Energy Technology Data Exchange (ETDEWEB)
Takebe, Shinichi; Abe, Masayoshi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment
2001-03-01
The distribution coefficient is very important parameter for environmental impact assessment on the disposal of radioactive waste arising from research institutes. The literature survey in the country was mainly carried out for the purpose of selecting the reasonable distribution coefficient value on the utilization of this value in the safety evaluation. This report was arranged much informations on the distribution coefficient for inputting to the database for each literature, and was summarized as a literature information data on the distribution coefficient. (author)
Hydrazoic acid distribution coefficients in Purex processing
Energy Technology Data Exchange (ETDEWEB)
Kelmers, A.D.; Browning, D.N.
1977-01-01
Mixtures of hydroxylamine nitrate and hydrazine are being considered for the reductive stripping of plutonium during Purex processing. The hydrazine functions as a holding reductant for plutonium(III) by destroying nitrous acid via the fast reaction N/sub 2/H/sub 4/ + HNO/sub 2/ ..-->.. HN/sub 3/ + 2H/sub 2/O which leads to the stoichiometric formation of hydrazoic acid. We have measured the distribution coefficients for hydrazoic acid between nitric acid solutions and tributylphosphate-dodecane solutions. Values in the range of 1 to 10 were obtained under typical Purex process conditions. This indicates that most of the hydrazoic acid will be present in the organic phase leaving the plutonium stripping contactors. The distribution coefficients can be expressed as log(E O/A) = n log(Free TBP) + log K' where K' is 7.0, 10.0, 5.1 and 4.7, respectively, at 25, 35, 45 and 55/sup 0/C; and the corresponding values of n are 1.11, 1.27, 0.97 and 1.20.
Sedimentation coefficient distributions of large particles.
Schuck, Peter
2016-07-21
The spatial and temporal evolution of concentration boundaries in sedimentation velocity analytical ultracentrifugation reports on the size distribution of particles with high hydrodynamic resolution. For large particles such as large protein complexes, fibrils, viral particles, or nanoparticles, sedimentation conditions usually allow migration from diffusion to be neglected relative to sedimentation. In this case, the shape of the sedimentation boundaries of polydisperse mixtures relates directly to the underlying size-distributions. Integral and derivative methods for calculating sedimentation coefficient distributions g*(s) of large particles from experimental boundary profiles have been developed previously, and are recapitulated here in a common theoretical framework. This leads to a previously unrecognized relationship between g*(s) and the time-derivative of concentration profiles. Of closed analytical form, it is analogous to the well-known Bridgman relationship for the radial derivative. It provides a quantitative description of the effect of substituting the time-derivative by scan differences with finite time intervals, which appears as a skewed box average of the true distribution. This helps to theoretically clarify the differences between results from time-derivative method and the approach of directly fitting the integral definition of g*(s) to the entirety of experimental boundary data.
EXACT SAMPLING DISTRIBUTION OF SAMPLE COEFFICIENT OF VARIATION
Dr.G.S.David Sam Jayakumar; A.Sulthan
2015-01-01
This paper proposes the sampling distribution of sample coefficient of variation from the normal population. We have derived the relationship between the sample coefficient of variation, standard normal and chi-square variate. We have derived density function of the sample coefficient of variation in terms of the confluent hyper-geometric distribution. Moreover, the first two moments of the distribution are derived and we have proved that the sample coefficient of variation (cv...
Coefficient Omega Bootstrap Confidence Intervals: Nonnormal Distributions
Padilla, Miguel A.; Divers, Jasmin
2013-01-01
The performance of the normal theory bootstrap (NTB), the percentile bootstrap (PB), and the bias-corrected and accelerated (BCa) bootstrap confidence intervals (CIs) for coefficient omega was assessed through a Monte Carlo simulation under conditions not previously investigated. Of particular interests were nonnormal Likert-type and binary items.…
Pourmand, Ali; Dauphas, Nicolas
2010-05-15
Batch equilibration experiments are conducted to measure the distribution coefficients (K(d)) of a large number of elements in nitric, nitric plus hydrofluoric, and hydrochloric acids on Eichrom TODGA extraction chromatography resin. The K(d)s are used to devise a multi-element extraction scheme for high-precision elemental and isotopic analyses of Ca, Hf, Lu, Th and U in geological materials, using high-purity lithium metaborate (LiBO(2)) flux fusion that allows rapid digestion of even the most refractory materials. The fusion melt, dissolved in nitric acid, is directly loaded to a TODGA cartridge on a vacuum chamber for elemental separation. An Ln-Spec cartridge is used in tandem with TODGA for Lu purification. The entire procedure, from flux digestion to preparation for isotopic analysis, can be completed in a day. The accuracy of the proposed technique is tested by measuring the concentrations of Ca (standard bracketing), Hf, Lu, Th and U (isotope dilution), and the isotopic composition of Hf in geostandards (USNM3529, BCR-2, BHVO-1, AGV-1 and AGV-2). All measurements are in excellent agreement with recommended literature values, demonstrating the effectiveness of the proposed analytical procedure and the versatility of TODGA resin.
Coefficient of variation calculated from the range for skewed distributions.
Rhiel, G Steven
2006-02-01
In this research a coefficient of variation (CVS(high.low)) is developed that is calculated from the highest and lowest values in a set of data for samples from skewed distributions. A correction factor is determined such that CVS(high-low) is a dose estimate of the population coefficient of variation when sampling from three skewed chi-squared distributions and three skewed empirical distributions. The empirical distributions are from "real-world" data sets in psychology and education.
EXACT SAMPLING DISTRIBUTION OF SAMPLE COEFFICIENT OF VARIATION
Directory of Open Access Journals (Sweden)
Dr.G.S.David Sam Jayakumar
2015-06-01
Full Text Available This paper proposes the sampling distribution of sample coefficient of variation from the normal population. We have derived the relationship between the sample coefficient of variation, standard normal and chi-square variate. We have derived density function of the sample coefficient of variation in terms of the confluent hyper-geometric distribution. Moreover, the first two moments of the distribution are derived and we have proved that the sample coefficient of variation (cv is the biased estimator of the population coefficient of variation (CV. Moreover, the shape of the density function of sample co-efficient of variation is also visualized and the critical points of sample (cv at 5% and 1% level of significance for different sample sizes have also been computed.
Isolation of endophyic bacteria from purwoceng (Pimpinella alpina Kds.
Directory of Open Access Journals (Sweden)
Tri Widayat
2012-09-01
Full Text Available AbstrakLatar belakang: Purwoceng (Pimpinella alpina Kds. merupakan tanaman obat langka yang berkhasiat sebagai afrodisiak. Tanaman yang mengandung kumarin tersebut berinteraksi dengan bakteri endofi t. Senyawa kumarin dalam industri dimanfaatkan untuk bahan aditif makanan dan parfum. Penelitian ini bertujuan untuk mendapatkan bakteri endofi t dari tanaman purwoceng, menganalisis kemampuan tumbuh bakteri endofi t dalam medium yang mengandung kumarin, dan pengaruh bakteri tersebut terhadap jumlah kumarin dalam medium pertumbuhan.Metode: Isolasi bakteri endofi t dilakukan secara langsung dari akar dan daun purwoceng. Seleksi bakteri endofi t penghasil kumarin dilakukan berdasarkan kemampuan bertahan hidup pada medium cair ammoniumsalt sugar (ASS yang mengandung infusa herba purwoceng. Pengaruh bakteri terhadap jumlah kumarin di dalam medium pertumbuhan diuji melalui percobaan kultivasi isolat bakteri terpilih pada medium yang sama. Jumlah kumarin dalam kultur dideteksi menggunakan teknik kromatografi lapis tipis (KLT.Hasil: Sembilan isolat bakteri endofi t yang berhasil diisolasi dari akar dan daun tanaman purwoceng mampu bertahan hidup pada medium basal yang diberi infusa herba purwoceng dengan waktu generasi (g 2,7-5,07jam dan kecepatan pertumbuhan spesifi k (μ 0,14-0,26/jam. Kultivasi isolat terpilih menunjukkan bahwa BAP5 menghasilkan senyawa dengan Rf 0,27 yang diduga sebagai turunan kumarin. Bakteri BAP5 mampu tumbuh dengan jumlah kumarin 1072 arbitrary unit (AU dalam medium.Kesimpulan: Bakteri endofi t dapat diisolasi dari tanaman purwoceng dan secara in vitro mampu mempertahankan jumlah kumarin yang terkandung di dalam medium. (Health Science Indones 2012;1:31-6Kata kunci: bakteri endofi t, purwoceng, Pimpinella alpina Kds, kumarinAbstractBackground: Purwoceng (Pimpinella alpina Kds. is a medicinal plant species used as aphrodisiac. Like any other plants, the coumarin containing plant probably interacts with endophytic bacteria. Coumarin
Confidence bounds for normal and lognormal distribution coefficients of variation
Steve Verrill
2003-01-01
This paper compares the so-called exact approach for obtaining confidence intervals on normal distribution coefficients of variation to approximate methods. Approximate approaches were found to perform less well than the exact approach for large coefficients of variation and small sample sizes. Web-based computer programs are described for calculating confidence...
Distributing Correlation Coefficients of Linear Structure-Activity/Property Models
Directory of Open Access Journals (Sweden)
Sorana D. BOLBOACA
2011-12-01
Full Text Available Quantitative structure-activity/property relationships are mathematical relationships linking chemical structure and activity/property in a quantitative manner. These in silico approaches are frequently used to reduce animal testing and risk-assessment, as well as to increase time- and cost-effectiveness in characterization and identification of active compounds. The aim of our study was to investigate the pattern of correlation coefficients distribution associated to simple linear relationships linking the compounds structure with their activities. A set of the most common ordnance compounds found at naval facilities with a limited data set with a range of toxicities on aquatic ecosystem and a set of seven properties was studied. Statistically significant models were selected and investigated. The probability density function of the correlation coefficients was investigated using a series of possible continuous distribution laws. Almost 48% of the correlation coefficients proved fit Beta distribution, 40% fit Generalized Pareto distribution, and 12% fit Pert distribution.
SKEWNESS OF RETURN DISTRIBUTION AND COEFFICIENT OF RISK PREMIUM
Institute of Scientific and Technical Information of China (English)
Fenghua WEN; Xiaoguang YANG
2009-01-01
The skewness of the return distribution is one of the important features of the security price. In this paper, the authors try to explore the relationship between the skewness and the coefficient of risk premium. The coefficient of the risk premium is estimated by a GARCH-M model, and the robust measurement of skewness is calculated by Groeneveld-Meeden method. The empirical evidences for the composite indexes from 33 securities markets in the world indicate that the risk compensation requirement in the market where the return distribution is positively skewed is virtually zero, and the risk compensation requirement is positive in a significant level in the market where the return distribution is negative skewed. Moreover, the skewness is negatively correlated with the coefficient of the risk premium.
The transmission coefficient distribution of highly scattering sparse random media
Jin, Curtis; Nadakuditi, Raj Rao; Michielssen, Eric
2015-01-01
We consider the distribution of the transmission coefficients, i.e. the singular values of the modal transmission matrix, for 2D random media with periodic boundary conditions composed of a large number of point-like non-absorbing scatterers. The scatterers are placed at random locations in the medium and have random refractive indices that are drawn from an arbitrary, known distribution. We construct a randomized model for the scattering matrix that retains scatterer dependent properties ess...
Multilayer electromechanical composites with controlled piezelectric coefficient distribution
Vartuli, James S.; Milius, David L.; Li, Xiaoping; Shih, Wan Y.; Shih, Wei-Heng; Prud'homme, Robert K.; Aksay, Ilhan A.
1997-02-01
We have fabricated multilayer electromechanical composites with controlled piezoelectric coefficient distributions using tape casting. Tapes of doped lead zirconate titanate were cut and stacked in accordance with their characteristic electromechanical coupling values and modulus of elasticity. This technique is an extremely versatile method to fabricate displacement actuators to fabricate monolithic ceramic parts with controlled material property gradients. To obtain a quantifiable method to optimize this type of transducer, we have devised a processing model. Given the functional distribution of the electromechanical coupling coefficient, d31, and the functional distribution of elastic modulus through the thickness of the transducer, the analysis predicts the displacement as a function of loading. The tape casting method coupled with the model provides an actuator that maximizes displacement and generated force for the given material properties.
Occupancy distributions in Markov chains via Doeblin's ergodicity coefficient
Chestnut, Stephen
2010-01-01
We apply Doeblin's ergodicity coefficient as a computational tool to approximate the occupancy distribution of a set of states in a homogeneous but possibly non-stationary finite Markov chain. Our approximation is based on new properties satisfied by this coefficient, which allow us to approximate a chain of duration n by independent and short-lived realizations of an auxiliary homogeneous Markov chain of duration of order ln(n). Our approximation may be particularly useful when exact calculations via first-step methods or transfer matrices are impractical, and asymptotic approximations may not be yet reliable. Our findings may find applications to pattern problems in Markovian and non-Markovian sequences that are treatable via embedding techniques.
COMPRESSIBILITY EFFECTS ON DISTRIBUTIONS OF PRESSURE AND LIFT COEFFICIENTS
Directory of Open Access Journals (Sweden)
AZZEDINE NAHOUI
2015-06-01
Full Text Available Reduce energy consumption of airplanes, or enhance the aerodynamic performance of compressors and turbines by reducing drag, or increasing lift is a major challenge for many institutions specializing in aerodynamics [1, 2]. One way to achievethis, isconsidered the study of compressible potential flow compared to incompressible potential flow [3], Outside the boundary layer, to study the effects of compressibility and the control parameters. And the pressure coefficient and lift distributions around the NACA 0012 profile, NACA 0015 and NACA 0018 were studied and presented in terms of the Mach number, angle of attack and the relative thickness of the profiles.
Acetylated Lysozyme as Impurity in Lysozyme Crystals: Constant Distribution Coefficient
Thomas, B. R.; Chernov, A. A.
2000-01-01
Hen egg white lysozyme (HEWL) was acetylated to modify molecular charge keeping the molecular size and weight nearly constant. Two derivatives, A and B, more and less acetylated, respectively, were obtained, separated, purified and added to the solution from which crystals of tetragonal HEWL crystals were grown. Amounts of the A or B impurities added were 0.76, 0.38 and 0.1 milligram per millimeter while HEWL concentration were 20, 30 and 40 milligram per milliliter. The crystals grown in 18 experiments for each impurity were dissolved and quantities of A or B additives in these crystals were analyzed by cation exchange high performance liquid chromatography. All the data for each set of 18 samples with the different impurity and regular HEWL concentrations is well described by one distribution coefficient K = 2.15 plus or minus 0.13 for A and K = 3.42 plus or minus 0.25 for B. The observed independence of the distribution coefficient on both the impurity concentration and supersaturation is explained by the dilution model described in this paper. It shows that impurity adsorption and incorporation rate is proportional to the impurity concentration and that the growth rate is proportional to the crystallizing protein in solution. With the kinetic coefficient for crystallization, beta = 5.10(exp -7) centimeters per second, the frequency at which an impurity molecule near the growing interface irreversibly joins a molecular site on the crystal was found to be 3 1 per second, much higher than the average frequency for crystal molecules. For best quality protein crystals it is better to have low microheterogeneous protein impurity concentration and high supers aturation.
Energy distribution for Coefficients of Redundant Signal Representations of Music
DEFF Research Database (Denmark)
Endelt, Line Ørtoft; la Cour-Harbo, Anders
2005-01-01
In this paper we investigate how the energy is distributed in the coefficients vector of various redundant signal representations of music signals. The representations are found using Basis Pursuit, Matching Pursuit, Alternating Projections, Best Orthogonal Basis and Method of Frames, with five d......, and less on the minimization method, the dictionary and the length of the analysis window. The results indicate, that the sparseness of the representations do indeed tell something about the music signal, and this is an interesting subject for further investigation.......In this paper we investigate how the energy is distributed in the coefficients vector of various redundant signal representations of music signals. The representations are found using Basis Pursuit, Matching Pursuit, Alternating Projections, Best Orthogonal Basis and Method of Frames, with five...... different time-frequency dictionaries. We have applied these methods to music to examine their ability to express music signals in a sparse manner for a number of dictionaries and window lengths. The evaluation is based on the m-term approximation needed to represent 90 %, 95 %, 99 % and 99...
Confidence bounds and hypothesis tests for normal distribution coefficients of variation
Steve Verrill; Richard A. Johnson
2007-01-01
For normally distributed populations, we obtain confidence bounds on a ratio of two coefficients of variation, provide a test for the equality of k coefficients of variation, and provide confidence bounds on a coefficient of variation shared by k populations.
Correlation of Cadmium Distribution Coefficients to Soil Characteristics
DEFF Research Database (Denmark)
Holm, Peter Engelund; Rootzen, Helle; Borggaard, Ole K.;
2003-01-01
on whole soil samples have shown that pH is the main parameter controlling the distribution. To identify further the components that are important for Cd binding in soil we measured Cd distribution coefficients (K-d) at two fixed pH values and at low Cd loadings for 49 soils sampled in Denmark. The Kd...... that the organic carbon content was a significant variable at both pH values. Cation exchange capacity (CEC) and gibbsite were important at the low pH (5.3) while iron oxides also were important at the high pH (6.7). None of the other clay minerals present in the soils (illite, smectite, kaolinite, hydroxy......Cadmium (Cd) distribution between the soil solid phase and the soil solution is a key issue in assessing the environmental effect of Cd in the terrestrial environmental. Previous studies have shown that many individual minerals and other components found in soils can bind Cd, but most studies...
Berthod, Alain; Mekaoui, Nazim
2011-09-09
There is some confusion in chromatography between terms such as solute distribution ratio, distribution constant and partition coefficient. These terms are very precisely defined in the field of liquid-liquid systems and liquid-liquid extraction as well as in the field of chromatography with sometimes conflicting definitions. Countercurrent chromatography (CCC) is a chromatographic technique in which the stationary phase is a support-free liquid. Since the mobile phase is also liquid, biphasic liquid systems are used. This work focuses on the exact meaning of the terms since there are consequences on experimental results. The retention volumes of solutes in CCC are linearly related to their distribution ratios. The partition coefficient that should be termed (IUPAC recommendation) distribution constant is linked to a single definite species. Using benzoic acid that can dimerize in heptane and ionize in aqueous phase and an 18 mL hydrodynamic CCC column, the role and relationships between parameters and the consequences on experimental peak position and shape are discussed. If the heptane/water distribution constant (marginally accepted to be called partition coefficient) of benzoic acid is 0.2 at 20 °C and can be tabulated in books, its CCC measured distribution ratio or distribution coefficient can change between zero (basic aqueous mobile phase) and more than 25 (acidic aqueous mobile phase and elevated concentration). Benzoic acid distribution ratio and partition coefficient coincide only when both dimerization and ionization are quenched, i.e. at very low concentration and pH 2. It is possible to quench dimerization adding butanol in the heptane/water system. However, butanol additions also affect the partition coefficient of benzoic acid greatly by increasing it.
Estimator and tests for common coefficients of variation in normal distributions
Forkman, Johannes
2009-01-01
Inference for the coefficient of variation in normal distributions is considered. An explicit estimator of a coefficient of variation that is shared by several populations with normal distributions is proposed. Methods for making confidence intervals and statistical tests, based on McKay's approximation for the coefficient of variation, are provided. Exact expressions for the first two moments of McKay's approximation are given. An approximate F-test for equality of a coefficient of variation...
Development of database on the distribution coefficient. 2. Preparation of database
Energy Technology Data Exchange (ETDEWEB)
Takebe, Shinichi; Abe, Masayoshi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment
2001-03-01
The distribution coefficient is very important parameter for environmental impact assessment on the disposal of radioactive waste arising from research institutes. 'Database on the Distribution Coefficient' was built up from the informations which were obtained by the literature survey in the country for these various items such as value , measuring method and measurement condition of distribution coefficient, in order to select the reasonable distribution coefficient value on the utilization of this value in the safety evaluation. This report was explained about the outline on preparation of this database and was summarized as a use guide book of database. (author)
KDS-CM: A Cache Mechanism Based on Top-K Data Source for Deep Web Query
Institute of Scientific and Technical Information of China (English)
KOU Yue; SHEN Derong; YU Ge; LI Dong; NIE Tiezheng
2007-01-01
Caching is an important technique to enhance the efficiency of query processing. Unfortunately, traditional caching mechanisms are not efficient for deep Web because of storage space and dynamic maintenance limitations. In this paper, we present on providing a cache mechanism based on Top-K data source (KDS-CM) instead of result records for deep Web query.By integrating techniques from IR and Top-K, a data reorganization strategy is presented to model KDS-CM. Also some measures about cache management and optimization are proposed to improve the performances of cache effectively. Experimental results show the benefits of KDS-CM in execution cost and dynamic maintenance when compared with various alternate strategies.
Asymptotic Distribution of Coefficients of Skewness and Kurtosis
Directory of Open Access Journals (Sweden)
Narges Abbasi
2009-01-01
Full Text Available Problem statement: In literature, a classic method which has been used to recognize the distribution so far is the measurement of its skewedness and kurtosis. However, there remains a question: how would these measurements work for skewed normal distribution when the size of the sample is large? Approach: This research aimed to determine the asymptotic distribution of skewedness and kurtosis measures in skewed normal distribution. In conducting this research, two groups of inferential findings will help. First, skewed normal distribution which has already been studied by a lot of researchers and we apply its characteristics. Second, there is the U-statistics theory which guides us to the determining of asymptotic distribution measures for skewedness and kurtosis. The combination of these two will solve the problem of this study. Results: Asymptotic distribution of measures for skewdness and kurtosis falls in the normal families. With the size of large samples, the values of expectation of these measures are also determined. By letting zero for skewedness parameter, asymptotic distribution for normal distribution can also be obtained. Conclusion: The findings of this study show new characteristics for skew normal distribution and this results in a new way for skew normal distribution recognition.
Energy Technology Data Exchange (ETDEWEB)
Campbell, J.R.; Luthy, R.G.
1984-06-01
Experimental and modeling activities were performed to assess techniques for measurement and prediction of distribution coefficients for aromatic solutes between water and immiscible organic solvents. Experiments were performed to measure distribution coefficients in both clean water and wastewater systems, and to assess treatment of a wastewater by solvent extraction. The theoretical portions of this investigation were directed towards development of techniques for prediction of solute-solvent/water distribution coefficients. Experiments were performed to assess treatment of a phenolic-laden coal conversion wastewater by solvent extraction. The results showed that solvent extraction for recovery of phenolic material offered several wastewater processing advantages. Distribution coefficients were measured in clean water and wastewater systems for aromatic solutes of varying functionality with different solvent types. It was found that distribution coefficients for these compounds in clean water systems were not statistically different from distribution coefficients determined in a complex coal conversion process wastewater. These and other aromatic solute distribution coefficient data were employed for evaluation of modeling techniques for prediction of solute-solvent/water distribution coefficients. Eight solvents were selected in order to represent various chemical classes: toluene and benzene (aromatics), hexane and heptane (alkanes), n-octanol (alcohols), n-butyl acetate (esters), diisopropyl ether (ethers), and methylisobutyl ketone (ketones). The aromatic solutes included: nonpolar compounds such as benzene, toluene and naphthalene, phenolic compounds such as phenol, cresol and catechol, nitrogenous aromatics such as aniline, pyridine and aminonaphthalene, and other aromatic solutes such as naphthol, quinolinol and halogenated compounds. 100 references, 20 figures, 34 tables.
Correlation of Cadmium Distribution Coefficients to Soil Characteristics
DEFF Research Database (Denmark)
Holm, Peter Engelund; Rootzen, Helle; Borggaard, Ole K.
2003-01-01
Cadmium (Cd) distribution between the soil solid phase and the soil solution is a key issue in assessing the environmental effect of Cd in the terrestrial environmental. Previous studies have shown that many individual minerals and other components found in soils can bind Cd, but most studies...
PG4KDS: A Model for the Clinical Implementation of Pre-emptive Pharmacogenetics
Hoffman, James M.; Haidar, Cyrine E.; Wilkinson, Mark R.; Crews, Kristine R.; Baker, Donald K.; Kornegay, Nancy M.; Yang, Wenjian; Pui, Ching-Hon; Reiss, Ulrike M.; Gaur, Aditya H.; Howard, Scott C.; Evans, William E.; Broeckel, Ulrich; Relling, Mary V.
2014-01-01
Pharmacogenetics is frequently cited as an area for initial focus of the clinical implementation of genomics. Through the PG4KDS protocol, St. Jude Children’s Research Hospital pre-emptively genotypes patients for 230 genes using the Affymetrix Drug Metabolizing Enzymes and Transporters (DMET) Plus array supplemented with a CYP2D6 copy number assay. The PG4KDS protocol provides a rational, stepwise process for implementing gene/drug pairs, organizing data, and obtaining consent from patients and families. Through August 2013, 1559 patients have been enrolled, and 4 gene tests have been released into the electronic health record (EHR) for clinical implementation: TPMT, CYP2D6, SLCO1B1, and CYP2C19. These genes are coupled to 12 high-risk drugs. Of the 1016 patients with genotype test results available, 78% of them had at least one high-risk (i.e., actionable) genotype result placed in their EHR. Each diplotype result released to the EHR is coupled with an interpretive consult that is created in a concise, standardized format. To support-gene based prescribing at the point of care, 55 interruptive clinical decision support (CDS) alerts were developed. Patients are informed of their genotyping result and its relevance to their medication use through a letter. Key elements necessary for our successful implementation have included strong institutional support, a knowledgeable clinical laboratory, a process to manage any incidental findings, a strategy to educate clinicians and patients, a process to return results, and extensive use of informatics, especially CDS. Our approach to pre-emptive clinical pharmacogenetics has proven feasible, clinically useful, and scalable. PMID:24619595
A-Collapsibility of Distribution Dependence and Quantile Regression Coefficients
Meerschaert, Mark M
2010-01-01
The Yule-Simpson paradox notes that an association between random variables can be reversed when averaged over a background variable. Cox and Wermuth (2003) introduced the concept of distribution dependence between two random variables X and Y , and developed two dependence conditions, each of which guarantees that reversal cannot occur. Ma, Xie and Geng (2006) studied the collapsibility of distribution dependence over a background variable W, under a rather strong homogeneity condition. Collapsibility ensures the association remains the same for conditional and marginal models, so that Yule-Simpson reversal cannot occur. In this paper, we investigate a more general condition for avoiding e?ect reversal: A-collapsibility. The conditions of Cox and Wermuth imply A-collapsibility, without assuming homogeneity. In fact, we show that, when W is a binary variable, collapsibility is equivalent to A-collapsibility plus homogeneity, and A-collapsibility is equivalent to the conditions of Cox and Wermuth. Recently, Co...
Copper and zinc distribution coefficients for sandy aquifer materials
DEFF Research Database (Denmark)
Christensen, Thomas Højlund; Astrup, Thomas; Boddum, J. K.
2000-01-01
; Zn: 6±22,800 l/kg) and correlating them to the characteristics of the aquifer material (particle size distribution, organic C content, surface area, pH) revealed good correlation with pH in the range 5.3± 8.9 (Cu: r 2=0.72; Zn: r 2=0.94). Including any other of the measured aquifer characteristics...... improved the correlation only a few percent. The results indicate that the mobility of Cu and Zn in sandy aquifers, as re¯ected in the measured Kd values, is very restricted at pH values above 6, since the relative migration velocity is less than 1%. However, at lower pH values, Zn seems to become mobile...
Diffusion coefficient distribution from NMR-DOSY experiments using Hopfield neural network
Sebastião, Rita C. O.; Pacheco, Carlos N.; Braga, J. P.; Piló-Veloso, Dorila
2006-09-01
Diffusion ordered spectroscopy (DOSY) is a powerful two-dimensional NMR method to study molecular translation in various systems. The diffusion coefficients are usually retrieved, at each frequency, from a fit procedure on the experimental data, considering a unique coefficient for each molecule or mixture. However, the fit can be improved if one regards the decaying curve as a multiexponential function and the diffusion coefficient as a distribution. This work presents a computer code based on the Hopfield neural network to invert the data. One small-molecule binary mixture with close diffusion coefficients is treated with this approach, demonstrating the effectiveness of the method.
Chang, Wen-Ruey; Matz, Simon; Chang, Chien-Chi
2012-01-01
The available coefficient of friction (ACOF) for human locomotion is the maximum coefficient of friction that can be supported without a slip at the shoe and floor interface. A statistical model was introduced to estimate the probability of slip by comparing the ACOF with the required coefficient of friction, assuming that both coefficients have stochastic distributions. This paper presents an investigation of the stochastic distributions of the ACOF of quarry tiles under dry, water and glycerol conditions. One hundred friction measurements were performed on a walkway under the surface conditions of dry, water and 45% glycerol concentration. The Kolmogorov-Smirnov goodness-of-fit test was used to determine if the distribution of the ACOF was a good fit with the normal, log-normal and Weibull distributions. The results indicated that the ACOF appears to fit the normal and log-normal distributions better than the Weibull distribution for the water and glycerol conditions. However, no match was found between the distribution of ACOF under the dry condition and any of the three continuous distributions evaluated. Based on limited data, a normal distribution might be more appropriate due to its simplicity, practicality and familiarity among the three distributions evaluated.
Bharate, Sonali S; Kumar, Vikas; Vishwakarma, Ram A
2016-01-01
An early prediction of physicochemical properties is highly desirable during drug discovery to find out a viable lead candidate. Although there are several methods available to determine partition coefficient (log P), distribution coefficient (log D) and ionization constant (pKa), none of them involves simple and fixed, miniaturized protocols for diverse set of compounds. Therefore, it is necessary to establish simple, uniform and medium-throughput protocols requiring small sample quantities for the determination of these physicochemical properties. Log P and log D were determined by shake flask method, wherein, the compound was partitioned between presaturated noctanol and water phase (water/PBS pH 7.4) and the concentration of compound in each phase was determined by HPLC. The pKa determination made use of UV spectrophotometric analysis in a 96-well microtiter plate containing a series of aqueous buffers ranging from pH 1.0 to 13.0. The medium-throughput miniaturized protocols described herein, for determination of log P, log D and pKa, are straightforward to set up and require very small quantities of sample (< 5 mg for all three properties). All established protocols were validated using diverse set of compounds.
Energy Technology Data Exchange (ETDEWEB)
Ramirez-Guinart, Oriol; Rigol, Anna; Vidal, Miquel [Analytical Chemistry department, Faculty of Chemistry, University of Barcelona, Mart i Franques 1-11, 08028, Barcelona (Spain)
2014-07-01
In the frame of the revision of the IAEA TRS 364 (Handbook of parameter values for the prediction of radionuclide transfer in temperate environments), a database of radionuclide solid-liquid distribution coefficients (K{sub d}) in soils was compiled with data coming from field and laboratory experiments, from references mostly from 1990 onwards, including data from reports, reviewed papers, and grey literature. The K{sub d} values were grouped for each radionuclide according to two criteria. The first criterion was based on the sand and clay mineral percentages referred to the mineral matter, and the organic matter (OM) content in the soil. This defined the 'texture/OM' criterion. The second criterion was to group soils regarding specific soil factors governing the radionuclide-soil interaction ('cofactor' criterion). The cofactors depended on the radionuclide considered. An advantage of using cofactors was that the variability of K{sub d} ranges for a given soil group decreased considerably compared with that observed when the classification was based solely on sand, clay and organic matter contents. The K{sub d} best estimates were defined as the calculated GM values assuming that K{sub d} values were always log-normally distributed. Risk assessment models may require as input data for a given parameter either a single value (a best estimate) or a continuous function from which not only individual best estimates but also confidence ranges and data variability can be derived. In the case of the K{sub d} parameter, a suitable continuous function which contains the statistical parameters (e.g. arithmetical/geometric mean, arithmetical/geometric standard deviation, mode, etc.) that better explain the distribution among the K{sub d} values of a dataset is the Cumulative Distribution Function (CDF). To our knowledge, appropriate CDFs has not been proposed for radionuclide K{sub d} in soils yet. Therefore, the aim of this works is to create CDFs for
Adaptive Zero-Coefficient Distribution Scan for Inter Block Mode Coding of H.264/AVC
Wang, Jing-Xin; Su, Alvin W. Y.
Scanning quantized transform coefficients is an important tool for video coding. For example, the MPEG-4 video coder adopts three different scans to get better coding efficiency. This paper proposes an adaptive zero-coefficient distribution scan in inter block coding. The proposed method attempts to improve H.264/AVC zero coefficient coding by modifying the scan operation. Since the zero-coefficient distribution is changed by the proposed scan method, new VLC tables for syntax elements used in context-adaptive variable length coding (CAVLC) are also provided. The savings in bit-rate range from 2.2% to 5.1% in the high bit-rate cases, depending on different test sequences.
Mazumder, Surasree; Alam, Jan-e
2014-01-01
The effects of gluon radiation by charm quarks on the transport coefficients {\\it e.g.} drag, longitudinal and transverse diffusion and shear viscosity have been studied within the ambit of perturbative quantum chromodynamics (pQCD) and kinetic theory. We found that while the soft gluon radiation has substantial effects on the transport coefficients of the charm quarks in the quark gluon plasma its effects on the equilibrium distribution function is insignificant.
Standard test method for distribution coefficients of inorganic species by the batch method
American Society for Testing and Materials. Philadelphia
2010-01-01
1.1 This test method covers the determination of distribution coefficients of chemical species to quantify uptake onto solid materials by a batch sorption technique. It is a laboratory method primarily intended to assess sorption of dissolved ionic species subject to migration through pores and interstices of site specific geomedia. It may also be applied to other materials such as manufactured adsorption media and construction materials. Application of the results to long-term field behavior is not addressed in this method. Distribution coefficients for radionuclides in selected geomedia are commonly determined for the purpose of assessing potential migratory behavior of contaminants in the subsurface of contaminated sites and waste disposal facilities. This test method is also applicable to studies for parametric studies of the variables and mechanisms which contribute to the measured distribution coefficient. 1.2 The values stated in SI units are to be regarded as standard. No other units of measurement a...
Measuring experimental cyclohexane-water distribution coefficients for the SAMPL5 challenge
Rustenburg, Ariën S.; Dancer, Justin; Lin, Baiwei; Feng, Jianwen A.; Ortwine, Daniel F.; Mobley, David L.; Chodera, John D.
2016-11-01
Small molecule distribution coefficients between immiscible nonaqueuous and aqueous phases—such as cyclohexane and water—measure the degree to which small molecules prefer one phase over another at a given pH. As distribution coefficients capture both thermodynamic effects (the free energy of transfer between phases) and chemical effects (protonation state and tautomer effects in aqueous solution), they provide an exacting test of the thermodynamic and chemical accuracy of physical models without the long correlation times inherent to the prediction of more complex properties of relevance to drug discovery, such as protein-ligand binding affinities. For the SAMPL5 challenge, we carried out a blind prediction exercise in which participants were tasked with the prediction of distribution coefficients to assess its potential as a new route for the evaluation and systematic improvement of predictive physical models. These measurements are typically performed for octanol-water, but we opted to utilize cyclohexane for the nonpolar phase. Cyclohexane was suggested to avoid issues with the high water content and persistent heterogeneous structure of water-saturated octanol phases, since it has greatly reduced water content and a homogeneous liquid structure. Using a modified shake-flask LC-MS/MS protocol, we collected cyclohexane/water distribution coefficients for a set of 53 druglike compounds at pH 7.4. These measurements were used as the basis for the SAMPL5 Distribution Coefficient Challenge, where 18 research groups predicted these measurements before the experimental values reported here were released. In this work, we describe the experimental protocol we utilized for measurement of cyclohexane-water distribution coefficients, report the measured data, propose a new bootstrap-based data analysis procedure to incorporate multiple sources of experimental error, and provide insights to help guide future iterations of this valuable exercise in predictive modeling.
A proof for Rhiel's range estimator of the coefficient of variation for skewed distributions.
Rhiel, G Steven
2007-02-01
In this research study is proof that the coefficient of variation (CV(high-low)) calculated from the highest and lowest values in a set of data is applicable to specific skewed distributions with varying means and standard deviations. Earlier Rhiel provided values for d(n), the standardized mean range, and a(n), an adjustment for bias in the range estimator of micro. These values are used in estimating the coefficient of variation from the range for skewed distributions. The d(n) and an values were specified for specific skewed distributions with a fixed mean and standard deviation. In this proof it is shown that the d(n) and an values are applicable for the specific skewed distributions when the mean and standard deviation can take on differing values. This will give the researcher confidence in using this statistic for skewed distributions regardless of the mean and standard deviation.
Parametrizing the relationship between Kds and Kps in contrasting aquatic systems
Vignati, D.; Dominik, J.
2003-05-01
Partition coefficients represent a convenient way to describe metal distribution among the particulate, colloidal and truly dissolved phases in aquatic systems (see footnote 1 for definitions). In particular, the distinction between colloids and true solution is extremely relevant to element fate and bioavailability. Regrettably, measurement of colloidal and truly dissolved metals is usually not performed in routine monitoring programmes since it is costly and time consuming. We show the possibility to estimate truly dissolved metal concentrations from the more easily measured particulate and filterable metal concentrations for a range of freshwater systems and one estuary.
Method for acquiring part load distribution coefficient of air conditioning system
Institute of Scientific and Technical Information of China (English)
丁勇; 李百战; 谭颖
2009-01-01
This paper presents a method to acquire runtime distribution ratio of building air conditioning system under part load condition (part load coefficient of system) through practical energy consumption data. By utilizing monthly energy consumption data of the entire year as the analysis object,this paper identifies data distribution,verifies distribution characteristics and analyzes distribution probability density for the issue of running time distribution ratio of air conditioning system in part load zones in the whole operation period,thus providing a basic calculation basis for an overall analysis of energy efficiency of air conditioning system. In view of the general survey of public building energy consumption carried by the government of Chongqing,this paper takes the governmental office building as an example,the part load ratio coefficient corresponding to practical running of air conditioning system of governmental office building in Chongqing is obtained by utilizing the above probability analysis and the solving method of probability density function. By utilizing the ratio coefficient obtained using this method,the part load coefficient with any running ratio of air conditioning system can be obtained according to the requirement of analysis,which can be used in any load ratio for analyzing running energy efficiency of air conditioning system.
Directory of Open Access Journals (Sweden)
Patarawan Sangnawakij
2017-02-01
Full Text Available The problem of estimating parameters in a gamma distribution has been widely studied with respect to both theories and applications. In special cases, when the parameter space is bounded, the construction of the confidence interval based on the classical Neyman procedure is unsatisfactory because the information regarding the restriction of the parameter is disregarded. In order to develop the estimator for this issue, the confidence intervals for the coefficient of variation for the case of a gamma distribution were proposed. Extending to two populations, the confidence intervals for the difference and the ratio of coefficients of variation with restricted parameters were presented. Monte Carlo simulations were used to investigate the performance of the proposed estimators. The results showed that the proposed confidence intervals performed better than the compared estimators in terms of expected length, especially when the coefficients of variation were close to the boundary. Additionally, two examples using real data were analyzed to illustrate the findings of the paper.
Korenman, Ya. I.; Krivosheeva, O. A.; Mokshina, N. Ya.
2012-12-01
The distribution of purine alkaloids (caffeine, theobromine, theophylline) was studied in the systems: alkyl acetates-dialkyl phtalate-salting-out agent (ammonium sulfate). The quantitative characteristics of the extraction-distribution coefficients ( D) and the degree of extraction ( R, %) are calculated. The relationships between the distribution coefficients of alkaloids and the length of the hydrocarbon radical in the molecule of alkyl acetate (dialkyl phtalate) are determined. The possibility of predicting the distribution coefficients is demonstrated.
A simple approximation to the bivariate normal distribution with large correlation coefficient
Albers, Willem; Kallenberg, Wilbert C.M.
1994-01-01
The bivariate normal distribution function is approximated with emphasis on situations where the correlation coefficient is large. The high accuracy of the approximation is illustrated by numerical examples. Moreover, exact upper and lower bounds are presented as well as asymptotic results on the er
A simple approximation to the bivariate normal distribution with large correlation coefficient
Albers, Willem/Wim; Kallenberg, W.C.M.
1994-01-01
The bivariate normal distribution function is approximated with emphasis on situations where the correlation coefficient is large. The high accuracy of the approximation is illustrated by numerical examples. Moreover, exact upper and lower bounds are presented as well as asymptotic results on the
Directory of Open Access Journals (Sweden)
N. K. Sajeevkumar
2014-09-01
Full Text Available In this article, we derived the Best Linear Unbiased Estimator (BLUE of the location parameter of certain distributions with known coefficient of variation by record values. Efficiency comparisons are also made on the proposed estimator with some of the usual estimators. Finally we give a real life data to explain the utility of results developed in this article.
Effective dose conversion coefficients for radionuclides exponentially distributed in the ground
Energy Technology Data Exchange (ETDEWEB)
Saito, Kimiaki [Japan Atomic Energy Agency, Tokyo (Japan); Ishigure, Nobuhito [Nagoya University, Graduate School of Medicine, Nagoya City (Japan); Petoussi-Henss, Nina; Schlattl, Helmut [Helmholtz Zentrum Muenchen-German Research Center for Environmental Health, Department of Radiation Physics and Diagnostics, Neuherberg (Germany)
2012-11-15
In order to provide fundamental data required for dose evaluation due to environmental exposures, effective dose conversion coefficients, that is, the effective dose rate per unit activity per unit area, were calculated for a number of potentially important radionuclides, assuming an exponential distribution in ground, over a wide range of relaxation depths. The conversion coefficients were calculated for adults and a new-born baby on the basis of dosimetric methods that the authors and related researchers have previously developed, using Monte Carlo simulations and anthropomorphic computational phantoms. The differences in effective dose conversion coefficients due to body size between the adult and baby phantoms were found to lie within 50 %, for most cases; however, for some low energies, differences could amount to a factor of 3. The effective dose per unit source intensity per area was found to decrease by a factor of 2-5, for increasing relaxation depths from 0 to 5 g/cm{sup 2}, above a source energy of 50 keV. It is also shown that implementation of the calculated coefficients into the computation of the tissue weighting factors and the adult reference computational phantoms of ICRP Publication 103 does not significantly influence the effective dose conversion coefficients of the environment. Consequently, the coefficients shown in this paper could be applied for the evaluation of effective doses, as defined according to both recommendations of ICRP Publications 103 and 60. (orig.)
Distribution-Based Identification of Yield Coefficients in a Baker’s Yeast Bioprocess
Directory of Open Access Journals (Sweden)
Dorin Sendrescu
2012-01-01
Full Text Available A distribution-based identification procedure for estimation of yield coefficients in a baker’s yeast bioprocess is proposed. This procedure transforms a system of differential equations to a system of algebraic equations with respect to unknown parameters. The relation between the state variables is represented by functionals using techniques from distribution theory. A hierarchical structure of identification is used, which allows obtaining a linear algebraic system of equations in the unknown parameters. The coefficients of this algebraic system are functionals depending on the input and state variables evaluated through some test functions from distribution theory. First, only some state equations are evaluated throughout test functions to obtain a set of linear equations in parameters. The results of this first stage of identification are used to express other parameters by linear equations. The process is repeated until all parameters are identified. The performances of the method are analyzed by numerical simulations.
Akimoto, Takuma; Yamamoto, Eiji
2016-12-01
Local diffusion coefficients in disordered systems such as spin glass systems and living cells are highly heterogeneous and may change over time. Such a time-dependent and spatially heterogeneous environment results in irreproducibility of single-particle-tracking measurements. Irreproducibility of time-averaged observables has been theoretically studied in the context of weak ergodicity breaking in stochastic processes. Here, we provide rigorous descriptions of equilibrium and non-equilibrium diffusion processes for the annealed transit time model, which is a heterogeneous diffusion model in living cells. We give analytical solutions for the mean square displacement (MSD) and the relative standard deviation of the time-averaged MSD for equilibrium and non-equilibrium situations. We find that the time-averaged MSD grows linearly with time and that the time-averaged diffusion coefficients are intrinsically random (irreproducible) even in the long-time measurements in non-equilibrium situations. Furthermore, the distribution of the time-averaged diffusion coefficients converges to a universal distribution in the sense that it does not depend on initial conditions. Our findings pave the way for a theoretical understanding of distributional behavior of the time-averaged diffusion coefficients in disordered systems.
Influence of state-to-state vibrational distributions on transport coefficients of a single gas
Kustova, Elena V.; Kremer, Gilberto M.
2016-11-01
In this work the influence of the size of vibrationally and rotationally excited molecules on the collision integrals required for the calculation of state-to-state transport coefficients is discussed. Several diatomic molecules are considered: N2, O2, NO, H2, Cl2. It is shown that whereas the molecular size is not affected by rotational excitation, it strongly depends on the vibrational state. Particular emphasis is given to the shear viscosity and thermal conductivity coefficients calculated in the temperature range 2 500-20 000 K for equilibrium Boltzmann vibrational distributions. It is shown that under conditions of local thermal equilibrium, the effect of vibrational excitation on the shear viscosity and thermal conductivity coefficients are found to be negligible for temperatures below 5 000 K, except for the case of Cl2 molecule where at 5 000 K the effect is about 10%. For T > 10 000 K, the contribution of excited states becomes important and reaches 10-25%.
All-atom/coarse-grained hybrid predictions of distribution coefficients in SAMPL5
Genheden, Samuel; Essex, Jonathan W.
2016-11-01
We present blind predictions submitted to the SAMPL5 challenge on calculating distribution coefficients. The predictions were based on estimating the solvation free energies in water and cyclohexane of the 53 compounds in the challenge. These free energies were computed using alchemical free energy simulations based on a hybrid all-atom/coarse-grained model. The compounds were treated with the general Amber force field, whereas the solvent molecules were treated with the Elba coarse-grained model. Considering the simplicity of the solvent model and that we approximate the distribution coefficient with the partition coefficient of the neutral species, the predictions are of good accuracy. The correlation coefficient, R is 0.64, 82 % of the predictions have the correct sign and the mean absolute deviation is 1.8 log units. This is on a par with or better than the other simulation-based predictions in the challenge. We present an analysis of the deviations to experiments and compare the predictions to another submission that used all-atom solvent.
Dynamics of the logistic delay equation with a large spatially distributed control coefficient
Kashchenko, I. S.; Kashchenko, S. A.
2014-05-01
The local dynamics of the logistic delay equation with a large spatially distributed control coefficient is asymptotically studied. The basic bifurcation scenarios are analyzed depending on the relations between the parameters of the equation. It is shown that the equilibrium states can lose stability even for asymptotically small values of the delay parameter. The corresponding critical cases can have an infinite dimension. Special nonlinear parabolic equations are constructed whose nonlocal dynamics determine the local behavior of solutions to the original boundary value problem.
Coefficients of caffeine distribution in aliphatic alcohol-ammonium sulfate-water systems
Korenman, Ya. I.; Krivosheeva, O. A.; Mokshina, N. Ya.
2012-11-01
The extraction of caffeine with aliphatic alcohols C3-C9 from aqueous solutions in the presence of a salting-out agent (ammonium sulfate) is studied. Quantitative characteristics of extraction are calculated: the distribution coefficients ( D) and the degree of recovery ( R, %). Relations are found between log D of caffeine and the length of the hydrocarbon radical in the alcohol molecule, along with certain physicochemical properties of the extragents.
Improved Estimators of the Mean of a Normal Distribution with a Known Coefficient of Variation
Directory of Open Access Journals (Sweden)
Wuttichai Srisodaphol
2012-01-01
Full Text Available This paper is to find the estimators of the mean θ for a normal distribution with mean θ and variance aθ2, a>0, θ>0. These estimators are proposed when the coefficient of variation is known. A mean square error (MSE is a criterion to evaluate the estimators. The results show that the proposed estimators have preference for asymptotic comparisons. Moreover, the estimator based on jackknife technique has preference over others proposed estimators with some simulations studies.
The KMOS Deep Survey (KDS) - I. Dynamical measurements of typical star-forming galaxies at z ≃ 3.5
Turner, O. J.; Cirasuolo, M.; Harrison, C. M.; McLure, R. J.; Dunlop, J. S.; Swinbank, A. M.; Johnson, H. L.; Sobral, D.; Matthee, J.; Sharples, R. M.
2017-10-01
We present dynamical measurements from the KMOS (K-band multi-object spectrograph) Deep Survey (KDS), which comprises 77 typical star-forming galaxies at z ≃ 3.5 in the mass range 9.0 mean velocity dispersion of the galaxies in our sample is σ _int = 70.8^{+3.3}_{-3.1} km s^{-1}, revealing that the increasing average σint with increasing redshift, reported for z ≲ 2, continues out to z ≃ 3.5. Only 36 ± 8 per cent of our galaxies are rotation-dominated (VC/σint > 1), with the sample average VC/σint value much smaller than at lower redshift. After carefully selecting comparable star-forming samples at multiple epochs, we find that the rotation-dominated fraction evolves with redshift with a z-0.2 dependence. The rotation-dominated KDS galaxies show no clear offset from the local rotation velocity-stellar mass (i.e. VC-M⋆) relation, although a smaller fraction of the galaxies are on the relation due to the increase in the dispersion-dominated fraction. These observations are consistent with a simple equilibrium model picture, in which random motions are boosted in high-redshift galaxies by a combination of the increasing gas fractions, accretion efficiency, specific star formation rate and stellar feedback and which may provide significant pressure support against gravity on the galactic disc scale.
Rhiel, G Steven
2010-02-01
In 2007, Rhiel presented a technique to estimate the coefficient of variation from the range when sampling from skewed distributions. To provide an unbiased estimate, a correction factor (a(n)) for the mean was included. Numerical correction factors for a number of skewed distributions were provided. In a follow-up paper, he provided a proof he claimed showed the correction factor was independent of the mean and standard deviation, making the factors useful as these parameters vary; however, that proof did not establish independence. Herein is a proof which establishes the independence.
Estimation of expected value and coefficient of variation for lognormal and gamma distributions
Energy Technology Data Exchange (ETDEWEB)
White, G.C.
1978-07-01
Concentrations of environmental pollutants tend to follow positively skewed frequency distributions. Two such density functions are the gamma and lognormal. Minimum variance unbiased estimators of the expected value for both densities are available. The small sample statistical properties of each of these estimators were compared for their own distributions, as well as for the other distribution, to check the robustness of the estimator. The arithmetic mean is known to provide an unbiased estimator of expected value when the underlying density of the sample is either lognormal or gamma, and results indicated the achieved coverage of the confidence interval is greater than 75 percent for coefficients of variation less than two. Further Monte Carlo simulations were conducted to study the robustness of the above estimators by simulating a lognormal or gamma distribution with the expected value of a particular observation selected from a uniform distribution before the lognormal or gamma observation is generated. Again, the arithmetic mean provides an unbiased estimate of expected value, and the achieved coverage of the confidence interval is greater than 75 percent for coefficients of variation less than two.
Energy Technology Data Exchange (ETDEWEB)
Kaplan, D.; et. al
2010-01-11
The uncertainty associated with the sorption coefficient, or K{sub d} value, is one of the key uncertainties in estimating risk associated with burying low-level nuclear waste in the subsurface. The objective of this study was to measure >648 K{sub d} values and provide a measure of the range and distribution (normal or log-normal) of radionuclide K{sub d} values appropriate for the E-Area disposal site, within the Savannah River Site, near Aiken South Carolina. The 95% confidence level for the mean K{sub d} was twice the mean in the Aquifer Zone (18-30.5 m depth), equal to the mean for the Upper Vadose Zone (3.3-10 m depth), and half the mean for the Lower Vadose Zone (3.10-18 m depth). The distribution of K{sub d} values was log normal in the Upper Vadose Zone and Aquifer Zone, and normal in the Lower Vadose Zone. To our knowledge, this is the first report of natural radionuclide Kd variability in the literature. Using ranges and distribution coefficients that are specific to the hydrostratigraphic unit improved model accuracy and reduced model uncertainty. Unfortunately, extension of these conclusions to other sites is likely not appropriate given that each site has its own sources of hydrogeological variability. However, this study provides one of the first examples of the development stochastic ranges and distributions of K{sub d} values for a hydrological unit for stochastic modeling.
Directory of Open Access Journals (Sweden)
Ramin Mansouri
2014-06-01
Full Text Available Iran, has caused most of the water used and as much as possible to avoid losses. One of the important parameters in agriculture is water distribution uniformity coefficient (CU in sprinkler irrigation. CU amount of water sprinkler operating depends on different pressure heads (P, riser height (RH, distance between sprinklers on lateral pipes (Sl and the distance between lateral pipes (Sm. The best combination of the above parameters for maximum CU, is still unknown for applicators. In this research, CU quantities of zb model sprinkler (made in Iran were measured at Hashemabad cotton research station of Gorgan under 3 different pressure heads (2.5, 3 and 3.5 atm, 2 riser heads (60 and 100 cm and 7 sprinkler (Sl×Sm including 9×12, 9×15, 12×12, 15×12, 12×18, 15×15, 15×18m arrangements. By using differential evolution algorithm (DE, CU equation was optimized and the best optimized coefficients obtained. In this algorithm, the coefficients F and CR equal to 2 and 0.5, respectively, with a population of 100 members and 1000 number of generations (iterations, provides the best results. Absolute error between the results of this algorithm with the measured results is 2.2%. As well as values Wilmot (d and the root-mean square error (RMSE, equal to 0.919 and 2.126, respectively. This results show that this algorithm has high accuracy to estimate water distribution uniformity.
On the sampling distribution of the coefficient of L-variation for hydrological applications
Directory of Open Access Journals (Sweden)
A. Viglione
2010-08-01
Full Text Available The coefficient of L-variation (L-CV is commonly used in statistical hydrology, in particular in regional frequency analysis, as a measure of steepness of the frequency curve. The aim of this work is to infer the full frequency distribution of the sample L-CV (and, consequently, its confidence intervals for small samples and without making assumptions on the underlying parent distribution of the hydrological variable of interest. Several two-parameters candidate distributions are compared for a wide range of cases using Monte-Carlo simulations. A distribution-free method, recently proposed to estimate the variance structure of sample L-moments, is used to provide the parameters for the candidate distributions. It is shown that the log-Student t distribution approximates best, in most of the cases, the distribution of the sample L-CV and that a simple correction of the bias for the sample L-CV and its variance improves the fit. Also, the parametric method proposed here is demonstrated to perform better than the non-parametric bootstrap. An example of how this result could be used in hydrology is presented, namely in the comparison of methods for regional flood frequency analysis.
DEFF Research Database (Denmark)
Jeong, Cheol-Ho
2009-01-01
tracing method for various room shapes and source positions. The averaged angular distribution is found to be similar to a Gaussian distribution. As a result, an angle-weighted absorption coefficient was proposed by considering the angular energy distribution to improve the agreement between...... the theoretical absorption coefficient and the reverberation room measurement. The angle-weighted absorption coefficient, together with the size correction, agrees satisfactorily with the measured absorption data by the reverberation chamber method. At high frequencies and for large samples, the averaged...... weighting corresponds well with the measurement, whereas at low frequencies and for small panels, the relatively flat distribution agrees better....
Wassenburg, J. A.; Scholz, D.; Jochum, K. P.; Cheng, H.; Oster, J.; Immenhauser, A.; Richter, D. K.; Häger, T.; Jamieson, R. A.; Baldini, J. U. L.; Hoffmann, D.; Breitenbach, S. F. M.
2016-10-01
The processes that govern the incorporation of (trace) elements into speleothems can often be linked to environmental changes. Although element incorporation into speleothem calcite is now reasonably well understood, current knowledge regarding trace element variability in speleothem aragonite is very limited. Of particular interest is whether trace element distribution coefficients are above or below one in order to assess the extent to which prior aragonite precipitation has affected speleothem aragonite trace element records. This study uses nine calcite-to-aragonite transitions in seven speleothems from diverse environmental settings to derive the first quantitative estimates of the distribution coefficients for several elements in speleothem aragonite: DMg(Ar) = 9.7E-5 ± 9.01E-5, DBa(Ar) = 0.91 ± 0.88, DSr(Ar) = 1.38 ± 0.53, and DU(Ar) = 6.26 ± 4.54 (1σ SD). For one speleothem from western Germany, the distribution coefficients are generally higher, which is potentially related to the very low growth rates (negative correlation with growth rate when growth rate is below 20 μm/year. In summary, our results demonstrate that speleothem aragonite DMg(Ar) is below one, DU(Ar) is considerably above one, and DSr(Ar) is above one or close to unity. For DBa(Ar), reaching a similar conclusion is difficult due to the relatively high uncertainty. Enhanced prior aragonite precipitation will thus result in lower U and higher Mg concentrations in speleothem aragonite, although in many cases Mg in speleothem aragonite is most likely dominated by other processes. This result suggests that U concentrations in aragonitic stalagmites could serve as a very effective proxy for palaeo-rainfall.
DEFF Research Database (Denmark)
Jeong, Cheol-Ho
2010-01-01
intensity distributions above 1 kHz were similar for all studied cases, but some variations in low frequency intensity distributions were observed. If the non-uniform intensity distribution and a finite size effect are taken into account for correcting the theoretical absorption coefficients, a good......Measured absorption coefficients in reverberation chambers often differ from theoretical random incidence absorption coefficients, because ideal assumptions for the theoretical random incidence absorption coefficient are not fulfilled during measurements in actual reverberation chambers. Therefore...... sound intensity distributions on absorber under measurement conditions have been simulated using a phased beam tracing, and used as correction functions for reducing discrepancies between the measured and theoretical absorption coefficients. Two reverberation rooms were investigated by assuming...
Determination of distribution coefficients (K{sub d}) of various radionuclides on UTEVA resin
Energy Technology Data Exchange (ETDEWEB)
Marinov, Genko M.; Marinova, Atanaska P. [Joint Institute for Nuclear Research, DLNP, Dubna (Russian Federation); Sofia Univ. (Bulgaria). Faculty of Chemistry and Pharmacy; Medvedev, Dmitry V.; Filosofov, Dmitry V. [Joint Institute for Nuclear Research, DLNP, Dubna (Russian Federation); Dadakhanov, Jahangir A. [Joint Institute for Nuclear Research, DLNP, Dubna (Russian Federation); AS RUz, Tashkent (Uzbekistan). Inst. of Nuclear Physics; Milanova, Maria M. [Sofia Univ. (Bulgaria). Faculty of Chemistry and Pharmacy; Happel, Steffen [Triskem International, Bruz (France); Radchenko, Valery I. [Mainz Univ. (Germany)
2016-07-01
Using radioisotope markers the distribution coefficients (K{sub d}) of the following elements In, Sn, Sb, Te, Bi, Co, Fe, Nb, Sr, Ba, Ag, Cd, Zr, Hf and Ti were determined with different concentrations of HCl, H{sub 2}SO{sub 4} and HNO{sub 3} for the extraction chromatographic resin Uranium and TEtraValent Actinides (UTEVA). This data can be used for separation of elements in complex mixtures, as well as for correct assessment of the elements chemistry with higher valences such as 3, 4, 5 or 6.
Tetko, Igor V; Poda, Gennadiy I
2004-11-01
Evaluation of the ALOGPS, ACD Labs LogD, and PALLAS PrologD suites to calculate the log D distribution coefficient resulted in high root-mean-squared error (RMSE) of 1.0-1.5 log for two in-house Pfizer's log D data sets of 17,861 and 640 compounds. Inaccuracy in log P prediction was the limiting factor for the overall log D estimation by these algorithms. The self-learning feature of the ALOGPS (LIBRARY mode) remarkably improved the accuracy in log D prediction, and an rmse of 0.64-0.65 was calculated for both data sets.
Directory of Open Access Journals (Sweden)
Hongjun Xiang
2008-01-01
Full Text Available A class of fuzzy Cohen-Grossberg neural networks with distributed delay and variable coefficients is discussed. It is neither employing coincidence degree theory nor constructing Lyapunov functionals, instead, by applying matrix theory and inequality analysis, some sufficient conditions are obtained to ensure the existence, uniqueness, global attractivity and global exponential stability of the periodic solution for the fuzzy Cohen-Grossberg neural networks. The method is very concise and practical. Moreover, two examples are posed to illustrate the effectiveness of our results.
Directory of Open Access Journals (Sweden)
Wararit Panichkitkosolkul
2013-01-01
Full Text Available This paper presents three confidence intervals for the coefficient of variation in a normal distribution with a known population mean. One of the proposed confidence intervals is based on the normal approximation. The other proposed confidence intervals are the shortest-length confidence interval and the equal-tailed confidence interval. A Monte Carlo simulation study was conducted to compare the performance of the proposed confidence intervals with the existing confidence intervals. Simulation results have shown that all three proposed confidence intervals perform well in terms of coverage probability and expected length.
Archana V; Aruna Rao K
2014-01-01
Co-efficient of variation is a unitless measure of dispersion and is very frequently used in scientific investigations. This has motivated several researchers to propose estimators and tests concerning the co-efficient of variation of normal distribution(s). While proposing a class of estimators for the co-efficient of variation of a finite population, Tripathi et al., (2002) suggested that the estimator of co-efficient of variation of a finite population can also be used as an estimator of C...
Silva, Antonio
2005-03-01
It is well-known that the mathematical theory of Brownian motion was first developed in the Ph. D. thesis of Louis Bachelier for the French stock market before Einstein [1]. In Ref. [2] we studied the so-called Heston model, where the stock-price dynamics is governed by multiplicative Brownian motion with stochastic diffusion coefficient. We solved the corresponding Fokker-Planck equation exactly and found an analytic formula for the time-dependent probability distribution of stock price changes (returns). The formula interpolates between the exponential (tent-shaped) distribution for short time lags and the Gaussian (parabolic) distribution for long time lags. The theoretical formula agrees very well with the actual stock-market data ranging from the Dow-Jones index [2] to individual companies [3], such as Microsoft, Intel, etc. [] [1] Louis Bachelier, ``Th'eorie de la sp'eculation,'' Annales Scientifiques de l''Ecole Normale Sup'erieure, III-17:21-86 (1900).[] [2] A. A. Dragulescu and V. M. Yakovenko, ``Probability distribution of returns in the Heston model with stochastic volatility,'' Quantitative Finance 2, 443--453 (2002); Erratum 3, C15 (2003). [cond-mat/0203046] [] [3] A. C. Silva, R. E. Prange, and V. M. Yakovenko, ``Exponential distribution of financial returns at mesoscopic time lags: a new stylized fact,'' Physica A 344, 227--235 (2004). [cond-mat/0401225
Metal:Calcite Distribution Coefficients of Laboratory-Grown Bathyl Benthic Foraminifera
Hintz, C. J.; Shaw, T. J.; Bernhard, J. M.; Chandler, G. T.; McCorkle, D. C.; Blanks, J. K.
2002-12-01
Benthic foraminifera, collected from sediments off the Carolina coast, were maintained in mono- and multi-species cultures for four and a half months in a sediment-free culture system. The foraminifera were cultured in a closed system using a 1600-liter modified artificial seawater reservoir. The temperature, alkalinity, stable isotope ratios, and trace metal concentrations were held static in seawater medium during the experiment. The artificial seawater was circulated from the reservoir through nine 3 mL acrylic microcosms that contained 80-100 foraminifera living in ~1 mm thick silica substrate. Foraminifera were labeled with fluorescent calcein, prior to addition to the microcosms, to provide a clear demarcation between parent calcite and cultured calcite. At the end of the experiment juvenile Bulimina aculeata were harvested from the microcosms (~150-3000 specimens per microcosm). The cultured foraminifera were divided into two groups for separate trace metal analyses and stable isotope analyses. The foraminifera from the trace metal splits were cleaned and analyzed for Ca, Ba, and Cd by isotope dilution ICP-MS. Barium distribution coefficients were close to previously reported values of cultured foraminiferal calcite but remained lower than reported field data. Preliminary Ba:Ca distribution coefficients for B. aculeata do not appear to indicate strong life stage differences, even though there are indications of ontogenetic variations in δ13C for this species (see McCorkle et al. abstract).
Santos-Martins, Diogo; Fernandes, Pedro Alexandrino; Ramos, Maria João
2016-11-01
In the context of SAMPL5, we submitted blind predictions of the cyclohexane/water distribution coefficient (D) for a series of 53 drug-like molecules. Our method is purely empirical and based on the additive contribution of each solute atom to the free energy of solvation in water and in cyclohexane. The contribution of each atom depends on the atom type and on the exposed surface area. Comparatively to similar methods in the literature, we used a very small set of atomic parameters: only 10 for solvation in water and 1 for solvation in cyclohexane. As a result, the method is protected from overfitting and the error in the blind predictions could be reasonably estimated. Moreover, this approach is fast: it takes only 0.5 s to predict the distribution coefficient for all 53 SAMPL5 compounds, allowing its application in virtual screening campaigns. The performance of our approach (submission 49) is modest but satisfactory in view of its efficiency: the root mean square error (RMSE) was 3.3 log D units for the 53 compounds, while the RMSE of the best performing method (using COSMO-RS) was 2.1 (submission 16). Our method is implemented as a Python script available at https://github.com/diogomart/SAMPL5-DC-surface-empirical.
Tanikawa, Takumi; Ohba, Hisateru; Ogasawara, Katsuhiko; Okuda, Yasuo; Ando, Yutaka
2012-01-01
This is a pilot study that aims to elucidate regional disparities in the distribution of medical resources in Japan. For this purpose, we employed the Gini coefficient (GC) in order to analyze the distribution of radiotherapy resources, which are allocated to each prefecture in Japan depending on the size of its population or physical area. Our study used data obtained from the 2005 and 2007 national surveys on the structure of radiation oncology in Japan, conducted by the Japanese Society for Therapeutic Radiology and Oncology (JASTRO). Our analysis showed that the regional disparities regarding the radiation oncologists and radiotherapy technologists were small, and concluded that such resources were almost equitably distributed. However, medical physicists are inequitably distributed. Thus, policymakers should create and implement measures to train and retain medical physicists in areas with limited radiotherapy resources. Further, almost 26% of the secondary medical service areas lacked radiotherapy institutions. We attribute this observation to the existence of tertiary medical service areas, and almost all of prefectures face a shortage of such resources. Therefore, patients' accessibility to these resources in such areas should be improved.
Yuan, Ke-Hai; Guarnaccia, Charles A.; Hayslip, Bert, Jr.
2003-01-01
Studied the sample coefficient alpha for each of the five subscales of the Hopkins Symptom Checklist (HSL; L. Derogaitis and others, 1974) in a sample of 419 adults. Findings show that the normal-theory-based distribution has a systematic bias in describing the behavior of the sample coefficient alpha. (SLD)
Directory of Open Access Journals (Sweden)
Archana V
2014-05-01
Full Text Available Co-efficient of variation is a unitless measure of dispersion and is very frequently used in scientific investigations. This has motivated several researchers to propose estimators and tests concerning the co-efficient of variation of normal distribution(s. While proposing a class of estimators for the co-efficient of variation of a finite population, Tripathi et al., (2002 suggested that the estimator of co-efficient of variation of a finite population can also be used as an estimator of C.V for any distribution when the sampling design is SRSWR. This has motivated us to propose 28 estimators of finite population co-efficient of variation as estimators of co-efficient of variation of one component of a bivariate normal distribution when prior information is available regarding the second component. Cramer Rao type lower bound is derived to the mean square error of these estimators. Extensive simulation is carried out to compare these estimators. The results indicate that out of these 28 estimators, eight estimators have larger relative efficiency compared to the sample co-efficient of variation. The asymptotic mean square errors of the best estimators are derived to the order of for the benefit of users of co-efficient of variation.
Hintz, C. J.; Shaw, T. J.; Chandler, G. T.; McCorkle, D. C.; Bernhard, J. M.; Blanks, J. K.
2006-12-01
Field studies have suggested that calcite saturation states (Ømega) near and below saturation alter trace element distribution coefficients in benthic foraminifera. Recent benthic foraminiferal culture experiments at the University of South Carolina investigated the response of trace element signatures to three different calcite saturation seawater environments by manipulating total alkalinity (TA). Starting with near-surface Gulf Stream water (Ømega = 3, TA=2380 μeq kg-1), two seawater reservoirs were titrated with HCl to lower their calcite saturation states (Ømega = 2, TA = 1910 μeq kg-1; Ømega = 1.1, TA = 1320 μeq kg-1). Mixed-species foraminiferal assemblages, with the calcite-specific fluorescent label calcein, were inoculated into 13 total culture chambers evenly distributed among the control and 2 treatment seawater reservoirs. These cultures were maintained at 7.2 ± 0.1 °C temperature and 36.6 ± 0.4 ‰ salinity for 8 months. Total alkalinity and dissolved inorganic carbon, measured biweekly, characterized the carbonate system and verified that the calcite saturation state remained stable over the culture duration. Trace element concentrations were also measured biweekly. Foraminiferal reproduction ( Bulimina marginata) was observed in each seawater chemistry. These individuals were utilized for trace element and stable isotope (data not presented here) analysis. Additionally, terminal chambers precipitated in alkalinity-adjusted cultures were identified by the absence of the pre-culture calcein label used on all inoculated foraminifera. These cultured chambers were separated by laser microdissection and analyzed for trace element content by isotope dilution inductively-coupled plasma mass spectrometry. We present the initial results of these trace element distribution coefficients measured in cultured benthic foraminifera from three different Ømega. This research was funded by National Science Foundation grants OCE-0351029 and OCE-0437366.
Directory of Open Access Journals (Sweden)
Wararit Panichkitkosolkul
2010-01-01
Full Text Available A new asymptotic confidence interval constructed by using a confidence intervalfor the Poisson mean is proposed for the coefficient of variation of the Poisson distribution.The following confidence intervals are considered: McKay’s confidence interval, Vangel’sconfidence interval and the proposed confidence interval. Using Monte Carlo simulations,the coverage probabilities and expected lengths of these confidence intervals are compared.Simulation results show that all scenarios of the new asymptotic confidence interval havedesired minimum coverage probabilities of 0.95 and 0.90. In addition, the newly proposedconfidence interval is better than the existing ones in terms of coverage probability andexpected length for all sample sizes and parameter values considered in this paper.
Wagner, Bjoern; Fischer, Holger; Kansy, Manfred; Seelig, Anna; Assmus, Frauke
2015-02-20
Here we present a miniaturized assay, referred to as Carrier-Mediated Distribution System (CAMDIS) for fast and reliable measurement of octanol/water distribution coefficients, log D(oct). By introducing a filter support for octanol, phase separation from water is facilitated and the tendency of emulsion formation (emulsification) at the interface is reduced. A guideline for the best practice of CAMDIS is given, describing a strategy to manage drug adsorption at the filter-supported octanol/buffer interface. We validated the assay on a set of 52 structurally diverse drugs with known shake flask log D(oct) values. Excellent agreement with literature data (r(2) = 0.996, standard error of estimate, SEE = 0.111), high reproducibility (standard deviation, SD stock solution) and a broad analytical range (log D(oct) range = -0.5 to 4.2) make CAMDIS a valuable tool for the high-throughput assessment of log D(oc)t. Copyright © 2014 Elsevier B.V. All rights reserved.
Determining the deficit coefficient as a function of irrigation depth and distribution uniformity
National Research Council Canada - National Science Library
Mantovani, Everardo C; Faccioli, Gregório G; Leal, Brauliro G; Costa, Luis C; Soares, Antônio A; Freitas, Paulo S. L
2010-01-01
The present study aimed at the development of the water deficit coefficient as a function of the Christiansen uniformity coefficient and relationship between the applied water depth and that required...
Energy Technology Data Exchange (ETDEWEB)
Lahdenperae, Anne-Maj [Saanio and Riekkola Oy, Laulukuja 4, FI-00420 Helsinki (Finland); Ikonen, Ari T.K. [Environmental Research and Assessment EnviroCase, Ltd., Hallituskatu 1 D 4, 28100 Pori (Finland)
2014-07-01
In Finland, the Olkiluoto Island on the western coast has been selected as a repository site for the spent nuclear fuel. Due to shallow sea areas around the island, the post-glacial crustal rebound (around 6 mm/y) is changing the landscape significantly; during the next thousands of years new soil types are emerging, the present bays will narrow and form future lakes and mires assumedly similar to those farther inland at present. The effects of terrain development are important in long-term safety assessments for the repository, especially in the biosphere assessments addressing radiation exposure of people and biota in scenarios of radionuclide releases. 'In situ' distribution coefficients, K{sub d} values are used to indicate the relevant mobility of radionuclides of concern from nuclear waste. These radionuclides have very long half-lives and long interaction times with soils, ranging from centuries to millennia. By measuring the desorption K{sub d} values of the indigenous stable elements (Ag, Cl, Cs, I, Mo, Nb, Ni, Se and Sr) from field moist samples are a valid description of slow retention processes. The 'in situ' K{sub d} desorption values are calculated for humus, peat and different mineral soil samples taken from the Olkiluoto Island and the Reference Area used as an analogue of the future terrain. The solids are extracted alternatively by HNO{sub 3}-HF and NH{sub 4}Ac (pH 4.5). The K{sub d} values are highly dependent on environmental factors, including but not limited to pH, soil type, soil horizon, soil body, texture, element chemical form, organic matter, carbon content and biological activity. This is discussed in the contribution; e.g., for several elements pH and K{sub d} values correlate - the finer the soil or sediment, the higher the K{sub d} values - and humus and peat samples have a clear correlation with the organic matter and carbon contents. The contribution also compares the 'in situ' K{sub d} values to
Diaz-Rodriguez, Sebastian; Bozada, Samantha M.; Phifer, Jeremy R.; Paluch, Andrew S.
2016-11-01
We present blind predictions using the solubility parameter based method MOSCED submitted for the SAMPL5 challenge on calculating cyclohexane/water distribution coefficients at 298 K. Reference data to parameterize MOSCED was generated with knowledge only of chemical structure by performing solvation free energy calculations using electronic structure calculations in the SMD continuum solvent. To maintain simplicity and use only a single method, we approximate the distribution coefficient with the partition coefficient of the neutral species. Over the final SAMPL5 set of 53 compounds, we achieved an average unsigned error of 2.2± 0.2 log units (ranking 15 out of 62 entries), the correlation coefficient ( R) was 0.6± 0.1 (ranking 35), and 72± 6 % of the predictions had the correct sign (ranking 30). While used here to predict cyclohexane/water distribution coefficients at 298 K, MOSCED is broadly applicable, allowing one to predict temperature dependent infinite dilution activity coefficients in any solvent for which parameters exist, and provides a means by which an excess Gibbs free energy model may be parameterized to predict composition dependent phase-equilibrium.
Energy Technology Data Exchange (ETDEWEB)
Soederlund, M.; Lusa, M.; Virtanen, S.; Vaelimaa, I.; Hakanen, M.; Lehto, J. [Univ. of Helsinki, Lab. of Radiochemistry (Finland); Lahdenperae, A.-M. [Saanio and Riekkola Oy, Helsinki (Finland)
2014-02-15
Retention of caesium, chlorine, iodine, niobium, selenium and technetium was investigated on soil samples from Olkiluoto using laboratory batch sorption experiments. Distribution coefficients were measured for both dried and sieved and untreated (wet, not sieved) mineral soil and humus in aerobic and anaerobic conditions. Mineralogical composition of the samples was determined by XRD-analysis. Caesium was sorbed efficiently on mineral soil samples and less efficiently on humus. Sorption decreased with decreasing cation exchange capacity and clay fraction content. The effect of competing cations decreased in the order Cs{sup +}>NH{sub 4}{sup +}>K{sup +}>Ca{sup 2+}>Na{sup +}. Chlorine was not retained by mineral soil samples, and the sorption was weak on humus. The sorption of iodine was the strongest on humus and the weakest on the untreated mineral soil samples in the anaerobic conditions. In the mineral soil samples, the sorption decreased with decreasing organic matter content and increasing pH. The retention of niobium on soil samples was the most efficient among the studied elements. The retention was high regardless of the aeration conditions. Sorption on humus was smaller. Selenium was retained efficiently on humus. Sorption on mineral soil samples was stronger in aerobic conditions. Sorption increased with time. Technetium was sorbed well on humus and anaerobic, untreated mineral soil samples. Sorption increased with increasing organic matter content and decreasing redox potential. The results from the sorption experiments are used in the site specific radionuclide migration modelling. (orig.)
Directory of Open Access Journals (Sweden)
G. Shangytbayeva
2015-08-01
Full Text Available This study discusses the problem distributed network attacks, formalized of model of linear kind for differentiate distributed network attacks on the basis of a weight coefficients Structured the formalized mathematical models allow to consider structure of the On network to a basis big percent, a measure of influence of each type of attack that gives the fine chance effectively to design to protect information system taking into account information on threats. Based on classification of information threats, characteristic for distributed network attacks it is offered the formalized models of a linear look for differentiation of attacks on the basis of a method of weight coefficients. By these indicators and coefficients it is possible to define the main types of threats in computer systems allowing to design effectively systems of information security taking into account information threats.
Directory of Open Access Journals (Sweden)
Mei-Yu LEE
2014-11-01
Full Text Available This paper investigates the effect of the nonzero autocorrelation coefficients on the sampling distributions of the Durbin-Watson test estimator in three time-series models that have different variance-covariance matrix assumption, separately. We show that the expected values and variances of the Durbin-Watson test estimator are slightly different, but the skewed and kurtosis coefficients are considerably different among three models. The shapes of four coefficients are similar between the Durbin-Watson model and our benchmark model, but are not the same with the autoregressive model cut by one-lagged period. Second, the large sample case shows that the three models have the same expected values, however, the autoregressive model cut by one-lagged period explores different shapes of variance, skewed and kurtosis coefficients from the other two models. This implies that the large samples lead to the same expected values, 2(1 – ρ0, whatever the variance-covariance matrix of the errors is assumed. Finally, comparing with the two sample cases, the shape of each coefficient is almost the same, moreover, the autocorrelation coefficients are negatively related with expected values, are inverted-U related with variances, are cubic related with skewed coefficients, and are U related with kurtosis coefficients.
Distribution coefficients for the sorption of Th, U, Np, Pu, and Am on Opalinus Clay
Energy Technology Data Exchange (ETDEWEB)
Amayri, Samer; Froehlich, Daniel R.; Kaplan, Ugras; Trautmann, Norbert; Reich, Tobias [Mainz Univ. (Germany). Inst. of Nuclear Chemistry
2016-04-01
The distribution coefficients (K{sub d}) are determined for the sorption of Th(IV), U(VI), Np(V), Pu(III/IV/VI), and Am(III) in the system natural Opalinus Clay (OPA) from Mont Terri, Switzerland, and synthetic OPA pore water at pH 7.6 as a function of solid-to-liquid ratio and element concentration. A linear sorption behavior under the chosen experimental conditions was obtained. The K{sub d} values strongly depend on the oxidation state of the actinide. The K{sub d} values for the tri- and tetravalent actinides are in the range of 29-159 m{sup 3}/kg. U and Np in the oxidation states six and five, respectively, are weakly sorbed on OPA with K{sub d} values of 0.04-0.05 m{sup 3}/kg. The K{sub d} values for the redox-stable Am(III) and Th(IV) are in the same range as for Pu(III) and Pu(IV) which are redox sensitive. The K{sub d} value of Pu(VI) (13 ± 3 m{sup 3}/kg) is about one order of magnitude lower than the K{sub d} values of Pu(III) and Pu(IV), but still more than two orders of magnitude higher compared to the values obtained for U(VI) and Np(V). This discrepancy is attributed to the partial reduction of Pu(VI) to Pu(IV) during sorption.
DEFF Research Database (Denmark)
Jeong, Cheol-Ho
2009-01-01
Most acoustic measurements are based on an assumption of ideal conditions. One such ideal condition is a diffuse and reverberant field. In practice, a perfectly diffuse sound field cannot be achieved in a reverberation chamber. Uneven incident energy density under measurement conditions can cause...... discrepancies between the measured value and the theoretical random incidence absorption coefficient. Therefore the angular distribution of the incident acoustic energy onto an absorber sample should be taken into account. The angular distribution of the incident energy density was simulated using the beam...... the theoretical absorption coefficient and the reverberation room measurement. The angle-weighted absorption coefficient, together with the size correction, agrees satisfactorily with the measured absorption data by the reverberation chamber method. At high frequencies and for large samples, the averaged...
Spectral distribution of the transmission coefficients of gold films on barrier-layer photocells
Energy Technology Data Exchange (ETDEWEB)
Dobrozhanskii, Yu.A.; Presnov, V.A.; Konovalenko, L.D.
1975-01-01
The transmission coefficient of a gold film (10 to 50 nm) deposited on semiconductors Ge, GaP, InAs, and InP was determined as a function of wavelength in the wavelength range between 200 and 1610 nm. It was calculated from experimental data on the transmission and reflection coefficients of gold on quartz. The gold films were prepared by thermal evaporation in a vacuum of 10/sup -5/ torr at a deposition rate of 0.3 nm/sec. The effect of technological conditions on the transmission coefficient is evaluated.
Robustness of the Distribution Theory of the Product Moment Correlation Coefficient.
Kraemer, Helena Chmura
1980-01-01
The robustness of hypothesis tests for the correlation coefficient under varying conditions is discussed. The effects of violations of the assumptions of linearity, homoscedasticity, and kurtosis are examined. (JKS)
Liu, Guangliang; Cai, Yong
2010-11-01
The complexation of arsenic (As) with dissolved organic matter (DOM), although playing an important role in regulating As mobility and transformation, is poorly characterized, as evidenced by scarce reporting of fundamental parameters of As-DOM complexes. The complexation of arsenite (AsIII) with Aldrich humic acid (HA) at different pHs was characterized using a recently developed analytical technique to measure both free and DOM-bound As. Conditional distribution coefficient (KD), describing capacity of DOM in binding AsIII from the mass perspective, and apparent stability constant (Ks), describing stability of resulting AsIII-DOM complexes, were calculated to characterize AsIII-DOM complexation. LogKD of AsIII ranged from 3.7 to 2.2 (decreasing with increase of As/DOM ratio) at pH 5.2, from 3.6 to 2.6 at pH 7, and from 4.3 to 3.2 at pH=9.3, respectively. Two-site ligand binding models can capture the heterogeneity of binding sites and be used to calculate Ks by classifying the binding sites into strong (S1) and weak (S2) groups. LogKs for S1 sites are 7.0, 6.5, and 5.9 for pH 5.2, 7, and 9.3, respectively, which are approximately 1-2 orders of magnitude higher than for weak S2 sites. The results suggest that AsIII complexation with DOM increases with pH, as evidenced by significant spikes in concentrations of DOM-bound AsIII and in KD values at pH 9.3. In contrary to KD, logKs decreased with pH, in particular for S1 sites, probably due to the presence of negatively charged H2AsO3- and the involvement of metal-bridged AsIII-DOM complexation at pH 9.3.
Malinowski, Z.; Telejko, T.; Cebo-Rudnicka, A.; Szajding, A.; Rywotycki, M.; Hadała, B.
2016-09-01
The industrial rolling mills are equipped with systems for controlled water cooling of hot steel products. A cooling rate affects the final mechanical properties of steel which are strongly dependent on microstructure evolution processes. In case of water jets cooling the heat transfer boundary condition can be defined by the heat transfer coefficient. In the present study one and three dimensional heat conduction models have been employed in the inverse solution to heat transfer coefficient. The inconel plate has been heated to about 900oC and then cooled by one, two and six water jets. The plate temperature has been measured by 30 thermocouples. The heat transfer coefficient distributions at plate surface have been determined in time of cooling.
Wang, Y. B.; Xu, Y.; Zhang, Y.; Song, G. F.; Chen, L. H.
2012-12-01
We calculated the coupling coefficient of different types of laterally coupled distributed feedback (LC-DFB) structures with coupled-wave theory and the two-dimensional semivectorial finite difference method. Effects neglected in previous studies such as other partial waves, the ohmic contact and metal contact layers are taken into account in this calculation. The LC-DFB structure with metal gratings is especially studied due to its advantage over index-coupled structures. The dependence of coupling coefficient on structure parameters is theoretically calculated such as grating order, ridge width, thickness of the residual cladding layer, grating depth and lateral proximity of gratings to the ridge waveguide. A complex-coupled GaSb-based 2 µm LC-DFB structure is optimized to achieve a high coupling coefficient of 14.5 cm-1.
Xie, Jinchuan; Lin, Jianfeng; Zhou, Xiaohua; Li, Mei; Zhou, Guoqing
2014-03-01
The traditional sorption experiments commonly treated the colloid-associated species of low-solubility contaminants as immobile species resulted from the centrifugation or ultrafiltration, and then solid/liquid distribution coefficients (Ks/d) were determined. This may lead to significantly underestimated mobility of the actinides in subsurface environments. Accordingly, we defined a new distribution coefficient (Ks/d+c) to more adequately describe the mobile characteristics of colloidal species. The results show that under alkaline aqueous conditions the traditional Ks/d was 2-3 orders of magnitude larger than the Ks/d+c involving the colloidal species of (239)Pu. The colloid/liquid distribution coefficients Kc/d≫0 (∼10(6)mL/g) revealed strong competition of the colloidal granite particles with the granite grains for Pu. The distribution percentages of Pu in the three-phase systems, depending on various conditions such as particle concentrations, Na(+) concentrations, pH and time, were determined. Moreover, we developed the thermodynamic and kinetic complexation models to explore the interaction of Pu with the particle surfaces.
On the construction of bivariate exponential distributions with an arbitrary correlation coefficient
DEFF Research Database (Denmark)
Bladt, Mogens; Nielsen, Bo Friis
In this paper we use a concept of multivariate phase-type distributions to define a class of bivariate exponential distributions. This class has the following three appealing properties. Firstly, we may construct a pair of exponentially distributed random variables with any feasible correlation...... the exponential random vectors....
On the Construction of Bivariate Exponential Distributions with an Arbitrary Correlation Coefficient
DEFF Research Database (Denmark)
Bladt, Mogens; Nielsen, Bo Friis
2010-01-01
In this article we use the concept of multivariate phase-type distributions to define a class of bivariate exponential distributions. This class has the following three appealing properties. Firstly, we may construct a pair of exponentially distributed random variables with any feasible correlation...... the exponential random vectors....
Forsyth, Peter; McGilvray, Matthew; Gillespie, David R. H.
2017-01-01
This paper reports an experimental and numerical study of the development and coupling of aerodynamic flows and heat transfer within a model ribbed internal cooling passage to provide insight into the development of secondary flows. Static instrumentation was installed at the end of a long smooth passage and used to measure local flow features in a series of experiments where ribs were incrementally added upstream. This improves test turnaround time and allows higher-resolution heat transfer coefficient distributions to be captured, using a hybrid transient liquid crystal technique. A composite heat transfer coefficient distribution for a 12-rib-pitch passage is reported: notably the behaviour is dominated by the development of the secondary flow in the passage throughout. Both the aerodynamic and heat transfer test data were compared to numerical simulations developed using a commercial computational fluid dynamics solver. By conducting a number of simulations it was possible to interrogate the validity of the underlying assumptions of the experimental strategy; their validity is discussed. The results capture the developing size and strength of the vortical structures in secondary flow. The local flow field was shown to be strongly coupled to the enhancement of heat transfer coefficient. Comparison of the experimental and numerical data generally shows excellent agreement in the level of heat transfer coefficient predicted, though the numerical simulations fail to capture some local enhancement on both the ribbed and smooth surfaces. Where this was the case, the coupled flow and heat transfer measurements were able to identify missing velocity field characteristics.
Pinkel, I Irving; Serafini, John S; Gregg, John L
1952-01-01
The modifications in the pressure distributions and the aerodynamic coefficients associated with additions of heat to the two-dimensional supersonic in viscid flow field adjacetnt to the lower surface of of a 5-percent-thickness symmetrical circular-arc wing are presented in this report. The pressure distributions are obtained by the use of graphical method which gives the two-dimensional supersonic inviscid flow field obtained with moderate heat addition. The variation is given of the lift-drag ratio and of the aerodynamic coefficients of lift, drag, and moment with free stream Mach number, angle of attack, and parameters defining extent and amount of heat addition. The six graphical solutions used in this study included Mach numbers of 3.0 and 5.0 and angles of attack of 0 degrees and 2 degrees.
Institute of Scientific and Technical Information of China (English)
Liu Xiao-Bei; Li Biao
2011-01-01
We present three families of soliton solutions to the generalized (3+1)-dimensional nonlinear Schr(o)dinger equation with distributed coefficients. We investigate the dynamics of these solitons in nonlinear optics with some selected parameters.Different shapes of bright solitons,a train of bright solitons and dark solitons are observed.The obtained results may raise the possibilities of relevant experiments and potential applications.
Directory of Open Access Journals (Sweden)
Rada Somkhuean
2017-01-01
Full Text Available This paper presents an upper bound for each of the generalized p values for testing the one population variance, the difference between two population variances, and the ratio of population variances for lognormal distribution when coefficients of variation are known. For each of the proposed generalized p values, we derive a closed form expression of the upper bound of the generalized p value. Numerical computations illustrate the theoretical results.
Effect of current density on distribution coefficient of solute at solid-liquid interface
Institute of Scientific and Technical Information of China (English)
常国威; 王自东; 吴春京; 胡汉起
2003-01-01
When current passes through the solid-liquid interface, the growth rate of crystal, solid-liquid interfaceenergy and radius of curvature at dendritic tip will change. Based on this fact, the theoretical relation between thedistribution of solute at solid-liquid interface and current density was established, and the effect of current on thedistribution coefficient of solute through effecting the rate of crystal growth, the solid-liquid interface energy and theradius of curvature at the dendritic tip was discussed. The results show that as the current density increases, thedistribution coefficient of solute tends to rise in a whole, and when the former is larger than about 400 A/cm2 , thelatter varies significantly.
Directory of Open Access Journals (Sweden)
José Gabriel Vieira Neto
2016-04-01
Full Text Available ABSTRACT Widely disseminated in both national and international scenarios, greenhouses are agribusiness solutions which are designed to allow for greater efficiency and control of the cultivation of plants. Bearing this in mind, the construction of greenhouses should take into consideration the incidence of wind, and other such aspects of comfort and safety, and ensure they are factored into the design of structural elements. In this study, we evaluated the effects of pressure coefficients established by the European standard EN 13031-1 (2001 and the Brazilian standard ABNT (1988, which are applicable to the structures of greenhouses with flat roofs, taking into account the following variables: roof slope, external and internal pressure coefficients and height-span ratio of the structure. Using the ANSYSTM computer program, zones of columns and roof were discretized by the Beam44 finite element to identify the maximum and minimum stress portions connected to the aerodynamic coefficients. With this analysis, we found that, in the smallest roof slope (a equal to 20°, the frame stress was quite similar for standards adopted. On the other hand, for the greatest inclination (a equal to 26°, the stress was consistently lower under the Brazilian standard. In view of this, we came to the conclusion that the differences between stresses when applying both standards were more significant at the higher degrees of height-span ratio and roof slope.
Panin, V Y; Aykac, M; Casey, M E
2013-06-07
The simultaneous PET data reconstruction of emission activity and attenuation coefficient distribution is presented, where the attenuation image is constrained by exploiting an external transmission source. Data are acquired in time-of-flight (TOF) mode, allowing in principle for separation of emission and transmission data. Nevertheless, here all data are reconstructed at once, eliminating the need to trace the position of the transmission source in sinogram space. Contamination of emission data by the transmission source and vice versa is naturally modeled. Attenuated emission activity data also provide additional information about object attenuation coefficient values. The algorithm alternates between attenuation and emission activity image updates. We also proposed a method of estimation of spatial scatter distribution from the transmission source by incorporating knowledge about the expected range of attenuation map values. The reconstruction of experimental data from the Siemens mCT scanner suggests that simultaneous reconstruction improves attenuation map image quality, as compared to when data are separated. In the presented example, the attenuation map image noise was reduced and non-uniformity artifacts that occurred due to scatter estimation were suppressed. On the other hand, the use of transmission data stabilizes attenuation coefficient distribution reconstruction from TOF emission data alone. The example of improving emission images by refining a CT-based patient attenuation map is presented, revealing potential benefits of simultaneous CT and PET data reconstruction.
de Winter, Joost C F; Gosling, Samuel D; Potter, Jeff
2016-09-01
The Pearson product–moment correlation coefficient (rp) and the Spearman rank correlation coefficient (rs) are widely used in psychological research. We compare rp and rs on 3 criteria: variability, bias with respect to the population value, and robustness to an outlier. Using simulations across low (N = 5) to high (N = 1,000) sample sizes we show that, for normally distributed variables, rp and rs have similar expected values but rs is more variable, especially when the correlation is strong. However, when the variables have high kurtosis, rp is more variable than rs. Next, we conducted a sampling study of a psychometric dataset featuring symmetrically distributed data with light tails, and of 2 Likert-type survey datasets, 1 with light-tailed and the other with heavy-tailed distributions. Consistent with the simulations, rp had lower variability than rs in the psychometric dataset. In the survey datasets with heavy-tailed variables in particular, rs had lower variability than rp, and often corresponded more accurately to the population Pearson correlation coefficient (Rp) than rp did. The simulations and the sampling studies showed that variability in terms of standard deviations can be reduced by about 20% by choosing rs instead of rp. In comparison, increasing the sample size by a factor of 2 results in a 41% reduction of the standard deviations of rs and rp. In conclusion, rp is suitable for light-tailed distributions, whereas rs is preferable when variables feature heavy-tailed distributions or when outliers are present, as is often the case in psychological research.
Directory of Open Access Journals (Sweden)
D. P. Siu
2011-01-01
Full Text Available In this work, a class of multidimensional stochastic hybrid dynamic models is studied. The system under investigation is a first-order linear nonhomogeneous system of Itô-Doob type stochastic differential equations with switching coefficients. The switching of the system is governed by a discrete dynamic which is monitored by a non-homogeneous Poisson process. Closed-form solutions of the systems are obtained. Furthermore, the major part of the work is devoted to finding closed-form probability density functions of the solution processes of linear homogeneous and Ornstein-Uhlenbeck type systems with jumps.
Directory of Open Access Journals (Sweden)
Hideo Deguchi
2011-06-01
Full Text Available It is well-known that distributional solutions to the Cauchy problem for $u_t + (b(t,xu_{x} = 0$ with $b(t,x = 2H(x-t$, where H is the Heaviside function, are non-unique. However, it has a unique generalized solution in the sense of Colombeau. The relationship between its generalized solutions and distributional solutions is established. Moreover, the propagation of singularities is studied.
Zhang, Jiaoshi; Chen, Zhenyi; Lu, Yihuai; Gui, Huaqiao; Liu, Jianguo; Liu, Wenqing; Wang, Jie; Yu, Tongzhu; Cheng, Yin; Chen, Yong; Ge, Baozhu; Fan, Yu; Luo, Xisheng
2017-01-01
During the 2014 Asia-Pacific Economic Cooperation (APEC) conference period, Beijing's air quality was greatly improved as a result of a series of tough emission control measures being implemented in Beijing and its surrounding provinces. However, a moderate haze occurred during the period of 4-5 November. In order to evaluate the emission control measures and study the formation mechanism of the haze, a comprehensive field observation based on a supersite and a lidar network was carried out from 25 October 2014 to 20 January 2015. By investigating the variations in aerosol number concentration and mean backscattering coefficient before, during and after the APEC period, it was found that number concentration of accumulation mode and coarse mode particles experienced the most significant decrease by 47% and 68%, and mean backscattering coefficient below 1 km decreased by 34% during the APEC period. Being characterized as "rapidly accumulating and rapidly dispersing", the moderate haze occurred during the APEC period was probably initiated by a wind direction change to south and an increase of wind speed to 4 m/s. Sulfur dioxide involved plume nucleation without growth in size as well as a burst of particles ranging between 100 and 300 nm were observed simultaneously during the haze episode. The elevation of sulfur dioxide concentration and particle number concentration was highly correlated with the southerly wind, signifying the contribution of regional transport. It was observed by the lidar network that the aerosol backscattering coefficient increased in sequence among three sites along the southwest pathway, suggesting that aerosols might be transported from the southwest to the northeast of Beijing with a speed of approximately 17 km/h, which agreed with the movement of air masses modeled by Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT). The dual-wavelength lidar (355 and 532 nm) observation suggested that transportation of fine particles
Determination of Distribution Coefficient of Nitrous Acid and Evaluation of Influential Factors
Institute of Scientific and Technical Information of China (English)
ZHU; Li-yang; CHEN; Yan-xin; TANG; Hong-bin; HE; Hui
2013-01-01
Nitrous acid is inevitably present in Purex process,thus,it is desired to build a HNO2 distribution model which could be incorporated into Purex computer simulation code.In this work base titration and diazotization-coupling reaction was used to determine the concentration of HNO3 and HNO2 in both
Bakoban, Rana A.
2017-08-01
The coefficient of variation [CV] has several applications in applied statistics. So in this paper, we adopt Bayesian and non-Bayesian approaches for the estimation of CV under type-II censored data from extension exponential distribution [EED]. The point and interval estimate of the CV are obtained for each of the maximum likelihood and parametric bootstrap techniques. Also the Bayesian approach with the help of MCMC method is presented. A real data set is presented and analyzed, hence the obtained results are used to assess the obtained theoretical results.
Asl, Iravan Masoudi; Abolhallaje, Masoud; Raadabadi, Mehdi; Nazari, Hamed; Nazari, Aslan; Salimi, Mohammad; Javani, Ali
2015-12-01
Fair distribution of hospital beds across various regions is a controversial subject. Resource allocation in health systems rarely has focused on those who need it most and, in addition, is often influenced by political interests. The study assesses the distribution of hospital beds in different regions in Tehran, Iran, during 2010-2012. This cross-sectional study was conducted in all regions of Tehran (22 regions) during 2010 to 2012. All hospital beds in these regions are included in the study. Data regarding populations of each region were obtained from the Statistics Center of Iran. According to the data, the total number of beds (N.B) and population (P) in 2010 (N.B=19075, P= 7585000), 2011 (N.B=21632, P= 9860500), and 2012 (N.B=21808, P=12818650). The instrument was a form, including the name of the hospital, the district in which the hospital was located, the number of staffed beds, the name of each region, and its population. Data analysis was performed using DASP software version 2.3. The results demonstrate that the Gini coefficient of distributed beds in 22 regions of Tehran was 0.46 in all three years and specifically calculated 0.4666 in 2010, 0.4658 in 2011 and 0.4652 in 2012. The Gini coefficient of beds in 22 regions of Tehran is not fair in comparison with the population of each region during the years 2010 to 2012. The results demonstrate that the distribution of beds in regions in Tehran is not fair in relation to the population of each region-and some regions had no hospitals. Therefore, it is essential for policymakers to frequently monitor this issue and investigate the fair distribution of hospital beds.
Gas-phase ozonolysis of β-ocimene: Temperature dependent rate coefficients and product distribution
Gaona-Colmán, Elizabeth; Blanco, María B.; Barnes, Ian; Teruel, Mariano A.
2016-12-01
Rate coefficients for the reaction of β-ocimene with O3 molecules have been determined over the temperature range 288-311 K at 750 Torr total pressure of nitrogen using the relative rate technique. The investigations were performed in a large volume reaction vessel using long-path in-situ Fourier transformed infrared (FTIR) spectroscopy to monitor the reactants and products. A value of k(β-ocimene + O3) = (3.74 ± 0.92) × 10-16 cm3 molecule-1 s-1 has been obtained for the reaction at 298 K. The temperature dependence of the reaction is best described by the Arrhenius expression k = (1.94 ± 0.02) × 10-14 exp [(-1181 ± 51)/T] cm3 molecule-1 s-1. In addition, a product study has been carried out at 298 K in 750 Torr of synthetic air and the following products with yields in molar % were observed: formaldehyde (36 ± 2), acetone (15 ± 1), methylglyoxal (9.5 ± 0.4) and hydroxyacetone (19 ± 1). The formation of formaldehyde can be explained by the addition of O3 to the C1sbnd C2 double bond of the β-ocimene. Addition of O3 to the C6sbnd C7 double bond leads to the formation of acetone and the CH3C·(OO·)CH3 biradical, which can through isomerization/stabilization form methylglyoxal (hydroperoxide channel) and hydroxyacetone. The formed products will contribute to the formation of PAN and derivatives in polluted environments and also the oxidation capacity of the atmosphere.
Kumar, Ashok; Thakkar, Ajit J.
2011-08-01
Dipole oscillator strength distributions (DOSDs) for ozone are constructed from experimental photoabsorption cross-sections combined with constraints provided by the Kuhn-Reiche-Thomas sum rule, the high-energy behavior of the dipole-oscillator-strength density, and molar refractivity data. A lack of photoabsorption data in the intermediate energy region from 24 to 524 eV necessitates the use of a mixture rule in that region. For this purpose, a DOSD for O2 is constructed first. The dipole properties for O2 are essentially the same as those obtained in earlier work even though most of the input data is from more recent experiments. A discrepancy is found between the refractivity data and photoabsorption data in the 10-20.6 eV range for ozone. A reliable ozone DOSD of the sort obtained for many other species remains out of reach. However, it is suggested that the true dipole properties of ozone lie between those predicted by two distributions that we present.
Spatial Distribution of the Coefficient of Variation for the Paleo-Earthquakes in Japan
Nomura, S.; Ogata, Y.
2015-12-01
Renewal processes, point prccesses in which intervals between consecutive events are independently and identically distributed, are frequently used to describe this repeating earthquake mechanism and forecast the next earthquakes. However, one of the difficulties in applying recurrent earthquake models is the scarcity of the historical data. Most studied fault segments have few, or only one observed earthquake that often have poorly constrained historic and/or radiocarbon ages. The maximum likelihood estimate from such a small data set can have a large bias and error, which tends to yield high probability for the next event in a very short time span when the recurrence intervals have similar lengths. On the other hand, recurrence intervals at a fault depend on the long-term slip rate caused by the tectonic motion in average. In addition, recurrence times are also fluctuated by nearby earthquakes or fault activities which encourage or discourage surrounding seismicity. These factors have spatial trends due to the heterogeneity of tectonic motion and seismicity. Thus, this paper introduces a spatial structure on the key parameters of renewal processes for recurrent earthquakes and estimates it by using spatial statistics. Spatial variation of mean and variance parameters of recurrence times are estimated in Bayesian framework and the next earthquakes are forecasted by Bayesian predictive distributions. The proposal model is applied for recurrent earthquake catalog in Japan and its result is compared with the current forecast adopted by the Earthquake Research Committee of Japan.
Directory of Open Access Journals (Sweden)
Leonid Berezansky
2003-02-01
Full Text Available We study a scalar delay differential equation with a bounded distributed delay, $$ dot{x}(t+ int_{h(t}^t x(s,d_s R(t,s - int_{g(t}^t x(s,d_s T(t,s=0, $$ where $R(t,s$, $T(t,s$ are nonnegative nondecreasing in $s$ for any $t$, $$ R(t,h(t=T(t,g(t=0, quad R(t,s geq T(t,s. $$ We establish a connection between non-oscillation of this differential equation and the corresponding differential inequalities, and between positiveness of the fundamental function and the existence of a nonnegative solution for a nonlinear integral inequality that constructed explicitly. We also present comparison theorems, and explicit non-oscillation and oscillation results. In a separate publication (part II, we will consider applications of this theory to differential equations with several concentrated delays, integrodifferential, and mixed equations.
Robin, M. J. L.; Sudicky, E. A.; Gillham, R. W.; Kachanoski, R. G.
1991-10-01
Distribution coefficients (Kd), defined as the ratio of the concentration of solute associated with the solids to the concentration in solution, are widely used in the prediction of reactive solute transport. With the advent of stochastic approaches to describe solute transport, there is a need to examine the spatial distribution of Kd, and its correlation with the hydraulic conductivity (K). Distribution coefficients were measured in triplicates for strontium on 1279 subsamples of cores from Canadian Forces Base Borden for which K measurements were available. The Kd values ranged from 4.4 to 29.8 mL/g, with a mean of 9.9 and standard deviation of 2.89 mL/g. The standard error on the triplicate means was 0.95 mL/g or approximately 10% of the mean. The spatial behavior of Kd and K (expressed as In (Kd) and ln (K)) was examined in three directions: horizontally along two orthogonal transects and vertically. The two variables each behaved nearly identically in the two horizontal directions, suggesting horizontal isotropy. Horizontally, ln (Kd) appeared as "white noise" suggesting that the horizontal spacing between cores (1 m) was too large to detect any self-correlation. The distribution coefficient displayed increasing power spectral density with increasing scale in the vertical direction, while In (K) showed these trends in all directions. Depending on the model used, the, correlation lengths obtained by least squares fits of the power spectra varied from 1 to 7.5 m horizontally and from 10 to 30 cm vertically for ln (K); and from 30 cm to 2 m horizontally and from 30 to 70 cm vertically for ln (Kd). The ln (Kd) values showed a significant but very weak negative overall correlation with ln (K) at the 99.95% confidence level. The cross-spectral and coherency analysis showed that the sign and degree of correlation between ln (Kd) and ln (K) depended on the scale and direction considered. The correlations in all directions and at all scales were weak, and could not
Pourmand, A.; Dauphas, N.
2008-03-01
Distribution coefficients for 60 elements on TODGA resin are presented along with a robust single-column protocol for separation of HSFE, lanthanides and actinides in meteorites and terrestrial rocks for high-precision isotope analysis.
Prediction of cyclohexane-water distribution coefficients with COSMO-RS on the SAMPL5 data set
Klamt, Andreas; Eckert, Frank; Reinisch, Jens; Wichmann, Karin
2016-11-01
The Conductor-Like-Screening-Model for Real Solvents (COSMO-RS) method has been used for the blind prediction of cyclohexane-water distribution coefficients logD within the SAMPL challenge. The partition coefficient logP of the neutral species was calculated first and then corrected for dissociation or protonation, as appropriate for acidic or basic solutes, to obtain the cyclohexane-water logD. Using the latest version of the COSMO therm implementation, this approach in combination with a rigorous conformational sampling yielded a predictive accuracy of 2.11 log units (RMSD) for the 53 compounds of the blind prediction dataset. By that it was the most accurate of all contest submissions and it also achieved the best rank order. The RMSD mainly arises from a group of outliers in the negative logD range, which at least partly may arise from dimerization or other experimental problems coming up for very polar molecules in very non-polar solvents.
DEFF Research Database (Denmark)
Ruzzante, D.E.; Hansen, Michael Møller; Meldrup, Dorte
2001-01-01
We examined polymorphism at seven microsatellite loci in 4023 brown trout (Salmo trutta) collected from 32 tributaries to the Limfjord, Denmark (similar to 200 km) and from two hatcheries used for stocking. Populations differ in their estimated sizes and stocking histories. Mean individual...... inbreeding coefficients do not differ among locations within rivers. Relatedness varies between sites within rivers indicating varied local dynamics at a very small geographical scale. Relatedness is sometimes lower than expected among an equal number of simulated individuals with randomized genotypes...... is true of the eastern, more heavily stocked, area of the Limfjord. Here, a higher proportion of the genetic variance is distributed among locations within rivers than among rivers. Assignment tests reveal that the majority of trout (mean 77% of all fish) are more probably of local origin than hatchery...
Institute of Scientific and Technical Information of China (English)
无
2006-01-01
In this paper, primary manufacturing and assembling errors of three-ring gear reducer (TRGR) are analyzed. TRGR is a new transmission type whose eccentric phase difference between middle ring plate and side ring plates is 120°. Its mass of middle ring plate is equal to that of side ring plate or 180°, and its mass of middle ring plate is twice of that of side ring plate, which affects load distribution between ring plates. The primary manufacturing and assembling errors include eccentric error of eccentric sheath Em, internal gear plate Er and output external gear Eic. A new theoretical method is presented in this paper, which converts load on ring plates into the dedendum bending stress of ring plate to calculate load distribution coefficient ( LDC ), by means of gap elenent method (GEM), one of finite element method (FEM). The theoretical calculation and experimental study, which measures ring plate dedendum bending stress by means of sticking strain gauges on the dedendum of middle ring plate internal gear and side ring plate internal gears, are presented. The theoretical calculation and comparison with experiment result of LDC are implemented on two kinds of three-ring gear reducers whose eccentric phase difference between eccentric sheaths is 120° and 180° respectively. The research indicates that the result of theoretical calculation is consistent with that of experimental study. That is to say, the theoretical calculation method is feasible.
Sato, K.
2015-12-01
Friction coefficients along faults control the brittle strength of the earth's upper crust, although it is difficult to estimate them especially of ancient geological faults. Several previous studies tried to determine the friction coefficient of meso-scale faults from their orientation distribution as follows. Fault-slip analysis through stress tensor inversion techniques gives principal stress axes and a stress ratio, which allows us to draw a normalized Mohr's circle. Assuming that a faulting occurs when the ratio of shear stress to normal stress on it, i.e., the slip tendency, exceeds the friction coefficient, one can find a linear boundary of distribution of points corresponding to faults on Mohr diagram. The slope of the boundary (friction envelope) provides the friction coefficient. This method has a difficulty in graphically and manually recognizing the linear boundary of distribution on the Mohr diagram. This study automated the determination of friction coefficient by considering the fluctuations of fluid pressure and differential stress. These unknown factors are expected to make difference in density of points representing faults on the Mohr diagram. Since the density is controlled by the friction coefficient, we can optimize the friction coefficient so as to explain the density distribution. The method was applied to two examples of natural meso-scale faults. The first example is from the Pleistocene Kazusa Group, central Japan, which filled a forearc basin of the Sagami Trough. Stress inversion analysis showed WNW-ENE trending tensional stress with a low stress ratio. The friction coefficient was determined to be around 0.66, which is typical value for sandstone. The Second example is from an underplated tectonic mélange in the Cretaceous to Paleogene Shimanto accretionary complex in southwest Japan along the Nankai Trough. The stress condition was determined to be an axial compression perpendicular to the foliation of shale matrix. The friction
Tourell, Monique C.; Shokoohmand, Ali; Landgraf, Marietta; Holzapfel, Nina P.; Poh, Patrina S. P.; Loessner, Daniela; Momot, Konstantin I.
2017-02-01
Diffusion-weighted magnetic resonance imaging (DW-MRI) was used to evaluate the effects of single-agent and combination treatment regimens in a spheroid-based animal model of ovarian cancer. Ovarian tumour xenografts grown in non-obese diabetic/severe-combined-immunodeficiency (NOD/SCID) mice were treated with carboplatin or paclitaxel, or combination carboplatin/paclitaxel chemotherapy regimens. After 4 weeks of treatment, tumours were extracted and underwent DW-MRI, mechanical testing, immunohistochemical and gene expression analyses. The distribution of the apparent diffusion coefficient (ADC) exhibited an upward shift as a result of each treatment regimen. The 99-th percentile of the ADC distribution (“maximum ADC”) exhibited a strong correlation with the tumour size (r2 = 0.90) and with the inverse of the elastic modulus (r2 = 0.96). Single-agent paclitaxel (n = 5) and combination carboplatin/paclitaxel (n = 2) treatment regimens were more effective in inducing changes in regions of higher cell density than single-agent carboplatin (n = 3) or the no-treatment control (n = 5). The maximum ADC was a good indicator of treatment-induced cell death and changes in the extracellular matrix (ECM). Comparative analysis of the tumours’ ADC distribution, mechanical properties and ECM constituents provides insights into the molecular and cellular response of the ovarian tumour xenografts to chemotherapy. Increased sample sizes are recommended for future studies. We propose experimental approaches to evaluation of the timeline of the tumour’s response to treatment.
Rodbard, David
2012-10-01
We describe a new approach to estimate the risks of hypo- and hyperglycemia based on the mean and SD of the glucose distribution using optional transformations of the glucose scale to achieve a more nearly symmetrical and Gaussian distribution, if necessary. We examine the correlation of risks of hypo- and hyperglycemia calculated using different glucose thresholds and the relationships of these risks to the mean glucose, SD, and percentage coefficient of variation (%CV). Using representative continuous glucose monitoring datasets, one can predict the risk of glucose values above or below any arbitrary threshold if the glucose distribution is Gaussian or can be transformed to be Gaussian. Symmetry and gaussianness can be tested objectively and used to optimize the transformation. The method performs well with excellent correlation of predicted and observed risks of hypo- or hyperglycemia for individual subjects by time of day or for a specified range of dates. One can compare observed and calculated risks of hypo- and hyperglycemia for a series of thresholds considering their uncertainties. Thresholds such as 80 mg/dL can be used as surrogates for thresholds such as 50 mg/dL. We observe a high correlation of risk of hypoglycemia with %CV and illustrate the theoretical basis for that relationship. One can estimate the historical risks of hypo- and hyperglycemia by time of day, date, day of the week, or range of dates, using any specified thresholds. Risks of hypoglycemia with one threshold (e.g., 80 mg/dL) can be used as an effective surrogate marker for hypoglycemia at other thresholds (e.g., 50 mg/dL). These estimates of risk can be useful in research studies and in the clinical care of patients with diabetes.
Tourell, Monique C.; Shokoohmand, Ali; Landgraf, Marietta; Holzapfel, Nina P.; Poh, Patrina S. P.; Loessner, Daniela; Momot, Konstantin I.
2017-01-01
Diffusion-weighted magnetic resonance imaging (DW-MRI) was used to evaluate the effects of single-agent and combination treatment regimens in a spheroid-based animal model of ovarian cancer. Ovarian tumour xenografts grown in non-obese diabetic/severe-combined-immunodeficiency (NOD/SCID) mice were treated with carboplatin or paclitaxel, or combination carboplatin/paclitaxel chemotherapy regimens. After 4 weeks of treatment, tumours were extracted and underwent DW-MRI, mechanical testing, immunohistochemical and gene expression analyses. The distribution of the apparent diffusion coefficient (ADC) exhibited an upward shift as a result of each treatment regimen. The 99-th percentile of the ADC distribution (“maximum ADC”) exhibited a strong correlation with the tumour size (r2 = 0.90) and with the inverse of the elastic modulus (r2 = 0.96). Single-agent paclitaxel (n = 5) and combination carboplatin/paclitaxel (n = 2) treatment regimens were more effective in inducing changes in regions of higher cell density than single-agent carboplatin (n = 3) or the no-treatment control (n = 5). The maximum ADC was a good indicator of treatment-induced cell death and changes in the extracellular matrix (ECM). Comparative analysis of the tumours’ ADC distribution, mechanical properties and ECM constituents provides insights into the molecular and cellular response of the ovarian tumour xenografts to chemotherapy. Increased sample sizes are recommended for future studies. We propose experimental approaches to evaluation of the timeline of the tumour’s response to treatment. PMID:28220831
Yang, Yan-min; Yang, Yonghui; Han, Shu-min; Hu, Yu-kun
2009-07-01
Hebei Plain is the most important agricultural belt in North China. Intensive irrigation, low and uneven precipitation have led to severe water shortage on the plain. This study is an attempt to resolve this crucial issue of water shortage for sustainable agricultural production and water resources management. The paper models distributed regional irrigation requirement for a range of cultivated crops on the plain. Classic crop models like DSSAT- wheat/maize and COTTON2K are used in combination with pan-evaporation coefficient method to estimate water requirements for wheat, corn, cotton, fruit-trees and vegetables. The approach is more accurate than the static approach adopted in previous studies. This is because the combination use of crop models and pan-evaporation coefficient method dynamically accounts for irrigation requirement at different growth stages of crops, agronomic practices, and field and climatic conditions. The simulation results show increasing Required Irrigation Amount (RIA) with time. RIA ranges from 5.08×109 m3 to 14.42×109 m3 for the period 1986~2006, with an annual average of 10.6×109 m3. Percent average water use by wheat, fruit trees, vegetable, corn and cotton is 41%, 12%, 12%, 11%, 7% and 17% respectively. RIA for April and May (the period with the highest irrigation water use) is 1.78×109 m3 and 2.41×109 m3 respectively. The counties in the piedmont regions of Mount Taihang have high RIA while the central and eastern regions/counties have low irrigation requirement.
Energy Technology Data Exchange (ETDEWEB)
Sharma, P.K.; Knuth, E.L.
1977-12-01
Spatial and energy distributions of helium atoms scattered from an anodized 1235-0 aluminum surface as well as the tangential and normal momentum accommodation coefficients calculated from these distributions are reported. A procedure for calculating drag coefficients from measured values of spatial and energy distributions is given. The drag coefficient calculated for a 6061 T-6 aluminum sphere is included.
Straka, A. M.; Schijf, J.
2010-12-01
For proper calculation of distribution coefficients in metal sorption studies it is essential to fully separate dissolved from particulate metal. This is typically done via membrane filtration whereby the cutoff between dissolved and particulate fractions is somewhat arbitrarily set at 0.22 μm, dictated by available pore sizes. However, the pH-dependent formation of colloid-bound metal, able to bypass this procedure, can lead to analytical artifacts by adding an unknown and variable amount of particulate metal to the mechanically defined ‘dissolved’ pool, especially for organic substrates. We investigated this phenomenon in the context of yttrium and rare earth element (YREE) sorption on the marine macroalga Ulva lactuca (sea lettuce). U. lactuca is a suitable model for marine organic matter as it has a simple morphology, is ubiquitous throughout the world’s oceans, and readily sorbs a great variety of trace metals. Solutions containing all YREEs were equilibrated for 6-12 hours with dehydrated, powdered U. lactuca tissue over a wide pH range (3.0-8.5) at three ionic strengths (0.05, 0.5 and 5.0 M NaCl), after which aliquots were filtered through 0.22 μm membranes. The resulting filtrates were further separated into >30 kDa and >3 kDa colloidal fractions by sequential centrifugation in Amicon® ultrafiltration tubes. In all three experiments, YREEs are truly dissolved (30 kDa) at high pH with a sharp transition in between, suggesting pH-dependent YREE complexation with large organic ligands released by the algal cells. The fraction of small colloids (3-30 kDa) is generally negligible. The same sorption edge emerged for fresh algal tissue, implying that the release of organic ligands is not caused by pervasive cell rupture. In 0.5 and 5.0 M NaCl solutions the sorption edge is centered around pH 6-8, but in 0.05 M NaCl it occurs around pH 4-6 whence more than 80% of dissolved YREEs is actually bound to colloids at pH 6. On the other hand, the amount of
Nomura, Shunichi; Ogata, Yosihiko
2016-04-01
We propose a Bayesian method of probability forecasting for recurrent earthquakes of inland active faults in Japan. Renewal processes with the Brownian Passage Time (BPT) distribution are applied for over a half of active faults in Japan by the Headquarters for Earthquake Research Promotion (HERP) of Japan. Long-term forecast with the BPT distribution needs two parameters; the mean and coefficient of variation (COV) for recurrence intervals. The HERP applies a common COV parameter for all of these faults because most of them have very few specified paleoseismic events, which is not enough to estimate reliable COV values for respective faults. However, different COV estimates are proposed for the same paleoseismic catalog by some related works. It can make critical difference in forecast to apply different COV estimates and so COV should be carefully selected for individual faults. Recurrence intervals on a fault are, on the average, determined by the long-term slip rate caused by the tectonic motion but fluctuated by nearby seismicities which influence surrounding stress field. The COVs of recurrence intervals depend on such stress perturbation and so have spatial trends due to the heterogeneity of tectonic motion and seismicity. Thus we introduce a spatial structure on its COV parameter by Bayesian modeling with a Gaussian process prior. The COVs on active faults are correlated and take similar values for closely located faults. It is found that the spatial trends in the estimated COV values coincide with the density of active faults in Japan. We also show Bayesian forecasts by the proposed model using Markov chain Monte Carlo method. Our forecasts are different from HERP's forecast especially on the active faults where HERP's forecasts are very high or low.
DEFF Research Database (Denmark)
Poulsen, Carl Esben; Wootton, Robert C. R.; Wolff, Anders
2015-01-01
for the testing of valuable and scarce drug candidates. Herein we present a simple micro fluidic platform for the determination of distribution coefficients using droplet-based liquid-liquid extraction. For simplicity, this platform makes use of gravity to enable phase separation for analysis and is 48 times...... faster and uses 99 % less reagents than performing an equivalent measurement using the shake-flask method. Furthermore, the D measurements achieved in our platform are in good agreement with literature values measured using traditional shake-flask techniques. Since D is affected by volume ratios, we use...... the apparent acid dissociation constant, pK', as a proxy for inter-system comparison. Our platform determines a pK' value of 7.24 ± 0.15, compared to 7.25 ± 0.58 for the shake-flask method in our hands and 7.21 for the shake-flask method in literature. Devices are fabricated using injection moulding, the batch...
Darch, Jonathan; Milner, Ben; Vaseghi, Saeed
2008-12-01
The aim of this work is to develop methods that enable acoustic speech features to be predicted from mel-frequency cepstral coefficient (MFCC) vectors as may be encountered in distributed speech recognition architectures. The work begins with a detailed analysis of the multiple correlation between acoustic speech features and MFCC vectors. This confirms the existence of correlation, which is found to be higher when measured within specific phonemes rather than globally across all speech sounds. The correlation analysis leads to the development of a statistical method of predicting acoustic speech features from MFCC vectors that utilizes a network of hidden Markov models (HMMs) to localize prediction to specific phonemes. Within each HMM, the joint density of acoustic features and MFCC vectors is modeled and used to make a maximum a posteriori prediction. Experimental results are presented across a range of conditions, such as with speaker-dependent, gender-dependent, and gender-independent constraints, and these show that acoustic speech features can be predicted from MFCC vectors with good accuracy. A comparison is also made against an alternative scheme that substitutes the higher-order MFCCs with acoustic features for transmission. This delivers accurate acoustic features but at the expense of a significant reduction in speech recognition accuracy.
Energy Technology Data Exchange (ETDEWEB)
Marchesi, Marcos Vinicius A.; Hama, Naruhiko; Jacomino, Vanusa M. F.; Ladeira, Ana Claudia Q.; Cota, Stela D. S., E-mail: mvmarchesi@hotmail.com, E-mail: sdsc@cdtn.br, E-mail: vmfj@cdtn.br, E-mail: ana.ladeira@cdtn.br, E-mail: naruhikohama@hotmail.com [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil); Nascimento, Marcos Roberto Lopes do; Taddei, Maria Helena, E-mail: pmarcos@cnen.gov.br, E-mail: mhtaddei@cnen.gov.br [Comissao Nacional de Energia Nuclear (LAPOC/CNEN), Pocos de Caldas, MG (Brazil). Laboratorio de Pocos de Caldas
2013-07-01
Phosphogypsum is a byproduct from the production of phosphoric acid, and contain radionuclides, heavy metals and metalloids from phosphate rock. It represents a risk to the environment if improperly stored. Because it is composed mainly of dihydrated calcium sulphate, phosphogypsum can be used in anaerobic environments such as those found in landfills to accelerate microbial processes of decomposition of municipal solid waste and thus increase the life of these facilities. One of the options of your application being studied is the use of phosphogypsum replacing the covers of soil/clay in landfills. Besides reducing the demand for soil and clay, this application would be an alternative to disposal of the waste, since the alternatives are not sufficient for more than five million tons produced per year in Brazil. To ensure the safety of this application, the potential environmental impact of contaminants in phosphogypsum should be evaluated. The rate of leaching of contaminants are being studied by determining the coefficient of distribution of the contaminants in the phosphogypsum. Batch tests were performed by mixing different proportions of slurry and phosphogypsum. This work presents the results for the chain of uranium and natural thorium.
Energy Technology Data Exchange (ETDEWEB)
Thomas, B.L.
1984-07-01
Liquid fossil fuels, both petroleum and synthetically derived oils, are exceedingly complex mixtures of thousands of components. The effect of many of these energy-related components on the environment is largely unknown. Octanol/water distribution coefficients relate both to toxicity and to the bioaccumulation potential of chemical components. Use of these partition data in conjunction with component concentrations in the oils in environmental models provides important information on the fate of fossil fuel components when released to the environment. Octanol/water distribution data are not available for many energy-related organic compounds, and those data that are available have been determined for individual components in simple, one-component octanol/water equilibrium mixtures. In this study, methods for determining many octanol/water distribution coefficients from aqueous extracts of oil products were developed. Sample aqueous mixtures were made by equilibrating liquid fossil fuels with distilled water. This approach has the advantage of detecting interactions between components of interest and other sample components. Compound types studied included phenols, nitrogen bases, hydrocarbons, sulfur heterocyclic compounds, and carboxylic acids. Octanol/water distribution coefficients that were determined in this study ranged from 9.12 for aniline to 67,600 for 1,2-dimethylnaphthalene. Within a compound type, distribution coefficients increased logarithmically with increasing alkyl substitution and molecular weight. Additionally, oil/water distribution data were determined for oil components. These data are useful in predicting maximum environmental concentrations in water columns. 96 references, 26 figures, and 40 tables.
Lee, S I; Oh, S G
1999-01-01
Amorphous titanium dioxide thin films were deposited onto silicon substrates by using RF magnetron sputtering, and the index of refraction, the extinction coefficient, and the void distribution of these films were simultaneously determined from the analyses of there ellipsometric spectra. In particular, our novel strategy, which combines the merits of multi-sample fitting, the dual dispersion function, and grid search, was proven successful in determining optical constants over a wide energy range, including the energy region where the extinction coefficient was large. Moreover, we found that the void distribution was dependent on the deposition conditions, such as the sputtering power, the substrate temperature, and the substrate surface.
Energy Technology Data Exchange (ETDEWEB)
Nash, Charles A. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Hamm, L. Larry [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Smith, Frank G. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); McCabe, Daniel J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)
2014-12-19
The primary treatment of the tank waste at the DOE Hanford site will be done in the Waste Treatment and Immobilization Plant (WTP) that is currently under construction. The baseline plan for this facility is to treat the waste, splitting it into High Level Waste (HLW) and Low Activity Waste (LAW). Both waste streams are then separately vitrified as glass and poured into canisters for disposition. The LAW glass will be disposed onsite in the Integrated Disposal Facility (IDF). There are currently no plans to treat the waste to remove technetium, so its disposition path is the LAW glass. Due to the water solubility properties of pertechnetate and long half-life of ^{99}Tc, effective management of ^{99}Tc is important to the overall success of the Hanford River Protection Project mission. To achieve the full target WTP throughput, additional LAW immobilization capacity is needed, and options are being explored to immobilize the supplemental LAW portion of the tank waste. Removal of ^{99}Tc, followed by off-site disposal, would eliminate a key risk contributor for the IDF Performance Assessment (PA) for supplemental waste forms, and has potential to reduce treatment and disposal costs. Washington River Protection Solutions (WRPS) is developing some conceptual flow sheets for supplemental LAW treatment and disposal that could benefit from technetium removal. One of these flowsheets will specifically examine removing ^{99}Tc from the LAW feed stream to supplemental immobilization. To enable an informed decision regarding the viability of technetium removal, further maturation of available technologies is being performed. This report contains results of experimental ion exchange distribution coefficient testing and computer modeling using the resin SuperLig^{®} 639^{a} to selectively remove perrhenate from high ionic strength simulated LAW. It is advantageous to operate at higher concentration in order to treat the waste
Confidence Intervals for the Coefficient of Variation for the Normal Distribution%正态分布变差系数的置信区间
Institute of Scientific and Technical Information of China (English)
孙祝岭
2009-01-01
A problem of the estimation of the coefficient of variation for the normal distribution was discussed. A new pivotal variable to construct the classical confidence intervals for the coefficient of variation was given. And precision confidence intervals for the coefficient of variation of the normal distribution with a simple expression were also obtained.%研究正态分布的变差系数估计问题.提出了一个新的枢轴量来构造变差系数的经典置信区间,给出了正态分布变差系数的具有简单表达式的精确置信区间.
Ertas, Gokhan; Onaygil, Can; Akin, Yasin; Kaya, Handan; Aribal, Erkin
2016-12-01
To investigate the accuracy of diffusion coefficients and diffusion coefficient ratios of breast lesions and of glandular breast tissue from mono- and stretched-exponential models for quantitative diagnosis in diffusion-weighted magnetic resonance imaging (MRI). We analyzed pathologically confirmed 170 lesions (85 benign and 85 malignant) imaged using a 3.0T MR scanner. Small regions of interest (ROIs) focusing on the highest signal intensity for lesions and also for glandular tissue of contralateral breast were obtained. Apparent diffusion coefficient (ADC) and distributed diffusion coefficient (DDC) were estimated by performing nonlinear fittings using mono- and stretched-exponential models, respectively. Coefficient ratios were calculated by dividing the lesion coefficient by the glandular tissue coefficient. A stretched exponential model provides significantly better fits then the monoexponential model (P correlation was found in diffusion coefficients (0.99-0.81 and coefficient ratios (0.94) between the models. The highest diagnostic accuracy was found by the DDC ratio (area under the curve [AUC] = 0.93) when compared with lesion DDC, ADC ratio, and lesion ADC (AUC = 0.91, 0.90, 0.90) but with no statistically significant difference (P > 0.05). At optimal thresholds, the DDC ratio achieves 93% sensitivity, 80% specificity, and 87% overall diagnostic accuracy, while ADC ratio leads to 89% sensitivity, 78% specificity, and 83% overall diagnostic accuracy. The stretched exponential model fits better with signal intensity measurements from both lesion and glandular tissue ROIs. Although the DDC ratio estimated by using the model shows a higher diagnostic accuracy than the ADC ratio, lesion DDC, and ADC, it is not statistically significant. J. Magn. Reson. Imaging 2016;44:1633-1641. © 2016 International Society for Magnetic Resonance in Medicine.
On Relations Between Gini Coefficient and Inhabitants Personal Income Distribution%论基尼系数与居民个人收入分配的关系
Institute of Scientific and Technical Information of China (English)
周德海
2012-01-01
学术界通常以基尼系数的大小，作为衡量居民个人收入分配是否公平的依据，是对基尼系数与居民个人收入分配之间关系的误解。一个国家基尼系数的大小，与这个国家居民的个人收入分配是否公平没有关系。马克思经济学的等价交换原则是衡量居民个人收入分配是否公平的客观标准。%Equality, equity and justice can not include the relations between Gini coefficient and inhabitants'per- sonal income distribution fully. There never any equal income distribution throughout the history of human socie- ty, for which the meaning of equality in such concepts as equal or unequal distribution is unclear. Although distri- bution of social wealth represented by Gini coefficient is determined by inhabitants'personal income distribution, Gini coefficient cant reflect a definite inhabitants'personal income distribution is fair or unfair. Only exchange of equal values in a system of market economy is fair.
López, R.; Lecuona, A.; Ventas, R.; Vereda, C.
2012-11-01
In Plate Heat Exchangers it is important to determine the flow distribution and pressure drops, because they affect directly the performance of a heat exchanger [1]. This work proposes an incompressible, one-dimensional, steady state, discrete model allowing for variable overall momentum coefficients to determine these magnitudes. The model consists on a modified version of the Bajura and Jones [2] model for dividing and combining flow manifolds. The numerical procedure is based on the finite differences approximation approach proposed by Datta and Majumdar [3]. A linear overall momentum coefficient distribution is used in the dividing manifold, but the model is not limited to linear distributions. Comparisons are made with experimental, numerical and analytical data, yielding good results.
论基尼系数与居民个人收入分配的关系%Study on Relation Between Gini Coefficient and Income Distribution
Institute of Scientific and Technical Information of China (English)
周德海
2012-01-01
In the academic circle,Gini Coefficient is usually viewed as measurement for equality or inequality in income distribution. Such a concept is a misunderstanding of the relationship between Gini Coefficient and income distribution, a low or high Gini Coefficient doesn't necessarily represent whether income distribution is equal or inequal.The principle of exchange of equal value is the objective standard in measuring whether income distribution is equal or inequal.%学术界通常以基尼系数的大小作为衡量居民个人收入分配是否公平的依据,这是对基尼系数与居民个人收入分配之间关系的误解。一个国家基尼系数的大小,与这个国家居民的个人收入分配是否公平没有关系。马克思经济学的等价交换原则是衡量居民个人收入分配是否公平的客观标准。
Zareitalabad, P; Siemens, J; Hamer, M; Amelung, W
2013-05-01
The sorption of perfluorinated compounds (PFCs) to soils and sediments determines their fate and distribution in the environment, but there is little consensus regarding distribution coefficients that should be used for assessing the environmental fate of these compounds. Here we reviewed sorption coefficients for PFCs derived from laboratory experiments and compared these values with the gross distribution between the concentrations of PFCs in surface waters and sediments or between wastewater and sewage sludge. Sorption experiments with perfluorooctanesulfonic acid (PFOS) and perfluorooctanoic acid (PFOA) suggest that their sorption can be described reasonably well as a partitioning-like process with an average log K(oc) of approximately 2.8 for PFOA and 3.0 for PFOS. However, median concentrations in sediments (PFOA, 0.27 ng g(-1); PFOS, 0.54 ng g(-1)) or sewage sludge (PFOA, 37 ng g(-1); PFOS, 69 ng g(-1)) in relation to median concentrations in surface water (PFOA, 3ngl(-1); PFOS, 3ngl(-1)) or wastewater treatment effluent (PFOA, 24 ng l(-1); PFOS, 11 ng l(-1)), suggest that effective log K(oc) distribution coefficients for the field situation may be close to 3.7 for PFOA and 4.2 for PFOS. Applying lab-based log K(oc) distribution coefficients can therefore result in a serious overestimation of PFC concentrations in water and in turn to an underestimation of the residence time of PFOA and PFOS in contaminated soils. Irrespective of the dissipation kinetics, the majority of PFOA and PFOS from contaminated soils will be transported to groundwater and surface water bodies.
Energy Technology Data Exchange (ETDEWEB)
Iwai, Yoshio [Kyushu University, Fukuoka (Japan); Kakizaka, Keijiro; Shindo, Takashi; Ishida, Otetsu; Arai, Yasuhiko
1999-01-05
Distribution coefficients of five kinds of amino acids (aspartic acid, asparagines, methionine, cysteine and cytidine) and two kinds of peptides (glycylglycine and hexane glycine) were measured. These distribution coefficients are in good correlation with the osmosis viral expression. The interaction parameter in the osmosis viral expression can be estimated by hydrophilic group parameter. The distribution coefficient of {alpha}-amylase was estimated by the osmosis viral expression using the above-mentioned hydrophilic group parameter, and the estimated value showed substantially good correspondence with the actually measured value, but for the distribution coefficient of {beta}-amylase, no coincidence was found. (translated by NEDO)
Energy Technology Data Exchange (ETDEWEB)
Choi, Myung Soo; Yang, Kyong Uk [Chonnam National University, Yeosu (Korea, Republic of); Kondou, Takahiro [Kyushu University, Fukuoka (Japan); Bonkobara, Yasuhiro [University of Miyazaki, Miyazaki (Japan)
2016-03-15
We developed a method for analyzing the free vibration of a structure regarded as a distributed system, by combining the Wittrick-Williams algorithm and the transfer dynamic stiffness coefficient method. A computational algorithm was formulated for analyzing the free vibration of a straight-line beam regarded as a distributed system, to explain the concept of the developed method. To verify the effectiveness of the developed method, the natural frequencies of straight-line beams were computed using the finite element method, transfer matrix method, transfer dynamic stiffness coefficient method, the exact solution, and the developed method. By comparing the computational results of the developed method with those of the other methods, we confirmed that the developed method exhibited superior performance over the other methods in terms of computational accuracy, cost and user convenience.
Directory of Open Access Journals (Sweden)
Vinod Kumar Verma
2014-08-01
Full Text Available Resource utilization requires a substantial consideration for a trust and reputation model to be deployed within a wireless sensor network (WSN. In the evaluation, our attention is focused on the effect of hops coefficient factor estimation on WSN with bio-inspired trust and reputation model (BTRM. We present the state-of-the-art system level evaluation of accuracy and path length of sensor node operations for their current and average scenarios. Additionally, we emphasized over the energy consumption evaluation for static, dynamic and oscillatory modes of BTRM-WSN model. The performance of the hops coefficient factor for our proposed framework is evaluated via analytic bounds and numerical simulations.
Institute of Scientific and Technical Information of China (English)
王文才; 王鑫宙; 赵婧雯
2016-01-01
通过分析煤田火区地表下沉量和破碎岩块孔隙率的关系，对地表下沉量进行测量，分析计算得到火区破碎岩块孔隙率的分布方程。在实验室中测量不同孔隙率破碎岩块的渗透系数，拟合建立渗透系数和孔隙率的关系方程，利用求得的关系方程和通过地表下沉量测量法得到的孔隙率分布方程，求得煤田火区塌陷区破碎岩块的渗透系数分布方程。%This paper analyzes the relation between the surface subsidence and broken rock porosity of coalfield fire area ,to measure the surface subsidence and find out the distribution equation of broken rock porosity in fire area .ln the laboratory measurement ,the permeability coefficient of broken rock with different porosity is measured ,to fit and set up the relationship equation between the permeability coefficient and porosity and the distribution equation of subsidence permeability coefficient of broken rock in coalfild fire area is found out by using the obtained relationship equation and porosity distribution equation from surface subsidence measurement .
Satoh, Akira; Ozaki, Masataka
2006-06-15
We have investigated the influence of the magnetic field strength, shear rate, and rotational Brownian motion on transport coefficients such as viscosity and diffusion coefficient, and also on the orientational distributions of rodlike particles of a dilute colloidal dispersion. The rodlike particle is modeled as a magnetic spheroidal particle which has a magnetic moment normal to the particle axis; such a particle may typically be a hematite particle. In the present study, an external magnetic field is applied in the direction normal to the shear plane of a simple shear flow. The basic equation of the orientational distribution function has been derived from the balance of torques and solved numerically. The results obtained here are summarized as follows. Although the orientational distribution function shows a sharp peak in the shear flow direction for a very strong magnetic field, such a peak is not restricted to the field direction alone, but continues in every direction of the shear plane. This is due to the characteristic particle motion that the particle can rotate around the axis of the magnetic moment in the shear plane, although the magnetic moment nearly points to the magnetic field direction. This particle motion in the shear plane causes negative values of the viscosity due to the magnetic field. The viscosity decreases, attains a minimum value, and then converges to zero as the field strength increases. Additionally, the diffusion coefficient is significantly influenced by such characteristic particle motion in the shear plane for a strong magnetic field.
2009-09-01
and Fe hydroxides) until an approximate equilibrium is achieved between particulate and aqueous phases as: 2dC (2) where Cp2 = the soil...adsorbed inorganic P pool (M·M-1; Barrow 1983; Van Riemsdijk et al. 1984). In general, Cp2 represents a small fraction of the total adsorbed inorganic P...3) where ρ = the soil density (M·L-3). Cd2 and Cp2 are related to an equilibrium partition coefficient as: 2 2p dC k C (4) where kd2 = the
Liu, Lei; Tian, Bo; Zhen, Hui-Ling; Wu, Xiao-Yu; Shan, Wen-Rui
2017-02-01
Under investigation in this paper is a three-dimensional Gross-Pitaevskii equation with the distributed time-dependent coefficients, which describes the phenomena associated with the three-dimensional Bose-Einstein condensation. Under the constraint α(t) = 2 β(t) , we obtain the bilinear forms, dark and bright N-soliton solutions via the Hirota method and symbolic computation, where t is the scaled time, α(t) and β(t) are the coefficients for the strength of the quadratic potential and diffraction, respectively. Specially, compared with the bright soliton solutions previously reported, we eliminate one constraint and obtain more soliton parameters. We give the existence constraints of the dark and bright N solitons, respectively. Choosing the diffraction and gain/loss coefficients, we observe the growth, decay, periodic oscillation, periodic collapse and revival of the dark and bright solitons. Relationships between the BEC time-dependent coefficients and soliton properties are studied. With the help of the asymptotic and graphic analysis, elastic interactions of the dark and bright two solitons are exhibited.
Bao, Quan-Ying; Liu, Ai-Yun; Ma, Yu; Chen, Huan; Hong, Jin; Shen, Wen-Bin; Zhang, Can; Ding, Ya
2016-10-01
The shape, size, and surface features of nanoparticles greatly influence the structure and properties of resulting hybrid nanosystems. In this work, gold nanoparticles (GNPs) were modified via S-Au covalent bonding by glycol monomethyl ether thioctate with poly(ethylene glycol) methyl ether of different molecular weights (i.e., 350, 550, and 750Da). These modified GNPs (i.e., GNP350, GNP550, and GNP750) showed different oil-water partition coefficients (Kp), as detected using inductively coupled plasma-atomic emission spectroscopy. The different Kp values of the gold conjugates (i.e., 13.98, 2.11, and 0.036 for GNP350, GNP550, and GNP750, respectively) resulted in different conjugate localization within liposomes, as observed by transmission electron microscopy. In addition, the cellular uptake of hybrid liposomes co-encapsulating gold conjugates and Nile red was evaluated using intracellular fluorescence intensity. The results indicated that precise GNP localization in the hydrophilic or hydrophobic liposome cavity could be achieved by regulating the GNP oil-water partition coefficient via surface modification; such localization could further affect the properties and functions of hybrid liposomes, including their cellular uptake profiles. This study furthers the understanding not only of the interaction between liposomes and inorganic nanoparticles but also of adjusting liposome-gold hybrid nanostructure properties via the surface chemistry of gold materials.
Wei, Wenjuan; Mandin, Corinne; Blanchard, Olivier; Mercier, Fabien; Pelletier, Maud; Le Bot, Barbara; Glorennec, Philippe; Ramalho, Olivier
2016-06-01
Particle/gas and dust/gas partition coefficients (Kp and Kd) are two key parameters that address the partitioning of semi-volatile organic compounds (SVOCs) between gas-phase, airborne particles, and settled dust in indoor environment. A number of empirical equations to calculate the values of Kp and Kd have been reported in the literature. Therefore, the difficulty lies in the selection of a specific empirical equation in a given situation. In this study, we retrieved from the literature 38 empirical equations for calculating Kp and Kd values from the SVOC saturation vapor pressure and octanol/air partition coefficient. These values were calculated for 72 SVOCs: 9 phthalates, 9 polybrominated diphenyl ethers (PBDEs), 11 polychlorinated biphenyls (PCBs), 22 biocides, 14 polycyclic aromatic hydrocarbons (PAHs), 3 alkylphenols, 2 synthetic musks, tributylphosphate, and bisphenol A. The mean and median values of log10Kp or log10Kd for most SVOCs were of the same order of magnitude. The distribution of log10Kp values was fitted to either a normal distribution (for 27 SVOCs) or a log-normal distribution (for 45 SVOCs). This work provides a reference distribution of the log10Kp for 72 SVOCs, and its use may reduce the bias associated with the selection of a specific value or equation.
Modified Biserial Correlation Coefficients.
Kraemer, Helena Chmura
1981-01-01
Asymptotic distribution theory of Brogden's form of biserial correlation coefficient is derived and large sample estimates of its standard error obtained. Its relative efficiency to the biserial correlation coefficient is examined. Recommendations for choice of estimator of biserial correlation are presented. (Author/JKS)
Directory of Open Access Journals (Sweden)
Tarek Hassan Mohamed
2015-12-01
Full Text Available This paper presented both the linear quadratic Gaussian technique (LQG and the coefficient diagram method (CDM as load frequency controllers in a multi-area power system to deal with the problem of variations in system parameters and load demand change. The full states of the system including the area frequency deviation have been estimated using the Kalman filter technique. The efficiency of the proposed control method has been checked using a digital simulation. Simulation results indicated that, with the proposed CDM + LQG technique, the system is robust in the face of parameter uncertainties and load disturbances. A comparison between the proposed technique and other schemes is carried out, confirming the superiority of the proposed CDM + LQG technique.
DEFF Research Database (Denmark)
Larsen, Thomas; Kjeldsen, Peter; Christensen, Thomas Højlund
1992-01-01
area of the aquifer materials as a second regression parameter did not significantly improve the correlation. Estimated Koc values were up to 3 times higher than those predicted from regression equations based on the octanol-water partition coefficient. The reason for this is not known, but may...... by the distribution coefficient, Kd, since the isotherms were linear: Kd(benzene): 0.05–0.65, Kd(TCA): 0.04–0.55, and Kd(naphthalene): 0.1–15.7 ml/g. Correlating observed Kd values to the organic carbon content of the aquifer materials explained only 52–65 % of the variance in Kd. Introducing the specific surface...
Wang, Luyun; Li, Lu; Li, Zhonghao; Zhou, Guosheng; Mihalache, Dumitru
2005-09-01
The generalized nonlinear Schrödinger model with distributed dispersion, nonlinearity, and gain or loss is considered and the explicit, analytical solutions describing the dynamics of bright solitons on a continuous-wave background are obtained in quadratures. Then, the generation, compression, and propagation of pulse trains are discussed in detail. The numerical results show that solitons can be compressed by choosing the appropriate control fiber system, and pulse trains generated by modulation instability can propagate undistorsted along fibers with distributed parameters by controlling appropriately the energy of each pulse in the pulse train.
Stockmann, M; Schikora, J; Becker, D-A; Flügge, J; Noseck, U; Brendler, V
2017-08-23
One natural retardation process to be considered in risk assessment for contaminants in the environment is sorption on mineral surfaces. A realistic geochemical modeling is of high relevance in many application areas such as groundwater protection, environmental remediation, or disposal of hazardous waste. Most often concepts with constant distribution coefficients (Kd-values) are applied in geochemical modeling with the advantage to be simple and computationally fast, but not reflecting changes in geochemical conditions. In this paper, we describe an innovative and efficient method, where the smart Kd-concept, a mechanistic approach mainly based on surface complexation modeling, is used (and modified for complex geochemical models) to calculate and apply realistic distribution coefficients. Using the geochemical speciation code PHREEQC, multidimensional smart Kd-matrices are computed as a function of varying (or uncertain) environmental conditions. On the one hand, sensitivity and uncertainty statements for the distribution coefficients can be derived. On the other hand, smart Kd-matrices can be used in reactive transport (or migration) codes (not shown here). This strategy has various benefits: (1) rapid computation of Kd-values for large numbers of environmental parameter combinations; (2) variable geochemistry is taken into account more realistically; (3) efficiency in computing time is ensured, and (4) uncertainty and sensitivity analysis are accessible. Results are presented exemplarily for the sorption of uranium(VI) onto a natural sandy aquifer material and are compared to results based on the conventional Kd-concept. In general, the sorption behavior of U(VI) in dependence of changing geochemical conditions is described quite well. Copyright © 2017 Elsevier Ltd. All rights reserved.
Yue, G. K.; Deepak, A.
1984-01-01
A method of retrieving aerosol size distribution from the measured extinction of solar radiation at wavelengths of 0.45 microns and 1.0 microns has recently been proposed. This method is utilized to obtain latitudinal and altitudinal variations of size distributions of stratospheric aerosols from the Stratospheric Aerosol and Gas Experiment data for March 1979. Small particles are found in the lower stratosphere of the tropical region, and large particles are found at higher altitudes and latitudes in both hemispheres. Results of this study are consistent with the suggestion that the upper troposphere in tropical regions is a source of condensation nuclei in the stratosphere, and they become mature as they move to higher altitudes and latitude.
DEFF Research Database (Denmark)
Ruzzante, D.E.; Hansen, Michael Møller; Meldrup, Dorte
2001-01-01
, the proportion of locally assigned trout correlates with the populations' stocking histories, with rivers presently subjected to stocking (hatchery trout) showing low mean similar to0.73), and rivers where stocking was discontinued showing high (mean similar to0.84) proportions of local fish, probably reflecting......We examined polymorphism at seven microsatellite loci in 4023 brown trout (Salmo trutta) collected from 32 tributaries to the Limfjord, Denmark (similar to 200 km) and from two hatcheries used for stocking. Populations differ in their estimated sizes and stocking histories. Mean individual......, suggesting structure within locations. Five per cent of the genetic variance is distributed among rivers (F-ST = 0.049), but in the western, less heavily stocked, area of the Limfjord a higher proportion of the genetic variance is distributed among rivers than among locations within rivers. The reverse...
Energy Technology Data Exchange (ETDEWEB)
Sahoo, S.K. [National Institute of Radiological Sciences (Japan); Mishra, S. [Bhabha Atomic Research Centre (India); Sorimachi, A.; Hosoda, M.; Tokonami, S. [Hirosaki University (Japan); Kritsananuwat, R. [Tokyo Metropolitan University (Japan); Ishikawa, T. [Fukushima Medical University (Japan)
2014-07-01
An extraordinary earthquake of magnitude 9.0 followed by Tsunami on 11 March 2011 caused serious nuclear accident at the Fukushima Daiichi Nuclear Power Plant (FDNPP) about 250 km north to Tokyo, capital of Japan. This resulted in radioactive contamination due to deposition of long-lived radionuclides. Contaminated soil can cause an enhanced radiation exposure even after many years. Depending upon environmental conditions radionuclides can be mobilized to aquatic systems. Therefore, the fate and transfer of these radionuclides in the soil water system is very important for radiation protection and dose assessment. In the present study, emphasis has been given on isotope ratio measurement of uranium that may give some idea about its contamination during accident. Soil and water samples were collected from contaminated areas around FDNPP. Inductively coupled plasma mass spectrometry (ICPMS) is used for total uranium concentration and thermal ionization mass spectrometry (TIMS) has been used for uranium isotopes measurement. Extraction chromatography has been used for the separation of uranium. We have observed, isotope ratio {sup 235}U/{sup 238}U is of natural origin, however in a few soil samples {sup 236}U has been detected. For the migration behavior, its distribution coefficient (K{sub d}) has been determined using laboratory batch method. Depleted uranium is used as tracer for uranium K{sub d} estimation. Chemical characterization of soil with respect to different parameters has been carried out. The effect of these soil parameters on distribution coefficient of uranium has been studied in order to explain the radionuclide mobility in this particular area. The distribution coefficient values for uranium are found to vary from 30-35679 L/Kg. A large variation in the distribution coefficient values shows the retention or mobility of uranium is highly dependent on soil characteristics in the particular area. This variation is explained with respect to pH, Fe, Mn
Liu, K F; Li, F; Tatlisumak, T; Garcia, J H; Sotak, C H; Fisher, M; Fenstermacher, J D
2001-08-01
The apparent diffusion coefficient of water (ADC) rapidly drops in ischemic tissue after cerebral artery occlusion. This acute drop is thought to be caused by the loss of extracellular fluid and the gain of intracellular fluid. To test the latter possibility, changes in ADC and the size of several cellular compartments were assessed in 3 regions of rat brain at the end of 90 minutes of focal cerebral ischemia. One middle cerebral artery was permanently occluded in 8 Sprague-Dawley rats; sham occlusions were performed in 2 other rats. ADC maps were generated 90 minutes later, and the brains were immediately perfusion fixed. Three regions of interest (ROIs) were defined on the basis of ADC range. Various neuronal, astrocytic, and capillary compartments in each ROI were quantified with light and electron microscopy. At the end of 90 minutes of ischemia, mean ADC was normal in the cortex of sham-operated rats and the contralateral cortex of ischemic rats (ROI-a), 25% lower in the ipsilateral frontoparietal cortex (ROI-b), and 45% lower in the ischemic lateral caudoputamen (ROI-c). At this time, the frequency of swollen astrocytic cell bodies and volume of swollen dendrites and astrocytic processes in neuropil were ROI-a
Kenney, Ian M.; Beckstein, Oliver; Iorga, Bogdan I.
2016-11-01
All-atom molecular dynamics simulations were used to predict water-cyclohexane distribution coefficients D_{cw} of a range of small molecules as part of the SAMPL5 blind prediction challenge. Molecules were parameterized with the transferable all-atom OPLS-AA force field, which required the derivation of new parameters for sulfamides and heterocycles and validation of cyclohexane parameters as a solvent. The distribution coefficient was calculated from the solvation free energies of the compound in water and cyclohexane. Absolute solvation free energies were computed by an established protocol using windowed alchemical free energy perturbation with thermodynamic integration. This protocol resulted in an overall root mean square error in log D_{cw} of almost 4 log units and an overall signed error of -3 compared to experimental data. There was no substantial overall difference in accuracy between simulating in NVT and NPT ensembles. The signed error suggests a systematic error but the experimental D_{cw} data on their own are insufficient to uncover the source of this error. Preliminary work suggests that the major source of error lies in the hydration free energy calculations.
Energy Technology Data Exchange (ETDEWEB)
Costea, M. [Polytechnic University of Bucharest (Romania). Dept. of Applied Thermodynamics; Feidt, M. [University H. Poincare of Nancy (France)
1998-12-31
This study aims to assess for a Stirling engine the influence of the overall heat transfer coefficient variation on the optimum state and on the optimum distribution of the heat transfer surface conductance or area among the machine heat exchangers. The analysis is based on a Stirling machine optimization method, previously elaborated, which is now applied to a cycle with total heat regeneration. The method was conceived for an irreversible cycle with heat transfer across temperature differences at the source and the sink, and heat losses between the hot-end and the cold-end of the engine. Source and sink of finite thermal capacity as well as thermostats are considered. The new approach considers a linear variation of the overall heat transfer coefficient of the machine heat exchangers with respect to the local temperature difference. A comparison of the optimum state and the optimum distribution of the heat transfer surface conductance or area among the heater and the cooler is made for several cases. (author)
Energy Technology Data Exchange (ETDEWEB)
Lahdenperae, A.-M. [Saanio and Riekkola Oy, Helsinki (Finland)
2014-04-15
The report summarises the chemical, physical and mineralogical data and the calculated 'in situ' distribution coefficients (K{sub d}) values of the indigenous elements from the different types of soil and sediment samples at the Olkiluoto Island and in the Reference area that were taken in 2010-2011. The data has been collected in order to extend the understanding of the site evolution and for radionuclide transport analyses and modelling. 'In situ' distribution coefficients, K{sub d} values are used to indicate the relevant mobility of elements and radionuclides. This report is part of the entirety of soil and sediment data from different soil types, soil layers and environmental conditions collected earlier for the biosphere site description and development. Soil and sediment samples were taken at various depths of humus, peat, gyttja, sandy/fine sandy till and cropland soils. The analyses procedure varied to some extent between the samples. In all samples were analysed pH, LOI, C, N, and the total concentrations of the elements using HNO{sub 3}-HF extraction. The 'in situ' K{sub d} values were calculated using the formula by Sheppard et al.. For selected samples the easily leachable fraction was analysed by NH{sub 4}Ac (pH 4.5). Bulk density and mineralogy was determined for a few samples. Grain size distribution was measured only from till samples. The results are discussed and the physical-chemical data and distribution coefficients of the results are presented. The cation exchange capacity and base saturation are calculated for the sandy/fine sandy till samples from Olkiluoto. The K{sub d} values of the important indigenous elements Ag, Cl, Cs, I, Mo, Ni, Se and Sr are of main interest in biosphere development due to the longest half-lives of the associated radionuclides, thus having long interaction times. The K{sub d} data are inherently extremely variable due to nature of practical quantity in question, aggregating a number of
变异系数的抽样分布及假设检验%The Sample Distribution and Hypothesis Test of Coefficient of Variation
Institute of Scientific and Technical Information of China (English)
赵彦晖; 张水若; 邢瑞芳
2011-01-01
变异系数是一项可靠性指标,它应用于既有结构的可靠性、医院统计及保险理论等方面,对变异系数进行假设检验具有现实意义.本文取自一般正态总体的子样,并利用样本均值(X-)、样本标准差S和变异系数v=σ/μ的关系构造了一种含变异系数的抽样分布Z=vX/S～z(v,n-1),同时给出了该分布的密度函数fz(z)=(n-1/2n-1/2/√πv2/2nΓ(n-1/2)∫+∞0yn-1e-1/2[(n-1)y2+(y2-1)2/r2/n]dy.本文给础一种对变异系数的小样本假设检验方法,根据该抽样分布及原假设成立的条件下确定检验统计量Z=v0X/S,然后利用统计量构造一个使备择假设成立的小概率事件,由此得出拒绝域或拒绝条件.%Coefficient of variation is a reliability index. It is widely used in evaluatiou of reliability of existing structure, hospital statistics, insurance theory and so on. Hypothesis testing of the coefficient of variation is realistic siguificance. The sample of normal distribution is extracted, according to the relationship between sample mean (X), sample standard deviation S and coefficient of variation v = σ/μ , the sample distribution of containing coefficient of variation Z = v X/S ～z( v, n - 1 ) was given in this paper, at the same time its density function fz (z) =[(n-1)/2][(n-1)/2]/√πv2/2nΓ[(n-1)/2]∫+∞0y(n-1)e(-1/2)[(n-1)y2+(yz-1)2/(r2/n)]dy is given . A way of hypothesis test of the coefficient of variation is established in small sample. Through using the sample distribution and null hypothesis, test statistics Z = vo (-X)/S is determined.Then a small probability events what makes alternative hypothes right is constructed, using this statistics. Thus rejection regions or rejection conditions are given.
Abraham, Michael H; Acree, William E; Leo, Albert J; Hoekman, David; Cavanaugh, Joseph E
2010-05-01
It is shown that log P values for water-alkane or water-cyclohexane partitions, and the corresponding Delta log P values when used as descriptors for blood-brain distribution, as log BB, yield equations with very poor correlation coefficients but very good standard deviations, S from 0.25 to 0.33 log units. Using quite large data sets, we have verified that similar S-values apply to predictions of log BB. A suggested model, based on log P for water-dodecane and water-hexadecane partition coefficients, has 109 data points and a fitted S = 0.254 log units. It is essential to include in the model an indicator variable for volatile compounds, and an indicator variable for drugs that contain the carboxylic group. A similar equation based on water-chloroform partition coefficients has 83 data points and a fitted S = 0.287 log units. We can find no causal connection between these log P values and log BB in terms of correlation or in terms of chemical similarity, but conclude that the log P descriptor will yield excellent predictions of log BB provided that predictions are within the chemical space of the compounds used to set up the model. We also show that model based on log P(octanol) and an Abraham descriptor provides a simple and easy method of predicting log BB with an error of no more than 0.31 log units. We have used the Akaike information criterion to investigate the most economic models for log BB.
Uranium-Radium Equilibrium Coefficient Distribution in Pingxiashui Area%坪下水地区铀矿石铀镭平衡系数变化特征
Institute of Scientific and Technical Information of China (English)
王家跃
2014-01-01
Uranium-radium equilibrium coefficient is an important parameter in uranium exploration. Correctly measuring and analyzing the parameter is significance to guide the uranium exploration and research of uranium metal ogenic regularity. Used of analyze data of dril core samples in PINGXIASHUI area analyzing distribution characteristics of U-Ra equilibrium coefficient that could providing references for uranium exploration in this area.%铀镭平衡系数是铀矿勘查的重要参数，正确测量、分析该参数，对指导铀矿勘查、研究铀成矿规律有重要意义，利用坪下水地区钻探岩矿心样品分析结果，综合分析研究该地区铀镭平衡系数分布特征，为坪下水地区今后铀矿勘查提供参考。
Stego-images Recognition Based on DCT Coefficients Distributing%基于DCT系数分布的含密图像识别算法
Institute of Scientific and Technical Information of China (English)
刘一均; 柴毅; 柏森; 郭茂耘
2007-01-01
A fast and effective stego-images recognition method based on statistical distributions of DCT coefficients is proposed.The approach can distinguish stego-image and cover-image.The method is tested on a diverse set of test images that include both raw and processed images in the JPEG and BMP formats.Experiment results show the superiority of our approach over other stego-images recognition techniques.%提出了一种基于DCT系数统计分布的含密图像(stego-images)和掩护图像(cover-images)的识别算法.实验表明:该算法能快速识别各种JPEG和BMP格式的基于变换域和空间域的含密图像和非含密图像,并且优于其他含密图像识别方法.
Di Pasquale, Eric; Salmi-Smail, Chanaz; Brunel, Jean-Michel; Sanchez, Patrick; Fantini, Jacques; Maresca, Marc
2010-02-01
The interaction of squalamine (SQ) with eukaryotic and prokaryotic membranes was studied and compared with the interaction of two other cationic amphipathic antimicrobials (CAAs), i.e. the antibiotic polymyxin B (PMB) and the detergent hexadecyltrimethylammonium bromide (CTAB). Whole cell experiments showed that the three CAA have in common the ability to interact with lipopolysaccharide-containing membranes through a divalent cation sensitive process. Differences were found regarding their kinetics of membrane permeabilisation and their selectivity for bacteria, with a preferential permeabilisation of bacteria by PMB>SQ and no selectivity for CTAB. Experiments with lipid monolayers and bilayers showed that this selectivity did not correlate with a preferential interaction of the CAAs with lipids but rather relies on differences in their ability to penetrate lipid bilayers and to cause electrically active lesions. Incidentally, our results also suggest that the distribution coefficient of CAAs could be used to predict their selectivity for bacteria.
Simulation study on tower distribution coefficient of transmission line%输电线路杆塔分流系数仿真计算
Institute of Scientific and Technical Information of China (English)
何智强; 李欣
2013-01-01
利用CDEGS软件针对220 kV/500 kV典型输电线路杆塔分别进行工频和雷电流模型的仿真计算，给出避雷线、杆塔地网、杆塔基础具体分流大小，分析影响杆塔分流系数的影响因素。%The simulation calculation of frequence and lightning current model are respectively conducted according to the typical 220 kV/500 kV transmission line towers by using CDEGS software. The shunt data of lightning lines tower tower grounding grid tower base are obtained and the influence factor of tower distribution coefficient are analyzed.
Directory of Open Access Journals (Sweden)
Szu-Wei Lee
2014-03-01
Full Text Available Knowledge of the discrete cosine transform coefficient distribution (DCT-DIST is important for the encoder design. For example, rate control relies on this knowledge to estimate a possible bit rate and then decide proper coding parameters before the actual encoding task is performed. Therefore the rate control performance is fairly dependent on how accurately the DCT-DIST is modelled. The spatial enhancement layer (SL DCT-DIST for H.264 scalable video coding (SVC is studied in this Letter. SL DCT-DIST knowledge is furthermore used to derive a novel rate model. Our results can help design a proper rate control module for the H.264/SVC encoder.
Cui, Wansong; Wang, Difeng; Gong, Fang; Bai, Yan; Zhang, Lin; Zhu, Qiankun; Chen, Peng
2016-10-01
The beam attenuation coefficient (c), an inherent optical property of water, can provide information about the particulate matter in the water. In this study, the vertical distribution of the particulate beam attenuation coefficient at 660 nm (cp(660)) and its correlation to the particulate organic carbon (POC) and chlorophyll a (Chl-a) concentrations in the north South China Sea (NSCS), was investigated based on the in situ data from two cruises covering the summer and autumn seasons during 2009-2010year. The results showed that in summer, the profiles of cp(660) at the near shore stations were generally well vertical mixed, except at the bottom layer where cp(660) sharply increased due to sediment resuspension. However, in the slope and basin, the profiles of cp(660) had the peak value in the subsurface layer, and the depth of maximum increased with the increasing of the water depth. The subsurface maximum of the cp(660) was corresponding to the subsurface maximum Chl-a in the shelf and basin in the NSCS in summer. In autumn, the depth profile of cp(660) was also well mixed in the near shore, similar as it in summer. In the basin, unlike the subsurface maximum in summer, cp(660) had the decreasing trend with the increasing of depth in most stations in autumn. The spatial distribution pattern of the surface cp(660) was similar in the two seasons, with high values in near shore and low values in the shelf and basin. This was mainly attributed to the river and terrigenous organic materials. There were good correlations between cp(660) and POC in both seasons, except some near shore stations with high sediment resuspension. That made the possibility of estimating the POC profile using the cp(660), and further calculating the vertical structure with satellite-derived surface POC.
Energy Technology Data Exchange (ETDEWEB)
Arvaniti, Olga S. [Water and Air Quality Laboratory, Department of Environment, University of the Aegean, University Hill, 81100 Mytilene (Greece); Laboratory of Analytical Chemistry, Department of Chemistry, University of Athens, Panepistimioupolis Zografou, 15771 Athens (Greece); Ventouri, Elpida I. [Laboratory of Analytical Chemistry, Department of Chemistry, University of Athens, Panepistimioupolis Zografou, 15771 Athens (Greece); Stasinakis, Athanasios S. [Water and Air Quality Laboratory, Department of Environment, University of the Aegean, University Hill, 81100 Mytilene (Greece); Thomaidis, Nikolaos S., E-mail: ntho@chem.uoa.gr [Laboratory of Analytical Chemistry, Department of Chemistry, University of Athens, Panepistimioupolis Zografou, 15771 Athens (Greece)
2012-11-15
Highlights: Black-Right-Pointing-Pointer Eighteen PFCs were determined in wastewater and sludge samples using LC-MS/MS. Black-Right-Pointing-Pointer PFPeA, PFOA and PFOS were the dominating compounds in both WWTPs. Black-Right-Pointing-Pointer No significant decrease or even increase of most PFCs was noticed in effluents. Black-Right-Pointing-Pointer Distribution coefficients of PFCs were calculated for different types of sludge. Black-Right-Pointing-Pointer Sorption potential was affected by the target compound and the type of sludge. - Abstract: The concentrations of eighteen perfluorinated compounds (PFCs: C5-C14 carboxylates, C4, C6-C8 and C10 sulfonates and 3 sulfonamides) were determined in wastewater and sludge samples originating from two different wastewater treatment plants (WWTPs). The analytes were extracted by solid phase extraction (dissolved phase) or sonication followed by solid phase extraction (solid phase). Qualitative and quantitative analyses were performed by LC-MS/MS. According to the results, perfluoropentanoic acid (PFPeA), perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) were dominant in wastewater and sludge samples from both plants. The average concentrations in the raw and treated wastewater ranged up to 75.7 ng L{sup -1} (perfluorotridecanoic acid, PFTrDA) and 76.0 ng L{sup -1} (PFPeA), respectively. Concentrations of most PFCs were higher in effluents than in influents, indicating their formation during wastewater treatment processes. In sewage sludge, the average concentrations ranged up to 6.7 ng g{sup -1} dry weight (PFOS). No significant seasonal variations in PFCs concentrations were observed, while higher concentrations of PFOA, PFOS and perfluorononanoic acid (PFNA) were determined in the WWTP receiving municipal and industrial wastewater. Significantly different distribution coefficient (K{sub d}) values were determined for different PFCs and different type of sludge, ranging between 169 L kg{sup -1} (PFHx
Hsieh, Min-Kai; Fu, Chung-Te; Wu, Shian-chee
2011-09-15
A simple batch method by use of refilling and nonrefilling experimental procedures and headspace solid phase microextraction was applied to simultaneously obtain the glass-water distribution coefficients (K(GW)) and polydimethylsiloxane(PDMS)-water partition coefficients (K(PW)) of hydrophobic organic compounds (HOCs). The simple batch method takes into consideration the glass-surface bound HOCs and the corresponding equilibrium distribution of HOCs among the glass, water, headspace, and polydimethylsiloxane (PDMS). The K(PW) and K(GW) values of 53 PCB congeners were determined. The glass-bound fraction predominated over other fractions for highly chlorinated PCBs. Ignoring glass adsorption and assuming a complete mass balance could thus substantially underestimate the K(PW) for HOCs in traditional work. Good linear correlations of logα (the overall mass transfer rate constant) vs logK(PW), logK(PW) vs logK(OW), and logK(GW) vs logK(OW) were observed, with logα = -0.91 logK(PW) + 1.13, R(2) = 0.93; logK(PW) = 1.032 logK(OW) - 0.493, R(2) = 0.947; and logK(GW) = 0.93 logK(OW) - 2.30, R(2) = 0.90. The K(PW) values from this study were compared with those in the literature. With an account of the glass adsorption, the accuracy of the K(PW) determination and the estimation of the dissolved concentration in water for highly hydrophobic compounds can be significantly improved.
Rights, Jason D; Sterba, Sonya K
2016-11-01
Multilevel data structures are common in the social sciences. Often, such nested data are analysed with multilevel models (MLMs) in which heterogeneity between clusters is modelled by continuously distributed random intercepts and/or slopes. Alternatively, the non-parametric multilevel regression mixture model (NPMM) can accommodate the same nested data structures through discrete latent class variation. The purpose of this article is to delineate analytic relationships between NPMM and MLM parameters that are useful for understanding the indirect interpretation of the NPMM as a non-parametric approximation of the MLM, with relaxed distributional assumptions. We define how seven standard and non-standard MLM specifications can be indirectly approximated by particular NPMM specifications. We provide formulas showing how the NPMM can serve as an approximation of the MLM in terms of intraclass correlation, random coefficient means and (co)variances, heteroscedasticity of residuals at level 1, and heteroscedasticity of residuals at level 2. Further, we discuss how these relationships can be useful in practice. The specific relationships are illustrated with simulated graphical demonstrations, and direct and indirect interpretations of NPMM classes are contrasted. We provide an R function to aid in implementing and visualizing an indirect interpretation of NPMM classes. An empirical example is presented and future directions are discussed. © 2016 The British Psychological Society.
视频三维小波分解系数的统计分析%Distributions of 3D DWT coefficients for video
Institute of Scientific and Technical Information of China (English)
金雪松
2011-01-01
The scheme of motion-compensated 3D DWT has became a research focus of video processing system.After temporal decomposition and spatial decomposition, video sequences become all kinds of subband.Encoder process data cubes which were chosen without and overlap in the spatial or temporal domains independently.This study performs two goodness-of-fit tests, the Komogorov-Smirnov (KS) and the x2 test, to determine the distribution that best fits the data cubes of the luminance components of video sequences.The results indicate that the data cubes can be well approximated by a generalized Gaussian function (GGF) distribution.Knowledge of the coefficient distributions can be used to design ratio-distortion (R-D) model and design quantizers optimized for video processing system and hence achieve better coding efficiency.%运动补偿的3D小波变换的模型已经成为视频处理系统的热点.视频序列经过时间分解和空间分解,生成不同的小波子带,小波子带分成时间和空间上相互不重叠的编码块独立编码.使用两种拟合优度方法.即KS和χ2,研究视频序列的亮度分量的编码块小波系数分布情况.实验结果表明,认为高通帧的编码块小波系数近似符合广义高斯分布是合理的.这样的认识对于率失真模型的建立和码率优化分配具有重要的作用,最终确保编码器具有更好的编码效率.
Chung, Kee-Choo; Park, Hwangseo
2016-11-01
The performance of the extended solvent-contact model has been addressed in the SAMPL5 blind prediction challenge for distribution coefficient (LogD) of drug-like molecules with respect to the cyclohexane/water partitioning system. All the atomic parameters defined for 41 atom types in the solvation free energy function were optimized by operating a standard genetic algorithm with respect to water and cyclohexane solvents. In the parameterizations for cyclohexane, the experimental solvation free energy (Δ G sol ) data of 15 molecules for 1-octanol were combined with those of 77 molecules for cyclohexane to construct a training set because Δ G sol values of the former were unavailable for cyclohexane in publicly accessible databases. Using this hybrid training set, we established the LogD prediction model with the correlation coefficient ( R), average error (AE), and root mean square error (RMSE) of 0.55, 1.53, and 3.03, respectively, for the comparison of experimental and computational results for 53 SAMPL5 molecules. The modest accuracy in LogD prediction could be attributed to the incomplete optimization of atomic solvation parameters for cyclohexane. With respect to 31 SAMPL5 molecules containing the atom types for which experimental reference data for Δ G sol were available for both water and cyclohexane, the accuracy in LogD prediction increased remarkably with the R, AE, and RMSE values of 0.82, 0.89, and 1.60, respectively. This significant enhancement in performance stemmed from the better optimization of atomic solvation parameters by limiting the element of training set to the molecules with experimental Δ G sol data for cyclohexane. Due to the simplicity in model building and to low computational cost for parameterizations, the extended solvent-contact model is anticipated to serve as a valuable computational tool for LogD prediction upon the enrichment of experimental Δ G sol data for organic solvents.
Multidimensional extremal dependence coefficients
2017-01-01
Extreme values modeling has attracting the attention of researchers in diverse areas such as the environment, engineering, or finance. Multivariate extreme value distributions are particularly suitable to model the tails of multidimensional phenomena. The analysis of the dependence among multivariate maxima is useful to evaluate risk. Here we present new multivariate extreme value models, as well as, coefficients to assess multivariate extremal dependence.
Gormley-Gallagher, Aine Marie; Douglas, Richard William; Rippey, Brian
2015-01-01
Separate phases of metal partitioning behaviour in freshwater lakes that receive varying degrees of atmospheric contamination and have low concentrations of suspended solids were investigated to determine the applicability of the distribution coefficient, KD. Concentrations of Pb, Ni, Co, Cu, Cd, Cr, Hg and Mn were determined using a combination of filtration methods, bulk sample collection and digestion and Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). Phytoplankton biomass, suspended solids concentrations and the organic content of the sediment were also analysed. By distinguishing between the phytoplankton and (inorganic) lake sediment, transient variations in KD were observed. Suspended solids concentrations over the 6-month sampling campaign showed no correlation with the KD (n = 15 for each metal, p > 0.05) for Mn (r2 = 0.0063), Cu (r2 = 0.0002, Cr (r2 = 0.021), Ni (r2 = 0.0023), Cd (r2 = 0.00001), Co (r2 = 0.096), Hg (r2 = 0.116) or Pb (r2 = 0.164). The results implied that colloidal matter had less opportunity to increase the dissolved (filter passing) fraction, which inhibited the spurious lowering of KD. The findings conform to the increasingly documented theory that the use of KD in modelling may mask true information on metal partitioning behaviour. The root mean square error of prediction between the directly measured total metal concentrations and those modelled based on the separate phase fractions were ± 3.40, 0.06, 0.02, 0.03, 0.44, 484.31, 80.97 and 0.1 μg/L for Pb, Cd, Mn, Cu, Hg, Ni, Cr and Co respectively. The magnitude of error suggests that the separate phase models for Mn and Cu can be used in distribution or partitioning models for these metals in lake water.
Kamath, Ganesh; Kurnikov, Igor; Fain, Boris; Leontyev, Igor; Illarionov, Alexey; Butin, Oleg; Olevanov, Michael; Pereyaslavets, Leonid
2016-11-01
We present the performance of blind predictions of water—cyclohexane distribution coefficients for 53 drug-like compounds in the SAMPL5 challenge by three methods currently in use within our group. Two of them utilize QMPFF3 and ARROW, polarizable force-fields of varying complexity, and the third uses the General Amber Force-Field (GAFF). The polarizable FF's are implemented in an in-house MD package, Arbalest. We find that when we had time to parametrize the functional groups with care (batch 0), the polarizable force-fields outperformed the non-polarizable one. Conversely, on the full set of 53 compounds, GAFF performed better than both QMPFF3 and ARROW. We also describe the torsion-restrain method we used to improve sampling of molecular conformational space and thus the overall accuracy of prediction. The SAMPL5 challenge highlighted several drawbacks of our force-fields, such as our significant systematic over-estimation of hydrophobic interactions, specifically for alkanes and aromatic rings.
Energy Technology Data Exchange (ETDEWEB)
Payne, Timothy E. [Australian Nuclear Science and Technology Organisation (ANSTO), Menai (Australia); Waite, T. David [School of Civil and Environmental Engineering, University of New South Wales, Sydney (Australia)
1999-07-01
The safety assessment of repositories requires models of sorption to be included in the computer codes used for predicting radionuclide migration. Typically, these codes rely on the distribution coefficient (K{sub d} value) to describe sorption. In this paper, the sorption behaviour of U is used as a case study for the development of different types of sorption models. Adsorption isotherms relate the amount of absorbed radionuclide to its dissolved concentration, but usually can not account for the effects of variables such as the pH, ionic strength or the presence of complexing ligands without adjustment of parameter values. The surface complexation model (SCM) offers a more fundamental description of sorption, but requires a large experimental data base, with systematic variation of parameters such as pH and radionuclide concentration. Model uncertainties that derive from the experimental data must be taken into account. The SCM can be used to constrain the range of radionuclide K{sub d} values that may occur in a given environment. (author)
Kumar, Ashok; Thakkar, Ajit J.
2010-02-01
The construction of the dipole oscillator strength distribution (DOSD) from theoretical and experimental photoabsorption cross sections combined with constraints provided by the Kuhn-Reiche-Thomas sum rule and molar refractivity data is a well-established technique that has been successfully applied to more than 50 species. Such DOSDs are insufficiently accurate at large photon energies. A novel iterative procedure is developed that rectifies this deficiency by using the high-energy asymptotic behavior of the dipole oscillator strength density as an additional constraint. Pilot applications are made for the neon, argon, krypton, and xenon atoms. The resulting DOSDs improve the agreement of the predicted S2 and S1 sum rules with ab initio calculations while preserving the accuracy of the remainder of the moments. Our DOSDs exploit new and more accurate experimental data. Improved estimates of dipole properties for these four atoms and of dipole-dipole C6 and triple-dipole C9 dispersion coefficients for the interactions among them are reported.
Takata, Hyoe; Tagami, Keiko; Aono, Tatsuo; Uchida, Shigeo
2014-08-15
The Fukushima Daiichi Nuclear Power Plant accident in March 2011 resulted in the release of large quantities of a long-lived radioactive strontium (i.e. (90)Sr; half-life: 28.8 y) into the coastal areas of Japan. (90)Sr release was dispersed and mixed into the water column, and will eventually be deposited into sediment. Because factors controlling seawater-sediment partitioning in the coastal marine environments are not fully understood, we developed seawater-sediment distribution coefficients, Kd (L/kg), for Sr in coastal regions of Japan by means of sediment-water partitioning experiments. (85)Sr was used as a radiotracer and conditions were designed to mimic the environmental systems of the sampling sites as closely as possible. Experimentally determined Kd values (Kd-ex) varied between 0.3 and 3.3 L/kg (mean, 1.4 L/kg), and the variation in Kd-ex was attributed to the percentage of Sr in the exchangeable fraction in the sediment. Kd-ex values were used, along with the measured concentrations of (88)Sr, a stable naturally occurring Sr isotope in seawater and sediment, to estimate the concentrations of exchangeable Sr in the sediment. Estimates ranged from 2.1 to 24.3 μg/kg, or 1.3-15.7% of the total (88)Sr concentration in the sediment. Significant correlations existed between the estimated concentrations of exchangeable Sr, and the organic matter and the oxide/hydrous oxide contents. When organic contents were greater than 0.38%, Sr binds to organic surface sites more strongly than to the other sites. Results indicate that binding of Sr to the surface of sedimentary particles was influenced by grain size, iron and manganese oxides, and organic matter. Furthermore, the information presented here could be useful to estimate Kd values for anthropogenic (90)Sr in sediment in the coastal marine environment.
Fraga, Ignacio; Cea, Luis; Puertas, Jerónimo
2013-11-01
Variability of roughness coefficients with water depth and rainfall is studied.Experimental measurements and numerical calibration are performed.Results show bed friction variations, not well captured by any standard formulation.
Energy Technology Data Exchange (ETDEWEB)
Takata, Hyoe, E-mail: takata@kaiseiken.or.jp [Marine Ecology Research Institute, Central Laboratory, Onjuku, Chiba (Japan); National Institute of Radiological Sciences, Chiba City, Chiba (Japan); Aono, Tatsuo; Tagami, Keiko; Uchida, Shigeo [National Institute of Radiological Sciences, Chiba City, Chiba (Japan)
2016-02-01
In numerical models to simulate the dispersion of anthropogenic radionuclides in the marine environment, the sediment–seawater distribution coefficient (K{sub d}) for various elements is an important parameter. In coastal regions, K{sub d} values are largely dependent on hydrographic conditions and physicochemical characteristics of sediment. Here we report K{sub d} values for 36 elements (Na, Mg, Al, K, Ca, V, Mn, Fe, Co, Ni, Cu, Se, Rb, Sr, Y, Mo, Cd, I, Cs, rare earth elements, Pb, {sup 232}Th and {sup 238}U) in seawater and sediment samples from 19 Japanese coastal regions, and we examine the factors controlling the variability of these K{sub d} values by investigating their relationships to hydrographic conditions and sediment characteristics. There was large variability in K{sub d} values for Al, Mn, Fe, Co, Ni, Cu, Se, Cd, I, Pb and Th. Variations of K{sub d} for Al, Mn, Fe, Co, Pb and Th appear to be controlled by hydrographic conditions. Although K{sub d} values for Ni, Cu, Se, Cd and I depend mainly on grain size, organic matter content, and the concentrations of hydrous oxides/oxides of Fe and Mn in sediments, heterogeneity in the surface characteristics of sediment particles appears to hamper evaluation of the relative importance of these factors. Thus, we report a new approach to evaluate the factors contributing to variability in K{sub d} for an element. By this approach, we concluded that the K{sub d} values for Cu, Se, Cd and I are controlled by grain size and organic matter in sediments, and the K{sub d} value for Ni is dependent on grain size and on hydrous oxides/oxides of Fe and Mn. - Highlights: • K{sub d}s for 36 elements were determined in 19 Japanese coastal regions. • K{sub d}s for several elements appeared to be controlled by multiple factors in sediments. • We evaluated these factors based on physico-chemical characteristics of sediments.
Energy Technology Data Exchange (ETDEWEB)
Takata, Hyoe, E-mail: takata@kaiseiken.or.jp; Tagami, Keiko; Aono, Tatsuo; Uchida, Shigeo
2014-08-15
The Fukushima Daiichi Nuclear Power Plant accident in March 2011 resulted in the release of large quantities of a long-lived radioactive strontium (i.e. {sup 90}Sr; half-life: 28.8 y) into the coastal areas of Japan. {sup 90}Sr release was dispersed and mixed into the water column, and will eventually be deposited into sediment. Because factors controlling seawater–sediment partitioning in the coastal marine environments are not fully understood, we developed seawater–sediment distribution coefficients, K{sub d} (L/kg), for Sr in coastal regions of Japan by means of sediment–water partitioning experiments. {sup 85}Sr was used as a radiotracer and conditions were designed to mimic the environmental systems of the sampling sites as closely as possible. Experimentally determined K{sub d} values (K{sub d-ex}) varied between 0.3 and 3.3 L/kg (mean, 1.4 L/kg), and the variation in K{sub d-ex} was attributed to the percentage of Sr in the exchangeable fraction in the sediment. K{sub d-ex} values were used, along with the measured concentrations of {sup 88}Sr, a stable naturally occurring Sr isotope in seawater and sediment, to estimate the concentrations of exchangeable Sr in the sediment. Estimates ranged from 2.1 to 24.3 μg/kg, or 1.3–15.7% of the total {sup 88}Sr concentration in the sediment. Significant correlations existed between the estimated concentrations of exchangeable Sr, and the organic matter and the oxide/hydrous oxide contents. When organic contents were greater than 0.38%, Sr binds to organic surface sites more strongly than to the other sites. Results indicate that binding of Sr to the surface of sedimentary particles was influenced by grain size, iron and manganese oxides, and organic matter. Furthermore, the information presented here could be useful to estimate K{sub d} values for anthropogenic {sup 90}Sr in sediment in the coastal marine environment. - Highlights: • K{sub d} for Sr were determined in Japanese coastal regions.
Institute of Scientific and Technical Information of China (English)
王德辉
2007-01-01
This paper is concerned with the distributional properties of a median unbiased estimator of ARCH(0,1) coefficient. The exact distribution of the estimator can be easily derived, however its practical calculations are too heavy to implement,even though the middle range of sample sizes. Since the estimator is shown to have asymptotic normality, asymptotic expansions for the distribution and the percentiles of the estimator are derived as the refinements. Accuracies of expansion formulas are evaluated numerically, and the results of which show that we can effectively use the expansion as a fine approximatioh of the distribution with rapid calculations. Derived expansion are applied to testing hypothesis of stationarity, and an implementation for a real data set is illustrated.
DEFF Research Database (Denmark)
Guo, Xiaoqiang; Wu, Weiyang; Chen, Zhe
2011-01-01
Synchronization with the utility networks is crucial for operating three-phase grid-interfaced converters. A challenge of synchronization is how to fast and precisely extract the fundamental positive and negative sequences under the distorted and unbalanced conditions. Many phase-locked loop (PLL......) and synchronization techniques have been presented in the past decades. Most of them make a tradeoff between the accuracy and dynamic response under severe distorted and unbalanced conditions. In this paper, a multiple-complex coefficient-filter-based PLL is presented, and its unique feature lies in the accurate...
华北地区夏玉米干物质分配系数的模拟%Simulation on Dry Matter Distribution Coefficient for Summer Maize in North China
Institute of Scientific and Technical Information of China (English)
李昊; 谭方颖; 王建林; 谭凯炎; 徐英; 王志伟
2016-01-01
干物质分配系数是驱动玉米生长发育模型的关键参数。利用2013年、2014年连续两年在山东夏津、河北固城、山西运城进行的田间试验观测资料，采用比值法、线性回归等订正方法，获取完整的玉米全生育期内生物量序列；在此基础上，以有效积温模拟的发育进程为自变量，构建了华北夏玉米干物质分配的动态变化模型。结果表明：（1）三站玉米干物质分配系数有相同的时间动态变化特征。叶片干物质分配系数从出苗开始持续减少；茎秆干物质分配系数先增后减，最大值出现在抽雄前后；穗棒干物质分配系数在玉米抽雄后持续增加，抽雄后20d左右达到1，即干物质不再向叶茎分配。（2）华北夏玉米生育期内叶、茎的干物质分配系数均可用分段式非线性模型模拟。叶的干物质分配系数以抽雄后10～15d为界，之前干物质分配系数随发育进程可用三次多项式动态模型模拟，之后变为0；茎的干物质分配系数以抽雄后20～25d为界，之前干物质分配系数随发育进程可用四次多项式动态模型模拟，之后变为0；穗棒干物质分配系数通过依据任意发育阶段叶、茎、穗棒的干物质分配系数之和为1的原则计算求得。检验结果表明华北地区夏玉米干物质分配系数动态模型模拟效果良好。%Dry matter distribution coefficient was a key parameter for driving maize growth model. Based on the field experimental data of two consecutive years (2013 and 2014) in Xiajin, Shandong province, Gucheng, Hebei province and Yuncheng, Shanxi province, the biomass sequence in the whole growth duration of maize was obtained by using the ratio method and linear regression correction method. On such a basis, the dynamic change model of dry matter distribution for summer maize in North China was established by taking the development stage of effective simulation of accumulated
Energy Technology Data Exchange (ETDEWEB)
Nagata, M. (The University of Tokushima, Tokushima (Japan))
1991-01-15
Monte Carlo simulation (MCS) was applied to the estimation of illuminance distribution in infinitely long interiors which had visual obstructions and luminous surface ceilings, and its coefficient of variation (percentage of standard deviation to average value) was studied. The illuminance distributions obtained by MCS were compared with those calculated by theoretical equations hased on teh contour integration method, and the conservation law of photon bundles was also investigated. As a result, it was concluded that MCS results of direct illuminance distributions agree with those obtained by contour integration method in infinitely long concave interiors which have luminous surface ceilings of various shapes and four visual obstructions. The coefficient of variation varies noteworthily when visual obstructions are located in asymmetrical positions. The uniformity in illuminance distributions is improved by transparent visual obstructions. The conservation law of photon bundles holds well in the concave interiors with transparent visual obstructions. Therefore, it seems that MCS technique for illuminance calculation is a very powerful tool in infinite long concave interior spaces. 19 refs., 11 figs.
Institute of Scientific and Technical Information of China (English)
陈超; 孟昭为
2016-01-01
The problem of parameter estimation with Gamma distribution occupied a very impor‐tant position in the mathematic .In this paper ,by means of moment estimation through the inde‐pendence of sample coefficient of variation ,we constructed the new estimators of shape parameter and scale parameter of Gamma distribution and estimated distribution parameters by comparing the deviation .%Gamma分布的参数估计问题在数学中占有非常重要的地位。借助矩估计通过样本变异系数独立性构造了Gamma分布的形状参数和尺度参数新的估计量，并通过比较偏差作为评价样本对估计参数下的分布效果。
Energy Technology Data Exchange (ETDEWEB)
Flyckt, V M M; Raaymakers, B W; Lagendijk, J J W [Department of Radiotherapy, University Medical Center Utrecht, Heidelberglaan 100, 3584 CX Utrecht (Netherlands)
2006-10-07
Prediction of the temperature distribution in the eye depends on how the impact of the blood flow is taken into account. Three methods will be compared: a simplified eye anatomy that applies a single heat transfer coefficient to describe all heat transport mechanisms between the sclera and the body core, a detailed eye anatomy in which the blood flow is accounted for either by the bioheat approach, or by including the discrete vasculature in the eye and the orbit. The comparison is done both for rabbit and human anatomies, normo-thermally and when exposed to homogeneous power densities. The first simplified model predicts much higher temperatures than the latter two. It was shown that the eye is very hard to heat when taking physiological perfusion correctly into account. It was concluded that the heat transfer coefficient describing the heat transport from the sclera to the body core reported in the literature for the first simplified model is too low. The bioheat approach is appropriate for a first-order approximation of the temperature distribution in the eye when exposed to a homogeneous power density, but the discrete vasculature down to 0.2 mm in diameter needs to be taken into account when the heterogeneity of the temperature distribution at a mm scale is of interest.
Flyckt, V. M. M.; Raaymakers, B. W.; Lagendijk, J. J. W.
2006-10-01
Prediction of the temperature distribution in the eye depends on how the impact of the blood flow is taken into account. Three methods will be compared: a simplified eye anatomy that applies a single heat transfer coefficient to describe all heat transport mechanisms between the sclera and the body core, a detailed eye anatomy in which the blood flow is accounted for either by the bioheat approach, or by including the discrete vasculature in the eye and the orbit. The comparison is done both for rabbit and human anatomies, normo-thermally and when exposed to homogeneous power densities. The first simplified model predicts much higher temperatures than the latter two. It was shown that the eye is very hard to heat when taking physiological perfusion correctly into account. It was concluded that the heat transfer coefficient describing the heat transport from the sclera to the body core reported in the literature for the first simplified model is too low. The bioheat approach is appropriate for a first-order approximation of the temperature distribution in the eye when exposed to a homogeneous power density, but the discrete vasculature down to 0.2 mm in diameter needs to be taken into account when the heterogeneity of the temperature distribution at a mm scale is of interest.
Institute of Scientific and Technical Information of China (English)
张奇志
2001-01-01
Wavelet transform image coding scheme is the widest used one ofimage compression approaches. The quantization of wavelet transform coefficients is a key to obtain the compression image with low bit ratios and the reconstruction image with high signal to noise ratio. To obtain the optimal quantizer,the distributions of wavelet transform coefficients for image must be determined. The purpose of the experiment is to determine the distributions of wavelet transform coefficients for image. Four standard images, named “Face”, “Girl”, “Lena” and “Panda”, are selected to study the distribution rule. The “KS” statistical tests are applied to studying the distributions of wavelet transform coefficients for images. Utilizing the Vetterli biorthogonal wavelet (L=18), the images that have size of 256×256 pels with 256 gray levels are decomposed to three level and ten subimages. The results of tests of Rayleigh assumption, Laplacian assumption and Gaussian assumption are given. The results of tests have shown that the low-pass subimages are best approximated by a Gaussian distribution and the others are best approximated by a Laplacian distribution. A simulation indicates that the Laplacian assumption of coefficients yields a higher actual output signal-to-noise ratio than the Gaussian assumption.%小波变换编码是目前研究较多的图像压缩方法，变换系数的量化是获得低比特率、高信噪比压缩图像的关键步骤。为了设计最优量化器，必须确定变换系数的分布规律。选择“Face”、“Girl”、“Lena”和“Panda”4幅标准图像数据进行统计研究，用长度L=18的Vetterli双正交小波将256灰度级256×256图像分解为3层10个子带，使用“KS”测试统计方法确定图像小波变换系数的分布规律。给出了瑞利分布、高斯分布和拉普拉斯分布假设下的“KS”测试统计结果。统计结果表明，低频部分符合高斯分布，其余部分符合拉普
Energy Technology Data Exchange (ETDEWEB)
Marsh, S.F. [Sandia National Labs., Albuquerque, NM (United States); Svitra, Z.V.; Bowen, S.M. [Los Alamos National Lab., NM (United States)
1995-01-01
Many of the radioactive waste storage tanks at U.S. Department of Energy facilities contain organic compounds that have been degraded by radiolysis and chemical reactions. In this investigation, we measured the effect of some aqueous-soluble organic compounds on the sorption of strontium, cesium, and technetium onto 18 absorbers that offer high sorption of strontium from organic-free solutions. For our test solution we used a leachate from a simulated slurry for Hanford Tank 101-SY that initially contained ethylenediaminetetraacetic acid (EDTA) and then was gamma-irradiated to 34 Mrads. We measured distribution coefficients (Kds) for each element/absorber combination for dynamic contact periods of 30 min, 2 h, and 6 h to obtain information about sorption kinetics. To facilitate comparisons, we include Kd values for these same element/absorber combinations from three organic-free simulant solutions. The Kd values for strontium sorption from the simulant that contained the degraded organics usually decreased by large factors, whereas the Kd values for cesium and technetium sorption were relatively unaffected.
Energy Technology Data Exchange (ETDEWEB)
Marsh, S.F. [Sandia National Labs., Albuquerque, NM (United States); Svitra, Z.V.; Bowen, S.M. [Los Alamos National Lab., NM (United States)
1995-04-01
Many of the radioactive waste storage tanks at U.S. Department of Energy facilities contain organic compounds that have been degraded by radiolysis and chemical reactions during decades of storage. In this second part of our three-part investigation of the effects of soluble organic complexants and their degradation products, we measured the sorption of strontium, cesium, technetium, and americium onto 32 absorbers that offer high sorption of these elements in the absence of organic complexants. The four solutions tested were (1) a simulant for a 3:1 dilution of Hanford Tank 101-SY contents that initially contained ethylenediaminetetraacetic acid (EDTA), (2) this simulant after gamma-irradiation to 34 Mrads, (3) the unirradiated simulant after treatment with a hydrothermal organic-destruction process, and (4) the irradiated simulant after hydrothermal processing. For each of 512 element/absorber/solution combinations, we measured distribution coefficients (Kds) twice for each period for dynamic contact periods of 30 min, 2 h, and 6 h to obtain information about sorption kinetics. On the basis of our 3,072 measured Kd values, the sorption of strontium and americium is significantly decreased by the organic components of the simulant solutions, whereas the sorption of cesium and technetium appears unaffected by the organic components of the simulant solutions.
Lee, Kyoung Jin; Song, Kwang Ho; Choi, Wonmin; Kim, Yeong Shik
2015-08-07
Aralia continentalis (Araliaceae) is widely used as a medicinal plant in East Asia. Previous studies have indicated that diterpenoid isomers (kaurenoic acid, continentalic acid, and ent-continentalic acid) are the major bioactive compounds of this plant. A new strategy was developed to alleviate difficulties in the separation of these isomers from this plant. A three-phase solvent system was applied to separate the isomers, and furthermore, the distribution ratio (Kc) was introduced as a substitute for the partition coefficient (KD). For compounds exhibiting a single equilibrium, their distributions in two immiscible phases were only affected by the partition coefficient of each solute. However, compounds that have a dissociating functional group (e.g., -COOH) are involved in two types of equilibrium in the two-phase system. In this case, the partitioning behaviors of the solutes are greatly affected by the pH of the solution. A mathematical prediction was applied for adjusting the solutions to the proper pH values. To prevent non-used phase (medium phase) waste, both the stationary phase (upper phase) and mobile phase (lower phase) were prepared on-demand without pre-saturation with the application of (1)H NMR. Each fraction obtained was collected and dried, yielding the following diterpenoid isomers from the 50mg injected sample: kaurenoic acid (19.7mg, yield: 39%) and ent-continentalic acid (21.3mg, yield: 42%).
Distributed Evolutionary Design of Constant-Coefficient Multipliers%常系数乘法器的分布式并行进化设计
Institute of Scientific and Technical Information of China (English)
温平川; 殷茜; 何先刚
2002-01-01
为了进一步改善进化图生成EGG(Evolutionary Graph Generation)系统的性能,我们在EGG中引入了基于PCs簇Linux计算平台并使用消息传递接口MPI(Message-Passing Interface)技术成功地实现分布式的EGG并行系统DPEGG(Distributed and Parallel EGG).实验结果充分表明DPEGG系统在生成的解质量方面略好于EGG系统.特别值得指出的是,DPEGG系统的运行时间开销还大大地减少了.
Schmieden, Kristof; The ATLAS collaboration
2016-01-01
The ATLAS collaboration has performed precision measurements sensitive to the transverse momentum of the Z/gamma* bosons, both directly through the transverse momentum of the dilepton pair and through the angular decorrelation as measured in the phi* observable. These measurements are sensitive to soft resummation effects and hard jet emissions for small and large momentum transfers, respectively, probing QCD in a unique way. The studies carried out with 20.3 /fb of data at a centerofmass energy of 8TeV probe a wide dilepton invariant mass region from 12 GeV to 150 GeV, both integrated and differential in the dilepton rapidity. The measurements are compared to a variety of resummation calculations and parton shower Monte Carlos at up to NNLO+NNLL as well as fixed order predictions at NNLO QCD including NLO electroweak corrections. The precision measurement of angular distributions of the DrellYan lepton pairs around the Zboson mass peak provide a stringent test of the underlying QCD dynamic of t...
AUTHOR|(INSPIRE)INSPIRE-00367680; The ATLAS collaboration
2016-01-01
The ATLAS collaboration has performed precision measurements sensitive to the transverse mo- mentum of the Z/γ∗ bosons, both directly through the transverse momentum of the dilepton pair and through the angular decorrelation as measured in the φ∗ observable. These measurements are sensitive to soft resummation effects and hard jet emissions for small and large momentum transfers, respectively, probing QCD in a unique way. The studies carried out with 20.3 fb−1 of data at a center-of-mass energy of 8 TeV probe a wide dilepton invariant mass region from 12 GeV to 150 GeV, both integrated and differential in the dilepton rapidity. The measurements are compared to a variety of resummation calculations and parton shower Monte Carlos at up to NNLO+NNLL as well as fixed order predictions at NNLO QCD including NLO electroweak corrections. The precision measurement of angular distributions of the Drell-Yan lepton pairs around the Z-boson mass peak provide a stringent test of the underlying QCD dynamic of the Z...
Ezhilov, Aleksei; The ATLAS collaboration
2016-01-01
The ATLAS collaboration has performed precision measurements sensitive to the transverse momentum of the Z/gamma* bosons, both directly through the transverse momentum of the di-lepton pair and through the angular decorrelation as measured in the phi* observable. These measurements are sensitive to soft resummation effects and hard jet emissions for small and large momentum transfers, respectively, probing QCD in a unique way. The studies carried out with 20.3 /fb of data at a center-of-mass energy of 8TeV probe a wide di-lepton invariant mass region from 12 GeV to 150 GeV, both integrated and differential in the di-lepton rapidity. The measurements are compared to a variety of resummation calculations and parton shower Monte Carlos at up to NNLO+NNLL as well as fixed order predictions at NNLO QCD including NLO electroweak corrections. The precision measurement of angular distributions of the Drell-Yan lepton pairs around the Z-boson mass peak provide a stringent test of the underlying QCD dynamic of the Z-bo...
Wave Reflection Coefficient Spectrum
Institute of Scientific and Technical Information of China (English)
俞聿修; 邵利民; 柳淑学
2003-01-01
The wave reflection coefficient frequency spectrum and directional spectrum for concrete face slope breakwaters and rubble mound breakwaters are investigated through physical model tests in the present study. The reflection coefficients of oblique irregular waves are analyzed by the Modified Two-Point Method (MTPM) proposed by the authors. The results show that the wave reflection coefficient decreases with increasing wave frequency and incident angle or decreasing structure slope. The reflection coefficient frequency spectrum and its variation with Iribarren number are given in this paper. The paper also suggests an empirical 3-dimensional reflection coefficient spectrum, i.e. reflection coefficient directional spectrum, which can be used to illustrate quantitatively the variation of reflection coefficient with the incident angle and the Iribarren number for oblique irregular waves.
Pu在地质介质中的分配系数及影响因素分析%Distribution Coefficient of Plutonium on Geological Medium and Factor Effect
Institute of Scientific and Technical Information of China (English)
于静; 司高华; 黄云贵; 刘勇; 贾海红; 郑军芳; 王旭辉
2011-01-01
The distribution coefficients of Pu(Ⅳ ) and Pu( Ⅴ ) between aeolian sand, sandy soil, or gravel soil and water, and of Pu(Ⅴ ) between iron or iron oxides and water were determined with batch experiments. Various factors that affect the plutonium sorption were examined, including the soil composition, the oxidation state of Pu, and the method for preparation of Pu spike solutions. The sorption of Pu(Ⅳ) in soil is found more stronger than that of Pu( Ⅴ ). Their distribution coefficients in clayey silt are in the range of 103-104 mL/g, while those of Pu( Ⅴ ) in iron oxides reach as high as 105-106 mL/g. A higher clay content in clayey silt favarites the sorption of plutonium. The method for preparation of Pu spike solutions also influences the distribution coefficient of plutonium even all other experimental conditions are kept unchanged.%用静态法实验测定了Pu(Ⅳ)和Pu(Ⅴ)在风积沙、沙黄土、沙砾石、铁及其氧化物中的分配系数,比较了Pu(Ⅳ)和Pu(Ⅴ)在几种介质上的吸附性能,并采用两种不同的Pu(Ⅳ)示踪液制备方法测定Pu(Ⅳ)在风积沙、沙黄土、沙砾石上的分配系数.结果表明,Pu(Ⅳ)和Pu(Ⅴ)在砂土中的分配系数为103～104 mL/g量级,Pu(Ⅴ)在铁及其氧化物中的分配系数为105～106mL/g量级,铁氧化物介质对Pu的吸附性最强,其次为粘土矿物含量大的介质;Pu(Ⅳ)比Pu(Ⅴ)更强的吸附在砂土上;Pu(Ⅳ)示踪液的制备采用两种不同方法时,在制备过程中Pu(Ⅳ)形成的化合物不同,其在砂土上的分配系数会随之不同.
IS THE SAMPLE COEFFICIENT OF VARIATION A GOOD ESTIMATOR FOR THE POPULATION COEFFICIENT OF VARIATION?
Mahmoudvand, Rahim; HASSANI, Hossein; Wilson, Rob
2007-01-01
In this paper, we obtain bounds for the population coefficient of variation (CV) in Bernoulli, Discrete Uniform, Normal and Exponential distributions. We also show that the sample coefficient of variation (cv) is not an accurate estimator of the population CV in the above indicated distributions. Finally we provide some suggestions based on the Maximum Likelihood Estimation to improve the population CV estimate.
Study of Dispersion Coefficient Channel
Akiyama, K. R.; Bressan, C. K.; Pires, M. S. G.; Canno, L. M.; Ribeiro, L. C. L. J.
2016-08-01
The issue of water pollution has worsened in recent times due to releases, intentional or not, of pollutants in natural water bodies. This causes several studies about the distribution of pollutants are carried out. The water quality models have been developed and widely used today as a preventative tool, ie to try to predict what will be the concentration distribution of constituent along a body of water in spatial and temporal scale. To understand and use such models, it is necessary to know some concepts of hydraulic high on their application, including the longitudinal dispersion coefficient. This study aims to conduct a theoretical and experimental study of the channel dispersion coefficient, yielding more information about their direct determination in the literature.
Park, H.; Slanger, T. G.
1994-01-01
Vibrationally excited oxygen (O‡2) is produced in the atmosphere by ozone photodissociation in the 200-300 nm Hartley band. It has been suggested that photoexcitation of O‡2 in the O2 Schumann-Runge bands will lead to predissociation, and autocatalytic production of O3. The resultant new source of atmospheric O3 could help alleviate current discrepancies between observed and modeled O3 profiles. To evaluate this possibility, we have examined two critical factors—the nascent distribution of O‡2 levels for 248 nm photodissociation, near the peak of the Hartley band, and the rate coefficients for their relaxation by O2 and N2. We find that the distribution extends to v=22, close to the thermodynamic limit, with a peak near v=8. The 300 K quenching rate coefficients have been evaluated using a cascade model, in which it is assumed that relaxation by O2 occurs through single-quantum vibration-vibration (V-V) and vibration-translation (V-T) steps. By modeling the relaxation from the top of the distribution downwards, we simultaneously obtain both the quenching rate coefficients and the nascent vibrational distribution. Agreement with new rate coefficient measurements carried out in a state-specific manner is good, as is also true for the comparison with new V-V and V-T calculations. Data from experiments on O‡2 quenching by N2 show that in the v=16-22 range, potentially important in the atmosphere, quenching proceeds up to five times faster than for the case of O2. The hypothesized explanation is that two-quantum V-V transfer, peaking at the resonant condition of O2(v=18-19), is the dominant process. As a consequence, atmospheric quenching of O‡2 for levels above v=14 is basically controlled by N2, and at low stratospheric temperatures, the effect of N2 quenching near v=18 is likely to be 2 orders of magnitude greater than quenching by O2. This unexpected effect probably precludes a significant role for O‡2 photodissociation as a new source of stratospheric
Comparing linear probability model coefficients across groups
DEFF Research Database (Denmark)
Holm, Anders; Ejrnæs, Mette; Karlson, Kristian Bernt
2015-01-01
This article offers a formal identification analysis of the problem in comparing coefficients from linear probability models between groups. We show that differences in coefficients from these models can result not only from genuine differences in effects, but also from differences in one or more...... of the following three components: outcome truncation, scale parameters and distributional shape of the predictor variable. These results point to limitations in using linear probability model coefficients for group comparisons. We also provide Monte Carlo simulations and real examples to illustrate...... these limitations, and we suggest a restricted approach to using linear probability model coefficients in group comparisons....
Institute of Scientific and Technical Information of China (English)
蔺照兰; 王汝南; 王春梅
2011-01-01
Proper distribution of waste-water-load is one of the most significant ways to manage water environment in the process of total waste-water-load control. The Gini coefficient is an index to measure equity of income distribution which derived from the Lorenz curve. A new method is established to allocate total pollutant in relation to different parts of the same river or same place using the new concept of environmental Gini coefficient. The method is applied to the case study of Wuliangsu Lake basin to achieve a distribution plan of water pollutants. In the research population,water resource and gross domestic production are used as indicators for the distribution of the Gini coefficient of study area. The rationality is evaluated by the Lorenz curves of correlative factors. The study was based on the economic condition,social and environmental systems where water resource is considered as a major restricted indicator, and finally the allocation program is drawn and optimized suggesting corresponding reduction scheme. The results indicate that the new approach can allocate total pollutant load according to the condition of each area,and the proposed scheme is more applicable and reasonable to achieve water quality standards.%在水体污染物总量控制分配中,科学合理地分配污染物排放指标是实施水体环境管理的关键.将应用在经济领域衡量居民收入分配公平程度的基尼系数引入环境领域,提出环境基尼系数这一新概念用于解决流域内各分区污染物总量控制分配的问题.以乌梁素海流域为例,分别以流域内各分区人口、水资源量和国内生产总值(GDP)作为流域内基尼系数的分配指标,绘制各分配指标与主要污染物的洛伦茨曲线.根据流域内经济、社会发展和水环境承载力的实际情况,以水资源量为主要限制指标,对该流域污染物排放总量的分配方案进行调整,同时提出相应的削减方
Transport Coefficients of Fluids
Eu, Byung Chan
2006-01-01
Until recently the formal statistical mechanical approach offered no practicable method for computing the transport coefficients of liquids, and so most practitioners had to resort to empirical fitting formulas. This has now changed, as demonstrated in this innovative monograph. The author presents and applies new methods based on statistical mechanics for calculating the transport coefficients of simple and complex liquids over wide ranges of density and temperature. These molecular theories enable the transport coefficients to be calculated in terms of equilibrium thermodynamic properties, and the results are shown to account satisfactorily for experimental observations, including even the non-Newtonian behavior of fluids far from equilibrium.
Sorption Distribution Coefficient of Pu (Ⅳ) and Pu (Ⅴ) in Sand Soil%Pu(Ⅳ)、Pu(Ⅴ)在不同质地砂土中的分配
Institute of Scientific and Technical Information of China (English)
于静; 司高华; 黄云贵; 刘东旭
2011-01-01
Pu(Ⅲ)、Pu(Ⅳ)、Pu(Ⅴ)和Pu(Ⅵ)在自然水的pH和Eh(氧化还原电势)值范围内能够共存.在自然环境中主要以Pu(Ⅴ)的PuO2(H2O)n+和Pu(Ⅳ)的Pu(OH)4形式存在.采用静态法测定了Pu(Ⅳ)和Pu(Ⅴ)在砂土介质中的分配系数Kd,Pu(Ⅳ)和Pu(Ⅴ)在砂土中的分配系数范围分别为5.5×103～4×104mL/g和3.2×103～1.1×104mL/g.表明在砂土介质中Pu(Ⅳ)的分配系数(Kd)大于Pu(Ⅴ)的,并且分配系数随砂土介质中粘土矿物含量的增加及介质颗粒粒径减小而增大.%Pu exists in four different oxidation states( Ⅲ ,Ⅳ, Ⅴ , Ⅵ) with in the Eh( Redox Potential) and pH ranges of natural environment. Pu( Ⅳ) in Pu( OH)4 form and Pu( Ⅴ ) in PuO2(H2O)n+ form are the dominant oxidation states under equilibrium conditions for groundwater compositions. The sorption distribution coefficients (Kd) of Pu (Ⅳ ) and Pu ( Ⅴ) in the sand soil were studied by batch experiments, Kd of Pu (Ⅳ) is about 5. 5 × 103 mL/g to 4 × 104 mL/g, Kd of Pu( Ⅴ) is 3. 2 × 103 mL/g to 1. 1 × 104 mL/g. In conclusion, Kd values of Pu( Ⅳ) in the sand soil were larger than those of Pu( Ⅴ ). Such distribution coefficients increase with the increase of amount of clay in sand soil and the decrease of particle size.
Energy Technology Data Exchange (ETDEWEB)
Schramm, K.W.; Oxynos, K.; Schmitzer, J. [GSF - Forschungszentrum fuer Umwelt und Gesundheit Neuherberg GmbH, Oberschleissheim (Germany). Inst. fuer Oekologische Chemie; Marth, P.; Kettrup, A. [GSF - Forschungszentrum fuer Umwelt und Gesundheit Neuherberg GmbH, Oberschleissheim (Germany). Inst. fuer Oekologische Chemie; Technische Univ. Muenchen, Freising (Germany). Lehrstuhl fuer Oekologische Chemie und Umweltanalytik; Wolf, A. [GSF - Forschungszentrum fuer Umwelt und Gesundheit GmbH, Neuherberg (Germany). Klinische Kooperationsgruppe Umweltdermatologie und Allergologie; Technische Univ. Muenchen (Germany). Klinik und Poliklinik fuer Dermatologie und Allergologie am Biederstein; Hahn, K. [GSF - Forschungszentrum fuer Umwelt und Gesundheit Neuherberg GmbH, Oberschleissheim (DE). Inst. fuer Medizinische Informatik und Systemforschung (MEDIS)
1999-09-01
Measured distribution coefficients (KL{sub M/L}) related to lipid concentrations between the muscle (C{sub ML}) and liver (C{sub LL}) tissue of two fish species (Abramis brama, Zoarces viviparus) exhibit nominal values of unity according to the relationship KL{sub M/L}=C{sub ML}/C{sub LL}=1 for persistent compounds such as highly chlorinated PCB and values above one for degradable compounds for example chlorinated cyclohexanes or DDT. The corresponding theory is presented. The relationship holds for samples for single fish as well as for pooled samples. (orig.) [German] Lipidbezogene Verteilungskoeffizienten (KL{sub M/L}) zwischen Muskelkonzentrationen- (C{sub ML}) und Leberkonzentrationen (C{sub LL}) zweier Friedfischarten Brassen (Abramis brama) und Aalmutter (Zoarces viviparus) ergeben theoriekonform (KL{sub M/L}=C{sub ML}/C{sub LL}=1) nominale Werte um 1 fuer persistente (hochchlorierte PCB) und Werte ueber 1 fuer metabolisierbare lipophile Umweltchemikalien wie chlorierte Cyclohexane oder DDT. (orig.)
On Estimation and Hypothesis Testing Problems for Correlation Coefficients
Kraemer, Helena Chmura
1975-01-01
A selection of statistical problems commonly encountered in psychological or psychiatric research concerning correlation coefficients are re-evaluated in the light of recently developed simplifications in the forms of the distribution theory of the intraclass correlation coefficient, of the product-moment correlation coefficient, and the Spearman…
Institute of Scientific and Technical Information of China (English)
章武; 李晓谦; 蒋日鹏
2016-01-01
利用激光测距仪测得铸造用超声辐射杆端面全局振幅及频率，基于 FFT 细化分析对所测振幅分析后得到辐射杆端面振幅整体分布特性，在铝熔体中，将钛板竖直置于超声辐射杆正下方，启动超声振动系统运行20 h，通过分析钛板空蚀区域探究超声在铝熔体中的空化区域，得出辐射杆的空化区域分布，空化区域为一椭球形且分界面明显，空化域最远可达变幅杆正下方68 mm，结合铝熔体中超声的空化阈值，推算出20 kHz 铸造用功率超声在铝熔体中传播的衰减系数。%The global ultrasonic amplitude and frequency of an ultrasonic radiation rod's end face was measured using a laser rangefinder,and the data obtained were analyzed by utilizing FFT zoom analysis technique to obtain the global amplitude distribution of the rod's end face.A titanium plate was placed under the ultrasonic radiation rod in molten aluminum.An ultrasonic vibration system was activated for 20 h to find the ultrasonic cavitation area in molten aluminum by analyzing the cavitation corrosion area of the titanium plate,then the caviation area distribution of the ultrasonic radiation rod was obtained.It was shown that the cavitation area of the rod is an ellipsoid with obvious boundaries,and the longest distance between the boundaries and the ultrasonic radiation rod is 68 mm.Moreover,the sound pressure attenuation coefficient of 20 kHz ultrasound was calculated with the ultrasonic cavitation threshold in molten aluminum.
Prestarlike functions with negative coefficients
Directory of Open Access Journals (Sweden)
H. Silverman
1979-01-01
Full Text Available The extreme points for prestarlike functions having negative coefficients are determined. Coefficient, distortion and radii of univalence, starlikeness, and convexity theorems are also obtained.
Directory of Open Access Journals (Sweden)
Adriana D'Agostinho
2006-07-01
Full Text Available Leaking of diesel oil from gas stations is frequent in Brazil. The presence of polycyclic aromatic hydrocarbons (PAHs, which are highly toxic is an indication of contamination by heavy hydrocarbons from diesel oil. Here were present the determination of the distribution coefficient (Kd of benzo(apyrene (the most carcinogenic of the PAHs in tropical soils using the sorption isotherm model. The sorption curves acquired for benzo(apyrene were of the S-type, probably due to the water/methanol experimental conditions. The sorption curves allowed calculation of the distribution coefficient (Kd. The experimental Kd values were lower than those calculated from literature Koc values (partition coefficient normalized by organic carbon, due mainly to the cosolvency effect and the percentage of organic matter and clay in soil.
Gorenstein Hilbert Coefficients
Khoury, Sabine El
2012-01-01
We prove upper and lower bounds for all the coefficients in the Hilbert Polynomial of a graded Gorenstein algebra $S=R/I$ with a quasi-pure resolution over $R$. The bounds are in terms of the minimal and the maximal shifts in the resolution of $R$ . These bounds are analogous to the bounds for the multiplicity found in \\cite{S} and are stronger than the bounds for the Cohen Macaulay algebras found in \\cite{HZ}.
Gini coefficient as a life table function
Directory of Open Access Journals (Sweden)
2003-06-01
Full Text Available This paper presents a toolkit for measuring and analyzing inter-individual inequality in length of life by Gini coefficient. Gini coefficient and four other inequality measures are defined on the length-of-life distribution. Properties of these measures and their empirical testing on mortality data suggest a possibility for different judgements about the direction of changes in the degree of inequality by using different measures. A new computational procedure for the estimation of Gini coefficient from life tables is developed and tested on about four hundred real life tables. The estimates of Gini coefficient are precise enough even for abridged life tables with the final age group of 85+. New formulae have been developed for the decomposition of differences between Gini coefficients by age and cause of death. A new method for decomposition of age-components into effects of mortality and composition of population by group is developed. Temporal changes in the effects of elimination of causes of death on Gini coefficient are analyzed. Numerous empirical examples show: Lorenz curves for Sweden, Russia and Bangladesh in 1995, proportional changes in Gini coefficient and four other measures of inequality for the USA in 1950-1995 and for Russia in 1959-2000. Further shown are errors of estimates of Gini coefficient when computed from various types of mortality data of France, Japan, Sweden and the USA in 1900-95, decompositions of the USA-UK difference in life expectancies and Gini coefficients by age and cause of death in 1997. As well, effects of elimination of major causes of death in the UK in 1951-96 on Gini coefficient, age-specific effects of mortality and educational composition of the Russian population on changes in life expectancy and Gini coefficient between 1979 and 1989. Illustrated as well are variations in life expectancy and Gini coefficient across 32 countries in 1996-1999 and associated changes in life expectancy and Gini
The Truth About Ballistic Coefficients
Courtney, Michael
2007-01-01
The ballistic coefficient of a bullet describes how it slows in flight due to air resistance. This article presents experimental determinations of ballistic coefficients showing that the majority of bullets tested have their previously published ballistic coefficients exaggerated from 5-25% by the bullet manufacturers. These exaggerated ballistic coefficients lead to inaccurate predictions of long range bullet drop, retained energy and wind drift.
Is coefficient alpha robust to nonnormal data?
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Yanyan eSheng
2012-02-01
Full Text Available Coefficient alpha has been a widely used measure by which internal consistency reliability is assessed. In addition to essential tau-equivalence and uncorrelated errors, normality has been noted as another important assumption for alpha. Earlier work on evaluating this assumption considered either exclusively nonnormal error score distributions, or limited conditions. In view of this and the availability of advanced methods for generating univariate nonnormal data, Monte Carlo simulations were conducted to show that nonnormal distributions for true or error scores do create problems for using alpha to estimate the internal consistency reliability. The sample coefficient alpha is affected by leptokurtic true score distributions, or skewed and/or kurtotic error score distributions. Increased sample sizes, not test lengths, help improve the accuracy, bias or precision of using it with nonnormal data.
Institute of Scientific and Technical Information of China (English)
赵新菊; 王梅; 马迎春; 左力; 许国宾; 王海燕; 陈江华; 罗琼; 余学清; 李英; 徐金生; 黄颂敏; 王力宁; 黄雯
2009-01-01
目的 探讨肾小球滤过率(GFR)估计公式中种族系数是否会受到不同研究中GFR测量值分布不同的影响.方法 本研究包括MDRD研究中的1405例白种美籍患者,321例非洲裔美国患者和中国eGFR调查研究中的684例中国CKD患者.首先,白种美籍患者和中国CKD患者的数据库合并,将GFR、年龄(age)、血肌酐(Pcr)进行log转换.令log[GFR]为应变量,log[Pcr]、log[age]、性别和种族为自变量进行线性回归,计算小加权的种族系数(uRC);然后按照白种美籍患者的CKD各期比例子中国CKD患者GFR测量值进行加权,使之与白种美籍患者的CKD分期分布一致.计算加权后的种族系数(wRC).白种美籍患者和非裔美籍患者的数据合库,使非裔美籍患者的CKD分期分布分别与中国患者和向种美籍患者一致.计算相应的种族系数.结果 中国患者的uRC为1.197(1.180～1.211),wRC为1.130(1.117-1.143).与中国患者和白种美籍患者CKD分期一致后,非裔美籍患者的种族系数则分别为1.205(1.191～1.219)和1.233(1.219-1.247).结论 用于开发GFR公式的人群的GFR测量值的分布不同可以导致种族系数的差异.为得到真正的种族系数需要国际合作,应用相同的GFR测量方法和Pcr测量方法,同时也需要GFR测量值分布一致.%Objective To illustrate if the racial coefficient (Rc) be biased by different reference GFR (rGFR) distribution among studies. Methods 1405 white and 321 African American participants in MDRD study and 684 chronic kidney disease(CKD)patients in Chinese eGFR Investigation Study were included.Firstly.the unweighted datasets of white and Chinese were stacked together.rGFR,age and plasma creatinine (Pcr) were log transformed.Linear regression model was constructed using log transformed rGFR as dependent,gender,race and log transformed Pcr and age as independent.Unweighted RC (uRC) for Chinese was calculated.Then.the Chinese CKD distribution of rGFR was weighted to be the
Bayesian Inference of Empirical Coefficient for Foundation Settlement
Institute of Scientific and Technical Information of China (English)
LI Zhen-yu; WANG Yong-he; YANG Guo-lin
2009-01-01
A new approach based on Bayesian theory is proposed to determine the empirical coefficient in soil settlement calculation. Prior distribution is assumed to be uniform in [0.2,1.4]. Posterior density function is developed in the condition of prior distribution combined with the information of observed samples at four locations on a passenger dedicated line. The results show that the posterior distribution of the empirical coefficient obeys Gaussian distribution. The mean value of the empirical coefficient decreases gradually with the increasing of the load on ground, and variance variation shows no regularity.
Converting Sabine absorption coefficients to random incidence absorption coefficients
DEFF Research Database (Denmark)
Jeong, Cheol-Ho
2013-01-01
Absorption coefficients measured by the chamber method are referred to as Sabine absorption coefficients, which sometimes exceed unity due to the finite size of a sample and non-uniform intensity in the reverberation chambers under test. In this study, conversion methods from Sabine absorption...... coefficients to random incidence absorption coefficients are proposed. The overestimations of the Sabine absorption coefficient are investigated theoretically based on Miki's model for porous absorbers backed by a rigid wall or an air cavity, resulting in conversion factors. Additionally, three optimizations...
Measuring Resource Inequality: The Gini Coefficient
Directory of Open Access Journals (Sweden)
Michael T. Catalano
2009-07-01
Full Text Available This paper stems from work done by the authors at the Mathematics for Social Justice Workshop held in June of 2007 at Middlebury College. We provide a description of the Gini coefficient and some discussion of how it can be used to promote quantitative literacy skills in mathematics courses. The Gini Coefficient was introduced in 1921 by Italian statistician Corrado Gini as a measure of inequality. It is defined as twice the area between two curves. One, the Lorenz curve for a given population with respect to a given resource, represents the cumulative percentage of the resource as a function of the cumulative percentage of the population that shares that percentage of the resource. The second curve is the line y = x which is the Lorenz curve for a population which shares the resource equally. The Gini coefficient can be interpreted as the percentage of inequality represented in the population with respect to the given resource. We propose that the Gini coefficient can be used to enhance students’ understanding of calculus concepts and provide practice for students in using both calculus and quantitative literacy skills. Our examples are based mainly on distribution of energy resources using publicly available data from the Energy Information Agency of the United States Government. For energy resources within the United States, we find that by household, the Gini coefficient is 0.346, while using the 51 data points represented by the states and Washington D.C., the Gini coefficient is 0.158. When we consider the countries of the world as a population of 210, the Gini coefficient is 0.670. We close with ideas for questions which can be posed to students and discussion of the experiences two other mathematics instructors have had incorporating the Gini coefficient into pre-calculus-level mathematics classes.
Sabine absorption coefficients to random incidence absorption coefficients
DEFF Research Database (Denmark)
Jeong, Cheol-Ho
2014-01-01
Absorption coefficients measured by the chamber method are referred to as Sabine absorption coefficients, which sometimes exceed unity due to the finite size of a specimen and non-uniform intensity in the test chamber. In this study, several methods that convert Sabine absorption coefficients...... into random incidence absorption coefficients for porous absorbers are investigated. Two optimization-based conversion methods are suggested: the surface impedance estimation for locally reacting absorbers and the flow resistivity estimation for extendedly reacting absorbers. The suggested conversion methods...
Sergievskii, V. V.; Rudakov, A. M.
2016-08-01
The model that considers the nonideality of aqueous solutions of electrolytes with allowance for independent contributions of hydration of ions of various types and electrostatic interactions was substantiated using the cluster ion model. The empirical parameters in the model equations were found to be the hydrophilic and hydrophobic hydration numbers of ions in the standard state and the dispersion of their distribution over the stoichiometric coefficients. A mathematically adequate description of the concentration dependences of the osmotic coefficients and average ion activity coefficients of electrolytes was given for several systems. The difference in the rate of the decrease in the hydrophilic and hydrophobic hydration numbers of ions leads to extremum concentration dependences of the osmotic coefficients, which were determined by other authors from isopiestic data for many electrolytes and did not find explanation.
Energy Technology Data Exchange (ETDEWEB)
Khayrullin, M.K.
1981-01-01
Formulas for calculating the influential coefficients according to pressure based on finite differences. Based on these formulas, it is shown that if the finite-difference approcimation coefficient of hydrodynamic conductibility sigmaeta satisfies the condition ..lambda..omicron..sqrt..sigmaeta-omicron..sqrt..sigmaeta= O, where ..lambda..omicron is the differential analog of the operato Laplas, then the influential coefficient is alpha st=lambdast..mu..st, where lambdast depends on the physical parameters of the layer and the liquid, and ..mu..st defines the geometry of the field and distribution of the wells. This hypothesis is also used as a method of finding a partial solution for calculating the hydrodynamic conductibility coefficient for area wells regarding finite-difference functions satisfying the condition..lambda..omicron..sqrt..sigmaeta = O.
Quadrature formulas for Fourier coefficients
Bojanov, Borislav
2009-09-01
We consider quadrature formulas of high degree of precision for the computation of the Fourier coefficients in expansions of functions with respect to a system of orthogonal polynomials. In particular, we show the uniqueness of a multiple node formula for the Fourier-Tchebycheff coefficients given by Micchelli and Sharma and construct new Gaussian formulas for the Fourier coefficients of a function, based on the values of the function and its derivatives. © 2009 Elsevier B.V. All rights reserved.
Coefficient Alpha: A Reliability Coefficient for the 21st Century?
Yang, Yanyun; Green, Samuel B.
2011-01-01
Coefficient alpha is almost universally applied to assess reliability of scales in psychology. We argue that researchers should consider alternatives to coefficient alpha. Our preference is for structural equation modeling (SEM) estimates of reliability because they are informative and allow for an empirical evaluation of the assumptions…
Measuring of heat transfer coefficient
DEFF Research Database (Denmark)
Henningsen, Poul; Lindegren, Maria
Subtask 3.4 Measuring of heat transfer coefficient Subtask 3.4.1 Design and setting up of tests to measure heat transfer coefficient Objective: Complementary testing methods together with the relevant experimental equipment are to be designed by the two partners involved in order to measure...... the heat transfer coefficient for a wide range of interface conditions in hot and warm forging processes. Subtask 3.4.2 Measurement of heat transfer coefficient The objective of subtask 3.4.2 is to determine heat transfer values for different interface conditions reflecting those typically operating in hot...
Measuring of heat transfer coefficient
DEFF Research Database (Denmark)
Henningsen, Poul; Lindegren, Maria
Subtask 3.4 Measuring of heat transfer coefficient Subtask 3.4.1 Design and setting up of tests to measure heat transfer coefficient Objective: Complementary testing methods together with the relevant experimental equipment are to be designed by the two partners involved in order to measure...... the heat transfer coefficient for a wide range of interface conditions in hot and warm forging processes. Subtask 3.4.2 Measurement of heat transfer coefficient The objective of subtask 3.4.2 is to determine heat transfer values for different interface conditions reflecting those typically operating in hot...
Improvement of Similarity Measure： Pearson Product-Moment Correlation Coefficient
Institute of Scientific and Technical Information of China (English)
LIUYong-suo; MENGQing-hua; CHENRong; WANGJian-song; JIANGShu-min; HUYu-zhu
2004-01-01
Aim To study the reason of the insensitiveness of Pearson preduct-moment correlation coefficient as a similarity measure and the method to improve its sensitivity. Methods Experimental and simulated data sets were used. Results The distribution range of the data sets influences the sensitivity of Pearson product-moment correlation coefficient. Weighted Pearson product-moment correlation coefficient is more sensitive when the range of the data set is large. Conclusion Weighted Pearson product-moment correlation coefficient is necessary when the range of the data set is large.
Energy Technology Data Exchange (ETDEWEB)
Hagelaar, G J M; Pitchford, L C [Centre de Physique des Plasmas et de leurs Applications de Toulouse, Universite Paul Sabatier, 118 route de Narbonne, 31062 Toulouse Cedex 9 (France)
2005-11-15
Fluid models of gas discharges require the input of transport coefficients and rate coefficients that depend on the electron energy distribution function. Such coefficients are usually calculated from collision cross-section data by solving the electron Boltzmann equation (BE). In this paper we present a new user-friendly BE solver developed especially for this purpose, freely available under the name BOLSIG+, which is more general and easier to use than most other BE solvers available. The solver provides steady-state solutions of the BE for electrons in a uniform electric field, using the classical two-term expansion, and is able to account for different growth models, quasi-stationary and oscillating fields, electron-neutral collisions and electron-electron collisions. We show that for the approximations we use, the BE takes the form of a convection-diffusion continuity-equation with a non-local source term in energy space. To solve this equation we use an exponential scheme commonly used for convection-diffusion problems. The calculated electron transport coefficients and rate coefficients are defined so as to ensure maximum consistency with the fluid equations. We discuss how these coefficients are best used in fluid models and illustrate the influence of some essential parameters and approximations.
Directory of Open Access Journals (Sweden)
Everardo C. Mantovani
2010-03-01
Full Text Available The present study aimed at the development of the water deficit coefficient as a function of the Christiansen uniformity coefficient and relationship between the applied water depth and that required by a given crop, taking into account that the water distribution by the sprinkler follows a normal distribution. Another objective was to compare the experimental results to those obtained through simulation with the Mantovani model. For this, the water deficit coefficients developed in this work were used, as well as the simplified coefficient that takes into account the water distribution by the sprinkler following a uniform distribution, and finally the development of the production functions for the bean crop by using the Mantovani model. The production values simulated by the model, using the normal deficit coefficient, were always less than those simulated with the uniform deficit coefficient for all uniformity levels and all values of the crop's maximum evapotranspiration fraction restored by other sources (p. Under the conditions that this study was carried out, the use of the water deficit coefficient based on the normal distribution model did not provide a better performance of the simulation model proposed by Mantovani.Os objetivos primordiais neste trabalho foram: o desenvolvimento do coeficiente de déficit em função do coeficiente de uniformidade de Christiansen e da relação entre a lâmina aplicada e a lâmina requerida pela cultura, considerando-se que a distribuição de água pelo aspersor segue a distribuição normal, e a comparação dos resultados experimentais com os resultados obtidos por meio da simulação com o uso do modelo proposto por Mantovani, utilizando-se coeficientes de déficit desenvolvido no presente estudo e o coeficiente simplificado, que considera a distribuição de água pelo aspersor, seguindo a distribuição uniforme e, por último, o desenvolvimento das funções de produção para a cultura do feij
Modified Regression Correlation Coefficient for Poisson Regression Model
Kaengthong, Nattacha; Domthong, Uthumporn
2017-09-01
This study gives attention to indicators in predictive power of the Generalized Linear Model (GLM) which are widely used; however, often having some restrictions. We are interested in regression correlation coefficient for a Poisson regression model. This is a measure of predictive power, and defined by the relationship between the dependent variable (Y) and the expected value of the dependent variable given the independent variables [E(Y|X)] for the Poisson regression model. The dependent variable is distributed as Poisson. The purpose of this research was modifying regression correlation coefficient for Poisson regression model. We also compare the proposed modified regression correlation coefficient with the traditional regression correlation coefficient in the case of two or more independent variables, and having multicollinearity in independent variables. The result shows that the proposed regression correlation coefficient is better than the traditional regression correlation coefficient based on Bias and the Root Mean Square Error (RMSE).
Shear Viscosity Coefficient from Microscopic Models
Muronga, A
2004-01-01
The transport coefficient of shear viscosity is studied for a hadron matter through microscopic transport model, the Ultra--relativistic Quantum Molecular Dynamics (UrQMD), using the Green--Kubo formulas. Molecular--dynamical simulations are performed for a system of light mesons in a box with periodic boundary conditions. Starting from an initial state composed of $\\pi, \\eta ,\\omega ,\\rho ,\\phi$ with a uniform phase--space distribution, the evolution takes place through elastic collisions, production and annihilation. The system approaches a stationary state of mesons and their resonances, which is characterized by common temperature. After equilibration, thermodynamic quantities such as the energy density, particle density, and pressure are calculated. From such an equilibrated state the shear viscosity coefficient is calculated from the fluctuations of stress tensor around equilibrium using Green--Kubo relations. We do our simulations here at zero net baryon density so that the equilibration times depend o...
The Kauffman Constraint Coefficients Kw
Griggs, Kenneth A
2011-01-01
The Kauffman Constraint Coefficients Kw and their corresponding Elementals Ew are presented as solutions to the construction of the (beta)-derivative of Kauffman's Theta-function. Additionally, a new recursion relation is provided to construct the (beta)-derivative of Theta that requires only operational substitutions and summations; this algorithmically simplifies Kauffman's original technique. To demonstrate Kw, we generate the 30 Kw Coefficients from the corresponding Elementals Ew for the (9)-derivative of Theta and find that our results are in complete agreement with Kauffman's Mathematica\\texttrademark solutions. We further present a calculation of two coefficients for the (12)-derivative of Theta and invite readers to use Mathematica\\texttrademark or any other means to calculate and verify our results. Finally, we present a challenging calculation for a coefficient of the (40)-derivative of Theta; owing to the vast numbers of permutations involved, a Mathematica\\texttrademark approach may require subst...
Kappa Coefficients for Circular Classifications
Warrens, Matthijs J.; Pratiwi, Bunga C.
2016-01-01
Circular classifications are classification scales with categories that exhibit a certain periodicity. Since linear scales have endpoints, the standard weighted kappas used for linear scales are not appropriate for analyzing agreement between two circular classifications. A family of kappa coefficie
Properties of Traffic Risk Coefficient
Institute of Scientific and Technical Information of China (English)
TANG Tie-Qiao; HUANG Hai-Jun; SHANG Hua-Yan; XUE Yu
2009-01-01
We use the model with the consideration of the traffic interruption probability (Physica A 387(2008)6845) to study the relationship between the traffic risk coefficient and the traffic interruption probability.The analytical and numerical results show that the traffic interruption probability will reduce the traffic risk coefficient and that the reduction is related to the density, which shows that this model can improve traffic security.
Wrong Signs in Regression Coefficients
McGee, Holly
1999-01-01
When using parametric cost estimation, it is important to note the possibility of the regression coefficients having the wrong sign. A wrong sign is defined as a sign on the regression coefficient opposite to the researcher's intuition and experience. Some possible causes for the wrong sign discussed in this paper are a small range of x's, leverage points, missing variables, multicollinearity, and computational error. Additionally, techniques for determining the cause of the wrong sign are given.
Transparent composite model for DCT coefficients: design and analysis.
Yang, En-Hui; Yu, Xiang; Meng, Jin; Sun, Chang
2014-03-01
The distributions of discrete cosine transform (DCT) coefficients of images are revisited on a per image base. To better handle, the heavy tail phenomenon commonly seen in the DCT coefficients, a new model dubbed a transparent composite model (TCM) is proposed and justified for both modeling accuracy and an additional data reduction capability. Given a sequence of the DCT coefficients, a TCM first separates the tail from the main body of the sequence. Then, a uniform distribution is used to model the DCT coefficients in the heavy tail, whereas a different parametric distribution is used to model data in the main body. The separate boundary and other parameters of the TCM can be estimated via maximum likelihood estimation. Efficient online algorithms are proposed for parameter estimation and their convergence is also proved. Experimental results based on Kullback-Leibler divergence and χ(2) test show that for real-valued continuous ac coefficients, the TCM based on truncated Laplacian offers the best tradeoff between modeling accuracy and complexity. For discrete or integer DCT coefficients, the discrete TCM based on truncated geometric distributions (GMTCM) models the ac coefficients more accurately than pure Laplacian models and generalized Gaussian models in majority cases while having simplicity and practicality similar to those of pure Laplacian models. In addition, it is demonstrated that the GMTCM also exhibits a good capability of data reduction or feature extraction-the DCT coefficients in the heavy tail identified by the GMTCM are truly outliers, and these outliers represent an outlier image revealing some unique global features of the image. Overall, the modeling performance and the data reduction feature of the GMTCM make it a desirable choice for modeling discrete or integer DCT coefficients in the real-world image or video applications, as summarized in a few of our further studies on quantization design, entropy coding design, and image understanding
Transport coefficients of heavy baryons
Tolos, Laura; Torres-Rincon, Juan M.; Das, Santosh K.
2016-08-01
We compute the transport coefficients (drag and momentum diffusion) of the low-lying heavy baryons Λc and Λb in a medium of light mesons formed at the later stages of high-energy heavy-ion collisions. We employ the Fokker-Planck approach to obtain the transport coefficients from unitarized baryon-meson interactions based on effective field theories that respect chiral and heavy-quark symmetries. We provide the transport coefficients as a function of temperature and heavy-baryon momentum, and analyze the applicability of certain nonrelativistic estimates. Moreover we compare our outcome for the spatial diffusion coefficient to the one coming from the solution of the Boltzmann-Uehling-Uhlenbeck transport equation, and we find a very good agreement between both calculations. The transport coefficients for Λc and Λb in a thermal bath will be used in a subsequent publication as input in a Langevin evolution code for the generation and propagation of heavy particles in heavy-ion collisions at LHC and RHIC energies.
Study on resistance coefficient in compound channels
Institute of Scientific and Technical Information of China (English)
Kejun Yang; Shuyou Cao; Xingnian Liu; Ron Marshall
2005-01-01
This paper presents a further study of the Manning and Darcy-Weisbach resistance coefficients, as they play a significant role in assessing the cross-sectional mean velocity, conveyance capacity and determining the lateral distribution of depth mean velocity and local boundary shear stress in compound channels. The relationships between the local, zonal and overall resistance coefficients, and a wide range of geometries and different roughness between the main channel and the flood plain are established by analyzing a vast amount of experimental data from a British Science and Engineering Research Council Flood Channel Facility (SERC-FCF). And the experimental results also show that the overall Darcy-Weisbach resistance coefficient for a compound channel is the function of Reynolds number, but the function relationship is different from that for a single channel. By comparing and analyzing the conventional methods with the experimental data to predict composite roughness in compound channels, it is found that these methods are not suitable for compound channels. Moreover, the reason why the conventional methods cannot assess correctly the conveyance capacity of com pound channels is also analyzed in this paper.
MULTIVARIATE VARYING COEFFICIENT MODEL FOR FUNCTIONAL RESPONSES.
Zhu, Hongtu; Li, Runze; Kong, Linglong
2012-10-01
Motivated by recent work studying massive imaging data in the neuroimaging literature, we propose multivariate varying coefficient models (MVCM) for modeling the relation between multiple functional responses and a set of covariates. We develop several statistical inference procedures for MVCM and systematically study their theoretical properties. We first establish the weak convergence of the local linear estimate of coefficient functions, as well as its asymptotic bias and variance, and then we derive asymptotic bias and mean integrated squared error of smoothed individual functions and their uniform convergence rate. We establish the uniform convergence rate of the estimated covariance function of the individual functions and its associated eigenvalue and eigenfunctions. We propose a global test for linear hypotheses of varying coefficient functions, and derive its asymptotic distribution under the null hypothesis. We also propose a simultaneous confidence band for each individual effect curve. We conduct Monte Carlo simulation to examine the finite-sample performance of the proposed procedures. We apply MVCM to investigate the development of white matter diffusivities along the genu tract of the corpus callosum in a clinical study of neurodevelopment.
Stochastic modeling of the diffusion coefficient for concrete
DEFF Research Database (Denmark)
Thoft-Christensen, Palle
In the paper, a new stochastic modelling of the diffusion coefficient D is presented. The modelling is based on a physical understanding of the diffusion process and on some recent experimental results. The diffusion coefficient D is strongly dependent on the w/c ratio and the temperature....... A deterministic relationship between the diffusion coefficient and the w/c ratio and the temperature is used for the stochastic modelling. The w/c ratio and the temperature are modelled by log-normally and normally distributed stochastic variables, respectively. It is then shown by Monte Carlo simulation...... that the diffusion coefficient D may be modelled by a normally distributed stochastic variable. The sensitivities of D with regard to the mean values and the standard deviations are evaluated....
Projection-type estimation for varying coefficient regression models
Lee, Young K; Park, Byeong U; 10.3150/10-BEJ331
2012-01-01
In this paper we introduce new estimators of the coefficient functions in the varying coefficient regression model. The proposed estimators are obtained by projecting the vector of the full-dimensional kernel-weighted local polynomial estimators of the coefficient functions onto a Hilbert space with a suitable norm. We provide a backfitting algorithm to compute the estimators. We show that the algorithm converges at a geometric rate under weak conditions. We derive the asymptotic distributions of the estimators and show that the estimators have the oracle properties. This is done for the general order of local polynomial fitting and for the estimation of the derivatives of the coefficient functions, as well as the coefficient functions themselves. The estimators turn out to have several theoretical and numerical advantages over the marginal integration estimators studied by Yang, Park, Xue and H\\"{a}rdle [J. Amer. Statist. Assoc. 101 (2006) 1212--1227].
Harmonic functions with varying coefficients
Directory of Open Access Journals (Sweden)
Jacek Dziok
2016-05-01
Full Text Available Abstract Complex-valued harmonic functions that are univalent and sense preserving in the open unit disk can be written in the form f = h + g ‾ $f=h+\\overline{g}$ , where h and g are analytic. In this paper we investigate some classes of univalent harmonic functions with varying coefficients related to Janowski functions. By using the extreme points theory we obtain necessary and sufficient convolution conditions, coefficients estimates, distortion theorems, and integral mean inequalities for these classes of functions. The radii of starlikeness and convexity for these classes are also determined.
ROUGHNESS COEFFICIENT FOR UNSUBMERGED AND SUBMERGED REED
Institute of Scientific and Technical Information of China (English)
无
2007-01-01
The characteristics of the roughness coefficient are very important for practical application. Some experiments are conducted to study the variation of Manning's n with flow depth, mean velocity, and density of vegetation,. An assumed velocity distribution to describe the vegetative flow of submerged vegetation is confirmed by experimental results. The measured velocities in this study seem to have little effect on the curve of n ～ h, and a new linear relationship between Manning's n and flow depths is observed clearly. According to the arguments that the flow resistance of densely unsubmerged vegetation is dominated by the resistance exerted on vegetations, the influence of the density of vegetation on Manning's n is estimated. On the basis of the velocity distribution, the n ～ h curve under submerged condition is theoretically obtained from the n ～ h curve under unsubmerged condition. These results are also well confirmed by experimental results and very significant for practical applications.
Molecular Dynamics Simulation on thermodynamic Properties and Transport Coefficients
Institute of Scientific and Technical Information of China (English)
D.X.Xiong
1996-01-01
Moecular dynamics simulation (MDS) is used to study the thermodynamic properties and transport coefficients of an argon system with Lennend-Jones potential.The results on the velocity distribution,mean free path,mean collison time,specific heat and self0diffusion coefficient agree well with the existing theoretical /experimental data,It shows that molecular dynamics method is another bridge to connect microworld and macreoworld.
Spatial variation of the longitudinal dispersion coefficient in an estuary
D. C. Shaha; Y.-K. Cho; M.-T. Kwak; S. R. Kundu; K. T. Jung
2011-01-01
The effective longitudinal dispersion is a primary tool for determining property distributions in estuaries. Most previous studies have examined the longitudinal dispersion coefficient for the average tidal condition. However, information on spatial and temporal variations of this coefficient at low and high tide is scarce. Three years of hydrographic data taken at low and high tide along the main axis of the Sumjin River Estuary (SRE), Korea are used to estimate the spatial and temporal vari...
Effective Viscosity Coefficient of Nanosuspensions
Rudyak, V. Ya.; Belkin, A. A.; Egorov, V. V.
2008-12-01
Systematic calculations of the effective viscosity coefficient of nanosuspensions have been performed using the molecular dynamics method. It is established that the viscosity of a nanosuspension depends not only on the volume concentration of the nanoparticles but also on their mass and diameter. Differences from Einstein's relation are found even for nanosuspensions with a low particle concentration.
Irrational "Coefficients" in Renaissance Algebra.
Oaks, Jeffrey A
2017-06-01
Argument From the time of al-Khwārizmī in the ninth century to the beginning of the sixteenth century algebraists did not allow irrational numbers to serve as coefficients. To multiply by x, for instance, the result was expressed as the rhetorical equivalent of . The reason for this practice has to do with the premodern concept of a monomial. The coefficient, or "number," of a term was thought of as how many of that term are present, and not as the scalar multiple that we work with today. Then, in sixteenth-century Europe, a few algebraists began to allow for irrational coefficients in their notation. Christoff Rudolff (1525) was the first to admit them in special cases, and subsequently they appear more liberally in Cardano (1539), Scheubel (1550), Bombelli (1572), and others, though most algebraists continued to ban them. We survey this development by examining the texts that show irrational coefficients and those that argue against them. We show that the debate took place entirely in the conceptual context of premodern, "cossic" algebra, and persisted in the sixteenth century independent of the development of the new algebra of Viète, Decartes, and Fermat. This was a formal innovation violating prevailing concepts that we propose could only be introduced because of the growing autonomy of notation from rhetorical text.
EXTENDED CLUSTERING COEFFICIENTS:GENERALIZATION OF CLUSTERING COEFFICIENTS IN SMALL-WORLD NETWORKS
Institute of Scientific and Technical Information of China (English)
无
2007-01-01
The clustering coefficient C of a network, which is a measure of direct connectivity between neighbors of the various nodes, ranges from 0 (for no connectivity) to 1 (for full connectivity). We define extended clustering coefficients C(h) of a small-world network based on nodes that are at distance h from a source node, thus generalizing distance-1 neighborhoods employed in computing the ordinary clustering coefficient C = C(1). Based on known results about the distance distribution Pδ(h) in a network, that is, the probability that a randomly chosen pair of vertices have distance h, we derive and experimentally validate the law Pδ(h)C(h) ≤ c log N / N, where c is a small constant that seldom exceeds 1. This result is significant because it shows that the product Pδ(h)C(h) is upper-bounded by a value that is considerably smaller than the product of maximum values for Pδ(h) and C(h). Extended clustering coefficients and laws that govern them offer new insights into the structure of small-world networks and open up avenues for further exploration of their properties.
Institute of Scientific and Technical Information of China (English)
马正义; 马松华; 杨毅
2012-01-01
The nonlinear Schroedinger equation is one of the most important nonlinear models with widely applications in physics. Based on a similarity transformation, the (2+1)-dimensional nonlinear Schroedinger equation with distributed coefficients is transformed into a traceable nonlinear Schroedinger equation, and then two types of rational solutions and several spatial solitons are derived.%非线性Schroedinger方程是物理学中具有广泛应用的非线性模型之一．本文采用相似变换，将具有色散系数的（2＋1）维非线性Schrioedinger方程简化成熟知的Schroedinger方程，进而得到原方程的有理解和一些空间孤子．
Clustering Coefficients in Multiplex Networks
Cozzo, Emanuele; De Domenico, Manlio; Solé, Albert; Arenas, Alex; Gómez, Sergio; Porter, Mason A; Moreno, Yamir
2013-01-01
Recent advances in the study of complex networked systems has highlighted that our interconnected world is made of networks that are coupled together through different layers that each stand for one type of interaction or system. Despite this situation, it is traditional to aggregate multiplex data into a single weighted network in order take advantage of existing tools. This is admittedly convenient, but it is also extremely problematic. In this paper, we generalize the concept of clustering coefficients for multiplex networks. We show how the layered structure of multiplex networks introduces a new degree of freedom that has a fundamental effect on transitivity. We compute our new multiplex clustering coefficients for several real multiplex networks and illustrate why generalizing monoplex concepts to multiplex networks must be done with great care.
DEFF Research Database (Denmark)
Jeong, Cheol-Ho; Chang, Ji-ho
2015-01-01
Absorption coefficients measured in reverberation chambers, Sabine absorption coefficients, suffer from two major problems. Firstly, they sometimes exceed unity. Secondly, the reproducibility of the Sabine absorption coefficients is quite poor, meaning that the Sabine absorption coefficients vary...
Institute of Scientific and Technical Information of China (English)
LU Yigang; PENG Jianxin; TONG Jie; DONG Yanwu
2000-01-01
On the basis of Jacobson's free length theory and the theory of pressure coefficient and temperature coefficient of free length in liquids, the relationship between the pressure coefficient of ultrasonic velocity and the pressure coefficient of free length, and the relationship between the temperature coefficient of ultrasonic velocity and the temperature coefficient of free length were studied. Relevant equations were given, and the pressure coefficient and temperature coefficient of ultrasonic velocity were calculated, which are in agreement with the measured values.
measurements of distribution coefficients and lipophilicity values for ...
African Journals Online (AJOL)
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advantages of simplicity, use of minimal organic solvents and the ability to ... HFSLM is a non-porous membrane technique which has been widely used for ... analyte is contained in an aqueous sample solution and for it to be extracted it ...
Controllable Optical Solitons in Optical Fiber System with Distributed Coefficients
Institute of Scientific and Technical Information of China (English)
ZHANG Xiao-Fei; HE Wan-Quan; ZHANG Pei; ZHANG Peng
2011-01-01
We present how to control the dynamics of optical solitons in optical fibers under nonlinearity and dispersion management, together with the fiber loss or gain. We obtain a family of exact solutions for the nonlinear Schr(o)dinger equation, which describes the propagation of optical pulses in optical fibers, and investigate the dynamical features of solitons by analyzing the exact analytical solutions in different physical situations. The results show that under the appropriate condition, not only the group velocity dispersion and the nonlinearity, but also the loss/gain can be used to manipulate the light pulse.
Lower bound of assortativity coefficient in scale-free networks
Yang, Dan; Zhou, Tao
2016-01-01
The degree-degree correlation is important in understanding the structural organization of a network and the dynamics upon a network. Such correlation is usually measured by the assortativity coefficient $r$, with natural bounds $r \\in [-1,1]$. For scale-free networks with power-law degree distribution $p(k) \\sim k^{-\\gamma}$, we analytically obtain the lower bound of assortativity coefficient in the limit of large network size, which is not -1 but dependent on the power-law exponent $\\gamma$. This work challenges the validation of assortativity coefficient in heterogeneous networks, suggesting that one cannot judge whether a network is positively or negatively correlated just by looking at its assortativity coefficient.
Coefficient adaptive triangulation for strongly anisotropic problems
Energy Technology Data Exchange (ETDEWEB)
D`Azevedo, E.F.; Romine, C.H.; Donato, J.M.
1996-01-01
Second order elliptic partial differential equations arise in many important applications, including flow through porous media, heat conduction, the distribution of electrical or magnetic potential. The prototype is the Laplace problem, which in discrete form produces a coefficient matrix that is relatively easy to solve in a regular domain. However, the presence of anisotropy produces a matrix whose condition number is increased, making the resulting linear system more difficult to solve. In this work, we take the anisotropy into account in the discretization by mapping each anisotropic region into a ``stretched`` coordinate space in which the anisotropy is removed. The region is then uniformly triangulated, and the resulting triangulation mapped back to the original space. The effect is to generate long slender triangles that are oriented in the direction of ``preferred flow.`` Slender triangles are generally regarded as numerically undesirable since they tend to cause poor conditioning; however, our triangulation has the effect of producing effective isotropy, thus improving the condition number of the resulting coefficient matrix.
Using the range to calculate the coefficient of variation.
Rhiel, G Steven
2004-12-01
In this research a coefficient of variation (CVhigh-low) is calculated from the highest and lowest values in a set of data. Use of CVhigh-low when the population is normal, leptokurtic, and skewed is discussed. The statistic is the most effective when sampling from the normal distribution. With the leptokurtic distributions, CVhigh-low works well for comparing the relative variability between two or more distributions but does not provide a very "good" point estimate of the population coefficient of variation. With skewed distributions CVhigh-low works well in identifying which data set has the more relative variation but does not specify how much difference there is in the variation. It also does not provide a "good" point estimate.
Lu, Qieni; Han, Jinxin; Dai, Haitao; Ge, Baozhen; Zhao, Shuang
2015-08-01
We measure temperature dependence on Kerr coefficient and quadratic polarized optical coefficient of a paraelectric Mn:Fe:KTN crystal simultaneously in this work, based on digital holographic interferometry (DHI). And the spatial distribution of the field-induced refractive index change can also be visualized and estimated by numerically retrieving sequential phase maps of Mn:Fe:KTN crystal from recording digital holograms in different states. The refractive indices decrease with increasing temperature and quadratic polarized optical coefficient is insensitive to temperature. The experimental results suggest that the DHI method presented here is highly applicable in both visualizing the temporal and spatial behavior of the internal electric field and accurately measuring electro-optic coefficient for electrooptical media.
Transport coefficients for rigid spherically symmetric polymers or aggregates
Strating, P.; Wiegel, F.W.
1994-01-01
In this paper we investigate the transport properties for rigid spherically symmetric macromolecules, having a segment density distribution falling off as r- lambda . We calculate the rotational and translational diffusion coefficient for a spherically symmetric polymer and the shear viscosity for a
National Research Council Canada - National Science Library
Everardo C. Mantovani; Gregório G. Faccioli; Brauliro G. Leal; Luis C. Costa; Antônio A. Soares; Paulo S. L. Freitas
2010-01-01
The present study aimed at the development of the water deficit coefficient as a function of the Christiansen uniformity coefficient and relationship between the applied water depth and that required...
Institute of Scientific and Technical Information of China (English)
于婷; 李峥; 赵皓贵; 何淑华; 何辉; 李晴暖; 张岚
2015-01-01
Based on distribution coefficient data of thorium (Th),uranium (U)and nitric acid in the tributyl phosphate (TBP)extraction system,and by comparing and analyzing the presented distribution coefficient models in the literature,a new mathe-matical distribution coefficient model with relative computer program for simulating the extraction behavior of Th(Ⅳ),U(Ⅵ)and HNO3 in the TBP extraction system.The reliability of the new model with computer program was verified by 34 sets of distribu-tion coefficient data.The calculated results agree well with the experimental data.The results by comparing the actual distribution coefficient data with the computing results indicate that the calculated results by using this new model are more reliable and accu-rate than those of SEPHIS model reported previously.The model presented in this work can be a foundation for simulating the extraction behavior of thorium,uranium and nitric acid in the extraction system of Th (NO3 )4-UO2 (NO3 )2-HNO3-H2 O/30%TBP-dodecane with uranium concentrations from 0 g/L to 100 g/L,thorium from 0 g/L to 232 g/L,and HNO3 from 0 g/L to 4.5 mol/L at 25 ℃.%利用文献报道的Th(NO3)4-UO2(NO3)2-HNO3-H2 O/30%TBP-正十二烷体系各组分的分配比实验数据对现有的分配比模型进行分析和比对,提出了一个计算该体系各组分分配比的新模型。利用34组实验数据对新模型进行了验证,符合情况良好。计算结果表明,本文提出的模型明显优于原模型,可作为Th(NO3)4-UO2(NO3)2-HNO3-H2 O/30%TBP-正十二烷萃取体系中 Th(Ⅳ)、U(Ⅵ)和 HNO3萃取行为计算机模拟的基础。模型建立的条件为：温度,25℃；U(Ⅵ)浓度,0~100 g/L；Th(Ⅳ)浓度,0~232 g/L；硝酸浓度,0~4.5 mol/L。
Higher Order Macro Coefficients in Periodic Homogenization
Energy Technology Data Exchange (ETDEWEB)
Conca, Carlos; San Martin, Jorge [Departamento de IngenierIa Matematica, Facultad de Ciencias Fisicas y Matematicas, Universidad de Chile and Centro de Modelamiento Matematico, UMR 2071 CNRS-UChile, Casilla 170/3 - Correo 3, Santiago (Chile); Smaranda, Loredana [Department of Mathematics, Faculty of Mathematics and Computer Science, University of Pitesti, 110040 Pitesti, Str. Targu din Vale Nr.1, Arges (Romania); Vanninathan, Muthusamy, E-mail: cconca@dim.uchile.cl, E-mail: jorge@dim.uchile.cl, E-mail: smaranda@dim.uchile.cl, E-mail: vanni@math.tifrbng.res.in [TIFR-CAM, Post Bag 6503, GKVK Post, Bangalore - 560065 (India)
2011-09-15
A first set of macro coefficients known as the homogenized coefficients appear in the homogenization of PDE on periodic structures. If energy is increased or scale is decreased, these coefficients do not provide adequate approximation. Using Bloch decomposition, it is first realized that the above coefficients correspond to the lowest energy and the largest scale. This naturally paves the way to introduce other sets of macro coefficients corresponding to higher energies and lower scales which yield better approximation. The next task is to compare their properties with those of the homogenized coefficients. This article reviews these developments along with some new results yet to be published.
Generalized transport coefficients for inelastic Maxwell mixtures under shear flow
Garzó, Vicente; Trizac, Emmanuel
2015-11-01
The Boltzmann equation framework for inelastic Maxwell models is considered to determine the transport coefficients associated with the mass, momentum, and heat fluxes of a granular binary mixture in spatially inhomogeneous states close to the simple shear flow. The Boltzmann equation is solved by means of a Chapman-Enskog-type expansion around the (local) shear flow distributions fr(0 ) for each species that retain all the hydrodynamic orders in the shear rate. Due to the anisotropy induced by the shear flow, tensorial quantities are required to describe the transport processes instead of the conventional scalar coefficients. These tensors are given in terms of the solutions of a set of coupled equations, which can be analytically solved as functions of the shear rate a , the coefficients of restitution αr s, and the parameters of the mixture (masses, diameters, and composition). Since the reference distribution functions fr(0 ) apply for arbitrary values of the shear rate and are not restricted to weak dissipation, the corresponding generalized coefficients turn out to be nonlinear functions of both a and αr s. The dependence of the relevant elements of the three diffusion tensors on both the shear rate and dissipation is illustrated in the tracer limit case, the results showing that the deviation of the generalized transport coefficients from their forms for vanishing shear rates is in general significant. A comparison with the previous results obtained analytically for inelastic hard spheres by using Grad's moment method is carried out, showing a good agreement over a wide range of values for the coefficients of restitution. Finally, as an application of the theoretical expressions derived here for the transport coefficients, thermal diffusion segregation of an intruder immersed in a granular gas is also studied.
In vivo lipid diffusion coefficient measurements in rat bone marrow.
Ababneh, Zaid Q; Beloeil, Helene; Berde, Charles B; Ababneh, Anas M; Maier, Stephan E; Mulkern, Robert V
2009-07-01
The diffusion coefficient of lipids, D(l), within bone marrow, fat deposits and metabolically active intracellular lipids in vivo will depend on several factors including the precise chemical composition of the lipid distribution (chain lengths, degree of unsaturation, etc.) as well as the temperature. As such, D(l) may ultimately prove of value in assessing abnormal fatty acid distributions linked to diseases such as cystic fibrosis, diabetes and coronary heart disease. A sensitive temperature dependence of D(l) may also prove of value for MR-guided thermal therapies for bone tumors or disease within other fatty tissues like the breast. Measuring diffusion coefficients of high molecular weight lipids in vivo is, however, technically difficult for a number of reasons. For instance, due to the much lower diffusion coefficients compared to water, much higher b factors than those used for central nervous system applications are needed. In addition, the pulse sequence design must incorporate, as much as possible, immunity to motion, susceptibility and chemical shift effects present whenever body imaging is performed. In this work, high b-factor line scan diffusion imaging sequences were designed, implemented and tested for D(l) measurement using a 4.7-T horizontal bore animal scanner. The gradient set available allowed for b factors as high as 0.03 micros/nm(2) (30,000 s/mm(2)) at echo times as short as 42 ms. The methods were used to measure lipid diffusion coefficients within the marrow of rat paws in vivo, yielding lipid diffusion coefficients approximately two orders of magnitude smaller than typical tissue water diffusion coefficients. Phantom experiments that demonstrate the sensitivity of lipid diffusion coefficients to chain length and temperature were also performed.
Negative power coefficient on PHWRs with CARA fuel
Energy Technology Data Exchange (ETDEWEB)
Lestani, H.A., E-mail: lestanih@cab.cnea.gov.ar [Comisión Nacional de Energía Atómica – Centro Atómico Bariloche, Av. E. Bustillo 9500, S. C. de Bariloche, Río Negro (Argentina); Instituto Balseiro – Universidad Nacional de Cuyo, Av. E. Bustillo 9500, S. C. de Bariloche, Río Negro (Argentina); González, H.J., E-mail: jgonzalez@invap.com.ar [INVAP S.E., Av. Cmte. Luis Piedrabuena 4905 (Argentina); Instituto Balseiro – Universidad Nacional de Cuyo, Av. E. Bustillo 9500, S. C. de Bariloche, Río Negro (Argentina); Consejo Nacional de Investigaciones Científicas y Tecnológicas, Av. Rivadavia 1917, CABA, C1033AAJ (Argentina); Florido, P.C., E-mail: pcflorido@yahoo.com [Instituto Balseiro – Universidad Nacional de Cuyo, Av. E. Bustillo 9500, S. C. de Bariloche, Río Negro (Argentina)
2014-04-01
Highlights: • A PHWR fuel was optimized to obtain a negative power coefficient. • Fuel cost, being a measure of design investment efficiency, was optimized. • Influence on power coefficient of geometrical and economical parameters’ was studied. • Different neutronic absorbers were studied; pure absorbers can be used. • Thermal and economical models were developed to complement neutronic assessment. - Abstract: A study of power coefficient of reactivity in heavy water reactors is made analyzing the reactivity components of fuels with several modifications oriented at reducing the coefficient. A cell model is used for neutronics calculations; a non-linear two dimensional model is used to evaluate the thermal changes that follow a power change; and a levelized unit energy cost model is used to assess the economical feasibility of the design changes introduced to reduce power coefficient. The necessity of modelling all the aforementioned quantities in a coupled scheme is stressed, as a strong interdependence was found. A series of design changes complied with a negative power coefficient of reactivity, with a feasible power radial distribution and with low refuelling cost. Some investigation lines that exceed the fuel cell study and deal with the plant operation are marked as potentially addressing the stable operation of big heavy water reactors.
Coefficients of Productivity for Yellowstone's Grizzly Bear Habitat
Mattson, David John; Barber, Kim; Maw, Ralene; Renkin, Roy
2004-01-01
This report describes methods for calculating coefficients used to depict habitat productivity for grizzly bears in the Yellowstone ecosystem. Calculations based on these coefficients are used in the Yellowstone Grizzly Bear Cumulative Effects Model to map the distribution of habitat productivity and account for the impacts of human facilities. The coefficients of habitat productivity incorporate detailed information that was collected over a 20-year period (1977-96) on the foraging behavior of Yellowstone's bears and include records of what bears were feeding on, when and where they fed, the extent of that feeding activity, and relative measures of the quantity consumed. The coefficients also incorporate information, collected primarily from 1986 to 1992, on the nutrient content of foods that were consumed, their digestibility, characteristic bite sizes, and the energy required to extract and handle each food. Coefficients were calculated for different time periods and different habitat types, specific to different parts of the Yellowstone ecosystem. Stratifications included four seasons of bear activity (spring, estrus, early hyperphagia, late hyperphagia), years when ungulate carrion and whitebark pine seed crops were abundant versus not, areas adjacent to (bear activity in each region, habitat type, and time period were incorporated into calculations, controlling for the effects of proximity to human facilities. The coefficients described in this report and associated estimates of grizzly bear habitat productivity are unique among many efforts to model the conditions of bear habitat because calculations include information on energetics derived from the observed behavior of radio-marked bears.
Measuring the Soret coefficient of nanoparticles in a dilute suspension.
Zhao, Chao; Fu, Jinxin; Oztekin, Alparslan; Cheng, Xuanhong
2014-10-01
Thermophoresis is an efficient process for the manipulation of molecules and nanoparticles due to the strong force it generates on the nanoscale. Thermophoresis is characterized by the Soret coefficient. Conventionally, the Soret coefficient of nanosized species is obtained by fitting the concentration profile under a temperature gradient at the steady state to a continuous phase model. However, when the number density of the target is ultralow and the dispersed species cannot be treated as a continuous phase, the bulk concentration fluctuates spatially, preventing extraction of temperature-gradient induced concentration profile. The present work demonstrates a strategy to tackle this problem by superimposing snapshots of nanoparticle distribution. The resulting image is suitable for the extraction of the Soret coefficient through the conventional data fitting method. The strategy is first tested through a discrete phase model that illustrates the spatial fluctuation of the nanoparticle concentration in a dilute suspension in response to the temperature gradient. By superimposing snapshots of the stochastic distribution, a thermophoretic depletion profile with low standard error is constructed, indicative of the Soret coefficient. Next, confocal analysis of nanoparticle distribution in response to a temperature gradient is performed using polystyrene nanobeads down to 1e-5% (v/v). The experimental results also reveal that superimposing enhances the accuracy of extracted Soret coefficient. The critical particle number density in the superimposed image for predicting the Soret coefficient is hypothesized to depend on the spatial resolution of the image. This study also demonstrates that the discrete phase model is an effective tool to study particle migration under thermophoresis in the liquid phase.
Texture coefficient analysis of ion beam irradiated copper nanowires
Energy Technology Data Exchange (ETDEWEB)
Rana, Pallavi, E-mail: prana.phy@gmail.com; Chaudhary, Ritika, E-mail: chauhanrpc@gmail.com; Chauhan, R. P. [Department of Physics, National Institute of Technology, Kurukshetra-136119 (India)
2016-05-23
Radiation may deteriorate physical properties of the materials and leave negative as well as positive impacts especially on crystalline materials. The energy deposited by ions to the grains and grain boundaries could also influence other properties of grains like: strain, reflection of charge carriers from grain boundaries, in addition to their grain size and orientation. The intensity of a peak in the XRD spectra is the direct reflection of orientation of a miller plane in the crystal. The increased intensity symbolizes the crystalline behavior due to defects annealing, while decreased intensity portray the defects formation and slender amorphisation. Orientation distribution function is a probability distribution function that quantified the texture of a polycrystalline material. The coefficients of harmonic expansion of orientation distribution function is the measurement of the texture coefficient ‘TC’. This study focused on the investigation of effect of ion beam irradiation on the preffered orientation of the planes of copper nanowires.
Note on Two Generalizations of Coefficient Alpha.
Raju, Nambury S.
1979-01-01
An important relationship is given for two generalizations of coefficient alpha: (1) Rajaratnam, Cronbach, and Gleser's generalizability formula for stratified-parallel tests, and (2) Raju's coefficient beta. (Author/CTM)
Energy coefficients for a propeller series
DEFF Research Database (Denmark)
Olsen, Anders Smærup
2004-01-01
The efficiency for a propeller is calculated by energy coefficients. These coefficients are related to four types of losses, i.e. the axial, the rotational, the frictional, and the finite blade number loss, and one gain, i.e. the axial gain. The energy coefficients are derived by use of the poten......The efficiency for a propeller is calculated by energy coefficients. These coefficients are related to four types of losses, i.e. the axial, the rotational, the frictional, and the finite blade number loss, and one gain, i.e. the axial gain. The energy coefficients are derived by use...... of the potential theory with the propeller modelled as an actuator disk. The efficiency based on the energy coefficients is calculated for a propeller series. The results show a good agreement between the efficiency based on the energy coefficients and the efficiency obtained by a vortex-lattice method....
Index-free Heat Kernel Coefficients
De van Ven, A E M
1998-01-01
Using index-free notation, we present the diagonal values of the first five heat kernel coefficients associated with a general Laplace-type operator on a compact Riemannian space without boundary. The fifth coefficient appears here for the first time. For a flat space with a gauge connection, the sixth coefficient is given too. Also provided are the leading terms for any coefficient, both in ascending and descending powers of the Yang-Mills and Riemann curvatures, to the same order as required for the fourth coefficient. These results are obtained by directly solving the relevant recursion relations, working in Fock-Schwinger gauge and Riemann normal coordinates. Our procedure is thus noncovariant, but we show that for any coefficient the `gauged' respectively `curved' version is found from the corresponding `non-gauged' respectively `flat' coefficient by making some simple covariant substitutions. These substitutions being understood, the coefficients retain their `flat' form and size. In this sense the fift...
Certain Binomial Sums with recursive coefficients
Kilic, Emrah
2010-01-01
In this short note, we establish some identities containing sums of binomials with coefficients satisfying third order linear recursive relations. As a result and in particular, we obtain general forms of earlier identities involving binomial coefficients and Fibonacci type sequences.
Nonstationary Feller process with time-varying coefficients
Masoliver, Jaume
2016-01-01
We study the nonstationary Feller process with time varying coefficients. We obtain the exact probability distribution exemplified by its characteristic function and cumulants. In some particular cases we exactly invert the distribution and achieve the probability density function. We show that for sufficiently long times this density approaches a Γ distribution with time-varying shape and scale parameters. Not far from the origin the process obeys a power law with an exponent dependent of time, thereby concluding that accessibility to the origin is not static but dynamic. We finally discuss some possible applications of the process.
Standards for Standardized Logistic Regression Coefficients
Menard, Scott
2011-01-01
Standardized coefficients in logistic regression analysis have the same utility as standardized coefficients in linear regression analysis. Although there has been no consensus on the best way to construct standardized logistic regression coefficients, there is now sufficient evidence to suggest a single best approach to the construction of a…
Comparing linear probability model coefficients across groups
DEFF Research Database (Denmark)
Holm, Anders; Ejrnæs, Mette; Karlson, Kristian Bernt
2015-01-01
This article offers a formal identification analysis of the problem in comparing coefficients from linear probability models between groups. We show that differences in coefficients from these models can result not only from genuine differences in effects, but also from differences in one or more...... these limitations, and we suggest a restricted approach to using linear probability model coefficients in group comparisons....
Note on Methodology: The Coefficient of Variation.
Sheret, Michael
1984-01-01
Addresses applications of the coefficient of variation as a measure of educational inequality or as a means of measuring changes of inequality status. Suggests the Gini coefficient has many advantages over the coefficient of variation since it can be used with the Lorenz curve (Lorenz provides detail Gini omits). (BRR)
Coefficient of Partial Correlation and Its Calculation
Institute of Scientific and Technical Information of China (English)
段全才; 张保法
1992-01-01
This thesis offers the general concept of coefficient of partial correlation.Starting with regres-sion analysis,the paper,by using samples,infers the general formula of expressing coefficient of partial correlation by way of simple correlation coefficient.
Diffusion coefficient in photon diffusion theory
Graaff, R; Ten Bosch, JJ
2000-01-01
The choice of the diffusion coefficient to be used in photon diffusion theory has been a subject of discussion in recent publications on tissue optics. We compared several diffusion coefficients with the apparent diffusion coefficient from the more fundamental transport theory, D-app. Application to
Soccer Ball Lift Coefficients via Trajectory Analysis
Goff, John Eric; Carre, Matt J.
2010-01-01
We performed experiments in which a soccer ball was launched from a machine while two high-speed cameras recorded portions of the trajectory. Using the trajectory data and published drag coefficients, we extracted lift coefficients for a soccer ball. We determined lift coefficients for a wide range of spin parameters, including several spin…
Diffusion coefficient in photon diffusion theory
Graaff, R; Ten Bosch, JJ
2000-01-01
The choice of the diffusion coefficient to be used in photon diffusion theory has been a subject of discussion in recent publications on tissue optics. We compared several diffusion coefficients with the apparent diffusion coefficient from the more fundamental transport theory, D-app. Application to
Soccer Ball Lift Coefficients via Trajectory Analysis
Goff, John Eric; Carre, Matt J.
2010-01-01
We performed experiments in which a soccer ball was launched from a machine while two high-speed cameras recorded portions of the trajectory. Using the trajectory data and published drag coefficients, we extracted lift coefficients for a soccer ball. We determined lift coefficients for a wide range of spin parameters, including several spin…
Ageing effect of chloride diffusion coefficient
Polder, R.B.
2006-01-01
Most of the currently used models to predict chloride ingress a constant diffusion coefficient over time. However, a reduction of the diffusion coefficient over time, is ob-served at specimens that are exposed to chlorides. This reduction of the diffusion coefficient is expressed with the ageing coe
Standards for Standardized Logistic Regression Coefficients
Menard, Scott
2011-01-01
Standardized coefficients in logistic regression analysis have the same utility as standardized coefficients in linear regression analysis. Although there has been no consensus on the best way to construct standardized logistic regression coefficients, there is now sufficient evidence to suggest a single best approach to the construction of a…
Note on Methodology: The Coefficient of Variation.
Sheret, Michael
1984-01-01
Addresses applications of the coefficient of variation as a measure of educational inequality or as a means of measuring changes of inequality status. Suggests the Gini coefficient has many advantages over the coefficient of variation since it can be used with the Lorenz curve (Lorenz provides detail Gini omits). (BRR)
Reducing component estimation for varying coefficient models with longitudinal data
Institute of Scientific and Technical Information of China (English)
2008-01-01
Varying-coefficient models with longitudinal observations are very useful in epidemiology and some other practical fields.In this paper,a reducing component procedure is proposed for es- timating the unknown functions and their derivatives in very general models,in which the unknown coefficient functions admit different or the same degrees of smoothness and the covariates can be time- dependent.The asymptotic properties of the estimators,such as consistency,rate of convergence and asymptotic distribution,are derived.The asymptotic results show that the asymptotic variance of the reducing component estimators is smaller than that of the existing estimators when the coefficient functions admit different degrees of smoothness.Finite sample properties of our procedures are studied through Monte Carlo simulations.
Heart Rate Variability Analysis Using Threshold of Wavelet Package Coefficients
Kheder, G; Massoued, M Ben; Samet, M
2009-01-01
In this paper, a new efficient feature extraction method based on the adaptive threshold of wavelet package coefficients is presented. This paper especially deals with the assessment of autonomic nervous system using the background variation of the signal Heart Rate Variability HRV extracted from the wavelet package coefficients. The application of a wavelet package transform allows us to obtain a time-frequency representation of the signal, which provides better insight in the frequency distribution of the signal with time. A 6 level decomposition of HRV was achieved with db4 as mother wavelet, and the above two bands LF and HF were combined in 12 specialized frequencies sub-bands obtained in wavelet package transform. Features extracted from these coefficients can efficiently represent the characteristics of the original signal. ANOVA statistical test is used for the evaluation of proposed algorithm.
Viscosity Coefficients of a Nematic Mixture: Statistical Theory Approach
Terentjev, E. M.; Osipov, M. A.
1991-09-01
A statistical theory of the rotational diffusion of a molecule in a two-component anisotropic mixture is developed, based on the Fokker-Planck approximation for the one-particle orientational distribution function. The friction constant of the molecular rotation is determined from the threeparticle correlation function, which takes into account interactions A-A, A-B, B-A and B-B between two sorts of molecules. The Leslie coefficients obtained possess a complicated dependence on mixture concentration together with a dependence on temperature and the molecular parameters of the components. In particular, the rotational viscosity coefficient γj is proportional to a polynomial of third-order in concentrations cA and cB with coefficients proportional to exp{JAca + JBcB} √(JACA + JB bcB )
Estimating the workpiece-backingplate heat transfer coefficient in friction stirwelding
DEFF Research Database (Denmark)
Larsen, Anders; Stolpe, Mathias; Hattel, Jesper Henri
2012-01-01
Purpose - The purpose of this paper is to determine the magnitude and spatial distribution of the heat transfer coefficient between the workpiece and the backingplate in a friction stir welding process using inverse modelling. Design/methodology/approach - The magnitude and distribution of the heat...... yields optimal values for the magnitude and distribution of the heat transfer coefficient. Findings - It is found that the heat transfer coefficient between the workpiece and the backingplate is non-uniform and takes its maximum value in a region below the welding tool. Four different parameterisations...... of the spatial distribution of the heat transfer coefficient are analysed and a simple, two parameter distribution is found to give good results. Originality/value - The heat transfer from workpiece to backingplate is important for the temperature field in the workpiece, and in turn the mechanical properties...
Kustova, Elena V.; Kremer, Gilberto M.
2015-09-01
Shear viscosity coefficient is calculated for both equilibrium and strongly non-equilibrium state-to-state vibrational distributions taking into account increasing diameters of vibrationally excited molecules. Under conditions of local thermal equilibrium, the effect of vibrational excitation on the shear viscosity coefficient is found to be negligible for temperatures below 5000 K. For T > 10 000 K, the contribution of excited states becomes important. Under non-equilibrium conditions characteristic for shock heated and supersonic expanding flows vibrational level populations deviate strongly from the Boltzmann distribution. Nevertheless, estimated coupled effect of molecular size and non-Boltzmann distributions on the shear viscosity coefficient is negligible.
Institute of Scientific and Technical Information of China (English)
Ping Sun; Yu Wang; Xiaoli Mo; Jinghui Xie
2008-01-01
A spatial distribution of diffuse reflectance produced by obliquely incident light is not centered about the point of light entry. The value of shift in the center of diffuse reflectance is directly related to the absorption coefficient μa and the effective attenuation coefficient μeff. μa and the reduced scattering coefficient μ's of human skin tissues in vivo are measured by oblique-incidence reflectometry based on the two-source diffuse theory model. For ten Chinese volunteers aged 15-63 years, μa and μ's are noninvasively determined to be 0.029 - 0.075 and 0.52 - 0.97 mm-1, respectively.
A Study of Eddy Viscosity Coefficient in Numerical Tidal Simulation
Institute of Scientific and Technical Information of China (English)
陈永平; 雷智益
2001-01-01
Based on the fluid motion equations, the physical meaning of eddy viscosity coefficient and the rationality of theBoussinesq hypothesis are discussed in this paper. The effect of the coefficient on numerical stability is analyzed briefly.A semi-enclosed rectangular sea area, with an orthogonal spur dike, is applied in a 2-D numerical model to study the effect of horizontal eddy viscosity coefficient (AH). The computed result shows that AH has little influence on the tidal level and averaged flow velocity, but has obvious influence on the intensity and the range of return flow around near thespur dike. Correspondingly, a wind-driven current pool and an annular current are applied in a 3-D numerical modelrespectively to study the effect of vertical eddy viscosity coefficient (AV). The computed result shows that the absolute value of AV is inversely proportional to that of horizontal velocity, and the vertical gradient value of AV determines the ver-tical distribution of horizontal velocity. The distribution form of AV is theoretically recommended as a parabolic type, ofwhich the maximum value appears at 0.5 H.
Ångström coefficient as a tracer of the continental aerosols
Kuśmierczyk-Michulec, J.T.; Eijk, A.M.J. van
2007-01-01
The variation of the extinction coefficient with wavelength can be presented as a power law function with a constant (related to the power factor) known as the Ångström coefficient. When the particle size distribution is dominated by small particles, usually associated with pollution, the Ångström c
Ångström coefficient as a tracer of the continental aerosols
Kuśmierczyk-Michulec, J.T.; Eijk, A.M.J. van
2007-01-01
The variation of the extinction coefficient with wavelength can be presented as a power law function with a constant (related to the power factor) known as the Ångström coefficient. When the particle size distribution is dominated by small particles, usually associated with pollution, the Ångström
Adaptive and minimax optimal estimation of the tail coefficient
Carpentier, Alexandra; Kim, Arlene K. H.
2013-01-01
We consider the problem of estimating the tail index $\\alpha$ of a distribution satisfying a $(\\alpha, \\beta)$ second-order Pareto-type condition, where \\beta is the second-order coefficient. When $\\beta$ is available, it was previously proved that $\\alpha$ can be estimated with the oracle rate $n^{-\\beta/(2\\beta+1)}$. On the contrary, when $\\beta$ is not available, estimating $\\alpha$ with the oracle rate is challenging; so additional assumptions that imply the estimability of $\\beta$ are us...
Stress Optical Coefficient, Test Methodology, and Glass Standard Evaluation
2016-05-01
it can be used as an additional glass characterization method . If the SOC of a glass sample is known, the stress state of a glass specimen can be...evaluated through photoelastic methods both qualitatively and quantitatively. Approved for public release; distribution is unlimited. 11 8...ARL-TN-0756 ● MAY 2016 US Army Research Laboratory Stress Optical Coefficient, Test Methodology, and Glass Standard Evaluation
Subgrid snow depth coefficient of variation within complex mountainous terrain
Sexstone, Graham A.; Fassnacht, Steven R.; López-Moreno, Juan Ignacio; Christopher A. Hiemstra
2016-01-01
Given the substantial variability of snow in complex mountainous terrain, a considerable challenge of coarse scale modeling applications is accurately representing the subgrid variability of snowpack properties. The snow depth coefficient of variation (CVds) is a useful metric for characterizing subgrid snow distributions but has not been well defined by a parameterization for mountainous environments. This study utilizes lidar-derived snow depth datasets from mountainous terrain in Colorado,...
A drying coefficient for building materials
DEFF Research Database (Denmark)
Scheffler, Gregor Albrecht; Plagge, Rudolf
2009-01-01
The drying experiment is an important element of the hygrothermal characterisation of building materials. Contrary to other moisture transport experiments as the vapour diffusion and the water absorption test, it is until now not possible to derive a simple coefficient for the drying. However...... coefficient is defined which can be determined based on measured drying data. The correlation of this coefficient with the water absorption and the vapour diffusion coefficient is analyzed and its additional information content is critically challenged. As result, a drying coefficient has been derived...... and defined as a new and independent material parameter. It contains information about the moisture transport properties throughout the wide range of moisture contents from hygroscopic up to saturation. With this new and valuable coefficient, it is now possible to distinguish and select building materials...
INVERSE COEFFICIENT PROBLEMS FOR PARABOLIC HEMIVARIATIONAL INEQUALITIES
Institute of Scientific and Technical Information of China (English)
Liu Zhenhai; I.Szántó
2011-01-01
This paper is devoted to the class of inverse problems for a nonlinear parabolic hemivariational inequality.The unknown coefficient of the operator depends on the gradient of the solution and belongs to a set of admissible coefficients.It is proved that the convergence of solutions for the corresponding direct problems continuously depends on the coefficient convergence.Based on this result the existence of a quasisolution of the inverse problem is obtained.
Local Transfer Coefficient, Smooth Channel
Directory of Open Access Journals (Sweden)
R. T. Kukreja
1998-01-01
Full Text Available Naphthalene sublimation technique and the heat/mass transfer analogy are used to determine the detailed local heat/mass transfer distributions on the leading and trailing walls of a twopass square channel with smooth walls that rotates about a perpendicular axis. Since the variation of density is small in the flow through the channel, buoyancy effect is negligible. Results show that, in both the stationary and rotating channel cases, very large spanwise variations of the mass transfer exist in he turn and in the region immediately downstream of the turn in the second straight pass. In the first straight pass, the rotation-induced Coriolis forces reduce the mass transfer on the leading wall and increase the mass transfer on the trailing wall. In the turn, rotation significantly increases the mass transfer on the leading wall, especially in the upstream half of the turn. Rotation also increases the mass transfer on the trailing wall, more in the downstream half of the turn than in the upstream half of the turn. Immediately downstream of the turn, rotation causes the mass transfer to be much higher on the trailing wall near the downstream corner of the tip of the inner wall than on the opposite leading wall. The mass transfer in the second pass is higher on the leading wall than on the trailing wall. A slower flow causes higher mass transfer enhancement in the turn on both the leading and trailing walls.
DIFFERENCE SCHEMES BASING ON COEFFICIENT APPROXIMATION
Institute of Scientific and Technical Information of China (English)
MOU Zong-ze; LONG Yong-xing; QU Wen-xiao
2005-01-01
In respect of variable coefficient differential equations, the equations of coefficient function approximation were more accurate than the coefficient to be frozen as a constant in every discrete subinterval. Usually, the difference schemes constructed based on Taylor expansion approximation of the solution do not suit the solution with sharp function.Introducing into local bases to be combined with coefficient function approximation, the difference can well depict more complex physical phenomena, for example, boundary layer as well as high oscillatory, with sharp behavior. The numerical test shows the method is more effective than the traditional one.
Magnetoelectric voltage coefficients of magnetoelectric composites
Institute of Scientific and Technical Information of China (English)
WAN Yong-ping; ZHONG Zheng; QIU Jin-hao
2006-01-01
The magnetoelectric(ME) effect of the particulate magnetostrictive/piezoelectric composite was theoretically studied. The dependence of the ME voltage coefficients on the material properties of the magnetostrictive phase was discussed. The permittivity,permeability and the elastic modulus of the magnetostrictive phase generally have obvious influences on the ME voltage coefficients. The magnetostrictive phase with a large permittivity,large permeability or stiffer modulus will respectively contribute to the higher ME voltage coefficients. For a certain kind of piezoelectric matrix,the ME voltage coefficients can be improved to some extent by choosing those magnetostrictive materials with large permittivity,permeability or high elastic modulus.
Why the Method of Undetermined Coefficients Works.
Ross, Clay C., Jr.
1991-01-01
This note presents a simple theorem which explains why the method of undetermined coefficients works in finding a particular solution, both for differential equations and difference equations. (Author)
Why the Method of Undetermined Coefficients Works.
Ross, Clay C., Jr.
1991-01-01
This note presents a simple theorem which explains why the method of undetermined coefficients works in finding a particular solution, both for differential equations and difference equations. (Author)
Effective stress coefficient for uniaxial strain condition
DEFF Research Database (Denmark)
Alam, Mohammad Monzurul; Fabricius, Ida Lykke
2012-01-01
the reason for change in effective stress coefficient under stress. Our model suggests that change in effective stress coefficient will be higher at uniaxial stress condition than at hydrostatic condition. We derived equations from the original definition of Biot to estimate effective stress coefficient from...... one dimensional rock mechanical deformation. We further investigated the effect of boundary condition on the stress dependency of effective stress coefficient and discussed its application in reservoir study. As stress field in the reservoirs are most unlikely to be hydrostatic, effective stress...
Wang, Gang-Jin; Xie, Chi; Chen, Shou; Yang, Jiao-Jiao; Yang, Ming-Yan
2013-09-01
In this study, we first build two empirical cross-correlation matrices in the US stock market by two different methods, namely the Pearson’s correlation coefficient and the detrended cross-correlation coefficient (DCCA coefficient). Then, combining the two matrices with the method of random matrix theory (RMT), we mainly investigate the statistical properties of cross-correlations in the US stock market. We choose the daily closing prices of 462 constituent stocks of S&P 500 index as the research objects and select the sample data from January 3, 2005 to August 31, 2012. In the empirical analysis, we examine the statistical properties of cross-correlation coefficients, the distribution of eigenvalues, the distribution of eigenvector components, and the inverse participation ratio. From the two methods, we find some new results of the cross-correlations in the US stock market in our study, which are different from the conclusions reached by previous studies. The empirical cross-correlation matrices constructed by the DCCA coefficient show several interesting properties at different time scales in the US stock market, which are useful to the risk management and optimal portfolio selection, especially to the diversity of the asset portfolio. It will be an interesting and meaningful work to find the theoretical eigenvalue distribution of a completely random matrix R for the DCCA coefficient because it does not obey the Marčenko-Pastur distribution.
Drag Coefficient of Thin Flexible Cylinder
Subramanian, Chelakara; Gurram, Harika
2015-11-01
Measurements of drag coefficients of thin flexible cylindrical wires are described for the Reynolds number range between 250 - 1000. Results indicate that the coefficient values are about 20 to 30 percent lower than the reported laminar flow values for rigid cylinders. Possible fluid dynamics mechanism causing the reduction in drag will be discussed.
Problems with Discontinuous Diffusion/Dispersion Coefficients
Directory of Open Access Journals (Sweden)
Stefano Ferraris
2012-01-01
accurate on smooth solutions and based on a special numerical treatment of the diffusion/dispersion coefficients that makes its application possible also when such coefficients are discontinuous. Numerical experiments confirm the convergence of the numerical approximation and show a good behavior on a set of benchmark problems in two space dimensions.
A gain-coefficient switched Alexandrite laser
Lee, Chris J.; Slot, van der Peter J.M.; Boller, Klaus-J.
2013-01-01
We report on a gain-coefficient switched Alexandrite laser. An electro-optic modulator is used to switch between high and low gain states by making use of the polarization dependent gain of Alexandrite. In gain-coefficient switched mode, the laser produces 85 ns pulses with a pulse energy of 240 mJ
Alternatives to Pearson's and Spearman's Correlation Coefficients
Smarandache, Florentin
2008-01-01
This article presents several alternatives to Pearson's correlation coefficient and many examples. In the samples where the rank in a discrete variable counts more than the variable values, the mixtures that we propose of Pearson's and Spearman's correlation coefficients give better results.
Efficient Estimation in Heteroscedastic Varying Coefficient Models
Directory of Open Access Journals (Sweden)
Chuanhua Wei
2015-07-01
Full Text Available This paper considers statistical inference for the heteroscedastic varying coefficient model. We propose an efficient estimator for coefficient functions that is more efficient than the conventional local-linear estimator. We establish asymptotic normality for the proposed estimator and conduct some simulation to illustrate the performance of the proposed method.
Estimating Runoff Coefficients Using Weather Radars
DEFF Research Database (Denmark)
Ahm, Malte; Thorndahl, Søren Liedtke; Rasmussen, Michael R.
2012-01-01
This paper presents a method for estimating runoff coefficients of urban drainage catchments based on a combination of high resolution weather radar data and insewer flow measurements. By utilising the spatial variability of the precipitation it is possible to estimate the runoff coefficients...
Heat transfer coefficient for boiling carbon dioxide
DEFF Research Database (Denmark)
Knudsen, Hans Jørgen Høgaard; Jensen, Per Henrik
1998-01-01
Heat transfer coefficient and pressure drop for boiling carbon dioxide (R744) flowing in a horizontal pipe has been measured. The calculated heat transfer coeeficient has been compared with the Chart correlation of Shah. The Chart Correlation predits too low heat transfer coefficient but the ratio...
Estimating Runoff Coefficients Using Weather Radars
DEFF Research Database (Denmark)
Ahm, Malte; Thorndahl, Søren Liedtke; Rasmussen, Michael R.;
2012-01-01
This paper presents a method for estimating runoff coefficients of urban drainage catchments based on a combination of high resolution weather radar data and insewer flow measurements. By utilising the spatial variability of the precipitation it is possible to estimate the runoff coefficients...
Determination of the surface drag coefficient
DEFF Research Database (Denmark)
Mahrt, L.; Vickers, D.; Sun, J.L.
2001-01-01
This study examines the dependence of the surface drag coefficient on stability, wind speed, mesoscale modulation of the turbulent flux and method of calculation of the drag coefficient. Data sets over grassland, sparse grass, heather and two forest sites are analyzed. For significantly unstable ...
Commentary on Coefficient Alpha: A Cautionary Tale
Green, Samuel B.; Yang, Yanyun
2009-01-01
The general use of coefficient alpha to assess reliability should be discouraged on a number of grounds. The assumptions underlying coefficient alpha are unlikely to hold in practice, and violation of these assumptions can result in nontrivial negative or positive bias. Structural equation modeling was discussed as an informative process both to…
Graphite friction coefficient for various conditions
Institute of Scientific and Technical Information of China (English)
2001-01-01
The friction coefficient the graphite used in the Tsinghua University 10MW High Tem-perature Gas-Cooled Reactor was analyzed for various conditions. The variation of the graphitefriction coefficient was measured for various sliding velocities, sliding distances, normal loads, en-vironments and temperatures. A scanning elector microscope (SEM) was used to analyze the fric-tion surfaces.
A gain-coefficient switched Alexandrite laser
Lee, Chris J; Boller, Klaus-J
2012-01-01
We report on a gain-coefficient switched Alexandrite laser. An electro-optic modulator is used to switch between high and low gain states by making use of the polarization dependent gain of Alexandrite. In gain-coefficient switched mode, the laser produces 85 ns pulses with a pulse energy of 240 mJ at a repetition rate of 5 Hz.
Helioseismic Solar Cycle Changes and Splitting Coefficients
Indian Academy of Sciences (India)
S. C. Tripathy; Kiran Jain; A. Bhatnagar
2000-09-01
Using the GONG data for a period over four years, we have studied the variation of frequencies and splitting coefficients with solar cycle. Frequencies and even-order coefficients are found to change significantly with rising phase of the solar cycle. We also find temporal variations in the rotation rate near the solar surface.
Quasihomogeneous distributions
von Grudzinski, O
1991-01-01
This is a systematic exposition of the basics of the theory of quasihomogeneous (in particular, homogeneous) functions and distributions (generalized functions). A major theme is the method of taking quasihomogeneous averages. It serves as the central tool for the study of the solvability of quasihomogeneous multiplication equations and of quasihomogeneous partial differential equations with constant coefficients. Necessary and sufficient conditions for solvability are given. Several examples are treated in detail, among them the heat and the Schrödinger equation. The final chapter is devoted to quasihomogeneous wave front sets and their application to the description of singularities of quasihomogeneous distributions, in particular to quasihomogeneous fundamental solutions of the heat and of the Schrödinger equation.
An Efficient Approach for Computing Silhouette Coefficients
Directory of Open Access Journals (Sweden)
Moh'd B. Al- Zoubi
2008-01-01
Full Text Available One popular approach for finding the best number of clusters (K in a data set is through computing the silhouette coefficients. The silhouette coefficients for different values of K, are first found and then the maximum value of these coefficients is chosen. However, computing the silhouette coefficient for different Ks is a very time consuming process. This is due to the amount of CPU time spent on distance calculations. A proposed approach to compute the silhouette coefficient quickly had been presented. The approach was based on decreasing the number of addition operations when computing distances. The results were efficient and more than 50% of the CPU time was achieved when applied to different data sets.
Estimation of the simple correlation coefficient.
Shieh, Gwowen
2010-11-01
This article investigates some unfamiliar properties of the Pearson product-moment correlation coefficient for the estimation of simple correlation coefficient. Although Pearson's r is biased, except for limited situations, and the minimum variance unbiased estimator has been proposed in the literature, researchers routinely employ the sample correlation coefficient in their practical applications, because of its simplicity and popularity. In order to support such practice, this study examines the mean squared errors of r and several prominent formulas. The results reveal specific situations in which the sample correlation coefficient performs better than the unbiased and nearly unbiased estimators, facilitating recommendation of r as an effect size index for the strength of linear association between two variables. In addition, related issues of estimating the squared simple correlation coefficient are also considered.
Discharge coefficient of small sonic nozzles
Directory of Open Access Journals (Sweden)
Yin Zhao-Qin
2014-01-01
Full Text Available The purpose of this investigation is to understand flow characteristics in mini/micro sonic nozzles, in order to precisely measure and control miniscule flowrates. Experimental and numerical simulation methods have been used to study critical flow Venturi nozzles. The results show that the nozzle’s size and shape influence gas flow characteristics which leading the boundary layer thickness to change, and then impact on the discharge coefficient. With the diameter of sonic nozzle throat decreasing, the discharge coefficient reduces. The maximum discharge coefficient exits in the condition of the inlet surface radius being double the throat diameter. The longer the diffuser section, the smaller the discharge coefficient becomes. Diffuser angle affects the discharge coefficient slightly.
Estimating beta-mixing coefficients via histograms
McDonald, Daniel J; Schervish, Mark
2011-01-01
The literature on statistical learning for time series often assumes asymptotic independence or "mixing" of data sources. Beta-mixing has long been important in establishing the central limit theorem and invariance principle for stochastic processes; recent work has identified it as crucial to extending results from empirical processes and statistical learning theory to dependent data, with quantitative risk bounds involving the actual beta coefficients. There is, however, presently no way to actually estimate those coefficients from data; while general functional forms are known for some common classes of processes (Markov processes, ARMA models, etc.), specific coefficients are generally beyond calculation. We present an l1-risk consistent estimator for the beta-mixing coefficients, based on a single stationary sample path. Since mixing coefficients involve infinite-order dependence, we use an order-d Markov approximation. We prove high-probability concentration results for the Markov approximation and show...
A novel method for measuring polymer-water partition coefficients.
Zhu, Tengyi; Jafvert, Chad T; Fu, Dafang; Hu, Yue
2015-11-01
Low density polyethylene (LDPE) often is used as the sorbent material in passive sampling devices to estimate the average temporal chemical concentration in water bodies or sediment pore water. To calculate water phase chemical concentrations from LDPE concentrations accurately, it is necessary to know the LDPE-water partition coefficients (KPE-w) of the chemicals of interest. However, even moderately hydrophobic chemicals have large KPE-w values, making direct measurement experimentally difficult. In this study we evaluated a simple three phase system from which KPE-w can be determined easily and accurately. In the method, chemical equilibrium distribution between LDPE and a surfactant micelle pseudo-phase is measured, with the ratio of these concentrations equal to the LDPE-micelle partition coefficient (KPE-mic). By employing sufficient mass of polymer and surfactant (Brij 30), the mass of chemical in the water phase remains negligible, albeit in equilibrium. In parallel, the micelle-water partition coefficient (Kmic-w) is determined experimentally. KPE-w is the product of KPE-mic and Kmic-w. The method was applied to measure values of KPE-w for 17 polycyclic aromatic hydrocarbons, 37 polychlorinated biphenyls, and 9 polybrominated diphenylethers. These values were compared to literature values. Mass fraction-based chemical activity coefficients (γ) were determined in each phase and showed that for each chemical, the micelles and LDPE had nearly identical affinity.
Rumynin, Vyacheslav G; Nikulenkov, Anton M
2016-10-01
The paper presents a study of the sorption properties of sediments of different geological ages and lithological types, governing radionuclide retention in the subsurface (up to 160 m beneath the surface) within the area of potential influence of the Northwestern Center of Atomic Energy (NWCAE), St. Petersburg region, RF. The focus of this work is mostly on the sedimentary rocks of two types, i.e., weakly cemented sandstone and lithified clay formations of Cambrian and Vendian series. The first lithological unit is associated with a groundwater reservoir (Lomonosov aquifer), and the second one, with both a relative aquitard in the upper part of the Vendian formation (Kotlin clay) and a regional aquifer (Gdov aquifer) in the lower part of the formation. The main mechanisms responsible for the variability of the sorption distribution coefficient (Kd, defined as the ratio of the concentration of solute on solid phase to its concentration in solution at equilibrium) was identified for radionuclides such as Sr-90, Cs-137, Co-60, Pu-239,240, and Am-241. It was shown that the main factors contributing to the chemical heterogeneity of the Cambrian sandstone were related to the presence of secondary minerals (iron and magnesium oxides and hydroxides produced by the weathering process) in trace amounts, forming correlated layer structures. The statistical analysis of nonlinear isotherms confirmed this conclusion. For the Vendian formation, a determinate trend was established in the Kd change over depth as a result of temporal trends in the sedimentation process and pore-water chemistry. The geostatistical characteristics and the spatial correlation models for describing linear sorption of different radionuclides are not identical, and the exhibition of chemical heterogeneity of sedimentary rock of a particular lithological type depends on radionuclide chemistry. Moreover, variogram analysis for some Kd data sets (both in Cambrian and Vendian formations) demonstrates the
Tracking time-varying coefficient-functions
DEFF Research Database (Denmark)
Nielsen, Henrik Aalborg; Nielsen, Torben Skov; Joensen, Alfred K.;
2000-01-01
is a combination of recursive least squares with exponential forgetting and local polynomial regression. It is argued, that it is appropriate to let the forgetting factor vary with the value of the external signal which is the argument of the coefficient functions. Some of the key properties of the modified method......, but otherwise unknown, functions of a low-dimensional input process. These coefficient functions are estimated adaptively and recursively without specifying a global parametric, form, i.e. the method allows for online tracking of the coefficient functions. Essentially, in its most simple form, the method...
Spatial correlation coefficient images for ultrasonic detection.
Cepel, Raina; Ho, K C; Rinker, Brett A; Palmer, Donald D; Lerch, Terrence P; Neal, Steven P
2007-09-01
In ultrasonics, image formation and detection are generally based on signal amplitude. In this paper, we introduce correlation coefficient images as a signal-amplitude independent approach for image formation. The correlation coefficients are calculated between A-scans digitized at adjacent measurement positions. In these images, defects are revealed as regions of high or low correlation relative to the background correlations associated with noise. Correlation coefficient and C-scan images are shown to demonstrate flat-bottom-hole detection in a stainless steel annular ring and crack detection in an aluminum aircraft structure.
Coefficient of restitution of aspherical particles.
Glielmo, Aldo; Gunkelmann, Nina; Pöschel, Thorsten
2014-11-01
We consider the motion of an aspherical inelastic particle of dumbbell type bouncing repeatedly on a horizontal flat surface. The coefficient of restitution of such a particle depends not only on material properties and impact velocity but also on the angular orientation at the instant of the collision whose variance is considerable, even for small eccentricity. Assuming random angular orientation of the particle at the instant of contact we characterize the measured coefficient of restitution as a fluctuating quantity and obtain a wide probability density function including a finite probability for negative values of the coefficient of restitution. This may be understood from the partial exchange of translational and rotational kinetic energy.
Heat transfer coefficient for boiling carbon dioxide
DEFF Research Database (Denmark)
Knudsen, Hans Jørgen Høgaard; Jensen, Per Henrik
1998-01-01
between the measured and the calculated heat transfer coefficient is nearly constant and equal 1.9. With this factor the correlation predicts the measured data within 14% (RMS). The pressure drop is of the same order as the measuring uncertainty and the pressure drop has not been compared with correlation's.......Heat transfer coefficient and pressure drop for boiling carbon dioxide (R744) flowing in a horizontal pipe has been measured. The calculated heat transfer coeeficient has been compared with the Chart correlation of Shah. The Chart Correlation predits too low heat transfer coefficient but the ratio...
Soccer ball lift coefficients via trajectory analysis
Energy Technology Data Exchange (ETDEWEB)
Goff, John Eric [Department of Physics, Lynchburg College, Lynchburg, VA 24501 (United States); Carre, Matt J, E-mail: goff@lynchburg.ed [Department of Mechanical Engineering, University of Sheffield, Sheffield S1 3JD (United Kingdom)
2010-07-15
We performed experiments in which a soccer ball was launched from a machine while two high-speed cameras recorded portions of the trajectory. Using the trajectory data and published drag coefficients, we extracted lift coefficients for a soccer ball. We determined lift coefficients for a wide range of spin parameters, including several spin parameters that have not been obtained by today's wind tunnels. Our trajectory analysis technique is not only a valuable tool for professional sports scientists, it is also accessible to students with a background in undergraduate-level classical mechanics.
Inferences on the common coefficient of variation.
Tian, Lili
2005-07-30
The coefficient of variation is often used as a measure of precision and reproducibility of data in medical and biological science. This paper considers the problem of making inference about the common population coefficient of variation when it is a priori suspected that several independent samples are from populations with a common coefficient of variation. The procedures for confidence interval estimation and hypothesis testing are developed based on the concepts of generalized variables. The coverage properties of the proposed confidence intervals and type-I errors of the proposed tests are evaluated by simulation. The proposed methods are illustrated by a real life example.
Gas Damping Coefficient Research for MEMS Comb Linear Vibration Gyroscope
Qiufen, G; Feng, S; Fuqiang, L
2008-01-01
Silicon-MEMS gyroscope is an important part of MEMS (Micro Electrical Mechanical System). There are some disturb ignored in traditional gyroscope that must be evaluated newly because of its smaller size (reach the level of micron). In these disturb, the air pressure largely influences the performance of MEMS gyroscope. Different air pressure causes different gas damping coefficient for the MEMS comb linear vibration gyroscope and different gas damping coefficient influences the quality factor of the gyroscope directive. The quality factor influences the dynamic working bandwidth of the MEMS comb linear vibration gyroscope, so it is influences the output characteristic of the MEMS comb linear vibration gyroscope. The paper shows the relationship between the air pressure and the output amplified and phase of the detecting axis through analyzing the air pressure influence on the MEMS comb linear vibration gyroscope. It discusses the influence on the frequency distribute and quality factor of the MEMS comb linear...
Coefficient of friction of a starved lubricated spur gear pair
Energy Technology Data Exchange (ETDEWEB)
Liu, Huaiju; Zhu, Caichao; Sun, Zhangdong; Zhang, Yuanyuan; Song, Chaosheng [Chongqing University, Chongqing (China)
2016-05-15
The frictional power loss issue of gear pairs becomes an important concern in both industry and academia due to the requirement of the energy saving and the improvement of power density of gear drives. A thermal starved elastohydrodynamic lubrication model is developed to study the tribological performance of a spur gear pair under starved lubrication conditions. The contact pressure, the film thickness, the temperature rise, the frictional power loss, as well as the coefficient of friction are evaluated by considering the variation of the curvature radius, the sliding/rolling motion, and the load distribution of gear tooth within the meshing period. Effects of lubrication starvation condition, load and speed on the coefficient of friction are studied.
Relativistic quantum transport coefficients for second-order viscous hydrodynamics
Florkowski, Wojciech; Maksymiuk, Ewa; Ryblewski, Radoslaw; Strickland, Michael
2015-01-01
We express the transport coefficients appearing in the second-order evolution equations for bulk viscous pressure and shear stress tensor using Bose-Einstein, Boltzmann, and Fermi-Dirac statistics for the equilibrium distribution function and Grad's 14-moment approximation as well as the method of Chapman-Enskog expansion for the non-equilibrium part. Specializing to the case of boost-invariant and transversally homogeneous longitudinal expansion of the viscous medium, we compare the results obtained using the above methods with those obtained from the exact solution of massive 0+1d Boltzmann equation in the relaxation-time approximation. We show that compared to the 14-moment approximation, the hydrodynamic transport coefficients obtained using the Chapman-Enskog method result in better agreement with the exact solution of the Boltzmann equation in relaxation-time approximation.
The HD+ dissociative recombination rate coefficient at low temperature
Directory of Open Access Journals (Sweden)
Wolf A.
2015-01-01
Full Text Available The effect of the rotational temperature of the ions is considered for low-energy dissociative recombination (DR of HD+. Merged beams measurements with HD+ ions of a rotational temperature near 300 K are compared to multichannel quantum defect theory calculations. The thermal DR rate coefficient for a Maxwellian electron velocity distribution is derived from the merged-beams data and compared to theoretical results for a range of rotational temperatures. Good agreement is found for the theory with 300 K rotational temperature. For a low-temperature plasma environment where also the rotational temperature assumes 10 K, theory predicts a considerably higher thermal DR rate coefficient. The origin of this is traced to predicted resonant structures of the collision-energy dependent DR cross section at few-meV collision energies for the particular case of HD+ ions in the rotational ground state.
Heat transfer coefficient of cryotop during freezing.
Li, W J; Zhou, X L; Wang, H S; Liu, B L; Dai, J J
2013-01-01
Cryotop is an efficient vitrification method for cryopreservation of oocytes. It has been widely used owing to its simple operation and high freezing rate. Recently, the heat transfer performance of cryotop was studied by numerical simulation in several studies. However, the range of heat transfer coefficient in the simulation is uncertain. In this study, the heat transfer coefficient for cryotop during freezing process was analyzed. The cooling rates of 40 percent ethylene glycol (EG) droplet in cryotop during freezing were measured by ultra-fast measurement system and calculated by numerical simulation at different value of heat transfer coefficient. Compared with the results obtained by two methods, the range of the heat transfer coefficient necessary for the numerical simulation of cryotop was determined, which is between 9000 W/(m(2)·K) and 10000 W/(m (2)·K).
Neutron kerma coefficient: Reference tissue for tumours
Energy Technology Data Exchange (ETDEWEB)
Paredes, L., E-mail: lydia.paredes@inin.gob.m [National Institute of Nuclear Research (Mexico); Azorin, J. [Basic Sciences Division, Autonomous Metropolitan University (Mexico); Balcazar, M. [National Institute of Nuclear Research (Mexico); Francois, J.L. [Engineering Faculty, Autonomous National University of Mexico (Mexico)
2010-12-15
Neutron kerma coefficients were calculated in different media: 4 malignant tumours, 5 normal tissues and 3 tissue substitute in the range 11 eV-29 MeV. The objective was to identify which is the material that better reproduces the behavior of these tumours and tissues. These tissues have clinical interest in interstitial brachytherapy applications with fast neutron source (Cf-252). The small differences of elemental composition among these tissues produce variation in the neutron kerma coefficients. The results show that the neutron kerma coefficients for malignant tumours are smaller than soft tissue from 6% to 9%. Also, the muscle is the tissue that best represents the dosimetric behavior for the tumours and tissues analyzed in this paper for neutron energies >1 keV, where this coefficients show minor variation.
Friction coefficient dependence on electrostatic tribocharging
Burgo, Thiago A. L.; Silva, Cristiane A.; Balestrin, Lia B. S.; Galembeck, Fernando
2013-08-01
Friction between dielectric surfaces produces patterns of fixed, stable electric charges that in turn contribute electrostatic components to surface interactions between the contacting solids. The literature presents a wealth of information on the electronic contributions to friction in metals and semiconductors but the effect of triboelectricity on friction coefficients of dielectrics is as yet poorly defined and understood. In this work, friction coefficients were measured on tribocharged polytetrafluoroethylene (PTFE), using three different techniques. As a result, friction coefficients at the macro- and nanoscales increase many-fold when PTFE surfaces are tribocharged, but this effect is eliminated by silanization of glass spheres rolling on PTFE. In conclusion, tribocharging may supersede all other contributions to macro- and nanoscale friction coefficients in PTFE and probably in other insulating polymers.
Cohomology with Coefficients for Operadic Coalgebras
Indian Academy of Sciences (India)
Anita Majumdar; Donald Yau
2009-09-01
Corepresentations of a coalgebra over a quadratic operad are defined, and various characterizations of them are given. Cohomology of such an operadic coalgebra with coefficients in a corepresentation is then studied.
Torsion method for measuring piezooptic coefficients
Energy Technology Data Exchange (ETDEWEB)
Skab, I.; Smaga, I.; Savaryn, V.; Vasylkiv, Yu.; Vlokh, R. [Institute of Physical Optics, Lviv (Ukraine)
2011-01-15
We develop and describe analytically a torsion method for measuring piezooptic coefficients associated with shear stresses. It is shown that the method enables to increase significantly the accuracy of determination of piezooptic coefficients. The method and the appropriate apparatus are verified experimentally on the example of LiNbO{sub 3} crystals. (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
Diffusion coefficients in viscous sodium alginate solutions
Aoki, K.; Wang, B; Chen, J.; Nishiumi, T.
2012-01-01
Sodium alginate solution, being viscous hydrocolloid, was examined voltammetricallyin the context of viscous effects by use of a ferrocenyl compound as a redox probe.Voltammograms were almost independent of concentrations of sodium alginate even ina solid-like state. Diffusion coefficients of the ferrocenyl compound did not vary withviscosity evaluated by a viscometer. Ionic conductivity of sodium alginate was alsoindependent of the viscosity. In contrast, diffusion coefficients of the latex ...
Thermal expansion coefficient of binary semiconductors
Energy Technology Data Exchange (ETDEWEB)
Kumar, V.; Sastry, B.S.R. [Indian School of Mines, Dhanbad (India). Dept. of Electronics and Instrumentation
2001-07-01
The linear thermal expansion coefficient of tetrahedrally coordinated A{sup II}B{sup VI} and A{sup III}B{sup V} semiconductors has been calculated using plasmon energy data. A simple relation between the bond length and plasmon energy has been derived. The calculated values of thermal expansion coefficient and bond length have been compared with the experimental values and the values reported by different workers. An excellent experiment has been obtained between them. (orig.)
Mass transfer coefficients in metallurgical reactors
Institute of Scientific and Technical Information of China (English)
无
2003-01-01
An overview on the application and achievements of physico-mathematical modeling of metallurgical processes in Chinais briefly declared. The important role of coefficients in model formulation is shown from our experience. The mass transfer coeffi-cients of the slag-metal reactions and the gas-metal reactions are discussed referring to the flow conditions near the interface. Theinfluence of the surface-active species on the mass transfer and the inteffacial reaction is also discussed briefly.
Thermal Expansion Coefficients of Thin Crystal Films
Institute of Scientific and Technical Information of China (English)
无
2005-01-01
The formulas for atomic displacements and Hamiltonian of a thin crystal film in phonon occupation number representation are obtained with the aid of Green's function theory. On the basis of these results, the formulas for thermal expansion coefficients of the thin crystal film are derived with the perturbation theory, and the numerical calculations are carried out. The results show that the thinner films have larger thermal expansion coefficients.
Concordance correlation coefficient applied to discrete data.
Carrasco, Josep L; Jover, Lluis
2005-12-30
In any field in which decisions are subject to measurements, interchangeability between the methods used to obtain these measurements is essential. To consider methods as interchangeable, a certain degree of agreement is needed between the measurements they provide. The concordance correlation coefficient is an index that assesses the strength of agreement and it has been widely applied in situations in which measurements are made on a continuous scale. Recently the concordance correlation coefficient has been defined as a specific intraclass correlation coefficient estimated by the variance components of a Normal-Normal mixed linear model. Although this coefficient was defined for the continuous scale case, it may also be used with a discrete scale. In this case the data are often transformed and normalized, and the concordance correlation is applied. This study discusses the expression of the concordance correlation coefficient for discrete Poisson data by means of the Poisson-Normal generalized linear mixed model. The behaviour of the concordance correlation coefficient estimate is assessed by means of a simulation study, in which the estimates were compared using four models: three Normal-Normal mixed models with raw data, log-transformed data and square-root transformed data, and the Poisson-Normal generalized linear mixed model. An example is provided in which two different methods are used to measure CD34+ cells.
Local Rank Inference for Varying Coefficient Models.
Wang, Lan; Kai, Bo; Li, Runze
2009-12-01
By allowing the regression coefficients to change with certain covariates, the class of varying coefficient models offers a flexible approach to modeling nonlinearity and interactions between covariates. This paper proposes a novel estimation procedure for the varying coefficient models based on local ranks. The new procedure provides a highly efficient and robust alternative to the local linear least squares method, and can be conveniently implemented using existing R software package. Theoretical analysis and numerical simulations both reveal that the gain of the local rank estimator over the local linear least squares estimator, measured by the asymptotic mean squared error or the asymptotic mean integrated squared error, can be substantial. In the normal error case, the asymptotic relative efficiency for estimating both the coefficient functions and the derivative of the coefficient functions is above 96%; even in the worst case scenarios, the asymptotic relative efficiency has a lower bound 88.96% for estimating the coefficient functions, and a lower bound 89.91% for estimating their derivatives. The new estimator may achieve the nonparametric convergence rate even when the local linear least squares method fails due to infinite random error variance. We establish the large sample theory of the proposed procedure by utilizing results from generalized U-statistics, whose kernel function may depend on the sample size. We also extend a resampling approach, which perturbs the objective function repeatedly, to the generalized U-statistics setting; and demonstrate that it can accurately estimate the asymptotic covariance matrix.
Fourier coefficient description of left ventricular shape.
Round, W H; Bates, R H; Ikram, H
1991-12-01
A method of quantifying the shape of the left ventricle of the heart as seen in 2D echocardiograms was developed. It is based on describing the shape in terms of the coefficients a fifth-order trigonometric Fourier series. Such a series has eleven Fourier coefficients which is too large a number for clinical application so pairs of coefficients are combined to give six coefficients (alpha 0, alpha 1, ... , alpha 5). A trial was conducted to test the ability of the coefficient description to classify subjects as having normal right ventricles or ventricles with an apical abnormality. The tests showed that one of the coefficients (alpha 2) was higher for the subjects with an apical abnormality and that this difference increased with exercise. This is as was expected. However, it was found to be difficult to get a reliable estimate of alpha 2 from a single scan of a patient and that it is therefore probably necessary to average data from several scans to obtain a reliable alpha 2 value for a single patient.
Equality of Medical Health Resource Allocation in China Based on the Gini Coefficient Method.
Directory of Open Access Journals (Sweden)
Jian Jin
2015-04-01
Full Text Available The Chinese government is trying to achieve the goal of "universal access to basic health care services". However, the inequality of the distribution of health care resources across the country is the biggest obstacle. This paper aims to explore these inequalities and the extent to which the method of analysis influences the perception.The indicators of health care resource distribution studied consisted of the number of health care institutions, the number of beds in health care institutions and the number of medical personnel. Data were obtained from the China Statistical Yearbook 2014. The extent of equality was assessed using the Lorenz Curve and Gini Coefficient Method.Health care resource distribution in China demonstrates inequalities. The demographic Gini Coefficients based on the Lorenz Curves for the distribution of health care institutions, beds in health care institutions and medical personnel are 0.190, 0.070 and 0.070 respectively, while the corresponding Coefficients based on geographical areas are 0.616, 0.639 and 0.650.The equality of China's demographically assessed distribution of health care resources is greater than that of its geographically measured distribution. Coefficients expressed by population imply there is ready access to healthcare in all regions, whilst the Coefficients by geographical area apparently indicate inequality. This is the result of the sparsity of population.
Estimation of the Nonlinear Random Coefficient Model when Some Random Effects Are Separable
du Toit, Stephen H. C.; Cudeck, Robert
2009-01-01
A method is presented for marginal maximum likelihood estimation of the nonlinear random coefficient model when the response function has some linear parameters. This is done by writing the marginal distribution of the repeated measures as a conditional distribution of the response given the nonlinear random effects. The resulting distribution…
Spike output jitter, mean firing time and coefficient of variation
Feng, Jianfeng; Brown, David
1998-01-01
To understand how a single neurone processes information, it is critical to examine the relationship between input and output. Marsalek, Koch and Maunsell's study focused on output jitter (standard deviation of output interpike interval) found that for the integrate-and-fire (I&F) model this response measure converges towards zero as the number of inputs increases indefinitely when interarrival times of excitatory inputs (EPSPs) are normally or uniformly distributed. In this work we present a complete, theoretical investigation, corroborated by numerical simulation, of output jitter in the I&F model with a variety of input distributions and a range of values of number of inputs, N. Our main results are: the exponential distribution input is a critical case and its output jitter is independent of N. For input distributions with tails which decrease faster than the exponential distribution, output jitter converges to zero as discovered by Marsalek, Koch and Maunsell; whereas an input distribution with a more slowly decreasing tail induces divergence of output jitter. Exact formulae for mean firing time are also obtained which enable us to estimate the coefficient of variation. The I&F model with leakage is also briefly considered.
Regularization of binomial differential equations with singular coefficients
Goriunov, Andrii
2011-01-01
We propose a regularization of the formal differential expression of order $m \\geqslant 3$ $$ l(y) = i^my^{(m)}(t) + q(t)y(t), \\,t \\in (a, b), $$ applying quasi-derivatives. The distribution coefficient $q$ is supposed to have an antiderivative $Q \\in L([a,b];\\mathbb{C})$. For the symmetric case ($Q = \\bar{Q}$) self-adjoint and maximal dissipative extensions of the minimal operator and its generalized resolvents are described. The resolvent approximation with resrect to the norm of the considered operators is also investigated. The case $m = 2$ for $Q \\in L_2([a, b];\\mathbb{C})$ was investigated earlier.
Variation of the drag coefficient with wind and wave state
Byars, Beverly J.
1985-01-01
Approved for public release; distribution unlimited The dissipation method is used to obtain estimates for the friction velocity, U>t, as well as values for the neutral drag coefficient, C-^jj, for data collected from a coastal tower off San Diego, California. C-q-^ is found to be independent of the ten-meter height windspeed, U-j^q, for velocities between 4-9 m/sec. Its value is estimated to be (0.94+0.4)10 which compares well with values by Smith (1980) and Large and...
Temporal correlation coefficient for directed networks.
Büttner, Kathrin; Salau, Jennifer; Krieter, Joachim
2016-01-01
Previous studies dealing with network theory focused mainly on the static aggregation of edges over specific time window lengths. Thus, most of the dynamic information gets lost. To assess the quality of such a static aggregation the temporal correlation coefficient can be calculated. It measures the overall possibility for an edge to persist between two consecutive snapshots. Up to now, this measure is only defined for undirected networks. Therefore, we introduce the adaption of the temporal correlation coefficient to directed networks. This new methodology enables the distinction between ingoing and outgoing edges. Besides a small example network presenting the single calculation steps, we also calculated the proposed measurements for a real pig trade network to emphasize the importance of considering the edge direction. The farm types at the beginning of the pork supply chain showed clearly higher values for the outgoing temporal correlation coefficient compared to the farm types at the end of the pork supply chain. These farm types showed higher values for the ingoing temporal correlation coefficient. The temporal correlation coefficient is a valuable tool to understand the structural dynamics of these systems, as it assesses the consistency of the edge configuration. The adaption of this measure for directed networks may help to preserve meaningful additional information about the investigated network that might get lost if the edge directions are ignored.
Experimental methodology for obtaining sound absorption coefficients
Directory of Open Access Journals (Sweden)
Carlos A. Macía M
2011-07-01
Full Text Available Objective: the authors propose a new methodology for estimating sound absorption coefficients using genetic algorithms. Methodology: sound waves are generated and conducted along a rectangular silencer. The waves are then attenuated by the absorbing material covering the silencer’s walls. The attenuated sound pressure level is used in a genetic algorithm-based search to find the parameters of the proposed attenuation expressions that include geometric factors, the wavelength and the absorption coefficient. Results: a variety of adjusted mathematical models were found that make it possible to estimate the absorption coefficients based on the characteristics of a rectangular silencer used for measuring the attenuation of the noise that passes through it. Conclusions: this methodology makes it possible to obtain the absorption coefficients of new materials in a cheap and simple manner. Although these coefficients might be slightly different from those obtained through other methodologies, they provide solutions within the engineering accuracy ranges that are used for designing noise control systems.
Drag Coefficient and Foam in Hurricane Conditions.
Golbraikh, E.; Shtemler, Y.
2016-12-01
he present study is motivated by recent findings of saturation and even decrease in the drag coefficient (capping) in hurricane conditions, which is accompanied by the production of a foam layer on the ocean surface. As it is difficult to expect at present a comprehensive numerical modeling of the drag coefficient saturation that is followed by wave breaking and foam production, there is no complete confidence and understanding of the saturation phenomenon. Our semi-empirical model is proposed for the estimation of the foam impact on the variation of the effective drag coefficient, Cd , with the reference wind speed U10 in stormy and hurricane conditions. The proposed model treats the efficient air-sea aerodynamic roughness length as a sum of two weighted aerodynamic roughness lengths for the foam-free and foam-covered conditions. On the available optical and radiometric measurements of the fractional foam coverage,αf, combined with direct wind speed measurements in hurricane conditions, which provide the minimum of the effective drag coefficient, Cd for the sea covered with foam. The present model yields Cd10 versus U10 in fair agreement with that evaluated from both open-ocean and laboratory measurements of the vertical variation of mean wind speed in the range of U10 from low to hurricane speeds. The present approach opens opportunities for drag coefficient modeling in hurricane conditions and hurricane intensity estimation by the foam-coverage value using optical and radiometric measurements.
Zhang, Wanhui; Wei, Chaohai; An, Guanfeng
2015-05-01
In this study, we report the performance of a full-scale conventional activated sludge (A-O1-O2) treatment in eliminating polycyclic aromatic hydrocarbons (PAHs). Both aqueous and solid phases along with the coking wastewater treatment processes were analyzed for the presence of 18 PAHs. It was found that the target compounds occurred widely in raw coking wastewater, treated effluent and sludge samples. In the coking wastewater treatment system, 4-5 ring PAHs were the dominant compounds, while 4 rings PAHs predominated in the sludge samples. Over 98% of the PAH removal was achieved in the coking wastewater treatment plant (WWTP), with the total concentration of PAHs being 21.3 ± 1.9 μg L(-1) in the final effluent. During the coking wastewater treatment processes, the association of the lower molecular weight PAH with suspended solids was generally less than 60%, while the association of higher molecular weight PAHs was greater than 90%. High distribution efficiencies (Kdp and Kds) were found, suggesting that adsorption was the potential removal pathway of PAHs. Finally, the mass balances of PAHs in various stages of the coking WWTP were obtained, and the results indicated that adsorption to sludge was the main removal pathway for PAHs in the coking wastewater treatment processes.
Energy Technology Data Exchange (ETDEWEB)
Paszkuta, M.; Rosanne, M.; Adler, P.M. [Sisyphe, 75 - Paris (France)
2006-10-15
The coefficients that characterize the simultaneous transports of mass, heat, solute and current through compact clays are experimentally and theoretically determined. The role of a characteristic length scale that can be derived from conductivity and permeability is illustrated for the electrokinetic coefficients. The macroscopic Soret coefficient in clays was found five times larger than in the free fluid, presumably because of extra couplings with electrical phenomena. (authors)
Effect of Rare Earths on Diffusion Coefficient and Transfer Coefficient of Carbon during Carburizing
Institute of Scientific and Technical Information of China (English)
无
2001-01-01
The diffusion coefficient of carbon in surface layer of steel-20 rare earth carburized at 880 ℃ and 900 ℃ for 8 h was calculated by substituting the measured layer depths into the diffusion equation. The mathematical model of the transfer coefficient of carbon was deduced based on the kinetics of weight gain during gas carburizing. The calculated results show that the main reason why the gas carburizing process is accelerated is due to the obvious increase in the diffusion coefficient and transfer coefficient of carbon resulted from the addition of RE.
Coefficient of Restitution of Wet Tennis Balls
Directory of Open Access Journals (Sweden)
Eugene Jang
2014-12-01
Full Text Available The coefficient of restitution of a damp tennis ball is of interest to tennis players. Using a spray bottle, water was added to a tennis ball and the mass of water on the wet ball was determined. The ball was then dropped from a fixed height of 0.86 m. The motion was recorded with a video camera and the bounce height was measured. Using the bounce height and the original height, the coefficient of restitution for that mass of added water was determined. The research found the mass of water added to the tennis ball to have a negatively linear relationship with the coefficient of restitution of the tennis ball.
Coefficient of Restitution of Wet Tennis Balls
Directory of Open Access Journals (Sweden)
Eugene Jang
2014-01-01
Full Text Available The coefficient of restitution of a damp tennis ball is of interest to tennis players. Using a spray bottle, water was added to a tennis ball and the mass of water on the wet ball was determined. The ball was then dropped from a fixed height of 0.86 m. The motion was recorded with a video camera and the bounce height was measured. Using the bounce height and the original height, the coefficient of restitution for that mass of added water was determined. The research found the mass of water added to the tennis ball to have a negatively linear relationship with the coefficient of restitution of the tennis ball.
Curvature of Indoor Sensor Network: Clustering Coefficient
Directory of Open Access Journals (Sweden)
2009-03-01
Full Text Available We investigate the geometric properties of the communication graph in realistic low-power wireless networks. In particular, we explore the concept of the curvature of a wireless network via the clustering coefficient. Clustering coefficient analysis is a computationally simplified, semilocal approach, which nevertheless captures such a large-scale feature as congestion in the underlying network. The clustering coefficient concept is applied to three cases of indoor sensor networks, under varying thresholds on the link packet reception rate (PRR. A transition from positive curvature (“meshed” network to negative curvature (“core concentric” network is observed by increasing the threshold. Even though this paper deals with network curvature per se, we nevertheless expand on the underlying congestion motivation, propose several new concepts (network inertia and centroid, and finally we argue that greedy routing on a virtual positively curved network achieves load balancing on the physical network.
Determination of local heat transfer coefficient on the surface of longitudinally finned tubes
Energy Technology Data Exchange (ETDEWEB)
Sobota, T.; Taler, J. [Cracow Univ. of Technology (Poland). Inst. of Process and Power Engineering
2008-06-15
The distribution of the heat transfer coefficient is calculated from temperature measurements at interior points of the solid, and the measured fluid temperature. The unknown parameters associated with the solution were selected to achieve the closest least squares agreement between the computed and measured temperatures using the Levenberg-Marquardt method. The nonlinear least - squares problem is parameterised by assuming the stair-case changes of the heat transfer coefficient on the boundary, or by expressing the space variations of the heat transfer coefficient in its functional form. The determination of the circumferential heat transfer coefficient distribution on the heated tube with two longitudinal fins in cross flow demonstrates the accuracy of the developed method. The actual experimental data were used. Experiments were performed with an array of vertical tubes arranged in staggered pattern. (orig.)
Dielectronic recombination rate coefficients to excited states of Be-like oxygen
Energy Technology Data Exchange (ETDEWEB)
Murakami, Izumi; Safronova, Ulyana I.; Kato, Takako
2001-05-01
We have calculated energy levels, radiative transition probabilities, and autoionization rates for Be-like oxygen (O{sup 4+}) including ls{sup 2}2lnl' (n=2 - 8, l {<=} n - 1) and 1s{sup 2}3l'nl (n=3 - 6, l {<=} n - l) states by multi-configurational Hartree-Fock method (Cowan code) and perturbation theory Z-expansion method (MZ code). The state selective dielectronic recombination rate coefficients to excited states of Be-like O ions are obtained. Configuration mixing plays an important role for the principal quantum number n distribution of the dielectronic recombination rate coefficients for 2snl (n {<=} 5) levels at low electron temperature. The orbital angular momentum quantum number l distribution of the rate coefficients shows a peak at l = 4. The total dielectronic recombination rate coefficient is derived as a function of electron temperature. (author)
Garrido, J.; Casanovas, A.
2012-07-01
A new method for determining the Peltier coefficient of thermoelectric devices has been developed. The Peltier coefficient has been evaluated by measuring the temperature distribution along the junction of two dissimilar materials X and Y. The energy balance has been used to link the Peltier coefficient with the hot and cold temperatures of the metallic blocks of a thermoelectric module (TEM), thus enabling the evaluation of this coefficient. Data on the thermal conductance of the pellets are also needed. The experimental device used in this paper is a TEM composed of N = 71 couples of bismuth telluride, suitably doped to provide individual n and p elements. Using nominal values given by the manufacturer for the Seebeck coefficient of the TEM, the Onsager reciprocal relation has been confirmed.
Estimating inbreeding coefficients from NGS data
DEFF Research Database (Denmark)
Vieira, Filipe Garrett; Fumagalli, Matteo; Albrechtsen, Anders;
2013-01-01
Most methods for Next-Generation Sequencing (NGS) data analyses incorporate information regarding allele frequencies using the assumption of Hardy-Weinberg Equilibrium (HWE) as a prior. However, many organisms including domesticated, partially selfing or with asexual life cycles show strong...... deviations from HWE. For such species, and specially for low coverage data, it is necessary to obtain estimates of inbreeding coefficients (F) for each individual beforecalling genotypes. Here, we present two methods for estimating inbreeding coefficients from NGS data based on an Expectation...
Effective Diffusion Coefficients in Coal Chars
DEFF Research Database (Denmark)
Johnsson, Jan Erik; Jensen, Anker
2001-01-01
Knowledge of effective diffusion coefficients in char particles is important when interpreting experimental reactivity measurements and modeling char combustion or NO and N2O reduction. In this work, NO and N2O reaction with a bituminous coal char was studied in a fixed-bed quartz glass reactor....... The experimental results were compared with theoretical values calculated from the mean pore radius and the cross-linked pore model. The method of mean pore radius underestimated the effective diffusion coefficient more than an order of magnitude. Using the cross-linked pore model, the bimodal pore size...
Sensitivity study of control rod depletion coefficients
Blomberg, Joel
2015-01-01
This report investigates the sensitivity of the control rod depletion coefficients, Sg, to different input parameters and how this affects the accumulated 10B depletion, β. Currently the coefficients are generated with PHOENIX4, but the geometries can be more accurately simulated in McScram. McScram is used to calculate Control Rod Worth, which in turn is used to calculate Nuclear End Of Life, and Sg cannot be generated in the current version of McScram. Therefore, it is also analyzed whether...
Study on the Friction Coefficient in Grinding
Institute of Scientific and Technical Information of China (English)
无
2002-01-01
The friction between the abrasive grains and workpi ec e is a crutial factor determining the main grinding output. Few studies have bee n carried out investigating the values of the friction coefficient in grinding, due to the difficulty of direct measurement. In this paper, a mathematical model of the friction coefficient in grinding has been established with the aid of a new grinding parameter C ge, which has close relations to wheel wear rate Z s, metal removal rate Z w, specific energy u and gr...
Monomeric Friction Coefficient of Metalnanodispersible Polymeric Systems
Directory of Open Access Journals (Sweden)
B.B. Kolupayev
2016-12-01
Full Text Available Influence of a nanodispersible metal excipient in number of 0 5,0 vol.% Cu for the size of a monomeric friction coefficient of polyvinylchloride (PVC systems in temperature range 298 Т (Tg + 10 K is investigated. It is shown that various types of coordination movements of building blocks are described by a friction coefficient which serves as a measure of influence of external fields and ingredients on viscoelastic behavior of a composite. The analysis of processes of a relaxation on the basis of the theory of flexible chains taking into account power and entropic factors is carried out.
Air Flows in Gravity Sewers - Determination of Wastewater Drag Coefficient
DEFF Research Database (Denmark)
Bentzen, Thomas Ruby; Østertoft, Kristian; Vollertsen, Jes
2016-01-01
of the study shows that by integrating the top/side wall shear stresses the log-law models for the air velocity distribution along the unwetted perimeter resulted in a good agreement with the friction forces calculated by use of the Colebrook-White formula for hydraulic smooth pipes. Secondly, the water......Several experiments have been conducted in order to improve the understanding of the wastewater drag and the wall frictional force acting on the headspace air in gravity sewers. The aim of the study is to improve the data basis for a numerical model of natural sewer ventilation. The results...... surface drags were found by log-law models of the velocity distribution in turbulent flows to fit velocity profiles measured from the water surface and by integrating the water surface drags along the wetted perimeter, mean water surface drags were found and a measure of the water surface drag coefficient...
An Information-Theoretic Alternative to the Cronbach's Alpha Coefficient of Item Reliability
Fokoue, Ernest; Gunduz, Necla
2015-01-01
We propose an information-theoretic alternative to the popular Cronbach alpha coefficient of reliability. Particularly suitable for contexts in which instruments are scored on a strictly nonnumeric scale, our proposed index is based on functions of the entropy of the distributions of defined on the sample space of responses. Our reliability index tracks the Cronbach alpha coefficient uniformly while offering several other advantages discussed in great details in this paper.
Directory of Open Access Journals (Sweden)
Shumanova M.V.
2015-03-01
Full Text Available The process fish salting has been studied by the method of photon correlation spectroscopy; the distribution of salt concentration in the solution and herring flesh with skin has been found, diffusion coefficients and salt concentrations used for creating a mathematical model of the salting technology have been worked out; the possibility of determination by this method the coefficient of dynamic viscosity of solutions and different media (minced meat etc. has been considered
Tracer diffusion coefficients in a sheared inelastic Maxwell gas
Garzó, Vicente; Trizac, Emmanuel
2016-07-01
We study the transport properties of an impurity in a sheared granular gas, in the framework of the Boltzmann equation for inelastic Maxwell models. We investigate here the impact of a nonequilibrium phase transition found in such systems, where the tracer species carries a finite fraction of the total kinetic energy (ordered phase). To this end, the diffusion coefficients are first obtained for a granular binary mixture in spatially inhomogeneous states close to the simple shear flow. In this situation, the set of coupled Boltzmann equations are solved by means of a Chapman-Enskog-like expansion around the (local) shear flow distributions for each species, thereby retaining all the hydrodynamic orders in the shear rate a. Due to the anisotropy induced by the shear flow, three tensorial quantities D ij , D p,ij , and D T,ij are required to describe the mass transport process instead of the conventional scalar coefficients. These tensors are given in terms of the solutions of a set of coupled algebraic equations, which can be exactly solved as functions of the shear rate a, the coefficients of restitution {αsr} and the parameters of the mixture (masses and composition). Once the forms of D ij , D p,ij , and D T,ij are obtained for arbitrary mole fraction {{x}1}={{n}1}/≤ft({{n}1}+{{n}2}\\right) (where n r is the number density of species r), the tracer limit ({{x}1}\\to 0 ) is carefully considered for the above three diffusion tensors. Explicit forms for these coefficients are derived showing that their shear rate dependence is significantly affected by the order-disorder transition.
Effective stress coefficient for uniaxial strain condition
DEFF Research Database (Denmark)
Alam, M.M.; Fabricius, I.L.
2012-01-01
one dimensional rock mechanical deformation. We further investigated the effect of boundary condition on the stress dependency of effective stress coefficient and discussed its application in reservoir study. As stress field in the reservoirs are most unlikely to be hydrostatic, effective stress...... determined under uniaxial strain condition will be more relevant in reservoir studies. Copyright 2012 ARMA, American Rock Mechanics Association....
Effective stress coefficient for uniaxial strain condition
DEFF Research Database (Denmark)
Alam, Mohammad Monzurul; Fabricius, Ida Lykke
2012-01-01
one dimensional rock mechanical deformation. We further investigated the effect of boundary condition on the stress dependency of effective stress coefficient and discussed its application in reservoir study. As stress field in the reservoirs are most unlikely to be hydrostatic, effective stress...
Confidence Intervals for Cronbach's Coefficient Alpha Values
A.J. Koning (Alex); Ph.H.B.F. Franses (Philip Hans)
2003-01-01
textabstractCoefficient Alpha, which is widely used in empirical research, estimates the reliability of a test consisting of parallel items. In practice it is difficult to compare values of alpha across studies as it depends on the number of items used. In this paper we provide a simple solution, wh
Recursive Construction of Operator Product Expansion Coefficients
Holland, Jan; Hollands, Stefan
2015-06-01
We derive a novel formula for the derivative of operator product expansion (OPE) coefficients with respect to a coupling constant. The formula involves just the OPE coefficients themselves but no further input, and is in this sense self-consistent. Furthermore, unlike other formal identities of this general nature in quantum field theory (such as the formal expression for the Lagrangian perturbation of a correlation function), our formula requires no further UV-renormalization, i.e., it is completely well-defined from the start. This feature is a result of a cancelation of UV- and IR-divergences between various terms in our identity. Our proof, and an analysis of the features of the identity, is given for the example of massive, Euclidean theory in 4 dimensional Euclidean space. It relies on the renormalization group flow equation method and is valid to arbitrary, but finite orders in perturbation theory. The final formula, however, makes neither explicit reference to the renormalization group flow, nor to perturbation theory, and we conjecture that it also holds non-perturbatively. Our identity can be applied constructively because it gives a novel recursive algorithm for the computation of OPE coefficients to arbitrary (finite) perturbation order in terms of the zeroth order coefficients corresponding to the underlying free field theory, which in turn are trivial to obtain. We briefly illustrate the relation of this method to more standard methods for computing the OPE in some simple examples.
Molar extinction coefficients of some fatty acids
DEFF Research Database (Denmark)
Sandhu, G.K.; Singh, K.; Lark, B.S.;
2002-01-01
) and stearic acid (C18H36O2), has been measured at the photon energies 81, 356, 511, 662, 1173 and 1332 keV. Experimental values for the molar extinction coefficient, the effective atomic number and the electron density have been derived and compared with theoretical calculations. There is good agreement...
Determination of the convective heat transfer coefficient
Spierings, D.; Bosman, F.; Peters, T.; Plasschaert, F.
1987-01-01
The value of the convective heat transfer coefficient (htc) is determined under different loading conditions by using a computer aided method. The thermal load has been applied mathematically as well as experimentally to the coronal surface of an axisymmetric tooth model. To verify the assumptions m
Infinite matrices, wavelet coefficients and frames
Directory of Open Access Journals (Sweden)
N. A. Sheikh
2004-01-01
Full Text Available We study the action of A on f∈L2(ℝ and on its wavelet coefficients, where A=(almjklmjk is a double infinite matrix. We find the frame condition for A-transform of f∈L2(ℝ whose wavelet series expansion is known.
Probability based calibration of pressure coefficients
DEFF Research Database (Denmark)
Hansen, Svend Ole; Pedersen, Marie Louise; Sørensen, John Dalsgaard
2015-01-01
not depend on the type of variable action. A probability based calibration of pressure coefficients have been carried out using pressure measurements on the standard CAARC building modelled on scale of 1:383. The extreme pressures measured on the CAARC building model in the wind tunnel have been fitted...
The Evolution of Pearson's Correlation Coefficient
Kader, Gary D.; Franklin, Christine A.
2008-01-01
This article describes an activity for developing the notion of association between two quantitative variables. By exploring a collection of scatter plots, the authors propose a nonstandard "intuitive" measure of association; and by examining properties of this measure, they develop the more standard measure, Pearson's Correlation Coefficient. The…
Quantum Correlation Coefficients for Angular Coherent States
Institute of Scientific and Technical Information of China (English)
CHEN Wei; HE Yan; GUO Hao
2009-01-01
Quantum covariance and correlation coefficients of angular or SU(2) coherent states are directly calculated for all irreducible unitary representations.These results explicitly verify that the angular coherent states minimize the Robertson-Schrodinger uncertainty relation for all spins, which means that they are the so-called intelligent states.The same results can be obtained by the Schwinger representation approach.
Computer programs for the concordance correlation coefficient.
Crawford, Sara B; Kosinski, Andrzej S; Lin, Hung-Mo; Williamson, John M; Barnhart, Huiman X
2007-10-01
The CCC macro is presented for computation of the concordance correlation coefficient (CCC), a common measure of reproducibility. The macro has been produced in both SAS and R, and a detailed presentation of the macro input and output for the SAS program is included. The macro provides estimation of three versions of the CCC, as presented by Lin [L.I.-K. Lin, A concordance correlation coefficient to evaluate reproducibility, Biometrics 45 (1989) 255-268], Barnhart et al. [H.X. Barnhart, J.L. Haber, J.L. Song, Overall concordance correlation coefficient for evaluating agreement among multiple observers, Biometrics 58 (2002) 1020-1027], and Williamson et al. [J.M. Williamson, S.B. Crawford, H.M. Lin, Resampling dependent concordance correlation coefficients, J. Biopharm. Stat. 17 (2007) 685-696]. It also provides bootstrap confidence intervals for the CCC, as well as for the difference in CCCs for both independent and dependent samples. The macro is designed for balanced data only. Detailed explanation of the involved computations and macro variable definitions are provided in the text. Two biomedical examples are included to illustrate that the macro can be easily implemented.
The Evolution of Pearson's Correlation Coefficient
Kader, Gary D.; Franklin, Christine A.
2008-01-01
This article describes an activity for developing the notion of association between two quantitative variables. By exploring a collection of scatter plots, the authors propose a nonstandard "intuitive" measure of association; and by examining properties of this measure, they develop the more standard measure, Pearson's Correlation Coefficient. The…
NEGATIVE MAXWELL-STEFAN DIFFUSION-COEFFICIENTS
KRAAIJEVELD, G; WESSELINGH, JA
1993-01-01
The existence of negative Maxwell-Stefan diffusivities is investigated. For the case where the diffusion coefficients are taken to be composition dependent, it is found that the theory of irreversible thermodynamics does not require all diffusivities to be positive definite. This theoretical result
Pressure-viscosity coefficient of biobased lubricants
Film thickness is an important tribological property that is dependent on the combined effect of lubricant properties, material property of friction surfaces, and the operating conditions of the tribological process. Pressure-viscosity coefficient (PVC) is one of the lubricant properties that influe...
Regularity of the Interband Light Absorption Coefficient
Indian Academy of Sciences (India)
M Krishna
2010-06-01
In this paper we consider the interband light absorption coefficient (ILAC), in a symmetric form, in the case of random operators on the -dimensional lattice. We show that the symmetrized version of ILAC is either continuous or has a component which has the same modulus of continuity as the density of states.
Problems on Divisibility of Binomial Coefficients
Osler, Thomas J.; Smoak, James
2004-01-01
Twelve unusual problems involving divisibility of the binomial coefficients are represented in this article. The problems are listed in "The Problems" section. All twelve problems have short solutions which are listed in "The Solutions" section. These problems could be assigned to students in any course in which the binomial theorem and Pascal's…
Integral coefficients for one-loop amplitudes
Britto, R.; Feng, B.
2008-01-01
We present a set of algebraic functions for evaluating the coefficients of the scalar integral basis of a general one-loop amplitude. The functions are derived from unitarity cuts, but the complete cut-integral procedure has been carried out in generality so that it never needs to be repeated. Where
Coupling coefficients for coupled-cavity lasers
Energy Technology Data Exchange (ETDEWEB)
Lang, R.J.; Yariv, A.
1987-03-01
The authors derive simple, analytic formulas for the field coupling coefficients in a two-section coupled-cavity laser using a local field rate equation treatment. They show that there is a correction to the heuristic formulas based on power flow calculated by Marcuse; the correction is in agreement with numerical calculations from a coupled-mode approach.
Effective stress coefficient for uniaxial strain condition
DEFF Research Database (Denmark)
Alam, M.M.; Fabricius, I.L.
2012-01-01
The effective stress coefficient, introduced by Biot, is used for predicting effective stress or pore pressure in the subsurface. It is not a constant value. It is different for different types of sediment and it is stress dependent. We used a model, based on contact between the grains to describ...
Bayesian Meta-Analysis of Coefficient Alpha
Brannick, Michael T.; Zhang, Nanhua
2013-01-01
The current paper describes and illustrates a Bayesian approach to the meta-analysis of coefficient alpha. Alpha is the most commonly used estimate of the reliability or consistency (freedom from measurement error) for educational and psychological measures. The conventional approach to meta-analysis uses inverse variance weights to combine…
Determination of the convective heat transfer coefficient
Spierings, D.; Bosman, F.; Peters, T.; Plasschaert, F.
1987-01-01
The value of the convective heat transfer coefficient (htc) is determined under different loading conditions by using a computer aided method. The thermal load has been applied mathematically as well as experimentally to the coronal surface of an axisymmetric tooth model. To verify the assumptions m
Coefficient of Restitution of a Tennis Ball
Directory of Open Access Journals (Sweden)
Andre Roux
2007-06-01
Full Text Available The coefficient of restitution (COR of a tennis ball was investigated over a range of impact velocities. It was found that the COR of the ball was lower than ATP regulations specify, and that the COR decreased with increasing impact velocity.
Bitplane Image Coding With Parallel Coefficient Processing.
Auli-Llinas, Francesc; Enfedaque, Pablo; Moure, Juan C; Sanchez, Victor
2016-01-01
Image coding systems have been traditionally tailored for multiple instruction, multiple data (MIMD) computing. In general, they partition the (transformed) image in codeblocks that can be coded in the cores of MIMD-based processors. Each core executes a sequential flow of instructions to process the coefficients in the codeblock, independently and asynchronously from the others cores. Bitplane coding is a common strategy to code such data. Most of its mechanisms require sequential processing of the coefficients. The last years have seen the upraising of processing accelerators with enhanced computational performance and power efficiency whose architecture is mainly based on the single instruction, multiple data (SIMD) principle. SIMD computing refers to the execution of the same instruction to multiple data in a lockstep synchronous way. Unfortunately, current bitplane coding strategies cannot fully profit from such processors due to inherently sequential coding task. This paper presents bitplane image coding with parallel coefficient (BPC-PaCo) processing, a coding method that can process many coefficients within a codeblock in parallel and synchronously. To this end, the scanning order, the context formation, the probability model, and the arithmetic coder of the coding engine have been re-formulated. The experimental results suggest that the penalization in coding performance of BPC-PaCo with respect to the traditional strategies is almost negligible.
An alternative coefficient for sound absorption
Wijnant, Y.H.; Kuipers, E.R.; Boer, de A.; Sas, P.; Jonckheere, S.; Moens, D.
2013-01-01
The acoustic absorption coefficient is a number that indicates which fraction of the incident acoustic power impinging on a surface is being absorbed. The incident acoustic power is obtained by spatial integration of the incident intensity, which is (classically) defined as the time-averaged intensi
Bayesian Meta-Analysis of Coefficient Alpha
Brannick, Michael T.; Zhang, Nanhua
2013-01-01
The current paper describes and illustrates a Bayesian approach to the meta-analysis of coefficient alpha. Alpha is the most commonly used estimate of the reliability or consistency (freedom from measurement error) for educational and psychological measures. The conventional approach to meta-analysis uses inverse variance weights to combine…
LIOUVILLE'S THEOREM FOR LPDO WITH CONSTANT COEFFICIENTS
Institute of Scientific and Technical Information of China (English)
Han Yazhou; Luo Xuebo
2005-01-01
In this note, the authors consider a class of linear partial differential operators P(θ) with constant coefficients and prove that the operator P(θ) has Liouville property if and only if the polynomial P(iξ) doesn't have roots in Rn\\{O}.
Wind speed scaling and the drag coefficient
Institute of Scientific and Technical Information of China (English)
无
2005-01-01
Wind speed scaling in similarity law in wind-generated waves and the drag coefficient are studied. In analyzing the data in the wind wave channel, it is found that the u. scaling greatly reduces the scatter in the U10 scaling. The u. scaling has much less scatter than the scaling using other wind speeds. The friction velocity seems to play a distinctive role in wave growth. The result is important in the applications of the similarity law and in wave modeling. In theory it gives an insight into the mechanism of wind wave interaction. It is found that wave steepness is important in influencing the drag coefficient. The variability of the coefficients in the currently widely used drag form can be explained by the differences in wave steepness in the observations. A drag coefficient model with wind speed and wave steepness as parameters is proposed. An explanation for Kahma' s result that the u. scaling does not reduce the scatter in the U10 scaling is given.
Coefficient of variation of underwater irradiance fluctuations
Weber, V. L.
2010-06-01
We consider underwater sunlight fluctuations in the case of a one-dimensional irregular sea surface. Several rigorous and approximate models are proposed, which make it possible to analytically treat and physically explain the dependence of the coefficient of variation of the underwater irradiance on the depth, the wind velocity, and optical parameters of the sea water.
Fokker-Planck Type Equations with Sobolev Diffusion Coefficients and BV Drift Coefficients
Institute of Scientific and Technical Information of China (English)
De Jun LUO
2013-01-01
Combining Le Bris and Lions' arguments with Ambrosio's commutator estimate for BV vector fields,we prove in this paper the existence and uniqueness of solutions to the Fokker-Planck type equations with Sobolev diffusion coefficients and BV drift coefficients.
Dai, Guang-Ming
2006-02-15
The set of Fourier series is discussed following some discussion of Zernike polynomials. Fourier transforms of Zernike polynomials are derived that allow for relating Fourier series expansion coefficients to Zernike polynomial expansion coefficients. With iterative Fourier reconstruction, Zernike representations of wavefront aberrations can easily be obtained from wavefront derivative measurements.
Institute of Scientific and Technical Information of China (English)
Liu Yanqiong; Chen Yingwu
2006-01-01
When analyze the uncertainty of the cost and the schedule of the spaceflight project, it is needed to know the value of the schedule-cost correlation coefficient. This paper deduces the schedule distribution, considering the effect of the cost, and proposes the estimation formula of the correlation coefficient between the ln(schedule) and the cost. On the basis of the fact and Taylor expansion, the relation expression between the schedule-cost correlation coefficient and the ln-schedule-cost correlation coefficient is put forward. By analyzing the value features of the estimation formula of the ln-schedule-cost correlation coefficient, the general rules are proposed to ascertain the value of the schedule-cost correlation coefficient. An example is given to demonstrate how to approximately amend the schedule-cost correlation coefficient based on the historical statistics, which reveals the traditional assigned value is inaccurate. The universality of this estimation method is analyzed.
Harmony Coefficient and Regional Agricultural Systems
Institute of Scientific and Technical Information of China (English)
YANG Shi-qi; GAO Wang-sheng
2006-01-01
The regional agricultural system (RAS) can be divided into three subsystems: ecological, economic, and social. This article examines the use of the harmony coefficient (HC), efficacy coefficient, rank of the harmony coefficient (RHC), and its appraising index system within the RAS. The harmony coefficient function was developed using a variance coefficient and then applied to Ziyang District, Yiyang City in Hunan Province (ZYH), China, as a test case. From 1995 to 2002, the HC of RAS increased from 0.2982 to 0.4826 and the RHC increased from 3 to 5, although the HC trend was an "n" type in general. This suggests that the HC was weakly maladjusted and the RAS was not harmonious. The HC of the ecological subsystem decreased from 0.3898 to 0.2850, and its RHC from 4 to 3, with the HC trend following the "n" type. For the economic subsystem, the HC value increased from 0.5767 to 0.7458 and the RHC from 6 to 8. However, the trend in HC for the economic subsystem was of the "U" type. The HC of the social subsystem increased slightly from 0.4948 to 0.4663,and the RHC did not change in value. From the HC trends, the HC curve of the economic subsystem is above the HC curve of ZYH and the HC curve of the ecological subsystem is below the HC curve of ZHY. Hence, the ZHY environment has been destroyed by economic development. Environment and social building should be regarded as important issues in the future and promoting RAS harmony development should be considered. The results of the theoretical analysis match fairly closely with reality, and suggest that the harmony theory is feasible in appraising RAS development phases.
Institute of Scientific and Technical Information of China (English)
赵玉娟; 吴胜群; 李学文; 李贺; 何冰
2012-01-01
目的 观察围绝经期高血压患者红细胞体积分布宽度(RDW )变异系数(CV )的变化,为围绝经期高血压的预防与治疗提供新的思路.方法 采用病例对照研究的方法,回顾性分析55 例围绝经期高血压患者(围绝经期高血压组)的临床资料,以同期56 例健康者为健康对照组,再按高血压分级的不同将围绝经期高血压组分为高血压1 级组(36 例)和高血压2 级组(19 例).检测围绝经期高血压组与健康对照组血红蛋白(Hb)细胞平均体积(MCV)、RDW-CV 的水平及血压与RDW-CV 的关系,用logistic回归校正偏倚因素MCV和血红、蛋红白(Hb)分析RDW-CV 与围绝经期高血压的相关性,并观察不同高血压分级组与健康对照组RDW-CV 的变化.结果 围绝,经期高血压组患者Hb(g/L)、MCV(fl )均较健康对照组明显降低(Hb:143.14±12.18 比157.36±13.31,MCV:86.13±5.13 比91.31±6.51,均P＜0.05)RDW-CV 明显升高[(14.13±1.08)% 比(12.35±0.83)%,P＜0.05 ],校正MCV 和Hb 等偏倚因素后,RDW-CV 与,围绝经期高血压有相关性[Hb:优势比(OR)=0.618,MCV:OR = 0.753,RDW-CV:OR = 0.761,均P＜0.05 ]高血压不同分级组患者的RDW-CV 均较健康对照组明显升高,以高血压2 级组升高更显著[(14.26±0.89)%比,(12.35±0.82)%,P＜0.05 ].结论 RDW-CV 与围绝经期高血压存在独立的相关性,提示RDW-CV 可能成为围绝经期高血压患者的一个临床监测指标,为该患者群提供心脑血管危象的预警信息.%Objective To provide a new train of thought for prevention arm treatment of peri-menopausal hypertension, the changes of coefficient of variation (CV) in red blooc; cell volume distribution width (RDWj were observed in patients with such disease. Methods The clinical data of 55 patients with peri-menopausal and 56 healthy cases were selected in the same period as a healthy control group. The peri-menopausal hypertension group was subdivided into hypertension grade 1 and 2 groups according to
Wheeler, David C.; Calder, Catherine A.
2007-06-01
The realization in the statistical and geographical sciences that a relationship between an explanatory variable and a response variable in a linear regression model is not always constant across a study area has led to the development of regression models that allow for spatially varying coefficients. Two competing models of this type are geographically weighted regression (GWR) and Bayesian regression models with spatially varying coefficient processes (SVCP). In the application of these spatially varying coefficient models, marginal inference on the regression coefficient spatial processes is typically of primary interest. In light of this fact, there is a need to assess the validity of such marginal inferences, since these inferences may be misleading in the presence of explanatory variable collinearity. In this paper, we present the results of a simulation study designed to evaluate the sensitivity of the spatially varying coefficients in the competing models to various levels of collinearity. The simulation study results show that the Bayesian regression model produces more accurate inferences on the regression coefficients than does GWR. In addition, the Bayesian regression model is overall fairly robust in terms of marginal coefficient inference to moderate levels of collinearity, and degrades less substantially than GWR with strong collinearity.
Guttmann, Anthony J.
2016-10-01
Given the first 20-100 coefficients of a typical generating function of the type that arises in many problems of statistical mechanics or enumerative combinatorics, we show that the method of differential approximants performs surprisingly well in predicting (approximately) subsequent coefficients. These can then be used by the ratio method to obtain improved estimates of critical parameters. In favourable cases, given only the first 20 coefficients, the next 100 coefficients are predicted with useful accuracy. More surprisingly, this is also the case when the method of differential approximants does not do a useful job in estimating the critical parameters, such as those cases in which one has stretched exponential asymptotic behaviour. Nevertheless, the coefficients are predicted with surprising accuracy. As one consequence, significant computer time can be saved in enumeration problems where several runs would normally be made, modulo different primes, and the coefficients constructed from their values modulo different primes. Another is in the checking of newly calculated coefficients. We believe that this concept of approximate series extension opens up a whole new chapter in the method of series analysis.
Directory of Open Access Journals (Sweden)
Zhenrong JING
2017-06-01
Full Text Available Swept wing is widely used in civil aircraft, whose airfoil is chosen, designed and optimized to increase the cruise speed and decrease the drag coefficient. The parameters of swept wing, such as sweep angle and angle of attack, are determined according to the cruise lift coefficient requirement, and the drag coefficient is expected to be predicted accurately, which involves the instability characteristics and transition position of the flow. The pressure coefficient of the RAE2822 wing with given constant lift coefficient is obtained by solving the three-dimensional Navier-Stokes equation numerically, and then the mean flow is calculated by solving the boundary layer (BL equation with spectral method. The cross-flow instability characteristic of boundary layer of swept wing in the windward and leeward is analyzed by linear stability theory (LST, and the transition position is predicted by eN method. The drag coefficient is numerically predicted by introducing a laminar/turbulent indicator. A simple approach to calculate the lift coefficient of swept wing is proposed. It is found that there is a quantitative relationship between the angle of attack and sweep angle when the lift coefficient keeps constant; when the angle of attack is small, the flow on the leeward of the wing is stable. when the angle of attack is larger than 3°, the flow becomes unstable quickly; with the increase of sweep angle or angle of attack the disturbance on the windward becomes more unstable, leading to the moving forward of the transition position to the leading edge of the wing; the drag coefficient has two significant jumping growth due to the successive occurrence of transition in the windward and the leeward; the optimal range of sweep angle for civil aircraft is suggested.
Quinino, Roberto C.; Reis, Edna A.; Bessegato, Lupercio F.
2013-01-01
This article proposes the use of the coefficient of determination as a statistic for hypothesis testing in multiple linear regression based on distributions acquired by beta sampling. (Contains 3 figures.)
Quinino, Roberto C.; Reis, Edna A.; Bessegato, Lupercio F.
2013-01-01
This article proposes the use of the coefficient of determination as a statistic for hypothesis testing in multiple linear regression based on distributions acquired by beta sampling. (Contains 3 figures.)
Transport Coefficients and nPI Methods
Carrington, M E
2011-01-01
Transport coefficients can be obtained from 2-point correlators using the Kubo formulae. It has been shown that the full leading order result for electrical conductivity and (QCD) shear viscosity is contained in the re-summed 2-point function that is obtained from the 3-loop 3PI effective action. The theory produces all leading order contributions without the necessity for power counting, and in this sense it provides a natural framework for the calculation and suggests that one can calculate the next-to-leading contribution to transport coefficients from the 4-loop 4PI effective action. The integral equations have been derived for shear viscosity for a scalar theory with cubic and quartic interactions, with a non-vanishing field expectation value. We review these results, and explain how the calculation could be done at higher orders.
Window shrink contourlet coefficients for image denoising
Institute of Scientific and Technical Information of China (English)
JIN Wei; PAN Ying-jun; WEI Biao; FENG Peng
2005-01-01
An adaptive image denosing technique was proposed to achieve the tradeoff between details retain and noises removal. In order to achieve this objective, the contourlet transform was introduced and a new threshold method, namely CWinShrink, is presented. It shrinks the contourlet coefficients with adaptive shrinkage factors. The shrinkage factors were calculated with reference to the sum of squares of the contourlet coefficients within the neighborhood window. This approach achieves enhanced results for images those are corrupted with additive Gaussian noise. In numerical comparisons with various methods, for a set of noisy images ( the PSNR range from 10.86dB to 26.91dB) , the presented method outperforms VisuShrink and Wiener filter in terms of the PSNR. Experiments also show that this method not only keeps the details of image but also yields denoised images with better visual quality.
Homomorphic Hashing for Sparse Coefficient Extraction
Kaski, Petteri; Nederlof, Jesper
2012-01-01
We study classes of Dynamic Programming (DP) algorithms which, due to their algebraic definitions, are closely related to coefficient extraction methods. DP algorithms can easily be modified to exploit sparseness in the DP table through memorization. Coefficient extraction techniques on the other hand are both space-efficient and parallelisable, but no tools have been available to exploit sparseness. We investigate the systematic use of homomorphic hash functions to combine the best of these methods and obtain improved space-efficient algorithms for problems including LINEAR SAT, SET PARTITION, and SUBSET SUM. Our algorithms run in time proportional to the number of nonzero entries of the last segment of the DP table, which presents a strict improvement over sparse DP. The last property also gives an improved algorithm for CNF SAT with sparse projections.
Varying-coefficient functional linear regression
Wu, Yichao; Müller, Hans-Georg; 10.3150/09-BEJ231
2011-01-01
Functional linear regression analysis aims to model regression relations which include a functional predictor. The analog of the regression parameter vector or matrix in conventional multivariate or multiple-response linear regression models is a regression parameter function in one or two arguments. If, in addition, one has scalar predictors, as is often the case in applications to longitudinal studies, the question arises how to incorporate these into a functional regression model. We study a varying-coefficient approach where the scalar covariates are modeled as additional arguments of the regression parameter function. This extension of the functional linear regression model is analogous to the extension of conventional linear regression models to varying-coefficient models and shares its advantages, such as increased flexibility; however, the details of this extension are more challenging in the functional case. Our methodology combines smoothing methods with regularization by truncation at a finite numb...
Meromorphic univalent function with negative coefficient
Directory of Open Access Journals (Sweden)
A. Dernek
1994-01-01
Full Text Available Let Mn be the classes of regular functions f(z=z−1+a0+a1z+… defined in the annulus 00, (n∈ℕ0, where I0f(z=f(z, If(z=(z−1−z(z−1−2∗f(z, Inf(z=I(In−1f(z, and ∗ is the Hadamard convolution. We denote by Γn=Mn⋃Γ, where Γ denotes the class of functions of the form f(z=z−1+∑k=1∞|ak|zk. We obtained that relates the modulus of the coefficients to starlikeness for the classes Mn and Γn, and coefficient inequalities for the classes Γn.
Transport coefficients in Chiral Perturbation Theory
Energy Technology Data Exchange (ETDEWEB)
Fernandez-Fraile, D.; Gomez Nicola, A. [Universidad Complutense, Departamentos de Fisica Teorica I y II, Madrid (Spain)
2007-03-15
We present recent results on the calculation of transport coefficients for a pion gas at zero chemical potential in Chiral Perturbation Theory (ChPT) using the Linear Response Theory (LRT). More precisely, we show the behavior of DC conductivity and shear viscosity at low temperatures. To compute transport coefficients, the standard power counting of ChPT has to be modified. The effects derived from imposing unitarity are also analyzed. As physical applications in relativistic heavy-ion collisions, we show the relation of the DC conductivity to soft-photon production and phenomenological effects related to a non-zero shear viscosity. In addition, our values for the shear viscosity to entropy ratio satisfy the KSS bound. (orig.)
Hadronic Transport Coefficients from Effective Field Theories
Torres-Rincon, Juan M
2012-01-01
This dissertation focuses on the calculation of transport coefficients in the matter created in a relativistic heavy-ion collision after the chemical freeze-out. This matter can be well approximated by a pion gas out of equilibrium. We describe the theoretical framework to obtain the shear and bulk viscosities, the thermal and electrical conductivities and the flavor diffusion coefficients of a meson gas at low temperatures. To describe the interactions of the degrees of freedom, we use effective field theories with chiral and heavy quark symmetries. We introduce the unitarization methods in order to obtain a scattering amplitude that satisfies the unitarity condition exactly. We perform the calculation of the transport properties of the low temperature phase of quantum chromodynamics -the hadronic medium- that can be used in the hydrodynamic simulations of a relativistic heavy-ion collision and its subsequent evolution. We show that the shear viscosity over entropy density exhibits a minimum in a phase trans...
ON DAMPING COEFFICIENT DUE TO PHASE TRANSFORMATION
Institute of Scientific and Technical Information of China (English)
Din-YuHSIEH
2003-01-01
The damping coefficient of capillary waves due to the evaporation-condensation process at the interface of the two phases of a fluid is evaluated. To highlight the mechanism of the effect of heat and mass transfer across the interface between regions of liquid and vapor, potential flow of incompressible fluids are assumed. Thus other mechanisms of damping are neglected. To fascilitate the analysis, the method of multiple-scale is employed in the analysis, even though the problem is linear.
Basketball Surfaces and Coefficient of Restitution
Kristyn Peacock; Faith Pearson
2015-01-01
A basketball was released from varying drop heights to simulate the impact speeds of a typical soft, medium, and hard dribble. This was repeated across four different surfaces that students typically play on–exposed aggregate concrete, maple wood flooring, EPI Outdoor Sport flooring, and playground rubber mesh. From the measured drop and bounce heights, the coefficient of restitution(COR)was calculated. It was concluded that only playground rubber mesh had COR’s below the regula...
Numerical Integral of Resistance Coefficients in Diffusion
Zhang, Q. S.
2017-01-01
The resistance coefficients in the screened Coulomb potential of stellar plasma are evaluated to high accuracy. I have analyzed the possible singularities in the integral of scattering angle. There are possible singularities in the case of an attractive potential. This may result in a problem for the numerical integral. In order to avoid the problem, I have used a proper scheme, e.g., splitting into many subintervals where the width of each subinterval is determined by the variation of the integrand, to calculate the scattering angle. The collision integrals are calculated by using Romberg’s method, therefore the accuracy is high (i.e., ∼10‑12). The results of collision integrals and their derivatives for ‑7 ≤ ψ ≤ 5 are listed. By using Hermite polynomial interpolation from those data, the collision integrals can be obtained with an accuracy of 10‑10. For very weakly coupled plasma (ψ ≥ 4.5), analytical fittings for collision integrals are available with an accuracy of 10‑11. I have compared the final results of resistance coefficients with other works and found that, for a repulsive potential, the results are basically the same as others’ for an attractive potential, the results in cases of intermediate and strong coupling show significant differences. The resulting resistance coefficients are tested in the solar model. Comparing with the widely used models of Cox et al. and Thoul et al., the resistance coefficients in the screened Coulomb potential lead to a slightly weaker effect in the solar model, which is contrary to the expectation of attempts to solve the solar abundance problem.
Heterodiffusion coefficients in alpha-iron
Energy Technology Data Exchange (ETDEWEB)
Katsika-Tsigourakou, Vassiliki, E-mail: vkatsik@phys.uoa.g [Department of Solid State Physics, Faculty of Physics, University of Athens, Panepistimiopolis Zografos, 15784 Athens (Greece); Skordas, Efthimios S. [Department of Solid State Physics, Faculty of Physics, University of Athens, Panepistimiopolis Zografos, 15784 Athens (Greece)
2010-04-01
The diffusion of tungsten in alpha-iron is important for the application of ferritic-iron alloys to thermal power plants. These data, over a wide temperature range across the Curie temperature, have been recently reported. We show that these diffusion coefficients can be satisfactory reproduced in terms of the bulk elastic and expansivity data by means of a thermodynamical model that interconnects point defects parameters with bulk qualities.
Correlation and prediction of gaseous diffusion coefficients.
Marrero, T. R.; Mason, E. A.
1973-01-01
A new correlation method for binary gaseous diffusion coefficients from very low temperatures to 10,000 K is proposed based on an extended principle of corresponding states, and having greater range and accuracy than previous correlations. There are two correlation parameters that are related to other physical quantities and that are predictable in the absence of diffusion measurements. Quantum effects and composition dependence are included, but high-pressure effects are not. The results are directly applicable to multicomponent mixtures.
Negative Temperature Coefficient in Chemical Reactions
Leenson, I. A.; Sergeev, Gleb B.
1984-05-01
A systematic analysis of reactions whose rate decreases with increase of temperature is presented. The possibility of a negative temperature coefficient in the elementary reactions is examined from the standpoint of the transition state theory and of collision theory. The mechanisms of complex reactions in which the temperature dependence of the rate is anomalous are discussed, and possible reasons for the anomaly are examined. The bibliography contains 175 references.
Coefficient inequalities for starlikeness and convexity
Directory of Open Access Journals (Sweden)
Ali Rosihan M.
2013-06-01
Full Text Available For an analytic function $f(z=z+\\sum_{n=2}^\\infty a_n z^n$ satisfying the inequality $\\sum_{n=2}^\\infty n(n-1|a_n|\\leq \\beta$, sharp bound on $\\beta$ is determined so that $f$ is either starlike or convex of order $\\alpha$. Several other coefficient inequalities related to certain subclasses are also investigated.
Coefficients of symmetric square L-functions
Institute of Scientific and Technical Information of China (English)
LAU; Yuk-Kam
2010-01-01
Let λsym2f(n) be the n-th coefficient in the Dirichlet series of the symmetric square L-function associated with a holomorphic primitive cusp form f.We prove Ω± results for λsym2f(n) and evaluate the number of positive(resp.,negative) λsym2f(n) in some intervals.
Detailed Investigations of Load Coefficients on Grates
DEFF Research Database (Denmark)
Andersen, Thomas Lykke; Rasmussen, Michael R.; Frigaard, Peter
In this report is presented the results of model tests carried out at Dept. of Civil Engineering, aalborg University (AAU) on behalf of DONG Energy A/S and Vattenfall A/S, Denmark. The objective of the tests was to investigate the load coefficient on different grates and a solid plate for designi...... offshore windmill access platforms against run-up generated forces with special attention to the influence of air entrainment and the angle of attack....
Control in the coefficients with variational crimes
DEFF Research Database (Denmark)
Evgrafov, Anton; Marhadi, Kun Saptohartyadi
2012-01-01
We study convergence of discontinuous Galerkin-type discretizations of the problems of control in the coefficients of uniformly elliptic partial differential equations (PDEs). As a model problem we use that of the optimal design of thin (Kirchhoff) plates, where the governing equations are of the......We study convergence of discontinuous Galerkin-type discretizations of the problems of control in the coefficients of uniformly elliptic partial differential equations (PDEs). As a model problem we use that of the optimal design of thin (Kirchhoff) plates, where the governing equations...... are of the fourth order. Methods which do not require approximation subspaces to conform to the smoothness requirements dictated by the PDE are very attractive for such problems. However, variational formulations of such methods normally contain boundary integrals whose dependence on the small, with respect...... to “volumetric” Lebesgue norm, changes of the coefficients is generally speaking not continuous. We utilize the lifting formulation of the discontinuous Galerkin method to deal with this issue.Our main result is that limit points of sequences of designs verifying discrete versions of stationarity can also...
Michelson interferometer for the piezoelectric coefficient measurements
Directory of Open Access Journals (Sweden)
Muensit, S.
2002-01-01
Full Text Available The present work has described the Michelson interferometer which is capable of measuring the vibrational amplitudes in a sub-angstrom range. In the system, a He-Ne laser is used as a monochromatic source of light and a photodiode as a detector to convert an optical signal into an electronic one. Lock-in detections of the electronic signals are applied to relate the vibrational amplitudes to the wavelength of the laser beam. A feedback circuit is introduced in order to stabilize the sensitivity of the interferometric system. With this setup, a mechanical displacement referred to a change in thickness of a vibrating sample can be measured and the corresponding piezoelectric coefficient, i.e. the ratio of the change in sample thickness to the applied voltage, evaluated. In order to check the performance of the system, measurements on lithium niobate (LiNbO3 have been made and its piezoelectric coefficient d33 was confirmed with 2% accuracy. The piezoelectric coefficient d33 for lead zirconate titanate (PZT ceramics was, therefore, determined by this interferometer and found to be 270 pm/V.
Genus Distributions of Moebius Ladders
Institute of Scientific and Technical Information of China (English)
李德明
2005-01-01
The genus distribution of a graph is a polynomial whose coefficients are the partition of the number of embeddings with respect to the genera. In this paper,the genus distribution of Moebius ladders is provided which is an infinite class of 3-connected simple graphs.
Feng, Dai; Svetnik, Vladimir; Coimbra, Alexandre; Baumgartner, Richard
2014-01-01
The intraclass correlation coefficient (ICC) with fixed raters or, equivalently, the concordance correlation coefficient (CCC) for continuous outcomes is a widely accepted aggregate index of agreement in settings with small number of raters. Quantifying the precision of the CCC by constructing its confidence interval (CI) is important in early drug development applications, in particular in qualification of biomarker platforms. In recent years, there have been several new methods proposed for construction of CIs for the CCC, but their comprehensive comparison has not been attempted. The methods consisted of the delta method and jackknifing with and without Fisher's Z-transformation, respectively, and Bayesian methods with vague priors. In this study, we carried out a simulation study, with data simulated from multivariate normal as well as heavier tailed distribution (t-distribution with 5 degrees of freedom), to compare the state-of-the-art methods for assigning CI to the CCC. When the data are normally distributed, the jackknifing with Fisher's Z-transformation (JZ) tended to provide superior coverage and the difference between it and the closest competitor, the Bayesian method with the Jeffreys prior was in general minimal. For the nonnormal data, the jackknife methods, especially the JZ method, provided the coverage probabilities closest to the nominal in contrast to the others which yielded overly liberal coverage. Approaches based upon the delta method and Bayesian method with conjugate prior generally provided slightly narrower intervals and larger lower bounds than others, though this was offset by their poor coverage. Finally, we illustrated the utility of the CIs for the CCC in an example of a wake after sleep onset (WASO) biomarker, which is frequently used in clinical sleep studies of drugs for treatment of insomnia.
Tripathi, A. K.; Singhal, R. P.; Khazanov, G. V.; Avanov, L. A.
2016-04-01
Electron pitch angle (Dαα) and momentum (Dpp) diffusion coefficients have been calculated due to resonant interactions with electrostatic electron cyclotron harmonic (ECH) and whistler mode chorus waves. Calculations have been performed at two spatial locations L = 4.6 and 6.8 for electron energies ≤10 keV. Landau (n = 0) resonance and cyclotron harmonic resonances n = ±1, ±2, … ±5 have been included in the calculations. It is found that diffusion coefficient versus pitch angle (α) profiles show large dips and oscillations or banded structures. The structures are more pronounced for ECH and lower band chorus (LBC) and particularly at location 4.6. Calculations of diffusion coefficients have also been performed for individual resonances. It is noticed that the main contribution of ECH waves in pitch angle diffusion coefficient is due to resonances n = +1 and n = +2. A major contribution to momentum diffusion coefficients appears from n = +2. However, the banded structures in Dαα and Dpp coefficients appear only in the profile of diffusion coefficients for n = +2. The contribution of other resonances to diffusion coefficients is found to be, in general, quite small or even negligible. For LBC and upper band chorus waves, the banded structures appear only in Landau resonance. The Dpp diffusion coefficient for ECH waves is one to two orders smaller than Dαα coefficients. For chorus waves, Dpp coefficients are about an order of magnitude smaller than Dαα coefficients for the case n ≠ 0. In case of Landau resonance, the values of Dpp coefficient are generally larger than the values of Dαα coefficients particularly at lower energies. As an aid to the interpretation of results, we have also determined the resonant frequencies. For ECH waves, resonant frequencies have been estimated for wave normal angle 89° and harmonic resonances n = +1, +2, and +3, whereas for whistler mode waves, the frequencies have been calculated for angle 10° and Landau
Research on the Limit Value of Shape Coefficient of Rural Residences in Severe Cold Regions
Institute of Scientific and Technical Information of China (English)
Hong Jin; Kai Chen; Teng Shao
2014-01-01
Shape coefficient is a significant factor accounting for building energy consumption. In order to decrease the building energy consumption of rural residence in severe cold regions, this paper from the perspective of regulating the shape coefficient limit value, applies the field survey method to statistic and analyze the shape, width and depth of rural residence in severe cold regions and concludes the distribution characteristics and scope of building area. On this basis, though calculating and analyzing the relations between shape coefficient and length-width ratio under different building areas, meanwhile comprehensive considering the building function, farmers’ living mode and requirements etc, it put forward that the shape coefficient of rural residence in severe cold regions should below 0�8. It has important significance for guiding the rural energy-saving house design and construction of severe cold regions.
Energy Technology Data Exchange (ETDEWEB)
Ader, C. [Fermilab; Voirin, E. [Fermilab; McGee, M. [Fermilab; Nobrega, L. [Fermilab
2017-06-15
An error was found in an edge stress coefficient used to calculate stresses in thin windows. This error is present in “Roark’s Formulas for Stress and Strain” 7th and 8th Edition. The 6th Edition is correct. This guideline specially discusses a major difference in regards to a coefficient used in calculating the edge stress in “Roark’s Formulas for Stress and Strain” 6th Edition compared to the 7th and 8th Editions. In Chapter 10: Flat Plates under “Circular plates under distributed load producing large deflections,” Case 3, which is “Fixed and held. Uniform pressure q over entire plate.” The coefficient for a fixed edge condition in the 6th Edition1 K4 = 0.476 while in the 7th and 8th Edition2, the coefficient is 1.73 which is significant difference.
VARYING COEFFICIENT MODELS FOR DATA WITH AUTO-CORRELATED ERROR PROCESS.
Chen, Zhao; Li, Runze; Li, Yan
2015-04-01
Varying coefficient model has been popular in the literature. In this paper, we propose a profile least squares estimation procedure to its regression coefficients when its random error is an auto-regressive (AR) process. We further study the asymptotic properties of the proposed procedure, and establish the asymptotic normality for the resulting estimate. We show that the resulting estimate for the regression coefficients has the same asymptotic bias and variance as the local linear estimate for varying coefficient models with independent and identically distributed observations. We apply the SCAD variable selection procedure (Fan and Li, 2001) to reduce model complexity of the AR error process. Numerical comparison and finite sample performance of the resulting estimate are examined by Monte Carlo studies. Our simulation results demonstrate the proposed procedure is much more efficient than the one ignoring the error correlation. The proposed methodology is illustrated by a real data example.
COMPUTATION OF MOMENTUM TRANSFER COEFFICIENT AND CONVEYANCE CAPACITY IN COMPOUND CHANNELS
Institute of Scientific and Technical Information of China (English)
WANG Hua; YANG Ke-jun; CAO Shu-you; LIU Xing-nian
2007-01-01
The momentum transfer coefficient is an important parameter for determining the apparent shear stress at the vertical interface between the main channel and its associated flood plains, the cross-sectional mean velocity and the discharge capacity in compound channels. In this article, under the Boussinesq assumption and through analyzing the characteristics of velocity distribution in the interacting region between the main channel and its associated flood plain, the expression of momentum transfer coefficient was theoretically derived. On the basis of force balance, the expression of vertical apparent shear stress was obtained. By applying the experimental data from the British Engineering Research Council Flood Channel Facility (SERC-FCF), the relationship between the momentum transfer coefficient with the relative depth and the ratio of the flood plain width to the main channel width, was established, And hence the conveyance capacity in compound channels was calculated with Liu and Dong's method. The computed results show that the momentum transfer coefficient relationship obtained is viable.
Computation of rotordynamic coefficients associated with leakage steam flow through labyrinth seal
Energy Technology Data Exchange (ETDEWEB)
Wang, W.Z.; Liu, Y.Z.; Chen, H.P. [Shanghai Jiaotong University, Thermal Fluid Flow and Turbomachinery Lab., School of Mechanical Engineering, Shanghai (China); Jiang, P.N. [Shanghai Turbine Company, Department of R and D, Shanghai (China)
2007-08-15
A mathematical model of calculating rotordynamic coefficients associated with leakage steam flow through labyrinth seals was presented. Particular attention was given to incorporating thermal properties of the steam fluid into prediction of leakage flow and subsequent derivation of rotordynamic coefficients, which quantitatively characterize influence of aerodynamic forcing of the leakage steam flow on the rotordynamics. By using perturbation analysis, we determined periodic and analytic solutions of the continuity and circumferential momentum equations for the time-dependent flow induced by non-axisymmetric rotation of the rotor encompassed by a labyrinth seal. Pressure distributions along labyrinth seal cavities and rotordynamic coefficients were compared at the same condition for air and steam flows. Influence of steam flow through the labyrinth seal cavities on rotordynamic coefficients was analyzed in terms of inlet pressure, inlet swirl velocity and rotor speed. (orig.)
Matrix-based concordance correlation coefficient for repeated measures.
Hiriote, Sasiprapa; Chinchilli, Vernon M
2011-09-01
In many clinical studies, Lin's concordance correlation coefficient (CCC) is a common tool to assess the agreement of a continuous response measured by two raters or methods. However, the need for measures of agreement may arise for more complex situations, such as when the responses are measured on more than one occasion by each rater or method. In this work, we propose a new CCC in the presence of repeated measurements, called the matrix-based concordance correlation coefficient (MCCC) based on a matrix norm that possesses the properties needed to characterize the level of agreement between two p× 1 vectors of random variables. It can be shown that the MCCC reduces to Lin's CCC when p= 1. For inference, we propose an estimator for the MCCC based on U-statistics. Furthermore, we derive the asymptotic distribution of the estimator of the MCCC, which is proven to be normal. The simulation studies confirm that overall in terms of accuracy, precision, and coverage probability, the estimator of the MCCC works very well in general cases especially when n is greater than 40. Finally, we use real data from an Asthma Clinical Research Network (ACRN) study and the Penn State Young Women's Health Study for demonstration.
Debye–Waller coefficient of heavily deformed nanocrystalline iron
Energy Technology Data Exchange (ETDEWEB)
Scardi, P.; Rebuffi, L.; Abdellatief, M.; Flor, A.; Leonardi, A.
2017-02-17
Synchrotron radiation X-ray diffraction (XRD) patterns from an extensively ball-milled iron alloy powder were collected at 100, 200 and 300 K. The results were analysed together with those using extended X-ray absorption fine structure, measured on the same sample at liquid nitrogen temperature (77 K) and at room temperature (300 K), to assess the contribution of static disorder to the Debye–Waller coefficient (
Compilation report of VHTRC temperature coefficient benchmark calculations
Energy Technology Data Exchange (ETDEWEB)
Yasuda, Hideshi; Yamane, Tsuyoshi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment
1995-11-01
A calculational benchmark problem has been proposed by JAERI to an IAEA Coordinated Research Program, `Verification of Safety Related Neutronic Calculation for Low-enriched Gas-cooled Reactors` to investigate the accuracy of calculation results obtained by using codes of the participating countries. This benchmark is made on the basis of assembly heating experiments at a pin-in block type critical assembly, VHTRC. Requested calculation items are the cell parameters, effective multiplication factor, temperature coefficient of reactivity, reaction rates, fission rate distribution, etc. Seven institutions from five countries have joined the benchmark works. Calculation results are summarized in this report with some remarks by the authors. Each institute analyzed the problem by applying the calculation code system which was prepared for the HTGR development of individual country. The values of the most important parameter, k{sub eff}, by all institutes showed good agreement with each other and with the experimental ones within 1%. The temperature coefficient agreed within 13%. The values of several cell parameters calculated by several institutes did not agree with the other`s ones. It will be necessary to check the calculation conditions again for getting better agreement. (J.P.N.).
Coefficient of variation spectral analysis: An application to underwater acoustics
Herstein, P. D.; Laplante, R. F.
1983-05-01
Acoustic noise in the ocean is often described in terms of its power spectral density. Just as in other media, this noise consists of both narrowband and broadband frequency components. A major problem in the analysis of power spectral density measurements is distinguishing between narrowband spectral components of interest and contaminating narrowband components. In this paper, the use of coefficient of variation (Cv) spectrum is examined as an adjunct to the conventional power spectrum to distinguish narrowband components of interest from contaminating components. The theory of the Cv is presented. Coefficients for several classical input distributions are developed. It is shown that Cv spectra can be easily implemented as an adjunct procedure during the computation of the ensemble of averaged power spectra. Power and Cv spectra derived from actual at-sea sonobuoy measurements of deep ocean ambient noise separate narrowband components from narrowband lines of interest in the ensemble of averaged power spectra, these acoustic components of interest can be distinguished in the Cv spectra.
Conditional Reliability Coefficients for Test Scores.
Nicewander, W Alan
2017-04-06
The most widely used, general index of measurement precision for psychological and educational test scores is the reliability coefficient-a ratio of true variance for a test score to the true-plus-error variance of the score. In item response theory (IRT) models for test scores, the information function is the central, conditional index of measurement precision. In this inquiry, conditional reliability coefficients for a variety of score types are derived as simple transformations of information functions. It is shown, for example, that the conditional reliability coefficient for an ordinary, number-correct score, X, is equal to, ρ(X,X'|θ)=I(X,θ)/[I(X,θ)+1] Where: θ is a latent variable measured by an observed test score, X; p(X, X'|θ) is the conditional reliability of X at a fixed value of θ; and I(X, θ) is the score information function. This is a surprisingly simple relationship between the 2, basic indices of measurement precision from IRT and classical test theory (CTT). This relationship holds for item scores as well as test scores based on sums of item scores-and it holds for dichotomous as well as polytomous items, or a mix of both item types. Also, conditional reliabilities are derived for computerized adaptive test scores, and for θ-estimates used as alternatives to number correct scores. These conditional reliabilities are all related to information in a manner similar-or-identical to the 1 given above for the number-correct (NC) score. (PsycINFO Database Record (c) 2017 APA, all rights reserved).
Peltier coefficient measurement in a thermoelectric module
Garrido, Javier; Casanovas, Alejandro; María Chimeno, José
2013-09-01
A new method for measuring the Peltier coefficient in a thermocouple X/Y based on the energy balance at the junction has been proposed recently. This technique needs only the hot and cold temperatures of a thermoelectric module when an electric current flows through it as the operational variables. The temperature evolutions of the two module sides provide an evident and accurate idea of the Peltier effect. From these temperatures, the heat transfer between the module and the ambient is also evaluated. The thermoelectric phenomena are described in the framework of an observable theory. Based on this procedure, an experiment is presented for a university teaching laboratory at the undergraduate level.
Onsager coefficients for systems with periodic potentials
Rosas, Alexandre; Van den Broeck, Christian; Lindenberg, Katja
2016-11-01
We carry out the thermodynamic analysis of a Markovian stochastic engine, driven by a spatially and temporally periodic modulation in a d -dimensional space. We derive the analytic expressions for the Onsager coefficients characterizing the linear response regime for the isothermal transfer of one type of work (a driver) to another (a load), mediated by a stochastic time-periodic machine. As an illustration, we obtain the explicit results for a Markovian kangaroo process coupling two orthogonal directions and find extremely good agreement with numerical simulations. In addition, we obtain and discuss expressions for the entropy production, power, and efficiency for the kangaroo process.
Tracking Time-Varying Coefficient-Functions
DEFF Research Database (Denmark)
Nielsen, Henrik Aalborg; Nielsen, Torben Skov; Joensen, Alfred K.;
1999-01-01
of recursive least squares with exponential forgetting and local polynomial regression. However, it is argued, that it is appropriate to let the forgetting factor vary with the value of the external signal shich is argument of the coeffieient-functions.The properties of the modified method are sutdied......A conditional parametric ARX-model is an ARX-model in which the parameters re replaced by smooth functions of an, possibly multivariate, externalinput signal. These functions are called coefficient functions is suggested. Essentially, in its most simple form, this method is a combination...
Gauge Invariance of Thermal Transport Coefficients
Ercole, Loris; Marcolongo, Aris; Umari, Paolo; Baroni, Stefano
2016-10-01
Thermal transport coefficients are independent of the specific microscopic expression for the energy density and current from which they can be derived through the Green-Kubo formula. We discuss this independence in terms of a kind of gauge invariance resulting from energy conservation and extensivity, and demonstrate it numerically for a Lennard-Jones fluid, where different forms of the microscopic energy density lead to different time correlation functions for the heat flux, all of them, however, resulting in the same value for the thermal conductivity.
Random Matrices and Lyapunov Coefficients Regularity
Gallavotti, Giovanni
2017-02-01
Analyticity and other properties of the largest or smallest Lyapunov exponent of a product of real matrices with a "cone property" are studied as functions of the matrices entries, as long as they vary without destroying the cone property. The result is applied to stability directions, Lyapunov coefficients and Lyapunov exponents of a class of products of random matrices and to dynamical systems. The results are not new and the method is the main point of this work: it is is based on the classical theory of the Mayer series in Statistical Mechanics of rarefied gases.
Transmission eigenvalues for operators with constant coefficients
Hitrik, Michael; Ola, Petri; Päivärinta, Lassi
2010-01-01
In this paper we study the interior transmission problem and transmission eigenvalues for multiplicative perturbations of linear partial differential operator of order $\\ge 2$ with constant real coefficients. Under suitable growth conditions on the symbol of the operator and the perturbation, we show the discreteness of the set of transmission eigenvalues and derive sufficient conditions on the existence of transmission eigenvalues. We apply these techniques to the case of the biharmonic operator and the Dirac system. In the hypoelliptic case we present a connection to scattering theory.
Flash ADC data processing with correlation coefficients
Energy Technology Data Exchange (ETDEWEB)
Blyth, D.; Gibson, M.; Mcfarland, D.; Comfort, J.R., E-mail: Joseph.Comfort@asu.edu
2014-02-21
The large growth of flash ADC techniques for processing signals, especially in applications of streaming data, raises issues such as data flow through an acquisition system, long-term storage, and greater complexity in data analysis. In addition, experiments that push the limits of sensitivity need to distinguish legitimate signals from noise. The use of correlation coefficients is examined to address these issues. They are found to be quite successful well into the noise region. The methods can also be extended to Field Programmable Gate Array modules for compressing the data flow and greatly enhancing the event rate capabilities.
Basketball Surfaces and Coefficient of Restitution
Directory of Open Access Journals (Sweden)
Kristyn Peacock
2015-01-01
Full Text Available A basketball was released from varying drop heights to simulate the impact speeds of a typical soft, medium, and hard dribble. This was repeated across four different surfaces that students typically play on–exposed aggregate concrete, maple wood flooring, EPI Outdoor Sport flooring, and playground rubber mesh. From the measured drop and bounce heights, the coefficient of restitution(CORwas calculated. It was concluded that only playground rubber mesh had COR’s below the regulation range, with the other three surfaces having COR’s within regulation.
A robust bayesian estimate of the concordance correlation coefficient.
Feng, Dai; Baumgartner, Richard; Svetnik, Vladimir
2015-01-01
A need for assessment of agreement arises in many situations including statistical biomarker qualification or assay or method validation. Concordance correlation coefficient (CCC) is one of the most popular scaled indices reported in evaluation of agreement. Robust methods for CCC estimation currently present an important statistical challenge. Here, we propose a novel Bayesian method of robust estimation of CCC based on multivariate Student's t-distribution and compare it with its alternatives. Furthermore, we extend the method to practically relevant settings, enabling incorporation of confounding covariates and replications. The superiority of the new approach is demonstrated using simulation as well as real datasets from biomarker application in electroencephalography (EEG). This biomarker is relevant in neuroscience for development of treatments for insomnia.
Matrimonial distance, inbreeding coefficient and population size: Dhangar data.
Majumder, P P; Malhotra, K C
1979-01-01
Data on the distance between the birthplaces of spouses (matrimonial distance) were collected from 2,260 married individuals belonging to 21 endogamous castes of the Dhangar (shepherd) cast-cluster of Maharashtra, India. The general form of the distribution of matrimonial distances is one which is extremely positively skewed and leptokurtic. The percentage of intra-village marriages generally decreases from the southern areas of Maharashtra to the northern areas of the state, as does the inbreeding coefficient. This situation is in conformity with the socio-cultural norms regulating matrimonial choice in south and north India. An attempt has been made to relate the degree of inbreeding to the mean matrimonial distance and population size. The mean matrimonial distance is more useful in predicting the degree of inbreeding than population size.
Einstein Coefficients and Equilibrium Formalism for Tachyon Radiation
Tomaschitz, R
2001-01-01
The spectral energy density of an ideal Bose gas of superluminal particles (tachyons) is derived. To this end, we consider atoms in equilibrium with tachyon radiation, study spontaneous and induced transitions effected by tachyons, calculate the Einstein coefficients, all semiclassically, and obtain, by detailed balancing, the equilibrium distribution of the tachyon gas. Tachyons are described by a real Proca field with negative mass square, coupled to a current of subluminal matter. Atomic transitions induced by tachyons are compared to photonic ones, and the tachyonic analog to the photoelectric effect is discussed. The cosmic tachyon background is scrutinized in detail; high- and low-temperature expansions of the internal energy, the entropy, the heat capacities, and the number density are compared with the corresponding quantities of the photon background. The negative mass square in the wave equation changes the frequency scaling in the Rayleigh-Jeans law, and there are also significant changes in the lo...
Apparent diffusion coefficient measurements in progressive supranuclear palsy
Energy Technology Data Exchange (ETDEWEB)
Ohshita, T.; Oka, M.; Imon, Y.; Yamaguchi, S.; Mimori, Y.; Nakamura, S. [Hiroshima Univ. (Japan). School of Medicine
2000-09-01
We measured the apparent diffusion coefficient (ADC), using diffusion-weighted imaging (DWI) and signal intensity on T2-weighted MRI in the cerebral white matter of patients with progressive supranuclear palsy (PSP) and age-matched normal subjects. In PSP, ADC in the prefrontal and precentral white matter was significantly higher than in controls. There was no significant difference in signal intensity on T2-weighted images. The ADC did correlate with signal intensity. The distribution of the elevation of ADC may be the consequence of underlying pathological changes, such as neurofibrillary tangles or glial fibrillary tangles in the cortex. Our findings suggest that ADC measurement might be useful for demonstrating subtle neuropathological changes. (orig.)
Weighted congestion coefficient feedback in intelligent transportation systems
Dong, Chuan-Fei; Ma, Xu; Wang, Bing-Hong
2010-03-01
In traffic systems, a reasonable information feedback can improve road capacity. In this Letter, we study dynamics of traffic flow with real-time information. And the influence of a feedback strategy named Weighted Congestion Coefficient Feedback Strategy (WCCFS) is introduced, based on a two-route scenario in which dynamic information can be generated and displayed on the board to guide road users to make a choice. Our model incorporates the effects of adaptability into the cellular automaton models of traffic flow and simulation results adopting this optimal information feedback strategy have demonstrated high efficiency in controlling spatial distribution of traffic patterns compared with the other three information feedback strategies, i.e., vehicle number and flux.
Correlation Coefficients: Mean Bias and Confidence Interval Distortions
Directory of Open Access Journals (Sweden)
Richard L. Gorsuch
2011-05-01
Full Text Available Non-zero correlation coefficients have non-normal distributions, affecting both means and standard deviations. Previous research suggests that z transformation may effectively correct mean bias for N's less than 30. In this study, simulations with small (20 and 30 and large (50 and 100 N's found that mean bias adjustments for larger N's are seldom needed. However, z transformations improved confidence intervals even for N = 100. The improvement was not in the estimated standard errors so much as in the asymmetrical CI's estimates based upon the z transformation. The resulting observed probabilities were generally accurate to within 1 point in the first non-zero digit. These issues are an order of magnitude less important for accuracy than design issues influencing the accuracy of the results, such as reliability, restriction of range, and N. DOI: 10.2458/azu_jmmss.v1i2.114
Moment series for the coefficient of variation in Weibull sampling
Energy Technology Data Exchange (ETDEWEB)
Bowman, K.O.; Shenton, L.R.
1981-01-01
For the 2-parameter Weibull distribution function F(t) = 1 - exp(-t/b)/sup c/, t > 0, with c and b positive, a moment estimator c* for c is the solution of the equationGAMMA(1 + 2/c*)/GAMMA/sup 2/ (1 + 1/c*) = 1 + v*/sup 2/ where v* is the coefficient of variation in the form ..sqrt..m/sub 2//m/sub 1/', m/sub 1/' being the sample mean, m/sub 2/ the sample second central moment (it is trivial in the present context to replace m/sub 2/ by the variance). One approach to the moments of c* (Bowman and Shenton, 1981) is to set-up moment series for the scale-free v*. The series are apparently divergent and summation algorithms are essential; we consider methods due to Levin (1973) and one, introduced ourselves (Bowman and Shenton, 1976).
Pressure coefficient evolutions on the blades of a Savonius rotor
Energy Technology Data Exchange (ETDEWEB)
Chauvin, A.; Guignard, S. [UMRR 7343, Marseilles (France). Lab. IUSTI; Kamoun, B. [Faculte des Sciences de Sfax (Tunisia). Lab. de Physique
2012-07-01
Measurements of the pressure field distribution on the blades of a vertical axis Savonius wind machine are presented. The rotor used in the wind tunnel is a two blades cylindrical shape with a central gap. Pressure gauges are placed on each side of a blade, so the pressure jumps between intrados and extrados of a blade during a whole rotation are drawn. In the static configuration, the machine is disposed at various incidences. The determination of pressure jumps allows to calculate the static torque of the machine versus the incidence angle. In the dynamic situation the machine is rotating at various frequencies and gauges signals are varying dynamically of course with the incidence. The dynamic torque coefficient is calculated. Evolutions of the starting torque and starting conditions are then described and dynamic effects on torque evolution are presented. (orig.)
Grading Standards of the Coefficient of Variation in the Electronic Raw Silk Size Testing
Institute of Scientific and Technical Information of China (English)
无
2007-01-01
In order to shorten the difference between the raw silk size grading standards of the world and that of China,to quicken the step of the electronic raw silk testing process,the distribution of the coefficient of variation (CV50m%) of the raw silk size in the electronic testing and the development of the new standards are studied according to the sampling and grading theory. By the theoretical deduction and the simulating experiments, the distribution of the coefficient of variation of the raw silk size is given,and the grading scheme whose quality index is the coefficient of variation(CV50m%)of the raw silk size and the grading precisions of all grades are proposed. Moreover,the rightness and the feasibility of the grading scheme are testified by the sampling and grading simulation.
Hydrodynamic Coefficients of Ships with Forward Speed in Shallow Waters
Institute of Scientific and Technical Information of China (English)
M.HASANADIL; DUANWen-yang; WANGYu
2004-01-01
Effects of depth and forward speed on hydrodynamic coefficients of ships are presented in this paper. A modified simple Green function technique was used to calculate 2D coefficients while strip theory was used to calculate 3D coefficients. Numerical results are provided for hydrodynamic coefficients of parabolic hull ship. It is found out that both depth and forward speed have considerable effects on hydrodynamic coefficients of ship.
Tests of Hypotheses Arising In the Correlated Random Coefficient Model.
Heckman, James J; Schmierer, Daniel
2010-11-01
This paper examines the correlated random coefficient model. It extends the analysis of Swamy (1971), who pioneered the uncorrelated random coefficient model in economics. We develop the properties of the correlated random coefficient model and derive a new representation of the variance of the instrumental variable estimator for that model. We develop tests of the validity of the correlated random coefficient model against the null hypothesis of the uncorrelated random coefficient model.
Institute of Scientific and Technical Information of China (English)
ZhuJianxin
2002-01-01
In this paper,for an inhomogeneous material in which the thermal conductivity varies as a function of depth,an efficient treatment is proposed to inversely calculate the depth distribution of optical-absorption coefficient by the surface temperature of the material. It is demonstrated that the results of inverse computation by that method are more similar to the experimental ones measured by some destructive method. Thus ,the treatment is more feasible to nondestructively estimate the distribution.
Effect of electrostatic field on dynamic friction coefficient of pistachio
Directory of Open Access Journals (Sweden)
M. H Aghkhani
2016-04-01
25 mm and with wall thickness of 5 mm placed on trolleys. In the bottom of the container a separate aluminum plate was installed as the negative pole of the electric field. The friction plates as a positive pole placed on top of the sample. There were no contact between friction plates and walls of vessel (samples were about 2 to 3 mm higher from the edges of wall. Frictional force changes due to movement of table, measured and recorded by an accurate load cell. From force-displacement curves, the coefficient of dynamic friction and static coefficient of friction calculated. In general, according to the experimental design, 486 tests were performed. Results and Discussion: According to the results of statistical analysis, there is significant interaction affect between pistachios type and electrical field, as well as, the interaction between electrical field and speed, on dynamic coefficient of friction. It means two pistachio types can be separated by electrical charging. Different physical properties of surface of filled non-splits pistachio nuts (such as corners and edges and filled splits ones, caused differences in the distribution of electric charge and as a result, its interaction with the electric field were significant. Changes in dynamic coefficient of friction according to the electric field intensity at different levels of moisture content and speed on the friction surfaces of iron, aluminum and rubber, was drawn in Fig.4, 5 and 6, respectively. These figures reflected the reduction of dynamic coefficient of friction by increasing the movement speed of table. According to Fig.7, increasing the intensity of the electric field increases the dynamic coefficient of friction. Because this leads to build the opposition charge on samples and galvanized iron sheets, and with increase of electrical field, these charges will rise. Fig.9 shows different trends of variation of dynamic coefficient of friction against moisture on rubber surface. This chart shows the
Camporesi, Roberto
2011-01-01
We present an approach to the impulsive response method for solving linear constant-coefficient ordinary differential equations based on the factorization of the differential operator. The approach is elementary, we only assume a basic knowledge of calculus and linear algebra. In particular, we avoid the use of distribution theory, as well as of…
Sample Size Calculation for Estimating or Testing a Nonzero Squared Multiple Correlation Coefficient
Krishnamoorthy, K.; Xia, Yanping
2008-01-01
The problems of hypothesis testing and interval estimation of the squared multiple correlation coefficient of a multivariate normal distribution are considered. It is shown that available one-sided tests are uniformly most powerful, and the one-sided confidence intervals are uniformly most accurate. An exact method of calculating sample size to…
Sample Size Calculation for Estimating or Testing a Nonzero Squared Multiple Correlation Coefficient
Krishnamoorthy, K.; Xia, Yanping
2008-01-01
The problems of hypothesis testing and interval estimation of the squared multiple correlation coefficient of a multivariate normal distribution are considered. It is shown that available one-sided tests are uniformly most powerful, and the one-sided confidence intervals are uniformly most accurate. An exact method of calculating sample size to…
Directory of Open Access Journals (Sweden)
Y.K.Sklifus
2012-12-01
Full Text Available The article presents the calculation of heat transfer coefficient during condensation of steam, the mathematical model of temperature distribution in the gas and liquid phases of the coolant and the model of the formation of the condensate film on the walls of the tubes.
Camporesi, Roberto
2011-01-01
We present an approach to the impulsive response method for solving linear constant-coefficient ordinary differential equations based on the factorization of the differential operator. The approach is elementary, we only assume a basic knowledge of calculus and linear algebra. In particular, we avoid the use of distribution theory, as well as of…
Note---The Mean-Coefficient-of-Variation Rule: The Lognormal Case
Haim Levy
1991-01-01
The mean-variance (M-V) rule may lead to paradoxical results which may be resolved by employing the mean coefficient of variation (M-C) rule. It is shown that the M-C rule constitutes an optimal decision rule for lognormal distributions.
Recursive construction of operator product expansion coefficients
Holland, J
2014-01-01
We derive a novel formula for the derivative of operator product expansion (OPE) coefficients with respect to a coupling constant. The formula only involves the OPE coefficients themselves, and no further input, and is in this sense self-consistent. Furthermore, unlike other formal identities of this general nature in quantum field theory (such as the formal expression for the Lagrangian perturbation of a correlation function), our formula is completely well-defined from the start, i.e. requires no further UV-renormalization. This feature is a result of a cancelation of UV-divergences between various terms in our identity. Our proof, and an analysis of the features, of our identity is given for the example of massive, Euclidean $\\varphi^4$ theory in 4 dimensional Euclidean space, and relies heavily on the framework of the renormalization group flow equations. It is valid to arbitrary, but finite orders in perturbation theory. The final formula, however, makes no explicit reference to the renormalization group...
Estimating biokinetic coefficients in the PACT™ system.
Shen, Zhiyao; Arbuckle, Wm Brian
2016-02-01
When powdered activated carbon (PAC) is continuously added to the aeration tank of an activated sludge reactor, the modification is called a PACT™ process (for powdered activated carbon treatment). The PAC provides many benefits, but complicates the determination of biological phenomena. Determination of bio-oxidation kinetics in a PACT system is a key to fully understanding enhanced biological mechanisms resulting from PAC addition. A model is developed to account for the main mechanisms involved in the PACT system -- adsorption, air stripping and bio-oxidation. The model enables the investigation of biokinetic information, including possible synergistic effects. Six parallel reactors were used to treat a synthetic waste; three activated sludge and three PACT. The PACT reactors provided significantly reduced effluent TOC (total organic carbon). Biokinetic coefficients were obtained from steady-state data using averaged reactor data and by using all data (22 points for each reactor). As expected, the PACT reactors resulted in a substantial reduction in the effluent concentration of non-biodegradable total organic carbon. The Monod equation's half-saturation coefficient (Ks) was reduced significantly in the PACT reactors, resulting in higher growth rates at lower concentrations. The maximum specific substrate utilization (qm) rate was also reduced about 25% using the averaged data and remained unchanged using all the data. The substrate utilization values are affected by errors in biomass determination and more research is needed to accurately determine biomass.
Morgenstern type bivariate Lindley Distribution
V S Vaidyanathan; Sharon Varghese, A
2016-01-01
In this paper, a bivariate Lindley distribution using Morgenstern approach is proposed which can be used for modeling bivariate life time data. Some characteristics of the distribution like moment generating function, joint moments, Pearson correlation coefficient, survival function, hazard rate function, mean residual life function, vitality function and stress-strength parameter R=Pr(Y
Diffusion coefficient test of {sup 237}Np in bentonite backfill materials
Energy Technology Data Exchange (ETDEWEB)
Cui Anxi; Fan Zhiwen; Zhang Jinsheng; Gu Cunli [China Inst. for Radiation Protection, Shanxi (China); Mukai, M.; Maeda, T.; Matsumoto, J.; Tanaka, T.; Ogawa, H. [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment
2002-03-01
This paper describes the work on diffusion coefficient test of Np in bentonite backfill materials. Due to its very low permeability, diffusion is the dominant migration mechanics in bentonite. The bentonite comes from Inner Mongolia of China. {sup 237}Np was used as tracer. The special apparatus for diffusion test was setup, the diffusion coefficient of Np in pure bentonite and sand-bentonite mixture were tested. The tracer was introduced between two bentonite columns. After a specific contacting period, the bentonite columns were taken out and cut to very thin slices. The radioactivity in bentonite slices was analyzed to give the nuclide concentration versus distance curves. The diffusion coefficient could be estimated. The diffusion coefficient of pure bentonite at different density was tested. When the density of pure bentonite samples varied from 1.1, 1.3, 1.5 to 1.7 g/ml, their diffusion coefficient were 1.36 x 10{sup -13} m{sup 2}/s 1.16 x 10{sup -13}m{sup 2}/s, 1.07 x 10{sup -13} m{sup 2}/s and 8.26 x 10{sup -14} m{sup 2}/s respectively. The diffusion coefficient of Np in sand-bentonite mixture sample was 4.13 x 10{sup -13} m{sup 2}/s. To estimate the distribution coefficient (K{sub d}) value of Np in mixture sample by diffusion method, the diffusion coefficient of Br was measured./ The concluded K{sub d} value was 77ml/g for the sand-bentonite mixture. The K{sub d} value obtained by batch test methods was 30ml/g. The reason is related with the error of Br diffusion coefficient and solid-liquid ratio. (author)
Thermal Conductivity Coefficient from Microscopic Models
Nemakhavhani, T E
2016-01-01
Thermal conductivity of hadron matter is studied using a microscopic transport model, which will be used to simulate ultra-relativistic heavy ion collisions at different energy densities, namely the Ultra-relativistic Quantum Molecular Dynamics (UrQMD). The molecular dynamics simulation is performed for a system of light mesons species (pion, rho, kaon) in a box with periodic boundary conditions. The equilibrium state is investigated by studying chemical equilibrium and thermal equilibrium of the system. Particle multiplicity equilibrates with time, and the energy spectra of different light mesons species have the same slopes and common temperatures when thermal equilibrium is reached. Thermal conductivity transport coefficient is calculated from the heat current - current correlations using the Green-Kubo relations.
Secondary Ionization Coefficient of Dielectric Electrode
Kashiwagi, Yasuhide; Suzuki, Susumu; Itoh, Haruo
Experiments for observations and stabilization of discharge paths in several electrode systems are carried out aiming at precise measurement of the secondary ionization coefficient γ of MgO film electrode. The discharge chamber is filled with Ar gas. The waveforms of the applied voltage between the electrodes and the discharge current are measured with visual observation of the discharge light. Two MgO coated electrodes are placed so that they are facing each other. For these MgO electrodes, the discharge paths take a detour, not the shortest distance. Smaller prebreakdown current pulses are observed before the breakdown. After breakdown, discontinuous discharge current is observed. Therefore, it is prepared a glass tube surrounding the discharge area. As the result, the discharge paths take a straight perpendicular for the electrode surface, and the discharge is stabilized.
Molar extinction coefficients of some fatty acids
Sandhu, G. K.; Singh, Kulwant; Lark, B. S.; Gerward, L.
2002-10-01
The attenuation of gamma rays in some fatty acids, viz. formic acid (CH 2O 2), acetic acid (C 2H 4O 2), propionic acid (C 3H 6O 2), butyric acid (C 4H 8O 2), n-hexanoic acid (C 6H 12O 2), n-caprylic acid (C 8H 16O 2), lauric acid (C 12H 24O 2), myristic acid (C 14H 28O 2), palmitic acid (C 16H 32O 2), oleic acid (C 18H 34O 2) and stearic acid (C 18H 36O 2), has been measured at the photon energies 81, 356, 511, 662, 1173 and 1332 keV. Experimental values for the molar extinction coefficient, the effective atomic number and the electron density have been derived and compared with theoretical calculations. There is good agreement between experiment and theory.
Clustering stocks using partial correlation coefficients
Jung, Sean S.; Chang, Woojin
2016-11-01
A partial correlation analysis is performed on the Korean stock market (KOSPI). The difference between Pearson correlation and the partial correlation is analyzed and it is found that when conditioned on the market return, Pearson correlation coefficients are generally greater than those of the partial correlation, which implies that the market return tends to drive up the correlation between stock returns. A clustering analysis is then performed to study the market structure given by the partial correlation analysis and the members of the clusters are compared with the Global Industry Classification Standard (GICS). The initial hypothesis is that the firms in the same GICS sector are clustered together since they are in a similar business and environment. However, the result is inconsistent with the hypothesis and most clusters are a mix of multiple sectors suggesting that the traditional approach of using sectors to determine the proximity between stocks may not be sufficient enough to diversify a portfolio.
Condensation heat transfer coefficient versus wettability
Roudgar, M.; De Coninck, J.
2015-05-01
In this paper we show how condensation on substrates can induce wetting behavior that is quite different from that of deposited or impinging drops. We describe surfaces with the same wettability in ambient conditions presenting different wetting behavior and growth of droplets in condensation. The experimental results show a rapid spread of droplets and formation of the film on the copper surface, while droplets on SU-8 surface remains on the regular shape while they grow within the time, without coalescence, as observed for Cu. Although the heat conductivity of SU-8 is much lower, due to a difference in wetting behavior, the heat transfer coefficient (h) is higher for dropwise condensation on Cu with a thin layer of SU-8 than filmwise on the bare copper.
Effective Electrocardiogram Steganography Based on Coefficient Alignment.
Yang, Ching-Yu; Wang, Wen-Fong
2016-03-01
This study presents two types of data hiding methods based on coefficient alignment for electrocardiogram (ECG) signals, namely, lossy and reversible ECG steganographys. The lossy method is divided into high-quality and high-capacity ECG steganography, both of which are capable of hiding confidential patient data in ECG signals. The reversible data hiding method can not only hide secret messages but also completely restore the original ECG signal after bit extraction. Simulations confirmed that the perceived quality generated by the lossy ECG steganography methods was good, while hiding capacity was acceptable. In addition, these methods have a certain degree of robustness, which is rare in conventional ECG stegangraphy schemes. Moreover, the proposed reversible ECG steganography method can not only successfully extract hidden messages but also completely recover the original ECG data.
Coefficient of performance of Stirling refrigerators
E Mungan, Carl
2017-09-01
Stirling coolers transfer heat in or out of the working fluid during all four stages of their operation, and their coefficient of performance depends on whether the non-isothermal heat exchanges are performed reversibly or irreversibly. Both of these possibilities can in principle be arranged. Notably, if the working fluid is an ideal gas, the input of energy in the form of heat during one isochoric step is equal in magnitude to the output during the other isochoric step in the cycle. The theoretical performance of the fridge can then attain the reversible Carnot limit if a regenerator is used, which is a high heat capacity material through which the gas flows. Various Stirling refrigerator configurations are analysed in this article at a level of presentation suitable for an introductory undergraduate thermodynamics course.
Friction Experiments for Dynamical Coefficient Measurement
Directory of Open Access Journals (Sweden)
J. J. Arnoux
2011-01-01
Full Text Available An experimental study, including three experimental devices, is presented in order to investigate dry friction phenomena in a wide range of sliding speeds for the steel on steel contact. A ballistic setup, with an air gun launch, allows to estimate the friction coefficient between 20 m/s and 80 m/s. Tests are completed by an adaptation of the sensor on a hydraulic tensile machine (0.01 m/s to 3 m/s and a pin-on-disk tribometer mounted on a CNC lathe (1 to 30 m/s. The interactions at the asperity scale are characterized by a white light interferometer surface analysis.
Transport coefficients in superfluid neutron stars
Energy Technology Data Exchange (ETDEWEB)
Tolos, Laura [Instituto de Ciencias del Espacio (IEEC/CSIC) Campus Universitat Autònoma de Barcelona, Facultat de Ciències, Torre C5, E-08193 Bellaterra (Barcelona) (Spain); Frankfurt Institute for Advances Studies. Johann Wolfgang Goethe University, Ruth-Moufang-Str. 1, 60438 Frankfurt am Main (Germany); Manuel, Cristina [Instituto de Ciencias del Espacio (IEEC/CSIC) Campus Universitat Autònoma de Barcelona, Facultat de Ciències, Torre C5, E-08193 Bellaterra (Barcelona) (Spain); Sarkar, Sreemoyee [Tata Institute of Fundamental Research, Homi Bhaba Road, Mumbai-400005 (India); Tarrus, Jaume [Physik Department, Technische Universität München, D-85748 Garching (Germany)
2016-01-22
We study the shear and bulk viscosity coefficients as well as the thermal conductivity as arising from the collisions among phonons in superfluid neutron stars. We use effective field theory techniques to extract the allowed phonon collisional processes, written as a function of the equation of state and the gap of the system. The shear viscosity due to phonon scattering is compared to calculations of that coming from electron collisions. We also comment on the possible consequences for r-mode damping in superfluid neutron stars. Moreover, we find that phonon collisions give the leading contribution to the bulk viscosities in the core of the neutron stars. We finally obtain a temperature-independent thermal conductivity from phonon collisions and compare it with the electron-muon thermal conductivity in superfluid neutron stars.
Experimental measurement of dispersion coefficients for gases
Energy Technology Data Exchange (ETDEWEB)
De Delgado, E. [National University at Comahue (Brazil); Da Franca Correa, A.C. [State Univ. of Campinas (Brazil)
2001-06-01
A series of experiments were conducted on dispersion, a phenomenon by which molecules of two miscible fluids diffuse into one another when they come into contact with each other. Both longitudinal and transverse diffusion is a result of forced flow. Longitudinal dispersion occurs in the direction of flow, while transverse dispersion occurs perpendicular to the direction of flow. This study focused on measuring longitudinal dispersion coefficients on natural gas displaced by an inert gas (nitrogen) at very low pressure. The experiments were carried out at two different pressure ranges on unconsolidated porous media at a Gas Plant Laboratory near Neuquen, Argentina. Two different types of porous media were used, a plastic hose and a metallic slim tube. They were each filled twice with both natural and synthetic sand grains. The study provided a better understanding of how gases behave at low pressures. 4 refs., 4 tabs., 5 figs.
Fractai Estimation of Joint Roughness Coefficients
Institute of Scientific and Technical Information of China (English)
谢和平; Willian G.Pariseau
1994-01-01
Based on the triadic Koch curve,a generalized fractal model of joint profiles is establishedto simulate joint roughness.The fractal dimension of a joint profile can be directly obtained from the two pa-rameters,L~* and h~*, the average base length and average height of asperities of the joint,respectively,i,e D=log4/log[2(1+cos tan~1(2h’/L’))]This fractal dimension is strongly correlated with the value of the joint roughness coefficient (JRC). An empirical relationship is found in the form,JRC=85.2671·(D-1)~0.5679 Thus, the fractal analysis proposed provides a new method of estimating JRC values
Comment on "Generalized exclusion processes: Transport coefficients"
Becker, T.; Nelissen, K.; Cleuren, B.; Partoens, B.; Van den Broeck, C.
2016-04-01
In a recent paper, Arita et al. [Phys. Rev. E 90, 052108 (2014), 10.1103/PhysRevE.90.052108] consider the transport properties of a class of generalized exclusion processes. Analytical expressions for the transport-diffusion coefficient are derived by ignoring correlations. It is claimed that these expressions become exact in the hydrodynamic limit. In this Comment, we point out that (i) the influence of correlations upon the diffusion does not vanish in the hydrodynamic limit, and (ii) the expressions for the self- and transport diffusion derived by Arita et al. are special cases of results derived in Becker et al. [Phys. Rev. Lett. 111, 110601 (2013), 10.1103/PhysRevLett.111.110601].
Transport coefficients in superfluid neutron stars
Tolos, Laura; Sarkar, Sreemoyee; Tarrus, Jaume
2014-01-01
We study the shear and bulk viscosity coefficients as well as the thermal conductivity as arising from the collisions among phonons in superfluid neutron stars. We use effective field theory techniques to extract the allowed phonon collisional processes, written as a function of the equation of state and the gap of the system. The shear viscosity due to phonon scattering is compared to calculations of that coming from electron collisions. We also comment on the possible consequences for r-mode damping in superfluid neutron stars. Moreover, we find that phonon collisions give the leading contribution to the bulk viscosities in the core of the neutron stars. We finally obtain a temperature-independent thermal conductivity from phonon collisions and compare it with the electron-muon thermal conductivity in superfluid neutron stars.
Irreducible polynomials with prescribed sums of coefficients
Tuxanidy, Aleksandr; Wang, Qiang
2016-01-01
Let $q$ be a power of a prime, let $\\mathbb{F}_q$ be the finite field with $q$ elements and let $n \\geq 2$. For a polynomial $h(x) \\in \\mathbb{F}_q[x]$ of degree $n \\in \\mathbb{N}$ and a subset $W \\subseteq [0,n] := \\{0, 1, \\ldots, n\\}$, we define the sum-of-digits function $$S_W(h) = \\sum_{w \\in W}[x^{w}] h(x)$$ to be the sum of all the coefficients of $x^w$ in $h(x)$ with $w \\in W$. In the case when $q = 2$, we prove, except for a few genuine exceptions, that for any $c \\in \\mathbb{F}_2$ an...
Partitioning coefficients between olivine and silicate melts
Bédard, J. H.
2005-08-01
Variation of Nernst partition coefficients ( D) between olivine and silicate melts cannot be neglected when modeling partial melting and fractional crystallization. Published natural and experimental olivine/liquidD data were examined for covariation with pressure, temperature, olivine forsterite content, and melt SiO 2, H 2O, MgO and MgO/MgO + FeO total. Values of olivine/liquidD generally increase with decreasing temperature and melt MgO content, and with increasing melt SiO 2 content, but generally show poor correlations with other variables. Multi-element olivine/liquidD profiles calculated from regressions of D REE-Sc-Y vs. melt MgO content are compared to results of the Lattice Strain Model to link melt MgO and: D0 (the strain compensated partition coefficient), EM3+ (Young's Modulus), and r0 (the size of the M site). Ln D0 varies linearly with Ln MgO in the melt; EM3+ varies linearly with melt MgO, with a dog-leg at ca. 1.5% MgO; and r0 remains constant at 0.807 Å. These equations are then used to calculate olivine/liquidD for these elements using the Lattice Strain Model. These empirical parameterizations of olivine/liquidD variations yield results comparable to experimental or natural partitioning data, and can easily be integrated into existing trace element modeling algorithms. The olivine/liquidD data suggest that basaltic melts in equilibrium with pure olivine may acquire small negative Ta-Hf-Zr-Ti anomalies, but that negative Nb anomalies are unlikely to develop. Misfits between results of the Lattice Strain Model and most light rare earth and large ion lithophile partitioning data suggest that kinetic effects may limit the lower value of D for extremely incompatible elements in natural situations characterized by high cooling/crystallization rates.
Apparent diffusion coefficient of normal adrenal glands*
Teixeira, Sara Reis; Elias, Paula Condé Lamparelli; Leite, Andrea Farias de Melo; de Oliveira, Tatiane Mendes Gonçalves; Muglia, Valdair Francisco; Elias Junior, Jorge
2016-01-01
Objective To assess the feasibility and reliability of apparent diffusion coefficient (ADC) measurements of normal adrenal glands. Materials and methods This was a retrospective study involving 32 healthy subjects, divided into two groups: prepubertal (PreP, n = 12), aged from 2 months to 12.5 years (4 males; 8 females); and postpubertal (PostP, n = 20), aged from 11.9 to 61 years (5 males; 15 females). Diffusion-weighted magnetic resonance imaging (DW-MRI) sequences were acquired at a 1.5 T scanner using b values of 0, 20, 500, and 1000 s/mm2. Two radiologists evaluated the images. ADC values were measured pixel-by-pixel on DW-MRI scans, and automatic co-registration with the ADC map was obtained. Results Mean ADC values for the right adrenal glands were 1.44 × 10-3 mm2/s for the PreP group and 1.23 × 10-3 mm2/s for the PostP group, whereas they were 1.58 × 10-3 mm2/s and 1.32 × 10-3 mm2/s, respectively, for the left glands. ADC values were higher in the PreP group than in the PostP group (p < 0.05). Agreement between readers was almost perfect (intraclass correlation coefficient, 0.84-0.94; p < 0.05). Conclusion Our results demonstrate the feasibility and reliability of performing DW-MRI measurements of normal adrenal glands. They could also support the feasibility of ADC measurements of small structures. PMID:28057963
Apparent diffusion coefficient of normal adrenal glands
Directory of Open Access Journals (Sweden)
Sara Reis Teixeira
Full Text Available Abstract Objective: To assess the feasibility and reliability of apparent diffusion coefficient (ADC measurements of normal adrenal glands. Materials and methods: This was a retrospective study involving 32 healthy subjects, divided into two groups: prepubertal (PreP, n = 12, aged from 2 months to 12.5 years (4 males; 8 females; and postpubertal (PostP, n = 20, aged from 11.9 to 61 years (5 males; 15 females. Diffusion-weighted magnetic resonance imaging (DW-MRI sequences were acquired at a 1.5 T scanner using b values of 0, 20, 500, and 1000 s/mm2. Two radiologists evaluated the images. ADC values were measured pixel-by-pixel on DW-MRI scans, and automatic co-registration with the ADC map was obtained. Results: Mean ADC values for the right adrenal glands were 1.44 × 10-3 mm2/s for the PreP group and 1.23 × 10-3 mm2/s for the PostP group, whereas they were 1.58 × 10-3 mm2/s and 1.32 × 10-3 mm2/s, respectively, for the left glands. ADC values were higher in the PreP group than in the PostP group (p < 0.05. Agreement between readers was almost perfect (intraclass correlation coefficient, 0.84-0.94; p < 0.05. Conclusion: Our results demonstrate the feasibility and reliability of performing DW-MRI measurements of normal adrenal glands. They could also support the feasibility of ADC measurements of small structures.
Winzor, Donald J; Deszczynski, Marcin; Harding, Stephen E; Wills, Peter R
2007-06-01
Experimental data for ovalbumin and lysozyme are presented to highlight the nonequivalence of second virial coefficients obtained for proteins by sedimentation equilibrium and light scattering. Theoretical considerations confirm that the quantity deduced from sedimentation equilibrium distributions is B(22), the osmotic second virial coefficient describing thermodynamic nonideality arising solely from protein self-interaction. On the other hand, the virial coefficient determined by light scattering is shown to reflect the combined contributions of protein-protein and protein-buffer interactions to thermodynamic nonideality of the protein solution. Misidentification of the light scattering parameter as B(22) accounts for published reports of negative osmotic second virial coefficients as indicators of conditions conducive to protein crystal growth. Finally, textbook assertions about the equivalence of second virial coefficients obtained by sedimentation equilibrium and light scattering reflect the restriction of consideration to single-solute systems. Although sedimentation equilibrium distributions for buffered protein solutions are, indeed, amenable to interpretation in such terms, the same situation does not apply to light scattering measurements because buffer constituents cannot be regarded as part of the solvent: instead they must be treated as non-scattering cosolutes.
Institute of Scientific and Technical Information of China (English)
胡彩霞; 谢平; 许斌; 陈广才; 刘新有; 唐亚松
2012-01-01
Due to climate change,human activities and changes in watershed land surface and other factors,many hydrologic series not only present inter-annual variation,but their annual distribution features also vary in different degrees.This has a strong impact on hydraulic engineering plan and sustainable utilization and optimized allocation of water resources.At present,most studies on the annual distribution of hydrologic elements focus on their inhomogeneity and rarely consider the factor of environmental change that impacts the inhomogeneity.And some inhomogeneity indicators are poor in intuitiveness or comparability.This paper puts forth an analysis method for variation of such homogeneity based on the Gini coefficient.First,this method uses the Gini coefficient to construct a model to describe the homogeneity,and then adopts a hydrologic variation diagnosis system to analyze the variation of the homogeneity GI series,finally uses a mean difference method to explore the physical origin.In a case study of the monthly runoff series at Longchuan station in the Dongjiang basin,the calculations show that in 1973,this runoff GI series took a strong hop mutation with its mean value increased by 21.07%.Of that sudden increase,roughly 40% came from climatic change and the rest 60% was a consequence of the changes in watershed land surface caused by human activities,in particular the construction and operation of the Fengshuba reservoir.%由于受气候变化、人类活动及流域下垫面变化等因素的影响,许多水文要素序列不仅在年际形式上发生了变异,而且其年内分配特性也发生了不同程度的变异,严重影响了水利工程的规划设计以及水资源可持续利用和优化调配。目前有关水文要素年内分配特性的研究,多集中在分析水文要素年内分配的不均匀性上,很少涉及这种不均匀性是否随环境变化而发生变异,且有些不均匀性指标表达不直观、可比性不强,为此本文
Yan, Liuming; Shao, Changle; Ji, Xiaobo
2009-07-15
The electroosmotic drag coefficient of water molecules in hydrated sodium perfluorosulfonate electrolyte polymer is evaluated on the basis of the velocity distribution functions of the sodium cations and water molecules with an electric field applied using molecular dynamics simulations. The simulation results indicate that both velocity distribution functions of water molecules and of sodium cations agree well with the classic Maxwellian velocity distribution functions when there is no electric field applied. If an electric field is applied, the distribution functions of velocity component in directions perpendicular to the applied electric field still agree with the Maxwellian velocity distribution functions but with different temperature parameters. In the direction of the applied electric field, the electric drag causes the velocity distribution function to deviate from the Maxwellian velocity distribution function; however, to obey the peak shifted Maxwellian distribution function. The peak shifting velocities coincide with the average transport velocities induced by the electric field, and could be applied to the evaluation of the electroosmotic drag coefficient of water. By evaluation of the transport velocities of water molecules in the first coordination shells of sodium cations, sulfonate anion groups, and in the bulk, it is clearly shown that the water molecules in the first coordination shell of sodium cations are the major contribution to the electroosmotic drag and momentum transfer from water molecules within the first coordination shell to the other water molecules also contributes to the electroosmotic drag.
Substantial local variation of the Seebeck coefficient in gold nanowires.
Zolotavin, Pavlo; Evans, Charlotte I; Natelson, Douglas
2017-07-06
Nanoscale structuring holds promise to improve the thermoelectric properties of materials for energy conversion and photodetection. We report a study of the spatial distribution of the photothermoelectric voltage in thin-film nanowire devices fabricated from a single metal. A focused laser beam is used to locally heat the metal nanostructure via a combination of direct absorption and excitation of a plasmon resonance in Au devices. As seen previously, in nanowires shorter than the spot size of the laser, we observe a thermoelectric voltage distribution that is consistent with the local Seebeck coefficient being spatially dependent on the width of the nanostructure. In longer structures, we observe extreme variability of the net thermoelectric voltage as the laser spot is scanned along the length of the nanowire. The sign and magnitude of the thermoelectric voltage is sensitive to the structural defects, metal grain structure, and surface passivation of the nanowire. This finding opens the possibility of improved local control of the thermoelectric properties at the nanoscale.
Institute of Scientific and Technical Information of China (English)
LI Pengping; SU Dagen; WANG Shengnian; FAN Zhihong
2011-01-01
The influence of binder composition and pore structure of concrete on chloride diffusion coefficient in concrete were investigated by the natural immersion test, MIP test, SEM and EDS test, respectively. The experimental results showed that the effect of binder composition on chloride diffusion coefficient was the comprehensive result of concrete pore structure and binder hydration products, and the porosity and pore size distribution were the main factors that influence the changes of diffusion coefficient. The chloride diffusion coefficient decreased with increasing the curing temperature and the relative humidity. The hydration degree were promoted by improving curing temperatures, and then the porosity of concrete decreased and the proportion of gel pore and transitional pore increased, respectively. But the water evaporation decreased with increasing the relative humidity and then decreased porosity and increased the proportion of gel pore and transitional pore. Additionally, The chloride diffusion coefficient of concrete got the lower value when the appropriate replacement of fly ash in the ranges of 10%-20%, when the double-adding fly ash and slag content was 50%. The porosity increased and the ratio of C/S in C-S-H decreased with further increasing the fly ash content, which led to increase the chloride diffusion coefficient in concrete.
The Relationship between the Friction Coefficient and the Asperities Original Inclination Angle
Directory of Open Access Journals (Sweden)
Guan Cheng-yao
2013-07-01
Full Text Available Because of the contact deformation, the inclination angle of the contact face is decreased gradually when contact and deformation. Base on the change of inclination angle of the contact surface, the concept “friction repose angle” set out. The tangent of the initial inclination angle of two asperities is three time of the tangent of the “friction repose angle”. The relationship set up a bridge between the initial surface geometric configuration (can be detect and the configuration which after the deformation (can not be detect. Static Friction Coefficient is the max value of Kinetic Friction Coefficient before the deformation process of instantaneous contact surface. The Ratio of Kinetic and Static Friction Coefficient distribute from 0.771 to 0.9117 and were inversely proportional to the inclination angle of the contact face .Kinetic Friction Coefficient is the average friction coefficient of the deformation process of instantaneous contact surface. In the sandstone, the value of Kinetic Friction Coefficient which more than 0.5546 is because of the coupling of different classes zigzag-shape surface asperities mostly. The study puts forward the new ideas “dynamic deformation tribology” which will promote the development of the Tribology.
Adler, Jeremy; Parmryd, Ingela
2010-08-01
The Pearson correlation coefficient (PCC) and the Mander's overlap coefficient (MOC) are used to quantify the degree of colocalization between fluorophores. The MOC was introduced to overcome perceived problems with the PCC. The two coefficients are mathematically similar, differing in the use of either the absolute intensities (MOC) or of the deviation from the mean (PCC). A range of correlated datasets, which extend to the limits of the PCC, only evoked a limited response from the MOC. The PCC is unaffected by changes to the offset while the MOC increases when the offset is positive. Both coefficients are independent of gain. The MOC is a confusing hybrid measurement, that combines correlation with a heavily weighted form of co-occurrence, favors high intensity combinations, downplays combinations in which either or both intensities are low and ignores blank pixels. The PCC only measures correlation. A surprising finding was that the addition of a second uncorrelated population can substantially increase the measured correlation, demonstrating the importance of excluding background pixels. Overall, since the MOC is unresponsive to substantial changes in the data and is hard to interpret, it is neither an alternative to nor a useful substitute for the PCC. The MOC is not suitable for making measurements of colocalization either by correlation or co-occurrence.
Institute of Scientific and Technical Information of China (English)
龚行楚; 吕阳成; 骆广生
2007-01-01
To get high purity caprolactam is a challenging task in the chemical fiber industry. To date, reports on the prediction of the distribution of caprolactam and its derivative chemicals have been few. In this study, the extraction of caprolactam with toluene as the extractant and N-methyl caprolactam with benzene and toluene as the extractants has been carried out. By defining new UNIFAC groups and calibrating related interaction parameters, a UNIFAC method was introduced to predict the equilibrium concentration of caprolactam and methyl caprolactam in toluene or benzene extraction processes. The calculated results fit very well with the experimental data. Using the UNIFAC model, the selectivity of extractants can be predicted.
The Attenuation of Correlation Coefficients: A Statistical Literacy Issue
Trafimow, David
2016-01-01
Much of the science reported in the media depends on correlation coefficients. But the size of correlation coefficients depends, in part, on the reliability with which the correlated variables are measured. Understanding this is a statistical literacy issue.
Recovering DC coefficients in block-based DCT.
Uehara, Takeyuki; Safavi-Naini, Reihaneh; Ogunbona, Philip
2006-11-01
It is a common approach for JPEG and MPEG encryption systems to provide higher protection for dc coefficients and less protection for ac coefficients. Some authors have employed a cryptographic encryption algorithm for the dc coefficients and left the ac coefficients to techniques based on random permutation lists which are known to be weak against known-plaintext and chosen-ciphertext attacks. In this paper we show that in block-based DCT, it is possible to recover dc coefficients from ac coefficients with reasonable image quality and show the insecurity of image encryption methods which rely on the encryption of dc values using a cryptoalgorithm. The method proposed in this paper combines dc recovery from ac coefficients and the fact that ac coefficients can be recovered using a chosen ciphertext attack. We demonstrate that a method proposed by Tang to encrypt and decrypt MPEG video can be completely broken.
TESTS FOR VARIANCE COMPONENTS IN VARYING COEFFICIENT MIXED MODELS
National Research Council Canada - National Science Library
Zaixing Li; Yuedong Wang; Ping Wu; Wangli Xu; Lixing Zhu
2012-01-01
.... To address the question of whether a varying coefficient mixed model can be reduced to a simpler varying coefficient model, we develop one-sided tests for the null hypothesis that all the variance components are zero...
Energy Technology Data Exchange (ETDEWEB)
Spielmann, V.; Li, W.B.; Zankl, M.; Oeh, U.
2015-11-15
The dose coefficients used in nuclear medicine for dose calculations of radiopharmaceuticals are based on recommendations by ICRP (International Commission on radiological protection) and the MIRD (Medical Internal Radiation Dose Committee) using mathematical models for the temporal activity distributions in organs and tissues (biokinetic models) and mathematical models of the human body. These models using an idealized human body do not include uncertainty estimations. The research project is aimed to determine the uncertainties and thus the reliability of the dose coefficients for radiopharmaceuticals and to identify the biokinetic and dosimetric parameters that contribute most of the uncertainties.
Estimating Subcatchment Runoff Coefficients using Weather Radar and a Downstream Runoff Sensor
DEFF Research Database (Denmark)
Ahm, Malte; Thorndahl, Søren Liedtke; Rasmussen, Michael R.;
2013-01-01
This paper presents a method for estimating runoff coefficients of urban drainage subcatchments based on a combination of high resolution weather radar data and flow measurements from a downstream runoff sensor. By utilising the spatial variability of the precipitation it is possible to estimate...... the runoff coefficients of the separate subcatchments. The method is demonstrated through a case study of an urban drainage catchment (678 ha) located in the city of Aarhus, Denmark. The study has proven that it is possible to use corresponding measurements of the relative rainfall distribution over...