WorldWideScience

Sample records for employing transport layer

  1. Highly efficient and stable inverted perovskite solar cell employing PEDOT:GO composite layer as a hole transport layer.

    Science.gov (United States)

    Yu, Jae Choul; Hong, Ji A; Jung, Eui Dae; Kim, Da Bin; Baek, Soo-Min; Lee, Sukbin; Cho, Shinuk; Park, Sung Soo; Choi, Kyoung Jin; Song, Myoung Hoon

    2018-01-18

    The beneficial use of a hole transport layer (HTL) as a substitution for poly(3,4-ethlyenedioxythiophene): polystyrene sulfonate (PEDOT:PSS) is regarded as one of the most important approaches for improving the stability and efficiency of inverted perovskite solar cells. Here, we demonstrate highly efficient and stable inverted perovskite solar cells by applying a GO-doped PEDOT:PSS (PEDOT:GO) film as an HTL. The high performance of this solar cell stems from the excellent optical and electrical properties of the PEDOT:GO film, including a higher electrical conductivity, a higher work function related to the reduced contact barrier between the perovskite layer and the PEDOT:GO layer, enhanced crystallinity of the perovskite crystal, and suppressed leakage current. Moreover, the device with the PEDOT:GO layer showed excellent long-term stability in ambient air conditions. Thus, the enhancement in the efficiency and the excellent stability of inverted perovskite solar cells are promising for the eventual commercialization of perovskite optoelectronic devices.

  2. Improved electron transport layer

    DEFF Research Database (Denmark)

    2012-01-01

    The present invention provides: a method of preparing a coating ink for forming a zinc oxide electron transport layer, comprising mixing zinc acetate and a wetting agent in water or methanol; a coating ink comprising zinc acetate and a wetting agent in aqueous solution or methanolic solution......; a method of preparing a zinc oxide electron transporting layer, which method comprises: i) coating a substrate with the coating ink of the present invention to form a film; ii) drying the film; and iii) heating the dry film to convert the zinc acetate substantially to ZnO; a method of preparing an organic...... photovoltaic device or an organic LED having a zinc oxide electron transport layer, the method comprising, in this order: a) providing a substrate bearing a first electrode layer; b) forming an electron transport layer according to the following method: i) coating a coating ink comprising an ink according...

  3. Sub-Transport Layer Coding

    DEFF Research Database (Denmark)

    Hansen, Jonas; Krigslund, Jeppe; Roetter, Daniel Enrique Lucani

    2014-01-01

    oblivious to the congestion control algorithms of the utilised transport layer protocol. Although our coding shim is indifferent towards the transport layer protocol, we focus on the performance of TCP when ran on top of our proposed coding mechanism due to its widespread use. The coding shim provides gains...

  4. Economic benefits of employment transportation services : final report

    Science.gov (United States)

    2008-06-30

    This report examines the benefits that accrue from employment transportation services implemented as a result of changes in welfare policy, namely the Personal Responsibility and Work Opportunity Reconciliation Act (PRWORA) of 1996. Employment transp...

  5. Planar perovskite solar cells employing copper(I) thiocyanate/N,N‧-di(1-naphthyl)-N,N‧-diphenyl-(1,1‧-biphenyl)-4,4‧-diamine bilayer structure as hole transport layers

    Science.gov (United States)

    Tseng, Zong-Liang; Chen, Lung-Chien

    2018-02-01

    Organic hole transport materials, such as N 2,N 2,N 2‧,N 2‧,N 7,N 7,N 7‧,N 7‧-octakis(4-methoxyphenyl)-9,9‧-spirobi[9H-fluorene]-2,2‧,7,7‧-tetramine (Spiro-OMeTAD), are commonly used as the hole transport materials in efficient perovskite solar cells, but the chemical synthetic procedure may increase the cost of the photovoltaic devices. On the other hand, inorganic hole transport materials, such as copper(I) thiocyanate (CuSCN) or copper(I) iodide (CuI), have potential for the manufacture of efficient and low-cost perovskite solar cells, but the performance of these devices is still imperfect. In this study, we demonstrate the use of an inorganic CuSCN and organic N,N‧-di(1-naphthyl)-N,N‧-diphenyl-(1,1‧-biphenyl)-4,4‧-diamine (NPB) hybrid bilayer as an alternative hole transport layer for planar CH3NH3PbI3 perovskite solar cells. The electronic behavior of the bilayer and the performance of the corresponding devices were discussed. As a result, the power conversion efficiency (PCE) for the best cells at AM1.5G illumination with a shadow mask was 12.3%.

  6. Hydrocarbon transport in a plasma boundary layer

    International Nuclear Information System (INIS)

    Langer, W.D.; Ehrhardt, A.B.

    1989-01-01

    The theory of carbon transport in a plasma boundary layers is important for understanding the impurity penetration, and carbon and hydrogen recycling, in tokamaks using carbon compounds as limiters and as wall coatings. Neutral carbon kinetics and transport at the edge of plasma devices where chemical release is a source of carbon are modeled. Plasma reactions with carbon and hydrocarbons are important for such modeling, and these collisional processes are summarized. Combining the reaction schemes and kinetics in the DEGAS code makes it possible to treat the neutral transport at the plasma boundary layer. Results of such modeling of the atomic carbon and methane distribution at the edge are presented for comparison with recent carbon probe experiments performed on the Divertor and Injection Tokamak Experiment (DITE)

  7. Carrier transport in layered nanolaminated carbides

    Science.gov (United States)

    Konar, Aniruddha; Pandey, Rajan K.; Ethirajan, Tamilmani

    2017-10-01

    This paper summarizes the ab-initio electronic and phonon band structures and the temperature-dependent carrier transport in layered Ti2AlC. It is found that the cylindrical Fermi surface is the origin of the anisotropic carrier effective mass (infinite effective mass along the c axis), which leads to a strong anisotropic (insulator along the c axis and metallic along the layer) carrier transport in these films. Using electronic and phonon band structure calculations, we have developed an analytical model for the carrier-phonon interaction and the in-plane carrier conductivity originating from the strong inter-valley (s → d) scattering in Ti2AlC. The density functional theory is used to calculate the average deformation potential corresponding to the acoustic phonon vibrations. The calculated deformation potential is in good agreement with the extracted deformation potential from the transport data available in the literature. The extracted deformation potential will be useful for predicting the transport quantities of these metals at elevated temperatures.

  8. Optoelectronic device with nanoparticle embedded hole injection/transport layer

    Science.gov (United States)

    Wang, Qingwu [Chelmsford, MA; Li, Wenguang [Andover, MA; Jiang, Hua [Methuen, MA

    2012-01-03

    An optoelectronic device is disclosed that can function as an emitter of optical radiation, such as a light-emitting diode (LED), or as a photovoltaic (PV) device that can be used to convert optical radiation into electrical current, such as a photovoltaic solar cell. The optoelectronic device comprises an anode, a hole injection/transport layer, an active layer, and a cathode, where the hole injection/transport layer includes transparent conductive nanoparticles in a hole transport material.

  9. Methods for producing thin film charge selective transport layers

    Science.gov (United States)

    Hammond, Scott Ryan; Olson, Dana C.; van Hest, Marinus Franciscus Antonius Maria

    2018-01-02

    Methods for producing thin film charge selective transport layers are provided. In one embodiment, a method for forming a thin film charge selective transport layer comprises: providing a precursor solution comprising a metal containing reactive precursor material dissolved into a complexing solvent; depositing the precursor solution onto a surface of a substrate to form a film; and forming a charge selective transport layer on the substrate by annealing the film.

  10. Compact Layer Free Perovskite Solar Cells with a High-Mobility Hole-Transporting Layer.

    Science.gov (United States)

    Zhu, Qianqian; Bao, Xichang; Yu, Jianhua; Zhu, Dangqiang; Qiu, Meng; Yang, Renqiang; Dong, Lifeng

    2016-02-03

    A high-mobility diketopyrrolopyrrole-based copolymer (P) was employed in compact layer free CH3NH3PbI3 perovskite solar cells as a hole-transporting layer (HTL). By using the P-HTL, the 6.62% device efficiency with conventional poly-3-hexylthiophene was increased to 10.80% in the simple device configuration (ITO/CH3NH3PbI3/HTL/MoO3/Ag). With improved short circuit current density, open circuit voltage, and fill factor, the higher power conversion efficiency of P-HTL device is ascribed to the higher carrier mobility, more suitable energy level, and lower interfacial charge recombination. Advantages of applying P-HTL to perovskite solar cells, such as low cost, low-temperature processing, and excellent performance with simple cell structure, exhibit a possibility for commercial applications.

  11. 49 CFR 805.735-8 - Employment of family members in transportation and related enterprises.

    Science.gov (United States)

    2010-10-01

    ... Employment of family members in transportation and related enterprises. (a) No individual will be employed or retained in employment by the Board if a member of his immediate family (blood relations who are residents... 49 Transportation 7 2010-10-01 2010-10-01 false Employment of family members in transportation and...

  12. Towards lightweight and flexible high performance nanocrystalline silicon solar cells through light trapping and transport layers

    Science.gov (United States)

    Gray, Zachary R.

    This thesis investigates ways to enhance the efficiency of thin film solar cells through the application of both novel nano-element array light trapping architectures and nickel oxide hole transport/electron blocking layers. Experimental results independently demonstrate a 22% enhancement in short circuit current density (JSC) resulting from a nano-element array light trapping architecture and a ˜23% enhancement in fill factor (FF) and ˜16% enhancement in open circuit voltage (VOC) resulting from a nickel oxide transport layer. In each case, the overall efficiency of the device employing the light trapping or transport layer was superior to that of the corresponding control device. Since the efficiency of a solar cell scales with the product of JSC, FF, and VOC, it follows that the results of this thesis suggest high performance thin film solar cells can be realized in the event light trapping architectures and transport layers can be simultaneously optimized. The realizations of these performance enhancements stem from extensive process optimization for numerous light trapping and transport layer fabrication approaches. These approaches were guided by numerical modeling techniques which will also be discussed. Key developments in this thesis include (1) the fabrication of nano-element topographies conducive to light trapping using various fabrication approaches, (2) the deposition of defect free nc-Si:H onto structured topographies by switching from SiH4 to SiF 4 PECVD gas chemistry, and (3) the development of the atomic layer deposition (ALD) growth conditions for NiO. Keywords: light trapping, nano-element array, hole transport layer, electron blocking layer, nickel oxide, nanocrystalline silicon, aluminum doped zinc oxide, atomic layer deposition, plasma enhanced chemical vapor deposition, electron beam lithography, ANSYS HFSS.

  13. Heterojunction PbS Nanocrystal Solar Cells with Oxide Charge-Transport Layers

    KAUST Repository

    Hyun, Byung-Ryool

    2013-12-23

    Oxides are commonly employed as electron-transport layers in optoelectronic devices based on semiconductor nanocrystals, but are relatively rare as hole-transport layers. We report studies of NiO hole-transport layers in PbS nanocrystal photovoltaic structures. Transient fluorescence experiments are used to verify the relevant energy levels for hole transfer. On the basis of these results, planar heterojunction devices with ZnO as the photoanode and NiO as the photocathode were fabricated and characterized. Solution-processed devices were used to systematically study the dependence on nanocrystal size and achieve conversion efficiency as high as 2.5%. Optical modeling indicates that optimum performance should be obtained with thinner oxide layers than can be produced reliably by solution casting. Roomerature sputtering allows deposition of oxide layers as thin as 10 nm, which enables optimization of device performance with respect to the thickness of the charge-transport layers. The best devices achieve an open-circuit voltage of 0.72 V and efficiency of 5.3% while eliminating most organic material from the structure and being compatible with tandem structures. © 2013 American Chemical Society.

  14. Unstirred Water Layers and the Kinetics of Organic Cation Transport

    Science.gov (United States)

    Shibayama, Takahiro; Morales, Mark; Zhang, Xiaohong; Martinez, Lucy; Berteloot, Alfred; Secomb, Timothy W.; Wright, Stephen H.

    2015-01-01

    Purpose Unstirred water layers (UWLs) present an unavoidable complication in the measurement of transport kinetics in cultured cells and the high rates of transport achieved by overexpressing heterologous transporters exacerbate the UWL effect. This study examined the correlation between measured Jmax and Kt values and the effect of manipulating UWL thickness or transport Jmax on the accuracy of experimentally determined kinetics of the multidrug transporters, OCT2 and MATE1. Methods Transport of TEA and MPP was measured in CHO cells that stably expressed human OCT2 or MATE1. UWL thickness was manipulated by vigorous reciprocal shaking. Several methods were used to manipulate maximal transport rates. Results Vigorous stirring stimulated uptake of OCT2-mediated transport by decreasing apparent Kt (Ktapp) values. Systematic reduction in transport rates was correlated with reduction in Ktapp values. The slope of these relationships indicated a 1500 µm UWL in multiwell plates. Reducing the influence of UWLs (by decreasing either their thickness or the Jmax of substrate transport) reduced Ktapp by 2-fold to >10-fold. Conclusions Failure to take into account the presence of UWLs in experiments using cultured cells to measure transport kinetics can result in significant underestimates of the affinity of multidrug transporters for substrates. PMID:25791216

  15. Layer-by-Layer technique employed to construct multitask interfaces in polymer composites

    Directory of Open Access Journals (Sweden)

    Luísa Sá Vitorino

    Full Text Available Abstract The properties of glass fiber-reinforced polymer composites are closely related to the fiber-matrix interface. Interfacial treatments to improve mechanical properties are usually limited to enhance interfacial adhesion. In this work, Layer-by-Layer (LbL technique was introduced to build a novel interface in polymer composites. Different numbers of bilayers of poly(diallyldimethylammonium chloride and poly(sodium 4-styrenesulfonate with carbon nanotubes were deposited through LbL on the surface of woven glass fibers (GFs. Polypropylene composites containing the modified GFs were prepared by compression molding. Thermogravimetric analysis, scanning electron microscopy and Raman spectroscopy proved that multilayers of polymers with carbon nanotubes could be deposited on GFs surface. Mechanical tests on composites with modified GFs revealed an increase in Flexural Modulus and toughness. The overall results attested that the LbL technique can be used to design interfaces with different compositions to perform diverse tasks, such as to improve the stiffness of composites and to encapsulate active nanocomponents.

  16. Characterization of transport phenomena in porous transport layers using X-ray microtomography

    Science.gov (United States)

    Hasanpour, S.; Hoorfar, M.; Phillion, A. B.

    2017-06-01

    Among different methods available for estimating the transport properties of porous transport layers (PTLs) of polymer electrolyte membrane fuel cells, X-ray micro computed tomography (X-μCT) imaging in combination with image-based numerical simulation has been recognized as a viable tool. In this study, four commercially-available single-layer and dual-layer PTLs are analyzed using this method in order to compare and contrast transport properties between different PTLs, as well as the variability within a single sheet. Complete transport property datasets are created for each PTL. The simulation predictions indicate that PTLs with high porosity show considerable variability in permeability and effective diffusivity, while PTLs with low porosity do not. Furthermore, it is seen that the Tomadakis-Sotirchos (TS) analytical expressions for porous media match the image-based simulations when porosity is relatively low but predict higher permeability and effective diffusivity for porosity values greater than 80%. Finally, the simulations show that cracks within MPL of dual-layer PTLs have a significant effect on the overall permeability and effective diffusivity of the PTLs. This must be considered when estimating the transport properties of dual-layer PTLs. These findings can be used to improve macro-scale models of product and reactant transport within fuel cells, and ultimately, fuel cell efficiency.

  17. Computations of intermittent transport in scrape-off layer plasmas

    DEFF Research Database (Denmark)

    Garcia, O.E.; Naulin, V.; Nielsen, A.H.

    2004-01-01

    Two-dimensional fluid simulations of interchange turbulence for geometry and parameters relevant for the scrape-off layer of magnetized plasmas are presented. The computations, which have distinct plasma production and loss regions, reveal bursty ejection of particles and heat from the bulk plasma...... in the form of blobs. These structures propagate far into the scrape-off layer where they are dissipated due to transport along open magnetic field lines. From single-point recordings it is shown that the blobs have asymmetric conditional wave forms and lead to positively skewed and flattened probability...

  18. Fluctuations and transport in the TCV scrape-off layer

    DEFF Research Database (Denmark)

    Garcia, Odd Erik; Horacek, J.; Pitts, R.A.

    2007-01-01

    Fluctuations and particle transport in the scrape-off layer of TCV plasmas have been investigated by probe measurements and direct comparison with two-dimensional interchange turbulence simulations at the outer midplane. The experiments demonstrate that with increasing line-averaged core plasma...... density, the radial particle density profile scale length becomes broader. The particle and radial flux density statistics in the far scrape-off layer exhibit a high degree of statistical similarity with respect to changes in the line-averaged density. The plasma flux onto the main chamber wall...... at the outer midplane scales linearly with the local particle density, suggesting that the particle flux here can be parameterized in terms of an effective convection velocity. Experimental probe measurements also provide evidence for significant parallel flows in the scrape-off layer caused by ballooning...

  19. Anisotropic bias dependent transport property of defective phosphorene layer

    Science.gov (United States)

    Umar Farooq, M.; Hashmi, Arqum; Hong, Jisang

    2015-01-01

    Phosphorene is receiving great research interests because of its peculiar physical properties. Nonetheless, no systematic studies on the transport properties modified due to defects have been performed. Here, we present the electronic band structure, defect formation energy and bias dependent transport property of various defective systems. We found that the defect formation energy is much less than that in graphene. The defect configuration strongly affects the electronic structure. The band gap vanishes in single vacancy layers, but the band gap reappears in divacancy layers. Interestingly, a single vacancy defect behaves like a p-type impurity for transport property. Unlike the common belief, we observe that the vacancy defect can contribute to greatly increasing the current. Along the zigzag direction, the current in the most stable single vacancy structure was significantly increased as compared with that found in the pristine layer. In addition, the current along the armchair direction was always greater than along the zigzag direction and we observed a strong anisotropic current ratio of armchair to zigzag direction. PMID:26198318

  20. Ion Transport through Diffusion Layer Controlled by Charge Mosaic Membrane

    Directory of Open Access Journals (Sweden)

    Akira Yamauchi

    2012-01-01

    Full Text Available The kinetic transport behaviors in near interface of the membranes were studied using commercial anion and cation exchange membrane and charge mosaic membrane. Current-voltage curve gave the limiting current density that indicates the ceiling of conventional flux. From chronopotentiometry above the limiting current density, the transition time was estimated. The thickness of boundary layer was derived with conjunction with the conventional limiting current density and the transition time from steady state flux. On the other hand, the charge mosaic membrane was introduced in order to examine the ion transport on the membrane surface in detail. The concentration profile was discussed by the kinetic transport number with regard to the water dissociation (splitting on the membrane surface.

  1. 49 CFR 40.409 - What does the issuance of a PIE mean to transportation employers?

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 1 2010-10-01 2010-10-01 false What does the issuance of a PIE mean to... What does the issuance of a PIE mean to transportation employers? (a) As an employer, you are deemed to have notice of the issuance of a PIE when it appears on the List mentioned in § 40.401(a) or the notice...

  2. Planar heterojunction perovskite solar cell based on CdS electron transport layer

    KAUST Repository

    Abulikemu, Mutalifu

    2017-07-02

    We report on planar heterojunction perovskite solar cells employing a metal chalcogenide (CdS) electron transport layer with power conversion efficiency up to 10.8%. The CdS layer was deposited via solution-process chemical bath deposition at low-temperature (60°C). Pinhole-free and uniform thin films were obtained with good structural, optical and morphological properties. An optimal layer thickness of 60nm yielded an improved open-circuit voltage and fill factor compared to the standard TiO2-based solar cells. Devices showed a higher reproducibility of the results compared to TiO2-based ones. We also tested the effect of annealing temperature on the CdS film and the effect of CdCl2 treatment followed by high temperature annealing (410°C) that is expected to passivate the surface, thus eliminating eventual trap-states inducing recombination.

  3. Turbulent transport of large particles in the atmospheric boundary layer

    Science.gov (United States)

    Richter, D. H.; Chamecki, M.

    2017-12-01

    To describe the transport of heavy dust particles in the atmosphere, assumptions must typically be made in order to connect the micro-scale emission processes with the larger-scale atmospheric motions. In the context of numerical models, this can be thought of as the transport process which occurs between the domain bottom and the first vertical grid point. For example, in the limit of small particles (both low inertia and low settling velocity), theory built upon Monin-Obukhov similarity has proven effective in relating mean dust concentration profiles to surface emission fluxes. For increasing particle mass, however, it becomes more difficult to represent dust transport as a simple extension of the transport of a passive scalar due to issues such as the crossing trajectories effect. This study focuses specifically on the problem of large particle transport and dispersion in the turbulent boundary layer by utilizing direct numerical simulations with Lagrangian point-particle tracking to determine under what, if any, conditions the large dust particles (larger than 10 micron in diameter) can be accurately described in a simplified Eulerian framework. In particular, results will be presented detailing the independent contributions of both particle inertia and particle settling velocity relative to the strength of the surrounding turbulent flow, and consequences of overestimating surface fluxes via traditional parameterizations will be demonstrated.

  4. Plasma blob transport in scrape-off layer

    International Nuclear Information System (INIS)

    Ohno, Noriyasu

    2006-01-01

    Scrape off layer (SOL) is an open magnetic field between wall and high temperature core plasma field with magnetic surface. The recent theories, simulation and experimental results of plasma blob transport are described. Characteristic properties and physical mechanism of plasma blob, magnetic structure of divertor, plasma density of SOL in Alcator C-Mod tokamak, analytical model of plasma blob transport, simulation of stability of second-dimension flow of plasma blob, change of the second-dimension structure, the probability density function (PDF), change of plasma parameters in the SOL field of DIII-D, change of ion saturation current observed in confining magnetic field and NAGDIS-II are shown. (S.Y.)

  5. High efficiency blue phosphorescent organic light-emitting diodes without electron transport layer

    Energy Technology Data Exchange (ETDEWEB)

    Jeon, Soon Ok [Department of Polymer Science and Engineering, Dankook University, Jukjeon-dong, Suji-gu, Yongin-si, Gyeonggi-do 448-701 (Korea, Republic of); Lee, Jun Yeob, E-mail: leej17@dankook.ac.kr [Department of Polymer Science and Engineering, Dankook University, Jukjeon-dong, Suji-gu, Yongin-si, Gyeonggi-do 448-701 (Korea, Republic of)

    2011-08-15

    High efficiency blue phosphorescent organic light-emitting diodes were fabricated without an electron transport layer using a spirobifluorene based blue triplet host material. The simple blue PHOLEDs without the electron transport layer showed a high external quantum efficiency and current efficiency of 16.1% and 30.2 cd/A, respectively. The high device performances of the electron transport layer free blue PHOLEDs were comparable to those of blue PHOLEDs with the electron transport layer. - Highlights: > Simple device structure without electron transport layer. > High efficiency blue phosphorescent organic light-emitting diode. > Spirobifluorene based high triplet energy host material.

  6. Reynolds number influences on turbulent boundary layer momentum transport

    Science.gov (United States)

    Priyadarshana, Paththage A.

    There are many engineering applications at Reynolds numbers orders of magnitude higher than existing turbulent boundary layer studies. Currently, the mechanisms for turbulent transport and the Reynolds number dependence of these mechanisms are not well understood. This dissertation presents Reynolds number influences on velocity and vorticity statistics, Reynolds shear stress, and velocity-vorticity correlations for turbulent boundary layers. Well resolved hot-wire data for this study were acquired in the atmospheric surface layer at the SLTEST facility in western Utah. It is shown that during near neutral thermal stability, the flow behaves as a canonical zero pressure gradient turbulent boundary layer, in which the Reynolds number based on momentum thickness, Rtheta, is approximately 2 x 106. The present study also provides information regarding the effects of wall roughness over a limited range of roughness. It is observed that with increasing Rtheta, the inner normalized streamwise intensity increases. This statistic is less sensitive to wall roughness away from the roughness sublayer. In contrast, the inner normalized wall normal intensity is less sensitive to the variation of Rtheta, and it is significantly sensitive to wall roughness. Outside the viscous sublayer, the inner normalized vorticity intensity is less sensitive to both Rtheta and roughness. A primary observation of the Reynolds stress study is that the predominant motions underlying the Reynolds shear stress undergo a significant shift from large to intermediate scales as Rtheta becomes large, irrespective of surface roughness. Quadrant analysis shows that types of motions contributing to the Reynolds stress change significantly at comparable wall normal locations with increasing Rtheta. The mean wall normal gradients of the Reynolds shear stress and the turbulent kinetic energy have direct connections to the transport mechanisms of the turbulent boundary layer. These gradients can be expressed in

  7. Exploring transportation, employment, housing, and location issues for New Jersey veterans with disability.

    Science.gov (United States)

    2014-11-01

    Working-age veterans with disability face myriad responsibilities when they seek to rejoin civilian life. They must secure housing : and employment while coping with health care concerns and one or more disabilities. Access to transportation part...

  8. Analytical solution of electrohydrodynamic flow and transport in rectangular channels: inclusion of double layer effects

    KAUST Repository

    Joekar-Niasar, V.

    2013-01-25

    Upscaling electroosmosis in porous media is a challenge due to the complexity and scale-dependent nonlinearities of this coupled phenomenon. "Pore-network modeling" for upscaling electroosmosis from pore scale to Darcy scale can be considered as a promising approach. However, this method requires analytical solutions for flow and transport at pore scale. This study concentrates on the development of analytical solutions of flow and transport in a single rectangular channel under combined effects of electrohydrodynamic forces. These relations will be used in future works for pore-network modeling. The analytical solutions are valid for all regimes of overlapping electrical double layers and have the potential to be extended to nonlinear Boltzmann distribution. The innovative aspects of this study are (a) contribution of overlapping of electrical double layers to the Stokes flow as well as Nernst-Planck transport has been carefully included in the analytical solutions. (b) All important transport mechanisms including advection, diffusion, and electromigration have been included in the analytical solutions. (c) Fully algebraic relations developed in this study can be easily employed to upscale electroosmosis to Darcy scale using pore-network modeling. © 2013 Springer Science+Business Media Dordrecht.

  9. Angular Momentum Transport in Accretion Disk Boundary Layers Around Weakly Magnetized Stars

    Directory of Open Access Journals (Sweden)

    Pessah Martin E.

    2013-04-01

    Full Text Available The standard model for turbulent shear viscosity in accretion disks is based on the assumption that angular momentum transport is opposite to the radial angular frequency gradient of the disk. This implies that the turbulent stress must be negative and thus transport angular momentum inwards, in the boundary layer where the accretion disk meets the surface of a weakly magnetized star. However, this behavior is not supported by numerical simulations of turbulent magnetohydrodynamic (MHD accretion disks, which show that angular momentum transport driven by the magnetorotational instability (MRI is inefficient in disk regions where, as expected in boundary layers, the angular frequency increases with radius. Motivated by the need of a deeper understanding of the behavior of an MHD fluid in a differentially rotating background that deviates from a Keplerian profile, we study the dynamics of MHD waves in configurations that are stable to the standard MRI. Employing the shearing-sheet framework, we show that transient amplification of shearing MHD waves can generate magnetic energy without leading to a substantial generation of hydromagnetic stresses. While these results are in agreement with numerical simulations, they emphasize the need to better understand the mechanism for angular momentum transport in the inner disk regions on more solid grounds.

  10. Electronic spin transport and spin precession in single graphene layers at room temperature.

    Science.gov (United States)

    Tombros, Nikolaos; Jozsa, Csaba; Popinciuc, Mihaita; Jonkman, Harry T; van Wees, Bart J

    2007-08-02

    Electronic transport in single or a few layers of graphene is the subject of intense interest at present. The specific band structure of graphene, with its unique valley structure and Dirac neutrality point separating hole states from electron states, has led to the observation of new electronic transport phenomena such as anomalously quantized Hall effects, absence of weak localization and the existence of a minimum conductivity. In addition to dissipative transport, supercurrent transport has also been observed. Graphene might also be a promising material for spintronics and related applications, such as the realization of spin qubits, owing to the low intrinsic spin orbit interaction, as well as the low hyperfine interaction of the electron spins with the carbon nuclei. Here we report the observation of spin transport, as well as Larmor spin precession, over micrometre-scale distances in single graphene layers. The 'non-local' spin valve geometry was used in these experiments, employing four-terminal contact geometries with ferromagnetic cobalt electrodes making contact with the graphene sheet through a thin oxide layer. We observe clear bipolar (changing from positive to negative sign) spin signals that reflect the magnetization direction of all four electrodes, indicating that spin coherence extends underneath all of the contacts. No significant changes in the spin signals occur between 4.2 K, 77 K and room temperature. We extract a spin relaxation length between 1.5 and 2 mum at room temperature, only weakly dependent on charge density. The spin polarization of the ferromagnetic contacts is calculated from the measurements to be around ten per cent.

  11. A Microfluidic Pore Network Approach to Investigate Water Transport in Fuel Cell Porous Transport Layers

    OpenAIRE

    Bazylak, A.; Berejnov, V.; Markicevic, B.; Sinton, D.; Djilali, N.

    2008-01-01

    Pore network modelling has traditionally been used to study displacement processes in idealized porous media related to geological flows, with applications ranging from groundwater hydrology to enhanced oil recovery. Very recently, pore network modelling has been applied to model the gas diffusion layer (GDL) of a polymer electrolyte membrane (PEM) fuel cell. Discrete pore network models have the potential to elucidate transport phenomena in the GDL with high computational efficiency, in cont...

  12. Atomic layer deposition of NiO hole-transporting layers for polymer solar cells

    Science.gov (United States)

    Hsu, Che-Chen; Su, Heng-Wei; Hou, Cheng-Hung; Shyue, Jing-Jong; Tsai, Feng-Yu

    2015-09-01

    NiO is an attractive hole-transporting material for polymer solar cells (PSCs) owing to its excellent stability and electrical/optical properties. This study demonstrates, for the first time, fabrication of uniform, defect-free, and conformal NiO ultra-thin films for use as hole-transporting layers (HTLs) in PSCs by atomic layer deposition (ALD) through optimization of the ALD processing parameters. The morphological, optical, and electrical properties of ALD NiO films were determined to be favorable for their HTL application. As a result, PSCs containing an ALD NiO HTL with an optimized thickness of 4 nm achieved a power conversion efficiency (PCE) of 3.4%, which was comparable to that of a control device with a poly(3,4-ethylenedioxy-thiophene):poly(styrene-sulfonate) HTL. The high quality and manufacturing scalability of ALD NiO films demonstrated here will facilitate the adoption of NiO HTLs in PSCs.

  13. Layered packaging: A synergistic method of transporting radioactive material

    International Nuclear Information System (INIS)

    Hohmann, G.L.

    1989-01-01

    The DOE certification for a transportation cask used to ship radioactive Krypton 85 from the Idaho Chemical Processing Plant (ICPP) to Oak Ridge National Laboratory (ORNL), was allowed to expire in 1987. The Westinghouse Idaho Nuclear Company (WINCO) was charged by DOE with modifying this cask to meet all current NRC requirements and preparing an updated Safety Analysis Report for Packaging, which would be submitted by DOE to the NRC for certification. However, an urgent need arose for ORNL to receive Krypton 85 which was in storage at the ICPP, which would not allow time to obtain certification of the modified shipping cask. WINCO elected to use a layered shipping configuration in which the gaseous Krypton 85 was placed in the uncertified, modified shipping cask to make use of its shielding and thermal insulation properties. This cask was then inserted into the Model No. 6400 (Super Tiger) packaging using a specially constructed plywood box and polyurethane foam dunnage. Structural evaluations were completed to assure the Super Tiger would provide the necessary impact, puncture, and thermal protection during maximum credible accidents. Analyses were also completed to determine the uncertified Krypton shipping cask would provide the necessary containment and shielding for up to 3.7 E+14 Bq of Krypton 85 when packaged inside the Super Tiger. The resulting reports, based upon this layered packaging concept, were adequate to first obtain DOE certification for several restricted shipments of Krypton 85 and then NRC certification for unrestricted shipments

  14. One-Dimensional Electron Transport Layers for Perovskite Solar Cells

    Science.gov (United States)

    Thakur, Ujwal K.; Kisslinger, Ryan; Shankar, Karthik

    2017-01-01

    The electron diffusion length (Ln) is smaller than the hole diffusion length (Lp) in many halide perovskite semiconductors meaning that the use of ordered one-dimensional (1D) structures such as nanowires (NWs) and nanotubes (NTs) as electron transport layers (ETLs) is a promising method of achieving high performance halide perovskite solar cells (HPSCs). ETLs consisting of oriented and aligned NWs and NTs offer the potential not merely for improved directional charge transport but also for the enhanced absorption of incoming light and thermodynamically efficient management of photogenerated carrier populations. The ordered architecture of NW/NT arrays affords superior infiltration of a deposited material making them ideal for use in HPSCs. Photoconversion efficiencies (PCEs) as high as 18% have been demonstrated for HPSCs using 1D ETLs. Despite the advantages of 1D ETLs, there are still challenges that need to be overcome to achieve even higher PCEs, such as better methods to eliminate or passivate surface traps, improved understanding of the hetero-interface and optimization of the morphology (i.e., length, diameter, and spacing of NWs/NTs). This review introduces the general considerations of ETLs for HPSCs, deposition techniques used, and the current research and challenges in the field of 1D ETLs for perovskite solar cells. PMID:28468280

  15. One-Dimensional Electron Transport Layers for Perovskite Solar Cells

    Directory of Open Access Journals (Sweden)

    Ujwal K. Thakur

    2017-04-01

    Full Text Available The electron diffusion length (Ln is smaller than the hole diffusion length (Lp in many halide perovskite semiconductors meaning that the use of ordered one-dimensional (1D structures such as nanowires (NWs and nanotubes (NTs as electron transport layers (ETLs is a promising method of achieving high performance halide perovskite solar cells (HPSCs. ETLs consisting of oriented and aligned NWs and NTs offer the potential not merely for improved directional charge transport but also for the enhanced absorption of incoming light and thermodynamically efficient management of photogenerated carrier populations. The ordered architecture of NW/NT arrays affords superior infiltration of a deposited material making them ideal for use in HPSCs. Photoconversion efficiencies (PCEs as high as 18% have been demonstrated for HPSCs using 1D ETLs. Despite the advantages of 1D ETLs, there are still challenges that need to be overcome to achieve even higher PCEs, such as better methods to eliminate or passivate surface traps, improved understanding of the hetero-interface and optimization of the morphology (i.e., length, diameter, and spacing of NWs/NTs. This review introduces the general considerations of ETLs for HPSCs, deposition techniques used, and the current research and challenges in the field of 1D ETLs for perovskite solar cells.

  16. One-Dimensional Electron Transport Layers for Perovskite Solar Cells.

    Science.gov (United States)

    Thakur, Ujwal K; Kisslinger, Ryan; Shankar, Karthik

    2017-04-29

    The electron diffusion length ( L n ) is smaller than the hole diffusion length ( L p ) in many halide perovskite semiconductors meaning that the use of ordered one-dimensional (1D) structures such as nanowires (NWs) and nanotubes (NTs) as electron transport layers (ETLs) is a promising method of achieving high performance halide perovskite solar cells (HPSCs). ETLs consisting of oriented and aligned NWs and NTs offer the potential not merely for improved directional charge transport but also for the enhanced absorption of incoming light and thermodynamically efficient management of photogenerated carrier populations. The ordered architecture of NW/NT arrays affords superior infiltration of a deposited material making them ideal for use in HPSCs. Photoconversion efficiencies (PCEs) as high as 18% have been demonstrated for HPSCs using 1D ETLs. Despite the advantages of 1D ETLs, there are still challenges that need to be overcome to achieve even higher PCEs, such as better methods to eliminate or passivate surface traps, improved understanding of the hetero-interface and optimization of the morphology (i.e., length, diameter, and spacing of NWs/NTs). This review introduces the general considerations of ETLs for HPSCs, deposition techniques used, and the current research and challenges in the field of 1D ETLs for perovskite solar cells.

  17. Employment and turnover in the transport and logistics sector in the STRING region

    DEFF Research Database (Denmark)

    Serin, Göran Folke; Holzweber, Markus

    development’. The purpose of the first re- port was to analyse the conditions for European transport and logistics in the STRING region. The purpose of this second report is to analyse the strength and competencies within the freight transport and logistics sector in the STRING region. This means basic...... conditions when analysing the possibilities of establishing a ‘Green Transport Corridor’. The analysis will take its point of departure in analysis of employment, turnover, firm structure and location within the freight transport and logistics sector in the STRING region....

  18. Disorder and transport of silver in some layered metal sulfides

    NARCIS (Netherlands)

    Gerards, Anthonius Gijsbertus

    1987-01-01

    The chemical and physical properties of compounds with a layered structure are strongly determined by the two-dimensional nature of the bonding, viz. strong bonding within the layers and much weaker bonds between the layers; graphite is an example of such and anisotropic solid. the layered

  19. CROSS LAYERED HYBRID TRANSPORT LAYER PROTOCOL APPROACH TO ENHANCE NETWORK UTILISATION FOR VIDEO TRAFFIC

    Directory of Open Access Journals (Sweden)

    Matilda.S

    2010-03-01

    Full Text Available Video data transfer is the major traffic in today’s Internet. With the emerging need for anytime anywhere communication, applications transmitting video is gaining momentum. Real Time Protocol is the primary standard for transfer of video data, as; it requires timely delivery and can tolerate loss of packets. Streaming is the method used for delivering video content from the source server to the user. But this has many drawbacks: a It sends only the amount of data equivalent to the streaming encoded rate to the client irrespective of the available bandwidth in the path. Hence the links are underutilized; b It utilizes the link for the entire period of transfer and hence the link is not available to service other new clients. Thus as the number of clients increases, the network performance decreases. In this work, the advantages and disadvantages of the combination of different protocols in the application layer and transport layer are analyzed. The significant characteristics of each of these protocols are utilized and a combination of protocols for improving the network performance is arrived at, while retaining the QoS of video transmission.

  20. Layered bismuth selenide utilized as hole transporting layer for highly stable organic photovoltaics

    KAUST Repository

    Yuan, Zhongcheng

    2015-11-01

    Abstract Layered bismuth selenide (L-Bi2Se3) nanoplates were implemented as hole transporting layers (HTLs) for inverted organic solar cells. Device based on L-Bi2Se3 showed increasing power conversion efficiency (PCE) during ambient condition storage process. A PCE of 4.37% was finally obtained after 5 days storage, which outperformed the ones with evaporated-MoO3 using poly(3-hexylthiophene) (P3HT) as donor material and [6,6]-phenyl-C61-butyric acid methyl ester (PC61BM) as acceptor. The improved device efficiency can be attributed to the high conductivity and increasing work function of L-Bi2Se3. The work function of L-Bi2Se3 increased with the storage time in ambient condition due to the oxygen atom doping. Ultraviolet photoelectron spectroscopy and high resolution X-ray photoelectron spectroscopy were conducted to verify the increased work function, which originated from the p-type doping process. The device based on L-Bi2Se3 exhibited excellent stability in ambient condition up to 4 months, which was much improved compared to the device based on traditional HTLs. © 2015 Elsevier B.V.

  1. Inefficient Angular Momentum Transport in Accretion Disk Boundary Layers: Angular Momentum Belt in the Boundary Layer

    Science.gov (United States)

    Belyaev, Mikhail A.; Quataert, Eliot

    2018-04-01

    We present unstratified 3D MHD simulations of an accretion disk with a boundary layer (BL) that have a duration ˜1000 orbital periods at the inner radius of the accretion disk. We find the surprising result that angular momentum piles up in the boundary layer, which results in a rapidly rotating belt of accreted material at the surface of the star. The angular momentum stored in this belt increases monotonically in time, which implies that angular momentum transport mechanisms in the BL are inefficient and do not couple the accretion disk to the star. This is in spite of the fact that magnetic fields are advected into the BL from the disk and supersonic shear instabilities in the BL excite acoustic waves. In our simulations, these waves only carry a small fraction (˜10%) of the angular momentum required for steady state accretion. Using analytical theory and 2D viscous simulations in the R - ϕ plane, we derive an analytical criterion for belt formation to occur in the BL in terms of the ratio of the viscosity in the accretion disk to the viscosity in the BL. Our MHD simulations have a dimensionless viscosity (α) in the BL that is at least a factor of ˜100 smaller than that in the disk. We discuss the implications of these results for BL dynamics and emission.

  2. Perpendicular Magnetic Anisotropy in FePt Patterned Media Employing a CrV Seed Layer

    Directory of Open Access Journals (Sweden)

    Chun Dong

    2011-01-01

    Full Text Available Abstract A thin FePt film was deposited onto a CrV seed layer at 400°C and showed a high coercivity (~3,400 Oe and high magnetization (900–1,000 emu/cm3 characteristic of L10 phase. However, the magnetic properties of patterned media fabricated from the film stack were degraded due to the Ar-ion bombardment. We employed a deposition-last process, in which FePt film deposited at room temperature underwent lift-off and post-annealing processes, to avoid the exposure of FePt to Ar plasma. A patterned medium with 100-nm nano-columns showed an out-of-plane coercivity fivefold larger than its in-plane counterpart and a remanent magnetization comparable to saturation magnetization in the out-of-plane direction, indicating a high perpendicular anisotropy. These results demonstrate the high perpendicular anisotropy in FePt patterned media using a Cr-based compound seed layer for the first time and suggest that ultra-high-density magnetic recording media can be achieved using this optimized top-down approach.

  3. Capillary flows across layers and textural interfaces - Pathways and colloid transport considerations in unsaturated layered porous media.

    Science.gov (United States)

    Hoogland, Frouke; Lehmann, Peter; Or, Dani

    2017-10-15

    Soils and other geologic porous media often display layering and associated textural contrasts that may alter unsaturated flow and transport pathways. Such natural interfaces are usually represented empirically in continuum flow models with limited mechanistic account of the effect of adjusted pathways across layers on colloid transport and on the nature of unsaturated flow. In this study we present the soil foam drainage equation (SFDE) as alternative framework to simulate unsaturated flow in layered porous media. In contrast to standard continuum flow models, the SFDE explicitly accounts for capillary flow pathways and their adjustment across textural interfaces that in turn define flow geometry for colloidal transport not predicted by continuum models. Pore scale water distribution in a layered sand sample was measured using X-ray tomography to quantify capillary flow pathways. Literature values of measured saturation and capillary pressure profiles in layered porous columns were used to evaluate solutions based on the SFDE framework and to deduce velocity profiles and their effects for colloid transport. The SFDE framework provides new insights into capillary architecture in unsaturated layered media and opens a new way for using pore scale information (from imaging) to provide the necessary SFDE parameters and potentially improve on the standard continuum representation of capillary flows in layered media. Copyright © 2017 Elsevier Inc. All rights reserved.

  4. Deposition of durable thin silver layers onto polyamides employing a heterogeneous Tollens’ reaction

    Science.gov (United States)

    Textor, Torsten; Fouda, Moustafa M. G.; Mahltig, Boris

    2010-02-01

    Tollens' reaction is a well-known reaction employed in chemical analyses to detect reducing groups—basically aldehydes. If aldehydes are available in a solution these will reduce silver(I) ions to silver(0). The present paper describes an approach to use a heterogeneous Tollens' reaction to establish thin layers of silver on polyamide surfaces. The polyamide surface is modified with aldehyde functions in a first step employing glutaraldehyde. The resulting polymer material is therefore equipped with reducing groups necessary for the reduction of silver in a next step. The polymer is subsequently treated with Tollens' reagent yielding a yellow/brownish colour typical for the surface plasmon resonance of silver. The extend of the colouring - indicating the amount of silver deposited - varies with both the concentration of the Tollens' reagent and the concentration of the glutaraldehyde solution used for the pre-treatment. The as-prepared samples not only show an excellent antimicrobial activity but also an enormous durability. Polyamide textiles that were treated with the described approach showed unchanged efficiency even after 30 laundry cycles.

  5. Electrical and optical transport properties of single layer WSe2

    Science.gov (United States)

    Tahir, M.

    2018-03-01

    The electronic properties of single layer WSe2 are distinct from the famous graphene due to strong spin orbit coupling, a huge band gap and an anisotropic lifting of the degeneracy of the valley degree of freedom under Zeeman field. In this work, band structure of the monolayer WSe2 is evaluated in the presence of spin and valley Zeeman fields to study the electrical and optical transport properties. Using Kubo formalism, an explicit expression for the electrical Hall conductivity is examined at finite temperatures. The electrical longitudinal conductivity is also evaluated. Further, the longitudinal and Hall optical conductivities are analyzed. It is observed that the contributions of the spin-up and spin-down states to the power absorption spectrum depend on the valley index. The numerical results exhibit absorption peaks as a function of photon energy, ℏ ω, in the range ∼ 1.5 -2 eV. Also, the optical response lies in the visible frequency range in contrast to the conventional two-dimensional electron gas or graphene where the response is limited to terahertz regime. This ability to isolate carriers in spin-valley coupled structures may make WSe2 a promising candidate for future spintronics, valleytronics and optical devices.

  6. Literature review on employment impacts of GHG reduction policies for transport

    Energy Technology Data Exchange (ETDEWEB)

    De Bruyn, S.; Brinke, L.; Kampman, B.; Koopman, M.

    2012-07-15

    Recently a large number of studies have been published that claim accelerated uptake of electrical vehicles (EVs) and fuel efficient cars in the market for automotive transport may have positive employment benefits. A literature review on this issue has been undertaken by CE Delft, to investigate if it is possible to determine whether a large-scale switch to advanced powertrains would yield positive employment benefits. The key conclusion from the study is that employment benefits are likely to result from CO2 regulations.

  7. Quantifying the transport of subcloud layer reactants by shallow cimulus clouds over the Amazon

    NARCIS (Netherlands)

    Ouwersloot, H.G.; Vilà-Guerau De Arellano, J.; Stratum, van B.J.H.; Krol, M.C.; Lelieveld, J.

    2013-01-01

    We investigate the vertical transport of atmospheric chemical reactants from the subcloud layer to the cumulus cloud layer driven by shallow convection over the Amazon during the dry season. The dynamical and chemical assumptions needed for mesoscale and global chemistry transport model

  8. Degradation Effects Related to the Hole Transport Layer in Organic Solar Cells

    NARCIS (Netherlands)

    Ecker, Bernhard; Nolasco, Jairo Cesar; Pallares, Josep; Marsal, Lluis Francesc; Posdorfer, Joerg; Parisi, Juergen; von Hauff, Elizabeth

    2011-01-01

    The influence of the hole transport layer on device stability in polymer:fullerene bulk-heterojunction solar cells is reported. Three different hole transport layers varying in composition, dispersion solvent, electrical conductivity, and work function were used in these studies. Two water-based

  9. Morphologically controlled fuel cell transport layers enabled via electrospun carbon nonwovens

    Science.gov (United States)

    Todd, Devin; Mérida, Walter

    2015-01-01

    We report on the synthesis and performance of carbon nanofibre substrates for PEM fuel cell transport layer applications. Electrospinning is used for fabrication; by manipulation of spinning properties, morphological control is demonstrated in the product. Our application of the technology and it's manipulability to PEMFC transport layers constitutes a novel approach to the manufacture of such layers. Ex-situ morphology, electrical resistance and water contact angles are reported in additional to in-situ hydrogen/air fuel cell performance. Electrospun transport layers are compared directly to established commercial products in a cathode PTL role. The electrospun transport layers demonstrate approximately 85% of the commercial limiting current density, swifter water transport characteristics, and markedly more stable operating points.

  10. Bimetallic nanocomposite as hole transport co-buffer layer in organic solar cell

    Science.gov (United States)

    Mola, Genene Tessema; Arbab, Elhadi A. A.

    2017-12-01

    Silver-zinc bimetallic nanocomposite (Ag:Zn BiM-NPs) was used as an inter-facial buffer layer in the preparation of thin film organic solar cell (TFOSC). The current investigation focuses on the effect of bimetallic nanoparticles on the performance of TFOSC. A number experiments were conducted by employing Ag:Zn nanocomposite buffer layer of thickness 1 nm at various positions of the device structure. In all cases, we found significant improvement on the power conversion efficiency of the solar cells. It is also noted that the open circuit voltage of the devices are decreasing when Ag:Zn form direct contact with the ITO electrode and without the inclusion of PEDOT:PSS. However, all results show that the introduction of Ag:Zn nanocomposite layer close to PEDOT:PSS could be beneficial to improve the charge transport processes in the preparation of thin film organic solar cell. The Ag:Zn BiM-NPs and the device properties were presented and discussed in terms of optical, electrical and film morphologies of the devices.

  11. Interfacial engineering of electron transport layer using Caesium Iodide for efficient and stable organic solar cells

    Science.gov (United States)

    Upama, Mushfika Baishakhi; Elumalai, Naveen Kumar; Mahmud, Md Arafat; Wright, Matthew; Wang, Dian; Xu, Cheng; Haque, Faiazul; Chan, Kah Howe; Uddin, Ashraf

    2017-09-01

    Polymer solar cells (PSCs) have gained immense research interest in the recent years predominantly due to low-cost, solution process-ability, and facile device fabrication. However, achieving high stability without compromising the power conversion efficiency (PCE) serves to be an important trade-off for commercialization. In line with this, we demonstrate the significance of incorporating a CsI/ZnO bilayer as electron transport layer (ETL) in the bulk heterojunction PSCs employing low band gap polymer (PTB7) and fullerene (PC71BM) as the photo-active layer. The devices with CsI/ZnO interlayer exhibited substantial enhancement of 800% and 12% in PCE when compared to the devices with pristine CsI and pristine ZnO as ETL, respectively. Furthermore, the UV and UV-ozone induced degradation studies revealed that the devices incorporating CsI/ZnO bilayer possess excellent decomposition stability (∼23% higher) over the devices with pristine ZnO counterparts. The incorporation of CsI between ITO and ZnO was found to favorably modify the energy-level alignment at the interface, contributing to the charge collection efficiency as well as protecting the adjacent light absorbing polymer layers from degradation. The mechanism behind the improvement in PCE and stability is analyzed using the electrochemical impedance spectroscopy and dark I-V characteristics.

  12. Optoelectronic devices, low temperature preparation methods, and improved electron transport layers

    KAUST Repository

    Eita, Mohamed S.

    2016-08-04

    An optoelectronic device such as a photovoltaic device which has at least one layer, such as an electron transport layer, which comprises a plurality of alternating, oppositely charged layers including metal oxide layers. The metal oxide can be zinc oxide. The plurality of layers can be prepared by layer-by-layer processing in which alternating layers are built up step-by-step due to electrostatic attraction. The efficiency of the device can be increased by this processing method compared to a comparable method like sputtering. The number of layers can be controlled to improve device efficiency. Aqueous solutions can be used which is environmentally friendly. Annealing can be avoided. A quantum dot layer can be used next to the metal oxide layer to form a quantum dot heterojunction solar device.

  13. Modeling methane fluxes in wetlands with gas-transporting plants 2. Soil layer scale

    NARCIS (Netherlands)

    Segers, R; Rappoldt, C; Leffelaar, PA

    2001-01-01

    Methane dynamics in a water-saturated soil layer with gas-transporting roots is modeled with a weighed set of single-loot model systems. Each model system consists of a soil cylinder with a gas-transporting root along its axis or a soil sphere with a gas-transporting root at its centre. The weights

  14. Connecting meteorology to surface transport in aeolian landscapes: Peering into the boundary layer with Doppler lidar

    Science.gov (United States)

    Gunn, A.; Jerolmack, D. J.; Edmonds, D. A.; Ewing, R. C.; Wanker, M.; David, S. R.

    2017-12-01

    Aolian sand dunes grow to 100s or 1000s of meters in wavelength by sand saltation, which also produces dust plumes that feed cloud formation and may spread around the world. The relations among sediment transport, landscape dynamics and wind are typically observed at the limiting ends of the relevant range: highly resolved and localized ground observations of turbulence and relevant fluxes; or regional and synoptic-scale meteorology and satellite imagery. Between the geostrophic winds aloft and shearing stress on the Earth's surface is the boundary layer, whose stability and structure determines how momentum is transferred and ultimately entrains sediment. Although the literature on atmospheric boundary layer flows is mature, this understanding is rarely applied to aeolian landscape dynamics. Moreover, there are few vertically and time-resolved datasets of atmospheric boundary layer flows in desert sand seas, where buoyancy effects are most pronounced. Here we employ a ground-based upward-looking doppler lidar to examine atmospheric boundary layer flow at the upwind margin of the White Sands (New Mexico) dune field, providing continuous 3D wind velocity data from the surface to 300-m aloft over 70 days of the characteristically windy spring season. Data show highly resolved daily cyles of convective instabilty due to daytime heating and stable stratification due to nightime cooling which act to enhance or depress, respectively, the surface wind stresses for a given free-stream velocity. Our data implicate convective instability in driving strong saltation and dust emission, because enhanced mixing flattens the vertical velocity profile (raising surface wind speed) while upward advection helps to deliver dust to the high atmosphere. We also find evidence for Ekman spiralling, with a magnitude that depends on atmospheric stability. This spiralling gives rise to a deflection in the direction between geostrophic and surface winds, that is significant for the

  15. All-inorganic quantum-dot light-emitting-diodes with vertical nickel oxide nanosheets as hole transport layer

    Directory of Open Access Journals (Sweden)

    Jiahui Li

    2016-10-01

    Full Text Available All-inorganic quantum dot light emitting diodes (QLEDs have gained great attention as a result of their high stability under oxygen-rich, humid and high current working conditions. In this work, we have fabricated an all-inorganic QLED device (FTO/NiO/QDs/AZO/Ag with sandwich-structure, wherein the inorganic metal oxides thin films of NiO and AZO were employed as hole and electron transport layers, respectively. The porous NiO layer with vertical lamellar nanosheets interconnected microstructure have been directly synthesized on the substrate of conductive FTO glass and increased the wettability of CdSe@ZnS QDs, which result in an enhancement of current transport performance of the QLED.

  16. Physics and modelling of scrape-off layer transport

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, R.H.; Allen, S.L.; Crotinger, J.A.; Kaiser, T.B.; Milovich, J.L.; Mattor, N.; Nevins, W.M.; Porter, G.D.; Rensink, M.E.; Rognlien, T.D. [Lawrence Livermore National Lab., CA (United States); Berk, H.L. [Texas Univ., Austin, TX (United States). Inst. for Fusion Studies; Campbell, R.B. [Sandia National Labs., Albuquerque, NM (United States); Diamond, P.H.; Rosenbluth, M.N. [California Univ., San Diego, CA (United States); Hinton, F.L.; Staebler, G.M. [General Atomics, San Diego, CA (United States); Knoll, D.A. [EG and G Idaho, Inc., Idaho Falls, ID (United States); Modi, B.; Xu, X.Q. [California Univ., Berkeley, CA (United States); Prinja, A.K. [New Mexico Univ., Albuquerque, NM (United States); Ryutov, D.D.; Tsidulko, Y.A. [Budker Institute of Nuclear Physics, Novosibirsk (Russia)

    1992-12-31

    We present studies of three schemes for reducing the peak heat flux on divertor plates, divertor biasing, impurity injection (``radiative divertor``) and neutral gas injection (``gas target divertor``). We report on theoretical analysis of a likely source of turbulent transport in the SOL and incorporation of the resultant transport coefficients into self-consistent models.

  17. Physics and modelling of scrape-off layer transport

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, R.H.; Allen, S.L.; Crotinger, J.A.; Kaiser, T.B.; Milovich, J.L.; Mattor, N.; Nevins, W.M.; Porter, G.D.; Rensink, M.E.; Rognlien, T.D. (Lawrence Livermore National Lab., CA (United States)); Berk, H.L. (Texas Univ., Austin, TX (United States). Inst. for Fusion Studies); Campbell, R.B. (Sandia National Labs., Albuquerque, NM (United States)); Diamond, P.H.; Rosenbluth, M.N. (California Univ., San Di

    1992-01-01

    We present studies of three schemes for reducing the peak heat flux on divertor plates, divertor biasing, impurity injection ( radiative divertor'') and neutral gas injection ( gas target divertor''). We report on theoretical analysis of a likely source of turbulent transport in the SOL and incorporation of the resultant transport coefficients into self-consistent models.

  18. Physics and modelling of scrape-off layer transport

    International Nuclear Information System (INIS)

    Cohen, R.H.; Allen, S.L.; Crotinger, J.A.; Kaiser, T.B.; Milovich, J.L.; Mattor, N.; Nevins, W.M.; Porter, G.D.; Rensink, M.E.; Rognlien, T.D.; Berk, H.L.; Diamond, P.H.; Rosenbluth, M.N.; Hinton, F.L.; Staebler, G.M.; Knoll, D.A.; Modi, B.; Xu, X.Q.; Prinja, A.K.; Ryutov, D.D.; Tsidulko, Y.A.

    1992-01-01

    We present studies of three schemes for reducing the peak heat flux on divertor plates, divertor biasing, impurity injection (''radiative divertor'') and neutral gas injection (''gas target divertor''). We report on theoretical analysis of a likely source of turbulent transport in the SOL and incorporation of the resultant transport coefficients into self-consistent models

  19. Reduced workfunction intermetallic seed layers allow growth of porous n-GaN and low resistivity, ohmic electron transport.

    Science.gov (United States)

    Bilousov, Oleksandr V; Carvajal, Joan J; Drouin, Dominique; Mateos, Xavier; Díaz, Francesc; Aguiló, Magdalena; O'Dwyer, Colm

    2012-12-01

    Porous GaN crystals have been successfully grown and electrically contacted simultaneously on Pt- and Au-coated silicon substrates as porous crystals and as porous layers. By the direct reaction of metallic Ga and NH(3) gas through chemical vapor deposition, intermetallic metal-Ga alloys form at the GaN-metal interface, allowing vapor-solid-solid seeding and subsequent growth of porous GaN. Current-voltage and capacitance-voltage measurements confirm that the intermetallic seed layers prevent interface oxidation and give a high-quality reduced workfunction contact that allows exceptionally low contact resistivities. Additionally, the simultaneous formation of a lower workfunction intermetallic permits ohmic electron transport to n-type GaN grown using high workfunction metals that best catalyze the formation of porous GaN layers and may be employed to seed and ohmically contact a range of III-N compounds and alloys for broadband absorption and emission.

  20. Color stable white phosphorescent organic light emitting diodes with red emissive electron transport layer

    Energy Technology Data Exchange (ETDEWEB)

    Wook Kim, Jin; Yoo, Seung Il; Sung Kang, Jin [Department of Green Energy & Semiconductor Engineering, Hoseo University, Asan 336-795 (Korea, Republic of); Eun Lee, Song; Kwan Kim, Young [Department of Information Display, Hongik University, Seoul 121-791 (Korea, Republic of); Hwa Yu, Hyeong; Turak, Ayse [Department of Engineering Physics, McMaster University, Hamilton, Ontario L8S 4L7 (Canada); Young Kim, Woo, E-mail: wykim@hoseo.edu [Department of Green Energy & Semiconductor Engineering, Hoseo University, Asan 336-795 (Korea, Republic of); Department of Engineering Physics, McMaster University, Hamilton, Ontario L8S 4L7 (Canada)

    2015-06-28

    We analyzed the performance of multi-emissive white phosphorescent organic light-emitting diodes (PHOLEDs) in relation to various red emitting sites of hole and electron transport layers (HTL and ETL). The shift of the recombination zone producing stable white emission in PHOLEDs was utilized as luminance was increased with red emission in its electron transport layer. Multi-emissive white PHOLEDs including the red light emitting electron transport layer yielded maximum external quantum efficiency of 17.4% with CIE color coordinates (−0.030, +0.001) shifting only from 1000 to 10 000 cd/m{sup 2}. Additionally, we observed a reduction of energy loss in the white PHOLED via Ir(piq){sub 3} as phosphorescent red dopant in electron transport layer.

  1. Common-User Land Transportation Management in the Layered, Non-Linear, Non-Contiguous Battlefield

    National Research Council Canada - National Science Library

    Strobel, Lawrence E

    2005-01-01

    .... Current multinational counterinsurgency warfare occurs in a layered, non-linear, non-contiguous battle space, making management of ground transportation assets even more critical than in conventional warfare...

  2. Quantum transport in superconducting hybrids : Molecular devices and layered materials

    NARCIS (Netherlands)

    Island, J.O.

    2016-01-01

    In this thesis we investigate superconducting hybrids made from two material systems, namely, molecules and layered materials. For studies of superconducting phenomena in molecular junctions we develop two platforms which rely on the superconducting proximity effect to preserve pre-existing nano-gap

  3. Modeling of Ultrathin Catalyst Layers in Polymer Electrolyte Fuel Cells: Proton Transport and Water Management

    OpenAIRE

    Chan, Karen Ka Wing

    2013-01-01

    Ultrathin catalyst layers (UTCLs) are emerging as a promising alternative to conventional catalyst layers in polymer electrolyte fuel cells. In comparison, UTCLs have dramatically reduced Pt loading and thicknesses and are ionomer–free. We explore two open questions in the theory of UTCLs (1) the proton transport mechanism within the ionomer–free layer and (2) water management in membrane electrode assemblies (MEAs) with UTCLs. To investigate (1), we present a UTCL model, which assumes the pr...

  4. Improving the photovoltaic parameters in Quantum dot sensitized solar cells through employment of chemically deposited compact titania blocking layer

    Energy Technology Data Exchange (ETDEWEB)

    Rajendra Prasad, M.B., E-mail: rajendraprasadmb75@gmail.com [Advanced Physics Laboratory, Department of Physics, SavitibaiPhule Pune University, Pune, 411007 (India); National Defence Academy, Khadakwasla, Pune, 411023 (India); Kadam, Vishal [Advanced Physics Laboratory, Department of Physics, SavitibaiPhule Pune University, Pune, 411007 (India); Joo, Oh-Shim [Korea Institute of Science and Technology, PO Box No. 131, Chongryang, Seoul, 130-650 (Korea, Republic of); Pathan, Habib M. [Advanced Physics Laboratory, Department of Physics, SavitibaiPhule Pune University, Pune, 411007 (India)

    2017-06-15

    Incorporation of compact blocking layer at the Transparent Conducting Oxide (TCO)/Electrolyte interface is an effective method to improve the device performance in QDSSC through mitigation of electron recombinations at this interface. This paper reports the most facile and cost effective method of depositing a rutile titania Compact Layer (CL) over Fluorine doped Tin Oxide (FTO) substrate and its application in titania based CdS QD sensitized solar cells. The deposited compact layers are characterized to study their structural, optical, morphological and electrochemical properties using X-Ray Diffractometry, UV–Visible spectroscopy, Scanning electron microscopy, Cyclic Voltammetry and Contact Angle measurements. Sandwich solar cells are fabricated using these CL based electrodes and characterized using Electrochemical Impedance Spectroscopy, Open Circuit Voltage Decay and J-V characteristics. The CL incorporated CdS QDSSC showed more than 100% increase in the photoconversion efficiency (1.68%) as compared to its bare FTO counterpart (0.73%) proving the efficacy of employed strategy. - Highlights: • Deposited titania compact layer by a facile room temperature chemical bath method. • Employed this to mitigate back electron transfer at TCO/Electrolyte interface. • Compact layer incorporation has improved the solar cell performance by 130%.

  5. Modeling of 1-D nitrate transport in single layer soils | Dike | Journal ...

    African Journals Online (AJOL)

    The transport of nitrate in laboratory single soil columns of sand, laterite and clay were investigated after 21 days. The 1-D contaminant transport model by Notodarmojo et al (1991) for single layer soils were calibrated and verified using field data collected from a refuse dump site at avu, owerri, Imo state. The experimental ...

  6. a transport layer protocol using adaptive loss recovery method for ...

    Indian Academy of Sciences (India)

    Ayhan Kİraz

    ALORT) has been developed for WSN. ... WSN; transport protocol; reliability; sensor network; bit error rate. 1. Introduction. In recent years, there have been ...... Services, Brussels, Belgium. [22] Wang C, Sohraby K and Li B 2005 SenTCP: a hop-by- ...

  7. Vortex-Transport Element Simulation of a Confined Mixing Layer

    Science.gov (United States)

    1988-11-01

    Vol. 125, pp. 397-410. Browand, F. E., and Ho, C.-M. (1983) Journal de Mecanique theorique et Aunliauee Numero Special, pp. 99-120. Chorin, A. J...layers was initiated by Givi and Jou (1988) using a hybrid pseudo-spectral second order finite difference scheme. In all cases, the Reynolds number was...confinement. Therefore, they can provide accurate simulations for high Reynolds number, spatially growing flows. Moreover, vortex methods optimize the

  8. OPTIMISATION OF BUFFER SIZE FOR ENHANCING QOS OF VIDEO TRAFFIC USING CROSS LAYERED HYBRID TRANSPORT LAYER PROTOCOL APPROACH

    Directory of Open Access Journals (Sweden)

    S. Matilda

    2011-03-01

    Full Text Available Video streaming is gaining importance, with the wide popularity of multimedia rich applications in the Internet. Video streams are delay sensitive and require seamless flow for continuous visualization. Properly designed buffers offer a solution to queuing delay. The diagonally opposite QoS metrics associated with video traffic poses an optimization problem, in the design of buffers. This paper is a continuation of our previous work [1] and deals with the design of buffers. It aims at finding the optimum buffer size for enhancing QoS offered to video traffic. Network-centric QoS provisioning approach, along with hybrid transport layer protocol approach is adopted, to arrive at an optimum size which is independent of RTT. In this combinational approach, buffers of routers and end devices are designed to satisfy the various QoS parameters at the transport layer. OPNET Modeler is used to simulate environments for testing the design. Based on the results of simulation it is evident that the hybrid transport layer protocol approach is best suited for transmitting video traffic as it supports the economical design.

  9. Heat and Moisture Transport in the Atmospheric Boundary Layer.

    Science.gov (United States)

    1987-01-05

    rst = r i, there can be isothermal flow. Here ri is defined as: ri = ( pcp /(Ry))(psv-pv), where y is the psychometric constant y = pc/(e) - (usually in...0. Thence, since Dral’t cc - ftlr and Dri/aq -c -8 6F/Fe ~ -Fq/Fq = 0(1/2 Bt/t, (- Pcp /R) (A/ra) 80, Sq/q), depending which term is most significant...Then the "Prandtl transposition theorem " (Rosenhead, sec.V.8, also valid in three dimensions) of laminar boundary layer theory is also applicable to

  10. Investigation on the effect of employing nano-fibrous structure as a scattering layer in dye sensitized solar cells

    International Nuclear Information System (INIS)

    Rahimi, S.; Mohammadpour, R.; Iraji zad, A.

    2012-01-01

    TiO 2 nano fibers with different diameters have been fabricated through electro-spinning method and employed as a scattering layer in dye sensitized solar cell. The amount of scattering from nano-fibrous layers depends on their diameters; Because of various ability of light collection in fibers with different diameters, it can directly influence the solar cell performance. In this study, we have studied the optical and electrical properties of TiO 2 nano fibers and solar cells based on these structures have been fabricated and characterized. Finally, by optimizing the structure of scattering layer, maximum efficiency of 6.8 p ercent h as been achieved using fibers in range of 200-350 nm diameter.

  11. Chemical Vapor Transport Deposition of Molybdenum Disulfide Layers Using H2O Vapor as the Transport Agent

    Directory of Open Access Journals (Sweden)

    Shichao Zhao

    2018-02-01

    Full Text Available Molybdenum disulfide (MoS2 layers show excellent optical and electrical properties and have many potential applications. However, the growth of high-quality MoS2 layers is a major bottleneck in the development of MoS2-based devices. In this paper, we report a chemical vapor transport deposition method to investigate the growth behavior of monolayer/multi-layer MoS2 using water (H2O as the transport agent. It was shown that the introduction of H2O vapor promoted the growth of MoS2 by increasing the nucleation density and continuous monolayer growth. Moreover, the growth mechanism is discussed.

  12. Improved air stability of perovskite solar cells via solution-processed metal oxide transport layers

    Science.gov (United States)

    You, Jingbi; Meng, Lei; Song, Tze-Bin; Guo, Tzung-Fang; Yang, Yang (Michael); Chang, Wei-Hsuan; Hong, Ziruo; Chen, Huajun; Zhou, Huanping; Chen, Qi; Liu, Yongsheng; De Marco, Nicholas; Yang, Yang

    2016-01-01

    Lead halide perovskite solar cells have recently attracted tremendous attention because of their excellent photovoltaic efficiencies. However, the poor stability of both the perovskite material and the charge transport layers has so far prevented the fabrication of devices that can withstand sustained operation under normal conditions. Here, we report a solution-processed lead halide perovskite solar cell that has p-type NiOx and n-type ZnO nanoparticles as hole and electron transport layers, respectively, and shows improved stability against water and oxygen degradation when compared with devices with organic charge transport layers. Our cells have a p-i-n structure (glass/indium tin oxide/NiOx/perovskite/ZnO/Al), in which the ZnO layer isolates the perovskite and Al layers, thus preventing degradation. After 60 days storage in air at room temperature, our all-metal-oxide devices retain about 90% of their original efficiency, unlike control devices made with organic transport layers, which undergo a complete degradation after just 5 days. The initial power conversion efficiency of our devices is 14.6 ± 1.5%, with an uncertified maximum value of 16.1%.

  13. Zwitter-Ionic Polymer Applied as Electron Transportation Layer for Improving the Performance of Polymer Solar Cells

    Directory of Open Access Journals (Sweden)

    Qiaoyun Chen

    2017-11-01

    Full Text Available A zwitter-ionic polymer poly (sulfobetaine methacrylate (denoted by PSBMA was employed as an electron transportation layer (ETL in polymer solar cells (PSCs based on poly(3-hexylthiophene (P3HT:[6,6]-phenyl-C61-butyric acid methyl ester (PC61BM. PSBMA is highly soluble in trifluoroethanol, showing an orthogonal solubility to the solvent of the active layer in the preparation of multilayered PSCs. Upon introduction of PSBMA, the short circuit current and as a consequence the power conversion efficiency of the corresponding PSCs are dramatically improved, which can be because of the relatively high polarity of PSBMA compared with the other ETLs. This study demonstrated that zwitter-ionic polymer should be a competitive potential candidate of ETLs in PSCs.

  14. Electronic structure, transport, and collective effects in molecular layered systems

    Directory of Open Access Journals (Sweden)

    Torsten Hahn

    2017-10-01

    Full Text Available The great potential of organic heterostructures for organic device applications is exemplified by the targeted engineering of the electronic properties of phthalocyanine-based systems. The transport properties of two different phthalocyanine systems, a pure copper phthalocyanine (CoPc and a flourinated copper phthalocyanine–manganese phthalocyanine (F16CoPc/MnPc heterostructure, are investigated by means of density functional theory (DFT and the non-equilibrium Green’s function (NEGF approach. Furthermore, a master-equation-based approach is used to include electronic correlations beyond the mean-field-type approximation of DFT. We describe the essential theoretical tools to obtain the parameters needed for the master equation from DFT results. Finally, an interacting molecular monolayer is considered within a master-equation approach.

  15. Convective transport in a porous medium layer saturated with a Maxwell nanofluid

    Directory of Open Access Journals (Sweden)

    J.C. Umavathi

    2016-01-01

    Full Text Available A linear and weakly non-linear stability analys is has been carried out to study the onset of convection in a horizontal layer of a porous medium saturated with a Maxwell nanofluid. To simulate the momentum equation in porous media, a modified Darcy–Maxwell nanofluid model incorporating the effects of Brownian motion and thermophoresis has been used. A Galerkin method has been employed to investigate the stationary and oscillatory convections; the stability boundaries for these cases are approximated by simple and useful analytical expressions. The stability of the system is investigated by varying various parameters viz., nanoparticle concentration Rayleigh number, Lewis number, modified diffusivity ratio, porosity, thermal capacity ratio, viscosity ratio, conductivity ratio, Vadász number and relaxation parameter. A representation of Fourier series method has been used to study the heat and mass transport on the non-linear stability analysis. The effect of transient heat and mass transport on various parameters is also studied. It is found that for stationary convection Lewis number, viscosity ratio and conductivity ratio have a stabilizing effect while nanoparticle concentration Rayleigh number Rn destabilizes the system. For oscillatory convection we observe that the conductivity ratio stabilizes the system whereas nanoparticle concentration Rayleigh number, Lewis number, Vadász number and relaxation parameter destabilize the system. The viscosity ratio increases the thermal Rayleigh number for oscillatory convection initially thus delaying the onset of convection and later decreases thus advancing the onset of convection hence showing a dual effect. For steady finite amplitude motions, the heat and mass transport decreases with an increase in the values of nanoparticle concentration Rayleigh number, Lewis number, viscosity ratio and conductivity ratio. The mass transport increases with an increase in Vadász number and relaxation

  16. Molecular Doping of the Hole-Transporting Layer for Efficient, Single-Step Deposited Colloidal Quantum Dot Photovoltaics

    KAUST Repository

    Kirmani, Ahmad R.

    2017-07-31

    Employment of thin perovskite shells and metal halides as surface-passivants for colloidal quantum dots (CQDs) have been important, recent developments in CQD optoelectronics. These have opened the route to single-step deposited high-performing CQD solar cells. These promising architectures employ a QD hole-transporting layer (HTL) whose intrinsically shallow Fermi level (EF) restricts band-bending at maximum power-point during solar cell operation limiting charge collection. Here, we demonstrate a generalized approach to effectively balance band-edge energy levels of the main CQD absorber and charge-transport layer for these high-performance solar cells. Briefly soaking the QD HTL in a solution of the metal-organic p-dopant, molybdenum tris(1-(trifluoroacetyl)-2-(trifluoromethyl)ethane-1,2-dithiolene), effectively deepens its Fermi level, resulting in enhanced band bending at the HTL:absorber junction. This blocks the back-flow of photo-generated electrons, leading to enhanced photocurrent and fill factor compared to undoped devices. We demonstrate 9.0% perovskite-shelled and 9.5% metal-halide-passivated CQD solar cells, both achieving ca. 10% relative enhancements over undoped baselines.

  17. Electrospun ZnO nanowire plantations in the electron transport layer for high-efficiency inverted organic solar cells.

    Science.gov (United States)

    Elumalai, Naveen Kumar; Jin, Tan Mein; Chellappan, Vijila; Jose, Rajan; Palaniswamy, Suresh Kumar; Jayaraman, Sundaramurthy; Raut, Hemant Kumar; Ramakrishna, Seeram

    2013-10-09

    Inverted bulk heterojunction organic solar cells having device structure ITO/ZnO/poly(3-hexylthiophene) (P3HT):[6,6]-phenyl C61 butyric acid methyl ester (PCBM) /MoO3/Ag were fabricated with high photoelectric conversion efficiency and stability. Three types of devices were developed with varying electron transporting layer (ETL) ZnO architecture. The ETL in the first type was a sol-gel-derived particulate film of ZnO, which in the second and third type contained additional ZnO nanowires of varying concentrations. The length of the ZnO nanowires, which were developed by the electrospinning technique, extended up to the bulk of the photoactive layer in the device. The devices those employed a higher loading of ZnO nanowires showed 20% higher photoelectric conversion efficiency (PCE), which mainly resulted from an enhancement in its fill factor (FF). Charge transport characteristic of the device were studied by transient photovoltage decay and charge extraction by linearly increasing voltage techniques. Results show that higher PCE and FF in the devices employed ZnO nanowire plantations resulted from improved charge collection efficiency and reduced recombination rate.

  18. Effects of the thickness of NiO hole transport layer on the performance of all-inorganic quantum dot light emitting diode

    International Nuclear Information System (INIS)

    Zhang, Xiao Li; Dai, Hai Tao; Zhao, Jun Liang; Li, Chen; Wang, Shu Guo; Sun, Xiao Wei

    2014-01-01

    All-inorganic quantum dot light emitting diodes (QLEDs) have recently gained great attention owing to their high stability under oxygenic, humid environment and higher operating currents. In this work, we fabricated all-inorganic CdSe/ZnS core-shell QLEDs composed of ITO/NiO/QDs/ZnO/Al, in which NiO and ZnO thin film deposited via all-solution method were employed as hole and electron transport layer, respectively. To achieve high light emitting efficiency, the balance transport between electrons and holes play a key role. In this work, the effects of the thickness of NiO film on the performance of QLEDs were explored experimentally in details. NiO layers with various thicknesses were prepared with different rotation speeds. Experimental results showed that thinner NiO layer deposited at higher rotation speed had higher transmittance and larger band gap. Four typical NiO thickness based QLEDs were fabricated to optimize the hole transport layer. Thinner NiO layer based device performs bright emission with high current injection, which is ascribed to the reduced barrier height between hole transport layer and quantum dot. - Highlights: • All-inorganic quantum dot light emitting diodes (QLEDs) were fabricated. • Thinner NiO film can effectively enhance on–off properties of devices. • Improved performance of QLEDs is mainly attributed to energy barrier reduction

  19. Charge-carrier transport in epitactical strontium titanate layers for the application in superconducting components

    International Nuclear Information System (INIS)

    Grosse, Veit

    2011-01-01

    In this thesis thin STO layers were epitactically deposited on YBCO for a subsequent electrical characterization. YBCO layers with a roughness of less than 2 nm (RMS), good out-of-plane orientation with a half-width in the rocking curve in the range (0.2..0.3) at only slightly diminished critical temperature could be reached. The STO layers exhibited also very good crystallographic properties. The charge-carrier transport in STO is mainly dominated by interface-limited processes. By means of an in thesis newly developed barrier model thereby the measured dependencies j(U,T) respectively σ(U,T) could be described very far-reachingly. At larger layer thicknesses and low temperatures the charge-carrier transport succeeds by hopping processes. So in the YBCO/STO/YBCO system the variable-range hopping could be identified as dominating transport process. Just above U>10 V a new behaviour is observed, which concerning its temperature dependence however is also tunnel-like. The STO layers exhibit here very large resistances, so that fields up to 10 7 ..10 8 V/m can be reached without flowing of significant leakage currents through the barrier. In the system YBCO/STO/Au the current transport can be principally in the same way as in the YBCO/STO/YBCO system. The special shape and above all the asymmetry of the barrier however work out very distinctly. It could be shown that at high temperatures according to the current direction a second barrier on the opposite electrode must be passed. So often observed breakdown effects can be well described. For STO layer-thicknesses in the range around 25 nm in the whole temperature range studied inelastic tunneling over chains of localized states was identified as dominating transport process. It could however for the first time be shown that at very low temperatures in the STO layers Coulomb blockades can be formed.

  20. Highly stable perovskite solar cells with an all-carbon hole transport layer

    Science.gov (United States)

    Wang, Feijiu; Endo, Masaru; Mouri, Shinichiro; Miyauchi, Yuhei; Ohno, Yutaka; Wakamiya, Atsushi; Murata, Yasujiro; Matsuda, Kazunari

    2016-06-01

    Nano-carbon materials (carbon nanotubes, graphene, and graphene oxide) have potential application for photovoltaics because of their excellent optical and electronic properties. Here, we demonstrate that a single-walled carbon nanotubes/graphene oxide buffer layer greatly improves the photovoltaic performance of organo-lead iodide perovskite solar cells. The carbon nanotubes/graphene oxide buffer layer works as an efficient hole transport/electron blocking layer. The photovoltaic conversion efficiency of 13.3% was achieved in the organo-lead iodide perovskite solar cell due to the complementary properties of carbon nanotubes and graphene oxide. Furthermore, the great improvement of photovoltaic performance stability in the perovskite solar cells using carbon nanotubes/graphene oxide/polymethyl methacrylate was demonstrated in comparison with that using a typical organic hole transport layer of 2,2',7,7'-tetrakis-(N,N-di-4-methoxyphenylamino)-9,9'-spirobifluorene.Nano-carbon materials (carbon nanotubes, graphene, and graphene oxide) have potential application for photovoltaics because of their excellent optical and electronic properties. Here, we demonstrate that a single-walled carbon nanotubes/graphene oxide buffer layer greatly improves the photovoltaic performance of organo-lead iodide perovskite solar cells. The carbon nanotubes/graphene oxide buffer layer works as an efficient hole transport/electron blocking layer. The photovoltaic conversion efficiency of 13.3% was achieved in the organo-lead iodide perovskite solar cell due to the complementary properties of carbon nanotubes and graphene oxide. Furthermore, the great improvement of photovoltaic performance stability in the perovskite solar cells using carbon nanotubes/graphene oxide/polymethyl methacrylate was demonstrated in comparison with that using a typical organic hole transport layer of 2,2',7,7'-tetrakis-(N,N-di-4-methoxyphenylamino)-9,9'-spirobifluorene. Electronic supplementary information (ESI

  1. Experimental validation of convection-diffusion discretisation scheme employed for computational modelling of biological mass transport

    Directory of Open Access Journals (Sweden)

    Ku David N

    2010-07-01

    Full Text Available Abstract Background The finite volume solver Fluent (Lebanon, NH, USA is a computational fluid dynamics software employed to analyse biological mass-transport in the vasculature. A principal consideration for computational modelling of blood-side mass-transport is convection-diffusion discretisation scheme selection. Due to numerous discretisation schemes available when developing a mass-transport numerical model, the results obtained should either be validated against benchmark theoretical solutions or experimentally obtained results. Methods An idealised aneurysm model was selected for the experimental and computational mass-transport analysis of species concentration due to its well-defined recirculation region within the aneurysmal sac, allowing species concentration to vary slowly with time. The experimental results were obtained from fluid samples extracted from a glass aneurysm model, using the direct spectrophometric concentration measurement technique. The computational analysis was conducted using the four convection-diffusion discretisation schemes available to the Fluent user, including the First-Order Upwind, the Power Law, the Second-Order Upwind and the Quadratic Upstream Interpolation for Convective Kinetics (QUICK schemes. The fluid has a diffusivity of 3.125 × 10-10 m2/s in water, resulting in a Peclet number of 2,560,000, indicating strongly convection-dominated flow. Results The discretisation scheme applied to the solution of the convection-diffusion equation, for blood-side mass-transport within the vasculature, has a significant influence on the resultant species concentration field. The First-Order Upwind and the Power Law schemes produce similar results. The Second-Order Upwind and QUICK schemes also correlate well but differ considerably from the concentration contour plots of the First-Order Upwind and Power Law schemes. The computational results were then compared to the experimental findings. An average error of 140

  2. Experimental validation of convection-diffusion discretisation scheme employed for computational modelling of biological mass transport.

    Science.gov (United States)

    Carroll, Gráinne T; Devereux, Paul D; Ku, David N; McGloughlin, Timothy M; Walsh, Michael T

    2010-07-19

    The finite volume solver Fluent (Lebanon, NH, USA) is a computational fluid dynamics software employed to analyse biological mass-transport in the vasculature. A principal consideration for computational modelling of blood-side mass-transport is convection-diffusion discretisation scheme selection. Due to numerous discretisation schemes available when developing a mass-transport numerical model, the results obtained should either be validated against benchmark theoretical solutions or experimentally obtained results. An idealised aneurysm model was selected for the experimental and computational mass-transport analysis of species concentration due to its well-defined recirculation region within the aneurysmal sac, allowing species concentration to vary slowly with time. The experimental results were obtained from fluid samples extracted from a glass aneurysm model, using the direct spectrophometric concentration measurement technique. The computational analysis was conducted using the four convection-diffusion discretisation schemes available to the Fluent user, including the First-Order Upwind, the Power Law, the Second-Order Upwind and the Quadratic Upstream Interpolation for Convective Kinetics (QUICK) schemes. The fluid has a diffusivity of 3.125 x 10-10 m2/s in water, resulting in a Peclet number of 2,560,000, indicating strongly convection-dominated flow. The discretisation scheme applied to the solution of the convection-diffusion equation, for blood-side mass-transport within the vasculature, has a significant influence on the resultant species concentration field. The First-Order Upwind and the Power Law schemes produce similar results. The Second-Order Upwind and QUICK schemes also correlate well but differ considerably from the concentration contour plots of the First-Order Upwind and Power Law schemes. The computational results were then compared to the experimental findings. An average error of 140% and 116% was demonstrated between the experimental

  3. 49 CFR 372.103 - Motor vehicles employed solely in transporting school children and teachers to or from school.

    Science.gov (United States)

    2010-10-01

    ... school children and teachers to or from school. 372.103 Section 372.103 Transportation Other Regulations... Exemptions § 372.103 Motor vehicles employed solely in transporting school children and teachers to or from school. The exemption set forth in 49 U.S.C. 13506(a)(1) shall not be construed as being inapplicable to...

  4. Magneto-transport properties of a random distribution of few-layer graphene patches

    International Nuclear Information System (INIS)

    Iacovella, Fabrice; Mitioglu, Anatolie; Pierre, Mathieu; Raquet, Bertrand; Goiran, Michel; Plochocka, Paulina; Escoffier, Walter; Trinsoutrot, Pierre; Vergnes, Hugues; Caussat, Brigitte; Conédéra, Véronique

    2014-01-01

    In this study, we address the electronic properties of conducting films constituted of an array of randomly distributed few layer graphene patches and investigate on their most salient galvanometric features in the moderate and extreme disordered limit. We demonstrate that, in annealed devices, the ambipolar behaviour and the onset of Landau level quantization in high magnetic field constitute robust hallmarks of few-layer graphene films. In the strong disorder limit, however, the magneto-transport properties are best described by a variable-range hopping behaviour. A large negative magneto-conductance is observed at the charge neutrality point, in consistency with localized transport regime

  5. Improved Efficiency of Polymer Solar Cells by means of Coating Hole Transporting Layer as Double Layer Deposition

    Science.gov (United States)

    Chonsut, T.; Kayunkid, N.; Rahong, S.; Rangkasikorn, A.; Wirunchit, S.; Kaewprajak, A.; Kumnorkaew, P.; Nukeaw, J.

    2017-09-01

    Polymer solar cells is one of the promising technologies that gain tremendous attentions in the field of renewable energy. Optimization of thickness for each layer is an important factor determining the efficiency of the solar cells. In this work, the optimum thickness of Poly(3,4-ethylenedioxythione): poly(styrenesulfonate) (PEDOT:PSS), a famous polymer widely used as hole transporting layer in polymer solar cells, is determined through the analyzing of device’s photovoltaic parameters, e.g. short circuit current density (Jsc), open circuit voltage (Voc), fill factor (FF) as well as power conversion efficiency (PCE). The solar cells were prepared with multilayer of ITO/PEDOT:PSS/PCDTBT:PC70BM/TiOx/Al by rapid convective deposition. In such preparation technique, the thickness of the thin film is controlled by the deposition speed. The faster deposition speed is used, the thicker film is obtained. Furthermore, double layer deposition of PEDOT:PSS was introduced as an approach to improve solar cell efficiency. The results obviously reveal that, with the increase of PEDOT:PSS thickness, the increments of Jsc and FF play the important role to improve PCE from 3.21% to 4.03%. Interestingly, using double layer deposition of PEDOT:PSS shows the ability to enhance the performance of the solar cells to 6.12% under simulated AM 1.5G illumination of 100 mW/cm2.

  6. Cross-field blob transport in tokamak scrape-off-layer plasmas

    International Nuclear Information System (INIS)

    D'Ippolito, D.A.; Myra, J.R.; Krasheninnikov, S.I.

    2002-01-01

    Recent measurements show that nondiffusive, intermittent transport of particles can play a major role in the scrape-off-layer (SOL) of fusion experiments. A possible mechanism for fast convective plasma transport is related to the plasma filaments or 'blobs' observed in the SOL with fast cameras and probes. In this paper, physical arguments suggesting the importance of blob transport [S. I. Krasheninnikov, Phys. Lett. A 283, 368 (2001)] have been extended by calculations using a three-field fluid model, treating the blobs as coherent propagating structures. The properties of density, temperature and vorticity blobs, and methods of averaging over ensembles of blobs to get the average SOL profiles, are illustrated. The role of ionization of background neutrals in sustaining the density blob transport is also discussed. Many qualitative features of the experiments, such as relatively flat density profiles and transport coefficients increasing toward the wall, are shown to emerge naturally from the blob transport paradigm

  7. Thermal transport in layered structure of YBa2Cu3O7-δ superconductors

    Science.gov (United States)

    Sharma, Rakhi; Indu, B. D.

    2017-12-01

    The heat transfer study in YBa2Cu3O7-δ superconductors structures is focused on the influence of the effect of scattering events in cross-plane and in-plane references. Understanding the mechanism of controlling the thermal conductivity of layered superconductors is an area of interest for nano microelectronics and thermo-electronic technological applications. The model of the thermal conduction, and phonon transport perpendicular and parallel to the layers of YBa2Cu3O7-δ are developed. It has been justified via numerical estimation and found substantial diminution in thermal conductivities in both in-plane and cross-plane directions of layered cuprate superconductors.

  8. The effect of interfacial layers on charge transport in organic solar cell

    Energy Technology Data Exchange (ETDEWEB)

    Mbuyise, Xolani G.; Tonui, Patrick; Mola, Genene Tessema, E-mail: mola@ukzn.ac.za

    2016-09-01

    The effect of interfacial buffer layers in organic photovoltaic cell (OPV) whose active layer is composed of poly(3 hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) blend was studied. The electrical properties of OPV devices produced with and without interfacial layers are compared and discussed in terms of measured parameters of the cells. The charge transport properties showed significant difference on the mobility and activation factor between the two types of device structures. The life time measurements in the unprotected conditions are also presented and discussed.

  9. Silicon transport in sputter-deposited tantalum layers grown under ion bombardment

    International Nuclear Information System (INIS)

    Gallais, P.; Hantzpergue, J.J.; Remy, J.C.; Roptin, D.

    1988-01-01

    Tantalum was sputter deposited on (111) Si substrate under low-energy ion bombardment in order to study the effects of the ion energy on the silicon transport into the Ta layer. The Si substrate was heated up to 500 0 C during growth. For ion energies up to 180 eV silicon is not transported into tantalum and the growth temperature has no effect. An ion bombardment energy of 280 eV enhances the transport of silicon throughout the tantalum layer. Growth temperatures up to 300 0 C have no effect on the silicon transport which is mainly enhanced by the ion bombardment. For growth temperatures between 300 and 500 0 C, the silicon transport is also enhanced by the thermal diffusion. The experimental depth distribution of silicon is similar to the theoretical depth distribution calculated for the case of an interdiffusion. The ion-enhanced process of silicon transport is characterized by an activation energy of 0.4 eV. Silicon into the layers as-grown at 500 0 C is in both states, amorphous silicide and microcrystalline cubic silicon

  10. Transport-driven formation of a polar ozone layer on Mars

    Science.gov (United States)

    Montmessin, Franck; Lefèvre, Franck

    2013-11-01

    Since the seasonal and spatial distribution of ozone on Mars was detected by the ultraviolet spectrometer onboard the spacecraft Mariner 7, our understanding has evolved considerably thanks to parallel efforts in observations and modelling. At low-to-mid latitudes, martian ozone is distributed vertically in two main layers, a near-surface layer and a layer at an altitude between 30 and 60km (ref. ). Here we report evidence from the SPICAM UV spectrometer onboard the Mars Express orbiter for the existence of a previously overlooked ozone layer that emerges in the southern polar night at 40-60km in altitude, with no counterpart observed at the north pole. Comparisons with global climate simulations for Mars indicate that this layer forms as a result of the large-scale transport of oxygen-rich air from sunlit latitudes to the poles, where the oxygen atoms recombine to form ozone during the polar night. However, transport-driven ozone formation is counteracted in our simulations by the destruction of ozone by reactions with hydrogen radicals, whose concentrations vary seasonally on Mars, reflecting seasonal variations of water vapour. We conclude that the observed dichotomy between the ozone layers of the two poles, with a significantly richer layer in the southern hemisphere, can be explained by the interplay of these mechanisms.

  11. Improvement of Power Efficiency in Phosphorescent White Organic Light-Emitting Diodes Using p-Doped Hole Transport Layer

    Directory of Open Access Journals (Sweden)

    Hyunkoo Lee

    2012-01-01

    Full Text Available We investigated the optical and electrical properties of molybdenum trioxide- (MoO3- doped (1,1-bis[(di-4-tolylaminophenyl]cyclohexane (TAPC films with different doping concentrations. Based on our results, we have fabricated white organic light emitting diodes (WOLEDs with multi-emitting layer structures that consist of 1,3-bis(9-carbazolylbenzene as a host and three phosphorescent dopants: iridium(III bis[4,6-difluorophenyl]-pyridinato-N,C2′] picolinate as a blue dopant, bis(2-phenylbenxothiozolato-N,C2′iridium(III (acetylacetonate as an orange dopant, and bis(1-phenylisoquinoline (acetylacetonate iridium(III as a red dopant. We improved the power efficiency and decreased driving voltage of WOLEDs by employing a MoO3-doped TAPC layer as a hole transport layer. The MoO3-doped TAPC layer lowers the driving voltage by about 1.2 V and increases the power efficiency from 6.2lm⋅W−1 to 7.9lm⋅W−1 at 1,000cd⋅m−2, an approximately 27.4% increase. Furthermore, the WOLED has a high color-rendering index, which is about 86 with the Commission Internationale de l’Eclairage 1931 chromatic coordinates of (0.4303, 0.3893 and correlated color temperature of 3008 K.

  12. Enhanced long-distance transport of periodic electron beams in an advanced double layer cone-channel target

    Directory of Open Access Journals (Sweden)

    Yanling Ji

    2018-02-01

    Full Text Available An enhanced long-distance transport of periodic electron beams in an advanced double layer cone-channel target is investigated using two-dimensional particle-in-cell simulations. The target consists of a cone attached to a double-layer hollow channel with a near-critical-density inner layer. The periodic electron beams are generated by the combination of ponderomotive force and longitudinal laser electric field. Then a stable electron propagation is achieved in the double-layer channel over a much longer distance without evident divergency, compared with a normal cone-channel target. Detailed simulations show that the much better long-distance collimation and guidance of energetic electrons is attributed to the much stronger electromagnetic fields at the inner wall surfaces. Furthermore, a continuous electron acceleration is obtained by the more intense laser electric fields and extended electron acceleration length in the channel. Our investigation shows that by employing this advanced target, both the forward-going electron energy flux in the channel and the energy coupling efficiency from laser to electrons are about threefold increased in comparison with the normal case.

  13. Enhanced long-distance transport of periodic electron beams in an advanced double layer cone-channel target

    Science.gov (United States)

    Ji, Yanling; Duan, Tao; Zhou, Weimin; Li, Boyuan; Wu, Fengjuan; Zhang, Zhimeng; Ye, Bin; Wang, Rong; Wu, Chunrong; Tang, Yongjian

    2018-02-01

    An enhanced long-distance transport of periodic electron beams in an advanced double layer cone-channel target is investigated using two-dimensional particle-in-cell simulations. The target consists of a cone attached to a double-layer hollow channel with a near-critical-density inner layer. The periodic electron beams are generated by the combination of ponderomotive force and longitudinal laser electric field. Then a stable electron propagation is achieved in the double-layer channel over a much longer distance without evident divergency, compared with a normal cone-channel target. Detailed simulations show that the much better long-distance collimation and guidance of energetic electrons is attributed to the much stronger electromagnetic fields at the inner wall surfaces. Furthermore, a continuous electron acceleration is obtained by the more intense laser electric fields and extended electron acceleration length in the channel. Our investigation shows that by employing this advanced target, both the forward-going electron energy flux in the channel and the energy coupling efficiency from laser to electrons are about threefold increased in comparison with the normal case.

  14. The Experimental Measurement of Local and Bulk Oxygen Transport Resistances in the Catalyst Layer of Proton Exchange Membrane Fuel Cells.

    Science.gov (United States)

    Wang, Chao; Cheng, Xiaojing; Lu, Jiabin; Shen, Shuiyun; Yan, Xiaohui; Yin, Jiewei; Wei, Guanghua; Zhang, Junliang

    2017-12-07

    Remarkable progress has been made in reducing the cathodic Pt loading of PEMFCs; however, a huge performance loss appears at high current densities, indicating the existence of a large oxygen transport resistance associated with the ultralow Pt loading catalyst layer. To reduce the Pt loading without sacrificing cell performance, it is essential to illuminate the oxygen transport mechanism in the catalyst layer. Toward this goal, an experimental approach to measure the oxygen transport resistance in catalyst layers is proposed and realized for the first time in this study. The measuring approach involves a dual-layer catalyst layer design, which consists of a dummy catalyst layer and a practical catalyst layer, followed by changing the thickness of dummy layer to respectively quantify the local and bulk resistances via limiting current measurements combined with linear extrapolation. The experimental results clearly reveal that the local resistance dominates the total resistance in the catalyst layer.

  15. Electronic spin transport and spin precession in single graphene layers at room temperature

    NARCIS (Netherlands)

    Tombros, Nikolaos; Jozsa, Csaba; Popinciuc, Mihaita; Jonkman, Harry T.; van Wees, Bart J.

    2007-01-01

    Electronic transport in single or a few layers of graphene is the subject of intense interest at present. The specific band structure of graphene, with its unique valley structure and Dirac neutrality point separating hole states from electron states, has led to the observation of new electronic

  16. Luminescent poly(p-phenylenevinylene) hole-transport layers with adjustable solubility

    NARCIS (Netherlands)

    Tanase, C; Wildeman, J; Blom, PWM

    2005-01-01

    The active part of present polymer light-emitting diodes (PLEDs) consists of only a single layer. Multilayer devices have the advantage that the electron and hole transport can be balanced and that the recombination can be removed from the metallic cathode, leading to highest efficiencies. A major

  17. Light transport through disordered layers of dense gallium arsenide submicron particles

    NARCIS (Netherlands)

    Van der Beek, T.; Barthelemy, P.J.C.; Johnson, P.M.; Wiersma, D.S.; Lagendijk, A.

    2012-01-01

    We present a study of optical transport properties of powder layers with submicrometer, strongly scattering gallium arsenide (GaAs) particles. Uniform, thin samples with well controlled thicknesses were created through the use of varying grinding times, sedimentation fractionation, annealing, and a

  18. Influence of the thickness of electrochemically deposited polyaniline used as hole transporting layer on the behaviour of polymer light-emitting diodes

    International Nuclear Information System (INIS)

    Alonso, J.L.; Ferrer, J.C.; Cotarelo, M.A.; Montilla, F.; Fernandez de Avila, S.

    2009-01-01

    An experimental study about the influence of the thickness of electrochemically deposited polyaniline (PANI), used as hole-transporting layer, on the behaviour of polymer light emitting diodes is presented. Two sets of devices with a different conjugated polymer used as active layer were prepared. Poly(9-vinylcarbazole) was used for the first type of devices, whereas Poly[2-methoxy-5-(3',7'-dimethyloctyloxy)-1,4-phenylene-vinylene] was used for the second type. Each set consists of five polymeric diodes in which the hole-transporting layer has been varied. In one case of each set no layer was deposited, in other one a Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) layer was deposited, and in the rest of the diodes a different thickness of electrochemically deposited PANI was employed. The optic and electronic characterization of the devices show that controlling the thickness of the PANI hole transporting layer, both the maximum emission peak of the electroluminescence curves and the driving voltage could be tuned. Furthermore, an exponential behaviour has been demonstrated for the maximum intensity of the electroluminescence curves as a function of the applied excitation voltage between anode and cathode

  19. Influence of the thickness of electrochemically deposited polyaniline used as hole transporting layer on the behaviour of polymer light-emitting diodes

    Energy Technology Data Exchange (ETDEWEB)

    Alonso, J.L. [Dpto. de Fisica y Arquitectura de Computadores, Universidad Miguel Hernandez, Av. de la Universidad s/n, Ed. Torrepinet, 03202, Elche, Alicante (Spain)], E-mail: j.l.alonso@umh.es; Ferrer, J.C. [Dpto. de Fisica y Arquitectura de Computadores, Universidad Miguel Hernandez, Av. de la Universidad s/n, Ed. Torrepinet, 03202, Elche, Alicante (Spain); Cotarelo, M.A.; Montilla, F. [Dpto. de Quimica Fisica e Instituto Universitario de Materiales de Alicante, Apdo. de Correos 99, E-03080, Alicante (Spain); Fernandez de Avila, S. [Dpto. de Fisica y Arquitectura de Computadores, Universidad Miguel Hernandez, Av. de la Universidad s/n, Ed. Torrepinet, 03202, Elche, Alicante (Spain)

    2009-02-27

    An experimental study about the influence of the thickness of electrochemically deposited polyaniline (PANI), used as hole-transporting layer, on the behaviour of polymer light emitting diodes is presented. Two sets of devices with a different conjugated polymer used as active layer were prepared. Poly(9-vinylcarbazole) was used for the first type of devices, whereas Poly[2-methoxy-5-(3',7'-dimethyloctyloxy)-1,4-phenylene-vinylene] was used for the second type. Each set consists of five polymeric diodes in which the hole-transporting layer has been varied. In one case of each set no layer was deposited, in other one a Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) layer was deposited, and in the rest of the diodes a different thickness of electrochemically deposited PANI was employed. The optic and electronic characterization of the devices show that controlling the thickness of the PANI hole transporting layer, both the maximum emission peak of the electroluminescence curves and the driving voltage could be tuned. Furthermore, an exponential behaviour has been demonstrated for the maximum intensity of the electroluminescence curves as a function of the applied excitation voltage between anode and cathode.

  20. Tandem colloidal quantum dot solar cells employing a graded recombination layer

    KAUST Repository

    Wang, Xihua

    2011-06-26

    Tuning of the electronic bandgap in colloidal quantum dots (CQDs) by changing their size enables the spectral response of CQD-based photodetectors and photovoltaic devices to be tailored. Multi-junction solar cells made from a combination of CQDs of differing sizes and thus bandgaps are a promising means by which to increase the energy harvested from the Sun\\'s broad spectrum. Here, we report the first CQD tandem solar cells using the size-effect tuning of a single CQD material, PbS. We use a graded recombination layer to provide a progression of work functions from the hole-accepting electrode in the bottom cell to the electron-accepting electrode in the top cell, allowing matched electron and hole currents to meet and recombine. Our tandem solar cell has an open-circuit voltage of 1.06Â V, equal to the sum of the two constituent single-junction devices, and a solar power conversion efficiency of up to 4.2%. © 2011 Macmillan Publishers Limited. All rights reserved.

  1. The boundary layers as the primary transport regions of the earth's magnetotail

    Science.gov (United States)

    Eastman, T. E.; Frank, L. A.; Huang, C. Y.

    1985-01-01

    A comprehensive survey of ISEE and IMP LEPEDEA plasma measurements in the earth's magnetotail reveals that the magnetospheric boundary layer and the plasma sheet boundary layer are the primary transport regions there. These plasma measurements also reveal various components of the plasma sheet, including the central plasma sheet and plasma sheet boundary layer. A significant new result reported here is that of cold- and hot-plasma components that are spatially co-present within the central plasma sheet. Such plasma components cannot be explained merely by temporal variations in spectra involving the entire plasma sheet. Contributions to a low temperature component of the plasma sheet enter directly from the boundary layer located along the magnetotail flanks. Field-aligned flows predominate within the plasma sheet boundary layer which is almost always present and is located near the high- and low-latitude border of the plasma sheet. The plasma sheet boundary layer comprises highly anisotropic ion distributions, including counter-streaming ion beams, that evolve into the hot, isotropic component of the plasma sheet. Tailward acceleration regions generate these ion beams with plasma input from the magnetospheric boundary layer. Antisunward-flowing ion beams, at E/q less than 1 kV and of ionospheric composition, are frequently observed in the plasma sheet boundary layer and in tail lobes. These ion beams are likely accelerated at low altitude over the polar cap and especially along auroral field lines.

  2. Low-temperature solution-processed hydrogen molybdenum and vanadium bronzes for an efficient hole-transport layer in organic electronics.

    Science.gov (United States)

    Xie, Fengxian; Choy, Wallace C H; Wang, Chuandao; Li, Xinchen; Zhang, Shaoqing; Hou, Jianhui

    2013-04-11

    A simple one-step method is reported to synthesize low-temperature solution-processed transition metal oxides (TMOs) of molybdenum oxide and vanadium oxide with oxygen vacancies for a good hole-transport layer (HTL). The oxygen vacancy plays an essential role for TMOs when they are employed as HTLs: TMO films with excess oxygen are highly undesirable for their application in organic electronics. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  3. RANS-based simulation of turbulent wave boundary layer and sheet-flow sediment transport processes

    DEFF Research Database (Denmark)

    Fuhrman, David R.; Schløer, Signe; Sterner, Johanna

    2013-01-01

    with bed and suspended load descriptions, the latter based on an unsteady turbulent-diffusion equation, for simulation of sheet-flow sediment transport processes. In addition to standard features common within such RANS-based approaches, the present model includes: (1) hindered settling velocities at high...... of a number of local factors important within cross-shore wave boundary layer and sediment transport dynamics. The hydrodynamic model is validated for both hydraulically smooth and rough conditions, based on wave friction factor diagrams and boundary layer streaming profiles, with the results in excellent...... agreement with experimental and/or previous numerical work. The sediment transport model is likewise validated against oscillatory tunnel experiments involving both velocity-skewed and acceleration-skewed flows, as well as against measurements beneath real progressive waves.Model capabilities are exploited...

  4. Pore network modeling to explore the effects of compression on multiphase transport in polymer electrolyte membrane fuel cell gas diffusion layers

    Science.gov (United States)

    Fazeli, Mohammadreza; Hinebaugh, James; Fishman, Zachary; Tötzke, Christian; Lehnert, Werner; Manke, Ingo; Bazylak, Aimy

    2016-12-01

    Understanding how compression affects the distribution of liquid water and gaseous oxygen in the polymer electrolyte membrane fuel cell gas diffusion layer (GDL) is vital for informing the design of improved porous materials for effective water management strategies. Pore networks extracted from synchrotron-based micro-computed tomography images of compressed GDLs were employed to simulate liquid water transport in GDL materials over a range of compression pressures. The oxygen transport resistance was predicted for each sample under dry and partially saturated conditions. A favorable GDL compression value for a preferred liquid water distribution and oxygen diffusion was found for Toray TGP-H-090 (10%), yet an optimum compression value was not recognized for SGL Sigracet 25BC. SGL Sigracet 25BC exhibited lower transport resistance values compared to Toray TGP-H-090, and this is attributed to the additional diffusion pathways provided by the microporous layer (MPL), an effect that is particularly significant under partially saturated conditions.

  5. Improving the efficiency of organic photovoltaics by tuning the work function of graphene oxide hole transporting layers

    Science.gov (United States)

    Stratakis, Emmanuel; Savva, Kyriaki; Konios, Dimitrios; Petridis, Constantinos; Kymakis, Emmanuel

    2014-05-01

    A facile, fast, non-destructive and roll-to-roll compatible photochemical method for simultaneous partial reduction and doping of graphene oxide (GO) films through ultraviolet laser irradiation in the presence of a Cl2 precursor gas is demonstrated. The photochemical chlorinated GO-Cl films were fully characterized by XPS and Raman measurements, in which grafting of chloride to the edges and the basal plane of GO was confirmed. By tuning the laser exposure time, it is possible to control the doping and reduction levels and therefore to tailor the work function (WF) of the GO-Cl layers from 4.9 eV to a maximum value of 5.23 eV. These WF values match with the HOMO level of most polymer donors employed in OPV devices. Furthermore, high efficiency poly(2,7-carbazole) derivative (PCDTBT):fullerene derivative (PC71BM) based OPVs with GO-Cl as the hole transporting layer (HTL) were demonstrated with a power conversion efficiency (PCE) of 6.56% which is 17.35% and 19.48% higher than that of the pristine GO and PEDOT:PSS based OPV devices, respectively. The performance enhancement was attributed to more efficient hole transportation due to the energy level matching between the GO-Cl and the polymer donor.

  6. All-solution-processed inverted organic solar cell with a stacked hole-transporting layer

    Science.gov (United States)

    Lin, Wen-Kai; Su, Shui-Hsiang; Liu, Che-Chun; Yokoyama, Meiso

    2014-11-01

    In this study, inverted organic solar cells (IOSCs) have been fabricated and characterized. A sol-gel zinc oxide (ZnO) film is used as a hole-blocking layer (HBL). Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) and copper phthalocyanine (CuPc) are used as a hole-transporting layer (HTL). The HBL, active layer, and HTL films are fabricated by spin-coating technique. The anode is fabricated from Ag nanoparticles by drop titration using a Pasteur burette. Experimental results show that the PEDOT:PSS/CuPc stacked HTL provides a stepwise hole-transporting energy diagram configuration, which subsequently increases the charge carrier transporting capability and extracts holes from the active layer to the anode. The characteristics of the IOSCs were optimized and exhibited an open-circuit voltage (Voc), short-circuit current density (Jsc), fill factor (FF), and power conversion efficiency (PCE) of 0.53 V, 6.13 mA/cm2, 37.53%, and 1.24%, respectively, under simulated AM1.5G illumination of 100 mW/cm2. Hence, a solution process is feasible for fabricating low-cost and large-area solar energy devices.

  7. Spin transport in two-layer-CVD-hBN/graphene/hBN heterostructures

    Science.gov (United States)

    Gurram, M.; Omar, S.; Zihlmann, S.; Makk, P.; Li, Q. C.; Zhang, Y. F.; Schönenberger, C.; van Wees, B. J.

    2018-01-01

    We study room-temperature spin transport in graphene devices encapsulated between a layer-by-layer-stacked two-layer-thick chemical vapor deposition (CVD) grown hexagonal boron nitride (hBN) tunnel barrier, and a few-layer-thick exfoliated-hBN substrate. We find mobilities and spin-relaxation times comparable to that of SiO2 substrate-based graphene devices, and we obtain a similar order of magnitude of spin relaxation rates for both the Elliott-Yafet and D'Yakonov-Perel' mechanisms. The behavior of ferromagnet/two-layer-CVD-hBN/graphene/hBN contacts ranges from transparent to tunneling due to inhomogeneities in the CVD-hBN barriers. Surprisingly, we find both positive and negative spin polarizations for high-resistance two-layer-CVD-hBN barrier contacts with respect to the low-resistance contacts. Furthermore, we find that the differential spin-injection polarization of the high-resistance contacts can be modulated by dc bias from -0.3 to +0.3 V with no change in its sign, while its magnitude increases at higher negative bias. These features point to the distinctive spin-injection nature of the two-layer-CVD-hBN compared to the bilayer-exfoliated-hBN tunnel barriers.

  8. Numerical modeling of solute transport in deformable unsaturated layered soil

    Directory of Open Access Journals (Sweden)

    Sheng Wu

    2017-07-01

    Full Text Available The effect of soil stratification was studied through numerical investigation based on the coupled model of solute transport in deformable unsaturated soil. The theoretical model implied two-way coupled excess pore pressure and soil deformation based on Biot's consolidation theory as well as a one-way coupled volatile pollutant concentration field developed from the advection-diffusion theory. Embedded in the model, the degree of saturation, fluid compressibility, self-weight of the soil matrix, porosity variance, longitudinal dispersion, and linear sorption were computed. Based on simulation results of a proposed three-layer landfill model using the finite element method, the multi-layer effects are discussed with regard to the hydraulic conductivity, shear modulus, degree of saturation, molecular diffusion coefficient, and thickness of each layer. Generally speaking, contaminants spread faster in a stratified field with a soft and highly permeable top layer; soil parameters of the top layer are more critical than the lower layers but controlling soil thicknesses will alter the results. This numerical investigation showed noticeable impacts of stratified soil properties on solute migration results, demonstrating the importance of correctly modeling layered soil instead of simply assuming the averaged properties across the soil profile.

  9. Transport parameters of thin, supported cathode layers in solid oxide fuel cells (SOFCs); Transportparameter duenner, getraegerter Kathodenschichten der oxidkeramischen Brennstoffzelle

    Energy Technology Data Exchange (ETDEWEB)

    Wedershoven, Christian

    2010-12-22

    The aim of this work was to determine the transport properties of thin cathode layers, which are part of the composite layer of a fabricated anode-supported solid oxide fuel cell (SOFC). The transport properties of the anode and cathode have a significant influence on the electrochemical performance of a fuel cell stack and therefore represent an important parameter when designing fuel cell stacks. In order to determine the transport parameters of the cathode layers in a fabricated SOFC, it is necessary to permeate the thin cathode layer deposited on the gas-tight electrolyte with a defined gas transport. These thin cathode layers cannot be fabricated as mechanically stable single layers and cannot therefore be investigated in the diffusion and permeation experiments usually used to determine transport parameters. The setup of these experiments - particularly the sample holder - was therefore altered in this work. The result of this altered setup was a three-dimensional flow configuration. Compared to the conventional setup, it was no longer possible to describe the gas transport in the experiments with an analytical one-dimensional solution. A numerical solution process had to be used to evaluate the measurements. The new setup permitted a sufficiently symmetrical gas distribution and thus allowed the description of the transport to be reduced to a two-dimensional description, which significantly reduced the computational effort required to evaluate the measurements. For pressure-induced transport, a parametrized coherent expression of transport could be derived. This expression is equivalent to the analytical description of the transport in conventional measurement setups, with the exception of parameters that describe the geometry of the gas diffusion. In this case, a numerical process is not necessary for the evaluation. Using the transport parameters of mechanically stable anode substrates, which can be measured both in the old and the new setups, the old and

  10. Progress in integrated 2-D models for analysis of scrape-off layer transport physics

    Energy Technology Data Exchange (ETDEWEB)

    Rognlien, T.D. [Lawrence Livermore National Lab., CA (United States); Braams, B.J. [New York Univ., NY (United States); Knoll, D.A. [Idaho National Engineering Lab., Idaho Falls (United States)

    1996-08-01

    We present the status of comprehensive two-dimensional (2-D) transport modeling for the tokamak scrape-off layer (SOL) using the UEDGE and B2.5 codes. These codes are now able to integrate a variety of physics, including coupling of plasma and neutral transport leading to detachment, complicated diverto-plate geometries, multispecies impurities, and currents and E x B drifts. These new models are outlined and the capabilities are illustrated by a number of examples that emphasize the importance of including the 2-D geometry. (orig.)

  11. Efficient organic solar cells using copper(I) iodide (CuI) hole transport layers

    Energy Technology Data Exchange (ETDEWEB)

    Peng, Ying [Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044 (China); Department of Physics and Centre for Plastic Electronics, Blackett Laboratory, Imperial College London, London SW7 2AZ (United Kingdom); Yaacobi-Gross, Nir; Perumal, Ajay K.; Faber, Hendrik A.; Bradley, Donal D. C.; Anthopoulos, Thomas D., E-mail: zhqhe@bjtu.edu.cn, E-mail: t.anthopoulos@imperial.ac.uk [Department of Physics and Centre for Plastic Electronics, Blackett Laboratory, Imperial College London, London SW7 2AZ (United Kingdom); Vourlias, George; Patsalas, Panos A. [Department of Physics, Laboratory of Applied Physics, Aristotle University of Thessaloniki, GR-54124 Thessaloniki (Greece); He, Zhiqun, E-mail: zhqhe@bjtu.edu.cn, E-mail: t.anthopoulos@imperial.ac.uk [Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044 (China)

    2015-06-15

    We report the fabrication of high power conversion efficiency (PCE) polymer/fullerene bulk heterojunction (BHJ) photovoltaic cells using solution-processed Copper (I) Iodide (CuI) as hole transport layer (HTL). Our devices exhibit a PCE value of ∼5.5% which is equivalent to that obtained for control devices based on the commonly used conductive polymer poly(3,4-ethylenedioxythiophene): polystyrenesulfonate as HTL. Inverted cells with PCE >3% were also demonstrated using solution-processed metal oxide electron transport layers, with a CuI HTL evaporated on top of the BHJ. The high optical transparency and suitable energetics of CuI make it attractive for application in a range of inexpensive large-area optoelectronic devices.

  12. Boundary layers as the primary transport regions of the earth's magnetotail

    International Nuclear Information System (INIS)

    Eastman, T.E.; Frank, L.A.; Huang, C.Y.

    1985-01-01

    A comprehensive survey of ISEE and IMP LEPEDEA plasma measurements in the earth's magnetotail reveals that the magnetospheric boundary layer and the plasma sheet boundary layer are the primary transport regions there. These plasma measurements also distinguish various components of the plasma sheet, including the central plasma sheet and plasma sheet boundary layer. A significant new result reported here is the existence of cold-and hot-plasma components that are spatially copresent within the central plasma sheet. Such plasma components cannot be explained merely by temporal variations in spectra involving the entire plasma sheet. Contributions to a low-temperature component of the plasma sheet enter directly from the boundary layer located along the magnetotail flanks. Field-aligned flows predominate within the plasma sheet boundary layer, which is almost always present and is located near the northern and southern border of the plasma sheet. The plasma sheet boundary layer comprises highly anisotropic ion distributions, including counteracting ion beams, that evolve into the hot, isotropic component of the plasma sheet

  13. Electron and Hole Transport Layers: Their Use in Inverted Bulk Heterojunction Polymer Solar Cells

    Directory of Open Access Journals (Sweden)

    Sandro Lattante

    2014-03-01

    Full Text Available Bulk heterojunction polymer solar cells (BHJ PSCs are very promising organic-based devices for low-cost solar energy conversion, compatible with roll-to-roll or general printing methods for mass production. Nevertheless, to date, many issues should still be addressed, one of these being the poor stability in ambient conditions. One elegant way to overcome such an issue is the so-called “inverted” BHJ PSC, a device geometry in which the charge collection is reverted in comparison with the standard geometry device, i.e., the electrons are collected by the bottom electrode and the holes by the top electrode (in contact with air. This reverted geometry allows one to use a high work function top metal electrode, like silver or gold (thus avoiding its fast oxidation and degradation, and eliminates the need of a polymeric hole transport layer, typically of an acidic nature, on top of the transparent metal oxide bottom electrode. Moreover, this geometry is fully compatible with standard roll-to-roll manufacturing in air and is less demanding for a good post-production encapsulation process. To date, the external power conversion efficiencies of the inverted devices are generally comparable to their standard analogues, once both the electron transport layer and the hole transport layer are fully optimized for the particular device. Here, the most recent results on this particular optimization process will be reviewed, and a general outlook regarding the inverted BHJ PSC will be depicted.

  14. Modeling reactive transport of reclaimed water through large soil columns with different low-permeability layers

    Science.gov (United States)

    Hu, Haizhu; Mao, Xiaomin; Barry, D. A.; Liu, Chengcheng; Li, Pengxiang

    2015-03-01

    The efficacy of different proportions of silt-loam/bentonite mixtures overlying a vadose zone in controlling solute leaching to groundwater was quantified. Laboratory experiments were carried out using three large soil columns, each packed with 200-cm-thick riverbed soil covered by a 2-cm-thick bentonite/silt-loam mixture as the low-permeability layer (with bentonite mass accounting for 12, 16 and 19 % of the total mass of the mixture). Reclaimed water containing ammonium (NH4 +), nitrate (NO3 -), organic matter (OM), various types of phosphorus and other inorganic salts was applied as inflow. A one-dimensional mobile-immobile multi-species reactive transport model was used to predict the preferential flow and transport of typical pollutants through the soil columns. The simulated results show that the model is able to predict the solute transport in such conditions. Increasing the amount of bentonite in the low-permeability layer improves the removal of NH4 + and total phosphorous (TP) because of the longer contact time and increased adsorption capacity. The removal of NH4 + and OM is mainly attributed to adsorption and biodegradation. The increase of TP and NO3 - concentration mainly results from discharge and nitrification in riverbed soils, respectively. This study underscores the role of low-permeability layers as barriers in groundwater protection. Neglect of fingers or preferential flow may cause underestimation of pollution risk.

  15. Application of solution-processed metal oxide layers as charge transport layers for CdSe/ZnS quantum-dot LEDs.

    Science.gov (United States)

    Nguyen, Huu Tuan; Nguyen, Nang Dinh; Lee, Soonil

    2013-03-22

    We fabricated and characterized quantum-dot light emitting devices (QLEDs) that consisted of a CdSe/ZnS quantum-dot (QD) emitting layer, a hole-transporting nickel oxide (NiO) layer and/or an electron-transporting zinc oxide (ZnO) layer. Both the p-type NiO and n-type ZnO layers were formed by using sol-gel processes. All the fabricated CdSe/ZnS QLEDs showed similar electroluminescence spectra that originated from the green CdSe/ZnS QDs. However, different combinations of hole- and electron-transporting layers resulted in efficiency variations. In addition to the control of the respective concentrations of holes and electrons within a multilayer device structure, which determines the luminance and efficiency of QLEDs, the use of metal oxide layers is advantageous for long-term stability of QLEDs because they are air stable and can block the permeation of water vapor and oxygen in ambient air to a QD emitting layer. Moreover, the wet chemistry processing for their formation makes metal oxide layers attractive for low cost and/or large area manufacture of QLEDs.

  16. Impact of different vertical transport representations on simulating processes in the tropical tropopause layer (TTL)

    Energy Technology Data Exchange (ETDEWEB)

    Ploeger, Felix

    2011-07-06

    The chemical and dynamical processes in the tropical tropopause layer (TTL) control the amount of radiatively active species like water vapour and ozone in the stratosphere, and hence turn out to be crucial for atmospheric trends and climate change. Chemistry transport models and chemistry climate models are suitable tools to understand these processes. But model results are subject to uncertainties arising from the parametrization of model physics. In this thesis the sensitivity of model predictions to the choice of the vertical transport representation will be analysed. Therefore, backtrajectories are calculated in the TTL, based on different diabatic and kinematic transport representations using ERA-Interim and operational ECMWF data. For diabatic transport on potential temperature levels, the vertical velocity is deduced from the ERA-Interim diabatic heat budget. For kinematic transport on pressure levels, the vertical wind is used as vertical velocity. It is found that all terms in the diabatic heat budget are necessary to cause transport from the troposphere to the stratosphere. In particular, clear-sky heating rates alone miss very important processes. Many characteristics of transport in the TTL turn out to depend very sensitively on the choice of the vertical transport representation. Timescales for tropical troposphere-to-stratosphere transport vary between one and three months, with respect to the chosen representation. Moreover, for diabatic transport ascent is found throughout the upper TTL, whereas for kinematic transport regions of mean subsidence occur, particularly above the maritime continent. To investigate the sensitivity of simulated trace gas distributions in the TTL to the transport representation, a conceptual approach is presented to predict water vapour and ozone concentrations from backtrajectories, based on instantaneous freeze-drying and photochemical ozone production. It turns out that ozone predictions and vertical dispersion of the

  17. Fabrication and characterization of perovskite based solar cells using phthalocyanine and naphthalocyanine as hole-transporting layer

    Science.gov (United States)

    Okada, Yuki; Suzuki, Atsushi; Yamasaki, Yasuhiro; Oku, Takeo

    2017-01-01

    Organic-inorganic hybrid heterojunction solar cells containing CH3NH3PbI3 perovskite compound were fabricated using TiO2 as an electronic transporting layer and spirobifluorence as a hole-transporting layer. The purpose of the present study is to investigate a role of the hole-transporting layer on the photovoltaic properties and microstructures of CH3NH3PbI3 perovskite solar cells. The X-ray diffraction identified crystal structures of the perovskite layer in the solar cells. Optical microscopy showed different surface morphologies, and the perovskite structures on the TiO2 mesoporous structure depended on addition of phthalocyanine into the hole-transporting layer. The photovoltaic properties and hole-transporting behavior was depending on carrier mobility, electron structures of the perovskite crystal and band gaps related with the photovoltaic parameters. Energy diagram and photovoltaic mechanism of the perovskite solar cells using hole-transporting layers were discussed by experimental results. Perovskite based solar cells using phthalocyanines as hole-transporting layers have advantages to provide a high photovoltaic performance with a wide region of optical absorption.

  18. Hydrodynamic theory of convective transport across a dynamically stabilized diffuse boundary layer

    International Nuclear Information System (INIS)

    Gerhauser, H.

    1983-09-01

    The diffuse boundary layer between miscible liquids is subject to Rayleigh-Taylor instabilities if the heavy fluid is supported by the light one. The resulting rapid interchange of the liquids can be suppressed by enforcing vertical oscillations on the whole system. This dynamic stabilization is incomplete and produces some peculiar novel transport phenomena such as decay off the density profile into several steps, periodic peeling of density sheets of the boundary layer and the appearance of steady vortex flow. The theory presented in this paper identifies the basic mechanism as formation of convective cells leading to enhanced diffusion, and explains previous experimental results with water and ZnJ 2 -solutions. A nonlinear treatment of the stationary convective flow problem gives the saturation amplitude of the ground mode and provides an upper bound for the maximum convective transport. The hydrodynamic model can be used for visualizing similar transport processes in the plasma of toroidal confinement devices such as sawtooth oscillations in soft disruptions of tokamak discharges and anomalous diffusion by excitation of convective cells. The latter process is investigated here in some detail, leading to the result that the maximum possible transport is of the order of Bohm diffusion. (orig.)

  19. Multigroup multi-layer models of neutron reflection and transmission for reactor transport calculations with anisotropic scattering

    International Nuclear Information System (INIS)

    Abreu, Marcos Pimenta de

    2006-01-01

    In this article, we extend the one-speed multi-layer models to neutron reflection and transmission developed in our earlier work (de Abreu, M.P., 2005. Multi-layer models to neutron reflection and transmission for whole-core transport calculations, Annals of Nuclear Energy 32, 215) to multigroup transport theory. We begin by considering a two-layer boundary region, and we develop for such a region discrete ordinates models to the diffuse reflection and transmission of neutrons for multigroup nuclear reactor core problems with anisotropic scattering. We perform numerical experiments to show that our models to neutron reflection and transmission can be used to replace efficiently and accurately two nonactive boundary layers in whole-core transport calculations. We conclude this article with an inductive extension of our two-layer results to a boundary region with an arbitrary number of layers

  20. Comparison of scrape-off layer transport in inner and outer wall limited JET plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Silva, C., E-mail: csilva@ipfn.ist.utl.pt [Associação Euratom/IST, Instituto de Plasmas e Fusão Nuclear, Instituto Superior Técnico, Universidade Técnica Lisboa (Portugal); Arnoux, G.; Devaux, S. [Euratom/CCFE Fusion Association, Culham Science Centre, Abingdon OX14 3DB (United Kingdom); Frigione, D. [Associazione EURATOM-ENEA sulla fusione, CR Frascati, Roma (Italy); Groth, M. [Aalto University, Association EURATOM-Tekes, Otakaari 4, 02015 Espoo (Finland); Horacek, J. [Institute of Plasma Physics AS CR, v.v.i., Association EURATOM/IPP.CR, Praha 8 (Czech Republic); Lomas, P.J. [Euratom/CCFE Fusion Association, Culham Science Centre, Abingdon OX14 3DB (United Kingdom); Marsen, S. [Max-Planck-Institute for Plasma Physics, EURATOM Association, 17491 Greifswald (Germany); Matthews, G. [Euratom/CCFE Fusion Association, Culham Science Centre, Abingdon OX14 3DB (United Kingdom); Pitts, R.A. [ITER Organization, Route de Vinon sur Verdon, 13115 Saint Paul Lez Durance (France)

    2013-07-15

    The JET scrape-off layer has been characterized with a reciprocating probe in inner wall, IW, and outer wall, OW, limited plasmas. Broad SOL profiles are observed for IW limited plasmas with power e-folding length substantially larger (by a factor of ∼5–7.5) than in OW limited plasmas. The properties of the fluctuations in the SOL parameters indicate larger turbulent transport for IW limited plasmas. The striking differences observed between IW and OW limited plasmas on the power e-folding length, parallel flow, turbulent transport as well as the characteristics of the fluctuations support the existence of a poloidally localized region of enhanced radial transport near the outboard midplane. The dependence of the SOL power e-folding length on the main plasma parameters was also investigated for IW limited plasmas and a modest negative dependence on both the plasma current and the line-averaged density found.

  1. Plasma transport in the Scrape-off-Layer of magnetically confined plasma and the plasma exhaust

    DEFF Research Database (Denmark)

    Rasmussen, Jens Juul; Naulin, Volker; Nielsen, Anders Henry

    An overview of the plasma dynamics in the Scrape-off-Layer (SOL) of magnetically confined plasma is presented. The SOL is the exhaust channel of the warm plasma from the core, and the understanding of the SOL plasma dynamics is one of the key issues in contemporary fusion research. It is essential...... for operation of fusion experiments and ultimately fusion power plants. Recent results clearly demonstrate that the plasma transport through the SOL is dominated by turbulent intermittent fluctuations organized into filamentary structures convecting particles, energy, and momentum through the SOL region. Thus......, the transport cannot be described and parametrized by simple diffusive type models. The transport leads to strong localized power loads on the first wall and the plasma facing components, which have serious lasting influence....

  2. Impact of Transport Layer Protocols on Reliable Information Access in Smart Grids

    DEFF Research Database (Denmark)

    Shahid, Kamal; Saeed, Aamir; Kristensen, Thomas le Fevre

    2017-01-01

    . In this context, transport layer offers different levels of end-to-end communication services to the applications. For instance, TCP guarantees the transport of messages between two ends, however, at the cost of high end-to-end delays due to the retransmission mechanism. Whereas UDP offers minimum end......Time is critical for certain types of dynamic information (e.g. frequency control) in a smart grid scenario. The usefulness of such information depends upon the arrival within a specific frame of time, which in other case may not serve the purpose and effect controller’s performance......-to-end delays at the cost of unreliable, best-effort data transportation service. The research question raised in this paper is thus, which is preferred for the delay-critical applications of smart grids, and to what degree of packet losses and round trip times, TCP is preferable to UDP and vice versa...

  3. Charge-transport anisotropy in black phosphorus: critical dependence on the number of layers.

    Science.gov (United States)

    Banerjee, Swastika; Pati, Swapan K

    2016-06-28

    Phosphorene is a promising candidate for modern electronics because of the anisotropy associated with high electron-hole mobility. Additionally, superior mechanical flexibility allows the strain-engineering of various properties including the transport of charge carriers in phosphorene. In this work, we have shown the criticality of the number of layers to dictate the transport properties of black phosphorus. Trilayer black phosphorus (TBP) has been proposed as an excellent anisotropic material, based on the transport parameters using Boltzmann transport formalisms coupled with density functional theory. The mobilities of both the electron and the hole are found to be higher along the zigzag direction (∼10(4) cm(2) V(-1) s(-1) at 300 K) compared to the armchair direction (∼10(2) cm(2) V(-1) s(-1)), resulting in the intrinsic directional anisotropy. Application of strain leads to additional electron-hole anisotropy with 10(3) fold higher mobility for the electron compared to the hole. Critical strain for maximum anisotropic response has also been determined. Whether the transport anisotropy is due to the spatial or charge-carrier has been determined through analyses of the scattering process of electrons and holes, and their recombination as well as relaxation dynamics. In this context, we have derived two descriptors (S and F(k)), which are general enough for any 2D or quasi-2D systems. Information on the scattering involving purely the carrier states also helps to understand the layer-dependent photoluminescence and electron (hole) relaxation in black phosphorus. Finally, we justify trilayer black phosphorus (TBP) as the material of interest with excellent transport properties.

  4. Amazon boundary layer aerosol concentration sustained by vertical transport during rainfall

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jian; Krejci, Radovan; Giangrande, Scott; Kuang, Chongai; Barbosa, Henrique M. J.; Brito, Joel; Carbone, Samara; Chi, Xuguang; Comstock, Jennifer; Ditas, Florian; Lavric, Jost; Manninen, Hanna E.; Mei, Fan; Moran-Zuloaga, Daniel; Pöhlker, Christopher; Pöhlker, Mira L.; Saturno, Jorge; Schmid, Beat; Souza, Rodrigo A. F.; Springston, Stephen R.; Tomlinson, Jason M.; Toto, Tami; Walter, David; Wimmer, Daniela; Smith, James N.; Kulmala, Markku; Machado, Luiz A. T.; Artaxo, Paulo; Andreae, Meinrat O.; Petäjä, Tuukka; Martin, Scot T.

    2016-10-24

    A necessary prerequisite of cloud formation, aerosol particles represent one of the largest uncertainties in computer simulations of climate change1,2, in part because of a poor understanding of processes under natural conditions3,4. The Amazon rainforest is one of the few continental regions where aerosol particles and their precursors can be studied under near-natural conditions5-7. Cloud condensation nuclei (CCN) in clean Amazonia are mostly produced by the growth of smaller particles in the boundary layer8-10, whereas these smaller particles themselves 31 appear to be produced elsewhere5,11. Key questions are in what part of the atmosphere they might 32 be produced and what could be the transport processes that deliver them to the boundary layer, where they grow into CCN. Here, using recent aircraft measurements above central Amazonia, we show high concentrations of small particles in the lower free troposphere. The particle size spectrum shifts towards larger sizes with decreasing altitude, implying particle growth as air descends from the free troposphere towards Earth's surface. Complementary measurements at ground sites show that free tropospheric air having high concentrations of small particles (diameters of less than 50 nm) is transported into the boundary layer during precipitation events, both by strong convective downdrafts and by weaker downward motions in the trailing stratiform region. This vertical transport helps maintain the population of small particles and ultimately CCN in the boundary layer, thereby playing an important role in controlling the climate state under natural conditions. In contrast, this mechanism becomes masked under polluted conditions, which sometimes prevail at times in Amazonia as well as over other tropical continental regions5,12.

  5. Dye-sensitized solar cells employing a SnO2-TiO2 core-shell structure made by atomic layer deposition.

    Science.gov (United States)

    Karlsson, Martin; Jõgi, Indrek; Eriksson, Susanna K; Rensmo, Håkan; Boman, Mats; Boschloo, Gerrit; Hagfeldt, Anders

    2013-01-01

    This paper describes the synthesis and characterization of core-shell structures, based on SnO2 and TiO2, for use in dye-sensitized solar cells (DSC). Atomic layer deposition is employed to control and vary the thickness of the TiO2 shell. Increasing the TiO2 shell thickness to 2 nm improved the device performance of liquid electrolyte-based DSC from 0.7% to 3.5%. The increase in efficiency originates from a higher open-circuit potential and a higher short-circuit current, as well as from an improvement in the electron lifetime. SnO2-TiO2 core-shell DSC devices retain their photovoltage in darkness for longer than 500 seconds, demonstrating that the electrons are contained in the core material. Finally core-shell structures were used for solid-state DSC applications using the hole transporting material 2,2',7,7',-tetrakis(N, N-di-p-methoxyphenyl-amine)-9,9',-spirofluorene. Similar improvements in device performance were obtained for solid-state DSC devices.

  6. Tuning the Transport Properties of Layered Materials for Thermoelectric Applications using First-Principles Calculations

    KAUST Repository

    Saeed, Yasir

    2014-05-11

    Thermoelectric materials can convert waste heat into electric power and thus provide a way to reduce the dependence on fossil fuels. Our aim is to model the underlying materials properties and, in particular, the transport as controlled by electrons and lattice vibrations. The goal is to develop an understanding of the thermoelectric properties of selected materials at a fundamental level. The structural, electronic, optical, and phononic properties are studied in order to tune the transport, focusing on KxRhO2, NaxRhO2, PtSb2 and Bi2Se3. The investigations are based on density functional theory as implemented in the all electron linearized augmented plane wave plus local orbitals WIEN2k and pseudo potential Quantum-ESPRESSO codes. The thermoelectric properties are derived from Boltzmann transport theory under the constant relaxation time approximation, using the BoltzTraP code. We will discuss first the changes in the electronic band structure under variation of the cation concentration in layered KxRhO2 in the 2H phase and NaxRhO2 in the 3R phase. We will also study the hydrated phase. The deformations of the RhO6 octahedra turn out to govern the thermoelectric properties, where the high Seebeck coefficient results from ”pudding mold" bands. We investigate the thermoelectric properties of electron and hole doped PtSb2, which is not a layered material but shares “pudding mold" bands. PtSb2 has a high Seebeck coefficient at room temperature, which increases significantly under As alloying by bandgap opening and reduction of the lattice thermal conductivity. Bi2Se3 (bulk and thin film) has a larger bandgap then the well-known thermoelectric material Bi2Te3, which is important at high temperature. The structural stability, electronic structure, and transport properties of one to six quintuple layers of Bi2Se3 will be discussed. We also address the effect of strain on a single quintuple layer by phonon band structures. We will analyze the electronic and transport

  7. A review on transport layer protocol performance for delivering video on an adhoc network

    Science.gov (United States)

    Suherman; Suwendri; Al-Akaidi, Marwan

    2017-09-01

    The transport layer protocol is responsible for the end to end data transmission. Transmission control protocol (TCP) provides a reliable connection and user datagram protocol (UDP) offers fast but unguaranteed data transfer. Meanwhile, the 802.11 (wireless fidelity/WiFi) networks have been widely used as internet hotspots. This paper evaluates TCP, TCP variants and UDP performances for video transmission on an adhoc network. The transport protocol - medium access cross-layer is proposed by prioritizing TCP acknowledgement to reduce delay. The NS-2 evaluations show that the average delays increase linearly for all the evaluated protocols and the average packet losses grow logarithmically. UDP produces the lowest transmission delay; 5.4% and 5.8% lower than TCP and TCP variant, but experiences the highest packet loss. Both TCP and TCP Vegas maintain packet loss as low as possible. The proposed cross-layer successfully decreases TCP and TCP Vegas delay about 0.12 % and 0.15%, although losses remain similar.

  8. Thermal transport in bismuth telluride quintuple layer: mode-resolved phonon properties and substrate effects.

    Science.gov (United States)

    Shao, Cheng; Bao, Hua

    2016-06-06

    The successful exfoliation of atomically-thin bismuth telluride (Bi2Te3) quintuple layer (QL) attracts tremendous research interest in this strongly anharmonic quasi-two-dimensional material. The thermal transport properties of this material are not well understood, especially the mode-wise properties and when it is coupled with a substrate. In this work, we have performed molecular dynamics simulations and normal mode analysis to study the mode-resolved thermal transport in freestanding and supported Bi2Te3 QL. The detailed mode-wise phonon properties are calculated and the accumulated thermal conductivities with respect to phonon mean free path (MFP) are constructed. It is shown that 60% of the thermal transport is contributed by phonons with MFP longer than 20 nm. Coupling with a-SiO2 substrate leads to about 60% reduction of thermal conductivity. Through varying the interfacial coupling strength and the atomic mass of substrate, we also find that phonon in Bi2Te3 QL is more strongly scattered by interfacial potential and its transport process is less affected by the dynamics of substrate. Our study provides an in-depth understanding of heat transport in Bi2Te3 QL and is helpful in further tailoring its thermal property through nanostructuring.

  9. New Perspectives on Blowing Snow Transport, Sublimation, and Layer Thermodynamic Structure over Antarctica

    Science.gov (United States)

    Palm, S. P.; Yang, Y.; Kayetha, V.; Pauly, R.

    2017-12-01

    Blowing snow over Antarctica is a widespread and frequent event. Satellite remote sensing using lidar has shown that blowing snow occurs over 70% of the time over large areas of Antarctica in winter. The transport and sublimation of blowing snow are important terms in the ice sheet mass balance equation and the latter is also an important part of the hydrological cycle. Until now the only way to estimate the magnitude of these processes was through model parameterization. We present a technique that uses direct satellite observations of blowing snow and model (MERRA-2) temperature and humidity fields to compute both transport and sublimation of blowing snow over Antarctica for the period 2006 to 2016. The results show a larger annual continent-wide integrated sublimation than current published estimates and a significant transport of snow from continent to ocean. The talk will also include the lidar backscatter structure of blowing snow layers that often reach heights of 200 to 300 m as well as the first dropsonde measurements of temperature, moisture and wind through blowing snow layers.

  10. A TCP/IP transport layer for the DAQ of the CMS experiment

    International Nuclear Information System (INIS)

    Kozlovszky, M.

    2004-01-01

    The CMS collaboration is currently investigating various networking technologies that may meet the requirements of the CMS Data Acquisition System (DAQ). During this study, a peer transport component based on TCP/IP has been developed using object-oriented techniques for the distributed DAQ framework named XDAQ. This framework has been designed to facilitate the development of distributed data acquisition systems within the CMS Experiment. The peer transport component has to meet 3 main requirements. Firstly, it had to provide fair access to the communication medium for competing applications. Secondly, it had to provide as much of the available bandwidth to the application layer as possible. Finally, it had to hide the complexity of using non-blocking TCP/IP connections from the application layer. This paper describes the development of the peer transport component and then presents and draws conclusions on the measurements made during tests. The major topics investigated include: blocking versus non-blocking communication, TCP/IP configuration options, multi-rail connections

  11. New Perspectives on Blowing Snow Transport, Sublimation, and Layer Thermodynamic Structure over Antarctica

    Science.gov (United States)

    Palm, Steve; Kayetha, Vinay; Yang, Yuekui; Pauly, Rebecca M.

    2017-01-01

    Blowing snow over Antarctica is a widespread and frequent event. Satellite remote sensing using lidar has shown that blowing snow occurs over 70% of the time over large areas of Antarctica in winter. The transport and sublimation of blowing snow are important terms in the ice sheet mass balance equation and the latter is also an important part of the hydrological cycle. Until now the only way to estimate the magnitude of these processes was through model parameterization. We present a technique that uses direct satellite observations of blowing snow and model (MERRA-2) temperature and humidity fields to compute both transport and sublimation of blowing snow over Antarctica for the period 2006 to 2016. The results show a larger annual continent-wide integrated sublimation than current published estimates and a significant transport of snow from continent to ocean. The talk will also include the lidar backscatter structure of blowing snow layers that often reach heights of 200 to 300 m as well as the first dropsonde measurements of temperature, moisture and wind through blowing snow layers.

  12. Improved efficiency of NiOx-based p-i-n perovskite solar cells by using PTEG-1 as electron transport layer

    NARCIS (Netherlands)

    Groeneveld, Bart G. H. M.; Najafi, Mehrdad; Steensma, Bauke; Adjokatse, Sampson; Fang, Hong-Hua; Jahani, Fatemeh; Qiu, Li; ten Brink, Gert H.; Hummelen, Jan C.; Loi, Maria Antonietta

    We present efficient p-i-n type perovskite solar cells using NiOx as the hole transport layer and a fulleropyrrolidine with a triethylene glycol monoethyl ether side chain (PTEG-1) as electron transport layer. This electron transport layer leads to higher power conversion efficiencies compared to

  13. Understanding the role of pore size homogeneity in the water transport through graphene layers.

    Science.gov (United States)

    Su, Jiaye; Zhao, Yunzhen; Fang, Chang

    2018-03-16

    Graphene is a versatile 2D material and attracts increasing attentions from a broad scientific community, including novel nanofluidic devices. In this work, we use molecular dynamics simulations to study the pressure driven water transport through graphene layers, focusing on the pore size homogeneity, realized by the arrangement of two pore sizes. For a given layer number, we find the water flux exhibits an excellent linear behavior with the pressure, in agreement with the prediction of Hagen-Poiseuille equation. Interestingly, the flux for concentrated pore size distribution is around twice larger than that of uniform distribution. More surprisingly, under a given pressure, the water flux changes in an opposite way for these two distributions, where the flux ratio almost increases linearly with the layer number. For the largest layer number, more distributions suggest the same conclusion that higher water flux can be attained for more concentrated pore size distributions. Similar differences for the water translocation time and occupancy are also identified. The major reason for these results should be clearly due to hydrogen bond and density profile distributions. Our results are helpful to delineate the exquisite role of pore size homogeneity, and should have great implications for the design of high flux nanofluidic devices and inversely the detection of pore structures. © 2018 IOP Publishing Ltd.

  14. A TiO2nanotube network electron transport layer for high efficiency perovskite solar cells.

    Science.gov (United States)

    Gao, Xianfeng; Li, Jianyang; Gollon, Sam; Qiu, Ming; Guan, Dongsheng; Guo, Xiaoru; Chen, Junhong; Yuan, Chris

    2017-02-15

    The electron transport layer (ETL) plays a critical role in high efficiency perovskite solar cells. In this study, an anodic TiO 2 nanotube film was transformed into a TiO 2 nanotube network film, which maintained its advantage as an efficient ETL for perovskite solar cells. Compared with the mesoporous TiO 2 nanoparticle ETL, the TiO 2 nanotube network ETL can increase the efficiency of perovskite solar cells by 26.6%, which is attributed to its superior charge collection property and light trapping ability. The results confirm the importance of optimizing the electron collecting layer and suggest another way to design and fabricate novel perovskite solid state solar cells, potentially by using a TiO 2 nanotube network film as an alternative high efficiency electrode.

  15. Transport of short-lived species into the Tropical Tropopause Layer

    Science.gov (United States)

    Ashfold, M. J.; Harris, N. R. P.; Atlas, E. L.; Manning, A. J.; Pyle, J. A.

    2012-07-01

    We use NAME, a trajectory model, to investigate the routes and timescales over which air parcels reach the tropical tropopause layer (TTL). Our aim is to assist the planning of aircraft campaigns focussed on improving knowledge of such transport. We focus on Southeast Asia and the Western Pacific which appears to be a particularly important source of air that enters the TTL. We first study the TTL above Borneo in November 2008, under neutral El Niño/Southern Oscillation (ENSO) conditions. Air parcels (trajectories) arriving in the lower TTL (below ~15 km) are most likely to have travelled from the boundary layer (BL; planning flights for the long-duration aircraft now capable of making such measurements.

  16. Conceptual Design of a Single-Aisle Turboelectric Commercial Transport With Fuselage Boundary Layer Ingestion

    Science.gov (United States)

    Welstead, Jason R.; Felder, James L.

    2016-01-01

    A single-aisle commercial transport concept with a turboelectric propulsion system architecture was developed assuming entry into service in 2035 and compared to a similar technology conventional configuration. The turboelectric architecture consisted of two underwing turbofans with generators extracting power from the fan shaft and sending it to a rear fuselage, axisymmetric, boundary layer ingesting fan. Results indicate that the turbo- electric concept has an economic mission fuel burn reduction of 7%, and a design mission fuel burn reduction of 12% compared to the conventional configuration. An exploration of the design space was performed to better understand how the turboelectric architecture changes the design space, and system sensitivities were run to determine the sensitivity of thrust specific fuel consumption at top of climb and propulsion system weight to the motor power, fan pressure ratio, and electrical transmission efficiency of the aft boundary layer ingesting fan.

  17. Transport of gaseous pollutants by convective boundary layer around a human body

    DEFF Research Database (Denmark)

    Licina, Dusan; Melikov, Arsen Krikor; Sekhar, Chandra

    2015-01-01

    of the pollution boundary layer. The study, in addition, evaluates the effects of the room air temperature, table positioning, and seated body inclination. The human body is represented by a thermal manikin that has a body shape, size, and surface temperature that resemble those of a real person. The results show...... at the upper back or behind the chair. The results also indicate that a decrease in personal exposure to pollutants released from or around the human body increases the extent to which the pollution spreads to the surroundings. Reducing the room air temperature or backward body inclination intensifies......This study investigates the ability of the human convective boundary layer to transport pollution in a quiescent indoor environment. The impact of the source location in the vicinity of a human body is examined in relation to pollution distribution in the breathing zone and the thickness...

  18. A two-phase moisture transport model accounting for sorption hysteresis in layered porous building constructions

    DEFF Research Database (Denmark)

    Johannesson, Björn; Janz, Mårten

    2009-01-01

    and exhibits different transport properties. A successful model of such a case may shred light on the performance of different constructions with regards to, for example, mould growth and freeze thaw damages. For this purpose a model has been developed which is based on a two phase flow, vapor and liquid water......, with account also to sorption hysteresis. The different materials in the considered layered construction are assigned different properties, i.e. vapor and liquid water diffusivities and boundary (wetting and drying) sorption curves. Further, the scanning behavior between wetting and drying boundary curves...

  19. Physical Layer Secret-Key Generation Scheme for Transportation Security Sensor Network.

    Science.gov (United States)

    Yang, Bin; Zhang, Jianfeng

    2017-06-28

    Wireless Sensor Networks (WSNs) are widely used in different disciplines, including transportation systems, agriculture field environment monitoring, healthcare systems, and industrial monitoring. The security challenge of the wireless communication link between sensor nodes is critical in WSNs. In this paper, we propose a new physical layer secret-key generation scheme for transportation security sensor network. The scheme is based on the cooperation of all the sensor nodes, thus avoiding the key distribution process, which increases the security of the system. Different passive and active attack models are analyzed in this paper. We also prove that when the cooperative node number is large enough, even when the eavesdropper is equipped with multiple antennas, the secret-key is still secure. Numerical results are performed to show the efficiency of the proposed scheme.

  20. Polycyclic aromatic hydrocarbons (PAHs) associated with PM2.5 within boundary layer: Cloud/fog and regional transport.

    Science.gov (United States)

    Yang, Minmin; Wang, Yan; Li, Hongli; Li, Tao; Nie, Xiaoling; Cao, Fangfang; Yang, Fengchun; Wang, Zhe; Wang, Tao; Qie, Guanghao; Jin, Tong; Du, Lili; Wang, Wenxing

    2018-06-15

    A study of PM 2.5 -associated PAHs analysis at Mount Lushan (1165m) was conducted to investigate the distributions of PAHs in PM 2.5 and influences of cloud/fog. The main purpose was to quantify the main emission sources of PAHs and estimate regional transport effects within the boundary layer. Mount Lushan is located between the boundary layer and troposphere, which is an ideal site for atmosphere transport investigation. The concentrations of PAHs in PM 2.5 were analyzed with GC-MS. The results showed that the volume concentration was 6.98ng/m 3 with a range from 1.47 to 25.17ng/m 3 and PAHs mass were 160.24μg/g (from 63.86 to 427.97μg/g) during the sampling time at Mount Lushan. The dominant compounds are BbF, Pyr and BP. In terms of aromatic-ring PAHs distributions, 4-6-ring PAHs are predominant, indicating that the high-ring PAHs tend to contribute more than low-ring PAHs in particulates. Due to frequent cloud/fog days at Mount Lushan, PAHs concentrations in the PM 2.5 were determined before and after cloud/fog weather. The results demonstrated that the cloud/fog and rain conditions cause lower PAHs levels. Regression analysis was used for studying the relationship of PAHs distributions with meteorological conditions like temperature, humidity and wind. The results showed that the temperature and wind speed were inversely related with PAHs concentration but humidity had no significant relationship. Furthermore, backward trajectories and PCA combined with DR (diagnostic ratio analysis) were employed to identify the influences of regional transport and main emission sources. The results revealed that PAHs in PM 2.5 were mainly affected by regional transport with the main emissions by mobile vehicle and steel industry, which contributed about 56.0% to the total PAHs in the area of Mount Lushan. In addition, backward trajectories revealed that the dominant air masses were from the northwest accounting for about one third of total PAHs. Copyright © 2018

  1. Mechanical characterization and durability of sintered porous transport layers for polymer electrolyte membrane electrolysis

    Science.gov (United States)

    Borgardt, Elena; Panchenko, Olha; Hackemüller, Franz Josef; Giffin, Jürgen; Bram, Martin; Müller, Martin; Lehnert, Werner; Stolten, Detlef

    2018-01-01

    Differential pressure electrolysis offers the potential for more efficient hydrogen compression. Due to the differential pressures acting within the electrolytic cell, the porous transport layer (PTL) is subjected to high stress. For safety reasons, the PTL's mechanical stability must be ensured. However, the requirements for high porosity and low thickness stand in contrast to that for mechanical stability. Porous transport layers for polymer electrolyte membrane (PEM) electrolysis are typically prepared by means of the thermal sintering of titanium powder. Thus far, the factors that influence the mechanical strength of the sintered bodies and how all requirements can be simultaneously fulfilled have not been investigated. Here, the static and dynamic mechanical properties of thin sintered titanium sheets are investigated ex-situ via tensile tests and periodic loading in a test cell, respectively. In order for a sintered PTL with a thickness of 500 μm and porosities above 25% to be able to withstand 50 bar differential pressure in the cell, the maximum flow field width should be limited to 3 mm. Thus, a method was developed to test the suitability of PTL materials for use in electrolysis for various differential pressures and flow field widths.

  2. Two-dimensional carbon crystals. Electrical transport in single- and double-layer graphene; Zweidimensionale Kohlenstoffkristalle. Elektrischer Transport in Einzel- und Doppellagen-Graphen

    Energy Technology Data Exchange (ETDEWEB)

    Schmidt, Hennrik

    2012-02-03

    In his work atomically thin layers of carbon, socalled graphene, are investigated. These systems exhibit outstanding electronic properties which are analysed using magnetotransport measurements. For this purpose, different types of samples are prepared, analysed and discussed. In addition to conventional single layer and single crystal bilayer systems, folded flakes with twisted planes are examined. Since monolayer graphene is a two dimensional crystal in which every atom sits at the surface, it is very sensitive to any type of perturbation. Three different cases are investigated: Firstly, dopants are removed from the surface and the change in transport properties is monitored. Secondly, the regime of small carrier concentrations is used to observe field induced recharging of inhomogeneities. Thirdly, an atomic force microscope is used to alter the graphene itself in a defined region. The implications of this modification are again investigated using magnetotransport measurements. The influence of one layer on another one is studied in decoupled two layer samples. A folded sample with separatly contacted layers is used to show transport through the folded region. For jointly contacted layers parallel transport measurements are performed to analyse screening effects of an applied electric field and substrate influence. The interaction of the two layers is shown by a significant reduction of the Fermivelocity.

  3. Optimized shielding calculation to the transport of 131I employed in nuclear medicine

    International Nuclear Information System (INIS)

    Sahyun, A.; Sordi, G.M.; Rodrigues, D.; Sanches, M.P.; Romero F, C.R.

    1996-01-01

    The objective of this paper is to present the basis for shielding calculation used in different situations that could occur during the transport of 131 I utilized in nuclear medicine for diagnostic and therapeutic purposes. The aim of these calculation is to optimize the shielding in order to satisfy the transport of radioactive material. These calculations were proposed for estimated activities around 1,85 GBq (50mCi), 3,7 GBq(100mCi) and 7,4 GBq(200mCi), considering the driver of the cargo company and his assistant as the critical group and the general people considered as effect of collective dose. The population density considered in the models is the one related to Sao Paulo city, because the transport is done by the highway across the city and the radioactive material is distributed from west to north and south, where the airports are located. This area ranges a perimeter of 40 km. For the collective dose calculation, it was considered a population dose of less than 1/100 of the annual limit dose for the public. Our main concern is related to the large volume of radioactive material that is transported per week, specially because 1/3 of this material has activities around 3,7 GBq (100mCi). During the calculations, we have figured out that the activities at the moment of transport are nearly 40% greater than the one related to the calibration date. As for the discrepancy of official alpha value of US$10000/man-Sv and the real value for our country of US$3000/man-Sv,a comparative study was performed. (authors). 3 refs., 2 figs., 2 tabs

  4. Colloidal metal oxide nanocrystals as charge transporting layers for solution-processed light-emitting diodes and solar cells.

    Science.gov (United States)

    Liang, Xiaoyong; Bai, Sai; Wang, Xin; Dai, Xingliang; Gao, Feng; Sun, Baoquan; Ning, Zhijun; Ye, Zhizhen; Jin, Yizheng

    2017-03-21

    Colloidal metal oxide nanocrystals offer a unique combination of excellent low-temperature solution processability, rich and tuneable optoelectronic properties and intrinsic stability, which makes them an ideal class of materials as charge transporting layers in solution-processed light-emitting diodes and solar cells. Developing new material chemistry and custom-tailoring processing and properties of charge transporting layers based on oxide nanocrystals hold the key to boosting the efficiency and lifetime of all-solution-processed light-emitting diodes and solar cells, and thereby realizing an unprecedented generation of high-performance, low-cost, large-area and flexible optoelectronic devices. This review aims to bridge two research fields, chemistry of colloidal oxide nanocrystals and interfacial engineering of optoelectronic devices, focusing on the relationship between chemistry of colloidal oxide nanocrystals, processing and properties of charge transporting layers and device performance. Synthetic chemistry of colloidal oxide nanocrystals, ligand chemistry that may be applied to colloidal oxide nanocrystals and chemistry associated with post-deposition treatments are discussed to highlight the ability of optimizing processing and optoelectronic properties of charge transporting layers. Selected examples of solution-processed solar cells and light-emitting diodes with oxide-nanocrystal charge transporting layers are examined. The emphasis is placed on the correlation between the properties of oxide-nanocrystal charge transporting layers and device performance. Finally, three major challenges that need to be addressed in the future are outlined. We anticipate that this review will spur new material design and simulate new chemistry for colloidal oxide nanocrystals, leading to charge transporting layers and solution-processed optoelectronic devices beyond the state-of-the-art.

  5. Scrape-off layer transport and deposition studies in DIII-D

    International Nuclear Information System (INIS)

    Groth, M.; Allen, S. L.; Fenstermacher, M. E.; Lasnier, C. J.; Porter, G. D.; Rensink, M. E.; Rognlien, T. D.; Boedo, J. A.; Rudakov, D. L.; Brooks, N. H.; Groebner, R. J.; Leonard, A. W.; West, W. P.; Elder, J. D.; McLean, A. G.; Lisgo, S.; Stangeby, P. C.; Wampler, W. R.; Watkins, J. G.; Whyte, D. G.

    2007-01-01

    Trace 13 CH 4 injection experiments into the main scrape-off layer (SOL) of low density L-mode and high-density H-mode plasmas have been performed in the DIII-D tokamak [J. L. Luxon, Nucl. Fusion 42, 614 (2002)] to mimic the transport and deposition of carbon arising from a main chamber sputtering source. These experiments indicated entrainment of the injected carbon in plasma flow in the main SOL, and transport toward the inner divertor. Ex situ surface analysis showed enhanced 13 C surface concentration at the corner formed by the divertor floor and the angled target plate of the inner divertor in L-mode; in H-mode high surface concentration was found both at the corner and along the surface bounding the private flux region inboard of the outer strike point. Interpretative modeling was made consistent with these experimental results by imposing a parallel carbon ion flow in the main SOL toward the inner target, and a radial pinch toward the separatrix. Predictive modeling carried out to better understand the underlying plasma transport processes suggests that the deuterium flow in the main SOL is related to the degree of detachment of the inner divertor leg. These simulations show that carbon ions are entrained with the deuteron flow in the main SOL via frictional coupling, but higher charge-state carbon ions may be suspended upstream of the inner divertor X-point region due to balance of the friction force and the ion temperature gradient force

  6. Block Copolymer-Tuned Fullerene Electron Transport Layer Enhances the Efficiency of Perovskite Photovoltaics.

    Science.gov (United States)

    Lin, Hsi-Kuei; Su, Yu-Wei; Chen, Hsiu-Cheng; Huang, Yi-Jiun; Wei, Kung-Hwa

    2016-09-21

    In this study, we enhanced the power conversion efficiency (PCE) of perovskite solar cells by employing an electron transfer layer (ETL) comprising [6,6]phenyl-C61-butyric acid methyl ester (PC61BM) and, to optimize its morphology, a small amount of the block copolymer polystyrene-b-poly(ethylene oxide) (PS-b-PEO), positioned on the perovskite active layer. When incorporating 0.375 wt % PS-b-PEO into PC61BM, the PCE of the perovskite photovoltaic device increased from 9.4% to 13.4%, a relative increase of 43%, because of a large enhancement in the fill factor of the device. To decipher the intricate morphology of the ETL, we used synchrotron grazing-incidence small-angle X-ray scattering for determining the PC61BM cluster size, atomic force microscopy and scanning electron microscopy for probing the surface, and transmission electron microscopy for observing the aggregation of PC61BM in the ETL. We found that the interaction between PS-b-PEO and PC61BM resulted in smaller PC61BM clusters that further aggregated into dendritic structures in some domains, a result of the similar polarities of the PS block and PC61BM; this behavior could be used to tune the morphology of the ETL. The optimal PS-b-PEO-mediated PC61BM cluster size in the ETL was 17 nm, a large reduction from 59 nm for the pristine PC61BM layer. This approach of incorporating a small amount of nanostructured block copolymer into a fullerene allowed us to effectively tune the morphology of the ETL on the perovskite active layer and resulted in enhanced fill factors of the devices and thus their device efficiency.

  7. The role of optical phonons in intermediate layer-mediated thermal transport across solid interfaces.

    Science.gov (United States)

    Lee, Eungkyu; Luo, Tengfei

    2017-07-19

    Thermal transport across solid interfaces plays important roles in many applications, especially in the thermal management of modern power electronics. In this study, we use non-equilibrium MD (NEMD) simulations to systematically study a model SiC/GaN interface, which is an important interface in GaN-based power electronics, mated by different intermediate layers (ILs) with the focus on how the atomic masses of the ILs influence the overall thermal conductance. To isolate the mass effect, the Tersoff potential with the same parameters is used to approximate the interatomic interactions between all atoms, with the only differences between materials being their atomic masses. The NEMD results show that the thermal boundary conductance (TBC) of IL-mated interfaces depends not only on the total primitive cell mass of the IL but also on the relative masses of the atoms within the unit cell. By analyzing the vibrational power spectra (VPS) of SiC, IL, and GaN, it is found that the optical phonons play important roles in thermal transport across the solid/solid interfaces. There is an optimal mass ratio of the atoms in the unit cell of the IL that can maximize the overlap of IL optical phonon VPS with those of SiC and GaN. Furthermore, the atomic masses of a number of III-V semiconductor compounds are studied for the ILs. It is shown that when only considering the mass effect, in the classical limit, AlN will be the best IL to enhance thermal transport across SiC/GaN interfaces with an improvement of as much as 27% over that of a pristine SiC/GaN interface. Despite the known limitation of the model (e.g., absence of strain and quantum effects), the results from this work may still provide some useful information for the design of ILs to improve thermal transport across solid/solid interfaces.

  8. Charge transport in quantum dot organic solar cells with Si quantum dots sandwiched between poly(3-hexylthiophene) (P3HT) absorber and bathocuproine (BCP) transport layers

    Science.gov (United States)

    Verma, Upendra Kumar; Kumar, Brijesh

    2017-10-01

    We have modeled a multilayer quantum dot organic solar cell that explores the current-voltage characteristic of the solar cell whose characteristics can be tuned by varying the fabrication parameters of the quantum dots (QDs). The modeled device consists of a hole transport layer (HTL) which doubles up as photon absorbing layer, several quantum dot layers, and an electron transport layer (ETL). The conduction of charge carriers in HTL and ETL has been modeled by the drift-diffusion transport mechanism. The conduction and recombination in the quantum dot layers are described by a system of coupled rate equations incorporating tunneling and bimolecular recombination. Analysis of QD-solar cells shows improved device performance compared to the similar bilayer and trilayer device structures without QDs. Keeping other design parameters constant, solar cell characteristics can be controlled by the quantum dot layers. Bimolecular recombination coefficient of quantum dots is a prime factor which controls the open circuit voltage (VOC) without any significant reduction in short circuit current (JSC).

  9. Transport of plasma impurities and the role of the plasma edge layers for the hot plasma production

    International Nuclear Information System (INIS)

    Drawin, H.W.

    1987-01-01

    The first problem of impurity transport is removal of alpha particles from the interior outward. The second problem is the control of impurities produced in the plasma-wall interaction. Finally there is the problem of using injected impurities for assessment of transport coefficients. The influence of impurity radiation on the power balance of a DT plasma is considered. Limiters and divertors as impurity sources are mentioned and transport equations for impurities are given. As an example iron impurities transport in a hydrogen plasma is considered. The role of the edge layer is emphasized. Finally requirements for plasma diagnostics are stated. 50 refs., 10 figs. (qui)

  10. High-efficiency green phosphorescent organic light-emitting diodes with double-emission layer and thick N-doped electron transport layer

    Energy Technology Data Exchange (ETDEWEB)

    Nobuki, Shunichiro, E-mail: shunichiro.nobuki.nb@hitachi.com [Hitachi Research Laboratory, Hitachi Ltd., 7-1-1 Omika-cho, Hitachi-city, Ibaraki 319-1292 (Japan); Wakana, Hironori; Ishihara, Shingo [Hitachi Research Laboratory, Hitachi Ltd., 7-1-1 Omika-cho, Hitachi-city, Ibaraki 319-1292 (Japan); Mikami, Akiyoshi [Dept. of Electrical Engineering, Kanazawa Institute of Technology, 7-1 Ohgigaoka, Nonoichimachi, Ishikawa 921-8501 (Japan)

    2014-03-03

    We have developed green phosphorescent organic light-emitting diodes (OLEDs) with high external quantum efficiency of 59.7% and power efficiency of 243 lm/W at 2.73 V at 0.053 mA/cm{sup 2}. A double emission layer and a thick n-doped electron transport layer were adopted to improve the exciton recombination factor. A high refractive index hemispherical lens was attached to a high refractive index substrate for extracting light trapped inside the substrate and the multiple-layers of OLEDs to air. Additionally, we analyzed an energy loss mechanism to clarify room for the improvement of our OLEDs including the charge balance factor. - Highlights: • We developed high efficiency green phosphorescent organic light-emitting diode (OLED). • Our OLED had external quantum efficiency of 59.7% and power efficiency of 243 lm/W. • A double emission layer and thick n-doped electron transport layer were adopted. • High refractive index media (hemispherical lens and substrate) were also used. • We analyzed an energy loss mechanism to clarify the charge balance factor of our OLED.

  11. Copper thiocyanate: An attractive hole transport/extraction layer for use in organic photovoltaic cells

    Energy Technology Data Exchange (ETDEWEB)

    Treat, Neil D., E-mail: neil.treat@imperial.ac.uk, E-mail: t.anthopoulos@imperial.ac.uk; Stingelin, Natalie [Department of Materials and Centre for Plastic Electronics, Imperial College London, South Kensington Campus, London SW7 2AZ (United Kingdom); Yaacobi-Gross, Nir; Faber, Hendrik; Perumal, Ajay K.; Bradley, Donal D. C.; Anthopoulos, Thomas D., E-mail: neil.treat@imperial.ac.uk, E-mail: t.anthopoulos@imperial.ac.uk [Department of Physics and Centre for Plastic Electronics, Blackett Laboratory, Imperial College London, South Kensington Campus, London SW7 2AZ (United Kingdom)

    2015-07-06

    We report the advantageous properties of the inorganic molecular semiconductor copper(I) thiocyanate (CuSCN) for use as a hole collection/transport layer (HTL) in organic photovoltaic (OPV) cells. CuSCN possesses desirable HTL energy levels [i.e., valence band at −5.35 eV, 0.35 eV deeper than poly(3,4-ethylenedioxythiophene):polystyrenesulfonate (PEDOT:PSS)], which produces a 17% increase in power conversion efficiency (PCE) relative to PEDOT:PSS-based devices. In addition, a two-fold increase in shunt resistance for the solar cells measured in dark conditions is achieved. Ultimately, CuSCN enables polymer:fullerene based OPV cells to achieve PCE > 8%. CuSCN continues to offer promise as a chemically stable and straightforward replacement for the commonly used PEDOT:PSS.

  12. Graphene oxide hole transport layers for large area, high efficiency organic solar cells

    Science.gov (United States)

    Smith, Chris T. G.; Rhodes, Rhys W.; Beliatis, Michail J.; Imalka Jayawardena, K. D. G.; Rozanski, Lynn J.; Mills, Christopher A.; P. Silva, S. Ravi

    2014-08-01

    Graphene oxide (GO) is becoming increasingly popular for organic electronic applications. We present large active area (0.64 cm2), solution processable, poly[[9-(1-octylnonyl)-9H-carbazole-2,7-diyl]-2,5-thiophenediyl-2,1,3-benzothiadiazole-4,7-diyl-2,5-thiophenediyl]:[6,6]-Phenyl C71 butyric acid methyl ester (PCDTBT:PC70BM) organic photovoltaic (OPV) solar cells, incorporating GO hole transport layers (HTL). The power conversion efficiency (PCE) of ˜5% is the highest reported for OPV using this architecture. A comparative study of solution-processable devices has been undertaken to benchmark GO OPV performance with poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS) HTL devices, confirming the viability of GO devices, with comparable PCEs, suitable as high chemical and thermal stability replacements for PEDOT:PSS in OPV.

  13. Towards printed perovskite solar cells with cuprous oxide hole transporting layers

    DEFF Research Database (Denmark)

    Wang, Yan; Xia, Zhonggao; Liang, Jun

    2015-01-01

    Solution-processed p-type metal oxide materials have shown great promise in improving the stability of perovskite-based solar cells and offering the feasibility for a low cost printing fabrication process. Herein, we performed a device modeling study on planar perovskite solar cells with cuprous...... oxide (Cu2O) hole transporting layers (HTLs) by using a solar cell simulation program, wxAMPS. The performance of a Cu2O/perovskite solar cell was correlated to the material properties of the Cu2O HTL, such as thickness, carrier mobility, mid-gap defect, and doping...... concentrations. The effect of interfacial defect densities on the solar cell performance was also investigated. Our simulation indicates that, with an optimized Cu2O HTL, high performance perovskite solar cells with efficiencies above 13% could be achieved, which shows the potential of using Cu2...

  14. Parameterizing Urban Canopy Layer transport in an Lagrangian Particle Dispersion Model

    Science.gov (United States)

    Stöckl, Stefan; Rotach, Mathias W.

    2016-04-01

    The percentage of people living in urban areas is rising worldwide, crossed 50% in 2007 and is even higher in developed countries. High population density and numerous sources of air pollution in close proximity can lead to health issues. Therefore it is important to understand the nature of urban pollutant dispersion. In the last decades this field has experienced considerable progress, however the influence of large roughness elements is complex and has as of yet not been completely described. Hence, this work studied urban particle dispersion close to source and ground. It used an existing, steady state, three-dimensional Lagrangian particle dispersion model, which includes Roughness Sublayer parameterizations of turbulence and flow. The model is valid for convective and neutral to stable conditions and uses the kernel method for concentration calculation. As most Lagrangian models, its lower boundary is the zero-plane displacement, which means that roughly the lower two-thirds of the mean building height are not included in the model. This missing layer roughly coincides with the Urban Canopy Layer. An earlier work "traps" particles hitting the lower model boundary for a recirculation period, which is calculated under the assumption of a vortex in skimming flow, before "releasing" them again. The authors hypothesize that improving the lower boundary condition by including Urban Canopy Layer transport could improve model predictions. This was tested herein by not only trapping the particles, but also advecting them with a mean, parameterized flow in the Urban Canopy Layer. Now the model calculates the trapping period based on either recirculation due to vortex motion in skimming flow regimes or vertical velocity if no vortex forms, depending on incidence angle of the wind on a randomly chosen street canyon. The influence of this modification, as well as the model's sensitivity to parameterization constants, was investigated. To reach this goal, the model was

  15. Electronic transport and dielectric properties of low-dimensional structures of layered transition metal dichalcogenides

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, Ashok, E-mail: ashok.1777@yahoo.com; Ahluwalia, P.K., E-mail: pk_ahluwalia7@yahoo.com

    2014-02-25

    Graphical abstract: We present electronic transport and dielectric response of layered transition metal dichalcogenides nanowires and nanoribbons. Illustration 1: Conductance (G) and corresponding local density of states(LDOS) for LTMDs wires at applied bias. I–V characterstics are shown in lowermost panels. Highlights: • The studied configurations show metallic/semiconducting nature. • States around the Fermi energy are mainly contributed by the d orbitals of metal atoms. • The studied configurations show non-linear current–voltage (I–V) characteristics. • Additional plasmonic features at low energy have been observed for both wires and ribbons. • Dielectric functions for both wires and ribbons are anisotropic (isotropic) at low (high) energy range. -- Abstract: We present first principle study of the electronic transport and dielectric properties of nanowires and nanoribbons of layered transition metal dichalcogenides (LTMDs), MX{sub 2} (M = Mo, W; X = S, Se, Te). The studied configuration shows metallic/semiconducting nature and the states around the Fermi energy are mainly contributed by the d orbitals of metal atoms. Zero-bias transmission show 1G{sub 0} conductance for the ribbons of MoS{sub 2} and WS{sub 2}; 2G{sub 0} conductance for MoS{sub 2}, WS{sub 2}, WSe{sub 2} wires, and ribbons of MoTe{sub 2} and WTe{sub 2}; and 3G{sub 0} conductance for WSe{sub 2} ribbon. The studied configurations show non-linear current–voltage (I–V) characteristics. Negative differential conductance (NDC) has also been observed for the nanoribbons of the selenides and tellurides of both Mo and W. Furthermore, additional plasmonic features below 5 eV energy have been observed for both wires and ribbons as compared to the corresponding monolayers, which is found to be red-shifted on going from nanowires to nanoribbons.

  16. Effective transport coefficients in PEM fuel cell catalyst and gas diffusion layers: Beyond Bruggeman approximation

    Energy Technology Data Exchange (ETDEWEB)

    Das, Prodip K. [Department of Mechanical and Mechatronics Engineering, University of Waterloo, 200 University Avenue West, Waterloo, ON (Canada); Institute for Fuel Cell Innovation, National Research Council, Vancouver, BC (Canada); Li, Xianguo [Department of Mechanical and Mechatronics Engineering, University of Waterloo, 200 University Avenue West, Waterloo, ON (Canada); Liu, Zhong-Sheng [Institute for Fuel Cell Innovation, National Research Council, Vancouver, BC (Canada)

    2010-09-15

    The Bruggeman approximation has widely been used for estimating the effective conductivity and diffusivity of both the catalyst and gas diffusion layers of polymer electrolyte membrane (PEM) fuel cells. This approximation is based on the Bruggeman's Effective Medium Theory [Bruggeman D. Berechnung verschiedener physikalischer konstanten von heterogenen substanzen. Ann Phys (Leipzig) 1935;24:636-79], which provides empirical correlation for the effective properties of a composite system. Since it is an empirical correlation, a unique correlation based on the Bruggeman approximation does not always hold for the PEM fuel cell effective properties. Rather, the Bruggeman correlation is a cell specific and experiment dependent correlation that depends on structure, phase composition, water saturation, experimental parameters, etc. Further, this correlation needs to be combined with other correlations to estimate the effective diffusivities. In this article, a set of mathematical formulations has been proposed for the effective transport properties in both the catalyst and gas diffusion layers of a PEM fuel cell. The effective conductivity and diffusivity expressions are derived from the mathematical formulations of the Hashin Coated Sphere model [Hashin Z. The elastic moduli of heterogeneous materials. J Appl Mech 1962;29:143-50], which provides an identical mathematical foundation for each of these effective properties rather than an empirical correlation and avoid to use of multiple correlations together. The present model formulations agree well with the results available in literature for the limiting case. Hence, the proposed formulations for the effective transport properties will be a useful estimating tool in the numerical modeling of PEM fuel cells. (author)

  17. Transport of desert dust mixed with North African industrial pollutants in the subtropical Saharan Air Layer

    Directory of Open Access Journals (Sweden)

    S. Rodríguez

    2011-07-01

    Full Text Available An analysis of chemical composition data of particulate matter samples (TSP, PM10 and PM2.5 collected from 2002 to 2008 in the North Atlantic free troposphere at the Izaña Global Atmospheric Watch (GAW observatory (Tenerife, Canary Islands shows that desert dust is very frequently mixed with particulate pollutants in the Saharan Air Layer (SAL. The study of this data set with Median Concentrations At Receptor (MCAR plots allowed the identification of the potential source regions of the dust and particulate pollutants. Areas located at the south of the southern slope of the Atlas mountains emerge as the most frequent source of the soil desert dust advected to the northern edge of the SAL in summer. Industrial emissions occurring in Northern Algeria, Eastern Algeria, Tunisia and the Atlantic coast of Morocco appear as the most important source of the nitrate, ammonium and a fraction of sulphate (at least 60 % of the sulphate <10 μm transported from some regions observed in the SAL. These emissions are mostly linked to crude oil refineries, phosphate-based fertilizer industry and power plants. Although desert dust emissions appear as the most frequent source of the phosphorous observed in the SAL, high P concentrations are observed when the SAL is affected by emissions from open mines of phosphate and phosphate based fertilizer industry. The results also show that a significant fraction of the sulphate (up to 90 % of sulphate <10 μm transported from some regions observed in the SAL may be influenced by soil emissions of evaporite minerals in well defined regions where dry saline lakes (chotts are present. These interpretations of the MCAR plots are consistent with the results obtained with the Positive Matrix Factorization (PMF2 receptor modelling. The results of this study show that North African industrial pollutants may be mixed with desert dust and exported to the North Atlantic in the Saharan Air Layer.

  18. Lipoprotein transport in the metabolic syndrome: pathophysiological and interventional studies employing stable isotopy and modelling methods.

    Science.gov (United States)

    Chan, Dick C; Barrett, P Hugh R; Watts, Gerald F

    2004-09-01

    The accompanying review in this issue of Clinical Science [Chan, Barrett and Watts (2004) Clin. Sci. 107, 221-232] presented an overview of lipoprotein physiology and the methodologies for stable isotope kinetic studies. The present review focuses on our understanding of the dysregulation and therapeutic regulation of lipoprotein transport in the metabolic syndrome based on the application of stable isotope and modelling methods. Dysregulation of lipoprotein metabolism in metabolic syndrome may be due to a combination of overproduction of VLDL [very-LDL (low-density lipoprotein)]-apo (apolipoprotein) B-100, decreased catabolism of apoB-containing particles and increased catabolism of HDL (high-density lipoprotein)-apoA-I particles. These abnormalities may be consequent on a global metabolic effect of insulin resistance, partly mediated by depressed plasma adiponectin levels, that collectively increases the flux of fatty acids from adipose tissue to the liver, the accumulation of fat in the liver and skeletal muscle, the hepatic secretion of VLDL-triacylglycerols and the remodelling of both LDL (low-density lipoprotein) and HDL particles in the circulation. These lipoprotein defects are also related to perturbations in both lipolytic enzymes and lipid transfer proteins. Our knowledge of the pathophysiology of lipoprotein metabolism in the metabolic syndrome is well complemented by extensive cell biological data. Nutritional modifications may favourably alter lipoprotein transport in the metabolic syndrome by collectively decreasing the hepatic secretion of VLDL-apoB and the catabolism of HDL-apoA-I, as well as by potentially increasing the clearance of LDL-apoB. Several pharmacological treatments, such as statins, fibrates or fish oils, can also correct the dyslipidaemia by diverse kinetic mechanisms of action, including decreased secretion and increased catabolism of apoB, as well as increased secretion and decreased catabolism of apoA-I. The complementary

  19. Turbulent transport regimes and the scrape-off layer heat flux width

    Science.gov (United States)

    Myra, J. R.; D'Ippolito, D. A.; Russell, D. A.

    2015-04-01

    Understanding the responsible mechanisms and resulting scaling of the scrape-off layer (SOL) heat flux width is important for predicting viable operating regimes in future tokamaks and for seeking possible mitigation schemes. In this paper, we present a qualitative and conceptual framework for understanding various regimes of edge/SOL turbulence and the role of turbulent transport as the mechanism for establishing the SOL heat flux width. Relevant considerations include the type and spectral characteristics of underlying instabilities, the location of the gradient drive relative to the SOL, the nonlinear saturation mechanism, and the parallel heat transport regime. We find a heat flux width scaling with major radius R that is generally positive, consistent with the previous findings [Connor et al., Nucl. Fusion 39, 169 (1999)]. The possible relationship of turbulence mechanisms to the neoclassical orbit width or heuristic drift mechanism in core energy confinement regimes known as low (L) mode and high (H) mode is considered, together with implications for the future experiments.

  20. Effect of hydrophobic additive on oxygen transport in catalyst layer of proton exchange membrane fuel cells

    Science.gov (United States)

    Wang, Shunzhong; Li, Xiaohui; Wan, Zhaohui; Chen, Yanan; Tan, Jinting; Pan, Mu

    2018-03-01

    Oxygen transport resistance (OTR) is a critical factor influencing the performance of proton exchange membrane fuel cells (PEMFCs). In this paper, an effective method to reduce the OTR of catalyst layers (CLs) by introducing a hydrophobic additive into traditional CLs is proposed. A low-molecular-weight polytetrafluoroethylene (PTFE) is selected for its feasibility to prepare an emulsion, which is mixed with a traditional catalyst ink to successfully fabricate the CL with PTFE of 10 wt%. The PTFE film exists in the mesopores between the carbon particles. The limiting current of the hydrophobic CL was almost 4000 mA/cm2, which is 500 mA/cm2 higher than that of the traditional CL. PTFE reduces the OTR of the CL in the dry region by as much as 24 s/m compared to the traditional CL and expands the dry region from 2000 mA/cm2 in the traditional CL to 2500 mA/cm2. Furthermore, the CL with the hydrophobic agent can improve the oxygen transport in the wet region (>2000 mA/cm2) more effectively than that in the dry region. All these results indicate that the CL with the hydrophobic agent shows a superior performance in terms of optimizing water management and effectively reduces the OTR in PEMFCs.

  1. Solution-Processed Metal Oxides as Efficient Carrier Transport Layers for Organic Photovoltaics.

    Science.gov (United States)

    Choy, Wallace C H; Zhang, Di

    2016-01-27

    Carrier (electron and hole) transport layers (CTLs) are essential components for boosting the performance of various organic optoelectronic devices such as organic solar cells and organic light-emitting diodes. Considering the drawbacks of conventional CTLs (easily oxidized/unstable, demanding/costly fabrication, etc.), transition metal oxides with good carrier transport/extraction and superior stability have drawn extensive research interest as CTLs for next-generation devices. In recent years, many research efforts have been made toward the development of solution-based metal oxide CTLs with the focus on low- or even room-temperature processes, which can potentially be compatible with the deposition processes of organic materials and can significantly contribute to the low-cost and scale-up of organic devices. Here, the recent progress of different types of solution-processed metal oxide CTLs are systematically reviewed in the context of organic photovoltaics, from synthesis approaches to device performance. Different approaches for further enhancing the performance of solution-based metal oxide CTLs are also discussed, which may push the future development of this exciting field. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Inverted polymer solar cell based on MEH-PPV/PC61BM coupled with ZnO nanoparticles as electron transport layer

    Science.gov (United States)

    Salem, A. M. S.; El-Sheikh, S. M.; Harraz, Farid A.; Ebrahim, S.; Soliman, M.; Hafez, H. S.; Ibrahim, I. A.; Abdel-Mottaleb, M. S. A.

    2017-12-01

    In this work, we demonstrate the use of annealed sol-gel derived ZnO nanoparticles acting as electron transport layer (ETL) in inverted bulk heterojunction (BHJ) polymer solar cells (PSCs). We have examined the photovoltaic performance of devices based on poly(2-methoxy-5-(2-ethylhexyloxy)-p-phenylenevinylene) (MEH-PPV):(6,6)-phenyl-C61-butyric acid methyl ester (PC61BM) blend system employing the ZnO nanoparticles as an ETL with CuI as hole transport layer (HTL) in comparison to the case of using the conventional HTL of poly(3,4-ethylenedioxythiophene)/poly(styrene sulfonate) sulfonic acid (PEDOT:PSS). The effect of the presence of another layer of ZnO macrospheres attached to the ZnO nanoparticles is also investigated. The highest power conversion efficiency (PCE) value of 1.35% was achieved for device: ITO/ZnO nanoparticles/MEH-PPV:PC61BM/CuI/Ag, which is 275% more the value obtained when CuI was replaced by PEDOT:PSS. The comprehensive analyses on structural and optical characteristics including SEM, XRD, FTIR, PL and UV-vis spectroscopy indicated that the use of the ZnO nanoparticles alone as ETL, together with the CuI as HTL could effectively reduce trap-assisted recombination and charge accumulation at the interface, which is beneficial for the enhanced device performance.

  3. The design, fabrication and maintenance of semi-trailers employed in the highway transport of weight-concentrated radioactive loads

    Energy Technology Data Exchange (ETDEWEB)

    Huffman, D.S. [Allied-Signal Inc., Metropolis, IL (United States)

    1991-12-31

    Transportation of weight-concentrated radioactive loads by truck is an essential part of a safe and economical nuclear industry. This proposed standard presents guidance and performance criteria for the safe transport of these weight-concentrated radioactive loads. ANSI N14.30 will detail specific requirements for the design, fabrication, testing, in-service inspections, maintenance and certification of the semi-trailers to be employed in said service. Furthermore, guidelines for a quality assurance program are also enumerated. This standard would apply to any semi-trailer that may or may not be specifically designed to carry weight-concentrated loads. Equipment not suitable per the criteria established in the standard would be removed from service. The nature of the nuclear industry and the need for a positive public perception of the various processes and players, mandates that the highway transportation of weight-concentrated radioactive loads be standardized and made inherently safe. This proposed standard takes a giant step in that direction.

  4. Optimization of an Electron Transport Layer to Enhance the Power Conversion Efficiency of Flexible Inverted Organic Solar Cells

    Directory of Open Access Journals (Sweden)

    Lee Kang Hyuck

    2010-01-01

    Full Text Available Abstract The photovoltaic (PV performance of flexible inverted organic solar cells (IOSCs with an active layer consisting of a blend of poly(3-hexylthiophene and [6, 6]-phenyl C61-butlyric acid methyl ester was investigated by varying the thicknesses of ZnO seed layers and introducing ZnO nanorods (NRs. A ZnO seed layer or ZnO NRs grown on the seed layer were used as an electron transport layer and pathway to optimize PV performance. ZnO seed layers were deposited using spin coating at 3,000 rpm for 30 s onto indium tin oxide (ITO-coated polyethersulphone (PES substrates. The ZnO NRs were grown using an aqueous solution method at a low temperature (90°C. The optimized device with ZnO NRs exhibited a threefold increase in PV performance compared with that of a device consisting of a ZnO seed layer without ZnO NRs. Flexible IOSCs fabricated using ZnO NRs with improved PV performance may pave the way for the development of PV devices with larger interface areas for effective exciton dissociation and continuous carrier transport paths.

  5. Rapid Transport of Stratospheric Ozone into the Planetary Boundary Layer over the Rocky Mountains

    Science.gov (United States)

    Skerlak, B.; Sprenger, M.; Pfahl, S.; Wernli, H.

    2013-12-01

    Stratosphere-troposphere exchange (STE) has important impacts on atmospheric chemistry: it changes the oxidative capacity of the troposphere and affects the climate system through the exchange of water vapor and ozone. Although a large part of tropospheric ozone is produced photochemically, significant amounts of stratospheric ozone can be brought into the troposphere during STE events. The relative importance of these two sources depends on the location of interest and transport characteristics. Of particular interest are so-called deep exchange events where ozone-rich stratospheric air reaches the planetary boundary layer (PBL) within a few days (deep STT). This rapid vertical transport can contribute to ozone concentrations at ground level which can impair plant and human physiology. It is therefore not only important to quantify the ozone flux across the tropopause but also to investigate the transport pathways after the crossing to identify affected areas at ground. Using a Lagrangian methodology and 33 years of ERA-Interim reanalysis data, we have compiled a global climatology of STE from which the mountainous areas in western North America can be identified as a 'hot spot' of deep STT, especially in boreal spring. To address the question of how the stratospheric air masses are transported into the PBL in more detail, we investigate case studies in this region with the mesoscale numerical weather prediction model COSMO. On this account, we initialize a passive tracer in the stratosphere using an elaborated 3D-labeling algorithm which applies the dynamical 2 pvu/380 K tropopause definition. This tracer is then advected by both resolved and parameterized processes and allows us to follow the stratospheric air masses along their journey into the mountainous PBL. Although this tracer does not directly represent a specific chemical species, its concentrations at the lowest model level can indicate when and where ozone levels at ground are likely to be influenced

  6. Transport of desert dust mixed with North African industrial pollutants in the subtropical Saharan Air Layer

    Science.gov (United States)

    Rodríguez, S.; Alastuey, A.; Alonso-Pérez, S.; Querol, X.; Cuevas, E.; Abreu-Afonso, J.; Viana, M.; Pérez, N.; Pandolfi, M.; de La Rosa, J.

    2011-07-01

    An analysis of chemical composition data of particulate matter samples (TSP, PM10 and PM2.5) collected from 2002 to 2008 in the North Atlantic free troposphere at the Izaña Global Atmospheric Watch (GAW) observatory (Tenerife, Canary Islands) shows that desert dust is very frequently mixed with particulate pollutants in the Saharan Air Layer (SAL). The study of this data set with Median Concentrations At Receptor (MCAR) plots allowed the identification of the potential source regions of the dust and particulate pollutants. Areas located at the south of the southern slope of the Atlas mountains emerge as the most frequent source of the soil desert dust advected to the northern edge of the SAL in summer. Industrial emissions occurring in Northern Algeria, Eastern Algeria, Tunisia and the Atlantic coast of Morocco appear as the most important source of the nitrate, ammonium and a fraction of sulphate (at least 60 % of the sulphate phosphate-based fertilizer industry and power plants. Although desert dust emissions appear as the most frequent source of the phosphorous observed in the SAL, high P concentrations are observed when the SAL is affected by emissions from open mines of phosphate and phosphate based fertilizer industry. The results also show that a significant fraction of the sulphate (up to 90 % of sulphate <10 μm transported from some regions) observed in the SAL may be influenced by soil emissions of evaporite minerals in well defined regions where dry saline lakes (chotts) are present. These interpretations of the MCAR plots are consistent with the results obtained with the Positive Matrix Factorization (PMF2) receptor modelling. The results of this study show that North African industrial pollutants may be mixed with desert dust and exported to the North Atlantic in the Saharan Air Layer.

  7. Slot-Die-Coated V2O5 as Hole Transport Layer for Flexible Organic Solar Cells and Optoelectronic Devices

    DEFF Research Database (Denmark)

    Beliatis, Michail; Helgesen, Martin; Garcia Valverde, Rafael

    2016-01-01

    Vanadium pentoxide has been proposed as a good alternative hole transport layer for improving device lifetime of organic photovoltaics. The article presents a study on the optimization of slot-die-coated vanadium oxide films produced with a roll coating machine with the aim of achieving scalable ...

  8. Water transport in the gas diffusion layer of a polymer electrolyte fuel cell : Dynamic Pore-Network Modeling

    NARCIS (Netherlands)

    Qin, C.

    2015-01-01

    The pore-scale modeling is a powerful tool for increasing our understanding of water transport in the fibrous gas diffusion layer (GDL) of a polymer electrolyte fuel cell (PEFC). In this work, a new dynamic pore-network model for air-water flow in the GDL is developed. It incorporates water vapor

  9. Electrical transport and Al doping efficiency in nanoscale ZnO films prepared by atomic layer deposition

    NARCIS (Netherlands)

    Wu, Y.; Hermkens, P.M.; Loo, B.W.H. van de; Knoops, H.C.M.; Potts, S.E.; Verheijen, M.A.; Roozeboom, F.; Kessels, W.M.M.

    2013-01-01

    In this work, the structural, electrical, and optical properties as well as chemical bonding state of Al-doped ZnO films deposited by atomic layer deposition have been investigated to obtain insight into the doping and electrical transport mechanisms in the films. The range in doping levels from 0%

  10. Regional atmospheric budgets of reduced nitrogen over the British isles assessed using a multi-layer atmospheric transport model

    NARCIS (Netherlands)

    Fournier, N.; Tang, Y.S.; Dragosits, U.; Kluizenaar, Y.de; Sutton, M.A.

    2005-01-01

    Atmospheric budgets of reduced nitrogen for the major political regions of the British Isles are investigated with a multi-layer atmospheric transport model. The model is validated against measurements of NH3 concentration and is developed to provide atmospheric budgets for defined subdomains of the

  11. Three-dimensional architecture hybrid perovskite solar cells using CdS nanorod arrays as an electron transport layer

    Science.gov (United States)

    Song, Zihang; Tong, Guoqing; Li, Huan; Li, Guopeng; Ma, Shuai; Yu, Shimeng; Liu, Qian; Jiang, Yang

    2018-01-01

    Three-dimensional (3D) architecture perovskite solar cells (PSCs) using CdS nanorod (NR) arrays as an electron transport layer were designed and prepared layer-by-layer via a physical-chemical vapor deposition (P-CVD) process. The CdS NRs not only provided a scaffold to the perovskite film, but also increased the interfacial contact between the perovskite film and electron transport layer. As an optimized result, a high power conversion efficiency of 12.46% with a short-circuit current density of 19.88 mA cm‑2, an open-circuit voltage of 1.01 V and a fill factor of 62.06% was obtained after 12 h growth of CdS NRs. It was four times the efficiency of contrast planar structure with a similar thickness. The P-CVD method assisted in achieving flat and voidless CH3NH3PbI3‑x Cl x perovskite film and binding the CdS NRs and perovskite film together. The different density of CdS NRs had obvious effects on light transmittance of 350–550 nm, the interfacial area and the difficulty of combining layers. Moreover, the efficient 1D transport paths for electrons and multiple absorption of light, which are generated in 3D architecture, were beneficial to realize a decent power conversion efficiency.

  12. GaN full-vertical p-i-n rectifiers employing AlGaN:Si conducting buffer layers on n-SiC substrates

    International Nuclear Information System (INIS)

    Yoo, D.; Limb, J.; Ryou, J.-H.; Lee, W.; Dupuis, R.D.

    2006-01-01

    The development of a full-vertical GaN p-i-n rectifier on a 6H n-type SiC substrate by employing a conducting Al x Ga 1-x N:Si (x=∼0.1) buffer layer scheme is reported. In this vertical configuration, the n contact is made on the backside of the SiC substrate using a Ni/Au metallization scheme. Epitaxial layers are grown by low-pressure metal organic chemical vapor deposition. The Al x Ga 1-x N:Si nucleation layer is proven to provide excellent electrical properties while also acting as a good buffer layer for subsequent GaN growth. The reverse breakdown voltage for a relatively thin 2.5 μm thick i region was found to be over -330 V. The devices also show a low on resistance of R on of 7.5x10 -3 Ω cm 2 . This full-vertical configuration provides the advantage of the reduction of sidewall damage from plasma etching and lower forward resistance due to the reduction of current crowding in the bottom n-type layer

  13. Acoustic-sounder investigation of the effects of boundary-layer decoupling on long-distance polutant transport

    International Nuclear Information System (INIS)

    Miller, E.L.

    1976-01-01

    The formation of the nocturnal surface temperature inversion results in a decrease in vertical momentum transfer which, in turn, is accompanied by an associated reduction in the transfer of pollutants from the atmosphere to surface sinks, thus decoupling the surface layer from the layer above the inversion. The diurnal oscillation in the surface temperature profiles may therefore have a significant effect upon the transport of atmospheric pollutants over long distances. Flights of a large manned balloon with a diverse array of chemical and meteorological instrumentation aboard, known as Project de Vinci, provided a unique opportunity to combine acoustic-sounder observations of qualitative temperature structure in the atmospheric boundary layer with the chemical measurements necessary to gain increased understanding of this decoupling process and its consequences for pollutant transport. The data collected on ozone on the balloon and the grounds are reported

  14. New Physical Deposition Approach for Low Cost Inorganic Hole Transport Layer in Normal Architecture of Durable Perovskite Solar Cells.

    Science.gov (United States)

    Nejand, Bahram Abdollahi; Ahmadi, Vahid; Shahverdi, Hamid Reza

    2015-10-07

    In this work we reported sputter deposited NiOx/Ni double layer as an HTM/contact couple in normal architecture of perovskite solar cell. A perovskite solar cell that is durable for more than 60 days was achieved, with increasing efficiency from 1.3% to 7.28% within 6 days. Moreover, low temperature direct deposition of NiOx layer on perovskite layer was introduced as a potential hole transport material for an efficient cost-effective solar cell applicable for various morphologies of perovskite layers, even for perovskite layers containing pinholes, which is a notable challenge in perovskite solar cells. The angular deposition of NiOx layers by dc reactive magnetron sputtering showed uniform and crack-free coverage of the perovskite layer with no negative impact on perovskite structure that is suitable for nickel back contact layer, surface shielding against moisture, and mechanical damages. Replacing the expensive complex materials in previous perovskite solar cells with low cost available materials introduces cost-effective scalable perovskite solar cells.

  15. Observed bottom boundary layer transport and uplift on the continental shelf adjacent to a western boundary current

    Science.gov (United States)

    Schaeffer, A.; Roughan, M.; Wood, J. E.

    2014-08-01

    Western boundary currents strongly influence the dynamics on the adjacent continental shelf and in particular the cross-shelf transport and uplift through the bottom boundary layer. Four years of moored in situ observations on the narrow southeastern Australian shelf (in water depths of between 65 and 140 m) were used to investigate bottom cross-shelf transport, both upstream (30°S) and downstream (34°S) of the separation zone of the East Australian Current (EAC). Bottom transport was estimated and assessed against Ekman theory, showing consistent results for a number of different formulations of the boundary layer thickness. Net bottom cross-shelf transport was onshore at all locations. Ekman theory indicates that up to 64% of the transport variability is driven by the along-shelf bottom stress. Onshore transport in the bottom boundary layer was more intense and frequent upstream than downstream, occurring 64% of the time at 30°S. Wind-driven surface Ekman transport estimates did not balance the bottom cross-shelf flow. At both locations, strong variability was found in bottom water transport at periods of approximately 90-100 days. This corresponds with periodicity in EAC fluctuations and eddy shedding as evidenced from altimeter observations, highlighting the EAC as a driver of variability in the continental shelf waters. Ocean glider and HF radar observations were used to identify the bio-physical response to an EAC encroachment event, resulting in a strong onshore bottom flow, the uplift of cold slope water, and elevated coastal chlorophyll concentrations.

  16. Risk assessment of nitrate transport through subsurface layers and groundwater using experimental and modeling approach.

    Science.gov (United States)

    Alslaibi, Tamer M; Abunada, Ziyad; Abu Amr, Salem S; Abustan, Ismail

    2017-09-22

    Landfills are one of the main point sources of groundwater pollution. This research mainly aims to assess the risk of nitrate [Formula: see text] transport from the unlined landfill to subsurface layers and groundwater using experimental results and the SESOIL model. Samples from 12 groundwater wells downstream of the landfill were collected and analyzed in 2008, 21 years after the landfill construction. The average [Formula: see text] concentration in the wells was 54 mg/L, slightly higher than the World Health Organization ([Formula: see text] 50 mg/L) standards. SESOIL model was used to predict the [Formula: see text] concentration at the bottom of the unsaturated zone. Results indicated that the current mean [Formula: see text] concentration at the bottom of the unsaturated zone is 75 mg/L. the model predicted that the level of NO 3 will increased up to 325 mg/L within 30 years. Accordingly, the [Formula: see text] concentration in groundwater wells near the landfill area is expected to gradually increase with time. Although the current risk associated with the [Formula: see text] level might not be harm to adults, however, it might pose severe risks to both adults and infants in the near future due to [Formula: see text] leaching. Urgent mitigation measures such as final cell cover (cap), lining system and vertical expansion should be considered at the landfill to protect the public health in the area.

  17. Mechanical and transport properties of layer-by-layer electrospun composite proton exchange membranes for fuel cell applications.

    Science.gov (United States)

    Mannarino, Matthew M; Liu, David S; Hammond, Paula T; Rutledge, Gregory C

    2013-08-28

    Composite membranes composed of highly conductive and selective layer-by-layer (LbL) films and electrospun fiber mats were fabricated and characterized for mechanical strength and electrochemical selectivity. The LbL component consists of a proton-conducting, methanol-blocking poly(diallyl dimethyl ammonium chloride)/sulfonated poly(2,6-dimethyl-1,4-phenylene oxide) (PDAC/sPPO) thin film. The electrospun fiber component consists of poly(trimethyl hexamethylene terephthalamide) (PA 6(3)T) fibers in a nonwoven mat of 60-90% porosity. The bare mats were annealed to improve their mechanical properties, which improvements are shown to be retained in the composite membranes. Spray LbL assembly was used as a means for the rapid formation of proton-conducting films that fill the void space throughout the porous electrospun matrix and create a fuel-blocking layer. Coated mats as thin as 15 μm were fabricated, and viable composite membranes with methanol permeabilities 20 times lower than Nafion and through-plane proton selectivity five and a half times greater than Nafion are demonstrated. The mechanical properties of the spray coated electrospun mats are shown to be superior to the LbL-only system and possess intrinsically greater dimensional stability and lower mechanical hysteresis than Nafion under hydrated conditions. The composite proton exchange membranes fabricated here were tested in an operational direct methanol fuel cell. The results show the potential for higher open circuit voltages (OCV) and comparable cell resistances when compared to fuel cells based on Nafion.

  18. Observations of mesoscale and boundary-layer scale circulations affecting dust transport and uplift over the Sahara

    Directory of Open Access Journals (Sweden)

    J. H. Marsham

    2008-12-01

    Full Text Available Observations of the Saharan boundary layer, made during the GERBILS field campaign, show that mesoscale land surface temperature variations (which were related to albedo variations induced mesoscale circulations. With weak winds along the aircraft track, land surface temperature anomalies with scales of greater than 10 km are shown to significantly affect boundary-layer temperatures and winds. Such anomalies are expected to affect the vertical mixing of the dusty and weakly stratified Saharan Residual Layer (SRL. Mesoscale variations in winds are also shown to affect dust loadings in the boundary layer.

    Using the aircraft observations and data from the COSMO model, a region of local dust uplift, with strong along-track winds, was identified in one low-level flight. Large eddy model (LEM simulations based on this location showed linearly organised boundary-layer convection. Calculating dust uplift rates from the LEM wind field showed that the boundary-layer convection increased uplift by approximately 30%, compared with the uplift rate calculated neglecting the convection. The modelled effects of boundary-layer convection on uplift are shown to be larger when the boundary-layer wind is decreased, and most significant when the mean wind is below the threshold for dust uplift and the boundary-layer convection leads to uplift which would not otherwise occur.

    Both the coupling of albedo features to the atmosphere on the mesoscale, and the enhancement of dust uplift by boundary-layer convection are unrepresented in many climate models, but may have significant impacts on the vertical transport and uplift of desert dust. Mesoscale effects in particular tend to be difficult to parametrise.

  19. Heat balance in the catalyst layer and the boundary condition for heat transport equation in a low-temperature fuel cell

    Science.gov (United States)

    Kulikovsky, A. A.

    We consider heat balance in the catalyst layer of a low-temperature fuel cell. Based on the heat transport equation in the layer, the exact boundary condition for the problem of heat transport in the cell is obtained. The limits of validity of the resulting expression are discussed.

  20. Co-precipitation of tobramycin into biomimetically coated orthopedic fixation pins employing submicron-thin seed layers of hydroxyapatite.

    Science.gov (United States)

    Sörensen, Jan H; Lilja, Mirjam; Åstrand, Maria; Sörensen, Torben C; Procter, Philip; Strømme, Maria; Steckel, Hartwig

    2014-01-01

    The migration, loosening and cut-out of implants and nosocomial infections are current problems associated with implant surgery. New innovative strategies to overcome these issues are emphasized in today's research. The current work presents a novel strategy involving co-precipitation of tobramycin with biomimetic hydroxyapatite (HA) formation to produce implant coatings that control local drug delivery to prevent early bacterial colonization of the implant. A submicron- thin HA layer served as seed layer for the co-precipitation process and allowed for incorporation of tobramycin in the coating from a stock solution of antibiotic concentrations as high as 20 mg/ml. Concentrations from 0.5 to 20 mg/ml tobramycin and process temperatures of 37 °C and 60 °C were tested to assess the optimal parameters for a thin tobramycin- delivering HA coating on discs and orthopedic fixation pins. The morphology and thickness of the coating and the drug-release profile were evaluated via scanning electron microscopy and high performance liquid chromatography. The coatings delivered pharmaceutically relevant amounts of tobramycin over a period of 12 days. To the best of our knowledge, this is the longest release period ever observed for a fast-loaded biomimetic implant coating. The presented approach could form the foundation for development of combination device/antibiotic delivery vehicles tailored to meet well-defined clinical needs while combating infections and ensuring fast implant in-growth.

  1. The effects of electron and hole transport layer with the electrode work function on perovskite solar cells

    Science.gov (United States)

    Deng, Quanrong; Li, Yiqi; Chen, Lian; Wang, Shenggao; Wang, Geming; Sheng, Yonglong; Shao, Guosheng

    2016-09-01

    The effects of electron and hole transport layer with the electrode work function on perovskite solar cells with the interface defects were simulated by using analysis of microelectronic and photonic structures-one-dimensional (AMPS-1D) software. The simulation results suggest that TiO2 electron transport layer provides best device performance with conversion efficiency of 25.9% compared with ZnO and CdS. The threshold value of back electrode work function for Spiro-OMeTAD, NiO, CuI and Cu2O hole transport layer are calculated to be 4.9, 4.8, 4.7 and 4.9 eV, respectively, to reach the highest conversion efficiency. The mechanisms of device physics with various electron and hole transport materials are discussed in details. The device performance deteriorates gradually as the increased density of interface defects located at ETM/absorber or absorber/HTM. This research results can provide helpful guidance for materials and metal electrode choice for perovskite solar cells.

  2. Enhanced power conversion efficiency of p-i-n type organic solar cells by employing a p-layer of palladium phthalocyanine

    KAUST Repository

    Kim, Inho

    2010-11-15

    We demonstrate an enhancement in the power conversion efficiency (PCE) of p-i-n type organic solar cells consisting of zinc phthalocyanine (ZnPc) and fullerene (C60) using a p-layer of palladium phthalocyanine (PdPc). Solar cells employing three different device structures such as ZnPc/ZnPc:C60/C60, PdPc/PdPc:C60/C60, and PdPc/ZnPc:C60/C60 with varying thickness of mixed interlayers were fabricated by thermal evaporation. The mixed i-layers were deposited by co-evaporation of MPc (M=Zn,Pd) and C60 by 1:1 ratio. PCE of 3.7% was obtained for optimized cells consisting of PdPc/ZnPc:C60/C60, while cells with device structure of ZnPc/ZnPc:C60/C60 showed PCE of 3.2%.

  3. Layered-disk transport experiments at 1.064μm and 0.355μm

    International Nuclear Information System (INIS)

    Campbell, E.M.; Mead, W.C.; Turner, R.E.

    1981-01-01

    The results of electron transport experiments conducted at 1.064μm and 0.355μm with the Argus Laser will be presented. The experiments were conducted at a fixed absorbed intensity and pulse width of approximately 1-2x10 14 W/cm 2 and 600 psec (FWHM) respectively. Energy on target ranged from 30 to 90 joules. To explore axial transport a variable thickness beryllium layer is coated onto an aluminum substrate. The effectiveness of electron heat conduction is studied by measuring the fall-off in aluminum x-ray yield (line and continuum) as the beryllium thickness is increased. In addition to the axial transport studies, lateral conduction is examined by placing the axial transport target onto a titanium disk

  4. Steady-state and time-dependent modelling of parallel transport in the scrape-off layer

    DEFF Research Database (Denmark)

    Havlickova, E.; Fundamenski, W.; Naulin, Volker

    2011-01-01

    temperature calculated in SOLF1D is compared with the approximative model used in the turbulence code ESEL both for steady-state and turbulent SOL. Dynamics of the parallel transport are investigated for a simple transient event simulating the propagation of particles and energy to the targets from a blob......The one-dimensional fluid code SOLF1D has been used for modelling of plasma transport in the scrape-off layer (SOL) along magnetic field lines, both in steady state and under transient conditions that arise due to plasma turbulence. The presented work summarizes results of SOLF1D with attention...... given to transient parallel transport which reveals two distinct time scales due to the transport mechanisms of convection and diffusion. Time-dependent modelling combined with the effect of ballooning shows propagation of particles along the magnetic field line with Mach number up to M ≈ 1...

  5. Solution processed deposition of electron transport layers on perovskite crystal surface—A modeling based study

    Energy Technology Data Exchange (ETDEWEB)

    Mortuza, S.M.; Taufique, M.F.N.; Banerjee, Soumik, E-mail: soumik.banerjee@wsu.edu

    2017-02-01

    Highlights: • The model determined the surface coverage of solution-processed film on perovskite. • Calculated surface density map provides insight into morphology of the monolayer. • Carbonyl oxygen atom of PCBM strongly attaches to the (110) surface of perovskite. • Uniform distribution of clusters on perovskite surface at lower PCBM concentration. • Deposition rate of PCBM on the surface is very high at initial stage of film growth. - Abstract: The power conversion efficiency (PCE) of planar perovskite solar cells (PSCs) has reached up to ∼20%. However, structural and chemicals defects that lead to hysteresis in the perovskite based thin film pose challenges. Recent work has shown that thin films of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) deposited on the photo absorption layer, using solution processing techniques, minimize surface pin holes and defects thereby increasing the PCE. We developed and employed a multiscale model based on molecular dynamics (MD) and kinetic Monte Carlo (kMC) to establish a relationship between deposition rate and surface coverage on perovskite surface. The MD simulations of PCBMs dispersed in chlorobenzene, sandwiched between (110) perovskite substrates, indicate that PCBMs are deposited through anchoring of the oxygen atom of carbonyl group to the exposed lead (Pb) atom of (110) perovskite surface. Based on rates of distinct deposition events calculated from MD, kMC simulations were run to determine surface coverage at much larger time and length scales than accessible by MD alone. Based on the model, a generic relationship is established between deposition rate of PCBMs and surface coverage on perovskite crystal. The study also provides detailed insights into the morphology of the deposited film.

  6. Solution processed deposition of electron transport layers on perovskite crystal surface—A modeling based study

    International Nuclear Information System (INIS)

    Mortuza, S.M.; Taufique, M.F.N.; Banerjee, Soumik

    2017-01-01

    Highlights: • The model determined the surface coverage of solution-processed film on perovskite. • Calculated surface density map provides insight into morphology of the monolayer. • Carbonyl oxygen atom of PCBM strongly attaches to the (110) surface of perovskite. • Uniform distribution of clusters on perovskite surface at lower PCBM concentration. • Deposition rate of PCBM on the surface is very high at initial stage of film growth. - Abstract: The power conversion efficiency (PCE) of planar perovskite solar cells (PSCs) has reached up to ∼20%. However, structural and chemicals defects that lead to hysteresis in the perovskite based thin film pose challenges. Recent work has shown that thin films of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) deposited on the photo absorption layer, using solution processing techniques, minimize surface pin holes and defects thereby increasing the PCE. We developed and employed a multiscale model based on molecular dynamics (MD) and kinetic Monte Carlo (kMC) to establish a relationship between deposition rate and surface coverage on perovskite surface. The MD simulations of PCBMs dispersed in chlorobenzene, sandwiched between (110) perovskite substrates, indicate that PCBMs are deposited through anchoring of the oxygen atom of carbonyl group to the exposed lead (Pb) atom of (110) perovskite surface. Based on rates of distinct deposition events calculated from MD, kMC simulations were run to determine surface coverage at much larger time and length scales than accessible by MD alone. Based on the model, a generic relationship is established between deposition rate of PCBMs and surface coverage on perovskite crystal. The study also provides detailed insights into the morphology of the deposited film.

  7. Electric double layer capacitors employing nitrogen and sulfur co-doped, hierarchically porous graphene electrodes with synergistically enhanced performance

    Science.gov (United States)

    Kannan, Aravindaraj G.; Samuthirapandian, Amaresh; Kim, Dong-Won

    2017-01-01

    Hierarchically porous graphene nanosheets co-doped with nitrogen and sulfur are synthesized via a simple hydrothermal method, followed by a pore activation step. Pore architectures are controlled by varying the ratio of chemical activation agents to graphene, and its influence on the capacitive performance is evaluated. The electric double layer capacitor (EDLC) assembled with optimized dual-doped graphene delivers a high specific capacitance of 146.6 F g-1 at a current density of 0.8 A g-1, which is higher than that of cells with un-doped and single-heteroatom doped graphene. The EDLC with dual-doped graphene electrodes exhibits stable cycling performance with a capacitance retention of 94.5% after 25,000 cycles at a current density of 3.2 A g-1. Such a good performance can be attributed to synergistic effects due to co-doping of the graphene nanosheets and the presence of hierarchical porous structures.

  8. Modeling the effect of anisotropy of gas diffusion layer on transport phenomena in a direct methanol fuel cell

    Science.gov (United States)

    Miao, Zheng; He, Ya-Ling; Zou, Jin-Qiang

    Transport phenomena in the gas diffusion layer (GDL) are of vital importance for the operation of direct methanol fuel cells (DMFCs). In this work, a two-phase mass transport model is developed to investigate the effects of anisotropic characteristics of a GDL, including the inherent anisotropy, deformation, and electrical and thermal contact resistances, on the coupled species, charges and thermal transport processes in a DMFC. In this model, methanol crossover and non-equilibrium evaporation/condensation of water and methanol are considered. The multistep electrochemical mechanisms are used to obtain a detailed description of the kinetics of methanol oxidization reaction (MOR) in both the anode and cathode catalyst layers (CLs). The numerical results show that the anisotropy of the GDL has a great effect on the distribution of species concentration, overpotential, local current density, and temperature. The deformation of the GDL depresses the transport of species through the GDL, particularly methanol diffusion in anode GDL, but facilitates the transport of electron and the removal of heat. The electrical contact resistance plays an important role in determining the cell performance.

  9. Modeling the effect of anisotropy of gas diffusion layer on transport phenomena in a direct methanol fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Miao, Zheng; He, Ya-Ling; Zou, Jin-Qiang [State Key Laboratory of Multiphase Flow in Power Engineering, School of Energy and Power Engineering, Xi' an Jiaotong University, Xi' an, Shaanxi 710049 (China)

    2010-06-01

    Transport phenomena in the gas diffusion layer (GDL) are of vital importance for the operation of direct methanol fuel cells (DMFCs). In this work, a two-phase mass transport model is developed to investigate the effects of anisotropic characteristics of a GDL, including the inherent anisotropy, deformation, and electrical and thermal contact resistances, on the coupled species, charges and thermal transport processes in a DMFC. In this model, methanol crossover and non-equilibrium evaporation/condensation of water and methanol are considered. The multistep electrochemical mechanisms are used to obtain a detailed description of the kinetics of methanol oxidization reaction (MOR) in both the anode and cathode catalyst layers (CLs). The numerical results show that the anisotropy of the GDL has a great effect on the distribution of species concentration, overpotential, local current density, and temperature. The deformation of the GDL depresses the transport of species through the GDL, particularly methanol diffusion in anode GDL, but facilitates the transport of electron and the removal of heat. The electrical contact resistance plays an important role in determining the cell performance. (author)

  10. Hybrid graphene-metal oxide solution processed electron transport layers for large area high-performance organic photovoltaics.

    Science.gov (United States)

    Beliatis, Michail J; Gandhi, Keyur K; Rozanski, Lynn J; Rhodes, Rhys; McCafferty, Liam; Alenezi, Mohammad R; Alshammari, Abdullah S; Mills, Christopher A; Jayawardena, K D G Imalka; Henley, Simon J; Silva, S Ravi P

    2014-04-02

    Solution processed core-shell nano-structures of metal oxide-reduced graphene oxide (RGO) are used as improved electron transport layers (ETL), leading to an enhancement in photocurrent charge transport in PCDTBT:PC70 BM for both single cell and module photovoltaic devices. As a result, the power conversion efficiency for the devices with RGO-metal oxides for ETL increases 8% in single cells and 20% in module devices. © 2014 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Impact of compression on gas transport in non-woven gas diffusion layers of high temperature polymer electrolyte fuel cells

    Science.gov (United States)

    Froning, Dieter; Yu, Junliang; Gaiselmann, Gerd; Reimer, Uwe; Manke, Ingo; Schmidt, Volker; Lehnert, Werner

    2016-06-01

    Gas transport in non-woven gas diffusion layers of a high-temperature polymer electrolyte fuel cell was calculated with the Lattice Boltzmann method. The underlying micro structure was taken from two sources. A real micro structure was analyzed in the synchrotron under the impact of a compression mask mimicking the channel/rib structure of a flow field. Furthermore a stochastic geometry model based on synchrotron X-ray tomography studies was applied. The effect of compression is included in the stochastic model. Gas transport in these micro structures was simulated and the impact of compression was analyzed. Fiber bundles overlaying the micro structure were identified which affect the homogeneity of the gas flow. There are significant deviations between the impact of compression on effective material properties for this type of gas diffusion layers and the Kozeny-Carman equation.

  12. Enhanced luminance of MEH-PPV based PLEDs using single walled carbon nanotube composite as an electron transporting layer

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Inderpreet, E-mail: inderpreetsingh_05@rediffmail.co [Materials Laboratory, Department of Electronic Science, University of Delhi South Campus, Benito Juarez Road, New Delhi 110021 (India); Madhwal, Devinder; Verma, A.; Kumar, A.; Rait, S. [Materials Laboratory, Department of Electronic Science, University of Delhi South Campus, Benito Juarez Road, New Delhi 110021 (India); Kaur, I.; Bharadwaj, L.M. [Central Scientific Instruments Organization, Sector-30, Chandigarh (India); Bhatia, C.S. [Department of Electrical and Computer Engineering, National University of Singapore (Singapore); Bhatnagar, P.K.; Mathur, P.C. [Materials Laboratory, Department of Electronic Science, University of Delhi South Campus, Benito Juarez Road, New Delhi 110021 (India)

    2010-11-15

    An efficient electron transporting layer (ETL) based on single walled carbon nanotube (SWCNT) composites has been developed for poly [2-methoxy-5-(2'-ethyl-hexyloxy)-1,4-phenylene vinylene] (MEH-PPV) based orange polymer light emitting diodes (PLEDs) and its effect on the performance of PLEDs has been examined. It is observed that with increase in SWCNT concentration, in ETL, the luminance and luminous efficiency of the PLEDs increase (about 5 times increase in luminance is observed at 5% w/w SWCNT concentration). The SWCNTs present in the MEH-PPV ETL boost the mobility of electrons injected from the cathode towards the emissive layer by establishing highly conducting percolation paths. This balances the concentration of holes and electrons in the emissive layer, which leads to enhanced emission from the PLEDs.

  13. Green phosphorescent organic light-emitting devices based on different electron transport layers combining with fluorescent sub-monolayer

    Science.gov (United States)

    Yang, Hui-shan; Guo, Hui-yu; Wu, Li-shuang

    2017-03-01

    We report a small molecule host of 4,4(-N,N)-dicarbazole-biphenyl (CBP) doped with 8% tris(2-phenylpyridine) iridium (Irppy3) for use in efficient green phosphorescent organic light-emitting devices (PHOLEDs) combined with different electron transport layers of Alq and BAlq. The PHOLEDs exhibit maximum current efficiency and power efficiency of 19.8 cd/A and 6.21 lm/W, respectively. The high performance of such PHOLEDs is attributed to the better electron mobile ability of BAlq and sub-monolayer quinacridone (QAD) as carrier trapping layer and equal charge carrier mobilities of hole and electron to form the broad carrier recombination zone in the emitting layer, which can reduce the triplet-triplet annihilation and improve the efficiency of the device.

  14. Real-Time Transportation Mode Identification Using Artificial Neural Networks Enhanced with Mode Availability Layers: A Case Study in Dubai

    Directory of Open Access Journals (Sweden)

    Young-Ji Byon

    2017-09-01

    Full Text Available Traditionally, departments of transportation (DOTs have dispatched probe vehicles with dedicated vehicles and drivers for monitoring traffic conditions. Emerging assisted GPS (AGPS and accelerometer-equipped smartphones offer new sources of raw data that arise from voluntarily-traveling smartphone users provided that their modes of transportation can correctly be identified. By introducing additional raster map layers that indicate the availability of each mode, it is possible to enhance the accuracy of mode detection results. Even in its simplest form, an artificial neural network (ANN excels at pattern recognition with a relatively short processing timeframe once it is properly trained, which is suitable for real-time mode identification purposes. Dubai is one of the major cities in the Middle East and offers unique environments, such as a high density of extremely high-rise buildings that may introduce multi-path errors with GPS signals. This paper develops real-time mode identification ANNs enhanced with proposed mode availability geographic information system (GIS layers, firstly for a universal mode detection and, secondly for an auto mode detection for the particular intelligent transportation system (ITS application of traffic monitoring, and compares the results with existing approaches. It is found that ANN-based real-time mode identification, enhanced by mode availability GIS layers, significantly outperforms the existing methods.

  15. The vertical structure of airflow turbulence characteristics within a boundary layer during wind blown sand transport over a beach

    Science.gov (United States)

    Lee, Z. S.; Baas, A. C.; Jackson, D.; Cooper, J. A.; Lynch, K.; Delgado-Fernandez, I.; Beyers, M.

    2010-12-01

    Recent studies have suggested the significant role of boundary layer turbulence and coherent flow structures on sand transport by wind over beaches and desert dunes. Widespread use of sonic anemometry and high-frequency sand transport sensors and traps have facilitated a move beyond the basic monitoring of shear velocities and bulk sediment transport to more detailed measurements at much higher spatio-temporal resolutions. In this paper we present results of a small-scale point-location field study of boundary layer turbulence and shear stresses conducted under obliquely onshore winds over a beach at Magilligan Strand, Northern Ireland. High-frequency (25 Hz) 3D wind vector measurements were collected at five different heights between 0.13 and 1.67 metres above the bed using sonic anemometry for durations of several hours, and the associated sand transport response was measured using an array of Safires. The wind data are used to investigate the vertical structure of Reynolds shear stresses and burst-sweep event characteristics, as well as a comparison with the standard logarithmic (law-of-the-wall) wind profile. The study explores the identification and selection of a characteristic event duration based on integral time-scales as well as spectral analysis, and includes an assessment of the issues involved with data rotations for yaw, pitch, and roll corrections relative to flow streamlines, and the subsequently derived turbulence parameters based on fluctuating vector components (u’, v’, w’). Results show how the contributions to shear stress and the average pitch of bursts and sweeps changes as a function of height above the bed, indicating the transformation of top-down turbulent eddies as they travel toward the surface. A comparison between the turbulence data and the synchronous sand transport events, meanwhile, reveals the potential effects of enhanced saltation layer roughness feedback on eddies close to the bed.

  16. Investigating the source, transport, and isotope composition of water vapor in the planetary boundary layer

    Science.gov (United States)

    Griffis, Timothy J.; Wood, Jeffrey D.; Baker, John M.; Lee, Xuhui; Xiao, Ke; Chen, Zichong; Welp, Lisa R.; Schultz, Natalie M.; Gorski, Galen; Chen, Ming; Nieber, John

    2016-04-01

    Increasing atmospheric humidity and convective precipitation over land provide evidence of intensification of the hydrologic cycle - an expected response to surface warming. The extent to which terrestrial ecosystems modulate these hydrologic factors is important to understand feedbacks in the climate system. We measured the oxygen and hydrogen isotope composition of water vapor at a very tall tower (185 m) in the upper Midwest, United States, to diagnose the sources, transport, and fractionation of water vapor in the planetary boundary layer (PBL) over a 3-year period (2010 to 2012). These measurements represent the first set of annual water vapor isotope observations for this region. Several simple isotope models and cross-wavelet analyses were used to assess the importance of the Rayleigh distillation process, evaporation, and PBL entrainment processes on the isotope composition of water vapor. The vapor isotope composition at this tall tower site showed a large seasonal amplitude (mean monthly δ18Ov ranged from -40.2 to -15.9 ‰ and δ2Hv ranged from -278.7 to -113.0 ‰) and followed the familiar Rayleigh distillation relation with water vapor mixing ratio when considering the entire hourly data set. However, this relation was strongly modulated by evaporation and PBL entrainment processes at timescales ranging from hours to several days. The wavelet coherence spectra indicate that the oxygen isotope ratio and the deuterium excess (dv) of water vapor are sensitive to synoptic and PBL processes. According to the phase of the coherence analyses, we show that evaporation often leads changes in dv, confirming that it is a potential tracer of regional evaporation. Isotope mixing models indicate that on average about 31 % of the growing season PBL water vapor is derived from regional evaporation. However, isoforcing calculations and mixing model analyses for high PBL water vapor mixing ratio events ( > 25 mmol mol-1) indicate that regional evaporation can account

  17. Investigating the source, transport, and isotope composition of water vapor in the planetary boundary layer

    Directory of Open Access Journals (Sweden)

    T. J. Griffis

    2016-04-01

    Full Text Available Increasing atmospheric humidity and convective precipitation over land provide evidence of intensification of the hydrologic cycle – an expected response to surface warming. The extent to which terrestrial ecosystems modulate these hydrologic factors is important to understand feedbacks in the climate system. We measured the oxygen and hydrogen isotope composition of water vapor at a very tall tower (185 m in the upper Midwest, United States, to diagnose the sources, transport, and fractionation of water vapor in the planetary boundary layer (PBL over a 3-year period (2010 to 2012. These measurements represent the first set of annual water vapor isotope observations for this region. Several simple isotope models and cross-wavelet analyses were used to assess the importance of the Rayleigh distillation process, evaporation, and PBL entrainment processes on the isotope composition of water vapor. The vapor isotope composition at this tall tower site showed a large seasonal amplitude (mean monthly δ18Ov ranged from −40.2 to −15.9 ‰ and δ2Hv ranged from −278.7 to −113.0 ‰ and followed the familiar Rayleigh distillation relation with water vapor mixing ratio when considering the entire hourly data set. However, this relation was strongly modulated by evaporation and PBL entrainment processes at timescales ranging from hours to several days. The wavelet coherence spectra indicate that the oxygen isotope ratio and the deuterium excess (dv of water vapor are sensitive to synoptic and PBL processes. According to the phase of the coherence analyses, we show that evaporation often leads changes in dv, confirming that it is a potential tracer of regional evaporation. Isotope mixing models indicate that on average about 31 % of the growing season PBL water vapor is derived from regional evaporation. However, isoforcing calculations and mixing model analyses for high PBL water vapor mixing ratio events ( >  25 mmol mol−1

  18. Numerical investigation of Scrape Off Layer anomalous particle transport for MAST parameters

    DEFF Research Database (Denmark)

    Militello, F.; Fundamenski, W.; Naulin, Volker

    2013-01-01

    Numerical simulations of L-mode plasma turbulence in the Scrape Off Layer of MAST are presented. Relevant features of the boundary plasma, such as the thickness of the density layer or the statistics of the fluctuations are related to the edge density and temperature, plasma current and parallel ...

  19. Cirrus and water vapor transport in the tropical tropopause layer – Part 1: A specific case modeling study

    Directory of Open Access Journals (Sweden)

    T. Dinh

    2012-10-01

    Full Text Available In a simulation of a tropical-tropopause-layer (TTL cirrus forced by a large-scale equatorial Kelvin wave, the radiatively induced mesoscale dynamics of the cloud actively contributes to the transport of water vapor in the vertical direction.

    In a typical TTL cirrus, the heating that results from absorption of radiation by ice crystals induces a mesoscale circulation. Advection of water vapor by the radiatively induced circulation leads to upward advection of the cloudy air. Upward advection of the cloudy air is equivalent to upward transport of water vapor when the air above the cloud is drier than the cloudy air. On the other hand, ice nucleation and depositional growth, followed by sedimentation and sublimation lead to downward transport of water vapor.

    Under the conditions specific to our simulation, the upward transport of water vapor by the mesoscale circulation dominates the downward transport by microphysical processes. The net result is upward transport of water vapor, which is equivalent to hydration of the lower stratosphere. Sensitivity to model conditions and parameters will be discussed in a follow-up paper.

  20. Low turn-on voltage perovskite light-emitting diodes with methanol treated PEDOT:PSS as hole transport layer

    Science.gov (United States)

    Wang, Zijun; Li, Zhirun; Zhou, Dianli; Yu, Junsheng

    2017-12-01

    We demonstrate the reduced low turn-on voltage of perovskite light-emitting diodes (PeLEDs) with methanol (MeOH) treated poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) as a hole transport layer (HTL). The MeOH treated PEDOT:PSS layer presents improved hole injection through reducing the contact barrier between the HTL and the CH3NH3PbBr3 emitting layer without sacrificing the quality of the perovskite film, which was characterized by X-ray diffraction, scanning electron microscopy, and time-resolved photoluminescence analysis. The optimized PeLEDs with the MeOH treated PEDOT:PSS layer exhibit a low turn-on voltage of 2.4 V and a maximum luminance of 1565 cd/m2, which represents a significant improvement over the PeLEDs using a pristine PEDOT:PSS layer. The approach could be used as a general method for decreasing the hole-injection barrier of PeLEDs and, eventually, to enhance the device performance.

  1. Momentum and energy transport in the accelerated fully rough turbulent boundary layer

    Energy Technology Data Exchange (ETDEWEB)

    Coleman, H.W.

    1976-06-01

    The behavior of the fully rough turbulent boundary layer subjected to favorable pressure gradients was investigated experimentally using a porous test surface composed of densely packed spheres of uniform size. Measurements of profiles of mean velocity, mean temperature and the components of the Reynolds stress tensor are reported for both unblown and blown layers. Stanton numbers were determined from energy balances on the test surface and skin friction coefficients from measurements of the Reynolds shear stress and mean velocity. A new acceleration parameter, K/sub r/, for fully rough layers is defined and shown to be dependent on a characteristic roughness dimension but independent of molecular viscosity. For fully rough turbulent flow, acceleration causes an increase in Stanton number compared to zero pressure gradient values at the same enthalpy thickness, Reynold number, or position. The fully rough Stanton number behavior observed in this study is contrary to that previously reported for unblown accelerated smooth wall layers. Acceleration of a fully rough layer decreases the normalized turbulent kinetic energy and makes the turbulence field much less isotropic in the inner region (for F equal zero) compared to zero pressure gradient fully rough layers. Increasing values of roughness Reynolds number with acceleration indicate that the fully rough layer does not tend toward the transitionally rough or smooth wall state when accelerated.

  2. Anomalous electron transport in metal/carbon multijunction devices by engineering of the carbon thickness and selecting metal layer

    Science.gov (United States)

    Dwivedi, Neeraj; Dhand, Chetna; Rawal, Ishpal; Kumar, Sushil; Malik, Hitendra K.; Lakshminarayanan, Rajamani

    2017-06-01

    A longstanding concern in the research of amorphous carbon films is their poor electrical conductivity at room temperature which constitutes a major barrier for the development of cost effective electronic and optoelectronic devices. Here, we propose metal/carbon hybrid multijunction devices as a promising facile way to overcome room temperature electron transport issues in amorphous carbon films. By the tuning of carbon thickness and swapping metal layers, we observe giant (upto ˜7 orders) reduction of electrical resistance in metal/carbon multijunction devices with respect to monolithic amorphous carbon device. We engineer the maximum current (electrical resistance) from about 10-7 to 10-3 A (˜107 to 103 Ω) in metal (Cu or Ti)/carbon hybrid multijunction devices with a total number of 10 junctions. The introduction of thin metal layers breaks the continuity of relatively higher resistance carbon layer as well as promotes the nanostructuring of carbon. These contribute to low electrical resistance of metal/carbon hybrid multijunction devices, with respect to monolithic carbon device, which is further reduced by decreasing the thickness of carbon layers. We also propose and discuss equivalent circuit model to explain electrical resistance in monolithic carbon and metal/carbon multijunction devices. Cu/carbon multijunction devices display relatively better electrical transport than Ti/carbon devices owing to low affinity of Cu with carbon that restricts carbide formation. We also observe that in metal/carbon multijunction devices, the transport mechanism changes from Poole-Frenkel/Schottky model to the hopping model with a decrease in carbon thickness. Our approach opens a new route to develop carbon-based inexpensive electronic and optoelectronic devices.

  3. Numerical Modeling of the Vertical Heat Transport Through the Diffusive Layer of the Arctic Ocean

    Science.gov (United States)

    2013-03-01

    transport through thermohaline staircases in the Arctic region. Results revealed that vertical fluxes exceeded those of extant “four-thirds flux...vertical heat flux, thermohaline staircase 15. NUMBER OF PAGES 73 16. PRICE CODE 17. SECURITY CLASSIFICATION OF REPORT Unclassified 18...DNS) were conducted to assess the vertical heat transport through thermohaline staircases in the Arctic region. Results revealed that vertical

  4. Chalk-Ex: Transport of Optically Active Particles from the Surface Mixed Layer

    National Research Council Canada - National Science Library

    Plueddemann, Albert J

    2005-01-01

    ... (from Cretaceous chalk) were injected into the mixed layer to create a "chalk patch". Experiments were performed at two stations, one mesotrophic and one eutrophic, during two times of the year, June and November...

  5. Electron-transporting layer doped with cesium azide for high-performance phosphorescent and tandem white organic light-emitting devices

    Science.gov (United States)

    Yu, Yaoyao; Chen, Xingming; Jin, Yu; Wu, Zhijun; Yu, Ye; Lin, Wenyan; Yang, Huishan

    2017-07-01

    Cesium azide was employed as an effective n-dopant in the electron-transporting layer (ETL) of organic light-emitting devices (OLEDs) owing to its low deposition temperature and high ambient stability. By doping cesium azide onto 4,7-diphenyl-1,10-phenanthroline, a green phosphorescent OLED having best efficiencies of 66.25 cd A-1, 81.22 lm W-1 and 18.82% was realized. Moreover, the efficiency roll-off from 1000 cd m-2 to 10 000 cd m-2 is only 12.9%, which is comparable with or even lower than that of devices utilizing the co-host system. Physical mechanisms for the improvement of device performance were studied in depth by analyzing the current density-voltage (J-V) characteristics of the electron-only devices. In particular, by comparing the J-V characteristics of the electron-only devices instead of applying the complicated ultraviolet photoelectron spectrometer measurements, we deduced the decrease in barrier height for electron injection at the ETL/cathode contact. Finally, an efficient tandem white OLED utilizing the n-doped layer in the charge generation unit (CGU) was constructed. As far as we know, this is the first report on the application of this CGU for fabricating tandem white OLEDs. The emissions of the tandem device are all in the warm white region from 1213 cd m-2 to 10870 cd m-2, as is beneficial to the lighting application.

  6. Solute transport in a single fracture involving an arbitrary length decay chain with rock matrix comprising different geological layers.

    Science.gov (United States)

    Mahmoudzadeh, Batoul; Liu, Longcheng; Moreno, Luis; Neretnieks, Ivars

    2014-08-01

    A model is developed to describe solute transport and retention in fractured rocks. It accounts for advection along the fracture, molecular diffusion from the fracture to the rock matrix composed of several geological layers, adsorption on the fracture surface, adsorption in the rock matrix layers and radioactive decay-chains. The analytical solution, obtained for the Laplace-transformed concentration at the outlet of the flowing channel, can conveniently be transformed back to the time domain by the use of the de Hoog algorithm. This allows one to readily include it into a fracture network model or a channel network model to predict nuclide transport through channels in heterogeneous fractured media consisting of an arbitrary number of rock units with piecewise constant properties. More importantly, the simulations made in this study recommend that it is necessary to account for decay-chains and also rock matrix comprising at least two different geological layers, if justified, in safety and performance assessment of the repositories for spent nuclear fuel. Copyright © 2014 Elsevier B.V. All rights reserved.

  7. Efficient and Air-Stable Planar Perovskite Solar Cells Formed on Graphene-Oxide-Modified PEDOT:PSS Hole Transport Layer

    Science.gov (United States)

    Luo, Hui; Lin, Xuanhuai; Hou, Xian; Pan, Likun; Huang, Sumei; Chen, Xiaohong

    2017-10-01

    As a hole transport layer, PEDOT:PSS usually limits the stability and efficiency of perovskite solar cells (PSCs) due to its hygroscopic nature and inability to block electrons. Here, a graphene-oxide (GO)-modified PEDOT:PSS hole transport layer was fabricated by spin-coating a GO solution onto the PEDOT:PSS surface. PSCs fabricated on a GO-modified PEDOT:PSS layer exhibited a power conversion efficiency (PCE) of 15.34%, which is higher than 11.90% of PSCs with the PEDOT:PSS layer. Furthermore, the stability of the PSCs was significantly improved, with the PCE remaining at 83.5% of the initial PCE values after aging for 39 days in air. The hygroscopic PSS material at the PEDOT:PSS surface was partly removed during spin-coating with the GO solution, which improves the moisture resistance and decreases the contact barrier between the hole transport layer and perovskite layer. The scattered distribution of the GO at the PEDOT:PSS surface exhibits superior wettability, which helps to form a high-quality perovskite layer with better crystallinity and fewer pin holes. Furthermore, the hole extraction selectivity of the GO further inhibits the carrier recombination at the interface between the perovskite and PEDOT:PSS layers. Therefore, the cooperative interactions of these factors greatly improve the light absorption of the perovskite layer, the carrier transport and collection abilities of the PSCs, and especially the stability of the cells.

  8. Low resistivity ZnO-GO electron transport layer based CH3NH3PbI3 solar cells

    Directory of Open Access Journals (Sweden)

    Muhammad Imran Ahmed

    2016-06-01

    Full Text Available Perovskite based solar cells have demonstrated impressive performances. Controlled environment synthesis and expensive hole transport material impede their potential commercialization. We report ambient air synthesis of hole transport layer free devices using ZnO-GO as electron selective contacts. Solar cells fabricated with hole transport layer free architecture under ambient air conditions with ZnO as electron selective contact achieved an efficiency of 3.02%. We have demonstrated that by incorporating GO in ZnO matrix, low resistivity electron selective contacts, critical to improve the performance, can be achieved. We could achieve max efficiency of 4.52% with our completed devices for ZnO: GO composite. Impedance spectroscopy confirmed the decrease in series resistance and an increase in recombination resistance with inclusion of GO in ZnO matrix. Effect of temperature on completed devices was investigated by recording impedance spectra at 40 and 60 oC, providing indirect evidence of the performance of solar cells at elevated temperatures.

  9. Low resistivity ZnO-GO electron transport layer based CH3NH3PbI3 solar cells

    Science.gov (United States)

    Ahmed, Muhammad Imran; Hussain, Zakir; Mujahid, Mohammad; Khan, Ahmed Nawaz; Javaid, Syed Saad; Habib, Amir

    2016-06-01

    Perovskite based solar cells have demonstrated impressive performances. Controlled environment synthesis and expensive hole transport material impede their potential commercialization. We report ambient air synthesis of hole transport layer free devices using ZnO-GO as electron selective contacts. Solar cells fabricated with hole transport layer free architecture under ambient air conditions with ZnO as electron selective contact achieved an efficiency of 3.02%. We have demonstrated that by incorporating GO in ZnO matrix, low resistivity electron selective contacts, critical to improve the performance, can be achieved. We could achieve max efficiency of 4.52% with our completed devices for ZnO: GO composite. Impedance spectroscopy confirmed the decrease in series resistance and an increase in recombination resistance with inclusion of GO in ZnO matrix. Effect of temperature on completed devices was investigated by recording impedance spectra at 40 and 60 oC, providing indirect evidence of the performance of solar cells at elevated temperatures.

  10. New magnetic rails with double-layer Halbach structure by employing NdFeB and ferrite magnets for HTS maglev

    Science.gov (United States)

    Sun, Ruixue; Zheng, Jun; Zheng, Botian; Qian, Nan; Li, Jipeng; Deng, Zigang

    2018-01-01

    In the high temperature superconducting (HTS) maglev system, the magnetic rail as an essential infrastructure is needed all along the route to carry passengers and goods to the destinations. Thus, large amount of rare earth magnetic materials are required in the magnetic rail construction. In order to decrease the dependence of magnetic rails on rare earth elements, the ferrite magnet is employed to replace part of the NdFeB magnets containing rare earth elements. Consequently, a new type rail with double-layer Halbach structure is presented, which is consisted of NdFeB and ferrite magnets. In this paper, we designed and fabricated the proposed rail, and further measured its magnetic flux density distribution and electromagnetic force interacting with HTS bulks. Experimental results indicate that, this new type rail, in double-layer Halbach structure, can achieve an equivalent distribution of magnetic flux density and levitation performance as the pure NdFeB Halbach rail, while a 10% reduction in NdFeB magnet consumption can be realized at the same time. In addition this work explores another magnetic material selection for HTS maglev applications. The dependence on rare earth element and the cost of magnetic rails can be further reduced, as the coercive force of ferrite magnets improved.

  11. Significantly improved photovoltaic performance in polymer bulk heterojunction solar cells with graphene oxide /PEDOT:PSS double decked hole transport layer

    Science.gov (United States)

    Rafique, Saqib; Abdullah, Shahino Mah; Shahid, Muhammad Mehmood; Ansari, Mohammad Omaish; Sulaiman, Khaulah

    2017-01-01

    This work demonstrates the high performance graphene oxide (GO)/PEDOT:PSS doubled decked hole transport layer (HTL) in the PCDTBT:PC71BM based bulk heterojunction organic photovoltaic device. The devices were tested on merits of their power conversion efficiency (PCE), reproducibility, stability and further compared with the devices with individual GO or PEDOT:PSS HTLs. Solar cells employing GO/PEDOT:PSS HTL yielded a PCE of 4.28% as compared to either of individual GO or PEDOT:PSS HTLs where they demonstrated PCEs of 2.77 and 3.57%, respectively. In case of single GO HTL, an inhomogeneous coating of ITO caused the poor performance whereas PEDOT:PSS is known to be hygroscopic and acidic which upon direct contact with ITO reduced the device performance. The improvement in the photovoltaic performance is mainly ascribed to the increased charge carriers mobility, short circuit current, open circuit voltage, fill factor, and decreased series resistance. The well matched work function of GO and PEDOT:PSS is likely to facilitate the charge transportation and an overall reduction in the series resistance. Moreover, GO could effectively block the electrons due to its large band-gap of ~3.6 eV, leading to an increased shunt resistance. In addition, we also observed the improvement in the reproducibility and stability.

  12. Significantly improved photovoltaic performance in polymer bulk heterojunction solar cells with graphene oxide /PEDOT:PSS double decked hole transport layer.

    Science.gov (United States)

    Rafique, Saqib; Abdullah, Shahino Mah; Shahid, Muhammad Mehmood; Ansari, Mohammad Omaish; Sulaiman, Khaulah

    2017-01-13

    This work demonstrates the high performance graphene oxide (GO)/PEDOT:PSS doubled decked hole transport layer (HTL) in the PCDTBT:PC 71 BM based bulk heterojunction organic photovoltaic device. The devices were tested on merits of their power conversion efficiency (PCE), reproducibility, stability and further compared with the devices with individual GO or PEDOT:PSS HTLs. Solar cells employing GO/PEDOT:PSS HTL yielded a PCE of 4.28% as compared to either of individual GO or PEDOT:PSS HTLs where they demonstrated PCEs of 2.77 and 3.57%, respectively. In case of single GO HTL, an inhomogeneous coating of ITO caused the poor performance whereas PEDOT:PSS is known to be hygroscopic and acidic which upon direct contact with ITO reduced the device performance. The improvement in the photovoltaic performance is mainly ascribed to the increased charge carriers mobility, short circuit current, open circuit voltage, fill factor, and decreased series resistance. The well matched work function of GO and PEDOT:PSS is likely to facilitate the charge transportation and an overall reduction in the series resistance. Moreover, GO could effectively block the electrons due to its large band-gap of ~3.6 eV, leading to an increased shunt resistance. In addition, we also observed the improvement in the reproducibility and stability.

  13. CROSSTEX - Wave breaking, Boundary Layer Processes, the Resulting Sediment Transport and Beach Profile Evolution

    National Research Council Canada - National Science Library

    Hsu, Tian-Jian; Trowbridge, John

    2006-01-01

    Two numerical models focused on different scales are revised and extended to model surf zone hydrodynamics and sand transport driven by random waves in order to test with data measured during CPOSSTEX...

  14. Control of long range turbulent transport with biasing in the tokamak scrape-off-layer

    International Nuclear Information System (INIS)

    Figarella, C.F.; Ghendrih, Ph.; Sarazin, Y.; Attuel, G.; Benkadda, S.; Beyer, P.; Falchetto, G.; Fleurence, E.; Garbet, X.; Grandgirard, V.

    2005-01-01

    Cross-field transport in the SOL influences tokamak performance in particular regarding the divertor efficiency. Recent experiment evidence emphasizes non-exponential and/or flat SOL profiles that suggest a large perpendicular transport. A 2D fluid model based on the interchange instability to simulate the SOL turbulence was found to exhibits intermittent dynamics of the particle flux. We propose a control method that prevents long range transport events from reaching the far SOL: It consists in biasing the far SOL leading to a transport barrier which stops the propagation of these intermittent events. The best trade off is to localize the biased toroidal ring around the baffles. We show that such a control is achievable providing the strength of the barrier is strong enough. The investigation of the minimal biasing power required to achieve the control as well as its experimental estimate is performed

  15. Numerical simulation and experimental validation of inverted planar perovskite solar cells based on NiOx hole transport layer

    Science.gov (United States)

    Wei, Xiaoqing; Wang, Xian; Jiang, Hailong; Huang, Yongliang; Han, Anjun; Gao, Qi; Bian, Jiantao; Liu, Zhengxin

    2017-12-01

    Numerical simulation of inverted planar perovskite solar cells based on NiOx hole transport layer was performed with AMPS-1D program. The simulated device parameters were shown to agree well with our experimental work. The simulated results revealed that the device contained typical p-i-n junction configuration. The optimum thickness of the absorber, the effects of the absorber quality, the defect density of interfaces, the effects of VBO and CBO, the interface contact at front and back electrodes were analyzed. Open-circuit voltage mainly depended on the defect density in CH3NH3PbI3 layer, the recombination at HTL/CH3NH3PbI3 and ETL/CH3NH3PbI3 interface, the values of VBO and CBO, while short-circuit current mainly depended on the thickness of CH3NH3PbI3 layer. Fill factor was significantly influenced by the interface contact at front and back electrodes. Remarkably, a power conversion efficiency of 21.8% is obtained under optimised conditions. Real devices with PCE of up to 15% were obtained by initially optimizing the preparation of CH3NH3PbI3 absorber layer. Our work can provide some important guidance for device design and optimization from the considerations of both theory and experiment.

  16. Enhanced efficiency of organic solar cells by using ZnO as an electron-transport layer

    Science.gov (United States)

    Ullah, Irfan; Shah, Said Karim; Wali, Sartaj; Hayat, Khizar; Khattak, Shaukat Ali; Khan, Aurangzeb

    2017-12-01

    This paper reports the use of ZnO, processed by sol-gel, as an efficient electron-transport layer for inverted organic photovoltaic cells. The device with incorporated ZnO interlayer, annealed at 100 °C, between transparent electrode and blend film plays an effective role in enhancing photovoltaic properties: the short-circuit current density (J sc) doubles while open-circuit voltage (V oc) and fill factor increase by 0.12 V and 10 %, respectively. Power conversion efficiency (PCE) of solar cell increases, approximately, three times. The improvement in the PCE is attributed to the presence of ZnO which, being an electron-facilitating layer, provides an energy step for charge collection at electrodes.

  17. Influence of the Hole Transporting Layer on the Thermal Stability of Inverted Organic Photovoltaics Using Accelerated-Heat Lifetime Protocols.

    Science.gov (United States)

    Hermerschmidt, Felix; Savva, Achilleas; Georgiou, Efthymios; Tuladhar, Sachetan M; Durrant, James R; McCulloch, Iain; Bradley, Donal D C; Brabec, Christoph J; Nelson, Jenny; Choulis, Stelios A

    2017-04-26

    High power conversion efficiency (PCE) inverted organic photovoltaics (OPVs) usually use thermally evaporated MoO 3 as a hole transporting layer (HTL). Despite the high PCE values reported, stability investigations are still limited and the exact degradation mechanisms of inverted OPVs using thermally evaporated MoO 3 HTL remain unclear under different environmental stress factors. In this study, we monitor the accelerated lifetime performance under the ISOS-D-2 protocol (heat conditions 65 °C) of nonencapsulated inverted OPVs based on the thiophene-based active layer materials poly(3-hexylthiophene) (P3HT), poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl

  18. The Effect of Post-Baking Temperature and Thickness of ZnO Electron Transport Layers for Efficient Planar Heterojunction Organometal-Trihalide Perovskite Solar Cells

    OpenAIRE

    Kun-Mu Lee; Chuan-Jung Lin; Yin-Hsuan Chang; Ting-Han Lin; Vembu Suryanarayanan; Ming-Chung Wu

    2017-01-01

    Solution-processed zinc oxide (ZnO)-based planar heterojunction perovskite photovoltaic device is reported in this study. The photovoltaic device benefits from the ZnO film as a high-conductivity and high-transparent electron transport layer. The optimal electron transport layer thickness and post-baking temperature for ZnO are systematically studied by scanning electron microscopy, photoluminescence and time-resolved photoluminescence spectroscopy, and X-ray diffraction. Optimized perovskite...

  19. Crystalline MoOx Thin-Films as Hole Transport Layers in DBP/C70 Based Organic Solar Cell

    DEFF Research Database (Denmark)

    Ahmadpour, Mehrad; Fernandes Cauduro, André Luis; dos Reis, Roberto

    Transition Metal Oxides such as Molybdenum oxide (MoOx) have been intensively used as hole transport layers in different organic, inorganic and hybrid technologies, demonstrating also important improvements on the power conversion efficiency as well as on the stability of different types of solar...... cells. Among several different deposition methods available for fabrication of MoOx thin-films, reactive sputtering arises as an interesting alternative due to its full control over the deposition parameters such as the deposition power, reactive gas partial pressure and the deposition rate....

  20. Phase-coherent electron transport in (Zn, Al)Ox thin films grown by atomic layer deposition

    Science.gov (United States)

    Saha, D.; Misra, P.; Ajimsha, R. S.; Joshi, M. P.; Kukreja, L. M.

    2014-11-01

    A clear signature of disorder induced quantum-interference phenomena leading to phase-coherent electron transport was observed in (Zn, Al)Ox thin films grown by atomic layer deposition. The degree of static-disorder was tuned by varying the Al concentration through periodic incorporation of Al2O3 sub-monolayer in ZnO. All the films showed small negative magnetoresistance due to magnetic field suppressed weak-localization effect. The temperature dependence of phase-coherence length ( l φ ∝ T - 3 / 4 ), as extracted from the magnetoresistance measurements, indicated electron-electron scattering as the dominant dephasing mechanism. The persistence of quantum-interference at relatively higher temperatures up to 200 K is promising for the realization of ZnO based phase-coherent electron transport devices.

  1. Angular momentum transport in accretion disk boundary layers around weakly magnetized stars

    DEFF Research Database (Denmark)

    Pessah, M.E.; Chan, C.-K.

    2013-01-01

    ) is inefficient in disk regions where, as expected in boundary layers, the angular frequency increases with radius. Motivated by the need of a deeper understanding of the behavior of an MHD fluid in a differentially rotating background that deviates from a Keplerian profile, we study the dynamics of MHD waves...

  2. Fluctuations, transport and flows in TCV scrape-off layer plasmas

    Czech Academy of Sciences Publication Activity Database

    Garcia, E.O.; Horáček, Jan; Naulin, V.; Nielsen, A.H.; Pitts, R.A.; Rasmussen, J.J.

    2007-01-01

    Roč. 47, č. 7 (2007), s. 667-676 ISSN 0029-5515 Grant - others:-(XE) European Training fellowships and Grants (Euratom), EDGETURB Institutional research plan: CEZ:AV0Z20430508 Keywords : tokamak * plasma * scrape-off layer * turbulence * interchange instability Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 3.278, year: 2007

  3. A Simple Model for the Vertical Transport of Reactive Species in the Convective Atmospheric Boundary Layer

    DEFF Research Database (Denmark)

    Kristensen, Leif; Lenschow, Donald H.; Gurarie, David

    2010-01-01

    We have developed a simple, steady-state, one-dimensional second-order closure model to obtain continuous profiles of turbulent fluxes and mean concentrations of non-conserved scalars in a convective boundary layer without shear. As a basic tool we first set up a model for conserved species with ...

  4. Poloidal electric field and variation of radial transport during ICRF heating in the JET scrape-off layer

    International Nuclear Information System (INIS)

    Clement, S.; Tagle, J.A.; Bures, M.; Vince, J.; Kock, L. de; Stangeby, P.C.

    1989-01-01

    The highly anomalous perpendicular transport in the plasma edge of a tokamak is generally attributed to plasma turbulence, primarily to density and electrostatic potential fluctuations. The edge transport could be modified by changing the geometry of objects in contact with the plasma (limiters, radio frequency antennae ...) and during additional heating experiments. Poloidal asymmetries in the scrape-off layer (SOL) in tokamaks using poloidal limiters (eg. ALCATOR-C) have been recently reported, indicating a poloidal asymmetry in cross-field transport. A poloidal ring limiter obstructs communications between different flux tubes in the SOL, thus permitting poloidal asymmetries in n e and T e to develop if D perpendicular is θ-dependent. When JET was operated with discrete limiters, equivalent to a single toroidal limiter at the outside mid-plane, little poloidal variation in the SOL plasma properties was observed. Currently JET is operated with two complete toroidal belt limiters located approximately one meter above and below the outside mid-plane. This configuration breaks the SOL into two regions: the low field side SOL (LFS), between the limiters, and the rest of the SOL on the high field side (HFS). Differences on the scrape-off lengths in the two SOLs are reported here, indicating that cross-field transport is faster on the LFS-SOL, in agreement with observations made on ASDEX and T-10. (author) 8 refs., 6 figs

  5. Influence of the nature of interfaces on the capillary transport in layered materials

    DEFF Research Database (Denmark)

    Derluyn, Hannelore; Janssen, Hans; Carmeliet, Jan

    2011-01-01

    This paper presents an experimental and quantitative analysis of capillary transport across the interface brick–mortar joint in masonry. Moisture profiles are measured with X-ray projection. The influence of curing conditions is analyzed by considering three types of mortars: cured in a mould......, between capillary wet and dry bricks. A decrease in moisture inflow for the mortars cured between bricks is measured. The pore structure and the moisture transport properties of mortar change significantly due to water extraction from the initially wet mortar to the bricks during curing. Numerical...

  6. Salt transport and crystallization in plaster layers: A nuclear magnetic resonance study

    NARCIS (Netherlands)

    Petkovic, J.; Pel, L.; Huinink, H.P.; Kopinga, K.; Hees, R.P.J. van

    2005-01-01

    The durability and performance of specially developed restoration plasters or renders, are not always as good as expected. Salt crystallization is one of the causes of the observed degradation processes. To understand these processes in more detail, we investigated whether transport in the plasters

  7. Sputter Deposited TiOx Thin-Films as Electron Transport Layers in Organic Solar Cells

    DEFF Research Database (Denmark)

    Mirsafaei, Mina; Bomholt Jensen, Pia; Lakhotiya, Harish

    solar cells that eliminates the need for light soaking and still allows for integration on flexible plastic substrates, which is beneficial for roll-to-roll mass production of flexible organic solar cells. 1. Steim, R.; Kogler, F. R.; Brabec, C. J., Interface materials for organic solar cells. Journal......The use of interfacial layers in organic solar cells has been investigated intensively over the past years, as it has a strong impact on both the power conversion efficiency and stability of the devices. Among the systems investigated are for example alkali salts, ionic liquids, neutral polymers...... transparency and favorable energy-level alignment with many commonly used electron-acceptor materials. There are several methods available for fabricating compact TiOx thin-films for use in organic solar cells, including sol-gel solution processing, spray pyrolysis and atomic-layer deposition; however...

  8. Transport and magnetic properties of Mn- and Mg-implanted GaAs layers

    International Nuclear Information System (INIS)

    Kulbachinskii, V.A.; Lunin, R.A.; Gurin, P.V.; Perov, N.S.; Sheverdyaeva, P.M.; Danilov, Yu.A.

    2006-01-01

    Mn-doped GaAs layers were fabricated by direct ion implantation into semi-insulating GaAs (100) substrates. The implanted samples were annealed at temperatures T a =700-800 o C. At these temperatures MnAs clusters are formed in GaAs due to decay of the supersaturated solid solution of Mn in GaAs. Additional Mg ion implantation was used to provide an enhancement of p-type doping in (Ga,Mn)As layers. Temperature dependence of resistance was measured between 4.2 and 300K, and the Hall effect was measured at temperatures of 4.2-200K. Anomalous Hall effect and ferromagnetic behavior have been found for all samples. An enhanced positive magnetoresistance was also observed at T>30K

  9. Comparison of scrape-off layer transport in inner and outer wall limited JET plasmas

    Czech Academy of Sciences Publication Activity Database

    Silva, C.; Arnoux, G.; Devaux, S.; Frigione, D.; Groth, M.; Horáček, Jan; Lomas, P. J.; Marsen, S.; Matthews, G.; Pitts, R. A.; JET EFDA, Contributors.

    2013-01-01

    Roč. 438, suppl (2013), S189-S193 ISSN 0022-3115. [International Conferenceon Plasma Surface Interactions in Controlled Fusion Devices/20./. Aachen, 21.05.2012-25.5.2012] R&D Projects: GA ČR(CZ) GAP205/12/2327 Institutional support: RVO:61389021 Keywords : plasma * tokamak * JET scrape-off layer Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.016, year: 2013 http://www.sciencedirect.com/science/article/pii/S0022311513001827#

  10. Transport of desert dust mixed with North African industrial pollutants in the subtropical Saharan Air Layer

    OpenAIRE

    Rodríguez González, Sergio; Alastuey Urós, José Andrés; Alonso Pérez, Silvia; Querol, X.; Cuevas, Emilio; Abreu Afonso, J.; Viana, M.; Pandolfi, M.; Rosa Díaz, Jesús de la

    2011-01-01

    An analysis of chemical composition data of particulate matter samples (TSP, PM10 and PM2.5) collected from 2002 to 2008 in the North Atlantic free troposphere at the Izana Global Atmospheric Watch (GAW) observatory (Tenerife, Canary Islands) shows that desert dust is very frequently mixed with particulate pollutants in the Saharan Air Layer (SAL). The study of this data set with Median Concentrations At Receptor (MCAR) plots allowed the identification of the potential source regions of the d...

  11. The effects of gas diffusion layers structure on water transportation using X-ray computed tomography based Lattice Boltzmann method

    Science.gov (United States)

    Jinuntuya, Fontip; Whiteley, Michael; Chen, Rui; Fly, Ashley

    2018-02-01

    The Gas Diffusion Layer (GDL) of a Polymer Electrolyte Membrane Fuel Cell (PEMFC) plays a crucial role in overall cell performance. It is responsible for the dissemination of reactant gasses from the gas supply channels to the reactant sites at the Catalyst Layer (CL), and the adequate removal of product water from reactant sites back to the gas channels. Existing research into water transport in GDLs has been simplified to 2D estimations of GDL structures or use virtual stochastic models. This work uses X-ray computed tomography (XCT) to reconstruct three types of GDL in a model. These models are then analysed via Lattice Boltzmann methods to understand the water transport behaviours under differing contact angles and pressure differences. In this study, the three GDL samples were tested over the contact angles of 60°, 80°, 90°, 100°, 120° and 140° under applied pressure differences of 5 kPa, 10 kPa and 15 kPa. By varying the contact angle and pressure difference, it was found that the transition between stable displacement and capillary fingering is not a gradual process. Hydrophilic contact angles in the region of 60°<θ < 90° showed stable displacement properties, whereas contact angles in the region of 100°<θ < 140° displayed capillary fingering characteristics.

  12. Microscopic observation of lateral and vertical charge transportation in Si nanocrystals sandwiched by amorphous SiC layers

    Science.gov (United States)

    Xu, Jie; Ji, Yang; Lu, Peng; Bai, Gang; Ren, Qingying; Xu, Jun

    2018-01-01

    Charge injection and transportation process is a fundamental problem to Si nanocrystals (Si-ncs) based electric and photonic devices. In the manuscript, a single layer of Si-ncs sandwiched by amorphous Si carbide (a-SiC) was prepared by excimer laser annealing of a-SiC/a-Si/a-SiC multilayers, and the charging effect was then characterized by Kelvin probe force microscopy (KPFM) on the microscopic scale. Opposite charges were injected into Si-ncs through the biased tip and formed a core-ring or up-down shaped distribution. The decay characteristics showed that these opposite charges would not only vertically tunnel through the bottom a-SiC layer to substrate but also laterally transport and recombine with each other driven by the attractive Coulomb force. Besides, the charge retention time was also found dependent on the injection biases, which is tentatively ascribed to the charge trapping by the Si-ncs/a-SiC interface states under high bias scanning. The analysis was further supported by conductive atomic force microscopy (CAFM) measurement, in which the current-voltage curves gradually shifted during the repetition test, probably because of bias screening by the trapped charges at these interface states.

  13. Predictions of Separated and Transitional Boundary Layers Under Low-Pressure Turbine Airfoil Conditions Using an Intermittency Transport Equation

    Science.gov (United States)

    Suzen, Y. B.; Huang, P. G.; Hultgren, Lennart S.; Ashpis, David E.

    2003-01-01

    A new transport equation for the intermittency factor was proposed to predict separated and transitional boundary layers under low-pressure turbine airfoil conditions. The intermittent behavior of the transitional flows is taken into account and incorporated into computations by modifying the eddy viscosity, t , with the intermittency factor, y. Turbulent quantities are predicted by using Menter s two-equation turbulence model (SST). The intermittency factor is obtained from a transport equation model, which not only can reproduce the experimentally observed streamwise variation of the intermittency in the transition zone, but also can provide a realistic cross-stream variation of the intermittency profile. In this paper, the intermittency model is used to predict a recent separated and transitional boundary layer experiment under low pressure turbine airfoil conditions. The experiment provides detailed measurements of velocity, turbulent kinetic energy and intermittency profiles for a number of Reynolds numbers and freestream turbulent intensity conditions and is suitable for validation purposes. Detailed comparisons of computational results with experimental data are presented and good agreements between the experiments and predictions are obtained.

  14. Fission Product Transport in TRISO Particle Layers under Operating and Off-Normal Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Van der Ven, Anton [Univ. of Michigan, Ann Arbor, MI (United States); Was, Gary [Univ. of Michigan, Ann Arbor, MI (United States); Wang, Lumin [Univ. of Michigan, Ann Arbor, MI (United States); Taheri, Mitra [Drexel Univ., Philadelphia, PA (United States)

    2014-04-26

    The objective of this project is to determine the diffusivity and chemical behavior of key fission products (ag, Cs, I. Te, Eu and Sr) through SiC and PyC both thermally, under irradiation, and under stress using FP introduction techniques that avoid the pitfalls of past experiments. The experimental approach is to create thin PyC-SiC couples containing the fission product to be studied embedded in the PyC layer. These samples will then be subjected to high temperature exposures in a vacuum and also to irradiation at high temperature, and last, to irradiation under stress at high temperature. The PyC serves as a host layer, providing a means of placing the fission product close to the SiC without damaging the SiC layer by its introduction or losing the FP during heating. Experimental measurements of grain boundary structure and distribution (EBSD, HRTEM, APT) will be used in the modeling effort to determine the qualitative dependence of FP diffusion coefficients on grain boundary orientation, temperature and stress.

  15. Low-Temperature Modification of ZnO Nanoparticles Film for Electron-Transport Layers in Perovskite Solar Cells.

    Science.gov (United States)

    Han, Gill Sang; Shim, Hyun-Woo; Lee, Seongha; Duff, Matthew L; Lee, Jung-Kun

    2017-06-09

    An electron-transport layer (ETL) that selectively collects photogenerated electrons is an important constituent of halide perovskite solar cells (PSCs). Although TiO 2 films are widely used as ETL of PSCs, the processing of TiO 2 films with high electron mobility requires high-temperature annealing and TiO 2 dissociates the perovskite layer through a photocatalytic reaction. Here, we report an effective surface-modification method of a room-temperature processed ZnO nanoparticles (NPs) layer as an alternative to the TiO 2 ETL. A combination of simple UV exposure and nitric acid treatment effectively removes the hydroxyl group and passivates surface defects in ZnO NPs. The surface modification of ZnO NPs increases the power conversion efficiency (PCE) of PSCs to 14 % and decreases the aging of PSCs under light soaking. These results suggest that the surface-modified ZnO film can be a good ETL of PSCs and provide a path toward low-temperature processing of efficient and stable PSCs that are compatible with flexible electronics. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. Modeling and analysis of HTM-free perovskite solar cells based on ZnO electron transport layer

    Science.gov (United States)

    Lin, Lingyan; Jiang, Linqin; Qiu, Yu; Yu, Yunlong

    2017-04-01

    On the road towards high-efficiency and low-cost photovoltaic technology, perovskite solar cells (PSCs) emerge as the most promising candidate. Their application is, however, limited by the expensive hole transport material(HTM) and electrode material (e.g. spiro-OMeTAD and gold) and the high-temperature processed electron transport layer (e.g. TiO2) in the common device structure. In this paper, device modeling of HTM free perovskite solar cells having the structure of FTO/ZnO/CH3NH3PbI3/carbon is performed. Various factors that influence the solar cell performance have been investigated, such as doping concentration and thickness of CH3NH3PbI3 absorber layer, the interface defect density and work function of the back contact (φ). The reasonable thickness of CH3NH3PbI3 absorber is around 500 nm. The doping concentrations in the CH3NH3PbI3 layer significantly affect the electron potential barrier height at the junction interface. Meanwhile, to achieve high photovoltaic performance, the defect densities at the CH3NH3PbI3/ZnO interface should be controlled under the order of ∼1017 cm-3 by interface modification. Finally, the φ matching is a requirement to obtain high device performance. We found that an efficiency over 15% can be obtained under the moderate simulation conditions. Moreover, the conversion efficiency of 18.11% can be obtained when the doping concentration of absorber is improved to 1016 cm-3. These findings will provide important guidelines for the manufacturing of low-temperature low-cost perovskite solar cells.

  17. Microstructure of Josephson junctions: Effect on supercurrent transport in YBCO grain boundary and barrier layer junctions

    International Nuclear Information System (INIS)

    Merkle, K.L.; Huang, Y.

    1998-01-01

    The electric transport of high-temperature superconductors, such as YBa 2 Cu 3 O 7-x (YBCO), can be strongly restricted by the presence of high-angle grain boundaries (GB). This weak-link behavior is governed by the macroscopic GB geometry and the microscopic grain boundary structure and composition at the atomic level. Whereas grain boundaries present a considerable impediment to high current applications of high T c materials, there is considerable commercial interest in exploiting the weak-link-nature of grain boundaries for the design of microelectronic devices, such as superconducting quantum interference devices (SQUIDs). The Josephson junctions which form the basis of this technology can also be formed by introducing artificial barriers into the superconductor. The authors have examined both types of Josephson junctions by EM techniques in an effort to understand the connection between microstructure/chemistry and electrical transport properties. This knowledge is a valuable resource for the design and production of improved devices

  18. Characterization of scrape-off layer transport in JET limiter plasmas

    Czech Academy of Sciences Publication Activity Database

    Silva, C.; Arnoux, G.; Devaux, S.; Frigione, D.; Groth, M.; Horáček, Jan; Lomas, P. J.; Marsen, S.; Matthews, G.; Meneses, L.; Pitts, R.A.

    2014-01-01

    Roč. 54, č. 8 (2014), 083022-083022 ISSN 0029-5515 R&D Projects: GA ČR(CZ) GAP205/12/2327 Institutional support: RVO:61389021 Keywords : plasma * tokamak * SOL transport * plasma turbulence Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 3.062, year: 2014 http://iopscience.iop.org/0029-5515/54/8/083022/pdf/0029-5515_54_8_083022.pdf

  19. Diffusive heat transport across magnetic islands and stochastic layers in tokamaks

    International Nuclear Information System (INIS)

    Hoelzl, Matthias

    2010-01-01

    Heat transport in tokamak plasmas with magnetic islands and ergodic field lines was simulated at realistic plasma parameters in realistic tokamak geometries. This requires the treatment of anisotropic heat diffusion, which is more efficient along magnetic field lines by up to ten orders of magnitude than perpendicular to them. Comparisons with analytical predictions and experimental measurements allow to determine the stability properties of neoclassical tearing modes as well as the experimental heat diffusion anisotropy.

  20. Transport of desert dust mixed with North African industrial pollutants in the subtropical Saharan Air Layer

    OpenAIRE

    S. Rodríguez; A. Alastuey; S. Alonso-Pérez; X. Querol; E. Cuevas; J. Abreu-Afonso; M. Viana; N. Pérez; M. Pandolfi; J. de la Rosa

    2011-01-01

    An analysis of chemical composition data of particulate matter samples (TSP, PM10 and PM2.5) collected from 2002 to 2008 in the North Atlantic free troposphere at the Izaña Global Atmospheric Watch (GAW) observatory (Tenerife, Canary Islands) shows that desert dust is very frequently mixed with particulate pollutants in the Saharan Air Layer (SAL). The study of this data set with Median Concentrations At Receptor (MCAR) plots allowed the identification of the potential source regions of the d...

  1. Electrical transport and magnetic properties of misfit layered compounds intercalated with cobaltocene

    NARCIS (Netherlands)

    Morales, J; Santos, J; Baas, J; Wiegers, GA; Martinez, JL

    1999-01-01

    The electrical and magnetic properties of misfit layered cobaltocene complexes of composition (PbS)(1.18)(TiS2)(2)(CoCp2)(0.28), (PbS)(1.14)(TaS2)(2)(CoCp2)(0.28), and (PbSe)(1.12)(NbSe2)(2)(CoCp2)(0.27) [Cp = C5H5-] were investigated. All the pristine chalcogenides studied exhibit a metallic

  2. Intermittent transport across the scrape-off layer: latest results from ASDEX Upgrade

    Czech Academy of Sciences Publication Activity Database

    Kočan, M.; Müller, H.W.; Nold, B.; Lunt, T.; Adámek, Jiří; Allan, S.Y.; Bernert, M.; Conway, G.D.; de Marné, P.; Eich, T.; Elmore, S.; Gennrich, F.P.; Herrmann, A.; Horáček, Jan; Huang, Z.; Kallenbach, A.; Komm, Michael; Maraschek, M.; Mehlmann, F.; Müller, S.; Ribeiro, T.T.; Rohde, V.; Schrittwieser, R.; Scott, B.; Stroth, U.; Suttrop, W.; Wolfrum, E.

    2013-01-01

    Roč. 53, č. 7 (2013), 073047-073047 ISSN 0029-5515 R&D Projects: GA MŠk(CZ) LG11018; GA ČR(CZ) GAP205/12/2327; GA ČR GA202/09/1467 Institutional support: RVO:61389021 Keywords : ASDEX Upgrade scrape-off layer * plasma * tokamak * edge-localized mode (ELM) Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 3.243, year: 2013 http://iopscience.iop.org/0029-5515/53/7/073047/pdf/0029-5515_53_7_073047.pdf

  3. Transport of energetic electrons in a magnetically expanding helicon double layer plasma

    International Nuclear Information System (INIS)

    Takahashi, Kazunori; Charles, Christine; Boswell, Rod; Cox, Wes; Hatakeyama, Rikizo

    2009-01-01

    Peripheral magnetic field lines extending from the plasma source into the diffusion chamber are found to separate two regions of Maxwellian electron energy probability functions: the central, ion-beam containing region with an electron temperature of 5 eV, and region near the chamber walls with electrons at 3 eV. Along the peripheral field lines a bi-Maxwellian population with a hot tail at 9 eV is shown to both originate from electrons in the source traveling downstream across the double layer and correspond to a local maximum in ion and electron densities.

  4. Potential Carbon Transport: Linking Soil Aggregate Stability and Sediment Enrichment for Updating the Soil Active Layer within Intensely Managed Landscapes

    Science.gov (United States)

    Wacha, K.; Papanicolaou, T.; Abban, B. K.; Wilson, C. G.

    2014-12-01

    Currently, many biogeochemical models lack the mechanistic capacity to accurately simulate soil organic carbon (SOC) dynamics, especially within intensely managed landscapes (IMLs) such as those found in the U.S. Midwest. These modeling limitations originate by not accounting for downslope connectivity of flowpathways initiated and governed by landscape processes and hydrologic forcing, which induce dynamic updates to the soil active layer (generally top 20-30cm of soil) with various sediment size fractions and aggregates being transported and deposited along the downslope. These hydro-geomorphic processes, often amplified in IMLs by tillage events and seasonal canopy, can greatly impact biogeochemical cycles (e.g., enhanced mineralization during aggregate breakdown) and in turn, have huge implications/uncertainty when determining SOC budgets. In this study, some of these limitations were addressed through a new concept, Potential Carbon Transport (PCT), a term which quantifies a maximum amount of material available for transport at various positions of the landscape, which was used to further refine a coupled modeling framework focused on SOC redistribution through downslope/lateral connectivity. Specifically, the size fractions slaked from large and small aggregates during raindrop-induced aggregate stability tests were used in conjunction with rainfall-simulated sediment enrichment ratio (ER) experiments to quantify the PCT under various management practices, soil types and landscape positions. Field samples used in determining aggregate stability and the ER experiments were collected/performed within the historic Clear Creek Watershed, home of the IML Critical Zone Observatory, located in Southeastern Iowa.

  5. Systematic Development and Validation of a Thin-Layer Densitometric Bioanalytical Method for Estimation of Mangiferin Employing Analytical Quality by Design (AQbD) Approach.

    Science.gov (United States)

    Khurana, Rajneet Kaur; Rao, Satish; Beg, Sarwar; Katare, O P; Singh, Bhupinder

    2016-01-01

    The present work aims at the systematic development of a simple, rapid and highly sensitive densitometry-based thin-layer chromatographic method for the quantification of mangiferin in bioanalytical samples. Initially, the quality target method profile was defined and critical analytical attributes (CAAs) earmarked, namely, retardation factor (Rf), peak height, capacity factor, theoretical plates and separation number. Face-centered cubic design was selected for optimization of volume loaded and plate dimensions as the critical method parameters selected from screening studies employing D-optimal and Plackett-Burman design studies, followed by evaluating their effect on the CAAs. The mobile phase containing a mixture of ethyl acetate : acetic acid : formic acid : water in a 7 : 1 : 1 : 1 (v/v/v/v) ratio was finally selected as the optimized solvent for apt chromatographic separation of mangiferin at 262 nm withRf 0.68 ± 0.02 and all other parameters within the acceptance limits. Method validation studies revealed high linearity in the concentration range of 50-800 ng/band for mangiferin. The developed method showed high accuracy, precision, ruggedness, robustness, specificity, sensitivity, selectivity and recovery. In a nutshell, the bioanalytical method for analysis of mangiferin in plasma revealed the presence of well-resolved peaks and high recovery of mangiferin. © The Author 2016. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

  6. Turbulent transport and production/destruction of ozone in a boundary layer over complex terrain

    Science.gov (United States)

    Greenhut, Gary K.; Jochum, Anne M.; Neininger, Bruno

    1994-01-01

    The first Intensive Observation Period (IOP) of the Swiss air pollution experiment POLLUMET took place in 1990 in the Aare River Valley between Bern and Zurich. During the IOP, fast response measurements of meteorological variables and ozone concentration were made within the boundary layer aboard a motorglider. In addition, mean values of meteorological variables and the concentrations of ozone and other trace species were measured using other aircraft, pilot balloons, tethersondes, and ground stations. Turbulent flux profiles of latent and sensible heat and ozone are calculated from the fast response data. Terms in the ozone mean concentration budget (time rate of change of mean concentration, horizontal advection, and flux divergence) are calculated for stationary time periods both before and after the passage of a cold front. The source/sink term is calculated as a residual in the budget, and its sign and magnitude are related to the measured concentrations of reactive trace species within the boundary layer. Relationships between concentration ratios of trace species and ozone concentration are determined in order to understand the influence of complex terrain on the processes that produce and destroy ozone.

  7. Impact of Transport Layer Protocols on Reliable Information Access in Smart Grids

    DEFF Research Database (Denmark)

    Shahid, Kamal; Saeed, Aamir; Kristensen, Thomas le Fevre

    2017-01-01

    Time is critical for certain types of dynamic information (e.g. frequency control) in a smart grid scenario. The usefulness of such information depends upon the arrival within a specific frame of time, which in other case may not serve the purpose and effect controller’s performance...... of events at grid assets as well as the information update strategy in one single metric which otherwise is not very intuitive and difficult to allow a similar useful comparison. Further, the analysis is concluded by providing a clear guide on the selection of the transport protocol to meet application...

  8. Spectra and Charge Transport of Polar Molecular Photoactive Layers Used for Solar Cells

    Directory of Open Access Journals (Sweden)

    Yuanzuo Li

    2015-01-01

    Full Text Available The ground state structures, HOMO and LUMO energy levels, band gaps ΔH-L, ionization potentials (IP, and electron affinities (EA of three types of copolymer P1 and its derivatives P2, P3, and PBDT-BTA were investigated by using density functional theory (DFT with B3LYP and 6-31G (d basis set. On the base of optimized structures of ground states, their absorption spectra were obtained by using TD-DFT//Cam-B3LYP/6-31 G (d. Research shows that with the increasing conjugated units, HOMO energy levels increased, LUMO energy levels decreased, and band gaps decreased gradually. Moreover, their ionization potentials decreased and electron affinities increased along with the increase of conjugated chains, and absorption spectra red-shifted. In addition, the side chain has a significant effect on the properties of ground and excited states. In order to investigate the influence of conjugated units and side chain on the charge transport, their hole and electron reorganization energies were calculated, and the results indicated that Pb have a good hole transport capability. Considering the practical application, the HOMO and LUMO energy levels, band gaps, and absorption spectra under external electric field were studied, and the results proved that the external electric field has an effect on the optical and electronic properties.

  9. Radon transport model into a porous ground layer of finite capacity

    Science.gov (United States)

    Parovik, Roman

    2017-10-01

    The model of radon transfer is considered in a porous ground layer of finite power. With the help of the Laplace integral transformation, a numerical solution of this model is obtained which is based on the construction of a generalized quadrature formula of the highest degree of accuracy for the transition to the original - the function of solving this problem. The calculated curves are constructed and investigated depending on the diffusion and advection coefficients.The work was a mathematical model that describes the effect of the sliding attachment (stick-slip), taking into account hereditarity. This model can be regarded as a mechanical model of earthquake preparation. For such a model was proposed explicit finite- difference scheme, on which were built the waveform and phase trajectories hereditarity effect of stick-slip.

  10. Electron Transport in SrTio3 Accumulation Layers and Semiconductor Nanocrystal Films

    Science.gov (United States)

    Fu, Han

    In this thesis, we study two subjects: SrTiO3 (STO) accumulation layers and films made of semiconductor nanocrystals (NCs), which are important for technological applications. We start from the low temperature conductivity of electron accumulation layers induced by the very strong electric field at the surface of STO sample. Due to the strongly nonlinear lattice dielectric response, the three-dimensional density of electrons n(z) in such a layer decays with the distance from the surface z very slowly as n(z) ≃ 1/z12/7 . We show that when the mobility is limited by the surface scattering the contribution of such a tail to the conductivity diverges at large z because of growing time electrons need to reach the surface. We explore truncation of this divergence by the finite sample width, by the bulk scattering rate, by the back gate voltage, or by the crossover to the bulk linear dielectric response with the dielectric constant kappa. As a result we arrive at the anomalously large mobility, which depends not only on the rate of the surface scattering, but also on the physics of truncation. Similar anomalous behavior is found for the Hall factor, the magnetoresistance, and the thermopower. For the second part, we extend to the cases of spherical and cylindrical geometries, and more complicated planar structures. For the planar case, we study overlapping accumulation layers in GdTiO3/STO/GdTiO 3 quantum wells and electron gases created by spill-out from NSTO (heavily n-type doped STO) layers into STO. Generalization of our approach to a spherical donor cluster creating a big Thomas-Fermi atom with electrons in STO brings us to the problem of supercharged nuclei. It is known that for an atom with nuclear charge Ze, where Z > 170, electrons collapse onto the nucleus resulting in a net charge Zn theories of roughness scattering so far dealt only with the small-density single subband two-dimensional (2D) electron gas. Here we develop a theory of roughness scattering

  11. Pore-Network Modeling of Water and Vapor Transport in the Micro Porous Layer and Gas Diffusion Layer of a Polymer Electrolyte Fuel Cell

    NARCIS (Netherlands)

    Qin, C.; Hassanizadeh, S.M.; van Oosterhout, L.M.

    2016-01-01

    In the cathode side of a polymer electrolyte fuel cell (PEFC), a micro porous layer (MPL) added between the catalyst layer (CL) and the gas diffusion layer (GDL) plays an important role in water management. In this work, by using both quasi-static and dynamic pore-network models, water and vapor

  12. Observations of Upward Propagating Gravity Waves in the Vertical Transport of Aerosols during Daytime Boundary Layer Evolution over Central Himalayan Region

    Science.gov (United States)

    Shukla, K. K.; Phani Kumar, D. V.; Kondapalli, N. K.; Kotamarthi, V. R.; Newsom, R. K.

    2014-12-01

    In this study, we present a case study on 16 October 2011 to show the first observational evidence of the influence of short period gravity waves in aerosol transport during daytime over the central Himalayan region. The Doppler lidar data has been utilized to address the daytime boundary layer evolution and related aerosol dynamics over the site. Mixing layer height is estimated by wavelet covariance transform method and found to be ~ 0.7 km, AGL. Aerosol optical depth observations during daytime revealed an asymmetry showing clear enhancement during afternoon hours as compared to forenoon. Interestingly, Fourier and wavelet analysis of vertical velocity and attenuated backscatter showed similar 50-90 min short period gravity wave signatures during afternoon hours. Moreover, our observations showed that gravity waves are dominant within the boundary layer implying that the daytime boundary layer dynamics is playing a vital role in transporting the aerosols from surface to the top of the boundary layer. Similar modulations are also evident in surface parameters like temperature, relative humidity and wind speed indicating these waves are associated with the dynamical aspects over Himalayan region. Finally, time evolution of range-height indicator snapshots during daytime showed strong upward velocities especially during afternoon hours implying that convective processes through short period gravity waves plays a significant role in transporting aerosols from the nearby valley region to boundary layer top over the site. These observations also establish the importance of wave induced daytime convective boundary layer dynamics in the lower Himalayan region.

  13. Effect of rotational speed modulation on heat transport in a fluid layer with temperature dependent viscosity and internal heat source

    Directory of Open Access Journals (Sweden)

    B.S. Bhadauria

    2014-12-01

    Full Text Available In this paper, a theoretical investigation has been carried out to study the combined effect of rotation speed modulation and internal heating on thermal instability in a temperature dependent viscous horizontal fluid layer. Rayleigh–Bénard momentum equation with Coriolis term has been considered to describe the convective flow. The system is rotating about it is own axis with non-uniform rotational speed. In particular, a time-periodic and sinusoidally varying rotational speed has been considered. A weak nonlinear stability analysis is performed to find the effect of modulation on heat transport. Nusselt number is obtained in terms of amplitude of convection and internal Rayleigh number, and depicted graphically for showing the effects of various parameters of the system. The effect of modulated rotation speed is found to have a stabilizing effect for different values of modulation frequency. Further, internal heating and thermo-rheological parameters are found to destabilize the system.

  14. Satellite Sounder Observations of Contrasting Tropospheric Moisture Transport Regimes: Saharan Air Layers, Hadley Cells, and Atmospheric Rivers

    Energy Technology Data Exchange (ETDEWEB)

    Nalli, Nicholas R.; Barnet, Christopher D.; Reale, Tony; Liu, Quanhua; Morris, Vernon R.; Spackman, J. Ryan; Joseph, Everette; Tan, Changyi; Sun, Bomin; Tilley, Frank; Leung, L. Ruby; Wolfe, Daniel

    2016-12-01

    This paper examines the performance of satellite sounder atmospheric vertical moisture proles (AVMP) under tropospheric conditions encompassing moisture contrasts driven by convection and advection transport mechanisms, specifically Atlantic Ocean Saharan air layers (SALs) and Pacific Ocean moisture conveyer belts (MCBs) commonly referred to as atmospheric rivers (ARs), both of these being mesoscale to synoptic meteorological phenomena within the vicinity of subtropical Hadley subsidence zones. Operational AVMP environmental data records retrieved from the Suomi National Polar-orbiting Partnership (SNPP) NOAA-Unique Combined Atmospheric Processing System (NUCAPS) are collocated with dedicated radiosonde observations (RAOBs) obtained from ocean-based intensive field campaigns; these RAOBs provide uniquely independent correlative truth data not assimilated into numerical weather prediction models for satellite sounder validation over open ocean. Using these marine-based data, we empirically assess the performance of the operational NUCAPS AVMP product for detecting and resolving these tropospheric moisture features over otherwise RAOB-sparse regions.

  15. Thermally Stable Mesoporous Perovskite Solar Cells Incorporating Low-Temperature Processed Graphene/Polymer Electron Transporting Layer.

    Science.gov (United States)

    Tong, Shi Wun; Balapanuru, Janardhan; Fu, Deyi; Loh, Kian Ping

    2016-11-02

    In the short time since its discovery, perovskite solar cells (PSCs) have attained high power conversion efficiency but their lack of thermal stability remains a barrier to commercialization. Among the experimentally accessible parameter spaces for optimizing performance, identifying an electron transport layer (ETL) that forms a thermally stable interface with perovskite and which is solution-processable at low-temperature will certainly be advantageous. Herein, we developed a mesoporous graphene/polymer composite with these advantages when used as ETL in CH 3 NH 3 PbI 3 PSCs, and a high efficiency of 13.8% under AM 1.5G solar illumination could be obtained. Due to the high heat transmission coefficient and low isoelectric point of mesoporous graphene-based ETL, the PSC device enjoys good chemical and thermal stability. Our work demonstrates that the mesoporous graphene-based scaffold is a promising ETL candidate for high performance and thermally stable PSCs.

  16. Subsonic Investigation of a Leading-Edge Boundary Layer Control Suction System on a High-Speed Civil Transport Configuration

    Science.gov (United States)

    Campbell, Bryan A.; Applin, Zachary T.; Kemmerly, Guy T.; Coe, Paul L., Jr.; Owens, D. Bruce; Gile, Brenda E.; Parikh, Pradip G.; Smith, Don

    1999-01-01

    A wind tunnel investigation of a leading edge boundary layer control system was conducted on a High Speed Civil Transport (HSCT) configuration in the Langley 14- by 22-Foot Subsonic Tunnel. Data were obtained over a Mach number range of 0.08 to 0.27, with corresponding chord Reynolds numbers of 1.79 x 10(exp 6) to 5.76 x 10(exp 6). Variations in the amount of suction, as well as the size and location of the suction area, were tested with outboard leading edge flaps deflected 0 and 30 deg and trailing-edge flaps deflected 0 and 20 deg. The longitudinal and lateral aerodynamic data are presented without analysis. A complete tabulated data listing is also presented herein.

  17. Study of pollutant transport in surface boundary layer by generalized integral transform technique

    Energy Technology Data Exchange (ETDEWEB)

    Guerrero, Jesus S.P.; Heilbron Filho, Paulo F.L. [Comissao Nacional de Energia Nuclear (CNEN), Rio de Janeiro, RJ (Brazil); Pimentel, Luiz C.G. [Universidade Federal do Rio de Janeiro (UFRJ), Rio de Janeiro, RJ (Brazil). Dept. de Meteorologia. Lab. de Modelagem de Processos Marinhos e Atmosfericos (LAMMA); Cataldi, Marcio [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-Graduacao de Engenharia (COPPE)

    2001-07-01

    A theoretical study was developed to obtain solutions of the atmospheric diffusion equation for various point source, considering radioactive decay and axial diffusion, under neutral atmospheric conditions. It was used an algebraic turbulence model available in the literature, based on Monin-Obukhov similarity theory, for the representation of the turbulent transport in the vertical direction, in the longitudinal directions was considered a constant mass eddy diffusivity . The bi-dimensional transient partial differential equation, representative of the physical phenomena, was transformed into a coupled one-dimensional transient equation system by applying the Generalized Integral Transform Technique. The coupled system was solved numerically using a subroutine based in the lines method. In order to evaluate the computational algorithm were analyzed some representative physical situations. (author)

  18. Study of pollutant transport in surface boundary layer by generalized integral transform technique

    International Nuclear Information System (INIS)

    Guerrero, Jesus S.P.; Heilbron Filho, Paulo F.L.; Pimentel, Luiz C.G.; Cataldi, Marcio

    2001-01-01

    A theoretical study was developed to obtain solutions of the atmospheric diffusion equation for various point source, considering radioactive decay and axial diffusion, under neutral atmospheric conditions. It was used an algebraic turbulence model available in the literature, based on Monin-Obukhov similarity theory, for the representation of the turbulent transport in the vertical direction, in the longitudinal directions was considered a constant mass eddy diffusivity . The bi-dimensional transient partial differential equation, representative of the physical phenomena, was transformed into a coupled one-dimensional transient equation system by applying the Generalized Integral Transform Technique. The coupled system was solved numerically using a subroutine based in the lines method. In order to evaluate the computational algorithm were analyzed some representative physical situations. (author)

  19. The Observed Relationship Between Water Vapor and Ozone in the Tropical Tropopause Saturation Layer and the Influence of Meridional Transport

    Science.gov (United States)

    Selkirk, Henry B.; Schoeberl, M. R.; Olsen, M. A.; Douglass, A. R.

    2011-01-01

    We examine balloonsonde observations of water vapor and ozone from three Ticosonde campaigns over San Jose, Costa Rica [10 N, 84 W] during northern summer and a fourth during northern winter. The data from the summer campaigns show that the uppermost portion of the tropical tropopause layer between 360 and 380 K, which we term the tropopause saturation layer or TSL, is characterized by water vapor mixing ratios from proximately 3 to 15 ppmv and ozone from approximately 50 ppbv to 250 ppbv. In contrast, the atmospheric water vapor tape recorder at 380 K and above displays a more restricted 4-7 ppmv range in water vapor mixing ratio. From this perspective, most of the parcels in the TSL fall into two classes - those that need only additional radiative heating to rise into the tape recorder and those requiring some combination of additional dehydration and mixing with drier air. A substantial fraction of the latter class have ozone mixing ratios greater than 150 ppbv, and with water vapor greater than 7 ppmv this air may well have been transported into the tropics from the middle latitudes in conjunction with high-amplitude equatorial waves. We examine this possibility with both trajectory analysis and transport diagnostics based on HIRDLS ozone data. We apply the same approach to study the winter season. Here a very different regime obtains as the ozone-water vapor scatter diagram of the sonde data shows the stratosphere and troposphere to be clearly demarcated with little evidence of mixing in of middle latitude air parcels.

  20. Characterizing the Asian Tropopause Aerosol Layer (ATAL) Using Satellite Observations, Balloon Measurements and a Chemical Transport Model

    Science.gov (United States)

    Fairlie, T. D.; Vernier, J.-P.; Liu, H.; Deshler, T.; Natarajan, M.; Bedka, K.; Wegner, T.; Baker, N.; Gadhavi, H.; Ratnam, M. V.; hide

    2016-01-01

    Satellite observations and numerical modeling studies have demonstrated that the Asian Summer Monsoon (ASM) provide a conduit for gas-phase pollutants in south Asia to reach the lower stratosphere. Now, observations from the CALIPSO satellite have revealed the Asian Tropopause Aerosol Layer (ATAL), a summertime accumulation of aerosols in the upper troposphere and lower stratosphere (UTLS), associated with the ASM anticyclone. The ATAL has potential implications for regional cloud properties, climate, and chemical processes in the UTLS. Here, we show in situ measurements from balloon-borne instruments, aircraft, and satellite observations, together with trajectory and chemical transport model (CTM) simulations to explore the origin, composition, physical, and optical properties of aerosols in the ATAL. In particular, we show balloon-data from our BATAL-2015 field campaign to India and Saudi Arabia in summer 2015, which includes in situ backscatter measurements from COBALD instruments, and the first observations of size and volatility of aerosols in the ATAL layer using optical particle counters (OPCs). Back trajectory calculations initialized from CALIPSO observations point to deep convection over North India as a principal source of ATAL aerosols. Available aircraft observations suggest significant sulfur and carbonaceous components to the ATAL, which is supported by simulations using the GEOS-Chem CTM. Source elimination studies conducted with the GEOS-Chem indicate that ATAL aerosols originate primary from south Asian sources, in contrast with some earlier studies.

  1. Inverted Organic Solar Cells with Low-Temperature Al-Doped-ZnO Electron Transport Layer Processed from Aqueous Solution

    Directory of Open Access Journals (Sweden)

    Qianni Zhang

    2018-01-01

    Full Text Available The aqueous-based Zn-ammine complex solutions represent one of the most promising routes to obtain the ZnO electron transport layer (ETL at a low temperature in inverted organic solar cells (OSCs. However, to dope the ZnO film processed from the Zn-ammine complex solutions is difficult since the introduction of metal ions into the Zn-ammine complex is a nontrivial process as ammonium hydroxide tends to precipitate metal salts due to acid-base neutralization reactions. In this paper, we investigate the inverted OSCs with Al-doped-ZnO ETL made by immersion of metallic Al into the Zn-ammine precursor solution. The effects of ZnO layer with different immersion time of Al on film properties and solar cell performance have been studied. The results show that, with the Al-doped-ZnO ETL, an improvement of the device performance could be obtained compared with the device with the un-doped ZnO ETL. The improved device performance is attributed to the enhancement of charge carrier mobility leading to a decreased charge carrier recombination and improved charge collection efficiency. The fabricated thin film transistors with the same ZnO or AZO films confirm the improved electrical characteristics of the Al doped ZnO film.

  2. Halide perovskite solar cells using monocrystalline TiO2 nanorod arrays as electron transport layers: impact of nanorod morphology

    Science.gov (United States)

    Thakur, Ujwal Kumar; Askar, Abdelrahman M.; Kisslinger, Ryan; Wiltshire, Benjamin D.; Kar, Piyush; Shankar, Karthik

    2017-07-01

    This is the first report of a 17.6% champion efficiency solar cell architecture comprising monocrystalline TiO2 nanorods (TNRs) coupled with perovskite, and formed using facile solution processing without non-routine surface conditioning. Vertically oriented TNR ensembles are desirable as electron transporting layers (ETLs) in halide perovskite solar cells (HPSCs) because of potential advantages such as vectorial electron percolation pathways to balance the longer hole diffusion lengths in certain halide perovskite semiconductors, ease of incorporating nanophotonic enhancements, and optimization between a high contact surface area for charge transfer (good) versus high interfacial recombination (bad). These advantages arise from the tunable morphology of hydrothermally grown rutile TNRs, which is a strong function of the growth conditions. Fluorescence lifetime imaging microscopy of the HPSCs demonstrated a stronger quenching of the perovskite PL when using TNRs as compared to mesoporous/compact TiO2 thin films. Due to increased interfacial contact area between the ETL and perovskite with easier pore filling, charge separation efficiency is dramatically enhanced. Additionally, solid-state impedance spectroscopy results strongly suggested the suppression of interfacial charge recombination between TNRs and perovskite layer, compared to other ETLs. The optimal ETL morphology in this study was found to consist of an array of TNRs ∼300 nm in length and ∼40 nm in width. This work highlights the potential of TNR ETLs to achieve high performance solution-processed HPSCs.

  3. Asymptotic modeling of transport phenomena at the interface between a fluid and a porous layer: Jump conditions

    Science.gov (United States)

    Angot, Philippe; Goyeau, Benoît; Ochoa-Tapia, J. Alberto

    2017-06-01

    We develop asymptotic modeling for two- or three-dimensional viscous fluid flow and convective transfer at the interface between a fluid and a porous layer. The asymptotic model is based on the fact that the thickness d of the interfacial transition region Ωfp of the one-domain representation is very small compared to the macroscopic length scale L . The analysis leads to an equivalent two-domain representation where transport phenomena in the transition layer of the one-domain approach are represented by algebraic jump boundary conditions at a fictive dividing interface Σ between the homogeneous fluid and porous regions. These jump conditions are thus stated up to first-order in O (d /L ) with d /L ≪1 . The originality and relevance of this asymptotic model lies in its general and multidimensional character. Indeed, it is shown that all the jump interface conditions derived for the commonly used 1D-shear flow are recovered by taking the tangential component of the asymptotic model. In that case, the comparison between the present model and the different models available in the literature gives explicit expressions of the effective jump coefficients and their associated scaling. In addition for multi-dimensional flows, the general asymptotic model yields the different components of the jump conditions including a new specific equation for the cross-flow pressure jump on Σ .

  4. Assessing the transport of PAH in the surficial sediment layer by passive sampler approach.

    Science.gov (United States)

    Belles, Angel; Alary, Claire; Criquet, Justine; Ivanovsky, Anastasia; Billon, Gabriel

    2017-02-01

    A new method based on passive samplers has been developed to assess the diffusive flux of fluorene, fluoranthene and pyrene in the sediment bed and across the sediment-water interface. The dissolved compound concentration gradient in the sediment in the vertical direction was measured at the outlet of a storm water pond by using polyethylene strips as passive samplers. Simultaneously, the dissipation of a set of tracer compounds preloaded in the passive samplers was measured to estimate the effective diffusion coefficients of the pollutants in the sediment. Both measurements were used to evaluate the diffusive flux of the compounds according to Fick's first law. The diffusive fluxes of the 3 studied compounds have been estimated with a centimetre-scale resolution in the upper 44cm of the sediment. According to the higher compound diffusion coefficient and the steeper concentration gradient in the surficial sediment layer, the results show that the net flux of compounds near the sediment interface (1cm depth) is on average 500 times higher than in the deep sediment, with average fluxes at 1cm depth on the order of 5, 0.1 and 0.1ng/m 2 /y for fluorene, fluoranthene and pyrene, respectively. Copyright © 2016 Elsevier B.V. All rights reserved.

  5. Equilibrium, kinetic and reactive transport models for Pu: employing numerical methods to uncover the nature of the intrinsic colloid

    International Nuclear Information System (INIS)

    Schwantes, Jon M.; Batchelor, Bill

    2000-01-01

    Future missions for the Department of Defense include processing plutonium for vitrification and conversion to mixed oxide fuels for commercial use. Such processing could result in the production of Pu-containing waste and unplanned releases of Pu to the environment. Some releases related to plutonium processing have occurred in the past. However, scientists are currently not able to explain the observed behavior of plutonium in natural systems. For example, classical filtration theory predicts that plutonium transport within groundwater should be limited to a few tens of meters. Experimental observations, however, show that plutonium is present in groundwater at distances orders of magnitude farther away from its source than predicted. Before adequate disposal practices can be designed for plutonium, its behavior in these systems must be better understood. The overall goal of this project is to develop equilibrium, kinetic and reactive transport models that describe the behavior of Pu in aqueous systems and to apply these models to natural and engineered systems

  6. Long-term climatology of air mass transport through the Tropical Tropopause Layer (TTL during NH winter

    Directory of Open Access Journals (Sweden)

    K. Krüger

    2008-02-01

    Full Text Available A long-term climatology of air mass transport through the tropical tropopause layer (TTL is presented, covering the period from 1962–2005. The transport through the TTL is calculated with a Lagrangian approach using radiative heating rates as vertical velocities in an isentropic trajectory model. We demonstrate the improved performance of such an approach compared to previous studies using vertical winds from meteorological analyses. Within the upper part of the TTL, the averaged diabatic ascent is 0.5 K/day during Northern Hemisphere (NH winters 1992–2001. Climatological maps show a cooling and strengthening of this part of the residual circulation during the 1990s and early 2000s compared to the long-term mean. Lagrangian cold point (LCP fields show systematic differences for varying time periods and natural forcing components. The interannual variability of LCP temperature and density fields is found to be influenced by volcanic eruptions, El Niño Southern Oscillation (ENSO, Quasi-Biennial Oscillation (QBO and the solar cycle. The coldest and driest TTL is reached during QBO easterly phase and La Niña over the western Pacific, whereas during volcanic eruptions, El Niño and QBO westerly phase it is warmer and less dry.

  7. Evidence for a poloidally localized enhancement of radial transport in the scrape-off layer of the Tore Supra tokamak

    International Nuclear Information System (INIS)

    Gunn, J.P.; Boucher, C.; Dionne, M.; Duran, I.; Fuchs, V.; Loarer, T.; Nanobashvili, I.; Panek, R.; Pascal, J.-Y.; Saint-Laurent, F.; Stoeckel, J.; Rompuy, T. van; Zagorski, R.; Adamek, J.; Bucalossi, J.; Dejarnac, R.; Devynck, P.; Hertout, P.; Hron, M.; Lebrun, G.; Moreau, P.; Rimini, F.; Sarkissian, A.; Oost, G. van

    2007-01-01

    Near-sonic parallel flows are systematically observed in the far scrape-off layer (SOL) of the limiter tokamak Tore Supra, as in many L-mode X-point divertor tokamak plasmas. The poloidal variation of the parallel flow has been measured by moving the contact point of a small circular plasma onto limiters at different poloidal angles. The resulting variations of flow are consistent with the existence of a poloidally localized enhancement of radial transport concentrated in a 30 deg. sector near the outboard midplane. If the plasma contact point is placed on the inboard limiters, then the SOL expands to fill all the space between the plasma and the outboard limiters, with density decay lengths between 10 and 20 cm. On the other hand, if the contact point lies on the outboard limiters, the localized plasma outflux is scraped off and the SOL is very thin with decay lengths around 2-3 cm. The outboard radial transport would have to be about two orders of magnitude stronger than inboard to explain these results

  8. Time-resolved soft-x-ray studies of energy transport in layered and planar laser-driven targets

    International Nuclear Information System (INIS)

    Stradling, G.L.

    1982-01-01

    New low-energy x-ray diagnostic techniques are used to explore energy-transport processes in laser heated plasmas. Streak cameras are used to provide 15-psec time-resolution measurements of subkeV x-ray emission. A very thin (50 μg/cm 2 ) carbon substrate provides a low-energy x-ray transparent window to the transmission photocathode of this soft x-ray streak camera. Active differential vacuum pumping of the instrument is required. The use of high-sensitivity, low secondary-electron energy-spread CsI photocathodes in x-ray streak cameras is also described. Significant increases in sensitivity with only a small and intermittant decrease in dynamic range were observed. These coherent, complementary advances in subkeV, time-resolved x-ray diagnostic capability are applied to energy-transport investigations of 1.06-μm laser plasmas. Both solid disk targets of a variety of Z's as well as Be-on-Al layered-disk targets were irradiated with 700-psec laser pulses of selected intensity between 3 x 10 14 W/cm 2 and 1 x 10 15 W/cm 2

  9. Graphene oxide/PEDOT:PSS composite hole transport layer for efficient and stable planar heterojunction perovskite solar cells

    Science.gov (United States)

    Lee, Da-Young; Na, Seok-In; Kim, Seok-Soon

    2016-01-01

    We investigated a graphene oxide (GO)/poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) composite as a promising candidate for the practical application of a 2-D carbonaceous hole transport layer (HTL) to planar heterojunction perovskite solar cells (PeSCs) consisting of a transparent electrode/HTL/perovskite/fullerene/metal electrode. Both the insulating properties of GO and the non-uniform coating of the transparent electrode with GO cause the poor morphology of perovskite induced low power conversion efficiency (PCE) of 6.4%. On the other hand, PeSCs with a GO/PEDOT:PSS composite HTL, exhibited a higher PCE of 9.7% than that of a device fabricated with conventional PEDOT:PSS showing a PCE of 8.2%. The higher performance is attributed to the decreased series resistance (RS) and increased shunt resistance (RSh). The well-matched work-function between GO (4.9 eV) and PEDOT:PSS (5.1 eV) probably results in more efficient charge transport and an overall decrease in RS. The existence of GO with a large bandgap of ~3.6 eV might induce the effective blocking of electrons, leading to an increase of RSh. Moreover, improvement in the long-term stability under atmospheric conditions was observed.

  10. Stochastic reconstruction and a scaling method to determine effective transport coefficients of a proton exchange membrane fuel cell catalyst layer

    Energy Technology Data Exchange (ETDEWEB)

    Barbosa, R. [Centro de Investigacion en Energia, UNAM, Privada Xochicalco S/N, 62580 Temixco (Mexico); Andaverde, J. [Centro de Investigacion en Ingenieria y Ciencias Aplicadas, UAEM, Av. Universidad 1001, Col. Chamilpa, 62210 Cuernavaca (Mexico); Escobar, B. [Instituto Tecnologico de Cancun, Av. Kabah 3, 77515 Cancun (Mexico); Cano, U. [Instituto de Investigaciones Electricas, Av. Reforma 113, col. Palmira, 62490 Cuernavaca (Mexico)

    2011-02-01

    This work uses a method for the stochastic reconstruction of catalyst layers (CLs) proposing a scaling method to determine effective transport properties in proton exchange membrane fuel cell (PEMFC). The algorithm that generates the numerical grid makes use of available information before and after manufacturing the CL. The structures so generated are characterized statistically by two-point correlation functions and by the resultant pore size distribution. As an example of this method, the continuity equation for charge transport is solved directly on the three-dimensional grid of finite control volumes (FCVs), to determine effective electrical and proton conductivities of different structures. The stochastic reconstruction and the electrical and proton conductivity of a 45 {mu}m side size cubic sample of a CL, represented by more than 3.3 x 10{sup 12} FVCs were realized in a much shorter time compared with non-scaling methods. Variables studied in an example of CL structure were: (i) volume fraction of dispersed electrolyte, (ii) total CL porosity and (iii) pore size distribution. Results for the conduction efficiency for this example are also presented. (author)

  11. Charge-carrier transport in epitactical strontium titanate layers for the application in superconducting components; Ladungstraegertransport in epitaktischen Strontiumtitanat-Schichten fuer den Einsatz in supraleitenden Bauelementen

    Energy Technology Data Exchange (ETDEWEB)

    Grosse, Veit

    2011-02-01

    In this thesis thin STO layers were epitactically deposited on YBCO for a subsequent electrical characterization. YBCO layers with a roughness of less than 2 nm (RMS), good out-of-plane orientation with a half-width in the rocking curve in the range (0.2..0.3) at only slightly diminished critical temperature could be reached. The STO layers exhibited also very good crystallographic properties. The charge-carrier transport in STO is mainly dominated by interface-limited processes. By means of an in thesis newly developed barrier model thereby the measured dependencies j(U,T) respectively {sigma}(U,T) could be described very far-reachingly. At larger layer thicknesses and low temperatures the charge-carrier transport succeeds by hopping processes. So in the YBCO/STO/YBCO system the variable-range hopping could be identified as dominating transport process. Just above U>10 V a new behaviour is observed, which concerning its temperature dependence however is also tunnel-like. The STO layers exhibit here very large resistances, so that fields up to 10{sup 7}..10{sup 8} V/m can be reached without flowing of significant leakage currents through the barrier. In the system YBCO/STO/Au the current transport can be principally in the same way as in the YBCO/STO/YBCO system. The special shape and above all the asymmetry of the barrier however work out very distinctly. It could be shown that at high temperatures according to the current direction a second barrier on the opposite electrode must be passed. So often observed breakdown effects can be well described. For STO layer-thicknesses in the range around 25 nm in the whole temperature range studied inelastic tunneling over chains of localized states was identified as dominating transport process. It could however for the first time be shown that at very low temperatures in the STO layers Coulomb blockades can be formed.

  12. Electronic traps in OLED transport layers: influence of doping and accelerated aging

    Science.gov (United States)

    Steiger, Juergen; Karg, Siegfried; von Seggern, Heinz

    2001-02-01

    The methods of thermally stimulated currents (TSC) and thermally stimulated luminescence (TSL) were employed to reveal the trap structure of the most prominent organic semiconductors materials such as tris-8-(hydroxyquinoline) (Alq3), N-N'-di(1-naphtyl)-N-N'-diphenylbenzidine ((alpha) -NPD), and 4,4',4'-tris-(N-2-naphtyl)-N-phenylamino- triphenylamine (1-Naph-DATA). The energetic trap depths and a lower limit of the trap densities were derived for all investigated materials by means of the initial-rise method and curve fitting techniques. Typical activation energies range between 0.1 and 0.6 eV and trap concentrations differ between 1014 and 1017 cm-3. Most materials exhibit trap levels with a single activation energy, however, in Alq3 a brought distribution of trap depths will be reported. In addition, the polarity of the dominant trap levels was determined by a comparison of TSC spectra from optically and electrically filled traps. Besides the trap detection and characterization the effect of doping and accelerated aging on the trap structure will be shown. TSC and TSL results on rubrene doped Alq3 reveals a characteristic shift in the trap depth indicating new rubrene related trapping site. The effect of aging on the trap structure of organic semiconductors in 'potentially harmful' atmospheres such as oxygen and humidity and their correlation to I-V characteristics will also be reported.

  13. A transport layer protocol for the future high speed grid computing: SCTP versus fast tcp multihoming

    International Nuclear Information System (INIS)

    Arshad, M.J.; Mian, M.S.

    2010-01-01

    TCP (Transmission Control Protocol) is designed for reliable data transfer on the global Internet today. One of its strong points is its use of flow control algorithm that allows TCP to adjust its congestion window if network congestion is occurred. A number of studies and investigations have confirmed that traditional TCP is not suitable for each and every type of application, for example, bulk data transfer over high speed long distance networks. TCP sustained the time of low-capacity and short-delay networks, however, for numerous factors it cannot be capable to efficiently deal with today's growing technologies (such as wide area Grid computing and optical-fiber networks). This research work surveys the congestion control mechanism of transport protocols, and addresses the different issues involved for transferring the huge data over the future high speed Grid computing and optical-fiber networks. This work also presents the simulations to compare the performance of FAST TCP multihoming with SCTP (Stream Control Transmission Protocol) multihoming in high speed networks. These simulation results show that FAST TCP multihoming achieves bandwidth aggregation efficiently and outperforms SCTP multihoming under a similar network conditions. The survey and simulation results presented in this work reveal that multihoming support into FAST TCP does provide a lot of benefits like redundancy, load-sharing and policy-based routing, which largely improves the whole performance of a network and can meet the increasing demand of the future high-speed network infrastructures (such as in Grid computing). (author)

  14. Effect of disorder on carrier transport in ZnO thin films grown by atomic layer deposition at different temperatures

    Science.gov (United States)

    Saha, D.; Das, Amit. K.; Ajimsha, R. S.; Misra, P.; Kukreja, L. M.

    2013-07-01

    We have grown ˜200 nm thick ZnO films on (0001) sapphire substrates using atomic layer deposition at different substrate temperatures ranging from ˜150 to 350 °C. X-ray diffraction and photoluminescence spectra of these films showed that crystalline and compositional native defects were strongly dependent on the substrate temperature. Room temperature Hall measurement showed that all the films were degenerate with carrier concentration exceeding the Mott's critical density nc required for metallic conduction. The lowest value of room temperature resistivity ˜3.6 × 10-3 Ω cm was achieved for the film deposited at ˜200 °C, which had an estimated carrier concentration ˜5.7 × 1019 cm-3 and mobility ˜30 cm2/V s. The films deposited both below and above ˜200 °C showed increased resistivity and decreased mobility presumably due to the intensified defects and deteriorated crystalline quality of these films. To investigate the effect of disorder on the underlying charge transport mechanisms in these films, the electrical resistivity was measured in the temperature range of ˜4.2 to 300 K. The films grown at ˜150, 300, and 350 °C were found to be semiconducting in the entire range of the measurement temperature due to the intensified disorder which impeded the metallic transport in these films. However, the films grown at ˜200 and 250 °C showed a transition from metallic to semiconducting transport behaviour at lower temperatures due to the reduced defects and improved crystalline quality of these films. The observed semiconducting behaviour below the transition temperature for these films could be well explained by considering quantum corrections to the Boltzmann conductivity which includes the effect of disorder induced weak localization and coulomb electron-electron interactions.

  15. Flexible ITO-free organic solar cells applying aqueous solution-processed V2O5 hole transport layer: An outdoor stability study

    DEFF Research Database (Denmark)

    Lima, F. Anderson S.; Beliatis, Michail J.; Roth, Bérenger

    2016-01-01

    Solution processable semiconductor oxides have opened a new paradigm for theenhancement of the lifetime of thin film solar cells. Their fabrication by low-costand environmentally friendly solution-processable methods makes them ideal barrier(hole and electron) transport layers. In this work, we...... fabricate flexible ITO-freeorganic solar cells (OPV) by printing methods applying an aqueous solution-processed V2O5 as the hole transport layer (HTL) and compared them to devices applying PEDOT:PSS. The transparent conducting electrode was PET/Ag/PEDOT/ZnO, and the OPV configuration was PET/Ag/PEDOT/ZnO/P3...

  16. Efficient Planar Perovskite Solar Cells with Reduced Hysteresis and Enhanced Open Circuit Voltage by Using PW12-TiO2 as Electron Transport Layer.

    Science.gov (United States)

    Huang, Chun; Liu, Canjun; Di, Yunxiang; Li, Wenzhang; Liu, Fangyang; Jiang, Liangxing; Li, Jie; Hao, Xiaojing; Huang, Haitao

    2016-04-06

    An electron transport layer is essential for effective operation of planar perovskite solar cells. In this Article, PW12-TiO2 composite was used as the electron transport layer for the planar perovskite solar cell in the device structure of fluorine-doped tin oxide (FTO)-glass/PW12-TiO2/perovskite/spiro-OMeTAD/Au. A proper downward shift of the conduction band minimum (CBM) enhanced electron extraction from the perovskite layer to the PW12-TiO2 composite layer. Consequently, the common hysteresis effect in TiO2-based planar perovskite solar cells was significantly reduced and the open circuit voltage was greatly increased to about 1.1 V. Perovskite solar cells using the PW12-TiO2 compact layer showed an efficiency of 15.45%. This work can contribute to the studies on the electron transport layer and interface engineering for the further development of perovskite solar cells.

  17. Solute transport through fractured rock: Radial diffusion into the rock matrix with several geological layers for an arbitrary length decay chain

    Science.gov (United States)

    Mahmoudzadeh, Batoul; Liu, Longcheng; Moreno, Luis; Neretnieks, Ivars

    2016-05-01

    The paper presents a model development to derive a semi-analytical solution to describe reactive solute transport through a single channel in a fracture with cylindrical geometry. The model accounts for advection through the channel, radial diffusion into the adjacent heterogeneous rock matrix comprising different geological layers, adsorption on both the channel surface, and the geological layers of the rock matrix and radioactive decay chain. Not only an arbitrary-length decay chain, but also as many number of the rock matrix layers with different properties as observed in the field can be handled. The solution, which is analytical in the Laplace domain, is transformed back to the time domain numerically e.g. by use of de Hoog algorithm. The solution is verified against experimental data and analytical solutions of limiting cases of solute transport through porous media. More importantly, the relative importance and contribution of different processes on solute transport retardation in fractured rocks are investigated by simulating several cases of varying complexity. The simulation results are compared with those obtained from rectangular model with linear matrix diffusion. It is found that the impact of channel geometry on breakthrough curves increases markedly as the transport distance along the flow channel and away into the rock matrix increase. The effect of geometry is more pronounced for transport of a decay chain when the rock matrix consists of a porous altered layer.

  18. Risk factors, health behaviors, and injury among adults employed in the transportation, warehousing, and utilities super sector.

    Science.gov (United States)

    Helmkamp, James C; Lincoln, Jennifer E; Sestito, John; Wood, Eric; Birdsey, Jan; Kiefer, Max

    2013-05-01

    The TWU super sector is engaged in the movement of passengers and cargo, warehousing of goods, and the delivery of services. The purpose of this study is to describe employee self-reported personal risk factors, health behaviors and habits, disease and chronic conditions, and employer-reported nonfatal injury experiences of workers in the TWU super sector. National Health Interview Survey (NHIS) data for 1997-2007, grouped into six morbidity and disability categories and three age groups, were reviewed. Demographic characteristics and prevalence estimates are reported for workers in the TWU super sector and the entire U.S. workforce, and compared with national adult population data from the NHIS. Bureau of Labor Statistics employer-reported TWU injury data from 2003 to 2007 was also reviewed. An average of 8.3 million workers were employed annually in the TWU super sector. TWU workers 65 or older reported the highest prevalence of hypertension (49%) across all industry sectors, but the 20% prevalence is notable among middle age workers (25-64). TWU workers had the highest prevalence of obesity (28%), compared to workers in all other industry sectors. Female TWU workers experienced the highest number of lost workdays (6.5) in the past year across all TWU demographic groups. Self-reported high proportions of chronic conditions including hypertension and heart disease combined with elevated levels of being overweight and obese, and lack of physical activity-particularly among TWUs oldest workers-can meaningfully inform wellness strategies and interventions focused on this demographic group. Am. J. Ind. Med. 56:556-568, 2013. © 2012 Wiley Periodicals, Inc. Copyright © 2012 Wiley Periodicals, Inc.

  19. Improved memory characteristics of charge trap memory by employing double layered ZrO2 nanocrystals and inserted Al2O3

    Science.gov (United States)

    Tang, Z. J.; Li, R.; Zhang, X. W.; Hu, D.; Zhao, Y. G.

    2016-07-01

    The charge trap memory capacitors incorporating a stacked charge trapping layer consisting of double layered ZrO2 nanocrystals (NCs) and inserted Al2O3 have been fabricated and investigated. It is observed that the memory capacitor with stacked trapping layer exhibits a hysteresis window as large as 14.3 V for ±10 V sweeping gate voltage range, faster program/erase speed, improved endurance performance, and good data retention characteristics with smaller extrapolated ten years charge loss at room temperature and 125 °C compared to single layered NCs. The special energy band alignment and the introduced additional traps of double layered ZrO2 NCs and inserted Al2O3 change the trapping and loss behavior of charges, and jointly contribute to the remarkable memory characteristics. Therefore, the memory capacitor with a stacked charge trapping layer is a promising candidate in future nonvolatile charge trap memory device design and application.

  20. Modeled transport of As (V) in the Nernst layer of an electro dialysis cell; Modelado del transporte de As (V) en la capa de Nernst de una celda electro dialitica

    Energy Technology Data Exchange (ETDEWEB)

    Ibanez, J. P.; Aracena, A.; Cifuentes, L.

    2012-11-01

    The transport of As (V) oxianions was modeled through the boundary layer generated between the bulk of an acidic As (V) electrolyte and the surface of an anionic exchange membrane during a batch electro dialysis process without agitation. The model was adapted from one developed for the transport of Cu (II) ions in the Nernst layer under the same hydrodynamic and electric conditions. The model shows the flux of oxianions in terms of the difference between the transport number of As (V) in the boundary layer and in the membrane as a function of the current density. The model approaches to the experimental data when the transport number in the boundary layer is 1.5 × 10-4 and 1.5 × 10{sup -}5 for As (V)-H{sub 2}SO{sub 4} and As (V)-Cu (II)-H{sub 2}SO{sub 4} electrolytes, respectively. The validation of the model was made with published data of As (V) transport. (Author)

  1. The Impact of Grain Alignment of the Electron Transporting Layer on the Performance of Inverted Bulk Heterojunction Solar Cells

    KAUST Repository

    Banavoth, Murali

    2015-08-13

    This report presents a new strategy for improving solar cell power conversion efficiencies (PCEs) through grain alignment and morphology control of the ZnO electron transport layer (ETL) prepared by radio frequency (RF) magnetron sputtering. The systematic control over the ETL\\'s grain alignment and thickness is shown, by varying the deposition pressure and operating substrate temperature during the deposition. Notably, a high PCE of 6.9%, short circuit current density (Jsc) of 12.8 mA cm-2, open circuit voltage (Voc) of 910 mV, and fill factor of 59% are demonstrated using the poly(benzo[1,2-b:4,5-b\\']dithiophene-thieno[3,4-c]pyrrole-4,6-dione):[6,6]-phenyl-C71-butyric acid methyl ester polymer blend with ETLs prepared at room temperature exhibiting oriented and aligned rod-like ZnO grains. Increasing the deposition temperature during the ZnO sputtering induces morphological cleavage of the rod-like ZnO grains and therefore reduced conductivity from 7.2 × 10-13 to ≈1.7 × 10-14 S m-1 and PCE from 6.9% to 4.28%. An investigation of the charge carrier dynamics by femtosecond (fs) transient absorption spectroscopy with broadband capability reveals clear evidence of faster carrier recombination for a ZnO layer deposited at higher temperature, which is consistent with the conductivity and device performance. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Edge transport studies in the edge and scrape-off layer of the National Spherical Torus Experiment with Langmuir probes

    Energy Technology Data Exchange (ETDEWEB)

    Boedo, J. A., E-mail: jboedo@ucsd.edu; Rudakov, D. L. [University of California San Diego, 9500 Gilman Dr., La Jolla, California 92093 (United States); Myra, J. R.; D' Ippolito, D. A. [Lodestar Research Corp, 2400 Central Ave., Boulder, Colorado 80301 (United States); Zweben, S.; Maingi, R.; Maqueda, R. J.; Bell, R.; Kugel, H.; Leblanc, B.; Roquemore, L. A. [Princeton University, PO Box 451, Princeton, New Jersey 08543 (United States); Soukhanovskii, V. A. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Ahn, J. W.; Canik, J. [Oak Ridge National Laboratory, PO Box 2008, Oak Ridge, Tennessee 37830 (United States); Crocker, N. [University of California Los Angeles, PO Box 957099, Los Angeles, California 90095 (United States)

    2014-04-15

    Transport and turbulence profiles were directly evaluated using probes for the first time in the edge and scrape-off layer (SOL) of NSTX [Ono et al., Nucl. Fusion 40, 557 (2000)] in low (L) and high (H) confinement, low power (P{sub in}∼ 1.3 MW), beam-heated, lower single-null discharges. Radial turbulent particle fluxes peak near the last closed flux surface (LCFS) at ≈4×10{sup 21} s{sup −1} in L-mode and are suppressed to ≈0.2×10{sup 21} s{sup −1} in H mode (80%–90% lower) mostly due to a reduction in density fluctuation amplitude and of the phase between density and radial velocity fluctuations. The radial particle fluxes are consistent with particle inventory based on SOLPS fluid modeling. A strong intermittent component is identified. Hot, dense plasma filaments 4–10 cm in diameter, appear first ∼2 cm inside the LCFS at a rate of ∼1×10{sup 21} s{sup −1} and leave that region with radial speeds of ∼3–5 km/s, decaying as they travel through the SOL, while voids travel inward toward the core. Profiles of normalized fluctuations feature levels of 10% inside LCFS to ∼150% at the LCFS and SOL. Once properly normalized, the intermittency in NSTX falls in similar electrostatic instability regimes as seen in other devices. The L-H transition causes a drop in the intermittent filaments velocity, amplitude and number in the SOL, resulting in reduced outward transport away from the edge and a less dense SOL.

  3. The Origin of the Terra Meridiani Sediments: Volatile Transport and the Formation of Sulfate Bearing Layered Deposits on Mars

    Science.gov (United States)

    Niles, P.B.

    2008-01-01

    formation process which must have acted over a large area of Mars. The results of this study suggest a mechanism for volatile transport on Mars without invoking an early greenhouse. They also imply a common formation mechanism for most of the sulfate minerals and layered deposits on Mars, which explains their common occurrence.

  4. Solution-processed MoO3:PEDOT:PSS hybrid hole transporting layer for inverted polymer solar cells.

    Science.gov (United States)

    Wang, Yiling; Luo, Qun; Wu, Na; Wang, Qiankun; Zhu, Hongfei; Chen, Liwei; Li, Yan-Qing; Luo, Liqiang; Ma, Chang-Qi

    2015-04-08

    Solution-processed organic-inorganic hybrids composing of MoO3 nanoparticles and PEDOT:PSS were developed for use in inverted organic solar cells as hole transporting layer (HTL). The hybrid MoO3:PEDOT:PSS inks were prepared by simply mixing PEDOT:PSS aqueous and MoO3 ethanol suspension together. A core-shell structure was proposed in the MoO3:PEDOT:PSS hybrid ink, where PEDOT chains act as the core and MoO3 nanoparticles connected with PSS chains act as the composite shell. The mixing with PEDOT:PSS suppressed the aggregation of MoO3 nanoparticles, which led to a smoother surface. In addition, since the hydrophilic PSS chains were passivated through preferentially connection with MoO3, the stronger adhesion between MoO3 nanoparticles and the photoactive layer improved the film forming ability of the MoO3:PEDOT:PSS hybrid ink. The MoO3:PEDOT:PSS hybrid HTL can therefore be feasibly deposited onto the hydrophobic photoactive polymer layer without any surface treatment. The use of the MoO3:PEDOT:PSS hybrid HTL resulted in the optimized P3HT:PC61BM- and PTB7:PC61BM-based inverted organic solar cells reaching highest power conversion efficiencies of 3.29% and 5.92%, respectively, which were comparable with that of the control devices using thermally evaporated MoO3 HTL (3.05% and 6.01%, respectively). Furthermore, less HTL thickness dependence of device performance was found for the hybrid HTL-based devices, which makes it more compatible with roll-to-roll printing process. In the end, influence of the blend ratio of MoO3 to PEDOT:PSS on photovoltaic performance and device stability was studied carefully, results indicated that the device performance would decrease with the increase of MoO3 blended ratio, whereas the long-term stability was improved.

  5. Fullerene-Based Electron Transport Layers for Semi-Transparent MAPbBr3 Perovskite Films in Planar Perovskite Solar Cells

    Directory of Open Access Journals (Sweden)

    Lung-Chien Chen

    2016-10-01

    Full Text Available In this study, four kinds of structures—[6,6]-phenyl-C61-butyric acid methyl ester (PCBM, PCBM/fullerene (C60, C60/bathocuproine (BCP, and PCBM/C60/BCP—were used as electron transport layers, and the structure, and optical and electronic behaviors of MAPbBr3 perovskite layers after annealing treatments were observed. The experimental results indicate that PCBM/C60 bi-layer structure is acceptable for MAPbBr3 planar perovskite solar cells due to electron step transporting. Low-temperature annealing is suitable for smooth and large grain MAPbBr3 films. The semi-transparent yellow C60/PCBM/MAPbBr3/PEDOT:PSS/ITO glass-structure solar cells exhibit the best performance with a power conversion efficiency of 4.19%. The solar cells are revealed to be suitable for application in building integrated photovoltaic (BIPV systems.

  6. Experimental and modeling study of the impact of vertical transport processes from the boundary-layer on the variability and the budget of tropospheric ozone

    International Nuclear Information System (INIS)

    Colette, A.

    2005-12-01

    Closing the tropospheric ozone budget requires a better understanding of the role of transport processes from the major reservoirs: the planetary boundary layer and the stratosphere. Case studies lead to the identification of mechanisms involved as well as their efficiency. However, their global impact on the budget must be addressed on a climatological basis. This manuscript is thus divided in two parts. First, we present case studies based on ozone LIDAR measurements performed during the ESCOMPTE campaign. This work consists in a data analysis investigation by means of a hybrid - Lagrangian study involving: global meteorological analyses, Lagrangian particle dispersion computation, and mesoscale, chemistry - transport, and Lagrangian photochemistry modeling. Our aim is to document the amount of observed ozone variability related to transport processes and, when appropriate, to infer the role of tropospheric photochemical production. Second, we propose a climatological analysis of the respective impact of transport from the boundary-layer and from the tropopause region on the tropospheric ozone budget. A multivariate analysis is presented and compared to a trajectography approach. Once validated, this algorithm is applied to the whole database of ozone profiles collected above Europe during the past 30 years in order to discuss the seasonal, geographical and temporal variability of transport processes as well as their impact on the tropospheric ozone budget. The variability of turbulent mixing and its impact on the persistence of tropospheric layers will also be discussed. (author)

  7. Novel nanostructured electron transport compact layer for efficient and large-area perovskite solar cells using acidic treatment of titanium layer

    Science.gov (United States)

    Ansari, Fatemeh; Nazari, Pariya; Payandeh, Masoud; Mardekatani Asl, Farzad; Abdollahi-Nejand, Bahram; Ahmadi, Vahid; Taghiloo, Jalal; Salavati-Niasari, Masoud

    2018-02-01

    A new method for the deposition of a pinhole-free compact layer of TiO2 is introduced for the development of efficient perovskite solar cells. Acidic treatment of titanium layer (ATTL), deposited by rotational magnetron sputtering, presents a compact pinhole-free TiO2 thin film. Deposition of a compact TiO2 thin film on fluorine-doped tin oxide layers by ATTL did not change the surface roughness. To compare the introduced method, perovskite solar cell devices were fabricated and studied using different methods for the deposition of the TiO2 compact layers, which were used as common compact layer deposition methods. The ATTL method proposed considerable photovoltaic enhancement of perovskite solar cell performance (at least 22% enhancement in this work) by reducing the pinholes and sheet resistance of the TiO2 thin film. The improvement in the open-circuit voltage and the fill factor of the prepared devices using the ATTL method strongly confirmed the nature of the deposited pinhole-free TiO2 thin film. This method is shown to be an appropriate route for the reliable large-scale deposition of TiO2 compact layers.

  8. Effect of fluorine plasma treatment with chemically reduced graphene oxide thin films as hole transport layer in organic solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Youn-Yeol; Kang, Byung Hyun; Lee, Yang Doo; Lee, Sang Bin; Ju, Byeong-Kwon, E-mail: bkju@korea.ac.kr

    2013-12-15

    The inorganic materials such as V{sub 2}O{sub 5}, MoO{sub 3} and WO{sub 3} were investigated to replace PEDOT:PSS as hole transport layer (HTL) in organic electronic devices such as organic solar cells (OSCs) and organic lighting emission diodes. However, these methods require vacuum techniques that are long time process and complex. Here, we report about plasma treatment with SF{sub 6} and CF{sub 4} using reactive ion etching on reduced graphene oxide (rGO) thin films that are obtained using an eco-friendly method with vitamin C. The plasma treated rGO thin films have dipoles since they consist of covalent bonds with fluorine on the surface of rGO. This means it is possible to increase the electrostatic potential energy than bare rGO. Increased potential energy on the surface of rGO films is worth applying organic electronic devices as HTL such as OSCs. Consequently, the power conversion efficiency of OSCs increased more than the rGO films without plasma treatment.

  9. Graphene as transparent conducting electrodes in organic photovoltaics: studies in graphene morphology, hole transporting layers, and counter electrodes.

    Science.gov (United States)

    Park, Hyesung; Brown, Patrick R; Bulović, Vladimir; Kong, Jing

    2012-01-11

    In this work, organic photovoltaics (OPV) with graphene electrodes are constructed where the effect of graphene morphology, hole transporting layers (HTL), and counter electrodes are presented. Instead of the conventional poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) PEDOT:PSS HTL, an alternative transition metal oxide HTL (molybdenum oxide (MoO(3))) is investigated to address the issue of surface immiscibility between graphene and PEDOT:PSS. Graphene films considered here are synthesized via low-pressure chemical vapor deposition (LPCVD) using a copper catalyst and experimental issues concerning the transfer of synthesized graphene onto the substrates of OPV are discussed. The morphology of the graphene electrode and HTL wettability on the graphene surface are shown to play important roles in the successful integration of graphene films into the OPV devices. The effect of various cathodes on the device performance is also studied. These factors (i.e., suitable HTL, graphene surface morphology and residues, and the choice of well-matching counter electrodes) will provide better understanding in utilizing graphene films as transparent conducting electrodes in future solar cell applications. © 2011 American Chemical Society

  10. Formation of edge transport barrier in the ergodic field layer of helical divertor configuration on the Large Helical Device

    International Nuclear Information System (INIS)

    Toi, K; Ohdachi, S; Watanabe, F; Narihara, K; Morisaki, T; Sakakibara, S; Morita, S; Goto, M; Ida, K; Masuzaki, S; Miyazawa, K; Tanaka, K; Tokuzawa, T; Watanabe, K W; Yoshinuma, M

    2006-01-01

    On the Large Helical Device (LHD), low to high confinement (L-H) transition and edge transport barrier (ETB) formation were observed in the low beta regime ((β dia ) dia ): volume-averaged beta derived from diamagnetic measurement) as well as in relatively high beta regime (>1.5%). In most of ETB plasmas electron density preferentially increases in the edge region without a substantial rise of the edge electron temperature. The ETB zone develops inside the ergodic field layer calculated in the vacuum field. The ETB formation strongly destabilizes edge coherent modes such as m/n = 2/3 or 1/2 (m, n: poloidal and toroidal mode numbers), because the plasma edge region is in the magnetic hill. The ETB is partially destroyed by the combination of these edge MHD modes and ELM-like activities. For a particular experimental condition, the forced generation of a sizable m/n = 1/1 magnetic island near the edge by application of external field perturbations facilitates the L-H transition at a lower electron density and suppresses edge MHD modes and ELM-like activities to lower levels

  11. Spontaneously formed high-performance charge-transport layers of organic single-crystal semiconductors on precisely synthesized insulating polymers

    Science.gov (United States)

    Makita, Tatsuyuki; Sasaki, Masayuki; Annaka, Tatsuro; Sasaki, Mari; Matsui, Hiroyuki; Mitsui, Chikahiko; Kumagai, Shohei; Watanabe, Shun; Hayakawa, Teruaki; Okamoto, Toshihiro; Takeya, Jun

    2017-04-01

    Charge-transporting semiconductor layers with high carrier mobility and low trap-density, desired for high-performance organic transistors, are spontaneously formed as a result of thermodynamic phase separation from a blend of π-conjugated small molecules and precisely synthesized insulating polymers dissolved in an aromatic solvent. A crystal film grows continuously to the size of centimeters, with the critical conditions of temperature, concentrations, and atmosphere. It turns out that the molecular weight of the insulating polymers plays an essential role in stable film growth and interfacial homogeneity at the phase separation boundary. Fabricating the transistor devices directly at the semiconductor-insulator boundaries, we demonstrate that the mixture of 3,11-didecyldinaphtho[2,3-d:2',3'-d']benzo[1,2-b:4,5-b']dithiophene and poly(methyl methacrylate) with the optimized weight-average molecular weight shows excellent device performances. The spontaneous phase separation with a one-step fabrication process leads to a high mobility up to 10 cm2 V-1 s-1 and a low subthreshold swing of 0.25 V dec-1 even without any surface treatment such as self-assembled monolayer modifications on oxide gate insulators.

  12. Enhanced photovoltaic performance of inverted hybrid bulk-heterojunction solar cells using TiO2/reduced graphene oxide films as electron transport layers

    Science.gov (United States)

    Morais, Andreia; Alves, João Paulo C.; Lima, Francisco Anderson S.; Lira-Cantu, Monica; Nogueira, Ana Flavia

    2015-01-01

    In this study, we investigated inverted hybrid bulk-heterojunction solar cells with the following configuration: fluorine-doped tin oxide (FTO) |TiO2/RGO|P3HT:PC61BM|V2O5 or PEDOT:PSS|Ag. The TiO2/GO dispersions were prepared by sol-gel method, employing titanium isopropoxide and graphene oxide (GO) as starting materials. The GO concentration was varied from 0.1 to 4.0 wt%. The corresponding dispersions were spin-coated onto FTO substrates and a thermal treatment was performed to remove organic materials and to reduce GO to reduced graphene oxide (RGO). The TiO2/RGO films were characterized by x-ray diffraction, Raman spectroscopy, and microscopy techniques. Atomic force microscopy (AFM) images showed that the addition of RGO significantly changes the morphology of the TiO2 films, with loss of uniformity and increase in surface roughness. Independent of the use of V2O5 or PEDOT: PSS films as the hole transport layer, the incorporation of 2.0 wt% of RGO into TiO2 films was the optimal concentration for the best organic photovoltaic performance. The solar cells based on TiO2/RGO (2.0 wt%) electrode exhibited a ˜22.3% and ˜28.9% short circuit current density (Jsc) and a power conversion efficiency enhancement, respectively, if compared with the devices based on pure TiO2 films. Kelvin probe force microscopy images suggest that the incorporation of RGO into TiO2 films can promote the appearance of regions with different charge dissipation capacities.

  13. Transport Asymmetry of Novel Bi-Layer Hybrid Perfluorinated Membranes on the Base of MF-4SC Modified by Halloysite Nanotubes with Platinum

    Directory of Open Access Journals (Sweden)

    Anatoly Filippov

    2018-03-01

    Full Text Available Three types of bi-layer hybrid nanocomposites on the base of perfluorinated cation-exchange membrane MF-4SC (Russian analogue of Nafion®-117 were synthesized and characterized. It was found that two membranes possess the noticeable asymmetry of the current–voltage curve (CVC under changing their orientation towards the applied electric field, despite the absence of asymmetry of diffusion permeability. These phenomena were explained in the frame of the “fine-porous model” expanded for bi-layer membranes. A special procedure to calculate the real values of the diffusion layers thickness and the limiting current density was proposed. Due to asymmetry effects of the current voltage curves of bi-layer hybrid membranes on the base of MF-4SC, halloysite nanotubes and platinum nanoparticles, it is prospective to assemble membrane switches (membrane relays or diodes with predictable transport properties, founded upon the theory developed here.

  14. A comparative study on the performance of hybrid solar cells containing ZnSTe QDs in hole transporting layer and photoactive layer

    Energy Technology Data Exchange (ETDEWEB)

    Najeeb, Mansoor Ani [Qatar University, Center for Advanced Materials (CAM) (Qatar); Abdullah, Shahino Mah; Aziz, Fakhra [University of Malaya, Low Dimensional Materials Research Centre (LDMRC), Department of Physics, Faculty of Science (Malaysia); Ahmad, Zubair, E-mail: zubairtarar@qu.edu.qa; Shakoor, R. A. [Qatar University, Center for Advanced Materials (CAM) (Qatar); Mohamed, A. M. A. [Suez University, Department of Metallurgical and Materials Engineering, Faculty of Petroleum and Mining Engineering (Egypt); Khalil, Uzma [University of Peshawar, Department of Electronics, Jinnah College for Women (Pakistan); Swelm, Wageh; Al-Ghamdi, Ahmed A. [King Abdulaziz University, Department of Physics, Faculty of Science (Saudi Arabia); Sulaiman, Khaulah [University of Malaya, Low Dimensional Materials Research Centre (LDMRC), Department of Physics, Faculty of Science (Malaysia)

    2016-12-15

    In this paper, ZnSTe quantum dots-based hybrid solar cells (HSC) with two different device architectures have been investigated. The improved performance of the poly(3-hexylthiophene) (P3HT) and [6,6]phenyl C{sub 71} butyric acid methyl ester (PC{sub 71}BM)-based bulk heterojunction (BHJ) solar cells by the incorporation of ZnSTe quantum dots (QDs) with an average size of 2.96 nm in PEDOT:PSS layer and active layer that have been demonstrated. Although the efficiency of both types of devices is almost the same, a close comparison reveals different reasons behind their improved performance. The device prepared with QDs in the HTL has shown reduced series resistance, increased shunt resistance, and improved mobility. On the other hand, QDs in the photoactive layer demonstrates increased photo-generation leading to improved efficiency.

  15. Efficient hole-transporting layer MoO{sub 3}:CuI deposited by co-evaporation in organic photovoltaic cells

    Energy Technology Data Exchange (ETDEWEB)

    Barkat, L.; Khelil, A. [Universite d' Oran 1 - Ahmed Ben Bella, LPCM2E, Oran (Algeria); Hssein, M. [Universite de Nantes, Institut des Materiaux Jean Rouxel (IMN), CNRS, UMR 6502, Nantes (France); Laboratoire Optoelectronique et Physico-chimie des Materiaux, Universite Ibn Tofail, Faculte des Sciences, Kenitra (Morocco); El Jouad, Z. [Laboratoire Optoelectronique et Physico-chimie des Materiaux, Universite Ibn Tofail, Faculte des Sciences, Kenitra (Morocco); Universite de Nantes, MOLTECH-Anjou, CNRS, UMR 6200, Nantes (France); Cattin, L.; Louarn, G.; Stephant, N. [Universite de Nantes, Institut des Materiaux Jean Rouxel (IMN), CNRS, UMR 6502, Nantes (France); Ghamnia, M. [Universite d' Oran 1 - Ahmed Ben Bella, Laboratoire des Sciences de la Matiere Condensee (LSMC), Oran (Algeria); Addou, M. [Laboratoire Optoelectronique et Physico-chimie des Materiaux, Universite Ibn Tofail, Faculte des Sciences, Kenitra (Morocco); Morsli, M. [Universite de Nantes, Faculte des Sciences et des Techniques, Nantes (France); Bernede, J.C. [Universite de Nantes, MOLTECH-Anjou, CNRS, UMR 6200, Nantes (France)

    2017-01-15

    In order to improve hole collection at the interface anode/electron donor in organic photovoltaic cells, it is necessary to insert a hole-transporting layer. CuI was shown to be a very efficient hole-transporting layer. However, its tendency to be quite rough tends to induce leakage currents and it is necessary to use a very slow deposition rate for CuI to avoid such negative effect. Herein, we show that the co-deposition of MoO{sub 3} and CuI avoids this difficulty and allows deposition of a homogeneous efficient hole-collecting layer at an acceptable deposition rate. Via an XPS study, we show that blending MoO{sub 3}:CuI improves the hole collection efficiency through an increase of the gap state density. This increase is due to the formation of Mo{sup 5+} following interaction between MoO{sub 3} and CuI. Not only does the co-evaporation process allow for decreasing significantly the deposition time of the hole-transporting layer, but also it increases the efficiency of the device based on the planar heterojunction, CuPc/C{sub 60}. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  16. Characterization of Organic Thin Film Solar Cells of PCDTBT : PC71BM Prepared by Different Mixing Ratio and Effect of Hole Transport Layer

    Directory of Open Access Journals (Sweden)

    Vijay Srinivasan Murugesan

    2015-01-01

    Full Text Available The organic thin film solar cells (OTFSCs have been successfully fabricated using PCDTBT : PC71BM with different mixing ratios (1 : 1 to 1 : 8 and the influence of hole transport layer thickness (PEDOT : PSS. The active layers with different mixing ratios of PCDTBT : PC71BM have been fabricated using o-dichlorobenzene (o-DCB. The surface morphology of the active layers and PEDOT : PSS layer with different thicknesses were characterized by AFM analysis. Here, we report that the OTFSCs with high performance have been optimized with 1 : 4 ratios of PCDTBT : PC71BM. The power conversion efficiency (PCE = 5.17% of the solar cells was significantly improved by changing thickness of PEDOT : PSS layer. The thickness of the PEDOT : PSS layer was found to be of significant importance; the thickness of the PEDOT : PSS layer at 45 nm (higher spin speed 5000 rpm shows higher short circuit current density (Jsc and lower series resistance (Rs and higher PCE.

  17. Bottom Boundary Layer Sediment Transport Processes in Fourleague Bay of Louisiana and Their Implication to Sediment Diversion and Coastal Restoration

    Science.gov (United States)

    Wang, J.; Xu, K.; Bentley, S. J.; Restreppo, G. A.

    2016-02-01

    Building land with a rising sea is a challenging problem in many major deltaic systems around the world. The Atchafalaya deltaic area is one of only a few growing sites in Louisiana coast. The sediment delivered to this deltaic area is mainly from three reservoirs: (1) sediment derived from ongoing fluvial delivery; (2) mobile sediment delivered to the coastal basin during the past year by cold fronts, tropical cyclones, and others; (3) more consolidated sediment stored in the seabed or bay floor for more than 12 months. In order to better understand the far-field dispersal and deposition of fine sediments in the Atchafalaya system, two tripods were used to study the hydrodynamics and sediment dynamics at two stations in Fourleague Bay, which are 15 km southeast of Atchafalaya Delta. One tripod was located at the middle of the bay, and the other was near the marsh edge. Six sensors including OBS (Optical Backscatter Sensor) 3A, OBS 5+, ADV (Acoustic Doppler Velocimeter) Ocean, Argonaut ADV, and two wave gauges were planned to deploy in the early summer and winter of 2015 for a month, respectively. Our study was focused on the near-bed sediment transport from each of the above three reservoirs to wetlands under fair weather and event condition. Based on the seasonal surface suspended sediment concentration (SSC), salinity, as well as turbidity, wave and current data, we have investigated the bottom boundary layer sediment dynamics, in order to illustrate sediment deposition and erosion processes under fair weather and energetic conditions in the bay. During an energetic event in early summer 2015, strong southeasterly wind waves carried salty water from inner Louisiana shelf northwestward into the bay, and led to increasing wave height, bottom shear stress, salinity, and near-bed turbidity. After the event, there was apparent decreasing of these parameters. SSC data in the bay showed an increasing trend since April, which is probably related to the fine sediment

  18. Study of Electrical Transport Properties of Thin Films Used as HTL and as Active Layer in Organic Solar Cells, through Impedance Spectroscopy Measurements

    Directory of Open Access Journals (Sweden)

    Camilo A. Otalora

    2016-01-01

    Full Text Available Impedance spectroscopy (IS is used for studying the electrical transport properties of thin films used in organic solar cells with structure ITO/HTL/active layer/cathode, where PEDOT:PSS (poly(3,4-ethylenedioxythiophene:polystyrene sulfonic acid and CuPC (tetrasulfonated copper-phthalocyanine were investigated as HTL (hole transport layer and P3HT:PCBM (poly-3-hexylthiophene:phenyl-C61-butyric acid methyl ester blends prepared from mesitylene and chlorobenzene based solutions were studied as active layer and Ag and Al were used as cathode. The study allowed determining the influence of the type of solvent used for the preparation of the active layer as well as the speed at which the solvents are removed on the carriers mobility. The effect of exposing the layer of P3HT to the air on its mobility was also studied. It was established that samples of P3HT and P3HT:PCBM prepared using mesitylene as a solvent have mobility values significantly higher than those prepared from chlorobenzene which is the solvent most frequently used. It was also determined that the mobility of carriers in P3HT films strongly decreases when this sample is exposed to air. In addition, it was found that the electrical properties of P3HT:PCBM thin films can be improved by removing the solvent slowly which is achieved by increasing the pressure inside the system of spin-coating during the film growth.

  19. Amorphous Tin Oxide as a Low-Temperature-Processed Electron-Transport Layer for Organic and Hybrid Perovskite Solar Cells

    KAUST Repository

    Barbe, Jeremy

    2017-02-08

    Chemical bath deposition (CBD) of tin oxide (SnO) thin films as an electron-transport layer (ETL) in a planar-heterojunction n-i-p organohalide lead perovskite and organic bulk-heterojunction (BHJ) solar cells is reported. The amorphous SnO (a-SnO) films are grown from a nontoxic aqueous bath of tin chloride at a very low temperature (55 °C) and do not require postannealing treatment to work very effectively as an ETL in a planar-heterojunction n-i-p organohalide lead perovskite or organic BHJ solar cells, in lieu of the commonly used ETL materials titanium oxide (TiO) and zinc oxide (ZnO), respectively. Ultraviolet photoelectron spectroscopy measurements on the glass/indium-tin oxide (ITO)/SnO/methylammonium lead iodide (MAPbI)/2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenylamine)-9,9′-spirobifluorene device stack indicate that extraction of photogenerated electrons is facilitated by a perfect alignment of the conduction bands at the SnO/MAPbI interface, while the deep valence band of SnO ensures strong hole-blocking properties. Despite exhibiting very low electron mobility, the excellent interfacial energetics combined with high transparency (E > 4 eV) and uniform substrate coverage make the a-SnO ETL prepared by CBD an excellent candidate for the potentially low-cost and large-scale fabrication of organohalide lead perovskite and organic photovoltaics.

  20. Amorphous Tin Oxide as a Low-Temperature-Processed Electron-Transport Layer for Organic and Hybrid Perovskite Solar Cells.

    Science.gov (United States)

    Barbé, Jérémy; Tietze, Max L; Neophytou, Marios; Murali, Banavoth; Alarousu, Erkki; Labban, Abdulrahman El; Abulikemu, Mutalifu; Yue, Wan; Mohammed, Omar F; McCulloch, Iain; Amassian, Aram; Del Gobbo, Silvano

    2017-04-05

    Chemical bath deposition (CBD) of tin oxide (SnO 2 ) thin films as an electron-transport layer (ETL) in a planar-heterojunction n-i-p organohalide lead perovskite and organic bulk-heterojunction (BHJ) solar cells is reported. The amorphous SnO 2 (a-SnO 2 ) films are grown from a nontoxic aqueous bath of tin chloride at a very low temperature (55 °C) and do not require postannealing treatment to work very effectively as an ETL in a planar-heterojunction n-i-p organohalide lead perovskite or organic BHJ solar cells, in lieu of the commonly used ETL materials titanium oxide (TiO 2 ) and zinc oxide (ZnO), respectively. Ultraviolet photoelectron spectroscopy measurements on the glass/indium-tin oxide (ITO)/SnO 2 /methylammonium lead iodide (MAPbI 3 )/2,2',7,7'-tetrakis(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene device stack indicate that extraction of photogenerated electrons is facilitated by a perfect alignment of the conduction bands at the SnO 2 /MAPbI 3 interface, while the deep valence band of SnO 2 ensures strong hole-blocking properties. Despite exhibiting very low electron mobility, the excellent interfacial energetics combined with high transparency (E gap,optical > 4 eV) and uniform substrate coverage make the a-SnO 2 ETL prepared by CBD an excellent candidate for the potentially low-cost and large-scale fabrication of organohalide lead perovskite and organic photovoltaics.

  1. Transportation

    International Nuclear Information System (INIS)

    Anon.

    1998-01-01

    Here is the decree of the thirtieth of July 1998 relative to road transportation, to trade and brokerage of wastes. It requires to firms which carry out a road transportation as well as to traders and to brokers of wastes to declare their operations to the prefect. The declaration has to be renewed every five years. (O.M.)

  2. Transportation

    Data.gov (United States)

    Earth Data Analysis Center, University of New Mexico — The National Flood Hazard Layer (NFHL) data incorporates all Digital Flood Insurance Rate Map(DFIRM) databases published by FEMA, and any Letters Of Map Revision...

  3. Flexible ITO-free organic solar cells applying aqueous solution-processed V2O5 hole transport layer: An outdoor stability study

    Directory of Open Access Journals (Sweden)

    F. Anderson S. Lima

    2016-02-01

    Full Text Available Solution processable semiconductor oxides have opened a new paradigm for the enhancement of the lifetime of thin film solar cells. Their fabrication by low-cost and environmentally friendly solution-processable methods makes them ideal barrier (hole and electron transport layers. In this work, we fabricate flexible ITO-free organic solar cells (OPV by printing methods applying an aqueous solution-processed V2O5 as the hole transport layer (HTL and compared them to devices applying PEDOT:PSS. The transparent conducting electrode was PET/Ag/PEDOT/ZnO, and the OPV configuration was PET/Ag/PEDOT/ZnO/P3HT:PC60BM/HTL/Ag. Outdoor stability analyses carried out for more than 900 h revealed higher stability for devices fabricated with the aqueous solution-processed V2O5.

  4. Transport phenomena in quantum wells and wires in presence of disorder and interactions

    OpenAIRE

    Vettchinkina, Valeria

    2012-01-01

    Present-day electronics employ circuits of smaller and smaller dimensions, and today the length scales are so small that the laws of physics which rule micro-cosmos, quantum mechanics, become directly important. This thesis reports on theoretical work on electron transport in different nanostructures. We have studied semiconductor quantum wells, layered materials where each layer can be only a few atomic layers thick, and transport in thin atomic wires. The layered materials have been stud...

  5. Modelling and sequential simulation of multi-tubular metallic membrane and techno-economics of a hydrogen production process employing thin-layer membrane reactor

    KAUST Repository

    Shafiee, Alireza

    2016-09-24

    A theoretical model for multi-tubular palladium-based membrane is proposed in this paper and validated against experimental data for two different sized membrane modules that operate at high temperatures. The model is used in a sequential simulation format to describe and analyse pure hydrogen and hydrogen binary mixture separations, and then extended to simulate an industrial scale membrane unit. This model is used as a sub-routine within an ASPEN Plus model to simulate a membrane reactor in a steam reforming hydrogen production plant. A techno-economic analysis is then conducted using the validated model for a plant producing 300 TPD of hydrogen. The plant utilises a thin (2.5 μm) defect-free and selective layer (Pd75Ag25 alloy) membrane reactor. The economic sensitivity analysis results show usefulness in finding the optimum operating condition that achieves minimum hydrogen production cost at break-even point. A hydrogen production cost of 1.98 $/kg is estimated while the cost of the thin-layer selective membrane is found to constitute 29% of total process capital cost. These results indicate the competiveness of this thin-layer membrane process against conventional methods of hydrogen production. © 2016 Hydrogen Energy Publications LLC

  6. Carrier transport in flexible organic bistable devices of ZnO nanoparticles embedded in an insulating poly(methyl methacrylate) polymer layer

    International Nuclear Information System (INIS)

    Son, Dong-Ick; Park, Dong-Hee; Choi, Won Kook; Cho, Sung-Hwan; Kim, Won-Tae; Kim, Tae Whan

    2009-01-01

    The bistable effects of ZnO nanoparticles embedded in an insulating poly(methyl methacrylate) (PMMA) polymer single layer by using flexible polyethylene terephthalate (PET) substrates were investigated. Transmission electron microscopy (TEM) images revealed that ZnO nanoparticles were formed inside the PMMA polymer layer. Current-voltage (I-V) measurement on the Al/ZnO nanoparticles embedded in an insulating PMMA polymer layer/ITO/PET structures at 300 K showed a nonvolatile electrical bistability behavior with a flat-band voltage shift due to the existence of the ZnO nanoparticles, indicative of trapping, storing, and emission of charges in the electronic states of the ZnO nanoparticles. The carrier transport mechanism of the bistable behavior for the fabricated organic bistable device (OBD) structures is described on the basis of the I-V results by analyzing the effect of space charge.

  7. A Surface-Layer Study of the Transport and Dissipation of Turbulent Kinetic Energy and the Variances of Temperature, Humidity and CO_2

    Science.gov (United States)

    Hackerott, João A.; Bakhoday Paskyabi, Mostafa; Reuder, Joachim; de Oliveira, Amauri P.; Kral, Stephan T.; Marques Filho, Edson P.; Mesquita, Michel dos Santos; de Camargo, Ricardo

    2017-11-01

    We discuss scalar similarities and dissimilarities based on analysis of the dissipation terms in the variance budget equations, considering the turbulent kinetic energy and the variances of temperature, specific humidity and specific CO_2 content. For this purpose, 124 high-frequency sampled segments are selected from the Boundary Layer Late Afternoon and Sunset Turbulence experiment. The consequences of dissipation similarity in the variance transport are also discussed and quantified. The results show that, for the convective atmospheric surface layer, the non-dimensional dissipation terms can be expressed in the framework of Monin-Obukhov similarity theory and are independent of whether the variable is temperature or moisture. The scalar similarity in the dissipation term implies that the characteristic scales of the atmospheric surface layer can be estimated from the respective rate of variance dissipation, the characteristic scale of temperature, and the dissipation rate of temperature variance.

  8. Enhanced charge collection with ultrathin AlOx electron blocking layer for hole-transporting material-free perovskite solar cell.

    Science.gov (United States)

    Wei, Huiyun; Shi, Jiangjian; Xu, Xin; Xiao, Junyan; Luo, Jianheng; Dong, Juan; Lv, Songtao; Zhu, Lifeng; Wu, Huijue; Li, Dongmei; Luo, Yanhong; Meng, Qingbo; Chen, Qiang

    2015-02-21

    An ultrathin AlOx layer has been deposited onto a CH3NH3PbI3 film using atomic layer deposition technology, to construct a metal-insulator-semiconductor (MIS) back contact for the hole-transporting material-free perovskite solar cell. By optimization of the ALD deposition cycles, the average power conversion efficiency (PCE) of the cell has been enhanced from 8.61% to 10.07% with a highest PCE of 11.10%. It is revealed that the improvement in cell performance with this MIS back contact is mainly attributed to the enhancement in charge collection resulting from the electron blocking effect of the AlOx layer.

  9. Seasonal Ozone Variations in the Isentropic Layer between 330 and 380 K as Observed by SAGE 2: Implications of Extratropical Cross-Tropopause Transport

    Science.gov (United States)

    Wang, Pi-Huan; Cunnold, Derek M.; Zawodny, Joseph M.; Pierce, R. Bradley; Olson, Jennifer R.; Kent, Geoffrey S.; Skeens, Kristi, M.

    1998-01-01

    To provide observational evidence on the extratropical cross-tropopause transport between the stratosphere and the troposphere via quasi-isentropic processes in the middleworld (the part of the atmosphere in which the isentropic surfaces intersect the tropopause), this report presents an analysis of the seasonal variations of the ozone latitudinal distribution in the isentropic layer between 330 K and 380 K based on the measurements from the Stratospheric Aerosol and Gas Experiment (SAGE) II. The results from SAGE II data analysis are consistent with (1) the buildup of ozone-rich air in the extratropical middleworld through the large-scale descending mass circulation during winter, (2) the spread of ozone-rich air in the isentropic layer from midlatitudes to subtropics via quasi-isentropic transport during spring, (3) significant photochemical ozone removal and the absence of an ozone-rich supply of air to the layer during summer, and (4) air mass exchange between the subtropics and the extratropics during the summer monsoon period. Thus the SAGE II observed ozone seasonal variations in the middleworld are consistent with the existing model calculated annual cycle of the diabatic circulation as well as the conceptual role of the eddy quasi-adiabatic transport in the stratosphere-troposphere exchange reported in the literature.

  10. The Effect of Post-Baking Temperature and Thickness of ZnO Electron Transport Layers for Efficient Planar Heterojunction Organometal-Trihalide Perovskite Solar Cells

    Directory of Open Access Journals (Sweden)

    Kun-Mu Lee

    2017-11-01

    Full Text Available Solution-processed zinc oxide (ZnO-based planar heterojunction perovskite photovoltaic device is reported in this study. The photovoltaic device benefits from the ZnO film as a high-conductivity and high-transparent electron transport layer. The optimal electron transport layer thickness and post-baking temperature for ZnO are systematically studied by scanning electron microscopy, photoluminescence and time-resolved photoluminescence spectroscopy, and X-ray diffraction. Optimized perovskite solar cells (PSCs show an open-circuit voltage, a short-circuit current density, and a fill factor of 1.04 V, 18.71 mA/cm2, and 70.2%, respectively. The highest power conversion efficiency of 13.66% was obtained when the device was prepared with a ZnO electron transport layer with a thickness of ~20 nm and when post-baking at 180 °C for 30 min. Finally, the stability of the highest performance ZnO-based PSCs without encapsulation was investigated in detail.

  11. Transportation

    National Research Council Canada - National Science Library

    Allshouse, Michael; Armstrong, Frederick Henry; Burns, Stephen; Courts, Michael; Denn, Douglas; Fortunato, Paul; Gettings, Daniel; Hansen, David; Hoffman, Douglas; Jones, Robert

    2007-01-01

    .... The ability of the global transportation industry to rapidly move passengers and products from one corner of the globe to another continues to amaze even those wise to the dynamics of such operations...

  12. Spatial and thickness dependence of coupling interaction of surface states and influence on transport and optical properties of few-layer Bi2Se3

    Science.gov (United States)

    Li, Zhongjun; Chen, Shi; Sun, Jiuyu; Li, Xingxing; Qiu, Huaili; Yang, Jinlong

    2018-02-01

    Coupling interaction between the bottom and top surface electronic states and the influence on transport and optical properties of Bi2Se3 thin films with 1–8 quintuple layers (QLs) have been investigated by first principles calculations. Obvious spatial and thickness dependences of coupling interaction are found by analyzing hybridization of two surface states. In the thin film with a certain thickness, from the outer to inner atomic layers, the coupling interaction exhibits an increasing trend. On the other hand, as thickness increases, the coupling interaction shows a disproportionate decrease trend. Moreover, the system with 3 QLs exhibits stronger interaction than that with 2 QLs. The presence of coupling interaction would suppress destructive interference of surface states and enhance resistance in various degrees. In view of the inversely proportional relation to transport channel width, the resistance of thin films should show disproportionate thickness dependence. This prediction is qualitatively consistent with the transport measurements at low temperature. Furthermore, the optical properties also exhibit obvious thickness dependence. Especially as the thickness increases, the coupling interaction results in red and blue shifts of the multiple-peak structures in low and high energy regions of imaginary dielectric function, respectively. The red shift trend is in agreement with the recent experimental observation and the blue shift is firstly predicted by the present calculation. The present results give a concrete understanding of transport and optical properties in devices based on Bi2Se3 thin films with few QLs.

  13. Efficient, Hysteresis-Free, and Stable Perovskite Solar Cells with ZnO as Electron-Transport Layer: Effect of Surface Passivation.

    Science.gov (United States)

    Cao, Jing; Wu, Binghui; Chen, Ruihao; Wu, Youyunqi; Hui, Yong; Mao, Bing-Wei; Zheng, Nanfeng

    2018-01-19

    The power conversion efficiency of perovskite solar cells (PSCs) has ascended from 3.8% to 22.1% in recent years. ZnO has been well-documented as an excellent electron-transport material. However, the poor chemical compatibility between ZnO and organo-metal halide perovskite makes it highly challenging to obtain highly efficient and stable PSCs using ZnO as the electron-transport layer. It is demonstrated in this work that the surface passivation of ZnO by a thin layer of MgO and protonated ethanolamine (EA) readily makes ZnO as a very promising electron-transporting material for creating hysteresis-free, efficient, and stable PSCs. Systematic studies in this work reveal several important roles of the modification: (i) MgO inhibits the interfacial charge recombination, and thus enhances cell performance and stability; (ii) the protonated EA promotes the effective electron transport from perovskite to ZnO, further fully eliminating PSCs hysteresis; (iii) the modification makes ZnO compatible with perovskite, nicely resolving the instability of ZnO/perovskite interface. With all these findings, PSCs with the best efficiency up to 21.1% and no hysteresis are successfully fabricated. PSCs stable in air for more than 300 h are achieved when graphene is used to further encapsulate the cells. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  14. Interfacial Engineering of Perovskite Solar Cells by Employing a Hydrophobic Copper Phthalocyanine Derivative as Hole-Transporting Material with Improved Performance and Stability.

    Science.gov (United States)

    Jiang, Xiaoqing; Yu, Ze; Lai, Jianbo; Zhang, Yuchen; Hu, Maowei; Lei, Ning; Wang, Dongping; Yang, Xichuan; Sun, Licheng

    2017-04-22

    In high-performance perovskite solar cells (PSCs), hole-transporting materials (HTMs) play an important role in extracting and transporting the photo-generated holes from the perovskite absorber to the cathode, thus reducing unwanted recombination losses and enhancing the photovoltaic performance. Herein, solution-processable tetra-4-(bis(4-tert-butylphenyl)amino)phenoxy-substituted copper phthalocyanine (CuPc-OTPAtBu) was synthesized and explored as a HTM in PSCs. The optical, electrochemical, and thermal properties were fully characterized for this organic metal complex. The photovoltaic performance of PSCs employing this CuPc derivative as a HTM was further investigated, in combination with a mixed-ion perovskite as a light absorber and a low-cost vacuum-free carbon as cathode. The optimized devices [doped with 6 % (w/w) tetrafluoro-tetracyano-quinodimethane (F4TCNQ)] showed a decent power conversion efficiency of 15.0 %, with an open-circuit voltage of 1.01 V, a short-circuit current density of 21.9 mA cm -2 , and a fill factor of 0.68. Notably, the PSC devices studied also exhibited excellent long-term durability under ambient condition for 720 h, mainly owing to the introduction of the hydrophobic HTM interlayer, which prevents moisture penetration into the perovskite film. The present work emphasizes that solution-processable CuPc holds a great promise as a class of alternative HTMs that can be further explored for efficient and stable PSCs in the future. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Ternary Oxides in the TiO2-ZnO System as Efficient Electron-Transport Layers for Perovskite Solar Cells with Efficiency over 15.

    Science.gov (United States)

    Yin, Xiong; Xu, Zhongzhong; Guo, Yanjun; Xu, Peng; He, Meng

    2016-11-02

    Perovskite solar cells, which utilize organometal-halide perovskites as light-harvesting materials, have attracted great attention due to their high power conversion efficiency (PCE) and potentially low cost in fabrication. A compact layer of TiO 2 or ZnO is generally applied as electron-transport layer (ETL) in a typical perovskite solar cell. In this study, we explored ternary oxides in the TiO 2 -ZnO system to find new materials for the ETL. Compact layers of titanium zinc oxides were readily prepared on the conducting substrate via spray pyrolysis method. The optical band gap, valence band maximum and conduction band minimum of the ternary oxides varied significantly with the ratio of Ti to Zn, surprisingly, in a nonmonotonic way. When a zinc-rich ternary oxide was applied as ETL for the device, a PCE of 15.10% was achieved, comparable to that of the device using conventional TiO 2 ETL. Interestingly, the perovskite layer deposited on the zinc-rich ternary oxide is stable, in sharp contrast with that fabricated on a ZnO layer, which will turn into PbI 2 readily when heated. These results indicate that potentially new materials with better performance can be found for ETL of perovskite solar cells in ternary oxides, which deserve more exploration.

  16. Polymer Solar Cells with Efficiency >10% Enabled via a Facile Solution-Processed Al-Doped ZnO Electron Transporting Layer

    KAUST Repository

    Jagadamma, Lethy Krishnan

    2015-04-22

    A facile and low-temperature (125 °C) solution-processed Al-doped ZnO (AZO) buffer layer functioning very effectively as electron accepting/hole blocking layer for a wide range of polymer:fullerene bulk heterojunction systems, yielding power conversion efficiency in excess of 10% (8%) on glass (plastic) substrates is described. The ammonia-treatment of the aqueous AZO nanoparticle solution produces compact, crystalline, and smooth thin films, which retain the aluminum doping, and eliminates/reduces the native defects by nitrogen incorporation, making them good electron transporters and energetically matched with the fullerene acceptor. It is demonstrated that highly efficient solar cells can be achieved without the need for additional surface chemical modifications of the buffer layer, which is a common requirement for many metal oxide buffer layers to yield efficient solar cells. Also highly efficient solar cells are achieved with thick AZO films (>50 nm), highlighting the suitability of this material for roll-to-roll coating. Preliminary results on the applicability of AZO as electron injection layer in F8BT-based polymer light emitting diode are also presented. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. Effects of Uniaxial and Biaxial Strain on Few-Layered Terrace Structures of MoS₂ Grown by Vapor Transport.

    Science.gov (United States)

    McCreary, Amber; Ghosh, Rudresh; Amani, Matin; Wang, Jin; Duerloo, Karel-Alexander N; Sharma, Ankit; Jarvis, Karalee; Reed, Evan J; Dongare, Avinash M; Banerjee, Sanjay K; Terrones, Mauricio; Namburu, Raju R; Dubey, Madan

    2016-03-22

    One of the most fascinating properties of molybdenum disulfide (MoS2) is its ability to be subjected to large amounts of strain without experiencing degradation. The potential of MoS2 mono- and few-layers in electronics, optoelectronics, and flexible devices requires the fundamental understanding of their properties as a function of strain. While previous reports have studied mechanically exfoliated flakes, tensile strain experiments on chemical vapor deposition (CVD)-grown few-layered MoS2 have not been examined hitherto, although CVD is a state of the art synthesis technique with clear potential for scale-up processes. In this report, we used CVD-grown terrace MoS2 layers to study how the number and size of the layers affected the physical properties under uniaxial and biaxial tensile strain. Interestingly, we observed significant shifts in both the Raman in-plane mode (as high as -5.2 cm(-1)) and photoluminescence (PL) energy (as high as -88 meV) for the few-layered MoS2 under ∼1.5% applied uniaxial tensile strain when compared to monolayers and few-layers of MoS2 studied previously. We also observed slippage between the layers which resulted in a hysteresis of the Raman and PL spectra during further applications of strain. Through DFT calculations, we contended that this random layer slippage was due to defects present in CVD-grown materials. This work demonstrates that CVD-grown few-layered MoS2 is a realistic, exciting material for tuning its properties under tensile strain.

  18. Polyethers containing 4-(carbazol-2-yl)-7-arylbenzo[c]-1,2,5-thiadiazole chromophores as solution processed materials for hole transporting layers of OLEDs

    Science.gov (United States)

    Krucaite, G.; Tavgeniene, D.; Xie, Z.; Lin, X.; Zhang, B.; Grigalevicius, S.

    2018-02-01

    Two polyethers containing electroactive pendent 4-(carbazol-2-yl)-7-arylbenzo[c]-1,2,5-thiadiazole moieties have been synthesized by the multi-step synthetic route. Full characterization of their structures is presented. The polymers represent derivatives of very high thermal stability with initial thermal degradation temperatures of 425 °C and 431 °C. Glass transition temperatures of the amorphous materials were also very high and reached values of 154 °C and 163 °C. The electron photoemission spectra of thin layers of the polymers showed ionization potentials of 5.84 eV and 5.93 eV. Hole-transporting properties of the polymeric materials were tested in the structures of organic light emitting diodes with Alq3 as the green emitter and electron transporting material. An electroluminescent device containing hole-transporting layer (HTL) of the polymer with electroactive 4-carbazolyl-7-phenylbenzo[c]-1,2,5-thiadiazole moieties exhibited turn on voltage of 6.2 V, maximum photometric efficiency of 2.5 cd/A and maximum brightness exceeding 300 cd/m2. The device containing HTL of the polymer with 4-carbazolyl-7-(1-naphtyl)benzo[c]-1,2,5-thiadiazole moieties demonstrated turn on voltage of 5.2 V, maximum photometric efficiency of 1.6 cd/A and maximum brightness exceeding 1500 cd/m2. The efficiencies were about 30-90% higher than that of the device containing widely used hole transporting layers of poly(9-vinylcarbazole).

  19. Controlling the transport of cations through permselective mesoporous alumina layers by manipulation of electric field and ionic strength

    NARCIS (Netherlands)

    Schmuhl, R.; Keizer, Klaas; van den Berg, Albert; ten Elshof, Johan E.; Blank, David H.A.

    2004-01-01

    The electric field-driven transport of ions through supported mesoporous γ-alumina membranes was investigated. The influence of ion concentration, ion valency, pH, ionic strength, and electrolyte composition on transport behavior was determined. The permselectivity of the membrane was found to be

  20. Single layer graphene electrodes for quantum dot-light emitting diodes

    Science.gov (United States)

    Yan, Long; Zhang, Yu; Zhang, Xiaoyu; Zhao, Jia; Wang, Yu; Zhang, Tieqiang; Jiang, Yongheng; Gao, Wenzhu; Yin, Jingzhi; Zhao, Jun; Yu, William W.

    2015-03-01

    Single layer graphene was employed as the electrode in quantum dot-light emitting diodes (QD-LEDs) to replace indium tin oxide (ITO). The graphene layer demonstrated low surface roughness, good hole injection ability, and proper work function matching with the poly (3,4-ethylenedioxythiophene):poly (styrenesulfonate) layer. Together with the hole transport layer and electron transport layer, the fabricated QD-LED showed good current efficiency and power efficiency, which were even higher than an ITO-based similar device under low current density. The result indicates that graphene can be used as anodes to replace ITO in QD-LEDs.

  1. STRUCTURE, ELECTRICAL TRANSPORT AND MAGNETIC-PROPERTIES OF THE MISFIT LAYER COMPOUND (SMS)1.19TAS2 SMTAS3

    NARCIS (Netherlands)

    WIEGERS, GA; MEETSMA, A; HAANGE, RJ; DEBOER, JL

    Single-crystal X-ray diffraction has shown that (SmS)1.19 TaS2 is a misfit layer compound built alternately of double layers of SmS, an approximately {100} slice of NaCl-type SmS and sandwiches of TaS2 with tantalum in slightly distorted trigonal prisms of sulfur. The two structural units are both

  2. Observations of transitional tidal boundary layers and their impact on sediment transport in the Great Bay, NH

    Science.gov (United States)

    Koetje, K. M.; Foster, D. L.; Lippmann, T. C.

    2017-12-01

    Observations of the vertical structure of tidal flows obtained in 2016 and 2017 in the Great Bay Estuary, NH show evidence of transitional tidal boundary layers at deployment locations on shallow mudflats. High-resolution bottom boundary layer currents, hydrography, turbidity, and bed characteristics were observed with an acoustic Doppler current profiler (ADCP), an acoustic Doppler velocimeter (ADV), conductivity-depth-temperature (CTD) sensors, optical backscatter sensors, multibeam bathymetric surveys, and sediment grab samples and cores. Over the 2.5 m tidal range and at water depths ranging from 0.3 m to 1.5 m at mean lower low water, peak flows ranged from 10 cm/s to 30 cm/s and were primarily driven by the tides. A downward-looking ADCP captured the velocity profile over the lowest 1 m of the water column. Results consistently show a dual-log layer system, with evidence of a lower layer within 15 cm of the bed, another layer above approximately 30 cm from the bed, and a transitional region where the flow field rotates between that the two layers that can be as much as 180 degrees out of phase. CTD casts collected over a complete tidal cycle suggest that the weak thermohaline stratification is not responsible for development of the two layers. On the other hand, acoustic and optical backscatter measurements show spatial and temporal variability in suspended sediments that are dependant on tidal phase. Current work includes an examination of the relationship between sediment concentrations in the water column and velocity profile characteristics, along with an effort to quantify the impact of rotation and dual-log layers on bed stress.

  3. Magneto-transport in the zero-energy Landau level of single-layer and bilayer graphene

    International Nuclear Information System (INIS)

    Zeitler, U; Giesbers, A J M; Elferen, H J van; Kurganova, E V; McCollam, A; Maan, J C

    2011-01-01

    We present recent low-temperature magnetotransport experiments on single-layer and bilayer graphene in high magnetic field up to 33 T. In single layer graphene the fourfold degeneracy of the zero-energy Landau level is lifted by a gap opening at filling factor ν = 0. In bilayer graphene, we observe a partial lifting of the degeneracy of the eightfold degenerate zero-energy Landau level.

  4. Steering the Properties of MoOx Hole Transporting Layers in OPVs and OLEDs: Interface Morphology vs. Electronic Structure

    Directory of Open Access Journals (Sweden)

    Wouter Marchal

    2017-01-01

    Full Text Available The identification, fine‐tuning, and process optimization of appropriate hole transporting layers (HTLs for organic solar cells is indispensable for the production of efficient and sustainable functional devices. In this study, the optimization of a solution‐processed molybdenum oxide (MoOx layer fabricated from a combustion precursor is carried out via the introduction of zirconium and tin additives. The evaluation of the output characteristics of both organic photovoltaic (OPV and organic light emitting diode (OLED devices demonstrates the beneficial influence upon the addition of the Zr and Sn ions compared to the generic MoOx precursor. A dopant effect in which the heteroatoms and the molybdenum oxide form a chemical identity with fundamentally different structural properties could not be observed, as the additives do not affect the molybdenum oxide composition or electronic band structure. An improved surface roughness due to a reduced crystallinity was found to be a key parameter leading to the superior performance of the devices employing modified HTLs.

  5. Influence of dopant transport rate upon photoluminescence and electrical properties of phosphorus-doped ZnMgTe layers grown by MOVPE

    Energy Technology Data Exchange (ETDEWEB)

    Saito, K.; Guo, Q.X. [Synchrotron Light Application Center, Saga University, 1 Honjo, Saga 840-8502 (Japan); Saeki, T.; Tanaka, T.; Nishio, M. [Graduate School of Science and Engineering, Saga University, 1 Honjo, Saga 840-8502 (Japan)

    2012-08-15

    p-type doping of Zn{sub 1-x}Mg{sub x} Te has been investigated by metalorganic vapour phase epitaxy using tris-dimethylaminophosphorus as a dopant source. The photoluminescence (PL) and electrical properties of the as-grown and post-annealed layers have been clarified as a function of the dopant transport rate. In PL spectra at 4.2 K, the strong donor acceptor pair emission vanished and instead enhancement of P acceptor-related excitonic emission and/or appearance of free-to-bound emission were observed for all the layers by the post-annealing treatment. In accordance with the PL behavior, the hole concentration at room temperature of the annealed layers was significantly enhanced from 2 x 10{sup 15}{proportional_to}2 x 10{sup 16} cm{sup -3} to 5 x 10{sup 16}{proportional_to}2 x 10{sup 18} cm{sup -3} by a maximum factor of {proportional_to}600. The enhanced hole concentration shows saturation tendency with increasing dopant transport rate. (copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  6. Electron scattering in graphene by defects in underlying h-BN layer: First-principles transport calculations

    Science.gov (United States)

    Kaneko, Tomoaki; Ohno, Takahisa

    2018-03-01

    We investigate the electronic structure and the transport properties of graphene adsorbed onto h-BN with carbon impurities or atomic vacancies using density functional theory and the non-equilibrium Green's function method. We find that the transport properties are degraded due to carrier doping and scattering off of localized defect states in h-BN. When graphene is doped by introducing defects in h-BN, the transmission spectra become asymmetric owing to the reduction of the electronic density of states, which contributes significantly to the degradation of graphene transport properties as compared with the effect of defect levels.

  7. Low resistivity ZnO-GO electron transport layer based CH{sub 3}NH{sub 3}PbI{sub 3} solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Ahmed, Muhammad Imran, E-mail: imranrahbar@scme.nust.edu.pk, E-mail: amirhabib@scme.nust.edu.pk; Hussain, Zakir; Mujahid, Mohammad; Khan, Ahmed Nawaz [School of Chemical and Materials Engineering, National University of Sciences and Technology, Islamabad, 44000 (Pakistan); Javaid, Syed Saad [College of Aeronautical Engineering, National University of Sciences and Technology, Islamabad, 44000 (Pakistan); Habib, Amir, E-mail: imranrahbar@scme.nust.edu.pk, E-mail: amirhabib@scme.nust.edu.pk [School of Chemical and Materials Engineering, National University of Sciences and Technology, Islamabad, 44000 (Pakistan); The Department of Physics, College of Sciences, University of Hafar Al Batin, P.O. Box 1803, Hafar Al Batin 31991 Saudi Arabia (Saudi Arabia)

    2016-06-15

    Perovskite based solar cells have demonstrated impressive performances. Controlled environment synthesis and expensive hole transport material impede their potential commercialization. We report ambient air synthesis of hole transport layer free devices using ZnO-GO as electron selective contacts. Solar cells fabricated with hole transport layer free architecture under ambient air conditions with ZnO as electron selective contact achieved an efficiency of 3.02%. We have demonstrated that by incorporating GO in ZnO matrix, low resistivity electron selective contacts, critical to improve the performance, can be achieved. We could achieve max efficiency of 4.52% with our completed devices for ZnO: GO composite. Impedance spectroscopy confirmed the decrease in series resistance and an increase in recombination resistance with inclusion of GO in ZnO matrix. Effect of temperature on completed devices was investigated by recording impedance spectra at 40 and 60 {sup o}C, providing indirect evidence of the performance of solar cells at elevated temperatures.

  8. Activity of the respiratory electron transport system and respiration rates within the oxygen minimum layer of the Arabian Sea

    Digital Repository Service at National Institute of Oceanography (India)

    Naqvi, S.W.A.; Shailaja, M.S.

    Measurements of the activity of the respirtory electron transport system (ETS) at 15 stations in the Arabian Sea during the northeast monsoon (December 1988) yield high respiration rates that do not correlate with the trends in primary productivity...

  9. Two-Step Physical Deposition of a Compact CuI Hole-Transport Layer and the Formation of an Interfacial Species in Perovskite Solar Cells.

    Science.gov (United States)

    Gharibzadeh, Saba; Nejand, Bahram Abdollahi; Moshaii, Ahmad; Mohammadian, Nasim; Alizadeh, Amir Hossein; Mohammadpour, Rahele; Ahmadi, Vahid; Alizadeh, Abdolali

    2016-08-09

    A simple and practical approach is introduced for the deposition of CuI as an inexpensive inorganic hole-transport material (HTM) for the fabrication of low cost perovskite solar cells (PSCs) by gas-solid phase transformation of Cu to CuI. The method provides a uniform and well-controlled CuI layer with large grains and good compactness that prevents the direct connection between the contact electrodes. Solar cells prepared with CuI as the HTM with Au electrodes displays an exceptionally high short-circuit current density of 32 mA cm(-2) , owing to an interfacial species formed between the perovskite and the Cu resulting in a long wavelength contribution to the incident photon-to-electron conversion efficiency (IPCE), and an overall power conversion efficiency (PCE) of 7.4 %. The growth of crystalline and uniform CuI on a low roughness perovskite layer leads to remarkably high charge extraction in the cells, which originates from the high hole mobility of CuI in addition to a large number of contact points between CuI and the perovskite layer. In addition, the solvent-free method has no damaging side effect on the perovskite layer, which makes it an appropriate method for large scale applications of CuI in perovskite solar cells. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. White Organic Light-Emitting Diodes Using Two Phosphorescence Materials in a Starburst Hole-Transporting Layer

    Directory of Open Access Journals (Sweden)

    Tomoya Inden

    2012-01-01

    Full Text Available We fabricated two kinds of white organic light-emitting diodes (WOLEDs; one consisted of two emissive materials of red and blue, and the other of three emissive materials of red, green, and blue. The red and blue emissive materials were phosphorescent. We evaluated the thickness dependence of the CIE coordinate, the external quantum efficiency (EQE, and the luminance by changing the thicknesses of the Ir(btp2acac and FIrpic layers. Samples consisting of three emissive materials revealed the best CIE coordinate and the best EQE in the same sample structure. On the other hand, the samples consisting of two emissive materials revealed the best CIE coordinate and the best EQE in different structures. The best CIE coordinate of (0.33, 0.36 was observed by changing the thicknesses of the stacked active layers. The best EQE was 9.73%, which was observed in the sample consisting of different thickness of stacked active layers.

  11. Photovoltaic Properties in Interpenetrating Heterojunction Organic Solar Cells Utilizing MoO3 and ZnO Charge Transport Buffer Layers

    Directory of Open Access Journals (Sweden)

    Tetsuro Hori

    2010-11-01

    Full Text Available Organic thin-film solar cells with a conducting polymer (CP/fullerene (C60 interpenetrating heterojunction structure, fabricated by spin-coating a CP onto a C60 deposit thin film, have been investigated and demonstrated to have high efficiency. The photovoltaic properties of solar cells with a structure of indium-tin-oxide/C60/ poly(3-hexylthiophene (PAT6/Au have been improved by the insertion of molybdenum trioxide (VI (MoO3 and zinc oxide charge transport buffer layers. The enhanced photovoltaic properties have been discussed, taking into consideration the ground-state charge transfer between PAT6 and MoO3 by measurement of the differential absorption spectra and the suppressed contact resistance at the interface between the organic and buffer layers.

  12. Comprehensive Study of Sol-Gel versus Hydrolysis-Condensation Methods To Prepare ZnO Films: Electron Transport Layers in Perovskite Solar Cells.

    Science.gov (United States)

    Zhao, Yu-Han; Zhang, Kai-Cheng; Wang, Zhao-Wei; Huang, Peng; Zhu, Kai; Li, Zhen-Dong; Li, Da-Hua; Yuan, Li-Gang; Zhou, Yi; Song, Bo

    2017-08-09

    Owing to the high charge mobility and low processing temperature, ZnO is regarded as an ideal candidate for electron transport layer (ETL) material in thin-film solar cells. For the film preparation, the presently dominated sol-gel (SG) and hydrolysis-condensation (HC) methods show great potential; however, the effect of these two methods on the performance of the resulting devices has not been investigated in the same frame. In this study, the ZnO films made through SG and HC methods were applied in perovskite solar cells (Pero-SCs), and the performances of corresponding devices were compared under parallel conditions. We found that the surface morphologies and the conductivities of the films prepared by SG and HC methods showed great differences. The HC-ZnO films with higher conductivity led to relatively higher device performance, and the best power conversion efficiencie (PCE) of 12.9% was obtained; meanwhile, for Pero-SCs based on SG-ZnO, the best PCE achieved was 10.9%. The better device performance of Pero-SCs based on HC-ZnO should be attributed to the better charge extraction and transportation ability of HC-ZnO film. Moreover, to further enhance the performance of Pero-SCs, a thin layer of pristine C 60 was introduced between HC-ZnO and perovskite layers. By doing so, the quality of perovskite films was improved, and the PCE was elevated to 14.1%. The preparation of HC-ZnO film involves relatively lower-temperature (maximum 100 °C) processing; the films showed better charge extraction and transportation properties and can be a more promising ETL material in Pero-SCs.

  13. Monte Carlo transport simulation for a long counter neutron detector employed as a cosmic rays induced neutron monitor at ground level

    Energy Technology Data Exchange (ETDEWEB)

    Pazianotto, Mauricio Tizziani; Carlson, Brett Vern [Instituto Tecnologico de Aeronautica (ITA), Sao Jose dos Campos, SP (Brazil); Federico, Claudio Antonio; Goncalez, Odair Lelis [Centro Tecnico Aeroespacial (CTA), Sao Jose dos Campos, SP (Brazil). Instituto de Estudos Avancados

    2011-07-01

    Full text: Great effort is required to understand better the cosmic radiation (CR) dose received by sensitive equipment, on-board computers and aircraft crew members at Brazil airspace, because there is a large area of South America and Brazil subject to the South Atlantic Anomaly (SAA). High energy neutrons are produced by interactions between primary cosmic ray and atmospheric atoms, and also undergo moderation resulting in a wider spectrum of energy ranging from thermal energies (0:025eV ) to energies of several hundreds of MeV. Measurements of the cosmic radiation dose on-board aircrafts need to be followed with an integral flow monitor on the ground level in order to register CR intensity variations during the measurements. The Long Counter (LC) neutron detector was designed as a directional neutron flux meter standard because it presents fairly constant response for energy under 10MeV. However we would like to use it as a ground based neutron monitor for cosmic ray induced neutron spectrum (CRINS) that presents an isotropic fluency and a wider spectrum of energy. The LC was modeled and tested using a Monte Carlo transport simulation for irradiations with known neutron sources ({sup 241}Am-Be and {sup 251}Cf) as a benchmark. Using this geometric model its efficiency was calculated to CRINS isotropic flux, introducing high energy neutron interactions models. The objective of this work is to present the model for simulation of the isotropic neutron source employing the MCNPX code (Monte Carlo N-Particle eXtended) and then access the LC efficiency to compare it with experimental results for cosmic ray neutrons measures on ground level. (author)

  14. Seasonal variability of upper-layer geostrophic transport in the tropical Indian Ocean during 1992-1996 along TOGA-I XBT tracklines

    Digital Repository Service at National Institute of Oceanography (India)

    Murty, V.S.N.; Sarma, M.S.S.; Lambata, B.P.; Gopalakrishna, V.V.; Pednekar, S.M.; Rao, A.S.; Luis, A.J.; Kaka, A.R.; Rao, L.V.G.

    the climatological monthly mean temperature and salinity pro"les (Levitus and Boyer, 1994) for 13]13grids. The upper ocean geostrophic currents between the XBT stations were derived and the seasonal variability of the upper-layer geostrophic transport of various... winter transition (September}November) seasons. XBT data were not available for April or August during the study period. The raw XBT data (export "les) with recorded temperature at 0.65 m depth intervals were linearly interpolated to 1 m depth intervals...

  15. Conductivity Modulation of Gold Thin Film at Room Temperature via All-Solid-State Electric-Double-Layer Gating Accelerated by Nonlinear Ionic Transport.

    Science.gov (United States)

    Asano, Tetsuya; Kaneko, Yukihiro; Omote, Atsushi; Adachi, Hideaki; Fujii, Eiji

    2017-02-15

    We demonstrated the field-effect conductivity modulation of a gold thin film by all-solid-state electric-double-layer (EDL) gating at room temperature using an epitaxially grown oxide fast lithium conductor, La 2/3-x Li 3x TiO 3 (LLT), as a solid electrolyte. The linearly increasing gold conductivity with increasing gate bias demonstrates that the conductivity modulation is indeed due to carrier injection by EDL gating. The response time becomes exponentially faster with increasing gate bias, a result of the onset of nonlinear ionic transportation. This nonlinear dynamic response indicates that the ionic motion-driven device can be much faster than would be estimated from a linear ionic transport model.

  16. Radiation Transport

    Energy Technology Data Exchange (ETDEWEB)

    Urbatsch, Todd James [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-06-15

    We present an overview of radiation transport, covering terminology, blackbody raditation, opacities, Boltzmann transport theory, approximations to the transport equation. Next we introduce several transport methods. We present a section on Caseology, observing transport boundary layers. We briefly broach topics of software development, including verification and validation, and we close with a section on high energy-density experiments that highlight and support radiation transport.

  17. An ultra-thin, un-doped NiO hole transporting layer of highly efficient (16.4%) organic-inorganic hybrid perovskite solar cells

    Science.gov (United States)

    Seo, Seongrok; Park, Ik Jae; Kim, Myungjun; Lee, Seonhee; Bae, Changdeuck; Jung, Hyun Suk; Park, Nam-Gyu; Kim, Jin Young; Shin, Hyunjung

    2016-06-01

    NiO is a wide band gap p-type oxide semiconductor and has potential for applications in solar energy conversion as a hole-transporting layer (HTL). It also has good optical transparency and high chemical stability, and the capability of aligning the band edges to the perovskite (CH3NH3PbI3) layers. Ultra-thin and un-doped NiO films with much less absorption loss were prepared by atomic layer deposition (ALD) with highly precise control over thickness without any pinholes. Thin enough (5-7.5 nm in thickness) NiO films with the thickness of few time the Debye length (LD = 1-2 nm for NiO) show enough conductivities achieved by overlapping space charge regions. The inverted planar perovskite solar cells with NiO films as HTLs exhibited the highest energy conversion efficiency of 16.40% with high open circuit voltage (1.04 V) and fill factor (0.72) with negligible current-voltage hysteresis.NiO is a wide band gap p-type oxide semiconductor and has potential for applications in solar energy conversion as a hole-transporting layer (HTL). It also has good optical transparency and high chemical stability, and the capability of aligning the band edges to the perovskite (CH3NH3PbI3) layers. Ultra-thin and un-doped NiO films with much less absorption loss were prepared by atomic layer deposition (ALD) with highly precise control over thickness without any pinholes. Thin enough (5-7.5 nm in thickness) NiO films with the thickness of few time the Debye length (LD = 1-2 nm for NiO) show enough conductivities achieved by overlapping space charge regions. The inverted planar perovskite solar cells with NiO films as HTLs exhibited the highest energy conversion efficiency of 16.40% with high open circuit voltage (1.04 V) and fill factor (0.72) with negligible current-voltage hysteresis. Electronic supplementary information (ESI) available. See DOI: 10.1039/c6nr01601d

  18. Plasma confinement modification and convective transport suppression in the scrape-off layer using additional gas puffing in the STOR-M tokamak

    International Nuclear Information System (INIS)

    Dreval, M; Hubeny, M; Ding, Y; Onchi, T; Liu, Y; Hthu, K; Elgriw, S; Xiao, C; Hirose, A

    2013-01-01

    The influence of short gas puffing (GP) pulses on the scrape-off layer (SOL) transport is studied. Similar responses of ion saturation current and floating potential measured near the GP injection valve and in the 90° toroidally separated cross-section suggest that the GP influence on the SOL region should be global. A drop in plasma temperature and a decrease in the rotational velocity of the plasma are observed in the SOL region immediately after the GP pulse; however, an unexpected increase in electron and ion temperatures is observed in the second stage of the plasma response. The decrease in floating potential fluctuations indicates that the turbulent transport is dumped immediately after the GP pulse. The GP-induced modification of turbulence properties in the SOL points to a convective transport suppression in the STOR-M tokamak. A substantial decrease in the skewness and kurtosis of ion saturation current fluctuations is observed in the SOL region resulting in the probability distribution function (PDF) getting closer to the Gaussian distribution. The plasma potential reduction, the change in plasma rotation and the suppression of turbulent transport in the SOL region indicate that the plasma confinement is modified after the GP injection. Some features of the H-mode-like confinement in the plasma bulk also accompany the SOL observations after application of the additional sharp GP pulse. (paper)

  19. Copper (I) Selenocyanate (CuSeCN) as a Novel Hole-Transport Layer for Transistors, Organic Solar Cells, and Light-Emitting Diodes

    KAUST Repository

    Wijeyasinghe, Nilushi

    2018-02-01

    The synthesis and characterization of copper (I) selenocyanate (CuSeCN) and its application as a solution-processable hole-transport layer (HTL) material in transistors, organic light-emitting diodes, and solar cells are reported. Density-functional theory calculations combined with X-ray photoelectron spectroscopy are used to elucidate the electronic band structure, density of states, and microstructure of CuSeCN. Solution-processed layers are found to be nanocrystalline and optically transparent (>94%), due to the large bandgap of ≥3.1 eV, with a valence band maximum located at −5.1 eV. Hole-transport analysis performed using field-effect measurements confirms the p-type character of CuSeCN yielding a hole mobility of 0.002 cm2 V−1 s−1. When CuSeCN is incorporated as the HTL material in organic light-emitting diodes and organic solar cells, the resulting devices exhibit comparable or improved performance to control devices based on commercially available poly(3,4-ethylenedioxythiophene):polystyrene sulfonate as the HTL. This is the first report on the semiconducting character of CuSeCN and it highlights the tremendous potential for further developments in the area of metal pseudohalides.

  20. Solution-Processed In2O3/ZnO Heterojunction Electron Transport Layers for Efficient Organic Bulk Heterojunction and Inorganic Colloidal Quantum-Dot Solar Cells

    KAUST Repository

    Eisner, Flurin

    2018-04-25

    We report the development of a solution‐processed In2O3/ZnO heterojunction electron transport layer (ETL) and its application in high efficiency organic bulk‐heterojunction (BHJ) and inorganic colloidal quantum dot (CQD) solar cells. Study of the electrical properties of this low‐dimensional oxide heterostructure via field‐effect measurements reveals that electron transport along the heterointerface is enhanced by more than a tenfold when compared to the individual single‐layer oxides. Use of the heterojunction as the ETL in organic BHJ photovoltaics is found to consistently improve the cell\\'s performance due to the smoothening of the ZnO surface, increased electron mobility and a noticeable reduction in the cathode\\'s work function, leading to a decrease in the cells’ series resistance and a higher fill factor (FF). Specifically, non‐fullerene based organic BHJ solar cells based on In2O3/ZnO ETLs exhibit very high power conversion efficiencies (PCE) of up to 12.8%, and high FFs of over 70%. The bilayer ETL concept is further extended to inorganic lead‐sulphide CQD solar cells. Resulting devices exhibit excellent performance with a maximum PCE of 8.2% and a FF of 56.8%. The present results highlight the potential of multilayer oxides as novel ETL systems and lay the foundation for future developments.

  1. Improving the stability of bulk heterojunction solar cells by incorporating pH-neutral PEDOT:PSS as the hole transport layer.

    Science.gov (United States)

    Meng, Yanhong; Hu, Zhanhao; Ai, Na; Jiang, Zhixiong; Wang, Jian; Peng, Junbiao; Cao, Yong

    2014-04-09

    In the application of traditional bulk heterojunction polymer solar cells, to prevent the etching of ITO by the acidic poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) and thereby improve the device stability, pH-neutral PEDOT:PSS is introduced as the hole transport layer (HTL). After treating the neutral PEDOT:PSS with UV-ozone and with an oxygen plasma, the average power conversion efficiency (PCE) of the device increases from 3.44% to 6.60%. Such surface treatments reduce the energy level offset between the HTL and the active layer, which increases the open circuit voltage and enhances hole transportation, leading to the PCE improvement. Moreover, the devices with the neutral PEDOT:PSS HTL are more stable in air than those with the acidic PEDOT:PSS HTL. The PCE of the devices with the acidic PEDOT:PSS HTL decreases by 20% after 7 days and 45% after 50 days under ambient conditions, whereas the PCE of the devices with the pH-neutral PEDOT:PSS HTL decreases by only 9 and 20% after 7 and 50 days, respectively. X-ray photoelectron spectroscopy shows that the acidic PEDOT:PSS etches the indium from the indium-tin-oxide (ITO) electrode, which is responsible for the degradation of the device. In comparison, the diffusion of the indium is much slower in the devices with the pH-neutral PEDOT:PSS HTL.

  2. Observation of dopant-profile independent electron transport in sub-monolayer TiOx stacked ZnO thin films grown by atomic layer deposition

    Science.gov (United States)

    Saha, D.; Misra, P.; Das, Gangadhar; Joshi, M. P.; Kukreja, L. M.

    2016-01-01

    Dopant-profile independent electron transport has been observed through a combined study of temperature dependent electrical resistivity and magnetoresistance measurements on a series of Ti incorporated ZnO thin films with varying degree of static-disorder. These films were grown by atomic layer deposition through in-situ vertical stacking of multiple sub-monolayers of TiOx in ZnO. Upon decreasing ZnO spacer layer thickness, electron transport smoothly evolved from a good metallic to an incipient non-metallic regime due to the intricate interplay of screening of spatial potential fluctuations and strength of static-disorder in the films. Temperature dependent phase-coherence length as extracted from the magnetotransport measurement revealed insignificant role of inter sub-monolayer scattering as an additional channel for electron dephasing, indicating that films were homogeneously disordered three-dimensional electronic systems irrespective of their dopant-profiles. Results of this study are worthy enough for both fundamental physics perspective and efficient applications of multi-stacked ZnO/TiOx structures in the emerging field of transparent oxide electronics.

  3. Employer branding

    OpenAIRE

    Mičková, Kateřina

    2008-01-01

    The demand for qualified employees is higher then the offering, both in Czech republic and internationally. Demand for specific skills, in addition to a greater demand for workforce generally, is making employee recruitment and retention much more difficult and expensive. Employer Branding claims to be an answer to this new challenge. This international concept focuses on developing an "employer brand" - mental image of a company as an employer. To achieve this, it is necessary to demonstrate...

  4. 49 CFR 807.140 - Employment.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 7 2010-10-01 2010-10-01 false Employment. 807.140 Section 807.140 Transportation... TRANSPORTATION SAFETY BOARD § 807.140 Employment. No qualified handicapped person shall, on the basis of handicap, be subjected to discrimination in employment under any program or activity conducted by the agency...

  5. Influence of doped-charge transport layers on the photovoltaic performance of donor-acceptor blend p-i-n type organic solar cells

    Directory of Open Access Journals (Sweden)

    D. Gebeyehu

    2004-06-01

    Full Text Available This report demonstrates external power conversion efficiencies of 2% under 100 mW/cm2 simulated AM1.5 illumination for organic thin-film photovoltaic cells using a phthalocyanine-fullerene (ZnPc/C60 bulk heterojunction as an active layer, embedded into a p-i-n type architecture with doped wide-gap charge transport layers. For an optically optimized device, we found internal quantum efficiency (IQE of above 80% under short circuit conditions. Such optically thin cells with high internal quantum efficiency are an important step towards high efficiency tandem cells. The p-i-n architecture allows for the design of solar cells with high internal quantum efficiency where only the photoactive region absorbs visible light and recombination losses at contacts are avoided. The I-V characteristics, power conversion efficiencies, the dependence of short circuit current on incident white light intensity, incident photon to collected electron efficiency (IPCE and absorption spectra of the active layer system are discussed.

  6. Impacts of synoptic condition and planetary boundary layer structure on the trans-boundary aerosol transport from Beijing-Tianjin-Hebei region to northeast China

    Science.gov (United States)

    Miao, Yucong; Guo, Jianping; Liu, Shuhua; Zhao, Chun; Li, Xiaolan; Zhang, Gen; Wei, Wei; Ma, Yanjun

    2018-05-01

    The northeastern China frequently experiences severe aerosol pollution in winter under unfavorable meteorological conditions. How and to what extent the meteorological factors affect the air quality there are not yet clearly understood. Thus, this study investigated the impacts of synoptic patterns on the aerosol transport and planetary boundary layer (PBL) structure in Shenyang from 1 to 3 December 2016, using surface observations, sounding measurements, satellite data, and three-dimensional simulations. Results showed that the aerosol pollution occurred in Shenyang was not only related to the local emissions, but also contributed by trans-boundary transport of aerosols from the Beiijng-Tianjin-Hebei (BTH) region. In the presence of the westerly and southwesterly synoptic winds, the aerosols emitted from BTH could be brought to Shenyang. From December 2 to 3, the aerosols emitted from BTH accounted for ∼20% of near-surface PM2.5 in Shenyang. In addition, the large-scale synoptic forcings could affect the vertical mixing of pollutants through modulating the PBL structure in Shenyang. The westerly and southwesterly synoptic winds not only brought the aerosols but also the warmer air masses from the southwest regions to Shenyang. The strong warm advections above PBL could enhance the already existing thermal inversion layers capping over PBL in Shenyang, leading to the suppressions of PBL. Both the trans-boundary transport of aerosols and the suppressions of PBL caused by the large-scale synoptic forcings should be partly responsible for the poor air quality in Shenyang, in addition to the high pollutant emissions. The present study revealed the physical mechanisms underlying the aerosol pollution in Shenyang, which has important implications for better forecasting and controlling the aerosols pollution.

  7. Evidence for a poloidally localized enhancement of radial transport in the scrape-off layer of the Tore Supra tokamak

    Czech Academy of Sciences Publication Activity Database

    Gunn, J. P.; Boucher, C.; Dionne, M.; Ďuran, Ivan; Fuchs, Vladimír; Loarer, T.; Nanobashvili, I.; Pánek, Radomír; Pascal, J.-Y.; Saint-Laurent, F.; Stöckel, Jan; Van Rompuy, T.; Zagórski, R.; Adámek, Jiří; Bucalossi, J.; Dejarnac, Renaud; Devynck, P.; Hertout, P.; Hron, Martin; Lebrun, G.; Moreau, P.; Rimini, F.; Sarkissian, A.; Van Oost, G.

    363-365, - (2007), s. 484-490 ISSN 0022-3115. [International Conference on Plasma-Surface Interactions in Controlled Fusion Devices/17th./. Hefei, 22.05.2006-26.05. 2006] R&D Projects: GA ČR GP202/03/P062 Institutional research plan: CEZ:AV0Z20430508 Keywords : Cross-field transport * Edge plasma * Plasma flow * Tore Supra Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 1.643, year: 2007

  8. Steady-state and time-dependent modelling of parallel transport in the scrape-off layer

    Czech Academy of Sciences Publication Activity Database

    Havlíčková, E.; Fundameski, W.; Naulin, V.; Nielsen, A.H.; Zagórski, R.; Seidl, Jakub; Horáček, Jan

    2011-01-01

    Roč. 53, č. 6 (2011), 065004-065004 ISSN 0741-3335 R&D Projects: GA ČR GAP205/10/2055; GA MŠk 7G09042 Institutional research plan: CEZ:AV0Z20430508 Keywords : Parallel transport * , SOLF1D Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.425, year: 2011 http://iopscience.iop.org/0741-3335/53/6/065004/pdf/0741-3335_53_6_065004.pdf

  9. Industry Employment

    Science.gov (United States)

    Occupational Outlook Quarterly, 2012

    2012-01-01

    This article illustrates projected employment change by industry and industry sector over 2010-20 decade. Workers are grouped into an industry according to the type of good produced or service provided by the establishment for which they work. Industry employment projections are shown in terms of numeric change (growth or decline in the total…

  10. VIA Employability

    DEFF Research Database (Denmark)

    Andersen, Henrik Mariendal

    2017-01-01

    The fact that students develop employability during their education is a key point for educational institutions and the focus on this issue has never been greater. This project looks into personal experience from VIA-graduates of "developing their employability" during the education and how it......’s realized at the entrance to the labor market and in the future career. The purpose is to find opportunities to improve employability-developing activities and to adapt it to specific needs from the students. Based on a number of qualitative interviews and personality tests of the graduates, an increased...... personal approach is proposed in the agenda of employability. And ensure a wide range of offers, that appeal to multiple and differentiated personal and professional approaches to employability....

  11. Effects of overlapping electric double layer on mass transport of a macro-solute across porous wall of a micro/nanochannel for power law fluid.

    Science.gov (United States)

    Bhattacharjee, Saikat; Mondal, Mrinmoy; De, Sirshendu

    2017-05-01

    Effects of overlapping electric double layer and high wall potential on transport of a macrosolute for flow of a power law fluid through a microchannel with porous walls are studied in this work. The electric potential distribution is obtained by coupling the Poisson's equation without considering the Debye-Huckel approximation. The numerical solution shows that the center line potential can be 16% of wall potential at pH 8.5, at wall potential -73 mV and scaled Debye length 0.5. Transport phenomena involving mass transport of a neutral macrosolute is formulated by species advective equation. An analytical solution of Sherwood number is obtained for power law fluid. Effects of fluid rheology are studied in detail. Average Sherwood number is more for a pseudoplastic fluid compared to dilatant upto the ratio of Poiseuille to electroosmotic velocity of 5. Beyond that, the Sherwood number is independent of fluid rheology. Effects of fluid rheology and solute size on permeation flux and concentration of neutral solute are also quantified. More solute permeation occurs as the fluid changes from pseudoplastic to dilatant. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Facile Sol-Gel Derived Crater-like Dual-functioning TiO2 Electron Transport Layer for High Efficiency Perovskite Solar Cells.

    Science.gov (United States)

    Ma, Sunihl; Ahn, Jihoon; Oh, Yunjung; Kwon, Hyeok-Chan; Lee, Eunsong; Kim, Kyungmi; Yun, Seong-Cheol; Moon, Jooho

    2018-04-05

    Organic-inorganic hybrid perovskite solar cells (PSCs) are considered promising materials for low-cost solar energy harvesting technology. An electron transport layer (ETL), which facilitates the extraction of photo-generated electrons and their transport to the electrodes, is a key component in planar perovskite solar cells. In this study, a new strategy to concurrently manipulate the electrical and optical properties of ETLs to improve the performance of PSCs is demonstrated. A careful control over the Ti alkoxide-based sol-gel chemistry leads to a crater-like porous/blocking bilayer TiO2 ETL with relatively uniform surface pores of 220 nm diameter. Additionally, the phase separation promoter added to the precursor solution enables nitrogen doping in the TiO2 lattice, thus generating oxygen vacancies. The crater-like surface morphology allows for better light transmission due to reduced reflection, while the electrically conductive crater-like bilayer ETL enhances charge extraction and transport. Through these synergetic improvements in both optical and electrical properties, the power conversion efficiency of crater-like bilayer TiO2 ETL-based PSCs could be increased from 13.7% to 16.0% as compared to conventional dense TiO2-based PSCs.

  13. Fast Crystallization and improved Stability of Perovskite Solar Cells with Zn 2 SnO 4 Electron Transporting Layer: Interface Matters

    KAUST Repository

    Bera, Ashok

    2015-12-03

    Here we report that mesoporous ternary oxide Zn2SnO4 can significantly promotes the crystallization of hybrid perovskite layers and serves as an efficient electron transporting material in perovskite solar cells. Such devices exhibit an energy conversion efficiency of 13.34%, which is even higher than that achieved with the commonly used TiO2 in the similar experimental conditions (9.1%). Simple one-step spin coating of CH3NH3PbI3−xClx on Zn2SnO4 is found to lead to rapidly crystalized bilayer perovskite structure without any solvent engineering. Furthermore, ultrafast transient absorption measurement reveals efficient charge transfer at the Zn2SnO4/perovskite interface. Most importantly, solar cells with Zn2SnO4 as the electron-transporting material exhibit negligible electrical hysteresis and exceptionally high stability without encapsulation for over one month. Besides underscoring Zn2SnO4 as a highly promising electron transporting material for perovskite solar cells, our results demonstrate the significant role of interfaces on improving the perovskite crystallization and photovoltaic performance.

  14. Effect of Energy Alignment, Electron Mobility, and Film Morphology of Perylene Diimide Based Polymers as Electron Transport Layer on the Performance of Perovskite Solar Cells.

    Science.gov (United States)

    Guo, Qiang; Xu, Yingxue; Xiao, Bo; Zhang, Bing; Zhou, Erjun; Wang, Fuzhi; Bai, Yiming; Hayat, Tasawar; Alsaedi, Ahmed; Tan, Zhan'ao

    2017-03-29

    For organic-inorganic perovskite solar cells (PerSCs), the electron transport layer (ETL) plays a crucial role in efficient electron extraction and transport for high performance PerSCs. Fullerene and its derivatives are commonly used as ETL for p-i-n structured PerSCs. However, these spherical small molecules are easy to aggregate with high annealing temperature and thus induce morphology stability problems. N-type conjugated polymers are promising candidates to overcome these problems due to the tunable energy levels, controllable aggregation behaviors, and good film formation abilities. Herein, a series of perylene diimide (PDI) based polymers (PX-PDIs), which contain different copolymeried units (X), including vinylene (V), thiophene (T), selenophene (Se), dibenzosilole (DBS), and cyclopentadithiophene (CPDT), are introduced as ETL for p-i-n structured PerSCs. The effect of energy alignment, electron mobility, and film morphology of these ETLs on the photovoltaic performance of the PerSCs are fully investigated. Among the PX-PDIs, PV-PDI demonstrates the deeper LUMO energy level, the highly delocalized LUMO electron density, and a better planar structure, making it the best electron transport material for PerSCs. The planar heterojunction PerSC with PV-PDI as ETL achieves a power conversion efficiency (PCE) of 10.14%, among the best values for non-fullerene based PerSCs.

  15. Fast Transport from Southeast Asia Boundary Layer Sources to Northern Europe: Rapid Uplift in Typhoons and Eastward Eddy Shedding of the Asian Monsoon Anticyclone

    Science.gov (United States)

    Mueller, R.; Vogel, B.; Guenther, G.; Grooss, J. U.; Hoor, P. M.; Kraemer, M.; Mueller, S.; Zahn, A.; Riese, M.

    2014-12-01

    During the TACTS aircraft campaign enhanced tropospheric trace gases such as CO, CH4, and H2O and reduced stratospheric O3 were measured in situ in the lowermost stratosphere over Northern Europe on 26 September 2012. The measurements indicate that these air masses differ from the stratospheric background. The calculation of 40 day backward trajectories with the trajectory module of the CLaMS model shows that these air masses are affected by the Asian monsoon anticyclone. Some air masses originate from the boundary layer in Southeast Asia/West Pacific and are rapidly lifted (1-2 days) within a typhoon. Afterwards they are injected directly into the anticyclonic circulation of the Asian monsoon. The subsequent long-range transport (8-14 days) of enhanced water vapour and pollutants to the lowermost stratosphere in Northern Europe is driven by eastward transport of tropospheric air from the Asian monsoon anticyclone caused by an eddy shedding event. We find that the combination of rapid uplift by a typhoon and eastward eddy shedding from the Asian monsoon anticyclone is an additional fast transport pathway that, for the case studied here, carries boundary emissions from Southeast Asia/West Pacific within approximately 5 weeks to the lowermost stratosphere in Northern Europe.

  16. Two case studies on the interaction of large-scale transport, mesoscale photochemistry, and boundary-layer processes on the lower tropospheric ozone dynamics in early spring

    Directory of Open Access Journals (Sweden)

    S. Brönnimann

    Full Text Available The vertical distribution of ozone in the lower troposphere over the Swiss Plateau is investigated in detail for two episodes in early spring (February 1998 and March 1999. Profile measurements of boundary-layer ozone performed during two field campaigns with a tethered balloon sounding system and a kite are investigated using regular aerological and ozone soundings from a nearby site, measurements from monitoring stations at various altitudes, backward trajectories, and synoptic analyses of meteorological fields. Additionally, the effect of in situ photochemistry was estimated for one of the episodes employing the Metphomod Eulerian photochemical model. Although the meteorological situations were completely different, both cases had elevated layers with high ozone concentrations, which is not untypical for late winter and early spring. In the February episode, the highest ozone concentrations of 55 to 60 ppb, which were found at around 1100 m asl, were partly advected from Southern France, but a considerable contribution of in situ photochemistry is also predicted by the model. Below that elevation, the local chemical sinks and surface deposition probably overcompensated chemical production, and the vertical ozone distribution was governed by boundary-layer dynamics. In the March episode, the results suggest that ozone-rich air parcels, probably of stratospheric or upper tropospheric origin, were advected aloft the boundary layer on the Swiss Plateau.

    Key words. Atmospheric composition and structure (pollution – urban and regional; troposphere – composition and  chemistry – Meteorology and atmospheric dynamics (mesoscale meteorology

  17. Importance of the colmation layer in the transport and removal of cyanobacteria, viruses, and dissolved organic carbon during natural lake-bank filtration

    Science.gov (United States)

    Harvey, Ronald W.; Metge, David W.; LeBlanc, Denis R.; Underwood, Jennifer C.; Aiken, George R.; Butler, Kenna D.; McCobb, Timothy D.; Jasperse, Jay

    2015-01-01

    This study focused on the importance of the colmation layer in the removal of cyanobacteria, viruses, and dissolved organic carbon (DOC) during natural bank filtration. Injection-and-recovery studies were performed at two shallow (0.5 m deep), sandy, near-shore sites at the southern end of Ashumet Pond, a waste-impacted, kettle pond on Cape Cod, MA, that is subject to periodic blooms of cyanobacteria and continuously recharges a sole-source drinking-water aquifer. The experiment involved assessing the transport behaviors of bromide (conservative tracer), Synechococcus sp. IU625 (cyanobacterium, 2.6 ± 0.2 µm), AS-1 (tailed cyanophage, 110 nm long), MS2 (coliphage, 26 nm diameter), and carboxylate-modified microspheres (1.7 µm diameter) introduced to the colmation layer using a bag-and-barrel (Lee-type) seepage meter. The injectate constituents were tracked as they were advected across the pond water–groundwater interface and through the underlying aquifer sediments under natural-gradient conditions past push-point samplers placed at ∼30-cm intervals along a 1.2-m-long, diagonally downward flow path. More than 99% of the microspheres, IU625, MS2, AS-1, and ∼44% of the pond DOC were removed in the colmation layer (upper 25 cm of poorly sorted bottom sediments) at two test locations characterized by dissimilar seepage rates (1.7 vs. 0.26 m d−1). Retention profiles in recovered core material indicated that >82% of the attached IU625 were in the top 3 cm of bottom sediments. The colmation layer was also responsible for rapid changes in the character of the DOC and was more effective (by three orders of magnitude) at removing microspheres than was the underlying 20-cm-thick segment of sediment.

  18. The heterojunction effects of TiO2 nanotubes fabricated by atomic layer deposition on photocarrier transportation direction

    OpenAIRE

    Chang, Yung-Huang; Liu, Chien-Min; Chen, Chih; Cheng, Hsyi-En

    2012-01-01

    The heterojunction effects of TiO2 nanotubes on photoconductive characteristics were investigated. For ITO/TiO2/Si diodes, the photocurrent is controlled either by the TiO2/Si heterojunction (p-n junction) or the ITO-TiO2 heterojunction (Schottky contact). In the short circuit (approximately 0 V) condition, the TiO2-Si heterojunction dominates the photocarrier transportation direction due to its larger space-charge region and potential gradient. The detailed transition process of the photocar...

  19. Development of an inter-layer solute transport algorithm for SOLTR computer program. Part 1. The algorithm

    International Nuclear Information System (INIS)

    Miller, I.; Roman, K.

    1979-12-01

    In order to perform studies of the influence of regional groundwater flow systems on the long-term performance of potential high-level nuclear waste repositories, it was determined that an adequate computer model would have to consider the full three-dimensional flow system. Golder Associates' SOLTR code, while three-dimensional, has an overly simple algorithm for simulating the passage of radionuclides from one aquifier to another above or below it. Part 1 of this report describes the algorithm developed to provide SOLTR with an improved capability for simulating interaquifer transport

  20. The osmotolerant fructophilic yeast Zygosaccharomyces rouxii employs two plasma-membrane fructose uptake systems belonging to a new family of yeast sugar transporters.

    Science.gov (United States)

    Leandro, Maria José; Sychrová, Hana; Prista, Catarina; Loureiro-Dias, Maria C

    2011-02-01

    Owing to its high resistance to weak-acid preservatives and extreme osmotolerance, Zygosaccharomyces rouxii is one of the main spoilage yeasts of sweet foods and beverages. In contrast with Saccharomyces cerevisiae, Z. rouxii is a fructophilic yeast; it consumes fructose faster than glucose. So far, to our knowledge, no specific Z. rouxii proteins responsible for this fructophilic behaviour have been characterized. We have identified two genes encoding putative fructose transporters in the Z. rouxii CBS 732 genome. Heterologous expression of these two Z. rouxii ORFs in a S. cerevisiae strain lacking its own hexose transporters (hxt-null) and subsequent kinetic analysis of sugar transport showed that both proteins are functionally expressed at the plasma membrane: ZrFfz1 is a high-capacity fructose-specific facilitator (K(m)∼400 mM and V(max)∼13 mmol h(-1) g(-1)) and ZrFfz2 is a facilitator transporting glucose and fructose with similar capacity and affinity (K(m)∼200 mM and V(max)∼4 mmol h(-1) g(-1)). These two proteins together with the Zygosaccharomyces bailii Ffz1 fructose-specific transporter belong to a new family of sugar transport systems mediating the uptake of hexoses via the facilitated diffusion mechanism, and are more homologous to drug/H(+) antiporters (regarding their primary protein structure) than to other yeast sugar transporters of the Sugar Porter family.

  1. Traffic Analysis Zones, This Layer was created by ARC's Transportation Planning Division to identify Traffic Analysis Zones (TAZs) in the 20-county Atlanta Region. These TAZs represent the geography used in the ongoing transportation modeling for the Envision 6 forecast series (, Published in 2006, 1:100000 (1in=8333ft) scale, Atlanta Regional Commission.

    Data.gov (United States)

    NSGIC Regional | GIS Inventory — Traffic Analysis Zones dataset current as of 2006. This Layer was created by ARC's Transportation Planning Division to identify Traffic Analysis Zones (TAZs) in the...

  2. Different methods to fabricate efficient planar perovskite solar cells based on solution-processing Nb2O5 as electron transporting layer

    Science.gov (United States)

    Guo, Heng; Yang, Jian; Pu, Bingxue; Zhang, Haiyan; Niu, Xiaobin

    2018-01-01

    Organo-lead perovskites as light harvesters have represented a hot field of research on high-efficiency perovskite solar cells. Previous approaches to increasing the solar cell efficiency have focused on optimization of the morphology of perovskite film. In fact, the electron transporting layer (ETL) also has a significant impact on solar cell performance. Herein, we introduce a facile and low temperature solution-processing method to deposit Nb2O5 film as ETL for PSCs. Based on Nb2O5 ETL, we investigate the effect of the annealing time for the perovskite films via different solution processing, relating it to the perovskite film morphology and its influence on the device working mechanisms. These results shed light on the origin of photovoltaic performance voltage in perovskite solar cells, and provide a path to further increase their efficiency.

  3. Shelf life stability comparison in air for solution processed pristine PDPP3T polymer and doped spiro-OMeTAD as hole transport layer for perovskite solar cell

    Directory of Open Access Journals (Sweden)

    Ashish Dubey

    2016-06-01

    Full Text Available This data in brief includes forward and reverse scanned current density–voltage (J–V characteristics of perovskite solar cells with PDPP3T and spiro-OMeTAD as HTL, stability testing conditions of perovskite solar cell shelf life in air for both PDPP3T and spiro-OMeTAD as HTL as per the description in Ref. [1], and individual J–V performance parameters acquired with increasing time exposed in ambient air are shown for both type of devices using PDPP3T and spiro-OMeTAD as HTL. The data collected in this study compares the device stability with time for both PDPP3T and spiro-OMeTAD based perovskite solar cells and is directly related to our research article “solution processed pristine PDPP3T polymer as hole transport layer for efficient perovskite solar cells with slower degradation” [2].

  4. Improving the conductivity of PEDOT:PSS hole transport layer in polymer solar cells via copper(II) bromide salt doping.

    Science.gov (United States)

    Zhao, Zhiqiang; Wu, Qiliang; Xia, Fei; Chen, Xiang; Liu, Yawei; Zhang, Wenfeng; Zhu, Jun; Dai, Songyuan; Yang, Shangfeng

    2015-01-28

    Copper(II) bromide (CuBr2) salt has been applied to dope poly(3,4-ethylene dioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) as the hole transport layer (HTL) in polymer solar cells (PSCs), improving dramatically the conductivity of PEDOT:PSS film and consequently the device power conversion efficiency (PCE). Under the optimized doping concentration of CuBr2 of 10 mmol·L(-1), PCE of the CuBr2:PEDOT:PSS HTL-incorporated BHJ-PSC device based on poly[N-9″-hepta-decanyl-2,7-carbazole-alt-5,5- (4',7'-di-2-thienyl-2',1',3'- benzothiadiazole) (PCDTBT) and [6,6]-phenyl C71-butyric acid methyl ester (PC71BM) (PCDTBT:PC71BM) reaches 7.05%, which is improved by ∼20.7% compared to that of the reference device based on pristine PEDOT:PSS HTL (5.84%) and represents the highest PCE for PCDTBT:PC71BM-based PSC devices without an electron transport layer (ETL) reported so far. The dramatic improvement of the conductivity of PEDOT:PSS film is interpreted by the weakening of the Coulombic attractions between PEDOT and PSS components. The work function of CuBr2:PEDOT:PSS slightly increases compared to that of the undoped PEDOT:PSS as inferred from scanning Kelvin probe microscopy (SKPM) measurements, contributing to the improved PCE due to the increases of the open-current voltage (Voc) and fill factor (FF).

  5. Solution-Processed Lithium-Doped ZnO Electron Transport Layer for Efficient Triple Cation (Rb, MA, FA) Perovskite Solar Cells.

    Science.gov (United States)

    Mahmud, Md Arafat; Elumalai, Naveen Kumar; Upama, Mushfika Baishakhi; Wang, Dian; Soufiani, Arman Mahboubi; Wright, Matthew; Xu, Cheng; Haque, Faiazul; Uddin, Ashraf

    2017-10-04

    The current work reports the lithium (Li) doping of a low-temperature processed zinc oxide (ZnO) electron transport layer (ETL) for highly efficient, triple-cation-based MA 0.57 FA 0.38 Rb 0.05 PbI 3 (MA: methylammonium, FA: formamidinium, Rb: rubidium) perovskite solar cells (PSCs). Lithium intercalation in the host ZnO lattice structure is dominated by interstitial doping phenomena, which passivates the intrinsic defects in ZnO film. In addition, interstitial Li doping also downshifts the Fermi energy position of Li-doped ETL by 30 meV, which contributes to the reduction of the electron injection barrier from the photoactive perovskite layer. Compared to the pristine ZnO, the power conversion efficiency (PCE) of the PSCs incorporating lithium-doped ZnO (Li-doped) is raised from 14.07 to 16.14%. The superior performance is attributed to the reduced current leakage, enhanced charge extraction characteristics, and mitigated trap-assisted recombination phenomena in Li-doped devices, thoroughly investigated by means of electrochemical impedance spectroscopy (EIS) analysis. Li-doped PSCs also exhibit lower photocurrent hysteresis than ZnO devices, which is investigated with regard to the electrode polarization phenomena of the fabricated devices.

  6. Room-Temperature and Solution-Processable Cu-Doped Nickel Oxide Nanoparticles for Efficient Hole-Transport Layers of Flexible Large-Area Perovskite Solar Cells.

    Science.gov (United States)

    He, Qiqi; Yao, Kai; Wang, Xiaofeng; Xia, Xuefeng; Leng, Shifeng; Li, Fan

    2017-12-06

    Flexible perovskite solar cells (PSCs) using plastic substrates have become one of the most attractive points in the field of thin-film solar cells. Low-temperature and solution-processable nanoparticles (NPs) enable the fabrication of semiconductor thin films in a simple and low-cost approach to function as charge-selective layers in flexible PSCs. Here, we synthesized phase-pure p-type Cu-doped NiO x NPs with good electrical properties, which can be processed to smooth, pinhole-free, and efficient hole transport layers (HTLs) with large-area uniformity over a wide range of film thickness using a room-temperature solution-processing technique. Such a high-quality inorganic HTL allows for the fabrication of flexible PSCs with an active area >1 cm 2 , which have a power conversion efficiency over 15.01% without hysteresis. Moreover, the Cu/NiO x NP-based flexible devices also demonstrate excellent air stability and mechanical stability compared to their counterpart fabricated on the pristine NiO x films. This work will contribute to the evolution of upscaling flexible PSCs with a simple fabrication process and high device performances.

  7. Polymer solar cells with efficiency >10% enabled via a facile solution-processed Al-doped ZnO electron transporting layer

    KAUST Repository

    Jagadamma, Lethy Krishnan

    2015-10-05

    The present work details a facile and low-temperature (125C) solution-processed Al-doped ZnO (AZO) buffer layer functioning very effectively as electron accepting/hole blocking layer for a wide range of polymer:fullerene bulk heterojunction systems, and yielding power conversion efficiency in excess of 10% (8%) on glass (plastic) substrates. We show that ammonia addition to the aqueous AZO nanoparticle solution is a critically important step toward producing compact and smooth thin films which partially retain the aluminum doping and crystalline order of the starting AZO nanocrystals. The ammonia treatment appears to reduce the native defects via nitrogen incorporation, making the AZO film a very good electron transporter and energetically matched with the fullerene acceptor. Importantly, highly efficient solar cells are achieved without the need for additional surface chemical passivation or modification, which has become an increasingly common route to improving the performance of evaporated or solution-processed ZnO ETLs in solar cells.

  8. Role of stochasticity in turbulence and convective intermittent transport at the scrape off layer of Ohmic plasma in QUEST

    Energy Technology Data Exchange (ETDEWEB)

    Banerjee, Santanu, E-mail: sbanerje@ipr.res.in; Ishiguro, M.; Tashima, S.; Mishra, K. [IGSES, Kyushu University, Kasuga, Fukuoka 816-8580 (Japan); Zushi, H.; Hanada, K.; Nakamura, K.; Idei, H.; Hasegawa, M.; Fujisawa, A.; Nagashima, Y.; Matsuoka, K. [RIAM, Kyushu University, Kasuga, Fukuoka 816-8580 (Japan); Nishino, N. [Mechanical System Engineering, Hiroshima University, Hiroshima 739-8527 (Japan); Liu, H. Q. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei, Anhui 230031 (China)

    2014-07-15

    Statistical features of fluctuations are investigated using the fast camera imaging technique in the scrape of layer (SOL) of electron cyclotron resonance heated Ohmic plasma. Fluctuations in the SOL towards low field side are dominated by coherent convective structures (blobs). Two dimensional structures of the higher order moments (skewness s and kurtosis k) representing the shape of probability density function (PDF) are studied. s and k are seen to be functions of the magnetic field lines. s and k are consistently higher towards the bottom half of the vessel in the SOL showing the blob trajectory along the field lines from the top towards bottom of the vessel. Parabolic relation (k=As{sup 2}+C) is observed between s and k near the plasma boundary, featuring steep density gradient region and at the far SOL. The coefficient A, obtained experimentally, indicates a shift of prominence from pure drift-wave instabilities towards fully developed turbulence. Numerical coefficients characterizing the Pearson system are derived which demonstrates the progressive deviation of the PDF from Gaussian towards gamma from the density gradient region, towards the far SOL. Based on a simple stochastic differential equation, a direct correspondence between the multiplicative noise amplitude, increased intermittency, and hence change in PDF is discussed.

  9. Role of stochasticity in turbulence and convective intermittent transport at the scrape off layer of Ohmic plasma in QUEST

    International Nuclear Information System (INIS)

    Banerjee, Santanu; Ishiguro, M.; Tashima, S.; Mishra, K.; Zushi, H.; Hanada, K.; Nakamura, K.; Idei, H.; Hasegawa, M.; Fujisawa, A.; Nagashima, Y.; Matsuoka, K.; Nishino, N.; Liu, H. Q.

    2014-01-01

    Statistical features of fluctuations are investigated using the fast camera imaging technique in the scrape of layer (SOL) of electron cyclotron resonance heated Ohmic plasma. Fluctuations in the SOL towards low field side are dominated by coherent convective structures (blobs). Two dimensional structures of the higher order moments (skewness s and kurtosis k) representing the shape of probability density function (PDF) are studied. s and k are seen to be functions of the magnetic field lines. s and k are consistently higher towards the bottom half of the vessel in the SOL showing the blob trajectory along the field lines from the top towards bottom of the vessel. Parabolic relation (k=As 2 +C) is observed between s and k near the plasma boundary, featuring steep density gradient region and at the far SOL. The coefficient A, obtained experimentally, indicates a shift of prominence from pure drift-wave instabilities towards fully developed turbulence. Numerical coefficients characterizing the Pearson system are derived which demonstrates the progressive deviation of the PDF from Gaussian towards gamma from the density gradient region, towards the far SOL. Based on a simple stochastic differential equation, a direct correspondence between the multiplicative noise amplitude, increased intermittency, and hence change in PDF is discussed

  10. Role of stochasticity in turbulence and convective intermittent transport at the scrape off layer of Ohmic plasma in QUEST

    Science.gov (United States)

    Banerjee, Santanu; Zushi, H.; Nishino, N.; Hanada, K.; Ishiguro, M.; Tashima, S.; Liu, H. Q.; Mishra, K.; Nakamura, K.; Idei, H.; Hasegawa, M.; Fujisawa, A.; Nagashima, Y.; Matsuoka, K.

    2014-07-01

    Statistical features of fluctuations are investigated using the fast camera imaging technique in the scrape of layer (SOL) of electron cyclotron resonance heated Ohmic plasma. Fluctuations in the SOL towards low field side are dominated by coherent convective structures (blobs). Two dimensional structures of the higher order moments (skewness s and kurtosis k) representing the shape of probability density function (PDF) are studied. s and k are seen to be functions of the magnetic field lines. s and k are consistently higher towards the bottom half of the vessel in the SOL showing the blob trajectory along the field lines from the top towards bottom of the vessel. Parabolic relation ( k = A s 2 + C) is observed between s and k near the plasma boundary, featuring steep density gradient region and at the far SOL. The coefficient A, obtained experimentally, indicates a shift of prominence from pure drift-wave instabilities towards fully developed turbulence. Numerical coefficients characterizing the Pearson system are derived which demonstrates the progressive deviation of the PDF from Gaussian towards gamma from the density gradient region, towards the far SOL. Based on a simple stochastic differential equation, a direct correspondence between the multiplicative noise amplitude, increased intermittency, and hence change in PDF is discussed.

  11. Electron transport investigation of layered MoO3 oxides doped with different concentrations of Nb2O5 oxide

    International Nuclear Information System (INIS)

    Al-Khawaja, S.; Kasem, M.

    2008-07-01

    The dc and ac electric conductivity has been studied for numerous samples of molybdenum oxide MoO 3 doped with niobium oxide Nb 2 O 5 elaborated via the solid state reactions. By means of the electric resistivity and dielectricity curves obtained as a function of temperature, and according to the dopant concentration, the behaviour of these compounds has been allocated. Most of the investigated samples, which are insulating at room temperature, have been witnessed to exhibit simultaneously two different electric comportments; metallic and semiconducting within the range of low and high temperatures respectively, designated by a critical temperature related to the nature of the material. Both of these behaviours are attributed electronically to ionic conduction mechanism, occurring in the solid material formed upon doping with Nb 2 O 5 , which is utterly diffused into the layered structure of MoO 3 particularly for x≥40% concentrations and accompanied by relaxation in the dielectric function between 5 Hz and 13 M Hz.(Authors)

  12. Effects of layered heterogeneity in subsurface geologic materials on solute transport under field conditions: A case study from northeastern Iowa, USA

    Science.gov (United States)

    Iqbal, Mohammad Z.

    2000-06-01

    In the Cedar River watershed of northeastern Iowa, USA, water quality in 17 out of 20 private wells indicates that groundwater is contaminated with nitrate from agricultural leachates. In nine of the wells, nitrate concentration exceeds the US Environmental Protection Agency recommended maximum contaminant level (MCL) of 45 mg/L (as NO3 -) for drinking purposes. Solute-transport investigations determined that the surficial loam sediments, the Quaternary sand and gravel deposits, and the glacial till deposits form layered heterogeneity in the subsurface. The resulting conductivity contrast causes a capillary barrier, thereby altering the mechanisms of vertical tracer movement. Storm-water tracing with potassium bromide, corn fertilizer, and fluorescein dye indicates that macropore flow occurs only within the upper 0.9 m of loamy sediments. An average breakthrough concentration of 204 mg/L bromide at 0.3 m depth on day 3 after the storm event supports the hypothesis of macropore flow in the surficial soils. Fluorescein dye was recovered at a depth of 0.3 m with a peak concentration of 650 μg/L at approximately 5 days after the storm event. The loamy sediment layer is underlain by the Iowan Pebble Band, a pebbly layer admixed with sand, developed in post-glacial time. In the field experiments, preferential flow of the tracers was predominantly vertical within the loamy sediments but rapidly changed to a horizontal matrix flow upon entering the materials of higher saturated hydraulic conductivity in the Pebble Band. The Pebble Band is underlain by low-conductivity deposits of pre-Illinoian till. Even though the upper oxidized portion of the glacial till is reported to have macropores, the Pebble Band prevented deeper infiltration of storm water by maintaining a strong component of horizontal hydraulic gradient. Chemical data indicate that the Pebble Band is a hydraulic-conductivity boundary that abruptly changes the unsaturated-flow mechanism from macropore flow to

  13. Employer Branding

    DEFF Research Database (Denmark)

    Frimann, Søren; Mønsted, Bolette Rye

    2012-01-01

    Employer branding er både for den private og den offentlige sektor blevet en måde, de kan imødekomme ændrede arbejdsmarkedsvilkår og organisatoriske udfordringer i en postmoderne og globaliseret verden. Den aktuelle finanskrise har skabt nye udfordringer for organisationer i deres bestræbelser på...... at tiltrække- og fastholde attraktive medarbejdere. Men hvilken betydning har det, når Grundfos siger ”Mennesket er i fokus”, og hvad siger ”mangfoldighed” om Københavns Kommune som arbejdsplads i relation til employer branding? Er der egentlig sammenhæng mellem tankerne bag employer branding og de eksternt...... kommunikerede employer brandprodukter. Eller bliver det unikke ved arbejdspladserne ersattet af buzzwords uden substans og inddragelse af ansatte og interessenter? Artiklen har til formål at vurdere disse spørgsmål på baggrund af analyser af to cases med employer branding....

  14. Parameterization of convective transport in the boundary layer and its impact on the representation of the diurnal cycle of wind and dust emissions

    Directory of Open Access Journals (Sweden)

    F. Hourdin

    2015-06-01

    boundary layer by a mass flux scheme leads to realistic representation of the diurnal cycle of wind in spring, with a maximum near-surface wind in the morning. This maximum occurs when the thermal plumes reach the low-level jet that forms during the night at a few hundred meters above surface. The horizontal momentum in the jet is transported downward to the surface by compensating subsidence around thermal plumes in typically less than 1 h. This leads to a rapid increase of wind speed at surface and therefore of dust emissions owing to the strong nonlinearity of emission laws. The numerical experiments are performed with a zoomed and nudged configuration of the LMDZ general circulation model coupled to the emission module of the CHIMERE chemistry transport model, in which winds are relaxed toward that of the ERA-Interim reanalyses. The new set of parameterizations leads to a strong improvement of the representation of the diurnal cycle of wind when compared to a previous version of LMDZ as well as to the reanalyses used for nudging themselves. It also generates dust emissions in better agreement with current estimates, but the aerosol optical thickness is still significantly underestimated.

  15. Investigation of intermittency and generalized self-similarity of turbulent boundary layers in laboratory and magnetospheric plasmas: towards a quantitative definition of plasma transport features

    International Nuclear Information System (INIS)

    Budaev, V P; Savin, Sergei P; Zelenyi, Lev M

    2011-01-01

    A comparative analysis of the fundamental properties of fluctuations in the vicinity of boundaries in fusion plasmas and in plasmas of magnetospheric turbulent boundary layers (TBLs) shows the similarity of their basic statistical characteristics, including the scaling of the structure functions and mutifractal parameters. Important features observed include intermittent fluctuations and anomalous mass and momentum transport, due to sporadic plasma flow injections with large flow amplitudes occuring with a much higher probability than predicted for classical Gaussian diffusion. Turbulence in edge fusion plasmas and in TBLs exhibits general self-similarity in a wide range of scales extending to the dissipation scale. Experimental scalings obtained for plasma TBLs are compared with neutral fluid results, revealing the universal properties of developed turbulence. TBL scalings are described within the log-Poisson model, which takes quasi-one-dimensional dissipative structures into account. The time (τ) dependence of the mean-square displacement 2 > obtained from the experimental parameters of the log-Poisson distribution takes the form 2 > ∝τ α with α∼ 1.2 - 1.8 and indicates the presence of superdiffusion in the TBLs studied. Determining the nature of the generalized diffusion process from available regular data is a necessary step toward the quantitative description of TBL transport. (reviews of topical problems)

  16. Solution-processed inorganic copper(I) thiocyanate (CuSCN) hole transporting layers for efficient p–i–n perovskite solar cells

    KAUST Repository

    Zhao, Kui

    2015-08-27

    CuSCN is a highly transparent, highly stable, low cost and easy to solution process HTL that is proposed as a low cost replacement to existing organic and inorganic metal oxide hole transporting materials. Here, we demonstrate hybrid organic-inorganic perovskite-based p-i-n planar heterojunction solar cells using a solution-processed copper(I) thiocyanate (CuSCN) bottom hole transporting layer (HTL). CuSCN, with its high workfunction, increases the open circuit voltage (Voc) by 0.23 V to 1.06 V as compared with devices based on the well-known poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) (0.83 V), resulting in a superior power conversion efficiency (PCE) of 10.8% without any notable hysteresis. Photoluminescence measurements suggest a similar efficiency of charge transfer at HTL/perovskite interface as PEDOT:PSS. However, we observe more efficient light harvesting in the presence of CuSCN at shorter wavelengths despite PEDOT:PSS being more transparent. Further investigation of the microstructure and morphology reveals differences in the crystallographic texture of the polycrystalline perovskite film, suggesting somewhat modified perovskite growth on the surface of CuSCN. The successful demonstration of the solution-processed inorganic HTL using simple and low temperature processing routes bodes well for the development of reliable and efficient flexible p-i-n perovskite modules or for integration as a front cell in hybrid tandem solar cells.

  17. Insights into the role of wettability in cathode catalyst layer of proton exchange membrane fuel cell; pore scale immiscible flow and transport processes

    Science.gov (United States)

    Fathi, H.; Raoof, A.; Mansouri, S. H.

    2017-05-01

    The production of liquid water in cathode catalyst layer, CCL, is a significant barrier to increase the efficiency of proton exchange membrane fuel cell. Here we present, for the first time, a direct three-dimensional pore-scale modelling to look at the complex immiscible two-phase flow in CCL. After production of the liquid water at the surface of CCL agglomerates due to the electrochemical reactions, water spatial distribution affects transport of oxygen through the CCL as well as the rate of reaction at the agglomerate surfaces. To explore the wettability effects, we apply hydrophilic and hydrophobic properties using different surface contact angles. Effective diffusivity is calculated under several water saturation levels. Results indicate larger diffusive transport values for hydrophilic domain compared to the hydrophobic media where the liquid water preferentially floods the larger pores. However, hydrophobic domain showed more available surface area and higher oxygen consumption rate at the reaction sites under various saturation levels, which is explained by the effect of wettability on pore-scale distribution of water. Hydrophobic domain, with a contact angle of 150, reveals efficient water removal where only 28% of the pore space stays saturated. This condition contributes to the enhanced available reaction surface area and oxygen diffusivity.

  18. Evidence of horizontal and vertical transport of water in the Southern Hemisphere tropical tropopause layer (TTL from high-resolution balloon observations

    Directory of Open Access Journals (Sweden)

    S. M. Khaykin

    2016-09-01

    Full Text Available High-resolution in situ balloon measurements of water vapour, aerosol, methane and temperature in the upper tropical tropopause layer (TTL and lower stratosphere are used to evaluate the processes affecting the stratospheric water budget: horizontal transport (in-mixing and hydration by cross-tropopause overshooting updrafts. The obtained in situ evidence of these phenomena are analysed using satellite observations by Aura MLS (Microwave Limb Sounder and CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation together with trajectory and transport modelling performed using CLaMS (Chemical Lagrangian Model of the Stratosphere and HYSPLIT (Hybrid Single-Particle Lagrangian Integrated Trajectory model. Balloon soundings were conducted during March 2012 in Bauru, Brazil (22.3° S in the frame of the TRO-Pico campaign for studying the impact of convective overshooting on the stratospheric water budget. The balloon payloads included two stratospheric hygrometers: FLASH-B (Fluorescence Lyman-Alpha Stratospheric Hygrometer for Balloon and Pico-SDLA instrument as well as COBALD (Compact Optical Backscatter Aerosol Detector sondes, complemented by Vaisala RS92 radiosondes. Water vapour vertical profiles obtained independently by the two stratospheric hygrometers are in excellent agreement, ensuring credibility of the vertical structures observed. A signature of in-mixing is inferred from a series of vertical profiles, showing coincident enhancements in water vapour (of up to 0.5 ppmv and aerosol at the 425 K (18.5 km level. Trajectory analysis unambiguously links these features to intrusions from the Southern Hemisphere extratropical stratosphere, containing more water and aerosol, as demonstrated by MLS and CALIPSO global observations. The in-mixing is successfully reproduced by CLaMS simulations, showing a relatively moist filament extending to 20° S. A signature of local cross-tropopause transport of water is observed in

  19. Evidence of horizontal and vertical transport of water in the Southern Hemisphere tropical tropopause layer (TTL) from high-resolution balloon observations

    Science.gov (United States)

    Khaykin, Sergey M.; Pommereau, Jean-Pierre; Riviere, Emmanuel D.; Held, Gerhard; Ploeger, Felix; Ghysels, Melanie; Amarouche, Nadir; Vernier, Jean-Paul; Wienhold, Frank G.; Ionov, Dmitry

    2016-09-01

    High-resolution in situ balloon measurements of water vapour, aerosol, methane and temperature in the upper tropical tropopause layer (TTL) and lower stratosphere are used to evaluate the processes affecting the stratospheric water budget: horizontal transport (in-mixing) and hydration by cross-tropopause overshooting updrafts. The obtained in situ evidence of these phenomena are analysed using satellite observations by Aura MLS (Microwave Limb Sounder) and CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation) together with trajectory and transport modelling performed using CLaMS (Chemical Lagrangian Model of the Stratosphere) and HYSPLIT (Hybrid Single-Particle Lagrangian Integrated Trajectory) model. Balloon soundings were conducted during March 2012 in Bauru, Brazil (22.3° S) in the frame of the TRO-Pico campaign for studying the impact of convective overshooting on the stratospheric water budget. The balloon payloads included two stratospheric hygrometers: FLASH-B (Fluorescence Lyman-Alpha Stratospheric Hygrometer for Balloon) and Pico-SDLA instrument as well as COBALD (Compact Optical Backscatter Aerosol Detector) sondes, complemented by Vaisala RS92 radiosondes. Water vapour vertical profiles obtained independently by the two stratospheric hygrometers are in excellent agreement, ensuring credibility of the vertical structures observed. A signature of in-mixing is inferred from a series of vertical profiles, showing coincident enhancements in water vapour (of up to 0.5 ppmv) and aerosol at the 425 K (18.5 km) level. Trajectory analysis unambiguously links these features to intrusions from the Southern Hemisphere extratropical stratosphere, containing more water and aerosol, as demonstrated by MLS and CALIPSO global observations. The in-mixing is successfully reproduced by CLaMS simulations, showing a relatively moist filament extending to 20° S. A signature of local cross-tropopause transport of water is observed in a particular

  20. Sediment transport and fluid mud layer formation in the macro-tidal Chikugo river estuary during a fortnightly tidal cycle

    Science.gov (United States)

    Azhikodan, Gubash; Yokoyama, Katsuhide

    2018-03-01

    The erosion and deposition dynamics of fine sediment in a highly turbid estuarine channel were successfully surveyed during the period from August 29 to September 12, 2009 using an echo sounder in combination with a high-resolution acoustic Doppler current profiler. Field measurements were conducted focusing on the tide driven dynamics of suspended sediment concentration (SSC), and fluid mud at the upstream of the macrotidal Chikugo river estuary during semidiurnal and fortnightly tidal cycles. Morphological evolution was observed especially during the spring tide over a period of two weeks. The elevation of the channel bed was stable during neap tide, but it underwent fluctuations when the spring tide occurred owing to the increase in the velocity and shear stress. Two days of time lag were observed between the maximum SSC and peak tidal flow, which resulted in the asymmetry between neap-to-spring and spring-to-neap transitions. During the spring tide, a hysteresis loop was observed between shear stress and SSC, and its direction was different during flood and ebb tides. Although both fine sediments and flocs were dominant during flood tides, only fine sediments were noticed during ebb tides. Hence, the net elevation change in the bed was positive, and sedimentation took place during the semilunar tidal cycle. Finally, a bed of consolidated mud was deposited on the initial bed, and the height of the channel bed increased by 0.9 m during the two-week period. The observed hysteretic effect between shear stress and SSC during the spring tides, and the asymmetrical neap-spring-neap tidal cycle influenced the near-bed sediment dynamics of the channel, and led to the formation of a fluid mud layer at the bottom of the river.

  1. How Irreversible Heat Transport Processes Drive Earth's Interdependent Thermal, Structural, and Chemical Evolution Providing a Strongly Heterogeneous, Layered Mantle

    Science.gov (United States)

    Hofmeister, A.; Criss, R. E.

    2013-12-01

    Because magmatism conveys radioactive isotopes plus latent heat rapidly upwards while advecting heat, this process links and controls the thermal and chemical evolution of Earth. We present evidence that the lower mantle-upper mantle boundary is a profound chemical discontinuity, leading to observed heterogeneities in the outermost layers that can be directly sampled, and construct an alternative view of Earth's internal workings. Earth's beginning involved cooling via explosive outgassing of substantial ice (mainly CO) buried with dust during accretion. High carbon content is expected from Solar abundances and ice in comets. Reaction of CO with metal provided a carbide-rich core while converting MgSiO3 to olivine via oxidizing reactions. Because thermodynamic law (and buoyancy of hot particles) indicates that primordial heat from gravitational segregation is neither large nor carried downwards, whereas differentiation forced radioactive elements upwards, formation of the core and lower mantle greatly cooled the Earth. Reference conductive geotherms, calculated using accurate and new thermal diffusivity data, require that heat-producing elements are sequestered above 670 km which limits convection to the upper mantle. These irreversible beginnings limit secular cooling to radioactive wind-down, permiting deduction of Earth's inventory of heat-producing elements from today's heat flux. Coupling our estimate for heat producing elements with meteoritic data indicates that Earth's oxide content has been underestimated. Density sorting segregated a Si-rich, peridotitic upper mantle from a refractory, oxide lower mantle with high Ca, Al and Ti contents, consistent with diamond inclusion mineralogy. Early and rapid differentiation means that internal temperatures have long been buffered by freezing of the inner core, allowing survival of crust as old as ca.4 Ga. Magmatism remains important. Melt escaping though stress-induced fractures in the rigid lithosphere imparts a

  2. Variability of the internal tide on the southern Monterey Bay continental shelf and associated bottom boundary layer sediment transport

    Science.gov (United States)

    Rosenberger, Kurt; Storlazzi, Curt; Cheriton, Olivia

    2016-01-01

    variability in the internal tide, as well as transport of near-bottom sediment in the mid-self mud belt during the relatively quiescent summer months.

  3. Performance Evaluation Model for Application Layer Firewalls.

    Directory of Open Access Journals (Sweden)

    Shichang Xuan

    Full Text Available Application layer firewalls protect the trusted area network against information security risks. However, firewall performance may affect user experience. Therefore, performance analysis plays a significant role in the evaluation of application layer firewalls. This paper presents an analytic model of the application layer firewall, based on a system analysis to evaluate the capability of the firewall. In order to enable users to improve the performance of the application layer firewall with limited resources, resource allocation was evaluated to obtain the optimal resource allocation scheme in terms of throughput, delay, and packet loss rate. The proposed model employs the Erlangian queuing model to analyze the performance parameters of the system with regard to the three layers (network, transport, and application layers. Then, the analysis results of all the layers are combined to obtain the overall system performance indicators. A discrete event simulation method was used to evaluate the proposed model. Finally, limited service desk resources were allocated to obtain the values of the performance indicators under different resource allocation scenarios in order to determine the optimal allocation scheme. Under limited resource allocation, this scheme enables users to maximize the performance of the application layer firewall.

  4. Performance Evaluation Model for Application Layer Firewalls.

    Science.gov (United States)

    Xuan, Shichang; Yang, Wu; Dong, Hui; Zhang, Jiangchuan

    2016-01-01

    Application layer firewalls protect the trusted area network against information security risks. However, firewall performance may affect user experience. Therefore, performance analysis plays a significant role in the evaluation of application layer firewalls. This paper presents an analytic model of the application layer firewall, based on a system analysis to evaluate the capability of the firewall. In order to enable users to improve the performance of the application layer firewall with limited resources, resource allocation was evaluated to obtain the optimal resource allocation scheme in terms of throughput, delay, and packet loss rate. The proposed model employs the Erlangian queuing model to analyze the performance parameters of the system with regard to the three layers (network, transport, and application layers). Then, the analysis results of all the layers are combined to obtain the overall system performance indicators. A discrete event simulation method was used to evaluate the proposed model. Finally, limited service desk resources were allocated to obtain the values of the performance indicators under different resource allocation scenarios in order to determine the optimal allocation scheme. Under limited resource allocation, this scheme enables users to maximize the performance of the application layer firewall.

  5. Student employment

    DEFF Research Database (Denmark)

    Jacob, Marita; Gerth, Maria; Weiss, Felix

    2018-01-01

    In this article, we examine social origin differences in employment patterns across different stages of higher education and compare these differences between vocational and academic fields of study. Using data from a large-scale German student survey, we study the development of inequality, acco...... decrease as students progress through higher education. While we find evidence for this hypothesis, we also show in multivariate models that the reduction of inequality in the student labour market is explained by prior differences between social origin groups.......In this article, we examine social origin differences in employment patterns across different stages of higher education and compare these differences between vocational and academic fields of study. Using data from a large-scale German student survey, we study the development of inequality...

  6. Illegal employment

    Directory of Open Access Journals (Sweden)

    Jana Mervartová

    2013-01-01

    Full Text Available Since 2007 Labour Code contains the definition of dependent work, which can be carried out only in labour-law relations. The Amendment to Labour Code from 2012 makes the definition more precise, when it stipulates essential elements of dependent work and designates the others as conditions, under which dependent work should be carried out. The Amendment to Employment Act changes the definition of illegal work. Illegal work is a performance of dependent work by natural person except for labour-law relation, or if natural person – foreigner carries out work in conflict with issued permission to employment or without this permission. Since 2012 sanctions for illegal work were increased. Labour inspection is entitled to impose sanctions, in case of foreigners it is Customs Office. For control purposes employer is obliged to have copies of documents at the workplace proving the existence of labour-law relation. Goal of controls and high fines is to limit illegal employment of citizens of Czech Republic and foreigners as well. Illegal work has unfavourable economic impact on state budget. It comes to extensive tax evasions and also to evasions within health insurance and social security. If a concluded commercial-law relation meets the attributes of dependent work, then it stands for a concealed legal relationship. Tax Office can subsequently assess an income tax to businessman. Labour-law relationship enjoys a higher legal protection than commercial-law relationship; nonetheless it is not suitable to limit liberty of contract in cases when it is not unambiguously a dependent activity.

  7. 49 CFR 1014.140 - Employment.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 8 2010-10-01 2010-10-01 false Employment. 1014.140 Section 1014.140... HANDICAP IN PROGRAMS OR ACTIVITIES CONDUCTED BY THE SURFACE TRANSPORTATION BOARD § 1014.140 Employment. No qualified handicapped person shall, on the basis of handicap, be subjected to discrimination in employment...

  8. Layered Communications Architecture for the Global Grid

    National Research Council Canada - National Science Library

    White, B. E

    2006-01-01

    ...), the communications infrastructure of the Global Information Grid (GIG). A seven-layer reference model consisting of Mission, Application, Service, Transport, Network, Link, and Physical Layers is introduced...

  9. Stacking layered structure of polymer light emitting diodes prepared by evaporative spray deposition using ultradilute solution for improving carrier balance

    International Nuclear Information System (INIS)

    Aoki, Youichi; Shakutsui, Masato; Fujita, Katsuhiko

    2009-01-01

    Polymer light-emitting diodes (PLEDs) with staking layered structures are prepared by the evaporative spray deposition using ultradilute solution (ESDUS) method, which has enabled forming a polymer layer onto another polymer layer even if both polymers are soluble in a solvent used for the preparation. By this method, polymers having various HOMO and LUMO levels can be stacked as a hole transport layer, an emitting layer and an electron transport layer as commonly employed in small molecule-based organic light emitting diodes. Here we demonstrated that a PLED having a tri-layer structure using three kinds of polymers showed significant improvement in quantum efficiency compared with those having a single or bi-layer structure of corresponding polymers.

  10. Surface tailoring of newly developed amorphous Znsbnd Sisbnd O thin films as electron injection/transport layer by plasma treatment: Application to inverted OLEDs and hybrid solar cells

    Science.gov (United States)

    Yang, Hongsheng; Kim, Junghwan; Yamamoto, Koji; Xing, Xing; Hosono, Hideo

    2018-03-01

    We report a unique amorphous oxide semiconductor Znsbnd Sisbnd O (a-ZSO) which has a small work function of 3.4 eV for as-deposited films. The surface modification of a-ZSO thin films by plasma treatments is examined to apply it to the electron injection/transport layer of organic devices. It turns out that the energy alignment and exciton dissociation efficiency at a-ZSO/organic semiconductor interface significantly changes by choosing different gas (oxygen or argon) for plasma treatments (after a-ZSO was exposed to atmospheric environment for 5 days). In situ ultraviolet photoelectron spectroscopy (UPS) measurement reveals that the work function of a-ZSO is increased to 4.0 eV after an O2-plasma treatment, while the work function of 3.5 eV is recovered after an Ar-plasma treatment which indicates this treatment is effective for surface cleaning. To study the effects of surface treatments to device performance, OLEDs and hybrid polymer solar cells with O2-plasma or Ar-plasma treated a-ZSO are compared. Effects of these surface treatments on performance of inverted OLEDs and hybrid polymer solar cells are examined. Ar-plasma treated a-ZSO works well as the electron injection layer in inverted OLEDs (Alq3/a-ZSO) because the injection barrier is small (∼ 0.1 eV). On the other hands, O2-plasma treated a-ZSO is more suitable for application to hybrid solar cells which is benefiting from higher exciton dissociation efficiency at polymer (P3HT)/ZSO interface.

  11. Opening Doors: Employing the Disabled.

    Science.gov (United States)

    Maurer, Lydia

    The handbook is intended to help employers understand barriers to employment of disabled people. Barriers are examined, including attitudinal, physical (architectural, transportation, site, and equipment), policy and practice barriers (interviewing and recruiting), and communication barriers. Suggestions and guidelines for dealing with the…

  12. The role of parallel heat transport in the relation between upstream scrape-off layer widths and target heat flux width in H-mode plasmas of NSTX.

    Energy Technology Data Exchange (ETDEWEB)

    Ahn, J W; Boedo, J A; Maingi, R; Soukhanovskii, V A

    2009-01-05

    The physics of parallel heat transport was tested in the Scrape-off Layer (SOL) plasma of the National Spherical Torus Experiment (NSTX) [M. Ono, et al., Nucl. Fusion 40, 557 (2000) and S. M. Kaye, et al., Nucl. Fusion 45, S168 (2005)] tokamak by comparing the upstream electron temperature (T{sub e}) and density (n{sub e}) profiles measured by the mid-plane reciprocating probe to the heat flux (q{sub {perpendicular}}) profile at the divertor plate measured by an infrared (IR) camera. It is found that electron conduction explains the near SOL width data reasonably well while the far SOL, which is in the sheath limited regime, requires an ion heat flux profile broader than the electron one to be consistent with the experimental data. The measured plasma parameters indicate that the SOL energy transport should be in the conduction-limited regime for R-R{sub sep} (radial distance from the separatrix location) < 2-3 cm. The SOL energy transport should transition to the sheath-limited regime for R-R{sub sep} > 2-3cm. The T{sub e}, n{sub e}, and q{sub {perpendicular}} profiles are better described by an offset exponential function instead of a simple exponential. The conventional relation between mid plane electron temperature decay length ({lambda}{sub Te}) and target heat flux decay length ({lambda}{sub q}) is {lambda}{sub Te} = 7/2{lambda}{sub q}, whereas the newly-derived relation, assuming offset exponential functional forms, implies {lambda}{sub Te} = (2-2.5){lambda}{sub q}. The measured values of {lambda}{sub Te}/{lambda}{sub q} differ from the new prediction by 25-30%. The measured {lambda}{sub q} values in the far SOL (R-R{sub sep} > 2-3cm) are 9-10cm, while the expected values are 2.7 < {lambda}{sub q} < 4.9 cm (for sheath-limited regime). We propose that the ion heat flux profile is substantially broader than the electron heat flux profile as an explanation for this discrepancy in the far SOL.

  13. Synergetic effects of solution-processable fluorinated graphene and PEDOT as a hole-transporting layer for highly efficient and stable normal-structure perovskite solar cells.

    Science.gov (United States)

    Yu, Jae-Hun; Lee, Cheol-Ho; Joh, Han-Ik; Yeo, Jun-Seok; Na, Seok-In

    2017-11-16

    We demonstrate that a bi-interlayer consisting of water-free poly(3,4-ethylenedioxythiophene) (PEDOT) and fluorinated reduced graphene oxide (FrGO) noticeably enhances the efficiency and the stability of the normal-structure perovskite solar cells (PeSCs). With simple and low temperature solution-processing, the PeSC employing the PEDOT + FrGO interlayer exhibits a significantly improved power conversion efficiency (PCE) of 14.9%. Comprehensive investigations indicate that the enhanced PCE is mostly attributed to the retarded recombination in the devices. The minimized recombination phenomena are related to the interfacial dipoles at the PEDOT/FrGO interface, which facilitates the electron-blocking and the higher built-in potential in the devices. Furthermore, the PEDOT + FrGO device shows a better stability by maintaining 70% of the initial PCE over the 30 days exposure to ambient conditions. This is because the more hydrophobic graphitic sheets of the FrGO on the PEDOT further protect the perovskite films from oxygen/water penetration. Consequently, the introduction of composite interfacial layers including graphene derivatives can be an effective and versatile strategy for high-performing, stable, and cost-effective PeSCs.

  14. Fabrication of a Combustion-Reacted High-Performance ZnO Electron Transport Layer with Silver Nanowire Electrodes for Organic Solar Cells.

    Science.gov (United States)

    Park, Minkyu; Lee, Sang-Hoon; Kim, Donghyuk; Kang, Juhoon; Lee, Jung-Yong; Han, Seung Min

    2018-02-28

    Herein, a new methodology for solution-processed ZnO fabrication on Ag nanowire network electrode via combustion reaction is reported, where the amount of heat emitted during combustion was minimized by controlling the reaction temperature to avoid damaging the underlying Ag nanowires. The degree of participation of acetylacetones, which are volatile fuels in the combustion reaction, was found to vary with the reaction temperature, as revealed by thermogravimetric and compositional analyses. An optimized processing temperature of 180 °C was chosen to successfully fabricate a combustion-reacted ZnO and Ag nanowire hybrid electrode with a sheet resistance of 30 Ω/sq and transmittance of 87%. A combustion-reacted ZnO on Ag nanowire hybrid structure was demonstrated as an efficient transparent electrode and electron transport layer for the PTB7-Th-based polymer solar cells. The superior electrical conductivity of combustion-reacted ZnO, compared to that of conventional sol-gel ZnO, increased the external quantum efficiency over the entire absorption range, whereas a unique light scattering effect due to the presence of nanopores in the combustion-derived ZnO further enhanced the external quantum efficiency in the 450-550 nm wavelength range. A power conversion efficiency of 8.48% was demonstrated for the PTB7-Th-based polymer solar cell with the use of a combustion-reacted ZnO/Ag NW hybrid transparent electrode.

  15. Estimating fate and transport of multiple contaminants in the vadose zone using a multi-layered soil column and three-phase equilibrium partitioning model

    International Nuclear Information System (INIS)

    Rucker, Gregory G.

    2007-01-01

    Soils at waste sites must be evaluated for the potential of residual soil contamination to leach and migrate to the groundwater beneath the disposal area. If migration to the aquifer occurs, contaminants can travel vast distances and pollute drinking water wells, thus exposing human receptors to harmful levels of toxins and carcinogens. To prevent groundwater contamination, a contaminant fate and transport analysis is necessary to assess the migration potential of residual soil contaminants. This type of migration analysis is usually performed using a vadose zone model to account for complex geotechnical and chemical variables including: decay processes, infiltration rate, soil properties, vadose zone thickness, and chemical behavior. The distinct advantage of using a complex model is that less restrictive, but still protective, soil threshold levels may be determined avoiding the unnecessary and costly remediation of marginally contaminated soils. However, the disadvantage of such modeling is the additional cost for data collection and labor required to apply these models. In order to allay these higher costs and to achieve a less restrictive but still protective clean-up level, a multiple contaminant and multi layered soil column equilibrium partitioning model was developed which is faster, simpler and less expensive to use. (authors)

  16. Enhancing the Performance of Quantum Dot Light-Emitting Diodes Using Room-Temperature-Processed Ga-Doped ZnO Nanoparticles as the Electron Transport Layer

    KAUST Repository

    Cao, Sheng

    2017-04-19

    Colloidal ZnO nanoparticle (NP) films are recognized as efficient electron transport layers (ETLs) for quantum dot light-emitting diodes (QD-LEDs) with good stability and high efficiency. However, because of the inherently high work function of such films, spontaneous charge transfer occurs at the QD/ZnO interface in such a QD-LED, thus leading to reduced performance. Here, to improve the QD-LED performance, we prepared Ga-doped ZnO NPs with low work functions and tailored band structures via a room-temperature (RT) solution process without the use of bulky organic ligands. We found that the charge transfer at the interface between the CdSe/ZnS QDs and the doped ZnO NPs was significantly weakened because of the incorporated Ga dopants. Remarkably, the as-assembled QD-LEDs, with Ga-doped ZnO NPs as the ETLs, exhibited superior luminances of up to 44 000 cd/m2 and efficiencies of up to 15 cd/A, placing them among the most efficient red-light QD-LEDs ever reported. This discovery provides a new strategy for fabricating high-performance QD-LEDs by using RT-processed Ga-doped ZnO NPs as the ETLs, which could be generalized to improve the efficiency of other optoelectronic devices.

  17. Modeling the Liquid Water Transport in the Gas Diffusion Layer for Polymer Electrolyte Membrane Fuel Cells Using a Water Path Network

    Directory of Open Access Journals (Sweden)

    Dietmar Gerteisen

    2013-09-01

    Full Text Available In order to model the liquid water transport in the porous materials used in polymer electrolyte membrane (PEM fuel cells, the pore network models are often applied. The presented model is a novel approach to further develop these models towards a percolation model that is based on the fiber structure rather than the pore structure. The developed algorithm determines the stable liquid water paths in the gas diffusion layer (GDL structure and the transitions from the paths to the subsequent paths. The obtained water path network represents the basis for the calculation of the percolation process with low calculation efforts. A good agreement with experimental capillary pressure-saturation curves and synchrotron liquid water visualization data from other literature sources is found. The oxygen diffusivity for the GDL with liquid water saturation at breakthrough reveals that the porosity is not a crucial factor for the limiting current density. An algorithm for condensation is included into the model, which shows that condensing water is redirecting the water path in the GDL, leading to an improved oxygen diffusion by a decreased breakthrough pressure and changed saturation distribution at breakthrough.

  18. Transport-driven scrape-off layer flows and the x-point dependence of the L-H power threshold in Alcator C-Moda)

    Science.gov (United States)

    LaBombard, B.; Rice, J. E.; Hubbard, A. E.; Hughes, J. W.; Greenwald, M.; Granetz, R. S.; Irby, J. H.; Lin, Y.; Lipschultz, B.; Marmar, E. S.; Marr, K.; Mossessian, D.; Parker, R.; Rowan, W.; Smick, N.; Snipes, J. A.; Terry, J. L.; Wolfe, S. M.; Wukitch, S. J.

    2005-05-01

    Factor of ˜2 higher power thresholds for low- to high-confinement mode transitions (L-H) with unfavorable x-point topologies in Alcator C-Mod [Phys. Plasmas 1, 1511 (1994)] are linked to flow boundary conditions imposed by the scrape-off layer (SOL). Ballooning-like transport drives flow along magnetic field lines from low- to high-field regions with toroidal direction dependent on upper/lower x-point balance; the toroidal rotation of the confined plasma responds, exhibiting a strong counter-current rotation when B ×∇B points away from the x point. Increased auxiliary heating power (rf, no momentum input) leads to an L-H transition at approximately twice the edge electron pressure gradient when B ×∇B points away. As gradients rise prior to the transition, toroidal rotation ramps toward the co-current direction; the H mode is seen when the counter-current rotation imposed by the SOL flow becomes compensated. Remarkably, L-H thresholds in lower-limited discharges are identical to lower x-point discharges; SOL flows are also found similar, suggesting a connection.

  19. Nanostructured TiO2/CH3NH3PbI3 heterojunction solar cells employing spiro-OMeTAD/Co-complex as hole-transporting material

    KAUST Repository

    Noh, Jun Hong

    2013-01-01

    For using 2,2′,7,7′-tetrakis(N,N′-di-p- methoxyphenylamine)-9,9′-spirobifluorene (spiro-OMeTAD) as a hole conductor in solar cells, it is necessary to improve its charge-transport properties through electrochemical doping. With the aim of fabricating efficient mesoscopic TiO2/CH3NH3PbI3 heterojunction solar cells, we used tris[2-(1H-pyrazol-1-yl)-4-tert- butylpyridine)cobalt(iii) tris(bis(trifluoromethylsulfonyl) imide)] (FK209) as a p-dopant for spiro-OMeTAD. The mixture of spiro-OMeTAD, FK209, lithium bis(trifluoromethylsulfonyl)imide (Li-TFSI), and 4-tert-butylpyridine (TBP) exhibited significantly higher performance than mixtures of pristine spiro-OMeTAD, spiro-OMeTAD, and FK209, and spiro-OMeTAD, Li-TFSI, and TBP. Such a synergistic effect between the Co-complex and Li-TFSI in conjunction with spiro-OMeTAD effectively improved the power conversion efficiency (PCE) of the fabricated solar cells. As a result, we achieved PCE of 10.4%, measured under standard solar conditions (AM 1.5G, 100 mW cm-2). © 2013 The Royal Society of Chemistry.

  20. Employing big data analytics to monitor transportation impacts in El Paso during Pope’s visit to the US-Mexico border City of Juárez

    Directory of Open Access Journals (Sweden)

    Sushant Sharma

    2017-06-01

    Full Text Available City and state agencies often need guidance to manage traffic demand during special events. The demand and supply uncertainty during a major event makes it challenging to identify an optimal demand management strategy. Hence, agencies take a conventional approach, developing inflexible plans that inherently assume a high demand and congested conditions. Often, perceived supply constraints on the day of “rare” special events leads to reduced demand, resulting in uncongested conditions. This was the case when Pope Francis visited various cities across the US, and later the border city of Juárez near El Paso on the US-Mexico border. This study analyzed the impact of the Papal Visit on El Paso’s transportation system. The results found mostly uncongested traffic conditions and increased travel time reliability when compared with regular weekdays and weekends. People preferred walking and transit over using private vehicles to cross the border to attend either the mass in Juárez or the event in El Paso. The developed methodology and results will be useful for city, state and federal agencies in El Paso to manage travel demand during similar special events.

  1. Fabrication of undoped ZnO thin film via photosensitive sol–gel method and its applications for an electron transport layer of organic solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Luong, Chi Hieu [Department of Materials Science and Engineering and Graduate School of Energy Science and Technology, Chungnam National University, Yuseong-gu, Daejeon 305-764 (Korea, Republic of); Kim, Sarah [Central Research Division, LG Chem., Yuseong-gu, Daejeon 305-738 (Korea, Republic of); Surabhi, Srivathsava; Vo, Thanh Son; Lee, Kyung-Min; Yoon, Soon-Gil [Department of Materials Science and Engineering and Graduate School of Energy Science and Technology, Chungnam National University, Yuseong-gu, Daejeon 305-764 (Korea, Republic of); Jeong, Jun-Ho [Nanomechanical Systems Research Division, Korea Institute of Machinery and Materials, Yuseong-gu, Daejeon 305-343 (Korea, Republic of); Choi, Jun-Hyuk, E-mail: junhyuk@kimm.re.kr [Nanomechanical Systems Research Division, Korea Institute of Machinery and Materials, Yuseong-gu, Daejeon 305-343 (Korea, Republic of); Jeong, Jong-Ryul, E-mail: jrjeong@cnu.ac.kr [Department of Materials Science and Engineering and Graduate School of Energy Science and Technology, Chungnam National University, Yuseong-gu, Daejeon 305-764 (Korea, Republic of)

    2015-10-01

    Highlights: • Investigated the effect of the interfacial ZnO for ETL synthesized by photochemical reaction using photosensitive 2-nitrobenzaldehyde on the inverted P3HT:PCBM OSC. • The abrupt increase of grain size and surface roughness was observed as increasing the annealing temperature above 350 °C. • The sheet resistance abruptly decreased with increasing the annealing temperature above 350 °C. • Increase of surface roughness caused by the high annealing temperature could be detrimental to the OSCs characteristics due to a high contact resistance and a large leakage current. - Abstract: We have investigated ZnO thin films prepared via photochemical reaction as the electron transport layer (ETL) of inverted organic solar cells (OSCs). Morphological and electrical properties of the ZnO thin films prepared by the photosensitive ZnO sol were studied according to the annealing temperature and their effects on the performance of the inverted poly(3-hexylthiophene):phenyl-C61-butyric acid methyl ester (P3HT:PCBM) OSCs was characterized. It was found that the optimal annealing temperature of the ZnO thin films was 330 °C, and that devices with the ZnO ETL annealed at this temperature exhibited the largest short-circuit current density (J{sub sc}) of 9.39 mA/cm{sup 2}, as well as the highest power conversion efficiency (PCE) of 2.31%, which can be attributed to enhanced electron transport and interfacial properties. Devices containing ZnO films formed at optimal annealing condition exhibited an open circuit voltage (V{sub oc}) of 0.60 V and a fill factor (FF) of 41.0%. However, further increase of the annealing temperature led to degradation of the device performance, despite further improvements in electrical properties. We have found that marked increase in the surface roughness of the ZnO films occurred at temperatures above 350 °C which could be detrimental to the OSCs characteristics due to a high contact resistance and a large leakage current.

  2. Assessing the potential of group 13 and 14 metal/metalloid phthalocyanines as hole transport layers in organic light emitting diodes

    Energy Technology Data Exchange (ETDEWEB)

    Plint, Trevor; Lessard, Benoît H. [Department of Chemical Engineering and Applied Chemistry, University of Toronto, 200 College Street, Toronto, Ontario M5S 3E5 (Canada); Bender, Timothy P. [Department of Chemical Engineering and Applied Chemistry, University of Toronto, 200 College Street, Toronto, Ontario M5S 3E5 (Canada); Department of Materials Science and Engineering, University of Toronto, 184 College Street, Toronto, Ontario M5S 3E4 (Canada); Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6 (Canada)

    2016-04-14

    In this study, we have assessed the potential application of group 13 and 14 metal and metalloid phthalocyanines ((X){sub n}-MPcs) and their axially substituted derivatives as hole-transporting layers in organic light emitting diodes (OLEDs). OLEDs studied herein have the generic structure of glass/ITO/(N,N′-di(1-naphthyl)-N,N′-diphenyl-(1,1′-biphenyl)-4,4′-diamine (NPB) or (X){sub n}-MPc)(50 nm)/Alq{sub 3} (60 nm)/LiF (1 nm)/Al (80 nm), where X is an axial substituent group. OLEDs using chloro aluminum phthalocyanine (Cl-AlPc) showed good peak luminance values of 2620 ± 113 cd/m{sup 2} at 11 V. To our knowledge, Cl-AlPc has not previously been shown to work as a hole transport material (HTL) in OLEDs. Conversely, the di-chlorides of silicon, germanium, and tin phthalocyanine (Cl{sub 2}-SiPc, Cl{sub 2}-GePc, and Cl{sub 2}-SnPc, respectively) showed poor performance compared to Cl-AlPc, having peak luminances of only 38 ± 4 cd/m{sup 2} (12 V), 23 ± 1 cd/m{sup 2} (8.5 V), and 59 ± 5 cd/m{sup 2} (13.5 V), respectively. However, by performing a simple axial substitution of the chloride groups of Cl{sub 2}-SiPc with pentafluorophenoxy groups, the resulting bis(pentafluorophenoxy) silicon phthalocyanine (F{sub 10}-SiPc) containing OLED had a peak luminance of 5141 ± 941 cd/m{sup 2} (10 V), a two order of magnitude increase over its chlorinated precursor. This material showed OLED characteristics approaching those of a baseline OLED based on the well-studied triarylamine NPB. Attempts to attach the pentafluorophenoxy axial group to both SnPc and GePc were hindered by synthetic difficulties and low thermal stability, respectively. In light of the performance improvements observed by simple axial substitution of SiPc in OLEDs, the use of axially substituted MPcs in organic electronic devices remains of continuing interest to us and potentially the field in general.

  3. Modeling thermal dynamics of active layer soils and near-surface permafrost using a fully coupled water and heat transport model

    Science.gov (United States)

    Jiang, Yueyang; Zhuang, Qianlai; O'Donnell, Jonathan A.

    2012-01-01

    Thawing and freezing processes are key components in permafrost dynamics, and these processes play an important role in regulating the hydrological and carbon cycles in the northern high latitudes. In the present study, we apply a well-developed soil thermal model that fully couples heat and water transport, to simulate the thawing and freezing processes at daily time steps across multiple sites that vary with vegetation cover, disturbance history, and climate. The model performance was evaluated by comparing modeled and measured soil temperatures at different depths. We use the model to explore the influence of climate, fire disturbance, and topography (north- and south-facing slopes) on soil thermal dynamics. Modeled soil temperatures agree well with measured values for both boreal forest and tundra ecosystems at the site level. Combustion of organic-soil horizons during wildfire alters the surface energy balance and increases the downward heat flux through the soil profile, resulting in the warming and thawing of near-surface permafrost. A projection of 21st century permafrost dynamics indicates that as the climate warms, active layer thickness will likely increase to more than 3 meters in the boreal forest site and deeper than one meter in the tundra site. Results from this coupled heat-water modeling approach represent faster thaw rates than previously simulated in other studies. We conclude that the discussed soil thermal model is able to well simulate the permafrost dynamics and could be used as a tool to analyze the influence of climate change and wildfire disturbance on permafrost thawing.

  4. Experimental and modeling study of the impact of vertical transport processes from the boundary-layer on the variability and the budget of tropospheric ozone; Etude experimentale et numerique de l'influence des processus de transport depuis la couche-limite sur la variabilite et le bilan d'ozone tropospherique

    Energy Technology Data Exchange (ETDEWEB)

    Colette, A

    2005-12-15

    Closing the tropospheric ozone budget requires a better understanding of the role of transport processes from the major reservoirs: the planetary boundary layer and the stratosphere. Case studies lead to the identification of mechanisms involved as well as their efficiency. However, their global impact on the budget must be addressed on a climatological basis. This manuscript is thus divided in two parts. First, we present case studies based on ozone LIDAR measurements performed during the ESCOMPTE campaign. This work consists in a data analysis investigation by means of a hybrid - Lagrangian study involving: global meteorological analyses, Lagrangian particle dispersion computation, and mesoscale, chemistry - transport, and Lagrangian photochemistry modeling. Our aim is to document the amount of observed ozone variability related to transport processes and, when appropriate, to infer the role of tropospheric photochemical production. Second, we propose a climatological analysis of the respective impact of transport from the boundary-layer and from the tropopause region on the tropospheric ozone budget. A multivariate analysis is presented and compared to a trajectography approach. Once validated, this algorithm is applied to the whole database of ozone profiles collected above Europe during the past 30 years in order to discuss the seasonal, geographical and temporal variability of transport processes as well as their impact on the tropospheric ozone budget. The variability of turbulent mixing and its impact on the persistence of tropospheric layers will also be discussed. (author)

  5. Sediment Transport

    DEFF Research Database (Denmark)

    Liu, Zhou

    Flow and sediment transport are important in relation to several engineering topics, e.g. erosion around structures, backfilling of dredged channels and nearshore morphological change. The purpose of the present book is to describe both the basic hydrodynamics and the basic sediment transport...... mechanics. Chapter 1 deals with fundamentals in fluid mechanics with emphasis on bed shear stress by currents, while chapter 3 discusses wave boundary layer theory. They are both written with a view to sediment transport. Sediment transport in rivers, cross-shore and longshore are dealt with in chapters 2...

  6. 36 CFR 1154.140 - Employment.

    Science.gov (United States)

    2010-07-01

    ... 36 Parks, Forests, and Public Property 3 2010-07-01 2010-07-01 false Employment. 1154.140 Section... ARCHITECTURAL AND TRANSPORTATION BARRIERS COMPLIANCE BOARD § 1154.140 Employment. No qualified handicapped person shall, on the basis of handicap, be subjected to discrimination in employment under any program or...

  7. The effect of a Ta oxygen scavenger layer on HfO2-based resistive switching behavior: thermodynamic stability, electronic structure, and low-bias transport.

    Science.gov (United States)

    Zhong, Xiaoliang; Rungger, Ivan; Zapol, Peter; Nakamura, Hisao; Asai, Yoshihiro; Heinonen, Olle

    2016-03-14

    Reversible resistive switching between high-resistance and low-resistance states in metal-oxide-metal heterostructures makes them very interesting for applications in random access memories. While recent experimental work has shown that inserting a metallic "oxygen scavenger layer" between the positive electrode and oxide improves device performance, the fundamental understanding of how the scavenger layer modifies the heterostructure properties is lacking. We use density functional theory to calculate thermodynamic properties and conductance of TiN/HfO2/TiN heterostructures with and without a Ta scavenger layer. First, we show that Ta insertion lowers the formation energy of low-resistance states. Second, while the Ta scavenger layer reduces the Schottky barrier height in the high-resistance state by modifying the interface charge at the oxide-electrode interface, the heterostructure maintains a high resistance ratio between high- and low-resistance states. Finally, we show that the low-bias conductance of device on-states becomes much less sensitive to the spatial distribution of oxygen removed from the HfO2 in the presence of the Ta layer. By providing a fundamental understanding of the observed improvements with scavenger layers, we open a path to engineer interfaces with oxygen scavenger layers to control and enhance device performance. In turn, this may enable the realization of a non-volatile low-power memory technology with concomitant reduction in energy consumption by consumer electronics and offering significant benefits to society.

  8. Estudo das propriedades físicas e de transporte na secagem de cebola (Allium cepa L. em camada delgada Study of the physical and transport properties in the onion (Allium cepa L. drying in thin layer

    Directory of Open Access Journals (Sweden)

    Pierre Corrêa Martins

    2004-09-01

    Full Text Available Neste trabalho estudou-se a cinética de secagem da cebola em camada delgada, comparando os valores da difusividade efetiva média baseados nas espessuras inicial e média das amostras. Estes resultados foram utilizados para a estimativa da temperatura das amostras através de um modelo térmico simplificado. Foram analisadas também as propriedades físicas e de transporte das amostras em função da umidade ao longo da operação. Os ensaios de secagem foram realizados em um secador com escoamento de ar perpendicular à área de seção transversal do leito de amostras de cebola, operando com Tar=60ºC e v ar=1,5m/s. A determinação da umidade de equilíbrio foi obtida através das isotermas de dessorção e a temperatura das amostras foi determinada por meio de um termopar inserido no centro da partícula. As massas específicas das amostras aparente e absoluta foram determinadas através dos métodos indireto e destrutivo, respectivamente. Os valores da difusividade efetiva variável de umidade foram obtidos através do método das tangentes. O modelo térmico simplificado apresentou melhor ajuste com os valores da difusividade efetiva média de secagem, baseados na espessura média. Os valores das massas específicas das amostras de cebola aparente e absoluta foram ajustados em função da umidade através da equação de LOZANO, ROTSTEIN & URBICAIN [10], apresentando coeficientes de correlação maiores que 96%. A redução de espessura do material foi de 80% em relação a da amostra inicial. Os resultados da difusividade efetiva média de umidade, baseados na espessura média das amostras, foram semelhantes aos valores médios da difusividade efetiva variável de umidade para a primeira etapa de secagem.In this work it was studied the onion drying kinetics in thin layer comparing the values of the drying difusivity effective average based on the initial and average thickness of the samples. These results were fitted to a simplified

  9. Copper(I) Thiocyanate (CuSCN) Hole-Transport Layers Processed from Aqueous Precursor Solutions and Their Application in Thin-Film Transistors and Highly Efficient Organic and Organometal Halide Perovskite Solar Cells

    KAUST Repository

    Wijeyasinghe, Nilushi

    2017-07-28

    This study reports the development of copper(I) thiocyanate (CuSCN) hole-transport layers (HTLs) processed from aqueous ammonia as a novel alternative to conventional n-alkyl sulfide solvents. Wide bandgap (3.4–3.9 eV) and ultrathin (3–5 nm) layers of CuSCN are formed when the aqueous CuSCN–ammine complex solution is spin-cast in air and annealed at 100 °C. X-ray photoelectron spectroscopy confirms the high compositional purity of the formed CuSCN layers, while the high-resolution valence band spectra agree with first-principles calculations. Study of the hole-transport properties using field-effect transistor measurements reveals that the aqueous-processed CuSCN layers exhibit a fivefold higher hole mobility than films processed from diethyl sulfide solutions with the maximum values approaching 0.1 cm2 V−1 s−1. A further interesting characteristic is the low surface roughness of the resulting CuSCN layers, which in the case of solar cells helps to planarize the indium tin oxide anode. Organic bulk heterojunction and planar organometal halide perovskite solar cells based on aqueous-processed CuSCN HTLs yield power conversion efficiency of 10.7% and 17.5%, respectively. Importantly, aqueous-processed CuSCN-based cells consistently outperform devices based on poly(3,4-ethylenedioxythiophene) polystyrene sulfonate HTLs. This is the first report on CuSCN films and devices processed via an aqueous-based synthetic route that is compatible with high-throughput manufacturing and paves the way for further developments.

  10. Employers' Guide to the Employment Equity Act

    Directory of Open Access Journals (Sweden)

    Lesley-Anne Katz

    2001-12-01

    Full Text Available Employers' Guide to the Employment Equity Act is aimed, according to the author, at assisting those in the labour arena (employers, managers, labour relations practitioners, union officials, and students to develop a practical understanding of the Employment Equity Act (hereafter, the Act.

  11. Prospects of Ternary Cd1-x Zn x S as an Electron Transport Layer and Associated Interface Defects in a Planar Lead Halide Perovskite Solar Cell via Numerical Simulation

    Science.gov (United States)

    Chowdhury, Towhid Hossain; Ferdaous, Mohammad Tanvirul; Wadi, Mohd. Aizat Abdul; Chelvanathan, Puvaneswaran; Amin, Nowshad; Islam, Ashraful; Kamaruddin, Nurhafiza; Zin, Muhammad Irsyamuddin M.; Ruslan, Mohd Hafidz; Sopian, Kamaruzzaman Bin; Akhtaruzzaman, Md.

    2018-03-01

    In this study we present a ternary alloy, Cd1-x Zn x S as an electron transport layer for a planar lead halide perovskite solar cell via numerical simulation with solar cell capacitance simulator (SCAPS) software. Performance dependence on molar composition variation in the Cd1-x Zn x S alloy was studied for the mixed perovskite CH3NH3PbI3-x Cl x absorber and spiro-OMeTAD hole transport material in a planar perovskite solar cell. Additionally, the defects on both Cd1-x Zn x S/CH3NH3PbI3-x Cl x and CH3NH3PbI3-x Cl x /spiro-OMeTAD interface were thoroughly investigated. Simultaneously, a thickness of 700 nm for CH3NH3PbI3-x Cl x absorber with 50-nm-thick Cd0.2Zn0.8S (x = 0.8) was optimized. Analysis of the numerical solutions via SCAPS provides a trend and pattern for Cd0.2Zn0.8S as an effective electron transport layer for planar perovskite solar cells with a yield efficiency up to 24.83%. The planar perovskite solar cell shows an open-circuit voltage of 1.224 V, short-circuit current density of 25.283 mA/cm2 and a fill factor of 80.22.

  12. High-Performance Nonvolatile Organic Field-Effect Transistor Memory Based on Organic Semiconductor Heterostructures of Pentacene/P13/Pentacene as Both Charge Transport and Trapping Layers.

    Science.gov (United States)

    Li, Wen; Guo, Fengning; Ling, Haifeng; Zhang, Peng; Yi, Mingdong; Wang, Laiyuan; Wu, Dequn; Xie, Linghai; Huang, Wei

    2017-08-01

    Nonvolatile organic field-effect transistor (OFET) memory devices based on pentacene/ N , N '-ditridecylperylene-3,4,9,10-tetracarboxylic diimide (P13)/pentacene trilayer organic heterostructures have been proposed. The discontinuous n-type P13 embedded in p-type pentacene layers can not only provide electrons in the semiconductor layer that facilitates electron trapping process; it also works as charge trapping sites, which is attributed to the quantum well-like pentacene/P13/pentacene organic heterostructures. The synergistic effects of charge trapping in the discontinuous P13 and the charge-trapping property of the poly(4-vinylphenol) (PVP) layer remarkably improve the memory performance. In addition, the trilayer organic heterostructures have also been successfully applied to multilevel and flexible nonvolatile memory devices. The results provide a novel design strategy to achieve high-performance nonvolatile OFET memory devices and allow potential applications for different combinations of various organic semiconductor materials in OFET memory.

  13. Carrier mobility and scattering lifetime in electric double-layer gated few-layer graphene

    Energy Technology Data Exchange (ETDEWEB)

    Piatti, E.; Galasso, S.; Tortello, M.; Nair, J.R.; Gerbaldi, C. [Dipartimento di Scienza Applicata e Tecnologia, Politecnico di Torino, 10129 Torino (Italy); Bruna, M.; Borini, S. [Istituto Nazionale di Ricerca Metrologica (INRIM), 10135 Torino (Italy); Daghero, D. [Dipartimento di Scienza Applicata e Tecnologia, Politecnico di Torino, 10129 Torino (Italy); Gonnelli, R.S., E-mail: renato.gonnelli@polito.it [Dipartimento di Scienza Applicata e Tecnologia, Politecnico di Torino, 10129 Torino (Italy)

    2017-02-15

    Highlights: • We fabricated few-layer graphene FETs by mechanical exfoliation and standard microfabrication techniques. • We employed a Li-TFSI based ion gel to induce carrier densities as high as ≈6e14 e{sup −}/cm{sup 2} in the devices' channel. • We found a strong asymmetry in the sheet conductance and mobility doping dependences between electron and hole doping. • We combined the experimental results with ab initio DFT calculations to obtain the average scattering lifetime of the charge carriers. • We found that the increase in the carrier density and an unexpected increase in the density of charged scattering centers compete in determining the scattering lifetime. - Abstract: We fabricate electric double-layer field-effect transistor (EDL-FET) devices on mechanically exfoliated few-layer graphene. We exploit the large capacitance of a polymeric electrolyte to study the transport properties of three, four and five-layer samples under a large induced surface charge density both above and below the glass transition temperature of the polymer. We find that the carrier mobility shows a strong asymmetry between the hole and electron doping regime. We then employ ab initio density functional theory (DFT) calculations to determine the average scattering lifetime from the experimental data. We explain its peculiar dependence on the carrier density in terms of the specific properties of the electrolyte we used in our experiments.

  14. Employment specialist competencies for supported employment programs

    NARCIS (Netherlands)

    Corbière, M.; Brouwers, E.P.M.; Lanctôt, N.; van Weeghel, J.

    2014-01-01

    Purpose Supported employment (SE) programs are evidence-based programs offered to people with severe mental illness to facilitate obtaining and keeping competitive work. However, significant variations in individuals’ vocational success may be partly explained by differences in their employment

  15. 49 CFR 655.42 - Pre-employment alcohol testing.

    Science.gov (United States)

    2010-10-01

    ... pre-employment alcohol test before the first performance of safety-sensitive functions by every...-employment alcohol test. (d) The employer must conduct all pre-employment alcohol tests using the alcohol... 49 Transportation 7 2010-10-01 2010-10-01 false Pre-employment alcohol testing. 655.42 Section 655...

  16. Public transport

    OpenAIRE

    Lethbridge, Jane

    2008-01-01

    Public transport plays an essential role in enabling people from low income and other disadvantaged groups to access employment and services. It also contributes to the development of social networks and social capital, by helping people to visit friends and relatives and take part in community and other social activities. Public policy makers have begun to recognise that adequate public transport provision can play an important role in reducing social exclusion. [Taken from introductory para...

  17. Chemistry, transport and dry deposition of trace gases in the boundary layer over the tropical Atlantic Ocean and the Guyanas during the GABRIEL field campaign

    NARCIS (Netherlands)

    Stickler, A.; Fischer, H.; Bozem, H.; Gurk, C.; Schiller, C.; Martinez-Harder, M.; Kubistin, D.; Harder, H.; Williams, J.; Eerdekens, G.; Yassaa, N.; Ganzeveld, L.N.; Sander, R.; Lelieveld, J.

    2007-01-01

    We present a comparison of different Lagrangian and chemical box model calculations with measurement data obtained during the GABRIEL campaign over the tropical Atlantic Ocean and the Amazon rainforest in the Guyanas, October 2005. Lagrangian modelling of boundary layer (BL) air constrained by

  18. The Role of Coriolis Forces and Ekman Boundary Layers in Controlling Sediment Transport in Large Submarine Channel-Levee Systems: Experiments and Theory.

    Science.gov (United States)

    Wells, M. G.

    2016-12-01

    Large-scale oceanic flows such as contourite currents and turbidity currents can be strongly influenced by Coriolis forces. One well known consequence of Coriolis forces is the presence of Ekman boundary layers, which result in transverse secondary flows of as much as 10% of the primary flow. For flows in sinuous channels these Ekman boundary layers can either act with, or against, the secondary flows driven by centrifugal forces. These secondary flows driven by Ekman boundary layers are likely responsible for many of the details of sediment erosion and deposition in contourites, as well as in the larger channels formed by turbidity currents. The magnitude and direction of flows in the Ekman boundary layers can be defined by two Rossby numbers, RoW =U/Wf and RoR =U/Rf, where U is the mean downstream velocity, W is the width of the channel, R is the radius of curvature and f is the Coriolis parameter. Flows with Rossby numbers less than 1 are dominated by Coriolis forces and have strong Ekman boundary layers dominating secondary circulation. A new finding is that even when the Rossby number is of order 10 there is an appreciable influence of Coriolis forces. In this presentation we will present results of changes in velocity structure as a function of Rossby number from a series of analog laboratory experiments from a 1 m (Toronto) and 15 m (Grenoble) wide rotating Coriolis platform. Changes in flow structures will be related to experimental observations of changes in erosion and deposition of a mobile bed form. We will discuss the implications of these laboratory experiments for interpretation of large-scale contourite and turbidite deposits.

  19. Accessibility, location, and employment center growth.

    Science.gov (United States)

    2015-03-01

    The purpose of this research is to examine the relationship between accessibility and the : growth of employment centers in order to improve our understanding of how transportation : investments influence the spatial organization of metropolitan area...

  20. Capillary-Driven Transport of Dissolved Salt to the Drying Zone During CO2 Injection in Homogeneous and Layered Porous Media

    NARCIS (Netherlands)

    Roels, S.M.; El Chatib, N.; Nicolaides, C.; Zitha, P.L.J.

    2016-01-01

    A major challenge of CO2 injection into saline aquifers is the risk of formation clogging due to salt precipitation. Capillary-driven flow of brine can provide a continuous transport of dissolved salt toward the dry zone around the injection well where it ultimately precipitates due to evaporation.

  1. Interrelation between the Structural and Transport Properties of Pervaporation Membranes with Diffusion Layers Based on Poly-γ-Benzyl-L-Glutamate

    Czech Academy of Sciences Publication Activity Database

    Kononova, S.V.; Kremnev, R.V.; Baklagina, Yu.G.; Volchek, B.Z.; Vlasova, E.N.; Shabsels, B.M.; Romashkova, K.A.; Romanov, D.P.; Arkhipov, S.N.; Bogomazov, A.V.; Uchytil, Petr

    2011-01-01

    Roč. 56, č. 3 (2011), s. 502-507 ISSN 1063-7745 R&D Projects: GA ČR GA104/09/1165 Institutional research plan: CEZ:AV0Z40720504 Keywords : transport properties * membranes * mixture Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 0.469, year: 2011

  2. Magnetism and transport properties of layered rare-earth cobaltates Ln.sub.0.3./sub.CoO.sub.2./sub

    Czech Academy of Sciences Publication Activity Database

    Knížek, Karel; Novák, Pavel; Jirák, Zdeněk; Hejtmánek, Jiří; Maryško, Miroslav; Buršík, Josef

    2015-01-01

    Roč. 117, č. 17 (2015), "17B706-1"-"17B706-4" ISSN 0021-8979 R&D Projects: GA ČR GA13-03708S Institutional support: RVO:68378271 ; RVO:61388980 Keywords : crystal field * rare earth cobaltates * magnetism and transport properties Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.101, year: 2015

  3. Progress towards vertical transport study of proton-irradiated InAs/GaSb type-II strained-layer superlattice materials for space-based infrared detectors using magnetoresistance measurements

    Science.gov (United States)

    Malone, Mitchell C.; Morath, Christian P.; Fahey, Stephen; Klein, Brianna; Cowan, Vincent M.; Krishna, Sanjay

    2015-09-01

    InAs/GaSb type-II strained-layer superlattice (T2SLS) materials are being considered for space-based infrared detector applications. However, an inadequate understanding of the role of carrier transport, specifically the vertical mobility, in the radiation tolerance of T2SLS detectors remains. Here, progress towards a vertical transport study of proton-irradiated, p-type InAs/GaSb T2SLS materials using magnetoresistance measurements is reported. Measurements in the growth direction of square mesas formed from InAs/GaSb superlattice material were performed using two distinct contact geometries in a Kelvin mode setup at variable magnetic fields, ranging from -9 T to 9 T, and temperatures, ranging from 5 K and 300 K. The results here suggested multi-carrier conduction and a field-dependent series resistance from the contact layer were present. The implications of these results and the plans for future magnetoresistance measurements on proton-irradiated T2SLS materials are discussed.

  4. Novel electrospun gas diffusion layers for polymer electrolyte membrane fuel cells: Part II. In operando synchrotron imaging for microscale liquid water transport characterization

    Science.gov (United States)

    Chevalier, S.; Ge, N.; Lee, J.; George, M. G.; Liu, H.; Shrestha, P.; Muirhead, D.; Lavielle, N.; Hatton, B. D.; Bazylak, A.

    2017-06-01

    This is the second paper in a two-part series in which we investigate the impact of the gas diffusion layer structure on the liquid water distribution in an operating polymer electrolyte membrane (PEM) fuel cell through the procedures of design, fabrication, and testing of novel hydrophobic electrospun gas diffusion layers (eGDLs). In this work, fibre diameters and alignment in eGDLs are precisely controlled, and concurrent synchrotron X-ray radiography and electrochemical impedance spectroscopy (EIS) are used to evaluate the influence of the controlled eGDL parameters on the liquid water distribution and on membrane liquid water content. For eGDLs with small fibre diameters (150-200 nm) and correspondingly smaller pore sizes, reduced liquid water accumulation under the flow field ribs is observed. However, more liquid water is pinned onto the eGDL - at the interface with flow field channels. Orienting fibre alignment perpendicular to the flow field channel direction leads to improved eGDL-catalyst layer contact and prevents rib-channel membrane deformation. On the other hand, eGDLs facilitate significant membrane dry-out, even under highly humidified operating conditions at high current densities.

  5. Metal deposition using seed layers

    Science.gov (United States)

    Feng, Hsein-Ping; Chen, Gang; Bo, Yu; Ren, Zhifeng; Chen, Shuo; Poudel, Bed

    2013-11-12

    Methods of forming a conductive metal layers on substrates are disclosed which employ a seed layer to enhance bonding, especially to smooth, low-roughness or hydrophobic substrates. In one aspect of the invention, the seed layer can be formed by applying nanoparticles onto a surface of the substrate; and the metallization is achieved by electroplating an electrically conducting metal onto the seed layer, whereby the nanoparticles serve as nucleation sites for metal deposition. In another approach, the seed layer can be formed by a self-assembling linker material, such as a sulfur-containing silane material.

  6. Transparent and Highly Responsive Phototransistors Based on a Solution-Processed, Nanometers-Thick Active Layer, Embedding a High-Mobility Electron-Transporting Polymer and a Hole-Trapping Molecule.

    Science.gov (United States)

    Caranzi, Lorenzo; Pace, Giuseppina; Sassi, Mauro; Beverina, Luca; Caironi, Mario

    2017-08-30

    Organic materials are suitable for light sensing devices showing unique features such as low cost, large area, and flexibility. Moreover, transparent photodetectors are interesting for smart interfaces, windows, and display-integrated electronics. The ease of depositing ultrathin organic films with simple techniques enables low light absorbing active layers, resulting in the realization of transparent devices. Here, we demonstrate a strategy to obtain high efficiency organic photodetectors and phototransistors based on transparent active layers with a visible transmittance higher than 90%. The photoactive layer is composed of two phases, each a few nanometers thick. First, an acceptor polymer, which is a good electron-transporting material, on top of which a small molecule donor material is deposited, forming noncontinuous domains. The small molecule phase acts as a trap for holes, thus inducing a high photoconductive gain, resulting in a high photoresponsivity. The organic transparent detectors proposed here can reach very high external quantum efficiency and responsivity values, which in the case of the phototransistors can be as high as ∼74000% and 340 A W -1 at 570 nm respectively, despite an absorber total thickness below 10 nm. Moreover, frequency dependent 2D photocurrent mapping allows discrimination between the contribution of a fast but inefficient and highly spatially localized photoinduced injection mechanism at the electrodes, and the onset of a slower and spatially extended photoconductive process, leading to high responsivity.

  7. Modelling of the material transport and layer formation in the divertor of JET: Comparison of ITER-like wall with full carbon wall conditions

    International Nuclear Information System (INIS)

    Kirschner, A.; Matveev, D.; Borodin, D.; Airila, M.; Brezinsek, S.; Groth, M.; Wiesen, S.; Widdowson, A.; Beal, J.; Esser, H.G.; Likonen, J.; Bekris, N.; Ding, R.

    2015-01-01

    Impurity transport within the inner JET divertor has been modelled with ERO to estimate the transport to and the resulting deposition at remote areas. Various parametric studies involving divertor plasma conditions and strike point position have been performed. In JET-ILW (beryllium main chamber and tungsten divertor) beryllium, flowing from the main chamber into the divertor and then effectively reflected at the tungsten divertor tiles, is transported to remote areas. The tungsten flux to remote areas in L-Mode is in comparison to the beryllium flux negligible due to small sputtering. However, tungsten is sputtered during ELMs in H-Mode conditions. Nevertheless, depending on the plasma conditions, strike point position and the location of the remote area, the maximum resulting tungsten flux to remote areas is at least ∼3 times lower than the corresponding beryllium flux. Modelled beryllium and tungsten deposition on a rotating collector probe located below tile 5 is in good agreement with measurements if the beryllium influx into the inner divertor is assumed to be in the range of 0.1% relative to the deuterium ion flux and erosion due to fast charge exchange neutrals is considered. Comparison between JET-ILW and JET-C is presented

  8. Special Issue: Productive Employment for the Poor.

    Science.gov (United States)

    Gaude, Jacques, Ed.; Miller, Steven, Ed.

    1992-01-01

    This special issue contains nine articles on labor-intensive public works, social investment funds, rural infrastructure projects, grassroots socioeconomic rights, remuneration systems for self-help projects, road construction and rural transport, employment and environmental rehabilitation, and water as a source of employment. (SK)

  9. Influence of polyaniline and phthalocyanine hole-transport layers on the electrical performance of light-emitting diodes using MEH-PPV as emissive material

    Energy Technology Data Exchange (ETDEWEB)

    Brito Santos, Joao Claudio; Paterno, Leonardo Giordano [Depto. de Engenharia de Sistemas Eletronicos - EPUSP, 05508-970, Sao Paulo (Brazil); Dirani, Ely Antonio Tadeu [Depto. de Engenharia de Sistemas Eletronicos - EPUSP, 05508-970, Sao Paulo (Brazil); Depto. de Engenharia Eletrica - FMFT/CCET/PUCSP, 01303-050, Sao Paulo (Brazil)], E-mail: dirani@lme.usp.br; Fonseca, Fernando Josepetti [Depto. de Engenharia de Sistemas Eletronicos - EPUSP, 05508-970, Sao Paulo (Brazil); Andrade, Adnei M. de [Depto. de Engenharia de Sistemas Eletronicos - EPUSP, 05508-970, Sao Paulo (Brazil); Instituto de Eletrotecnica e Energia - IEE/USP, 05508-010, Sao Paulo (Brazil)

    2008-03-31

    The influence of layer-by-layer films of polyaniline and Ni-tetrasulfonated phthalocyanine (PANI/Ni-TS-Pc) on the electrical performance of polymeric light-emitting diodes (PLED) made from (poly[2-methoxy-5-(2'-ethyl-hexyloxy)-1,4-phenylene vinylene]) (MEH-PPV) is investigated by using current versus voltage measurements and impedance spectroscopy. The PLED is composed by a thin layer of MEH-PPV sandwiched between indium tin oxide (ITO) and aluminum electrodes, resulting in the device structure ITO/(PANI/Ni-TS-Pc){sub n}/MEH-PPV/Al, where n stands for the number of PANI/Ni-TS-Pc bilayers. The deposition of PANI/Ni-TS-Pc leads to a decrease in the driving voltage of the PLEDs, which reaches a minimum when n = 5 bilayers. In addition, impedance spectroscopy data reveal that the PLED impedance decreases as more PANI/Ni-TS-Pc bilayers are deposited. The PLED structure is further described by an equivalent circuit composed by two R-C combinations, one for the bulk and other for the interface components, in series with a resistance originated in the ITO contact. From the impedance curves, the values for each circuit element is determined and it is found that both, bulk and interface resistances are decreased upon PANI/Ni-TS-Pc deposition. The results indicate that PANI/Ni-TS-Pc films reduce the contact resistance at ITO/MEH-PPV interface, and for that reason improve the hole-injection within the PLED structure.

  10. Tunneling and Transport in Nanowires

    International Nuclear Information System (INIS)

    Goldman, Allen M.

    2016-01-01

    The goal of this program was to study new physical phenomena that might be relevant to the performance of conductive devices and circuits of the smallest realizable feature sizes possible using physical rather than biological techniques. Although the initial scientific work supported involved the use of scanning tunneling microscopy and spectroscopy to ascertain the statistics of the energy level distribution of randomly sized and randomly shaped quantum dots, or nano-crystals, the main focus was on the investigation of selected properties, including superconductivity, of conducting and superconducting nanowires prepared using electron-beam-lithography. We discovered a magnetic-field-restoration of superconductivity in out-of-equilibrium nanowires driven resistive by current. This phenomenon was explained by the existence of a state in which dissipation coexisted with nonvanishing superconducting order. We also produced ultra-small superconducting loops to study a predicted anomalous fluxoid quantization, but instead, found a magnetic-field-dependent, high-resistance state, rather than superconductivity. Finally, we developed a simple and controllable nanowire in an induced charged layer near the surface of a masked single-crystal insulator, SrTiO 3 . The layer was induced using an electric double layer transistor employing an ionic liquid (IL). The transport properties of the induced nanowire resembled those of collective electronic transport through an array of quantum dots.

  11. Tunneling and Transport in Nanowires

    Energy Technology Data Exchange (ETDEWEB)

    Goldman, Allen M. [Univ. of Minnesota, Minneapolis, MN (United States)

    2016-08-16

    The goal of this program was to study new physical phenomena that might be relevant to the performance of conductive devices and circuits of the smallest realizable feature sizes possible using physical rather than biological techniques. Although the initial scientific work supported involved the use of scanning tunneling microscopy and spectroscopy to ascertain the statistics of the energy level distribution of randomly sized and randomly shaped quantum dots, or nano-crystals, the main focus was on the investigation of selected properties, including superconductivity, of conducting and superconducting nanowires prepared using electron-beam-lithography. We discovered a magnetic-field-restoration of superconductivity in out-of-equilibrium nanowires driven resistive by current. This phenomenon was explained by the existence of a state in which dissipation coexisted with nonvanishing superconducting order. We also produced ultra-small superconducting loops to study a predicted anomalous fluxoid quantization, but instead, found a magnetic-field-dependent, high-resistance state, rather than superconductivity. Finally, we developed a simple and controllable nanowire in an induced charged layer near the surface of a masked single-crystal insulator, SrTiO3. The layer was induced using an electric double layer transistor employing an ionic liquid (IL). The transport properties of the induced nanowire resembled those of collective electronic transport through an array of quantum dots.

  12. Becoming Self-Employed.

    Science.gov (United States)

    Lee, Grant; Cochran, Larry

    1997-01-01

    Explored how persons become self-employed. In critical incident interviews with five self-employed persons the critical events that assisted or hindered progress toward self-employment were listed in chronological order. In general, becoming self-employed involved establishing conditions of action that enhanced a sense of agency, thus enabling…

  13. Numerical modelling of transient heat transport in a two-layered metal film using the fuzzy lattice Boltzmann method with α-cuts

    Science.gov (United States)

    Piasecka-Belkhayat, Alicja; Korczak, Anna

    2018-01-01

    In the paper a description of heat transfer in a one-dimensional two-layered metal film is considered. The fuzzy coupled lattice Boltzmann equations for electrons and phonons supplemented by appropriate boundary and initial conditions are applied to analyse the thermal process in a thin metal film. The model with fuzzy values of relaxation times and boundary-initial conditions for gold and titanium is proposed. The problem considered is solved by the fuzzy lattice Boltzmann method using α-cuts and the rules of directed interval arithmetic. The application of α-cuts allows one to avoid complicated arithmetical operations in the fuzzy numbers set. In the final part of the paper an example for a numerical solution is presented.

  14. Chemistry, transport and dry deposition of trace gases in the boundary layer over the tropical Atlantic Ocean and the Guyanas during the GABRIEL field campaign

    Directory of Open Access Journals (Sweden)

    A. Stickler

    2007-07-01

    Full Text Available We present a comparison of different Lagrangian and chemical box model calculations with measurement data obtained during the GABRIEL campaign over the tropical Atlantic Ocean and the Amazon rainforest in the Guyanas, October 2005. Lagrangian modelling of boundary layer (BL air constrained by measurements is used to derive a horizontal gradient (≈5.6 pmol/mol km−1 of CO from the ocean to the rainforest (east to west. This is significantly smaller than that derived from the measurements (16–48 pmol/mol km−1, indicating that photochemical production from organic precursors alone cannot explain the observed strong gradient. It appears that HCHO is overestimated by the Lagrangian and chemical box models, which include dry deposition but not exchange with the free troposphere (FT. The relatively short lifetime of HCHO implies substantial BL-FT exchange. The mixing-in of FT air affected by African and South American biomass burning at an estimated rate of 0.12 h−1 increases the CO and decreases the HCHO mixing ratios, improving agreement with measurements. A mean deposition velocity of 1.35 cm/s for H2O2 over the ocean as well as over the rainforest is deduced assuming BL-FT exchange adequate to the results for CO. The measured increase of the organic peroxides from the ocean to the rainforest (≈0.66 nmol/mol d−1 is significantly overestimated by the Lagrangian model, even when using high values for the deposition velocity and the entrainment rate. Our results point at either heterogeneous loss of organic peroxides and/or their radical precursors, underestimated photodissociation or missing reaction paths of peroxy radicals not forming peroxides in isoprene chemistry. We calculate a mean integrated daytime net ozone production (NOP in the BL of (0.2±5.9 nmol/mol (ocean and (2.4±2.1 nmol/mol (rainforest. The NOP strongly correlates with NO and has a positive tendency in

  15. Concentration polarization: Electrodeposition and transport phenomena at overlimiting current

    DEFF Research Database (Denmark)

    Nielsen, Christoffer Peder

    . Secondly, we investigate concentration polarization in a microchannel with charged walls. We provide full numerical solutions to the transport problem, including the effects of advection and surface conduction in the electric double layers. We show that in large areas of the relevant parameter space...... the transport can be understood in terms of a group of simple analytical models. Some of these are generalizations of a previously published analytical model. In addition to the full numerical model, we employ a numerical boundary layer model with a slip velocity. By carefully comparing the full model...... and the boundary layer model, we reveal a number of issues, which invalidate most previous attempts at modeling microchannel concentration polarization using a slip model. Returning to concentration polarization in a bulk system, we study the effects of water splitting at a permselective membrane. We investigate...

  16. Efficiency enhancement of regular-type perovskite solar cells based on Al-doped ZnO nanorods as electron transporting layers

    Science.gov (United States)

    Huang, Zheng-Lun; Chen, Chih-Ming; Lin, Zheng-Kun; Yang, Sheng-Hsiung

    2017-02-01

    In this paper, we first incorporated Al(NO3)3·9H2O as the Al source into ZnO nanorods (NRs) lattice via the hydrothermal method to modify nature properties of ZnO NRs for the fabrication of perovskite solar cells (PSCs). The X-ray diffraction (XRD) pattern of Al-doped ZnO NRs exhibits higher 2θ values and stronger intensity of (002) plane. Larger optical band gap and higher electrical conductivity of Al-doped ZnO NRs are also observed relative to non-doped ZnO ones. The steady-state photoluminescence shows effective charge extraction and collection at the interface between Al-doped ZnO NRs and perovskite layer. The optimized PSC based on Al-doped ZnO NRs showed an open-circuit voltage of 0.84 V, a short-circuit current density of 21.93 mA/cm2, a fill factor of 57%, and a power conversion efficiency of 10.45% that was 23% higher than the non-doped ZnO ones.

  17. Catalyst containing oxygen transport membrane

    Science.gov (United States)

    Christie, Gervase Maxwell; Wilson, Jamie Robyn; van Hassel, Bart Antonie

    2012-12-04

    A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

  18. Magnetic, thermal, and transport properties of layered arsenides BaRu2As2 and SrRu2As2

    Science.gov (United States)

    Nath, R.; Singh, Yogesh; Johnston, D. C.

    2009-05-01

    The magnetic, thermal, and transport properties of polycrystalline BaRu2As2 and SrRu2As2 samples with the ThCr2Si2 structure were investigated by means of magnetic susceptibility χ(T) , electrical resistivity ρ(T) , and heat capacity Cp(T) measurements. The temperature (T) dependence of ρ indicates metallic character for both compounds with residual resistivity ratios ρ(310K)/ρ(2K) of 17 and 5 for the Ba and Sr compounds, respectively. The Cp(T) results reveal a low- T Sommerfeld coefficient γ=4.9(1) and 4.1(1)mJ/molK2 and Debye temperature ΘD=271(7) and 271(4) K for the Ba and Sr compounds, respectively. The χ(T) was found to be diamagnetic with a small absolute value for both compounds. No transitions were found for BaRu2As2 above 1.8 K. The χ(T) data for SrRu2As2 exhibit a cusp at ˜200K , possibly an indication of a structural and/or magnetic transition. We discuss the properties of BaRu2As2 and SrRu2As2 in the context of other ThCr2Si2 -type and ZrCuSiAs-type transition metal pnictides.

  19. Perspectives of employability skills

    OpenAIRE

    ANNE LOUISE NEWTON

    2017-01-01

    The study investigated the different perspectives held by young people, employers and policy makers around Employability Skills and it examined how young people learnt these skills. This study draws young peoples’ perspectives into the research around Employability Skills and highlights the way in which social and cultural capital mediate their development. The research points to a model to re-vision employability skills which recognises the many ways in which they are learnt, over time a...

  20. A re-examination of the minor role of unstirred layers during the measurement of transport coefficients of Chara corallina internodes with the cell pressure probe.

    Science.gov (United States)

    Ye, Qing; Kim, Yangmin; Steudle, Ernst

    2006-05-01

    The impact of unstirred layers (USLs) during cell pressure probe experiments with Chara corallina internodes has been quantified. The results show that the hydraulic conductivity (Lp) measured in hydrostatic relaxations was not significantly affected by USLs even in the presence of high water flow intensities ('sweep-away effect'). During pressure clamp, there was a reversible reduction in Lp by 20%, which was explained by the constriction of water to aquaporins (AQPs) in the C. corallina membrane and a rapid diffusional equilibration of solutes in arrays where water protruded across AQPs. In osmotic experiments, Lp, and permeability (Ps) and reflection (sigma s) coefficients increased as external flow rate of medium increased, indicating some effects of external USLs. However, the effect was levelling off at 'usual' flow rates of 0.20-0.30 m s(-1) and in the presence of vigorous stirring by air bubbles, suggesting a maximum thickness of external USLs of around 30 microm including the cell wall. Because the diameters of internodes were around 1 mm, internal USLs could have played a significant or even a dominating role, at least in the presence of the rapidly permeating solutes used [acetone, 2-propanol and dimethylformamide (DMF)]. A comparison of calculated (diffusion kinetics) and of measured permeabilities indicated an upper limit of the contribution of USLs for the rapidly moving solute acetone of 29%, and of 15% for the less rapidly permeating DME The results throw some doubt on recent claims that in C. corallina, USLs rather than the cell membrane dominate solute uptake, at least for the most rapidly moving solute acetone.

  1. Study of the effect of soil disturbance on vapor transport through integrated modeling of the atmospheric boundary layer and shallow subsurface

    Science.gov (United States)

    Trautz, A.; Smits, K. M.; Cihan, A.; Wallen, B.

    2014-12-01

    Soil-water evaporation is one of the governing processes responsible for controlling water and energy exchanges between the land and atmosphere. Despite its wide relevance and application in many natural and manmade environments (e.g. soil tillage practices, wheel-track compaction, fire burn environments, textural layering and buried ordinances), there are very few studies of evaporation from disturbed soil profiles. The purpose of this study was to explore the effect of soil disturbance and capillary coupling on water distribution and fluxes. We modified a theory previously developed by the authors that allows for coupling single-phase (gas), two-component (air and water vapor) transfer in the atmosphere and two-phase (gas, liquid), two-component (air and water vapor) flow in porous media at the REV scale under non-isothermal, non-equilibrium conditions to better account for the hydraulic and thermal interactions within the media. Modeling results were validated and compared using precision data generated in a two-dimensional soil tank consisting of a loosely packed soil surrounded by a tightly packed soil. The soil tank was outfitted with an array of sensors for the measurement of wind velocity, soil and air temperature, relative humidity, soil moisture, and weight. Results demonstrated that, by using this coupling approach, it is possible to predict the different stages of the drying process in heterogeneous soils with good accuracy. Evaporation from a heterogeneous soil consisting of a loose and tight packing condition is larger than the homogeneous equivalent systems. Liquid water is supplied from the loosely packed soil region to the tightly packed soil regions, sustaining a longer Stage I evaporation in the tightly packed regions with overall greater evaporation rate than uniform homogeneous packing. In contrast, lower evaporation rates from the loosely packed regions are observed due to a limited liquid water supply resulting from capillary flow to the

  2. Social innovation in employment

    NARCIS (Netherlands)

    Oeij, P.R.A.; Torre, W. van der; Santoclides, M.E

    2017-01-01

    This policy brief on Social Innovation of Employment informs on an inventory of challenges and policy recommendations based on the Case Study Report of Employment and on the Second Policy Foresight Workshop of Employment. A ‘paradigm shift’ is needed in the mind-set of policymakers. ‘Traditional’

  3. Youth employment in Egypt

    OpenAIRE

    Eekelen, Willem van; De Luca, Loretta; Ismail, Magwa

    2001-01-01

    Examines economic and social factors affecting youth employment in Egypt and describes three national programmes for the promotion of youth employment based on human resources development, direct job creation and support in self-employment and enterprise creation. Describes one public-private project in each case.

  4. Magnetic, Thermodynamic, and Transport Properties of Layered Arsenides BaRu2As2 and SrRu2As2

    Science.gov (United States)

    Nath, R.; Singh, Y.; Johnston, D. C.

    2009-03-01

    As part of our effort to search for novel superconductors related to the FeAs high-T superconductors, we have synthesized polycrystalline samples of BaRu2As2 and SrRu2As2. The magnetic, transport and thermodynamic properties of the samples were investigated by means of magnetic susceptibility χ(T), electrical resistivity ρ(T), and heat capacity Cp(T) measurements. The temperature dependence of ρ indicates metallic character for both compounds with a residual resistivity ratio ρ(310 K)/ρ(2 K) of 17 and 7 for the Ba and Sr compounds, respectively. The Cp(T) results indicate a low density of states at the Fermi level with the low-T Sommerfeld coefficient γ˜4.9 and 4.13 mJ/mole K^2 for the Ba and Sr compounds, respectively. The Debye temperature θD was estimated to be 270 K and 260 K for the Ba and Sr compounds, respectively. The χ(T) was found to be diamagnetic with a small absolute value for both the compounds. No evidence for superconductivity, a spin density wave, or a structural transition was observed from the Cp(T) and ρ(T) measurements down to 2 K. However, the χ(T) data for SrRu2As2 exhibit a cusp at ˜190 K, possibly an indication of a structural and/or magnetic transition.* Supported by the USDOE under contact No. DE-AC02-07CH11358.

  5. Identifying Opportunities for Exploiting Cross-Layer Interactions in Adaptive Wireless Systems

    Directory of Open Access Journals (Sweden)

    Troy Weingart

    2007-01-01

    Full Text Available The flexibility of cognitive and software-defined radio heralds an opportunity for researchers to reexamine how network protocol layers operate with respect to providing quality of service aware transmission among wireless nodes. This opportunity is enhanced by the continued development of spectrally responsive devices—ones that can detect and respond to changes in the radio frequency environment. Present wireless network protocols define reliability and other performance-related tasks narrowly within layers. For example, the frame size employed on 802.11 can substantially influence the throughput, delay, and jitter experienced by an application, but there is no simple way to adapt this parameter. Furthermore, while the data link layer of 802.11 provides error detection capabilities across a link, it does not specify additional features, such as forward error correction schemes, nor does it provide a means for throttling retransmissions at the transport layer (currently, the data link and transport layer can function counterproductively with respect to reliability. This paper presents an analysis of the interaction of physical, data link, and network layer parameters with respect to throughput, bit error rate, delay, and jitter. The goal of this analysis is to identify opportunities where system designers might exploit cross-layer interactions to improve the performance of Voice over IP (VoIP, instant messaging (IM, and file transfer applications.

  6. Accident resistant transport container

    Science.gov (United States)

    Anderson, J.A.; Cole, K.K.

    The invention relates to a container for the safe air transport of plutonium having several intermediate wood layers and a load spreader intermediate an inner container and an outer shell for mitigation of shock during a hypothetical accident.

  7. Stacking dependence of carrier transport properties in multilayered black phosphorous.

    Science.gov (United States)

    Sengupta, A; Audiffred, M; Heine, T; Niehaus, T A

    2016-02-24

    We present the effect of different stacking orders on carrier transport properties of multi-layer black phosphorous. We consider three different stacking orders AAA, ABA and ACA, with increasing number of layers (from 2 to 6 layers). We employ a hierarchical approach in density functional theory (DFT), with structural simulations performed with generalized gradient approximation (GGA) and the bandstructure, carrier effective masses and optical properties evaluated with the meta-generalized gradient approximation (MGGA). The carrier transmission in the various black phosphorous sheets was carried out with the non-equilibrium green's function (NEGF) approach. The results show that ACA stacking has the highest electron and hole transmission probabilities. The results show tunability for a wide range of band-gaps, carrier effective masses and transmission with a great promise for lattice engineering (stacking order and layers) in black phosphorous.

  8. General Outside Employment

    Data.gov (United States)

    Montgomery County of Maryland — This dataset contains all outside employment requests held by employees of Montgomery County (excluding uniformed police officer) approved by the Ethics Commission...

  9. Youth-Education-Employment.

    Science.gov (United States)

    Wirtz, Willard; And Others

    The document presents the proceedings of an international symposium analyzing the relationship among youth, education, and employment, with emphasis on youth employment trends and the need to find solutions for unemployment problems. The objectives are to evaluate the existing relationship in the light of changing values and expectations of young…

  10. Homosexual Discrimination in Employment

    Science.gov (United States)

    Siniscalco, Gary R.

    1976-01-01

    Recent developments in homosexual activism regarding employment problems in both the public and private sector are analyzed. Focus is on the law governing private employment, where homosexuals are afforded the least legal protection against discrimination. Available from: the University of Santa Clara, Santa Clara, California 95053. (LBH)

  11. Maine's Employability Skills Program

    Science.gov (United States)

    McMahon, John M.; Wolffe, Karen E.; Wolfe, Judy; Brooker, Carrie

    2013-01-01

    This Practice Report describes the development and implementation of the "Maine Employability Skills Program," a model employment program developed by the Maine Division for the Blind and Visually Impaired (DBVI). The program was designed to support the efforts of the chronically unemployed or underemployed. These consumers were either…

  12. Employment Challenges in Kenya

    African Journals Online (AJOL)

    Dr Kazungu

    Key Words: Employment Challenge, Employment Policy, Kenya. 1.0 Context ... Fiscal Measures. √. ×. √. Source: own elaboration based on government documents. Key: √- policy measure present; ×- policy measure not present ..... are Republic of Korea (1960–2001); Malaysia (1967–1997); Malta (1963–1994); Oman.

  13. Dimensions of Adolescent Employment.

    Science.gov (United States)

    Mael, Fred A.; Morath, Ray A.; McLellan, Jeffrey A.

    1997-01-01

    Examines positive and negative correlates of adolescent work as a function of work dimensions. Results indicate that concurrent costs and benefits of adolescent employment may depend on dimensions of work as well as adolescent characteristics. Adolescent employment was generally related to subsequent work motivation and nonacademic performance.…

  14. 49 CFR 219.502 - Pre-employment alcohol testing.

    Science.gov (United States)

    2010-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION CONTROL OF ALCOHOL AND DRUG USE Pre-Employment Tests § 219.502 Pre... must comply with the following requirements: (1) It must conduct a pre-employment alcohol test before... the purpose of pre-employment alcohol testing (i.e., it must not test some covered employees and not...

  15. 49 CFR 25.435 - Employment assistance to students.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 1 2010-10-01 2010-10-01 false Employment assistance to students. 25.435 Section... Basis of Sex in Education Programs or Activities Prohibited § 25.435 Employment assistance to students... agency, organization, or person in making employment available to any of its students: (1) Shall assure...

  16. Crack layer theory

    Science.gov (United States)

    Chudnovsky, A.

    1987-01-01

    A damage parameter is introduced in addition to conventional parameters of continuum mechanics and consider a crack surrounded by an array of microdefects within the continuum mechanics framework. A system consisting of the main crack and surrounding damage is called crack layer (CL). Crack layer propagation is an irreversible process. The general framework of the thermodynamics of irreversible processes are employed to identify the driving forces (causes) and to derive the constitutive equation of CL propagation, that is, the relationship between the rates of the crack growth and damage dissemination from one side and the conjugated thermodynamic forces from another. The proposed law of CL propagation is in good agreement with the experimental data on fatigue CL propagation in various materials. The theory also elaborates material toughness characterization.

  17. Institutionalized Employer Collective Action

    DEFF Research Database (Denmark)

    Ibsen, Christian Lyhne; Navrbjerg, Steen Erik

    2016-01-01

    Recent studies show that employer associations continue to exist in new ways despite internationalisation of the economy, liberalisation of markets and the decline of trade unions. This paradox raises two questions regarding EOs in today’s labour markets: Which employers join employer associations...... and what kind of services do EOs offer employers? This article explores these questions using two comprehensive surveys on EOs in Denmark – a prominent case of coordinated market economies. The main finding of the analyses is that collective activities vis-à-vis trade unions and government are still...... important but that individual and selective goods are just as important for recruitment and retention of members. The most important predictor of EO-membership is the existence of a collective agreement. Local union power and representation is not significant which supports the idea that EOs...

  18. Youth Employment and Unemployment

    Science.gov (United States)

    OECD Observer, 1977

    1977-01-01

    Discusses youth employment and unemployment in Canada, France, Germany, Italy, Japan, United Kingdom, and the United States; the trends, causes, consequences, policy goals, and specific measures needed to resolve problems. (SL)

  19. Dependence of the Efficiency of Spin Hall Torque on the Transparency of Pt-Ferromagnetic Layer Interfaces

    OpenAIRE

    Pai, Chi-Feng; Ou, Yongxi; Ralph, D. C.; Buhrman, R. A.

    2014-01-01

    We report that spin current transport across Pt-ferromagnet (FM) interfaces is strongly dependent on the type and the thickness of the FM layer and on post-deposition processing protocols. By employing both harmonic voltage measurements and spin-torque ferromagnetic resonance measurements, we find that the efficiency of the Pt spin Hall effect in exerting a damping-like spin torque on the FM ranges from 0.10 under different interfacial conditions. We also show that the temperature...

  20. Employers meet employees

    OpenAIRE

    Scheuer, Christian

    2009-01-01

    "Leaping into the future of labor economics: the research potential of linking employer and employee data" is the title of a paper by Daniel S Hammermesh published in Labour Economics in 1999. I quote it here, since it captures much of my motivation for the work included in this thesis. Considering applied micro econometrics and labor economics my main elds of interest, the development of linked employer-employee data that took place in Denmark around the time of the new mille...

  1. Deficiency of employability capacity

    Directory of Open Access Journals (Sweden)

    Pelse I.

    2012-10-01

    Full Text Available Young unemployed people have comprised one of the significantly largest groups of the unemployed people in Latvia in recent years. One of the reasons why young people have difficulty integrating into the labour market is the “expectation gap” that exists in the relations between employers and the new generation of workers. Employers focus on capacity-building for employability such individual factors as strength, patience, self-discipline, self-reliance, self-motivation, etc., which having a nature of habit and are developed in a long-term work socialization process, which begins even before the formal education and will continue throughout the life cycle. However, when the socialization is lost, these habits are depreciated faster than they can be restored. Currently a new generation is entering the labour market, which is missing the succession of work socialization. Factors, such as rising unemployment and poverty in the background over the past twenty years in Latvia have created a very unfavourable employability background of “personal circumstances” and “external factors”, which seriously have impaired formation of the skills and attitudes in a real work environment. The study reveals another paradox – the paradox of poverty. Common sense would want to argue that poverty can be overcome by the job. However, the real state of affairs shows that unfavourable coincidence of the individual, personal circumstances and external factors leads to deficit of employability capacity and possibility of marked social and employment deprivation.

  2. Reducing Employment Insecurity

    Directory of Open Access Journals (Sweden)

    Florence Lebert

    2016-10-01

    Full Text Available The perception of job insecurity is known to be a stressful condition for employees. Less is known about employment insecurity and the ways employees and their families deal with it. This study investigates whether participation in further training is a strategy that employees adopt to reduce perceived employment insecurity. As participation in further training is often costly and time-consuming, we assume that the family context is of importance for the decision to take part in further training. To take account of possible self-selection, we apply a propensity score matching procedure on longitudinal data from the Swiss Household Panel (2004-2013. Three main findings can be emphasized: first, participation in further training is not a strategy adopted particularly by employees who perceive high employment insecurity as they are less likely to train than their secure counterparts. Second, even though further training is not a strategy that is actively adopted, employees who train subsequently report lower levels of perceived employment insecurity. Third, the family context indeed influences the likelihood to train: partnered employees are more likely to train and preschool-aged children act as a constraint on women’s but enhance men’s participation in further training. Yet, in the context of high perceived employment insecurity, children generally reduce their parents’ likelihood to train as the parents may turn to other strategies that reduce perceived employment insecurity.

  3. Data Transfer Advisor with Transport Profiling Optimization

    Energy Technology Data Exchange (ETDEWEB)

    Rao, Nageswara S. [ORNL; Liu, Qiang [ORNL; Yun, Daqing [Harrisburg University; Wu, Chase Qishi [New Jersey Institute of Technology; Kettimuthu, R. [Argonne National Laboratory (ANL); Jung, Eun-sung [Argonne National Laboratory (ANL)

    2017-11-01

    The network infrastructures have been rapidly upgraded in many high-performance networks (HPNs). However, such infrastructure investment has not led to corresponding performance improvement in big data transfer, especially at the application layer, largely due to the complexity of optimizing transport control on end hosts. We design and implement ProbData, a PRofiling Optimization Based DAta Transfer Advisor, to help users determine the most effective data transfer method with the most appropriate control parameter values to achieve the best data transfer performance. ProbData employs a profiling optimization based approach to exploit the optimal operational zone of various data transfer methods in support of big data transfer in extreme scale scientific applications. We present a theoretical framework of the optimized profiling approach employed in ProbData as wellas its detailed design and implementation. The advising procedure and performance benefits of ProbData are illustrated and evaluated by proof-of-concept experiments in real-life networks.

  4. Strategies for the optimization of organic solar cells. Doped transport layers and novel oligothiophenes with reduced band gap; Strategien zur Optimierung organischer Solarzellen. Dotierte Transportschichten und neuartige Oligothiophene mit reduzierter Bandluecke

    Energy Technology Data Exchange (ETDEWEB)

    Uhrich, Christian

    2008-03-11

    Organic solar cells have the potential for light weight and flexible applications. They can be manufactured cost-effectively and can thus contribute to the reduction of the emission of carbon dioxide, methane and nitric oxides. In order to manufacture organic solar cells, only small amounts of organic materials are required. They can be processed at comparably low temperatures. Therefore, the fabrication on substrates like plastic foil is possible. Three different types of organic solar cells exist. The first kinds are solar cells prepared from small molecules that are manufactured via sublimation of the material in a vacuum. The second kind are polymer solar cells manufactured from solution by spin coating techniques or ink jet printing. And thirdly, dye sensitized solar cells - also known as Graetzel cells - consisting of a porous layer of titanium dioxide and most commonly a liquid electrolyte for the charge transport. This work deals exclusively with small molecule solar cells. The highest power conversion efficiencies reached by small molecule organic photovoltaics are now in the range of 5 %. In order to increase the efficiencies of solar cells prepared from small molecules, two major aspects must be developed. The understanding of the physical processes within the organic devices must be improved. And secondly, new materials are required with physical properties optimized for organic photovoltaics. In this work, I followed two strategies for optimizing organic solar cells: - By optimizing the offset of energy levels between donor and acceptor material, the open circuit voltage could be increased. In the investigated model system, the origin of the open circuit voltage and the recombination dynamics of photo generated charge carriers were analyzed. Concerning the open circuit voltage, solar cells consisting of a donor acceptor double layer structure, show fundamental differences to solar cells consisting of a donor acceptor blend. - Furthermore, new thiophene

  5. Resource Allocation and Cross Layer Control in Wireless Networks

    National Research Council Canada - National Science Library

    Georgiadis, L; Neely, M; Tassiulas, L

    2006-01-01

    .... In this paper we will present abstract models that capture the cross layer interaction from the physical to transport layer in wireless network architectures including cellular, ad-hoc and sensor...

  6. Wall Layers

    Science.gov (United States)

    1992-01-14

    Mathematical Sciences Institute. Ithaca, NY: Cornell. Guckenheimer, J. & Labouriau, 1. 1990. Bifurcation of the Hodgkin - Huxley equations: a new vt.vist. In...olm es -____ II_ John Guckenheimer Avwi tI.,,ti 1it y ’odes ,Av9L! an.,I/or Dist Special •D L 2 Narrative Philip Holmes is continuing to study the...not localized in spae like the structur observed in the turbulent baft y layer. Wavelet bases, having compact support, seem much more appropriate. J

  7. Implementing public employment policy

    DEFF Research Database (Denmark)

    Larsen, Flemming; Bredgaard, Thomas

    . But there is an interesting question to investigate here: whether and if so how, NPM-inspired reforms are related to changes in employment policy towards a work-first approach? Are changes in public management systems created as deliberate policy changes, or do they bring about more indirect and unintended policy changes......Like most other areas within welfare policy, the employment and social policy areas are undergoing far-reaching changes in many countries. Partly in the shape of new forms of governance inspired by New Public Management (NPM), partly through new policies oriented towards activation and stronger...... disciplining of the unemployed (work first) (cf.Bredgaard & Larsen, 2005; Sol & Westerweld, 2005). It is, however, remarkable that in the research field there seems to be a division of labour so that changes in public administration and changes in the substance of employment policies are dealt with separately...

  8. Employment certificates on HRT

    CERN Multimedia

    HR Department

    2008-01-01

    As part of the ongoing drive to simplify and streamline administrative procedures and processes, the IT and HR Departments have made employment certificates available on a self-service basis on the HRT application, in the main menu under "My self services". All members of the personnel can thus obtain a certificate of employment or association, in French or in English, for the present or past contractual period. The HR Department’s Records Office remains responsible for issuing any special certificates that might be required. IT-AIS (Administrative Information Services) HR-SPS (Services, Procedures & Social) Records Office – Tel. 73700

  9. Policies for full employment

    DEFF Research Database (Denmark)

    de Koning, Jaap; Layard, Richard; Nickel, Stephen

    European unemployment is too high, and employment is too low. Over 7½ per cent of Europe's workforce is unemployed, and only two thirds of people aged 15-64 are in work. At the Lisbon summit two years ago the heads of government set the target that by 2010 the employment rate should rise from 64 ......, the Netherlands and Sweden). And seven of the 15 countries in the E.U already have lower unemployment than the United States (the previous four plus Austria, Ireland and Luxembourg)....

  10. Youth, family and employment.

    Science.gov (United States)

    Peters, J F

    1987-01-01

    Some of the functions and dysfunctions of youth employment in contemporary society are discussed. The focus then shifts to a third variable: family dynamics. The research indicates that youth unemployment prolongs residence with parents. The younger the youth, the more tolerant are the parents of the unemployment. It was also found that a daughter's lack of employment in the summer months is more acceptable than a son's; that debts are part of the lifestyle of youth after age 18; that males incur more debts than do females; and that parents are the major source of financial loans.

  11. Implementing the employability agenda

    DEFF Research Database (Denmark)

    Lee, Donna; Snaith, Holly Grace; Foster, Emma

    2014-01-01

    This article draws on research commissioned by the Higher Education Academy (HEA) and conducted during 2013. It interrogates the ways in which the employability agenda has been fed through to the level of individual politics departments. The project was particularly concerned with establishing...... whether, and how, colleagues in politics and international relations (IR) had taken ownership of student employability at the level of the curriculum. In the article, the key findings of the research are summarised. There is also discussion of the (sometimes troubling) professional implications...... of infusing concern for graduate outcomes within a pedagogic framework that emphasises critical engagement with the underpinning political structures of the labour market....

  12. Governing EU employment policy

    DEFF Research Database (Denmark)

    Sørensen, Eva; Triantafillou, Peter; Damgaard, Bodil

    2015-01-01

    In the European Union (EU), employment policy is a prerogative of the member states. Therefore the EU's ability to govern in this area depends on its capability to involve national governments and relevant stakeholders in a collaborative effort to formulate and implement shared policy objectives....... Drawing an analytical distinction between cooperation, coordination and collaboration, the article analyses the formulation and implementation of EU employment policies. It concludes that while the formulation of policy objectives and the discussion of national policy approaches do involve elements...... of collaboration, the implementation phase mainly consists in the less demanding forms of cooperation and coordination....

  13. Radiation protection - the employer

    International Nuclear Information System (INIS)

    Goldfinch, E.

    1983-01-01

    A brief report is given of a paper presented at the symposium on 'Radiation and the Worker - where do we go from here' in London 1983. The paper concerned the employers' viewpoint on the draft of the proposed Ionising Radiations Regulations in the Health and Safety Commission Consultative Document. It was concluded that there was already a very good standard of radiological protection in the UK and that any improvements could therefore only be fringe improvements, although the cost to the employer of introducing and implementing the new proposed Regulations was bound to be high. (U.K.)

  14. A parcel formulation for Hamiltonian layer models

    NARCIS (Netherlands)

    Bokhove, Onno; Oliver, M.

    Starting from the three-dimensional hydrostatic primitive equations, we derive Hamiltonian N-layer models with isentropic tropospheric and isentropic or isothermal stratospheric layers. Our construction employs a new parcel Hamiltonian formulation which describes the fluid as a continuum of

  15. Two-dimensional layered semiconductor/graphene heterostructures for solar photovoltaic applications

    Science.gov (United States)

    Shanmugam, Mariyappan; Jacobs-Gedrim, Robin; Song, Eui Sang; Yu, Bin

    2014-10-01

    Schottky barriers formed by graphene (monolayer, bilayer, and multilayer) on 2D layered semiconductor tungsten disulfide (WS2) nanosheets are explored for solar energy harvesting. The characteristics of the graphene-WS2 Schottky junction vary significantly with the number of graphene layers on WS2, resulting in differences in solar cell performance. Compared with monolayer or stacked bilayer graphene, multilayer graphene helps in achieving improved solar cell performance due to superior electrical conductivity. The all-layered-material Schottky barrier solar cell employing WS2 as a photoactive semiconductor exhibits efficient photon absorption in the visible spectral range, yielding 3.3% photoelectric conversion efficiency with multilayer graphene as the Schottky contact. Carrier transport at the graphene/WS2 interface and the interfacial recombination process in the Schottky barrier solar cells are examined.

  16. Declining Black Employment.

    Science.gov (United States)

    Vedder, Richard; Gallaway, Lowell

    1993-01-01

    Explores income inequality during declining African-American employment, examines current welfare systems, and suggests ways to improve the economic disadvantages of minority groups. Letting markets work can improve the economic status of African Americans. The present dual African-American economy, a market economy and an entitlement economy, is…

  17. Views of the employers

    International Nuclear Information System (INIS)

    Ishida, J.

    2003-01-01

    The employer shall establish and maintain a safety management system, which is a part of the overall management system that facilitates the management of the occupational health and safety risks associated with the business of the organization. In addition to meeting its legal responsibilities, the employer should aim to improve its occupational health and safety performance, and its safety management system, effectively and efficiently, to meet changing business and regulatory needs. Occupational radiation protection is also a part of its activities. The concept of 'as low as reasonably achievable' (ALARA) presumes that any increment of radiation dose may produce a proportionate incremental risk, and that all radiation doses shall be kept ALARA, taking into account social and economic factors. Up to now, by implementing various activities in accordance with the principle of ALARA, employers have been minimizing the exposure dose of plant workers. Owing to improvements in hardware and administrative control, the exposure dose of workers has followed a remarkable downward trend, and now the number of workers exceeding 20 mSv/a is nearly zero. By implementing more thorough radiation protection and safety programmes, as well as by promoting safety consciousness among individual workers, the employers are continuing their efforts, respecting ALARA, to prevent workers from being exposed to radiation unnecessarily. As a consequence, the average individual dose of workers has dropped to 1 mSv/a or so. There may no longer be a discernible decrease in doses received at most of nuclear facilities

  18. Employment without Growth

    DEFF Research Database (Denmark)

    Nørgaard, Jørgen

    Employment is a central argument for economic growth in the Western world. But environmental problems like global warming points towards limits to growth. The presentation outlines the history of what has lead to this dilemma. Fortunately citizens attitudes now points towards a preference for less...

  19. Should Universities Promote Employability?

    Science.gov (United States)

    McCowan, Tristan

    2015-01-01

    Employability is becoming increasingly central to the mission and functioning of universities, spurred on by national and supranational agencies, and the demands of marketisation. This article provides a response to the normative dimensions of the question, progressing through four stages: first, there is a brief consideration of the meaning and…

  20. Employment Relations in Denmark

    DEFF Research Database (Denmark)

    Madsen, Jørgen Steen; Due, Jesper Jørgen; Andersen, Søren Kaj

    2011-01-01

    Jørgen Steen Madsen, Jesper Due og Søren Kaj Andersen har skrevet et kapitel om udviklingen i dansk arbejdsmarkedsregulering til bogen International and Comparative Employment Relations, redigeret af Greg Bamber, Russell Lansbury og Nick Wailes. Bogen indeholder bidrag, der præsenterer og...

  1. Shifting employment revisited

    NARCIS (Netherlands)

    Cremers, J.; Gramuglia, A.

    2014-01-01

    The CLR-network examined in 2006 the phenomenon of undeclared labour, with specific regard to the construction sector. The resulting study, Shifting Employment: undeclared labour in construction, gave evidence that this is an area particularly affected by undeclared activities with one of the

  2. Shifting employment revisited

    NARCIS (Netherlands)

    Cremers, Jan; Gramuglia, Alessia

    2014-01-01

    The CLR-network examined in 2006 the phenomenon of undeclared labour, with specific regard to the construction sector. The resulting study, Shifting Employment: undeclared labour in construction (Shifting-study hereafter), gave evidence that this is an area particularly affected by undeclared

  3. A Stochastic Employment Problem

    Science.gov (United States)

    Wu, Teng

    2013-01-01

    The Stochastic Employment Problem(SEP) is a variation of the Stochastic Assignment Problem which analyzes the scenario that one assigns balls into boxes. Balls arrive sequentially with each one having a binary vector X = (X[subscript 1], X[subscript 2],...,X[subscript n]) attached, with the interpretation being that if X[subscript i] = 1 the ball…

  4. The Employment Mismatch

    Science.gov (United States)

    Fischer, Karin

    2013-01-01

    Employers value a four-year college degree, many of them more than ever. Yet half of those surveyed recently by "The Chronicle" and American Public Media's "Marketplace" said they had trouble finding recent graduates qualified to fill positions at their company or organization. Nearly a third gave colleges just fair to poor marks for producing…

  5. An Exploration of Employer Perceptions of Graduate Student Employability

    Science.gov (United States)

    Chhinzer, Nita; Russo, Anna Maria

    2018-01-01

    Purpose: The purpose of this paper is to explore employer perceptions of graduate student employability. This study is novel since existing research focused on employability is largely theoretic, remains focused on defining employability of undergraduates and largely fails to determine employer perceptions of factors that increase or decrease…

  6. Computers and Communications. Improving the Employability of Persons with Handicaps.

    Science.gov (United States)

    Deitel, Harvey M.

    1984-01-01

    Reviews applications of computer and communications technologies for persons with visual, hearing, physical, speech, and language impairments, as well as the effects of technologies on transportation, work at home, education, and other aspects affecting the employment of the disabled. (SK)

  7. Energy levy and employment

    International Nuclear Information System (INIS)

    De Mooij, R.A.

    1993-01-01

    The employment in the Netherlands seems to be relatively vulnerable for an energy levy compared to other European countries. Therefore, implementation of an energy levy because of the environment demands a supporting policy for the employment. This can be realized by using the yield of the levy totally for the decrease of the tax burden on labour. An unbalanced distribution of incomes between the working population and the unemployed population must be taken for granted. Based on the general equilibrium model ENTAX (ENvironmental TAXation) for a small economy a number of factors, which can impact the cost effectiveness of a regulating energy levy, are discussed. Six countries (Netherlands, Belgium, Denmark, Germany, France and the United Kingdom) are compared regarding these factors. 4 tabs., 15 refs

  8. Employment and winter construction

    DEFF Research Database (Denmark)

    Hansen, Ernst Jan de Place; Larsen, Jacob Norvig

    2011-01-01

    Reduced seasonal building activity in the construction sector is often assumed to be related to hard winter conditions for building activities and poor working conditions for construction workers, resulting in higher costs and poor quality of building products, particularly in the northern...... hemisphere. Can climatic conditions alone explain the sizeable difference in reduction in building activity in the construction sector in European countries in the winter months, or are other factors such as technology, economic cycles and schemes for financial compensation influential as well? What...... possibilities exist for reducing seasonal variation in employment? In addition to a literature review related to winter construction, European and national employment and meteorological data were studied. Finally, ministerial acts, ministerial orders or other public policy documents related to winter...

  9. Entrepreneurship and Employment Stability

    DEFF Research Database (Denmark)

    Failla, Virgilio; Melillo, Francesca; Reichstein, Toke

    2017-01-01

    are identified and empirically explored: (i) job matching, (ii) labour market value, and (iii) personal commitment. Entrepreneurs appear to be more productive and thus better matched compared to wageworkers. However, they also appear to be locked in entrepreneurship because of their anticipated lower value......This paper challenges the conventional belief that entrepreneurship is an unstable career path. Using longitudinal matched employer–employee data from Denmark, the analysis reveals that a transition to entrepreneurship decreases individual's employment turnover tendency. Three explanations...... in the labour market and because of their personal attachment to the venture. The counter-intuitive finding – entrepreneurship yields greater employment stability – only holds with respect to subsequent transitions to wagework and not for new venture founding. The results have implications for our understanding...

  10. Liability in Employment Law

    OpenAIRE

    Lang, Roman

    2006-01-01

    97 Liability in labour law Summary This diploma paper analyzes liability in labour law with focus on liability for damage. At first the diploma paper introduces conception of liability in general and idea of liability in labour law considering different position of employee and employer in labour relations. The diploma paper then enumerates the types of labour-law liability. The next chapter concentrates on liability for damage. This chapter describes characteristic features of liability for ...

  11. Work and Employment

    OpenAIRE

    De Poorter, Mathieu

    2012-01-01

    The social and solidarity economy (SSE) and its ties to the questions of employment and work are discussed here from the perspective of enterprises and organisations of the SSE and their efforts to create decent work, as defined by the International Labour Organisation. Enterprises and organisations of the SSE are analysed under the four dimensions that define decent work, namely: The guarantee of labour rights, and the promotion of the application and respect for the (fundamental) working st...

  12. RELATIONSHIPS BETWEEN EMPLOYMENT AND GROWTH FROM INDUSTRIAL PERSPECTIVE BY CONSIDERING EMPLOYMENT INCENTIVES: THE CASE OF TURKEY

    Directory of Open Access Journals (Sweden)

    Emre Aksoy

    2013-01-01

    Full Text Available By using quarterly data this study applied Toda-Yamamoto (1995 method for the period 1988-2010 to uncover the relationship between growth and employment in aggregate and industrial respects and also to investigate the impacts of investment and employment incentives on employment for Turkish Economy. The findings showed that the relationship between growth and employment varied with the industries. The study covers ten industries and there were causalities detected for four out of ten industries, either one or two ways. For the rest six industries covered in the study, there was no causal relationship obtained. The incentives impacts on employment, similarly, vary with industries. The law numbered as 5084 had positive and statistically significant influences on social service, manufacturing, and transportation and communication industries while the law numbered as 5763 extracted positive and significant influences on energy production and distribution, and financial intermediation industries.

  13. Soldiers’ employment attitude and employability: An exploratory study

    Directory of Open Access Journals (Sweden)

    Peng Gao

    2015-04-01

    Full Text Available Purpose: Nowadays it is very difficult for Chinese retired soldiers to find proper jobs, and the primary reason is the significant gap between job requirements and soldiers owned job skills. Therefore, it is very important to improve the soldiers’ job skills and enhance their understanding of employment.Design/methodology/approach: This paper expands the study scope from the soldiers’ job skills to the employability, initiatively introduces the employment attitude which has obvious impact on the employment of soldiers, and analyses the influence that employment attitude can play on employability. At last, this paper develops statistical method to find the relationship between soldiers’ employment attitude and employability.Findings: The empirical analysis shows that soldiers’ employment attitude has the positive linkage with employability, which makes the employment attitude a measurable variable for the employability rather than an absolute standard.Research limitations/implications: According to the research purpose, more variables should be considered in the model, consequently, there are only three indicators to describe solders’ employment attitude and four indicators to describe solders’ employability.Originality/value: This paper takes research on soldiers’ employability in a new perspective. The soldiers’ employment attitude is served as the entry point, showing the influence that soldiers’ employment attitude has on employability.

  14. Employer supports for parents with young children.

    Science.gov (United States)

    Friedman, D E

    2001-01-01

    The competing interests of employers, working parents, and very young children collide in decisions over work schedules, child care arrangements, promotions, children's sicknesses, and overtime hours. With the rising number of women in the labor force, more and more employers are concerned about how their workers balance work and family priorities. This article examines the supports that employers provide to help parents with young children juggle demands on their time and attention. It reviews the availability of traditional benefits, such as vacation and health insurance, and describes family-friendly initiatives. Exciting progress is being made in this arena by leading employers, but coverage remains uneven: Employers say they provide family-friendly policies and programs to improve staff recruitment and retention, reduce absenteeism, and increase job satisfaction and company loyalty. Evaluations demonstrate positive impacts on each of these valued outcomes. Employee benefits and work/family supports seldom reach all layers of the work force, and low-income workers who need assistance the most are the least likely to receive or take advantage of it. Understandably, employer policies seek to maximize productive work time. However, it is often in the best interests of children for a parent to be able to set work aside to address urgent family concerns. The author concludes that concrete work/family supports like on-site child care, paid leave, and flextime are important innovations. Ultimately, the most valuable aid to employees would be a family-friendly workplace culture, with supportive supervision and management practices.

  15. Environment, employment and development

    International Nuclear Information System (INIS)

    Bhalla, A.S.

    1992-01-01

    It is generally recognised that the question of sustainable development is a global problem, emphasizing the increasingly interdependent nature of relationships among nations. Solutions to the problem are as much political as they are economic and technological. Notwithstanding the deepening and widening of the debate on sustainable development, its implications for employment - a major concern of the ILO under its World Employment Programme - have remained largely unexplored. This volume, therefore, has a very modest objective, namely to place the employment question on the policy agenda in the context of the current debate on environment and development. The design of environmental policies should allow for the differences that exist between countries with a high level of development and technological dynamism and those with a low level of development and low technological capability. One must also recognize the costs imposed by adjustment and the consequent distributional impact. In the long term, technology choice plays a crucial role in promoting sustainable development in both industrialized and developing countries. It is not only environment-friendly technologies that need to be developed and diffused; in the case of the least developed countries, technological transformation needs to be accelerated in order to minimise their dependence on natural resources for economic growth. Refs, figs and tabs

  16. Energy investments and employment

    International Nuclear Information System (INIS)

    1993-08-01

    A study was conducted to assess the effect that different energy options would have on provincial and regional employment prospects in British Columbia. Current and future economic and employment patterns were examined to develop a more detailed understanding of the skills, age, gender, location, and other characteristics of British Columbia workers. Over 40 previous studies examining the energy/employment relationship were also reviewed. Based on this review and an analysis of the province's economic and labor conditions, the following conclusions are drawn. Investment in non-energy sectors offers better prospects for reducing unemployment than investment in the energy sector, whether for new supply or improving efficiency. Investments in the energy sector provide fewer jobs than investments in most other sectors of the economy. Among the available electricity supply options, large hydroelectric projects tend to produce the fewest jobs per investment dollar. Smaller thermal projects such as wood residue plants produce the most jobs. If and when more energy is needed in British Columbia, the most cost-effective combination of energy supply and efficiency options will also create the most jobs. Compared to traditional energy supply options, investments in energy efficiency would create about twice as many total jobs, create jobs that better match the skills of the province's unemployed and its population distribution, and create jobs that last longer on the average. Construction-related measures such as improved insulation tend to produce more jobs per investment dollar than the substitution of more energy-efficient equipment. 69 refs., 9 tabs

  17. Employment opportunities for the disabled

    NARCIS (Netherlands)

    Delsen, L.W.M.

    1996-01-01

    Policy makers in the OECD Member States have developed quite different programmes and institutional arrangements to create and promote employment opportunities for the disabled. These policy approaches include legal interventions, employment support services, financial support of open employment and

  18. ZnSe passivation layer for the efficiency enhancement of CuInS2 quantum dots sensitized solar cells

    International Nuclear Information System (INIS)

    Peng, Zhuoyin; Liu, Yueli; Zhao, Yinghan; Chen, Keqiang; Cheng, Yuqing; Kovalev, Valery; Chen, Wen

    2014-01-01

    Highlights: • ZnSe is employed as passivation layer in CuInS 2 quantum dots sensitized solar cells. • Slight red-shift has been occurred in UV–vis absorption spectra with ZnSe coating. • CuInS 2 based solar cells coated by ZnSe have better efficiency than that of ZnS. • Higher rate of charge transport can be produced after coating with ZnSe. -- Abstract: The effect of ZnSe passivation layer is investigated in the CuInS 2 quantum dot sensitized solar cells, which is used to improve the photovoltaic performance. The CuInS 2 quantum dot sensitized TiO 2 photo-anodes are prepared by assembly linking technique, and then deposited by the ZnSe passivation layer using the successive ionic layer absorption and reaction technique. The optical absorption edge and photoluminescence peak have slightly red-shifted after the passivation layer coating. Under solar light illumination, the ZnSe passivation layer based CuInS 2 quantum dot sensitized solar cells have the higher photovoltaic efficiency of 0.95% and incident photon conversion efficiency response than that of pure CuInS 2 based solar cells and ZnS passivation layer based solar cells, as the electron injection rate becomes faster after coating with ZnSe passivation layer

  19. Highly Efficient and Stable Flexible Perovskite Solar Cells with Metal Oxides Nanoparticle Charge Extraction Layers.

    Science.gov (United States)

    Najafi, Mehrdad; Di Giacomo, Francesco; Zhang, Dong; Shanmugam, Santhosh; Senes, Alessia; Verhees, Wiljan; Hadipour, Afshin; Galagan, Yulia; Aernouts, Tom; Veenstra, Sjoerd; Andriessen, Ronn

    2018-02-09

    In this study, the fabrication of highly efficient and durable flexible inverted perovskite solar cells (PSCs) is reported. Presynthesized, solution-derived NiO x and ZnO nanoparticles films are employed at room temperature as a hole transport layer (HTL) and electron transport layer (ETL), respectively. The triple cation perovskite films are produced in a single step and for the sake of comparison, ultrasmooth and pinhole-free absorbing layers are also fabricated using MAPbI 3 perovskite. The triple cation perovskite cells exhibit champion power conversion efficiencies (PCEs) of 18.6% with high stabilized power conversion efficiency of 17.7% on rigid glass/indium tin oxide (ITO) substrates (comparing with 16.6% PCE with 16.1% stabilized output efficiency for the flexible polyethylene naphthalate (PEN)/thin film barrier/ITO substrates). More interestingly, the durability of flexible PSC under simulation of operative condition is proved. Over 85% of the maximum stabilized output efficiency is retained after 1000 h aging employing a thin MAPbI 3 perovskite (over 90% after 500 h with a thick triple cation perovskite). This result is comparable to a similar state of the art rigid PSC and represents a breakthrough in the stability of flexible PSC using ETLs and HTLs compatible with roll to roll production speed, thanks to their room temperature processing. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. 28 CFR 97.11 - Pre-employment screening.

    Science.gov (United States)

    2010-07-01

    ... 28 Judicial Administration 2 2010-07-01 2010-07-01 false Pre-employment screening. 97.11 Section 97.11 Judicial Administration DEPARTMENT OF JUSTICE (CONTINUED) STANDARDS FOR PRIVATE ENTITIES PROVIDING PRISONER OR DETAINEE SERVICES § 97.11 Pre-employment screening. Private prisoner transport...