WorldWideScience

Sample records for electrostatic vibration energy

  1. Electrostatic MEMS vibration energy harvester for HVAC applications

    Science.gov (United States)

    Oxaal, J.; Hella, M.; Borca-Tasciuc, D.-A.

    2015-12-01

    This paper reports on an electrostatic MEMS vibration energy harvester with gapclosing interdigitated electrodes, designed for and tested on HVAC air ducts. The device is fabricated on SOI wafers using a custom microfabrication process. A dual-level physical stopper system is implemented in order to control the minimum gap between the electrodes and maximize the power output. It utilizes cantilever beams to absorb a portion of the impact energy as the electrodes approach the impact point, and a film of parylene with nanometer thickness deposited on the electrode sidewalls, which defines the absolute minimum gap and provides electrical insulation. The fabricated device was first tested on a vibration shaker to characterize its resonant behavior. The device exhibits spring hardening behavior due to impacts with the stoppers and spring softening behavior with increasing voltage bias. Testing was carried out on HVAC air duct vibrating with an RMS acceleration of 155 mgRMS and a primary frequency of 60 Hz with a PSD of 7.15·10-2 g2/Hz. The peak power measured is 12nW (0.6 nW RMS) with a PSD of 6.9·10-11 W/Hz at 240 Hz (four times of the primary frequency of 60 Hz), which is the highest output reported for similar vibration conditions and biasing voltages.

  2. Electrostatic energy harvesting device with dual resonant structure for wideband random vibration sources at low frequency.

    Science.gov (United States)

    Zhang, Yulong; Wang, Tianyang; Zhang, Ai; Peng, Zhuoteng; Luo, Dan; Chen, Rui; Wang, Fei

    2016-12-01

    In this paper, we present design and test of a broadband electrostatic energy harvester with a dual resonant structure, which consists of two cantilever-mass subsystems each with a mass attached at the free edge of a cantilever. Comparing to traditional devices with single resonant frequency, the proposed device with dual resonant structure can resonate at two frequencies. Furthermore, when one of the cantilever-masses is oscillating at resonance, the vibration amplitude is large enough to make it collide with the other mass, which provides strong mechanical coupling between the two subsystems. Therefore, this device can harvest a decent power output from vibration sources at a broad frequency range. During the measurement, continuous power output up to 6.2-9.8 μW can be achieved under external vibration amplitude of 9.3 m/s2 at a frequency range from 36.3 Hz to 48.3 Hz, which means the bandwidth of the device is about 30% of the central frequency. The broad bandwidth of the device provides a promising application for energy harvesting from the scenarios with random vibration sources. The experimental results indicate that with the dual resonant structure, the vibration-to-electricity energy conversion efficiency can be improved by 97% when an external random vibration with a low frequency filter is applied.

  3. Electrostatic vibration energy harvester with 2.4-GHz Cockcroft-Walton rectenna start-up

    Science.gov (United States)

    Takhedmit, Hakim; Saddi, Zied; Karami, Armine; Basset, Philippe; Cirio, Laurent

    2017-02-01

    In this paper, we propose the design, fabrication and experiments of a macro-scale electrostatic vibration energy harvester (e-VEH), pre-charged wirelessly for the first time with a 2.4-GHz Cockcroft-Walton rectenna. The rectenna is designed and optimized to operate at low power densities and provide high voltage levels: 0.5 V at 0.76 μW/cm2 and 1 V at 1.53 μW/cm2. The e-VEH uses a Bennet doubler as a conditioning circuit. Experiments show a 23-V voltage across the transducer terminal, when the harvester is excited at 25 Hz by 1.5 g of external acceleration. An accumulated energy of 275 μJ and a maximum available power of 0.4 μW are achieved. xml:lang="fr"

  4. Electrostatic Vibration Energy Harvester Pre-charged Wirelessly at 2.45 GHz

    Science.gov (United States)

    Saddi, Z.; Takhedmit, H.; Karami, A.; Basset, P.; Cirio, L.

    2016-11-01

    This paper reports the design, fabrication and experiments of an electrostatic vibration harvester (e-VEH), pre-charged wirelessly for the first time by using an electromagnetic waves harvester at 2.4 GHz. The rectenna uses the Cockcroft-Walton voltage doubler rectifier. It is designed and optimized to operate at low power densities and provides high voltage levels: 0.5 V at 0.5 μW/cm2 and 0.8 V at 1 μW/cm2 The e-VEH uses the Bennet doubler as conditioning circuit. Experiments show 23 V voltage across the transducer terminal when the harvester is excited at 25 Hz by 1.5 g of external acceleration. An accumulated energy of 275 μJ and a maximum power of 0.4 μW are available for the load.

  5. Electrostatic MEMS vibration energy harvester for HVAC applications with impact-based frequency up-conversion

    Science.gov (United States)

    Oxaal, J.; Hella, M.; Borca-Tasciuc, D.-A.

    2016-12-01

    This paper reports on electrostatic MEMS vibration energy harvesters with gap-closing interdigitated electrodes, designed for and tested on HVAC air ducts. The harvesters were fabricated on SOI wafers with 200 µm device layer using a custom microfabrication process. Designs with aspects ratio (electrodes’ gap versus depth) of 10 and 20 were implemented, while the overall footprint was approximately 1 cm  ×  1 cm in both cases. In order to enhance the power output, a dual-level physical stopper system was designed to control the minimum gap between the electrodes, which is a key parameter in the conversion process. The dual-level stopper utilizes cantilever beams to absorb a portion of the impact energy as the electrodes approach the impact point, and a film of parylene with nanometer thickness deposited on the electrode sidewalls. The parylene layer defines the absolute minimum gap and provides electrical insulation. The fabricated devices were first tested on a vibration shaker to characterize the resonant behavior. Devices with aspect ratio 10 were found to exhibit frequency up-conversion, which enhances the amount of converted power. Devices with both aspect ratios were found to exhibits spring hardening due to impact with the stoppers and spring softening behavior at increasing voltage bias. The highest power measured on shaker table for sinusoidal vibrations was 3.13 µW (includes enhancement due to frequency up-conversion driven by impact) for aspect ratio 10, and 0.166 µW for aspect ratio 20. The corresponding dimensional figure-of-merit, defined as the power output normalized to vibration acceleration and frequency, squared voltage and device mass, was in the range of 10 · 10-8 m V-2 for both devices, about an order of magnitude higher than state-of-the-art. Testing was carried out on HVAC air duct vibrating with an RMS acceleration of 155 mg RMS, a primary frequency of 60 Hz and a PSD of 7.15 · 10-2 g2 Hz-1. The peak power measured was

  6. Low cost electrostatic vibration energy harvesters based on negatively-charged polypropylene cellular films with a folded structure

    Science.gov (United States)

    Ma, Xingchen; Zhang, Xiaoqing

    2017-08-01

    Low cost electrostatic vibration energy harvesters based on negatively-charged polypropylene cellular films with a folded structure were designed in this study. Strips of such energy harvesters were excited by applying mechanical stress in length direction. A current in a terminating resistor was generated due to the capacitance variation of the samples. For a typical double-periodic folded-structure electrostatic vibration energy harvester sample whose effective length and width were 30 mm and 10 mm, respectively, the generated power across a matching resistor at a resonance frequency of 36 Hz amounts to 641 μW for a seismic mass of 4 g and an acceleration of 1 g (g is the gravity of the Earth). Similar structures which were designed and fabricated in this study were also tested for energy harvesting and high output power in the order of a few hundred microwatt was gained. Following the presentation of a theoretical model allowing for the calculation of the power generated in a load resistance at the resonance frequency of the harvesters, experimental results are shown and compared to theoretical prediction. It turns out that the experiment results accord well with the theoretical predictions.

  7. Electrostatics determine vibrational frequency shifts in hydrogen bonded complexes.

    Science.gov (United States)

    Dey, Arghya; Mondal, Sohidul Islam; Sen, Saumik; Ghosh, Debashree; Patwari, G Naresh

    2014-12-14

    The red-shifts in the acetylenic C-H stretching vibration of C-H∙∙∙X (X = O, N) hydrogen-bonded complexes increase with an increase in the basicity of the Lewis base. Analysis of various components of stabilization energy suggests that the observed red-shifts are correlated with the electrostatic component of the stabilization energy, while the dispersion modulates the stabilization energy.

  8. Understanding and Manipulating Electrostatic Fields at the Protein-Protein Interface Using Vibrational Spectroscopy and Continuum Electrostatics Calculations.

    Science.gov (United States)

    Ritchie, Andrew W; Webb, Lauren J

    2015-11-05

    Biological function emerges in large part from the interactions of biomacromolecules in the complex and dynamic environment of the living cell. For this reason, macromolecular interactions in biological systems are now a major focus of interest throughout the biochemical and biophysical communities. The affinity and specificity of macromolecular interactions are the result of both structural and electrostatic factors. Significant advances have been made in characterizing structural features of stable protein-protein interfaces through the techniques of modern structural biology, but much less is understood about how electrostatic factors promote and stabilize specific functional macromolecular interactions over all possible choices presented to a given molecule in a crowded environment. In this Feature Article, we describe how vibrational Stark effect (VSE) spectroscopy is being applied to measure electrostatic fields at protein-protein interfaces, focusing on measurements of guanosine triphosphate (GTP)-binding proteins of the Ras superfamily binding with structurally related but functionally distinct downstream effector proteins. In VSE spectroscopy, spectral shifts of a probe oscillator's energy are related directly to that probe's local electrostatic environment. By performing this experiment repeatedly throughout a protein-protein interface, an experimental map of measured electrostatic fields generated at that interface is determined. These data can be used to rationalize selective binding of similarly structured proteins in both in vitro and in vivo environments. Furthermore, these data can be used to compare to computational predictions of electrostatic fields to explore the level of simulation detail that is necessary to accurately predict our experimental findings.

  9. Fabrication of SU-8 low frequency electrostatic energy harvester

    KAUST Repository

    Ramadan, Khaled S.

    2011-11-01

    A 1500μm × 1500μm × 150μm out-of-plane, gap closing, electrostatic energy harvester is designed and fabricated to harvest low-frequency ambient vibrations. SU-8 is used to fabricate the proof mass (1200μm × 1200μm × 150μm) and the 5 m springs. Different harvesters were designed to harvest at 50, 75 and 110 Hz. At 110 Hz, Simulations show that with an input vibration of 10 μm amplitude at the frequency of resonance of the structure, the energy harvester should generate an average output power density of 0.032μW/mm3. This is the most area-efficient low-frequency electrostatic harvester to-date. © 2011 IEEE.

  10. Research of vibration controlling based on programmable logic controller for electrostatic precipitator

    Science.gov (United States)

    Zhang, Zisheng; Li, Yanhu; Li, Jiaojiao; Liu, Zhiqiang; Li, Qing

    2013-03-01

    In order to improve the reliability, stability and automation of electrostatic precipitator, circuits of vibration motor for ESP and vibration control ladder diagram program are investigated using Schneider PLC with high performance and programming software of Twidosoft. Operational results show that after adopting PLC, vibration motor can run automatically; compared with traditional control system of vibration based on single-chip microcomputer, it has higher reliability, better stability and higher dust removal rate, when dust emission concentrations <= 50 mg m-3, providing a new method for vibration controlling of ESP.

  11. An electrostatic CMOS/BiCMOS Lithium ion vibration-based harvester-charger IC

    Science.gov (United States)

    Torres, Erick Omar

    Self-powered microsystems, such as wireless transceiver microsensors, appeal to an expanding application space in monitoring, control, and diagnosis for commercial, industrial, military, space, and biomedical products. As these devices continue to shrink, their microscale dimensions allow them to be unobtrusive and economical, with the potential to operate from typically unreachable environments and, in wireless network applications, deploy numerous distributed sensing nodes simultaneously. Extended operational life, however, is difficult to achieve since their limited volume space constrains the stored energy available, even with state-of-the-art technologies, such as thin-film lithium-ion batteries (Li Ion) and micro-fuel cells. Harvesting ambient energy overcomes this deficit by continually replenishing the energy reservoir and, as a result, indefinitely extending system lifetime. In this work, an electrostatic harvester that harnesses ambient kinetic energy from vibrations to charge an energy-storage device (e.g., a battery) is investigated, developed, and evaluated. The proposed harvester charges and holds the voltage across a vibration-sensitive variable capacitor so that vibrations can induce it to generate current into the battery when capacitance decreases (as its plates separate). The challenge is that energy is harnessed at relatively slow rates, producing low output power, and the electronics required to transfer it to charge a battery can easily demand more than the power produced. To this end, the system reduces losses by time-managing and biasing its circuits to operate only when needed and with just enough energy while charging the capacitor through an efficient quasi-lossless inductor-based precharger. As result, the proposed energy harvester stores a net energy gain in the battery during every vibration cycle. Two energy-harvesting integrated circuits (IC) were analyzed, designed, developed, and validated using a 0.7-im BiCMOS process and a 30-Hz

  12. Electrostatic Energy Exchange in Shock Acceleration

    Science.gov (United States)

    Barchas, Joseph A.

    Plasma shocks are very common occurrences, and diffusive shock acceleration is a simple and efficient mechanism for generating cosmic rays. A shock's main effect is turbulent dissipation, which rapidly thermalizes the downstream plasma. Diffusive shock acceleration produces a non-thermal component to the particle distributions (quasi-power-law tails) which translates to non-thermal photon spectra, as seen in supernova remnants, jets in active galactic nuclei, and gamma-ray bursts. In supernova remnants, X-ray observations show that inferred proton temperatures are considerably cooler than standard shock heating predicts. A cross-shock electrostatic potential, akin to a double layer, is reasoned to exist in certain conditions due to the different inertial gyration scales of the plasma species. It provides a mechanism for energy exchange between species, and should result in a respective heating/cooling of the electrons/ions. It modifies the electron/ion distributions, which couple through radiative processes to the observed X-ray emission. In this thesis, the effects of cross-shock electrostatics are explored using a Monte Carlo simulation, where test particles gyrate and stochastically diffuse in a background fluid pre-defined by MHD jump conditions.A cross-shock electric field is derived from the steady-state spatial distribution of particles via a modified Poisson's equation that includes Debye screening, and the simulation is rerun with this field superimposed on the background magnetic and drift electric fields. This feedback loop continues until a self-consistent solution is obtained. Results show a significant departure of the particle distributions from the usual thermal+power-law form, and clearly demonstrates substantial energy exchange between the electron and ion populations.

  13. Wideband Piezomagnetoelastic Vibration Energy Harvesting

    DEFF Research Database (Denmark)

    Lei, Anders; Thomsen, Erik Vilain

    2014-01-01

    This work presents a small-scale wideband piezomagnetoelastic vibration energy harvester (VEH) aimed for operation at frequencies of a few hundred Hz. The VEH consists of a tape-casted PZT cantilever with thin sheets of iron foil attached on each side of the free tip. The wideband operation...

  14. Low-energy isovector quadrupole vibrations

    Energy Technology Data Exchange (ETDEWEB)

    Faessler, A.; Nojarov, R.

    1986-01-23

    The low-lying isovector quadrupole vibrations are described by an extension of the vibrational model allowing independent proton and neutron vibrations coupled by the symmetry energy. The recently detected low-lying isovector states in nearly spherical nuclei with N=84 are described well concerning their energies and E2/M1 mixing ratios. (orig.).

  15. Theoretical Comparison of the Energy Conversion Efficiencies of Electrostatic Energy Harvesters

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Chang-Kyu [Korea Polytechnic University, Siheung (Korea, Republic of)

    2017-02-15

    The characteristics of a new type of electrostatic energy harvesting device, called an out-of plane overlap harvester, are analyzed for the first time. This device utilizes a movable part that vibrates up and down on the surface of a wafer and a changing overlapping area between the vertical comb fingers. This operational principle enables the minimum capacitance to be close to 0 and significantly increases the energy conversion efficiency per unit volume. The characteristics of the out-of-plane overlap harvester, an in-plane gap-closing harvester, and an in-plane overlap harvester are compared in terms of the length, height, and width of the comb finger and the parasitic capacitance. The efficiency is improved as the length or the height increases and as the width or the parasitic capacitance decreases. In every case, the out-of-plane overlap harvester is able to create more energy and is, thus, preferable over other designs. It is also free from collisions between two electrodes caused by random vibration amplitudes and creates more energy from off axis perturbations. This device, given its small feature size, is expected to provide more energy to various types of wireless electronics devices and to offer high compatibility with other integrated circuits and ease of embedment.

  16. Review of magnetostrictive vibration energy harvesters

    Science.gov (United States)

    Deng, Zhangxian; Dapino, Marcelo J.

    2017-10-01

    The field of energy harvesting has grown concurrently with the rapid development of portable and wireless electronics in which reliable and long-lasting power sources are required. Electrochemical batteries have a limited lifespan and require periodic recharging. In contrast, vibration energy harvesters can supply uninterrupted power by scavenging useful electrical energy from ambient structural vibrations. This article reviews the current state of vibration energy harvesters based on magnetostrictive materials, especially Terfenol-D and Galfenol. Existing magnetostrictive harvester designs are compared in terms of various performance metrics. Advanced techniques that can reduce device size and improve performance are presented. Models for magnetostrictive devices are summarized to guide future harvester designs.

  17. Surface morphology effects in a vibration based triboelectric energy harvester

    Science.gov (United States)

    Nafari, A.; Sodano, H. A.

    2018-01-01

    Despite the abundance of ambient mechanical energy in our environment, it is often neglected and left unused. However, recent studies have demonstrated that mechanical vibrations can be harvested and used to power small wireless electronic devices, such as micro electromechanical sensors (MEMS) and actuators. Most commonly, these energy harvesters convert vibration into electrical energy by utilizing piezoelectric, electromagnetic or electrostatic effects. Recently, triboelectric based energy harvesters have shown to be among the simplest and most cost-effective techniques for scavenging mechanical energy. The basis of triboelectric energy harvesters is the periodic contact and separation of two surfaces with opposite triboelectric properties which results in induced charge flow through an external load. Here, a vibration driven triboelectric nanogenerator (TENG) is fabricated and the effect of micro/nano scale surface modification is studied. The TENG produces electrical energy on the basis of periodic out-of-plane charge separation between gold and polydimethylsiloxane (PDMS) with opposite triboelectric charge polarities. By introducing micro/nano scale surface modifications to the PDMS and gold, the TENG’s power output is further enhanced. This work demonstrates that the morphology of the surfaces in a TENG device is important and by increasing the effective surface area through micro/nano scale modification, the power output of the device can increase by 118%. Moreover, it is shown that unlike many TENGs proposed in the literature, the fabricated device has a high RMS open circuit voltage and short circuit current and can perform for an extended period of time.

  18. ELISA - an electrostatic storage ring for low-energy ions

    Science.gov (United States)

    Pape Moeller, Soeren

    1997-05-01

    The design of a new type of storage ring for low-energy ions using electrostatic deflection and focusing devices is described. Electrostatic bends and quadrupoles are used since they are more efficient than magnetic ones for low-velocity heavy ions. Furthermore, electrostatic devices are more compact and easier to construct than magnetic devices. In comparison to an electromagnetic trap, one important advantage of the elecrostatic ring is the easy access to the circulating beam and its decay products. These and other features, e.g. no magnetic fields, makes such storage devices attractive for many atomic-physics experiments. Also neigboring fields as chemistry and biology might benefit from such an relatively inexpensive device. One important difference between an electrostatic and a magnetic ring is, that the longitudinal energy is not conserved for the electrostatic ring. The actual ring will have a race-track shape as defined by two straight sections each with two quadrupole doublets connected by 180-degrees bends. The bends will consist of 160-degrees spherical deflection plates surrounded by two parallel plate 10-degrees bends. The storage ring ELISA, currently being built, will have a circumference of 6 meters. The first beam tests will take place during summer 1996.

  19. Review of Energy Harvesters Utilizing Bridge Vibrations

    Directory of Open Access Journals (Sweden)

    Farid Ullah Khan

    2016-01-01

    Full Text Available For health monitoring of bridges, wireless acceleration sensor nodes (WASNs are normally used. In bridge environment, several forms of energy are available for operating WASNs that include wind, solar, acoustic, and vibration energy. However, only bridge vibration has the tendency to be utilized for embedded WASNs application in bridge structures. This paper reports on the recent advancements in the area of vibration energy harvesters (VEHs utilizing bridge oscillations. The bridge vibration is narrowband (1 to 40 Hz with low acceleration levels (0.01 to 3.8 g. For utilization of bridge vibration, electromagnetic based vibration energy harvesters (EM-VEHs and piezoelectric based vibration energy harvesters (PE-VEHs have been developed. The power generation of the reported EM-VEHs is in the range from 0.7 to 1450000 μW. However, the power production by the developed PE-VEHs ranges from 0.6 to 7700 μW. The overall size of most of the bridge VEHs is quite comparable and is in mesoscale. The resonant frequencies of EM-VEHs are on the lower side (0.13 to 27 Hz in comparison to PE-VEHs (1 to 120 Hz. The power densities reported for these bridge VEHs range from 0.01 to 9539.5 μW/cm3 and are quite enough to operate most of the commercial WASNs.

  20. Reviving Vibration Energy Harvesting and Self-Powered Sensing by a Triboelectric Nanogenerator

    KAUST Repository

    Chen, Jun

    2017-10-10

    Vibration energy harvesting and sensing is a traditional and growing research field in which various working mechanisms and designs have been developed for an improved performance. Relying on a coupling effect of contact electrification and electrostatic induction, in the past 5 years, triboelectric nanogenerator (TENG) has been applied as a fundamentally new technology to revive the field of vibration energy harvesting and self-powered sensing, especially for low-frequency vibrations such as human motion, automobile, machine, and bridge vibrations. The demonstrated instantaneous energy conversion efficiency of ∼70% and a total efficiency up to 85% distinguished TENG from traditional techniques. In this article, both TENG-enabled vibration energy harvesting and self-powered active sensing are comprehensively reviewed. Moving toward future development, problems pressing for solutions and onward research directions are also posed to deliver a coherent picture.

  1. High Energy Vibration for Gas Piping

    Science.gov (United States)

    Lee, Gary Y. H.; Chan, K. B.; Lee, Aylwin Y. S.; Jia, ShengXiang

    2017-07-01

    In September 2016, a gas compressor in offshore Sarawak has its rotor changed out. Prior to this change-out, pipe vibration study was carried-out by the project team to evaluate any potential high energy pipe vibration problems at the compressor’s existing relief valve downstream pipes due to process condition changes after rotor change out. This paper covers high frequency acoustic excitation (HFAE) vibration also known as acoustic induced vibration (AIV) study and discusses detailed methodologies as a companion to the Energy Institute Guidelines for the avoidance of vibration induced fatigue failure, which is a common industry practice to assess and mitigate for AIV induced fatigue failure. Such detailed theoretical studies can help to minimize or totally avoid physical pipe modification, leading to reduce offshore plant shutdown days to plant shutdowns only being required to accommodate gas compressor upgrades, reducing cost without compromising process safety.

  2. Piezoelectric energy harvesting from broadband random vibrations

    Science.gov (United States)

    Adhikari, S.; Friswell, M. I.; Inman, D. J.

    2009-11-01

    Energy harvesting for the purpose of powering low power electronic sensor systems has received explosive attention in the last few years. Most works using deterministic approaches focusing on using the piezoelectric effect to harvest ambient vibration energy have concentrated on cantilever beams at resonance using harmonic excitation. Here, using a stochastic approach, we focus on using a stack configuration and harvesting broadband vibration energy, a more practically available ambient source. It is assumed that the ambient base excitation is stationary Gaussian white noise, which has a constant power-spectral density across the frequency range considered. The mean power acquired from a piezoelectric vibration-based energy harvester subjected to random base excitation is derived using the theory of random vibrations. Two cases, namely the harvesting circuit with and without an inductor, have been considered. Exact closed-form expressions involving non-dimensional parameters of the electromechanical system have been given and illustrated using numerical examples.

  3. On Kinetics Modeling of Vibrational Energy Transfer

    Science.gov (United States)

    Gilmore, John O.; Sharma, Surendra P.; Cavolowsky, John A. (Technical Monitor)

    1996-01-01

    Two models of vibrational energy exchange are compared at equilibrium to the elementary vibrational exchange reaction for a binary mixture. The first model, non-linear in the species vibrational energies, was derived by Schwartz, Slawsky, and Herzfeld (SSH) by considering the detailed kinetics of vibrational energy levels. This model recovers the result demanded at equilibrium by the elementary reaction. The second model is more recent, and is gaining use in certain areas of computational fluid dynamics. This model, linear in the species vibrational energies, is shown not to recover the required equilibrium result. Further, this more recent model is inconsistent with its suggested rate constants in that those rate constants were inferred from measurements by using the SSH model to reduce the data. The non-linear versus linear nature of these two models can lead to significant differences in vibrational energy coupling. Use of the contemporary model may lead to significant misconceptions, especially when integrated in computer codes considering multiple energy coupling mechanisms.

  4. Development of MEMS Multi-Mode Electrostatic Energy Harvester Based on the SOI Process

    Directory of Open Access Journals (Sweden)

    Bongwon Jeong

    2017-02-01

    Full Text Available Multi-vibrational-mode electrostatic energy harvesters are designed and micro-machined utilizing a simple silicon-on-insulator (SOI wafer-based process. Enhanced adaptability to various vibrational environments is achieved in the proposed design by using serpentine springs attached to the fishbone-shaped inertial mass. The experimental results show that the developed device could convert an input vibration of 6 g at 1272 Hz to 2.96, 3.28, and 2.30 μW for different vibrational directions of 0°, 30°, and 45° with respect to a reference direction, respectively, when all serpentine springs are identical. An alternative device design using serpentine springs with different stiffnesses between x- and y-axes exhibited resonance frequencies at 1059 and 1635 Hz for an input vibrational direction of 45° and acceleration amplitude of 4 g, successfully generating 0.723 and 0.927 μW of electrical power at each resonance, respectively.

  5. Vibrational energy flow in substituted benzenes

    Science.gov (United States)

    Pein, Brandt C.

    Using ultrafast infrared (IR) Raman spectroscopy, vibrational energy flow was monitored in several liquid-state substituted benzenes at ambient temperature. In a series of mono-halogenated benzenes, X-C6H 5 (X = F, Cl, Br, I), a similar CH-stretch at 3068 cm-1 was excited using picosecond IR pulses and the resulting vibrational relaxation and overall vibrational cooling processes were monitored with anti-Stokes spectroscopy. In the molecules with a heavier halide substituent the CH-stretch decayed slower while midrange vibrations decayed faster. This result was logical if the density of states (DOS) in the first few tiers, which is the DOS composed of vibrations with smaller quantum number, is what primarily determines energy flow. For tiers 1-4, the DOS was nearly identical in the CH-stretch region while it increased in the midrange region for heavier halide mass. Excitation spectroscopy, an extension of 3D IR-Raman spectroscopy, was developed and used to selectively pump vibrations localized to the substituent or the phenyl group in nitrobenzene (NB), o-fluoronitrobenzene (OFNB) and o-nitrotoluene (ONT) and in the alkylbenzene series toluene, isopropylbenzene (IPB), and t-butylbenzene (TBB). Using quantum chemical calculations, each Raman active vibration was sorted, according to their atomic displacements, into three classifications: substituent, phenyl, or global. Using IR pump wavenumbers that initially excited substituent or phenyl vibrations, IR-Raman spectroscopy was used to monitor energy flowing from the substituent to phenyl vibrations and vice versa. In NB nitro-to-phenyl and nitro-to-global energy flow was almost nonexistent while phenyl-to-nitro and phenyl-to-global was weak. When ortho substituents (-CH3, -F) were introduced, energy flow from nitro-to-phenyl and nitro-to-global was activated. In ONT, phenyl-to-nitro energy flow ceased possibly due to the added methyl group diverting energy from entering the nitro vibrations. Energy flow is therefore

  6. Vibrational and Rotational Energy Relaxation in Liquids

    DEFF Research Database (Denmark)

    Petersen, Jakob

    Vibrational and rotational energy relaxation in liquids are studied by means of computer simulations. As a precursor for studying vibrational energy relaxation of a solute molecule subsequent to the formation of a chemical bond, the validity of the classical Bersohn-Zewail model for describing......, the vibrational energy relaxation of I2 subsequent to photodissociation and recombination in CCl4 is studied using classical Molecular Dynamics simulations. The vibrational relaxation times and the time-dependent I-I pair distribution function are compared to new experimental results, and a qualitative agreement...... the intramolecular dynamics during photodissociation is investigated. The apparent agreement with quantum mechanical calculations is shown to be in contrast to the applicability of the individual approximations used in deriving the model from a quantum mechanical treatment. In the spirit of the Bersohn-Zewail model...

  7. A hybrid nonlinear vibration energy harvester

    Science.gov (United States)

    Yang, Wei; Towfighian, Shahrzad

    2017-06-01

    Vibration energy harvesting converts mechanical energy from ambient sources to electricity to power remote sensors. Compared to linear resonators that have poor performance away from their natural frequency, nonlinear vibration energy harvesters perform better because they use vibration energy over a broader spectrum. We present a hybrid nonlinear energy harvester that combines bi-stability with internal resonance to increase the frequency bandwidth. A two-fold increase in the frequency bandwidth can be obtained compared to a bi-stable system with fixed magnets. The harvester consists of a piezoelectric cantilever beam carrying a movable magnet facing a fixed magnet. A spring allows the magnet to move along the beam and it provides an extra stored energy to further increase the amplitude of vibration acting as a mechanical amplifier. An electromechanically coupled mathematical model of the system is presented to obtain the dynamic response of the cantilever beam, the movable magnet and the output voltage. The perturbation method of multiple scales is applied to solve these equations and obtain approximate analytical solutions. The effects of various system parameters on the frequency responses are investigated. The numerical approaches of the long time integration (Runge-Kutta method) and the shooting technique are used to verify the analytical results. The results of this study can be used to improve efficiency in converting wasted mechanical vibration to useful electrical energy by broadening the frequency bandwidth.

  8. Size-dependent free vibrations of electrostatically predeformed functionally graded micro-cantilevers

    Science.gov (United States)

    Tahani, Masoud; Batra, Romesh C.; Askari, Amir R.

    2015-07-01

    Size-dependent free vibration analysis of cantilever-type resonant micro-sensors made of non-homogeneous functionally graded materials with two material phases is the objective of the present paper. For this aim, the modified couple stress theory together with the Euler-Bernoulli beam model is considered, and the size-dependent equation of motion which accounts for the non-linear and distributed electrostatic force is derived using the Hamilton's principle. The natural frequencies of the system are extracted using the Galerkin weighted residual method. It is found that the fundamental frequency of the system is decreased with an increase of applied voltage and becomes zero when the input voltage reaches the pull-in voltage of the system. The findings of the present paper are compared and validated by available results in the literature and excellent agreements between them are observed.

  9. Nanoscale piezoelectric vibration energy harvester design

    Science.gov (United States)

    Foruzande, Hamid Reza; Hajnayeb, Ali; Yaghootian, Amin

    2017-09-01

    Development of new nanoscale devices has increased the demand for new types of small-scale energy resources such as ambient vibrations energy harvesters. Among the vibration energy harvesters, piezoelectric energy harvesters (PEHs) can be easily miniaturized and fabricated in micro and nano scales. This change in the dimensions of a PEH leads to a change in its governing equations of motion, and consequently, the predicted harvested energy comparing to a macroscale PEH. In this research, effects of small scale dimensions on the nonlinear vibration and harvested voltage of a nanoscale PEH is studied. The PEH is modeled as a cantilever piezoelectric bimorph nanobeam with a tip mass, using the Euler-Bernoulli beam theory in conjunction with Hamilton's principle. A harmonic base excitation is applied as a model of the ambient vibrations. The nonlocal elasticity theory is used to consider the size effects in the developed model. The derived equations of motion are discretized using the assumed-modes method and solved using the method of multiple scales. Sensitivity analysis for the effect of different parameters of the system in addition to size effects is conducted. The results show the significance of nonlocal elasticity theory in the prediction of system dynamic nonlinear behavior. It is also observed that neglecting the size effects results in lower estimates of the PEH vibration amplitudes. The results pave the way for designing new nanoscale sensors in addition to PEHs.

  10. Nanoscale piezoelectric vibration energy harvester design

    Directory of Open Access Journals (Sweden)

    Hamid Reza Foruzande

    2017-09-01

    Full Text Available Development of new nanoscale devices has increased the demand for new types of small-scale energy resources such as ambient vibrations energy harvesters. Among the vibration energy harvesters, piezoelectric energy harvesters (PEHs can be easily miniaturized and fabricated in micro and nano scales. This change in the dimensions of a PEH leads to a change in its governing equations of motion, and consequently, the predicted harvested energy comparing to a macroscale PEH. In this research, effects of small scale dimensions on the nonlinear vibration and harvested voltage of a nanoscale PEH is studied. The PEH is modeled as a cantilever piezoelectric bimorph nanobeam with a tip mass, using the Euler-Bernoulli beam theory in conjunction with Hamilton’s principle. A harmonic base excitation is applied as a model of the ambient vibrations. The nonlocal elasticity theory is used to consider the size effects in the developed model. The derived equations of motion are discretized using the assumed-modes method and solved using the method of multiple scales. Sensitivity analysis for the effect of different parameters of the system in addition to size effects is conducted. The results show the significance of nonlocal elasticity theory in the prediction of system dynamic nonlinear behavior. It is also observed that neglecting the size effects results in lower estimates of the PEH vibration amplitudes. The results pave the way for designing new nanoscale sensors in addition to PEHs.

  11. Multipolar electrostatics for proteins: atom-atom electrostatic energies in crambin.

    Science.gov (United States)

    Yuan, Yongna; Mills, Matthew J L; Popelier, Paul L A

    2014-02-15

    Accurate electrostatics necessitates the use of multipole moments centered on nuclei or extra point charges centered away from the nuclei. Here, we follow the former alternative and investigate the convergence behavior of atom-atom electrostatic interactions in the pilot protein crambin. Amino acids are cut out from a Protein Data Bank structure of crambin, as single amino acids, di, or tripeptides, and are then capped with a peptide bond at each side. The atoms in the amino acids are defined through Quantum Chemical Topology (QCT) as finite volume electron density fragments. Atom-atom electrostatic energies are computed by means of a multipole expansion with regular spherical harmonics, up to a total interaction rank of L = ℓA+ ℓB + 1 = 10. The minimum internuclear distance in the convergent region of all the 15 possible types of atom-atom interactions in crambin that were calculated based on single amino acids are close to the values calculated from di and tripeptides. Values obtained at B3LYP/aug-cc-pVTZ and MP2/aug-cc-pVTZ levels are only slightly larger than those calculated at HF/6-31G(d,p) level. This convergence behavior is transferable to the well-known amyloid beta polypeptide Aβ1-42. Moreover, for a selected central atom, the influence of its neighbors on its multipole moments is investigated, and how far away this influence can be ignored is also determined. Finally, the convergence behavior of AMBER becomes closer to that of QCT with increasing internuclear distance. Copyright © 2013 Wiley Periodicals, Inc.

  12. Grain size and nanoscale effects on the nonlinear pull-in instability and vibrations of electrostatic actuators made of nanocrystalline material

    Science.gov (United States)

    Gholami, R.; Ansari, R.

    2018-01-01

    Presented herein is the study of grain size, grain surface energy and small scale effects on the nonlinear pull-in instability and free vibration of electrostatic nanoscale actuators made of nanocrystalline silicon (Nc-Si). A Mori–Tanaka micromechanical model is utilized to calculate the effective material properties of Nc-Si considering material structure inhomogeneity, grain size and grain surface energy. The small-scale effect is also taken into account using Mindlin’s strain gradient theory. Governing equations are derived in the discretized weak form using the variational differential quadrature method based on the third-order shear defamation beam theory in conjunction with the von Kármán hypothesis. The electrostatic actuation is modeled considering the fringing field effects based upon the parallel plate approximation. Moreover, the Casimir force effect is considered. The pseudo arc-length continuation technique is used to obtain the applied voltage-deflection curve of Nc-Si actuators. Then, a time-dependent small disturbance around the deflected configuration is assumed to solve the free vibration problem. By performing a numerical study, the influences of various factors such as length scale parameter, volume fraction of the inclusion phase, density ratio, average inclusion radius and Casimir force on the pull-in instability and free vibration of Nc-Si actuators are investigated.

  13. Mechanical vibration to electrical energy converter

    Science.gov (United States)

    Kellogg, Rick Allen [Tijeras, NM; Brotz, Jay Kristoffer [Albuquerque, NM

    2009-03-03

    Electromechanical devices that generate an electrical signal in response to an external source of mechanical vibrations can operate as a sensor of vibrations and as an energy harvester for converting mechanical vibration to electrical energy. The devices incorporate a magnet that is movable through a gap in a ferromagnetic circuit, wherein a coil is wound around a portion of the ferromagnetic circuit. A flexible coupling is used to attach the magnet to a frame for providing alignment of the magnet as it moves or oscillates through the gap in the ferromagnetic circuit. The motion of the magnet can be constrained to occur within a substantially linear range of magnetostatic force that develops due to the motion of the magnet. The devices can have ferromagnetic circuits with multiple arms, an array of magnets having alternating polarity and, encompass micro-electromechanical (MEM) devices.

  14. Vibrational energy relaxation of a diatomic molecule in a room-temperature ionic liquid.

    Science.gov (United States)

    Shim, Youngseon; Kim, Hyung J

    2006-07-14

    Vibrational energy relaxation (VER) dynamics of a diatomic solute in ionic liquid 1-ethyl-3-methylimidazolium hexafluorophosphate (EMI(+)PF(6) (-)) are studied via equilibrium and nonequilibrium molecular dynamics simulations. The time scale for VER is found to decrease markedly with the increasing solute dipole moment, consonant with many previous studies in polar solvents. A detailed analysis of nonequilibrium results shows that for a dipolar solute, dissipation of an excess solute vibrational energy occurs almost exclusively via the Lennard-Jones interactions between the solute and solvent, while an oscillatory energy exchange between the two is mainly controlled by their electrostatic interactions. Regardless of the anharmonicity of the solute vibrational potential, VER becomes accelerated as the initial vibrational energy increases. This is attributed primarily to the enhancement in variations of the solvent force on the solute bond, induced by large-amplitude solute vibrations. One interesting finding is that if a time variable scaled with the initial excitation energy is employed, dissipation dynamics of the excess vibrational energy of the dipolar solute tend to show a universal behavior irrespective of its initial vibrational state. Comparison with water and acetonitrile shows that overall characteristics of VER in EMI(+)PF(6) (-) are similar to those in acetonitrile, while relaxation in water is much faster than the two. It is also found that the Landau-Teller theory predictions for VER time scale obtained via equilibrium simulations of the solvent force autocorrelation function are in reasonable agreement with the nonequilibrium results.

  15. Vibrational energy relaxation in liquids

    Science.gov (United States)

    Chesnoy, J.; Gale, G. M.

    The de-excitation of the vibrational population of small molecules in the liquid state is considered. Experimental techniques applicable to the measurement of relaxation times in dense phases are first described. Theoretical approaches are subsequently developed with special emphasis on the relationship between ab-initio quantum methods and binary interaction models. Finally, a selection of experimental results is analysed in the light of these theories. Special attention is given to the dependence of the relaxation time on experimental parameters such as density, temperature or the concentration of a mixture. The behaviour of the relaxation time across the liquid/solid phase transition is also treated. La désexcitation vibrationnelle de petites molécules est étudiée en phase liquide. Les techniques expérimentales utilisables pour mesurer les temps de relaxation en phase dense sont d'abord décrites. Les approches théoriques sont ensuite développées en montrant en particulier les liens entre les deux principales : l'approche quantique ab-initio et les modèles d'interaction binaire. Un choix de résultats expérimentaux est finalement analysé à la lumière de ces théories. Les dépendances des temps de relaxation envers les paramètres expérimentaux, comme la densité, la température ou la concentration d'un mélange, sont spécialement étudiées. Le comportement de la relaxation à la transition liquide/solide est aussi abordé.

  16. An Extra Electrostatic Energy in Semiconductors and its Impact in Nanostructures

    OpenAIRE

    Sallese, Jean-Michel

    2015-01-01

    This work revisits the classical concept of electric energy and suggests that the common definition is likely to generate large errors when dealing with nanostructures. For instance, deriving the electrostatic energy in semiconductors using the traditional formula fails at giving the correct electrostatic force between capacitor plates and reveals the existence of an extra contribution to the standard electrostatic energy. This additional energy is found to proceed from the generation of spac...

  17. Status of the Frankfurt low energy electrostatic storage ring (FLSR)

    Science.gov (United States)

    King, F.; Kruppi, T.; Müller, J.; Dörner, R.; Schmidt, L. Ph H.; Schmidt-Böcking, H.; Stiebing, K. E.

    2015-11-01

    Frankfurt low-energy storage ring (FLSR) is an electrostatic storage ring for low-energy ions up to q · 80 keV (q being the ion charge state) at Institut für Kernphysik der Goethe-Universität, Frankfurt am Main, Germany. It has especially been designed to provide a basis for experiments on the dynamics of ionic and molecular collisions in complete kinematics, as well as for high precision and time resolved laser spectroscopy. The ring has ‘racetrack’ geometry with a circumference of 14.23 m. It comprises four experimental/diagnostic sections with regions of enhanced ion density (interaction regions). First beam has successfully been stored in FLSR in summer 2013. Since then the performance of the ring has continuously been improved and an electron target for experiments on dissociative recombination has been installed in one of the experimental sections.

  18. Nanostructured Electrodes Via Electrostatic Spray Deposition for Energy Storage System

    KAUST Repository

    Chen, C.

    2014-10-02

    Energy storage systems such as Li-ion batteries and supercapacitors are extremely important in today’s society, and have been widely used as the energy and power sources for portable electronics, electrical vehicles and hybrid electrical vehicles. A lot of research has focused on improving their performance; however, many crucial challenges need to be addressed to obtain high performance electrode materials for further applications. Recently, the electrostatic spray deposition (ESD) technique has attracted great interest to satisfy the goals. Due to its many advantages, the ESD technique shows promising prospects compared to other conventional deposition techniques. In this paper, our recent research outcomes related to the ESD derived anodes for Li-ion batteries and other applications is summarized and discussed.

  19. MEMS-Based Waste Vibrational Energy Harvesters

    Science.gov (United States)

    2013-06-01

    low spring constant objective to be achieved. A piezoelectric cantilever beam that is very long and very thin would produce the maximum voltage...California, Berkeley, 2002. [11] A. Kasyap, “Development of MEMS-based piezoelectric cantilever arrays for vibrational energy harvesting,” Gainesville, FL...maximum 200 words) The piezoelectric effect is a phenomenon where strain on a piezoelectric crystal structure causes potential difference at its

  20. Hierarchical cellulose-derived carbon nanocomposites for electrostatic energy storage

    Science.gov (United States)

    Kuzmenko, V.; Saleem, A. M.; Bhaskar, A.; Staaf, H.; Desmaris, V.; Enoksson, P.

    2015-12-01

    The problem of energy storage and its continuous delivery on demand needs new effective solutions. Supercapacitors are viewed as essential devices for solving this problem since they can quickly provide high power basically countless number of times. The performance of supercapacitors is mostly dependent on the properties of electrode materials used for electrostatic charge accumulation, i.e. energy storage. This study presents new sustainable cellulose-derived materials that can be used as electrodes for supercapacitors. Nanofibrous carbon nanofiber (CNF) mats were covered with vapor-grown carbon nanotubes (CNTs) in order to get composite CNF/CNT electrode material. The resulting composite material had significantly higher surface area and was much more conductive than pure CNF material. The performance of the CNF/CNT electrodes was evaluated by various analysis methods such as cyclic voltammetry, galvanostatic charge-discharge, electrochemical impedance spectroscopy and cyclic stability. The results showed that the cellulose-derived composite electrodes have fairly high values of specific capacitance and power density and can retain excellent performance over at least 2 000 cycles. Therefore it can be stated that sustainable cellulose-derived CNF/CNT composites are prospective materials for supercapacitor electrodes.

  1. A flexible electrostatic kinetic energy harvester based on electret films of electrospun nanofibers

    Science.gov (United States)

    Lu, Y.; Capo-Chichi, M.; Leprince-Wang, Y.; Basset, P.

    2018-01-01

    This paper reports a paper-based electrostatic kinetic energy harvester (e-KEH) implementing multilayered electret films based on electrospun nanofibrous material. It is the first time that a fully flexible electret-based e-KEH is reported. The proposed electret, PVDF-PTFD nanofibrous covered by Parylene C, has a faster stabilization of surface potential than a planar thin film of Parylene C, and a higher stability of charge storage. With a maximum force of 0.5 N and a 3-layer electret, the device capacitance increases from 25 to 100 pF during a pressing operation. Working with the optimal resistive load of 16 MΩ, the device pressed manually delivers a peak instantaneous power up to 45.6 μW and an average energy of 54 nJ/stroke, corresponding to a peak instantaneous power density of 7.3 μW cm‑2 and an average energy density of 8.6 nJ cm‑2/stroke. Within 450 manual strokes, a 10 nF capacitor is charged up to 8.5 V by the prototype through a full-wave diode bridge. On a 1 μF capacitor, the energy delivery of 9.9 nJ/stroke has been obtained with a 10 Hz pressing movement excited by a vibrator with a maximum force of 0.5 N.

  2. A review on energy harvesting approaches for renewable energies from ambient vibrations and acoustic waves using piezoelectricity

    Science.gov (United States)

    Ahmed, Riaz; Mir, Fariha; Banerjee, Sourav

    2017-08-01

    The principal objective of this article is to categorically review and compare the state of the art vibration based energy harvesting approaches. To evaluate the contemporary methodologies with respect to their physics, average power output and operational frequencies, systematically divided and easy readable tables are presented followed by the description of the energy harvesting methods. Energy harvesting is the process of obtaining electrical energy from the surrounding vibratory mechanical systems through an energy conversion method using smart structures, like, piezoelectric, electrostatic materials. Recent advancements in low power electronic gadgets, micro electro mechanical systems, and wireless sensors have significantly increased local power demand. In order to circumvent the energy demand; to allow limitless power supply, and to avoid chemical waste from conventional batteries, low power local energy harvesters are proposed for harvesting energy from different ambient energy sources. Piezoelectric materials have received tremendous interest in energy harvesting technology due to its unique ability to capitalize the ambient vibrations to generate electric potential. Their crystalline configuration allows the material to convert mechanical strain energy into electrical potential, and vice versa. This article discusses the various approaches in vibration based energy scavenging where piezoelectric materials are employed as the energy conversion medium.

  3. Production, Delivery and Application of Vibration Energy in Healthcare

    Science.gov (United States)

    Abundo, Paolo; Trombetta, Chiara; Foti, Calogero; Rosato, Nicola

    2011-02-01

    In Rehabilitation Medicine therapeutic application of vibration energy in specific clinical treatments and in sport rehabilitation is being affirmed more and more.Vibration exposure can have positive or negative effects on the human body depending on the features and time of the characterizing wave. The human body is constantly subjected to different kinds of vibrations, inducing bones and muscles to actively modify their structure and metabolism in order to fulfill the required functions. Like every other machine, the body supports only certain vibration energy levels over which long term impairments can be recognized. As shown in literature anyway, short periods of vibration exposure and specific frequency values can determine positive adjustments.

  4. Methods of performing downhole operations using orbital vibrator energy sources

    Science.gov (United States)

    Cole, Jack H.; Weinberg, David M.; Wilson, Dennis R.

    2004-02-17

    Methods of performing down hole operations in a wellbore. A vibrational source is positioned within a tubular member such that an annulus is formed between the vibrational source and an interior surface of the tubular member. A fluid medium, such as high bulk modulus drilling mud, is disposed within the annulus. The vibrational source forms a fluid coupling with the tubular member through the fluid medium to transfer vibrational energy to the tubular member. The vibrational energy may be used, for example, to free a stuck tubular, consolidate a cement slurry and/or detect voids within a cement slurry prior to the curing thereof.

  5. Evaluation of Breaking Performance in Vibration-Assisted Electrostatic Surface Induction Actuator

    DEFF Research Database (Denmark)

    Nemoto, Takeru; Zsurzsan, Tiberiu-Gabriel; Yamamoto, Akio

    2015-01-01

    force can be changed by turning on and off the vibrator. The friction change can be utilized for high-performance slider motion control; for example, friction can be increased by switching off the vibrator when the slider needs to stop. In this paper, we evaluated how fast the slider can stop in several...

  6. Energy Efficient Clothes Dryer with IR Heating and Electrostatic Precipitator

    Energy Technology Data Exchange (ETDEWEB)

    Weaver, Stanton [GE Global Research, Niskayuna, NY (United States)

    2017-12-12

    The project goal was to develop a revolutionary energy saving technology for residential clothes drying. The team developed an IR (infrared) heating system and NESP (Nebulizer and Electro-Static Precipitator) for integration into a ventless clothes dryer. The proposed technology addresses two of the major inefficiencies in current electric vented dryers by providing effective energy transfer for the removal of the water and recapture of the vapor latent heat. The IR heaters operating in the mid wave (2.5-10um) are very efficient as they target the 3-micron peak absorption of the water molecule. This allows direct energy absorption, unlike conventional element heaters where heat is transferred by convection. The low power NESP removes water vapor from the exhausted stream and recaptures the latent heat in the ESP (Electro-Static Precipitator) exchanger section. This allows the warm dry air to be recirculated back into the drum for additional efficiency savings. The remaining majority of the dryer hardware stays the same. Summing the efficiency gain from the two subcomponents we anticipated the EF (Efficiency Factor) to exceed the goal of 4.04. EF is obtained by dividing the weight (lbs) of water removed by the energy (kWhr) used, where the test load size is 8.45 lbs of bone dry clothing wetted to 57.5% or 4.8lbs of water, and dried to a remaining moisture content of 2.5-5%. Additional benefits include not having to recondition (heat or cool) the large amounts of make-up air to replace the air exhausted by a vented dryer. It was anticipated that the NESP/heat exchanger would be the most challenging and highest risk element in the program. Therefore, the team focused their efforts during Phase 1 of the program on the design, construction, testing, and optimization of the NESP/heat exchanger. At the end Phase 1, the team compared the performance of the NESP/heat exchanger with the system level requirements and made a Go/No-Go decision on proceeding with the second

  7. Modelling of micro vibration energy harvester considering size effect

    Science.gov (United States)

    Li, Chuangye; Huo, Rui; Wang, Weike

    2017-09-01

    Considering increase of stiffness caused by size effect, equivalent Young's modulus was introduced for futher analysis. Experimental platform was established to test vibration characteristics. Dynamic equation for micro piezoelectric cantilever beam considering size effect was studied with finite element analysis and experiment. Results shows it is accurate. Based on that, dynamic model for micro vibration energy harvester was improved, a T-type micro vibration energy harvester was designed and fabricated. Resonant frequency, tip displacement and output voltage of the harvester were obtained. Comparing with macroscopic model for vibration harvester, improved one reduces errors by 13%, 35% and 22%.

  8. Modeling and Optimization of an Electrostatic Energy Harvesting Device

    DEFF Research Database (Denmark)

    Crovetto, Andrea; Wang, Fei; Hansen, Ole

    2014-01-01

    that the electrostatic transducer force is related to the voltage output and cannot be approximated by viscous damping or a Coulomb force as reported previously. The coupled model with two simultaneous differential equations is numerically solved for the voltage output and transduction force with given parameters...

  9. Electrostatics, structure prediction, and the energy landscapes for protein folding and binding.

    Science.gov (United States)

    Tsai, Min-Yeh; Zheng, Weihua; Balamurugan, D; Schafer, Nicholas P; Kim, Bobby L; Cheung, Margaret S; Wolynes, Peter G

    2016-01-01

    While being long in range and therefore weakly specific, electrostatic interactions are able to modulate the stability and folding landscapes of some proteins. The relevance of electrostatic forces for steering the docking of proteins to each other is widely acknowledged, however, the role of electrostatics in establishing specifically funneled landscapes and their relevance for protein structure prediction are still not clear. By introducing Debye-Hückel potentials that mimic long-range electrostatic forces into the Associative memory, Water mediated, Structure, and Energy Model (AWSEM), a transferable protein model capable of predicting tertiary structures, we assess the effects of electrostatics on the landscapes of thirteen monomeric proteins and four dimers. For the monomers, we find that adding electrostatic interactions does not improve structure prediction. Simulations of ribosomal protein S6 show, however, that folding stability depends monotonically on electrostatic strength. The trend in predicted melting temperatures of the S6 variants agrees with experimental observations. Electrostatic effects can play a range of roles in binding. The binding of the protein complex KIX-pKID is largely assisted by electrostatic interactions, which provide direct charge-charge stabilization of the native state and contribute to the funneling of the binding landscape. In contrast, for several other proteins, including the DNA-binding protein FIS, electrostatics causes frustration in the DNA-binding region, which favors its binding with DNA but not with its protein partner. This study highlights the importance of long-range electrostatics in functional responses to problems where proteins interact with their charged partners, such as DNA, RNA, as well as membranes. © 2015 The Protein Society.

  10. A Flexible Electret Membrane with Persistent Electrostatic Effect and Resistance to Harsh Environment for Energy Harvesting.

    Science.gov (United States)

    Huiming, Xiao; Gangjin, Chen; Xuming, Chen; Zhi, Chen

    2017-08-16

    A novel flexible electret membrane, exhibiting persistent electrostatic effect, distinctive temperature stability and outstanding capability of resistance to harsh environment and fatigue, is demonstrated by experiment. Its excellent electret performance is correlated to the synergy of three factors, which are space charge injection, dipole orientation and interfacial polarization according to the analysis of charge storage mechanism. This electret membrane is provided with sandwich configuration PTFE/THV/PTFE, prepared by hot pressing method and thermal charging technology. After wiped its surface with alcohol, its surface potential declines to zero from -550 V, then recovers rapidly to -310 V and finally maintains constant for 800 hours, which shows that its electret performance distinctly precedes traditional electret material such as single PTFE, FEP electret membrane. The measurement of thermal stimulating potentials displays that its surface potential reaches maximum about 5 times initial value at 125 °C. A micro-vibration energy harvester is assembled with this membrane. Its maximum output power reaches 4.66 μW at tapping frequency 5 Hz and keeps stable during over 2000 tapping tests within 100 days, which indicates the long-life service and resistance to harsh environment and fatigue of this electret membrane.

  11. A MEMS vibration energy harvester for automotive applications

    Science.gov (United States)

    van Schaijk, R.; Elfrink, R.; Oudenhoven, J.; Pop, V.; Wang, Z.; Renaud, M.

    2013-05-01

    The objective of this work is to develop MEMS vibration energy harvesters for tire pressure monitoring systems (TPMS), they can be located on the rim or on the inner-liner of the car tire. Nowadays TPMS modules are powered by batteries with a limited lifetime. A large effort is ongoing to replace batteries with small and long lasting power sources like energy harvesters [1]. The operation principle of vibration harvesters is mechanical resonance of a seismic mass, where mechanical energy is converted into electrical energy. In general, vibration energy harvesters are of specific interest for machine environments where random noise or repetitive shock vibrations are present. In this work we present the results for MEMS based vibration energy harvesting for applying on the rim or inner-liner. The vibrations on the rim correspond to random noise. A vibration energy harvester can be described as an under damped mass-spring system acting like a mechanical band-pass filter, and will resonate at its natural frequency [2]. At 0.01 g2/Hz noise amplitude the average power can reach the level that is required to power a simple wireless sensor node, approximately 10 μW [3]. The dominant vibrations on the inner-liner consist mainly of repetitive high amplitude shocks. With a shock, the seismic mass is displaced, after which the mass will "ring-down" at its natural resonance frequency. During the ring-down period, part of the mechanical energy is harvested. On the inner-liner of the tire repetitive (one per rotation) high amplitude (few hundred g) shocks occur. The harvester enables an average power of a few tens of μW [4], sufficient to power a more sophisticated wireless sensor node that can measure additional tire-parameters besides pressure. In this work we characterized MEMS vibration energy harvesters for noise and shock excitation. We validated their potential for TPMS modules by measurements and simulation.

  12. Broadband vibration energy harvester utilizing three out-of-plane modes of one vibrating body

    Science.gov (United States)

    Park, Shi-Baek; Jang, Seon-Jun; Kim, In-Ho; Choi, Yong Je

    2017-10-01

    In this paper, we introduce the concept, design equation, and realization of a broadband electromagnetic vibrational energy harvester. The spatial vibrating system in the proposed harvester is arranged to have three out-of-plane vibration modes. We devise the design method for its three natural frequencies and accompanying modes and apply it to the broadband energy harvesting by locating three frequencies close to each other. The numerical simulation and the experimental results show that it satisfies the designated frequencies as well as the enhanced bandwidth for power generation.

  13. Energy evaluation of protection effectiveness of anti-vibration gloves.

    Science.gov (United States)

    Hermann, Tomasz; Dobry, Marian Witalis

    2017-09-01

    This article describes an energy method of assessing protection effectiveness of anti-vibration gloves on the human dynamic structure. The study uses dynamic models of the human and the glove specified in Standard No. ISO 10068:2012. The physical models of human-tool systems were developed by combining human physical models with a power tool model. The combined human-tool models were then transformed into mathematical models from which energy models were finally derived. Comparative energy analysis was conducted in the domain of rms powers. The energy models of the human-tool systems were solved using numerical simulation implemented in the MATLAB/Simulink environment. The simulation procedure demonstrated the effectiveness of the anti-vibration glove as a method of protecting human operators of hand-held power tools against vibration. The desirable effect is achieved by lowering the flow of energy in the human-tool system when the anti-vibration glove is employed.

  14. The Electrostatic Wind Energy Converter : Electrical performance of a high voltage prototype

    NARCIS (Netherlands)

    Djairam, D.

    2008-01-01

    Wind energy is converted to electrical energy by letting the wind move charged particles against the direction of an electric field. The advantage of this type of conversion is that no rotational movement, which occurs in conventional wind turbines, is required. An electrostatic wind energy

  15. A Novel Ropes-DrivenWideband Piezoelectric Vibration Energy Harvester

    Directory of Open Access Journals (Sweden)

    Jinhui Zhang

    2016-12-01

    Full Text Available This paper presents a novel piezoelectric vibration energy harvester (PVEH in which a high-frequency generating beam (HFGB is driven by an array of low-frequency driving beams (LFDBs using ropes. Two mechanisms based on frequency upconversion and multimodal harvesting work together to broaden the frequency bandwidth of the proposed vibration energy harvester (VEH. The experimental results show that the output power of generating beam (GB remains unchanged with the increasing number of driving beams (DBs, compared with the traditional arrays of beams vibration energy harvester (AB-VEH, and the output power and bandwidth behavior can be adjusted by parameters such as acceleration, rope margin, and stiffness of LFDBs, which shows the potential to achieve unlimited wideband vibration energy-harvesting for a variable environment.

  16. Time Resolved Energy Transfer and Photodissociation of Vibrationally Excited Molecules

    National Research Council Canada - National Science Library

    Crim, F. F

    2007-01-01

    ...) in solution and in the gas phase. This second experiment is one of the few direct comparisons of intramolecular vibrational energy flow in a solvated molecule with that in the same molecule isolated in a gas...

  17. Nonlinear spring-less electromagnetic vibration energy harvesting system

    Science.gov (United States)

    Hadas, Z.; Ondrusek, C.

    2015-11-01

    This paper deals with a description and modelling of a spring-less electromagnetic vibration energy harvesting system. The presented unique electromagnetic vibration energy harvester consists of a nonlinear resonance mechanism, magnetic circuit with a coil and an electronic load. The mechanical vibrations excite the nonlinear resonance mechanism and the relative movement of the magnetic circuit against fixed coil induces voltage due to Faraday's Law. When the electronics is connected the current flows through the load and output power is harvested. There are several nonlinearities which affects operations of the presented electromagnetic energy harvesting system. The significant nonlinearity of the system is stiffness of the resonance mechanism and it causes extending of an operation bandwidth. The harvesting of electrical energy from mechanical vibrations provides electromagnetic damping feedbacks of the coil to moving magnetic circuit. The feedback depends on the current flow through the electronic load and coil. The using of modern power management circuit with optimal power point provides other nonlinear operation.

  18. Vibrational Energy Relaxation in Water-Acetonitrile Mixtures

    NARCIS (Netherlands)

    Cringus, Dan; Yeremenko, Sergey; Pshenichnikov, Maxim S.; Wiersma, Douwe A.; Kobayashi, Takayoshi; Kobayashi, Tetsuro; Nelson, Keith A.; Okada, Tadashi; Silvestri, Sandro De

    2004-01-01

    IR pump-probe spectroscopy is used to study the effect of hydrogen bonding on the vibrational energy relaxation pathways. Hydrogen bonding accelerates the population relaxation from 12ps in diluted acetonitrile solution to 700fs in bulk water.

  19. Vibrational energy relaxation in water-acetonitrile mixtures

    NARCIS (Netherlands)

    Cringus, D; Yeremenko, S; Pshenichnikov, MS; Wiersma, DA; Kobayashi, T; Okada, T; Kobayashi, T; Nelson, KA; DeSilvestri, S

    2005-01-01

    IR pump-probe spectroscopy is used to study the effect of hydrogen bonding on the vibrational energy relaxation pathways. Hydrogen bonding accelerates the population relaxation from 12ps in diluted acetonitrile solution to 700fs in bulk water.

  20. Vibrational energy relaxation in water-acetonitrile mixtures

    NARCIS (Netherlands)

    Cringus, Dan; Yeremenko, Sergey; Pshenichnikov, Maxim S.; Wiersma, Douwe A.

    2004-01-01

    IR pump-probe spectroscopy is used to study the effect of hydrogen bonding on the vibrational energy relaxation pathways. Hydrogen bonding accelerates the population relaxation from 12ps in diluted acetonitrile solution to 700fs in bulk water.

  1. Vibrational spectroscopic (FT-IR and FT-Raman) studies, natural bond orbital analysis and molecular electrostatic potential surface of Isoxanthopterin.

    Science.gov (United States)

    Prabavathi, N; Nilufer, A; Krishnakumar, V

    2013-10-01

    The FTIR and FT-Raman spectra of Isoxanthopterin have been recorded in the region 4000-450 and 4000-100 cm(-1), respectively. The optimized geometry, frequency and intensity of the vibrational bands of Isoxanthopterin were obtained by the density functional theory (DFT) using 6-311++G(d,p) basis set. The harmonic vibrational frequencies were scaled and compared with experimental values. The observed and the calculated frequencies are found to be in good agreement. The (1)H and (13)C nuclear magnetic resonance chemical shifts of the molecule were also calculated using the gauge independent atomic orbital (GIAO) method. The UV-visible spectrum was also recorded and compared with the theoretical values. The calculated HOMO and LUMO energies show that charge transfer occurs within molecule. The first order hyperpolarizability (β0), related properties (β, α0 and Δα) and the Mulliken charges of the molecule were also computed using DFT calculations. Stability of the molecule arising from hyperconjugative interactions, charge delocalization have been analyzed using natural bond orbital (NBO) analysis. The results show that charge in electron density (ED) in the σ* and π* antibonding orbitals and second order delocalization energies (E2) confirms the occurrence of intramolecular charge transfer (ICT) within the molecule. Information about the charge density distribution of the molecule and its chemical reactivity has been obtained by mapping molecular electrostatic potential surface. In addition, the non-linear optical properties were discussed from the dipole moment values and excitation wavelength in the UV-visible region. Copyright © 2013 Elsevier B.V. All rights reserved.

  2. A Detailed Level Kinetics Model of NO Vibrational Energy Distributions

    Science.gov (United States)

    Sharma, Surendra P.; Gilmore, John; Cavolowsky, John A. (Technical Monitor)

    1996-01-01

    Several contemporary problems have pointed to the desirability of a detailed level kinetics approach to modeling the distribution of vibrational energy in NO. Such a model is necessary when vibrational redistribution reactions are insufficient to maintain a Boltzmann distribution over the vibrational energy states. Recent calculations of the rate constant for the first reaction of the Zeldovich mechanism (N2 + O (goes to) NO + N) have suggested that the product NO is formed in high vibrational states. In shock layer flowfields, the product NO molecules may experience an insufficient number of collisions to establish a Boltzmann distribution over vibrational states, thus necessitating a level kinetics model. In other flows, such as expansions of high temperature air, fast, near-resonance vibrational energy exchanges with N2 and O2 may also require a level specific model for NO because of the relative rates of vibrational exchange and redistribution. The proposed report will integrate computational and experimental components to construct such a model for the NO molecule.

  3. Spectroscopic probes of vibrationally excited molecules at chemically significant energies

    Energy Technology Data Exchange (ETDEWEB)

    Rizzo, T.R. [Univ. of Rochester, NY (United States)

    1993-12-01

    This project involves the application of multiple-resonance spectroscopic techniques for investigating energy transfer and dissociation dynamics of highly vibrationally excited molecules. Two major goals of this work are: (1) to provide information on potential energy surfaces of combustion related molecules at chemically significant energies, and (2) to test theoretical modes of unimolecular dissociation rates critically via quantum-state resolved measurements.

  4. Free-energy functionals of the electrostatic potential for Poisson-Boltzmann theory.

    Science.gov (United States)

    Jadhao, Vikram; Solis, Francisco J; de la Cruz, Monica Olvera

    2013-08-01

    In simulating charged systems, it is often useful to treat some ionic components of the system at the mean-field level and solve the Poisson-Boltzmann (PB) equation to get their respective density profiles. The numerically intensive task of solving the PB equation at each step of the simulation can be bypassed using variational methods that treat the electrostatic potential as a dynamic variable. But such approaches require the access to a true free-energy functional: a functional that not only provides the correct solution of the PB equation upon extremization, but also evaluates to the true free energy of the system at its minimum. Moreover, the numerical efficiency of such procedures is further enhanced if the free-energy functional is local and is expressed in terms of the electrostatic potential. Existing PB functionals of the electrostatic potential, while possessing the local structure, are not free-energy functionals. We present a variational formulation with a local free-energy functional of the potential. In addition, we also construct a nonlocal free-energy functional of the electrostatic potential. These functionals are suited for employment in simulation schemes based on the ideas of dynamical optimization.

  5. A MEMS Energy Harvesting Device for Vibration with Low Acceleration

    DEFF Research Database (Denmark)

    Triches, Marco; Wang, Fei; Crovetto, Andrea

    2012-01-01

    We propose a polymer electret based energy harvesting device in order to extract energy from vibration sources with low acceleration. With MEMS technology, a silicon structure is fabricated which can resonate in 2D directions. Thanks to the excellent mechanical properties of the silicon material...

  6. Design, modeling, fabrication and characterization of an electret-based MEMS electrostatic energy harvester

    NARCIS (Netherlands)

    Altena, G.; Hohlfeld, D.; Elfrink, R.; Goedbloed, M.H.; Schaijk, R. van

    2011-01-01

    This paper reports on the design, modelling, fabrication and characterization of an electret-based MEMS electrostatic energy harvester with an elegant and robust process flow. The fabrication is based on a SOI wafer with self-aligned electrodes of the variable capacitor. The output current of the

  7. Student Reasoning about Electrostatic and Gravitational Potential Energy: An Exploratory Study with Interdisciplinary Consequences

    Science.gov (United States)

    Lindsey, Beth A.

    2014-01-01

    This paper describes an investigation into student reasoning about potential energy in the context of introductory electrostatics. Similar incorrect reasoning patterns emerged both in written questions administered after relevant instruction and in one-on-one interviews. These reasoning patterns are also prevalent in responses to questions posed…

  8. Bi-axial Vibration Energy Harvesting

    Science.gov (United States)

    2012-07-01

    impedance measurement are presented in Section 4, however it is noted that the measured capacitance of ME transducer (i.e. the bonded PZT element...two wire ligaments), connected to a 75 N vibration shaker (TIRA S 511 75 N). Host accelerations were measured using an accelerometer (PCB 333B40... capacitance of the ME transducer was 1.86 nF (see above), resulting in a capacitive reactance at 10 Hz of, XC = 1/(2  f C) ~ 8.6 MΩ . (6

  9. Low Head, Vortex Induced Vibrations River Energy Converter

    Energy Technology Data Exchange (ETDEWEB)

    Bernitsas, Michael B.; Dritz, Tad

    2006-06-30

    Vortex Induced Vibrations Aquatic Clean Energy (VIVACE) is a novel, demonstrated approach to extracting energy from water currents. This invention is based on a phenomenon called Vortex Induced Vibrations (VIV), which was first observed by Leonardo da Vinci in 1504AD. He called it ‘Aeolian Tones.’ For decades, engineers have attempted to prevent this type of vibration from damaging structures, such as offshore platforms, nuclear fuel rods, cables, buildings, and bridges. The underlying concept of the VIVACE Converter is the following: Strengthen rather than spoil vortex shedding; enhance rather than suppress VIV; harness rather than mitigate VIV energy. By maximizing and utilizing this unique phenomenon, VIVACE takes this “problem” and successfully transforms it into a valuable resource for mankind.

  10. Development of a Cantilever-Type Electrostatic Energy Harvester and Its Charging Characteristics on a Highway Viaduct

    Directory of Open Access Journals (Sweden)

    Hideaki Koga

    2017-09-01

    Full Text Available We have developed a micro-electro-mechanical systems (MEMS electrostatic vibratory power generator with over 100 μ W RMS of (root-mean-square output electric power under 0.03 G RMS (G: the acceleration of gravity accelerations. The device is made of a silicon-on-insulator (SOI wafer and is fabricated by silicon micromachining technology. An electret built-in potential is given to the device by electrothermal polarization in silicon oxide using potassium ions. The force factor, which is defined by a proportional coefficient of the output current with respect to the vibration velocity, is 2.34 × 10 − 4 C/m; this large value allows the developed vibration power generator to have a very high power efficiency of 80.7%. We have also demonstrated a charging experiment by using an environmental acceleration waveform with an average amplitude of about 0.03 G RMS taken at a viaduct of a highway, and we obtained 4.8 mJ of electric energy stored in a 44 μ F capacitor in 90 min.

  11. Current integrator for calibration system of energy scale of electrostatic accelerator

    CERN Document Server

    Nagornyj, A G

    2002-01-01

    To calibrate energy scale of electrostatic accelerator one designed a current integrator based on a reference charge equalizing. Current integrator measures positive charge coming to the target at its bombardment by a particle beam via charge transformation into number of pulses. Paper describes a basic diagram of integrator and lists its basic characteristics. Current integrator operates within 10 nA - 30 mu A current range. Its transformation factor is equal to 10 sup 9 pulses/C, while transformation error is maximum 1.2x10 sup - sup 1 sup 2 A/deg C. Current integrator showed stable operation with 2 MeV small-scale electrostatic accelerator

  12. Passive and Active Vibration Control of Renewable Energy Structures

    DEFF Research Database (Denmark)

    Zhang, Zili

    The present thesis deals with fundamental researches on passive and active vibration control of renewable energy structures, and provides useful models for practical applications. Effective and robust vibration control methods have been explored for mitigating the lightly damped edgewise blade...... solutions for wave energy point absorbers, in order to maximize the mean absorbed power and to deliver more smooth power to the grid. A novel suboptimal causal control law has been established for controlling the motion of the point absorber, and a new type of point absorber has also been proposed...

  13. Combined Euler column vibration isolation and energy harvesting

    Science.gov (United States)

    Davis, R. B.; McDowell, M. D.

    2017-05-01

    A new device that combines vibration isolation and energy harvesting is modeled, simulated, and tested. The vibration isolating portion of the device uses post-buckled beams as its spring elements. Piezoelectric film is applied to the beams to harvest energy from their dynamic flexure. The entire device operates passively on applied base excitation and requires no external power or control system. The structural system is modeled using the elastica, and the structural response is applied as forcing on the electric circuit equation to predict the output voltage and the corresponding harvested power. The vibration isolation and energy harvesting performance is simulated across a large parameter space and the modeling approach is validated with experimental results. Experimental transmissibilities of 2% and harvested power levels of 0.36 μW are simultaneously demonstrated. Both theoretical and experimental data suggest that there is not necessarily a trade-off between vibration isolation and harvested power. That is, within the practical operational range of the device, improved vibration isolation will be accompanied by an increase in the harvested power as the forcing frequency is increased.

  14. Damping and energy dissipation in soft tissue vibrations during running.

    Science.gov (United States)

    Khassetarash, Arash; Hassannejad, Reza; Enders, Hendrik; Ettefagh, Mir Mohammad

    2015-01-21

    It has been well accepted that the vibrations of soft tissue cannot be simulated by a single sinusoidal function. In fact, these vibrations are a combination of several vibration modes. In this study, these modes are extracted applying a recently developed method namely, partly ensemble empirical mode decomposition (PEEMD). Then, a methodology for estimating the damping properties and energy dissipation caused by damping for each mode is used. Applying this methodology on simulated signals demonstrates high accuracy. This methodology is applied to the acceleration signals of the gastrocnemius muscle during sprinting and the differences between the damping properties of different vibration modes were identified. The results were 1) the damping property of high-frequency mode was higher than that for low-frequency modes. 2) All identified modes were in under damped condition, therefore, the vibrations had an oscillatory nature. 3) The damping ratios of lower modes are about 100% increased compared to higher modes. 4) The energy dissipation occurred in lower modes were much more than that for higher mode; According to the power spectrum of the ground reaction force (GRF), which is the input force into the body, the recent finding supports the muscle tuning paradigm. It is suggested that the damping properties and energy dissipation can be used to distinguish between different running conditions (surface, fatigue, etc.). Copyright © 2014 Elsevier Ltd. All rights reserved.

  15. Heavy atom vibrational modes and low-energy vibrational autodetachment in nitromethane anions

    Energy Technology Data Exchange (ETDEWEB)

    Thompson, Michael C.; Weber, J. Mathias, E-mail: weberjm@jila.colorado.edu [JILA, University of Colorado at Boulder, 440 UCB, Boulder, Colorado 80309-0440 (United States); Department of Chemistry and Biochemistry, University of Colorado at Boulder, 215UCB, Boulder, Colorado 80309-0215 (United States); Baraban, Joshua H. [Department of Chemistry and Biochemistry, University of Colorado at Boulder, 215UCB, Boulder, Colorado 80309-0215 (United States); Matthews, Devin A. [Institute for Computational Engineering and Science, University of Texas at Austin, 201 E. 24th St., Austin, Texas 78712 (United States); Stanton, John F. [Department of Chemistry and Biochemistry, University of Texas at Austin, 1 University Station A5300, Austin, Texas 78712-0165 (United States)

    2015-06-21

    We report infrared spectra of nitromethane anion, CH{sub 3}NO{sub 2}{sup −}, in the region 700–2150 cm{sup −1}, obtained by Ar predissociation spectroscopy and electron detachment spectroscopy. The data are interpreted in the framework of second-order vibrational perturbation theory based on coupled-cluster electronic structure calculations. The modes in the spectroscopic region studied here are mainly based on vibrations involving the heavier atoms; this work complements earlier studies on nitromethane anion that focused on the CH stretching region of the spectrum. Electron detachment begins at photon energies far below the adiabatic electron affinity due to thermal population of excited vibrational states.

  16. Time-varying output performances of piezoelectric vibration energy harvesting under nonstationary random vibrations

    Science.gov (United States)

    Yoon, Heonjun; Kim, Miso; Park, Choon-Su; Youn, Byeng D.

    2018-01-01

    Piezoelectric vibration energy harvesting (PVEH) has received much attention as a potential solution that could ultimately realize self-powered wireless sensor networks. Since most ambient vibrations in nature are inherently random and nonstationary, the output performances of PVEH devices also randomly change with time. However, little attention has been paid to investigating the randomly time-varying electroelastic behaviors of PVEH systems both analytically and experimentally. The objective of this study is thus to make a step forward towards a deep understanding of the time-varying performances of PVEH devices under nonstationary random vibrations. Two typical cases of nonstationary random vibration signals are considered: (1) randomly-varying amplitude (amplitude modulation; AM) and (2) randomly-varying amplitude with randomly-varying instantaneous frequency (amplitude and frequency modulation; AM-FM). In both cases, this study pursues well-balanced correlations of analytical predictions and experimental observations to deduce the relationships between the time-varying output performances of the PVEH device and two primary input parameters, such as a central frequency and an external electrical resistance. We introduce three correlation metrics to quantitatively compare analytical prediction and experimental observation, including the normalized root mean square error, the correlation coefficient, and the weighted integrated factor. Analytical predictions are in an excellent agreement with experimental observations both mechanically and electrically. This study provides insightful guidelines for designing PVEH devices to reliably generate electric power under nonstationary random vibrations.

  17. Low energy electron impact vibrational excitation of acetylene

    Science.gov (United States)

    Patra, Sigma; Hargreaves, Leigh; Khakoo, Murtadha

    2016-05-01

    Experimental differential cross sections for the vibration excitation of the four fundamental modes of acetylene at low incident electron energies from 1 eV to 20 eV and scattering angles of 10o to 130o will be presented. The results will be compared to results available in the literature. Funded by NSF-AMOP-RUI Grant.

  18. Energy harvesting from wood floor vibration using a piezoelectric generator

    Science.gov (United States)

    Jiangming Kan; Robert J. Ross; Xiping Wang; Wenbin Li

    2017-01-01

    Vibration can occur in wood floor systems as a consequence of a variety of human activities, ranging from common daily movements associated with individuals living in homes to high-intensity activities associated with sporting events that are held in large sports arenas. For example, the potential for harvesting energy from a wooden floor system in public buildings...

  19. An implantable fluidic vibrational energy harvester

    Science.gov (United States)

    Inoue, S.; Takahashi, T.; Kumemura, M.; Fujita, H.; Toshiyoshi, H.

    2016-11-01

    Targeting implantable medical devices such as respiratory pace-maker, we have developed a proof-of-concept level energy harvester device that could earn electric power of 44 μW/cm2 by the fluidic motion in a PDMS microchannel placed on a silicon substrate with built-in permanent electrical charges or so-called electrets. The motion of the working fluid will be operated by the heart beat or breathing as a final shape of the energy harvesting system.

  20. Electrostatic polarization makes a substantial contribution to the free energy of avidin-biotin binding.

    Science.gov (United States)

    Tong, Yan; Mei, Ye; Li, Yong L; Ji, Chang G; Zhang, John Z H

    2010-04-14

    Avidin-biotin is one of the strongest protein-ligand binding systems, with broad applications in biomedical science. Here we report a quantum-based computational study to help elucidate the mechanism of binding avidin to biotin (BTN1) and its close analogue, 2'-iminobiotin (BTN2). Our study reveals that electronic polarization of protein plays a critical role in stabilizing the beta sheet (Thr113-Arg122) at the binding site and makes a substantial contribution to the free energy of avidin-biotin binding. The current finding is in contradiction to the previous notion that electrostatic interaction has no effect on or makes an unfavorable contribution to the free energy of avidin-biotin binding. Our calculations also show that the difference in binding free energy of avidin to BTN1 and BTN2 is almost entirely due to the contribution of electrostatic interaction resulting from polarization-induced stabilization of a hydrogen bond between avidin and BTN1. The current result provides strong evidence that protein polarization accounts for the electrostatic contribution to binding free energy that was missing in previous studies of avidin-biotin binding.

  1. Rotor position and vibration control for aerospace flywheel energy storage devices and other vibration based devices

    Science.gov (United States)

    Alexander, B. X. S.

    Flywheel energy storage has distinct advantages over conventional energy storage methods such as electrochemical batteries. Because the energy density of a flywheel rotor increases quadratically with its speed, the foremost goal in flywheel design is to achieve sustainable high speeds of the rotor. Many issues exist with the flywheel rotor operation at high and varying speeds. A prominent problem is synchronous rotor vibration, which can drastically limit the sustainable rotor speed. In a set of projects, the novel Active Disturbance Rejection Control (ADRC) is applied to various problems of flywheel rotor operation. These applications include rotor levitation, steady state rotation at high speeds and accelerating operation. Several models such as the lumped mass model and distributed three-mass models have been analyzed. In each of these applications, the ADRC has been extended to cope with disturbance, noise, and control effort optimization; it also has been compared to various industry-standard controllers such as PID and PD/observer, and is proven to be superior. The control performance of the PID controller and the PD/observer currently used at NASA Glenn has been improved by as much as an order of magnitude. Due to the universality of the second order system, the results obtained in the rotor vibration problem can be straightforwardly extended to other vibrational systems, particularly, the MEMS gyroscope. Potential uses of a new nonlinear controller, which inherits the ease of use of the traditional PID, are also discussed.

  2. Energy Harvesting from Mechanical Shocks Using a Sensitive Vibration Energy Harvester

    Directory of Open Access Journals (Sweden)

    Zdenek Hadas

    2012-11-01

    Full Text Available This paper deals with a unique principle of energy harvesting technologies. An energy harvesting device generates electric energy from its surroundings using some kind of energy conversion method. Therefore, the considered energy harvesting device does not consume any fuel or substance. The presented energy harvesting system is used forenergy harvesting of electrical energy from mechanical shocks. The presented energy harvesting system uses a very sensitive vibration energy harvester, which was developed for an aeronautic application at Brno University of Technology. This energy harvesting system is a complex mechatronic device, which consists of a precise mechanical part, an electromagnetic converter, power electronics (power management and a load (e.g., wireless sensor. The very sensitive vibration energy harvester is capable of usingthe mechanical energy of mechanical shocks and it can harvest useful energy. This energy harvesting system is used with a wireless temperature sensor and measured results are presented in this paper.

  3. Multistable chain for ocean wave vibration energy harvesting

    Science.gov (United States)

    Harne, R. L.; Schoemaker, M. E.; Wang, K. W.

    2014-03-01

    The heaving of ocean waves is a largely untapped, renewable kinetic energy resource. Conversion of this energy into electrical power could integrate with solar technologies to provide for round-the-clock, portable, and mobile energy supplies usable in a wide variety of marine environments. However, the direct drive conversion methodology of gridintegrated wave energy converters does not efficiently scale down to smaller, portable architectures. This research develops an alternative power conversion approach to harness the extraordinarily large heaving displacements and long oscillation periods as an excitation source for an extendible vibration energy harvesting chain. Building upon related research findings and engineering insights, the proposed system joins together a series of dynamic cells through bistable interfaces. Individual impulse events are generated as the inertial mass of each cell is pulled across a region of negative stiffness to induce local snap through dynamics; the oscillating magnetic inertial mass then generates current in a coil which is connected to energy harvesting circuitry. It is shown that linking the cells into a chain transmits impulses through the system leading to cascades of vibration and enhancement of electrical energy conversion from each impulse event. This paper describes the development of the multistable chain and ways in which realistic design challenges were addressed. Numerical modeling and corresponding experiments demonstrate the response of the chain due to slow and large amplitude input motion. Lastly, experimental studies give evidence that energy conversion efficiency of the chain for wave energy conversion is much higher than using an equal number of cells without connections.

  4. Energy expenditure and substrate utilization during whole body vibration

    Directory of Open Access Journals (Sweden)

    Ravena Santos Raulino

    2015-04-01

    Full Text Available INTRODUCTION AND OBJECTIVE: the aim of this study was to investigate whether the addition of vibration during interval training would raise oxygen consumption VO2 to the extent necessary for weight management and to evaluate the influence of the intensity of the vibratory stimulus for prescribing the exercise program in question. METHODS: VO2, measured breath by breath, was evaluated at rest and during the four experimental conditions to determine energy expenditure, metabolic equivalent MET, respiratory exchange ratio RER, % Kcal from fat, and rate of fat oxidation. Eight young sedentary females age 22±1 years, height 163.88± 7.62 cm, body mass 58.35±10.96 kg, and VO2 max 32.75±3.55 mLO2.Kg-1.min-1 performed interval training duration = 13.3 min to the upper and lower limbs both with vibration 35 Hz and 2 mm, 40 Hz and 2 mm, 45 Hz and 2 mm and without vibration. The experimental conditions were randomized and balanced at an interval of 48 hours. RESULTS: the addition of vibration to exercise at 45 Hz and 2 mm resulted in an additional increase of 17.77±12.38% of VO2 compared with exercise without vibration. However, this increase did not change the fat oxidation rate p=0.42 because intensity of exercise 29.1±3.3 %VO2max, 2.7 MET was classified as mild to young subjects. CONCLUSION: despite the influence of vibration on VO2 during exercise, the increase was insufficient to reduce body weight and did not reach the minimum recommendation of exercise prescription for weight management for the studied population.

  5. Accurate ab initio vibrational energies of methyl chloride

    Energy Technology Data Exchange (ETDEWEB)

    Owens, Alec, E-mail: owens@mpi-muelheim.mpg.de [Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany); Department of Physics and Astronomy, University College London, Gower Street, WC1E 6BT London (United Kingdom); Yurchenko, Sergei N.; Yachmenev, Andrey; Tennyson, Jonathan [Department of Physics and Astronomy, University College London, Gower Street, WC1E 6BT London (United Kingdom); Thiel, Walter [Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany)

    2015-06-28

    Two new nine-dimensional potential energy surfaces (PESs) have been generated using high-level ab initio theory for the two main isotopologues of methyl chloride, CH{sub 3}{sup 35}Cl and CH{sub 3}{sup 37}Cl. The respective PESs, CBS-35{sup  HL}, and CBS-37{sup  HL}, are based on explicitly correlated coupled cluster calculations with extrapolation to the complete basis set (CBS) limit, and incorporate a range of higher-level (HL) additive energy corrections to account for core-valence electron correlation, higher-order coupled cluster terms, scalar relativistic effects, and diagonal Born-Oppenheimer corrections. Variational calculations of the vibrational energy levels were performed using the computer program TROVE, whose functionality has been extended to handle molecules of the form XY {sub 3}Z. Fully converged energies were obtained by means of a complete vibrational basis set extrapolation. The CBS-35{sup  HL} and CBS-37{sup  HL} PESs reproduce the fundamental term values with root-mean-square errors of 0.75 and 1.00 cm{sup −1}, respectively. An analysis of the combined effect of the HL corrections and CBS extrapolation on the vibrational wavenumbers indicates that both are needed to compute accurate theoretical results for methyl chloride. We believe that it would be extremely challenging to go beyond the accuracy currently achieved for CH{sub 3}Cl without empirical refinement of the respective PESs.

  6. Magnetostrictive Vibration Damper and Energy Harvester for Rotating Machinery

    Science.gov (United States)

    Deng, Zhangxian; Asnani, Vivake M.; Dapino, Marcelo J.

    2015-01-01

    Vibrations generated by machine driveline components can cause excessive noise and structural damage. Magnetostrictive materials, including Galfenol (iron-gallium alloys) and Terfenol-D (terbium-iron-dysprosium alloys), are able to convert mechanical energy to magnetic energy. A magnetostrictive vibration ring is proposed, which generates electrical energy and dampens vibration, when installed in a machine driveline. A 2D axisymmetric finite element (FE) model incorporating magnetic, mechanical, and electrical dynamics is constructed in COMSOL Multiphysics. Based on the model, a parametric study considering magnetostrictive material geometry, pickup coil size, bias magnet strength, flux path design, and electrical load is conducted to maximize loss factor and average electrical output power. By connecting various resistive loads to the pickup coil, the maximum loss factors for Galfenol and Terfenol-D due to electrical energy loss are identified as 0.14 and 0.34, respectively. The maximum average electrical output power for Galfenol and Terfenol-D is 0.21 W and 0.58 W, respectively. The loss factors for Galfenol and Terfenol-D are increased to 0.59 and 1.83, respectively, by using an L-C resonant circuit.

  7. An Electromagnetic MEMS Energy Harvester Array with Multiple Vibration Modes

    Directory of Open Access Journals (Sweden)

    Huicong Liu

    2015-07-01

    Full Text Available This paper reports the design, micromachining and characterization of an array of electromagnetic energy harvesters (EHs with multiple frequency peaks. The authors present the combination of three multi-modal spring-mass structures so as to realize at least nine resonant peaks within a single microelectromechanical systems (MEMS chip. It is assembled with permanent magnet to show an electromagnetic-based energy harvesting capability. This is the first demonstration of multi-frequency MEMS EH existing with more than three resonant peaks within a limited frequency range of 189 to 662 Hz. It provides a more effective approach to harvest energy from the vibration sources of multiple frequency peaks.

  8. Harvesting Energy from Vibrations of the Underlying Structure

    DEFF Research Database (Denmark)

    Han, Bo; Vssilaras, S; Papadias, C.B.

    2013-01-01

    The use of wireless sensors for structural health monitoring offers several advantages such as small size, easy installation and minimal intervention on existing structures. However the most significant concern about such wireless sensors is the lifetime of the system, which depends heavily on th...... an improved Maximum Power Point Tracking technique on the conversion circuit, the proposed method is shown to maximize the conversion coefficient from kinetic energy to applicable electrical energy....... emerges as a technique that can harvest energy from the surrounding environment. Among all possible energy harvesting solutions, kinetic energy harvesting seems to be the most convenient, especially for sensors placed on structures that experience regular vibrations. Such micro-vibrations can be harmful...... on the type of power supply. No matter how energy efficient the operation of a battery operated sensor is, the energy of the battery will be exhausted at some point. In order to achieve a virtually unlimited lifetime, the sensor node should be able to recharge its battery in an easy way. Energy harvesting...

  9. Student reasoning about electrostatic and gravitational potential energy: An exploratory study with interdisciplinary consequences

    Directory of Open Access Journals (Sweden)

    Beth A. Lindsey

    2014-01-01

    Full Text Available This paper describes an investigation into student reasoning about potential energy in the context of introductory electrostatics. Similar incorrect reasoning patterns emerged both in written questions administered after relevant instruction and in one-on-one interviews. These reasoning patterns are also prevalent in responses to questions posed about gravitational potential energy in the context of universal gravitation in introductory mechanics. This finding is relevant for interdisciplinary research, because many courses in multiple disciplines first introduce the concept of electric potential energy in analogy to gravitational potential energy. The results suggest that in introductory courses students do not gain an understanding of potential energy that is sufficiently robust to apply in more advanced physics courses or in disciplines other than physics, in which students must frequently reason with energy in the context of interactions between atoms and molecules.

  10. Minimization of the Vibration Energy of Thin-Plate Structures and the Application to the Reduction of Gearbox Vibration

    Science.gov (United States)

    Inoue, Katsumi; Krantz, Timothy L.

    1995-01-01

    While the vibration analysis of gear systems has been developed, a systematic approach to the reduction of gearbox vibration has been lacking. The technique of reducing vibration by shifting natural frequencies is proposed here for gearboxes and other thin-plate structures using the theories of finite elements, modal analysis, and optimization. A triangular shell element with 18 degrees of freedom is developed for structural and dynamic analysis. To optimize, the overall vibration energy is adopted as the objective function to be minimized at the excitation frequency by varying the design variable (element thickness) under the constraint of overall constant weight. Modal analysis is used to determine the sensitivity of the vibration energy as a function of the eigenvalues and eigenvectors. The optimum design is found by the gradient projection method and a unidimensional search procedure. By applying the computer code to design problems for beams and plates, it was verified that the proposed method is effective in reducing vibration energy. The computer code is also applied to redesign the NASA Lewis gear noise rig test gearbox housing. As one example, only the shape of the top plate is varied, and the vibration energy levels of all the surfaces are reduced, yielding an overall reduction of 1/5 compared to the initial design. As a second example, the shapes of the top and two side plates are varied to yield an overall reduction in vibration energy of 1/30.

  11. Electrostatic free energy of weakly charged macromolecules in solution and intermacromolecular complexes consisting of oppositely charged polymers

    NARCIS (Netherlands)

    Biesheuvel, P.M.; Cohen Stuart, M.A.

    2004-01-01

    When oppositely charged polyelectrolytes are mixed in water, attraction between oppositely charged groups may lead to the formation of polyelectrolyte complexes (associative phase separation, complex coacervation, interpolymer complexes). Theory is presented to describe the electrostatic free energy

  12. Electrostatic model of the energy-bending within organic semiconductors: experiment and simulation.

    Science.gov (United States)

    Whitcher, T J; Wong, W S; Talik, A N; Woon, K L; Chanlek, N; Nakajima, H; Saisopa, T; Songsiriritthigul, P

    2016-09-14

    The interfacial properties between electrodes and the various organic layers that comprise an organic electronic device are of direct relevance in understanding charge injection, extraction and generation. The energy levels and energy-bending of three interfaces; indium tin oxide (ITO)/poly(3,4-ethylenedioxythiophene) polystyrene sulfonate ( PSS), ITO/poly(N-vinylcarbazole) (PVK) and PSS/PVK were measured using ultraviolet photoelectron spectroscopy (UPS) and x-ray photoelectron spectroscopy (XPS). By decoupling the vacuum shift and energy-bending, the energy-bending at these interfaces can be simulated using an electrostatic model that takes into account the energetic disorder of the polymers. The model is further extended to include blended mixtures of semiconductors at differing concentrations and it was found that a very good agreement exists between the experiment and theory for all interfaces. This suggests that the electrostatic model can be used to describe energy-bending at the interface between any organic semiconductors. Further investigation into the effect of the Gaussian density of states width on energy-bending is warranted.

  13. DESIREE A Double Electrostatic Storage Ring for Low Energy Ion-Ion Collisions

    CERN Document Server

    Liljeby, Leif; Bagge, Lars; Blom, Mikael; Cederquist, Henrik; Danared, Håkan; Källberg, Anders; Larsson, Mats; Leontein, Sven; Löfgren, Patrik; Paal, Andras; Rensfelt, Karl-Gunnar; Schmidt, Henning T; Schmidt, Kjell; Simonsson, Ansgar; Skeppstedt, Örjan

    2005-01-01

    The advantages of storage rings with only electrostatic elements were first demonstrated in ELISA at Aarhus University and later in other places. At MSL and the Physics Department at Stockholm University the ideas have been developed further in the Double Electrostatic Storage Ion Ring ExpEriment, DESIREE. Beams of negative and positive atomic or molecular ions will be merged in a common straight section of two storage rings for studies of low energy collisions. The whole system may be cooled to below 20 K in order to relax internal excitations in stored molecules. This project is now fully financed and the final design work is in progress. A status report will be given in this paper together with a brief review of the planned physics program.

  14. Solid-state energetics and electrostatics: Madelung constants and Madelung energies.

    Science.gov (United States)

    Glasser, Leslie

    2012-02-20

    The Madelung constants of ionic solids relate to their geometry and electrostatic interactions. Furthermore, because of issues in their evaluation, they are also of considerable mathematical interest. The corresponding Madelung (electrostatic, coulomb) energy is the principal contributor to the lattice energies of ionic systems, and these energies largely influence many of their physical properties. The Madelung constants are here defined and their properties considered. A difficulty with their application is that they may be defined relative to various lattice distances, and with various conventions for inclusion of the charges, leading to possible confusion in their use. Instead, the unambiguous Madelung energy, E(M), is to be preferred in chemistry. An extensive list of Madelung energies is presented. From this data set, it is observed that there is a strong linear correlation between the lattice energies of ionic solids, U(POT), and their Madelung energies: U(POT)/kJ mol(-1) = 0.8519E(M) + 293.9. This correlation establishes that the lattice energy, U(POT), for ionic solids is about 15% smaller than the attractive Madelung energy, the difference arising from the repulsions unaccounted for by the solely coulombic Madelung energy calculation. Correlations of U(POT) against E(M) for alkali metal hydrides and transition metal compounds, each having considerable covalency, show much reduced Madelung contributions to the lattice energy. These correlations permit ready estimation of lattice energies, and are the first to be based on actual data rather than a broad analysis. The independent volume-based thermodynamic (VBT) method, which relies on a separate correlation with the formula unit volume of the ionic material, complements these correlations.

  15. A review of vibration-based MEMS piezoelectric energy harvesters

    Energy Technology Data Exchange (ETDEWEB)

    Saadon, Salem; Sidek, Othman [Collaborative Microelectronic Design Excellence Center (CEDEC), School of Electrical and Electronic Engineering, Universiti Sains Malaysia, Engineering Campus, 14300 Nibong Tebal, Seberang Perai Selatan, Pulau Pinang (Malaysia)

    2011-01-15

    The simplicity associated with the piezoelectric micro-generators makes it very attractive for MEMS applications, especially for remote systems. In this paper we reviewed the work carried out by researchers during the last three years. The improvements in experimental results obtained in the vibration-based MEMS piezoelectric energy harvesters show very good scope for MEMS piezoelectric harvesters in the field of power MEMS in the near future. (author)

  16. Design and optimization of the electrostatic input module for the ISTTOK Tokamak HIBD cylindrical energy analyzer

    Science.gov (United States)

    Sharma, R.; Nedzelskiy, I. S.; Malaquias, A.; Henriques, R. B.

    2017-11-01

    The Heavy Ion Beam Diagnostic of the ISTTOK Tokamak is based on the injection of a single ionized primary beam (Xe+, Cs+) of energy 20–25 keV and on the collection of all doubly ionized ions emerging from the primary beam due to the impact ionization with the plasma electrons. In the present configuration three local plasma parameters can be retrieved: plasma density (ne), electron temperature (Te), and poloidal magnetic field (Bp). A new detection system is being design in order to determine the plasma potential (Vp) profile via the secondary ions energy measurements. To that end an improved 90o cylindrical electrostatic analyzer (CEA) has been designed and optimized to measure the energy of the secondary ions. This paper reports on the design optimization of the input stage of the new detection arrangement to guide and shape 4 secondary beams into the entrance of the CEA. It is composed of a set of four electrostatic cylindrical plates followed by four pairs of steering plates and a multiple aperture Einzel-like electrostatic lens, consisting of four planar vertical electrodes containing four passing slits. Individual secondary beams with dimension of 8 mm × 2.5 mm were obtained without overlapping between the four beams from different slits. By changing the incident beam energy from 20 keV to 20.2 keV (in order to simulate a local plasma potential value of +200 V), without adjusting bias voltage of the input system, results in a vertical beam shift of 1 mm which can be recovered by changing the voltage on the parallel plate arrangement by 40 V. The flexibility and tolerance of the optic system was tested successfully for the expected angular uncertainty of the beam by +/‑0.5o at the input module entrance and with the expected energy spread of the beam corresponding to different plasma positions inside the tokamak.

  17. Internal resonance and low frequency vibration energy harvesting

    Science.gov (United States)

    Yang, Wei; Towfighian, Shahrzad

    2017-09-01

    A nonlinear vibration energy harvester with internal resonance is presented. The proposed harvester consists of two cantilevers, each with a permanent magnet on its tip. One cantilever has a piezoelectric layer at its base. When magnetic force is applied this two degrees-of-freedom nonlinear vibration system shows the internal resonance phenomenon that broadens the frequency bandwidth compared to a linear system. Three coupled partial differential equations are obtained to predict the dynamic behavior of the nonlinear energy harvester. The perturbation method of multiple scales is used to solve equations. Results from experiments done at different vibration levels with varying distances between the magnets validate the mathematical model. Experiments and simulations show the design outperforms the linear system by doubling the frequency bandwidth. Output voltage for frequency response is studied for different system parameters. The optimal load resistance is obtained for the maximum power in the internal resonance case. The results demonstrate that a design combining internal resonance and magnetic nonlinearity improves the efficiency of energy harvesting.

  18. On the Energy Conversion Efficiency of Piezoelectric Vibration Energy Harvesting Devices

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jae Eun [Catholic University of Daegu, Kyungsan (Korea, Republic of)

    2015-05-15

    To properly design and assess a piezoelectric vibration energy harvester, it is necessary to consider the application of an efficiency measure of energy conversion. The energy conversion efficiency is defined in this work as the ratio of the electrical output power to the mechanical input power for a piezoelectric vibration energy harvester with an impedance-matched load resistor. While previous research works employed the electrical output power for approximate impedance-matched load resistance, this work derives an efficiency measure considering optimally matched resistance. The modified efficiency measure is validated by comparing it with finite element analysis results for piezoelectric vibration energy harvesters with three different values of the electro-mechanical coupling coefficient. New findings on the characteristics of energy conversion and conversion efficiency are also provided for the two different impedance matching methods.

  19. MEMS-based thick film PZT vibrational energy harvester

    DEFF Research Database (Denmark)

    Lei, Anders; Xu, Ruichao; Thyssen, Anders

    2011-01-01

    We present a MEMS-based unimorph silicon/PZT thick film vibrational energy harvester with an integrated proof mass. We have developed a process that allows fabrication of high performance silicon based energy harvesters with a yield higher than 90%. The process comprises a KOH etch using...... a mechanical front side protection of an SOI wafer with screen printed PZT thick film. The fabricated harvester device produces 14.0 μW with an optimal resistive load of 100 kΩ from 1g (g=9.81 m s-2) input acceleration at its resonant frequency of 235 Hz....

  20. Energy harvesting from structural vibrations of magnetic shape memory alloys

    Science.gov (United States)

    Farsangi, Mohammad Amin Askari; Cottone, Francesco; Sayyaadi, Hassan; Zakerzadeh, Mohammad Reza; Orfei, Francesco; Gammaitoni, Luca

    2017-03-01

    This letter presents the idea of scavenging energy from vibrating structures through magnetic shape memory alloy (MSMA). To this end, a MSMA specimen made of Ni50Mn28Ga22 is coupled to a cantilever beam through a step. Two permanent magnets installed at the top and bottom of the beam create a bias field perpendicular to the magnetization axis of the specimen. When vibrating the device, a longitudinal axial load applies on the MSMA, which in turn changes the magnetization, due to the martensitic variant reorientation mechanism. A pick-up coil wounded around the MSMA converts this variation into voltage according to the Faraday's law. Experimental test confirms the possibility of generating voltage in a vibrating MSMA. In particular, 15 μW power is harvested for acceleration of 0.3 g RMS at a frequency of 19.1 Hz, which is comparable with piezoelectric energy harvesters. It is also found that the optimum bias magnetic field for maximum voltage is lower than the starting field of pseudo elastic behavior.

  1. Analyses of electromagnetic and piezoelectric systems for efficient vibration energy harvesting

    Science.gov (United States)

    Hadas, Z.; Smilek, J.; Rubes, O.

    2017-05-01

    The paper deals with analyses and evaluation of vibration energy harvesting systems which are based on electromagnetic and piezoelectric physical principles off electro-mechanical conversion. Energy harvesting systems are associated with wireless sensors and a monitoring of engineering objects. The most of engineering objects operate with unwanted mechanical vibrations. However, vibrations could provide an ambient source of energy which is converted into useful electricity. The use of electromagnetic and piezoelectric vibration energy harvesters is analyzed in this paper. Thee evaluated output power is used for a choice of the efficient system with respect to the character of vibrations and thee required power output.

  2. Fusion energy in an inertial electrostatic confinement device using a magnetically shielded grid

    Energy Technology Data Exchange (ETDEWEB)

    Hedditch, John, E-mail: john.hedditch@sydney.edu.au; Bowden-Reid, Richard, E-mail: rbow3948@physics.usyd.edu.au; Khachan, Joe, E-mail: joe.khachan@sydney.edu.au [School of Physics, The University of Sydney, Sydney, New South Whales 2006 (Australia)

    2015-10-15

    Theory for a gridded inertial electrostatic confinement (IEC) fusion system is presented, which shows a net energy gain is possible if the grid is magnetically shielded from ion impact. A simplified grid geometry is studied, consisting of two negatively biased coaxial current-carrying rings, oriented such that their opposing magnetic fields produce a spindle cusp. Our analysis indicates that better than break-even performance is possible even in a deuterium-deuterium system at bench-top scales. The proposed device has the unusual property that it can avoid both the cusp losses of traditional magnetic fusion systems and the grid losses of traditional IEC configurations.

  3. Electron transfer energies and dipole moments of alkyl halides and amines from an electrostatic model

    Science.gov (United States)

    Applequist, Jon; Felder, Clifford E.

    1981-08-01

    Energies of the electron transfer reaction CH3X+RX+→CH3X++RX and dipole moments of molecules RX, where R is an alkyl group and X = Cl, Br, I, or NH2, are calculated for an electrostatic model in which each atom is characterized by a fixed charge and polarizability located at the position of the nucleus. The calculation takes into account the mutual polarization of the atoms in the molecular field. Atom polarizabilities are obtained from previous applications of the atom-dipole interaction model to molecular polarizabilities. Atom charges are assumed to be nonzero only for X and Cα, and these are optimized to fit 13 experimental electron transfer energies from first ionization potentials and 17 gas-phase dipole moments for selected alkyl compounds. Energies of 19 transfer reactions and dipole moments of 29 molecules are calculated, showing satisfactory overall agreement with experiment. The results suggest that the electrostatic interaction of the fixed charges with the polarizable atoms is responsible for the trend toward decreasing ionization potential with increasing size of the R group.

  4. Efficiency Enhancement of a Cantilever-Based Vibration Energy Harvester

    Directory of Open Access Journals (Sweden)

    Ali E. Kubba

    2013-12-01

    Full Text Available Extracting energy from ambient vibration to power wireless sensor nodes has been an attractive area of research, particularly in the automotive monitoring field. This article reports the design, analysis and testing of a vibration energy harvesting device based on a miniature asymmetric air-spaced cantilever. The developed design offers high power density, and delivers electric power that is sufficient to support most wireless sensor nodes for structural health monitoring (SHM applications. The optimized design underwent three evolutionary steps, starting from a simple cantilever design, going through an air-spaced cantilever, and ending up with an optimized air-spaced geometry with boosted power density level. Finite Element Analysis (FEA was used as an initial tool to compare the three geometries’ stiffness (K, output open-circuit voltage (Vave, and average normal strain in the piezoelectric transducer (εave that directly affect its output voltage. Experimental tests were also carried out in order to examine the energy harvesting level in each of the three designs. The experimental results show how to boost the power output level in a thin air-spaced cantilever beam for energy within the same space envelope. The developed thin air-spaced cantilever (8.37 cm3, has a maximum power output of 2.05 mW (H = 29.29 μJ/cycle.

  5. Efficiency enhancement of a cantilever-based vibration energy harvester.

    Science.gov (United States)

    Kubba, Ali E; Jiang, Kyle

    2013-12-23

    Extracting energy from ambient vibration to power wireless sensor nodes has been an attractive area of research, particularly in the automotive monitoring field. This article reports the design, analysis and testing of a vibration energy harvesting device based on a miniature asymmetric air-spaced cantilever. The developed design offers high power density, and delivers electric power that is sufficient to support most wireless sensor nodes for structural health monitoring (SHM) applications. The optimized design underwent three evolutionary steps, starting from a simple cantilever design, going through an air-spaced cantilever, and ending up with an optimized air-spaced geometry with boosted power density level. Finite Element Analysis (FEA) was used as an initial tool to compare the three geometries' stiffness (K), output open-circuit voltage (V(ave)), and average normal strain in the piezoelectric transducer (ε(ave)) that directly affect its output voltage. Experimental tests were also carried out in order to examine the energy harvesting level in each of the three designs. The experimental results show how to boost the power output level in a thin air-spaced cantilever beam for energy within the same space envelope. The developed thin air-spaced cantilever (8.37 cm3), has a maximum power output of 2.05 mW (H = 29.29 μJ/cycle).

  6. Fundamental issues in nonlinear wideband-vibration energy harvesting.

    Science.gov (United States)

    Halvorsen, Einar

    2013-04-01

    Mechanically nonlinear energy harvesters driven by broadband vibrations modeled as white noise are investigated. We derive an upper bound on output power versus load resistance and show that, subject to mild restrictions that we make precise, the upper-bound performance can be obtained by a linear harvester with appropriate stiffness. Despite this, nonlinear harvesters can have implementation-related advantages. Based on the Kramers equation, we numerically obtain the output power at weak coupling for a selection of phenomenological elastic potentials and discuss their merits.

  7. Design aspects of an electrostatic electron cooler for low-energy RHIC operation

    Energy Technology Data Exchange (ETDEWEB)

    Fedotov, A.; Ben-Zvi, I.; Brodowski, J.; Chang, X.Y.; Gassner, D.; Hoff, L.; Kayran, D.; Kewisch, J.; Oerter, B.; Pendzick, A.; Tepikian, S.; Thieberger, P.; Prost, L.; Shemyakin, A.

    2011-03-28

    Electron cooling was proposed to increase the luminosity of the Relativistic Heavy Ion Collider (RHIC) operation for heavy ion beam energies below 10 GeV/nucleon. The electron cooling system needed should be able to deliver an electron beam of adequate quality in a wide range of electron beam energies (0.9-5 MeV). An option of using an electrostatic accelerator to produce electrons for cooling heavy ions in RHIC was evaluated in detail. In this paper, we describe the requirements and options which were considered in the design of such a cooler for RHIC, as well as the associated challenges. The expected luminosity improvement and limitations with such an electron cooling system are also discussed.

  8. Global Nonlinear Analysis of Piezoelectric Energy Harvesting from Ambient and Aeroelastic Vibrations

    Science.gov (United States)

    Abdelkefi, Abdessattar

    Converting vibrations to a usable form of energy has been the topic of many recent investigations. The ultimate goal is to convert ambient or aeroelastic vibrations to operate low-power consumption devices, such as microelectromechanical systems, heath monitoring sensors, wireless sensors or replacing small batteries that have a finite life span or would require hard and expensive maintenance. The transduction mechanisms used for transforming vibrations to electric power include: electromagnetic, electrostatic, and piezoelectric mechanisms. Because it can be used to harvest energy over a wide range of frequencies and because of its ease of application, the piezoelectric option has attracted significant interest. In this work, we investigate the performance of different types of piezoelectric energy harvesters. The objective is to design and enhance the performance of these harvesters. To this end, distributed-parameter and phenomenological models of these harvesters are developed. Global analysis of these models is then performed using modern methods of nonlinear dynamics. In the first part of this Dissertation, global nonlinear distributed-parameter models for piezoelectric energy harvesters under direct and parametric excitations are developed. The method of multiple scales is then used to derive nonlinear forms of the governing equations and associated boundary conditions, which are used to evaluate their performance and determine the effects of the nonlinear piezoelectric coefficients on their behavior in terms of softening or hardening. In the second part, we assess the influence of the linear and nonlinear parameters on the dynamic behavior of a wing-based piezoaeroelastic energy harvester. The system is composed of a rigid airfoil that is constrained to pitch and plunge and supported by linear and nonlinear torsional and flexural springs with a piezoelectric coupling attached to the plunge degree of freedom. Linear analysis is performed to determine the

  9. Vibrational Stark Effect of the Electric-Field Reporter 4-Mercaptobenzonitrile as a Tool for Investigating Electrostatics at Electrode/SAM/Solution Interfaces

    Directory of Open Access Journals (Sweden)

    Peter Hildebrandt

    2012-06-01

    Full Text Available 4-mercaptobenzonitrile (MBN in self-assembled monolayers (SAMs on Au and Ag electrodes was studied by surface enhanced infrared absorption and Raman spectroscopy, to correlate the nitrile stretching frequency with the local electric field exploiting the vibrational Stark effect (VSE. Using MBN SAMs in different metal/SAM interfaces, we sorted out the main factors controlling the nitrile stretching frequency, which comprise, in addition to external electric fields, the metal-MBN bond, the surface potential, and hydrogen bond interactions. On the basis of the linear relationships between the nitrile stretching and the electrode potential, an electrostatic description of the interfacial potential distribution is presented that allows for determining the electric field strengths on the SAM surface, as well as the effective potential of zero-charge of the SAM-coated metal. Comparing this latter quantity with calculated values derived from literature data, we note a very good agreement for Au/MBN but distinct deviations for Ag/MBN which may reflect either the approximations and simplifications of the model or the uncertainty in reported structural parameters for Ag/MBN. The present electrostatic model consistently explains the electric field strengths for MBN SAMs on Ag and Au as well as for thiophenol and mercaptohexanoic acid SAMs with MBN incorporated as a VSE reporter.

  10. Electrostatically frequency tunable micro-beam-based piezoelectric fluid flow energy harvester

    Science.gov (United States)

    Rezaee, Mousa; Sharafkhani, Naser

    2017-07-01

    This research investigates the dynamic behavior of a sandwich micro-beam based piezoelectric energy harvester with electrostatically adjustable resonance frequency. The system consists of a cantilever micro-beam immersed in a fluid domain and is subjected to the simultaneous action of cross fluid flow and nonlinear electrostatic force. Two parallel piezoelectric laminates are extended along the length of the micro-beam and connected to an external electric circuit which generates an output power as a result of the micro-beam oscillations. The fluid-coupled structure is modeled using Euler-Bernoulli beam theory and the equivalent force terms for the fluid flow. Fluid induced forces comprise the added inertia force which is evaluated using equivalent added mass and the drag and lift forces which are evaluated using relative velocity and Van der Pol equation. In addition to flow velocity and fluid density, the influence of several design parameters such as external electrical resistance, piezo layer position, and dc voltage on the generated power are investigated by using Galerkin and step by step linearization method. It is shown that for given flowing fluid parameters, i.e., density and velocity, one can adjust the applied dc voltage to tune resonance frequency so that the lock-in phenomenon with steady large amplitude oscillations happens, also by adjusting the harvester parameters including the mechanical and electrical ones, the maximal output power of the harvester becomes possible.

  11. A nonlinear MEMS electrostatic kinetic energy harvester for human-powered biomedical devices

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Y.; Cottone, F.; Marty, F.; Basset, P., E-mail: p.basset@esiee.fr [Université Paris-Est/ESYCOM/ESIEE Paris, Noisy-le-Grand 93162 (France); Boisseau, S. [CEA, Leti, Minatec Campus, Grenoble 38054 (France); Galayko, D. [UPMC-Sorbonne Université/LIP 6, CNRS, Paris 75005 (France)

    2015-12-21

    This article proposes a silicon-based electrostatic kinetic energy harvester with an ultra-wide operating frequency bandwidth from 1 Hz to 160 Hz. This large bandwidth is obtained, thanks to a miniature tungsten ball impacting with a movable proof mass of silicon. The motion of the silicon proof mass is confined by nonlinear elastic stoppers on the fixed part standing against two protrusions of the proof mass. The electrostatic transducer is made of interdigited-combs with a gap-closing variable capacitance that includes vertical electrets obtained by corona discharge. Below 10 Hz, the e-KEH offers 30.6 nJ per mechanical oscillation at 2 g{sub rms}, which makes it suitable for powering biomedical devices from human motion. Above 10 Hz and up to 162 Hz, the harvested power is more than 0.5 μW with a maximum of 4.5 μW at 160 Hz. The highest power of 6.6 μW is obtained without the ball at 432 Hz, in accordance with a power density of 142 μW/cm{sup 3}. We also demonstrate the charging of a 47-μF capacitor to 3.5 V used to power a battery-less wireless temperature sensor node.

  12. Driven diffusion against electrostatic or effective energy barrier across α-hemolysin

    Energy Technology Data Exchange (ETDEWEB)

    Ansalone, Patrizio [Istituto Nazionale di Ricerca Metrologica, Strada delle Cacce 91, Torino, IT-10135 (Italy); Chinappi, Mauro [Center for Life Nano Science@Sapienza, Istituto Italiano di Tecnologia, Via Regina Elena 291, 00161 Roma (Italy); Rondoni, Lamberto [Scienze Matematiche, Politecnico di Torino Corso Duca degli Abruzzi 24, Torino, IT-10129, Italy and INFN, Sez. di Torino, Via P. Giuria 1, Torino IT-10125 (Italy); Cecconi, Fabio, E-mail: fabio.cecconi@roma1.infn.it [CNR-Istituto dei Sistemi Complessi UoS “Sapienza,” Via dei Taurini 19, 00185 Roma (Italy)

    2015-10-21

    We analyze the translocation of a charged particle across an α-Hemolysin (αHL) pore in the framework of a driven diffusion over an extended energy barrier generated by the electrical charges of the αHL. A one-dimensional electrostatic potential is extracted from the full 3D solution of the Poisson’s equation. We characterize the particle transport under the action of a constant forcing by studying the statistics of the translocation time. We derive an analytical expression of translocation time average that compares well with the results from Brownian dynamic simulations of driven particles over the electrostatic potential. Moreover, we show that the translocation time distributions can be perfectly described by a simple theory which replaces the true barrier by an equivalent structureless square barrier. Remarkably, our approach maintains its accuracy also for low-applied voltage regimes where the usual inverse-Gaussian approximation fails. Finally, we discuss how the comparison between the simulated time distributions and their theoretical prediction results to be greatly simplified when using the notion of the empirical Laplace transform technique.

  13. Mems-based pzt/pzt bimorph thick film vibration energy harvester

    DEFF Research Database (Denmark)

    Xu, Ruichao; Lei, Anders; Dahl-Petersen, Christian

    2011-01-01

    We describe fabrication and characterization of a significantly improved version of a MEMS-based PZT/PZT thick film bimorph vibration energy harvester with an integrated silicon proof mass. The main advantage of bimorph vibration energy harvesters is that strain energy is not lost in mechanical...

  14. Vibration properties of and power harvested by a system of electromagnetic vibration energy harvesters that have electrical dynamics

    Science.gov (United States)

    Cooley, Christopher G.

    2017-09-01

    This study investigates the vibration and dynamic response of a system of coupled electromagnetic vibration energy harvesting devices that each consist of a proof mass, elastic structure, electromagnetic generator, and energy harvesting circuit with inductance, resistance, and capacitance. The governing equations for the coupled electromechanical system are derived using Newtonian mechanics and Kirchhoff circuit laws for an arbitrary number of these subsystems. The equations are cast in matrix operator form to expose the device's vibration properties. The device's complex-valued eigenvalues and eigenvectors are related to physical characteristics of its vibration. Because the electrical circuit has dynamics, these devices have more natural frequencies than typical electromagnetic vibration energy harvesters that have purely resistive circuits. Closed-form expressions for the steady state dynamic response and average power harvested are derived for devices with a single subsystem. Example numerical results for single and double subsystem devices show that the natural frequencies and vibration modes obtained from the eigenvalue problem agree with the resonance locations and response amplitudes obtained independently from forced response calculations. This agreement demonstrates the usefulness of solving eigenvalue problems for these devices. The average power harvested by the device differs substantially at each resonance. Devices with multiple subsystems have multiple modes where large amounts of power are harvested.

  15. Harvesting vibrational energy due to intermodal systems via nano coated piezo electric devices.

    Science.gov (United States)

    2015-12-01

    Vibrational energy resulting from intermodal transport systems can be recovered through the use of energy harvesting system consisting of PZT piezo electric material as the primary energy harvesting component. The ability of traditional PZT piezo ele...

  16. Dependence of Interaction Free Energy between Solutes on an External Electrostatic Field

    Directory of Open Access Journals (Sweden)

    Pei-Kun Yang

    2013-07-01

    Full Text Available To explore the athermal effect of an external electrostatic field on the stabilities of protein conformations and the binding affinities of protein-protein/ligand interactions, the dependences of the polar and hydrophobic interactions on the external electrostatic field, −Eext, were studied using molecular dynamics (MD simulations. By decomposing Eext into, along, and perpendicular to the direction formed by the two solutes, the effect of Eext on the interactions between these two solutes can be estimated based on the effects from these two components. Eext was applied along the direction of the electric dipole formed by two solutes with opposite charges. The attractive interaction free energy between these two solutes decreased for solutes treated as point charges. In contrast, the attractive interaction free energy between these two solutes increased, as observed by MD simulations, for Eext = 40 or 60 MV/cm. Eext was applied perpendicular to the direction of the electric dipole formed by these two solutes. The attractive interaction free energy was increased for Eext = 100 MV/cm as a result of dielectric saturation. The force on the solutes along the direction of Eext computed from MD simulations was greater than that estimated from a continuum solvent in which the solutes were treated as point charges. To explore the hydrophobic interactions, Eext was applied to a water cluster containing two neutral solutes. The repulsive force between these solutes was decreased/increased for Eext along/perpendicular to the direction of the electric dipole formed by these two solutes.

  17. Smart nanocoated structure for energy harvesting at low frequency vibration

    Science.gov (United States)

    Sharma, Sudhanshu

    Increasing demands of energy which is cleaner and has an unlimited supply has led development in the field of energy harvesting. Piezoelectric materials can be used as a means of transforming ambient vibrations into electrical energy that can be stored and used to power other devices. With the recent surge of micro scale devices, piezoelectric power generation can provide a convenient alternative to traditional power sources. In this research, a piezoelectric power generator composite prototype was developed to maximize the power output of the system. A lead zirconate titanate (PZT) composite structure was formed and mounted on a cantilever bar and was studied to convert vibration energy of the low range vibrations at 30 Hz--1000 Hz. To improve the performance of the PZT, different coatings were made using different percentage of Ferrofluid (FNP) and Zinc Oxide nanoparticles (ZnO) and binder resin. The optimal coating mixture constituent percentage was based on the performance of the composite structure formed by applying the coating on the PZT. The fabricated PZT power generator composite with an effective volume of 0.062 cm3 produced a maximum of 44.5 μW, or 0.717mW/cm3 at its resonant frequency of 90 Hz. The optimal coating mixture had the composition of 59.9%FNP + 40% ZnO + 1% Resin Binder. The coating utilizes the opto-magneto-electrical properties of ZnO and Magnetic properties of FNP. To further enhance the output, the magneto-electric (ME) effect was increased by subjecting the composite to magnetic field where coating acts as a magnetostrictive material. For the effective volume of 0.0062 cm 3, the composite produced a maximum of 68.5 μW, or 1.11mW/cm 3 at its resonant frequency of 90 Hz at 160 gauss. The optimal coating mixture had the composition of 59.9% FNP + 40% ZnO + 1% Resin Binder. This research also focused on improving the efficiency of solar cells by utilizing the magnetic effect along with gas plasma etching to improve the internal reflection

  18. Hierarchical cellulose-derived CNF/CNT composites for electrostatic energy storage

    Science.gov (United States)

    Kuzmenko, V.; Saleem, A. M.; Staaf, H.; Haque, M.; Bhaskar, A.; Flygare, M.; Svensson, K.; Desmaris, V.; Enoksson, P.

    2016-12-01

    Today many applications require new effective approaches for energy delivery on demand. Supercapacitors are viewed as essential energy storage devices that can continuously provide quick energy. The performance of supercapacitors is mostly determined by electrode materials that can store energy via electrostatic charge accumulation. This study presents new sustainable cellulose-derived composite electrodes which consist of carbon nanofibrous (CNF) mats covered with vapor-grown carbon nanotubes (CNTs). The CNF/CNT electrodes have high electrical conductivity and surface area: the two most important features that are responsible for good electrochemical performance of supercapacitor electrodes. The results show that the composite electrodes have fairly high values of specific capacitance (101 F g-1 at 5 mV s-1), energy and power density (10.28 W h kg-1 and 1.99 kW kg-1, respectively, at 1 A g-1) and can retain excellent performance over at least 2000 cycles (96.6% retention). These results indicate that sustainable cellulose-derived composites can be extensively used in the future as supercapacitor electrodes.

  19. Second Energy Variation for Heterogeneous Systems with Electrostatic and Magnetostatic Interaction

    Science.gov (United States)

    Greenfield, Michael; Greenfield, Pavel

    2017-10-01

    Systems carrying electric charges and magnetic dipoles are widespread in nature and applications. Variational principles and methods play key role in modelling these systems, and they have been developed for a couple of centuries (see, Landau, L.D. and Lifshitz, E.M. Electrodynamics of Continuous Media, Pergamon, 1963). Nonetheless, even a quick glance at the literature shows that the variational approach remains unfinished. In particular, in terms of calculus of variations, all the studies are based on the analysis of first energy variations (i.e., analysis of ponderomotive forces and conditions of equilibrium.) The analysis of the second variation, the cornerstone of the stability analysis, is not even touched in a systematic manner. We partially fixed this gap in (Grinfeld, M., Grinfeld, P., A Variational Approach to Electrostatics of Polarizable Heterogeneous Substances, Advances in Mathematical Physics, Article ID 659127, 2015). In this paper, we present corresponding results relating to the problems of plasma physics.

  20. A modal approach to modeling spatially distributed vibration energy dissipation.

    Energy Technology Data Exchange (ETDEWEB)

    Segalman, Daniel Joseph

    2010-08-01

    The nonlinear behavior of mechanical joints is a confounding element in modeling the dynamic response of structures. Though there has been some progress in recent years in modeling individual joints, modeling the full structure with myriad frictional interfaces has remained an obstinate challenge. A strategy is suggested for structural dynamics modeling that can account for the combined effect of interface friction distributed spatially about the structure. This approach accommodates the following observations: (1) At small to modest amplitudes, the nonlinearity of jointed structures is manifest primarily in the energy dissipation - visible as vibration damping; (2) Correspondingly, measured vibration modes do not change significantly with amplitude; and (3) Significant coupling among the modes does not appear to result at modest amplitudes. The mathematical approach presented here postulates the preservation of linear modes and invests all the nonlinearity in the evolution of the modal coordinates. The constitutive form selected is one that works well in modeling spatially discrete joints. When compared against a mathematical truth model, the distributed dissipation approximation performs well.

  1. Vibration Suppression of an Axially Moving String with Transverse Wind Loadings by a Nonlinear Energy Sink

    Directory of Open Access Journals (Sweden)

    Ye-Wei Zhang

    2013-01-01

    Full Text Available Nonlinear targeted energy transfer (TET is applied to suppress the excessive vibration of an axially moving string with transverse wind loads. The coupling dynamic equations used are modeled by a nonlinear energy sink (NES attached to the string to absorb vibrational energy. By a two-term Galerkin procedure, the equations are discretized, and the effects of vibration suppression by numerical methods are demonstrated. Results show that the NES can effectively suppress the vibration of the axially moving string with transverse wind loadings, thereby protecting the string from excessive movement.

  2. Homotopy analysis approach for nonlinear piezoelectric vibration energy harvesting

    Directory of Open Access Journals (Sweden)

    Shahlaei-Far Shahram

    2016-01-01

    Full Text Available Piezoelectric energy harvesting from a vertical geometrically nonlinear cantilever beam with a tip mass subject to transverse harmonic base excitations is analyzed. One piezoelectric patch is placed on the slender beam to convert the tension and compression into electrical voltage. Applying the homotopy analysis method to the coupled electromechanical governing equations, we derive analytical solutions for the horizontal displacement of the tip mass and consequently the output voltage from the piezoelectric patch. Analytical approximation for the frequency response and phase of the geometrically forced nonlinear vibration system are also obtained. The research aims at a rigorous analytical perspective on a nonlinear problem which has previously been solely investigated by numerical and experimental methods.

  3. Energy harvesting from vibration with cross-linked polypropylene piezoelectrets

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Xiaoqing [Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology & School of Physics Science and Engineering, Tongji University, Shanghai 200092 (China); Institute for Telecommunications Technology, Merckstrasse 25, 64283 Darmstadt (Germany); Wu, Liming [Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology & School of Physics Science and Engineering, Tongji University, Shanghai 200092 (China); Sessler, Gerhard M., E-mail: g.sessler@nt.tu-darmstadt.de [Institute for Telecommunications Technology, Merckstrasse 25, 64283 Darmstadt (Germany)

    2015-07-15

    Piezoelectret films are prepared by modification of the microstructure of polypropylene foam sheets cross-linked by electronic irradiation (IXPP), followed by proper corona charging. Young’s modulus, relative permittivity, and electromechanical coupling coefficient of the fabricated films, determined by dielectric resonance spectra, are about 0.7 MPa, 1.6, and 0.08, respectively. Dynamic piezoelectric d{sub 33} coefficients up to 650 pC/N at 200 Hz are achieved. The figure of merit (FOM, d{sub 33} ⋅ g{sub 33}) for a more typical d{sub 33} value of 400 pC/N is about 11.2 GPa{sup −1}. Vibration-based energy harvesting with one-layer and two-layer stacks of these films is investigated at various frequencies and load resistances. At an optimum load resistance of 9 MΩ and a resonance frequency of 800 Hz, a maximum output power of 120 μW, referred to the acceleration g due to gravity, is obtained for an energy harvester consisting of a one-layer IXPP film with an area of 3.14 cm{sup 2} and a seismic mass of 33.7 g. The output power can be further improved by using two-layer stacks of IXPP films in electric series. IXPP energy harvesters could be used to energize low-power electronic devices, such as wireless sensors and LED lights.

  4. Energy harvesting from vibration with cross-linked polypropylene piezoelectrets

    Directory of Open Access Journals (Sweden)

    Xiaoqing Zhang

    2015-07-01

    Full Text Available Piezoelectret films are prepared by modification of the microstructure of polypropylene foam sheets cross-linked by electronic irradiation (IXPP, followed by proper corona charging. Young’s modulus, relative permittivity, and electromechanical coupling coefficient of the fabricated films, determined by dielectric resonance spectra, are about 0.7 MPa, 1.6, and 0.08, respectively. Dynamic piezoelectric d33 coefficients up to 650 pC/N at 200 Hz are achieved. The figure of merit (FOM, d33 ⋅ g33 for a more typical d33 value of 400 pC/N is about 11.2 GPa−1. Vibration-based energy harvesting with one-layer and two-layer stacks of these films is investigated at various frequencies and load resistances. At an optimum load resistance of 9 MΩ and a resonance frequency of 800 Hz, a maximum output power of 120 μW, referred to the acceleration g due to gravity, is obtained for an energy harvester consisting of a one-layer IXPP film with an area of 3.14 cm2 and a seismic mass of 33.7 g. The output power can be further improved by using two-layer stacks of IXPP films in electric series. IXPP energy harvesters could be used to energize low-power electronic devices, such as wireless sensors and LED lights.

  5. Modelling of Mechanical Coupling for Piezoelectric Energy Harvester Adapted to Low-Frequency Vibration

    Science.gov (United States)

    Untoro, T.; Viridi, S.; Suprijanto; Ekawati, E.

    2017-07-01

    In our previous work, we have developed a mechanical coupling for energy harvester from vibration source. This energy harvester uses piezoelectric with additional cantilever beam and permanent magnets. Our work proposed alternative scheme of mechanical coupling for tune the vibration input into resonant frequency of piezoelectric. Based on the experiment, correlation between the length of cantilever beam and the output power also evaluated. In this paper, we try to modelling our work into mathematical model and apply it to some case study. For example application, we apply our energy harvester system to generate electrical energy to enlighten the street. The human footsteps can be used as vibration source to generate electrical energy.

  6. Ab initio potential energy and dipole moment surfaces for CS2: determination of molecular vibrational energies.

    Science.gov (United States)

    Pradhan, Ekadashi; Carreón-Macedo, José-Luis; Cuervo, Javier E; Schröder, Markus; Brown, Alex

    2013-08-15

    The ground state potential energy and dipole moment surfaces for CS2 have been determined at the CASPT2/C:cc-pVTZ,S:aug-cc-pV(T+d)Z level of theory. The potential energy surface has been fit to a sum-of-products form using the neural network method with exponential neurons. A generic interface between neural network potential energy surface fitting and the Heidelberg MCTDH software package is demonstrated. The potential energy surface has also been fit using the potfit procedure in MCTDH. For fits to the low-energy regions of the potential, the neural network method requires fewer parameters than potfit to achieve high accuracy; global fits are comparable between the two methods. Using these potential energy surfaces, the vibrational energies have been computed for the four most abundant CS2 isotopomers. These results are compared to experimental and previous theoretical data. The current potential energy surfaces are shown to accurately reproduce the low-lying vibrational energies within a few wavenumbers. Hence, the potential energy and dipole moments surfaces will be useful for future study on the control of quantum dynamics in CS2.

  7. Observations of a free-energy source for intense electrostatic waves. [in upper atmosphere near upper hybrid resonance frequency

    Science.gov (United States)

    Kurth, W. S.; Frank, L. A.; Gurnett, D. A.; Burek, B. G.; Ashour-Abdalla, M.

    1980-01-01

    Significant progress has been made in understanding intense electrostatic waves near the upper hybrid resonance frequency in terms of the theory of multiharmonic cyclotron emission using a classical loss-cone distribution function as a model. Recent observations by Hawkeye 1 and GEOS 1 have verified the existence of loss-cone distributions in association with the intense electrostatic wave events, however, other observations by Hawkeye and ISEE have indicated that loss cones are not always observable during the wave events, and in fact other forms of free energy may also be responsible for the instability. Now, for the first time, a positively sloped feature in the perpendicular distribution function has been uniquely identified with intense electrostatic wave activity. Correspondingly, we suggest that the theory is flexible under substantial modifications of the model distribution function.

  8. Electrostatically driven resonance energy transfer in "cationic" biocompatible indium phosphide quantum dots.

    Science.gov (United States)

    Devatha, Gayathri; Roy, Soumendu; Rao, Anish; Mallick, Abhik; Basu, Sudipta; Pillai, Pramod P

    2017-05-01

    Indium Phosphide Quantum Dots (InP QDs) have emerged as an alternative to toxic metal ion based QDs in nanobiotechnology. The ability to generate cationic surface charge, without compromising stability and biocompatibility, is essential in realizing the full potential of InP QDs in biological applications. We have addressed this challenge by developing a place exchange protocol for the preparation of cationic InP/ZnS QDs. The quaternary ammonium group provides the much required permanent positive charge and stability to InP/ZnS QDs in biofluids. The two important properties of QDs, namely bioimaging and light induced resonance energy transfer, are successfully demonstrated in cationic InP/ZnS QDs. The low cytotoxicity and stable photoluminescence of cationic InP/ZnS QDs inside cells make them ideal candidates as optical probes for cellular imaging. An efficient resonance energy transfer (E ∼ 60%) is observed, under physiological conditions, between the cationic InP/ZnS QD donor and anionic dye acceptor. A large bimolecular quenching constant along with a linear Stern-Volmer plot confirms the formation of a strong ground state complex between the cationic InP/ZnS QDs and the anionic dye. Control experiments prove the role of electrostatic attraction in driving the light induced interactions, which can rightfully form the basis for future nano-bio studies between cationic InP/ZnS QDs and anionic biomolecules.

  9. Real-time detection of doorway states in the intramolecular vibrational energy redistribution of the OH/OD stretch vibration of phenol

    OpenAIRE

    Yamada, Yuji; Mikami, Naohiko; Ebata, Takayuki

    2004-01-01

    A picosecond time-resolved IR-UV pump-probe spectroscopic study was carried out for the intramolecular vibrational energy redistribution of the OH/OD stretching vibration of isolated phenol and its isotopomers in supersonic beams. The time evolution due to IVR showed a significant isotope effect; the OH stretch vibration showed a single exponential decay and its lifetime is greatly lengthened upon the deuterium substitution of the CH group. The OD stretch vibration exhibited prominent quantum...

  10. Ultrafast vibrational energy transfer at the water/air interface revealed by two-dimensional surface vibrational spectroscopy

    NARCIS (Netherlands)

    Zhang, Z.; Piatkowski, L.; Bakker, H.J.; Bonn, M.

    2011-01-01

    Water is very different from liquids of similar molecular weight, and one of its unique properties is the very efficient transfer of vibrational energy between molecules, which arises as a result of strong dipole-dipole interactions between the O-H oscillators. Although we have a sound understanding

  11. Vibration piezoelectric energy harvester with multi-beam

    Energy Technology Data Exchange (ETDEWEB)

    Cui, Yan, E-mail: yanc@dlut.edu.cn; Zhang, Qunying, E-mail: zhangqunying89@126.com; Yao, Minglei, E-mail: yaomingleiok@126.com [Key Laboratory for Precision and Non-traditional Machining Technology of the Ministry of Education, Dalian University of Technology, 116024, Dalian, Liaoning Province (China); Dong, Weijie, E-mail: dongwj@dlut.edu.cn [School of Electronic and Information Engineering, Dalian University of Technology, 116024, Dalian, Liaoning Province (China); Gao, Shiqiao, E-mail: gaoshq@bit.edu.cn [State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, 100081, Beijing Province (China)

    2015-04-15

    This work presents a novel vibration piezoelectric energy harvester, which is a micro piezoelectric cantilever with multi-beam. The characteristics of the PZT (Pb(Zr{sub 0.53}Ti{sub 0.47})O{sub 3}) thin film were measured; XRD (X-ray diffraction) pattern and AFM (Atomic Force Microscope) image of the PZT thin film were measured, and show that the PZT (Pb(Zr{sub 0.53}Ti{sub 0.47})O{sub 3}) thin film is highly (110) crystal oriented; the leakage current is maintained in nA magnitude, the residual polarisation Pr is 37.037 μC/cm{sup 2}, the coercive field voltage Ec is 27.083 kV/cm, and the piezoelectric constant d{sub 33} is 28 pC/N. In order to test the dynamic performance of the energy harvester, a new measuring system was set up. The maximum output voltage of the single beam of the multi-beam can achieve 80.78 mV under an acceleration of 1 g at 260 Hz of frequency; the maximum output voltage of the single beam of the multi-beam is almost 20 mV at 1400 Hz frequency. .

  12. Vibration piezoelectric energy harvester with multi-beam

    Directory of Open Access Journals (Sweden)

    Yan Cui

    2015-04-01

    Full Text Available This work presents a novel vibration piezoelectric energy harvester, which is a micro piezoelectric cantilever with multi-beam. The characteristics of the PZT (Pb(Zr0.53Ti0.47O3 thin film were measured; XRD (X-ray diffraction pattern and AFM (Atomic Force Microscope image of the PZT thin film were measured, and show that the PZT (Pb(Zr0.53Ti0.47O3 thin film is highly (110 crystal oriented; the leakage current is maintained in nA magnitude, the residual polarisation Pr is 37.037 μC/cm2, the coercive field voltage Ec is 27.083 kV/cm, and the piezoelectric constant d33 is 28 pC/N. In order to test the dynamic performance of the energy harvester, a new measuring system was set up. The maximum output voltage of the single beam of the multi-beam can achieve 80.78 mV under an acceleration of 1 g at 260 Hz of frequency; the maximum output voltage of the single beam of the multi-beam is almost 20 mV at 1400 Hz frequency.

  13. Ab initio potential energy surface and vibration-rotation energy levels of beryllium monohydroxide.

    Science.gov (United States)

    Koput, Jacek

    2017-01-05

    The accurate potential energy surface of beryllium monohydroxide, BeOH, in its ground electronic state X 2A' has been determined from ab initio calculations using the coupled-cluster approach in conjunction with the correlation-consistent core-valence basis sets up to septuple-zeta quality. The higher-order electron correlation, scalar relativistic, and adiabatic effects were taken into account. The BeOH molecule was confirmed to be bent at equilibrium, with the BeOH angle of 141.2° and the barrier to linearity of 129 cm-1 . The vibration-rotation energy levels of the BeOH and BeOD isotopologues were predicted using a variational approach and compared with recent experimental data. The results can be useful in a further analysis of high-resolution vibration-rotation spectra of these interesting species. © 2016 Wiley Periodicals, Inc. © 2016 Wiley Periodicals, Inc.

  14. Impact Vibration Attenuation for a Flexible Robotic Manipulator through Transfer and Dissipation of Energy

    Directory of Open Access Journals (Sweden)

    Yushu Bian

    2013-01-01

    Full Text Available Due to the presence of system flexibility, impact can excite severe large amplitude vibration responses of the flexible robotic manipulator. This impact vibration exhibits characteristics of remarkable nonlinearity and strong energy. The main goal of this study is to put forward an energy-based control method to absorb and attenuate large amplitude impact vibration of the flexible robotic manipulator. The method takes advantage of internal resonance and is implemented through a vibration absorber based on the transfer and dissipation of energy. The addition of the vibration absorber to the flexible arm generates a coupling effect between vibration modes of the system. By means of analysis on 2:1 internal resonance, the exchange of energy is proven to be existent. The impact vibrational energy can be transferred from the arm to the absorber and dissipated through the damping of the absorber. The results of numerical simulations are promising and preliminarily verify that the method is feasible and can be used to combat large amplitude impact vibration of the flexible manipulator undergoing rigid motion.

  15. Retrofit of waste-to-energy facilities equipped with electrostatic precipitators. Volume III: Test protocol

    Energy Technology Data Exchange (ETDEWEB)

    Rigo, H.G. [Rigo & Rigo Associates, Inc., Berea, OH (US); Chandler, A.J. [A.J. Chandler & Associates, Inc., Toronto, Ontario (Canada)

    1996-04-01

    The American Society of Mechanical Engineers' [ASME] Center for Research and Technology Development [CRTD] has been awarded a subcontract by the National Renewable Energy Laboratory [NREL] to demonstrate the technical performance and viability of flue gas temperature control in combination with dry acid gas reagent and activated carbon injection at an existing electrostatic precipitator [ESP] equipped municipal waste combustor [MWC]. The objective of this proof-of-concept demonstration test is to economically and reliably meet 40 CFR 60 Subpart Cb Emissions Guidelines for MWC's at existing ESP equipped facilities. The effort is being directed by a Subcommittee of tile ASME Research Committee on Industrial and Municipal Wastes [RCIMW] chaired by Dave Hoecke. Mr. Greg Barthold of ASME/CRTD is the Project Manager. ASME/CRTD contracted with Rigo & Rigo Associates, Inc. in cooperation with A.J. Chandler & Associates, Ltd. to be the Principal Investigator for the project and manage the day-t o-day aspects of the program, conduct the testing reduce and interpret the data and prepare the report. Testing will be conducted at the 2 by 210 TPD, ESP equipped MWC at the Davis County Resource Recovery Facility in Layton, Utah. The test plan calls for duplicate metals (Cd, Pb and Hg), dioxin and acid gas runs.

  16. DelPhiForce web server: electrostatic forces and energy calculations and visualization.

    Science.gov (United States)

    Li, Lin; Jia, Zhe; Peng, Yunhui; Chakravorty, Arghya; Sun, Lexuan; Alexov, Emil

    2017-11-15

    Electrostatic force is an essential component of the total force acting between atoms and macromolecules. Therefore, accurate calculations of electrostatic forces are crucial for revealing the mechanisms of many biological processes. We developed a DelPhiForce web server to calculate and visualize the electrostatic forces at molecular level. DelPhiForce web server enables modeling of electrostatic forces on individual atoms, residues, domains and molecules, and generates an output that can be visualized by VMD software. Here we demonstrate the usage of the server for various biological problems including protein-cofactor, domain-domain, protein-protein, protein-DNA and protein-RNA interactions. The DelPhiForce web server is available at: http://compbio.clemson.edu/delphi-force. delphi@clemson.edu. Supplementary data are available at Bioinformatics online.

  17. Vibrational spectra of halide-water dimers: Insights on ion hydration from full-dimensional quantum calculations on many-body potential energy surfaces

    Science.gov (United States)

    Bajaj, Pushp; Wang, Xiao-Gang; Carrington, Tucker; Paesani, Francesco

    2018-03-01

    Full-dimensional vibrational spectra are calculated for both X-(H2O) and X-(D2O) dimers (X = F, Cl, Br, I) at the quantum-mechanical level. The calculations are carried out on two sets of recently developed potential energy functions (PEFs), namely, Thole-type model energy (TTM-nrg) and many-body energy (MB-nrg), using the symmetry-adapted Lanczos algorithm with a product basis set including all six vibrational coordinates. Although both TTM-nrg and MB-nrg PEFs are derived from coupled-cluster single double triple-F12 data obtained in the complete basis set limit, they differ in how many-body effects are represented at short range. Specifically, while both models describe long-range interactions through the combination of two-body dispersion and many-body classical electrostatics, the relatively simple Born-Mayer functions employed in the TTM-nrg PEFs to represent short-range interactions are replaced in the MB-nrg PEFs by permutationally invariant polynomials to achieve chemical accuracy. For all dimers, the MB-nrg vibrational spectra are in close agreement with the available experimental data, correctly reproducing anharmonic and nuclear quantum effects. In contrast, the vibrational frequencies calculated with the TTM-nrg PEFs exhibit significant deviations from the experimental values. The comparison between the TTM-nrg and MB-nrg results thus reinforces the notion that an accurate representation of both short-range interactions associated with electron density overlap and long-range many-body electrostatic interactions is necessary for a correct description of hydration phenomena at the molecular level.

  18. Shock reliability enhancement for MEMS vibration energy harvesters with nonlinear air damping as a soft stopper

    Science.gov (United States)

    Chen, Shao-Tuan; Du, Sijun; Arroyo, Emmanuelle; Jia, Yu; Seshia, Ashwin

    2017-10-01

    This paper presents a novel application of utilising nonlinear air damping as a soft mechanical stopper to increase the shock reliability for microelectromechanical systems (MEMS) vibration energy harvesters. The theoretical framework for nonlinear air damping is constructed for MEMS vibration energy harvesters operating in different air pressure levels, and characterisation experiments are conducted to establish the relationship between air pressure and nonlinear air damping coefficient for rectangular cantilever MEMS micro cantilevers with different proof masses. Design guidelines on choosing the optimal air pressure level for different MEMS vibration energy harvesters based on the trade-off between harvestable energy and the device robustness are presented, and random excitation experiments are performed to verify the robustness of MEMS vibration energy harvesters with nonlinear air damping as soft stoppers to limit the maximum deflection distance and increase the shock reliability of the device.

  19. Development of electrostatic supercapacitors by atomic layer deposition on nanoporous anodic aluminium oxides for energy harvesting applications

    Directory of Open Access Journals (Sweden)

    Lucia eIglesias

    2015-03-01

    Full Text Available Nanomaterials can provide innovative solutions for solving the usual energy harvesting and storage drawbacks that take place in conventional energy storage devices based on batteries or electrolytic capacitors, because they are not fully capable for attending the fast energy demands and high power densities required in many of present applications. Here, we report on the development and characterization of novel electrostatic supercapacitors made by conformal Atomic Layer Deposition on the high open surface of nanoporous anodic alumina membranes employed as templates. The structure of the designed electrostatic supercapacitor prototype consists of successive layers of Aluminium doped Zinc Oxide, as the bottom and top electrodes, together Al2O3 as the intermediate dielectric layer. The conformality of the deposited conductive and dielectric layers, together with their composition and crystalline structure have been checked by XRD and electron microscopy techniques. Impedance measurements performed for the optimized electrostatic supercapacitor device give a high capacitance value of 200 µF/cm2 at the frequency of 40 Hz, which confirms the theoretical estimations for such kind of prototypes, and the leakage current reaches values around of 1.8 mA/cm2 at 1 V. The high capacitance value achieved by the supercapacitor prototype together its small size turns these devices in outstanding candidates for using in energy harvesting and storage applications.

  20. Vibration-to-electric energy conversion with porous graphene oxide-nickel electrode

    Science.gov (United States)

    Zhang, Chen; Dang, Fei; Chen, Youlong; Yan, Yuan; Liu, Yilun; Chen, Xi

    2017-11-01

    In this work, we present a new approach of converting vibration energy to electric energy using porous graphene oxide-nickel (pGO-Ni) electrode and ionic solution. When actuated by vibration, the ionic solution repeatedly flows across the pGO-Ni electrode which changes the electric double layer at the interface between the pGO-Ni electrode and ionic solution. Therefore, a significant potential difference between the working electrode and the reference electrode immersed into the static ionic solution is observed. The output voltage first increases with the vibration frequency and then gradually approaches to a saturated value of 70.12 mV as the vibration frequency increases to 15 Hz. By connecting a 3 kΩ resistance to the energy conversion system, the discharging behaviors of the energy conversion system are studied, which shows an exponential decay of the output voltage and current. The proposed energy conversion system is analogous to a supercapacitor, whose effective capacitance, internal resistance and energy conversion efficiency are deduced based on the discharging experiments. The work provides a new vibration-to-electric energy conversion mechanism, which may inspire potential applications in flow sensor and harvesting waste mechanical or vibration energy.

  1. Broadband characteristics of vibration energy harvesting using one-dimensional phononic piezoelectric cantilever beams

    Energy Technology Data Exchange (ETDEWEB)

    Chen Zhongsheng, E-mail: czs_study@sina.com [Key Laboratory of Science and Technology on Integrated Logistics Support, College of Mechatronic Engineering and Automation, National University of Defense Technology, Changsha, Hunan 410073 (China); Yang Yongmin; Lu Zhimiao; Luo Yanting [Key Laboratory of Science and Technology on Integrated Logistics Support, College of Mechatronic Engineering and Automation, National University of Defense Technology, Changsha, Hunan 410073 (China)

    2013-02-01

    Nowadays broadband vibration energy harvesting using piezoelectric effect has become a research hotspot. The innovation in this paper is the widening of the resonant bandwidth of a piezoelectric harvester based on phononic band gaps, which is called one-dimensional phononic piezoelectric cantilever beams (PPCBs). Broadband characteristics of one-dimensional PPCBs are analyzed deeply and the vibration band gap can be calculated. The effects of different parameters on the vibration band gap are presented by both numerical and finite element simulations. Finally experimental tests are conducted to validate the proposed method. It can be concluded that it is feasible to use the PPCB for broadband vibration energy harvesting and there should be a compromise among related parameters for low-frequency vibrations.

  2. Analysis of vibroprotection characteristics of pneumatic relaxation seat suspension with capability of vibration energy recuperation

    Directory of Open Access Journals (Sweden)

    Lyashenko Mikhail

    2017-01-01

    Full Text Available This paper proposes mechanism and control algorithm for pneumatic relaxation system of suspension with vibration energy recuperation applied to standard vehicle operator seat (“Sibeko” company. Mathematical model of the seat pneumatic relaxation suspension with two additional air volumes was created. Pneumatic motor – recuperator activated by means of air flow from the one additional volume to another is installed in air piping between additional volumes. Computational research was made in Matlab/Simulink. Amplitude-frequency characteristics of transmission coefficient for standard and proposed suspensions were plotted for preliminary evaluation of vibration protection properties of seat suspension. Performed comparative analysis of amplitude-frequency characteristics shows that noticeable improvement of vibration protection properties of pneumatic relaxation suspension system with vibration energy recuperation in comparison with standard system both in region of resonance disturbances and in above-resonance region. Main ways for further improvement of vibration protection properties of proposed system were marked out.

  3. A dimensionless analysis of a 2DOF piezoelectric vibration energy harvester

    Science.gov (United States)

    Xiao, Han; Wang, Xu; John, Sabu

    2015-06-01

    In this study, a dimensionless analysis method is proposed to predict the output voltage and harvested power for a 2DOF vibration energy harvesting system. This method allows us to compare the harvesting power and efficiency of the 2DOF vibration energy harvesting system and to evaluate the harvesting system performance regardless the sizes or scales. The analysis method is a hybrid of time domain simulation and frequency response analysis approaches, which would be a useful tool for parametric study, design and optimisation of a 2DOF piezoelectric vibration energy harvester. In a case study, a quarter car suspension model with a piezoelectric material insert is chosen to be studied. The 2DOF vibration energy harvesting system could potentially be applied in a vehicle to convert waste or harmful ambient vibration energy into electrical energy for charging the battery. Especially for its application in a hybrid vehicle or an electrical vehicle, the 2DOF vibration energy harvesting system could improve charge mileage, comfort and reliability.

  4. Dipolar electrostatic energy effect on relaxation process of monolayers at air-water interface: analysis of thermodynamics and kinetics.

    Science.gov (United States)

    Ou-Yang, Wei; Weis, Martin; Lee, Keanchuan; Manaka, Takaaki; Iwamoto, Mitsumasa

    2009-12-28

    In order to understand the effect of electrostatic energy on phase transition from monolayer to multilayer, isobaric relaxation process of Langmuir monolayers composed of stearic acid or ferroelectric polyvinylidene fluoride and trifluoroethylene copolymer with various vinylidene fluoride (VDF) ratios is investigated in terms of thermodynamic and kinetic analysis. A monotonous decreasing tendency of material loss with respect to temperature is observed for stearic acid monolayer, which is due to thermal activation effect on phase transition from monolayer to multilayer. In contrast, for the ferroelectric monolayer it presents a nonmonotonous behavior of losing materials with a peak position near the Curie temperature, which is not only owing to thermal activation but also dipole moment change. This observation is confirmed for the copolymer monolayers with other VDF content ratios. Amazingly, for the ferroelectric monolayers a good correspondence is found for critical temperatures evaluated from several independent methods including the analysis on slow collapse. This finding again tells the fact that the relaxation process, namely phase transition from monolayer to multilayer, is greatly influenced by dipolar electrostatic energy. Moreover, the study of time dependent relaxation process reveals a diffusionlike behavior of multilayer structure formation, which cannot be interpreted by classical models. Hence a new model based on diffusion-driven material transfer is proposed and diffusivity of the copolymer molecules is estimated with a value of 0.4x10(-5) cm(2)/s. As a whole, this research reflects the importance of dipolar electrostatic energy for phase transition of monolayers at air-water interface.

  5. Electrostatic interactions between ions near Thomas-Fermi substrates and the surface energy of ionic crystal at imperfect metals

    Science.gov (United States)

    Kaiser, V.; Comtet, J.; Niguès, A.; Siria, A.; Coasne, B.; Bocquet, L.

    2017-01-01

    The electrostatic interaction between two charged particles is strongly modified in the vicinity of a metal. This situation is usually accounted for by the celebrated image charges approach, which was further extended to account for the electronic screening properties of the metal at the level of the Thomas-Fermi description. In this paper we build upon the approach by [Kornyshev et al. Zh. Eksp. Teor. Fiz., 78(3):1008–1019, 1980] and successive works to calculate the 1-body and 2-body electrostatic energy of ions near a metal in terms of the Thomas-Fermi screening length. We propose workable approximations suitable for molecular simulations of ionic systems close to metallic walls. Furthermore, we use this framework to calculate analytically the electrostatic contribution to the surface energy of a one dimensional crystal at a metallic wall and its dependence on the Thomas-Fermi screening length. These calculations provide a simple interpretation for the surface energy in terms of image charges, which allow for an estimate of interfacial properties in more complex situations of a disordered ionic liquid close to a metal surface. A counterintuitive outcome is that electronic screening, as characterized by a molecular Thomas-Fermi length ℓTF, profoundly affects the wetting of ionic systems close to a metal, in line with the recent experimental observation of capillary freezing of ionic liquids in metallic confinement. PMID:28436506

  6. Electrostatic interactions between ions near Thomas-Fermi substrates and the surface energy of ionic crystals at imperfect metals.

    Science.gov (United States)

    Kaiser, V; Comtet, J; Niguès, A; Siria, A; Coasne, B; Bocquet, L

    2017-07-01

    The electrostatic interaction between two charged particles is strongly modified in the vicinity of a metal. This situation is usually accounted for by the celebrated image charges approach, which was further extended to account for the electronic screening properties of the metal at the level of the Thomas-Fermi description. In this paper we build upon a previous approach [M. A. Vorotyntsev and A. A. Kornyshev, Zh. Eksp. Teor. Fiz., 1980, 78(3), 1008-1019] and successive works to calculate the 1-body and 2-body electrostatic energy of ions near a metal in terms of the Thomas-Fermi screening length. We propose workable approximations suitable for molecular simulations of ionic systems close to metallic walls. Furthermore, we use this framework to calculate analytically the electrostatic contribution to the surface energy of a one dimensional crystal at a metallic wall and its dependence on the Thomas-Fermi screening length. These calculations provide a simple interpretation for the surface energy in terms of image charges, which allows for an estimation of the interfacial properties in more complex situations of a disordered ionic liquid close to a metal surface. The counter-intuitive outcome is that electronic screening, as characterized by a molecular Thomas-Fermi length lTF, profoundly affects the wetting of ionic systems close to a metal, in line with the recent experimental observation of capillary freezing of ionic liquids in metallic confinement.

  7. Characterization of real-world vibration sources with a view toward optimal energy harvesting architectures

    Science.gov (United States)

    Rantz, Robert; Roundy, Shad

    2016-04-01

    A tremendous amount of research has been performed on the design and analysis of vibration energy harvester architectures with the goal of optimizing power output; most studies assume idealized input vibrations without paying much attention to whether such idealizations are broadly representative of real sources. These "idealized input signals" are typically derived from the expected nature of the vibrations produced from a given source. Little work has been done on corroborating these expectations by virtue of compiling a comprehensive list of vibration signals organized by detailed classifications. Vibration data representing 333 signals were collected from the NiPS Laboratory "Real Vibration" database, processed, and categorized according to the source of the signal (e.g. animal, machine, etc.), the number of dominant frequencies, the nature of the dominant frequencies (e.g. stationary, band-limited noise, etc.), and other metrics. By categorizing signals in this way, the set of idealized vibration inputs commonly assumed for harvester input can be corroborated and refined, and heretofore overlooked vibration input types have motivation for investigation. An initial qualitative analysis of vibration signals has been undertaken with the goal of determining how often a standard linear oscillator based harvester is likely the optimal architecture, and how often a nonlinear harvester with a cubic stiffness function might provide improvement. Although preliminary, the analysis indicates that in at least 23% of cases, a linear harvester is likely optimal and in no more than 53% of cases would a nonlinear cubic stiffness based harvester provide improvement.

  8. Simulation of vibrational energy transfer in two-dimensional infrared spectroscopy of amide I and amide II modes in solution

    NARCIS (Netherlands)

    Bloem, Robbert; Dijkstra, Arend G.; Jansen, Thomas La Cour; Knoester, Jasper

    2008-01-01

    Population transfer between vibrational eigenstates is important for many phenomena in chemistry. In solution, this transfer is induced by fluctuations in molecular conformation as well as in the surrounding solvent. We develop a joint electrostatic density functional theory map that allows us to

  9. Simulating electrostatic energies in proteins: perspectives and some recent studies of pKas, redox, and other crucial functional properties.

    Science.gov (United States)

    Warshel, Arieh; Dryga, Anatoly

    2011-12-01

    Electrostatic energies provide what is arguably the most effective tool for structure-function correlation of biological molecules. Here, we provide an overview of the current state-of-the-art simulations of electrostatic energies in macromolecules, emphasizing the microscopic perspective but also relating it to macroscopic approaches. We comment on the convergence issue and other problems of the microscopic models and the ways of keeping the microscopic physics while moving to semi-macroscopic directions. We discuss the nature of the protein dielectric "constants" reiterating our long-standing point that the dielectric "constants" in semi-macroscopic models depend on the definition and the specific treatment. The advances and the challenges in the field are illustrated considering different functional properties including pK(a)'s, redox potentials, ion and proton channels, enzyme catalysis, ligand binding, and protein stability. We emphasize the microscopic overcharging approach for studying pK(a) 's of internal groups in proteins and give a demonstration of power of this approach. We also emphasize recent advances in coarse grained models with a physically based electrostatic treatment and provide some examples including further directions in treating voltage activated ion channels. Copyright © 2011 Wiley-Liss, Inc.

  10. Piezoelectric Cylindrical Design for Harvesting Energy in Multi-Directional Vibration Source

    Science.gov (United States)

    Nguyen, M. S.; Ng, S. H.; Kim, P.; Yoon, Y. J.

    2017-08-01

    Vibration Energy Harvester (VEH) has attracted a great attention recently both in academia and industry. One of the most challenging issues in VEH is the possibility to harvest vibration energy in multiple directions. In fact, Conventional VEH (CVEH) using cantilever beam’s structure may possibly become inefficient for the application under multi-directional vibration sources. To overcome this shortcoming of CVEH, this paper proposes a novel design of piezoelectric cylindrical energy harvester (PCEH) which is using patches of piezoelectric material attached to the surface of a cylindrical structure. The Finite Element Method (FEM) analysis using COMSOL Multiphysics software package showed that PCEH has a great potential for the applicability of VEH in the multi-directional vibrating applications such as wearable devices and biomedical devices.

  11. Theoretical potential for low energy consumption phase change memory utilizing electrostatically-induced structural phase transitions in 2D materials

    Science.gov (United States)

    Rehn, Daniel A.; Li, Yao; Pop, Eric; Reed, Evan J.

    2018-01-01

    Structural phase-change materials are of great importance for applications in information storage devices. Thermally driven structural phase transitions are employed in phase-change memory to achieve lower programming voltages and potentially lower energy consumption than mainstream nonvolatile memory technologies. However, the waste heat generated by such thermal mechanisms is often not optimized, and could present a limiting factor to widespread use. The potential for electrostatically driven structural phase transitions has recently been predicted and subsequently reported in some two-dimensional materials, providing an athermal mechanism to dynamically control properties of these materials in a nonvolatile fashion while achieving potentially lower energy consumption. In this work, we employ DFT-based calculations to make theoretical comparisons of the energy required to drive electrostatically-induced and thermally-induced phase transitions. Determining theoretical limits in monolayer MoTe2 and thin films of Ge2Sb2Te5, we find that the energy consumption per unit volume of the electrostatically driven phase transition in monolayer MoTe2 at room temperature is 9% of the adiabatic lower limit of the thermally driven phase transition in Ge2Sb2Te5. Furthermore, experimentally reported phase change energy consumption of Ge2Sb2Te5 is 100-10,000 times larger than the adiabatic lower limit due to waste heat flow out of the material, leaving the possibility for energy consumption in monolayer MoTe2-based devices to be orders of magnitude smaller than Ge2Sb2Te5-based devices.

  12. Application of nonlinear magnetic vibro-impact vibration suppressor and energy harvester

    Science.gov (United States)

    Afsharfard, Aref

    2018-01-01

    In the present study, application of a single unit vibro-impact system is improved. For this reason, in the so-called ;magnetic impact damper; the impact mass is replaced by a permanent magnet, which moves in coil of gap enclosure. In the magnetic impact damper, wasting energy during inelastic contacts of masses and converting energy into electrical energy during the mass movement inside the coil, leads to suppress undesired vibrations. In this study it is shown that the magnetic impact dampers are not only good vibration suppressors but also they can harvest electrical energy. Effect of changing the main parameters of this system including gap size, load resistance and electromagnetic coupling coefficient is studied on the vibratory and energy behavior of the magnetic impact dampers. Finally using several user oriented charts, it is shown that energy-based and vibration-based design considerations can effectively improve application of the discussed vibro-impact system.

  13. Designing, modelling and testing of vibration energy harvester with nonlinear stiffness

    Science.gov (United States)

    Rubes, Ondrej; Hadas, Zdenek

    2017-05-01

    This paper is focused on a design of a piezoelectric vibration energy harvester with an additional nonlinear stiffness. Common piezoelectric energy harvesters consist of a cantilever with piezoceramic layers and a tip mass for tuning up the operation frequency. This system is excited by mechanical vibrations and it provides an autonomous source of electrical energy. A linear stiffness of the cantilever has very narrow resonance frequency bandwidth which makes the piezoelectric cantilever sensitive to tuning up of the resonance frequency. It could be tuned only for one narrow vibration frequency bandwidth. The piezoelectric vibration energy harvester with nonlinear stiffness could provide the resonance frequency bandwidth wider and it allows energy harvesting from the wider bandwidth of excitation vibrations. The additional nonlinear stiffness is implemented by using a set of permanent magnets. A simulation and an experiment were performed and the results show a wider resonance bandwidth. However, it depended on direction of vibration frequency sweeping. The frequency bandwidth is more than three times wider but there is only a half resonance amplitude of oscillations. That means that the maximal harvested power is lower but the average harvested power around resonance frequency was higher which was the goal of this research.

  14. Vibrational energy transport in acetylbenzonitrile described by an ab initio-based quantum tier model

    Science.gov (United States)

    Fujisaki, Hiroshi; Yagi, Kiyoshi; Kikuchi, Hiroto; Takami, Toshiya; Stock, Gerhard

    2017-01-01

    Performing comprehensive quantum-chemical calculations, a vibrational Hamiltonian of acetylbenzonitrile is constructed, on the basis of which a quantum-mechanical "tier model" is developed that describes the vibrational dynamics following excitation of the CN stretch mode. Taking into account 36 vibrational modes and cubic and quartic anharmonic couplings between up to three different modes, the tier model calculations are shown to qualitatively reproduce the main findings of the experiments of Rubtsov and coworkers (2011), including the energy relaxation of the initially excited CN mode and the structure-dependent vibrational transport. Moreover, the calculations suggest that the experimentally measured cross-peak among the CN and CO modes does not correspond to direct excitation of the CO normal mode but rather reflects excited low-frequency vibrations that anharmonically couple to the CO mode. Complementary quasiclassical trajectory calculations are found to be in good overall agreement with the quantum calculations.

  15. Electrostatics in ionic solution : work and energy, charge regulation, and inhomogeneous surfaces

    NARCIS (Netherlands)

    Boon, N.J.H.

    2012-01-01

    This thesis concerns the electrostatic properties of charged objects that are immersed into an ionic solvent, for example water with dissolved salt. Typically, the ions inside such a solvent form layers of countercharge close to the charged objects, causing `screening' of the charges. By employing

  16. Report of workshop on vibration related to fluid in atomic energy field. 7

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-31

    Because of the nonlinearity of the equation that governs flow, sometimes vibration occurs in an unexpected system, and it causes trouble. This 7th workshop on vibration related to fluid in atomic energy field was held at Nuclear Engineering Research Laboratory of University of Tokyo on August 25 and 26, 1997. Two themes were ``Vibration of liquid surface by flow`` and ``Numerical analysis of coupled vibration of fluid-structures``. The former is related to the problem in the development of a demonstration FBR, and the latter is related to the numerical analysis technology such as the handling of boundary conditions and the method of taking position, moving velocity and acceleration into account. This workshop aims at thoroughly discussing a small number of themes, and deepening the understanding. In this report, the summaries of 17 papers are collected, of which the titles are as follows. Liquid surface self-exciting vibration by flow, vibration of upper plenum liquid surface of fast reactor, stability analysis of multiple liquid surfaces, flow instability phenomena of multi-loop system, sloshing in a vessel in which fluid flows, the mechanism of occurrence of self-exciting sloshing in a vessel elucidated by numerical analysis, numerical analysis of manometer vibration excited by flow, numerical analysis of flutter phenomena of aircraft, numerical analysis of aerodynamic elastic problem, mechanism of in-line excitation, numerical analysis of hydrodynamic elastic vibration of tube nest and so on. (K.I.)

  17. A Novel Self-Powered Wireless Sensor Node Based on Energy Harvesting for Mechanical Vibration Monitoring

    Directory of Open Access Journals (Sweden)

    Xihai Zhang

    2014-01-01

    Full Text Available Wireless sensor networks (WSNs have been expected to improve the capability of capturing mechanical vibration dynamic behaviors and evaluating the current health status of equipment. While the expectation for mechanical vibration monitoring using WSNs has been high, one of the key limitations is the limited lifetime of batteries for sensor node. The energy harvesting technologies have been recently proposed. One of them shares the same main idea, that is, energy harvesting from ambient vibration can be converted into electric power. Employing the vibration energy harvesting, a novel self-powered wireless sensor node has been developed to measure mechanical vibration in this paper. The overall architecture of node is proposed. The wireless sensor node is described into four main components: the energy harvesting unit, the microprocessor unit, the radio transceiver unit, and accelerometer. Moreover, the software used to control the operation of wireless node is also suggested. At last, in order to achieve continuous self-powered for nodes, two operation modes including the charging mode and discharging mode are proposed. This design can effectively solve the problem of continuous supply power of sensor node for mechanical vibration monitoring.

  18. Efficient Vibrational Energy Transfer through Covalent Bond in Indigo Carmine Revealed by Nonlinear IR Spectroscopy.

    Science.gov (United States)

    He, Xuemei; Yu, Pengyun; Zhao, Juan; Wang, Jianping

    2017-10-12

    Ultrafast vibrational relaxation and structural dynamics of indigo carmine in dimethyl sulfoxide were examined using femtosecond pump-probe infrared and two-dimensional infrared (2D IR) spectroscopies. Using the intramolecularly hydrogen-bonded C═O and delocalized C═C stretching modes as infrared probes, local structural and dynamical variations of this blue dye molecule were observed. Energy relaxation of the vibrationally excited C═O stretching mode was found to occur through covalent bond to the delocalized aromatic vibrational modes on the time scale of a few picoseconds or less. Vibrational quantum beating was observed in magic-angle pump-probe, anisotropy, and 2D IR cross-peak dynamics, showing an oscillation period of ca. 1010 fs, which corresponds to the energy difference between the C═O and C═C transition frequency (33 cm-1). This confirms a resonant vibrational energy transfer happened between the two vibrators. However, a more efficient energy-accepting mode of the excited C═O stretching was believed to be a nearby combination and/or overtone mode that is more tightly connected to the C═O species. On the structural aspect, dynamical-time-dependent 2D IR spectra reveal an insignificant inhomogeneous contribution to time-correlation relaxation for both the C═O and C═C stretching modes, which is in agreement with the generally believed structural rigidity of such conjugated molecules.

  19. A velocity-amplified electromagnetic energy harvester for small amplitude vibration

    Science.gov (United States)

    Klein, J.; Zuo, L.

    2017-09-01

    Dedicated, self-powered wireless sensors are widely being studied for use throughout many industries to monitor everyday operations, maintain safety, and report performance characteristics. To enable sensors to power themselves, harvesting energy from machine vibration has been studied, however, its overall effectiveness can be hampered due to small vibration amplitudes and thus limited harvestable energy density. This paper addresses the issue by proposing a novel vibration energy harvester architecture in which a compliant mechanism and proof mass system is used to amplify the vibrational velocity of machine vibration for a linear electromagnetic generator. A prototype has been fabricated and experimentally characterized to verify its effectiveness. When operating at its natural frequency in a low base amplitude, 0.001 inch (25.4 μm) at 19.4 Hz, during lab tests, the harvester has been shown to produce up to 0.91 V AC open voltage, and a maximum power of 2 mW, amplifying the relative proof mass velocity by approximately 5.4 times. This method of locally increasing the machine vibrational velocity has been shown to be a viable option for increasing the potential power output of an energy harvester. In addition, a mathematical model is created based on pseudo-rigid-body dynamics and the analysis matches closely with experiments.

  20. Incorporating nuclear vibrational energies into the "atom in molecules" analysis: An analytical study.

    Science.gov (United States)

    Gharabaghi, Masumeh; Shahbazian, Shant

    2017-04-21

    The quantum theory of atoms in molecules (QTAIM) is based on the clamped nucleus paradigm and solely working with the electronic wavefunctions, so does not include nuclear vibrations in the AIM analysis. On the other hand, the recently extended version of the QTAIM, called the multi-component QTAIM (MC-QTAIM), incorporates both electrons and quantum nuclei, i.e., those nuclei treated as quantum waves instead of clamped point charges, into the AIM analysis using non-adiabatic wavefunctions. Thus, the MC-QTAIM is the natural framework to incorporate the role of nuclear vibrations into the AIM analysis. In this study, within the context of the MC-QTAIM, the formalism of including nuclear vibrational energy in the atomic basin energy is developed in detail and its contribution is derived analytically using the recently proposed non-adiabatic Hartree product nuclear wavefunction. It is demonstrated that within the context of this wavefunction, the quantum nuclei may be conceived pseudo-adiabatically as quantum oscillators and both isotropic harmonic and anisotropic anharmonic oscillator models are used to compute the zero-point nuclear vibrational energy contribution to the basin energies explicitly. Inspired by the results gained within the context of the MC-QTAIM analysis, a heuristic approach is proposed within the context of the QTAIM to include nuclear vibrational energy in the basin energy from the vibrational wavefunction derived adiabatically. The explicit calculation of the basin contribution of the zero-point vibrational energy using the uncoupled harmonic oscillator model leads to results consistent with those derived from the MC-QTAIM.

  1. Local orientational order in liquids revealed by resonant vibrational energy transfer.

    Science.gov (United States)

    Panman, M R; Shaw, D J; Ensing, B; Woutersen, S

    2014-11-14

    We demonstrate that local orientational ordering in a liquid can be observed in the decay of the vibrational anisotropy caused by resonant transfer of vibrational excitations between its constituent molecules. We show that the functional form of this decay is determined by the (distribution of) angles between the vibrating bonds of the molecules between which energy transfer occurs, and that the initial drop in the decay reflects the average angle between nearest neighbors. We use this effect to observe the difference in local orientational ordering in the two hydrogen-bonded liquids ethanol and N-methylacetamide.

  2. Ab initio potential energy surface and vibration-rotation energy levels of sulfur dioxide.

    Science.gov (United States)

    Koput, Jacek

    2017-05-05

    An accurate potential energy surface of sulfur dioxide, SO2 , in its ground electronic state X∼ 1A1 has been determined from ab initio calculations using the coupled-cluster approach in conjunction with the correlation-consistent basis sets up to septuple-zeta quality. The results obtained with the conventional and explicitly correlated coupled-cluster methods are compared. The role of the core-electron correlation, higher-order valence-electron correlation, scalar relativistic, and adiabatic effects in determining the structure and dynamics of the SO2 molecule is discussed. The vibration-rotation energy levels of the 32 SO2 and 34 SO2 isotopologues were predicted using a variational approach. It was shown that the inclusion of the aforementioned effects was mandatory to attain the "spectroscopic" accuracy. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.

  3. Peculiarities of the Third Natural Frequency Vibrations of a Cantilever for the Improvement of Energy Harvesting

    Directory of Open Access Journals (Sweden)

    Vytautas Ostasevicius

    2015-05-01

    Full Text Available This paper focuses on several aspects extending the dynamical efficiency of a cantilever beam vibrating in the third mode. A few ways of producing this mode stimulation, namely vibro-impact or forced excitation, as well as its application for energy harvesting devices are proposed. The paper presents numerical and experimental analyses of novel structural dynamics effects along with an optimal configuration of the cantilever beam. The peculiarities of a cantilever beam vibrating in the third mode are related to the significant increase of the level of deformations capable of extracting significant additional amounts of energy compared to the conventional harvester vibrating in the first mode. Two types of a piezoelectric vibrating energy harvester (PVEH prototype are analysed in this paper: the first one without electrode segmentation, while the second is segmented using electrode segmentation at the strain nodes of the third vibration mode to achieve effective operation at the third resonant frequency. The results of this research revealed that the voltage generated by any segment of the segmented PVEH prototype excited at the third resonant frequency demonstrated a 3.4–4.8-fold increase in comparison with the non-segmented prototype. Simultaneously, the efficiency of the energy harvester prototype also increased at lower resonant frequencies from 16% to 90%. The insights presented in the paper may serve for the development and fabrication of advanced piezoelectric energy harvesters which would be able to generate a considerably increased amount of electrical energy independently of the frequency of kinematical excitation.

  4. Analysis of wind energy potential and vibrations caused by wind turbine on its basement

    OpenAIRE

    Kaláb, Zdeněk; Hanslian, David; Stolárik, Martin; Pinka, Miroslav

    2014-01-01

    This paper deals with study of wind energy potential and experimental measurement of vibrations caused by wind turbine. Study area was wind park Horní Loděnice – Lipina. To obtain frequency distribution of wind speed, two models were used for calculation. Experimental seismological measurement was performed in near surroundings of the wind turbine. At low wind speed without significant wind gust, only negligible vibrations were measured. Web of Science 19 3 159 151

  5. Synchronous inversion and charge extraction (SICE): a hybrid switching interface for efficient vibrational energy harvesting

    Science.gov (United States)

    Lallart, Mickaël; Wu, Wen-Jong; Hsieh, Yuchieh; Yan, Linjuan

    2017-11-01

    This paper aims at proposing an electrical interface taking advantage of nonlinear treatment for both significantly increasing the voltage of a piezoelectric device and extracting the corresponding electrostatic energy in an independent way from the connected electrical load. The principles of the proposed system lies in quickly inverting the piezoelectric voltage on each extremum (synchronized switch on inductor operations) for a given number of extremum occurrences, and then extracting the total electrostatic energy available on the piezoelectric element through the so-called synchronous electric charge extraction (SECE) for energy harvesting purpose. Compared to classical SECE approach, which consists in extracting the energy on each voltage extremum occurrence, the proposed scheme shows a significant improvement in low-coupled systems thanks to a fine control of the trade-off between voltage amplification and number of extraction events.

  6. Modelling of a Bi-axial Vibration Energy Harvester

    Science.gov (United States)

    2013-05-01

    effect of the electrical load on the transduction, and on the mechanical dynamics. It was demonstrated that the back EMF from current flow in the...created with a permanent-magnet/ball-bearing arrangement. The mechanical oscillations of the ball-bearing in response to bi-axial vibrations in a host...system on an aircraft platform. Modelling of the mechanical dynamics and the electromechanical transduction of the harvester is undertaken by: means of

  7. Using Electronic Energy Derivative Information in Automated Potential Energy Surface Construction for Vibrational Calculations.

    Science.gov (United States)

    Sparta, Manuel; Hansen, Mikkel B; Matito, Eduard; Toffoli, Daniele; Christiansen, Ove

    2010-10-12

    The availability of an accurate representation of the potential energy surface (PES) is an essential prerequisite in an anharmonic vibrational calculation. At the same time, the high dimensionality of the fully coupled PES and the adverse scaling properties with respect to the molecular size make the construction of an accurate PES a computationally demanding task. In the past few years, our group tested and developed a series of tools and techniques aimed at defining computationally efficient, black-box protocols for the construction of PESs for use in vibrational calculations. This includes the definition of an adaptive density-guided approach (ADGA) for the construction of PESs from an automatically generated set of evaluation points. Another separate aspect has been the exploration of the use of derivative information through modified Shepard (MS) interpolation/extrapolation procedures. With this article, we present an assembled machinery where these methods are embedded in an efficient way to provide both a general machinery as well as concrete computational protocols. In this framework we introduce and discuss the accuracy and computational efficiency of two methods, called ADGA[2gx3M] and ADGA[2hx3M], where the ADGA recipe is used (with MS interpolation) to automatically define modest sized grids for up to two-mode couplings, while MS extrapolation based on, respectively, gradients only and gradients and Hessians from the ADGA determined points provides access to sufficiently accurate three-mode couplings. The performance of the resulting potentials is investigated in vibrational coupled cluster (VCC) calculations. Three molecular systems serve as benchmarks: a trisubstituted methane (CHFClBr), methanimine (CH2NH), and oxazole (C3H3NO). Furthermore, methanimine and oxazole are addressed in accurate calculations aiming to reproduce experimental results.

  8. Design and experimental study of a velocity amplified electromagnetic vibration energy harvester

    Science.gov (United States)

    Klein, Jackson A.; Zuo, Lei

    2017-04-01

    Dedicated sensors are widely used throughout many industries to monitor everyday operations, maintain safety and report performance characteristics. In order to adopt a more sustainable solution, intensive research is being conducted for self-powered sensing. To enable sensors to power themselves, harvesting energy from environmental vibration has been widely studied, however, its overall effectiveness remains questionable due to small vibration amplitudes and thus limited harvestable energy density. This paper addresses the issue by proposing a novel vibration energy harvester in which a metal compliant mechanism frame is used to house both a linear electromagnetic generator and proof mass. Due to the compliant mechanism, the proposed energy harvester is capable of amplifying machine vibration velocity for a dedicated electromagnetic generator, largely increasing the energy density. The harvester prototype is also fabricated and experimentally characterized to verify its effectiveness. When operating at its natural frequency in a low base amplitude, 0.001 in (25.4μm) at 19.4 Hz, during lab tests, the harvester has been shown to produce up to 0.91 V AC open voltage, and a maximum power of 2 mW, amplifying the relative proof mass velocity by approximately 5.4 times. In addition, a mathematical model is created based on the pseudo-rigid-body dynamics and the analysis matches closely with experiments. The proposed harvester was designed using vibration data from nuclear power plants. Further steps for improving such a design are given for broader applications.

  9. Vacuum-packaged piezoelectric vibration energy harvesters: Damping contributions and autonomy for a wireless sensor system

    NARCIS (Netherlands)

    Elfrink, R.; Renaud, M.; Kamel, T.M.; Nooijer, C. de; Jambunathan, M.; Goedbloed, M.; Hohlfeld, D.; Matova, S.; Pop, V.; Caballero, L.; Schaijk, R. van

    2010-01-01

    This paper describes the characterization of thin-film MEMS vibration energy harvesters based on aluminum nitride as piezoelectric material. A record output power of 85 μW is measured. The parasitic-damping and the energy-harvesting performances of unpackaged and packaged devices are investigated.

  10. Energy-autonomous wireless vibration sensor for condition-based maintenance of machinery

    NARCIS (Netherlands)

    Wang, Z.; Bouwens, F.; Vullers, R.; Petré, F.; Devos, S.

    2011-01-01

    This paper addresses the development of an energy-autonomous wireless vibration sensor for condition-based monitoring of machinery. Such technology plays an increasingly important role in modern manufacturing industry. In this work, energy harvesting is realized by resorting to a custom designed

  11. Effect of the gel elasticity of model skin matrices on the distance/depth-dependent transmission of vibration energy supplied from a cosmetic vibrator.

    Science.gov (United States)

    Jeong, M K; Hwang, C; Nam, H; Cho, Y S; Kang, B Y; Cho, E C

    2017-02-01

    The purpose of this study was to determine how the energies supplied from a cosmetic vibrator are deeply or far transferred into organs and tissues, and how these depths or distances are influenced by tissue elasticity. External vibration energy was applied to model skin surfaces through a facial cleansing vibrator, and we measured a distance- and depth-dependent energy that was transferred to model skin matrices. As model skin matrices, we synthesized hard and soft poly(dimethylsiloxane) (PDMS) gels, as well as hydrogels with a modulus of 2.63 MPa, 0.33 MPa and 21 kPa, respectively, mostly representing those of skin and other organs. The transfer of vibration energy was measured either by increasing the separation distances or by increasing the depth from the vibrator. The energies were transmitted deeper into the hard PDMS than into the soft PDMS and hydrogel matrices. This finding implies that the vibration forces influence a larger area of the gel matrices when the gels are more elastic (or rigid). There were no appreciable differences between the soft PDMS and hydrogel matrices. However, the absorbed energies were more concentrated in the area closest to the vibrator with decreasing elasticity of the matrix. Softer materials absorbed most of the supplied energy around the point of the vibrator. In contrast, harder materials scattered the external energy over a broad area. The current results are the first report in estimating how the external energy is deeply or distantly transferred into a model skins depending on the elastic moduli of the models skins. In doing so, the results would be potentially useful in predicting the health of cells, tissues and organs exposed to various stimuli. © 2016 Society of Cosmetic Scientists and the Société Française de Cosmétologie.

  12. Electrostatic interaction between Interball-2 and the ambient plasma. 2. Influence on the low energy ion measurements with Hyperboloid

    Directory of Open Access Journals (Sweden)

    M. Hamelin

    Full Text Available The measurement of the thermal ion distributions in space is always strongly influenced by the ion motion through the complex 3D electrostatic potential structure built around a charged spacecraft. In this work, we study the related aberrations of the ion distribution detected on board, with special application to the case of the Hyperboloid instrument borne by the Interball-2 auroral satellite. Most of the time, the Interball-2 high altitude auroral satellite is charged at some non-negligible positive potential with respect to the ambient plasma, as shown in part 1; in consequence, the measurement of magnetospheric low energy ions (< 80 eV with the Hyperboloid instrument can be disturbed by the complex electric potential environment of the satellite. In the case of positive charging, as in previous experiments, a negative bias is applied to the Hyperboloid structure in order to reduce this effect and to keep as much as possible the opportunity to detect very low energy ions. Then, the ions reaching the Hyperboloid entrance windows would have travelled across a continuous huge electrostatic lens involving various spatial scales from ~ 10 cm (detector radius to ~ 10 m (satellite antennas. Neglecting space charge effects, we have computed the ion trajectories that are able to reach the Hyperboloid windows within their acceptance angles. There are three main results: (i for given values of the satellite potential, and for each direction of arrival (each window, we deduced the related energy cutoff; (ii we found that all ions in the energy channel, including the cutoff, can come from a large range of directions in the unperturbed plasma, especially when the solar panels or antennas act as electrostatic mirrors; (iii for higher energy channels, the disturbances are reduced to small angular shifts. Biasing of the aperture is not very effective with the Hyperboloid instrument (as on previous missions with instruments installed close to the spacecraft

  13. Electrostatic interaction between Interball-2 and the ambient plasma. 2. Influence on the low energy ion measurements with Hyperboloid

    Directory of Open Access Journals (Sweden)

    M. Hamelin

    2002-03-01

    Full Text Available The measurement of the thermal ion distributions in space is always strongly influenced by the ion motion through the complex 3D electrostatic potential structure built around a charged spacecraft. In this work, we study the related aberrations of the ion distribution detected on board, with special application to the case of the Hyperboloid instrument borne by the Interball-2 auroral satellite. Most of the time, the Interball-2 high altitude auroral satellite is charged at some non-negligible positive potential with respect to the ambient plasma, as shown in part 1; in consequence, the measurement of magnetospheric low energy ions (< 80 eV with the Hyperboloid instrument can be disturbed by the complex electric potential environment of the satellite. In the case of positive charging, as in previous experiments, a negative bias is applied to the Hyperboloid structure in order to reduce this effect and to keep as much as possible the opportunity to detect very low energy ions. Then, the ions reaching the Hyperboloid entrance windows would have travelled across a continuous huge electrostatic lens involving various spatial scales from ~ 10 cm (detector radius to ~ 10 m (satellite antennas. Neglecting space charge effects, we have computed the ion trajectories that are able to reach the Hyperboloid windows within their acceptance angles. There are three main results: (i for given values of the satellite potential, and for each direction of arrival (each window, we deduced the related energy cutoff; (ii we found that all ions in the energy channel, including the cutoff, can come from a large range of directions in the unperturbed plasma, especially when the solar panels or antennas act as electrostatic mirrors; (iii for higher energy channels, the disturbances are reduced to small angular shifts. Biasing of the aperture is not very effective with the Hyperboloid instrument (as on previous missions with instruments installed close to the spacecraft

  14. Importance of energy and angular resolutions in top-hat electrostatic analysers for solar wind proton measurements

    Science.gov (United States)

    De Marco, R.; Marcucci, M. F.; Bruno, R.; D'Amicis, R.; Servidio, S.; Valentini, F.; Lavraud, B.; Louarn, P.; Salatti, M.

    2016-08-01

    We use a numerical code which reproduces the angular/energy response of a typical top-hat electrostatic analyser starting from solar wind proton velocity distribution functions (VDFs) generated by numerical simulations. The simulations are based on the Hybrid Vlasov-Maxwell numerical algorithm which integrates the Vlasov equation for the ion distribution function, while the electrons are treated as a fluid. A virtual satellite launched through the simulation box measures the particle VDFs. Such VDFs are moved from the simulation Cartesian grid to energy-angular coordinates to mimic the response of a real sensor in the solar wind. Different energy-angular resolutions of the analyser are investigated in order to understand the influence of the phase-space resolution in existing and upcoming space missions, with regards to determining the key parameters of plasma dynamics.

  15. Development of Absorbed Blasting Vibration Energy Index for the Evaluation of Human Comfort in Multistorey Buildings

    Directory of Open Access Journals (Sweden)

    Qiang Yao

    2017-01-01

    Full Text Available There have been civil disputes and complaints regarding the negative effects of blasting vibration on buildings around the blasting site. By considering the effect of blasting vibration on a human body as a process of energy transfer and conversion, the human body absorbed blasting vibration energy (ABVE index has been developed for comfort evaluation. Using dynamic monitoring and theoretical analysis, the elevation amplification effect and selective amplification effect on different frequency components of the ABVE have been investigated. The elevation amplification factor and selective amplification coefficients on different frequency components of the ABVE index for a typical 4-storey brick and concrete building have been determined. Based on the results, the magnitude and frequency components of the ABVE index in different parts especially in different storeys for the typical building have been determined. According to the characteristics of human body’s response to vibrations of different frequencies, the frequency-based weighting method of ABVE index has been simplified. By calculating the combined effect of vibrations from all directions, the total human body ABVE and its frequency components at different floors of the building can be determined accurately. This can be used to evaluate the human body comfort against blasting vibration at different floors.

  16. A Hybrid Indoor Ambient Light and Vibration Energy Harvester for Wireless Sensor Nodes

    Directory of Open Access Journals (Sweden)

    Hua Yu

    2014-05-01

    Full Text Available To take advantage of applications where both light and vibration energy are available, a hybrid indoor ambient light and vibration energy harvesting scheme is proposed in this paper. This scheme uses only one power conditioning circuit to condition the combined output power harvested from both energy sources so as to reduce the power dissipation. In order to more accurately predict the instantaneous power harvested from the solar panel, an improved five-parameter model for small-scale solar panel applying in low light illumination is presented. The output voltage is increased by using the MEMS piezoelectric cantilever arrays architecture. It overcomes the disadvantage of traditional MEMS vibration energy harvester with low voltage output. The implementation of the maximum power point tracking (MPPT for indoor ambient light is implemented using analog discrete components, which improves the whole harvester efficiency significantly compared to the digital signal processor. The output power of the vibration energy harvester is improved by using the impedance matching technique. An efficient mechanism of energy accumulation and bleed-off is also discussed. Experiment results obtained from an amorphous-silicon (a-Si solar panel of 4.8 × 2.0 cm2 and a fabricated piezoelectric MEMS generator of 11 × 12.4 mm2 show that the hybrid energy harvester achieves a maximum efficiency around 76.7%.

  17. Research on vibration signal of engine based on subband energy method

    Science.gov (United States)

    Wu, Chunmei; Cui, Feng; Zhao, Yong; Fu, Baohong; Ma, Junchi; Yang, Guihua

    2017-04-01

    Based on the research of DA462 type engine cylinder and cylinder head vibration signal of the surface, the signal measured in the time domain and frequency domain are analyzed in detail, draw the following conclusions: the analysis of vibration signal of the subband energy method is applied to the engine, the concentration response of each of the motivation band can clearly be seen. Through the analysis we can see that the combustion excitation frequency response from 0k to 1K, the vibration influence on the body piston lateral impact force is mainly concentrated in 2K˜5K frequency range of Hz, valve opening and closing the excitation response frequency is mainly concentrated in the 3K˜4K range of Hz, and thus locating the valve clearance fault. This method is simple, accurate and practical for the post processing and analysis of vibration signals.

  18. Use of wavelet energy for spinal cord vibration analysis during spinal surgery.

    Science.gov (United States)

    Dai, Yu; Zhang, Jianxun; Xue, Yuan

    2013-12-01

    An online non-contact measurement system using a laser displacement sensor was developed for obtaining the vibration amplitude of spinal cord and hard tissue. The discrete wavelet transform was used to extract the distinctive features of tissue vibration signals. The spinal cord and spinal cancellous bone can be discriminated by the comparison of wavelet energy over a characteristic scale. We also derived the integro-differential equation of motion to describe the spinal cord vibration excited by the motion of bone. Experimental results show that the method works well in identifying spinal cord and bone. However, available viscoelastic constants cannot describe the high-frequency features of spinal cord. The examined issue of tissue vibration due to the operation power device is a significant problem. The proposed method can be used by a surgery robot, and then spinal surgery may greatly benefit from the enhanced safety of robotics. Copyright © 2012 John Wiley & Sons, Ltd.

  19. Vibration-based Energy Harvesting Systems Characterization Using Automated Electronic Equipment

    Directory of Open Access Journals (Sweden)

    Ioannis KOSMADAKIS

    2015-04-01

    Full Text Available A measurement bench has been developed to fully automate the procedure for the characterization of a vibration-based energy scavenging system. The measurement system is capable of monitoring all important characteristics of a vibration harvesting system (input and output voltage, current, and other parameters, frequency and acceleration values, etc.. It is composed of a PC, typical digital measuring instruments (oscilloscope, waveform generator, etc., certain sensors and actuators, along with a microcontroller based automation module. The automation of the procedure and the manipulation of the acquired data are performed by LabVIEW software. Typical measurements of a system consisting of a vibrating source, a vibration transducer and an active rectifier are presented.

  20. Analysis of vibrational-translational energy transfer using the direct simulation Monte Carlo method

    Science.gov (United States)

    Boyd, Iain D.

    1991-01-01

    A new model is proposed for energy transfer between the vibrational and translational modes for use in the direct simulation Monte Carlo method (DSMC). The model modifies the Landau-Teller theory for a harmonic oscillator and the rate transition is related to an experimental correlation for the vibrational relaxation time. Assessment of the model is made with respect to three different computations: relaxation in a heat bath, a one-dimensional shock wave, and hypersonic flow over a two-dimensional wedge. These studies verify that the model achieves detailed balance, and excellent agreement with experimental data is obtained in the shock wave calculation. The wedge flow computation reveals that the usual phenomenological method for simulating vibrational nonequilibrium in the DSMC technique predicts much higher vibrational temperatures in the wake region.

  1. Energy harvesting from coherent resonance of horizontal vibration of beam excited by vertical base motion

    Energy Technology Data Exchange (ETDEWEB)

    Lan, C. B.; Qin, W. Y. [Department of Engineering Mechanics, Northwestern Polytechnical University, Xi' an 710072 (China)

    2014-09-15

    This letter investigates the energy harvesting from the horizontal coherent resonance of a vertical cantilever beam subjected to the vertical base excitation. The potential energy of the system has two symmetric potential wells. So, under vertical excitation, the system can jump between two potential wells, which will lead to the large vibration in horizontal direction. Two piezoelectric patches are pasted to harvest the energy. From experiment, it is found that the vertical excitation can make the beam turn to be bistable. The system can transform vertical vibration into horizontal vibration of low frequency when excited by harmonic motion. The horizontal coherence resonance can be observed when excited by a vertical white noise. The corresponding output voltages of piezoelectric films reach high values.

  2. Van der Waals potential and vibrational energy levels of the ground state radon dimer

    Science.gov (United States)

    Sheng, Xiaowei; Qian, Shifeng; Hu, Fengfei

    2017-08-01

    In the present paper, the ground state van der Waals potential of the Radon dimer is described by the Tang-Toennies potential model, which requires five essential parameters. Among them, the two dispersion coefficients C6 and C8 are estimated from the well determined dispersion coefficients C6 and C8 of Xe2. C10 is estimated by using the approximation equation that C6C10/C82 has an average value of 1.221 for all the rare gas dimers. With these estimated dispersion coefficients and the well determined well depth De and Re the Born-Mayer parameters A and b are derived. Then the vibrational energy levels of the ground state radon dimer are calculated. 40 vibrational energy levels are observed in the ground state of Rn2 dimer. The last vibrational energy level is bound by only 0.0012 cm-1.

  3. Relaxation dynamics and coherent energy exchange in coupled vibration-cavity polaritons (Conference Presentation)

    Science.gov (United States)

    Simpkins, Blake S.; Fears, Kenan P.; Dressick, Walter J.; Dunkelberger, Adam D.; Spann, Bryan T.; Owrutsky, Jeffrey C.

    2016-09-01

    Coherent coupling between an optical transition and confined optical mode have been investigated for electronic-state transitions, however, only very recently have vibrational transitions been considered. Here, we demonstrate both static and dynamic results for vibrational bands strongly coupled to optical cavities. We experimentally and numerically describe strong coupling between a Fabry-Pérot cavity and carbonyl stretch ( 1730 cm 1) in poly-methylmethacrylate and provide evidence that the mixed-states are immune to inhomogeneous broadening. We investigate strong and weak coupling regimes through examination of cavities loaded with varying concentrations of a urethane monomer. Rabi splittings are in excellent agreement with an analytical description using no fitting parameters. Ultrafast pump-probe measurements reveal transient absorption signals over a frequency range well-separated from the vibrational band, as well as drastically modified relaxation rates. We speculate these modified kinetics are a consequence of the energy proximity between the vibration-cavity polariton modes and excited state transitions and that polaritons offer an alternative relaxation path for vibrational excitations. Varying the polariton energies by angle-tuning yields transient results consistent with this hypothesis. Furthermore, Rabi oscillations, or quantum beats, are observed at early times and we see evidence that these coherent vibration-cavity polariton excitations impact excited state population through cavity losses. Together, these results indicate that cavity coupling may be used to influence both excitation and relaxation rates of vibrations. Opening the field of polaritonic coupling to vibrational species promises to be a rich arena amenable to a wide variety of infrared-active bonds that can be studied in steady state and dynamically.

  4. Piezoelectric Vibration Energy Harvesting Device Combined with Damper

    Directory of Open Access Journals (Sweden)

    Hung-I Lu

    2014-05-01

    Full Text Available Piezoelectricity is a type of material that enables mechanical energy and electrical energy to be interchangeable, which can be divided into positive piezoelectric effect and inverse piezoelectric effect. The positive piezoelectric effect is that the electric dipole moment of material generates changes when the piezoelectric material is subjected to pressure, resulting in electrical energy. Conversely, the inverse piezoelectric effect is the process of electrical energy converted into mechanical energy.

  5. A miniaturised, nested-cylindrical electrostatic analyser geometry for dual electron and ion, multi-energy measurements

    Energy Technology Data Exchange (ETDEWEB)

    Bedington, Robert, E-mail: r.bedington@nus.edu.sg; Kataria, Dhiren; Smith, Alan

    2015-09-01

    The CATS (Cylindrical And Tiny Spectrometer) electrostatic optics geometry features multiple nested cylindrical analysers to simultaneously measure multiple energies of electron and multiple energies of ion in a configuration that is targeted at miniaturisation and MEMS fabrication. In the prototyped model, two configurations of cylindrical analyser were used, featuring terminating side-plates that caused particle trajectories to either converge (C type) or diverge (D type) in the axial direction. Simulations show how these different electrode configurations affect the particle focussing and instrument parameters; C-type providing greater throughputs but D-type providing higher resolving powers. The simulations were additionally used to investigate unexpected plate spacing variations in the as-built model, revealing that the k-factors are most sensitive to the width of the inter-electrode spacing at its narrowest point. - Highlights: • A new nested cylindrical miniaturised electrostatic analyser geometry is described. • “Converging” (C) and “diverging” (D) type channel properties are investigated. • C channels are shown to have greater throughputs and D greater resolving powers. • Plate factors are shown to be sensitive to the minimum in inter-electrode spacing.

  6. Dual resonant structure for energy harvesting from random vibration sources at low frequency

    Directory of Open Access Journals (Sweden)

    Shanshan Li

    2016-01-01

    Full Text Available We introduce a design with dual resonant structure which can harvest energy from random vibration sources at low frequency range. The dual resonant structure consists of two spring-mass subsystems with different frequency responses, which exhibit strong coupling and broad bandwidth when the two masses collide with each other. Experiments with piezoelectric elements show that the energy harvesting device with dual resonant structure can generate higher power output than the sum of the two separate devices from random vibration sources.

  7. Analysis of bifurcation behavior of a piecewise linear vibrator with electromagnetic coupling for energy harvesting applications

    KAUST Repository

    El Aroudi, Abdelali

    2014-05-01

    Recently, nonlinearities have been shown to play an important role in increasing the extracted energy of vibration-based energy harvesting systems. In this paper, we study the dynamical behavior of a piecewise linear (PWL) spring-mass-damper system for vibration-based energy harvesting applications. First, we present a continuous time single degree of freedom PWL dynamical model of the system. Different configurations of the PWL model and their corresponding state-space regions are derived. Then, from this PWL model, extensive numerical simulations are carried out by computing time-domain waveforms, state-space trajectories and frequency responses under a deterministic harmonic excitation for different sets of system parameter values. Stability analysis is performed using Floquet theory combined with Filippov method, Poincaré map modeling and finite difference method (FDM). The Floquet multipliers are calculated using these three approaches and a good concordance is obtained among them. The performance of the system in terms of the harvested energy is studied by considering both purely harmonic excitation and a noisy vibrational source. A frequency-domain analysis shows that the harvested energy could be larger at low frequencies as compared to an equivalent linear system, in particular, for relatively low excitation intensities. This could be an advantage for potential use of this system in low frequency ambient vibrational-based energy harvesting applications. © 2014 World Scientific Publishing Company.

  8. A Design Study Of A Wireless Power Transfer System For Use To Transfer Energy From A Vibration Energy Harvester

    Science.gov (United States)

    Grabham, N. J.; Harden, C.; Vincent, D.; Beeby, S. P.

    2016-11-01

    A wirelessly powered remote sensor node is presented along with its design process. The purpose of the node is the further expansion of the sensing capabilities of the commercial Perpetuum system used for condition monitoring on trains and rolling stock which operates using vibration energy harvesting. Surplus harvested vibration energy is transferred wirelessly to a remote satellite sensor to allow measurements over a wider area to be made. This additional data is to be used for long term condition monitoring. Performance measurements made on the prototype remote sensor node are reported and advantages and disadvantages of using the same RF frequency for power and data transfer are identified.

  9. Iron oxide/aluminum/graphene energetic nanocomposites synthesized by atomic layer deposition: Enhanced energy release and reduced electrostatic ignition hazard

    Energy Technology Data Exchange (ETDEWEB)

    Yan, Ning; Qin, Lijun [Laboratory of Material Surface Engineering and Nanofabrication, Xi’an Modern Chemistry Research Institute, Shaanxi (China); Science and Technology on Combustion and Explosion Laboratory, Xi’an Modern Chemistry Research Institute, Shaanxi (China); Hao, Haixia [Science and Technology on Combustion and Explosion Laboratory, Xi’an Modern Chemistry Research Institute, Shaanxi (China); Hui, Longfei [Laboratory of Material Surface Engineering and Nanofabrication, Xi’an Modern Chemistry Research Institute, Shaanxi (China); Science and Technology on Combustion and Explosion Laboratory, Xi’an Modern Chemistry Research Institute, Shaanxi (China); Zhao, Fengqi [Science and Technology on Combustion and Explosion Laboratory, Xi’an Modern Chemistry Research Institute, Shaanxi (China); Feng, Hao, E-mail: fenghao98@hotmail.com [Laboratory of Material Surface Engineering and Nanofabrication, Xi’an Modern Chemistry Research Institute, Shaanxi (China); State Key Laboratory of Fluorine and Nitrogen Chemicals, Xi’an Modern Chemistry Research Institute, Shaanxi (China)

    2017-06-30

    Highlights: • Energetic rGO/Al@Fe{sub 2}O{sub 3}nanocompositeswerefabricatedbyatomiclayerdepositionapproach. • A novel Al@Fe{sub 2}O{sub 3} unit featuring core-shell structure was decorated on the graphene nanosheet. • RGO/Al@Fe{sub 2}O{sub 3} nanocomposite exhibits superior energy release and reduced electrostatic ignition hazard. - Abstract: Nanocomposites consisting of iron oxide (Fe{sub 2}O{sub 3}) and nano-sized aluminum (Al), possessing outstanding exothermic redox reaction characteristics, are highly promising nanothermite materials. However, the reactant diffusion inhibited in the solid state system makes the fast and complete energy release very challenging. In this work, Al nanoparticles anchored on graphene oxide (GO/Al) was initially prepared by a solution assembly approach. Fe{sub 2}O{sub 3} was deposited on GO/Al substrates by atomic layer deposition (ALD). Simultaneously thermal reduction of GO occurs, resulting in rGO/Al@Fe{sub 2}O{sub 3} energetic composites. Differential scanning calorimetry (DSC) analysis reveals that rGO/Al@Fe{sub 2}O{sub 3} composite containing 4.8 wt% of rGO exhibits a 50% increase of the energy release compared to the Al@Fe{sub 2}O{sub 3} nanothermite synthesized by ALD, and an increase of about 130% compared to a random mixture of rGO/Al/Fe{sub 2}O{sub 3} nanoparticles. The enhanced energy release of rGO/Al@Fe{sub 2}O{sub 3} is attributed to the improved spatial distribution as well as the increased interfacial intimacy between the oxidizer and the fuel. Moreover, the rGO/Al@Fe{sub 2}O{sub 3} composite with an rGO content of 9.6 wt% exhibits significantly reduced electrostatic discharge sensitivity. These findings may inspire potential pathways for engineering energetic nanocomposites with enhanced energy release and improved safety characteristics.

  10. Electrostatic energy harvesting device with out-of-the-plane gap closing scheme

    DEFF Research Database (Denmark)

    Wang, Fei; Hansen, Ole

    2014-01-01

    as an electret material and an adhesive layer for low temperature wafer bonding. The overall size of the device is about 1.1 cm × 1.3 cm. At an external load resistance of 13.4 MΩ, a power output of 0.15 μW is achieved when vibration at an acceleration amplitude of 1 g (∼9.8 m/s2) is applied at a low frequency...

  11. Electrostatic energy harvesting device with out-of-the-plane gap closing scheme

    DEFF Research Database (Denmark)

    Wang, Fei; Hansen, Ole

    2013-01-01

    and an adhesive layer for low temperature wafer bonding. The overall size of the device is about 1.1×1.3 cm2. With an external load of 13.4 MΩ, a power output of 0.15 μW is achieved when vibration at an acceleration amplitude of 1 g (9.8 m/s2) is applied at a low frequency of 96 Hz. The frequency response...

  12. State-To Rotational and Vibrational Energy Transfers Following Vibrational Excitation of (1010000) and (0112000) in the Ground Electronic State of Acetylene

    Science.gov (United States)

    Han, Jiande; Freel, Keith; Heaven, Michael C.

    2011-06-01

    We have examined state-to-state rotational and vibrational energy transfers for the vibrational levels (1010000) and (0112000) of C2H2 in the ground electronic state at ambient temperature. Measurements were made using a pulsed IR - UV double resonance technique. Total removal rate constants and state-to-state rotational energy transfer rate constants have been characterized for certain even-numbered rotational levels from J = 0 to 12 within the two vibrational modes. The measured state-to-state rotational energy transfer rate constants were fit to some energy-based empirical scaling and fitting laws, and the rate constants were found to be best reproduced by the statistical power-exponential gap law (PEGL). The measured rate constants were then further evaluated by a kinetic model which simulated the experimental spectra by solving simultaneous first order differential rate equations. Some rotationally-resolved vibrational energy transfer channels were also observed following excitation of (1010000). The vibrational relaxation channels were found to contribute less than 30% to the total removal rate constants of the measured rotational levels for both of the studied vibrational states.

  13. A study on the reduction of nitric oxide molecule (NO) to nitroxyl anion (NO{sup -}) by vibrational energy

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Seon Woog [Silla Univ., Pusan (Korea, Republic of)

    2002-02-01

    It is shown that one-electron reduction of nitric oxide (NO) to nitroxyl anion (NO{sup -}) can be accelerated by vibrational energy. Potential energy surfaces of NO and NO{sup -} reveal that the vertical transition between them has favorable energetics for vibrationally excited molecule. Also, Franck-Condon factors between NO and NO{sup -} vibrational wave functions are calculated. It shows that the number of open channels increases with increased vibrational energy. These results mean that we can control the rate of reduction of NO to NO{sup -} by radiating an appropriate light.

  14. Protonation state and free energy calculation of HIV-1 protease-inhibitor complex based on electrostatic polarisation effect

    Science.gov (United States)

    Yang, Maoyou; Jiang, Xiaonan; Jiang, Ning

    2014-06-01

    The protonation states of catalytic Asp25/25‧ residues remarkably affect the binding mechanism of the HIV-1 protease-inhibitor complex. Here we report a molecular dynamics simulation study, which includes electrostatic polarisation effect, to investigate the influence of Asp25/25‧ protonation states upon the binding free energy of the HIV-1 protease and a C2-symmetric inhibitor. Good agreements are obtained on inhibitor structure, hydrogen bond network, and binding free energy between our theoretical calculations and the experimental data. The calculations show that the Asp25 residue is deprotonated, and the Asp25‧ residue is protonated. Our results reveal that the Asp25/25‧ residues can have different protonation states when binding to different inhibitors although the protease and the inhibitors have the same symmetry. This study offers some insights into understanding the protonation state of HIV-1 protease-inhibitor complex, which could be helpful in designing new inhibitor molecules.

  15. Three-dimensional piezoelectric vibration energy harvester using spiral-shaped beam with triple operating frequencies

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Nian; Yang, Jin, E-mail: yangjin@cqu.edu.cn; Yu, Qiangmo; Zhao, Jiangxin; Liu, Jun; Wen, Yumei; Li, Ping [Department of Optoelectronic Engineering, Chongqing University, Chongqing 400044 (China)

    2016-01-15

    This work has demonstrated a novel piezoelectric energy harvester without a complex structure and appended component that is capable of scavenging vibration energy from arbitrary directions with multiple resonant frequencies. In this harvester, a spiral-shaped elastic thin beam instead of a traditional thin cantilever beam was adopted to absorb external vibration with arbitrary direction in three-dimensional (3D) spaces owing to its ability to bend flexibly and stretch along arbitrary direction. Furthermore, multiple modes in the elastic thin beam contribute to a possibility to widen the working bandwidth with multiple resonant frequencies. The experimental results show that the harvester was capable of scavenging the vibration energy in 3D arbitrary directions; they also exhibited triple power peaks at about 16 Hz, 21 Hz, and 28 Hz with the powers of 330 μW, 313 μW, and 6 μW, respectively. In addition, human walking and water wave energies were successfully converted into electricity, proving that our harvester was practical to scavenge the time-variant or multi-directional vibration energies in our daily life.

  16. A small-form-factor piezoelectric vibration energy harvester using a resonant frequency-down conversion

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Kyung Ho; Kim, Young-Cheol [Department of System Dynamics, Korea Institute of Machinery and Materials, 156 Gajeongbuk-Ro, Yuseong-Gu, Daejeon 305-343 (Korea, Republic of); Kim, Jae Eun, E-mail: jekim@cu.ac.kr [School of Mechanical and Automotive Engineering, Catholic University of Daegu, 13-13 Hayang-Ro, Hayang-Eup, Gyeongsan-Si, Gyeongsangbuk-Do 712-702 (Korea, Republic of)

    2014-10-15

    While environmental vibrations are usually in the range of a few hundred Hertz, small-form-factor piezoelectric vibration energy harvesters will have higher resonant frequencies due to the structural size effect. To address this issue, we propose a resonant frequency-down conversion based on the theory of dynamic vibration absorber for the design of a small-form-factor piezoelectric vibration energy harvester. The proposed energy harvester consists of two frequency-tuned elastic components for lowering the first resonant frequency of an integrated system but is so configured that an energy harvesting beam component is inverted with respect to the other supporting beam component for a small form factor. Furthermore, in order to change the unwanted modal characteristic of small separation of resonant frequencies, as is the case with an inverted configuration, a proof mass on the supporting beam component is slightly shifted toward a second proof mass on the tip of the energy harvesting beam component. The proposed small-form-factor design capability was experimentally verified using a fabricated prototype with an occupation volume of 20 × 39 × 6.9 mm{sup 3}, which was designed for a target frequency of as low as 100 Hz.

  17. A small-form-factor piezoelectric vibration energy harvester using a resonant frequency-down conversion

    Directory of Open Access Journals (Sweden)

    Kyung Ho Sun

    2014-10-01

    Full Text Available While environmental vibrations are usually in the range of a few hundred Hertz, small-form-factor piezoelectric vibration energy harvesters will have higher resonant frequencies due to the structural size effect. To address this issue, we propose a resonant frequency-down conversion based on the theory of dynamic vibration absorber for the design of a small-form-factor piezoelectric vibration energy harvester. The proposed energy harvester consists of two frequency-tuned elastic components for lowering the first resonant frequency of an integrated system but is so configured that an energy harvesting beam component is inverted with respect to the other supporting beam component for a small form factor. Furthermore, in order to change the unwanted modal characteristic of small separation of resonant frequencies, as is the case with an inverted configuration, a proof mass on the supporting beam component is slightly shifted toward a second proof mass on the tip of the energy harvesting beam component. The proposed small-form-factor design capability was experimentally verified using a fabricated prototype with an occupation volume of 20 × 39 × 6.9 mm3, which was designed for a target frequency of as low as 100 Hz.

  18. A nonlinear multi-mode wideband piezoelectric vibration-based energy harvester using compliant orthoplanar spring

    Energy Technology Data Exchange (ETDEWEB)

    Dhote, Sharvari, E-mail: sharvari.dhote@mail.utoronto.ca; Zu, Jean; Zhu, Yang [Department of Mechanical and Industrial Engineering, University of Toronto, 5 King' s College Road, Toronto, Ontario M5S-3G8 (Canada)

    2015-04-20

    In this paper, a nonlinear wideband multi-mode piezoelectric vibration-based energy harvester (PVEH) is proposed based on a compliant orthoplanar spring (COPS), which has an advantage of providing multiple vibration modes at relatively low frequencies. The PVEH is made of a tri-leg COPS flexible structure, where three fixed-guided beams are capable of generating strong nonlinear oscillations under certain base excitation. A prototype harvester was fabricated and investigated through both finite-element analysis and experiments. The frequency response shows multiple resonance which corresponds to a hardening type of nonlinear resonance. By adding masses at different locations on the COPS structure, the first three vibration modes are brought close to each other, where the three hardening nonlinear resonances provide a wide bandwidth for the PVEH. The proposed PVEH has enhanced performance of the energy harvester in terms of a wide frequency bandwidth and a high-voltage output under base excitations.

  19. An analytical model for a piezoelectric vibration energy harvester with resonance frequency tunability

    Directory of Open Access Journals (Sweden)

    Yun Wang

    2015-06-01

    Full Text Available This article conceptually proposes a new method to tune the resonance frequency of piezoelectric vibration energy harvesters, in which the supporting position of the vibrator can be adjusted for frequency tuning. The corresponding analytical model is established to predict the performances of the harvester based on the principles of energy. First, the equivalent stiffness and mass of the vibrator in bending mode are derived explicitly for the different supporting positions. A simple analysis method is then established for the frequency, output voltage, and output power. Finally, some numerical examples are given to demonstrate the presented method. The results are also compared with those by finite element method and good agreement is observed.

  20. A Method to Assess Transverse Vibration Energy of Ship Propeller Shaft for Diagnostic Purposes

    Directory of Open Access Journals (Sweden)

    Korczewski Zbigniew

    2017-12-01

    Full Text Available The article discusses a key problem of ship propulsion system vibration diagnostics, which concerns assessing this part of mechanical energy transmitted from the main engine to the ship propeller which is dissipated due to propeller shaft vibration. A simplified calculation model is proposed which allows the total energy of the generated torsional vibration to be assessed from the shaft deflection amplitude measured at the mind-span point between the supports. To verify the developed model, pilot tests were performed on the laboratory rotational mechanical system test rig. In those tests, cyclic bending moment was applied to a unified (cylindrical material sample, which modelled, at an appropriate scale, structural and functional properties of a real propeller shaft.

  1. Design of mechanical metamaterials for simultaneous vibration isolation and energy harvesting

    Science.gov (United States)

    Li, Ying; Baker, Evan; Reissman, Timothy; Sun, Cheng; Liu, Wing Kam

    2017-12-01

    Through finite element analysis and a 3D printing assisted experimental study, we demonstrate a design of mechanical metamaterials for simultaneous mechanical wave filtering and energy harvesting. The mechanical metamaterials compromise a square array of free-standing cantilevers featuring piezoelectric properties being attached to a primary structural frame. A complete bandgap has thus been created via the strong coupling of the bulk elastic wave propagating along the structural frame and the distributed local resonance associated with the square array of piezoelectrically active cantilevers. Operating within the stop-band, external vibration energy has been trapped and transferred into the kinetic energy of the cantilevers, which is further converted into electric energy through mechano-electrical conversion of its integrated piezoelectric elements. Therefore, two distinct functions, vibration isolation and energy harvesting, are achieved simultaneously through the designed mechanical metamaterials.

  2. High-performance gap-closing vibrational energy harvesting using electret-polarized dielectric oscillators

    Science.gov (United States)

    Feng, Yue; Yu, Zejie; Han, Yanhui

    2018-01-01

    In conventional gap-closing electret-biased electrostatic energy harvesting (EEEH) schemes, electrets with a very low ratio of electret thickness to permittivity are in great demand to allow the attainment of high power output. However, in practice, pursuing such a low ratio introduces unwanted burdens on the electret stability and therefore the reliability of the EEEH devices. In this paper, we propose a dielectric-oscillator-based electrostatic EH (DEEH) scheme as an alternative approach to harvesting electret-biased electrostatic energy. This approach permits the fabrication of an electret-free closed EH circuit. The DEEH architecture directly collects the electrical energy exclusively through the oscillating dielectric body and thus completely circumvents the restrictions imposed by the electret parameters (thickness and permittivity) on power generation. Significantly, without considering the electret thickness and permittivity, both theoretical analysis and experiments have verified the effectiveness of this DEEH strategy, and a high figure of merit (on the order of 10-8 mW cm-2 V-2 Hz-1) was achieved for low-frequency movements.

  3. Simultaneous passive broadband vibration suppression and energy harvesting with multifunctional metastructures

    Science.gov (United States)

    Hobeck, Jared D.; Inman, Daniel J.

    2017-04-01

    The research presented in this paper focuses on a unique multifunctional structural design that not only absorbs vibration at desired frequency bands, but also extracts significant amounts of electrical energy. This is accomplished by first designing an array of low-frequency resonators to be integrated into a larger host structure. This array of resonators can contribute not only to static requirements, e.g., stiffness, strength, mass, etc., of the host structure but the array also functions as a distributed system of passive vibration absorbers. Structures having these distributed vibration absorber systems are known as metastructures. Here, the authors present a unique absorber design referred to as a zigzag beam, which can have a natural frequency an order of magnitude lower than that of a basic cantilever beam of the same scale. It will be shown that the zigzag beams can be designed with an added layer of piezoelectric material, which allows them to harvest significant amounts of electrical power as they suppress vibration of the host structure. This paper includes details of the fully-coupled electromechanical analytical and numerical models for energy harvesting metastructures. Experimental results used to validate the proposed modeling methods will be discussed. Lastly, results of a multi-objective design optimization will be presented and discussed. Results of the optimization study were able to show that allowing only an 82 % increase in the host structure vibration could yield more than a 1500 % increase in total power output. Other results show that the power output (or absorber motion) could be increased 241% without increasing host structure vibrations due to multiple design solutions existing at fixed host structure vibration levels.

  4. DIFFUSED SOLUTE-SOLVENT INTERFACE WITH POISSON-BOLTZMANN ELECTROSTATICS: FREE-ENERGY VARIATION AND SHARP-INTERFACE LIMIT.

    Science.gov (United States)

    Li, B O; Liu, Yuan

    A phase-field free-energy functional for the solvation of charged molecules (e.g., proteins) in aqueous solvent (i.e., water or salted water) is constructed. The functional consists of the solute volumetric and solute-solvent interfacial energies, the solute-solvent van der Waals interaction energy, and the continuum electrostatic free energy described by the Poisson-Boltzmann theory. All these are expressed in terms of phase fields that, for low free-energy conformations, are close to one value in the solute phase and another in the solvent phase. A key property of the model is that the phase-field interpolation of dielectric coefficient has the vanishing derivative at both solute and solvent phases. The first variation of such an effective free-energy functional is derived. Matched asymptotic analysis is carried out for the resulting relaxation dynamics of the diffused solute-solvent interface. It is shown that the sharp-interface limit is exactly the variational implicit-solvent model that has successfully captured capillary evaporation in hydrophobic confinement and corresponding multiple equilibrium states of underlying biomolecular systems as found in experiment and molecular dynamics simulations. Our phase-field approach and analysis can be used to possibly couple the description of interfacial fluctuations for efficient numerical computations of biomolecular interactions.

  5. Chaotic Dynamics-Based Analysis of Broadband Piezoelectric Vibration Energy Harvesting Enhanced by Using Nonlinearity

    Directory of Open Access Journals (Sweden)

    Zhongsheng Chen

    2016-01-01

    Full Text Available Nonlinear magnetic forces are always used to enlarge resonant bandwidth of vibration energy harvesting systems with piezoelectric cantilever beams. However, how to determine properly the distance between two magnets is one of the key engineering problems. In this paper, the Melnikov theory is introduced to overcome it. Firstly, the Melnikov state-space model of the nonlinear piezoelectric vibration energy harvesting (PVEH system is built. Based on it, chaotic dynamics mechanisms of achieving broadband PVEH by nonlinearity are exposed by potential function of the unperturbed nonlinear PVEH system. Then the corresponding Melnikov function of the nonlinear PVEH system is defined, based on which two Melnikov necessary conditions of determining the distance are obtained. Finally, numerical simulations are done to testify the theoretic results. The results demonstrate that the distance is closely related to the excitation amplitude and frequency once geometric and material parameters are fixed. Under a single-frequency excitation, the nonlinear PVEH system can generate a periodic vibration around a stable point, a large-amplitude vibration around two stable points, or a chaotic vibration. The proposed method is very valuable for optimally designing and utilizing nonlinear broadband PVEH devices in engineering applications.

  6. Zero-point energy, tunnelling, and vibrational adiabaticity in the Mu + H2 reaction

    Science.gov (United States)

    Mielke, Steven L.; Garrett, Bruce C.; Fleming, Donald G.; Truhlar, Donald G.

    2015-01-01

    Isotopic substitution of muonium for hydrogen provides an unparalleled opportunity to deepen our understanding of quantum mass effects on chemical reactions. A recent topical review in this journal of the thermal and vibrationally state-selected reaction of Mu with H2 raises a number of issues that are addressed here. We show that some earlier quantum mechanical calculations of the Mu + H2 reaction, which are highlighted in this review, and which have been used to benchmark approximate methods, are in error by as much as 19% in the low-temperature limit. We demonstrate that an approximate treatment of the Born-Oppenheimer diagonal correction that was used in some recent studies is not valid for treating the vibrationally state-selected reaction. We also discuss why vibrationally adiabatic potentials that neglect bend zero-point energy are not a useful analytical tool for understanding reaction rates, and why vibrationally non-adiabatic transitions cannot be understood by considering tunnelling through vibrationally adiabatic potentials. Finally, we present calculations on a hierarchical family of potential energy surfaces to assess the sensitivity of rate constants to the quality of the potential surface.

  7. Vibrational energy transfer in gas phase water and ammonia

    Energy Technology Data Exchange (ETDEWEB)

    Hovis, F.E. Jr.

    1979-09-01

    The V ..-->.. T, R relaxation rate for NH/sub 3/ (..nu../sub 2/) was studied from 198/sup 0/K to 398/sup 0/K by the method of laser-excited vibrational fluorescence. The self-deactivation rate constant decreases from 2.4 ..mu..sec torr/sup -1/ at 198/sup 0/K to 0.65 ..mu..sec/sup -1/ torr/sup -1/ at 398/sup 0/K. The rate constants for deactivation by He, Ar, N/sub 2/, and O/sub 2/ are much smaller and show a weak temperature dependence in the opposite direction. The vibrational relaxation rates of the coupled ..nu../sub 1/, ..nu../sub 3/ stretching level manifold and of the 2..nu../sub 2/ bending level in H/sub 2//sup 18/O was studied from 250/sup 0/K to 400/sup 0/K using th same method as for NH/sub 3/. The ..nu../sub 1/, ..nu../sub 3/ self-deactivation rate goes from 1.4 ..mu..sec/sup -1/ torr/sup -1/ at 250/sup 0/K to 0.48 ..mu..sec-/sup 1/ torr-/sup 1/ at 400/sup 0/K. For 2..nu../sub 2/ it goes from 4.5 ..mu..sec-/sup 1/ torr to 1.9 ..mu..sec/sup -1/ torr/sup -1/. The temperature dependence of the deactivation of both levels by He and Ar is much weaker and the rates are several hundred times slower. Deactivation of ..nu../sub 1/, ..nu../sub 3/ by N/sub 2/, O/sub 2/, and CO/sub 2/ is measured only at 293/sup 0/K. N/sub 2/ and O/sub 2/ deactivate ..nu../sub 1/, ..nu../sub 3/ about 5 and CO/sub 2/ about 50 times faster than He or Ar.

  8. A resonant electromagnetic vibration energy harvester for intelligent wireless sensor systems

    Energy Technology Data Exchange (ETDEWEB)

    Qiu, Jing, E-mail: jingqiu@cqu.edu.cn; Wen, Yumei; Li, Ping; Liu, Xin; Chen, Hengjia; Yang, Jin [Sensors and Instruments Research Center, College of Optoelectronic Engineering, Chongqing University, Chongqing 400044 (China)

    2015-05-07

    Vibration energy harvesting is now receiving more interest as a means for powering intelligent wireless sensor systems. In this paper, a resonant electromagnetic vibration energy harvester (VEH) employing double cantilever to convert low-frequency vibration energy into electrical energy is presented. The VEH is made up of two cantilever beams, a coil, and magnetic circuits. The electric output performances of the proposed electromagnetic VEH have been investigated. With the enhancement of turns number N, the optimum peak power of electromagnetic VEH increases sharply and the resonance frequency deceases gradually. When the vibration acceleration is 0.5 g, we obtain the optimum output voltage and power of 9.04 V and 50.8 mW at frequency of 14.9 Hz, respectively. In a word, the prototype device was successfully developed and the experimental results exhibit a great enhancement in the output power and bandwidth compared with other traditional electromagnetic VEHs. Remarkably, the proposed resonant electromagnetic VEH have great potential for applying in intelligent wireless sensor systems.

  9. Density of low-energy vibrational states in a protein solution

    Science.gov (United States)

    Brill, A. S.; Fiamingo, F. G.; Hampton, D. A.; Levin, P. D.; Thorkildsen, R.

    1985-04-01

    Electron paramagnetic resonance measurements on the aquo complex of sperm whale skeletal myoglobin in solution at T<4 K show that, at phonon energies around 20 cm-1, the density of vibrational states is that of a three-dimensional system.

  10. A smart and self-sufficient frequency tunable vibration energy harvester

    Science.gov (United States)

    Eichhorn, C.; Tchagsim, R.; Wilhelm, N.; Woias, P.

    2011-10-01

    We present a piezoelectric energy-harvesting system, which is able to self-tune its resonance frequency in an energy-autonomous way, in order to extend its efficient operation over a large frequency range. The system consists of a resonant and frequency-tunable piezoelectric generator and a control unit. In predefined temporal intervals, the control unit analyzes the ambient vibration frequency, decides whether an adjustment of the generator's resonance frequency is necessary or not and delivers the appropriate voltage to a piezoelectric actuator which alters the generator's mechanical stiffness to tune its resonance frequency. The control unit has been optimized to an ultralow power consumption which means that up to 90% of the harvested energy can be fed to the powered electrical load, which could be an embedded system. With frequency-tunable generators, the application range of vibration energy harvesters can be extended to environments with a non-constant vibration frequency, like e.g. the surface of an engine with a varying number of revolutions per minute. Furthermore, the presented system opens the door to off-the-shelf solutions for environments with constant but uncommon vibration frequencies. With the smart tuning algorithm presented in this work, our system is even able to compensate typical weak points of piezoelectrically tunable harvesters, like e.g. hysteresis effects, the temperature dependence of the mechanical stiffness and aging effects.

  11. Compact and Low-Frequency Vibration Energy Scavenger using the longitudinal excitation of a piezoelectric bar

    Science.gov (United States)

    Colin, M.; Mortier, Q.; Basrour, S.; Bencheikh, N.

    2013-12-01

    This paper introduces an innovative architecture of a piezoelectric harvester, which enables harvesting vibration energy at low frequency using the {33}-transduction mode of a piezoelectric element. Unlike cantilevers integrating ferroelectric material combined with interdigitated electrodes, the concept that we propose is based on the elongation/compression excitation of a piezoelectric bar.

  12. Analytical, FEA, and Experimental Comparisons of Piezoelectric Energy Harvesting Using Engine Vibrations

    Directory of Open Access Journals (Sweden)

    Abhay Khalatkar

    2014-01-01

    Full Text Available Piezoelectric elements can be used as sensors and actuators in flexible structures. In this paper, using the most basic concepts of piezoelectric micropower generators, all useful mathematical equations for getting analytical output are discussed and derived for different piezo positions on cantilever beam and then 3D finite element modeling and simulation of generalized piezoelectric laminated beam problem with proper specifications and properties are done in ANSYS12.0. Experimental analysis is also done on the very practical problem to harvest energy (to get electric energy by applying some deflection (mechanical energy on piezo-bonded aluminum beam, that is, to harvest energy (at microlevel at least by using vibrations of 4-stroke car diesel engine with mounting of piezo cantilever beam. Here piezoelectric beam is used to measure the charge generated from the engine vibrations. The vibration amplitudes are measured with a Laser Vibrometer with considerations of maximum number of power cycles is to be covered for analysis. The vibration response data of displacement of the cantilever at free end measured from Vibrometer are considered for harmonic and analytical analyses as mean displacement amplitude of 3.98 mm at free end. The study further carried out for effect of different piezo positions and various engine speeds also. Then comparison is also done among obtained results from these three analyses to get validation of all derived mathematical equations.

  13. Vibration based structural health monitoring in fibre reinforced composites employing the modal strain energy method

    NARCIS (Netherlands)

    Loendersloot, Richard; Ooijevaar, T.H.; Warnet, Laurent; Akkerman, Remko; de Boer, Andries; Meguid, S.A.; Gomes, J.F.S.

    2009-01-01

    The feasibility of a vibration based damage identification method is investigated. The Modal Strain Energy method is applied to a T–beam structure. The dynamic response of an intact structure and a damaged, delaminated structure is analysed employing a commercially available Finite Element package.

  14. Based On Intrinsic Mode Function Energy Tracking Method of Circuit Breaker Vibration Signal Feature Extraction Studies

    Directory of Open Access Journals (Sweden)

    Sun Yi-Hang

    2017-01-01

    Full Text Available In order to detect a mechanical type of structural failure of the circuit breaker, the characteristics of the circuit breaker mechanical vibration signal is analyzed in this paper. A combination of medium voltage circuit breaker based on empirical mode decomposition (EMD amount of energy and support vector machine (SVM theory vibration signal feature vector extraction and analysis of fault classification method is proposed. First, the vibration signal of the circuit breaker is decomposed by EMD, then intrinsic mode function (IMF is obtain. The major fault feature information intrinsic mode functions the amount of energy of the component is obtained by discrete sampling points and the amount of energy. Using the amount of energy of IMF component as a feature vector, the failure of the test sample signal as input feature vector into trained “BT-SVM” support vector machine classification mechanism for fault classification. The differences and fault type of vibration signals can be identified by this method through the experimental analysis.

  15. Hydrogen bonding and vibrational energy relaxation in water-acetonitrile mixtures

    NARCIS (Netherlands)

    Cringus, D; Yeremenko, S; Pshenichnikov, MS; Wiersma, DA; Pshenichnikov, Maxim S.

    2004-01-01

    We present a study of the effect of hydrogen bonding on vibrational energy relaxation of the OH-stretching mode in pure water and in water-acetonitrile mixtures. The extent of hydrogen bonding is controlled by dissolving water at various concentrations in acetonitrile. Infrared frequency-resolved

  16. Energy trapping of thickness-shear vibration modes of elastic plates with functionally graded materials.

    Science.gov (United States)

    Wang, Ji; Yang, Jiashi; Li, Jiangyu

    2007-03-01

    Energy trapping has important applications in the design of thickness-shear resonators. Considerable efforts have been made for the effective utilization and improvement of energy trapping with variations of plate configurations, such as adding electrodes and contouring. As a new approach in seeking improved energy trapping feature, we analyze thickness-shear vibrations in an elastic plate with functionally graded material (FGM) of in-plane variation of mechanical properties, such as elastic constants and density. A simple and general equation governing the thickness-shear modes is derived from a variational analysis. A plate with piecewise constant material properties is analyzed as an example. It is shown that such a plate can support thickness-shear vibration modes with obvious energy trapping. Bechmann's number for the existence of only one trapped mode also can be determined accordingly.

  17. Fabrication and characterization of MEMS-based PZT/PZT bimorph thick film vibration energy harvesters

    DEFF Research Database (Denmark)

    Xu, Ruichao; Lei, Anders; Dahl-Petersen, Christian

    2012-01-01

    We describe the fabrication and characterization of a significantly improved version of a microelectromechanical system-based PZT/PZT thick film bimorph vibration energy harvester with an integrated silicon proof mass; the harvester is fabricated in a fully monolithic process. The main advantage...... of bimorph vibration energy harvesters is that strain energy is not lost in mechanical support materials since only Pb(ZrxTi1-x)O3 (PZT) is strained; as a result, the effective system coupling coefficient is increased, and thus a potential for significantly higher output power is released. In addition, when...... the two layers are connected in series, the output voltage is increased, and as a result the relative power loss in the necessary rectifying circuit is reduced. We describe an improved process scheme for the energy harvester, which resulted in a robust fabrication process with a record high fabrication...

  18. Surface energy effect on free vibration of nano-sized piezoelectric double-shell structures

    Science.gov (United States)

    Fang, Xue-Qian; Zhu, Chang-Song; Liu, Jin-Xi; Liu, Xiang-Lin

    2018-01-01

    Combining Goldenveizer-Novozhilov shell theory, thin plate theory and electro-elastic surface theory, the size-dependent vibration of nano-sized piezoelectric double-shell structures under simply supported boundary condition is presented, and the surface energy effect on the natural frequencies is discussed. The displacement components of the cylindrical nano-shells and annular nano-plates are expanded as the superposition of standard Fourier series based on Hamilton's principle. The total stresses with consideration of surface energy effect are derived, and the total energy function is obtained by using Rayleigh-Ritz energy method. The free vibration equation is solved, and the natural frequency is analyzed. In numerical examples, it is found that the surface elastic constant, piezoelectric constant and surface residual stress show different effects on the natural frequencies. The effect of surface piezoelectric constant is the maximum. The effect of dimensions of the double-shell under different surface material properties is also examined.

  19. Development of Non-Conservative Joints in Beam Networks for Vibration Energy Flow Analysis

    Directory of Open Access Journals (Sweden)

    Jee-Hun Song

    2007-01-01

    Full Text Available Our work aims to find a general solution for the vibrational energy flow through a plane network of beams on the basis of an energy flow analysis. A joint between two semi-infinite beams are modeled by three sets of springs and dashpots. Thus, the results can incorporate the case of complaint and non-conservative in all the three degrees of freedom. In the cases of finite coupled structures connected at a certain angle, the derived non-conservative joints and developed wave energy equation were applied. The joint properties, the frequency, the coupling angle, and the internal loss factor were changed to evaluate the proposed methods for predicting medium-to-high frequency vibrational energy and intensity distributions.

  20. Selected characteristics of vibration signal at a minimal energy consumption for the rock disintegration

    Directory of Open Access Journals (Sweden)

    Viera Miklúšová

    2011-12-01

    Full Text Available The rock disintegration process involves the action of disintegrating tool, resulting in the formation of forced mechanicaloscillations of all components, i.e. the disintegration device, tool and the rock. The vibration signal scanned during the process dependson all of the presented components, on their properties and on the regime parameters. The paper presents relations of the vibrationsignal characteristics, effective values of the acceleration of vibration oscillations and dominant frequencies, and the energyconsumption needed for the rock disintegration, which is characterized by a specific disintegration energy. Presented results wereacquired as a part of laboratory experimental research on the rotary drilling of rocks.

  1. Vibration energy harvesting using piezoelectric unimorph cantilevers with unequal piezoelectric and nonpiezoelectric lengths.

    Science.gov (United States)

    Gao, Xiaotong; Shih, Wei-Heng; Shih, Wan Y

    2010-12-06

    We have examined a piezoelectric unimorph cantilever (PUC) with unequal piezoelectric and nonpiezoelectric lengths for vibration energy harvesting theoretically by extending the analysis of a PUC with equal piezoelectric and nonpiezoelectric lengths. The theoretical approach was validated by experiments. A case study showed that for a fixed vibration frequency, the maximum open-circuit induced voltage which was important for charge storage for later use occurred with a PUC that had a nonpiezoelectric-to-piezoelectric length ratio greater than unity, whereas the maximum power when the PUC was connected to a resistor for immediate power consumption occurred at a unity nonpiezoelectric-to-piezoelectric length ratio.

  2. Vibrational Energy Relaxation: A Benchmark for Mixed Quantum-Classical Methods.

    Science.gov (United States)

    Jain, Amber; Subotnik, Joseph E

    2018-01-11

    We investigate the ability of mixed quantum-classical methods to capture the dynamics of vibrational energy relaxation. Several methods, including surface hopping, and Ehrenfest and symmetrical quasiclassical (SQC) dynamics, are benchmarked for the exactly solvable model problem of a harmonic oscillator bilinearly coupled to a bath of harmonic oscillators. Results show that, very often, one can recover accurate vibrational relaxation rates and detailed balance using simple mixed quantum-classical approaches. A few anomalous results do appear, however, especially regarding Ehrenfest and SQC dynamics.

  3. Temperature-dependent vibrational spectra and structure of liquid water from classical and quantum simulations with the MB-pol potential energy function.

    Science.gov (United States)

    Reddy, Sandeep K; Moberg, Daniel R; Straight, Shelby C; Paesani, Francesco

    2017-12-28

    The structure of liquid water as a function of temperature is investigated through the modeling of infrared and Raman spectra along with structural order parameters calculated from classical and quantum molecular dynamics simulations with the MB-pol many-body potential energy function. The magnitude of nuclear quantum effects is also monitored by comparing the vibrational spectra obtained from classical and centroid molecular dynamics, both in intensities and peak positions. The observed changes in spectral activities are shown to reflect changes in the underlying structure of the hydrogen-bond network and are found to be particularly sensitive to many-body effects in the representation of the electrostatic interactions. Overall, good agreement is found with the experimental spectra, which provides further evidence for the accuracy of MB-pol in predicting the properties of water.

  4. Temperature-dependent vibrational spectra and structure of liquid water from classical and quantum simulations with the MB-pol potential energy function

    Science.gov (United States)

    Reddy, Sandeep K.; Moberg, Daniel R.; Straight, Shelby C.; Paesani, Francesco

    2017-12-01

    The structure of liquid water as a function of temperature is investigated through the modeling of infrared and Raman spectra along with structural order parameters calculated from classical and quantum molecular dynamics simulations with the MB-pol many-body potential energy function. The magnitude of nuclear quantum effects is also monitored by comparing the vibrational spectra obtained from classical and centroid molecular dynamics, both in intensities and peak positions. The observed changes in spectral activities are shown to reflect changes in the underlying structure of the hydrogen-bond network and are found to be particularly sensitive to many-body effects in the representation of the electrostatic interactions. Overall, good agreement is found with the experimental spectra, which provides further evidence for the accuracy of MB-pol in predicting the properties of water.

  5. Solar-pumped electronic-to-vibrational energy transfer lasers

    Science.gov (United States)

    Harries, W. L.; Wilson, J. W.

    1981-01-01

    The possibility of using solar-pumped lasers as solar energy converters is examined. The absorbing media considered are halogens or halogen compounds, which are dissociated to yield excited atoms, which then hand over energy to a molecular lasing medium. Estimates of the temperature effects for a Br2-CO2-He system with He as the cooling gas are given. High temperatures can cause the lower energy levels of the CO2 laser transition to be filled. The inverted populations are calculated and lasing should be possible. However, the efficiency is less than 0.001. Examination of other halogen-molecular lasant combinations (where the rate coefficients are known) indicate efficiencies in all cases of less than 0.005.

  6. Iron oxide/aluminum/graphene energetic nanocomposites synthesized by atomic layer deposition: Enhanced energy release and reduced electrostatic ignition hazard

    Science.gov (United States)

    Yan, Ning; Qin, Lijun; Hao, Haixia; Hui, Longfei; Zhao, Fengqi; Feng, Hao

    2017-06-01

    Nanocomposites consisting of iron oxide (Fe2O3) and nano-sized aluminum (Al), possessing outstanding exothermic redox reaction characteristics, are highly promising nanothermite materials. However, the reactant diffusion inhibited in the solid state system makes the fast and complete energy release very challenging. In this work, Al nanoparticles anchored on graphene oxide (GO/Al) was initially prepared by a solution assembly approach. Fe2O3 was deposited on GO/Al substrates by atomic layer deposition (ALD). Simultaneously thermal reduction of GO occurs, resulting in rGO/Al@Fe2O3 energetic composites. Differential scanning calorimetry (DSC) analysis reveals that rGO/Al@Fe2O3 composite containing 4.8 wt% of rGO exhibits a 50% increase of the energy release compared to the Al@Fe2O3 nanothermite synthesized by ALD, and an increase of about 130% compared to a random mixture of rGO/Al/Fe2O3 nanoparticles. The enhanced energy release of rGO/Al@Fe2O3 is attributed to the improved spatial distribution as well as the increased interfacial intimacy between the oxidizer and the fuel. Moreover, the rGO/Al@Fe2O3 composite with an rGO content of 9.6 wt% exhibits significantly reduced electrostatic discharge sensitivity. These findings may inspire potential pathways for engineering energetic nanocomposites with enhanced energy release and improved safety characteristics.

  7. Vibration energy harvesting in railway tunnels with a wireless sensor node application

    Energy Technology Data Exchange (ETDEWEB)

    Wischke, Martin

    2012-07-01

    Vibration harvesting is a promising concept to prolong the lifetime of batterypowered stand-alone systems, or even to enable their energy-autonomy. This thesis focuses on ambient vibrations converted by electromechanical transducers into electricity. The final goal is energy scavenging from train-induced vibrations in railway tunnels. This is achieved via the development of a suitable harvester for this environment and the practical demonstration of a vibrationpowered wireless sensor node (WSN). At the beginning of this thesis, extensive vibration measurements were performed in several traffic tunnels. The obtained unique data set formed the basis for the design and test of several harvesters. The railway sleeper was chosen as usable harvester location. A shock-resistant double-side suspended piezoelectric cantilever was developed. Several cantilevers with different eigenfrequencies are combined in an array, creating a robust harvester with a broad bandwidth. A field test of 7 days in the Loetschbergbasis-tunnel verified that, on average the sufficient energy for powering a virtual wireless sensor node was scavenged. For application in a real WSN, the harvester array was scaled up to 10 cantilevers. The power management for the sensor node was developed concurrently. The central component is a power switch that monitors the energy level in the system's storage capacitor and only triggers the wireless interface when sufficient energy is available. Combined with a train detection circuit, the presented energy-autonomous WSN reliably reports every passing vehicle. In addition to the development of an energy-autonomous fully integrated WSN, this work investigates nonlinear properties of PZT ceramics. Consideration of the elastostriction and the electrostriction enables a more precises prediction of the tip displacement of a piezoelectric cantilever actuator. Further, the elastostriction is exploited to modify the resonance frequency of a bimorph cantilever. Basing

  8. Roles of the Excitation in Harvesting Energy from Vibrations.

    Directory of Open Access Journals (Sweden)

    Hui Zhang

    Full Text Available The study investigated the role of excitation in energy harvesting applications. While the energy ultimately comes from the excitation, it was shown that the excitation may not always behave as a source. When the device characteristics do not perfectly match the excitation, the excitation alternately behaves as a source and a sink. The extent to which the excitation behaves as a sink determines the energy harvesting efficiency. Such contradictory roles were shown to be dictated by a generalized phase defined as the instantaneous phase angle between the velocity of the device and the excitation. An inductive prototype device with a diamagnetically levitated seismic mass was proposed to take advantage of the well established phase changing mechanism of vibro-impact to achieve a broader device bandwidth. Results suggest that the vibro-impact can generate an instantaneous, significant phase shift in response velocity that switches the role of the excitation. If introduced properly outside the resonance zone it could dramatically increase the energy harvesting efficiency.

  9. Detection of directional energy damping in vibrating systems - Indian ...

    Indian Academy of Sciences (India)

    Abstract. The transmission efficiency, frequency and amplitude alteration have been measured by a simple technique of coupled oscillators with a frequency gradient and in a system of non-Newtonian fluid in the form of corn-flour slime. The system of coupled oscillators was found to exhibit preferential energy transfer ...

  10. Inelastic surface vibrations versus energy-dependent nucleus ...

    Indian Academy of Sciences (India)

    Abstract. Limitations of the static Woods–Saxon potential and the applicability of the energy- dependent Woods–Saxon potential (EDWSP) model within the framework of one-dimensional. Wong formula to explore the sub-barrier fusion data are highlighted. The inelastic surface exci- tations of the fusing nuclei are found to ...

  11. Development of Vibration-Based Piezoelectric Raindrop Energy Harvesting System

    Science.gov (United States)

    Wong, Chin Hong; Dahari, Zuraini

    2017-03-01

    The trend of finding new means to harvest energy has triggered numerous researches to explore the potential of raindrop energy harvesting. This paper presents an investigation on raindrop energy harvesting which compares the performance of polyvinylidene fluoride (PVDF) cantilever and bridge structure transducers and the development of a raindrop energy harvesting system. The parameters which contribute to the output voltage such as droplet size, droplets released at specific heights and dimensions of PVDF transducers are analyzed. Based on the experimental results, the outcomes have shown that the bridge structure transducer generated a higher voltage than the cantilever. Several dimensions have been tested and it was found that the 30 mm × 4 mm × 25 μm bridge structure transducer generated a relatively high AC open-circuit voltage, which is 4.22 V. The power generated by the bridge transducer is 18 μW across a load of 330 kΩ. The transducer is able to drive up a standard alternative current (AC) to direct current (DC) converter (full-wave bridge rectifier). It generated a DC voltage, V DC of 8.7 mV and 229 pW across a 330 kΩ resistor per drop. It is also capable to generate 9.3 nJ in 20 s from an actual rain event.

  12. Inelastic surface vibrations versus energy-dependent nucleus ...

    Indian Academy of Sciences (India)

    Limitations of the static Woods–Saxon potential and the applicability of the energy dependent Woods–Saxon potential (EDWSP) model within the framework of one-dimensional Wong formula to explore the sub-barrier fusion data are highlighted. The inelastic surface excitations of the fusing nuclei are found to be ...

  13. Detection of directional energy damping in vibrating systems

    Indian Academy of Sciences (India)

    The transmission efficiency, frequency and amplitude alteration have been measured by a simple technique of coupled oscillators with a frequency gradient and in a system of non-Newtonian fluid in the form of corn-flour slime. The system of coupled oscillators was found to exhibit preferential energy transfer towards the ...

  14. Research and development of energy harvesting from vibrations and human motions (Conference Presentation)

    Science.gov (United States)

    Liao, Wei-Hsin

    2017-04-01

    Most of the ambient energy, which was regarded useless in the past, now is under the spotlight. With the rapid developments on low power electronics, future personal mobile devices and remote sensing systems might become self-powered by scavenging energy in different forms from their surroundings. Kinetic energy is one of the promising energy forms in our living environment, e.g., human motions and vibrations. We have proposed an energy flow to clarify the functions of piezoelectric energy harvesting, dissipation, and their effects on the structural damping of vibrating structures. Impedance modeling and analysis were performed. We have designed an improved self-powered switching interface for piezoelectric energy harvesting circuits. With electromagnetic transduction, we also proposed a knee-mounted energy harvester that could convert the mechanical power from knee joints into electricity during walking. On the other hand, we have developed magnetorheological (MR) fluid devices with multiple functions, including rotary actuators and linear dampers. Multifunctional rotary actuator was designed to integrate motor/generator part and MR fluids into a single device. The actuator could function as motor, generator, clutch and brake, with compact size and good energy efficiency. In addition, novel self-sensing MR dampers with power generation, so as to integrate the dynamic sensing, controllable damping and power generation functions, were developed and investigated. Prototypes were fabricated and tested. The developed actuators were promising for various applications. In this paper, related research in energy harvesting done at The Chinese University of Hong Kong and key results will be presented.

  15. A two-dimensional broadband vibration energy harvester using magnetoelectric transducer

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Jin, E-mail: yangjin@cqu.edu.cn; Wen, Yumei; Li, Ping; Yue, Xihai; Yu, Qiangmo; Bai, Xiaoling [Department of Optoelectronic Engineering, Research Center of Sensors and Instruments, Chongqing University, Chongqing 400044 (China)

    2013-12-09

    In this study, a magnetoelectric vibration energy harvester was demonstrated, which aims at addressing the limitations of the existing approaches in single dimensional operation with narrow working bandwidth. A circular cross-section cantilever rod, not a conventional thin cantilever beam, was adopted to extract vibration energy in arbitrary in-plane motion directions. The magnetic interaction not only resulted in a nonlinear motion of the rod with increased frequency bandwidth, but also contributed to a multi-mode motion to exhibit double power peaks. In energy harvesting with in-plane directions, it showed a maximum bandwidth of 4.4 Hz and power of 0.59 mW, with acceleration of 0.6 g (with g = 9.8 m s{sup −2})

  16. Frequency Up-Converted Low Frequency Vibration Energy Harvester Using Trampoline Effect

    Science.gov (United States)

    Ju, S.; Chae, S. H.; Choi, Y.; Jun, S.; Park, S. M.; Lee, S.; Lee, H. W.; Ji, C.-H.

    2013-12-01

    This paper presents a non-resonant vibration energy harvester based on magnetoelectric transduction mechanism and mechanical frequency up-conversion using trampoline effect. The harvester utilizes a freely movable spherical permanent magnet which bounces off the aluminum springs integrated at both ends of the cavity, achieving frequency up-conversion from low frequency input vibration. Moreover, bonding method of magnetoelectric laminate composite has been optimized to provide higher strain to piezoelectric material and thus obtain a higher output voltage. A proof-of-concept energy harvesting device has been fabricated and tested. Maximum open-circuit voltage of 11.2V has been obtained and output power of 0.57μW has been achieved for a 50kΩ load, when the fabricated energy harvester was hand-shaken.

  17. Computing vibrational energy levels of CH4 with a Smolyak collocation method

    Science.gov (United States)

    Avila, Gustavo; Carrington, Tucker

    2017-10-01

    In this paper, we demonstrate that it is possible to apply collocation to compute vibrational energy levels of a five-atom molecule using an exact kinetic energy operator (with cross terms and coordinate-dependent coefficients). This is made possible by using (1) a pruned basis of products of univariate functions; (2) a Smolyak grid made from nested sequences of grids for each coordinate; (3) a collocation method that obviates the need to solve a generalized eigenvalue problem; (4) an efficient sequential transformation between the (nondirect product) grid and the (nondirect product) basis representations; and (5) hierarchical univariate functions that make it possible to avoid storing large intermediate vectors. The accuracy of the method is confirmed by computing 500 vibrational energy levels of methane.

  18. An Impact-Based Frequency Up-Converting Hybrid Vibration Energy Harvester for Low Frequency Application

    Directory of Open Access Journals (Sweden)

    Zhenlong Xu

    2017-11-01

    Full Text Available In this paper, a novel impact-based frequency up-converting hybrid energy harvester (FUCHEH was proposed. It consisted of a piezoelectric cantilever beam and a driving beam with a magnetic tip mass. A solenoid coil was attached at the end of the piezoelectric beam. This innovative configuration amplified the relative motion velocity between magnet and coil, resulting in an enhancement of the induced electromotive force in the coil. An electromechanical coupling model was developed and a numerical simulation was performed to study the principle of impact-based frequency up-converting. A prototype was fabricated and experimentally tested. The time-domain and frequency-domain analyses were performed. Fast Fourier transform (FFT analysis verified that fundamental frequencies and coupled vibration frequency contributes most of the output voltage. The measured maximum output power was 769.13 µW at a frequency of 13 Hz and an acceleration amplitude of 1 m/s2, which was 3249.4%- and 100.6%-times larger than that of the frequency up-converting piezoelectric energy harvesters (FUCPEH and frequency up-converting electromagnetic energy harvester (FUCEMEH, respectively. The root mean square (RMS voltage of the piezoelectric energy harvester subsystem (0.919 V was more than 16 times of that of the stand-alone PEH (0.055 V. This paper provided a new scheme to improve generating performance of the vibration energy harvester with high resonant frequency working in the low-frequency vibration environment.

  19. Optimization of constrained layer damping for strain energy minimization of vibrating pads

    Directory of Open Access Journals (Sweden)

    Supachai Lakkam1

    2012-04-01

    Full Text Available An optimization study for brake squeals aims to minimize the strain energy of vibrating pads with constrained layerdamping. To achieve this, using finite element method and experiments were operated and assumed-coupling mode methodwas used to solve it. The integrated global strain energy of the pad over a frequency range of interesting mode was calculated.Parametric studies were then performed to identify those dominant parameters on the vibration response of the damped pad.Moreover, the proposed methodology was employed to search for the optimum of the position/geometry of the constrainedlayer damping patch. Optimal solutions are given and discussed for different cases where the strain energy of the pad over afrequency range is covering the first bending mode and with the inclusion of the restriction of minimum damping materialutilization. As a result, the integrated strain energy is then performed to identify and optimize the position and geometry of thedamping shim. The optimization of the constrained layer damping for strain energy minimization of vibrating pads depend onthe position of the shape of the damping patch. These data can guide to specify the position of the constrained layer dampingpatch under pressure conditions.

  20. Ab initio potential energy surface and vibration-rotation energy levels of silicon dicarbide, SiC2.

    Science.gov (United States)

    Koput, Jacek

    2016-10-05

    The accurate ground-state potential energy surface of silicon dicarbide, SiC2 , has been determined from ab initio calculations using the coupled-cluster approach. Results obtained with the conventional and explicitly correlated coupled-cluster methods were compared. The core-electron correlation, higher-order valence-electron correlation, and scalar relativistic effects were taken into account. The potential energy barrier to the linear SiCC configuration was predicted to be 1782 cm(-1) . The vibration-rotation energy levels of the SiC2 , (29) SiC2 , (30) SiC2 , and SiC(13) C isotopologues were calculated using a variational method. The experimental vibration-rotation energy levels of the main isotopologue were reproduced to high accuracy. In particular, the experimental energy levels of the highly anharmonic vibrational ν3 mode of SiC2 were reproduced to within 6.7 cm(-1) , up to as high as the v3  = 16 state. © 2016 Wiley Periodicals, Inc.

  1. Progresses in Ab Initio QM/MM Free Energy Simulations of Electrostatic Energies in Proteins: Accelerated QM/MM Studies of pKa, Redox Reactions and Solvation Free Energies

    Energy Technology Data Exchange (ETDEWEB)

    Kamerlin, Shina C. L.; Haranczyk, Maciej; Warshel, Arieh

    2009-03-01

    Hybrid quantum mechanical / molecular mechanical (QM/MM) approaches have been used to provide a general scheme for chemical reactions in proteins. However, such approaches still present a major challenge to computational chemists, not only because of the need for very large computer time in order to evaluate the QM energy but also because of the need for propercomputational sampling. This review focuses on the sampling issue in QM/MM evaluations of electrostatic energies in proteins. We chose this example since electrostatic energies play a major role in controlling the function of proteins and are key to the structure-function correlation of biological molecules. Thus, the correct treatment of electrostatics is essential for the accurate simulation of biological systems. Although we will be presenting here different types of QM/MM calculations of electrostatic energies (and related properties), our focus will be on pKa calculations. This reflects the fact that pKa of ionizable groups in proteins provide one of the most direct benchmarks for the accuracy of electrostatic models of macromolecules. While pKa calculations by semimacroscopic models have given reasonable results in many cases, existing attempts to perform pKa calculations using QM/MM-FEP have led to large discrepancies between calculated and experimental values. In this work, we accelerate our QM/MM calculations using an updated mean charge distribution and a classical reference potential. We examine both a surface residue (Asp3) of the bovine pancreatic trypsin inhibitor, as well as a residue buried in a hydrophobic pocket (Lys102) of the T4-lysozyme mutant. We demonstrate that by using this approach, we are able to reproduce the relevant sidechain pKas with an accuracy of 3 kcal/mol. This is well within the 7 kcal/mol energy difference observed in studies of enzymatic catalysis, and is thus sufficient accuracy to determine the main contributions to the catalytic energies of enzymes. We also provide an

  2. Investigation of an energy harvesting MR damper in a vibration control system

    Science.gov (United States)

    Sapiński, Bogdan; Rosół, Maciej; Węgrzynowski, Marcin

    2016-12-01

    In this paper the authors investigate the performance of an energy harvesting MR damper (EH-MRD) employed in a semi-active vibration control system (SVCS) and used in a single DOF mechanical structure configuration. Main components of the newly proposed SCVS include the MR damper and an electromagnetic vibration energy harvester based on the Faraday’s law (EVEH) that converts vibration energy into electrical energy and delivers electrical power supplying the MR damper. The main objective of the study is to indicate that the SVCS, controlled by the specially designed embedded system, is feasible and presents good performance at the present stage of the research. The work describes investigation the unique features of the EH-MRD, i.e. its self-powering and self-sensing capabilities. Two cases were considered and the testing was done accordingly. In the case 1, only the self-powered capability was investigated. It was found out that harvested energy is sufficient to power the EH-MRD damper and to adjust it to structural vibration. The results confirmed the adequacy of the SVCS and demonstrated a significant reduction of the resonance peak. In the case 2, both the self-powering and self-sensing capabilities were investigated. Due to the self-sensing capability, the SCVS does not require any sensor. It appeared that thus harvested energy is sufficient to power the EH-MRD and enables self-sensing action since the signal of voltage induced by EVEH agrees with the relative velocity signal across the device. Similar to case 1, the resonance peak is significantly reduced.

  3. Multi-directional electromagnetic vibration energy harvester using circular Halbach array

    Science.gov (United States)

    Qiu, Jing; Liu, Xin; Hu, Zhenwen; Chang, Qijie; Gao, Yuan; Yang, Jin; Wen, Jing; Tang, Xiaosheng; Hu, Wei

    2017-05-01

    In this paper, a multi-directional electromagnetic vibration energy harvester (EVEH) using the circular Halbach array (HA) is presented based on the Faraday's law of electromagnetic induction. The circular HA is a specific arrangement of permanent magnets which could concentrate the magnetic field inside the circular array by a certain rule, while reduce the magnetic field outside the circular array to almost zero at the same time. The HA could break through the limitation of the related published vibration energy harvesters that could work in only one single direction. Thus, it could optimize the collecting efficiency. The experimental results show that the presented harvester could generate considerable electric output power in all vibrating directions. An optimal output power is 9.32 mW at a resonant frequency of 15.40 Hz with an acceleration of 0.5 g (with g=9.8 m/s2) across a 700-turn coil in the vibrating direction of 90°, which is 1.53 times than the minimum optimal one in the direction of 45°. The EVEH using the circular HA could work in all directions and generate considerable electric output power, which validates the feasibility of the EVEH that works in all directions and is beneficial for improving the practical application.

  4. Coupled analysis of multi-impact energy harvesting from low-frequency wind induced vibrations

    Science.gov (United States)

    Zhu, Jin; Zhang, Wei

    2015-04-01

    Energy need from off-grid locations has been critical for effective real-time monitoring and control to ensure structural safety and reliability. To harvest energy from ambient environments, the piezoelectric-based energy-harvesting system has been proven very efficient to convert high frequency vibrations into usable electrical energy. However, due to the low frequency nature of the vibrations of civil infrastructures, such as those induced from vehicle impacts, wind, and waves, the application of a traditional piezoelectric-based energy-harvesting system is greatly restrained since the output power drops dramatically with the reduction of vibration frequencies. This paper focuses on the coupled analysis of a proposed piezoelectric multi-impact wind-energy-harvesting device that can effectively up-convert low frequency wind-induced vibrations into high frequency ones. The device consists of an H-shape beam and four bimorph piezoelectric cantilever beams. The H-shape beam, which can be easily triggered to vibrate at a low wind speed, is originated from the first Tacoma Narrows Bridge, which failed at wind speeds of 18.8 m s-1 in 1940. The multi-impact mechanism between the H-shape beam and the bimorph piezoelectric cantilever beams is incorporated to improve the harvesting performance at lower frequencies. During the multi-impact process, a series of sequential impacts between the H-shape beam and the cantilever beams can trigger high frequency vibrations of the cantilever beams and result in high output power with a considerably high efficiency. In the coupled analysis, the coupled structural, aerodynamic, and electrical equations are solved to obtain the dynamic response and the power output of the proposed harvesting device. A parametric study for several parameters in the coupled analysis framework is carried out including the external resistance, wind speed, and the configuration of the H-shape beam. The average harvested power for the piezoelectric cantilever

  5. Buck-boost converter for simultaneous semi-active vibration control and energy harvesting for electromagnetic regenerative shock absorber

    Science.gov (United States)

    Li, Peng; Zhang, Chongxiao; Kim, Junyoung; Yu, Liangyao; Zuo, Lei

    2014-04-01

    Regenerative semi-active suspensions can capture the previously dissipated vibration energy and convert it to usable electrical energy for powering on-board electronic devices, while achieve both the better ride comfort and improved road handling performance at the same time when certain control is applied. To achieve this objective, the power electronics interface circuit connecting the energy harvester and the electrical loads, which can perform simultaneous vibration control and energy harvesting function is in need. This paper utilized a buck-boost converter for simultaneous semi-active vibration control and energy harvesting with electromagnetic regenerative shock absorber, which utilizes a rotational generator to converter the vibration energy to electricity. It has been found that when the circuit works in discontinuous current mode (DCM), the ratio between the input voltage and current is only related to the duty cycle of the switch pulse width modulation signal. Using this property, the buck-boost converter can be used to perform semi-active vibration control by controlling the load connected between the terminals of the generator in the electromagnetic shock absorber. While performing the vibration control, the circuit always draw current from the shock absorber and the suspension remain dissipative, and the shock absorber takes no additional energy to perform the vibration control. The working principle and dynamics of the circuit has been analyzed and simulations were performed to validate the concept.

  6. Tube-Super Dielectric Materials: Electrostatic Capacitors with Energy Density Greater than 200 J·cm−3

    Science.gov (United States)

    Cortes, Francisco Javier Quintero; Phillips, Jonathan

    2015-01-01

    The construction and performance of a second generation of super dielectric material based electrostatic capacitors (EC), with energy density greater than 200 J·cm−3, which rival the best reported energy density of electric double layer capacitors (EDLC), also known as supercapacitors, are reported. The first generation super dielectric materials (SDM) are multi-material mixtures with dielectric constants greater than 1.0 × 105, composed of a porous, electrically insulating powder filled with a polarizable, ion-containing liquid. Second-generation SDMs (TSDM), introduced here, are anodic titania nanotube arrays filled with concentrated aqueous salt solutions. Capacitors using TiO2 based TSDM were found to have dielectric constants at ~0 Hz greater than 107 in all cases, a maximum operating voltage of greater than 2 volts and remarkable energy density that surpasses the highest previously reported for EC capacitors by approximately one order of magnitude. A simple model based on the classic ponderable media model was shown to be largely consistent with data from nine EC type capacitors employing TSDM. PMID:28793561

  7. Tube-Super Dielectric Materials: Electrostatic Capacitors with Energy Density Greater than 200 J·cm−3

    Directory of Open Access Journals (Sweden)

    Francisco Javier Quintero Cortes

    2015-09-01

    Full Text Available The construction and performance of a second generation of super dielectric material based electrostatic capacitors (EC, with energy density greater than 200 J·cm−3, which rival the best reported energy density of electric double layer capacitors (EDLC, also known as supercapacitors, are reported. The first generation super dielectric materials (SDM are multi-material mixtures with dielectric constants greater than 1.0 × 105, composed of a porous, electrically insulating powder filled with a polarizable, ion-containing liquid. Second-generation SDMs (TSDM, introduced here, are anodic titania nanotube arrays filled with concentrated aqueous salt solutions. Capacitors using TiO2 based TSDM were found to have dielectric constants at ~0 Hz greater than 107 in all cases, a maximum operating voltage of greater than 2 volts and remarkable energy density that surpasses the highest previously reported for EC capacitors by approximately one order of magnitude. A simple model based on the classic ponderable media model was shown to be largely consistent with data from nine EC type capacitors employing TSDM.

  8. Robust triboelectric nanogenerator based on rolling electrification and electrostatic induction at an instantaneous energy conversion efficiency of ∼ 55%.

    Science.gov (United States)

    Lin, Long; Xie, Yannan; Niu, Simiao; Wang, Sihong; Yang, Po-Kang; Wang, Zhong Lin

    2015-01-27

    In comparison to in-pane sliding friction, rolling friction not only is likely to consume less mechanical energy but also presents high robustness with minimized wearing of materials. In this work, we introduce a highly efficient approach for harvesting mechanical energy based on rolling electrification and electrostatic induction, aiming at improving the energy conversion efficiency and device durability. The rolling triboelectric nanogenerator is composed of multiple steel rods sandwiched by two fluorinated ethylene propylene (FEP) thin films. The rolling motion of the steel rods between the FEP thin films introduces triboelectric charges on both surfaces and leads to the change of potential difference between each pair of electrodes on back of the FEP layer, which drives the electrons to flow in the external load. As power generators, each pair of output terminals works independently and delivers an open-circuit voltage of 425 V, and a short-circuit current density of 5 mA/m(2). The two output terminals can also be integrated to achieve an overall power density of up to 1.6 W/m(2). The impacts of variable structural factors were investigated for optimization of the output performance, and other prototypes based on rolling balls were developed to accommodate different types of mechanical energy sources. Owing to the low frictional coefficient of the rolling motion, an instantaneous energy conversion efficiency of up to 55% was demonstrated and the high durability of the device was confirmed. This work presents a substantial advancement of the triboelectric nanogenerators toward large-scope energy harvesting and self-powered systems.

  9. Retrofit of waste-to-energy facilities equipped with electrostatic precipitators. Volume II: Field and laboratory reports, Part 2 of 2

    Energy Technology Data Exchange (ETDEWEB)

    Rigo, H.G. [Rigo & Rigo Associates, Inc., Berea, OH (US); Chandler, A.J. [A.J. Chandler & Associates, Ltd., Toronto, Ontario (Canada)

    1996-04-01

    Volume II (part 2 of 2) of ''Retrofit of Waste-to-energy Facilities Equipped with Electrostatic Precipitators'' contains the field and laboratory reports, including: (1) field reports, (2) analytic laboratory reports, (3) chain of custody forms, and (4) TCLP laboratory reports.

  10. Kinetic model for the vibrational energy exchange in flowing molecular gas mixtures. Ph.D. Thesis

    Science.gov (United States)

    Offenhaeuser, F.

    1987-01-01

    The present study is concerned with the development of a computational model for the description of the vibrational energy exchange in flowing gas mixtures, taking into account a given number of energy levels for each vibrational degree of freedom. It is possible to select an arbitrary number of energy levels. The presented model uses values in the range from 10 to approximately 40. The distribution of energy with respect to these levels can differ from the equilibrium distribution. The kinetic model developed can be employed for arbitrary gaseous mixtures with an arbitrary number of vibrational degrees of freedom for each type of gas. The application of the model to CO2-H2ON2-O2-He mixtures is discussed. The obtained relations can be utilized in a study of the suitability of radiation-related transitional processes, involving the CO2 molecule, for laser applications. It is found that the computational results provided by the model agree very well with experimental data obtained for a CO2 laser. Possibilities for the activation of a 16-micron and 14-micron laser are considered.

  11. Bi-resonant structure with piezoelectric PVDF films for energy harvesting from random vibration sources at low frequency

    DEFF Research Database (Denmark)

    Liang, Shanshan; Crovetto, Andrea; Peng, Zhuoteng

    2016-01-01

    and experiments with piezoelectric elements show that the energy harvesting device with the bi-resonant structure can generate higher power output than that of the sum of the two separate devices from random vibration sources at low frequency, and hence significantly improves the vibration-to- electricity...

  12. Harvesting vibrational energy with liquid-bridged electrodes: thermodynamics in mechanically and electrically driven RC-circuits

    NARCIS (Netherlands)

    Janssen, Mathijs; Werkhoven, Ben; Van Roij, René

    2016-01-01

    We theoretically study a vibrating pair of parallel electrodes bridged by a (deformed) liquid droplet, which is a recently developed microfluidic device to harvest vibrational energy. The device can operate with various liquids, including liquid metals, electrolytes, as well as ionic liquids. We

  13. Self-starting power management circuits for piezoelectric and electret-based electrostatic mechanical energy harvesters

    Science.gov (United States)

    Boisseau, S.; Gasnier, P.; Gallardo, M.; Despesse, G.

    2013-12-01

    This paper reports on an innovative power management circuit for piezoelectric and electret-based mechanical energy harvesters able to self-start and to power battery-free Wireless Sensor Nodes (WSN) from scratch without any initial energy. The key elements of this circuit are a depletion-mode MOSFET combined with self-powered Schmitt triggers that enable to switch between (i) a non-optimized passive diode-bridge-capacitor configuration to start the system and (ii) an active power conversion path to maximize the energy extraction from mechanical energy harvesters. A discrete circuit implementing this architecture is presented and its operation is validated on simple piezoelectric and electret-based devices. An ASIC, based on the same architecture, has finally been designed, fabricated and validated.

  14. Electrostatic solvation free energies of charged hard spheres using molecular dynamics with density functional theory interactions

    Energy Technology Data Exchange (ETDEWEB)

    Duignan, Timothy T. [Physical Science Division, Pacific Northwest National Laboratory, P.O. Box 999, Richland, Washington 99352, USA; Baer, Marcel D. [Physical Science Division, Pacific Northwest National Laboratory, P.O. Box 999, Richland, Washington 99352, USA; Schenter, Gregory K. [Physical Science Division, Pacific Northwest National Laboratory, P.O. Box 999, Richland, Washington 99352, USA; Mundy, Chistopher J. [Department of Chemical Engineering, University of Washington, Seattle, Washington 98185, USA

    2017-10-28

    Determining the solvation free energies of single ions in water is one of the most fundamental problems in physical chemistry and yet many unresolved questions remain. In particular, the ability to decompose the solvation free energy into simple and intuitive contributions will have important implications for coarse grained models of electrolyte solution. Here, we provide rigorous definitions of the various types of single ion solvation free energies based on different simulation protocols. We calculate solvation free energies of charged hard spheres using density functional theory interaction potentials with molecular dynamics simulation (DFT-MD) and isolate the effects of charge and cavitation, comparing to the Born (linear response) model. We show that using uncorrected Ewald summation leads to highly unphysical values for the solvation free energy and that charging free energies for cations are approximately linear as a function of charge but that there is a small non-linearity for small anions. The charge hydration asymmetry (CHA) for hard spheres, determined with quantum mechanics, is much larger than for the analogous real ions. This suggests that real ions, particularly anions, are significantly more complex than simple charged hard spheres, a commonly employed representation. We would like to thank Thomas Beck, Shawn Kathmann, Richard Remsing and John Weeks for helpful discussions. Computing resources were generously allocated by PNNL's Institutional Computing program. This research also used resources of the National Energy Research Scientific Computing Center, a DOE Office of Science User Facility supported by the Office of Science of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231. TTD, GKS, and CJM were supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences. MDB was supported by MS3 (Materials Synthesis and Simulation Across

  15. Exploring the vibrational fingerprint of the electronic excitation energy via molecular dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Deyne, Andy Van Yperen-De; Pauwels, Ewald; Ghysels, An; Waroquier, Michel; Van Speybroeck, Veronique; Hemelsoet, Karen, E-mail: karen.hemelsoet@ugent.be [Center for Molecular Modeling (CMM), Ghent University, Technologiepark 903, 9052 Zwijnaarde (Belgium); De Meyer, Thierry [Center for Molecular Modeling (CMM), Ghent University, Technologiepark 903, 9052 Zwijnaarde (Belgium); Department of Textiles, Ghent University, Technologiepark 907, 9052 Zwijnaarde (Belgium); De Clerck, Karen [Department of Textiles, Ghent University, Technologiepark 907, 9052 Zwijnaarde (Belgium)

    2014-04-07

    A Fourier-based method is presented to relate changes of the molecular structure during a molecular dynamics simulation with fluctuations in the electronic excitation energy. The method implies sampling of the ground state potential energy surface. Subsequently, the power spectrum of the velocities is compared with the power spectrum of the excitation energy computed using time-dependent density functional theory. Peaks in both spectra are compared, and motions exhibiting a linear or quadratic behavior can be distinguished. The quadratically active motions are mainly responsible for the changes in the excitation energy and hence cause shifts between the dynamic and static values of the spectral property. Moreover, information about the potential energy surface of various excited states can be obtained. The procedure is illustrated with three case studies. The first electronic excitation is explored in detail and dominant vibrational motions responsible for changes in the excitation energy are identified for ethylene, biphenyl, and hexamethylbenzene. The proposed method is also extended to other low-energy excitations. Finally, the vibrational fingerprint of the excitation energy of a more complex molecule, in particular the azo dye ethyl orange in a water environment, is analyzed.

  16. Electrostatic solvation free energies of charged hard spheres using molecular dynamics with density functional theory interactions

    Science.gov (United States)

    Duignan, Timothy T.; Baer, Marcel D.; Schenter, Gregory K.; Mundy, Chistopher J.

    2017-10-01

    Determining the solvation free energies of single ions in water is one of the most fundamental problems in physical chemistry and yet many unresolved questions remain. In particular, the ability to decompose the solvation free energy into simple and intuitive contributions will have important implications for models of electrolyte solution. Here, we provide definitions of the various types of single ion solvation free energies based on different simulation protocols. We calculate solvation free energies of charged hard spheres using density functional theory interaction potentials with molecular dynamics simulation and isolate the effects of charge and cavitation, comparing to the Born (linear response) model. We show that using uncorrected Ewald summation leads to unphysical values for the single ion solvation free energy and that charging free energies for cations are approximately linear as a function of charge but that there is a small non-linearity for small anions. The charge hydration asymmetry for hard spheres, determined with quantum mechanics, is much larger than for the analogous real ions. This suggests that real ions, particularly anions, are significantly more complex than simple charged hard spheres, a commonly employed representation.

  17. On Hoyle-Narlikar-Wheeler mechanism of vibration energy powered magneto-dipole emission of neutron stars

    OpenAIRE

    Bastrukov, S. I.; Yu, J. W.; Molodtsova, I. V.; Xu, R. X.

    2011-01-01

    We revisit the well-known Hoyle-Narlikar-Wheeler proposition that neutron star emerging in the magnetic-flux-conserving process of core-collapse supernova can convert the stored energy of Alfven vibrations into power of magneto-dipole radiation. We show that the necessary requirement for the energy conversion is the decay of internal magnetic field. In this case the loss of vibration energy of the star causes its vibration period, equal to period of pulsating emission, to lengthen at a rate p...

  18. Experimental energy harvesting from fluid flow by using two vibrating masses

    Science.gov (United States)

    Nishi, Yoshiki; Fukuda, Kengo; Shinohara, Wataru

    2017-04-01

    In this study, an experiment was performed to determine how the addition of a second degree of freedom to a vibratory system affects its energy extraction from a surrounding fluid flow. A circular cylinder was submerged underwater and subjected to flow, and another cylinder mounted on springs was inserted between the submerged cylinder and a generator. The experiment results demonstrated that vortex-induced vibration occurred at frequencies that were locked-in to the first and second natural modes for reduced velocity ranges of 5.0-9.0 and greater than 12.0, respectively. The output voltages were particularly high when the vibration frequency was locked-in to that of the second natural mode. It was found that application of energy extraction using a system with two degrees of freedom can widen the range of reduced velocity within which power extraction is effective.

  19. Piezoelectric vibration energy harvesters with stretched and multistacked organic ferroelectric films

    Science.gov (United States)

    Kajihara, Tadao; Ueno, Yoshikazu; Tsujiura, Yuichi; Koshiba, Yasuko; Morimoto, Masahiro; Kanno, Isaku; Ishida, Kenji

    2017-04-01

    We investigated piezoelectric vibration energy harvesters with poly(vinylidene fluoride/trifluoroethylene) films and the improved power generation from using multistacked and stretched ferroelectric films on the cantilevers. The energy harvesters generated electric power with a resonant frequency of approximately 25 Hz, which corresponded to the ambient vibration. The power density of four-layered harvesters was estimated to be 2.5 µW/m3, which was larger than the power density of previous harvesters. The output power of stretched-film harvesters was 3.6 times the output obtained from unstretched films. In addition, because organic ferroelectric films are flexible, the resonant frequency of each harvester was practically constant even when using the techniques of multistacking and stretching.

  20. Shoe-mounted vibration energy harvester of PZT piezoelectric thin films on metal foils

    Science.gov (United States)

    Nishi, T.; Ito, T.; Hida, H.; Kanno, I.

    2016-11-01

    This paper describes shoe-mounted piezoelectric vibration energy harvesters (PVEHs). The PVEHs were fabricated from Pb(ZrTi)O3 (PZT) thin films which were directly deposited onto Pt/Ti-coated stainless steel foil by rf-magnetron sputtering. We experimentally and theoretically evaluated impulse responses of the PVEHs by applying a simple impulse input on the energy harvesters, typical damped free vibration behaviour was clearly observed, and the output signal was in good agreement with the theoretical value. We measured the output power by applying the impulse input with an optimal load resistance of 33.9 kΩ. The maximum output power was approximately 20 μW, which correspond with the calculated value based on theoretical equation. From these results, the theoretical equation we derived might be helpful for design purposes of the shoe-mounted PVEHs.

  1. Vibrational Energy Levels via Finite-Basis Calculations Using a Quasi-Analytic Form of the Kinetic Energy.

    Science.gov (United States)

    Vázquez, Juana; Harding, Michael E; Stanton, John F; Gauss, Jürgen

    2011-05-10

    A variational method for the calculation of low-lying vibrational energy levels of molecules with small amplitude vibrations is presented. The approach is based on the Watson Hamiltonian in rectilinear normal coordinates and characterized by a quasi-analytic integration over the kinetic energy operator (KEO). The KEO beyond the harmonic approximation is represented by a Taylor series in terms of the rectilinear normal coordinates around the equilibrium configuration. This formulation of the KEO enables its extension to arbitrary order until numerical convergence is reached for those states describing small amplitude motions and suitably represented with a rectilinear system of coordinates. A Gauss-Hermite quadrature grid representation of the anharmonic potential is used for all the benchmark examples presented. Results for a set of molecules with linear and nonlinear configurations, i.e., CO2, H2O, and formyl fluoride (HFCO), illustrate the performance of the method and the versatility of our implementation.

  2. Analysis of vibroprotection characteristics of pneumatic relaxation seat suspension with capability of vibration energy recuperation

    OpenAIRE

    Lyashenko Mikhail; Potapov Pavel; Iskaliev Azamat

    2017-01-01

    This paper proposes mechanism and control algorithm for pneumatic relaxation system of suspension with vibration energy recuperation applied to standard vehicle operator seat (“Sibeko” company). Mathematical model of the seat pneumatic relaxation suspension with two additional air volumes was created. Pneumatic motor – recuperator activated by means of air flow from the one additional volume to another is installed in air piping between additional volumes. Computational research was made in M...

  3. Application of Energy Finite Element Method in Active Vibration Control of Piezoelectric Intelligent Beam

    Directory of Open Access Journals (Sweden)

    Jinhua Xie

    2012-01-01

    Full Text Available Based on the transmission and equilibrium relationship of vibration energy in beam-like structures, the Galerkin weighted residual method was applied to equation discretization. An equivalent transformation of feedback element was suggested to develop the Energy Finite Element model of a composite piezoelectric cantilever beam driven by harmonic excitation on lateral direction, with both systems with and without time delay being studied and the power input estimation of harmonic excitation was discussed for the resolution of Energy Finite Element function. Then the energy density solutions of the piezoelectric coupling beam through Energy Finite Element Method (EFEM and classical wave theory were compared to verify the EFEM model, which presented a good accordance. Further investigation was undertaken about the influence of control parameters including the feedback gain and arrangement of piezoelectric patches on characteristics of system energy density distribution.

  4. Expressions For Total Energy And Relativistic Kinetic Energy At Low Speeds In Special Relativity Must Include Rotational And Vibrational As Well As Linear Kinetic Energies

    Science.gov (United States)

    Brekke, Stewart

    2017-09-01

    Einstein calculated the total energy at low speeds in the Special Theory of Relativity to be Etotal =m0c2 + 1 / 2m0v2 . However, the total energy must include the rotational and vibrational kinetic energies as well as the linear kinetic energies. If 1 / 2 Iω2 is the expression for the rotational kinetic energy of mass and 1 / 2 kx02 is the vibrational kinetic energy expression of a typical mass, the expression for the total energy of a mass at low speeds must be Etotal =m0c2 + 1 / 2m0v2 + 1 / 2 Iω2 + 1 / 2 kx02 . If this expression is correct, the relativistic kinetic energy of a mass. at low speeds must include the rotational and vibrational kinetic energies as well as the linear kinetic energies since according to Einstein K = (m -m0) c2 and therefore, K = 1 / 2m0v2 + 1 / 2 Iω2 + 1 / 2 kx02 .

  5. Shear-horizontal vibration modes of an oblate elliptical cylinder and energy trapping in contoured acoustic wave resonators.

    Science.gov (United States)

    He, Huijing; Yang, Jiashi; Kosinski, John A

    2012-08-01

    We study shear-horizontal free vibrations of an elastic cylinder with an oblate elliptical cross section and a traction-free surface. Exact vibration modes and frequencies are obtained. The results show the existence of thickness-shear and thickness-twist modes. The energy-trapping behavior of these modes is examined. Trapped modes are found wherein the vibration energy is largely confined to the central portion of the cross section and little vibration energy is found at the edges. It is also shown that face-shear modes are not allowed in such a cylinder. The results are useful for the understanding of the energy trapping phenomenon in contoured acoustic wave resonators.

  6. First-Principles Vibrational Electron Energy Loss Spectroscopy of β -Guanine

    Science.gov (United States)

    Radtke, G.; Taverna, D.; Lazzeri, M.; Balan, E.

    2017-07-01

    A general approach to model vibrational electron energy loss spectra obtained using an electron beam positioned away from the specimen is presented. The energy-loss probability of the fast electron is evaluated using first-principles quantum mechanical calculations (density functional theory) of the dielectric response of the specimen. The validity of the method is assessed using recently measured anhydrous β -guanine, an important molecular solid used by animals to produce structural colors. The good agreement between theory and experiments lays the basis for a quantitative interpretation of this spectroscopy in complex systems.

  7. Optimisation of dynamic vibration absorbers to minimise kinetic energy and maximise internal power dissipation

    OpenAIRE

    Zilletti, Michele; Elliott, Stephen J.; Rustighi, Emiliano

    2012-01-01

    The tuning of a dynamic vibration absorber is considered such that either the kinetic energy of the host structure is minimised or the power dissipation within the absorber is maximised. If the host structure is approximated as a damped single degree of freedom, the optimal values for the ratio of the absorber's natural frequency to the host structure and the optimal damping ratio of the absorber are shown to be the same whether the kinetic energy of the host structure is minimised or the pow...

  8. Electrostatic accelerators

    CERN Document Server

    Hinterberger, F

    2006-01-01

    The principle of electrostatic accelerators is presented. We consider Cockcroft– Walton, Van de Graaff and Tandem Van de Graaff accelerators. We resume high voltage generators such as cascade generators, Van de Graaff band generators, Pelletron generators, Laddertron generators and Dynamitron generators. The speci c features of accelerating tubes, ion optics and methods of voltage stabilization are described. We discuss the characteristic beam properties and the variety of possible beams. We sketch possible applications and the progress in the development of electrostatic accelerators.

  9. Beamline electrostatic levitator for in situ high energy x-ray diffraction studies of levitated solids and liquids

    Energy Technology Data Exchange (ETDEWEB)

    Gangopadhyay, A.K.; Lee, G.W.; Kelto, K.F.; Rogers, J.R.; Goldman, A.I.; Robinson, D.S.; Rathz, T.J.; Hyers, R.W. (WU); (UAB); (NASA); (UMASS, Amherst)

    2010-07-19

    Determinations of the phase formation sequence, crystal structures and the thermo-physical properties of materials at high temperatures are hampered by contamination from the sample container and environment. Containerless processing techniques, such as electrostatic (ESL), electromagnetic, aerodynamic, and acoustic levitation, are most suitable for these studies. An adaptation of ESL for in situ structural studies of a wide range of materials using high energy (30-130 keV) x rays at a synchrotron source is described here. This beamline ESL (BESL) allows the in situ determination of the atomic structures of equilibrium solid and liquid phases, undercooled liquids and time-resolved studies of solid-solid and liquid-solid phase transformations. The use of area detectors enables the rapid acquisition of complete diffraction patterns over a wide range (0.5-14 {angstrom}{sup -1}) of reciprocal space. The wide temperature range (300-2500 K), containerless processing environment under high vacuum (10{sup -7}-10{sup -8} Torr), and fast data acquisition capability, make BESL particularly well suited for phase stability studies of high temperature solids and liquids. An additional, but important, feature of BESL is the capability for simultaneous measurements of a host of thermo-physical properties including the specific heat, enthalpy of transformation, solidus and liquidus temperatures, density, viscosity, and surface tension, all on the same sample during the structural measurements.

  10. Energy Expenditure and Substrate Oxidation in Response to Side-Alternating Whole Body Vibration across Three Commonly-Used Vibration Frequencies.

    Directory of Open Access Journals (Sweden)

    Elie-Jacques Fares

    Full Text Available There is increasing recognition about the importance of enhancing energy expenditure (EE for weight control through increases in low-intensity physical activities comparable with daily life (1.5-4 METS. Whole-body vibration (WBV increases EE modestly and could present both a useful adjuvant for obesity management and tool for metabolic phenotyping. However, it is unclear whether a "dose-response" exists between commonly-used vibration frequencies (VF and EE, nor if WBV influences respiratory quotient (RQ, and hence substrate oxidation. We aimed to investigate the EE-VF and RQ-VF relationships across three different frequencies (30, 40, and 50Hz.EE and RQ were measured in 8 healthy young adults by indirect calorimetry at rest, and subsequently during side-alternating WBV at one of 3 VFs (30, 40, and 50 Hz. Each frequency was assessed over 5 cycles of intermittent WBV (30s vibration/30s rest, separated by 5 min seated rest. During the WBV participants stood on the platform with knees flexed sufficiently to maintain comfort, prevent transmission of vibration to the upper body, and minimise voluntary physical exertion. Repeatability was assessed across 3 separate days in a subset of 4 individuals. In order to assess any sequence/habituation effect, an additional group of 6 men underwent 5 cycles of intermittent WBV (30s vibration/30s rest at 40 Hz, separated by 5 min seated rest.Side-alternating WBV increased EE relative to standing, non-vibration levels (+36%, p<0.001. However, no differences in EE were observed across VFs. Similarly, no effect of VF on RQ was found, nor did WBV alter RQ relative to standing without vibration.No relationship could be demonstrated between EE and VF in the range of 30-50Hz, and substrate oxidation did not change in response to WBV. Furthermore, the thermogenic effect of intermittent WBV, whilst robust, was quantitatively small (<2 METS.

  11. Micro electro-mechanical system piezoelectric cantilever array for a broadband vibration energy harvester.

    Science.gov (United States)

    Chun, Inwoo; Lee, Hyun-Woo; Kwon, Kwang-Ho

    2014-12-01

    Limited energy sources of ubiquitous sensor networks (USNs) such as fuel cells and batteries have grave drawbacks such as the need for replacements and re-charging owing to their short durability and environmental pollution. Energy harvesting which is converting environmental mechanical vibration into electrical energy has been researched with some piezoelectric materials and various cantilever designs to increase the efficiency of energy-harvesting devices. In this study, we focused on an energy-harvesting cantilever with a broadband vibration frequency. We fabricated a lead zirconate titanate (PZT) cantilever array with various Si proof masses on small beams (5.5 mm x 0.5 mm x 0.5 mm). We obtained broadband resonant frequencies ranging between 127 Hz and 136 Hz using a micro electro-mechanical system (MEMS) process. In order to obtain broadband resonant characteristics, the cantilever array was comprised of six cantilevers with different resonant frequencies. We obtained an output power of about 2.461 μW at an acceleration of 0.23 g and a resistance of 4 kΩ. The measured bandwidth of the resonant frequency was approximately 9 Hz (127-136 Hz), which is about six times wider than the bandwidth of a single cantilever.

  12. Dynamics of Transition Regime in Bi-stable Vibration Energy Harvesters

    KAUST Repository

    Ibrahim, Alwathiqbellah

    2017-04-20

    Vibration energy harvesting can be an effective method for scavenging wasted mechanical energy for use by wireless sensors that have limited battery life. Two major goals in designing energy harvesters are enhancing the power scavenged at low frequency and improving efficiency by increasing the frequency bandwidth. To achieve these goals, we derived a magneto-elastic beam operated at the transition between mono- and bi-stable regions. By improving the mathematical model of the interaction of magnetic force and beam dynamics, we obtained a precise prediction of natural frequencies as the distance of magnets varies. Using the shooting technique for the improved model, we present a fundamental understanding of interesting combined softening and hardening responses that happen at the transition between the two regimes. The transition regime is proposed as the optimal region for energy conversion in terms of frequency bandwidth and output voltage. Using this technique, low frequency vibration energy harvesting at around 17 Hz was possible. The theoretical results were in good agreement with the experimental results. The target application is to power wildlife bio-logging devices from bird flights that have consistent high power density around 16 Hz [1].

  13. A Vibration-Based MEMS Piezoelectric Energy Harvester and Power Conditioning Circuit

    Directory of Open Access Journals (Sweden)

    Hua Yu

    2014-02-01

    Full Text Available This paper presents a micro-electro-mechanical system (MEMS piezoelectric power generator array for vibration energy harvesting. A complete design flow of the vibration-based energy harvester using the finite element method (FEM is proposed. The modal analysis is selected to calculate the resonant frequency of the harvester, and harmonic analysis is performed to investigate the influence of the geometric parameters on the output voltage. Based on simulation results, a MEMS Pb(Zr,TiO3 (PZT cantilever array with an integrated large Si proof mass is designed and fabricated to improve output voltage and power. Test results show that the fabricated generator, with five cantilever beams (with unit dimensions of about 3 × 2.4 × 0.05 mm3 and an individual integrated Si mass dimension of about 8 × 12.4 × 0.5 mm3, produces a output power of 66.75 μW, or a power density of 5.19 μW∙mm−3∙g−2 with an optimal resistive load of 220 kΩ from 5 m/s2 vibration acceleration at its resonant frequency of 234.5 Hz. In view of high internal impedance characteristic of the PZT generator, an efficient autonomous power conditioning circuit, with the function of impedance matching, energy storage and voltage regulation, is then presented, finding that the efficiency of the energy storage is greatly improved and up to 64.95%. The proposed self-supplied energy generator with power conditioning circuit could provide a very promising complete power supply solution for wireless sensor node loads.

  14. Vibration attenuation of a continuous rotor-blisk-journal bearing system employing smooth nonlinear energy sinks

    Science.gov (United States)

    Bab, Saeed; Khadem, S. E.; Shahgholi, Majid; Abbasi, Amirhassan

    2017-02-01

    The current paper investigates the effects of a number of smooth nonlinear energy sinks (NESs) located on the disk and bearings on the vibration attenuation of a rotor-blisk-journal bearing system under excitation of a mass eccentricity force. The blade and rotor are modeled using the Euler-Bernoulli beam theory. The nonlinear energy sinks on the bearing have a linear damping and an essentially nonlinear stiffness. The nonlinear energy sinks on the disk have a linear damping, linear stiffness, and an essentially nonlinear stiffness. It can be seen that the linear stiffness of the NESs on the disk is eliminated by the negative stiffness induced by the centrifugal force, and the collection of the NESs can be tuned to a required rotational speed of the rotor by varying the linear stiffness of the NESs. Furthermore, the remained stiffness of the NESs on the disk after elimination of their linear stiffness, would be essentially a nonlinear (nonlinearizable) one. Two nonlinear energy sinks in the vertical axes are positioned on the bearing housing and nnd NESs are located on the perimeter of the disk. The equations of motion are extracted using the extended Hamilton principle. The modal coordinates and complex transformations are employed to decrease the number of equations of motion. A genetic algorithm is used to optimize the parameters of the nonlinear energy sinks and its objective function is considered as minimizing the vibration of the rotating system within an operating speed range. In order to examine the periodic and non-periodic solutions of the system, time history, bifurcation diagram, Poincaré map, phase portrait, Lyapunov exponent, and power spectra analyses are performed. System shows periodic and quasi-periodic motions for different values of the system parameters. It is shown that the NESs on the disk and bearings have almost local effects on vibration reduction of rotating system. In addition, the optimum NESs remove the instability region from the

  15. Vibration mitigation of a bridge cable using a nonlinear energy sink: design and experiment

    Directory of Open Access Journals (Sweden)

    Weiss Mathieu

    2015-01-01

    Full Text Available This work deals with the design and experiment of a cubic nonlinear energy sink (NES for horizontal vibration mitigation of a bridge cable. Modal analysis of horizontal linear modes of the cable is experimentally performed using accelerometers and displacement sensors. A theoretical simplified 2-dof model of the coupled cable-NES system is used to analytically design the NES by mean of multi-time scale systems behaviours and detection its invariant manifold, equilibrium and singular points which stand for periodic and strongly modulated regimes, respectively. Numerical integration is used to confirm the efficiency of the designed NES for the system under step release excitation. Then, the prototype system is built using geometrical cubic nonlinearity as the potential of the NES. Efficiency of the prototype system for mitigation of horizontal vibrations of the cable under for step release and forced excitations is experimentally demonstrated.

  16. Excitation of vibrational quanta in furfural by intermediate-energy electrons

    Energy Technology Data Exchange (ETDEWEB)

    Jones, D. B. [School of Chemical and Physical Sciences, Flinders University, GPO Box 2100, Adelaide, South Australia 5001 (Australia); Neves, R. F. C. [School of Chemical and Physical Sciences, Flinders University, GPO Box 2100, Adelaide, South Australia 5001 (Australia); Instituto Federal do Sul de Minas Gerais, Campus Poços de Caldas, Minas Gerais (Brazil); Departamento de Física, Universidade Federal de Juiz de Fora, 36036-900, Juiz de Fora, MG (Brazil); Lopes, M. C. A. [Departamento de Física, Universidade Federal de Juiz de Fora, 36036-900, Juiz de Fora, MG (Brazil); Costa, R. F. da [Instituto de Física “Gleb Wataghin,” Universidade Estadual de Campinas, Campinas, 13083-859 São Paulo (Brazil); Centro de Ciências Naturais e Humanas, Universidade Federal do ABC, Santo André, 09210-580 São Paulo (Brazil); Varella, M. T. do N. [Instituto de Física, Universidade de São Paulo, CP 66318, 05315-970 São Paulo, São Paulo (Brazil); Bettega, M. H. F. [Departamento de Física, Universidade Federal do Paraná, CP 19044, 81531-990 Curitiba, Paraná (Brazil); Lima, M. A. P. [Instituto de Física “Gleb Wataghin,” Universidade Estadual de Campinas, Campinas, 13083-859 São Paulo (Brazil); García, G. [Instituto de Física Fundamental, CSIC, Serrano 113-bis, 28006 Madrid (Spain); and others

    2015-12-14

    We report cross sections for electron-impact excitation of vibrational quanta in furfural, at intermediate incident electron energies (20, 30, and 40 eV). The present differential cross sections are measured over the scattered electron angular range 10°–90°, with corresponding integral cross sections subsequently being determined. Furfural is a viable plant-derived alternative to petrochemicals, being produced via low-temperature plasma treatment of biomass. Current yields, however, need to be significantly improved, possibly through modelling, with the present cross sections being an important component of such simulations. To the best of our knowledge, there are no other cross sections for vibrational excitation of furfural available in the literature, so the present data are valuable for this important molecule.

  17. Experimental characterization of cantilever-type piezoelectric generator operating at resonance for vibration energy harvesting

    Energy Technology Data Exchange (ETDEWEB)

    Montanini, Roberto, E-mail: rmontanini@unime.it; Quattrocchi, Antonino, E-mail: aquattrocchi@unime.it [University of Messina, Dept. of Engineering, Contrada di Dio, Messina (Italy)

    2016-06-28

    A cantilever-type resonant piezoelectric generator (RPG) has been designed by gluing a PZT patch working in d{sub 31} mode onto a glass fibre reinforced composite cantilever beam with a discrete mass applied on its free end. The electrical and dynamic behaviour of the RPG prototype has been investigated by carrying out laboratory tests aimed to assess the effect of definite design parameters, specifically the electric resistance load and the excitation frequency. Results showed that an optimum resistance load exists, at which power generation is maximized. Moreover, it has been showed that power generation is strongly influenced by the vibration frequency highlighting that, at resonance, output power can be increased by more than one order of magnitude. Possible applications include inertial resonant harvester for energy recovery from vibrating machines, sea waves or wind flux and self-powering of wireless sensor nodes.

  18. Micro-scale piezoelectric vibration energy harvesting: From fixed-frequency to adaptable-frequency devices

    Science.gov (United States)

    Miller, Lindsay Margaret

    Wireless sensor networks (WSNs) have the potential to transform engineering infrastructure, manufacturing, and building controls by allowing condition monitoring, asset tracking, demand response, and other intelligent feedback systems. A wireless sensor node consists of a power supply, sensor(s), power conditioning circuitry, radio transmitter and/or receiver, and a micro controller. Such sensor nodes are used for collecting and communicating data regarding the state of a machine, system, or process. The increasing demand for better ways to power wireless devices and increase operation time on a single battery charge drives an interest in energy harvesting research. Today, wireless sensor nodes are typically powered by a standard single-charge battery, which becomes depleted within a relatively short timeframe depending on the application. This introduces tremendous labor costs associated with battery replacement, especially when there are thousands of nodes in a network, the nodes are remotely located, or widely-distributed. Piezoelectric vibration energy harvesting presents a potential solution to the problems associated with too-short battery life and high maintenance requirements, especially in industrial environments where vibrations are ubiquitous. Energy harvester designs typically use the harvester to trickle charge a rechargeable energy storage device rather than directly powering the electronics with the harvested energy. This allows a buffer between the energy harvester supply and the load where energy can be stored in a "tank". Therefore, the harvester does not need to produce the full required power at every instant to successfully power the node. In general, there are tens of microwatts of power available to be harvested from ambient vibrations using micro scale devices and tens of milliwatts available from ambient vibrations using meso scale devices. Given that the power requirements of wireless sensor nodes range from several microwatts to about one

  19. Assistance of molecular vibrations on coherent energy transfer in photosynthesis from the view of a quantum heat engine.

    Science.gov (United States)

    Zhang, Zhedong; Wang, Jin

    2015-04-02

    Recently, the quantum nature in the energy transport in solar cells and light-harvesting complexes has attracted much attention as being triggered by the experimental observations. We model the light-harvesting complex (i.e., PEB50 dimer) as a quantum heat engine (QHE) and study the effect of the undamped intramolecule vibrational modes on the coherent energy-transfer process and quantum transport. We find that the exciton-vibration interaction has nontrivial contribution to the promotion of quantum yield as well as transport properties of the QHE at steady state by enhancing the quantum coherence quantified by entanglement entropy. The perfect quantum yield over 90% has been obtained, with the exciton-vibration coupling. We attribute these improvements to the renormalization of the electronic couplings effectively induced by exciton-vibration interaction and the subsequent delocalization of excitons. Finally, we demonstrate that the thermal relaxation and dephasing can help the excitation energy transfer in the PEB50 dimer.

  20. Multipolar electrostatics.

    Science.gov (United States)

    Cardamone, Salvatore; Hughes, Timothy J; Popelier, Paul L A

    2014-06-14

    Atomistic simulation of chemical systems is currently limited by the elementary description of electrostatics that atomic point-charges offer. Unfortunately, a model of one point-charge for each atom fails to capture the anisotropic nature of electronic features such as lone pairs or π-systems. Higher order electrostatic terms, such as those offered by a multipole moment expansion, naturally recover these important electronic features. The question remains as to why such a description has not yet been widely adopted by popular molecular mechanics force fields. There are two widely-held misconceptions about the more rigorous formalism of multipolar electrostatics: (1) Accuracy: the implementation of multipole moments, compared to point-charges, offers little to no advantage in terms of an accurate representation of a system's energetics, structure and dynamics. (2) Efficiency: atomistic simulation using multipole moments is computationally prohibitive compared to simulation using point-charges. Whilst the second of these may have found some basis when computational power was a limiting factor, the first has no theoretical grounding. In the current work, we disprove the two statements above and systematically demonstrate that multipole moments are not discredited by either. We hope that this perspective will help in catalysing the transition to more realistic electrostatic modelling, to be adopted by popular molecular simulation software.

  1. Vibration Energy Harvesting on Vehicle Suspension Using Rotary and Linear Electromagnetic Generator

    Directory of Open Access Journals (Sweden)

    Arif Indro Sultoni

    2013-04-01

    Full Text Available In this paper, we discuss comparation of vehicle vibration energy harvesting between rotary and linear electromagnetic generator. We construct the two model of energy harvester mechanism and then analyze both of energy absorbtion and vehicle comfortability. Furthermore, we analyze both of energy absorbtion and vehicle comfortability. Vehicle is modeled as quarter car. Rotarty generator harvests 2.5 x 10-4 Watt. The other hand, linear generator has viscous characteristic and capable to generates 90 Watts with 12 Volt power supply for 0.03 m amplitude of bumpy road input. Linear generator reduces oscillation with 1.2 sec settling time. It is more comfort than the angular which has 3 sec in settling time. With unnevenees road input, mean power of this generator is 64 Watt.

  2. Non-adiabatic corrections to the energies of the pure vibrational states of H2

    Science.gov (United States)

    Bubin, Sergiy; Leonarski, Filip; Stanke, Monika; Adamowicz, Ludwik

    2009-07-01

    Nonrelativistic energies of all fifteen pure vibrational states of the H molecule have been recalculated with much higher accuracy than before. In the calculations we employed explicitly correlated Gaussian functions and an approach where the Born-Oppenheimer (BO) approximation is not assumed. The wave function of each state was expanded in terms of 10 000 Gaussians whose nonlinear parameters were optimized using a procedure involving the analytical energy gradient. The obtained non-BO energies combined with the recent BO adiabatic energies of Pachucki and Komasa [K. Pachucki, J. Komasa, J. Chem. Phys. 129 (2008) 034102] allowed us to determine new improved values of the non-adiabatic corrections for the considered states.

  3. Research and design of underwater flow-induced vibration energy harvester based on Karman vortex street

    Science.gov (United States)

    Yao, Gang; Wang, Hai; Yang, Chunlai; Wen, Li

    2017-03-01

    With the increasing development of wireless sensor network (WSN), power supply for WSN nodes had attracted increasing attention, and the energy harvesting system based on Karman vortex street has been widely used in underwater WSN. But the research of the influences of affecting factors towards the energy harvesting system is yet to be completed. So, in this paper, an underwater flow-induced vibration energy harvesting system based on Karman vortex street was proposed and tested. The influence of bluff body geometry and flow velocity towards the performance of the energy harvesting has been researched. The results showed that the output voltage increased as the diameter of bluff body and the water velocity increase. The power generation efficiency was the best when the shape of bluff body was circular.

  4. Vibration energy harvesting based on integrated piezoelectric components operating in different modes.

    Science.gov (United States)

    Hu, Junhui; Jong, Januar; Zhao, Chunsheng

    2010-01-01

    To increase the vibration energy-harvesting capability of the piezoelectric generator based on a cantilever beam, we have proposed a piezoelectric generator that not only uses the strain change of piezoelectric components bonded on a cantilever beam, but also employs the weights at the tip of the cantilever beam to hit piezoelectric components located on the 2 sides of weights. A prototype of the piezoelectric generator has been fabricated and its characteristics have been measured and analyzed. The experimental results show that the piezoelectric components operating in the hit mode can substantially enhance the energy harvesting of the piezoelectric generator on a cantilever beam. Two methods are used and compared in the management of rectified output voltages from different groups of piezoelectric components. In one of them, the DC voltages from rectifiers are connected in series, and then the total DC voltage is applied to a capacitor. In another connection, the DC voltage from each group is applied to different capacitors. It is found that 22.3% of the harvested energy is wasted due to the series connection. The total output electric energy of our piezoelectric generator at nonresonance could be up to 43 nJ for one vibration excitation applied by spring, with initial vibration amplitude (0-p) of 18 mm and frequency of 18.5 Hz, when the rectified voltages from different groups of piezoelectric components are connected to their individual capacitors. In addition, the motion and impact of the weights at the tip of the cantilever beam are theoretically analyzed, which well explains the experimental phenomena and suggests the measures to improve the generator.

  5. Microstereolithography of Three-Dimensional Polymeric Springs for Vibration Energy Harvesting

    Directory of Open Access Journals (Sweden)

    Evan Baker

    2012-01-01

    Full Text Available The inefficiency in converting low frequency vibration (6~240 Hz to electrical energy remains a key issue for miniaturized vibration energy harvesting devices. To address this subject, this paper reports on the novel, three-dimensional micro-fabrication of spring elements within such devices, in order to achieve resonances and maximum energy conversion within these common frequencies. The process, known as projection microstereolithography, is exploited to fabricate polymer-based springs direct from computer-aided designs using digital masks and ultraviolet-curable resins. Using this process, a micro-spring structure is fabricated consisting of a two-by-two array of three-dimensional, constant-pitch helical coils made from 1,6-hexanediol diacrylate. Integrating the spring structure into an electromagnetic device, with a magnetic load mass of 1.236 grams, the resonance is measured at 61 Hz, which is within 2% of the theoretical model. The device provides a maximum normalized power output of 9.14 μW/G (G=9.81 ms−2 and an open circuit normalized voltage output of 621 mV/G. To the best of the authors knowledge, notable features of this work include the lowest Young’s modulus (530 MPa, density (1.011 g/cm3, and “largest feature size” (3.4 mm for a spring element in a vibration energy harvesting device with sub-100 Hz resonance.

  6. Charging power optimization for nonlinear vibration energy harvesting systems subjected to arbitrary, persistent base excitations

    Science.gov (United States)

    Dai, Quanqi; Harne, Ryan L.

    2018-01-01

    The vibrations of mechanical systems and structures are often a combination of periodic and random motions. Emerging interest to exploit nonlinearities in vibration energy harvesting systems for charging microelectronics may be challenged by such reality due to the potential to transition between favorable and unfavorable dynamic regimes for DC power delivery. Therefore, a need exists to devise an optimization method whereby charging power from nonlinear energy harvesters remains maximized when excitation conditions are neither purely harmonic nor purely random, which have been the attention of past research. This study meets the need by building from an analytical approach that characterizes the dynamic response of nonlinear energy harvesting platforms subjected to combined harmonic and stochastic base accelerations. Here, analytical expressions are formulated and validated to optimize charging power while the influences of the relative proportions of excitation types are concurrently assessed. It is found that about a 2 times deviation in optimal resistive loads can reduce the charging power by 20% when the system is more prominently driven by harmonic base accelerations, whereas a greater proportion of stochastic excitation results in a 11% reduction in power for the same resistance deviation. In addition, the results reveal that when the frequency of a predominantly harmonic excitation deviates by 50% from optimal conditions the charging power reduces by 70%, whereas the same frequency deviation for a more stochastically dominated excitation reduce total DC power by only 20%. These results underscore the need for maximizing direct current power delivery for nonlinear energy harvesting systems in practical operating environments.

  7. Comparative structural and vibrational study of the four lowest energy conformers of serotonin

    Science.gov (United States)

    Jha, Omkant; Yadav, T. K.; Yadav, R. A.

    2017-02-01

    A computational investigation of all possible lowest energy conformers of serotonin was carried out at the B3LYP/6-311 ++G** level. Out of the 14 possible lowest energy conformers, the first 4 conformers were investigated thoroughly for the optimized geometries, fundamental frequencies, the potential energy distributions, APT and natural charges, natural bond orbital (NBO) analysis, MEP, Contour map, total density array, HOMO, LUMO energies. The second third and fourth conformers are energetically at higher temperatures of 78, 94 and 312 K respectively with respect to the first one. Bond angles and bond lengths do not show significant variations while the dihedral angles vary significantly in going from one conformer to the other. Some of the vibrational modes of the indole moiety are conformation dependent to some extent whereas most of the normal modes of vibration of amino-ethyl side chain vary significantly in going from one conformer to conformer. The MEP for the four conformers suggested that the sites of the maximum positive and negative ESP change on changing the conformation. The charges at some atomic sites also change significantly from conformer to conformer.

  8. High resolution IR diode laser study of collisional energy transfer between highly vibrationally excited monofluorobenzene and CO2: the effect of donor fluorination on strong collision energy transfer.

    Science.gov (United States)

    Kim, Kilyoung; Johnson, Alan M; Powell, Amber L; Mitchell, Deborah G; Sevy, Eric T

    2014-12-21

    Collisional energy transfer between vibrational ground state CO2 and highly vibrationally excited monofluorobenzene (MFB) was studied using narrow bandwidth (0.0003 cm(-1)) IR diode laser absorption spectroscopy. Highly vibrationally excited MFB with E' = ∼41,000 cm(-1) was prepared by 248 nm UV excitation followed by rapid radiationless internal conversion to the electronic ground state (S1→S0*). The amount of vibrational energy transferred from hot MFB into rotations and translations of CO2 via collisions was measured by probing the scattered CO2 using the IR diode laser. The absolute state specific energy transfer rate constants and scattering probabilities for single collisions between hot MFB and CO2 were measured and used to determine the energy transfer probability distribution function, P(E,E'), in the large ΔE region. P(E,E') was then fit to a bi-exponential function and extrapolated to the low ΔE region. P(E,E') and the biexponential fit data were used to determine the partitioning between weak and strong collisions as well as investigate molecular properties responsible for large collisional energy transfer events. Fermi's Golden rule was used to model the shape of P(E,E') and identify which donor vibrational motions are primarily responsible for energy transfer. In general, the results suggest that low-frequency MFB vibrational modes are primarily responsible for strong collisions, and govern the shape and magnitude of P(E,E'). Where deviations from this general trend occur, vibrational modes with large negative anharmonicity constants are more efficient energy gateways than modes with similar frequency, while vibrational modes with large positive anharmonicity constants are less efficient at energy transfer than modes of similar frequency.

  9. Electromagnetic Linear Vibration Energy Harvester Using Sliding Permanent Magnet Array and Ferrofluid as a Lubricant

    Directory of Open Access Journals (Sweden)

    Song Hee Chae

    2017-09-01

    Full Text Available We present an electromagnetic linear vibration energy harvester with an array of rectangular permanent magnets as a springless proof mass. Instead of supporting the magnet assembly with spring element, ferrofluid has been used as a lubricating material. When external vibration is applied laterally to the harvester, magnet assembly slides back and forth on the channel with reduced friction and wear due to ferrofluid, which significantly improves the long-term reliability of the device. Electric power is generated across an array of copper windings formed at the bottom of the aluminum housing. A proof-of-concept harvester has been fabricated and tested with a vibration exciter at various input frequencies and accelerations. For the device where 5 μL of ferrofluid was used for lubrication, maximum output power of 493 μW has been generated, which was 4.37% higher than that without ferrofluid. Long-term reliability improvement due to ferrofluid lubrication has also been verified. For the device with ferrofluid, 1.02% decrease of output power has been observed, in contrast to 59.73% decrease of output power without ferrofluid after 93,600 cycles.

  10. A piezoelectric brace for passive suppression of structural vibration and energy harvesting

    Science.gov (United States)

    Yang, Chuang-Sheng Walter; Lai, Yong-An; Kim, Jin-Yeon

    2017-08-01

    Power outage after an earthquake would cause an additional chaos to the existing aftermath, greatly aggravating the situation if the outage lasts for an extended period. This research aims at developing an innovative piezoelectric brace, which provides both passive energy-dissipating and energy-harvesting capabilities—a passive suppression of structural vibrations and conversion of vibration energy into reusable electricity. The piezoelectric brace has compression modules that exert compressive loads on the piezoelectric material regardless if the brace is in compression or in tension. The compression module consists of a piezoelectric stack and rubber pads. The rubber pads are used to limit the maximum strain in the piezoelectric material below the allowable operational strain. The electro-mechanical equations of motion are derived for a 1-story and a 3-story frame model with the piezoelectric braces. To evaluate the structural behavior and the energy harvesting performance, numerical simulations are executed for the two model buildings (in downtown Los Angeles) that are equipped with the piezoelectric braces. The effects of design parameters including the geometry of the piezoelectric stack and rubber pads and the electric resistance in the electro-mechanical conversion circuit on the performance are investigated. The numerical results indicate that the piezoelectric braces passively dissipate energy through inclined oval-shaped hysteretic loops. The harvested energy is up to approximately 40% of the input energy. The structural displacements are significantly reduced, as compared to the original frames without the piezoelectric braces. Finally, a design procedure for a frame with the proposed passive piezoelectric braces is also presented.

  11. Fast vibrational calculation of anharmonic OH-stretch frequencies for two low-energy noradrenaline conformers

    Science.gov (United States)

    Benoit, David M.

    2008-12-01

    We introduce a new reduced-coupling technique to accelerate direct calculations of a selected number of vibrational frequencies in large molecular systems. Our method combines the advantages of the single-to-all correlation-corrected vibrational self-consistent field (STA-CC-VSCF) approach [D. M. Benoit, J. Chem. Phys. 125, 244110 (2006)] with those of the fast-CC-VSCF technique [D. M. Benoit, J. Chem. Phys. 120, 562 (2004)] and allows the ab initio calculation of only the relevant parts of the required potential energy surface (PES). We demonstrate, using a set of five aliphatic alcohol molecules, that the new fast-STA-CC-VSCF method is accurate and leads to very substantial time gains for the computations of the PES. We then use the fast-STA-CC-VSCF method to accelerate the computation of the OH-stretch and NH-stretch frequencies of the two lowest-energy conformers of noradrenaline, namely, AG1a and GG1a. Our new approach enables us to run the calculation 89 times faster than the standard CC-VSCF technique and makes it possible to use a high-level MP2/TZP description of the PES. We demonstrate that the influence of the strong mode-mode couplings is crucial for a realistic description of the particular OH-stretch vibrational signature of each conformer. Finally, of the two possible low-energy conformers, we identify AG1a as the one most likely to have been observed in the experiments of Snoek et al. [Mol. Phys. 101, 1239 (2003)].

  12. Motion characteristics and output voltage analysis of micro-vibration energy harvester based on diamagnetic levitation

    Science.gov (United States)

    Ye, Zhitong; Duan, Zhiyong; Takahata, Kenichi; Su, Yufeng

    2015-01-01

    In this paper, the force analysis and output performance of the micro-vibration energy harvester are elaborated. The force of the floating magnet in the magnetic field of the lifting magnet is firstly analyzed. Using COMSOL™, the change of magnetic force exerted on the floating magnet versus the vertical distance and the horizontal eccentric distance is obtained for different lifting magnets of a cylinder, a ring and an inner cylinder plus an outer ring, respectively. When the distance between the lifting and floating magnets ranges from 7.3 to 8.1 mm, the change rate of the magnetic force versus the vertical distance for the inner cylinder plus outer ring structure is the smallest, whose value is 619 µN/mm. In other words, if the inner cylinder plus outer ring structure is used as the lifting magnet, the vibration space of the floating magnet is the largest, which is 8 and 7.6 % larger than the cylinder and ring lifting magnets, respectively. The horizontal restoring forces of the three structures are substantially equal to each other at the horizontal eccentric distance of 4 mm, which is around 860 µN. Then the equilibrium position change of the floating magnet is discussed when the energy harvester is in an inclined position. Finally, by the analysis of the vibration model, the output performances of the energy harvester are comparatively calculated under the vertical and inclined positions. At the natural frequency of 6.93 Hz, the maximum power of 66.7 µW is generated.

  13. Energy Expenditure and Substrate Oxidation in Response to Side-Alternating Whole Body Vibration across Three Commonly-Used Vibration Frequencies.

    Science.gov (United States)

    Fares, Elie-Jacques; Charrière, Nathalie; Montani, Jean-Pierre; Schutz, Yves; Dulloo, Abdul G; Miles-Chan, Jennifer L

    2016-01-01

    There is increasing recognition about the importance of enhancing energy expenditure (EE) for weight control through increases in low-intensity physical activities comparable with daily life (1.5-4 METS). Whole-body vibration (WBV) increases EE modestly and could present both a useful adjuvant for obesity management and tool for metabolic phenotyping. However, it is unclear whether a "dose-response" exists between commonly-used vibration frequencies (VF) and EE, nor if WBV influences respiratory quotient (RQ), and hence substrate oxidation. We aimed to investigate the EE-VF and RQ-VF relationships across three different frequencies (30, 40, and 50Hz). EE and RQ were measured in 8 healthy young adults by indirect calorimetry at rest, and subsequently during side-alternating WBV at one of 3 VFs (30, 40, and 50 Hz). Each frequency was assessed over 5 cycles of intermittent WBV (30s vibration/30s rest), separated by 5 min seated rest. During the WBV participants stood on the platform with knees flexed sufficiently to maintain comfort, prevent transmission of vibration to the upper body, and minimise voluntary physical exertion. Repeatability was assessed across 3 separate days in a subset of 4 individuals. In order to assess any sequence/habituation effect, an additional group of 6 men underwent 5 cycles of intermittent WBV (30s vibration/30s rest) at 40 Hz, separated by 5 min seated rest. Side-alternating WBV increased EE relative to standing, non-vibration levels (+36%, pvibration. No relationship could be demonstrated between EE and VF in the range of 30-50Hz, and substrate oxidation did not change in response to WBV. Furthermore, the thermogenic effect of intermittent WBV, whilst robust, was quantitatively small (<2 METS).

  14. Instantaneous pair theory for high-frequency vibrational energy relaxation in fluids

    Science.gov (United States)

    Larsen, Ross E.; Stratt, Richard M.

    1999-01-01

    Notwithstanding the long and distinguished history of studies of vibrational energy relaxation, exactly how it is that high frequency vibrations manage to relax in a liquid remains somewhat of a mystery. Both experimental and theoretical approaches seem to say that there is a natural frequency range associated with intermolecular motion in liquids, typically spanning no more than a few hundred cm-1. Landau-Teller-type theories explain rather easily how a solvent can absorb any vibrational energy within this "band," but how is it that molecules can rid themselves of superfluous vibrational energies significantly in excess of these values? In this paper we develop a theory for such processes based on the idea that the crucial liquid motions are those that most rapidly modulate the force on the vibrating coordinate — and that by far the most important of these motions are those involving what we have called the mutual nearest neighbors of the vibrating solute. Specifically, we suggest that whenever there is a single solvent molecule sufficiently close to the solute that the solvent and solute are each other's nearest neighbors, then the instantaneous scattering dynamics of the solute-solvent pair alone suffices to explain the high-frequency relaxation. This highly reduced version of the dynamics has implications for some of the previous theoretical formulations of this problem. Previous instantaneous-normal-mode theories allowed us to understand the origin of a band of liquid frequencies, and even had some success in predicting relaxation within this band, but lacking a sensible picture of the effects of liquid anharmonicity on dynamics, were completely unable to treat higher frequency relaxation. When instantaneous-normal-mode dynamics is used to evaluate the instantaneous pair theory, though, we end up with a multiphonon picture of the relaxation which is in excellent agreement with the exact high-frequency dynamics — suggesting that the critical anharmonicity

  15. Vibration absorption in systems with a nonlinear energy sink: Nonlinear damping

    Science.gov (United States)

    Starosvetsky, Y.; Gendelman, O. V.

    2009-07-01

    In this work, response regimes are investigated in a system comprising of a linear oscillator (subject to harmonic excitation) and a nonlinear energy sink (NES) with nonlinear damping characteristics. An analytical technique for the treatment of certain class of nonlinear damping functions is developed. Special attention is paid to the case of piecewise-quadratic damping, motivated by possible applications. It is demonstrated that the NES with a properly tuned piecewise-quadratic damping element allows complete elimination of undesirable periodic regimes. In this way, an efficient system of vibration absorption is obtained, and its performance can overcome that of a tuned mass damper (TMD). Numerical results agree satisfactorily with the analytical predictions.

  16. Measurement of flexoelectric response in polyvinylidene fluoride films for piezoelectric vibration energy harvesters

    Science.gov (United States)

    Choi, Seung-Bok; Kim, Gi-Woo

    2017-02-01

    This study presents an investigation on the measurement of flexoelectric response in β-phase polyvinylidene fluoride (PVDF) films attached on cantilever beam-based flexible piezoelectric vibration energy harvesters (PVEHs). The flexoelectric response associated with negative strain gradients was simulated through harmonic response analysis by using the finite element method (FEM). The polarization frequency response functions (FRFs) modified by direct flexoelectric effect of PVDF films was experimentally validated by multi-mode FRFs. From quantitative comparisons between experimental observations and simulated estimation of FRFs, it is demonstrated that the direct flexoelectric response can be observed in PVDF films attached on PVEHs.

  17. Design and experiment of controlled bistable vortex induced vibration energy harvesting systems operating in chaotic regions

    Science.gov (United States)

    Huynh, B. H.; Tjahjowidodo, T.; Zhong, Z.-W.; Wang, Y.; Srikanth, N.

    2018-01-01

    Vortex induced vibration based energy harvesting systems have gained interests in these recent years due to its potential as a low water current energy source. However, the effectiveness of the system is limited only at a certain water current due to the resonance principle that governs the concept. In order to extend the working range, a bistable spring to support the structure is introduced on the system. The improvement on the performance is essentially dependent on the bistable gap as one of the main parameters of the nonlinear spring. A sufficiently large bistable gap will result in a significant performance improvement. Unfortunately, a large bistable gap might also increase a chance of chaotic responses, which in turn will result in diminutive harvested power. To mitigate the problem, an appropriate control structure is required to stabilize the chaotic vibrations of a VIV energy converter with the bistable supporting structure. Based on the nature of the double-well potential energy in a bistable spring, the ideal control structure will attempt to drive the responses to inter-well periodic vibrations in order to maximize the harvested power. In this paper, the OGY control algorithm is designed and implemented to the system. The control strategy is selected since it requires only a small perturbation in a structural parameter to execute the control effort, thus, minimum power is needed to drive the control input. Facilitated by a wake oscillator model, the bistable VIV system is modelled as a 4-dimensional autonomous continuous-time dynamical system. To implement the controller strategy, the system is discretized at a period estimated from the subspace hyperplane intersecting to the chaotic trajectory, whereas the fixed points that correspond to the desired periodic orbits are estimated by the recurrence method. Simultaneously, the Jacobian and sensitivity matrices are estimated by the least square regression method. Based on the defined fixed point and the

  18. Mode shape combination in a two-dimensional vibration energy harvester through mass loading structural modification

    Energy Technology Data Exchange (ETDEWEB)

    Sharpes, Nathan; Kumar, Prashant [Center for Energy Harvesting Materials and Systems (CEHMS), Virginia Tech, Blacksburg, Virginia 24061 (United States); Abdelkefi, Abdessattar; Abdelmoula, Hichem [Department of Mechanical and Aerospace Engineering, New Mexico State University, Las Cruces, New Mexico 88003 (United States); Adler, Jan [Center for Energy Harvesting Materials and Systems (CEHMS), Virginia Tech, Blacksburg, Virginia 24061 (United States); Institute of Dynamics and Vibration Research (IDS), Leibniz Universität, Hannover 30167 (Germany); Priya, Shashank [Center for Energy Harvesting Materials and Systems (CEHMS), Virginia Tech, Blacksburg, Virginia 24061 (United States); Bio-Inspired Materials and Devices Laboratory (BMDL), Virginia Tech, Blacksburg, Virginia 24061 (United States)

    2016-07-18

    Mode shapes in the design of mechanical energy harvesters, as a means of performance increase, have been largely overlooked. Currently, the vast majority of energy harvester designs employ some variation of a single-degree-of-freedom cantilever, and the mode shapes of such beams are well known. This is especially true for the first bending mode, which is almost exclusively the chosen vibration mode for energy harvesting. Two-dimensional beam shapes (those which curve, meander, spiral, etc., in a plane) have recently gained research interest, as they offer freedom to modify the vibration characteristics of the harvester beam for achieving higher power density. In this study, the second bending mode shape of the “Elephant” two-dimensional beam shape is examined, and its interaction with the first bending mode is evaluated. A combinatory mode shape created by using mass loading structural modification to lower the second bending modal frequency was found to interact with the first bending mode. This is possible since the first two bending modes do not share common areas of displacement. The combined mode shape is shown to produce the most power of any of the considered mode shapes.

  19. The Assistance of Molecular Vibrations on Coherent Energy Transfer in Photosynthesis from the View of Quantum Heat Engine

    CERN Document Server

    Zhang, Zhedong

    2015-01-01

    Recently the quantum nature in the energy transport in solar cell and light-harvesting complexes have attracted much attention, as being triggered by the experimental observations. We model the light-harvesting complex (i.e., PEB50 dimer) as a quantum heat engine (QHE) and study the effect of the undamped intra-molecule vibrational modes on the coherent energy transfer process and quantum transport. We find that the exciton-vibration interaction has non-trivial contribution to the promotion of quantum yield as well as transport properties of the quantum heat engine at steady state, by enhancing the quantum coherence quantified by entanglement entropy. The perfect quantum yield over 90% has been obtained, with theexciton-vibration coupling. We attribute these improvements to the renormalization of the electronic couplings effectively induced by exciton-vibration interaction and the subsequent delocalization of excitons. Finally we demonstrate that the thermal relaxation and dephasing can help the excitation en...

  20. On the Nonlinear Behavior of the Piezoelectric Coupling on Vibration-Based Energy Harvesters

    Directory of Open Access Journals (Sweden)

    Luciana L. Silva

    2015-01-01

    Full Text Available Vibration-based energy harvesting with piezoelectric elements has an increasing importance nowadays being related to numerous potential applications. A wide range of nonlinear effects is observed in energy harvesting devices and the analysis of the power generated suggests that they have considerable influence on the results. Linear constitutive models for piezoelectric materials can provide inconsistencies on the prediction of the power output of the energy harvester, mainly close to resonant conditions. This paper investigates the effect of the nonlinear behavior of the piezoelectric coupling. A one-degree of freedom mechanical system is coupled to an electrical circuit by a piezoelectric element and different coupling models are investigated. Experimental tests available in the literature are employed as a reference establishing the best matches of the models. Subsequently, numerical simulations are carried out showing different responses of the system indicating that nonlinear piezoelectric couplings can strongly modify the system dynamics.

  1. Design and Experimental Characterization of a Vibration Energy Harvesting Device for Rotational Systems

    Directory of Open Access Journals (Sweden)

    Lutao Yan

    2013-01-01

    Full Text Available This paper presents a new vibration based electromagnetic power generator to transfer energy from stationary to rotating equipment, which can be a new attempt to substitute slip ring in rotational systems. The natural frequencies and modes are simulated in order to have a maximum and steady power output from the device. Parameters such as piezoelectric disk location and relative motion direction of the magnet are theoretically and experimentally analyzed. The results show that the position that is close to the fixed end of the cantilever and the relative motion along the long side gives higher power output. Moreover, the capability of the energy harvester to extract power from lower energy environment is experimentally validated. The voltage and power output are measured at different excitation frequencies.

  2. Orientation of bluff body for designing efficient energy harvesters from vortex-induced vibrations

    Energy Technology Data Exchange (ETDEWEB)

    Dai, H. L. [Department of Mechanics, Huazhong University of Science and Technology, Wuhan 430074 (China); School of Civil and Environmental Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Abdelkefi, A. [Department of Mechanical and Aerospace Engineering, New Mexico State University, Las Cruces, New Mexico 88003 (United States); Yang, Y., E-mail: cywyang@ntu.edu.sg [School of Civil and Environmental Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Wang, L. [Department of Mechanics, Huazhong University of Science and Technology, Wuhan 430074 (China)

    2016-02-01

    The characteristics and performances of four distinct vortex-induced vibrations (VIVs) piezoelectric energy harvesters are experimentally investigated and compared. The difference between these VIV energy harvesters is the installation of the cylindrical bluff body at the tip of cantilever beam with different orientations (bottom, top, horizontal, and vertical). Experiments show that the synchronization regions of the bottom, top, and horizontal configurations are almost the same at low wind speeds (around 1.5 m/s). The vertical configuration has the highest wind speed for synchronization (around 3.5 m/s) with the largest harvested power, which is explained by its highest natural frequency and the smallest coupled damping. The results lead to the conclusion that to design efficient VIV energy harvesters, the bluff body should be aligned with the beam for low wind speeds (<2 m/s) and perpendicular to the beam at high wind speeds (>2 m/s)

  3. Intermediate-energy differential and integral cross sections for vibrational excitation in α-tetrahydrofurfuryl alcohol

    Energy Technology Data Exchange (ETDEWEB)

    Duque, H. V. [School of Chemical and Physical Sciences, Flinders University, GPO Box 2100, Adelaide, SA 5001 (Australia); Departamento de Física, Universidade Federal de Juiz de Fora, Juiz de Fora, MG (Brazil); Chiari, L.; Jones, D. B.; Pettifer, Z. [School of Chemical and Physical Sciences, Flinders University, GPO Box 2100, Adelaide, SA 5001 (Australia); Silva, G. B. da [School of Chemical and Physical Sciences, Flinders University, GPO Box 2100, Adelaide, SA 5001 (Australia); Universidade Federal de Mato Grosso, Barra do Garças, Mato Grosso (Brazil); Limão-Vieira, P. [Laboratório de Colisões Atómicas e Moleculares, CEFITEC, Departamento de Física, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica (Portugal); Blanco, F. [Departamento de Física Atómica, Molecular y Nuclear, Universidad Complutense de Madrid, Madrid E-28040 (Spain); García, G. [Instituto de Física Fundamental, CSIC, Madrid E-28006 (Spain); White, R. D. [School of Engineering and Physical Sciences, James Cook University, Townsville, 4810 Queensland (Australia); Lopes, M. C. A. [Departamento de Física, Universidade Federal de Juiz de Fora, Juiz de Fora, MG (Brazil); Brunger, M. J., E-mail: Michael.Brunger@flinders.edu.au [School of Chemical and Physical Sciences, Flinders University, GPO Box 2100, Adelaide, SA 5001 (Australia); Institute of Mathematical Sciences, University of Malaya, Kuala Lumpur (Malaysia)

    2014-06-07

    Differential and integral cross section measurements, for incident electron energies in the 20–50 eV range, are reported for excitation of several composite vibrational modes in α-tetrahydrofurfuryl alcohol (THFA). Optimisation and frequency calculations, using GAUSSIAN 09 at the B3LYP/aug-cc-pVDZ level, were also undertaken for the two most abundant conformers of THFA, with results being reported for their respective mode classifications and excitation energies. Those calculations assisted us in the experimental assignments of the composite features observed in our measured energy loss spectra. There are, to the best of our knowledge, no other experimental or theoretical data currently available in the literature against which we can compare the present results.

  4. Electrostatic hazards

    CERN Document Server

    Luttgens, Günter; Luttgens, Gnter; Luttgens, G Nter

    1997-01-01

    In the US, UK and Europe there is in excess of one notifiable dust or electrostatic explosion every day of the year. This clearly makes the hazards associated with the handling of materials subject to either cause or react to electrostatic discharge of vital importance to anyone associated with their handling or industrial bulk use. This book provides a comprehensive guide to the dangers of static electricity and how to avoid them. It will prove invaluable to safety managers and professionals, as well as all personnel involved in the activities concerned, in the chemical, agricultural, pharmaceutical and petrochemical process industries. The book makes extended use of case studies to illustrate the principles being expounded, thereby making it far more open, accessible and attractive to the practitioner in industry than the highly theoretical texts which are also available. The authors have many years' experience in the area behind them, including the professional teaching of the content provided here. Günte...

  5. Electrostatic accelerators

    OpenAIRE

    Hinterberger, F.

    2006-01-01

    The principle of electrostatic accelerators is presented. We consider Cockcroft– Walton, Van de Graaff and Tandem Van de Graaff accelerators. We resume high voltage generators such as cascade generators, Van de Graaff band generators, Pelletron generators, Laddertron generators and Dynamitron generators. The speci c features of accelerating tubes, ion optics and methods of voltage stabilization are described. We discuss the characteristic beam properties and the variety of possible beams. We ...

  6. Excitonic, vibrational, and van der Waals interactions in electron energy loss spectroscopy.

    Science.gov (United States)

    Mizoguchi, T; Miyata, T; Olovsson, W

    2017-09-01

    The pioneer, Ondrej L. Krivanek, and his collaborators have opened up many frontiers for the electron energy loss spectroscopy (EELS), and they have demonstrated new potentials of the EELS method for investigating materials. Here, inspired by those achievements, we show further potentials of EELS based on the results of theoretical calculations, that is excitonic and van der Waals (vdW) interactions, as well as vibrational information of materials. Concerning the excitonic interactions, we highlight the importance of the two-particle calculation to reproduce the low energy-loss near-edge structure (ELNES), the Na-L 2,3 edge of NaI and the Li-K edge of LiCl and LiFePO 4 . Furthermore, an unusually strong excitonic interaction at the O-K edge of perovskite oxides, SrTiO 3 and LaAlO 3 , is shown. The effect of the vdW interaction in the ELNES is also investigated, and we observe that the magnitude of the vdW effect is approximately 0.1eV in the case of the ELNES from a solid and liquid, whereas its effect is almost negligible in the case of the ELNES from the gaseous phase owing to the long inter-molecular distance. In addition to the "static" information, the influence of the "dynamic" behavior of atoms in materials to EELS is also investigated. We show that measurements of the infrared spectrum are possible by using a modern monochromator system. Furthermore, an estimation of the atomic vibration in core-loss ELNES is also presented. We show the acquisition of vibrational information using the ELNES of liquid methanol and acetic acid, solid Al 2 O 3 , and oxygen gas. Copyright © 2017 Elsevier B.V. All rights reserved.

  7. Vibrational energy transfer in selectively excited diatomic molecules. [Relaxation rates, self-relaxation, upper limits

    Energy Technology Data Exchange (ETDEWEB)

    Dasch, C.J.

    1978-09-01

    Single rovibrational states of HCl(v=2), HBr(v=2), DCl(v=2), and CO(v=2) were excited with a pulsed optical parametric oscillator (OPO). Total vibrational relaxation rates near - resonance quenchers were measured at 295/sup 0/K using time resolved infrared fluorescence. These rates are attributed primarily to V - V energy transfer, and they generally conform to a simple energy gap law. A small deviation was found for the CO(v) + DCl(v') relaxation rates. Upper limits for the self relaxation by V - R,T of HCl(v=2) and HBr(v=2) and for the two quantum exchange between HCl and HBr were determined. The HF dimer was detected at 295/sup 0/K and 30 torr HF pressure with an optoacoustic spectrometer using the OPO. Pulsed and chopped, resonant and non-resonant spectrophones are analyzed in detail. From experiments and first order perturbation theory, these V - V exchange rates appear to behave as a first order perturbation in the vibrational coordinates. The rotational dynamics are known to be complicated however, and the coupled rotational - vibrational dynamics were investigated theoreticaly in infinite order by the Dillon and Stephenson and the first Magnus approximations. Large ..delta..J transitions appear to be important, but these calculations differ by orders of magnitude on specific rovibrational transition rates. Integration of the time dependent semiclassical equations by a modified Gordon method and a rotationally distorted wave approximation are discussed as methods which would treat the rotational motion more accurately. 225 references.

  8. An analytical approach for predicting the energy capture and conversion by impulsively-excited bistable vibration energy harvesters

    Science.gov (United States)

    Harne, R. L.; Zhang, Chunlin; Li, Bing; Wang, K. W.

    2016-07-01

    Impulsive energies are abundant throughout the natural and built environments, for instance as stimulated by wind gusts, foot-steps, or vehicle-road interactions. In the interest of maximizing the sustainability of society's technological developments, one idea is to capture these high-amplitude and abrupt energies and convert them into usable electrical power such as for sensors which otherwise rely on less sustainable power supplies. In this spirit, the considerable sensitivity to impulse-type events previously uncovered for bistable oscillators has motivated recent experimental and numerical studies on the power generation performance of bistable vibration energy harvesters. To lead to an effective and efficient predictive tool and design guide, this research develops a new analytical approach to estimate the electroelastic response and power generation of a bistable energy harvester when excited by an impulse. Comparison with values determined by direct simulation of the governing equations shows that the analytically predicted net converted energies are very accurate for a wide range of impulse strengths. Extensive experimental investigations are undertaken to validate the analytical approach and it is seen that the predicted estimates of the impulsive energy conversion are in excellent agreement with the measurements, and the detailed structural dynamics are correctly reproduced. As a result, the analytical approach represents a significant leap forward in the understanding of how to effectively leverage bistable structures as energy harvesting devices and introduces new means to elucidate the transient and far-from-equilibrium dynamics of nonlinear systems more generally.

  9. Vibration Control of Structures using Vibro-Impact Nonlinear Energy Sinks

    Directory of Open Access Journals (Sweden)

    M. Ahmadi

    2016-09-01

    Full Text Available Using Vibro-Impact Nonlinear Energy Sinks (VI NESs is one of the novel strategies to control structural vibrations and mitigate their seismic response. In this system, a mass is tuned on the structure floor, so that it has a specific distance from an inelastic constraint connected to the floor mass. In case of structure stimulation, the displaced VI NES mass collides with the  inelastic constraint and upon impacts, energy is dissipated. In the present work, VI NES is studied when its parameters, including clearance and stiffness ratio, are simultaneously optimized. Harmony search as a recent meta-heuristic algorithm is efficiently specialized and utilized for the aforementioned continuous optimization problem. The optimized attached VI NES is thus shown to be capable of interacting with the primary structure over a wide range of frequencies. The resulting controlled response is then investigated, in a variety of low and medium rise steel moment frames, via nonlinear dynamic time history analyses. Capability of the VI NES to dissipate siesmic input energy of earthquakes and their capabilitiy in reducing response of srtructures effectively, through vibro-impacts between the energy sink’s mass and the floor mass, is discussed by extracting several performance indices and the corresponding Fourier spectra. Results of the numerical simulations done on some structural model examples reveal that the optimized VI NES has caused successive redistribution of energy from low-frequency high-amplitude vibration modes to high-frequency low-amplitude modes, bringing about the desired attenuation of the structural responses.

  10. A highly modular beamline electrostatic levitation facility, optimized for in situ high-energy x-ray scattering studies of equilibrium and supercooled liquids

    Energy Technology Data Exchange (ETDEWEB)

    Mauro, N.A.; Kelton, K.F. (WU)

    2011-10-27

    High-energy x-ray diffraction studies of metallic liquids provide valuable information about structural evolution on the atomic length scale, leading to insights into the origin of the nucleation barrier and the processes of supercooling and glass formation. The containerless processing of the beamline electrostatic levitation (BESL) facility allows coordinated thermophysical and structural studies of equilibrium and supercooled liquids to be made in a contamination-free, high-vacuum ({approx}10{sup -8} Torr) environment. To date, the incorporation of electrostatic levitation facilities into synchrotron beamlines has been difficult due to the large footprint of the apparatus and the difficulties associated with its transportation and implementation. Here, we describe a modular levitation facility that is optimized for diffraction studies of high-temperature liquids at high-energy synchrotron beamlines. The modular approach used in the apparatus design allows it to be easily transported and quickly setup. Unlike most previous electrostatic levitation facilities, BESL can be operated by a single user instead of a user team.

  11. Vibration mitigation in partially liquid-filled vessel using passive energy absorbers

    Science.gov (United States)

    Farid, M.; Levy, N.; Gendelman, O. V.

    2017-10-01

    We consider possible solutions for vibration mitigation in reduced-order model (ROM) of partially filled liquid tank under impulsive forcing. Such excitations may lead to strong hydraulic impacts applied to the tank inner walls. Finite stiffness of the tank walls is taken into account. In order to mitigate the dangerous internal stresses in the tank walls, we explore both linear (Tuned Mass Damper) and nonlinear (Nonlinear Energy Sink) passive vibration absorbers; mitigation performance in both cases is examined numerically. The liquid sloshing mass is modeled by equivalent mass-spring-dashpot system, which can both perform small-amplitude linear oscillations and hit the vessel walls. We use parameters of the equivalent mass-spring-dashpot system for a well-explored case of cylindrical tanks. The hydraulic impacts are modeled by high-power potential and dissipation functions. Critical location in the tank structure is determined and expression of the corresponding local mechanical stress is derived. We use finite element approach to assess the natural frequencies for specific system parameters. Numerical evaluation criteria are suggested to determine the energy absorption performance.

  12. Ab Initio Potential Energy Surfaces and the Calculation of Accurate Vibrational Frequencies

    Science.gov (United States)

    Lee, Timothy J.; Dateo, Christopher E.; Martin, Jan M. L.; Taylor, Peter R.; Langhoff, Stephen R. (Technical Monitor)

    1995-01-01

    Due to advances in quantum mechanical methods over the last few years, it is now possible to determine ab initio potential energy surfaces in which fundamental vibrational frequencies are accurate to within plus or minus 8 cm(exp -1) on average, and molecular bond distances are accurate to within plus or minus 0.001-0.003 Angstroms, depending on the nature of the bond. That is, the potential energy surfaces have not been scaled or empirically adjusted in any way, showing that theoretical methods have progressed to the point of being useful in analyzing spectra that are not from a tightly controlled laboratory environment, such as vibrational spectra from the interstellar medium. Some recent examples demonstrating this accuracy will be presented and discussed. These include the HNO, CH4, C2H4, and ClCN molecules. The HNO molecule is interesting due to the very large H-N anharmonicity, while ClCN has a very large Fermi resonance. The ab initio studies for the CH4 and C2H4 molecules present the first accurate full quartic force fields of any kind (i.e., whether theoretical or empirical) for a five-atom and six-atom system, respectively.

  13. Enhancement of wind energy harvesting by interaction between vortex-induced vibration and galloping

    Science.gov (United States)

    He, Xuefeng; Yang, Xiaokang; Jiang, Senlin

    2018-01-01

    Most wind energy harvesters (WEHs) that have been reported in the literature collect wind energy using only one type of wind-induced vibration, such as vortex-induced vibration (VIV), galloping, and flutter or wake galloping. In this letter, the interaction between VIV and galloping is used to improve the performance of WEHs. For a WEH constructed by attaching a bluff body with a rectangular cross-section to the free end of a piezoelectric cantilever, the measures to realize the interaction are theoretically discussed. Experiments verified the theoretical prediction that the WEHs with the same piezoelectric beam may demonstrate either separate or interactive VIV and galloping, depending on the geometries of the bluff bodies. For the WEHs with the interaction, the wind speed region of the VIV merges with that of the galloping to form a single region with high electrical outputs, which greatly increases the electrical outputs at low wind speeds. The interaction can be realized even when the predicted galloping critical speed is much higher than the predicted VIV critical speed. The proposed interaction is thus an effective approach to improve the scavenging efficiencies of WEHs operating at low wind speeds.

  14. PLASMA EFFECTS ON EXTRAGALACTIC ULTRAHIGH-ENERGY COSMIC-RAY HADRON BEAMS IN COSMIC VOIDS. II. KINETIC INSTABILITY OF PARALLEL ELECTROSTATIC WAVES

    Energy Technology Data Exchange (ETDEWEB)

    Krakau, S.; Schlickeiser, R., E-mail: steffen.krakau@rub.de, E-mail: rsch@tp4.rub.de [Institut für Theoretische Physik, Lehrstuhl IV: Weltraum- und Astrophysik, Ruhr-Universität Bochum, D-44780 Bochum (Germany)

    2016-02-20

    The linear instability of an ultrarelativistic hadron beam in the unmagnetized intergalactic medium (IGM) is investigated with respect to the excitation of parallel electrostatic and electromagnetic fluctuations. This analysis is important for the propagation of extragalactic ultrarelativistic cosmic rays from their distant sources to Earth. As opposed to the previous paper, we calculate the minimum instability growth time for Lorentz-distributed cosmic rays which traverse the hot IGM. The growth times are orders of magnitude higher than the cosmic-ray propagation time in the IGM. Since the backreaction of the generated plasma fluctuations (plateauing) lasts longer than the propagation time, the cosmic-ray hadron beam can propagate to the Earth without losing a significant amount of energy to electrostatic turbulence.

  15. Low-frequency and wideband vibration energy harvester with flexible frame and interdigital structure

    Energy Technology Data Exchange (ETDEWEB)

    Li, Pengwei, E-mail: lipengwei@tyut.edu.cn; Wang, Yanfen; Luo, Cuixian; Li, Gang; Hu, Jie; Zhang, Wendong [MicroNano System Research Center of College of Information Engineering and Key Lab of Advanced Transducers and Intelligent Control System of the Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, Shanxi (China); Liu, Ying [MicroNano System Research Center of College of Information Engineering and Key Lab of Advanced Transducers and Intelligent Control System of the Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, Shanxi (China); Baicheng Ordnance Test Center of China, Baicheng 137000, Jilin (China); Liu, Wei [Baicheng Ordnance Test Center of China, Baicheng 137000, Jilin (China)

    2015-04-15

    As an alternative to traditional cantilever beam structures and their evolutions, a flexible beam based, interdigital structure, vibration energy harvester has been presented and investigated. The proposed interdigital-shaped oscillator consists of a rectangular flexible frame and series of cantilever beams interdigitally bonded to it. In order to achieve low frequency and wide-bandwidth harvesting, Young’s modulus of materials, frame size and the amount of the cantilevers have been studied systematically. The measured frequency responses of the designed device (PDMS frame, quintuple piezoelectric cantilever beams) show a 460% increase in bandwidth below 80Hz. When excited at an acceleration of 1.0 g, the energy harvester achieves to a maximum open-circuit voltage of 65V, and the maximum output power 4.5 mW.

  16. Vibration energy harvester with sustainable power based on a single-crystal piezoelectric cantilever array.

    Science.gov (United States)

    Kim, Moonkeun; Lee, Sang-Kyun; Ham, Yong-Hyun; Yang, Yil Suk; Kwon, Jong-Kee; Kwon, Kwang-Ho

    2012-08-01

    We designed and fabricated a bimorph cantilever array for sustainable power with an integrated Cu proof mass to obtain additional power and current. We fabricated a cantilever system using single-crystal piezoelectric material and compared the calculations for single and arrayed cantilevers to those obtained experimentally. The vibration energy harvester had resonant frequencies of 60.4 and 63.2 Hz for short and open circuits, respectively. The damping ratio and quality factor of the cantilever device were 0.012 and 41.66, respectively. The resonant frequency at maximum average power was 60.8 Hz. The current and highest average power of the harvester array were found to be 0.728 mA and 1.61 mW, respectively. The sustainable maximum power was obtained after slightly shifting the short-circuit frequency. In order to improve the current and power using an array of cantilevers, we also performed energy conversion experiments.

  17. Low-frequency and wideband vibration energy harvester with flexible frame and interdigital structure

    Directory of Open Access Journals (Sweden)

    Pengwei Li

    2015-04-01

    Full Text Available As an alternative to traditional cantilever beam structures and their evolutions, a flexible beam based, interdigital structure, vibration energy harvester has been presented and investigated. The proposed interdigital-shaped oscillator consists of a rectangular flexible frame and series of cantilever beams interdigitally bonded to it. In order to achieve low frequency and wide-bandwidth harvesting, Young’s modulus of materials, frame size and the amount of the cantilevers have been studied systematically. The measured frequency responses of the designed device (PDMS frame, quintuple piezoelectric cantilever beams show a 460% increase in bandwidth below 80Hz. When excited at an acceleration of 1.0 g, the energy harvester achieves to a maximum open-circuit voltage of 65V, and the maximum output power 4.5 mW.

  18. Development of a Vibration-Based Electromagnetic Energy Harvester by a Conductive Direct-Write Process

    Directory of Open Access Journals (Sweden)

    Yao-Yun Feng

    2017-03-01

    Full Text Available A conductive direct-write process of multilayered coils for micro electromagnetic generators is proposed. This novel approach of using silver ink to form the conductive structures largely reduces the fabrication complexity, and it provides a faster alternative to the conventional semiconductor methods. Multi-layered coils with insulation were accurately layered on a micromachined cantilevered diaphragm by a dispenser. Coils several layers thick could be used to increase the power output and double coils were separated by a layer of insulation. Six prototypes, all capable of efficient conversion of vibrational energy into electrical energy, were fabricated. The experimental results, which include measurements of the electromotive force and power output, are presented. Prototypes with two coils and thicker conducting layers had less resistance and the power output was much more than that of a single-coil unit. This generator can produce 82 nW of power at a resonance frequency of 275 Hz under 5 g excitation.

  19. Symmetry, vibrational energy redistribution and vibronic coupling: The internal conversion processes of cycloketones

    DEFF Research Database (Denmark)

    Kuhlman, Thomas Scheby; Sauer, Stephan P.A.; Sølling, Theis I.

    2012-01-01

    In this paper, we discern two basic mechanisms of internal conversion processes; one direct, where immediate activation of coupling modes leads to fast population transfer and one indirect, where internal vibrational energy redistribution leads to equidistribution of energy, i.e., ergodicity......, and slower population transfer follows. Using model vibronic coupling Hamiltonians parameterized on the basis of coupled-cluster calculations, we investigate the nature of the Rydberg to valence excited-state internal conversion in two cycloketones, cyclobutanone and cyclopentanone. The two basic mechanisms...... can amply explain the significantly different time scales for this process in the two molecules, a difference which has also been reported in recent experimental findings [T. S. Kuhlman, T. I. Sølling, and K. B. Møller, ChemPhysChem. 13, 820 (2012)]...

  20. Kinetic study of low-temperature CO2 plasmas under non-equilibrium conditions. I. Relaxation of vibrational energy

    Science.gov (United States)

    Silva, T.; Grofulović, M.; Klarenaar, B. L. M.; Morillo-Candas, A. S.; Guaitella, O.; Engeln, R.; Pintassilgo, C. D.; Guerra, V.

    2018-01-01

    A kinetic model describing the time evolution of ∼70 individual CO2(X1Σ+) vibrational levels during the afterglow of a pulsed DC glow discharge is developed in order to contribute to the understanding of vibrational energy transfer in CO2 plasmas. The results of the simulations are compared against in situ Fourier transform infrared spectroscopy data obtained in a pulsed DC glow discharge and its afterglow at pressures of a few Torr and discharge currents of around 50 mA. The very good agreement between the model predictions and the experimental results validates the kinetic scheme considered here and the corresponding vibration–vibration and vibration–translation rate coefficients. In this sense, it establishes a reaction mechanism for the vibrational kinetics of these CO2 energy levels and offers a firm basis to understand the vibrational relaxation in CO2 plasmas. It is shown that first-order perturbation theories, namely, the Schwartz–Slawsky–Herzfeld and Sharma–Brau methods, provide a good description of CO2 vibrations under low excitation regimes.

  1. Enhancement of Energy Harvesting Performance by a Coupled Bluff Splitter Body and PVEH Plate through Vortex Induced Vibration near Resonance

    Directory of Open Access Journals (Sweden)

    Wei Ken Chin

    2017-09-01

    Full Text Available Inspired by vortex induced vibration energy harvesting development as a new source of renewable energy, a T-shaped design vibration energy harvester is introduced with the aim of enhancing its performance through vortex induced vibration at near resonance conditions. The T-shaped structural model designed consists of a fixed boundary aluminum bluff splitter body coupled with a cantilever piezoelectric vibration energy harvesters (PVEH plate model which is a piezoelectric bimorph plate made of a brass plate sandwiched between 2 lead zirconate titanate (PZT plates. A 3-dimensional Fluid-Structure Interaction simulation analysis is carried out with Reynolds Stress Turbulence Model under wind speed of 7, 10, 12, 14, 16, 18, 19, 20, 22.5, and 25 m/s. The results showed that with 19 m/s wind speed, the model generates 75.758 Hz of vortex frequency near to the structural model’s natural frequency of 76.9 Hz. Resonance lock-in therefore occurred, generating a maximum displacement amplitude of 2.09 mm or a 49.76% increment relatively in vibrational amplitude. Under the effect of resonance at the PVEH plate’s fundamental natural frequency, it is able to generate the largest normalized power of 13.44 mW/cm3g2.

  2. Impact-based piezoelectric energy harvester for multidimensional, low-level, broadband, and low-frequency vibrations

    Science.gov (United States)

    Zhang, Hongjiang; Jiang, Senlin; He, Xuefeng

    2017-05-01

    This letter proposes an impact-based piezoelectric energy harvester that uses a rolling bead contained in a bracket that is supported by a spring. Under either translational or rotational base excitation, the bead moves within the bracket and collides with piezoelectric cantilevers that are located around the bracket; these collisions cause the piezoelectric beams to vibrate and thus produce electrical outputs. The low rolling friction and the motion amplification effect of the spring make the resulting device suitable for collection of low-level vibration energy. Experiments show that the proposed harvester is promising for use in scavenging of energy from the multidimensional, low-level, broadband, and low-frequency vibrations that occur in natural environments.

  3. Energy calibration issues in nuclear resonant vibrational spectroscopy: observing small spectral shifts and making fast calibrations.

    Science.gov (United States)

    Wang, Hongxin; Yoda, Yoshitaka; Dong, Weibing; Huang, Songping D

    2013-09-01

    The conventional energy calibration for nuclear resonant vibrational spectroscopy (NRVS) is usually long. Meanwhile, taking NRVS samples out of the cryostat increases the chance of sample damage, which makes it impossible to carry out an energy calibration during one NRVS measurement. In this study, by manipulating the 14.4 keV beam through the main measurement chamber without moving out the NRVS sample, two alternative calibration procedures have been proposed and established: (i) an in situ calibration procedure, which measures the main NRVS sample at stage A and the calibration sample at stage B simultaneously, and calibrates the energies for observing extremely small spectral shifts; for example, the 0.3 meV energy shift between the 100%-(57)Fe-enriched [Fe4S4Cl4](=) and 10%-(57)Fe and 90%-(54)Fe labeled [Fe4S4Cl4](=) has been well resolved; (ii) a quick-switching energy calibration procedure, which reduces each calibration time from 3-4 h to about 30 min. Although the quick-switching calibration is not in situ, it is suitable for normal NRVS measurements.

  4. Fluorine Gauche Effect Explained by Electrostatic Polarization Instead of Hyperconjugation: An Interacting Quantum Atoms (IQA) and Relative Energy Gradient (REG) Study.

    Science.gov (United States)

    Thacker, Joseph C R; Popelier, Paul L A

    2018-02-08

    We present an interacting quantum atoms (IQA) study of the gauche effect by comparing 1,2-difluoroethane, 1,2-dichloroethane, and three conformers of 1,2,3,4,5,6-hexafluorocyclohexane. In the 1,2-difluoroethane, the gauche effect is observed in that the gauche conformation is more stable than the anti, whereas in 1,2-dichloroethane the opposite is true. The analysis performed here is exhaustive and unbiased thanks to using the recently introduced relative energy gradient (REG) method [ Thacker , J. C. R. ; Popelier , P. L. A. Theor. Chem. Acc . 2017 , 136 , 86 ], as implemented in the in-house program ANANKE. We challenge the common explanation that hyperconjugation is responsible for the gauche stability in 1,2-difluoroethane and instead present electrostatics as the cause of gauche stability. Our explanation of the gauche effect is also is seen in other molecules displaying local gauche conformations, such as the recently synthesized "all-cis" hexafluorocyclohexane and its conformers where all the fluorine atoms are in the equatorial positions. Using our extension of the traditional IQA methodology that allows for the partitioning of electrostatic terms into polarization and charge transfer, we propose that the cause of gauche stability is 1,3 C···F electrostatic polarization interactions. In other words, if a number of fluorine atoms are aligned, then the stability due to polarization of nearby carbon atoms is increased.

  5. An Improved Lumped Parameter Model for a Piezoelectric Energy Harvester in Transverse Vibration

    Directory of Open Access Journals (Sweden)

    Guang-qing Wang

    2014-01-01

    Full Text Available An improved lumped parameter model (ILPM is proposed which predicts the output characteristics of a piezoelectric vibration energy harvester (PVEH. A correction factor is derived for improving the precisions of lumped parameter models for transverse vibration, by considering the dynamic mode shape and the strain distribution of the PVEH. For a tip mass, variations of the correction factor with PVEH length are presented with curve fitting from numerical solutions. The improved governing motion equations and exact analytical solution of the PVEH excited by persistent base motions are developed. Steady-state electrical and mechanical response expressions are derived for arbitrary frequency excitations. Effects of the structural parameters on the electromechanical outputs of the PVEH and important characteristics of the PVEH, such as short-circuit and open-circuit behaviors, are analyzed numerically in detail. Accuracy of the output performances of the ILPM is identified from the available lumped parameter models and the coupled distributed parameter model. Good agreement is found between the analytical results of the ILPM and the coupled distributed parameter model. The results demonstrate the feasibility of the ILPM as a simple and effective means for enhancing the predictions of the PVEH.

  6. High-efficiency MOSFET bridge rectifier for AlN MEMS cantilever vibration energy harvester

    Science.gov (United States)

    Takei, Ryohei; Okada, Hironao; Noda, Daiji; Ohta, Ryo; Takeshita, Toshihiro; Itoh, Toshihiro; Kobayashi, Takeishi

    2017-04-01

    We developed a high-efficiency MOSFET bridge rectifier for use in an aluminum nitride (AlN) piezoelectric MEMS cantilever vibration energy harvester (VEH). The bridge rectifier consists of four MOSFETs with a circuit configuration similar to that of a typical diode bridge rectifier. The output voltage of the full-wave rectification via the MOSFET bridge was simulated with an equivalent circuit model of the AlN VEH, which is extracted from an experimental result. The channel width of the MOSFET was designed to be adopted for use with a high-voltage and low-current AlN VEH. The designed rectifier was fabricated using the 0.18 µm high voltage technology of a commercially available CMOS foundry. The AlN VEH with our bridge rectifier generated a DC power of 0.514 µW at 2.49 V under an applied vibration with an acceleration amplitude of 0.5 m/s2 at a frequency of 46.6 Hz. The DC power is 1.4 times higher than that generated by the same AlN VEH with a MOSFET bridge consisting of commercially available discrete MOSFETs.

  7. An experimental study of vibration based energy harvesting in dynamically tailored structures with embedded acoustic black holes

    Science.gov (United States)

    Zhao, Liuxian; Conlon, Stephen C.; Semperlotti, Fabio

    2015-06-01

    In this paper, we present an experimental investigation on the energy harvesting performance of dynamically tailored structures based on the concept of embedded acoustic black holes (ABHs). Embedded ABHs allow tailoring the wave propagation characteristics of the host structure creating structural areas with extreme levels of energy density. Experiments are conducted on a tapered plate-like aluminum structure with multiple embedded ABH features. The dynamic response of the structure is tested via laser vibrometry in order to confirm the vibration localization and the passive wavelength sweep characteristic of ABH embedded tapers. Vibrational energy is extracted from the host structure and converted into electrical energy by using ceramic piezoelectric discs bonded on the ABHs and shunted on an external electric circuit. The energy harvesting performance is investigated both under steady state and transient excitation. The experimental results confirm that the dynamic tailoring produces a drastic increase in the harvested energy independently from the nature of the excitation input.

  8. Relaxation dynamics in quantum dissipative systems: The microscopic effect of intramolecular vibrational energy redistribution

    Energy Technology Data Exchange (ETDEWEB)

    Uranga-Piña, L. [Facultad de Física, Universidad de la Habana, San Lázaro y L, Vedado, 10400 Havana (Cuba); Institute for Chemistry and Biochemistry, Freie Universität Berlin, Takustr. 3, D-14195 Berlin (Germany); Tremblay, J. C., E-mail: jean.c.tremblay@gmail.com [Institute for Chemistry and Biochemistry, Freie Universität Berlin, Takustr. 3, D-14195 Berlin (Germany)

    2014-08-21

    We investigate the effect of inter-mode coupling on the vibrational relaxation dynamics of molecules in weak dissipative environments. The simulations are performed within the reduced density matrix formalism in the Markovian regime, assuming a Lindblad form for the system-bath interaction. The prototypical two-dimensional model system representing two CO molecules approaching a Cu(100) surface is adapted from an ab initio potential, while the diatom-diatom vibrational coupling strength is systematically varied. In the weak system-bath coupling limit and at low temperatures, only first order non-adiabatic uni-modal coupling terms contribute to surface-mediated vibrational relaxation. Since dissipative dynamics is non-unitary, the choice of representation will affect the evolution of the reduced density matrix. Two alternative representations for computing the relaxation rates and the associated operators are thus compared: the fully coupled spectral basis, and a factorizable ansatz. The former is well-established and serves as a benchmark for the solution of Liouville-von Neumann equation. In the latter, a contracted grid basis of potential-optimized discrete variable representation is tailored to incorporate most of the inter-mode coupling, while the Lindblad operators are represented as tensor products of one-dimensional operators, for consistency. This procedure results in a marked reduction of the grid size and in a much more advantageous scaling of the computational cost with respect to the increase of the dimensionality of the system. The factorizable method is found to provide an accurate description of the dissipative quantum dynamics of the model system, specifically of the time evolution of the state populations and of the probability density distribution of the molecular wave packet. The influence of intra-molecular vibrational energy redistribution appears to be properly taken into account by the new model on the whole range of coupling strengths. It

  9. A Miniature Magnetic-Force-Based Three-Axis AC Magnetic Sensor with Piezoelectric/Vibrational Energy-Harvesting Functions.

    Science.gov (United States)

    Hung, Chiao-Fang; Yeh, Po-Chen; Chung, Tien-Kan

    2017-02-08

    In this paper, we demonstrate a miniature magnetic-force-based, three-axis, AC magnetic sensor with piezoelectric/vibrational energy-harvesting functions. For magnetic sensing, the sensor employs a magnetic-mechanical-piezoelectric configuration (which uses magnetic force and torque, a compact, single, mechanical mechanism, and the piezoelectric effect) to convert x-axis and y-axis in-plane and z-axis magnetic fields into piezoelectric voltage outputs. Under the x-axis magnetic field (sine-wave, 100 Hz, 0.2-3.2 gauss) and the z-axis magnetic field (sine-wave, 142 Hz, 0.2-3.2 gauss), the voltage output with the sensitivity of the sensor are 1.13-26.15 mV with 8.79 mV/gauss and 1.31-8.92 mV with 2.63 mV/gauss, respectively. In addition, through this configuration, the sensor can harness ambient vibrational energy, i.e., possessing piezoelectric/vibrational energy-harvesting functions. Under x-axis vibration (sine-wave, 100 Hz, 3.5 g) and z-axis vibration (sine-wave, 142 Hz, 3.8 g), the root-mean-square voltage output with power output of the sensor is 439 mV with 0.333 μW and 138 mV with 0.051 μW, respectively. These results show that the sensor, using this configuration, successfully achieves three-axis magnetic field sensing and three-axis vibration energy-harvesting. Due to these features, the three-axis AC magnetic sensor could be an important design reference in order to develop future three-axis AC magnetic sensors, which possess energy-harvesting functions, for practical industrial applications, such as intelligent vehicle/traffic monitoring, processes monitoring, security systems, and so on.

  10. Application of Vortex Induced Vibration Energy Generation Technologies to the Offshore Oil and Gas Platform: The Preliminary Study

    OpenAIRE

    M. A. Zahari; S. S. Dol

    2014-01-01

    The global demand for continuous and eco-friendly renewable energy as alternative to fossils fuels is large and ever growing in nowadays. This paper will focus on capability of Vortex Induced Vibration (VIV) phenomenon in generating alternative energy for offshore platform application. In order to maximize the potential of energy generation, the effects of lock in phenomenon and different geometries of cylinder were studied in this project. VIV is the motion induced on bl...

  11. Hybrid nanogenerators for low frequency vibration energy harvesting and self-powered wireless locating

    Science.gov (United States)

    Yuan, Ying; Zhang, Hulin; Wang, Jie; Xie, Yuhang; Khan, Saeed Ahmed; Jin, Long; Yan, Zhuocheng; Huang, Long; Pan, Taisong; Yang, Weiqing; Lin, Yuan

    2018-01-01

    Hybrid energy harvesters based on different physical effects is fascinating, but a rational design for multiple energy harvesting is challenging. In this work, a spring-magnet oscillator-based triboelectric-electromagnetic generator (EMG) with a solar cell cap is proposed. A power was produced by a triboelectric nanogenerator (TENG) and an EMG independently or simultaneously by using a shared spring-magnet oscillator. The oscillator configuration enables versatile energy harvesting with the excellent size scalability and self-packaged structure which can perform well at low frequency ranging from 3.5 to 5 Hz. The solar cell cap mounted above the oscillator can harvest solar energy. Under vibrations at the frequency of 4 Hz, the TENG and the EMG produced maximum output power of 5.46 nW cm‑3 and 378.79 μW cm‑3, respectively. The generated electricity by the hybrid nanogenerator can be stored in a capacitor or Li-ion battery, which is capable of powering a wireless locator for real-time locating data reporting to a personal cell phone. The light-weight and handy hybrid nanogenerator can directly light a caution light or play as a portable flashlight by shaking hands at night.

  12. Spin Dynamics and Low Energy Vibrations: Insights from Vanadyl-Based Potential Molecular Qubits.

    Science.gov (United States)

    Atzori, Matteo; Tesi, Lorenzo; Benci, Stefano; Lunghi, Alessandro; Righini, Roberto; Taschin, Andrea; Torre, Renato; Sorace, Lorenzo; Sessoli, Roberta

    2017-03-29

    Here we report the investigation of the magnetization dynamics of a vanadyl complex with diethyldithiocarbamate (Et2dtc(-)) ligands, namely [VO(Et2dtc)2] (1), in both solid-state and frozen solution. This showed an anomalous and unprecedentedly observed field dependence of the relaxation time, which was modeled with three contributions to the relaxation mechanism. The temperature dependence of the weight of the two processes dominating at low fields was found to well correlate with the low energy vibrations as determined by THz spectroscopy. This detailed experimental comparative study represents a fundamental step to understand the spin dynamics of potential molecular quantum bits, and enriches the guidelines to design molecule-based systems with enhanced quantum coherence.

  13. Optimal linear generator with Halbach array for harvesting of vibration energy during human walking

    Directory of Open Access Journals (Sweden)

    Joonsoo Jun

    2016-05-01

    Full Text Available In IT business, the capacity of the battery in smartphone was drastically improved to digest various functions such as communication, Internet, e-banking, and entertainment. Although the capacity of the battery is improved, it still needs to be upgraded due to customer’s demands. In this article, we optimize the design of the linear generator with the Halbach array to improve the efficiency of harvesting vibration energy during human walking for the battery capacitance. We propose the optimal design of the tubular permanent magnet with the linear generator that uses a Halbach array. The approximate model is established using generic algorithm. Furthermore, we performed electromagnetic finite element analysis to predict the induced voltage.

  14. Low-frequency wideband vibration energy harvesting by using frequency up-conversion and quin-stable nonlinearity

    Science.gov (United States)

    Wang, Chen; Zhang, Qichang; Wang, Wei

    2017-07-01

    This work presents models and experiments of an impact-driven and frequency up-converted wideband piezoelectric-based vibration energy harvester with a quintuple-well potential induced by the combination effect of magnetic nonlinearity and mechanical piecewise-linearity. Analysis shows that the interwell motions during coupled vibration period enable to increase electrical power output in comparison to conventional frequency up-conversion technology. Besides, the quintuple-well potential with shallower potential wells could extend the harvester's operating bandwidth to lower frequencies. Experiments demonstrate our proposed approach can dramatically boost the measured power of the energy harvester as much as 35 times while its lower cut-off frequency is two times lower than that of a conventional counterpart. These results reveal our proposed approach shows promise for powering portable wireless smart devices from low-intensity, low-frequency vibration sources.

  15. The crystal structure, electrostatic properties, and thermal vibrations of some hydrated spermine compounds using neutron and x-ray diffraction data

    Science.gov (United States)

    Cohen, Aina Elizabeth

    Spermine phosphate hexahydrate crystallizes in space group P21/a with unit cell dimensions a = 7.931(1) A, b = 23.158(5) A, c = 6.856(2) A, and b = 113.44(2)° at 125 K with unit cell contents ([C10H 30N4]2+4 4[HPO4] -2·12H2O). The packing of spermines and monohydrogen phosphates in this crystal structure has features which may be relevant to the binding of spermine to DNA. Another important structural feature is the presence of channels containing water that is H-bonded as in ice-Ih with disordered protons. The channels occur between sheets of spermine long chains and are also bordered by H-bonded monohydrogen phosphate chains. Using neutron diffraction data, the H-bonding scheme of these water chains proposed on the basis of an earlier X-ray study is now confirmed. Nuclear positions, anisotropic m.s. displacements, an overall scale factor, and two extinction parameters ( r and g) were refined using full-matrix least-squares giving values of R(Fo2) = 0.09, Rw(Fo 2) = 0.11 and S = 1.02. Thermal vibrational analysis revealed that the backbone of the spermine cation can be described as a single rigid segment with a substantial libration of 27 deg2 around the spermine molecular long axis. The charge density distribution in the crystal structure of spermine phosphate hexahydrate ([C10H30N4] +4 2[HPO4]-2·6H2O) has been determined from X-ray diffraction data MoKa at 125 K using 13,984 reflections with sin/l≤1. 51 A-1. Least-squares structure refinement assuming Stewart's rigid pseudoatom model (variables included electron populations for multipole terms extending to octapoles for C, N, O, and P and up to dipoles for H) gave R(F2) = 0.042, Rw(F2) = 0.071 and S = 1.06. The electron density and its Laplacian have been determined at the (3, -1) or bond-critical points. The crystal structure of spermine dihydrate (C10H26N 4·2H2O), or possibly sperminium dihydroxide, has been determined for the non-hydrogen atoms. Spermine dihydrate crystallizes in space group P1¯ with

  16. Optimal design of a vibration-based energy harvester using magnetostrictive material (MsM)

    Science.gov (United States)

    Hu, J.; Xu, F.; Huang, A. Q.; Yuan, F. G.

    2011-01-01

    In this study, an optimal vibration-based energy harvesting system using magnetostrictive material (MsM) was designed and tested to enable the powering of a wireless sensor. In particular, the conversion efficiency, converting from magnetic to electric energy, is approximately modeled from the magnetic field induced by the beam vibration. A number of factors that affect the output power such as the number of MsM layers, coil design and load matching are analyzed and explored in the design optimization. From the measurements, the open-circuit voltage can reach 1.5 V when the MsM cantilever beam operates at the second natural frequency 324 Hz. The AC output power is 970 µW, giving a power density of 279 µW cm - 3. The attempt to use electrical reactive components (either inductors or capacitors) to resonate the system at any frequency has also been analyzed and tested experimentally. The results showed that this approach is not feasible to optimize the power. Since the MsM device has low output voltage characteristics, a full-wave quadrupler has been designed to boost the rectified output voltage. To deliver the maximum output power to the load, a complex conjugate impedance matching between the load and the MsM device is implemented using a discontinuous conduction mode (DCM) buck-boost converter. The DC output power after the voltage quadrupler reaches 705 µW and the corresponding power density is 202 µW cm - 3. The output power delivered to a lithium rechargeable battery is around 630 µW, independent of the load resistance.

  17. Vibrational Surface Electron-Energy-Loss Spectroscopy Probes Confined Surface-Phonon Modes

    Directory of Open Access Journals (Sweden)

    Hugo Lourenço-Martins

    2017-12-01

    Full Text Available Recently, two reports [Krivanek et al. Nature (London 514, 209 (2014NATUAS0028-083610.1038/nature13870, Lagos et al. Nature (London 543, 529 (2017NATUAS0028-083610.1038/nature21699] have demonstrated the amazing possibility to probe vibrational excitations from nanoparticles with a spatial resolution much smaller than the corresponding free-space phonon wavelength using electron-energy-loss spectroscopy (EELS. While Lagos et al. evidenced a strong spatial and spectral modulation of the EELS signal over a nanoparticle, Krivanek et al. did not. Here, we show that discrepancies among different EELS experiments as well as their relation to optical near- and far-field optical experiments [Dai et al. Science 343, 1125 (2014SCIEAS0036-807510.1126/science.1246833] can be understood by introducing the concept of confined bright and dark surface phonon modes, whose density of states is probed by EELS. Such a concise formalism is the vibrational counterpart of the broadly used formalism for localized surface plasmons [Ouyang and Isaacson Philos. Mag. B 60, 481 (1989PMABDJ1364-281210.1080/13642818908205921, García de Abajo and Aizpurua Phys. Rev. B 56, 15873 (1997PRBMDO0163-182910.1103/PhysRevB.56.15873, García de Abajo and Kociak Phys. Rev. Lett. 100, 106804 (2008PRLTAO0031-900710.1103/PhysRevLett.100.106804, Boudarham and Kociak Phys. Rev. B 85, 245447 (2012PRBMDO1098-012110.1103/PhysRevB.85.245447]; it makes it straightforward to predict or interpret phenomena already known for localized surface plasmons such as environment-related energy shifts or the possibility of 3D mapping of the related surface charge densities [Collins et al. ACS Photonics 2, 1628 (2015APCHD52330-402210.1021/acsphotonics.5b00421].

  18. A batch-fabricated electret-biased wideband MEMS vibration energy harvester with frequency-up conversion behavior powering a UHF wireless sensor node

    Science.gov (United States)

    Lu, Y.; O'Riordan, E.; Cottone, F.; Boisseau, S.; Galayko, D.; Blokhina, E.; Marty, F.; Basset, P.

    2016-12-01

    This paper reports a batch-fabricated, low-frequency and wideband MEMS electrostatic vibration energy harvester (e-VEH), which implements corona-charged vertical electrets and nonlinear elastic stoppers. A numeric model is used to perform parametric study, where we observe a wideband bi-modality resulting from nonlinearity. The nonlinear stoppers improve the bandwidth and induce a frequency-up feature at low frequencies. When the e-VEH works with a bias of 45 V, the power reaches a maximum value of 6.6 μW at 428 Hz and 2.0 g rms, and is above 1 μW at 50 Hz. When the frequency drops below 60 Hz, a ‘frequency-up’ conversion behavior is observed with peaks of power at 34 Hz and 52 Hz. The  -3 dB bandwidth is more than 60% of its central frequency, both including and excluding the hysteresis introduced by the nonlinear stoppers. We also perform experiments with wideband Gaussian noise. The device is eventually tested with an RF data transmission setup, where a communication node with an internal temperature sensor is powered. Every 2 min, a data transmission at 868 MHz is performed by the sensor node supplied by the e-VEH, and received at a distance of up to 15 m.

  19. Investigation of the performances of PZT vs rare earth (BaLaTiO3 vibration based energy harvester

    Directory of Open Access Journals (Sweden)

    Pak Nehemiah

    2017-01-01

    Full Text Available This study proposes the investigation of two piezoelectric material namely PZT and Lanthanum Doped Barium Titanate (BaLaTiO3 performance as a vibration based energy harvester. The piezoelectric material when applied mechanical stress or strain produces electricity through the piezoelectric effect. The vibration energy would exude mechanical energy and thus apply mechanical force on the energy harvester. The energy harvester would be designed and simulated using the piezoelectric material individually. The studied outputs are divided to frequency response, the load dependence, and the acceleration dependence whereby measurement are observed and taken at maximum power output. The simulation is done using the cantilevers design which employs d31 type of constants. Three different simulations to study the dependence of output power on the resonant frequency response, load and acceleration have found that material that exhibit highest power generation was the BaLaTiO3.

  20. Two-dimensional concentrated-stress low-frequency piezoelectric vibration energy harvesters

    Science.gov (United States)

    Sharpes, Nathan; Abdelkefi, Abdessattar; Priya, Shashank

    2015-08-01

    Vibration-based energy harvesters using piezoelectric materials have long made use of the cantilever beam structure. Surmounting the deficiencies in one-dimensional cantilever-based energy harvesters has been a major focus in the literature. In this work, we demonstrate a strategy of using two-dimensional beam shapes to harvest energy from low frequency excitations. A characteristic Zigzag-shaped beam is created to compare against the two proposed two-dimensional beam shapes, all of which occupy a 25.4 × 25.4 mm2 area. In addition to maintaining the low-resonance bending frequency, the proposed beam shapes are designed with the goal of realizing a concentrated stress structure, whereby stress in the beam is concentrated in a single area where a piezoelectric layer may be placed, rather than being distributed throughout the beam. It is shown analytically, numerically, and experimentally that one of the proposed harvesters is able to provide significant increase in power production, when the base acceleration is set equal to 0.1 g, with only a minimal change in the resonant frequency compared to the current state-of-the-art Zigzag shape. This is accomplished by eliminating torsional effects, producing a more pure bending motion that is necessary for high electromechanical coupling. In addition, the proposed harvesters have a large effective beam tip whereby large tip mass may be placed while retaining a low-profile, resulting in a low volume harvester and subsequently large power density.

  1. Improved vibration-based energy harvesting by annular mass configuration of piezoelectric circular diaphragms

    Science.gov (United States)

    Yang, Yangyiwei; Li, Yuanbo; Guo, Yaqian; Xu, Bai-Xiang; Yang, Tongqing

    2018-03-01

    Vibration-based energy harvesting using piezoelectric circular diaphragms (PCDs) with a structure featuring the central mass (C-mass) configuration has drawn much attention in recent decades. In this work, we propose a new configuration with the annular proof mass (A-mass) where an improved energy harvesting is promised. The numerical analysis was employed using the circuit-coupled piezoelectric simulation, and the experimental validation was implemented using PCDs with the even-width annular electrodes. Samples with the different mass configurations as well as structural parameters ϖ 1 and ϖ 2, which indicate the ratio between the inner boundary radius and piezoelectric ceramic radius as well as the ratio between outer boundary radius and the substrate radius, respectively, were prepared and tested. The impedance-matched output power of full-electrode PCDs was also collected, and some distinct improvement was measured on samples with the certain structural parameters. The power increases from 14.1 mW to 19.0 mW after changing the configuration from C-mass to A-mass with the same parameters (ϖ 1, ϖ 2) = (0.16, 0.9), showing the considerable improvement in energy harvesting by using A-mass configuration.

  2. Rectifying the output of vibrational piezoelectric energy harvester using quantum dots.

    Science.gov (United States)

    Li, Lijie

    2017-03-20

    Piezoelectric energy harvester scavenges mechanical vibrations and generates electricity. Researchers have strived to optimize the electromechanical structures and to design necessary external power management circuits, aiming to deliver high power and rectified outputs ready for serving as batteries. Complex deformation of the mechanical structure results in charges with opposite polarities appearing on same surface, leading to current loss in the attached metal electrode. External power management circuits such as rectifiers comprise diodes that consume power and have undesirable forward bias. To address the above issues, we devise a novel integrated piezoelectric energy harvesting device that is structured by stacking a layer of quantum dots (QDs) and a layer of piezoelectric material. We find that the QD can rectify electrical charges generated from the piezoelectric material because of its adaptable conductance to the electrochemical potentials of both sides of the QDs layer, so that electrical current causing energy loss on the same surface of the piezoelectric material can be minimized. The QDs layer has the potential to replace external rectification circuits providing a much more compact and less power-consumption solution.

  3. Segmentation of a Vibro-Shock Cantilever-Type Piezoelectric Energy Harvester Operating in Higher Transverse Vibration Modes

    Directory of Open Access Journals (Sweden)

    Darius Zizys

    2015-12-01

    Full Text Available The piezoelectric transduction mechanism is a common vibration-to-electric energy harvesting approach. Piezoelectric energy harvesters are typically mounted on a vibrating host structure, whereby alternating voltage output is generated by a dynamic strain field. A design target in this case is to match the natural frequency of the harvester to the ambient excitation frequency for the device to operate in resonance mode, thus significantly increasing vibration amplitudes and, as a result, energy output. Other fundamental vibration modes have strain nodes, where the dynamic strain field changes sign in the direction of the cantilever length. The paper reports on a dimensionless numerical transient analysis of a cantilever of a constant cross-section and an optimally-shaped cantilever with the objective to accurately predict the position of a strain node. Total effective strain produced by both cantilevers segmented at the strain node is calculated via transient analysis and compared to the strain output produced by the cantilevers segmented at strain nodes obtained from modal analysis, demonstrating a 7% increase in energy output. Theoretical results were experimentally verified by using open-circuit voltage values measured for the cantilevers segmented at optimal and suboptimal segmentation lines.

  4. Segmentation of a Vibro-Shock Cantilever-Type Piezoelectric Energy Harvester Operating in Higher Transverse Vibration Modes.

    Science.gov (United States)

    Zizys, Darius; Gaidys, Rimvydas; Dauksevicius, Rolanas; Ostasevicius, Vytautas; Daniulaitis, Vytautas

    2015-12-23

    The piezoelectric transduction mechanism is a common vibration-to-electric energy harvesting approach. Piezoelectric energy harvesters are typically mounted on a vibrating host structure, whereby alternating voltage output is generated by a dynamic strain field. A design target in this case is to match the natural frequency of the harvester to the ambient excitation frequency for the device to operate in resonance mode, thus significantly increasing vibration amplitudes and, as a result, energy output. Other fundamental vibration modes have strain nodes, where the dynamic strain field changes sign in the direction of the cantilever length. The paper reports on a dimensionless numerical transient analysis of a cantilever of a constant cross-section and an optimally-shaped cantilever with the objective to accurately predict the position of a strain node. Total effective strain produced by both cantilevers segmented at the strain node is calculated via transient analysis and compared to the strain output produced by the cantilevers segmented at strain nodes obtained from modal analysis, demonstrating a 7% increase in energy output. Theoretical results were experimentally verified by using open-circuit voltage values measured for the cantilevers segmented at optimal and suboptimal segmentation lines.

  5. MULTIMODE quantum calculations of intramolecular vibrational energies of the water dimer and trimer using ab initio-based potential energy surfaces

    Science.gov (United States)

    Wang, Yimin; Carter, Stuart; Braams, Bastiaan J.; Bowman, Joel M.

    2008-02-01

    We report vibrational configuration interaction calculations of the monomer fundamentals of (H2O)2, (D2O)2, (H2O)3, and (D2O)3 using the code MULTIMODE and full dimensional ab initio-based global potential energies surfaces (PESs). For the dimer the HBB PES [Huang et al., J. Chem. Phys 128, 034312 (2008)] is used and for the trimer a new PES, reported here, is used. The salient properties of the new trimer PES are presented and compared to previous single-point calculations and the vibrational energies are compared with experiments.

  6. Simulated vibrational spectra of aflatoxins and their demethylated products and the estimation of the energies of the demethylation reactions

    Science.gov (United States)

    Billes, Ferenc; Móricz, Ágnes M.; Tyihák, Ernő; Mikosch, Hans

    2006-06-01

    The structure of four natural mycotoxins, the aflatoxin B 1, B 2, G 1 and G 2 and their demethylated products were optimized with quantum chemical method. The energies and the thermodynamic functions of the molecules were calculated and applied to calculation of the reaction energies of the demethylations. Further results of the calculations are the vibrational force constants, the infrared spectra of the molecules and the assignments of the spectral bands.

  7. Analyses of Non-bonding Length, Partial Atomics Charge and Electrostatic Energy from Molecular Dynamics Simulation of Phospholipase A2 – Substrate

    Directory of Open Access Journals (Sweden)

    Nirwan Syarif

    2016-11-01

    Full Text Available This paper reports molecular dynamics simulation of phospholipase A2 (PLA2– substrate that has been done. Non-bonding length, partial atomic charge and electrostatic energy were used to evaluation the interaction between PLA2 and substrate. The research was subjected for three types of PLA2 of different sources, i.e, homo sapien, bovinus and porcinus, by using computer files of their molecular structures. The files with code 3elo, 1bp2, dan 1y6o were downloaded from protein data bank. Substrate structure can be found in 1y60 and was separated from its enzyme structure and docked into two other PLA2 structures for simulation purpose. Molecular dynamics simulations were done for 30000 steps with constant in number of molecules, volume and temperature (NVT. The results showed the existing of flip-flop mechanism as basic feature of PLA2 – substrate reactions. Interaction length analysis results indicated the presence of water molecules on the structures of 1bp2 and 3elo at the time of the simulation was completed. The existence of aspagine at the reaction site confirmed the theory that this amino acid is responsible for the survival of the reaction. the electrostatic energy increased substantially in the interaction after homo sapien PLA2 (3elo and Bovinus (1bp2 with the substrate. Inverse effect took place in the PLA porcinus (1y6o.

  8. A new deflection technique applied to an existing scheme of electrostatic accelerator for high energy neutral beam injection in fusion reactor devices

    Energy Technology Data Exchange (ETDEWEB)

    Pilan, N., E-mail: nicola.pilan@igi.cnr.it; Antoni, V.; De Lorenzi, A.; Chitarin, G.; Veltri, P.; Sartori, E. [Consorzio RFX—Associazione EURATOM-ENEA per la Fusione, Corso Stati Uniti 4, 35127 Padova (Italy)

    2016-02-15

    A scheme of a neutral beam injector (NBI), based on electrostatic acceleration and magneto-static deflection of negative ions, is proposed and analyzed in terms of feasibility and performance. The scheme is based on the deflection of a high energy (2 MeV) and high current (some tens of amperes) negative ion beam by a large magnetic deflector placed between the Beam Source (BS) and the neutralizer. This scheme has the potential of solving two key issues, which at present limit the applicability of a NBI to a fusion reactor: the maximum achievable acceleration voltage and the direct exposure of the BS to the flux of neutrons and radiation coming from the fusion reactor. In order to solve these two issues, a magnetic deflector is proposed to screen the BS from direct exposure to radiation and neutrons so that the voltage insulation between the electrostatic accelerator and the grounded vessel can be enhanced by using compressed SF{sub 6} instead of vacuum so that the negative ions can be accelerated at energies higher than 1 MeV. By solving the beam transport with different magnetic deflector properties, an optimum scheme has been found which is shown to be effective to guarantee both the steering effect and the beam aiming.

  9. A new deflection technique applied to an existing scheme of electrostatic accelerator for high energy neutral beam injection in fusion reactor devices

    Science.gov (United States)

    Pilan, N.; Antoni, V.; De Lorenzi, A.; Chitarin, G.; Veltri, P.; Sartori, E.

    2016-02-01

    A scheme of a neutral beam injector (NBI), based on electrostatic acceleration and magneto-static deflection of negative ions, is proposed and analyzed in terms of feasibility and performance. The scheme is based on the deflection of a high energy (2 MeV) and high current (some tens of amperes) negative ion beam by a large magnetic deflector placed between the Beam Source (BS) and the neutralizer. This scheme has the potential of solving two key issues, which at present limit the applicability of a NBI to a fusion reactor: the maximum achievable acceleration voltage and the direct exposure of the BS to the flux of neutrons and radiation coming from the fusion reactor. In order to solve these two issues, a magnetic deflector is proposed to screen the BS from direct exposure to radiation and neutrons so that the voltage insulation between the electrostatic accelerator and the grounded vessel can be enhanced by using compressed SF6 instead of vacuum so that the negative ions can be accelerated at energies higher than 1 MeV. By solving the beam transport with different magnetic deflector properties, an optimum scheme has been found which is shown to be effective to guarantee both the steering effect and the beam aiming.

  10. Micromachined cantilevers-on-membrane topology for broadband vibration energy harvesting

    Science.gov (United States)

    Jia, Yu; Du, Sijun; Seshia, Ashwin A.

    2016-12-01

    The overwhelming majority of microelectromechanical piezoelectric vibration energy harvesting topologies have been based on cantilevers, doubly-clamped beams or basic membranes. While these conventional designs offer simplicity, their broadband responses have been limited thus far. This paper investigates the feasibility of a new integrated cantilevers-on-membrane design that explores the optimisation of piezoelectric strain distribution and improvement of the broadband power output. While a classic membrane has the potential to offer a broader resonant peak than its cantilever counterpart, the inclusion of a centred proof mass compromises its otherwise high strain energy regions. The proposed topology addresses this issue by relocating the proof mass onto subsidiary cantilevers and combines the merits of both the membrane and the cantilever designs. Numerical simulations, constructed using fitted values based on finite element models, were used to investigate the broadband response of the proposed design in contrast to a classic plain membrane. Experimentally, when subjected to a band-limited white noise excitation, the new cantilevers-on-membrane harvester exhibited nearly two fold power output enhancement when compared to a classic plain membrane harvester of a comparable size.

  11. Comparison of Five Topologies of Cantilever-based MEMS Piezoelectric Vibration Energy Harvesters

    Science.gov (United States)

    Jia, Y.; Seshia, A. A.

    2014-11-01

    In the realm of MEMS piezoelectric vibration energy harvesters, cantilever-based designs are by far the most popular. Despite being deceptively simple, the active piezoelectric area near the clamped end is able to accumulate maximum strain-generated-electrical-charge, while the free end is able to accommodate a proof mass without compromising the effective area of the piezoelectric generator since it experiences minimal strain anyway. While other contending designs do exist, this paper investigates five micro-cantilever (MC) topologies, namely: a plain MC, a tapered MC, a lined MC, a holed MC and a coupled MC, in order to assess their relative performance as an energy harvester. Although a classical straight and plain MC offers the largest active piezoelectric area, alternative MC designs can potentially offer higher average mechanical strain distribution for a given mechanical loading. Numerical simulation and experimental comparison of these 5 MCs (0.5 μ AlN on 10 μm Si) with the same practical dimensions of 500 μm and 2000 μm, suggest a cantilever with a coupled subsidiary cantilever yield the best power performance, closely followed by the classical plain topology.

  12. Harvesting microalgal biomass using a magnetically induced membrane vibration (MMV) system: filtration performance and energy consumption.

    Science.gov (United States)

    Bilad, M R; Discart, V; Vandamme, D; Foubert, I; Muylaert, K; Vankelecom, Ivo F J

    2013-06-01

    This study was performed to investigate the effectiveness of submerged microfiltration to harvest both a marine diatom Phaeodactylum tricornutum and a Chlorella vulgaris in a recently developed magnetically induced membrane vibrating (MMV) system. We assess the filtration performance by conducting the improved flux step method (IFM), fed-batch concentration filtrations and membrane fouling autopsy using two lab-made membranes with different porosity. The full-scale energy consumption was also estimated. Overall results suggest that the MMV offers a good fouling control and the process was proven to be economically attractive. By combining the membrane filtration (15× concentration) with centrifugation to reach a final concentration of 25% w/v, the energy consumption to harvest P. tricornutum and C. vulgaris was, respectively, as low as 0.84 and 0.77kWh/m(3), corresponding to 1.46 and 1.39 kWh/kg of the harvested biomass. Copyright © 2013 Elsevier Ltd. All rights reserved.

  13. Ion association in aqueous solutions probed through vibrational energy transfers among cation, anion, and water molecules.

    Science.gov (United States)

    Li, Jiebo; Bian, Hongtao; Chen, Hailong; Wen, Xiewen; Hoang, Bryan T; Zheng, Junrong

    2013-04-25

    KSCN and NH4SCN aqueous solutions were investigated with intermolecular vibrational energy transfer methods. In a KSCN/H2O (1/10 molar ratio) solution, 90% of the initial excitation of the CN stretch (~2066 cm(-1)) of the SCN(-) anion is transferred to the HOH bending mode (~1636 cm(-1)) of water molecules with an energy transfer time constant 3.1 ps. In a NH4SCN/H2O (1/10 molar ratio) solution, only 49% of the CN excitation flows to the water HOH bending mode with a time constant 6.3 ps. Most of the remaining CN excitation goes to the NH bending mode (~1460 cm(-1)) of the NH(+) cation with a time constant of 7.0 ps. The results indicate that about 50% of the energy transfer channel from the CN stretch to the HOH bending observed in the KSCN solution is overpowered by the NH4(+) cations in the NH4SCN/H2O solution. Ion concentration dependent measurements support this argument. According to the dipole/dipole approximation, the CN/OH energy transfer occurs most efficiently between SCN(-) anions and the water molecules closest to them. The experimental results therefore suggest that more than 50% of the water molecules closest to the SCN(-) anions are replaced by the NH4(+) cations in the NH4SCN/H2O (1/10 molar ratio) solution. The percentage is much larger than the NH4(+)/water ratio of 10%, indicating that the ion association between NH4(+) and SCN(-) is caused by the chemical nature of the solution rather than the statistical "forced contact" because of the high ion concentration.

  14. Electrostatic Solvation Energy for Two Oppositely Charged Ions in a Solvated Protein System: Salt Bridges Can Stabilize Proteins

    Science.gov (United States)

    Gong, Haipeng; Freed, Karl F.

    2010-01-01

    Abstract Born-type electrostatic continuum methods have been an indispensable ingredient in a variety of implicit-solvent methods that reduce computational effort by orders of magnitude compared to explicit-solvent MD simulations and thus enable treatment using larger systems and/or longer times. An analysis of the limitations and failures of the Born approaches serves as a guide for fundamental improvements without diminishing the importance of prior works. One of the major limitations of the Born theory is the lack of a liquidlike description of the response of solvent dipoles to the electrostatic field of the solute and the changes therein, a feature contained in the continuum Langevin-Debye (LD) model applied here to investigate how Coulombic interactions depend on the location of charges relative to the protein/water boundary. This physically more realistic LD model is applied to study the stability of salt bridges. When compared head to head using the same (independently measurable) physical parameters (radii, dielectric constants, etc.), the LD model is in good agreement with observations, whereas the Born model is grossly in error. Our calculations also suggest that a salt bridge on the protein's surface can be stabilizing when the charge separation is ≤4 Å. PMID:20141761

  15. Perspectives on electrostatics and conformational motions in enzyme catalysis.

    Science.gov (United States)

    Hanoian, Philip; Liu, C Tony; Hammes-Schiffer, Sharon; Benkovic, Stephen

    2015-02-17

    CONSPECTUS: Enzymes are essential for all living organisms, and their effectiveness as chemical catalysts has driven more than a half century of research seeking to understand the enormous rate enhancements they provide. Nevertheless, a complete understanding of the factors that govern the rate enhancements and selectivities of enzymes remains elusive, due to the extraordinary complexity and cooperativity that are the hallmarks of these biomolecules. We have used a combination of site-directed mutagenesis, pre-steady-state kinetics, X-ray crystallography, nuclear magnetic resonance (NMR), vibrational and fluorescence spectroscopies, resonance energy transfer, and computer simulations to study the implications of conformational motions and electrostatic interactions on enzyme catalysis in the enzyme dihydrofolate reductase (DHFR). We have demonstrated that modest equilibrium conformational changes are functionally related to the hydride transfer reaction. Results obtained for mutant DHFRs illustrated that reductions in hydride transfer rates are correlated with altered conformational motions, and analysis of the evolutionary history of DHFR indicated that mutations appear to have occurred to preserve both the hydride transfer rate and the associated conformational changes. More recent results suggested that differences in local electrostatic environments contribute to finely tuning the substrate pKa in the initial protonation step. Using a combination of primary and solvent kinetic isotope effects, we demonstrated that the reaction mechanism is consistent across a broad pH range, and computer simulations suggested that deprotonation of the active site Tyr100 may play a crucial role in substrate protonation at high pH. Site-specific incorporation of vibrational thiocyanate probes into the ecDHFR active site provided an experimental tool for interrogating these microenvironments and for investigating changes in electrostatics along the DHFR catalytic cycle

  16. Two-dimensional concentrated-stress low-frequency piezoelectric vibration energy harvesters

    Energy Technology Data Exchange (ETDEWEB)

    Sharpes, Nathan [Center for Energy Harvesting Materials and Systems (CEHMS), Virginia Tech, Blacksburg, Virginia 24061 (United States); Abdelkefi, Abdessattar [Department of Mechanical and Aerospace Engineering, New Mexico State University, Las Cruces, New Mexico 88003 (United States); Priya, Shashank [Center for Energy Harvesting Materials and Systems (CEHMS), Virginia Tech, Blacksburg, Virginia 24061 (United States); Bio-Inspired Materials and Devices Laboratory (BMDL), Virginia Tech, Blacksburg, Virginia 24061 (United States)

    2015-08-31

    Vibration-based energy harvesters using piezoelectric materials have long made use of the cantilever beam structure. Surmounting the deficiencies in one-dimensional cantilever-based energy harvesters has been a major focus in the literature. In this work, we demonstrate a strategy of using two-dimensional beam shapes to harvest energy from low frequency excitations. A characteristic Zigzag-shaped beam is created to compare against the two proposed two-dimensional beam shapes, all of which occupy a 25.4 × 25.4 mm{sup 2} area. In addition to maintaining the low-resonance bending frequency, the proposed beam shapes are designed with the goal of realizing a concentrated stress structure, whereby stress in the beam is concentrated in a single area where a piezoelectric layer may be placed, rather than being distributed throughout the beam. It is shown analytically, numerically, and experimentally that one of the proposed harvesters is able to provide significant increase in power production, when the base acceleration is set equal to 0.1 g, with only a minimal change in the resonant frequency compared to the current state-of-the-art Zigzag shape. This is accomplished by eliminating torsional effects, producing a more pure bending motion that is necessary for high electromechanical coupling. In addition, the proposed harvesters have a large effective beam tip whereby large tip mass may be placed while retaining a low-profile, resulting in a low volume harvester and subsequently large power density.

  17. Global stabilization control of high-energy responses of a nonlinear wideband piezoelectric vibration energy harvester using a self-excitation circuit

    Science.gov (United States)

    Kitamura, Norihiko; Masuda, Arata

    2017-04-01

    This paper presents a resonance-type vibration energy harvester using a nonlinear oscillator with self-excitation circuit. The bandwidth of the resonance peak and the performance of the power generation at the resonance frequency are trade- offs for the conventional linear vibration energy harvester. A nonlinear oscillator can expand the resonance frequency band to generate larger electric power in a wider frequency range. However, it is difficult for the harmonically excited nonlinear vibration energy harvester to maintain the highest-energy response under the presence of disturbances since the nonlinear oscillator can have multiple stable steady-state solutions in the resonance band. In order to provide the global stability to the highest-energy solution, we introduce a self-excitation circuit which can destabilize other unexpected lower-energy solutions and entrain the oscillator only in the highest-energy solution. Numerical and experimental studies show that the proposed self-excitation control can provide the global stability to the highest-solution and maintain the high performance of the power generation in the widened resonance frequency band.

  18. Local orientational order in liquids revealed by resonant vibrational energy transfer

    NARCIS (Netherlands)

    Panman, M.R.; Shaw, D.J.; Ensing, B.; Woutersen, S.

    2014-01-01

    We demonstrate that local orientational ordering in a liquid can be observed in the decay of the vibrational anisotropy caused by resonant transfer of vibrational excitations between its constituent molecules. We show that the functional form of this decay is determined by the (distribution of)

  19. Vibronic energy map and excited state vibrational characteristics of magnesium myoglobin determined by energy-selective fluorescence.

    OpenAIRE

    Kaposi, A D; Vanderkooi, J. M.

    1992-01-01

    The vibrational frequencies of the singlet excited state of Mg-substituted myoglobin and relative absorption probabilities were determined by fluorescence line-narrowing spectroscopy. These spectra contain information on the structure of the excited state species, and the availability of vibrationally resolved spectra from excited state biomolecules should aid in elucidating their structure and reactivity.

  20. Electrostatic Climber for Space Elevator and Launcher

    OpenAIRE

    Bolonkin, A.

    2007-01-01

    Author details research on the new, very prospective, electrostatic Space Elevator climber based on a new electrostatic linear engine previously offered at the 42nd Joint Propulsion Conference (AIAA-2006-5229) and published in AEAT, Vol.78, No.6, 2006, pp. 502-508. The electrostatic climber discussed can have any speed (and braking), the energy for climber movement is delivered by a lightweight high-voltage line into a Space Elevator-holding cable from Earth electric generator. This electric ...

  1. Water 16-mers and hexamers: assessment of the three-body and electrostatically embedded many-body approximations of the correlation energy or the nonlocal energy as ways to include cooperative effects.

    Science.gov (United States)

    Qi, Helena W; Leverentz, Hannah R; Truhlar, Donald G

    2013-05-30

    This work presents a new fragment method, the electrostatically embedded many-body expansion of the nonlocal energy (EE-MB-NE), and shows that it, along with the previously proposed electrostatically embedded many-body expansion of the correlation energy (EE-MB-CE), produces accurate results for large systems at the level of CCSD(T) coupled cluster theory. We primarily study water 16-mers, but we also test the EE-MB-CE method on water hexamers. We analyze the distributions of two-body and three-body terms to show why the many-body expansion of the electrostatically embedded correlation energy converges faster than the many-body expansion of the entire electrostatically embedded interaction potential. The average magnitude of the dimer contributions to the pairwise additive (PA) term of the correlation energy (which neglects cooperative effects) is only one-half of that of the average dimer contribution to the PA term of the expansion of the total energy; this explains why the mean unsigned error (MUE) of the EE-PA-CE approximation is only one-half of that of the EE-PA approximation. Similarly, the average magnitude of the trimer contributions to the three-body (3B) term of the EE-3B-CE approximation is only one-fourth of that of the EE-3B approximation, and the MUE of the EE-3B-CE approximation is one-fourth that of the EE-3B approximation. Finally, we test the efficacy of two- and three-body density functional corrections. One such density functional correction method, the new EE-PA-NE method, with the OLYP or the OHLYP density functional (where the OHLYP functional is the OptX exchange functional combined with the LYP correlation functional multiplied by 0.5), has the best performance-to-price ratio of any method whose computational cost scales as the third power of the number of monomers and is competitive in accuracy in the tests presented here with even the electrostatically embedded three-body approximation.

  2. PCE: web tools to compute protein continuum electrostatics

    Science.gov (United States)

    Miteva, Maria A.; Tufféry, Pierre; Villoutreix, Bruno O.

    2005-01-01

    PCE (protein continuum electrostatics) is an online service for protein electrostatic computations presently based on the MEAD (macroscopic electrostatics with atomic detail) package initially developed by D. Bashford [(2004) Front Biosci., 9, 1082–1099]. This computer method uses a macroscopic electrostatic model for the calculation of protein electrostatic properties, such as pKa values of titratable groups and electrostatic potentials. The MEAD package generates electrostatic energies via finite difference solution to the Poisson–Boltzmann equation. Users submit a PDB file and PCE returns potentials and pKa values as well as color (static or animated) figures displaying electrostatic potentials mapped on the molecular surface. This service is intended to facilitate electrostatics analyses of proteins and thereby broaden the accessibility to continuum electrostatics to the biological community. PCE can be accessed at . PMID:15980492

  3. Energy Finite Element Analysis Developments for Vibration Analysis of Composite Aircraft Structures

    Science.gov (United States)

    Vlahopoulos, Nickolas; Schiller, Noah H.

    2011-01-01

    The Energy Finite Element Analysis (EFEA) has been utilized successfully for modeling complex structural-acoustic systems with isotropic structural material properties. In this paper, a formulation for modeling structures made out of composite materials is presented. An approach based on spectral finite element analysis is utilized first for developing the equivalent material properties for the composite material. These equivalent properties are employed in the EFEA governing differential equations for representing the composite materials and deriving the element level matrices. The power transmission characteristics at connections between members made out of non-isotropic composite material are considered for deriving suitable power transmission coefficients at junctions of interconnected members. These coefficients are utilized for computing the joint matrix that is needed to assemble the global system of EFEA equations. The global system of EFEA equations is solved numerically and the vibration levels within the entire system can be computed. The new EFEA formulation for modeling composite laminate structures is validated through comparison to test data collected from a representative composite aircraft fuselage that is made out of a composite outer shell and composite frames and stiffeners. NASA Langley constructed the composite cylinder and conducted the test measurements utilized in this work.

  4. Equivalent-circuit models for electret-based vibration energy harvesters

    Science.gov (United States)

    Phu Le, Cuong; Halvorsen, Einar

    2017-08-01

    This paper presents a complete analysis to build a tool for modelling electret-based vibration energy harvesters. The calculational approach includes all possible effects of fringing fields that may have significant impact on output power. The transducer configuration consists of two sets of metal strip electrodes on a top substrate that faces electret strips deposited on a bottom movable substrate functioning as a proof mass. Charge distribution on each metal strip is expressed by series expansion using Chebyshev polynomials multiplied by a reciprocal square-root form. The Galerkin method is then applied to extract all charge induction coefficients. The approach is validated by finite element calculations. From the analytic tool, a variety of connection schemes for power extraction in slot-effect and cross-wafer configurations can be lumped to a standard equivalent circuit with inclusion of parasitic capacitance. Fast calculation of the coefficients is also obtained by a proposed closed-form solution based on leading terms of the series expansions. The achieved analytical result is an important step for further optimisation of the transducer geometry and maximising harvester performance.

  5. Optimal Load and Stiffness for Displacement-Constrained Vibration Energy Harvesters

    CERN Document Server

    Halvorsen, Einar

    2016-01-01

    The power electronic interface to a vibration energy harvester not only provides ac-dc conversion, but can also set the electrical damping to maximize output power under displacement-constrained operation. This is commonly exploited for linear two-port harvesters by synchronous switching to realize a Coulomb-damped resonant generator, but has not been fully explored when the harvester is asynchronously switched to emulate a resistive load. In order to understand the potential of such an approach, the optimal values of load resistance and other control parameters need to be known. In this paper we determine analytically the optimal load and stiffness of a harmonically driven two-port harvester with displacement constraints. For weak-coupling devices, we do not find any benefit of load and stiffness adjustment beyond maintaining a saturated power level. For strong coupling we find that the power can be optimized to agree with the velocity damped generator beyond the first critical force for displacement-constra...

  6. Low-Frequency and Broadband Vibration Energy Harvesting Using Base-Mounted Piezoelectric Transducers.

    Science.gov (United States)

    Koven, Robert; Mills, Matthew; Gale, Richard; Aksak, Burak

    2017-11-01

    Piezoelectric vibration energy harvesters often consist of a cantilevered beam composed of a support layer and one or two piezoelectric layers with a tip mass. While this configuration is advantageous for maximizing electromechanical coupling, the mechanical properties of the piezoelectric material can place limitations on harvester size and resonant frequency. Here, we present numerical and experimental results from a new type of piezoelectric energy harvester in which the mechanical properties and the resonant frequency of the cantilever beam resonator are effectively decoupled from the piezoelectric component. Referred to as a base-mounted piezoelectric (BMP) harvester in this paper, this new design features a piezoelectric transducer mounted beneath the base of the cantilevered beam resonator. The flexibility in the material choice for the cantilever beam resonator means that the resonant frequency and the beam dimensions are essentially free parameters. A prototype made with a 1.6 mm mm mm polyurethane beam, a PZT-5H piezoelectric transducer, and an 8.36-g tip mass is shown to produce an average power of 8.75 and at 45 Hz across a 13.0- load under harmonic base excitations of constant peak acceleration at 0.25 and 1.0-g, respectively. We also show an increase in full-width half-maximum bandwidth approximately from 1.5 to 5.6 Hz using an array of four individual BMP harvesters of similar dimensions with peak power generation of at 37.6 Hz across a 1.934- load at 0.25-g peak base excitation. Finite elements-based numerical simulations are shown to be in reasonable agreement with experimental results, indicating that the harvester behaves like a damped mass-spring system as proposed in this paper. Fabricated using casting and laser machining techniques, this harvester shows potential as a low-cost option for powering small, low-power wireless sensor nodes and other low-power devices.

  7. Full Dimensional Vibrational Calculations for Methane Using AN Accurate New AB Initio Based Potential Energy Surface

    Science.gov (United States)

    Majumder, Moumita; Dawes, Richard; Wang, Xiao-Gang; Carrington, Tucker; Li, Jun; Guo, Hua; Manzhos, Sergei

    2014-06-01

    New potential energy surfaces for methane were constructed, represented as analytic fits to about 100,000 individual high-level ab initio data. Explicitly-correlated multireference data (MRCI-F12(AE)/CVQZ-F12) were computed using Molpro [1] and fit using multiple strategies. Fits with small to negligible errors were obtained using adaptations of the permutation-invariant-polynomials (PIP) approach [2,3] based on neural-networks (PIP-NN) [4,5] and the interpolative moving least squares (IMLS) fitting method [6] (PIP-IMLS). The PESs were used in full-dimensional vibrational calculations with an exact kinetic energy operator by representing the Hamiltonian in a basis of products of contracted bend and stretch functions and using a symmetry adapted Lanczos method to obtain eigenvalues and eigenvectors. Very close agreement with experiment was produced from the purely ab initio PESs. References 1- H.-J. Werner, P. J. Knowles, G. Knizia, 2012.1 ed. 2012, MOLPRO, a package of ab initio programs. see http://www.molpro.net. 2- Z. Xie and J. M. Bowman, J. Chem. Theory Comput 6, 26, 2010. 3- B. J. Braams and J. M. Bowman, Int. Rev. Phys. Chem. 28, 577, 2009. 4- J. Li, B. Jiang and Hua Guo, J. Chem. Phys. 139, 204103 (2013). 5- S Manzhos, X Wang, R Dawes and T Carrington, JPC A 110, 5295 (2006). 6- R. Dawes, X-G Wang, A.W. Jasper and T. Carrington Jr., J. Chem. Phys. 133, 134304 (2010).

  8. ZnO thin film piezoelectric MEMS vibration energy harvesters with two piezoelectric elements for higher output performance.

    Science.gov (United States)

    Wang, Peihong; Du, Hejun

    2015-07-01

    Zinc oxide (ZnO) thin film piezoelectric microelectromechanical systems (MEMS) based vibration energy harvesters with two different designs are presented. These harvesters consist of a silicon cantilever, a silicon proof mass, and a ZnO piezoelectric layer. Design I has a large ZnO piezoelectric element and Design II has two smaller and equally sized ZnO piezoelectric elements; however, the total area of ZnO thin film in two designs is equal. The ZnO thin film is deposited by means of radio-frequency magnetron sputtering method and is characterized by means of XRD and SEM techniques. These ZnO energy harvesters are fabricated by using MEMS micromachining. The natural frequencies of the fabricated ZnO energy harvesters are simulated and tested. The test results show that these two energy harvesters with different designs have almost the same natural frequency. Then, the output performance of different ZnO energy harvesters is tested in detail. The effects of series connection and parallel connection of two ZnO elements on the load voltage and power are also analyzed. The experimental results show that the energy harvester with two ZnO piezoelectric elements in parallel connection in Design II has higher load voltage and higher load power than the fabricated energy harvesters with other designs. Its load voltage is 2.06 V under load resistance of 1 MΩ and its maximal load power is 1.25 μW under load resistance of 0.6 MΩ, when it is excited by an external vibration with frequency of 1300.1 Hz and acceleration of 10 m/s(2). By contrast, the load voltage of the energy harvester of Design I is 1.77 V under 1 MΩ resistance and its maximal load power is 0.98 μW under 0.38 MΩ load resistance when it is excited by the same vibration.

  9. Homogeneity analysis of high yield manufacturing process of mems-based pzt thick film vibrational energy harvesters

    DEFF Research Database (Denmark)

    Lei, Anders; Xu, Ruichao; Pedersen, C.M.

    2011-01-01

    This work presents a high yield wafer scale fabrication of MEMS-based unimorph silicon/PZT thick film vibrational energy harvesters aimed towards vibration sources with peak frequencies in the range of a few hundred Hz. By combining KOH etching with mechanical front side protection, SOI wafer...... to accurately define the thickness of the silicon part of the harvester and a silicon compatible PZT thick film screen-printing technique, we are able to fabricate energy harvesters on wafer scale with a yield higher than 90%. The characterization of the fabricated harvesters is focused towards the full wafer....../mass-production aspect; hence the analysis of uniformity in harvested power and resonant frequency....

  10. Calculated low-energy electron-impact vibrational excitation cross sections for CO2 molecule

    CERN Document Server

    Laporta, V; Celiberto, R

    2016-01-01

    Vibrational-excitation cross sections of ground electronic state of carbon dioxide molecule by electron-impact through the CO2-(2\\Pi) shape resonance is considered in the separation of the normal modes approximation. Resonance curves and widths are computed for each vibrational mode. The calculations assume decoupling between normal modes and employ the local complex potential model for the treatment of the nuclear dynamics, usually adopted for the electron-scattering involving diatomic molecules. Results are presented for excitation up to 10 vibrational levels in each mode and comparison with data present in the literature is discussed.

  11. Energy-Saving Vibration Impulse Coal Degradation at Finely Dispersed Coal-Water Slurry Preparation

    Directory of Open Access Journals (Sweden)

    Moiseev V.A.

    2015-01-01

    Full Text Available Theoretical and experimental research results of processes of finely dispersed coal-water slurry preparation for further generation of energetic gas in direct flow and vortex gas generator plants have been presented. It has been stated that frequency parameters of parabolic vibration impulse mill influence degradation degree. Pressure influence on coal parameters in grinding cavity has been proven. Experimental researches have proven efficiency of vibration impulse mill with unbalanced mass vibrator generator development. Conditions of development on intergranular walls of coal cracks have been defined.

  12. Relative contribution of combined kinetic and exchange energy terms vs the electronic component of molecular electrostatic potential in hardness potential derivatives.

    Science.gov (United States)

    Bhattacharjee, Rituparna; Roy, Ram Kinkar

    2013-11-14

    The relative contribution of the sum of kinetic [(10/9)CFρ(r)2/3] and exchange energy [(4/9)CXρ(r)1/3] terms to that of the electronic part of the molecular electrostatic potential [Vel(r)] in the variants of hardness potential is investigated to assess the proposed definition of Δ+h(k) = −[VelN+1(k) – VelN(k)] and Δ–h(k) = −[VelN(k) – VelN–1(k)] (Saha; et al. J. Comput. Chem. 2013, 34, 662). Some substituted benzenes and polycyclic aromatic hydrocarbons (PAHs) (undergoing electrophilic aromatic substitution), carboxylic acids, and their derivatives are chosen to carry out the theoretical investigation as stated above. Intra- and intermolecular reactivity trends generated by Δ+h(k) and Δ–h(k) are found to be satisfactory and are correlated reasonably well with experimental results.

  13. Vibration-rotation energy pattern in acetylene: (13)CH(12)CH up to 10 120 cm(-1).

    Science.gov (United States)

    Robert, S; Amyay, B; Fayt, A; Di Lonardo, G; Fusina, L; Tamassia, F; Herman, M

    2009-11-26

    All 18,219 vibration-rotation absorption lines of (13)CH(12)CH published in the literature, accessing substates up to 9400 cm(-1) and including some newly assigned, were simultaneously fitted to J-dependent Hamiltonian matrices exploiting the well-known vibrational polyad or cluster block-diagonalization, in terms of the pseudo quantum numbers N(s) = v(1) + v(2) + v(3) and N(r) = 5v(1) + 3v(2) + 5v(3) + v(4) + v(5), also accounting for k = l(4) + l(5) parity and e/f symmetry properties. Some 1761 of these lines were excluded from the fit, corresponding either to blended lines, for about 30% of them, or probably to lines perturbed by Coriolis for the remaining ones. The dimensionless standard deviation of the fit is 1.10, and 317 vibration-rotation parameters are determined. These results significantly extend those of a previous report considering levels below only 6750 cm(-1) [Fayt, A.; et al. J. Chem. Phys. 2007, 126, 114303]. Unexpected problems are reported when inserting in the global fit the information available on higher-energy polyads, extending from 9300 to 10 120 cm(-1). They are tentatively interpreted as resulting from a combination of the relative evolution of the two effective bending frequencies and long-range interpolyad low-order anharmonic resonances. The complete database, made of 18,865 vibration-rotation lines accessing levels up to 10 120 cm(-1), is made available as Supporting Information.

  14. Energy Dissipation from Vibrating Floor Slabs due to Human-Structure Interaction

    Directory of Open Access Journals (Sweden)

    James M.W. Brownjohn

    2001-01-01

    Full Text Available Lightweight pre-cast flooring systems using post-tensioning to increase strength but not stiffness are increasingly popular, and vibration serviceability problems tend to govern design of such floors where human occupants are increasingly concerned with vibrations. At the same time as inducing response, stationary human observers can also participate in the response as mitigating influence and it is clear that a human behaves as a highly effective damper, even when seated.

  15. Review on the Modeling of Electrostatic MEMS

    Science.gov (United States)

    Chuang, Wan-Chun; Lee, Hsin-Li; Chang, Pei-Zen; Hu, Yuh-Chung

    2010-01-01

    Electrostatic-driven microelectromechanical systems devices, in most cases, consist of couplings of such energy domains as electromechanics, optical electricity, thermoelectricity, and electromagnetism. Their nonlinear working state makes their analysis complex and complicated. This article introduces the physical model of pull-in voltage, dynamic characteristic analysis, air damping effect, reliability, numerical modeling method, and application of electrostatic-driven MEMS devices. PMID:22219707

  16. Vibration-rotation energy pattern in acetylene: 13CH12CH up to 6750 cm-1.

    Science.gov (United States)

    Fayt, A; Robert, S; Di Lonardo, G; Fusina, L; Tamassia, F; Herman, M

    2007-03-21

    All known vibration-rotation absorption lines of 13CH12CH accessing levels up to 6750 cm-1 were gathered from the literature. They were fitted simultaneously to J-dependent Hamiltonian matrices exploiting the well known vibrational polyad or cluster block diagonalization, in terms of the pseudo-quantum-numbers Ns=v1+v2+v3 and Nr=5v1+3v2+5v3+v4+v5, and accounting also for l parity and ef symmetry properties. The anharmonic interaction coupling terms known to occur from a pure vibrational fit in this acetylene isotopologue [Robert et al., J. Chem. Phys. 123, 174302 (2005)] were included in the model. A total of 12 703 transitions accessing 158 different (v1v2v3v4v5,l4l5) vibrational states was fitted with a dimensionless standard deviation of 0.99, leading to the determination of 216 vibration-rotation parameters. The experimental data included very weak vibration-rotation transitions accessing 18 previously unreported states, some of them forming Q branches with very irregular patterns.

  17. Low-frequency, broadband vibration energy harvester using coupled oscillators and frequency up-conversion by mechanical stoppers

    Science.gov (United States)

    Dechant, Eduard; Fedulov, Feodor; Chashin, Dmitrii V.; Fetisov, Leonid Y.; Fetisov, Yuri K.; Shamonin, Mikhail

    2017-06-01

    The frequencies of ambient vibrations are often low (below 30 Hz). A broadband (3 dB bandwidth is larger than 10 Hz at an acceleration amplitude of 9.81 m s-2) vibration based energy harvester is proposed for transducing mechanical energy at such low frequencies into electrical energy. The mechanical setup converts low frequency mechanical vibrations into high frequency resonance oscillations of the transducer. This conversion is done by mechanical impacts on two mechanical stoppers. The originality of the presented design is that both low-frequency and high-frequency oscillators are permanently mechanically coupled. In the equivalent mechanical circuit, this coupling is achieved by connecting the ends of the stiff spring to both seismic masses, whereas one seismic mass (collison member) is also attached to the soft spring used as the constitutive element of a low-frequency oscillator. Further, both mechanical oscillators are not realized as conventional cantilever beams. In particular, the high frequency oscillator with the natural frequency of 340 Hz is a disc-shaped diaphragm with attached piezoelectric elements and a seismic mass. It is shown that it is possible to convert mechanical vibrations with acceleration amplitude of 9.81 m s-2 in the region between approximately 7 and 25 Hz into electrical power larger than 0.1 mW with the maximum value of 0.8 mW. A simplified mathematical model based on piecewise linear coupled oscillators shows good agreement with experimental results. The ways to enhance the performance of the harvester and improve agreement with experiments are discussed.

  18. Design of serial linkage-type vibration energy harvester with three resonant frequencies

    Science.gov (United States)

    Kim, Hyun Soo; Kim, Jun Woo; Park, Shi-Baek; Choi, Yong Je

    2017-11-01

    This paper presents a new design method of a planar 3 degrees-of-freedom(DOF) serial linkage-type vibration energy harvester with a single proof mass. The harvester is designed to generate electrical power at equally spaced three target resonant frequencies which can be chosen arbitrarily. For given target frequencies and a proof mass, the design method involves (1) the determination of the stiffness matrix, (2) the synthesis of the stiffness by means of a parallel connection of three line springs and (3) its conversion into a 3DOF device connected serially by torsional springs. The torsional springs are realized by the flexible hinge joints and the polyvinylidene fluoride(PVDF) films are attached on the joints. Upon determination of the desired stiffness matrix, the SQP algorithm is utilized to find the optimum locations and spring constants of the serial hinge joints for the minimum difference among three electrical power peaks. The FEM analysis and experiments are conducted to verify the proposed design method. Three measured resonant power peaks occur at 24.7, 30.4 and 33.6 Hz comparing to the target frequencies of 25, 30 and 35 Hz. The normalized maximum power of 14.5 {{uW}}/{({{{ms}}}-2)}2 is generated at 24.7 Hz. The experimental results also demonstrate that the harvester can generate at least 18.6% of the peak power throughout the frequency range from 23.1 to 36.5 Hz, which ensures consistently acquirable power within the operating frequency range by virtue of the coupled effect of a serial linkage-type structure.

  19. Combined experimental and numerical investigation of energy harness utilizing vortex induced vibration over half cylinder using piezoelectric beams

    Science.gov (United States)

    Ahmed, Md. Tusher; Hossain, Md. Tanver; Rahman, Md. Ashiqur

    2017-06-01

    Energy harvesting technology has the ability to create self-powered electronic systems that do not rely on battery power for their operation. Wind energy can be converted into electricity via a piezoelectric transducer during the air flow over a cylinder. The vortex-induced vibration over the cylinder causes the piezoelectric beam to vibrate. Thus useful electric energy at the range 0.2-0.3V is found which can be useful for self-powering small electronic devices. In the present study, prototypes of micro-energy harvester with a shape of 65 mm × 37 mm × 0.4 mm are developed and tested for airflow over D-shaped bluff body for diameters of 15, 20 and 28mm in an experimental setup consisting of a long wind tunnel of 57cm × 57cm with variable speeds of the motor for different flow velocities and the experimental setup is connected at the downstream where flow velocity is the maximum. Experimental results show that the velocity and induced voltage follows a regular linear pattern. A maximum electrical potential of 140 mV for velocity of 1.1 ms-1 at a bluff body diameter of 15 mm is observed in the energy harvester that can be applied in many practical cases for self-powering electronic devices. The simulation of this energy harvesting phenomena is then simulated using COMSOLE multi-physics. Diameter of the bluff bodies as well as flow velocity and size of cantilever beam are varied and the experimental findings are found to be in good agreement with the simulated ones. The simulations along with the experimental data show the possibility of generating electricity from vortex induced vibration and can be applied in many practical cases for self-powering electronic devices.

  20. Vibrational studies of Thyroxine hormone: Comparative study with quantum chemical calculations

    Science.gov (United States)

    Borah, Mukunda Madhab; Devi, Th. Gomti

    2017-11-01

    The FTIR and Raman techniques have been used to record spectra of Thyroxine. The stable geometrical parameters and vibrational wave numbers were calculated based on potential energy distribution (PED) using vibrational energy distribution analysis (VEDA) program. The vibrational energies are assigned to monomer, chain dimer and cyclic dimers of this molecule using the basis set B3LYP/LANL2DZ. The computational scaled frequencies are in good agreements with the experimental results. The study is extended to calculate the HOMO-LUMO energy gap, Molecular Electrostatic Potential (MEP) surface, hardness (η), chemical potential (μ), Global electrophilicity index (ω) and different thermo dynamical properties of Thyroxine in different states. The calculated HOMO-LUMO energies show the charge transfer occurs within the molecule. The calculated Natural bond orbital (NBO) analysis confirms the presence of intra-molecular charge transfer as well as the hydrogen bonding interaction.

  1. Electrostatics in Chemistry

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 4; Issue 7. Electrostatics in Chemistry - Molecular Electrostatic Potential: Visualization and Topography. Shridhar R Gadre Pravin K Bhadane. Series Article Volume 4 Issue 7 July 1999 pp 14-23 ...

  2. Vibrational and Electronic Energy Transfer and Dissociation of Diatomic Molecules by Electron Collisions

    Science.gov (United States)

    Huo, Winifred M.; Langhoff, Stephen R. (Technical Monitor)

    1995-01-01

    At high altitudes and velocities equal to or greater than the geosynchronous return velocity (10 kilometers per second), the shock layer of a hypersonic flight will be in thermochemical nonequilibrium and partially ionized. The amount of ionization is determined by the velocity. For a trans atmospheric flight of 10 kilometers per second and at an altitude of 80 kilometers, a maximum of 1% ionization is expected. At a velocity of 12 - 17 kilometer per second, such as a Mars return mission, up to 30% of the atoms and molecules in the flow field will be ionized. Under those circumstances, electrons play an important role in determining the internal states of atoms and molecules in the flow field and hence the amount of radiative heat load and the distance it takes for the flow field to re-establish equilibrium. Electron collisions provide an effective means of transferring energy even when the electron number density is as low as 1%. Because the mass of an electron is 12,760 times smaller than the reduced mass of N2, its average speed, and hence its average collision frequency, is more than 100 times larger. Even in the slightly ionized regime with only 1% electrons, the frequency of electron-molecule collisions is equal to or larger than that of molecule-molecule collisions, an important consideration in the low density part of the atmosphere. Three electron-molecule collision processes relevant to hypersonic flows will be considered: (1) vibrational excitation/de-excitation of a diatomic molecule by electron impact, (2) electronic excitation/de-excitation, and (3) dissociative recombination in electron-diatomic ion collisions. A review of available data, both theory and experiment, will be given. Particular attention will be paid to tailoring the molecular physics to the condition of hypersonic flows. For example, the high rotational temperatures in a hypersonic flow field means that most experimental data carried out under room temperatures are not applicable. Also

  3. New analytical model for the ozone electronic ground state potential surface and accurate ab initio vibrational predictions at high energy range.

    Science.gov (United States)

    Tyuterev, Vladimir G; Kochanov, Roman V; Tashkun, Sergey A; Holka, Filip; Szalay, Péter G

    2013-10-07

    An accurate description of the complicated shape of the potential energy surface (PES) and that of the highly excited vibration states is of crucial importance for various unsolved issues in the spectroscopy and dynamics of ozone and remains a challenge for the theory. In this work a new analytical representation is proposed for the PES of the ground electronic state of the ozone molecule in the range covering the main potential well and the transition state towards the dissociation. This model accounts for particular features specific to the ozone PES for large variations of nuclear displacements along the minimum energy path. The impact of the shape of the PES near the transition state (existence of the "reef structure") on vibration energy levels was studied for the first time. The major purpose of this work was to provide accurate theoretical predictions for ozone vibrational band centres at the energy range near the dissociation threshold, which would be helpful for understanding the very complicated high-resolution spectra and its analyses currently in progress. Extended ab initio electronic structure calculations were carried out enabling the determination of the parameters of a minimum energy path PES model resulting in a new set of theoretical vibrational levels of ozone. A comparison with recent high-resolution spectroscopic data on the vibrational levels gives the root-mean-square deviations below 1 cm(-1) for ozone band centres up to 90% of the dissociation energy. New ab initio vibrational predictions represent a significant improvement with respect to all previously available calculations.

  4. Electrostatics in Chemistry

    Indian Academy of Sciences (India)

    Electrostatics in Chemistry. 3. Molecular Electrostatic Potential: Visualization and Topography. Shridhar R Gadre and Pravin K Bhadane. 1 1. Basic Principles, Resona- nce, Vol.4, No.2, 11-19, 1999. 2. Electrostatic Potentials of. Atoms, Ions and Molecules,. Resonance, Vol.4, No.5, 40-51,. 1999. Topographical features of the ...

  5. Vibrational lineshapes of adsorbates on solid surfaces

    Science.gov (United States)

    Ueba, H.

    A review is presented of the current activity in vibrational spectroscopy of adsorbates on metal surfaces. A brief introduction of the representative spectroscopies is given to demonstrate the rich information contained in vibrational spectra, which are characterized by their intensity, peak position and width. Analysis of vibrational spectra enables us to gain the deep insight into not only the local character of adsorption site or geometry, but also the dynamical interaction between the adsorbates or between the adsorbate and the substrate. Some recent instructive experimental results, mostly of a CO molecule adsorbed on various metal surfaces, are accompanied by the corresponding theoretical recipe for vibrational excitation mechanisms. Wide spread experimental results of the C-O stretching frequency of CO adsorbed on metal surfaces are discussed in terms of the chemical effect involving the static and dynamic charge transfers between the chemisorbed CO and metal, and also of the electrostatic dipole-dipole interaction between the molecules. The central subject of this review is directed to the linshapes characterized by the vibrational relaxation processes of adsorbates. A simple and transparent model is introduced to show that the characteristic decay time of the correlation function for the vibrational coordinates is the key quantity to determine the spectral lineshapes. Recent experimental results focused on a search for an intrinsic broadening mechanism are reviewed in the light of the so-called T1 (energy) and T2 (phase) relaxation processesof the vibrational excited states of adsorbates. Those are the vibrational energy dissipation into the elementary excitation, such as phonons or electron-hole pairs in the metal substrate, and pure dephasing due to the energy exchange with the sorroundings. The change of width and frequency by varying the experimental variables, such as temperature or isotope effect, provides indispensable knowledge for the dynamical

  6. Experimental verification of a novel MEMS multi-modal vibration energy harvester for ultra-low power remote sensing nodes

    Science.gov (United States)

    Iannacci, J.; Sordo, G.; Serra, E.; Kucera, M.; Schmid, U.

    2015-05-01

    In this work, we discuss the verification and preliminary experimental characterization of a MEMS-based vibration Energy Harvester (EH) design. The device, named Four-Leaf Clover (FLC), is based on a circular-shaped mechanical resonator with four petal-like mass-spring cascaded systems. This solution introduces several mechanical Degrees of Freedom (DOFs), and therefore enables multiple resonant modes and deformation shapes in the vibrations frequency range of interest. The target is to realize a wideband multi-modal EH-MEMS device, that overcomes the typical narrowband working characteristics of standard cantilevered EHs, by ensuring flexible and adaptable power source to ultra-low power electronics for integrated remote sensing nodes (e.g. Wireless Sensor Networks - WSNs) in the Internet of Things (IoT) scenario, aiming to self-powered and energy autonomous smart systems. Finite Element Method simulations of the FLC EH-MEMS show the presence of several resonant modes for vibrations up to 4-5 kHz, and level of converted power up to a few μW at resonance and in closed-loop conditions (i.e. with resistive load). On the other hand, the first experimental tests of FLC fabricated samples, conducted with a Laser Doppler Vibrometer (LDV), proved the presence of several resonant modes, and allowed to validate the accuracy of the FEM modeling method. Such a good accordance holds validity for what concerns the coupled field behavior of the FLC EH-MEMS, as well. Both measurements and simulations performed at 190 Hz (i.e. out of resonance) showed the generation of power in the range of nW (Root Mean Square - RMS values). Further steps of this work will include the experimental characterization in a full range of vibrations, aiming to prove the whole functionality of the FLC EH-MEMS proposed design concept.

  7. Atomic packing and low energy vibrations in B2O3 glasses, compacted under GPa pressures

    Directory of Open Access Journals (Sweden)

    Giovanni Carini Jr.

    2017-06-01

    Full Text Available Vibrational properties of crystals are well described by Debye's theory. This doesn't hold for vitreous systems, where an excess density of low frequency vibrational states, called Boson peak, appears. In this work we study glassy boron trioxide (B2O3, a prototype system widely used as basic element of multi component glasses. Our aim is to get some insight into the dependence of mechanical and vibrational properties on the structure of glasses, i.e., on the atomic packing. For this reason, samples were compacted by using a multi anvil press up to pressures of 10 GPa. A comparative analysis of light Raman scattering and mechanical characteristics have been performed on densified samples. The results show that either Raman spectra and elastic constants are affected by the densification process owing to the hardening of the elastic continuum.

  8. Stochastic Response of Energy Balanced Model for Vortex-Induced Vibration

    DEFF Research Database (Denmark)

    Nielsen, Søren R.K.; Krenk, S.

    of lightly damped structures are found on two branches, with the highest amplification branch on the low-frequency branch. The effect free wind turbulence is to destabilize the vibrations on the high amplification branch, thereby reducing the oscillation amplitude. The effect is most pronounced for very......A double oscillator model for vortex-induced oscillations of structural elements based on exact power exchange between fluid and structure, recently proposed by authors, is extended to include the effect of the turbulent component of the wind. In non-turbulent flow vortex-induced vibrations...... lightly damped structures. The character of the structural vibrations changes with increasing turbulence and damping from nearly regular harmonic oscillation to typical narrow-banded stochastic response, closely resembling observed behaviour in experiments and full-scale structures....

  9. Energy-efficient on-node signal processing for vibration monitoring

    NARCIS (Netherlands)

    Ramachandran, Vignesh Raja Karuppiah; Sanchez Ramirez, Andrea; van der Zwaag, B.J.; Meratnia, Nirvana; Havinga, Paul J.M.

    In recent years, the use of wireless sensor networks for vibration monitoring is emphasized, because of its capability to continuously monitor at hard-to-reach locations of complex machines. Low power consumption is one of the main requirements for the sensor nodes in continuous and long-term

  10. Screen printed PZT/PZT thick film bimorph MEMS cantilever device for vibration energy harvesting

    DEFF Research Database (Denmark)

    Xu, Ruichao; Lei, Anders; Dahl-Petersen, Christian

    2012-01-01

    materials; it provides mechanical support but it also reduces the power output. In our device we replace the support material with another layer of the piezoelectric material. With the absence of an inactive mechanical support all stresses induced by vibrations will be harvested by the active piezoelectric...

  11. Screen printed PZT/PZT thick film bimorph MEMS cantilever device for vibration energy harvesting

    DEFF Research Database (Denmark)

    Xu, R.; Lei, A.; Christiansen, T. L.

    2011-01-01

    . It provides mechanical support but it also reduces the power output. Our device replaces the support with another layer of the piezoelectric material, and with the absence of an inactive mechanical support all of the stresses induced by the vibrations will be harvested by the active piezoelectric elements....

  12. A handy-motion driven, frequency up-converted hybrid vibration energy harvester using PZT bimorph and nonmagnetic ball

    Science.gov (United States)

    Halim, M. A.; Cho, H. O.; Park, J. Y.

    2014-11-01

    We have presented a frequency up-converted hybrid type (Piezoelectric and Electromagnetic) vibration energy harvester that can be used in powering portable and wearable smart devices by handy motion. A transverse impact mechanism has been employed for frequency up-conversion. Use of two transduction mechanisms increases the output power as well as power density. The proposed device consists of a non-magnetic spherical ball (freely movable at handy motion frequency) to impact periodically on the parabolic top of a piezoelectric (PZT) cantilevered mass by sliding over it, allowing it to vibrate at its higher resonant frequency and generates voltage by virtue of piezoelectric effect. A magnet attached to the cantilever vibrates along with it at the same frequency and a relative motion between the magnet and a coil placed below it, induces emf voltage across the coil terminals as well. A macro-scale prototype of the harvester has been fabricated and tested by handy motion. With an optimum magnet-coil overlap, a maximum 0.98mW and 0.64mW peak powers have been obtained from the piezoelectric and the electromagnetic transducers of the proposed device while shaken, respectively. It offers 84.4μWcm-3 peak power density.

  13. Electrostatic accelerators fundamentals and applications

    CERN Document Server

    2005-01-01

    Electrostatic accelerators are an important and widespread subgroup within the broad spectrum of modern, large particle acceleration devices. They are specifically designed for applications that require high-quality ion beams in terms of energy stability and emittance at comparatively low energies (a few MeV). Their ability to accelerate virtually any kind of ion over a continuously tunable range of energies make them a highly versatile tool for investigations in many research fields including, but not limited to, atomic and nuclear spectroscopy, heavy ion reactions, accelerator mass spectroscopy as well as ion-beam analysis and modification. The book is divided into three parts. The first part concisely introduces the field of accelerator technology and techniques that emphasize their major modern applications. The second part treats the electrostatic accelerator per se: its construction and operational principles as well as its maintenance. The third part covers all relevant applications in which electrosta...

  14. Bandwidth Widening of Piezoelectric Cantilever Beam Arrays by Mass-Tip Tuning for Low-Frequency Vibration Energy Harvesting

    Directory of Open Access Journals (Sweden)

    Eduard Dechant

    2017-12-01

    Full Text Available Wireless sensor networks usually rely on internal permanent or rechargeable batteries as a power supply, causing high maintenance efforts. An alternative solution is to supply the entire system by harvesting the ambient energy, for example, by transducing ambient vibrations into electric energy by virtue of the piezoelectric effect. The purpose of this paper is to present a simple engineering approach for the bandwidth optimization of vibration energy harvesting systems comprising multiple piezoelectric cantilevers (PECs. The frequency tuning of a particular cantilever is achieved by changing the tip mass. It is shown that the bandwidth enhancement by mass tuning is limited and requires several PECs with close resonance frequencies. At a fixed frequency detuning between subsequent PECs, the achievable bandwidth shows a saturation behavior as a function of the number of cantilevers used. Since the resonance frequency of each PEC is different, the output voltages at a particular excitation frequency have different amplitudes and phases. A simple power-transfer circuit where several PECs with an individual full wave bridge rectifier are connected in parallel allows one to extract the electrical power close to the theoretical maximum excluding the diode losses. The experiments performed on two- and three-PEC arrays show reasonable agreement with simulations and demonstrate that this power-transfer circuit additionally influences the frequency dependence of the harvested electrical power.

  15. Electron energy and vibrational distribution functions of carbon monoxide in nanosecond atmospheric discharges and microsecond afterglows

    Science.gov (United States)

    Pietanza, L. D.; Colonna, G.; Capitelli, M.

    2017-12-01

    Nanopulse atmospheric carbon monoxide discharges and corresponding afterglows have been investigated in a wide range of applied reduced electric field (130 kinetics of vibrational and electronic excited states as well as to a simplified plasma chemistry for the different species formed during the activation of CO. The molar fraction of electronically excited states generated in the discharge is sufficient to create structures in the EEDF in the afterglow regime. On the other hand, only for long duration pulses (i.e. 50 ns), non-equilibrium vibrational distributions can be observed especially in the afterglow. The trend of the results for the case study E/N = 200 Td, \\text{pulse}=2$ ns is qualitatively and quantitatively similar to the corresponding case for CO2 implying that the activation of CO2 by cold plasmas should take into account the kinetics of formed CO with the same accuracy as the CO2 itself.

  16. Beamline Electrostatic Levitator (BESL) for in-situ High Energy K-Ray Diffraction Studies of Levitated Solids and Liquids at High Temperature

    Science.gov (United States)

    Gangopadhyay, A. K.; Lee, G. W.; Kelton, K. F.; Rogers, J. R.; Goldman, A. I.; Robinson, D. S.; Rathz, T. J.; Hyers, R. W.

    2005-01-01

    Determinations of the phase formation sequence, the crystal structures and the thermodynamic properties of materials at high temperatures are difficult because of contamination from the sample container and environment. Containerless processing techniques, such as electrostatic (ESL), electromagnetic (EML), aerodynamic, and acoustic levitation, are most suitable these studies. An adaptation of ESL for in-situ structural studies of a wide range of materials, including metals, semiconductors, insulators using high energy (125 keV) synchrotron x-rays is described here. This beamline ESL (BESL) allows the in-situ determination of the atomic structures of equilibrium solid and liquid phases, including undercooled liquids, as well as real-time studies of solid-solid and liquid-solid phase transformations. The use of image plate (MAR345) or GE-Angio detectors enables fast (30 ms - 1s) acquisition of complete diffraction patterns over a wide q-range (4 - 140/mm). The wide temperature range (300 - 2500 K), containerless processing under high vacuum (10(exp -7) - 10(exp -8) torr), and fast data acquisition, make BESL particularly suitable for phase diagram studies of high temperature materials. An additional, critically important, feature of BESL is the ability to also make simultaneous measurement of a host of thermo-physical properties, including the specific heat, enthalpy of transformation, solidus and liquidus temperatures, density, viscosity, and surface tension; all on the same sample and simultaneous with the structural measurements.

  17. Dynamic vibrations in wind energy systems: Application to vertical axis wind turbine

    Science.gov (United States)

    Mabrouk, Imen Bel; El Hami, Abdelkhalak; Walha, Lassâad; Zghal, Bacem; Haddar, Mohamed

    2017-02-01

    Dynamic analysis of Darrieus turbine bevel spur gear subjected to transient aerodynamic loads is carried out in the present study. The aerodynamic torque is obtained by solving the two dimensional unsteady incompressible Navies Stocks equation with the k-ω shear stress transport turbulence model. The results are presented for several values of tip speed ratio. The two-dimensional Computational Fluid Dynamics model is validated with experimental results. The optimum tip speed ratio is achieved, giving the best overall performance. In this study, we developed a lamped mass dynamic model with 14 degrees of freedom. This model is excited by external and internal issues sources. The main factors of these excitations are the periodic fluctuations of the gear meshes' stiffness and the unsteady aerodynamic torque oscillations. The vibration responses are obtained in time and frequency domains. The originality of our work is the correlation between the complexity of the aerodynamic phenomenon and the non-stationary dynamics vibration of the mechanical gearing system. The effect of the rotational speed on the dynamic behavior of the Darrieus turbine is also discussed. The present study shows that the variation of rotor rotational speed directly affects the torque production. However, there is a small change in the dynamic vibration of the studied gearing system.

  18. Tribo-charging properties of waste plastic granules in process of tribo-electrostatic separation.

    Science.gov (United States)

    Li, Jia; Wu, Guiqing; Xu, Zhenming

    2015-01-01

    Plastic products can be found everywhere in people's daily life. With the consistent growth of plastic consumption, more and more plastic waste is generated. Considering the stable chemical and physics characteristics of plastic, regular waste management methods are not suitable for recycling economic strategy of each government, which has become a serious environmental problem. Recycling plastic waste is considered to be the best way to treat it, because it cannot only deduce the waste but also save the energy to produce new virgin plastic. Tribo-electrostatic separation is strongly recommended for plastic separation as it can preserve the original properties of plastic and has little additional pollution. In this study, plastic granules are generated by crushing plastic waste in waste electric and electronic equipment. The tribo-charging properties of plastic waste were studied by vibrating tribo-charging and cyclone tribo-charging. The triboelectric series obtained by vibrating was: (-)-PE-PS-PC-PVC-ABS-PP-(+), while the triboelectric series obtained by cyclone was (-)-PE-PS-PC-PVC-ABS-PP-(+). Further, the cyclone charging was more effective and stable than vibrating charging. The impact factors experiments showed that small particle size was better changed than large ones and were more suitable recycled by tribo-electrostatic separation. High relative humidity was identified as impede charging effect. The results of this study will help defining the operating parameters of subsequent separator. Copyright © 2014 Elsevier Ltd. All rights reserved.

  19. Electrostatically controlled micromechanical gyroscope

    Science.gov (United States)

    Hawkey, Timothy (Inventor); Torti, Richard (Inventor); Johnson, Bruce (Inventor)

    1994-01-01

    An integrated electrostatically-controlled micromechanical gyroscope with a rotor encompassed within a rotor cavity and electrostatically spun within the cavity. The gyroscope includes a plurality of axial electrostatic rotor actuators above and below the rotor for controlling the axial and tilt position of the rotor within the cavity, and a plurality of radial electrostatic actuators spaced circumferentially around the rotor for controlling the radial and tilt position of the rotor within the cavity. The position of the rotor within the cavity is then resolved to determine the external forces acting on the rotor.

  20. Embedding beyond electrostatics

    DEFF Research Database (Denmark)

    Nåbo, Lina J.; Olsen, Jógvan Magnus Haugaard; Holmgaard List, Nanna

    2016-01-01

    We study excited states of cholesterol in solution and show that, in this specific case, solute wave-function confinement is the main effect of the solvent. This is rationalized on the basis of the polarizable density embedding scheme, which in addition to polarizable embedding includes non-electrostatic...... repulsion that effectively confines the solute wave function to its cavity. We illustrate how the inclusion of non-electrostatic repulsion results in a successful identification of the intense π → π∗ transition, which was not possible using an embedding method that only includes electrostatics....... This underlines the importance of non-electrostatic repulsion in quantum-mechanical embedding-based methods....

  1. Wind Induced Vibration Control and Energy Harvesting of Electromagnetic Resonant Shunt Tuned Mass-Damper-Inerter for Building Structures

    Directory of Open Access Journals (Sweden)

    Yifan Luo

    2017-01-01

    Full Text Available This paper proposes a novel inerter-based dynamic vibration absorber, namely, electromagnetic resonant shunt tuned mass-damper-inerter (ERS-TMDI. To obtain the performances of the ERS-TMDI, the combined ERS-TMDI and a single degree of freedom system are introduced. H2 criteria performances of the ERS-TMDI are introduced in comparison with the classical tuned mass-damper (TMD, the electromagnetic resonant shunt series TMDs (ERS-TMDs, and series-type double-mass TMDs with the aim to minimize structure damage and simultaneously harvest energy under random wind excitation. The closed form solutions, including the mechanical tuning ratio, the electrical damping ratio, the electrical tuning ratio, and the electromagnetic mechanical coupling coefficient, are obtained. It is shown that the ERS-TMDI is superior to the classical TMD, ERS-TMDs, and series-type double-mass TMDs systems for protection from structure damage. Meanwhile, in the time domain, a case study of Taipei 101 tower is presented to demonstrate the dual functions of vibration suppression and energy harvesting based on the simulation fluctuating wind series, which is generated by the inverse fast Fourier transform method. The effectiveness and robustness of ERS-TMDI in the frequency and time domain are illustrated.

  2. Exploring the possible role of Glu286 in CcO by electrostatic energy computations combined with molecular dynamics.

    Science.gov (United States)

    Woelke, Anna Lena; Galstyan, Gegham; Galstyan, Artur; Meyer, Tim; Heberle, Joachim; Knapp, Ernst-Walter

    2013-10-17

    Cytochrome c oxidase (CcO) is a central enzyme in aerobic life catalyzing the conversion of molecular oxygen to water and utilizing the chemical energy to pump protons and establish an electrochemical gradient. Despite intense research, it is not understood how CcO achieves unidirectional proton transport and avoids short circuiting the proton pump. Within this work, we analyzed the potential role of Glu286 as a proton valve. We performed unconstrained MD simulations of CcO with an explicit membrane for up to 80 ns. Those MD simulations revealed that deprotonated Glu286 (Glu286-) is repelled by the negatively charged propionic acid PRD of heme a3. Thus, it destabilizes a potential linear chain of waters in the hydrophobic cavity connecting Glu286 with PRD and the binuclear center (BNC). Conversely, protonated Glu286 (Glu286H) may remain in an upward position (oriented toward PRD) and can stabilize the connecting linear water chain in the hydrophobic cavity. We calculated the pKa of Glu286 under physiological conditions to be above 12, but this value decreases to about 9 under increased water accessibility of Glu286. The latter value is in accordance with experimental measurements. In the time course of MD simulation, we also observed conformations where Glu286 bridges between water molecules located on both sides (the D channel being connected to the N side and the hydrophobic cavity), which might lead to proton backflow.

  3. Vibrational Excitation of H2 Scattering from Cu(111): Effects of Surface Temperature and of Allowing Energy Exchange with the Surface.

    Science.gov (United States)

    Kroes, Geert-Jan; Juaristi, J I; Alducin, M

    2017-06-29

    In scattering of H2 from Cu(111), vibrational excitation has so far defied an accurate theoretical description. To expose the causes of the large discrepancies with experiment, we investigate how the feature due to vibrational excitation (the "gain peak") in the simulated time-of-flight spectrum of (v = 1, j = 3) H2 scattering from Cu(111) depends on the surface temperature (Ts) and the possibility of energy exchange with surface phonons and electron-hole pairs (ehp's). Quasi-classical dynamics calculations are performed on the basis of accurate semiempirical density functionals for the interaction with H2 + Cu(111). The methods used include the quasi-classical trajectory method within the Born-Oppenheimer static surface model, the generalized Langevin oscillator (GLO) method incorporating energy transfer to surface phonons, the GLO + friction (GLO+F) method also incorporating energy exchange with ehp's, and ab initio molecular dynamics with electronic friction (AIMDEF). Of the quasi-classical methods tested, comparison with AIMDEF suggests that the GLO+F method is accurate enough to describe vibrational excitation as measured in the experiments. The GLO+F calculations also suggest that the promoting effect of raising Ts on the measured vibrational excitation is due to an electronically nonadiabatic mechanism. However, by itself, enabling energy exchange with the surface by modeling surface phonons and ehp's leads to reduced vibrational excitation, further decreasing the agreement with experiment. The simulated gain peak is quite sensitive to energy shifts in calculated vibrational excitation probabilities and to shifts in a specific experimental parameter (the chopper opening time). While the GLO+F calculations allow important qualitative conclusions, comparison to quantum dynamics results suggests that, with the quasi-classical way of describing nuclear motion and the present box quantization method for assigning the final vibrational state, the gain peak is not

  4. Dedicated algorithm and software for the integrated analysis of AC and DC electrical outputs of piezoelectric vibration energy harvesters

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jae Eum [Catholic University of Daegu, Gyeongsan (Korea, Republic of)

    2014-10-15

    DC electrical outputs of a piezoelectric vibration energy harvester by nonlinear rectifying circuitry can hardly be obtained either by any mathematical models developed so far or by finite element analysis. To address the issue, this work used an equivalent electrical circuit model and newly developed an algorithm to efficiently identify relevant circuit parameters of arbitrarily-shaped cantilevered piezoelectric energy harvesters. The developed algorithm was then realized as a dedicated software module by adopting ANSYS finite element analysis software for the parameters identification and the Tcl/Tk programming language for a graphical user interface and linkage with ANSYS. For verifications, various AC electrical outputs by the developed software were compared with those by traditional finite element analysis. DC electrical outputs through rectifying circuitry were also examined for varying values of the smoothing capacitance and load resistance.

  5. Design, Simulation, and Optimization of a Frequency-Tunable Vibration Energy Harvester That Uses a Magnetorheological Elastomer

    Directory of Open Access Journals (Sweden)

    Wan Sun

    2015-01-01

    Full Text Available This study focuses on the design, simulation, and load power optimization for the development of a novel frequency-tunable electromagnetic vibrational energy harvester. The unique characteristic of a magnetorheological elastomer (MRE is utilized, that the shear modulus can be varied by changing the strength of an applied magnetic field. The electromagnetic energy harvester is fabricated, the external electric circuit is connected, and the performance is evaluated through a series of experiments. The resonant frequencies and the parasitic damping constant are measured experimentally for different tuning magnet gap distances, which validate the application of the MRE to the development of a frequency-tunable energy harvesting system. The harvested energy of the system is measured by the voltage across the load resistor. The maximum load power is attained by optimizing the external circuit connected to the coil system. The analysis results are presented for harvesting the maximum load power in terms of the coil parameters and external circuit resistance. The optimality of the load resistance is validated by comparing the analytical results with experimental results. The optimal load resistances under various resonance frequencies are also found for the design and composition of the optimal energy harvesting circuit of the energy harvester system.

  6. Vibration-based energy harvesting with piezoelectrets having high d31 activity

    Science.gov (United States)

    Zhang, X.; Pondrom, P.; Wu, L.; Sessler, G. M.

    2016-05-01

    Sandwiched fluoroethylene propylene films with charged, parallel-tunnel voids between the layers, which exhibit high d31 piezoelectric activity, were designed. Stripes of such piezoelectrets were exposed to mechanical stress in length direction by a seismic mass excited to vibrations. Due to the piezoelectricity of the films, a current in a terminating resistor is generated. The harvested power across the resistor amounts to about 0.2 mW for a seismic mass of 2 g and an acceleration of 1 g. In comparison with other piezoelectret or with poly(vinylidene fluoride) harvesters, the generated power referred to equal acceleration and force, is significantly larger.

  7. Vibration-based energy harvesting with piezoelectrets having high d{sub 31} activity

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, X. [Institute for Telecommunications Technology, Technische Universität Darmstadt, Merckstr. 25, 64283 Darmstadt (Germany); School of Physics Science and Engineering, Tongji University, Siping Road 1239, Shanghai 200092 (China); Pondrom, P. [Institute for Telecommunications Technology, Technische Universität Darmstadt, Merckstr. 25, 64283 Darmstadt (Germany); System Reliability and Machine Acoustics SzM, Technische Universität Darmstadt, Magdalenenstr. 4, 64289 Darmstadt (Germany); Wu, L. [School of Physics Science and Engineering, Tongji University, Siping Road 1239, Shanghai 200092 (China); Sessler, G. M., E-mail: g.sessler@nt.tu-darmstadt.de [Institute for Telecommunications Technology, Technische Universität Darmstadt, Merckstr. 25, 64283 Darmstadt (Germany)

    2016-05-09

    Sandwiched fluoroethylene propylene films with charged, parallel-tunnel voids between the layers, which exhibit high d{sub 31} piezoelectric activity, were designed. Stripes of such piezoelectrets were exposed to mechanical stress in length direction by a seismic mass excited to vibrations. Due to the piezoelectricity of the films, a current in a terminating resistor is generated. The harvested power across the resistor amounts to about 0.2 mW for a seismic mass of 2 g and an acceleration of 1 g. In comparison with other piezoelectret or with poly(vinylidene fluoride) harvesters, the generated power referred to equal acceleration and force, is significantly larger.

  8. Electrostatic Discharge Training Manual

    Science.gov (United States)

    1980-09-01

    NAVSEA SE 003-AA-TRN-OO LEYE V ELECTROSTATIC DISCHARGE TRAINING MANUAL s DTIC ,T OF I!ELECTE, ,4MA 0W\\R 9 981 E PUBLISHED BY DIRECTION OF COMMANDER...LABORATORY-TYPE DETECTORS SHOULD BE USED. IN SUMMARY, CHARACTERIS- TICS TO CONSIDER IN SELECTING AN ELECTROSTATIC DETECTOR ARE: o SENSITIVITY (MINIMUM

  9. Electrostatics in Chemistry

    Indian Academy of Sciences (India)

    For an excellent summary of the field of supramolecular chemistry, readers are referred to the article by J-M Lehn in Resonance, VaLl,. No.3, p.39, 1996. Electrostatics plays an important role in weak intermolecular interactions. The present series is aimed at understanding these electrostatic aspects. This article presents the.

  10. Edutainment Science: Electrostatics

    Science.gov (United States)

    Ahlers, Carl

    2009-01-01

    Electrostatics should find a special place in all primary school science curricula. It is a great learning area that reinforces the basics that underpin electricity and atomic structure. Furthermore, it has many well documented hands-on activities. Unfortunately, the "traditional" electrostatics equipment such as PVC rods, woollen cloths, rabbit…

  11. Electrostatic septum, SPS

    CERN Multimedia

    CERN PhotoLab

    1978-01-01

    To minimize losses during slow extraction towards N- and W-Area, electrostatic septa in long straight sections 2 and 6 precede the magnetic septa. This picture shows such an electrostatic septum in its tank. See 7501120X, 7501199 and 7501201 for more detailed pictures.

  12. Collisionless electrostatic shocks

    DEFF Research Database (Denmark)

    Andersen, H.K.; Andersen, S.A.; Jensen, Vagn Orla

    1970-01-01

    An attempt was made in the laboratory to observe the standing collisionless electrostatic shocks in connection with the bow shock of the earth......An attempt was made in the laboratory to observe the standing collisionless electrostatic shocks in connection with the bow shock of the earth...

  13. The IUPAC Database of Rotational-Vibrational Energy Levels and Transitions of Water Isotopologues from Experiment and Theory

    Science.gov (United States)

    Császár, Attila G.; Furtenbacher, T.; Tennyson, Jonathan; Bernath, Peter F.; Brown, Linda R.; Campargue, Alain; Daumont, Ludovic; Gamache, Robert R.; Hodges, Joseph T.; Naumenko, Olga V.; Polyansky, Oleg L.; Rothman, Laurence S.; Vandaele, Ann Carine; Zobov, Nikolai F.

    2014-06-01

    The results of an IUPAC Task Group formed in 2004 on "A Database of Water Transitions from Experiment and Theory" (Project No. 2004-035-1-100) are presented. Energy levels and recommended labels involving exact and approximate quantum numbers for the main isotopologues of water in the gas phase, H216O, H218O, H217O, HD16O, HD18O, HD17O, D216O, D218O, and D217O, are determined from measured transition wavenumbers. The transition wavenumbers and energy levels are validated using the MARVEL (measured active rotational-vibrational energy levels) approach and first-principles nuclear motion computations. The extensive data, e.g., more than 200,000 transitions have been handled for H216O, including lines and levels that are required for analysis and synthesis of spectra, thermochemical applications, the construction of theoretical models, and the removal of spectral contamination by ubiquitous water lines. These datasets can also be used to assess where measurements are lacking for each isotopologue and to provide accurate frequencies for many yet-to-be measured transitions. The lack of high-quality frequency calibration standards in the near infrared is identified as an issue that has hindered the determination of high-accuracy energy levels at higher frequencies. The generation of spectra using the MARVEL energy levels combined with transition intensities computed using high accuracy ab initio dipole moment surfaces are discussed.

  14. Performance enhancement of a rotational energy harvester utilizing wind-induced vibration of an inclined stay cable

    Science.gov (United States)

    Kim, In-Ho; Jang, Seon-Jun; Jung, Hyung-Jo

    2013-07-01

    In this paper, an innovative strategy for improving the performance of a recently developed rotational energy harvester is proposed. Its performance can be considerably enhanced by replacing the electromagnetic induction part, consisting of moving permanent magnets and a fixed solenoid coil, with a moving mass and a rotational generator (i.e., an electric motor). The proposed system is easily tuned to the natural frequency of a target structure using the position change of a proof mass. Owing to the high efficiency of the rotational generator, the device can more effectively harness electrical energy from the wind-induced vibration of a stay cable. Also, this new configuration makes the device more compact and geometrically tunable. In order to validate the effectiveness of the new configuration, a series of laboratory and field tests are carried out with the prototype of the proposed device, which is designed and fabricated based on the dynamic characteristics of the vibration of a stay cable installed in an in-service cable-stayed bridge. From the field test, it is observed that the normalized output power of the proposed system is 35.67 mW (m s-2)-2, while that of the original device is just 5.47 mW (m s-2)-2. These results show that the proposed device generates much more electrical energy than the original device. Moreover, it is verified that the proposed device can generate sufficient electricity to power a wireless sensor node placed on a cable under gentle-moderate wind conditions.

  15. [Vibrational to rotational energy transfer between CsH (Chi1 Sigma+, nu > or = 15) and CO2].

    Science.gov (United States)

    Dai, Kang; Wang, Shu-Ying; Liu, Jing; Shen, Yi-Fan

    2012-11-01

    The quenching of highly vibrational excited CsH through collisions with a 500 K bath of CO2 was investigated using the laser spectroscopy technique. CsH was formed by the Cs(7P)+H2 reaction. The pulse laser prepared CsH in the highly vibrational levels. Laser induced fluorescence was used to detect collisionally relaxed CsH. The relaxation rate coefficient of CsH (nu" = 21) with CO2 is 10 times larger than that of CsH(nu" = 15). Relaxation of CsH(nu") with H2 was also investigated. The mass effect on the collisional relaxation rate coefficients is strong. The observed collisional relaxation rate coefficients of H2 are bigger than those of CO2. Energy gain into CO2 resulting from collisions with excited CsH was probed using laser overtone spectroscopy technique. Distributions of nascent CO2 rotational population in the ground (00(0)0) state were determined. For CsH excited at nu" = 15, the scattered CO2 molecules have a rotational temperature of T(rot) = (605 +/- 50) K. For excitation at nu" = 21, the CO2 rotational temperature is T(rot) = (780 +/- 70) K. Based on the rotational temperatures, the average change in the CO2 rotational energy has a stronger dependence on the CsH initial energy. Using the ambient cell temperature, nu = 21 -2. 7 nu" = 15 was found. The nascent distributions of recoil velocities for collisions were determined from stimulated absorption line profiles of individual CO2 rotational states. For nu" = 15, scattered CO2 molecules with J = 36-48 have center of mass translational energy of = 600-972 cm(-1). For nu" = 21, the values increase to = 972-1 351 cm(-1). Based on propensity rules for collisions that favor small changes in energy and angular momentum, it is reasonable that low-J CO2 states will have lower translational energy than the high-J states. Extrapolating nu" = 15 and 21 data to the initial relative translational energy of E0 = 520 cm(-1) gives an estimate of the threshold states J(th) = 34 and 24, respectively. The onset of large

  16. Vibrational analysis on the revised potential energy curve of the low-barrier hydrogen bond in photoactive yellow protein.

    Science.gov (United States)

    Kanematsu, Yusuke; Kamikubo, Hironari; Kataoka, Mikio; Tachikawa, Masanori

    2016-01-01

    Photoactive yellow protein (PYP) has a characteristic hydrogen bond (H bond) between p-coumaric acid chromophore and Glu46, whose OH bond length has been observed to be 1.21 Å by the neutron diffraction technique [Proc. Natl. Acad. Sci. 106, 440-4]. Although it has been expected that such a drastic elongation of the OH bond could be caused by the quantum effect of the hydrogen nucleus, previous theoretical computations including the nuclear quantum effect have so far underestimated the bond length by more than 0.07 Å. To elucidate the origin of the difference, we performed a vibrational analysis of the H bond on potential energy curve with O…O distance of 2.47 Å on the equilibrium structure, and that with O…O distance of 2.56 Å on the experimental crystal structure. While the vibrationally averaged OH bond length for equilibrium structure was underestimated, the corresponding value for crystal structure was in reasonable agreement with the corresponding experimental values. The elongation of the O…O distance by the quantum mechanical or thermal fluctuation would be indispensable for the formation of a low-barrier hydrogen bond in PYP.

  17. Vibrational analysis on the revised potential energy curve of the low-barrier hydrogen bond in photoactive yellow protein

    Directory of Open Access Journals (Sweden)

    Yusuke Kanematsu

    2016-01-01

    Full Text Available Photoactive yellow protein (PYP has a characteristic hydrogen bond (H bond between p-coumaric acid chromophore and Glu46, whose OH bond length has been observed to be 1.21 Å by the neutron diffraction technique [Proc. Natl. Acad. Sci. 106, 440–4]. Although it has been expected that such a drastic elongation of the OH bond could be caused by the quantum effect of the hydrogen nucleus, previous theoretical computations including the nuclear quantum effect have so far underestimated the bond length by more than 0.07 Å. To elucidate the origin of the difference, we performed a vibrational analysis of the H bond on potential energy curve with O…O distance of 2.47 Å on the equilibrium structure, and that with O…O distance of 2.56 Å on the experimental crystal structure. While the vibrationally averaged OH bond length for equilibrium structure was underestimated, the corresponding value for crystal structure was in reasonable agreement with the corresponding experimental values. The elongation of the O…O distance by the quantum mechanical or thermal fluctuation would be indispensable for the formation of a low-barrier hydrogen bond in PYP.

  18. Twenty-Eight Orders of Parametric Resonance in a Microelectromechanical Device for Multi-band Vibration Energy Harvesting

    Science.gov (United States)

    Jia, Yu; Du, Sijun; Seshia, Ashwin A.

    2016-01-01

    This paper contends to be the first to report the experimental observation of up to 28 orders of parametric resonance, which has thus far only been envisioned in the theoretical realm. While theory has long predicted the onset of n orders of parametric resonance, previously reported experimental observations have been limited up to about the first 5 orders. This is due to the rapid narrowing nature of the frequency bandwidth of the higher instability intervals, making practical accessibility increasingly more difficult. Here, the authors have experimentally confirmed up to 28 orders of parametric resonance in a micromachined membrane resonator when electrically undamped. While the implication of this finding spans across the vibration dynamics and transducer application spectrum, the particular significance of this work is to broaden the accumulative operational frequency bandwidth of vibration energy harvesting for enabling self-powered microsystems. Up to 5 orders were recorded when driven at 1.0 g of acceleration across a matched load of 70 kΩ. With a natural frequency of 980 Hz, the fundamental mode direct resonance had a −3 dB bandwidth of 55 Hz, in contrast to the 314 Hz for the first order parametric resonance; furthermore, the half power bands of all 5 orders accumulated to 478 Hz. PMID:27445205

  19. Fabrication and Characterization of Planar Spring Based on FR4-PCB for Electrodynamics Vibration Energy Harvesting Application

    Science.gov (United States)

    Sugandi, Gandi; Mambu, Grace A.; Mulyadi, Dadang; Mulyana, Edi

    2017-07-01

    Planar spring as a mechanical resonator is very important in designing an electrodynamic vibration energy harvesting application (EVEH) to generate output power with high efficiency. Generally, component of the mechanical resonator is a cantilever beam that is designed using one cantilever with an inertial mass placed cantilever tip. In this study, a planar spring which has four arms cantilever beam was designed and fabricated using an extra-thin FR4-PCB material with a total thickness of 130 µm. There are four types of planar spring that were designed and fabricated in this research to produce resonant frequencies at about 30, 40, 50 and 60 Hz with 1 mm width cantilever arm and various length of 13.5, 11.2, 9.8 and 8.7 mm, respectively. FR4 resonator is fabricated using technology LASER-cutting in order to obtain results precisely. The resonant frequency generated by the mechanical resonator is characterized using vibrator system with certain acceleration. The resonant frequency of the planar spring was obtained at a frequency where the maximum induced voltage occurs. The resonant frequency generated by each type of planar spring was obtained at 24.81, 34.24, 40.2, and 46.8 Hz with three conditions of acceleration of 0.02, 0.06, and 0,1g (g=9.8 m/s2).

  20. A Spectral Canonical Electrostatic Algorithm

    CERN Document Server

    Webb, Stephen D

    2015-01-01

    Studying single-particle dynamics over many periods of oscillations is a well-understood problem solved using symplectic integration. Such integration schemes derive their update sequence from an approximate Hamiltonian, guaranteeing that the geometric structure of the underlying problem is preserved. Simulating a self-consistent system over many oscillations can introduce numerical artifacts such as grid heating. This unphysical heating stems from using non-symplectic methods on Hamiltonian systems. With this guidance, we derive an electrostatic algorithm using a discrete form of Hamilton's Principle. The resulting algorithm, a gridless spectral electrostatic macroparticle model, does not exhibit the unphysical heating typical of most particle-in-cell methods. We present results of this using a two-body problem as an example of the algorithm's energy- and momentum-conserving properties.

  1. Vibrational Fingerprints of Low-Lying PtnP2n (n = 1–5) Cluster Structures from Global Optimization Based on Density Functional Theory Potential Energy Surfaces

    KAUST Repository

    Jedidi, Abdesslem

    2015-11-13

    Vibrational fingerprints of small PtnP2n (n = 1–5) clusters were computed from their low-lying structures located from a global exploration of their DFT potential energy surfaces with the GSAM code. Five DFT methods were assessed from the CCSD(T) wavenumbers of PtP2 species and CCSD relative energies of Pt2P4 structures. The eight first PtnP2n isomers found are reported. The vibrational computations reveal (i) the absence of clear signatures made by overtone or combination bands due to very weak mechanical and electrical anharmonicities and (ii) some significant and recurrent vibrational fingerprints in correlation with the different PP bonding situations in the PtnP2n structures.

  2. Estimation of Oil Production Rates in Reservoirs Exposed to Focused Vibrational Energy

    KAUST Repository

    Jeong, Chanseok

    2014-01-01

    Elastic wave-based enhanced oil recovery (EOR) is being investigated as a possible EOR method, since strong wave motions within an oil reservoir - induced by earthquakes or artificially generated vibrations - have been reported to improve the production rate of remaining oil from existing oil fields. To date, there are few theoretical studies on estimating how much bypassed oil within an oil reservoir could be mobilized by such vibrational stimulation. To fill this gap, this paper presents a numerical method to estimate the extent to which the bypassed oil is mobilized from low to high permeability reservoir areas, within a heterogeneous reservoir, via wave-induced cross-flow oscillation at the interface between the two reservoir permeability areas. This work uses the finite element method to numerically obtain the pore fluid wave motion within a one-dimensional fluid-saturated porous permeable elastic solid medium embedded in a non-permeable elastic semi-infinite solid. To estimate the net volume of mobilized oil from the low to the high permeability area, a fluid flow hysteresis hypothesis is adopted to describe the behavior at the interface between the two areas. Accordingly, the fluid that is moving from the low to the high permeability areas is assumed to transport a larger volume of oil than the fluid moving in the opposite direction. The numerical experiments were conducted by using a prototype heterogeneous oil reservoir model, subjected to ground surface dynamic loading operating at low frequencies (1 to 50 Hz). The numerical results show that a sizeable amount of oil could be mobilized via the elastic wave stimulation. It is observed that certain wave frequencies are more effective than others in mobilizing the remaining oil. We remark that these amplification frequencies depend on the formation’s elastic properties. This numerical work shows that the wave-based mobilization of the bypassed oil in a heterogeneous oil reservoir is feasible, especially

  3. Nonlinear analysis of a two-degree-of-freedom vibration energy harvester using high order spectral analysis techniques

    Science.gov (United States)

    Nico, V.; Frizzell, R.; Punch, J.

    2017-04-01

    Conventional vibration energy harvesters are generally based on linear mass-spring oscillator models. Major limitations with common designs are their narrow bandwidths and the increase of resonant frequency as the device is scaled down. To overcome these problems, a two-degree-of-freedom nonlinear velocity-amplified energy harvester has been developed. The device comprises two masses, oscillating one inside the other, between four sets of nonlinear magnetic springs. Impacts between the masses allow momentum transfer from the heavier mass to the lighter, providing velocity amplification. This paper studies the nonlinear effects introduced by the presence of magnetic springs, using high order spectral analysis techniques on experimental and simulated data obtained for a range of excitation levels and magnetic spring configurations, which enabled the effective spring constant to be varied. Standard power spectrum analysis only provide limited information on the response of nonlinear systems. Instead, bispectral analysis is used here to provide deeper insight of the complex dynamics of the nonlinear velocity-amplified energy harvester. The analysis allows identification of period-doubling and couplings between modes that could be used to choose geometrical parameters to enhance the bandwidth of the device.

  4. Electrostatic pickup station

    CERN Multimedia

    CERN PhotoLab

    1982-01-01

    Electrostatic pickup station, with 4 interleaved electrodes, to measure beam position in the horizontal and vertical plane. This type is used in the transfer lines leaving the PS (TT2, TT70, TTL2). See also 7904075.

  5. Electrostatic model of semiconductor nanoparticles trapped in ...

    Indian Academy of Sciences (India)

    A simple electrostatic model is applied to study the solvation energy and localization energy to inorganic semiconductor nanocrystallites trapped in polymer and ion conducting ... In the single charge configuration, the dielectric constant of the medium has been identified as the selection criteria for hosting the nanoparticles.

  6. Electrostatic model of semiconductor nanoparticles trapped in ...

    Indian Academy of Sciences (India)

    Abstract. A simple electrostatic model is applied to study the solvation energy and localization energy to inorganic semiconductor nanocrystallites trapped in polymer and ion conducting polymer electrolytes. The effective mass approximation has been applied to the system. In the single charge configuration, the dielectric ...

  7. Theoretical and applied research on bistable dual-piezoelectric-cantilever vibration energy harvesting toward realistic ambience

    Science.gov (United States)

    Gao, Y.; Leng, Y.; Javey, A.; Tan, D.; Liu, J.; Fan, S.; Lai, Z.

    2016-11-01

    Pink noise, which is similar to realistic ambient noise, is normally used to simulate ambience where a piezoelectric energy harvesting system (PEHS) is set up. However, pink noise with standard spectral representation can only be used to simulate excitations assumed to possess constant intensity, whereas realistic ambient noise normally appears with a random spectrum and varying intensity in terms of different locations and time. The output performance of conventional bistable magnetic repulsive energy harvesters is significantly affected by the ambience intensity. Considering this fact, a model bistable dual-piezoelectric-cantilever energy harvester (DPEH) is developed in this study to achieve optimal broadband energy harvesting under a varying-intensity realistic circumstance. We utilized various realistic ambient conditions as excitations to obtain the DPEH energy harvesting performance for theoretical and applied study. The elastically supported PEHS has been proven to be more adaptive to realistic ambience with significant or medium intensity variation, but is less qualified for realistic ambience with constant intensity compared with the rigidly supported PEHS (RPEHS). Fortunately, the dual-piezoelectric-cantilever energy harvesting system is superior to the RPEHS under all circumstances because the dual-piezoelectric cantilevers are efficiently utilized for electromechanical energy conversion to realize optimal energy harvesting.

  8. Vibration energy harvesting in a small channel fluid flow using piezoelectric transducer

    Energy Technology Data Exchange (ETDEWEB)

    Hassan, Md. Mehedi, E-mail: buetmehedi10@gmail.com; Hossain, Md. Yeam, E-mail: yeamhossain@gmail.com; Mazumder, Rakib, E-mail: rakibmazumder46075@gmail.com; Rahman, Roussel, E-mail: roussel.rahman@gmail.com; Rahman, Md. Ashiqur, E-mail: ashiqurrahman@me.buet.ac.bd [Department of Mechanical Engineering, Bangladesh University of Engineering and Technology (BUET), Dhaka-1000 (Bangladesh)

    2016-07-12

    This work is aimed at developing a way to harvest energy from a fluid stream with the application of piezoelectric transducers in a small channel. In this COMSOL Multiphysics based simulation study, it is attempted to harvest energy from the abundant renewable source of energy available in the form of kinetic energy of naturally occurring flow of fluids. The strategy involves harnessing energy from a fluid-actuator through generation of couples, eddies and vortices, resulting from the stagnation and separation of flow around a semi-circular bluff-body attached to a cantilever beam containing a piezoceramic layer. Fluctuation of fluidic pressure impulse on the beam due to vortex shedding and varying lift forces causes the flexible cantilever beam to oscillate in the direction normal to the fluid flow in a periodic manner. The periodic application and release of a mechanical strain upon the beam effected a generation of electric potential within the piezoelectric layer, thus enabling extraction of electrical energy from the kinetic energy of the fluid. The piezoelectric material properties and transducer design are kept unchanged throughout the study, whereas the configuration is tested with different fluids and varying flow characteristics. The size and geometry of the obstructing entity are systematically varied to closely inspect the output from different iterations and for finding the optimum design parameters. The intermittent changes in the generated forces and subsequent variation in the strain on the beam are also monitored to find definitive relationship with the electrical energy output.

  9. Electrostatic Levitator Electrode Layout

    Science.gov (United States)

    1998-01-01

    Schematic of Electrostatic Levitator (ESL) electrodes and controls system. The ESL uses static electricity to suspend an object (about 2-3 mm in diameter) inside a vacuum chamber while a laser heats the sample until it melts. This lets scientists record a wide range of physical properties without the sample contacting the container or any instruments, conditions that would alter the readings. The Electrostatic Levitator is one of several tools used in NASA's microgravity materials science program.

  10. Electrostatic Levitator Layout

    Science.gov (United States)

    1998-01-01

    General oayout of Electrostatic Levitator (ESL). The ESL uses static electricity to suspend an object (about 2-3 mm in diameter) inside a vacuum chamber while a laser heats the sample until it melts. This lets scientists record a wide range of physical properties without the sample contacting the container or any instruments, conditions that would alter the readings. The Electrostatic Levitator is one of several tools used in NASA's microgravity materials science program.

  11. Structure-based sampling and self-correcting machine learning for accurate calculations of potential energy surfaces and vibrational levels

    Science.gov (United States)

    Dral, Pavlo O.; Owens, Alec; Yurchenko, Sergei N.; Thiel, Walter

    2017-06-01

    We present an efficient approach for generating highly accurate molecular potential energy surfaces (PESs) using self-correcting, kernel ridge regression (KRR) based machine learning (ML). We introduce structure-based sampling to automatically assign nuclear configurations from a pre-defined grid to the training and prediction sets, respectively. Accurate high-level ab initio energies are required only for the points in the training set, while the energies for the remaining points are provided by the ML model with negligible computational cost. The proposed sampling procedure is shown to be superior to random sampling and also eliminates the need for training several ML models. Self-correcting machine learning has been implemented such that each additional layer corrects errors from the previous layer. The performance of our approach is demonstrated in a case study on a published high-level ab initio PES of methyl chloride with 44 819 points. The ML model is trained on sets of different sizes and then used to predict the energies for tens of thousands of nuclear configurations within seconds. The resulting datasets are utilized in variational calculations of the vibrational energy levels of CH3Cl. By using both structure-based sampling and self-correction, the size of the training set can be kept small (e.g., 10% of the points) without any significant loss of accuracy. In ab initio rovibrational spectroscopy, it is thus possible to reduce the number of computationally costly electronic structure calculations through structure-based sampling and self-correcting KRR-based machine learning by up to 90%.

  12. New Ro-Vibrational Kinetic Energy Operators using Polyspherical Coordinates for Polyatomic Molecules

    Science.gov (United States)

    Schwenke, David W.; Kwak, Dochan (Technical Monitor)

    2002-01-01

    We illustrate how one can easily derive kinetic energy operators for polyatomic molecules using polyspherical coordinates with very general choices for z-axis embeddings arid angles used to specify relative orientations of internal vectors. Computer algebra is not required.

  13. Theoretical calculations and vibrational potential energy surface of 4-silaspiro(3,3)heptane.

    Science.gov (United States)

    Ocola, Esther J; Medders, Cross; Meinander, Niklas; Laane, Jaan

    2014-04-28

    Theoretical computations have been carried out on 4-silaspiro(3,3)heptane (SSH) in order to calculate its molecular structure and conformational energies. The molecule has two puckered four-membered rings with dihedral angles of 34.2° and a tilt angle of 9.4° between the two rings. Energy calculations were carried out for different conformations of SSH. These results allowed the generation of a two-dimensional ring-puckering potential energy surface (PES) of the form V = a(x1 (4) + x2 (4)) - b(x1 (2) + x2 (2)) + cx1 (2)x2 (2), where x1 and x2 are the ring-puckering coordinates for the two rings. The presence of sufficiently high potential energy barriers prevents the molecule from undergoing pseudorotation. The quantum states, wave functions, and predicted spectra resulting from the PESs were calculated.

  14. Theoretical calculations and vibrational potential energy surface of 4-silaspiro(3,3)heptane

    Science.gov (United States)

    Ocola, Esther J.; Medders, Cross; Meinander, Niklas; Laane, Jaan

    2014-04-01

    Theoretical computations have been carried out on 4-silaspiro(3,3)heptane (SSH) in order to calculate its molecular structure and conformational energies. The molecule has two puckered four-membered rings with dihedral angles of 34.2° and a tilt angle of 9.4° between the two rings. Energy calculations were carried out for different conformations of SSH. These results allowed the generation of a two-dimensional ring-puckering potential energy surface (PES) of the form V = a(x14 + x24) - b(x12 + x22) + cx12x22, where x1 and x2 are the ring-puckering coordinates for the two rings. The presence of sufficiently high potential energy barriers prevents the molecule from undergoing pseudorotation. The quantum states, wave functions, and predicted spectra resulting from the PESs were calculated.

  15. Composite Struts Would Damp Vibrations

    Science.gov (United States)

    Dolgin, Benjamin P.

    1991-01-01

    New design of composite-material (fiber/matrix laminate) struts increases damping of longitudinal vibrations without decreasing longitudinal stiffness or increasing weight significantly. Plies with opposing chevron patterns of fibers convert longitudinal vibrational stresses into shear stresses in intermediate viscoelastic layer, which dissipate vibrational energy. Composite strut stronger than aluminum strut of same weight and stiffness.

  16. Design and fabrication of vibration based energy harvester using microelectromechanical system piezoelectric cantilever for low power applications.

    Science.gov (United States)

    Kim, Moonkeun; Lee, Sang-Kyun; Yang, Yil Suk; Jeong, Jaehwa; Min, Nam Ki; Kwon, Kwang-Ho

    2013-12-01

    We fabricated dual-beam cantilevers on the microelectromechanical system (MEMS) scale with an integrated Si proof mass. A Pb(Zr,Ti)O3 (PZT) cantilever was designed as a mechanical vibration energy-harvesting system for low power applications. The resonant frequency of the multilayer composition cantilevers were simulated using the finite element method (FEM) with parametric analysis carried out in the design process. According to simulations, the resonant frequency, voltage, and average power of a dual-beam cantilever was 69.1 Hz, 113.9 mV, and 0.303 microW, respectively, at optimal resistance and 0.5 g (gravitational acceleration, m/s2). Based on these data, we subsequently fabricated cantilever devices using dual-beam cantilevers. The harvested power density of the dual-beam cantilever compared favorably with the simulation. Experiments revealed the resonant frequency, voltage, and average power density to be 78.7 Hz, 118.5 mV, and 0.34 microW, respectively. The error between the measured and simulated results was about 10%. The maximum average power and power density of the fabricated dual-beam cantilever at 1 g were 0.803 microW and 1322.80 microW cm(-3), respectively. Furthermore, the possibility of a MEMS-scale power source for energy conversion experiments was also tested.

  17. Finite element analysis of vibration-driven electro-active paper energy harvester with experimental verification

    Directory of Open Access Journals (Sweden)

    Zafar Abas

    2015-02-01

    Full Text Available In this research work, a coupled-field finite element model of electro-active paper energy harvester is presented, and the results are verified experimentally. Electro-active paper is a smart form of cellulose coated with electrodes on both sides. A finite element model was developed, and harmonic and transient analyses were performed using a commercial finite element analysis package. Two 80 mm × 50 mm and 100 mm × 50 mm aluminum cantilever benders bonded with electro-active paper were tested to validate the finite element model results. Displacement and voltage generated by the energy harvester at the electrode surfaces were measured. The electro-active paper energy harvesters were excited at their fundamental resonance frequencies by a sinusoidal force located 18 mm from the free end. The voltage obtained from the 80 mm × 50 mm and 100 mm × 50 mm electro-active paper energy harvester finite element model was 3.7 and 7 mV, respectively. Experimental results have shown good agreement with the finite element model. The direct piezoelectric effect of electro-active paper shows potential for a cellulose-based eco-friendly energy harvester.

  18. Vibration attenuation of rotating machines by application of magnetorheological dampers to minimize energy losses in the rotor support

    Science.gov (United States)

    Zapoměl, J.; Ferfecki, P.

    2016-09-01

    A frequently used technological solution for minimization of undesirable effects caused by vibration of rotating machines consists in placing damping devices in the rotor supports. The application of magnetorheological squeeze film dampers enables their optimum performance to be achieved in a wide range of rotating speeds by adapting their damping effect to the current operating conditions. The damping force, which is produced by squeezing the layer of magnetorheological oil, can be controlled by changing magnetic flux passing through the lubricant. The force acting between the rotor and its frame is transmitted through the rolling element bearing, the lubricating layer and the squirrel spring. The loading of the bearing produces a time variable friction moment, energy losses, uneven rotor running, and has an influence on the rotor service life and the current fluctuation in electric circuits. The carried out research consisted in the development of a mathematical model of a magnetorheological squeeze film damper, its implementation into the computational models of rotor systems, and in performing the study on the dependence of the energy losses and variation of the friction moment on the damping force and its control. The new and computationally stable mathematical model of a magnetorheological squeeze film damper, its implementation in the computational models of rigid rotors and learning more on the energy losses generated in the rotor supports in dependence on the damping effect are the principal contributions of this paper. The results of the computational simulations prove that a suitable control of the damping force enables the energy losses to be reduced in a wide velocity range.

  19. Broadband vibration energy harvesting by application of stochastic resonance from rotational environments

    Science.gov (United States)

    Zhang, Y.; Zheng, R.; Kaizuka, T.; Su, D.; Nakano, K.; Cartmell, M. P.

    2015-11-01

    A model for energy harvesting from a rotating automotive tyre is suggested in which the principle of stochastic resonance is advantageously exploited. A bistable response characteristic is obtained by recourse a small harvester comprising a magnetically repellant configuration in which an instrumented cantilever beam can flip between two physical response states when suitably excited by the rotation of a car wheel into which it is fitted. The rotation of the wheel creates a periodic modulation which enables stochastic resonance to take place and as a consequence of this for energy to be harvested from road noise transmitted through the tyre. An optimised mathematical model of the system is presented based on a series of experimental tests and it is shown that a ten-fold increase in harvested energy over a comparable monostable case is feasible. The suggested application for this harvester is to provide electrical power for a tyre pressure monitoring system.

  20. CMOS circuits for electromagnetic vibration transducers interfaces for ultra-low voltage energy harvesting

    CERN Document Server

    Maurath, Dominic

    2015-01-01

    Chip-integrated power management solutions are a must for ultra-low power systems. This enables not only the optimization of innovative sensor applications. It is also essential for integration and miniaturization of energy harvesting supply strategies of portable and autonomous monitoring systems. The book particularly addresses interfaces for energy harvesting, which are the key element to connect micro transducers to energy storage elements. Main features of the book are: - A comprehensive technology and application review, basics on transducer mechanics, fundamental circuit and control design, prototyping and testing, up to sensor system supply and applications. - Novel interfacing concepts - including active rectifiers, MPPT methods for efficient tracking of DC as well as AC sources, and a fully-integrated charge pump for efficient maximum AC power tracking at sub-100µW ultra-low power levels. The chips achieve one of widest presented operational voltage range in standard CMOS technology: 0.44V to over...

  1. A Novel Tunable Multi-Frequency Hybrid Vibration Energy Harvester Using Piezoelectric and Electromagnetic Conversion Mechanisms

    Directory of Open Access Journals (Sweden)

    Zhenlong Xu

    2016-01-01

    Full Text Available This paper presents a novel tunable multi-frequency hybrid energy harvester (HEH. It consists of a piezoelectric energy harvester (PEH and an electromagnetic energy harvester (EMEH, which are coupled with magnetic interaction. An electromechanical coupling model was developed and numerically simulated. The effects of magnetic force, mass ratio, stiffness ratio, and mechanical damping ratios on the output power were investigated. A prototype was fabricated and characterized by experiments. The measured first peak power increases by 16.7% and 833.3% compared with that of the multi-frequency EMEH and the multi-frequency PEH, respectively. It is 2.36 times more than the combined output power of the linear PEH and linear EMEH at 22.6 Hz. The half-power bandwidth for the first peak power is also broadened. Numerical results agree well with the experimental data. It is indicated that magnetic interaction can tune the resonant frequencies. Both magnetic coupling configuration and hybrid conversion mechanism contribute to enhancing the output power and widening the operation bandwidth. The magnitude and direction of magnetic force have significant effects on the performance of the HEH. This proposed HEH is an effective approach to improve the generating performance of the micro-scale energy harvesting devices in low-frequency range.

  2. Theoretical calculations and vibrational potential energy surface of 4-silaspiro(3,3)heptane

    Energy Technology Data Exchange (ETDEWEB)

    Ocola, Esther J.; Medders, Cross; Laane, Jaan, E-mail: laane@mail.chem.tamu.edu [Department of Chemistry, Texas A and M University, College Station, Texas 77843-3255 (United States); Meinander, Niklas [Department of Military Technology, Finnish National Defence University, P.O. Box 7, 00861 Helsinki (Finland)

    2014-04-28

    Theoretical computations have been carried out on 4-silaspiro(3,3)heptane (SSH) in order to calculate its molecular structure and conformational energies. The molecule has two puckered four-membered rings with dihedral angles of 34.2° and a tilt angle of 9.4° between the two rings. Energy calculations were carried out for different conformations of SSH. These results allowed the generation of a two-dimensional ring-puckering potential energy surface (PES) of the form V = a(x{sub 1}{sup 4} + x{sub 2}{sup 4}) – b(x{sub 1}{sup 2} + x{sub 2}{sup 2}) + cx{sub 1}{sup 2}x{sub 2}{sup 2}, where x{sub 1} and x{sub 2} are the ring-puckering coordinates for the two rings. The presence of sufficiently high potential energy barriers prevents the molecule from undergoing pseudorotation. The quantum states, wave functions, and predicted spectra resulting from the PESs were calculated.

  3. Nonlinear dynamics and control strategies: On a energy harvester vibrating system with a linear form to non-ideal motor torquet

    Directory of Open Access Journals (Sweden)

    de Pontes B. R.

    2012-07-01

    Full Text Available In this paper, we deal with the research of a vibrating model of an energy harvester device, including the nonlinearities in the model of the piezoelectric coupling and the non-ideal excitation. We show, using numerical simulations, in the analysis of the dynamic responses, that the harvested power is influenced by non-linear vibrations of the structure. Chaotic behavior was also observed, causing of the loss of energy throughout the simulation time. Using a perturbation technique, we find an approximate analytical solution for the non-ideal system. Then, we apply both two control techniques, to keep the considered system, into a stable condition. Both the State Dependent Ricatti Equation (SDRE control as the feedback control by changing the energy of the oscillator, were efficient in controlling of the considered non-ideal system.

  4. Arch-Shaped triboelectric nanogenerator as a facile device for water-wave vibrational energy

    Science.gov (United States)

    Ko, Young Joon; Kim, Hyun Soo; Jung, Jong Hoon

    2017-11-01

    We report an arch-shaped triboelectric nanogenerator (A-TENG) as for a simple and effective water-wave energy harvesting device. The A-TENG consists of arch-shaped polyethylene terephthalate (PET) polymer film and flat Al metal electrode. Especially, the arch-shape of PET provides an inherent restoring force after the contact with Al; which significantly reduces the weight and volume of the TENG. For a mild mechanical impact of water waves with an amplitude of 5 cm and frequency of 1 Hz, the single A-TENG unit generates an open-circuit voltage of 8 V and closedcircuit current of 200 nA. In addition, two A-TENG units connected in parallel generate almost double the voltage and current. These results imply that the scaled-up A-TENG units could be used at water-breakers in coastal areas for effective harvesting of ocean wave mechanical energy.

  5. Molecular Dynamics Simulation Study on Energy Exchange Between Vibration Modes of a Square Graphene Nanoflake Oscillator.

    Science.gov (United States)

    Lee, Eunae; Kang, Jeong Won; Kim, Ki-Sub; Kwon, Oh-Kuen

    2016-02-01

    Superlubricity in nanoscale graphene structures has been of interest for developing graphene-based nanoelectromechanical systems, as well as for the study of basic mechanical properties. Here, we investigated the translational and rotational motions of a square graphene nanoflake with retracting motions by performing classical molecular dynamics simulations. Our results show that the kinetic energy of the translational motion was exchanged into the kinetic energy of the rotational motion. Thus, square graphene nanoflake oscillators have very low quality factors in translational motions. We discuss that square graphene nanoflakes have great potential to be a core component in nanoelectromechanical systems by detecting their motions with ultrahigh sensitivity to facilitate the development of sensor, memory, and quantum computing.

  6. Energy flow analysis of out-of-plane vibration in coplanar coupled finite Mindlin plates

    Directory of Open Access Journals (Sweden)

    Young-Ho Park

    2015-01-01

    Full Text Available : In this paper, an Energy Flow Analysis (EFA for coplanar coupled Mindlin plates was performed to estimate their dynamic responses at high frequencies. Mindlin plate theory can consider the effects of shear distortion and rotatory inertia, which are very important at high frequencies. For EFA for coplanar coupled Mindlin plates, the wave transmission and reflection relationship for progressing out-of-plane waves (out-of-plane shear wave, bending dominant flexural wave, and shear dominant flexural wave in coplanar coupled Mindlin plates was newly derived. To verify the validity of the EFA results, numerical analyses were performed for various cases where coplanar coupled Mindlin plates are excited by a harmonic point force, and the energy flow solutions for coplanar coupled Mindlin plates were compared with the classical solutions in the various conditions.

  7. Analysis and Modelling towards Hybrid Piezo-Electromagnetic Vibrating Energy Harvesting Devices

    Science.gov (United States)

    Reuschel, Torsten; Salehian, Armaghan

    2011-11-01

    The efficiency of mobile electrical devices increased over the last years. Self-supply by harvesting ambient energy became a possibility of reducing operational costs by ruling out the need of battery replacement. Many energy harvesting devices employ cantilever configurations with base excitation to increase the effective displacement. The proposed design extends this design with an electromagnetic harvesting device (EMH) placed at its tip. It features an alternating stack of magnets with opposing poles and discs of highly permeable material. The composite cylinder is encircled by coils. This EMH design has successfully been employed for ocean wave harvesting and vehicle suspension systems. Its efficiency with respect to mass and energy output is compared to a previously published design using a single magnet placed at the tip moving within a coil. There exists proof that combining readily available technologies into a so-called coupled or hybrid design can increase the efficiency in comparison to respective stand-alone designs. Once the model for the proposed design is derived and evaluated, it is extended by a cantilevered excitation. Piezoelectric layers for hybrid harvesting may be included in future research.

  8. Control between coexistent attractors for optimal performance of a bistable piezoelectric vibration energy harvester

    Science.gov (United States)

    Geiyer, Daniel; Kauffman, Jeffrey L.

    2016-04-01

    Research in broadband nonlinear piezoelectric energy harvesting has gained traction in recent years as resonant, linear harvesters do not operate optimally in dynamic environments. By placing a linear harvester in a symmetric magnetic field, a nonlinear restoring force allows the system to realize motion across two potential wells. Different levels of excitation enable the system to oscillate solely in one potential well, periodically across both potential wells, or aperiodically across both potential wells. Periodic interwell motion is considered desirable for nonlinear energy harvesting systems, however, coexistent attractors inhibit uniqueness of such a solution. The authors have previously shown that chaotic, aperiodic motion between potential wells can be optimized for improved energy harvesting. The technique applied a chaotic controller to stabilize a large amplitude periodic orbit within the chaotic attractor. This work considers the basins of attraction of the two concurrent attractors and applies an intermittent control law in which the system is perturbed from a chaotic, aperiodic interwell response into the desirable large amplitude, periodic, interwell response.

  9. Stochastic resonance energy harvesting for a rotating shaft subject to random and periodic vibrations: influence of potential function asymmetry and frequency sweep

    Science.gov (United States)

    Kim, Hongjip; Che Tai, Wei; Zhou, Shengxi; Zuo, Lei

    2017-11-01

    Stochastic resonance is referred to as a physical phenomenon that is manifest in nonlinear systems whereby a weak periodic signal can be significantly amplified with the aid of inherent noise or vice versa. In this paper, stochastic resonance is considered to harvest energy from two typical vibrations in rotating shafts: random whirl vibration and periodic stick-slip vibration. Stick-slip vibrations impose a constant offset in centrifugal force and distort the potential function of the harvester, leading to potential function asymmetry. A numerical analysis based on a finite element method was conducted to investigate stochastic resonance with potential function asymmetry. Simulation results revealed that a harvester with symmetric potential function generates seven times higher power than that with asymmetric potential function. Furthermore, a frequency-sweep analysis also showed that stochastic resonance has hysteretic behavior, resulting in frequency difference between up-sweep and down-sweep excitations. An electromagnetic energy harvesting system was constructed to experimentally verify the numerical analysis. In contrast to traditional stochastic resonance harvesters, the proposed harvester uses magnetic force to compensate the offset in the centrifugal force. System identification was performed to obtain the parameters needed in the numerical analysis. With the identified parameters, the numerical simulations showed good agreement with the experiment results with around 10% error, which verified the effect of potential function asymmetry and frequency sweep excitation condition on stochastic resonance. Finally, attributed to compensating the centrifugal force offset, the proposed harvester generated nearly three times more open-circuit output voltage than its traditional counterpart.

  10. Electrostatic septum, SPS

    CERN Multimedia

    1975-01-01

    To minimize losses during slow extraction towards N- and W-Areas, electrostatic septa in long straight sections 2 an 6 precede the magnetic septa. The 2 electrode plates, visible at the entrance to the septum, provide a vertical electric field to remove the ions created by the circulating beam in the residual gas. Here we see one of the electrostatic septa being assembled by Faustin Emery (left) and Jacques Soubeyran (right), in the clean room of building 867. See also 7501199, 7501201, 7801286 and further explanations there.

  11. Driving electrostatic transducers

    DEFF Research Database (Denmark)

    Nielsen, Dennis; Knott, Arnold; Andersen, Michael A. E.

    2013-01-01

    depended, nonlinear and high bias voltage for linearization) must be developed. This paper analyzes power stages and bias configurations suitable for driving an electrostatic transducer. Measurement results of a 300 V prototype amplifier are shown. Measuring THD across a high impedance source is discussed......Electrostatic transducers represent a very interesting alternative to the traditional inefficient electrodynamic transducers. In order to establish the full potential of these transducers, power amplifiers which fulfill the strict requirements imposed by such loads (high impedance, frequency......, and a high voltage attenuation interface for an audio analyzer is presented. THD below 0:1% is reported....

  12. Bounds on the vibrational energy that can be harvested from random base motion

    Science.gov (United States)

    Langley, R. S.

    2015-03-01

    This paper is concerned with the development of upper bounds on the energy harvesting performance of a general multi-degree-of-freedom nonlinear electromechanical system that is subjected to random base motion and secondary applied periodic forces. The secondary forces are applied with the aim of enhancing the energy harvested from the base motion, and they may constitute direct excitation, or they may produce parametric terms in the equations of motion. It is shown that when the base motion has white noise acceleration then the power input by the base is always πS0 M / 2 where S0 is the single sided spectral density of the acceleration, and M is the mass of the system. This implies that although the secondary forces may enhance the energy harvested by causing a larger fraction of the power input from the base to be harvested rather than dissipated, there is an upper limit on the power that can be harvested. Attention is then turned to narrow band excitation, and it is found that in the absence of secondary forces a bound can be derived for a single degree of freedom system with linear damping and arbitrary nonlinear stiffness. The upper bound on the power input by the base is πM max [ S (ω) ] / 2, where S (ω) is the single sided base acceleration spectrum. The validity of this result for more general systems is found to be related to the properties of the first Wiener kernel, and this issue is explored analytically and by numerical simulation.

  13. Freezing vibrational energy flow: a fitness function for interchangeable computational and experimental control.

    Science.gov (United States)

    Weidinger, D; Engel, M F; Gruebele, M

    2009-04-23

    We develop a fitness functional for freezing molecular energy flow that relies only on experimental observables. The functional allows us to implement a modular control algorithm where simulation data and experimental data can be used interchangeably. This interchangeability could be useful as a spectroscopic tool and for reactive control because the controllability of the experimental system and its model can be compared directly. The fitness functional performs as well as functionals based on complete knowledge of the wave function. We compare our simulation results with an analytical theory of control, and find good agreement between the simulated and predicted times over which the system can be controlled.

  14. Surface-catalyzed recombination into excited electronic, vibrational, rotational, and kinetic energy states: A review

    Science.gov (United States)

    Kofsky, I. L.; Barrett, J. L.

    1985-01-01

    Laboratory experiments in which recombined CO, CO2, D2O, OH, N2, H2, and O2 molecules desorb from surfaces in excited internal and translational states are briefly reviewed. Unequilibrated distributions predominate from the principally catalytic metal substrates so far investigated. Mean kinetic energies have been observed up to approx. 3x, and in some cases less than, wall-thermal; the velocity distributions generally vary with emission angle, with non-Lambertian particle fluxes. The excitation state populations are found to depend on surface impurities, in an as yet unexplained way.

  15. An energy ratio feature extraction method for optical fiber vibration signal

    Science.gov (United States)

    Sheng, Zhiyong; Zhang, Xinyan; Wang, Yanping; Hou, Weiming; Yang, Dan

    2017-12-01

    The intrusion events in the optical fiber pre-warning system (OFPS) are divided into two types which are harmful intrusion event and harmless interference event. At present, the signal feature extraction methods of these two types of events are usually designed from the view of the time domain. However, the differences of time-domain characteristics for different harmful intrusion events are not obvious, which cannot reflect the diversity of them in detail. We find that the spectrum distribution of different intrusion signals has obvious differences. For this reason, the intrusion signal is transformed into the frequency domain. In this paper, an energy ratio feature extraction method of harmful intrusion event is drawn on. Firstly, the intrusion signals are pre-processed and the power spectral density (PSD) is calculated. Then, the energy ratio of different frequency bands is calculated, and the corresponding feature vector of each type of intrusion event is further formed. The linear discriminant analysis (LDA) classifier is used to identify the harmful intrusion events in the paper. Experimental results show that the algorithm improves the recognition rate of the intrusion signal, and further verifies the feasibility and validity of the algorithm.

  16. Energy Finite Element Analysis for Computing the High Frequency Vibration of the Aluminum Testbed Cylinder and Correlating the Results to Test Data

    Science.gov (United States)

    Vlahopoulos, Nickolas

    2005-01-01

    The Energy Finite Element Analysis (EFEA) is a finite element based computational method for high frequency vibration and acoustic analysis. The EFEA solves with finite elements governing differential equations for energy variables. These equations are developed from wave equations. Recently, an EFEA method for computing high frequency vibration of structures either in vacuum or in contact with a dense fluid has been presented. The presence of fluid loading has been considered through added mass and radiation damping. The EFEA developments were validated by comparing EFEA results to solutions obtained by very dense conventional finite element models and solutions from classical techniques such as statistical energy analysis (SEA) and the modal decomposition method for bodies of revolution. EFEA results have also been compared favorably with test data for the vibration and the radiated noise generated by a large scale submersible vehicle. The primary variable in EFEA is defined as the time averaged over a period and space averaged over a wavelength energy density. A joint matrix computed from the power transmission coefficients is utilized for coupling the energy density variables across any discontinuities, such as change of plate thickness, plate/stiffener junctions etc. When considering the high frequency vibration of a periodically stiffened plate or cylinder, the flexural wavelength is smaller than the interval length between two periodic stiffeners, therefore the stiffener stiffness can not be smeared by computing an equivalent rigidity for the plate or cylinder. The periodic stiffeners must be regarded as coupling components between periodic units. In this paper, Periodic Structure (PS) theory is utilized for computing the coupling joint matrix and for accounting for the periodicity characteristics.

  17. Electrostatics in Chemistry-Electrostatic Models for Weak Molecular ...

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 4; Issue 12. Electrostatics in Chemistry - Electrostatic Models for Weak Molecular Complexation. Shridhar R Gadre Pravin K Babu. Series Article Volume 4 Issue 12 December 1999 pp 11-20 ...

  18. Incident flow effects on the performance of piezoelectric energy harvesters from galloping vibrations

    Directory of Open Access Journals (Sweden)

    Abdessattar Abdelkefi

    2014-01-01

    Full Text Available In this paper, we investigate experimentally the concept of energy harvesting from galloping oscillations with a focus on wake and turbulence effects. The harvester is composed of a unimorph piezoelectric cantilever beam with a square cross-section tip mass. In one case, the harvester is placed in the wake of another galloping harvester with the objective of determining the wake effects on the response of the harvester. In the second case, meshes were placed upstream of the harvester with the objective of investigating the effects of upstream turbulence on the response of the harvester. The results show that both wake effects and upstream turbulence significantly affect the response of the harvester. Depending on the spacing between the two squares and the opening size of the mesh, wake and upstream turbulence can positively enhance the level of the harvested power.

  19. Lead-free piezoelectric transducers for vibration-based energy harvesting devices

    Energy Technology Data Exchange (ETDEWEB)

    Roescher, Mark

    2011-11-15

    Future applications like piezoelectric energy harvesters in addition with increasing environmental awareness ultimately demand novel sophisticated material systems in the field of piezoelectrics as an alternative to the long-established system lead-zirconate-titanate. In this publication state-of-the-art microgenerators have been designed to possess nonlinear Duffing oscillator characteristics. It is shown by measurement and simulation that lead-zirconate-titanate may hence no longer be the first choice in material selection for a piezoelectric microgenerator. Polyvinylidene fluoride has been integrated in a piezoelectric microgenerator and identified as an extraordinarily promising material system for transducer applications being highly insusceptible to stretching induced material failure. Finally, a fundamentally new chemical synthesis approach has been developed for the fabrication of potassium-sodium-niobate films that may also be suitable for other complex oxides.

  20. An asymmetry in electrostatics

    Science.gov (United States)

    Ganci, Salvatore

    2013-11-01

    This paper outlines a misuse of the electrostatic induction concept. A non-symmetrical behaviour was observed in a charge by the induction of an insulated hollow metallic conductor (the Faraday ice pail experiment). The major consequence of this experiment is a quick demonstration that the Earth must have a net negative charge.

  1. Electrostatic shielding of transformers

    Energy Technology Data Exchange (ETDEWEB)

    De Leon, Francisco

    2017-11-28

    Toroidal transformers are currently used only in low-voltage applications. There is no published experience for toroidal transformer design at distribution-level voltages. Toroidal transformers are provided with electrostatic shielding to make possible high voltage applications and withstand the impulse test.

  2. Electrostatic pickup station

    CERN Multimedia

    CERN PhotoLab

    1979-01-01

    Electrostatic pickup station, with 4 electrodes, to measure beam position in the horizontal and vertical plane. This type is used in the transfer lines leaving the PS (TT2, TTL2, TT70). See also 8206063, where the electrode shapes are clearly visible.

  3. Electrostatic septum, SPS

    CERN Multimedia

    CERN PhotoLab

    1975-01-01

    To minimize losses during slow extraction towards N- and W-Area, electrostatic septa in long straight sections 2 and 6 precede the magnetic septa. This picture is a detail of 7501199, and shows the suspension of the wires. 7801286 shows a septum in its tank. See also 7501120X.

  4. Electrostatics in Chemistry

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 4; Issue 2. Electrostatics in Chemistry - Basic Principles. Shridhar R Gadre Pravin K Bhadane. Series Article Volume 4 Issue 2 February 1999 pp 8-19. Fulltext. Click here to view fulltext PDF. Permanent link:

  5. The effect of pi-stacking, h-bonding, and electrostatic interactions on the ionization energies of nucleic acid bases: adenine-adenine, thymine-thymine and adenine-thymine dimers

    Energy Technology Data Exchange (ETDEWEB)

    Bravaya, Ksenia B.; Kostko, Oleg; Ahmed, Musahid; Krylov, Anna I.

    2009-09-02

    A combined theoretical and experimental study of the ionized dimers of thymine and adenine, TT, AA, and AT, is presented. Adiabatic and vertical ionization energies(IEs) for monomers and dimers as well as thresholds for the appearance of the protonated species are reported and analyzed. Non-covalent interactions stronglyaffect the observed IEs. The magnitude and the nature of the effect is different for different isomers of the dimers. The computations reveal that for TT, the largestchanges in vertical IEs (0.4 eV) occur in asymmetric h-bonded and symmetric pi- stacked isomers, whereas in the lowest-energy symmetric h-bonded dimer the shiftin IEs is much smaller (0.1 eV). The origin of the shift and the character of the ionized states is different in asymmetric h-bonded and symmetric stacked isomers. Inthe former, the initial hole is localized on one of the fragments, and the shift is due to the electrostatic stabilization of the positive charge of the ionized fragment by thedipole moment of the neutral fragment. In the latter, the hole is delocalized, and the change in IE is proportional to the overlap of the fragments' MOs. The shifts in AAare much smaller due to a less effcient overlap and a smaller dipole moment. The ionization of the h-bonded dimers results in barrierless (or nearly barrierless) protontransfer, whereas the pi-stacked dimers relax to structures with the hole stabilized by the delocalization or electrostatic interactions.

  6. Characterizing self-excited fluidic energy harvesters subjected to Vortex Induced Vibration by utilizing Griffin scaling

    Science.gov (United States)

    Elvin, Niell; Azadeh Ranjbar, Vahid; Andreopoulos, Yiannis

    2015-11-01

    The present work has experimentally characterized energy harvesters consisting of a circular cylinder mounted at the tip of a flexible cantilever beam. VIV phenomena such as lock-in range, maximum amplitude of transverse oscillation and hysteresis effects have been studied by testing different physical parameters such as structural damping, mass ratio, and aspect ratio. Griffin plot generated by the experimental data of SDOF high aspect ratio circular cylinders have been used to validate VIV. As the harvester is a continuous system of low aspect ratio circular cylinders, three cases have been investigated: low aspect ratio effect of cylinders, effect of multiple modes or coupled transverse-torsional oscillation and non-linear effect due to large deformation of flexible cantilever beams. Griffin plot shows large variance in the case of aspect ratios less than 3. Coupled transverse-torsional oscillation affects VIV negatively. Results show that added structural damping due to piezoelectric patches attached to the cantilever beam decreases electrical power output as a non-linear function of mass ratio. Work supported by National Science Foundation under Grant No. CBET #1033117.

  7. Experimental verification of a bridge-shaped, nonlinear vibration energy harvester

    Energy Technology Data Exchange (ETDEWEB)

    Gafforelli, Giacomo, E-mail: giacomo.gafforelli@polimi.it; Corigliano, Alberto [Department of Civil and Environmental Engineering, Politecnico di Milano, Milano, 20133 (Italy); Xu, Ruize; Kim, Sang-Gook [Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

    2014-11-17

    This paper reports a comprehensive modeling and experimental characterization of a bridge shaped nonlinear energy harvester. A doubly clamped beam at large deflection requires stretching strain in addition to the bending strain to be geometrically compatible, which stiffens the beam as the beam deflects and transforms the dynamics to a nonlinear regime. The Duffing mode non-linear resonance widens the frequency bandwidth significantly at higher frequencies than the linear resonant frequency. The modeling includes a nonlinear measure of strain coupled with piezoelectric constitutive equations which end up in nonlinear coupling terms in the equations of motion. The main result supports that the power generation is bounded by the mechanical damping for both linear and nonlinear harvesters. Modeling also shows the power generation is over a wider bandwidth in the nonlinear case. A prototype is manufactured and tested to measure the power generation at different load resistances and acceleration amplitudes. The prototype shows a nonlinear behavior with well-matched experimental data to the modeling.

  8. Design and fabrication of a PZT cantilever for low frequency vibration energy harvesting.

    Science.gov (United States)

    Kim, Moonkeun; Hwang, Beomseok; Min, Nam Ki; Jeong, Jaehwa; Kwon, Kwang-Ho; Park, Kang-Bak

    2011-07-01

    In this study, a PZT cantilever with a Si proof mass is designed and fabricated for a low frequency energy harvesting application. A mathematical model of a multi-layer composite beam was derived and applied in a parametric analysis of the piezoelectric cantilever. Finally, the dimensions of the cantilever were determined for the resonant frequency of the cantilever. Our cantilever design was based on MATLAB and ANSYS simulations. For this simulation, the proof mass volumes were varied from 0 to 0.5 mm3 and resonant frequencies were calculated from 833.5 Hz to 125.5 Hz, respectively. Based on simulation, we fabricated a device with beam dimensions of about 4.10 mm x 0.48 mm x 0.012 mm, and an integrated Si proof mass with dimensions of about 0.481 mm x 0.48 mm x 0.45 mm. The resonant frequency, maximum peak voltage, and highest average power of the cantilever device were 224.8 Hz, 4.8 mV, and 2.24 nW, respectively.

  9. Electromechanical modeling and experimental analysis of a compression-based piezoelectric vibration energy harvester

    Directory of Open Access Journals (Sweden)

    X.Z. Jiang

    2014-07-01

    Full Text Available Over the past few decades, wireless sensor networks have been widely used in the field of structure health monitoring of civil, mechanical, and aerospace systems. Currently, most wireless sensor networks are battery-powered and it is costly and unsustainable for maintenance because of the requirement for frequent battery replacements. As an attempt to address such issue, this article theoretically and experimentally studies a compression-based piezoelectric energy harvester using a multilayer stack configuration, which is suitable for civil infrastructure system applications where large compressive loads occur, such as heavily vehicular loading acting on pavements. In this article, we firstly present analytical and numerical modeling of the piezoelectric multilayer stack under axial compressive loading, which is based on the linear theory of piezoelectricity. A two-degree-of-freedom electromechanical model, considering both the mechanical and electrical aspects of the proposed harvester, was developed to characterize the harvested electrical power under the external electrical load. Exact closed-form expressions of the electromechanical models have been derived to analyze the mechanical and electrical properties of the proposed harvester. The theoretical analyses are validated through several experiments for a test prototype under harmonic excitations. The test results exhibit very good agreement with the analytical analyses and numerical simulations for a range of resistive loads and input excitation levels.

  10. Micro-molding with ultrasonic vibration energy: new method to disperse nanoclays in polymer matrices.

    Science.gov (United States)

    Planellas, Marc; Sacristán, Matías; Rey, Lorena; Olmo, Cristian; Aymamí, Joan; Casas, María T; del Valle, Luis J; Franco, Lourdes; Puiggalí, Jordi

    2014-07-01

    Ultrasound technology was proved as an efficient processing technique to obtain micro-molded specimens of polylactide (PLA) and polybutylene succinate (PBS), which were selected as examples of biodegradable polyesters widely employed in commodity and specialty applications. Operational parameters such as amplitude, molding force and processing time were successfully optimized to prepare samples with a decrease in the number average molecular weight lower than 6%. Ultrasonic waves also seemed an ideal energy source to provide effective disaggregation of clay silicate layers, and therefore exfoliated nanocomposites. X-ray diffraction patterns of nanocomposites prepared by direct micro-molding of PLA or PBS powder mixtures with natural montmorillonite or different organo-modified clays showed the disappearance of the 001 silicate reflection for specimens having up to 6 wt.% clay content. All electron micrographs revealed relatively homogeneous dispersion and sheet nanostructures oriented in the direction of the melt flow. Incorporation of clay particles during processing had practically no influence on PLA characteristics but enhanced PBS degradation when an organo-modifier was employed. This was in agreement with thermal stability data deduced from thermogravimetric analysis. Cold crystallization experiments directly performed on micro-molded PLA specimens pointed to a complex influence of clay particles reflected by the increase or decrease of the overall non-isothermal crystallization rate when compared to the neat polymer. In all cases, the addition of clay led to a clear decrease in the Avrami exponent. Copyright © 2014 Elsevier B.V. All rights reserved.

  11. The role of proton mobility in determining the energy-resolved vibrational activation/dissociation channels of N-glycopeptide ions

    Energy Technology Data Exchange (ETDEWEB)

    Kolli, Venkata; Roth, Heidi A. [Department of Chemistry, University of Nebraska – Lincoln, Lincoln, NE, 68588-0304 (United States); De La Cruz, Gabriela; Fernando, Ganga S. [Department of Chemistry, University of Nebraska – Lincoln, Lincoln, NE, 68588-0304 (United States); Department of Chemistry, Cottey College, Nevada, MO, 64772 (United States); Dodds, Eric D., E-mail: edodds2@unl.edu [Department of Chemistry, University of Nebraska – Lincoln, Lincoln, NE, 68588-0304 (United States)

    2015-10-08

    Site-specific glycoproteomic analysis largely hinges on the use of tandem mass spectrometry (MS/MS) to identify glycopeptides. Experiments of this type are usually aimed at drawing connections between individual oligosaccharide structures and their specific sites of attachment to the polypeptide chain. These determinations inherently require ion dissociation methods capable of interrogating both the monosaccharide and amino acid connectivity of the glycopeptide. Collision-induced dissociation (CID) shows potential to satisfy this requirement, as the vibrational activation/dissociation of protonated N-glycopeptides has been observed to access cleavage of either glycosidic bonds of the glycan or amide bonds of the peptide in an energy-resolved manner. Nevertheless, the relative energy requirement for these fragmentation pathways varies considerably among analytes. This research addresses the influence of proton mobility on the vibrational energy necessary to achieve either glycan or peptide cleavage in a collection of protonated N-glycopeptide ions. While greater proton mobility of the precursor ion was found to correlate with lower energy requirements for precursor ion depletion and appearance of glycosidic fragments, the vibrational energy deposition necessary for appearance of peptide backbone fragments showed no relation to the precursor ion proton mobility. These results are consistent with observations suggesting that peptide fragments arise from an intermediate fragment which is generally of lower proton mobility than the precursor ion. Such findings have potential to facilitate the rational selection of CID conditions which are best suited to provide either glycan or peptide cleavage products in MS/MS based N-glycoproteomic analysis. - Highlights: • Collision-induced dissociation covers both glycan and peptide connectivity. • Precursor proton mobility predicts collision energy needed for glycan fragmentation. • Collision energy needed for peptide

  12. Nonlinear network model analysis of vibrational energy transfer and localisation in the Fenna-Matthews-Olson complex

    National Research Council Canada - National Science Library

    Sarah E Morgan; Daniel J Cole; Alex W Chin

    2016-01-01

    .... The nonlinear network model (NNM) provides a computationally inexpensive approach to studying vibrational modes at the microscopic level in large protein structures, whilst incorporating anharmonicity in the inter-residue...

  13. Electrostatic adhesion testing of electronic metallizations

    Science.gov (United States)

    Yang, H. S.; Brotzen, F. R.; Callahan, D. L.; Dunn, C. F.

    1997-06-01

    A novel technique is developed to measure quantitatively the adhesion strength of metallizations deposited on substrates such as silicon. Electrostatic adhesion testing employs electrostatic forces to generate delaminating stresses in thin metallic films. The interfacial adhesion strength is readily calculated from the electrode geometry and the applied electrostatic field at failure. Unlike other adhesion tests, this technique does not require any mechanical contact and is virtually independent of the plastic deformation of the film. Furthermore, this test provides direct strength measurements as opposed to work or energy of adhesion measurements obtained by the common peel test. The adhesion strengths of several metallizations (Cu, Al) are characterized using the electrostatic technique. The distribution of stress-at-failure data follows Weibull failure statistics. Field emission scanning electron microscopy reveals that the films are delaminated in a microblister-type mode. It is shown that electrostatic adhesion testing is effective in providing quantitative values for the adhesion strengths and failure probabilities of thin-film metallizations.

  14. Screened Electrostatic Interactions in Molecular Mechanics.

    Science.gov (United States)

    Wang, Bo; Truhlar, Donald G

    2014-10-14

    In a typical application of molecular mechanics (MM), the electrostatic interactions are calculated from parametrized partial atomic charges treated as point charges interacting by radial Coulomb potentials. This does not usually yield accurate electrostatic interactions at van der Waals distances, but this is compensated by additional parametrized terms, for example Lennard-Jones potentials. In the present work, we present a scheme involving radial screened Coulomb potentials that reproduces the accurate electrostatics much more accurately. The screening accounts for charge penetration of one subsystem's charge cloud into that of another subsystem, and it is incorporated into the interaction potential in a way similar to what we proposed in a previous article (J. Chem. Theory Comput. 2010, 6, 3330) for combined quantum mechanical and molecular mechanical (QM/MM) simulations, but the screening parameters are reoptimized for MM. The optimization is carried out with electrostatic-potential-fitted partial atomic charges, but the optimized parameters should be useful with any realistic charge model. In the model we employ, the charge density of an atom is approximated as the sum of a point charge representing the nucleus and inner electrons and a smeared charge representing the outermost electrons; in particular, for all atoms except hydrogens, the smeared charge represents the two outermost electrons in the present model. We find that the charge penetration effect can cause very significant deviations from the popular point-charge model, and by comparison to electrostatic interactions calculated by symmetry-adapted perturbation theory, we find that the present results are considerably more accurate than point-charge electrostatic interactions. The mean unsigned error in electrostatics for a large and diverse data set (192 interaction energies) decreases from 9.2 to 3.3 kcal/mol, and the error in the electrostatics for 10 water dimers decreases from 1.7 to 0.5 kcal

  15. Electrostatic septum, SPS

    CERN Multimedia

    1975-01-01

    To minimize losses during slow extraction towards N- and W-Area, electrostatic septa in long straight section 2 and 6 precede the magnetic septa. The 2 electrode plates, visible at the entrance to the septum, establish a vertical electrical field to remove the ions created by the circulating beam in the residual gas. See 7801286 for such a septum in its tank, and 7501201 for a detailed view of the wire suspension. See also 7501120X.

  16. Electrostatic containerless processing system

    Science.gov (United States)

    Rulison, Aaron J.; Watkins, John L.; Zambrano, Brian

    1997-07-01

    We introduce a materials science tool for investigating refractory solids and melts: the electrostatic containerless processing system (ESCAPES). ESCAPES maintains refractory specimens of materials in a pristine state by levitating and heating them in a vacuum chamber, thereby avoiding the contaminating influences of container walls and ambient gases. ESCAPES is designed for the investigation of thermophysical properties, phase equilibria, metastable phase formation, undercooling and nucleation, time-temperature-transformation diagrams, and other aspects of materials processing. ESCAPES incorporates several design improvements over prior electrostatic levitation technology. It has an informative and responsive computer control system. It has separate light sources for heating and charging, which prevents runaway discharging. Both the heating and charging light sources are narrow band, which allows the use of optical pyrometry and other diagnostics at all times throughout processing. Heat is provided to the levitated specimens by a 50 W Nd:YAG laser operating at 1.064 μm. A deuterium arc lamp charges the specimen through photoelectric emission. ESCAPES can heat metals, ceramics, and semiconductors to temperatures exceeding 2300 K; specimens range in size from 1 to 3 mm diam. This article describes the design, capabilities, and applications of ESCAPES, focusing on improvements over prior electrostatic levitation technology.

  17. A New Approach for Studying Bond Rupture/Closure of a Spiro Benzopyran Photochromic Material: Reactivity Descriptors Derived from Frontier Orbitals and DFT Computed Electrostatic Potential Energy Surface Maps

    Directory of Open Access Journals (Sweden)

    M. S. A. Abdel-Mottaleb

    2016-01-01

    Full Text Available This paper focuses on computations technique within the framework of the TD-DFT theory for studying the relationship between structure-properties of reversible conversion of photochromic materials. Specifically, we report on 1′,3′-dihydro-8-methoxy-1′,3′,3′-trimethyl-6-nitrospiro[2H-1-benzopyran-2,2′-(2H-indole] (SP and its isomers. TD-DFT calculated UV-Vis electronic spectra of the closed and open isomers of this photochromic material are in excellent agreement with the experimental results. Moreover, this paper reports on the results of theoretical investigations of reactivity indices that may govern the conversion between spiropyrans and its isomers. In addition, the solvent and rigidity of the medium significantly control the thermal bleaching of the photogenerated colored isomers and hence the switch ability pattern of the photochromic material. The effect of molecular structure computed by DFT in gas-phase and solvents on Cspiro-O bond length has been shown to correlate with photochromic properties. For this compound, DFT optimized geometry could be used to predict photochromism. Furthermore, in an attempt to predict the driving force for MC → SP, this work explores, for the first time, profitable exploitation of the calculated and visualized mapped electrostatic potential energy surfaces (ESP map. Interestingly, it seems that the electrostatic potential forces over the molecular fragments govern spirobond rupture/closure reactions. Thermodynamically, all-trans-colored isomer (CTT is the most stable merocyanine-like form.

  18. The role of the long-range tail of the potential in O2 + N2 collisional inelastic vibrational energy transfers.

    Science.gov (United States)

    Garcia, Ernesto; Pirani, Fernando; Laganà, Antonio; Martí, Carles

    2017-05-10

    In the study of non-reactive energy transfer between O2 and N2 molecules bearing different vibrationally excited states we have faced the problem of selecting a proper formulation of the interaction. To this end we have compared the values of the related observables computed either on a potential energy surface globally fitted to very large ab initio potential energy values [Varga et al., J. Chem. Phys., 2016, 144, 024310] or on two more traditional ones formulated as a combination of an intra- and inter-molecular model component of the interaction (and based on a different combined use of experimental and ab initio information) [Garcia et al., J. Phys. Chem. A, 2016, 120, 5208] in order to enforce an appropriate modelling of the long-range tail of the potential, crucial for the description of inelastic vibrational energy transfer. A detailed graphical analysis of the potential plus a quantitative analysis of the computed opacity functions, of the state-to-state rate coefficients, of the second virial coefficient and of the integral non-reactive cross section allowed us to conclude that the model formulation of the interaction has to be preferred for non-reactive studies of the O2 + N2 energy transfer processes in thermal and subthermal regimes.

  19. Symbolic derivation of high-order Rayleigh-Schroedinger perturbation energies using computer algebra: Application to vibrational-rotational analysis of diatomic molecules

    Energy Technology Data Exchange (ETDEWEB)

    Herbert, John M. [Kansas State Univ., Manhattan, KS (United States). Dept. of Chemistry

    1997-01-01

    Rayleigh-Schroedinger perturbation theory is an effective and popular tool for describing low-lying vibrational and rotational states of molecules. This method, in conjunction with ab initio techniques for computation of electronic potential energy surfaces, can be used to calculate first-principles molecular vibrational-rotational energies to successive orders of approximation. Because of mathematical complexities, however, such perturbation calculations are rarely extended beyond the second order of approximation, although recent work by Herbert has provided a formula for the nth-order energy correction. This report extends that work and furnishes the remaining theoretical details (including a general formula for the Rayleigh-Schroedinger expansion coefficients) necessary for calculation of energy corrections to arbitrary order. The commercial computer algebra software Mathematica is employed to perform the prohibitively tedious symbolic manipulations necessary for derivation of generalized energy formulae in terms of universal constants, molecular constants, and quantum numbers. As a pedagogical example, a Hamiltonian operator tailored specifically to diatomic molecules is derived, and the perturbation formulae obtained from this Hamiltonian are evaluated for a number of such molecules. This work provides a foundation for future analyses of polyatomic molecules, since it demonstrates that arbitrary-order perturbation theory can successfully be applied with the aid of commercially available computer algebra software.

  20. Innovative Electrostatic Adhesion Technologies

    Science.gov (United States)

    Bryan, Tom; Macleod, Todd; Gagliano, Larry; Williams, Scott; McCoy, Brian

    2015-01-01

    Developing specialized Electro-Static grippers (commercially used in Semiconductor Manufacturing and in package handling) will allow gentle and secure Capture, Soft Docking, and Handling of a wide variety of materials and shapes (such as upper-stages, satellites, arrays, and possibly asteroids) without requiring physical features or cavities for a pincher or probe or using harpoons or nets. Combined with new rigid boom mechanisms or small agile chaser vehicles, flexible, high speed Electro-Static Grippers can enable compliant capture of spinning objects starting from a safe stand-off distance. Electroadhesion (EA) can enable lightweight, ultra-low-power, compliant attachment in space by using an electrostatic force to adhere similar and dissimilar surfaces. A typical EA enabled device is composed of compliant space-rated materials, such as copper-clad polyimide encapsulated by polymers. Attachment is induced by strong electrostatic forces between any substrate material, such as an exterior satellite panel and a compliant EA gripper pad surface. When alternate positive and negative charges are induced in adjacent planar electrodes in an EA surface, the electric fields set up opposite charges on the substrate and cause an electrostatic adhesion between the electrodes and the induced charges on the substrate. Since the electrodes and the polymer are compliant and can conform to uneven or rough surfaces, the electrodes can remain intimately close to the entire surface, enabling high clamping pressures. Clamping pressures of more than 3 N/cm2 in shear can be achieved on a variety of substrates with ultra-low holding power consumption (measured values are less than 20 microW/Newton weight held). A single EA surface geometry can be used to clamp both dielectric and conductive substrates, with slightly different physical mechanisms. Furthermore EA clamping requires no normal force be placed on the substrate, as conventional docking requires. Internally funded research and

  1. The effect of pi-stacking, H-bonding, and electrostatic interactions on the ionization energies of nucleic acid bases: adenine-adenine, thymine-thymine and adenine-thymine dimers.

    Science.gov (United States)

    Bravaya, Ksenia B; Kostko, Oleg; Ahmed, Musahid; Krylov, Anna I

    2010-03-14

    A combined theoretical and experimental study of the ionized dimers of thymine and adenine, TT, AA, and AT, is presented. Experimentally observed and computed adiabatic and vertical ionization energies (IEs) for monomers and dimers as well as thresholds for the appearance of the protonated species are reported and analyzed. Non-covalent interactions strongly affect the observed IEs. The magnitude and the nature of the effect is different for different isomers of the dimers. The computations reveal that for TT, the largest changes in vertical IEs (0.4 eV) relative to the monomer occur in asymmetric H-bonded and symmetric pi-stacked isomers, whereas in the lowest-energy symmetric H-bonded dimer the shift in IEs is much smaller (0.2 eV). The origin of the shift and the character of the ionized states is different in asymmetric H-bonded and symmetric stacked isomers. In the former, the initial hole is localized on one of the fragments, and the shift is due to the electrostatic stabilization of the positive charge of the ionized fragment by the dipole moment of the neutral fragment. In the latter, the hole is delocalized, and the change in IE is proportional to the overlap of the fragments' MOs. Relative to TT, the shifts in AA and AT are much smaller due to a less efficient overlap, smaller dipole of A and the large energy gap between ionized states of A and T monomers in the case of AT dimer. The ionization of the H-bonded dimers results in barrierless (or nearly barrierless) proton transfer, whereas the pi-stacked dimers relax to structures with the hole stabilized by the delocalization or electrostatic interactions.

  2. Simulation study of MEMS piezoelectric vibration energy harvester based on c-axis tilted AlN thin film for performance improvement

    Directory of Open Access Journals (Sweden)

    Lingfeng Kong

    2016-12-01

    Full Text Available In this paper, a MEMS piezoelectric cantilevered vibration energy harvester based on c-axis tilted AlN thin film is investigated. Based on basic piezoelectric equations and static analysis of cantilever beam, the equations for generated energy (E and open circuit voltage (Vo were derived, and simulations were carried out to study the effects of geometry parameters and c-axis tilted angle. Results show that E and Vo of energy harvesters are greatly dependent on c-axis tilted angle and geometry parameters, while the coupling between c-axis tilted angle and geometry parameters is not strong. For a given structure size, E and Vo can be almost simultaneously improved by controlling c-axis tilted angle; compared with the case of normal c-axis angle, E with optimal c-axis tilted angle can be amplified by more than 3 times, and the Vo is amplified by about 2 times. E or Vo could be further improved by geometry parameters, while there is trade-off between them. These results can be used for the design and application of piezoelectric cantilevered vibration energy harvester.

  3. Simulation study of MEMS piezoelectric vibration energy harvester based on c-axis tilted AlN thin film for performance improvement

    Science.gov (United States)

    Kong, Lingfeng; Zhang, Jinhui; Wang, Huiyuan; Ma, Shenglin; Li, Fang; Wang, Qing-Ming; Qin, Lifeng

    2016-12-01

    In this paper, a MEMS piezoelectric cantilevered vibration energy harvester based on c-axis tilted AlN thin film is investigated. Based on basic piezoelectric equations and static analysis of cantilever beam, the equations for generated energy (E) and open circuit voltage (Vo) were derived, and simulations were carried out to study the effects of geometry parameters and c-axis tilted angle. Results show that E and Vo of energy harvesters are greatly dependent on c-axis tilted angle and geometry parameters, while the coupling between c-axis tilted angle and geometry parameters is not strong. For a given structure size, E and Vo can be almost simultaneously improved by controlling c-axis tilted angle; compared with the case of normal c-axis angle, E with optimal c-axis tilted angle can be amplified by more than 3 times, and the Vo is amplified by about 2 times. E or Vo could be further improved by geometry parameters, while there is trade-off between them. These results can be used for the design and application of piezoelectric cantilevered vibration energy harvester.

  4. PREFACE: Electrostatics 2015

    Science.gov (United States)

    Matthews, James

    2015-10-01

    Electrostatics 2015, supported by the Institute of Physics, was held in the Sir James Matthews building at Southampton Solent University, UK between 12th and 16th April 2015. Southampton is a historic city on the South Coast of England with a strong military and maritime history. Southampton is home to two Universities: Solent University, which hosted the conference, and the University of Southampton, where much work is undertaken related to electrostatics. 37 oral and 44 poster presentations were accepted for the conference, and 60 papers were submitted and accepted for the proceedings. The Bill Bright Memorial Lecture was delivered this year by Professor Mark Horenstein from Boston University who was, until recently, Editor-in-Chief of the Journal of Electrostatics. He spoke on The contribution of surface potential to diverse problems in electrostatics and his thorough knowledge of the subject of electrostatics was evident in the presentation. The first session was chaired by the Conference Chair, Dr Keith Davies, whose experience in the field showed through his frequent contributions to the discussions throughout the conference. Hazards and Electrostatic Discharge have formed a strong core to Electrostatics conferences for many years, and this conference contained sessions on both Hazards and on ESD, including an invited talk from Dr Jeremy Smallwood on ESD in Industry - Present and Future. Another strong theme to emerge from this year's programme was Non-Thermal Plasmas, which was covered in two sessions. There were two invited talks on this subject: Professor Masaaki Okubo gave a talk on Development of super-clean diesel engine and combustor using nonthermal plasma hybrid after treatment and Dr David Go presented a talk on Atmospheric-pressure ionization processes: New approaches and applications for plasmas in contact with liquids. A new innovation to the conference this year was the opportunity for conference sponsors to present to the delegates a technical

  5. Vibration based structural health monitoring and the modal strain energy damage index algorithm applied to a composite T-beam

    NARCIS (Netherlands)

    Loendersloot, Richard; Ooijevaar, T.H.; Warnet, Laurent; de Boer, Andries; Akkerman, Remko; Vasques, C.M.A.; Dias Rodrigues, J.

    2011-01-01

    A Finite Element based numerical model for a vibration based damage identification method for a 2.5D composite structure is discussed in this chapter. The linear dynamic response of an intact and a locally delaminated 16-layer unidirectional carbon fibre PEKK reinforced T-beam is analysed. A

  6. Calculating the binding free energies of charged species based on explicit-solvent simulations employing lattice-sum methods: An accurate correction scheme for electrostatic finite-size effects

    Science.gov (United States)

    Rocklin, Gabriel J.; Mobley, David L.; Dill, Ken A.; Hünenberger, Philippe H.

    2013-01-01

    The calculation of a protein-ligand binding free energy based on molecular dynamics (MD) simulations generally relies on a thermodynamic cycle in which the ligand is alchemically inserted into the system, both in the solvated protein and free in solution. The corresponding ligand-insertion free energies are typically calculated in nanoscale computational boxes simulated under periodic boundary conditions and considering electrostatic interactions defined by a periodic lattice-sum. This is distinct from the ideal bulk situation of a system of macroscopic size simulated under non-periodic boundary conditions with Coulombic electrostatic interactions. This discrepancy results in finite-size effects, which affect primarily the charging component of the insertion free energy, are dependent on the box size, and can be large when the ligand bears a net charge, especially if the protein is charged as well. This article investigates finite-size effects on calculated charging free energies using as a test case the binding of the ligand 2-amino-5-methylthiazole (net charge +1 e) to a mutant form of yeast cytochrome c peroxidase in water. Considering different charge isoforms of the protein (net charges −5, 0, +3, or +9 e), either in the absence or the presence of neutralizing counter-ions, and sizes of the cubic computational box (edges ranging from 7.42 to 11.02 nm), the potentially large magnitude of finite-size effects on the raw charging free energies (up to 17.1 kJ mol−1) is demonstrated. Two correction schemes are then proposed to eliminate these effects, a numerical and an analytical one. Both schemes are based on a continuum-electrostatics analysis and require performing Poisson-Boltzmann (PB) calculations on the protein-ligand system. While the numerical scheme requires PB calculations under both non-periodic and periodic boundary conditions, the latter at the box size considered in the MD simulations, the analytical scheme only requires three non-periodic PB

  7. Quantum dynamics of vibrational excitations and vibrational charge ...

    Indian Academy of Sciences (India)

    Quantum dynamics of vibrational excitations and vibrational charge transfer processes in H+ + O2 collisions at collision energy 23 eV ... The Fritz Haber Research Centre and The Department of Physical Chemisry, Hebrew University of Jerusalem, Jerusalem, Israel 91904; Department of Chemistry, Indian Institute of ...

  8. Electrostatic analysis of nanoelectromechanical systems

    Science.gov (United States)

    Xu, Yang

    much stronger screening abilities than semiconducting SWNTs. Our results indicate that it is possible to distinctly identify different ions and also to differentiate between arm-chair and zigzag nanotubes. The TB method is further applied to compute the electrostatic signals generated by DNA segments inside semiconducting single-wall carbon nanotubes. The electrostatic signals indicate that when defective DNA molecules pass through the CNTs, it is possible to identify the number of total base pairs and the relative positions of defective base pairs in DNA chains. Our calculations suggest that it is possible to differentiate Dickerson and hairpin DNA structures by comparing electrical signal patterns. In addition to the multiscale method, we present an ab initio study of electronic properties of graphene flakes and nanoribbons adsorbed on clean and H-passivated (100) silicon surfaces. The graphene electronic properties are not perturbed by the H-passivated Si substrate. In contrast, the interaction between the clean Si surface and graphene can significantly change the bandstructure of graphene. This is caused by the covalent bonding formed by C and surface Si atoms, which changes the pi-band network of the graphene layer. The dispersion curves and density of states calculations show that the bonded Si-C surface states are highly delocalized and located near the Fermi energy. Adsorption energy indicates that the graphene flakes and nanoribbons are stable on clean Si(100) surfaces.

  9. IUPAC critical evaluation of the rotational-vibrational spectra of water vapor, Part III: Energy levels and transition wavenumbers for H216O

    Science.gov (United States)

    Tennyson, Jonathan; Bernath, Peter F.; Brown, Linda R.; Campargue, Alain; Császár, Attila G.; Daumont, Ludovic; Gamache, Robert R.; Hodges, Joseph T.; Naumenko, Olga V.; Polyansky, Oleg L.; Rothman, Laurence S.; Vandaele, Ann Carine; Zobov, Nikolai F.; Al Derzi, Afaf R.; Fábri, Csaba; Fazliev, Alexander Z.; Furtenbacher, Tibor; Gordon, Iouli E.; Lodi, Lorenzo; Mizus, Irina I.

    2013-03-01

    This is the third of a series of articles reporting critically evaluated rotational-vibrational line positions, transition intensities, and energy levels, with associated critically reviewed labels and uncertainties, for all the main isotopologues of water. This paper presents experimental line positions, experimental-quality energy levels, and validated labels for rotational-vibrational transitions of the most abundant isotopologue of water, H216O. The latest version of the MARVEL (Measured Active Rotational-Vibrational Energy Levels) line-inversion procedure is used to determine the rovibrational energy levels of the electronic ground state of H216O from experimentally measured lines, together with their self-consistent uncertainties, for the spectral region up to the first dissociation limit. The spectroscopic network of H216O containstwo components, an ortho (o) and a para (p) one. For o-H216O and p-H216O, experimentally measured, assigned, and labeled transitions were analyzed from more than 100 sources. The measured lines come from one-photon spectra recorded at room temperature in absorption, from hot samples with temperatures up to 3000 K recorded in emission, and from multiresonance excitation spectra which sample levels up to dissociation. The total number of transitions considered is 184 667 of which 182 156 are validated: 68 027 between para states and 114 129 ortho ones. These transitions give rise to 18 486 validated energy levels, of which 10 446 and 8040 belong to o-H216O and p-H216O, respectively. The energy levels, including their labeling with approximate normal-mode and rigid-rotor quantum numbers, have been checked against ones determined from accurate variational nuclear motion computations employing exact kinetic energy operators as well as against previous compilations of energy levels. The extensive list of MARVEL lines and levels obtained are deposited in the supplementary data of this paper, as well as in a distributed information system

  10. Pemodelan dan Analisa Reduksi Respon Getaran Translasi pada Sistem Utama dan Energi Listrik yang Dihasilkan oleh Mekanisme Dynamic Vibration Absorber Metode Cantilever Piezoelectric (CPVA

    Directory of Open Access Journals (Sweden)

    Wahyu Rachma Efendy

    2017-03-01

    Full Text Available Getaran banyak terjadi pada mesin-mesin di industri. Salah satu solusi untuk mereduksi getaran berlebih adalah dengan menambahkan Dynamic Vibration Absorber (DVA. Prinsip kerja dari Dynamic Vibration Absorber adalah penambahan massa absorber dan pegas pada sistem utama. DVA akan mereduksi getaran sistem utama dengan menghasilkan getaran yang arahnya berlawanan dengan arah getar dari sistem utama. Berdasarkan penelitian yang dilakukan oleh Pachpute [1], penggunaan DVA telah terbukti dapat mereduksi getaran dari sistem utama yang dioperasikan di frekuensi natural secara signifikan. Dalam penelitian Tugas Akhir ini telah dirancang sebuah mekanisme alat vibration absorber dan energy harvesting metode Cantilever Piezoelectric Vibration Absorber (CPVA. Sistem utama yang digunakan dalam penelitian ini adalah plat datar yang ditopang oleh empat pegas. Plat tersebut akan menerima gaya eksitasi dari pegas dibawahnya yang dihubungkan dengan massa eksentris pada motor DC. Koefisien pegas yang digunakan untuk menumpu plat datar memiliki nilai yang sama, yaitu sebesar 300 N/m. Sehingga eksitasi yang terjadi pada plat datar hanya ke arah translasi. Pada penelitian ini, dilakukan analisa dengan variasi amplitudo massa eksentris sebesar 0.025 m, 0.030 m, dan 0.035 m. Kecepatan putaran motor sebesar 20.61 rad/s (frekuensi natural, 22.05 rad/s (frekuensi panen, dan 25 rad/s (frekuensi lembah. Sedangkan variasi jumlah cantilever piezoelectric yang digunakan adalah 2600, 2800, dan 3000 buah. Dari simulasi yang telah dilakukan, daya bangkitan dan nilai persentase reduksi terbesar dari CPVA terjadi ketika sistem dioperasikan di frekuensi naturalnya, yaitu sebesar 3.52E-7 watt dan 20.36%. Selain itu, dari simulasi juga didapatkan karakteristik CPVA dengan memvariasikan jumlah piezoelectric, didapatkan rentang jumlah piezoelectric optimum adalah 1400 hingga 2400 buah. Pada rentang tersebut, daya bangkitan dan persentase reduksi perpindahan massa utama terbesar yang

  11. Airborne particle monitoring by electrostatic precipitation

    Science.gov (United States)

    Robinson, J. C.; Stoneback, I. T.

    1977-01-01

    For qualitative analysis of atmospheric particulates by microscopy, the sampling device should preserve the particles in the state existing at the moment of capture. A collector is described that uses electrostatic precipitation to capture and disperse specimens on various substrates for direct insertion into microscopes. Sampling runs in various atmospheres are described. Micrographs are presented to show particle morphology and distribution on the substrates. Chemical identification by X-ray energy probe and electron diffraction is illustrated.

  12. Study of the Vibration Transmission and Path Recognition of an Underground Powerhouse Using Energy Finite Element Method

    Directory of Open Access Journals (Sweden)

    Wei Xu

    2016-01-01

    Full Text Available Taking the underground powerhouse of a pumped storage power station as the engineering background, this study established a 3D finite element model of the main and auxiliary powerhouse and performed the dynamic harmonica calculation for its fluctuating pressure. Based on the power flow theory, the ANSYS Parametric Design Language (APDL procedure was completed to calculate the power transmission in the powerhouse. The law of dominant path recognition was first proposed to assess the structure’s dominant transmission using a numerical solution on nodes in the model. The conductivity of the closed-cell foam that filled the structure’s joints was examined, as were the dynamic transmission features of the rock around and beneath the powerhouse. The results indicated that, as a structural joint filler, closed-cell foam could actively restrict vibration transmission, and the directions of dynamic transmission were mainly perpendicular to and along the river in the foundation rock. Approximately 20 percent of the foundation rock beneath the auxiliary powerhouse was disturbed by the concrete around the spiral case and induced vibrations in the powerhouse’s lower floors. Vibration in the higher floors was derived from downstream rock, and the dynamic transmission effect had a clear advantage along the horizontal direction.

  13. Potentially useful to NLO materials: 4-Chloro-3-(trifluoromethyl)aniline, 4-bromo-3-(trifluoromethyl)aniline and 4-fluoro-3-(trifluoromethyl)aniline are combined experimental and theoretical vibrational analysis

    Science.gov (United States)

    Revathi, B.; Balachandran, V.; Raja, B.; Anitha, K.; Kavimani, M.

    2017-08-01

    Primarily, the vibrational analysis of 4-chloro-3-(trifluoromethyl)aniline, 4-bromo-3-(trifluoromethyl)aniline and 4-fluoro-3-(trifluoromethyl)aniline are studied through an experiment by means that of Fourier Transform-Infrared and Fourier Transform-Raman techniques. The electrons both of donating and withdrawing effects on the structure of aniline and effects of substituent positions on the vibrational spectra of the title molecules in compared with similar reasonably molecules have also been illustrated. The details about hyperconjugation interactions, HOMO-LUMO energy gap, molecular electrostatic potential (MEP) surface analysis and thermodynamic functions are expected with the assistance of theoretical density functional theory computations.

  14. Improved methods for Feynman path integral calculations and their application to calculate converged vibrational-rotational partition functions, free energies, enthalpies, entropies, and heat capacities for methane.

    Science.gov (United States)

    Mielke, Steven L; Truhlar, Donald G

    2015-01-28

    We present an improved version of our "path-by-path" enhanced same path extrapolation scheme for Feynman path integral (FPI) calculations that permits rapid convergence with discretization errors ranging from O(P(-6)) to O(P(-12)), where P is the number of path discretization points. We also present two extensions of our importance sampling and stratified sampling schemes for calculating vibrational-rotational partition functions by the FPI method. The first is the use of importance functions for dihedral angles between sets of generalized Jacobi coordinate vectors. The second is an extension of our stratification scheme to allow some strata to be defined based only on coordinate information while other strata are defined based on both the geometry and the energy of the centroid of the Feynman path. These enhanced methods are applied to calculate converged partition functions by FPI methods, and these results are compared to ones obtained earlier by vibrational configuration interaction (VCI) calculations, both calculations being for the Jordan-Gilbert potential energy surface. The earlier VCI calculations are found to agree well (within ∼1.5%) with the new benchmarks. The FPI partition functions presented here are estimated to be converged to within a 2σ statistical uncertainty of between 0.04% and 0.07% for the given potential energy surface for temperatures in the range 300-3000 K and are the most accurately converged partition functions for a given potential energy surface for any molecule with five or more atoms. We also tabulate free energies, enthalpies, entropies, and heat capacities.

  15. Monitoring vibrations

    Energy Technology Data Exchange (ETDEWEB)

    Tiryaki, B. [Hacettepe University (Turkey). Dept. of Mining Engineering

    2003-12-01

    The paper examines the prediction and optimisation of machine vibrations in longwall shearers. Underground studies were carried out at the Middle Anatolian Lignite Mine, between 1993 and 1997. Several shearer drums with different pick lacing arrangements were designed and tested on double-ended ranging longwall shearers employed at the mine. A computer program called the Vibration Analysis Program (VAP) was developed for analysing machine vibrations in longwall shearers. Shearer drums that were tested underground, as well as some provided by leading manufacturers, were analyzed using these programs. The results of the experiments and computer analyses are given in the article. 4 refs., 9 figs.

  16. Electrostatic forces on charged surfaces of bilayer lipid membranes

    OpenAIRE

    Mikucki, Michael; Zhou, Y. C.

    2013-01-01

    Simulating protein-membrane interactions is an important and dynamic area of research. A proper definition of electrostatic forces on membrane surfaces is necessary for developing electromechanical models of protein-membrane interactions. Here we modeled the bilayer membrane as a continuum with general continuous distributions of lipids charges on membrane surfaces. A new electrostatic potential energy functional was then defined for this solvated protein-membrane system. We investigated the ...

  17. Theoretical structural and vibrational study of 5-trifluoromethyluracil. A comparison with uracil

    Energy Technology Data Exchange (ETDEWEB)

    Rudyk, Roxana; Ramos, María E.; Checa, María A.; Brandán, Silvia A. [Cátedra de Química General, Instituto de Química Inorgánica, Facultad de Bioquímica, Química y Farmacia, Universidad Nacional de Tucumán, Ayacucho 471,(4000), San Miguel de Tucumán, Tucum and #x00E1 (Argentina); Chamorro, Eduardo E. [Facultad de Ciencias Exactas, Universidad Andrés Bello, Avda. República 275, 8370146, Santiago (Chile)

    2014-10-06

    In the present work, a comparative study on the structural and vibrational properties of the 5-trifluoromethyluracil (TFMU) derivative with those corresponding to uracil in gas and aqueous solution phases was performed combining the available H{sup 1}-NMR, C{sup 13}-NMR, F{sup 19}-NMR and FTIR spectra with Density Functional Theory (DFT) calculations. Three stable conformers were theoretically determined in both media by using the hybrid B3LYP/6-31G* method. The solvent effects were simulated by means of the self-consistent reaction field (SCRF) method employing the integral equation formalism variant (IEFPCM). Complete assignments of the vibrational spectra in both phases were performed combining the internal coordinates analysis and the DFT calculations with the Scaled Quantum Mechanics Force Field (SQMFF) methodology. The atomic charges, bond orders, solvation energies, dipole moments, molecular electrostatic potentials and force constants parameters were calculated for the three conformers of TFMU in gas phase and aqueous solution.

  18. Vibrational and theoretical studies of a sesquiterpene lactone, 11αH-dihydrozaluzanin E

    Science.gov (United States)

    Molina, José R.; Finetti, Mariela; Díaz, Oscar J.; de la Fuente, Juana R.; Jubert, Alicia

    2008-03-01

    Infrared vibrational spectrum of 11αH-dihydrozaluzanin E has been measured at room temperature and it was analyzed theoretically by means of ab initio calculations. The conformational space of the compound has been scanned using molecular dynamics and complemented with functional density calculations that optimize the geometry of the lowest-energy conformers of each species as obtained in the simulations. The vibrational frequencies were assigned using functional density calculations. The Molecular Electrostatic Potential Map (MEP) was obtained and analyzed. Coupling constants were calculated at ab initio level and by means of the Karplus-Calculator method and via the MestRe-J Program, chemical shifts were also calculated at ab initio level and all the results were compared with respect to experimental data. Conclusions are reported on the stereochemistry of the molecule.

  19. Quantum chemical density functional theory studies on the molecular structure and vibrational spectra of mannitol

    Science.gov (United States)

    Moorthi, P. P.; Gunasekaran, S.; Swaminathan, S.; Ramkumaar, G. R.

    2015-02-01

    A collective experimental and theoretical study was conducted on the molecular structure and vibrational spectra of mannitol. The FT-IR and FT-Raman spectra of mannitol were recorded in the solid phase. The molecular geometry, vibrational frequencies, thermodynamic functions and atomic charges of mannitol in the ground state have been calculated by using the ab initio HF (Hartree-Fock) and density functional methods (B3LYP) invoking cc-pVDZ basis set. The complete vibrational assignments were performed on the basis of Total Energy Distribution (TED) of the vibrational modes. The UV absorption spectra of the title compound dissolved in water. Natural bond orbital analysis has been carried out to explain the charge transfer or delocalization of charge due to the intra-molecular interactions. The 1H and 13C nuclear magnetic resonance (NMR) chemical shifts of the molecule were calculated by GIAO methods. The first order hyperpolarizability (β0) of this novel molecular system and related properties (β, α0 and Δα) of mannitol are calculated using B3LYP/cc-pVDZ and HF/cc-pVDZ methods on the finite-field approach. By using TD-DFT calculation, electronic absorption spectra of the title compound have been predicted and a good agreement with experimental one is established. In addition, the molecular electrostatic potential (MEP) have been investigated using theoretical calculations, the calculated HOMO and LUMO energies shows that the charge transfer within the molecule.

  20. ELECTROSTATICALLY ENHANCED BARRIER FILTER COLLECTION

    Energy Technology Data Exchange (ETDEWEB)

    John Erjavec; Michael D. Mann; Ryan Z. Knutson; Michael L. Swanson; Michael E. Collings

    2003-06-01

    This work was performed through the University of North Dakota (UND) Chemical Engineering Department with assistance from UND's Energy & Environmental Research Center. This research was undertaken in response to the U.S. Department of Energy Federal Technology Center Program Solicitation No. DE-PS26-99FT40479, Support of Advanced Coal Research at U.S. Universities and Colleges. Specifically, this research was in support of the UCR Core Program and addressees Topic 1, Improved Hot-Gas Contaminant and Particulate Removal Techniques, introducing an advanced design for particulate removal. Integrated gasification combined cycle (IGCC) offers the potential for very high efficiency and clean electric generation. In IGCC, the product gas from the gasifier needs to be cleaned of particulate matter to avoid erosion and high-temperature corrosion difficulties arising with the turbine blades. Current methods involve cooling the gases to {approx}100 C to condense alkalis and remove sulfur and particulates using conventional scrubber technology. This ''cool'' gas is then directed to a turbine for electric generation. While IGCC has the potential to reach efficiencies of over 50%, the current need to cool the product gas for cleaning prior to firing it in a turbine is keeping IGCC from reaching its full potential. The objective of the current project was to develop a highly reliable particulate collector system that can meet the most stringent turbine requirements and emission standards, can operate at temperatures above 1500 F, is applicable for use with all U.S. coals, is compatible with various sorbent injection schemes for sulfur and alkali control, can be integrated into a variety of configurations for both pressurized gasification and combustion, increases allowable face velocity to reduce filter system capital cost, and is cost-competitive with existing technologies. The collector being developed is a new concept in particulate control called