Control of ordered mesoporous titanium dioxide nanostructures formed using plasma enhanced glancing angle deposition

Energy Technology Data Exchange (ETDEWEB)

Gibson, Des [Institute of Thin Films, Sensors & Imaging, Scottish Universities Physics Alliance, University of West of Scotland, Paisley, PA1 2BE (United Kingdom); Child, David, E-mail: david.child@uws.ac.uk [Institute of Thin Films, Sensors & Imaging, Scottish Universities Physics Alliance, University of West of Scotland, Paisley, PA1 2BE (United Kingdom); Song, Shigeng; Zhao, Chao [Institute of Thin Films, Sensors & Imaging, Scottish Universities Physics Alliance, University of West of Scotland, Paisley, PA1 2BE (United Kingdom); Alajiani, Yahya [Institute of Thin Films, Sensors & Imaging, Scottish Universities Physics Alliance, University of West of Scotland, Paisley, PA1 2BE (United Kingdom); Department of Physics, Faculty of Science, Jazan University, Jazan (Saudi Arabia); Waddell, Ewan [Thin Film Solutions Ltd, West of Scotland Science Park, Glasgow, G20 0TH (United Kingdom)

2015-10-01

Three dimensional nanostructures of mesoporous (pore diameter between 2-50 nm) nanocrystalline titania (TiO{sub 2}) were produced using glancing angle deposition combined with plasma ion assisted deposition, providing plasma enhanced glancing angle deposition eliminating the need for post-annealing to achieve film crystallinity. Electron beam evaporation was chosen to deposit nanostructures at various azimuthal angles, achieving designed variation in three dimensional nanostructure. A thermionic broad beam hollow cathode plasma source was used to enhance electron beam deposition, with ability to vary in real time ion fluxes and energies providing a means to modify and control TiO{sub 2} nanostructure real time with controlled density and porosity along and lateral to film growth direction. Plasma ion assisted deposition was carried out at room temperature using a hollow cathode plasma source, ensuring low heat loading to the substrate during deposition. Plasma enhanced glancing angle TiO{sub 2} structures were deposited onto borosilicate microscope slides and used to characterise the effects of glancing angle and plasma ion energy distribution function on the optical and nanostructural properties. Variation in TiO{sub 2} refractive index from 1.40 to 2.45 (@ 550 nm) using PEGLAD is demonstrated. Results and analysis of the influence of plasma enhanced glancing angle deposition on evaporant path and resultant glancing angle deviation from standard GLAD are described. Control of mesoporous morphology is described, providing a means of optimising light trapping features and film porosity, relevant to applications such as fabrication of dye sensitised solar cells. - Highlights: • Plasma assistance during glancing angle deposition enables control of morphology. • Ion energy variation during glancing angle deposition varies columnar angle • Column thickness of glancing angle deposition dependant on ion current density • Ion current density variation during

Controllable deposition distance of aligned pattern via dual-nozzle near-field electrospinning

Science.gov (United States)

Wang, Zhifeng; Chen, Xindu; Zeng, Jun; Liang, Feng; Wu, Peixuan; Wang, Han

2017-03-01

For large area micro/nano pattern printing, multi-nozzle electrohydrodynamic (EHD) printing setup is an efficient method to boost productivity in near-field electrospinning (NFES) process. And controlling EHD multi-jet accurate deposition under the interaction of nozzles and other parameters are crucial concerns during the process. The influence and sensitivity of various parameters such as the needle length, needle spacing, electrode-to-collector distance, voltage etc. on the direct-write patterning performance was investigated by orthogonal experiments with dual-nozzle NFES setup, and then the deposition distance estimated based on a novel model was compared with measurement results and proven. More controllable deposition distance and much denser of aligned naofiber can be achieved by rotating the dual-nozzle setup. This study can be greatly contributed to estimate the deposition distance and helpful to guide the multi-nozzle NFES process to accurate direct-write pattern in manufacturing process in future.

Controlled Deposition of Tin Oxide and Silver Nanoparticles Using Microcontact Printing

Directory of Open Access Journals (Sweden)

Joo C. Chan

2015-02-01

Full Text Available This report describes extensive studies of deposition processes involving tin oxide (SnOx nanoparticles on smooth glass surfaces. We demonstrate the use of smooth films of these nanoparticles as a platform for spatially-selective electroless deposition of silver by soft lithographic stamping. The edge and height roughness of the depositing metallic films are 100 nm and 20 nm, respectively, controlled by the intrinsic size of the nanoparticles. Mixtures of alcohols as capping agents provide further control over the size and shape of nanoparticles clusters. The distribution of cluster heights obtained by atomic force microscopy (AFM is modeled through a modified heterogeneous nucleation theory as well as Oswald ripening. The thermodynamic modeling of the wetting properties of nanoparticles aggregates provides insight into their mechanism of formation and how their properties might be further exploited in wide-ranging applications.

Real-time beam tracing for control of the deposition location of electron cyclotron waves

Energy Technology Data Exchange (ETDEWEB)

Reich, M., E-mail: matthias.reich@ipp.mpg.de; Bilato, R.; Mszanowski, U.; Poli, E.; Rapson, C.; Stober, J.; Volpe, F.; Zille, R.

2015-11-15

Highlights: • We successfully integrated a real-time EC beam tracing code at ASDEX Upgrade. • The calculation of EC beam deposition location is fast enough for control purposes. • The accuracy of the deposition location calculation exceeds equivalent measurements. • The implementation method is by design portable to larger fusion devices. - Abstract: Plasma control techniques that use electron cyclotron (EC) resonance heating and current drive such as control of neoclassical tearing modes require accurate control of the deposition location of EC beams. ASDEX Upgrade has successfully implemented a real-time version of the beam-tracing code TORBEAM into its real-time diagnostic system to act as a globally available module that calculates current deposition location and its sensitivity from other real-time diagnostic measurements for all its moveable EC wave launchers. Based on a highly (100×) accelerated version of TORBEAM, the software implementation as a diagnostic process uses parallelization and achieves cycle times of 15–20 ms for determining the radial deposition location of 12 beams in the plasma. This cycle time includes data input–output overhead arising from the use of available real-time signals. The system is by design portable to other machines such as ITER.

Optimization of spray deposition and Tetranychus urticae control with air assisted and electrostatic sprayer

Directory of Open Access Journals (Sweden)

Denise Tourino Rezende de Cerqueira

Full Text Available ABSTRACT: Improved spray deposition can be attained by electrostatically charging spray droplets, which increases the attraction of droplets to plants and decreases operator exposure to pesticide and losses to the environment. However, this technique alone is not sufficient to achieve desirable penetration of the spray solution into the crop canopy; thus, air assistance can be added to the electrostatic spraying to further improve spray deposition. This study was conducted to compare different spraying technologies on spray deposition and two-spotted spider mite control in cut chrysanthemum. Treatments included in the study were: conventional TJ 8003 double flat fan nozzles, conventional TXVK-3 hollow cone nozzles, semi-stationary motorized jet launched spray with electrostatic spray system (ESS and air assistance (AA, and semi-stationary motorized jet launched spray with AA only (no ESS. To evaluate the effect of these spraying technologies on the control of two-spotted spider mite, a control treatment was included that did not receive an acaricide application. The AA spraying technology, with or without ESS, optimized spray deposition and provided satisfactory two-spotted spider mite control up to 4 days after application.

Deposition of elemental sulfur in city gate Pressure Control Valves (PCVs)

Energy Technology Data Exchange (ETDEWEB)

Quinto, Thiago C. do; Veiga, Leandro S. da; Silva, Marcos J.M. da; Lemos, Marcelo C. de; Goncalves, Luciane T. [PETROBRAS Transporte S.A. (TRANSPETRO), Rio de Janeiro, RJ (Brazil)

2009-12-19

Deposition of elemental sulfur has been observed in city gate pressure control valves (PCV s), a phenomenon that causes operational problems in these facilities. This article discusses the problems caused by this deposition, especially in pilots of pressure control valves. While passing through PCV s, the flow of natural gas is subjected to a sharp drop in temperature due to the reduction of pressure (Joule-Thompson). When this happens, the elemental sulfur that is in balance with the flow of natural gas is deposited inside the PCV s and the obstacles ahead. Since PCV s are self-operated and use natural gas as the working fluid, the elemental sulfur is also deposited in the pilots as well. Elemental sulfur in powder form has very small particles - around 20 {mu}m - that prevent the perfect operation of the small moving parts of pilots. Because of this, the affected pilot cannot operate the PCV satisfactorily to regulate the pressure of the natural gas supplied to the customer. There are two possible consequences of this situation: when the customer increases consumption, the pressure will decline to less than below the limit established under the supply contract, which can lead to fines; and the pressure can rise above the limit tolerated by pipes, which can lead to dangerous ruptures. (author)

The role and origin of dilatant structural environments in the spatial control of geo-economic deposits

International Nuclear Information System (INIS)

Rosello, E.

2010-01-01

A major controlling the geometry, size and spatial location of the mineralization is the tectonic structure. This control is indeed essential in epigenetic deposits, where the structure is the main factor to determine the circulation, precipitation, and in many cases the generation of hydrothermal solutions associated with mineral deposits and / or alterations. Therefore, learning the type of structural control that a particular deposit is charged on a particular aspect and of fundamental importance not only in yacimientología to contribute to the genetic knowledge but also in economic terms to provide ideas and guidance in tasks prospecting, exploration and mineral exploitation

Thickness control in electrophoretic deposition of WO3 nanofiber thin films for solar water splitting

International Nuclear Information System (INIS)

Fang, Yuanxing; Lee, Wei Cheat; Canciani, Giacomo E.; Draper, Thomas C.; Al-Bawi, Zainab F.; Bedi, Jasbir S.; Perry, Christopher C.; Chen, Qiao

2015-01-01

Graphical abstract: - Highlights: • A novel method combining electrospinning and electrophoretic deposition was established for the creation of nanostructured semiconductor thin films. • The created thin films displayed a high chemical stability with a controllable thickness. • The PEC water splitting performance of the thin films was optimized by fine-tuning the thickness of the films. • A maximum photoconversion efficiency was achieved by 18 μm nanofibrous thin films. - Abstract: Electrophoretic deposition (EPD) of ground electrospun WO 3 nanofibers was applied to create photoanodes with controlled morphology for the application of photoelectrochemical (PEC) water splitting. The correlations between deposition parameters and film thicknesses were investigated with theoretical models to precisely control the morphology of the nanostructured porous thin film. The photoconversion efficiency was further optimized as a function of film thickness. A maximum photoconversion efficiency of 0.924% from electrospun WO 3 nanofibers that EPD deposited on a substrate was achieved at a film thickness of 18 μm.

Deposition of controllable preferred orientation silicon films on glass by inductively coupled plasma chemical vapor deposition

International Nuclear Information System (INIS)

Li Junshuai; Wang Jinxiao; Yin Min; Gao Pingqi; He Deyan; Chen Qiang; Li Yali; Shirai, Hajime

2008-01-01

An inductively coupled plasma (ICP) system with the adjustable distance between the inductance coil and substrates was designed to effectively utilize the spatial confinement of ICP discharge, and then control the gas-phase transport process. The effects of the gas phase processes on the crystallinity and preferred orientation of silicon films deposited on glass were systematically investigated. The investigation was conducted in the ICP-chemical vapor deposition process with the precursor gas of a SiH 4 /H 2 mixture at a substrate temperature of 350 deg. Highly crystallized silicon films with different preferred orientations, (111) or (220), could be selectively deposited by adjusting the SiH 4 dilution ratio [R=[SiH 4 ]/([SiH 4 ]+[H 2 ])] or total working pressure. When the total working pressure is 20 Pa, the crystallinity of the silicon films increases with the increase of the SiH 4 dilution ratio, while the preferred orientation was changed from (111) to (220). In the case of the fixed SiH 4 dilution (10%), the silicon film with I (220) /I (111) of about 3.5 and Raman crystalline fraction of about 89.6% has been deposited at 29.7 nm/min when the total working pressure was increased to 40 Pa. At the fixed SiH 4 partial pressure of 2 Pa, the film crystallinity decreases and the preferred orientation is always (111) with increasing the H 2 partial pressure from 18 to 58 Pa. Atomic force microscope reveals that the film deposited at a relatively high H 2 partial pressure has a very rough surface caused by the devastating etching of H atoms to the silicon network

Chemical Controls of Ozone Dry Deposition to the Sea Surface Microlayer

Science.gov (United States)

Carpenter, L.; Chance, R.; Tinel, L.; Saint, A.; Sherwen, T.; Loades, D.; Evans, M. J.; Boxhall, P.; Hamilton, J.; Stolle, C.; Wurl, O.; Ribas-Ribas, M.; Pereira, R.

2017-12-01

Oceanic dry deposition of atmospheric ozone (O3) is both the largest and most uncertain O3 depositional sink, and is widely acknowledged to be controlled largely by chemical reactions in the sea surface microlayer (SML) involving iodide (I-) and dissolved organic material (DOM). These reactions not only determine how quickly O3 can be removed from the atmosphere, but also result in emissions of trace gases including volatile organic compounds and may constitute a source of secondary organic aerosols to the marine atmosphere. Iodide concentrations at the sea surface vary by approximately an order of magnitude spatially, leading to more than fivefold variation in ozone deposition velocities (and volatile iodine fluxes). Sea-surface temperature is a reasonable predictor of [I-], however two recent parameterisations for surface I- differ by a factor of two at low latitudes. The nature and reactivity of marine DOM to O3 is almost completely unknown, although studies have suggested approximately equivalent chemical control of I- and DOM on ozone deposition. Here we present substantial new measurements of oceanic I- in both bulk seawater and the overlying SML, and show improved estimates of the global sea surface iodide distribution. We also present analyses of water-soluble DOM isolated from the SML and bulk seawater, and corresponding laboratory studies of ozone uptake to bulk and SML seawater, with the aim of characterizing the reactivity of O3 towards marine DOM.

Factors controlling deposits in recovery boilers -particle formation and deposition; Soodakattilan likaantuminen ja siihen vaikuttavien tekijoeiden hallinta. Hiukkasten muodostuminen ja depositio

Energy Technology Data Exchange (ETDEWEB)

Kauppinen, E I; Mikkanen, P; Tapper, U; Ylaetalo, S; Jaervinen, R [VTT Chemical Technology, Espoo (Finland); Jokiniemi, J K; Pyykoenen, J; Eskola, A [VTT Energy, Espoo (Finland)

1997-10-01

In this project the aim is to find critical factors controlling the deposit formation in the recovery boilers. Focus is on particle formation, growth and deposition. During year 1995 the aerosol particle formation was studied by an experimental study within the recovery boiler furnace and by a sensitivity study with the ABC (Aerosol Behaviour in Combustion) computer code. During year 1996 the experimental studies on the aerosol particle formation continued within the furnace and the deposition mechanisms for carry over particles were included in the ABC code and sensitivity studies of the deposition were carried out. The experimental study confirmed the fact that the particles are already formed in the recovery boiler furnace. The particle formation is initiated in the boundary layer of the burning droplet or char bed, where metals are vaporised and oxidised to form tiny seed particles

Controls of nitrous oxide emission after simulated cattle urine deposition

DEFF Research Database (Denmark)

Baral, Khagendra Raj; Thomsen, Anton Gårde; Olesen, Jørgen E

2014-01-01

Urine deposited during grazing is a significant source of atmospheric nitrous oxide (N2O). The potential for N2O emissions from urine patches is high, and a better understanding of controls is needed. This study investigated soil nitrogen (N) dynamics and N2O emissions from cattle urine...

Thickness control in electrophoretic deposition of WO{sub 3} nanofiber thin films for solar water splitting

Energy Technology Data Exchange (ETDEWEB)

Fang, Yuanxing; Lee, Wei Cheat; Canciani, Giacomo E.; Draper, Thomas C.; Al-Bawi, Zainab F. [Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ (United Kingdom); Bedi, Jasbir S. [School of Public Health & Zoonoses, Guru Angad Dev Veterinary and Animal Sciences University, Ludhiana 141004 Punjab (India); Perry, Christopher C. [Division of Biochemistry, School of Medicine, Loma Linda University, Loma Linda, CA 92350 (United States); Chen, Qiao, E-mail: qiao.chen@sussex.ac.uk [Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ (United Kingdom)

2015-12-15

Graphical abstract: - Highlights: • A novel method combining electrospinning and electrophoretic deposition was established for the creation of nanostructured semiconductor thin films. • The created thin films displayed a high chemical stability with a controllable thickness. • The PEC water splitting performance of the thin films was optimized by fine-tuning the thickness of the films. • A maximum photoconversion efficiency was achieved by 18 μm nanofibrous thin films. - Abstract: Electrophoretic deposition (EPD) of ground electrospun WO{sub 3} nanofibers was applied to create photoanodes with controlled morphology for the application of photoelectrochemical (PEC) water splitting. The correlations between deposition parameters and film thicknesses were investigated with theoretical models to precisely control the morphology of the nanostructured porous thin film. The photoconversion efficiency was further optimized as a function of film thickness. A maximum photoconversion efficiency of 0.924% from electrospun WO{sub 3} nanofibers that EPD deposited on a substrate was achieved at a film thickness of 18 μm.

Voltage-Controlled Spray Deposition of Multiwalled Carbon Nanotubes on Semiconducting and Insulating Substrates

Science.gov (United States)

Maulik, Subhodip; Sarkar, Anirban; Basu, Srismrita; Daniels-Race, Theda

2018-05-01

A facile, cost-effective, voltage-controlled, "single-step" method for spray deposition of surfactant-assisted dispersed carbon nanotube (CNT) thin films on semiconducting and insulating substrates has been developed. The fabrication strategy enables direct deposition and adhesion of CNT films on target samples, eliminating the need for substrate surface functionalization with organosilane binder agents or metal layer coatings. Spray coating experiments on four types of sample [bare silicon (Si), microscopy-grade glass samples, silicon dioxide (SiO2), and polymethyl methacrylate (PMMA)] under optimized control parameters produced films with thickness ranging from 40 nm to 6 μm with substantial surface coverage and packing density. These unique deposition results on both semiconducting and insulator target samples suggest potential applications of this technique in CNT thin-film transistors with different gate dielectrics, bendable electronics, and novel CNT-based sensing devices, and bodes well for further investigation into thin-film coatings of various inorganic, organic, and hybrid nanomaterials on different types of substrate.

Process control of high rate microcrystalline silicon based solar cell deposition by optical emission spectroscopy

International Nuclear Information System (INIS)

Kilper, T.; Donker, M.N. van den; Carius, R.; Rech, B.; Braeuer, G.; Repmann, T.

2008-01-01

Silicon thin-film solar cells based on microcrystalline silicon (μc-Si:H) were prepared in a 30 x 30 cm 2 plasma-enhanced chemical vapor deposition reactor using 13.56 or 40.68 MHz plasma excitation frequency. Plasma emission was recorded by optical emission spectroscopy during μc-Si:H absorber layer deposition at deposition rates between 0.5 and 2.5 nm/s. The time course of SiH * and H β emission indicated strong drifts in the process conditions particularly at low total gas flows. By actively controlling the SiH 4 gas flow, the observed process drifts were successfully suppressed resulting in a more homogeneous i-layer crystallinity along the growth direction. In a deposition regime with efficient usage of the process gas, the μc-Si:H solar cell efficiency was enhanced from 7.9 % up to 8.8 % by applying process control

Dynamic Control of Particle Deposition in Evaporating Droplets by an External Point Source of Vapor.

Science.gov (United States)

Malinowski, Robert; Volpe, Giovanni; Parkin, Ivan P; Volpe, Giorgio

2018-02-01

The deposition of particles on a surface by an evaporating sessile droplet is important for phenomena as diverse as printing, thin-film deposition, and self-assembly. The shape of the final deposit depends on the flows within the droplet during evaporation. These flows are typically determined at the onset of the process by the intrinsic physical, chemical, and geometrical properties of the droplet and its environment. Here, we demonstrate deterministic emergence and real-time control of Marangoni flows within the evaporating droplet by an external point source of vapor. By varying the source location, we can modulate these flows in space and time to pattern colloids on surfaces in a controllable manner.

Analysis on ore-controlling factors of Zhajistan uranium deposit, Xinjiang

International Nuclear Information System (INIS)

A Zhongming

2000-01-01

The geologic-structural background where the Zhajistan uranium deposit is located, and sedimentary features of the basin, as well as ore-controlling factors such as the uranium source, the reductant, hydrogeologic conditions and development features of interlayer oxidation zone in Zhajistan, are analysed. Then the author proposes the most favourable sedimentary cycle for uranium metallogenesis and the most favourable prospecting areas

Controlling droplet-based deposition uniformity of long silver nanowires by micrometer scale substrate patterning

International Nuclear Information System (INIS)

Basu, Nandita; Cross, Graham L W

2015-01-01

We report control of droplet-deposit uniformity of long silver nanowires suspended in solutions by microscopic influence of the liquid contact line. Substrates with microfabricated line patterns with a pitch far smaller than mean wire length lead to deposit thickness uniformity compared to unpatterned substrates. For high boiling-point solvents, two significant effects were observed: The substrate patterns suppressed coffee ring staining, and the wire deposits exhibited a common orientation lying perpendicular over top the lines. The latter result is completely distinct from previously reported substrate groove channeling effects. This work shows that microscopic influence of the droplet contact line geometry including the contact angle by altered substrate wetting allows significant and advantageous influence of deposition patterns of wire-like solutes as the drop dries. (paper)

Intelligent process control of fiber chemical vapor deposition

Science.gov (United States)

Jones, John Gregory

Chemical Vapor Deposition (CVD) is a widely used process for the application of thin films. In this case, CVD is being used to apply a thin film interface coating to single crystal monofilament sapphire (Alsb2Osb3) fibers for use in Ceramic Matrix Composites (CMC's). The hot-wall reactor operates at near atmospheric pressure which is maintained using a venturi pump system. Inert gas seals obviate the need for a sealed system. A liquid precursor delivery system has been implemented to provide precise stoichiometry control. Neural networks have been implemented to create real-time process description models trained using data generated based on a Navier-Stokes finite difference model of the process. Automation of the process to include full computer control and data logging capability is also presented. In situ sensors including a quadrupole mass spectrometer, thermocouples, laser scanner, and Raman spectrometer have been implemented to determine the gas phase reactants and coating quality. A fuzzy logic controller has been developed to regulate either the gas phase or the in situ temperature of the reactor using oxygen flow rate as an actuator. Scanning electron microscope (SEM) images of various samples are shown. A hierarchical control structure upon which the control structure is based is also presented.

Controlled density of vertically aligned carbon nanotubes in a triode plasma chemical vapor deposition system

International Nuclear Information System (INIS)

Lim, Sung Hoon; Park, Kyu Chang; Moon, Jong Hyun; Yoon, Hyun Sik; Pribat, Didier; Bonnassieux, Yvan; Jang, Jin

2006-01-01

We report on the growth mechanism and density control of vertically aligned carbon nanotubes using a triode plasma enhanced chemical vapor deposition system. The deposition reactor was designed in order to allow the intermediate mesh electrode to be biased independently from the ground and power electrodes. The CNTs grown with a mesh bias of + 300 V show a density of ∼ 1.5 μm -2 and a height of ∼ 5 μm. However, CNTs do not grow when the mesh electrode is biased to - 300 V. The growth of CNTs can be controlled by the mesh electrode bias which in turn controls the plasma density and ion flux on the sample

Structurally controlled deposition of silicon onto nanowires

Science.gov (United States)

Wang, Weijie; Liu, Zuqin; Han, Song; Bornstein, Jonathan; Stefan, Constantin Ionel

2018-03-20

Provided herein are nanostructures for lithium ion battery electrodes and methods of fabrication. In some embodiments, a nanostructure template coated with a silicon coating is provided. The silicon coating may include a non-conformal, more porous layer and a conformal, denser layer on the non-conformal, more porous layer. In some embodiments, two different deposition processes, e.g., a PECVD layer to deposit the non-conformal layer and a thermal CVD process to deposit the conformal layer, are used. Anodes including the nanostructures have longer cycle lifetimes than anodes made using either a PECVD or thermal CVD method alone.

Improvement in Device Performance and Reliability of Organic Light-Emitting Diodes through Deposition Rate Control

Directory of Open Access Journals (Sweden)

Shun-Wei Liu

2014-01-01

Full Text Available We demonstrated a fabrication technique to reduce the driving voltage, increase the current efficiency, and extend the operating lifetime of an organic light-emitting diode (OLED by simply controlling the deposition rate of bis(10-hydroxybenzo[h]qinolinato beryllium (Bebq2 used as the emitting layer and the electron-transport layer. In our optimized device, 55 nm of Bebq2 was first deposited at a faster deposition rate of 1.3 nm/s, followed by the deposition of a thin Bebq2 (5 nm layer at a slower rate of 0.03 nm/s. The Bebq2 layer with the faster deposition rate exhibited higher photoluminescence efficiency and was suitable for use in light emission. The thin Bebq2 layer with the slower deposition rate was used to modify the interface between the Bebq2 and cathode and hence improve the injection efficiency and lower the driving voltage. The operating lifetime of such a two-step deposition OLED was 1.92 and 4.6 times longer than that of devices with a single deposition rate, that is, 1.3 and 0.03 nm/s cases, respectively.

Macro controlling of copper oxide deposition processes and spray mode by using home-made fully computerized spray pyrolysis system

Science.gov (United States)

Essa, Mohammed Sh.; Chiad, Bahaa T.; Shafeeq, Omer Sh.

2017-09-01

Thin Films of Copper Oxide (CuO) absorption layer have been deposited using home-made Fully Computerized Spray Pyrolysis Deposition system FCSPD on glass substrates, at the nozzle to substrate distance equal to 20,35 cm, and computerized spray mode (continues spray, macro-control spray). The substrate temperature has been kept at 450 °c with the optional user can enter temperature tolerance values ± 5 °C. Also that fixed molar concentration of 0.1 M, and 2D platform speed or deposition platform speed of 4mm/s. more than 1000 instruction program code, and specific design of graphical user interface GUI to fully control the deposition process and real-time monitoring and controlling the deposition temperature at every 200 ms. The changing in the temperature has been recorded during deposition processes, in addition to all deposition parameters. The films have been characterized to evaluate the thermal distribution over the X, Y movable hot plate, the structure and optical energy gap, thermal and temperature distribution exhibited a good and uniform distribution over 20 cm2 hot plate area, X-ray diffraction (XRD) measurement revealed that the films are polycrystalline in nature and can be assigned to monoclinic CuO structure. Optical band gap varies from 1.5-1.66 eV depending on deposition parameter.

Control of thermal deformation in dielectric mirrors using mechanical design and atomic layer deposition.

Science.gov (United States)

Gabriel, Nicholas T; Kim, Sangho S; Talghader, Joseph J

2009-07-01

A mechanical design technique for optical coatings that simultaneously controls thermal deformation and optical reflectivity is reported. The method requires measurement of the refractive index and thermal stress of single films prior to the design. Atomic layer deposition was used for deposition because of the high repeatability of the film constants. An Al2O3/HfO2 distributed Bragg reflector was deposited with a predicted peak reflectivity of 87.9% at 542.4 nm and predicted edge deformation of -360 nm/K on a 10 cm silicon substrate. The measured peak reflectivity was 85.7% at 541.7 nm with an edge deformation of -346 nm/K.

Electrophoretic Deposition of Gallium with High Deposition Rate

Directory of Open Access Journals (Sweden)

Hanfei Zhang

2014-12-01

Full Text Available In this work, electrophoretic deposition (EPD is reported to form gallium thin film with high deposition rate and low cost while avoiding the highly toxic chemicals typically used in electroplating. A maximum deposition rate of ~0.6 μm/min, almost one order of magnitude higher than the typical value reported for electroplating, is obtained when employing a set of proper deposition parameters. The thickness of the film is shown to increase with deposition time when sequential deposition is employed. The concentration of Mg(NO32, the charging salt, is also found to be a critical factor to control the deposition rate. Various gallium micropatterns are obtained by masking the substrate during the process, demonstrating process compatibility with microfabrication. The reported novel approach can potentially be employed in a broad range of applications with Ga as a raw material, including microelectronics, photovoltaic cells, and flexible liquid metal microelectrodes.

Controlling the resistivity gradient in aluminum-doped zinc oxide grown by plasma-enhanced chemical vapor deposition

NARCIS (Netherlands)

Ponomarev, M.; Verheijen, M.A.; Keuning, W.; Sanden, van de M.C.M.; Creatore, M.

2012-01-01

Aluminum-doped ZnO (ZnO:Al) grown by chemical vapor deposition (CVD) generally exhibit a major drawback, i.e., a gradient in resistivity extending over a large range of film thickness. The present contribution addresses the plasma-enhanced CVD deposition of ZnO:Al layers by focusing on the control

Sediment problems in reservoirs. Control of sediment deposits

Energy Technology Data Exchange (ETDEWEB)

Jacobsen, Tom

1997-12-31

When a reservoir is formed on a river, sediment will deposit in the reservoir. Such processes are unfortunate, for instance, for the implementation of hydroelectric energy. This thesis studies the problem of reservoir sedimentation and discusses methods of removing the sediments. Various aspects of reservoir sedimentation are discussed. Anthropogenic impacts seem to greatly affect the erosion processes. Temporal distribution is uneven, mainly because of the very large flood events. A world map showing the Reservoir Capacity: Annual Sediment Inflow ratio for reservoirs with volume equal to 10% of annual inflow has been prepared. The map shows that sedimentation is severe in the western parts of North and South America, eastern, southern and northern Africa, parts of Australia and most of Asia. The development of medium-sized reservoirs is difficult, as they are too large for conventional flushing technique and too small to store the sediment that accumulates during their economic lifetime. A computer model, SSIIM, was used with good results in a case study of two flood drawdown trials in Lake Roxburg, New Zealand. Two techniques have been developed that permits controlled suction of sediment and water into a pipe: the Slotted Pipe Sediment Sluicer (SPSS) and the Saxophone Sediment Sluicer (SSS). The techniques exploit the inflow pattern in through a slot in a pipe. An equation describing this inflow pattern was derived and verified experimentally. The SPSS is fixed near the reservoir bed, and sediment that deposits on top of it is removed in the sluicing process. The SSS sluices sediment from the surface of the sediment deposits. Some technical and economic conditions affecting the economics of sediment removal from reservoirs have been identified and studied. 79 refs., 112 figs., 14 tabs.

Low temperature (< 100 °C) deposited P-type cuprous oxide thin films: Importance of controlled oxygen and deposition energy

International Nuclear Information System (INIS)

Li, Flora M.; Waddingham, Rob; Milne, William I.; Flewitt, Andrew J.; Speakman, Stuart; Dutson, James; Wakeham, Steve; Thwaites, Mike

2011-01-01

With the emergence of transparent electronics, there has been considerable advancement in n-type transparent semiconducting oxide (TSO) materials, such as ZnO, InGaZnO, and InSnO. Comparatively, the availability of p-type TSO materials is more scarce and the available materials are less mature. The development of p-type semiconductors is one of the key technologies needed to push transparent electronics and systems to the next frontier, particularly for implementing p–n junctions for solar cells and p-type transistors for complementary logic/circuits applications. Cuprous oxide (Cu 2 O) is one of the most promising candidates for p-type TSO materials. This paper reports the deposition of Cu 2 O thin films without substrate heating using a high deposition rate reactive sputtering technique, called high target utilisation sputtering (HiTUS). This technique allows independent control of the remote plasma density and the ion energy, thus providing finer control of the film properties and microstructure as well as reducing film stress. The effect of deposition parameters, including oxygen flow rate, plasma power and target power, on the properties of Cu 2 O films are reported. It is known from previously published work that the formation of pure Cu 2 O film is often difficult, due to the more ready formation or co-formation of cupric oxide (CuO). From our investigation, we established two key concurrent criteria needed for attaining Cu 2 O thin films (as opposed to CuO or mixed phase CuO/Cu 2 O films). First, the oxygen flow rate must be kept low to avoid over-oxidation of Cu 2 O to CuO and to ensure a non-oxidised/non-poisoned metallic copper target in the reactive sputtering environment. Secondly, the energy of the sputtered copper species must be kept low as higher reaction energy tends to favour the formation of CuO. The unique design of the HiTUS system enables the provision of a high density of low energy sputtered copper radicals/ions, and when combined with a

Modeling and control of diffusion and low-pressure chemical vapor deposition furnaces

Science.gov (United States)

De Waard, H.; De Koning, W. L.

1990-03-01

In this paper a study is made of the heat transfer inside cylindrical resistance diffusion and low-pressure chemical vapor deposition furnaces, aimed at developing an improved temperature controller. A model of the thermal behavior is derived which also covers the important class of furnaces equipped with semitransparent quartz process tubes. The model takes into account the thermal behavior of the thermocouples. It is shown that currently used temperature controllers are highly inefficient for very large scale integration applications. Based on the model an alternative temperature controller of the linear-quadratic-Gaussian type is proposed which features direct wafer temperature control. Some simulation results are given.

Sensing system for detection and control of deposition on pendant tubes in recovery and power boilers

Science.gov (United States)

Kychakoff, George [Maple Valley, WA; Afromowitz, Martin A [Mercer Island, WA; Hogle, Richard E [Olympia, WA

2008-10-14

A system for detection and control of deposition on pendant tubes in recovery and power boilers includes one or more deposit monitoring sensors operating in infrared regions of about 4 or 8.7 microns and directly producing images of the interior of the boiler, or producing feeding signals to a data processing system for information to enable a distributed control system by which the boilers are operated to operate said boilers more efficiently. The data processing system includes an image pre-processing circuit in which a 2-D image formed by the video data input is captured, and includes a low pass filter for performing noise filtering of said video input. It also includes an image compensation system for array compensation to correct for pixel variation and dead cells, etc., and for correcting geometric distortion. An image segmentation module receives a cleaned image from the image pre-processing circuit for separating the image of the recovery boiler interior into background, pendant tubes, and deposition. It also accomplishes thresholding/clustering on gray scale/texture and makes morphological transforms to smooth regions, and identifies regions by connected components. An image-understanding unit receives a segmented image sent from the image segmentation module and matches derived regions to a 3-D model of said boiler. It derives a 3-D structure the deposition on pendant tubes in the boiler and provides the information about deposits to the plant distributed control system for more efficient operation of the plant pendant tube cleaning and operating systems.

Control of hydrocarbon radicals and film deposition by using an RF Whistler wave discharge

International Nuclear Information System (INIS)

Mieno, Tetsu; Shoji, Tatsuo; Kadota, Kiyoshi.

1991-10-01

Production of hydrocarbon radicals is controlled by using an RF Whistler wave discharge in a low pressure region (∼0.1 Pa). Plasma density of 10 10 - 10 13 cm -3 , electron temperature of 2-20 eV is obtained for the discharge of admixture of Ar and small content of source gases (CH 4 , C 2 H 2 , CO). Spectroscopic measurement indicates that densities of CH and H radicals and deposition rate of amorphous carbon:H film increase with electron density, electron temperature and source gas pressure. The etching effect of H atoms influences on the deposition rate and a high deposition rate (90 μm/hr for CO/Ar discharge) is obtained even in a low neutral pressure discharge. (author)

Microstructural control during direct laser deposition of a β-titanium alloy

International Nuclear Information System (INIS)

Qiu, Chunlei; Ravi, G.A.; Attallah, Moataz M.

2015-01-01

Graphical abstract: Microstructural development of Ti5553 during Direct Laser Deposition (DLD). - Highlights: • Good structural and geometrical integrity could be achieved by process design. • Build height increases with decreased scanning speed and increased powder flow rate. • Keeping Z increment close to actual layer thickness is crucial for consistent building. • The laser deposited Ti5553 are dominated by mixed columnar and equiaxed grains. • In situ dwelling and annealing promote α precipitation which improves microhardness. - Abstract: A concern associated with Direct Laser Deposition (DLD) is the difficulty in controlling microstructure due to rapid cooling rates after deposition, particularly in beta-Ti alloys. In these alloys, the beta-phase is likely to exist following DLD, instead of the desirable duplex alpha + beta microstructure that gives a good balance of properties. Thus, in this work, a parametric study was performed to assess the role of DLD parameters on porosity, build geometry, and microstructure in a beta-Ti alloy, Ti–5Al–5Mo–5V–3Cr (Ti5553). The builds were examined using optical microscopy, scanning electron microscopy, and X-ray diffraction. Microhardness measurements were performed to assess the degree of re-precipitation of alpha-phase following an in situ dwelling and laser annealing procedure. The study identified several processing conditions that enable deposition of samples with the desired geometry and low porosity level. The microstructure was dominated by beta-phase, except for the region near the substrate where a limited amount of alpha-precipitates was present due to reheating effect. Although the microstructure was a mixture of equiaxed and columnar beta-grains alongside infrequent fine alpha-precipitates, the builds showed fairly uniform microhardness in different regions. In situ dwelling and annealing did not cause an obvious change in porosity, but did promote the formation of alpha-precipitates

Spatial control of direct chemical vapor deposition of graphene on silicon dioxide by directional copper dewetting

NARCIS (Netherlands)

van den Beld, Wesley Theodorus Eduardus; van den Berg, Albert; Eijkel, Jan C.T.

2016-01-01

In this paper we present a method for the spatial control of direct graphene synthesis onto silicon dioxide by controlled dewetting. The dewetting process is controlled through a combination of using a grooved substrate and conducting copper deposition at an angle. The substrate is then treated

Electrostatic Deposition of Large-Surface Graphene

Directory of Open Access Journals (Sweden)

Charles Trudeau

2018-01-01

Full Text Available This work describes a method for electrostatic deposition of graphene over a large area using controlled electrostatic exfoliation from a Highly Ordered Pyrolytic Graphite (HOPG block. Deposition over 130 × 130 µm2 with 96% coverage is achieved, which contrasts with sporadic micro-scale depositions of graphene with little control from previous works on electrostatic deposition. The deposition results are studied by Raman micro-spectroscopy and hyperspectral analysis using large fields of view to allow for the characterization of the whole deposition area. Results confirm that laser pre-patterning of the HOPG block prior to cleaving generates anchor points favoring a more homogeneous and defect-free HOPG surface, yielding larger and more uniform graphene depositions. We also demonstrate that a second patterning of the HOPG block just before exfoliation can yield features with precisely controlled geometries.

Direct fabrication of integrated 3D Au nanobox arrays by sidewall deposition with controllable heights and thicknesses

Energy Technology Data Exchange (ETDEWEB)

Cha, Nam-Goo; Lee, Bong Kuk; Kanki, Teruo; Lee, Hea Yeon; Kawai, Tomoji; Tanaka, Hidekazu, E-mail: h-tanaka@sanken.osaka-u.ac.j [Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047 (Japan)

2009-09-30

This paper provides a unique strategy for controlling integrated hollow nanostructure arrays such as boxes or pillars at the nanometer scale. The key merit of this technique is that it can overcome resolution limits by sidewall deposition and deposit various materials using a sputtering method. The sputtering method can be replaced by other dry deposition techniques such as pulsed laser deposition (PLD) for complex functional materials. Furthermore, it can produce low-cost large-area fabrication and high reproducibility using the NIL (nanoimprint lithograph) process. The fabrication method consists of a sequence of bilayer spin-coating, UV-NIL, RIE (reactive ion etching), sputtering, ion milling and piranha cleaning processes. By changing the deposition time and molds, various thicknesses and shapes can be fabricated, respectively. Furthermore, the fabricated Au box nanostructure has a bending zone of the top layer and a {approx}17 nm undercut of the bottom layer as observed by SEM (scanning electron microscope). The sidewall thickness was changed from 12 to 61 nm by controlling the deposition time, and was investigated to understand the relationship with blanket thicknesses and geometric effects. The calculated sidewall thickness matched well with experimental results. Using smaller hole-patterned molds, integrated nanobox arrays, with inner squares measuring {approx}160 nm, and nanopillar arrays, with inside pores measuring {approx}65 nm, were fabricated under the same conditions.

Feedback control of the lower hybrid power deposition profile on Tore Supra

International Nuclear Information System (INIS)

Barana, O; Mazon, D; Laborde, L; Turco, F

2007-01-01

The Tore Supra facility is well suited to study ITER relevant topics such as the real-time control of plasma current and the sustaining of steady-state discharges. This work describes a tool that was recently developed and implemented on Tore Supra to control in real time, by means of the direct knowledge of the suprathermal electron local emission profile, the width of the lower hybrid power deposition profile. This quantity can be considered to some extent equivalent to the width of the plasma current density profile in case of fully non-inductive discharges. This system takes advantage of an accurate hard x-ray diagnostics, of an efficient lower hybrid additional heating and of a reliable real-time communication network. The successful experiments carried out to test the system employed, as actuators, the parallel refractive index n // and the total power P LH . The control of the suprathermal electron local emission profile through n // was also integrated with the feedback control of the total plasma current I P with P LH and of the loop voltage V loop with the central solenoid flux. These results demonstrate that the system is robust, reliable and able to counterbalance destabilizing events. This tool can be effectively used in the future in fully non-inductive discharges to improve the MHD stability and to maintain internal transport barriers or lower hybrid enhanced performance modes. The real-time control of the lower hybrid power deposition profile could also be used in conjunction with the electron-cyclotron radiofrequency heating for synergy studies

Interface control of atomic layer deposited oxide coatings by filtered cathodic arc deposited sublayers for improved corrosion protection

Energy Technology Data Exchange (ETDEWEB)

Härkönen, Emma, E-mail: emma.harkonen@helsinki.fi [Laboratory of Inorganic Chemistry, University of Helsinki, P.O. Box 55, FIN-00014 Helsinki (Finland); Tervakangas, Sanna; Kolehmainen, Jukka [DIARC-Technology Inc., Espoo (Finland); Díaz, Belén; Światowska, Jolanta; Maurice, Vincent; Seyeux, Antoine; Marcus, Philippe [Laboratoire de Physico-Chimie des Surfaces, CNRS (UMR 7075) – Chimie ParisTech (ENSCP), F-75005 Paris (France); Fenker, Martin [FEM Research Institute, Precious Metals and Metals Chemistry, D-73525 Schwäbisch Gmünd (Germany); Tóth, Lajos; Radnóczi, György [Research Centre for Natural Sciences HAS, (MTA TKK), Budapest (Hungary); Ritala, Mikko [Laboratory of Inorganic Chemistry, University of Helsinki, P.O. Box 55, FIN-00014 Helsinki (Finland)

2014-10-15

Sublayers grown with filtered cathodic arc deposition (FCAD) were added under atomic layer deposited (ALD) oxide coatings for interface control and improved corrosion protection of low alloy steel. The FCAD sublayer was either Ta:O or Cr:O–Ta:O nanolaminate, and the ALD layer was Al{sub 2}O{sub 3}–Ta{sub 2}O{sub 5} nanolaminate, Al{sub x}Ta{sub y}O{sub z} mixture or graded mixture. The total thicknesses of the FCAD/ALD duplex coatings were between 65 and 120 nm. Thorough analysis of the coatings was conducted to gain insight into the influence of the FCAD sublayer on the overall coating performance. Similar characteristics as with single FCAD and ALD coatings on steel were found in the morphology and composition of the duplex coatings. However, the FCAD process allowed better control of the interface with the steel by reducing the native oxide and preventing its regrowth during the initial stages of the ALD process. Residual hydrocarbon impurities were buried in the interface between the FCAD layer and steel. This enabled growth of ALD layers with improved electrochemical sealing properties, inhibiting the development of localized corrosion by pitting during immersion in acidic NaCl and enhancing durability in neutral salt spray testing. - Highlights: • Corrosion protection properties of ALD coatings were improved by FCAD sublayers. • The FCAD sublayer enabled control of the coating-substrate interface. • The duplex coatings offered improved sealing properties and durability in NSS. • The protective properties were maintained during immersion in a corrosive solution. • The improvements were due to a more ideal ALD growth on the homogeneous FCAD oxide.

Critical Factors Controlling Pd and Pt Potential in Porphyry Cu–Au Deposits: Evidence from the Balkan Peninsula

Directory of Open Access Journals (Sweden)

Demetrios G. Eliopoulos

2014-03-01

Full Text Available Porphyry Cu–Au–Pd±Pt deposits are significant Au resources, but their Pd and Pt potential is still unknown. Elevated Pd, Pt (hundreds of ppb and Au contents are associated with typical stockwork magnetite-bornite-chalcopyrite assemblages, at the central parts of certain porphyry deposits. Unexpected high grade Cu–(Pd+Pt (up to 6 ppm mineralization with high Pd/Pt ratios at the Elatsite porphyry deposit, which is found in a spatial association with the Chelopech epithermal deposit (Bulgaria and the Skouries porphyry deposit, may have formed during late stages of an evolved hydrothermal system. Estimated Pd, Pt and Au potential for porphyry deposits is consistent with literature model calculations demonstrating the capacity of aqueous vapor and brine to scavenge sufficient quantities of Pt and Pd, and could contribute to the global platinum-group element (PGE production. Critical requirements controlling potential of porphyry deposits may be from the metals contained in magma (metasomatized asthenospheric mantle wedge as indicated by significant Cr, Co, Ni and Re contents. The Cr content may be an indicator for the mantle input.

Controllable chemical vapor deposition of large area uniform nanocrystalline graphene directly on silicon dioxide

DEFF Research Database (Denmark)

Sun, Jie; Lindvall, Niclas; Cole, Matthew T.

2012-01-01

Metal-catalyst-free chemical vapor deposition (CVD) of large area uniform nanocrystalline graphene on oxidized silicon substrates is demonstrated. The material grows slowly, allowing for thickness control down to monolayer graphene. The as-grown thin films are continuous with no observable pinholes...

Nanomanufacturing of titania interfaces with controlled structural and functional properties by supersonic cluster beam deposition

International Nuclear Information System (INIS)

Podestà, Alessandro; Borghi, Francesca; Indrieri, Marco; Bovio, Simone; Piazzoni, Claudio; Milani, Paolo

2015-01-01

Great emphasis is placed on the development of integrated approaches for the synthesis and the characterization of ad hoc nanostructured platforms, to be used as templates with controlled morphology and chemical properties for the investigation of specific phenomena of great relevance in interdisciplinary fields such as biotechnology, medicine, and advanced materials. Here, we discuss the crucial role and the advantages of thin film deposition strategies based on cluster-assembling from supersonic cluster beams. We select cluster-assembled nanostructured titania (ns-TiO 2 ) as a case study to demonstrate that accurate control over morphological parameters can be routinely achieved, and consequently, over several relevant interfacial properties and phenomena, like surface charging in a liquid electrolyte, and proteins and nanoparticles adsorption. In particular, we show that the very good control of nanoscale morphology is obtained by taking advantage of simple scaling laws governing the ballistic deposition regime of low-energy, mass-dispersed clusters with reduced surface mobility

Nanomanufacturing of titania interfaces with controlled structural and functional properties by supersonic cluster beam deposition

Energy Technology Data Exchange (ETDEWEB)

Podestà, Alessandro, E-mail: alessandro.podesta@mi.infn.it, E-mail: pmilani@mi.infn.it; Borghi, Francesca; Indrieri, Marco; Bovio, Simone; Piazzoni, Claudio; Milani, Paolo, E-mail: alessandro.podesta@mi.infn.it, E-mail: pmilani@mi.infn.it [Centro Interdisciplinare Materiali e Interfacce Nanostrutturati (C.I.Ma.I.Na.), Dipartimento di Fisica, Università degli Studi di Milano, via Celoria 16, 20133 Milano (Italy)

2015-12-21

Great emphasis is placed on the development of integrated approaches for the synthesis and the characterization of ad hoc nanostructured platforms, to be used as templates with controlled morphology and chemical properties for the investigation of specific phenomena of great relevance in interdisciplinary fields such as biotechnology, medicine, and advanced materials. Here, we discuss the crucial role and the advantages of thin film deposition strategies based on cluster-assembling from supersonic cluster beams. We select cluster-assembled nanostructured titania (ns-TiO{sub 2}) as a case study to demonstrate that accurate control over morphological parameters can be routinely achieved, and consequently, over several relevant interfacial properties and phenomena, like surface charging in a liquid electrolyte, and proteins and nanoparticles adsorption. In particular, we show that the very good control of nanoscale morphology is obtained by taking advantage of simple scaling laws governing the ballistic deposition regime of low-energy, mass-dispersed clusters with reduced surface mobility.

Nanomanufacturing of titania interfaces with controlled structural and functional properties by supersonic cluster beam deposition

Science.gov (United States)

Podestà, Alessandro; Borghi, Francesca; Indrieri, Marco; Bovio, Simone; Piazzoni, Claudio; Milani, Paolo

2015-12-01

Great emphasis is placed on the development of integrated approaches for the synthesis and the characterization of ad hoc nanostructured platforms, to be used as templates with controlled morphology and chemical properties for the investigation of specific phenomena of great relevance in interdisciplinary fields such as biotechnology, medicine, and advanced materials. Here, we discuss the crucial role and the advantages of thin film deposition strategies based on cluster-assembling from supersonic cluster beams. We select cluster-assembled nanostructured titania (ns-TiO2) as a case study to demonstrate that accurate control over morphological parameters can be routinely achieved, and consequently, over several relevant interfacial properties and phenomena, like surface charging in a liquid electrolyte, and proteins and nanoparticles adsorption. In particular, we show that the very good control of nanoscale morphology is obtained by taking advantage of simple scaling laws governing the ballistic deposition regime of low-energy, mass-dispersed clusters with reduced surface mobility.

Quantification of controls on regional rockfall activity and talus deposition, Kananaskis, Canadian Rockies

Science.gov (United States)

Thapa, Prasamsa; Martin, Yvonne E.; Johnson, E. A.

2017-12-01

Rockfall is a significant geomorphic process in many mountainous regions that also poses a notable natural hazard risk. Most previous studies of rockfall erosion have investigated the mechanics and rates of local rockwall retreat and talus deposition, with only a few investigations of rockfall and/or associated talus considering larger spatial scales (i.e., drainage basin, mountain range). The purpose of the current research is to investigate the areal extent of rockfall-talus and controlling factors of its distribution over regional spatial scales (of order 102 km2) in Kananaskis, Canadian Rockies to inform our understanding of its significance in mountain development. To achieve this goal, a large talus inventory is collected and analyzed for 11 steep tributaries of the Kananaskis River, Canadian Rockies. Talus accumulations associated with rockfall provide evidence about the nature and rates of rockfall activity that supplies sediment to these deposits and are the focus of the present study. To quantify the controls of rockfall-talus activity in this region, we analyze the association of talus deposits with structural geology, glacial topography, and temperature-related weathering (i.e., frost cracking). A total of 324 talus polygons covering a surface area of 28.51 km2 are delineated within the 11 study basins, with the number of talus polygons in each study basin ranging from 1 to 73. Analysis of the talus inventory shows that cirques and glacially sculpted valleys are locations of notable talus accumulation in Kananaskis, with other locations of significant talus deposition being associated with thrust faults. We also found that the upper elevations at which talus deposits are typically found are the general range of elevations experiencing a notable number of days in the frost cracking window when this window is defined as - 3 to - 15 °C; no such association is found for the frost cracking window of - 3 to - 8 °C. Estimates of average erosion rates for all

Local Measurement of Fuel Energy Deposition and Heat Transfer Environment During Fuel Lifetime Using Controlled Calorimetry

International Nuclear Information System (INIS)

Don W. Miller; Andrew Kauffmann; Eric Kreidler; Dongxu Li; Hanying Liu; Daniel Mills; Thomas D. Radcliff; Joseph Talnagi

2001-01-01

A comprehensive description of the accomplishments of the DOE grant titled, ''Local Measurement of Fuel Energy Deposition and Heat Transfer Environment During Fuel Lifetime using Controlled Calorimetry''

Size- and density-controlled deposition of Ag nanoparticle films by a novel low-temperature spray chemical vapour deposition method—research into mechanism, particle growth and optical simulation

Energy Technology Data Exchange (ETDEWEB)

Liu, Yang, E-mail: yang.liu@helmholtz-berlin.de; Plate, Paul, E-mail: paul.plate@helmholtz-berlin.de; Hinrichs, Volker; Köhler, Tristan; Song, Min; Manley, Phillip; Schmid, Martina [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH (Germany); Bartsch, Peter [Beuth Hochschule für Technik Berlin, Fachbereich VIII Maschinenbau, Veranstaltungstechnik, Verfahrenstechnik (Germany); Fiechter, Sebastian; Lux-Steiner, Martha Ch. [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH (Germany); Fischer, Christian-Herbert [Freie Universität Berlin, Institute of Chemistry and Biochemistry (Germany)

2017-04-15

Ag nanoparticles have attracted interest for plasmonic absorption enhancement of solar cells. For this purpose, well-defined particle sizes and densities as well as very low deposition temperatures are required. Thus, we report here a new spray chemical vapour deposition method for producing Ag NP films with independent size and density control at substrate temperatures even below 100 °C, which is much lower than for many other techniques. This method can be used on different substrates to deposit Ag NP films. It is a reproducible, low-cost process which uses trimethylphosphine (hexafluoroacetylacetonato) silver as a precursor in alcoholic solution. By systematic variation of deposition parameters and classic experiments, mechanisms of particle growth and of deposition processes as well as the low decomposition temperature of the precursor could be explained. Using the 3D finite element method, absorption spectra of selected samples were simulated, which fitted well with the measured results. Hence, further applications of such Ag NP films for generating plasmonic near field can be predicted by the simulation.

Size- and density-controlled deposition of Ag nanoparticle films by a novel low-temperature spray chemical vapour deposition method—research into mechanism, particle growth and optical simulation

International Nuclear Information System (INIS)

Liu, Yang; Plate, Paul; Hinrichs, Volker; Köhler, Tristan; Song, Min; Manley, Phillip; Schmid, Martina; Bartsch, Peter; Fiechter, Sebastian; Lux-Steiner, Martha Ch.; Fischer, Christian-Herbert

2017-01-01

Ag nanoparticles have attracted interest for plasmonic absorption enhancement of solar cells. For this purpose, well-defined particle sizes and densities as well as very low deposition temperatures are required. Thus, we report here a new spray chemical vapour deposition method for producing Ag NP films with independent size and density control at substrate temperatures even below 100 °C, which is much lower than for many other techniques. This method can be used on different substrates to deposit Ag NP films. It is a reproducible, low-cost process which uses trimethylphosphine (hexafluoroacetylacetonato) silver as a precursor in alcoholic solution. By systematic variation of deposition parameters and classic experiments, mechanisms of particle growth and of deposition processes as well as the low decomposition temperature of the precursor could be explained. Using the 3D finite element method, absorption spectra of selected samples were simulated, which fitted well with the measured results. Hence, further applications of such Ag NP films for generating plasmonic near field can be predicted by the simulation.

Facies-controlled reservoir properties in ramp-fan and slope-apron deposits, Miocene Puente Formation, Los Angeles basin

Energy Technology Data Exchange (ETDEWEB)

Lyons, K.T.; Geving, R.L.; Suchecki, R.K.

1989-03-01

The Miocene Puente Formation in outcrops of the eastern Los Angeles basin is interpreted as a succession of slope-apron and ramp-fan deposits that accumulated in a prism-rise wedge. The principal depositional components of this dominantly base-of-slope and ramp system are ramp-fan channels and lobes, and slope-channel and slope-apron channel/interchannel deposits. Facies-specific textural, compositional, and diagenetic attributes observed in thin section assist in the classification of depositional facies. Specifically, occurrence of carbonate cement, clay mineralogy, and abundance of organic material vary as a function of component facies architecture of the depositional system. Slope and ramp-fan channel-fill sandstones are characterized by pervasive carbonate cements, including poikilotopic and fine-grained calcite, fine-grained and baroque dolomite, and minor siderite. Diagenetic clays predate carbonate cements, and dolomite predates coarser, void-filling calcite. Ramp-fan lobe and interchannel deposits are carbonate free but are rich in detrital clay and organic matter. Diagenetic clays include mixed-layer illite/smectite and kaolinite. Sediments deposited in slope-apron channel fill are virtually cement free except for small amounts of authigenic illite/smectite. Slope-apron interchannel deposits are characterized by high content of organic matter and clay-rich matrix. Potential reservoir characteristics, such as grain size, sorting, and abundance of depositional clay matrix, are related to the primary sedimentary properties of depositional architectural components in the ramp-fan and slope-apron system. Additional diagenetic modifications, without consideration of compaction, were controlled by precipitation reactions associated with fluid flow along pathways related to the depositional architectural framework.

Closed-Loop Process Control for Electron Beam Freeform Fabrication and Deposition Processes

Science.gov (United States)

Taminger, Karen M. (Inventor); Hafley, Robert A. (Inventor); Martin, Richard E. (Inventor); Hofmeister, William H. (Inventor)

2013-01-01

A closed-loop control method for an electron beam freeform fabrication (EBF(sup 3)) process includes detecting a feature of interest during the process using a sensor(s), continuously evaluating the feature of interest to determine, in real time, a change occurring therein, and automatically modifying control parameters to control the EBF(sup 3) process. An apparatus provides closed-loop control method of the process, and includes an electron gun for generating an electron beam, a wire feeder for feeding a wire toward a substrate, wherein the wire is melted and progressively deposited in layers onto the substrate, a sensor(s), and a host machine. The sensor(s) measure the feature of interest during the process, and the host machine continuously evaluates the feature of interest to determine, in real time, a change occurring therein. The host machine automatically modifies control parameters to the EBF(sup 3) apparatus to control the EBF(sup 3) process in a closed-loop manner.

Laser vapor phase deposition of semiconductors

Energy Technology Data Exchange (ETDEWEB)

Karlov, N.V.; Luk' ianchuk, B.S.; Sisakian, E.V.; Shafeev, G.A.

1987-06-01

The pyrolytic effect of IR laser radiation is investigated with reference to the initiation and control of the vapor phase deposition of semiconductor films. By selecting the gas mixture composition and laser emission parameters, it is possible to control the deposition and crystal formation processes on the surface of semiconductors, with the main control action achieved due to the nonadiabatic kinetics of reactions in the gas phase and high temperatures in the laser heating zone. This control mechanism is demonstrated experimentally during the laser vapor deposition of germanium and silicon films from tetrachlorides on single-crystal Si and Ge substrates. 5 references.

Bayesian fuzzy logic-based estimation of electron cyclotron heating (ECH) power deposition in MHD control systems

Energy Technology Data Exchange (ETDEWEB)

Davoudi, Mehdi, E-mail: mehdi.davoudi@polimi.it [Department of Electrical and Computer Engineering, Buein Zahra Technical University, Buein Zahra, Qazvin (Iran, Islamic Republic of); Davoudi, Mohsen, E-mail: davoudi@eng.ikiu.ac.ir [Department of Electrical Engineering, Imam Khomeini International University, Qazvin, 34148-96818 (Iran, Islamic Republic of)

2017-06-15

Highlights: • A couple of algorithms to diagnose if Electron Cyclotron Heating (ECH) power is deposited properly on the expected deposition minor radius are proposed. • The algorithms are based on Bayesian theory and Fuzzy logic. • The algorithms are tested on the off-line experimental data acquired from Frascati Tokamak Upgrade (FTU), Frascati, Italy. • Uncertainties and evidences derived from the combination of online information formed by the measured diagnostic data and the prior information are also estimated. - Abstract: In the thermonuclear fusion systems, the new plasma control systems use some measured on-line information acquired from different sensors and prior information obtained by predictive plasma models in order to stabilize magnetic hydro dynamics (MHD) activity in a tokamak. Suppression of plasma instabilities is a key issue to improve the confinement time of controlled thermonuclear fusion with tokamaks. This paper proposes a couple of algorithms based on Bayesian theory and Fuzzy logic to diagnose if Electron Cyclotron Heating (ECH) power is deposited properly on the expected deposition minor radius (r{sub DEP}). Both algorithms also estimate uncertainties and evidences derived from the combination of the online information formed by the measured diagnostic data and the prior information. The algorithms have been employed on a set of off-line ECE channels data which have been acquired from the experimental shot number 21364 at Frascati Tokamak Upgrade (FTU), Frascati, Italy.

Stoichiometry control of complex oxides by sequential pulsed-laser deposition from binary-oxide targets

Energy Technology Data Exchange (ETDEWEB)

Herklotz, A. [ORNL, Materials Science and Technology Division, Bethel Valley Road, Oak Ridge, Tennessee 37831-6056 (United States); Martin Luther University Halle-Wittenberg, Institute for Physics, Von-Danckelmann-Platz 3, 06120 Halle (Germany); Dörr, K. [Martin Luther University Halle-Wittenberg, Institute for Physics, Von-Danckelmann-Platz 3, 06120 Halle (Germany); Ward, T. Z.; Eres, G. [ORNL, Materials Science and Technology Division, Bethel Valley Road, Oak Ridge, Tennessee 37831-6056 (United States); Christen, H. M.; Biegalski, M. D. [ORNL, Center for Nanophase Materials Sciences, Bethel Valley Road, Oak Ridge, Tennessee 37831-6496 (United States)

2015-03-30

To have precise atomic layer control over interfaces, we examine the growth of complex oxides through the sequential deposition from binary targets by pulsed laser deposition. In situ reflection high-energy electron diffraction (RHEED) is used to control the growth and achieve films with excellent structural quality. The growth from binary oxide targets is fundamentally different from single target growth modes and shows more similarities to shuttered growth by molecular beam epitaxy. The RHEED intensity oscillations of non-stoichiometric growth are consistent with a model of island growth and accumulation of excess material on the surface that can be utilized to determine the correct stoichiometry for growth. Correct monolayer doses can be determined through an envelope frequency in the RHEED intensity oscillations. In order to demonstrate the ability of this growth technique to create complex heterostructures, the artificial n = 2 and 3 Sr{sub n+1}Ti{sub n}O{sub 3n+1} Ruddlesden-Popper phases are grown with good long-range order. This method enables the precise unit-cell level control over the structure of perovskite-type oxides, and thus the growth of complex materials with improved structural quality and electronic functionality.

Factors Controlling Black Carbon Deposition in Snow in the Arctic

Science.gov (United States)

Qi, L.; Li, Q.; He, C.; Li, Y.

2015-12-01

This study evaluates the sensitivity of black carbon (BC) concentration in snow in the Arctic to BC emissions, dry deposition and wet scavenging efficiency using a 3D global chemical transport model GEOS-Chem driven by meteorological field GEOS-5. With all improvements, simulated median BC concentration in snow agrees with observation (19.2 ng g-1) within 10%, down from -40% in the default GEOS-Chem. When the previously missed gas flaring emissions (mainly located in Russia) are included, the total BC emission in the Arctic increases by 70%. The simulated BC in snow increases by 1-7 ng g-1, with the largest improvement in Russia. The discrepancy of median BC in snow in the whole Arctic reduces from -40% to -20%. In addition, recent measurements of BC dry deposition velocity suggest that the constant deposition velocity of 0.03 cm s-1 over snow and ice used in the GEOS-Chem is too low. So we apply resistance-in-series method to calculate the dry deposition velocity over snow and ice and the resulted dry deposition velocity ranges from 0.03 to 0.24 cm s-1. However, the simulated total BC deposition flux in the Arctic and BC in snow does not change, because the increased dry deposition flux has been compensated by decreased wet deposition flux. However, the fraction of dry deposition to total deposition increases from 16% to 25%. This may affect the mixing of BC and snow particles and further affect the radative forcing of BC deposited in snow. Finally, we reduced the scavenging efficiency of BC in mixed-phase clouds to account for the effect of Wegener-Bergeron-Findeisen (WBF) process based on recent observations. The simulated BC concentration in snow increases by 10-100%, with the largest increase in Greenland (100%), Tromsø (50%), Alaska (40%), and Canadian Arctic (30%). Annual BC loading in the Arctic increases from 0.25 to 0.43 mg m-2 and the lifetime of BC increases from 9.2 to 16.3 days. This indicates that BC simulation in the Arctic is really sensitive to

Distribution of soil selenium in China is potentially controlled by deposition and volatilization?

Science.gov (United States)

Sun, Guo-Xin; Meharg, Andrew A.; Li, Gang; Chen, Zheng; Yang, Lei; Chen, Song-Can; Zhu, Yong-Guan

2016-02-01

Elucidating the environmental drivers of selenium (Se) spatial distribution in soils at a continental scale is essential to better understand it’s biogeochemical cycling to improve Se transfer into diets. Through modelling Se biogeochemistry in China we found that deposition and volatilization are key factors controlling distribution in surface soil, rather than bedrock-derived Se (balance in other terrestrial environments worldwide.

Characterization and temperature controlling property of TiAlN coatings deposited by reactive magnetron co-sputtering

International Nuclear Information System (INIS)

Chen, J.T.; Wang, J.; Zhang, F.; Zhang, G.A.; Fan, X.Y.; Wu, Z.G.; Yan, P.X.

2009-01-01

Titanium aluminum nitride (TiAlN) ternary coating is a potential material which is expected to be applied on satellite for thermal controlling. In order to investigate thermal controlling property, TiAlN coatings were deposited on Si wafers with different N 2 and Ar flux ratio by reactive magnetron co-sputtering. The structure, morphology, chemical composition and optical reflectance are investigated by X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM), atom force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and spectrophotometer, respectively. The orientation of the coatings depends on the N 2 /Ar flux ratio. The coatings deposited with N 2 /Ar ratio of 10, 30 and 60% show the cubic-TiN [2 2 0] preferred orientation and the coating deposited with N 2 /Ar ratio of 100% exhibits the phase of hexagonal-AlN and cubic-TiN. The surface of the coatings becomes more compact and smoother with the N 2 /Ar ratios increase. XPS spectrum indicates that the oxides (TiO 2 and Al 2 O 3 ), oxynitride (TiN x O y ) and nitrides (TiN and AlN x ) appear at the surface of the coatings. Ignoring internal power, the optimum equilibrium temperature of TiAlN coatings is 18 deg. C and the equilibrium temperature after heat-treated has slight change, which provides the prospective application on thermal controlling

Interaction of tectonic and depositional processes that control the evolution of the Iberian Gulf of Cadiz margin

Science.gov (United States)

Maldonado, A.; Nelson, C.H.

1999-01-01

This study provides an integrated view of the growth patterns and factors that controlled the evolution of the Gulf of Cadiz continental margin based on studies of the tectonic, sedimentologic and oceanographic history of the area. Seven sedimentary regimes are identified, but there are more extensive descriptions of the late Cenozoic regimes because of the larger data base. The regimes of the Mesozoic passive margin include carbonate platforms, which become mixed calcareous-terrigenous deposits during the Late Cretaceous-early Tertiary. The Oligocene and Early Miocene terrigenous regimes developed, in contrast, over the active and transcurrent margins near the African-Iberian plate boundary. The top of the Gulf of Cadiz olistostrome, emplaced in the Late Miocene, is used as a key horizon to define the 'post-orogenic' depositional regimes. The Late Miocene progradational margin regime is characterized by a large terrigenous sediment supply to the margin and coincides with the closing of the Miocene Atlantic-Mediterranean gateways. The terrigenous drift depositional regime of the Early Pliocene resulted from the occurrence of high eustatic sea level and the characteristics of the Mediterranean outflow currents that developed after the opening of the Strait of Gibraltar. The Late Pliocene and Quaternary regimes are dominated by sequences of deposits related to cycles of high and low sea levels. Deposition of shelf-margin deltas and slope wedges correlate with regressive and low sea level regimes caused by eustasy and subsidence. During the highstand regimes of the Holocene, inner shelf prograding deltas and deep-water sediment drifts were developed under the influence of the Atlantic inflow and Mediterranean outflow currents, respectively. A modern human cultural regime began 2000 years ago with the Roman occupation of Iberia; human cultural effects on sedimentary regimes may have equalled natural factors such as climate change. Interplay of tectonic and

Topographic controls on pyroclastic density current dynamics: Insight from 18 May 1980 deposits at Mount St. Helens, Washington (USA)

Science.gov (United States)

Brand, Brittany D.; Bendaña, Sylvana; Self, Stephen; Pollock, Nicholas

2016-07-01

Our ability to interpret the deposits of pyroclastic density currents (PDCs) is critical for understanding the transport and depositional processes that control PDC dynamics. This paper focuses on the influence of slope on flow dynamics and criticality as recorded in PDC deposits from the 18 May 1980 eruption of Mt. St. Helens (USA). PDC deposits are found along the steep flanks (10°-30°) and across the pumice plain ( 5°) up to 8 km north of the volcano. Granulometry, componentry and descriptions of depositional characteristics (e.g., bedform morphology) are recorded with distance from source. The pumice plain deposits are primarily thick (3-12 m), massive and poorly-sorted, and represent deposition from a series of concentrated PDCs. By contrast, the steep flank deposits are stratified to cross-stratified, suggesting deposition from PDCs where turbulence strongly influenced transport and depositional processes. We propose that acceleration of the concentrated PDCs along the steep flanks resulted in thinning of the concentrated, basal region of the current(s). Enhanced entrainment of ambient air, and autofluidization from upward fluxes of air from substrate interstices and plunging breakers across rugged, irregular topography further inflated the currents to the point that the overriding turbulent region strongly influenced transport and depositional mechanisms. Acceleration in combination with partial confinement in slot canyons and high surface roughness would also increase basal shear stress, further promoting shear and traction transport in the basal region of the current. Conditions along the steep flank resulted in supercritical flow, as recorded by regressive bedforms, which gradually transitioned to subcritical flow downstream as the concentrated basal region thickness increased as a function of decreasing slope and flow energy. We also find that (1) PDCs were erosive into the underlying granular substrate along high slopes (> 25°) where currents were

Large Area Deposition of MoS2 by Pulsed Laser Deposition with In-Situ Thickness Control

KAUST Repository

Serna, Martha I.

2016-05-24

A scalable and catalyst-free method to deposit stoichiometric Molybdenum Disulfide (MoS2) films over large areas is reported with the maximum area limited by the size of the substrate holder. The method allows deposition of MoS2 layers on a wide range of substrates without any additional surface preparation including single crystals (sapphire and quartz), polycrystalline (HfO2), and amorphous (SiO2). The films are deposited using carefully designed MoS2 targets fabricated with excess of sulfur (S) and variable MoS2 and S particle size. Uniform and layered MoS2 films as thin as two monolayers, with an electrical resistivity of 1.54 × 104 Ω cm-1 were achieved. The MoS2 stoichiometry was as confirmed by High Resolution Rutherford Backscattering Spectrometry (HRRBS). With the method reported here, in situ graded MoS2 films ranging from ~1 to 10 monolayers can also be deposited.

Large Area Deposition of MoS2 by Pulsed Laser Deposition with In-Situ Thickness Control

KAUST Repository

Serna, Martha I.; Yoo, Seong H.; Moreno, Salvador; Xi, Yang; Oviedo, Juan Pablo; Choi, Hyunjoo; Alshareef, Husam N.; Kim, Moon J.; Minary-Jolandan, Majid; Quevedo-Lopez, Manuel A.

2016-01-01

A scalable and catalyst-free method to deposit stoichiometric Molybdenum Disulfide (MoS2) films over large areas is reported with the maximum area limited by the size of the substrate holder. The method allows deposition of MoS2 layers on a wide range of substrates without any additional surface preparation including single crystals (sapphire and quartz), polycrystalline (HfO2), and amorphous (SiO2). The films are deposited using carefully designed MoS2 targets fabricated with excess of sulfur (S) and variable MoS2 and S particle size. Uniform and layered MoS2 films as thin as two monolayers, with an electrical resistivity of 1.54 × 104 Ω cm-1 were achieved. The MoS2 stoichiometry was as confirmed by High Resolution Rutherford Backscattering Spectrometry (HRRBS). With the method reported here, in situ graded MoS2 films ranging from ~1 to 10 monolayers can also be deposited.

Microstructural control over soluble pentacene deposited by capillary pen printing for organic electronics.

Science.gov (United States)

Lee, Wi Hyoung; Min, Honggi; Park, Namwoo; Lee, Junghwi; Seo, Eunsuk; Kang, Boseok; Cho, Kilwon; Lee, Hwa Sung

2013-08-28

Research into printing techniques has received special attention for the commercialization of cost-efficient organic electronics. Here, we have developed a capillary pen printing technique to realize a large-area pattern array of organic transistors and systematically investigated self-organization behavior of printed soluble organic semiconductor ink. The capillary pen-printed deposits of organic semiconductor, 6,13-bis(triisopropylsilylethynyl) pentacene (TIPS_PEN), was well-optimized in terms of morphological and microstructural properties by using ink with mixed solvents of chlorobenzene (CB) and 1,2-dichlorobenzene (DCB). Especially, a 1:1 solvent ratio results in the best transistor performances. This result is attributed to the unique evaporation characteristics of the TIPS_PEN deposits where fast evaporation of CB induces a morphological evolution at the initial printed position, and the remaining DCB with slow evaporation rate offers a favorable crystal evolution at the pinned position. Finally, a large-area transistor array was facilely fabricated by drawing organic electrodes and active layers with a versatile capillary pen. Our approach provides an efficient printing technique for fabricating large-area arrays of organic electronics and further suggests a methodology to enhance their performances by microstructural control of the printed organic semiconducting deposits.

Deposition of SrTiO3 films by electrophoresis with thickness and particle size control

International Nuclear Information System (INIS)

Junior, W.D.M.; Pena, A.F.V.; Souza, A.E.; Santos, G.T.A.; Teixeira, S.R.; Senos, A.M.R.; Longo, E.

2012-01-01

The SrTiO3 (ST) is a material that exhibits semiconducting characteristics and interesting electrical properties. In room temperature has a structure of high cubic symmetry. The size of the crystallites of this material directly influences this symmetry, changing its network parameters. ST nanoparticles are obtained by hydrothermal method assisted by microwave (MAH). ST films are prepared by electrophoretic deposition (EPD). Approximately 1 g of the powder is dissolved in 100 ml of acetone and 1.5 ml of triethanolamine. The stainless steel substrates are arranged horizontally in the solution. The depositions are performed for 1-10 min and subjected to a potential difference of 20-100 V. The films were characterized by x-ray diffraction (XRD) and atomic force microscopy (AFM). The characterizations show that it is possible to control both the thickness and size of the crystallites of the film depending on the deposition parameters adopted. (author)

Photo-sensitive Ge nanocrystal based films controlled by substrate deposition temperature

KAUST Repository

Stavarache, Ionel

2017-07-21

Lowering the temperature of crystallization by deposition of thin films on a heated substrate represents the easiest way to find new means to develop and improve new working devices based on nanocrystals embedded in thin films. The improvements are strongly related with the increasing of operation speed, substantially decreasing the energy consumption and reducing unit fabrication costs of the respective semiconductor devices. This approach avoids major problems, such as those related to diffusion or difficulties in controlling of nanocrystallites size, which appear during thermal treatments at high temperatures after deposition. It is reported here the significant progress introduced by synthesis procedure to the in-situ structuring of Ge nanocrystallites in SiO₂ thin films by heating the substrate at low temperature, 400 °C during co-deposition of Ge and SiO₂ by magnetron sputtering. As a proof-of-concept, a Si/Ge-NCs:SiO₂ photo-sensitive structure was fabricated thereof and characterized. The structure shows superior performance on broad operation bandwidth from visible to near-infrared, as strong rectification properties in dark, significant current rise in the inversion mode when illuminated, high responsivity, high photo-detectivity of 10¹⁴ Jones, quick response and significant conversion efficiency of 850 %. This simple preparation approach brings an important contribution to the efort of structuring Ge nanocrystallites in SiO₂ thin films at a lower temperature for the purpose of using these materials for devices in optoelectronics, solar cells and electronics on flexible substrates.

Photo-sensitive Ge nanocrystal based films controlled by substrate deposition temperature

Science.gov (United States)

Stavarache, Ionel; Maraloiu, Valentin Adrian; Negrila, Catalin; Prepelita, Petronela; Gruia, Ion; Iordache, Gheorghe

2017-10-01

Lowering the temperature of crystallization by deposition of thin films on a heated substrate represents the easiest way to find new means to develop and improve new working devices based on nanocrystals embedded in thin films. The improvements are strongly related with the increasing of operation speed, substantially decreasing the energy consumption and reducing unit fabrication costs of the respective semiconductor devices. This approach avoids major problems, such as those related to diffusion or difficulties in controlling nanocrystallites size, which appear during thermal treatments at high temperatures after deposition. This article reports on a significant progress given by structuring Ge nanocrystals (Ge-NCs) embedded in silicon dioxide (SiO2) thin films by heating the substrate at 400 °C during co-deposition of Ge and SiO2 by magnetron sputtering. As a proof-of-concept, a Si/Ge-NCs:SiO2 photo-sensitive structure was fabricated thereof and characterized. The structure shows superior performance on broad operation bandwidth from visible to near-infrared, as strong rectification properties in dark, significant current rise in the inversion mode when illuminated, high responsivity, high photo-detectivity of 1014 Jones, quick response and significant conversion efficiency with peak value reaching 850% at -1 V and about 1000 nm. This simple preparation approach brings an important contribution to the effort of structuring Ge nanocrystallites in SiO2 thin films at a lower temperature for the purpose of using these materials for devices in optoelectronics, solar cells and electronics on flexible substrates.

Acid Deposition Phenomena

International Nuclear Information System (INIS)

Ramadan, A.E.K.

2004-01-01

Acid deposition, commonly known as acid rain, occurs when emissions from the combustion of fossil fuels and other industrial processes undergo complex chemical reactions in the atmosphere and fall to the earth as wet deposition (rain, snow, cloud, fog) or dry deposition (dry particles, gas). Rain and snow are already naturally acidic, but are only considered problematic when less than a ph of 5.0 The main chemical precursors leading to acidic conditions are atmospheric concentrations of sulfur dioxide (SO 2 ) and nitrogen oxides (NO x ). When these two compounds react with water, oxygen, and sunlight in the atmosphere, the result is sulfuric (H 2 SO 4 ) and nitric acids (HNO 3 ), the primary agents of acid deposition which mainly produced from the combustion of fossil fuel and from petroleum refinery. Airborne chemicals can travel long distances from their sources and can therefore affect ecosystems over broad regional scales and in locations far from the sources of emissions. According to the concern of petroleum ministry with the environment and occupational health, in this paper we will discussed the acid deposition phenomena through the following: Types of acidic deposition and its components in the atmosphere Natural and man-made sources of compounds causing the acidic deposition. Chemical reactions causing the acidic deposition phenomenon in the atmosphere. Factors affecting level of acidic deposition in the atmosphere. Impact of acid deposition. Procedures for acidic deposition control in petroleum industry

Characterization and temperature controlling property of TiAlN coatings deposited by reactive magnetron co-sputtering

Energy Technology Data Exchange (ETDEWEB)

Chen, J.T. [School of Physical Science and Technology, Lanzhou University, Lanzhou 730000 (China); Wang, J. [School of Physical Science and Technology, Lanzhou University, Lanzhou 730000 (China); National Key Laboratory of Surface Engineering, Lanzhou Institute of Physics, Lanzhou 730000 (China); Zhang, F.; Zhang, G.A.; Fan, X.Y.; Wu, Z.G. [School of Physical Science and Technology, Lanzhou University, Lanzhou 730000 (China); Yan, P.X. [School of Physical Science and Technology, Lanzhou University, Lanzhou 730000 (China); State Key Laboratory of Solid Lubrication, Lanzhou Institute Chemical and Physics, Chinese Academy of Sciences, Lanzhou 730000 (China)], E-mail: pxyan@lzu.edu.cn

2009-03-20

Titanium aluminum nitride (TiAlN) ternary coating is a potential material which is expected to be applied on satellite for thermal controlling. In order to investigate thermal controlling property, TiAlN coatings were deposited on Si wafers with different N{sub 2} and Ar flux ratio by reactive magnetron co-sputtering. The structure, morphology, chemical composition and optical reflectance are investigated by X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM), atom force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and spectrophotometer, respectively. The orientation of the coatings depends on the N{sub 2}/Ar flux ratio. The coatings deposited with N{sub 2}/Ar ratio of 10, 30 and 60% show the cubic-TiN [2 2 0] preferred orientation and the coating deposited with N{sub 2}/Ar ratio of 100% exhibits the phase of hexagonal-AlN and cubic-TiN. The surface of the coatings becomes more compact and smoother with the N{sub 2}/Ar ratios increase. XPS spectrum indicates that the oxides (TiO{sub 2} and Al{sub 2}O{sub 3}), oxynitride (TiN{sub x}O{sub y}) and nitrides (TiN and AlN{sub x}) appear at the surface of the coatings. Ignoring internal power, the optimum equilibrium temperature of TiAlN coatings is 18 deg. C and the equilibrium temperature after heat-treated has slight change, which provides the prospective application on thermal controlling.

The Neogene molasse deposits of the Zagros Mountains in central Dezful Embayment: facies, sedimentary environments and controls

Directory of Open Access Journals (Sweden)

Ali Hossein Jalilian

2016-03-01

Full Text Available The upper part of Neogene sequence of the Zagros Mountains consists of a clastic succession which is identified as Aghajari and Bakhtyari formations. The sequence is an excellent example of synorogenic sedimentation or molasse deposited in northern portion of the Zagros foreland basin. Sedimentological analysis of an outcrop section representing Miocene-Pliocene sediments in central Dezful Embayment resulted in recognizing 9 lithofacies and 4 architectural elements. These lithofacies include conglometate (Gt, Gh, Gmm, sandstone (Sp, Sh, Sr, St and mudstone (Fm, Fl that were deposited in meandering stream, braided river and alluvial fan environments. Paleocurrent analysis of cross-beds, channels and asymmetric ripple marks indicate that these Neogene clastics were mainly drived from Cretaceous to Paleogene highlands in the Zagros Mountains on the north. This stratigraphic record is coarsening-upward and formed by a regressive depositional megacycle under arid climate. Facies and depositional history analysis show that sedimentation of the Zagros molasse was primarily controlled by base-level changes rather than catchment lithology or climate. The sedimentary record of this regressive megacycle reveales the base-level was constantly falling down on one hand and the provenance was uplifting on the other hand. Tectonic activities and Zagros Mountains rising in the Late Miocene resulted in deposition of fining-upward point-bar and floodplain sequences of the Aghajari Formation in low-gradient meandering streams. The Lahbari Member of the Aghajari Formation represents deposition in braided rivers that composed predominantly of flood-plain deposits in the Early Pliocene. Finally, the sedimentary cycle of the Zagros molasse deposits terminated with massive conglomerates of the Bakhtyari Formation deposited in large alluvial fans near the source area.

Controlled surface diffusion in plasma-enhanced chemical vapor deposition of GaN nanowires

International Nuclear Information System (INIS)

Hou, W C; Hong, Franklin Chau-Nan

2009-01-01

This study investigates the growth of GaN nanowires by controlling the surface diffusion of Ga species on sapphire in a plasma-enhanced chemical vapor deposition (CVD) system. Under nitrogen-rich growth conditions, Ga has a tendency to adsorb on the substrate surface diffusing to nanowires to contribute to their growth. The significance of surface diffusion on the growth of nanowires is dependent on the environment of the nanowire on the substrate surface as well as the gas phase species and compositions. Under nitrogen-rich growth conditions, the growth rate is strongly dependent on the surface diffusion of gallium, but the addition of 5% hydrogen in nitrogen plasma instantly diminishes the surface diffusion effect. Gallium desorbs easily from the surface by reaction with hydrogen. On the other hand, under gallium-rich growth conditions, nanowire growth is shown to be dominated by the gas phase deposition, with negligible contribution from surface diffusion. This is the first study reporting the inhibition of surface diffusion effects by hydrogen addition, which can be useful in tailoring the growth and characteristics of nanowires. Without any evidence of direct deposition on the nanowire surface, gallium and nitrogen are shown to dissolve into the catalyst for growing the nanowires at 900 deg. C.

Laboratory Deposition Apparatus to Study the Effects of Wax Deposition on Pipe Magnetic Field Leakage Signals

Directory of Open Access Journals (Sweden)

Karim Mohd Fauzi Abd

2014-07-01

Full Text Available Accurate technique for wax deposition detection and severity measurement on cold pipe wall is important for pipeline cleaning program. Usually these techniques are validated by conventional techniques on laboratory scale wax deposition flow loop. However conventional techniques inherent limitations and it is difficult to reproduce a predetermine wax deposit profile and hardness at designated location in flow loop. An alternative wax deposition system which integrates modified pour casting method and cold finger method is presented. This system is suitable to reproduce high volume of medium hard wax deposit in pipe with better control of wax deposit profile and hardness.

Morphology control in thin films of PS:PLA homopolymer blends by dip-coating deposition

Energy Technology Data Exchange (ETDEWEB)

Vital, Alexane [Interfaces, Confinement, Matériaux et Nanostructures (ICMN), CNRS-Université d’Orléans, UMR 7374, 1B Rue de la Férollerie, C.S. 40059, 45071 Orléans Cedex 2 (France); Groupe de recherches sur l’énergétique des milieux ionisés (GREMI), CNRS-Université d’Orléans, UMR 7344, 14 rue d' Issoudun, B.P. 6744, F45067 Orléans Cedex 2 (France); Vayer, Marylène [Interfaces, Confinement, Matériaux et Nanostructures (ICMN), CNRS-Université d’Orléans, UMR 7374, 1B Rue de la Férollerie, C.S. 40059, 45071 Orléans Cedex 2 (France); Tillocher, Thomas; Dussart, Rémi [Groupe de recherches sur l’énergétique des milieux ionisés (GREMI), CNRS-Université d’Orléans, UMR 7344, 14 rue d' Issoudun, B.P. 6744, F45067 Orléans Cedex 2 (France); Boufnichel, Mohamed [STMicroelectronics, 16, rue Pierre et Marie Curie, B.P. 7155, 37071 Tours Cedex 2 (France); and others

2017-01-30

Highlights: • A process to control the morphology of polymer blends thin film is described. • It is based on the use of dip-coating at various withdrawal speeds. • The process is examined within the capillary and the draining regimes. • The final dried morphology is controlled by the regime of deposition. • This study is of high interest for the preparation of advanced functional surfaces. - Abstract: In this work, smooth polymer films of PS, PLA and their blends, with thicknesses ranging from 20 nm up to 400 nm and very few defects on the surface were obtained by dip-coating. In contrast to the process of spin-coating which is conventionally used to prepare thin films of polymer blends, we showed that depending on the deposition parameters (withdrawal speed and geometry of the reservoir), various morphologies such as layered films and laterally phase-separated domains could be formed for a given blend/solvent pair, offering much more opportunities compared to the spin-coating process. This diversity of morphologies was explained by considering the superposition of different phenomena such as phase separation process, dewetting and vitrification in which parameters such as the drying time, the compatibility of the polymer/solvent pairs and the affinity of the polymer towards the interfaces were suspected to play a significant role. For that purpose, the process of dip-coating was examined within the capillary and the draining regimes (for low and high withdrawal speed respectively) in order to get a full description of the thickness variation and evaporation rate as a function of the deposition parameters.

MAPLE deposition of nanomaterials

International Nuclear Information System (INIS)

Caricato, A.P.; Arima, V.; Catalano, M.; Cesaria, M.; Cozzoli, P.D.; Martino, M.; Taurino, A.; Rella, R.; Scarfiello, R.; Tunno, T.; Zacheo, A.

2014-01-01

The matrix-assisted pulsed laser evaporation (MAPLE) has been recently exploited for depositing films of nanomaterials by combining the advantages of colloidal inorganic nanoparticles and laser-based techniques. MAPLE-deposition of nanomaterials meeting applicative purposes demands their peculiar properties to be taken into account while planning depositions to guarantee a congruent transfer (in terms of crystal structure and geometric features) and explain the deposition outcome. In particular, since nanofluids can enhance thermal conductivity with respect to conventional fluids, laser-induced heating can induce different ablation thermal regimes as compared to the MAPLE-treatment of soft materials. Moreover, nanoparticles exhibit lower melting temperatures and can experience pre-melting phenomena as compared to their bulk counterparts, which could easily induce shape and or crystal phase modification of the material to be deposited even at very low fluences. In this complex scenario, this review paper focuses on examples of MAPLE-depositions of size and shape controlled nanoparticles for different applications highlights advantages and challenges of the MAPLE-technique. The influence of the deposition parameters on the physical mechanisms which govern the deposition process is discussed.

MAPLE deposition of nanomaterials

Energy Technology Data Exchange (ETDEWEB)

Caricato, A.P., E-mail: annapaola.caricato@le.infn.it [Department of Mathematics and Physics “E. De Giorgi”, University of Salento, Via Arnesano, I-73100 Lecce (Italy); Arima, V.; Catalano, M. [National Nanotechnology Laboratory (NNL), CNR Istituto Nanoscienze, c/o Distretto Tecnologico, Via Arnesano n. 16, I-73100 Lecce (Italy); Cesaria, M. [Department of Mathematics and Physics “E. De Giorgi”, University of Salento, Via Arnesano, I-73100 Lecce (Italy); Cozzoli, P.D. [Department of Mathematics and Physics “E. De Giorgi”, University of Salento, Via Arnesano, I-73100 Lecce (Italy); National Nanotechnology Laboratory (NNL), CNR Istituto Nanoscienze, c/o Distretto Tecnologico, Via Arnesano n. 16, I-73100 Lecce (Italy); Martino, M. [Department of Mathematics and Physics “E. De Giorgi”, University of Salento, Via Arnesano, I-73100 Lecce (Italy); Taurino, A.; Rella, R. [Institute for Microelectronics and Microsystems, IMM-CNR, Via Monteroni, I-73100 Lecce (Italy); Scarfiello, R. [National Nanotechnology Laboratory (NNL), CNR Istituto Nanoscienze, c/o Distretto Tecnologico, Via Arnesano n. 16, I-73100 Lecce (Italy); Tunno, T. [Department of Mathematics and Physics “E. De Giorgi”, University of Salento, Via Arnesano, I-73100 Lecce (Italy); Zacheo, A. [Department of Mathematics and Physics “E. De Giorgi”, University of Salento, Via Arnesano, I-73100 Lecce (Italy); National Nanotechnology Laboratory (NNL), CNR Istituto Nanoscienze, c/o Distretto Tecnologico, Via Arnesano n. 16, I-73100 Lecce (Italy)

2014-05-01

The matrix-assisted pulsed laser evaporation (MAPLE) has been recently exploited for depositing films of nanomaterials by combining the advantages of colloidal inorganic nanoparticles and laser-based techniques. MAPLE-deposition of nanomaterials meeting applicative purposes demands their peculiar properties to be taken into account while planning depositions to guarantee a congruent transfer (in terms of crystal structure and geometric features) and explain the deposition outcome. In particular, since nanofluids can enhance thermal conductivity with respect to conventional fluids, laser-induced heating can induce different ablation thermal regimes as compared to the MAPLE-treatment of soft materials. Moreover, nanoparticles exhibit lower melting temperatures and can experience pre-melting phenomena as compared to their bulk counterparts, which could easily induce shape and or crystal phase modification of the material to be deposited even at very low fluences. In this complex scenario, this review paper focuses on examples of MAPLE-depositions of size and shape controlled nanoparticles for different applications highlights advantages and challenges of the MAPLE-technique. The influence of the deposition parameters on the physical mechanisms which govern the deposition process is discussed.

Uniform deposition of uranium hexafluoride (UF6): Standardized mass deposits and controlled isotopic ratios using a thermal fluorination method

Energy Technology Data Exchange (ETDEWEB)

McNamara, Bruce K.; O’Hara, Matthew J.; Casella, Andrew M.; Carter, Jennifer C.; Addleman, R. Shane; MacFarlan, Paul J.

2016-07-01

Abstract: We report a convenient method for the generation of volatile uranium hexafluoride (UF6) from solid uranium oxides and other uranium compounds, followed by uniform deposition of low levels of UF6 onto sampling coupons. Under laminar flow conditions, UF6 is shown to interact with surfaces within the chamber to a highly predictable degree. We demonstrate the preparation of uranium deposits that range between ~0.01 and 470±34 ng∙cm-2. The data suggest the method can be extended to creating depositions at the sub-picogram∙cm-2 level. Additionally, the isotopic composition of the deposits can be customized by selection of the uranium source materials. We demonstrate a layering technique whereby two uranium solids, each with a different isotopic composition, are employed to form successive layers of UF6 on a surface. The result is an ultra-thin deposit of UF6 that bears an isotopic signature that is a composite of the two uranium sources. The reported deposition method has direct application to the development of unique analytical standards for nuclear safeguards and forensics.

The fate of eroded soil organic carbon along a European transect – controls after deposition in terrestrial and aquatic systems

DEFF Research Database (Denmark)

Kirkels, Frédérique; Cammeraat, Erik; Kalbitz, Karsten

that the turnover of deposited C is significantly affected by soil and organic matter properties, and whether deposition occurs in terrestrial or aquatic environments. We sampled topsoils from 10 agricultural sites along a European transect, spanning a wide range of SOC and soil characteristics (e.g. texture......The potential fate of eroded soil organic carbon (SOC) after deposition is key to understand carbon cycling in eroding landscapes. Globally, large quantities of sediments and SOC are redistributed by soil erosion on agricul-tural land, particularly after heavy precipitation events. Deposition......, aggregation, C content, etc.). Turnover of SOC was determined for terrestrial and aquatic depositional conditions in a 10-week incubation study. Moreover, we studied the impact of labile carbon inputs (‘priming’) on SOC stability using 13C labelled cellulose. We evaluated potentially important controls...

A chemical bath deposition route to facet-controlled Ag{sub 3}PO{sub 4} thin films with improved visible light photocatalytic activity

Energy Technology Data Exchange (ETDEWEB)

Gunjakar, Jayavant L.; Jo, Yun Kyung; Kim, In Young; Lee, Jang Mee; Patil, Sharad B. [Department of Chemistry and Nanoscience, College of Natural Sciences, Ewha Womans University, Seoul 03760 (Korea, Republic of); Pyun, Jae-Chul [Department of Materials Science and Engineering, College of Engineering, Yonsei University, Seoul (Korea, Republic of); Hwang, Seong-Ju, E-mail: hwangsju@ewha.ac.kr [Department of Chemistry and Nanoscience, College of Natural Sciences, Ewha Womans University, Seoul 03760 (Korea, Republic of)

2016-08-15

A facile, economic, and reproducible chemical bath deposition (CBD) method is developed for the fabrication of facet-controlled Ag{sub 3}PO{sub 4} thin films with enhanced visible light photocatalytic activity. The fine-control of bath temperature, precursor, complexing agent, substrate, and solution pH is fairly crucial in preparing the facet-selective thin film of Ag{sub 3}PO{sub 4} nanocrystal. The change of precursor from silver nitrate to silver acetate makes possible the tailoring of the crystal shape of Ag{sub 3}PO{sub 4} from cube to rhombic dodecahedron and also the bandgap tuning of the deposited films. The control of [Ag{sup +}]/[phosphate] ratio enables to maximize the loading amount of Ag{sub 3}PO{sub 4} crystals per the unit area of the deposited film. All the fabricated Ag{sub 3}PO{sub 4} thin films show high photocatalytic activity for visible light-induced degradation of organic molecules, which can be optimized by tailoring the crystal shape of the deposited crystals. This CBD method is also useful in preparing the facet-controlled hybrid film of Ag{sub 3}PO{sub 4}–ZnO photocatalyst. The present study clearly demonstrates the usefulness of the present CBD method for fabricating facet-controlled thin films of metal oxosalt and its nanohybrid. - Highlights: • The crystal facet of Ag{sub 3}PO{sub 4} films can be tuned by chemical bath deposition. • The crystal shape of Ag{sub 3}PO{sub 4} is tailorable from cube to rhombic dodecahedron. • Facet-tuned Ag{sub 3}PO{sub 4} film shows enhanced visible light photocatalyst activity.

Adhesion Strength of Biomass Ash Deposits

DEFF Research Database (Denmark)

Laxminarayan, Yashasvi; Jensen, Peter Arendt; Wu, Hao

2016-01-01

. Therefore, timely removal of ash deposits is essential for optimal boiler operation. In order to improve the qualitative and quantitative understanding of deposit shedding in boilers, this study investigates the shear adhesion strength of biomass ash deposits on superheater tubes. Artificial biomass ash...... deposits were prepared on superheater tubes and sintered in an oven at temperatures up to 1000 °C. Subsequently, the deposits were sheared off by an electrically controlled arm, and the corresponding adhesion strength was measured. The results reveal the effect of temperature, ash/deposit composition......, sintering duration, and steel type on the adhesion strength....

Reducing tube bundle deposition with alternative amines

International Nuclear Information System (INIS)

Turner, C.W.; Klimas, S.J.; Frattini, P.L.

1998-01-01

Particle deposition rates have been measured in a high-temperature loop for magnetite and hematite depositing onto Inconel-600 under flow-boiling conditions with pH controlled using one of the following amines: morpholine, ammonia, ethanolamine, or dimethylamine. Hematite particles deposited at rates an order of magnitude greater than those measured for magnetite, although the hematite deposition rate dropped when the loop was operated under reducing conditions. The magnetite deposition rate was influenced by the amine used to control the pH, with the relative rate decreasing in the following series: morpholine (1) : ethanolamine (0.72) ammonia (0.51) : dimethylamine (0.25). These trends in deposition rate are discussed in terms of the surface chemistry of the corrosion products. Deposition rates for both magnetite and hematite increased significantly once the mixture quality exceeded about 0.3, which may be related to a change in the heat transfer mechanism from nucleate boiling to two-phase forced convection through a thin film. (author)

Reducing tube bundle deposition using alternative amines

International Nuclear Information System (INIS)

Turner, C.W.; Klimas, S.J.; Frattini, P.L.

1999-07-01

Particle deposition rates were measured in a high-temperature loop for magnetite and hematite depositing onto Inconel-600 under flow-boiling conditions with pH controlled, using one of the following amines: morpholine, ammonia, ethanolamine, or dimethylamine. Hematite particles deposited at rates 10 times greater than those measured for magnetite although the hematite deposition rate dropped when the loop was operated under reducing conditions. The magnetite deposition rate was influenced by the amine used to control the pH, with the relative rate decreasing in the following series: morpholine (1) : ethanolamine (0.72) : ammonia (0.51) dimethylamine (0.25). These trends in deposition rate are discussed in terms of the surface chemistry of the corrosion products. Deposition rates for both magnetite and hematite increased significantly once the mixture quality exceeded about 0.3, which may be related to a change in the heat-transfer mechanism from nucleate boiling to 2-phase forced-convection through a thin film. (author)

Improvement of deposition efficiency and control of hardness for cold-sprayed coatings using high carbon steel/mild steel mixture powder

International Nuclear Information System (INIS)

Ogawa, Kazuhiro; Amao, Satoshi; Yokoyama, Nobuyuki; Ootaki, Kousuke

2011-01-01

In this study, in order to make high carbon steel coating by cold spray technique, spray conditions such as carrier gas temperature and pressure etc. were investigated. And also, in order to improve deposition efficiency and control coating hardness of cold-sprayed high carbon steel, high carbon and mild steel mixed powder and its mechanical milled powder were developed and were optimized. By using the cold-spray technique, particle deposition of a high carbon steel was successful. Moreover, by applying mixed and mechanical milled powders, the porosity ratio was decreased and deposition efficiency was improved. Furthermore, using these powders, it is possible to control the hardness value. Especially, when using mechanical milled powder, it is very difficult to identify the interface between the coating and the substrate. The bonding between the coating and the substrate is thus considered to be excellent. (author)

Uniform deposition of uranium hexafluoride (UF6): Standardized mass deposits and controlled isotopic ratios using a thermal fluorination method.

Science.gov (United States)

McNamara, Bruce K; O'Hara, Matthew J; Casella, Andrew M; Carter, Jennifer C; Addleman, R Shane; MacFarlan, Paul J

2016-07-01

We report a convenient method for the generation of volatile uranium hexafluoride (UF6) from solid uranium oxides and other U compounds, followed by uniform deposition of low levels of UF6 onto sampling coupons. Under laminar flow conditions, UF6 is shown to interact with surfaces within a fixed reactor geometry to a highly predictable degree. We demonstrate the preparation of U deposits that range between approximately 0.01 and 500ngcm(-2). The data suggest the method can be extended to creating depositions at the sub-picogramcm(-2) level. The isotopic composition of the deposits can be customized by selection of the U source materials and we demonstrate a layering technique whereby two U solids, each with a different isotopic composition, are employed to form successive layers of UF6 on a surface. The result is an ultra-thin deposit that bears an isotopic signature that is a composite of the two U sources. The reported deposition method has direct application to the development of unique analytical standards for nuclear safeguards and forensics. Further, the method allows access to very low atomic or molecular coverages of surfaces. Copyright © 2016 Elsevier B.V. All rights reserved.

The influence of organic acids in relation to acid deposition in controlling the acidity of soil and stream waters on a seasonal basis

International Nuclear Information System (INIS)

Chapman, Pippa J.; Clark, Joanna M.; Reynolds, Brian; Adamson, John K.

2008-01-01

Much uncertainty still exists regarding the relative importance of organic acids in relation to acid deposition in controlling the acidity of soil and surface waters. This paper contributes to this debate by presenting analysis of seasonal variations in atmospheric deposition, soil solution and stream water chemistry for two UK headwater catchments with contrasting soils. Acid neutralising capacity (ANC), dissolved organic carbon (DOC) concentrations and the Na:Cl ratio of soil and stream waters displayed strong seasonal patterns with little seasonal variation observed in soil water pH. These patterns, plus the strong relationships between ANC, Cl and DOC, suggest that cation exchange and seasonal changes in the production of DOC and seasalt deposition are driving a shift in the proportion of acidity attributable to strong acid anions, from atmospheric deposition, during winter to predominantly organic acids in summer. - Seasonal variations in soil solution ANC is controlled by seasonal variations in seasalt deposition and production of dissolved organic acids

Understanding the spectrum of diesel injector deposits

Energy Technology Data Exchange (ETDEWEB)

Quigley, Robert; Barbour, Robert [Lubrizol Limited, Derby (United Kingdom); Arters, David; Bush, Jim [Lubrizol Corporation, Wickliffe, OH (United States)

2013-06-01

Understanding the origin of diesel fuel injector deposits used to be relatively simple; for the most part they were caused by the decomposition of fuel during the combustion process, were generally organic in nature and typically only affected the nozzle orifices. However, modem fuel injector designs appear to be both more severe in terms of generating conditions conducive to creating new and different types of deposits and more likely to have their operation affected by those deposits. Changes to fuel composition and type have in some cases increased the potential pool of reactive species or provided new potential deposit precursors. As a result, the universe of diesel injector deposits now range from the traditional organic to partially or fully inorganic in nature and from nozzle coking deposits to deposits which can seize the internal components of the injector; so called internal diesel injector deposits. Frequently, combinations of inorganic and organic deposits are found. While power loss is one well known issue associated with nozzle deposits, other field problems resulting from these new deposits include severe issues with drivability, emissions, fuel consumption and even engine failure. Conventional deposit control additive chemistries were developed to be effective against organic nozzle coking deposits. These conventional additives in many cases may prove ineffective against this wide range of deposit types. This paper discusses the range of deposits that have been found to adversely impact modem diesel fuel injectors and compares the performance of conventional and new, advanced deposit control additives against these various challenges to proper fuel injector functioning. (orig.)

Atomic layer deposition of HfO2 on graphene through controlled ion beam treatment

International Nuclear Information System (INIS)

Kim, Ki Seok; Oh, Il-Kwon; Jung, Hanearl; Kim, Hyungjun; Yeom, Geun Young; Kim, Kyong Nam

2016-01-01

The polymer residue generated during the graphene transfer process to the substrate tends to cause problems (e.g., a decrease in electron mobility, unwanted doping, and non-uniform deposition of the dielectric material). In this study, by using a controllable low-energy Ar + ion beam, we cleaned the polymer residue without damaging the graphene network. HfO 2 grown by atomic layer deposition on graphene cleaned using an Ar + ion beam showed a dense uniform structure, whereas that grown on the transferred graphene (before Ar + ion cleaning) showed a non-uniform structure. A graphene–HfO 2 –metal capacitor fabricated by growing 20-nm thick HfO 2 on graphene exhibited a very low leakage current (<10 −11 A/cm 2 ) for Ar + ion-cleaned graphene, whereas a similar capacitor grown using the transferred graphene showed high leakage current.

Finding a solution to internal diesel injector deposits

Energy Technology Data Exchange (ETDEWEB)

Barbour, Robert; Quigley, Robert; Panesar, Avtar; Payne, James [Lubrizol Limited, Derby (United Kingdom); Arters, David; Bush, Jim; Stevens, Andrew [Lubrizol Corporation, Wickliffe, OH (United States)

2013-06-01

Internal diesel injector deposits (IDIDs) have caused widespread problems in the automotive industry since around 2005. Modem injectors that have been precisely engineered to operate highly controlled injection strategies are experiencing problems in the field due to deposits that have formed on their critical moving parts, such as the needle and control valve. Problems range from rough idling to a failure to start, when the moving parts become stuck. Early studies showed that the composition of these deposits is variable. In some cases the deposit contained noticeable amounts of sodium carboxylate; these are now generally referred to as 'sodium soaps'. In other incidences the dominant chemical functionality observed was an amide group, and hence these deposits are referred to as 'amide lacquers'. A combination of both types has been observed in many cases and other metals, like calcium, have also been detected. Further studies have shown that the sodium soap type can be formed from specific types of corrosion inhibitors. The source of the amide lacquers is less certain, but there are indications that they originate from specific fuel additives that contain critical levels of low molecular weight species. This paper broadly explores this area of high interest. It will report results on the analysis of deposits and the conditions needed to reproduce both types of IDID in bench engine testing. It will also investigate the types of contaminants that are likely to form IDIDs and explore difference in chemical structure that can lead to pro-fouling, non-fouling and anti-fouling behaviour. It will then show that a deposit control additive, specifically designed to control nozzle tip deposits in modem direct injection diesels, is equally effective in controlling IDIDs; both in terms of prevention and removal. Since IDIDS are formed from multiple sources, some of which are difficult to control in today' s market, the use of a broadly acting fuel

Nanodot deposition and its application with atomic force microscope

Energy Technology Data Exchange (ETDEWEB)

Liu Zenglei, E-mail: liuzenglei@sia.cn; Jiao Niandong, E-mail: ndjiao@sia.cn [Chinese Academy of Sciences, State Key Laboratory of Robotics, Shenyang Institute of Automation (China); Xu Ke [Shenyang Jianzhu University (China); Wang, Zhidong [Chiba Institute of Technology (Japan); Dong Zaili; Liu Lianqing [Chinese Academy of Sciences, State Key Laboratory of Robotics, Shenyang Institute of Automation (China)

2013-06-15

Nanodot deposition using atomic force microscope (AFM) is investigated. To realize repeatable and precise deposition of nanodots, the detailed control method is discussed. The electric field between AFM tip and substrate is analyzed, and a convenient method to control tip-substrate separation is proposed. In experiments, two nanodot matrixes are fabricated and the heights of the nanodots are analyzed. Experimental results testify that the control method can lead to repeatable and precise fabrication of deposited nanodots. As an application of deposited nanodots, a carbon nanotube (CNT) is soldered on gold electrodes with deposited Au nanodots. After soldering, the contact resistances between the CNT and the electrodes decrease greatly. AFM-based nanodot deposition can be used to fabricate special nanopatterns; also it can be used to solder nanomaterials on substrates to improve the electrical connection, which has a promising future for nanodevice fabrication.

Reaction kinetics of metal deposition via surface limited red-ox replacement of underpotentially deposited metal monolayers

International Nuclear Information System (INIS)

Gokcen, Dincer; Bae, Sang-Eun; Brankovic, Stanko R.

2011-01-01

The study of the kinetics of metal deposition via surface limited red-ox replacement of underpotentially deposited metal monolayers is presented. The model system was Pt submonolayer deposition on Au(1 1 1) via red-ox replacement of Pb and Cu UPD monolayers on Au(1 1 1). The kinetics of a single replacement reaction was studied using the formalism of the comprehensive analytical model developed to fit the open circuit potential transients from deposition experiments. The practical reaction kinetics parameters like reaction half life, reaction order and reaction rate constant are determined and discussed with their relevance to design and control of deposition experiments. The effects of transport limitation and the role of the anions/electrolyte on deposition kinetics are investigated and their significance to design of effective deposition process is discussed.

The study on the characteristic of Shuangqiao fault and the ore-control action of it in Daqiaowu deposit

International Nuclear Information System (INIS)

Han Xiaozhong; Hui Xiaochao; Wang Mingtai; Liu Rongrong; Liu Quan; Tang Jiangwei; Jin Miaozhang

2012-01-01

Shuangqiao fault is the most important one to control uranium ore bodies in Daqiaowu district of Quzhou area, Zhejiang province, but there is the obvious argument about the attitude which results in the restriction of the U- prognosis in the area. It aims at finding out the movement and ore-control action of the fault by the study on the characteristic of geometry and kinematics. and combining with geophysics in the depth. The Shuangqiao fault's trend is SE instead of NW by researching, and it has the polygenetic movement. There are two obvious stages of tension about the Shuangqiao fault which tally with the two stages of mineralization in Daqiaowu deposit to show the controlled action to ore bodies by it. By the study in-depth, the Shuangqiao fault can lead the metallogenic hydrothermal, and the secondary faults which connect with it can store the ore bodies. The point that the hanging side of fault can control the ore bodies is put forward by making a synthesis of tectonic assembled form and ore-control factors in Daqiaowu deposit. This view is approved by exploration to provide the reference for disposition of uranium prospecting. (authors)

Controlled planar interface synthesis by ultrahigh vacuum diffusion bonding/deposition

International Nuclear Information System (INIS)

Kim, M. J.; Carpenter, R. W.; Cox, M. J.; Xu, J.

2000-01-01

An ultrahigh vacuum (UHV) diffusion bonding/deposition instrument was designed and constructed, which can produce homophase and heterophase planar interfaces from a wide array of materials. The interfaces are synthesized in situ by diffusion bonding of two substrates with or without various interfacial layers, at temperatures up to about 1500 degree sign C. Substrate surfaces can be heat treated, ion-beam sputter cleaned, and chemically characterized in situ by Auger electron spectroscopy prior to deposition and/or bonding. Bicrystals can be synthesized by bonding two single-crystal substrates at a specified orientation. Interfacial layers can be deposited by electron beam evaporation and/or sputter deposition in any layered or alloyed combination on the substrates before bonding. The instrument can accommodate cylindrical and/or wafer type specimens whose sizes are sufficient for fracture mechanical testing to measure interface bond strength. A variety of planar interfaces of metals, semiconductors, and ceramics were synthesized. Examples of bonded stainless steel/Ti/stainless steel, Si/Si, and sapphire/sapphire interfaces are presented. (c) 2000 Materials Research Society

The relationship between depositional system and ore-formation of sandstone-type uranium deposits in Dongsheng area, Ordos basin

International Nuclear Information System (INIS)

Zhao Honggang; Ou Guangxi

2006-01-01

The analysis on depositional system plays a very important role in studying sandstone-type uranium deposits. Based on depositional system analysis and sequence stratigraphy, and through the study of depositional system characteristics and the spatial distribution of sedimentary facies, the evolution of sedimentary environments as well as the sequence stratigraphy of Zhiluo Formation in Dongsheng area, Ordos basin, authors have come to the following conclusions, (1) the spatial distribution of sand bodies is controlled by the planar distribution of sedimentary facies, which, in turn, affects the spatial distribution of ore-hosting sand bodies; (2) the evolution of sedimentary facies and sedimentary environments creates good lithofacies and lithological conditions favorable for interlayer oxidation; (3) the spatial lithologic combination of 'three layer structure' is controlled by sedimentary sequence. (authors)

Nuclear criticality safety controls for uranium deposits during D and D at the Oak Ridge Gaseous Diffusion Plant

International Nuclear Information System (INIS)

Haire, M.J.; Jordan, W.C.; Jollay, L.J. III; Dahl, T.L.

1997-01-01

The US Department of Energy (DOE) Deputy Assistant Secretary of Energy for Environmental Management has issued a challenge to complete DOE environmental cleanup within a decade. The response for Oak Ridge facilities is in accordance with the DOE ten-year plan which calls for completion of > 95% of environmental management work by the year 2006. This will result in a 99% risk reduction and in a significant savings in base line costs in waste management (legacy waste); remedial action (groundwater, soil, etc.); and decontamination and decommissioning (D and D). It is assumed that there will be long-term institutional control of cascade equipment, i.e., there will be no walk away from sites, and that there will be firm radioactivity release limits by 1999 for recycle metals. An integral part of these plants is the removal of uranium deposits which pose nuclear criticality safety concerns in the shut down of the Oak Ridge Gaseous Diffusion Plant. DOE has initiated the Nuclear Criticality Stabilization Program to improve nuclear criticality safety by removing the larger uranium deposits from unfavorable geometry equipment. Nondestructive assay (NDA) measurements have identified the location of these deposits. The objective of the K-25 Site Nuclear Criticality Stabilization Program is to remove and place uranium deposits into safe geometry storage containers to meet the double contingency principle. Each step of the removal process results in safer conditions where multiple controls are present. Upon completion of the Program, nuclear criticality risks will be greatly reduced

Studying and controlling order within nanoparticle monolayers fabricated through electrophoretic deposition

Science.gov (United States)

Krejci, Alexander J.

Just as ensembles of ordered atoms (a crystal) exhibit collective properties which give rise to phenomena that do not exist for a single atom, the same is true of NP ensembles; ordered arrays of NPs (supercrystals) exhibit properties that are not observed in individual NPs. These collective properties open the door for even more applications for nanomaterials. A few examples that demonstrate this fact will be discussed. In the first example, photoluminescent (PL) optical properties of three CdSe NP systems were studied: one ordered array of NPs, one unordered array, and one system of isolated NPs. In these three systems, the ordered array showed a significantly sharper PL peak compared to the unordered array and the individual NPs. In a second example, the electrical properties for three systems of Ag NPs were studied: one hexagonally packed 2D array of Ag NPs, one cubically packed 2D array, and one individual NP. I-V curves of each system were measured and produced dramatically different behaviors simply due to the change in arrangement of NPs. In a final example, arrays of Ag NPs were created and then sintered. By sintering ordered arrays, it was possible to create large monocrystals of silver; monocrystals could not be created using unordered arrays. These are just three examples that elucidate the control over a wide range of properties that can be achieved by tuning the order within NP ensembles. Given the potential of films composed of ordered NP arrays, many researchers have been investigating how to create and control such arrays using a variety of techniques. For example, ligand-mediated assembly is being studied using a variety of ligands. DNA ligands, in particular, offer a powerful way to control NP assemblies. Evaporative self-assembly has been used to create large supercrystals of one, two, and even more types/sizes of NPs. Assisted assembly incorporating electric and/or magnetic fields has shown promise in creating ordered NP arrays. Spin-casting and

Peat-accumulating depositional systems of Sarawak, East Malaysia

Science.gov (United States)

Staub, James R.; Esterle, Joan S.

1994-02-01

Many coal deposits originate in deltaic, estuarine, and coastal plain settings and a knowledge of interrelationships between the tectonic and depositional elements active at the time of sediment deposition is necessary to formulate basin scale models. The prograding coastal depositional systems of Sarawak all contain domed peat-accumulating environments in which low-ash, low-sulfur peats are being deposited in areas of active clastic siliciclastic sedimentation. These depositional systems are as large as 11,400 km 2 and individual peat deposits within systems are in excess of 20 m thick and 1000 km 2 in area. The geographic positions and drainage basin areas of each depositional system are controlled by fault and fold systems. Although prograding into the same receiving basin, individual system geomorphology is variable and ranges from a wave-dominated microtidal delta, to a wave-dominated meso- to macro-tidal delta/coastal plain system, to a tide-dominated macrotidal estuarine embayment along a 450 km stretch of coastline. System variation is a function of sediment supply, shelf and embayment geometry, wave climate, and tidal range. These factors, which control depositional system geomorphology, also control the resulting long axis orientation of the thick, domed peat deposits. The surface vegetation and internal characteristics of most domed peat deposits, however, are similar. Internal characteristics consist of basal high-ash, high-sulfur, degraded peats overlain by low-ash, low-sulfur, well preserved peats in vertical profile. These systems demonstrate variable responses to late Pleistocene/Holocene sea-level rise and, in these instances, the variation is most attributable to local differences in siliciclastic sediment supply, which is a function of the drainage basin area.

Surficial uranium deposits in Algeria

International Nuclear Information System (INIS)

Mokaddem, M.; Fuchs, Y.

1984-01-01

Along southern border of the Hoggar (Algeria) Precambrian shield, Lower Palaeozoic sediments lie unconformably on weathered metamorphic rocks. Along the eastern border of the Tin Seririne basin some good examples of the weathered rocks underneath the unconformity are exposed. The palaeosurface is a peneplain with only minor topographical reliefs from one to a few metres high. The nature and intensity of the weathering process was controlled by the topography, and the existence of badly drained areas is particularly important. At one such area the Tahaggart uranium ore deposit was discovered. The uranium ore consists mainly of torbernite and autunite. The deposit is present in the weathered gneiss underneath the palaeosurface. Mineralogical and geochemical observations indicated that the ore deposit was formed during the period of weathering which was controlled by climatological and palaeotopographical factors. (author)

Controlled deposition and utilization of carbon on Ni-YSZ anodes of SOFCs operating on dry methane

International Nuclear Information System (INIS)

Jiao, Yong; Zhang, Liqin; An, Wenting; Zhou, Wei; Sha, Yujing; Shao, Zongping; Bai, Jianping; Li, Si-Dian

2016-01-01

Solid oxide fuel cells (SOFCs) are promising power-generation systems to utilize methane or methane-based fuels with a high energy efficiency and low environmental impact. A successive multi-stage process is performed to explore the operation of cells using dry methane or the deposited carbon from methane decomposition as fuel. Stable operation can be maintained by optimizing the fuel supply and current density parameters. An electrochemical impedance analysis suggests that the partial oxidization of Ni can occur at anodes when the carbon fuel is consumed. The stability of cells operated on pure methane is investigated in three operating modes. The cell can run in a comparatively stable state with continuous power output in an intermittent methane supply mode, where the deposition and utilization of carbon is controlled by balancing the fuel supply and consumption. The increase in the polarization resistance of the cell might originate from the small amount of NiO and residual carbon at the anode, which can be removed via an oxidation-and-reduction maintenance process. Based on the above strategy, this work provides an alternative operating mode to improve the stability of direct methane SOFCs and demonstrates the feasibility of its application. - Highlights: • A new strategy to control the deposition and utilization of carbon was developed. • A stable fuel cell operation was obtained with an intermittent fuel supply mode. • Polarization resistance increased due to small amount of NiO and residual carbon.

Acid deposition in the northern hemisphere

Energy Technology Data Exchange (ETDEWEB)

Longhurst, J.W.S.; Green, S.E.; Lee, D.S.

1987-02-01

Examines the phenomenon of acid deposition: the distribution and magnitude of sources and its actual and potential direct and indirect effects on soils, forests and other vegetation; wildlife, freshwaters, materials and health. The wide range of technological and other controls that are available to reduce the emissions of pollutants contributing to the phenomenon is also examined and includes pre-combustion control of pollutants, removal during combustion and post-combustion control. Also considered are political responses to acidification, acid deposition monitoring in the United Kingdom and the treatment of acidified areas.

Factors controlling alkali salt deposition in recovery boilers - particle formation and deposition; Soodakattilan likaantuminen ja siihen vaikuttavien tekijoeiden hallinta - hiukkasten muodostuminen ja depositio

Energy Technology Data Exchange (ETDEWEB)

Kauppinen, E.I.; Mikkanen, P.; Ylaetalo, S. [VTT Chemistry, Espoo (Finland); Jokiniemi, J.K.; Lyyraenen, J.; Pyykoenen, J.; Saastamoinen, J. [VTT Energy, Espoo (Finland)

1996-12-01

In this project, the aim was to find out those critical factors that control the deposit formation in the recovery boilers. We focus on the particle formation, growth and deposition as well as the single black liquor particle combustion behaviour. The final goal is the development of the predictive model to be used to describe deposit growth and subsequent behaviour as well as the dependence of deposition on black liquor characteristics and boiler operation conditions. During year 1995 an experimental study on the aerosol particle formation within the recovery boiler furnace and a sensitivity study with the Aerosol Behaviour in Combustion (ABC) code were carried out. The experimental study confirmed the fact that the particles are already formed in the recovery boiler furnace. The particle formation is initiated in the boundary layer of the burning droplet or smelt bed, where metals are vaporised and oxidised to form tiny seed particles. Trace amounts of metals were measured in all particle sizes and the sensitivity study with the ABC model gave further evidence of the seed formation was necessary primary step in the particle formation. At the furnace outlet the sintration ratio and the sulfation ratio of the particles were dependent on the furnace temperature and the residence time in the furnace. At ESP inlet three types of particles were observed (1) fine particles with the major mass mode at about 1-2 {mu}m, (2) large agglomerates in sizes larger than 8 {mu}m, and (3) spherical particles about 2-4 {mu}m in size. The fine particles were formed from vapours and the large agglomerates were formed from fine particles agglomerated on heat exchanger surfaces and re-entrained back to flue gas flow. The large agglomerates also contain vapours that have directly condensed to surfaces. The large spherical particles contain silicon and pass the process almost unchanged. (Abstract Truncated)

An Advanced Electrospinning Method of Fabricating Nanofibrous Patterned Architectures with Controlled Deposition and Desired Alignment

Science.gov (United States)

Rasel, Sheikh Md

We introduce a versatile advanced method of electrospinning for fabricating various kinds of nanofibrous patterns along with desired alignment, controlled amount of deposition and locally variable density into the architectures. In this method, we employed multiple electrodes whose potentials have been altered in milliseconds with the help of microprocessor based control system. Therefore, key success of this method was that the electrical field as well as charge carrying fibers could be switched shortly from one electrode's location to another, as a result, electrospun fibers could be deposited on the designated areas with desired alignment. A wide range of nanofibrous patterned architectures were constructed using proper arrangement of multiple electrodes. By controlling the concurrent activation time of two adjacent electrodes, we demonstrated that amount of fibers going into the pattern can be adjusted and desired alignment in electrospun fibers can be obtained. We also revealed that the deposition density of electrospun fibers in different areas of patterned architectures can be varied. We showed that by controlling the deposition time between two adjacent electrodes, a number of functionally graded patterns can be generated with uniaxial alignment. We also demonstrated that this handy method was capable of producing random, aligned, and multidirectional nanofibrous mats by engaging a number of electrodes and switching them in desired patterns. A comprehensive study using finite element method was carried out to understand the effects of electrical field. Simulation results revealed that electrical field strength alters shortly based on electrode control switch patterns. Nanofibrous polyvinyl alcohol (PVA) scaffolds and its composite reinforced with wollastonite and wood flour were fabricated using rotating drum electrospinning technique. Morphological, mechanical, and thermal, properties were characterized on PVA/wollastonite and PVA/wood flour nanocomposites

Basement and climate controls on proximal depositional systems in continental settings

NARCIS (Netherlands)

Ventra, D.

2011-01-01

This doctoral dissertation discusses the sedimentology and dynamics of selected, modern and ancient clastic depositional systems (alluvial fans and colluvial aprons) at continental basin margins. The focus on single depositional systems gave the opportunity to devote particular attention to

Low-temperature plasma-enhanced atomic layer deposition of 2-D MoS2 : Large area, thickness control and tuneable morphology

NARCIS (Netherlands)

Sharma, A.; Verheijen, M.A.; Wu, L.; Karwal, S.; Vandalon, V.; Knoops, H.C.M.; Sundaram, R.S.; Hofmann, J.P.; Kessels, W.M.M.; Bol, A.A.

2018-01-01

Low-temperature controllable synthesis of monolayer-to-multilayer thick MoS2 with tuneable morphology is demonstrated by using plasma enhanced atomic layer deposition (PEALD). The characteristic self-limiting ALD growth with a growth-per-cycle of 0.1 nm per cycle and digital thickness control down

Block Copolymer Patterns as Templates for the Electrocatalyzed Deposition of Nanostructures on Electrodes and for the Generation of Surfaces of Controlled Wettability.

Science.gov (United States)

Chandaluri, Chanchayya Gupta; Pelossof, Gilad; Tel-Vered, Ran; Shenhar, Roy; Willner, Itamar

2016-01-20

ITO electrodes modified with a nanopatterned film of polystyrene-block-poly(2-vinylpyridine), PS-b-P2VP, where the P2VP domains are quaternized with iodomethane, are used for selective deposition of redox-active materials. Electrochemical studies (cyclic voltammetry, Faradaic impedance measurements) indicate that the PS domains insulate the conductive surface toward redox labels in solution. In turn, the quaternized P2VP domains electrostatically attract negatively charged redox labels solubilized in the electrolyte solution, resulting in an effective electron transfer between the electrode and the redox label. This phenomenon is implemented for the selective deposition of the electroactive Prussian blue on the nanopatterned surface and for the electrochemical deposition of Au nanoparticles, modified with a monolayer of p-aminothiophenol/2-mercaptoethanesulfonic acid, on the quaternized P2VP domains. The patterned Prussian blue-modified surface enables controlling the wettability properties by the content of the electrochemically deposited Prussian blue. Controlled wettability is unattainable with the homopolymer-modified surface, attesting to the role of the nanopattern.

Ultra-small platinum and gold nanoparticles by arc plasma deposition

International Nuclear Information System (INIS)

Kim, Sang Hoon; Jeong, Young Eun; Ha, Heonphil; Byun, Ji Young; Kim, Young Dok

2014-01-01

Highlights: • Ultra-small (<2 nm) and bigger platinum and gold nanoparticles were produced by arc plasma deposition (APD). • Size and coverage of deposited nanoparticles were easily controlled with APD parameters. • Crystalline structures of deposited nanoparticles emerged only when the particle size was bigger than ∼2 nm. - Abstract: Ultra-small (<2 nm) nanoparticles of platinum and gold were produced by arc plasma deposition (APD) in a systematic way and the deposition behavior was studied. Nanoparticles were deposited on two dimensional amorphous carbon and amorphous titania thin films and characterized by transmission electron microscopy (TEM). Deposition behavior of nanoparticles by APD was studied with discharge voltage (V), discharge condenser capacitance (C), and the number of plasma pulse shots (n) as controllable parameters. The average size of intrinsic nanoparticles generated by APD process was as small as 0.9 nm and deposited nanoparticles began to have crystal structures from the particle size of about 2 nm. V was the most sensitive parameter to control the size and coverage of generated nanoparticles compared to C and n. Size of APD deposited nanoparticles was also influenced by the nature of evaporating materials and substrates

In-flight monitoring of particle deposition in the environmental control systems of commercial airliners in China

Science.gov (United States)

Cao, Qing; Xu, Qiuyu; Liu, Wei; Lin, Chao-Hsin; Wei, Daniel; Baughcum, Steven; Norris, Sharon; Chen, Qingyan

2017-04-01

Severe air pollution and low on-time performance of commercial flights in China could increase particle deposition in the environmental control systems (ECSs) of commercial airliners. The particles deposited in the ECSs could negatively affect the performance of the airplanes. In addition, particles that penetrate into the aircraft cabin could adversely impact the health of passengers and crew members. This investigation conducted simultaneous measurements of particle mass concentration and size distribution inside and outside the cabin during 64 commercial flights of Boeing 737 and Airbus 320 aircraft departing from or arriving at Tianjin Airport in China. The results showed that the PM2.5 mass concentration deposition in the ECSs of these airplanes ranged from 50% to 90%, which was much higher than that measured in an airplane with a ground air-conditioning unit. The average deposition rates of particles with diameters of 0.5-1 μm, 1-2 μm, 2-5 μm, 5-10 μm, and >10 μm were 89 ± 8%, 85 ± 13%, 80 ± 13%, 73 ± 15%, and 80 ± 14%, respectively. The in-flight measurement results indicated that the particle concentration in the breathing zone was higher than that in the air-supply zone, which implies a significant contribution by particles in the interior of the cabin. Such particles come from human emissions or particle resuspension from interior surfaces.

Ore-controlling mechanism of carbonaceous-siliceous-pelitic rock type uranium deposits with down-faulted red basins in the southeast continental margin of Yangtze plate

International Nuclear Information System (INIS)

Zhang Zilong; Qi Fucheng; He Zhongbo; Li Zhixing; Wang Wenquan; Yu Jinshui

2012-01-01

One of the important ore-concentrated areas of carbonaceous-siliceous-pelitic rock type uranium deposits is the Southeast continental margin of Yangtze plate. Sedimentary-exogenously transformed type and sedimentary- hydrothermal superimposed transformed type uranium deposits are always distributed at or near the edge of down-faulted red ba sins. In this paper, the distributions of the deposits are analyzed with the relation to down-faulted red basins. The connective effect and ore-controlling mechanism are proposed of carbonaceous-siliceous-pelitic rock type uranium deposits with marginal fractures of red basins. (authors)

Radiometric control for P/sub 2/O/sub 5/ content in Polpinsky are deposit phosphorites

Energy Technology Data Exchange (ETDEWEB)

Belyakov, M A; Berenshtein, M L; Startsev, V K; Akindinov, V A

1977-01-01

Results are cited of laboratory research into the possibility of radiometric determination of P/sub 2/O/sub 5/ in phosphorites of Polpinsky deposit. On the basis of the studies performed, a plant and methods have been developed for the continuous control of P/sub 2/O/sub 5/ content in ore. The plant has been tested at the Bryansk phosphorite works. The accuracy of analysis is 0.8 percent.

Suppression of hydrogenated carbon film deposition by scavenger techniques and their application to the tritium inventory control of fusion devices

International Nuclear Information System (INIS)

Tabares, F.L.; Tafalla, D.; Tanarro, I.; Herrero, V.J.; Islyaikin, A.; Maffiotte, C.

2002-01-01

The well-known radical and ion scavenger techniques of application in amorphous hydrogenated carbon film deposition studies are investigated in relation to the mechanism of tritium and deuterium co-deposition in carbon-dominated fusion devices. A particularly successful scheme results from the injection of nitrogen into methane/hydrogen plasmas for conditions close to those prevailing in the divertor region of present fusion devices. A complete suppression of the a-C : H film deposition has been achieved for N 2 /CH 4 ratios close to one in methane (5%)/hydrogen DC plasma. The implications of these findings in the tritium retention control in future fusion reactors are addressed. (author). Letter-to-the-editor

Mercury Wet Scavenging and Deposition Differences by Precipitation Type.

Science.gov (United States)

Kaulfus, Aaron S; Nair, Udaysankar; Holmes, Christopher D; Landing, William M

2017-03-07

We analyze the effect of precipitation type on mercury wet deposition using a new database of individual rain events spanning the contiguous United States. Measurements from the Mercury Deposition Network (MDN) containing single rainfall events were identified and classified into six precipitation types. Mercury concentrations in surface precipitation follow a power law of precipitation depth that is modulated by precipitation system morphology. After controlling for precipitation depth, the highest mercury deposition occurs in supercell thunderstorms, with decreasing deposition in disorganized thunderstorms, quasi-linear convective systems (QLCS), extratropical cyclones, light rain, and land-falling tropical cyclones. Convective morphologies (supercells, disorganized, and QLCS) enhance wet deposition by a factor of at least 1.6 relative to nonconvective morphologies. Mercury wet deposition also varies by geographic region and season. After controlling for other factors, we find that mercury wet deposition is greater over high-elevation sites, seasonally during summer, and in convective precipitation.

Discussion on the genesis of Zhongchuan uranium deposit

International Nuclear Information System (INIS)

Zhang Yulong; Zhang Chengzhong

2008-01-01

Through elaborating the geological setting, deposit and orebody geological charactors and hydrological features, the ore controlling factors are analysed and the genesis of Zhongchuan uranium deposit is discussed in the way of deposit occurrence, mineral asembleage and matalization ages. It is believed that uranium deposit was formed under the regional uplifting background with the exogenous mechanism and its genesis belongs to surface leaching. (authors)

Real time spectroscopic ellipsometry for analysis and control of thin film polycrystalline semiconductor deposition in photovoltaics

Energy Technology Data Exchange (ETDEWEB)

Koirala, Prakash; Attygalle, Dinesh; Aryal, Puruswottam; Pradhan, Puja; Chen, Jie [Center for Photovoltaics Innovation and Commercialization and Department of Physics and Astronomy, University of Toledo, Toledo, OH 43606 (United States); Marsillac, Sylvain [Department of Electrical and Computer Engineering, Old Dominion University, Norfolk, VA 23529 (United States); Ferlauto, Andre S.; Podraza, Nikolas J.; Collins, Robert W. [Center for Photovoltaics Innovation and Commercialization and Department of Physics and Astronomy, University of Toledo, Toledo, OH 43606 (United States)

2014-11-28

Real time spectroscopic ellipsometry (RTSE) from the near-infrared to ultraviolet has been applied for analysis of the deposition of polycrystalline thin films that form the basis of two key photovoltaic heterojunction configurations, superstrate SnO{sub 2}/CdS/CdTe and substrate Mo/Cu(In{sub 1−x}Ga{sub x})Se{sub 2}/CdS. The focus of this work is to develop capabilities for monitoring and controlling the key steps in the fabrication of these device structures. Analysis of RTSE data collected during sputter deposition of CdS on a rough SnO{sub 2} transparent top contact provides the time evolution of the CdS effective thickness, or film volume per unit substrate area. This thickness includes interface, bulk, and surface roughness layer components and affects the CdS/CdTe heterojunction performance and the quantum efficiency of the solar cell in the blue region of the solar spectrum. Similarly, analysis of RTSE data collected during co-evaporation of Cu(In{sub 1−x}Ga{sub x})Se{sub 2} (CIGS; x ∼ 0.3) on a rough Mo back contact provides the evolution of a second phase of Cu{sub 2−x}Se within the CIGS layer. During the last stage of CIGS deposition, the In, Ga, and Se co-evaporants convert this Cu{sub 2−x}Se phase to CIGS, and RTSE identifies the endpoint, specifically the time at which complete conversion occurs and single-phase, large-grain CIGS is obtained in this key stage. - Highlights: • Real time spectroscopic ellipsometry (RTSE) study of CdS and CuIn{sub 1−x}Ga{sub x}Se{sub 2} (CIGS) films. • RTSE during CdS deposition provides the evolution of the CdS effective thickness. • RTSE for CIGS film enables to measure and control the composition and thickness. • The work leads to the development of optical models for processing steps.

Atmospheric Nitrogen Deposition Loadings to the Chesapeake Bay: An Initial Analysis of the Cost Effectiveness of Control Options (1996)

Science.gov (United States)

This report examines the cost effectiveness of control options which reduce nitrate deposition to the Chesapeake watershed and to the tidal Bay. The report analyzes current estimates of the reductions expected in the ozone transport region.

Breakthrough to Non-Vacuum Deposition of Single-Crystal, Ultra-Thin, Homogeneous Nanoparticle Layers: A Better Alternative to Chemical Bath Deposition and Atomic Layer Deposition

Directory of Open Access Journals (Sweden)

Yu-Kuang Liao

2017-04-01

Full Text Available Most thin-film techniques require a multiple vacuum process, and cannot produce high-coverage continuous thin films with the thickness of a few nanometers on rough surfaces. We present a new ”paradigm shift” non-vacuum process to deposit high-quality, ultra-thin, single-crystal layers of coalesced sulfide nanoparticles (NPs with controllable thickness down to a few nanometers, based on thermal decomposition. This provides high-coverage, homogeneous thickness, and large-area deposition over a rough surface, with little material loss or liquid chemical waste, and deposition rates of 10 nm/min. This technique can potentially replace conventional thin-film deposition methods, such as atomic layer deposition (ALD and chemical bath deposition (CBD as used by the Cu(In,GaSe2 (CIGS thin-film solar cell industry for decades. We demonstrate 32% improvement of CIGS thin-film solar cell efficiency in comparison to reference devices prepared by conventional CBD deposition method by depositing the ZnS NPs buffer layer using the new process. The new ZnS NPs layer allows reduction of an intrinsic ZnO layer, which can lead to severe shunt leakage in case of a CBD buffer layer. This leads to a 65% relative efficiency increase.

Atomic layer deposition of HfO{sub 2} on graphene through controlled ion beam treatment

Energy Technology Data Exchange (ETDEWEB)

Kim, Ki Seok [School of Advanced Materials Science and Engineering, Sungkyunkwan University, 2066 Seobu-ro, Jangan-gu, Suwon-si, Gyeonggi-do 16419 (Korea, Republic of); Oh, Il-Kwon; Jung, Hanearl; Kim, Hyungjun [School of Electrical and Electronics Engineering, Yonsei University, 50 Yonsei Ro, Seodaemun-gu, Seoul 120-749 (Korea, Republic of); Yeom, Geun Young, E-mail: knam1004@dju.kr, E-mail: gyyeom@skku.edu [School of Advanced Materials Science and Engineering, Sungkyunkwan University, 2066 Seobu-ro, Jangan-gu, Suwon-si, Gyeonggi-do 16419 (Korea, Republic of); SKKU Advanced Institute of Nano Technology (SAINT), Sungkyunkwan University, 2066 Seobu-ro, Jangan-gu, Suwon-si, Gyeonggi-do 16419 (Korea, Republic of); Kim, Kyong Nam, E-mail: knam1004@dju.kr, E-mail: gyyeom@skku.edu [School of Advanced Materials Science and Engineering, Daejeon University, Yongun-dong, Dong-gu, Daejeon 34520 (Korea, Republic of)

2016-05-23

The polymer residue generated during the graphene transfer process to the substrate tends to cause problems (e.g., a decrease in electron mobility, unwanted doping, and non-uniform deposition of the dielectric material). In this study, by using a controllable low-energy Ar{sup +} ion beam, we cleaned the polymer residue without damaging the graphene network. HfO{sub 2} grown by atomic layer deposition on graphene cleaned using an Ar{sup +} ion beam showed a dense uniform structure, whereas that grown on the transferred graphene (before Ar{sup +} ion cleaning) showed a non-uniform structure. A graphene–HfO{sub 2}–metal capacitor fabricated by growing 20-nm thick HfO{sub 2} on graphene exhibited a very low leakage current (<10{sup −11} A/cm{sup 2}) for Ar{sup +} ion-cleaned graphene, whereas a similar capacitor grown using the transferred graphene showed high leakage current.

Superpermeable membrane for particle control in divertor: the effect of impurity deposition

International Nuclear Information System (INIS)

Nakahara, Y.; Nakamura, Y.; Ohyabu, N.; Suzuki, H.; Busnyuk, A.; Alimov, V.

2000-01-01

The effect of impurity (stainless steel (SS) components, carbon) deposition onto niobium membrane surface on the membrane permeability to hydrogen particles is investigated with a plasma device. The deposition of SS components onto the upstream surface of the membrane at the membrane temperature (T M ) M M ≥800 deg. C. It appears to be due to the dissolution of the impurities deposited onto the upstream surface into the membrane bulk within the measurements

Controlling of morphology and electrocatalytic properties of cobalt oxide nanostructures prepared by potentiodynamic deposition method

Energy Technology Data Exchange (ETDEWEB)

Hallaj, Rahman [Department of Chemistry, University of Kurdistan, P.O. Box 416, Sanandaj (Iran, Islamic Republic of); Akhtari, Keivan [Department of Chemistry, University of Kurdistan, P.O. Box 416, Sanandaj (Iran, Islamic Republic of); Research Center for Nanotechnology, University of Kurdistan, P.O.Box 416, Sanandaj (Iran, Islamic Republic of); Salimi, Abdollah, E-mail: absalimi@uok.ac.ir [Department of Chemistry, University of Kurdistan, P.O. Box 416, Sanandaj (Iran, Islamic Republic of); Research Center for Nanotechnology, University of Kurdistan, P.O.Box 416, Sanandaj (Iran, Islamic Republic of); Soltanian, Saied [Department of Physics, University of Kurdistan, P.O. Box 416, Sanandaj (Iran, Islamic Republic of)

2013-07-01

Electrodeposited cobalt oxide nanostructures were prepared by Repetitive Triangular Potential Scans (RTPS) as a simple, remarkably fast and scalable potentiodynamic method. Electrochemical deposition of cobalt oxide nanostructures onto GC electrode was performed from aqueous Co(NO{sub 3}){sub 2}, (pH 6) solution using cyclic voltammetry method. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) were used to characterize the morphology of fabricated nanostructures. The evaluation of electrochemical properties of deposited films was performed using cyclic voltametry (CV) and impedance spectroscopy (IS) techniques. The analysis of the experimental data clearly showed that the variations of potential scanning ranges during deposition process have drastic effects on the geometry, chemical structure and particle size of cobalt oxide nanoparticles. In addition, the electrochemical and electrocatalytic properties of prepared nanostructures can be controlled through applying different potential windows in electrodeposition process. The imaging and voltammetric studies suggested to the existence of at least three different shapes of cobalt-oxide nanostructures in various potential windows applied for electrodeposition. With enlarging the applied potential window, the spherical-like cobalt oxide nanoparticles with particles sizes about 30–50 nm changed to the grain-like structures (30 nm × 80 nm) and then to the worm-like cobalt oxide nanostructures with 30 nm diameter and 200–400 nm in length. Furthermore, the roughness of the prepared nanostructures increased with increasing positive potential window. The GC electrodes modified with cobalt oxide nanostructures shows excellent electrocatalytic activity toward H{sub 2}O{sub 2} and As (III) oxidation. The electrocatalytic activity of cobalt oxide nanostructures prepared at more positive potential window toward hydrogen peroxide oxidation was increased, while for As(III) oxidation the electrocatalytic

Controlling of morphology and electrocatalytic properties of cobalt oxide nanostructures prepared by potentiodynamic deposition method

International Nuclear Information System (INIS)

Hallaj, Rahman; Akhtari, Keivan; Salimi, Abdollah; Soltanian, Saied

2013-01-01

Electrodeposited cobalt oxide nanostructures were prepared by Repetitive Triangular Potential Scans (RTPS) as a simple, remarkably fast and scalable potentiodynamic method. Electrochemical deposition of cobalt oxide nanostructures onto GC electrode was performed from aqueous Co(NO 3 ) 2 , (pH 6) solution using cyclic voltammetry method. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) were used to characterize the morphology of fabricated nanostructures. The evaluation of electrochemical properties of deposited films was performed using cyclic voltametry (CV) and impedance spectroscopy (IS) techniques. The analysis of the experimental data clearly showed that the variations of potential scanning ranges during deposition process have drastic effects on the geometry, chemical structure and particle size of cobalt oxide nanoparticles. In addition, the electrochemical and electrocatalytic properties of prepared nanostructures can be controlled through applying different potential windows in electrodeposition process. The imaging and voltammetric studies suggested to the existence of at least three different shapes of cobalt-oxide nanostructures in various potential windows applied for electrodeposition. With enlarging the applied potential window, the spherical-like cobalt oxide nanoparticles with particles sizes about 30–50 nm changed to the grain-like structures (30 nm × 80 nm) and then to the worm-like cobalt oxide nanostructures with 30 nm diameter and 200–400 nm in length. Furthermore, the roughness of the prepared nanostructures increased with increasing positive potential window. The GC electrodes modified with cobalt oxide nanostructures shows excellent electrocatalytic activity toward H 2 O 2 and As (III) oxidation. The electrocatalytic activity of cobalt oxide nanostructures prepared at more positive potential window toward hydrogen peroxide oxidation was increased, while for As(III) oxidation the electrocatalytic activity decreased

Underpotential deposition-mediated layer-by-layer growth of thin films

Science.gov (United States)

Wang, Jia Xu; Adzic, Radoslav R.

2015-05-19

A method of depositing contiguous, conformal submonolayer-to-multilayer thin films with atomic-level control is described. The process involves the use of underpotential deposition of a first element to mediate the growth of a second material by overpotential deposition. Deposition occurs between a potential positive to the bulk deposition potential for the mediating element where a full monolayer of mediating element forms, and a potential which is less than, or only slightly greater than, the bulk deposition potential of the material to be deposited. By cycling the applied voltage between the bulk deposition potential for the mediating element and the material to be deposited, repeated desorption/adsorption of the mediating element during each potential cycle can be used to precisely control film growth on a layer-by-layer basis. This process is especially suitable for the formation of a catalytically active layer on core-shell particles for use in energy conversion devices such as fuel cells.

Controlled deposition of functionalized silica coated zinc oxide nano-assemblies at the air/water interface for blood cancer detection

Energy Technology Data Exchange (ETDEWEB)

Pandey, Chandra Mouli [Biomedical Instrumentation Section, CSIR-National Physical Laboratory, New Delhi 110012 (India); Nanobioelectronics Laboratory, Department of Biotechnology, Delhi Technological University, Delhi 110042 (India); Dewan, Srishti [Biomedical Instrumentation Section, CSIR-National Physical Laboratory, New Delhi 110012 (India); Biomedical Engineering Department, Deenbandhu Chhotu Ram University of Science & Technology, Haryana 131039 (India); Chawla, Seema [Biomedical Engineering Department, Deenbandhu Chhotu Ram University of Science & Technology, Haryana 131039 (India); Yadav, Birendra Kumar [Rajiv Gandhi Cancer Institute and Research Centre, Rohini, Delhi 110085 (India); Sumana, Gajjala, E-mail: sumanagajjala@gmail.com [Biomedical Instrumentation Section, CSIR-National Physical Laboratory, New Delhi 110012 (India); Malhotra, Bansi Dhar, E-mail: bansi.malhotra@gmail.com [Biomedical Instrumentation Section, CSIR-National Physical Laboratory, New Delhi 110012 (India); Nanobioelectronics Laboratory, Department of Biotechnology, Delhi Technological University, Delhi 110042 (India)

2016-09-21

We report results of the studies relating to controlled deposition of the amino-functionalized silica-coated zinc oxide (Am-Si@ZnO) nano-assemblies onto an indium tin oxide (ITO) coated glass substrate using Langmuir-Blodgett (LB) technique. The monolayers have been deposited by transferring the spread solution of Am-Si@ZnO stearic acid prepared in chloroform at the air-water interface, at optimized pressure (16 mN/m), concentration (10 mg/ml) and temperature (23 °C). The high-resolution transmission electron microscopic studies of the Am-Si@ZnO nanocomposite reveal that the nanoparticles have a microscopic structure comprising of hexagonal assemblies of ZnO with typical dimensions of 30 nm. The surface morphology of the LB multilayer observed by scanning electron microscopy shows uniform surface of the Am-Si@ZnO film in the nanometer range (<80 nm). These electrodes have been utilized for chronic myelogenous leukemia (CML) detection by covalently immobilizing the amino-terminated oligonucleotide probe sequence via glutaraldehyde as a crosslinker. The response studies of these fabricated electrodes carried out using electrochemical impedance spectroscopy show that this Am-Si@ZnO LB film based nucleic acid sensor exhibits a linear response to complementary DNA (10{sup −6}–10{sup −16} M) with a detection limit of 1 × 10{sup −16} M. This fabricated platform is validated with clinical samples of CML positive patients and the results demonstrate its immense potential for clinical diagnosis. - Graphical abstract: Controlled deposition of functionalized silica coated zinc oxide nano-assemblies at the air/water interface for label free electrochemical detection of chronic myelogenous leukemia. - Highlights: • Stable and controlled deposition of Am-Si@ZnO nano-assemblies using LB technique. • Uniform monolayer deposition of the Am-Si@ZnO LB film within the nanometer range. • Am-Si@ZnO LB film shows enhanced electrochemical properties. • Fabricated

Uranium deposits in Africa

International Nuclear Information System (INIS)

Wilpolt, R.H.; Simov, S.D.

1979-01-01

Africa is not only known for its spectacular diamond, gold, copper, chromium, platinum and phosphorus deposits but also for its uranium deposits. At least two uranium provinces can be distinguished - the southern, with the equatorial sub-province; and the south Saharan province. Uranium deposits are distributed either in cratons or in mobile belts, the first of sandstone and quartz-pebble conglomerate type, while those located in mobile belts are predominantly of vein and similar (disseminated) type. Uranium deposits occur within Precambrian rocks or in younger platform sediments, but close to the exposed Precambrian basement. The Proterozoic host rocks consist of sediments, metamorphics or granitoids. In contrast to Phanerozoic continental uranium-bearing sediments, those in the Precambrian are in marginal marine facies but they do contain organic material. The geology of Africa is briefly reviewed with the emphasis on those features which might control the distribution of uranium. The evolution of the African Platform is considered as a progressive reduction of its craton area which has been affected by three major Precambrian tectonic events. A short survey on the geology of known uranium deposits is made. However, some deposits and occurrences for which little published material is available are treated in more detail. (author)

The controlling role of positive structures over the metallogenesis and emplacement of inter layer oxidation sandstone type uranium deposits

International Nuclear Information System (INIS)

Gu Kangheng; Chen Zuyi

2010-01-01

The positive structures in this paper mean the geological structures related to the occurrence of U-metallogenic zones or U-deposit such as anticlines, uplifts and uplifted fault-blocks. Occurrence features of interlayer oxidation sandstone type deposit at the southern margin of Yili basin and southwestern margin of Turpan-Hami basin, the northeastern margin of Jiudong basin illustrate that the sandstone-hosted uranium deposits, the U-mineralized sections and the uranium occurrences are always selectively emplaced on/in positive structures. The reasons for this lie in the formation mechanism of sandstone-hosted U-deposits. The positive structures raised the elevation of ore-hosting sandstone horizon and make it close to ground surface or exposed at the ground surface, which result in the infiltration of uranium and oxygen bearing groundwater from recharge area into host sandstone horizon, and the interlayer oxidation of host sandstone, as well as the dissolution and the migration of uranium in host sandstone, and the reduction mineralization at the oxidation-reduction interface. Sufficient attention should be paid to the controlling role of positive structures over the metallogenesis and emplacement of sandstone-hosted uranium deposits. They could act as an important criterion for recognizing and prognosticating potential uranium mineralized areas in uranium metallogenic zones or uranium-productive sedimentary basins. (authors)

A radon progeny deposition model

International Nuclear Information System (INIS)

Rielage, Keith; Elliott, Steven R.; Hime, Andrew; Guiseppe, Vincent E.; Westerdale, S.

2010-01-01

The next generation low-background detectors operating underground aim for unprecedented low levels of radioactive backgrounds. Although the radioactive decays of airborne radon (particularly 222 Rn) and its subsequent progeny present in an experiment are potential backgrounds, also problematic is the deposition of radon progeny on detector materials. Exposure to radon at any stage of assembly of an experiment can result in surface contamination by progeny supported by the long half life (22 y) of 210 Pb on sensitive locations of a detector. An understanding of the potential surface contamination from deposition will enable requirements of radon-reduced air and clean room environments for the assembly of low background experiments. It is known that there are a number of environmental factors that govern the deposition of progeny onto surfaces. However, existing models have not explored the impact of some environmental factors important for low background experiments. A test stand has been constructed to deposit radon progeny on various surfaces under a controlled environment in order to develop a deposition model. Results from this test stand and the resulting deposition model are presented.

A Radon Progeny Deposition Model

International Nuclear Information System (INIS)

Guiseppe, V. E.; Elliott, S. R.; Hime, A.; Rielage, K.; Westerdale, S.

2011-01-01

The next generation low-background detectors operating underground aim for unprecedented low levels of radioactive backgrounds. Although the radioactive decays of airborne radon (particularly 222 Rn) and its subsequent progeny present in an experiment are potential backgrounds, also problematic is the deposition of radon progeny on detector materials. Exposure to radon at any stage of assembly of an experiment can result in surface contamination by progeny supported by the long half life (22 y) of 210 Pb on sensitive locations of a detector. An understanding of the potential surface contamination from deposition will enable requirements of radon-reduced air and clean room environments for the assembly of low background experiments. It is known that there are a number of environmental factors that govern the deposition of progeny onto surfaces. However, existing models have not explored the impact of some environmental factors important for low background experiments. A test stand has been constructed to deposit radon progeny on various surfaces under a controlled environment in order to develop a deposition model. Results from this test stand and the resulting deposition model are presented.

Hydroxyapatite coatings deposited by liquid precursor plasma spraying: controlled dense and porous microstructures and osteoblastic cell responses

International Nuclear Information System (INIS)

Huang Yi; Song Lei; Liu Xiaoguang; Xiao Yanfeng; Wu Yao; Chen Jiyong; Wu Fang; Gu Zhongwei

2010-01-01

Hydroxyapatite coatings were deposited on Ti-6Al-4V substrates by a novel plasma spraying process, the liquid precursor plasma spraying (LPPS) process. X-ray diffraction results showed that the coatings obtained by the LPPS process were mainly composed of hydroxyapatite. The LPPS process also showed excellent control on the coating microstructure, and both nearly fully dense and highly porous hydroxyapatite coatings were obtained by simply adjusting the solid content of the hydroxyapatite liquid precursor. Scanning electron microscope observations indicated that the porous hydroxyapatite coatings had pore size in the range of 10-200 μm and an average porosity of 48.26 ± 0.10%. The osteoblastic cell responses to the dense and porous hydroxyapatite coatings were evaluated with human osteoblastic cell MG-63, in respect of the cell morphology, proliferation and differentiation, with the hydroxyapatite coatings deposited by the atmospheric plasma spraying (APS) process as control. The cell experiment results indicated that the heat-treated LPPS coatings with a porous structure showed the best cell proliferation and differentiation among all the hydroxyapatite coatings. Our results suggest that the LPPS process is a promising plasma spraying technique for fabricating hydroxyapatite coatings with a controllable microstructure, which has great potential in bone repair and replacement applications.

Uranium deposits of Australia to 1975

International Nuclear Information System (INIS)

Spannari, S.

1979-01-01

This bibliography provides a retrospective account of Australian uranium deposits, particularly the unpublished materials in the Australian Capital Territory. Some abstracts are included. Occurrences, mineralogy, ore genesis, structural controls and the eonomic geology of uranium deposits are covered but the mining of uranium, exploration reports, surveys, environmental aspects and controversial materials are not

Deposition and cycling of sulfur controls mercury accumulation in Isle Royale fish

Energy Technology Data Exchange (ETDEWEB)

Paul E. Drevnick; Donald E. Canfield; Patrick R. Gorski (and others) [Miami University, Oxford, OH (United States). Department of Zoology

2007-11-01

Mercury contamination of fish is a global problem. Consumption of contaminated fish is the primary route of methylmercury exposure in humans and is detrimental to health. Newly mandated reductions in anthropogenic mercury emissions aim to reduce atmospheric mercury deposition and thus mercury concentrations in fish. However, factors other than mercury deposition are important for mercury bioaccumulation in fish. In the lakes of Isle Royale, U.S.A., reduced rates of sulfate deposition since the Clean Air Act of 1970 have caused mercury concentrations in fish to decline to levels that are safe for human consumption, even without a discernible decrease in mercury deposition. Therefore, reductions in anthropogenic sulfur emissions may provide a synergistic solution to the mercury problem in sulfate-limited freshwaters. 71 refs., 3 figs., 1 tab.

Microwave absorption properties of carbon nanocoils coated with highly controlled magnetic materials by atomic layer deposition.

Science.gov (United States)

Wang, Guizhen; Gao, Zhe; Tang, Shiwei; Chen, Chaoqiu; Duan, Feifei; Zhao, Shichao; Lin, Shiwei; Feng, Yuhong; Zhou, Lei; Qin, Yong

2012-12-21

In this work, atomic layer deposition is applied to coat carbon nanocoils with magnetic Fe(3)O(4) or Ni. The coatings have a uniform and highly controlled thickness. The coated nanocoils with coaxial multilayer nanostructures exhibit remarkably improved microwave absorption properties compared to the pristine carbon nanocoils. The enhanced absorption ability arises from the efficient complementarity between complex permittivity and permeability, chiral morphology, and multilayer structure of the products. This method can be extended to exploit other composite materials benefiting from its convenient control of the impedance matching and combination of dielectric-magnetic multiple loss mechanisms for microwave absorption applications.

Aligned, plasma sprayed SmCo5 deposits

International Nuclear Information System (INIS)

Kumar, K.; Das, D.

1986-01-01

Highly aligned SmCo 5 deposits were produced using plasma spraying. c-axis alignment, normal to the plane of the deposit, was achieved by depositing the Sm-Co alloys on steel substrates maintained at high temperatures. The substrates were heated by the plasma flame to obtain the high temperatures. The attainment of a range of substrate temperatures was made possible through control over the geometry of the substrate

Adhesion Strength of Biomass Ash Deposits

DEFF Research Database (Denmark)

Laxminarayan, Yashasvi; Jensen, Peter Arendt; Wu, Hao

2015-01-01

This study investigates the shear adhesion strength of biomass ash deposits on superheater tubes. Artificial biomass ash deposits were prepared on superheater tubes and sintered in an oven at temperatures up to 1000°C. Subsequently, the deposits were sheared off with the help of an electrically...... controlled arm. Higher sintering temperatures resulted in greater adhesion strengths, with a sharp increase observed near the melting point of the ash. Repetition of experiments with fixed operation conditions revealed considerable variation in the obtained adhesion strengths, portraying the stochastic...

Control of microstructure in soldered, brazed, welded, plated, cast or vapor deposited manufactured components

Science.gov (United States)

Ripley, Edward B.; Hallman, Russell L.

2015-11-10

Disclosed are methods and systems for controlling of the microstructures of a soldered, brazed, welded, plated, cast, or vapor deposited manufactured component. The systems typically use relatively weak magnetic fields of either constant or varying flux to affect material properties within a manufactured component, typically without modifying the alloy, or changing the chemical composition of materials or altering the time, temperature, or transformation parameters of a manufacturing process. Such systems and processes may be used with components consisting of only materials that are conventionally characterized as be uninfluenced by magnetic forces.

Post-deposition treatments of plasma-sprayed YBaCuO coatings deposited on nickel

Energy Technology Data Exchange (ETDEWEB)

Dube, D; Lambert, P; Arsenault, B; Champagne, B [National Research Council of Canada, Boucherville, PQ (Canada)

1990-12-15

As-sprayed YBaCuO coatings do not exhibit superconductivity because of the non-equilibrium solidification conditions of molten particles on the substrate and to the deposit's loss of oxygen. Therefore post-deposition treatments are required to restore the superconductivity. In this study, post-deposition treatments were carried out on thick YBaCuO coatings (200 {mu}m) deposited on cold nickel substrates to modify their microstructure, to restore the oxygen content and to improve their superconducting properties. These treatments consist in heating the coatings at various temperatures above 950deg C followed by controlled solidification cycles. The effect of these treatments on the microstructure of the coatings was assessed and the interaction between the coatings and the nickel substrate was also examined. Solidification cycles including a low cooling rate near the non-congruent melting temperature of YBa{sub 2}Cu{sub 3}O{sub x} and involving a temperature gradient were carried out to create a texture. (orig.).

INVESTMENT DEPOSITS DECISION-MAKING IN BANK: A BEHAVIORAL FINANCE PERSPECTIVE

Directory of Open Access Journals (Sweden)

Hanopia B.L.

2018-02-01

Full Text Available This research was conducted using behavioral finance theories. The objectives of this research was to analyze influencing factors of investment deposits decision-making for the depositor, and to analyze the most dominant factor of investment deposits decision-making in Bank NTB of Pejanggik Principle Branches. The instrument of this research was questionnaire with the total sample of 90 respondents who were the deposit customers. The research results show that deposits’ interest, gain and cost, feelings of disappointment and satisfaction, worries, reluctances, good companies, budget allocation, self-control, net interest income, belief in net interest income, overestimate and underestimate are factors influencing investment deposits decision-making in Bank NTB of Pejanggik Principle Branches. Dominant factors determining investment deposits decision-making are deposits cost, interest and feelings of satisfaction, budget allocation, overestimate and self-control. Those factors are included in the factor group of deposits cost.

Modification of thin film properties by ion bombardment during deposition

International Nuclear Information System (INIS)

Harper, J.M.E.; Cuomo, J.J.; Gambino, R.J.; Kaufman, H.R.

1984-01-01

Many thin film deposition techniques involve some form of energetic particle bombardment of the growing film. The degree of bombardment greatly influences the film composition, structure and other properties. While in some techniques the degree of bombardment is secondary to the original process design, in recent years more deposition systems are being designed with the capability for controlled ion bombardment of thin films during deposition. The highest degree of control is obtained with ion beam sources which operate independently of the vapor source providing the thin film material. Other plasma techniques offer varying degrees of control of energetic particle bombardment. Deposition methods involving ion bombardment are described, and the basic processes with which film properties are modified by ion bombardment are summarized. (Auth.)

Physical vapor deposition of cubic boron nitride thin films

International Nuclear Information System (INIS)

Kester, D.J.

1991-01-01

Cubic boron nitride was successfully deposited using physical vapor-deposition methods. RF-sputtering, magnetron sputtering, dual-ion-beam deposition, and ion-beam-assisted evaporation were all used. The ion-assisted evaporation, using boron evaporation and bombardment by nitrogen and argon ions, led to successful cubic boron nitride growth over the widest and most controllable range of conditions. It was found that two factors were important for c-BN growth: bombardment of the growing film and the presence of argon. A systematic study of the deposition conditions was carried out. It was found that the value of momentum transferred into the growing from by the bombarding ions was critical. There was a very narrow transition range in which mixed cubic and hexagonal phase films were prepared. Momentum-per-atom value took into account all the variables involved in ion-assisted deposition: deposition rate, ion energy, ion flux, and ion species. No other factor led to the same control of the process. The role of temperature was also studied; it was found that at low temperatures only mixed cubic and hexagonal material are deposited

Control of Crud and Boron Deposition for AOA Prevention

International Nuclear Information System (INIS)

Maeng, W. Y.; Choi, B. S.; Na, J. W.

2010-07-01

Ο Understand effects of water chemistry variables on AOA and investigate AOA mechanism Ο Mitigate AOA in terms of water chemistry control AOA(Axial Offset Anomaly) has been reported in many PWR plants in the world, including Korea, especially in the plants of higher burn-up and longer cycle operation or power up-rate. A test loop has been designed and made by KAERI, in order to investigate and mitigate AOA problems in Korea. This project included the study of hydrodynamic simulation and the modeling about AOA. The analysis of radioactive crud was performed to investigate of NPPs primary water chemical effect on AOA and to reduce the radioactive dose rate. The present primary water chemistry guideline of EPRI is to operate NPPs with AOA in the condition of initial 3.5 ppm Li and pH 7.1. However, the tests in this project indicate that the amount of deposit on fuel cladding can be reduced when an appropriate water chemistry strategy is applied. High pH water chemistry in the beginning of operation is recommended based on the results of this project

31 CFR 535.566 - Unblocking of foreign currency deposits held by U.S.-owned or controlled foreign firms.

Science.gov (United States)

2010-07-01

... Licensing Policy § 535.566 Unblocking of foreign currency deposits held by U.S.-owned or controlled foreign... persons subject to the jurisdiction of the United States are unblocked, provided however that conversions... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Unblocking of foreign currency...

Diameter control and emission properties of carbon nanotubes grown using chemical vapor deposition

Energy Technology Data Exchange (ETDEWEB)

Kaatz, F.H.; Siegal, M.P.; Overmyer, D.L.; Provencio, P.P.; Jackson, J.L

2003-01-15

We grow multiwalled carbon nanotubes (CNTs) via thermal chemical vapor deposition from a sputtered 4-nm-thick nickel catalyst film on a tungsten-coated silicon substrate. CNTs grow from a mixture of nitrogen and acetylene gases at temperatures ranging from 630 to 790 deg. C, resulting in CNT outer diameters of 5-350 nm. CNT diameters increase exponentially with temperature. These results define regimes for template growth fabricated in catalytically active anodized aluminum oxide (AAO) with controlled pinhole sizes ranging from 10 to 50 nm. We measure a threshold electron emission field of 3 V/{mu}m and a field enhancement factor {beta}=5230 on randomly oriented 10-nm diameter CNTs.

Diameter control and emission properties of carbon nanotubes grown using chemical vapor deposition

International Nuclear Information System (INIS)

Kaatz, F.H.; Siegal, M.P.; Overmyer, D.L.; Provencio, P.P.; Jackson, J.L.

2003-01-01

We grow multiwalled carbon nanotubes (CNTs) via thermal chemical vapor deposition from a sputtered 4-nm-thick nickel catalyst film on a tungsten-coated silicon substrate. CNTs grow from a mixture of nitrogen and acetylene gases at temperatures ranging from 630 to 790 deg. C, resulting in CNT outer diameters of 5-350 nm. CNT diameters increase exponentially with temperature. These results define regimes for template growth fabricated in catalytically active anodized aluminum oxide (AAO) with controlled pinhole sizes ranging from 10 to 50 nm. We measure a threshold electron emission field of 3 V/μm and a field enhancement factor β=5230 on randomly oriented 10-nm diameter CNTs

Oxide deposition in the orifices of AGR boiler inlet ferrule assemblies

International Nuclear Information System (INIS)

Thomas, D.M.

1988-08-01

In experiments designed to study the erosion-corrosion behaviour of AGR boiler inlet ferrules using the CERL high velocity circulating isothermal water rig, oxide deposition was frequently found within the flow control orifices. The present investigation was carried out as a preliminary to a programme of experiments addressed specifically to this problem. Analysis shows the deposits to be predominantly magnetite (or possible maghemite) with traces of α-haematite. Calculations indicate that the maximum rate of magnetite deposition is mass transfer limited, although in some experiments no deposition occurred in cases where mass transfer would have allowed substantial deposition. Thus the occurrence of deposition is thought to depend on the rig potential as this varies with experimental conditions. In these experiments the surface potential is not found to be governed by the hydrogen level. Metallographic cross-sections through the ferrule control bores show the deposits to be found in regions of separated flow, and the flow markings in the deposits show that the flow is turbulent in these zones. The exact morphology is thought to be influenced by machining marks within the control bore. (author)

Controlled Deposition and Alignment of Carbon Nanotubes

Science.gov (United States)

Smits, Jan M. (Inventor); Wincheski, Russell A. (Inventor); Patry, JoAnne L. (Inventor); Watkins, Anthony Neal (Inventor); Jordan, Jeffrey D. (Inventor)

2012-01-01

A carbon nanotube (CNT) attraction material is deposited on a substrate in the gap region between two electrodes on the substrate. An electric potential is applied to the two electrodes. The CNT attraction material is wetted with a solution defined by a carrier liquid having carbon nanotubes (CNTs) suspended therein. A portion of the CNTs align with the electric field and adhere to the CNT attraction material. The carrier liquid and any CNTs not adhered to the CNT attraction material are then removed.

Controls on mercury and methylmercury deposition for two watersheds in Acadia National Park, Maine.

Science.gov (United States)

Johnson, K B; Haines, T A; Kahl, J S; Norton, S A; Amirbahman, Aria; Sheehan, K D

2007-03-01

Throughfall and bulk precipitation samples were collected for two watersheds at Acadia National Park, Maine, from 3 May to 16 November 2000, to determine which landscape factors affected mercury (Hg) deposition. One of these watersheds, Cadillac Brook, burned in 1947, providing a natural experimental design to study the effects of forest type on deposition to forested watersheds. Sites that face southwest received the highest Hg deposition, which may be due to the interception of cross-continental movement of contaminated air masses. Sites covered with softwood vegetation also received higher Hg deposition than other vegetation types because of the higher scavenging efficiency of the canopy structure. Methyl mercury (MeHg) deposition was not affected by these factors. Hg deposition, as bulk precipitation and throughfall was lower in Cadillac Brook watershed (burned) than in Hadlock Brook watershed (unburned) because of vegetation type and watershed aspect. Hg and MeHg inputs were weighted by season and vegetation type because these two factors had the most influence on deposition. Hg volatilization was not determined. The total Hg deposition via throughfall and bulk precipitation was 9.4 microg/m(2)/year in Cadillac Brook watershed and 10.2 microg/m(2)/year in Hadlock Brook watershed. The total MeHg deposition via throughfall and bulk precipitation was 0.05 microg/m(2)/year in Cadillac Brook watershed and 0.10 microg/m(2)/year in Hadlock Brook watershed.

Characteristics and model of sandstone type uranium deposit in south of Songliao basin

International Nuclear Information System (INIS)

Yu Wenbin; Yu Zhenqing

2010-01-01

Through analyzing the uranium deposit tectonic environment, upper cretaceous sequence stratigraphy, depositional system, evolutionary characteristics of sand bodies, the effect of subsequent transformation and the characteristic of uranium deposit, the sandstone type uranium deposit in southern basin is different from typical interlayer oxidation zone sandstone type uranium deposit. The formation and evolution of sandstone-type uranium deposit are controlled by structure fensters; the favorable sedimentary facies type is braided river facies, and the ore body is braided river sand body. The size of uranium deposits is controlled by the local oxidation zone with the characteristics of sandstone type uranium deposit in partial oxidation zone. Uranium ore bodies which distribute in the roof wings of structure fenstes, and occur in gray layers between the upper and lower oxidation zone, showing tabular, and the plate of uranium ore body is controlled by the local oxidation zone. Based on the geological features of sandstone-type uranium deposits, the metallogenic model of local oxidation zones sandstone-type uranium deposits has been set up in the south of Songliao Baisn. (authors)

Magmatic-vapor expansion and the formation of high-sulfidation gold deposits: Chemical controls on alteration and mineralization

Science.gov (United States)

Henley, R.W.; Berger, B.R.

2011-01-01

Large bulk-tonnage high-sulfidation gold deposits, such as Yanacocha, Peru, are the surface expression of structurally-controlled lode gold deposits, such as El Indio, Chile. Both formed in active andesite-dacite volcanic terranes. Fluid inclusion, stable isotope and geologic data show that lode deposits formed within 1500. m of the paleo-surface as a consequence of the expansion of low-salinity, low-density magmatic vapor with very limited, if any, groundwater mixing. They are characterized by an initial 'Sulfate' Stage of advanced argillic wallrock alteration ?? alunite commonly with intense silicification followed by a 'Sulfide' Stage - a succession of discrete sulfide-sulfosalt veins that may be ore grade in gold and silver. Fluid inclusions in quartz formed during wallrock alteration have homogenization temperatures between 100 and over 500 ??C and preserve a record of a vapor-rich environment. Recent data for El Indio and similar deposits show that at the commencement of the Sulfide Stage, 'condensation' of Cu-As-S sulfosalt melts with trace concentrations of Sb, Te, Bi, Ag and Au occurred at > 600 ??C following pyrite deposition. Euhedral quartz crystals were simultaneously deposited from the vapor phase during crystallization of the vapor-saturated melt occurs to Fe-tennantite with progressive non-equilibrium fractionation of heavy metals between melt-vapor and solid. Vugs containing a range of sulfides, sulfosalts and gold record the changing composition of the vapor. Published fluid inclusion and mineralogical data are reviewed in the context of geological relationships to establish boundary conditions through which to trace the expansion of magmatic vapor from source to surface and consequent alteration and mineralization. Initially heat loss from the vapor is high resulting in the formation of acid condensate permeating through the wallrock. This Sulfate Stage alteration effectively isolates the expansion of magmatic vapor in subsurface fracture arrays

Phanerozoic Rifting Phases And Mineral Deposits

Science.gov (United States)

Hassaan, Mahmoud

2016-04-01

In North Africa occur Mediterranean and Red Sea metallogenic provinces. In each province distribute 47 iron- manganese- barite and lead-zinc deposits with tectonic-structural control. The author presents in this paper aspects of position of these deposits in the two provinces with Phanerozoic rifting . The Mediterranean Province belongs to two epochs, Hercynian and Alpine. The Hercynian Epoch manganese deposits in only Moroccoa- Algeria belong to Paleozoic tectonic zones and Proterozoic volcanics. The Alpine Epoch iron-manganese deposits are of post-orogenic exhalative-sedimentary origin. Manganese deposits in southern Morocco occur in Kabil-Rief quartz-chalcedony veins controlled by faults in andesitic sheets and in bedded pelitic tuffs, strata-form lenses and ore veins, in Precambrian schist and in Triassic and Cretaceous dolomites. Disseminated manganese with quartz and barite and effusive hydrothermal veins are hosted in Paleocene volcanics. Manganese deposits in Algeria are limited and unrecorded in Tunisia. Strata-form iron deposits in Atlas Heights are widespread in sub-rift zone among Jurassic sediments inter-bedding volcanic rocks. In Algeria, Group Beni-Saf iron deposits are localized along the Mediterranean coast in terrigenous and carbonate rocks of Jurassic, Cretaceous and Eocene age within faults and bedding planes. In Morocco strata-form hydrothermal lead-zinc deposits occur in contact zone of Tertiary andesite inter-bedding Cambrian shale, Lias dolomites and Eocene andesite. In both Algeria and Tunisia metasomatic Pb-Zn veins occur in Campanian - Maastrichtian carbonates, Triassic breccia, Jurassic limestone, Paleocene sandstones and limestone and Neogene conglomerates and sandstones. The Red Sea metallogenic province belongs to the Late Tertiary-Miocene times. In Wadi Araba hydrothermal iron-manganese deposits occur in Cretaceous sediments within 320°and 310 NW faults related to Tertiary basalt. Um-Bogma iron-manganese deposits are closely

Acid deposition. Origins, impacts and abatement strategies

Energy Technology Data Exchange (ETDEWEB)

Longhurst, J.W.S. (Manchester Polytechnic, Acid Rain Information Centre (United Kingdom). Dept. of Environmental and Geographical Studies) (ed.)

1991-01-01

The subject of acid deposition is one of the most important of our contemporary environmental problems. Presenting and discussing new data on the sources and effects of such deposition, this book seeks to assist in the definition of our future research requirements and policy developments. It is divided into four broad themes: Emissions, Chemistry and Deposition, Ecosystem Effects (freshwater, soils and forest systems), Effects on Structural Materials, and Mitigation, Control and Management. (orig.) With 130 figs.

Trade-Induced Atmospheric Mercury Deposition over China and Implications for Demand-Side Controls.

Science.gov (United States)

Chen, Long; Meng, Jing; Liang, Sai; Zhang, Haoran; Zhang, Wei; Liu, Maodian; Tong, Yindong; Wang, Huanhuan; Wang, Wei; Wang, Xuejun; Shu, Jiong

2018-02-20

Mercury (Hg) is of global concern because of its adverse effects on humans and the environment. In addition to long-range atmospheric transport, Hg emissions can be geographically relocated through economic trade. Here, we investigate the effect of China's interregional trade on atmospheric Hg deposition over China, using an atmospheric transport model and multiregional input-output analysis. In general, total atmospheric Hg deposition over China is 408.8 Mg yr -1 , and 32% of this is embodied in China's interregional trade, with the hotspots occurring over Gansu, Henan, Hebei, and Yunnan provinces. Interprovincial trade considerably redistributes atmospheric Hg deposition over China, with a range in deposition flux from -104% to +28%. Developed regions, such as the Yangtze River Delta (Shanghai, Jiangsu, and Zhejiang) and Guangdong, avoid Hg deposition over their geographical boundaries, instead causing additional Hg deposition over developing provinces. Bilateral interaction among provinces is strong over some regions, suggesting a need for joint mitigation, such as the Jing-Jin-Ji region (Beijing, Tianjin, and Hebei) and the Yangtze River Delta. Transferring advanced technology from developed regions to their developing trade partners would be an effective measure to mitigate China's Hg pollution. Our findings are relevant to interprovincial efforts to reduce trans-boundary Hg pollution in China.

Fault geometry and fluid-rock reaction: Combined controls on mineralization in the Xinli gold deposit, Jiaodong Peninsula, China

Science.gov (United States)

Yang, Lin; Zhao, Rui; Wang, Qingfei; Liu, Xuefei; Carranza, Emmanuel John M.

2018-06-01

The structures and fluid-rock reaction in the Xinli gold deposit, Jiaodong Peninsula, were investigated to further understand their combined controls on the development of permeability associated with ore-forming fluid migration. Orebodies in this deposit are hosted by the moderately SE-to S-dipping Sanshandao-Cangshang fault (SCF). Variations in both dip direction and dip angle along the SCF plane produced fault bends, which controlled the fluid accumulation and ore-shoot formation. Gold mineralizations occurred in early gold-quartz-pyrite and late gold-quartz-polymetallic sulphide stages following pervasive sericitization and silicification alterations. Theoretical calculation indicates that sericitization caused 8-57% volume decrease resulting in the development/enlargement of voids, further increase of grain-scale permeability, and resultant precipitation of the early gold-quartz-pyrite pods, which destroyed permeability. The rock softening produced by alterations promoted activities of SCF secondary faults and formation of new fractures, which rebuilt the permeability and controlled the late gold-quartz-polymetallic sulfide veins. Quantitative studies on permeability distributions show that the southwestern and northeastern bend areas with similar alteration and mineralization have persistent and anti-persistent permeability networks, respectively. These were likely caused by different processes of rebuilding permeability due to different stress states resulting from changes in fault geometry.

Controlling the diameters and field emission properties of vertically aligned carbon nanotubes synthesized by thermal chemical vapor deposition

International Nuclear Information System (INIS)

Choi, Sung Yool; Kang, Young Il; Cho, Kyoung Ik; Choi, Kyu Seok; Kim, Do Jin

2001-01-01

We report here the synthesis of vertically well-aligned carbon nanotubes and the effect of catalytic metal layer on the diameter of grown carbon nanotubes and the field emission characteristics of them, The carbon nanotubes were grown by thermal chemical vapor deposition at temperatures below 900 .deg. C on Fe metal catalytic layer, deposited by sputtering process on a Si substrate and pretreated by heat and NH 3 gas. We found that the thickness of metal layers could be an important parameter in controlling the diameters of carbon nanotubes. With varying the thickness of the metal layers the grain sizes of them also vary so that the diameters of the nanotubes could be controlled. Field emission measurement has been made on the carbon nanotube field emitters at room temperature in a vacuum chamber below 10 -6 Torr. Our vertically aligned carbon nanotube field emitter of the smallest diameter emits a current density about 10 mA/cm 2 at 7.2 V/μm. The field emission property of the carbon nanotubes shows strong dependence on the nanotube diameters as expected

Time variant layer control in atmospheric pressure chemical vapor deposition based growth of graphene

KAUST Repository

Qaisi, Ramy M.; Smith, Casey; Hussain, Muhammad Mustafa

2013-01-01

Graphene is a semi-metallic, transparent, atomic crystal structure material which is promising for its high mobility, strength and transparency - potentially applicable for radio frequency (RF) circuitry and energy harvesting and storage applications. Uniform (same number of layers), continuous (not torn or discontinuous), large area (100 mm to 200 mm wafer scale), low-cost, reliable growth are the first hand challenges for its commercialization prospect. We show a time variant uniform (layer control) growth of bi- to multi-layer graphene using atmospheric chemical vapor deposition system. We use Raman spectroscopy for physical characterization supported by electrical property analysis. © 2013 IEEE.

Time variant layer control in atmospheric pressure chemical vapor deposition based growth of graphene

KAUST Repository

Qaisi, Ramy M.

2013-04-01

Graphene is a semi-metallic, transparent, atomic crystal structure material which is promising for its high mobility, strength and transparency - potentially applicable for radio frequency (RF) circuitry and energy harvesting and storage applications. Uniform (same number of layers), continuous (not torn or discontinuous), large area (100 mm to 200 mm wafer scale), low-cost, reliable growth are the first hand challenges for its commercialization prospect. We show a time variant uniform (layer control) growth of bi- to multi-layer graphene using atmospheric chemical vapor deposition system. We use Raman spectroscopy for physical characterization supported by electrical property analysis. © 2013 IEEE.

Phase control of Mn-based spinel films via pulsed laser deposition

International Nuclear Information System (INIS)

Feng, Zhenxing; Chen, Xiao; Fister, Timothy T.; Bedzyk, Michael J.; Fenter, Paul

2016-01-01

Phase transformations in battery cathode materials during electrochemical-insertion reactions lead to capacity fading and low cycle life. One solution is to keep the same phase of cathode materials during cation insertion-extraction processes. Here, we demonstrate a novel strategy to control the phase and composition of Mn-based spinel oxides for magnesium-ion battery applications through the growth of thin films on lattice-matched substrates using pulsed laser deposition. Materials at two extreme conditions are considered: fully discharged cathode MgMn_2O_4 and fully charged cathode Mn_2O_4. The tetragonal MgMn_2O_4 (MMO) phase is obtained on MgAl_2O_4 substrates, while the cubic MMO phase is obtained on MgO substrates. Similarly, growth of the empty Mn_2O_4 spinel in the cubic phase is obtained on an MgO substrate. These results demonstrate the ability to control separately the phase of spinel thin films (e.g., tetragonal vs. cubic MMO) at nominally fixed composition, and to maintain a fixed (cubic) phase while varying its composition (MgxMn_2O_4, for x = 0, 1). As a result, this capability provides a novel route to gain insights into the operation of battery electrodes for energy storage applications.

Self-Ordering and Complexity in Epizonal Mineral Deposits

Science.gov (United States)

Henley, Richard W.; Berger, Byron R.

Epizonal base and precious metal deposits makeup a range of familiar deposit styles including porphyry copper-gold, epithermal veins and stockworks, carbonate-replacement deposits, and polymetallic volcanic rock-hosted (VHMS) deposits. They occur along convergent plate margins and are invariably associated directly with active faults and volcanism. They are complex in form, variable in their characteristics at all scales, and highly localized in the earth's crust. More than a century of detailed research has provided an extensive base of observational data characterizing these deposits, from their regional setting to the fluid and isotope chemistry of mineral deposition. This has led to a broad understanding of the large-scale hydrothermal systems within which they form. Low salinity vapor, released by magma crystallization and dispersed into vigorously convecting groundwater systems, is recognized as a principal source of metals and the gases that control redox conditions within systems. The temperature and pressure of the ambient fluid anywhere within these systems is close to its vapor-liquid phase boundary, and mineral deposition is a consequence of short timescale perturbations generated by localized release of crustal stress. However, a review of occurrence data raises questions about ore formation that are not addressed by traditional genetic models. For example, what are the origins of banding in epithermal veins, and what controls the frequency of oscillatory lamination? What controls where the phenomenon of mineralization occurs, and why are some porphyry deposits, for example, so much larger than others? The distinctive, self-organized characteristics of epizonal deposits are shown to be the result of repetitive coupling of fracture dilation consequent on brittle failure, phase separation ("boiling"), and heat transfer between fluid and host rock. Process coupling substantially increases solute concentrations and triggers fast, far

Hot-wire chemical vapour deposition of carbon nanotubes

CSIR Research Space (South Africa)

Cummings, FR

2006-07-01

Full Text Available ablation of graphite, carbon-arc discharge and chemical vapour deposition (CVD). However, some of these techniques have been shown to be expensive due to high deposition temperatures and are not easily controllable. Recently hot-wire chemical vapour...

Factors influencing chloride deposition in a coastal hilly area and application to chloride deposition mapping

Directory of Open Access Journals (Sweden)

H. Guan

2010-05-01

Full Text Available Chloride is commonly used as an environmental tracer for studying water flow and solute transport in the environment. It is especially useful for estimating groundwater recharge based on the commonly used chloride mass balance (CMB method. Strong spatial variability in chloride deposition in coastal areas is one difficulty encountered in appropriately applying the method. A high-resolution bulk chloride deposition map in the coastal region is thus needed. The aim of this study is to construct a chloride deposition map in the Mount Lofty Ranges (MLR, a coastal hilly area of approximately 9000 km² spatial extent in South Australia. We examined geographic (related to coastal distance, orographic, and atmospheric factors that may influence chloride deposition, using partial correlation and regression analyses. The results indicate that coastal distance, elevation, as well as terrain aspect and slope, appear to be significant factors controlling chloride deposition in the study area. Coastal distance accounts for 70% of spatial variability in bulk chloride deposition, with elevation, terrain aspect and slope an additional 15%. The results are incorporated into a de-trended residual kriging model (ASOADeK to produce a 1 km×1 km resolution bulk chloride deposition and concentration maps. The average uncertainty of the deposition map is about 20–30% in the western MLR, and 40–50% in the eastern MLR. The maps will form a useful basis for examining catchment chloride balance for the CMB application in the study area.

Matrix shaped pulsed laser deposition: New approach to large area and homogeneous deposition

Energy Technology Data Exchange (ETDEWEB)

Akkan, C.K.; May, A. [INM – Leibniz Institute for New Materials, CVD/Biosurfaces Group, Campus D2 2, 66123 Saarbrücken (Germany); Hammadeh, M. [Department for Obstetrics, Gynecology and Reproductive Medicine, IVF Laboratory, Saarland University Medical Center and Faculty of Medicine, Building 9, 66421 Homburg, Saar (Germany); Abdul-Khaliq, H. [Clinic for Pediatric Cardiology, Saarland University Medical Center and Faculty of Medicine, Building 9, 66421 Homburg, Saar (Germany); Aktas, O.C., E-mail: cenk.aktas@inm-gmbh.de [INM – Leibniz Institute for New Materials, CVD/Biosurfaces Group, Campus D2 2, 66123 Saarbrücken (Germany)

2014-05-01

Pulsed laser deposition (PLD) is one of the well-established physical vapor deposition methods used for synthesis of ultra-thin layers. Especially PLD is suitable for the preparation of thin films of complex alloys and ceramics where the conservation of the stoichiometry is critical. Beside several advantages of PLD, inhomogeneity in thickness limits use of PLD in some applications. There are several approaches such as rotation of the substrate or scanning of the laser beam over the target to achieve homogenous layers. On the other hand movement and transition create further complexity in process parameters. Here we present a new approach which we call Matrix Shaped PLD to control the thickness and homogeneity of deposited layers precisely. This new approach is based on shaping of the incoming laser beam by a microlens array and a Fourier lens. The beam is split into much smaller multi-beam array over the target and this leads to a homogenous plasma formation. The uniform intensity distribution over the target yields a very uniform deposit on the substrate. This approach is used to deposit carbide and oxide thin films for biomedical applications. As a case study coating of a stent which has a complex geometry is presented briefly.

Thermal barrier coatings of rare earth materials deposited by electron beam-physical vapor deposition

Energy Technology Data Exchange (ETDEWEB)

Xu Zhenhua [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); Graduate School of Chinese Academy of Sciences, Beijing 100039 (China); Beijing Institute of Aeronautical Materials, Department 5, P.O. Box 81-5, Beijing 100095 (China); He Limin, E-mail: he_limin@yahoo.co [Beijing Institute of Aeronautical Materials, Department 5, P.O. Box 81-5, Beijing 100095 (China); Chen Xiaolong; Zhao Yu [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); Graduate School of Chinese Academy of Sciences, Beijing 100039 (China); Cao Xueqiang, E-mail: xcao@ciac.jl.c [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China)

2010-10-15

Thermal barrier coatings (TBCs) have very important applications in gas turbines for higher thermal efficiency and protection of components at high temperature. TBCs of rare earth materials such as lanthanum zirconate (La{sub 2}Zr{sub 2}O{sub 7}, LZ), lanthanum cerate (La{sub 2}Ce{sub 2}O{sub 7}, LC), lanthanum cerium zirconate (La{sub 2}(Zr{sub 0.7}Ce{sub 0.3}){sub 2}O{sub 7}, LZ7C3) were prepared by electron beam-physical vapor deposition (EB-PVD). The composition, crystal structure, cross-sectional morphology and cyclic oxidation behavior of these coatings were studied. These coatings have partially deviated from their original compositions due to the different evaporation rates of oxides, and the deviation could be reduced by properly controlling the deposition condition. A double ceramic layer-thermal barrier coatings (DCL-TBCs) of LZ7C3 and LC could also be deposited with a single LZ7C3 ingot by properly controlling the deposition energy. LaAlO{sub 3} is formed due to the chemical reaction between LC and Al{sub 2}O{sub 3} in the thermally grown oxide (TGO) layer. The failure of DCL-TBCs is a result of the sintering-induced of LZ7C3 coating and the chemical incompatibility of LC and TGO. Since no single material that has been studied so far satisfies all the requirements for high temperature applications, DCL-TBCs are an important development direction of TBCs.

Deposit Shedding in Biomass-fired Boilers: Shear Adhesion Strength Measurements

DEFF Research Database (Denmark)

Laxminarayan, Yashasvi; Jensen, Peter Arendt; Wu, Hao

2016-01-01

. Therefore, timely removal of ash deposits is essential for optimal boiler operation. In order to improve the understanding of deposit shedding in boilers, this study investigates the shear adhesion strength of biomass ash deposits on superheater tubes. Artificial biomass ash deposits were prepared...... on superheater tubes and sintered in an oven at temperatures up to 1000 °C. Subsequently, the deposits were sheared off by an electrically controlled arm, and the corresponding adhesion strength was measured. The results reveal the effect of temperature, deposit composition, sintering duration, and steel type...... on the adhesion strength....

Preparation and characterization of thick metastable sputter deposits

International Nuclear Information System (INIS)

Allen, R.P.; Dahlgren, S.D.; Merz, M.D.

1975-01-01

High-rate dc supported-discharge sputtering techniques were developed and used to prepare 0.1 mm to 5.0 mm-thick deposits of a variety of metastable materials including amorphous alloys representing more than 15 different rare-earth-transition metal systems and a wide range of compositions and deposition conditions. The ability to prepare thick, homogeneous deposits has made it possible for the first time to investigate the structure, properties, and annealing behavior of these unique sputtered alloys using neutron diffraction, ultrasonic, and other experimental techniques that are difficult or impractical for thin films. More importantly, these characterization studies show that the structure and properties of the massive sputter deposits are independent of thickness and can be reproduced from deposit to deposit. Other advantages and applications of this metastable materials preparation technique include the possibility of varying structure and properties by control of the deposition parameters and the ability to deposit even reactive alloys with a very low impurity content

Process and system to control manganese and cobalt isotopes deposits from the cooling fluid of a reactor

International Nuclear Information System (INIS)

Brehm, W.F.; McGuire, J.C.

1978-01-01

Process for controlling the deposition of manganese-54, cobalt-58 and cobalt-60 radionuclides on component surfaces, as from a liquid flow containing these nuclides and entering into contact with the surface of these components. It is characterised by the positioning of a getter forming substance in the liquid flow to collect these radionuclides on the getter forming substance which contains at least 73% nickel by weight [fr

Controlled deposition of sol–gel sensor material using hemiwicking

DEFF Research Database (Denmark)

Mikkelsen, Morten Bo Lindholm; Marie, Rodolphe; Hansen, Jan H

2011-01-01

the volume between the surface structures and form a liquid film with a thickness determined by the height of the micropillars. After evaporation of solvents, a uniform layer of sensor material resides on the surface. This fabrication method enables easy and reproducible deposits of isolated spots...

Application of base-level cycles to sandstone-type uranium deposit: taking Dongsheng uranium deposits as an example

International Nuclear Information System (INIS)

Yang Renchao; Han Zuozhen; Fan Aiping; Chang Xiangchun

2006-01-01

High-resolution sequence stratigraphy taking base-level cycles as interface of reference was developed rapidly in recent years. Its greatest predominance lies in that it can be applied to multi-controled continental sedimentary basins and can effectively improve accuracy and distinguishability of sequence stratigraphy analysis. Principles of base-level cycles can also be applied to the research and practice of the exploration and exploitation of sandstone-type uranium deposits as they control the spatial distribution, porosity, the permeability and the sealing ability of sandstone and mudstone, and stacking patterns of strata configuration. Taking Dongsheng uranium deposits as an example, the application of base-level cycles to exploration and exploitation of sandstone uranium deposits was analyzed. It is suggested that favorable strata framework of sandstone and mudstone was developed very well in the fluctuation of base-level cycles. Sand bodies were provided with good connectedness, coarse granularity, high debris content, low matrix content and good porosity-permeability becoming the most important uranium hosted strata. (authors)

Electrospray ionization deposition of BSA under vacuum conditions

Science.gov (United States)

Hecker, Dominic; Gloess, Daniel; Frach, Peter; Gerlach, Gerald

2015-05-01

Vacuum deposition techniques like thermal evaporation and CVD with their precise layer control and high layer purity often cannot be applied for the deposition of chemical or biological molecules. The molecules are usually decomposed by heat. To overcome this problem, the Electrospray ionization (ESI) process known from mass spectroscopy is employed to transfer molecules into vacuum and to deposit them on a substrate. In this work, a homemade ESI tool was used to deposit BSA (Bovine serum albumin) layers with high deposition rates. Solutions with different concentrations of BSA were prepared using a methanol:water (MeOH:H2O) mixture (1:1) as solvent. The influence of the substrate distance on the deposition rate and on the transmission current was analyzed. Furthermore, the layer thickness distribution and layer adhesion were investigated.

Co-depositing Sn controls the growth of Al films as surfactant

International Nuclear Information System (INIS)

Barna, P. B.; Kovacs, A.; Misjak, F.; Eisenmenger-Sittner, C.; Bangert, H.; Tomastik, C.

2002-01-01

The present study investigates the influence of co-deposited Sn on the atomic processes involved in the structure evolution of vapour-deposited Al films. The films were prepared in HV by thermal evaporation from W sources at 1600 C substrate temperature either on Si wafers covered by a thermally grown oxide or on air cleaved mica. By applying the half-shadow technique, pure and Sn-doped Al films could be deposited simultaneously. The samples were investigated by AFM, scanning AES, X-TEM as well as by X-ray diffraction methods. The grain growth of Al is promoted by Sn in all stages of the film formation. Scanning AES measurements prove the existence of a wetting Sn layer both on the surface of Al islands and on the surface of the continuos Al layer. Excess Sn forms islands on the growth surface. The surface of pure Al layers exhibits grain boundary grooves and bunches of growth steps around terraces, while that of the Sn doped layers is more rounded. The substrate-film interface was covered by a thin Sn layer. AES measurements also prove the presence of Sn on the growth surface of Al films even after termination of Sn addition. Results of these experiments indicate that during co-deposition of Al and Sn the impinging Al atoms penetrate the wetting layer and are incorporated into the already existing Al crystals. A model has been developed for describing the growth of Al crystals in the presence Sn. (Authors)

Unconformity-related uranium deposits

International Nuclear Information System (INIS)

Ewers, G.R.; Ferguson, J.

1985-01-01

Documentation of ore deposit characterisation is being undertaken to assess the controls of uranium mineralisation associated with Proterozoic unconformities. The Turee Creek uranium prospect in Western Australia is associated with a faulted contact between the Middle Proterozoic Kunderong Sandstone and the Lower Proterozoic Wyloo Group

Atmospheric nitrogen deposition in the Yangtze River basin: Spatial pattern and source attribution

International Nuclear Information System (INIS)

Xu, Wen; Zhao, Yuanhong; Liu, Xuejun; Dore, Anthony J.; Zhang, Lin; Liu, Lei; Cheng, Miaomiao

2018-01-01

The Yangtze River basin is one of the world's hotspots for nitrogen (N) deposition and likely plays an important role in China's riverine N output. Here we constructed a basin-scale total dissolved inorganic N (DIN) deposition (bulk plus dry) pattern based on published data at 100 observational sites between 2000 and 2014, and assessed the relative contributions of different reactive N (N r ) emission sectors to total DIN deposition using the GEOS-Chem model. Our results show a significant spatial variation in total DIN deposition across the Yangtze River basin (33.2 kg N ha −1 yr −1 on average), with the highest fluxes occurring mainly in the central basin (e.g., Sichuan, Hubei and Hunan provinces, and Chongqing municipality). This indicates that controlling N deposition should build on mitigation strategies according to local conditions, namely, implementation of stricter control of N r emissions in N deposition hotspots but moderate control in the areas with low N deposition levels. Total DIN deposition in approximately 82% of the basin area exceeded the critical load of N deposition for semi-natural ecosystems along the basin. On the basin scale, the dominant source of DIN deposition is fertilizer use (40%) relative to livestock (11%), industry (13%), power plant (9%), transportation (9%), and others (18%, which is the sum of contributions from human waste, residential activities, soil, lighting and biomass burning), suggesting that reducing NH 3 emissions from improper fertilizer (including chemical and organic fertilizer) application should be a priority in curbing N deposition. This, together with distinct spatial variations in emission sector contributions to total DIN deposition also suggest that, in addition to fertilizer, major emission sectors in different regions of the basin should be considered when developing synergistic control measures. - Highlights: • Total DIN deposition fluxes showed a significant spatial variation in the

Ti-doped hydrogenated diamond like carbon coating deposited by hybrid physical vapor deposition and plasma enhanced chemical vapor deposition

Science.gov (United States)

Lee, Na Rae; Sle Jun, Yee; Moon, Kyoung Il; Sunyong Lee, Caroline

2017-03-01

Diamond-like carbon films containing titanium and hydrogen (Ti-doped DLC:H) were synthesized using a hybrid technique based on physical vapor deposition (PVD) and plasma enhanced chemical vapor deposition (PECVD). The film was deposited under a mixture of argon (Ar) and acetylene gas (C2H2). The amount of Ti in the Ti-doped DLC:H film was controlled by varying the DC power of the Ti sputtering target ranging from 0 to 240 W. The composition, microstructure, mechanical and chemical properties of Ti-doped DLC:H films with varying Ti concentrations, were investigated using Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), nano indentation, a ball-on-disk tribometer, a four-point probe system and dynamic anodic testing. As a result, the optimum composition of Ti in Ti-doped DLC:H film using our hybrid method was found to be a Ti content of 18 at. %, having superior electrical conductivity and high corrosion resistance, suitable for bipolar plates. Its hardness value was measured to be 25.6 GPa with a low friction factor.

Controlled Ag electroless deposition in bulk structures with complex three-dimensional profiles

DEFF Research Database (Denmark)

Malureanu, Radu; Zalkovskij, Maksim; Andryieuski, Andrei

2010-01-01

are of high uniformity, having an average roughness of about 4 nm. The characterization of the metal deposition is done using both the scanning electron microscopy technique as well as by atomic force microscope measurements. The electroless technique can be easily implemented, providing the effective...... and reliable metal deposition for fabrication of 3D samples in the broad range of plasmonics and photonics applications....

Acoustic Sample Deposition MALDI-MS (ASD-MALDI-MS): A Novel Process Flow for Quality Control Screening of Compound Libraries.

Science.gov (United States)

Chin, Jefferson; Wood, Elizabeth; Peters, Grace S; Drexler, Dieter M

2016-02-01

In the early stages of drug discovery, high-throughput screening (HTS) of compound libraries against pharmaceutical targets is a common method to identify potential lead molecules. For these HTS campaigns to be efficient and successful, continuous quality control of the compound collection is necessary and crucial. However, the large number of compound samples and the limited sample amount pose unique challenges. Presented here is a proof-of-concept study for a novel process flow for the quality control screening of small-molecule compound libraries that consumes only minimal amounts of samples and affords compound-specific molecular data. This process employs an acoustic sample deposition (ASD) technique for the offline sample preparation by depositing nanoliter volumes in an array format onto microscope glass slides followed by matrix-assisted laser desorption/ionization mass spectrometric (MALDI-MS) analysis. An initial study of a 384-compound array employing the ASD-MALDI-MS workflow resulted in a 75% first-pass positive identification rate with an analysis time of <1 s per sample. © 2015 Society for Laboratory Automation and Screening.

Controlled fluoridation of amorphous carbon films deposited at reactive plasma conditions

Directory of Open Access Journals (Sweden)

Yoffe Alexander

2015-09-01

Full Text Available A study of the correlations between plasma parameters, gas ratios, and deposited amorphous carbon film properties is presented. The injection of a C4F8/Ar/N2 mixture of gases was successfully used in an inductively coupled plasma system for the preparation of amorphous carbon films with different fluoride doping at room-temperature, using silicon as a substrate. This coating was formed at low-pressure and low-energy using an inductively coupled plasma process. A strong dependence between the ratios of gases during deposition and the composition of the substrate compounds was shown. The values of ratios between Ar (or Ar+N2 and C4F8 - 1:1 and between N2 and Ar - 1:2 in the N2/Ar/C4F8 mixture were found as the best for low fluoridated coatings. In addition, an example of improving the etch-passivation in the Bosch procedure was described. Scanning electron microscopy with energy dispersive spectroscopy options, X-ray diffraction, and X-ray reflectivity were used for quantitative analysis of the deposited films.

Atmospheric nitrogen deposition in the Yangtze River basin: Spatial pattern and source attribution.

Science.gov (United States)

Xu, Wen; Zhao, Yuanhong; Liu, Xuejun; Dore, Anthony J; Zhang, Lin; Liu, Lei; Cheng, Miaomiao

2018-01-01

The Yangtze River basin is one of the world's hotspots for nitrogen (N) deposition and likely plays an important role in China's riverine N output. Here we constructed a basin-scale total dissolved inorganic N (DIN) deposition (bulk plus dry) pattern based on published data at 100 observational sites between 2000 and 2014, and assessed the relative contributions of different reactive N (N r ) emission sectors to total DIN deposition using the GEOS-Chem model. Our results show a significant spatial variation in total DIN deposition across the Yangtze River basin (33.2 kg N ha -1 yr -1 on average), with the highest fluxes occurring mainly in the central basin (e.g., Sichuan, Hubei and Hunan provinces, and Chongqing municipality). This indicates that controlling N deposition should build on mitigation strategies according to local conditions, namely, implementation of stricter control of N r emissions in N deposition hotspots but moderate control in the areas with low N deposition levels. Total DIN deposition in approximately 82% of the basin area exceeded the critical load of N deposition for semi-natural ecosystems along the basin. On the basin scale, the dominant source of DIN deposition is fertilizer use (40%) relative to livestock (11%), industry (13%), power plant (9%), transportation (9%), and others (18%, which is the sum of contributions from human waste, residential activities, soil, lighting and biomass burning), suggesting that reducing NH 3 emissions from improper fertilizer (including chemical and organic fertilizer) application should be a priority in curbing N deposition. This, together with distinct spatial variations in emission sector contributions to total DIN deposition also suggest that, in addition to fertilizer, major emission sectors in different regions of the basin should be considered when developing synergistic control measures. Copyright © 2017. Published by Elsevier Ltd.

Nitrogen deposition and prey nitrogen uptake control the nutrition of the carnivorous plant Drosera rotundifolia

Energy Technology Data Exchange (ETDEWEB)

Millett, J., E-mail: j.millett@lboro.ac.uk [Centre for Hydrological and Ecosystem Science, Department of Geography, Loughborough University, Loughborough LE11 3TU (United Kingdom); Foot, G.W. [Centre for Hydrological and Ecosystem Science, Department of Geography, Loughborough University, Loughborough LE11 3TU (United Kingdom); Svensson, B.M. [Department of Plant Ecology and Evolution, Uppsala University, Norbyvägen 18 D, SE-752 36 Uppsala (Sweden)

2015-04-15

Nitrogen (N) deposition has important negative impacts on natural and semi-natural ecosystems, impacting on biotic interactions across trophic levels. Low-nutrient systems are particularly sensitive to changes in N inputs and are therefore more vulnerable to N deposition. Carnivorous plants are often part of these ecosystems partly because of the additional nutrients obtained from prey. We studied the impact of N deposition on the nutrition of the carnivorous plant Drosera rotundifolia growing on 16 ombrotrophic bogs across Europe. We measured tissue N, phosphorus (P) and potassium (K) concentrations and prey and root N uptake using a natural abundance stable isotope approach. Our aim was to test the impact of N deposition on D. rotundifolia prey and root N uptake, and nutrient stoichiometry. D. rotundifolia root N uptake was strongly affected by N deposition, possibly resulting in reduced N limitation. The contribution of prey N to the N contained in D. rotundifolia ranged from 20 to 60%. N deposition reduced the maximum amount of N derived from prey, but this varied below this maximum. D. rotundifolia tissue N concentrations were a product of both root N availability and prey N uptake. Increased prey N uptake was correlated with increased tissue P concentrations indicating uptake of P from prey. N deposition therefore reduced the strength of a carnivorous plant–prey interaction, resulting in a reduction in nutrient transfer between trophic levels. We suggest that N deposition has a negative impact on D. rotundifolia and that responses to N deposition might be strongly site specific. - Highlights: • We measured nutrition of the carnivorous plant Drosera rotundifolia across Europe. • We measured tissue nutrient concentrations and prey and root N uptake at 16 sites. • Tissue N concentrations were a product of root N availability and prey N uptake. • N deposition reduced the maximum amount of N derived from prey. • N deposition reduced the strength of a

Nitrogen deposition and prey nitrogen uptake control the nutrition of the carnivorous plant Drosera rotundifolia

International Nuclear Information System (INIS)

Millett, J.; Foot, G.W.; Svensson, B.M.

2015-01-01

Nitrogen (N) deposition has important negative impacts on natural and semi-natural ecosystems, impacting on biotic interactions across trophic levels. Low-nutrient systems are particularly sensitive to changes in N inputs and are therefore more vulnerable to N deposition. Carnivorous plants are often part of these ecosystems partly because of the additional nutrients obtained from prey. We studied the impact of N deposition on the nutrition of the carnivorous plant Drosera rotundifolia growing on 16 ombrotrophic bogs across Europe. We measured tissue N, phosphorus (P) and potassium (K) concentrations and prey and root N uptake using a natural abundance stable isotope approach. Our aim was to test the impact of N deposition on D. rotundifolia prey and root N uptake, and nutrient stoichiometry. D. rotundifolia root N uptake was strongly affected by N deposition, possibly resulting in reduced N limitation. The contribution of prey N to the N contained in D. rotundifolia ranged from 20 to 60%. N deposition reduced the maximum amount of N derived from prey, but this varied below this maximum. D. rotundifolia tissue N concentrations were a product of both root N availability and prey N uptake. Increased prey N uptake was correlated with increased tissue P concentrations indicating uptake of P from prey. N deposition therefore reduced the strength of a carnivorous plant–prey interaction, resulting in a reduction in nutrient transfer between trophic levels. We suggest that N deposition has a negative impact on D. rotundifolia and that responses to N deposition might be strongly site specific. - Highlights: • We measured nutrition of the carnivorous plant Drosera rotundifolia across Europe. • We measured tissue nutrient concentrations and prey and root N uptake at 16 sites. • Tissue N concentrations were a product of root N availability and prey N uptake. • N deposition reduced the maximum amount of N derived from prey. • N deposition reduced the strength of a

Mineralogical controls on the weathering characteristics of arid continental deposits of the Colorado Plateau

OpenAIRE

Tunheim, Ragnhild Johanne

2015-01-01

The Permian to Jurassic stratigraphy of the Colorado Plateau includes a number of units that were deposited under arid depositional conditions. These units each show distinctive weathering characteristics which cannot solely be attributed to variation in depositional environment or burial history. The stratigraphic units are the Permian Cutler Formation, the Triassic Chinle Formation, the Jurassic Wingate Sandstone, the Kayenta Formation, the Navajo Sandstone, the Slickrock Member and the Moa...

Aerial electrostatic spray deposition and canopy penetration in cotton

Science.gov (United States)

Spray deposition on abaxial and adaxial leaf surfaces along with canopy penetration are essential for insect control and foliage defoliation in cotton production agriculture. Researchers have reported that electrostatically charged sprays have increased spray deposit onto these surfaces under widel...

Factors controlling present-day tufa dynamics in the Monasterio de Piedra Natural Park (Iberian Range, Spain): depositional environmental settings, sedimentation rates and hydrochemistry

Science.gov (United States)

Vázquez-Urbez, M.; Arenas, C.; Sancho, C.; Osácar, C.; Auqué, L.; Pardo, G.

2010-07-01

The tufa record and hydrochemical characteristics of the River Piedra in the Monasterio de Piedra Natural Park (NE Spain) were studied for 6 years. The mean discharge of this river was 1.22 m3/s. The water was supersaturated with calcium carbonate. The HCO3 -, Ca2+ and TDIC concentrations decreased along the 0.5-km-long studied stretch, whereas the calcite SI showed no systematic downstream or seasonal variation over the same stretch. Several sedimentary subenvironments exist in which four broad types of tufa facies form: (1) Dense laminated tufa (stromatolites), (2) Dense to porous, massive tufa, (3) Porous, coarsely laminated tufa with bryophytes and algae, and (4) Dense, hard, laminated deposits in caves. The half-yearly period thickness and weight of sediment accumulated on 14 tablets installed in several subenvironments showed that the deposition rate was greater in fast flowing river areas and in stepped waterfalls, and lower in slow flowing or standing river areas and in spray and splash areas. Mechanical CO2 outgassing is the main factor controlling calcite precipitation on the river bed and in waterfalls, but this process does not explain the seasonal changes in depositional rates. The deposition rates showed a half-yearly period pattern recorded in all fluvial subenvironments persistent over time (5.26 mm, 0.86 g/cm2 in warm periods; 2.26 mm, 0.13 g/cm2 in cool periods). Mass balance calculations showed higher calcite mass values in warm (21.58 mg/L) than in cool (13.68 mg/L) periods. This biannual variation is mainly attributed to the seasonal differences in temperature that caused changes in inorganic calcite precipitation rate and in biomass and the correlative photosynthetic activity. Tufa sedimentation was therefore controlled by both physicochemical and biological processes. The results of this study may help test depositional rates and their environmental controls and thus assess the climatic and hydrological significance of ancient tufas in semi

The origin and control of the Camamu barite deposit (BA)

International Nuclear Information System (INIS)

Campos, E.G.

1984-01-01

Geological and geochemical mechanisms responsible for the origin of the camamu barite deposit (Bahia State) was studied. The marine origin of sulfate is confirmed by the isotopic studies of oxygen delta and sulphur delta. (Author) [pt

Layered ceramic composites via control of electrophoretic deposition kinetics

Czech Academy of Sciences Publication Activity Database

Hadraba, Hynek; Drdlík, D.; Chlup, Zdeněk; Maca, K.; Dlouhý, Ivo; Cihlář, J.

2013-01-01

Roč. 33, č. 12 (2013), s. 2305-2312 ISSN 0955-2219 R&D Projects: GA ČR(CZ) GAP108/11/1644; GA MŠk(CZ) ED1.1.00/02.0068 Institutional support: RVO:68081723 Keywords : Alumina * Zirconia * Laminates * Electrophoretic deposition Subject RIV: JH - Ceramics, Fire-Resistant Materials and Glass Impact factor: 2.307, year: 2013

The uranium deposits of Ontario

International Nuclear Information System (INIS)

Robertson, J.A.

1981-01-01

The principal types of uranium deposits in Ontario are carbonatites and fenites, alkalic volcanic rocks, pegiatites, calc-silicate rocks, pyritic quartz-pebble conglomerates, polymictic conglomerates and some pelitic rocks, and various 'pitchblende' deposits including late Precambrian unconformities, possibly late Precambrian diabase dikes, and other unconformities: carbonates, sandstones, lignites, and semi-pelitic rocks of middle and upper Precambrian age. Only red unzoned pegmatite and the pyritic quartz-pebble conglomerate have supported production. Ontario reasonably assured and estimated resources in the economic and subeconomic categories in 1977 amounted to 553 000 tonnes U, and 1977 production was 4000 tonnes U. Measured, indicated, and inferred resources in the Elliot Lake - Agnew Lake area are at least 400 000 tonnes U. The latter deposits are also a significant thorium resource. Geological features reflecting major changes in physics and chemistry are prime controls on distribution of uranium deposits. Geological province and subprovince boundaries, major faults, higher metamorphic grades, domain boundaries related to quartz monzonite batholiths, alkalic complexes, and the distribution of carbonate rocks are examples of such geological features

Quantification of Gaseous Elemental Mercury Dry Deposition to Environmental Surfaces using Mercury Stable Isotopes in a Controlled Environment

Science.gov (United States)

Rutter, A. P.; Schauer, J. J.; Shafer, M. M.; Olson, M.; Robinson, M.; Vanderveer, P.; Creswell, J. E.; Parman, A.; Mallek, J.; Gorski, P.

2009-12-01

Andrew P. Rutter (1) * *, James J, Schauer (1,2) *, Martin M. Shafer(1,2), Michael R. Olson (1), Michael Robinson (1), Peter Vanderveer (3), Joel Creswell (1), Justin L. Mallek (1), Andrew M. Parman (1) (1) Environmental Chemistry and Technology Program, 660 N. Park St, Madison, WI 53705. (2) Wisconsin State Laboratory of Hygiene, 2601 Agriculture Drive, Madison, WI 53718. (3) Biotron, University of Wisconsin - Madison, 2115 Observatory Drive, Madison, WI 53706 * Correspond author(jjschauer@wisc.edu) * *Presenting author (aprutter@wisc.edu) Abstract Gaseous elemental mercury (GEM) is the predominant component of atmospheric mercury outside of arctic depletion events, and locations where anthropogenic point sources are not influencing atmospheric concentrations. GEM constitutes greater than 99% of the mercury mass in most rural and remote locations. While dry and wet deposition of atmospheric mercury is thought to be dominated by oxidized mercury (a.k.a. reactive mercury), only small GEM uptake to environmental surfaces could impact the input of mercury to terrestrial and aquatic ecosystems. Dry deposition and subsequent re-emission of gaseous elemental mercury is a pathway from the atmosphere that remains only partially understood from a mechanistic perspective. In order to properly model GEM dry deposition and re-emission an understanding of its dependence on irradiance, temperature, and relative humidity must be measured and parameterized for a broad spectrum of environmental surfaces colocated with surrogate deposition surfaces used to make field based dry deposition measurements. Measurements of isotopically enriched GEM dry deposition were made with a variety of environmental surfaces in a controlled environment room at the University of Wisconsin Biotron. The experimental set up allowed dry deposition components which are not easily separated in the field to be decoupled. We were able to isolate surface transfer processes from variabilities caused by

Long-term controls on continental-scale bedrock river terrace deposition from integrated clast and heavy mineral assemblage analysis: An example from the lower Orange River, Namibia

Science.gov (United States)

Nakashole, Albertina N.; Hodgson, David M.; Chapman, Robert J.; Morgan, Dan J.; Jacob, Roger J.

2018-02-01

Establishing relationships between the long-term landscape evolution of drainage basins and the fill of sedimentary basins benefits from analysis of bedrock river terrace deposits. These fragmented detrital archives help to constrain changes in river system character and provenance during sediment transfer from continents (source) to oceans (sink). Thick diamondiferous gravel terrace deposits along the lower Orange River, southern Namibia, provide a rare opportunity to investigate controls on the incision history of a continental-scale bedrock river. Clast assemblage and heavy mineral data from seven localities permit detailed characterisation of the lower Orange River gravel terrace deposits. Two distinct fining-upward gravel terrace deposits are recognised, primarily based on mapped stratigraphic relationships (cross-cutting relationships) and strath and terrace top elevations, and secondarily on the proportion of exotic clasts, referred to as Proto Orange River deposits and Meso Orange River deposits. The older early to middle Miocene Proto Orange River gravels are thick (up to 50 m) and characterised by a dominance of Karoo Supergroup shale and sandstone clasts, whereas the younger Plio-Pleistocene Meso Orange River gravels (6-23 m thick) are characterised by more banded iron formation clasts. Mapping of the downstepping terraces indicates that the Proto gravels were deposited by a higher sinuosity river, and are strongly discordant to the modern Orange River course, whereas the Meso deposits were deposited by a lower sinuosity river. The heavy minerals present in both units comprise magnetite, garnet, amphibole, epidote and ilmenite, with rare titanite and zircon grains. The concentration of amphibole-epidote in the heavy minerals fraction increases from the Proto to the Meso deposits. The decrease in incision depths, recorded by deposit thicknesses above strath terraces, and the differences in clast character (size and roundness) and type between the two

Powder Flux Regulation in the Laser Material Deposition Process

Science.gov (United States)

Arrizubieta, Jon Iñaki; Wegener, Maximiliam; Arntz, Kristian; Lamikiz, Aitzol; Ruiz, Jose Exequiel

In the present research work a powder flux regulation system has been designed, developed and validated with the aim of improving the Laser Material Deposition (LMD) process. In this process, the amount of deposited material per substrate surface unit area depends on the real feed rate of the nozzle. Therefore, a regulation system based on a solenoid valve has been installed at the nozzle entrance in order to control the powder flux. The powder flux control has been performed based on the machine real feed rate, which is compared with the programmed feed rate. An instantaneous velocity error is calculated and the powder flow is controlled as a function of this variation using Pulse Width Modulation (PWM) signals. Thereby, in zones where the Laser Material Deposition machine reduces the feed rate due to a trajectory change, powder accumulation can be avoided and the generated clads would present a homogeneous shape.

Does deposition depth control the OSL bleaching of fluvial sediment?

NARCIS (Netherlands)

Cunningham, A. C.; Wallinga, J.; Hobo, N.; Versendaal, A. J.; Makaske, B.; Middelkoop, H.

2014-01-01

The Optically Stimulated Luminescence (OSL) signal from fluvial sediment often contains a remnant from the previous deposition cycle, leading to a partially bleached equivalent-dose distribution. Although identification of the burial dose is of primary concern, the degree of bleaching could

X-ray amplifier energy deposition scaling with channeled propagation

International Nuclear Information System (INIS)

Boyer, K.; Luk, T.S.; McPherson, A.

1991-01-01

The spatial control of the energy deposited for excitation of an x-ray amplifier plays an important role in the fundamental scaling relationship between the required energy, the gain and the wavelength. New results concerning the ability to establish confined modes of propagation of sort pulse radiation of sufficiently high intensity in plasmas lead to a sharply reduced need for the total energy deposited, since the concentration of deposited power can be very efficiently organized

Chemistry of plasma-polymerized vinyltriethoxysilane controlled by deposition conditions

Czech Academy of Sciences Publication Activity Database

Čech, V.; Zemek, Josef; Peřina, Vratislav

2008-01-01

Roč. 5, č. 8 (2008), s. 745-752 ISSN 1612-8850 Grant - others:GAČR(CZ) GA104/06/0437 Institutional research plan: CEZ:AV0Z10100521; CEZ:AV0Z10480505 Keywords : ESCA/XPS * FTIR * plasma-enhanced chemical vapor deposition (PECVD) * Rutherford back-scattering (RBS) * thin films Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.921, year: 2008

Model boiler studies on deposition and corrosion

International Nuclear Information System (INIS)

Balakrishnan, P.V.; McVey, E.G.

1977-09-01

Deposit formation was studied in a model boiler, with sea-water injections to simulate the in-leakage which could occur from sea-water cooled condensers. When All Volatile Treatment (AVT) was used for chemistry control the deposits consisted of the sea-water salts and corrosion products. With sodium phosphate added to the boiler water, the deposits also contained the phosphates derived from the sea-water salts. The deposits were formed in layers of differing compositions. There was no significant corrosion of the Fe-Ni-Cr alloy boiler tube under deposits, either on the open area of the tube or in crevices. However, carbon steel that formed a crevice around the tube was corroded severely when the boiler water did not contain phosphate. The observed corrosion of carbon steel was caused by the presence of acidic, highly concentrated chloride solution produced from the sea-water within the crevice. Results of theoretical calculations of the composition of the concentrated solution are presented. (author)

20 CFR 703.306 - Kinds of negotiable securities that may be deposited; conditions of deposit; acceptance of deposits.

Science.gov (United States)

2010-04-01

... the Act in the amount fixed by the Office under the regulations in this part shall deposit any... deposited; conditions of deposit; acceptance of deposits. 703.306 Section 703.306 Employees' Benefits... negotiable securities that may be deposited; conditions of deposit; acceptance of deposits. A self-insurer or...

Principal types of precambrian uranium-gold deposits and their metallogenetic characteristics in China

International Nuclear Information System (INIS)

Liang Liang; Zhong Zhiyun.

1988-01-01

Principal types of Precambrian uranium-gold deposits are follows: paleo-conglomerate uranium-deposit, stratified or strata-bound uranium-gold deposit, unconformity-related uranium deposit (no or seldem gold) and greenstone gold deposit. The main types of gold deposits in China is greenstone one which is characterized by later age, high grade metamorphism and a large time difference between diagenesis of host rocks and gold metallogenesis. Gold deposits are spatially distributed in the uplift area, whereas uranium deposits are distributed in the downfaulted belt. Furthermore, both uranium and gold deposits are controlled by regional fractures

Tsunami deposits

Energy Technology Data Exchange (ETDEWEB)

NONE

2013-08-15

The NSC (the Nuclear Safety Commission of Japan) demand to survey on tsunami deposits by use of various technical methods (Dec. 2011), because tsunami deposits have useful information on tsunami activity, tsunami source etc. However, there are no guidelines on tsunami deposit survey in JAPAN. In order to prepare the guideline of tsunami deposits survey and evaluation and to develop the method of tsunami source estimation on the basis of tsunami deposits, JNES carried out the following issues; (1) organizing information of paleoseismological record and tsunami deposit by literature research, (2) field survey on tsunami deposit, and (3) designing the analysis code of sediment transport due to tsunami. As to (1), we organize the information gained about tsunami deposits in the database. As to (2), we consolidate methods for surveying and identifying tsunami deposits in the lake based on results of the field survey in Fukui Pref., carried out by JNES. In addition, as to (3), we design the experimental instrument for hydraulic experiment on sediment transport and sedimentation due to tsunamis. These results are reflected in the guideline on the tsunami deposits survey and evaluation. (author)

Tsunami deposits

International Nuclear Information System (INIS)

2013-01-01

The NSC (the Nuclear Safety Commission of Japan) demand to survey on tsunami deposits by use of various technical methods (Dec. 2011), because tsunami deposits have useful information on tsunami activity, tsunami source etc. However, there are no guidelines on tsunami deposit survey in JAPAN. In order to prepare the guideline of tsunami deposits survey and evaluation and to develop the method of tsunami source estimation on the basis of tsunami deposits, JNES carried out the following issues; (1) organizing information of paleoseismological record and tsunami deposit by literature research, (2) field survey on tsunami deposit, and (3) designing the analysis code of sediment transport due to tsunami. As to (1), we organize the information gained about tsunami deposits in the database. As to (2), we consolidate methods for surveying and identifying tsunami deposits in the lake based on results of the field survey in Fukui Pref., carried out by JNES. In addition, as to (3), we design the experimental instrument for hydraulic experiment on sediment transport and sedimentation due to tsunamis. These results are reflected in the guideline on the tsunami deposits survey and evaluation. (author)

Technologies for the control of fat and lean deposition in livestock.

Science.gov (United States)

Sillence, M N

2004-05-01

by the poor level of control over gene expression, and faces an uphill battle over consumer acceptance. There are several alternatives to HGPs and transgenics, that are more likely to gain world-wide acceptance. Genetic selection can be enhanced by using markers for polymorphic genes that control fat and lean, such as thyroglobulin, or the callipyge gene. Feed additives of natural origin, such as betaine, chromium and conjugated linoleic acid, can improve the fat:lean ratio under specific circumstances. Additionally, 'production vaccines' have been developed, which alter the neuro-endocrine system by causing an auto-immune response. Thus, antibodies have been used to neutralise growth-limiting factors, prolong the half-life of anabolic hormones, or activate hormone receptors directly. Unfortunately, none of these technologies is sufficiently well advanced yet to rival the use of exogenous HGPs in terms of efficacy and reliability. Therefore, further research is needed to find ways to control fat and lean deposition with due consideration of industry needs, animal welfare and consumer requirements.

Atomic layer deposition of a MoS₂ film.

Science.gov (United States)

Tan, Lee Kheng; Liu, Bo; Teng, Jing Hua; Guo, Shifeng; Low, Hong Yee; Tan, Hui Ru; Chong, Christy Yuen Tung; Yang, Ren Bin; Loh, Kian Ping

2014-09-21

A mono- to multilayer thick MoS₂ film has been grown by using the atomic layer deposition (ALD) technique at 300 °C on a sapphire wafer. ALD provides precise control of the MoS₂ film thickness due to pulsed introduction of the reactants and self-limiting reactions of MoCl₅ and H₂S. A post-deposition annealing of the ALD-deposited monolayer film improves the crystallinity of the film, which is evident from the presence of triangle-shaped crystals that exhibit strong photoluminescence in the visible range.

Control of crystal structure, morphology and optical properties of ceria films by post deposition annealing treatments

International Nuclear Information System (INIS)

Eltayeb, Asmaa; Vijayaraghavan, Rajani K.; McCoy, Anthony P.; Cullen, Joseph; Daniels, Stephen; McGlynn, Enda

2016-01-01

In this paper, the effects of post-deposition annealing temperature and atmosphere on the properties of pulsed DC magnetron sputtered ceria (CeO_2) thin films, including crystalline structure, grain size and shape and optical properties were investigated. Experimental results, obtained from X-ray diffraction (XRD), showed that the prepared films crystallised predominantly in the CeO_2 cubic fluorite structure, although evidence of Ce_2O_3 was also seen and this was quantified by a Rietveld refinement. The anneal temperature and oxygen content of the Ar/O_2 annealing atmosphere both played important roles on the size and shape of the nanocrystals as determined by atomic force microscopy (AFM). The average grain size (determined by an AFM) as well as the out of plane coherence length (obtained from XRD) varied with increasing oxygen flow rate (OFR) in the annealing chamber. In addition, the shape of the grains seen in the AFM studies transformed from circular to triangular as the OFR was raised from 20 sccm to 30 sccm during an 800 °C thermal anneal. X-ray photoelectron spectroscopy was used to measure near-surface oxidation states of the thin-films with varying OFR in the annealing chamber. The bandgap energies were estimated from the ultra-violet and visible absorption spectra and low-temperature photoluminescence. An extracted bandgap value of 3.04 eV was determined for as-deposited CeO_2 films and this value increased with increasing annealing temperatures. However, no difference was observed in bandgap energies with variation of annealing atmosphere. - Highlights: • Deposition of ceria thin films by pulsed DC magnetron sputtering • Effect of annealing temperature and gas ambient on film crystalline structure • Evidence for control of the film roughness and grain size and shape is achieved. • Investigation of the effect of post-deposition annealing on the film stoichiometry • Films showed blue shifts in bandgap energies with increasing annealing

Impact of future Arctic shipping on high-latitude black carbon deposition (Invited)

Science.gov (United States)

Corbett, J. J.; Browse, J.; Carslaw, K. S.; Schmidt, A.

2013-12-01

The retreat of Arctic sea-ice has led to renewed calls to exploit Arctic shipping routes. The diversion of ship traffic through the Arctic will shorten shipping routes and possibly reduce global shipping emissions. However, deposition of black carbon (BC) aerosol emitted by additional Arctic ships could cause a reduction in the albedo of snow and ice, accelerating snow-melt and sea-ice loss. We use recently compiled Arctic shipping emission inventories for 2004 and 2050 together with a global aerosol microphysics model GLOMAP coupled to the chemical transport model TOMCAT to quantify the contribution of future Arctic shipping to high-latitude BC deposition. Emission rates of SOx (SO2 and SO4) and particulate matter (PM) were estimated for 2050 under both business-as-usual and high-growth scenarios. BC particles are assumed to be water-insoluble at emission but can become active in cloud drop formation through soluble material accumulation. After BC particles become cloud-active they are more efficiently wet scavenged, which accounts for 80% of modeled BC deposition. Current-day Arctic shipping contributes 0.3% to the BC mass deposited north of 60N (250 Gg). About 50% of modelled BC deposition is on open ocean, suggesting that current Arctic ship traffic may not significantly contribute to BC deposition on central Arctic sea ice. However, 6 - 8% of deposited BC on the west coast of Greenland originates from local ship traffic. Moreover, in-Arctic shipping contributes some 32% to high-latitude ship-sourced deposition despite accounting for less than 1.0% of global shipping emissions. This suggests that control of in-Arctic shipping BC emissions could yield greater decrease in high-latitude BC deposition than a similar control strategy applied only to the extra-Arctic shipping industry. Arctic shipping in 2050 will contribute less than 1% to the total BC deposition north of 60N due to the much greater relative contribution of BC transported from non-shipping sources

Co-deposition of metallic actinides on a solid cathode

Energy Technology Data Exchange (ETDEWEB)

Limmer, S. J.; Williamson, M. A.; Willit, J. L. [Argonne National Laboratory, Argonne (United States)

2008-08-15

The amount of rare earth contamination that will be found in a co-deposit of actinides is a function of the type of cathode used. A non-alloying solid cathode will result in a significantly lower rare earth contamination in the actinide co-deposit than a liquid cadmium cathode. With proper control of the cathode potential vs. a stable reference electrode, co-deposition of uranium with other more electroactive metals has been demonstrated using a non-alloying solid cathode.

Co-deposition of metallic actinides on a solid cathode

International Nuclear Information System (INIS)

Limmer, S. J.; Williamson, M. A.; Willit, J. L.

2008-01-01

The amount of rare earth contamination that will be found in a co-deposit of actinides is a function of the type of cathode used. A non-alloying solid cathode will result in a significantly lower rare earth contamination in the actinide co-deposit than a liquid cadmium cathode. With proper control of the cathode potential vs. a stable reference electrode, co-deposition of uranium with other more electroactive metals has been demonstrated using a non-alloying solid cathode

Electrochemical deposition of mineralized BSA/collagen coating

Energy Technology Data Exchange (ETDEWEB)

Zhuang, Junjun [School of Materials Science and Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027 (China); Lin, Jun; Li, Juan; Wang, Huiming [The First Affiliated Hospital of Medical College, Zhejiang University, Hangzhou 310003 (China); Cheng, Kui [School of Materials Science and Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027 (China); Weng, Wenjian, E-mail: wengwj@zju.edu.cn [School of Materials Science and Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027 (China); The Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China)

2016-09-01

In this work, mineralized collagen coatings with different loading quantity of bovine serum albumin (BSA) were prepared via in situ electrochemical deposition on titanium substrate. The microstructure and BSA loading quantity of the coatings could be controlled by the electrochemical deposition parameters, such as deposition potential, BSA concentration and its adding sequence in the electrolyte. The BSA loading quantity in the coatings was obtained in the range of 0.0170–0.173 mg/cm{sup 2}, enhancing the cell adhesion and proliferation of the coatings with the simultaneous release. The distinct release behaviors of BSA were attributed to their gradient distribution with different mineralization degrees, which could be adjusted by the deposition process. These results suggest that in situ electrochemical deposition is a promising way to incorporate functional molecules into the mineralized collagen coatings and the mineralized BSA/collagen coatings are highly promising for improving the rhBMP-2 loading capability (1.8-fold). - Highlights: • BSA is incorporated into mineralized collagen coating by electrochemical deposition. • The loading amount of BSA in coatings can be adjusted in the range of 0-173 ng. • The BSA/collagen coating shows good cytocompatibility with free-albumin culture. • The incorporation process is put forward for some other molecules deposition.

Self-limiting atomic layer deposition of conformal nanostructured silver films

International Nuclear Information System (INIS)

Golrokhi, Zahra; Chalker, Sophia; Sutcliffe, Christopher J.; Potter, Richard J.

2016-01-01

Graphical abstract: - Highlights: • We grow metallic silver by direct liquid injection thermal atomic layer deposition. • Highly conformal silver nanoparticle coatings on high aspect ratio surfaces. • An ALD temperature growth window between 123 and 128 °C is established. • ALD cycles provides sub nanometre control of silver growth. • Catalytic dehydrogenation ALD mechanism has been elucidated by in-situ QCM. - Abstract: The controlled deposition of ultra-thin conformal silver nanoparticle films is of interest for applications including anti-microbial surfaces, plasmonics, catalysts and sensors. While numerous techniques can produce silver nanoparticles, few are able to produce highly conformal coatings on high aspect ratio surfaces, together with sub-nanometre control and scalability. Here we develop a self-limiting atomic layer deposition (ALD) process for the deposition of conformal metallic silver nanoparticle films. The films have been deposited using direct liquid injection ALD with ((hexafluoroacetylacetonato)silver(I)(1,5-cyclooctadiene)) and propan-1-ol. An ALD temperature window between 123 and 128 °C is identified and within this range self-limiting growth is confirmed with a mass deposition rate of ∼17.5 ng/cm"2/cycle. The effects of temperature, precursor dose, co-reactant dose and cycle number on the deposition rate and on the properties of the films have been systematically investigated. Under self-limiting conditions, films are metallic silver with a nano-textured surface topography and nanoparticle size is dependent on the number of ALD cycles. The ALD reaction mechanisms have been elucidated using in-situ quartz crystal microbalance (QCM) measurements, showing chemisorption of the silver precursor, followed by heterogeneous catalytic dehydrogenation of the alcohol to form metallic silver and an aldehyde.

Trace elements in tourmalines from massive sulfide deposits and tourmalinites: Geochemical controls and exploration applications

Science.gov (United States)

Griffin, W.L.; Slack, J.F.; Ramsden, A.R.; Win, T.T.; Ryan, C.G.

1996-01-01

Trace element contents of tourmalines from massive sulfide deposits and tourmalinites have been determined in situ by proton microprobe; >390 analyses were acquired from 32 polished thin sections. Concentrations of trace elements in the tourmalines vary widely, from Sr, Ba, and Ca). Base metal proportions in the tourmalines show systematic patterns on ternary Cu-Pb-Zn diagrams that correlate well with the major commodity metals in the associated massive sulfide deposits. For example, data for tourmalines from Cu-Zn deposits (e.g., Ming mine, Newfoundland) fall mainly on the Cu-Zn join, whereas those from Pb-Zn deposits (e.g., Broken Hill, Australia) plot on the Pb-Zn join; no data fall on the Cu-Pb join, consistent with the lack of this metal association in massive sulfide deposits. The systematic relationship between base metal proportions in the tourmalines and the metallogeny of the host massive sulfide deposits indicates that the analyzed tourmalines retain a strong chemical signature of their original hydrothermal formation, in spite of variable metamorphic recrystallization. Such trace element patterns in massive sulfide tourmalines may be useful in mineral exploration, specifically for the evaluation of tourmaline concentrations in rocks, soils, and stream sediments.

The Setup Design for Selective Laser Sintering of High-Temperature Polymer Materials with the Alignment Control System of Layer Deposition

Directory of Open Access Journals (Sweden)

Alexey Nazarov

2018-03-01

Full Text Available This paper presents the design of an additive setup for the selective laser sintering (SLS of high-temperature polymeric materials, which is distinguished by an original control system for aligning the device for depositing layers of polyether ether ketone (PEEK powder. The kinematic and laser-optical schemes are given. The main cooling circuits are described. The proposed technical and design solutions enable conducting the SLS process in different types of high-temperature polymer powders. The principles of the device adjustment for depositing powder layers based on an integral thermal analysis are disclosed. The PEEK sinterability was shown on the designed installation. The physic-mechanical properties of the tested 3D parts were evaluated in comparison with the known data and showed an acceptable quality.

Recent advances in controlled synthesis of two-dimensional transition metal dichalcogenides via vapour deposition techniques

KAUST Repository

Shi, Yumeng; Li, Henan; Li, Lain-Jong

2014-01-01

In recent years there have been many breakthroughs in two-dimensional (2D) nanomaterials, among which the transition metal dichalcogenides (TMDs) attract significant attention owing to their unusual properties associated with their strictly defined dimensionalities. TMD materials with a generalized formula of MX2, where M is a transition metal and X is a chalcogen, represent a diverse and largely untapped source of 2D systems. Semiconducting TMD monolayers such as MoS2, MoSe2, WSe2 and WS2 have been demonstrated to be feasible for future electronics and optoelectronics. The exotic electronic properties and high specific surface areas of 2D TMDs offer unlimited potential in various fields including sensing, catalysis, and energy storage applications. Very recently, the chemical vapour deposition technique (CVD) has shown great promise to generate high-quality TMD layers with a scalable size, controllable thickness and excellent electronic properties. Wafer-scale deposition of mono to few layer TMD films has been obtained. Despite the initial success in the CVD synthesis of TMDs, substantial research studies on extending the methodology open up a new way for substitution doping, formation of monolayer alloys and producing TMD stacking structures or superlattices. In this tutorial review, we will introduce the latest development of the synthesis of monolayer TMDs by CVD approaches.

Recent advances in controlled synthesis of two-dimensional transition metal dichalcogenides via vapour deposition techniques

KAUST Repository

Shi, Yumeng

2014-10-20

In recent years there have been many breakthroughs in two-dimensional (2D) nanomaterials, among which the transition metal dichalcogenides (TMDs) attract significant attention owing to their unusual properties associated with their strictly defined dimensionalities. TMD materials with a generalized formula of MX2, where M is a transition metal and X is a chalcogen, represent a diverse and largely untapped source of 2D systems. Semiconducting TMD monolayers such as MoS2, MoSe2, WSe2 and WS2 have been demonstrated to be feasible for future electronics and optoelectronics. The exotic electronic properties and high specific surface areas of 2D TMDs offer unlimited potential in various fields including sensing, catalysis, and energy storage applications. Very recently, the chemical vapour deposition technique (CVD) has shown great promise to generate high-quality TMD layers with a scalable size, controllable thickness and excellent electronic properties. Wafer-scale deposition of mono to few layer TMD films has been obtained. Despite the initial success in the CVD synthesis of TMDs, substantial research studies on extending the methodology open up a new way for substitution doping, formation of monolayer alloys and producing TMD stacking structures or superlattices. In this tutorial review, we will introduce the latest development of the synthesis of monolayer TMDs by CVD approaches.

Design of tunable ultraviolet (UV) absorbance by controlling the Agsbnd Al co-sputtering deposition

Science.gov (United States)

Zhang, Xin-Yuan; Chen, Lei; Wang, Yaxin; Zhang, Yongjun; Yang, Jinghai; Choi, Hyun Chul; Jung, Young Mee

2018-05-01

Changing the structure and composition of a material can alter its properties; hence, the controlled fabrication of metal nanostructures plays a key role in a wide range of applications. In this study, the structure of Agsbnd Al ordered arrays fabricated by co-sputtering deposition onto a monolayer colloidal crystal significantly increased its ultraviolet (UV) absorbance owing to a tunable localized surface plasmon resonance (LSPR) effect. By increasing the spacing between two nanospheres and the content of aluminum, absorbance in the UV region could be changed from UVA (320-400 nm) to UVC (200-275 nm), and the LSPR peak in the visible region gradually shifted to the UV region. This provides the potential for surface-enhanced Raman scattering (SERS) in both the UV and visible regions.

Perovskite Thin Films via Atomic Layer Deposition

KAUST Repository

Sutherland, Brandon R.; Hoogland, Sjoerd; Adachi, Michael M.; Kanjanaboos, Pongsakorn; Wong, Chris T. O.; McDowell, Jeffrey J.; Xu, Jixian; Voznyy, Oleksandr; Ning, Zhijun; Houtepen, Arjan J.; Sargent, Edward H.

2014-01-01

© 2014 Wiley-VCH Verlag GmbH & Co. KGaA. (Graph Presented) A new method to deposit perovskite thin films that benefit from the thickness control and conformality of atomic layer deposition (ALD) is detailed. A seed layer of ALD PbS is place-exchanged with PbI2 and subsequently CH3NH3PbI3 perovskite. These films show promising optical properties, with gain coefficients of 3200 ± 830 cm-1.

Perovskite Thin Films via Atomic Layer Deposition

KAUST Repository

Sutherland, Brandon R.

2014-10-30

© 2014 Wiley-VCH Verlag GmbH & Co. KGaA. (Graph Presented) A new method to deposit perovskite thin films that benefit from the thickness control and conformality of atomic layer deposition (ALD) is detailed. A seed layer of ALD PbS is place-exchanged with PbI2 and subsequently CH3NH3PbI3 perovskite. These films show promising optical properties, with gain coefficients of 3200 ± 830 cm-1.

Factors controlling localization of uranium deposits in the Dakota Sandstone, Gallup and Ambrosia Lake mining districts, McKinley County, New Mexico

Science.gov (United States)

Pierson, Charles Thomas; Green, Morris W.

1977-01-01

Geologic studies were made at all of the uranium mines and prospects in the Dakota Sandstone of Early(?) and Late Cretaceous age in the Gallup mining district, McKinley County, New Mexico. Dakota mines in the adjacent Ambrosia Lake mining district were visited briefly for comparative purposes. Mines in the eastern part of the Gallup district, and in the Ambrosia Lake district, are on the Chaco slope of the southern San Juan Basin in strata which dip gently northward toward the central part of the basin. Mines in the western part of the Gallup district are along the Gallup hogback (Nutria monocline) in strata which dip steeply westward into the Gallup sag. Geologic factors which controlled formation of the uranium deposits in the Dakota Sandstone are: (1) a source of uranium, believed to be uranium deposits of the underlying Morrison Formation of Late Jurassic age; (2) the accessibility to the Dakota of uranium-bearing solutions from the Morrison; (3) the presence in the Dakota of permeable sandstone beds overlain by impermeable carbonaceous shale beds; and (4) the occurrence within the permeable Dakota sandstone beds of carbonaceous reducing material as bedding-plane laminae, or as pockets of carbonaceous trash. Most of the Dakota uranium deposits are found in the lower part of the formation in marginal-marine distributary-channel sandstones which were deposited in the backshore environment. However, the Hogback no. 4 (Hyde) Mine (Gallup district) occurs in sandy paludal shale of the backshore environment, and another deposit, the Silver Spur (Ambrosia Lake district), is found in what is interpreted to be a massive beach or barrier-bar sandstone of the foreshore environment in the upper part of the Dakota. The sedimentary depositional environment most favorable for the accumulation of uranium is that of backshore areas lateral to main distributary channels, where levee, splay, and some distributary-channel sandstones intertongue with gray carbonaceous shales and

A review of unconformity-type uranium deposits

International Nuclear Information System (INIS)

Dabrowski, F.A.

1980-01-01

Intense interest in uranium in the past decade has led to the discovery of new kinds of deposits of which the so-called unconformity-type are economically the most important. Presently known occurrences are restricted to Australia and Canada where they are characterized chiefly by their spatial relationship to Lower-Middle Proterozoic unconformities. Other common features include similar host-rock assemblages, structural controls, alteration, mineralogy, age relationships and fluid-inclusion data. Similar characteristics in other vein-type deposits, including those of the Beaverlodge district in Canada, deposits in France and Portugal, and the Schwartzwalder mine in the United States, suggest that they may also be of the unconformity-type. Various interpretations of the geological relationships of unconformity-type deposits have resulted in a number of genetic hypotheses, which require different exploration philosophies. Near-surface supergene processes are considered to be most important although other mechanisms may have played contributing roles in the concentration of uranium. There is considerable potential for further discoveries of unconformity-type uranium deposits throughout the world. No such deposits are yet known in southern Africa although several favourable Precambrian unconformities are present

Precise control of multiwall carbon nanotube diameters using thermal chemical vapor deposition

Science.gov (United States)

Siegal, M. P.; Overmyer, D. L.; Provencio, P. P.

2002-03-01

We grow multiwall carbon nanotube (CNT) films using thermal chemical vapor deposition at atmospheric pressure using a mixture of acetylene and nitrogen from a 4-nm-thick Ni film catalyst. CNTs are characterized using electron microscopy and Rutherford backscattering spectrometry. CNTs grown with this method are extremely uniform in diameter, both throughout the sample and within the lengths of individual tubes. Nanotube outer diameters, ranging from 5-350 nm, and the total deposition of carbon material, increase exponentially with growth temperature from 630 °C-790 °C.

On the characteristics of metallotect features and origin of Chanziping uranium deposit

International Nuclear Information System (INIS)

Kang Zili; Liu Haiying

1991-01-01

Chanziping Uranium Deposit is one of the representative uranium deposits which lie in the Lower Cambrian Qingxi Formation in China, Chiefly composed of black shale formation. The mineralization is largely controlled by the U-rich strata and bedding-plane faults. The former is the source of ore and ore-bearing wallrock; the latter controls the distributions of ore bodies, and is the source of force for remobilization, and mineralization of uranium and other metallogenetic elements. The formation of this deposit approximately undergoes the following 4 stages: 1. Preliminary enrichment of sedimentary uranium source layer in the Qingxi Formation; 2. Further uranium enrichment during the deformation and metamorphism of strata; 3. Formation of hydrothermal (thermal water) uranium deposit (main metallogenetic epoch) due to dynamic differentation and thermodynamic metamorphism; 4. Formation of rich multiple ore bodies due to the secondary leaching and enrichment. Then, the deposit, which contains strata-bound features, becomes a polygenetic compound uranium deposit. These characteristics may be used as the rules for searching for uranium deposits of this type

Evaluating the effectiveness of pollution control measures via the occurrence of DDTs and HCHs in wet deposition of an urban center, China.

Science.gov (United States)

Guo, Ling-Chuan; Bao, Lian-Jun; Li, Shao-Meng; Tao, Shu; Zeng, Eddy Y

2017-04-01

Wet deposition is not only a mechanism for removing atmospheric pollutants, but also a process which reflects loadings of atmospheric pollutants. Our previous study on wet deposition examined the effectiveness of short-term control measures on atmospheric particulate pollution, which were partly effective for organic pollutants of current input sources. In the present study, dichlorodiphenyltrichloroethanes (DDTs) and hexachlorocyclohexanes (HCHs), representative of legacy contaminants, were measured in the same samples collected throughout the entire year of 2010 in Guangzhou, a large urban center in South China. Concentrations of ∑DDT (sum of o,p' and p,p'-DDT, o,p' and p,p'-DDE, o,p' and p,p'-DDD, and p,p'-DDMU) and ∑HCH (sum of α-, β-, γ-, and δ-HCH) in wet deposition were in the ranges of nd-69 (average: 1.8 ng L -1 ) and nd-150 ng L -1 (average: 5.1 ng L -1 ), respectively. In addition, the results of source diagnostics and backward air mass trajectories appeared to suggest the transport of antifouling paint derived DDTs from the coastal region off South China to Guangzhou. The combined wet and dry deposition flux of ∑HCH in the first quarter (January to March) was greater than that in the fourth quarter (October to December), while those of ∑DDT were comparable in the first and fourth quarters. Similar trends were also observed for the concentrations of ∑HCH and ∑DDT in aerosol samples. These results suggested the short-term pollution control measures implemented during the 16th Asian Games and 10th Asian Para Games (held in November and December 2010, respectively) did not work well for DDTs. The reduced input of HCHs during the fourth quarter was probably associated with the strict ban on lindane for food safety, which also exposed the weakness of control measures focusing mainly on the removal of atmospheric particulate matter. Copyright © 2017 Elsevier Ltd. All rights reserved.

Quantitative controls on location and architecture of carbonate depositional sequences: upper miocene, cabo de gata region, se Spain

Science.gov (United States)

Franseen, E.K.; Goldstein, R.H.; Farr, M.R.

1998-01-01

Sequence stratigraphy, pinning-point relative sea-level curves, and magnetostratigraphy provide the quantitative data necessary to understand how rates of sea-level change and different substrate paleoslopes are dominant controls on accumulation rate, carbonate depositional sequence location, and internal architecture. Five third-order (1-10 my) and fourth-order (0.1-1.0 my) upper Miocene carbonate depositional sequences (DS1A, DS1B, DS2, DS3, TCC) formed with superimposed higher-frequency sea-level cycles in an archipelago setting in SE Spain. Overall, our study indicates when areas of high substrate slope (> 15??) are in shallow water, independent of climate, the location and internal architecture of carbonate deposits are not directly linked to sea-level position but, instead, are controlled by location of gently sloping substrates and processes of bypass. In contrast, if carbonate sediments are generated where substrates of low slope ( 15.6 cm/ky to ??? 2 cm/ky and overall relative sea level rose at rates of 17-21.4 cm/ky. Higher frequency sea-level rates were about 111 to more than 260 cm/ky, producing onlapping, fining- (deepening-) upward cycles. Decreasing accumulation rates resulted from decreasing surface area for shallow-water sediment production, drowning of shallow-water substrates, and complex sediment dispersal related to the archipelago setting. Typical systems tract and parasequence development should not be expected in "bypass ramp" settings; facies of onlapping strata do not track base level and are likely to be significantly different compared to onlapping strata associated with coastal onlap. Basal and upper DS2 reef megabreccias (indicating the transition from cool to warmer climatic conditions) were eroded from steep upslope positions and redeposited downslope onto areas of gentle substrate during rapid sea-level falls (> 22.7 cm/ky) of short duration. Such rapid sea-level falls and presence of steep slopes are not conducive to formation of

Predictive models for deposit accumulation and corrosion on secondary side of steam generators

International Nuclear Information System (INIS)

Choi, Samuel; Moroney, Velvet; Marks, Chuck; Kreider, Marc

2012-09-01

Experience demonstrates that deposit accumulation in steam generators (SGs) can lead to corrosion of tubes. To minimize the probability of this corrosion, utilities employ a variety of deposit control strategies. However, these processes can involve significant costs and potentially affect outage critical paths. Since there has been no model that quantifies tube degradation as a function of deposit accumulation, utilities have had to make decisions regarding deposit control strategies without a reliable quantitative basis. The objective of this study is to develop methods that utilities can use to quantify benefits of SG deposit control strategies with regard to rates of secondary-side tube corrosion. Two different methodologies are employed in this work. The first methodology is empirical and is involved an attempt to correlate degradation rates with deposit accumulation as indicated by sludge pile height. Because there has been relatively little tube degradation in currently operating steam generators, this correlation is developed using data for Alloy 600MA SG tubes. To increase the number of units that could be used for defect/deposit correlations, a method to relate the sludge pile deposit mass and the number of tubes with non-zero sludge height is developed. The second methodology is theoretical and is based on the use of calculated differences in temperature and chemistry to predict the effect of deposits on corrosion rates. Computational fluid dynamics (CFD) models are developed to simulate thermal-hydraulic conditions representative of conditions that are present within porous deposits formed at the top of tube sheet. This paper will discuss the development and application of the predictive models for deposit accumulation and corrosion on the secondary side of steam generators. (authors)

Lipase biofilm deposited by Matrix Assisted Pulsed Laser Evaporation technique

International Nuclear Information System (INIS)

Aronne, Antonio; Bloisi, Francesco; Calabria, Raffaela; Califano, Valeria; Depero, Laura E.; Fanelli, Esther; Federici, Stefania; Massoli, Patrizio; Vicari, Luciano R.M.

2015-01-01

Highlights: • A lipase film was deposited with Matrix Assisted Pulsed Laser Evaporation technique. • FTIR spectra show that laser irradiation do not damage lipase molecule. • Laser fluence controls the characteristics of complex structure generated by MAPLE. - Abstract: Lipase is an enzyme that finds application in biodiesel production and for detection of esters and triglycerides in biosensors. Matrix Assisted Pulsed Laser Evaporation (MAPLE), a technique derived from Pulsed Laser Deposition (PLD) for deposition of undamaged biomolecules or polymers, is characterized by the use of a frozen target obtained from a solution/suspension of the guest material (to be deposited) in a volatile matrix (solvent). The presence of the solvent avoids or at least reduces the potential damage of guest molecules by laser radiation but only the guest material reaches the substrate in an essentially solvent-free deposition. MAPLE can be used for enzymes immobilization, essential for industrial application, allowing the development of continuous processes, an easier separation of products, the reuse of the catalyst and, in some cases, enhancing enzyme properties (pH, temperature stability, etc.) and catalytic activity in non-aqueous media. Here we show that MAPLE technique can be used to deposit undamaged lipase and that the complex structure (due to droplets generated during extraction from target) of the deposited material can be controlled by changing the laser beam fluence

Lipase biofilm deposited by Matrix Assisted Pulsed Laser Evaporation technique

Energy Technology Data Exchange (ETDEWEB)

Aronne, Antonio [Department of Chemical Engineering, Materials and Industrial Production, University of Naples “Federico II”, Napoli (Italy); Bloisi, Francesco, E-mail: bloisi@na.infn.it [SPIN – CNR, Naples (Italy); Department of Physics, University of Naples “Federico II”, Napoli (Italy); Calabria, Raffaela; Califano, Valeria [Istituto Motori – CNR, Naples (Italy); Depero, Laura E. [Department of Mechanical and Industrial Engineering, University of Brescia, Brescia (Italy); Fanelli, Esther [Department of Chemical Engineering, Materials and Industrial Production, University of Naples “Federico II”, Napoli (Italy); Federici, Stefania [Department of Mechanical and Industrial Engineering, University of Brescia, Brescia (Italy); Massoli, Patrizio [Istituto Motori – CNR, Naples (Italy); Vicari, Luciano R.M. [SPIN – CNR, Naples (Italy); Department of Physics, University of Naples “Federico II”, Napoli (Italy)

2015-05-01

Highlights: • A lipase film was deposited with Matrix Assisted Pulsed Laser Evaporation technique. • FTIR spectra show that laser irradiation do not damage lipase molecule. • Laser fluence controls the characteristics of complex structure generated by MAPLE. - Abstract: Lipase is an enzyme that finds application in biodiesel production and for detection of esters and triglycerides in biosensors. Matrix Assisted Pulsed Laser Evaporation (MAPLE), a technique derived from Pulsed Laser Deposition (PLD) for deposition of undamaged biomolecules or polymers, is characterized by the use of a frozen target obtained from a solution/suspension of the guest material (to be deposited) in a volatile matrix (solvent). The presence of the solvent avoids or at least reduces the potential damage of guest molecules by laser radiation but only the guest material reaches the substrate in an essentially solvent-free deposition. MAPLE can be used for enzymes immobilization, essential for industrial application, allowing the development of continuous processes, an easier separation of products, the reuse of the catalyst and, in some cases, enhancing enzyme properties (pH, temperature stability, etc.) and catalytic activity in non-aqueous media. Here we show that MAPLE technique can be used to deposit undamaged lipase and that the complex structure (due to droplets generated during extraction from target) of the deposited material can be controlled by changing the laser beam fluence.

Applications of interface controlled pulsed-laser deposited polymer films in field-effect transistors

Science.gov (United States)

Adil, Danish; Ukah, Ndubuisi; Guha, Suchi; Gupta, Ram; Ghosh, Kartik

2010-03-01

Matrix assisted pulsed laser evaporation, a derivative of pulsed laser deposition (PLD), is an alternative method of depositing polymer and biomaterial films that allows homogeneous film coverage of high molecular weight organic materials for layer-by-layer growth without any laser induced damage. Polyfluorene (PF)-based conjugated polymers have attracted considerable attention in organic field-effect transistors (FETs). A co-polymer of PF (PFB) was deposited as a thin film using matrix assisted PLD employing a KrF excimer laser. Electrical characteristics of FETs fabricated using these PLD grown films were compared to those of FETs using spin-coated films. We show that threshold voltages, on/off ratios, and charge carrier motilities are significantly improved in PLD grown films. This is attributed to an improved dielectric-polymer interface.

Deposition of heated whey proteins on a chromium oxide surface.

NARCIS (Netherlands)

Jeurnink, Th.; Verheul, M.; Cohen Stuart, M.A.; Kruif, de C.G.

1996-01-01

Whey protein solutions were given different heat treatments after which their deposition on a chromium oxide surface (the outer layer of stainless steel) was measured by reflectometry. The deposition was studied under controlled flow conditions by using a stagnation point flow configuration. The

Mechanism of potentiostatic deposition of MnO2 and electrochemical characteristics of the deposit in relation to carbohydrate oxidation

International Nuclear Information System (INIS)

Das, Debasmita; Sen, Pratik Kumar; Das, Kaushik

2008-01-01

Cyclic voltammetric (CV) and chronoamperometric (CA) studies on potentiostatic deposition of MnO 2 on Pt from Mn(II) solution in very weakly alkaline media show the process to be controlled by a one-electron transfer step, which means that the deposition proceeds through the generation of Mn(III). The electrocatalytic activity of the deposited electrode towards carbohydrate oxidation is found to be maximum at an optimum amount of deposition. Chronopotentiometric (CP) and CV measurements show that the oxidation of carbohydrates on the deposited electrodes follows a catalytic EC (electrochemical-chemical) mechanism via electrolytic formation of Mn(V) and its subsequent consumption either by disproportionation or by chemical reaction in the presence of carbohydrates. The rate constants of the reaction of Mn(V) with dextrose and fructose have been obtained from CA results. The relative order of the oxidation currents for dextrose and fructose as well as their dependence on carbohydrate concentration has been discussed. Replacement of Pt by carbon as the electrode support material does not affect the electrocatalytic activity of the MnO 2 deposit. The observed linear variation of the steady state oxidation currents with carbohydrate concentration can be exploited for analytical application

Atomic-layer deposition of silicon nitride

CERN Document Server

Yokoyama, S; Ooba, K

1999-01-01

Atomic-layer deposition (ALD) of silicon nitride has been investigated by means of plasma ALD in which a NH sub 3 plasma is used, catalytic ALD in which NH sub 3 is dissociated by thermal catalytic reaction on a W filament, and temperature-controlled ALD in which only a thermal reaction on the substrate is employed. The NH sub 3 and the silicon source gases (SiH sub 2 Cl sub 2 or SiCl sub 4) were alternately supplied. For all these methods, the film thickness per cycle was saturated at a certain value for a wide range of deposition conditions. In the catalytic ALD, the selective deposition of silicon nitride on hydrogen-terminated Si was achieved, but, it was limited to only a thin (2SiO (evaporative).

Gasification of carbon deposits on catalysts and metal surfaces

Energy Technology Data Exchange (ETDEWEB)

Figueiredo, J L

1986-10-01

'Coke' deposited on catalysts and reactor surfaces includes a variety of carbons of different structures and origins, their reactivities being conveniently assessed by Temperature Programmed Reaction (TPR). The gasification of carbon deposits obtained in the laboratory under well controlled conditions, and the regeneration of coked catalysts from petroleum refining processes are reviewed and discussed. Filamentary carbon deposits, containing dispersed metal particles, behave as supported metal catalysts during gasification, and show high reactivities. Pyrolytic and acid catalysis carbons are less reactive on their own, as the gasification is not catalysed; however, metal components of the catalyst or metal impurities deposited on the surface may enhance gasification. 26 refs., 8 figs., 2 tabs.

Pena Blanca uranium deposits and ash-flow tuffs relationship

International Nuclear Information System (INIS)

Magonthier, M.

1987-01-01

The Pena Blanca uranium deposits (Chihuahua, Mexico) are associated with a Tertiary sequence of ash-flow tuffs. Stratigraphic control is dominant and uranium mineralization occurs in stratiform and fracture-controlled deposits within 44 My-old units: Nopal Rhyolite and Escuadra Rhyolite. These units consist of highly vapor-phase crystallized ash-flow tuffs. They contain sanidine, quartz and granophyric phenocrysts, and minor ferromagnesian silicates. Nopal and Escuadra units are high-silica alkali-rich rhyolites that have a primary potassic character. The trace-element chemistry shows high concentrations in U-Th-Rb-Cs and low contents in Ba-Sr-Eu. These chemical properties imply a genetic relationship between deposits and host-units. The petrochemical study show that the Nopal Rhyolite and Escuadra Rhyolite are the source of U and of hydrothermal solutions [fr

Deposition of selenium coatings on beryllium foils. Revision 1

International Nuclear Information System (INIS)

Erikson, E.D.; Tassano, P.L.; Reiss, R.H.; Griggs, G.E.

1984-01-01

A technique for preparing selenium films on 50.8 micrometers thick beryllium foils is described. The selenium was deposited in vacuum from a resistance heated evaporation source. A water-cooled enclosure was used to minimize contamination of the vacuum system and to reduce the exposure of personnel to toxic and obnoxious materials. Profilometry measurements of the coatings indicated selenium thicknesses of 5.5, 12.9, 37.5, 49.8 and 74.5 micrometers. The control of deposition rate and of coating thickness was facilitated using a commercially available closed-loop programmable deposition controller. The x-ray transmission of the coated substrates was measured using a tritiated zirconium source. The transmissivities of the film/substrate combination are presented for the range of energies from 4 to 20 keV

Dry deposition of radionuclides on leafy vegetables

International Nuclear Information System (INIS)

Heuberger, H.; Tschiersch, J.; Shinonaga, T.; Bunzl, K.; Pliml, A.; Dietl, F.; Keusch, M.

2004-01-01

The dry deposition of gaseous elemental radio-iodine and particulate radio-caesium on mature leafy vegetable was studied in chamber experiments. The simultaneous exposition of endive, head lettuce, red oak leaf lettuce and spinach (spring leafy vegetable) rsp. curly kale, white cabbage and spinach (summer leafy vegetable) was performed under homogeneous and controlled conditions. The sample collective of each species was such large that for the expected variation of the results a statistically firm analysis was possible. Significant differences were observed for the 131 I deposition on spring vegetable: the deposition on spinach was roughly 3times that on leaf lettuce, 4times that on endive and 9times that on head lettuce. For 134 Cs, there was no significant difference between spinach and leaf lettuce, about twice the amount was deposited on both species as on endive and 3times as on head lettuce. All summer vegetables showed differences in deposition. For lodine, the deposition on spinach was roughly 3times (6times) that on curly kale and 35times (100times) that on white cabbage in the 2 experiments. For caesium, the deposition to curly kale was highest, about twice that on spinach and 35times (80times) that on white cabbage. The deposition velocity could be estimated, in average it was about 8times higher for 131 I than for 134 Cs. The influence of the particle size on the deposition velocity was small in the considered size range. Washing could reduce the contamination by about 10% for 131 I and 45% for 134 Cs. (orig.)

Advanced deposition model for thermal activated chemical vapor deposition

Science.gov (United States)

Cai, Dang

Thermal Activated Chemical Vapor Deposition (TACVD) is defined as the formation of a stable solid product on a heated substrate surface from chemical reactions and/or dissociation of gaseous reactants in an activated environment. It has become an essential process for producing solid film, bulk material, coating, fibers, powders and monolithic components. Global market of CVD products has reached multi billions dollars for each year. In the recent years CVD process has been extensively used to manufacture semiconductors and other electronic components such as polysilicon, AlN and GaN. Extensive research effort has been directed to improve deposition quality and throughput. To obtain fast and high quality deposition, operational conditions such as temperature, pressure, fluid velocity and species concentration and geometry conditions such as source-substrate distance need to be well controlled in a CVD system. This thesis will focus on design of CVD processes through understanding the transport and reaction phenomena in the growth reactor. Since the in situ monitor is almost impossible for CVD reactor, many industrial resources have been expended to determine the optimum design by semi-empirical methods and trial-and-error procedures. This approach has allowed the achievement of improvements in the deposition sequence, but begins to show its limitations, as this method cannot always fulfill the more and more stringent specifications of the industry. To resolve this problem, numerical simulation is widely used in studying the growth techniques. The difficulty of numerical simulation of TACVD crystal growth process lies in the simulation of gas phase and surface reactions, especially the latter one, due to the fact that very limited kinetic information is available in the open literature. In this thesis, an advanced deposition model was developed to study the multi-component fluid flow, homogeneous gas phase reactions inside the reactor chamber, heterogeneous surface

Dry deposition of particulate Cs-134 to several leafy vegetable species and comparison to deposition of gaseous radioiodine

International Nuclear Information System (INIS)

Tschiersch, J.; Shinonaga, T.; Heuberger, H.

2004-01-01

The height of the dry deposition of particulate radionuclides to leafy vegetable is quite uncertain because of the different habit, surface texture and leaf uptake of the different species. There is no comparative data on the deposition to various species, but leafy vegetables are taken as reference plants for the estimation of the height of contamination of vegetable foods after a nuclear accident. Therefore new chamber experiments were performed to determine under homogeneous and controlled conditions the dry deposition of particulate radio-caesium on mature leafy vegetable. The simultaneous exposition of endive, head lettuce, red oak leaf lettuce and spinach (spring leafy vegetable) rsp. curly kale, white cabbage and spinach (summer leafy vegetable) was arranged. The sample collective of each species was such large that for the expected variation of the results a statistically firm analysis was possible. For spring vegetable, there was no significant difference observed in deposition of 134 Cs between spinach and leaf lettuce, about twice the amount was deposited on both species as on endive and 3 times as on head lettuce. All summer vegetables showed differences in deposition for Caesium, the deposition to curly kale was highest, about twice that on spinach and 35 times (80 times) that on white cabbage. The normalized deposition velocity could be estimated, in average it was about 8 times lower for 134 Cs than for gaseous elemental 131 I. The influence of the particle size on the deposition velocity was small in the considered size range of 0.58-1.1μm (AMAD) of the monodisperse aerosol. Washing could reduce the contamination by about 45% for 134 Cs. (author)

Particle deposition in ventilation ducts

Energy Technology Data Exchange (ETDEWEB)

Sippola, Mark Raymond [Univ. of California, Berkeley, CA (United States)

2002-09-01

experimental measurements was applied to evaluate particle losses in supply and return duct runs. Model results suggest that duct losses are negligible for particle sizes less than 1 μm and complete for particle sizes greater than 50 μm. Deposition to insulated ducts, horizontal duct floors and bends are predicted to control losses in duct systems. When combined with models for HVAC filtration and deposition to indoor surfaces to predict the ultimate fates of particles within buildings, these results suggest that ventilation ducts play only a small role in determining indoor particle concentrations, especially when HVAC filtration is present. However, the measured and modeled particle deposition rates are expected to be important for ventilation system contamination.

The atmospheric chemical vapour deposition of coatings on glass

International Nuclear Information System (INIS)

Sanderson, Kevin David

1996-01-01

The deposition of thin films of indium oxide, tin doped indium oxide (ITO) and titanium nitride for solar control applications have been investigated by Atmospheric Chemical Vapour Deposition (APCVD). Experimental details of the deposition system and the techniques used to characterise the films are presented. Results from investigations into the deposition parameters, the film microstructure and film material properties are discussed. A range of precursors were investigated for the deposition of indium oxide. The effect of pro-mixing the vaporised precursor with an oxidant source and the deposition temperature has been studied. Polycrystalline In 2 O 3 films with a resistivity of 1.1 - 3x10 -3 Ω cm were obtained with ln(thd) 3 , oxygen and nitrogen. The growth of ITO films from ln(thd) 3 , oxygen and a range of tin dopants is also presented. The effect of the dopant precursor, the doping concentration, deposition temperature and the effect of additives on film growth and microstructure is discussed. Control over the preferred orientation growth of ITO has been achieved by the addition of acetate species during film growth. Insitu infra-red spectroscopy has been used to identify the gas phase species and identify the species responsible for the film modification. ITO films with a resistivities of 1.5 - 4x10 -4 Ω cm have been achieved. The deposition of titanium nitride by the APCVD of Ti(NMe 2 ) 4 and a mixture of Ti(NMe 2 ) 4 and ammonia is reported. Contamination of the films and pro-reaction between the precursors in the gas phase is discussed, and the synthesis of new precursors for the deposition of titanium nitride is reported. New precursors have been synthesised under anaerobic conditions and characterised by infra-red spectroscopy, 1 H and 13 C NMR, mass spectrometry, thermal gravemetric analysis and three by single crystal X-ray diffraction. Deposition of titanium nitride utilising two new precursors is reported. (author)

20 CFR 703.207 - Kinds of negotiable securities that may be deposited; conditions of deposit; acceptance of deposits.

Science.gov (United States)

2010-04-01

... amount fixed by the Office under the regulations in this part shall deposit any negotiable securities... deposited; conditions of deposit; acceptance of deposits. 703.207 Section 703.207 Employees' Benefits... AND RELATED STATUTES INSURANCE REGULATIONS Insurance Carrier Security Deposit Requirements § 703.207...

Importance of root HTO uptake in controlling land-surface tritium dynamics after an-acute HT deposition: a numerical experiment

International Nuclear Information System (INIS)

Ota, Masakazu; Nagai, Haruyasu; Koarashi, Jun

2012-01-01

To investigate the role of belowground root uptake of tritiated water (HTO) in controlling land-surface tritium (T) dynamics, a sophisticated numerical model predicting tritium behavior in an atmosphere-vegetation-soil system was developed, and numerical experiments were conducted using the model. The developed model covered physical tritiated hydrogen (HT) transport in a multilayered atmosphere and soil, as well as microbial oxidation of HT to HTO in the soil, and it was incorporated into a well-established HTO-transfer organically bound tritium (OBT)-formation model. The model performance was tested through the simulation of an existing HT-release experiment. Numerical experiments involving a hypothetical acute HT exposure to a grassland field with a range of rooting depths showed that the HTO release from the leaves to the atmosphere, driven by the root uptake of the deposited HTO, can exceed the HTO evaporation from the ground surface to the atmosphere when root water absorption preferentially occurs beneath the ground surface. Such enhanced soil-leaf-atmosphere HTO transport, caused by the enhanced root HTO uptake, increased HTO concentrations in both the surface atmosphere and in the cellular water of the leaf. Consequently, leaf OBT assimilation calculated for shallow rooting depths increased by nearly an order of magnitude compared to that for large rooting depths. - Highlights: ► A model that calculates HT deposition from atmosphere to soil was developed. ► Tritium dynamics after an-acute HT deposition was studied by numerical experiments. ► OBT formation highly depends on magnitude of uptake of the deposited HTO by roots.

Controllable nitrogen doping in as deposited TiO{sub 2} film and its effect on post deposition annealing

Energy Technology Data Exchange (ETDEWEB)

Deng, Shaoren; Devloo-Casier, Kilian; Devulder, Wouter; Dendooven, Jolien; Deduytsche, Davy; Detavernier, Christophe, E-mail: Christophe.Detavernier@ugent.be [Department of Solid State Sciences, Ghent University, Krijgslaan 281/S1, B-9000 Gent (Belgium); Verbruggen, Sammy W. [Department of Bio-Engineering Sciences, University of Antwerp, Groenenborgerlaan 171, B-2020 Antwerp, Belgium and Center for Surface Chemistry and Catalysis, KU Leuven, Kasteelpark Arenberg 23, B-3001 Heverlee (Belgium); Lenaerts, Silvia [Department of Bio-Engineering Sciences, University of Antwerp, Groenenborgerlaan 171, B-2020 Antwerp (Belgium); Martens, Johan A. [Center for Surface Chemistry and Catalysis, KU Leuven, Kasteelpark Arenberg 23, B-3001 Heverlee (Belgium); Van den Berghe, Sven [SCK-CEN, Boeretang 200, B-2400 Mol (Belgium)

2014-01-15

In order to narrow the band gap of TiO{sub 2}, nitrogen doping by combining thermal atomic layer deposition (TALD) of TiO{sub 2} and plasma enhanced atomic layer deposition (PEALD) of TiN has been implemented. By altering the ratio between TALD TiO{sub 2} and PEALD TiN, the as synthesized TiO{sub x}N{sub y} films showed different band gaps (from 1.91 eV to 3.14 eV). In situ x-ray diffraction characterization showed that the crystallization behavior of these films changed after nitrogen doping. After annealing in helium, nitrogen doped TiO{sub 2} films crystallized into rutile phase while for the samples annealed in air a preferential growth of the anatase TiO{sub 2} along (001) orientation was observed. Photocatalytic tests of the degradation of stearic acid were done to evaluate the effect of N doping on the photocatalytic activity.

Thermal release of D2 from new Be-D co-deposits on previously baked co-deposits

Science.gov (United States)

Baldwin, M. J.; Doerner, R. P.

2015-12-01

Past experiments and modeling with the TMAP code in [1, 2] indicated that Be-D co-deposited layers are less (time-wise) efficiently desorbed of retained D in a fixed low-temperature bake, as the layer grows in thickness. In ITER, beryllium rich co-deposited layers will grow in thickness over the life of the machine. Although, compared with the analyses in [1, 2], ITER presents a slightly different bake efficiency problem because of instances of prior tritium recover/control baking. More relevant to ITER, is the thermal release from a new and saturated co-deposit layer in contact with a thickness of previously-baked, less-saturated, co-deposit. Experiments that examine the desorption of saturated co-deposited over-layers in contact with previously baked under-layers are reported and comparison is made to layers of the same combined thickness. Deposition temperatures of ∼323 K and ∼373 K are explored. It is found that an instance of prior bake leads to a subtle effect on the under-layer. The effect causes the thermal desorption of the new saturated over-layer to deviate from the prediction of the validated TMAP model in [2]. Instead of the D thermal release reflecting the combined thickness and levels of D saturation in the over and under layer, experiment differs in that, i) the desorption is a fractional superposition of desorption from the saturated over-layer, with ii) that of the combined over and under -layer thickness. The result is not easily modeled by TMAP without the incorporation of a thin BeO inter-layer which is confirmed experimentally on baked Be-D co-deposits using X-ray micro-analysis.

Thermal release of D_2 from new Be-D co-deposits on previously baked co-deposits

International Nuclear Information System (INIS)

Baldwin, M.J.; Doerner, R.P.

2015-01-01

Past experiments and modeling with the TMAP code in [1, 2] indicated that Be-D co-deposited layers are less (time-wise) efficiently desorbed of retained D in a fixed low-temperature bake, as the layer grows in thickness. In ITER, beryllium rich co-deposited layers will grow in thickness over the life of the machine. Although, compared with the analyses in [1, 2], ITER presents a slightly different bake efficiency problem because of instances of prior tritium recover/control baking. More relevant to ITER, is the thermal release from a new and saturated co-deposit layer in contact with a thickness of previously-baked, less-saturated, co-deposit. Experiments that examine the desorption of saturated co-deposited over-layers in contact with previously baked under-layers are reported and comparison is made to layers of the same combined thickness. Deposition temperatures of ∼323 K and ∼373 K are explored. It is found that an instance of prior bake leads to a subtle effect on the under-layer. The effect causes the thermal desorption of the new saturated over-layer to deviate from the prediction of the validated TMAP model in [2]. Instead of the D thermal release reflecting the combined thickness and levels of D saturation in the over and under layer, experiment differs in that, i) the desorption is a fractional superposition of desorption from the saturated over-layer, with ii) that of the combined over and under -layer thickness. The result is not easily modeled by TMAP without the incorporation of a thin BeO inter-layer which is confirmed experimentally on baked Be-D co-deposits using X-ray micro-analysis.

Modification of thin film properties by ion bombardment during deposition

International Nuclear Information System (INIS)

Harper, J.M.E.; Cuomo, J.J.; Gambino, R.J.; Kaufman, H.R.

1984-01-01

Deposition methods involving ion bombardment are described, and the basic processes with which film properties are modified by ion bombardment are summarized. Examples of thin film property modification by ion bombardment during deposition, including effects which are primarily compositional as well as those which are primarily structural are presented. The examples demonstrate the usefulness of ion beam techniques in identifying and controlling the fundamental deposition parameters. 68 refs.; 15 figs.; 1 table

Deposit Shedding in Biomass-Fired Boilers: Shear Adhesion Strength Measurements

DEFF Research Database (Denmark)

Laxminarayan, Yashasvi; Jensen, Peter Arendt; Wu, Hao

2017-01-01

Ash deposition on boiler surfaces is a major problem encountered in biomass combustion. Timely removal of ash deposits is essentialfor optimal boiler operation. In order to improve the understanding of deposit shedding in boilers, this study investigates the adhesion strength of biomass ash from...... off by an electrically controlled arm, and the corresponding adhesion strength was measured. The effect of sintering temperature, sintering time, deposit composition, thermal shocks on the deposit, and steel type was investigated. The results reveal that the adhesion strength of ash deposits...... is dependent on two factors: ash melt fraction, and corrosion occurring at the deposit–tube interface. Adhesion strength increases with increasing sintering temperature, sharply increasing at the ash deformation temperature. However, sintering time, as well as the type of steel used, does not have...

Twin-cuvette measurement technique for investigation of dry deposition of O3 and PAN to plant leaves under controlled humidity conditions

Directory of Open Access Journals (Sweden)

S. Sun

2016-02-01

with Quercus ilex was investigated over a 14 day measurement period under controlled climate chamber conditions. By using O3 mixing ratios between 32 and 105 ppb and PAN mixing ratios between 100 and 350 ppt, a linear dependency of the O3 flux as well as the PAN flux in relation to its ambient mixing ratio could be observed. At relative humidity (RH of 40 %, the deposition velocity ratio of O3 and PAN was determined to be 0.45. At that humidity, the deposition of O3 to the plant leaves was found to be only controlled by the leaf stomata. For PAN, an additional resistance inhibited the uptake of PAN by the leaves. Furthermore, the formation of water films on the leaf surface of plants inside the chamber could be continuously tracked with our custom built leaf wetness sensors. Using this modified leaf wetness sensor measuring the electrical surface conductance on the leaves, an exponential relationship between the ambient humidity and the electrical surface conductance could be determined.

Role of hydrogen in Sb film deposition and characterization of Sb and GexSby films deposited by cyclic plasma enhanced chemical vapor deposition using metal-organic precursors

International Nuclear Information System (INIS)

Kim, Hyung Keun; Jung, Jin Hwan; Choi, Doo Jin

2012-01-01

To meet increasing demands for chemical vapor deposition methods for high performance phase-change memory, cyclic plasma enhanced chemical vapor deposition of Sb and Ge x Sb y phase-change films and characterization of their properties were performed. Two cycle sequences were designed to investigate the role of hydrogen gas as a reduction gas during Sb film deposition. Hydrogen gas was not introduced into the reaction chamber during the purge step in cycle sequence A and was introduced during the purge step for cycle sequence B. The role of hydrogen gas was investigated by comparing the results obtained from these two cycle sequences and was concluded to exert an effect by a combination of precursor decomposition, surface maintenance as a hydrogen termination agent, and surface etching. These roles of hydrogen gas are discussed through consideration of changes in deposition rates, the oxygen concentration on the surface of the Sb film, and observations of film surface morphology. Based on these results, Ge x Sb y phase-change films were deposited with an adequate flow rate of hydrogen gas. The Ge and Sb composition of the film was controlled with the designed cycle sequences. A strong oxygen affinity for Ge was observed during the X-ray photoelectron spectroscopy analysis of Sb 3d, Sb 4d, and Ge 3d orbitals. Based on the XPS results, the ratios of Ge to Sb were calculated to be Ge 0.32 Sb 0.68 , Ge 0.38 Sb 0.62 , Ge 0.44 Sb 0.56 , Ge 0.51 Sb 0.49 and Ge 0.67 Sb 0.33 for the G1S7, G1S3, G1S2, G1S1, and G2S1 cycles, respectively. Crystal structures of Sb, Ge, and the GeSb metastable phase were observed with various Ge x Sb y film compositions. Sb crystallinity decreased with respect to Ge crystallinity by increasing the Ge fraction. A current–voltage curve was introduced, and an electro-switching phenomenon was clearly generated at a typical voltage, V th . V th values increased in conjunction with an increased proportion of Ge. The Sb crystallinity decrease and V

Deposit growth and property development in coal-fired furnaces

Energy Technology Data Exchange (ETDEWEB)

Baxter, L. [Sandia National Lab., Livermore, CA (United States)

1995-11-01

The objectives of this research project are: (1) to provide a self-consistent database of simultaneously measured, time-resolved ash deposit properties in well-controlled and well-defined environments and (2) to provide analytical expressions that relate deposit composition and structure to deposit properties of immediate relevance to PETC`s Combustion 2000 program. This project is distinguished from related work being done elsewhere by: (1) the development and deployment of in-situ diagnostics to monitor deposit properties, including heat transfer coefficients, porosity, emissivity, tenacity, strength, density, and viscosity; (2) the time resolution of such properties during deposit growth; (3) simultaneous measurement of structural and composition properties; (4) development of algorithms from a self-consistent, simultaneously measured database that includes the interdependence of properties; and (5) application of the results to technologically relevant environments such as those being planned under Combustion 2000 program. Work completed during FY94 emphasized diagnostic development. During FY95, this development work will be completed and we will emphasize application of the diagnostics to meet the other project objectives. Included in this work are the development and application of two in-situ, real-time diagnostic systems for monitoring the properties of inorganic materials on Heat transfer surfaces and in the gas-phase during controlled combustion of selected coal samples in Sandia`s Multifuel Combustor (MFC). Also, several diagnostics are being incorporated into the MFC that will eventually be used to characterize ash deposit properties.

Controlling single and few-layer graphene crystals growth in a solid carbon source based chemical vapor deposition

International Nuclear Information System (INIS)

Papon, Remi; Sharma, Subash; Shinde, Sachin M.; Vishwakarma, Riteshkumar; Tanemura, Masaki; Kalita, Golap

2014-01-01

Here, we reveal the growth process of single and few-layer graphene crystals in the solid carbon source based chemical vapor deposition (CVD) technique. Nucleation and growth of graphene crystals on a polycrystalline Cu foil are significantly affected by the injection of carbon atoms with pyrolysis rate of the carbon source. We observe micron length ribbons like growth front as well as saturated growth edges of graphene crystals depending on growth conditions. Controlling the pyrolysis rate of carbon source, monolayer and few-layer crystals and corresponding continuous films are obtained. In a controlled process, we observed growth of large monolayer graphene crystals, which interconnect and merge together to form a continuous film. On the other hand, adlayer growth is observed with an increased pyrolysis rate, resulting few-layer graphene crystal structure and merged continuous film. The understanding of monolayer and few-layer crystals growth in the developed CVD process can be significant to grow graphene with controlled layer numbers.

Association between type 1 diabetes mellitus and deposits in the semicircular canals.

Science.gov (United States)

Yoda, Shigetoshi; Cureoglu, Sebahattin; Yildirim-Baylan, Muzeyyen; Morita, Norimasa; Fukushima, Hisaki; Harada, Tamotsu; Paparella, Michael M

2011-09-01

To compare the prevalence of cupular and free-floating deposits in the semicircular canals between temporal bones of type 1 diabetes mellitus patients and normal controls. Case-control histopathologic human temporal bone study. Otopathology laboratory in a tertiary academic medical center. Twenty-eight temporal bones from 14 patients with type 1 diabetes mellitus and 56 normal temporal bones from 28 age-matched individuals were histopathologically examined. The cupula and lumina of the semicircular canals were examined for evidence of deposits. The prevalence of cupular and free-floating deposits in the lateral and posterior semicircular canals was significantly higher in type 1 diabetes mellitus patients compared with normal temporal bones (lateral, cupular deposits, odds ratio [OR], 5.47; 95% confidence interval [CI], 1.43 to 21.02; free-floating deposits, OR, 8.25; 95% CI, 2.42 to 27.85; posterior, cupular deposits, OR, 41.73; 95% CI, 5.96 to 275.50; free-floating deposits, OR, 7.44; 95% CI, 1.91 to 28.53). The prevalence of these deposits was associated with the duration of disease rather than with aging. The findings suggest that type 1 diabetes mellitus is associated with cupular and free-floating deposits in the semicircular canals. The patients with type 1 diabetes mellitus with a longer duration of disease have an increased probability of suffering from benign paroxysmal positional vertigo.

Deposition of plasmon gold-fluoropolymer nanocomposites

Science.gov (United States)

Safonov, Alexey I.; Sulyaeva, Veronica S.; Timoshenko, Nikolay I.; Kubrak, Konstantin V.; Starinskiy, Sergey V.

2016-12-01

Degradation-resistant two-dimensional metal-fluoropolymer composites consisting of gold nanoparticles coated with a thin fluoropolymer film were deposited on a substrate by hot wire chemical vapour deposition (HWCVD) and ion sputtering. The morphology and optical properties of the obtained coatings were determined. The thickness of the thin fluoropolymer film was found to influence the position of the surface plasmon resonance peak. Numerical calculations of the optical properties of the deposited materials were performed using Mie theory and the finite-difference time-domain (FDTD) method. The calculation results are consistent with the experimental data. The study shows that the position of the resonance peak can be controlled by changing the surface concentration of particles and the thickness of the fluoropolymer coating. The protective coating was found to prevent the plasmonic properties of the nanoparticles from changing for several months.

Cobalt—Styles of deposits and the search for primary deposits

Science.gov (United States)

Hitzman, Murray W.; Bookstrom, Arthur A.; Slack, John F.; Zientek, Michael L.

2017-11-30

Cobalt (Co) is a potentially critical mineral. The vast majority of cobalt is a byproduct of copper and (or) nickel production. Cobalt is increasingly used in magnets and rechargeable batteries. More than 50 percent of primary cobalt production is from the Central African Copperbelt. The Central African Copperbelt is the only sedimentary rock-hosted stratiform copper district that contains significant cobalt. Its presence may indicate significant mafic-ultramafic rocks in the local basement. The balance of primary cobalt production is from magmatic nickel-copper and nickel laterite deposits. Cobalt is present in several carbonate-hosted lead-zinc and copper districts. It is also variably present in Besshi-type volcanogenic massive sulfide and siliciclastic sedimentary rock-hosted deposits in back arc and rift environments associated with mafic-ultramafic rocks. Metasedimentary cobalt-copper-gold deposits (such as Blackbird, Idaho), iron oxide-copper-gold deposits, and the five-element vein deposits (such as Cobalt, Ontario) contain different amounts of cobalt. None of these deposit types show direct links to mafic-ultramafic rocks; the deposits may result from crustal-scale hydrothermal systems capable of leaching and transporting cobalt from great depths. Hydrothermal deposits associated with ultramafic rocks, typified by the Bou Azzer district of Morocco, represent another type of primary cobalt deposit.In the United States, exploration for cobalt deposits may focus on magmatic nickel-copper deposits in the Archean and Proterozoic rocks of the Midwest and the east coast (Pennsylvania) and younger mafic rocks in southeastern and southern Alaska; also, possibly basement rocks in southeastern Missouri. Other potential exploration targets include—The Belt-Purcell basin of British Columbia (Canada), Idaho, Montana, and Washington for different styles of sedimentary rock-hosted cobalt deposits;Besshi-type VMS deposits, such as the Greens Creek (Alaska) deposit and

Controlling Factors of Mercury Wet Deposition and Precipitation Concentrations in Upstate New York

Science.gov (United States)

Ye, Z.; Mao, H.; Driscoll, C. T.

2017-12-01

Observations from the Mercury Deposition Network (MDN) at Huntington Wildlife Forest (HWF) suggested that a significant decline in Hg concentrations in precipitation was linked to Hg emission decreases in the United States, especially in the Northeast and Midwest, and yet Hg wet deposition has remained fairly constant over the past two decades. The present study was aimed to investigate how climatic, terrestrial, and anthropogenic factors had influenced the Hg wet deposition flux in upstate New York (NY). To achieve this, an improved Community Multiscale Air Quality (CMAQ) model was employed, which included state-of-the-art Hg and halogen chemistry mechanisms. A base simulation and five sensitivity simulations were conducted. The base simulation used 2010 meteorology, U.S. EPA NEI 2011, and GEOS-Chem output as initial and boundary conditions (ICs and BCs). The five sensitivity runs each changed one condition at the time as follows: 1-3) 2004, 2005, and 2007 meteorology instead of 2010, 4) NEI 2005 Hg anthropogenic emission out of NYS instead of NEI 2011, and 5) no in-state Hg anthropogenic emission. The study period of all the simulations was March - November 2010, and the domain covered the northeastern United States at 12 km resolution. As a result, compared with rural areas in NYS, Hg wet deposition and ambient Hg concentrations in urban areas were affected more significantly by in-state anthropogenic Hg emission. The in-state anthropogenic Hg emissions contributed up to 20% of Hg wet deposition at urban sites and cloud height, precipitation, wind speed and direction, and relative humidity, among which precipitation had the largest effects in most areas. Diluting effects were found in non-convective precipitation, which contributed 31-48% to changes in Hg concentration in precipitation.

Supercritical fluid molecular spray film deposition and powder formation

Science.gov (United States)

Smith, Richard D.

1986-01-01

Solid films are deposited, or fine powders formed, by dissolving a solid material into a supercritical fluid solution at an elevated pressure and then rapidly expanding the solution through a short orifice into a region of relatively low pressure. This produces a molecular spray which is directed against a substrate to deposit a solid thin film thereon, or discharged into a collection chamber to collect a fine powder. Upon expansion and supersonic interaction with background gases in the low pressure region, any clusters of solvent are broken up and the solvent is vaporized and pumped away. Solute concentration in the solution is varied primarily by varying solution pressure to determine, together with flow rate, the rate of deposition and to control in part whether a film or powder is produced and the granularity of each. Solvent clustering and solute nucleation are controlled by manipulating the rate of expansion of the solution and the pressure of the lower pressure region. Solution and low pressure region temperatures are also controlled.

Plasma-deposited hybrid silica membranes with a controlled retention of organic bridges

Energy Technology Data Exchange (ETDEWEB)

Ngamou, P.H.T.; Creatore, M. [Department of Applied Physics, Eindhoven University of Technology, 5600 MB Eindhoven (Netherlands); Overbeek, J.P.; Kreiter, R.; Van Veen, H.M.; Vente, J.F. [ECN, Energy research Centre of the Netherlands, Petten (Netherlands); Wienk, I.M.; Cuperus, P.F. [SolSep BV, Apeldoorn (Netherlands)

2013-03-05

Hybrid organically bridged silica membranes are suitable for energy-efficient molecular separations under harsh industrial conditions. Such membranes can be useful in organic solvent nanofiltration if they can be deposited on flexible, porous and large area supports. Here, we report the proof of concept for applying an expanding thermal plasma to the synthesis of perm-selective hybrid silica films from an organically bridged monomer, 1,2-bis(triethoxysilyl)ethane. This membrane is the first in its class to be produced by plasma enhanced chemical vapor deposition. By tuning the plasma and process parameters, the organic bridging groups could be retained in the separating layer. This way, a defect free film could be made with pervaporation performances of an n-butanol-water mixture comparable with those of conventional ceramic supported membranes made by sol-gel technology (i.e. a water flux of [similar]1.8 kg m'-{sup 2} h{sup -1}, a water concentration in the permeate higher than 98% and a separation factor of >1100). The obtained results show the suitability of expanding thermal plasma as a technology for the deposition of hybrid silica membranes for molecular separations.

Vapor deposition on doublet airfoil substrates: Control of coating thickness and microstructure

Energy Technology Data Exchange (ETDEWEB)

Rodgers, Theron M.; Zhao, Hengbei; Wadley, Haydn N. G., E-mail: haydn@virginia.edu [Department of Materials Science and Engineering, University of Virginia, 395 McCormick Rd., P.O. Box 400745, Charlottesville, Virginia 22904 (United States)

2015-11-15

Gas jet assisted vapor deposition processes for depositing coatings are conducted at higher pressures than conventional physical vapor deposition methods, and have shown promise for coating complex shaped substrates including those with non-line-of-sight (NLS) regions on their surface. These regions typically receive vapor atoms at a lower rate and with a wider incident angular distribution than substrate regions in line-of-sight (LS) of the vapor source. To investigate the coating of such substrates, the thickness and microstructure variation along the inner (curved) surfaces of a model doublet airfoil containing both LS and NLS regions has been investigated. Results from atomistic simulations and experiments confirm that the coating's thickness is thinner in flux-shadowed regions than in other regions for all the coating processes investigated. They also indicated that the coatings columnar microstructure and pore volume fraction vary with surface location through the LS to NLS transition zone. A substrate rotation strategy for optimizing the thickness over the entire doublet airfoil surface was investigated, and led to the identification of a process that resulted in only small variation of coating thickness, columnar growth angle, and pore volume fraction on all doublet airfoil surfaces.

Sputtering. [as deposition technique in mechanical engineering

Science.gov (United States)

Spalvins, T.

1976-01-01

This paper primarily reviews the potential of using the sputtering process as a deposition technique; however, the manufacturing and sputter etching aspects are also discussed. Since sputtering is not regulated by classical thermodynamics, new multicomponent materials can be developed in any possible chemical composition. The basic mechanism for dc and rf sputtering is described. Sputter-deposition is described in terms of the unique advantageous features it offers such as versatility, momentum transfer, stoichiometry, sputter-etching, target geometry (coating complex surfaces), precise controls, flexibility, ecology, and sputtering rates. Sputtered film characteristics, such as strong adherence and coherence and film morphology, are briefly evaluated in terms of varying the sputtering parameters. Also described are some of the specific industrial areas which are turning to sputter-deposition techniques.

Effect of high temperature deposition on CoSi2 phase formation

International Nuclear Information System (INIS)

Comrie, C. M.; Ahmed, H.; Smeets, D.; Demeulemeester, J.; Vantomme, A.; Turner, S.; Van Tendeloo, G.; Detavernier, C.

2013-01-01

This paper discusses the nucleation behaviour of the CoSi to CoSi 2 transformation from cobalt silicide thin films grown by deposition at elevated substrate temperatures ranging from 375 °C to 600 °C. A combination of channelling, real-time Rutherford backscattering spectrometry, real-time x-ray diffraction, and transmission electron microscopy was used to investigate the effect of the deposition temperature on the subsequent formation temperature of CoSi 2 , its growth behaviour, and the epitaxial quality of the CoSi 2 thus formed. The temperature at which deposition took place was observed to exert a significant and systematic influence on both the formation temperature of CoSi 2 and its growth mechanism. CoSi films grown at the lowest temperatures were found to increase the CoSi 2 nucleation temperature above that of CoSi 2 grown by conventional solid phase reaction, whereas the higher deposition temperatures reduced the nucleation temperature significantly. In addition, a systematic change in growth mechanism of the subsequent CoSi 2 growth occurs as a function of deposition temperature. First, the CoSi 2 growth rate from films grown at the lower reactive deposition temperatures is substantially lower than that grown at higher reactive deposition temperatures, even though the onset of growth occurs at a higher temperature, Second, for deposition temperatures below 450 °C, the growth appears columnar, indicating nucleation controlled growth. Elevated deposition temperatures, on the other hand, render the CoSi 2 formation process layer-by-layer which indicates enhanced nucleation of the CoSi 2 and diffusion controlled growth. Our results further indicate that this observed trend is most likely related to stress and changes in microstructure introduced during reactive deposition of the CoSi film. The deposition temperature therefore provides a handle to tune the CoSi 2 growth mechanism.

Nanoparticle layer deposition for highly controlled multilayer formation based on high-coverage monolayers of nanoparticles

International Nuclear Information System (INIS)

Liu, Yue; Williams, Mackenzie G.; Miller, Timothy J.; Teplyakov, Andrew V.

2016-01-01

This paper establishes a strategy for chemical deposition of functionalized nanoparticles onto solid substrates in a layer-by-layer process based on self-limiting surface chemical reactions leading to complete monolayer formation within the multilayer system without any additional intermediate layers — nanoparticle layer deposition (NPLD). This approach is fundamentally different from previously established traditional layer-by-layer deposition techniques and is conceptually more similar to well-known atomic and molecular layer deposition processes. The NPLD approach uses efficient chemical functionalization of the solid substrate material and complementary functionalization of nanoparticles to produce a nearly 100% coverage of these nanoparticles with the use of “click chemistry”. Following this initial deposition, a second complete monolayer of nanoparticles is deposited using a copper-catalyzed “click reaction” with the azide-terminated silica nanoparticles of a different size. This layer-by-layer growth is demonstrated to produce stable covalently-bound multilayers of nearly perfect structure over macroscopic solid substrates. The formation of stable covalent bonds is confirmed spectroscopically and the stability of the multilayers produced is tested by sonication in a variety of common solvents. The 1-, 2- and 3-layer structures are interrogated by electron microscopy and atomic force microscopy and the thickness of the multilayers formed is fully consistent with that expected for highly efficient monolayer formation with each cycle of growth. This approach can be extended to include a variety of materials deposited in a predesigned sequence on different substrates with a highly conformal filling. - Highlights: • We investigate the formation of high-coverage monolayers of nanoparticles. • We use “click chemistry” to form these monolayers. • We form multiple layers based on the same strategy. • We confirm the formation of covalent bonds

Plasma deposited composite coatings to control biological response of osteoblast-like MG-63 cells

Science.gov (United States)

Keremidarska, M.; Radeva, E.; Eleršič, K.; Iglič, A.; Pramatarova, L.; Krasteva, N.

2014-12-01

The successful osseointegration of a bone implant is greatly dependent on its ability to support cellular adhesion and functions. Deposition of thin composite coatings onto the implant surface is a promising approach to improve interactions with cells without compromising implant bulk properties. In this work, we have developed composite coatings, based on hexamethyldisiloxane (HMDS) and detonation nanodiamond (DND) particles and have studied adhesion, growth and function of osteoblast-like MG-63 cells. PPHMDS/DND composites are of interest for orthopedics because they combine superior mechanical properties and good biocompatibility of DND with high adherence of HMDS to different substrata including glass, metals and plastics. We have used two approaches of the implementation of DND particles into a polymer matrix: pre-mixture of both components followed by plasma polymerization and layer-by-layer deposition of HMDS and DND particles and found that the deposition approach affects significantly the surface properties of the resulting layers and cell behaviour. The composite, prepared by subsequent deposition of monomer and DND particles was hydrophilic, with a rougher surface and MG-63 cells demonstrated better spreading, growth and function compared to the other composite which was hydrophobic with a smooth surface similarly to unmodified polymer. Thus, by varying the deposition approach, different PPHMDS/DND composite coatings, enhancing or inhibiting osteoblast adhesion and functions, can be obtained. In addition, the effect of fibronectin pre-adsorption was studied and was found to increase greatly MG-63 cell spreading.

Dynamic control of low-Z material deposition and tungsten erosion by strike point sweeping on DIII-D

Directory of Open Access Journals (Sweden)

J. Guterl

2017-08-01

Full Text Available Carbon deposition on tungsten between ELMs was investigated in DIII-D in semi-attached/detached H-mode plasma conditions using fixed outer strike point (OSP positions. Carbon deposition during plasma exposure of tungsten was monitored in-situ by measuring the reflectivity of the tungsten sample surface. No significant carbon deposition, i.e., without strong variations of the reflectivity, was observed during these experiments including discharges at high densities. In contrast, ERO modeling predicts a significant carbon deposition on the tungsten surface for those high density plasma conditions. The surface reflectivity decreases with methane injection, consistent with increased carbon coverage, as expected. The sweeping of OSP leads to a pronounced increase of the surface reflectivity, suggesting that the strike point sweeping may provide an effective means to remove carbon coating from tungsten surface. The ERO modeling however predicts again a regime of carbon deposition for these experiments. The discrepancies between carbon deposition regime predicted by the ERO model and the experimental observations suggest that carbon erosion during ELMs may significantly affect carbon deposition on tungsten.

Transport Properties of LCMO Granular Films Deposited by the Pulsed Electron Deposition Technique

Institute of Scientific and Technical Information of China (English)

CHEN Leiming; XU Bin; ZHANG Yan; CHEN Zhenping

2011-01-01

By finely controlling the deposition parameters in the pulsed electron deposition process,granular La2/3Ca1/3MnO3 (LCMO) film was grown on silicon substrates.The substrate temperature,ambient pressure in the deposition chamber and acceleration potential for the electron beam were all found to affect the grain size of the film,resulting in different morphologies of the samples.Transport properties of the obtained granular films,especially the magnetoresistance (MR),were studied.Prominent low-field MR was observed in all samples,indicating the forming of grain boundaries in the sample.The low-field MR show great sensitive to the morphology evolution,which reaches the highest value of about 40％ for the sample with the grain size of about 250 nm.More interestingly,positive-MR (p-MR) was also detected above 300 K when low magnetic field applying,whereas it disappeared with higher magnetic field applied up to 1.5 and 2 Tesla.Instead of the spinpolarized tunneling process being commonly regarded as a responsible reason,lattice mismatch between LCMO film and silicon substrate appears to be the origin of the p-MR

Study of dithiol monolayer as the interface for controlled deposition of gold nanoparticles

International Nuclear Information System (INIS)

Cichomski, M.; Tomaszewska, E.; Kosla, K.; Kozlowski, W.; Kowalczyk, P.J.; Grobelny, J.

2011-01-01

Self-assembled monolayer of dithiol molecules, deposited on polycrystalline Au (111), prepared at room atmosphere, was studied using scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (XPS). Dithiols were used as interface, which chemically bonds to the deposited gold nanoparticles through strong covalent bonds. The size and size distribution of the deposited nanoparticles were measured using dynamic light scattering (DLS), scanning electron microscopy (SEM) and atomic force microscopy (AFM). The AFM results showed that nanoparticles are immobilized and stable during scanning procedure and do not contaminate the AFM tip. The size of monodisperse nanoparticles obtained from the DLS measurements is slightly higher than that obtained from the AFM and SEM measurements. This is due to the fact that the DLS measures the hydrodynamic radius, dependent on the protective chemical layer on nanoparticles. - Research Highlights: → Dithiols molecules create chemically bounded layers on a Au (111) surface. → Gold nanoparticles can be chemically bounded to a self-assembled monolayer. → Nanoparticles are stable during AFM probe interactions.

Thermal release of D{sub 2} from new Be-D co-deposits on previously baked co-deposits

Energy Technology Data Exchange (ETDEWEB)

Baldwin, M.J., E-mail: m1baldwin@ucsd.edu; Doerner, R.P.

2015-12-15

Past experiments and modeling with the TMAP code in [1, 2] indicated that Be-D co-deposited layers are less (time-wise) efficiently desorbed of retained D in a fixed low-temperature bake, as the layer grows in thickness. In ITER, beryllium rich co-deposited layers will grow in thickness over the life of the machine. Although, compared with the analyses in [1, 2], ITER presents a slightly different bake efficiency problem because of instances of prior tritium recover/control baking. More relevant to ITER, is the thermal release from a new and saturated co-deposit layer in contact with a thickness of previously-baked, less-saturated, co-deposit. Experiments that examine the desorption of saturated co-deposited over-layers in contact with previously baked under-layers are reported and comparison is made to layers of the same combined thickness. Deposition temperatures of ∼323 K and ∼373 K are explored. It is found that an instance of prior bake leads to a subtle effect on the under-layer. The effect causes the thermal desorption of the new saturated over-layer to deviate from the prediction of the validated TMAP model in [2]. Instead of the D thermal release reflecting the combined thickness and levels of D saturation in the over and under layer, experiment differs in that, i) the desorption is a fractional superposition of desorption from the saturated over-layer, with ii) that of the combined over and under -layer thickness. The result is not easily modeled by TMAP without the incorporation of a thin BeO inter-layer which is confirmed experimentally on baked Be-D co-deposits using X-ray micro-analysis.

Differences in the deposition of radionuclides to leafy vegetables

International Nuclear Information System (INIS)

Tschiersch, J.; Shinonaga, T.; Heuberger, H.; Bunzl, K.; Pliml, A.; Dietl, F.; Keusch, M.

2003-01-01

To quantify the variability in deposition to several species, the dry deposition of gaseous elemental radio-iodine and particulate radio-caesium on mature leafy vegetables was studied inside a deposition chamber by comparative experiments. The simultaneous exposition of endive, head lettuce, red oak leaf lettuce, curly kale, white cabbage and spinach was performed under homogeneous and controlled conditions ( 131 vertical stroke 2 -portion, particle median, stomata opening, air humidity and temperature). Significant differences were observed for the 131 vertical stroke deposition on spring vegetables: the deposition on spinach was roughly 3times that on leaf lettuce, 4times that on endive and 9times that on head lettuce. For 134 Cs, there was no significant difference between spinach and leaf lettuce, about twice the amount was deposited on both species as on endive and 3times as on head lettuce. All summer vegetables showed differences in deposition. For Iodine, the deposition on spinach was roughly 3times (6times) that on curly kale and 35times (100times) that on white cabbage in the 2 experiments. For Caesium, the deposition to curly kale was highest, about twice that on spinach and 35times (80times) that on white cabbage. The deposition was always the lowest on the closed heads of white cabbage and head lettuce. The many open stomata of spinach increased the efficiency of gaseous deposition. In addition, rough and crimpy leafs increased the particle deposition efficiency. The estimation of the deposition velocity showed that dry deposition was in average about 8times higher for 131 vertical stroke than for 134 Cs. The influence of the particle size on the deposition velocity was small in the considered size range. Washing could reduce the contamination by about 10% for 131 vertical stroke and 45% for 134 Cs. (orig.) [de

Uranium deposit types and resources of Argentina

International Nuclear Information System (INIS)

Lopez, L.; Cuney, M.

2014-01-01

The uranium-related activities in Argentina begun in the 1950s and, as a result of the systematic exploration, several types of deposits have been discovered since then: volcanic and caldera-related, sandstone-hosted, vein spatially related to granite (intragranitic and perigranitic) and surficial. The deposits that have been the focus of the most important uranium exploitations are the ones that belong to the volcaniclastic type. These are localized in Permian formations associated with synsedimentary acid volcanism in the Sierra Pintada district (Mendoza province). The volcanic and caldera related type is also present in the Laguna Colorada deposit (Chubut province) located in the San Jorge basin (Cretaceous). Several important uranium mineralisations have been identified in Cretaceous fluvial sandstones and conglomerates, among which the most relevant is the Cerro Solo deposit (Chubut province) that corresponds to the paleochannel structure subtype. Other subtypes of sandstone model have been studied. For instance, the Don Otto deposit (Salta province), located in the Salta Group Basin (Cretaceous - Tertiary), belongs to the tabular U-V subtype. The roll front subtype can be also found in the Los Mogotes Colorados deposit (La Rioja province) which is hosted by Carboniferous continental sandstones. The uranium mineralisations in veins and disseminated episyenites within peraluminous leucogranites of the Sierras Pampeanas (Cordoba and San Luis provinces) represent other types of existing deposits. These granites are Devonian – Carboniferous and the related deposits are comparable to those from the Middle European Variscan. There are also other vein-type uranium deposits located in metamorphic basement in the periphery of high potassium calcalkaline granites (Sierras Pampeanas of Catamarca and La Rioja provinces), where the mineralisation control is mainly structural. The current uranium identified resources of the country are approximately 24,000 tU in the

Obtaining Thickness-Limited Electrospray Deposition for 3D Coating.

Science.gov (United States)

Lei, Lin; Kovacevich, Dylan A; Nitzsche, Michael P; Ryu, Jihyun; Al-Marzoki, Kutaiba; Rodriguez, Gabriela; Klein, Lisa C; Jitianu, Andrei; Singer, Jonathan P

2018-04-04

Electrospray processing utilizes the balance of electrostatic forces and surface tension within a charged spray to produce charged microdroplets with a narrow dispersion in size. In electrospray deposition, each droplet carries a small quantity of suspended material to a target substrate. Past electrospray deposition results fall into two major categories: (1) continuous spray of films onto conducting substrates and (2) spray of isolated droplets onto insulating substrates. A crossover regime, or a self-limited spray, has only been limitedly observed in the spray of insulating materials onto conductive substrates. In such sprays, a limiting thickness emerges, where the accumulation of charge repels further spray. In this study, we examined the parametric spray of several glassy polymers to both categorize past electrospray deposition results and uncover the critical parameters for thickness-limited sprays. The key parameters for determining the limiting thickness were (1) field strength and (2) spray temperature, related to (i) the necessary repulsive field and (ii) the ability for the deposited materials to swell in the carrier solvent vapor and redistribute charge. These control mechanisms can be applied to the uniform or controllably-varied microscale coating of complex three-dimensional objects.

Progress on sputter-deposited thermotractive titanium-nickel films

International Nuclear Information System (INIS)

Grummon, D.S.; Hou Li; Zhao, Z.; Pence, T.J.

1995-01-01

It is now well established that titanium-nickel alloys fabricated as thin films by physical vapor deposition can display the same transformation and shape-memory effects as their ingot-metallurgy counterparts. As such they may find important application to microelectromechanical and biomechanical systems. Furthermore, we show here that titanium-nickel films may be directly processed so as to possess extremely fine austenite grain size and very high strength. These films display classical transformational superelasticity, including high elastic energy storage capacity, the expected dependence of martensite-start temperature on transformation enthalpy, and large, fully recoverable anelastic strains at temperatures above A f . Processing depends on elevated substrate temperatures during deposition, which may be manipulated within a certain range to control both grain size and crystallographic texture. It is also possible to deposit crystalline titanium-nickel films onto polymeric substrates, making them amenable to lithographic patterning into actuator elements that are well-suited to electrical excitation of the martensite reversion transformation. Finally, isothermal annealing of nickel-rich films, under conditions of controlled extrinsic residual stress, leads to topotaxial orientation of Ni 4 Ti 3 -type precipitates, and the associated possibility of two-way memory effects. Much work remains to be done, especially with respect to precise control of composition. (orig.)

Patterned electrochemical deposition of copper using an electron beam

Directory of Open Access Journals (Sweden)

Mark den Heijer

2014-02-01

Full Text Available We describe a technique for patterning clusters of metal using electrochemical deposition. By operating an electrochemical cell in the transmission electron microscope, we deposit Cu on Au under potentiostatic conditions. For acidified copper sulphate electrolytes, nucleation occurs uniformly over the electrode. However, when chloride ions are added there is a range of applied potentials over which nucleation occurs only in areas irradiated by the electron beam. By scanning the beam we control nucleation to form patterns of deposited copper. We discuss the mechanism for this effect in terms of electron beam-induced reactions with copper chloride, and consider possible applications.

Hybrid radio-frequency/direct-current plasma-enhanced chemical vapor deposition system for deposition on inner surfaces of polyethylene terephthalate bottles

Science.gov (United States)

Li, Jing; Tian, Xiubo; Gong, Chunzhi; Yang, Shiqin; Fu, Ricky K. Y.; Chu, Paul K.

2009-12-01

A hybrid radio-frequency (rf)/direct-current (dc) system has been developed to control the biasing effects during deposition of diamondlike carbon (DLC) films onto the inner wall of polyethylene terephthalate (PET) bottles. An additional dc bias is coupled to the rf electrode to produce the effect of equivalent rf self-biasing. This allows more flexible control of the deposition of the DLC films which are intended to improve the gas barrier characteristics. The experimental results demonstrate that the additional dc bias improves the adhesion strength between the DLC film and PET, although the enhancement in the gas barrier properties is not significantly larger compared to the one without dc bias. The apparatus and methodology have practical importance in the food and beverage industry.

Hybrid radio-frequency/direct-current plasma-enhanced chemical vapor deposition system for deposition on inner surfaces of polyethylene terephthalate bottles

International Nuclear Information System (INIS)

Li Jing; Gong Chunzhi; Yang Shiqin; Tian Xiubo; Fu, Ricky K. Y.; Chu, Paul K.

2009-01-01

A hybrid radio-frequency (rf)/direct-current (dc) system has been developed to control the biasing effects during deposition of diamondlike carbon (DLC) films onto the inner wall of polyethylene terephthalate (PET) bottles. An additional dc bias is coupled to the rf electrode to produce the effect of equivalent rf self-biasing. This allows more flexible control of the deposition of the DLC films which are intended to improve the gas barrier characteristics. The experimental results demonstrate that the additional dc bias improves the adhesion strength between the DLC film and PET, although the enhancement in the gas barrier properties is not significantly larger compared to the one without dc bias. The apparatus and methodology have practical importance in the food and beverage industry.

Hybrid radio-frequency/direct-current plasma-enhanced chemical vapor deposition system for deposition on inner surfaces of polyethylene terephthalate bottles

Energy Technology Data Exchange (ETDEWEB)

Li Jing; Gong Chunzhi; Yang Shiqin [Institute of Plasma Surface Engineering and Equipment, State Key Laboratory of Advanced Welding Production and Technology, School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); Tian Xiubo [Institute of Plasma Surface Engineering and Equipment, State Key Laboratory of Advanced Welding Production and Technology, School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon (Hong Kong); Fu, Ricky K. Y.; Chu, Paul K. [Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon (Hong Kong)

2009-12-15

A hybrid radio-frequency (rf)/direct-current (dc) system has been developed to control the biasing effects during deposition of diamondlike carbon (DLC) films onto the inner wall of polyethylene terephthalate (PET) bottles. An additional dc bias is coupled to the rf electrode to produce the effect of equivalent rf self-biasing. This allows more flexible control of the deposition of the DLC films which are intended to improve the gas barrier characteristics. The experimental results demonstrate that the additional dc bias improves the adhesion strength between the DLC film and PET, although the enhancement in the gas barrier properties is not significantly larger compared to the one without dc bias. The apparatus and methodology have practical importance in the food and beverage industry.

Numerical Modelling of Suspended Transport and Deposition of Highway Deposited Sediments

DEFF Research Database (Denmark)

Bentzen, Thomas Ruby; Larsen, Torben; Bach, Christine

Good data for calibration and validation of numerical models are of high importance. In the natural environment data can be hard to archive and the stochastic nature have governing influence on the data archived. Hence for modelling of suspended transport and deposition of particles, originating ...... from the highway surfaces, in highway detention ponds, four experiments are carried out. To simplify the complexity of a real pond and for easy control and measurement the sediment transports where carried out in two rectangular channels....

Mine waters of the flooded Příbram uranium deposit

OpenAIRE

Lusk, Karel

2010-01-01

From the Příbram deposit, which was the largest exploited uranium deposit in the Czech Republic, mine water has been drained under controlled conditions, treated and discharged into the Kocába River since the flooding of the deposit in October 2005. The amount of water drained in this way is determined at any particular moment by the volume of seepage from precipitation and surface water into the underground mine cavities. The draining of overbalance mine waters is carried out at two points t...

Excess Fibrin Deposits Decrease Fetal Weight of Pregnant Mice Infected by Plasmodium berghei

Directory of Open Access Journals (Sweden)

Desy Andari

2014-05-01

Full Text Available Low birth weight is commonly attributed to malaria in pregnancy, but the cellular and molecular mechanisms that underlie this poor birth outcome are incompletely understood. A universally described histopathological feature of placental malaria is excessive deposition of fibrin, the end-product of the coagulation cascade. This study was conducted to compare fibrin deposit in pregnant mice that infected by Plasmodium berghei (treatment group to the normal pregnant mice (control group and its association with fetal weight. This research is in vivo experimental laboratory study that used 18 pregnant Balb/c mice which divided to the control the group (8 mice and treatment group (9 mice infected by P.berghei. Placentas were staining with Haematoxylin-Eosin (HE for fibrin deposits examination whereas fetal weight was performed with Mettler analytical balance AE 50. Fetal weight of the treatment group was lower than those of the control group (t test, p=0,002. Fibrin deposits were increased in the treatment group (t test, p=0,005 and influenced weight of fetuses (Spearman r= -0,586, p= 0,014. Weights of fetuses are interfered by fibrin deposits during malaria infection.

Fabrication of Hyperbolic Metamaterials using Atomic Layer Deposition

DEFF Research Database (Denmark)

Shkondin, Evgeniy

 technology allowing thickness control on atomic scale. As the deposition relies on a surface reaction, conformal pinhole free films can be deposited on various substrates with advanced topology. This method has been a central theme of the project and a core fabrication technique of plasmonic and dielectric...... in dielectric host, the fabrication is still challenging, since ultrathin, continuous, pinhole free nanometer-scale coatings are desired. The required high-quality thin layers have been fabricated using atomic layer deposition (ALD). It is a relatively new, cyclic, self-limiting thin film deposition......, especially in the infrared range, result in high loss and weak connement to the surface. Additionally, the most implemented metals in plasmonics such as Au and Ag are diffcult to pattern at nanoscale due to their limited chemistry, adhesion or oxidation issues. Therefore the implementation of...

Ion-assisted sputter deposition of molybdenum--silicon multilayers

International Nuclear Information System (INIS)

Vernon, S.P.; Stearns, D.G.; Rosen, R.S.

1993-01-01

X-ray multilayer (ML) structures that are fabricated by the use of magnetron-sputter deposition exhibit a degradation in structural quality as the deposition pressure is increased. The observed change in morphology is attributed to a reduced mobility of surface adsorbed atoms, which inhibits the formation of smooth, continuous layers. The application of a negative substrate bias produces ion bombardment of the growing film surface by sputtering gas ions extracted from the plasma and permits direct control of the energy density supplied to the film surface during thin-film growth. The technique supplements the energy lost to thermalization in high-pressure deposition and permits the fabrication of high-quality ML structures at elevated processing pressures. A threefold improvement in the soft-x-ray normal-incidence reflectance at 130 A results for substrate bias voltages of the order of ∼-150 V for Mo--Si ML's deposited at 10-mTorr Ar

Depositional controls on coal distribution and quality in the Eocene Brunner Coal Measures, Buller Coalfield, South Island, New Zealand

Science.gov (United States)

Flores, R.M.; Sykes, R.

1996-01-01

The Buller Coalfield on the West Coast of the South Island, New Zealand, contains the Eocene Brunner Coal Measures. The coal measures unconformably overlie Paleozoic-Cretaceous basement rocks and are conformably overlain by, and laterally interfinger with, the Eocene marine Kaiata Formation. This study examines the lithofacies frameworks of the coal measures in order to interpret their depositional environments. The lower part of the coal measures is dominated by conglomeratic lithofacies that rest on a basal erosional surface and thicken in paleovalleys incised into an undulating peneplain surface. These lithofacies are overlain by sandstone, mudstone and organic-rich lithofacies of the upper part of the coal measures. The main coal seam of the organic-rich lithofacies is thick (10-20 m), extensive, locally split, and locally absent. This seam and associated coal seams in the Buller Coalfield are of low- to high-volatile bituminous rank (vitrinite reflectance between 0.65% and 1.75%). The main seam contains a variable percentage of ash and sulphur. These values are related to the thickening and areal distribution of the seam, which in turn, were controlled by the nature of clastic deposition and peat-forming mire systems, marine transgression and local tidal incursion. The conglomeratic lithofacies represent deposits of trunk and tributary braided streams that rapidly aggraded incised paleovalleys during sea-level stillstands. The main seam represents a deposit of raised mires that initially developed as topogenous mires on abandoned margins of inactive braidbelts. Peat accumulated in mires as a response to a rise in the water table, probably initially due to gradual sea-level rise and climate, and the resulting raised topography served as protection from floods. The upper part of the coal measures consists of sandstone lithofacies of flu vial origin and bioturbated sandstone, mudstone and organic-rich lithofacies, which represent deposits of paralic (deltaic

Metallogenesis and metallogenic model of Nuheting uranium deposit in Erlian Basin

International Nuclear Information System (INIS)

Li Hongjun; Kuang Wenzhan

2010-01-01

Based on the study on geological characteristics, metallogesis and geochemical features in Nuheting uranium deposit, it is considered that the deposit belongs to syn-sedimentary and epigenetic reworking type. The deposit position was controlled by the lake area developed during Erlian period in Late Cretaceous. The metallognesis has experienced three stages, they are syn-sedimentary metallogenesis, epigenetic reworking metallogenesis and exogenic metallogenesis. The ore-forming ages are respectively 85 Ma, (41±5)Ma and 6-13 Ma. Based on the summary of metallogenic geological features,metallogenesis and geochemical features, the metallogenic model of Nuheting uranium deposit has been established. (authors)

Building of nested components by a double-nozzle droplet deposition process

Science.gov (United States)

Li, SuLi; Wei, ZhengYing; Du, Jun; Zhao, Guangxi; Wang, Xin; Lu, BingHeng

2016-07-01

According to the nested components jointed with multiple parts,a double-nozzle droplet deposition process was put forward in this paper, and the experimental system was developed. Through the research on the properties of support materials and the process of double-nozzle droplet deposition, the linkage control of the metal droplet deposition and the support material extrusion was realized, and a nested component with complex construction was fabricated directly. Compared with the traditional forming processes, this double-nozzle deposition process has the advantages of short cycle, low cost and so on. It can provide an approach way to build the nested parts.

Twin-cuvette measurement technique for investigation of dry deposition of O3 and PAN to plant leaves under controlled humidity conditions

Science.gov (United States)

Sun, Shang; Moravek, Alexander; von der Heyden, Lisa; Held, Andreas; Sörgel, Matthias; Kesselmeier, Jürgen

2016-02-01

We present a dynamic twin-cuvette system for quantifying the trace-gas exchange fluxes between plants and the atmosphere under controlled temperature, light, and humidity conditions. Compared with a single-cuvette system, the twin-cuvette system is insensitive to disturbing background effects such as wall deposition. In combination with a climate chamber, we can perform flux measurements under constant and controllable environmental conditions. With an Automatic Temperature Regulated Air Humidification System (ATRAHS), we are able to regulate the relative humidity inside both cuvettes between 40 and 90 % with a high precision of 0.3 %. Thus, we could demonstrate that for a cuvette system operated with a high flow rate (> 20 L min-1), a temperature-regulated humidification system such as ATRAHS is an accurate method for air humidification of the flushing air. Furthermore, the fully automatic progressive fill-up of ATRAHS based on a floating valve improved the performance of the entire measurement system and prevented data gaps. Two reactive gas species, ozone (O3) and peroxyacetyl nitrate (PAN), were used to demonstrate the quality and performance of the twin-cuvette system. O3 and PAN exchange with Quercus ilex was investigated over a 14 day measurement period under controlled climate chamber conditions. By using O3 mixing ratios between 32 and 105 ppb and PAN mixing ratios between 100 and 350 ppt, a linear dependency of the O3 flux as well as the PAN flux in relation to its ambient mixing ratio could be observed. At relative humidity (RH) of 40 %, the deposition velocity ratio of O3 and PAN was determined to be 0.45. At that humidity, the deposition of O3 to the plant leaves was found to be only controlled by the leaf stomata. For PAN, an additional resistance inhibited the uptake of PAN by the leaves. Furthermore, the formation of water films on the leaf surface of plants inside the chamber could be continuously tracked with our custom built leaf wetness sensors

Anastomosing river deposits: palaeoenvironmental control on coal quality and distribution, Northern Karoo Basin

Energy Technology Data Exchange (ETDEWEB)

Cairncross, B

1980-01-01

Borehole data from an area close to the northern margin of the Karoo Basin 110 m thick coal reveal a bearing succession of the Vryheid Formation overlying Dwyka tillite. The lowermost sediments reflect processes of deglaciation with a complex array of glaciolacustrine, glaciofluvial and alluvial-outwash fan deposits. Above this paraglacial milieu, tundra-type peat bogs developed in inactive areas and account for the two thick basal coal seams (No. 1 and 2 seams). During accumulation of peat which was later to form the extensive No. 2 coal seam, active clastic sedimentation was confined to laterally restricted river channels which incised into the underlying peat. Lateral migration was inhibited by vegetation stabilized river banks and channel deposits are characterized by vertically accreted upward-fining cycles. Channel fill consists of coarse-grinder bedload sediment deposited in anastomosing streams. Flood episodes are marked by widespread, but thin (< 1 m), shale zones that intercalate with the channel sandstones. Both sandstone and shale units are completely enveloped by No. 2 coal seams. This clastic parting influences No. 2 coal seam distribution and ash content. 23 references

Dispersion, deposition and resuspension of atmospheric contaminants

International Nuclear Information System (INIS)

Anon.

1985-01-01

The following topics are discussed: dry deposition, oil shale fugitive air emissions, particle resuspension and translocation, theoretical studies and applications, and processing of emissions by clouds and precipitation. The concentration of contaminant species in air is governed by the rate of input from sources, the rate of dilution or dispersion as a result of air turbulence, and the rate of removal to the surface by wet and dry deposition processes. Once on the surface, contaminants also may be resuspended, depending on meteorological and surface conditions. An understanding of these processes is necessary for accurate prediction of exposures of hazardous or harmful contaminants to humans, animals, and crops. In the field, plume dispersion and plume depletion by dry deposition were studied by the use of tracers. Dry deposition was investigated for particles of both respiration and inhalation interest. Complementary dry deposition studies of particles to rock canopies were conducted under controlled conditions in a wind tunnel. Because of increasing concern about hazardous, organic gases in the atmosphere some limited investigations of the dry deposition of nitrobenzene to a lichen mat were conducted in a stirred chamber. Resuspension was also studied using tracers and contaminated surfaces and in the wind tunnel. The objective of the resuspension studies was to develop and verify models for predicting the airborne concentrations of contaminants over areas with surface contamination, develop resuspension rate predictors for downwind transport, and develop predictors for resuspension input to the food chain. These models will be of particular relevance to the evaluation of deposition and resuspension of both radionuclides and chemical contaminants

Electrophoretic deposition of biomaterials

Science.gov (United States)

Boccaccini, A. R.; Keim, S.; Ma, R.; Li, Y.; Zhitomirsky, I.

2010-01-01

Electrophoretic deposition (EPD) is attracting increasing attention as an effective technique for the processing of biomaterials, specifically bioactive coatings and biomedical nanostructures. The well-known advantages of EPD for the production of a wide range of microstructures and nanostructures as well as unique and complex material combinations are being exploited, starting from well-dispersed suspensions of biomaterials in particulate form (microsized and nanoscale particles, nanotubes, nanoplatelets). EPD of biological entities such as enzymes, bacteria and cells is also being investigated. The review presents a comprehensive summary and discussion of relevant recent work on EPD describing the specific application of the technique in the processing of several biomaterials, focusing on (i) conventional bioactive (inorganic) coatings, e.g. hydroxyapatite or bioactive glass coatings on orthopaedic implants, and (ii) biomedical nanostructures, including biopolymer–ceramic nanocomposites, carbon nanotube coatings, tissue engineering scaffolds, deposition of proteins and other biological entities for sensors and advanced functional coatings. It is the intention to inform the reader on how EPD has become an important tool in advanced biomaterials processing, as a convenient alternative to conventional methods, and to present the potential of the technique to manipulate and control the deposition of a range of nanomaterials of interest in the biomedical and biotechnology fields. PMID:20504802

Photocatalytic activity of tin-doped TiO{sub 2} film deposited via aerosol assisted chemical vapor deposition

Energy Technology Data Exchange (ETDEWEB)

Chua, Chin Sheng, E-mail: cschua@simtech.a-star.edu.sg [School of Electrical and Electronic Engineering, Nanyang Technological University, 50 Nanyang Avenue, 639798 (Singapore); Singapore Institute of Manufacturing Technology, 71 Nanyang Drive, 638075 (Singapore); Tan, Ooi Kiang; Tse, Man Siu [School of Electrical and Electronic Engineering, Nanyang Technological University, 50 Nanyang Avenue, 639798 (Singapore); Ding, Xingzhao [Singapore Institute of Manufacturing Technology, 71 Nanyang Drive, 638075 (Singapore)

2013-10-01

Tin-doped TiO{sub 2} films are deposited via aerosol assisted chemical vapor deposition using a precursor mixture composing of titanium tetraisopropoxide and tetrabutyl tin. The amount of tin doping in the deposited films is controlled by the volume % concentration ratio of tetrabutyl tin over titanium tetraisopropoxide in the mixed precursor solution. X-ray diffraction analysis results reveal that the as-deposited films are composed of pure anatase TiO{sub 2} phase. Red-shift in the absorbance spectra is observed attributed to the introduction of Sn{sup 4+} band states below the conduction band of TiO{sub 2}. The effect of tin doping on the photocatalytic property of TiO{sub 2} films is studied through the degradation of stearic acid under UV light illumination. It is found that there is a 10% enhancement on the degradation rate of stearic acid for the film with 3.8% tin doping in comparison with pure TiO{sub 2} film. This improvement of photocatalytic performance with tin incorporation could be ascribed to the reduction of electron-hole recombination rate through charge separation and an increased amount of OH radicals which are crucial for the degradation of stearic acid. Further increase in tin doping results in the formation of recombination site and large anatase grains, which leads to a decrease in the degradation rate. - Highlights: ► Deposition of tin-doped TiO{sub 2} film via aerosol assisted chemical vapor deposition ► Deposited anatase films show red-shifted in UV–vis spectrum with tin-dopants. ► Photoactivity improves at low tin concentration but reduces at higher concentration. ► Improvement in photoactivity due to bandgap narrowing from Sn{sup 4+} band states ► Maximum photoactivity achieved occurs for films with 3.8% tin doping.

Technique for controllable vapor-phase deposition of 1-nitro(14C)pyrene and other polycyclic aromatic hydrocarbons onto environmental particulate matter

International Nuclear Information System (INIS)

Lucas, S.V.; Lee, K.W.; Melton, C.W.; Lewtas, J.; Ball, L.M.

1991-01-01

To produce environmental particles fortified with a polycyclic aromatic hydrocarbon (PAH) for toxicology studies, an experimental apparatus was devised for deposition of the desired chemical species onto particles in a controlled and reproducible manner. The technique utilized consists of dispersion of the particles on a gaseous stream at a controlled rate, thermal vaporization of a solution of PAH, delivery of the vaporized PAH into the aerosol of particles at a controlled rate, subsequent condensation of the PAH onto the particles, and final recovery of the coated particles. The effectiveness of this approach was demonstrated by vapor-coating a 14 C-labeled PAH (1-nitro( 14 C)-pyrene) onto diesel engine exhaust particles that had previously been collected by tunnel dilution sampling techniques. Using the 14 C label as a tracer, the coated particles were characterized with respect to degree of coating, integrity of particle structure and absence of chemical decomposition of the coating substrate. The study demonstrates that the described method provides a controllable means for depositing a substance uniformly and with a high coating efficiency onto aerosolized particles. The technique was also used to vapor-coat benzo(a)pyrene onto diesel engine exhaust and urban ambient air particulate matter, and 2-nitrofluoranthene onto urban ambient air particulate matter. Coating efficiencies of about 400 micrograms/g particulate matter were routinely obtained on a single coating run, and up to 1200 micrograms/g (1200 ppm) were achieved after a second pass through the process. The coated particles were subsequently utilized in biological fate, distribution and metabolism studies

Essential application of depositional analysis and interpretation in hydrogeologic assessments of contaminated sites

International Nuclear Information System (INIS)

Sciacca, J.

1991-01-01

In most hydrogeologic studies of contaminated sites, little attention is given to analysis of depositional environments and associated depositional patterns. This analysis is essential for sedimentary deposits present at a majority of these sites. The depositional processes associated with alluvial, fluvial and deltaic environments yield heterogeneity ranging from large to small scale. These processes also yield preferential grain orientations in coarse grained units which result in preferential directions of increased permeability. Studies conducted in fluvial and deltaic petroleum reservoirs have shown varying permeabilities resulting from deposition that strongly control the flow of fluids. The marked heterogeneity evident in the sandy portion of a single 3 to 30-foot thick fluvial point bar deposit can exert significant differences in porous flow. Preferential permeability has been shown parallel to the long axis of fluvial channel sand units while barrier beach sands exhibit preferential permeability perpendicular to the long axis of the sand body. Such controls influence natural flow and transport of contaminants in groundwater. Hydrogeologic studies should: determine the depositional environment and facies present at the site; determine the propensity for heterogeneity within the entire vertical sequence investigated and within the different facies present; assess the potential for preferential permeability within sand bodies; and provide a predictive depositional model to assess potential connections between major high permeability units. Sand unit connections are commonly forced during cross section generation and subsequent aquifer analysis. Failure to incorporate the above objectives in hydrogeologic investigations ignores the basic precept that process controls the distribution of permeability and will result in poor prediction of natural and remedial transport of contaminants in groundwater

Electrophoretic deposition of composite halloysite nanotube–hydroxyapatite–hyaluronic acid films

Energy Technology Data Exchange (ETDEWEB)

Deen, I. [Department of Materials Science and Engineering, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4L7 (Canada); Zhitomirsky, I., E-mail: zhitom@mcmaster.ca [Department of Materials Science and Engineering, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4L7 (Canada)

2014-02-15

Highlights: ► Composite halloysite nanotubes–hydroxyapatite–hyaluronic acid films were prepared. ► Electrophoretic deposition method was used for deposition. ► Natural hyaluronic acid was used as a dispersing, charging and film forming agent. ► Film composition and deposition yield can be varied. ► The films can be used for biomedical implants with controlled release of drugs. -- Abstract: Electrophoretic deposition method has been developed for the deposition of biocomposite films containing halloysite nanotubes (HNTs), hydroxyapatite (HA) and hyaluronic acid. The method is based on the use of natural hyaluronate biopolymer as a dispersing and charging agent for HNT and HA and film forming agent for the fabrication of the composite films. The deposition kinetics was studied by the quartz crystal microbalance method. The composite films were studied by X-ray diffraction, thermogravimetric analysis, differential thermal analysis and electron microscopy. The composite films are promising materials for the fabrication of biomedical implants with advanced functional properties.

Electrophoretic deposition of composite halloysite nanotube–hydroxyapatite–hyaluronic acid films

International Nuclear Information System (INIS)

Deen, I.; Zhitomirsky, I.

2014-01-01

Highlights: ► Composite halloysite nanotubes–hydroxyapatite–hyaluronic acid films were prepared. ► Electrophoretic deposition method was used for deposition. ► Natural hyaluronic acid was used as a dispersing, charging and film forming agent. ► Film composition and deposition yield can be varied. ► The films can be used for biomedical implants with controlled release of drugs. -- Abstract: Electrophoretic deposition method has been developed for the deposition of biocomposite films containing halloysite nanotubes (HNTs), hydroxyapatite (HA) and hyaluronic acid. The method is based on the use of natural hyaluronate biopolymer as a dispersing and charging agent for HNT and HA and film forming agent for the fabrication of the composite films. The deposition kinetics was studied by the quartz crystal microbalance method. The composite films were studied by X-ray diffraction, thermogravimetric analysis, differential thermal analysis and electron microscopy. The composite films are promising materials for the fabrication of biomedical implants with advanced functional properties

Enzymatic pH control for biomimetic deposition of calcium phosphate coatings

NARCIS (Netherlands)

Nijhuis, A.W.G.; Nejadnik, M.R.; Nudelman, F.; Walboomers, X.F.; Riet, J. te; Habibovic, P.; Tahmasebi Birgani, Z.; Li, Y.; Bomans, P.H.; Jansen, J.A.; Sommerdijk, N.A.; Leeuwenburgh, S.C.G.

2014-01-01

The current study examines the enzymatic decomposition of urea into carbon dioxide and ammonia as a means to increase the pH during biomimetic deposition of calcium phosphate (CaP) onto implant surfaces. The kinetics of the enzymatically induced pH increase were studied by monitoring pH, calcium

Synthesis of functional nanomaterials via colloidal mask templating and glancing angle deposition (GLAD)”

DEFF Research Database (Denmark)

Dolatshahi-Pirouz, Alireza; Jensen, Thomas Bo; Vorup-Jensen, Thomas

2010-01-01

We present a simple method for the fabrication of separated brush-like networks with both improved optical and biological properties. The brush networks were fabricated by combing the glancing angle deposition (GLAD) technique with colloidal mask templating. By changing the deposition angle durin...... of multifunctional nanomaterials which could have potential impact on devices where both controlled optical properties and cell surface interactions are needed (for instance controlled cell adhesion on optical biosensor materials).......We present a simple method for the fabrication of separated brush-like networks with both improved optical and biological properties. The brush networks were fabricated by combing the glancing angle deposition (GLAD) technique with colloidal mask templating. By changing the deposition angle during...

Local deposition of high-purity Pt nanostructures by combining electron beam induced deposition and atomic layer deposition

NARCIS (Netherlands)

Mackus, A.J.M.; Mulders, J.J.L.; Sanden, van de M.C.M.; Kessels, W.M.M.

2010-01-01

An approach for direct-write fabrication of high-purity platinum nanostructures has been developed by combining nanoscale lateral patterning by electron beam induced deposition (EBID) with area-selective deposition of high quality material by atomic layer deposition (ALD). Because virtually pure,

Iron deposition is independent of cellular inflammation in a cerebral model of multiple sclerosis

Directory of Open Access Journals (Sweden)

Lee Phil

2011-06-01

Full Text Available Abstract Background Perivenular inflammation is a common early pathological feature in multiple sclerosis (MS. A recent hypothesis stated that CNS inflammation is induced by perivenular iron deposits that occur in response to altered blood flow in MS subjects. In order to evaluate this hypothesis, an animal model was developed, called cerebral experimental autoimmune encephalomyelitis (cEAE, which presents with CNS perivascular iron deposits. This model was used to investigate the relationship of iron deposition to inflammation. Methods In order to generate cEAE, mice were given an encephalitogen injection followed by a stereotactic intracerebral injection of TNF-α and IFN-γ. Control animals received encephalitogen followed by an intracerebral injection of saline, or no encephalitogen plus an intracerebral injection of saline or cytokines. Laser Doppler was used to measure cerebral blood flow. MRI and iron histochemistry were used to localize iron deposits. Additional histological procedures were used to localize inflammatory cell infiltrates, microgliosis and astrogliosis. Results Doppler analysis revealed that cEAE mice had a reduction in cerebral blood flow compared to controls. MRI revealed T2 hypointense areas in cEAE animals that spatially correlated with iron deposition around vessels and at some sites of inflammation as detected by iron histochemistry. Vessels with associated iron deposits were distributed across both hemispheres. Mice with cEAE had more iron-labeled vessels compared to controls, but these vessels were not commonly associated with inflammatory cell infiltrates. Some iron-laden vessels had associated microgliosis that was above the background microglial response, and iron deposits were observed within reactive microglia. Vessels with associated astrogliosis were more commonly observed without colocalization of iron deposits. Conclusion The findings indicate that iron deposition around vessels can occur independently of

Application of a substrate bias to control the droplet density on Cu(In,Ga)Se{sub 2} thin films grown by Pulsed Electron Deposition

Energy Technology Data Exchange (ETDEWEB)

Rampino, S. [IMEM-CNR Institute, Parco Area delle Scienze 37/A, 43124 Parma (Italy); Pattini, F., E-mail: rampino@imem.cnr.it [IMEM-CNR Institute, Parco Area delle Scienze 37/A, 43124 Parma (Italy); Malagù, C.; Pozzetti, L. [Department of Physics and Earth Sciences, University of Ferrara, Via Saragat, 1-44122 Ferrara (Italy); Stefancich, M. [LENS Laboratory, Masdar Institute of Science and Technology, Masdar City, PO Box 54224, Abu Dhabi (United Arab Emirates); Bronzoni, M. [IMEM-CNR Institute, Parco Area delle Scienze 37/A, 43124 Parma (Italy)

2014-07-01

One of the main shortcomings in the fabrication of thin-film solar cells by pulsed high-energy deposition techniques (i.e. Pulsed Laser Deposition or Pulsed Electron Deposition — PED), is the presence of a significant number of particulates on the film surface. This affects the morphological properties of the cell active layers and, ultimately, the performance of the final device. To reduce the density of these defects, we deposited a Cu(In,Ga)Se{sub 2} (CIGS) thin film by PED and studied the effect on the film morphology when a DC bias was applied between the substrate and the target. Our results show that a negative substrate voltage, comprised between 0 and − 300 V, can not only reduce the droplet density on the CIGS film surface of about one order of magnitude with respect to the standard unbiased case (from 6 × 10{sup 5} to 5 × 10{sup 4} cm{sup −2}), but also lower the maximum particulate size and the surface smoothness. When a positive voltage is applied, we observed that a significant increase in the droplet surface density (up to 10{sup 8} cm{sup −2}) occurs. The abrupt change in the preferred crystal orientation (switching from (112) to (220)/(204) by applying negative and positive biases, respectively) is also a direct consequence of the applied DC voltage. These results confirm that the external DC bias could be used as an additional parameter to control the physical properties of thin films grown by PED. - Highlights: • Cu(In,Ga)Se{sub 2} (CIGS) films were grown by Pulsed Electron Deposition (PED). • Positive and negative DC biases were applied between the target and the substrate. • The droplet density can be reduced by one order of magnitude by DC negative bias. • Chemical composition and grain orientation of CIGS are influenced by the DC bias. • The DC bias can be an additional parameter of PED for controlling the film properties.

Seasonal variability in 7Be depositional fluxes at Granada, Spain

International Nuclear Information System (INIS)

Gonzalez-Gomez, C.; Azahra, M.; Lopez-Penalver, J.J.; Camacho-Garcia, A.; Bardouni, T.El.; Boukhal, H.

2006-01-01

Measurement of 7 Be depositional fluxes at Granada, Spain (37 o 10'50''N-3 o 35'44''W, altitude 670 m) in the period 1995 through 1998 indicates substantial variations between the four seasons and also between corresponding seasons in different years, ranging from 23.6 to 242 Bq m -2 per season. A strongly positive correlation with precipitation is shown, which explains about 70% of the variations in the 7 Be depositional fluxes over the 16 seasons studied. The depositional 7 Be flux is on the average highest in the fall and lowest in the summer. The study shows that precipitation primarily controls the 7 Be depositional flux and plays a dominant role in the removal of 7 Be from the troposphere. The average annual 7 Be depositional flux at Granada amounts to 469+145 Bq m -2

Mechanisms controlling temperature dependent mechanical and electrical behavior of SiH4 reduced chemically vapor deposited W

International Nuclear Information System (INIS)

Joshi, R.V.; Prasad, V.; Krusin-Elbaum, L.; Yu, M.; Norcott, M.

1990-01-01

The effects of deposition temperature on growth, composition, structure, adhesion properties, stress, and resistivity of chemically vapor deposited W deposited purely by SiH 4 reduction of WF 6 are discussed. At lower deposition temperatures, due to incomplete Si reduction reaction, a small amount of Si is incorporated in the film. This elemental Si in W is responsible for the observed high stresses and high resistivities over a wide temperature range. With the increase in the deposition temperature, the conversion of incorporated Si as well as the initial Si reduction are taking place, stimulating increased grain growth and thereby relieving stress and reducing resistivity. The optimum values for stress and resistivity are achieved around 500 degree C, as Si content is at its minimum. At higher temperatures the reaction between residual Si and W, is the prime cause of resistivity increase

Enzymatic pH Control for Biomimetic Deposition of Calcium Phosphate Coatings

NARCIS (Netherlands)

Nijhuis, A.W.; Reza Nejadnik, M.; Nudelman, F.; Walboomers, X.F.; te Riet, J.; Habibovic, Pamela; Tahmasebi Birgani, Zeinab; Yubao, L.; Bomans, P.H.H.; Jansen, J.A.; Sommerdijk, N.A.J.M.; Leeuwenburgh, S.C.G.

2014-01-01

The current study has focused on enzymatic decomposition of urea into carbon dioxide and ammonia as a means to increase the pH during biomimetic deposition of Calcium Phospate (CaP) onto implant surfaces. The kinetics of the enzymatically induced pH increase were studied by monitoring pH, calcium

Depositing Materials on the Micro- and Nanoscale

DEFF Research Database (Denmark)

Mar, Mikkel Dysseholm; Herstrøm, Berit; Shkondin, Evgeniy

2014-01-01

on sequential introduction of precursor pulses with intermediate purging steps. The process proceeds by specific surface ligand-exchange reactions and this leads to layer-by-layer growth control. No other thin film deposition technique can approach the conformity achieved by ALD on high aspect ratio structures....... In these systems thin films of different kind are important parts of giving the system the properties needed. This can be properties like light absorbing layers, antireflection coatings or conductive layers in solar cells. It can be low stress layers in membranes, chemicals resistant layers in chemical sensors......, layers with specific optical properties in optical sensors, piezoelectric thin films or insulating layers in many other applications. These different materials and properties impose a demand for different kind of deposition techniques. At DTU Danchip we have a large variety of these deposition techniques...

Optimizing best management practices to control anthropogenic sources of atmospheric phosphorus deposition to inland lakes.

Science.gov (United States)

Weiss, Lee; Thé, Jesse; Winter, Jennifer; Gharabaghi, Bahram

2018-04-18

Excessive phosphorus loading to inland freshwater lakes around the globe has resulted in nuisance plant growth along the waterfronts, degraded habitat for cold water fisheries, and impaired beaches, marinas and waterfront property. The direct atmospheric deposition of phosphorus can be a significant contributing source to inland lakes. The atmospheric deposition monitoring program for Lake Simcoe, Ontario indicates roughly 20% of the annual total phosphorus load (2010-2014 period) is due to direct atmospheric deposition (both wet and dry deposition) on the lake. This novel study presents a first-time application of the Genetic Algorithm (GA) methodology to optimize the application of best management practices (BMPs) related to agriculture and mobile sources to achieve atmospheric phosphorus reduction targets and restore the ecological health of the lake. The novel methodology takes into account the spatial distribution of the emission sources in the airshed, the complex atmospheric long-range transport and deposition processes, cost and efficiency of the popular management practices and social constraints related to the adoption of BMPs. The optimization scenarios suggest that the optimal overall capital investment of approximately $2M, $4M, and $10M annually can achieve roughly 3, 4 and 5 tonnes reduction in atmospheric P load to the lake, respectively. The exponential trend indicates diminishing returns for the investment beyond roughly $3M per year and that focussing much of this investment in the upwind, nearshore area will significantly impact deposition to the lake. The optimization is based on a combination of the lowest-cost, most-beneficial and socially-acceptable management practices that develops a science-informed promotion of implementation/BMP adoption strategy. The geospatial aspect to the optimization (i.e. proximity and location with respect to the lake) will help land managers to encourage the use of these targeted best practices in areas that

Elemental tritium deposition and conversion in the terrestrial environment

International Nuclear Information System (INIS)

Dunstall, T.G.; Ogram, G.L.; Spencer, F.S.

1985-01-01

Studies were undertaken to determine the deposition and conversion of atmospheric elemental tritium in soils and vegetation. In the field tritium deposition velocities ranged between 0.007 and 0.07 cm s -1 during the summer and autumn and were less than 0.0005 cm s -1 during the winter. Deposition velocity was found to depend significantly on soil water content, total pore space and organic content in controlled laboratory experiments. In contrast to soils, exposure of vegetation to atmospheric elemental tritium resulted in negligible uptake and conversion in foliage. These studies are of significance to the assessment of behaviour and impact of elemental tritium releases

Controls on upper Campanian-Maastrichtian chalk deposition in the eastern Danish Basin

DEFF Research Database (Denmark)

Boussaha, Myriam; Thibault, Nicolas Rudolph; Anderskouv, Kresten

2017-01-01

% of the sediment. Sedimentation took place in deep water, below the photic zone and storm-wave base, and is characterized by decimetre to metre-scale variations in facies and trace fossil assemblages indicating repeated shifts in depositional environment. Integration of facies with published data on sea...... of accumulation rates and sea temperatures and is interpreted to represent a very broad set of deep water environmental conditions with an ample supply of calcareous nannofossil debris and intense bioturbation. Longer term shifts in deposition are best expressed by distribution of clay, flint and bioturbated...... micro-wackestone, bioturbated wackestone and laminated mudstone chalk facies, whereas the trace fossil assemblages appear less useful. The data set indicates overall shallowing over time with two distinctive events of clay influx to the basin during the late Campanian-earliest Maastrichtian and late...

A deposit model for magmatic iron-titanium-oxide deposits related to Proterozoic massif anorthosite plutonic suites

Science.gov (United States)

Woodruff, Laurel G.; Nicholson, Suzanne W.; Fey, David L.

2013-01-01

This descriptive model for magmatic iron-titanium-oxide (Fe-Ti-oxide) deposits hosted by Proterozoic age massif-type anorthosite and related rock types presents their geological, mineralogical, geochemical, and geoenvironmental attributes. Although these Proterozoic rocks are found worldwide, the majority of known deposits are found within exposed rocks of the Grenville Province, stretching from southwestern United States through eastern Canada; its extension into Norway is termed the Rogaland Anorthosite Province. This type of Fe-Ti-oxide deposit dominated by ilmenite rarely contains more than 300 million tons of ore, with between 10- to 45-percent titanium dioxide (TiO2), 32- to 45-percent iron oxide (FeO), and less than 0.2-percent vanadium (V). The origin of these typically discordant ore deposits remains as enigmatic as the magmatic evolution of their host rocks. The deposits clearly have a magmatic origin, hosted by an age-constrained unique suite of rocks that likely are the consequence of a particular combination of tectonic circumstances, rather than any a priori temporal control. Principal ore minerals are ilmenite and hemo-ilmenite (ilmenite with extensive hematite exsolution lamellae); occurrences of titanomagnetite, magnetite, and apatite that are related to this deposit type are currently of less economic importance. Ore-mineral paragenesis is somewhat obscured by complicated solid solution and oxidation behavior within the Fe-Ti-oxide system. Anorthosite suites hosting these deposits require an extensive history of voluminous plagioclase crystallization to develop plagioclase-melt diapirs with entrained Fe-Ti-rich melt rising from the base of the lithosphere to mid- and upper-crustal levels. Timing and style of oxide mineralization are related to magmatic and dynamic evolution of these diapiric systems and to development and movement of oxide cumulates and related melts. Active mines have developed large open pits with extensive waste-rock piles, but

Metalorganic atomic layer deposition of TiN thin films using TDMAT and NH3

International Nuclear Information System (INIS)

Kim, Hyo Kyeom; Kim, Ju Youn; Park, Jin Yong; Kim, Yang Do; Kim, Young Do; Jeon, Hyeong Tag; Kim, Won Mok

2002-01-01

TiN films were deposited by using the metalorganic atomic layer deposition (MOALD) method using tetrakis-dimethyl-amino-titanium (TDMAT) as the titanium precursor and ammonia (NH 3 ) as the reactant gas. Two saturated TiN film growth regions were observed in the temperature ranges from 175 and 190 .deg. C and from 200 and 210 .deg. C. TiN films deposited by the MOALD technique showed relatively lower carbon content than films deposited by metalorganic chemical vapor deposition (MOCVD) method. TiN films deposited at around 200 .deg. C under standard conditions showed the resistivity values as low as 500 μΩ-cm, which is about one order lower than the values for TiN films deposited by MOCVD using TDMAT or TDMAT with NH 3 . Also, the carbon incorporation and the resistivity were further decreased with increasing Ar purge time and flow rate. TiN films deposited at temperature below 300 .deg. C showed amorphous characteristics. TiN film deposited on contact holes, about 0.4-μm wide and 0.8-μm deep, by using the MOALD method showed excellent conformal deposition with almost 100% step coverage. This study demonstrates that the processing parameters need to be carefully controlled to optimize the film properties that the processing parameters need to be carefully controlled to optimize the film properties when using the ALD technique and that TiN films deposited by using the MOALD method exhibited excellent film properties compared to those of films deposited by using other CVD methods

Composition and Morphology Control of Metal Dichalcogenides via Chemical Vapor Deposition for Photovoltaic and Nanoelectronic Applications

Science.gov (United States)

Samad, Leith L. J.

The body of work reviewed here encompasses a variety of metal dichalcogenides all synthesized using chemical vapor deposition (CVD) for solar and electronics applications. The first reported phase-pure CVD synthesis of iron pyrite thin films is presented with detailed structural and electrochemical analysis. The phase-pure thin film and improved crystal growth on a metallic backing material represents one of the best options for potential solar applications using iron pyrite. Large tin-sulfur-selenide solid solution plates with tunable bandgaps were also synthesized via CVD as single-crystals with a thin film geometry. Solid solution tin-sulfur-selenide plates were demonstrated to be a new material for solar cells with the first observed solar conversion efficiencies up to 3.1%. Finally, a low temperature molybdenum disulfide vertical heterostructure CVD synthesis with layered controlled growth was achieved with preferential growth enabled by Van der Waals epitaxy. Through recognition of additional reaction parameters, a fully regulated CVD synthesis enabled the controlled growth of 1-6 molybdenum disulfide monolayers for nanoelectronic applications. The improvements in synthesis and materials presented here were all enabled by the control afforded by CVD such that advances in phase purity, growth, and composition control of several metal dichalcogenides were achieved. Further work will be able to take full advantage of these advances for future solar and electronics technologies.

Control of the optical properties of silicon and chromium mixed oxides deposited by reactive magnetron sputtering

International Nuclear Information System (INIS)

Vergara, L.; Galindo, R. Escobar; Martinez, R.; Sanchez, O.; Palacio, C.; Albella, J.M.

2011-01-01

The development of mixed-oxide thin films allows obtaining materials with better properties than those of the different binary oxides, which makes them suitable for a great number of applications in different fields, such as tribology, optics or microelectronics. In this paper we investigate the deposition of mixed chromium and silicon oxides deposited by reactive magnetron sputtering with a view to use them as optical coatings with an adjustable refractive index. These films have been characterized by means of Rutherford backscattering spectrometry, Auger electron spectroscopy, X-ray diffraction, scanning electron microscopy, Fourier-transform infrared spectroscopy and spectroscopic ellipsometry so as to determine how the deposition conditions influence the characteristics of the material. We have found that the deposition parameter whose influence determines the properties of the films to a greater extent is the amount of oxygen in the reactive sputtering gas.

On the classification of uranium deposits associated with volcano-techtonic depressions

International Nuclear Information System (INIS)

Konstantinov, V.M.

1981-01-01

Advisability of separating uranium deposits associated with volcano-techtonic depressions as a class is grounded. Three groups of deposits are stated: foundation or low depression zone, medium depression zone, upper depression zone. Deposits are unified in five subgroups: in terrigenic molass, effusion- sedimentary formations, paleovulcanic setups and subvulcanic intrusions, granitoides, sedimentary and metamorphical rocks of geocinclinic complex. 18 structural-morphological types of deposits are determined by accounting of the basic structural-lithologic factors of ore control. An idealized diagram of ore-bearing vulcano-techtonic depression and its alternations at different erosion shears are presented. A conclusion is made on practical application of the classification [ru

A robotic system to characterize soft tailings deposits

Energy Technology Data Exchange (ETDEWEB)

Lipsett, M.G.; Dwyer, S.C. [Alberta Univ., Edmonton, AB (Canada). Dept. of Mechanical Engineering

2009-07-01

A robotic system for characterizing soft tailings deposits was discussed in this presentation. The system was developed to reduce variability in feedstocks and process performance as well as to improve the trafficability of composite tailings (CT). The method was designed to reliably sample different locations of a soft deposit. Sensors were used to determine water content, clay content, organic matter, and strength. The system included an autonomous rover with a sensor package and teleoperation capability. The system was also designed to be used without automatic controls. The wheeled mobile robot was used to conduct ground contact and soil measurements. The gas-powered robot included on-board microcontrollers and a host computer. The system also featured traction control and fault recovery sub-systems. Wheel contact was used to estimate soil parameters. It was concluded that further research is needed to improve traction control and soil parameter estimation testing capabilities. Overall system block diagrams were included. tabs., figs.

Application research on remote sensing geology of sandstone-type uranium deposit in Yili basin

International Nuclear Information System (INIS)

Wang Huaiwu

2002-01-01

Based on remote sensing images and practical materials, and new ideas of laying particular emphasis on the research of regional geologic structures, and large in-situ leachable sandstone-type uranium deposits, applying the theory of plate tectonics, the author makes a comprehensive analysis on the uranium metallogenic environments, characteristics of regional geologic structures, the ore-controlling mechanism and factors, and uranium metallogeny. Authors propose that large interlayer oxidation zone sandstone-type uranium deposits are controlled by the combination of the stable block in Meso-Cenozoic compressive-shearing faulted subsided basin on the Yili multiphase massif in Tianshan paleo-island arc system, and the specific paleo-geographic environments and its' structural terrace'. The origin of hydrogenic sandstone-type uranium deposits is summarized by the authors as the 'mixing and neutralization' genetic model, and the 'eight ore-controlling factors merge into an organic whole' prospecting model. The above mentioned provides clear prospecting direction and new ideas for the forecasting direction for prospecting large sandstone-type uranium deposits

DepositScan, a Scanning Program to Measure Spray Deposition Distributions

Science.gov (United States)

DepositScan, a scanning program was developed to quickly measure spray deposit distributions on water sensitive papers or Kromekote cards which are widely used for determinations of pesticide spray deposition quality on target areas. The program is installed in a portable computer and works with a ...

Sources and processes contributing to nitrogen deposition: an adjoint model analysis applied to biodiversity hotspots worldwide.

Science.gov (United States)

Paulot, Fabien; Jacob, Daniel J; Henze, Daven K

2013-04-02

Anthropogenic enrichment of reactive nitrogen (Nr) deposition is an ecological concern. We use the adjoint of a global 3-D chemical transport model (GEOS-Chem) to identify the sources and processes that control Nr deposition to an ensemble of biodiversity hotspots worldwide and two U.S. national parks (Cuyahoga and Rocky Mountain). We find that anthropogenic sources dominate deposition at all continental sites and are mainly regional (less than 1000 km) in origin. In Hawaii, Nr supply is controlled by oceanic emissions of ammonia (50%) and anthropogenic sources (50%), with important contributions from Asia and North America. Nr deposition is also sensitive in complicated ways to emissions of SO2, which affect Nr gas-aerosol partitioning, and of volatile organic compounds (VOCs), which affect oxidant concentrations and produce organic nitrate reservoirs. For example, VOC emissions generally inhibit deposition of locally emitted NOx but significantly increase Nr deposition downwind. However, in polluted boreal regions, anthropogenic VOC emissions can promote Nr deposition in winter. Uncertainties in chemical rate constants for OH + NO2 and NO2 hydrolysis also complicate the determination of source-receptor relationships for polluted sites in winter. Application of our adjoint sensitivities to the representative concentration pathways (RCPs) scenarios for 2010-2050 indicates that future decreases in Nr deposition due to NOx emission controls will be offset by concurrent increases in ammonia emissions from agriculture.

Sources of nitrogen deposition in Federal Class I areas in the US

Directory of Open Access Journals (Sweden)

H.-M. Lee

2016-01-01

Full Text Available It is desired to control excessive reactive nitrogen (Nr deposition due to its detrimental impact on ecosystems. Using a three-dimensional atmospheric chemical transport model, GEOS-Chem, Nr deposition in the contiguous US and eight selected Class I areas (Voyageurs (VY, Smoky Mountain (SM, Shenandoah (SD, Big Bend (BB, Rocky Mountain (RM, Grand Teton (GT, Joshua Tree (JT, and Sequoia (SQ is investigated. First, modeled Nr deposition is compared with National Trends Network (NTN and Clean Air Status and Trends Network (CASTNET deposition values. The seasonality of measured species is generally well represented by the model (R2 > 0.6, except in JT. While modeled Nr is generally within the range of seasonal observations, large overestimates are present in sites such as SM and SD in the spring and summer (up to 0.6 kg N ha month−1, likely owing to model high-biases in surface HNO3. The contribution of non-measured species (mostly dry deposition of NH3 to total modeled Nr deposition ranges from 1 to 55 %. The spatial distribution of the origin of Nr deposited in each Class I area and the contributions of individual emission sectors are estimated using the GEOS-Chem adjoint model. We find the largest role of long-range transport for VY, where 50 % (90 % of annual Nr deposition originates within 670 (1670 km of the park. In contrast, the Nr emission footprint is most localized for SQ, where 50 % (90 % of the deposition originates from within 130 (370 km. Emissions from California contribute to the Nr deposition in remote areas in the western US (RM, GT. Mobile NOx and livestock NH3 are found to be the major sources of Nr deposition in all sites except BB, where contributions of NOx from lightning and soils to natural levels of Nr deposition are significant (∼ 40 %. The efficiency in terms of Nr deposition per kg emissions of NH3-N, NOx-N, and SO2-S are also estimated. Unique seasonal features are found in JT (opposing

Fat, oil and grease deposits in sewers: characterisation of deposits and formation mechanisms.

Science.gov (United States)

Williams, J B; Clarkson, C; Mant, C; Drinkwater, A; May, E

2012-12-01

Fat, oil and grease deposits (FOG) in sewers are a major problem and can cause sewer overflows, resulting in environmental damage and health risks. Often simplistically portrayed as cooling of fats, recent research has suggested that saponification may be involved in FOG formation. However there are still questions about the mechanisms effecting transformations in sewers and the role and source of metal cations involved in saponification. This study characterises FOG deposits from pumping stations, sewers and sewage works from different water hardness zones across the UK. The sites all had previous problems with FOG and most catchments contained catering and food preparation establishments. The FOG deposits were highly variable with moisture content ranging from 15 to 95% and oil content from 0 to 548 mg/g. Generally the pumping stations had lower moisture content and higher fat content, followed by the sewers then the sewage works. The water in contact with the FOG had high levels of oil (mean of about 800 mg/L) and this may indicate poor kitchen FOG management practices. FOG fatty acid profiles showed a transformation from unsaturated to saturated forms compared to typical cooking oils. This seems to relate to ageing in the sewer network or the mechanism of formation, as samples from pumping stations had higher proportions of C18:1 compared to C16. This may be due to microbial transformations by bacteria such as Clostridium sp. in a similar process to adipocere formation. There was an association between water hardness and increased Ca levels in FOG along with harder deposits and higher melting points. A link between FOG properties and water hardness has not been previously reported for field samples. This may also be due to microbial processes, such as biocalcification. By developing the understanding of these mechanisms it may be possible to more effectively control FOG deposits, especially when combined with promotion of behavioural change. Copyright © 2012

Nitrogen deposition effects on Mediterranean-type ecosystems: An ecological assessment

Energy Technology Data Exchange (ETDEWEB)

Ochoa-Hueso, Raul, E-mail: raul.ochoa@ccma.csic.es [Department of Plant Physiology and Ecology, Centro de Ciencias Medioambientales, Consejo Superior de Investigaciones Cientificas, C/Serrano 115 Dpdo., 28006 Madrid (Spain); Allen, Edith B. [Department of Botany and Plant Sciences and Center for Conservation Biology, University of California, Riverside, CA 92521 (United States); Branquinho, Cristina; Cruz, Cristina; Dias, Teresa [Universidade de Lisboa, Faculdade de Ciencias, Centro de Biologia Ambiental, Campo Grande, Bloco C4, 1749-016 Lisboa (Portugal); Fenn, Mark E. [US Department of Agriculture (USDA) Forest Service, Pacific Southwest Research Station, 4955 Canyon Crest Drive, Riverside, CA 92507 (United States); Manrique, Esteban [Department of Plant Physiology and Ecology, Centro de Ciencias Medioambientales, Consejo Superior de Investigaciones Cientificas, C/Serrano 115 Dpdo., 28006 Madrid (Spain); Perez-Corona, M. Esther [Department of Ecology, Faculty of Biology, Universidad Complutense de Madrid, C/Jose Antonio Novais 2, 28040 Madrid (Spain); Sheppard, Lucy J. [Centre of Ecology and Hydrology, Bush Estate, Penicuik EH26 0QB (United Kingdom); Stock, William D. [Centre for Ecosystem Management, School of Natural Sciences, Edith Cowan University, 100 Joondalup Drive, Joondalup, Perth, WA 6027 (Australia)

2011-10-15

We review the ecological consequences of N deposition on the five Mediterranean regions of the world. Seasonality of precipitation and fires regulate the N cycle in these water-limited ecosystems, where dry N deposition dominates. Nitrogen accumulation in soils and on plant surfaces results in peaks of availability with the first winter rains. Decoupling between N flushes and plant demand promotes losses via leaching and gas emissions. Differences in P availability may control the response to N inputs and susceptibility to exotic plant invasion. Invasive grasses accumulate as fuel during the dry season, altering fire regimes. California and the Mediterranean Basin are the most threatened by N deposition; however, there is limited evidence for N deposition impacts outside of California. Consequently, more research is needed to determine critical loads for each region and vegetation type based on the most sensitive elements, such as changes in lichen species composition and N cycling. - Highlights: > N deposition impacts are understudied in Mediterranean ecosystems out of California. > Dry N deposition is dominant and N flushes are common after rainless periods. > Water availability and P fertility regulate ecosystem responses to N deposition. > Research is needed to determine critical loads for each region and vegetation type. - Nitrogen deposition threatens the Mediterranean regions of the world.

Nitrogen deposition effects on Mediterranean-type ecosystems: An ecological assessment

International Nuclear Information System (INIS)

Ochoa-Hueso, Raul; Allen, Edith B.; Branquinho, Cristina; Cruz, Cristina; Dias, Teresa; Fenn, Mark E.; Manrique, Esteban; Perez-Corona, M. Esther; Sheppard, Lucy J.; Stock, William D.

2011-01-01

We review the ecological consequences of N deposition on the five Mediterranean regions of the world. Seasonality of precipitation and fires regulate the N cycle in these water-limited ecosystems, where dry N deposition dominates. Nitrogen accumulation in soils and on plant surfaces results in peaks of availability with the first winter rains. Decoupling between N flushes and plant demand promotes losses via leaching and gas emissions. Differences in P availability may control the response to N inputs and susceptibility to exotic plant invasion. Invasive grasses accumulate as fuel during the dry season, altering fire regimes. California and the Mediterranean Basin are the most threatened by N deposition; however, there is limited evidence for N deposition impacts outside of California. Consequently, more research is needed to determine critical loads for each region and vegetation type based on the most sensitive elements, such as changes in lichen species composition and N cycling. - Highlights: → N deposition impacts are understudied in Mediterranean ecosystems out of California. → Dry N deposition is dominant and N flushes are common after rainless periods. → Water availability and P fertility regulate ecosystem responses to N deposition. → Research is needed to determine critical loads for each region and vegetation type. - Nitrogen deposition threatens the Mediterranean regions of the world.

Plasma deposition of microcrystalline silicon solar cells. Looking beyond the glass

Energy Technology Data Exchange (ETDEWEB)

Donker, M.N. van den

2006-07-01

Microcrystalline silicon emerged in the past decade as highly interesting material for application in efficient and stable thin film silicon solar cells. It consists of nanometer-sized crystallites embedded in a micrometer-sized columnar structure, which gradually evolves during the SiH{sub 4} based deposition process starting from an amorphous incubation layer. Understanding of and control over this transient and multi-scale growth process is essential in the route towards low-cost microcrystalline silicon solar cells. This thesis presents an experimental study on the technologically relevant high rate (5-10 Aa s{sup -1}) parallel plate plasma deposition process of state-of-the-art microcrystalline silicon solar cells. The objective of the work was to explore and understand the physical limits of the plasma deposition process as well as to develop diagnostics suitable for process control in eventual solar cell production. Among the developed non-invasive process diagnostics were a pyrometer, an optical spectrometer, a mass spectrometer and a voltage probe. Complete thin film silicon solar cells and modules were deposited and characterized. (orig.)

RIR-MAPLE deposition of conjugated polymers and hybrid nanocomposites for application to optoelectronic devices

International Nuclear Information System (INIS)

Stiff-Roberts, Adrienne D.; Pate, Ryan; McCormick, Ryan; Lantz, Kevin R.

2012-01-01

Resonant infrared matrix-assisted pulsed laser evaporation (RIR-MAPLE) is a variation of pulsed laser deposition that is useful for organic-based thin films because it reduces material degradation by selective absorption of infrared radiation in the host matrix. A unique emulsion-based RIR-MAPLE approach has been developed that reduces substrate exposure to solvents and provides controlled and repeatable organic thin film deposition. In order to establish emulsion-based RIR-MAPLE as a preferred deposition technique for conjugated polymer or hybrid nanocomposite optoelectronic devices, studies have been conducted to demonstrate the value added by the approach in comparison to traditional solution-based deposition techniques, and this work will be reviewed. The control of hybrid nanocomposite thin film deposition, and the photoconductivity in such materials deposited using emulsion-based RIR-MAPLE, will also be reviewed. The overall result of these studies is the demonstration of emulsion-based RIR-MAPLE as a viable option for the fabrication of conjugated polymer and hybrid nanocomposite optoelectronic devices that could yield improved device performance.

Discussion on geological characteristics and types of uranium deposit of Mesozoic-cenozoic basin in Guangdong

International Nuclear Information System (INIS)

Wang Kesheng; Deng Shihua

1992-01-01

Systematic summary is briefly made of the distribution, classification, formation, regional geological setting, uranium deposit type, ore-controlling geological conditions of the Mesozoic-Cenozoic basin in Guangdong area, and on this basis it is proposed that there exist different ore-controlling conditions in different types of basin and different types of deposit can be formed in them, thus indicating the direction for exploration of the basin type uranium deposit from now on and expanding the prospect of ore-finding in the basins in Guangdong area

Control of the threshold voltage by using the oxygen partial pressure in sputter-deposited InGaZnO4 thin-film transistors

International Nuclear Information System (INIS)

Ahn, Jeung Sun; Lee, Kwang Bae

2012-01-01

We investigate the controllability of the threshold voltage (V th ) by varying the O 2 partial pressure in sputter-deposited of InGaZnO 4 thin-film transistors (IGZO TFTs). We showed that the V th values could be linearly controlled from a depletion-type of V th ∼ -6 V to an enhancement-type of V th ∼ 2 V, without any abrupt change in μ sat , I on/off , and S, by only changing the O 2 partial pressure in a fixed region of the Ar partial pressure. Such V th controllability is thought to be due to the proper reduction of defect states and, in turn, to the preservation of high-performance TFT behavior.

Uranium deposits of the world. Europe

Energy Technology Data Exchange (ETDEWEB)

Dahlkamp, Franz J.

2016-07-01

Uranium Deposits of the World, in three volumes, comprises an unprecedented compilation of data and descriptions of the uranium regions in Asia, USA, Latin America and Europe structured by countries. With this third, the Europe volume, Uranium Deposits of the World presents the most extensive data collection of the set. It covers about 140 uranium regions in more than 20 European countries with nearly 1000 mentioned uranium deposits. Each country and region receives an analytical overview followed by the geologically- and economically-relevant synopsis of the individual regions and fields. The presentations are structured in three major sections: (a) location and magnitude of uranium regions, districts, and deposits, (b) principal features of regions and districts, and (c) detailed characteristics of selected ore fields and deposits. This includes sections on geology, alteration, mineralization, shape and dimensions of deposits, isotopes data, ore control and recognition criteria, and metallogenesis. Beside the main European uranium regions, for example in the Czech Republic, Eastern Germany, France, the Iberian Peninsula or Ukraine, also small regions an districts to the point of singular occurrences of interest are considered. This by far the most comprehensive presentation of European uranium geology and mining would not be possible without the author's access to extensive information covering the countries of the former Eastern Bloc states, which was partly not previously available. Abundantly illustrated with information-laden maps and charts throughout, this reference work is an indispensable tool for geologists, mining companies, government agencies, and others with an interest in European key natural resources. A great help for the reader's orientation are the substantial bibliography of uranium-related publications and the indices, latter containing about 3900 entries in the geographical part alone. The three volumes of Uranium Deposits of the

78 FR 56583 - Deposit Insurance Regulations; Definition of Insured Deposit

Science.gov (United States)

2013-09-13

... as a potential global deposit insurer, preserve confidence in the FDIC deposit insurance system, and... the United States.\\2\\ The FDIC generally pays out deposit insurance on the next business day after a... since 2001 and total approximately $1 trillion today. In many cases, these branches do not engage in...

Controlling Barium Sulphate Scale Deposition Problems in an unbleached Kraft Paper Mill

CSIR Research Space (South Africa)

Sithole, Bruce

2015-06-01

Full Text Available Troubleshooting of scale deposits and defects in paper samples showed that the problem was caused by barium sulphate and calcium sulphate scales. However, it was ascertained that barium sulphate was more of a concern than calcium sulphate...

Stabilizing laser energy density on a target during pulsed laser deposition of thin films

Science.gov (United States)

Dowden, Paul C.; Jia, Quanxi

2016-05-31

A process for stabilizing laser energy density on a target surface during pulsed laser deposition of thin films controls the focused laser spot on the target. The process involves imaging an image-aperture positioned in the beamline. This eliminates changes in the beam dimensions of the laser. A continuously variable attenuator located in between the output of the laser and the imaged image-aperture adjusts the energy to a desired level by running the laser in a "constant voltage" mode. The process provides reproducibility and controllability for deposition of electronic thin films by pulsed laser deposition.

Geological principles of exploration for sandstone-hosted uranium deposits

International Nuclear Information System (INIS)

Le Roux, J.P.

1982-10-01

Although the importance of sandstone-hosted uranium deposits has seemingly faded in recent years due to the discovery of large, high -grade deposits elsewhere, a forecasted energy shortage in the near future will probably necessitate a new look at sedimentary basins as a source of uranium. Back-arc basins adjacent to calcalkaline source areas are especially favourable if they are filled with fluvial, post-Devonian sediments. Syn- and post-depositional tectonics play an important role in the sedimentation-mineralisation process and should be investigated. The oxidation-reduction state of the sandstones is a valid prospecting tool. Sedimentological environments govern the permeability and vegetal matter content of sandstones and directly control uranium mineralisation

Deposition characteristics of titanium coating deposited on SiC fiber by cold-wall chemical vapor deposition

Energy Technology Data Exchange (ETDEWEB)

Luo, Xian, E-mail: luo_shenfan@hotmail.com; Wu, Shuai; Yang, Yan-qing; Jin, Na; Liu, Shuai; Huang, Bin

2016-12-01

The deposition characteristics of titanium coating on SiC fiber using TiCl{sub 4}-H{sub 2}-Ar gas mixture in a cold-wall chemical vapor deposition were studied by the combination of thermodynamic analysis and experimental studies. The thermodynamic analysis of the reactions in the TiCl{sub 4}-H{sub 2}-Ar system indicates that TiCl{sub 4} transforms to titanium as the following paths: TiCl{sub 4} → TiCl{sub 3} → Ti, or TiCl{sub 4} → TiCl{sub 3} → TiCl{sub 2} → Ti. The experimental results show that typical deposited coating contains two distinct layers: a TiC reaction layer close to SiC fiber and titanium coating which has an atomic percentage of titanium more than 70% and that of carbon lower than 30%. The results illustrate that a carbon diffusion barrier coating needs to be deposited if pure titanium is to be prepared. The deposition rate increases with the increase of temperature, but higher temperature has a negative effect on the surface uniformity of titanium coating. In addition, appropriate argon gas flow rate has a positive effect on smoothing the surface morphology of the coating. - Highlights: • Both thermodynamic analysis and experimental studies were adopted in this work. • The transformation paths of TiCl{sub 4} to Ti is: TiCl{sub 4} → TiCl{sub 3} → Ti, or TiCl{sub 4} → TiCl{sub 3} → TiCl{sub 2} → Ti. • Typical deposited Ti coating on SiC fiber contained two distinct layers. • Deposition temperature is important on deposition rate and morphologies. • Appropriate argon gas flow rate has a positive effect on smoothing of the coating.

The NSLS-II Multilayer Laue Lens Deposition System

International Nuclear Information System (INIS)

Conley, R.; Bouet, N.; Biancarosa, J.; Shen, Q.; Boas, L.; Feraca, J.; Rosenbaum, L.

2009-01-01

The NSLS-II(1) program has a requirement for an unprecedented level of x-ray nanofocusing and has selected the wedged multilayer Laue lens(2,3) (MLL) as the optic of choice to meet this goal. In order to fabricate the MLL a deposition system is required that is capable of depositing depth-graded and laterally-graded multilayers with precise thickness control over many thousands of layers, with total film growth in one run up to 100 m thick or greater. This machine design expounds on the positive features of a rotary deposition system(4) constructed previously for MLLs and will contain multiple stationary, horizontally-oriented magnetron sources where a transport will move a substrate back and forth in a linear fashion over shaped apertures at well-defined velocities to affect a multilayer coating.

Coronary triglyceride deposition in contemporary advanced diabetics.

Science.gov (United States)

Ikeda, Yoshihiko; Zaima, Nobuhiro; Hirano, Ken-ichi; Mano, Masayuki; Kobayashi, Kunihisa; Yamada, Sohsuke; Yamaguchi, Satoshi; Suzuki, Akira; Kanzaki, Hideaki; Hamasaki, Toshimitsu; Kotani, Jun-ichi; Kato, Seiya; Nagasaka, Hironori; Setou, Mitsutoshi; Ishibashi-Ueda, Hatsue

2014-07-01

It is of importance to clarify pathophysiology of diabetic heart diseases such as heart failure and coronary artery disease. We reported a novel clinical phenotype called triglyceride deposit cardiomyovasculopathy (TGCV), showing aberrant TG accumulation in both coronary arteries and myocardium, in a cardiac transplant recipient. Here, we examined autopsied diabetics for TG deposition in cardiovasculature. Consecutive series of hearts from advanced diabetes mellitus (DM) subjects (DM group: DMG, n = 20) and those from age- and sex-matched non-diabetic controls (non DM group: NDMG, n = 20) were examined. The diagnostic criteria of 'advanced DM' was made based on 2014 Clinical Practice Recommendations proposed by the American Diabetes Association. The mean duration of DM was 15.8 years. All DMG suffered from heart diseases including coronary artery diseases and 14 subjects had multi-vessel disease. Tissue TG contents were measured biochemically. Coronary arterial TG contents was significantly higher in DMG compared with NDMG. Spatial distribution of TG in transverse sections of coronary arteries showed TG deposition mainly in smooth muscle cells by Imaging Mass Spectrometry. Abundant TG deposition in coronary artery might be associated with advanced DM. © 2014 Japanese Society of Pathology and Wiley Publishing Asia Pty Ltd.

Deposition of Boron in Possible Evaporite Deposits in Gale Crate

Science.gov (United States)

Gasda, P. J.; Peets, E.; Lamm, S. N.; Rapin, W.; Lanza, N.; Frydenvang, J.; Clark, B. C.; Herkenhoff, K. E.; Bridges, J.; Schwenzer, S. P.; Haldeman, E. B.; Wiens, R. C.; Maurice, S.; Clegg, S. M.; Delapp, D.; Sanford, V.; Bodine, M. R.; McInroy, R.

2017-12-01

Boron has been previously detected in Gale crater using the ChemCam instrument on board the NASA Curiosity rover within calcium sulfate fracture fill hosted by lacustrine mudstone and eolian sandstone units. Recent results show that up to 300 ppm B is present in the upper sections of the lacustrine unit. Boron has been detected in both the groundwater-emplaced calcium sulfate fracture fill materials and bedding-parallel calcium sulfate layers. The widespread bedding-parallel calcium sulfate layers within the upper strata of the lacustrine bedrock that Curiosity has encountered recently could be interpreted as primary evaporite deposits. We have two hypotheses for the history of boron in Gale crater. In both hypotheses, borates were first deposited as lake water evaporated, depositing primary evaporates that were later re-dissolved by groundwater, which redistributed the boron into secondary evaporitic calcium sulfate fracture fill deposits. In the first scenario, Gale crater may have undergone a period of perennial lake formation during a drier period of martian history, depositing layers of evaporitic minerals (including borates) among lacustrine mudstone layers. In the second scenario, lake margins could have become periodically exposed during cyclic drops in lake level and subsequently desiccated. Evaporites were deposited and desiccation features were formed in lowstand deposits. Either hypothetical scenario of evaporite deposition would promote prebiotic chemical reactions via wet-dry cycles. Boron may be an important prebiotic element, and as such, its presence in ancient martian surface and groundwater provides evidence that important prebiotic chemical reactions could occur on Mars if organics were present. The presence of boron in ancient Gale crater groundwater also provides additional evidence that a habitable environment existed in the martian subsurface well after the expected disappearance of liquid water on the surface of Mars. We will report on the

Supersonic cluster beams: a powerful method for the deposition of nanostructured thin films with tailored properties

International Nuclear Information System (INIS)

Milani, P.

2002-01-01

By using a pulsed micro-plasma cluster source and by exploiting aero-dynamical effects typical of supersonic beams it is possible to obtain very high deposition rates with a control on neutral cluster mass distribution, allowing the deposition of thin films with controlled nanostructure. Due to high deposition rates, high lateral resolution, low temperature processing supersonic cluster beams can also be used for the micro and nano-patterning of cluster-assembled films when little or no post-growth manipulation or assembly is required. For example the nano and meso-structure of films obtained by carbon cluster beam deposition can be controlled by selecting in the beam the elemental building blocks, moreover functional properties such as field emission can be controlled and tailored. The use of supersonic cluster beams opens also new perspectives for the production of nano-structured films with novel physico-chemical and topological properties such as nano-structured carbon matrices containing carbide and transition metal particles. (Author)

Geometrical Characterization of Sediment Deposits at the Confluence of Mountain Streams

Directory of Open Access Journals (Sweden)

Laura Maria Stancanelli

2018-03-01

Full Text Available Debris flow injections from tributaries into a main mountain stream generate deposits of sediments which, in turn, result in obstruction and eventual damming of the river section. This contribution presents the results of a series of flume experiments on the dynamics of these deposits, with reference to three different types of blockage: no blockage, partial blockage, and full blockage. Results show that the shape of the deposit is mainly controlled by the ratio between the debris flow discharge and the main river discharge. The experimental dataset is used to develop a deposit resilience stability index based on the shape of the deposit contour retrieved from photos taken from above. The proposed index is based on the invariant elliptic Fourier coefficients and the dimensionless transverse obstruction parameter. The elliptic Fourier coefficients give information on the symmetry of the deposit contour. High symmetry indicates more stable and resilient deposits. The proposed index is calibrated on the basis of the flume experiments and tested with field data. The results are quite promising and suggest that the index can be appropriate for a fast hazard assessment of multiple debris flow deposits at a regional scale.

Controllable deposition of platinum nanoparticles on single-wall carbon nanohorns as catalyst for direct methanol fuel cells.

Science.gov (United States)

Niu, Ben; Xu, Wei; Guo, Zhengduo; Zhou, Nengzhi; Liu, Yang; Shi, Zujin; Lian, Yongfu

2012-09-01

Uniform and well dispersed platinum nanoparticles were successfully deposited on single-walled carbon nanohorns with the assistance of 4,4-dipydine and ion liquids, respectively. In particular, the size of platinum nanoparticles could be controlled in a very narrow range (2.2 to 2.5 nm) when ion liquids were applied. The crystalline nature of these platinum nanoparticles was confirmed by high resolution transmission electron microscopy observation and X-ray power diffraction analysis, and two species of platinum Pt(0) and Pt(II) were detected by X-ray photoelectron spectroscopy. Electrochemical studies revealed that thus obtained nanocomposites had much better electrocatalytic activity for the methanol oxidation than those prepared with carbon nanotubes as supporter.

The late cretaceous Donlin Creek gold deposit, Southwestern Alaska: Controls on epizonal ore formation

Science.gov (United States)

Goldfarb, R.J.; Ayuso, R.; Miller, M.L.; Ebert, S.W.; Marsh, E.E.; Petsel, S.A.; Miller, L.D.; Bradley, D.; Johnson, Chad; McClelland, W.

2004-01-01

The Donlin Creek gold deposit, southwestern Alaska, has an indicated and inferred resource of approximately 25 million ounces (Moz) Au at a cutoff grade of 1.5 g/t. The ca. 70 Ma deposit is hosted in the Late Cretaceous Kuskokwim flysch basin, which developed in the back part of the are region of an active continental margin, on previously accreted oceanic terranes and continental fragments. A hypabyssal, mainly rhyolitic to rhyodacitic, and commonly porphyritic, 8- ?? 3-km dike complex, part of a regional ca. 77 to 58 Ma magmatic arc, formed a structurally competent host for the mineralization. This deposit is subdivided into about one dozen distinct prospects, most of which consist of dense quartz ?? carbonate veinlet networks that fill north-northeast-striking extensional fractures in the northeast-trending igneous rocks. The sulfide mineral assemblage is dominated by arsenopyrite, pyrite, and, typically younger, stibnite; gold is refractory within the arsenopyrite. Sericitization, carbonatization, and suffidation were the main alteration processes. Fluid inclusion studies of the quartz that hosts the resource indicate dominantly aqueous ore fluids with also about 3 to 7 mol percent CO2 ?? CH4 and a few tenths to a few mole percent NaCl + KCl. The gold-bearing fluids were mainly homogeneously trapped at approximately 275?? to 300??C and at depths of 1 to 2 km. Some of the younger stibnite may have been deposited by late-stage aqueous fluids at lower temperature. Measured ??18O values for the gold-bearing quartz range between 11 and 25 per mil; the estimated ??18O fluid values range from 7 to 12 per mil, suggesting a mainly crustally derived fluid. A broad range of measured ??D values for hydrothermal micas, between -150 and -80 per mil, is suggestive of a contribution from devolatilization of organic matter and/or minor amounts of mixing with meteoric fluids. Gold-associated hydrothermal sulfide minerals are characterized by ??34S values mainly between -16 and

Geochemical and modal data for igneous rocks associated with epithermal mineral deposits

Science.gov (United States)

du Bray, Edward A.

2014-01-01

The purposes of this report are to (1) present available geochemical and modal data for igneous rocks associated with epithermal mineral deposits and (2) to make those data widely and readily available for subsequent, more in-depth consideration and interpretation. Epithermal precious and base-metal deposits are commonly associated with subduction-related calc-alkaline to alkaline arc magmatism as well as back-arc continental rift magmatism. These deposits form in association with compositionally diverse extrusive and intrusive igneous rocks. Temperature and depth regimes prevailing during deposit formation are highly variable. The deposits form from hydrothermal fluids that range from acidic to near-neutral pH, and they occur in a variety of structural settings. The disparate temperature, pressure, fluid chemistry, and structural controls have resulted in deposits with wide ranging characteristics. Economic geologists have employed these characteristics to develop classification schemes for epithermal deposits and to constrain the important genetic processes responsible for their formation.

Experimental investigation on the effect of ultrasonic waves on reducing asphaltene deposition and improving oil recovery under temperature control.

Science.gov (United States)

Rezaei Dehshibi, Reza; Mohebbi, Ali; Riazi, Masoud; Niakousari, Mehrdad

2018-07-01

A well-known complication in the oil reservoir during oil production is asphaltene deposition in and around the production wellbore. Deposition of asphaltene around the production wellbore may cause a significant pressure drop and in turn loss of efficiency in the production process. Various mechanical and chemical methods have been employed in order to reduce asphaltene formation or to eliminate the precipitate. A novel technique which presented a great potential for prevention or elimination of asphaltene is spreading out the high energy ultrasound wave within the oil reservoir. In this study, in a glass micro-model, asphaltene precipitation was first simulated in a transparent porous medium and its removal by application of high energy ultrasound wave was then investigated. To simulate asphaltene precipitation, the micro-model was first saturated with oil and then a normal-pentane was injected. This was followed by flooding the porous media with brine while propagating ultrasound waves (30 kHz and 100 W) to eliminate asphaltene precipitation. The experiment setup was equipped with a temperature controller. The results indicate a significant reduction in asphaltene precipitation in the oil reservoir may be achieved by application of ultrasound energy. Asphaltene particle deposition has been solved reversibly in the oil layer of porous medium and with the oil layering mechanism, the rate of oil production has been increased. In some spots, water/oil emulsion has been formed because of the ultrasonic vibration on the wall. Both the crude and synthetic oils were examined. Copyright © 2018 Elsevier B.V. All rights reserved.

Crystalline phase control and growth selectivity of β-MnO{sub 2} thin films by remote plasma assisted pulsed laser deposition

Energy Technology Data Exchange (ETDEWEB)

Abi-Akl, M.; Tabbal, M., E-mail: malek.tabbal@aub.edu.lb; Kassem, W.

2016-08-01

In this paper, we exploit the effect of coupling an oxygen remote plasma source to Pulsed Laser Deposition (PLD) for the growth of pure and well crystallized β-MnO{sub 2} films. Films were grown on Si substrates by laser ablation of a MnO target in oxygen ambient and remote plasma. X-Ray Diffraction, Fourier Transform Infra-Red spectroscopy and Raman scattering were used to determine the crystalline structure and bonding in the grown layers, whereas Atomic Force Microscopy was used to study their morphology and surface roughness. Deposition at 500 °C and high oxygen pressure (33.3–66.6 Pa) resulted in the formation of films with roughness of 12 nm consisting of nsutite γ-MnO{sub 2}, a structure characterized by the intergrowth of the pyrolusite β-MnO{sub 2} in a ramsdellite R-MnO{sub 2} matrix. Deposition at the same temperature but low pressure (1.33–3.33 Pa) in oxygen ambient lead to the formation of Mn{sub 2}O{sub 3} whereas plasma activation within the same pressure range induced the growth of single phase highly crystalline β-MnO{sub 2} having smooth surfaces with a roughness value of 0.6 nm. Such results underline the capability of remote plasma assisted PLD in selecting and controlling the crystalline phase of manganese oxide layers. - Highlights: • MnO{sub 2} films were grown by Remote Plasma Assisted Pulsed Laser Deposition. • Crystalline MnO{sub 2} is formed at a substrate temperature of 500 °C. • Smooth crystalline single phase β-MnO{sub 2} films were obtained at 1.33–3.33 Pa. • Deposition at 1.33–3.33 Pa without plasma activation lead to the growth of Mn{sub 2}O{sub 3}. • Without plasma, mixed phases of MnO{sub 2} polymorphs are obtained at 33.3 Pa and above.

Economical Atomic Layer Deposition

Science.gov (United States)

Wyman, Richard; Davis, Robert; Linford, Matthew

2010-10-01

Atomic Layer Deposition is a self limiting deposition process that can produce films at a user specified height. At BYU we have designed a low cost and automated atomic layer deposition system. We have used the system to deposit silicon dioxide at room temperature using silicon tetrachloride and tetramethyl orthosilicate. Basics of atomic layer deposition, the system set up, automation techniques and our system's characterization are discussed.

Enhanced sensitivity of surface plasmon resonance phase-interrogation biosensor by using oblique deposited silver nanorods.

Science.gov (United States)

Chung, Hung-Yi; Chen, Chih-Chia; Wu, Pin Chieh; Tseng, Ming Lun; Lin, Wen-Chi; Chen, Chih-Wei; Chiang, Hai-Pang

2014-01-01

Sensitivity of surface plasmon resonance phase-interrogation biosensor is demonstrated to be enhanced by oblique deposited silver nanorods. Silver nanorods are thermally deposited on silver nanothin film by oblique angle deposition (OAD). The length of the nanorods can be tuned by controlling the deposition parameters of thermal deposition. By measuring the phase difference between the p and s waves of surface plasmon resonance heterodyne interferometer with different wavelength of incident light, we have demonstrated that maximum sensitivity of glucose detection down to 7.1 × 10(-8) refractive index units could be achieved with optimal deposition parameters of silver nanorods.

Critical elements in Carlin, epithermal, and orogenic gold deposits

Science.gov (United States)

Goldfarb, Richard J.; Hofstra, Albert H.; Simmons, Stuart F.

2016-01-01

Carlin, epithermal, and orogenic gold deposits, today mined almost exclusively for their gold content, have similar suites of anomalous trace elements that reflect similar low-salinity ore fluids and thermal conditions of metal transport and deposition. Many of these trace elements are commonly referred to as critical or near-critical elements or metals and have been locally recovered, although typically in small amounts, by historic mining activities. These elements include As, Bi, Hg, In, Sb, Se, Te, Tl, and W. Most of these elements are now solely recovered as by-products from the milling of large-tonnage, base metal-rich ore deposits, such as porphyry and volcanogenic massive sulfide deposits.A combination of dominance of the world market by a single country for a single commodity and a growing demand for many of the critical to near-critical elements could lead to future recovery of such elements from select epithermal, orogenic, or Carlin-type gold deposits. Antimony continues to be recovered from some orogenic gold deposits and tellurium could potentially be a primary commodity from some such deposits. Tellurium and indium in sphalerite-rich ores have been recovered in the past and could be future commodities recovered from epithermal ores. Carlin-type gold deposits in Nevada are enriched in and may be a future source for As, Hg, Sb, and/or Tl. Some of the Devonian carbonaceous host rocks in the Carlin districts are sufficiently enriched in many trace elements, including Hg, Se, and V, such that they also could become resources. Thallium may be locally enriched to economic levels in Carlin-type deposits and it has been produced from Carlin-like deposits elsewhere in the world (e.g., Alsar, southern Macedonia; Lanmuchang, Guizhou province, China). Mercury continues to be recovered from shallow-level epithermal deposits, as well as a by-product of many Carlin-type deposits where refractory ore is roasted to oxidize carbon and pyrite, and mercury is then

High rate deposition of thin film cadmium sulphide by pulsed direct current magnetron sputtering

Energy Technology Data Exchange (ETDEWEB)

Lisco, F., E-mail: F.Lisco@lboro.ac.uk [Centre for Renewable Energy Systems Technology (CREST), School of Electronic, Electrical and Systems Engineering, Loughborough University, Leicestershire LE11 3TU (United Kingdom); Kaminski, P.M.; Abbas, A.; Bowers, J.W.; Claudio, G. [Centre for Renewable Energy Systems Technology (CREST), School of Electronic, Electrical and Systems Engineering, Loughborough University, Leicestershire LE11 3TU (United Kingdom); Losurdo, M. [Institute of Inorganic Methodologies and of Plasmas, IMIP-CNR, via Orabona 4, 70126 Bari (Italy); Walls, J.M. [Centre for Renewable Energy Systems Technology (CREST), School of Electronic, Electrical and Systems Engineering, Loughborough University, Leicestershire LE11 3TU (United Kingdom)

2015-01-01

Cadmium Sulphide (CdS) is an important n-type semiconductor widely used as a window layer in thin film photovoltaics Copper Indium Selenide, Copper Indium Gallium (di)Selenide, Copper Zinc Tin Sulphide and Cadmium Telluride (CdTe). Cadmium Sulphide has been deposited using a number of techniques but these techniques can be slow (chemical bath deposition and Radio Frequency sputtering) or the uniformity and the control of thickness can be relatively difficult (close space sublimation). In this paper we report on the development of a process using pulsed Direct Current magnetron sputtering which allows nanometre control of thin film thickness using time only. The CdS thin films deposited in this process are highly uniform and smooth. They exhibit the preferred hexagonal structure at room temperature deposition and they have excellent optical properties. Importantly, the process is highly stable despite the use of a semi-insulating magnetron target. Moreover, the process is very fast. The deposition rate using 1.5 kW of power to a 6-inch circular magnetron was measured to be greater than 8 nm/s. This makes the process suitable for industrial deployment. - Highlights: • Pulsed DC magnetron sputtering of CdS • High deposition rate deposition • Uniform, pinhole free films.

High rate deposition of thin film cadmium sulphide by pulsed direct current magnetron sputtering

International Nuclear Information System (INIS)

Lisco, F.; Kaminski, P.M.; Abbas, A.; Bowers, J.W.; Claudio, G.; Losurdo, M.; Walls, J.M.

2015-01-01

Cadmium Sulphide (CdS) is an important n-type semiconductor widely used as a window layer in thin film photovoltaics Copper Indium Selenide, Copper Indium Gallium (di)Selenide, Copper Zinc Tin Sulphide and Cadmium Telluride (CdTe). Cadmium Sulphide has been deposited using a number of techniques but these techniques can be slow (chemical bath deposition and Radio Frequency sputtering) or the uniformity and the control of thickness can be relatively difficult (close space sublimation). In this paper we report on the development of a process using pulsed Direct Current magnetron sputtering which allows nanometre control of thin film thickness using time only. The CdS thin films deposited in this process are highly uniform and smooth. They exhibit the preferred hexagonal structure at room temperature deposition and they have excellent optical properties. Importantly, the process is highly stable despite the use of a semi-insulating magnetron target. Moreover, the process is very fast. The deposition rate using 1.5 kW of power to a 6-inch circular magnetron was measured to be greater than 8 nm/s. This makes the process suitable for industrial deployment. - Highlights: • Pulsed DC magnetron sputtering of CdS • High deposition rate deposition • Uniform, pinhole free films

Impact Response of Thermally Sprayed Metal Deposits

Science.gov (United States)

Wise, J. L.; Hall, A. C.; Moore, N. W.; Pautz, S. D.; Franke, B. C.; Scherzinger, W. M.; Brown, D. W.

2017-06-01

Gas-gun experiments have probed the impact response of tantalum specimens that were additively manufactured using a controlled thermal spray deposition process. Velocity interferometer (VISAR) diagnostics provided time-resolved measurements of sample response under one-dimensional (i . e . , uniaxial strain) shock compression to peak stresses ranging between 1 and 4 GPa. The acquired wave-profile data have been analyzed to determine the Hugoniot Elastic Limit (HEL), Hugoniot equation of state, and high-pressure yield strength of the thermally deposited samples for comparison to published baseline results for conventionally wrought tantalum. The effects of composition, porosity, and microstructure (e . g . , grain/splat size and morphology) are assessed to explain differences in the dynamic mechanical behavior of spray-deposited versus conventional material. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

Particle deposition from aqueous suspensions in turbulent pipe flow - a comparison of observed deposition rates and predicted arrival rates

International Nuclear Information System (INIS)

Rodliffe, R.S.

1979-11-01

At the present time, there appear to be only four adequately controlled and characterised experimental studies of particle deposition from single phase water in turbulent pipe flow. These are used to illustrate the ranges of applicability of methods for predicting particle arrival rates at tube walls. Arrival rates are predicted from mass transfer correlations and the theory of Reeks and Skyrme (1976) when transport is limited by Brownian diffusion and inertial behaviour, respectively. The regimes in which finite particle size limits the application of these methods are defined and preliminary consideration is given to the conditions under which gravitational settling may make a contribution to deposition in vertically mounted tubes. (author)

OES control of a low-pressure DC arc at TiN layer deposition

International Nuclear Information System (INIS)

Andreev, M.A.; Maksimenko, V.N.; Ershov-Pavlov, E.A.

1995-01-01

Results are presented of a low-pressure DC arc study as applied for a deposition of TiN wear-resistant coatings in a commercial plant. Plasma parameters of the arc have been measured by optical emission spectroscopy. The plasma emission spectra have been recorded using a grating spectrometer equipped with an on line computer. Changes in the resulting layers due to a difference in working conditions have been determined by metallography and X-ray analysis giving composition, microstructure and thickness of the resulting layers. Using the data, a correlation between emission spectra of the arc and the TiN layer characteristics has been found. The results allow monitoring parameters of the deposition process to obtain necessary quality of the layer and to increase the process efficiency

A Palaeoproterozoic multi-stage hydrothermal alteration system at Nalunaq gold deposit, South Greenland

DEFF Research Database (Denmark)

Bell, Robin-Marie; Kolb, Jochen; Waight, Tod Earle

2017-01-01

Nalunaq is an orogenic, high gold grade deposit situated on the Nanortalik Peninsula, South Greenland. Mineralisation is hosted in shear zone-controlled quartz veins, located in fine- and medium-grained amphibolite. The deposit was the site of Greenland’s only operating metalliferous mine until i...

Achieving uniform layer deposition by atmospheric-pressure plasma-enhanced chemical vapor deposition

Energy Technology Data Exchange (ETDEWEB)

Lee, Jae-Ok [Department of Plasma Engineering, Korea Institute of Machinery & Materials (KIMM), Daejeon 305-343 (Korea, Republic of); Kang, Woo Seok, E-mail: kang@kimm.re.kr [Department of Plasma Engineering, Korea Institute of Machinery & Materials (KIMM), Daejeon 305-343 (Korea, Republic of); Department of Environment & Energy Mechanical Engineering, University of Science & Technology (UST), Daejeon 305-350 (Korea, Republic of); Hur, Min; Lee, Jin Young [Department of Plasma Engineering, Korea Institute of Machinery & Materials (KIMM), Daejeon 305-343 (Korea, Republic of); Song, Young-Hoon [Department of Plasma Engineering, Korea Institute of Machinery & Materials (KIMM), Daejeon 305-343 (Korea, Republic of); Department of Environment & Energy Mechanical Engineering, University of Science & Technology (UST), Daejeon 305-350 (Korea, Republic of)

2015-12-31

This work investigates the use of plasma-enhanced chemical vapor deposition under atmospheric pressure for achieving uniform layer formation. Electrical and optical measurements demonstrated that the counterbalance between oxygen and precursors maintained the homogeneous discharge mode, while creating intermediate species for layer deposition. Several steps of the deposition process of the layers, which were processed on a stationary stage, were affected by flow stream and precursor depletion. This study showed that by changing the flow streamlines using substrate stage motion uniform layer deposition under atmospheric pressure can be achieved. - Highlights: • Zirconium oxide was deposited by atmospheric-pressure plasma-enhanced chemical vapor deposition. • Homogeneous plasma was maintained by counterbalancing between discharge gas and precursors. • Several deposition steps were observed affected by the gas flow stream and precursor depletion. • Thin film layer was uniformly grown when the substrate underwent a sweeping motion.

Pulsed laser deposition in Twente: from research tool towards industrial deposition

NARCIS (Netherlands)

Blank, David H.A.; Dekkers, Jan M.; Rijnders, Augustinus J.H.M.

2014-01-01

After the discovery of the perovskite high Tc superconductors in 1986, a rare and almost unknown deposition technique attracted attention. Pulsed laser deposition (PLD), or laser ablation as it was called in the beginning, became popular because of the possibility to deposit complex materials, like

Electrophoretic deposits of boron on duralumin plates used for measuring neutron flux

International Nuclear Information System (INIS)

Lang, F.M.; Magnier, P.; Finck, C.

1956-01-01

Preparation of boron thin film deposits of around 1 mg per cm 2 on duralumin plates with a diameter of 8 cm. The boron coated plates for ionization chambers were originally prepared at the CEA by pulverization of boron carbides on sodium silicates. This method is not controlling precisely enough the quantity of boron deposit. Thus, an electrophoretic method is considered for a better control of the quantity of boron deposit in the scope of using in the future boron 10 which is costly and rare. The method described by O. Flint is not satisfying enough and a similar electrophoretic process has been developed. Full description of the method is given as well as explanation of the use of dried methanol as solvent, tannin as electrolyte and magnesium chloride to avoid alumina formation. (M.P.)

Structural controls and evolution of gold-, silver-, and REE-bearing copper-cobalt ore deposits, Blackbird district, east-central Idaho: Epigenetic origins

Science.gov (United States)

Lund, K.; Tysdal, Russell G.; Evans, Karl V.; Kunk, Michael J.; Pillers, Renee M.

2011-01-01

The Cu-Co ± Au (± Ag ± Ni ± REE) ore deposits of the Blackbird district, east-central Idaho, have previously been classified as Besshi-type VMS, sedex, and IOCG deposits within an intact stratigraphic section. New studies indicate that, across the district, mineralization was introduced into the country rocks as a series of structurally controlled vein and alteration systems. Quartz-rich and biotite-rich veins (and alteration zones) and minor albite and siderite veinlets maintain consistent order and sulfide mineral associations across the district. Both early and late quartz veins contain chalcopyrite and pyrite, whereas intermediate-stage tourmaline-biotite veins host the cobaltite. Barren early and late albite and late carbonate (generally siderite) form veins or are included in the quartz veins. REE minerals, principally monazite, allanite, and xenotime, are associated with both tourmaline-biotite and late quartz veins. The veins are in mineralized intervals along axial planar cleavage, intrafolial foliation, and shears.

Plasma deposition of polymer composite films incorporating nanocellulose whiskers

Science.gov (United States)

Samyn, P.; Airoudj, A.; Laborie, M.-P.; Mathew, A. P.; Roucoules, V.

2011-11-01

In a trend for sustainable engineering and functionalization of surfaces, we explore the possibilities of gas phase processes to deposit nanocomposite films. From an analysis of pulsed plasma polymerization of maleic anhydride in the presence of nanocellulose whiskers, it seems that thin nanocomposite films can be deposited with various patterns. By specifically modifying plasma parameters such as total power, duty cycle, and monomer gas pressure, the nanocellulose whiskers are either incorporated into a buckled polymer film or single nanocellulose whiskers are deposited on top of a polymeric film. The density of the latter can be controlled by modifying the exact positioning of the substrate in the reactor. The resulting morphologies are evaluated by optical microscopy, AFM, contact angle measurements and ellipsometry.

Development of atmospheric acid deposition in China from the 1990s to the 2010s

International Nuclear Information System (INIS)

Yu, Haili; He, Nianpeng; Wang, Qiufeng; Zhu, Jianxing; Gao, Yang; Zhang, Yunhai; Jia, Yanlong; Yu, Guirui

2017-01-01

Atmospheric acid deposition is a global environmental issue. China has been experiencing serious acid deposition, which is anticipated to become more severe with the country's economic development and increasing consumption of fossil fuels in recent decades. We explored the spatiotemporal variations of acid deposition (wet acid deposition) and its influencing factors by collecting nationwide data on pH and concentrations of sulfate (SO 4 2− ) and nitrate (NO 3 − ) in precipitation between 1980 and 2014 in China. Our results showed that average precipitation pH values were 4.59 and 4.70 in the 1990s and 2010s, respectively, suggesting that precipitation acid deposition in China has not seriously worsened. Average SO 4 2− deposition declined from 40.54 to 34.87 kg S ha −1 yr −1 but average NO 3 − deposition increased from 4.44 to 7.73 kg N ha −1 yr −1 . Specifically, the area of severe precipitation acid deposition in southern China has shrunk to some extent as a result of controlling the pollutant emissions; but the area of moderate precipitation acid deposition has expanded in northern China, associated with rapid industrial and transportation development. Furthermore, we found significant positive correlations between precipitation acid deposition, energy consumption, and rainfall. Our findings provide a relatively comprehensive evaluation of the spatiotemporal dynamics of precipitation acid deposition in China over past three decades, and confirm the idea that strategies implemented to save energy and control pollutant emissions in China have been effective in alleviating precipitation acid deposition. These findings might be used to demonstrate how developing countries could achieve economic development and environmental protection through the implementation of advanced technologies to reduce pollutant emissions. - Highlights: • Explore spatial and temporal dynamics of wet acid deposition during three decades in China. • Acid

Regional deposition of inhaled fog droplets: preliminary observations

International Nuclear Information System (INIS)

Bowes, S.M. III; Laube, B.L.; Links, J.M.; Frank, R.

1989-01-01

The regional deposition of a monodisperse 10-micron mass median aerodynamic diameter fog was studied in four healthy adult male nonsmokers. The fog was radiolabeled with technetium-99m sulfur colloid to enable detection by an Anger camera of deposited activity in the following regions of the respiratory tract: oropharynx, larynx, trachea, and intrapulmonary airways. Intrapulmonary deposition was further analyzed by computer with inner, intermediate, and outer zones, and within apical, intermediate and basal zones of the right lung. The radiolabeled aerosol was inhaled by mouth through a face-mask with the nasal airway occluded. Respiratory frequency, tidal volume, and jaw position were controlled and were commensurate with the oral component of oronasal breathing during moderate exercise. Deposition in the larynx, trachea, and intrapulmonary airways was a function of the scrubbing efficiency of the oropharynx, which differed substantially among subjects, and ranged from 72 to 99%. The density of the aerosol deposit in the larynx probably exceeded that of any of the subdivisions of the tracheobronchial tree and lung. Within the lung, deposition favored the inner zone (assumed to contain the larger airways) over the outer zone (assumed to be dominated by smaller airways and alveoli). Intrapulmonary aerosol distribution in an elderly subject with borderline evidence of airway obstruction differed from that observed in younger subjects. The possible consequences of altered lung elastic recoil, as may occur with aging, for regional dosimetry is discussed

Effects of deposition time in chemically deposited ZnS films in acidic solution

Energy Technology Data Exchange (ETDEWEB)

Haddad, H.; Chelouche, A., E-mail: azeddinechelouche@gmail.com; Talantikite, D.; Merzouk, H.; Boudjouan, F.; Djouadi, D.

2015-08-31

We report an experimental study on the synthesis and characterization of zinc sulfide (ZnS) single layer thin films deposited on glass substrates by chemical bath deposition technique in acidic solution. The effect of deposition time on the microstructure, surface morphology, optical absorption, transmittance, and photoluminescence (PL) was investigated by X-ray diffraction (XRD), scanning electronic microscopy (SEM), UV-Vis–NIR spectrophotometry and photoluminescence (PL) spectroscopy. The results showed that the samples exhibit wurtzite structure and their crystal quality is improved by increasing deposition time. The latter, was found to affect the morphology of the thin films as showed by SEM micrographs. The optical measurements revealed a high transparency in the visible range and a dependence of absorption edge and band gap on deposition time. The room temperature PL spectra indicated that all ZnS grown thin films emit a UV and blue light, while the band intensities are found to be dependent on deposition times. - Highlights: • Single layer ZnS thin films were deposited by CBD in acidic solution at 95 °C. • The effect of deposition time was investigated. • Coexistence of ZnS and ZnO hexagonal structures for time deposition below 2 h • Thicker ZnS films were achieved after monolayer deposition for 5 h. • The highest UV-blue emission observed in thin film deposited at 5 h.

Uraniferous surficial deposits

International Nuclear Information System (INIS)

Toens, P.D.; Hambleton-Jones, B.B.

1980-10-01

As a result of the discovery of uranium in surficial deposits of Tertiary to Recent age, in Australia and Southern Africa, increasing attention is being paid to the location and understanding of the genesis of these deposits. The paper discusses the definitions and terminology currently in use and a classification of these deposits is presented. It is concluded that in order to obtain a measure of clarity, the terms calcrete, gypcrete and dolocrete should not be used to describe the uraniferous valley-fill deposits of Southern Africa and Australia [af

Sandstone-type uranium deposits

International Nuclear Information System (INIS)

Austin, S.R.; D'Andrea, R.F. Jr.

1978-01-01

Three overall factors are necessary for formation of uranium deposits in sandstone: a source of uranium, host rocks capable of transmitting uranium-bearing solutions, and a precipitant. Possible sources of uranium in sandstone-type deposits include groundwaters emanating from granitic highlands, arkosic sediments, tuffaceous material within or overlying the host rocks, connate fluids, and overlying black shales. The first three sources are considered the most likely. Host rocks are generally immature sandstones deposited in alluvial-fan, intermontane-basin or marginal-marine environments, but uranium deposits do occur in well-winnowed barrier-bar or eolian sands. Host rocks for uranium deposits generally show coefficients of permeability on the order of 1 to 100 gal/day/ft 2 . Precipitants are normally agents capable of reducing uranium from the uranyl to the uranous state. The association of uranium with organic matter is unequivocal; H 2 S, a powerful reductant, may have been present at the time of formation of some deposits but may go unnoticed today. Vanadium can serve to preserve the tabular characteristics of some deposits in the near-surface environment, but is considered an unlikely primary precipitant for uranium. Uranium deposits in sandstone are divided into two overall types: peneconcordant deposits, which occur in locally reducing environments in otherwise oxidized sandstones; and roll-type deposits, which occur at the margin of an area where an oxidized groundwater has permeated an otherwise reduced sandstone. Uranium deposits are further broken down into four subclasses; these are described

Plasma-deposited aluminum-doped zinc oxide : controlling nucleation, growth and electrical properties

NARCIS (Netherlands)

Ponomarev, M.

2012-01-01

In this work, the Expanding Thermal Plasma (ETP) deposition technique was employed to study the growth development of ZnO:Al thin film as a transparent conductive oxide layer for sustainable applications. Characteristic for ETP-grown ZnO:Al is a gradually reducing resistivity of the growing layer

111In-platelet and 125I-fibrinogen deposition in the lungs in experimental acute pancreatitis

International Nuclear Information System (INIS)

Goulbourne, I.A.; Watson, H.; Davies, G.C.

1987-01-01

An experimental model of acute pancreatitis in rats has been used to study intrapulmonary 125 I-fibrinogen and 111 In-platelet deposition. Pancreatitis caused a significant increase in wet lung weight compared to normal, and this could be abolished by heparin or aspirin pretreatment. 125 I-fibrinogen was deposited in the lungs of animals to a significantly greater degree than in controls (P less than 0.01). 125 I-fibrinogen deposition was reduced to control levels by pretreatment with aspirin or heparin (P less than 0.05). The uptake of radiolabeled platelets was greater in pancreatitis than in controls (P less than 0.001). Pancreatitis appears to be responsible for platelet entrapment in the lungs. Platelet uptake was reduced by heparin treatment but unaffected by aspirin therapy

Polymer deposition morphology by electrospray deposition - Modifications through distance variation

International Nuclear Information System (INIS)

Altmann, K.; Schulze, R.-D.; Friedrich, J.

2014-01-01

Electrospray deposition (ESD) of highly diluted polymers was examined with regard to the deposited surface structure. Only the flight distance (flight time) onto the resulting deposited surface was varied from 20 to 200 mm. An apparatus without any additional heating or gas flows was used. Polyacrylic acid (PAA) and polyallylamine (PAAm) in methanol were deposited on Si wafers. The polymer layers were characterized by scanning electron microscopy, X-ray photoelectron spectroscopy, derivatization reactions and Fourier transform infrared spectroscopy using a grazing incidence unit. SEM images illustrated the changing structures of PAA and PAAm. For PAA the deposited structure changed from a smooth film (20 mm) to a film with individual droplets on the coated surface (100 mm and 200 mm), while for PAAm individual droplets can be seen at all distances. The ESD process with cascades of splitting droplets slows down for PAA after distances greater than 40 mm. In contrast, the ESD process for PAAm is nearly stopped within the first flight distance of 20 mm. Residual solvent analysis showed that most of the solvent evaporated within the first 20 mm capillary-sample distance. - Highlights: • We deposited polyacrylic acid and polyallylamine by electrospray ionization (ESI). • The morphology in dependence of flight distance (20 mm to 200 mm) was analyzed. • The amount of residual solvent after deposition was determined. • ESI-process slows down for polyacrylic acid after 40 mm flight distance. • ESI-Process is complete for polyallylamine within the first 20 mm

Narrative depositional systems on the area with Nalinggou the relationship between uranium mineralization

International Nuclear Information System (INIS)

Meng Rui

2012-01-01

For sandstone-type uranium deposits in China began to research the late 1950s, 1990s in-situ leachable sand stone-type uranium deposits has become China's industrial significance of the important uranium deposits type. The sedimentary system analysis in in-situ leachable sandstone-type uranium deposit research plays a very important role. Based on the sedimentary system analysis and sequence stratigraphy as the basis, the area of Nalinggou on ridge middle Jurassic straight ROM group sedimentary system characteristics, middle Jurassic straight ROM group of sand body thickness, the area on ridge aspects of river channel exhibition cloth direction studied that: (1) river space distribution direction control the sand body cloth of the spatial distribution, then affects fu cloth of the spatial distribution of uranium sand body; (2) the evolution of the sedimentary environment created a good sand sequence distribution and enrichment conditions intercalation, be helpful for interlayer oxidation effect; (3) sequence of sedimentary control three layer structure lithology space combination. (authors)

Laser-assisted deposition of thin C60 films

DEFF Research Database (Denmark)

Schou, Jørgen; Canulescu, Stela; Fæster, Søren

Metal and metal oxide films with controlled thickness from a fraction of a monolayer up more than 1000 nm and known stoichiometry can be produced by pulsed laser deposition (PLD) relatively easily, and (PLD) is now a standard technique in all major research laboratories within materials science...... of the matrix material, anisole, with a concentration of 0.67 wt% C60. At laser fluences below 1.5 J/cm2, a dominant fraction of the film molecules are C60 transferred to the substrate without any fragmentation. High-resolution SEM images of MAPLE deposited films reveal large circular features on the surface...

Tempo of magma degassing and the genesis of porphyry copper deposits.

Science.gov (United States)

Chelle-Michou, Cyril; Rottier, Bertrand; Caricchi, Luca; Simpson, Guy

2017-01-12

Porphyry deposits are copper-rich orebodies formed by precipitation of metal sulphides from hydrothermal fluids released from magmatic intrusions that cooled at depth within the Earth's crust. Finding new porphyry deposits is essential because they are our largest source of copper and they also contain other strategic metals including gold and molybdenum. However, the discovery of giant porphyry deposits is hindered by a lack of understanding of the factors governing their size. Here, we use thermal modelling and statistical simulations to quantify the tempo and the chemistry of fluids released from cooling magmatic systems. We confirm that typical arc magmas produce fluids similar in composition to those that form porphyry deposits and conclude that the volume and duration of magmatic activity exert a first order control on the endowment (total mass of deposited copper) of economic porphyry copper deposits. Therefore, initial magma enrichment in copper and sulphur, although adding to the metallogenic potential, is not necessary to form a giant deposit. Our results link the respective durations of magmatic and hydrothermal activity from well-known large to supergiant deposits to their metal endowment. This novel approach can readily be implemented as an additional exploration tool that can help assess the economic potential of magmatic-hydrothermal systems.

Deposition Pattern of Inhaled Thoron Progeny Size Distribution in Human Lung

International Nuclear Information System (INIS)

Mohamed, A.

2005-01-01

One of the important factors controlling the distribution of radiation dose to the different portions of the human respiratory tract is the deposition pattern of thoron progeny containing aerosol. Based on the activity size distribution parameters of thoron progeny, which were measured in El-Minia University, the deposition behavior of thoron progeny (attached and unattached) has been studied by using a stochastic deposition model. The measurements were performed with a wire screen diffusion battery and a low pressure cascade impactor (type Berner). The bronchial deposition efficiencies of particles in the size range of attached thoron progeny were found to be lower than those of unattached progeny. The effect of thoron progeny deposition by adult male has been also studied for various levels of physical exertion. An increase in the breathing rate was found to decrease the efficiencies with which inhaled progeny were deposited in the bronchi. As the ventilation rate increases from 0.54 to 1.5 m3 h-1, the average deposition efficiencies of airway generation 1 through 8 are expected to decrease by 22 % for 1.4 nm particles and by 38 % for 150 nm particles

Visible-light active thin-film WO3 photocatalyst with controlled high-rate deposition by low-damage reactive-gas-flow sputtering

Directory of Open Access Journals (Sweden)

Nobuto Oka

2015-10-01

Full Text Available A process based on reactive gas flow sputtering (GFS for depositing visible-light active photocatalytic WO3 films at high deposition rates and with high film quality was successfully demonstrated. The deposition rate for this process was over 10 times higher than that achieved by the conventional sputtering process and the process was highly stable. Furthermore, Pt nanoparticle-loaded WO3 films deposited by the GFS process exhibited much higher photocatalytic activity than those deposited by conventional sputtering, where the photocatalytic activity was evaluated by the extent of decomposition of CH3CHO under visible light irradiation. The decomposition time for 60 ppm of CH3CHO was 7.5 times more rapid on the films deposited by the GFS process than on the films deposited by the conventional process. During GFS deposition, there are no high-energy particles bombarding the growing film surface, whereas the bombardment of the surface with high-energy particles is a key feature of conventional sputtering. Hence, the WO3 films deposited by GFS should be of higher quality, with fewer structural defects, which would lead to a decrease in the number of centers for electron-hole recombination and to the efficient use of photogenerated holes for the decomposition of CH3CHO.

Control of composition and crystallinity in hydroxyapatite films deposited by electron cyclotron resonance plasma sputtering

Science.gov (United States)

Akazawa, Housei; Ueno, Yuko

2014-01-01

Hydroxyapatite (HAp) films were deposited by electron cyclotron resonance plasma sputtering under a simultaneous flow of H2O vapor gas. Crystallization during sputter-deposition at elevated temperatures and solid-phase crystallization of amorphous films were compared in terms of film properties. When HAp films were deposited with Ar sputtering gas at temperatures above 460 °C, CaO byproducts precipitated with HAp crystallites. Using Xe instead of Ar resolved the compositional problem, yielding a single HAp phase. Preferentially c-axis-oriented HAp films were obtained at substrate temperatures between 460 and 500 °C and H2O pressures higher than 1×10-2 Pa. The absorption signal of the asymmetric stretching mode of the PO43- unit (ν3) in the Fourier-transform infrared absorption (FT-IR) spectra was the narrowest for films as-crystallized during deposition with Xe, but widest for solid-phase crystallized films. While the symmetric stretching mode of PO43- (ν1) is theoretically IR-inactive, this signal emerged in the FT-IR spectra of solid-phase crystallized films, but was absent for as-crystallized films, indicating superior crystallinity for the latter. The Raman scattering signal corresponding to ν1 PO43- sensitively reflected this crystallinity. The surface hardness of as-crystallized films evaluated by a pencil hardness test was higher than that of solid-phase crystallized films.

Comparison of braided-stream depositional environment and uranium deposits at Saint Anthony underground mine

International Nuclear Information System (INIS)

Baird, C.W.; Martin, K.W.; Lowry, R.M.

1980-01-01

United Nuclear's Saint Anthony mine, located in the Laguna district, produces uranium ore from the Jackpile sandstone unit of the Morrison Formation. The Jackpile sediments were deposited in a fluvial environment characterized by aridity, gentle slope, distant source area, and limited flow volume. Resultant stratigraphy consists of an intricate assemblage of trough and tabular cross-stratification grading to near massive bedding at some locations. Interbedded with the Jackpile sands are green mudstones and siltstones that commonly display irregular thicknesses of less than 2 ft and that are laterally discontinuous. Major penecontemporaneous and postdepositional alteration of originally deposited sands, silts, and clays includes: 1) infiltration and filling of interstices by kaolinitic clays; 2) mobilization and relocation of organic carbonaceous material; and 3) geochemical alteration of mineral constituents and fixation of uranium ions in organic carbonaceous material. Mineralized zones of economic volume display a spatial relationship to bedding features indicative of loosely packed sand deposited in dune and trough foresets. This relationship indicates possible permeability control by initial stratigraphy upon the flow of mineralizing solutions. Additionally, the low-energy foreset environment facilitates the accumulation of low-specific-gravity carbonaceous material necessary for interaction with mineralizing solutions. Large volumes of loosely packed foreset sands accumulate in transverse bars in braided-stream environments. These structures have a great potential for conducting large volumes of mineralizing fluids and hosting economic quantities of uranium ore

Patterned deposition by atmospheric pressure plasma-enhanced spatial atomic layer deposition

NARCIS (Netherlands)

Poodt, P.; Kniknie, B.J.; Branca, A.; Winands, G.J.J.; Roozeboom, F.

2011-01-01

An atmospheric pressure plasma enhanced atomic layer deposition reactor has been developed, to deposit Al2O3 films from trimethyl aluminum and an He/O2 plasma. This technique can be used for 2D patterned deposition in a single in-line process by making use of switched localized plasma sources. It

Coating material innovation in conjunction with optimized deposition technologies

International Nuclear Information System (INIS)

Stolze, M.; Leitner, K.

2009-01-01

Concentrating on physical vapour deposition methods several examples of recently developed coating materials for optical applications were studied for film deposition with optimized coating technologies: mixed evaporation materials for ion assisted deposition with modern plasma ion sources, planar metal and oxide sputter targets for Direct Current (DC) and Mid-Frequency (MF) pulsed sputter deposition and planar and rotatable sputter targets of transparent conductive oxides (TCO) for large-area sputter deposition. Films from specially designed titania based mixed evaporation materials deposited with new plasma ion sources and possible operation with pure oxygen showed extended ranges of the ratio between refractive index and structural film stress, hence there is an increased potential for the reduction of the total coating stress in High-Low alternating stacks and for coating plastics. DC and MF-pulsed sputtering of niobium metal and suboxide targets for optical coatings yielded essential benefits of the suboxide targets in a range of practical coating conditions (for absent in-situ post-oxidation ability): higher refractive index and deposition rate, better reproducibility and easier process control, and the potential for co-deposition of several targets. Technological progress in the manufacture of rotatable indium tin oxide (ITO) targets with regard to higher wall-thickness and density was shown to be reflected in higher material stock and coater up-time, economical deposition rates and stable process behaviour. Both for the rotatable ITO targets and higher-dense aluminum-doped zinc oxide (AZO) planar targets values of film transmittance and resistivity were in the range of the best values industrially achieved for films from the respective planar targets. The results for the rotatable ITO and planar AZO targets point to equally optimized process and film properties for the optimized rotatable AZO targets currently in testing

Complex mineralization at large ore deposits in the Russian Far East

Science.gov (United States)

Schneider, A. A.; Malyshev, Yu. F.; Goroshko, M. V.; Romanovsky, N. P.

2011-04-01

Genetic and mineralogical features of large deposits with complex Sn, W, and Mo mineralization in the Sikhote-Alin and Amur-Khingan metallogenic provinces are considered, as well as those of raremetal, rare earth, and uranium deposits in the Aldan-Stanovoi province. The spatiotemporal, geological, and mineralogical attributes of large deposits are set forth, and their geodynamic settings are determined. These attributes are exemplified in the large Tigriny Sn-W greisen-type deposit. The variation of regional tectonic settings and their spatial superposition are the main factor controlling formation of large deposits. Such a variation gives rise to multiple reactivation of the ore-magmatic system and long-term, multistage formation of deposits. Pulsatory mineralogical zoning with telescoped mineral assemblages related to different stages results in the formation of complex ores. The highest-grade zones of mass discharge of hydrothermal solutions are formed at the deposits. The promising greisen-type mineralization with complex Sn-W-Mo ore is suggested to be an additional source of tungsten and molybdenum. The Tigriny, Pravourminsky, and Arsen'evsky deposits, as well as deposits of the Komsomol'sk and Khingan-Olonoi ore districts are examples. Large and superlarge U, Ta, Nb, Be, and REE deposits are localized in the southeastern Aldan-Stanovoi Shield. The Ulkan and Arbarastakh ore districts attract special attention. The confirmed prospects of new large deposits with Sn, W, Mo, Ta, Nb, Be, REE, and U mineralization in the south of the Russian Far East assure expediency of further geological exploration in this territory.

Strike Point Control on EAST Using an Isoflux Control Method

International Nuclear Information System (INIS)

Xing Zhe; Xiao Bingjia; Luo Zhengping; Walker, M. L.; Humphreys, D. A.

2015-01-01

For the advanced tokamak, the particle deposition and thermal load on the divertor is a big challenge. By moving the strike points on divertor target plates, the position of particle deposition and thermal load can be shifted. We could adjust the Poloidal Field (PF) coil current to achieve the strike point position feedback control. Using isoflux control method, the strike point position can be controlled by controlling the X point position. On the basis of experimental data, we establish relational expressions between X point position and strike point position. Benchmark experiments are carried out to validate the correctness and robustness of the control methods. The strike point position is successfully controlled following our command in the EAST operation. (paper)

The conjunction of factors that lead to formation of giant gold provinces and deposits in non-arc settings

Directory of Open Access Journals (Sweden)

David I. Groves

2016-05-01

In contrast to their province scale similarities, the different giant gold deposit styles show contrasting critical controls at the district to deposit scale. For orogenic gold deposits, the giants appear to have formed by conjunction of a greater number of parameters to those that control smaller deposits, with resultant geometrical and lithostratigraphic complexity as a guide to their location. There are few giant IRGS due to their inferior fluid-flux systems relative to orogenic gold deposits, and those few giants are essentially preservational exceptions. Many Carlin-type deposits are giants due to the exceptional conjunction of both structural and lithological parameters that caused reactive and permeable rocks, enriched in syngenetic gold, to be located below an impermeable cap along antiformal “trends”. Hydrocarbons probably played an important role in concentrating metal. The supergiant Post-Betze deposit has additional ore zones in strain heterogeneities surrounding the pre-gold Goldstrike stock. All unequivocal IOCG deposits are giant or near-giant deposits in terms of gold-equivalent resources, partly due to economic factors for this relatively poorly understood, low Cu-Au grade deposit type. The supergiant Olympic Dam deposit, the most shallowly formed deposit among the larger IOCGs, probably owes its origin to eruption of volatile-rich hybrid magma at surface, with formation of a large maar and intense and widespread brecciation, alteration and Cu-Au-U deposition in a huge rock volume.

Deposition of plasmon gold–fluoropolymer nanocomposites

Energy Technology Data Exchange (ETDEWEB)

Safonov, Alexey I., E-mail: safonov@itp.nsc.ru [Kutateladze Institute of Thermophysics SB RAS, Lavrentyev Ave. 1, 630090, Novosibirsk (Russian Federation); Sulyaeva, Veronica S. [Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentyev Ave. 3, 630090, Novosibirsk (Russian Federation); Timoshenko, Nikolay I.; Kubrak, Konstantin V.; Starinskiy, Sergey V. [Kutateladze Institute of Thermophysics SB RAS, Lavrentyev Ave. 1, 630090, Novosibirsk (Russian Federation)

2016-12-01

Degradation-resistant two-dimensional metal–fluoropolymer composites consisting of gold nanoparticles coated with a thin fluoropolymer film were deposited on a substrate by hot wire chemical vapour deposition (HWCVD) and ion sputtering. The morphology and optical properties of the obtained coatings were determined. The thickness of the thin fluoropolymer film was found to influence the position of the surface plasmon resonance peak. Numerical calculations of the optical properties of the deposited materials were performed using Mie theory and the finite-difference time-domain (FDTD) method. The calculation results are consistent with the experimental data. The study shows that the position of the resonance peak can be controlled by changing the surface concentration of particles and the thickness of the fluoropolymer coating. The protective coating was found to prevent the plasmonic properties of the nanoparticles from changing for several months. - Highlights: • The gold–fluoropolymer composites are obtained by a combination of GJD and HWCVD. • The optical properties of composites were determined by experiments and calculation. • The dependence of SPR position on filling, NPs size and FP thickness were analyzed. • The plasmonic properties of the Au NPs are saved in the fluoropolymer matrix.

The genesis of surficial uranium deposits

International Nuclear Information System (INIS)

Boyle, D.R.

1984-01-01

Surficial uranium deposits can form in such diverse environments as calcareous-dolomitic-gypsiferous fluvial and aeolian valley sediments in hot arid and semi-arid regions, oxidizing and reducing alkaline and saline playas, highly organic and/or clay-rich wetland areas, calcareous regoliths in arid terranes, laterites, lake sediments, and highly fractured zones in igneous and metamorphic basement complexes. Formation of ore is governed by the interrelationships between source of ore-forming elements, mechanisms of migration, environment of deposition, climate, preservation, tectonic history and structural framework. The principal factors controlling mobilization of ore-forming elements from source to site of deposition are the availability of elements in source rocks, presence of complexing agents, climate, nature of source rock regolith and structure of source rock terrane. The major processes governing precipitation of uranium in the surficial environment are reduction mechanisms, sorption processes, dissociation of uranyl complexes, change in redox states of ore-forming constituents, evaporation of surface and groundwaters, change in partial pressure of dissolved carbon dioxide, changes in pH, colloidal precipitation, and mixing of two or more surface and groundwaters. One or a number of these processes may be actively involved in ore formation. (author)

Control of a metalorganic chemical vapor deposition process for improved composition and thickness precision in compound semiconductors

Science.gov (United States)

Gaffney, Monique Suzanne

1998-11-01

Metalorganic chemical vapor deposition (MOCVD) is a process used to manufacture electronic and optoelectronic devices that has traditionally lacked real-time growth monitoring and control. Controlling the growth rate and composition using the existing sensors, as well as advanced monitoring systems developed in-house, is shown to improve device quality. Specific MOCVD growth objectives are transformed into controller performance goals. Group III bubbler concentration variations, which perturb both growth rate and composition precision, are identified to be the primary disturbances. First a feed forward control system was investigated, which used an ultrasonic concentration monitor, located upstream in the process. This control strategy resulted in improved regulation of the gallium delivery rate by cancelling the sensed gallium bubbler concentration disturbances via the injection mass flow controller. The controller performance is investigated by growing GaInAs/InP superlattices. Results of growths performed under normal operating conditions and also under large perturbations include X-ray diffraction from the samples as well as real-time sensor signal data. High quality superlattices that display up to eight orders of satellite peaks are obtained under the feed forward compensation scheme, demonstrating improved layer-to-layer reproducibility of thickness and composition. The success of the feed forward control demonstration led to the development of a more complex downstream feedback control system. An ultraviolet absorption monitor was fabricated and retrofitted as a feedback control signal. A control-oriented model of the downstream process was developed for the feedback controller synthesis. Although challenged with both the photolysis and multi-gas detection issues common to UV absorption monitors, closed loop control with the UV sensor was performed and proved to be an effective method of disturbance rejection. An InP/GaInAs test structure was grown under

ITO thin films deposited by advanced pulsed laser deposition

International Nuclear Information System (INIS)

Viespe, Cristian; Nicolae, Ionut; Sima, Cornelia; Grigoriu, Constantin; Medianu, Rares

2007-01-01

Indium tin oxide thin films were deposited by computer assisted advanced PLD method in order to obtain transparent, conductive and homogeneous films on a large area. The films were deposited on glass substrates. We studied the influence of the temperature (room temperature (RT)-180 deg. C), pressure (1-6 x 10 -2 Torr), laser fluence (1-4 J/cm 2 ) and wavelength (266-355 nm) on the film properties. The deposition rate, roughness, film structure, optical transmission, electrical conductivity measurements were done. We deposited uniform ITO thin films (thickness 100-600 nm, roughness 5-10 nm) between RT and 180 deg. C on a large area (5 x 5 cm 2 ). The films have electrical resistivity of 8 x 10 -4 Ω cm at RT, 5 x 10 -4 Ω cm at 180 deg. C and an optical transmission in the visible range, around 89%

Atmospheric deposition of 137Cs between 1994 and 2002 at Cienfuegos, Cuba

International Nuclear Information System (INIS)

Alonso-Hernandez, C.M.; Cartas-Aguila, H.; Diaz-Asencio, M.; Munoz-Caravaca, A.; Martin-Perez, J.; Sibello-Hernandez, R.

2006-01-01

Levels of 137 Cs in total atmospheric deposition have been measured in the Cienfuegos region (Cuba) between 1994 and 2002. Samples were collected every three months, evaporated to dryness to obtain residual samples, and measured by gamma spectrometry. The 137 Cs mean concentration in total deposition was 0.24 Bq m -2 and data ranged between -2 . Precipitation rates and raintime have proved to be the most important factors controlling the concentration and depositional flux of 137 Cs in the atmosphere over Cienfuegos, showing a high correlation coefficient (R = 0.93)

The conjunction of factors that lead to formation of giant gold provinces and deposits in non-arc settings

Science.gov (United States)

Groves, David I.; Goldfarb, Richard J.; Santosh, M.

2016-01-01

It is quite evident that it is not anomalous metal transport, nor unique depositional conditions, nor any single factor at the deposit scale, that dictates whether a mineral deposit becomes a giant or not. A hierarchical approach thus is required to progressively examine controlling parameters at successively decreasing scales in the total mineral system to understand the location of giant gold deposits in non-arc environments. For giant orogenic, intrusion-related gold systems (IRGS) and Carlin-type gold deposits and iron oxide-copper-gold (IOCG) deposits, there are common factors among all of these at the lithospheric to crustal scale. All are sited in giant gold provinces controlled by complex fundamental fault or shear zones that follow craton margins or, in the case of most Phanerozoic orogenic giants, define the primary suture zones between tectonic terranes. Giant provinces of IRGS, IOCG, and Carlin-type deposits require melting of metasomatized lithosphere beneath craton margins with ascent of hybrid lamprophyric to granitic magmas and associated heat flux to generate the giant province. The IRGS and IOCG deposits require direct exsolution of volatile-rich magmatic-hydrothermal fluids, whereas the association of such melts with Carlin-type ores is more indirect and enigmatic. Giant orogenic gold provinces show no direct relationship to such magmatism, forming from metamorphic fluids, but show an indirect relationship to lamprophyres that reflect the mantle connectivity of controlling first-order structures.

Mars north polar deposits: stratigraphy, age, and geodynamical response.

Science.gov (United States)

Phillips, Roger J; Zuber, Maria T; Smrekar, Suzanne E; Mellon, Michael T; Head, James W; Tanaka, Kenneth L; Putzig, Nathaniel E; Milkovich, Sarah M; Campbell, Bruce A; Plaut, Jeffrey J; Safaeinili, Ali; Seu, Roberto; Biccari, Daniela; Carter, Lynn M; Picardi, Giovanni; Orosei, Roberto; Mohit, P Surdas; Heggy, Essam; Zurek, Richard W; Egan, Anthony F; Giacomoni, Emanuele; Russo, Federica; Cutigni, Marco; Pettinelli, Elena; Holt, John W; Leuschen, Carl J; Marinangeli, Lucia

2008-05-30

The Shallow Radar (SHARAD) on the Mars Reconnaissance Orbiter has imaged the internal stratigraphy of the north polar layered deposits of Mars. Radar reflections within the deposits reveal a laterally continuous deposition of layers, which typically consist of four packets of finely spaced reflectors separated by homogeneous interpacket regions of nearly pure ice. The packet/interpacket structure can be explained by approximately million-year periodicities in Mars' obliquity or orbital eccentricity. The observed approximately 100-meter maximum deflection of the underlying substrate in response to the ice load implies that the present-day thickness of an equilibrium elastic lithosphere is greater than 300 kilometers. Alternatively, the response to the load may be in a transient state controlled by mantle viscosity. Both scenarios probably require that Mars has a subchondritic abundance of heat-producing elements.

Microbial deposition of gold nanoparticles by the metal-reducing bacterium Shewanella algae

International Nuclear Information System (INIS)

Konishi, Y.; Tsukiyama, T.; Tachimi, T.; Saitoh, N.; Nomura, T.; Nagamine, S.

2007-01-01

Microbial reduction and deposition of gold nanoparticles was achieved at 25 deg. C over the pH range 2.0-7.0 using the mesophilic bacterium Shewanella algae in the presence of H 2 as the electron donor. The reductive deposition of gold by the resting cells of S. algae was a fast process: 1 mM AuCl 4 - ions were completely reduced to elemental gold within 30 min. At a solution pH of 7, gold nanoparticles 10-20 nm in size were deposited in the periplasmic space of S. algae cells. At pH 2.8, gold nanoparticles 15-200 nm in size were deposited on the bacterial cells, and the biogenic nanoparticles exhibited a variety of shapes that included nanotriangles: in particular, single crystalline gold nanotriangles 100-200 nm in size were microbially deposited. At a solution pH of 2.0, gold nanoparticles about 20 nm in size were deposited intracellularly, and larger gold particles approximately 350 nm in size were deposited extracellularly. The solution pH was an important factor in controlling the morphology of the biogenic gold particles and the location of gold deposition. Microbial deposition of gold nanoparticles is potentially attractive as an environmentally friendly alternative to conventional methods

Impurities in chromium deposits produced by electroplating and physical vapor deposition

Energy Technology Data Exchange (ETDEWEB)

Dini, J.W.

1994-05-01

Impurity contents in electrodeposited (hexavalent and trivalent) chromium deposits and physically vapor deposited (thermal evaporation, electron beam evaporation and rf-sputtering) were compared. Oxygen is the key impurity obtained in electrodeposited films but it can be minimized in hexavalent plating solutions by operating at high temperature, e. g., 85 C. Electrodeposits produced in trivalent chromium plating solutions and physically vapor deposited films have much higher oxygen contents than electrodeposits produced in hexavalent chromium solutions operated at temperatures around 85 C. Depending on the target material used for physically vapor deposited films, these films can also have high amounts of other impurities.

Evaluation of Wax Deposition and Its Control During Production of Alaska North Slope Oils

Energy Technology Data Exchange (ETDEWEB)

Tao Zhu; Jack A. Walker; J. Liang

2008-12-31

Due to increasing oil demand, oil companies are moving into arctic environments and deep-water areas for oil production. In these regions of lower temperatures, wax deposits begin to form when the temperature in the wellbore falls below wax appearance temperature (WAT). This condition leads to reduced production rates and larger pressure drops. Wax problems in production wells are very costly due to production down time for removal of wax. Therefore, it is necessary to develop a solution to wax deposition. In order to develop a solution to wax deposition, it is essential to characterize the crude oil and study phase behavior properties. The main objective of this project was to characterize Alaskan North Slope crude oil and study the phase behavior, which was further used to develop a dynamic wax deposition model. This report summarizes the results of the various experimental studies. The subtasks completed during this study include measurement of density, molecular weight, viscosity, pour point, wax appearance temperature, wax content, rate of wax deposition using cold finger, compositional characterization of crude oil and wax obtained from wax content, gas-oil ratio, and phase behavior experiments including constant composition expansion and differential liberation. Also, included in this report is the development of a thermodynamic model to predict wax precipitation. From the experimental study of wax appearance temperature, it was found that wax can start to precipitate at temperatures as high as 40.6 C. The WAT obtained from cross-polar microscopy and viscometry was compared, and it was discovered that WAT from viscometry is overestimated. From the pour point experiment it was found that crude oil can cease to flow at a temperature of 12 C. From the experimental results of wax content, it is evident that the wax content in Alaskan North Slope crude oil can be as high as 28.57%. The highest gas-oil ratio for a live oil sample was observed to be 619.26 SCF

Atomic layer deposition for high-efficiency crystalline silicon solar cells

NARCIS (Netherlands)

Macco, B.; van de Loo, B.W.H.; Kessels, W.M.M.; Bachmann, J.

2017-01-01

This chapter illustrates that Atomic Layer Deposition (ALD) is in fact an enabler of novel high-efficiency Si solar cells, owing to its merits such as a high material quality, precise thickness control, and the ability to prepare film stacks in a well-controlled way. It gives an overview of the

Lung deposition of sub-micron aerosols calculated as a function of age and breathing rate

International Nuclear Information System (INIS)

James, A.C.

1978-01-01

Experimental measurements of lung deposition and especially of regional deposition, of aerosols in the sub-micron size range have been so few that it is worthwhile establishing a method of calculation. A computer routine has therefore been developed to calculate aerosol deposition in successive bronchial and bronchiolar generations of the Weibel 'A' model of human lung for the sub-micron size range where deposition occurs solely by diffusion. This model can be scaled to represent lungs at various ages and vital capacities. Some calculated results are presented here and compared with measurements of lung deposition made under carefully controlled conditions in humans. (author)

Superhydrophobic polytetrafluoroethylene thin films with hierarchical roughness deposited using a single step vapor phase technique

International Nuclear Information System (INIS)

Gupta, Sushant; Arjunan, Arul Chakkaravarthi; Deshpande, Sameer; Seal, Sudipta; Singh, Deepika; Singh, Rajiv K.

2009-01-01

Superhydrophobic polytetrafluoroethylene films with hierarchical surface roughness were deposited using pulse electron deposition technique. We were able to modulate roughness of the deposited films by controlling the beam energy and hence the electron penetration depth. The films deposited at higher beam energy showed contact angle as high as 166 o . The scanning electron and atomic force microscope studies revealed clustered growth and two level sub-micron asperities on films deposited at higher energies. Such dual-scale hierarchical roughness and heterogeneities at the water-surface interface was attributed to the observed contact angle and thus its superhydrophobic nature.

Superhydrophobic polytetrafluoroethylene thin films with hierarchical roughness deposited using a single step vapor phase technique

Energy Technology Data Exchange (ETDEWEB)

Gupta, Sushant, E-mail: sushant3@ufl.ed [Department of Materials Science and Engineering, University of Florida, Gainesville, FL 32611 (United States); Arjunan, Arul Chakkaravarthi [Sinmat Incorporated, 2153 SE Hawthorne Road, 129, Gainesville, Florida 32641 (United States); Deshpande, Sameer; Seal, Sudipta [Advanced Material Processing and Analysis Center, University of Central Florida, Orlando, Florida 32816 (United States); Singh, Deepika [Sinmat Incorporated, 2153 SE Hawthorne Road, 129, Gainesville, Florida 32641 (United States); Singh, Rajiv K. [Department of Materials Science and Engineering, University of Florida, Gainesville, FL 32611 (United States)

2009-06-30

Superhydrophobic polytetrafluoroethylene films with hierarchical surface roughness were deposited using pulse electron deposition technique. We were able to modulate roughness of the deposited films by controlling the beam energy and hence the electron penetration depth. The films deposited at higher beam energy showed contact angle as high as 166{sup o}. The scanning electron and atomic force microscope studies revealed clustered growth and two level sub-micron asperities on films deposited at higher energies. Such dual-scale hierarchical roughness and heterogeneities at the water-surface interface was attributed to the observed contact angle and thus its superhydrophobic nature.

Oxygen Barrier Coating Deposited by Novel Plasma-enhanced Chemical Vapor Deposition

DEFF Research Database (Denmark)

Jiang, Juan; Benter, M.; Taboryski, Rafael Jozef

2010-01-01

We report the use of a novel plasma-enhanced chemical vapor deposition chamber with coaxial electrode geometry for the SiOx deposition. This novel plasma setup exploits the diffusion of electrons through the inner most electrode to the interior samples space as the major energy source. This confi......We report the use of a novel plasma-enhanced chemical vapor deposition chamber with coaxial electrode geometry for the SiOx deposition. This novel plasma setup exploits the diffusion of electrons through the inner most electrode to the interior samples space as the major energy source...... effect of single-layer coatings deposited under different reaction conditions was studied. The coating thickness and the carbon content in the coatings were found to be the critical parameters for the barrier property. The novel barrier coating was applied on different polymeric materials...

Deposition Measurements in NSTX

Science.gov (United States)

Skinner, C. H.; Kugel, H. W.; Hogan, J. T.; Wampler, W. R.

2004-11-01

Two quartz microbalances have been used to record deposition on the National Spherical Torus Experiment. The experimental configuration mimics a typical diagnostic window or mirror. An RS232 link was used to acquire the quartz crystal frequency and the deposited thickness was recorded continuously with 0.01 nm resolution. Nuclear Reaction Analysis of the deposit was consistent with the measurement of the total deposited mass from the change in crystal frequency. We will present measurements of the variation of deposition with plasma conditions. The transport of carbon impurities in NSTX has been modelled with the BBQ code. Preliminary calculations indicated a negligible fraction of carbon generated at the divertor plates in quiescent discharges directly reaches the outer wall, and that transient events are responsible for the deposition.

Shedding of ash deposits

DEFF Research Database (Denmark)

Zbogar, Ana; Frandsen, Flemming; Jensen, Peter Arendt

2009-01-01

Ash deposits formed during fuel thermal conversion and located on furnace walls and on convective pass tubes, may seriously inhibit the transfer of heat to the working fluid and hence reduce the overall process efficiency. Combustion of biomass causes formation of large quantities of troublesome...... ash deposits which contain significant concentrations of alkali, and earth-alkali metals. The specific composition of biomass deposits give different characteristics as compared to coal ash deposits, i.e. different physical significance of the deposition mechanisms, lower melting temperatures, etc....... Low melting temperatures make straw ashes especially troublesome, since their stickiness is higher at lower temperatures, compared to coal ashes. Increased stickiness will eventually lead to a higher collection efficiency of incoming ash particles, meaning that the deposit may grow even faster...

Urban wet deposition nitrate: a comparison to non-urban deposition

International Nuclear Information System (INIS)

Schultz, J.A.M.

1994-01-01

The concentration of nitrate in both wet and dry deposition has both increased historically and currently, and recently parallels emissions in NO x . Since NO x is produced in amounts comparable to SO 2 , it is an important contributor to acid deposition, and is produced in higher amounts in urban areas due to concentrated sources. Prior to to this study, national acid deposition monitoring networks in the United States have been and remain established in non-urban areas. This research study consisted of a comparison of precipitation sampling and analysis of wet deposition nitrate and pH for each deposition event in each of two urban sites over a 15 mo period. Also, a comparison of urban data and data generated at a nearby non-urban NADP site was made by examination of both monthly and seasonal data. This research suggests that national monitoring programs should consider inclusion of urban and non-urban monitoring sites in order to achieve a more representative regional assessment. 24 refs., 2 figs., 2 tabs

Acid deposition and water use efficiency in Appalachian forests

Science.gov (United States)

Malcomb, J.

2017-12-01

Multiple studies have reported increases in forest water use efficiency in recent decades, but the drivers of these trends remain uncertain. While acid deposition has profoundly altered the biogeochemistry of Appalachian forests in the past century, its impacts on forest water use efficiency have been largely overlooked. Plant ecophysiology literature suggests that plants up-regulate transpiration in response to soil nutrient limitation in order to maintain sufficient mass flow of nutrients. To test the impacts of acid deposition on forest eco-hydrology in central Appalachia, we integrated dendrochronological techniques, including tree ring δ13C analysis, with catchment water balance data from the Fernow Experimental Forest in West Virginia. Tree cores from four species were collected in Fernow Watershed 3, which has received experimental ammonium sulfate additions since 1989, and Watershed 7, an adjacent control catchment. Initial results suggest that acidification treatments have not significantly influenced tree productivity compared to a control watershed, but the effect varies by species, with tulip poplar showing greatest sensitivity to acidification. Climatic water balance, defined as the difference between growing season precipitation and evapotranspiration, is significantly related to annual tree ring growth, suggesting that climate may be driving tree growth trends in chronically acidified Appalachian forests. Tree ring 13C analysis from Fernow cores is underway and these data will be integrated with catchment hydrology data from five other sites in central Appalachia and the U.S. Northeast, representing a range of forest types, soil base saturations, and acid deposition histories. This work will advance understanding of how climate and acid deposition interact to influence forest productivity and water use efficiency, and improve our ability to model carbon and water cycling in forested ecosystems impacted by acid deposition.

Tectonic and climatic controls on continental depositional facies in the Karoo Basin of northern Natal, South Africa

Science.gov (United States)

Turner, Brian R.

1986-02-01

The eastern Karoo Basin, South Africa, contains a thick sequence of terrigenous clastic sediments comprising a meanderbelt facies, braided channel facies divided into coarse and fine subfacies, fluviolacustrine facies and aeolian facies. Depositional trends and changes in fluvial style reflect a progressive increase in aridity of the climate under stable tectonic conditions, interrupted by two phases of source area tectonism and the development of fine and coarse clastic wedges of the braided channel subfacies; the latter signifying a short interlude of cool, wet conditions. The fine braided channel subfacies occurs in the upper part of the meanderbelt facies, which was deposited by ephemeral, meandering mixed-load streams of variable discharge and sinuosity, under dry, semi-arid climatic conditions. These deposited complex, internally discordant channel sands and well-developed levee deposits. Following deposition of the coarse braided channel subfacies semi-arid conditions returned and fluvial deposition was dominated by ephemeral, straight to slightly sinuous mixed load streams characterised by simple channel sand bodies. As the aridity of the climate increased, the streams became more localised and carried an increasing proportion of fines. Interbedded with and overlying the fluvial deposits is a mudstone-dominated lacustrine sequence grading up into aeolian sands suggesting a playa lake-type situation. The general absence of evaporites from these sediments is attributed to the fresh nature of the lake waters, as evidenced by the freshwater aquatic organisms and clay-mineral suite, the lack of adequate inflow for solute accumulation and the removal of dust impregnated by salts from the surface of the dry lake bed during the dry season by superheated, upward-spiralling columns of air. Broadly similar environments to the fluvio-lacustrine and aeolian facies sequence are to be found in the Lake Eyre Basin of central Australia and the Okavango "delta" of northern

pH-controlled desorption of silver nanoparticles from monolayers deposited on PAH-covered mica

Energy Technology Data Exchange (ETDEWEB)

Oćwieja, Magdalena, E-mail: ncocwiej@cyf-kr.edu.pl; Adamczyk, Zbigniew, E-mail: ncadamcz@cyf-kr.edu.pl; Morga, Maria, E-mail: ncmorga@cyf-kr.edu.pl [Polish Academy of Sciences, Jerzy Haber Institute of Catalysis and Surface Chemistry (Poland)

2015-05-15

Although the release of silver nanoparticles from various surfaces and coatings plays an important role in many practical applications, the mechanisms of these processes are not fully understood. Therefore, in this work, the charge-stabilized silver particles of well-defined surface properties, with average sizes of 15, 28, and 54 nm, were used to quantitatively study this problem. The silver nanoparticles were obtained by the chemical reduction method using trisodium citrate as the stabilizing agent. Their size distributions and stabilities were determined using dynamic light scattering and transmission electron microscopy. The electrophoretic mobility and zeta potential of nanoparticles were determined for controlled ionic strength as a function of pH. The monolayers were produced on poly(allylamine hydrochloride)-modified mica under diffusion-controlled conditions. The coverage was determined by a direct enumeration of deposited nanoparticles using atomic force microscopy (AFM) and scanning electron microscopy (SEM). Using these well-defined monolayers, the kinetics of the release of nanoparticles was studied under controlled ionic strength and various pH values. The direct AFM and SEM measurements of the monolayer coverage, as a function of desorption time, allowed one to determine the kinetics of the release process. The equilibrium adsorption constant and the binding energy of particles were also determined using the random sequential adsorption model. The experimental results indicated that the release rate of particles is the fastest at lower pH values and for smaller particle sizes. This is confirmed by the binding energy values that at pH 3.5 varied between −15.9 and −18.1 kT for particles of the sizes 15 and 54 nm, respectively. These results were quantitatively interpreted in terms of the ion-pair concept where it was assumed that the binding energy between nanoparticles and the substrate was controlled by electrostatic interactions. Based on the

Surface modification of reverse osmosis desalination membranes by thin-film coatings deposited by initiated chemical vapor deposition

Energy Technology Data Exchange (ETDEWEB)

Ozaydin-Ince, Gozde, E-mail: gozdeince@sabanciuniv.edu [Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States); Matin, Asif, E-mail: amatin@mit.edu [Department of Mechanical Engineering, King Fahd University of Petroleum and Minerals, Dhahran 31261 (Saudi Arabia); Khan, Zafarullah, E-mail: zukhan@mit.edu [Department of Mechanical Engineering, King Fahd University of Petroleum and Minerals, Dhahran 31261 (Saudi Arabia); Zaidi, S.M. Javaid, E-mail: zaidismj@kfupm.edu.sa [Department of Mechanical Engineering, King Fahd University of Petroleum and Minerals, Dhahran 31261 (Saudi Arabia); Gleason, Karen K., E-mail: kkgleasn@mit.edu [Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States)

2013-07-31

Thin-film polymeric reverse osmosis membranes, due to their high permeation rates and good salt rejection capabilities, are widely used for seawater desalination. However, these membranes are prone to biofouling, which affects their performance and efficiency. In this work, we report a method to modify the membrane surface without damaging the active layer or significantly affecting the performance of the membrane. Amphiphilic copolymer films of hydrophilic hydroxyethylmethacrylate and hydrophobic perfluorodecylacrylate (PFA) were synthesized and deposited on commercial RO membranes using an initiated chemical vapor deposition technique which is a polymer deposition technique that involves free-radical polymerization initiated by gas-phase radicals. Relevant surface characteristics such as hydrophilicity and roughness could be systematically controlled by varying the polymer chemistry. Increasing the hydrophobic PFA content in the films leads to an increase in the surface roughness and hydrophobicity. Furthermore, the surface morphology studies performed using the atomic force microscopy show that as the thickness of the coating increases average surface roughness increases. Using this knowledge, the coating thickness and chemistry were optimized to achieve high permeate flux and to reduce cell attachment. Results of the static bacterial adhesion tests show that the attachment of bacterial cells is significantly reduced on the coated membranes. - Highlights: • Thin films are deposited on reverse osmosis membranes. • Amphiphilic thin films are resistant to protein attachment. • The permeation performance of the membranes is not affected by the coating. • The thin film coatings delayed the biofouling.

Field electron emission characteristics of chemical vapour deposition diamond films with controlled sp2 phase concentration

International Nuclear Information System (INIS)

Lu, X.; Yang, Q.; Xiao, C.; Hirose, A.

2008-01-01

Diamond films were synthesized in a microwave plasma-enhanced chemical vapour deposition reactor. The microstructure and surface morphology of deposited films were characterized by Raman spectroscope and scanning electron microscope. The sp 2 phase concentration in diamond films was varied and its effect on the field electron emission (FEE) properties was investigated. Diamond films deposited under higher methane concentration exhibit better FEE property including lower turn-on electric field and larger emission current. The predominating factor modifying the FEE property is presumed to be the increase of sp 2 phase concentration. The influence of bias voltage on the FEE property of diamond films is not monotonic. Postgrowth acid treatment reduces the sp 2 phase content in diamond films without changing diamond grain sizes. The corresponding FEE property was degraded

76 FR 41392 - Interest on Deposits; Deposit Insurance Coverage

Science.gov (United States)

2011-07-14

... banks' funding costs and also allow them to plan business growth more dependably and rigorously... of business deposits by offering continually higher rates of interest. Three of the four contended... deposits. They reasoned that large banks will offer high rates of interest and lure away business...

Atmospheric deposition 2000. NOVA 2003; Atmosfaerisk deposition 2000. NOVA 2003

Energy Technology Data Exchange (ETDEWEB)

Ellermann, T.; Hertel, O.; Hovmand, M.F.; Kemp, K.; Skjoeth, C.A.

2001-11-01

This report presents measurements and calculations from the atmospheric part of NOVA 2003 and covers results for 2000. It summarises the main results concerning concentrations and depositions of nitrogen, phosphorus and sulphur compounds related to eutrophication and acidification. Depositions of atmospheric compounds to Danish marine waters as well as land surface are presented. Measurements: In 2000 the monitoring program consisted of eight stations where wet deposition of ammonium, nitrate, phosphate (semi quantitatively) and sulphate were measured using bulk precipitation samplers. Six of the stations had in addition measurements of atmospheric content of A, nitrogen, phosphorus, and sulphur compounds in gas and particulate phase carried out by use of filter pack samplers. Filters were analysed at the National Environmental Research Institute. Furthermore nitrogen dioxide were measured using nitrogen dioxide filter samplers and monitors. Model calculations: The measurements in the monitoring program were supplemented with model calculations of concentrations and depositions of nitrogen and sulphur compounds to Danish land surface, marine waters, fjords and bays using the ACDEP model (Atmospheric Chemistry and Deposition). The model is a so-called trajectory model and simulates the physical and chemical processes in the atmosphere using meteorological and emission data as input. The advantage of combining measurements with model calculations is that the strengths of both methods is obtained. Conclusions concerning: 1) actual concentration levels at the monitoring stations, 2) deposition at the monitoring stations, 3) seasonal variations and 4) long term trends in concentrations and depositions are mainly based on the direct measurements. These are furthermore used to validate the results of the model calculations. Calculations and conclusions concerning: 1) depositions to land surface and to the individual marine water, 2) contributions from different emission

Phase-controlled preparation of TiO{sub 2} films and micro(nano)spheres by low-temperature chemical bath deposition

Energy Technology Data Exchange (ETDEWEB)

Wang, Mingsong, E-mail: wangms@mail.ujs.edu.cn [School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013 (China); Li, Qihui; Yu, Haiyan [School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013 (China); Hur, Seung Hyun [Department of Chemical Engineering, University of Ulsan, Ulsan 680-749 (Korea, Republic of); Kim, Eui Jung, E-mail: ejkim@ulsan.ac.kr [Department of Chemical Engineering, University of Ulsan, Ulsan 680-749 (Korea, Republic of)

2013-11-25

Highlights: •Simultaneously preparation of TiO{sub 2} films and sphere-like precipitates by low-temperature chemical bath deposition. •The same building blocks observed in the films and precipitates. •Cluster-by-cluster attachment is succeeded by the ion-by-ion growth. •Phase-controlled growth of TiO{sub 2} by the effects of solvent or fluorine ion. -- Abstract: TiO{sub 2} films and micro(nano)spheres have been simultaneously prepared by means of low-temperature chemical bath deposition (CBD). The films and precipitates are found to be constructed of the same building blocks regardless of the bath conditions. Thin nanosheets of ca. 20 nm in thickness serve as the building blocks of rutile TiO{sub 2} grown in an acidic bath. They aggregate to form spheres to reduce the surface energy of the precipitates, while in the films they grow into discrete crystallites on the seeded substrate. Fine control over the crystalline phase of TiO{sub 2} is achieved by replacing some water with ethanol or the addition of NH{sub 4}F. A gradual transition from rutile to anatase is observed as the ethanol and NH{sub 4}F contents are increased. Moreover, the crystallite size of TiO{sub 2} is significantly reduced and there exists monodisperse nanoparticles and aggregate microspheres in the products modified with ethanol and NH{sub 4}F, respectively. This size-dependent phase transition is consistent with previous theoretical and thermodynamic studies. The facile tune of the TiO{sub 2} phase by low-temperature CBD method may be useful to improve the performance of TiO{sub 2} for its various applications.

Atomic layer deposition of nanostructured materials

CERN Document Server

Pinna, Nicola

2012-01-01

Atomic layer deposition, formerly called atomic layer epitaxy, was developed in the 1970s to meet the needs of producing high-quality, large-area fl at displays with perfect structure and process controllability. Nowadays, creating nanomaterials and producing nanostructures with structural perfection is an important goal for many applications in nanotechnology. As ALD is one of the important techniques which offers good control over the surface structures created, it is more and more in the focus of scientists. The book is structured in such a way to fi t both the need of the expert reader (du

High nitrogen deposition in an agricultural ecosystem of Shaanxi, China.

Science.gov (United States)

Liang, Ting; Tong, Yan'an; Liu, Xuejun; Xu, Wen; Luo, Xiaosheng; Christie, Peter

2016-07-01

Atmospheric nitrogen (N) deposition plays an important role in the global N cycle. Data for dry and wet N deposition in agricultural ecosystem of Shaanxi in China is still imperfect; in this study, we continuously measured concentrations and fluxes of dry N deposition from 2010 to 2013 in Yangling district of Shaanxi province and wet N deposition from 2010 to 2012. The average annual concentrations of NH3, NO2, HNO3, particulate ammonium, and nitrate (pNH4 (+) and pNO3 (-)) varied among 3.9-9.1, 6.6-8.0, 1.2-1.4, 3.1-4.3, and 3.3-4.8 μg N m(-3), respectively, with mean values of 6.0, 7.2, 1.3, 3.8, and 4.1 μg N m(-3), respectively, during the entire monitoring period. The annual NH4 (+)-N and NO3 (-)-N concentrations in precipitation ranged 3.9-4.3 and 2.8-3.4 mg N L(-1) with the mean values of 4.1 and 3.3 mg N L(-1). The NH4 (+)-N/NO3 (-)-N ratio in rainfall averaged 1.2. Dry N deposition flux was determined to be 19.2 kg N ha(-1) year(-1) and the wet N deposition flux was 27.2 kg N ha(-1) year(-1). The amount of total atmospheric N deposition (dry plus wet) reached 46.4 kg N ha(-1) year(-1), in which dry deposition accounted 41 %. Gaseous N deposition comprised over 75 % of the dry deposition, and the proportion of oxidized N in dry deposition was equal to the reduced N. Therefore, the results suggest that more stringent regional air pollution control policies are required in the target area and that N deposition is an important nutrient resource from the atmosphere that must be taken into consideration in nutrient management planning of agricultural ecosystems.

Mechanical characteristics of a tool steel layer deposited by using direct energy deposition

Science.gov (United States)

Baek, Gyeong Yun; Shin, Gwang Yong; Lee, Eun Mi; Shim, Do Sik; Lee, Ki Yong; Yoon, Hi-Seak; Kim, Myoung Ho

2017-07-01

This study focuses on the mechanical characteristics of layered tool steel deposited using direct energy deposition (DED) technology. In the DED technique, a laser beam bonds injected metal powder and a thin layer of substrate via melting. In this study, AISI D2 substrate was hardfaced with AISI H13 and M2 metal powders for mechanical testing. The mechanical and metallurgical characteristics of each specimen were investigated via microstructure observation and hardness, wear, and impact tests. The obtained characteristics were compared with those of heat-treated tool steel. The microstructures of the H13- and M2-deposited specimens show fine cellular-dendrite solidification structures due to melting and subsequent rapid cooling. Moreover, the cellular grains of the deposited M2 layer were smaller than those of the H13 structure. The hardness and wear resistance were most improved in the M2-deposited specimen, yet the H13-deposited specimen had higher fracture toughness than the M2-deposited specimen and heat-treated D2.

Exogenous deposits

International Nuclear Information System (INIS)

Khasanov, A.Kh.

1988-01-01

Exogenous deposits forming as a result of complex exogenous processes, passed under the influence of outside forces on the Earth surface. To them relate physical and chemical weathering, decomposition and decay of mineral masses, redistribution and transportation of material, forming and deposit of new minerals and ores steady on the earth surface conditions

Two dimensional radial gas flows in atmospheric pressure plasma-enhanced chemical vapor deposition

Science.gov (United States)

Kim, Gwihyun; Park, Seran; Shin, Hyunsu; Song, Seungho; Oh, Hoon-Jung; Ko, Dae Hong; Choi, Jung-Il; Baik, Seung Jae

2017-12-01

Atmospheric pressure (AP) operation of plasma-enhanced chemical vapor deposition (PECVD) is one of promising concepts for high quality and low cost processing. Atmospheric plasma discharge requires narrow gap configuration, which causes an inherent feature of AP PECVD. Two dimensional radial gas flows in AP PECVD induces radial variation of mass-transport and that of substrate temperature. The opposite trend of these variations would be the key consideration in the development of uniform deposition process. Another inherent feature of AP PECVD is confined plasma discharge, from which volume power density concept is derived as a key parameter for the control of deposition rate. We investigated deposition rate as a function of volume power density, gas flux, source gas partial pressure, hydrogen partial pressure, plasma source frequency, and substrate temperature; and derived a design guideline of deposition tool and process development in terms of deposition rate and uniformity.

Surface-deposition and distribution of the radon-decay products indoors

International Nuclear Information System (INIS)

Espinosa, G.; Tommasino, L.

2015-01-01

The exposure to radon-decay products is of great concern both in dwellings and workplaces. The model to estimate the lung dose refers to the deposition mechanisms and particle sizes. Unfortunately, most of the dose data available are based on the measurement of radon concentration and the concentration of radon decay products. These combined measurements are widely used in spite of the fact that accurate dose assessments require information on the particle deposition mechanisms and the spatial distribution of radon decay products indoors. Most of the airborne particles and/or radon decay products are deposited onto indoor surfaces, which deposition makes the radon decay products unavailable for inhalation. These deposition processes, if properly known, could be successfully exploited to reduce the exposure to radon decay products. In spite of the importance of the surface deposition of the radon decay products, both for the correct evaluation of the dose and for reducing the exposure; little or no efforts have been made to investigate these deposition processes. Recently, two parallel investigations have been carried out in Rome and at Universidad Nacional Autónoma de México (UNAM) in Mexico City respectively, which address the issue of the surface-deposited radon decay products. Even though these investigations have been carried independently, they complement one another. It is with these considerations in mind that it was decided to report both investigations in the same paper. - Highlights: • Distribution of Radon and Thoron decay indoor products. • Indoor radon measurements complexity. • Short and long term measurements of surface deposit of Radon and Thoron decay products. • Microclimate controlled conditions room. • Nuclear Tracks Detectors

Deposition of nanocomposite Cu-TiO2 using heterogeneous colliding plasmas

Science.gov (United States)

Pandey, Pramod K.; Thareja, Raj K.; Singh, Ravi Pratap; Costello, John T.

2018-03-01

The formation of CuTiO2 nanocomposites has been observed in an experiment in which laser plasma plumes of Cu and Ti collide and stagnate in an oxygen atmosphere. The inherent advantage of this technique lies in its simplicity and flexibility where laser, target composition and geometry along with ambient atmosphere are all controllable parameters through which the stoichiometry of the deposited nanocomposites may be selected. The experiment has been performed at three oxygen ambient pressures 10-4, 10-2, 100 mbar and we observe its effect on stoichiometry, and morphology of the deposited nanocomposites. Here, we show how the stoichiometry of deposited nanocomposites can be readily controlled by changing just one parameter, namely the ambient oxygen pressure. The different peaks of photoluminescence spectra λ =390{ nm}( {E=3.18{ eV}} ) corresponding to the anatase phase of TiO2, along with the peaks at λ = 483 nm ( E = 2.56 eV) and 582 nm ( E = 2.13 eV) of deposited nanocomposites, shows the doping/blending effect on the band gaps which may potentially be of value in solar cell technology. The technique can, in principle, be extended to include nanocomposites of other materials making it potentially more widely applicable.

Sandstone uranium deposits of Eurasia – from genetic concepts to forecasting and new discoveries

International Nuclear Information System (INIS)

Pechenkin, I.

2014-01-01

Along the Eurasian continent’s southern borders lie uranium ore provinces and regions controlling medium-sized and, on rare occasions, large sandstone deposits. Central French, Eastern Rhodope and other regions are known in the west. Large uranium ore provinces were discovered in the south of the Turan Plate and in the depressions of South Kazakhstan, viz. Central Kyzyl Kum, Syr Darya, Chu Sarysu. A common criterion has been established for all objects of the sandstone type, located in oil and gas, coal etc. sedimentary basins – the zone of interlayer or ground-interlayer oxidation, controlling uranium mineralization. In 2003 we were able to justify the concept that the formation of giant deposits in Chu Sarysu province was caused by the collision between the Indian Plate and the southern part of the Eurasian continent. Within the limits of Pacific ore belt there is a zonal distribution of ore deposits. Ordinary mineralization is drawn towards its eastern fringe: gold, tin, copper, tungsten etc. Volcanic and tectonic structures of central type of Mesozoic age are located further west, from the north to the south, that is large calderas – Streltsovskaya (Russia), Dornot (Mongolia), Sian Shan (China), which control large and unique endogene uranium deposits. In the far west, in the region of subsiding tectonic tensions, there are sandstone deposits of uranium in Transbaikalia, Mongolia and Yunnan, which are specially connected to young basalts. Infiltration deposits of Vitim region are adjacent to endogene deposits of Streltsovsky region in the southern-easterly direction, and to the east of the deposits of Yunnan at the same latitude lay the Sian Shan caldera with geothermal deposits of uranium and other metals. We combined them into the unified submeridional Baikal-Southern China uranium ore belt. After examining the southern extremities of the Eurasian continent, the region of the collision of the Indian Plate, a distinct similarity can be perceived between

Nuclear imaging of amyloid deposits based upon thioflavins

International Nuclear Information System (INIS)

Wang Yanming; Wu Chunying; Wei Jinjun

2005-01-01

Alzheimer's Disease (AD) is a chronic neurodegenerative disorders characterized by the presence of amyloid deposits and neurofibrillar tangles in the brain. Direct assessment of local changes of amyloid deposits in vivo would greatly facilitate the diagnosis and therapeutic treatments of AD. The goal of this study is to develop small-molecule probes that can be used to follow amyloid deposition in vivo in patients with neurodegenerative diseases. Over the past years, we set out to develop a series of small molecules based on thioflavins as radiotracers for use in nuclear imaging modalities such as positron emission tomography and single photon emission computed tomography. The potential of these amyloid-imaging agents for in vivo studies of amyloid deposition has been evaluated based on the following methods: 1) spectrophotometric binding. assays with synthetic amyloid-β (Aβ) fibrils and AD brain homogenates; 2) fluorescent staining of brain tissue sections to evaluate specificity of binding to amyloid deposits; 3) fluorescent microscopy in mouse models to determine the brain permeability and characterize the binding specificity in vivo, and 4) PET studies in human subjects diagnosed with AD and age-matched control subjects. To date, we have identified some lead compounds as molecular probes with specificity towards amyloid deposits. The in vitro and in vivo binding properties of these compounds have been demonstrated in the following ways: 1) they selectively binds to Aβ fibrils; 2) they selectively stains amyloid deposits in AD brain tissue sections; 3) they readily penetrates the blood-brain barrier, selectively detects amyloid deposits in vivo iri living mice; and 4) One of these compounds, termed PIB, has been successfully used in PET studies in human subjects. In conclusion, amyloid-imaging probes have been developed that could be used to monitor amyloid load in vivo. Applications of the probes are under investigation for potential pathophysiology studies

Recent progress of atomic layer deposition on polymeric materials

Energy Technology Data Exchange (ETDEWEB)

Guo, Hong Chen; Ye, Enyi [Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, Innovis, #08-03, Singapore 138634 (Singapore); Li, Zibiao, E-mail: lizb@imre.a-star.edu.sg [Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, Innovis, #08-03, Singapore 138634 (Singapore); Han, Ming-Yong [Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, Innovis, #08-03, Singapore 138634 (Singapore); Loh, Xian Jun, E-mail: lohxj@imre.a-star.edu.sg [Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, Innovis, #08-03, Singapore 138634 (Singapore); Department of Materials Science and Engineering, National University of Singapore, Singapore 117574 (Singapore); Singapore Eye Research Institute, 20 College Road, Singapore 169856 (Singapore)

2017-01-01

As a very promising surface coating technology, atomic layer deposition (ALD) can be used to modify the surfaces of polymeric materials for improving their functions and expanding their application areas. Polymeric materials vary in surface functional groups (number and type), surface morphology and internal structure, and thus ALD deposition conditions that typically work on a normal solid surface, usually do not work on a polymeric material surface. To date, a large variety of research has been carried out to investigate ALD deposition on various polymeric materials. This paper aims to provide an in-depth review of ALD deposition on polymeric materials and its applications. Through this review, we will provide a better understanding of surface chemistry and reaction mechanism for controlled surface modification of polymeric materials by ALD. The integrated knowledge can aid in devising an improved way in the reaction between reactant precursors and polymer functional groups/polymer backbones, which will in turn open new opportunities in processing ALD materials for better inorganic/organic film integration and potential applications. - Highlights: • ALD deposition on different natural and synthetic polymer materials • Reaction mechanism based on the surface functional groups of polymers • Application of ALD-modified polymers in different fields.

Electro-Deposition Laboratory

Data.gov (United States)

Federal Laboratory Consortium — The electro-deposition laboratory can electro-deposit various coatings onto small test samples and bench level prototypes. This facility provides the foundation for...

Controls on the deposition and preservation of the Cretaceous Mowry Shale and Frontier Formation and equivalents, Rocky Mountain region, Colorado, Utah, and Wyoming

Science.gov (United States)

Kirschbaum, Mark A.; Mercier, Tracey J.

2013-01-01

Regional variations in thickness and facies of clastic sediments are controlled by geographic location within a foreland basin. Preservation of facies is dependent on the original accommodation space available during deposition and ultimately by tectonic modification of the foreland in its postthrusting stages. The preservation of facies within the foreland basin and during the modification stage affects the kinds of hydrocarbon reservoirs that are present. This is the case for the Cretaceous Mowry Shale and Frontier Formation and equivalent strata in the Rocky Mountain region of Colorado, Utah, and Wyoming. Biostratigraphically constrained isopach maps of three intervals within these formations provide a control on eustatic variations in sea level, which allow depositional patterns across dip and along strike to be interpreted in terms of relationship to thrust progression and depositional topography. The most highly subsiding parts of the Rocky Mountain foreland basin, near the fold and thrust belt to the west, typically contain a low number of coarse-grained sandstone channels but limited sandstone reservoirs. However, where subsidence is greater than sediment supply, the foredeep contains stacked deltaic sandstones, coal, and preserved transgressive marine shales in mainly conformable successions. The main exploration play in this area is currently coalbed gas, but the enhanced coal thickness combined with a Mowry marine shale source rock indicates that a low-permeability, basin-centered play may exist somewhere along strike in a deep part of the basin. In the slower subsiding parts of the foreland basin, marginal marine and fluvial sandstones are amalgamated and compartmentalized by unconformities, providing conditions for the development of stratigraphic and combination traps, especially in areas of repeated reactivation. Areas of medium accommodation in the most distal parts of the foreland contain isolated marginal marine shoreface and deltaic sandstones

Mechanical characteristics of ultra-long horizontal nanocantilevers grown by real-time feedback control on focused-ion-beam chemical vapour deposition

International Nuclear Information System (INIS)

Guo, Dengji; Warisawa, Shin’ichi; Ishihara, Sunao; Kometani, Reo

2015-01-01

Focused-ion-beam chemical vapour deposition (FIB-CVD) has been repeatedly proved to be a useful tool for the growth of three-dimensional (3D) micro- and nano-structures. The strategy of real-time feedback control on FIB-CVD was previously proposed and experimentally demonstrated to be effective for growing ultra-long horizontal nanocantilevers. To fabricate various nanoelectromechanical systems that consist of such types of nanocantilever structures, the mechanical characteristics of ultra-long horizontal nanocantilevers should be investigated. In this study, nanocantilevers with an overhang length of up to 35 μm were grown by using a 30 kV Ga + FIB, a beam current of 0.50 pA and phenanthrene (C 14 H 10 ) as the gas source to deposit a diamond-like carbon structure. The Young’s modulus of each nanocantilever was measured by bending the nanocantilever with a nanopillar whose Young’s modulus was known. The average density of each nanocantilever was calculated from the Young’s modulus and the measured resonant frequency. We found that the mechanical characteristics of each nanocantilever depended on the length of the nanocantilever if the strategy of real-time feedback control was applied in fabrication. The Young’s moduli and the averaged densities of the nanocantilevers with a length of 11 to 34 μm were found to be 86 to 254 GPa and 1950 to 5750 kg m −3 , respectively. With the increase of the overhang length, the Young’s modulus and the average density were found to gradually increase. (paper)

Electron-stimulated purification of platinum nanostructures grown via focused electron beam induced deposition

Directory of Open Access Journals (Sweden)

Brett B. Lewis

2015-04-01

Full Text Available Platinum–carbon nanostructures deposited via electron beam induced deposition from MeCpPt(IVMe3 are purified during a post-deposition electron exposure treatment in a localized oxygen ambient at room temperature. Time-dependent studies demonstrate that the process occurs from the top–down. Electron beam energy and current studies demonstrate that the process is controlled by a confluence of the electron energy loss and oxygen concentration. Furthermore, the experimental results are modeled as a 2nd order reaction which is dependent on both the electron energy loss density and the oxygen concentration. In addition to purification, the post-deposition electron stimulated oxygen purification process enhances the resolution of the EBID process due to the isotropic carbon removal from the as-deposited materials which produces high-fidelity shape retention.

Effects of heat treatment on the microstructure of amorphous boron carbide coating deposited on graphite substrates by chemical vapor deposition

International Nuclear Information System (INIS)

Li Siwei; Zeng Bin; Feng Zude; Liu Yongsheng; Yang Wenbin; Cheng Laifei; Zhang Litong

2010-01-01

A two-layer boron carbide coating is deposited on a graphite substrate by chemical vapor deposition from a CH 4 /BCl 3 /H 2 precursor mixture at a low temperature of 950 o C and a reduced pressure of 10 KPa. Coated substrates are annealed at 1600 o C, 1700 o C, 1800 o C, 1900 o C and 2000 o C in high purity argon for 2 h, respectively. Structural evolution of the coatings is explored by electron microscopy and spectroscopy. Results demonstrate that the as-deposited coating is composed of pyrolytic carbon and amorphous boron carbide. A composition gradient of B and C is induced in each deposition. After annealing, B 4 C crystallites precipitate out of the amorphous boron carbide and grow to several hundreds nanometers by receiving B and C from boron-doped pyrolytic carbon. Energy-dispersive spectroscopy proves that the crystallization is controlled by element diffusion activated by high temperature annealing, after that a larger concentration gradient of B and C is induced in the coating. Quantified Raman spectrum identifies a graphitization enhancement of pyrolytic carbon. Transmission electron microscopy exhibits an epitaxial growth of B 4 C at layer/layer interface of the annealed coatings. Mechanism concerning the structural evolution on the basis of the experimental results is proposed.

Facile synthesis of graphene on single mode fiber via chemical vapor deposition

International Nuclear Information System (INIS)

Zhang, C.; Man, B.Y.; Jiang, S.Z.; Yang, C.; Liu, M.; Chen, C.S.; Xu, S.C.; Feng, D.J.; Bi, D.; Liu, F.Y.; Qiu, H.W.

2014-01-01

Direct deposition of graphene film on the standard single mode fiber is offered using a Cu-vapor-assisted chemical vapor deposition system. The gas flow of H 2 and Ar before the growth process plays a crucial role for the direct deposition of the graphene film and the layers of the graphene can be controlled by the growth time. With a large gas flow, Cu atoms are carried off with the gas flow and hard to deposit on the surface of the single mode fiber before the growth process. Consequently, uniform graphene film is obtained in this case. On the contrary, with a lower one, Cu atoms is facile to deposit on the surface of the single mode fiber and form nanodots acting as active catalytic sites for the growth of carbon nanotubes. This method presents us a promising transfer-free technique for fabrication of the photonic applications.

Mississippian depositional history of the Texas Panhandle: A reappraisal

International Nuclear Information System (INIS)

Ruppel, S.C.

1988-01-01

Recent lithostratigraphic and biostratigraphic study of subsurface Mississippian rocks of the Texas Panhandle indicates that previous interpretations of the sequence and timing of depositional events in the area need revision. Early Mississippian (Kinderhookian to Osagean) deposition in the area was restricted to the northeastern Panhandle (Anadarko Basin). The Texas Arch, a Devonian structure, remained positive and effectively limited sediment accumulation throughout the remainder of the area at this time. Major inundation of the southern Panhandle did not occur until the Meramecian. At that time shallow platform conditions developed in the area of the submerged Texas Arch; carbonate buildups formed locally on the outer ramp along the previous margin of the Arch. This marine transgression correlates with drowning of platform margins throughout the midcontinent region. The Texas Arch continued intermittently to control deposition until the end of the Mississippian Period. 20 refs., 2 figs

Chemical bath deposited PbS thin films on ZnO nanowires for photovoltaic applications

Energy Technology Data Exchange (ETDEWEB)

Gertman, Ronen [Dept of Chemistry, Ben Gurion University of the Negev, Be' er Sheva 84105 (Israel); Ilse Katz Institute for Nanoscale Science and Technology, Ben Gurion University of the Negev, Be' er Sheva 84105 (Israel); Osherov, Anna; Golan, Yuval [Dept of Materials Engineering, Ben Gurion University of the Negev, Be' er Sheva 84105 (Israel); Ilse Katz Institute for Nanoscale Science and Technology, Ben Gurion University of the Negev, Be' er Sheva 84105 (Israel); Visoly-Fisher, Iris, E-mail: irisvf@bgu.ac.il [Ilse Katz Institute for Nanoscale Science and Technology, Ben Gurion University of the Negev, Be' er Sheva 84105 (Israel); Department of Solar Energy and Environmental Physics, Swiss Institute for Dryland Environmental and Energy Research, Jacob Blaustein Institutes for Desert Research, Ben Gurion University of the Negev, Sede Boqer Campus 84990 (Israel)

2014-01-01

Photovoltaic devices usually exploit mid-range band-gap semiconductors which absorb in the visible range of the solar spectrum. However, much energy is lost in the IR and near-IR range. We combined the advantages of small band-gap, bulk-like PbS deposited by facile, cheap and direct chemical bath deposition (CBD), with the good electronic properties of ZnO and the large surface area of nanowires, towards low cost photovoltaic devices utilizing IR and near-IR light. Surprisingly, CBD of PbS on ZnO, and particularly on ZnO nanowires, was not studied hitherto. Therefore, the mechanism of PbS growth by chemical bath deposition on ZnO nanowires was studied in details. A visible proof is shown for a growth mechanism starting from amorphous Pb(OH){sub 2} layer, that evolved into the ‘ion-by-ion’ growth mechanism. The growth mechanism and the resulting morphology at low temperatures were controlled by the thiourea concentration. The grain size affected the magnitude of the band-gap and was controlled by the deposition temperatures. Deposition above 40 °C resulted in bulk-like PbS with an optical band-gap of 0.4 eV. Methods were demonstrated for achieving complete PbS coverage of the complex ZnO NW architecture, a crucial requirement in optoelectronic devices to prevent shorts. Measurements of photocurrents under white and near-IR (784 nm) illumination showed that despite a 200 meV barrier for electron transfer at the PbS/ZnO interface, extraction of photo-electrons from PbS to the ZnO was feasible. The ability to harvest electrons from a narrow band-gap semiconductor deposited on a large surface-area electrode can advance the field towards high efficiency, low cost IR and near-IR sensors and third generation solar cells. - Highlights: • PbS was deposited on ZnO nanowires using chemical bath deposition. • At 50 °C the growth mechanism starts from an amorphous Pb(OH){sub 2} layer. • At 5 °C the growth mechanism of PbS can be controlled by thiourea concentrations

Rare Earth Elements (REE Deposits Associated with Great Plain Margin Deposits (Alkaline-Related, Southwestern United States and Eastern Mexico

Directory of Open Access Journals (Sweden)

Virginia T. McLemore

2018-01-01

alkaline-igneous rocks, and associated mineral deposits along this boundary suggests that this region is characterized by highly fractionated and differentiated, multiple pulses of mantle-derived magmas evolving to lower crustal magmas related to the subduction of the Farallon plate. The differences in incompatible trace elements, including REE and beryllium, between the different granitic to rhyolite rocks are likely related to either differences in the crustal rocks that were assimilated during magmatic differentiation or by potential minor contamination from crustal sources and/or magma mixing. Deep-seated fracture systems or crustal lineaments apparently channeled the magmas and hydrothermal fluids. Once magmas and metal-rich fluids reached shallow levels, the distribution and style of these intrusions, as well as the resulting associated mineral deposits were controlled by local structures and associated igneous rock compositions.

Growth characteristics of inclined columns produced by Glancing Angle Deposition (GLAD) and colloidal lithography

DEFF Research Database (Denmark)

Foss, Morten; Besenbacher, Flemming; Sutherland, Duncan S

2011-01-01

Nanocolumns were produced by performing Glancing Angle Deposition (GLAD) onto self-assembled template arrays consisting of platinum coated polystyrene spheres. By varying the angle of incidence (θ = 35°, 10° and 5°) and the deposited surface mass density it was possible to control the shape of th...

Controls of tectonics and sediment source locations on along-strike variations in transgressive deposits on the northern California margin

Science.gov (United States)

Spinelli, G.A.; Field, M.E.

2003-01-01

We identify two surfaces in the shallow subsurface on the Eel River margin offshore northern California, a lowstand erosion surface, likely formed during the last glacial maximum, and an overlying surface likely formed during the most recent transgression of the shoreline. The lowstand erosion surface, which extends from the inner shelf to near the shelfbreak and from the Eel River to Trinidad Head (???80 km), truncates underlying strata on the shelf. Above the surface, inferred transgressive coastal and estuarine sedimentary units separate it from the transgressive surface on the shelf. Early in the transgression, Eel River sediment was likely both transported down the Eel Canyon and dispersed on the slope, allowing transgressive coastal sediment from the smaller Mad River to accumulate in a recognizable deposit on the shelf. The location of coastal Mad River sediment accumulation was controlled by the location of the paleo-Mad River. Throughout the remainder of the transgression, dispersed sediment from the Eel River accumulated an average of 20 m of onlapping shelf deposits. The distribution and thickness of these transgressive marine units was strongly modified by northwest-southeast trending folds. Thick sediment packages accumulated over structural lows in the lowstand surface. The thinnest sediment accumulations (0-10 m) were deposited over structural highs along faults and uplifting anticlines. The Eel margin, an active margin with steep, high sediment-load streams, has developed a thick transgressive systems tract. On this margin sediment accumulates as rapidly as the processes of uplift and downwarp locally create and destroy accommodation space. Sequence stratigraphic models of tectonically active margins should account for variations in accommodation space along margins as well as across them. ?? 2003 Elsevier Science B.V. All rights reserved.

Electrochemical Sensor Coating Based on Electrophoretic Deposition of Au-Doped Self-Assembled Nanoparticles.

Science.gov (United States)

Zhang, Rongli; Zhu, Ye; Huang, Jing; Xu, Sheng; Luo, Jing; Liu, Xiaoya

2018-02-14

The electrophoretic deposition (EPD) of self-assembled nanoparticles (NPs) on the surface of an electrode is a new strategy for preparing sensor coating. By simply changing the deposition conditions, the electrochemical response for an analyte of deposited NPs-based coating can be controlled. This advantage can decrease the difference between different batches of sensor coating and ensure the reproducibility of each sensor. This work investigated the effects of deposition conditions (including deposition voltage, pH value of suspension, and deposition time) on the structure and the electrochemical response for l-tryptophan of sensor coating formed from Au-doped poly(sodium γ-glutamate) with pendant dopamine units nanohybrids (Au/γ-PGA-DA NBs) via the EPD method. The structure and thickness of the deposited sensor coating were measured by atomic force microscopy, which demonstrated that the structure and thickness of coating can be affected by the deposition voltage, the pH value of the suspension, and the deposition time. The responsive current for l-tryptophan of the deposited sensor coating were measured by differential pulse voltammetry, which showed that the responsive current value was affected by the structure and thickness of the deposited coating. These arguments suggested that a rich design-space for tuning the electrochemical response for analyte and a source of variability in the structure of sensor coating can be provided by the deposition conditions. When Au/γ-PGA-DA NBs were deposited on the electrode surface and formed a continuous coating with particle morphology and thinner thickness, the deposited sensor coating exhibited optimal electrochemical response for l-tryptophan.

Conceptual design of a remote system for characterizing oilsands tailings deposits

Energy Technology Data Exchange (ETDEWEB)

Lipsett, M.G.; Rivard, B. [Alberta Univ., Edmonton, AB (Canada). Dept. of Mechanical Engineering; Alberta Univ., Edmonton, AB (Canada). Dept. of Earth and Atmospheric Sciences

2010-07-01

This PowerPoint presentation described the design of a remote system for characterizing oil sands tailings deposits. The wheeled mobile robot technology was developed in order to improve the trafficability of composite tailings (CT) and other engineering tailings deposits, as well as to identify differences in feedstocks and process performance, and to determine shear strength losses from dynamic loading. The technology was comprised of a spectroscopy component, and a mobile robot equipped with surface measurement sensors. The control system included navigation and traction control devices. A communication component was also included. Tools used in the system included a penetrometer, a viscosimeter, and an automatic sample collection device. Tests have been conducted to determine the system's driving ability. Further tests are being conducted to evaluate the performance of the robot sensors and controllers. tabs., figs.

Uranium metallogenic features and prospecting potentialities in the areas around Shabazi uranium deposit in Nanling metallogenic belt

International Nuclear Information System (INIS)

Yang Shanghai

2008-01-01

Based on the actuality of exploration and research on Shabazi uranium deposit in Nanling metallogenic belt, the author analyzes and summarizes uranium metallogenic features of the deposit. Under the direction of modern metallogenic theories of uranium deposit, such as deep-source mineralization and deep prospecting for uranium deposits, it is shown that there is great mineralization and prospecting potentiality in the areas around Shabazi uranium deposit and high attention importance should be paid to the areas in the future exploration according to the synthetical analysis on geologic background of the deposit, uranium mineralization features, ore-controlling factors and systematic data of geology. (authors)

Use of structural geology in exploration for and mining of sedimentary rock-hosted Au deposits

Science.gov (United States)

Peters, Stephen G.

2001-01-01

Structural geology is an important component in regional-, district- and orebody-scale exploration and development of sedimentary rock-hosted Au deposits.Identification of timing of important structural events in an ore district allows analysis and classification of fluid conduits and construction of genetic models for ore formation.The most practical uses of structural geology deal with measurement and definition of various elements that comprise orebodies, which can then be directly applied to ore-reserve estimation,ground control,grade control, safety issues,and mine planning.District- and regional-scale structural studies are directly applicable to long-term strategic planning,economic analysis,and land ownership. Orebodies in sedimentary rock-hosted Au deposits are discrete, hypogene, epigenetic masses usually hosted in a fault zone,breccia mass, or lithologic bed or unit. These attributes allow structural geology to be directly applied to the mining and exploration of sedimentary rock-hosted Au deposits. Internal constituents in orebodies reflect unique episodes relating to ore formation.The main internal constituents in orebodies are ore minerals, gangue, and alteration minerals that usually are mixed with one another in complex patterns, the relations among which may be used to interpret the processes of orebody formation and control.Controls of orebody location and shape usually are due to structural dilatant zones caused by changes in attitude, splays, lithologic contacts,and intersections of the host conduit or unit.In addition,conceptual parameters such as district fabric,predictable distances, and stacking also are used to understand the geometry of orebodies.Controls in ore districts and location and geometry of orebodies in ore districts can be predicted to various degrees by using a number of qualitative concepts such as internal and external orebody plunges,district plunge, district stacking, conduit classification, geochemical, geobarometric and

Athabasca basin unconformity-type uranium deposits. A special class of sandstone-type deposits

International Nuclear Information System (INIS)

Hoeve, J.

1980-01-01

Two major episodes of uranium metallogenesis are recognized in Northern Saskatchewan. The first is of late-Hudsonian age and gave rise to metamorphic-hydrothermal pitchblende deposits of simple mineralogy at Beaverlodge (primary mineralization: 1780+-20 m.y.). The second and more important episode of approximately Grenvillian age rendered unconformity-type deposits in the Athabasca Basin (primary mineralization: 1000-1300 m.y.). The late-Hudsonian deposits at Beaverlodge were overprinted by this second event and new deposits of complex mineralogy were formed in that area. The metallogenetic importance of a third and much later episode which gave rise to mineralization within the Athabasca Formation is uncertain at the moment. With regards to metallogenesis of the unconformity-type deposits, presently available evidence favours a diagenetic-hydrothermal rather than a near-surface supergene or a magmatic/metamorphic hydrothermal model. The diagenetic-hydrothermal model relates uranium mineralization to 'red bed-type' diagenetic processes in the Athabasca Formation involving post-depositional oxidation and leaching, which continued for several hundred million years after deposition. Ore deposits were formed by interaction, under conditions of deep burial at elevated temperatures and pressures, of a uraniferous oxidizing Athabasca aquifer with reducing, graphite-bearing, metamorphic rocks of the basin floor. The large-scale convection required for such interaction may have been induced by mafic magmatic activity coeval with the episode of mineralization. The diagenetic-hydrothermal model displays close similarities with metallogenetic models developed for certain sandstone-type deposits. (author)

World Distribution of Uranium Deposits (UDEPO) with uranium deposit classification. 2009 ed

International Nuclear Information System (INIS)

2009-10-01

The World Distribution of Uranium Deposits (UDEPO) database provides general, technical and geological information, including references, about the worldwide uranium deposits. UDEPO has been published on the internet which allows the users to register freely and to work with datasets (http://www-nfcis.iaea.org). The UDEPO web site is designed to allow users to retrieve data sets on a variety of deposit related topics ranging from specific information on individual uranium deposits to statistical information on uranium deposits worldwide. The basic building blocks for the UDEPO database are the more than 900 individual deposits for which information is available in the database. The database is arranged in a relational database format which has one main table and a number of associated tables. Structured nature of the database allows filtering and querying the database in more systematic way. The web site provides filtering and navigation to the data from the database. It has also a statistical tool which provides summary information on number of deposits and uranium resources by type and status, and by country and status. In this respect and with regard to the data presented, the UDEPO database is a unique database which provides freely accessible information on worldwide uranium deposits. Although a great effort is spent to have complete and accurate database, the users should take into consideration that there still might be missing or outdated data for individual deposits due to the rapid changes in the uranium industry due to the new exploration works which are ongoing everyday. This document and its supplementary CD-ROM represent a snapshot of the status of the database as of the end of 2008. However, the database is being continuously updated and the latest updates and additions can be accessed from the database web site (http://wwwnfcis.iaea.org)

Geological factors of deposit formation

International Nuclear Information System (INIS)

Grushevoj, G.V.

1980-01-01

Geologic factors of hydrogenic uranium deposit formation are considered. Structural, formation and lithological-facies factors of deposit formation, connected with zones of stratal oxidation, are characterized. Peculiarities of deposit localization, connected with orogenic structures of Mesozoic and lenozoic age, are described. It is noted that deposits of anagenous group are widely spread in Paleozoic formations, infiltration uranium deposits are localized mainly in Cenozoic sediments, while uranium mineralization both anagenous and infiltration groups are widely developed in Mesozoic sediments. Anagenous deposits were formed in non-oxygen situation, their age varies from 200 to 55 mln years. Infiltration deposit formation is determined by asymmetric oxidation zonation, their age varies from 10 - 40 mln years to dozens of thousand years [ru

Deposition of highly (111)-oriented PZT thin films by using metal organic chemical deposition

CERN Document Server

Bu, K H; Choi, D K; Seong, W K; Kim, J D

1999-01-01

Lead zirconate titanate (PZT) thin films have been grown on Pt/Ta/SiNx/Si substrates by using metal organic chemical vapor deposition with Pb(C sub 2 H sub 5) sub 4 , Zr(O-t-C sub 4 H sub 9) sub 4 , and Ti(O-i-C sub 3 H sub 7) sub 4 as source materials and O sub 2 as an oxidizing gas. The Zr fraction in the thin films was controlled by varying the flow rate of the Zr source material. The crystal structure and the electrical properties were investigated as functions of the composition. X-ray diffraction analysis showed that at a certain range of Zr fraction, highly (111)-oriented PZT thin films with no pyrochlore phases were deposited. On the other hand, at low Zr fractions, there were peaks from Pb-oxide phases. At high Zr fractions, peaks from pyrochlore phase were seen. The films also showed good electrical properties, such as a high dielectric constant of more than 1200 and a low coercive voltage of 1.35 V.

Deposit3D: a tool for automating structure depositions to the Protein Data Bank

Energy Technology Data Exchange (ETDEWEB)

Badger, J., E-mail: jbadger@active-sight.com; Hendle, J.; Burley, S. K.; Kissinger, C. R. [SGX Inc., 10505 Roselle Street, San Diego, CA 92121 (United States)

2005-09-01

This paper describes a Python script that may be used to gather all required structure-annotation information into an mmCIF file for upload through the RCSB PDB ADIT structure-deposition interface. Almost all successful protein structure-determination projects in the public sector culminate in a structure deposition to the Protein Data Bank (PDB). In order to expedite the deposition proces, Deposit3D has been developed. This command-line script calculates or gathers all the required structure-deposition information and outputs this data into a mmCIF file for subsequent upload through the RCSB PDB ADIT interface. Deposit3D might be particularly useful for structural genomics pipeline projects because it allows workers involved with various stages of a structure-determination project to pool their different categories of annotation information before starting a deposition session.