditional inorganic semiconductor solar cells, where all the charge generation and collection processes are well understood, these excitonic solar cells contain extremely disordered structures with complex interfaces which results in large variations in nanoscale electronic properties and has a strong influence on carrier generation, transport, dissociation and collection. Detailed understanding of these processes is important for fabrication of highly efficient solar cells. Efforts to improve efficiency are underway at a large number of research groups throughout the world focused on inorganic and organic semiconductors, photonics, photophysics, charge transport, nanoscience, ultrafast spectroscopy, photonics, semiconductor processing, device physics, device structures, interface structure etc. Rapid progress in this multidisciplinary area requires strong synergetic efforts among researchers from diverse backgrounds. Such effort can lead to novel methods for development of new materials with improved photon harvesting and interfacial treatments for improved carrier transport, process optimization to yield ordered nanoscale morphologies with well defined electronic structures.

  1. Multiple Exciton Generation in Quantum Dot Solar Cells

    Science.gov (United States)

    Semonin, O. E.

    Photovoltaics are limited in their power conversion efficiency (PCE) by very rapid relaxation of energetic carriers to the band edge. Therefore, photons from the visible and ultraviolet parts of the spectrum typically are not efficiently converted into electrical energy. One approach that can address this is multiple exciton generation (MEG), where a single photon of sufficient energy can generate multiple excited electron-hole pairs. This process has been shown to be more efficient in quantum dots than bulk semiconductors, but it has never been demonstrated in the photocurrent of a solar cell. In order to demonstrate that multiple exciton generation can address fundamental limits for conventional photovoltaics, I have developed prototype devices from colloidal PbS and PbSe quantum dot inks. I have characterized both the colloidal suspensions and films of quantum dots with the goal of understanding what properties determine the efficiency of the solar cell and of the MEG process. I have found surface chemistry effects on solar cells, photoluminescence, and MEG, and I have found some chemical treatments that lead to solar cells showing MEG. These devices show external quantum efficiency (EQE) greater than 100% for certain parts of the solar spectrum, and I extract internal quantum efficiency (IQE) consistent with previous measurements of colloidal suspensions of quantum dots. These findings are a small first step toward breaking the single junction Shockley-Queisser limit of present-day first and second generation solar cells, thus moving photovoltaic cells toward a new regime of efficiency.

  2. Excitonic processes and their contribution to non-proportionality observed in the light yield of inorganic scintillators

    International Nuclear Information System (INIS)

    Singh, J.; Koblov, A.

    2013-01-01

    Using the derived expression for the light yield in a scintillator, the influence of linear radiative and non-radiative (quenching) rates on the non-proportionality in light yield is studied. It is found that if the excitation created within the electron track initiated by a γ-photon incident on a scintillator, remains mainly excitonic, then non-proportionality can be minimized by inventing a scintillator material with linear radiative rate > 10 7 s -1 , linear quenching rate 6 s -1 and track radius ≥ 70 nm along with maintaining the rates of other non-linear processes as discovered earlier. If one can increase the linear radiative rate to 10 9 s -1 , then the non-proportionality can be eliminated at a track radius > 20 nm. (authors)

  3. HIGH STAR FORMATION RATES IN TURBULENT ATOMIC-DOMINATED GAS IN THE INTERACTING GALAXIES IC 2163 AND NGC 2207

    Energy Technology Data Exchange (ETDEWEB)

    Elmegreen, Bruce G. [IBM Research Division, T.J. Watson Research Center, 1101 Kitchawan Road, Yorktown Heights, NY 10598 (United States); Kaufman, Michele [110 Westchester Rd, Newton, MA 02458 (United States); Bournaud, Frédéric; Juneau, Stéphanie [Laboratoire AIM-Paris-Saclay, CEA/DSM-CNRS-Université Paris Diderot, Irfu/Service d’Astrophysique, CEA Saclay, Orme des Merisiers, F-91191 Gif sur Yvette (France); Elmegreen, Debra Meloy [Department of Physics and Astronomy, Vassar College, Poughkeepsie, NY 12604 (United States); Struck, Curtis [Department of Physics and Astronomy, Iowa State University, Ames, IA 50011 (United States); Brinks, Elias, E-mail: bge@us.ibm.com, E-mail: kaufmanrallis@icloud.com, E-mail: frederic.bournaud@gmail.com, E-mail: stephanie.juneau@cea.fr, E-mail: elmegreen@vassar.edu, E-mail: struck@iastate.edu, E-mail: e.brinks@herts.ac.uk [University of Hertfordshire, Centre for Astrophysics Research, College Lane, Hatfield AL10 9AB (United Kingdom)

    2016-05-20

    CO observations of the interacting galaxies IC 2163 and NGC 2207 are combined with HI, H α , and 24 μ m observations to study the star formation rate (SFR) surface density as a function of the gas surface density. More than half of the high-SFR regions are HI dominated. When compared to other galaxies, these HI-dominated regions have excess SFRs relative to their molecular gas surface densities but normal SFRs relative to their total gas surface densities. The HI-dominated regions are mostly located in the outer part of NGC 2207 where the HI velocity dispersion is high, 40–50 km s{sup −1}. We suggest that the star-forming clouds in these regions have envelopes at lower densities than normal, making them predominantly atomic, and cores at higher densities than normal because of the high turbulent Mach numbers. This is consistent with theoretical predictions of a flattening in the density probability distribution function for compressive, high Mach number turbulence.

  4. NEAR-INFRARED ADAPTIVE OPTICS IMAGING OF INFRARED LUMINOUS GALAXIES: THE BRIGHTEST CLUSTER MAGNITUDE-STAR FORMATION RATE RELATION

    International Nuclear Information System (INIS)

    Randriamanakoto, Z.; Väisänen, P.; Escala, A.; Kankare, E.; Kotilainen, J.; Mattila, S.; Ryder, S.

    2013-01-01

    We have established a relation between the brightest super star cluster (SSC) magnitude in a galaxy and the host star formation rate (SFR) for the first time in the near-infrared (NIR). The data come from a statistical sample of ∼40 luminous IR galaxies (LIRGs) and starbursts utilizing K-band adaptive optics imaging. While expanding the observed relation to longer wavelengths, less affected by extinction effects, it also pushes to higher SFRs. The relation we find, M K ∼ –2.6log SFR, is similar to that derived previously in the optical and at lower SFRs. It does not, however, fit the optical relation with a single optical to NIR color conversion, suggesting systematic extinction and/or age effects. While the relation is broadly consistent with a size-of-sample explanation, we argue physical reasons for the relation are likely as well. In particular, the scatter in the relation is smaller than expected from pure random sampling strongly suggesting physical constraints. We also derive a quantifiable relation tying together cluster-internal effects and host SFR properties to possibly explain the observed brightest SSC magnitude versus SFR dependency

  5. HIGH STAR FORMATION RATES IN TURBULENT ATOMIC-DOMINATED GAS IN THE INTERACTING GALAXIES IC 2163 AND NGC 2207

    International Nuclear Information System (INIS)

    Elmegreen, Bruce G.; Kaufman, Michele; Bournaud, Frédéric; Juneau, Stéphanie; Elmegreen, Debra Meloy; Struck, Curtis; Brinks, Elias

    2016-01-01

    CO observations of the interacting galaxies IC 2163 and NGC 2207 are combined with HI, H α , and 24 μ m observations to study the star formation rate (SFR) surface density as a function of the gas surface density. More than half of the high-SFR regions are HI dominated. When compared to other galaxies, these HI-dominated regions have excess SFRs relative to their molecular gas surface densities but normal SFRs relative to their total gas surface densities. The HI-dominated regions are mostly located in the outer part of NGC 2207 where the HI velocity dispersion is high, 40–50 km s −1 . We suggest that the star-forming clouds in these regions have envelopes at lower densities than normal, making them predominantly atomic, and cores at higher densities than normal because of the high turbulent Mach numbers. This is consistent with theoretical predictions of a flattening in the density probability distribution function for compressive, high Mach number turbulence.

  6. Hypoxia enhances proliferation through increase of colony formation rate with chondrogenic potential in primary synovial mesenchymal stem cells.

    Science.gov (United States)

    Ohara, Toshiyuki; Muneta, Takeshi; Nakagawa, Yusuke; Matsukura, Yu; Ichinose, Shizuko; Koga, Hideyuki; Tsuji, Kunikazu; Sekiya, Ichiro

    2016-01-01

    Synovial mesenchymal stem cells (MSCs) are an attractive cell source for cartilage and meniscus regeneration. Use of primary MSCs is the preferable because these cells are safer than cells passaged several times in terms of probability of chromosome abnormalities. The effect of hypoxia on the proliferation of MSCs is controversial and remains unknown in primary synovial MSCs. Primary synovial MSCs were cultured at normoxia or hypoxia, and colony number, cell number, surface epitopes, mitochondria activity, TEM finding, and chondrogenic potential were analyzed. To investigate the effect of hypoxia on attachment of synovial MSCs, cells were cultured at hypoxia for the first 3 days, then cultured at normoxia. To investigate the effect of hypoxia on proliferation, cells were also cultured at hypoxia for the last 11 days. Hypoxia increased colony number and cell number per dish in primary synovial MSCs. Hypoxia did not affect cell number per colony, surface epitopes, mitochondria activity, TEM finding or chondrogenic potential. Hypoxia for the first 3 days did not alter colony number per dish or cell number per dish, while hypoxia for the last 11 days increased. Hypoxia enhanced proliferation through increase of colony formation rate with chondrogenic potential in primary synovial MSCs.

  7. Large Binocular Telescope and Sptizer Spectroscopy of Star-forming Galaxies at 1 Extinction and Star Formation Rate Indicators

    Science.gov (United States)

    Rujopakarn, W.; Rieke, G. H.; Papovich, C. J.; Weiner, B. J.; Rigby, Jane; Rex, M.; Bian, F.; Kuhn, O. P.; Thompson, D.

    2012-01-01

    We present spectroscopic observations in the rest-frame optical and near- to mid-infrared wavelengths of four gravitationally lensed infrared (IR) luminous star-forming galaxies at redshift 1 extinction, Av, of these systems, as well as testing star formation rate (SFR) indicators against the SFR measured by fitting spectral energy distributions to far-IR photometry. Our galaxies occupy a range of Av from 0 to 5.9 mag, larger than previously known for a similar range of IR luminosities at these redshifts. Thus, estimates of SFR even at z 2 must take careful count of extinction in the most IR luminous galaxies.We also measure extinction by comparing SFR estimates from optical emission lines with those from far- IR measurements. The comparison of results from these two independent methods indicates a large variety of dust distribution scenarios at 1 extinction, the Ha SFR indicator underestimates the SFR; the size of the necessary correction depends on the IR luminosity and dust distribution scenario. Individual SFR estimates based on the 6.2µm polycyclic aromatic hydrocarbon emission line luminosity do not show a systematic discrepancy with extinction, although a considerable, 0.2 dex, scatter is observed.

  8. Efficient Multiple Exciton Generation Observed in Colloidal PbSe Quantum Dots with Temporally and Spectrally Resolved Intraband Excitation

    KAUST Repository

    Ji, Minbiao

    2009-03-11

    We have spectrally resolved the intraband transient absorption of photogenerated excitons to quantify the exciton population dynamics in colloidal PbSe quantum dots (QDs). These measurements demonstrate that the spectral distribution, as well as the amplitude, of the transient spectrum depends on the number of excitons excited in a QD. To accurately quantify the average number of excitons per QD, the transient spectrum must be spectrally integrated. With spectral integration, we observe efficient multiple exciton generation In colloidal PbSe QDs. © 2009 American Chemical Society.

  9. Superposition of the luminescence spectra of free and bound excitons in ZnP2-D48

    International Nuclear Information System (INIS)

    Stamov, Ion; Nemerenco, Lucretia; Ivanenco, Iurii; Syrbu, Nicolae

    2011-01-01

    The luminescence spectra of ZnP 2 tetragonal crystals doped Mn, Sn, Cd, Sb at 10 K emission lines of bound excitons is detected. In the spectra non-phonon emission lines of bound and free excitons and their phonon replicas is isolated. The emission lines by the levels of the axial center are described. The composition of the luminescence of free and bound excitons at the axial center is investigated. In the region of phonon replicas of free excitons observed enhancement of lines due to forbidden transitions involving the recombination of excitons. A model of optic recombination transitions of the axial centre is proposed

  10. Relaxation dynamics of a driven two-level system coupled to a Bose–Einstein condensate: application to quantum dot-dipolar exciton gas hybrid systems

    Science.gov (United States)

    Kovalev, Vadim M.; Tse, Wang-Kong

    2017-11-01

    We develop a microscopic theory for the relaxation dynamics of an optically pumped two-level system (TLS) coupled to a bath of weakly interacting Bose gas. Using Keldysh formalism and diagrammatic perturbation theory, expressions for the relaxation times of the TLS Rabi oscillations are derived when the boson bath is in the normal state and the Bose–Einstein condensate (BEC) state. We apply our general theory to consider an irradiated quantum dot coupled with a boson bath consisting of a two-dimensional dipolar exciton gas. When the bath is in the BEC regime, relaxation of the Rabi oscillations is due to both condensate and non-condensate fractions of the bath bosons for weak TLS-light coupling and pre dominantly due to the non-condensate fraction for strong TLS-light coupling. Our theory also shows that a phase transition of the bath from the normal to the BEC state strongly influences the relaxation rate of the TLS Rabi oscillations. The TLS relaxation rate is approximately independent of the pump field frequency and monotonically dependent on the field strength when the bath is in the low-temperature regime of the normal phase. Phase transition of the dipolar exciton gas leads to a non-monotonic dependence of the TLS relaxation rate on both the pump field frequency and field strength, providing a characteristic signature for the detection of BEC phase transition of the coupled dipolar exciton gas.

  11. Influence of heating time and metal ions on the amount of free fatty acids and formation rates of selected carbonyl compounds during the thermal oxidation of canola oil.

    Science.gov (United States)

    Bastos, Luciane Conceição Silva; Pereira, Pedro Afonso de Paula

    2010-12-22

    Canola oil was heated continuously for 8 h at a typical frying temperature (180 °C) in the presence of various concentrations of the metal ions Fe(III), Cu(II), and Al(III) (9.2, 27.5, and 46.0 μg L(-1) of oil) to evaluate changes occurring in the amount of free fatty acids, expressed as acidity index, and in the formation rates of aldehydes. The aldehydes were collected and derivatized in silica cartridges functionalized with C18 and impregnated with an acid solution of 2,4-dinitrophenylhydrazine, after which they were eluted with acetonitrile and analyzed by LC-DAD-MS. Among the substances emitted, the following were identified and quantified: formaldehyde, acetaldehyde, acrolein, propanal, butanal, hexanal, (E)-2-heptenal, and octanal. During heating of the oil, the compounds presenting the highest mean formation rates were acrolein, hexanal, and acetaldehyde. In the study of the metal ions, the addition of ions to the samples generally led to a corresponding increase in the formation rates of the eight substances. The compounds showing the highest relative increases in formation rates were formaldehyde, acetaldehyde, propanal, and heptenal. In terms of catalytic effect, copper proved to be the most efficient in promoting increased formation rates, followed by iron and aluminum.

  12. Analytic derivative couplings and first-principles exciton/phonon coupling constants for an ab initio Frenkel-Davydov exciton model: Theory, implementation, and application to compute triplet exciton mobility parameters for crystalline tetracene.

    Science.gov (United States)

    Morrison, Adrian F; Herbert, John M

    2017-06-14

    Recently, we introduced an ab initio version of the Frenkel-Davydov exciton model for computing excited-state properties of molecular crystals and aggregates. Within this model, supersystem excited states are approximated as linear combinations of excitations localized on molecular sites, and the electronic Hamiltonian is constructed and diagonalized in a direct-product basis of non-orthogonal configuration state functions computed for isolated fragments. Here, we derive and implement analytic derivative couplings for this model, including nuclear derivatives of the natural transition orbital and symmetric orthogonalization transformations that are part of the approximation. Nuclear derivatives of the exciton Hamiltonian's matrix elements, required in order to compute the nonadiabatic couplings, are equivalent to the "Holstein" and "Peierls" exciton/phonon couplings that are widely discussed in the context of model Hamiltonians for energy and charge transport in organic photovoltaics. As an example, we compute the couplings that modulate triplet exciton transport in crystalline tetracene, which is relevant in the context of carrier diffusion following singlet exciton fission.

  13. Rate of dune formation and sediment transfer in the past few hundred years on the Danube-Tisza Interfluve, Hungary

    Science.gov (United States)

    Schubert, Gábor; Sipos, György

    2010-05-01

    Environmental change let it be induced either by climatic or anthropogenic factors has had a key role in determining the rate of aeolian sediment transfer, on the highly sensitive landscape of the Danube-Tisza Interfluve, Hungary. The study area is located on a former alluvial fan of the Danube, abandoned by the river in the Late Pleistocene, and then reshaped by aeolian activity. The resultant dune fields were time to time reactivated during the Holocene and historical times. As this part of the Carpathian Basin is often stricken by droughts, anthropogenic factors, such as forest clearances and/or overgrazing could easily lead to the disturbance of morphological stability. These effects acted on a local level, however in certain historical periods they supposedly were more extended and general. An era of this type was the time of Turkish occupation (16th-17th c.) and the following two centuries. During the Turkish rule the territory was cleared of forests and became deserted. Following the slow recolonisation by people and vegetation the land was mainly used for grazing. There are numerous historical reports on repeated sand storms and wind erosional events. However, we have no concept on the true amount of sediment reworked these times and the rate of geomorphic change. The major aim of the present study is therefore to quantify the possible amount of sediment transfer in a wind blown depression-hummock system on the central part of the Danube-Tisza Interfluve during the past 500 years. The determination of dune formation and migration rate provides further insight into the active morphological processes of the region, and also highlights the possible geomorphic responses to environmental changes (mostly climatic) currently affecting the central part of the Carpathian Basin. Seven drillings were made on the chosen hummock and the adjacent blow out to set up the chronological framework of dune formation by the means of luminescence dating (OSL). The relatively

  14. Spectral and Dynamical Properties of Single Excitons, Biexcitons, and Trions in Cesium-Lead-Halide Perovskite Quantum Dots.

    Science.gov (United States)

    Makarov, Nikolay S; Guo, Shaojun; Isaienko, Oleksandr; Liu, Wenyong; Robel, István; Klimov, Victor I

    2016-04-13

    Organic-inorganic lead-halide perovskites have been the subject of recent intense interest due to their unusually strong photovoltaic performance. A new addition to the perovskite family is all-inorganic Cs-Pb-halide perovskite nanocrystals, or quantum dots, fabricated via a moderate-temperature colloidal synthesis. While being only recently introduced to the research community, these nanomaterials have already shown promise for a range of applications from color-converting phosphors and light-emitting diodes to lasers, and even room-temperature single-photon sources. Knowledge of the optical properties of perovskite quantum dots still remains vastly incomplete. Here we apply various time-resolved spectroscopic techniques to conduct a comprehensive study of spectral and dynamical characteristics of single- and multiexciton states in CsPbX3 nanocrystals with X being either Br, I, or their mixture. Specifically, we measure exciton radiative lifetimes, absorption cross-sections, and derive the degeneracies of the band-edge electron and hole states. We also characterize the rates of intraband cooling and nonradiative Auger recombination and evaluate the strength of exciton-exciton coupling. The overall conclusion of this work is that spectroscopic properties of Cs-Pb-halide quantum dots are largely similar to those of quantum dots of more traditional semiconductors such as CdSe and PbSe. At the same time, we observe some distinctions including, for example, an appreciable effect of the halide identity on radiative lifetimes, considerably shorter biexciton Auger lifetimes, and apparent deviation of their size dependence from the "universal volume scaling" previously observed for many traditional nanocrystal systems. The high efficiency of Auger decay in perovskite quantum dots is detrimental to their prospective applications in light-emitting devices and lasers. This points toward the need for the development of approaches for effective suppression of Auger

  15. Formation of Valley Networks in a Cold and Icy Early Mars Climate: Predictions for Erosion Rates and Channel Morphology

    Science.gov (United States)

    Cassanelli, J.

    2017-12-01

    Mars is host to a diverse array of valley networks, systems of linear-to-sinuous depressions which are widely distributed across the surface and which exhibit branching patterns similar to the dendritic drainage patterns of terrestrial fluvial systems. Characteristics of the valley networks are indicative of an origin by fluvial activity, providing among the most compelling evidence for the past presence of flowing liquid water on the surface of Mars. Stratigraphic and crater age dating techniques suggest that the formation of the valley networks occurred predominantly during the early geologic history of Mars ( 3.7 Ga). However, whether the valley networks formed predominantly by rainfall in a relatively warm and wet early Mars climate, or by snowmelt and episodic rainfall in an ambient cold and icy climate, remains disputed. Understanding the formative environment of the valley networks will help distinguish between these warm and cold end-member early Mars climate models. Here we test a conceptual model for channel incision and evolution under cold and icy conditions with a substrate characterized by the presence of an ice-free dry active layer and subjacent ice-cemented regolith, similar to that found in the Antarctic McMurdo Dry Valleys. We implement numerical thermal models, quantitative erosion and transport estimates, and morphometric analyses in order to outline predictions for (1) the precise nature and structure of the substrate, (2) fluvial erosion/incision rates, and (3) channel morphology. Model predictions are compared against morphologic and morphometric observational data to evaluate consistency with the assumed cold climate scenario. In the cold climate scenario, the substrate is predicted to be characterized by a kilometers-thick globally-continuous cryosphere below a 50-100 meter thick desiccated ice-free zone. Initial results suggest that, with the predicted substrate structure, fluvial channel erosion and morphology in a cold early Mars

  16. Composite Boson Description of a Low-Density Gas of Excitons

    Science.gov (United States)

    Golomedov, A. E.; Lozovik, Yu. E.; Astrakharchik, G. E.; Boronat, J.

    2017-12-01

    Ground-state properties of a fermionic Coulomb gas are calculated using the fixed-node diffusion Monte Carlo method. The validity of the composite boson description is tested for different densities. We extract the exciton-exciton s-wave scattering length by solving the four-body problem in a harmonic trap and mapping the energy to that of two trapped bosons. The equation of state is consistent with the Bogoliubov theory for composite bosons interacting with the obtained s-wave scattering length. The perturbative expansion at low density has contributions physically coming from (a) exciton binding energy, (b) mean-field Gross-Pitaevskii interaction between excitons, and (c) quantum depletion of the excitonic condensate (Lee-Huang-Yang terms for composite bosons). In addition, for low densities we find a good agreement with the Bogoliubov bosonic theory for the condensate fraction of excitons. The equation of state in the opposite limit of large density is found to be well described by the perturbative theory including (a) mixture of two ideal Fermi gases and (b) exchange energy. We find that for low densities both energetic and coherent properties are correctly described by the picture of composite bosons (excitons).

  17. Intrinsic homogeneous linewidth and broadening mechanisms of excitons in monolayer transition metal dichalcogenides

    KAUST Repository

    Moody, Galan

    2015-09-18

    The band-edge optical response of transition metal dichalcogenides, an emerging class of atomically thin semiconductors, is dominated by tightly bound excitons localized at the corners of the Brillouin zone (valley excitons). A fundamental yet unknown property of valley excitons in these materials is the intrinsic homogeneous linewidth, which reflects irreversible quantum dissipation arising from system (exciton) and bath (vacuum and other quasiparticles) interactions and determines the timescale during which excitons can be coherently manipulated. Here we use optical two-dimensional Fourier transform spectroscopy to measure the exciton homogeneous linewidth in monolayer tungsten diselenide (WSe2). The homogeneous linewidth is found to be nearly two orders of magnitude narrower than the inhomogeneous width at low temperatures. We evaluate quantitatively the role of exciton–exciton and exciton–phonon interactions and population relaxation as linewidth broadening mechanisms. The key insights reported here—strong many-body effects and intrinsically rapid radiative recombination—are expected to be ubiquitous in atomically thin semiconductors.

  18. Strong excitonic interactions in the oxygen K-edge of perovskite oxides

    Energy Technology Data Exchange (ETDEWEB)

    Tomita, Kota; Miyata, Tomohiro [Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505 (Japan); Olovsson, Weine [Department of Physics, Chemistry and Biology (IFM), Linköping University, SE-581 83 Linköping (Sweden); Mizoguchi, Teruyasu, E-mail: teru@iis.u-tokyo.ac.jp [Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505 (Japan)

    2017-07-15

    Excitonic interactions of the oxygen K-edge electron energy-loss near-edge structure (ELNES) of perovskite oxides, CaTiO{sub 3}, SrTiO{sub 3}, and BaTiO{sub 3}, together with reference oxides, MgO, CaO, SrO, BaO, and TiO{sub 2}, were investigated using a first-principles Bethe–Salpeter equation calculation. Although the transition energy of oxygen K-edge is high, strong excitonic interactions were present in the oxygen K-edge ELNES of the perovskite oxides, whereas the excitonic interactions were negligible in the oxygen K-edge ELNES of the reference compounds. Detailed investigation of the electronic structure suggests that the strong excitonic interaction in the oxygen K-edge ELNES of the perovskite oxides is caused by the directionally confined, low-dimensional electronic structure at the Ti–O–Ti bonds. - Highlights: • Excitonic interaction in oxygen-K edge is investigated. • Strong excitonic interaction is found in the oxygen-K edge of perovskite oxides. • The strong excitonic interaction is ascribed to the low-dimensional and confined electronic structure.

  19. Theory of optical absorption by interlayer excitons in transition metal dichalcogenide heterobilayers

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Fengcheng; Lovorn, Timothy; MacDonald, A. H.

    2018-01-01

    We present a theory of optical absorption by interlayer excitons in a heterobilayer formed from transition metal dichalcogenides. The theory accounts for the presence of small relative rotations that produce a momentum shift between electron and hole bands located in different layers, and a moire pattern in real space. Because of the momentum shift, the optically active interlayer excitons are located at the moire Brillouin zone's corners, instead of at its center, and would have elliptical optical selection rules if the individual layers were translationally invariant. We show that the exciton moire potential energy restores circular optical selection rules by coupling excitons with different center of mass momenta. A variety of interlayer excitons with both senses of circular optical activity, and energies that are tunable by twist angle, are present at each valley. The lowest energy exciton states are generally localized near the exciton potential energy minima. We discuss the possibility of using the moire pattern to achieve scalable two-dimensional arrays of nearly identical quantum dots.

  20. Organic photovoltaics: elucidating the ultra-fast exciton dissociation mechanism in disordered materials.

    Science.gov (United States)

    Heitzer, Henry M; Savoie, Brett M; Marks, Tobin J; Ratner, Mark A

    2014-07-14

    Organic photovoltaics (OPVs) offer the opportunity for cheap, lightweight and mass-producible devices. However, an incomplete understanding of the charge generation process, in particular the timescale of dynamics and role of exciton diffusion, has slowed further progress in the field. We report a new Kinetic Monte Carlo model for the exciton dissociation mechanism in OPVs that addresses the origin of ultra-fast (<1 ps) dissociation by incorporating exciton delocalization. The model reproduces experimental results, such as the diminished rapid dissociation with increasing domain size, and also lends insight into the interplay between mixed domains, domain geometry, and exciton delocalization. Additionally, the model addresses the recent dispute on the origin of ultra-fast exciton dissociation by comparing the effects of exciton delocalization and impure domains on the photo-dynamics.This model provides insight into exciton dynamics that can advance our understanding of OPV structure-function relationships. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Effects of excitation spectral width on decay profile of weakly confined excitons

    International Nuclear Information System (INIS)

    Kojima, O.; Isu, T.; Ishi-Hayase, J.; Kanno, A.; Katouf, R.; Sasaki, M.; Tsuchiya, M.

    2008-01-01

    We report the effect due to a simultaneous excitation of several exciton states on the radiative decay profiles on the basis of the nonlocal response of weakly confined excitons in GaAs thin films. In the case of excitation of single exciton state, the transient grating signal has two decay components. The fast decay component comes from nonlocal response, and the long-lived component is attributed to free exciton decay. With an increase of excitation spectral width, the nonlocal component becomes small in comparison with the long-lived component, and disappears under irradiation of a femtosecond-pulse laser with broader spectral width. The transient grating spectra clearly indicates the contribution of the weakly confined excitons to the signal, and the exciton line width hardly changes by excitation spectral width. From these results, we concluded that the change of decay profile is attributed not to the many-body effect but to the effect of simultaneous excitation of several exciton states

  2. Exciton diamagnetic shift and optical properties in CdSe nanocrystal quantum dots in magnetic fields

    Science.gov (United States)

    Wu, Shudong; Cheng, Liwen

    2018-04-01

    The magnetic field dependence of the optical properties of CdSe nanocrystal quantum dots (NQDs) is investigated theoretically using a perturbation method within the effective-mass approximation. The results show that the magnetic field lifts the degeneracy of the electron (hole) states. A blue-shift in the absorption spectra of m ≥ 0 exciton states is observed while the absorption peak of m magnetic field strength B. This is attributed to the interplay of the orbital Zeeman effect and the additive confinement induced by the magnetic field. The excitonic absorption coefficient is almost independent of B in the strong confinement regime. The applied magnetic field causes the splitting of degenerated exciton states, resulting in the new absorption peaks. Based on the first-order perturbation theory, we propose the analytical expressions for the exciton binding energy, exciton transition energy and exciton diamagnetic shift of 1s, 1p-1, 1p0, 1p1, 1d-2, 1d-1, 1d0, 1d1, 1d2 and 2s exciton states on the applied magnetic field in the strong confinement regime.

  3. Resonantly excited exciton dynamics in two-dimensional MoSe2 monolayers

    Science.gov (United States)

    Scarpelli, L.; Masia, F.; Alexeev, E. M.; Withers, F.; Tartakovskii, A. I.; Novoselov, K. S.; Langbein, W.

    2017-07-01

    We report on the exciton and trion density dynamics in a single layer of MoSe2, resonantly excited and probed using three-pulse four-wave mixing (FWM), at temperatures from 300 K to 77 K. A multiexponential third-order response function for amplitude and phase of the heterodyne-detected FWM signal including four decay processes is used to model the data. We provide a consistent interpretation within the intrinsic band structure, not requiring the inclusion of extrinsic effects. We find an exciton radiative lifetime in the subpicosecond range consistent to what has been recently reported by Jakubczyk et al. [Nano Lett. 16, 5333 (2016), 10.1021/acs.nanolett.6b01060]. After the dominating radiative decay, the remaining exciton density, which has been scattered from the initially excited direct spin-allowed radiative state into dark states of different nature by exciton-phonon scattering or disorder scattering, shows a slower dynamics, covering 10-ps to 10-ns time scales. This includes direct spin-allowed transitions with larger in-plane momentum, as well as indirect and spin-forbidden exciton states. We find that exciton-exciton annihilation is not relevant in the observed dynamics, in variance from previous finding under nonresonant excitation. The trion density at 77 K reveals a decay of the order of 1 ps, similar to what is observed for the exciton. After few tens of picoseconds, the trion dynamics resembles the one of the exciton, indicating that trion ionization occurs on this time scale.

  4. External quantum efficiency exceeding 100% in a singlet-exciton-fission-based solar cell

    Science.gov (United States)

    Baldo, Marc

    2013-03-01

    Singlet exciton fission can be used to split a molecular excited state in two. In solar cells, it promises to double the photocurrent from high energy photons, thereby breaking the single junction efficiency limit. We demonstrate organic solar cells that exploit singlet exciton fission in pentacene to generate more than one electron per incident photon in the visible spectrum. Using a fullerene acceptor, a poly(3-hexylthiophene) exciton confinement layer, and a conventional optical trapping scheme, the peak external quantum efficiency is (109 +/-1)% at λ = 670 nm for a 15-nm-thick pentacene film. The corresponding internal quantum efficiency is (160 +/-10)%. Independent confirmation of the high internal efficiency is obtained by analysis of the magnetic field effect on photocurrent, which determines that the triplet yield approaches 200% for pentacene films thicker than 5 nm. To our knowledge, this is the first solar cell to generate quantum efficiencies above 100% in the visible spectrum. Alternative multiple exciton generation approaches have been demonstrated previously in the ultraviolet, where there is relatively little sunlight. Singlet exciton fission differs from these other mechanisms because spin conservation disallows the usual dominant loss process: a thermal relaxation of the high-energy exciton into a single low-energy exciton. Consequently, pentacene is efficient in the visible spectrum at λ = 670 nm because only the collapse of the singlet exciton into twotriplets is spin-allowed. Supported as part of the Center for Excitonics, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC0001088.

  5. The influence of morphology on excitons in single conjugated molecules

    Science.gov (United States)

    Thiessen, Alexander

    The electronic properties of pi-conjugated molecules are strongly related to their molecular shape and morphology of assembly in three-dimensional space. Understanding the various structure-property relationships is relevant to the applications of these materials in optoelectronic devices such as organic light-emitting diodes, field effect transistors and photovoltaic cells. The fact that conjugated systems interact with visible light opens these materials to a plethora of noninvasive spectroscopic investigation techniques. In this work, electronic properties of different pi-conjugated systems are studied spectroscopically on the ensemble and the single molecule levels. Single molecule spectroscopy is advantageous in that it allows the investigation of the individual nuclear building blocks that contribute to the properties of the ensemble. Additionally, transient photoluminescence spectroscopy methods can provide useful insight into the temporal evolution of the emissive states. In combination with these methods, novel pi-conjugated model molecules are used to probe processes related to exciton dynamics. For the first time, the spatial localization of excited states is probed experimentally in a molecule with a circular chromophoric structure. In addition, a set of model molecules with different geometries is employed to study exciton relaxation in pi-conjugated systems. The molecular morphology is utilized to distinguish between processes such as nuclear reorganization and torsional relaxation. Furthermore, single molecule spectroscopy is used to study the electronic structure of individual polymer chains in the photovoltaic cell material poly-(3-hexylthiophene). Optical spectra of this polymer are known to change with the morphology of the bulk film. Single molecule studies reveal that individual polymer chains exhibit similar behavior and indicate that spectral diversity is an intrinsic property of single P3HT molecules. The main results of this work are the

  6. A comparative theoretical study of exciton-dissociation and charge-recombination processes in oligothiophene/fullerene and oligothiophene/perylenediimide complexes for organic solar cells

    KAUST Repository

    Yi, Yuanping

    2011-01-01

    The exciton-dissociation and charge-recombination processes in donor-acceptor complexes found in α-sexithienyl/C60 and α-sexithienyl/perylenetetracarboxydiimide (PDI) solar cells are investigated by means of quantum-chemical methods. The electronic couplings and exciton-dissociation and charge-recombination rates have been evaluated for various configurations of the complexes. The results suggest that the decay of the lowest charge-transfer state to the ground state in the PDI-based devices: (i) is faster than that in the fullerene-based devices and (ii) in most cases, can compete with the dissociation of the charge-transfer state into mobile charge carriers. This faster charge-recombination process is consistent with the lower performance observed experimentally for the devices using PDI derivatives as the acceptor. © 2011 The Royal Society of Chemistry.

  7. Degradation of blue-phosphorescent organic light-emitting devices involves exciton-induced generation of polaron pair within emitting layers.

    Science.gov (United States)

    Kim, Sinheui; Bae, Hye Jin; Park, Sangho; Kim, Wook; Kim, Joonghyuk; Kim, Jong Soo; Jung, Yongsik; Sul, Soohwan; Ihn, Soo-Ghang; Noh, Changho; Kim, Sunghan; You, Youngmin

    2018-03-23

    Degradation of organic materials is responsible for the short operation lifetimes of organic light-emitting devices, but the mechanism by which such degradation is initiated has yet to be fully established. Here we report a new mechanism for degradation of emitting layers in blue-phosphorescent devices. We investigate binary mixtures of a wide bandgap host and a series of novel Ir(III) complex dopants having N-heterocyclocarbenic ligands. Our mechanistic study reveals the charge-neutral generation of polaron pairs (radical ion pairs) by electron transfer from the dopant to host excitons. Annihilation of the radical ion pair occurs by charge recombination, with such annihilation competing with bond scission. Device lifetime correlates linearly with the rate constant for the annihilation of the radical ion pair. Our findings demonstrate the importance of controlling exciton-induced electron transfer, and provide novel strategies to design materials for long-lifetime blue electrophosphorescence devices.

  8. Polarised two-photon excitation of quantum well excitons for manipulation of optically pumped terahertz lasers

    Energy Technology Data Exchange (ETDEWEB)

    Slavcheva, G., E-mail: gsk23@bath.ac.uk [Blackett Laboratory, Imperial College London, Prince Consort Road, London SW7 2AZ (United Kingdom); Kavokin, A.V., E-mail: A.Kavokin@soton.ac.uk [School of Physics and Astronomy, University of Southampton, Highfield, Southampton SO17 1BJ (United Kingdom); Spin Optics Laboratory, St. Petersburg State University, 1, Ulyanovskaya 198504 (Russian Federation)

    2014-11-15

    Optical pumping of excited exciton states in a semiconductor quantum well embedded in a microcavity is a tool for realisation of ultra-compact terahertz (THz) lasers based on stimulated optical transition between excited (2p) and ground (1s) exciton state. We show that the probability of two-photon absorption by a 2p-exciton is strongly dependent on the polarisation of both pumping photons. Five-fold variation of the threshold power for terahertz lasing by switching from circular to co-linear pumping is predicted. We identify photon polarisation configurations for achieving maximum THz photon generation quantum efficiency.

  9. Excitons, Biexcitons and Dephasing in GaAs T-shaped quantum wires

    DEFF Research Database (Denmark)

    Langbein, Wolfgang; Gislason, Hannes; Hvam, Jørn Märcher

    2000-01-01

    The binding energy of excitons and biexcitons and the exciton dephasing in T-shaped GaAs quantum wires is investigated by transient four-wave mixing. The T-shaped structure is fabricated by cleaved-edge overgrowth and its geometry is engineered to optimize the one-dimensional confinement...... structures due to the different confinement of electron and hole in the T-shaped wire. A dispersion of the homogeneous linewidth within the inhomogeneous broadening due to phonon-assisted relaxation is observed. An exciton acoustic-phonon scattering coefficient of 6.1 +-0.5 ìeV/K is found, which is larger...

  10. Optical nonlinearity and bistability in the bound exciton energy range of CdS

    International Nuclear Information System (INIS)

    Hoenig, T.; Gutowski, J.

    1988-01-01

    Under high excitation conditions thick CdS samples show pronounced broad-band nonlinear transmission in the bound exciton region and up to a wavelength of about 515 nm at cryo-temperatures. This behavior is only explainable in a model based on impurity neutralization and bound exciton creation. The suitability of these nonlinearities to yield optical bistability will be shown. Bistable operation is investigated in dependence of crystal thickness, impurity concentration, excitation density, wavelength, and temperature. A strong correlation to acceptor-bound exciton generation is obtained, and the explanation of this bistable operation fits well with that of the above mentioned transmission behavior. (author)

  11. Dynamic Control of Plasmon-Exciton Coupling in Au Nanodisk–J-Aggregate Hybrid Nanostructure Arrays

    KAUST Repository

    Zheng, Yue Bing

    2009-01-01

    We report the dynamic control of plasmon-exciton coupling in Au nanodisk arrays adsorbed with J-aggregate molecules by incident angle of light. The angle-resolved spectra of an array of bare Au nanodisks exhibit continuous shifting of localized surface plasmon resonances. This characteristic enables the production of real-time, controllable spectral overlaps between molecular and plasmonic resonances, and the efficient measurement of plasmon-exciton coupling as a function of wavelength with one or fewer nanodisk arrays. Experimental observations of varying plasmon-exciton coupling match with coupled dipole approximation calculations.

  12. Statistics, synergy, and mechanism of multiple photogeneration of excitons in quantum dots: Fundamental and applied aspects

    International Nuclear Information System (INIS)

    Oksengendler, B. L.; Turaeva, N. N.; Uralov, I.; Marasulov, M. B.

    2012-01-01

    The effect of multiple exciton generation is analyzed based on statistical physics, quantum mechanics, and synergetics. Statistical problems of the effect of multiple exciton generation (MEG) are broadened and take into account not only exciton generation, but also background excitation. The study of the role of surface states of quantum dots is based on the synergy of self-catalyzed electronic reactions. An analysis of the MEG mechanism is based on the idea of electronic shaking using the sudden perturbation method in quantum mechanics. All of the above-mentioned results are applied to the problem of calculating the limiting efficiency to transform solar energy into electric energy. (authors)

  13. Particle-in-a-bos model of one-dimensional excitons in conjugated polymers

    DEFF Research Database (Denmark)

    Pedersen, T.G.; Johansen, P.M.; Pedersen, H.C.

    2000-01-01

    A simple two-particle model of excitons in conjugated polymers is proposed as an alternative to usual highly computationally demanding quantum chemical methods. In the two-particle model, the exciton is described as an electron-hole pair interacting via Coulomb forces and confined to the polymer...... of these cases an approximate solution for the general case is obtained. As an application of the model the influence of a static electric field on the electron-hole overlap integral and exciton energy is considered....

  14. Superior Valley Polarization and Coherence of 2 s Excitons in Monolayer WSe2

    Science.gov (United States)

    Chen, Shao-Yu; Goldstein, Thomas; Tong, Jiayue; Taniguchi, Takashi; Watanabe, Kenji; Yan, Jun

    2018-01-01

    We report the experimental observation of 2 s exciton radiative emission from monolayer tungsten diselenide, enabled by hexagonal boron nitride protected high-quality samples. The 2 s luminescence is highly robust and persists up to 150 K, offering a new quantum entity for manipulating the valley degree of freedom. Remarkably, the 2 s exciton displays superior valley polarization and coherence than 1 s under similar experimental conditions. This observation provides evidence that the Coulomb-exchange-interaction-driven valley-depolarization process, the Maialle-Silva-Sham mechanism, plays an important role in valley excitons of monolayer transition metal dichalcogenides.

  15. Resonant Rayleigh scattering of exciton-polaritons in multiple quantum wells

    DEFF Research Database (Denmark)

    Malpuech, Guillaume; Kavokin, Alexey; Langbein, Wolfgang Werner

    2000-01-01

    A theoretical concept of resonant Rayleigh scattering (RRS) of exciton-polaritons in multiple quantum wells (QWs) is presented. The optical coupling between excitons in different QWs can strongly affect the RRS dynamics, giving rise to characteristic temporal oscillations on a picosecond scale....... Bragg and anti-Bragg arranged QW structures with the same excitonic parameters are predicted to have drastically different RRS spectra. Experimental data on the RRS from multiple QWs show the predicted strong temporal oscillations at small scattering angles, which are well explained by the presented...... theory....

  16. Modeling the effects of cooling rate, hydrogen content, grain refiner and modifier on microporosity formation in Al A356 alloys

    Energy Technology Data Exchange (ETDEWEB)

    Conley, J.G.; Huang, J.; Asada, J.; Akiba, K. [Northwestern Univ., Evanston, IL (United States). Dept. of Mechanical Engineering

    2000-06-15

    Cast Aluminum-Silicon alloys are used in numerous automotive and industrial weight sensitive applications because of their low density and excellent castability. The presence of trapped gas and or shrinkage pores in certain locations within castings has been shown to influence fatigue life. These micromechanical defects can be found most anywhere in a casting depending on processing conditions. A large amount of porosity located in the center of the cast material thickness may have no effect on mechanical properties or fatigue performance. A smaller, isolated pore near a surface may have a significant impact on mechanical properties. Hence, it is important to develop a comprehensive model to predict the size, location and distribution of microporosity in castings. In this work, we model the effect of various casting process parameters on microporosity formation for aluminum A356 alloy castings. The process parameters include cooling rate, hydrogen content, grain refiner and modifier. The proposed two-dimensional model predicts the size, morphology and distribution of microporosity at a given location in the casting. The method couples a mathematical model of porosity evolution with a probabilistic grain structure prediction model. The porosity evolution model is based on the simultaneous solution of the continuity and momentum equations for the metal and the mass conservation equation for the dissolved gas. The nucleation and growth of grains are simulated with a probabilistic method that uses the information from a heat transfer simulation, i.e. temperature and solid fraction, to determine the transition rules for grain evolution. The simulation results correlate well with experimental observation of porosity in cast structures. (orig.)

  17. STELLAR MASSES AND STAR FORMATION RATES OF LENSED, DUSTY, STAR-FORMING GALAXIES FROM THE SPT SURVEY

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Jingzhe; Gonzalez, Anthony H. [Department of Astronomy, University of Florida, Gainesville, FL 32611 (United States); Spilker, J. S.; Marrone, D. P. [Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721 (United States); Strandet, M. [Max-Planck-Institut für Radioastronomie, Auf dem Hügel 69 D-53121 Bonn (Germany); Ashby, M. L. N. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Aravena, M. [Núcleo de Astronomía, Facultad de Ingeniería, Universidad Diego Portales, Av. Ejército 441, Santiago (Chile); Béthermin, M.; Breuck, C. de; Gullberg, B. [European Southern Observatory, Karl Schwarzschild Straße 2, D-85748 Garching (Germany); Bothwell, M. S. [Cavendish Laboratory, University of Cambridge, JJ Thompson Avenue, Cambridge CB3 0HA (United Kingdom); Brodwin, M. [Department of Physics and Astronomy, University of Missouri, 5110 Rockhill Road, Kansas City, MO 64110 (United States); Chapman, S. C. [Dalhousie University, Halifax, Nova Scotia (Canada); Fassnacht, C. D. [Department of Physics, University of California, One Shields Avenue, Davis, CA 95616 (United States); Greve, T. R. [Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom); Hezaveh, Y. [Kavli Institute for Particle Astrophysics and Cosmology, Stanford University, Stanford, CA 94305 (United States); Malkan, M. [Department of Physics and Astronomy, University of California, Los Angeles, CA 90095-1547 (United States); Saliwanchik, B. R., E-mail: jingzhema@ufl.edu [Department of Physics, Case Western Reserve University, Cleveland, OH 44106 (United States); and others

    2015-10-10

    To understand cosmic mass assembly in the universe at early epochs, we primarily rely on measurements of the stellar masses and star formation rates (SFRs) of distant galaxies. In this paper, we present stellar masses and SFRs of six high-redshift (2.8 ≤ z ≤ 5.7) dusty, star-forming galaxies (DSFGs) that are strongly gravitationally lensed by foreground galaxies. These sources were first discovered by the South Pole Telescope (SPT) at millimeter wavelengths and all have spectroscopic redshifts and robust lens models derived from Atacama Large Millimeter/submillimeter Array observations. We have conducted follow-up observations to obtain multi-wavelength imaging data using the Hubble Space Telescope (HST), Spitzer, Herschel, and the Atacama Pathfinder EXperiment. We use the high-resolution HST/Wide Field Camera 3 images to disentangle the background source from the foreground lens in Spitzer/IRAC data. The detections and upper limits provide important constraints on the spectral energy distributions (SEDs) for these DSFGs, yielding stellar masses, IR luminosities, and SFRs. The SED fits of six SPT sources show that the intrinsic stellar masses span a range more than one order of magnitude with a median value ∼5 ×10{sup 10} M{sub ⊙}. The intrinsic IR luminosities range from 4 × 10{sup 12} L{sub ⊙} to 4 × 10{sup 13} L{sub ⊙}. They all have prodigious intrinsic SFRs of 510–4800 M{sub ⊙} yr{sup −1}. Compared to the star-forming main sequence (MS), these six DSFGs have specific SFRs that all lie above the MS, including two galaxies that are a factor of 10 higher than the MS. Our results suggest that we are witnessing ongoing strong starburst events that may be driven by major mergers.

  18. Carrier Formation Dynamics in Prototypical Organic Solar Cells as Investigated by Transient Absorption Spectroscopy

    Directory of Open Access Journals (Sweden)

    Yutaka Moritomo

    2016-01-01

    Full Text Available Subpicosecond transient absorption spectroscopy is a powerful tool used to clarify the exciton and carrier dynamics within the organic solar cells (OSCs. In this review article, we introduce a method to determine the absolute numbers of the excitons and carriers against delay time (t only from the photoinduced absorption (PIA and electrochemically induced absorption (EIA spectra. Application of this method to rr-P3HT-, PTB7-, and SMDPPEH-based OSCs revealed common aspects of the carrier formation dynamics. First, the temporal evolution of the numbers of the excitons and carriers indicates that the late decay component of exciton does not contribute to the carrier formation process. This is probably because the late component has not enough excess energy to separate into the electron and hole across the donor/acceptor (D/A interface. Secondly, the spectroscopy revealed that the exciton-to-carrier conversion process is insensitive to temperature. This observation, together with the fast carrier formation time in OSCs, is consistent with the hot exciton picture.

  19. Influence of fluctuating strain on exciton reflection spectra

    DEFF Research Database (Denmark)

    Skettrup, Torben

    1982-01-01

    , for example, between crossed polarizers or from ellipsometric measurements. Assuming the phase fluctuations to obey a Gaussian distribution, σ can be expressed in a simple way in terms of the degree of polarization or the depolarization of the reflected light. σ is then derived in terms of the standard......The influence of an internal distribution of strain on the exciton reflection spectra is investigated. The resulting fluctuating optical constants give rise to a fluctuating phase of reflectivity. The standard deviation σ of these phase fluctuations is the quantity which can be observed...... to derive the dependence of the phase of reflectivity on the direction of the fluctuating optical axis. The results obtained for σ are compared with the experimental depolarization spectra of ZnO. The only fitting parameter is the common standard deviation of the strain components. It is found...

  20. Using Nanowires To Extract Excitons from a Nanocrystal Solid

    Energy Technology Data Exchange (ETDEWEB)

    Dorn, August; Strasfeld, David B.; Harris, Daniel K.; Han, Hee-Sun; Bawendi, Moungi G.

    2011-11-22

    Synthetic methods yielding highly uniform colloidal semiconductor nanocrystals with controlled shapes and sizes are now available for many materials. These methods have enabled geometrical control of optical properties, which are difficult or impossible to achieve in conventional bulk solids. However, incorporating nanocrystals efficiently into photodetectors remains challenging because of the low charge carrier mobilities typical of nanocrystal solids. Here we present an approach based on exciton energy transfer from CdSe/CdS core/shell nanocrystals to embedded CdSe nanowires. By combining the wide electronic tunability of nanocrystals with the excellent one-dimensional charge transport characteristics obtainable in nanowires, we are able to increase photocurrent extraction from a nanocrystal solid by 2–3 orders of magnitude. Furthermore, we correlate local device morphology with optoelectronic functionality by measuring the local photocurrent response in a scanning confocal microscope. We also discuss how nancocrystal/nanowire hybrid devices could be used in particle detector systems.

  1. Anisotropic plasmons, excitons, and electron energy loss spectroscopy of phosphorene

    Science.gov (United States)

    Ghosh, Barun; Kumar, Piyush; Thakur, Anmol; Chauhan, Yogesh Singh; Bhowmick, Somnath; Agarwal, Amit

    2017-07-01

    In this article, we explore the anisotropic electron energy loss spectrum (EELS) in monolayer phosphorene based on ab initio time-dependent density-functional-theory calculations. Similarly to black phosphorus, the EELS of undoped monolayer phosphorene is characterized by anisotropic excitonic peaks for energies in the vicinity of the band gap and by interband plasmon peaks for higher energies. On doping, an additional intraband plasmon peak also appears for energies within the band gap. Similarly to other two-dimensional systems, the intraband plasmon peak disperses as ωpl∝√{q } in both the zigzag and armchair directions in the long-wavelength limit and deviates for larger wave vectors. The anisotropy of the long-wavelength plasmon intraband dispersion is found to be inversely proportional to the square root of the ratio of the effective masses: ωpl(q y ̂) /ωpl(q x ̂) =√{mx/my } .

  2. Multiple exciton generation in quantum dot-based solar cells

    Science.gov (United States)

    Goodwin, Heather; Jellicoe, Tom C.; Davis, Nathaniel J. L. K.; Böhm, Marcus L.

    2018-01-01

    Multiple exciton generation (MEG) in quantum-confined semiconductors is the process by which multiple bound charge-carrier pairs are generated after absorption of a single high-energy photon. Such charge-carrier multiplication effects have been highlighted as particularly beneficial for solar cells where they have the potential to increase the photocurrent significantly. Indeed, recent research efforts have proved that more than one charge-carrier pair per incident solar photon can be extracted in photovoltaic devices incorporating quantum-confined semiconductors. While these proof-of-concept applications underline the potential of MEG in solar cells, the impact of the carrier multiplication effect on the device performance remains rather low. This review covers recent advancements in the understanding and application of MEG as a photocurrent-enhancing mechanism in quantum dot-based photovoltaics.

  3. Exciton dephasing in single InGaAs quantum dots

    DEFF Research Database (Denmark)

    Leosson, Kristjan; Østergaard, John Erland; Jensen, Jacob Riis

    2000-01-01

    The homogeneous linewidth of excitonic transitions is a parameter of fundamental physical importance. In self-assembled quantum dot systems, a strong inhomogeneous broadening due to dot size fluctuations masks the homogeneous linewidth associated with transitions between individual states....... The homogeneous and inhomogeneous broadening of InGaAs quantum dot luminescence is of central importance for the potential application of this material system in optoelectronic devices. Recent measurements of MOCVD-grown InAs/InGaAs quantum dots indicate a large homogeneous broadening at room temperature due...... to fast dephasing. We present an investigation of the low-temperature homogeneous linewidth of individual PL lines from MBE-grown In0.5Ga0.5As/GaAs quantum dots....

  4. Warping and interactions of vortices in exciton-polariton condensates

    Science.gov (United States)

    Toledo-Solano, M.; Mora-Ramos, M. E.; Figueroa, A.; Rubo, Y. G.

    2014-01-01

    We investigate the properties of the vortex singularities in two-component exciton-polariton condensates in semiconductor microcavities in the presence of transverse-electric-transverse-magnetic (TE-TM) splitting of the lower polariton branch. This splitting does not change qualitatively the basic (lemon and star) geometry of half-quantum vortices (HQVs), but results in warping of both the polarization field and the supercurrent streamlines around these entities. The TE-TM splitting has a pronounced effect on the HQV energies and interactions, as well as on the properties of integer vortices, especially on the energy of the hedgehog polarization vortex. The energy of this vortex can become smaller than the energies of HQVs. This leads to modification of the Berezinskii-Kosterlitz-Thouless transition from the proliferation of half-vortices to the proliferation of hedgehog-based vortex molecules.

  5. Exciton interaction: its possible role in high temperature superconductivity

    International Nuclear Information System (INIS)

    Little, W.A.

    1987-01-01

    The recent remarkable developments in superconductivity has forced the group of physicists in the main stream of superconductivity research to re-examine the possible role of what has been referred to in the conference as novel mechanisms of superconductivity. The exciton mechanism is one such. While the many studies and developments in this subject are relatively well known to those involved in studies of organic superconductors and superconductors of reduced dimension, it appears that it is not well known to that large body of physicists involved in the more conventional mainstream of superconductivity. The salient features of the mechanism are reviewed and what it can and cannot do is discussed. Remarks are based on the most recent and most comprehensive review of the subject published in 1979, plus a few key papers since that time

  6. Studies on muon cycling rates in muon catalyzed D-T fusion system with possible four-body muonic molecules formation

    International Nuclear Information System (INIS)

    Eskandri, M.R.; Hosini Motlagh, N.; Hataf, A.

    2000-01-01

    In recent studies, it is shown that the fusion rate for four-body molecules of ppμμ, ddμμ, ptμμ, pdμμ, dtμμ, ttμμ, is considerably larger than that of similar three-body molecules of ppμμ, ddμμ, ptμμ, pdμμ, dtμμ, ttμμ. It is shown that for dtμμ, fusion rate is R f (dt) ≅ 3 * 10 13 - 6 * * 10 13 S -1 which is 40 times higher than fusion rate of dtμμ molecule. In this paper we have looked for the effect of these molecules formation in muon catalyzed D-T fusion. The required data for all possible branches do not exist, so the main dtμμ branch are considered here. By choosing a variable value for dtμμ molecule formation rate and comparing obtained cycling rates with existing experimental values, the order of this parameter is evaluated to be ≅ 10 9 S -1 . Using obtained data in different conditions of D-T muon cycling rate calculations have shown that considering of four-body molecule formations in existing muon injection intensities do not make considerable change in three-body muonic molecule cycling rate

  7. Stellar Absorption Line Analysis of Local Star-forming Galaxies: The Relation between Stellar Mass, Metallicity, Dust Attenuation, and Star Formation Rate

    International Nuclear Information System (INIS)

    Jabran Zahid, H.; Kudritzki, Rolf-Peter; Ho, I-Ting; Conroy, Charlie; Andrews, Brett

    2017-01-01

    We analyze the optical continuum of star-forming galaxies in the Sloan Digital Sky Survey by fitting stacked spectra with stellar population synthesis models to investigate the relation between stellar mass, stellar metallicity, dust attenuation, and star formation rate. We fit models calculated with star formation and chemical evolution histories that are derived empirically from multi-epoch observations of the stellar mass–star formation rate and the stellar mass–gas-phase metallicity relations, respectively. We also fit linear combinations of single-burst models with a range of metallicities and ages. Star formation and chemical evolution histories are unconstrained for these models. The stellar mass–stellar metallicity relations obtained from the two methods agree with the relation measured from individual supergiant stars in nearby galaxies. These relations are also consistent with the relation obtained from emission-line analysis of gas-phase metallicity after accounting for systematic offsets in the gas-phase metallicity. We measure dust attenuation of the stellar continuum and show that its dependence on stellar mass and star formation rate is consistent with previously reported results derived from nebular emission lines. However, stellar continuum attenuation is smaller than nebular emission line attenuation. The continuum-to-nebular attenuation ratio depends on stellar mass and is smaller in more massive galaxies. Our consistent analysis of stellar continuum and nebular emission lines paves the way for a comprehensive investigation of stellar metallicities of star-forming and quiescent galaxies.

  8. Assessment of terrestrial gamma radiation dose rate (TGRD) of Kelantan State, Malaysia. Relationship between the geological formation and soil type to radiation dose rate

    International Nuclear Information System (INIS)

    Garba, N.N.; Gabdo, H.T.; Federal College of Education, Yola

    2014-01-01

    Terrestrial gamma radiation dose rates (TGRD) of Kelantan State were measured in situ using a portable [NaI(TI)] micro roentgen (μR) survey meter. The TGRD rates ranged between 44 and 500 nGy h -1 with a mean value of 209 ± 8 nGy h -1 . The distribution of these measurements in various districts of the state shows the statistically the influence of geology and soil types on the dose rate values. The data obtained could be used in formulating safety standard and radiological guidelines. (author)

  9. Phonon induced pure dephasing process of excitonic state in colloidal semiconductor quantum dots

    Science.gov (United States)

    Huang, Tongyun; Han, Peng; Wang, Xinke; Feng, Shengfei; Sun, Wenfeng; Ye, Jiasheng; Zhang, Yan

    2016-04-01

    We present a theoretical study on the pure dephasing process of colloidal semiconductor quantum dots induced by lattice vibrations using continuum model calculations. By solving the time dependent Liouville-von Neumann equation, we present the ultrafast Rabi oscillations between excitonic state and virtual state via exciton-phonon interaction and obtain the pure dephasing time from the fast decayed envelope of the Rabi oscillations. The interaction between exciton and longitudinal optical phonon vibration is found to dominate the pure dephasing process and the dephasing time increases nonlinearly with the reduction of exciton-phonon coupling strength. We further find that the pure dephasing time of large quantum dots is more sensitive to temperature than small quantum dots.

  10. Dipolar excitons indirect in real and momentum space in a GaAs/AlAs heterostructure

    Energy Technology Data Exchange (ETDEWEB)

    Gorbunov, A. V., E-mail: gorbunov@issp.ac.ru; Timofeev, V. B. [Russian Academy of Sciences, Institute of Solid State Physics (Russian Federation)

    2015-01-15

    For a Schottky-diode structure containing two narrow GaAs (3.5 nm) and AlAs (5 nm) heterolayers, the photoluminescence properties of long-living dipolar excitons, indirect in both real and momentum space, are studied in perpendicular magnetic fields in the Faraday configuration of measurements. With an external perpendicular electric field, the lifetimes of such excitons can be extended to ∼1 μs. Nevertheless the exciton spin subsystem remains nonequilibrium: the exciton spin-relaxation time is even longer. The degree of circular polarization of the photoluminescence attains 80% in a field of 6 T. With an electric field, it is possible to control the degree and sign of the circular polarization.

  11. Structural and quantum chemical analysis of exciton coupling in homo- and heteroaggregate stacks of merocyanines

    Science.gov (United States)

    Bialas, David; Zitzler-Kunkel, André; Kirchner, Eva; Schmidt, David; Würthner, Frank

    2016-01-01

    Exciton coupling is of fundamental importance and determines functional properties of organic dyes in (opto-)electronic and photovoltaic devices. Here we show that strong exciton coupling is not limited to the situation of equal chromophores as often assumed. Quadruple dye stacks were obtained from two bis(merocyanine) dyes with same or different chromophores, respectively, which dimerize in less-polar solvents resulting in the respective homo- and heteroaggregates. The structures of the quadruple dye stacks were assigned by NMR techniques and unambiguously confirmed by single-crystal X-ray analysis. The heteroaggregate stack formed from the bis(merocyanine) bearing two different chromophores exhibits remarkably different ultraviolet/vis absorption bands compared with those of the homoaggregate of the bis(merocyanine) comprising two identical chromophores. Quantum chemical analysis based on an extension of Kasha's exciton theory appropriately describes the absorption properties of both types of stacks revealing strong exciton coupling also between different chromophores within the heteroaggregate. PMID:27680284

  12. Unifying Optical Selection Rules for Excitons in Two Dimensions: Band Topology and Winding Numbers

    Science.gov (United States)

    Cao, Ting; Wu, Meng; Louie, Steven G.

    2018-02-01

    We show that band topology can dramatically change the photophysics of two-dimensional semiconductors. For systems in which states near the band extrema are of multicomponent character, the spinors describing these components (pseudospins) can pick up nonzero winding numbers around the extremal k point. In these systems, we find that the strength and required light polarization of an excitonic optical transition are dictated by the optical matrix element winding number, a unique and heretofore unrecognized topological characteristic. We illustrate these findings in three gapped graphene systems—monolayer graphene with inequivalent sublattices and biased bi- and trilayer graphene, where the pseudospin textures manifest into nontrivial optical matrix element winding numbers associated with different valley and photon circular polarization. This winding-number physics leads to novel exciton series and optical selection rules, with each valley hosting multiple bright excitons coupled to light of different circular polarization. This valley-exciton selective circular dichroism can be unambiguously detected using optical spectroscopy.

  13. Quantum dot-like excitonic behavior in individual single walled-carbon nanotubes

    Science.gov (United States)

    Wang, Xu; Alexander-Webber, Jack A.; Jia, Wei; Reid, Benjamin P. L.; Stranks, Samuel D.; Holmes, Mark J.; Chan, Christopher C. S.; Deng, Chaoyong; Nicholas, Robin J.; Taylor, Robert A.

    2016-11-01

    Semiconducting single-walled carbon nanotubes are one-dimensional materials with great prospects for applications such as optoelectronic and quantum information devices. Yet, their optical performance is hindered by low fluorescent yield. Highly mobile excitons interacting with quenching sites are attributed to be one of the main non-radiative decay mechanisms that shortens the exciton lifetime. In this paper we report on time-integrated photoluminescence measurements on individual polymer wrapped semiconducting carbon nanotubes. An ultra narrow linewidth we observed demonstrates intrinsic exciton dynamics. Furthermore, we identify a state filling effect in individual carbon nanotubes at cryogenic temperatures as previously observed in quantum dots. We propose that each of the CNTs is segmented into a chain of zero-dimensional states confined by a varying local potential along the CNT, determined by local environmental factors such as the amount of polymer wrapping. Spectral diffusion is also observed, which is consistent with the tunneling of excitons between these confined states.

  14. Observation of bright and dark exciton transitions in monolayer MoSe2 by photocurrent spectroscopy

    Science.gov (United States)

    Quereda, Jorge; Ghiasi, Talieh S.; van Zwol, Feitze A.; van der Wal, Caspar H.; van Wees, Bart J.

    2018-03-01

    We investigate the excitonic transitions in single- and few-layer MoSe2 phototransistors by photocurrent spectroscopy. The measured spectral profiles show a well-defined peak at the optically active (bright) A0 exciton resonance. More interestingly, when a gate voltage is applied to the MoSe2 to bring its Fermi level near the bottom of the conduction band, another prominent peak emerges at an energy 30 meV above the A0 exciton. We attribute this second peak to a gate-induced activation of the spin-forbidden dark exciton transition, \\text{A}\\text{D}0 . Additionally, we evaluate the thickness-dependent optical bandgap of the fabricated MoSe2 crystals by characterizing their absorption edge.

  15. Impact of the Crystallite Orientation Distribution on Exciton Transport in Donor–Acceptor Conjugated Polymers

    KAUST Repository

    Ayzner, Alexander L.

    2015-12-30

    © 2015 American Chemical Society. Conjugated polymers are widely used materials in organic photovoltaic devices. Owing to their extended electronic wave functions, they often form semicrystalline thin films. In this work, we aim to understand whether distribution of crystallographic orientations affects exciton diffusion using a low-band-gap polymer backbone motif that is representative of the donor/acceptor copolymer class. Using the fact that the polymer side chain can tune the dominant crystallographic orientation in the thin film, we have measured the quenching of polymer photoluminescence, and thus the extent of exciton dissociation, as a function of crystal orientation with respect to a quenching substrate. We find that the crystallite orientation distribution has little effect on the average exciton diffusion length. We suggest several possibilities for the lack of correlation between crystallographic texture and exciton transport in semicrystalline conjugated polymer films.

  16. Materials and architectures for efficient harvesting of singlet and triplet excitons for white light emitting OLEDs

    Energy Technology Data Exchange (ETDEWEB)

    Thompson, Mark E; Forrest, Stephen

    2015-02-03

    The present invention relates to organic light emitting devices (OLEDs), and more specifically to OLEDS that emit light using a combination of fluorescent emitters and phosphorescent emitters for the efficient utilization of all of the electrically generated excitons.

  17. Radiative and non-radiative relaxation of excitons in strain-compensated quantum dots

    International Nuclear Information System (INIS)

    Kujiraoka, M.; Ishi-Hayase, J.; Akahane, K.; Yamamoto, Y.; Ema, K.; Sasaki, M.

    2008-01-01

    We have investigated the population dynamics of excitons in strain-compensated InAs quantum dots (QDs) using a pump-probe technique under resonant excitation. Precise control of polarization directions of incident pulses enabled us to selectively estimate population lifetimes for two orthogonally polarized exciton ground states according to polarization selection rules. Measured decay times of the probe transmissions were highly dependent on the polarization directions of the exciton states. We found that the ratio of the decay times for the orthogonally polarized states is in quantitative agreement with the ratio of square of the transition dipole moments. This indicates that radiative recombination processes have a dominant effect on the population dynamics and that non-radiative and spin relaxations are negligible in our QDs. As a result, we can estimate the radiative lifetimes to be 1.0±0.1 and 1.7±0.2 ns for orthogonally polarized exciton ground states

  18. Efficient Exciton Diffusion and Resonance-Energy Transfer in Multi-Layered Organic Epitaxial Nanofibers

    DEFF Research Database (Denmark)

    Tavares, Luciana; Cadelano, Michele; Quochi, Francesco

    2015-01-01

    ) spectroscopy to quantify exciton diffusion and resonance-energy transfer (RET) processes in multi-layered nanofibers consisting of alternating layers of para-hexaphenyl (p6P) and α-sexithiophene (6T), serving as exciton donor and acceptor material, respectively. The high probability for RET processes......-to-6T resonance-energy transfer efficiency, and the observed weak PL temperature dependence of the 6T acceptor material together result in an exceptionally high optical emission performance of this all-organic material system, thus making it well suited for example for organic light-emitting devices....... is confirmed by Quantum Chemical calculations. The activation energy for exciton diffusion in p6P is determined to be as low as 19 meV, proving p6P epitaxial layers also as a very suitable donor material system. The small activation energy for exciton diffusion of the p6P donor material, the inferred high p6P...

  19. Exciton localization and interface roughness in growth-interrupted GaAs/AlAs quantum wells

    DEFF Research Database (Denmark)

    Leosson, Kristjan; Jensen, Jacob Riis; Langbein, Wolfgang Werner

    2000-01-01

    regions differing in effective thickness by an integral number of monolayers. The energies of monolayers peaks, taking into account the in-plane localization energy, are found to be reproducible in wafers grown under similar conditions. We conclude that atomically smooth growth islands are formed on both...... of the in-plane disorder potential and the exciton localization length determines the spectral shape of the exciton luminescence. When the correlation length of the in-plane disorder potential is larger than the exciton localization length, the excitonic spectrum splits up into discrete peaks, stemming from...... AlAs and GaAs surfaces after growth interruption. During overgrowth, surface segregation leads to the generation of an atomic-scale disorder in the first overgrown monolayers. This results in an additional in-plane disorder potential with a much shorter correlation length than the original surface...

  20. Predicting excitonic gaps of semiconducting single-walled carbon nanotubes from a field theoretic analysis

    Science.gov (United States)

    Konik, Robert M.; Sfeir, Matthew Y.; Misewich, James A.

    2015-02-01

    We demonstrate that a nonperturbative framework for the treatment of the excitations of single-walled carbon nanotubes based upon a field theoretic reduction is able to accurately describe experiment observations of the absolute values of excitonic energies. This theoretical framework yields a simple scaling function from which the excitonic energies can be read off. This scaling function is primarily determined by a single parameter, the charge Luttinger parameter of the tube, which is in turn a function of the tube chirality, dielectric environment, and the tube's dimensions, thus expressing disparate influences on the excitonic energies in a unified fashion. We test this theory explicitly on the data reported by Dukovic et al. [Nano Lett. 5, 2314 (2005), 10.1021/nl0518122] and Sfeir et al. [Phys. Rev. B 82, 195424 (2010), 10.1103/PhysRevB.82.195424] and so demonstrate the method works over a wide range of reported excitonic spectra.