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Sample records for elements estonian organizations

  1. Stocks of organic carbon in Estonian soils

    Directory of Open Access Journals (Sweden)

    Kõlli, Raimo

    2009-06-01

    Full Text Available The soil organic carbon (SOC stocks (Mg ha–1 ofautomorphic mineral (9 soil groups, hydromorphic mineral (7, and lowland organic soils (4 are given for the soil cover or solum layer as a whole and also for its epipedon (topsoil layer. The SOC stocks for forest, arable lands, and grasslands and for the entire Estonian soil cover were calculated on the basis of the mean SOC stock and distribution area of the respective soil type. In the Estonian soil cover (42 400 km2, a total of 593.8 ± 36.9 Tg of SOC is retained, with 64.9% (385.3 ± 27.5 Tg in the epipedon layer (O, H, and A horizons and 35.1% in the subsoil (B and E horizons. The pedo-ecological regularities of SOC retention in soils are analysed against the background of the Estonian soil ordination net.

  2. Sources and distribution of trace elements in Estonian peat

    Science.gov (United States)

    Orru, Hans; Orru, Mall

    2006-10-01

    This paper presents the results of the distribution of trace elements in Estonian mires. Sixty four mires, representative of the different landscape units, were analyzed for the content of 16 trace elements (Cr, Mn, Ni, Cu, Zn, and Pb using AAS; Cd by GF-AAS; Hg by the cold vapour method; and V, Co, As, Sr, Mo, Th, and U by XRF) as well as other peat characteristics (peat type, degree of humification, pH and ash content). The results of the research show that concentrations of trace elements in peat are generally low: V 3.8 ± 0.6, Cr 3.1 ± 0.2, Mn 35.1 ± 2.7, Co 0.50 ± 0.05, Ni 3.7 ± 0.2, Cu 4.4 ± 0.3, Zn 10.0 ± 0.7, As 2.4 ± 0.3, Sr 21.9 ± 0.9, Mo 1.2 ± 0.2, Cd 0.12 ± 0.01, Hg 0.05 ± 0.01, Pb 3.3 ± 0.2, Th 0.47 ± 0.05, U 1.3 ± 0.2 μg g - 1 and S 0.25 ± 0.02%. Statistical analyses on these large database showed that Co has the highest positive correlations with many elements and ash content. As, Ni, Mo, ash content and pH are also significantly correlated. The lowest abundance of most trace elements was recorded in mires fed only by precipitation (ombrotrophic), and the highest in mires fed by groundwater and springs (minerotrophic), which are situated in the flood plains of river valleys. Concentrations usually differ between the superficial, middle and bottom peat layers, but the significance decreases depending on the type of mire in the following order: transitional mires - raised bogs - fens. Differences among mire types are highest for the superficial but not significant for the basal peat layers. The use of peat with high concentrations of trace elements in agriculture, horticulture, as fuel, for water purification etc., may pose a risk for humans: via the food chain, through inhalation, drinking water etc.

  3. The Challenges Organic Food Processors Meet at Small Emerging Market – Estonian Case

    OpenAIRE

    Sarapuu, Kerttu; Pehme, Sirli; Peetsmann, Elen; Matt, Darja

    2014-01-01

    Organic farming and demand for organic products is continually a growing trend all over the world (Willer et al., 2013). In Estonia the share of organic land is 15% of all agricultural land and the number of organic farmers is also growing (Vetemaa, Mikk 2013). Estonian organic food market is still in forming stage being affected by local organic farming development, marketing situation, economic situation and consumer attitudes. Organic processing has clearly not kept up with organic farming...

  4. The Rocky Road towards Professional Autonomy: The Estonian Journalists’ Organization in the Political Turmoil of the 20th Century

    Directory of Open Access Journals (Sweden)

    Epp Lauk

    2017-09-01

    Full Text Available This article attempts to explain the relationships between journalists, politics and the state from the perspective of collective autonomy, that of the professional organization of journalists. The case of Estonian Journalists’ Union demonstrates the complexity and historical contingency of professional autonomy of journalism. The development of the Estonian journalists’ organization occurred as a sequence of transformations from the Estonian Journalists’ Association to the Estonian Journalists’ Union to the Soviet type journalists’ union, and lastly to an independent trade union. This sequence was disrupted by several fatal breakdowns that changed not only the character of the association, but also professional values, the whole occupational ideology and the conditions of the existence of journalism as a profession in Estonia.

  5. Spatial patterns of soil organic carbon stocks in Estonian arable soils

    Science.gov (United States)

    Suuster, Elsa; Astover, Alar; Kõlli, Raimo; Roostalu, Hugo; Reintam, Endla; Penu, Priit

    2010-05-01

    Soil organic carbon (SOC) determines ecosystem functions, influencing soil fertility, soil physical, chemical and biological properties and crop productivity. Therefore the spatial pattern of SOC stocks and its appropriate management is important at various scales. Due to climate change and the contribution of carbon store in the soils, the national estimates of soil carbon stocks should be determined. Estonian soils have been well studied and mapped at a scale 1:10,000. Previous studies have estimated SOC stocks based on combinations of large groups of Estonian soils and the mean values of the soil profile database, but were not embedded into the geo-referenced databases. These studies have estimated SOC stocks of Estonian arable soils 122.3 Tg. Despite of available soil maps and databases, this information is still very poorly used for spatial soil modelling. The aim of current study is to assess and model spatial pattern of SOC stocks of arable soils on a pilot area Tartu County (area 3089 sq km). Estonian digital soil map and soil monitoring databases are providing a good opportunity to assess SOC stocks at various scales. The qualitative nature of the initial data from a soil map prohibits any straightforward use in modelling. Thus we have used several databases to construct models and linkages between soil properties that can be integrated into soil map. First step was to reorganize the soil map database (44,046 mapping units) so it can be used as an input to modelling. Arable areas were distinguished by a field layer of Agricultural Registers and Information Board, which provides precise information of current land use as it is the basis of paying CAP subsidies. The estimates of SOC content were found by using the arable land evaluation database of Tartu from the Estonian Land Board (comprising 950 sq km and 31,226 fields), where each soil type was assessed separately and average SOC content grouped by texture was derived. SOC content of epipedon varies in

  6. Estonian horticultural peat marketing: sales promotion and price formation. 2. part

    International Nuclear Information System (INIS)

    Hammer, Hele

    1999-01-01

    When forming prices, Estonian peat companies' decisions should be based on marginal cost analysis. Unfortunately most Estonian companies sell peat to intermediaries and cannot influence its price. Estonian peat producers have to choose between either selling peat directly or selling through a central marketing organization. Both systems have their pros and cons. Direct selling gives more freedom to individual producers but is more risky. Central marketing makes cost saving possible and is more effective and stable, but may alienate producers from clients and markets. Whichever marketing system Estonian peat companies choose, the most important elements in their marketing strategy should be: careful market analysis, personal sales, attending trade shows, catalogues, quality service and offering transportation services. (author)

  7. Estonian literature / Janika Kronberg

    Index Scriptorium Estoniae

    Kronberg, Janika, 1963-

    2003-01-01

    Sisu: Estonian literature - born on the margins of Europe ; Baltic German literature and its impact ; Seeking the contours of a 'truly' Estonian literature ; Literature and an independent Estonia ; Estonian literature in two cultural spheres ; The fifties and sixties ; Literature and congealed time ; A bold new Estonian literature

  8. Estonian white paper on energy

    International Nuclear Information System (INIS)

    Hamburg, Arvi

    1997-01-01

    Energy policy, environmental protection and economy form a triangle of tightly linked sectors, and any solution of some energy problem can be solved only in the light of all the above mentioned factors. There are several energy master plans for Estonia, the first of them dating back to the years of the Soviet Union and ending the list with the plan to cover the years up to 2000. By now the basic principles of the Estonian energy policy have been prepared and Estonian Energy Concept is being worked out. The main goal of Estonian energy policy is ensure an effective and environmentally benign energy supply for the country. It means safety in energy supply, effective production and supply together with sufficient environmental protection. Energy Council in the role of an advisory voluntary organization for inspection of the energy system and finding measures to improve its efficiency is established with parliament members included. The Estonian Energy Research Institute and the Oil--Shale Research Institute serve as a scientific advisory board for the government in energy policy. It's important to emphasise that privatisation is no panacea, solving all the problems, and therefore we are facing hard to move in the right direction, satisfying all the consumers of energy

  9. Valued Estonian Music CDs

    Index Scriptorium Estoniae

    2004-01-01

    2002. aastal välja antud eesti muusika heliplaatidest Artur Kapp "Symphonische Werke", Eduard Tubin "Symphonies No.9, No.10 and No.11", "Estonian Preludes", "Eesti heliloojad. Hortus Musicus", "Eesti Muusika Päevad", "Tallinn Saxophone Quartet. Estonian Contemporary Music", "Triskele. Kolga-Jaani vaimulikud rahvalaulud", "Helmekaala. Linnupuu Anne", "Modern Fox mängib Raimond Valgret",

  10. Organic chemistry of elemental phosphorus

    International Nuclear Information System (INIS)

    Milyukov, V A; Budnikova, Yulia H; Sinyashin, Oleg G

    2005-01-01

    The principal achievements and the modern trends in the development of the chemistry of elemental phosphorus are analysed, described systematically and generalised. The possibilities and advantages of the preparation of organophosphorus compounds directly from white phosphorus are demonstrated. Attention is focused on the activation and transformation of elemental phosphorus in the coordination sphere of transition metal complexes. The mechanisms of the reactions of white phosphorus with nucleophilic and electrophilic reagents are discussed. Electrochemical approaches to the synthesis of organic phosphorus derivatives based on white phosphorus are considered.

  11. Swedish-Estonian energy forest research cooperation

    International Nuclear Information System (INIS)

    Ross, J.; Kirt, E.; Koppel, A.; Kull, K.; Noormets, A.; Roostalu, H.; Ross, V.; Ross, M.

    1996-01-01

    The Organization of Estonian energetic economy is aimed at cutting the usage of oil, gas and coal and increasing the local resources firewood, oil-shale and peat for fuel. The resources of low-valued firewood-brushwood, fallen deadwood etc. are available during the following 10-15 years, but in the future the cultivation of energy forest (willow) plantations will be actual. During the last 20 years the Swedish scientists have been extensively studying the willow forest selection, cultivation and use in energetics and waste water purification systems. A Swedish-Estonian energy forest research project was started in 1993 between the Swedish Agricultural University on one hand and Toravere Observatory, Institute of Zoology and Botany, Estonian Academy of Sciences and Estonian Potato Processing Association on the other hand. In spring 5 willow plantations were established with the help of Swedish colleagues and obtained from Sweden 36000 willow cuttings. The aim of the project: a) To study experimentally and by means of mathematical modelling the biogeophysical aspects of growth and productivity of willow plantations in Sweden and Estonian climatological conditions. b) To study the possibility of using the willow plantations in waste waters purification. c) To study the economical efficiency of energy forest as an energy resource under the economic and environmental conditions of Estonia. d) To study the economic efficiency of willow plantations as a raw material for the basket industry in Estonia. e) To select the most productive and least vulnerable willow clones for practical application in energy plantations. During 1993 in all five plantations detailed analysis of soil properties has been carried out. In the plantation at Toravere Observatory phytometrical measurements were carried out - the growth of plant biomass leaf and stem area, vertical distribution of dry matter content, biomass and phyto area separately for leaves and stems has been performed. Some

  12. Estonian Tax Structure

    Directory of Open Access Journals (Sweden)

    Viktor Trasberg

    2014-08-01

    Full Text Available The paper analyses Estonian tax structure changes during the last decade and critically assesses the current situation. The country’s tax mix is rather unique among EU countries – it has one of the highest proportions of consumption taxes in total taxes and the lowest level of capital and profit taxes. Such an unbalanced tax structure creates risks for public finances, limits revenue collection and distorts the business environment.

  13. Estonian energy forest project

    International Nuclear Information System (INIS)

    Koppel, A.; Kirt, E.; Kull, K.; Lasn, R.; Noormets, A.; Roostalu, H.; Ross, J.; Ross, V.; Sulev, M.

    1994-04-01

    In February 1993 an agreement of Swedish-Estonian scientific co-operation on energy forest was signed. In may five energy forest plantations (altogether 2 ha) were established in Estonia with Swedish selected clones of Salix viminalis and Salix dasyclados. The research within this project is carried out within three main directions. The studies of basic ecophysiological processes and radiation regime of willow canopy will be carried out in Toravere. The production ecology studies, comparison of the productivity of multiple clones on different soil types is based on the plantations as vegetation filter for wastewater purification is studied on the basis of plantations in Vaeike-Maarja and Valga (author)

  14. The distribution of some rare metals in the process of separation of organic matter from Estonian dictyonema argillite

    International Nuclear Information System (INIS)

    Palvadre, R.; Ahelik, V.

    1993-01-01

    The distribution of rare metals Mo, U and V in the process of separation of organic matter from Maardu and Toolse argillite s is discussed. The beneficiation process of argillite consists of the hydro cycling treatment, in the course of which organic matter is separated as a light fraction, followed by direct flotation of organic matter and pyrite concentrates. Determinations of Mo and U were made by X-ray fluorescence, V by titration and pyrite by titration of iron. It can be concluded that rare metals Mo, U and V were concentrating in organic matter, their recovery in pyrite and quartz was negligible, depending on the degree of pyrite separation. The recovery of rare metals, especially that of V in the mineral phase, was more considerable in the processing of Maardu argillite, whose content of clay minerals was higher than that of Toolse argillite. 4 tabs., 6 refs

  15. Estonian Airi uued soodsad pakkumised

    Index Scriptorium Estoniae

    2010-01-01

    Estonian Airi kodulehelt on võimalik osta lennupileteid koostööpartnerite poolt pakutavatele mandritevahelistele lendudele ning broneerida internetis hotellituba Euroopa suurima hotelli broneerimise teenust pakkuva ettevõtte Booking.com kaudu

  16. [Mati Erelt. Estonian Language] / Katrin Hiietamm

    Index Scriptorium Estoniae

    Hiietamm, Katrin

    2004-01-01

    Arvustus: Estonian language / [Estonian Academy of Sciences] ; edited by Mati Erelt.Tallinn : Teaduste Akadeemia Kirjastus, 2003. 412, [1] lk. : ill., kaart. (Linguistica Uralica. Supplementary series, 0868-4731 ; vol. 1)

  17. Estonian wind climate

    International Nuclear Information System (INIS)

    Kull, Ain

    1999-01-01

    Estonia is situated on the eastern coast of the Baltic Sea. This is a region with intensive cyclonic activity and therefore with a relatively high mean wind speed. Atmospheric circulation and its seasonal variation determine the general character of the Estonian wind regime over the Atlantic Ocean and Eurasia. However, the Baltic sea itself is a very important factor affecting wind climate, it has an especially strong influence on the wind regime in costal areas. The mean energy density (W/m 2 ) is a wind energy characteristic that is proportional to the third power of wind speed and describes energy available in a flow of air through a unit area. The mean energy density is a characteristic which has practical importance in regional assessment of snowdrift, storm damage and wind energy

  18. Transuranium elements in organic chemical forms

    International Nuclear Information System (INIS)

    Sakanoue, Masanobu; Yamamoto, Masayoshi

    1987-01-01

    It is very important to achive an understanding what role organic matter plays in the behavior of transuranium elements in the environment. This paper reports the studies on characteristics of fallout Pu and Am in soil closely related to soil organic matter, and interaction of humic acid and Am (III) in aqueous solution. From the results obtained, it was suggested that the humic acids had strong interaction with transuranium elements, but such soluble complexes were removed soon from the solution by coagulation and sorption on soil. (author)

  19. Characterization of elements in marine organisms

    International Nuclear Information System (INIS)

    Ishii, Toshiaki

    1993-01-01

    Characterization of elements in marine organisms was carried out to estimate the behavior of radionuclides in marine ecosystem or to clarify the physiological roles of elements in marine organisms. The concentrations of 238 U in fifty-five species of marine organisms were measured by inductively coupled plasma mass spectrometry. The concentrations of 238 U in soft tissues of marine animals ranged from 0.076 to 5000ng/g wet wt. Especially, the branchial heart of octopus vulgaris showed the specific accumulation of 238 U. The kidney granules of bivalve molluscs showed very high concentrations of Mn, Zn, 210 Pb, 210 Po etc. The XAFS study for the granules of Cyclosunetta menstrualis indicated that the chemical form of metals in the granules was phosphate (e. g. Mn 3 (PO 4 ) 2 · 4H 2 O). (author)

  20. Concentration of trace elements in marine organisms

    International Nuclear Information System (INIS)

    Ishii, Takaaki; Suzuki, Hamaji; Iimura, Mitsue; Koyanagi, Taku

    1976-01-01

    Information on the quality and quantity of stable trace elements in marine environments is frequently required to analyze the radioecological behavior of radionuclides released from nuclear facilities into the sea. In the present work, special attention was concentrated in determination of stable Mn, Fe, Co, Zn, Rb and Cs in marine organisms to estimate the concentration factors for these elements and corresponding radionuclides. Marine organisms (fishes, marine invertebrates and seaweeds) were collected at the seashore of Ibaragi prefecture and provided for chemical analysis after dry-ashing and wet-ashing. Atomic absorption spectrophotometry and neutron activation analysis were applied to determine the concentration of elements. The concentration of stable elements in fish muscle was independent on species of the fishes though slightly higher trends were observed in ''Usumebaru'', Sebastes nivosus for Cs, ''Ishimochi'', Nibea mitsukurii for Zn and Fe compared with other species. The concentration of Co, Zn and Fe in muscle of marine invertebrates was one order of magnitude higher than fish muscles especially in shellfishes for Co. Seaweeds showed peculiar species specificity for the concentration of stable trace elements and remarkable differences was observed between the species even among the same genus. (auth.)

  1. Characterization of elements in marine organisms

    Energy Technology Data Exchange (ETDEWEB)

    Ishii, Toshiaki [National Inst. of Radiological Sciences, Nakaminato, Ibaraki (Japan). Nakaminato Lab. Branch Office

    1994-03-01

    Characterization of elements was carried out to clarify the mechanisms of bioconcentration and the physiological roles of elements in marine organisms. The concentrations of {sup 238}U in fifty-five species of marine organisms were measured by inductively coupled plasma mass spectrometry. The concentrations of {sup 238}U in soft tissues of marine animals ranged from 0.076 to 500ng/g wet wt. Especially, the branchial heart of cephalopod molluscs showed the specific accumulation of {sup 238}U. The concentration factor of the branchial heart of Octopus vulgaris, which indicated the highest value, was calculated to be about 10{sup 3} by comparing it with the concentration of {sup 238}U (3.2 {+-} 0.2ng/ml) in coastal seawater of Japan. The concentrations of {sup 238}U of twenty species of algae ranged from 10 to 3700ng/g dry wt. (author).

  2. Characterization of elements in marine organisms

    International Nuclear Information System (INIS)

    Ishii, Toshiaki

    1994-01-01

    Characterization of elements was carried out to clarify the mechanisms of bioconcentration and the physiological roles of elements in marine organisms. The concentrations of 238 U in fifty-five species of marine organisms were measured by inductively coupled plasma mass spectrometry. The concentrations of 238 U in soft tissues of marine animals ranged from 0.076 to 500ng/g wet wt. Especially, the branchial heart of cephalopod molluscs showed the specific accumulation of 238 U. The concentration factor of the branchial heart of Octopus vulgaris, which indicated the highest value, was calculated to be about 10 3 by comparing it with the concentration of 238 U (3.2 ± 0.2ng/ml) in coastal seawater of Japan. The concentrations of 238 U of twenty species of algae ranged from 10 to 3700ng/g dry wt. (author)

  3. The Category of Time in Fairy Tales: Searching for Folk Calendar Time in the Estonian Fairy Tale Corpus

    Directory of Open Access Journals (Sweden)

    Mairi Kaasik

    2011-03-01

    Full Text Available The article examines how folk calendar holidays are represented in Estonian fairy tales. It introduces some views presented in folklore studies about the concept of time in fairy tales and finds parallels with them in the Estonian context. The analysis relies on the digital corpus of Estonian fairy tales (5400 variants, created from the texts found in the Estonian Folklore Archives by the Fairy Tale Project of the Department of Estonian and Comparative Folklore, University of Tartu. Folk calendar holidays occur in Estonian fairy tales relatively seldom; most often these are holidays that occupy a significant place in the Estonian folk calendar (Christmas, St. John’s Day, Easter, St. George’s Day. Calendar holidays are notably mentioned more often in tale types which remain on the borderline between the fairy tale and the legend or the fairy tale and the religious tale. In Estonian fairy tales, calendar holidays are used on three levels of meaning: (1 the holiday is organically associated with the tale type; it has an essential role in the plot of the tale; (2 to a certain extent, the holiday could be replaced by another holiday having an analogous meaning; (3 the holiday forms an unimportant or occasional addition to the tale.

  4. Logistics in Estonian business companies

    Directory of Open Access Journals (Sweden)

    A. Kiisler

    2008-12-01

    Full Text Available The article describes logistics survey in Estonia carried out in 2007 as a part of the LogOnBaltic project. The level of logistics in Estonian manufacturing, trading and logistics companies is explored through logistics costs, performance indicators, outsourcing, ICT use and logistics self-estimation of the companies responded. Responses from 186 Estonian companies were gathered through a web-based survey (38% of manufacturing, 38% of trading and 24% of logistics sector. Logistics costs as the percentage of turnover make in average 13.8% in manufacturing and 13.3% in trading. Transportation and inventory carrying cost form around 70% of overall logistics costs. Considering the logistics indicators surveyed, Estonian companies show up with relatively low perfect order fulfillment rates, short customer order fulfillment cycles and effective management of cash flows. The most widely outsourced logistics function is international transportation followed by domestic transportation, freight forwarding and reverse logistics. By 2010, the outsourcing of IT systems in logistics followed by inventory management, warehousing and product customization is expected to increase more substantially. The awareness of logistics importance is still low among Estonian companies. Only 27–44% of those agree that logistics has a considerable impact on profitability, competitive advantage, top management or customer service level.

  5. Phytoremediation of Toxic Elemental and Organic Pollutants

    International Nuclear Information System (INIS)

    Meagher, Richard B.

    2000-01-01

    Phytoremediation is the use of plants to extract, sequester, and/or detoxify pollutants. Phytoremediation is widely viewed as the ecologically responsible alternative to the environmentally destructive physical remediation methods currently practiced. Plants have many endogenous genetic, biochemical, and physiological properties that make them ideal agents for soil and water remediation. Significant progress has been made in recent years in developing native or genetically modified plants for the remediation of environmental contaminants. Because elements are immutable, phytoremediation strategies for radionuclide and heavy metal pollutants focus on hyperaccumulation above-ground. In contrast, organic pollutants can potentially be completely mineralized by plants

  6. On the System of Place Name Signs in Estonian Sign Language

    Directory of Open Access Journals (Sweden)

    Liina Paales

    2011-05-01

    Full Text Available A place name sign is a linguistic-cultural marker that includes both memory and landscape. The author regards toponymic signs in Estonian Sign Language as representations of images held by the Estonian Deaf community: they reflect the geographical place, the period, the relationships of the Deaf community with hearing community, and the common and distinguishing features of the two cultures perceived by community's members. Name signs represent an element of signlore, which includes various types of creative linguistic play. There are stories hidden behind the place name signs that reveal the etymological origin of place name signs and reflect the community's memory. The purpose of this article is twofold. Firstly, it aims to introduce Estonian place name signs as Deaf signlore forms, analyse their structure and specify the main formation methods. Secondly, it interprets place-denoting signs in the light of understanding the foundations of Estonian Sign Language, Estonian Deaf education and education history, the traditions of local Deaf communities, and also of the cultural and local traditions of the dominant hearing communities. Both perspectives - linguistic and folkloristic - are represented in the current article.

  7. Estonian Air to overhaul strategy / Matt Withers

    Index Scriptorium Estoniae

    Withers, Matt

    2008-01-01

    Estonian Air on majanduslikes raskustes, mida aitaks leevendada riigipoolne toetus. Majandus- ja kommunikatsiooniminister Juhan Parts leiab, et riik peaks omama lennufirma juhatuses esimehe kohta, et mõjutada rohkem vastuvõetavaid otsuseid ja investeeringuid

  8. Estonian Golf & Country Club / Urmas Oja

    Index Scriptorium Estoniae

    Oja, Urmas, 1981-2012

    2005-01-01

    Konkursil "Eesti parim puitehitis 2005" pälvis voodrilaua eripreemia Jõelähtme Estonian Golf & Country Club'i katus. Arhitekt Andres Siim. Sisearhitekt Juta Lember. Konstruktor: AS Resand. 11 värv. ill

  9. Estonian Air / Kirsti Vainküla

    Index Scriptorium Estoniae

    Vainküla, Kirsti, 1972-

    2004-01-01

    Estonian Air reklaamib end Taani linna Aalborgi raadiojaama ilmateates. Lennukompanii pressiesindaja Epp Alatalu sõnul on firma Taanis reklaamimise põhjus see, et liinil Tallinn-Kopenhaagen sõitjate hulgas ei ole peaaegu üldse taanlasi

  10. On the System of Person-Denoting Signs in Estonian Sign Language: Estonian Name Signs

    Science.gov (United States)

    Paales, Liina

    2010-01-01

    This article discusses Estonian personal name signs. According to study there are four personal name sign categories in Estonian Sign Language: (1) arbitrary name signs; (2) descriptive name signs; (3) initialized-descriptive name signs; (4) loan/borrowed name signs. Mostly there are represented descriptive and borrowed personal name signs among…

  11. Air Baltic: Estonian Air on nurka surutud / Teele Tammeorg

    Index Scriptorium Estoniae

    Tammeorg, Teele

    2010-01-01

    Air Balticu asepresidendi Janis Vanagsi hinnangul on Estonian Air aastaid jätnud tähelepanuta oma peamised turismiturud ning on praegu halvas seisus. Air Baltic on endiselt huvitatud Estonian Airi ostust. Majandus- ja kommunikatsiooniminister Juhan Partsi seisukoht

  12. Composition of Estonian atmosphere

    International Nuclear Information System (INIS)

    Punning, J. M.; Karindi, A.

    1996-01-01

    Atmospheric study, particularly that of its chemical composition, has a long tradition in Estonia. Since middle of this century, in addition to meteorological observations, some chemical compounds in precipitations have been regularly measured in many meteorological stations. The main aim was to acquire information about the state and dynamics of the atmosphere. Therefore, main attention was paid to monitoring chemical compounds which have a direct impact on the human environment. As energy production developed intensively and SO 2 and NO x increased drastically in the atmosphere in acidic rock areas, like Scandinavia, the problem of acid rain became the most important environmental problem in Europe and North-America. As a consequence, monitoring the compounds of sulphur in precipitation was organized in Estonia. In the 1970 s, as related to large operating oil shale-based power plants, Estonia became a country , where emissions of sulphur compounds per capita were extremely high. In 1979, Estonia became a participant in the European Monitoring and Evaluation Programme - the network created to study transboundary air pollution. The aims of the precipitation chemistry study and the related problems of the formation and transformation of the atmospheric composition have varied over the years. But monitoring of pollutant (in particular, sulphur compound) loads has been a central issue. Over recent years, an attempt was made to estimate the spatial regularities of atmospheric impurities and their impact on the pH of mean monthly precipitations. Furthermore, calculations were provided to find out the origin of atmospheric impurities washed out in Estonia. Until the 1990 s, CO 2 , and some other greenhouse gas (GHG) emissions were not studied in Estonia. The first inventory of GHG for Estonia was provided in 1995 using the Intergovernmental Panel on Climate Change (IPCC) methodology

  13. Relationship between trace element content in human organs and hair

    International Nuclear Information System (INIS)

    Kinova, L.

    1993-01-01

    Autopsy samples from 22 clinically healthy human males between the ages of 20 to 52 were collected from Bulgaria for the investigation of possible correlations between trace elements in hair and body organs. Samples of heart, spleen, liver, kidney, and hair were analyzed by neutron activation analysis to determine trace element concentrations. Statistical analysis of the data did not indicate any significant correlations between elemental concentrations in hair and internal organs, probably due to the limited number of available samples. However, lower than normal selenium concentrations were found in the organ samples, indicating possible selenium deficiency. (author). 6 refs, 4 tabs

  14. Accumulative capabilities of essential nutrient elements in organs of ...

    African Journals Online (AJOL)

    Monsonia burkeana is widely used as herbal tea in South Africa. However, the accumulative capabilities (ACs) of its organs for essential nutrient elements are not documented. A study was conducted to determine the ACs for nutrient elements in fruit, leaf, stem and root of M. burkeana. Ten plants per plot, with three ...

  15. Organic waste process containing at least one radioactive element

    International Nuclear Information System (INIS)

    Le Roy, F.

    1977-01-01

    The description is given of an organic waste process containing at least one element from the group comprising strontium, cesium, iodine and ruthenium. It comprises the introduction of the organic waste and gaseous oxygen in a bath of melted salt containing an alkaline carbonate, the bath being maintained at a high temperature between 400 and 1000 0 C and at a pressure of 0.5 to 10 bars, so that the organic waste is burnt and oxidised at least partly, the element selected being retained by the bath of melted salt [fr

  16. Digimodernistlik eesti kirjanik / The Digimodernist Estonian Writer

    Directory of Open Access Journals (Sweden)

    Piret Viires

    2013-06-01

    Full Text Available The article examines the cultural situation following postmodernism in the first decade of the 21st century. To characterise this situation, the umbrella term “post-postmodernism” is used, as well as “neomodernism”, “altermodern”, “metamodernism”, “hypermodernity”, “performatism”, “critical realism” etc. All these approaches are, in a wider sense, united by their aim of opposing postmodernist cynicism and irony, and bringing back truth, simplicity and clarity. It has also been found that literature has returned or is returning to realism, and various cultural phenomena are emerging, which have been designated by the concept “new sincerity”.In descriptions of the current cultural situation, this trend seeking truth and simplicity is supported by approaches which emphasise the significance of technological developments during the last decade. A prominent figure here is Alan Kirby, who launched the term “digimodernism”, mainly linked with the adaptation and spread of Web 2.0 at the beginning of the 21st century: the blogosphere, Wikipedia, Twitter and Facebook.The article seeks answers to the question of whether we can talk about digimodernism in Estonian literature in the 2000s. In the 1990s Estonian writers were quite reluctant to undertake computer-technological experiments, and there are only a few examples of Estonian digital literature, whereas a change occurred in the 2000s. Many Estonian writers have had and still have their own blogs and surprisingly many have joined Facebook. The term “twitterature” is also familiar to Estonian writers. The article tackles the dominant topics in the blogs of Estonian writers and analyses their possible collective creative work on Facebook. A question is raised as to whether it is possible that the fragmentary narrative structure of blogs and Facebook has influenced mainstream literature.The article concludes that one essential change in Estonian literature in the

  17. Valued Estonian Music CDs / Igor Garshnek

    Index Scriptorium Estoniae

    Garšnek, Igor, 1958-

    2003-01-01

    2002. aastal välja antud eesti muusika heliplaatidest Arvo Pärt "Summa", Lepo Sumera "Chamber Music", "Baltic Voices 1.", "Sequenzen - Europäische Orgelmusik des 20. Jahrhundrets mit...", "El silenco ئ Silence. Kuldar and Marje Sink. Songs of Mother and Son", "Riho Sibul. Estonian Dream Big Band", "Rull's Royce ئ Rull's Choice"

  18. Resource and utilization of Estonian hydropower

    International Nuclear Information System (INIS)

    Raesaar, P.

    2005-01-01

    An overview of the Estonian hydropower resources and their utilization at present as well as prospective for the future are presented in this paper. A short overview of advantages of small hydropower stations and related issues is given. Some technological aspects are treated briefly. (authors)

  19. Transformational Leadership in the Estonian Defence Forces

    Directory of Open Access Journals (Sweden)

    Antek Kasemaa

    2015-06-01

    Full Text Available Purpose – The study is a contribution to the validation of the 15 items and 5 subscales Transformational Leadership Scale (TLS proposed by Rafferty and Griffin (2004. Design/methodology/approach – The sample includes participants from different levels of the Estonian Defence Forces (EDF military hierarchy (N=2570. The structure of the TLS was examined by using exploratory and confirmatory factor analyses. Additionally ANOVA was used to compare the results between different subsamples. Findings – TLS showed satisfactory reliability. Confirmatory factor analyses found TLS as valid five dimensions instrument to measure transformational leadership in the Estonian military context. Different management levels showed different emphases among the dimensions of transformational leadership. Research and practical limitations/implications – TLS will be an important tool to use in transformational leadership research in the Estonian military context and beyond. Additionally, the current research contributes to the development of alternative measurement tools besides the most commonly used MLQ. The limitation of the work will be the rather homogenous sample from the Estonian military, however it will open the door for the subsequent research using different samplings. Originality/value – The current research found TLS to be a reliable and valid instrument, very short and therefore easy to administrate, having the possibility to use it with five dimensional and as one general transformational instrument as well.

  20. Elemental composition and oxidation of chamber organic aerosol

    Directory of Open Access Journals (Sweden)

    P. S. Chhabra

    2011-09-01

    Full Text Available Recently, graphical representations of aerosol mass spectrometer (AMS spectra and elemental composition have been developed to explain the oxidative and aging processes of secondary organic aerosol (SOA. It has been shown previously that oxygenated organic aerosol (OOA components from ambient and laboratory data fall within a triangular region in the f44 vs. f43 space, where f44 and f43 are the ratios of the organic signal at m/z 44 and 43 to the total organic signal in AMS spectra, respectively; we refer to this graphical representation as the "triangle plot." Alternatively, the Van Krevelen diagram has been used to describe the evolution of functional groups in SOA. In this study we investigate the variability of SOA formed in chamber experiments from twelve different precursors in both "triangle plot" and Van Krevelen domains. Spectral and elemental data from the high-resolution Aerodyne aerosol mass spectrometer are compared to offline species identification analysis and FTIR filter analysis to better understand the changes in functional and elemental composition inherent in SOA formation and aging. We find that SOA formed under high- and low-NOx conditions occupy similar areas in the "triangle plot" and Van Krevelen diagram and that SOA generated from already oxidized precursors allows for the exploration of areas higher on the "triangle plot" not easily accessible with non-oxidized precursors. As SOA ages, it migrates toward the top of the triangle along a path largely dependent on the precursor identity, which suggests increasing organic acid content and decreasing mass spectral variability. The most oxidized SOA come from the photooxidation of methoxyphenol precursors which yielded SOA O/C ratios near unity. α-pinene ozonolysis and naphthalene photooxidation SOA systems have had the highest degree of mass closure in previous chemical characterization studies and also show the

  1. Emission from Estonian oil shale power plants

    International Nuclear Information System (INIS)

    Aunela, L.; Haesaenen, E.; Kinnunen, V.; Larjava, K.; Mehtonen, A.; Salmikangas, T.; Leskelae, J.; Loosaar, J.

    1995-01-01

    Flue gas emissions from pulverized oil shale fired boilers of Estonian and Baltic power plants have been studied. The concentrations of NO x , CO, C x H y , HCI, Hf and polycyclic aromatic hydrocarbons in flue gases have been found to be relatively low and acceptable according to German emission limits, for instance. Desulphurization degree of flue gases by SO 2 absorption with ash has been found to vary defending on boiler type and operation conditions. In spite of significant sulphur capture (average values for different boilers in the range between 68 and 77 % of the initial sulphur content of the fuel), SO 2 concentrations in flue gases remain still very high (up to 2600 mg/m 3 , 10% O 2 ). Very high concentrations of particles, especially at Estonian Power Plant (up o 6250 mg/m 3 , 10 % 0 2 ) have been detected. Heavy metal emissions were too high by the reason of particle control insufficiency as well. Yearly emission estimates of this study support the former Estonian ones within the range of 10-15 %. (author)

  2. TFIIIC bound DNA elements in nuclear organization and insulation.

    Science.gov (United States)

    Kirkland, Jacob G; Raab, Jesse R; Kamakaka, Rohinton T

    2013-01-01

    tRNA genes (tDNAs) have been known to have barrier insulator function in budding yeast, Saccharomyces cerevisiae, for over a decade. tDNAs also play a role in genome organization by clustering at sites in the nucleus and both of these functions are dependent on the transcription factor TFIIIC. More recently TFIIIC bound sites devoid of pol III, termed Extra-TFIIIC sites (ETC) have been identified in budding yeast and these sites also function as insulators and affect genome organization. Subsequent studies in Schizosaccharomyces pombe showed that TFIIIC bound sites were insulators and also functioned as Chromosome Organization Clamps (COC); tethering the sites to the nuclear periphery. Very recently studies have moved to mammalian systems where pol III genes and their associated factors have been investigated in both mouse and human cells. Short interspersed nuclear elements (SINEs) that bind TFIIIC, function as insulator elements and tDNAs can also function as both enhancer - blocking and barrier insulators in these organisms. It was also recently shown that tDNAs cluster with other tDNAs and with ETCs but not with pol II transcribed genes. Intriguingly, TFIIIC is often found near pol II transcription start sites and it remains unclear what the consequences of TFIIIC based genomic organization are and what influence pol III factors have on pol II transcribed genes and vice versa. In this review we provide a comprehensive overview of the known data on pol III factors in insulation and genome organization and identify the many open questions that require further investigation. This article is part of a Special Issue entitled: Transcription by Odd Pols. Copyright © 2012 Elsevier B.V. All rights reserved.

  3. Elements of Performance Management and Audit in Public Organizations

    Directory of Open Access Journals (Sweden)

    Gheorghe MINCULETE

    2015-12-01

    Full Text Available The concept of performance is a new one, having in mind the fact that, in order to achieve functional progress, public organizations are themselves determined to measure the results of their activity over a definite period of time. Nevertheless, a new characteristic regarding the implementation of this concept refers to the approach used by managers for putting it into practice that is the identification of the answers to the question: „What should be measured/monitored in order to have a better control over activities and which will determine their improvement?” The current article presents notions and elements specific to performance management at the level of public organizations, with a brief emphasis on the indicators and standards related to this domain.

  4. Overview of the Estonian Biofuels Association activities

    International Nuclear Information System (INIS)

    Hueues, Meelis

    2000-01-01

    Due to global warming and environment pollution because of widespread use of fossil fuels there are already tendencies to stabilize and decrease the consumption of these energy resources and take into use more renewable energy resources. Estonian Biofuels Association (EBA) is a non-profit association, which was founded on 8. of May 1998 in Tallinn. The EBA is an independent and voluntary alliance of its members. Fields of activity of the EBA are by biofuels research, developing and evaluation to engage environmental, biofuels and energy saving. EBA members are: energy consultants, scientists, as well as fuel suppliers, DH-companies, technology suppliers, energy service companies etc. The members of EBA are involved in different projects in Estonia, where biomass are produced and used for heating, where wood, waste, peat, rape oil and biogas resources are examined and put into use, and also projects which deal with energy saving and environment friendly equipment production for using biofuels. During our short experience we have noticed that people in Estonia have become more aware of biomass and their use, so the development of environment friendly and sustainable energetics will continue in Estonia. Available biofuels in Estonia could compete with fossil fuels if burnt rationally with high technology equipment. EBA members are convinced that biomass have perspective and that they could play an important role in improving Estonian economic and environmental situation. Modem biomass combustion devices are taken into use more the faster general wealth increases and EBA can raise people's awareness of bio fuel subject through special, courses and media. We want Estonian energy policy to develop towards widespread use of renewable energy resources, which would save energy and environment improve nation's foreign trade balance and create jobs mainly in rural areas

  5. Rare earth elements and neodymium isotopes in sedimentary organic matter

    Science.gov (United States)

    Freslon, Nicolas; Bayon, Germain; Toucanne, Samuel; Bermell, Sylvain; Bollinger, Claire; Chéron, Sandrine; Etoubleau, Joel; Germain, Yoan; Khripounoff, Alexis; Ponzevera, Emmanuel; Rouget, Marie-Laure

    2014-09-01

    We report rare earth element (REE) and neodymium (Nd) isotope data for the organic fraction of sediments collected from various depositional environments, i.e. rivers (n = 25), estuaries (n = 18), open-ocean settings (n = 15), and cold seeps (n = 12). Sedimentary organic matter (SOM) was extracted using a mixed hydrogen peroxide/nitric acid solution (20%-H2O2-0.02 M-HNO3), after removal of carbonate and oxy-hydroxide phases with dilute hydrochloric acid (0.25 M-HCl). A series of experimental tests indicate that extraction of sedimentary organic compounds using H2O2 may be complicated occasionally by partial dissolution of sulphide minerals and residual carbonates. However, this contamination is expected to be minor for REE because measured concentrations in H2O2 leachates are about two-orders of magnitude higher than in the above mentioned phases. The mean REE concentrations determined in the H2O2 leachates for samples from rivers, estuaries, coastal seas and open-ocean settings yield relatively similar levels, with ΣREE = 109 ± 86 ppm (mean ± s; n = 58). The organic fractions leached from cold seep sediments display even higher concentration levels (285 ± 150 ppm; mean ± s; n = 12). The H2O2 leachates for most sediments exhibit remarkably similar shale-normalized REE patterns, all characterized by a mid-REE enrichment compared to the other REE. This suggests that the distribution of REE in leached sedimentary organic phases is controlled primarily by biogeochemical processes, rather than by the composition of the source from which they derive (e.g. pore, river or sea-water). The Nd isotopic compositions for organic phases leached from river sediments are very similar to those for the corresponding detrital fractions. In contrast, the SOM extracted from marine sediments display εNd values that typically range between the εNd signatures for terrestrial organic matter (inferred from the analysis of the sedimentary detrital fractions) and marine organic matter

  6. MINORITY LANGUAGES IN ESTONIAN SEGREGATIVE LANGUAGE ENVIRONMENTS

    Directory of Open Access Journals (Sweden)

    Elvira Küün

    2011-01-01

    Full Text Available The goal of this project in Estonia was to determine what languages are spoken by students from the 2nd to the 5th year of basic school at their homes in Tallinn, the capital of Estonia. At the same time, this problem was also studied in other segregated regions of Estonia: Kohtla-Järve and Maardu. According to the database of the population census from the year 2000 (Estonian Statistics Executive Office's census 2000, there are representatives of 142 ethnic groups living in Estonia, speaking a total of 109 native languages. At the same time, the database doesn’t state which languages are spoken at homes. The material presented in this article belongs to the research topic “Home Language of Basic School Students in Tallinn” from years 2007–2008, specifically financed and ordered by the Estonian Ministry of Education and Research (grant No. ETF 7065 in the framework of an international study called “Multilingual Project”. It was determined what language is dominating in everyday use, what are the factors for choosing the language for communication, what are the preferred languages and language skills. This study reflects the actual trends of the language situation in these cities.

  7. Utilisation of Estonian energy wood resources

    Energy Technology Data Exchange (ETDEWEB)

    Muiste, P.; Tullus, H.; Uri, V. [Estonian Agricultural University, Tartu (Estonia)

    1996-12-31

    In the end of the Soviet period in the 1980s, a long-term energy programme for Estonia was worked out. The energy system was planned to be based on nuclear power and the share of domestic alternative sources of energy was low. The situation has greatly changed after the re-establishment of the Estonian independence, and now wood and peat fuels play an important role in the energy system. Energy consumption in Estonia decreased during the period 1970-1993, but this process has less influenced the consumption of domestic renewable fuels - peat and wood. It means that the share of these fuels has grown. The investment on substitution of imported fossil fuels and on conversion of boiler plants from fossil fuels to domestic fuels has reached the level of USD 100 million. The perspectives of the wood energy depend mainly on two factors; the resources and the price of wood energy compared with other fuels. The situation in wood market influences both the possible quantities and the price. It is typical that the quickly growing cost of labour power in Estonia is greatly affecting the price of energy wood. Though the price level of fuel peat and wood chips is lower than the world market price today, the conditions for using biofuels could be more favourable, if higher environmental fees were introduced. In conjunction with increasing utilisation of biofuels it is important to evaluate possible emissions or removal of greenhouse gases from Estonian forests 3 refs.

  8. Utilisation of Estonian energy wood resources

    Energy Technology Data Exchange (ETDEWEB)

    Muiste, P; Tullus, H; Uri, V [Estonian Agricultural University, Tartu (Estonia)

    1997-12-31

    In the end of the Soviet period in the 1980s, a long-term energy programme for Estonia was worked out. The energy system was planned to be based on nuclear power and the share of domestic alternative sources of energy was low. The situation has greatly changed after the re-establishment of the Estonian independence, and now wood and peat fuels play an important role in the energy system. Energy consumption in Estonia decreased during the period 1970-1993, but this process has less influenced the consumption of domestic renewable fuels - peat and wood. It means that the share of these fuels has grown. The investment on substitution of imported fossil fuels and on conversion of boiler plants from fossil fuels to domestic fuels has reached the level of USD 100 million. The perspectives of the wood energy depend mainly on two factors; the resources and the price of wood energy compared with other fuels. The situation in wood market influences both the possible quantities and the price. It is typical that the quickly growing cost of labour power in Estonia is greatly affecting the price of energy wood. Though the price level of fuel peat and wood chips is lower than the world market price today, the conditions for using biofuels could be more favourable, if higher environmental fees were introduced. In conjunction with increasing utilisation of biofuels it is important to evaluate possible emissions or removal of greenhouse gases from Estonian forests 3 refs.

  9. Estonian Air valmistub odavate piletitega EasyJeti tulekuks / Erkki Erilaid

    Index Scriptorium Estoniae

    Erilaid, Erkki

    2004-01-01

    Estonian Air pidi langetama piletihindu Berliini ja Londoni liinil kolmandiku võrra, kuna oktoobri lõpust hakkab Tallinna lennujaamast reise tegema uus odavlennufirma Easy-Jet. Lisa: Estonian Airi hinnad internetis

  10. Estonian Air lõpetab Pariisi ja Vilniuse lennud / Hindrek Riikoja

    Index Scriptorium Estoniae

    Riikoja, Hindrek

    2005-01-01

    Talvisele lennuplaanile üleminev Estonian Air lõpetab otselennud Tallinnast Vilniusesse ja Pariisi. Estonian Airi presidendi Borge Thornbechi sõnul kavatseb firma suurendada talvehooajal turismilendude mahtu

  11. Interactions of rare earth elements with bacteria and organic ligands

    International Nuclear Information System (INIS)

    Ozaki, Takuo; Suzuki, Yoshinori; Nankawa, Takuya; Yoshida, Takahiro; Ohnuki, Toshihiko; Kimura, Takaumi; Francis, Arokiasamy J.

    2006-01-01

    We investigated the interactions of rare earth elements (REEs) Eu(III) and/or Ce(III, IV) with the common soil bacterium Pseudomonas fluorescens and organic ligands, such as malic acid, citric acid, a siderophore (DFO), cellulose, chitin, and chitosan. Malic acid formed complexes with Eu(III), but degradation of malic acid was observed when the ratio of malic acid to Eu(III) was higher than 100. Citric acid formed a stoichiometric complex with Eu(III) that was not degraded by P. fluorescens. Adsorption of Eu(III) from the DFO complex occurred as a free ion dissociated from DFO and not as the Eu(III)-DFO complex. Cerium(III) was oxidized to Ce(IV) during complexation with DFO to form the Ce(IV)-DFO complex. Time-resolved laser-induced fluorescence spectroscopy (TRLFS) analysis showed that cellulose, chitin, and chitosan, respectively, formed a weak complex, an inner-spherical complex, and an outer-spherical complex with Eu(III). This method also demonstrated that the coordination environment of Eu(III) adsorbed on P. fluorescens possessed similar characteristics to that of chitin, and revealed that adsorption of Eu(III) on P. fluorescens was through a multidentate and predominantly inner-spherical coordination

  12. The figure of the teacher in Estonian school discourse

    Directory of Open Access Journals (Sweden)

    Ott Puumeister

    2014-10-01

    Full Text Available The article concerns itself with the figure of the teacher in Estonian society. We do not concentrate on the educational system as a whole, but on one specific and crucial element in this apparatus - the teacher. We begin by offering a brief historical overview of the conditions of pedagogues in the 20th century before moving on to describe the adoption of neo-liberal free market policies since the 1990s and the effects these policies had and still have on education. Our main concern is to understand the teacher as an actor in power relations; to achieve this understanding we have selected as our examples 1 surveillance techniques in school environment that have direct relations to the state and the market; and 2 the 2012 educational workers' strike that made it quite clear that the teachers have been fixed to a position of wage workers. The overall and more abstract aim of the paper is to think about the social role of the teacher in Estonia.

  13. Cresco sai lahti võlast SASile ja osalusest Estonian Airis / Rivo Sarapik, Alyona Stadnik

    Index Scriptorium Estoniae

    Sarapik, Rivo, 1981-

    2010-01-01

    Majandus- ja kommunikatsiooniminister Juhan Parts ning SAS-i asepresident Benny Zakrisson kirjutasid alla Estonian Airi ostu-müügitehingule. Investeerimispank Cresco, millele kuulus 17% Estonian Airist, jääb välja Estonian Airi omanikeringist ning SAS-i nõue Crescole tühistatakse

  14. SAS tahab Estonian Airi liita lätlaste firmaga airBaltic / Andres Eilart

    Index Scriptorium Estoniae

    Eilart, Andres

    2007-01-01

    SAS plaanib Estonian Airi ja Läti firma airBalticu liitmisega luua uue lennufirma. Autori hinnangul viitavad Estonian Airi laienemisplaanidele kriipsu peale tõmbamine ja SAS-i investeeringud airBalticusse sellele, et ühendamise käigus "neelab" Läti firma Estonian Airi

  15. Joakim Helenius: Estonian Air võtku eeskuju airBalticust / Siim Sultson

    Index Scriptorium Estoniae

    Sultson, Siim

    2010-01-01

    Estonian Airi ühe võimaliku nõukogu esimehe Jaokim Heleniuse hinnangul on väikeste lennufirmade, nagu Estonian Air ja airBaltic jaoks päris palju tegutsemisruumi. Estonian Airil tuleb leida oma nišš ja kindel, kuid omanäoline strateegia

  16. The Estonian national program for sustainable resource development and its connection with teaching about fossil fuels in chemistry courses

    International Nuclear Information System (INIS)

    Karik, H.

    1996-01-01

    The conception of sustainable resource development worked out under the initiative of the United Nations (UN) actualizes ideas for improving the health of people and the environment. The needs of people are to he addressed and, simultaneously, natural resources preserved. That is ,why ecological and economic expenses are to he integrated and flow sheets of industrial plants are to be reorganized in order to utilize natural resources in a rational way. The association of Estonia with the resolution of the UN Conference on Environmental Development held in Rio de Janeiro and the resolution of the Estonian Parliament concerning The National Program of Sustainable Development require changes in our lifestyle. Chemical education in schools has to support a change in the way of thinking and many concrete subjects can be connected with the problems of sustainable development. Metallic elements get into the environment mostly with fuel combustion ashes. According to various prognoses, fossil fuel resources will last for a thousand years. This means that more and more metallic compounds are thrown into the environment. Dispersion of metals in the air, water bodies and soil is continuously increasing. Finally, they reach the food chain and to the human body. As a result, toxicosis, illnesses, and inadvisable dislocations in organic life may occur. The trend to use ash as a raw material for metal production is considered to have some prospective economically attractive application. This would be one possible way of sustainable resource development to avoid the increase of environmental pollution and increase production of the corresponding metals

  17. Accumulative capabilities of essential nutrient elements in organs of ...

    African Journals Online (AJOL)

    use

    2011-11-23

    Nov 23, 2011 ... Cu > Mn > Zn > B. In conclusion, the ACs for essential nutrient elements differed, with the ... and Fe were quantified using Perkin Elmer Atomic Absorption .... vitamin C, protein and fat ranging from 249.6 to 266 .... Boron determination in plant tissues by ... Accumulation of cadmium and selected elements.

  18. Monitoring of organic and elemental carbon (OC/EC) in the atmospheric aerosol

    Energy Technology Data Exchange (ETDEWEB)

    Hannemann, A.; Fuchs, J.; Jaeschke, W.; Weingartner, E.; Baltensperger, U.

    2003-03-01

    A new instrument for the measurement of ambient carbonaceous aerosol concentrations is described, which enables discrimination between organic and elemental carbon on a semi-continuous basis. (author)

  19. Organotrichlorogermane synthesis by the reaction of elemental germanium, tetrachlorogermane and organic chloride via dichlorogermylene intermediate.

    Science.gov (United States)

    Okamoto, Masaki; Asano, Takuya; Suzuki, Eiichi

    2004-08-07

    Organotrichlorogermanes were synthesized by the reaction of elemental germanium, tetrachlorogermane and organic chlorides, methyl, propyl, isopropyl and allyl chlorides. Dichlorogermylene formed by the reaction of elemental germanium with tetrachlorogermane was the reaction intermediate, which was inserted into the carbon-chlorine bond of the organic chloride to give organotrichlorogermane. When isopropyl or allyl chloride was used as an organic chloride, organotrichlorogermane was formed also in the absence of tetrachlorogermane. These chlorides were converted to hydrogen chloride, which subsequently reacted with elemental germanium to give the dichlorogermylene intermediate. The reaction of elemental germanium, tetrachlorogermane and organic chlorides provides a simple and easy method for synthesizing organotrichlorogermanes, and all the raw materials are easily available.

  20. Estonian Airi president : uus äristrateegia toob ettevõttele edu / Borge Thornbech ; interv. Andres Reimer

    Index Scriptorium Estoniae

    Thornbech, Borge

    2007-01-01

    Estonian Air asutas regionaalsete lendude korraldamiseks ettevõtte Estonian Air Regional, idee on arendada tegevust lühidistantsidel ja luua ühenduslüli lennukompanii Euroopa-liinide vahel. Kommenteerivad Olev Schults, Oleg Harlamov, Rein Mark. Vt. samas: Kõik aktsionärid vannuvad Estonian Airile truudust; Estonian Air kaalub Tartu lennuliini avamist. Kaart: Reisijate jagunemine sihtkohtade vahel. Graafikud: Estonian Air kukkus kahjumisse

  1. Liberalism - Key to Entrepreneurial and Innovation Success: Estonian Case Study

    Directory of Open Access Journals (Sweden)

    Augustin Ignatov

    2017-12-01

    Full Text Available Since its independence in 1991 Estonia has successfully overpassed the challenges of the transition period being in the present of one the most technologically developed nations of Europe. The present research is intended to evaluate the relationship between Estonian pro-market regulation, entrepreneurship and innovation. In order to reach relevant conclusions in this regard there have been used both qualitative and quantitative methods of analysis. In such a way, it could be comprehensively reviewed the process of Estonian economic development from a relatively underdeveloped USSR republic to an advanced innovation driven economy. The results show that pro-market governmental regulation has favourably influenced Estonian entrepreneurship, while it fostered country’s innovation capacities. It has been concluded that the economic “miracle” of Estonia has been at a great extent determined by proper government regulation oriented towards economic liberalisation.

  2. Trace Elements in Marine Sediment and Organisms in the Gulf of Thailand

    Science.gov (United States)

    Worakhunpiset, Suwalee

    2018-01-01

    This review summarizes the findings from studies of trace element levels in marine sediment and organisms in the Gulf of Thailand. Spatial and temporal variations in trace element concentrations were observed. Although trace element contamination levels were low, the increased urbanization and agricultural and industrial activities may adversely affect ecosystems and human health. The periodic monitoring of marine environments is recommended in order to minimize human health risks from the consumption of contaminated marine organisms. PMID:29677146

  3. DISTRIBUTION OF TRACE ELEMENTS IN MUSCLE AND ORGANS ...

    African Journals Online (AJOL)

    a

    revealed organ specific distribution of trace metals in Tilapia, which has been discussed .... The concentrations of copper (Table 2) varied from 1.68–4.95 in muscle, .... The lead concentrations in muscle and organs of Tilapia from both lakes were comparable. ... A, D and K, trace minerals, and essential fats and amino acids.

  4. Ethnic Self-Esteem and Intergroup Attitudes Among the Estonian Majority and the non-Estonian Minority

    Directory of Open Access Journals (Sweden)

    Maaris Raudsepp

    2009-11-01

    Full Text Available The study was focussed on the relationships between ethnic self-esteem and various indicators of intergroup attitudes in a representative sample of adult population of Estonia (N=1142. Attitudinal variables that discriminated most between persons with high and low ethnic self-esteem were identified. Among Estonians ethnic self-esteem was related to positive ingroup bias, readiness for outgroup contact, perceived threat from the outgroup, attitudes to non-Estonian minority, and attitudes toward minority integration. Among non-Estonians ethnic self-esteem was related to readiness for outgroup contact, ethnic sterotypes, and various attitudes towards minority integration. An attempt was made to reconstruct the system of intergroup attidues of prototypical persons with high and low ethnic selfesteem and to describe psychological implications of high and low ethnic self-esteem for members of majority and minority groups. Various theoretical models (social identity theory, integrated threat theory, social dominane theory were used for interpretation of the results.

  5. Organic and volatile elements in the solar system

    Directory of Open Access Journals (Sweden)

    Remusat L.

    2012-01-01

    Full Text Available Chondrites and comets have accreted primitive materials from the early solar system. Those materials include organics, water and other volatile components. The most primitive chondrites and comets have undergone few modifications on their respective parent bodies and can deliver to laboratories components that were present at the origin of the protosolar nebula. Here I present a review of the organic material and volatile components that have been studied in the most primitive chondrites, and the last data from the stardust mission about the cometary record. This paper focuses on materials that can be studied in laboratories, by mass spectrometry, ion probes or organic chemistry techniques.

  6. Trends in phytoremediation of toxic elemental and organic pollutants

    African Journals Online (AJOL)

    OHWESIRI IBUJE

    2010-09-13

    Sep 13, 2010 ... interactions and other rhizosphere processes, plant uptake .... protein and they play important role in deciding plant's tolerance to .... molecular biology, vol. 107. Totawa, NJ: .... Simulation of organic processes. Boca Raton, FL: ...

  7. Elemental and isotopic compositions of organic carbon and nitrogen ...

    African Journals Online (AJOL)

    The general downcore trend can be attributed to systematic changes in relative proportion between C3 and C4 types of organic matter (OM), resulting from climatic changes or nutrient changes and shift between algae and higher plants. The lower most section containing the most depleted values can be attributed either to ...

  8. Friends' Organizations: The Supportive Element Essential to Libraries.

    Science.gov (United States)

    Progar, Dorothy

    Reviewed are the history and public relations, financial and service roles of lay "Friends of the Library" groups. Programs and techniques useful in the pursuit of these roles are suggested. Guidelines for a constitution, fee schedule, and administrative structure plus a bibliography give potential friends organizations help in…

  9. Organics, Meteoritic Material, and other Elements in High Altitude Aerosols

    Science.gov (United States)

    Mahoney, M.; Murphy, D. M.; Thomson, D. S.

    1998-01-01

    Recent in situ measurements of the chemical composition of single aerosol particles at altitudes up to 19 km have revealed a number of surprising features about ambient particles. Upper tropospheric aerosols in the study region often contained more organic material than sulfate.

  10. The interrelations amongst control system elements in public sector organizations.

    NARCIS (Netherlands)

    Verbeeten, F.H.M.

    2013-01-01

    The aim of this study is to explain the decisions that public sector organizations make with regard to the design and use of their management control system. New Public Management, based on economics theory, suggests that employees in the public sector should be freed from traditional bureaucratic

  11. Estonian Golf & Country Club / Liina Jänes

    Index Scriptorium Estoniae

    Jänes, Liina, 1977-

    2005-01-01

    Estonian Golf & Country Club'i etnomodernistlik golfikeskus ja klubihoone Jõelähtmel. Projekteerija: Arhitektuuristuudio Siim & Kreis. Autor Andres Siim. Konstruktor: Resand. Sisekujundaja Juta Lember (SAB Lember & Padar). Projekt 2004, valmis 2005. Ill.: I ja II korruse plaan, 3 värv. välis ja 3 sisevaadet

  12. Estonian Golf & Country Clubi klubihoone / Andres Siim, Alar Just

    Index Scriptorium Estoniae

    Siim, Andres

    2005-01-01

    Harjumaal Jõelähtme vallas rajab Estonian Golf & Country Club uut Jägala-Jõesuu spordi- ja puhkekeskust, mille südameks saab puidust golgiklubi hoone, mida tutvustavad klubihoone arhitekt ja üks inseneridest. Ill.: vaade ehitusele, projekti kaks vaadet, lõige

  13. Organizational Commitment in Estonian University Libraries: A Review and Survey

    Science.gov (United States)

    Kont, Kate-Riin; Jantson, Signe

    2014-01-01

    The data used in this article is based on the reviewing of relevant literature to provide an overview of the concepts of organizational commitment, job security, and interpersonal relations, as well as on the results of the original online survey, conducted by the article's authors, held in 2012 in Estonian university libraries governed by public…

  14. Top 10 Estonian albums of 2004 / Igor Garshnek

    Index Scriptorium Estoniae

    Garšnek, Igor, 1958-

    2004-01-01

    Heliplaatidest: Arvo Pärt "Pro et contra", Various composers "Baltic Voices 2", Raimo Kangro "Displays", Toivo Tulev "Be Lost in the Call", Indrek Vau and Mati Mikalai "Estonian Trumpet Music", Erdmann/Sooäär "Dessert Time, Peer Gynt & Other Stories", Alo Mattiisen "50 parimat laulu", Riho Sibul "Must", Rein Rannap "Tantsib klaveril", Eesti Keeled "Kella tiksumist..."

  15. Value Education in Estonian Preschool Child Care Institutions

    Science.gov (United States)

    Ülavere, Pärje; Tammik, Anu

    2017-01-01

    For systematic implementation of value education in educational institutions, the national programme "Values Development in Estonian Society 2009-2013" (Ministry of Education and Research 2009) was prepared in Estonia. However, it was launched only in 2010, and the authors intended to ascertain the values of the heads of preschool child…

  16. Studies on rare earth elements in seawater and uptake by marine organisms

    International Nuclear Information System (INIS)

    Suzuki, H.; Koyanagi, T.; Saiki, M.

    1975-01-01

    The contents of rare earth elements in marine environmental samples were determined by neutron activation analysis to examine the existing state in coastal seawater and the concentration by marine organisms of the elements. Seawater was filtered through a Millipore filter GS (pore size 0.22 μm), before the analysis. Some of the seawater was treated with HC1 solution before filtration and some after filtration. Certain marine organisms were also analysed for determination of rare earth elements. These were: flounder (Paralichthys olivaceus); yellowtails (Seriola quinqueradiata); immature anchovy (Engraulis japonica); clams (Meretrix lusoria); green algae (Ulva pertusa); brown algae (Hizikia fusiforme, Sargassum fulvellum, Undaria pinnatifida). In the seawater without HC1 treatment before filtration, considerable amounts of the elements existed in residue on the filter, whereas in the seawater treated with HC1 before filtration, the greater part remained in the dissolved state. Concentration factors calculated from the contents of stable elements, therefore, are affected remarkably by the existing state of the elements in seawater. If only the dissolved state is assumed available for marine organisms, values one order higher are attained compared with the case where total amounts of the elements were used for the calculation. However, the contribution of the insoluble state seems to be not negligible with some organisms. The higher concentration factors for immature anchovy and clams observed in this study were considered to be caused by surface adsorption of elements in particulate form and also ingested sediment with high element concentration. (author)

  17. Ion-selective electrodes in organic elemental and functional group analysis: a review

    International Nuclear Information System (INIS)

    Selig, W.

    1977-01-01

    The literature on the use of ion-selective electrodes in organic elemental and functional group analysis is surveyed in some detail. The survey is complete through Chemical Abstracts, Vol. 83 (1975). 40 figures, 52 tables, 236 references

  18. Ion-selective electrodes in organic elemental and functional group analysis: a review

    Energy Technology Data Exchange (ETDEWEB)

    Selig, W.

    1977-11-08

    The literature on the use of ion-selective electrodes in organic elemental and functional group analysis is surveyed in some detail. The survey is complete through Chemical Abstracts, Vol. 83 (1975). 40 figures, 52 tables, 236 references.

  19. Russia and the Shanghai Cooperation Organization: Some Elements of Strategy

    Directory of Open Access Journals (Sweden)

    Mikhail Konarovsky

    2016-12-01

    Full Text Available The new geopolitical reality that resulted from the dissolution of the USSR created the conditions for the establishment of the Shanghai Cooperation Organisation (SCO in 2001. The successful settlement of border issues between Russia and Kazakhstan, Kirgizstan and Tajikistan as well as with China also facilitated the process. With Uzbekistan joining the “Shanghai Five,” a new regional organization emerged. The SCO’s priorities were in the security sphere and the fight against the proliferation of drugs, illegal migration and organized crime, given the requirements of the times and the specific regional situation (including that in Afghanistan. As one of the active founders, Russia has always taken a leading role in the SCO’s organizational, political and legal formation, including setting specific trends and forms of cooperation, taking common measures, and holding events. During its presidency in 2008–2009 and 2014–2015, Moscow made additional efforts to strengthen cooperation among the SCO members in meeting new regional security challenges and to agree on coordinated positions on the key issues on the international and regional agenda. To increase the SCO’s credibility and political significance, Moscow emphasized its expansion, particularly with regard to the Eurasian Economic Union and the Silk Road Economic Belt. With global political and economic development growing more complicated, in order to revitalize Russia’s role in the SCO it is necessary to strengthen cooperation with China. The strategic character of bilateral relations reaffirmed at the Russian-Chinese summit in the summer of 2016 set a solid foundation.

  20. [Pärtel Lippus. The acoustic features and perception of the Estonian quantity system] / Stefan Werner

    Index Scriptorium Estoniae

    Werner, Stefan

    2012-01-01

    Arvustus: Pärtel Lippus. The acoustic features and perception of the Estonian quantity system. Tartu : Tartu University Press, 2011. (Dissertationes philologiae estonicae Universitatis Tartuensis ; 29)

  1. Study of the interactions between organic matter and transuranic elements

    International Nuclear Information System (INIS)

    Moulin, V.; Billon, A.; Theyssier, M.; Dellis, T.

    1991-01-01

    The study of the occurrence of humic substances present in natural waters and their physico-chemical properties, in particular their complexing behaviour, constitutes the main objectives of this research programme. In the first part, the report presents the description of the selected aquifer (representative of a granitic geological formation: Fanay-Augeres), the method for the collection and concentration of the humic substances (a sorption technique) and their characterization by different physico-chemical techniques (elementary and mineral composition, spectroscopic properties, size, proton capacity, datation). The results show that Fanay-Augeres humic substances (considered as site-specific humic substances) represent 41% of the total organic carbon (TOC) present in the aquifer (2ppm) and have properties similar to other aquatic humic substances. The second part describes the study of the interactions occurring between these humic substances and trivalent cations (Eu and Am). Two different analytical methods have been developed to perform these investigations: spectrophotometry and size-exclusion chromatography. Interaction constants and complexing capacities have been determined and compared with literature data. Fanay-Augeres humic substances present complexing for trivalent actinides which agrees with published data. Further developments needed in complexation studies are described. 10 figs.; 15 tabs.; 39 refs

  2. Influence of S186 on trace elements in organs of dogs

    International Nuclear Information System (INIS)

    Luo Meichu; Li Landi; Chen Guibao; Zhang Meizhen

    1993-01-01

    The authors report the influence of a radiostrontium de-cooperating agents, S186 (calcium sodium N-acetylproplysmine 1, 1-diphosphonate), on trace elements in internal organs of dogs. The trace elements contents were determined with a PE-3030 atomic absorption spectrophotometer. Compared with the control group, the trace elements (Cu, Zn and Mn) contents and the Cu/Zn ratio in organs of Beagle dogs after intramuscular injection of S186 for 30 days did not change obviously except the Cu content in the liver increased

  3. Estonian Air püüdis viimase hetkeni Top Toursi päästa / Mirko Ojakivi

    Index Scriptorium Estoniae

    Ojakivi, Mirko

    2010-01-01

    Estonian Air kaalus Top Toursile appiminekut, sest reisifirma oli Estonian Airil üks olulisemaid koostööpartnereid. Abi oleks puudutanud ennekõike uutele lendudele allahindluse tegemist, räägiti ka võimalikust krediidist

  4. Phrenic motoneurons: output elements of a highly organized intraspinal network.

    Science.gov (United States)

    Ghali, Michael George Zaki

    2018-03-01

    pontomedullary respiratory network generates the respiratory pattern and relays it to bulbar and spinal respiratory motor outputs. The phrenic motor system controlling diaphragm contraction receives and processes descending commands to produce orderly, synchronous, and cycle-to-cycle-reproducible spatiotemporal firing. Multiple investigators have studied phrenic motoneurons (PhMNs) in an attempt to shed light on local mechanisms underlying phrenic pattern formation. I and colleagues (Marchenko V, Ghali MG, Rogers RF. Am J Physiol Regul Integr Comp Physiol 308: R916-R926, 2015.) recorded PhMNs in unanesthetized, decerebrate rats and related their activity to simultaneous phrenic nerve (PhN) activity by creating a time-frequency representation of PhMN-PhN power and coherence. On the basis of their temporal firing patterns and relationship to PhN activity, we categorized PhMNs into three classes, each of which emerges as a result of intrinsic biophysical and network properties and organizes the orderly contraction of diaphragm motor fibers. For example, early inspiratory diaphragmatic activation by the early coherent burst generated by high-frequency PhMNs may be necessary to prime it to overcome its initial inertia. We have also demonstrated the existence of a prominent role for local intraspinal inhibitory mechanisms in shaping phrenic pattern formation. The objective of this review is to relate and synthesize recent findings with those of previous studies with the aim of demonstrating that the phrenic nucleus is a region of active local processing, rather than a passive relay of descending inputs.

  5. The Estonian study of Chernobyl cleanup workers. I. Introduction

    International Nuclear Information System (INIS)

    Rahu, Mati

    1999-01-01

    The most comprehensive epidemiological project ever performed in Estonia - The Estonian Study of Chernobyl Cleanup Workers - was the joint effort of researchers from Estonia, Finland and USA. Until September 1999, the results of this study were published in English only. To familiarize the readership of 'Eesti Arst' with the major study findings, the abridged versions of four original papers from 'Radiation Research' are presented in the current issue of the journal. For the Estonian epidemiologists, the work under this project that consists of eight sub projects was a real challenge. In the course of the study, skills were developed in writing a study protocol, preparing a questionnaire, progress reporting, documenting the structure of databases, record linkage, and problem solving. It was an exciting experience to work with top scientists like William Bigbee, John Boice, Timo Hakulinen, Ronald Jensen and Gayle Littlefield. (author)

  6. Critical Success Factors and information needs in Estonian industry

    Directory of Open Access Journals (Sweden)

    Aiki Tibar

    2002-01-01

    Full Text Available The article reports the results of the study on the critical success factors and related information needs in Estonian industry conducted in 1999. Data were collected by interviews with 27 managers and engineers from 16 manufacturing companies in various industries. Most of the critical success factors taken up were related to marketing, information management, quality management, product development and technological innovations. The information needs of managers and engineers were related to competitors, customers, markets, technology, regulations, etc. Some identified CSFs expressed also priorities for development by Estonian economic authorities: to support the implementation of new technologies and introduction of quality management methods. The finding that information management was perceived as a very critical area supports the result of the recent Finnish study on CSFs.

  7. Trace metal emissions from the Estonian oil shale fired power

    DEFF Research Database (Denmark)

    Aunela-Tapola, Leena A.; Frandsen, Flemming; Häsänen, Erkki K.

    1998-01-01

    Emission levels of selected trace metals from the Estonian oil shale fired power plant were studied. The plant is the largest single power plant in Estonia with an electricity production capacity of 1170 MWe (1995). Trace metals were sampled from the flue gases by a manual method incorporating...... in the flue gases of the studied oil shale plant contribute, however, to clearly higher total trace metal emission levels compared to modern coal fired power plants. Although the old electrostatic precipitators in the plant have been partly replaced by state-of-the-art electrostatic precipitators...... a two-fraction particle sampling and subsequent absorption of the gaseous fraction. The analyses were principally performed with ICP-MS techniques. The trace metal contents of Estonian oil shale were found to be in the same order of magnitude as of coal on average. The high total particle concentrations...

  8. Exhibition of photography from the Estonian diaspora / Ellu Maar

    Index Scriptorium Estoniae

    Maar, Ellu, 1982-

    2010-01-01

    Näitus "Photography from the Estonian Diaspora / Väliseesti foto" Kumu Kunstimuuseumis 8.10.-19.11.2010, kuraatorid Eha Komissarov ja Ellu Maar. Näitus tutvustas 1944. a. Eestist lahkunud või juba võõrsil sündinud fotograafide (Eric Soovere, Karl Hintzer, Priit Vesilind, Rein Välme jt.) loomingut ja valikut väliseesti fotoarhiividest

  9. Estonian Leader's Freedom Call Creates Storm / Anna Smolchenko

    Index Scriptorium Estoniae

    Smolchenko, Anna

    2008-01-01

    President Toomas Hendrik Ilvese esinemisest soome-ugri rahvaste maailmakongressil Hantõ-Mansiiskis, kohtumisest Venemaa presidendi Dmitri Medvedeviga, Eesti delegatsiooni saalist väljamarssimisest Venemaa riigiduuma väliskomisjoni esimehe Konstantin Kossatshovi sõnavõtu ajal. Ilmunud ka: St. Petersburg Times 1. juuli 2008, pealk.: Estonian Leader's Freedom Call Creates Controversy (lüh.). Vabariigi President töövisiidil Venemaal 27.-30.06.2008

  10. Efficiency of Estonian grain farms in 2000 2004

    Directory of Open Access Journals (Sweden)

    N. VASILIEV

    2008-12-01

    Full Text Available The aim of this study is to analyse the efficiency of Estonian grain farms after Estonia’s transition to a market economy and during the accession period to the European Union (EU. The non-parametric method Data Envelopment Analysis (DEA was used to estimate the total technical, pure technical and scale efficiency of Estonian grain farms in 2000–2004. Mean total technical efficiency varied from 0.70 to 0.78. Of the grain farms 62% are operating under increasing returns to scale. Solely based on the DEA model it is not possible to determine optimum farm scale and the range of Estonian farm sizes operating efficiently is extensive. The most pure technically efficient farms were the smallest and the largest but the productivity of small farms is low compared to larger farms because of their small scale. Therefore, they are the least competitive. Since pre-accession period to the EU, large input slacks of capital have replaced the former excessive use of labour and land. This raises the question about the effects on efficiency of the EU’s investment support schemes in new member states.;

  11. Revisiting the Estonian Cyber Attacks: Digital Threats and Multinational Responses

    Directory of Open Access Journals (Sweden)

    Stephen Herzog

    2011-01-01

    Full Text Available In April 2007, the Estonian Government moved a memorial commemorating the Soviet liberation of the country from the Nazis to a less prominent and visible location in Tallinn. This decision triggered rioting among Russian-speaking minorities and cyber terrorism targeting Estonia's critical economic and political infrastructure. Drawing upon the Estonian cyber attacks, this article argues that globalization and the Internet have enabled transnational groups—such as the Russian diaspora—to avenge their grievances by threatening the sovereignty of nation-states in cyberspace. Sophisticated and virtually untraceable political "hacktivists" may now possess the ability to disrupt or destroy government operations, banking transactions, city power grids, and even military weapon systems. Fortunately, western countries banded together to effectively combat the Estonian cyber attacks and minimize their effects. However, this article concludes that in the age of globalization, interdependence, and digital interconnectedness, nation-states must engage in increased cooperative cyber-defense activities to counter and prevent devastating Internet attacks and their implications.

  12. Conceptual co-presence of motion and emotion in the Estonian terms of personality

    Directory of Open Access Journals (Sweden)

    Heili Orav

    2010-05-01

    Full Text Available The purpose of the study was to find out whether the conceptual connection of emotion and motion is holding in the domain of personality traits. In a quantitative study 40 Estonian terms of personality traits were investigated and a conclusion was driven that, indeed, the qualities of emotionality and motion are perceived as co-present characteristics. In further data analysis some visualized measures were applied in order to get further insights into the hidden structure of the data. The self-organizing map (SOM analysis revealed an additional dimension of axiological evaluations present in the semantics and the SOM meta-analysis technique revealed groups of near synonymous words as well as gave overview of the more general structure common in the two data sets. The latter was tentatively explained by the person’s habitual level of activation.DOI: http://dx.doi.org/10.5128/ERYa6.21

  13. Chemistry of the Estonian oil-shale kukersite

    Energy Technology Data Exchange (ETDEWEB)

    Kogerman, P N

    1931-01-01

    Estonian oil shale is one of the oldest and richest oil shales in the world. The deposits occur in the Middle-Ordovician strata having a total thickness of 2.2 meters. The ultimate composition of the kerogen varied within the following limits: carbon 76.5 to 76.7 percent, hydrogen 9.1 to 9.2 percent, nitrogen 0.2 to 0.4 percent, sulfur 1.6 to 2.2 percent, chlorine 0.5 to 0.7 percent, and oxygen (by difference) 11.2 to 12.2 percent. The composition of kukersite kerogen corresponds nearly to the empirical formula (C/sub 8/H/sub 11/O)n. One of the most significant differences between kukersite, coal, and lignite is the amount of alkali-soluble substances present. Kukersite has almost no humic acids. Samples of kukersite were brominated and chlorinated. The halogenated shales showed a solubility in absolute alcohol of 26 percent compared to only 0.31 percent for untreated shale. Enriched shale (4.5 percent ash) did not react with chlorine as much as did raw shale. Apparently the mineral matter acted catalytically during chlorination. The amount of soluble extract obtained by solvent treatment of kukersite ranged from 0.22 percent with chloroform to 2.20 percent with tetrachloroethane. Heat was the most effective agent for the depolymerization of kukersite kerogen. The percentage loss of weight due to drying in air was much less than in the presence of carbon dioxide. The results indicated that on drying in air, the powdered shale loses water and a volatile substance, probably the oxides of carbon, up to 80/sup 0/C. Carbon dioxide was also found to be present in the gases eliminated at the temperature of initial decomposition. Pulverized shale, heated for 6 hours at 220/sup 0/C, lost 2.6 percent of its weight; its solubility in carbon disulfide was 2.11 percent. Kukersite kerogen was formed from compounds that were resistent to bacteriological decomposition, such as waxes and resins, plus decomposition products of proteins, cellulose, and putrefaction products of

  14. Olev Schults : SAS vajab Estonian Airi rahvusliku lennufirmana / Olev Schults ; interv. Andres Reimer

    Index Scriptorium Estoniae

    Schults, Olev

    2008-01-01

    Estonian Airi nõukogu esimees vastab küsimustele, kas SAS arendas Läti airBalticut Estonian SAS-i arvel, mis mõte on rahvuslikul lennukompaniil, kui riik ei tohi seda finantseerida, kuidas mõjutab investorite meeleolu SAS-i Eestis tabanud poliitikute kriitika tulv

  15. The Representation of the Cold War in Three Estonian History Textbooks

    Science.gov (United States)

    Korbits, Keit

    2015-01-01

    The article looks at the discursive strategies different Estonian history textbooks employ to represent the Cold War period, and the "commonsense" ideologies instilled through these representations. The textbooks analysed include two history books dating back to the Estonian Soviet Socialist Republic and, for contrast, one written during…

  16. Re-conceptualizing mother tongue tuition of Estonian abroad as a transnational phenomenon

    Directory of Open Access Journals (Sweden)

    Maarja Siiner

    2017-05-01

    Full Text Available The governmental initiative called the Compatriots Programme, which supports language tuition in Estonian schools and societies abroad, reveals an increased interest in developing intergenerational language transmission in the growing Estonian diaspora. This transnational language political activity signals a new era in language policy, where nation states are increasingly decentralized by migration. The evaluation of the program furthermore reveals that organizing such schools requires a willingness to take language political agency, typically conducted by well-educated and well-integrated resourceful transnational multilingual parents. The present article outlines the results of an ethnographic study of the process of establishing the Estonian School in Copenhagen. This step has demanded a change in the mindset still prevailing in Estonia that language political activities, such as planning language acquisition, are solely the responsibility of the state. Since the prevailing language ideology in Denmark is not favorable towards multilingualism in migrant languages, intergenerational language transmission furthermore presupposes a feeling of ownership of the language and high language self-esteem. "Hargmaise keelepoliitika sünd. Eesti keeleõppe korraldamise võimalikkusest välismaal Taani näitel" Hargmaisus, kasvav väljarändajate arv ja sellega ka eesti keele rääkijate hulk välismaal on jätnud oma jälje eesti keelepoliitikale. Kui varem uuriti peamiselt seda, kuidas eesti keel muukeelses kontekstis muutub, siis viimasel kümnendil on riik asunud aktiivselt toetama eesti keele jätkuvat kasutamist välismaal, rahastades rahvuskaaslaste programmi abil haridusprogramme. Kuid millised faktorid määravad selle, kas uus eestlaste põlvkond oskab ja tahab eesti keelt rääkida? Artikkel hindab etnograafilises ja sotsiolingvistilises võtmes Kopenhaagenis kolm aastat tegutsenud Eesti Kooli ja Lasteklubi näitel, millised on keelekasutust

  17. Assessment of Human Organism's Intake of Trace Elements from Staple Foodstuffs in Central Region of Russia

    CERN Document Server

    Gorbunov, A V; Okina, O I; Frontasyeva, M A; Gundorina, S F

    2004-01-01

    The trace element content of raw materials and foodstuffs produced from them, typical for basket of goods of residents of Central Russia, was examined. An excess of permissible levels of some trace elements was observed. This phenomenon is explained in terms of different factors such as pollution of the environment, industrial technologies, biological peculiarities of raw materials of animal and vegetable origin. An assessment of human organism's trace element intake of different food allowances is given. This study was undertaken in the framework of IAEA CRP (Contract No. 11927/R2).

  18. Eco-organic tourism as an element of the sustainable development of territories

    Science.gov (United States)

    Ivanov, D. V.; Ziganshin, I. I.

    2018-01-01

    Organic agricultural production is an ecologically oriented alternative to traditional agriculture and is aimed at ensuring food and environmental safety of the population and territories. The development of ecological tourism on the basis of organic production farms is considered as a promising direction in the development of regional programs for the sustainable development of territories. Studies have shown that, farms engaged in the production of organic products in the Republic of Tatarstan have a significant potential for the development of eco-organic tourism using elements of the nature protection structure.

  19. Uniting the Divided Continent. The Estonian National Committee of the European Movement

    Directory of Open Access Journals (Sweden)

    Pauli Heikkilä

    2010-12-01

    Full Text Available The article examines the exiled Estonian politicians in the European Movement in the early Cold War period. The ultimate goal of exiled Estonians was to restore their state’s independence. In order to promote this, Estonian leaders sought connections with Western leaders. The European Movement was the only organisation involving actors from both the East and the West, and this corresponded to the Estonian discourse on Europe as a whole. Therefore, the European Movement was appreciated, although its limited opportunities for decisive actions were also recognised. East and West European interest in the European Movement declined as West European integration rapidly intensified through the European Coal and Steel Community (ECSC and particularly after the January 1952 Eastern European Conference in London. By 1957, disappointment in the inability of European unification to help regain Estonian independence became evident.

  20. Heavy metals and other elements in serum of cattle from organic and conventional farms.

    Science.gov (United States)

    Tomza-Marciniak, Agnieszka; Pilarczyk, Bogumiła; Bąkowska, Małgorzata; Pilarczyk, Renata; Wójcik, Jerzy

    2011-11-01

    Concentrations of cadmium, lead, iron, zinc, copper, chromium, nickel, aluminium and arsenium were analysed in blood serum of cattle from organic (n=20) and conventional (n=21) farms. The elements were determined by inductively coupled plasma atomic emission spectrometry using an Optima 2000 DV instrument (Perkin Elmer Inc.). Animals from the organic farm were characterised by significantly lower (Panimals from the conventional farm. The concentration of Cd was similar in animals from both organic and conventional farms. The concentration of toxic elements in cattle from organic and conventional farms studied was very low. The trace essential elements were generally within the adequate ranges except Zn and Cu, which were deficient. In organically reared animals, also serum Fe content was below the critical level for diagnosing iron deficiency. Pb was significantly correlated with Cd, Zn, Fe, Cu and Ni. A significant positive correlation between the concentration of Cd and Zn, Cu and Ni concentrations was only observed in cows from the organic farm. The present results suggest that organically raised animals are less exposed to harmful environmental influences such as the environmental pollution with heavy metals. On the other hand, these animals are at a greater risk of mineral deficiency compared to animals kept on conventional farms.

  1. Influence of acid rain and organic matter on the adsorption of trace elements on soil

    International Nuclear Information System (INIS)

    Wang, H.; Ambe, S.; Takematsu, N.; Ambe, F.

    1998-01-01

    Acid rain has become one of the most serious environmental problems. Soil loses its buffering capacity by long exposure to acid rain, and the soil pH value decreases significantly. The acidification of the soil disturbs the adsorption equilibrium of many elements in the soil-water system. Soil is a very complex heterogeneous system, primarily consisting of clay minerals, hydrous oxides and polymeric organic substances, which possess their own characteristic element-adsorbing properties. On the other hand, the intrinsic properties of elements are reflected in their adsorption process as a matter of course. Therefore, both the effects of the pH of acid rain and that of the components of the soil on the adsorption of different elements should be studied when the adsorption process in acid soils is to be clarified. Although leaching of major cations in soil, such as Ca 2+ , Mg 2+ and Al 3+ , by acid rain, has been extensively studied, relatively little attention has been focused on trace elements which can also seriously affect the ecological system. We studied the acid rain effects on element adsorption by kaolin, forest soil, black soil, and also these soils with Fe- and Mn-oxides or organic matter selectively removed by using the radioactive multitracer technique. (author)

  2. Behaviour of trace element concentration in human organs in dependence of age and environment

    International Nuclear Information System (INIS)

    Persigehl, M.; Schicha, H.; Kasperek, K.; Feinendegen, L.E.; Kernforschungsanlage Juelich G.m.b.H.

    1977-01-01

    To study the behaviour of trace elements in dependence of age and environment, samples of skin, lung, heart, aorta, kidney, liver and brain were assayed for concentrations of Fe, Zn, Rb, Co, Cr, Se, Sc, Sb, Cs, Al and partly Eu. All samples were dried at 100 deg C for two days. Instrumental neutron-activation analysis was used to determine the element concentrations. The neutron flux was 5 x 10 13 n cm -2 sec -1 . After decay of the short lived radioisotopes, the Al-concentration was measured following a second irradiation of 1 minute and directly comparing with a standard sample. Nearly all element concentrations changed with processing age, but they showed no clear correlation to either parameter assessed. The non-essential elements Se, Sb and Sc were increasingly concentrated in all organs except the skin. Comparing lung samples of patients from highly industrialized regions with those of lesser industrialization, the elements Sc, Al, Sb, Eu and Co were accumulated by a factor of 10 to 100. Thus the concentrations of trace elements in human organism also depend on the degree of industrialization. (T.G.)

  3. Online Tutoring Procedure for Research Project Supervision: Management, Organization and Key Elements

    Science.gov (United States)

    Darder Mesquida, Antònia; Pérez Garcias, Adolfina

    2015-01-01

    Research project tutoring appears as a crucial element for teaching; it is a planned action based on the relationship between a tutor and a student. This paper presents the findings of a design and development research which has as its main aim to create an organization system for the tutoring of online research projects. That system seeks to…

  4. Separation of organic compounds binding trace elements in seeds of Leuzea carthamoides (Willd.)DC

    Czech Academy of Sciences Publication Activity Database

    Pavlíková, D.; Pavlík, Milan; Vašíčková, Soňa; Száková, J.; Tlustoš, P.; Vokáč, Karel; Balík, J.

    2004-01-01

    Roč. 18, - (2004), s. 619-625 ISSN 0268-2605 R&D Projects: GA MZe QD1256 Institutional research plan: CEZ:AV0Z4055905 Keywords : trace elements * sequential analysis * Leuzea carthamoides Subject RIV: CC - Organic Chemistry Impact factor: 1.385, year: 2004

  5. Concentrations of transuranic elements in critical organs and tissues of goats (CAPRA HIRCUS)

    International Nuclear Information System (INIS)

    Averin, V.S.; Vaskovtsova, V.A.; Kuhtsevich, A.B.; Tagai, S.A.; Tsarenok, A.A.; Buzdalkin, K.N.; Gvozdik, A.F.; Makarovets, I.V.; Nilova, E.K.

    2012-01-01

    Parameters of Am 241 and Pu 238, 239+240 transfer from the dietary soil-based component (mineral soil) to organs and tissues of goats during a grazing period of 80 and 160 days have been determined. The maximum specific activities of transuranic elements have been found in liver of goats. (authors)

  6. Elemental and organic carbon in aerosols over urbanized coastal region (southern Baltic Sea, Gdynia).

    Science.gov (United States)

    Lewandowska, Anita; Falkowska, Lucyna; Murawiec, Dominika; Pryputniewicz, Dorota; Burska, Dorota; Bełdowska, Magdalena

    2010-09-15

    Studies on PM 10, total particulate matter (TSP), elemental carbon (EC) and organic carbon (OC) concentrations were carried out in the Polish coastal zone of the Baltic Sea, in urbanized Gdynia. The interaction between the land, the air and the sea was clearly observed. The highest concentrations of PM 10, TSP and both carbon fractions were noted in the air masses moving from southern and western Poland and Europe. The EC was generally of primary origin and its contribution to TSP and PM 10 mass was on average 2.3% and 3.7% respectively. Under low wind speed conditions local sources (traffic and industry) influenced increases in elemental carbon and PM 10 concentrations in Gdynia. Elemental carbon demonstrated a pronounced weekly cycle, yielding minimum values at the weekend and maximum values on Thursdays. The role of harbors and ship yards in creating high EC concentrations was clearly observed. Concentration of organic carbon was ten times higher than that of elemental carbon, and the average OC contribution to PM 10 mass was very high (31.6%). An inverse situation was observed when air masses were transported from over the Atlantic Ocean, the North Sea and the Baltic Sea. These clean air masses were characterized by the lowest concentrations of all analysed compounds. Obtained results for organic and elemental carbon fluxes showed that atmospheric aerosols can be treated, along with water run-off, as a carbon source for the coastal waters of the Baltic Sea. The enrichment of surface water was more effective in the case of organic carbon (0.27+/-0.19 mmol m(-2) d(-1)). Elemental carbon fluxes were one order of magnitude smaller, on average 0.03+/-0.04 mmol m(-2) d(-1). We suggest that in some situations atmospheric carbon input can explain up to 18% of total carbon fluxes into the Baltic coastal waters. Copyright 2010 Elsevier B.V. All rights reserved.

  7. Effect of organic substrates on available elemental contents in nutrient solution

    Energy Technology Data Exchange (ETDEWEB)

    Ao, Y.S.; Sun, M.; Li, Y.Q. [Shanghai Jiao Tong University, Shanghai (China). School for Agriculture & Biology

    2008-07-15

    In this paper, the changes of available elemental contents in the nutrient solution extracts of organic substrates (peat moss, charred rice husk, chicken manure, sawdust, turfgrass clipping and weathered coal) were studied and compared with that in the water extracts. Results showed that available elemental contents in the nutrient solution extracts are significantly different between organic substrates, whereas ionic concentrations are basically under steady condition after treatment for 36-108 h. Ionic contents in the nutrient solution extracts are not equal to the value of adding ionic concentrations in the supplied nutrient solution to that in the water extract. Thus, a mathematical model was proposed for adjusting the composition of supplied nutrient solution to match plant requirements in the organic soilless culture system.

  8. Revisiting the elemental composition and the calorific value of the organic fraction of municipal solid wastes.

    Science.gov (United States)

    Komilis, Dimitrios; Evangelou, Alexandros; Giannakis, Georgios; Lymperis, Constantinos

    2012-03-01

    In this work, the elemental content (C, N, H, S, O), the organic matter content and the calorific value of various organic components that are commonly found in the municipal solid waste stream were measured. The objective of this work was to develop an empirical equation to describe the calorific value of the organic fraction of municipal solid waste as a function of its elemental composition. The MSW components were grouped into paper wastes, food wastes, yard wastes and plastics. Sample sizes ranged from 0.2 to 0.5 kg. In addition to the above individual components, commingled municipal solid wastes were sampled from a bio-drying facility located in Crete (sample sizes ranged from 8 to 15 kg) and were analyzed for the same parameters. Based on the results of this work, an improved empirical model was developed that revealed that carbon, hydrogen and oxygen were the only statistically significant predictors of calorific value. Total organic carbon was statistically similar to total carbon for most materials in this work. The carbon to organic matter ratio of 26 municipal solid waste substrates and of 18 organic composts varied from 0.40 to 0.99. An approximate chemical empirical formula calculated for the organic fraction of commingled municipal solid wastes was C(32)NH(55)O(16). Copyright © 2011 Elsevier Ltd. All rights reserved.

  9. Relation between the location of elements in the periodic table and various organ-uptake rates.

    Science.gov (United States)

    Ando, A; Ando, I; Hiraki, T; Hisada, K

    1989-01-01

    Fifty four elements and 65 radioactive compounds were examined to determine the organ uptake rates for rats 3, 24 and 48 h after i.v. injection of these compounds. They were prepared as carrier free nuclides, or containing a small amount of stable nuclide. Generally speaking, behaviors of K, Rb, Cs and Tl in all the organs were very similar to one another, but they differed from that of Na. Bivalent hard acids were avidly taken up into bone; therefore, uptake rates in soft tissues were very small. Hard acids of tri-, quadri- and pentavalence which were taken up into the soft tissue organs decreased more slowly from these organs than other ions. Soft acids such as Hg2+ were bound very firmly to the component in the kidney. Anions (with few exceptions), GeCl4 and SbCl3 were rapidly excreted in urine, so that the uptake rates in organs were low.

  10. Inorganics in Organics: Tracking down the Intrinsic Equilibriums between Organic Molecules and Trace Elements in Oceanic Waters

    Science.gov (United States)

    Lechtenfeld, O. J.; Koch, B. P.; Kattner, G.

    2010-12-01

    Recent developments in analytical instrumentation enable to describe biogeochemical processes in oceanic waters on a molecular level. This is the prerequisite to integrate biological and geochemical parameters and to develop chemical cycles on a global perspective. The state-of-the-art Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) applications for dissolved organic matter (DOM) focus mainly on carbon, hydrogen, oxygen and nitrogen isotopes. Implementation of sulfur and especially phosphorus in the molecular formula assignment has been questionable because of ambiguous calculated elemental formulas. On the other hand, many compounds bearing these elements are well known to occur in the dissolved state as part of the permanent recycling processes (e.g. phospholipids, phosphonates) but analytics of dissolved organic phosphorus (DOP) and sulfur (DOS) are often hampered by the large inorganic P and S pools. Even less is known about complexation characteristics of the DOM moieties. Although electrochemical methods provide some information about trace metal speciation, the high amount of organic molecules and its insufficient description as chemical functional classes prevent the assignment of trace metals to ligand classes. Nevertheless, it is undoubtful that a varying but extensive amount of transition metals is bond in form of organic complexes. Hyphenation of reversed phase high performance liquid chromatography (RP-HPLC) with high resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) is a valuable tool to study these metal-organic interactions in a qualitative and quantitative approach. We established a desolvation method that allows direct transfer of high organic solvent loads into the plasma. Thus, in combination with internal standardization and external calibration, the investigation of a broad polarity scale was possible. This approach overcomes previous restrictions to non-organic solvent separation techniques like size

  11. Estonian Language of Technology as a Factor Supporting the Evolution of Engineering Thinking

    Directory of Open Access Journals (Sweden)

    Mägi, Vahur

    2013-03-01

    Full Text Available Casual mention of teaching technology subjects in Estonian schools dates back several centuries. Navigation and construction were amongthe earliest professional skills that were taught. As both of them required mathematical thinking skills, teaching the subjects was usually accompanied by explaining the principles of mathematics. The first technology book in Estonian was published about two centuries ago and it dealed with geodesy. The earliest Estonian glossaries of technological terminology were published in the fields of physics and chemistry. The rise of Estonian as a language of higher education and science in the country came about in the 1920s and 1930s. Faculty members of the Tallinn School of Technology then published the first textbooks composed in the Estonian language for students of technology. The Estonian Society for Technology and the Estonian Association of Engineers became seriously involved in linguistic activities. Together with the Vocational Teachers’ Assembly of Tartu they published an illustrated technology glossary for machinery and tools terms. It was followed by a glossary of construction and building terms, compiled under the lead of the University of Technology. In addition, journals of technology introducedinnovations in the lexicon of technology to the general public. The postwar period in the development of the lexicon of technical terms was of little significance at first. A surge in language creativity could be detected in the 1960s, when terminology became a target of constantly growing attention to the development of technology lexicon. Series of technology glossaries were published. This tendency has continued to this day.

  12. E-Banking: Risk Management Practices of the Estonian Banks

    OpenAIRE

    Dmitri Sokolov

    2007-01-01

    During the last years the development of e-banking in Estonia has been very significant. According to the report of the World Economic Forum, the Estonian IT-development has been substantial. The success of e-banking in Estonia can be compared to the corresponding success of the Nordic countries. According to the Deutsche Bank Research, around 70-80% of the Internet users in Estonia use Internet banking and in this respect, Estonia could be compared to Finland, Norway and Iceland. Despite of ...

  13. Studies in Bangladesh on ingestion and organ content of trace elements of importance in radiological protection

    International Nuclear Information System (INIS)

    Begum, M.; Miah, M.F.K.

    1998-01-01

    In order to characterize a Reference Asian Man for radiation protection a study on the ingestion and organ content of trace elements of importance in radiological protection has been taken up by the IAEA/RCA among the Asian Countries. Representative sampling sample collection, appropriate techniques for analysis, quality assurance etc. for the study of this project are important parameters for accurate measurements. Some elemental composition in drinking supply water (Tap water and ground water) in the Dhaka city in Bangladesh has been presented in this paper. (author)

  14. Determination of elemental composition of metals using ambient organic mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Shiea, Christopher [Department of Medical Laboratory Science and Biotechnology, Kaohsiung Medical University, 100 Shih-Chuan 1st Rd, Kaohsiung 807, Taiwan (China); Huang, Yeou-Lih [Department of Medical Laboratory Science and Biotechnology, Kaohsiung Medical University, 100 Shih-Chuan 1st Rd, Kaohsiung 807, Taiwan (China); Department of Chemistry, National Sun Yat-Sen University, 70 Lien-Hai Rd, Kaohsiung 804, Taiwan (China); Cheng, Sy-Chyi; Chen, Yi-Lun [Department of Chemistry, National Sun Yat-Sen University, 70 Lien-Hai Rd, Kaohsiung 804, Taiwan (China); Shiea, Jentaie, E-mail: jetea@mail.nsysu.edu.tw [Department of Chemistry, National Sun Yat-Sen University, 70 Lien-Hai Rd, Kaohsiung 804, Taiwan (China); Department of Medicinal and Applied Chemistry, Kaohsiung Medical University, 100 Shih-Chuan 1st Rd, Kaohsiung 807, Taiwan (China)

    2017-05-22

    Conventional inorganic mass spectrometric (MS) analysis of metals can require time-consuming and tedious sample preparation. We thus report the novel and direct characterization of metals in solid samples using an organic MS technique known as electrospray laser desorption ionization mass spectrometry (ELDI/MS). No sample pretreatment was needed, and results were rapidly obtained due to the ambient and laser-based nature of ELDI/MS. Metals from samples were desorbed and ionized by laser irradiation, after which they reacted with EDTA and then post-ionized and detected as metal-EDTA complexes. Aluminum, copper, iron, lead, nickel, and zinc from plates, foils, and coins were characterized in seconds. This study demonstrates that an ESI/MS system can be easily modified to analyze metal elements in solids by involving a chelating agent, indicating a potentially promising development in MS towards the analysis of metals using organic MS. - Highlights: • “Organic MS” was utilized as “inorganic MS” to detect metal ions in solid samples. • Element ions desorbed by laser irradiation rapidly reacted with a chelating reagent before they were detected by MS. • Elemental composition of metals was determined by this “Organic MS” method.

  15. Determination of elemental composition of metals using ambient organic mass spectrometry

    International Nuclear Information System (INIS)

    Shiea, Christopher; Huang, Yeou-Lih; Cheng, Sy-Chyi; Chen, Yi-Lun; Shiea, Jentaie

    2017-01-01

    Conventional inorganic mass spectrometric (MS) analysis of metals can require time-consuming and tedious sample preparation. We thus report the novel and direct characterization of metals in solid samples using an organic MS technique known as electrospray laser desorption ionization mass spectrometry (ELDI/MS). No sample pretreatment was needed, and results were rapidly obtained due to the ambient and laser-based nature of ELDI/MS. Metals from samples were desorbed and ionized by laser irradiation, after which they reacted with EDTA and then post-ionized and detected as metal-EDTA complexes. Aluminum, copper, iron, lead, nickel, and zinc from plates, foils, and coins were characterized in seconds. This study demonstrates that an ESI/MS system can be easily modified to analyze metal elements in solids by involving a chelating agent, indicating a potentially promising development in MS towards the analysis of metals using organic MS. - Highlights: • “Organic MS” was utilized as “inorganic MS” to detect metal ions in solid samples. • Element ions desorbed by laser irradiation rapidly reacted with a chelating reagent before they were detected by MS. • Elemental composition of metals was determined by this “Organic MS” method.

  16. Arabidopsis and the Genetic Potential for the Phytoremediation of Toxic Elemental and Organic Pollutants

    Science.gov (United States)

    Cobbett, Christopher S.; Meagher, Richard B.

    2002-01-01

    In a process called phytoremediation, plants can be used to extract, detoxify, and/or sequester toxic pollutants from soil, water, and air. Phytoremediation may become an essential tool in cleaning the environment and reducing human and animal exposure to potential carcinogens and other toxins. Arabidopsis has provided useful information about the genetic, physiological, and biochemical mechanisms behind phytoremediation, and it is an excellent model genetic organism to test foreign gene expression. This review focuses on Arabidopsis studies concerning: 1) the remediation of elemental pollutants; 2) the remediation of organic pollutants; and 3) the phytoremediation genome. Elemental pollutants include heavy metals and metalloids (e.g., mercury, lead, cadmium, arsenic) that are immutable. The general goal of phytoremediation is to extract, detoxify, and hyperaccumulate elemental pollutants in above-ground plant tissues for later harvest. A few dozen Arabidopsis genes and proteins that play direct roles in the remediation of elemental pollutants are discussed. Organic pollutants include toxic chemicals such as benzene, benzo(a)pyrene, polychlorinated biphenyls, trichloroethylene, trinitrotoluene, and dichlorodiphenyltrichloroethane. Phytoremediation of organic pollutants is focused on their complete mineralization to harmless products, however, less is known about the potential of plants to act on complex organic chemicals. A preliminary survey of the Arabidopsis genome suggests that as many as 700 genes encode proteins that have the capacity to act directly on environmental pollutants or could be modified to do so. The potential of the phytoremediation proteome to be used to reduce human exposure to toxic pollutants appears to be enormous and untapped. PMID:22303204

  17. A multidimensional approach to assessing the elemental status of an organism

    Science.gov (United States)

    Akimov, S.; Vedeneev, P.; Kiyaeva, E.; Laryushina, I.; Notova, S.; Pishchukhin, A.

    2017-10-01

    Multidimensional space is a convenient means of representing large amounts of information. This fully applies to information on the elemental status of population groups. The novelty of the approach of this study is based on the fact that the totality of the weight parts of all elements of the periodic table together makes up the weight of a person. In a multidimensional space, organisms with the same weight have the same sum of coordinates and are located on one hyperplane. Since for any norms it is important to have a ratio between the quantities that reflect the content of the chemical elements - a ray becomes the standard, for each point of which the ratio between the coordinates is observed. Large amounts of data will adequately represent the proximity an organism to one or another class, that is, increasing the accuracy of diagnosing the elemental status. The algorithm for diagnosing, therefore, should include finding the corresponding hyperplane, the point of intersection with the ray and determining the proximity to this point.

  18. Artificial neural networks applied to quantitative elemental analysis of organic material using PIXE

    International Nuclear Information System (INIS)

    Correa, R.; Chesta, M.A.; Morales, J.R.; Dinator, M.I.; Requena, I.; Vila, I.

    2006-01-01

    An artificial neural network (ANN) has been trained with real-sample PIXE (particle X-ray induced emission) spectra of organic substances. Following the training stage ANN was applied to a subset of similar samples thus obtaining the elemental concentrations in muscle, liver and gills of Cyprinus carpio. Concentrations obtained with the ANN method are in full agreement with results from one standard analytical procedure, showing the high potentiality of ANN in PIXE quantitative analyses

  19. Artificial neural networks applied to quantitative elemental analysis of organic material using PIXE

    Energy Technology Data Exchange (ETDEWEB)

    Correa, R. [Universidad Tecnologica Metropolitana, Departamento de Fisica, Av. Jose Pedro Alessandri 1242, Nunoa, Santiago (Chile)]. E-mail: rcorrea@utem.cl; Chesta, M.A. [Universidad Nacional de Cordoba, Facultad de Matematica, Astronomia y Fisica, Medina Allende s/n Ciudad Universitaria, 5000 Cordoba (Argentina)]. E-mail: chesta@famaf.unc.edu.ar; Morales, J.R. [Universidad de Chile, Facultad de Ciencias, Departamento de Fisica, Las Palmeras 3425, Nunoa, Santiago (Chile)]. E-mail: rmorales@uchile.cl; Dinator, M.I. [Universidad de Chile, Facultad de Ciencias, Departamento de Fisica, Las Palmeras 3425, Nunoa, Santiago (Chile)]. E-mail: mdinator@uchile.cl; Requena, I. [Universidad de Granada, Departamento de Ciencias de la Computacion e Inteligencia Artificial, Daniel Saucedo Aranda s/n, 18071 Granada (Spain)]. E-mail: requena@decsai.ugr.es; Vila, I. [Universidad de Chile, Facultad de Ciencias, Departamento de Ecologia, Las Palmeras 3425, Nunoa, Santiago (Chile)]. E-mail: limnolog@uchile.cl

    2006-08-15

    An artificial neural network (ANN) has been trained with real-sample PIXE (particle X-ray induced emission) spectra of organic substances. Following the training stage ANN was applied to a subset of similar samples thus obtaining the elemental concentrations in muscle, liver and gills of Cyprinus carpio. Concentrations obtained with the ANN method are in full agreement with results from one standard analytical procedure, showing the high potentiality of ANN in PIXE quantitative analyses.

  20. Structural Organization of Muscular Elements of a Skin-Muscular Sac of Trematodes: Literature Survey

    OpenAIRE

    Kanat Kambarovich Akhmetov; Irina Yurievna Chidunchi

    2015-01-01

    The issue of structural organization of muscular elements of a trematodes’ skin-muscular sac is considered in the study. Special attention is paid to an analysis of materials of preceding researches, study of foreign authors and also to additional literature reflecting peculiarities of structure of a trematodes’ body muscular system. The stated issue is insufficiently studied and calls for further researches. A comparative analysis of places of trematodes’ localization, taking into considerat...

  1. Smoking habits and attitudes towards smoking among Estonian physicians.

    Science.gov (United States)

    Pärna, K; Rahu, K; Rahu, M

    2005-05-01

    This study examined the smoking habits and attitudes towards smoking among Estonian physicians. Cross-sectional data for 2668 physicians were gathered by a self-administered postal survey. The current smoking prevalence was 24.9% for male physicians and 10.8% for female physicians. The percentages of ex-smokers were 32.9 and 16.8%, respectively. Smoking prevalence among physicians was below the levels reported for the highest educational bracket of the total population in Estonia. Non-smoking physicians had more unfavourable views towards smoking than those who smoked. The majority of physicians were aware of the association between smoking and various diseases, with significant differences between smokers and non-smokers. Non-smoking physicians were more active in asking patients about smoking habits than those who smoked. Most Estonian physicians, especially those who smoked, failed to perceive themselves as positive role models. This study found a lower prevalence of smoking among physicians compared with the general population, and demonstrated the impact of personal smoking on physicians' attitudes towards smoking. The results provide an important challenge to medical education in Estonia.

  2. Development of a breeding objective for Estonian Holstein cattle

    Directory of Open Access Journals (Sweden)

    E. PÄRNA

    2008-12-01

    Full Text Available Economic weights for milk carrier (water plus lactose, fat and protein yields, calving interval, age at first service, interval between the first service and conception of heifers and length of productive life of Estonian Holsteins were estimated under assumed milk production quota and for non-quota conditions. A bio-economic model of an integrated production system of a closed herd was used. Economic values of milk carrier yield and length of productive life differed between quota and non-quota conditions, but there were only minor differences between those marketing systems in economic values for functional traits. The standardised economic values of the most important traits varied in magnitude between18 to 81% of the economic value for milk yield. Discounting had a substantial impact on the economic value of length of productive life. When defining the breeding objective for Estonian Holstein, the interval between the first service and conception of heifers, and the length of productive life should be included in the breeding goal along with the traits with the highest economic value, milk, fat and protein yield. In the optimum breeding objective, relative weights of production vs. functional traits were 79 and 21%, respectively.;

  3. Acquisition of noun derivation in Estonian and Russian L1

    Directory of Open Access Journals (Sweden)

    Reili Argus

    2018-04-01

    Full Text Available Acquisition of derivation is not a well-studied area in first language research and a comparative approach to the acquisition of derivation in different languages doesn’t exist. There is no information on how a child acquires derivation in a language with a rich and regular system of derivational patterns, or in a language where derivation is productive, but the system of derivational patterns is opaque. According to general ideas of complexity in a language, the child should start to use simplex stems first and, only after that, complex ones, that is, complexity should increase in the course of acquisition. Our paper is intended to address these issues, based on longitudinal child data from typologically different languages, Estonian and Russian. The results revealed significant differences in the acquisition of noun derivation in the two languages under observation. The system of noun derivation is acquired at a faster pace in Russian, while Estonian children have far fewer noun derivatives in their speech and they use different derivation suffixes with less regularity. Even so, the so-called building block model may be applied for both languages only partially.

  4. Physical-mathematical model for cybernetic description of the human organs with trace element concentrations as input variables

    International Nuclear Information System (INIS)

    Mihai, Maria; Popescu, I.V.

    2003-01-01

    In this paper we report a physical-mathematical model for studying the organs and humans fluids by cybernetic principle. The input variables represent the trace elements which are determined by atomic and nuclear methods of elemental analysis. We have determined the health limits between which the organs might function. (authors)

  5. Studies in China on ingestion and organ content of trace elements of importance in radiological protection

    International Nuclear Information System (INIS)

    Wang Jixian; Zhu Hongda; Chen Rusong

    1998-01-01

    In order to ensure the representative sampling for ingestion study a sampling strategy that took account of all relevant ethnic, socioeconomic and geographic variables was devised by the Institute of Nutrition and Food Hygiene, CAPM for the first total diet study in China. Total diet samples was prepared as 'market basket' samples. Based on the information of food consumption, composition and cookery obtained by the diet consumption survey, the 12 categories of food were collected from nearby markets and cooked by local cookery. For investigation the relationship between elements intake and organ content the specimens for organ content study will be collected from the subjects of sudden death inhabited in the region where the diet samples to be collected for ingestion study. The analytical technique that will be used to determine trace elements of interest in specimens of diet and organs have been proposed, for I that is ENAA, for Cs and Sr that is FAAS or ICP-MS, and for U and Th that is ICP-MS. At last the report summarized the information on trace element content of drinking water supplies in China. (author)

  6. Key Element Performance In Occupational Safety And Health Management System In Organization (A Literature

    Directory of Open Access Journals (Sweden)

    Agus Salim Nuzaihan Aras

    2016-01-01

    Full Text Available Setting an effective safety and health management system is crucial in order to reduce problem relating to accident and ill in management organizational. It is involve with multiple level of management and stakeholders who empower the organization to the management in handling the safety and health cases and issues in organizational. It is necessary to prepare a well knowledge about safety and health management systems and preparing the framework for setting a certain scale in measuring its performance in this area. The successful or failure of management does showing the capability of the organization in delivering the responsible to management levels [1]. The problem in safe work issues and practices cause by the management commitment and involvement that create improper safety program and procedures, and this crisis keep continuing till present [2]. This paper describes about key element of safety and health management system and measuring the performance in order to get an effective management system in organization that describes the process in achieving effectiveness in management. The literature review will be conducted through the data collection from research findings and defined the strong character of key element in which focusing on measuring performance. A guide on key element performance in occupational safety and health management system is specifically drawn to prepare for a future research.

  7. Serological evidence of exposure to globally relevant zoonotic parasites in the Estonian population

    DEFF Research Database (Denmark)

    Lassen, Brian; Janson, Marilin; Viltrop, Arvo

    2016-01-01

    We investigated Estonian population and its selected subgroups for serological evidence of exposure to Ascaris lumbricoides, Echinococcus spp., Taenia solium, Toxocara canis, Toxoplasma gondii, and Trichinella spiralis. Serum samples from 999 adults representing general population, 248 children a...

  8. [Marge Rennit. Eesti muuseumid / Estonian museums] / Tapio Mäkeläinen

    Index Scriptorium Estoniae

    Mäkeläinen, Tapio

    2009-01-01

    Tutvustus: Eesti muuseumid = Estonian museums / [Eesti Muuseumiühing ; koostaja Marge Rennit ; tõlkija Tiina Mällo ; toimetaja Ivi Tammaru ; eessõna: Piret Õunapuu ; kujundaja Marek Allvee]. Tallinn : Oomen, 2008

  9. Problems of contemporary ecology. Temporal changes in Estonian nature and environment

    International Nuclear Information System (INIS)

    Frey, T.

    1997-01-01

    This conference was held 8-9 May 1997 at Tartu, Estonia. The proceedings of the 7. Estonian Conference in Ecology contain the results of mostly original research in environmental science, conservation and natural philosophy

  10. Identification of organically associated trace elements in wood and coal by inductively coupled plasma mass spectrometry.

    Science.gov (United States)

    Richaud, R; Lazaro, M J; Lachas, H; Miller, B B; Herod, A A; Dugwell, D R; Kandiyoti, R

    2000-01-01

    1-Methyl-2-pyrrolidinone (NMP) was used to extract samples of wood (forest residue) and coal; the extracts were analysed by inductively coupled plasma mass spectrometry (ICP-MS) using two different sample preparation methods, in order to identify trace elements associated with the organic part of the samples. A sample of fly ash was similarly extracted and analysed in order to assess the behaviour of the mineral matter contained within the wood and coal samples. 32% of the biomass was extracted at the higher temperature and 12% at room temperature while only 12% of the coal was extracted at the higher temperature and 3% at room temperature. Less than 2% of the ash dissolved at the higher temperature. Size exclusion chromatograms of the extracts indicated the presence of significant amounts of large molecular mass materials (>1000 mu) in the biomass and coal extracts but not in the ash extract. Trace element analyses were carried out using ICP-MS on the acid digests prepared by 'wet ashing' and microwave extraction. Sixteen elements (As, Ba, Be, Cd, Co, Cr, Cu, Ga, Mn, Mo, Ni, Pb, Sb, Se, V and Zn) were quantified, in the samples before extraction, in the extracts and in the residues. Concentrations of trace elements in the original biomass sample were lower than in the coal sample while the concentrations in the ash sample were the highest. The major trace elements in the NMP extracts were Ba, Cu, Mn and Zn from the forest residue; Ba, Cu, Mn, Pb and Zn from the coal; Cu and Zn from the ash. These elements are believed to be associated with the organic extracts from the forest residue and coal, and also from the ash. Be and Sb were not quantified in the extracts because they were present at too low concentrations; up to 40% of Mn was extracted from the biomass sample at 202 degrees C, while Se was totally extracted from the ash sample. For the forest residue, approximately 7% (at room temperature) and 45% (at 202 degrees C) of the total trace elements studied were

  11. Trace element accumulation and trophic relationships in aquatic organisms of the Sundarbans mangrove ecosystem (Bangladesh)

    International Nuclear Information System (INIS)

    Borrell, Asunción; Tornero, Victoria; Bhattacharjee, Dola; Aguilar, Alex

    2016-01-01

    The Sundarbans forest is the largest and one of the most diverse and productive mangrove ecosystems in the world. Located at the northern shoreline of the Bay of Bengal in the Indian Ocean and straddling India and Bangladesh, the mangrove forest is the result of three primary river systems that originate further north and northwest. During recent decades, the Sundarbans have been subject to increasing pollution by trace elements caused by the progressive industrialization and urbanization of the basins of these three rivers. As a consequence, animals and plants dwelling downstream in the mangroves are exposed to these pollutants in varying degrees, and may potentially affect human health when consumed. The aim of the present study was to analyse the concentrations of seven trace elements (Zn, Cu, Cr, Hg, Pb, Cd and As) in 14 different animal and plant species collected in the Sundarbans in Bangladesh to study their transfer through the food web and to determine whether their levels in edible species are acceptable for human consumption. δ"1"5N values were used as a proxy of the trophic level. A decrease in Zn, Cu, Pb and Cd levels was observed with increasing trophic position. Trace element concentrations measured in all organisms were, in general, lower than the concentrations obtained in other field studies conducted in the same region. When examined with respect to accepted international standards, the concentrations observed in fish and crustaceans were generally found to be safe for human consumption. However, the levels of Zn in Scylla serrata and Cr and Cd in Harpadon nehereus exceeded the proposed health advisory levels and may be of concern for human health. - Highlights: • Trace elements were determined in organisms from the Sundarbans mangrove. • The levels found were similar to those determined in wildlife from other mangroves. • Levels in three edible species were close to threshold limits for human consumption. • Except for Cr, As and Hg

  12. Trace element accumulation and trophic relationships in aquatic organisms of the Sundarbans mangrove ecosystem (Bangladesh)

    Energy Technology Data Exchange (ETDEWEB)

    Borrell, Asunción, E-mail: xonborrell@ub.edu [Department of Animal Biology, Institute of Biodiversity (IRBIO), University of Barcelona, Av. Diagonal, 643, Barcelona (Spain); Tornero, Victoria [Department of Animal Biology, Institute of Biodiversity (IRBIO), University of Barcelona, Av. Diagonal, 643, Barcelona (Spain); Bhattacharjee, Dola [Indian Institute of Science Education & Research — Kolkata, Department of Biological Sciences, Mohanpur Campus, Nadia, West Bengal (India); Aguilar, Alex [Department of Animal Biology, Institute of Biodiversity (IRBIO), University of Barcelona, Av. Diagonal, 643, Barcelona (Spain)

    2016-03-01

    The Sundarbans forest is the largest and one of the most diverse and productive mangrove ecosystems in the world. Located at the northern shoreline of the Bay of Bengal in the Indian Ocean and straddling India and Bangladesh, the mangrove forest is the result of three primary river systems that originate further north and northwest. During recent decades, the Sundarbans have been subject to increasing pollution by trace elements caused by the progressive industrialization and urbanization of the basins of these three rivers. As a consequence, animals and plants dwelling downstream in the mangroves are exposed to these pollutants in varying degrees, and may potentially affect human health when consumed. The aim of the present study was to analyse the concentrations of seven trace elements (Zn, Cu, Cr, Hg, Pb, Cd and As) in 14 different animal and plant species collected in the Sundarbans in Bangladesh to study their transfer through the food web and to determine whether their levels in edible species are acceptable for human consumption. δ{sup 15}N values were used as a proxy of the trophic level. A decrease in Zn, Cu, Pb and Cd levels was observed with increasing trophic position. Trace element concentrations measured in all organisms were, in general, lower than the concentrations obtained in other field studies conducted in the same region. When examined with respect to accepted international standards, the concentrations observed in fish and crustaceans were generally found to be safe for human consumption. However, the levels of Zn in Scylla serrata and Cr and Cd in Harpadon nehereus exceeded the proposed health advisory levels and may be of concern for human health. - Highlights: • Trace elements were determined in organisms from the Sundarbans mangrove. • The levels found were similar to those determined in wildlife from other mangroves. • Levels in three edible species were close to threshold limits for human consumption. • Except for Cr, As and Hg

  13. Studies in Japan on ingestion and organ content of trace elements of importance in radiological protection

    International Nuclear Information System (INIS)

    Kawamura, H.; Shiraishi, K.; Yukawa, M.

    1998-01-01

    Data on intake of elements through foods, water and air, and concentration or Content of such elements in body tissues are essential part of the ICRP Reference Man recommended by ICRP for use in setting body composition and also deriving essential parameters for internal dose assessment models particularly for biokinetics or metabolism of radionuclides and their stable elements (1). However, in the RCA region, these data are comparatively scarce and it has been felt necessary to accumulate relevant data of high quality, reflecting the progress in analytical and related methods. In the present CRP (Phase 2), ingestion and organ content of elements of importance in internal dose assessment for the general public, i.e. Sr, Cs, I, Th and U as of the primary priority, are to be studied by performing chemical analysis following collecting representative samples in each participating country under proper quality control and assurance program (2). The data to be accumulated will enrich our knowledge in metabolic characteristics on the national, regional and global basis, after the large amount of data accumulated particularly on the physical characteristics and organ measurements in the first phase of Reference Asian Man CRP. The National Institute of Radiological Sciences (NIRS) of Japan will participate the present phase of CRP following the current concepts on the 'Reference Man'-oriented studies in the RCA region (3). The CRP will supplement the already existing data in Japan and extend them for some elements for which our data are to be further accumulated in ingestion and tissue content in normal and healthy Japanese adult males and females. The NIRS is requested to function as a Central Reference Laboratory (CRL) to promote the CRP in co-operation with the IAEA and the NIST as well as participating laboratories (2)

  14. Bio indicator organisms available to use for determination of radioactive elements in Turkey's seas

    International Nuclear Information System (INIS)

    Kocbas, F.; Guener, H.

    2006-01-01

    In determination of radioactive concentration and monitoring alive and lifeless environmental samples possess a significant place. Thus, intense study is carried out related to natural and artificial radionuclides sediment. Bio indicator living organisms inhabiting in sea ecosystems; are being evaluated in researches such as determinations of environmental pollution, natural and artificial radioactive elements. Turkey's seas are rich related to diversification of various types. In determining and monitoring radioactivity concentration widespread implementation of some sorts appeal attention and on the other hand inadequate usage of many types is observed. In the present study, providing information about the bio indicator organisms keep living in seas and plays important role in food supply chain and increasing the numbers of the types of organisms used are aimed

  15. Outer personal marketing as the element of the holistic orientation of organization

    Directory of Open Access Journals (Sweden)

    Agnieszka Izabela Baruk

    2013-09-01

    Full Text Available In the article the problems related to outer personal marketing as the fundamental element of the holistic marketing orientation were presented. The essence of holistic attitude was shown and its role in the effective marketing activities directed to employees of a scientific organization was underlined. The special attention was paid to the key role of potential empoyees’ knowledge about this approach. On the base of the results of the empirical researches one can state that its level is very low. It is one of the main barriers in the process of outer personal marketing implementing in the case of a scientific organization as well as in the case of others organizations.

  16. Survey of reference materials for trace elements, nuclides and organic microcontaminants

    International Nuclear Information System (INIS)

    Parr, R.M.; Stone, S.F.; Bel-Amakeletch, T.; Zeisler, R.

    1998-01-01

    The International Atomic Energy Agency (IAEA), in co-operation with the United Nations Environment Programme (UNEP), has recently prepared a survey on internationally available analytical reference materials for trace elements, nuclides and organic contaminants in biological, environmental and related matrices. The purpose is to help analysts to select reference materials for quality assurance that match as closely as possible, with respect to matrix type and concentrations of the measurands of interest, the ''real'' samples that are to be measured. The present version of the survey, which is available in the form of two cost-free printed volumes [1], contains over 10,000 certified and information values in 650 reference materials from 27 different producers. The 455 measurands listed include trace elements, major and minor elements, organic contaminants, organometallic compounds, radionuclides and stable isotopes. Currently, the database from which the survey has been produced is being modified and extended so as to make the data available in electronic form via the Internet. (orig.)

  17. Inorganic elements and organic compounds degradation studies by gamma irradiation in used lubricating oils

    International Nuclear Information System (INIS)

    Scapin, Marcos Antonio

    2008-01-01

    The automotive lubricating oils have partial degradation of organic compounds and addition of undesirable inorganic elements, during its use. These substances classify the used lubricating oils as dangerous and highly toxic. According to global consensus, concerning the environmental conservation, the best is to perform a reuse treatment of these lubricating oils. For this purpose, the uses of an alternative and effective technology have been sought. In this work, the efficacy and technical feasibility of the advanced oxidation process (AOP), by gamma radiation, for used automotive lubricating oil treatment has been studied. Different quantities of hydrogen peroxide and water Milli-Q were added to oil samples. They were submitted to the Cobalt-60 irradiator, type Gammacell, with 100, 200 and 500 kGy absorbed doses. The inorganic analysis by X-ray fluorescence (WDXRF) showed inorganic elements removal, mainly to sulphur, calcium, iron and nickel elements at acceptable levels by environmental protection law for oils reusing. The gas chromatography (GC/MS) analysis showed that the advanced oxidation process promotes the organic compounds degradation. The main identified compounds were tridecane, 2-methyl-naphthalene, and trietilamina-tetramethyl urea, which have important industrial applications. The multivariate analysis, Cluster Analysis, showed that advanced oxidation process application is a viable and promising treatment for used lubricating oil reusing. (author)

  18. Organization of spinocerebellar projection map in three types of agranular cerebellum: Purkinje cells vs. granule cells as organizer element

    International Nuclear Information System (INIS)

    Arsenio Nunes, M.L.; Sotelo, C.; Wehrle, R.

    1988-01-01

    The organization of the spinocerebellar projection was analysed by the anterograde axonal WGA-HRP (horseradish peroxidase-wheat germ agglutinin conjugate) tracing method in three different types of agranular cerebellar cortex either induced experimentally by X-irradiation or occurring spontaneously in weaver (wv/wv) and staggerer (sg/sg) mutant mice. The results of this study show that in the X-irradiated rat and weaver mouse, in both of which the granule cells are directly affected and die early in development, the spinal axons reproduce, with few differences, the normal spinocerebellar pattern. Conversely, in staggerer mouse, in which the Purkinje cells are intrinsically affected and granule neurons do not seem to be primarily perturbed by the staggerer gene action, the spinocerebellar organization is severely modified. These findings appear somewhat paradoxical because if granule cells, the synaptic targets of mossy spinocerebellar fibers, were necessary for the organization of spinocerebellar projection, the staggerer cerebellum would exhibit a much more normal projectional map than the weaver and the X-irradiated cerebella. It is, therefore, obvious that granule cells, and even specific synaptogenesis, are not essential for the establishment of the normal spinocerebellar topography. On the other hand, the fact that the Purkinje cells are primarily affected in the unique agranular cortex in which the spinocerebellar organization is severely modified suggests that these neurons could be the main element in the organization of the spinocerebellar projection map. This hypothesis is discussed in correlation with already-reported findings on the zonation of the cerebellar cortex by biochemically different clusters of Purkinje cells

  19. Metallothionein is induced and trace element balance changed in target organs of a common viral infection

    International Nuclear Information System (INIS)

    Ilbaeck, Nils-Gunnar; Glynn, Anders W.; Wikberg, Lotta; Netzel, Elvy; Lindh, Ulf

    2004-01-01

    In experimental studies on the common human coxsackievirus B type 3 (CB3) infection, administered cadmium (Cd) is known to accumulate in the liver and kidneys. CB3 adapted to Balb/c mice was used to study whether infection affects the Cd-binding protein, metallothionein (MT) and if this alters the normal physiological trace element balance in the liver, kidney, spleen and brain. On day 3 of infection, degradation of liver proteins (44%, P<0.01) occurred, whereas in the spleen, protein increased (63%, P<0.05). The infection increased MT five-fold (P<0.01) in liver and kidneys, and in spleen by 34% (P<0.05). A redistribution of Cd and copper (Cu) from the liver to the kidney was associated with this increase in MT, resulting in an increased (P<0.01) kidney/liver ratio for both elements. The infection increased the zinc (Zn) concentration more in the kidney than in the liver, but the kidney/liver ratio was not significantly affected. Results show that MT is increased in several organs during the early phase of infection and is associated with redistribution of both essential and non-essential trace elements. This may be a normal response in common infections that could adversely influence the pathogenesis when the host is concomitantly exposed to potentially toxic trace elements, even at levels in the physiological range

  20. Wet scavenging of organic and elemental carbon during summer monsoon and winter monsoon seasons

    Science.gov (United States)

    Sonwani, S.; Kulshrestha, U. C.

    2017-12-01

    In the era of rapid industrialization and urbanization, atmospheric abundance of carbonaceous aerosols is increasing due to more and more fossil fuel consumption. Increasing levels of carbonaceous content have significant adverse effects on air quality, human health and climate. The present study was carried out at Delhi covering summer monsoon (July -Sept) and winter monsoon (Dec-Jan) seasons as wind and other meteorological factors affect chemical composition of precipitation in different manner. During the study, the rainwater and PM10 aerosols were collected in order to understand the scavenging process of elemental and organic carbon. The Rain water samples were collected on event basis. PM10 samples were collected before rain (PR), during rain (DR) and after rain (AR) during 2016-2017. The collected samples were analysed by the thermal-optical reflectance method using IMPROVE-A protocol. In PM10, the levels of organic carbon (OC) and its fractions (OC1, OC2, OC3 and OC4) were found significantly lower in the AR samples as compared to PR and DR samples. A significant positive correlation was noticed between scavenging ratios of organic carbon and rain intensity indicating an efficient wet removal of OC. In contrast to OCs, the levels of elemental carbon and its fractions (EC1, EC2, and EC3) in AR were not distinct during PR and DR. The elemental carbon showed very week correlation with rain intensity in Delhi region which could be explained on the basis of hydrophobic nature of freshly emitted carbon soot. The detailed results will be discussed during the conference.

  1. Studies on determination of stable elements in sea water and organisms

    International Nuclear Information System (INIS)

    Anon.

    1974-01-01

    The existing conditions of stable elements including Co, Zn, Cs, Ce and Eu in sea water were determined by adding radioactive tracers, and determination methods were discussed. 60 Co added to sea water revealed to be kept in solution in 93 per cent of non-filtrated sea water, and in 98 per cent of filtrated sea water. 65 Zn also added to sea water showed to be kept in solution in 97 per cent of both non-filtrated and filtrated sea water. Both elements seemed to exist as particle or ion smaller than 0.45 μ, which solved in sea water. On the other hand, in both Ce and Eu of rare earth elements, about 80 per cent of them presented in the residue, but the treatment of sea water by hydrochroric acid solubilized 80 to 90 per cent of them in filtrated sea water. One of the instrumental analysis, irradiation analysis by nuclear reactor, was applied: each of preconcentration procedure by ion exchange method for Co and Zn in sea water and drying up sample marine organisms to ash content combined with irradiation analysis. Chemical recovery of both 60 Co and 65 Zn in sea water by preconcentration procedure reached more than 95 per cent. As to marine organisms, Co, Zn, and Cs could be determined with only 100 to 200 mg. of ash content obtained from sample marine organisms showing 80 per cent of chemical yield of the carrier through whole the procedure of analysis in almost all the samples. The chemical recovery of Ce and Eu in sea water and marine organisms by the preconcentration procedure reached about 85 per cent, and chemical yield through whole the procedure of analysis was more than 60 per cent. Concentration factor of Co and Zn in fishes and shells, especially that of muscles, obtained by stable elements determination method was almost 10 times that by RI tracer method. The difference of chemical forms between RI tracer and stable isotope affected not only to physiological metabolism but also to food chains. (Kanao, K.)

  2. Sorption characteristics of honeycomb type sorption element composed of organic sorbent; Yukikei shuchakuzai wo tofushita honeycomb jo shuchaku element nio shuchaku tokuse

    Energy Technology Data Exchange (ETDEWEB)

    Inaba, H.; Horibe, A. [Okayama University, Okayama (Japan); Kida, T.; Kaneda, M. [Japan Exlan Co. Ltd., Osaka (Japan)

    2000-12-25

    This paper has dealt with the sorption characteristics of honeycomb shape type sorbent element composed of new organic sorbent which was composed of the bridged complex of sodium polyacrylate. The transient experiments in which the moist air was passed into the honeycomb type sorbent element were conducted under various conditions of air velocity, temperature, relative-humidity and honeycomb length. As a result, the effective mass transfer coefficient of the organic sorbent sorbing the water-vapor was non-dimensionalized as a function of Reynolds number, modified Stefan number and non-dimensional honeycomb length. (author)

  3. The Dominance of Indirect Taxes in Estonian State Budget

    Directory of Open Access Journals (Sweden)

    Olev Raju

    2013-01-01

    Full Text Available Recession has sharply erected the question of tax burden and the optimal proportion of different kinds of taxes among the incomes of the budget. Indirect taxes and consumption taxes, which proportion is different according to different methodologies, dominate in Estonian state budget. The buoyancy of a tax system based on taxes of that kind is especially weak during the recession. Difficulties concerning the incomes of budget have arisen the necessity for lifting taxes, which is possible as the tax burden is low now. But a sharp question of the optimal level of taxes is going to be raised. A formula for indirect tax optimum according to Ramsey taxes and Slutski decomposition has been proposed in the article.

  4. Online tutoring procedure for research project supervision: management, organization and key elements

    Directory of Open Access Journals (Sweden)

    Antònia Darder Mesquida

    2015-07-01

    Full Text Available Research project tutoring appears as a crucial element for teaching; it is a planned action based on the relationship between a tutor and a student. This paper presents the findings of a design and development research which has as its main aim to create an organization system for the tutoring of online research projects. That system seeks to facilitate the tutoring and supervision task with trainee researchers, providing guidance for its management and instruments for its implementation. The main conclusions arising from this research derive from considering the need to offer a solution to the problem of distance research project supervision and has materialized in organization and sequencing through a model about the variables that influence the research project tutoring problem.

  5. Elemental analysis of chamber organic aerosol using an aerodyne high-resolution aerosol mass spectrometer

    Directory of Open Access Journals (Sweden)

    P. S. Chhabra

    2010-05-01

    Full Text Available The elemental composition of laboratory chamber secondary organic aerosol (SOA from glyoxal uptake, α-pinene ozonolysis, isoprene photooxidation, single-ring aromatic photooxidation, and naphthalene photooxidation is evaluated using Aerodyne high-resolution time-of-flight mass spectrometer data. SOA O/C ratios range from 1.13 for glyoxal uptake experiments to 0.30–0.43 for α-pinene ozonolysis. The elemental composition of α-pinene and naphthalene SOA is also confirmed by offline mass spectrometry. The fraction of organic signal at m/z 44 is generally a good measure of SOA oxygenation for α-pinene/O3, isoprene/high-NOx, and naphthalene SOA systems. The agreement between measured and estimated O/C ratios tends to get closer as the fraction of organic signal at m/z 44 increases. This is in contrast to the glyoxal uptake system, in which m/z 44 substantially underpredicts O/C. Although chamber SOA has generally been considered less oxygenated than ambient SOA, single-ring aromatic- and naphthalene-derived SOA can reach O/C ratios upward of 0.7, well within the range of ambient PMF component OOA, though still not as high as some ambient measurements. The spectra of aromatic and isoprene-high-NOx SOA resemble that of OOA, but the spectrum of glyoxal uptake does not resemble that of any ambient organic aerosol PMF component.

  6. Estonian soil classification as a tool for recording information on soil cover and its matching with local site types, plant covers and humus forms classifications

    Science.gov (United States)

    Kõlli, Raimo; Tõnutare, Tõnu; Rannik, Kaire; Krebstein, Kadri

    2015-04-01

    Estonian soil classification (ESC) has been used successfully during more than half of century in soil survey, teaching of soil science, generalization of soil databases, arrangement of soils sustainable management and others. The Estonian normally developed (postlithogenic) mineral soils (form 72.4% from total area) are characterized by mean of genetic-functional schema, where the pedo-ecological position of soils (ie. location among other soils) is given by means of three scalars: (i) 8 stage lithic-genetic scalar (from rendzina to podzols) separates soils each from other by parent material, lithic properties, calcareousness, character of soil processes and others, (ii) 6 stage moisture and aeration conditions scalar (from aridic or well aerated to permanently wet or reductic conditions), and (iii) 2-3 stage soil development scalar, which characterizes the intensity of soil forming processes (accumulation of humus, podzolization). The organic soils pedo-ecological schema, which links with histic postlithogenic soils, is elaborated for characterizing of peatlands superficial mantle (form 23.7% from whole soil cover). The position each peat soil species among others on this organic (peat) soil matrix schema is determined by mean of 3 scalars: (i) peat thickness, (ii) type of paludification or peat forming peculiarities, and (iii) stage of peat decomposition or peat type. On the matrix of abnormally developed (synlithogenic) soils (all together 3.9%) the soil species are positioned (i) by proceeding in actual time geological processes as erosion, fluvial processes (at vicinity of rivers, lakes or sea) or transforming by anthropogenic and technological processes, and (ii) by 7 stage moisture conditions (from aridic to subaqual) of soils. The most important functions of soil cover are: (i) being a suitable environment for plant productivity; (ii) forming adequate conditions for decomposition, transformation and conversion of falling litter (characterized by humus

  7. Study in Malaysia on ingestion and organ content of trace elements of importance in radiological protection

    International Nuclear Information System (INIS)

    Zawiah, H.; Khalik Haji Wood, A.; Shahrom, A.W.; Halim Mansar, A.

    1998-01-01

    Involvement in the Reference Asian man project, Phase 2 began at the project, formulation meeting in Hitachinaka City, Japan in February 1995. The objective of the project is to look into the ingestion and organ content of trace elements of importance in radiological protection. The data on ingestion of radionuclides from diet and deposition in tissues are important for estimating internal dose for radiation protection. The meeting agreed the elements of primary interest are caesium, iodine, strontium, thorium and uranium in samples of representative diets and autopsy specimens of liver, muscle, thyroid, bone, and kidney. This report will highlight the methodology for implementation of the project including defining the study groups, sampling duplicate diet and autopsy specimens and the analytical techniques involved. Emphasis will be given to nuclear-related analytical technique (NAA) together with a complementary technique (AAS) available in our institution. Some data on trace element contents of local marine and fresh water fishes and milk was reported. Included also a brief discussion on drinking water quality in Malaysia and some information on related studies available. The information on drinking water will be very useful to the present study since water is part of daily diet. (author)

  8. Investigation of the remaining major and trace elements in clean coal generated by organic solvent extraction

    Energy Technology Data Exchange (ETDEWEB)

    Jie Wang; Chunqi Li; Kinya Sakanishi; Tetsuya Nakazato; Hiroaki Tao; Toshimasa Takanohashi; Takayuki Takarada; Ikuo Saito [National Institute Advanced Industrial Science and Technology (AIST), Ibaraki (Japan). Energy Technology Research Institute

    2005-09-01

    A sub-bituminous Wyodak coal (WD coal) and a bituminous Illinois No. 6 coal (IL coal) were thermally extracted with 1-methylnaphthalene (1-MN) and N-methyl-2-pyrrolidone (NMP) to produce clean extract. A mild pretreatment with acetic acid was also carried out. Major and trace inorganic elements in the raw coals and resultant extracts were determined by means of inductively coupled plasma optical emission spectrometry (ICP-OES), flow injection inductively coupled plasma mass spectrometry (FI-ICP-MS), and cold vapor atomic absorption spectrometry (CV-AAS). It was found that the extraction with 1-MN resulted in 73-100% reductions in the concentration of Li, Be, V, Ga, As, Se, Sr, Cd, Ba, Hg, and Pb. The extraction with NMP yielded more extract than that with 1-MN, but it retained more organically associated major and trace metals in the extracts. In the extraction of WD coal with NMP, the acid pretreatment not only significantly enhanced the extraction yield but also significantly reduced the concentrations of alkaline earth elements such as Be, Ca, Mg, Sr, and Ba in the extract. In addition, the modes of occurrence of trace elements in the coals were discussed according to their extraction behaviors. 30 refs., 2 figs., 5 tabs.

  9. Ambient concentrations and insights on organic and elemental carbon dynamics in São Paulo, Brazil

    Science.gov (United States)

    Monteiro dos Santos, Djacinto A.; Brito, Joel F.; Godoy, José Marcus; Artaxo, Paulo

    2016-11-01

    The São Paulo Metropolitan Area (SPMA) is a megacity with about 20 million people and about 8 million vehicles, most of which are fueled with a significant fraction of ethanol - making it a unique case worldwide. This study presents organic and elemental carbon measurements using thermal-optical analysis from quartz filters collected in four sampling sites within the SPMA. Overall Organic Carbon (OC) concentration was comparable at all sites, where Street Canyon had the highest concentration (3.37 μg m-3) and Park site the lowest (2.65 μg m-3). Elemental Carbon (EC), emitted as result of incomplete combustion, has been significantly higher at the Street Canyon site (6.11 μg m-3) in contrast to all other three sites, ranging from 2.25 μg m-3 (Downtown) to 1.50 μg m-3 (Park). For all sampling sites, the average OC:EC ratio are found on the lower bound (pollution dynamics in a megacity impacted by a unique vehicular fleet. It also shows the need of implementation of EURO VI technology and to improve mass transport systems such a metro and more bus corridors to allow better transport for 19 million people in the SPMA.

  10. Frost related dieback in Estonian energy plantations of willows in relation to fertilisation and pathogenic bacteria

    Energy Technology Data Exchange (ETDEWEB)

    Cambours, M.A.; Nejad, P. [Department of Forest Mycology and Pathology, Swedish University of Agricultural Sciences, Box 7026, 750 07 Uppsala (Sweden); Heinsoo, K. [Institute of Zoology and Botany, Estonian Agricultural University, Riia 181, 51014 Tartu (Estonia); Granhall, U. [Department of Microbiology, Swedish University of Agricultural Sciences, Box 7025, 750 07 Uppsala (Sweden)

    2006-03-15

    Two 9-year old Estonian Salix plantations suffering from dieback were studied: one situated on poor mineral soil and divided into fertilised and unfertilised plots (Saare plantation) and another growing on a well-decomposed and nitrogen-rich organic soil, without fertiliser application (Kambja plantation). Bacteria from internal tissues of visually damaged shoots from seven clones were isolated in spring and autumn. The strains were subsequently biochemically characterised and tested for ice nucleation activity and pathogenicity on Salix. Some strains were also analysed with 16S rRNA. High numbers of culturable bacteria were found, belonging mainly to Erwinia, Sphingomonas, Pseudomonas and Xanthomonas spp. Fertilised plots were significantly more colonised by bacteria than unfertilised plots and also more extensively damaged, showing a lower density of living plants after 7 years of culture. More ice nucleation active (INA) strains were found in Saare fertilised plots and at Kambja than in Saare unfertilised plots. Likewise, most pathogenic strains were isolated from Saare fertilised plots and from Kambja. For some of the willow clones studied, dieback appeared to be related to both clonal frost sensitivity and abundance of INA and pathogenic bacteria. The plantations probably suffered from the presence of high amounts of pathogens and from frost related injuries aggravated by INA bacteria. Most probably the fertilisation at Saare and the nitrogen-rich soil at Kambja created a favourable environment for bacterial development and led to high dieback levels after the first harvest. (author)

  11. Jäätmetega kimpus Estonian Cell annab muda põldudele kompostiks / Ulvar Käärt

    Index Scriptorium Estoniae

    Käärt, Ulvar, 1982-

    2007-01-01

    Kundas asuv Estonian Celli tehas jagab ümberkaudsetele talunikele jäätmetest lahtisaamiseks kompostimissegu. Seadused ei sätesta, kuidas Estonian Cellis tekkivaid jäätmeid töödelda. Kommenteerib Peeter Eek: Aasta läbi ei saa muda põllule viia

  12. Musical Practices and Methods in Music Lessons: A Comparative Study of Estonian and Finnish General Music Education

    Science.gov (United States)

    Sepp, Anu; Ruokonen, Inkeri; Ruismäki, Heikki

    2015-01-01

    This article reveals the results of a comparative study of Estonian and Finnish general music education. The aim was to find out what music teaching practices and approaches/methods were mostly used, what music education perspectives supported those practices. The data were collected using questionnaires and the results of 107 Estonian and 50…

  13. Evaluation of a two-step thermal method for separating organic and elemental carbon for radiocarbon analysis

    NARCIS (Netherlands)

    Dusek, U.; Monaco, M.; Prokopiou, M.; Gongriep, F.; Hitzenberger, R.; Meijer, H. A. J.; Rockmann, T.

    2014-01-01

    We thoroughly characterized a system for thermal separation of organic carbon (OC) and elemental carbon (EC) for subsequent radiocarbon analysis. Different organic compounds as well as ambient aerosol filter samples were introduced into an oven system and combusted to CO2 in pure O-2. The main

  14. Surface-type nonvolatile electric memory elements based on organic-on-organic CuPc-H2Pc heterojunction

    International Nuclear Information System (INIS)

    Karimov, Khasan S.; Muqeet Rehman, M.; Zameer Abbas, S.; Ahmad, Zubair; Touati, Farid; Mahroof-Tahir, M.

    2015-01-01

    A novel surface-type nonvolatile electric memory elements based on organic semiconductors CuPc and H 2 Pc are fabricated by vacuum deposition of the CuPc and H 2 Pc films on preliminary deposited metallic (Ag and Cu) electrodes. The gap between Ag and Cu electrodes is 30–40 μm. For the current–voltage (I–V) characteristics the memory effect, switching effect, and negative differential resistance regions are observed. The switching mechanism is attributed to the electric-field-induced charge transfer. As a result the device switches from a low to a high-conductivity state and then back to a low conductivity state if the opposite polarity voltage is applied. The ratio of resistance at the high resistance state to that at the low resistance state is equal to 120–150. Under the switching condition, the electric current increases ∼ 80–100 times. A comparison between the forward and reverse I–V characteristics shows the presence of rectifying behavior. (paper)

  15. Selected elements and organic chemicals in streambed sediment in the Salem area, Oregon, 1999

    Science.gov (United States)

    Tanner, Dwight Q.

    2002-09-13

    Analysis of streambed sediments in the Salem, Oregon, area showed anomalously large concentrations of some elements and organic chemicals, indicating contamination from anthropogenic and/or geologic sources. The streambed sediment sample from Clark Creek, an urban basin, had large concentrations of polycyclic aromatic hyrdocarbons (PAHs), organochlorines, cadmium, lead, and zinc. The sample from the East Fork of Pringle Creek, which is a mostly urban basin, had the highest concentrations of DDD, DDE, and DDT compounds. Aldrin was detected in streambed sediment at only one site, the East Fork of Pringle Creek. Ten of the 14 sites sampled had exceedances of the sediment quality guidelines of the Canadian Council of Ministers of the Environment (CCME), and 8 sites had exceedances of guidelines from the Puget Sound Dredged Disposal Analysis (PSDDA) Program.

  16. Composition and leaching of construction and demolition waste: Inorganic elements and organic compounds

    DEFF Research Database (Denmark)

    Butera, Stefania; Christensen, Thomas Højlund; Astrup, Thomas Fruergaard

    2014-01-01

    Thirty-three samples of construction and demolition waste collected at 11 recycling facilities in Denmark were characterised in terms of total content and leaching of inorganic elements and presence of the persistent organic pollutants PCBs and PAHs. Samples included (i) "clean" (i.e. unmixed...... for leaching, was observed indicating that the number of analysed samples may be critical in relation to decisions regarding management and utilisation of the materials. Higher leaching of chromium, sulphate and chloride were observed for masonry-containing and partly carbonated samples, indicating that source...... segregation and management practices may be important. Generally, leaching was in compliance with available leaching limits, except for selenium, and in some cases chromium, sulphate and antimony. © 2014 Elsevier B.V....

  17. Elemental, stable isotopic and biochemical characterization of soil organic matter alteration across a natural peatland gradient

    Science.gov (United States)

    Cowie, G.; Mowbray, S.; Belyea, L.; Laing, C.; Allton, K.; Abbott, G.; Muhammad, A.

    2010-12-01

    Northern peatlands store around one third of global soil C and thus represent a key reservoir. To elucidate how these systems might respond to climate change, field- and laboratory-based experimental incubation studies are being conducted at sites across a natural peatland gradient in the boreonemoral zone of central Sweden (Ryggmossen). The site comprises four successional stages, from edge to centre; Swamp Forest (SF), Lagg Fen (LF), Bog Margin (BM) and Bog Plateau (BP). The well-preserved succession shows strong decreases in mineral cations and pH, and distinct changes in vegetation and water-table depth. As an underpinning to these experiments, comprehensive characterization of natural soil organic matter (SOM) alteration has been carried out through detailed analyses of vegetation and downcore profiles at contrasting topographic sites (hummock vs hollow) in each of the four locations. As illustrated in Figure 1, while some similarities occur in downcore trends, contrasts are observed in C and N elemental and stable isotopic compositions, between stages and, in some cases, between microtopographic settings. Downcore trends and intersite differences are also observed in biochemical yields and molecular composition (carbohydrates, amino acids, phenols, lipids and D/L amino acid ratios). These reflect SOM decay and alteration combined with the effects of contrasting hydrologic, redox and nutrient regimes and differing vegetation and microbial inputs at each of the study sites. Multivariate analysis is used to to elucidate compositional patterns that characterize and delineate progressive SOM decay, specific vegetation types, and the effects of contrasting environmental conditions at the different sites. Figure 1. A. Organic carbon content (wt %), B. Atomic ratio of organic C to total N, C. Stable C isotopic composition of organic C (d13Corg), and D. Stable N isotopic composition of total nitrogen (d15N), all for core profiles from contrasting settings (hummock and

  18. Radon in Estonian dwellings - Results from a National Radon Survey

    Energy Technology Data Exchange (ETDEWEB)

    Pahapill, Lia; Rulkov, Anne; Rajamaee, Raivo [Estonian Radiation Protection Centre (Kiirguskeskus), Tallinn (Spain); Aakerblom, Gustav [Swedish Radiation Protection Authority, Stockholm (Sweden)

    2003-10-01

    A countrywide survey of radon concentrations in Estonian dwellings was carried out during the period 1998-2001. The survey formed a part of the cooperation program on radiation protection between the Estonian Radiation Protection (Kiirguskeskus) Centre and the Swedish Radiation Protection Authority (SSI). The survey included measurements in a number of dwellings representative for Estonia in detached houses and multifamily buildings (only dwellings on the bottom floor were included in the survey). Altogether, radon concentrations were measured in 515 dwellings, a number large enough to be statistically significant. All measurements were made with alphatrack film detectors of the same type that SSI uses in Sweden. The measurements were made during a 2-3 month period during the winter half-year. Two detectors were used in each dwelling. In Estonia there are 0.17 million dwellings in detached houses and 0.45 million in multi apartment buildings. Of the 1.26 million inhabitants in Estonia. 0.36 million live in detached houses and 0.90 million in multi apartment buildings. Most of the latter were built during the Soviet occupation. Of the dwellings in multifamily buildings 30 % are assumed to be situated on the first floor. The mean radon concentration in dwellings in detached hoses, according to the survey results, is 103 Bq/m{sup 3}, in dwellings on the bottom floor in multi apartment buildings it is 78 Bq/m{sup 3}. In 1% of the dwellings the radon concentration exceeded 400 Bq/m{sup 3}. The highest radon concentration found in the study was 1040 Bq/m{sup 3}. Based on the assumption that the average radon concentration in the dwellings in multi-apartment buildings that are not situated on the bottom floor is 30 Bq/m{sup 3}, and that these dwellings constitute 70% of all dwellings in multi apartment buildings, the mean radon concentration in dwellings in multi apartment buildings is calculated to be 44 Bq/m{sup 3}. The mean value for all Estonia dwellings is calculated

  19. Radon in Estonian dwellings - Results from a National Radon Survey

    International Nuclear Information System (INIS)

    Pahapill, Lia; Rulkov, Anne; Rajamaee, Raivo; Aakerblom, Gustav

    2003-10-01

    A countrywide survey of radon concentrations in Estonian dwellings was carried out during the period 1998-2001. The survey formed a part of the cooperation program on radiation protection between the Estonian Radiation Protection (Kiirguskeskus) Centre and the Swedish Radiation Protection Authority (SSI). The survey included measurements in a number of dwellings representative for Estonia in detached houses and multifamily buildings (only dwellings on the bottom floor were included in the survey). Altogether, radon concentrations were measured in 515 dwellings, a number large enough to be statistically significant. All measurements were made with alphatrack film detectors of the same type that SSI uses in Sweden. The measurements were made during a 2-3 month period during the winter half-year. Two detectors were used in each dwelling. In Estonia there are 0.17 million dwellings in detached houses and 0.45 million in multi apartment buildings. Of the 1.26 million inhabitants in Estonia. 0.36 million live in detached houses and 0.90 million in multi apartment buildings. Most of the latter were built during the Soviet occupation. Of the dwellings in multifamily buildings 30 % are assumed to be situated on the first floor. The mean radon concentration in dwellings in detached hoses, according to the survey results, is 103 Bq/m 3 , in dwellings on the bottom floor in multi apartment buildings it is 78 Bq/m 3 . In 1% of the dwellings the radon concentration exceeded 400 Bq/m 3 . The highest radon concentration found in the study was 1040 Bq/m 3 . Based on the assumption that the average radon concentration in the dwellings in multi-apartment buildings that are not situated on the bottom floor is 30 Bq/m 3 , and that these dwellings constitute 70% of all dwellings in multi apartment buildings, the mean radon concentration in dwellings in multi apartment buildings is calculated to be 44 Bq/m 3 . The mean value for all Estonia dwellings is calculated to be 60 Bq/m 3 . Using

  20. Biological and environmental reference materials for trace elements, nuclides and organic microcontaminants

    International Nuclear Information System (INIS)

    Cortes Toro, E.; Parr, R.M.; Clements, S.A.

    1990-01-01

    This report has been produced from a database on analytical reference materials of biological and environmental origin, which is maintained at the International Atomic Energy Agency. It is an updated version of an earlier report, published in 1985, which focussed mainly on reference materials for trace elements. In the present version of the report, reference materials for trace elements still constitute the major part of the data; however, information is also now included on a number of other selected analytes of relevance to IAEA programmes, i.e. radionuclides, stable isotopes and organic microcontaminants. The database presently contains 2,694 analyte values for 117 analytes in 116 biological and 77 environmental (non-biological) reference materials produced by 20 different suppliers. Additional information on the cost of the material, the unit size supplied, (weight or volume), and the minimum weight of material recommended for analysis is also provided (if available to the authors). It is expected that this report will help analysts to select the reference material that matches as closely as possible, with respect to matrix type and concentrations of the analytes of interest, the ''real'' samples that are to be analysed. Refs, 12 tabs

  1. Composition and leaching of construction and demolition waste: inorganic elements and organic compounds.

    Science.gov (United States)

    Butera, Stefania; Christensen, Thomas H; Astrup, Thomas F

    2014-07-15

    Thirty-three samples of construction and demolition waste collected at 11 recycling facilities in Denmark were characterised in terms of total content and leaching of inorganic elements and presence of the persistent organic pollutants PCBs and PAHs. Samples included (i) "clean" (i.e. unmixed) concrete waste, (ii) mixed masonry and concrete, (iii) asphalt and (iv) freshly cast concrete cores; both old and newly generated construction and demolition waste was included. PCBs and PAHs were detected in all samples, generally in non-critical concentrations. Overall, PAHs were comparable to background levels in urban environments. "Old" and "new" concrete samples indicated different PCB congener profiles and the presence of PCB even in new concrete suggested that background levels in raw materials may be an issue. Significant variability in total content of trace elements, even more pronounced for leaching, was observed indicating that the number of analysed samples may be critical in relation to decisions regarding management and utilisation of the materials. Higher leaching of chromium, sulphate and chloride were observed for masonry-containing and partly carbonated samples, indicating that source segregation and management practices may be important. Generally, leaching was in compliance with available leaching limits, except for selenium, and in some cases chromium, sulphate and antimony. Copyright © 2014 Elsevier B.V. All rights reserved.

  2. Effect of kombucha on some trace element levels in different organs of electromagnetic field exposed rats

    Directory of Open Access Journals (Sweden)

    Ola A. Gharib

    2014-01-01

    Full Text Available Mobile phones have increased exponentially all over the world. The present study was performed to evaluate the effect of kombucha (KT on some trace element levels of brain, spleen and intestine in male albino rats exposed to a 950 MHz electromagnetic field (EMF. Four experimental groups labelled as controls, EMF group, KT group and KT + EMF group were formed with six randomly chosen animals in each group. After EMF exposure for eight weeks and the animals were sacrificed by decapitation. Brain, spleen and intestine samples were collected for trace element analysis. The group of animals subjected to electromagnetic waves caused significant increases in iron copper levels and copper/zinc ratio accompanied with a decrease of zinc level in all studied organs. Combined treatment of kombucha with EMF resulted in a successful attenuation of these adverse effects of EMF. From present findings we can state that kombucha as a supplement has an ameliorative signs against the effects of electromagnetic radiation.

  3. Selected organic compounds and trace elements in streambed sediments and fish tissues, Cook Inlet Basin, Alaska

    Science.gov (United States)

    Frenzel, Steven A.

    2000-01-01

    Organochlorines, semivolatile organic compounds (SVOCs), and trace elements were investigated in streambed sediments and fish tissues at selected sites in the Cook Inlet Basin, Alaska, during 1998. At most sites, SVOCs and organochlorine compounds were either not detected or detected at very low concentrations. Chester Creek at Arctic Boulevard at Anchorage, which was the only site sampled with a significant degree of development in the watershed, had elevated levels of many SVOCs in streambed sediment. Coring of sediments from two ponds on Chester Creek confirmed the presence of elevated concentrations of a variety of organic compounds. Moose Creek, a stream with extensive coal deposits in its watershed, had low concentrations of numerous SVOCs in streambed sediment. Three sites located in national parks or in a national wildlife refuge had no detectable concentrations of SVOCs. Trace elements were analyzed in both streambed sediments and tissues of slimy sculpin. The two media provided similar evidence for elevated concentrations of cadmium, lead, and zinc at Chester Creek. In this study, 'probable effect levels '(PELs) were determined from sediments finer than 0.063 millimeters, where concentrations tend to be greatest. Arsenic and chromium concentrations exceeded the PEL at eight and six sites respectively. Zinc exceeded the PEL at one site. Cadmium and copper concentrations were smaller than the PEL at all sites. Mercury concentrations in streambed sediments from the Deshka River were near the PEL, and selenium concentrations at that site also appear to be elevated above background levels. At half the sites where slimy sculpin were sampled, selenium concentrations were at levels that may cause adverse effects in some species.

  4. Kolm Eesti Robinsoni: Daniel Defoe romaan eesti tõlkes / Three Estonian Robinsons: Daniel Defoe’s Novel in Estonian Translation

    Directory of Open Access Journals (Sweden)

    Ene-Reet Soovik

    2012-06-01

    acceptable during the Soviet times to curb the source text in translation while still claiming that it held the status of a representative translation; in 1950 the existence of omissions could even be frankly mentioned in the translator’s foreword. The content of the omissions correlated with topics disapproved of by the authorities of the time. The translation hailing from 1984 was, in comparison, less cautious and found it possible to include numerous elements missing from the earlier translation. The 2007 translation, however, appeared in an Estonia that had regained independence in 1991; thus, the novel’s text was published to the full. The two earlier translations were published as children’s literature at times when an acute need was felt in the society for such works. Children’s literature has also been considered more likely to be adapted to meet the needs of the target culture than works meant for adults. The 2007 translation seems to want to also engage a mature readership and follows the principles of a literary work’s integrity set out in the Berne Convention. Robinson himself as the main character has appeared to the Estonian reader in various guises: as an embodiment of quasi-Soviet labour valour, an incarnation of practical rationality of the Age of Reason, and finally as a person who also makes progress towards spiritual enlightenment. Thus, he can also be seen as an illustration of the major social change s that occurred in Estonia during the mid- and late 20th century.

  5. Organic, elemental and inorganic carbon in particulate matter of six urban environments in Europe

    Directory of Open Access Journals (Sweden)

    M. Sillanpää

    2005-01-01

    Full Text Available A series of 7-week sampling campaigns were conducted in urban background sites of six European cities as follows: Duisburg (autumn, Prague (winter, Amsterdam (winter, Helsinki (spring, Barcelona (spring and Athens (summer. The campaigns were scheduled to include seasons of local public health concern due to high particulate concentrations or findings in previously conducted epidemiological studies. Aerosol samples were collected in parallel with two identical virtual impactors that divide air particles into fine (PM2.5 and coarse (PM2.5-10 size ranges. From the collected filter samples, elemental (EC and organic (OC carbon contents were analysed with a thermal-optical carbon analyser (TOA; total Ca, Ti, Fe, Si, Al and K by energy dispersive X-ray fluorescence (ED-XRF; As, Cu, Ni, V, and Zn by inductively coupled plasma mass spectrometry (ICP/MS; Ca2+, succinate, malonate and oxalate by ion chromatography (IC; and the sum of levoglucosan+galactosan+mannosan (∑MA by liquid chromatography mass spectrometry (LC/MS. The campaign means of PM2.5 and PM2.5-10 were 8.3-29.6 µg m-3 and 5.4-28.7 µg m-3, respectively. The contribution of particulate organic matter (POM to PM2.5 ranged from 21% in Barcelona to 54% in Prague, while that to PM2.5-10 ranged from 10% in Barcelona to 27% in Prague. The contribution of EC was higher to PM2.5 (5-9% than to PM2.5-10 (1-6% in all the six campaigns. Carbonate (C(CO3, that interferes with the TOA analysis, was detected in PM2.5-10 of Athens and Barcelona but not elsewhere. It was subtracted from the OC by a simple integration method that was validated. The CaCO3 accounted for 55% and 11% of PM2.5-10 in Athens and Barcelona, respectively. It was anticipated that combustion emissions from vehicle engines affected the POM content in PM2.5 of all the six sampling campaigns, but a comparison of mass concentration ratios of the selected inorganic and organic tracers of common sources of organic material to POM suggested

  6. Retranslocation and localization of nutrient elements in various organs of moso bamboo (Phyllostachys pubescens)

    Energy Technology Data Exchange (ETDEWEB)

    Umemura, Mitsutoshi, E-mail: mitsutoshi.ume@gmail.com; Takenaka, Chisato, E-mail: chisato@agr.nagoya-u.ac.jp

    2014-09-15

    Moso bamboo (Phyllostachys pubescens) is one of the major giant bamboo species growing in Japan, and the invasion of mismanaged bamboo populations into contiguous forests has been a serious problem. To understand expansion mechanisms of the bamboo, it is important to obtain some first insights into the plant's rapid growth from the viewpoints of the nutrient dynamics in bamboo organs. We have investigated seasonal changes in the concentrations of several nutrient elements in leaves of the plants from three P. pubescens forests and the distributions of those elements in both mature (culms, branches, leaves, roots, and rhizomes) and growing organs (shoots and rhizomes). Among all elements analyzed, boron (B) concentrations in leaves showed a specific seasonal variation that was synchronous across all study sites. Boron was detected at high concentrations in the younger parts of growing rhizomes and shoots, and in mature leaves. These results indicate that P. pubescens could actively utilize B for vegetative reproduction by the retranslocation and the local accumulation behaving as mobile B. Silicon (Si) was found in high concentrations in surface parts of culms and in the mature sheaths of growing rhizomes and shoots following those in mature leaves. P. pubescens, a plant known to accumulate Si, accumulated only low levels of Ca and B in the leaves, indicating that it is possible to utilize more Si for cell wall enhancement than Ca or B. In both mature culms and rhizomes, zinc (Zn) was found at much higher concentrations in the nodes with meristematic tissue than those in internodes, indicating that Zn might play a role in promoting culm and rhizome elongation. We suggest that specific and local utilization of B, Si, and Zn in P. pubescens might support the vegetative reproduction and rapid growth. - Highlights: • The bamboo efficiently utilizes boron by the retranslocation and local accumulation. • Zinc found in nodes at high concentrations may support

  7. Retranslocation and localization of nutrient elements in various organs of moso bamboo (Phyllostachys pubescens)

    International Nuclear Information System (INIS)

    Umemura, Mitsutoshi; Takenaka, Chisato

    2014-01-01

    Moso bamboo (Phyllostachys pubescens) is one of the major giant bamboo species growing in Japan, and the invasion of mismanaged bamboo populations into contiguous forests has been a serious problem. To understand expansion mechanisms of the bamboo, it is important to obtain some first insights into the plant's rapid growth from the viewpoints of the nutrient dynamics in bamboo organs. We have investigated seasonal changes in the concentrations of several nutrient elements in leaves of the plants from three P. pubescens forests and the distributions of those elements in both mature (culms, branches, leaves, roots, and rhizomes) and growing organs (shoots and rhizomes). Among all elements analyzed, boron (B) concentrations in leaves showed a specific seasonal variation that was synchronous across all study sites. Boron was detected at high concentrations in the younger parts of growing rhizomes and shoots, and in mature leaves. These results indicate that P. pubescens could actively utilize B for vegetative reproduction by the retranslocation and the local accumulation behaving as mobile B. Silicon (Si) was found in high concentrations in surface parts of culms and in the mature sheaths of growing rhizomes and shoots following those in mature leaves. P. pubescens, a plant known to accumulate Si, accumulated only low levels of Ca and B in the leaves, indicating that it is possible to utilize more Si for cell wall enhancement than Ca or B. In both mature culms and rhizomes, zinc (Zn) was found at much higher concentrations in the nodes with meristematic tissue than those in internodes, indicating that Zn might play a role in promoting culm and rhizome elongation. We suggest that specific and local utilization of B, Si, and Zn in P. pubescens might support the vegetative reproduction and rapid growth. - Highlights: • The bamboo efficiently utilizes boron by the retranslocation and local accumulation. • Zinc found in nodes at high concentrations may support

  8. Compiling the Dictionary of Word Associations in Estonian: From scratch to the database

    Directory of Open Access Journals (Sweden)

    Ene Vainik

    2018-04-01

    Full Text Available The present paper describes the project titled “The Dictionary of Word Associations in Estonian” undertaken by the author at the Institute of the Estonian Language. The general aim of the Dictionary is to provide insights into Estonians’ common-sense mind. It is meant to be a tool of self-reflection for Estonian native speakers and a guide for the foreigners who are eager enough to make themselves familiar with the Estonian cultural patterns of thought. The Dictionary will be published online. The number of keywords was initially limited to approximately 800. Specific emphasis is given to the stage of data collection by implementing the principles of citizen science.

  9. Effect of organic compounds for the advection of actinide elements in the environments

    Energy Technology Data Exchange (ETDEWEB)

    Muraoka, Susumu; Nagao, Seiya; Tanaka, Tadao [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; Hiraki, Keizo; Nakaguchi, Yuzuru; Suzuki, Yasuhiro

    1998-01-01

    The aim of this studies is understood the effects of humic substances for the advection of actinide elements in the environments. These substances are a major role of dissolved organic matter in natural waters. In order to obtain the informations on the structure of metal-humic substances complexes, these substances were studied by fluorescence spectroscopy. Observation the spectrum forms, peak positions of maximum intensity are related to these informations on the chemical structures and functional groups in organic compounds. Using three-dimensional excitation emission matrix (3-D EEM) spectroscopy, the characteristics of metal-humic substances complexes were studied. Observation the wavelengths and fluorescence intensity of the peaks were varied between humic substances before the complex to the metal and these substances after ones. Understanding the fluorescence properties of metal-humic substances complexes, working program of the 3-D EEM spectroscopy was studied to obtaining detailed data collection. New program was applied to copper-humic acid complex, the peak positions which different with before the complex and after ones were recorded. This program is supported by the interpreation of fluorescence properties in the metal-humic substances by the 3-D EEM spectroscopy. (author)

  10. The width of the lateral element of the synaptonemal complex is determined by a multilayered organization of its components

    Energy Technology Data Exchange (ETDEWEB)

    Ortiz, Rosario, E-mail: r_oh@ciencias.unam.mx [Laboratorio de Microscopía Electrónica, Facultad de Ciencias, Universidad Nacional Autónoma de México, México DF 04510, México (Mexico); Kouznetsova, Anna, E-mail: Anna.Kouznetsova@ki.se [Department of Cell and Molecular Biology, Karolinska Institutet, Berzelius väg 35, 171 77 Stockholm (Sweden); Echeverría-Martínez, Olga M., E-mail: omem@ciencias.unam.mx [Laboratorio de Microscopía Electrónica, Facultad de Ciencias, Universidad Nacional Autónoma de México, México DF 04510, México (Mexico); Vázquez-Nin, Gerardo H., E-mail: vazqueznin@ciencias.unam.mx [Laboratorio de Microscopía Electrónica, Facultad de Ciencias, Universidad Nacional Autónoma de México, México DF 04510, México (Mexico); Hernández-Hernández, Abrahan, E-mail: abrahan.hernandez@ki.se [Department of Cell and Molecular Biology, Karolinska Institutet, Berzelius väg 35, 171 77 Stockholm (Sweden)

    2016-05-15

    The synaptonemal complex (SC) is a proteinaceous structure that holds the homologous chromosomes in close proximity while they exchange genetic material in a process known as meiotic recombination. This meiotic recombination leads to genetic variability in sexually reproducing organisms. The ultrastructure of the SC is studied by electron microscopy and it is observed as a tripartite structure. Two lateral elements (LE) separated by a central region (CR) confer its classical tripartite organization. The LEs are the anchoring platform for the replicated homologous chromosomes to properly exchange genetic material with one another. An accurate assembly of the LE is indispensable for the proper completion of meiosis. Ultrastructural studies suggested that the LE is organized as a multilayered unit. However, no validation of this model has been previously provided. In this ultrastructural study, by using mice with different genetic backgrounds that affect the LE width, we provide further evidence that support a multilayered organization of the LE. Additionally, we provide data suggesting additional roles of the different cohesin complex components in the structure of the LEs of the SC. - Highlights: • The lateral element of the synaptonemal complex is a multilayered structure. • The width of the lateral element in synaptonemal complex-null mice is different. • Two cohesin complex cores plus one axial element form a wild-type lateral element. • The layers of the lateral element can be analyzed in different null mice models.

  11. The Woman as Wolf (AT 409: Some Interpretations of a Very Estonian Folk Tale

    Directory of Open Access Journals (Sweden)

    Merili Metsvahi

    2013-12-01

    Full Text Available The article analyses tale type The Woman as Wolf, which is one of the most popular folk tales in the Estonian Folklore Archives and is represented there both in the form of a fairy tale and in the form of a legend. The vast majority of the versions of The Woman as Wolf were written down in the first part of the 20th century within Estonia and where recorded from Estonians. The article introduces the content of the tale, the origin of the first records from the early 19th century, and the dissemination area of the tale, which remains outside Western Europe: apart from the Estonian versions there are Sami, Karelian, Vepsian, Livonian, Latvian, Lithuanian, Russian, Ukrainian and Belarusian versions. While in almost all the Estonian versions the main protagonist is transformed into a wolf, in most of the versions written down in other areas and ethnic groups, another animal or bird replaces the wolf. The author is of the opinion that the Finnic area is central to the distribution of the folk tale The Woman as Wolf. The animal the woman is transformed into in the plot would not have been a wolf in earlier times. The article provides an explanation why the wolf is predominant in Estonian written sources. For that purpose the ways in which the wolf and werewolf were perceived in earlier Estonian folk belief are introduced. At the end of the article interpretation of the folk tale is provided. The author states that the plot and some of the motifs found in this folk tale reflect the difficulties women had in submitting to the norms and values of patriarchal order within their society.

  12. MODELLING DICLOFENAC AND IBUPROFEN RESIDUES IN MAJOR ESTONIAN SEASIDE CITIES

    Directory of Open Access Journals (Sweden)

    Erki Lember

    2016-06-01

    Full Text Available A theoretical model was developed to model the fate of two common pharmaceutical residues: diclofenac and ibuprofen in eight Estonian seaside cities that discharge their wastewaters directly into the Baltic Sea. The consumption rates of the active ingredients of diclofenac and ibuprofen from 2006-2014 were analysed. A decrease of 19.9% for diclofenac consumption and an increase of 14.1% for ibuprofen were found. The fate of diclofenac and ibuprofen were modelled by considering the human metabolism removal rate for pharmaceuticals, the removal rate of diclofenac and ibuprofen in activated sludge wastewater treatment plants (WWTP and annual flow rates. An average decrease from 1 to 0.8 µg/l (decrease of 20% for diclofenac and an increase from 11.4 to 13.4 µg/l (increase of 14.9% for ibuprofen for the concentration in the effluents of the WWTP were modelled. The model gives us a good overview about the theoretical concentrations of pharmaceutical residues in the environment and is helpful for evaluating environmental impacts.

  13. History of experimental psychology from an Estonian perspective.

    Science.gov (United States)

    Allik, Jüri

    2007-11-01

    A short review of the development of experimental psychology from an Estonian perspective is presented. The first rector after the reopening of the University of Dorpat (Tartu) in 1802, Georg Friedrich Parrot (1767-1852) was interested in optical phenomena which he attempted to explain by introducing the concept of unconscious inferences, anticipating a similar theory proposed by Herman von Helmholtz 20 years later. One of the next rectors, Alfred Wilhelm Volkmann (1800-1878) was regarded by Edwin Boring as one of the founding fathers of the experimental psychology. Georg Wilhelm Struve (1793-1864) played an essential part in solving the problem of personal equations. Arthur Joachim von Oettingen (1836-1920) developed a theory of music harmony, which stimulated his student Wilhelm Friedrich Ostwald (1853-1932) to study colour harmony. Emil Kraepelin (1856-1926), the founder of modern psychiatry, is by far the most important experimental psychologist who has worked in Estonia. His successor Wladimir von Tchisch (1855-1922), another student of Wilhelm Wundt, continued Kraepelin's work in experimental psychology. The lives of Wolfgang Köhler (1887-1967), who was born in Reval (Tallinn), and Oswald Külpe (1862-1915), who graduated from the University of Dorpat, extended the link between the history of experimental psychology and Estonia. Karl Gustav Girgensohn (1875-1925), the founder of the Dorpat School of the psychology of religion, stretched the use of experimental methods to the study of religious experience.

  14. Chernobyl is still haunting us. Radionuclides in Estonian mushrooms

    International Nuclear Information System (INIS)

    Martin, J.; Vilde, R.; Martin, L.; Aaspollu, J.; Tekko, S.

    1993-01-01

    The disaster that happened at the Chernobyl nuclear power station in 1986 caused a sharp rise in radioactive pollution over an extensive area in the region of the Baltic Sea. To estimate the distribution and the concentration of Cs-137 and Sr-90 in Estonian ecosystems, samples of mushrooms, mosses, lichens and the upper horizons of soil were gathered from 63 test sites during 1991. We were particularly interested in the amounts of radionuclides in mushrooms because these are used as food by people. Dangerously high radionuclide concentrations were found in mushrooms gathered in North-East Estonia. Heightened concentrations were registered here and there all over the territory of Estonia, especially in mushrooms gathered in Central and South-Western Estonia. The Cs-137 content in mushrooms depends on its content in other components of the ecosystems, first and foremost on the concentrations of radiocaesium in mosses and litter, which, therefore, can be used as indicators in prognostication the radioactive pollution of mushrooms in a certain region. As Cs-137 migrates between various ecosystem components, it is necessary to check the radioactivity of the forest products used for food for still a number of years to come. The Sr-90 level was low in all the ecosystem components examined. (author). 3 figs., 10 refs

  15. Estonian Perceptions of Security: Not Only About Russia and the Refugees

    Directory of Open Access Journals (Sweden)

    Veebel Viljar

    2016-12-01

    Full Text Available The current study focuses on the Estonian perceptions of security and on the defence situation both globally and locally. The dynamic results of the public opinion surveys on security risks conducted in Estonia over the last 10 years (2006-2016 will be presented. In addition, to understand whether some of the security risks could be over- or underestimated in Estonia, these results will be compared with the views expressed recently by the World Economic Forum, particularly the Global Risks Report 2016. Also, the arguments why some topics have played or are currently playing key role in the Estonian security perception will be presented and discussed.

  16. Iseseisvusdeklaratsioonid 1776–1918. The Estonian Declaration of Sovereignty: An Example of the Civilizing Force of Hypocrisy

    Directory of Open Access Journals (Sweden)

    Hent Kalmo

    2012-06-01

    Full Text Available Sovereignty has been characterised as a form of “organized hypocrisy”, a system governed by a set of rules that are generally recognised as binding and yet are continually infringed upon by the most powerful actors. This idea can be extended to analyse the role of sovereignty within the Soviet Union. The Soviet Union was nominally governed by a Constitution which endowed the Union Republics with the right of secession, but there was no realistic possibility of exercising this right. One should not rush to conclude, however, that the actual wording of the Soviet Constitution of 1977 was entirely without relevance. As Jon Elster has argued, hypocrisy can have a “civilizing force” when the need to appear impartial and to retain public credibility forces actors to choose a strategy they would not choose otherwise. A good example of this kind of argumentative constraint is offered by the dilemma faced by the Soviet leadership after the mid-1980s, as it became reluctant to use military force to suppress independence movements within the Baltic States while, at the same time, promising to give more weight to the Soviet Constitution and respect the “sovereignty” of the Union Republics. In this setting, the ambiguity of the word “sovereignty” could be played upon by a whole gamut of political movements in order to further their agenda, from local communists eager to expand their autonomy within the Soviet system to those making an explicit bid for the restoration of independence. Significant legal and political changes could be justified as mere conclusions from the constitutionally recognised status of the Union Republics – a strategy which was all the more effective as Moscow struggled to formulate an alternative line of constitutional interpretation that could be used to counter the Baltic claims. This exchange of opinions escalated into a constitutional conflict in November 1988, when the Estonian Supreme Soviet responded to

  17. Combustion characteristics of water-insoluble elemental and organic carbon in size selected ambient aerosol particles

    Directory of Open Access Journals (Sweden)

    K. Wittmaack

    2005-01-01

    Full Text Available Combustion of elemental carbon (EC and organic carbon (OC contained in ambient aerosol matter was explored using scanning electron microscopy (SEM in combination with energy dispersive X-ray analysis (EDX. To ease identification of the particles of interest and to avoid or at least reduce interaction with simultaneously sampled inorganic oxides and salts, the approach used in this work differed in two ways from commonly applied procedures. First, rather than using a mixture of particles of vastly different sizes, as in PM10 or PM2.5, aerosol matter was collected in a 5-stage impactor. Second, the water soluble fraction of the collected matter was removed prior to analysis. Diesel soot particles, which appeared in the well-known form of chain-type aggregates, constituted the major fraction of EC. In contrast, OC containing particles were observed in a variety of shapes, including a sizable amount of bioaerosol matter appearing mostly in the size range above about 1 µm. During heating in ambient air for 1h, diesel soot particles were found to be stable up to 470°C, but complete combustion occurred in a narrow temperature interval between about 480 and 510°C. After diesel soot combustion, minute quantities of 'ash' were observed in the form of aggregated tiny particles with sizes less than 10 nm. These particles could be due to elemental or oxidic contaminants of diesel soot. Combustion of OC was observed over a wide range of temperatures, from well below 200°C to at least 500°C. Incompletely burnt bioaerosol matter was still found after heating to 600°C. The results imply that the EC fraction in aerosol matter can be overestimated significantly if the contribution of OC to a thermogram is not well separated.

  18. Comparative Study of Elemental Nutrients in Organic and Conventional Vegetables Using Laser-Induced Breakdown Spectroscopy (LIBS).

    Science.gov (United States)

    Bhatt, Chet R; Alfarraj, Bader; Ghany, Charles T; Yueh, Fang Y; Singh, Jagdish P

    2017-04-01

    In this study, the laser-induced breakdown spectroscopy (LIBS) technique was used to identify and compare the presence of major nutrient elements in organic and conventional vegetables. Different parts of cauliflowers and broccolis were used as working samples. Laser-induced breakdown spectra from these samples were acquired at optimum values of laser energy, gate delay, and gate width. Both univariate and multivariate analyses were performed for the comparison of these organic and conventional vegetable flowers. Principal component analysis (PCA) was taken into account for multivariate analysis while for univariate analysis, the intensity of selected atomic lines of different elements and their intensity ratio with some reference lines of organic cauliflower and broccoli samples were compared with those of conventional ones. In addition, different parts of the cauliflower and broccoli were compared in terms of intensity and intensity ratio of elemental lines.

  19. Investigation on trace elements in crude oil and organic matter extracted from rocks with instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    Ding Zuguo; Chai Zhifang

    1990-01-01

    Solvent extraction, column chromatography and instrumental neutron activation analysis(INAA) have been used to investigate the trace elements in crude oil, organic matter extracted from rocks and their related fractions. With these methods, about 70 crude oil samples from eight different oil fields in China and 6 extracted asphaltene samples of the lower paleozoic from the upper Yangtze region have been analyzed, and about 40 elements of interest have been determined. Those elements include Al, As, Au, Ba, Br, Cl, Co, Cr, Cs, Cu, Fe, Hf, I, Ir, Mg, Mn, Mo, Na, Ni, Rb, Re, S, Sb, Sc, Se, Sr, Th, Zn, V and parts of REE. The experimental results show that the method possesses several advantages, i.e. non-destructive, multi-elements, sensitive, precise and accurate. Without ashing samples, the loss of volatile elements such as Cl, S, Se and Sb are avoided. The column chromatography makes it possible to study the distributions of trace elements in different fractions of crude oil and organic matter extracted. Meanwhile, the characters of trace elements in them have also been discussed

  20. Occurrence and risk assessment of potentially toxic elements and typical organic pollutants in contaminated rural soils.

    Science.gov (United States)

    Xu, Yongfeng; Dai, Shixiang; Meng, Ke; Wang, Yuting; Ren, Wenjie; Zhao, Ling; Christie, Peter; Teng, Ying

    2018-07-15

    The residual levels and risk assessment of several potentially toxic elements (PTEs), phthalate esters (PAEs) and polycyclic aromatic hydrocarbons (PAHs) in rural soils near different types of pollution sources in Tianjin, China, were studied. The soils were found to be polluted to different extents with PTEs, PAEs and PAHs from different pollution sources. The soil concentrations of chromium (Cr), nickel (Ni), di-n-butyl phthalate (DnBP), acenaphthylene (Any) and acenaphthene (Ane) were higher than their corresponding regulatory reference limits. The health risk assessment model used to calculate human exposure indicates that both non-carcinogenic and carcinogenic risks from selected pollutants were generally acceptable or close to acceptable. Different types of pollution sources and soil physicochemical properties substantially affected the soil residual concentrations of and risks from these pollutants. PTEs in soils collected from agricultural lands around industrial and residential areas and organic pollutants (PAEs and PAHs) in soils collected from agricultural areas around livestock breeding were higher than those from other types of pollution sources and merit long-term monitoring. Copyright © 2018 Elsevier B.V. All rights reserved.

  1. Elemental and organic carbon in flue gas particles of various wood combustion systems

    Energy Technology Data Exchange (ETDEWEB)

    Gaegauf, C.; Schmid, M.; Guentert, P.

    2005-12-15

    The airborne particulate matter (PM) in the environment is of ever increasing concern to authorities and the public. The major fractions of particles in wood combustion processes are in the size less than 1 micron, typically in the range of 30 to 300 nm. Of specific interest is the content of the elemental carbon (EC) and organic carbon (OC) in the particles since these substances are known for its particular potential as carcinogens. Various wood combustion systems have been analysed (wood chip boiler, pellet boiler, wood log boiler, wood stove and open fire). The sampling of the particles was done by mean of a multi-stage particle sizing sampler cascade impactor. The impactor classifies the particles collected according to their size. The 7 stages classify the particles between 0.4 and 9 microns aerodynamic diameter. The analytical method for determining the content of EC and OC in the particles is based on coulometry. The coulometer measures the conductivity of CO{sub 2} released by oxidation of EC in the samples at 650 {sup o}C. The OC content is determined by pyrolysis of the particle samples in helium atmosphere.

  2. Polycyclic aromatic hydrocarbons, elemental and organic carbon emissions from tire-wear.

    Science.gov (United States)

    Aatmeeyata; Sharma, Mukesh

    2010-09-15

    Tire-wear is an important source of PAHs, elemental carbon (EC) and organic carbon (OC). The emissions of these pollutants have been studied in an experimental set-up, simulating a realistic road-tire interaction (summer tire-concrete road). The large particle non-exhaust emissions (LPNE; diameter greater than 10 microm) have been evaluated over 14,500 km run of the tire. An increasing linear trend with cumulative km run was observed for emissions of PAHs and carbon. Amongst PAHs in LPNE, pyrene has been observed to be the highest (30+/-4 mg kg(-1)) followed by benzo[ghi]perylene (17+/-2 mg kg(-1)). Different fractions of EC-OC for tire-wear have been analyzed, and unlike exhaust emissions, EC1 was observed to be 99% of EC whereas more than 70% of the OC was the high temperature carbon (OC3 and OC4). The overall emission factors (mass tire(-1) km(-1)) for PAHs, EC and OC from tire-wear are 378 ng tire(-1) km(-1), 1.46 mg tire(-1) km(-1) and 2.37 mg tire(-1) km(-1) for small cars. Copyright 2010 Elsevier B.V. All rights reserved.

  3. Organic and Elemental Carbon Aerosol Particulates at the Southern Great Plains Site Field Campaign Report

    Energy Technology Data Exchange (ETDEWEB)

    Cary, Robert

    2016-04-01

    The purpose of this study was to measure the organic carbon (OC) and elemental carbon (EC) fractions of PM2.5 particulate matter at the U.S. Department of Energy (DOE)’s Atmospheric Radiation Measurement (ARM) Climate Research Facility Southern Great Plains (SGP) sampling site for a 6-month period during the summer of 2013. The site is in a rural location remote from any populated areas, so it would be expected to reflect carbon concentration over long-distance transport patterns. During the same period in 2012, a number of prairie fires in Oklahoma and Texas had produced large plumes of smoke particles, but OC and EC particles had not been quantified. In addition, during the summer months, other wild fires, such as forest fires in the Rocky Mountain states and other areas, can produce carbon aerosols that are transported over long distances. Both of these source types would be expected to contain mixtures of both OC and EC.

  4. The problems and development potential of revenue autonomy in Estonian municipalities. Kohalike omavalitsuste tuluautonoomia probleemid ja arenguvõimalused Eestis

    Directory of Open Access Journals (Sweden)

    Janno Reiljan

    2013-01-01

    Full Text Available In a regionally heterogeneous country like Estonia, it is a difficult task to create a local government revenue structure that guarantees even supply of public services across the entire country and, at the same time, revenue autonomy for the municipalities. In the theoretical part of the current article the suitability of different sources of own revenues are analysed in the context of Estonian municipalities. The empirical part of the article compares the financing principles of Estonian municipalities with other EU countries. Finally, the proportions of different own sources of revenues in the budgets of Estonian local governments are examined and suggestions are made for changing the current system

  5. Purification of the Drain Water and Distillation Residues from Organic Compounds, Transuranic Elements and Uranium at the Chernobyl NPP

    Directory of Open Access Journals (Sweden)

    Rudenko, L.I.

    2014-05-01

    Full Text Available Article examines the purification of drain water and distillation residue from organic (polymeric compounds, tran suranic elements and uranium. We propose the pretreatment method with the use of a type «Sizol» coagulant-flocculant and catalytic oxidation with hydrogen peroxide and ultrafiltration. This method prevents evaporator coking by dustsuppression and other organic substances, which are vulcanized by heating. Removing alpha-emitting radionuclides increases safety level at the nuclear power plant.

  6. Tiger in Focus--A National Survey of ICT in Estonian Schools

    Science.gov (United States)

    Toots, Anu; Laanpere, Mart

    2004-01-01

    Estonia has not participated in international studies of ICT in education, nor have there been any similar studies at the national level up until the year 2000. The first survey of ICT in Estonian schools was conducted after completion of the national school computerization programme called Tiger Leap. This paper focuses on the targeted responses…

  7. Alberta's Estonians 1899 - Present TLÜ Akadeemilises Raamatukogus / Sander Jürisson

    Index Scriptorium Estoniae

    Jürisson, Sander

    2014-01-01

    Tallinna Ülikooli Akadeemilises Raamatukogus on üleval näitus "Alberta's Estonians 1899 - Present", mis annab ülevaate Kanada Alberta provintsi eestlaste loost. Näitus valmis Alberta Eesti Kultuuripärandi Seltsi koostöös Alberta Provintsi Arhiivi Kultuuripärandi Osakonnaga Edmontonis

  8. Consumer Socialisation and Value Orientations among Estonian and Chinese Young People

    Science.gov (United States)

    Waerdahl, Randi; Kalmus, Veronika; Keller, Margit

    2011-01-01

    This paper asks if Estonian and Chinese tweens' access to pocket money influences their brand valuation, as well as value orientations in the context of perceived peer popularity and personal well-being. Surveys conducted in autumns 2006 (China n = 188) and 2007 (Estonia n = 111) show an inherent cultural resistance among tweens in both countries…

  9. The Perceived Impact of External Evaluation: The System, Organisation and Individual Levels-Estonian Case

    Science.gov (United States)

    Seema, Riin; Udam, Maiki; Mattisen, Heli; Lauri, Liia

    2017-01-01

    The purpose of this article is to provide an overview of how the employees of higher education institutions perceive the impact of external evaluations. The study was conducted using the concurrent mixed method and involved 361 employees from Estonian universities and professional higher education institutions. The results indicated that…

  10. The 2011 Estonian High School Language Reform in the Context of Critical Language Policy and Planning

    Science.gov (United States)

    Skerrett, Delaney Michael

    2014-01-01

    This paper seeks to situate Estonian language use and policy within the emerging field of critical language policy and planning (CLPP) by investigating the discourses that frame linguistic behaviour. This done by way of an analysis of a series of interviews carried out with key actors in language policy in Estonia. The discourses framing language…

  11. Estonian Airi ümber käib lehmakauplemine / Tõnu Lilleorg

    Index Scriptorium Estoniae

    Lilleorg, Tõnu

    2008-01-01

    Skandinaavia lennukompanii SAS saatis Eesti valitsusele kirja, milles teatab, et on nõus raskustes Estonian Airile lisainvesteeringuid tegema vaid siis, kui riik müüb SAS-ile oma osaluse, 34%. Vt. samas: SAS ei taha lennufirma eest maksta üle 150 miljoni. Diagramm: Majandusnäitajad, omanikud

  12. Estonian Cell peab suu kasumist puhtaks pühkima / Kaisa Tahlfeld, Katre Pilvinski

    Index Scriptorium Estoniae

    Tahlfeld, Kaisa

    2008-01-01

    Estonian Cell saatis valitsusele pöördumise, milles palutakse teha parandusi elektrienergiaga seonduvates seadustes, mis aitaksid ettevõtet energia hinnatõusu ajal. Elektri hinnatõusu tõttu on muutunud küsitavaks ka Nitroferti tehase edasine eksisteerimine

  13. Sustainable development outlooks of the Estonian energy sector for convergence with the European Union countries

    International Nuclear Information System (INIS)

    Laur, Anton; Tenno, Koidu; Soosaar, Sulev

    2002-01-01

    The article presents an overview of a research conducted in the Estonian Inst. of Economics and the Estonian Energy Research Inst. with the objectives to: analyse the dynamics of the main Estonian energy use indicators over the last 8-10 years with the background of general macroeconomics developments; compare these indicators with the respective energy indicators in the European Union Member States and Candidate Countries; evaluate Estonia's potential to catch up by the energy use efficiency (GDP energy intensity) of the average level of EU countries, modelling our possible development scenarios of GDP and TPES. The research results indicates several positive development tendencies (e.g. reduction of TPES and CO 2 emissions with the background of economic growth) in the Estonian energy sector, as well as convergence with the EU countries in terms of GDP energy intensity. Unfortunately, the model analysis results demonstrate that it takes a lot of time for Estonia to reach the current EU level - even under the most favourable GDP and TPES development conditions, 25-30 years. The primary reason is the very low level of our GDP per capita compared to the EU countries. (author)

  14. Estonian Vocational Teachers' Attitudes towards Inclusive Education for Students with Special Educational Needs

    Science.gov (United States)

    Rose, Richard; Kaikkonen, Leena; Koiv, Kristi

    2007-01-01

    This paper presents the findings from research conducted with two samples of teachers from Estonian Vocational Schools. The first sample comprised a group of teachers who had received professional development directly related to the management of students with special educational needs in vocational education settings. Their attitudes and…

  15. Russian-Estonian Economic and Investment Cooperation During the Crisis: Dynamics and Possibilities

    Directory of Open Access Journals (Sweden)

    Nevskaya Anastasia

    2015-06-01

    Full Text Available The article deals with the development in Russian-Estonian relations during the crises of 2007 and 2014, taking into consideration the balance between political and economic factors in the decision-making by Estonian government. A number of special aspects, trends and problems in trade and investment ties are detected. The aim of the study is to uncover key motivation behind the actions of both Russia and Estonia, to identify the drivers for economic and political development in the region, and to work out recommendations to adjust them. The questions put forward by the authors of this article could not be more topical at the time, when Russian economic situation is obviously getting worse and capital flight (to the neighboring EU Member States is likely to increase. The method of the study is comparative analysis of the impact on economic ties made by Russian-Estonian crisis of 2007 and the current international tension around Ukraine. The regional fossil fuel market and the possibilities of Gazprom involvement in its development are also analyzed. It is concluded that political motives are still important for Estonian decisionmaking, though they are balanced out by measures of business support (despite some of these measures being taken by the EU bodies. The role of political factor for the Russian side is increasing. It is acknowledged that there is a growing number of missed economic opportunities in the Russian Northwest.

  16. The Estonian diaspora in South-West Russia in the 1920—30s: migration results

    Directory of Open Access Journals (Sweden)

    Stupin Yuri

    2010-11-01

    Full Text Available This article analyses the spatial features of the settling of Russian Estonians in the Northwest region at the “zenith” of diaspora on the basis of 1920, 1926, and 1939 censuses. The author identifies the principal settling areas and points out the geographical preconditions for the rapid decline of the diaspora.

  17. Gender Advantages and Gender Normality in the Views of Estonian Secondary School Students

    Science.gov (United States)

    Kuurme, Tiiu; Kasemaa, Gertrud

    2015-01-01

    The aim of the study on Estonian secondary school students was to obtain an overview of the gender-related views and experiences of the everyday school life by students, and to analyse the school-related factors in the development of gender roles and gender-related expectations. We view gender equality as a central condition for social…

  18. Organizational culture based on the example of an Estonian hospital.

    Science.gov (United States)

    Saame, Iisi; Reino, Anne; Vadi, Maaja

    2011-01-01

    The concept of organisational culture (also referred to later as OC) is one of the approaches in modern organisational analysis exploring the values, attitudes and beliefs behind human behaviour in the workplace. OC as a social phenomenon is considered to be important for the sustainability of every organisation. In the service sector, OC may affect the nature and quality of the services provided. The aim of this paper is twofold: on the one hand, to highlight the patterns of OC in a hospital; and, on the other hand, to outline relationships between OC and patient satisfaction. The study was conducted in Tartu University Hospital, one of the most influential health care organisations in Estonia. This paper has original value by presenting an insight into organisational culture in the Estonian health care sector, and the findings of the study will expand knowledge of OC in the health care sector in general. The OC instrument applied in a quantitative cross-sectional study was earlier developed according to the Competing Values Framework (CVF). Data from 456 medical and non-medical professionals were analysed using non-parametric tests of descriptive statistics. A factor analysis was performed to assess the instrument's compatibility for analysing the OC pattern in the health care sector. The dominant culture type in all the groups investigated was the Internal Processes type, mainly followed by the Rational Goal type, while different cultural patterns were observed in professional groups. The factor analysis yielded a three-subscale solution. Clinics with high patient satisfaction did not score more than clinics with low patient satisfaction in terms of the Human Relations type. In future studies a random sample design and a multidisciplinary approach to OC research should be followed in order to further explore OC patterns in hospitals and their consequences for different aspects of hospital performance.

  19. Power without manpower: Forecasting labour demand for Estonian energy sector

    International Nuclear Information System (INIS)

    Meriküll, Jaanika; Eamets, Raul; Humal, Katrin; Espenberg, Kerly

    2012-01-01

    As energy demand and prices continue to grow, oil shale might help mitigate the energy crisis—it can widely be found all over the world but so far has not been widely used. Estonia is unique in the world for producing a large majority of energy out of oil shale and has been set as an example in numerous papers covering oil shale deposits, technology etc. This paper is the first to analyse oil shale energy related workforce and provides scenario forecasts of the labour demand for the Estonian energy sector in 2010–2020. The contribution of the paper is twofold. First, the paper provides a valuable insight into oil shale energy related workforce, enabling to take into consideration the educational needs in countries where oil shale industry might be set up. Second, methodology-wise, the paper relates labour demand and supply to different scenarios of energy production capacities. The results illustrate problems related to aging of the workforce in energy production. If the existing trends continue in educational attainment in Estonia, there will be a serious shortage of high-skilled engineering and manufacturing specialists. Our method provides a simple yet reliable enough way to check for such problems early enough. - Highlights: ► This paper analyses oil shale energy related workforce and provides scenario forecasts. ► This is the first study to investigate the workforce related to oil shale energy production. ► The main workforce-related problem in the sector is ageing of the workforce. ► Workers immigrating to the sector during the Soviet times are at the retirement age. ► There will be a serious shortage of engineers for energy sector in the near future.

  20. Elements of Organizational Culture Superintendents Perceive as Important to Create and Maintain a Successful Organization in Times of Crisis

    Science.gov (United States)

    Wilson, Marylou K.

    2012-01-01

    Purpose: The purpose of this study was to identify and describe the elements of culture public school superintendents perceive to be most important in creating and sustaining successful organizations in times of crisis. In addition, it was the purpose of this study to identify and describe the leadership strategies superintendents use to create…

  1. Organization of cis-acting regulatory elements in osmotic- and cold-stress-responsive promoters.

    Science.gov (United States)

    Yamaguchi-Shinozaki, Kazuko; Shinozaki, Kazuo

    2005-02-01

    cis-Acting regulatory elements are important molecular switches involved in the transcriptional regulation of a dynamic network of gene activities controlling various biological processes, including abiotic stress responses, hormone responses and developmental processes. In particular, understanding regulatory gene networks in stress response cascades depends on successful functional analyses of cis-acting elements. The ever-improving accuracy of transcriptome expression profiling has led to the identification of various combinations of cis-acting elements in the promoter regions of stress-inducible genes involved in stress and hormone responses. Here we discuss major cis-acting elements, such as the ABA-responsive element (ABRE) and the dehydration-responsive element/C-repeat (DRE/CRT), that are a vital part of ABA-dependent and ABA-independent gene expression in osmotic and cold stress responses.

  2. Phytoremediation of sewage sludge contaminated by trace elements and organic compounds.

    Science.gov (United States)

    Guidi Nissim, Werther; Cincinelli, Alessandra; Martellini, Tania; Alvisi, Laura; Palm, Emily; Mancuso, Stefano; Azzarello, Elisa

    2018-07-01

    Phytoremediation is a green technique being increasingly used worldwide for various purposes including the treatment of municipal sewage sludge (MSS). Most plants proposed for this technique have high nutrient demands, and fertilization is often required to maintain soil fertility and nutrient balance while remediating the substrate. In this context, MSS could be a valuable source of nutrients (especially N and P) and water for plant growth. The aim of this study was to determine the capacity willow (Salix matsudana, cv Levante), poplar (Populus deltoides × Populus nigra, cv Orion), eucalyptus (Eucalyptus camaldulensis) and sunflower (Helianthus annuus) to clean MSS, which is slightly contaminated by trace elements (TEs) and organic pollutants, and to assess their physiological response to this medium. In particular, we aimed to evaluate the TE accumulation by different species as well as the decrease of TEs and organic pollutants in the sludge after one cropping cycle and the effect of MSS on plant growth and physiology. Since MSS did not show any detrimental effect on the biomass yield of any of the species tested, it was found to be a suitable growing medium for these species. TE phytoextraction rates depended on the species, with eucalyptus showing the highest accumulation for Cr, whereas sunflower exhibited the best performance for As, Cu and Zn. At the end of the trial, some TEs (i.e. Cr, Pb and Zn), n-alkanes and PCBs showed a significant concentration decrease in the sludge for all tested species. The highest Cr decrease was observed in pots with eucalyptus (57.4%) and sunflower (53.4%), whereas sunflower showed the highest Cu decrease (44.2%), followed by eucalyptus (41.2%), poplar (16.2%) and willow (14%). A significant decrease (41.1%) of Pb in the eucalyptus was observed. Zn showed a high decrease rate with sunflower (59.5%) and poplar (52%) and to a lesser degree with willow (35.3%) and eucalyptus (25.4%). The highest decrease in n

  3. Some trace elements in the waters, marine organisms and sediments of the Adriatic by neutron activation analysis

    International Nuclear Information System (INIS)

    Kosta, L.; Ravnik, V.; Byrne, A.R.; Dermelj, M.; Stirn, J.

    1978-01-01

    A number of investigations of trace elements in the waters, organisms and sediments of the Adriatic, using neutron activation analysis with radiochemical separations are reported. These include studies of Hg in mussels from the Northern Adriatic, of Hg and Se in edible animals from the Rijeka region, and of seven elements (As, Cd, Cu, Hg, Mn, Se and Zn) in marine invertebrates from the Slovene coast. Additionally, plankton, sediment cores and water samples were taken from a grid of stations covering the whole Adriatic and analyzed for 6 to 11 of the trace elements As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Sb and Zn (Hg only in water). Generally, levels found were not indicative of pollution as compared with oceanic samples, but some evidence of locally increased levels was found, especially for Hg. The levels of eleven trace elements in three marine Intercomparison samples prepared by the IAEA Monaco Laboratory are also presented. (T.G.)

  4. On-line hydrogen-isotope measurements of organic samples using elemental chromium: An extension for high temperature elemental-analyzer techniques

    Science.gov (United States)

    Gehre, Matthias; Renpenning, Julian; Gilevska, Tetyana; Qi, Haiping; Coplen, Tyler B.; Meijer, Harro A.J.; Brand, Willi A.; Schimmelmann, Arndt

    2015-01-01

    The high temperature conversion (HTC) technique using an elemental analyzer with a glassy carbon tube and filling (temperature conversion/elemental analysis, TC/EA) is a widely used method for hydrogen isotopic analysis of water and many solid and liquid organic samples with analysis by isotope-ratio mass spectrometry (IRMS). However, the TC/EA IRMS method may produce inaccurate δ2H results, with values deviating by more than 20 mUr (milliurey = 0.001 = 1‰) from the true value for some materials. We show that a single-oven, chromium-filled elemental analyzer coupled to an IRMS substantially improves the measurement quality and reliability for hydrogen isotopic compositions of organic substances (Cr-EA method). Hot chromium maximizes the yield of molecular hydrogen in a helium carrier gas by irreversibly and quantitatively scavenging all reactive elements except hydrogen. In contrast, under TC/EA conditions, heteroelements like nitrogen or chlorine (and other halogens) can form hydrogen cyanide (HCN) or hydrogen chloride (HCl) and this can cause isotopic fractionation. The Cr-EA technique thus expands the analytical possibilities for on-line hydrogen-isotope measurements of organic samples significantly. This method yielded reproducibility values (1-sigma) for δ2H measurements on water and caffeine samples of better than 1.0 and 0.5 mUr, respectively. To overcome handling problems with water as the principal calibration anchor for hydrogen isotopic measurements, we have employed an effective and simple strategy using reference waters or other liquids sealed in silver-tube segments. These crimped silver tubes can be employed in both the Cr-EA and TC/EA techniques. They simplify considerably the normalization of hydrogen-isotope measurement data to the VSMOW-SLAP (Vienna Standard Mean Ocean Water-Standard Light Antarctic Precipitation) scale, and their use improves accuracy of the data by eliminating evaporative loss and associated isotopic fractionation while

  5. On-line hydrogen-isotope measurements of organic samples using elemental chromium: an extension for high temperature elemental-analyzer techniques.

    Science.gov (United States)

    Gehre, Matthias; Renpenning, Julian; Gilevska, Tetyana; Qi, Haiping; Coplen, Tyler B; Meijer, Harro A J; Brand, Willi A; Schimmelmann, Arndt

    2015-01-01

    The high temperature conversion (HTC) technique using an elemental analyzer with a glassy carbon tube and filling (temperature conversion/elemental analysis, TC/EA) is a widely used method for hydrogen isotopic analysis of water and many solid and liquid organic samples with analysis by isotope-ratio mass spectrometry (IRMS). However, the TC/EA IRMS method may produce inaccurate δ(2)H results, with values deviating by more than 20 mUr (milliurey = 0.001 = 1‰) from the true value for some materials. We show that a single-oven, chromium-filled elemental analyzer coupled to an IRMS substantially improves the measurement quality and reliability for hydrogen isotopic compositions of organic substances (Cr-EA method). Hot chromium maximizes the yield of molecular hydrogen in a helium carrier gas by irreversibly and quantitatively scavenging all reactive elements except hydrogen. In contrast, under TC/EA conditions, heteroelements like nitrogen or chlorine (and other halogens) can form hydrogen cyanide (HCN) or hydrogen chloride (HCl) and this can cause isotopic fractionation. The Cr-EA technique thus expands the analytical possibilities for on-line hydrogen-isotope measurements of organic samples significantly. This method yielded reproducibility values (1-sigma) for δ(2)H measurements on water and caffeine samples of better than 1.0 and 0.5 mUr, respectively. To overcome handling problems with water as the principal calibration anchor for hydrogen isotopic measurements, we have employed an effective and simple strategy using reference waters or other liquids sealed in silver-tube segments. These crimped silver tubes can be employed in both the Cr-EA and TC/EA techniques. They simplify considerably the normalization of hydrogen-isotope measurement data to the VSMOW-SLAP (Vienna Standard Mean Ocean Water-Standard Light Antarctic Precipitation) scale, and their use improves accuracy of the data by eliminating evaporative loss and associated isotopic fractionation while

  6. Elemental, isotopic, and structural changes in Tagish Lake insoluble organic matter produced by parent body processes

    Science.gov (United States)

    Alexander, C. M. O'd.; Cody, G. D.; Kebukawa, Y.; Bowden, R.; Fogel, M. L.; Kilcoyne, A. L. D.; Nittler, L. R.; Herd, C. D. K.

    2014-04-01

    Here, we present the results of a multitechnique study of the bulk properties of insoluble organic material (IOM) from the Tagish Lake meteorite, including four lithologies that have undergone different degrees of aqueous alteration. The IOM C contents of all four lithologies are very uniform and comprise about half the bulk C and N contents of the lithologies. However, the bulk IOM elemental and isotopic compositions vary significantly. In particular, there is a correlated decrease in bulk IOM H/C ratios and δD values with increasing degree of alteration—the IOM in the least altered lithology is intermediate between CM and CR IOM, while that in the more altered lithologies resembles the very aromatic IOM in mildly metamorphosed CV and CO chondrites, and heated CMs. Nuclear magnetic resonance (NMR) spectroscopy, C X-ray absorption near-edge (XANES), and Fourier transform infrared (FTIR) spectroscopy confirm and quantitate this transformation from CR-like, relatively aliphatic IOM functional group chemistry to a highly aromatic one. The transformation is almost certainly thermally driven, and probably occurred under hydrothermal conditions. The lack of a paramagnetic shift in 13C NMR spectra and 1s-σ* exciton in the C-XANES spectra, both typically seen in metamorphosed chondrites, shows that the temperatures were lower and/or the timescales were shorter than experienced by even the least metamorphosed type 3 chondrites. Two endmember models were considered to quantitatively account for the changes in IOM functional group chemistry, but the one in which the transformations involved quantitative conversion of aliphatic material to aromatic material was the more successful. It seems likely that similar processes were involved in producing the diversity of IOM compositions and functional group chemistries among CR, CM, and CI chondrites. If correct, CRs experienced the lowest temperatures, while CM and CI chondrites experienced similar more elevated temperatures

  7. Source apportionment of size and time resolved trace elements and organic aerosols from an urban courtyard site in Switzerland

    Science.gov (United States)

    Richard, A.; Gianini, M. F. D.; Mohr, C.; Furger, M.; Bukowiecki, N.; Minguillón, M. C.; Lienemann, P.; Flechsig, U.; Appel, K.; Decarlo, P. F.; Heringa, M. F.; Chirico, R.; Baltensperger, U.; Prévôt, A. S. H.

    2011-09-01

    Time and size resolved data of trace elements were obtained from measurements with a rotating drum impactor (RDI) and subsequent X-ray fluorescence spectrometry. Trace elements can act as indicators for the identification of sources of particulate matter Switzerland. Eight different sources were identified for the three examined size ranges (PM1-0.1, PM2.5-1 and PM10-2.5): secondary sulfate, wood combustion, fire works, road traffic, mineral dust, de-icing salt, industrial and local anthropogenic activities. The major component was secondary sulfate for the smallest size range; the road traffic factor was found in all three size ranges. This trace element analysis is complemented with data from an Aerodyne high-resolution time-of-flight aerosol mass spectrometer (AMS), assessing the PM1 fraction of organic aerosols. A separate PMF analysis revealed three factors related to three of the sources found with the RDI: oxygenated organic aerosol (OOA, related to inorganic secondary sulfate), hydrocarbon-like organic aerosol (HOA, related to road traffic) and biomass burning organic aerosol (BBOA), explaining 60 %, 22 % and 17 % of total measured organics, respectively. Since different compounds are used for the source classification, a higher percentage of the ambient PM10 mass concentration can be apportioned to sources by the combination of both methods.

  8. Estonian Business Schooli magistriharidus nüüd ka koju kätte / Madis Habakuk

    Index Scriptorium Estoniae

    Habakuk, Madis

    2007-01-01

    Sügisest hakkab Estonian Business School koos Mainori Kõrgkooliga pakkuma magistriõpet majandushariduseta inimestele, kus soovijatel on võimalus õppida EBSi Master of Business Administration programmi järgi

  9. [Encapsulated voices : Estonian sound recordings from the German prisoner-of-war camps in 1916-1918] / Tõnu Tannberg

    Index Scriptorium Estoniae

    Tannberg, Tõnu, 1961-

    2013-01-01

    Arvustus: Encapsulated voices : Estonian sound recordings from the German prisoner-of-war camps in 1916-1918 (Das Baltikum in Geschichte und Gegenwart, 5). Hrsg. von Jaan Ross. Böhlau Verlag. Köln, Weimar und Wien 2012

  10. Väärikas Estonian Air jäi kampaaniaga hätta / Alyona Stadnik

    Index Scriptorium Estoniae

    Stadnik, Alyona

    2010-01-01

    Estonian Air müüs veebikaupluse cherry.ee kaudu soodsaid kinkekaarte. Vastuolu tekkis asjaolust, et nõudlus kinkekaartide järele oli suurem kui pakkumine. Lennukompanii katkestas soodsate kinkekaartide müügi

  11. Noor eesti teater ja Noor-Eesti. Young Estonian Theatre and Young Estonia

    Directory of Open Access Journals (Sweden)

    Katri Aaslav-Tepandi

    2012-04-01

    Full Text Available This article begins by examining points of intersection between two professional theatres, ”Estonia” and ”Vanemuine” (both established in 1906, their young directors – Karl Menning, Paul Pinna, Theodor Altermann, and Karl Jungholz, and the literary movement Young Estonia. Subsequently, we will consider Young Estonia’s theatrical ideals and the influence of these ideas on later Estonian theatrical life. Since not much information has survived regarding direct personal contacts between ”movers and shakers” in the theatre world and Young Estonians, the main focus here shall be on indirect creative connections and influences. One such context is education: like the Young Estonians, theatre activists of the younger generation aspired to place themselves on the larger map of European culture. Thus, their artistic beliefs and goals shall be examined in relation to those of Young Estonians’ quest for modern culture. Pinna, Altermann, Menning, Jungholz, and others went on study tours to Germany and France, where they were energized and inspired by innovative German and Russian theatres, by naturalistic staging, and by psychological realism, both in acting and in performance style. Among their models were A. Antoine’s Théâtre- Libre in Paris, K. Stanislavski’s Art Theatre in Moscow, O. Brahm’s Lessing-Theater, and M. Reinhardt’s Deutsches Theater in Berlin. These models were likewise known to the Young Estonians, but if theatre activists oriented themselves more fundamentally to German naturalist and realist dramatic art, Young Estonians were more taken with ”theatrical theatre” with its symbolist and impressionist influences. The Young Estonians attended performances at both theatres, ”Vanemuine” and ”Estonia”, and wrote numerous theatre reviews. Yet in the Young Estonia albums (yearbooks and in the magazine Young Estonia, theatre topics have a relatively modest representation. Young Estonians did not have direct

  12. Effect of microbial processes on transuranium elements behaviour in soil, plants and animal organism

    International Nuclear Information System (INIS)

    Uajldung, R.Eh.; Garlend, T.P.

    1985-01-01

    Results of preliminary studies discussed in the present paper bring about the supposition that concentration and chemical from of an element in a plant play an essential role in variation of its availability for animals consuming plants. That is why any assessment of long-term behaviour of transuranium elements in terrestrialenvironment should be based on determination of factors affecting solubility and forms of soluble compounds in soil. These factors include concentration and chemical form of the element migrating to soil; effect of the properties of soil on element distribution between solid and liquid phases; effect soil processes on kinetics of sorption reactions, concentration of transuranium elements, forms of soluble and non-soluble chemical compounds

  13. Anatomy of a cluster IDP. Part 2: Noble gas abundances, trace element geochemistry, isotopic abundances, and trace organic chemistry of several fragments from L2008#5

    Science.gov (United States)

    Thomas, K. L.; Clemett, S. J.; Flynn, G. J.; Keller, L. P.; Mckay, David S.; Messenger, S.; Nier, A. O.; Schlutter, D. J.; Sutton, S. R.; Walker, R. M.

    1994-01-01

    The topics discussed include the following: noble gas content and release temperatures; trace element abundances; heating summary of cluster fragments; isotopic measurements; and trace organic chemistry.

  14. Effect of trace element addition and increasing organic loading rates on the anaerobic digestion of cattle slaughterhouse wastewater.

    Science.gov (United States)

    Schmidt, Thomas; McCabe, Bernadette K; Harris, Peter W; Lee, Seonmi

    2018-05-18

    In this study, anaerobic digestion of slaughterhouse wastewater with the addition of trace elements was monitored for biogas quantity, quality and process stability using CSTR digesters operated at mesophilic temperature. The determination of trace element concentrations was shown to be deficient in Fe, Ni, Co, Mn and Mo compared to recommendations given in the literature. Addition of these trace elements resulted in enhanced degradation efficiency, higher biogas production and improved process stability. Higher organic loading rates and lower hydraulic retention times were achieved in comparison to the control digesters. A critical accumulation of volatile fatty acids was observed at an organic loading rate of 1.82 g L -1  d -1 in the control compared to 2.36 g L -1  d -1 in the digesters with trace element addition. The improved process stability was evident in the final weeks of experimentation, in which control reactors produced 84% less biogas per day compared to the reactors containing trace elements. Copyright © 2018 Elsevier Ltd. All rights reserved.

  15. Studies in China on ingestion and organ content of trace elements of importance in radiological protection. Country report

    International Nuclear Information System (INIS)

    Wang Jixian; Zhu Hongda; Chen Rusong

    2000-01-01

    In order to estimate internal dose and derive annual limits of intake for radionuclides in the field of Radiation Protection, it is necessary to study the parameters of ingestion of radionuclides from diet, deposition in tissues and following metabolism of the radionuclides. But these kinds of parameters may be influenced by intake of nutrients and inorganic constituents of diets, for example, a relatively higher uptake rate and longer retention time of radioiodine in thyroid of person who's diet poor of stable iodine. So there is a need to have accurate knowledge of corresponding stable elements intake and their concentration in organs, especially for some trace elements of importance in radiological protection such as Caesium, Iodine, Strontium, Thorium and Uranium. A IAEA RCA CRP on 'Ingestion and organ content of trace elements of importance in Radiological protection' was formulated in 1995 and initiated after the first RCM CRP on the project, held in Manila, Philippine 1-4 July 1996. This is the progress report for studies in China on ingestion and organ content of trace elements of importance in radiological protection after the first RCM

  16. Trace element, semivolatile organic, and chlorinated organic compound concentrations in bed sediments of selected streams at Fort Gordon, Georgia, February-April 2010

    Science.gov (United States)

    Thomas, Lashun K.; Journey, Celeste A.; Stringfield, Whitney J.; Clark, Jimmy M.; Bradley, Paul M.; Wellborn, John B.; Ratliff, Hagan; Abrahamsen, Thomas A.

    2011-01-01

    A spatial survey of streams was conducted from February to April 2010 to assess the concentrations of major ions, selected trace elements, semivolatile organic compounds, organochlorine pesticides, and polychlorinated biphenyls associated with the bed sediments of surface waters at Fort Gordon military installation near Augusta, Georgia. This investigation expanded a previous study conducted in May 1998 by the U.S. Geological Survey, in cooperation with the U.S. Department of the Army Environmental and Natural Resources Management Office of the U.S. Army Signal Center and Fort Gordon, that evaluated the streambed sediment quality of selected surface waters at Fort Gordon. The data presented in this report are intended to help evaluate bed sediment quality in relation to guidelines for the protection of aquatic life, and identify temporal trends in trace elements and semivolatile organic compound concentrations at streambed sites previously sampled. Concentrations of 34 major ions and trace elements and 102 semivolatile organic, organochlorine pesticide, and polychlorinated biphenyl compounds were determined in the fine-grained fraction of bed sediment samples collected from 13 of the original 29 sites in the previous study, and 22 additional sites at Fort Gordon. Three of the sites were considered reference sites as they were presumed to be located away from potential sources of contaminants and were selected to represent surface waters flowing onto the fort, and the remaining 32 nonreference sites were presumed to be located within the contamination area at the fort. Temporal trends in trace elements and semivolatile organic compound concentrations also were evaluated at 13 of the 32 nonreference sites to provide an assessment of the variability in the number of detections and concentrations of constituents in bed sediment associated with potential sources, accumulation, and attenuation processes. Major ion and trace element concentrations in fine-grained bed

  17. Elemental analysis of sediments and organisms from the Cape Verde abyssal plain (CV 1 and CV 2 sites)

    International Nuclear Information System (INIS)

    Germain, P.; Boust, D.; Sibuet, M.; Philippot, J.C.; Hemon, G.

    1984-08-01

    Some 20 stable elements were determined by neutron activation analysis in epibenthic organisms and sediments from the Cape Verde abyssal plain. The levels measured in two Plesiopenaeus sp. (shrimp) individuals and one Barathrites sp. (fish) individual are similar to those found in others crustaceans and fish from oceanic and coastal areas. Concentration factors were calculated for the elements whose radioactive isotopes should be considered in the case of subseabed waste disposal ( 90 Sr, 135 Cs, 79 Se). The sediments are biogenous marly oozes. The levels measured reflect the variations of terrigenous inputs since the last glacial maximum 18,000 B.P [fr

  18. A methodology for elemental and organic carbon emission inventory and results for Lombardy region, Italy

    Energy Technology Data Exchange (ETDEWEB)

    Caserini, Stefano [Politecnico di Milano, DICA Environmental Engineering Section, Piazza Leonardo da Vinci 32, 20133 Milano (Italy); Galante, Silvia, E-mail: silvia1.galante@polimi.it [Politecnico di Milano, DICA Environmental Engineering Section, Piazza Leonardo da Vinci 32, 20133 Milano (Italy); Ozgen, Senem; Cucco, Sara; Gregorio, Katia de [Politecnico di Milano, DICA Environmental Engineering Section, Piazza Leonardo da Vinci 32, 20133 Milano (Italy); Moretti, Marco [Environmental Protection Agency of Lombardia Region, ARPA, 20124 Milano (Italy)

    2013-04-15

    This paper presents a methodology and its application for the compilation of elemental carbon (EC) and organic carbon (OC) emission inventories. The methodology consists of the estimation of EC and OC emissions from available total suspended particulate matter (TSP) emission inventory data using EC and OC abundances in TSP derived from an extensive literature review, by taking into account the local technological context. In particular, the method is applied to the 2008 emissions of Lombardy region, Italy, considering 148 different activities and 30 types of fuels, typical of Western Europe. The abundances estimated in this study may provide a useful basis to assess the emissions also in other emission contexts with similar prevailing sources and technologies. The dominant sources of EC and OC in Lombardy are diesel vehicles for EC and the residential wood combustion (RWC) for OC which together account for about 83% of the total emissions of both pollutants. The EC and OC emissions from industrial processes and other fuel (e.g., gasoline, kerosene and LPG) combustion are significantly lower, while non-combustion sources give an almost negligible contribution. Total EC + OC contribution to regional greenhouse gas emissions is positive for every sector assuming whichever GWP100 value within the range proposed in literature. An uncertainty assessment is performed through a Monte Carlo simulation for RWC, showing a large uncertainty range (280% of the mean value for EC and 70% for OC), whereas for road transport a qualitative analysis identified a narrower range of uncertainty. - Highlights: ► Diesel and wood combustion contribute to more than 80% of total EC and OC. ► More than 50% of EC emissions come from road transport. ► Monte Carlo method is used to assess the uncertainty of wood combustion emissions. ► Residential wood combustion is the main source of uncertainty of EC OC inventory. ► In terms of CO{sub 2}eq, EC and OC correspond to 3% of CO{sub 2

  19. Source apportionment of size and time resolved trace elements and organic aerosols from an urban courtyard site in Switzerland

    Directory of Open Access Journals (Sweden)

    A. Richard

    2011-09-01

    Full Text Available Time and size resolved data of trace elements were obtained from measurements with a rotating drum impactor (RDI and subsequent X-ray fluorescence spectrometry. Trace elements can act as indicators for the identification of sources of particulate matter <10 μm (PM10 in ambient air. Receptor modeling was performed with positive matrix factorization (PMF for trace element data from an urban background site in Zürich, Switzerland. Eight different sources were identified for the three examined size ranges (PM1−0.1, PM2.5−1 and PM10−2.5: secondary sulfate, wood combustion, fire works, road traffic, mineral dust, de-icing salt, industrial and local anthropogenic activities. The major component was secondary sulfate for the smallest size range; the road traffic factor was found in all three size ranges. This trace element analysis is complemented with data from an Aerodyne high-resolution time-of-flight aerosol mass spectrometer (AMS, assessing the PM1 fraction of organic aerosols. A separate PMF analysis revealed three factors related to three of the sources found with the RDI: oxygenated organic aerosol (OOA, related to inorganic secondary sulfate, hydrocarbon-like organic aerosol (HOA, related to road traffic and biomass burning organic aerosol (BBOA, explaining 60 %, 22 % and 17 % of total measured organics, respectively. Since different compounds are used for the source classification, a higher percentage of the ambient PM10 mass concentration can be apportioned to sources by the combination of both methods.

  20. Ligand extraction of rare earth elements from aquifer sediments: Implications for rare earth element complexation with organic matter in natural waters

    Science.gov (United States)

    Tang, Jianwu; Johannesson, Karen H.

    2010-12-01

    The ability of organic matter as well as carbonate ions to extract rare earth elements (REEs) from sandy sediments of a Coastal Plain aquifer was investigated for unpurified organic matter from different sources (i.e., Mississippi River natural organic matter, Aldrich humic acid, Nordic aquatic fulvic acid, Suwannee River fulvic acid, and Suwannee River natural organic matter) and for extraction solutions containing weak (i.e., CH 3COO -) or strong (i.e., CO32-) ligands. The experimental results indicate that, in the absence of strong REE complexing ligands in solution, the amount of REEs released from the sand is small and the fractionation pattern of the released REEs appears to be controlled by the surface stability constants for REE sorption with Fe(III) oxides/oxyhydroxides. In the presence of strong solution complexing ligands, however, the amount and the fractionation pattern of the released REEs reflect the strength and variation of the stability constants of the dominant aqueous REE species across the REE series. The varying amount of REEs extracted by the different organic matter employed in the experiments indicates that organic matter from different sources has different complexing capacity for REEs. However, the fractionation pattern of REEs extracted by the various organic matter used in our experiments is remarkable consistent, being independent of the source and the concentration of organic matter used, as well as solution pH. Because natural aquifer sand and unpurified organic matter were used in our experiments, our experimental conditions are more broadly similar to natural systems than many previous laboratory experiments of REE-humic complexation that employed purified humic substances. Our results suggest that the REE loading effect on REE-humic complexation is negligible in natural waters as more abundant metal cations (e.g., Fe, Al) out-compete REEs for strong binding sites on organic matter. More specifically, our results indicate that REE

  1. Studies in the Philippines on ingestion and organ content of trace elements of importance to radiological protection

    International Nuclear Information System (INIS)

    Natera, E.S.

    1998-01-01

    The first Coordinated Research Program on Reference Asian Man (RAM) was conducted for a period of six years. The study dealt with the collection of data in four areas namely: (1) anthropometric measurements, (2) organ mass measurements, (3) nutritional and dietary intake, and (4) pulmonary and water balance studies. Based on the research needs with reference to radiation protection, dietary intake and tissue analysis appear to be important aspects of the RAM. Information to be generated from the elemental analysis of food and tissue would be used to characterize the intake, retention and release of radioactive elements coming from different population groups. This study also aims to establish the elemental composition profile of the average Filipino using simple and accurate methods of measurements. This report will present the protocol which is based to the extent possible on prescribed procedures required for the study. A standardized Protocol to be used in the study is important since stable elements are present only in trace quantities in biological samples of interest. The procedures presented in this document include: collection of one day diet samples and tissue samples (lung, liver, skeletal muscle, thyroid, bone and kidney) from average healthy adult Filipino. The sample treatment and preparation, analytical measurements, data evaluation and reporting will complete said protocol. The elements that are of importance to radiation protection are iodine, cesium, strontium, thorium, and uranium. The essential minor elements are calcium, potassium and sodium. Trace elements like copper. manganese, iron, selenium and zinc will also be included in the analysis. Concentrations of common toxic elements such as mercury, cadmium and lead may likewise be reported in this study. (author)

  2. Az észt névtervezés az észt nyelvpolitikai modell tükrében [The name management in the mirror of the Estonian LPP-model

    OpenAIRE

    Pomozi, Péter; Földesi, Eszter

    2016-01-01

    The Estonian model of language planning and policy, which has been serving the development and protection of the Estonian language in its current form since 2004, is one of the most successful of such strategies in Europe. It owes it success to the broad social and scientific consensus reached in questions of language policy, regardless of changes in government. The Development Plan of the Estonian Language divides Estonian language planning and policy into three parts: status planning, corpu...

  3. The Hunting of the Snark: Organizing and Synchronizing of Informational Elements for Homeland Defense and Civil Support

    Science.gov (United States)

    2009-06-01

    Organizing and synchronizing informational elements is filled with tension, which is metaphorically illustrated in the Victorian children’s story, The...or distance divided by time. In a similar fashion , dominance can be correlated to the control of a domain. Superiority equates to the degree of...how PA should act in this fashion . The literature recommends that leadership bring PA into the operational fold. The literature consistently

  4. Identification of urushi coated films taken from ancient Buddha images by using PIXE, FT-IR, and organic elemental analysis

    International Nuclear Information System (INIS)

    Kagemori, N.; Umemura, K.; Yoshimura, T.; Inoue, M.; Kawai, S.; Yano, K.; Sera, K.; Futatsugawa, S.; Nakamura, Y.

    1999-01-01

    Six types of samples including urushi, urushi tree and black coating films taken from ancient Buddha images were examined by analyses of PIXE, organic element and FT-IR to identify with urushi or another material. Based on the results of three analytical experiments above mentioned, the coating materials aging over hundreds of years were identified with weathered urushi films mixed with other material. Further investigation may reveal the urushi coating techniques used in the past. (author)

  5. Bioaccumulation of potentially toxic trace elements in benthic organisms of Admiralty Bay (King George Island, Antarctica)

    International Nuclear Information System (INIS)

    Majer, Alessandra Pereira; Petti, Mônica Angélica Varella; Corbisier, Thais Navajas; Ribeiro, Andreza Portella; Theophilo, Carolina Yume Sawamura; Ferreira, Paulo Alves de Lima; Figueira, Rubens Cesar Lopes

    2014-01-01

    Highlights: • Toxic metals were released in the 2012 fire in the Brazilian base at Admiralty Bay. • Potentially toxic metals were measured in eight Antarctic benthos species. • The bioaccumulation of As, Cd and Pb was verified in the studied species. • The biomagnification of Cd is suggested for the studied Antarctic food web. - Abstract: Data about the concentration, accumulation and transfer of potentially toxic elements in Antarctic marine food webs are essential for understanding the impacts of these elements, and for monitoring the pollution contribution of scientific stations, mainly in Admiralty Bay due to the 2012 fire in the Brazilian scientific station. Accordingly, the concentration of As, Cd, Cu, Ni, Pb and Zn was measured in eight benthic species collected in the 2005/2006 austral summer and the relationship between concentration and trophic position (indicated by δ 15 N values) was tested. A wide variation in metal content was observed depending on the species and the element. In the studied trophic positions, it was observed bioaccumulation for As, Cd and Pb, which are toxic elements with no biological function. In addition, Cd showed a positive relationship between concentration and trophic level suggesting the possible biomagnification of this element

  6. Instrumental Neutron Activation Analysis applied to the study of chemical element accumulation in organs of Rhinella schneideri (Werner, 1894)

    Energy Technology Data Exchange (ETDEWEB)

    Bardini Junior, Claudiney; Fernandes, Elisabete A. de Nadai, E-mail: lis@cena.usp.br [Centro de Energia Nuclear na Agricultura (CENA/USP), Piracicaba, SP (Brazil); Santos, Katarine M. Barbosa; Silva Neto, Luiz J. da; Santos, Robson A. dos; Silva, Karolayne E.M.; França, Elvis J. de, E-mail: ejfranca@cnen.gov.br [Centro Regional de Ciências Nucleares do Nordeste (DIAMB/CRCN-NE/CNEN-PE), Recife, PE (Brazil). Div. de Monitoração Ambiental

    2017-07-01

    Instrumental Neutron Activation Analysis (INAA) is a multielementar technique with high sensitivity, and can be applied to study small samples. Therefore, this research proposes using the INAA for quantifying the accumulation of chemical elements in organs of anuran amphibians Rhinella schneideri (Werner, 1894). Male individuals were collected on areas with anthropogenic influence close to water resources on the campus of ESALQ/USP in 2009. The animals were sacrificed in a cold chamber and dissected to separate their kidneys, livers, lungs and skins. After cleaning, the organs were lyophilized and pulverized. Samples weighing from 200 to 500 mg were placed in polyethylene capsules to be irradiated. The INAA technique, based on the bombardment of samples with neutrons for the production of radionuclides, was applied using the Nuclear Research Reactor of the Nuclear and Energy Research Institute. Portions of certified reference materials were used to evaluate the quality of the analytical procedure. The mass fractions were quantified by the k0 method, and the results indicated differences among the As, Br, Co, Cr, Fe, Hg, Sc, Se and Zn concentrations in the analyzed organs. Therefore, it was possible to calculate the bioaccumulation indexes relative to these chemical elements for the species. In addition, it was possible to infer the contamination pathways: As, Br, Co, Cr and Se by ingestion and Co, Fe, Hg, Sc and Zn by contact, which corroborated the usage of R. schneideri anuran as a biomonitor of chemical elements. (author)

  7. Instrumental Neutron Activation Analysis applied to the study of chemical element accumulation in organs of Rhinella schneideri (Werner, 1894)

    International Nuclear Information System (INIS)

    Bardini Junior, Claudiney; Fernandes, Elisabete A. de Nadai; Santos, Katarine M. Barbosa; Silva Neto, Luiz J. da; Santos, Robson A. dos; Silva, Karolayne E.M.; França, Elvis J. de

    2017-01-01

    Instrumental Neutron Activation Analysis (INAA) is a multielementar technique with high sensitivity, and can be applied to study small samples. Therefore, this research proposes using the INAA for quantifying the accumulation of chemical elements in organs of anuran amphibians Rhinella schneideri (Werner, 1894). Male individuals were collected on areas with anthropogenic influence close to water resources on the campus of ESALQ/USP in 2009. The animals were sacrificed in a cold chamber and dissected to separate their kidneys, livers, lungs and skins. After cleaning, the organs were lyophilized and pulverized. Samples weighing from 200 to 500 mg were placed in polyethylene capsules to be irradiated. The INAA technique, based on the bombardment of samples with neutrons for the production of radionuclides, was applied using the Nuclear Research Reactor of the Nuclear and Energy Research Institute. Portions of certified reference materials were used to evaluate the quality of the analytical procedure. The mass fractions were quantified by the k0 method, and the results indicated differences among the As, Br, Co, Cr, Fe, Hg, Sc, Se and Zn concentrations in the analyzed organs. Therefore, it was possible to calculate the bioaccumulation indexes relative to these chemical elements for the species. In addition, it was possible to infer the contamination pathways: As, Br, Co, Cr and Se by ingestion and Co, Fe, Hg, Sc and Zn by contact, which corroborated the usage of R. schneideri anuran as a biomonitor of chemical elements. (author)

  8. Bernhard Linde. Noor-Eesti vooriülem. Bernhard Linde. Leader of the Young Estonian Pack

    Directory of Open Access Journals (Sweden)

    Jaanus Kulli

    2012-04-01

    Full Text Available Bernhard Linde (1886–1954 was a recognized and prolific Estonian theatre critic of the first quarter of the 20th century, who mediated and propagated western as well as eastern European theatrical innovations. In addition, he was active as a literary and art critic, publisher, and proponent of libraries, to a modest extent he was a prose writer and poet. Unquestionably, however, Bernhard Linde’s most prominent role was as one of the founding members of the literary movement Young Estonia. He was the group’s first general manager; later on, he was the secretary of the Estonian Writers’ Association Young Estonia, and the chairman of the board of the Young Estonia Publishing House. Linde’s formal education culminated in graduation from Tartu University as a Slavic philologist; he was the only member of the Young Estonia group to demonstrate serious and sustained interest toward Slavic cultures and peoples. Linde was a contradictory figure, evoking a range of responses from his contemporaries: on the one hand, there was the unbelievably broad range of his participation in cultural life, his organizing skills and business instincts in directing publishing houses; on the other hand, a superficiality in his writings, his often rash and subjective style as a critic, and his financial intrigues. If one adds in Linde’s stubbornness, egocentrism, and intense spirit of protest, which often led to lawsuits, the outcome is the portrait of an extremely complicated, fascinating, and passionate man—both in his creative work and his personal life Linde guaranteed a place for himself in literary history through a small catch of texts: a few foundational essays (for example, on August Kitzberg, a translation of Balzac’s Le père Goriot, the essay collection Omad ja võõrad (Own and Foreign and a travel book focusing on the literature and theatre of eastern Europe (Loova Kesk-Euroopa Poole (Toward A Creative Central Europe. The prominent public

  9. Toxicologically important trace elements and organic compounds investigated in size-fractionated urban particulate matter collected near the Prague highway

    International Nuclear Information System (INIS)

    Sysalová, Jiřina; Sýkorová, Ivana; Havelcová, Martina; Száková, Jiřina; Trejtnarová, Hana; Kotlík, Bohumil

    2012-01-01

    Urban particulate matter was collected in the most exposed area of Prague, near a busy highway, in order to provide petrographic and chemical characterization useful for health impact assessment in that locality or other applications. Samples were collected from filters of the air conditioning system in two years, 2009 and 2010, and sieved into four grain-size fractions: 0.507–0.119 mm, 0.119–0.063 mm, 3 extracted solutions. A composition of inorganic and carbonaceous particles of natural and anthropogenic origin and their morphology were studied by optical and electron microscopy. Organic solvent extracts of the samples were analyzed using gas chromatography to compare the organic compound distribution in fractions. Only slight differences between 2009 and 2010 years are visible. The relatively high extractable part of most investigated elements confirms mobility and potential availability to organisms. The changes can be recognized in the petrographic and organic composition in samples from both years, which were likely the result of various inputs of source materials. Specific organic marker compounds indicate contribution from fossil fuels, plant materials and bacteria. -- Highlights: ► Uncommon urban particulate matter collected near the highway in years 2009 and 2010 was deeply characterized. ► Harmful organic compounds and toxic analytes were tested in grain-size fractions and completed with electron microscopy studies. ► Very similar concentration levels were found in elemental composition in samples from two years. ► Petrographic and organic compositions were different in both samples. ► Relatively high mobility of selected analytes was found in 2M HNO 3 extracted solutions.

  10. Eesti Rahva Muuseumi strateegiad ja praktikad rahvaga suhtlemisel muuseumi algusaastatel / Estonian National Museum: Public communication strategies and practices in the initial years

    Directory of Open Access Journals (Sweden)

    Piret Õunapuu

    2012-01-01

    Full Text Available Until recently the museum phenomenon as the valuator of the indigenous culture in the context of the awakening national consciousness has received little attention. The evolution of the idea of the Estonian National Museum (ENM and its realization reflects the story of the Estonian people maturing into a nation. The museum was founded by a few dedicated persons and it took a long time before the general public recognised it as the museum for the Estonian people. The main purpose of this research is to ascertain how relations developed between the public and the museum in its initial years and what were the museum strategies in declaring its objectives. After the official foundation of the ENM in 1909 the museum narrative can be divided into two main parts. First, work inside the museum, the compilation and arrangement of collections. This was, above all, the work of the collection committee and organizing heritage collection trips. Collections constitute the basis of a museum – therefore the primary and most important task of the established museum was the collection of heritage items. The collections were started immediately after the foundation of the museum; within the first ten years approximately 20,000 items were collected, approximately two thirds of the items in the years 1911–1913. The phenomenon that a museum where people worked mainly without a salary for the benefit of their homeland, with the set aim to empty the whole of Estonia of heritage items parish by parish and succeeded in engaging dozens and dozens of people for this work, is probably exceptional in world history. As a result, the museum acquired not only voluminous but also valuable item collections, which reached the museum before the devastating First World War. The timing was favourable. There were enough old artefacts left, although most collectors complained in their diaries that there was nothing interesting to be found any more. However, the majority of the

  11. The Role of Language in (Recreating Tatar Diaspora Identity: The Case of the Estonian Tatars

    Directory of Open Access Journals (Sweden)

    Maarja Klaas

    2015-06-01

    Full Text Available This paper focuses on the meanings assigned to Tatar language among the Tatar diaspora in Estonia. According to interviews with Estonian Tatars as well as descriptions of field material from Tatarstan, language is an important aspect of Tatar ethnic identity. This paper will track common discourses about the Tatar language and the way it is connected to Tatar ethnic identity. Issues concerning Tatar language are used to demonstrate various ways of enacting Tatarness in Estonia. It is shown that Estonian Tatars worry about the vitality and purity of Tatar language, but for some, marginalization of dialects is also an issue. People categorized with the same identity labels by self and others can experience and enact their Tatarness in a variety of different ways.

  12. Field of genes: the politics of science and identity in the Estonian Genome Project.

    Science.gov (United States)

    Fletcher, Amy L

    2004-04-01

    This case study of the Estonian Genome Project (EGP) analyses the Estonian policy decision to construct a national human gene bank. Drawing upon qualitative data from newspaper articles and public policy documents, it focuses on how proponents use discourse to link the EGP to the broader political goal of securing Estonia's position within the Western/European scientific and cultural space. This dominant narrative is then situated within the analytical notion of the "brand state", which raises potentially negative political consequences for this type of market-driven genomic research. Considered against the increasing number of countries engaging in gene bank and/or gene database projects, this analysis of Estonia elucidates issues that cross national boundaries, while also illuminating factors specific to this small, post-Soviet state as it enters the global biocybernetic economy.

  13. Strategies for Estonian rural family enterprises. Eesti maapiirkonna pereettevõtete strateegia

    Directory of Open Access Journals (Sweden)

    Maret Kirsipuu

    2013-01-01

    Full Text Available The paper seeks to analyse family businesses in rural areas, family business strategies and re-registration of sole proprietors with the Centre of Registers and Information Systems (hereinafter Commercial Register in 2009, and to provide an overview of entrepreneurship policies targeted at Estonian rural businesses. Layoffs have increased the number of unemployed; some of those who have lost employment opt for social assistance benefits, but some others decide to become entrepreneurs. Many enterprising people in Estonia have set up a family enterprise, mainly in the sphere of services, agriculture and tourism. The Estonian entrepreneurship policy supports enterprising people and approves of entrepreneurship as a promoter of national economic development. One of the most positive qualities of family enterprises is their short decision-making chain, which ensures rapid implementation of the strategy.

  14. Study on correlation of trace elements in human hair and internal organs by nuclear methods

    International Nuclear Information System (INIS)

    Cheng Yuandi; Zhuang Guisun; Zhang Yuanxun

    1993-01-01

    Autopsy samples from 24 human males, aged 35-60 years were collected from Shanghai, People's Republic of China, to study possible relationships between the trace element content in hair and internal tissues. Samples of hair, kidney-cortex and lung were collected and analyzed. A radiochemical neutron activation analysis (RNAA) procedure was developed based on a simple group extraction scheme using zinc-diethyl dithiocarbamate and methyl-isobutyl ketone-iodide. The trace elements As, Cd, Hg, Cu and Zn were measured following this procedure. In addition, the elements Se, Na, Mg, Cl, Br, S, Cr, Co, and Rb were determined using instrumental neutron activation analysis (INAA). The reliability of the analytical procedures were checked analyzing several biological reference materials, such as IAEA-H-8 Horse Kidney, NBS-SRM-1573 Tomato Leaves and NIES-5 Human Hair. The results showed a larger concentration variability for As, Cd and Hg than for Cu, Se and Zn. Some significant positive correlations were found for some elements among different tissues. (author). 15 refs, 22 figs, 4 tabs

  15. Implications of silica on biorefineries – interactions with organic material and mineral elements in grasses

    DEFF Research Database (Denmark)

    Le, Duy Michael; Sørensen, Hanne Risbjerg; Knudsen, Niels Ole

    2015-01-01

    their problems with silica in different ways. High pH and co-precipitation with mineral elements are some common ways of alleviating silica problems. Reviewing the literature for the fundamentals of silica revealed a complex chemistry that is not yet fully understood. Much is still to be learned about...

  16. Short outlines of books by Estonian authors : [annotations] / Rutt Hinrikus, Janika Kronberg

    Index Scriptorium Estoniae

    Hinrikus, Rutt, 1946-

    1998-01-01

    Laretei, Käbi. Eksiil; Toona, Elin. Lotukata; Park, Eeva. Naeru õpilane; Luik, Viivi. Inimese kapike; Laaman, Ilona. Vesi ahjus; Viiding, Juhan (Üdi, Jüri). Kogutud luuletused; Paju, Juhan. Katkenud romaan; Paju, Juhan. Hõõguv rist; Estonian short stories / toim. Kajar Pruul ja Darlene Reddaway; Traat, Mats. Kartaago kiirrong; Kauksi Ülle. Säng; Kross, Jaan. Paigallend; Puhvel, Madli. Symbol of dawn; Kaplinski, Jaan. Võimaluste võimalikkus; Kaplinski, Jaan. Usk on uskmatus

  17. Estonian Perceptions of Security: Not Only About Russia and the Refugees

    OpenAIRE

    Veebel Viljar; Ploom Illimar

    2016-01-01

    The current study focuses on the Estonian perceptions of security and on the defence situation both globally and locally. The dynamic results of the public opinion surveys on security risks conducted in Estonia over the last 10 years (2006-2016) will be presented. In addition, to understand whether some of the security risks could be over- or underestimated in Estonia, these results will be compared with the views expressed recently by the World Economic Forum, particularly the Global Risks R...

  18. Assessment of the Estonian Research Development Technology and Innovation Funding System

    OpenAIRE

    Nedeva, Maria; Georghiou, Luke

    2003-01-01

    The objectives of the assessment of the RDTI funding system in Estonia as specified by the Terms of Reference are as follows: 1) to conduct a review of the current R&D funding system in Estonia; 2) to review the objectives of the Estonian R&D Strategy 2002-2006; 3) to review best practice in R&D funding elsewhere; and 4) to propose an efficient, transparent and accountable R&D funding system.

  19. The origin and evolution of chondrites recorded in the elemental and isotopic compositions of their macromolecular organic matter

    Science.gov (United States)

    Alexander, C. M. O.'D.; Fogel, M.; Yabuta, H.; Cody, G. D.

    2007-09-01

    Extraterrestrial organic matter in meteorites potentially retains a unique record of synthesis and chemical/thermal modification by parent body, nebular and even presolar processes. In a survey of the elemental and isotopic compositions of insoluble organic matter (IOM) from 75 carbonaceous, ordinary and enstatite chondrites, we find dramatic variations within and between chondrite classes. There is no evidence that these variations correlate with the time and/or location of chondrite formation, or with any primary petrologic or bulk compositional features that are associated with nebular processes (e.g., chondrule and volatile trace element abundances). Nor is there evidence for the formation of the IOM by Fischer-Tropsch-Type synthesis in the nebula or in the parent bodies. The elemental variations are consistent with thermal maturation and/or oxidation of a common precursor. For reasons that are unclear, there are large variations in isotopic composition within and between chondrite classes that do not correlate in a simple way with elemental composition or petrologic type. Nevertheless, because of the pattern of elemental variations with petrologic type and the lack of any correlation with the primary features of the chondrite classes, at present the most likely explanation is that all IOM compositional variations are the result of parent body processing of a common precursor. If correct, the range of isotopic compositions within and between chondrite classes implies that the IOM is composed of several isotopically distinct components whose relative stability varied with parent body conditions. The most primitive IOM is found in the CR chondrites and Bells (CM2). Isotopically, the IOM from these meteorites resembles the IOM in interplanetary dust particles. Chemically, their IOM resembles the CHON particles of comet Halley. Despite the large isotopic anomalies in the IOM from these meteorites, it is uncertain whether the IOM formed in the interstellar medium or

  20. Is Estonian oil shale beneficial in the future?

    International Nuclear Information System (INIS)

    Reinsalu, Enno

    1998-01-01

    Oil shale mining production reached its maximum level of 31.35·10 6 tonnes per year in 1980. After the eighties there was a steady decline in mining. The first scientific prognoses of the inescapable decrease in oil shale mining were published in 1988. According to this, the Estonian oil shale industry would vanish in the third decade of the next century. From the beginning of the nineties, the consumption and export of electricity have dropped in Estonia. The minimum level of oil shale mining was 13.5·10 6 tonnes per year. This occurred in 1994/1995. Some increase in consumption of electric power and oil shale began at the end of 1995. Oil shale processing began to increase gradually in 1993. Oil shale is the most important fuel in Estonia today. In 1997, oil shale provided 76% of Estonia's primary energy supply and accounted for 57% of its economic value. Oil shale is the cheapest fuel in Estonia. Nowadays, oil shale provides an essential part of the fuel supply in Estonia because it is considerably cheaper than other fuels. Oil shale costs EEK 12.16 per G J. At the same time, coal costs EEK 23.41 per G J and peat costs EEK 14.80 per G J (year 1997). There are three important customers of oil shale: the electric power company Eesti Energia, the oil processing company Kiviter and the factory Kunda Nordic Cement. In 1995, the power company utilised 81% of the oil shale mass and 77% of its heating value. The state energy policy inhibits increases in the oil shale price even though the mining infrastructure is decaying. Government price policies subside oil shale processing. The energy of oil shale processing is 1.9 times cheaper than the heating value of raw oil shale for power stations. It could be considered as a state subsidisation of oil and cement export at the expense of electricity. The subsidy assigned to oil processing was of EEK 124·10 6 and to the cement industry of EEK 8.4·10 6 in year 1997 (based on heating value). State regulation of prices and

  1. Elemental and stable isotopic approaches for studying the organic and inorganic carbon components in natural samples

    International Nuclear Information System (INIS)

    Helie, J-F

    2009-01-01

    The carbon cycle is an important part of major biogeochemical cycles. Many techniques may be used to characterize carbon amounts and sources in the environment. Here we first review the most popular techniques for the determination of organic and inorganic carbon concentrations. Decarbonatation techniques are also reviewed in details since it is often an important part of organic carbon analysis. The second part of this paper addresses the use of carbon stable isotopes to characterize organic carbon sources and processes in the environment. An overview of general stable isotopes background and terminology is given as well as the most popular analytical techniques.

  2. Impact of rice cultivar and organ on elemental composition of phytoliths and the release of bio-available silicon

    Directory of Open Access Journals (Sweden)

    Zimin eLi

    2014-10-01

    Full Text Available The continental bio-cycling of silicon (Si plays a key role in global Si cycle and as such partly controls global carbon (C budget through nutrition of marine and terrestrial biota, accumulation of phytolith-occluded organic carbon (PhytOC and weathering of silicate minerals. Despite the key role of elemental composition of phytoliths on their solubility in soils, the impact of plant cultivar and organ on the elemental composition of phytoliths in Si high-accumulator plants, such as rice (Oryza sativa is not yet fully understood. Here we show that rice cultivar significantly impacts the elemental composition of phytoliths (Si, Al, Fe and C in different organs of the shoot system (grains, sheath, leaf and stem. The amount of occluded OC within phytoliths is affected by contents of Si, Al and Fe in plants, while independent of the element composition of phytoliths. Our data document, for different cultivars, higher bio-available Si release from phytoliths of leaves and sheaths, which are characterized by higher enrichment with Al and Fe (i.e., lower Si/Al and Si/Fe ratios, compared to grains and stems. We indicate that phytolith solubility in soils may be controlled by rice cultivar and type of organs. Our results highlight that the role of the morphology, the hydration rate and the chemical composition in the solubility of phytoliths and the kinetic release of Si in soil solution needs to be studied further. This is central to a better understanding of the impact of soil amendment with different plant organs and cultivars on soil OC stock and on the delivery of dissolved Si as we show that sheath and leaf rice organs are both characterized by higher content of OC occluded in phytolith and higher phytolith solubility compared to grains and stems. Our study shows the importance of studying the impact of the agro-management on the evolution of sinks and sources of Si and C in soils used for Si-high accumulator plants.

  3. [Scale of organizational learning in schools. Organizational learning is a key element for the development of organizations].

    Science.gov (United States)

    López, Verónica; Ahumada, Luis; Olivares, Rodrigo; González, Alvaro

    2012-05-01

    Organizational learning is a key element for the development of organizations. School organizations are not exempt from this challenge and they currently face a highly dynamic and demanding context of education policies that emphasize the school's ability to learn. Thus, research on organizational learning in educational contexts requires valid instruments that are sensitive to the specifics of schools as organizations. In this study, we adapted and validated a scale of organizational learning in a sample of 119 Chilean municipal schools (N= 1,545). The results suggest a structural model made up of three factors: culture of learning, strategic clarity, and group learning. These factors predicted dimensions of educational achievement, as measured through the National Assessment System of Educational Achievement (SNED). Results are discussed in view of the literature on school improvement.

  4. HIV testing and counselling in Estonian prisons, 2012 to 2013: aims, processes and impacts.

    Science.gov (United States)

    Kivimets, K; Uuskula, A

    2014-11-27

    We present data from an observational cohort study on human immunodeficiency virus (HIV) prevention and control measures in prisons in Estonia to assess the potential for HIV transmission in this setting. HIV testing and retesting data from the Estonian prison health department were used to estimate HIV prevalence and incidence in prison. Since 2002, voluntary HIV counselling and testing has routinely been offered to all prisoners and has been part of the new prisoners health check. At the end of 2012, there were 3,289 prisoners in Estonia, including 170 women: 28.5% were drug users and 15.6% were infected with HIV. Of the HIV-positive inmates, 8.3% were newly diagnosed on prison entry. In 2012, 4,387 HIV tests (including retests) were performed in Estonian prisons. Among 1,756 initially HIV-negative prisoners who were in prison for more than one year and therefore tested for HIV twice within 12 months (at entry and annual testing), one new HIV infection was detected, an incidence of 0.067 per 100 person-years (95% confidence interval (CI): 0.025–5.572). This analysis indicates low risk of HIV transmission in Estonian prisons. Implementation of HIV management interventions could impact positively on the health of prisoners and the communities to which they return.

  5. Estonian folk traditional experiences on natural anticancer remedies: from past to the future.

    Science.gov (United States)

    Sak, Katrin; Jürisoo, Kadi; Raal, Ain

    2014-07-01

    Despite diagnostic and therapeutic advancements, the burden of cancer is still increasing worldwide. Toxicity of current chemotherapeutics to normal cells and their resistance to tumor cells highlights the urgent need for new drugs with minimal adverse side effects. The use of natural anticancer agents has entered into the area of cancer research and increased efforts are being made to isolate bioactive products from medicinal plants. To lead the search for plants with potential cytotoxic activity, ethnopharmacological knowledge can give a great contribution. Therefore, the attention of this review is devoted to the natural remedies traditionally used for the cancer treatment by Estonian people over a period of almost 150 years. Two massive databases, the first one stored in the Estonian Folklore Archives and the second one in the electronic database HERBA ( http://herba.folklore.ee/ ), containing altogether more than 30 000 ethnomedicinal texts were systematically reviewed to compile data about the Estonian folk traditional experiences on natural anticancer remedies. As a result, 44 different plants with potential anticancer properties were elicited, 5 of which [Angelica sylvestris L. (Apiaceae), Anthemis tinctoria L. (Asteraceae), Pinus sylvestris L. (Pinaceae), Sorbus aucuparia L. (Rosaceae), and Prunus padus L. (Rosaceae)] have not been previously described with respect to their tumoricidal activities in the scientific literature, suggesting thus the potential herbal materials for further investigations of natural anticancer compounds.

  6. Comparison of knowledge, attitudes and behaviour regarding smoking among Estonian and Finnish physicians.

    Science.gov (United States)

    Pärna, Kersti; Rahu, Kaja; Barengo, Noël C; Rahu, Mati; Sandström, Patrick H; Jormanainen, Vesa J; Myllykangas, Markku T

    2005-01-01

    To compare smoking behaviour, attitudes and opinions towards smoking and smoking cessation among Estonian and Finnish physicians. A cross-sectional postal survey using a self-administered questionnaire was carried out among 2,480 Estonian and 2,075 Finnish physicians. Daily smoking prevalence was higher among Estonian physicians than among their Finnish counterparts in both male (18.6% and 6.7%) and female (6.6% and 3.6%). Compared to Estonia, physicians in Finland more often agreed that smoking is very harmful to their health, that trying to convince people to stop smoking is their responsibility and that smoking prevention should be part of the normal and special training of health professionals. In both countries, non-smoking physicians held more unfavourable attitudes towards smoking than those who were smoking. Physicians' own smoking patterns and quitting behaviour are important because physicians serve as models for their patients and play a key role in the reinforcement of smoke-free health facilities. These results remain a challenge to medical educators, especially in Estonia. Estonia needs to improve medical education in terms of motivating physicians to ask about the smoking patterns of their patients and of training medical students and resident physicians to counsel their patients to stop smoking.

  7. Cancer incidence and thyroid disease among Estonian Chernobyl clean-up workers

    Energy Technology Data Exchange (ETDEWEB)

    Auvinen, A; Salomaa, S [eds.; Radiation and Nuclear Safety Authority, Helsinki (Finland); Rahu, M; Veidebaum, T; Tekkel, M [eds.; Inst. of Experimental and Clinical Medicine, Tallinn (Estonia); Hakulinen, T [ed.; Finnish Cancer Registry, Helsinki (Finland); Boice, Jr, J D [ed.; Int. Epidemiology Inst., MD (United States)

    1998-09-01

    The report describes the development and summarizes the results of the project Cancer incidence and thyroid disease among Estonian Chernobyl clean-up workers. One of the goals of the report is to give research protocols and questionnaires for researchers involved in other studies. Eight previously published articles are also included summarizing the results. The development of the collaboration work of the project is described in the introduction of the report. Epidemiological methods are described in an article complemented by the protocol and English version of the questionnaire administered to all cleanup workers, as well as the data collection form of the thyroid study. The results from biological biodosimetry using both glycophorin A and FISH methods have shown that the radiation doses received by the Chernobyl cleanup workers were relatively low. Thyroid nodularity was not associated with any radiation exposure characteristic in the thyroid screening study. Estonian Chernobyl cleanup workers were followed up for cancer incidence through the Estonian Cancer Registry. No cases of leukemia or thyroid cancer were observed by the end of 1993. It is too early to observe possible effect on other types of cancer. However, mortality from suicides was increased compared with general population. Further follow-up and the extension to other Baltic countries in the future will undoubtedly strengthen the study. There are also plans for future projects covering areas from psychosocial factors to radiation biology

  8. Recent advances in organic one-dimensional composite materials: design, construction, and photonic elements for information processing.

    Science.gov (United States)

    Yan, Yongli; Zhang, Chuang; Yao, Jiannian; Zhao, Yong Sheng

    2013-07-19

    Many recent activities in the use of one-dimensional nanostructures as photonic elements for optical information processing are explained by huge advantages that photonic circuits possess over traditional silicon-based electronic ones in bandwidth, heat dissipation, and resistance to electromagnetic wave interference. Organic materials are a promising candidate to support these optical-related applications, as they combine the properties of plastics with broad spectral tunability, high optical cross-section, easy fabrication, as well as low cost. Their outstanding compatibility allows organic composite structures which are made of two or more kinds of materials combined together, showing great superiority to single-component materials due to the introduced interactions among multiple constituents, such as energy transfer, electron transfer, exciton coupling, etc. The easy processability of organic 1D crystalline heterostructures enables a fine topological control of both composition and geometry, which offsets the intrinsic deficiencies of individual material. At the same time, the strong exciton-photon coupling and exciton-exciton interaction impart the excellent confinement of photons in organic microstructures, thus light can be manipulated according to our intention to realize specific functions. These collective properties indicate a potential utility of organic heterogeneous material for miniaturized photonic circuitry. Herein, focus is given on recent advances of 1D organic crystalline heterostructures, with special emphasis on the novel design, controllable construction, diverse performance, as well as wide applications in isolated photonic elements for integration. It is proposed that the highly coupled, hybrid optical networks would be an important material basis towards the creation of on-chip optical information processing. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Nonvolatile Memory Elements Based on the Intercalation of Organic Molecules Inside Carbon Nanotubes

    Science.gov (United States)

    Meunier, Vincent; Kalinin, Sergei V.; Sumpter, Bobby G.

    2007-02-01

    We propose a novel class of nonvolatile memory elements based on the modification of the transport properties of a conducting carbon nanotube by the presence of an encapsulated molecule. The guest molecule has two stable orientational positions relative to the nanotube that correspond to conducting and nonconducting states. The mechanism, governed by a local gating effect of the molecule on the electronic properties of the nanotube host, is studied using density functional theory. The mechanisms of reversible reading and writing of information are illustrated with a F4TCNQ molecule encapsulated inside a metallic carbon nanotube. Our results suggest that this new type of nonvolatile memory element is robust, fatigue-free, and can operate at room temperature.

  10. Organic tracer-based source analysis of PM2.5 organic and elemental carbon: A case study at Dongguan in the Pearl River Delta, China

    Science.gov (United States)

    Wang, Qiong Qiong; Huang, X. H. Hilda; Zhang, Ting; Zhang, Qingyan; Feng, Yongming; Yuan, Zibing; Wu, Dui; Lau, Alexis K. H.; Yu, Jian Zhen

    2015-10-01

    Organic carbon (OC) and elemental carbon (EC) are major constituents of PM2.5 and their source apportionment remains a challenging task due to the great diversity of their sources and lack of source-specific tracer data. In this work, sources of OC and EC are investigated using positive matrix factorization (PMF) analysis of PM2.5 chemical composition data, including major ions, OC, EC, elements, and organic molecular source markers, for a set of 156 filter samples collected over three years from 2010 to 2012 at Dongguan in the Pearl River Delta, China. The key organic tracers include levoglucosan, mannosan, hopanes, C27-C33n-alkanes, and polycyclic aromatic hydrocarbons (PAHs). Using these species as input for the PMF model, nine factors were resolved. Among them, biomass burning and coal combustion were significant sources contributing 15-17% of OC and 24-30% and 34-35% of EC, respectively. Industrial emissions and ship emissions, identified through their characteristic metal signatures, contributed 16-24% and 7-8% of OC and 8-11% and 16-17% of EC, respectively. Vehicle exhaust was a less significant source, accounting for 3-4% of OC and 5-8% of EC. Secondary OC, taken to be the sum of OC present in secondary sulfate and nitrate formation source factors, made up 27-36% of OC. Plastic burning, identified through 1,3,5-triphenylbenzene as a tracer, was a less important source for OC(≤4%) and EC (5-10%), but a significant source for PAHs at this site. The utility of organic source tracers was demonstrated by comparing PMF runs with different combinations of organic tracers removed from the input species list. Levoglucosan and mannosan were important additions to distinguish biomass burning from coal combustion by reducing collinearity among source profiles. Inclusion of hopanes and 1,3,5-triphenylbenzene was found to be necessary in resolving the less significant sources vehicle exhaust and plastic burning. Inclusion of C27-C33n-alkanes and PAHs can influence the

  11. Field trial on glucose-induced insulin and metabolite responses in Estonian Holstein and Estonian Red dairy cows in two herds

    Directory of Open Access Journals (Sweden)

    Kaart Tanel

    2010-01-01

    Full Text Available Abstract Background Insulin secretion and tissue sensitivity to insulin is considered to be one of the factors controlling lipid metabolism post partum. The objective of this study was to compare glucose-induced blood insulin and metabolite responses in Estonian Holstein (EH, n = 14 and Estonian Red (ER, n = 14 cows. Methods The study was carried out using the glucose tolerance test (GTT performed at 31 ± 1.9 days post partum during negative energy balance. Blood samples were obtained at -15, -5, 5, 10, 20, 30, 40, 50 and 60 min relative to infusion of 0.15 g/kg BW glucose and analysed for glucose, insulin, triglycerides (TG, non-esterified fatty acids (NEFA, cholesterol and β-hydroxybutyrate (BHB. Applying the MIXED Procedure with the SAS System the basal concentration of cholesterol, and basal concentration and concentrations at post-infusion time points for other metabolites, area under the curve (AUC for glucose and insulin, clearance rate (CR for glucose, and maximum increase from basal concentration for glucose and insulin were compared between breeds. Results There was a breed effect on blood NEFA (P P P P P P th min nadir (P th min postinfusion (P Conclusion Our results imply that glucose-induced changes in insulin concentration and metabolite responses to insulin differ between EH and ER dairy cows.

  12. Sensing element for detection of polar organic vapours on the base of polyaniline-composite - Effect of substrate surface area

    International Nuclear Information System (INIS)

    Olejnik, Robert; Babar, Dipak Gorakh; Slobodian, Petr; Matyas, Jiri

    2016-01-01

    Conductive polymer polyaniline (PANI) was synthesized by oxidative polymerization of aniline hydrochloride as a source of aniline and ammonium persulfate as an oxidation agent. The polymerization process is relatively easy and cheap. The reaction was carried out in presence of polymer substrate, in our case polyethylene terephthalate (PET) as a representative of smooth surface substrate and polyvinylidenfluoride (PVDF) nanofibers membrane as a representative of porous substrate. Both these substrates were covered by polyaniline (PANI) and used as a sensing element for organic vapors detection. The detection was made by measuring and the record of the change of resistivity during adsorption and desorption of saturated vapors. The result shows that sensitivity decreases with increasing polarity of chosen solvent in order N,N- Dimethylformamide (DMF), N,N-Dimethylacetamide (DMAc) and Dimethyl sulfoxide (DMSO). The PANI base sensing element on PVDF substrate improves sensitivity, selectivity and it also has good reversibility and repeatability. (paper)

  13. Structural optimisation of a high speed Organic Rankine Cycle generator using a genetic algorithm and a finite element method

    Energy Technology Data Exchange (ETDEWEB)

    Palko, S. [Machines Division, ABB industry Oy, Helsinki (Finland)

    1997-12-31

    The aim in this work is to design a 250 kW high speed asynchronous generator using a genetic algorithm and a finite element method for Organic Rankine Cycle. The characteristics of the induction motors are evaluated using two-dimensional finite element method (FEM) The movement of the rotor and the non-linearity of the iron is included. In numerical field problems it is possible to find several local extreme for an optimisation problem, and therefore the algorithm has to be capable of determining relevant changes, and to avoid trapping to a local minimum. In this work the electromagnetic (EM) losses at the rated point are minimised. The optimisation includes the air gap region. Parallel computing is applied to speed up optimisation. (orig.) 2 refs.

  14. Differences between elemental composition of orange juices and leaves from organic and conventional production systems

    International Nuclear Information System (INIS)

    Turra, C.; Fernandes, E.A.N.; Bacchi, M.A.; Tagliaferro, F.S.; Franca, E.J.

    2006-01-01

    A comprehensive sampling of organic and conventional oranges was carried out in Bebedouro, an important citrus producing region of Brazil. The soils, leaves and fruits of the variety Valencia (Citrus sinensis [L.] Osbeck) budded on Rangpur lime (Citrus limonia Osbeck) were analyzed. The chemical characterization was accomplished by instrumental neutron activation analysis (INAA). Indications for a difference between organic and conventional orange juices and leaves were obtained by applying univariate and multivariate statistical analysis. There were differences between samples for Br, Co, Cs, La and Rb from both systems. (author)

  15. Organic Carbon and Trace Element Cycling in a River-Dominated Tidal Coastal Wetland System (Tampa Bay, FL, USA)

    Science.gov (United States)

    Moyer, R. P.; Smoak, J. M.; Engelhart, S. E.; Powell, C. E.; Chappel, A. R.; Gerlach, M. J.; Kemp, A.; Breithaupt, J. L.

    2016-02-01

    Tampa Bay is the largest open water, river-fed estuary in Florida (USA), and is characterized by the presence of both mangrove and salt marsh ecosystems. Both coastal wetland systems, and small rivers such as the ones draining into Tampa Bay have historically been underestimated in terms of their role in the global carbon and elemental cycles. Climate change and sea-level rise (SLR) are major threats in Tampa Bay and stand to disrupt hydrologic cycles, compromising sediment accumulation and the rate of organic carbon (OC) burial. This study evaluates organic carbon content, sediment accumulation, and carbon burial rates in salt marsh and mangrove ecosystems, along with measurements of fluxes of dissolved OC (DOC) and trace elements in the water column of the Little Manatee River (LMR) in Tampa Bay. The characterization of OC and trace elements in tidal rivers and estuaries is critical for quantitatively constraining these systems in local-to-regional scale biogeochemical budgets, and provide insight into biogeochemical processes occurring with the estuary and adjacent tidal wetlands. Material fluxes of DOC and trace elements were tied to discharge irrespective of season, and the estuarine habitats removed 15-65% of DOC prior to export to Tampa Bay and the Gulf of Mexico. Thus, material is available for cycling and burial within marsh and mangrove peats, however, LMR mangrove peats have higher OC content and burial rates than adjacent salt marsh peats. Sedimentary accretion rates in LMR marshes are not currently keeping pace with SLR, thus furthering the rapid marsh-to-mangrove conversions that have been seen in Tampa Bay over the past half-century. Additionally, wetlands in Tampa Bay tend to have a lower rate of carbon burial than other Florida tidal wetlands, demonstrating their high sensitivity to climate change and SLR.

  16. Molecular composition of recycled organic wastes, as determined by solid-state {sup 13}C NMR and elemental analyses

    Energy Technology Data Exchange (ETDEWEB)

    Eldridge, S.M., E-mail: simon.eldridge@dpi.nsw.gov.au [Environmental Futures Centre, School of Environment, Griffith University, Nathan, QLD 4111 (Australia); NSW Department of Primary Industries, Bruxner Highway, Wollongbar, NSW 2477 (Australia); Chen, C.R. [Environmental Futures Centre, School of Environment, Griffith University, Nathan, QLD 4111 (Australia); Xu, Z.H. [Environmental Futures Centre, School of Biomolecular and Physical Sciences, Griffith University, Nathan, QLD 4111 (Australia); Nelson, P.N. [School of Earth and Environmental Sciences, James Cook University, Cairns, QLD 4870 (Australia); Boyd, S.E. [Environmental Futures Centre, School of Biomolecular and Physical Sciences, Griffith University, Nathan, QLD 4111 (Australia); Meszaros, I. [Formerly NSW Department of Primary Industries, Richmond, NSW 2753 (Australia); Chan, K.Y. [Graduate School of Environment, Macquarie University, North Ryde, NSW 2109 (Australia); Formerly NSW Department of Primary Industries, Richmond, NSW 2753 (Australia)

    2013-11-15

    Highlights: • Model estimated the molecular C components well for most RO wastes. • Molecular nature of organic matter in RO wastes varied widely. • Molecular composition by NMR modelling preferable to extraction techniques. • Some model shortcomings in estimating molecular composition of biochars. • Waste molecular composition important for carbon/nutrient outcomes in soil. - Abstract: Using solid state {sup 13}C NMR data and elemental composition in a molecular mixing model, we estimated the molecular components of the organic matter in 16 recycled organic (RO) wastes representative of the major materials generated in the Sydney basin area. Close correspondence was found between the measured NMR signal intensities and those predicted by the model for all RO wastes except for poultry manure char. Molecular nature of the organic matter differed widely between the RO wastes. As a proportion of organic C, carbohydrate C ranged from 0.07 to 0.63, protein C from <0.01 to 0.66, lignin C from <0.01 to 0.31, aliphatic C from 0.09 to 0.73, carbonyl C from 0.02 to 0.23, and char C from 0 to 0.45. This method is considered preferable to techniques involving imprecise extraction methods for RO wastes. Molecular composition data has great potential as a predictor of RO waste soil carbon and nutrient outcomes.

  17. Molecular composition of recycled organic wastes, as determined by solid-state 13C NMR and elemental analyses

    International Nuclear Information System (INIS)

    Eldridge, S.M.; Chen, C.R.; Xu, Z.H.; Nelson, P.N.; Boyd, S.E.; Meszaros, I.; Chan, K.Y.

    2013-01-01

    Highlights: • Model estimated the molecular C components well for most RO wastes. • Molecular nature of organic matter in RO wastes varied widely. • Molecular composition by NMR modelling preferable to extraction techniques. • Some model shortcomings in estimating molecular composition of biochars. • Waste molecular composition important for carbon/nutrient outcomes in soil. - Abstract: Using solid state 13 C NMR data and elemental composition in a molecular mixing model, we estimated the molecular components of the organic matter in 16 recycled organic (RO) wastes representative of the major materials generated in the Sydney basin area. Close correspondence was found between the measured NMR signal intensities and those predicted by the model for all RO wastes except for poultry manure char. Molecular nature of the organic matter differed widely between the RO wastes. As a proportion of organic C, carbohydrate C ranged from 0.07 to 0.63, protein C from <0.01 to 0.66, lignin C from <0.01 to 0.31, aliphatic C from 0.09 to 0.73, carbonyl C from 0.02 to 0.23, and char C from 0 to 0.45. This method is considered preferable to techniques involving imprecise extraction methods for RO wastes. Molecular composition data has great potential as a predictor of RO waste soil carbon and nutrient outcomes

  18. Toxicologically important trace elements and organic compounds investigated in size-fractionated urban particulate matter collected near the Prague highway.

    Science.gov (United States)

    Sysalová, Jiřina; Sýkorová, Ivana; Havelcová, Martina; Száková, Jiřina; Trejtnarová, Hana; Kotlík, Bohumil

    2012-10-15

    Urban particulate matter was collected in the most exposed area of Prague, near a busy highway, in order to provide petrographic and chemical characterization useful for health impact assessment in that locality or other applications. Samples were collected from filters of the air conditioning system in two years, 2009 and 2010, and sieved into four grain-size fractions: 0.507-0.119 mm, 0.119-0.063 mm, origin and their morphology were studied by optical and electron microscopy. Organic solvent extracts of the samples were analyzed using gas chromatography to compare the organic compound distribution in fractions. Only slight differences between 2009 and 2010 years are visible. The relatively high extractable part of most investigated elements confirms mobility and potential availability to organisms. The changes can be recognized in the petrographic and organic composition in samples from both years, which were likely the result of various inputs of source materials. Specific organic marker compounds indicate contribution from fossil fuels, plant materials and bacteria. Copyright © 2012 Elsevier B.V. All rights reserved.

  19. Classification of trace elements in tissues from organic and conventional French pig production.

    Science.gov (United States)

    Parinet, Julien; Royer, Eric; Saint-Hilaire, Mailie; Chafey, Claude; Noël, Laurent; Minvielle, Brice; Dervilly-Pinel, Gaud; Engel, Erwan; Guérin, Thierry

    2018-07-01

    This study assesses the impact of the farming system on the levels of copper, zinc, arsenic, cadmium, lead and mercury in pig tissues from three types of production (Organic (n = 28), Label Rouge (n = 12) and Conventional (n = 30)) randomly sampled in different slaughterhouses. All the concentrations were below regulatory limits. In muscles, Cu, Zn and As were measured at slightly higher levels in organic samples but no differences between organic and Label Rouge was observed. Livers from conventional and Label Rouge pig farms exhibited higher Zn and Cd contents than the organic ones, probably due to different practice in zinc or phytase supplementation of fattening diets. Principal component analysis indicated a correlation between Cu and As concentrations in liver and carcass weight, and between Zn and Cd liver levels and lean meat percentage. The linear discriminant analysis succeeded in predicting the farming process on the basis of the lean meat percentage and the liver Cd level. Copyright © 2018 Elsevier Ltd. All rights reserved.

  20. Vision change in a governmental R&D organization : The pioneering legacy as an enduring element

    NARCIS (Netherlands)

    Landau, Dana; Drori, Israel; Porras, Jerry

    The present research demonstrates how a defense R&D organization wishing to deal effectively with a changing reality developed a vision that accommodated somewhat contradictory sets of aspirations and goals: the old and nationalistic together with the new, economically motivated, and market

  1. The study of the trace element in organisms by neutron activation analysis, 1

    International Nuclear Information System (INIS)

    Shinogi, Masaki; Murai, Yasuko; Mori, Itsuhiko; Takeuchi, Takayuki.

    1974-01-01

    Examinations were made on optimal experimental conditions for instrumental determination of various elements in cannabis by neutron activation analysis, without any radiochemical separation, and the following conditions were found to be useful. Irradiation samples to be used are about 300 mg of the leaves or stem bark, and about 100 mg of the root. For soil sample, about 50 mg is used for the determination of short half-life nuclides and about 300 mg for long half-life nuclides. For short half-life nuclides, the samples are irradiated for 1 min, activity is measured for 200 sec after a decay of 3 min, and for 400 sec after a decay of 10 min. For long half-life nuclides, the samples are irradiated for 60 min and the activites are measured for 4 K sec after 1 week and for 10 K sec after 1 month. Use of supersonic waves is also convenient for cleansing of the samples. Thirty-five kinds of interesting elements were determined by this method from cannabis cultivated in Maizuru area. (auth.)

  2. Ingestion and organ content of trace elements of importance in radiological protection. Country report, Bangladesh

    International Nuclear Information System (INIS)

    2000-01-01

    The main elements of radiological importance to be studied under the CRP are Strontium, Cesium, Iodine, Uranium and Thorium. Total diets for daily intake of human consisting of eleven common food samples were collected from the local market of Dhaka, the central part of the Country. The food samples were collected on market basket basis and according to the statistical dietary survey for the people of age ranging from 20-50 years. The number of frequency for the sample collection for the total daily diets was eleven, five for man and six for women. After collection, the food items were washed, cleaned and dried at room temperature and weighed and then cooked as is normally eaten in the Bangladeshi style. The cooked samples were then homogenized using commercial blender, mortar and pestle. The samples were then dried at 100-110 deg. C in an electric oven. Before drying a pail of the cooked samples was kept separately in polyethylene bottles with screw caps for iodine determination. Percentage of moisture content of these samples was calculated which varied from max 55.5% to min 40.4%. Ile dried samples were then kept in polyethylene bottles and tight with screw caps and then stored in refrigerator for elemental analysis. (author)

  3. Four years of highly time resolved measurements of elemental and organic carbon at a rural background site in Central Europe

    Czech Academy of Sciences Publication Activity Database

    Mbengue, Saliou; Fusek, M.; Schwarz, J.; Vodička, P.; Holubová Šmejkalová, Adéla; Holoubek, Ivan

    2018-01-01

    Roč. 182, jun (2018), s. 335-346 ISSN 1352-2310 R&D Projects: GA MŠk(CZ) LM2015037; GA MŠk(CZ) LO1415; GA MŠk(CZ) EF16_013/0001315 EU Projects: European Commission(XE) 654109 - ACTRIS-2 Institutional support: RVO:67179843 Keywords : Air masses origin * Censored data * Elemental organic carbon * OC/EC ratio * Rural background site * Variability Subject RIV: CE - Biochemistry OBOR OECD: Biochemistry and molecular biology Impact factor: 3.629, year: 2016

  4. Four Years of Highly Time Resolved Measurements of Elemental and Organic Carbon at a Rural Background Site in Central Europe.

    Czech Academy of Sciences Publication Activity Database

    Mbengue, S.; Fusek, M.; Schwarz, Jaroslav; Vodička, Petr; Holubová Šmejkalová, Adéla; Holoubek, I.

    2018-01-01

    Roč. 182, June 2018 (2018), s. 335-346 ISSN 1352-2310 R&D Projects: GA MŠk(CZ) LM2015037; GA MŠk(CZ) EF16_013/0001315 EU Projects: European Commission(XE) 654109 - ACTRIS-2 Institutional support: RVO:67985858 Keywords : elemental - organic carbon * OC/EC ratio * rural background site * air masses origin * censored data * variability OBOR OECD: Environmental sciences (social aspects to be 5.7) Impact factor: 3.629, year: 2016

  5. Selected elements and organic chemicals in bed sediment and fish tissue of the Tualatin River basin, Oregon, 1992-96

    Science.gov (United States)

    Bonn, Bernadine A.

    1999-01-01

    A variety of elements and organic compounds have entered the environment as a result of human activities. Such substances find their way to aquatic sediments from direct discharges to waterways, atmospheric emissions, and runoff. Some of these chemicals are known to harm fish or wildlife, either by direct toxicity, by reducing viability, or by limiting reproductive success. In aquatic systems, sediments become the eventual sink for most of these chemicals. Analyzing the sediments provides a first step in a chemical inventory that can lead to an assessment of potential biological impacts (Kennicutt and others, 1994).

  6. Organic radionuclide compounds in soil solutions and their role in elements absorption in plants

    International Nuclear Information System (INIS)

    Agapkin, G.I.; Tikhomirov, F.A.

    1991-01-01

    The results of reference experiments with introduction of radioactive labels ( 35 S, 45 Ca, 59 Fe, 85 , 125 I) into 5 types of climatophytic soils by the method of radiogel-chromatography allow to ascertain that in soil solutions 59 Fe and 125 I incorporate completely and 35 S, 45 Ca and 85 Sr incorporate by 60-90 % into the composition of one of three fractions of organic compounds with molecular masses of 4x10 2 -6x10 4 . It is shown that significant variations between soils in the absorption of such radionuclides as 4 5 Ca, 58 Fe, 85 Sr and 125 I are celated to a different degree of their transport into soil solutions as well as to differencies in their distribution by molecular-mass fractions of water-soluble organic compounds

  7. Synthesis and adsorption behaviour of some organic and inorganic sorbents for some hazardous toxic elements

    International Nuclear Information System (INIS)

    El-Naggar, I.M.; Abou-Mesalam, M.M.; Abdel-Hamid, M.M.; Shady, S.A.; Aly, H.F.

    2000-01-01

    Poly (acrylamide-acrylic acid ) -zirconium phosphate p(AM-AA) -Zr p is a new organic resin and can be synthesized by gamma radiation induced polymerization of acrylic acid (AA) in the presence of poly acrylamide (PAM) using a template polymerization technique in the presence of zirconium oxychloride and then soaking in phosphoric acid. The obtained polymer shows an excellent thermal and chemical stabilities, high capacities measurements in addition to high selectivity behaviour to some hazardous heavy metals. In a comparative study for the previous organic resin, P(AM-AA)-Zr P with cerium(IV) antimonate (Ce Sb) and titanium (IV) antimonate (Ti Sb) as inorganic ion exchangers we can concluded that both of Ce Sb and Ti Sb have a greater selectivities to the hazardous heavy metals as compared with p(AM-AA) Zr P whereas the later has a higher capacity than Ce Sb and Ti Sb

  8. Arabidopsis and the Genetic Potential for the Phytoremediation of Toxic Elemental and Organic Pollutants

    OpenAIRE

    Cobbett, Christopher S.; Meagher, Richard B.

    2002-01-01

    In a process called phytoremediation, plants can be used to extract, detoxify, and/or sequester toxic pollutants from soil, water, and air. Phytoremediation may become an essential tool in cleaning the environment and reducing human and animal exposure to potential carcinogens and other toxins. Arabidopsis has provided useful information about the genetic, physiological, and biochemical mechanisms behind phytoremediation, and it is an excellent model genetic organism to test foreign gene expr...

  9. CORPORATE VOLUNTEERING AS AN ELEMENT OF SUSTAINABLE DEVELOPMENT OF THE ORGANIZATION

    Directory of Open Access Journals (Sweden)

    Natalia Ivanovna Gorlova

    2018-01-01

    Full Text Available Purpose. The article is devoted to the topic of development of corporate volunteering, which is topical for Russian society. The subject of the analysis is corporate volunteering in Russia and its impact on the sustainable development of the organization. Corporate volunteering is seen at the intersection of the interests of the company, employees and the local community. The aim of the research is a theoretical analysis of modern practices of corporate volunteer activity as a factor of sustainable development of the organization. Methodology. Within the framework of the article, using the method of comparison and grouping, we analyzed and studied the materials of the latest international and Russian studies based on expert opinions from business, government, civil society on this phenomenon. Results. The results of the work consist in the fact that the authors grouped and summarized the motivational attitudes of participants in the corporate volunteer movement, presented practical recommendations on the formation of a system for supporting corporate volunteering, and showed the relationship between the organization’s sustainable development and corporate volunteering. Practical implications. The practical significance of the study is that its conclusions and recommendations can be used in the organization of corporate volunteering in Russian companies.

  10. Pilk ingliskeelse kirjanduse tõlgetele 18. sajandi lõpust 20. sajandi algusveerandini / A Look at Estonian Translations of English Literature from the late 18th Century to the Early 20th Century

    Directory of Open Access Journals (Sweden)

    Krista Mits

    2012-06-01

    Full Text Available The aim of this article is to provide an overview of translations of English literature into Estonian between 1779 and 1917. There is an attempt to analyse the texts by describing them on the basis of, or in their departure from, a text or texts that chronologically and logically precede them. The discussion includes the nature of the transfer and the changes that have been made to the text, either because they existed in the source or mediating text or because of the expectations or requirements in the receptor, i.e. Estonian culture. The translated texts are seen in their historical-cultural context. For the analysis, a corpus of translated texts – religious, fiction, drama and non-fiction (published in a book form was compiled. The general orientation of Estonia until the 1880s was to the German cultural sphere. So the first translations of English literature were made via a mediating language, which was German. English Puritan writers were introduced by the Pietist missionaries with the aim of spreading their teachings in the second half of the 18th century. At about the same time the narrative element was introduced into stories with religious content. Some internationally popular stories, e.g. the Inkle and Yarico story, later robinsonades, stories of slavery and plant at ion life, as well as Amer ican Indian st or ies wer e also t r anslat ed fr om Ger man. However, until  1875  ver  y  few  translations  of  English  literature  into  E stonian were  published.  The  last quarter of the 19th century saw an explosion in literary production: there was a substantial increase  both  in  the  number  of  translations  of  English  literature  into  E stonian  as  well  as diversification of genres. This continued into the first decade of the 20th  centur y,  when  the sociopolitical situation in Estonia changed. In addition, books came to be translated directly from  English,  although  many  translations

  11. Elements of automata theory and the theory of Markov chains. [Self-organizing control systems

    Energy Technology Data Exchange (ETDEWEB)

    Lind, M

    1975-03-01

    Selected topics from automata theory and the theory of Markov chains are treated. In particular, finite-memory automata are discussed in detail, and the results are used to formulate an automation model of a class of continuous systems. Stochastic automata are introduced as a natural generalization of the deterministic automaton. Markov chains are shown to be closely related to stochastic automata. Results from Markov chain theory are thereby directly applicable to analysis of stochastic automata. This report provides the theoretical foundation for the investigation in Riso Report No. 315 of a class of self-organizing control systems. (25 figures) (auth)

  12. Classifying organic materials by oxygen-to-carbon elemental ratio to predict the activation regime of Cloud Condensation Nuclei (CCN

    Directory of Open Access Journals (Sweden)

    M. Kuwata

    2013-05-01

    Full Text Available The governing highly soluble, slightly soluble, or insoluble activation regime of organic compounds as cloud condensation nuclei (CCN was examined as a function of oxygen-to-carbon elemental ratio (O : C. New data were collected for adipic, pimelic, suberic, azelaic, and pinonic acids. Secondary organic materials (SOMs produced by α-pinene ozonolysis and isoprene photo-oxidation were also included in the analysis. The saturation concentrations C of the organic compounds in aqueous solutions served as the key parameter for delineating regimes of CCN activation, and the values of C were tightly correlated to the O : C ratios. The highly soluble, slightly soluble, and insoluble regimes of CCN activation were found to correspond to ranges of [O : C] > 0.6, 0.2 < [O : C] < 0.6, and [O : C] < 0.2, respectively. These classifications were evaluated against CCN activation data of isoprene-derived SOM (O : C = 0.69–0.72 and α-pinene-derived SOM (O : C = 0.38–0.48. Isoprene-derived SOM had highly soluble activation behavior, consistent with its high O : C ratio. For α-pinene-derived SOM, although CCN activation can be modeled as a highly soluble mechanism, this behavior was not predicted by the O : C ratio, for which a slightly soluble mechanism was anticipated. Complexity in chemical composition, resulting in continuous water uptake and the absence of a deliquescence transition that can thermodynamically limit CCN activation, might explain the difference in the behavior of α-pinene-derived SOM compared to that of pure organic compounds. The present results suggest that atmospheric particles dominated by hydrocarbon-like organic components do not activate (i.e., insoluble regime whereas those dominated by oxygenated organic components activate (i.e., highly soluble regime for typical atmospheric cloud life cycles.

  13. Capture of elemental and organic iodine from dilute gas streams by silver-exchanged mordenite

    Energy Technology Data Exchange (ETDEWEB)

    Bruffey, S.H.; Jubin, R.T.; Jordan, J.A. [Oak Ridge National Laboratory, 1 Bethel Valley Road, Oak Ridge, TN 37831 (United States)

    2016-07-01

    The treatment of off-gas streams arising from reprocessing of used nuclear fuel (UNF) is an area of active study by the U.S. Department of Energy. Such off-gas streams contain volatile fission products, including long-lived {sup 129}I. Although {sup 129}I is released into the off-gas at multiple points within the chemical reprocessing flowsheet, previous research has focused on removal from the dissolver off-gas stream (DOG). The DOG is expected to contain up to 98% of iodine in UNF at ppm levels within the stream. Other off-gas streams will also contain iodine but at substantially lower concentrations. Recent work has shown that compliance with U.S. regulations will likely require capture of iodine from these dilute streams in addition to capture from DOG. In particular, the vessel off-gas (VOG) stream is expected to contain 1-3% of the total iodine inventory at ppb concentrations. A review of literature also indicates that the speciation of iodine in the VOG stream will differ from that of the DOG, with the DOG containing primarily I{sub 2} and the VOG containing a mixture of I{sub 2} and organic iodine species. Silver-exchanged mordenite (AgZ) has been identified for use in the removal of iodine from off-gas streams. It is an effective capture material for I{sub 2} at the concentrations expected in the DOG, but little is known about its performance in gas streams that may contain both I{sub 2} and organic iodides at very dilute concentrations. The experiments to be described were designed to separately characterize the adsorption of I{sub 2} and methyl iodide on AgZ through extended duration testing. Simulated vessel off-gases containing low levels of either I{sub 2} or methyl iodide were contacted with AgZ sorbent beds for up to four months. Through the use of sorbent beds in series and varied sampling times, key parameters such as adsorption rate, decontamination factor, and performance over time could be determined for the capture of each species by AgZ. This

  14. Tracking transformation processes of organic micropollutants in aquatic environments using multi-element isotope fractionation analysis

    International Nuclear Information System (INIS)

    Hofstetter, Thomas B.; Bolotin, Jakov; Skarpeli-Liati, Marita; Wijker, Reto; Kurt, Zohre; Nishino, Shirley F.; Spain, Jim C.

    2011-01-01

    The quantitative description of enzymatic or abiotic transformations of man-made organic micropollutants in rivers, lakes, and groundwaters is one of the major challenges associated with the risk assessment of water resource contamination. Compound-specific isotope analysis enables one to identify (bio)degradation pathways based on changes in the contaminants' stable isotope ratios even if multiple reactive and non-reactive processes cause concentrations to decrease. Here, we investigated how the magnitude and variability of isotope fractionation in some priority pollutants is determined by the kinetics and mechanisms of important enzymatic and abiotic redox reactions. For nitroaromatic compounds and substituted anilines, we illustrate that competing transformation pathways can be assessed via trends of N and C isotope signatures.

  15. [Affinity of the elements in group VI of the periodic table to tumors and organs].

    Science.gov (United States)

    Ando, A; Hisada, K; Ando, I

    1976-10-01

    In order to investigate the tumor affinity radioisotopes, chromium (51Cr), molybdenum (99Mo), tungsten (181W), selenium (75Se) and tellurium (127mTe)--the elements of group VI in the periodic table--were examined, using the rats which were subcutaneously transplanted with Yoshida sarcoma. Seven preprarations, sodium chromate (Na251CrO4), chromium chloride (51CrCl3), normal ammonium molybdate ((NH4)299MoO7), sodium tungstate (Na2181WO4), sodium selenate (Na275SeO4), sodium selenite (Na275SeO3) and tellurous acid (H2127mTeO3) were injected intravenously to each group of tumor bearing rats. These rats were sacrificed at various periods after injection of each preparation: 3 hours, 24 hours and 48 hours in all preparations. The radioactivities of the tumor, blood, muscle, liver, kidney and spleen were measured by a well-type scintillation counter, and retention values (in every tissue including the tumor) were calculated in percent of administered dose per g-tissue weight. All of seven preparations did not have any affinity for malignant tumor. Na251CrO4 and H2127mTeO3 had some affinity for the kidneys, and Na275SeO3 had some affinity for the liver. Na2181WO4 and (NH4)299MoO4 disappeared very rapidly from the blood and soft tissue, and about seventy-five percent of radioactivity was excreted in urine within first 3 hours.

  16. Finite element simulation of interactions between pelvic organs: predictive model of the prostate motion in the context of radiotherapy.

    Science.gov (United States)

    Boubaker, Mohamed Bader; Haboussi, Mohamed; Ganghoffer, Jean-François; Aletti, Pierre

    2009-08-25

    The setting up of predictive models of the pelvic organ motion and deformation may prove an efficient tool in the framework of prostate cancer radiotherapy, in order to deliver doses more accurately and efficiently to the clinical target volume (CTV). A finite element (FE) model of the prostate, rectum and bladder motion has been developed, investigating more specifically the influence of the rectum and bladder repletions on the gland motion. The required organ geometries are obtained after processing the computed tomography (CT) images, using specific softwares. Due to their structural characteristics, a 3D shell discretization is adopted for the rectum and the bladder, whereas a volume discretization is adopted for the prostate. As for the mechanical behavior modelling, first order Ogden hyperelastic constitutive laws for both the rectum and bladder are identified. The prostate is comparatively considered as more rigid and is accordingly modelled as an elastic tissue undergoing small strains. A FE model is then created, accounting for boundary and contact conditions, internal and applied loadings being selected as close as possible to available anatomic data. The order of magnitude of the prostate motion predicted by the FE simulations is similar to the measurements done on a deceased person, accounting for the delineation errors, with a relative error around 8%. Differences are essentially due to uncertainties in the constitutive parameters, pointing towards the need for the setting up of direct measurement of the organs mechanical behavior.

  17. Uptake of dissolved organic carbon and trace elements by zebra mussels

    Science.gov (United States)

    Roditi, Hudson A.; Fisher, Nicholas S.; Sañudo-Wilhelmy, Sergio A.

    2000-09-01

    Zebra mussels (Dreissena polymorpha) are widespread and abundant in major freshwater ecosystems in North America, even though the phytoplankton food resources in some of these systems seem to be too low to sustain them. Because phytoplankton biomass is greatly depleted in ecosystems with large D. polymorpha populations and bacteria do not seem to be an important food source for this species, exploitation of alternative carbon sources may explain the unexpected success of D. polymorpha in such environments. Here we examine the possibility that absorption of dissolved organic carbon (DOC) from water could provide a nutritional supplement to zebra mussels. We find that mussels absorb 14C-labelled DOC produced by cultured diatoms with an efficiency of 0.23%; this indicates that DOC in natural waters could contribute up to 50% of the carbon demand of zebra mussels. We also find that zebra mussels absorb some dissolved metals that have been complexed by the DOM; although absorption of dissolved selenium was unaffected by DOC, absorption of dissolved cadmium, silver and mercury by the mussels increased 32-, 8.7- and 3.6-fold, respectively, in the presence of high-molecular-weight DOC.

  18. Atmospheric Deposition of Inorganic Elements and Organic Compounds at the Inlets of the Venice Lagoon

    Directory of Open Access Journals (Sweden)

    E. Morabito

    2014-01-01

    Full Text Available The Venice Lagoon is subjected to long-range transport of contaminants via aerosol from the near Po Valley. Moreover, it is an area with significant local anthropogenic emissions due to the industrial area of Porto Marghera, the urban centres, and the glass factories and with emissions by ships traffic within the Lagoon. Furthermore, since 2005, the Lagoon has also been affected by the construction of the MOSE (Modulo Sperimentale Elettromeccanico—Electromechanical Experimental Module mobile dams, as a barrier against the high tide. This work presents and discusses the results from chemical analyses of bulk depositions, carried out in different sites of the Venice Lagoon. Fluxes of pollutants were also statistically analysed on PCA with the aim of investigating the spatial variability of depositions and their correlation with precipitations. Fluxes of inorganic pollutants depend differently on precipitations, while organic compounds show a more seasonal trend. The statistical analysis showed that the site in the northern Lagoon has lower and almost homogeneous fluxes of pollutants, while the other sites registered more variable concentrations. The study also provided important information about the annual trend of pollutants and their evolution over a period of about five years, from 2005 to 2010.

  19. Trends in smoking behaviour among Estonian physicians in 1982-2014.

    Science.gov (United States)

    Pärna, Kersti; Põld, Mariliis; Ringmets, Inge

    2017-07-25

    Smoking surveys among physicians have proved useful in highlighting the importance of physicians as healthy life style exemplars and role models in tobacco control and smoking cessation. The aim of this study was to give an overview of smoking behaviour among Estonian physicians from 1982 to 2014. Three cross-sectional postal surveys using a self-administered questionnaire were carried out among all practising physicians in Estonia. The number of physicians participating in this study was 3786 in 1982, 2735 in 2002, and 2902 in 2014. Data analysis involved calculating the age-standardized prevalences of smoking, prevalences of smoking by age group and mean age of smoking initiation. A non-parametric test for trend was used to assess significant changes in smoking over time. Age-standardized prevalence of current smoking among men was 39.7% in 1982, 20.9% in 2002, and 14.3% in 2014 and among women 12.2%, 8.0%, and 5.2%, respectively (p smoking among men and women was in age groups under 35 (from 55.2% to 16.7% and from 16.7% to 2.8%, respectively) and 35-44 (from 47.1% to 8.3% and from 19.5% to 5.1%, respectively) (p smoking initiation decreased from 20.4 to 19.3 among men and from 24.5 to 20.4 among women over the study period. In 1982-2014, smoking prevalence among Estonian physicians declined substantially. This may influence the willingness of society to recognize the health consequences of smoking which could give a support to the decline of the smoking epidemic in the country. Differences between smoking among male and female physicians persisted over the study period, but mean age of smoking initiation decreased. A further decline in smoking among Estonian physicians should be encouraged by special efforts targeted at physicians.

  20. The treatment of lexical collocations in EFL coursebooks in the Estonian secondary school context

    Directory of Open Access Journals (Sweden)

    Liina Vassiljev

    2015-04-01

    Full Text Available The article investigates lexical collocations encountered in English as a Foreign Language (EFL instruction in Estonian upper secondary schools. This is achieved through a statistical analysis of collocations featuring in three coursebooks where the collocations found are analysed in terms of their type, frequency and usefulness index by studying them through an online language corpus (Collins Wordbanks Online. The coursebooks are systematically compared and contrasted relying upon the data gathered. The results of the study reveal that the frequency and range of lexical collocations in a language corpus have not been regarded as an essential criterion for their selection and practice by any of the coursebook authors under discussion.

  1. Estonian experience in establishing the national radiation protection infrastructure in the newly independent State

    International Nuclear Information System (INIS)

    Kalam, J.

    2001-01-01

    The Estonian Radiation Protection Centre (ERPC) was established on 4 January 1996 as the regulatory authority for radiation protection and safety of radiation sources. The report explains the ERPC's structure and its main functions and activities, and provides information on the regulations that have been approved or are planned to be adopted. Reference is made to radiological emergency preparedness and, in particular, to the status of development of the system of regulatory control by authorization and inspection of radiation practices in the country. (author)

  2. Poster 6: Influence of traces elements in the organic chemistry of upper atmosphere of Titan

    Science.gov (United States)

    Mathe, Christophe; Carrasco, Nathalie; Trainer, Melissa G.; Gautier, Thomas; Gavilan, Lisseth; Dubois, David; Li, Xiang

    2016-06-01

    In the upper atmosphere of Titan, complex chemistry leads to the formation of organic aerosols. Since the work of Khare et al. in 1984, several experiments investigated the formation of Titan aerosols, so called tholins, in the laboratory. It has been suggested that nitrogen-containing compounds may contribute significantly to the aerosols formation process. In this study, we focused on the influence of pyridine, the simplest nitrogenous aromatic hydrocarbon, on the chemistry of Titan's atmosphere and on aerosol formation. To assess the effect of pyridine on aerosol formation chemistry, we used two different experimental setups : a capacitively coupled radio-frequency (electronic impact), and a VUV Deuterium lamp (photochemistry) in a collaboration between LATMOS (Guyancourt) and NASA-GSFC (Greenbelt), respectively. Aerosols produced with both setups were first analyzed using a FTIR-ATR (Fourier Transform Infrared spectroscopy - Attenuated Total Reflection) with a spectral range of 4000-800 cm-1 to characterize their optical properties. Next the samples were analysed using a Bruker Autoflex Speed MALDI mass spectrometer with a m/z range up to 2000 Da in order to infer their composition. Infrared spectroscopy analysis showed that tholins produced with a nitrogen-methane gas mixture (95:5) and nitrogenpyridine gas mixture (99:250ppm) present very similar spectra features. Tholins produced with a mixture of nitrogenmethane-pyridine (99:1:250ppm) do not present aliphatic CH2 or CH3 vibrational signatures. This could indicate a cyclic polymerization by a pyridine skeleton. Mass spectrometry is still in progress to confirm this.

  3. Elemental and isotope behavior of macromolecular organic matter from CM chondrites during hydrous pyrolysis

    Science.gov (United States)

    Oba, Y.; Naraoka, H.

    2009-08-01

    A new insight into carbon and hydrogen isotope variations of insoluble organic matter (IOM) is provided from seven CM chondrites, including Murchison and six Antarctic meteorites (Y-791198, Y-793321, A-881280, A-881334, A-881458 and B-7904) as well as Murchison IOM residues after hydrous pyrolysis at 270-330 °C for 72 h. Isotopic compositions of bulk carbon (δ13Cbulk) and hydrogen (δD) of the seven IOMs vary widely, ranging from -15.1 to -7.6‰ and +133 to +986‰, respectively. Intramolecular carboxyl carbon (δ13CCOOH) is more enriched in 13C by 7.5 -11‰ than bulk carbon. After hydrous pyrolysis of Murchison IOM at 330 °C, H/C ratio, δ13Cbulk, δ13CCOOH, and δD values decrease by up to 0.31, 3.5‰, 5.5‰, and 961‰, respectively. The O/C ratio increases from 0.22 to 0.46 at 270 °C and to 0.25 at 300 °C, and decreases to 0.10 at 330 °C. δ13Cbulk- δD cross plot of Murchison IOM and its pyrolysis residues shows an isotopic sequence. Of the six Antarctic IOMs, A-881280, A-881458, Y-791198 and B-7904 lie on or near the isotopic sequence depending on the degree of hydrous and/or thermal alteration, while A-881334 and Y-793321 consist of another distinct isotope group. A δ13Cbulk-δ13CCOOH cross-plot of IOMs, including Murchison pyrolysis residues, has a positive correlation between them, implying that the oxidation process to produce carboxyls is similar among all IOMs. These isotope distributions reflect various degree of alteration on the meteorite parent bodies and/or difference in original isotopic compositions before the parent body processes.

  4. Application of neutron activation analysis to the study of the variations of the concentration of trace elements in various organs of rat as a function of age

    International Nuclear Information System (INIS)

    Maziere, B.; Loc'h, C.; Stulzaft, O.; Gaudry, A.; Comar, D.

    1976-01-01

    In order to know the normal distribution of trace elements in rats as accurately as possible, the composition of different organs and body tissues by neutron activation analysis was determined in animals from 15 days to 22 months old. The experiment conditions were described. Normal concentrations for more than 20 trace elements were obtained, some of them being less than a tenth of a part per billion. The experiment has shown that variations in elemental concentrations in terms of age were a general phenomenon and that for some elements a steady state is apparently never attained

  5. Post-irradiation examination of the first SAP clad UO{sub 2} fuel elements irradiated in the X-7 organic loop

    Energy Technology Data Exchange (ETDEWEB)

    MacDonald, R. D.; Aspila, K.

    1962-02-15

    Seven fuel elements composing the first in-reactor test at Chalk River of SAP sheathing were irradiated in the X-7 organic loop. Activity, denoting a fuel failure, was detected in the loop coolant immediately after reactor start up; the fuel string was consequently removed from the loop nine hours later. Leak tests disclosed that five of the seven elements were defective. Inspection of the specimens showed essentially no change in element dimensions. Practically no organic fouling film was observed on the surface of the SAP cladding; organic coolant was found inside four of the defective elements. The appearance of the UO{sub 2} fuel was consistent with the irradiation time and the heat ratings achieved during the test. (author)

  6. Geochemical and mineralogical investigation of uranium in multi-element contaminated, organic-rich subsurface sediment

    International Nuclear Information System (INIS)

    Qafoku, Nikolla P.; Gartman, Brandy N.; Kukkadapu, Ravi K.; Arey, Bruce W.; Williams, Kenneth H.; Mouser, Paula J.; Heald, Steve M.; Bargar, John R.; Janot, Noémie; Yabusaki, Steve; Long, Philip E.

    2014-01-01

    Highlights: • Subsurface naturally reduced zones (NRZ) contain U and other potential co-contaminants. • The NRZ has a remarkable assortment of chemically complex, potential U hosts. • Micron-scale, multi-contaminant areas were discovered in NRZ. • U(IV) occurs as biogenic UO 2 (82%), or biomass – bound monomeric U(IV) (18%). • NRZs may exhibit contaminant sink-source complex behavior. - Abstract: Subsurface regions of alluvial sediments characterized by an abundance of refractory or lignitic organic carbon compounds and reduced Fe and S bearing minerals, which are referred to as naturally reduced zones (NRZ), are present at the Integrated Field Research Challenge site in Rifle, CO (a former U mill site), and other contaminated subsurface sites. A study was conducted to demonstrate that the NRZ contains a variety of contaminants and unique minerals and potential contaminant hosts, investigate micron-scale spatial association of U with other co-contaminants, and determine solid phase-bounded U valence state and phase identity. The NRZ sediment had significant solid phase concentrations of U and other co-contaminants suggesting competing sorption reactions and complex temporal variations in dissolved contaminant concentrations in response to transient redox conditions, compared to single contaminant systems. The NRZ sediment had a remarkable assortment of potential contaminant hosts, such as Fe oxides, siderite, Fe(II) bearing clays, rare solids such as ZnS framboids and CuSe, and, potentially, chemically complex sulfides. Micron-scale inspections of the solid phase showed that U was spatially associated with other co-contaminants. High concentration, multi-contaminant, micron size (ca. 5–30 μm) areas of mainly U(IV) (53–100%) which occurred as biogenic UO 2 (82%), or biomass – bound monomeric U(IV) (18%), were discovered within the sediment matrix confirming that biotically induced reduction and subsequent sequestration of contaminant U(VI) via

  7. Development of treatment method for stillage residues of liquid radioactive wastes to remove organic substances and transuranium elements

    International Nuclear Information System (INIS)

    Rudenko, L.I.; Dzhuzha, O.V.; Khan, V.E.

    2008-01-01

    The paper presents the results of the study into the laws that govern the process of treating by oxidation the stillage residues of liquid radioactive wastes to remove organic compounds and transuranium elements with the use of hydrogen peroxide, potassium permanganate and subsequent ultra-filtration. The optimum oxidisation regime has been defined on the basis of this study to ensure that the initial dichromate oxidability of LRW's stillage residues decreases from 6,000-9,500 to 500-1,000 mg O/I, whereas the TUE activity associated with the key isotopes is reduced by 74-87 % for 238,239,240 Pu, by 94-95 % for 241 Am, and by 90-95 % for 244 Cm. The concentration of uranium decreases by 94-99 %. It is proposed to implement this method at the Chernobyl NPP site.

  8. The 1 MV multi-element AMS system for biomedical applications at the Netherlands Organization for Applied Scientific Research (TNO)

    Energy Technology Data Exchange (ETDEWEB)

    Klein, Matthias, E-mail: mklein@highvolteng.com [High Voltage Engineering Europa B.V., P.O. Box 99, 3800 AB Amersfoort (Netherlands); Vaes, W.H.J.; Fabriek, B.; Sandman, H. [TNO, P.O. Box 360, 3700 AJ Zeist (Netherlands); Mous, D.J.W.; Gottdang, A. [High Voltage Engineering Europa B.V., P.O. Box 99, 3800 AB Amersfoort (Netherlands)

    2013-01-15

    The Netherlands Organization for Applied Scientific Research (TNO) has installed a compact 1 MV multi-element AMS system manufactured by High Voltage Engineering Europa B.V., The Netherlands. TNO performs clinical research programs for pharmaceutical and innovative foods industry to obtain early pharmacokinetic data and to provide anti-osteoporotic efficacy data of new treatments. The AMS system will analyze carbon, iodine and calcium samples for this purpose. The first measurements on blank samples indicate background levels in the low 10{sup -12} for calcium and iodine, making the system well suited for these biomedical applications. Carbon blanks have been measured at low 10{sup -16}. For unattended, around-the-clock analysis, the system features the 200 sample version of the SO110 hybrid ion source and user friendly control software.

  9. Elemental Composition Analysis to Investigate NOx Effects on Secondary Organic Aerosol from α-Pinene Using Ultrahigh Resolution Mass Spectrometry

    Science.gov (United States)

    Lim, H. J.; Park, J. H.; Babar, Z.

    2015-12-01

    Secondary organic aerosol (SOA) accounts for 20-70% of atmospheric fine aerosol. NOx plays crucial roles in SOA formation and consequently affects the composition and yield of SOA. SOA component speciation is incomplete due to its complex composition of polar oxygenated and multifunctional species. In this study, ultrahigh resolution mass spectrometry (UHR MS) was applied to improve the understanding of NOx effects on biogenic SOA formation by identifying the elemental composition of SOA. Additional research aim was to investigate oligomer components that are considered as a driving force for SOA formation and growth. In this study α-pinene SOA from photochemical reaction was examined. SOA formation was performed in the absence and presence of NOx at dry condition (grant funded by the Korea government (MEST) (No. 2011-01350000).

  10. Changes in trace element concentration in hair and other organs in relation to disease and metal burden

    International Nuclear Information System (INIS)

    Wiesener, W.; Goerner, W.; Niese, S.

    1979-01-01

    With the help of reactor neutron activation analysis, the concentrations of F, Cl, Mn, Cu, Zn, Se, Ag, I and Au in hair and other organs of normal and diseased persons and of persons occupationally or otherwise exposed to high concentrations of certain elements have been determined. When necessary, before gamma spectrometry, 24 Na interference was removed by hydrated antimony pentoxide or the elements of interest were separated by an anion-exchange resin. Short-lived nuclides were determined by a short activation with the help of a pneumatic irradiation facility and automatic correction of deadtime and decay. The hair of welders was found to contain considerably more Mn than that of normal persons. The concentration of F in the hair of people working with F compounds was also enhanced. The amount of Au in the serum of patients treated with sodium-gold-thiosulphate was determined. Goitre patients showed a small increase of Se and a decrease of I in the hair. Patients with mammary carcinoma showed an increase of Cu, Zn and I. The Zn content of tumorous mammary tissue was many times higher than that of neighbouring tissue. Muscle tissue of rats with a Yoshida ascites sarcoma showed an enhanced content of Zn as well. The content of Mn, Cu and Zn in fatty livers decreases with increasing content of fat. (author)

  11. Thermal neutron activation analysis of essential and trace elements and organic constituents in Trikatu. An Ayurvedic formulation

    International Nuclear Information System (INIS)

    Choudhury, R.P.; Kumar, A.; Garg, A.N.; Reddy, A.V.R.

    2007-01-01

    Trikatu, an Ayurvedic formulation of three dried powder spices, ginger, black pepper and pipali in equal proportion is widely used to promote digestion, assimilation and bioavailibility of food. It works synergistically, and hence, is more effective than an equal amount of any of its three ingredients taken separately. Five different brands and its three constituents were analyzed for 31 elements by instrumental neutron activation analysis (INAA) using 5-minute and 6-hour thermal neutron irradiation followed by high-resolution γ-ray spectrometry. Heavy toxic metals Cd, Ni and Pb determined by atomic absorption spectrometry (AAS) were found below permissible limits. Most elements in different brands vary in a narrow range. Ginger is particularly enriched in Ca, Fe, Mg and Mn whereas black pepper is enriched in Cr, Se, P and Zn. Cu/Zn shows linear relationship (r = 0.92) with Cu whereas Fe and Mn exhibit inverse correlation (r = -0.89) in different brands. Hydro distillation of pipali yielded an essential oil whereby 10 organic constituents were identified by GC-MS. Also barbituric and tannic acids were isolated from the aqueous methanolic extract of pipali. (author)

  12. Parallel measurements of organic and elemental carbon dry (PM1, PM2.5) and wet (rain, snow, mixed) deposition into the Baltic Sea.

    Science.gov (United States)

    Witkowska, Agnieszka; Lewandowska, Anita; Falkowska, Lucyna M

    2016-03-15

    Parallel studies on organic and elemental carbon in PM1 and PM2.5 aerosols and in wet deposition in various forms of its occurrence were conducted in the urbanised coastal zone of the Baltic Sea. The carbon load introduced into the sea water was mainly affected by the form of precipitation. Dry deposition load of carbon was on average a few orders of magnitude smaller than wet deposition. The suspended organic carbon was more effectively removed from the air with rain than snow, while an inverse relationship was found for elemental carbon. However the highest flux of water insoluble organic carbon was recorded in precipitation of a mixed nature. The atmospheric cleaning of highly dissolved organic carbon was observed to be the most effective on the first day of precipitation, while the hydrophobic elemental carbon was removed more efficiently when the precipitation lasted longer than a day. Copyright © 2016 Elsevier Ltd. All rights reserved.

  13. The organization structure and regulatory elements of Chlamydomonas histone genes reveal features linking plant and animal genes.

    Science.gov (United States)

    Fabry, S; Müller, K; Lindauer, A; Park, P B; Cornelius, T; Schmitt, R

    1995-09-01

    The genome of the green alga Chlamydomonas reinhardtii contains approximately 15 gene clusters of the nucleosomal (or core) histone H2A, H2B, H3 and H4 genes and at least one histone H1 gene. Seven non-allelic histone gene loci were isolated from a genomic library, physically mapped, and the nucleotide sequences of three isotypes of each core histone gene species and one linked H1 gene determined. The core histone genes are organized in clusters of H2A-H2B and H3-H4 pairs, in which each gene pair shows outwardly divergent transcription from a short (< 300 bp) intercistronic region. These intercistronic regions contain typically conserved promoter elements, namely a TATA-box and the three motifs TGGCCAG-G(G/C)-CGAG, CGTTGACC and CGGTTG. Different from the genes of higher plants, but like those of animals and the related alga Volvox, the 3' untranslated regions contain no poly A signal, but a palindromic sequence (3' palindrome) essential for mRNA processing is present. One single H1 gene was found in close linkage to a H2A-H2B pair. The H1 upstream region contains the octameric promoter element GGTTGACC (also found upstream of the core histone genes) and two specific sequence motifs that are shared only with the Volvox H1 promoters. This suggests differential transcription of the H1 and the core histone genes. The H1 gene is interrupted by two introns. Unlike Volvox H3 genes, the three sequenced H3 isoforms are intron-free. Primer-directed PCR of genomic DNA demonstrated, however, that at least 8 of the about 15 H3 genes do contain one intron at a conserved position. In synchronized C. reinhardtii cells, H4 mRNA levels (representative of all core histone mRNAs) peak during cell division, suggesting strict replication-dependent gene control. The derived peptide sequences place C. reinhardtii core histones closer to plants than to animals, except that the H2A histones are more animal-like. The peptide sequence of histone H1 is closely related to the V. carteri VH1-II

  14. Exploring Constructivist Social Learning Practices in Aiding Russian-Speaking Teachers to Learn Estonian: An Action Research Approach

    Science.gov (United States)

    Kiilo, Tatjana; Kutsar, Dagmar

    2012-01-01

    Based on appreciative inquiry and threshold concepts from an intercultural learning perspective, the article makes insights into the constructivist social learning practice of Estonian language learning amongst Russian-speaking teachers in Estonia. The application of educational action research methodology, more specifically that of Bridget…

  15. Proficiency Assessment of Male Volleyball Teams of the 13-15-Year Age Group at Estonian Championships

    Science.gov (United States)

    Stamm, Meelis; Stamm, Raini; Koskel, Sade

    2008-01-01

    Study aim: Assessment of feasibility of using own computer software "Game" at competitions. Material and methods: The data were collected during Estonian championships in 2006 for male volleyball teams of the 13-15-years age group (n = 8). In all games, the performance of both teams was recorded in parallel with two computers. A total of…

  16. CORRELATION AMONG DAMAGES CAUSED BY YELLOW BEETLE, CLIMATOLOGICAL ELEMENTS AND PRODUCTION OF GUAVA ACCESSES GROWN IN ORGANIC SYSTEM

    Directory of Open Access Journals (Sweden)

    JULIANA ALTAFIN GALLI

    Full Text Available ABSTRACT The objective of this research was evaluate the damage caused by the yellow beetle on 85 guava accessions and correlations of the damage with the climatological elements and the production of fruit in an orchard of guava conducted in organic system. Ten leaves by access were analyzed containing the injury of insect attack. Each leaf had its foliar area measured by leaf area meter and, after obtaining the total area, the leaf was covered with duct tape, and measure again. The averages were compared by Scott-Knott test at 5% probability. The 15 accessions with highest average damage had the data submitted to the correlation with the minimum and maximum temperature, precipitation and relative humidity. The production was obtained by the number of fruits/plant. The damages are negatively correlated with the mean relative humidity of 7:00h (local time in the period of 14 days prior to the assessments, and negatively affect production. The accessions Saito, L4P16, Monte Alto Comum 1 and L5P19 are promising in organic agriculture, for presenting good production and minor damage to insect attack, when compared to others.

  17. Evolution in the block: common elements of 5S rDNA organization and evolutionary patterns in distant fish genera.

    Science.gov (United States)

    Campo, Daniel; García-Vázquez, Eva

    2012-01-01

    The 5S rDNA is organized in the genome as tandemly repeated copies of a structural unit composed of a coding sequence plus a nontranscribed spacer (NTS). The coding region is highly conserved in the evolution, whereas the NTS vary in both length and sequence. It has been proposed that 5S rRNA genes are members of a gene family that have arisen through concerted evolution. In this study, we describe the molecular organization and evolution of the 5S rDNA in the genera Lepidorhombus and Scophthalmus (Scophthalmidae) and compared it with already known 5S rDNA of the very different genera Merluccius (Merluccidae) and Salmo (Salmoninae), to identify common structural elements or patterns for understanding 5S rDNA evolution in fish. High intra- and interspecific diversity within the 5S rDNA family in all the genera can be explained by a combination of duplications, deletions, and transposition events. Sequence blocks with high similarity in all the 5S rDNA members across species were identified for the four studied genera, with evidences of intense gene conversion within noncoding regions. We propose a model to explain the evolution of the 5S rDNA, in which the evolutionary units are blocks of nucleotides rather than the entire sequences or single nucleotides. This model implies a "two-speed" evolution: slow within blocks (homogenized by recombination) and fast within the gene family (diversified by duplications and deletions).

  18. Tabud ja reeglid. Sissevaateid eesti laagriromaani / Taboos and Rules. Insights into Prison Camp Novels by Estonian Writers

    Directory of Open Access Journals (Sweden)

    Anneli Kõvamees

    2013-12-01

    Full Text Available The article concentrates on Estonian novels depicting Soviet prison camps in the 1940s and 1950s. The goal is to map themes, motifs and characteristics in such novels, concentrating on various taboos and rules in the prison camp environment. For a long time the Soviet prison camp theme was not publicly discussed in Estonia due to political reasons. Texts dealing with prison camps could appear in print only outside the Soviet Union; the way Estonians saw these historical events and hellish experiences were depicted mostly in exile novels. Most notable are the novels by Arved Viirlaid (b. 1922, e.g., Kes tappis Eerik Hormi? (Who Killed Eerik Horm? (1974, Surnud ei loe (The Dead do not Read (1975, Vaim ja ahelad (Mind and Chains (1961. Estonian prison camp novels can be seen as “the literature of testimony”, to use the term by Leona Toker. Dramatic historical events are written down to record the events and to show the inhumane nature of Soviet society. These records of the dramatic past follow certain patterns and create certain self- and hetero-images. A prison camp is a closed territory within a closed territory; prison camps can be seen as small models of Soviet society. Prison camp novels give a detailed view of the environment of the prison camp, its inhabitants and activities. Two central aspects are labour and food; the life of the prisoner whirls around these. The most important thing is to survive, which often leads to moral decline, e.g., stealing, cheating. However, there are lines Estonians do not cross, e.g., cannibalism or homosexual relationships with superiors. Estonians are always depicted as political prisoners (not common criminals and heterosexuals, while Russians are portrayed mainly as criminals and often also as homosexuals. Another important component of the image of the Estonians is their enterprising spirit and ability to manage even under very difficult conditions. Therefore, several oppositions can be identified, e

  19. Mental health and alcohol problems among Estonian cleanup workers 24 years after the Chernobyl accident.

    Science.gov (United States)

    Laidra, Kaia; Rahu, Kaja; Tekkel, Mare; Aluoja, Anu; Leinsalu, Mall

    2015-11-01

    To study the long-term mental health consequences of the 1986 Chernobyl nuclear accident among cleanup workers from Estonia. In 2010, 614 Estonian Chernobyl cleanup workers and 706 geographically and age-matched population-based controls completed a mail survey that included self-rated health, the Posttraumatic Stress Disorder Checklist (PCL), alcohol symptoms (AUDIT), and scales measuring depressive, anxiety, agoraphobia, fatigue, insomnia, and somatization symptoms. Respondents were dichotomized into high (top quartile) and low symptom groups on each measure. Logistic regression analysis detected significant differences between cleanup workers and controls on all measures even after adjustment for ethnicity, education, marital status, and employment status. The strongest difference was found for somatization, with cleanup workers being three times more likely than controls to score in the top quartile (OR = 3.28, 95% CI 2.39-4.52), whereas for alcohol problems the difference was half as large (OR = 1.52, 95% CI 1.16-1.99). Among cleanup workers, arrival at Chernobyl in 1986 (vs. later) was associated with sleep problems, somatization, and symptoms of agoraphobia. The toll of cleanup work was evident 24 years after the Chernobyl accident among Estonian cleanup workers indicating the need for focused mental health interventions.

  20. Radon in Estonian buildings. Establishment of a measurement system and obtained results

    International Nuclear Information System (INIS)

    Pahapill, L.; Rulkov, A.; Swedjemark, G.A.

    1996-12-01

    One purpose of this project was the establishment of a radon monitoring programme inside the state environmental monitoring programme. Another purpose was to investigate regions, expected to have high radon levels indoors. A new method for the long-term measurement of indoor radon was established and the staff for these measurements was trained. The results of the measurement can be used by Estonian decision-makers to work out rules and standards. There is no legislative act in the field of radiation in Estonian at this time. To summarize the results of the measurements we can say that indoor radon concentrations vary by region. The radon investigations must be continued to identify the risk areas and types of housing construction. The results of the state radon monitoring are provided to the municipalities, who advice the owners of planned new houses to select the right construction for the house. A new project will follow with an investigation of radon in randomly selected dwellings, training and equipment for radon measurement in soil, and general advice with regard to radon, as well as assistance in preparing information about radon. 7 refs, 5 figs

  1. Sustainable Soil Washing: Shredded Card Filtration of Potentially Toxic Elements after Leaching from Soil Using Organic Acid Solutions

    Science.gov (United States)

    Ash, Christopher; Drábek, Ondřej; Tejnecký, Václav; Jehlička, Jan; Michon, Ninon; Borůvka, Luboš

    2016-01-01

    Shredded card (SC) was assessed for use as a sorbent of potentially toxic elements (PTE) carried from contaminated soil in various leachates (oxalic acid, formic acid, CaCl2, water). We further assessed SC for retention of PTE, using acidified water (pH 3.4). Vertical columns and a peristaltic pump were used to leach PTE from soils (O and A/B horizons) before passing through SC. Sorption onto SC was studied by comparing leachates, and by monitoring total PTE contents on SC before and after leaching. SC buffers against acidic soil conditions that promote metals solubility; considerable increases in solution pH (+4.49) were observed. Greatest differences in solution PTE content after leaching with/without SC occurred for Pb. In oxalic acid, As, Cd, Pb showed a high level of sorption (25, 15, and 58x more of the respective PTE in leachates without SC). In formic acid, Pb sorption was highly efficient (219x more Pb in leachate without SC). In water, only Pb showed high sorption (191x more Pb in leachate without SC). In desorption experiments, release of PTE from SC varied according to the source of PTE (organic/mineral soil), and type of solvent used. Arsenic was the PTE most readily leached in desorption experiments. Low As sorption from water was followed by fast release (70% As released from SC). A high rate of Cd sorption from organic acid solutions was followed by strong retention (~12% Cd desorption). SC also retained Pb after sorption from water, with subsequent losses of ≤8.5% of total bound Pb. The proposed use of this material is for the filtration of PTE from extract solution following soil washing. Low-molecular-mass organic acids offer a less destructive, biodegradable alternative to strong inorganic acids for soil washing. PMID:26900684

  2. Sustainable Soil Washing: Shredded Card Filtration of Potentially Toxic Elements after Leaching from Soil Using Organic Acid Solutions.

    Directory of Open Access Journals (Sweden)

    Christopher Ash

    Full Text Available Shredded card (SC was assessed for use as a sorbent of potentially toxic elements (PTE carried from contaminated soil in various leachates (oxalic acid, formic acid, CaCl2, water. We further assessed SC for retention of PTE, using acidified water (pH 3.4. Vertical columns and a peristaltic pump were used to leach PTE from soils (O and A/B horizons before passing through SC. Sorption onto SC was studied by comparing leachates, and by monitoring total PTE contents on SC before and after leaching. SC buffers against acidic soil conditions that promote metals solubility; considerable increases in solution pH (+4.49 were observed. Greatest differences in solution PTE content after leaching with/without SC occurred for Pb. In oxalic acid, As, Cd, Pb showed a high level of sorption (25, 15, and 58x more of the respective PTE in leachates without SC. In formic acid, Pb sorption was highly efficient (219x more Pb in leachate without SC. In water, only Pb showed high sorption (191x more Pb in leachate without SC. In desorption experiments, release of PTE from SC varied according to the source of PTE (organic/mineral soil, and type of solvent used. Arsenic was the PTE most readily leached in desorption experiments. Low As sorption from water was followed by fast release (70% As released from SC. A high rate of Cd sorption from organic acid solutions was followed by strong retention (~12% Cd desorption. SC also retained Pb after sorption from water, with subsequent losses of ≤8.5% of total bound Pb. The proposed use of this material is for the filtration of PTE from extract solution following soil washing. Low-molecular-mass organic acids offer a less destructive, biodegradable alternative to strong inorganic acids for soil washing.

  3. Vene kirjandus venestusaja eesti koolides. Russian Literature in the Estonian Schools of the Russification Era

    Directory of Open Access Journals (Sweden)

    Ülle Pärli

    2012-04-01

    Full Text Available This article aims to give an overview of literary instruction in schools of the russification era at the beginning of the 20th century in Estonia; this was likewise the curriculum of literary study offered to the generation of educated youth which included the Young Estonians. Based on official documents, archival materials, and memoirs, and through analyses of anthologies, literary histories, and teaching methods in use at the time, we attempt to reconstruct the outlines of literary reading and requirements for students in various types of schools. When, as a result of school reform, Russian became the language of instruction; lessons in Russian became central in the curriculum, alongside the word of God; selections from Russian literature were read in the original language. In the lower grades, teaching was by the so-called ”natural method”, intended to guarantee swift achievement of fluency in ”living Russian language”; this was later replaced by systematic textual analysis, which distinguished between belles lettres and other types of texts. However, the study of literature was always subordinated to the goals of language instruction. In institutions of secondary education, study of Russian literature was separate from language instruction. Indeed, Russian literature was the only literature systematically studied in high schools (though one must keep in mind that not all schools completely followed the official program. Private schools were especially noticeable for their greater freedom, though all of them had to take general curriculum directives into account. Reading of literary texts connected with other languages thus had to remain almost purely illustrative. In view of the above, in the upper grades of elementary school and high school, students obtained a thorough introduction to the Russian classics. According to the official school curriculum, Russian literary history ended with Nikolai Gogol. Attempts were made to ignore

  4. Identity and Othering in Past and Present: Representations of the Soviet Era in Estonian Post-Soviet Textbooks

    Directory of Open Access Journals (Sweden)

    Katrin Kello

    2018-02-01

    Full Text Available This paper analyses representations of the ‘core Soviet era’ (1945-1985 in Estonian post-Soviet history textbooks (1989-2016. Attitudes towards the Soviet system have been a rich resource for identity building, and hence a powerful political tool across the whole of the post-Soviet block. Based on an analysis of sections about the Soviet era in Estonia in 21 textbooks, the paper takes a look at how textbooks reflect broader processes of social meaning making, identity building and othering after a profound social and political turn. In 1989 and during the early 1990s, perspectives and narratives in Estonian history textbooks were closely related to social memory and national politics, enacting a specific social representation of the Soviet era that dominated the Estonian-speaking public space during the 1990s. The Soviet era, Russia and local Russians became the main Others for Estonia and Estonians. Over time, public discourse has diversified. The national curriculum and textbooks, however, still maintain the canon that formed in 1990s and thus reflect earlier sentiments. Apart from the increasing salience of Soviet-era daily life in more recent textbooks, the thematic choices and emphases have changed little since the 1990s. Therefore, even if the style of writing has ‘cooled down’, issues of identity preservation, resistance and accommodation, together with a saliently negative representation of wrongdoings by the Soviet system, still prevail. On the one hand, this testifies to the resilience of an established tradition in the textbook genre in general. On the other hand, it reflects the dominance of an ethnocentric tradition in Estonian history textbook writing. The paper discusses the implications of these findings for interethnic relations in Estonia.

  5. [Relationship between groundwater quality index of nutrition element and organic matter in riparian zone and water quality in river].

    Science.gov (United States)

    Hua-Shan, Xu; Tong-Qian, Zhao; Hong-Q, Meng; Zong-Xue, Xu; Chao-Hon, Ma

    2011-04-01

    bank, which is the efficient microbial nitrogen purification unit, nitrification-denitrification is intensive. Farm manure is an important source of organic matter loss at the artificial wetlands. Floodplain has sandy soil texture, with high infiltration capacity and low water and fertilizer conservation ability. Such features are prone for the loss of surface soil nutrition and organic matter if agricultural activities taken place in these areas change the land use of wetlands and apply extensive fertilizer. The infiltrated nutrition elements and organic matter can pollute the groundwater and the river. Compared with the losses of nutrition element and organic matter caused by surface runoff, the infiltrated process is even more prominent. As typical floodplain groundwater-river ecotone, the area between 50 m and 200 m from the river bank is a momentous pollution purification unit. Rational protection for this region is critical for the conservation of water quality in the river and groundwater.

  6. Phytoplasma infection in tomato is associated with re-organization of plasma membrane, ER stacks, and actin filaments in sieve elements

    OpenAIRE

    Buxa, Stefanie V; Degola, Francesca; Polizzotto, Rachele; de Marco, Federica; Loschi, Alberto; Kogel, Karl-Heinz; di Toppi, Luigi Sanità; van Bel, Aart J. E.; Musetti, Rita

    2015-01-01

    Phytoplasmas, biotrophic wall-less prokaryotes, only reside in sieve elements of their host plants. The essentials of the intimate interaction between phytoplasmas and their hosts are poorly understood, which calls for research on potential ultrastructural modifications. We investigated modifications of the sieve-element ultrastructure induced in tomato plants by ‘Candidatus Phytoplasma solani,’ the pathogen associated with the stolbur disease. Phytoplasma infection induces a drastic re-organ...

  7. Assessment of N and P in organic fertilizer using the missing element technique and a microbial bioassay

    International Nuclear Information System (INIS)

    Salas, E.; Ramirez, C.

    2002-01-01

    Assessment of N and P in organic fertilizers using the missing element technique and a microbial bioassay.Through a greenhouse bioassay, using sorghum (Sorghum vulgare) as a test plant, and a microbial assay the availability of N and P in 6 substrates was determined, namely: soil alone and in combination with several organic amendments 10% W/W of chicken manure (CM), compost (C), bocashi (B), vermicompost (V) and coffe hulls (Br). In the microbial assay a complete randomized design with 6 replicates was used; the microbial biomass (BM) was determined 2 days after the glucose amendment of each treatment. In both bioassays a 2 X 2 factorial (N and P fertilization) was establish and the following combinations resulted: +N, +P, +P+N and -P-N (control). For the greenhouse experiment, a complete randomized design with 4 replicates was used. Above-ground plant material of sorghum was harvested 34 days after showing to determine plant dry weight (PS) and content of N and P. Both assays showed a response to the soil amendment with N and P. Soil treatments with CM, C and B showed the highest values of PS and BM. Soil treatment with CM amended with N, P or both did not showed a response in PS or BM, in C and B there was a response to N addition but not to P. In treatments with V and Br, the lowest values for PS and BM were obtained, and there was a growth response to N and P. Both bioassays were able to pinpoint N and P defficiencies in the soil as well in some of the mixtures of soil with organic amendments. A high correlation was encountered between the greenhouse assay and the microbial bioassay (r= 0.86, P=0.0001). Therefore, the microbial bioassay can be a cheaper alternative to the plant bioassay not only to evaluate the nutritional quality of compost but also to identify nutrient deficiencies in soils as well as in substrates amended with organic fertilizers. (Author) [es

  8. Phytoplasma infection in tomato is associated with re-organization of plasma membrane, ER stacks, and actin filaments in sieve elements.

    Science.gov (United States)

    Buxa, Stefanie V; Degola, Francesca; Polizzotto, Rachele; De Marco, Federica; Loschi, Alberto; Kogel, Karl-Heinz; di Toppi, Luigi Sanità; van Bel, Aart J E; Musetti, Rita

    2015-01-01

    Phytoplasmas, biotrophic wall-less prokaryotes, only reside in sieve elements of their host plants. The essentials of the intimate interaction between phytoplasmas and their hosts are poorly understood, which calls for research on potential ultrastructural modifications. We investigated modifications of the sieve-element ultrastructure induced in tomato plants by 'Candidatus Phytoplasma solani,' the pathogen associated with the stolbur disease. Phytoplasma infection induces a drastic re-organization of sieve-element substructures including changes in plasma membrane surface and distortion of the sieve-element reticulum. Observations of healthy and stolbur-diseased plants provided evidence for the emergence of structural links between sieve-element plasma membrane and phytoplasmas. One-sided actin aggregates on the phytoplasma surface also inferred a connection between phytoplasma and sieve-element cytoskeleton. Actin filaments displaced from the sieve-element mictoplasm to the surface of the phytoplasmas in infected sieve elements. Western blot analysis revealed a decrease of actin and an increase of ER-resident chaperone luminal binding protein (BiP) in midribs of phytoplasma-infected plants. Collectively, the studies provided novel insights into ultrastructural responses of host sieve elements to phloem-restricted prokaryotes.

  9. Elemental and Organic Carbon Measurements at the Kosetice Observatory, Czech Republic within EU Projects in 2009-2014

    Science.gov (United States)

    Vana, M.; Holubova, A.; Cech, J.

    2016-12-01

    Carbonaceous aerosol (TC) is a complex mixture of many organics (OC fraction) and elemental carbon (EC). EC is a product of anthropogenic activities, especially incomplete combustion of fossil fuels by transport, heating, power plants, wood and biomass burning and agriculture activities. EC could have larger health impact than other PM constituents (Cassee et al., 2013). Carbonaceous aerosols also play an important role in climate change (Boucher et al., 2013). Kosetice Observatory, operated by the Czech Hydrometeorological Institute has been carrying out long-term air quality monitoring at the background scale the Czech Republic since 1988. Regular EC-OC measurement has been implementing within EU-projects EUSAAR and ACTRIS since 2009. Sampling frequency is every 6th day in fraction PM2,5 on 2 quartz-fibre filters. Since October 2011 the sampling on filters has been implementing behind the denuder catching the organic vapor. Amount of OC on back quartz fiber filter represents positive artifact by measurement without denuder and negative artifact by measurements with denuder. The analytical method is thermal-optical analysis. The samples are analyzed in CHMI Central Laboratories in Prague-Libuš using EC-OC Sunset Lab Dual Analyzer. Charring correction is made by laser transmission monitoring. Slightly decreasing tendency of EC-OC was found in the period under review (2009-2014). The mean annual concentration of total carbon (TC) in PM2,5 was 3,73 µg.m-3. The figure for elemental carbon (0,5 µg.m-3) represents the mean annual ratio of 13% on TC. EC-OC concentrations follow an annual course that reflects their emission levels, i.e. with maximums in winter and minimums in summer. The seasonal variation of EC/TC ratio ranges between 9,6 (summer) - 14,2% (winter). Mean TC ratio on PM2,5 total mass in the period under review was 29%, the highest ratios reached 50%. EC participated on PM2,5 total mass by 3,5% in average. 3D trajectories were used for sector analysis of

  10. Polish and Estonian Economic Competitiveness. A Comparative Study

    Directory of Open Access Journals (Sweden)

    Anna Kowalska

    2007-10-01

    Full Text Available The starting point of the study has been a survey of indices developed by international economic organizations. Such indices tend to encompass a number of qualitative/quantitative variables relating to economic viability, e.g. economic liberties, budgetary balance, judiciary, technical sophistication, social factors and innovation. Basing on the aforementioned data, the study has focused upon the comparison of both countries competitive stances and permitted the formulation of certain economic policy guidelines with regard to Poland, which has underperformed Estonia in most of the rankings.

  11. Murine homeobox-containing gene, Msx-1: analysis of genomic organization, promoter structure, and potential autoregulatory cis-acting elements.

    Science.gov (United States)

    Kuzuoka, M; Takahashi, T; Guron, C; Raghow, R

    1994-05-01

    Detailed molecular organization of the coding and upstream regulatory regions of the murine homeodomain-containing gene, Msx-1, is reported. The protein-encoding portion of the gene is contained in two exons, 590 and 1214 bp in length, separated by a 2107-bp intron; the homeodomain is located in the second exon. The two-exon organization of the murine Msx-1 gene resembles a number of other homeodomain-containing genes. The 5'-(GTAAGT) and 3'-(CCCTAG) splicing junctions and the mRNA polyadenylation signal (UAUAA) of the murine Msx-1 gene are also characteristic of other vertebrate genes. By nuclease protection and primer extension assays, the start of transcription of the Msx-1 gene was located 256 bp upstream of the first AUG. Computer analysis of the promoter proximal 1280-bp sequence revealed a number of potentially important cis-regulatory sequences; these include the recognition elements for Ap-1, Ap-2, Ap-3, Sp-1, a possible binding site for RAR:RXR, and a number of TCF-1 consensus motifs. Importantly, a perfect reverse complement of (C/G)TTAATTG, which was recently shown to be an optimal binding sequence for the homeodomain of Msx-1 protein (K.M. Catron, N. Iler, and C. Abate (1993) Mol. Cell. Biol. 13:2354-2365), was also located in the murine Msx-1 promoter. Binding of bacterially expressed Msx-1 homeodomain polypeptide to Msx-1-specific oligonucleotide was experimentally demonstrated, raising a distinct possibility of autoregulation of this developmentally regulated gene.

  12. Bullying at work: do industries differ in the Estonian case? Kas psühholoogilise töövägivalla levik on majandus-sektorites erinev: olukord Eestis?

    Directory of Open Access Journals (Sweden)

    Merle Tambur

    2012-01-01

    Full Text Available The bullying at work has not so far analyzed in Estonia – its dispersal, causes and impact have not studied, while in the countries with long democratic traditions it has been the actual problem of work context for two decades. The current study examines the prevalence of workplace bullying in Estonian organizations and the extent of the problem by industries because bullying may put impact on the employees´ efficiency. The sample consists of 1941 respondents which covers 59 organizations across Estonia and represents in all over 30 000 employee and the unemployed. The results reveal that bullying poses a serious problem in Estonia. According to Leymann´s criteria (1996 at least one negative act per week with a duration of at least 6 months, has been reported by 23,44% of respondents. Although, it came out that bullying is not sector-specific problem in Estonia, several and different industries are vulnerable from bullying.

  13. Decrease of concentration and colloidal fraction of organic carbon and trace elements in response to the anomalously hot summer 2010 in a humic boreal lake.

    Science.gov (United States)

    Shirokova, L S; Pokrovsky, O S; Moreva, O Yu; Chupakov, A V; Zabelina, S A; Klimov, S I; Shorina, N V; Vorobieva, T Ya

    2013-10-01

    The colloidal distribution and size fractionation of organic carbon (OC), major elements and trace elements (TE) were studied in a seasonally stratified, organic-rich boreal lake, Lake Svyatoe, located in the European subarctic zone (NW Russia, Arkhangelsk region). This study took place over the course of 4 years in both winter and summer periods using an in situ dialysis technique (1 kDa, 10 kDa and 50 kDa) and traditional frontal filtration and ultrafiltration (5, 0.22 and 0.025 μm). We observed a systematic difference in dissolved elements and colloidal fractions between summer and winter periods with the highest proportion of organic and organo-ferric colloids (1 kDa-0.22 μm) observed during winter periods. The anomalously hot summer of 2010 in European Russia produced surface water temperatures of approximately 30°C, which were 10° above the usual summer temperatures and brought about crucial changes in element speciation and size fractionation. In August 2010, the concentration of dissolved organic carbon (DOC) decreased by more than 30% compared to normal period, while the relative proportion of organic colloids decreased from 70-80% to only 20-30% over the full depth of the water column. Similarly, the proportion of colloidal Fe decreased from 90-98% in most summers and winters to approximately 60-70% in August 2010. During this hot summer, measurable and significant (>30% compared to other periods) decreases in the colloidal fractions of Ca, Mg, Sr, Ba, Al, Ti, Ni, As, V, Co, Y, all rare earth elements (REEs), Zr, Hf, Th and U were also observed. In addition, dissolved (organic matter by heterotrophic aerobic bacterioplankton and 3) photo-degradation of DOM and photo-chemical liberation of organic-bound TE. While the first process may have caused significant decreases in the total dissolved concentration of micronutrients (a factor of 2 to 5 for Cr, Mn, Fe, Ni, Cu, Zn and Cd and a factor of >100 for Co), the second and third factors could have brought

  14. Functional consequences of inducible genetic elements from the p53 SOS response in a mammalian organ system.

    Science.gov (United States)

    Guthrie, O'neil W

    2017-10-01

    In response to DNA damage from ultraviolet (UV) radiation, bacteria deploy the SOS response in order to limit cell death. This bacterial SOS response is characterized by an increase in the recA gene that transactivates expression of multiple DNA repair genes. The current series of experiments demonstrate that a mammalian organ system (the cochlea) that is not evolutionarily conditioned to UV radiation can elicit SOS responses that are reminiscent of that of bacteria. This mammalian SOS response is characterized by an increase in the p53 gene with activation of multiple DNA repair genes that harbor p53 response elements in their promoters. Furthermore, the experimental results provide support for the notion of a convergent trigger paradox, where independent SOS triggers facilitate disparate physiologic sequelae (loss vs. recovery of function). Therefore, it is proposed that the mammalian SOS response is multifunctional and manipulation of this endogenous response could be exploited in future biomedical interventions. Copyright © 2017 Elsevier Inc. All rights reserved.

  15. Sampling artifacts in measurement of elemental and organic carbon: Low-volume sampling in indoor and outdoor environments

    Science.gov (United States)

    Olson, David A.; Norris, Gary A.

    Experiments were completed to determine the extent of artifacts from sampling elemental carbon (EC) and organic carbon (OC) under sample conditions consistent with personal sampling. Two different types of experiments were completed; the first examined possible artifacts from oils used in personal environmental monitor (PEM) impactor plates, and the second examined artifacts from microenvironmental sampling using different sampling media combinations (quartz, Teflon, XAD denuder, and electrostatic precipitator). The effectiveness of front and backup filters was evaluated for most sampling configurations. Mean total carbon concentrations from sampling configurations using impactor oils were not statistically different from the control case (using a sharp cut cyclone). Three microenvironments were tested (kitchen, library, and ambient); carbon concentrations were highest in the kitchen using a front quartz filter (mean OC of 16.4 μg m -3). The lowest front quartz filter concentrations were measured in the library using XAD denuders (mean OC of 3.6 μg m -3). Denuder removal efficiencies (average of 82% for total carbon) were lower compared with previous ambient studies and may indicate that indoor sources influenced denuder efficiency during sample collection. The highest carbon concentrations from backup quartz filters were measured using the Teflon-quartz combination.

  16. Spatial and Temporal Trends in PM2.5 Organic and Elemental Carbon across the United States

    Directory of Open Access Journals (Sweden)

    J. L. Hand

    2013-01-01

    Full Text Available The rural/remote IMPROVE network (Interagency Monitoring of Protected Visual Environments and the Environmental Protection Agency's urban Chemical Speciation Network have measured PM2.5 organic (OC and elemental carbon (EC since 1989 and 2000, respectively. We aggregated OC and EC data from 2007 to 2010 at over 300 sites from both networks in order to characterize the spatial and seasonal patterns in rural and urban carbonaceous aerosols. The spatial extent of OC and EC was more regional in the eastern United States relative to more localized concentrations in the West. The highest urban impacts of OC and EC relative to background concentrations occurred in the West during fall and winter. Urban and rural carbonaceous aerosols experienced a large (although opposite range in seasonality in the West compared to a much lower seasonal variability in the East. Long-term (1990–2010 trend analyses indicated a widespread decrease in rural TC (TC = OC + EC across the country, with positive, though insignificant, trends in the summer and fall in the West. Short-term trends indicated that urban and rural TC concentrations have both decreased since 2000, with the strongest and more spatially homogeneous urban and rural trends in the West relative to the East.

  17. Ambient organic carbon to elemental carbon ratios: Influence of the thermal–optical temperature protocol and implications

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, Yuan, E-mail: ycheng@mail.tsinghua.edu.cn [State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing (China); He, Ke-bin, E-mail: hekb@tsinghua.edu.cn [State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing (China); State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex, Beijing (China); Duan, Feng-kui; Du, Zhen-yu [State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing (China); Zheng, Mei [College of Environmental Sciences and Engineering, Peking University, Beijing (China); Ma, Yong-liang [State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing (China)

    2014-01-01

    Ambient organic carbon (OC) to elemental carbon (EC) ratios are strongly associated with not only the radiative forcing due to aerosols but also the extent of secondary organic aerosol (SOA) formation. An inter-comparison study was conducted based on fine particulate matter samples collected during summer in Beijing to investigate the influence of the thermal–optical temperature protocol on the OC to EC ratio. Five temperature protocols were used such that the NIOSH (National Institute for Occupational Safety and Health) and EUSAAR (European Supersites for Atmospheric Aerosol Research) protocols were run by the Sunset carbon analyzer while the IMPROVE (the Interagency Monitoring of Protected Visual Environments network)-A protocol and two alternative protocols designed based on NIOSH and EUSAAR were run by the DRI analyzer. The optical attenuation measured by the Sunset carbon analyzer was more easily biased by the shadowing effect, whereas total carbon agreed well between the Sunset and DRI analyzers. The EC{sub IMPROVE-A} (EC measured by the IMPROVE-A protocol; similar hereinafter) to EC{sub NIOSH} ratio and the EC{sub IMPROVE-A} to EC{sub EUSAAR} ratio averaged 1.36 ± 0.21 and 0.91 ± 0.10, respectively, both of which exhibited little dependence on the biomass burning contribution. Though the temperature protocol had substantial influence on the OC to EC ratio, the contributions of secondary organic carbon (SOC) to OC, which were predicted by the EC-tracer method, did not differ significantly among the five protocols. Moreover, the SOC contributions obtained in this study were comparable with previous results based on field observation (typically between 45 and 65%), but were substantially higher than the estimation provided by an air quality model (only 18%). The comparison of SOC and WSOC suggests that when using the transmittance charring correction, all of the three common protocols (i.e., IMPROVE-A, NIOSH and EUSAAR) could be reliable for the estimation

  18. Ambient organic carbon to elemental carbon ratios: Influence of the thermal–optical temperature protocol and implications

    International Nuclear Information System (INIS)

    Cheng, Yuan; He, Ke-bin; Duan, Feng-kui; Du, Zhen-yu; Zheng, Mei; Ma, Yong-liang

    2014-01-01

    Ambient organic carbon (OC) to elemental carbon (EC) ratios are strongly associated with not only the radiative forcing due to aerosols but also the extent of secondary organic aerosol (SOA) formation. An inter-comparison study was conducted based on fine particulate matter samples collected during summer in Beijing to investigate the influence of the thermal–optical temperature protocol on the OC to EC ratio. Five temperature protocols were used such that the NIOSH (National Institute for Occupational Safety and Health) and EUSAAR (European Supersites for Atmospheric Aerosol Research) protocols were run by the Sunset carbon analyzer while the IMPROVE (the Interagency Monitoring of Protected Visual Environments network)-A protocol and two alternative protocols designed based on NIOSH and EUSAAR were run by the DRI analyzer. The optical attenuation measured by the Sunset carbon analyzer was more easily biased by the shadowing effect, whereas total carbon agreed well between the Sunset and DRI analyzers. The EC IMPROVE-A (EC measured by the IMPROVE-A protocol; similar hereinafter) to EC NIOSH ratio and the EC IMPROVE-A to EC EUSAAR ratio averaged 1.36 ± 0.21 and 0.91 ± 0.10, respectively, both of which exhibited little dependence on the biomass burning contribution. Though the temperature protocol had substantial influence on the OC to EC ratio, the contributions of secondary organic carbon (SOC) to OC, which were predicted by the EC-tracer method, did not differ significantly among the five protocols. Moreover, the SOC contributions obtained in this study were comparable with previous results based on field observation (typically between 45 and 65%), but were substantially higher than the estimation provided by an air quality model (only 18%). The comparison of SOC and WSOC suggests that when using the transmittance charring correction, all of the three common protocols (i.e., IMPROVE-A, NIOSH and EUSAAR) could be reliable for the estimation of SOC by the EC

  19. Effects of radioactive by-products along the extraction of rare earth elements on aquatic and terrestrial organisms

    Energy Technology Data Exchange (ETDEWEB)

    Findeiss, Matthias

    2016-12-13

    Lanthanides, also called rare earth elements (REE) are key elements in modern technologies and especially in green technologies such as energy generation through wind power. Thus, they are of considerable economic importance with a global production of around 124 000 t REE per year. A detailed environmental assessment with identification of all risks is the foundation to assess the sustainability of mining, processing and separation processes. Rare earth elements usually are found together with actinides such as uranium and thorium. Therefore, actinides and their decay products are simultaneously enriched during the processing of REE. In addition to conventional REE minerals such as monazite or bastnasite, the mineral eudialyte can be used as a REE source. Even though, the total share of REE is low, the most important REE needed for industrial usages are strongly represented in eudialyte. Furthermore, the proportion of radioactive impurities is very low. Eudialyte is currently not used as source mineral, but might play a bigger role on the global market in the future.Little information about the environmental impacts of REE-production is available to the public, in particular with regard to its radioactive by-products. Thorium is the most prominent of these and has therefore been characterized in detail for its ecotoxicity. A first goal of this work was to evaluate the a- emitter thorium and its impact on the environment. To this aim, an intensive literature search was conducted and results were prepared including the long-term effects of thorium dust and gaseous emissions. Therefore and because ecotoxicological testing of gaseous emissions was technically difficult and environmentally less relevant - unlike its immense impact for exposed industrial workers and bystanders - the water effluent und solid waste streams were investigated with aquatic and terrestrial toxicological experiments. The knowledge gained is meant to supplement the missing data for thorium. A

  20. Effects of radioactive by-products along the extraction of rare earth elements on aquatic and terrestrial organisms

    International Nuclear Information System (INIS)

    Findeiss, Matthias

    2016-01-01

    Lanthanides, also called rare earth elements (REE) are key elements in modern technologies and especially in green technologies such as energy generation through wind power. Thus, they are of considerable economic importance with a global production of around 124 000 t REE per year. A detailed environmental assessment with identification of all risks is the foundation to assess the sustainability of mining, processing and separation processes. Rare earth elements usually are found together with actinides such as uranium and thorium. Therefore, actinides and their decay products are simultaneously enriched during the processing of REE. In addition to conventional REE minerals such as monazite or bastnasite, the mineral eudialyte can be used as a REE source. Even though, the total share of REE is low, the most important REE needed for industrial usages are strongly represented in eudialyte. Furthermore, the proportion of radioactive impurities is very low. Eudialyte is currently not used as source mineral, but might play a bigger role on the global market in the future.Little information about the environmental impacts of REE-production is available to the public, in particular with regard to its radioactive by-products. Thorium is the most prominent of these and has therefore been characterized in detail for its ecotoxicity. A first goal of this work was to evaluate the a- emitter thorium and its impact on the environment. To this aim, an intensive literature search was conducted and results were prepared including the long-term effects of thorium dust and gaseous emissions. Therefore and because ecotoxicological testing of gaseous emissions was technically difficult and environmentally less relevant - unlike its immense impact for exposed industrial workers and bystanders - the water effluent und solid waste streams were investigated with aquatic and terrestrial toxicological experiments. The knowledge gained is meant to supplement the missing data for thorium. A

  1. Elemental composition and optical properties reveal changes in dissolved organic matter along a permafrost thaw chronosequence in a subarctic peatland

    Energy Technology Data Exchange (ETDEWEB)

    Hodgkins, Suzanne; Tfaily, Malak M.; Podgorski, David C.; McCalley, Carmody; Saleska, Scott; Crill, Patrick M.; Rich, Virginia; Chanton, Jeffrey; Cooper, William T.

    2016-08-01

    The fate of carbon stored in permafrost-zone peatlands represents a significant uncertainty in global climate modeling. Given that the breakdown of dissolved organic matter (DOM) is often a major pathway for decomposition in peatlands, knowledge of DOM reactivity under different permafrost regimes is critical for determining future climate feedbacks. To explore the effects of permafrost thaw and resultant plant succession on DOM reactivity, we used a combination of Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS), UV/Vis absorbance, and excitation-emission matrix spectroscopy (EEMS) to examine the DOM elemental composition and optical properties of 27 pore water samples gathered from various sites along a permafrost thaw sequence in Stordalen Mire, a thawing subarctic peatland in northern Sweden. The presence of dense Sphagnum moss, a feature that is dominant in the intermediate thaw stages, appeared to be the main driver of variation in DOM elemental composition and optical properties at Stordalen. Specifically, DOM from sites with Sphagnum had greater aromaticity, higher average molecular weights, and greater O/C, consistent with a higher abundance of phenolic compounds that likely inhibit decomposition. These compounds are released by Sphagnum and may accumulate due to inhibition of phenol oxidase activity by the acidic pH at these sites. In contrast, sites without Sphagnum, specifically fully-thawed rich fens, had more saturated, more reduced compounds, which were high in N and S. Optical properties at rich fens were indicated the presence of microbially-derived DOM, consistent with the higher decomposition rates previously measured at these sites. These results indicate that Sphagnum acts as an inhibitor of rapid decomposition and CH4 release in thawing subarctic peatlands, consistent with lower rates of CO2 and CH4 production previously observed at these sites. However, this inhibitory effect may disappear if Sphagnumdominated bogs

  2. Elemental composition and optical properties reveal changes in dissolved organic matter along a permafrost thaw chronosequence in a subarctic peatland

    Science.gov (United States)

    Hodgkins, Suzanne B.; Tfaily, Malak M.; Podgorski, David C.; McCalley, Carmody K.; Saleska, Scott R.; Crill, Patrick M.; Rich, Virginia I.; Chanton, Jeffrey P.; Cooper, William T.

    2016-08-01

    The fate of carbon stored in permafrost-zone peatlands represents a significant uncertainty in global climate modeling. Given that the breakdown of dissolved organic matter (DOM) is often a major pathway for decomposition in peatlands, knowledge of DOM reactivity under different permafrost regimes is critical for determining future climate feedbacks. To explore the effects of permafrost thaw and resultant plant succession on DOM reactivity, we used a combination of Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS), UV/Vis absorbance, and excitation-emission matrix spectroscopy (EEMS) to examine the DOM elemental composition and optical properties of 27 pore water samples gathered from various sites along a permafrost thaw sequence in Stordalen Mire, a thawing subarctic peatland in northern Sweden. The presence of dense Sphagnum moss, a feature that is dominant in the intermediate thaw stages, appeared to be the main driver of variation in DOM elemental composition and optical properties at Stordalen. Specifically, DOM from sites with Sphagnum had greater aromaticity, higher average molecular weights, and greater O/C, consistent with a higher abundance of phenolic compounds that likely inhibit decomposition. These compounds are released by Sphagnum and may accumulate due to inhibition of phenol oxidase activity by the acidic pH at these sites. In contrast, sites without Sphagnum, specifically fully-thawed rich fens, had more saturated, more reduced compounds, which were high in N and S. Optical properties at rich fens indicated the presence of microbially-derived DOM, consistent with the higher decomposition rates previously measured at these sites. These results indicate that Sphagnum acts as an inhibitor of rapid decomposition and CH4 release in thawing subarctic peatlands, consistent with lower rates of CO2 and CH4 production previously observed at these sites. However, this inhibitory effect may disappear if Sphagnum-dominated bogs

  3. Content of selected elements and low-molecular-weight organic acids in fruiting bodies of edible mushroom Boletus badius (Fr.) Fr. from unpolluted and polluted areas.

    Science.gov (United States)

    Mleczek, Mirosław; Magdziak, Zuzanna; Gąsecka, Monika; Niedzielski, Przemysław; Kalač, Pavel; Siwulski, Marek; Rzymski, Piotr; Zalicka, Sylwia; Sobieralski, Krzysztof

    2016-10-01

    The aim of the study was to (i) investigate the potential of edible mushroom Boletus badius (Fr.) Fr. to accumulate 53 elements from unpolluted acidic sandy soil and polluted alkaline flotation tailing sites in Poland, (ii) to estimate the low-molecular-weight organic acid (LMWOA) profile and contents in fruit bodies, and finally (iii) to explore the possible relationship between elements and LMWOA content in mushrooms. The content of most elements in fruiting bodies collected from the flotation tailings was significantly higher than in mushrooms from the unpolluted soils. The occurrence of elements determined in fruiting bodies of B. badius has been varied (from 0.01 mg kg -1 for Eu, Lu, and Te up to 18,932 mg kg -1 for K). The results established the high importance of element contents in substrate. Among ten organic acids, nine have been found in wide range: from below 0.01 mg kg -1 for fumaric acid to 14.8 mg g -1 for lactic acid. Lactic and succinic acids were dominant in both areas, and citric acid was also in high content in polluted area. The correlation between element contents and the individual and total content of LMWOAs was confirmed.

  4. Whole-word frequency and inflectional paradigm size facilitate Estonian case-inflected noun processing.

    Science.gov (United States)

    Lõo, Kaidi; Järvikivi, Juhani; Baayen, R Harald

    2018-06-01

    Estonian is a morphologically rich Finno-Ugric language with nominal paradigms that have at least 28 different inflected forms but sometimes more than 40. For languages with rich inflection, it has been argued that whole-word frequency, as a diagnostic of whole-word representations, should not be predictive for lexical processing. We report a lexical decision experiment, showing that response latencies decrease both with frequency of the inflected form and its inflectional paradigm size. Inflectional paradigm size was also predictive of semantic categorization, indicating it is a semantic effect, similar to the morphological family size effect. These findings fit well with the evidence for frequency effects of word n-grams in languages with little inflectional morphology, such as English. Apparently, the amount of information on word use in the mental lexicon is substantially larger than was previously thought. Copyright © 2018 Elsevier B.V. All rights reserved.

  5. Determination of Heating Value of Estonian Oil Shale by Laser-Induced Breakdown Spectroscopy

    Directory of Open Access Journals (Sweden)

    M. Aints

    2018-01-01

    Full Text Available The laser-induced breakdown spectroscopy (LIBS combined with multivariate regression analysis of measured data were utilised for determination of the heating value and the chemical composition of pellets made from Estonian oil shale samples with different heating values. The study is the first where the oil shale heating value is determined on the basis of LIBS spectra. The method for selecting the optimal number of spectral lines for ordinary multivariate least squares regression model is presented. The correlation coefficient between the heating value predicted by the regression model, and that measured by calorimetric bomb, was R2=0.98. The standard deviation of prediction was 0.24 MJ/kg. Concentrations of oil shale components predicted by the regression model were compared with those measured by ordinary methods.

  6. Taxes, Estonian state budget and economic crises. Maksud, riigi eelarve ja majanduskriis

    Directory of Open Access Journals (Sweden)

    Olev Raju

    2013-01-01

    Full Text Available Recession has sharply erected the question of tax burden and the optimal proportion of different kinds of taxes among the incomes of the budget. Indirect taxes and consumption taxes, which proportion is different according to different methodologies, dominate in Estonian state budget. The buoyancy of a tax system based on taxes of that kind is especially weak during the recession. Difficulties concerning the incomes of budget have arisen the necessity for lifting taxes, which is possible as the tax burden is low now. But a sharp question of the optimal level of taxes is going to be raised. A formula for indirect tax optimum according to Ramsey taxes and Slutski decomposition has been proposed in the article.

  7. Comparative analysis of idiom selection and sequencing 5 in Estonian basic school EFL coursebooks

    Directory of Open Access Journals (Sweden)

    Rita Anita Forssten

    2017-05-01

    Full Text Available The article investigates the selection and sequencing of the idioms encountered in two locally-produced and international coursebook series currently employed in Estonian basic schools. It is hypothesized that there exists a positive correlation between idioms’ difficulty and coursebooks’ language proficiency level. The hypothesis is tested through a statistical analysis of the idioms found which are categorized in terms of their analysability into three categories where category 1 includes analysable semi-literal idioms, category 2 comprises analysable semi-transparent idioms, and category 3 encompasses non-analysable opaque idioms, and then analysed through an online language corpus (British National Corpus. The results of the study reveal that the coursebook authors under discussion have disregarded idioms’ frequency as a criterion for selection or sequencing, whereas the factor utilized to some extent is the degree of analysability.

  8. Trace elements and stable isotopes (δ13C and δ15N) in shallow and deep-water organisms from the East China Sea

    International Nuclear Information System (INIS)

    Asante, Kwadwo Ansong; Agusa, Tetsuro; Mochizuki, Hiroko; Ramu, Karri; Inoue, Suguru; Kubodera, Tsunemi; Takahashi, Shin; Subramanian, Annamalai; Tanabe, Shinsuke

    2008-01-01

    Trace elements (22) and stable isotope ratios (δ 15 N and δ 13 C) were analyzed in marine organisms from shallow (SW) and deep-water (DW) of the East China Sea to understand biomagnification and prey source of trace elements. In the benthic marine organisms from DW, δ 15 N values were negatively correlated with Ba, Cu, Ag, Mo, Sr, As, and Co concentrations. This may be due to the specific accumulation in lower trophic animals and/or the biodilution through the food web in DW. Relationships between δ 15 N and concentrations of Co, Cr, Bi, and Tl in fish and Ag, Bi, V, Hg, and Tl in crustaceans showed positive correlations, suggesting that trophic position was affecting the concentrations of those elements in phyla, with higher trophic animals retaining higher concentrations than the lower trophic animals. Positive correlations between δ 13 C and Rb were observed in marine organisms. Therefore, Rb may be a possible substitute of δ 13 C as tracer of prey source in the East China Sea although further investigation is required. - This is the first study on trophic transfer and prey source of trace elements in marine organisms from the East China Sea

  9. The influence of intestine-based treatment using Xuan Bai Cheng Qi Tang on the concentration of trace elements in the main organs of COPD rats

    Directory of Open Access Journals (Sweden)

    Jiamin Yang

    2017-01-01

    Conclusion: This study showed that “treating from the intestine” using Xuan Bai Cheng Qi Tang and its modified formulae can regulate the concentration of trace elements in the main organs of COPD rats. This may be one of the mechanisms for intestine-based treatment for COPD.

  10. Leadership style as determinant of creativity profiles in Estonian organizations / Ruth Alas, Krista Tuulik

    Index Scriptorium Estoniae

    Alas, Ruth, 1960-2018

    2004-01-01

    Eesti organisatsioonides aastatel 2001-2003 projekti GLOBE raames läbi viidud empiirilise juhiuuringu tulemuste analüüs. Uuringu käigus selgitati välja, kuidas alluvad tajuvad oma juhte, keda eestlased peavad suurepäraseks juhiks, milliseid isiksuseomadusi ning käitumist omab karismaatiline juht. Definitsioonid: innovatsioon, loovus, juhtimine, eestvedamine ja väärtushinnangud. Diagrammid, tabelid

  11. Change in medical plant use in Estonian ethnomedicine: a historical comparison between 1888 and 1994.

    Science.gov (United States)

    Sõukand, Renata; Kalle, Raivo

    2011-05-17

    The aim of this paper is to compare the changes in the utilization of species from various hemeroby categories (indicating the degree of sensitivity of the plant to human impact) using historical data concerning the years 1888-1994. The authors digitised 8808 handwritten reports, reflecting local ethnopharmacological knowledge from 8 selected collections from the Estonian Folklore Archives of the Estonian Literary Museum. They were semi-quantitatively analyzed according to the sensitivity to human impact of 540 taxa that could possibly be related to the plant vernacular names given in the reports. Although in different periods of time the number of ethnopharmacologically used plants has changed, the proportion of plants utilized from each group has remained relatively same, consisting on average of: 23% anthropophytes, 42% apophytes, 32% hemeradiaphores and 3% hemerophobes. Comparison of the application of the most used plants revealed considerable changes of plant utilization, in which the varied use of the most popular anthropophytes increased and the applied scope of the most popular hemeradiaphores and hemerophobes decreased almost by twofold in one century. Case studies on seven taxa are presented, of them, use of Allium sativum L., Aesculus hippocastanum L. and Mentha xpiperita L. increased, whereas the use of Hordeum L., Orchidaceae, Paris quadrifolia L. and Briza media L. decreased greatly. This research contributes to the better understanding of the cognitive and human ecological concepts underlying the use of medicinal plants in Estonia. Strong increase in the ethnomedical utilization of plants depending on human influence, and a decrease in the use of taxa that do not prefer human activities indicates that, despite some of the population still have access to natural resources and diverse knowledge of the medical use of plants, the majority relies on a very narrow selection and a rather restricted herbal landscape. Copyright © 2011 Elsevier Ireland Ltd

  12. Fossil and non-fossil sources of organic carbon (OC and elemental carbon (EC in Göteborg, Sweden

    Directory of Open Access Journals (Sweden)

    S. Szidat

    2009-03-01

    Full Text Available Particulate matter was collected at an urban site in Göteborg (Sweden in February/March 2005 and in June/July 2006. Additional samples were collected at a rural site for the winter period. Total carbon (TC concentrations were 2.1–3.6 μg m−3, 1.8–1.9 μg m−3, and 2.2–3.0 μg m−3 for urban/winter, rural/winter, and urban/summer conditions, respectively. Elemental carbon (EC, organic carbon (OC, water-insoluble OC (WINSOC, and water-soluble OC (WSOC were analyzed for 14C in order to distinguish fossil from non-fossil emissions. As wood burning is the single major source of non-fossil EC, its contribution can be quantified directly. For non-fossil OC, the wood-burning fraction was determined independently by levoglucosan and 14C analysis and combined using Latin-hypercube sampling (LHS. For the winter period, the relative contribution of EC from wood burning to the total EC was >3 times higher at the rural site compared to the urban site, whereas the absolute concentrations of EC from wood burning were elevated only moderately at the rural compared to the urban site. Thus, the urban site is substantially more influenced by fossil EC emissions. For summer, biogenic emissions dominated OC concentrations most likely due to secondary organic aerosol (SOA formation. During both seasons, a more pronounced fossil signal was observed for Göteborg than has previously been reported for Zurich, Switzerland. Analysis of air mass origin using back trajectories suggests that the fossil impact was larger when local sources dominated, whereas long-range transport caused an enhanced non-fossil signal. In comparison to other European locations, concentrations of levoglucosan and other monosaccharide anhydrides were low for the urban and the rural site in the area of Göteborg during winter.

  13. Concentrations and Loads of Organic Compounds and Trace Elements in Tributaries to Newark and Raritan Bays, New Jersey

    Science.gov (United States)

    Wilson, Timothy P.; Bonin, Jennifer L.

    2007-01-01

    throughout each event for trace-element analysis, and multiple samples were collected for suspended sediment (SS), particulate carbon (POC), and dissolved organic carbon (DOC) analysis. The suspended sediment and exchange resin were analyzed for 114 polychlorinated biphenyls (PCBs, by US EPA method 1668A, modified), seven 2,3,7,8-substituted chlorinated dibenzo-p-dioxins (CDD) and 10 dibenzo-p-difurans (CDF) (by US EPA method 1613), 24 PAHs (by low-resolution isotope dilution/mass-spectral methods), 27 organo-chlorine pesticides (OCPs) (by high resolution isotope dilution/mass-spectral methods), and the trace elements mercury (Hg), methyl-mercury (MeHg), lead (Pb), and cadmium (Cd). Isotope dilution methods using gas chromatography and high-and low-resolution mass spectral (GC/MS) detection were used to accurately identify and quantify organic compounds in the sediment and water phases. Trace elements were measured using inductively coupled plasma-mass spectrometry and cold-vapor atomic fluorescence spectrometry methods. The loads of sediment, carbon, and chemicals were calculated for each storm and low-flow event sampled. Because only a few storm events were sampled, yearly loads of sediment were calculated from rating curves developed using historical SS and POC data. The average annual loads of sediment and carbon were calculated for the period 1975-2000, along with the loads for the selected water years being modeled as part of the New York New Jersey Harbor Estuary Program CARP. Comparison of loads calculated using the rating curve method to loads measured during the sampled storm events indicated that the rating curve method likely underpredicts annual loads. Average annual loads of suspended sediment in the tributaries were estimated to be 395,000 kilograms per year (kg/yr) in the Hackensack River, 417,000 kg/yr in the Elizabeth River, 882,000 kg/yr in the Rahway River, 22,700,000 kg/yr in the Passaic River, and 93,100,000 kg/yr in the Raritan River. Averag

  14. Organic and elemental carbon bound to particulate matter in the air of printing office and beauty salon

    Science.gov (United States)

    Rogula-Kopiec, Patrycja; Pastuszka, Józef S.; Rogula-Kozłowska, Wioletta; Mucha, Walter

    2017-11-01

    The aim of this study was to determine the role of internal sources of emissions on the concentrations of total suspended particulate matter (TSP) and its sub-fraction, so-called respirable PM (PM4; fraction of particles with particle size ≤ 4 µm) and to estimate to which extent those emissions participate in the formation of PM-bound elemental (EC) and organic (OC) carbon in two facilities - one beauty salon and one printing office located in Bytom (Upper Silesia, Poland). The average concentration of PM in the printing office and beauty salon during the 10-day measurement period was 10 and 4 (PM4) and 8 and 3 (TSP) times greater than the average concentration of PM fractions recorded in the same period in the atmospheric air; it was on average: 204 µg/m3 (PM4) and 319 µg/m3 (TSP) and 93 µg/m3 (PM4) and 136 µg/m3 (TSP), respectively. OC concentrations determined in the printing office were 38 µg/m3 (PM4) and 56 µg/m3 (TSP), and those referring to EC: 1.8 µg/m3 (PM4) and 3.5 µg/m3 (TSP). In the beauty salon the average concentration of OC for PM4 and TSP were 58 and 75 µg/m3, respectively and in case of EC - 3.1 and 4.7 µg/m3, respectively. The concentrations of OC and EC within the those facilities were approximately 1.7 (TSP-bound EC, beauty salon) to 4.7 (TSP-bound OC, printing office) times higher than the average atmospheric concentrations of those compounds measured in both PM fractions at the same time. In both facilities the main source of TSP-and PM4-bound OC in the indoor air were the chemicals - solvents, varnishes, paints, etc.

  15. Metallic Trace Elements (MTE in soils and plant organs of some crop in periurban of Abidjan (Ivory Coast

    Directory of Open Access Journals (Sweden)

    Thierry Philippe Guety

    2017-12-01

    Full Text Available The quality of the plant production in periurban agriculture is subjected to question given the potential contamination of soils that can affect the crops. The levels of contamination of soils and vegetables by Metallic trace elements (MTE as copper (Cu, zinc (Zn, cadmium (Cd and lead (Pb in the district of Abidjan, have been evaluated. Multi-sites survey of cropping areas of sweet potato and Hibiscus was conducted in three municipalities in Abidjan (Port-Bouët, Yopougon and Bingerville in relation to the intensity of industrial and commercial activities. The site of Bingerville has been used as the reference site referring to the low activities. Soil samples (in 0-20 cm and 20 - 40 cm, combined with that of plants (leaf, stem, and root, and water were collected, transported in laboratory for analysis. The total amounts of MTE in soil, as well as the different fractions extracted were determined in addition to the respective concentration in plants (Hibiscus and Sweet potato. Toxic level of Pb (< 8 mgkg-1 was observed in the plant organs collected at Port-Bouët site indifferently to crops while lowest content of Pb (35.5 mgkg-1 was accounting for the soil of Yopougon (39.8 mgkg-1. A neutral pH of the soil has been considered more favorable to the contamination of plants in Pb on the polluted sites somewhat differing for extractable fractions. The acidity and small width of leaf as observed for Hibiscus, were identified as the control factors of crop contamination in periurban agroecosystems prone to Pb pollution. To strengthen the consistency of the knowledge, studies of the interaction between Pb and Zn as well as the translocation of Pb in the plants to tubers are suggested in the tropical ecosystems.

  16. Distribution of trace elements in organs of six species of cetaceans from the Ligurian Sea (Mediterranean), and the relationship with stable carbon and nitrogen ratios

    Energy Technology Data Exchange (ETDEWEB)

    Capelli, R. [Dipartimento di Chimica e Tecnologie Farmaceutiche ed Alimentari - Universita degli Studi di Genova - Via Brigata Salerno, 13 I-16147 Genova (Italy); Das, K. [MARE center, Laboratory for Oceanology, University of Liege, B6 Sart-Tilman, B-4000 Liege (Belgium); Pellegrini, R. De; Drava, G. [Dipartimento di Chimica e Tecnologie Farmaceutiche ed Alimentari - Universita degli Studi di Genova - Via Brigata Salerno, 13 I-16147 Genova (Italy); Lepoint, G. [MARE center, Laboratory for Oceanology, University of Liege, B6 Sart-Tilman, B-4000 Liege (Belgium); Miglio, C. [Dipartimento di Chimica e Tecnologie Farmaceutiche ed Alimentari - Universita degli Studi di Genova - Via Brigata Salerno, 13 I-16147 Genova (Italy); Minganti, V. [Dipartimento di Chimica e Tecnologie Farmaceutiche ed Alimentari - Universita degli Studi di Genova - Via Brigata Salerno, 13 I-16147 Genova (Italy)], E-mail: minganti@dictfa.unige.it; Poggi, R. [Museo Civico di Storia Naturale ' Giacomo Doria' - Via Brigata Liguria, 9 I-16121 Genova (Italy)

    2008-02-15

    Mercury (total and organic), cadmium, lead, copper, iron, manganese, selenium and zinc concentrations were measured in different organs of 6 different cetacean species stranded in an area of extraordinary ecological interest (Cetaceans' Sanctuary of the Mediterranean Sea) along the coast of the Ligurian Sea (North-West Mediterranean). Stable-isotopes ratios of carbon ({sup 13}C/{sup 12}C) and nitrogen ({sup 15}N/{sup 14}N) were also measured in the muscle. A significant relationship exists between {sup 15}N/{sup 14}N, mercury concentration and the trophic level. The distribution of essential and non-essential trace elements was studied on several organs, and a significant relationship between selenium and mercury, with a molar ratio close to 1, was found in the cetaceans' kidney, liver and spleen, regardless of their species. High selenium concentrations are generally associated with a low organic to total mercury ratio. While narrow ranges of concentrations were observed for essential elements in most organs, mercury and selenium concentrations are characterised by a wide range of variation. Bio-accumulation and bio-amplification processes in cetaceans can be better understood by comparing trace element concentrations with the stable-isotopes data.

  17. Studies in Korea on ingestion and organ content of trace elements of importance in radiological protection. December 1996 - April 1998

    International Nuclear Information System (INIS)

    Seung Yeon Cho

    2000-01-01

    Concentrations of trace elements including 5 important elements such as U, Th, Cs, Sr and I in Korean total diet and 4 most frequently consuming Korean foodstuffs have been analyzed by neutron activation analysis. One day representative mixed diet of adult Korean was collected from the data based on the food diary of 77 healthy subjects at the age between 20 to 50

  18. Identifying Military Impacts on Archaeological Deposits Based on Differences in Soil Organic Carbon and Chemical Elements at Soil Horizon Interfaces

    Science.gov (United States)

    2012-03-01

    Robotic pH meter (AS-3000 Dual pH Analyzer, LabFit, Burswood, Australia) using a 1:1 soil / solution ratio (0.01 M CaCl2) (Kissel et al., 2009). Soil lime...displacement of elements in the soil profile, and alterations in mineralization processes which affect the leachable element concentration in soil solution . Leachable

  19. Smoking prevalence and attitudes towards smoking among Estonian physicians: results from cross-sectional studies in 2002 and 2014

    OpenAIRE

    Põld, Mariliis; Pärna, Kersti

    2017-01-01

    Objectives To explore smoking prevalence and attitudes towards smoking among Estonian physicians in 2002 and 2014. Design Two self-administered cross-sectional postal surveys were conducted among practising physicians in Estonia. Participants Initial sample consisted of all practising physicians in Estonia. The corrected response rate was 67.8% in 2002 and 53.1% in 2014. Present study sample was restricted to physicians younger than 65 years (n=2549 in 2002, n=2339 in 2014). Methods Age-stand...

  20. Mutational analysis of COL1A1 and COL1A2 genes among Estonian osteogenesis imperfecta patients.

    Science.gov (United States)

    Zhytnik, Lidiia; Maasalu, Katre; Reimann, Ene; Prans, Ele; Kõks, Sulev; Märtson, Aare

    2017-08-15

    Osteogenesis imperfecta (OI) is a rare bone disorder. In 90% of cases, OI is caused by mutations in the COL1A1/2 genes, which code procollagen α1 and α2 chains. The main aim of the current research was to identify the mutational spectrum of COL1A1/2 genes in Estonian patients. The small population size of Estonia provides a unique chance to explore the collagen I mutational profile of 100% of OI families in the country. We performed mutational analysis of peripheral blood gDNA of 30 unrelated Estonian OI patients using Sanger sequencing of COL1A1 and COL1A2 genes, including all intron-exon junctions and 5'UTR and 3'UTR regions, to identify causative OI mutations. We identified COL1A1/2 mutations in 86.67% of patients (26/30). 76.92% of discovered mutations were located in the COL1A1 (n = 20) and 23.08% in the COL1A2 (n = 6) gene. Half of the COL1A1/2 mutations appeared to be novel. The percentage of quantitative COL1A1/2 mutations was 69.23%. Glycine substitution with serine was the most prevalent among missense mutations. All qualitative mutations were situated in the chain domain of pro-α1/2 chains. Our study shows that among the Estonian OI population, the range of collagen I mutations is quite high, which agrees with other described OI cohorts of Northern Europe. The Estonian OI cohort differs due to the high number of quantitative variants and simple missense variants, which are mostly Gly to Ser substitutions and do not extend the chain domain of COL1A1/2 products.

  1. Comparison of two organic fertilizers along with Zn and B elements on concentration, uptake of nutrients and some growth parameters in millet (Panicum miliaceum L.

    Directory of Open Access Journals (Sweden)

    T Nezhad hoseini

    2016-05-01

    Full Text Available A field experiment was conducted to study the effect of two organic fertilizers along with zinc and boron elements on some growth parameters, concentration and uptake of nutrients in millet (Panicum miliaceum L. by using factorial based on randomized completely block design with three replications in Qaen region, Iran. The main treatments were municipal solid waste compost and cow manure (each at 0 and 25 t.ha-1 and sub treatments were elements of Zn (0, 50 kg.ha-1 and B (0, 10 kg.ha-1 using their respective ZnSO4 and H3BO3 salts. Results showed that treatments interaction had significant effects on total dry matter yield, number of tillers per plant and plant height of Millet. The highest total dry matter production was achieved by interaction of cow manure along with Zn and B elements. Concentrations of N, Fe, Zn, B and Cu in plant were increased significantly by treatments interaction effects compared to control. Interaction effect of organic fertilizers with B (in the absence of Zn enhanced plant B concentration significantly, whereas, interaction of organic fertilizers with Zn (in the absence of B decreased B concentration in plant. The highest plant uptake of N, P, K, Zn, and B was observed in plots with cow manure and Zn and B elements.

  2. How to Improve the Supportive Role of Estonian Innovation System toward Launching New Products by High Technology Companies?

    Directory of Open Access Journals (Sweden)

    Liisi Sepp

    2013-01-01

    Full Text Available The purpose of the study is to evaluate how supportive is Estonian national innovation system toward the launching of new innovative products by high technology firms. The article intends to combine two broad areas of research – national innovation system approach and the different models of the new product launching. Based on the literature review and in-depth analysis of three case studies of Estonian high-tech company’s major barriers as well success factors of highly innovative product launches were identified. The barriers of the new product launching were linked with the systemic failures of the national innovation system. The most relevant failures of Estonian national innovation system inhibiting the new product development are capability and networking failures. The sources of innovation of high-technology firms are too narrow, linkages with domestic firms and higher education institutions as well with foreign firms are poorly developed. High-tech firms have also serious capacity problems due to the extremely weak support mechanism by national innovation system on the seed funding stage of product development and prototype building stage as well. Paper argues that resources needed for the innovation should not be looked too narrowly following linear innovation model approach. Instead interactive approach is needed, which combines capability building, network development, interactive learning with direct investments into fundamental research.

  3. The NAA of trace elements and its application in the identification of the type of sedimentary organic matter

    International Nuclear Information System (INIS)

    Tong Chunhan; Li Guodong

    1998-01-01

    The type of sedimentary organic matter is an important parameter in evaluating an oil or gas field. Since the conventional organic geochemistry methods for determining the type meet unsurmountable difficulties when the maturity of organic matter is high, a new method to identify the type according to V and Ni contents in soluble organic matter based on NAA has been developed. Details of the method are introduced and an applied example is given

  4. Four years of highly time resolved measurements of elemental and organic carbon at a rural background site in Central Europe

    Science.gov (United States)

    Mbengue, Saliou; Fusek, Michal; Schwarz, Jaroslav; Vodička, Petr; Šmejkalová, Adéla Holubová; Holoubek, Ivan

    2018-06-01

    Elemental carbon (EC) and organic carbon (OC) in fine atmospheric aerosols (PM2.5: aerodynamic diameter smaller than 2.5 μm) have been measured with a semi-automatic instrument during a 4-year survey at the National Atmospheric Observatory Košetice (NAOK), Czech Republic. Ground based measurements were performed from March 2013 to December 2016 with a field Semi-Continuous OCEC Aerosol Analyzer (Sunset Laboratory Inc., USA). The variation of EC and OC concentrations and the OC/EC ratio was characterized for different seasons and days of the week. During our survey, higher concentrations of EC and OC were observed in winter (0.83 ± 0.67 and 3.33 ± 2.28 μg m-3, respectively), and lower concentrations were recorded in summer (0.34 ± 0.18 and 2.30 ± 1.15 μg m-3, respectively). Inversely, the OC/EC ratio with mean value (5.1 ± 2.6) characteristic to rural background area was higher in summer (7.33 ± 3.23) in comparison to the other seasons. Since the data contain values below detection and quantification limits of the measuring device (i.e., censored values), statistical methods for censored data have been used in order to compare mean EC and OC concentrations between various seasons. It was found out that there is a significant difference between summer and the other seasons with the exception of mean OC concentrations at noon. In most cases, there was also a significant difference between winter and the other seasons. Moreover, it was found out that when dealing with OC concentrations, it is possible to replace censored values by a constant and still obtain reasonable results. In case of EC concentrations, the method based on censored distributions should be preferred when the sample size is small and the proportion of censored values is high. The diurnal variation of EC and OC is less pronounced in summer. During working days, the EC diurnal pattern displays a morning (between 6:00 and 10:00) and an afternoon/evening (between 18:00 and 22:00) peaks, while

  5. Estonian exceptionalism

    Index Scriptorium Estoniae

    2011-01-01

    Ulatuslikud kärped ja liitumine eurotsooniga toovad Eestist häid majandusuudiseid: töötus langeb, majandus kasvab, eksport tõuseb, eelarve on plussis, reitinguagentuur Fitch krediidireiting tõusis tasemele A+

  6. With or without articles? A comparison of article-like determiners in Estonian and Finnish

    Directory of Open Access Journals (Sweden)

    Helen Hint

    2017-10-01

    Full Text Available In this paper, we compare the use and functions of definite and indefinite article-like determiners in Estonian and Finnish. Our main aim is to explore whether the factors that explain the choice of particular determiner forms are similar in Estonian and Finnish. We use a picture-sequence based elicitation experiment to collect spoken narratives from adult native speakers of Estonian and Finnish, and apply non-parametric tree and forest models to analyze the data. Our findings indicate that number of mention and animacy are important predictor variables in both languages, but their exact effect is divergent. We also find that in Finnish, case of the determiner NP proves to be an important factor, while in Estonian, syntactic role of the NP explains some aspects of determiner form choice. Nevertheless, the overall usage frequency of determiners is modest in the Estonian and Finnish data, and the process of grammaticalizing articles is only in initial stages in both languages. *** Artikliga, artiklita? Eesti ja soome keele artiklilaadsete määratlejate võrdlus Siinses uurimuses analüüsime võrdlevalt artiklilaadseid definiitseid ja indefiniitseid määratlejaid eesti ja soome keeles. Eelkõige kõrvutame eesti keele definiitset määratlejat see ja soome keele definiitseid määratlejaid se ja tämä ning eesti ja soome indefiniitset määratlejat üks/yks(i. Samuti vaatleme eesti keele possessiivpronoomeni oma ning soome 3sg possessiivsufiksi (-nsa/-nsä, -Vn referentsiaalseid omadusi. Uurimuse põhieesmärgiks on selgitada, millised on peamised määratlejate kasutust mõjutavad keelelised faktorid eesti ja soome keeles ning kas need faktorid on keeliti sarnased või erinevad. Ühtlasi otsime vastust küsimusele, kas eesti ja soome keeles on põhjust rääkida määratlejate grammatisatsioonist artikliteks. Uuritav keelematerjal pärineb pildiseeria põhjal kogutud suulistest narratiividest. Uurimuses osales 20 eesti ja 20 soome keele

  7. Solid-phase extraction element based on epoxy polymer monolith for determination of polar organic compounds in aqueous media.

    Science.gov (United States)

    Takahashi, Tadashi; Odagiri, Kayo; Watanabe, Atsushi; Watanabe, Chuichi; Kubo, Takuya; Hosoya, Ken

    2011-10-01

    A solid-phase extraction element based on epoxy polymer monolith was fabricated for sorptive enrichment of polar compounds from liquid and gaseous samples. After ultrasonication of the element in an aqueous solution for a given period of time, the thermal desorption (TD) using a pyrolyzer with gas chromatography/mass spectrometry (GC/MS), in which TD temperature was programmed from 50 to 250 °C for the analytes absorbed in the element, was used to evaluate the element for basic extraction performance using the aqueous standard mixtures consisting of compounds having varied polarities such as hexanol, isoamyl acetate, linalool, furfural and decanoic acid, in concentrations ranging from 10 μg/L to 1 mg/L. Excellent linear relationships were observed for all compounds in the standard mixture, except decanoic acid. In the extraction of beverages such as red wine, the extraction element showed stronger adsorption characteristics for polar compounds such as alcohols and acids than a non-polar polydimethylsiloxane-based element. This feature is derived from the main polymer structure along with hydroxyl and amino groups present in the epoxy-based monolith polymer matrix. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Study in Vietnam on ingestion and organ content of trace elements of importance in radiological protection (Cs, I, Sr, U, Th etc.)

    International Nuclear Information System (INIS)

    Nguyen Mong Sinh

    2000-01-01

    This report presents results of our investigation work carried out from November 1996 to April 1998 in the field of 'Study in Vietnam on ingestion and organ content of trace elements of importance in Radiological Protection'. This work related to the Co-ordinated Research Programme for Reference Asian Man Project, Phase 2. The data reported are the daily individual intake of the elements of interest for some different socio-economic groups of Vietnamese population living in Hanoi, Hochiminh city Vinh Phu and Dalat areas. The obtained results showed that the average content for four elements (Cs, I, U, Th) in Vietnamese dietary intakes slightly changes from area to area in dependence on geographical, natural and socio-economical conditions, on type and composition of foods. (author)

  9. Inductively coupled plasma-mass spectrometry for elemental analysis and isotope ratio determinations in individual organic compounds separated by gas chromatography

    International Nuclear Information System (INIS)

    Chong, N.S.; Houk, R.S.

    1987-01-01

    A gas chromatograph (GC) with a packed column was interfaced to an inductively coupled plasma-mass spectrometer (ICP-MS) to yield atomic mass spectra from volatile organic compounds. Atomization of injected compounds was nearly complete and independent of molecular structure, so that elemental ratios could be determined. Detection limits were in the range 0.001 to 400 ng s -1 , depending on the ionization energy of the element and its abundance in the background spectrum. The relative standard deviation of measured isotope ratios varied from 0.4% for Br (i.e., a ratio close to unity) to 18% for N (a very large ratio). Thus, GC-ICP-MS provides elemental and isotope ratio information that is complementary to the molecular information derived from GC-MS with conventional ionization methods

  10. Decrease of concentration and colloidal fraction of organic carbon and trace elements in response to the anomalously hot summer 2010 in a humic boreal lake

    International Nuclear Information System (INIS)

    Shirokova, L.S.; Pokrovsky, O.S.; Moreva, O.Yu.; Chupakov, A.V.; Zabelina, S.A.; Klimov, S.I.; Shorina, N.V.; Vorobieva, T.Ya.

    2013-01-01

    The colloidal distribution and size fractionation of organic carbon (OC), major elements and trace elements (TE) were studied in a seasonally stratified, organic-rich boreal lake, Lake Svyatoe, located in the European subarctic zone (NW Russia, Arkhangelsk region). This study took place over the course of 4 years in both winter and summer periods using an in situ dialysis technique (1 kDa, 10 kDa and 50 kDa) and traditional frontal filtration and ultrafiltration (5, 0.22 and 0.025 μm). We observed a systematic difference in dissolved elements and colloidal fractions between summer and winter periods with the highest proportion of organic and organo-ferric colloids (1 kDa–0.22 μm) observed during winter periods. The anomalously hot summer of 2010 in European Russia produced surface water temperatures of approximately 30 °C, which were 10° above the usual summer temperatures and brought about crucial changes in element speciation and size fractionation. In August 2010, the concentration of dissolved organic carbon (DOC) decreased by more than 30% compared to normal period, while the relative proportion of organic colloids decreased from 70–80% to only 20–30% over the full depth of the water column. Similarly, the proportion of colloidal Fe decreased from 90–98% in most summers and winters to approximately 60–70% in August 2010. During this hot summer, measurable and significant (> 30% compared to other periods) decreases in the colloidal fractions of Ca, Mg, Sr, Ba, Al, Ti, Ni, As, V, Co, Y, all rare earth elements (REEs), Zr, Hf, Th and U were also observed. In addition, dissolved ( 100 for Co), the second and third factors could have brought about the decrease of allochthonous DOC concentration as well as the concentration and proportion of organic and organo-mineral colloidal forms of non-essential low-soluble trace elements present in the form of organic colloids (Al, Y, Ti, Zr, Hf, Th, Pb, all REEs). It can be hypothesized that climate warming in

  11. Contribution to the experimental study of transuranian element (Pu, Am, Cm) transfers between the various phases (particles, water, organisms) of the sedimentary system

    International Nuclear Information System (INIS)

    Grillo, M.C.

    1982-06-01

    The methodology of this work is first given. Transfer kinetics of 237 Pu, 241 Am and 242 Cm between seawater and macrofauna of loose substrates are studied. The effect of temperature and salinity over the transfers of 237 Pu, 241 Am and 242 Cm between water and bivalve mollusk Tapes decussatus is then studied. This work deals also with transfer kinetics of these elements between carnivorous organisms of the loose substrates and their preys. A preliminary study of 241 Am transfers between two phases, particles and interstitial water is finally presented: role of benthic burrowing organisms [fr

  12. Co-ordinated research project: ingestion and organ content of trace elements of importance in radiological protection. Reference Asian man project, phase 2

    International Nuclear Information System (INIS)

    1998-01-01

    This First Research Co-ordination Meeting on Ingestion and Organ Content of Trace Elements was held at the Hotel Rembrandt,Quezon City, the Philippines. Information on individual participant's plans for participation in the CRP, and the progress achieved so far on this and related topics is presented in each country's report. The major themes covered include sampling of diets and tissues, analytical techniques used, analytical quality assurance and data reporting of results

  13. Authentication of organically grown plants - advantages and limitations of atomic spectroscopy for multi-element and stable isotope analysis

    DEFF Research Database (Denmark)

    Laursen, Kristian Holst; Schjørring, Jan Kofod; Kelly, S.D.

    2014-01-01

    Organic food products are believed to be healthier, safer and more environment-friendly than their conventional counterparts and are sold at premium prices. Consequently, adulteration of organic plants and fraudulent activities for economic profit are increasing. This has spurred the development...... plant tissue, and compound-specific isotope analysis based on isotope ratio-mass spectrometry are promising tools for documenting the fertilization history of organic plants. However, these techniques are challenged by the potential diversity of fertilization practices of organic and conventional plant...

  14. Grupuskulaarne identiteediloome paremäärmuslaste võrgusuhtluses / The Formation of Groupuscular Identity in the Web Communication of the Estonian Extreme Right

    Directory of Open Access Journals (Sweden)

    Mari-Liis Madisson

    2015-06-01

    core Estonianness“ and protect it from foreign influences; the belief that the world order (including Estonian power structures are controlled by a secret alliance between Zionists and Masonic orders; the danger of mixing races and cultures; the need to exert strong state control over a range of areas of life; euroskepticism.  According to the authors of this article non-institutionalized extreme right movements operating in hypermedia have been most extensively examined by Roger Griffin’s research. Griffin has developed the concept of the groupuscule, which can be defined as small, political, (though almost never directly partypolitical unit in the context of contemporary extreme right-wing politics, and which strive toward revolutionary, ideological, organizational, and activist goals, the overall purpose of which is to overcome the decadence of the liberal democratic system.  Groupuscules can have diverse physical manifestations: webpages, magazines, and why not also underground meetings of extreme-right cell groups. Indeed, according to Griffin, groupuscules can be treated as non-nuclear cellular networks without a leader. The communication of groupuscules reflects the characteristics of hypermedia itself: nonhierarchical or network-like structure, internal multiplicity, the lack of a centre or a central axis of organization, fluidity, and temporariness, all of which are most often connected with the abstract textuality of the hypermedia environment.  In our view, the main limitation of Griffin’s account of groupuscules is the undertheorization of communication both within and among groupuscules. Too little attention has been directed to the primary mechanisms of meaning-creation, which organize navigation on the groupuscular information field and the development of hierarchies. In this article we aim to supplement Griffin’s theory of the groupsucule by means of a cultural-semiotic approach, particularly through the concepts of the semiosphere and the code text

  15. Redistribution of elements between wastes and organic-bearing material in the dispersion train of gold-bearing sulfide tailings: Part I. Geochemistry and mineralogy.

    Science.gov (United States)

    Saryg-Ool, B Yu; Myagkaya, I N; Kirichenko, I S; Gustaytis, M A; Shuvaeva, O V; Zhmodik, S M; Lazareva, E V

    2017-03-01

    Migration and redistribution of elements during prolonged interaction of cyanide wastes with the underlying natural organic-bearing material have been studied in two ~40cm deep cores that sample primary ores and their weathering profile (wastes I and II, respectively) in the dispersion train of gold-bearing sulfide tailings in Siberia. Analytical results of SR-XRF, whole-rock XRF, AAS, CHNS, and SEM measurements of core samples show high K, Sr, Ti, and Fe enrichments and correlation of P 2 O 5 and Mn with LOI and C org . Organic material interlayered or mixed with the wastes accumulates Cu, Zn, Se, Cd, Ag, Au, and Hg. The peat that contacts wastes II bears up to 3wt.% Zn, 1000g/t Se, 100g/t Cd, and 8000g/t Hg. New phases of Zn and Hg sulfides and Hg selenides occur as abundant sheaths over bacterial cells suggesting microbial mediation in sorption of elements. Organic-bearing material in the cores contains 10-30g/t Au in 2-5cm thick intervals, both within and outside the intervals rich in sulfides and selenides. Most of gold is invisible but reaches 345g/t and forms 50nm to 1.5μm Au 0 particles in a thin 2-3cm interval of organic remnants mixed with wastes I. Vertical and lateral infiltration of AMD waters in peat and oxidative dissolution of wastes within the dispersion train of the Ursk tailings lead to redistribution of elements and their accumulation by combined physical (material's permeability, direction AMD), chemical (complexing, sorption by organic matter and Fe(III) hydroxides) and biochemical (metabolism of sulfate-reducing bacteria) processes. The accumulated elements form secondary sulfates, and Hg and Zn selenides. The results provide insights into accumulation of elements in the early history of coal and black shale deposits and have implications for remediation of polluted areas and for secondary enrichment technologies. Copyright © 2017 Elsevier B.V. All rights reserved.

  16. Long-term use of biosolids as organic fertilizers in agricultural soils: potentially toxic elements occurrence and mobility.

    Science.gov (United States)

    Marguí, E; Iglesias, M; Camps, F; Sala, L; Hidalgo, M

    2016-03-01

    The presence of potentially toxic elements (PTEs) may hinder a more widespread application of biosolids in agriculture. At present, the European Directive 86/278/CEE limit the total concentrations of seven metals (Cu, Cr, Ni, Pb, Zn, Cd and Hg) in agricultural soils and in sewage sludges used as fertilizers but it has not taken into consideration the potential impacts of other emerging micropollutants that may be present in the biosolids as well as their mobility. The aim of this study was to evaluate the accumulation and mobility of 13 elements (including regulated metals and other inorganic species) in agricultural soils repeatedly amended with biosolids for 15 years. Firstly, three digestions programs using different acid mixtures were tested to evaluate the most accurate and efficient method for analysis of soil and sludge. Results demonstrated that sewage sludge application increased concentrations of Pb and Hg in soil, but values did not exceed the quality standard established by legislation. In addition, other elements (As, Co, Sb, Ag, Se and Mn) that at present are not regulated by the Spanish and European directives were identified in the sewage sludge, and significant differences were found between Ag content in soils amended with biosolids in comparison with control soils. This fact can be related to the increasing use of silver nanoparticles in consumer products due to their antibacterial properties. Results from the leaching tests show up that, in general, the mobility degree for both regulated and non-regulated elements in soils amended with biosolids was quite low (<10 %).

  17. The Contents of Selected Risk Elements and Organic Pollutants in Soil and Vegetation within a Former Military Area

    Czech Academy of Sciences Publication Activity Database

    Sladková, A.; Száková, J.; Havelcová, Martina; Najmanová, J.; Tlustoš, P.

    2015-01-01

    Roč. 24, č. 3 (2015), s. 325-342 ISSN 1532-0383 Institutional support: RVO:67985891 Keywords : Military area * risk elements * polycyclic aromatic hydrocarbons * mobility * plant-availability Subject RIV: DD - Geochemistry Impact factor: 1.189, year: 2015

  18. Regional patterns of labile organic carbon flux in North American Arctic Margin (NAAM) as reflected by redox sensitive-elements distributions in sediments

    Science.gov (United States)

    Gobeil, C.; Kuzyk, Z. Z. A.; Goni, M. A.; Macdonald, R. W.

    2016-02-01

    Concentrations of elements (S, Mn, Mo, U, Cd, Re) providing insights on organic C metabolized through oxidative processes at the sea floor were measured in 27 sediment cores collected along a section extending from the North Bering Sea to Davis Strait via the Canadian Archipelago. Sedimentary distributions and accumulation rates of these elements were used to i) document the relative importance of aerobic versus anaerobic degradation of organic C in NAAM sediments, ii) infer variations in water column carbon flux and iii) estimate the importance of this margin as a sink for key elements in the Arctic and global ocean. Distributions of Mn, total S and reduced inorganic S demonstrated that most sediments along the NAAM had relatively thick (>1 cm) surface oxic layers, underlain by sediments with weakly reducing conditions and limited sulphate reduction. Strongly reducing conditions accompanied by substantial sedimentary pyrite burial occurred only in certain subregions, including the Bering-Chukchi Shelves, shallow portions of Barrow Canyon. Estimated accumulation rates of authigenic S, Mo, Cd and U, and total Re displayed marked spatial variability that was related to sedimentary redox conditions induced by the supply of labile C to the seabed, as shown by significant relationships between the accumulation rates and vertical C flux, estimated from regional primary production values and water depth at the coring sites. High primary production combined with shallow water columns drive elevated rates of authigenic trace element accumulation in sediments from the Bering-Chukchi Shelves whereas low production combined with moderately deep conditions drive low rates of accumulation in sediments in the Beaufort Shelf, Davis Strait and Canadian Archipelago. Using the average authigenic trace element accumulation rates in sediments from the various regions, we submit that the shelves along the NAAM margin are important sinks in global marine biogeochemical budgets.

  19. Estonian energy system: Proposals for the implementation of a cogeneration strategy

    International Nuclear Information System (INIS)

    Lund, H.; Hvelplund, F.; Ingermann, K.; Kask, U.

    2000-01-01

    Since the Soviet era Estonia inherited oil-shale-based electricity plants, with a capacity of 3000 MW. Oil shale now provides Estonia with very low electricity prices. However, most of the stations are very old. Half of them were built before 1965, and sooner or later the old oil shale production units will have to be replaced. Estonia will then have to face serious increases in electricity production prices. At the same time Estonia has problems in restoring its district heating systems. The prices are rising and may consumers have converted to other heating sources such as electric heating. The major long-term strategic policy choices to make in Estonia are to decide (1) whether the oil shale power stations should be replaced by new centralized production units such as new oil shale stations or nuclear power, or (2) whether the electricity production should be decentralized. In the centralized solution (oil shale or nuclear power), the domestic heating will be left to boilers or electric heating leading to a very high primary energy supply. In the decentralized solution, Estonia could benefit from the advantage of cogeneration leading to very low fuel consumption. But this latter strategy depends on the restoration of the district heating systems. This article seeks to form a strategy to improve the efficiency of the Estonian energy system by increasing the use of cogeneration. (author)

  20. Vitality of the Estonian forests (results of the inventory and research)

    International Nuclear Information System (INIS)

    Karoles, K.

    1991-01-01

    Factors affecting Estonian forests are: The environmental, specially atmospheric pollution, - the foundation of new forests as monoculture on unsuitable locations, - mechanical damages by unsuitable forest machinery, - unfavourable water conditions, - Heterobasidion or Armillaria rot roots. Local damages in consequence of air pollutants are distributed in environments of Tallinn, Kivioli, Kohtla-Jaerve and the thermal power stations (Narva), where the SO 2 -content in the air is on the average higher than 50 (80) μg/m 3 . Pine forests on dry sand soils (600 ha damaged in 1989) and the older spruce forests show the new type of forest decline. High Al-ion concentration, disturbances of the Ca-Mg-metabolism, an extreme nutrient deficit, (specially N-deficit) and periodical water deficit as well as pathogenic fungi are damaging the trees. Spruces show nonspecific defoliation, needle necrosis, needlefall, occurence of fungal diseases. More damaged are the spruce forests in regions with basic precipitations and high sulphur-deposition. (orig./UWA) [de

  1. Gender differences in factors associated with sexual intercourse among Estonian adolescents.

    Science.gov (United States)

    Part, Kai; Rahu, Kaja; Rahu, Mati; Karro, Helle

    2011-06-01

    To examine factors associated with early sexual intercourse among 15 to 16-year-old adolescents by gender. The data were collected from a random sample of Estonian basic schools' ninth grade pupils in 1999 using self-completed questionnaires. A multivariate logistic regression analysis for boys and girls was used to test for associations between sexual intercourse, and personal gender role-related attitudes, attitudes towards sexual intercourse, pubertal timing, smoking status and experience of drunkenness. Of the respondents, 14.6% of boys and 13.1% of girls had experienced sexual intercourse. Traditional gender role-related attitudes were associated with sexual intercourse among girls, but not among boys. Smoking and experience of drunkenness was strongly associated with sexual intercourse for both genders. Gender differences in the association between gender role-related attitudes and early sexual intercourse were observed among 15 to 16-year-olds in Estonia. Smoking and experience of drunkenness were strongly related to sexual intercourse for both genders.

  2. Sexual behavior, depressive feelings, and suicidality among Estonian school children aged 13 to 15 years.

    Science.gov (United States)

    Heidmets, L; Samm, A; Sisask, M; Kõlves, K; Aasvee, K; Värnik, A

    2010-01-01

    The present paper is based on a WHO Collaborative Cross-National Study "Health Behavior in School-Aged Children (HBSC)." It aimed at describing and analyzing how the sexual behaviors of 13- to 15-year-old Estonian school children were associated with self-reported depressive feelings and suicidality. Distinctive behavioral traits in relation to age of first sexual intercourse were also investigated. Self-reported questionnaires from school children (n = 3,055) were analyzed. In total, 15.2% of school children reported being nonvirgin. Among 13-year-olds, 2.9% of girls and 6.8% of boys were nonvirgins. Approximately 25% of the 15-year-old girls and boys were nonvirgins. The likelihood of depressive feelings and suicidal ideation increased significantly in both genders with loss of virginity. Boys who had lost their virginity at 13 years or younger were 4.2 times more likely to have suicidal thoughts; comparable girls were 7.8 times more likely to have suicidal thoughts. Compared to virgins, youths who had lost their virginity reported poor self-assessed health and more risk behaviors in themselves and their peers. Experiences of sexual intercourse increased the odds ratios for depressive feelings and suicidality. The earlier sexual intercourse was initiated, the greater were the odds of lower mental well-being. Risk behaviors emerged as a complex phenomenon requiring complex prevention.

  3. Supervision, mentorship and peer networks: how Estonian early career researchers get (or fail to get support

    Directory of Open Access Journals (Sweden)

    Jaana Eigi

    2018-03-01

    Full Text Available The paper analyses issues related to supervision and support of early career researchers in Estonian academia. We use nine focus groups interviews conducted in 2015 with representatives of social sciences in order to identify early career researchers’ needs with respect to support, frustrations they may experience, and resources they may have for addressing them. Our crucial contribution is the identification of wider support networks of peers and colleagues that may compensate, partially or even fully, for failures of official supervision. On the basis of our analysis we argue that support for early career researchers should take into account the resources they already possess but also recognise the importance of wider academic culture, including funding and employment patterns, and the roles of supervisors and senior researchers in ensuring successful functioning of support networks. Through analysing the conditions for the development of early career researchers – producers of knowledge – our paper contributes to social epistemology understood as analysis of specific forms of social organisation of knowledge production.

  4. Elemental and isotopic characterization of organic particles in carbonaceous chondrites by NanoSIMS imaging: assessment on the origin, accretion and preservation of organic matter in chondrites

    Science.gov (United States)

    Remusat, L.; Guan, Y.; Eiler, J. M.

    2009-12-01

    Chondrites accreted primitive components, including organic compounds sampled from the proto-solar nebula. However, the molecular and isotopic fingerprints of organic matter extracted from chondrites are also potentially influenced by complex evolution on the parent bodies. We have performed NanoSIMS in situ characterisation of organic matter in the matrices of carbonaceous chondrites Orgueil (CI), Murchison (CM), Tagish Lake (C2), Renazzo (CR) and Allende (CV) with a spatial resolution of ~200 nm; we could also constrains textural relationships between organic constituents and other phases. Those meteorites have undergone a diverse set of parent body processes. I.e., CI, C2 and CM meteorites have undergone aqueous alteration, and the CV’s are thermally metamorphosed. The CR’s are inferred to be the least altered class of chondrites. Despite these differences in parent body modification, the distributions of organic carbon in these meteorites is similar: in all cases it can be found as micron-size, randomly distributed organic particles that are surrounded by the clay minerals that dominate the matrix material, but are not specifically associated with sulfides, sulfates or oxides. In addition, there is a “diffuse” fraction of organic carbon intimately associated with the clay-rich matrix. We hypothesize that the C particles we identify are hosts of insoluble organic matter that co-accreted with other primitive constituents of these materials, whereas the diffuse C fraction is the soluble component (i.e., soluble in laboratory organic and aqueous solvents). Our analytical technique lacks the spatial resolution required to analyze the diffuse organic matter without contamination by associated clays. But we are able to analyze the compositions of the interiors of relatively large C-rich particles (>500 nm) without such contamination. Some fraction of the C-rich particles in all of the examined meteorites but Allende exhibit a very high enrichment in deuterium

  5. Seltsi muuseumist riigi keskmuuseumiks: ikka ajutiste lahendustega / Changes in the Estonian National Museum from 1909 to the present.

    Directory of Open Access Journals (Sweden)

    Krista Aru

    2011-01-01

    Full Text Available Changes in the Estonian National Museum from 1909 to the presentThe Estonian National Museum was founded in Tartu in 1909 as part of the national movement. With its activities and connections in society, the ENM helped create Estonian society, the nation’s collective memory and identity.The ENM has always been – despite the changing locations, names, and content – one of the symbols of national identity. But at the same time, ENM has never had its own building designed specially for the museum’s purposes.Since 1909 there have been several attempts to establish a home for the ENM. At first (1909–1923, Estonian society wanted to establish the museum in the center of Tartu. The museum was intended to become a key institution of the growing nation and establishing the nation’s identity.At last in 1923 the ENM secured the Raadi manor, outside the center of the city, in a beautiful park, near the lake with its boats and water attractions. In this manor the first permanent exhibition of mainly 19th century Estonian peasant life was compiled, and the ENM operated in the Raadi manor from 1923–1940 as the “Estonian’s own museum” The years of alternating occupations, World War II, and political terror damaged and destroyed the whole society. The Raadi manor was destroyed in the war too, and the ENM itself was divided into two parts – the State Ethnographic Museum and the State Literary Museum. The collections of the ENM were given to Tallinn and to many different places inside and outside Tartu. Then began “the period of temporary location” that continues today. The museum is located in several places in the city of Tartu.In 1988, the prior name of the State Ethnographic Museum – the Estonian National Museum – was reinstated. Since the 1990s there have been many attempts to secure a special building for the ENM. Now, at last, as a result of serious economic pressure, we are closer to this goal than ever. During the last five

  6. Study in Vietnam on ingestion and organ content of trace elements of importance in radiological protection (I, Cr, Sr, Th, U etc.)

    International Nuclear Information System (INIS)

    Nguyen Mong Sinh

    1998-01-01

    To study on ingestion and organ content of trace elements of importance in Radiological Protection for population in Vietnam we need to select representative population groups. This can be done using some basic information about relevant ethnic, socioeconomic and geographical factors of Vietnam. It is also very importance to know the average food consumption, a characteristics and nutritive value of Vietnamese diet and the daily nutritional intake for this population groups. A general discussion have been made on proposal of sample collection, using analytical techniques to determine the elements of interest. There are also some primary results of analysis of iodine content in different kinds of foodstuffs in natural water and human urine. (author)

  7. Training of health care students and professionals: a pivotal element in the process of optimal organ donation awareness and professionalization.

    Science.gov (United States)

    Paez, G; Valero, R; Manyalich, M

    2009-01-01

    Successes in organ donation and transplantation programs are directly evidence-based education. Transplant Procurement Management (TPM) is an international educational project on organ donation and transplantation. Our purpose was to evaluate the TPM educational project. We compared the data of 17 years of experience, strategies, and methods. We retrospectively performed a descriptive analysis of all educational activities developed between 1991 and 2008. We identified 7 crucial points. (1) In 1991, TPM was started under the auspices of the University of Barcelona (UB) and the National Spanish Transplant Organization (ONT; national training, face-to-face). (2) In 1994, TPM became international (international advanced training and country-based). (3) Since 1997 in Italy and 2006 in France, national training courses were organized adapting the same methodologies as the advanced international TPM courses. TPM also implemented short (1-3 days) introductory courses worldwide. (4) In 2002, the e-learning platform program was launched to facilitate the education of professionals. (5) In 2005, an international master's degree was created at UB under the Life-Long Learning Institute (IL3). (6) In 2006, the courses were expanded to include pregraduate health science faculties with the International Project on Education and Research in Donation at University of Barcelona (PIERDUB). (7) In 2007, the European-funded European Training Program on Organ Donation (ETPOD) project was started. Currently, TPM offers face-to-face, e-learning, and blended international courses. As of 2008, TPM has trained 6498 professionals in 89 countries on 5 continents. TPM has impacted positively on the various essential levels in the process of organ donation and transplantation, with lifelong follow-up and an international network through the capacity to adapt to specific country needs as well as continuous quality improvement thanks to the collaboration of expert teachers and consultants.

  8. Implementation of quality assurance and quality control in the Nuclear Analytical Laboratory of the Estonian Radiation Protection Centre

    International Nuclear Information System (INIS)

    Koeoep, T.; Jakobson, E.

    2002-01-01

    The Analytical Laboratory of the Estonian Radiation Protection Centre is in the process of implementing the system of Quality Assurance (QA) and Quality Control (QC) in the framework of the IAEA TC Project RER/2/004/ 'QA/QC of Nuclear Analytical Techniques'. The draft Quality Manual with annexes has been prepared accordingly to the ISO 17025 Guide, documents and other printed material delivered on the seminars of the project. The laboratory supply has been supplemented with necessary equipment for guaranteeing of quality. Proficiency testing included in the project has been performed successfully. (author)

  9. Bernhard Linde. Noor-Eesti vooriülem. Bernhard Linde. Leader of the Young Estonian Pack

    OpenAIRE

    Jaanus Kulli

    2012-01-01

    Bernhard Linde (1886–1954) was a recognized and prolific Estonian theatre critic of the first quarter of the 20th century, who mediated and propagated western as well as eastern European theatrical innovations. In addition, he was active as a literary and art critic, publisher, and proponent of libraries, to a modest extent he was a prose writer and poet. Unquestionably, however, Bernhard Linde’s most prominent role was as one of the founding members of the literary movement Young Estonia. He...

  10. Jüri Okas’ ‘specific objects’: diverging discourses in Estonian Art in the 1970s.

    OpenAIRE

    Kurg, Andres.

    2003-01-01

    Previously in the University eprints HAIRST pilot service at http://eprints.st-andrews.ac.uk/archive/00000367/ Article 3 of 6 in issue devoted to the visual culture of the Scandinavian and Baltic region. This article will look at the early works of Estonian architect and artist Jüri Okas and will try to work between diverging languages and interpretations, reading works by Okas against the background of Anglo-american conceptualism and minimalism of the same period. The first part of th...

  11. Ingestion and organ content of trace elements of importance in radiological protection. Reference Asian man, phase-2

    International Nuclear Information System (INIS)

    Akhter, P.; Aslam, M.; Akram, M.; Rashid, A.; Orfi, S.D.

    2000-01-01

    The Second Phase of Reference Asian Man Project is in progress with the collaboration of IAEA under Regional Co-operative Agreement to strengthen the radiation protection infrastructure of the country. In this regard dietary samples are being collected from various ecological areas of Pakistan on market basket method. During this Project year, twenty two (22) diet samples were collected, prepared and stored for Neutron Activation Analysis. The stable radionuclides of our primary interest are Sr, Cs, Th, U, I, Ca and K whereas other essential and toxic elements have secondary importance. (author)

  12. Reference Asian man phase-2 entitled 'Ingestion and organ content of trace elements of importance in radiological protection'

    International Nuclear Information System (INIS)

    Akhter, P.; Hussain, M.; Orfi, S.D.; Atta, M.A.; Zaidi, J.H.; Arif, M.; Fatima, I.

    1998-01-01

    The second phase of Reference Asian Man project was started with the collaboration of IAEA to strengthen the radiation protection infra-structure of the country. In this regard dietary samples are being collected from various ecological areas of Pakistan. The sample collection is being made on market basket method. Four diet samples were collected, prepared and stored in the refrigerator for analysis with the help of Neutron Activation Analysis (NAA) . The stable radio nuclide of our interest are Sr, Cs, Th, U, I. The other minor, essential trace and toxic elements are Ca, K, Mg, Na, Cu, Fe, Mn, Sc, Zn, Cd, Hg, and Pb. (author)

  13. chemical studies on the reactivity of some organic extractants for extraction and separation of certain elements from aqueous solutions

    International Nuclear Information System (INIS)

    Aly, M.M.I.

    2010-01-01

    Lanthanide elements such as lanthanum and neodymium are important elements in photo-electronic and metallurgical industries as well as in nuclear technology. The main constituents of the spent nuclear fuel are actinides like uranium, thorium and various fission products including lanthanides. The co-ordination compounds of the trivalent lanthanum and neodymium continues to be an active research area, which includes the specific spectroscopic and magnetic properties of rare earth ions and their applications as super molecular device, contrast-enhancing agents in magnetic resonance imaging, optical signal amplifiers and electroluminescent (EL) devices. Hence, the separation and purification of these elements is of great concern. Solvent extraction technique is employed to separate and purify rare earth elements in an industrial scale, but the separation of lanthanum and neodymium is a difficult task, as lanthanide ions exhibit similar chemical and physical properties. They have generally common and stable +3 oxidation state that requires synthesis of certain extractants which are able to extract them from different aqueous solutions. During the last twenty years, different publications have pointed out the remarkable properties of alkyl amide in the field of separation chemistry. These extractants are able to form stable co-ordination compounds with different metallic ions. In this concern, this thesis deals with the synthesis of different amide extractants namely N, N diethylacetoamide (DEAA), N, N Teteraphenyl malonamide (TPMA), N, N diphenylbenzamide (DPBA), N, N' diphenylacetoamide (DPAA), and N, N' Teteraethyl malonamide (TEMA), which were synthesized, characterized and compared with Aliquat-336 in kerosene for extraction and separation of La (III) and Nd (III). The effect of the different parameters affecting the extraction of these metals from aqueous nitric acid medium in the different systems has been studied in terms of shaking time, nitric acid, hydrogen

  14. Study of the trace element in organisms by neutron activation analysis, 1. Multielement instrumental neutron activation analysis of cannabis

    Energy Technology Data Exchange (ETDEWEB)

    Shinogi, M; Murai, Y; Mori, I [Kobe Women' s Coll. of Pharmacy (Japan); Takeuchi, T

    1974-12-01

    Examinations were made on optimal experimental conditions for instrumental determination of various elements in cannabis by neutron activation analysis, without any radiochemical separation, and the following conditions were found to be useful. Irradiation samples to be used are about 300 mg of the leaves or stem bark, and about 100 mg of the root. For soil sample, about 50 mg is used for the determination of short half-life nuclides and about 300 mg for long half-life nuclides. For short half-life nuclides, the samples are irradiated for 1 min, activity is measured for 200 sec after a decay of 3 min, and for 400 sec after a decay of 10 min. For long half-life nuclides, the samples are irradiated for 60 min and the activites are measured for 4 K sec after 1 week and for 10 K sec after 1 month. Use of supersonic waves is also convenient for cleansing of the samples. Thirty-five kinds of interesting elements were determined by this method from cannabis cultivated in Maizuru area.

  15. The study of the trace element in organisms by neutron analysis. I. Multielement instrumental neutron activation analysis of cannabis

    International Nuclear Information System (INIS)

    Shinogi, M.; Murai, Y.; Mori, I.; Takeuchi, T.

    1977-05-01

    Examinations were made on optimal experimental conditions for instrumental determination of various elements in cannabis by neutron activation analysis, without any radiochemical separation, and the following conditions were found to be useful. Irradiation samples to be used are about 300 mg of the leaves or stem bark, and about 100 mg of the root. For soil sample, about 50 mg is used for the determination of short half-life nuclides and about 300 mg for long half-life nuclides. For short half-life nuclides, the samples are irradiated for 1 min, activity is measured for 200 sec after a decay of 3 min, and for 400 sec after a decay of 10 min. For long half-life nuclides, the samples are irradiated for 60 min and the activities are measured for 4 K sec after 1 week and for 10 K sec after 1 month. Use of supersonic waves is also convenient for cleansing of the samples. Thirty-five kinds of interesting elements were determined by this method from cannabis cultivated in Maizuru area. (Author)

  16. Patient-specific non-linear finite element modelling for predicting soft organ deformation in real-time: application to non-rigid neuroimage registration.

    Science.gov (United States)

    Wittek, Adam; Joldes, Grand; Couton, Mathieu; Warfield, Simon K; Miller, Karol

    2010-12-01

    Long computation times of non-linear (i.e. accounting for geometric and material non-linearity) biomechanical models have been regarded as one of the key factors preventing application of such models in predicting organ deformation for image-guided surgery. This contribution presents real-time patient-specific computation of the deformation field within the brain for six cases of brain shift induced by craniotomy (i.e. surgical opening of the skull) using specialised non-linear finite element procedures implemented on a graphics processing unit (GPU). In contrast to commercial finite element codes that rely on an updated Lagrangian formulation and implicit integration in time domain for steady state solutions, our procedures utilise the total Lagrangian formulation with explicit time stepping and dynamic relaxation. We used patient-specific finite element meshes consisting of hexahedral and non-locking tetrahedral elements, together with realistic material properties for the brain tissue and appropriate contact conditions at the boundaries. The loading was defined by prescribing deformations on the brain surface under the craniotomy. Application of the computed deformation fields to register (i.e. align) the preoperative and intraoperative images indicated that the models very accurately predict the intraoperative deformations within the brain. For each case, computing the brain deformation field took less than 4 s using an NVIDIA Tesla C870 GPU, which is two orders of magnitude reduction in computation time in comparison to our previous study in which the brain deformation was predicted using a commercial finite element solver executed on a personal computer. Copyright © 2010 Elsevier Ltd. All rights reserved.

  17. Understanding the partitioning and concentration of trace elements in the plant organs of some food crops : influence of the plant allometry and of the growth stage

    OpenAIRE

    Liñero Campo , Olaia

    2016-01-01

    This work is focuded on the accumulation of essential and non-essential elements, paying a special attention to the dible part of the plants, in terms of food safety and human health. The thesis work has been divided in two main parts. The first one is related to a field expeiment performed in open-air plots, where Swiss chards and tomato plants were grown from seedlings to maturity in a natural soil during five months, using organic or conventional agricultural practices. Plants were harvest...

  18. Certification of the methylmercury content in SRM 2977 mussel tissue (organic contaminants and trace elements) and SRM 1566b oyster tissue.

    Science.gov (United States)

    Tutschku, S; Schantz, M M; Horvat, M; Logar, M; Akagi, H; Emons, H; Levenson, M; Wise, S A

    2001-02-01

    The methylmercury content in two new marine bivalve mollusk tissue Standard Reference Materials (SRMs) has been certified using results of analyses from the National Institute of Standards and Technology (NIST) and two other laboratories. The certified concentrations of methylmercury were established based on the results from four and six different (independent) analytical methods, respectively, for SRM 1566b Oyster Tissue (13.2 +/- 0.7 microg/kg) and SRM 2977 Mussel Tissue (organic contaminants and trace elements) (36.2 +/- 1.7 microg/kg). The certified concentration of methylmercury in SRM 1566b is among the lowest in any certified reference material (CRM).

  19. The Baltic Klint beneath the central Baltic Sea and its comparison with the North Estonian Klint

    Science.gov (United States)

    Tuuling, Igor; Flodén, Tom

    2016-06-01

    Along its contact with the Baltic Shield, the margin of the East European Platform reveals a well-developed, flooded terraced relief. The most striking and consistent set of escarpments at the contact of the Lower Palaeozoic calcareous and terrigenous rocks, known as the Baltic Klint (BK), extends from northwest of Russia to the Swedish island of Öland. Marine seismic reflection profiling in 1990-2004 revealed the central Baltic Sea Klint (BSK) section in detail and enabled comparison of its geology/geomorphology with a classical klint-section onshore, namely the North Estonian Klint (NEK). The conception of the BK onshore, which is based on the land-sea separating terraced relief in northern Estonia, is not fully applicable beneath the sea. Therefore, we consider that the BSK includes the entire terraced Cambrian outcrop. We suggest the term "Baltic Klint Complex" to include the well-terraced margin of the Ordovician limestone outcrop, which is weakly developed in Estonia. Because of a steady lithological framework of the bedrock layers across the southern slope of the Fennoscandian Shield, the central BSK in the western and the NEK in the eastern part of the Baltic Homocline have largely identical morphologies. The North Estonian Ordovician limestone plateau with the calcareous crest of the BK extends across the central Baltic Sea, whereas morphological changes/variations along the Klint base occur due to the east-westerly lithostratigraphic/thickness changes in the siliciclastic Cambrian sequence. The verge of the NEK, located some 30-50 m above sea level, starts to drop in altitude as its east-westerly course turns to northeast-southwest in western Estonia. Further westwards, the BK shifts gradually into southerly deepening (0.1-0.2°) layers as its crest drops to c. 150 m below sea level (b.s.l.) near Gotska Sandön. This course change is accompanied by a considerable decrease in thickness of the platform sedimentary cover, as below the central Baltic Sea the

  20. Organics.

    Science.gov (United States)

    Chian, Edward S. K.; DeWalle, Foppe B.

    1978-01-01

    Presents water analysis literature for 1978. This review is concerned with organics, and it covers: (1) detergents and surfactants; (2) aliphatic and aromatic hydrocarbons; (3) pesticides and chlorinated hydrocarbons; and (4) naturally occurring organics. A list of 208 references is also presented. (HM)

  1. Organizers.

    Science.gov (United States)

    Callison, Daniel

    2000-01-01

    Focuses on "organizers," tools or techniques that provide identification and classification along with possible relationships or connections among ideas, concepts, and issues. Discusses David Ausubel's research and ideas concerning advance organizers; the implications of Ausubel's theory to curriculum and teaching; "webbing," a…

  2. Temporal and Spatial variations in Organic and Elemental carbon concentrations in PM10/PM2.5 in the Metropolitan Area of Costa Rica, Central America

    Science.gov (United States)

    Campos-Ramos, A.; Herrera Murillo, J.; Rodriguez-Roman, S.; Cardenas, B.; Blanco-Jimenez, S.

    2011-12-01

    During 2010-2011, as part of a Binational Cooperation Project between Mexico and Costa Rica, samples collected weekly in 15 and 5 sites for PM10 and PM2,5 respectively, in the Metropolitan area of Costa Rica, a region of 2.5 million habitants. Based on the high PM2.5 mass concentrations found (17-38 μg/m3), samples were analyzed to determinate the organic and elemental carbon concentrations using DRI Model 2001 Thermal/Optical Carbon Analyzer (Atmoslytic Inc., Calabasas, CA, USA). Organic (OC) and Elemental (EC) carbon concentrations exhibited a clear seasonal pattern with higher concentrations in the rainy period than in the dry period, due to cooperative effects of changes in emission rates and seasonal meteorology. Spatial variations in carbonaceous species concentrations were observed mostly influenced by the local sources at the different sampling sites in the following magnitude of contribution: vehicle emissions > industrial > agricultural burning. Total carbonaceous aerosol accounted for 42.7% and 26.8% of PM2.5 mass in rainy and dry period, respectively. Good correlation (R = 0.87-0.93) between OC and EC indicated that they had common dominant sources of combustion such as heavy fuels used in industries and traffic emissions. The estimated secondary organic carbon (SOC) accounted for 46.9% and 35.3% of the total OC in the rainy and dry period, respectively, indicating that SOC may be an important contributor to fine organic aerosol in the Metropolitan Area of Costa Rica. These results will be used to improve the National Emissions Inventory, particularly for PM2.5.

  3. Concentrations of Trace Elements in Organic Fertilizers and Animal Manures and Feeds and Cadmium Contamination in Herbal Tea (Gynostemma pentaphyllum Makino).

    Science.gov (United States)

    Nookabkaew, Sumontha; Rangkadilok, Nuchanart; Prachoom, Norratouch; Satayavivad, Jutamaad

    2016-04-27

    Thailand is predominantly an agriculture-based country. Organic farming is enlisted as an important national agenda to promote food safety and international export. The present study aimed to determine the concentrations of trace elements in commercial organic fertilizers (fermented and nonfermented) composed of pig and cattle manures available in Thailand. Pig and cattle manures as well as animal feeds were also collected from either animal farms or markets. The results were compared to the literature data from other countries. Fermented fertilizer composed of pig manure contained higher concentrations of nitrogen (N) and phosphorus (P) than fertilizer composed of cattle manure. High concentrations of copper (Cu) and zinc (Zn) were also found in fertilizers and manures. Some organic fertilizers had high concentrations of arsenic (As), cadmium (Cd), and lead (Pb). The range of As concentration in these fertilizers was 0.50-24.4 mg/kg, whereas the ranges of Cd and Pb were 0.10-11.4 and 1.13-126 mg/kg, respectively. Moreover, pig manure contained As and Cd (15.7 and 4.59 mg/kg, respectively), higher than their levels in cattle manure (1.95 and 0.16 mg/kg, respectively). The use of pig manure as soil supplement also resulted in high Cd contamination in herbal tea (Gynostemma pentaphyllum Makino; GP). The Cd concentration in GP plants positively correlated with the Cd concentration in the soil. Therefore, the application of some organic fertilizers or animal manures to agricultural soil could increase some potentially toxic elements in soil, which may be absorbed by plants and, thus, increase the risk of contamination in agricultural products.

  4. Attitudes of Academic Staff towards Their Own Work and towards External Evaluation, from the Perspective of Self-Determination Theory: Estonian Case

    Science.gov (United States)

    Seema, Riin; Udam, Maiki; Mattisen, Heli

    2016-01-01

    The purpose of this study was to ascertain the attitudes of academic staff towards their own work as well as towards external evaluations. The study was based on (1) an analysis of assessment reports of institutional accreditations conducted by the Estonian Quality Agency for Higher and Vocational Education and (2) self-determination theory on…

  5. “... if there’s a party, then there’s definitely alcohol”. Construction of partying practices and abstinence in Estonian youth forums

    Directory of Open Access Journals (Sweden)

    Parder Mari-Liisa

    2015-12-01

    Full Text Available AIMS – Adolescents’ abstinence from alcohol has not been much researched in terms of providing suggestions for prevention strategies. This study aims to fill that gap by offering a practice theory-inspired analysis of how the unwritten rules of partying practices are communicated between posters of Estonian youth forums.

  6. Corporate Governance from the Perspective of Stakeholder Theory and in Light of Perceptions among Estonian Owners and Managers of Relations with Stakeholders / Mari Kooskora

    Index Scriptorium Estoniae

    Kooskora, Mari, 1969-

    2006-01-01

    Äriühingute valitsemise kontseptsioon ja teoreetiline taust; Eesti omanike ja tippjuhtide ootused suhetes erinevate huvigruppidega ning äriühingute valitsemine huvigruppide teooriast lähtudes. Skeem: The stakeholder model. Tabelid: Contractual and community stakeholders; Overview of how perceptions of the main stakeholder groups among Estonian business leaders between 1995-2004 have changed

  7. Economic modelling of the capture-transport-sink scenario of industrial CO2 emissions: The Estonian-Latvian cross-border case study

    NARCIS (Netherlands)

    Shogenova, A.; Shogenov, K.; Pomeranceva, R.; Nulle, I.; Neele, F.; Hendriks, C.

    2011-01-01

    Industrial CO2 emissions and opportunities for CO2 geological storage in the Baltic Region were studied within the EU GeoCapacity project supported by the European Union Framework Programme 6. Estonia produces the largest amounts of CO2 emissions in the region, due to the combustion of Estonian oil

  8. The Role of Parents and Parental Mediation on 0-3-Year Olds' Digital Play with Smart Devices: Estonian Parents' Attitudes and Practices

    Science.gov (United States)

    Nevski, Elyna; Siibak, Andra

    2016-01-01

    In this manuscript, we analyse the attitudes and practices of Estonian parents (N = 198) who allowed their 0-3-year olds to use smart devices. We aimed to discover if there was an interaction between parental use of smart technologies, parents' attitudes and the child's age that would predict young children's usage of smart devices. We also wanted…

  9. Occurrence of clinical mastitis in primiparous Estonian dairy cows in different housing conditions

    Directory of Open Access Journals (Sweden)

    Aasmäe Birgit

    2006-11-01

    Full Text Available Abstract Background Objectives of the study were to document the impact of some management factors on the occurrence of clinical mastitis in primiparous dairy cows and to identify common udder pathogens of clinical mastitis in freshly calved heifers and multiparous cows on the day of calving. Methods A one-year study was conducted during 2004 and 2005 in 11 selected Estonian dairy herds. Data consisted of 68 heifers with clinical mastitis and 995 heifers without clinical mastitis on the day of calving. Multivariable logistic regression with a random herd effect was used to investigate any association between housing system or the time interval from movement of heifers to the calving facility and day of calving on occurrence of clinical mastitis. Milk samples for bacteriological analysis were collected from affected heifers and multiparous cows on the day of calving Results Clinical mastitis occurrence in the study population of freshly calved heifers equalled 6.1 %. Housing system was not a significant risk factor for clinical mastitis of freshly calved heifers. Moving heifers to the cowbarn less than two weeks before calving in tiestall farms increased risk (OR = 5.9 p = 0.001 for clinical mastitis at parturition. The most frequently isolated udder pathogens among heifers were Escherichia coli (22.1%, Streptococcus uberis (19.1% and coagulase-negative staphylococci (8.8%. In comparison, the main pathogen in multiparous cows with clinical mastitis at parturition was Staphylococcus aureus (11.2%. Conclusion Moving heifers to the calving facilities too late in tiestall farms increased risk for clinical mastitis at parturition. The isolated udder pathogens did not differ significantly in tiestall farms compared to freestall farms in heifers, but differences were found between heifers and multiparous cows at parturition.

  10. Non-cancer morbidity among Estonian Chernobyl cleanup workers: a register-based cohort study.

    Science.gov (United States)

    Rahu, Kaja; Bromet, Evelyn J; Hakulinen, Timo; Auvinen, Anssi; Uusküla, Anneli; Rahu, Mati

    2014-05-14

    To examine non-cancer morbidity in the Estonian Chernobyl cleanup workers cohort compared with the population sample with special attention to radiation-related diseases and mental health disorders. Register-based cohort study. Estonia. An exposed cohort of 3680 men (cleanup workers) and an unexposed cohort of 7631 men (population sample) were followed from 2004 to 2012 through the Population Registry and Health Insurance Fund database. Morbidity in the exposed cohort compared with the unexposed controls was estimated in terms of rate ratio (RR) with 95% CIs using Poisson regression models. Elevated morbidity in the exposed cohort was found for diseases of the nervous system, digestive system, musculoskeletal system, ischaemic heart disease and for external causes. The most salient excess risk was observed for thyroid diseases (RR=1.69; 95% CI 1.38 to 2.07), intentional self-harm (RR=1.47; 95% CI 1.04 to 2.09) and selected alcohol-related diagnoses (RR=1.25; 95% CI 1.12 to 1.39). No increase in morbidity for stress reactions, depression, headaches or sleep disorders was detected. No obvious excess morbidity consistent with biological effects of radiation was seen in the exposed cohort, with the possible exception of benign thyroid diseases. Increased alcohol-induced morbidity may reflect alcohol abuse, and could underlie some of the higher morbidity rates. Mental disorders in the exposed cohort were probably under-reported. The future challenge will be to study mental and physical comorbidities in the Chernobyl cleanup workers cohort. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://group.bmj.com/group/rights-licensing/permissions.

  11. Personality traits and eating habits in a large sample of Estonians.

    Science.gov (United States)

    Mõttus, René; Realo, Anu; Allik, Jüri; Deary, Ian J; Esko, Tõnu; Metspalu, Andres

    2012-11-01

    Diet has health consequences, which makes knowing the psychological correlates of dietary habits important. Associations between dietary habits and personality traits were examined in a large sample of Estonians (N = 1,691) aged between 18 and 89 years. Dietary habits were measured using 11 items, which grouped into two factors reflecting (a) health aware and (b) traditional dietary patterns. The health aware diet factor was defined by eating more cereal and dairy products, fish, vegetables and fruits. The traditional diet factor was defined by eating more potatoes, meat and meat products, and bread. Personality was assessed by participants themselves and by people who knew them well. The questionnaire used was the NEO Personality Inventory-3, which measures the Five-Factor Model personality broad traits of Neuroticism, Extraversion, Openness, Agreeableness, and Conscientiousness, along with six facets for each trait. Gender, age and educational level were controlled for. Higher scores on the health aware diet factor were associated with lower Neuroticism, and higher Extraversion, Openness and Conscientiousness (effect sizes were modest: r = .11 to 0.17 in self-ratings, and r = .08 to 0.11 in informant-ratings, ps < 0.01 or lower). Higher scores on the traditional diet factor were related to lower levels of Openness (r = -0.14 and -0.13, p < .001, self- and informant-ratings, respectively). Endorsement of healthy and avoidance of traditional dietary items are associated with people's personality trait levels, especially higher Openness. The results may inform dietary interventions with respect to possible barriers to diet change.

  12. The Estonian study of Chernobyl cleanup workers: I. Design and questionnaire data

    International Nuclear Information System (INIS)

    Tekkel, M.; Rahu, M.; Veidebaum, T.

    1997-01-01

    Nearly 2% of the male population of Estonia aged 20-39 years were sent to Chernobyl to assist in the cleanup activities after the reactor accident. A cohort of 4,833 cleanup workers was assembled based on multiple and independent sources of information. Information obtained from 3,704 responses to a detailed questionnaire indicated that 63% of the workers were sent to Chernobyl in 1986; 54% were of Estonian and 35% of Russian ethnicity; 72% were married, and 1,164 of their 5,392 children were conceived after the Chernobyl disaster. The workers were less educated than their counterparts than their counterparts in the general population of Estonia, and only 8.5% had attended university. Based on doses entered in workers records, the mean dose was 11 cGy, with only 1.4% over 25 cGy. Nearly 85% of the workers were sent as part of military training activities, and more than half spent in excess of 3 months in the Chernobyl area. Thirty-six percent of the workers reported having worked within the immediate vicinity of the accident site; 11.5% worked on the roofs near the damaged reactor, clearing the highly radioactive debris. The most commonly performed task was the removal and burial of topsoil (55% of the workers). Potassium iodide was given to over 18% of the men. The study design also incorporates biological indicators of exposure based on the glycophorin A mutational assay of red blood cells and chromosome translocation analyses of lymphocytes; record linkage with national cancer registry and mortality registry files to determine cancer incidence and cause-specific mortality; thyroid screening examinations with ultrasound and fine-needle biopsy; and cryopreserved white blood cells and plasma for future molecular studies. Comprehensive studies of Chernobyl cleanup workers have potential to provide a new information about cancer risks due to protracted exposures to ionizing radiation. 21 refs., 1 fig., 11 tabs

  13. Omaeluloolisus eesti teatris: Merle Karusoo lavastustest. Life Narratives and Estonian Theatre: The Productions of Merle Karusoo

    Directory of Open Access Journals (Sweden)

    Piret Kruuspere

    2012-04-01

    Full Text Available Any consideration of Estonian theatre from the point of view of biographical theatre needs to include the work of playwright and director Merle Karusoo. Productions based on various life narratives (diaries, letters, biographical interviews form the core of her work that can be defined as biographical or memory theatre. Her work has also been viewed within the context of community theatre or political theatre; Karusoo has herself referred to her work as sociological theatre. Life narratives have functioned in Karusoo’s productions as the basis for restoring oppressed or denied collective discourses of memory. Her productions emerged within the framework of the more general process of restoration of historical heritage and the rehabilitation of collective memory at the end of the 1980s and the beginning of the 1990s. Life story can be viewed as the essence of Merle Karusoo’s theatre. The personal in the life story in the production activates the emotional memory of the audience; for older generations such theatre facilitates a legitimisation of remembering one’s life story in entirety, and for younger generations it functions as a vehicle of collective, historical and national memory. The current article outlines the main stages of Karusoo’s biographical theatre, highlights major productions of each stage and provides an overview of their reception. Karusoo’s theatre dates back to 1980s. Productions based on life stories of the generations born in 1950s and 1960s, Meie elulood (Our Biographies and Kui ruumid on täis ... (Full Rooms both in 1982, mediated fragments of life stories of 16 drama students, focusing on the processes of self-conception and -reflection of young persons. In the context of the Soviet regime that exerted firm ideological control over the private lives of its citizens, Karusoo’s productions struck an especially powerful and unusual chord. Karusoo’s biographical theatre has gathered momentum and assumed a more

  14. Euroopa-ihalusest taasiseseisvusperioodi autobiograafiates / European Identifications in Post-Soviet Estonian Life Writing

    Directory of Open Access Journals (Sweden)

    Leena Kurvet-Käosaar

    2016-12-01

    Full Text Available Teesid: Artikkel käsitleb Euroopat kui identiteedi ja minaduse sõlmpunkti ja enesevahenduse mõõdet kolmes omaelulookirjutuslikus teoses, mille autoritel on väljapaistev positsioon eesti (kirjanduskultuuris: Jaan Krossi „Kallid kaasteelised“ (2003a, 2008, Jaan Kaplinski „Isale“ (2003 ja Tõnu Õnnepalu „Flandria päevik“ (2007. Artikkel keskendub sellele, kuidas küsimused suhestumise trajektooridest Euroopa mäluruumiga haakuvad Krossi, Kaplinski ja Õnnepalu teostes esiletuleva enesemääratlusliku raamiga, neist lähtuvate vastastikuse kõnetuse võimaluste ja oma aegruumi tunnetuse pidepunktidega. Kuigi tegemist on eesti keeles ilmunud ning eesti kultuuriruumi lugejale suunatud teostega, seostuvad neis väljajoonistuvad enesemääratluse teljed viimastel aastakümnetel hoogustunud laiemate aruteludega ühtse Euroopa mäluraami ning identiteedi võimalikkusest ja selle toimimise tingimustest.   In recent years, the question of the possibility of a shared frame of memory and identity in Europe, its desired manifestations and practices for attaining it as well as its obstacles and limitations to it have gained prominence in scholarly debates in a number of disciplines. In terms of the division between the East and West of Europe, these discussions take as their starting point the collapse of the Soviet system in 1989 as well as the European Union enlargement in 2004. Far from uniform, the exceedingly complex and contrasting ranges of arguments have put forward a varied palette of perspectives and suggestions about possible and desirable implications of Europe in different socio-political and cultural configurations. Taking these debates as my starting point, the current article offers an analysis of three life writing works by contemporary Estonian authors and intellectuals, Kallid kaasteelised (Dear Fellow Travellers, 2003, 2008 by Jaan Kross, Isale (To My Father, 2003 by Jaan Kaplinski and Flandria päevik (The Flemish Diary

  15. Characterization of organic matter in sediment cores of the Todos os Santos Bay, Bahia, Brazil, by elemental analysis and 13C NMR

    International Nuclear Information System (INIS)

    Costa, A.B.; Novotny, E.H.; Bloise, A.C.; Azevedo, E.R. de; Bonagamba, T.J.; Zucchi, M.R.; Santos, V.L.C.S.; Azevedo, A.E.G.

    2011-01-01

    Highlights: → The impact of human activity on the sediments of Todos os Santos Bay in Brazil was evaluated by EA and 13 C NMR. → This article reports a study of six sediment cores collected at different depths and regions. → The elemental profiles of cores suggest an abrupt change in the sedimentation regime, corresponds to about 50 years ago, coinciding with the implantation of major onshore industrial projects. → The results presented illustrate several important aspects of environmental impact of human activity on this bay. - Abstract: The impact of human activity on the sediments of Todos os Santos Bay in Brazil was evaluated by elemental analysis and 13 C Nuclear Magnetic Resonance ( 13 C NMR). This article reports a study of six sediment cores collected at different depths and regions of Todos os Santos Bay. The elemental profiles of cores collected on the eastern side of Frades Island suggest an abrupt change in the sedimentation regime. Autoregressive Integrated Moving Average (ARIMA) analysis corroborates this result. The range of depths of the cores corresponds to about 50 years ago, coinciding with the implantation of major onshore industrial projects in the region. Principal Component Analysis of the 13 C NMR spectra clearly differentiates sediment samples closer to the Subae estuary, which have high contents of terrestrial organic matter, from those closer to a local oil refinery. The results presented in this article illustrate several important aspects of environmental impact of human activity on this bay.

  16. Effects of biochar and greenwaste compost amendments on mobility, bioavailability and toxicity of inorganic and organic contaminants in a multi-element polluted soil

    Energy Technology Data Exchange (ETDEWEB)

    Beesley, Luke, E-mail: L.Beesley@2007.ljmu.ac.u [Faculty of Science, Liverpool John Moores University, Liverpool L3 3AF (United Kingdom); Moreno-Jimenez, Eduardo [Departamento de Quimica Agricola, Universidad Autonoma de Madrid, 28049 Madrid (Spain); Gomez-Eyles, Jose L. [University of Reading, Department of Soil Science, Whiteknights, Reading RG6 6DW (United Kingdom)

    2010-06-15

    Applying amendments to multi-element contaminated soils can have contradictory effects on the mobility, bioavailability and toxicity of specific elements, depending on the amendment. Trace elements and PAHs were monitored in a contaminated soil amended with biochar and greenwaste compost over 60 days field exposure, after which phytotoxicity was assessed by a simple bio-indicator test. Copper and As concentrations in soil pore water increased more than 30 fold after adding both amendments, associated with significant increases in dissolved organic carbon and pH, whereas Zn and Cd significantly decreased. Biochar was most effective, resulting in a 10 fold decrease of Cd in pore water and a resultant reduction in phytotoxicity. Concentrations of PAHs were also reduced by biochar, with greater than 50% decreases of the heavier, more toxicologically relevant PAHs. The results highlight the potential of biochar for contaminated land remediation. - Biochar was more effective than greenwaste compost at reducing bioavailable fractions of phytotoxic Cd and Zn as well as the heavier, more toxicologically relevant PAHs.

  17. Bioavailable concentrations of germanium and rare earth elements in soil as affected by low molecular weight organic acids and root exudates

    Science.gov (United States)

    Wiche, Oliver; Székely, Balázs; Kummer, Nicolai-Alexeji; Heinemann, Ute; Tesch, Silke; Heilmeier, Hermann

    2014-05-01

    Availability of elements in soil to plant is generally dependent on the solubility and mobility of elements in soil solution which is controlled by soil, elemental properties and plant-soil interactions. Low molecular organic acids or other root exudates may increase mobility and availability of certain elements for plants as an effect of lowering pH in the rhizosphere and complexation. However, these processes take place in a larger volume in soil, therefore to understand their nature, it is also important to know in which layers of the soil what factors modify these processes. In this work the influence of citric acid and root exudates of white lupin (Lupinus albus L.) on bioavailable concentrations of germanium, lanthan, neodymium, gadolinium and erbium in soil solution and uptake in root and shoot of rape (Brassica napus L.), comfrey (Symphytum officinale L.), common millet (Panicum milliaceum L.) and oat (Avena sativa L.) was investigated. Two different pot experiments were conducted: (1) the mentioned plant species were treated with nutrient solutions containing various amount of citric acid; (2) white lupin was cultivated in mixed culture (0 % lupin, 33 % lupin) with oat (Avena sativa L.) and soil solution was obtained by plastic suction cups placed at various depths. As a result, addition of citric acid significantly increased germanium concentrations in plant tissue of comfrey and rape and increased translocation of germanium, lanthan, neodymium, gadolinium and erbium from root to shoot. The cultivation of white lupin in mixed culture with oat led to significantly higher concentrations of germanium and increasing concentrations of lanthan, neodymium, gadolinium and erbium in soil solution and aboveground plant tissue. In these pots concentrations of citric acid in soil solution were significantly higher than in the control. The results show, that low molecular organic acids exuded by plant roots are of great importance for the mobilization of germanium

  18. Isamaalaulud ja okupatsioonirežiim – nostalgia, utoopia ja reaalsus. Estonian Patriotic Songs and the Occupational Regime – Nostalgia, Utopia and Reality

    Directory of Open Access Journals (Sweden)

    Kanni Labi

    2012-04-01

    Full Text Available Estonian knowledge of history emanates from the fact that constituting an independent nation has for the most part been nothing but a utopia, and was a reality for a relatively short time. When it comes to selfidentification though, the expression ’a singing people’ is often used by the Estonians to describe themselves. Nostalgia for freedom is reflected in the Estonian culture of almost all periods and is carried on by the singing tradition, where patriotic songs emerge independent of different musical tastes within a particular generation and form an important part of a common Estonian repertoire. Patriotic songs occupy a central place in several fields of Estonian culture: besides music culture also in popular culture,and literary history – the works of poetry which have gained the most popularity are those which when put to music have been the most widely spread among the people. The main part of the most popular Estonian patriotic songs are choral songs from the national awakening at the end of the 19th century. Despite the national programmes aiming to wipe out ‘bourgeois nationalism’, they were sung at the song festivals in the Soviet era and were published in song books, expressing the people’s nostalgia for freedom lost. After the end of the Second World War, there was an attempt at launching a kind of patriotic new creation, where patriotism was merged with Soviet pathos; the aim was to show that the people’s utopia was in fact communism, but not a single one of those songs made it into the people’s common repertoire. Only the patriotic songs composed in the 1980s during the so-called new national awakening reached a popularity comparable to that of the old songs. The discourse on ’Estonianness’ and the shaping of a matching repertoire under imperial Russian rule took place under very different circumstances than its preservation and development in the second half of the 20th century under Soviet occupation, but

  19. The dominance of indirect taxes in Estonian state budget. Summary:Kaudsete maksude dominant Eesti riigieelarve tuludes

    Directory of Open Access Journals (Sweden)

    Olev Raju

    2013-09-01

    Full Text Available Recession has sharply erected the question of tax burden and the optimal proportion of different kinds of taxes among the incomes of the budget. Indirect taxes and consumption taxes, which proportion is different according to different methodologies, dominate in Estonian state budget. The buoyancy of a tax system based on taxes of that kind is especially weak during the recession. The purpose of Estonian government’s economic policy during the highest peak of crisis was to keep the budget in balance. Instead of recovering economy the taxes were arisen and costs were reduced. The results of such a policy aren’t still clear. Difficulties concerning the incomes of budget have arisen the necessity for lifting taxes, which is possible as the tax burden is low now. But a sharp question of the optimal level of taxes is going to be raised. A formula for indirect tax optimum according to Ramsey taxes and Slutski decomposition has been proposed in the article

  20. Selected trace-element and organic contaminants in the streambed sediments of the Potomac River Basin, August 1992

    Science.gov (United States)

    Gerhart, James M.; Blomquist, Joel D.

    1995-01-01

    This report describes the occurrence and distribution of five selected contaminants in streambed sediments at 22 stream sites in the Potomac River Basin. Lead, mercury, and total DDT (dichlorodiphenyltrichloroethane) were detected at all sites, and chlordane and total PCB's (polychlorinated biphenyls) were detected at most sites. At six sites, streambed-sediment concentrations of contaminants were detected at levels with the potential to cause frequent adverse effects on aquatic organisms that live in the sediments. Chlordane was detected at these high levels at sampling sites on the Anacostia River, the North Branch Potomac River, Bull Run, and Accotink Creek; mercury was detected at these levels at sites on the South River and the South Fork Shenandoah River; and total PCB's were detected at these levels at the site on the South Fork Shenandoah River. The highest concentrations of all five contaminants generally occurred at sampling sites downstream from areas with industrial plants, urban centers, or orchard and agricultural activity. The occurrence of these contaminants in streambed sediments of the Potomac River Basin is of concern because the contaminants (1) are environmentally persistent, (2) are available for downstream transport during high streamflow periods, and (3) have the potential to cause adverse effects on the health of aquatic organisms and humans through bioaccumulation.

  1. Elemental imaging of organic matter and associated metals in ore deposits using micro PIXE and micro-EBS

    Energy Technology Data Exchange (ETDEWEB)

    Fuchs, S., E-mail: fuchs@geomin.eu [Department of Earth and Planetary Science, McGill University, 3450 University Street, Montreal H3A 0E8 (Canada); Przybylowicz, W.J., E-mail: przybylowicz@tlabs.ac.za [Materials Research Department, iThemba LABS, National Research Foundation, P.O. Box 722, Somerset West 7129 (South Africa); AGH University of Science and Technology, Faculty of Physics and Applied Computer Science, Al. A. Mickiewicza 30, 30-059 Krakow (Poland); Williams-Jones, A.E., E-mail: anthony.williams-jones@mcgill.ca [Department of Earth and Planetary Science, McGill University, 3450 University Street, Montreal H3A 0E8 (Canada)

    2014-01-01

    Micro-PIXE and micro-EBS analyses were carried out on samples from the Au–U-bearing Carbon Leader Reef of the Witwatersrand in South Africa to investigate the role of organic matter in the formation of this deposit. Micro-PIXE and Micro-EBS shows a very complex metal distribution within the bitumen nodules and their interstitial spaces. The style of the gold distribution and its association with epigenetic minerals (REE phosphates, phyllosilicates) indicates that all observed gold migrated in aqueous solution and precipitated by reduction on the surfaces of the bitumen nodules. Uraninite occurrences are confined to the bitumen nodules, which supports the argument of a uraninite paleo-placer; however the pervasive distribution of uranium also supports the argument that uraninite is derived from organo-metallic complexes. This study shows that micro-PIXE is a powerful tool to characterize metals associated with hydrocarbons. However, the organic matrix, the complexity of the obtained spectra and the small size of the minerals have significant influence on the reliability of the quantitative data. Due to highly variable amounts of heavy metals (U, Au, Pb) the obtained micro-EBS results are of questionable quality.

  2. Design Elements and Feasibility of an Organized Multiplayer Mobile Active Videogame for Primary School-Aged Children.

    Science.gov (United States)

    McKenzie, Sophie; Bangay, Shaun; Barnett, Lisa M; Ridgers, Nicola D; Salmon, Jo

    2014-12-01

    This article describes the design, development, and implementation feasibility of a purpose-built mobile active videogame (M-AVG) named "Pirate Adventure," which was designed for primary school-aged children to engage in physical activity (PA) and fundamental movement skills (FMS), such as hopping, sidestepping, jumping, or running, in an afterschool setting. The design of "Pirate Adventure" was the result of a collaboration between games designers and health researchers. "Pirate Adventure" was designed and developed using Android(®) (Google, Mountain View, CA) phone sensors to respond to player actions within a playground environment. Using an interactive game framework, players solve clues and complete PA and FMS challenges via sensing the physical world through marked-out key game locations. Fourteen primary school-aged children participated in the feasibility evaluation, which took place in four afternoon sessions. The game was evaluated using Android phone telemetry data and a post-gameplay survey for children on their opinions and enjoyment of the game. The "Pirate Adventure" game design facilitated an enjoyable treasure hunt game (average of 11 minutes of activity per game) with narrative elements supporting children's engagement with movement activities. The majority of children (n=9/13) reported that they would like to play the game again. Combining real world and virtual world content through "Pirate Adventure" was moderately successful, with multiple gameplay sessions occurring. Further implementation feasibility testing, under more controlled conditions, needs to be conducted to assert the benefits of using a M-AVG for children's PA and FMS.

  3. Organizations

    DEFF Research Database (Denmark)

    Hatch, Mary Jo

    and considers many more. Mary Jo Hatch introduces the concept of organizations by presenting definitions and ideas drawn from the a variety of subject areas including the physical sciences, economics, sociology, psychology, anthropology, literature, and the visual and performing arts. Drawing on examples from......Most of us recognize that organizations are everywhere. You meet them on every street corner in the form of families and shops, study in them, work for them, buy from them, pay taxes to them. But have you given much thought to where they came from, what they are today, and what they might become...... prehistory and everyday life, from the animal kingdom as well as from business, government, and other formal organizations, Hatch provides a lively and thought provoking introduction to the process of organization....

  4. EDUCATIONAL PROGRAMMES OF BRITISH ORGANIZATIONS IN AZERBAIJAN AS AN ELEMENT OF THE UNITED KINGDOM FOREIGN LANGUAGE POLICY

    Directory of Open Access Journals (Sweden)

    G. Y. Niyazova

    2014-10-01

    Full Text Available The article considers the United Kingdom language policy on the territory of Azerbaijan after the Soviet Union collapse, which is a bright example of the world political map redrawing. Taking into account the fact that the language is an important tool of the extending one’s influence over the country, we can say with certainty that the success of the specific state laying a claim to play the leading role in on the global political arena strongly depends on its ability to promote its language abroad, to enhance its status and to create such conditions where in the foreign country its language conquers the status close to the status of the native language. In this regard, the United Kingdom activity can serve as an example of a successful foreign language state policy.The authors analyze the activity of such organizations as the British Council, the BBC and BP on spreading the English language. The aforesaid British organizations are the master plate of the efficient language state policy tools, as long as they not only actively develop the global picture of the world, but also promote the interests of the United Kingdom on the territory of the former Soviet Union.Azerbaijan encourages the United Kingdom intention to spread the English language on its territory and does its best in assisting in the implementation of the proposed initiatives, realizing that the spread of the English language being the language of a global communication in Azerbaijan would contribute to the raising of Azerbaijan status on the world arena.

  5. Riik võib lüüa SAS-i esmaspäevaks Estonian Airi omanikeringist välja / Erik Müürsepp, Mikk Salu

    Index Scriptorium Estoniae

    Müürsepp, Erik

    2008-01-01

    SAS osaleb Estonian Airþile lisakapitali eraldamises ainult juhul, kui Eesti riik müüb oma osaluses lennukompaniis SAS-ile. Peaminister Andrus Ansipi ning majandus- ja kommunikatsiooniminister Juhan Partsi seisukoht

  6. Eesti autobiograafilise kirjutuse kujunemisest 18. sajandist Teise maailmasõjani. The Development of Estonian Autobiographical Writing from the 18th Century to the Second World War

    Directory of Open Access Journals (Sweden)

    Rutt Hinrikus

    2012-04-01

    Full Text Available In this article I examine the development of Estonian autobiographical writing from its first manifestations to published memoirs, and the development of life writing and its diversification. The beginnings of life writing can be traced back to Estonian folk song and Estonian incidental poetry. The Moravian Brethren movement in Estonia in the 18th century promoted the spread of canonical autobiography. The Moravian Brethren offered alternative opportunities for self-realisation for Estonians who were serfs, and were therefore popular with the people. The practice of the Moravian Brethren made use of retelling and writing about the life of the congregation members, which sometimes became suitable biographies in print, especially stories of awakening. Several manuscript biographies have survived from the Brethren times, such as the biographies of Mäletu Jaan and Mihkel Sarapuu. In addition to the history of the Moravian Brethren movement, these biographies give information about the educational situation and living conditions of the people of the time. The Estonian life writing tradition emerged within the reigning Baltic German cultural space thanks to the Estophiles among the Baltic Germans (J. H. Rosenplänter and the first Estonian men of letters; from the early 19th century we have the diary by Rosenplänter, an estophile pastor from Pärnu, and the diary by the Estonian poet, the then-student Kristjan Jaak Peterson, both in the Estonian language. Johann Voldemar Jannsen, the founder of Estonian-language journalism, kept a diary in the German language for a longer period of time; it was usual that the first Estonian intellectuals (Lilli Suburg, and others in the late 19th century wrote in German. Admittedly, the first Estonian-language life history was written by a forward-looking 19th century peasant named Märt Mitt (1833-1912, who was conscious of himself as a historical subject and gave his memoirs, begun in the 1880s, a memorable title

  7. Affinity for a malignant tumor and organs at the elements in group VIII of the periodic table

    International Nuclear Information System (INIS)

    Ando, Atsushi; Hisada, Kinichi; Ando, Itsuko.

    1975-01-01

    In order to investigate the tumor affinity of the radioisotopes, iron(Fe-59), cobalt(Co-58), ruthenium(Ru-103), palladium(Pd-103), osmium(Os-185+191) and iridium(Ir-192), the elements of group VIII in the periodic table were examined, using rats which were subcutaneously transplanted with Yoshida sarcoma. Six preparations, 59 Fe-chloride, 58 Co-chloride, 103 Ru-chloride, 103 Pd-chloride, 185+191 Os-hexachlorosmic acid and 192 Ir-hexachloriridic acid were injected intravenously in to each group of tumor bearing rats. These rats were sacrificed at various periods after injection of each preparation: 3 hours, 24 hours and 48 hours in all preparations, except 59 Fe-chloride with 30 minutes, 3 hours, 24 hours and 48 hours. The radioactivities of the tumor, blood muscle, liver, kidney and spleen were measured by a well-type scintillation counter, and retention values (in every tissue including the tumor were calculated in percent of administered dose per g-tissue weight). 185+191 Os-hexachlorosmic acid had a considerably strong affinity for the malignant tumor. 59 Fe-chloride, 58 Co-chloride, 103 Ru-chloride, 103 Pd-chloride and 192 Ir-hexachloriridic acid did not have any affinity for the malignant tumor. However 59 Fe-chloride had a very strong affinity for blood corpuscles. 103 Pd-chloride had a fairly strong affinity for the kidney and liver, 58 Co-chloride had a fairly affinity for the liver, 103 Ru-chloride, 185+191 Os-hexachlorosmic acid and 192 Ir-hexachloriridic acid had a fairly strong affinity for the kidney. (Evans, J.)

  8. The success factors of scaling-up Estonian sexual and reproductive health youth clinic network--from a grassroots initiative to a national programme 1991-2013.

    Science.gov (United States)

    Kempers, Jari; Ketting, Evert; Chandra-Mouli, Venkatraman; Raudsepp, Triin

    2015-01-08

    A growing number of middle-income countries are scaling up youth-friendly sexual and reproductive health pilot projects to national level programmes. Yet, there are few case studies on successful national level scale-up of such programmes. Estonia is an excellent example of scale-up of a small grassroots adolescent sexual and reproductive health initiative to a national programme, which most likely contributed to improved adolescent sexual and reproductive health outcomes. This study; (1) documents the scale-up process of the Estonian youth clinic network 1991-2013, and (2) analyses factors that contributed to the successful scale-up. This research provides policy makers and programme managers with new insights to success factors of the scale-up, that can be used to support planning, implementation and scale-up of adolescent sexual and reproductive health programmes in other countries. Information on the scale-up process and success factors were collected by conducting a literature review and interviewing key stakeholders. The findings were analysed using the WHO-ExpandNet framework, which provides a step-by-step process approach for design, implementation and assessment of the results of scaling-up health innovations. The scale-up was divided into two main phases: (1) planning the scale-up strategy 1991-1995 and (2) managing the scaling-up 1996-2013. The planning phase analysed innovation, user organizations (youth clinics), environment and resource team (a national NGO and international assistance). The managing phase examines strategic choices, advocacy, organization, resource mobilization, monitoring and evaluation, strategic planning and management of the scale-up. The main factors that contributed to the successful scale-up in Estonia were: (1) favourable social and political climate, (2) clear demonstrated need for the adolescent services, (3) a national professional organization that advocated, coordinated and represented the youth clinics, (4) enthusiasm

  9. Bulk soil and maize rhizosphere resistance genes, mobile genetic elements and microbial communities are differently impacted by organic and inorganic fertilization

    DEFF Research Database (Denmark)

    Wolters, Birgit; Jacquiod, Samuel Jehan Auguste; Sørensen, Søren Johannes

    2018-01-01

    Organic soil fertilizers, such as livestock manure and biogas digestate, frequently contain bacteria carrying resistance genes (RGs) to antimicrobial substances and mobile genetic elements (MGEs). The effects of different fertilizers (inorganic, manure, digestate) on RG and MGE abundance...... and microbial community composition were investigated in a field plot experiment. The relative abundances of RGs [sul1, sul2, tet(A), tet(M), tet(Q), tet(W), qacEΔ1/qacE] and MGEs [intI1, intI2, IncP-1, IncP-1ε and LowGC plasmids] in total community (TC)-DNA from organic fertilizers, bulk soil and maize......, integrons and few genera affiliated to Bacteroidetes and Firmicutes in bulk soil, while digestate increased sul2, tet(W) and intI2. At harvest, treatment effects vanished in bulk soil. However, organic fertilizer effects were still detectable in the rhizosphere for RGs [manure: intI1, sul1; digestate: tet...

  10. Printable organic thin film transistors for glucose detection incorporating inkjet-printing of the enzyme recognition element

    Energy Technology Data Exchange (ETDEWEB)

    Elkington, D., E-mail: Daniel.Elkington@newcastle.edu.au; Wasson, M.; Belcher, W.; Dastoor, P. C.; Zhou, X. [Centre for Organic Electronics, The University of Newcastle, Callaghan 2308 (Australia)

    2015-06-29

    The effect of device architecture upon the response of printable enzymatic glucose sensors based on poly(3-hexythiophene) (P3HT) organic thin film transistors is presented. The change in drain current is used as the basis for glucose detection and we show that significant improvements in drain current response time can be achieved by modifying the design of the sensor structure. In particular, we show that eliminating the dielectric layer and reducing the thickness of the active layer reduce the device response time considerably. The results are in good agreement with a diffusion based model of device operation, where an initial rapid dedoping process is followed by a slower doping of the P3HT layer from protons that are enzymatically generated by glucose oxidase (GOX) at the Nafion gate electrode. The fitted diffusion data are consistent with a P3HT doping region that is close to the source-drain electrodes rather than located at the P3HT:[Nafion:GOX] interface. Finally, we demonstrate that further improvements in sensor structure and morphology can be achieved by inkjet-printing the GOX layer, offering a pathway to low-cost printed biosensors for the detection of glucose in saliva.

  11. Spatial variation in diesel-related elemental and organic PM2.5 components during workweek hours across a downtown core.

    Science.gov (United States)

    Tunno, Brett J; Shmool, Jessie L C; Michanowicz, Drew R; Tripathy, Sheila; Chubb, Lauren G; Kinnee, Ellen; Cambal, Leah; Roper, Courtney; Clougherty, Jane E

    2016-12-15

    Capturing intra-urban variation in diesel-related pollution exposures remains a challenge, given its complex chemical mix, and relatively few well-characterized ambient-air tracers for the multiple diesel sources in densely-populated urban areas. To capture fine-scale spatial resolution (50×50m grid cells) in diesel-related pollution, we used geographic information systems (GIS) to systematically allocate 36 sampling sites across downtown Pittsburgh, PA, USA (2.8km 2 ), cross-stratifying to disentangle source impacts (i.e., truck density, bus route frequency, total traffic density). For buses, outbound and inbound trips per week were summed by route and a kernel density was calculated across sites. Programmable monitors collected fine particulate matter (PM 2.5 ) samples specific to workweek hours (Monday-Friday, 7 am-7 pm), summer and winter 2013. Integrated filters were analyzed for black carbon (BC), elemental carbon (EC), organic carbon (OC), elemental constituents, and diesel-related organic compounds [i.e., polycyclic aromatic hydrocarbons (PAHs), hopanes, steranes]. To our knowledge, no studies have collected this suite of pollutants with such high sampling density, with the ability to capture spatial patterns during specific hours of interest. We hypothesized that we would find substantial spatial variation for each pollutant and significant associations with key sources (e.g. diesel and gasoline vehicles), with higher concentrations near the center of this small downtown core. Using a forward stepwise approach, we developed seasonal land use regression (LUR) models for PM 2.5 , BC, total EC, OC, PAHs, hopanes, steranes, aluminum (Al), calcium (Ca), and iron (Fe). Within this small domain, greater concentration differences were observed in most pollutants across sites, on average, than between seasons. Higher PM 2.5 and BC concentrations were found in the downtown core compared to the boundaries. PAHs, hopanes, and steranes displayed different spatial

  12. Az észt névtervezés az észt nyelvpolitikai modell tükrében [The name management in the mirror of the Estonian LPP-model

    Directory of Open Access Journals (Sweden)

    Pomozi, Péter

    2016-12-01

    Full Text Available The Estonian model of language planning and policy, which has been serving the development and protection of the Estonian language in its current form since 2004, is one of the most successful of such strategies in Europe. It owes it success to the broad social and scientific consensus reached in questions of language policy, regardless of changes in government. The Development Plan of the Estonian Language divides Estonian language planning and policy into three parts: status planning, corpus planning and prestige planning. Name management is a part of corpus planning, although certain aspects are also connected to legal and prestige planning. Name management strategies are present in all components of the Estonian model of language planning and policy, as linguistically appropriate name use is not only a socio-cultural, but economic question, as informative and easy to understand names contribute to measurable economic advantages. The paper mainly demonstrates the dilemmas and answers of Estonian name management through examples from personal name giving practices, but questions concerning the problems of name use in a multicultural environment and the difficulties of place name and firm name management are also discussed.

  13. Computation of Estonian CORS data using Bernese 5.2 and Gipsy 6.4 softwares

    Science.gov (United States)

    Kollo, Karin; Kall, Tarmo; Liibusk, Aive

    2017-04-01

    GNSS permanent station network in Estonia (ESTREF) was established already in 2007. In 2014-15 extensive reconstruction of ESTREF was carried out, including the establishment of 18 new stations, change of the hardware in CORS stations as well as establishing GNSS-RTK service for the whole Estonia. For GNSS-RTK service one needs precise coordinates in well-defined reference frame, i.e., ETRS89. For long time stability of stations and time-series analysis the re-processing of Estonian CORS data is ongoing. We re-process data from 2007 until 2015 with program Bernese GNSS 5.2 (Dach, 2015). For the set of ESTREF stations established in 2007, we perform as well computations with GIPSY 6.4 software (Ries et al., 2015). In the computations daily GPS-only solution was used. For precise orbits, final products from CODE (CODE analysis centre at the Astronomical Institute of the University of Bern) and JPL (Jet Propulsion Laboratory) for Bernese and GIPSY solutions were used, respectively. The cut-off angle was set to 10 degrees in order to avoid near-field multipath influence. In GIPSY, precise point positioning method with fixing ambiguities was used. Bernese calculations were performed based on double difference processing. Antenna phase centers were modelled based on igs08.atx and epnc_08.atx files. Vienna mapping function was used for mapping tropospheric delays. For the GIPSY solution, the higher order ionospheric term was modelled based on IRI-2012b model. For the Bernese solution higher order ionospheric term was neglected. FES2004 ocean tide loading model was used for the both computation strategies. As a result, two solutions using different scientific GNSS computation programs were obtained. The results from Bernese and GIPSY solutions were compared, using station repeatability values, RMS and coordinate differences. KEYWORDS: GNSS reference station network, Bernese GNSS 5.2, Gipsy 6.4, Estonia. References: Dach, R., S. Lutz, P. Walser, P. Fridez (Eds); 2015

  14. Towards The Operational Oceanographic Model System In Estonian Coastal Sea, Baltic Sea

    Science.gov (United States)

    Kõuts, T.; Elken, J.; Raudsepp, U.

    An integrated system of nested 2D and 3D hydrodynamic models together with real time forcing data asquisition is designed and set up in pre-operational mode in the Gulf of Finland and Gulf of Riga, the Baltic Sea. Along the Estonian coast, implicit time-stepping 3D models are used in the deep bays and 2D models in the shallow bays with ca 200 m horizontal grid step. Specific model setups have been verified by in situ current measurements. Optimum configuration of initial parameters has been found for certain critical locations, usually ports, oil terminals, etc. Operational system in- tegrates also section of historical database of most important hydrologic parameters in the region, allowing use of certain statistical analysis and proper setup of initial conditions for oceanographic models. There is large variety of applications for such model system, ranging from environmental impact assessment at local coastal sea pol- lution problems to forecast of offshore blue algal blooms. Most probable risk factor in the coastal sea engineering is oil pollution, therefore current operational model sys- tem has direct custom oriented output the oil spill forecast for critical locations. Oil spill module of the operational system consist the automatic weather and hydromet- ric station (distributed in real time to internet) and prognostic model of sea surface currents. System is run using last 48 hour wind data and wind forecast and estimates probable oil deposition areas on the shoreline under certain weather conditions. Cal- culated evolution of oil pollution has been compared with some real accidents in the past and there was found good agreement between model and measurements. Graphi- cal user interface of oil spill model is currently installed at location of port authorities (eg. Muuga port), so in case of accidents it could be used in real time supporting the rescue operations. In 2000 current pre-operational oceanographic model system has been sucessfully used to

  15. The Needs for and the Basic Elements of an Integrated Approach to Planning, Organization and Management of Decommissioning Activities in the Russian Federation

    Energy Technology Data Exchange (ETDEWEB)

    Nechaev, A. F.; Akatov, A.A., E-mail: anechaev@lti-gti.ru, E-mail: andrey_akatov@mail.ru [Saint-Petersburg State Institute of Technology (Technical University), Saint-Petersburg (Russian Federation)

    2013-08-15

    This report contains the principal results of analytical studies performed by Research Group of St.-Petersburg State Institute of Technology in the framework of the IAEA CRP on ''Planning, Management and Organizational Aspects in Decommissioning of Nuclear Facilities''. The aims of the studies were to determine the adequacy of available tools and mechanisms for planning and organization of a large scale decommissioning and waste management activities; to define such elements of planning and management system that require changes and improvements; to elaborate recommendations on necessary actions; and to provide info analytical and methodical support for sustainable realization of decommissioning programme. Final report includes systematized information on a broad spectrum of issues related to CRP goals - from legislation, financing, subordination to concrete plans, projects, relevant manuals and guides addressed both to decision makers, technical executors and the public. (author)

  16. Use of stirred tanks for studying matrix effects caused by inorganic acids, easily ionized elements and organic solvents in inductively coupled plasma atomic emission spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Paredes, Eduardo [Departamento de Quimica Analitica, Nutricion y Bromatologia, University of Alicante, 03080 Alicante (Spain); Maestre, Salvador E. [Departamento de Quimica Analitica, Nutricion y Bromatologia, University of Alicante, 03080 Alicante (Spain); Todoli, Jose L. [Departamento de Quimica Analitica, Nutricion y Bromatologia, University of Alicante, 03080 Alicante (Spain)]. E-mail: jose.todoli@ua.es

    2006-03-15

    A stirred tank was used for the first time to elucidate the mechanism responsible for inductively coupled plasma atomic emission spectroscopy (ICP-AES) matrix effects caused by inorganic, acids and easily ionized elements (EIEs), as well as organic, ethanol and acetic acid, compounds. In order to gradually increase the matrix concentration, a matrix solution was introduced inside a stirred container (tank) initially filled with an aqueous multielement standard. PolyTetraFluoroEthylene (PTFE) tubing was used to deliver the resulting solution to the liquid sample introduction system. Matrix concentration ranged from 0 to 2 mol l{sup -1} in the case of inorganic acids (i.e., nitric, sulfuric, hydrochloric and a mixture of them), from 0 to about 2500 mg l{sup -1} for EIEs (i.e., sodium, calcium and mixtures of both) and from 0% to 15%, w/w for organic compounds. Up to 40-50 different solutions were prepared and measured in a period of time shorter than 6-7 min. This investigation was carried out in terms of emission intensity and tertiary aerosols characteristics. The experimental setup used in the present work allowed to thoroughly study the effect of matrix concentration on analytical signal. Generally speaking, the experiments concerning tertiary aerosol characterization revealed that, in the case of inorganic acids and EIEs, the mechanism responsible for changes in aerosol characteristics was the droplet fission. In contrast, for organic matrices it was found that the interference was caused by a change in both aerosol transport and plasma thermal characteristics. The extent of the interferences caused by organic as well as inorganic compounds was compared for a set of 14 emission lines through a wide range of matrix concentrations. With a stirred tank, it is possible to choose an efficient internal standard for any given matrix composition. The time required to complete this procedure was shorter than 7 min.

  17. Use of stirred tanks for studying matrix effects caused by inorganic acids, easily ionized elements and organic solvents in inductively coupled plasma atomic emission spectrometry

    International Nuclear Information System (INIS)

    Paredes, Eduardo; Maestre, Salvador E.; Todoli, Jose L.

    2006-01-01

    A stirred tank was used for the first time to elucidate the mechanism responsible for inductively coupled plasma atomic emission spectroscopy (ICP-AES) matrix effects caused by inorganic, acids and easily ionized elements (EIEs), as well as organic, ethanol and acetic acid, compounds. In order to gradually increase the matrix concentration, a matrix solution was introduced inside a stirred container (tank) initially filled with an aqueous multielement standard. PolyTetraFluoroEthylene (PTFE) tubing was used to deliver the resulting solution to the liquid sample introduction system. Matrix concentration ranged from 0 to 2 mol l -1 in the case of inorganic acids (i.e., nitric, sulfuric, hydrochloric and a mixture of them), from 0 to about 2500 mg l -1 for EIEs (i.e., sodium, calcium and mixtures of both) and from 0% to 15%, w/w for organic compounds. Up to 40-50 different solutions were prepared and measured in a period of time shorter than 6-7 min. This investigation was carried out in terms of emission intensity and tertiary aerosols characteristics. The experimental setup used in the present work allowed to thoroughly study the effect of matrix concentration on analytical signal. Generally speaking, the experiments concerning tertiary aerosol characterization revealed that, in the case of inorganic acids and EIEs, the mechanism responsible for changes in aerosol characteristics was the droplet fission. In contrast, for organic matrices it was found that the interference was caused by a change in both aerosol transport and plasma thermal characteristics. The extent of the interferences caused by organic as well as inorganic compounds was compared for a set of 14 emission lines through a wide range of matrix concentrations. With a stirred tank, it is possible to choose an efficient internal standard for any given matrix composition. The time required to complete this procedure was shorter than 7 min

  18. Studies in the Philippines on ingestion and organ content of trace elements of importance to radiological protection. Reference Asian man project (phase 2)

    International Nuclear Information System (INIS)

    Natera, E.S.

    2000-01-01

    The first Coordinated Research Program (CRP) on Reference Asian Man was conducted for a period of six years. This study dealt with the collection of data in four areas namely, anthropometric measurements, organ mass measurements, nutritional and dietary intake, pulmonary and water balance studies. Results of this study participated by eight Asian member states including the Philippines are contained in the IAEA TECDOC-1005. Based on research needs with reference to radiation protection, dietary intake and tissue analysis appears to be important aspects of the RAM. Hence, the first CRM for Phase 2 held in Manila July 1-4, 1996 strengthened the need to continue the project. Protocols on its implementation were discussed during this meeting. The Philippines presented a report that described the sampling and analytical methods that will be applied. This report aim to present the initial samples collected as well as the data generated from these samples. Elements of interest to radiation protection include Sr, Th, U, 1, Cs and trace elements present in food, water and in selected tissues such as liver, lung, kidney, thyroid and bone

  19. Mercury, trace elements and organic constituents in atmospheric fine particulate matter, Shenandoah National Park, Virginia, USA: A combined approach to sampling and analysis

    Science.gov (United States)

    Kolker, A.; Engle, M.A.; Orem, W.H.; Bunnell, J.E.; Lerch, H.E.; Krabbenhoft, D.P.; Olson, M.L.; McCord, J.D.

    2008-01-01

    Compliance with U.S. air quality regulatory standards for atmospheric fine particulate matter (PM2.5) is based on meeting average 24 hour (35 ?? m-3) and yearly (15 ??g m-3) mass-per-unit-volume limits, regardless of PM2.5 composition. Whereas this presents a workable regulatory framework, information on particle composition is needed to assess the fate and transport of PM2.5 and determine potential environmental/human health impacts. To address these important non-regulatory issues an integrated approach is generally used that includes (1) field sampling of atmospheric particulate matter on filter media, using a size-limiting cyclone, or with no particle-size limitation; and (2) chemical extraction of exposed filters and analysis of separate particulate-bound fractions for total mercury, trace elements and organic constituents, utilising different USGS laboratories optimised for quantitative analysis of these substances. This combination of sampling and analysis allowed for a more detailed interpretation of PM2.5 sources and potential effects, compared to measurements of PM2.5 abundance alone. Results obtained using this combined approach are presented for a 2006 air sampling campaign in Shenandoah National Park (Virginia, USA) to assess sources of atmospheric contaminants and their potential impact on air quality in the Park. PM2.5 was collected at two sampling sites (Big Meadows and Pinnacles) separated by 13.6 km. At both sites, element concentrations in PM2.5 were low, consistent with remote or rural locations. However, element/Zr crustal abundance enrichment factors greater than 10, indicating anthropogenic input, were found for Hg, Se, S, Sb, Cd, Pb, Mo, Zn and Cu, listed in decreasing order of enrichment. Principal component analysis showed that four element associations accounted for 84% of the PM 2.5 trace element variation; these associations are interpreted to represent: (1) crustal sources (Al, REE); (2) coal combustion (Se, Sb), (3) metal production

  20. Postmodernistlikke jooni eesti noore režissuuri lavastustes 1969–1975 / Postmodernist Traits in the Performances of Young Estonian Directors 1969-1975

    Directory of Open Access Journals (Sweden)

    Rein Heinsalu

    2015-06-01

    activities on stage were also transferred to the audience. All of these tendencies indicate a new approach to the theatre. Overthrowing, deconstruction, and the Zeitgeist of rebellion, a new spirit of play, homo ludens are reflected in many writings from the end of the 1960s. When describing the atmosphere of that time, Mati Unt uses Derrida’s term onto-theo-teleo-phallo-phonocentrism. This period is also characterized by the phrase „rebellion against old stereotypes“, with the goal of deconstructing them. According to the theory of Brian McHale, the most important marker of postmodernism is the ontological dominant. And yet such designations as placing objectivity totally in suspension, metatheatrical devices,  resistance, physicality, rejection, class and power as mystifications, confessionality – these key words also provide a multi-layered characterization of the postmodernist theatre of the 1960s–1970s both in the USA and Estonia. So far Estonian researchers of postmodernism have not produced a unified account of postmodernism in culture and literature. As the playwright Robert Patrick observes in retrospect, postmodernism set itself in opposition to the schemata of modernism, viewing them as irrelevant: „there was no manifesto, credo, or criteria. It just happened“. It was a rebellion against society as a structure. The abovementioned criteria correspond to a great extent with the traits postmodernism listed by Ihab Hassan: antiauthoritarianism, distantiation from myths, Ego, the disintegration of the I, new sexuality, counterculture, improvisational and aleatory structures, the mixture of forms, play, parody, apocalyptic expectations, elements of communal life and the hippie movement, in addition to frequent attraction toZen, Buddhism, and the occult; applications of intermediality. It is this anti-authoritarianism that is one of the main themes in the Suits poetry evening, the performance Letting their hand be kissed, You, who get

  1. Chemical composition of anthropogenic particles on needles collected close to the Estonian oil-shale power plants

    International Nuclear Information System (INIS)

    Meinander, O.

    1995-01-01

    Within the countries surrounding the Baltic Sea, north-eastern Estonia is among the most polluted areas. Emissions from the oil-shale power plants produce air pollution problems both locally and on a larger scale. In the atmosphere, pollutants mix and convert. Consequently, the particles deposited due to the use of oil-shale can have various chemical compositions. From the point of view of air chemistry, ecological effects and air pollution modelling, knowledge of the chemical composition of the deposited particles can be of great value. The aim of this work was to study the chemical composition of single anthropogenic particles occurring on needle surfaces in north-eastern Estonia and Southern Finland close to the Estonian oil-shale power plants. For the purpose, scanning electron microscopical microanalysis was used

  2. The Problems of Estonian R&D and Innovation Strategy and the Demand-Side Innovation Policies

    Directory of Open Access Journals (Sweden)

    Tõnu Roolaht

    2012-12-01

    Full Text Available The second larger Estonian R&D and Innovation Strategy ‘Knowledge-based Estonia 2007-2013’ is aimed at continuing the advancement of research and development efforts towards an innovative knowledge-based society and economic system in Estonia. Fostering of knowledge-based high-tech industries is seen as paramount for retaining country’s competitive advantage. However, the mid-term evaluations indicate that several goals of the strategy might not be achievable by 2013. In fact, the policy measures have been much more successful in developing scientific research, as indicated by increased international publication, number of patents, and number of researchers and engineers. The advances in development of high-tech products and services through innovations are noticeable but less prominent. The purpose of this study is to suggest the role for demand-side innovation policies in helping to advance commercial development and innovation

  3. Field trial on progesterone cycles, metabolic profiles, body condition score and their relation to fertility in Estonian Holstein dairy cows.

    Science.gov (United States)

    Samarütel, J; Ling, K; Waldmann, A; Jaakson, H; Kaart, T; Leesmäe, A

    2008-08-01

    Resumption of luteal activity postpartum and fertility were investigated in an Estonian Holstein high milk production and good fertility dairy herd. Body condition was scored after every 10 days in 54 multiparous dairy cows (71 lactations) calving inside from December to March during 4-year period. Blood samples were taken 1-14 days before calving and 1-14, 28-42 and 63-77 days after calving: analytes estimated were serum aspartate aminotransferase (AST), glucose, ketone bodies, total cholesterol, non-esterified fatty acids and triglycerides. The general linear mixed model was used to compare the data for cows with different characteristics in luteal activity postpartum based on their milk progesterone profiles. Forty-five per cent of cases had abnormal profiles; delayed resumption of ovarian cyclicity postpartum (DC) was the most prevalent abnormality. There was no difference in body condition scores between the groups. The DC and prolonged luteal phase groups had higher serum AST activity (p fertility.

  4. Using micro-contexts to describe a writing process in Estonian as a second language across proficiency levels

    Directory of Open Access Journals (Sweden)

    Olga Pastuhhova

    2015-04-01

    Full Text Available This paper aims to describe the writing process of native Russian‑speaking students in Estonian as a second language. 34 participants were given the assignment of writing a text in the L2. The written texts were then rated as being at levels from A2 to C1 according to the Common European Framework of Reference for Languages (CEFR. The data were collected by computer keystroke logging and analysed based on the concept of a ‘micro-context’. Micro-contexts were analysed according to their frequency and duration and were compared across proficiency levels. The results show that writing in the L2 is not a smooth process. The longest transitions in micro-contexts reveal that the most cognitive effort is made between paragraphs and sentences and when deletions are involved. The growing number of consecutive deletions demonstrates that even with developing proficiency, the linear production text is subject to constant revision, correction and modification.

  5. Tõlkepärl eesti ilukirjanduse algusaegadest – esimene eestikeelne robinsonaad / A Translation Gem from the Beginnings of Estonian Literature - the First Robinsonade

    Directory of Open Access Journals (Sweden)

    Ave Mattheus

    2015-06-01

    Full Text Available Teesid: Artiklis uuritakse Eesti Kirjandusmuuseumis asuvat mahukat, ligi 800 lk tõlkekäsikirja „Norem Robinson“, mida võib pidada esimeseks eesti kirjanduse täiemahuliseks robinsonaadiks. Selle valmistas Pärnu koolmeister Heinrich Gottlieb Lorenzsonn saksa pedagoogi ja koolikirjaniku Joachim Heinrich Campe menukast noorsooromaanist „Robinson der Jüngere“ (1779–1780. Tõlge valmis 1822.–1823. aastal, kuid jõudis trükki alles 1842. aastal tugevasti kärbitud ja mugandatud kujul. Toetudes deskriptiivse tõlkeuurimuse analüüsikategooriatele, vaadeldakse artiklis, millised tegurid tõlkeprotsessi suunasid ja milline oli kultuuriruum, kuhu tõlge omal ajal paigutus. SU M M A R Y This article discusses a voluminous manuscript translation of almost 800 pages entitled Norem Robinson (Engl. Robinson the Younger, from the collections of the Estonian Literary Museum. This manuscript can be considered as the first complete Robinsonade in Estonian literature. Its author is a schoolteacher from Pärnu, Heinrich Gottlieb Lorenzsonn (1803–1847, who translated it from the youth novel Robinson der Jüngere(1779–1780, Engl. Robinson the Younger, a bestseller by the educator, writer and a major representative of German Enlightenment, Heinrich Joachim Campe. Lorenzsonn’s translation was completed in 1822–1823, but not printed until 1842 in a strongly adapted version titled Norema Robinsoni ello ja juhtumised ühhe tühja sare peäl (Engl. The Life and Adventures of Robinson the Younger on a deserted island. The print version of the Robinsonade lacks a pedagogical frame story, where the father tells children about the adventures of Robinson and takes the opportunity to discuss and imitate with children all the actions taken by Robinson the Younger. Due to this and other extirpated parts, the possible target audience was enlarged – besides children and youth, the text was now addressed to adults as well. In accordance with the

  6. Dissolved organic carbon and major and trace elements in peat porewater of sporadic, discontinuous, and continuous permafrost zones of western Siberia

    Science.gov (United States)

    Raudina, Tatiana V.; Loiko, Sergey V.; Lim, Artyom G.; Krickov, Ivan V.; Shirokova, Liudmila S.; Istigechev, Georgy I.; Kuzmina, Daria M.; Kulizhsky, Sergey P.; Vorobyev, Sergey N.; Pokrovsky, Oleg S.

    2017-07-01

    Mobilization of dissolved organic carbon (DOC) and related trace elements (TEs) from the frozen peat to surface waters in the permafrost zone is expected to enhance under ongoing permafrost thaw and active layer thickness (ALT) deepening in high-latitude regions. The interstitial soil solutions are efficient tracers of ongoing bio-geochemical processes in the critical zone and can help to decipher the intensity of carbon and metals migration from the soil to the rivers and further to the ocean. To this end, we collected, across a 640 km latitudinal transect of the sporadic to continuous permafrost zone of western Siberia peatlands, soil porewaters from 30 cm depth using suction cups and we analyzed DOC, dissolved inorganic carbon (DIC), and 40 major elements and TEs in 0.45 µm filtered fraction of 80 soil porewaters. Despite an expected decrease in the intensity of DOC and TE mobilization from the soil and vegetation litter to the interstitial fluids with the increase in the permafrost coverage and a decrease in the annual temperature and ALT, the DOC and many major and trace elements did not exhibit any distinct decrease in concentration along the latitudinal transect from 62.2 to 67.4° N. The DOC demonstrated a maximum of concentration at 66° N, on the border of the discontinuous/continuous permafrost zone, whereas the DOC concentration in peat soil solutions from the continuous permafrost zone was equal to or higher than that in the sporadic/discontinuous permafrost zone. Moreover, a number of major (Ca, Mg) and trace (Al, Ti, Sr, Ga, rare earth elements (REEs), Zr, Hf, Th) elements exhibited an increasing, not decreasing, northward concentration trend. We hypothesize that the effects of temperature and thickness of the ALT are of secondary importance relative to the leaching capacity of peat, which is in turn controlled by the water saturation of the peat core. The water residence time in peat pores also plays a role in enriching the fluids in some elements

  7. Dissolved organic carbon and major and trace elements in peat porewater of sporadic, discontinuous, and continuous permafrost zones of western Siberia

    Directory of Open Access Journals (Sweden)

    T. V. Raudina

    2017-07-01

    Full Text Available Mobilization of dissolved organic carbon (DOC and related trace elements (TEs from the frozen peat to surface waters in the permafrost zone is expected to enhance under ongoing permafrost thaw and active layer thickness (ALT deepening in high-latitude regions. The interstitial soil solutions are efficient tracers of ongoing bio-geochemical processes in the critical zone and can help to decipher the intensity of carbon and metals migration from the soil to the rivers and further to the ocean. To this end, we collected, across a 640 km latitudinal transect of the sporadic to continuous permafrost zone of western Siberia peatlands, soil porewaters from 30 cm depth using suction cups and we analyzed DOC, dissolved inorganic carbon (DIC, and 40 major elements and TEs in 0.45 µm filtered fraction of 80 soil porewaters. Despite an expected decrease in the intensity of DOC and TE mobilization from the soil and vegetation litter to the interstitial fluids with the increase in the permafrost coverage and a decrease in the annual temperature and ALT, the DOC and many major and trace elements did not exhibit any distinct decrease in concentration along the latitudinal transect from 62.2 to 67.4° N. The DOC demonstrated a maximum of concentration at 66° N, on the border of the discontinuous/continuous permafrost zone, whereas the DOC concentration in peat soil solutions from the continuous permafrost zone was equal to or higher than that in the sporadic/discontinuous permafrost zone. Moreover, a number of major (Ca, Mg and trace (Al, Ti, Sr, Ga, rare earth elements (REEs, Zr, Hf, Th elements exhibited an increasing, not decreasing, northward concentration trend. We hypothesize that the effects of temperature and thickness of the ALT are of secondary importance relative to the leaching capacity of peat, which is in turn controlled by the water saturation of the peat core. The water residence time in peat pores also plays a role in enriching the

  8. Individual and work-related risk factors for musculoskeletal pain: a cross-sectional study among Estonian computer users.

    Science.gov (United States)

    Oha, Kristel; Animägi, Liina; Pääsuke, Mati; Coggon, David; Merisalu, Eda

    2014-05-28

    Occupational use of computers has increased rapidly over recent decades, and has been linked with various musculoskeletal disorders, which are now the most commonly diagnosed occupational diseases in Estonia. The aim of this study was to assess the prevalence of musculoskeletal pain (MSP) by anatomical region during the past 12 months and to investigate its association with personal characteristics and work-related risk factors among Estonian office workers using computers. In a cross-sectional survey, the questionnaires were sent to the 415 computer users. Data were collected by self-administered questionnaire from 202 computer users at two universities in Estonia. The questionnaire asked about MSP at different anatomical sites, and potential individual and work related risk factors. Associations with risk factors were assessed by logistic regression. Most respondents (77%) reported MSP in at least one anatomical region during the past 12 months. Most prevalent was pain in the neck (51%), followed by low back pain (42%), wrist/hand pain (35%) and shoulder pain (30%). Older age, right-handedness, not currently smoking, emotional exhaustion, belief that musculoskeletal problems are commonly caused by work, and low job security were the statistically significant risk factors for MSP in different anatomical sites. A high prevalence of MSP in the neck, low back, wrist/arm and shoulder was observed among Estonian computer users. Psychosocial risk factors were broadly consistent with those reported from elsewhere. While computer users should be aware of ergonomic techniques that can make their work easier and more comfortable, presenting computer use as a serious health hazard may modify health beliefs in a way that is unhelpful.

  9. Organic aerosols and inorganic species from post-harvest agricultural-waste burning emissions over northern India: impact on mass absorption efficiency of elemental carbon.

    Science.gov (United States)

    Rajput, Prashant; Sarin, M M; Sharma, Deepti; Singh, Darshan

    2014-01-01

    Atmospheric PM2.5 (particulate matter with aerodynamic diameter of ≤ 2.5 μm), collected from a source region [Patiala: 30.2 °N; 76.3 °E; 250 m above mean sea level] of emissions from post-harvest agricultural-waste (paddy-residue) burning in the Indo-Gangetic Plain (IGP), North India, has been studied for its chemical composition and impact on regional atmospheric radiative forcing. On average, organic aerosol mass accounts for 63% of PM2.5, whereas the contribution of elemental carbon (EC) is ∼3.5%. Sulphate, nitrate and ammonium contribute up to ∼85% of the total water-soluble inorganic species (WSIS), which constitutes ∼23% of PM2.5. The potassium-to-organic carbon ratio from paddy-residue burning emissions (KBB(+)/OC: 0.05 ± 0.01) is quite similar to that reported from Amazonian and Savanna forest-fires; whereas non-sea-salt-sulphate-to-OC ratio (nss-SO4(2-)/OC: 0.21) and nss-SO4(2-)/EC ratio of 2.6 are significantly higher (by factor of 5 to 8). The mass absorption efficiency of EC (3.8 ± 1.3 m(2) g(-1)) shows significant decrease with a parallel increase in the concentrations of organic aerosols and scattering species (sulphate and nitrate). A cross plot of OC/EC and nss-SO4(2-)/EC ratios show distinct differences for post-harvest burning emissions from paddy-residue as compared to those from fossil-fuel combustion sources in south-east Asia.

  10. The Dialogue with Hamlet: Paul-Eerik Rummo’s “Hamlet’s Songs” as an Example of the Existential Paradigm in Estonian Culture

    Directory of Open Access Journals (Sweden)

    Anneli Mihkelev

    2013-06-01

    Full Text Available The article demonstrates different meanings of the motif of Hamlet in the Estonian culture. Hamlet as a literary figure has been very important and influential, a symbol of will and a fighter in a hopeless situation. Paul-Eerik Rummo’s poem “Hamlet’s Songs” (1964 forms the centre around which revolve not only written texts but also many such cultural texts as theatre performances and music, all connected by allusions to Hamlet. Rummo’s poem is one of the most innovative poems from the 1960s in Estonian literature. The generation of the 1960s was influenced by several important contemporary theories, including existentialism. Many young writers systematically undermined the Soviet regime in their works. The use of the motif of Hamlet reveals a similarity between the existential and romantic rebellions. Rummo’s dialogue with Hamlet in his poem expresses optimism in a hopeless situation in a way different from Shakespeare’s.

  11. Standard elements; Elements standards

    Energy Technology Data Exchange (ETDEWEB)

    Blanc, B [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    Following his own experience the author recalls the various advantages, especially in the laboratory, of having pre-fabricated vacuum-line components at his disposal. (author) [French] A la suite de sa propre experience, l'auteur veut rappeler les divers avantages que presente, tout particulierement en laboratoire, le fait d'avoir a sa disposition des elements pre-fabriques de canalisations a vide. (auteur)

  12. Describing temporal variability of the mean Estonian precipitation series in climate time scale

    Science.gov (United States)

    Post, P.; Kärner, O.

    2009-04-01

    Applicability of the random walk type models to represent the temporal variability of various atmospheric temperature series has been successfully demonstrated recently (e.g. Kärner, 2002). Main problem in the temperature modeling is connected to the scale break in the generally self similar air temperature anomaly series (Kärner, 2005). The break separates short-range strong non-stationarity from nearly stationary longer range variability region. This is an indication of the fact that several geophysical time series show a short-range non-stationary behaviour and a stationary behaviour in longer range (Davis et al., 1996). In order to model series like that the choice of time step appears to be crucial. To characterize the long-range variability we can neglect the short-range non-stationary fluctuations, provided that we are able to model properly the long-range tendencies. The structure function (Monin and Yaglom, 1975) was used to determine an approximate segregation line between the short and the long scale in terms of modeling. The longer scale can be called climate one, because such models are applicable in scales over some decades. In order to get rid of the short-range fluctuations in daily series the variability can be examined using sufficiently long time step. In the present paper, we show that the same philosophy is useful to find a model to represent a climate-scale temporal variability of the Estonian daily mean precipitation amount series over 45 years (1961-2005). Temporal variability of the obtained daily time series is examined by means of an autoregressive and integrated moving average (ARIMA) family model of the type (0,1,1). This model is applicable for daily precipitation simulating if to select an appropriate time step that enables us to neglet the short-range non-stationary fluctuations. A considerably longer time step than one day (30 days) is used in the current paper to model the precipitation time series variability. Each ARIMA (0

  13. Organic carbon, and major and trace element dynamic and fate in a large river subjected to poorly-regulated urban and industrial pressures (Sebou River, Morocco)

    Energy Technology Data Exchange (ETDEWEB)

    Hayzoun, H. [Université de Toulon, PROTEE, EA 3819, 83957 La Garde (France); LIMOM, Faculté des Sciences Dhar El Mehraz, Université Sidi Mohamed Ben Abdellah, Dhar El Mehraz B.P. 1796 Atlas, Fès 30000 (Morocco); Garnier, C., E-mail: cgarnier@univ-tln.fr [Université de Toulon, PROTEE, EA 3819, 83957 La Garde (France); Durrieu, G.; Lenoble, V.; Le Poupon, C. [Université de Toulon, PROTEE, EA 3819, 83957 La Garde (France); Angeletti, B. [Centre Européen de Recherche et d' Enseignement de Géosciences de l' Environnement UMR 6635 CNRS — Aix-Marseille Université, FR ECCOREV, Europôle Méditerranéen de l' Arbois, 13545 Aix-en-Provence (France); Ouammou, A. [LIMOM, Faculté des Sciences Dhar El Mehraz, Université Sidi Mohamed Ben Abdellah, Dhar El Mehraz B.P. 1796 Atlas, Fès 30000 (Morocco); Mounier, S. [Université de Toulon, PROTEE, EA 3819, 83957 La Garde (France)

    2015-01-01

    An annual-basis study of the impacts of the anthropogenic inputs from Fez urban area on the water geochemistry of the Sebou and Fez Rivers was conducted mostly focusing on base flow conditions, in addition to the sampling of industrial wastewater characteristic of the various pressures in the studied environment. The measured trace metals dissolved/particulate partitioning was compared to the ones predicted using the WHAM-VII chemical speciation code. The Sebou River, upstream from Fez city, showed a weakly polluted status. Contrarily, high levels of major ions, organic carbon and trace metals were encountered in the Fez River and the Sebou River downstream the Fez inputs, due to the discharge of urban and industrial untreated and hugely polluted wastewaters. Trace metals were especially enriched in particles with levels even exceeding those recorded in surface sediments. The first group of elements (Al, Fe, Mn, Ti, U and V) showed strong inter-relationships, impoverishment in Fez particles/sediments and stable partition coefficient (Kd), linked to their lithogenic origin from Sebou watershed erosion. Conversely, most of the studied trace metals/metalloids, originated from anthropogenic sources, underwent significant changes of Kd and behaved non-conservatively in the Sebou/Fez water mixing. Dissolved/particulate partitioning was correctly assessed by WHAM-VII modeling for Cu, Pb and Zn, depicting significant differences in chemical speciation in the Fez River when compared to that in the Sebou River. The results of this study demonstrated that a lack of compliance in environmental regulations certainly explained this poor status. - Highlights: • Pristine status of the Sebou River, Morrocco's main river, upstream Fez (1 M inhabitants) • The Fez River collecting Fez's urban/industrial wastewaters is heavily polluted. • The Fez discharge into the Sebou induces an increase of contaminant levels. • Change in partitioning and chemical speciation of

  14. Organic carbon, and major and trace element dynamic and fate in a large river subjected to poorly-regulated urban and industrial pressures (Sebou River, Morocco)

    International Nuclear Information System (INIS)

    Hayzoun, H.; Garnier, C.; Durrieu, G.; Lenoble, V.; Le Poupon, C.; Angeletti, B.; Ouammou, A.; Mounier, S.

    2015-01-01

    An annual-basis study of the impacts of the anthropogenic inputs from Fez urban area on the water geochemistry of the Sebou and Fez Rivers was conducted mostly focusing on base flow conditions, in addition to the sampling of industrial wastewater characteristic of the various pressures in the studied environment. The measured trace metals dissolved/particulate partitioning was compared to the ones predicted using the WHAM-VII chemical speciation code. The Sebou River, upstream from Fez city, showed a weakly polluted status. Contrarily, high levels of major ions, organic carbon and trace metals were encountered in the Fez River and the Sebou River downstream the Fez inputs, due to the discharge of urban and industrial untreated and hugely polluted wastewaters. Trace metals were especially enriched in particles with levels even exceeding those recorded in surface sediments. The first group of elements (Al, Fe, Mn, Ti, U and V) showed strong inter-relationships, impoverishment in Fez particles/sediments and stable partition coefficient (Kd), linked to their lithogenic origin from Sebou watershed erosion. Conversely, most of the studied trace metals/metalloids, originated from anthropogenic sources, underwent significant changes of Kd and behaved non-conservatively in the Sebou/Fez water mixing. Dissolved/particulate partitioning was correctly assessed by WHAM-VII modeling for Cu, Pb and Zn, depicting significant differences in chemical speciation in the Fez River when compared to that in the Sebou River. The results of this study demonstrated that a lack of compliance in environmental regulations certainly explained this poor status. - Highlights: • Pristine status of the Sebou River, Morrocco's main river, upstream Fez (1 M inhabitants) • The Fez River collecting Fez's urban/industrial wastewaters is heavily polluted. • The Fez discharge into the Sebou induces an increase of contaminant levels. • Change in partitioning and chemical speciation of

  15. Non-market value of Estonian seminatural grasslands: a contingent valuation study. Eesti poolloodusliku rohumaa turuväline väärtus: tingliku hindamise uuring

    Directory of Open Access Journals (Sweden)

    Helli Lepasaar

    2015-12-01

    Full Text Available Seminatural grasslands i.e. the floodplain meadows, seashore meadows, wooded meadows, dry meadows, wooded pastures are the very traditional part of Estonian landscapes, which play an important role in the appearance of the landscape in general and also serve as an important habitat for many plant and animal species. In order to preserve the seminatural grasslands continuous annual mowing and/or pasturing is needed. This activity is not economically profitable and needs subsidizing. The authors of the work raise a hypothesis that the Estonian seminatural grasslands could be viewed as a valuable non-market environmental good for which a significant public demand exists. In order to find out the non-market value of the seminatural grasslands a contingent valuation study was carried out among the Estonian working-age population (size of the sample 1061 individuals. The average individual willingness to pay was 11.3 euros. During the study, the authors constructed the total demand function and discovered that the total annual demand for seminatural grasslands was 17.9 million euros.

  16. Where Do Dead Books Go? The Problem of the Soviet Canon Today, on the Example of Johannes Becher's Work in Estonian

    Directory of Open Access Journals (Sweden)

    Katre Talviste

    2013-06-01

    Full Text Available The article describes the conception and editing process of an anthology of Johannes Becher’s poems (Unistades täiusest, 1962 in Estonian, and discusses its status in the Soviet and contemporary literary canon. The work on the Becher anthology was led by an already outstanding literary scholar Nigol Andresen and a young poet and translator Ain Kaalep, who later became one of the most prolific and wellknown poetry translators in Estonia. An important part was also played by another poet-translator, August Sang, who already had achieved such a standing in the Estonian literary field. Several other translators contributed to the anthology, making it a common project for intellectuals otherwise very differently positioned vis-à-vis the Soviet political authorities and cultural agendas. Becher’s work was strongly promoted by these instances, but his poetry was also read with genuine enthusiasm by the main contributors to the anthology (whose own poetry has certain parallels to some aspects of Becher’s, as well as the general public, at that time. After the fall of the Soviet regime it has been forgotten, mostly for the same contextual reasons that once granted its success. The case of his poetry in Estonian explores the question of this new invisibility of now politically irrelevant, but still voluminous and aesthetically intriguing literary works in the post-Soviet canon.

  17. Short interspersed nuclear elements (SINEs) are abundant in Solanaceae and have a family-specific impact on gene structure and genome organization.

    Science.gov (United States)

    Seibt, Kathrin M; Wenke, Torsten; Muders, Katja; Truberg, Bernd; Schmidt, Thomas

    2016-05-01

    Short interspersed nuclear elements (SINEs) are highly abundant non-autonomous retrotransposons that are widespread in plants. They are short in size, non-coding, show high sequence diversity, and are therefore mostly not or not correctly annotated in plant genome sequences. Hence, comparative studies on genomic SINE populations are rare. To explore the structural organization and impact of SINEs, we comparatively investigated the genome sequences of the Solanaceae species potato (Solanum tuberosum), tomato (Solanum lycopersicum), wild tomato (Solanum pennellii), and two pepper cultivars (Capsicum annuum). Based on 8.5 Gbp sequence data, we annotated 82 983 SINE copies belonging to 10 families and subfamilies on a base pair level. Solanaceae SINEs are dispersed over all chromosomes with enrichments in distal regions. Depending on the genome assemblies and gene predictions, 30% of all SINE copies are associated with genes, particularly frequent in introns and untranslated regions (UTRs). The close association with genes is family specific. More than 10% of all genes annotated in the Solanaceae species investigated contain at least one SINE insertion, and we found genes harbouring up to 16 SINE copies. We demonstrate the involvement of SINEs in gene and genome evolution including the donation of splice sites, start and stop codons and exons to genes, enlargement of introns and UTRs, generation of tandem-like duplications and transduction of adjacent sequence regions. © 2016 The Authors The Plant Journal © 2016 John Wiley & Sons Ltd.

  18. A temperature-tolerant multiplex elements and genes screening system for genetically modified organisms based on dual priming oligonucleotide primers and capillary electrophoresis.

    Science.gov (United States)

    Fu, Wei; Wei, Shuang; Wang, Chenguang; Du, Zhixin; Zhu, Pengyu; Wu, Xiyang; Wu, Gang; Zhu, Shuifang

    2017-08-15

    High throughput screening systems are the preferred solution to meet the urgent requirement of increasing number of genetically modified organisms (GMOs). In this study, we have successfully developed a multiplex GMO element screening system with dual priming oligonucleotide (DPO) primers. This system can detect the cauliflower mosaic virus 35S (CaMV 35S), terminator of nopaline synthase gene (NOS), figwort mosaic virus 35S (FMV 35S) promoter, neomycin phosphotransferaseII (NPTII), Bt Cry 1Ab, phosphinothricin acetyltransferase genes (bar) and Streptomyces viridochromogenes (pat) simultaneously, which covers more than 90% of all authorized GMO species worldwide. This system exhibits a high tolerance to annealing temperatures, high specificity and a limit of detection equal to conventional PCR. A total of 214 samples from markets, national entry-exit agencies, the Institute for Reference Materials and Measurement (IRMM) and the American Oil Chemists' Society (AOCS) were also tested for applicability. This screening system is therefore suitable for GMO screening. Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. Evaluation of microbial transformations of dissolved organic matter - what information can be extracted from high-field FTICR-MS elemental formula data sets?

    Science.gov (United States)

    Herzsprung, Peter; von Tümpling, Wolf; Harir, Mourad; Hertkorn, Norbert; Schmitt-Kopplin, Philippe; Norf, Helge; Weitere, Markus; Kamjunke, Norbert

    2017-04-01

    Transformation of DOC and DOM was and is widespread investigated (1-3). Due to the complex composition of DOC increased attention was payed to DOM quality change during degradation processes. In order to get a better insight in DOM transformation processes both resolution as a function of time and on a molecular level are promising. The observation of DOM quality changes requires sophisticated evaluation techniques. A new evaluation strategy of FTICR-MS elemental formula data sets is introduced. An experiment with seven flumes and leaf leachate was performed. All flumes were sampled on five dates (within 7 days) and the SPEDOM was characterized using high-field FTICR-MS analysis, resulting in together 35 elemental formula data sets. The time dependent change of components abundance was fitted by a simple linear regression model after normalization of mass peak intensities. All components were categorized by calculation of the slope (change of percent intensity per day) in all seven flumes. A positive slope means product formation, a negative slope means degradation of components. Specific data filtration was developed to find out components with relevant change of relative intensity. About 7000 different components were present in at least one of the 35 samples. Of those about 1800 components were present in all of the 35 samples. About 300 components with significant increase of intensity were identified. They were mainly unsaturated and oxygen-rich components (lignin-like or tannin-like) and had molecular masses less than 450 Dalton. A group of about 70 components was partially degraded (significant negative slope, present in all samples). These components were more saturated and less oxygen-rich compared to the product group and had molecular masses > 450 Dalton. A third group of about 150 components was identified with a tendency to total degradation (significant negative slope, not present in all samples, reduced or no abundance at the end of the experiment

  20. Elements in biological AMS

    International Nuclear Information System (INIS)

    Vogel, J.S.; McAninch, J.; Freeman, S.

    1996-08-01

    AMS (Accelerator Mass Spectrometry) provides high detection sensitivity for isotopes whose half-lives are between 10 years and 100 million years. 14 C is the most developed of such isotopes and is used in tracing natural and anthropogenic organic compounds in the Earth's biosphere. Thirty-three elements in the main periodic table and 17 lanthanides or actinides have long lived isotopes, providing potential tracers for research in elemental biochemistry. Overlap of biologically interesting heavy elements and possible AMS tracers is discussed

  1. Rahvusliku ajaloo tõlgendusi eesti draamas ja teatris 1970.–1980. aastatel. Interpretations of National History in Estonian Drama and Theatre in the 1970s–1980s

    Directory of Open Access Journals (Sweden)

    Piret Kruuspere

    2012-04-01

    Full Text Available According to theatre scholar Freddie Rokem, theatre portraying or performing historical events is seeking to overcome both the separation and the exclusion from the past, as well as ’striving to create a community where the events from this past will matter again’. This article covers the topic of interpretations of national history in Estonian theatre and in original dramaturgy during the Soviet era, with the focus on aspects like national self-reflection and the relationship to the common past. The main focus is on the 1970s, with examples from Rein Saluri’s, Mati Unt’s and Jaan Kaplinski’s drama productions. During the period in question, re-tellings of national history on Estonian theatre stages were clothed in metaphors, allusions and secret codes – Aesopian language. Within the Soviet cultural context, I analyse if and to what extent theatre of the time displayed resistance, political theatre or social allegory. Theatre was also connected with the principle of playing or playfulness, which on one hand indicates national resistance, national endurance, and a certain survival strategy, but on the other hand indicates the Estonian as being an involuntary homo ludens – the Playing Man, who through various enforced roles is trying to adjust to the whirlwinds of history. Saluri’s first play, the intellectual drama Külalised (The Guests, opens with an allusion to a drama classic the world over, William Shakespeare’s Hamlet, adding a powerful national-symbolic background to the play. The role-play which permeates and structures the play (The Host–The Guest however, displays allegorical references to changes in the status and self-image of Estonians. In Unt’s play Peaproov (Dress Rehearsal, the principle of playing/acting sheds ironic light on the makers of an historical film and their readiness to create superficially flashy interpretations at any cost: this take acts as an estranging and generalising reflection in a context

  2. Galvanic element. Galvanisches Element

    Energy Technology Data Exchange (ETDEWEB)

    Sprengel, D.; Haelbig, H.

    1980-01-03

    The invention concerns a gas-tight sealed accumulator with positive and negative electrode plates and an auxillary electrode electroconductively bound to the latter for suppressing oxygen pressure. The auxillary electrode is an intermediate film electrode. The film catalysing oxygen reduction is hydrophilic in character and the other film is hydrophobic. A double coated foil has proved to be advantageous, the hydrophilic film being formed from polymer-bound activated carbon and the hydrophrobic film from porous polytetrafluoroethylene. A metallic network of silver or nickel is rolled into the outer side of the activated carbon film. This auxillary electrode can be used to advantage in all galvanic elements. Even primary cells fall within the scope of application for auxillary electrodes because many of these contain a highly oxidized electrodic material which tends to give off oxygen.

  3. Experiences of a long-term randomized controlled prevention trial in a maiden environment: Estonian Postmenopausal Hormone Therapy trial

    Directory of Open Access Journals (Sweden)

    Rahu Mati

    2008-08-01

    Full Text Available Abstract Background Preventive drugs require long-term trials to show their effectiveness or harms and often a lot of changes occur during post-marketing studies. The purpose of this article is to describe the research process in a long-term randomized controlled trial and discuss the impact and consequences of changes in the research environment. Methods The Estonian Postmenopausal Hormone Therapy trial (EPHT, originally planned to continue for five years, was planned in co-operation with the Women's International Study of Long-Duration Oestrogen after Menopause (WISDOM in the UK. In addition to health outcomes, EPHT was specifically designed to study the impact of postmenopausal hormone therapy (HT on health services utilization. Results After EPHT recruited in 1999–2001 the Women's Health Initiative (WHI in the USA decided to stop the estrogen-progestin trial after a mean of 5.2 years in July 2002 because of increased risk of breast cancer and later in 2004 the estrogen-only trial because HT increased the risk of stroke, decreased the risk of hip fracture, and did not affect coronary heart disease incidence. WISDOM was halted in autumn 2002. These decisions had a major influence on EPHT. Conclusion Changes in Estonian society challenged EPHT to find a balance between the needs of achieving responses to the trial aims with a limited budget and simultaneously maintaining the safety of trial participants. Flexibility was the main key for success. Rapid changes are not limited only to transiting societies but are true also in developed countries and the risk must be included in planning all long-term trials. The role of ethical and data monitoring committees in situations with emerging new data from other studies needs specification. Longer funding for preventive trials and more flexibility in budgeting are mandatory. Who should prove the effectiveness of an (old drug for a new preventive indication? In preventive drug trials companies may

  4. Measuring oxygen yields of a thermal conversion/elemental analyzer-isotope ratio mass spectrometer for organic and inorganic materials through injection of CO.

    Science.gov (United States)

    Yin, Xijie; Chen, Zhigang

    2014-12-01

    The thermal conversion/elemental analyzer-isotope ratio mass spectrometer (TC/EA-IRMS) is widely used to measure the δ(18) O value of various substances. A premise for accurate δ(18) O measurement is that the oxygen in the sample can be converted into carbon monoxide (CO) quantitatively or at least proportionally. Therefore, a precise method to determine the oxygen yield of TC/EA-IRMS measurements is needed. Most studies have used the CO peak area obtained from a known amount of a solid reference material (for example, benzoic acid) to calibrate the oxygen yield of the sample. Although it was assumed that the oxygen yield of the solid reference material is 100%, no direct evidence has been provided. As CO is the analyte gas for δ(18) O measurement by IRMS, in this study, we use a six-port valve to inject CO gas into the TC/EA. The CO is carried to the IRMS by the He carrier gas and the CO peak area is measured by the IRMS. The CO peak area thus obtained from a known amount of the injected CO is used to calibrate the oxygen yield of the sample. The oxygen yields of commonly used organic and inorganic reference materials such as benzoic acid (C6 H5 COOH), silver phosphate (Ag3 PO4 ), calcium carbonate (CaCO3 ) and silicon dioxide (SiO2 ) are investigated at different reactor temperatures and sample sizes. We obtained excellent linear correlation between the peak area for the injected CO and its oxygen atom amount. C6 H5 COOH has the highest oxygen yield, followed by Ag3 PO4 , CaCO3 and SiO2 . The oxygen yields of TC/EA-IRMS are less than 100% for both organic and inorganic substances, but the yields are relatively stable at the specified reactor temperature and for a given quantity of sample. Copyright © 2014 John Wiley & Sons, Ltd.

  5. Eesti patsient. Haiguse ja haige inimese kujutamise mudel 19. sajandi eesti kultuuris ja kirjasõnas. The Estonian Patient: A Model for the Representation of Illness and the Ill in 19th Century Estonian Culture and Letters

    Directory of Open Access Journals (Sweden)

    Janek Kraavi

    2012-04-01

    Full Text Available The portrait of the 18th and 19th century „Estonian patient” sketched in this article is a theoretical model of the ill person, based mainly on literary texts, but with reference to a variety of scientific and popular-scientific material. The point of departure is the classic postcolonial theorist, Frantz Fanon, in whose writings medicine, healing, and discourse on such topics are seen as the functioning of a specific colonial practice. The most notable characteristic of the figure of the Estonian patient is non-communicativeness. Communication is avoided and feared primarily because it has to be directed toward those in higher positions of power, or to institutions that embody power (the apothecary, the hospital. While these traits also characterize the separation between peasants and their rulers more generally, in a situation of illness the exclusion is felt with a double intensity. Sickness casts the peasant in a double bind: when in need of help or healing, contact across the divide between social rank, and – more broadly, between two cultures and ways of understanding the world, becomes unavoidable. In such situations, illness signifies an intensification of the gap in social standing. The ill person, who already stands on a lower rung of the social hierarchy, becomes all the more marginalized. In keeping with these observations, the real reason behind indecisiveness and refusal of medical treatment may well be an effort to avoid or postpone humiliation on the basis of lower social standing. Other contributing factors might include unconscious resistance – or even a conscious model of resistance – in the psyche, which manifests as an avoidance of communication. The content and motivating force for the model is not heroism, but rather a sense of shame. Indeed, behind the context of medical culture lurks ethnic and material isolation. The individual’s economic situation, living conditions, education and – most important – his

  6. Contributions of biomass/biofuel burning to organic aerosols and particulate matter in Tanzania, East Africa, based on analyses of ionic species, organic and elemental carbon, levoglucosan and mannosan

    Science.gov (United States)

    Mkoma, S. L.; Kawamura, K.; Fu, P. Q.

    2013-10-01

    Atmospheric aerosol samples of PM2.5 and PM10 were collected at a rural site in Tanzania, East Africa, in 2011 during wet and dry seasons and were analysed for carbonaceous components, levoglucosan, mannosan and water-soluble inorganic ions. The contributions of biomass/biofuel burning to the organic carbon (OC) and particulate matter (PM) mass were estimated to be 46-52% and 87-13%, respectively. The mean mass concentrations of PM2.5 and PM10 were 28 ± 6 μg m-3 and 47 ± 8 μg m-3 in wet season, and 39 ± 10 μg m-3 and 61 ± 19 μg m-3 in dry season, respectively. Total carbon (TC) accounted for 16-19% of the PM2.5 mass and 13-15% of the PM10 mass. On average, 86 to 89% of TC in PM2.5 and 87 to 90% of TC in PM10 was OC, of which 67-72% and 63% was found to be water-soluble organic carbon (WSOC) in PM2.5 and PM10, respectively. We found that concentrations of levoglucosan and mannosan (specific organic tracers of pyrolysis of cellulose) well correlated with non-sea-salt potassium (nss-K+) (r2 = 0.56-0.75), OC (r2 = 0.75-0.96) and WSOC (r2 = 0.52-0.78). The K+ / OC ratios varied from 0.06 to 0.36 in PM2.5 and from 0.03 to 0.36 in PM10 with slightly higher ratios in dry season. Mean percent ratios of levoglucosan and mannosan to OC were found to be 3-4% for PM2.5 and PM10 in both seasons. We found lower levoglucosan / K+ ratios and higher K+ / EC (elemental carbon) ratios in the biomass-burning aerosols from Tanzania than those reported from other regions. This feature is consistent with the high levels of potassium reported in the soils of Morogoro, Tanzania, suggesting an importance of direct emission of potassium by soil resuspension although K+ is present mostly in fine particles. It is also likely that biomass burning of vegetation of Tanzania emits high levels of potassium that may be enriched in plant tissues. The present study demonstrates that emissions from mixed biomass- and biofuel-burning activities largely influence the air quality in Tanzania.

  7. Contributions of biomass/biofuel burning to organic aerosols and particulate matter in Tanzania, East Africa, based on analyses of ionic species, organic and elemental carbon, levoglucosan and mannosan

    Directory of Open Access Journals (Sweden)

    S. L. Mkoma

    2013-10-01

    Full Text Available Atmospheric aerosol samples of PM2.5 and PM10 were collected at a rural site in Tanzania, East Africa, in 2011 during wet and dry seasons and were analysed for carbonaceous components, levoglucosan, mannosan and water-soluble inorganic ions. The contributions of biomass/biofuel burning to the organic carbon (OC and particulate matter (PM mass were estimated to be 46–52% and 87–13%, respectively. The mean mass concentrations of PM2.5 and PM10 were 28 ± 6 μg m−3 and 47 ± 8 μg m−3 in wet season, and 39 ± 10 μg m−3 and 61 ± 19 μg m−3 in dry season, respectively. Total carbon (TC accounted for 16–19% of the PM2.5 mass and 13–15% of the PM10 mass. On average, 86 to 89% of TC in PM2.5 and 87 to 90% of TC in PM10 was OC, of which 67–72% and 63% was found to be water-soluble organic carbon (WSOC in PM2.5 and PM10, respectively. We found that concentrations of levoglucosan and mannosan (specific organic tracers of pyrolysis of cellulose well correlated with non-sea-salt potassium (nss-K+ (r2 = 0.56–0.75, OC (r2 = 0.75–0.96 and WSOC (r2 = 0.52–0.78. The K+ / OC ratios varied from 0.06 to 0.36 in PM2.5 and from 0.03 to 0.36 in PM10 with slightly higher ratios in dry season. Mean percent ratios of levoglucosan and mannosan to OC were found to be 3–4% for PM2.5 and PM10 in both seasons. We found lower levoglucosan / K+ ratios and higher K+ / EC (elemental carbon ratios in the biomass-burning aerosols from Tanzania than those reported from other regions. This feature is consistent with the high levels of potassium reported in the soils of Morogoro, Tanzania, suggesting an importance of direct emission of potassium by soil resuspension although K+ is present mostly in fine particles. It is also likely that biomass burning of vegetation of Tanzania emits high levels of potassium that may be enriched in plant tissues. The present study demonstrates that emissions from mixed biomass- and biofuel-burning activities largely

  8. The effects of political and economic transitions on health and safety in Estonia: an Estonian-Swedish comparative study.

    Science.gov (United States)

    Kaasik, T; Andersson, R; Hörte, L G

    1998-11-01

    A general and dramatic deterioration of health in Estonia during the transition period 1990-1994 was analysed using Sweden as a comparative example. Though there were diverging trends between Estonia and Sweden in the leading cause of death, cardiovascular diseases, the gap in mortality from injury had increased most rapidly. While the injury mortality rate slightly decreased in Sweden from 1990 to 1994, it almost doubled in Estonia. In 1994, the total injury death rate for men was about 6 times higher in Estonia than in Sweden. The death rates for some types of injuries, such as alcohol intoxication and homicide, were many tenfolds higher in Estonia than in Sweden. Injury contributed the most to the widening health gap between the countries, especially in males. The mechanisms of this sudden health deterioration remain to be fully explained. It could be hypothesised that behind the traditional behavioural risk factors, the influence of socio-political factors related to economic and political reconstruction is present. A widespread risk-taking and unhealthy behaviour among Estonians can likely be partly explained as a way of coping with the distress created by the new demands of transition society. An important challenge on the way to improvement is creating the political will among policy-makers to confront the tremendous problems of controlling the factors in society that affect the population's health in Estonia.

  9. Characterization and source apportionment of atmospheric organic and elemental carbon during fall and winter of 2003 in Xi'an, China

    Directory of Open Access Journals (Sweden)

    J. J. Cao

    2005-01-01

    Full Text Available Continuous measurements of atmospheric organic and elemental carbon (OC and EC were taken during the high-pollution fall and winter seasons at Xi'an, Shaanxi Province, China from September 2003 through February 2004. Battery-powered mini-volume samplers collected PM2.5 samples daily and PM10 samples every third day. Samples were also obtained from the plumes of residential coal combustion, motor-vehicle exhaust, and biomass burning sources. These samples were analyzed for OC/EC by thermal/optical reflectance (TOR following the Interagency Monitoring of Protected Visual Environments (IMPROVE protocol. OC and EC levels at Xi'an are higher than most urban cities in Asia. Average PM2.5 OC concentrations in fall and winter were 34.1±18.0 μg m−3 and 61.9±;33.2 μg m−3, respectively; while EC concentrations were 11.3±6.9 μg m−3 and 12.3±5.3 μg m−3, respectively. Most of the OC and EC were in the PM2.5 fraction. OC was strongly correlated (R>0.95 with EC in the autumn and moderately correlated (R=0.81 with EC during winter. Carbonaceous aerosol (OC×1.6+EC accounted for 48.8%±10.1% of the PM2.5 mass during fall and 45.9±7.5% during winter. The average OC/EC ratio was 3.3 in fall and 5.1 in winter, with individual OC/EC ratios nearly always exceeding 2.0. The higher wintertime OC/EC corresponded to increased residential coal combustion for heating. Total carbon (TC was associated with source contributions using absolute principal component analysis (APCA with eight thermally-derived carbon fractions. During fall, 73% of TC was attributed to gasoline engine exhaust, 23% to diesel exhaust, and 4% to biomass burning. During winter, 44% of TC was attributed to gasoline engine exhaust, 44% to coal burning, 9% to biomass burning, and 3% to diesel engine exhaust.

  10. Involvement of Russian Organized Crime Syndicates, Criminal Elements in the Russian Military, and Regional Terrorist Groups in Narcotics Trafficking in Central Asia, the Caucasus, and Chechnya

    National Research Council Canada - National Science Library

    Curtis, Glenn E

    2002-01-01

    ... (Armenia, Azerbaijan, and Georgia), and in Chechnya. The purpose of the report is to reveal the role of Russian organized crime and Central Asian terrorist organizations in narcotics trafficking in those areas...

  11. Noor-Eesti enesekoloniseerimisprojekt. Teine osa Olulised kirjandusmõtteviisid . The Self-Colonization Project of Young Estonia. Part II. Modes of Literary Thinking and Relations with Colonialism in Estonian Literature of the beginning of the 20th century

    Directory of Open Access Journals (Sweden)

    Tiit Hennoste

    2012-04-01

    Full Text Available The topic of this article is the literary discourse of Young Estonia; its relations with other important Estonian literary discourses from the beginning of the 20th century, and its relations with colonial cultural discourse. First, I give an overview of the basic positions of the Young Estonians’ literary discourse, the main shapers of which were Friedebert Tuglas, Gustav Suits, later on Johannes Semper as well. Next, I present the basic principles of three Estonian literary discourses from the beginning of the 20th century, which were also important to the Young Estonians: nationalist-naturalistic (close-to-life; socialist/ class-based, and 20th century modernist. The Young Estonians began as nationalists and/or socialists. During the formation of Young Estonia’s discourse at the end of the first and beginning of the second decade of the 20th century, 20th century modernism began, which the Young Estonians regarded first and foremost with irony. The Young Estonians’ literary discourse is a mixture of aestheticism, decadence, symbolism, romanticism, and classicism. The point of departure for the Young Estonian approach to literature was eurocentrism. They took a superior and negative view of existing Estonian literature, which they regarded as having fallen drastically behind Europe. Since it was unable to build on its own foundation, it had to borrow from Europe. The discourse’s understandings of cultural values – theory, reading, knowledge, ready-made culture, derive from the centrality of the dynamic of borrowing. New culture could be created freely, without the support of previous local tradition; it was to be an elite culture, while the writer remained an individualist. Literature was to follow the principle of art for art’s sake; aesthetics and the form of the work of art were basic criteria. The formal ideals of the work of art were classicist: unity, integrity (wholeness, harmony, order, logic, etc. Thirdly, I outline the

  12. Short rotation willow coppice for renewable energy and improved environment. Proceedings of a joint Swedish - Estonian seminar on energy forestry and vegetation filters

    International Nuclear Information System (INIS)

    Perttu, K.; Koppel, A.

    1996-01-01

    The overall aim of the present seminar was to present and discuss results from the joint Swedish - Estonian energy forestry research activities during the period of 1993-1995 and to publish the papers in a technical report. The results is a publication, presenting interesting methods and results, and is meant partly to serve as the final report of the joint efforts during the period mentioned, partly to be used for future planning of new projects and for application of funding for a continued cooperation. Separate abstracts have been prepared for all of the 17 papers in the report

  13. Organic Compounds, Trace Elements, Suspended Sediment, and Field Characteristics at the Heads-of-Tide of the Raritan, Passaic, Hackensack, Rahway, and Elizabeth Rivers, New Jersey, 2000-03

    Science.gov (United States)

    Bonin, Jennifer L.; Wilson, Timothy P.

    2006-01-01

    Concentrations of suspended sediment, particulate and dissolved organic carbon, trace elements, and organic compounds were measured in samples from the heads-of-tide of the five tributaries to the Newark and Raritan Bays during June 2000 to June 2003. The samples were collected as part of the New Jersey Department of Environmental Protection Toxics Reduction Workplan/Contaminant Assessment Reduction Program. Samples of streamwater were collected at water-quality sampling stations constructed near U.S. Geological Survey gaging stations on the Raritan, Passaic, Hackensack, Rahway, and Elizabeth Rivers. Sampling was conducted during base-flow conditions and storms. Constituent concentrations were measured to determine the water quality and to calculate the load of sediment and contaminants contributed to the bays from upstream sources. Water samples were analyzed for suspended sediment, dissolved organic carbon, particulate organic carbon, and specific conductance. Samples of suspended sediment and water were analyzed for 98 distinct polychlorinated biphenyl congeners, 7 dioxins, 10 furans, 27 pesticides, 26 polycyclic aromatic hydrocarbons, and the trace elements cadmium, lead, mercury, and methyl-mercury. Measurements of ultra-low concentrations of organic compounds in sediment and water were obtained by collecting 1 to 3 grams of suspended sediment on glass fiber filters and by passing at least 20 liters of filtered water through XAD-2 resin. The extracted sediment and XAD-2 resin were analyzed for organic compounds by high- and low-resolution gas chromatography mass-spectrometry that uses isotope dilution procedures. Trace elements in filtered and unfiltered samples were analyzed for cadmium, lead, mercury, and methyl-mercury by inductively coupled charged plasma and mass-spectrometry. All constituent concentrations are raw data. Interpretation of the data will be completed in the second phase of the study.

  14. Transplutonium elements

    Energy Technology Data Exchange (ETDEWEB)

    Sivaramakrishnan, C. K.; Jadhav, A. V.; Reghuraman, K.; Mathew, K. A.; Nair, P. S.; Ramaniah, M. V.

    1973-07-01

    Research progress is reported on studies of the transplutonium elements including recovery and purification of americium, preparation of /sup 238/Pu, extraction studies using diethylhexyl phosphate. (DHM)

  15. Smoking prevalence and attitudes towards smoking among Estonian physicians: results from cross-sectional studies in 2002 and 2014.

    Science.gov (United States)

    Põld, Mariliis; Pärna, Kersti

    2017-11-25

    To explore smoking prevalence and attitudes towards smoking among Estonian physicians in 2002 and 2014. Two self-administered cross-sectional postal surveys were conducted among practising physicians in Estonia. Initial sample consisted of all practising physicians in Estonia. The corrected response rate was 67.8% in 2002 and 53.1% in 2014. Present study sample was restricted to physicians younger than 65 years (n=2549 in 2002, n=2339 in 2014). Age-standardised prevalence of smoking and prevalence of agreement with seven statements concerning attitudes towards smoking was determined. To analyse association of physicians' attitudes towards smoking with study year and smoking status, logistic regression analysis was used. Adjusted ORs of agreement with the seven statements were determined. Corresponding 95% CIs were calculated. The age-standardised prevalence of current smoking among men was 26.8% in 2002 and 15.3% in 2014, among women 10.4% and 5.8%, respectively. Compared with the year 2002, in 2014, prevalence of agreement with statements declaring harmfulness of smoking was higher and prevalence of agreement with statements approving smoking was lower. Adjusted ORs showed that compared with 2002, physicians' attitudes towards smoking were less favourable in 2014, and physicians' attitudes towards smoking were associated with their smoking status. Compared with 2002, the age-standardised smoking prevalence among male and female physicians was lower, and attitudes towards smoking were less approving in 2014. The smoking physicians had more approving attitudes towards smoking than their non-smoking colleagues. © Article author(s) (or their employer(s) unless otherwise stated in the text of the article) 2017. All rights reserved. No commercial use is permitted unless otherwise expressly granted.

  16. Relationships between luteal activity, fertility, blood metabolites and body condition score in multiparous Estonian Holstein dairy cows under different management.

    Science.gov (United States)

    Samarütel, Jaak; Waldmann, Andres; Ling, Katri; Jaakson, Hanno; Kaart, Tanel; Leesmäe, Andres; Kärt, Olav

    2008-11-01

    The objective was to compare the relationships between luteal activity and fertility, and relate these parameters to metabolic indices and body condition changes in multiparous Estonian Holstein cows on two commercial dairy farms under different management and levels of production and nutrition (higher, H, n=54 (71 lactations) and lower, L, n=39 (39 lactations)). For statistical analysis cows were categorized according to their milk progesterone (P4) profiles as follows: normal ovarian function; delayed start of cyclicity (DC) (interval from calving to first luteal response (P45 ng/ml up to and more than 50 d respectively, followed by regular cyclicity); cessation of luteal activity (prolonged interluteal interval, P4bodies, non-esterified fatty acids, total cholesterol) and aspartate aminotransferase, body condition scores (BCS) and fertility parameters between the two farms, and also fertility parameters between the farms within P4 categories. Differences in milk fat/protein ratio, ketone body levels and BCS indicated a deeper negative energy balance (NEB) during the first month after calving on farm L. On both farms nearly 50% of the recently calved dairy cows suffered from ovarian dysfunction during the post-partum period. Delayed start of cyclicity was the most prevalent abnormal P4 profile, 25% and 28% on farms H and L, respectively. Prolonged luteal activity accounted for one-third of atypical ovarian patterns on farm H, and cessation of luteal activity on farm L. On farm L, DC cows had lower BCS values from day 10 to day 90 after calving compared with normal cows (Pcows lost more BCS (1.2 units) during the 40 d after calving than normal resumption cows (0.75 units; P<0.05). On farm H with moderate NEB the delayed start of ovulation post partum did not impair subsequent reproductive performance.

  17. The Missing Elements of Change. A Response to "Youth Change Agents: Comparing the Sociopolitical Identities of Youth Organizers and Youth Commissioners"

    Science.gov (United States)

    Goldwasser, Matthew L.

    2016-01-01

    By establishing a set of theoretical frameworks to view and compare the work of youth organizers and youth commissioners, and through personal interviews, the authors of the paper "Youth Change Agents: Comparing the Sociopolitical Identities of Youth Organizers and Youth Commissioners" presented their explanation of the development of…

  18. #IHeartChemistryNCSU: Free Choice, Content, and Elements of Science Communication as the Framework for an Introductory Organic Chemistry Project

    Science.gov (United States)

    Frohock, Bram H.; Winterrowd, Samantha T.; Gallardo-Williams, Maria T.

    2018-01-01

    Students in a large introductory organic chemistry class were given the freedom to choose an organic compound of interest and were challenged to develop an educational object (physical or digital) designed to be shared with the broader public via social media. Analysis of the project results shows that most students appreciated the open nature of…

  19. Varying response of the concentration and content of soybean seed mineral elements, carbohydrates, organic acids, amino acids, protein, and oil to phosphorus starvation and CO2 enrichment

    Science.gov (United States)

    A detailed investigation of the concentration (g-1 seed weight) and content (g plant-1) of seed mineral elements and metabolic profile under phosphorus (P) starvation at ambient (aCO2) and elevated carbon dioxide (eCO2) in soybean is limited. Soybean plants were grown in a controlled environment at ...

  20. Neither Reb1p nor poly(dA*T) elements are responsible for the highly specific chromatin organization at the ILV1 promoter

    DEFF Research Database (Denmark)

    Moreira, José Manuel Alfonso; Hörz, Wolfram; Holmberg, Steen

    2001-01-01

    Analysis of the chromatin structure at the yeast ILV1 locus revealed highly positioned nucleosomes covering the entire locus except for a hypersensitive site in the promoter region. All previously identified cis-acting elements required for GCN4-independent ILV1 basal level transcription, includi...

  1. Biological dosimetric studies in the Chernobyl radiation accident, on populations living in the contaminated areas (Gomel regions) and in Estonian clean-up workers, using FISH technique

    International Nuclear Information System (INIS)

    Darroudi, F.; Natarajan, A.T.

    1996-01-01

    In order to perform retrospective estimations of radiation doses seven years after the nuclear accident in Chernobyl, the frequencies of chromosomal aberrations in the peripheral blood lymphocytes of individuals living in contaminated areas around Chernobyl and the Estonian clean-up workers were determined. The first study group composed of 45 individuals living in four areas (i.e. Rechitsa, Komsomolski, Choiniki and Zaspa) in the vicinity (80-125 km) of Chernobyl and 20 individuals living in Minsk (control group - 340 km from Chernobyl). The second study group (Estonian clean-up workers) composed of 26 individuals involved in cleaning up the Chernobyl for a different period of time (up to 7 months) and a matched control group consisting of 9 probands. Unstable aberrations (dicentrics and rings) were scored in Giemsa stained preparations and stable aberrations (translocations) were analyzed using chromosome specific DNA libraries and fluorescence in situ hybridization (FISH) technique. For both study groups the estimated average dose is between 0,1-0,4 Gy. Among the people living in the contaminated areas in the vicinity of Chernobyl, a higher frequency of numerical aberrations (i.e. trisomy, hyper diploidy) was evident

  2. Toxic Elements

    DEFF Research Database (Denmark)

    Hajeb, Parvaneh; Shakibazadeh, Shahram; Sloth, Jens Jørgen

    2016-01-01

    Food is considered the main source of toxic element (arsenic, cadmium, lead, and mercury) exposure to humans, and they can cause major public health effects. In this chapter, we discuss the most important sources for toxic element in food and the foodstuffs which are significant contributors to h...

  3. Influence of seaweed extract as an organic fertilizer on the growth and yield of Arachis hypogea L. and their elemental composition using SEM–Energy Dispersive Spectroscopic analysis

    Directory of Open Access Journals (Sweden)

    G. Ganapathy Selvam

    2014-03-01

    Conclusion: It is suggested that there are considerable gains to be made in increasing yield and stabilizing the yield in environments characterized by terminal requirement for organic and by shortening crop duration nutrient management appear promising.

  4. Inorganic elements and organic compounds degradation studies by gamma irradiation in used lubricating oils; Estudos de remocao de elementos inorganicos e degradacao de compostos organicos por radiacao gama em oleos lubrificantes usados

    Energy Technology Data Exchange (ETDEWEB)

    Scapin, Marcos Antonio

    2008-07-01

    The automotive lubricating oils have partial degradation of organic compounds and addition of undesirable inorganic elements, during its use. These substances classify the used lubricating oils as dangerous and highly toxic. According to global consensus, concerning the environmental conservation, the best is to perform a reuse treatment of these lubricating oils. For this purpose, the uses of an alternative and effective technology have been sought. In this work, the efficacy and technical feasibility of the advanced oxidation process (AOP), by gamma radiation, for used automotive lubricating oil treatment has been studied. Different quantities of hydrogen peroxide and water Milli-Q were added to oil samples. They were submitted to the Cobalt-60 irradiator, type Gammacell, with 100, 200 and 500 kGy absorbed doses. The inorganic analysis by X-ray fluorescence (WDXRF) showed inorganic elements removal, mainly to sulphur, calcium, iron and nickel elements at acceptable levels by environmental protection law for oils reusing. The gas chromatography (GC/MS) analysis showed that the advanced oxidation process promotes the organic compounds degradation. The main identified compounds were tridecane, 2-methyl-naphthalene, and trietilamina-tetramethyl urea, which have important industrial applications. The multivariate analysis, Cluster Analysis, showed that advanced oxidation process application is a viable and promising treatment for used lubricating oil reusing. (author)

  5. Effects of organic ligands on fractionation of rare earth elements (REEs) in hydroponic plants: an application to the determination of binding capacities by humic acid for modeling.

    Science.gov (United States)

    Ding, ShiMing; Liang, Tao; Zhang, ChaoSheng; Yan, JunCai; Zhang, ZiLi

    2006-12-01

    Previous studies have revealed the fractionation processes of rare earth elements (REEs) in hydroponic plants, with a heavy REE (HREE, the elements from Gd to Lu) enrichment in leaves. In this study, effects on the HREE enrichment in soybean leaves with additions of carboxylic acids (acetate, malate, citrate, NTA, EDTA and DTPA) and two soil humic acids (HAs) were investigated. REE speciation in carboxylic acid and HA solutions was simulated using Visual MINTEQ and Model V, respectively. The results showed that the effects caused by carboxylic acids were strongly dependent on the differences between their binding strengths for light REEs (LREEs, the elements from La to Eu) and those for HREEs. A good correlation existed between these effects and the changes of free REE ions in solutions. This relationship was also observed for the HA treatments, provided that the intrinsic equilibrium constants of REEs for cation-proton exchange with HA (i.e., pK(MHA)) in Model V were estimated using a free-energy relationship with the stability constants for REE complexation with lactic acid. It is suggested that this set of pK(MHA) values is more suitable for use in Model V for the simulation of REE complexation with HA.

  6. “Viimne reliikvia” ja “Kolme katku vahel”: ruumist eesti ajalookirjanduse ekraniseeringutes / The Last Relic and Between Three Plagues: On Space in Film Adaptations of Estonian Historical Fiction

    Directory of Open Access Journals (Sweden)

    Eva Näripea

    2015-06-01

    Full Text Available Teesid: Artikkel keskendub kahele ajalooromaani ekraniseeringule Nõukogude Eesti filmikunstis: „Viimne reliikvia“ (1969, rež Grigori Kromanov, Tallinnfilm, mis põhineb Eduard Bornhöhe romaanil „Vürst Gabriel ehk Pirita kloostri viimsed päevad“ (1893, ning „Kolme katku vahel“ (1970, rež Virve Aruoja, Eesti Telefilm, mille seosed oma kirjandusliku allikaga (Jaan Krossi samanimelise romaaniga on oluliselt keerulisemad. Ekraniseeringuid käsitletakse ruumirepresentatsioonide perspektiivist, uurides, missuguseid strateegiaid kasutati filmiruumide loomisel, kuidas suhestuti kirjandusliku (lähtematerjaliga ning millised ajaloonarratiivi ja rahvusliku identiteedi vahekorrad neis kangastuvad. SU M M A R Y This article examines two Soviet Estonian screen adaptations of historical novels: The Last Relic (Viimne reliikvia, Tallinnfilm, 1969, directed by Grigori Kromanov, based on Eduard Bornhöhe’s novel Prince Gabriel or The Last Days of Pirita Monastery (1893, which became a box-office hit throughout the Soviet Union and even beyond; and Between Three Plagues (Kolme katku vahel, Eesti Telefilm, 1970, directed by Virve Aruoja which reached much more limited TV-audiences; the connections between this film and its literary „source“ (a novel of the same name by Jaan Kross are much more complicated. These screen adaptations are considered from the perspective of spatial representations. I examine which strategies and devices the scriptwriters, directors and production designers drew upon when constructing these cinematic spaces and how they related to their literary hypotexts. As generally for adaptations of historical novels to other media, both The Last Relic and Between Three Plagues speak (perhaps even primarily about their time of production, about the present rather than the past. In this regard, it is important to recall the role of Tallinn’s Old Town as a locus of resistance in Soviet Estonian culture. Arguably

  7. Creativity Management Key Elements

    Directory of Open Access Journals (Sweden)

    Rosa María Fuchs Ángeles

    2015-09-01

    Full Text Available Organizations are constantly looking towards innovation. In order to reach it they must foment creativity. This paper analyzes a series of elements considered in the organizational creativity management and proposes a model with the indispensable factors that organizations should consider to reach it. These elements are: culture and organizational environment, strategy, structure, communication, relation with customers, human resources (recruiting, training, job design, compensation, promotion, and performance evaluation, long term orientation and the organizational life cycle. Having the analysis of those elements as a basis, the indispensable pillars on management creativity are identified. The proposed model is based on 5 pillars: the alignment between strategic, culture and organizational structure, called by the authors 'Holy Trinity'; intern publicity; customer’s voice; recognition and a look towards future. Finally, the case of an innovative Peruvian enterprise is presented from the model’s perspective and the study conclusions.

  8. Fuel element

    International Nuclear Information System (INIS)

    Armijo, J.S.

    1976-01-01

    A fuel element for nuclear reactors is proposed which has a higher corrosion resisting quality in reactor operations. The zirconium alloy coating around the fuel element (uranium or plutonium compound) has on its inside a protection layer of metal which is metallurgically bound to the substance of the coating. As materials are namned: Alluminium, copper, niobium, stainless steel, and iron. This protective metallic layer has another inner layer, also metallurgically bound to its surface, which consists usually of a zirconium alloy. (UWI) [de

  9. Organic, Gas, and Element Geochemistry of Hydrothermal Fluids of the Newly Discovered Extensive Hydrothermal Area in the Wallis and Futuna Region (SW Pacific

    Directory of Open Access Journals (Sweden)

    C. Konn

    2018-01-01

    Full Text Available Two newly discovered hydrothermal vent fields of the Wallis and Futuna region, Kulo Lasi and Fatu Kapa, were sampled for fluid geochemistry. A great geochemical diversity was observed and assigned to the diversity of lithologies as well as the occurrence of various processes. Kulo Lasi fluids likely formed by interaction with fresh volcanic rocks, phase separation, and mixing with magmatic fluid. Conversely, the geochemistry of the Fatu Kapa fluids would be mostly due to water/felsic lavas reactions. In terms of organic geochemistry, fluids from both fields were found to be enriched in formate, acetate, and semivolatile organic compounds (SVOCs: n-alkanes, n-fatty acids, and polyaromatic hydrocarbons (PAHs. Concentrations of SVOCs reached a few ppb at most. The distribution patterns of SVOCs indicated that several processes and sources, at once of biogenic, thermogenic, and abiogenic types, likely controlled organic geochemistry. Although the contribution of each process remains unknown, the mere presence of organics at the μM level has strong implications for metal dispersion (cycles, deposition (ore-forming, and bioavailability (ecosystems, especially as our fluxes estimations suggest that back-arc hosted vent fields could contribute as much as MOR to the global ocean heat and mass budget.

  10. Unique spectrum of SPAST variants in Estonian HSP patients: presence of benign missense changes but lack of exonic rearrangements

    Directory of Open Access Journals (Sweden)

    Gross-Paju Katrin

    2010-03-01

    Full Text Available Abstract Background Hereditary spastic paraplegia (HSP is a clinically and genetically heterogeneous disorder that can be an autosomal-dominant, autosomal-recessive, or X-linked disease. The most common autosomal-dominant form of the disease derives from mutations in the SPAST gene. Methods The aim of this study was to analyze 49 patients diagnosed with HSP from the Estonian population for sequence variants of the SPAST gene and to describe the associated phenotypes. Healthy control individuals (n = 100 with no family history of HSP were also analyzed. All patient samples were screened using denaturing high performance liquid chromatography (DHPLC and multiplex ligation-dependent probe amplification (MLPA assay. Samples with abnormal DHPLC and MLPA profiles were sequenced, with the same regions sequenced in control samples. Results Sequence variants of SPAST were identified in 19/49 HSP patients (38.8%, twelve among them had pathogenic mutations. Within the latter group there was one sporadic case. Eight patients had pure, and four - complex HSP. The twelve variants were identified: seven pathogenic (c.1174-1G>C, c.1185delA, c.1276C>T, c.1352_1356delGAGAA, c.1378C>A, c.1518_1519insTC, c.1841_1842insA and five non-pathogenic (c.131C>T, c.484G>A, c.685A>G, c.1245+202delG, c.1245+215G>C. Only 2 of these mutations had previously been described (c.131C>T, c.1245+202delG. Three mutations, c.1174-1G>C, c.1276 C>T, c.1378C>A, showed intrafamilial segregation. Conclusion This study identified new variants of the SPAST gene which included benign missense variants and short insertions/deletions. No large rearrangements were found. Based on these data, 7 new pathogenic variants of HSP are associated with clinical phenotypes.

  11. Fast determination of trace elements in organic fertilizers using a cup-horn reactor for ultrasound-assisted extraction and fast sequential flame atomic absorption spectrometry.

    Science.gov (United States)

    Teixeira, Leonel Silva; Vieira, Heulla Pereira; Windmöller, Cláudia Carvalhinho; Nascentes, Clésia Cristina

    2014-02-01

    A fast and accurate method based on ultrasound-assisted extraction in a cup-horn sonoreactor was developed to determine the total content of Cd, Co, Cr, Cu, Mn, Ni, Pb and Zn in organic fertilizers by fast sequential flame atomic absorption spectrometry (FS FAAS). Multivariate optimization was used to establish the optimal conditions for the extraction procedure. An aliquot containing approximately 120 mg of the sample was added to a 500 µL volume of an acid mixture (HNO3/HCl/HF, 5:3:3, v/v/v). After a few minutes, 500 µL of deionized water was added and eight samples were simultaneously sonicated for 10 min at 50% amplitude, allowing a sample throughput of 32 extractions per hour. The performance of the method was evaluated with a certified reference material of sewage sludge (CRM 029). The precision, expressed as the relative standard deviation, ranged from 0.58% to 5.6%. The recoveries of analytes were found to 100%, 109%, 96%, 92%, 101%, 104% and 102% for Cd, Cr, Cu, Mn, Ni, Pb and Zn, respectively. The linearity, limit of detection and limit of quantification were calculated and the values obtained were adequate for the quality control of organic fertilizers. The method was applied to the analysis of several commercial organic fertilizers and organic wastes used as fertilizers, and the results were compared with those obtained using the microwave digestion procedure. A good agreement was found between the results obtained by microwave and ultrasound procedures with recoveries ranging from 80.4% to 117%. Two organic waste samples were not in accordance with the Brazilian legislation regarding the acceptable levels of contaminants. © 2013 Published by Elsevier B.V.

  12. Application of different methodologies in the preparation of organic matrices for determination of trace elements by differential pulse anodic stripping voltammetry

    International Nuclear Information System (INIS)

    Sisti, Cristina

    2001-01-01

    The determination of trace elements in food samples is of great importance for the human health, considering the factors of essentiality and toxicity. On the other hand, the chemical analysis is largely affected for the steps of sample preparation; laboratory contamination of the sample and the reagents or still volatilization and losses of the elements. If these parameters are not controlled the achieved precision and accuracy could be low. In this work, the content of zinc, cadmium, lead and copper was determined in adults diet samples collected by duplicate portion technique and bovine liver, applying the differential pulse anodic stripping voltametry - (DP-ASV) technique. In the digestion of the matrices in acid medium, conventional methodologies were used, conductive heating in open recipients and equipment with microwaves source in open and closed vessels. The best procedure was the sample digestion by microwaves, in closed vessels and the other treatments made in controlled atmosphere with hood laminar-airflow class 100. The established methodology was validated with the use of a certified sample as reference (NIST - bovine liver 1577b). (author)

  13. Evaluation of the use of common sculpin (Myoxocephalus scorpius) organ histology as bioindicator for element exposure in the fjord of the mining area Maarmorilik, West Greenland

    Energy Technology Data Exchange (ETDEWEB)

    Sonne, Christian, E-mail: csh@dmu.dk [Aarhus University, Faculty of Science and Technology, Department of Bioscience, Arctic Research Centre (ARC), Frederiksborgvej 399, P.O. Box 358, DK-4000 Roskilde (Denmark); Bach, Lis; Søndergaard, Jens; Rigét, Frank F.; Dietz, Rune; Mosbech, Anders [Aarhus University, Faculty of Science and Technology, Department of Bioscience, Arctic Research Centre (ARC), Frederiksborgvej 399, P.O. Box 358, DK-4000 Roskilde (Denmark); Leifsson, Pall S. [University of Copenhagen, Faculty of Health and Medical Sciences, Department of Veterinary Disease Biology, Bülowsvej 17, DK-1870 Frederiksberg (Denmark); Gustavson, Kim [Aarhus University, Faculty of Science and Technology, Department of Bioscience, Arctic Research Centre (ARC), Frederiksborgvej 399, P.O. Box 358, DK-4000 Roskilde (Denmark)

    2014-08-15

    The former Black Angel lead–zinc mine in Maarmorilik, West Greenland, is a historic example of how mining activity may result in a significant impact on the surrounding fjord system in terms of elevated concentrations of especially lead (Pb) and zinc (Zn) in seawater, sediments and surrounding biota. In order to shed light on the present contamination and possible effects in the fjord we initiated a range of studies including a pilot study on gill and liver morphology of common sculpins (Myoxocephalus scorpius) around Maarmorilik. Sculpins were caught and sampled at five different stations known to represent a gradient of Pb concentrations. Fish livers from all specimens were analyzed for relevant elements in the area: Fe, Zn, As, Cu, Se, Cd, Pb, Ag, Hg, Co and Ni. Lead, As and Hg showed significant differences among the five stations. For 20% of the sculpins, Hg concentrations were in the range of lowest observed effect dose (LOED) of 0.1–0.5 μg/g ww for toxic threshold on reproduction and subclinical endpoints. Likewise LOEDs for tissue lesions, LOEDs for biochemistry, growth, survival and reproduction were exceeded for Cd (0.42–1.8 μg/g ww) and for As (11.6 μg/g ww) in 28% and 85% of the sculpins, respectively. Similar to this, the no observed effect dose (NOED) for biochemistry was exceeded for Pb (0.32 μg/g ww) and for growth, mortality and reproduction for Zn (60–68 μg/g ww) in 33% and 24% of the sculpins, respectively. For all sculpins, females were significantly larger than males and for five of the elements (Fe, Co, Ni, Cu, Se) females had higher concentrations. The chronic lesions observed in liver (mononuclear cell infiltrates, necrosis, vacuolar hepatocytes, portal fibrosis, bile duct hyperplasia, active melanomacrophage centers) and gills (fusion and edema of secondary lamellae, laminar telangiectasis, mononuclear cell infiltrates, blebs) were similar to those in the literature studies for both wild and laboratory exposed sculpins and

  14. Evaluation of the use of common sculpin (Myoxocephalus scorpius) organ histology as bioindicator for element exposure in the fjord of the mining area Maarmorilik, West Greenland

    International Nuclear Information System (INIS)

    Sonne, Christian; Bach, Lis; Søndergaard, Jens; Rigét, Frank F.; Dietz, Rune; Mosbech, Anders; Leifsson, Pall S.; Gustavson, Kim

    2014-01-01

    The former Black Angel lead–zinc mine in Maarmorilik, West Greenland, is a historic example of how mining activity may result in a significant impact on the surrounding fjord system in terms of elevated concentrations of especially lead (Pb) and zinc (Zn) in seawater, sediments and surrounding biota. In order to shed light on the present contamination and possible effects in the fjord we initiated a range of studies including a pilot study on gill and liver morphology of common sculpins (Myoxocephalus scorpius) around Maarmorilik. Sculpins were caught and sampled at five different stations known to represent a gradient of Pb concentrations. Fish livers from all specimens were analyzed for relevant elements in the area: Fe, Zn, As, Cu, Se, Cd, Pb, Ag, Hg, Co and Ni. Lead, As and Hg showed significant differences among the five stations. For 20% of the sculpins, Hg concentrations were in the range of lowest observed effect dose (LOED) of 0.1–0.5 μg/g ww for toxic threshold on reproduction and subclinical endpoints. Likewise LOEDs for tissue lesions, LOEDs for biochemistry, growth, survival and reproduction were exceeded for Cd (0.42–1.8 μg/g ww) and for As (11.6 μg/g ww) in 28% and 85% of the sculpins, respectively. Similar to this, the no observed effect dose (NOED) for biochemistry was exceeded for Pb (0.32 μg/g ww) and for growth, mortality and reproduction for Zn (60–68 μg/g ww) in 33% and 24% of the sculpins, respectively. For all sculpins, females were significantly larger than males and for five of the elements (Fe, Co, Ni, Cu, Se) females had higher concentrations. The chronic lesions observed in liver (mononuclear cell infiltrates, necrosis, vacuolar hepatocytes, portal fibrosis, bile duct hyperplasia, active melanomacrophage centers) and gills (fusion and edema of secondary lamellae, laminar telangiectasis, mononuclear cell infiltrates, blebs) were similar to those in the literature studies for both wild and laboratory exposed sculpins and

  15. Optimization of on-line hydrogen stable isotope ratio measurements of halogen- and sulfur-bearing organic compounds using elemental analyzer–chromium/high-temperature conversion isotope ratio mass spectrometry (EA-Cr/HTC-IRMS)

    Science.gov (United States)

    Gehre, Matthias; Renpenning, Julian; Geilmann, Heike; Qi, Haiping; Coplen, Tyler B.; Kümmel, Steffen; Ivdra, Natalija; Brand, Willi A.; Schimmelmann, Arndt

    2017-01-01

    Rationale: Accurate hydrogen isotopic analysis of halogen- and sulfur-bearing organics has not been possible with traditional high-temperature conversion (HTC) because the formation of hydrogen-bearing reaction products other than molecular hydrogen (H2) is responsible for non-quantitative H2 yields and possible hydrogen isotopic fractionation. Our previously introduced, new chromium-based EA-Cr/HTC-IRMS (Elemental Analyzer–Chromium/High-Temperature Conversion Isotope Ratio Mass Spectrometry) technique focused primarily on nitrogen-bearing compounds. Several technical and analytical issues concerning halogen- and sulfur-bearing samples, however, remained unresolved and required further refinement of the reactor systems.

  16. Challenges for single molecule electronic devices with nanographene and organic molecules. Do single molecules offer potential as elements of electronic devices in the next generation?

    Science.gov (United States)

    Enoki, Toshiaki; Kiguchi, Manabu

    2018-03-01

    Interest in utilizing organic molecules to fabricate electronic materials has existed ever since organic (molecular) semiconductors were first discovered in the 1950s. Since then, scientists have devoted serious effort to the creation of various molecule-based electronic systems, such as molecular metals and molecular superconductors. Single-molecule electronics and the associated basic science have emerged over the past two decades and provided hope for the development of highly integrated molecule-based electronic devices in the future (after the Si-based technology era has ended). Here, nanographenes (nano-sized graphene) with atomically precise structures are among the most promising molecules that can be utilized for electronic/spintronic devices. To manipulate single small molecules for an electronic device, a single molecular junction has been developed. It is a powerful tool that allows even small molecules to be utilized. External electric, magnetic, chemical, and mechanical perturbations can change the physical and chemical properties of molecules in a way that is different from bulk materials. Therefore, the various functionalities of molecules, along with changes induced by external perturbations, allows us to create electronic devices that we cannot create using current top-down Si-based technology. Future challenges that involve the incorporation of condensed matter physics, quantum chemistry calculations, organic synthetic chemistry, and electronic device engineering are expected to open a new era in single-molecule device electronic technology.

  17. PELTIER ELEMENTS

    CERN Document Server

    Tani, Laurits

    2015-01-01

    To control Peltier elements, temperature controller was used. I used TEC-1091 that was manufactured my Meerstetter Engineering. To gain control with the temperature controller, software had to be intalled on a controlling PC. There were different modes to control the Peltier: Tempererature controller to control temperature, Static current/voltage to control voltage and current and LIVE ON/OFF to auto-tune the controller respectively to the system. Also, since near the collision pipe there is much radiation, radiation-proof Peltier elements have to be used. To gain the best results, I had to find the most efficient Peltier elements and try to get their cold side to -40 degrees Celsius.

  18. Differential Concentrations of some Nutrient Element in Forage of Corn (Zea mays L. as Affected by Organic Fertilizers and Soil Compaction

    Directory of Open Access Journals (Sweden)

    N. Najafi

    2016-01-01

    Full Text Available Soil compaction is one of the most important limiting factor for normal crop growth, because it reduces absorption by the plant. Application of organic fertilizers in agricultural soils can reduce the detrimental effects of soil compaction on plant growth and also supply some nutrients to plant. Thus, a factorial experiment was carried out in a randomized complete block design with three replications and 14 treatments to evaluate the effects of organic fertilizers in mitigating soil compaction. The first factor in this study was the source and amount of organic fertilizer at seven levels (control, farmyard manure, sewage sludge compost and municipal solid waste compost and each of organic fertilizers at two levels of 15 and 30 g/kg of soil. The second factor was soil compaction at two levels (bulk density of 1.2 and 1.7 g/cm3. To perform this experiment, 10 kg of dry soil was poured into special PVC pots and then seeds of single cross 704 corn were planted. At the end of the growth period, the corn shoot was harvested and concentrations of phosphorus (P, potassium (K, sodium (Na, iron (Fe, zinc (Zn, manganese (Mn, cadmium (Cd and lead (Pb were determined by dry ashing method. The results showed that concentrations of Cd and Pb in the shoot, related to the different treatments, were negligible. Concentrations of P, K, Fe, Mn and Zn in the corn shoot were increased significantly by application of farmyard manure, sewage sludge compost and municipal solid waste compost at both levels of soil compaction. However, Na concentration of shoot did not change significantly. Soil compaction significantly reduced P, Fe, Mn and Zn concentrations of corn shoot, but it affected concentrations of Na and K significantly. Application of organic fertilizers and increasing their levels reduced the negative effects of soil compaction on nutrients uptake by corn plant. This study showed that to improve forage corn nutrition, application of 15 or 30 g of farmyard

  19. 1988. aasta suveräänsusdeklaratsioon: silmakirjalikkuse tsiviliseeriv mõju / The Estonian Declaration of Sovereignty: An example of the civilising force of hypocrisy

    Directory of Open Access Journals (Sweden)

    Hent-Raul Kalmo

    2011-01-01

    Full Text Available Sovereignty has been characterised as a form of “organised hypocrisy”, a system governed by a set of rules that are generally recognised as binding and yet continually infringed by the most powerful actors. This idea can be extended to analyse the role of sovereignty within the Soviet Union. The latter was also nominally governed by a constitution which endowed the Union Republics with the right of secession, but there was no realistic possibility of exercising this right. One should not rush to conclude, however, that the letter of the Soviet Constitution of 1977 was entirely without relevance. As Jon Elster has argued, hypocrisy can be a “civilising force” when the need to appear impartial and retain public credibility forces actors to choose a strategy they would not have chosen otherwise. A good example of this kind of argumentative constraint is offered by the dilemma faced by the Soviet leadership after the mid-1980s, as it became reluctant to use military force to suppress independence movements within the Baltic States while, at the same time, promising to give more weight to the Soviet Constitution and respect the “sovereignty” of the Union Republics. In this setting, the ambiguity of the word “sovereignty” could be used by a whole gamut of political movements in order to further their agenda, from local communists eager to expand their autonomy within the Soviet system to those making an explicit bid for the restoration of independence. Significant legal and political changes could be justified as mere conclusions from the constitutionally recognised status of the Union Republics — a strategy which was all the more effective as Moscow struggled to formulate an alternative line of constitutional interpretation that could be used to counter the Baltic claims. This exchange of opinions escalated into a constitutional conflict in November 1988 when the Estonian Supreme Soviet responded to proposed amendments to the Soviet

  20. Fuel element

    International Nuclear Information System (INIS)

    Kennedy, S.T.

    1982-01-01

    A nuclear reactor fuel element wherein a stack of nuclear fuel is prevented from displacement within its sheath by a retainer comprising a tube member which is radially expanded into frictional contact with the sheath by means of a captive ball within a tapered bore. (author)

  1. Transactinide elements

    International Nuclear Information System (INIS)

    Hemingway, J.D.

    1975-01-01

    The review is covered in sections, entitled: predicted nuclear properties - including closed shells, decay characteristics; predicted chemical properties - including electronic structure and calculated properties, X-radiation, extrapolated chemical properties, separation chemistry; methods of synthesis; the natural occurrence of superheavy elements. (U.K.)

  2. Client-centeredness of Finnish and Estonian nursing students and the support from nursing education to develop it. Students' self-evaluation.

    Science.gov (United States)

    Kalam-Salminen, Ly; Valkonen, Marjo-Riitta; Aro, Ilme; Routasalo, Pirkko

    2013-10-01

    The purpose of this comparative study is to describe the differences between Finnish and Estonian students evaluations about their client-centeredness and educational support they received to develop it. Client-centeredness has many positive effects on the quality and effectiveness of care. However, some deficiencies have been identified in the client-centeredness of nursing staff. Research on the subject has been limited, and we lack knowledge of graduating students' competence in client-centeredness and the support of their education to develop it. The sample consisted of 390 undergraduate nursing students, 195 from Finland and 195 from Estonia. The data were collected in 2009 using the structured five-point scale questionnaire. The questionnaire was designed to measure students' client-centeredness and the educational support they received from nursing education. The data were analyzed by the PASW Statistics 18-programme using descriptive statistics, Kolmogorov-Smirnov test and Mann-Whitney U-test. Predominantly, students in both countries evaluated their level of client-centeredness high. The Estonian students generally evaluated their client-centeredness higher compared to the Finnish students. The same applied to support provided by nursing education. The greatest differences were related to education and particularly theoretical teaching. In Estonia, students' client-centeredness manifested itself more in politeness and willingness to serve clients, whereas respecting the clients' values was emphasized in Finland. Students' requisites, referred here as knowledge, skills and abilities to implement client-centered nursing, for client-centeredness had deficiencies, and the support from education was also the weakest regarding these aspects. In future, education on development of nursing activities, acquisition of knowledge and services provided by health care as well as legislation should be enhanced, since these areas proved the most difficult for the students

  3. Assesment of trace elements and organic pollutants from a marine oil complex into the coral reef system of Cayo Arcas, Mexico.

    Science.gov (United States)

    Cram, Silke; Ponce De León, Claudia A; Fernández, Pilar; Sommer, Irene; Rivas, Hilda; Morales, Luis Miguel

    2006-10-01

    Possible contaminants produced by the Petroleos Mexicanos (PEMEX) marine oil complex in the vicinity of the Cayo Arcas (Mexico) coral reef ecosystem were evaluated by analyzing sediments and sea water for hydrocarbons and metal elements. We found that the concentrations of aliphatic hydrocarbons in the sea water were generally low, with the highest values detected near the oil station; the concentration of polycyclic aromatic hydrocarbons (PAHs) was generally below the detection limit. The hydrocarbons found in the sediments seem to have a pyrogenic origin, and were probably produced by marine traffic in the study area. The total PAH concentration did not exceed the NOAA criteria, although levels of some individual PAHs did. The only metal detected in the sea water at high concentrations was nickel. The Ni/V ratio in the sediments indicates the contribution of crude oil to the system. The high content of Ni and Zn was attributed to the ballast waters from the oil tankers that load at the station's monobuoys. The presence of fine sediments that commonly originate from terrestrial ecosystems supported this assumption.

  4. Biokinetics of a transuranic (238PU) and a rare earth element (152Eu) in the lobster (Homarus gammarus): transfer mechanisms (accumulation and detoxification) in organs and at the cellular level

    International Nuclear Information System (INIS)

    Tocquet, N.

    1995-01-01

    The work presented here is an experimental investigation of the biokinetics of transfer of a transuranic and a rare earth element ( 238 Pu and 152 Eu) in the lobster Homarus gammarus. The study of 238 Pu biokinetics forms part of a wider framework of research concerning the transfer of transuranic elements in marine species, while the study of 152 Eu is carried out with a view to supporting the analogy between the behaviour of transuranics and rare earths in living organisms. Exactly the same experimental protocol, based on techniques from various disciplines (biology, biochemistry and metrology), was used to Investigate the biokinetics of transfer of these two radionuclides. The Individual lobsters were radiolabelled by means of one-shot or chronic ingestion of spiked meals. As the first approach, the kinetics and transfer mechanisms were studied In whole animal samples and in different organs distinct series of pathways through the different organs were identified in the case of both radionuclides, being mainly linked to digestive processes induced by the meal as well as the transport function of hemo-lymph in this way, the Important role of the digestive gland was picked out, with two of four cellular types displaying a successive involvement In the fixation and then the retention of the studied radionuclides. As a corroborative approach, the digestive gland was subjected to a more detailed investigation with the aim of describing the mechanisms of Incorporation and elucidating transfer processes at the cellular and molecular levels. 238 Pu is preferentially partitioned into the cytosol, where it is associated with various constituents such as ferritin (iron-storing protein). 152 Eu is more diffusely distributed in the hepato-pancreatic cells, while the lysosomes appear to play a more important role during transfer. The results obtained in this study, both on the macroscopic scale (i.e. the whole animal and different organs) as well as the cellular and molecular

  5. Historical storage budgets of organic carbon, nutrient and contaminant elements in saltmarsh sediments: Biogeochemical context for managed realignment, Humber Estuary, UK

    International Nuclear Information System (INIS)

    Andrews, J.E.; Samways, G.; Shimmield, G.B.

    2008-01-01

    Biogeochemical data from Welwick marsh (Humber Estuary, UK), an actively accreting saltmarsh, provides a decadal-centennial-scale natural analogue for likely future biogeochemical storage effects of managed realignment sites accreting either intertidal muds or saltmarsh. Marsh topographic profiles and progradation history from aerial photographs were combined with 137 Cs and niobium contamination history to establish and verify chronology and sediment mass accumulation. These data, combined with down-core measurements of particulate organic carbon (C org ), organic nitrogen (N org ), particle reactive phosphorus and selected contaminant metal (Zn, Pb, Cu, As and Nb) contents were then used to calculate sediment and chemical storage terms and to quantify changes in these over time. These data are used to help predict likely future biogeochemical storage changes at managed realignment sites in the estuary. The net effect of returning some 26 km 2 of reclaimed land to intertidal environments now (about 25% of the maximum possible realignment storage identified for the estuary) could result in the storage of some 40,000 tonnes a -1 of sediment which would also bury about 800 tonnes a -1 of C org and 40 tonnes a -1 of N org . Particulate contaminant P burial would be around 25 tonnes a -1 along with ∼ 6 tonnes a -1 contaminant Zn, 3 tonnes a -1 contaminant Pb, and ∼ 1 tonnes a -1 contaminant As and Cu. The study also shows that reclamation activities in the outer estuary since the mid-1700s has prevented, in total, the deposition of about 10 million tonnes of sediment, along with 320,000 tonnes of C org and 16,000 tonnes of N org . The study provides a mid-1990s baseline against which future measurements at the site can determine changes in burial fluxes and improvement or deterioration in contaminant metal contents of the sediments. The data are directly relevant for local managed realignment sites but also broadly indicative for sites generally on the European

  6. New elements

    International Nuclear Information System (INIS)

    Flerov, G.

    1976-01-01

    The history is briefly described of the investigation of superheavy elements at the Joint Institute for Nuclear Research at Dubna. The significance of the investigation is assessed from the point of view of the nuclear structure study and major problems encountered in experimental efforts are indicated. Current experimental methods aiming at the discovery or the production of superheavy nuclei with Z approximately 114 are listed. (I.W.)

  7. Biokinetics of a transuranic ({sup 238}PU) and a rare earth element ({sup 152}Eu) in the lobster (Homarus gammarus): transfer mechanisms (accumulation and detoxification) in organs and at the cellular level; Biocinetiques d'un element transuranien, le {sup 238}PU, et d'une terre rare, le {sup 152}EU, chez le homard homarus gammarus (organes et niveau cellulaire) modalites des transferts (accumulation et detoxication)

    Energy Technology Data Exchange (ETDEWEB)

    Tocquet, N

    1995-07-01

    The work presented here is an experimental investigation of the biokinetics of transfer of a transuranic and a rare earth element ({sup 238}Pu and {sup 152}Eu) in the lobster Homarus gammarus. The study of {sup 238}Pu biokinetics forms part of a wider framework of research concerning the transfer of transuranic elements in marine species, while the study of {sup 152}Eu is carried out with a view to supporting the analogy between the behaviour of transuranics and rare earths in living organisms. Exactly the same experimental protocol, based on techniques from various disciplines (biology, biochemistry and metrology), was used to Investigate the biokinetics of transfer of these two radionuclides. The Individual lobsters were radiolabelled by means of one-shot or chronic ingestion of spiked meals. As the first approach, the kinetics and transfer mechanisms were studied In whole animal samples and in different organs distinct series of pathways through the different organs were identified in the case of both radionuclides, being mainly linked to digestive processes induced by the meal as well as the transport function of hemo-lymph in this way, the Important role of the digestive gland was picked out, with two of four cellular types displaying a successive involvement In the fixation and then the retention of the studied radionuclides. As a corroborative approach, the digestive gland was subjected to a more detailed investigation with the aim of describing the mechanisms of Incorporation and elucidating transfer processes at the cellular and molecular levels. {sup 238}Pu is preferentially partitioned into the cytosol, where it is associated with various constituents such as ferritin (iron-storing protein). {sup 152}Eu is more diffusely distributed in the hepato-pancreatic cells, while the lysosomes appear to play a more important role during transfer. The results obtained in this study, both on the macroscopic scale (i.e. the whole animal and different organs) as well

  8. Biokinetics of a transuranic ({sup 238}PU) and a rare earth element ({sup 152}Eu) in the lobster (Homarus gammarus): transfer mechanisms (accumulation and detoxification) in organs and at the cellular level; Biocinetiques d'un element transuranien, le {sup 238}PU, et d'une terre rare, le {sup 152}EU, chez le homard homarus gammarus (organes et niveau cellulaire) modalites des transferts (accumulation et detoxication)

    Energy Technology Data Exchange (ETDEWEB)

    Tocquet, N

    1995-07-01

    The work presented here is an experimental investigation of the biokinetics of transfer of a transuranic and a rare earth element ({sup 238}Pu and {sup 152}Eu) in the lobster Homarus gammarus. The study of {sup 238}Pu biokinetics forms part of a wider framework of research concerning the transfer of transuranic elements in marine species, while the study of {sup 152}Eu is carried out with a view to supporting the analogy between the behaviour of transuranics and rare earths in living organisms. Exactly the same experimental protocol, based on techniques from various disciplines (biology, biochemistry and metrology), was used to Investigate the biokinetics of transfer of these two radionuclides. The Individual lobsters were radiolabelled by means of one-shot or chronic ingestion of spiked meals. As the first approach, the kinetics and transfer mechanisms were studied In whole animal samples and in different organs distinct series of pathways through the different organs were identified in the case of both radionuclides, being mainly linked to digestive processes induced by the meal as well as the transport function of hemo-lymph in this way, the Important role of the digestive gland was picked out, with two of four cellular types displaying a successive involvement In the fixation and then the retention of the studied radionuclides. As a corroborative approach, the digestive gland was subjected to a more detailed investigation with the aim of describing the mechanisms of Incorporation and elucidating transfer processes at the cellular and molecular levels. {sup 238}Pu is preferentially partitioned into the cytosol, where it is associated with various constituents such as ferritin (iron-storing protein). {sup 152}Eu is more diffusely distributed in the hepato-pancreatic cells, while the lysosomes appear to play a more important role during transfer. The results obtained in this study, both on the macroscopic scale (i.e. the whole animal and different organs) as well

  9. Photoshop Elements 10 For Dummies

    CERN Document Server

    Obermeier, Barbara

    2011-01-01

    Perfect your photos and images with this "focused" guide to the latest version of Photoshop Elements For most of us, the professional-level Photoshop is overkill for our needs. Amateur photographers and photo enthusiasts turn to Photoshop Elements for a powerful but simpler way to edit and retouch their snapshots. Photoshop Elements 10 For Dummies, fully updated and revised for the latest release of this software product, helps you navigate Elements to create, edit, fix, share, and organize the high-quality images you desire. Full color pages bring the techniques to life and make taking great

  10. Elements for the Design of a Decision-making Information System for activities related to genetically modified organisms: Contributions from a case study

    International Nuclear Information System (INIS)

    Benavides Molineros, Julia; Aguirre Ramirez, Nestor

    2012-01-01

    In Colombia, decisions related to genetically modified organisms (GMOs) must be supported by assessment of the risk to biodiversity, human health and agricultural production. Based on this assessment, authorities can make decisions involving authorization or denial of the requested activities. The rationality of the decision-making process is very well established with respect to human health, particularly toxicity and allergenicity, but that is not the case for biodiversity issues. One of the biggest problems in this area is the lack of definition of a decision-making methodology, which leads to decisions made in an intuitive and non-systematic manner. Authorities in the field have recognized the need for a decision-making information system to help solve this situation. A proposal for the basic structure of a decision-making information system oriented to authorities involved in the process is presented. The proposal was developed based on a review of the main existing methodologies for GMO risk assessment and on a case study of the gene flow from GMOs to wild relatives. The structure is presented as a broad entity-relationship model from which the detailed design of the system can be developed. The proposal emphasizes the documentation of the decision protocols and the rationality of use of the information inputs.

  11. Radiographic element

    International Nuclear Information System (INIS)

    Abbott, T.I.; Jones, C.G.

    1984-01-01

    Radiographic elements are disclosed comprised of first and second silver halide emulsion layers separated by an interposed support capable of transmitting radiation to which the second image portion is responsive. At least the first imaging portion contains a silver halide emulsion in which thin tubular silver halide grains of intermediate aspect ratios (from 5:1 to 8:1) are present. Spectral sensitizing dye is adsorbed to the surface of the tubular grains. Increased photographic speeds can be realized at comparable levels of crossover. (author)

  12. Selected trace-element and synthetic-organic compound data for streambed sediment from the Clark Fork-Pend Oreille and Spokane River basins, Montana, Idaho, and Washington, 1998

    Science.gov (United States)

    Beckwith, Michael A.

    2002-01-01

    Streambed-sediment samples were collected at 22 sites during the summer of 1998 as part of the U.S. Geological Survey National Water-Quality Assessment Program. Sampling sites in the Clark Fork-Pend Oreille and Spokane River basins represented a wide range of environmental conditions including pristine mountain streams and large rivers affected by mining-related and urban activities. Samples were analyzed for 45 inorganic major and trace elements, 109 syn­thetic organic compounds, and carbon. This report pre­sents the selected results of streambed-sediment sampling from the Clark Fork-Pend Oreille and Spo­kane River basins in Montana, Idaho, and Washington.

  13. Superheavy elements

    CERN Document Server

    Hofmann, S

    1999-01-01

    The outstanding aim of experimental investigations of heavy nuclei is the exploration of spherical 'SuperHeavy Elements' (SHEs). On the basis of the nuclear shell model, the next double magic shell-closure beyond sup 2 sup 0 sup 8 Pb is predicted at proton numbers between Z=114 and 126 and at neutron number N=184. All experimental efforts aiming at identifying SHEs (Z>=114) were negative so far. A highly sensitive search experiment was performed in November-December 1995 at SHIP. The isotope sup 2 sup 9 sup 0 116 produced by 'radiative capture' was searched for in the course of a 33 days irradiation of a sup 2 sup 0 sup 8 Pb target with sup 8 sup 2 Se projectiles, however, only cross-section limits were measured. Positive results were obtained in experiments searching for elements from 110 to 112 using cold fusion and the 1n evaporation channel. The produced isotopes were unambiguously identified by means of alpha-alpha correlations. Not fission, but alpha emission is the dominant decay mode. The measurement ...

  14. Co-ordinated research project: Ingestion and organ content of trace elements of importance in radiological protection (CRP: E4.30.08). Reference Asian man project, phase 2

    International Nuclear Information System (INIS)

    2000-01-01

    The Second Research Coordination Meeting for the Co-ordinated Research Project (CRP) on 'Ingestion and Organ Content of Trace Elements of Importance in Radiological Protection: Reference Asian Man Project, Phase 2' was held at the China Institute for Radiation Protection (CIRP) in Taiyuan, People's Republic of China. During the first technical Session, an overview of the current status of the CRP was presented by the IAEA technical officer, Dr. Parr, and the responsible officer of the Central Reference Laboratory (NIRS, Japan), Dr. Kawamura. They drew attention to the agreed programme of work, as described in the project documentation, and the timetable foreseen for the CRP as summarized in table 1. In general, they concluded that the achievements of the CRP to-date appear to be good, particularly in relation to sample collection (in most countries) and quality control (the development of appropriate reference materials). However, some aspects of the work appear to be a little behind schedule, particularly (1) the final stages of preparation of total diet samples (because of delays in providing a suitable food blender), (2) the analysis of some of the elements of first priority (because of the non-availability, until now, of suitable analytical reference materials), and (3) in some countries, the collection of autopsy specimens. One country (Malaysia) has experienced considerable difficulties in implementing the project due to the retirement of the former Chief Scientific Investigator. For this reason it was unfortunately not possible for the Malaysian representative to be present at the RCM

  15. Estonian total ozone climatology

    Directory of Open Access Journals (Sweden)

    K. Eerme

    Full Text Available The climatological characteristics of total ozone over Estonia based on the Total Ozone Mapping Spectrometer (TOMS data are discussed. The mean annual cycle during 1979–2000 for the site at 58.3° N and 26.5° E is compiled. The available ground-level data interpolated before TOMS, have been used for trend detection. During the last two decades, the quasi-biennial oscillation (QBO corrected systematic decrease of total ozone from February–April was 3 ± 2.6% per decade. Before 1980, a spring decrease was not detectable. No decreasing trend was found in either the late autumn ozone minimum or in the summer total ozone. The QBO related signal in the spring total ozone has an amplitude of ± 20 DU and phase lag of 20 months. Between 1987–1992, the lagged covariance between the Singapore wind and the studied total ozone was weak. The spring (April–May and summer (June–August total ozone have the best correlation (coefficient 0.7 in the yearly cycle. The correlation between the May and August total ozone is higher than the one between the other summer months. Seasonal power spectra of the total ozone variance show preferred periods with an over 95% significance level. Since 1986, during the winter/spring, the contribution period of 32 days prevails instead of the earlier dominating 26 days. The spectral densities of the periods from 4 days to 2 weeks exhibit high interannual variability.

    Key words. Atmospheric composition and structure (middle atmosphere – composition and chemistry; volcanic effects – Meteorology and atmospheric dynamics (climatology

  16. Fuel element

    International Nuclear Information System (INIS)

    Hirose, Yasuo.

    1982-01-01

    Purpose: To increase the plenum space in a fuel element used for a liquid metal cooled reactor. Constitution: A fuel pellet is secured at one end with an end plug and at the other with a coil spring in a tubular container. A mechanism for fixing the coil spring composed of a tubular unit is mounted by friction with the inner surface of the tubular container. Accordingly, the recoiling force of the coil spring can be retained by fixing mechanism with a small volume, and since a large amount of plenum space can be obtained, the internal pressure rise in the cladding tube can be suppressed even if large quantities of fission products are discharged. (Kamimura, M.)

  17. Effect of organic matrices on the determination of the trace element chemistry (Mg, Sr, Mg/Ca, Sr/Ca) of aragonitic bivalve shells (Arctica islandica). Comparison of ICP-OES and LA-ICP-MS data

    International Nuclear Information System (INIS)

    Schoene, Bernd R.; Zhang, Zengjie; Jacob, Dorrit; Soldate, Analia; Gillikin, David P.; Tuetken, Thomas; Garbe-Shoenberg, Dieter; McConnaughey, Ted

    2010-01-01

    The element chemistry of biogenic carbonates can provide important data on past environments. However, the Sr/Ca and Mg/Ca ratios as well as the Mg and Sr concentrations of biological carbonates, especially aragonitic bivalves often depart from apparent thermodynamic equilibrium. When measured in situ by means of LA-ICP-MS, the Mg concentration is often substantially enriched (two- to threefold) near the organic-rich, annual growth lines. To test the hypothesis that some organic components exert a major influence on the skeletal metal content, the element chemistry of different shell components (insoluble organic matrix, IOM; dissolved CaCO 3 and soluble organics, SOM) of Arctica islandica was measured by means of ICP-OES and LA-ICP-MS. The ICP-OES data indicate that the IOM is strongly enriched in Mg (130 ppm) and depleted in Sr and Ca (10 ppm and 0.22 wt%, respectively) when compared to the whole biomineral (Mg: 68 to 99 ppm, Sr: 860 to 1,060 ppm, Ca: ∼35.72 wt%). Although the average relative abundance of the IOM barely exceeds 0.46 wt%, its chemical composition in combination with its heterogeneous distribution across the shell can significantly increase estimates of the Mg concentration if measured in situ by LA-ICP-MS. Depending on the distribution of the IOM, the Ca concentration may be significantly lower locally than the average Ca concentration of the whole shell (35.72 wt%). If this remains undetected, the Mg concentration of shell portions with higher than average IOM content is overestimated by LA-ICP-MS and, conversely, the Mg concentration is underestimated in shell portions with lower than average IOM content. Removal of the IOM prior to the chemical analysis by LA-ICP-MS or mathematical correction for the IOM-derived magnesium concentrations is therefore strongly advised. The different chemistry of the IOM may also exert a major control on the trace element to calcium ratios. Shell portions enriched in IOM will show up to 200 times higher Mg

  18. Optimization of on-line hydrogen stable isotope ratio measurements of halogen- and sulfur-bearing organic compounds using elemental analyzer-chromium/high-temperature conversion isotope ratio mass spectrometry (EA-Cr/HTC-IRMS).

    Science.gov (United States)

    Gehre, Matthias; Renpenning, Julian; Geilmann, Heike; Qi, Haiping; Coplen, Tyler B; Kümmel, Steffen; Ivdra, Natalija; Brand, Willi A; Schimmelmann, Arndt

    2017-03-30

    Accurate hydrogen isotopic analysis of halogen- and sulfur-bearing organics has not been possible with traditional high-temperature conversion (HTC) because the formation of hydrogen-bearing reaction products other than molecular hydrogen (H 2 ) is responsible for non-quantitative H 2 yields and possible hydrogen isotopic fractionation. Our previously introduced, new chromium-based EA-Cr/HTC-IRMS (Elemental Analyzer-Chromium/High-Temperature Conversion Isotope Ratio Mass Spectrometry) technique focused primarily on nitrogen-bearing compounds. Several technical and analytical issues concerning halogen- and sulfur-bearing samples, however, remained unresolved and required further refinement of the reactor systems. The EA-Cr/HTC reactor was substantially modified for the conversion of halogen- and sulfur-bearing samples. The performance of the novel conversion setup for solid and liquid samples was monitored and optimized using a simultaneously operating dual-detection system of IRMS and ion trap MS. The method with several variants in the reactor, including the addition of manganese metal chips, was evaluated in three laboratories using EA-Cr/HTC-IRMS (on-line method) and compared with traditional uranium-reduction-based conversion combined with manual dual-inlet IRMS analysis (off-line method) in one laboratory. The modified EA-Cr/HTC reactor setup showed an overall H 2 -recovery of more than 96% for all halogen- and sulfur-bearing organic compounds. All results were successfully normalized via two-point calibration with VSMOW-SLAP reference waters. Precise and accurate hydrogen isotopic analys