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Sample records for cubta chemisorbed structure

  1. Infrared spectroscopy of physisorbed and chemisorbed N-2 in the Pt(111)(3x3)N-2 structure

    DEFF Research Database (Denmark)

    Gustafsson, K.; Karlberg, Gustav; Andersson, Sven

    2007-01-01

    Using infrared spectroscopy and low electron energy diffraction, we have investigated the adsorption of N-2, at 30 K, on the Pt(111) and the Pt(111)(1x1)H surfaces. At monolayer coverage, N-2 orders in commensurate (3x3) structures on both surfaces, and we propose that the unit cells contain four...... molecules in each case. The infrared spectra reveal that N-2 exclusively physisorbs on the Pt(111)(1x1)H surface, while both physisorbed and chemisorbed N-2 is detected on the Pt(111) surface. Physisorbed N-2 is the majority species in the latter case, and the two adsorption states show an almost identical...... uptake behavior, which indicates that they are intrinsic constituents of the growing (3x3) N-2 islands. An analysis of the infrared absorbance data, based on a simple scaling concept suggested by density functional theory calculations, supports a model in which the (3x3) unit cell contains one...

  2. Two-photon photoemission study of the coverage-dependent electronic structure of chemisorbed alkali atoms on a Ag(111) surface.

    Science.gov (United States)

    Wang, Lei-Ming; Sametoglu, Vahit; Winkelmann, Aimo; Zhao, Jin; Petek, Hrvoje

    2011-09-01

    We report a systematic investigation of the electronic structure of chemisorbed alkali atoms (Li-Cs) on a Ag(111) surface by two-photon photoemission spectroscopy. Angle-resolved two-photon photoemission spectra are obtained for 0-0.1 monolayer coverage of alkali atoms. The interfacial electronic structure as a function of periodic properties and the coverage of alkali atoms is observed and interpreted assuming ionic adsorbate/substrate interaction. The energy of the alkali atom σ-resonance at the limit of zero coverage is primarily determined by the image charge interaction, whereas at finite alkali atom coverages, it follows the formation of a dipolar surface field. The coverage- and angle-dependent two-photon photoemission spectra provide information on the photoinduced charge-transfer excitation of adsorbates on metal surfaces. This work complements the previous work on alkali/Cu(111) chemisorption [Phys. Rev. B 2008, 78, 085419].

  3. In situ polyphenyl derivatisation and the effect of thermal decomposition of adsorbed and chemisorbed polyphenyls on the structure of multi-wall carbon nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Gergely, Andras, E-mail: doohan11@chemres.hu [Department of Surface Modification and Nanostructures, Institute of Nanochemistry and Catalysis, Chemical Research Center of the Hungarian Academy of Sciences, Pusztaszeri ut 59-67, Budapest 1025 (Hungary); Ujszaszy, Kalman [Mass Spectrometry Department, Institute of Structural Chemistry, Pusztaszeri ut 59-67, Chemical Research Center of the Hungarian Academy of Sciences, Budapest 1025 (Hungary); Peltz, Csaba [EGIS Pharmaceuticals PLC, Kereszturi ut 30-38, Budapest 1106 (Hungary); Kiraly, Peter; Tarkanyi, Gabor [NMR Spectroscopy Department, Institute of Structural Chemistry, Chemical Research Center of the Hungarian Academy of Sciences, Pusztaszeri ut 59-67, Budapest 1025 (Hungary); Mihaly, Judith [Department of Biological Nanochemistry, Institute of Nanochemistry and Catalysis, Chemical Research Center of the Hungarian Academy of Sciences, Pusztaszeri ut 59-67, Budapest 1025 (Hungary); Kalman, Erika [Department of Surface Modification and Nanostructures, Institute of Nanochemistry and Catalysis, Chemical Research Center of the Hungarian Academy of Sciences, Pusztaszeri ut 59-67, Budapest 1025 (Hungary)

    2011-05-01

    This study presents the exploitation of an alternative reaction route of deamination of arylamines to perform in situ derivatisation of multi-walled carbon nanotubes (MWCNTs) with polyphenyl (PPh) species of various masses. As a result of consecutive derivatisation, high conversion of PPh grafting of the MWCNTs was realised with the collateral outgrowth of physical modification with adsorbed additional PPhs. Applied derivatisation process exceeds the monolayer coverage related superficial saturation limitations in the overall grafting yield of the nanotubes. Thus, a linear relationship was recognized between the overall quantities of chemisorbed PPhs composed of D{sub 5}-phenylene oligomers and the applied excess of diazonium activated reagents, corresponding to {sup 2}H MAS NMR spectroscopy results. According to mass spectrometry (MS) investigations, uniform thermal decomposition of the chemisorbed PPhs modified MWCNTs was found besides the more intense and altered decomposition characteristic-featured adsorbate-chemisorbate PPhs contained MWCNTs during sequential pyrolysis under inert atmosphere. This is attributed to the pyrolysis provoked isomerisation, decomposition and the formation of adsorbed and chemisorbed PPh moieties. As a result, a mediated and an even more pronounced degradation in the order of graphitic lattice of the MWCNTs were evidenced in the adsorbate-chemisorbate and the chemisorbate PPhs contained samples by FT-Raman spectroscopy and transmission electron microscopy (TEM), respectively. {sup 2}H MAS NMR supplied results of relevant amount of deuterium in the chemisorbate PPh contained sample without traces of aromatic related MS detected volatile products, these allow us to conclude about a thermally stable derivatisation that is interpreted as an endohedral modification of the nanotubes.

  4. The formation and structure of the oxide and hydroxide chemisorbed phases at the aluminum surface, and relevance to hydrogen embrittlement

    Science.gov (United States)

    Francis, Michael; Kelly, Robert; Neurock, Matthew

    2010-03-01

    Aluminum alloys used in aerospace structures are susceptible to environmentally assisted cracking (EAC) induced by hydrogen embrittlement (HE) (Gangloff and Ives 1990). Crack growth experiments have demonstrated a linear relation between the relative humidity of the environment and crack growth rates, indicating the importance of water (Speidel and Hyatt 1972). While the presence of water has been demonstrated to be necessary for EAC of aluminum, crack growth rates have been linked to the diffusivity of hydrogen in aluminum (Gangloff 2003) and hydrogen densities at the crack tip as high as Al2H have been observed (Young and Scully 1998). While the mechanism by which hydrogen embrittles aluminum is yet not well understood, without the entry of hydrogen into the aluminum matrix, embrittlement would not occur. While at the crack tip high hydrogen concentrations exist, the solubility of hydrogen in aluminum is normal near 1 ppm (Wolverton 2004). In this work combined first principles and kinetic Monte Carlo methods will be used to examine the oxide and hydroxide structure resulting from exposure of aluminum to H2O or O2 and relevance to hydrogen entry as well as EAC is discussed.

  5. Tribological properties of the synthesis of Cu-BTA composite nanoparticles via the thermal decomposition application in lubricants

    Science.gov (United States)

    Kao, M. J.; Hsu, F. C.; Guo, J. B.; Huang, K. D.; Peng, D. X.

    2013-11-01

    This project investigated the tribological properties of Cu-benzotriazole (BTA) composite nanoparticles as lubricant additives. BTA functions as a stabilizer for the Cu nanoparticles and as a protector from oxidation of the Cu nanoparticles in various test circumstances. Tribological experiments were conducted using a pin-on-disk (ASTM G99) test for the wear scar diameter, friction coefficient, and morphology of worn surfaces. Furthermore, the dispersivity of these Cu-BTA nanoparticles in liquid paraffin oil was measured using a UV/VIS spectrophotometer. The experiment results revealed the dispersion capability of the benzotriazole-capped Cu nanoparticles and indicated the dispersing stability in liquid paraffin oil for the BTA-capped surface of Cu nanoparticles. The testing results demonstrate that the Cu-BTA nanoparticle used as an additive in liquid paraffin oil at an appropriate concentration exhibits better tribological properties than those of pure paraffin oil. Moreover, Cu-BTA functioning as an additive has different anti-wear abilities due to its small size effect. Finally, the repair ability of Cu-BTA nanoparticles on the worn surfaces was observed using SEM and EDS.

  6. Corrosion inhibition of cobalt with a thin film of Cu-BTA

    Energy Technology Data Exchange (ETDEWEB)

    Brusic, V.; Frankel, G.S.; Schrott, A.G.; Petersen, T.A. (Thomas J. Watson Research Center, Yorktown Heights, NY (United States). IBM Research Division); Rush, B.M. (Univ. of California, Berkeley, CA (United States). Dept. of Chemical Engineering)

    1993-09-01

    Electrochemical techniques, ellipsometry and X-ray photoelectron spectroscopy were used to evaluate the use of benzotriazole, alone or in combination with boric acid/borate buffer and dilute copper sulfate for the protection of cobalt. The data indicate that in slightly alkaline solutions benzotriazole is a strong inhibitor for cobalt corrosion, whereas in water and neutral solutions it produces a barely measurable effect. In the presence of benzotriazole and Cu[sup +2] ions, spontaneous reduction of copper ions leads to the formation of a thin film of Cu-BTA on the cobalt surface. This film acts as a corrosion protector that is better than benzotriazole, with a significant reduction of the corrosion rate even during subsequent exposure to solutions without inhibitors.

  7. Electronic signatures of a model pollutant-particle system: chemisorbed phenol on TiO₂(110).

    Science.gov (United States)

    Patterson, Matthew C; Thibodeaux, Chad A; Kizilkaya, Orhan; Kurtz, Richard L; Poliakoff, E D; Sprunger, Phillip T

    2015-04-07

    Environmentally persistent free radicals (EPFRs) are a class of composite organic/metal oxide pollutants that have recently been discovered to form from a wide variety of substituted benzenes chemisorbed to commonly encountered oxides. Although a qualitative understanding of EPFR formation on particulate metal oxides has been achieved, a detailed understanding of the charge transfer mechanism that must accompany the creation of an unpaired radical electron is lacking. In this study, we perform photoelectron spectroscopy and electron energy loss spectroscopy on a well-defined model system-phenol chemisorbed on TiO2(110) to directly observe changes in the electronic structure of the oxide and chemisorbed phenol as a function of adsorption temperature. We show strong evidence that, upon exposure at high temperature, empty states in the TiO2 are filled and the phenol HOMO is depopulated, as has been proposed in a conceptual model of EPFR formation. This experimental evidence of charge transfer provides a deeper understanding of the EPFR formation mechanism to guide future experimental and computational studies as well as potential environmental remediation strategies.

  8. Phase behaviour of self-assembled monolayers controlled by tuning physisorbed and chemisorbed states: A lattice-model view.

    Science.gov (United States)

    Fortuna, Sara; Cheung, David L; Johnston, Karen

    2016-04-07

    The self-assembly of molecules on surfaces into 2D structures is important for the bottom-up fabrication of functional nanomaterials, and the self-assembled structure depends on the interplay between molecule-molecule interactions and molecule-surface interactions. Halogenated benzene derivatives on platinum have been shown to have two distinct adsorption states: a physisorbed state and a chemisorbed state, and the interplay between the two can be expected to have a profound effect on the self-assembly and phase behaviour of these systems. We developed a lattice model that explicitly includes both adsorption states, with representative interactions parameterised using density functional theory calculations. This model was used in Monte Carlo simulations to investigate pattern formation of hexahalogenated benzene molecules on the platinum surface. Molecules that prefer the physisorbed state were found to self-assemble with ease, depending on the interactions between physisorbed molecules. In contrast, molecules that preferentially chemisorb tend to get arrested in disordered phases. However, changing the interactions between chemisorbed and physisorbed molecules affects the phase behaviour. We propose functionalising molecules in order to tune their adsorption states, as an innovative way to control monolayer structure, leading to a promising avenue for directed assembly of novel 2D structures.

  9. Electronic Signatures of a Model Pollutant-Particle System: Chemisorbed Phenol on TiO2(110)

    Science.gov (United States)

    Patterson, Matthew C.; Thibodeaux, Chad A.; Kizilkaya, Orhan; Kurtz, Richard L.; Poliakoff, E. D.; Sprunger, Phillip T.

    2015-01-01

    Environmentally persistent free radicals (EPFRs) are a class of composite organic/metal oxide pollutants that have recently been discovered to form from a wide variety of substituted benzenes chemisorbed to commonly encountered oxides. Although a qualitative understanding of EPFR formation on particulate metal oxides has been achieved, a detailed understanding of the charge transfer mechanism that must accompany the creation of an unpaired radical electron is lacking. In this study, we perform photoelectron spectroscopy and electron energy loss spectroscopy on a well-defined model system – phenol chemisorbed on TiO2(110) – to directly observe changes in the electronic structure of the oxide and chemisorbed phenol as a function of adsorption temperature. We show strong evidence that, upon exposure at high temperature, empty states in the TiO2 are filled and the phenol HOMO is depopulated, as has been proposed in a conceptual model of EPFR formation. This experimental evidence of charge transfer provides a deeper understanding of the EPFR formation mechanism to guide future experimental and computational studies, as well as potential environmental remediation strategies. PMID:25774565

  10. Origin of the contact angle hysteresis of water on chemisorbed and physisorbed self-assembled monolayers.

    Science.gov (United States)

    Belman, Nataly; Jin, Kejia; Golan, Yuval; Israelachvili, Jacob N; Pesika, Noshir S

    2012-10-16

    Self-assembled monolayers (SAMs) are known to form on a variety of substrates either via chemisorption (i.e., through chemical interactions such as a covalent bond) or physisorption (i.e., through physical interactions such as van der Waals forces or "ionic" bonds). We have studied the behavior and effects of water on the structures and surface energies of both chemisorbed octadecanethiol and physisorbed octadecylamine SAMs on GaAs using a number of complementary techniques including "dynamic" contact angle measurements (with important time and rate-dependent effects), AFM, and electron microscopy. We conclude that both molecular overturning and submolecular structural changes occur over different time scales when such SAMs are exposed to water. These results provide new insights into the time-dependent interactions between surfaces and colloids functionalized with SAMs when synthesized in or exposed to high humidity or bulk water or wetted by water. The study has implications for a wide array of phenomena and applications such as adhesion, friction/lubrication and wear (tribology), surfactant-solid surface interactions, the organization of surfactant-coated nanoparticles, etc.

  11. Surface reactivity and layer analysis of chemisorbed reaction films in the surface-chemical environment of alkyl octadecenoates

    Indian Academy of Sciences (India)

    R B Choudhary; O N Anand; O S Tyagi

    2009-05-01

    Studies on surface reactivity of substrate iron (Fe-particles) were made in the tribo-chemical environment of alkyl octadecenoates. Two alkyl octadecenoates namely ethyl octadecenoate and methyl 12-hydroxy octadecenoate, slightly different in their chemical nature, were taken for preparing the chemisorbed reaction films (CRF) at the temperature 100 ± 5°C. The reaction products collected in the composite (amorphous) phase were isolated into three different solvent-soluble fractions (sub-layer films) using polar solvents of increasing polar strength. The FTIR analysis of these films showed that these were primarily organic in nature and were composed of alkyl and/or aryl hydroxy ethers, unsaturated hydroxy ketones, and aromatic structures chemically linked with iron surface. These reaction films also contained large amount of iron (Fe). Further, these film fractions also showed varying thermal behaviour during thermal decomposition in the temperature range of 50-800°C when thermally evaluated in the nitrogen environment.

  12. (10, 10) Single walled carbon nanotube consisted of chemisorbed oxygen atoms as a promising supercapacitor electrode material: A first principles study

    Science.gov (United States)

    Targholi, Ehsan; Molaei, Masoumeh; Mousavi-Khoshdel, S. Morteza

    2016-11-01

    The effects of atomic oxygen chemisorption on the electronic structures and quantum capacitance of (10, 10) CNT have been studied in this article. The results indicated that the chemisorption on bonds aligned with nanotube axis is more favorable than other position. The most efficient configuration for enhancing quantum capacitance is the nanotube with oxygen atoms chemisorbed on axial bonds. Specifically, in water stability range, the quantum capacitance of (10, 10) CNT before and after chemisorption of six oxygen atoms (aligned with nanotube axis) were found to be 222.6 (anode) -117.6 (cathode) and 306.9 (anode) -217.2 (cathode) F/g, respectively.

  13. Near-infrared surface-enhanced Raman spectroscopy of chemisorbed compounds on gold colloids

    Science.gov (United States)

    Xu, Hong; Tseng, Ching-Hui; Vickers, Thomas J.; Mann, Charles K.; Schlenoff, Joseph B.

    1994-05-01

    Near-infrared surface-enhanced Raman scattering (SERS) spectra have been measured for strongly chemisorbed compounds, such as 4-mercaptopyridine and thiophenol, on gold colloids in mixed solvents of ethanol and water using a diode laser as an excitation source. From UV-vis spectroscopy, the aggregated gold colloids show a broad absorbance band through the visible to the near-infrared after adding chemisorbing compounds. The absorption maximum is located in the range 750-850 nm, permitting the use of a near-IR source (826 nm) for the first time in SERS of gold colloid systems. The estimated enhancement is on the order of 10 5. Transmission electron microscopy of aggregated gold particles revealed a cluster morphology. The aggregated mixed-solvent colloids were more stable than those prepared in water, and were useful in dissolving compounds with poor water solubility.

  14. Pi resonance of chemisorbed alkali atoms on noble metals.

    Science.gov (United States)

    Borisov, A G; Sametoglu, V; Winkelmann, A; Kubo, A; Pontius, N; Zhao, J; Silkin, V M; Gauyacq, J P; Chulkov, E V; Echenique, P M; Petek, H

    2008-12-31

    We have performed a joint experimental and theoretical study of the unoccupied electronic structure of alkali adsorbates on the (111) surfaces of Cu and Ag. Combining angle- and time-resolved two-photon photoemission spectroscopy with wave packet propagation calculations we show that, along with the well known sigma resonance oriented along the surface normal, there exist long-lived alkali-localized resonances oriented parallel to the surface (pi symmetry). These new resonances are stabilized by the projected band gap of the substrate and emerge primarily from the mixing of the p and d Rydberg orbitals of the free alkali atom modified by the interaction with the surface.

  15. Low-energy electron-induced dissociation in condensed-phase L-cysteine II: a comparative study on anion desorption from chemisorbed and physisorbed films

    Science.gov (United States)

    Alizadeh, Elahe; Massey, Sylvain; Sanche, Léon; Rowntree, Paul A.

    2016-04-01

    Due to its multifunctional structure, cysteine is becoming an ideal model molecule for investigating the complex interactions of proteins with metallic surfaces such as gold nanoparticles. We report herein the results of low-energy electron induced degradation of L-cysteine films, chemisorbed on a gold substrate via the thiol group or physisorbed into a clean gold surface. The data were recorded under ultra-high vacuum conditions at room temperature. Anion yields desorbed from these films by the impact of 0.5 to 19 eV electrons provide clear evidence of the efficient decomposition of this amino acid via dissociative electron attachment (i.e., from dissociation of intermediate transient anions located between 5 and 14 eV). The peaks in the desorbed-anion yield functions, associated with DEA, are superimposed on a continuously rising signal attributed to dipolar dissociation. Similar to the results previously observed from physisorbed films, light anionic species, with masses lower than 35 amu, have been detected. In addition, we measured for first time fragments at 14 amu (CH2-) and 15 amu (CH3-) desorbing from physisorbed films, as well as heavier fragments of mass 45 and 46 amu desorbing from chemisorbed films. Contribution to the Topical Issue "Low-Energy Interactions related to Atmospheric and Extreme Conditions", edited by S. Ptasinska, M. Smialek-Telega, A. Milosavljevic, B. Sivaraman.

  16. Methane reacts with heteropolyacids chemisorbed on silica to produce acetic acid under soft conditions

    KAUST Repository

    Sun, Miao

    2013-01-16

    Selective functionalization of methane at moderate temperature is of crucial economic, environmental, and scientific importance. Here, we report that methane reacts with heteropolyacids (HPAs) chemisorbed on silica to produce acetic acid under soft conditions. Specially, when chemisorbed on silica, H 4SiW12O40, H3PW12O 40, H4SiMo12O40, and H 3PMo12O40 activate the primary C-H bond of methane at room temperature and atmospheric pressure. With these systems, acetic acid is produced directly from methane, in a single step, in the absence of Pd and without adding CO. Extensive surface characterization by solid-state NMR spectroscopy, IR spectroscopy, cyclic voltammetry, and X-ray photoelectron spectroscopy suggests that C-H activation of methane is triggered by the protons in the HPA-silica interface with concerted reduction of the Keggin cage, leading to water formation and hydration of the interface. This is the simplest and mildest way reported to date to functionalize methane. © 2012 American Chemical Society.

  17. Probing the photochemistry of chemisorbed oxygen on TiO2(110) with Kr and other co-adsorbates.

    Science.gov (United States)

    Petrik, Nikolay G; Kimmel, Greg A

    2014-02-14

    Weakly-bound atoms and molecules (Ar, Kr, Xe, CO, CH4, CO2, CH3OH, N2O, and N2) are used to probe the photochemical interactions of chemisorbed oxygen on rutile TiO2(110). Ultraviolet irradiation of chemisorbed oxygen co-adsorbed with the probe species leads to photon-stimulated desorption (PSD) of some of the probe species (e.g. Kr and CH4), but not others (e.g. CO2 and N2O). Without chemisorbed oxygen, the PSD yields of all the probe species are very low or not observed. Surprisingly, both chemisorbed O2 and oxygen adatoms, Oa, are photo-active for desorption of Kr and other weakly-bound species. To our knowledge, this is the first evidence for photo-activity of Oa on TiO2(110). The Kr PSD yield increases with increasing coverage of Kr and of chemisorbed oxygen. For Kr, the angular distribution of the photodesorbed atoms is approximately cosine. The Kr distribution is quite different from the angular distribution for the O2 PSD, which is sharply peaked along the surface normal. We propose that various forms of chemisorbed oxygen are excited by reactions with electrons and/or holes created in the TiO2 substrate by UV photon irradiation. The photo-excited oxygen collides with, and transfers energy to, neighboring co-adsorbed atoms or molecules. For co-adsorbates with a small enough binding energy to the substrate, desorption may result. The observed phenomenon provides a new tool for studying photochemical processes.

  18. Density functional theory study of O-H and C-H bond scission of methanol catalyzed by a chemisorbed oxygen layer on Cu(111)

    Science.gov (United States)

    Li, Jonathan; Zhou, Guangwen

    2016-04-01

    Using the density-functional theory within the generalized gradient approximation, we have studied the partial oxidation of methanol on a Cu(111) surface covered with a chemisorbed oxygen layer that resembles a Cu2O layer. Adsorption energies and geometries were computed for methanol, methoxy, hydroxymethyl and formaldehyde on both clean Cu(111) and Cu2O/Cu(111) and electronic structures were computed for the reaction intermediates on Cu2O/Cu(111). We also calculated the energy barrier for partial oxidation of methanol to formaldehyde on Cu2O/Cu(111). These results show that the Cu2O monolayer slightly lowers the stability of each of the surface adsorbates and the oxygen strongly promotes hydrogen dissociation by lowering the energy barrier of methanol decomposition and causing the spontaneous dissociation of methanol into methoxy.

  19. Efficient, rapid one-electron photooxidation of chemisorbed polyhydroxyl alcohols and carbohydrates by TiO2 nanoparticles in an aqueous solution

    CERN Document Server

    Shkrob, I A; Gosztola, D J

    2004-01-01

    Time-resolved transient absorption spectroscopy has been used to study nanosecond and sub-microsecond electron dynamics in aqueous anatase nanoparticles in the presence of hole scavengers: chemisorbed polyols and carbohydrates. These polyhydroxylated compounds are rapidly oxidized by the holes; 50-60% of these holes are scavenged within the duration of 355 nm excitation laser pulse. The scavenging efficiency rapidly increases with the number of anchoring hydroxyl groups and varies considerably as a function of the carbohydrate structure. A specific binding site for the polyols and carbohydrates is suggested that involves an octahedral Ti atom chelated by the poly-OH ligand. This mode of binding accounts for the depletion of undercoordinated Ti atoms observed in the XANES spectra of polyol coated nanoparticles. We suggest that these binding sites trap a substantial fraction of holes before the latter descend to surface traps and/or recombine with free electrons. The resulting oxygen hole center rapidly loses a...

  20. Photoemission study of the adsorption of benzotriazole on copper

    Energy Technology Data Exchange (ETDEWEB)

    Fang, B.S.

    1986-01-01

    A new model of the CuBTA chemisorbed structure is presented. The Cu-BTA polymer is formed by strong charge-transfer interactions between benzotriazole molecules instead of by BTA-Cu-BTA connections. It successfully interprets the experimental results from solubility and tarnish resistance tests on adsorbed films on copper surfaces. It also gives a reasonable explanation for the different inhibition coefficients among BTA-treated copper single crystal surfaces. This study leads to an understanding of the benzotriazole inhibition mechanism: (1) All the copper atoms can be bound to BTA nitrogen atoms and the absence of active surface sites prevents attack by corrosive ions. (2) The BTA molecule stands vertically, or nearly so, to the copper surface, but still allows the formation of a compact protective surface film. (3) The strong infinite polymer chains stabilize the protective film and strengthen its inhibition capability. 92 refs., 26 figs., 10 tabs.

  1. Evaluation of a Combined Ultraviolet Photocatalytic Oxidation(UVPCO)/Chemisorbent Air Cleaner for Indoor Air Applications

    Energy Technology Data Exchange (ETDEWEB)

    Hodgson, Alfred T.; Destaillats, Hugo; Hotchi, Toshifumi; Fisk,William J.

    2007-02-01

    We previously reported that gas-phase byproducts of incomplete oxidation were generated when a prototype ultraviolet photocatalytic oxidation (UVPCO) air cleaner was operated in the laboratory with indoor-relevant mixtures of VOCs at realistic concentrations. Under these conditions, there was net production of formaldehyde and acetaldehyde, two important indoor air toxicants. Here, we further explore the issue of byproduct generation. Using the same UVPCO air cleaner, we conducted experiments to identify common VOCs that lead to the production of formaldehyde and acetaldehyde and to quantify their production rates. We sought to reduce the production of formaldehyde and acetaldehyde to acceptable levels by employing different chemisorbent scrubbers downstream of the UVPCO device. Additionally, we made preliminary measurements to estimate the capacity and expected lifetime of the chemisorbent media. For most experiments, the system was operated at 680-780 m{sup 3}/h (400-460 cfm). A set of experiments was conducted with common VOCs introduced into the UVPCO device individually and in mixture. Compound conversion efficiencies and the production of formaldehyde and acetaldehyde were determined by comparison of compound concentrations upstream and downstream of the reactor. There was general agreement between compound conversions efficiencies determined individually and in the mixture. This suggests that competition among compounds for active sites on the photocatalyst surface will not limit the performance of the UVPCO device when the total VOC concentration is low. A possible exception was the very volatile alcohols, for which there were some indications of competitive adsorption. The results also showed that formaldehyde was produced from many commonly encountered VOCs, while acetaldehyde was generated by specific VOCs, particularly ethanol. The implication is that formaldehyde concentrations are likely to increase when an effective UVPCO air cleaner is used in

  2. Probing the photochemistry of chemisorbed oxygen on TiO2(110) with Kr and other co-adsorbates

    Energy Technology Data Exchange (ETDEWEB)

    Petrik, Nikolay G.; Kimmel, Gregory A.

    2014-02-14

    Weakly bound (physisorbed) atoms and molecules such as Ar, Kr, Xe, CO, CH4, CH3OH, CO2 and N2 are used to probe the photochemical interactions of O2 on rutile TiO2(110). UV irradiation of chemisorbed O2 along with the physisorbed probe species leads to photon-stimulated desorption (PSD) of Ar, Kr, CO, CH4 and N2. Without co-adsorbed O2, the PSD yields of the probe species are very low or not observed. No PSD was observed for CO2, N2O, CH3OH and the PSD yield for Xe is very low compared to the other probe atoms or molecules. The angular distribution of the photo-desorbing Kr, which is broad and cosine, is quite different from the O2 PSD angular distribution, which is sharply peaked along the surface normal. The Kr PSD yields increase with increasing coverage of Kr and of chemisorbed O2. We propose a mechanism for the observed phenomena where the chemisorbed O2 serves as photoactive center, excited via electronic excitations (electrons and/or holes) created in the TiO2 substrate by UV photon irradiation. The photo-excited O2 may transfer its energy to neighboring co-adsorbed atom or molecule resulting in desorption of the latter. Simple momentum transfer considerations suggest that heavier adsorbates (like Xe) and adsorbates with higher binding energy (like CO2) should desorb less efficiently according to the proposed mechanism. Various forms of chemisorbed O2 appeared photoactive in such stimulated desorption of Kr atoms: molecular anions (O22-, O2-), adatoms (Oa), and others. The observed phenomenon provides a new tool for study of photocatalysis.

  3. Light-induced reversible modification of the work function of a new perfluorinated biphenyl azobenzene chemisorbed on Au (111)

    Science.gov (United States)

    Masillamani, Appan Merari; Osella, Silvio; Liscio, Andrea; Fenwick, Oliver; Reinders, Federica; Mayor, Marcel; Palermo, Vincenzo; Cornil, Jérôme; Samorì, Paolo

    2014-07-01

    We describe the synthesis of a novel biphenyl azobenzene derivative exhibiting: (i) a protected thiol anchoring group in the α-position to readily form self-assembled monolayers (SAMs) on Au surfaces; and (ii) a terminal perfluorinated benzene ring in the ω-position to modify the surface properties. The design of this molecule ensured both an efficient in situ photoswitching between the trans and cis isomers when chemisorbed on Au(111), due to the presence of a biphenyl bridge between the thiol protected anchoring group and the azo dye, and a significant variation of the work function of the SAM in the two isomeric states, induced by the perfluorinated phenyl head group. By exploiting the light responsive nature of the chemisorbed molecules, it is possible to dynamically modify in situ the work function of the SAM-covered electrode, as demonstrated both experimentally and by quantum-chemical calculations, revealing changes in work function up to 220 meV. These findings are relevant for tuning the work function of metallic electrodes, and hence to dynamically modulate charge injection at metal-semiconductor interfaces for organic opto-electronic applications.We describe the synthesis of a novel biphenyl azobenzene derivative exhibiting: (i) a protected thiol anchoring group in the α-position to readily form self-assembled monolayers (SAMs) on Au surfaces; and (ii) a terminal perfluorinated benzene ring in the ω-position to modify the surface properties. The design of this molecule ensured both an efficient in situ photoswitching between the trans and cis isomers when chemisorbed on Au(111), due to the presence of a biphenyl bridge between the thiol protected anchoring group and the azo dye, and a significant variation of the work function of the SAM in the two isomeric states, induced by the perfluorinated phenyl head group. By exploiting the light responsive nature of the chemisorbed molecules, it is possible to dynamically modify in situ the work function of

  4. First-Principles Study of Mo Segregation in MoNi(111: Effects of Chemisorbed Atomic Oxygen

    Directory of Open Access Journals (Sweden)

    Yanlin Yu

    2015-12-01

    Full Text Available Segregation at metal alloy surfaces is an important issue because many electrochemical and catalytic properties are directly correlated to the surface composition. We have performed density functional theory calculations for Mo segregation in MoNi(111 in the presence of chemisorbed atomic oxygen. In particular, the coverage dependence and possible adsorption-induced segregation phenomena are addressed by investigating segregation energies of the Mo atom in MoNi(111. The theoretical calculated results show that the Mo atom prefers to be embedded in the bulk for the clean MoNi(111, while it segregates to the top-most layer when the oxygen coverage is thicker than 1/9 monolayer (ML. Furthermore, we analyze the densities of states for the clean and oxygen-chemisorbed MoNi(111, and see a strong covalent bonding between Mo d-band states and O p-states. The present study provides valuable insight for exploring practical applications of Ni-based alloys as hydrogen evolution electrodes.

  5. Light-induced reversible modification of the work function of a new perfluorinated biphenyl azobenzene chemisorbed on Au (111).

    Science.gov (United States)

    Masillamani, Appan Merari; Osella, Silvio; Liscio, Andrea; Fenwick, Oliver; Reinders, Federica; Mayor, Marcel; Palermo, Vincenzo; Cornil, Jérôme; Samorì, Paolo

    2014-08-07

    We describe the synthesis of a novel biphenyl azobenzene derivative exhibiting: (i) a protected thiol anchoring group in the α-position to readily form self-assembled monolayers (SAMs) on Au surfaces; and (ii) a terminal perfluorinated benzene ring in the ω-position to modify the surface properties. The design of this molecule ensured both an efficient in situ photoswitching between the trans and cis isomers when chemisorbed on Au(111), due to the presence of a biphenyl bridge between the thiol protected anchoring group and the azo dye, and a significant variation of the work function of the SAM in the two isomeric states, induced by the perfluorinated phenyl head group. By exploiting the light responsive nature of the chemisorbed molecules, it is possible to dynamically modify in situ the work function of the SAM-covered electrode, as demonstrated both experimentally and by quantum-chemical calculations, revealing changes in work function up to 220 meV. These findings are relevant for tuning the work function of metallic electrodes, and hence to dynamically modulate charge injection at metal-semiconductor interfaces for organic opto-electronic applications.

  6. Novel SiO2-deposited CaF2 substrate for vibrational sum-frequency generation (SFG) measurements of chemisorbed monolayers in an aqueous environment.

    Science.gov (United States)

    Padermshoke, Adchara; Konishi, Shouta; Ara, Masato; Tada, Hirokazu; Ishibashi, Taka-Aki

    2012-06-01

    A novel SiO(2)-deposited CaF(2) (SiO(2)/CaF(2)) substrate for measuring vibrational sum-frequency generation (SFG) spectra of silane-based chemisorbed monolayers in aqueous media has been developed. The substrate is suitable for silanization and transparent over a broad range of the infrared (IR) probe. The present work demonstrates the practical application of the SiO(2)/CaF(2) substrate and, to our knowledge, the first SFG spectrum at the solid/water interface of a silanized monolayer observed over the IR fingerprint region (1780-1400 cm(-1)) using a back-side probing geometry. This new substrate can be very useful for SFG studies of various chemisorbed organic molecules, particularly biological compounds, in aqueous environments.

  7. A theoretical study of the relaxation of a phenyl group chemisorbed to an RDX freestanding thin film

    Science.gov (United States)

    Pereverzev, Andrey; Sewell, Thomas D.

    2016-08-01

    Energy relaxation from an excited phenyl group chemisorbed to the surface of a crystalline thin film of α-1,3,5-trinitro-1,3,5-triazacyclohexane (α-RDX) at 298 K and 1 atm is simulated using molecular dynamics. Two schemes are used to excite the phenyl group. In the first scheme, the excitation energy is added instantaneously as kinetic energy by rescaling momenta of the 11 atoms in the phenyl group. In the second scheme, the phenyl group is equilibrated at a higher temperature in the presence of static RDX geometries representative of the 298 K thin film. An analytical model based on ballistic phonon transport that requires only the harmonic part of the total Hamiltonian and includes no adjustable parameters is shown to predict, essentially quantitatively, the short-time dynamics of the kinetic energy relaxation (˜200 fs). The dynamics of the phenyl group for times longer than about 6 ps follows exponential decay and agrees qualitatively with the dynamics described by a master equation. Long-time heat propagation within the bulk of the crystal film is consistent with the heat equation.

  8. Selective ultrafast probing of transient hot chemisorbed and precursor states of CO on Ru(0001)

    DEFF Research Database (Denmark)

    Beye, M.; Anniyev, T.; Coffee, R.

    2013-01-01

    We have studied the femtosecond dynamics following optical laser excitation of CO adsorbed on a Ru surface by monitoring changes in the occupied and unoccupied electronic structure using ultrafast soft x-ray absorption and emission. We recently reported [M. Dell'Angela et al. Science 339, 1302...... (2013)SCIEAS0036-8075] a phonon-mediated transition into a weakly adsorbed precursor state occurring on a time scale of >2 ps prior to desorption. Here we focus on processes within the first picosecond after laser excitation and show that the metal-adsorbate coordination is initially increased due...... to hot-electron-driven vibrational excitations. This process is faster than, but occurs in parallel with, the transition into the precursor state. With resonant x-ray emission spectroscopy, we probe each of these states selectively and determine the respective transient populations depending on optical...

  9. Photoemission study of the adsorption of benzotriazole on copper

    Energy Technology Data Exchange (ETDEWEB)

    Fang, B.S.

    1985-01-01

    A photoemission study was performed on the chemisorption of benzotriazole (BTA) on polycrystalline copper (clean and oxidized) surfaces to understand the corrosion inhibition mechanism. The energy distribution curves indicate benzotriazole bonding to copper through nitrogen lone pair orbitals. They also disagree with the models which suggest that the benzotriazole molecular plane is oriented parallel to the copper surface by showing a lack of ..pi..-d interaction. The observed chemisorption of benzotriazole on atomically clean copper surfaces at room temperature suggests that an oxide layer is not necessary for the adsorption of benzotriazole. No structural difference was observed in the photoemission studies on BTA-clean copper and BTA-cuprous oxide surface film. This result demonstrates the major role of the copper atom upon benzotriazole adsorption. A new model of the CuBTA chemisorbed structure is presented. The Cu-BTA polymer is formed by strong charge-transfer interactions between benzotriazole molecules instead of by BTA-Cu-BTA connections. It successfully interprets the experimental results from solubility and tarnish resistance tests on adsorbed films on copper surfaces. It also gives a reasonable explanation for the different inhibition coefficients among BTA-treated copper single crystal surfaces. Mechanisms are suggested for the benzotriazole inhibition mechanisms.

  10. Reactivity of Chemisorbed Oxygen Atoms and Their Catalytic Consequences during CH 4 –O 2 Catalysis on Supported Pt Clusters

    Energy Technology Data Exchange (ETDEWEB)

    Chin, Ya-Huei(Cathy); Buda, Corneliu; Neurock, Matthew; Iglesia, Enrique

    2011-10-12

    Kinetic and isotopic data and density functional theory treatments provide evidence for the elementary steps and the active site requirements involved in the four distinct kinetic regimes observed during CH4 oxidation reactions using O2, H2O, or CO2 as oxidants on Pt clusters. These four regimes exhibit distinct rate equations because of the involvement of different kinetically relevant steps, predominant adsorbed species, and rate and equilibrium constants for different elementary steps. Transitions among regimes occur as chemisorbed oxygen (O*) coverages change on Pt clusters. O* coverages are given, in turn, by a virtual O2 pressure, which represents the pressure that would give the prevalent steady-state O* coverages if their adsorption–desorption equilibrium was maintained. The virtual O2 pressure acts as a surrogate for oxygen chemical potentials at catalytic surfaces and reflects the kinetic coupling between C–H and O=O activation steps. O* coverages and virtual pressures depend on O2 pressure when O2 activation is equilibrated and on O2/CH4 ratios when this step becomes irreversible as a result of fast scavenging of O* by CH4-derived intermediates. In three of these kinetic regimes, C–H bond activation is the sole kinetically relevant step, but occurs on different active sites, which evolve from oxygen–oxygen (O*–O*), to oxygen–oxygen vacancy (O*–*), and to vacancy–vacancy (*–*) site pairs as O* coverages decrease.

  11. Prototype Tests for the Recovery and Conversion of UF6 Chemisorbed in NaF Traps for the Molten Salt Reactor Remediation Project

    Energy Technology Data Exchange (ETDEWEB)

    Del Cul, G.D.; Icenhour, A.S.; Simmons, D.W.

    2000-04-01

    The remediation of the Molten Salt Reactor Experiment (MSRE) site includes the removal of about 37 kg of uranium. Of that inventory, about 23 kg have already been removed from the piping system and chemisorbed in 25 NaF traps. This material is being stored in Building 3019. The planned recovery of -11 kg of uranium from the fuel salt will generate another 15 to 19 NaF traps. The remaining 2 to 3 kg of uranium are present in activated charcoal beds, which are also scheduled to be removed from the reactor site. Since all of these materials (NaF traps and the uranium-laden charcoal) are not suitable for long-term storage, they will be converted to a chemical form [uranium oxide], which is suitable for long-term storage. This document describes the process that will be used to recover and convert the uranium in the NaF traps into a stable oxide for long-term storage. Included are a description of the process, equipment, test results, and lessons learned. The process was developed for remote operation in a hot cell. Lessons learned from the prototype testing were incorporated into the process design.

  12. Prototype Tests for the Recovery and Conversion of UF6Chemisorbed in NaF Traps for the Molten Salt Reactor Remediation Project

    Energy Technology Data Exchange (ETDEWEB)

    Del Cul, G.D.

    2000-06-07

    The remediation of the Molten Salt Reactor Experiment (MSRE) site includes the removal of about 37 kg of uranium. Of that inventory, about 23 kg have already been removed from the piping system and chemisorbed in 25 NaF traps. This material is being stored in Building 3019. The planned recovery of {approx}11 kg of uranium from the fuel salt will generate another 15 to 19 NaF traps. The remaining 2 to 3 kg of uranium are present in activated charcoal beds, which are also scheduled to be removed from the reactor site. Since all of these materials (NaF traps and the uranium-laden charcoal) are not suitable for long-term storage, they will be converted to a chemical form [uranium oxide (U{sub 3}O{sub 8})], which is suitable for long-term storage. This document describes the process that will be used to recover and convert the uranium in the NaF traps into a stable oxide for long-term storage. Included are a description of the process, equipment, test results, and lessons learned. The process was developed for remote operation in a hot cell. Lessons learned from the prototype testing were incorporated into the process design.

  13. Selectivity of Chemisorbed Oxygen in C–H Bond Activation and CO Oxidation and Kinetic Consequences for CH₄–O₂ Catalysis on Pt and Rh Clusters

    Energy Technology Data Exchange (ETDEWEB)

    Chin, Ya-Huei; Buda, Corneliu; Neurock, Matthew; Iglesia, Enrique

    2011-10-06

    Rate measurements, density functional theory (DFT) within the framework of transition state theory, and ensemble-averaging methods are used to probe oxygen selectivities, defined as the reaction probability ratios for O* reactions with CO and CH₄, during CH₄–O₂ catalysis on Pt and Rh clusters. CO₂ and H₂O are the predominant products, but small amounts of CO form as chemisorbed oxygen atoms (O*) are depleted from cluster surfaces. Oxygen selectivities, measured using ¹²CO–¹³CH₄–O₂ reactants, increase with O₂/ CO ratio and O* coverage and are much larger than unity at all conditions on Pt clusters. These results suggest that O* reacts much faster with CO than with CH₄, causing any CO that forms and desorbs from metal cluster surfaces to react along the reactor bed with other O* to produce CO₂ at any residence time required for detectable extents of CH₄ conversion. O* selectivities were also calculated by averaging DFTderived activation barriers for CO and CH₄ oxidation reactions over all distinct surface sites on cubo-octahedral Pt clusters (1.8 nm diameter, 201 Pt atoms) at low O* coverages, which are prevalent at low O₂ pressures during catalysis. CO oxidation involves non-activated molecular CO adsorption as the kinetically relevant step on exposed Pt atoms vicinal of chemisorbed O* atoms (on *–O* site pairs). CH₄ oxidation occurs via kinetically relevant C–H bond activation on *–* site pairs involving oxidative insertion of a Pt atom into one of the C–H bonds in CH₄, forming a three-centered HC₃–Pt–H transition state. C–H bond activation barriers reflect the strength of Pt–CH₃ and Pt–H interactions at the transition state, which correlates, in turn, with the Pt coordination and with CH₃ * binding energies. Ensemble-averaged O* selectivities increase linearly with O₂/CO ratios, which define the O* coverages, via a proportionality constant. The proportionality constant is given by the ratio of rate

  14. Chemisorbed and physisorbed structures for 1,10-phenanthroline and dipyrido[3,2-a : 2 ',3 '-c]phenazine on au(111)

    DEFF Research Database (Denmark)

    Cafe, P.F.; Larsen, Allan G.; Yang, W.R.

    2007-01-01

    Scanning tunneling microscopy (STM) images of 1,10-phenanthroline (PHEN) and dipyrido[3,2-a:2',3'-c]phenazine (DPPZ) on Au(111) are recorded using both in situ and ex situ techniques. The images of PHEN depict regimes of physisorption and chemisorption, whereas DPPZ is only physisorbed. All physi...

  15. a Photoemission Study of the Adsorption of Benzotriazole on Copper.

    Science.gov (United States)

    Fang, Bo-Shung

    1985-12-01

    A photoemission study was performed on the chemisorption of benzotriazole (BTA) on polycrystalline copper (clean and oxidized) surfaces to understand the corrosion inhibition mechanism. The energy distribution curves indicate benzotriazole bonding to copper through nitrogen lone pair orbitals. They also disagree with the models which suggest that the benzotriazole molecular plane is oriented parallel to the copper surface by showing a lack of (pi)-d interaction. The observed chemisorption of benzotriazole on atomi- cally clean copper surfaces at room temperature suggests that an oxide layer is not necessary for the adsorption of benzotriazole. No structural difference was observed in the photoemission studies on BTA-clean copper and BTA-cuprous oxide surface film. This results demonstrates the major role of the copper atom upon benzotriazole adsorption. A new model of the CuBTA chemisorbed structure is presented. The Cu-BTA polymer is formed by strong charge -transfer interac- tions between benzotriazole molecules instead of by BTA-Cu-BTA connections. It successfully interprets the experimental results from solubility and tarnish resistance tests on adsorbed films on copper surfaces. It also gives a reasonable explanation for the different inhibition coefficients among BTA-treated copper single crystal surfaces. This study leads to an understanding of the benzotriazole inhi- bition mechanism: (1) All the copper atoms can be bound to BTA nitrogen atoms and the absence of active surface sites prevents attack by corrosive ions. (2) The BTA molecule stands vertically, or nearly so, to the copper surface, but still allows the formation of a compact protective surface film. (3) The strong infinite polymer. chains stabilize the protective film and strengthen its inhibition capability. ('1)DOE Report IS-T-1196. This work was performed under contract No. W-7405-Eng-82 with the U.S. Department of Energy.

  16. Sulfur-induced structural motifs on copper and gold surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Walen, Holly [Iowa State Univ., Ames, IA (United States)

    2016-01-01

    The interaction of sulfur with copper and gold surfaces plays a fundamental role in important phenomena that include coarsening of surface nanostructures, and self-assembly of alkanethiols. Here, we identify and analyze unique sulfur-induced structural motifs observed on the low-index surfaces of these two metals. We seek out these structures in an effort to better understand the fundamental interactions between these metals and sulfur that lends to the stability and favorability of metal-sulfur complexes vs. chemisorbed atomic sulfur. The experimental observations presented here—made under identical conditions—together with extensive DFT analyses, allow comparisons and insights into factors that favor the existence of metal-sulfur complexes, vs. chemisorbed atomic sulfur, on metal terraces. We believe this data will be instrumental in better understanding the complex phenomena occurring between the surfaces of coinage metals and sulfur.

  17. Synthesis, Structure and Reactivity of Molecules Attached to Electrode Surfaces.

    Science.gov (United States)

    2014-09-26

    Structure and Reactivity of Molecules Attached to Electrode Surfaces", AFOSR #81-0149 III. REPORTING PERIOD: April 15, 1981 through April 14, 1985 IV...Adsorption .... ............... 17 9. Effect of Surface Roughness on Adsorbate Orientation and Reactivity . 20 10. Ordered/ Disordered Packing in Chemisorbed... reactivity only when present in the edge-pendant orientation. Clearly, molecular orientation (i.e., mode of +. .4 o,, -12- attachment to the surface) is a

  18. Robust, functionalizable, nanometer-thick poly(acrylic acid) films spontaneously assembled on oxidized aluminum substrates: structures and chemical properties.

    Science.gov (United States)

    Koo, Eunhae; Yoon, Sungho; Atre, Sundar V; Allara, David L

    2011-04-05

    Immersion of oxidized aluminum substrates in ethanol solutions of poly(acrylic acid) (PAA), followed by extensive solvent immersion, results in tenaciously chemisorbed, nanometer scale, controllable thickness films for a wide range of solution concentrations and molecular weights. Atomic force microscope images reveal isolated polymer globules from adsorption in low-concentration solutions with crossover to conformal, highly uniform, nanometer-thickness films at higher concentrations, an indication that the chemisorbing chains start to overlap and trap underlying segments to form planar chemisorbed films only two or three chains in thickness. Quantitative IR reflection spectroscopy in combination with chemical derivitization on a standard set of 1.0(±0.2) nm thick films reveals a film structure with 5.5(±1) chemisorbed -CO(-)(2) groups/nm(2) and 6.3 unattached -CO(2)H groups/nm(2), with up to ∼3.6/nm(2) available for chemical derivitization, a comparable number to typical self-assembled monolayer coverages of ∼4-5 molecules/nm(2). Thermal treatment of the ∼1 nm chemisorbed films, at even extreme temperatures of ∼150 °C, results in almost no anhydride formation via adjacent -CO(2)H condensation, in strong contrast to bulk PAA, a clear indication that the films have a frozen glass structure with effectively no segment and side group mobility. Overall, these results demonstrate that these limiting thickness nanometer films provide a model surface for understanding the behavior of strongly bound polymer chains at substrates and show potential as a path to creating highly stable, chemically functionalized inorganic substrates with highly variable surface properties.

  19. Photoinduced electron transfer through peptide-based self-assembled monolayers chemisorbed on gold electrodes: directing the flow-in and flow-out of electrons through peptide helices.

    Science.gov (United States)

    Venanzi, Mariano; Gatto, Emanuela; Caruso, Mario; Porchetta, Alessandro; Formaggio, Fernando; Toniolo, Claudio

    2014-08-21

    Photoinduced electron transfer (PET) experiments have been carried out on peptide self-assembled monolayers (SAM) chemisorbed on a gold substrate. The oligopeptide building block was exclusively formed by C(α)-tetrasubstituted α-aminoisobutyric residues to attain a helical conformation despite the shortness of the peptide chain. Furthermore, it was functionalized at the C-terminus by a pyrene choromophore to enhance the UV photon capture cross-section of the compound and by a lipoic group at the N-terminus for linking to gold substrates. Electron transfer across the peptide SAM has been studied by photocurrent generation experiments in an electrochemical cell employing a gold substrate modified by chemisorption of a peptide SAM as a working electrode and by steady-state and time-resolved fluorescence experiments in solution and on a gold-coated glass. The results show that the electronic flow through the peptide bridge is strongly asymmetric; i.e., PET from the C-terminus to gold is highly favored with respect to PET in the opposite direction. This effect arises from the polarity of the Au-S linkage (Au(δ+)-S(δ-), junction effect) and from the electrostatic field generated by the peptide helix.

  20. High-resolution solid-state (13)C NMR studies of chemisorbed organometallics. Chemisorptive formation of cation-like and alkylidene organotantalum complexes on high surface area inorganic oxides.

    Science.gov (United States)

    Ahn, Hongsang; Marks, Tobin J

    2002-06-19

    (13)C CPMAS NMR spectroscopy has been employed to investigate the surface chemistry of the organotantalum hydrocarbyl/alkylidene complexes, Cp'Ta((13)CH(3))(4) (1*), Cp(2)Ta((13)CH(3))(3) (2*), Cp(2)Ta((13)CH(2))((13)CH(3)) (3*), and Ta((13)CH(t)Bu)((13)CH(2)(t)Bu)(3) (4*) [Cp' = eta(5)-(CH(3))(5)C(5), Cp = eta(5)-C(5)H(5)] supported on partially dehydroxylated silica (PDS), dehydroxylated silica (DS), or dehydroxylated gamma-alumina (DA). Mono-Cp tantalum hydrocarbyl 1* undergoes chemisorption to form Cp'Ta((13)CH(3))(3)O-Si mu-oxo species on silica, and "cation-like" Cp'Ta((13)CH(3))(3)(+) and Cp'Ta((13)CH(3))(3)O-Al mu-oxo species on DA, via pathways analogous to those established for organo-group 4 and actinide complexes. When supported on DA, bis-Cp tantalum hydrocarbyl 2* follows the same chemisorption mode as 1*. However, when 2* is chemisorbed on PDS and DS, a "cation-like" Cp(2)Ta((13)CH(3))(2)(+) species is the major adsorbate product. On PDS, bis-Cp tantalum alkylidene complex 3* is converted predominantly to a stable "cation-like" Cp(2)Ta((13)CH(3))(2)(+) species, presumably via electrophilic addition of a proton from the PDS surface. In contrast to 3*, Ta alkylidene complex 4* forms predominantly a Ta((13)CH(t)Bu)((13)CH(2)(t)Bu)(2)O-Si, mu-oxo-alkylidene species on PDS.

  1. Promotional effects of chemisorbed oxygen and hydroxide in the activation of C-H and O-H bonds over transition metal surfaces

    Science.gov (United States)

    Hibbitts, David; Neurock, Matthew

    2016-08-01

    Electronegative coadsorbates such as atomic oxygen (O*) and hydroxide (OH*) can act as Brønsted bases when bound to Group 11 as well as particular Group 8-10 metal surfaces and aid in the activation of X-H bonds. First-principle density functional theory calculations were carried out to systematically explore the reactivity of the C-H bonds of methane and surface methyl intermediates as well as the O-H bond of methanol directly and with the assistance of coadsorbed O* and OH* intermediates over Group 11 (Cu, Ag, and Au) and Group 8-10 transition metal (Ru, Rh, Pd, Os, Ir, and Pt) surfaces. C-H as well as O-H bond activation over the metal proceeds via a classic oxidative addition type mechanism involving the insertion of the metal center into the C-H or O-H bond. O* and OH* assist C-H and O-H activation over particular Group 11 and Group 8-10 metal surfaces via a σ-bond metathesis type mechanism involving the oxidative addition of the C-H or O-H bond to the metal along with a reductive deprotonation of the acidic C-H and O-H bond over the M-O* or M-OH* site pair. The O*- and OH*-assisted C-H activation paths are energetically preferred over the direct metal catalyzed C-H scission for all Group 11 metals (Cu, Ag, and Au) with barriers that are 0.4-1.5 eV lower than those for the unassisted routes. The barriers for O*- and OH*-assisted C-H activation of CH4 on the Group 8-10 transition metals, however, are higher than those over the bare transition metal surfaces by as much as 1.4 eV. The C-H activation of adsorbed methyl species show very similar trends to those for CH4 despite the differences in structure between the weakly bound methane and the covalently adsorbed methyl intermediates. The activation of the O-H bond of methanol is significantly promoted by O* as well as OH* intermediates over both the Group 11 metals (Cu, Ag, and Au) as well as on all Group 8-10 metals studied (Ru, Rh, Pd, Os, Ir, and Pt). The O*- and OH*-assisted CH3O-H barriers are 0.6 to 2

  2. In situ chemical and structural investigations of the oxidation of Ge(001) substrates by atomic oxygen

    Science.gov (United States)

    Molle, Alessandro; Bhuiyan, Md. Nurul Kabir; Tallarida, Grazia; Fanciulli, Marco

    2006-08-01

    The exposure of Ge(001) substrates to atomic oxygen was studied in situ to establish the stability of the germanium oxide. After preparing chemically clean and atomically flat Ge(001) surfaces, the Ge samples were exposed to atomic oxygen in a wide temperature range from room temperature to 400°C. The chemical composition of the so-formed oxides was studied by means of x-ray photoelectron spectroscopy, while the structure was observed by reflection high energy electron diffraction. At low substrate temperatures the atomic oxygen is efficiently chemisorbed and suboxides coexist with the dioxide, which in turn is remarkably promoted in the high temperature range.

  3. Optical properties of molecules chemisorbed on the Ni (111) surface

    Energy Technology Data Exchange (ETDEWEB)

    Robota, H. J. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States); Whitmore, P. M. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States); Harris, C. B. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)

    1982-02-15

    The adsorption of a variety of molecules on Ni(111) is studied by UV/visible spectroscopic ellipsometry. The spectra were analyzed within a simple dielectric model. The absorption spectra of annealed, thin, condensed layers of pyrazine, pyridine, and naphthalene on the Ni(111) surface resemble bulk crystal spectra, indicating minimal perturbations due to the metal substrate. Chemisorption of molecules on the Ni(111) surface produced enhanced absorption between 2800Å and 3100Å. The wide range of adsorbate properties and surface chemistry suggest a modification of the optical response of the metal upon chemisorption. Furthermore, this enhanced optical absorption is attributed to nonvertical interband transitions made possible by loss of translational invariance at the surface.

  4. Surface Acoustic Wave Sensor with Pd/ZnO Bilayer Structure for Room Temperature Hydrogen Detection.

    Science.gov (United States)

    Viespe, Cristian; Miu, Dana

    2017-06-29

    A Surface Acoustic Wave (SAW) hydrogen sensor with a Pd/ZnO bilayer structure for room temperature sensing operation has been obtained by Pulsed Laser Deposition (PLD). The sensor structure combines a Pd layer with optimized porosity for maximizing mass effects, with the large acoustoelectric effect at the Pd/ZnO interface. The large acoustoelectric effect is due to the fact that ZnO has a surface conductivity which is highly sensitive to chemisorbed gases. The sensitivity of the sensor was determined for hydrogen concentrations between 0.2% and 2%. The limit of detection (LOD) of the bilayer sensor was about 4.5 times better than the single ZnO films and almost twice better than single Pd films.

  5. Structure and stability of a high-coverage (1x1) oxygen phase on Ru(0001)

    CERN Document Server

    Stampfl, C; Over, H; Scheffler, M; Ertl, G

    1996-01-01

    The formation of chemisorbed O-phases on Ru(0001) by exposure to O_2 at low pressures is apparently limited to coverages Theta <= 0.5. Using low-energy electron diffraction and density functional theory we show that this restriction is caused by kinetic hindering and that a dense O overlayer (Theta = 1) can be formed with a (1x1) periodicity. The structural and energetic properties of this new adsorbate phase are analyzed and discussed in view of attempts to bridge the so-called "pressure gap" in heterogeneous catalysis. It is argued that the identified system actuates the unusually high rate of oxidizing reactions at Ru surfaces under high oxygen pressure conditions.

  6. Determining Orientational Structure of Diamondoid Thiols Attached to Silver Using Near Edge X-ray Absorption Fine Structure Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Willey, T M; Lee, J I; Fabbri, J D; Wang, D; Nielsen, M; Randel, J C; Schreiner, P R; Fokin, A A; Tkachenko, B A; Fokina, N A; Dahl, J P; Carlson, R K; Terminello, L J; Melosh, N A; van Buuren, T

    2008-10-07

    Near-edge x-ray absorption fine structure spectroscopy (NEXAFS) is a powerful tool for determination of molecular orientation in self-assembled monolayers and other surface-attached molecules. A general framework for using NEXAFS to simultaneously determine molecular tilt and twist of rigid molecules attached to surfaces is presented. This framework is applied to self-assembled monolayers of higher diamondoid, hydrocarbon molecules with cubic-diamond-cage structures. Diamondoid monolayers chemisorbed on metal substrates are known to exhibit interesting electronic and surface properties. This work compares molecular orientation in monolayers prepared on silver substrates using two different thiol positional isomers of [121]tetramantane, and thiols derived from two different pentamantane structural isomers, [1212]pentamantane and [1(2,3)4]pentamantane. The observed differences in monolayer structure demonstrate the utility and limitations of NEXAFS spectroscopy and the framework. The results also demonstrate the ability to control diamondoid assembly, in particular the molecular orientational structure, providing a flexible platform for the modification of surface properties with this exciting new class of nanodiamond materials.

  7. Structural transitions between epitaxially ordered phases in adsorbed submonolayers

    Science.gov (United States)

    Ostlund, S.; Berker, A. N.

    1980-06-01

    The global phase diagram of a triangular lattice-gas model for submonolayers adsorbed epitaxially on basal graphite is studied using a position-space renormalization method. This model has nearest-neighbor exclusion, and accomodates dominant third-neighbor interaction. Each cell of 12 sites is mapped onto a single local degree of freedom with a single-triplet-quadruplet structure. The lattice gas, with up to 20th-neighbor interactions, is thereby transformed into a nearest-neighbor model, which is then analyzed by a Migdal-Kadanoff renormalization transformation. At low temperatures, as coverage is increased from zero, gas, 2 × 2 solid, and 3×3 solid phases can be encountered, separated by first-order transitions. These solids undergo first-or higher-order transitions into fluid phases as temperature is increased at given density. Triple points, multicritical points, and/or critical end-points occur for various relative strengths of interactions. For certain plausible potentials, the 2 × 2 solid occurs at finite temperature, but not at zero temperature. Distinct liquid and gas phases, with a solid-liquid-gas triple point, are found in some cases. Contact is made with the phase diagram of methane physisorbed on basal graphite, suggesting that the effective hard-core radius of methane is increased by adsorption. A phase diagram very similar to that exhibited by oxygen chemisorbed on nickel (111), with both 2 × 2 and 3×3 structures, is also obtained.

  8. Adsorption site and structure determination of c(2x2) N{sub 2}/Ni(100) using angle-resolved photoemission extended fine structure

    Energy Technology Data Exchange (ETDEWEB)

    Moler, E.J.; Kellar, S.A.; Huff, W.R.A. [Lawrence Berkeley National Lab., CA (United States)] [and others

    1997-04-01

    The authors have determined the atomic spatial structure of c(2x2) N2Ni(100) with Angle-Resolved Photoemission Extended Fine Structure (ARPEFS) from the nitrogen 1s core level using monochromatized x-rays from beamline 6.1 at SSRL and beamline 9.3.2 at the ALS. The chemically shifted N 1s peak intensities were summed together to obtain ARPEFS curves for both nitrogen atoms in the molecule. They used a new, highly-optimized program based on the Rehr-Albers scattering matrix formalism to find the adsorption site and to quantitatively determine the bond-lengths. The nitrogen molecule stands upright at an atop site, with a N-Ni bond length of 2.25(1) {angstrom}, a N-N bond length of 1.10(7) {angstrom}, and a first layer Ni-Ni spacing of 1.76(4) {angstrom}. The shake-up peak shows an identical ARPEFS diffraction pattern, confirming its intrinsic nature and supporting a previous use of this feature to decompose the peak into contributions from the chemically inequivalent nitrogen atoms. Comparison to a previously published theoretical treatment of N-N-Ni and experimental structures of analogous adsorbate systems demonstrates the importance of adsorbate-adsorbate interactions in weakly chemisorbed systems.

  9. Self-Assembled Structures of Benzoic Acid on Au(111) Surface

    Science.gov (United States)

    Vu, Thu-Hien; Wandlowski, Thomas

    2017-02-01

    Electrochemical scanning tunneling microscopy combined with cyclic voltammetry were employed to explore the self-assembly of benzoic acid (BA) on a Au(111) substrate surface in a 0.1-M HClO4 solution. At the negatively charged surface, BA molecules form two highly ordered physisorbed adlayers with their phenyl rings parallel to the substrate surface. High-resolution scanning tunneling microscopy images reveal the packing arrangement and internal molecular structures. The striped pattern and zigzag structure of the BA adlayers are composed of parallel rows of dimers, in which two BA molecules are bound through a pair of O-H···O hydrogen bonds. Increasing the electrode potential further to positive charge densities of Au(111) leads to the desorption of the physisorbed hydrogen-bonded networks and the formation of a chemisorbed adlayer. BA molecules change their orientation from planar to upright fashion, which is accompanied by the deprotonation of the carboxyl group. Furthermore, potential-induced formation and dissolution of BA adlayers were also investigated. Structural transitions between the various types of ordered adlayers occur according to a nucleation and growth mechanism.

  10. Calcium-phosphorus interactions at a nano-structured silicate surface.

    Science.gov (United States)

    Southam, Daniel C; Lewis, Trevor W; McFarlane, Andrew J; Borrmann, T; Johnston, Jim H

    2008-03-15

    Nano-structured calcium silicate (NCS), a highly porous material synthesized by controlled precipitation from geothermal fluids or sodium silicate solution, was developed as filler for use in paper manufacture. NCS has been shown to chemisorb orthophosphate from an aqueous solution probably obeying a Freundlich isotherm with high selectivity compared to other common environmental anions. Microanalysis of the products of chemisorption indicated there was significant change from the porous and nano-structured morphology of pristine NCS to fibrous and crystalline morphologies and non-porous detritus. X-ray diffraction analysis of the crystalline products showed it to be brushite, CaHPO42H2O, while the largely X-ray amorphous component was a mixture of calcium phosphates. A two-step mechanism was proposed for the chemisorption of phosphate from an aqueous solution by NCS. The first step, which was highly dependent on pH, was thought to be desorption of hydroxide ions from the NCS surface. This was kinetically favoured at lower initial pH, where the predominant form of phosphate present was H2PO(-)4, and led to decreased phosphorus uptake with increasing pH. The second step was thought to be a continuing chemisorption process after stabilization of the pH-value. The formation of brushite as the primary chemisorption product was found to be consistent with the proposed mechanism.

  11. Adlayer structures of anthracenthiol on Au(111) after removal of covering multilayers with probe scan

    Science.gov (United States)

    Azzam, Waleed

    2016-05-01

    Self-assembled monolayers (SAMs) of anthracene-2-thiol (AnT) on Au(111) have been investigated using scanning tunneling microscopy (STM). A preparation of AnT-SAMs from ethanolic solutions results in a deposition of multilayer films. As a result, the general features that have been frequently observed for different systems of thiol-modified gold surfaces are hidden in AnT-SAMs. The thin overlayers on top of the chemisorbed anthracenethiolate monolayer are removed by the STM-tip after a repetitive scanning over the same part of the SAM at nondestructive imaging conditions. After ∼2 h of consecutive and continuous STM scanning, smooth AnT-SAM surfaces were formed. The polished surfaces contain vacancy depressions rather than the elevated gold islands which are typically formed after the adsorption of purely aromatic thiols such as AnT on Au(111). The STM data showed the coexistence of two distinct stable commensurate phases, namely, α and β. High-resolution STM images revealed a (√{ 3 } × 8) structure for the α phase and a (√{ 7 } × 4) R11° structure for the β phase whose unit cells contain, respectively, four and two molecules. The β phase was found to be 50% less densely packed than the α phase. The lower molecular density of the β phase should be correlated with a significantly larger tilt angle of the AnT molecular backbone with respect to the surface normal.

  12. Self-assembled alkanethiol monolayers on gold surfaces: resolving the complex structure at the interface by STM.

    Science.gov (United States)

    Guo, Quanmin; Li, Fangsen

    2014-09-28

    The surface properties of metals and metal oxides can be modified by adding a single layer of organic molecules. A most popular route for depositing such a molecular layer is via the formation of self-assembled monolayers (SAMs). The molecules that form SAMs have a functionality which binds to the surface and the adsorption is self-regulated to terminate at exactly one single molecular layer. The very first example, which has become the most widely studied system, of SAMs on metal surfaces consists of chemisorbed alkylthiolate on gold. Despite the simplicity in the preparation of alkanethiol SAMs and the seemingly straightforward structure of such SAMs, the detailed bonding between the sulfur head group and gold is still subject to debate. Experimental and theoretical effort in the last six years has led to a much improved understanding of this classical system of SAMs. In this review, we will highlight the most recent progress in the study of the interfacial structure of alkanethiol SAMs on gold. We focus on the important phenomenon of phase transition that occurs from n-propanethiol to n-butanethiol, and propose a unified structural model to explain how the (3 × 4) phase for short chain alkanethiol monolayers (methyl-, ethyl- and propylthiolate monolayers) changes into the (3 × 2√3)-rect./c(4 × 2) phase for long chain molecular monolayers.

  13. The Dynamics and Structures of Adsorbed Surfaces

    DEFF Research Database (Denmark)

    Nielsen, M; Ellenson, W. D.; McTague, J. P.

    1978-01-01

    of molecules such as NH3 or the internal modes of adsorbed molecules such as C4H10. Neutron scattering measurements where substrates other than graphite products are used as the adsorbents will not be reviewed here. However, the power of the technique will be demonstrated in an example of H2 physisorbed...... to activated alumina and in an example where hydrogen is chemisorbed to Raney nickel...

  14. Structure-activity relationship of CuO/MnO2 catalysts in CO oxidation

    Science.gov (United States)

    Qian, Kun; Qian, Zhaoxia; Hua, Qing; Jiang, Zhiquan; Huang, Weixin

    2013-05-01

    A series of CuO/MnO2 catalysts with different CuO loadings were synthesized by the incipient wetness impregnation method. The catalysts were characterized by N2 adsorption-desorption isotherms, powder X-ray diffraction, X-ray photoelectron spectroscopy, H2-temperature programmed reduction, CO-temperature programmed reduction and scanning electron microscope. The CuO/MnO2 catalysts with CuO loading of 1-40% exhibit almost the same catalytic performance toward CO oxidation while those with higher CuO loadings exhibit a much poorer catalytic activity. The structural characterization results demonstrate that the CuO-MnO2 interface is the active site for CO oxidation in CuO/MnO2 catalysts and CO oxidation over CuO/MnO2 probably follows the interfacial reaction mechanism in which CO chemisorbed on CuO reacts with oxygen species on MnO2 at the CuO-MnO2 interface.

  15. Toward quantitative STM: Scanning tunneling microscopy study of structure and dynamics of adsorbates on transition metal surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Dunphy, J.C.

    1995-05-01

    STM was applied to chemisorbed S layers on Re(000l) and Mo(100) surfaces. As function of coverage on both these surfaces, S orders into several different overlayer structures, which have been studied by dynamic LEED. STM images of all these structures were obtained. Approximate location of S atoms in the structures was determined by inspecting the images, especially the regions containing defects. Results are in agreement with LEED except for the p(2{times}l) overlayer of sulfur on Mo(100). The STM images were compared to calculations made with Electron Scattering Quantum Chemistry (ESQC) theory. Variation of contrast in experimental images is explained as a result of changes in STM tip termination structure. STM image contrast is a result of changes in the interference between different paths for the tunneling electrons. The simplest structure on the Mo(100) surface was used as a model for developing and testing a method of quantitative structure determination with the STM. Experimental STM images acquired under a range of tunneling conditions were compared to theoretical calculations of the images as a function of surface structure to determine the structure which best fit. Results matched within approximately 0.1 Angstroms a LEED structural determination. At lower S coverage, diffusion of S atoms over the Re(0001) surface and the lateral interaction between these atoms were investigated by application of a new image analysis technique. The interaction between the S and a coadsorbed CO layer was also studied, and CO was found to induce compression of the S overlayer. A similar result was found for Au deposited on the sulfur covered Mo(100) surface. The interaction between steps on the Mo surface was found to be influenced by S adsorption and this observation was interpreted with the theory of equilibrium crystal shape. Design of an STM instrument which operates at cryogenic and variable sample temperatures, and its future applications, are described.

  16. Toward quantitative STM: Scanning tunneling microscopy study of structure and dynamics of adsorbates on transition metal surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Dunphy, James Christopher [Univ. of California, Berkeley, CA (United States)

    1995-05-01

    STM was applied to chemisorbed S layers on Re(000l) and Mo(100) surfaces. As function of coverage on both these surfaces, S orders into several different overlayer structures, which have been studied by dynamic LEED. STM images of all these structures were obtained. Approximate location of S atoms in the structures was determined by inspecting the images, especially the regions containing defects. Results are in agreement with LEED except for the p(2xl) overlayer of sulfur on Mo(100). The STM images were compared to calculations made with Electron Scattering Quantum Chemistry (ESQC) theory. Variation of contrast in experimental images is explained as a result of changes in STM tip termination structure. STM image contrast is a result of changes in the interference between different paths for the tunneling electrons. The simplest structure on the Mo(100) surface was used as a model for developing and testing a method of quantitative structure determination with the STM. Experimental STM images acquired under a range of tunneling conditions were compared to theoretical calculations of the images as a function of surface structure to determine the structure which best fit. Results matched within approximately 0.1 Angstroms a LEED structural determination. At lower S coverage, diffusion of S atoms over the Re(0001) surface and the lateral interaction between these atoms were investigated by application of a new image analysis technique. The interaction between the S and a coadsorbed CO layer was also studied, and CO was found to induce compression of the S overlayer. A similar result was found for Au deposited on the sulfur covered Mo(100) surface. The interaction between steps on the Mo surface was found to be influenced by S adsorption and this observation was interpreted with the theory of equilibrium crystal shape. Design of an STM instrument which operates at cryogenic and variable sample temperatures, and its future applications, are described.

  17. Non-dissociative activation of chemisorbed dinitrogen on Ni(110) by co-adsorbed lithium

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Tao, E-mail: tgliu24@gmail.com; Temprano, Israel; Jenkins, Stephen J.; King, David A. [Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW (United Kingdom)

    2013-11-14

    Weakening the intramolecular N–N bond is essential to promote direct hydrogenation of adsorbed N{sub 2} on catalyst surfaces. The interaction of N{sub 2} with Li on Ni(110) surfaces has been investigated. We show that the N–N bond is significantly weakened with increasing Li coverage, evidenced by large redshifts in N–N stretch frequency of up to 380 cm{sup −1} compared to the gas phase. Some increased thermal stability of the most weakened N{sub 2,ads} states is also observed. We speculate that the various observed redshifts in N–N stretch frequency are associated with an enhanced backfilling of the 2π* antibonding orbital of N{sub 2} due to both the Li-induced surface electrostatic field, and the formation of Li{sub x}(N{sub 2}){sub y} surface complexes.

  18. Adhesion of yeasts and bacteria to fluoro-alkylsiloxane layers chemisorbed on silicone rubber

    NARCIS (Netherlands)

    Everaert, EPJM; van der Mei, HC; Busscher, HJ

    1998-01-01

    Indwelling voice prostheses are most often made of silicone rubber. However, the silicone rubber surface attracts huge quantities of adhering yeasts and bacteria and their colonization on the valve side of voice prostheses leads to frequent malfunctioning. On average, indwelling voice prostheses hav

  19. Nanoscopic and redox characterization of engineered horse cytochrome C chemisorbed on a bare gold electrode.

    Science.gov (United States)

    Andolfi, Laura; Caroppi, Paola; Bizzarri, Anna Rita; Piro, Maria Cristina; Sinibaldi, Federica; Ferri, Tommaso; Polticelli, Fabio; Cannistraro, Salvatore; Santucci, Roberto

    2007-06-01

    In this paper, we exploit the potential offered by site-directed mutagenesis to achieve direct adsorption of horse cyt c on a bare gold electrode surface. To this issue, the side chain T102 has been replaced by a cysteine. T102 is close to the surface exposed C-terminal residue (E104), therefore the T102C mutation is expected to generate an exposed cysteine side chain able to facilitate protein binding to the electrode via the sulphur atom (analogously to what observed for yeast iso-1-cyt c). Scanning Tunnelling and Tapping Mode Atomic Force Microscopy measurements show that the T102C mutant stably adsorbs on an Au(111) surface and retains the morphological characteristics of the native form. Cyclic voltammetry reveals that the adsorbed variant is electroactive; however, the heterogeneous electron transfer with the electrode surface is slower than that observed for yeast iso-1-cyt c. We ascribe it to differences in the tertiary architecture of the two proteins, characterized by different flexibility and stability. In particular, the region where the N- and C-terminal helices get in contact (and where the mutation occurs) is analyzed in detail, since the interactions between these two helices are considered crucial for the stability of the overall protein fold.

  20. Studies and correlation among the structural, electrical and gas response properties of aerosol spray deposited self assembled nanocrystalline CuO

    Science.gov (United States)

    Singh, Iqbal; Bedi, R. K.

    2011-06-01

    Nanostructured CuO films have been grown on to the glass substrate by varying the deposition time from 10 to 30 min and substrate temperature from 300 to 400 °C by a simple ultrasonic spray pyrolysis technique, using aqueous a cupric nitrate solution as precursor. The effect of the substrate temperature on the textural, structural, electrical, and gas sensing properties of CuO films was studied and correlated. Thermal analysis of the dried precursor shows the elimination of physisorbed and chemisorbed water. It suggests the formation of CuO phase on substrate at temperature of 300 °C. X-ray diffractograms of the films indicate the formation of polycrystalline monoclinic CuO having monoclinic with crystallite size around 18 nm. The texture coefficient finds the (0 0 2) plane as the preferred orientation in films. The microstrain and dislocation densities have been calculated and found to decreases with increase in substrate temperature. The scanning electron micrographs indicate the formation of trapezium like facet structures on the film surface. AFM analysis shows uniform deposition of the CuO film over the entire substrate surface. Observations reveal that the film deposited at 300 °C show comparatively higher activation energy and appreciable response to ammonia at room temperature. The use of aqueous cupric nitrate as precursor results in the deposition of single phase copper oxide films.

  1. Structural cladding /clad structures:

    DEFF Research Database (Denmark)

    Beim, Anne

    2013-01-01

    tendencies, which can be traced in the use of materials, the structural features and the construction details of building systems in selected architectural works. With a particular focus at heavy constructions made of solid wood and masonry, and light weight constructions made of wooden frame structures...... do we see limitations of tectonic maneuver; how does the performative logic challenge the heavy building constructions....

  2. Correlation between structural and electrical properties of PLD prepared ZnO thin films used as a photodetector material

    Energy Technology Data Exchange (ETDEWEB)

    Triolo, C., E-mail: trioloc@unime.it [Dipartimento di Fisica e di Scienze della Terra, Università degli Studi di Messina, Viale F. Stagno d‘Alcontres 31, 98166, Messina (Italy); Fazio, E.; Neri, F.; Mezzasalma, A.M. [Dipartimento di Fisica e di Scienze della Terra, Università degli Studi di Messina, Viale F. Stagno d‘Alcontres 31, 98166, Messina (Italy); Trusso, S. [CNR-IPCF Istituto per i Processi Chimico-Fisici, Viale F. Stagno d’Alcontres 37, 98158, Messina (Italy); Patanè, S. [Dipartimento di Fisica e di Scienze della Terra, Università degli Studi di Messina, Viale F. Stagno d‘Alcontres 31, 98166, Messina (Italy)

    2015-12-30

    Highlights: • ZnO thin filmswere deposited by pulsed laser ablation from a metallic zinc target in a controlled oxygen atmosphere in shock wave regime. • The samples morphology is tuned, varying the growth temperature. • The transport properties were measured at RT and at 30 K under vacuumboth illuminating the sample by an UV laser and in dark conditions. • All samples are sensible to the UV radiations; the oxygen chemisorbed on the grain surface affects the speed of photoresponse. - Abstract: The electrical transport properties of a set of zinc oxide (ZnO) thin films, prepared by pulsed laser ablation, were investigated at the temperatures of 30 K and 300 K. Information about the structural and morphological properties of the samples were obtained by means of atomic force microscopy (AFM) and X-ray diffraction (XRD). A significant variation in the surface morphology and photoresponse characteristics of the ZnO thin films were observed as a function of the deposition temperature. Upon increasing the deposition temperature, the surface topography changes from a more fine-grained to a more coarse-grained structure, showing a tetragonal wurtzite crystalline structure. Time resolved photocurrent measurements showed significantly variations as function of the observed samples morphologies. A photocurrent value of about three order of magnitude larger is observed for samples showing a more coarse-grained structure with respect to the fine-grained ones. Such a result is interpreted as due to the contributions of both “bulk” and defect centers that affect the conduction mechanisms and influence both the photoconductivity values and the photoresponse speed. The observed decay times are very long with respect to films grown by other techniques, due to the reduction of the surface localized centers of defect available for recombination. In this context, the sample morphology appears to be a key parameter to control the photoconductivity in ZnO thin films.

  3. The structure and reactivity of adsorbates on stepped Rh and Pt surfaces investigated by LEED, HREELS, TPD, XPS and STM

    Energy Technology Data Exchange (ETDEWEB)

    Batteas, J.D. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry]|[Lawrence Berkeley Lab., CA (United States). Materials Science Div.

    1995-06-01

    Defects on surfaces such as steps play an important role in surface chemistry. In order to obtain an understanding of the influence of steps in surface chemical reactions, the structure and reactivity of small molecules (O{sub 2}, CO, H{sub 2}S, and C{sub 2}H{sub 4}) on atomically stepped surfaces of RH and Pt have been investigated. The detailed structures of CO and oxygen bonded to the Rh(110) surface were determined. The CO molecules bond near the short bridge sites with the CO molecular axis tilted approximately 24{degree} from the surface normal. Oxygen atoms are bound asymmetrically in the 3-fold fcc hollow-sites to the (111) facets of the steps. The interactions of CO and oxygen on the Rh(311) surface were examined. The reaction of CO with the ordered phases of O shows two distinct reaction channels, a low temperature reaction limited channel (200 K) and a high temperature diffusion limited channel (350 K). Models of the reaction geometry and dynamics are proposed. The thermal decomposition of ethylene was examined on the Rh(311) surface. The stable decomposition species (C{sub 2}H, CH and C{sub 2}) are formed near 300 K, approximately 100 K lower on the stepped Rh(311) than on the flatter Rh(111) surface. The formation of these species at lower temperatures is attributed to the stepped nature of the surface. Finally, in situ STM was used to examine surface structural changes of a stepped Pt(111) crystal under coadsorption of sulfur and CO. This is the first direct evidence for a new mechanism by which a surface covered with an unreactive, strongly chemisorbed overlayer can form new sites, for bonding and reactions to occur, by massive surface restructuring at the step edges. This new surface phenomenon answers some of the puzzles of metal surface catalysis and its implications are described. 278 refs.

  4. Organic/metal interfaces. Electronic and structural properties

    Energy Technology Data Exchange (ETDEWEB)

    Duhm, Steffen

    2008-07-17

    This work addresses several important topics of the field of organic electronics. The focus lies on organic/metal interfaces, which exist in all organic electronic devices. Physical properties of such interfaces are crucial for device performance. Four main topics have been covered: (i) the impact of molecular orientation on the energy levels, (ii) energy level tuning with strong electron acceptors, (iii) the role of thermodynamic equilibrium at organic/ organic homo-interfaces and (iv) the correlation of interfacial electronic structure and bonding distance. To address these issues a broad experimental approach was necessary: mainly ultraviolet photoelectron spectroscopy was used, supported by X-ray photoelectron spectroscopy, metastable atom electron spectroscopy, X-ray diffraction and X-ray standing waves, to examine vacuum sublimed thin films of conjugated organic molecules (COMs) in ultrahigh vacuum. (i) A novel approach is presented to explain the phenomenon that the ionization energy in molecular assemblies is orientation dependent. It is demonstrated that this is due to a macroscopic impact of intramolecular dipoles on the ionization energy in molecular assemblies. Furthermore, the correlation of molecular orientation and conformation has been studied in detail for COMs on various substrates. (ii) A new approach was developed to tune hole injection barriers ({delta}{sub h}) at organic/metal interfaces by adsorbing a (sub-) monolayer of an organic electron acceptor on the metal electrode. Charge transfer from the metal to the acceptor leads to a chemisorbed layer, which reduces {delta}{sub h} to the COM overlayer. This concept was tested with three acceptors and a lowering of {delta}{sub h} of up to 1.2 eV could be observed. (iii) A transition from vacuum-level alignment to molecular level pinning at the homo-interface between a lying monolayer and standing multilayers of a COM was observed, which depended on the amount of a pre-deposited acceptor. The

  5. Structural cladding /clad structures

    DEFF Research Database (Denmark)

    Beim, Anne

    2012-01-01

    of materials, the structural features and the construction details of building systems in selected architectural works. With a particular focus at heavy constructions made of solid wood and masonry, and light weight constructions made of wooden frame structures and steel profiles, it is the intention......, to ask for more restrictive building codes. As an example, in Denmark there are series of increasing demands in the current building legislations that are focused at enhancing the energy performance of buildings, which consequently foster rigid insulation standards and ask for improvement of air...... with at a global or national level. How to bring the knowledge, material evidence and cultural dimension, which exist in traditional building practices into play with present day hardcore technocratic demands in the construction industry and in building construction, seem be With point of departure...

  6. Structural cladding /clad structures

    DEFF Research Database (Denmark)

    Beim, Anne

    2012-01-01

    to analyze, compare, and discuss how these various construction solutions point out strategies for development based on fundamentally different mindsets. The research questions address the following issues: How to learn from traditional construction principles: When do we see limitations of tectonic maneuver...... in the challenges previously described this paper forms a ‘tectonic enquiry’ into contemporary building practice by looking at specific performative tendencies, which can be traced in the structural features and the construction details of selected building systems and architectural works. With a particular focus...... at heavy constructions made of solid wood and masonry, and light weight constructions made of wooden frame structures and steel profiles, it is the intention to analyze, compare, and discuss how these various construction solu-tions point out strategies for development based on fundamentally different...

  7. Distribution Structures

    NARCIS (Netherlands)

    Friedrich, H.; Tavasszy, L.A.; Davydenko, I.

    2013-01-01

    Distribution structures are important elements of the freight transportation system. Goods are routed via warehouses on their way from production to consumption. This chapter discusses drivers behind these structures, logistics decisions connected to distribution structures on the micro level, and

  8. Probing the molecular structures of plasma-damaged and surface-repaired low-k dielectrics.

    Science.gov (United States)

    Zhang, Xiaoxian; Myers, John N; Lin, Qinghuang; Bielefeld, Jeffery D; Chen, Zhan

    2015-10-21

    Fully understanding the effect and the molecular mechanisms of plasma damage and silylation repair on low dielectric constant (low-k) materials is essential to the design of low-k dielectrics with defined properties and the integration of low-k dielectrics into advanced interconnects of modern electronics. Here, analytical techniques including sum frequency generation vibrational spectroscopy (SFG), Fourier transform infrared spectroscopy (FTIR), contact angle goniometry (CA) and X-ray photoelectron spectroscopy (XPS) have been employed to provide a comprehensive characterization of the surface and bulk structure changes of poly(methyl)silsesquioxane (PMSQ) low-k thin films before and after O2 plasma treatment and silylation repair. O2 plasma treatment altered drastically both the molecular structures and water structures at the surfaces of the PMSQ film while no bulk structural change was detected. For example, ∼34% Si-CH3 groups were removed from the PMSQ surface, and the Si-CH3 groups at the film surface tilted toward the surface after the O2 plasma treatment. The oxidation by the O2 plasma made the PMSQ film surface more hydrophilic and thus enhanced the water adsorption at the film surface. Both strongly and weakly hydrogen bonded water were detected at the plasma-damaged film surface during exposure to water with the former being the dominate component. It is postulated that this enhancement of both chemisorbed and physisorbed water after the O2 plasma treatment leads to the degradation of low-k properties and reliability. The degradation of the PMSQ low-k film can be recovered by repairing the plasma-damaged surface using a silylation reaction. The silylation method, however, cannot fully recover the plasma induced damage at the PMSQ film surface as evidenced by the existence of hydrophilic groups, including C-O/C[double bond, length as m-dash]O and residual Si-OH groups. This work provides a molecular level picture on the surface structural changes of low

  9. CO adsorption and dissociation on Pt(111) and Ni(111) surfaces

    DEFF Research Database (Denmark)

    Morikawa, Y.; Mortensen, Jens Jørgen; Hammer, Bjørk

    1997-01-01

    CO adsorption and dissociation processes have been studied using first-principles total energy and force calculations. The adsorption energies, atomic structures and vibrational modes of molecularly chemisorbed states are well reproduced in the present calculations. We have examined several...

  10. STRUCTURAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20140014Deng Lin(College of Resources and Environment,Southwest Petroleum University,Chengdu 610500,China)Structural Geometry and Structural Kinematics of the Jiulongshan Structure in the North Longmenshan Mountains(Acta Geologica Sichuan,ISSN1006-0995,CN51-1273/P,33(1),2013,p.1-2,11,1illus.,9refs.)Key words:plate geometry,structural analysis,Longmenshan Fault Zone

  11. Sentence Structure

    CERN Document Server

    Fabb, Nigel

    2012-01-01

    Sentence Structure:introduces the evidence for sentence structure and reveals its purposeis based on a problem-solving approach to languageteaches the reader how to identify word classes, such as noun, preposition and demonstrativeuses simple tree structures to analyse sentencescontains numerous exercises to encourage practical skills of sentence analysisincludes a database and exercises that compare the structure of English with other languages.The second edition of Sentence Structure has been revised and updated throughout and includes new material on tense, aspect, modality and the verb phr

  12. Effect of oxygen on the production of abnormally high heats of interaction with hydrogen chemisorbed on gold

    Energy Technology Data Exchange (ETDEWEB)

    Groszek, A.J., E-mail: info@microscal.com [Microscal Limited, 79 Southern Row, London W10 5AL (United Kingdom); Institute of Catalysis and Surface Chemistry, Polish Academy of Science, ul.Niezapominajek 8, Krakow 30-239 (Poland); Lalik, E. [Institute of Catalysis and Surface Chemistry, Polish Academy of Science, ul.Niezapominajek 8, Krakow 30-239 (Poland)

    2011-02-01

    Abnormally high heats, exceeding 1600 kJ/mol (16 eV) per molecular oxygen, are generated by interaction of the oxygen with the hydrogen adsorbed on gold surfaces at 125 deg. C. The highest heats were observed during the interactions of fine gold particles supported on titanium oxide, approaching 1700 kJ/mol for three consecutive 100 nmol pulses of O{sub 2} interacting with the adsorbed hydrogen atoms. The heats rapidly decrease after the hydrogen is consumed. It was also observed that the interactions of the gold particles with pure oxygen in the presence of noble gases, such as argon and helium, produced the heats markedly higher than those observed in the absence of noble gases. The abnormally high heats revealed by this work reach values from 3.5 to 6.1 times higher than the heats of formation of gaseous water from molecular hydrogen and oxygen.

  13. Fen (n=1–6) clusters chemisorbed on vacancy defects in graphene: Stability, spin-dipole moment, and magnetic anisotropy

    KAUST Repository

    Haldar, Soumyajyoti

    2014-05-09

    In this work, we have studied the chemical and magnetic interactions of Fen (n=1–6) clusters with vacancy defects (monovacancy to correlated vacancies with six missing C atoms) in a graphene sheet by ab initio density functional calculations combined with Hubbard U corrections for correlated Fe-d electrons. It is found that the vacancy formation energies are lowered in the presence of Fe, indicating an easier destruction of the graphene sheet. Due to strong chemical interactions between Fe clusters and vacancies, a complex distribution of magnetic moments appear on the distorted Fe clusters which results in reduced averaged magnetic moments compared to the free clusters. In addition to that, we have calculated spin-dipole moments and magnetic anisotropy energies. The calculated spin-dipole moments arising from anisotropic spin density distributions vary between positive and negative values, yielding increased or decreased effective moments. Depending on the cluster geometry, the easy axis of magnetization of the Fe clusters shows in-plane or out-of-plane behavior.

  14. High-Resolution Distance Dependence Study of Surface-Enhanced Raman Scattering Enabled by Atomic Layer Deposition

    Science.gov (United States)

    2016-06-15

    range SERS distance dependence should make it possible to detect chemisorbed surface species located as far as ∼3 nm from the AgFON substrate and will...calculations. Based on our results, we anticipate that the long-range distance dependence of SERS should enable detection of chemisorbed species located as far...structural information provided by operando SERS , especially the detection of low frequency metal−oxygen vibrations, will lead to an improved mechanistic

  15. Coilgun structures

    Science.gov (United States)

    Andrews, J. A.

    1993-01-01

    Recent research into the optimal design of 'coilgun' structures has indicated that structural requirements are strong functions of launcher classification as well as acceleration mode. Attention is presently given to both closed-form and numerical analytical techniques for coaxial DC accelerator (DCA) structural-design calculations. The DCA is a multistage pulsed-induction launcher that makes extensive use of composite materials technology; measured plastic deformations of the armature after a high energy experiment are compared to FEM analysis predictions.

  16. Effect of the thickness reduction on the structural, surface and magnetic properties of α-Fe{sub 2}O{sub 3} thin films

    Energy Technology Data Exchange (ETDEWEB)

    Aragón, Fermin F.H., E-mail: fherrera@fis.unb.br [Núcleo de Física Aplicada, Instituto de Física, Universidade de Brasília, Brasília, DF 70910-900 (Brazil); Centro de Desenvolvimento da Tecnologia Nuclear, CDTN, 31270-901 Belo Horizonte, MG (Brazil); Ardisson, José D. [Centro de Desenvolvimento da Tecnologia Nuclear, CDTN, 31270-901 Belo Horizonte, MG (Brazil); Aquino, Juan C.R. [Núcleo de Física Aplicada, Instituto de Física, Universidade de Brasília, Brasília, DF 70910-900 (Brazil); Gonzalez, Ismael; Macedo, Waldemar A.A. [Centro de Desenvolvimento da Tecnologia Nuclear, CDTN, 31270-901 Belo Horizonte, MG (Brazil); Coaquira, José A.H.; Mantilla, John; Silva, Sebastião W. da; Morais, Paulo C. [Núcleo de Física Aplicada, Instituto de Física, Universidade de Brasília, Brasília, DF 70910-900 (Brazil)

    2016-05-31

    Hematite (α-Fe{sub 2}O{sub 3}) polycrystalline thin films of different thicknesses were produced by thermal oxidation in air atmosphere from Fe metallic thin-films deposited by radio frequency (RF) sputtering technique. X-ray diffraction (XRD) patterns confirm the formation of hematite phase in all samples and indicate that the mean grain size decreases as the film thickness becomes thinner. Conversion electron Mössbauer spectroscopy (CEMS) spectra at room temperature show magnetic splitting (six line patterns). It is determined that the resonance peaks become broader and asymmetric as the film thickness decreases. This finding was associated with the structural disorder introduced by the thickness reduction. Magnetization as a function of the magnetic field curve obtained at 300 K shows the presence of a weak-ferromagnetic contribution, which was assigned to the large density of decompensated spins at the films surface. From the magnetization vs. temperature curves it has been determined that the Morin transition temperature (T{sub M}) is shifted from ~ 240 K to ~ 196 K, meanwhile it becomes more broadened as the film thickness decreases. X-ray photoelectron spectroscopy (XPS) measurements show the presence of Fe{sup 2+} ions coexisting with Fe{sup 3+} ions whose population increases as the film becomes thinner. The density of chemisorbed oxygen increases as the film thickness is reduced in agreement with the results obtained from the other measurements in this work. - Highlights: • Hematite thin films with different thickness were deposited by RF sputtering technique. • X-ray diffraction patterns confirm the formation of hematite phase in all samples. • Hysteresis curve at 300 K shows the presence of a weak-ferromagnetic phase. • XPS show the presence of Fe{sup 2+} ions coexisting with Fe{sup 3+} ions.

  17. Effect of peptide secondary structure on adsorption and adsorbed film properties on end-grafted polyethylene oxide layers.

    Science.gov (United States)

    Binazadeh, M; Zeng, H; Unsworth, L D

    2014-01-01

    Poly-l-lysine (PLL), in α-helix or β-sheet configuration, was used as a model peptide for investigating the effect of secondary structures on adsorption events to poly(ethylene oxide) (PEO) modified surfaces formed using θ solvents. Circular dichroism results showed that the secondary structure of PLL persisted upon adsorption to Au and PEO modified Au surfaces. Quartz crystal microbalance with dissipation (QCM-D) was used to characterize the chemisorbed PEO layer in different solvents (θ and good solvents), as well as the sequential adsorption of PLL in different secondary structures (α-helix or β-sheet). QCM-D results suggest that chemisorption of PEO 750 and 2000 from θ solutions led to brushes 3.8 ± 0.1 and 4.5 ± 0.1 nm thick with layer viscosities of 9.2 ± 0.8 and 4.8 ± 0.5 cP, respectively. The average number of H2O per ethylene oxides, while in θ solvent, was determined as ~0.9 and ~1.2 for the PEO 750 and 2000 layers, respectively. Upon immersion in good solvent (as used for PLL adsorption experiments), the number of H2O per ethylene oxides increased to ~1.5 and ~2.0 for PEO 750 and 2000 films, respectively. PLL adsorbed masses for α-helix and β-sheet on Au sensors was 231 ± 5 and 1087 ± 14 ng cm(-2), with layer viscosities of 2.3 ± 0.1 and 1.2 ± 0.1 cP, respectively; suggesting that the α-helix layer was more rigid, despite a smaller adsorbed mass, than that of β-sheet layers. The PEO 750 layer reduced PLL adsorbed amounts to ~10 and 12% of that on Au for α-helices and β-sheets respectively. The PLL adsorbed mass to PEO 2000 layers dropped to ~12% and 4% of that on Au, for α-helix and β-sheet respectively. No significant differences existed for the viscosities of adsorbed α-helix and β-sheet PLL on PEO surfaces. These results provide new insights into the fundamental understanding of the effects of secondary structures of peptides and proteins on their surface adsorption.

  18. Protein Structure

    Science.gov (United States)

    Asmus, Elaine Garbarino

    2007-01-01

    Individual students model specific amino acids and then, through dehydration synthesis, a class of students models a protein. The students clearly learn amino acid structure, primary, secondary, tertiary, and quaternary structure in proteins and the nature of the bonds maintaining a protein's shape. This activity is fun, concrete, inexpensive and…

  19. Tau structures

    Directory of Open Access Journals (Sweden)

    Jesus Avila

    2016-11-01

    Full Text Available Tau is a microtubule-associated protein that plays an important role in axonal stabilization, neuronal development, and neuronal polarity. In this review, we focus on the primary, secondary, tertiary and quaternary tau structures. We describe the structure of tau from its specific residues until its conformation in dimers, oligomers and larger polymers in physiological and pathological situations.

  20. Organisational Structure

    Science.gov (United States)

    National Centre for Vocational Education Research (NCVER), 2006

    2006-01-01

    An understanding of organisational structure can provide guidance for organisations that want to change and innovate. Many writers agree that this understanding allows organisations to shape how their work is done to ultimately achieve their business goals--and that too often structure is given little consideration in business strategy and…

  1. Vcsel structure

    DEFF Research Database (Denmark)

    2015-01-01

    The invention relates to a VCSEL structure based on a novel grating reflector. The grating reflector comprises a grating layer with a contiguous core grating region having a grating structure, wherein an index of refraction of high-index sections of the grating structure is at least 2.......5, and wherein an index of refraction of low-index sections of the grating structure is less than 2. The core grating region defines a projection in a direction normal to the grating layer. The grating reflector further comprises a cap layer abutting the grating layer, and an index of refraction of the cap layer...... the projection of the core grating region, the grating layer is also abutted by a second low-index layer and/or by air, an index of refraction of the second low-index layer or air being less than 2. The VCSEL structure furthermore comprises a first reflector and an active region for providing a cavity...

  2. Structural Behaviour of Reciprocal Structures

    DEFF Research Database (Denmark)

    Parigi, Dario; Kirkegaard, Poul Henning

    2013-01-01

    The present paper focuses on the comparison of several two-dimensional and three-dimensional reciprocal configurations. The goal of such comparison is to analyse the structural behaviour when changing the geometric parameters used to describe the geometry of reciprocal structures....

  3. Structured light in structured media

    Science.gov (United States)

    Zeng, Jinwei

    The objective of this dissertation is to investigate fundamental optical phenomena at the interface between two emerging fields of modern optics - structured light and micro/nano-structured optical materials. Until recently, these fields were developing in parallel yet independently. A majority of researchers in the field of metamaterials and photonic crystals considered "simple" linearly or circularly polarized light or Gaussian beam propagation in "structured" materials with properties not found in nature. However, in addition to conventional polarization states, light beams can be radially or azimuthally polarized and carry orbital angular momentum (OAM). A fascinating example of a beam carrying OAM is the optical vortex---a donut-shaped beam with a helical phase front. Similarly, the structured light community largely focused on complex light propagation in rather simple homogeneous, isotropic, transparent media. In this dissertation, we explore fundamentals and applications of light-matter interactions that involve both complex light and complex media. The central question that we aim to tackle is: How may the synergy of these two fields lead to a breakthrough in modern photonics? Structured materials, including metamaterials and photonic bandgap structures, realize unprecedented control over light propagation and design flexibility. They can enable new optical properties and functionalities, including new regimes of wave guiding, negative index of refraction, magnetism at optical frequencies, and subwavelength imaging to name a few. We demonstrate how nearly unlimited possibilities in engineering the properties of structured media can be used for generation and manipulation of structured light. Also, we show how the unique properties of structured light could be used for characterization of structured media.

  4. Hydraulic Structures

    Data.gov (United States)

    Department of Homeland Security — This table is required whenever hydraulic structures are shown in the flood profile. It is also required if levees are shown on the FIRM, channels containing the...

  5. Hydraulic structures

    CERN Document Server

    Chen, Sheng-Hong

    2015-01-01

    This book discusses in detail the planning, design, construction and management of hydraulic structures, covering dams, spillways, tunnels, cut slopes, sluices, water intake and measuring works, ship locks and lifts, as well as fish ways. Particular attention is paid to considerations concerning the environment, hydrology, geology and materials etc. in the planning and design of hydraulic projects. It also considers the type selection, profile configuration, stress/stability calibration and engineering countermeasures, flood releasing arrangements and scouring protection, operation and maintenance etc. for a variety of specific hydraulic structures. The book is primarily intended for engineers, undergraduate and graduate students in the field of civil and hydraulic engineering who are faced with the challenges of extending our understanding of hydraulic structures ranging from traditional to groundbreaking, as well as designing, constructing and managing safe, durable hydraulic structures that are economical ...

  6. Nuclear Structure

    Science.gov (United States)

    Gargano, Angela

    2003-04-01

    An account of recent studies in the field of theoretical nuclear structure is reported. These studies concern essentially research activities performed under the Italian project "Fisica Teorica del Nucleo e dei Sistemi a Molti Corpi". Special attention is addressed to results obtained during the last two years as regards the development of new many-body techniques as well as the interpretation of new experimental aspects of nuclear structure.

  7. Foundation Structure

    OpenAIRE

    Schakenda, Bruno; Nielsen, Søren Andreas; Ibsen, Lars Bo

    2009-01-01

    Method of installing a bucket foundation structure comprising one, two, three or more skirts, into soils in a controlled manner. The method comprises two stages: a first stage being a design phase and the second stage being an installation phase. In the first stage, design parameters are determined relating to the loads on the finished foundation structure; soil profile on the location; allowable installation tolerances, which parameters are used to estimate the minimum diameter and length of...

  8. Surface Coverage and Structure of Mixed DNA/Alkylthiol Monolayers on Gold: Characterization by XPS, NEXAFS, and Fluorescence Intensity Measurements

    Energy Technology Data Exchange (ETDEWEB)

    Lee,C.; Gong, P.; Harbers, G.; Grainger, D.; Castner, D.; Gamble, L.

    2006-01-01

    Self-assembly of thiol-terminated single-stranded DNA (HS-ssDNA) on gold has served as an important model system for DNA immobilization at surfaces. Here, we report a detailed study of the surface composition and structure of mixed self-assembled DNA monolayers containing a short alkylthiol surface diluent [11-mercapto-1-undecanol (MCU)] on gold supports. These mixed DNA monolayers were studied with X-ray photoelectron spectroscopy (XPS), near-edge X-ray absorption fine structure spectroscopy (NEXAFS), and fluorescence intensity measurements. XPS results on sequentially adsorbed DNA/MCU monolayers on gold indicated that adsorbed MCU molecules first incorporate into the HS-ssDNA monolayer and, upon longer MCU exposures, displace adsorbed HS-ssDNA molecules from the surface. Thus, HS-ssDNA surface coverage steadily decreased with MCU exposure time. Polarization-dependent NEXAFS and fluorescence results both show changes in signals consistent with changes in DNA orientation after only 30 min of MCU exposure. NEXAFS polarization dependence (followed by monitoring the N 1s{yields}{pi}* transition) of the mixed DNA monolayers indicated that the DNA nucleotide base ring structures are oriented more parallel to the gold surface compared to DNA bases in pure HS-ssDNA monolayers. This indicates that HS-ssDNA oligomers reorient toward a more-upright position upon MCU incorporation. Fluorescence intensity results using end-labeled DNA probes on gold show little observable fluorescence on pure HS-ssDNA monolayers, likely due to substrate quenching effects between the fluorophore and the gold. MCU diluent incorporation into HS-ssDNA monolayers initially increases DNA fluorescence signal by densifying the chemisorbed monolayer, prompting an upright orientation of the DNA, and moving the terminal fluorophore away from the substrate. Immobilized DNA probe density and DNA target hybridization in these mixed DNA monolayers, as well as effects of MCU diluent on DNA hybridization in

  9. Surface Coverage and Structure of Mixed DNA/Alkylthiol Monolayers on Gold: Characterization by XPS, NEXAFS, and Fluorescence Intensity Measurements

    Science.gov (United States)

    Lee, Chi-Ying; Gong, Ping; Harbers, Gregory M.; Grainger, David W.; Castner, David G.; Gamble, Lara J.

    2006-01-01

    Self-assembly of thiol-terminated single-stranded DNA (HS-ssDNA) on gold has served as an important model system for DNA immobilization at surfaces. Here, we report a detailed study of the surface composition and structure of mixed self-assembled DNA monolayers containing a short alkylthiol surface diluent [11-mercapto-1-undecanol (MCU)] on gold supports. These mixed DNA monolayers were studied with X-ray photoelectron spectroscopy (XPS), near-edge X-ray absorption fine structure spectroscopy (NEXAFS), and fluorescence intensity measurements. XPS results on sequentially adsorbed DNA/MCU monolayers on gold indicated that adsorbed MCU molecules first incorporate into the HS-ssDNA monolayer and, upon longer MCU exposures, displace adsorbed HS-ssDNA molecules from the surface. Thus, HS-ssDNA surface coverage steadily decreased with MCU exposure time. Polarization-dependent NEXAFS and fluorescence results both show changes in signals consistent with changes in DNA orientation after only 30 min of MCU exposure. NEXAFS polarization dependence (followed by monitoring the N 1s → π* transition) of the mixed DNA monolayers indicated that the DNA nucleotide base ring structures are oriented more parallel to the gold surface compared to DNA bases in pure HS-ssDNA monolayers. This indicates that HS-ssDNA oligomers reorient toward a more-upright position upon MCU incorporation. Fluorescence intensity results using end-labeled DNA probes on gold show little observable fluorescence on pure HS-ssDNA monolayers, likely due to substrate quenching effects between the fluorophore and the gold. MCU diluent incorporation into HS-ssDNA monolayers initially increases DNA fluorescence signal by densifying the chemisorbed monolayer, prompting an upright orientation of the DNA, and moving the terminal fluorophore away from the substrate. Immobilized DNA probe density and DNA target hybridization in these mixed DNA monolayers, as well as effects of MCU diluent on DNA hybridization in complex

  10. Electronic structure and binding geometry of tetraphenylporphyrin-derived molecules adsorbed on metal and metal oxide surfaces

    Science.gov (United States)

    Coh, Senia

    Tetraphenylporphyrin (TPP)-derived molecules have been studied extensively as efficient photosensitizers when chemisorbed on the metal oxide substrates in dye-sensitized solar cells. Still, many fundamental electronic properties of the dye/oxide interface are not understood and need careful consideration. In this thesis we present a comprehensive study of the electronic structure, energy level alignment and the adsorption geometry of the TPP-derived dye molecules adsorbed on TiO2(110), ZnO(1120) and Ag(100) single crystal surfaces using ultra-high vacuum (UHV) based surface sensitive techniques. The alignment of the molecular energy levels with respect to the TiO 2 and ZnO band edges for all TPP-derived molecules we studied was found to be insensitive to either the nature of the functional groups located on the phenyl rings, presence of zinc as a central metal ion and different binding geometry of the molecules. Binding geometry, molecule-molecule interaction and the aggregation effects in the adsorbed layer, that were observed in the UV-visible spectra of the molecules adsorbed on ZnO substrate were not observed in the ultraviolet photoemission (UPS) and inverse photoemission (IPS) spectra of the occupied and unoccupied molecular states. Using near edge X-ray absorption fine structure (NEXAFS) and scanning tunneling microscopy (STM), binding geometry of the two representative TPP-derivatives was directly determined to be upright, with the porphyrin ring under large angle with respect to the surface for the p-ZnTCPP molecules and with the porphyrin ring parallel to the surface for the m-ZnTCPP molecules. We observe that the energies and the energy level alignment of the ZnTPP molecular levels measured in UPS and IPS depend on the substrate on which the molecules are adsorbed (Ag(100) or TiO2(110) single crystal surfaces). The differences are attributed to different charge screening properties of these two materials. Image charges created in the substrates during

  11. Surface coverage and structure of mixed DNA/alkylthiol monolayers on gold: characterization by XPS, NEXAFS, and fluorescence intensity measurements.

    Science.gov (United States)

    Lee, Chi-Ying; Gong, Ping; Harbers, Gregory M; Grainger, David W; Castner, David G; Gamble, Lara J

    2006-05-15

    Self-assembly of thiol-terminated single-stranded DNA (HS-ssDNA) on gold has served as an important model system for DNA immobilization at surfaces. Here, we report a detailed study of the surface composition and structure of mixed self-assembled DNA monolayers containing a short alkylthiol surface diluent [11-mercapto-1-undecanol (MCU)] on gold supports. These mixed DNA monolayers were studied with X-ray photoelectron spectroscopy (XPS), near-edge X-ray absorption fine structure spectroscopy (NEXAFS), and fluorescence intensity measurements. XPS results on sequentially adsorbed DNA/MCU monolayers on gold indicated that adsorbed MCU molecules first incorporate into the HS-ssDNA monolayer and, upon longer MCU exposures, displace adsorbed HS-ssDNA molecules from the surface. Thus, HS-ssDNA surface coverage steadily decreased with MCU exposure time. Polarization-dependent NEXAFS and fluorescence results both show changes in signals consistent with changes in DNA orientation after only 30 min of MCU exposure. NEXAFS polarization dependence (followed by monitoring the N 1s --> pi* transition) of the mixed DNA monolayers indicated that the DNA nucleotide base ring structures are oriented more parallel to the gold surface compared to DNA bases in pure HS-ssDNA monolayers. This indicates that HS-ssDNA oligomers reorient toward a more-upright position upon MCU incorporation. Fluorescence intensity results using end-labeled DNA probes on gold show little observable fluorescence on pure HS-ssDNA monolayers, likely due to substrate quenching effects between the fluorophore and the gold. MCU diluent incorporation into HS-ssDNA monolayers initially increases DNA fluorescence signal by densifying the chemisorbed monolayer, prompting an upright orientation of the DNA, and moving the terminal fluorophore away from the substrate. Immobilized DNA probe density and DNA target hybridization in these mixed DNA monolayers, as well as effects of MCU diluent on DNA hybridization in complex

  12. Eu{sup 3+} doped yttrium oxysulfide quantum structures-structural, optical and electronic properties

    Energy Technology Data Exchange (ETDEWEB)

    Thirumalai, J.; Chandramohan, R. [Sree Sevugan Annamalai College, Department of Physics (India)], E-mail: chandramohan_rm@rediffmail.com; Sekar, M. [Indira Gandhi Centre for Atomic Research, Advanced Materials Laboratory, Materials Science Division (India); Rajachandrasekar, R. [Department of Atomic Energy, CAR Project, BARC F-Facilities (India)

    2008-03-15

    Small particles of trivalent europium doped yttrium oxysulfide nanocrystals ({phi} {approx} 7 nm) were synthesized using sol-gel polymer thermolysis. The nanocrystals show significant change in the excitation bands corresponding to fundamental absorption and charge transfer absorption bands. The optical spectra essentially comprise of two parts: fundamental absorption ({approx}260 nm) and Eu{sup 3+}-X{sup 2-} ligand (O{sup 2-}/S{sup 2-}) charge transfer ({approx}290 nm) bands. They show significant blue shifts (0.24-0.30 eV), respectively, with respect to the bulk counterpart. These may be explained by considering possible size dependent changes associated with quantum confinement effect in this large bandgap semiconductor system. FT-IR spectra revealed the difference in chemisorbed species between bulk and nanocrystalline samples. The results of the solid-state photo-induced electrical impedance spectroscopy studies are reported.

  13. Tension Structure

    Science.gov (United States)

    1978-01-01

    The fabric structure pictured is the Campus Center of La Verne College, La Verne, California. Unlike the facilities shown on the preceding pages, it is not air-supported. It is a "tension structure," its multi-coned fabric membrane supported by a network of cables attached to steel columns which function like circus tent poles. The spider-web in the accompanying photo is a computer graph of the tension pattern. The designers, Geiger-Berger Associates PC, of New York City, conducted lengthy computer analysis to determine the the best placement of columns and cables. The firm also served as structural engineering consultant on the Pontiac Silverdome and a number of other large fabric structures. Built by Birdair Structures, Inc., Buffalo, New York, the La Verne Campus Center was the first permanent facility in the United States enclosed by the space-spinoff fabric made of Owens-Corning Beta fiber glass coated with Du Pont Teflon TFE. The flexible design permits rearrangement of the interior to accommodate athletic events, student activities, theatrical productions and other recreational programs. Use of fabric covering reduced building cost 30 percent below conventional construction.

  14. Adenovirus structure.

    Science.gov (United States)

    Rux, John J; Burnett, Roger M

    2004-12-01

    Structural studies continue to play an essential role as the focus of adenovirus research shifts in emphasis from basic biology to adenovirus-based vector technologies. A crucial step in developing novel therapeutics for gene replacement, cancer, and vaccines is often to modify the virion. Such engineered changes are designed to retarget the virus, or to reduce the immunological responses to infection. These efforts are far more effective when they are based on detailed structural knowledge. This minireview provides a brief summary of the wealth of information that has been obtained from the combined application of X-ray crystallography and electron microscopy. This knowledge now includes a good working model for the architectural organization of the virion, and atomic resolution molecular structures for all the major capsid proteins, hexon, penton, and fiber. We highlight new developments, which include the structure of the penton base and the discovery that adenovirus has several relatives. We sketch how the structural information can be used to engineer novel virions and conclude with the prospects for future progress.

  15. Data Structures

    DEFF Research Database (Denmark)

    Davoodi, Pooya

    weight in a query path; (3) the range diameter problem: given a point set in the plane, find two points that are farthest away in a query rectangle. These and similar problems arise in various applications including document retrieval, genome sequence analysis, OLAP data cubes, network flows, shape......-fitting, and clustering. The three mentioned problems are considered for either static inputs or dynamic inputs. In the static setting, we investigate the space-efficiency of data structures, which is an important aspect in massive data algorithmics. We provide lower bounds on the trade-off between the query time......-dimensional range minimum queries. In the dynamic setting, we present data structures for the path minima problem that support optimal query time for various types of update operations. One of the results presents a comparison-based data structure which answers path minima queries in sub-logarithmic time...

  16. Fireplace structure

    Energy Technology Data Exchange (ETDEWEB)

    Faehling, F.L.; Billmeyer, T.F.; Peterson, S.O.

    1984-09-18

    A fireplace having one or more conduits for directing outside combustion air into the firebox with a movable member adjacent a conduit outlet for normally closing said conduit and having either open or closed positions dependent upon the existence of a pressure difference across said member. A pressure difference caused by a fire in the firebox results in a higher pressure on the side of the member opposite the firebox to cause the member to move to open position. Operating structure is provided for positively closing the member and with the operating structure being operable from the front of the fireplace.

  17. Lightweight Structures.

    Science.gov (United States)

    Shaver and Co., Michigan City, IN.

    One of the newest and most promising developments in architecture has been the use of lightweight structures for encapsulating space. Using this new technology, builders can enclose large and small areas at a fraction of the cost of conventional construction and at the same time provide interior space that is totally flexible. This brochure shows…

  18. Structural parsing

    NARCIS (Netherlands)

    Hoede, C.; Zhang, Lei

    2000-01-01

    Parsing is an essential part of natural language processing. In this paper, structural parsing, which is based on the theory of knowledge graphs, is introduced. Under consideration of the semantic and syntactic features of natural language, both semantic and syntactic word graphs are formed. Grammar

  19. Coastal Structures

    DEFF Research Database (Denmark)

    Oumeraci, H.; Burcharth, H. F.; Rouck, J. De;

    1995-01-01

    The paper attempts to present an overview of five research projects supported by the Commission of the European Communities, Directorate General XII, under the MAST 2- Programme (Marine Sciences and Technology), with the overall objective of contributing to the development of improved rational me...... methods for the design of coastal structures....

  20. Organizational structure

    NARCIS (Netherlands)

    Hendriks, P.H.J.

    2011-01-01

    For many decades, organization scientists have paid considerable attention to the link between knowledge and organization structure. An early contributor to these discussions was Max Weber (1922), who elaborated his concepts of professional bureaucracy. History shows a multitude of other description

  1. STRUCTURAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20130642 Bai Daoyuan (Hunan Institute of Geology Survey , Mineral Exploration and Development of Hunan Province , Changsha 410011 , China); Jia Baohua Potential Genesis of the Trending Changes of Jinning Period and Caledonian Structural Lineamens in Middle-Southern Hunan Province (Journal of Geomechanics , ISSN1006-6616 ,

  2. European structuralism

    OpenAIRE

    Willems, Klaas

    2014-01-01

    European structuralism is a paradigm for the study of language developed by prominent European linguists during the inter-war period and the first decades after World War II that radically rejected the prevailing atomism of 19th century (particularly neo-grammarian) linguistics and language psychology.

  3. Nuclear structure

    CERN Document Server

    Nazarewicz, W

    1999-01-01

    Current developments in nuclear structure are discussed from a theoretical perspective. The studies of the nuclear many-body system provide us with invaluable information about the nature of the nuclear interaction, nucleonic correlations at various energy-distance scales, and the modes of the nucleonic matter.

  4. Data Structures

    DEFF Research Database (Denmark)

    Davoodi, Pooya

    We study data structures for variants of range query problems. In particular, we consider (1) the range minimum problem: given a multidimensional array, find the position of the minimum element in a query rectangle; (2) the path minima problem: given a weighted tree, find the edge with minimum...... weight in a query path; (3) the range diameter problem: given a point set in the plane, find two points that are farthest away in a query rectangle. These and similar problems arise in various applications including document retrieval, genome sequence analysis, OLAP data cubes, network flows, shape......-fitting, and clustering. The three mentioned problems are considered for either static inputs or dynamic inputs. In the static setting, we investigate the space-efficiency of data structures, which is an important aspect in massive data algorithmics. We provide lower bounds on the trade-off between the query time...

  5. Syllable structure

    Directory of Open Access Journals (Sweden)

    Jakobsen Per

    2008-01-01

    Full Text Available In traditional structuralist understanding, language is a system of signs i.e. an inseparable unity of content and expression. According to glossematic linguistic theory, the dichotomy of form and substance in the content has its parallel in the expression. The present paper shows that in one language certain consonant clusters within the syllable are allowed, in other languages they are not. The phonotactic structure, i.e. the rules of forming syllables decide the forming of new words and identify the language at the same time. This fundamental syllable structure shows that it is scientifically untenable to maintain that the Serbo-Croatian language has split up in several new languages. .

  6. Concrete structures

    CERN Document Server

    Setareh, Mehdi

    2017-01-01

    This revised, fully updated second edition covers the analysis, design, and construction of reinforced concrete structures from a real-world perspective. It examines different reinforced concrete elements such as slabs, beams, columns, foundations, basement and retaining walls and pre-stressed concrete incorporating the most up-to-date edition of the American Concrete Institute Code (ACI 318-14) requirements for the design of concrete structures. It includes a chapter on metric system in reinforced concrete design and construction. A new chapter on the design of formworks has been added which is of great value to students in the construction engineering programs along with practicing engineers and architects. This second edition also includes a new appendix with color images illustrating various concrete construction practices, and well-designed buildings. The ACI 318-14 constitutes the most extensive reorganization of the code in the past 40 years. References to the various sections of the ACI 318-14 are pro...

  7. Terminal structure

    Science.gov (United States)

    Schmidt, Frank; Allais, Arnaud; Mirebeau, Pierre; Ganhungu, Francois; Lallouet, Nicolas

    2009-10-20

    A terminal structure (2) for a superconducting cable (1) is described. It consists of a conductor (2a) and an insulator (2b) that surrounds the conductor (2a), wherein the superconducting cable (1) has a core with a superconducting conductor (5) and a layer of insulation that surrounds the conductor (5), and wherein the core is arranged in such a way that it can move longitudinally in a cryostat. The conductor (2a) of the terminal structure (2) is electrically connected with the superconducting conductor (5) or with a normal conductor (6) that is connected with the superconducting conductor (5) by means of a tubular part (7) made of an electrically conductive material, wherein the superconducting conductor (5) or the normal conductor (6) can slide in the part (7) in the direction of the superconductor.

  8. Lightweight Structures

    Science.gov (United States)

    Whittenberger, J. Daniel

    2001-01-01

    Present structural concepts for hot static structures are conventional "sheet & stringer" or truss core construction. More weight-efficient concepts such as honeycomb and lattice block are being investigated, in combination with both conventional superalloys and TiAl. Development efforts for components made from TiAl sheet are centered on lower cost methods for sheet and foil production, plus alloy development for higher temperature capability. A low-cost casting technology recently developed for aluminum and steel lattice blocks has demonstrated the required higher strength and stiffness, with weight efficiency approach- ing honeycombs. The current effort is based on extending the temperature capability by developing lattice block materials made from IN-718 and Mar-M247.

  9. STRUCTURAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    <正>20122174 Bai Daoyuan ( Institute of Geological Survey of Hunan Province,Changsha 410011,China );Jia Baohua Neoproterozoic TectonicEvolution of the Xuefeng Orogenic Zone in Hunan Province ( Sedimentary Geology and Tethyan Geology,ISSN1009-3850,CN51-1593 / P,31 ( 3 ), 2011,p.78-87,2illus.,1 table,96refs. ) Key words:structural evolution,Neoproterozoic Era,Hunan Province This paper deals,on the basis of abundant lithogeochemical and geochronologic

  10. Structural dynamics

    CERN Document Server

    Strømmen, Einar N

    2014-01-01

    This book introduces to the theory of structural dynamics, with focus on civil engineering structures that may be described by line-like beam or beam-column type of systems, or by a system of rectangular plates. Throughout this book the mathematical presentation contains a classical analytical description as well as a description in a discrete finite element format, covering the mathematical development from basic assumptions to the final equations ready for practical dynamic response predictions. Solutions are presented in time domain as well as in frequency domain. Structural Dynamics starts off at a basic level and step by step brings the reader up to a level where the necessary safety considerations to wind or horizontal ground motion induced dynamic design problems can be performed. The special theory of the tuned mass damper has been given a comprehensive treatment, as this is a theory not fully covered elsewhere. For the same reason a chapter on the problem of moving loads on beams has been included.

  11. Microplastic Structures

    Science.gov (United States)

    Feely, Wayne E.

    1986-07-01

    Thick coatings (5-15μm) of a new dual image, aqueous developable photoresist can be exposed using a light attenuating photomask consisting of clear, opaque and grey areas and then processed to yield thermally stable 3-dimensional structures which are potentially useful as mechanical and optical components of devices. In the positive mode, relief and intaglio images are produced by processing similar to positive novolak based resists with 1- 2μm resolution and with the added feature that the images can be made thermally stable to temperatures >300° C. Negative mode processing of coated wafers imaged with the special mask produces thermally stable structures with tunnels or hollow chambers as well as cantilever beams. Because these structures are crosslinked at the time of development, processing in the negative mode shows much wider latitude than is the case in the positive mode. Images by negative mode processing are capable of submicron resolution, higher aspect ratio (>3 vs resin compositions cover a broad range of compositions so that resins can be tailored to meet specific property requirements.

  12. Graphene nano-devices and nano-composites for structural, thermal and sensing applications

    Science.gov (United States)

    Yavari, Fazel

    In this dissertation we have developed graphene-based nano-devices for applications in integrated circuits and gas sensors; as well as graphene-based nano-composites for applications in structures and thermal management. First, we have studied the bandgap of graphene for semiconductor applications. Graphene as a zero-bandgap material cannot be used in the semiconductor industry unless an effective method is developed to open the bandgap in this material. We have demonstrated that a bandgap of 0.206 eV can be opened in graphene by adsorption of water vapor molecules on its surface. Water molecules break the molecular symmetries of graphene resulting in a significant bandgap opening. We also illustrate that the lack of bandgap in graphene can be used to our advantage by making sensors that are able to detect low concentrations of gas molecules mixed in air. We have shown that 1-2 layers of graphene synthesized by chemical vapor deposition enables detection of trace amounts of NO 2 and NH3 in air at room temperature and atmospheric pressure. The gas species are detected by monitoring changes in electrical resistance of the graphene film due to gas adsorption. The sensor response time is inversely proportional to the gas concentration. Heating the film expels chemisorbed molecules from the graphene surface enabling reversible operation. The detection limits of ~100 parts-per-billion (ppb) for NO2 and ~500 ppb for NH3 obtained using this device are markedly superior to commercially available NO2 and NH3 detectors. This sensor is fabricated using individual graphene sheets that are exquisitely sensitive to the chemical environment. However, the fabrication and operation of devices that use individual nanostructures for sensing is complex, expensive and suffers from poor reliability due to contamination and large variability from sample-to-sample. To overcome these problems we have developed a gas sensor based on a porous 3D network of graphene sheets called graphene foam

  13. STRUCTURED BACKWARD ERRORS FOR STRUCTURED KKT SYSTEMS

    Institute of Scientific and Technical Information of China (English)

    Xin-xiu Li; Xin-guo Liu

    2004-01-01

    In this paper we study structured backward errors for some structured KKT systems.Normwise structured backward errors for structured KKT systems are defined, and computable formulae of the structured backward errors are obtained. Simple numerical examples show that the structured backward errors may be much larger than the unstructured ones in some cases.

  14. The structure, energetics, and nature of the chemical bonding of phenylthiol adsorbed on the Au(111) surface: implications for density-functional calculations of molecular-electronic conduction.

    Science.gov (United States)

    Bilić, Ante; Reimers, Jeffrey R; Hush, Noel S

    2005-03-01

    The adsorption of phenylthiol on the Au(111) surface is modeled using Perdew and Wang density-functional calculations. Both direct molecular physisorption and dissociative chemisorption via S-H bond cleavage are considered as well as dimerization to form disulfides. For the major observed product, the chemisorbed thiol, an extensive potential-energy surface is produced as a function of both the azimuthal orientation of the adsorbate and the linear translation of the adsorbate through the key fcc, hcp, bridge, and top binding sites. Key structures are characterized, the lowest-energy one being a broad minimum of tilted orientation ranging from the bridge structure halfway towards the fcc one. The vertically oriented threefold binding sites, often assumed to dominate molecular electronics measurements, are identified as transition states at low coverage but become favored in dense monolayers. A similar surface is also produced for chemisorption of phenylthiol on Ag(111); this displays significant qualitative differences, consistent with the qualitatively different observed structures for thiol chemisorption on Ag and Au. Full contours of the minimum potential energy as a function of sulfur translation over the crystal face are described, from which the barrier to diffusion is deduced to be 5.8 kcal mol(-1), indicating that the potential-energy surface has low corrugation. The calculated bond lengths, adsorbate charge and spin density, and the density of electronic states all indicate that, at all sulfur locations, the adsorbate can be regarded as a thiyl species that forms a net single covalent bond to the surface of strength 31 kcal mol(-1). No detectable thiolate character is predicted, however, contrary to experimental results for alkyl thiols that indicate up to 20%-30% thiolate involvement. This effect is attributed to the asymptotic-potential error of all modern density functionals that becomes manifest through a 3-4 eV error in the lineup of the adsorbate and

  15. High aspect ratio, nanostructured, platinum based electrodes for proton exchange membrane fuel cells: Design, development and ionic conduction of the proposed structures

    Science.gov (United States)

    Paschos, Odysseas

    High aspect ratio nanostructures can provide substantial benefits when used as fuel cell electrodes since they can alleviate problems associated with conventional carbon supports. In this work the potential of incorporating high aspect ratio nanostructures as electrodes for fuel cells was studied. Moreover, a model was created that demonstrated the potential for the nanostructures to yield high performance. The creation of Pt nanorods using anodic aluminum oxide templates was investigated and experiments showed complete utilization of the electrodes surface area. However, the Pt nanorod structure was found to not be effective in terms of Pt mass utilization, since only the outer surface of the rod is utilized for catalytic activity. An alternate method was developed to coat (with Pt) high aspect ratio structures made from a cost-effective support material. Thus far, methods used to conformally coat Pt either cannot be used directly on several materials or tend not to be cost-effective. A non-vacuum method based on an Aerosol Assisted Deposition (AAD) technique was developed and optimized. Initial experiments showed feasibility of the technique to coat a large variety of substrates. Dimensions of the particles were controlled by the deposition parameters and ranged from 4 nm up to several hundreds of nm in diameter. Experiments where Pt nanoparticles were deposited on gas diffusion layer substrates, showed higher electrochemical performance compared to commercial catalyst. The need for electrolyte coating on the high aspect ratio structures was also investigated. Initial experiments were performed by splitting an MEA in half and using an intermediate Pt film. These experiments showed that ionic conduction on Pt surface is possible. Moreover these studies indicated that ionic conduction on Pt could result from hydrophilic groups that can exist on its surface. Since these groups can either be physisorbed due to presence of water or chemisorbed on the oxidized Pt

  16. First attempts at an elucidation of the interface structure resulting from the interaction between methacrylonitrile and a platinum anode: an experimental and theoretical (ab initio) study

    Science.gov (United States)

    Bureau, Christophe; Deniau, Guy; Valin, Françoise; Guittet, Marie-Joseph; Lécayon, Gérard; Delhalle, Joseph

    1996-06-01

    The aim of the present paper is to contribute to the elucidation of the molecular structures obtained on a platinum surface as this surface is submitted to an anodic potential (with respect to a silver reference electrode) when dipped into pure 2-methyl 2-propenenitrile (methacrylonitrile). Modified surfaces are examined using X- and UV-photoelectron spectroscopies (UPS and XPS). The results evidence the formation of an ultra-thin (20-40 Å) grafted oligomer film, which is not classical polymethacrylonitrile (PMAN), as obtained through a radical or anionic mechanism: spectral characteristics argue in the sense of a cationic polymerization of methacrylonitrile through its nitrile groups, as evidenced by a lowering of the gap as well as by the UPS and XPS (N 1s region) spectra. Molecular models of the reactants and reaction intermediates are proposed for the cationic polymerization of methacrylonitrile, and show that this polymerization is about as feasible as that of acetonitrile, at least on kinetic control grounds. Two different mechanisms are nonetheless possible, leading either to a quasi conjugated poly-imine type -(N  C) n-, or to a poly-cumulene type -(N  C  C) n- network. Theoretical consierations on reactants properties lead us to select the poly-imine way as the most plausible. Along with literature data concerning chemisorbed nitriles on platinum surfaces, a molecular model of the final state of the poly-imine reaction is then designed, comprising a three atom cluster to render the grafting site, and a dimer to render the grafted structure. A full geometry optimization is performed on the organic moiety at the Hartree-Fock (ab initio) level of theory, and a rough evaluation of the spectral footprint of the interface bond in the N 1s region is performed on the basis of Koopmans theorem with calibration on the bulk polymer peak. A preliminary 2.7 eV downward shift is predicted for N 1s interface nitrogens with respect to the polymer peak, which can

  17. Stoker structure

    Energy Technology Data Exchange (ETDEWEB)

    Mros, F.

    1981-11-10

    A screw-conveyor or auger feed and associated leveling system are disclosed for underfeed stoker troughs receiving particulate, cominuted, or chunk material, such as ''green'' coal, by way of example, this for assuring a uniformly rising level of material relative to the trough. The stoker structure herein includes combustion beds which are air perforate and kept this way through periodically rising members such as tuyeres which shear or break up clinkerformation on such beds. A pneumatically-operated system may preferably be used to actuate such movable tuyeres relative to such combustion beds. Combustion air flows through the combustion beds upwardly but not over the trough; hot gasses rising rapidly from the combustion beds confine volatiles gently rising vertically from the cone within the trough for complete combustion, essentially eliminating smoke-production thereat.

  18. Structural Discrimination

    DEFF Research Database (Denmark)

    Thorsen, Mira Skadegård

    In this article, I discuss structural discrimination, an underrepresented area of study in Danish discrimination and intercultural research. It is defined here as discursive and constitutive, and presented as a central element of my analytical approach. This notion is employed in the with which...... to understand and identify aspects of power and asymmetry in communication and interactions. With this as a defining term, I address how exclusion and discrimination exist, while also being indiscernible, within widely accepted societal norms. I introduce the concepts of microdiscrimination and benevolent...... discrimination as two ways of articulating particular, opaque forms of racial discrimination that occur in everyday Danish (and other) contexts, and have therefore become normalized. I present and discuss discrimination as it surfaces in data from my empirical studies of discrimination in Danish contexts...

  19. Reliable structural, thermodynamic, and spectroscopic properties of organic molecules adsorbed on silicon surfaces from computational modeling: the case of glycine@Si(100).

    Science.gov (United States)

    Carnimeo, Ivan; Biczysko, Malgorzata; Bloino, Julien; Barone, Vincenzo

    2011-10-06

    Chemisorption of glycine on Si(100) has been studied by an integrated computational strategy based on perturbative anharmonic computations employing geometries and harmonic force fields evaluated by hybrid density functionals coupled to purposely tailored basis sets. It is shown that such a strategy allows the prediction of spectroscopic properties of isolated and chemisorbed molecules with comparable accuracy, paving the route toward a detailed analysis of surface-induced changes of glycine vibrational spectra.

  20. Structural Bionic Design of Machine Tool Structures

    Institute of Scientific and Technical Information of China (English)

    ZHAO Ling; WANG Ting; GUO Hong-liang; LI Guo-meng

    2011-01-01

    A structural bionic design process is systematically presented for lightweight mechanical structures. By mimicking biological excellent structural principles, the stiffening ribs of a machining table and a moving column were redesigned for better load-bearing efficiency. Finite element method(FEM) simulation and model experiments were carried out for performance verification, which showed the increase of structural static and dynamic performance. Structural bionic offers a new solution to change conventional structures for high specific stiffness.

  1. Asteroid structure

    Science.gov (United States)

    Asphaug, E.

    2014-07-01

    Even before the first space missions to asteroids, in the mid-1990s, it was known that asteroids have weird structures. Photometry indicated complicated shapes, and the pioneering radar investigations by Ostro and colleagues followed by adaptive optics campaigns and flybys showed odd binary forms, and confirmed the common presence of satellites, and indications of highly varying surface roughness. Some asteroids turned out to be dominated by a single major cratering event, while others showed no evidence of a major crater, or perhaps for global crater erasure. The first space mission to orbit an asteroid, NEAR, found a mixture of heavily cratered terrains and geomorphically active 'ponds', and indicated evidence for global seismicity from impact. The next mission to orbit an asteroid, Hayabusa, found what most agree is a rubble pile, with no major craters and an absence of fines. There is to date no direct evidence of asteroid interior geology, other than measurements of bulk density, and inferences made for mass distribution asymmetry based on dynamics, and inferences based on surface lineaments. Interpolating from the surface to the interior is always risky and usually wrong, but of course the answer is important since we are someday destined to require this knowledge in order to divert a hazardous asteroid from impact with the Earth. Even considering the near-subsurface, here we remain as ignorant as we were about the Moon in the early 1960s, whether the surface will swallow us up in dust, or will provide secure landing and anchoring points. Laboratory experimentation in close to zero-G is still in its early stages. Adventures such as mining and colonization will surely have to wait until we better know these things. How do we get from here to there? I will focus on 3 areas of progress: (1) asteroid cratering seismology, where we use the surface craters to understand what is going on inside; (2) numerical modeling of collisions, which predicts the internal

  2. Structural Biology Fact Sheet

    Science.gov (United States)

    ... Home > Science Education > Structural Biology Fact Sheet Structural Biology Fact Sheet Tagline (Optional) Middle/Main Content Area ​Other Fact Sheets What is structural biology? Structural biology is the study of how biological ...

  3. Organic molecules as tools to control the growth, surface structure, and redox activity of colloidal quantum dots.

    Science.gov (United States)

    Weiss, Emily A

    2013-11-19

    Account, I describe the varied roles of organic molecules in controlling the structure and properties of colloidal quantum dots. Molecules serve as surfactant that determines the mechanism and rate of nucleation and growth and the final size and surface structure of a quantum dot. Anionic surfactant in the reaction mixture allows precise control over the size of the quantum dot core but also drives cation enrichment and structural disordering of the quantum dot surface. Molecules serve as chemisorbed ligands that dictate the energetic distribution of surface states. These states can then serve as thermodynamic traps for excitonic charge carriers or couple to delocalized states of the quantum dot core to change the confinement energy of excitonic carriers. Ligands, therefore, in some cases, dramatically shift the ground state absorption and photoluminescence spectra of quantum dots. Molecules also act as protective layers that determine the probability of redox processes between quantum dots and other molecules. How much the ligand shell insulates the quantum dot from electron exchange with a molecular redox partner depends less on the length or degree of conjugation of the native ligand and more on the density and packing structure of the adlayer and the size and adsorption mode of the molecular redox partner. Control of quantum dot properties in these examples demonstrates that nanoscale interfaces, while complex, can be rationally designed to enhance or specify the functionality of a nanostructured system.

  4. Collapsible Geostrut Structure

    Science.gov (United States)

    Robertson, Glen A.

    1994-01-01

    Portable truss structure collapsible into smaller volume for storage and transportation. At new site, reerected quickly, without need to reassemble parts. Structure could be tent, dome, tunnel, or platform. Key element in structure joint, called "geostrut joint," includes internal cable. Structure is network of struts attached to geostrut joints. Pulling cables taut in all joints makes structure rigid. Releasing cables relaxes structure.

  5. Magnetic multilayer structure

    Energy Technology Data Exchange (ETDEWEB)

    Herget, Philipp; O' Sullivan, Eugene J.; Romankiw, Lubomyr T.; Wang, Naigang; Webb, Bucknell C.

    2017-03-21

    A mechanism is provided for an integrated laminated magnetic device. A substrate and a multilayer stack structure form the device. The multilayer stack structure includes alternating magnetic layers and diode structures formed on the substrate. Each magnetic layer in the multilayer stack structure is separated from another magnetic layer in the multilayer stack structure by a diode structure.

  6. Magnetic multilayer structure

    Science.gov (United States)

    Herget, Philipp; O'Sullivan, Eugene J.; Romankiw, Lubomyr T.; Wang, Naigang; Webb, Bucknell C.

    2016-07-05

    A mechanism is provided for an integrated laminated magnetic device. A substrate and a multilayer stack structure form the device. The multilayer stack structure includes alternating magnetic layers and diode structures formed on the substrate. Each magnetic layer in the multilayer stack structure is separated from another magnetic layer in the multilayer stack structure by a diode structure.

  7. Structural Analysis of Plate Based Tensegrity Structures

    DEFF Research Database (Denmark)

    Hald, Frederik; Kirkegaard, Poul Henning; Damkilde, Lars

    2013-01-01

    Plate tensegrity structures combine tension cables with a cross laminated timber plate and can then form e.g. a roof structure. The topology of plate tensegrity structures is investigated through a parametric investigation. Plate tensegrity structures are investigated, and a method...... for determination of the structures pre-stresses is used. A parametric investigation is performed to determine a more optimized form of the plate based tensegrity structure. Conclusions of the use of plate based tensegrity in civil engineering and further research areas are discussed....

  8. Structural Analysis of Plate Based Tensegrity Structures

    DEFF Research Database (Denmark)

    Hald, Frederik; Kirkegaard, Poul Henning; Damkilde, Lars

    2013-01-01

    Plate tensegrity structures combine tension cables with a cross laminated timber plate and can then form e.g. a roof structure. The topology of plate tensegrity structures is investigated through a parametric investigation. Plate tensegrity structures are investigated, and a method...... for determination of the structures pre-stresses is used. A parametric investigation is performed to determine a more optimized form of the plate based tensegrity structure. Conclusions of the use of plate based tensegrity in civil engineering and further research areas are discussed....

  9. Computational structural mechanics for engine structures

    Science.gov (United States)

    Chamis, C. C.

    1989-01-01

    The computational structural mechanics (CSM) program at Lewis encompasses: (1) fundamental aspects for formulating and solving structural mechanics problems, and (2) development of integrated software systems to computationally simulate the performance/durability/life of engine structures. It is structured to mainly supplement, complement, and whenever possible replace, costly experimental efforts which are unavoidable during engineering research and development programs. Specific objectives include: investigate unique advantages of parallel and multiprocesses for: reformulating/solving structural mechanics and formulating/solving multidisciplinary mechanics and develop integrated structural system computational simulators for: predicting structural performances, evaluating newly developed methods, and for identifying and prioritizing improved/missing methods needed. Herein the CSM program is summarized with emphasis on the Engine Structures Computational Simulator (ESCS). Typical results obtained using ESCS are described to illustrate its versatility.

  10. Common structure-balance between spacetime structure and massenergy structure

    Science.gov (United States)

    Cao, Daqing; Cao, Dayong

    2017-01-01

    According to Einstein field equation, there is a balance between spacetime structure and massenergy structure. nd the paper consider it as a common structurewhich was brought forward by Daqing Cao in 2011 ecause it is general structure in the universe and everything have the same model of structure in their one system. The Jovian planets is spacetime structure of solar system because they are gas-sphere and they have more density of spacetime (spacetime/massenergy) than the density of massenergy (massenergy/spacetime). The terrestrial planets is massenergy structure of solar system because they are rock-ball and they have more density of massenergy than the density of spacetime. That can explain of that the Jovian planets of big mass is far away from sun. With the idea that the wave is spacetime and the wave effect is spacetime structure, the planets have elliptic orbits and the same direction of their revolution. Because sun is like a massenergy center of the massenergy structure and the terrestrial planets, the paper supposes there is a dark sun-a dark hole who has a spacetime center of spacetime structure and influences on the orbits of the Jovian planets. http://meetings.aps.org/Meeting/APR16/Session/M13.8

  11. Offshore Structural Control Considering Fluid Structure Interaction

    Institute of Scientific and Technical Information of China (English)

    Ju Myung KIM; Dong Hyawn KIM; Gyu Won LEE

    2006-01-01

    Tuned Mass Damper (TMD) was applied to an offshore structure to control ocean wave-induced vibration. In the analysis of the dynamic response of the offshore structure, fluid-structure interaction is considered and the errors, which occur in the linearization of the interaction, are investigated. For the investigation of the performance of TMD in controlling the vibration, both regular waves with different periods and irregular waves with different significant wave heights are used. Based on the numerical analysis it is concluded that the fluid-structure interaction should be considered in the evaluation of the capability of TMD in vibration control of offshore structures.

  12. Designing pliable structural Skins

    DEFF Research Database (Denmark)

    Tamke, Martin; Peters, Brady; Nielsen, Stig Anton;

    2013-01-01

    Structural stability can be formed through structured or seemingly unstructured approaches to fold, plead or crumble paper. This paper reports on two projects that showcase how computational design approaches can help to widen the understanding and use of structural skins....

  13. Electronic Structure of the Perylene / Zinc Oxide Interface: A Computational Study of Photoinduced Electron Transfer and Impact of Surface Defects

    KAUST Repository

    Li, Jingrui

    2015-07-29

    The electronic properties of dye-sensitized semiconductor surfaces consisting of pery- lene chromophores chemisorbed on zinc oxide via different spacer-anchor groups, have been studied at the density-functional-theory level. The energy distributions of the donor states and the rates of photoinduced electron transfer from dye to surface are predicted. We evaluate in particular the impact of saturated versus unsaturated aliphatic spacer groups inserted between the perylene chromophore and the semiconductor as well as the influence of surface defects on the electron-injection rates.

  14. Study of Boundary Structures.

    Science.gov (United States)

    1982-09-01

    THEORY OF ABC-CBA STACKING BOUNDARY IN fcc STRUCTURE .......... 11 - 4 TRANSITIONS AND PHASE EQUILIBRIA AMONG GRAIN BOUNDARY STRUCTURES...19 B THEORY OF ABC-CBA STACKING BOUNDARY IN fcc STRUCTURE .......... 37 C TRANSITIONS AND PHASE EQUILIBRIA AMONG GRAIN BOUNDARY...layer structure. 10 SECTION 3 THEORY OF ABC-CBA STACKING BOUNDARY IN fcc STRUCTURE The (111) planes of the fcc structure is stacked as ABCABC... as

  15. Protein structure search and local structure characterization

    Directory of Open Access Journals (Sweden)

    Ku Shih-Yen

    2008-08-01

    Full Text Available Abstract Background Structural similarities among proteins can provide valuable insight into their functional mechanisms and relationships. As the number of available three-dimensional (3D protein structures increases, a greater variety of studies can be conducted with increasing efficiency, among which is the design of protein structural alphabets. Structural alphabets allow us to characterize local structures of proteins and describe the global folding structure of a protein using a one-dimensional (1D sequence. Thus, 1D sequences can be used to identify structural similarities among proteins using standard sequence alignment tools such as BLAST or FASTA. Results We used self-organizing maps in combination with a minimum spanning tree algorithm to determine the optimum size of a structural alphabet and applied the k-means algorithm to group protein fragnts into clusters. The centroids of these clusters defined the structural alphabet. We also developed a flexible matrix training system to build a substitution matrix (TRISUM-169 for our alphabet. Based on FASTA and using TRISUM-169 as the substitution matrix, we developed the SA-FAST alignment tool. We compared the performance of SA-FAST with that of various search tools in database-scale search tasks and found that SA-FAST was highly competitive in all tests conducted. Further, we evaluated the performance of our structural alphabet in recognizing specific structural domains of EGF and EGF-like proteins. Our method successfully recovered more EGF sub-domains using our structural alphabet than when using other structural alphabets. SA-FAST can be found at http://140.113.166.178/safast/. Conclusion The goal of this project was two-fold. First, we wanted to introduce a modular design pipeline to those who have been working with structural alphabets. Secondly, we wanted to open the door to researchers who have done substantial work in biological sequences but have yet to enter the field of protein

  16. Deployable Composite Structures Project

    Data.gov (United States)

    National Aeronautics and Space Administration — NASA is seeking innovative structure technologies that will advance expandable modules for orbital and surface based habitats. These secondary structures must...

  17. Composite Structures Manufacturing Facility

    Data.gov (United States)

    Federal Laboratory Consortium — The Composite Structures Manufacturing Facility specializes in the design, analysis, fabrication and testing of advanced composite structures and materials for both...

  18. Distributed Structure Searchable Toxicity

    Data.gov (United States)

    U.S. Environmental Protection Agency — The Distributed Structure Searchable Toxicity (DSSTox) online resource provides high quality chemical structures and annotations in association with toxicity data....

  19. Protein structure mining using a structural alphabet.

    Science.gov (United States)

    Tyagi, M; de Brevern, A G; Srinivasan, N; Offmann, B

    2008-05-01

    We present a comprehensive evaluation of a new structure mining method called PB-ALIGN. It is based on the encoding of protein structure as 1D sequence of a combination of 16 short structural motifs or protein blocks (PBs). PBs are short motifs capable of representing most of the local structural features of a protein backbone. Using derived PB substitution matrix and simple dynamic programming algorithm, PB sequences are aligned the same way amino acid sequences to yield structure alignment. PBs are short motifs capable of representing most of the local structural features of a protein backbone. Alignment of these local features as sequence of symbols enables fast detection of structural similarities between two proteins. Ability of the method to characterize and align regions beyond regular secondary structures, for example, N and C caps of helix and loops connecting regular structures, puts it a step ahead of existing methods, which strongly rely on secondary structure elements. PB-ALIGN achieved efficiency of 85% in extracting true fold from a large database of 7259 SCOP domains and was successful in 82% cases to identify true super-family members. On comparison to 13 existing structure comparison/mining methods, PB-ALIGN emerged as the best on general ability test dataset and was at par with methods like YAKUSA and CE on nontrivial test dataset. Furthermore, the proposed method performed well when compared to flexible structure alignment method like FATCAT and outperforms in processing speed (less than 45 s per database scan). This work also establishes a reliable cut-off value for the demarcation of similar folds. It finally shows that global alignment scores of unrelated structures using PBs follow an extreme value distribution. PB-ALIGN is freely available on web server called Protein Block Expert (PBE) at http://bioinformatics.univ-reunion.fr/PBE/.

  20. Structural behaviour of super-light structures

    DEFF Research Database (Denmark)

    Bagger, Anne; Hertz, Kristian Dahl

    2010-01-01

    with a lighter and softer material, such as lightweight concrete. The combined use of stiff and light material in SLS results in structures of high stiffness and low weight. The applied technology and the advantages of SLS are elaborated upon in [1] in these proceedings. The present paper focuses......A new structural concept, called Super-light Structures (SLS), has recently been invented and patented at the Technical University of Denmark. The basic concept of SLS is to construct a skeleton of a stiff and strong material, such as ordinary or high strength concrete, and stabilize this skeleton...... on the structural correlation between the stiff material and the light material. The shape of the skeleton can be optimized for the primary load on the structure, and it will take up the majority of the load. The lighter material forms the outer geometry of the structural component (e.g. a wall), and has several...

  1. A new form of chemisorbed photo- and electro-active atomic H species on the TiO2(110) surface

    Science.gov (United States)

    Zhang, Zhen; Yates, John T.

    2016-10-01

    Hydrogen adsorption on TiO2 is of importance in chemical and photochemical reduction processes. Using several surface science methods, we clearly distinguish two kinds of H species on the surface of rutile TiO2(110)-1 × 1. In contrast with the well-studied bridge-bonded OH species (α-H) originating from H2O dissociation on the surface oxygen vacancy site on TiO2(110), atomic H adsorption on the TiO2(110) (denoted as β-H) exhibits special high sensitivity to the electronic excitation of the TiO2(110) by either electrons or UV photons. The formation of molecular H2 gas by photoexcitation of β-H/TiO2(110) surfaces has been observed, which may shed light on the basic understanding of the processes of photocatalytic H2 production by splitting water.

  2. Chinese Conversation Structure

    Institute of Scientific and Technical Information of China (English)

    LIU Yan

    2016-01-01

    This paper aims to describe the features of Chinese conversation structure. Specifically speaking, the structure will be analyzed from the following four aspects:openings and pre-sequence, adjacency pairs, pre-closing and closing. Generally speak-ing, Chinese conversation structure is similar to English conversation structure. But still a lot of differences are found due to cul-tural factors.

  3. Probing environmentally significant surface radicals: Crystallographic and temperature dependent adsorption of phenol on ZnO

    Science.gov (United States)

    Thibodeaux, Chad A.; Poliakoff, E.D.; Kizilkaya, Orhan; Patterson, Matthew C.; DiTusa, Mark F.; Kurtz, Richard L.

    2015-01-01

    Environmentally persistent free radicals (EPFRs) are toxic organic/metal oxide composite particles that have been discovered to form from substituted benzenes chemisorbed to metal oxides. Here, we perform photoelectron spectroscopy, electron energy loss spectroscopy, and low energy electron diffraction of phenol chemisorbed to ZnO(1 0 1̱ 0) and (0 0 0 1̱)-Zn to observe electronic structure changes and charge transfer as a function adsorption temperature. We show direct evidence of charge transfer from the ZnO surfaces to the phenol. This evidence can help gain a better understanding of EPFRs and be used to develop possible future remediation strategies. PMID:26388650

  4. Crystal structure and prediction.

    Science.gov (United States)

    Thakur, Tejender S; Dubey, Ritesh; Desiraju, Gautam R

    2015-04-01

    The notion of structure is central to the subject of chemistry. This review traces the development of the idea of crystal structure since the time when a crystal structure could be determined from a three-dimensional diffraction pattern and assesses the feasibility of computationally predicting an unknown crystal structure of a given molecule. Crystal structure prediction is of considerable fundamental and applied importance, and its successful execution is by no means a solved problem. The ease of crystal structure determination today has resulted in the availability of large numbers of crystal structures of higher-energy polymorphs and pseudopolymorphs. These structural libraries lead to the concept of a crystal structure landscape. A crystal structure of a compound may accordingly be taken as a data point in such a landscape.

  5. Strategy implemented through structuring and new structures

    DEFF Research Database (Denmark)

    Nielsen, Renate

    Research objective: With the purpose of generating a new understanding of how development in organisations take place, an interpretive perspective at continuous processes in organisations will be applied: more specifically at how organisational interpretation forms an organisation's strategy...... and how the strategy is implemented through structuring, new structures and routines....

  6. Internal structure of structurally stitched NCF preform

    NARCIS (Netherlands)

    Koissin, V.; Ruopp, A.; Lomov, S.V.; Verpoest, I.; Witzel, V.; Drechsler, K.

    2006-01-01

    The paper addresses the experimental investigation of the unit cell architecture in a structurally stitched multilayer carbon-fibre preform. Each layer is a multiaxial multiply non-crimp fabric (NCF) knit with a non-structural stitching. The term “structural” presumes here that the stitching yarn do

  7. Building a Structural Model: Parameterization and Structurality

    Directory of Open Access Journals (Sweden)

    Michel Mouchart

    2016-04-01

    Full Text Available A specific concept of structural model is used as a background for discussing the structurality of its parameterization. Conditions for a structural model to be also causal are examined. Difficulties and pitfalls arising from the parameterization are analyzed. In particular, pitfalls when considering alternative parameterizations of a same model are shown to have lead to ungrounded conclusions in the literature. Discussions of observationally equivalent models related to different economic mechanisms are used to make clear the connection between an economically meaningful parameterization and an economically meaningful decomposition of a complex model. The design of economic policy is used for drawing some practical implications of the proposed analysis.

  8. Band structure of semiconductors

    CERN Document Server

    Tsidilkovski, I M

    2013-01-01

    Band Structure of Semiconductors provides a review of the theoretical and experimental methods of investigating band structure and an analysis of the results of the developments in this field. The book presents the problems, methods, and applications in the study of band structure. Topics on the computational methods of band structure; band structures of important semiconducting materials; behavior of an electron in a perturbed periodic field; effective masses and g-factors for the most commonly encountered band structures; and the treatment of cyclotron resonance, Shubnikov-de Haas oscillatio

  9. Structural system identification: Structural dynamics model validation

    Energy Technology Data Exchange (ETDEWEB)

    Red-Horse, J.R.

    1997-04-01

    Structural system identification is concerned with the development of systematic procedures and tools for developing predictive analytical models based on a physical structure`s dynamic response characteristics. It is a multidisciplinary process that involves the ability (1) to define high fidelity physics-based analysis models, (2) to acquire accurate test-derived information for physical specimens using diagnostic experiments, (3) to validate the numerical simulation model by reconciling differences that inevitably exist between the analysis model and the experimental data, and (4) to quantify uncertainties in the final system models and subsequent numerical simulations. The goal of this project was to develop structural system identification techniques and software suitable for both research and production applications in code and model validation.

  10. Rheology of Structured Oils

    Science.gov (United States)

    Kelbaliev, G. I.; Rasulov, S. R.; Rzaev, A. G.; Mustafaeva, G. R.

    2017-07-01

    Rheological models of structured oils are proposed and compared with available experimental data on oils from different deposits. It is shown that structured oils can possess properties of Bingham and power-law non-Newtonian fluids.

  11. Structural Measures - Hospital

    Data.gov (United States)

    U.S. Department of Health & Human Services — A list of hospitals and the availability of structural measures at that hospital. A structural measure reflects the environment in which hospitals care for patients....

  12. Structural Static Laboratory

    Data.gov (United States)

    Federal Laboratory Consortium — Structural testing is performed to verify the structural integrity of space flight and ground test hardware. Testing is also performed to verify the finite element...

  13. Growing Timber Structures

    DEFF Research Database (Denmark)

    Tamke, Martin; Evers, Henrik Leander; Stasiuk, David

    2013-01-01

    The contemporary design of timber structures has to answer questions concerning structural stability, production impact and energy implications in ever earlier stages. The interrelation of these levels creates a complexity that is difficult to resolve through contemporary linear parametric...

  14. Advanced structural inorganic chemistry

    CERN Document Server

    Li, Wai-Kee; Mak, Thomas C W

    2008-01-01

    An English edition of a textbook based on teaching at the final year undergraduate and graduate level. It presents structure and bonding, generalizations of structural trends, crystallographic data, as well as highlights from the recent literature.

  15. Antenna Structure Registrate

    Data.gov (United States)

    Department of Homeland Security — This file is an extract of the Antenna Structure Registrate (ASR). The ASR consists of antenna structures that are more than 60.96 meters (200 feet) in height or...

  16. Structural health monitoring for ship structures

    Energy Technology Data Exchange (ETDEWEB)

    Farrar, Charles [Los Alamos National Laboratory; Park, Gyuhae [Los Alamos National Laboratory; Angel, Marian [Los Alamos National Laboratory; Bement, Matthew [Los Alamos National Laboratory; Salvino, Liming [NSWC, CADEROCK

    2009-01-01

    Currently the Office of Naval Research is supporting the development of structural health monitoring (SHM) technology for U.S. Navy ship structures. This application is particularly challenging because of the physical size of these structures, the widely varying and often extreme operational and environmental conditions associated with these ships missions, lack of data from known damage conditions, limited sensing that was not designed specifically for SHM, and the management of the vast amounts of data that can be collected during a mission. This paper will first define a statistical pattern recognition paradigm for SHM by describing the four steps of (1) Operational Evaluation, (2) Data Acquisition, (3) Feature Extraction, and (4) Statistical Classification of Features as they apply to ship structures. Note that inherent in the last three steps of this process are additional tasks of data cleansing, compression, normalization and fusion. The presentation will discuss ship structure SHM challenges in the context of applying various SHM approaches to sea trials data measured on an aluminum multi-hull high-speed ship, the HSV-2 Swift. To conclude, the paper will discuss several outstanding issues that need to be addressed before SHM can make the transition from a research topic to actual field applications on ship structures and suggest approaches for addressing these issues.

  17. Structural requirements and reaction pathways in dimethyl ether combustion catalyzed by supported Pt clusters.

    Science.gov (United States)

    Ishikawa, Akio; Neurock, Matthew; Iglesia, Enrique

    2007-10-31

    The identity and reversibility of the elementary steps required for catalytic combustion of dimethyl ether (DME) on Pt clusters were determined by combining isotopic and kinetic analyses with density functional theory estimates of reaction energies and activation barriers to probe the lowest energy paths. Reaction rates are limited by C-H bond activation in DME molecules adsorbed on surfaces of Pt clusters containing chemisorbed oxygen atoms at near-saturation coverages. Reaction energies and activation barriers for C-H bond activation in DME to form methoxymethyl and hydroxyl surface intermediates show that this step is more favorable than the activation of C-O bonds to form two methoxides, consistent with measured rates and kinetic isotope effects. This kinetic preference is driven by the greater stability of the CH3OCH2* and OH* intermediates relative to chemisorbed methoxides. Experimental activation barriers on Pt clusters agree with density functional theory (DFT)-derived barriers on oxygen-covered Pt(111). Measured DME turnover rates increased with increasing DME pressure, but decreased as the O2 pressure increased, because vacancies (*) on Pt surfaces nearly saturated with chemisorbed oxygen are required for DME chemisorption. DFT calculations show that although these surface vacancies are required, higher oxygen coverages lead to lower C-H activation barriers, because the basicity of oxygen adatoms increases with coverage and they become more effective in hydrogen abstraction from DME. Water inhibits reaction rates via quasi-equilibrated adsorption on vacancy sites, consistent with DFT results indicating that water binds more strongly than DME on vacancies. These conclusions are consistent with the measured kinetic response of combustion rates to DME, O2, and H2O, with H/D kinetic isotope effects, and with the absence of isotopic scrambling in reactants containing isotopic mixtures of 18O2-16O2 or 12CH3O12CH3-13CH3O13CH3. Turnover rates increased with Pt

  18. Multilayer structured amperometric immunosensor built by self-assembly of a redox multi-wall carbon nanotube composite

    Energy Technology Data Exchange (ETDEWEB)

    Su Huilan [Key Laboratory on Luminescence and Real-Time Analysis, Ministry of Education, College of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715 (China); Yuan Ruo [Key Laboratory on Luminescence and Real-Time Analysis, Ministry of Education, College of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715 (China)], E-mail: yuanruo@swu.edu.cn; Chai Yaqin; Zhuo Ying; Hong Chenglin; Liu Zhongyuan; Yang Xia [Key Laboratory on Luminescence and Real-Time Analysis, Ministry of Education, College of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715 (China)

    2009-07-01

    In this paper, a novel reagentless amprometric immunosensor was built on the conductive multilayer, comprised of Nafion-coated multi-wall carbon nanotubes (MWCNT), thionine (Thi) and gold nanoparticles (nano-Au). First, Nafion-MWCNT homogeneous composite was dropped on the surface of the glass carbon electrode (GCE). Then Thi was chemisorbed by both carboxylic MWCNT and cation exchanger Nafion. Furthermore, the negative-charged nano-Au, which was used to immobilize biomolecules, was chemisorbed onto Thi film through the electrostatic force with the amino groups of Thi. The stepwise self-assembly process of the immunosensor was characterized by means of cyclic voltammetry (CV), and the microstructure of modified film was observed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Using {alpha}-1-fetoprotein (AFP) as a model, this novel immunosensor presented amplified sensitivity, good stability, and a broader linear response in two ranges from 0.5-20 ng/mL and 20-200 ng/mL with a detection limit of 0.26 ng/mL, as well as good selectivity and storage stability.

  19. Fundamentals of structural dynamics

    CERN Document Server

    Craig, Roy R

    2006-01-01

    From theory and fundamentals to the latest advances in computational and experimental modal analysis, this is the definitive, updated reference on structural dynamics.This edition updates Professor Craig's classic introduction to structural dynamics, which has been an invaluable resource for practicing engineers and a textbook for undergraduate and graduate courses in vibrations and/or structural dynamics. Along with comprehensive coverage of structural dynamics fundamentals, finite-element-based computational methods, and dynamic testing methods, this Second Edition includes new and e

  20. Synchronously Deployable Truss Structures

    Science.gov (United States)

    Rhodes, M. D.; Hedgepeth, J. M.

    1986-01-01

    Structure lightweight, readily deployed, and has reliable joints. New truss concept, designated as "pac truss," developed. Features easy deployment without need for complex mechanisms. Structures of this type deployed in free flight by controlled release of stored energy in torsional springs at selected hinges located throughout structure. Double-folding technique used in beam model applicable to flat planar trusses, allowing structures of large expanse to fold into compact packages and be deployed for space-platform applications.

  1. Extended icosahedral structures

    CERN Document Server

    Jaric, Marko V

    1989-01-01

    Extended Icosahedral Structures discusses the concepts about crystal structures with extended icosahedral symmetry. This book is organized into six chapters that focus on actual modeling of extended icosahedral crystal structures. This text first presents a tiling approach to the modeling of icosahedral quasiperiodic crystals. It then describes the models for icosahedral alloys based on random connections between icosahedral units, with particular emphasis on diffraction properties. Other chapters examine the glassy structures with only icosahedral orientational order and the extent of tra

  2. HIV Structural Database

    Science.gov (United States)

    SRD 102 HIV Structural Database (Web, free access)   The HIV Protease Structural Database is an archive of experimentally determined 3-D structures of Human Immunodeficiency Virus 1 (HIV-1), Human Immunodeficiency Virus 2 (HIV-2) and Simian Immunodeficiency Virus (SIV) Proteases and their complexes with inhibitors or products of substrate cleavage.

  3. Structural Ceramics Database

    Science.gov (United States)

    SRD 30 NIST Structural Ceramics Database (Web, free access)   The NIST Structural Ceramics Database (WebSCD) provides evaluated materials property data for a wide range of advanced ceramics known variously as structural ceramics, engineering ceramics, and fine ceramics.

  4. Structural safety during construction

    NARCIS (Netherlands)

    Terwel, K.C.; Mud, M.; Frijters, A.

    2014-01-01

    Structural safety during construction is a main concern for the building industry. Collapses of temporary structures or incomplete permanent structures are a threat for the safety of persons. Based on data from Dutch Labour Inspectorate this study concluded that approximately 20% of the fatalities

  5. Programing Structural Synthesis System

    Science.gov (United States)

    Rogers, James L., Jr.

    1986-01-01

    Program aids research in analysis and optimization. Programing Structural Synthesis System (PROSSS2) developed to provide structural-synthesis capability by combining access to SPAR with CONMIN program and set of interface procedures. SPAR is large general-purpose finite-element structural-analysis program, and CONMIN is large general-purpose optimization program. PROSSS2 written in FORTRAN IV for batch execution.

  6. Structural Enhancement of Learning

    Science.gov (United States)

    Trumpower, David L.; Goldsmith, Timothy E.

    2004-01-01

    Structural learning aids, such as interactive overviews (IOs), have previously been shown to facilitate text comprehension and recall. In this study, we examined the effects of structural aids on learners' structural knowledge and their performance on a procedural transfer task. In Experiment 1, 90 college students were presented definitions of…

  7. Neutrality in bipolar structures

    DEFF Research Database (Denmark)

    Montero, Javier; Rodríguez, J. Tinguaro; Franco, Camilo

    2014-01-01

    In this paper, we want to stress that bipolar knowledge representation naturally allows a family of middle states which define as a consequence different kinds of bipolar structures. These bipolar structures are deeply related to the three types of bipolarity introduced by Dubois and Prade, but our...... approach offers a systematic explanation of how such bipolar structures appear and can be identified....

  8. Organizational Knowledge Management Structure

    Science.gov (United States)

    Walczak, Steven

    2005-01-01

    Purpose: To propose and evaluate a novel management structure that encourages knowledge sharing across an organization. Design/methodology/approach: The extant literature on the impact of organizational culture and its link to management structure is examined and used to develop a new knowledge sharing management structure. Roadblocks to…

  9. Hypermedia 1990 structured Hypertext tutorial

    Science.gov (United States)

    Johnson, J. Scott

    1990-01-01

    Hypermedia 1990 structured Hypertext tutorial is presented in the form of view-graphs. The following subject areas are covered: structured hypertext; analyzing hypertext documents for structure; designing structured hypertext documents; creating structured hypertext applications; structuring service and repair documents; maintaining structured hypertext documents; and structured hypertext conclusion.

  10. PRODUCT STRUCTURE DIGITAL MODEL

    Directory of Open Access Journals (Sweden)

    V.M. Sineglazov

    2005-02-01

    Full Text Available  Research results of representation of product structure made by means of CADDS5 computer-aided design (CAD system, Product Data Management Optegra (PDM system and Product Life Cycle Management Wind-chill system (PLM, are examined in this work. Analysis of structure component development and its storage in various systems is carried out. Algorithms of structure transformation required for correct representation of the structure are considered. Management analysis of electronic mockup presentation of the product structure is carried out for Windchill system.

  11. Shell-like structures

    CERN Document Server

    Altenbach, Holm

    2011-01-01

    In this volume, scientists and researchers from industry discuss the new trends in simulation and computing shell-like structures. The focus is put on the following problems: new theories (based on two-dimensional field equations but describing non-classical effects), new constitutive equations (for materials like sandwiches, foams, etc. and which can be combined with the two-dimensional shell equations), complex structures (folded, branching and/or self intersecting shell structures, etc.) and shell-like structures on different scales (for example: nano-tubes) or very thin structures (similar

  12. Basic structural dynamics

    CERN Document Server

    Anderson, James C

    2012-01-01

    A concise introduction to structural dynamics and earthquake engineering Basic Structural Dynamics serves as a fundamental introduction to the topic of structural dynamics. Covering single and multiple-degree-of-freedom systems while providing an introduction to earthquake engineering, the book keeps the coverage succinct and on topic at a level that is appropriate for undergraduate and graduate students. Through dozens of worked examples based on actual structures, it also introduces readers to MATLAB, a powerful software for solving both simple and complex structural d

  13. Materials and structures

    Science.gov (United States)

    Saito, Theodore T.; Langenbeck, Sharon L.; Al-Jamily, Ghanim; Arnold, Joe; Barbee, Troy; Coulter, Dan; Dolgin, Ben; Fichter, Buck; George, Patricia; Gorenstein, Paul

    1992-08-01

    Materials and structures technology covers a wide range of technical areas. Some of the most pertinent issues for the Astrotech 21 missions include dimensionally stable structural materials, advanced composites, dielectric coatings, optical metallic coatings for low scattered light applications, low scattered light surfaces, deployable and inflatable structures (including optical), support structures in 0-g and 1-g environments, cryogenic optics, optical blacks, contamination hardened surfaces, radiation hardened glasses and crystals, mono-metallic telescopes and instruments, and materials characterization. Some specific examples include low coefficients of thermal expansion (CTE) structures (0.01 ppm/K), lightweight thermally stable mirror materials, thermally stable optical assemblies, high reliability/accuracy (1 micron) deployable structures, and characterization of nanometer level behavior of materials/structures for interferometry concepts. Large filled-aperture concepts will require materials with CTE's of 10(exp 9) at 80 K, anti-contamination coatings, deployable and erectable structures, composite materials with CTE's less than 0.01 ppm/K and thermal hysteresis, 0.001 ppm/K. Gravitational detection systems such as LAGOS will require rigid/deployable structures, dimensionally stable components, lightweight materials with low conductivity, and high stability optics. The Materials and Structures panel addressed these issues and the relevance of the Astrotech 21 mission requirements by dividing materials and structures technology into five categories. These categories, the necessary development, and applicable mission/program development phasing are summarized. For each of these areas, technology assessments were made and development plans were defined.

  14. Exotic cluster structures on

    CERN Document Server

    Gekhtman, M; Vainshtein, A

    2017-01-01

    This is the second paper in the series of papers dedicated to the study of natural cluster structures in the rings of regular functions on simple complex Lie groups and Poisson-Lie structures compatible with these cluster structures. According to our main conjecture, each class in the Belavin-Drinfeld classification of Poisson-Lie structures on \\mathcal{G} corresponds to a cluster structure in \\mathcal{O}(\\mathcal{G}). The authors have shown before that this conjecture holds for any \\mathcal{G} in the case of the standard Poisson-Lie structure and for all Belavin-Drinfeld classes in SL_n, n<5. In this paper the authors establish it for the Cremmer-Gervais Poisson-Lie structure on SL_n, which is the least similar to the standard one.

  15. Structural realism beyond physics.

    Science.gov (United States)

    Tulodziecki, Dana

    2016-10-01

    The main purpose of this paper is to test structural realism against (one example from) the historical record. I begin by laying out an existing challenge to structural realism - that of providing an example of a theory exhibiting successful structures that were abandoned - and show that this challenge can be met by the miasma theory of disease. However, rather than concluding that this is an outright counterexample to structural realism, I use this case to show why it is that structural realism, in its current form, has trouble dealing with theories outside physics. I end by making some concrete suggestions for structural realists to pursue if, indeed, they are serious about extending structural realism to other domains.

  16. Reducts of Ramsey structures

    CERN Document Server

    Bodirsky, Manuel

    2011-01-01

    One way of studying a relational structure is to investigate functions which are related to that structure and which leave certain aspects of the structure invariant. Examples are the automorphism group, the self-embedding monoid, the endomorphism monoid, or the polymorphism clone of a structure. Such functions can be particularly well understood when the relational structure is countably infinite and has a first-order definition in another relational structure which has a finite language, is totally ordered and homogeneous, and has the Ramsey property. This is because in this situation, Ramsey theory provides the combinatorial tool for analyzing these functions -- in a certain sense, it allows to represent such functions by functions on finite sets. This is a survey of results in model theory and theoretical computer science obtained recently by the authors in this context. In model theory, we approach the problem of classifying the reducts of countably infinite ordered homogeneous Ramsey structures in a fin...

  17. Improving reversible capacities of high-surface lithium insertion materials – the case of amorphous TiO2

    NARCIS (Netherlands)

    Ganapathy, S.; Basak, S.; Lefering, A.; Rogers, E.; Zandbergen, H.W.; Wagemaker, M.

    2014-01-01

    Chemisorbed water and solvent molecules and their reactivity with components from the electrolyte in high-surface nano-structured electrodes remains a contributing factor toward capacity diminishment on cycling in lithium ion batteries due to the limit in maximum annealing temperature. Here, we repo

  18. Insight into the adsorption and dissociation of water over different CuO(111) surfaces: The effect of surface structures

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Jin; Zhang, Riguang, E-mail: zhangriguang@tyut.edu.cn; Wang, Baojun; Ling, Lixia

    2016-02-28

    Graphical abstract: - Highlights: • OH species is the main product of H{sub 2}O dissociation on CuO(111) surface. • The presence of hydrogen (produced from H{sub 2}O dissociation) is in favor of OH dissociation. • OH species fails to dissociate into H and O on the stoichiometric CuO(111) surface. • Oxygen-vacancy surface is favorable for H{sub 2}O dissociation than the stoichiometric surface. • Oxygen-rich surface is the most favorable for H{sub 2}O dissociation than other two surfaces. - Abstract: Water adsorption and dissociation on solid surfaces play a key role in a variety of industrial processes, a detailed comprehension of this process and the effect of the surface structure will assist in developing the improved catalysts. In this study, the adsorption and dissociation of H{sub 2}O on three different types of CuO(111) surfaces, including the stoichiometric, oxygen-vacancy and oxygen-rich surfaces, have been systematically investigated and compared using density functional theory methods. All possible initial configurations of H{sub 2}O adsorbed on those surfaces with only one coverage have been identified. Our results show that the adsorption ability of H{sub 2}O is substantially weaker than that of the dissociated species (HO, H and O). H{sub 2}O chemisorbs at the Cu{sub SUB}, Cu{sup 2} and Cu{sub SUB} sites of the stoichiometric, oxygen-vacancy and oxygen-rich surfaces, respectively; subsequently, the chemisorption H{sub 2}O dissociates into OH and H species. The dissociation mechanisms of chemisorption H{sub 2}O and the single OH group leading to the final O and H species suggest that the dissociation of single OH species occurs at a higher barrier compared to the dissociation of OH in the presence of neighboring H atom (produced from the initial step of H{sub 2}O dissociation), namely, the presence of H is in favor of OH dissociation, which agrees with the results of charge transfer. However, owing to the significantly high barrier of OH

  19. Robustness of Structures

    DEFF Research Database (Denmark)

    Faber, M.H.; Vrouwenvelder, A.C.W.M.; Sørensen, John Dalsgaard

    2011-01-01

    In 2005, the Joint Committee on Structural Safety (JCSS) together with Working Commission (WC) 1 of the International Association of Bridge and Structural Engineering (IABSE) organized a workshop on robustness of structures. Two important decisions resulted from this workshop, namely the developm......In 2005, the Joint Committee on Structural Safety (JCSS) together with Working Commission (WC) 1 of the International Association of Bridge and Structural Engineering (IABSE) organized a workshop on robustness of structures. Two important decisions resulted from this workshop, namely...... the development of a joint European project on structural robustness under the COST (European Cooperation in Science and Technology) programme and the decision to develop a more elaborate document on structural robustness in collaboration between experts from the JCSS and the IABSE. Accordingly, a project titled...... ‘COST TU0601: Robustness of Structures’ was initiated in February 2007, aiming to provide a platform for exchanging and promoting research in the area of structural robustness and to provide a basic framework, together with methods, strategies and guidelines enhancing robustness of structures...

  20. Structure - Riverine Flow Structure (Dike/Wingdam)

    Data.gov (United States)

    Army Corps of Engineers, Department of the Army, Department of Defense — A natural or man-made flow (or sediment) control structure in a water course or water body such as a dike or weir. This feature should not be used to model a levee....

  1. Exponential Dowling structures

    CERN Document Server

    Ehrenborg, Richard

    2010-01-01

    The notion of exponential Dowling structures is introduced, generalizing Stanley's original theory of exponential structures. Enumerative theory is developed to determine the M\\"obius function of exponential Dowling structures, including a restriction of these structures to elements whose types satisfy a semigroup condition. Stanley's study of permutations associated with exponential structures leads to a similar vein of study for exponential Dowling structures. In particular, for the extended r-divisible partition lattice we show the M\\"obius function is, up to a sign, the number of permutations in the symmetric group on rn+k elements having descent set {r, 2r, ..., nr}. Using Wachs' original EL-labeling of the r-divisible partition lattice, the extended r-divisible partition lattice is shown to be EL-shellable.

  2. Electronic structure, total energies, and STM images of clean and oxygen-covered Al(111)

    DEFF Research Database (Denmark)

    Jacobsen, Joachim; Hammer, Bjørk; Jacobsen, Karsten Wedel

    1995-01-01

    A set of density-functional calculations for clean and O-covered Al(111) are presented. At low O coverages the potential energy surface (PES) of chemisorbed O is investigated. The PES indicates large barriers (0.8 eV) against O diffusion and a large corrugation of the equilibrium O height over...... the Al(111) while only a moderate energy gain (5 eV per atom) is found upon Oz dissociation over the surface. The possible existence of ''hot'' O adatoms after O-2 dissociation is discussed on the basis of the presented PES and existing dynamical simulations on model potentials. At high O coverages...... an attractive O-O interaction is identified together with an enhancement in the dipole moment induced per O atom. Finally, Tersoff-Hamann-type scanning tunneling microscopy (STM) topographs are derived based on the calculated one-electron wave functions and spectra. For the clean Al(111) a theoretical STM...

  3. Predicting the adsorption properties of carbon dioxide corrosion inhibitors using a structure-activity relationship

    Energy Technology Data Exchange (ETDEWEB)

    Kinsella, B.; De Marco, R.; Jefferson, A.; Pejcic, B. [Western Australian Corrosion Research Group, Department of Applied Chemistry, Curtin University of Technology, GPO Box U1987, Perth, 6845, WA (Australia); Durnie, W. [Nalco/Exxon Energy Chemicals Ltd, Hardley, Hythe, Southampton (Australia)

    2004-07-01

    This paper presents a study of the influence of various chemical inhibitors on the corrosion rate of mild steel in brine electrolyte under carbon dioxide conditions. The performances as corrosion inhibitors were fitted to a Temkin adsorption isotherm, and various constants of adsorption (i.e., adsorption equilibrium constants and molecular interaction constants) have been obtained. The inhibitor adsorption mechanism has been discussed in terms of thermodynamics (i.e., {delta}H, {delta}G and {delta}S) and this revealed that some compounds chemisorbed onto the steel electrode. In addition, molecular modelling was undertaken using PCSPARTAN Plus and HyperChem Professional, and the various molecular parameters have been correlated with the thermodynamic adsorption properties of the inhibitors. A four-parameter fit for both negative and positive charged molecules is discussed. (authors)

  4. Origami - Folded Plate Structures

    OpenAIRE

    Buri, Hans Ulrich

    2010-01-01

    This research investigates new methods of designing folded plate structures that can be built with cross-laminated timber panels. Folded plate structures are attractive to both architects and engineers for their structural, spatial, and plastic qualities. Thin surfaces can be stiffened by a series of folds, and thus not only cover space, but also act as load bearing elements. The variation of light and shadow along the folded faces emphasizes the plas...

  5. Catalytic distillation structure

    Science.gov (United States)

    Smith, L.A. Jr.

    1984-04-17

    Catalytic distillation structure is described for use in reaction distillation columns, and provides reaction sites and distillation structure consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and is present with the catalyst component in an amount such that the catalytic distillation structure consists of at least 10 volume % open space. 10 figs.

  6. Advance in structural bioinformatics

    CERN Document Server

    Wei, Dongqing; Zhao, Tangzhen; Dai, Hao

    2014-01-01

    This text examines in detail mathematical and physical modeling, computational methods and systems for obtaining and analyzing biological structures, using pioneering research cases as examples. As such, it emphasizes programming and problem-solving skills. It provides information on structure bioinformatics at various levels, with individual chapters covering introductory to advanced aspects, from fundamental methods and guidelines on acquiring and analyzing genomics and proteomics sequences, the structures of protein, DNA and RNA, to the basics of physical simulations and methods for conform

  7. Structure of Human Adenovirus

    OpenAIRE

    Nemerow, Glen R.; Phoebe L Stewart; Reddy, Vijay S.

    2012-01-01

    A detailed structural analysis of the entire human adenovirus capsid has been stymied by the complexity and size of this 150 MDa macromolecular complex. Over the past 10 years, the steady improvements in viral genome manipulation concomitant with advances in crystallographic techniques and data processing software has allowed structure determination of this virus by X-ray diffraction at 3.5 Å resolution. The virus structure revealed the location, folds, and interactions of major and minor (ce...

  8. Reforming Organizational Structures

    OpenAIRE

    Van de Walle, Steven

    2016-01-01

    textabstractPublic sectors have undergone major transformations. Public sector reform touches upon the core building blocks of the public sector: organizational structures, people and finances. These are objects of reform. This chapter presents and discusses a set of major transformations with regard to organizational structures. It provides readers a fairly comprehensive overview of the key reforms that have taken place in Western public sectors. Structural reforms in the public sector show ...

  9. Auxetic materials and structures

    CERN Document Server

    Lim, Teik-Cheng

    2015-01-01

    This book describes the fundamentals of the mechanics and design of auxetic solids and structures, which possess a negative Poisson’s ratio. It will benefit two groups of readers: (a) industry practitioners, such as product and structural designers, who need to control mechanical stress distributions using auxetic materials, and (b) academic researchers and students who intend to produce structures with unique mechanical and other physical properties using auxetic materials.

  10. Structural elements design manual

    CERN Document Server

    Draycott, Trevor

    2012-01-01

    Gives clear explanations of the logical design sequence for structural elements. The Structural Engineer says: `The book explains, in simple terms, and with many examples, Code of Practice methods for sizing structural sections in timber, concrete,masonry and steel. It is the combination into one book of section sizing methods in each of these materials that makes this text so useful....Students will find this an essential support text to the Codes of Practice in their study of element sizing'.

  11. Organisational structure of Enterprise

    OpenAIRE

    Varenytsya, Maryan

    2015-01-01

    The purpose of the bachelor final work is to identify effective organizational management structure, as well offer advice company branch of JSC "Rostelecom" for the improvement of organizational structure of management. It examines the relevance of the study, defined goals, objectives and methods of research, a review of the literature. This thesis contains information on the main causes of changes in the organizational structure of the enterprise management, the design of the organizational ...

  12. Valency and molecular structure

    CERN Document Server

    Cartmell, E

    1977-01-01

    Valency and Molecular Structure, Fourth Edition provides a comprehensive historical background and experimental foundations of theories and methods relating to valency and molecular structures. In this edition, the chapter on Bohr theory has been removed while some sections, such as structures of crystalline solids, have been expanded. Details of structures have also been revised and extended using the best available values for bond lengths and bond angles. Recent developments are mostly noted in the chapter on complex compounds, while a new chapter has been added to serve as an introduction t

  13. Linguistic Structure Prediction

    CERN Document Server

    Smith, Noah A

    2011-01-01

    A major part of natural language processing now depends on the use of text data to build linguistic analyzers. We consider statistical, computational approaches to modeling linguistic structure. We seek to unify across many approaches and many kinds of linguistic structures. Assuming a basic understanding of natural language processing and/or machine learning, we seek to bridge the gap between the two fields. Approaches to decoding (i.e., carrying out linguistic structure prediction) and supervised and unsupervised learning of models that predict discrete structures as outputs are the focus. W

  14. Structural Precast Concrete Handbook

    DEFF Research Database (Denmark)

    Kjærbye, Per Oluf H

    Structural concept for precast concrete systems. Design og precast reinforced concrete components. Design of precast concrete connections. Illustrations on design of precast concrete buildings. Precast concrete assembly....

  15. Structural Dynamics Laboratory (SDL)

    Data.gov (United States)

    Federal Laboratory Consortium — Structural dynamic testing is performed to verify the survivability of a component or assembly when exposed to vibration stress screening, or a controlled simulation...

  16. Machine tool structures

    CERN Document Server

    Koenigsberger, F

    1970-01-01

    Machine Tool Structures, Volume 1 deals with fundamental theories and calculation methods for machine tool structures. Experimental investigations into stiffness are discussed, along with the application of the results to the design of machine tool structures. Topics covered range from static and dynamic stiffness to chatter in metal cutting, stability in machine tools, and deformations of machine tool structures. This volume is divided into three sections and opens with a discussion on stiffness specifications and the effect of stiffness on the behavior of the machine under forced vibration c

  17. Flexible Volumetric Structure

    Science.gov (United States)

    Cagle, Christopher M. (Inventor); Schlecht, Robin W. (Inventor)

    2014-01-01

    A flexible volumetric structure has a first spring that defines a three-dimensional volume and includes a serpentine structure elongatable and compressible along a length thereof. A second spring is coupled to at least one outboard edge region of the first spring. The second spring is a sheet-like structure capable of elongation along an in-plane dimension thereof. The second spring is oriented such that its in-plane dimension is aligned with the length of the first spring's serpentine structure.

  18. Laboratory for Structural Acoustics

    Data.gov (United States)

    Federal Laboratory Consortium — FUNCTION: Supports experimental research where acoustic radiation, scattering, and surface vibration measurements of fluid-loaded and non-fluid-loaded structures are...

  19. Deployable Soft Composite Structures

    Science.gov (United States)

    Wang, Wei; Rodrigue, Hugo; Ahn, Sung-Hoon

    2016-02-01

    Deployable structure composed of smart materials based actuators can reconcile its inherently conflicting requirements of low mass, good shape adaptability, and high load-bearing capability. This work describes the fabrication of deployable structures using smart soft composite actuators combining a soft matrix with variable stiffness properties and hinge-like movement through a rigid skeleton. The hinge actuator has the advantage of being simple to fabricate, inexpensive, lightweight and simple to actuate. This basic actuator can then be used to form modules capable of different types of deformations, which can then be assembled into deployable structures. The design of deployable structures is based on three principles: design of basic hinge actuators, assembly of modules and assembly of modules into large-scale deployable structures. Various deployable structures such as a segmented triangular mast, a planar structure comprised of single-loop hexagonal modules and a ring structure comprised of single-loop quadrilateral modules were designed and fabricated to verify this approach. Finally, a prototype for a deployable mirror was developed by attaching a foldable reflective membrane to the designed ring structure and its functionality was tested by using it to reflect sunlight onto to a small-scale solar panel.

  20. Deployable Soft Composite Structures.

    Science.gov (United States)

    Wang, Wei; Rodrigue, Hugo; Ahn, Sung-Hoon

    2016-02-19

    Deployable structure composed of smart materials based actuators can reconcile its inherently conflicting requirements of low mass, good shape adaptability, and high load-bearing capability. This work describes the fabrication of deployable structures using smart soft composite actuators combining a soft matrix with variable stiffness properties and hinge-like movement through a rigid skeleton. The hinge actuator has the advantage of being simple to fabricate, inexpensive, lightweight and simple to actuate. This basic actuator can then be used to form modules capable of different types of deformations, which can then be assembled into deployable structures. The design of deployable structures is based on three principles: design of basic hinge actuators, assembly of modules and assembly of modules into large-scale deployable structures. Various deployable structures such as a segmented triangular mast, a planar structure comprised of single-loop hexagonal modules and a ring structure comprised of single-loop quadrilateral modules were designed and fabricated to verify this approach. Finally, a prototype for a deployable mirror was developed by attaching a foldable reflective membrane to the designed ring structure and its functionality was tested by using it to reflect sunlight onto to a small-scale solar panel.

  1. Bioinspired structural materials

    Science.gov (United States)

    Wegst, Ulrike G. K.; Bai, Hao; Saiz, Eduardo; Tomsia, Antoni P.; Ritchie, Robert O.

    2015-01-01

    Natural structural materials are built at ambient temperature from a fairly limited selection of components. They usually comprise hard and soft phases arranged in complex hierarchical architectures, with characteristic dimensions spanning from the nanoscale to the macroscale. The resulting materials are lightweight and often display unique combinations of strength and toughness, but have proven difficult to mimic synthetically. Here, we review the common design motifs of a range of natural structural materials, and discuss the difficulties associated with the design and fabrication of synthetic structures that mimic the structural and mechanical characteristics of their natural counterparts.

  2. Nuclear structure theory

    CERN Document Server

    Irvine, J M

    1972-01-01

    Nuclear Structure Theory provides a guide to nuclear structure theory. The book is comprised of 23 chapters that are organized into four parts; each part covers an aspect of nuclear structure theory. In the first part, the text discusses the experimentally observed phenomena, which nuclear structure theories need to look into and detail the information that supports those theories. The second part of the book deals with the phenomenological nucleon-nucleon potentials derived from phase shift analysis of nucleon-nucleon scattering. Part III talks about the phenomenological parameters used to de

  3. Roadmap on structured light

    Science.gov (United States)

    Rubinsztein-Dunlop, Halina; Forbes, Andrew; Berry, M. V.; Dennis, M. R.; Andrews, David L.; Mansuripur, Masud; Denz, Cornelia; Alpmann, Christina; Banzer, Peter; Bauer, Thomas; Karimi, Ebrahim; Marrucci, Lorenzo; Padgett, Miles; Ritsch-Marte, Monika; Litchinitser, Natalia M.; Bigelow, Nicholas P.; Rosales-Guzmán, C.; Belmonte, A.; Torres, J. P.; Neely, Tyler W.; Baker, Mark; Gordon, Reuven; Stilgoe, Alexander B.; Romero, Jacquiline; White, Andrew G.; Fickler, Robert; Willner, Alan E.; Xie, Guodong; McMorran, Benjamin; Weiner, Andrew M.

    2017-01-01

    Structured light refers to the generation and application of custom light fields. As the tools and technology to create and detect structured light have evolved, steadily the applications have begun to emerge. This roadmap touches on the key fields within structured light from the perspective of experts in those areas, providing insight into the current state and the challenges their respective fields face. Collectively the roadmap outlines the venerable nature of structured light research and the exciting prospects for the future that are yet to be realized.

  4. Probabilistic conditional independence structures

    CERN Document Server

    Studeny, Milan

    2005-01-01

    Probabilistic Conditional Independence Structures provides the mathematical description of probabilistic conditional independence structures; the author uses non-graphical methods of their description, and takes an algebraic approach.The monograph presents the methods of structural imsets and supermodular functions, and deals with independence implication and equivalence of structural imsets.Motivation, mathematical foundations and areas of application are included, and a rough overview of graphical methods is also given.In particular, the author has been careful to use suitable terminology, and presents the work so that it will be understood by both statisticians, and by researchers in artificial intelligence.The necessary elementary mathematical notions are recalled in an appendix.

  5. Structural patterns in nature

    DEFF Research Database (Denmark)

    Wester, Ture

    2004-01-01

    It seems that some very basic randomly produced geometric/topological patterns are commonly found in Nature and have often very distinctive structural qualities. In nature we find the same pattern in all scales from the universe to molecules, from solar systems to packing of cells, from glaciers...... to sea shells, from river systems to trees etc. Sometimes this seeming archetypical morphology involve structural action and sometimes not - but the fact that it often posses efficient structural action opens a tool for evaluation and analyses of structures in nature and at the same time might...

  6. Stable umbral chromospheric structures

    Science.gov (United States)

    Henriques, V. M. J.; Scullion, E.; Mathioudakis, M.; Kiselman, D.; Gallagher, P. T.; Keenan, F. P.

    2015-02-01

    Aims: We seek to understand the morphology of the chromosphere in sunspot umbra. We investigate if the horizontal structures observed in the spectral core of the Ca II H line are ephemeral visuals caused by the shock dynamics of more stable structures, and examine their relationship with observables in the H-alpha line. Methods: Filtergrams in the core of the Ca II H and H-alpha lines as observed with the Swedish 1-m Solar Telescope are employed. We utilise a technique that creates composite images and tracks the flash propagation horizontally. Results: We find 0.̋15 wide horizontal structures, in all of the three target sunspots, for every flash where the seeing is moderate to good. Discrete dark structures are identified that are stable for at least two umbral flashes, as well as systems of structures that live for up to 24 min. We find cases of extremely extended structures with similar stability, with one such structure showing an extent of 5''. Some of these structures have a correspondence in H-alpha, but we were unable to find a one-to-one correspondence for every occurrence. If the dark streaks are formed at the same heights as umbral flashes, there are systems of structures with strong departures from the vertical for all three analysed sunspots. Conclusions: Long-lived Ca II H filamentary horizontal structures are a common and likely ever-present feature in the umbra of sunspots. If the magnetic field in the chromosphere of the umbra is indeed aligned with the structures, then the present theoretical understanding of the typical umbra needs to be revisited. Movies associated to Figs. 3 and 4 are available in electronic form at http://www.aanda.org

  7. Organisational Structure & Change

    Science.gov (United States)

    National Centre for Vocational Education Research (NCVER), 2006

    2006-01-01

    Structural change is seen as a way to meet the challenges of the future that face many organisations. While some writers agree that broad-ranging structural change may not always transform an organisation or enhance its performance, others claim that innovation will be a major source of competitive advantage to organisations, particularly when…

  8. The Structure of Reciprocity

    Science.gov (United States)

    Molm, Linda D.

    2010-01-01

    Reciprocity is one of the defining features of social exchange and social life, yet exchange theorists have tended to take it for granted. Drawing on work from a decade-long theoretical research program, I argue that reciprocity is structured and variable across different forms of exchange, that these variations in the structure of reciprocity…

  9. Tapered structure construction

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Eric D.; Takata, Rosalind K.; Slocum, Alexander H.; Nayfeh, Samir A.

    2016-04-05

    Feeding stock used to form a tapered structure into a curving device such that each point on the stock undergoes rotational motion about a peak location of the tapered structure; and the stock meets a predecessor portion of stock along one or more adjacent edges.

  10. Wave scour around structures

    DEFF Research Database (Denmark)

    Sumer, B. Mutlu; Fredsøe, Jørgen

    1999-01-01

    This review (of scour around marine structures) is organized in seven main sections: Basic concepts; Tunnel erosion; Two- and three-dimensional scour around pipelines; Scour around piles (slender bodies), including pile groups; Scour around complex structures; Scour around large, vertical cylinde......; and Scour around breakwaters (vertical-wall breakwaters and rubble-mound breakwaters)....

  11. Neutrinos and nucleon structure

    CERN Document Server

    Sehgal, L M

    1979-01-01

    The study of neutrino interactions in matter is yielding a wealth of information on the form factors and structure functions of the nucleon. These data allow tests of models of nucleon structure and of dynamical theories of quarks and gluons. The author attempts a critical appraisal of recent facts and their impact on our theoretical understanding. (35 refs).

  12. The Cambridge Structural Database.

    Science.gov (United States)

    Groom, Colin R; Bruno, Ian J; Lightfoot, Matthew P; Ward, Suzanna C

    2016-04-01

    The Cambridge Structural Database (CSD) contains a complete record of all published organic and metal-organic small-molecule crystal structures. The database has been in operation for over 50 years and continues to be the primary means of sharing structural chemistry data and knowledge across disciplines. As well as structures that are made public to support scientific articles, it includes many structures published directly as CSD Communications. All structures are processed both computationally and by expert structural chemistry editors prior to entering the database. A key component of this processing is the reliable association of the chemical identity of the structure studied with the experimental data. This important step helps ensure that data is widely discoverable and readily reusable. Content is further enriched through selective inclusion of additional experimental data. Entries are available to anyone through free CSD community web services. Linking services developed and maintained by the CCDC, combined with the use of standard identifiers, facilitate discovery from other resources. Data can also be accessed through CCDC and third party software applications and through an application programming interface.

  13. Periodic truss structures

    Science.gov (United States)

    Zok, Frank W.; Latture, Ryan M.; Begley, Matthew R.

    2016-11-01

    Despite the recognition of the enormous potential of periodic trusses for use in a broad range of technologies, there are no widely-accepted descriptors of their structure. The terminology has been based loosely either on geometry of polyhedra or of point lattices: neither of which, on its own, has an appropriate structure to fully define periodic trusses. The present article lays out a system for classification of truss structure types. The system employs concepts from crystallography and geometry to describe nodal locations and connectivity of struts. Through a series of illustrative examples of progressively increasing complexity, a rational taxonomy of truss structure is developed. Its conceptual evolution begins with elementary cubic trusses, increasing in complexity with non-cubic and compound trusses as well as supertrusses, and, finally, with complex trusses. The conventions and terminology adopted to define truss structure yield concise yet unambiguous descriptions of structure types and of specific (finite) trusses. The utility of the taxonomy is demonstrated by bringing into alignment a disparate set of ad hoc and incomplete truss designations previously employed in a broad range of science and engineering fields. Additionally, the merits of a particular compound truss (comprising two interpenetrating elementary trusses) is shown to be superior to the octet truss for applications requiring high stiffness and elastic isotropy. By systematically stepping through and analyzing the finite number of structure types identified through the present classification system, optimal structures for prescribed mechanical and functional requirements are expected to be ascertained in an expeditious manner.

  14. Structures of Mn clusters

    Indian Academy of Sciences (India)

    Tina M Briere; Marcel H F Sluiter; Vijay Kumar; Yoshiyuki Kawazoe

    2003-01-01

    The geometries of several Mn clusters in the size range Mn13–Mn23 are studied via the generalized gradient approximation to density functional theory. For the 13- and 19-atom clusters, the icosahedral structures are found to be most stable, while for the 15-atom cluster, the bcc structure is more favoured. The clusters show ferrimagnetic spin configurations.

  15. Lightweight Composite Intertank Structure

    Science.gov (United States)

    Mehle, Greg V.

    1995-01-01

    Report presents results of study for proposed lightweight composite material alternative to present semimonocoque aluminum intertank structure for advanced launch vehicles. Proposed structure integrated assembly of sandwich panels made of laminated epoxy-matrix/carbon-fiber skins, and aluminum honeycomb core.

  16. Structural Precast Concrete Handbook

    DEFF Research Database (Denmark)

    Kjærbye, Per Oluf H

    Structural concept for precast concrete systems. Design og precast reinforced concrete components. Design of precast concrete connections. Illustrations on design of precast concrete buildings. Precast concrete assembly.......Structural concept for precast concrete systems. Design og precast reinforced concrete components. Design of precast concrete connections. Illustrations on design of precast concrete buildings. Precast concrete assembly....

  17. Magnetic Nano-structures

    Institute of Scientific and Technical Information of China (English)

    姚永德

    2004-01-01

    Fabrication of magnetic nano-structures with dots array and wires has been paid attention recently due to the application of high-density magnetic recording. In this study, we fabricated the magnetic dots array and wires through several ways that ensure the arrangement of magnetic dots and wires to be the structures we designed. Their magnetic properties are studied experimentally.

  18. Hierarchical Porous Structures

    Energy Technology Data Exchange (ETDEWEB)

    Grote, Christopher John [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-06-07

    Materials Design is often at the forefront of technological innovation. While there has always been a push to generate increasingly low density materials, such as aero or hydrogels, more recently the idea of bicontinuous structures has gone more into play. This review will cover some of the methods and applications for generating both porous, and hierarchically porous structures.

  19. Fire exposed aluminium structures

    NARCIS (Netherlands)

    Maljaars, J.; Fellinger, J.H.H.; Soetens, F.

    2006-01-01

    Material properties and mechanical response models for fire design of steel structures are based on extensive research and experience. Contrarily, the behaviour of aluminium load bearing structures exposed to fire is relatively unexplored. This article gives an overview of physical and mechanical pr

  20. Solution structure of (+)-discodermolide.

    Science.gov (United States)

    Smith, A B; LaMarche, M J; Falcone-Hindley, M

    2001-03-01

    [structure: see text]. The solution structure of (+)-discodermolide (1) has been determined via 1- and 2-D NMR techniques in conjunction with Monte Carlo conformational analysis. Taken together, the results demonstrate that in solution (+)-discodermolide occupies a helical conformation remarkably similar to the solid state conformation.

  1. Hedging structured concepts

    NARCIS (Netherlands)

    Koolen, W.M.; Warmuth, M.K.; Kivinen, J.; Kalai, A.T.; Mohri, M.

    2010-01-01

    We develop an online algorithm called Component Hedge for learning structured concept classes when the loss of a structured concept sums over its components. Example classes include paths through a graph (composed of edges) and partial permutations (composed of assignments). The algorithm maintains

  2. Describing migration spatial structure

    NARCIS (Netherlands)

    Rogers, A; Willekens, F; Little, J; Raymer, J

    The age structure of a population is a fundamental concept in demography and is generally depicted in the form of an age pyramid. The spatial structure of an interregional system of origin-destination-specific migration streams is, however, a notion lacking a widely accepted definition. We offer a

  3. Structure sensitivity in adsorption

    DEFF Research Database (Denmark)

    Hammer, Bjørk; Nielsen, Ole Holm; Nørskov, Jens Kehlet

    1997-01-01

    The structure sensitivity of CO adsorption on different flat, stepped, kinked and reconstructed Pt surfaces is studied using large-scale density-functional calculations. We find an extremely strong structure sensitivity in the adsorption energy with variations up to 1 eV (or 100%) from one...

  4. Shipping Industry Structure

    NARCIS (Netherlands)

    Wijnolst, N.; Waals, F.

    1999-01-01

    Understanding Shipping Management requires a thorough understanding of the Shipping Industry Structure. This book provides this knowledge base and should be seen in conjunction with two other books: Shipping and Design Innovation in Shipping. Shipping Industry Structure was intended as the first par

  5. Wave scour around structures

    DEFF Research Database (Denmark)

    Sumer, B. Mutlu; Fredsøe, Jørgen

    1999-01-01

    This review (of scour around marine structures) is organized in seven main sections: Basic concepts; Tunnel erosion; Two- and three-dimensional scour around pipelines; Scour around piles (slender bodies), including pile groups; Scour around complex structures; Scour around large, vertical cylinders......; and Scour around breakwaters (vertical-wall breakwaters and rubble-mound breakwaters)....

  6. Piaget's Structural Developmental Psychology.

    Science.gov (United States)

    Broughton, John M.

    1981-01-01

    Piaget's theory is identified as a branch of structuralism concerned with the concept of truth, in distinction from French structuralism, which is focused on meaning. The two branches are compared and contrasted, and relations between logic and language are explored. Similarities and differences in the theories of Piaget, Levi-Strauss, and Chomsky…

  7. Robustness of structures

    DEFF Research Database (Denmark)

    Vrouwenvelder, T.; Sørensen, John Dalsgaard

    2009-01-01

    robustness is still an issue of controversy and poses difficulties in regard to interpretation as well as regulation. Typically modern structural design codes require that ‘the consequence of damages to structures should not be disproportional to the causes of the damages'. However, despite the importance...

  8. Structural Crashworthiness and Failure

    Science.gov (United States)

    1993-04-16

    structures en materiaux composite. VDI-Bericht Nr 369, 1980. 46. Kirsch, P. A. & Jahnle, H. A., Energy absorption of glass-polyester structures. SAE...materials in the automotive industry. They built two cabins, one equipped with front and rear suspension , steering assembly, rear engine, seats, outer skin

  9. Generalized holomorphic structures

    Science.gov (United States)

    Wang, Yicao

    2014-12-01

    We define the notion of generalized holomorphic principal bundles and establish that their associated vector bundles of holomorphic representations are generalized holomorphic vector bundles defined by M. Gualtieri. Motivated by our definition, several examples of generalized holomorphic structures are constructed. A reduction theorem of generalized holomorphic structures is also included.

  10. Shipping Industry Structure

    NARCIS (Netherlands)

    Wijnolst, N.; Waals, F.

    1999-01-01

    Understanding Shipping Management requires a thorough understanding of the Shipping Industry Structure. This book provides this knowledge base and should be seen in conjunction with two other books: Shipping and Design Innovation in Shipping. Shipping Industry Structure was intended as the first par

  11. Shipping Industry Structure

    NARCIS (Netherlands)

    Wijnolst, N.; Waals, F.

    1999-01-01

    Understanding Shipping Management requires a thorough understanding of the Shipping Industry Structure. This book provides this knowledge base and should be seen in conjunction with two other books: Shipping and Design Innovation in Shipping. Shipping Industry Structure was intended as the first

  12. Dynamic term structure models

    DEFF Research Database (Denmark)

    Andreasen, Martin Møller; Meldrum, Andrew

    This paper studies whether dynamic term structure models for US nominal bond yields should enforce the zero lower bound by a quadratic policy rate or a shadow rate specification. We address the question by estimating quadratic term structure models (QTSMs) and shadow rate models with at most four...

  13. Buckling of Ship Structures

    CERN Document Server

    Shama, Mohamed

    2013-01-01

    Buckling of Ship Structures presents a comprehensive analysis of the buckling problem of ship structural members. A full analysis of the various types of loadings and stresses imposed on ship plating and primary and secondary structural members is given. The main causes and consequences of the buckling mode of failure of ship structure and the methods commonly used to control buckling failure are clarified. This book contains the main equations required to determine the critical buckling stresses for both ship plating and the primary and secondary stiffening structural members. The critical buckling stresses are given for ship plating subjected to the induced various types of loadings and having the most common boundary conditions encountered in ship structures.  The text bridges the gap existing in most books covering the subject of buckling of ship structures in the classical analytical format, by putting the emphasis on the practical methods required to ensure safety against buckling of ship structur...

  14. Product Structuring, an overview

    DEFF Research Database (Denmark)

    Tichem, Marcel; Storm, Ton; Andreasen, Mogens Myrup;

    1997-01-01

    This paper presents the highlights of two WDK Workshops on Product Structuring. Product structuring plays an important role in creating products which have good functional and life-cycle related properties, in design process management, and in several other company functions like production control...

  15. Fire exposed aluminium structures

    NARCIS (Netherlands)

    Maljaars, J.; Fellinger, J.H.H.; Soetens, F.

    2006-01-01

    Material properties and mechanical response models for fire design of steel structures are based on extensive research and experience. Contrarily, the behaviour of aluminium load bearing structures exposed to fire is relatively unexplored. This article gives an overview of physical and mechanical

  16. Describing migration spatial structure

    NARCIS (Netherlands)

    Rogers, A; Willekens, F; Little, J; Raymer, J

    2002-01-01

    The age structure of a population is a fundamental concept in demography and is generally depicted in the form of an age pyramid. The spatial structure of an interregional system of origin-destination-specific migration streams is, however, a notion lacking a widely accepted definition. We offer a d

  17. Cosmic structure formation

    Science.gov (United States)

    Bertschinger, Edumund

    1994-01-01

    This article reviews the prevailing paradigm for how galaxies and larger structures formed in the universe: gravitational instability. Basic observational facts are summarized to motivate the standard cosmological framework underlying most detailed investigations of structure formation. The observed univers approaches spatial uniformity on scales larger than about 10(exp 26) cm. On these scales gravitational dynamics is almost linear and therefore relatively easy to relate to observations of large-scale structure. On smaller scales cosmic structure is complicated not only by nonlinear gravitational clustering but also by nonlinear nongravitational gas dynamical processes. The complexity of these phenomena makes galaxy formation one of the grand challenge problems of the physical sciences. No fully satisfactory theory can presently account in detail for the observed cosmic structure. However, as this article summarizes, significant progress has been made during the last few years.

  18. Iconicity as structure mapping.

    Science.gov (United States)

    Emmorey, Karen

    2014-09-19

    Linguistic and psycholinguistic evidence is presented to support the use of structure-mapping theory as a framework for understanding effects of iconicity on sign language grammar and processing. The existence of structured mappings between phonological form and semantic mental representations has been shown to explain the nature of metaphor and pronominal anaphora in sign languages. With respect to processing, it is argued that psycholinguistic effects of iconicity may only be observed when the task specifically taps into such structured mappings. In addition, language acquisition effects may only be observed when the relevant cognitive abilities are in place (e.g. the ability to make structural comparisons) and when the relevant conceptual knowledge has been acquired (i.e. information key to processing the iconic mapping). Finally, it is suggested that iconicity is better understood as a structured mapping between two mental representations than as a link between linguistic form and human experience.

  19. Nonlinear dynamics of structures

    CERN Document Server

    Oller, Sergio

    2014-01-01

    This book lays the foundation of knowledge that will allow a better understanding of nonlinear phenomena that occur in structural dynamics.   This work is intended for graduate engineering students who want to expand their knowledge on the dynamic behavior of structures, specifically in the nonlinear field, by presenting the basis of dynamic balance in non‐linear behavior structures due to the material and kinematics mechanical effects.   Particularly, this publication shows the solution of the equation of dynamic equilibrium for structure with nonlinear time‐independent materials (plasticity, damage and frequencies evolution), as well as those time dependent non‐linear behavior materials (viscoelasticity and viscoplasticity). The convergence conditions for the non‐linear dynamic structure solution  are studied, and the theoretical concepts and its programming algorithms are presented.  

  20. Regularized Structural Equation Modeling.

    Science.gov (United States)

    Jacobucci, Ross; Grimm, Kevin J; McArdle, John J

    A new method is proposed that extends the use of regularization in both lasso and ridge regression to structural equation models. The method is termed regularized structural equation modeling (RegSEM). RegSEM penalizes specific parameters in structural equation models, with the goal of creating easier to understand and simpler models. Although regularization has gained wide adoption in regression, very little has transferred to models with latent variables. By adding penalties to specific parameters in a structural equation model, researchers have a high level of flexibility in reducing model complexity, overcoming poor fitting models, and the creation of models that are more likely to generalize to new samples. The proposed method was evaluated through a simulation study, two illustrative examples involving a measurement model, and one empirical example involving the structural part of the model to demonstrate RegSEM's utility.

  1. Socio-Technical Structure

    DEFF Research Database (Denmark)

    Rose, Jeremy; Lindgren, Rikard; Henfridsson, Ole

    2004-01-01

    a reference discipline in its own right (in other words a theory exporter), this paper offers an example of integrative theory development. Instead of adapting a theory from another discipline or building a theory from empirical data, we examine the structure concept in some of its various theoretical...... adaptations in IS and try to integrate them to produce theory that focuses on IS concerns whilst resolving some of the major areas of contention. Both social and technological versions of structure are investigated through three theoretical IS perspectives drawn from different reference disciplines. The first...... perspective relates to social theories (principally structuration theory), the second to linguistic theories (principally the structural linguistics of Chomsky), and the last to science studies (principally actor-network theory). The objective is to study areas of agreement and contention around the structure...

  2. Optoelectronic Mounting Structure

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, Gene R. (Albuquerque, NM); Armendariz, Marcelino G. (Albuquerque, NM); Baca, Johnny R. F. (Albuquerque, NM); Bryan, Robert P. (Albuquerque, NM); Carson, Richard F. (Albuquerque, NM); Chu, Dahwey (Albuquerque, NM); Duckett, III, Edwin B. (Albuquerque, NM); McCormick, Frederick B. (Albuquerque, NM); Peterson, David W. (Sandia Park, NM); Peterson, Gary D. (Albuquerque, NM); Reber, Cathleen A. (Corrales, NM); Reysen, Bill H. (Lafayette, CO)

    2004-10-05

    An optoelectronic mounting structure is provided that may be used in conjunction with an optical transmitter, receiver or transceiver module. The mounting structure may be a flexible printed circuit board. Thermal vias or heat pipes in the head region may transmit heat from the mounting structure to the heat spreader. The heat spreader may provide mechanical rigidity or stiffness to the heat region. In another embodiment, an electrical contact and ground plane may pass along a surface of the head region so as to provide an electrical contact path to the optoelectronic devices and limit electromagnetic interference. In yet another embodiment, a window may be formed in the head region of the mounting structure so as to provide access to the heat spreader. Optoelectronic devices may be adapted to the heat spreader in such a manner that the devices are accessible through the window in the mounting structure.

  3. On Granular Knowledge Structures

    CERN Document Server

    Zeng, Yi

    2008-01-01

    Knowledge plays a central role in human and artificial intelligence. One of the key characteristics of knowledge is its structured organization. Knowledge can be and should be presented in multiple levels and multiple views to meet people's needs in different levels of granularities and from different perspectives. In this paper, we stand on the view point of granular computing and provide our understanding on multi-level and multi-view of knowledge through granular knowledge structures (GKS). Representation of granular knowledge structures, operations for building granular knowledge structures and how to use them are investigated. As an illustration, we provide some examples through results from an analysis of proceeding papers. Results show that granular knowledge structures could help users get better understanding of the knowledge source from set theoretical, logical and visual point of views. One may consider using them to meet specific needs or solve certain kinds of problems.

  4. Effect of pH and chemical mechanical planarization process conditions on the copper-benzotriazole complex formation

    Science.gov (United States)

    Cho, Byoung-Jun; Kim, Jin-Yong; Hamada, Satomi; Shima, Shohei; Park, Jin-Goo

    2016-06-01

    Benzotriazole (BTA) has been used to protect copper (Cu) from corrosion during Cu chemical mechanical planarization (CMP) processes. However, an undesirable Cu-BTA complex is deposited after Cu CMP processes and it should be completely removed at post-Cu CMP cleaning for next fabrication process. Therefore, it is very important to understand of Cu-BTA complex formation behavior for its applications such as Cu CMP and post-Cu CMP cleaning. The present study investigated the effect of pH and polisher conditions on the formation of Cu-BTA complex layers using electrochemical techniques (potentiodynamic polarization and electrochemical impedance spectroscopy) and the surface contact angle. The wettability was not a significant factor for the polishing interface, as no difference in the contact angles was observed for these processes. Both electrochemical techniques revealed that BTA had a unique advantage of long-term protection for Cu corrosion in an acidic condition (pH 3).

  5. DISCUSSIONS ON STRUCTURAL COUPLING

    Institute of Scientific and Technical Information of China (English)

    ZHU Wenbin; GUO Lingzhi; MA Ruishi; SUN Yan; WANG Feng

    2004-01-01

    The structural coupling is a common geological phenomenon. The structural differences between eastern and western active continental margins of modern Pacific and between paleo-Pacific and modern-Pacific continental margins are related to the characteristics and status of the subducting oceanic plate, namely, 1. subducting angle; 2. change in subducting angle; 3. subducting velocity; 4. change in subducting velocity; 5. subduction depth; 6. horizontal distance between the leading edge of the subducting plate and the trench; 7. the structural form of the subducting plate at the 670km boundary between the upper and lower mantle; 8. the displacement and the direction of displacement of subducting plate. The control and influence toward the shallow-level structures by the deep-level structural activities is a detailed representation of the structural coupling on active continental margin.The basin-maintain coupling phenomenon is an intracontinental structural coupling. The far field effect of collision between Indian plate and Eurasian plate results in the occurrence of intracontinental A-type subduction in central Asia, and the A-type subduction is the key factor that results in the atrophy of basins and the formation of mountain systems.

  6. Cell packing structures

    KAUST Repository

    Pottmann, Helmut

    2015-03-03

    This paper is an overview of architectural structures which are either composed of polyhedral cells or closely related to them. We introduce the concept of a support structure of such a polyhedral cell packing. It is formed by planar quads and obtained by connecting corresponding vertices in two combinatorially equivalent meshes whose corresponding edges are coplanar and thus determine planar quads. Since corresponding triangle meshes only yield trivial structures, we focus on support structures associated with quad meshes or hex-dominant meshes. For the quadrilateral case, we provide a short survey of recent research which reveals beautiful relations to discrete differential geometry. Those are essential for successfully initializing numerical optimization schemes for the computation of quad-based support structures. Hex-dominant structures may be designed via Voronoi tessellations, power diagrams, sphere packings and various extensions of these concepts. Apart from the obvious application as load-bearing structures, we illustrate here a new application to shading and indirect lighting. On a higher level, our work emphasizes the interplay between geometry, optimization, statics, and manufacturing, with the overall aim of combining form, function and fabrication into novel integrated design tools.

  7. Chromatin Structure and Function

    CERN Document Server

    Wolffe, Alan P

    1999-01-01

    The Third Edition of Chromatin: Structure and Function brings the reader up-to-date with the remarkable progress in chromatin research over the past three years. It has been extensively rewritten to cover new material on chromatin remodeling, histone modification, nuclear compartmentalization, DNA methylation, and transcriptional co-activators and co-repressors. The book is written in a clear and concise fashion, with 60 new illustrations. Chromatin: Structure and Function provides the reader with a concise and coherent account of the nature, structure, and assembly of chromatin and its active

  8. Deployable geodesic truss structure

    Science.gov (United States)

    Mikulas, Martin M., Jr. (Inventor); Rhodes, Marvin D. (Inventor); Simonton, J. Wayne (Inventor)

    1987-01-01

    A deployable geodesic truss structure which can be deployed from a stowed state to an erected state is described. The truss structure includes a series of bays, each bay having sets of battens connected by longitudinal cross members which give the bay its axial and torsional stiffness. The cross members are hinged at their mid point by a joint so that the cross members are foldable for deployment or collapsing. The bays are deployed and stabilized by actuator means connected between the mid point joints of the cross members. Hinged longerons may be provided to also connect the sets of battens and to collapse for stowing with the rest of the truss structure.

  9. Wind Loads on Structures

    DEFF Research Database (Denmark)

    Dyrbye, Claes; Hansen, Svend Ole

    pressure to structural response) and design criteria. Starting with an introduction of the wind load chain, the book moves on to meteorological considerations, atmospheric boundary layer, static wind load, dynamic wind load and scaling laws used in wind-tunnel tests. The dynamic wind load covers vibrations......Wind loads have to be taken into account when designing civil engineering structures. The wind load on structures can be systematised by means of the wind load chain: wind climate (global), terrain (wind at low height), aerodynamic response (wind load to pressure), mechanical response (wind...

  10. Wind Loads on Structures

    DEFF Research Database (Denmark)

    Dyrbye, Claes; Hansen, Svend Ole

    pressure to structural response) and design criteria. Starting with an introduction of the wind load chain, the book moves on to meteorological considerations, atmospheric boundary layer, static wind load, dynamic wind load and scaling laws used in wind-tunnel tests. The dynamic wind load covers vibrations......Wind loads have to be taken into account when designing civil engineering structures. The wind load on structures can be systematised by means of the wind load chain: wind climate (global), terrain (wind at low height), aerodynamic response (wind load to pressure), mechanical response (wind...

  11. Robustness of Structures

    DEFF Research Database (Denmark)

    Sørensen, John Dalsgaard

    2011-01-01

    robust design as well as strategies for maintaining the robustness of existing structures throughout their service life. This paper describes an overall theoretical framework for assessing robustness of structures developed within WG1 “Robustness of structures”. Robustness can be defined in different......An important aspect of the COST Action TU0601 “Robustness of structures” concerns the development of a theoretically sound basis for the assessment of robustness and acceptance criteria for structural robustness which can form the basis for development of practical relevant methods for ensuring...

  12. Structural Reliability Methods

    DEFF Research Database (Denmark)

    Ditlevsen, Ove Dalager; Madsen, H. O.

    of structural reliability, including the theoretical basis for these methods. Partial safety factor codes under current practice are briefly introduced and discussed. A probabilistic code format for obtaining a formal reliability evaluation system that catches the most essential features of the nature......The structural reliability methods quantitatively treat the uncertainty of predicting the behaviour and properties of a structure given the uncertain properties of its geometry, materials, and the actions it is supposed to withstand. This book addresses the probabilistic methods for evaluation...

  13. Equivariant Zariski Structures

    CERN Document Server

    Solanki, Vinesh

    2011-01-01

    A category of equivariant algebras is defined, after introducing some important examples (the first Weyl algebra, $U_{q}(sl_{2}(k))$ for generic q, quantum tori at generic parameter). To each equivariant algebra, a first order theory is assigned. Model theoretic results are established (uncountable categoricity, quantifier elimination to the level of existential formulas) and that an appropriate dimension theory exists for models, making them Zariski structures. A functor from the category of equivariant algebras to the category of Zariski structures is defined and further properties of equivariant structures are briefly discussed.

  14. Structural patterns in nature

    DEFF Research Database (Denmark)

    Wester, Ture

    2003-01-01

    It seemens that some very basic randomly produced geometric/topological patterns are commonly found in Nature and have often very distinctive structural qualities. In Nature we find the same pattern in all scales from the universe to molecules, from solar systems to packing of cells, from glaciers...... to sea shells, from river systems to trees etc. Sometimes this seeming archetypical morphology involve structrual action and sometimes not-but the fact that it often posses efficient structural action opens a tool for evaluation and analysis of structures in nature and at the same time might...

  15. Kernels for structured data

    CERN Document Server

    Gärtner, Thomas

    2009-01-01

    This book provides a unique treatment of an important area of machine learning and answers the question of how kernel methods can be applied to structured data. Kernel methods are a class of state-of-the-art learning algorithms that exhibit excellent learning results in several application domains. Originally, kernel methods were developed with data in mind that can easily be embedded in a Euclidean vector space. Much real-world data does not have this property but is inherently structured. An example of such data, often consulted in the book, is the (2D) graph structure of molecules formed by

  16. Programming language structures

    CERN Document Server

    Organick, Elliott Irving; Plummer, Robert P

    1978-01-01

    Programming Language Structures deals with the structures of programming languages and introduces the reader to five important programming languages: Algol, Fortran, Lisp, Snobol, and Pascal. The fundamental similarities and differences among these languages are discussed. A unifying framework is constructed that can be used to study the structure of other languages, such as Cobol, PL/I, and APL. Several of the tools and methodologies needed to construct large programs are also considered.Comprised of 10 chapters, this book begins with a summary of the relevant concepts and principles about al

  17. Sensemaking, structuring and strategy

    DEFF Research Database (Denmark)

    Nielsen, Renate

    With the purpose of generating a new understanding of how organisations develop, an interpretive perspective at continuous processes in organisations will be applied: more specifically at sensemaking, structuring and strategising....

  18. Robustness of Structures

    DEFF Research Database (Denmark)

    Sørensen, John Dalsgaard

    2008-01-01

    . According to Danish design rules robustness shall be documented for all structures in high consequence class. The design procedure to document sufficient robustness consists of: 1) Review of loads and possible failure modes / scenarios and determination of acceptable collapse extent; 2) Review......This paper describes the background of the robustness requirements implemented in the Danish Code of Practice for Safety of Structures and in the Danish National Annex to the Eurocode 0, see (DS-INF 146, 2003), (DS 409, 2006), (EN 1990 DK NA, 2007) and (Sørensen and Christensen, 2006). More...... frequent use of advanced types of structures with limited redundancy and serious consequences in case of failure combined with increased requirements to efficiency in design and execution followed by increased risk of human errors has made the need of requirements to robustness of new structures essential...

  19. Structural dynamic modification

    Indian Academy of Sciences (India)

    A Sestieri

    2000-06-01

    Vibration and acoustic requirements are becoming increasingly important in the design of mechanical structures, but they are not usually of primary concern in the design process. So the need to vary the structural behaviour to solve noise and vibration problems often occurs at the prototype stage, giving rise to the so-called structural modification problem. In this paper, the direct problem of determing the new response of a system, after some modifications are introduced into the sestem, is analysed using two different databases: the modal database and the frequency response function database. The limitaions of the modal database are discussed. Structural modifications that can be accounted for are lumped masses, springs, dampers and dynamic absorbers.

  20. Territorial Administrative Budgetary Structure

    Directory of Open Access Journals (Sweden)

    Lucia Risti

    2011-06-01

    Full Text Available Local budget structure is a consequence of the way the country’s venues are organized from the territorial administrative point of view, in communes, towns, municipalities and the capital, Bucharest, in districts.

  1. Extremely deformable structures

    CERN Document Server

    2015-01-01

    Recently, a new research stimulus has derived from the observation that soft structures, such as biological systems, but also rubber and gel, may work in a post critical regime, where elastic elements are subject to extreme deformations, though still exhibiting excellent mechanical performances. This is the realm of ‘extreme mechanics’, to which this book is addressed. The possibility of exploiting highly deformable structures opens new and unexpected technological possibilities. In particular, the challenge is the design of deformable and bi-stable mechanisms which can reach superior mechanical performances and can have a strong impact on several high-tech applications, including stretchable electronics, nanotube serpentines, deployable structures for aerospace engineering, cable deployment in the ocean, but also sensors and flexible actuators and vibration absorbers. Readers are introduced to a variety of interrelated topics involving the mechanics of extremely deformable structures, with emphasis on ...

  2. Shock structures of astrospheres

    CERN Document Server

    Scherer, Klaus; Kleimann, Jens; Wiengarten, Tobias; Bomans, Dominik J; Weis, Kerstin

    2015-01-01

    The interaction between a supersonic stellar wind and a (super-)sonic interstellar wind has recently been viewed with new interest. We here first give an overview of the modeling, which includes the heliosphere as an example of a special astrosphere. Then we concentrate on the shock structures of fluid models, especially of hydrodynamic (HD) models. More involved models taking into account radiation transfer and magnetic fields are briefly sketched. Even the relatively simple HD models show a rich shock structure, which might be observable in some objects. We employ a single fluid model to study these complex shock structures, and compare the results obtained including heating and cooling with results obtained without these effects. Furthermore, we show that in the hypersonic case valuable information of the shock structure can be obtained from the Rankine-Hugoniot equations. We solved the Euler equations for the single fluid case and also for a case including cooling and heating. We also discuss the analytic...

  3. Differential geometric structures

    CERN Document Server

    Poor, Walter A

    2007-01-01

    This introductory text defines geometric structure by specifying parallel transport in an appropriate fiber bundle and focusing on simplest cases of linear parallel transport in a vector bundle. 1981 edition.

  4. Structural assessment of nanocomposites.

    Science.gov (United States)

    Gan, Yong X

    2012-07-01

    This paper provides an overview on structural assessment of nanocomposite materials. First of all, a brief description of advanced structure characterization methods such as scanning electron microscopy, X-ray diffraction, transmission electron microscopy, atomic force microscopy, and scanning tunneling microscopy is presented. Secondly, applications of these methods for analysis of structures and compositions of typical nanocomposites are introduced. The nanocomposites are formed by different nanoscale processing technologies. Electrochemically polymerized polyaniline (PANi) nanocomposites, thermomechanically processed metal matrix nanocomposites, nanocast ceramic matrix composites are typical examples discussed in this paper. Case studies on several functional nanocomposites for energy storage/conversion, catalysis and sensing applications are mentioned. After that, assessment of the interface structures of nanocomposite materials using surface characterization techniques and mechanical damage models is discussed. Finally, concluding remarks are provided.

  5. Deployable Composite Structures Project

    Data.gov (United States)

    National Aeronautics and Space Administration — NASA is seeking innovative structure technologies that will advance expandable exploration space modules and surface based habitats. To address this need CTD has...

  6. Optimal Sound Absorbing Structures

    CERN Document Server

    Yang, Min; Fu, Caixing; Sheng, Ping

    2016-01-01

    Causal nature of the acoustic response, for any materials or structures, dictates an inequality that relates the absorption spectrum of the sample to its thickness. We present a general recipe for constructing sound-absorbing structures that can attain near-equality for the causal relation with very high absorption performance; such structures are denoted optimal. Our strategy involves using carefully designed acoustic metamaterials as backing to a thin layer of conventional sound absorbing material, e.g., acoustic sponge. By using this design approach, we have realized a 12 cm-thick structure that exhibits broadband, near-perfect flat absorption spectrum starting at around 400 Hz. From the causal relation, the calculated minimum sample thickness is 11.5 cm for the observed absorption spectrum. We present the theory that underlies such absorption performance, involving the evanescent waves and their interaction with a dissipative medium, and show the excellent agreement with the experiment.

  7. FEMA DFIRM Hydraulic Structures

    Data.gov (United States)

    Minnesota Department of Natural Resources — This layer and accompanying attribute table is required whenever hydraulic structures are shown in the flood profile. It is also required if levees are shown on the...

  8. Creep in structures

    Energy Technology Data Exchange (ETDEWEB)

    Zyczkowski, M. (Krakow Univ. of Technology (Poland). Inst. of Mechanics and Machine Design) (ed.)

    1991-01-01

    This volume contains 81 papers divided into three almost equal parts: Constitutive equations, combined loadings; damage, creep crack growth, creep rupture; structures, analytical and numerical methods, optimal design. (orig.).

  9. Bioinspired structured surfaces.

    Science.gov (United States)

    Bhushan, Bharat

    2012-01-24

    Nature has evolved objects with desired functionality using commonly found materials. Nature capitalizes on hierarchical structures to achieve functionality. The understanding of the functions provided by objects and processes found in nature can guide us to produce nanomaterials, nanodevices, and processes with desirable functionality. Various natural objects which provide functionality of commercial interest have been characterized to understand how a natural object provides functionality. We have modeled and fabricated structures in the lab using nature's route and developed optimum structures. Once it is understood how nature does it, optimum structures have been fabricated using smart materials and fabrication techniques. This feature article provides an overview of four topics: Lotus effect, rose petal effect, gecko feet, and shark skin.

  10. Fundamentals of Structural Engineering

    CERN Document Server

    Connor, Jerome J

    2013-01-01

    Fundamentals of Structural Engineering provides a balanced, seamless treatment of both classic, analytic methods and contemporary, computer-based techniques for conceptualizing and designing a structure. The book’s principle goal is to foster an intuitive understanding of structural behavior based on problem solving experience for students of civil engineering and architecture who have been exposed to the basic concepts of engineering mechanics and mechanics of materials. Making it distinct from many other undergraduate textbooks, the authors of this text recognize the notion that engineers reason about behavior using simple models and intuition they acquire through problem solving. The approach adopted in this text develops this type of intuition  by presenting extensive, realistic problems and case studies together with computer simulation, which allows rapid exploration of  how a structure responds to changes in geometry and physical parameters. This book also: Emphasizes problem-based understanding of...

  11. Structures and their analysis

    CERN Document Server

    Fuchs, Maurice Bernard

    2016-01-01

    Addressing structures, this book presents a classic discipline in a modern setting by combining illustrated examples with insights into the solutions. It is the fruit of the author’s many years of teaching the subject and of just as many years of research into the design of optimal structures. Although intended for an advanced level of instruction it has an undergraduate course at its core. Further, the book was written with the advantage of having massive computer power in the background, an aspect which changes the entire approach to many engineering disciplines and in particular to structures. This paradigm shift has dislodged the force (flexibility) method from its former prominence and paved the way for the displacement (stiffness) method, despite the multitude of linear equations it spawns. In this book, however, both methods are taught: the force method offers a perfect vehicle for understanding structural behavior, bearing in mind that it is the displacement method which does the heavy number crunch...

  12. Change in Business Structure

    Data.gov (United States)

    Department of Veterans Affairs — Provides information on whether a company’s change in business structure affects its Data Universal Numbering System (DUNS) Number and its Vendor Information Pages...

  13. Modern frame structure buildings

    National Research Council Canada - National Science Library

    В. М. Першаков; Т. О. Петрова; К. М. Лисницька

    2013-01-01

    The article deals with the design, construction and implementation of reinforced concrete frame structures with span 18, 21 m for agricultural production buildings, hall-premises of public buildings...

  14. Stable generalized complex structures

    CERN Document Server

    Cavalcanti, Gil R

    2015-01-01

    A stable generalized complex structure is one that is generically symplectic but degenerates along a real codimension two submanifold, where it defines a generalized Calabi-Yau structure. We introduce a Lie algebroid which allows us to view such structures as symplectic forms. This allows us to construct new examples of stable structures, and also to define period maps for their deformations in which the background three-form flux is either fixed or not, proving the unobstructedness of both deformation problems. We then use the same tools to establish local normal forms for the degeneracy locus and for Lagrangian branes. Applying our normal forms to the four-dimensional case, we prove that any compact stable generalized complex 4-manifold has a symplectic completion, in the sense that it can be modified near its degeneracy locus to produce a compact symplectic 4-manifold.

  15. Encapsulation with structured triglycerides

    Science.gov (United States)

    Lipids provide excellent materials to encapsulate bioactive compounds for food and pharmaceutical applications. Lipids are renewable, biodegradable, and easily modified to provide additional chemical functionality. The use of structured lipids that have been modified with photoactive properties are ...

  16. Structural Identification Problem

    Directory of Open Access Journals (Sweden)

    Suvorov Aleksei

    2016-01-01

    Full Text Available The identification problem of the existing structures though the Quasi-Newton and its modification, Trust region algorithms is discussed. For the structural problems, which could be represented by means of the mathematical modelling of the finite element code discussed method is extremely useful. The nonlinear minimization problem of the L2 norm for the structures with linear elastic behaviour is solved by using of the Optimization Toolbox of Matlab. The direct and inverse procedures for the composition of the desired function to minimize are illustrated for the spatial 3D truss structure as well as for the problem of plane finite elements. The truss identification problem is solved with 2 and 3 unknown parameters in order to compare the computational efforts and for the graphical purposes. The particular commands of the Matlab codes are present in this paper.

  17. Extracellular matrix structure.

    Science.gov (United States)

    Theocharis, Achilleas D; Skandalis, Spyros S; Gialeli, Chrysostomi; Karamanos, Nikos K

    2016-02-01

    Extracellular matrix (ECM) is a non-cellular three-dimensional macromolecular network composed of collagens, proteoglycans/glycosaminoglycans, elastin, fibronectin, laminins, and several other glycoproteins. Matrix components bind each other as well as cell adhesion receptors forming a complex network into which cells reside in all tissues and organs. Cell surface receptors transduce signals into cells from ECM, which regulate diverse cellular functions, such as survival, growth, migration, and differentiation, and are vital for maintaining normal homeostasis. ECM is a highly dynamic structural network that continuously undergoes remodeling mediated by several matrix-degrading enzymes during normal and pathological conditions. Deregulation of ECM composition and structure is associated with the development and progression of several pathologic conditions. This article emphasizes in the complex ECM structure as to provide a better understanding of its dynamic structural and functional multipotency. Where relevant, the implication of the various families of ECM macromolecules in health and disease is also presented.

  18. Helical surface structures

    CERN Document Server

    Brandenburg, A; Brandenburg, Axel; Blackman, Eric G.

    2002-01-01

    Over the past few years there has been growing interest in helical magnetic field structures seen at the solar surface, in coronal mass ejections, as well as in the solar wind. Although there is a great deal of randomness in the data, on average the extended structures are mostly left-handed on the northern hemisphere and right-handed on the southern. Surface field structures are also classified as dextral (= right bearing) and sinistral (= left bearing) occurring preferentially in the northern and southern hemispheres respectively. Of particular interest here is a quantitative measurement of the associated emergence rates of helical structures, which translate to magnetic helicity fluxes. In this review, we give a brief survey of what has been found so far and what is expected based on models. Particular emphasis is put on the scale dependence of the associated fields and an attempt is made to estimate the helicity flux of the mean field vs. fluctuating field.

  19. Dielectric assist accelerating structure

    Science.gov (United States)

    Satoh, D.; Yoshida, M.; Hayashizaki, N.

    2016-01-01

    A higher-order TM02 n mode accelerating structure is proposed based on a novel concept of dielectric loaded rf cavities. This accelerating structure consists of ultralow-loss dielectric cylinders and disks with irises which are periodically arranged in a metallic enclosure. Unlike conventional dielectric loaded accelerating structures, most of the rf power is stored in the vacuum space near the beam axis, leading to a significant reduction of the wall loss, much lower than that of conventional normal-conducting linac structures. This allows us to realize an extremely high quality factor and a very high shunt impedance at room temperature. A simulation of a 5 cell prototype design with an existing alumina ceramic indicates an unloaded quality factor of the accelerating mode over 120 000 and a shunt impedance exceeding 650 M Ω /m at room temperature.

  20. Adaptive structures flight experiments

    Science.gov (United States)

    Martin, Maurice

    The topics are presented in viewgraph form and include the following: adaptive structures flight experiments; enhanced resolution using active vibration suppression; Advanced Controls Technology Experiment (ACTEX); ACTEX program status; ACTEX-2; ACTEX-2 program status; modular control patch; STRV-1b Cryocooler Vibration Suppression Experiment; STRV-1b program status; Precision Optical Bench Experiment (PROBE); Clementine Spacecraft Configuration; TECHSAT all-composite spacecraft; Inexpensive Structures and Materials Flight Experiment (INFLEX); and INFLEX program status.

  1. Structure of Proton

    CERN Document Server

    Fayyazuddin, A

    2003-01-01

    Electron--proton scattering in elastic and highly inelastic region is reviewed in a unified approach. The importance of parity--violating scattering due to electro--weak interference in probing the structure of proton is emphasized. The importance of longitudnal spin--spin asymmetry as well as parity violating longitudnal asymmetry to extract the structure functions of proton in both regions are discussed. The recoil polarization of proton in the elastic scattering is also discussed.

  2. Deployable Soft Composite Structures

    OpenAIRE

    Wei Wang; Hugo Rodrigue; Sung-Hoon Ahn

    2016-01-01

    Deployable structure composed of smart materials based actuators can reconcile its inherently conflicting requirements of low mass, good shape adaptability, and high load-bearing capability. This work describes the fabrication of deployable structures using smart soft composite actuators combining a soft matrix with variable stiffness properties and hinge-like movement through a rigid skeleton. The hinge actuator has the advantage of being simple to fabricate, inexpensive, lightweight and sim...

  3. Structured luminescence conversion layer

    Science.gov (United States)

    Berben, Dirk; Antoniadis, Homer; Jermann, Frank; Krummacher, Benjamin Claus; Von Malm, Norwin; Zachau, Martin

    2012-12-11

    An apparatus device such as a light source is disclosed which has an OLED device and a structured luminescence conversion layer deposited on the substrate or transparent electrode of said OLED device and on the exterior of said OLED device. The structured luminescence conversion layer contains regions such as color-changing and non-color-changing regions with particular shapes arranged in a particular pattern.

  4. Purely Functional Structured Programming

    OpenAIRE

    Obua, Steven

    2010-01-01

    The idea of functional programming has played a big role in shaping today's landscape of mainstream programming languages. Another concept that dominates the current programming style is Dijkstra's structured programming. Both concepts have been successfully married, for example in the programming language Scala. This paper proposes how the same can be achieved for structured programming and PURELY functional programming via the notion of LINEAR SCOPE. One advantage of this proposal is that m...

  5. Renovation of Roof Structure

    DEFF Research Database (Denmark)

    Kjærbye, Per Oluf H

    1997-01-01

    A 30 year old not-watertight roof based on wooden boards with roofing felt have been changed to a pitched structure with cementos plates. At the same time more thermal insulation has been placed.......A 30 year old not-watertight roof based on wooden boards with roofing felt have been changed to a pitched structure with cementos plates. At the same time more thermal insulation has been placed....

  6. Structure function monitor

    Energy Technology Data Exchange (ETDEWEB)

    McGraw, John T [Placitas, NM; Zimmer, Peter C [Albuquerque, NM; Ackermann, Mark R [Albuquerque, NM

    2012-01-24

    Methods and apparatus for a structure function monitor provide for generation of parameters characterizing a refractive medium. In an embodiment, a structure function monitor acquires images of a pupil plane and an image plane and, from these images, retrieves the phase over an aperture, unwraps the retrieved phase, and analyzes the unwrapped retrieved phase. In an embodiment, analysis yields atmospheric parameters measured at spatial scales from zero to the diameter of a telescope used to collect light from a source.

  7. REACTOR MODERATOR STRUCTURE

    Science.gov (United States)

    Greenstreet, B.L.

    1963-12-31

    A system for maintaining the alignment of moderator block structures in reactors is presented. Integral restraining grids are placed between each layer of blocks in the moderator structure, at the top of the uppermost layer, and at the bottom of the lowermost layer. Slots are provided in the top and bottom surfaces of the moderator blocks so as to provide a keying action with the grids. The grids are maintained in alignment by vertical guiding members disposed about their peripheries. (AEC)

  8. Structural Transformation in Ecuador

    OpenAIRE

    Ricardo Hausmann; Bailey Klinger

    2010-01-01

    This paper applies new techniques and metrics to analyze Ecuador's past record of and future opportunities for structural transformation. Ecuador's export dynamics and the emergence of new export activities have been the historical drivers of the country's growth, but recently Ecuador's export basket has undergone little structural transformation. The same broad sectors continue to dominate, and the overall sophistication of the export basket has actually declined in recent years. In order to...

  9. Estonian Tax Structure

    Directory of Open Access Journals (Sweden)

    Viktor Trasberg

    2014-08-01

    Full Text Available The paper analyses Estonian tax structure changes during the last decade and critically assesses the current situation. The country’s tax mix is rather unique among EU countries – it has one of the highest proportions of consumption taxes in total taxes and the lowest level of capital and profit taxes. Such an unbalanced tax structure creates risks for public finances, limits revenue collection and distorts the business environment.

  10. Trajectory grouping structure

    Directory of Open Access Journals (Sweden)

    Maike Buchin

    2015-03-01

    Full Text Available The collective motion of a set of moving entities like people, birds, or other animals, is characterized by groups arising, merging, splitting, and ending. Given the trajectories of these entities, we define and model a structure that captures all of such changes using the Reeb graph, a concept from topology. The trajectory grouping structure has three natural parameters that allow more global views of the data in group size, group duration, and entity inter-distance. We prove complexity bounds on the maximum number of maximal groups that can be present, and give algorithms to compute the grouping structure efficiently. We also study how the trajectory grouping structure can be made robust, that is, how brief interruptions of groups can be disregarded in the global structure, adding a notion of persistence to the structure. Furthermore, we showcase the results of experiments using data generated by the NetLogo flocking model and from the Starkey project. The Starkey data describe the movement of elk, deer, and cattle. Although there is no ground truth for the grouping structure in this data, the experiments show that the trajectory grouping structure is plausible and has the desired effects when changing the essential parameters. Our research provides the first complete study of trajectory group evolvement, including combinatorial,algorithmic, and experimental results.

  11. Meteorite Seymchan structure

    Science.gov (United States)

    Hontsova, S. S.; Petrova, E. V.; Muftahetdinova, R. F.; Chulanova, V. N.; Grokhovsky, V. I.

    2016-09-01

    The meteorite Seymchan specimen was studied using optical microscopy and scanning electron microscopy. Olivine grains have roundish shapes, which was formed during matter cooling. Different features of the metal structure such as plessite structure and Neimann bands were observed. The oxide edges were observed in the boundaries between phases. The oxides were formed in the terrestrial conditions. The boundary regions between metal and olivine in the meteorite contain grains of troilite, schreibersite, and chromite.

  12. Integral Textile Ceramic Structures

    Science.gov (United States)

    Marshall, David B.; Cox, Brian N.

    2008-08-01

    A new paradigm for ceramic composite structural components enables functionality in heat exchange, transpiration, detailed shape, and thermal strain management that significantly exceeds the prior art. The paradigm is based on the use of three-dimensional fiber reinforcement that is tailored to the specific shape, stress, and thermal requirements of a structural application and therefore generally requires innovative textile methods for each realization. Key features include the attainment of thin skins (less than 1 mm) that are nevertheless structurally robust, transpiration holes formed without cutting fibers, double curvature, compliant integral attachment to other structures that avoids thermal stress buildup, and microcomposite ceramic matrices that minimize spalling and allow the formation of smooth surfaces. All these features can be combined into structures of very varied gross shape and function, using a wide range of materials such as all-oxide systems and SiC and carbon fibers in SiC matrices. Illustrations are drawn from rocket nozzles, thermal protection systems, and gas turbine engines. The new design challenges that arise for such material/structure systems are being met by specialized computational modeling that departs significantly in the representation of materials behavior from that used in conventional finite element methods.

  13. Structural optimization of free-form reciprocal structures

    DEFF Research Database (Denmark)

    Parigi, Dario

    2014-01-01

    This paper presents an optimization algorithm for the design of structurally efficient free-form reciprocal structures. Because of the geometric complexity of reciprocal structures, only a few structural studies have been carried out so far, and we have a limited knowledge of the relation between...... geometry and structural behaviour in reciprocal structures. This study takes advantage of the preceding work carried by the author on the Reciprocalizer, a software tool for the generation of reciprocal geometries. The Reciprocalizer has been included into a structural optimization algorithm...... for the generation of structurally efficient free-form reciprocal structures....

  14. Structural prediction in aphasia

    Directory of Open Access Journals (Sweden)

    Tessa Warren

    2015-05-01

    Full Text Available There is considerable evidence that young healthy comprehenders predict the structure of upcoming material, and that their processing is facilitated when they encounter material matching those predictions (e.g., Staub & Clifton, 2006; Yoshida, Dickey & Sturt, 2013. However, less is known about structural prediction in aphasia. There is evidence that lexical prediction may be spared in aphasia (Dickey et al., 2014; Love & Webb, 1977; cf. Mack et al, 2013. However, predictive mechanisms supporting facilitated lexical access may not necessarily support structural facilitation. Given that many people with aphasia (PWA exhibit syntactic deficits (e.g. Goodglass, 1993, PWA with such impairments may not engage in structural prediction. However, recent evidence suggests that some PWA may indeed predict upcoming structure (Hanne, Burchert, De Bleser, & Vashishth, 2015. Hanne et al. tracked the eyes of PWA (n=8 with sentence-comprehension deficits while they listened to reversible subject-verb-object (SVO and object-verb-subject (OVS sentences in German, in a sentence-picture matching task. Hanne et al. manipulated case and number marking to disambiguate the sentences’ structure. Gazes to an OVS or SVO picture during the unfolding of a sentence were assumed to indicate prediction of the structure congruent with that picture. According to this measure, the PWA’s structural prediction was impaired compared to controls, but they did successfully predict upcoming structure when morphosyntactic cues were strong and unambiguous. Hanne et al.’s visual-world evidence is suggestive, but their forced-choice sentence-picture matching task places tight constraints on possible structural predictions. Clearer evidence of structural prediction would come from paradigms where the content of upcoming material is not as constrained. The current study used self-paced reading study to examine structural prediction among PWA in less constrained contexts. PWA (n=17 who

  15. Initial stages of benzotriazole adsorption on the Cu(111) surface.

    Science.gov (United States)

    Grillo, Federico; Tee, Daniel W; Francis, Stephen M; Früchtl, Herbert; Richardson, Neville V

    2013-06-21

    Benzotriazole (BTAH) has been used as a copper corrosion inhibitor since the 1950s; however, the molecular level detail of how inhibition occurs remains a matter of debate. The onset of BTAH adsorption on a Cu(111) single crystal was investigated via scanning tunnelling microscopy (STM), vibrational spectroscopy (RAIRS) and supporting DFT modelling. BTAH adsorbs as anionic (BTA(-)), CuBTA is a minority species, while Cu(BTA)2, the majority of the adsorbed species, form chains, whose sections appear to diffuse in a concerted manner. The copper surface appears to reconstruct in a (2 × 1) fashion.

  16. RNA Thermodynamic Structural Entropy.

    Science.gov (United States)

    Garcia-Martin, Juan Antonio; Clote, Peter

    2015-01-01

    Conformational entropy for atomic-level, three dimensional biomolecules is known experimentally to play an important role in protein-ligand discrimination, yet reliable computation of entropy remains a difficult problem. Here we describe the first two accurate and efficient algorithms to compute the conformational entropy for RNA secondary structures, with respect to the Turner energy model, where free energy parameters are determined from UV absorption experiments. An algorithm to compute the derivational entropy for RNA secondary structures had previously been introduced, using stochastic context free grammars (SCFGs). However, the numerical value of derivational entropy depends heavily on the chosen context free grammar and on the training set used to estimate rule probabilities. Using data from the Rfam database, we determine that both of our thermodynamic methods, which agree in numerical value, are substantially faster than the SCFG method. Thermodynamic structural entropy is much smaller than derivational entropy, and the correlation between length-normalized thermodynamic entropy and derivational entropy is moderately weak to poor. In applications, we plot the structural entropy as a function of temperature for known thermoswitches, such as the repression of heat shock gene expression (ROSE) element, we determine that the correlation between hammerhead ribozyme cleavage activity and total free energy is improved by including an additional free energy term arising from conformational entropy, and we plot the structural entropy of windows of the HIV-1 genome. Our software RNAentropy can compute structural entropy for any user-specified temperature, and supports both the Turner'99 and Turner'04 energy parameters. It follows that RNAentropy is state-of-the-art software to compute RNA secondary structure conformational entropy. Source code is available at https://github.com/clotelab/RNAentropy/; a full web server is available at http

  17. RNA Thermodynamic Structural Entropy.

    Directory of Open Access Journals (Sweden)

    Juan Antonio Garcia-Martin

    Full Text Available Conformational entropy for atomic-level, three dimensional biomolecules is known experimentally to play an important role in protein-ligand discrimination, yet reliable computation of entropy remains a difficult problem. Here we describe the first two accurate and efficient algorithms to compute the conformational entropy for RNA secondary structures, with respect to the Turner energy model, where free energy parameters are determined from UV absorption experiments. An algorithm to compute the derivational entropy for RNA secondary structures had previously been introduced, using stochastic context free grammars (SCFGs. However, the numerical value of derivational entropy depends heavily on the chosen context free grammar and on the training set used to estimate rule probabilities. Using data from the Rfam database, we determine that both of our thermodynamic methods, which agree in numerical value, are substantially faster than the SCFG method. Thermodynamic structural entropy is much smaller than derivational entropy, and the correlation between length-normalized thermodynamic entropy and derivational entropy is moderately weak to poor. In applications, we plot the structural entropy as a function of temperature for known thermoswitches, such as the repression of heat shock gene expression (ROSE element, we determine that the correlation between hammerhead ribozyme cleavage activity and total free energy is improved by including an additional free energy term arising from conformational entropy, and we plot the structural entropy of windows of the HIV-1 genome. Our software RNAentropy can compute structural entropy for any user-specified temperature, and supports both the Turner'99 and Turner'04 energy parameters. It follows that RNAentropy is state-of-the-art software to compute RNA secondary structure conformational entropy. Source code is available at https://github.com/clotelab/RNAentropy/; a full web server is available at http

  18. Hierarchically Structured Electrospun Fibers

    Directory of Open Access Journals (Sweden)

    Nicole E. Zander

    2013-01-01

    Full Text Available Traditional electrospun nanofibers have a myriad of applications ranging from scaffolds for tissue engineering to components of biosensors and energy harvesting devices. The generally smooth one-dimensional structure of the fibers has stood as a limitation to several interesting novel applications. Control of fiber diameter, porosity and collector geometry will be briefly discussed, as will more traditional methods for controlling fiber morphology and fiber mat architecture. The remainder of the review will focus on new techniques to prepare hierarchically structured fibers. Fibers with hierarchical primary structures—including helical, buckled, and beads-on-a-string fibers, as well as fibers with secondary structures, such as nanopores, nanopillars, nanorods, and internally structured fibers and their applications—will be discussed. These new materials with helical/buckled morphology are expected to possess unique optical and mechanical properties with possible applications for negative refractive index materials, highly stretchable/high-tensile-strength materials, and components in microelectromechanical devices. Core-shell type fibers enable a much wider variety of materials to be electrospun and are expected to be widely applied in the sensing, drug delivery/controlled release fields, and in the encapsulation of live cells for biological applications. Materials with a hierarchical secondary structure are expected to provide new superhydrophobic and self-cleaning materials.

  19. PRSEUS Structural Concept Development

    Science.gov (United States)

    Velicki, Alex; Jegley, Dawn

    2014-01-01

    A lighter, more robust airframe is one of the key technological advancements necessary for the successful launch of any large next-generation transport aircraft. Such a premise dictates that considerable improvements beyond current state-of-the-art aluminum structures is needed, and that improvements of this magnitude will require an extensive use of composite materials that are not only lightweight, but also economical to produce. To address this challenge, researchers at NASA and The Boeing Company are developing a novel structural concept called the Pultruded Rod Stitched Efficient Unitized Structure (PRSEUS) under the Environmentally Responsible Aviation (ERA) Project. It is an integrally stiffened panel concept that is stitched together and designed to maintain residual load-carrying capabilities under a variety of damage scenarios. In addition to improved structural performance, an important facet of this unique arrangement of stitched carbon fibers is its innovative manufacturing method that has the potential to lower fabrication costs by eliminating fasteners and autoclave cures. The rationale and development status for this new approach forms the basis of the work described in this paper. The test specimens described herein were fabricated, or are currently being fabricated, by The Boeing Company, while the structural analyses and testing tasks are being performed by NASA and Boeing personnel.

  20. Prosodic Structure as a Parallel to Musical Structure

    Science.gov (United States)

    Heffner, Christopher C.; Slevc, L. Robert

    2015-01-01

    What structural properties do language and music share? Although early speculation identified a wide variety of possibilities, the literature has largely focused on the parallels between musical structure and syntactic structure. Here, we argue that parallels between musical structure and prosodic structure deserve more attention. We review the evidence for a link between musical and prosodic structure and find it to be strong. In fact, certain elements of prosodic structure may provide a parsimonious comparison with musical structure without sacrificing empirical findings related to the parallels between language and music. We then develop several predictions related to such a hypothesis. PMID:26733930

  1. Structure and biophysics

    CERN Document Server

    Puglisi, Joseph D

    2007-01-01

    This volume is a collection of articles from the proceedings of the ISSBMR 7th Course: Structure and Biophysics - New Technologies for Current Challenges in Biology and Beyond. This NATO Advanced Institute (ASI) was held in Erice at the Ettore Majorana Foundation and Centre for Scientific Culture on 22 June through 3 July 2005. The ASI brought together a diverse group of experts in the fields of Structural Biology, Biophysics and Physics. Prominent lecturers, from seven different countries, and students from around the world participated in the NATO ASI organized by Professors Joseph Puglisi (Stanford University, USA) and Alexander Arseniev (Moscow, RU). Advances in nuclear magnetic resonance spectroscopy (NMR) and x-ray crystallography have allowed the three-dimensional structures of many biological macromolecules and their complexes, including the ribosome and RNA polymerase to be solved. Fundamental principles of NMR spectroscopy and dynamics, x-ray crystallography, computation and experimental dynamics we...

  2. Structural motion engineering

    CERN Document Server

    Connor, Jerome

    2014-01-01

    This innovative volume provides a systematic treatment of the basic concepts and computational procedures for structural motion design and engineering for civil installations. The authors illustrate the application of motion control to a wide spectrum of buildings through many examples. Topics covered include optimal stiffness distributions for building-type structures, the role of damping in controlling motion, tuned mass dampers, base isolation systems, linear control, and nonlinear control. The book's primary objective is the satisfaction of motion-related design requirements, such as restrictions on displacement and acceleration. The book is ideal for practicing engineers and graduate students. This book also: ·         Broadens practitioners' understanding of structural motion control, the enabling technology for motion-based design ·         Provides readers the tools to satisfy requirements of modern, ultra-high strength materials that lack corresponding stiffness, where the motion re...

  3. Freeform Honeycomb Structures

    KAUST Repository

    Jiang, Caigui

    2014-07-01

    Motivated by requirements of freeform architecture, and inspired by the geometry of hexagonal combs in beehives, this paper addresses torsion-free structures aligned with hexagonal meshes. Since repetitive geometry is a very important contribution to the reduction of production costs, we study in detail “honeycomb structures”, which are defined as torsion-free structures where the walls of cells meet at 120 degrees. Interestingly, the Gauss-Bonnet theorem is useful in deriving information on the global distribution of node axes in such honeycombs. This paper discusses the computation and modeling of honeycomb structures as well as applications, e.g. for shading systems, or for quad meshing. We consider this paper as a contribution to the wider topic of freeform patterns, polyhedral or otherwise. Such patterns require new approaches on the technical level, e.g. in the treatment of smoothness, but they also extend our view of what constitutes aesthetic freeform geometry.

  4. Graphene heat dissipating structure

    Energy Technology Data Exchange (ETDEWEB)

    Washburn, Cody M.; Lambert, Timothy N.; Wheeler, David R.; Rodenbeck, Christopher T.; Railkar, Tarak A.

    2017-08-01

    Various technologies presented herein relate to forming one or more heat dissipating structures (e.g., heat spreaders and/or heat sinks) on a substrate, wherein the substrate forms part of an electronic component. The heat dissipating structures are formed from graphene, with advantage being taken of the high thermal conductivity of graphene. The graphene (e.g., in flake form) is attached to a diazonium molecule, and further, the diazonium molecule is utilized to attach the graphene to material forming the substrate. A surface of the substrate is treated to comprise oxide-containing regions and also oxide-free regions having underlying silicon exposed. The diazonium molecule attaches to the oxide-free regions, wherein the diazonium molecule bonds (e.g., covalently) to the exposed silicon. Attachment of the diazonium plus graphene molecule is optionally repeated to enable formation of a heat dissipating structure of a required height.

  5. Implications of social structure

    DEFF Research Database (Denmark)

    Brask, Josefine Bohr

    social environment of the individual. In the last two studies, we investigate the role of social structure for cooperation in a classic natural system for behavioural research, the Trinidadian guppy (Poecilia reticulata), by means of computer simulations. Cooperation contradicts evolutionary theory......, we investigate empirically the role of the social environment of individuals for their communication patterns. Our study species is a song bird, the black-capped chickadee (Poecile atricapillus). The results suggest that individual communication in this species is influenced by features of the local...... and requires special explanations. Theory predicts that heterogeneous social structure can support and promote cooperation in populations. Our simulations suggest that social structure may not be able to explain the presence of cooperation in the guppy system. Overall the thesis provides new insights...

  6. Human Spacecraft Structures Internship

    Science.gov (United States)

    Bhakta, Kush

    2017-01-01

    DSG will be placed in halo orbit around themoon- Platform for international/commercialpartners to explore lunar surface- Testbed for technologies needed toexplore Mars• Habitat module used to house up to 4crew members aboard the DSG- Launched on EM-3- Placed inside SLS fairing Habitat Module - Task Habitat Finite Element Model Re-modeled entire structure in NX2) Used Beam and Shell elements torepresent the pressure vessel structure3) Created a point cloud of centers of massfor mass components- Can now inspect local moments andinertias for thrust ring application8/ Habitat Structure – Docking Analysis Problem: Artificial Gravity may be necessary forastronaut health in deep spaceGoal: develop concepts that show how artificialgravity might be incorporated into a spacecraft inthe near term Orion Window Radiant Heat Testing.

  7. Structure learning in action

    Science.gov (United States)

    Braun, Daniel A.; Mehring, Carsten; Wolpert, Daniel M.

    2010-01-01

    ‘Learning to learn’ phenomena have been widely investigated in cognition, perception and more recently also in action. During concept learning tasks, for example, it has been suggested that characteristic features are abstracted from a set of examples with the consequence that learning of similar tasks is facilitated—a process termed ‘learning to learn’. From a computational point of view such an extraction of invariants can be regarded as learning of an underlying structure. Here we review the evidence for structure learning as a ‘learning to learn’ mechanism, especially in sensorimotor control where the motor system has to adapt to variable environments. We review studies demonstrating that common features of variable environments are extracted during sensorimotor learning and exploited for efficient adaptation in novel tasks. We conclude that structure learning plays a fundamental role in skill learning and may underlie the unsurpassed flexibility and adaptability of the motor system. PMID:19720086

  8. Laser induced structural vibration

    Science.gov (United States)

    Koss, L. L.; Tobin, R. C.

    1983-01-01

    A technique is described for exciting structural vibration by using a focussed laser beam to vaporize material from a target attached to the structure. The rapid ejection of material results in an impulsive reaction to the target which is transmitted to the structure. The method has been studied with a Nd: glass laser, operated in the long pulse mode, in combination with a bismuth target attached in turn to a ballistic pendulum and cantilever beam. The specific mechanical energy was found to be proportional to the laser pulse energy raised to a power in the range 2.5-2.9. The highest efficiency of energy transfer achieved for the first vibrational mode of the cantilever was about 2 millipercent for the maximum laser pulse energy used, 1.5 J, the signal to noise ratio then being about 40 dB.

  9. Dynamic Data Structures

    DEFF Research Database (Denmark)

    Kejlberg-Rasmussen, Casper

    to a given key? The updates we can do are: inserting a new key or deleting a given key. Our dictionary has the working set property, which means that the running time of a query depends on the query distribution. Specifically the time to search for a key depends on when we last searched for it. Our data...... statements about our data structure, which are based on the structure of the underlying problem, that we are trying to solve. We can rely on the properties of the invariants when performing queries, and in return we need to ensure that the invariants remain true after we perform updates. When designing data......In this thesis I will address three dynamic data structure problems using the concept of invariants. The first problem is maintaining a dynamically changing set of keys – a dictionary – where the queries we can ask are: does it contain a given key? and what is the preceding (or succeeding) key...

  10. Dynamic Data Structures

    DEFF Research Database (Denmark)

    Tsakalidis, Konstantinos

    We study dynamic data structures for different variants of orthogonal range reporting query problems. In particular, we consider (1) the planar orthogonal 3-sided range reporting problem: given a set of points in the plane, report the points that lie within a given 3-sided rectangle with one....... Dynamic problems like the above arise in various applications of network optimization, VLSI layout design, computer graphics and distributed computing. For the first problem, we present dynamic data structures for internal and external memory that support planar orthogonal 3-sided range reporting queries......, and insertions and deletions of points efficiently over an average case sequence of update operations. The external memory data structures find applications in constraint and temporal databases. In particular, we assume that the coordinates of the points are drawn from different probabilistic distributions...

  11. Dynamic Data Structures

    DEFF Research Database (Denmark)

    Kejlberg-Rasmussen, Casper

    statements about our data structure, which are based on the structure of the underlying problem, that we are trying to solve. We can rely on the properties of the invariants when performing queries, and in return we need to ensure that the invariants remain true after we perform updates. When designing data......In this thesis I will address three dynamic data structure problems using the concept of invariants. The first problem is maintaining a dynamically changing set of keys – a dictionary – where the queries we can ask are: does it contain a given key? and what is the preceding (or succeeding) key...... to a given key? The updates we can do are: inserting a new key or deleting a given key. Our dictionary has the working set property, which means that the running time of a query depends on the query distribution. Specifically the time to search for a key depends on when we last searched for it. Our data...

  12. Structure of potato starch

    DEFF Research Database (Denmark)

    Bertoft, Eric; Blennow, Andreas

    2016-01-01

    are interconnected by long chains with more than 36 residues. The clusters consist of still smaller, very tightly branched building blocks. The clusters direct the semicrystalline structures found inside the starch granules. The crystals, which are ~5.2. nm thick, contain double helices formed from the external...... chains extending from the clusters. A range of enzymes is involved in the biosynthesis of the cluster structures and linear segments. These are required for sugar activation, chain elongation, branching, and trimming of the final branching pattern. As an interesting feature, potato amylopectin...... is substituted with low amounts of phosphate groups monoesterified to the C-3 and the C-6 carbons of the glucose units. They seem to align well in the granular structure and have tremendous effects on starch degradation in the potato and functionality of the refined starch. A specific dikinase catalyzes...

  13. Folksodriven Structure Network

    CERN Document Server

    Mas, Massimiliano Dal

    2011-01-01

    Nowadays folksonomy is used as a system derived from user-generated electronic tags or keywords that annotate and describe online content. But it is not a classification system as an ontology. To consider it as a classification system it would be necessary to share a representation of contexts by all the users. This paper is proposing the use of folksonomies and network theory to devise a new concept: a "Folksodriven Structure Network" to represent folksonomies. This paper proposed and analyzed the network structure of Folksodriven tags thought as folsksonomy tags suggestions for the user on a dataset built on chosen websites. It is observed that the Folksodriven Network has relative low path lengths checking it with classic networking measures (clustering coefficient). Experiment result shows it can facilitate serendipitous discovery of content among users. Neat examples and clear formulas can show how a "Folksodriven Structure Network" can be used to tackle ontology mapping challenges.

  14. Structural power flow measurement

    Energy Technology Data Exchange (ETDEWEB)

    Falter, K.J.; Keltie, R.F.

    1988-12-01

    Previous investigations of structural power flow through beam-like structures resulted in some unexplained anomalies in the calculated data. In order to develop structural power flow measurement as a viable technique for machine tool design, the causes of these anomalies needed to be found. Once found, techniques for eliminating the errors could be developed. Error sources were found in the experimental apparatus itself as well as in the instrumentation. Although flexural waves are the carriers of power in the experimental apparatus, at some frequencies longitudinal waves were excited which were picked up by the accelerometers and altered power measurements. Errors were found in the phase and gain response of the sensors and amplifiers used for measurement. A transfer function correction technique was employed to compensate for these instrumentation errors.

  15. Structural Sparse Tracking

    KAUST Repository

    Zhang, Tianzhu

    2015-06-01

    Sparse representation has been applied to visual tracking by finding the best target candidate with minimal reconstruction error by use of target templates. However, most sparse representation based trackers only consider holistic or local representations and do not make full use of the intrinsic structure among and inside target candidates, thereby making the representation less effective when similar objects appear or under occlusion. In this paper, we propose a novel Structural Sparse Tracking (SST) algorithm, which not only exploits the intrinsic relationship among target candidates and their local patches to learn their sparse representations jointly, but also preserves the spatial layout structure among the local patches inside each target candidate. We show that our SST algorithm accommodates most existing sparse trackers with the respective merits. Both qualitative and quantitative evaluations on challenging benchmark image sequences demonstrate that the proposed SST algorithm performs favorably against several state-of-the-art methods.

  16. Implications of social structure

    DEFF Research Database (Denmark)

    Brask, Josefine Bohr

    Social systems in nature are characterised by heterogeneous social structures. The pattern of social interactions or associations between individuals within populations (i.e. their social network) is typically non-random. Such structuring may have important implications for the expression......, we investigate empirically the role of the social environment of individuals for their communication patterns. Our study species is a song bird, the black-capped chickadee (Poecile atricapillus). The results suggest that individual communication in this species is influenced by features of the local...... social environment of the individual. In the last two studies, we investigate the role of social structure for cooperation in a classic natural system for behavioural research, the Trinidadian guppy (Poecilia reticulata), by means of computer simulations. Cooperation contradicts evolutionary theory...

  17. Superalloy Lattice Block Structures

    Science.gov (United States)

    Nathal, M. V.; Whittenberger, J. D.; Hebsur, M. G.; Kantzos, P. T.; Krause, D. L.

    2004-01-01

    Initial investigations of investment cast superalloy lattice block suggest that this technology will yield a low cost approach to utilize the high temperature strength and environmental resistance of superalloys in lightweight, damage tolerant structural configurations. Work to date has demonstrated that relatively large superalloy lattice block panels can be successfully investment cast from both IN-718 and Mar-M247. These castings exhibited mechanical properties consistent with the strength of the same superalloys measured from more conventional castings. The lattice block structure also accommodates significant deformation without failure, and is defect tolerant in fatigue. The potential of lattice block structures opens new opportunities for the use of superalloys in future generations of aircraft applications that demand strength and environmental resistance at elevated temperatures along with low weight.

  18. Dynamics of structures

    CERN Document Server

    Paultre, Patrick

    2013-01-01

    This book covers structural dynamics from a theoretical and algorithmic approach. It covers systems with both single and multiple degrees-of-freedom. Numerous case studies are given to provide the reader with a deeper insight into the practicalities of the area, and the solutions to these case studies are given in terms of real-time and frequency in both geometric and modal spaces. Emphasis is also given to the subject of seismic loading. The text is based on many lectures on the subject of structural dynamics given at numerous institutions and thus will be an accessible and practical aid to

  19. Cellular structural biology.

    Science.gov (United States)

    Ito, Yutaka; Selenko, Philipp

    2010-10-01

    While we appreciate the complexity of the intracellular environment as a general property of every living organism, we collectively lack the appropriate tools to analyze protein structures in a cellular context. In-cell NMR spectroscopy represents a novel biophysical tool to investigate the conformational and functional characteristics of biomolecules at the atomic level inside live cells. Here, we review recent in-cell NMR developments and provide an outlook towards future applications in prokaryotic and eukaryotic cells. We hope to thereby emphasize the usefulness of in-cell NMR techniques for cellular studies of complex biological processes and for structural analyses in native environments. Copyright © 2010 Elsevier Ltd. All rights reserved.

  20. Structured Analog CMOS Design

    CERN Document Server

    Stefanovic, Danica

    2008-01-01

    Structured Analog CMOS Design describes a structured analog design approach that makes it possible to simplify complex analog design problems and develop a design strategy that can be used for the design of large number of analog cells. It intentionally avoids treating the analog design as a mathematical problem, developing a design procedure based on the understanding of device physics and approximations that give insight into parameter interdependences. The proposed transistor-level design procedure is based on the EKV modeling approach and relies on the device inversion level as a fundament

  1. POLYMERIC SURFACTANT STRUCTURE

    Institute of Scientific and Technical Information of China (English)

    P.M. Saville; J.W. White

    2001-01-01

    Polymeric surfactants are amongst the most widespread of all polymers. In nature, proteins and polysaccharides cause self organization as a result of this surfactancy; in industry, polymeric surfactants play key roles in the food, explosives and surface coatings sectors. The generation of useful nano- and micro-structures in films and emulsions as a result of polymer amphiphilicity and the application of mechanical stress is discussed. The use of X-ray and neutron small angle scattering and reflectivity to measure these structures and their dynamic properties will be described. New results on linear and dendritic polymer surfactants are presented.

  2. Kilns and Firing Structures

    OpenAIRE

    Nicholson, Paul

    2010-01-01

    The purpose of firing pottery is to change clay, a plastic material, into ceramic, which is aplastic. Examined here are structures designed to fire pottery or faience or to make glass (although the latter might be better described as furnaces). Firing can take place in an open, bonfire-like environment, which can also be enclosed as a firing structure. Beyond this is the development of the true kiln of which there are two main types: updraft and downdraft. The first of these is by far the mos...

  3. Objective Eulerian Coherent Structures

    CERN Document Server

    Serra, M

    2015-01-01

    We define objective Eulerian Coherent Structures (OECSs) in two-dimensional, non-autonomous dynamical systems as instantaneously most influential material curves. Specifically, OECSs are stationary curves of the averaged instantaneous material stretching-rate or material shearing-rate functionals. From these objective (frame-invariant) variational principles, we obtain explicit differential equations for hyperbolic, elliptic and parabolic OECSs. As illustration, we compute OECSs in an unsteady ocean velocity data set. In comparison to structures suggested by other common Eulerian diagnostic tools, we find OECSs to be the correct short-term cores of observed trajectory deformation patterns.

  4. Nuclear structure and astrophysics

    Energy Technology Data Exchange (ETDEWEB)

    Grawe, H [Gesellschaft fuer Schwerionenforschung (GSI), D-64291 Darmstadt (Germany); Langanke, K [Gesellschaft fuer Schwerionenforschung (GSI), D-64291 Darmstadt (Germany); MartInez-Pinedo, G [Gesellschaft fuer Schwerionenforschung (GSI), D-64291 Darmstadt (Germany)

    2007-09-15

    The nuclear structure in regions of the Segre chart which are of astrophysical importance is reviewed. The main emphasis is put on those nuclei that are relevant for stellar nucleosynthesis in fusion processes, and in slow neutron capture, both located close to stability, rapid neutron capture close to the neutron dripline and rapid proton capture near the proton dripline. The basic features of modern nuclear structure, their importance and future potential for astrophysics and their level of predictibility are critically discussed. Recent experimental and theoretical results for shell evolution far off the stability line and consequences for weak interaction processes, proton and neutron capture are reviewed.

  5. Structural dynamics analysis

    Science.gov (United States)

    Housner, J. M.; Anderson, M.; Belvin, W.; Horner, G.

    1985-01-01

    Dynamic analysis of large space antenna systems must treat the deployment as well as vibration and control of the deployed antenna. Candidate computer programs for deployment dynamics, and issues and needs for future program developments are reviewed. Some results for mast and hoop deployment are also presented. Modeling of complex antenna geometry with conventional finite element methods and with repetitive exact elements is considered. Analytical comparisons with experimental results for a 15 meter hoop/column antenna revealed the importance of accurate structural properties including nonlinear joints. Slackening of cables in this antenna is also a consideration. The technology of designing actively damped structures through analytical optimization is discussed and results are presented.

  6. Structural model integrity

    Science.gov (United States)

    Wallerstein, D. V.; Lahey, R. S.; Haggenmacher, G. W.

    1977-01-01

    Many of the practical aspects and problems of ensuring the integrity of a structural model are discussed, as well as the steps which have been taken in the NASTRAN system to assure that these checks can be routinely performed. Model integrity as used applies not only to the structural model but also to the loads applied to the model. Emphasis is also placed on the fact that when dealing with substructure analysis, all of the checking procedures discussed should be applied at the lowest level of substructure prior to any coupling.

  7. Stellar structure of magnetars

    Science.gov (United States)

    Dong, JianMin; Zuo, Wei; Gu, JianZhong; Shang, XinLe

    2016-04-01

    Magnetars are strong magnetized neutron stars which could emit quiescent X-ray, repeating burst of soft gamma ray, and even the giant flares. We investigate the effects of magnetic fields on the structure of isolated magnetars. The stellar structure together with the magnetic field configuration can be obtained at the same time within a self-consistent procedure. The magnetar mass and radius are found to be weakly enhanced by the strong magnetic fields. Unlike other previous investigations, the magnetic field is unable to violate the mass limit of the neutron stars.

  8. Dissipative structures and chaos

    CERN Document Server

    Mori, Hazime

    1998-01-01

    This monograph consists of two parts and gives an approach to the physics of open nonequilibrium systems. Part I derives the phenomena of dissipative structures on the basis of reduced evolution equations and includes Bénard convection and Belousov-Zhabotinskii chemical reactions. Part II discusses the physics and structures of chaos. While presenting a construction of the statistical physics of chaos, the authors unify the geometrical and statistical descriptions of dynamical systems. The shape of chaotic attractors is characterized, as are the mixing and diffusion of chaotic orbits and the fluctuation of energy dissipation exhibited by chaotic systems.

  9. Structure refinement of astrophyllite

    Institute of Scientific and Technical Information of China (English)

    MA; Zhesheng

    2001-01-01

    [1]Abdel-Fattah M. Abdel-Rahman., Mineral chemistry and paragenesis of astrophyllite from Egypt, Mineralogical Magazine, 1992, 56: 17-26.[2]Liu Yan, Ma Zhesheng, Han Xiuling et al, Astrophyllite from the Namjabarwa Area, Eastern Tibet, Acta Petrologica et Mineralogica, 1997,16(4): 338-340.[3]Peng Zhizhong, Ma Zhesheng, The crystal structure of astrophyllite (in Russian), Scientia Sinica, 1963, 12(2): 272-276.[4]Pen Zhizhong, Ma Zhesheng, The crystal structure of Tricinic Mangano-astrophyllite (in Russian), Scientia Sinica (Scien-ce in China), 1964, 13(7): 1180-1183.[5]Shi Nicheng, Ma Zhesheng, Li Guowu et al., Stucyure Refinement of Monoclinic astrophyllite, Acta Crystallographica, Section B, 1998, B54: 109-114.[6]Woodrow, P. J., The Crystal structure of astrophyllite, Acta Crystallographica, 1967, 22: 673-678.[7]СеменовЕ. И., Куплетскит-Новый Минерал Группы Астрофиллита, ДАН, 1956, 108(5), 933-936.[8]Nickel, E. H., Rowland, J. E., Charette, D. J., Niobophyllite the niobium analogue of astrophyllite: A new mineral from Sead Laxe Labrador, Canad. Mine., 1964, 8(1): 40.[9]X-Ray Laboratory of Hubei Geologic College, The crystal chemistry of astrophyllite group minerals (in Chinese), Scientia Geologica Sinica, 1974, (1): 18-30.[10]Sheldrick, G. M., Program for the solution of crystal structures, SHELX86, University of G?ttingen, 1985, Germany.[11]Sheldrick, G. M., Program for the refinement of crystal structures, SHELXL93, University of G?ttingen, 1993, Germany.[12]Liebau, F., Structural Chemistry of Silicates Structure, Bonding, and Classification, Heidelberg: Springer-Verlag QD181, S6L614, 1985.[13]Ferraris, G., Ivaldi, G., Khomyakov, A. P. et al., Nafertisite, a layer titanosilicate member of a polysomatic series including mica, Eur. J. Mineral.,1996, 8: 241-249.[14]Ferraris, G., Polysomatism as a tool for correlating properties and structure, in EMU Notes in

  10. Robustness of Structural Systems

    DEFF Research Database (Denmark)

    Canisius, T.D.G.; Sørensen, John Dalsgaard; Baker, J.W.

    2007-01-01

    The importance of robustness as a property of structural systems has been recognised following several structural failures, such as that at Ronan Point in 1968,where the consequenceswere deemed unacceptable relative to the initiating damage. A variety of research efforts in the past decades have...... systems. Guidance is provided regarding the assessment of robustness in a framework that considers potential hazards to the system, vulnerability of system components, and failure consequences. Several proposed methods for quantifying robustness are reviewed, and guidelines for robust design...

  11. Safety of Marine Structures

    DEFF Research Database (Denmark)

    Burcharth, H. F.

    1990-01-01

    of a "future safe" design code for exposed marine structures like breakwaters should be different from the ones usually applied in modern design standards for conventional structures within civil engineering. Moreover, results from ongoing development of a design code for rubble mound breakwaters are presented.......Based on the large number of recent failures of major rubble mound breakwaters the paper discusses the experience gained so far and points out the weak spots in our present knowledge. On this base the difficulties in developing design standards are discussed and it is argued that the principles...

  12. Coastal Structures and Barriers 2012

    Data.gov (United States)

    California Department of Resources — This dataset is a compilation of the UCSC Sand Retention Structures, MC Barriers, and USACE Coastal Structures. UCSC Sand Retention Structures originate from a...

  13. System Reliability of Timber Structures

    DEFF Research Database (Denmark)

    Kirkegaard, Poul Henning; Sørensen, John Dalsgaard

    2010-01-01

    For reduction of the risk of collapse in the event of loss of structural element(s), a structural engineer may take necessary steps to design a collapse-resistant structure that is insensitive to accidental circumstances e.g. by incorporating characteristics like redundancy, ties, ductility, key ...... elements, alternate load path(s) etc. in the structural design. In general these characteristics can have a positive influence on system reliability of a structure however, in Eurocodes ductility is only awarded for concrete and steel structures but not for timber structures. It is well......-know that structural systems can redistribute internal forces due to ductility of a connection, i.e. some additional loads can be carried by the structure. The same effect is also possible for reinforced concrete structures and structures of steel. However, for timber structures codes do not award that ductility...

  14. Coastal Structures and Barriers 2012

    Data.gov (United States)

    California Department of Resources — This dataset is a compilation of the UCSC Sand Retention Structures, MC Barriers, and USACE Coastal Structures. UCSC Sand Retention Structures originate from a...

  15. Integrated materials–structural models

    DEFF Research Database (Denmark)

    Stang, Henrik; Geiker, Mette Rica

    2008-01-01

    Reliable service life models for load carrying structures are significant elements in the evaluation of the performance and sustainability of existing and new structures. Furthermore, reliable service life models are prerequisites for the evaluation of the sustainability of maintenance strategies......, repair works and strengthening methods for structures. A very significant part of the infrastructure consists of reinforced concrete structures. Even though reinforced concrete structures typically are very competitive, certain concrete structures suffer from various types of degradation. A framework...

  16. Robustness Analysis of Kinetic Structures

    DEFF Research Database (Denmark)

    Kirkegaard, Poul Henning; Sørensen, John Dalsgaard

    2009-01-01

    The present paper considers robustness of kinetic structures. Robustness of structures has obtained a renewed interest due to a much more frequent use of advanced types of structures with limited redundancy and serious consequences in case of failure. Especially for these types of structural syst...... systems, it is of interest to investigate how robust the structures are, or what happens if a structural element is added to or removed from the original structure. The present paper discusses this issue for kinetic structures in architecture....

  17. Market structures in international telecommunications

    DEFF Research Database (Denmark)

    Henten, Anders

    1998-01-01

    Paper dealing with the internationalisation of telecommunications and the developing market structures.......Paper dealing with the internationalisation of telecommunications and the developing market structures....

  18. Organisational Structures & Considerations

    NARCIS (Netherlands)

    Luiijf, H.A.M.; Healey, J.

    2012-01-01

    The purpose of this section is to review specific types of national cyber security (NCS) areas (also called ‘mandates’) and examine the organisational and collaborative models associated with them. Before discussing the wide variety of organisational structures at the national and international leve

  19. Structure from interaction events

    NARCIS (Netherlands)

    de Nooy, W.

    2015-01-01

    In this contribution to the colloquium, I argue why and how I lost interest in the overall structure of social networks even though Big Data techniques are increasingly simplifying the collection, organisation, and analysis of ever larger networks. The challenge that Big Data techniques pose to the

  20. Teaching concrete structures

    DEFF Research Database (Denmark)

    Goltermann, Per

    2014-01-01

    The teaching of concrete structures has been revised and a number of new approaches have been developed, implemented and evaluated. Inductive teaching, E-learning and “patches” have been found to be improvements and may be an inspiration and help for others development of the teaching and learning...

  1. Nanoscale Turing structures

    DEFF Research Database (Denmark)

    Dziekan, Piotr; Hansen, Jesper Schmidt; Nowakowski, Bogdan

    2014-01-01

    Formation of Turing patterns of nanoscopic length scale is simulated using molecular dynamics. Based on Fourier spectra of the concentrations of species, we compare stabilities of the structures of different wavelengths and for different intermolecular potentials. Long range attraction is shown t...

  2. Capital Structure and Assets

    DEFF Research Database (Denmark)

    Flor, Christian Riis

    2008-01-01

    post optimally sell the assets or re-optimize the capital structure. Ex ante, more uncertain asset value decreases leverage, but not firm value, and selling the assets becomes less likely. Firms should tend to invest in assets whose value is less correlated to changes in earnings and, in addition...

  3. Reliability based structural design

    NARCIS (Netherlands)

    Vrouwenvelder, A.C.W.M.

    2014-01-01

    According to ISO 2394, structures shall be designed, constructed and maintained in such a way that they are suited for their use during the design working life in an economic way. To fulfil this requirement one needs insight into the risk and reliability under expected and non-expected actions. A ke

  4. Reliability based structural design

    NARCIS (Netherlands)

    Vrouwenvelder, A.C.W.M.

    2013-01-01

    According to ISO 2394, structures shall be designed, constructed and maintained in such a way that they are suited for their use during the design working life in an economic way. To fulfil this requirement one needs insight into the risk and reliability under expected and non-expected actions. A ke

  5. Secondary Structure Switch

    Science.gov (United States)

    King, Angela G.

    2006-01-01

    Neurogenerative diseases like Alzheimer's disease and Parkinson's disease involve a transformation between two peptide and protein structures of alpha-helices and beta-sheets, where the peptide backbone can also participate in metal ion binding in addition to histidine residues. However, the complete absence of change in conformation of Coiled…

  6. Structure - materials - production

    DEFF Research Database (Denmark)

    Gammelgaard Nielsen, Anders; Gammel, Peder; Busch, Jens

    2002-01-01

    For the last six years th Aarhus School of Architecture has introduced the first year students (there are about 200 students admitted each year) to structure, materials, design and production through a five week course in collaboration with a group of local companies....

  7. The Structure of Pectin

    Energy Technology Data Exchange (ETDEWEB)

    Mort, Andrew [Oklahoma State Univ., Stillwater, OK (United States). Dept. of Biochemistry and Molecular Biology

    2017-01-12

    At the beginning of this project we hypothesized that pectin, which is a major polysaccharide in primary plant cell walls, is composed of various distinct structural regions covalently linked together into a high molecular weight complex polymer. We also hypothesized that a considerable portion of xyloglucan, the major hemicellulose in most primary cell walls, is linked to the pectin. Our goal was to determine if these interconnections exist and to characterize the exact nature of the interactions. It seems imperative that we have a complete knowledge of the structure of pectin to be able to propose realistic models of cell walls. There is a lot of interest in the biosynthesis of pectin. I do not think it will be possible to completely understand the biosynthesis of pectin without knowing the structure of pectin and thus the sequence of reactions needed to put each sugar or ester in its correct position in the polymer. We made considerable progress in determining the detailed structure of pectin and within a year or so will be able to put forward a comprehensive model of it.

  8. Large, Easily Deployable Structures

    Science.gov (United States)

    Agan, W. E.

    1983-01-01

    Study of concepts for large space structures will interest those designing scaffolding, radio towers, rescue equipment, and prefabricated shelters. Double-fold, double-cell module was selected for further design and for zero gravity testing. Concept is viable for deployment by humans outside space vehicle as well as by remotely operated manipulator.

  9. Inequalities in network structures

    NARCIS (Netherlands)

    Whitmeyer, Joseph M.; Wittek, Rafael

    We use a model of continuous attachments in networks to generate propositions concerning inequalities in network structures, and test the propositions on data from organizational settings. Our network model, inspired by that of [Gould, Roger 2002. The origins of status hierarchies: A formal theory

  10. Mining Structured Data

    NARCIS (Netherlands)

    Nijssen, Siegfried Gerardus Remius

    2006-01-01

    Many databases do not consist of a single table of fixed dimensions, but of objects that are related to each other: the databases are relational, or structured. We study the discovery of patterns in such data. In our approach, a data analyst specifies constraints on patterns that she believes to be

  11. Land, Structure & Depreciation

    NARCIS (Netherlands)

    M. Francke; A. van de Minne

    2013-01-01

    We introduce a hedonic price model which enables us to disentangle the value of a residential property into the value of land and the value of structure, while controlling for depreciation and vintage effects. For given reconstruction costs we are able to estimate the impact of physical depreciation

  12. Visual Narrative Structure

    Science.gov (United States)

    Cohn, Neil

    2013-01-01

    Narratives are an integral part of human expression. In the graphic form, they range from cave paintings to Egyptian hieroglyphics, from the Bayeux Tapestry to modern day comic books (Kunzle, 1973; McCloud, 1993). Yet not much research has addressed the structure and comprehension of narrative images, for example, how do people create meaning out…

  13. Structured Programming: An Introduction.

    Science.gov (United States)

    Moulton, Peter

    Designed for use by computer programming teachers, this booklet presents the concepts of structured programming and provides examples of how to implement this methodology, which provides a systematic way of organizing programs so that even large and complex programs are easier to understand and modify than unstructured programs. After a brief…

  14. Structural Equation Model Trees

    Science.gov (United States)

    Brandmaier, Andreas M.; von Oertzen, Timo; McArdle, John J.; Lindenberger, Ulman

    2013-01-01

    In the behavioral and social sciences, structural equation models (SEMs) have become widely accepted as a modeling tool for the relation between latent and observed variables. SEMs can be seen as a unification of several multivariate analysis techniques. SEM Trees combine the strengths of SEMs and the decision tree paradigm by building tree…

  15. Air Structures: Inflatable Alternatives

    Science.gov (United States)

    Valerio, Joseph M.; And Others

    1973-01-01

    Describes and evaluates several avant garde'' examples of air structures. Included are a soft'' child's playpen, a pneudome that employs a water ballast for anchoring, a one-acre enclosed campus, an instant city'' constructed for an industrial design conference, and the Fuji Pavilion, at Expo '70 in Osaka, Japan, that was large enough to cover…

  16. Structuring the Information Gap.

    Science.gov (United States)

    Edge, Julian

    1984-01-01

    Describes an information gap procedure to teach a new structure which requires students to look for and exchange information in order to complete a task in an English as a second language class. Illustrates the method with a set of materials and suggests ways for teachers to produce similar materials. (SED)

  17. Whence Structured Propositions?

    Science.gov (United States)

    Keller, Lorraine Juliano

    2012-01-01

    This thesis is a critical examination of "Structured Propositionalism" (SP), the view that propositions are complex entities composed of the semantic values of the (meaningful) parts of the sentences that express them. According to SP, propositions have constituents and are individuated by the identity and arrangement of their…

  18. Hybrid composite laminate structures

    Science.gov (United States)

    Chamis, C. C.; Lark, R. F. (Inventor)

    1977-01-01

    An invention which relates to laminate structures and specifically to essentially anisotropic fiber composite laminates is described. Metal foils are selectively disposed within the laminate to produce increased resistance to high velocity impact, fracture, surface erosion, and other stresses within the laminate.

  19. Manipulating Combinatorial Structures.

    Science.gov (United States)

    Labelle, Gilbert

    This set of transparencies shows how the manipulation of combinatorial structures in the context of modern combinatorics can easily lead to interesting teaching and learning activities at every level of education from elementary school to university. The transparencies describe: (1) the importance and relations of combinatorics to science and…

  20. Corporate strategies: organizational structure.

    Science.gov (United States)

    Howe, R C; Oestreicher, V

    1988-06-01

    In previous installments of this series, the authors outlined factors that influence corporation information system strategies. The factor that appears to be most significant is centralization vs. decentralization. This article presents examples of organizational structures, roles and responsibilities for either approach.

  1. Unsupervised Knowledge Structuring

    DEFF Research Database (Denmark)

    Kano Glückstad, Fumiko; Herlau, Tue; Schmidt, Mikkel N.;

    2013-01-01

    This work presents a conceptual framework for learning an ontological structure of domain knowledge, which combines Jaccard similarity coefficient with the Infinite Relational Model (IRM) by (Kemp et al. 2006) and its extended model, i.e. the normal-Infinite Relational Model (n-IRM) by (Herlau et...

  2. Multilevel distributed structure optimization

    NARCIS (Netherlands)

    Entzinger, J.O.; Spallino, R.; Ruijter, W.

    2003-01-01

    An iterative optimisation routine for aircraft structures using Genetic Algorithms (GAs) and Neural Networks (NNs) is presented. In this setup the NNs form a response surface, approximating the key mechanical properties of substructures. NNs are updated every iteration. The GA uses these NNs in the

  3. Reforming Organizational Structures

    NARCIS (Netherlands)

    S.G.J. Van de Walle (Steven)

    2016-01-01

    textabstractPublic sectors have undergone major transformations. Public sector reform touches upon the core building blocks of the public sector: organizational structures, people and finances. These are objects of reform. This chapter presents and discusses a set of major transformations with

  4. Probabilistic Structural Analysis Program

    Science.gov (United States)

    Pai, Shantaram S.; Chamis, Christos C.; Murthy, Pappu L. N.; Stefko, George L.; Riha, David S.; Thacker, Ben H.; Nagpal, Vinod K.; Mital, Subodh K.

    2010-01-01

    NASA/NESSUS 6.2c is a general-purpose, probabilistic analysis program that computes probability of failure and probabilistic sensitivity measures of engineered systems. Because NASA/NESSUS uses highly computationally efficient and accurate analysis techniques, probabilistic solutions can be obtained even for extremely large and complex models. Once the probabilistic response is quantified, the results can be used to support risk-informed decisions regarding reliability for safety-critical and one-of-a-kind systems, as well as for maintaining a level of quality while reducing manufacturing costs for larger-quantity products. NASA/NESSUS has been successfully applied to a diverse range of problems in aerospace, gas turbine engines, biomechanics, pipelines, defense, weaponry, and infrastructure. This program combines state-of-the-art probabilistic algorithms with general-purpose structural analysis and lifting methods to compute the probabilistic response and reliability of engineered structures. Uncertainties in load, material properties, geometry, boundary conditions, and initial conditions can be simulated. The structural analysis methods include non-linear finite-element methods, heat-transfer analysis, polymer/ceramic matrix composite analysis, monolithic (conventional metallic) materials life-prediction methodologies, boundary element methods, and user-written subroutines. Several probabilistic algorithms are available such as the advanced mean value method and the adaptive importance sampling method. NASA/NESSUS 6.2c is structured in a modular format with 15 elements.

  5. GKZ Hypergeometric Structures

    NARCIS (Netherlands)

    Stienstra, J.

    2007-01-01

    This text is based on lectures by the author in the Summer School Algebraic Geometry and Hypergeometric Functions in Istanbul in June 2005. It gives a review of some of the basic aspects of the theory of hypergeometric structures of Gelfand, Kapranov and Zelevinsky, including Differential Equations,

  6. Cell Structure Study.

    Science.gov (United States)

    Ekstrom, James V.

    2000-01-01

    Presents an activity in which students use microscopes and digital images to examine Elodea, a fresh water plant, before and after the process of plasmolysis, identify plant cellular structures before and after plasmolysis, and calculate the size of the plant's vacuole. (ASK)

  7. Silicon Betavoltaic Batteries Structures

    Directory of Open Access Journals (Sweden)

    V.N. Murashev

    2015-12-01

    Full Text Available For low-power miniature energy creation sources the particular interest is nickel Ni63. This paper discusses the main types of betavoltaic battery structures with the prospects for industrial application using - isotope of nickel Ni63. It is shown that the prospects for improving the effective efficiency are planar multijunction betavoltaic batteries.

  8. Magnetic Structure of Erbium

    DEFF Research Database (Denmark)

    Gibbs, D.; Bohr, Jakob; Axe, J. D.

    1986-01-01

    , and at positions split symmetrically about the fundamental. As the temperature is lowered below 52 K the charge and magnetic scattering display a sequence of lock-in transitions to rational wave vectors. A spin-slip description of the magnetic structure is presented which explains the wave vectors...

  9. Space-time structure

    CERN Document Server

    Schrödinger, Erwin

    1985-01-01

    In response to repeated requests this classic book on space-time structure by Professor Erwin Schrödinger is now available in the Cambridge Science Classics series. First published in 1950, and reprinted in 1954 and 1960, this lucid and profound exposition of Einstein's 1915 theory of gravitation still provides valuable reading for students and research workers in the field.

  10. Verification of ceramic structures

    NARCIS (Netherlands)

    Behar-Lafenetre, S.; Cornillon, L.; Rancurel, M.; Graaf, D. de; Hartmann, P.; Coe, G.; Laine, B.

    2012-01-01

    In the framework of the "Mechanical Design and Verification Methodologies for Ceramic Structures" contract [1] awarded by ESA, Thales Alenia Space has investigated literature and practices in affiliated industries to propose a methodological guideline for verification of ceramic spacecraft and instr

  11. Structured Mechanical Collage.

    Science.gov (United States)

    Huang, Zhe; Wang, Jiang; Fu, Hongbo; Lau, Rynson W H

    2014-07-01

    We present a method to build 3D structured mechanical collages consisting of numerous elements from the database given artist-designed proxy models. The construction is guided by some graphic design principles, namely unity, variety and contrast. Our results are visually more pleasing than previous works as confirmed by a user study.

  12. Information Structure: Afterword

    Directory of Open Access Journals (Sweden)

    Craige Roberts

    2012-12-01

    Full Text Available This is the afterword to the 2012 republication of "Information structure in discourse: Towards an integrated formal theory of pragmatics". See also the annotated bibliography on related topics at http://www.ling.ohio-state.edu/~croberts/QUDbib/. http://dx.doi.org/10.3765/sp.5.7 BibTeX info

  13. Inequalities in network structures

    NARCIS (Netherlands)

    Whitmeyer, Joseph M.; Wittek, Rafael

    2010-01-01

    We use a model of continuous attachments in networks to generate propositions concerning inequalities in network structures, and test the propositions on data from organizational settings. Our network model, inspired by that of [Gould, Roger 2002. The origins of status hierarchies: A formal theory a

  14. Communications Policies and Structures.

    Science.gov (United States)

    Pigeat, Henri; And Others

    These two papers discuss communications policies and structures in France and in the United States. The first paper reports that efforts to develop new electronic communication systems in France are hindered by rivalry between two public monopolies and by governmental protection against foreign influence. The second paper assesses ownership of…

  15. Capital Structure and Assets

    DEFF Research Database (Denmark)

    Flor, Christian Riis

    2008-01-01

    post optimally sell the assets or re-optimize the capital structure. Ex ante, more uncertain asset value decreases leverage, but not firm value, and selling the assets becomes less likely. Firms should tend to invest in assets whose value is less correlated to changes in earnings and, in addition...

  16. Nature teaching structures

    DEFF Research Database (Denmark)

    Wester, Ture

    2002-01-01

    If one is looking for an example of a conceptual design which is extremely appropriate in its morphology, well adapted to the surroundings, structurally and functionally optimised, and has a refined and appropriate appearance - all in one single configuration - you have either an exceptional and ...

  17. Structural analysis for Diagnosis

    DEFF Research Database (Denmark)

    Izadi-Zamanabadi, Roozbeh; Blanke, M.

    2001-01-01

    Aiming at design of algorithms for fault diagnosis, structural analysis of systems offers concise yet easy overall analysis. Graph-based matching, which is the essential technique to obtain redundant information for diagnosis, is re-considered in this paper. Matching is re-formulated as a problem...

  18. Structural analysis for diagnosis

    DEFF Research Database (Denmark)

    Izadi-Zamanabadi, Roozbeh; Blanke, M.

    2002-01-01

    Aiming at design of algorithms for fault diagnosis, structural analysis of systems offers concise yet easy overall analysis. Graph-based matching, which is the essential tech-nique to obtain redundant information for diagnosis, is reconsidered in this paper. Matching is reformulated as a problem...

  19. LUTE telescope structural design

    Science.gov (United States)

    Ruthven, Gregory

    1993-01-01

    The major objective of the Lunar Ultraviolet Transit Experiment (LUTE) Telescope Structural Design Study was to investigate the feasibility of designing an ultralightweight 1-m aperture system within optical performance requirements and mass budget constraints. This study uses the results from our previous studies on LUTE as a basis for further developing the LUTE structural architecture. After summarizing our results in Section 2, Section 3 begins with the overall logic we used to determine which telescope 'structural form' should be adopted for further analysis and weight estimates. Specific telescope component analysis showing calculated fundamental frequencies and how they compare with our derived requirements are included. 'First-order' component stress analyses to ensure telescope optical and structural component (i.e. mirrors & main bulkhead) weights are realistic are presented. Layouts of both the primary and tertiary mirrors showing dimensions that are consistent with both our weight and frequency calculations also form part of Section 3. Section 4 presents our calculated values for the predicted thermally induced primary-to-secondary mirror despace motion due to the large temperature range over which LUTE must operate. Two different telescope design approaches (one which utilizes fused quartz metering rods and one which assumes the entire telescope is fabricated from beryllium) are considered in this analysis. We bound the secondary mirror focus mechanism range (in despace) based on these two telescope configurations. In Section 5 we show our overall design of the UVTA (Ultraviolet Telescope Assembly) via an 'exploded view' of the sub-system. The 'exploded view' is annotated to help aid in the understanding of each sub-assembly. We also include a two view layout of the UVTA from which telescope and telescope component dimensions can be measured. We conclude our study with a set of recommendations not only with respect to the LUTE structural architecture

  20. Titanium honeycomb structure. [for supersonic aircraft wing structure

    Science.gov (United States)

    Davis, R. A.; Elrod, S. D.; Lovell, D. T.

    1972-01-01

    A brazed titanium honeycomb sandwich system for supersonic transport wing cover panels provides the most efficient structure spanwise, chordwise, and loadwise. Flutter testing shows that high wing stiffness is most efficient in a sandwich structure. This structure also provides good thermal insulation if liquid fuel is carried in direct contact with the wing structure in integral fuel tanks.

  1. The Meaning of Surface Structure and Deep Structure to Translation

    Institute of Scientific and Technical Information of China (English)

    罗源

    2014-01-01

    Surface structure and deep structure first come up with by Chomsky is an innovative action in linguistics. Despite the arguments involved around surface structure and deep structure, it is instructional to English-Chinese translation to some degree and its scientific connotation is meaningful to deepen language study and construct related disciplinary both in theory and practice.

  2. Soil Retaining Structures: Development of models for structural analysis

    NARCIS (Netherlands)

    Bakker, K.J.

    2000-01-01

    The topic of this thesis is the development of models for the structural analysis of soil retaining structures. The soil retaining structures being looked at are; block revetments, flexible retaining walls and bored tunnels in soft soil. Within this context typical structural behavior of these struc

  3. Analysis of Pumphouse RCC Frame Structure for Soil Structure Interaction

    Directory of Open Access Journals (Sweden)

    Mr A.S. Thombare

    2016-06-01

    Full Text Available When structure is built on ground some elements of structure are direct contact with soil. When loads are applied on structure internal forces are developed in both the structure as well as in soil. It results in deformation of both the components which are independent to each other. This are called soil structure interaction. The analysis is done by using (Bentley STAAD.Pro V8i Version 2007 software. The analysis carried out been pump house structure R.C.C. frame structure find out shear force Z direction fixed support and fixed but support for different soil. It concluded that soil structure interaction more affected on fixed base. So overcome the effects of the soil structure interaction on the soft soil, it is important to design the structure to standard loading condition and interaction forces. Thus here concluded that pump house building should be design resist the maximum shear force in fixed base

  4. Rigid collapsible dish structure

    Science.gov (United States)

    Palmer, William B. (Inventor); Giebler, Martin M. (Inventor)

    1982-01-01

    A collapsible dish structure composed of a plurality of rows of rigid radial petal assemblies concentric with the axis of the dish. The petal assemblies consist of a center petal and two side petals, the center petal hinged on an axis tangent to a circle concentric with the axis of the dish and the side petals hinged to the center petal at their mating edge. The center petal is foldable inwardly and the side petals rotate about their hinges such that the collapsed dish structure occupies a much smaller volume than the deployed dish. Means of controlling the shape of the dish to compensate for differential expansion of the deployed dish are also provided.

  5. Integrated Structural Design Education

    DEFF Research Database (Denmark)

    Bjerregaard Jensen, Lotte; Almegaard, Henrik

    2011-01-01

    In Environmental Impact Assessment (EIA), the environment is broadly defined and includes not only quantifiable aspects, but also social conditions, scenic beauty, traffic, cultural heritage, and commercial development. A successful bridge design must comply with all of these demands according to...... of a project, function well in design teams, and comply with EU EIA demands.......In Environmental Impact Assessment (EIA), the environment is broadly defined and includes not only quantifiable aspects, but also social conditions, scenic beauty, traffic, cultural heritage, and commercial development. A successful bridge design must comply with all of these demands according...... landscaping and structural design. The integrated courses create a setting for learning about the design of large-scale structures and involve geometry, statics, computer simulation, graphical design and landscape architecture. Together, they educate engineers who can take part in the early design phases...

  6. Sparse structure regularized ranking

    KAUST Repository

    Wang, Jim Jing-Yan

    2014-04-17

    Learning ranking scores is critical for the multimedia database retrieval problem. In this paper, we propose a novel ranking score learning algorithm by exploring the sparse structure and using it to regularize ranking scores. To explore the sparse structure, we assume that each multimedia object could be represented as a sparse linear combination of all other objects, and combination coefficients are regarded as a similarity measure between objects and used to regularize their ranking scores. Moreover, we propose to learn the sparse combination coefficients and the ranking scores simultaneously. A unified objective function is constructed with regard to both the combination coefficients and the ranking scores, and is optimized by an iterative algorithm. Experiments on two multimedia database retrieval data sets demonstrate the significant improvements of the propose algorithm over state-of-the-art ranking score learning algorithms.

  7. Resource Structuring and Ambidexterity

    DEFF Research Database (Denmark)

    Ma, Yucheng; Li, Peter Ping

    -shaped effect on organizational ambidexterity in new ventures. Further, because of the traditional culture and economic transition characteristics, new ventures actively leverage managerial ties as key social relations to obtain special resources or nurture business transactions. We propose that ties with other......Focusing on how resource structuring mechanisms and managerial ties influence organizational ambidexterity of new ventures in emerging economy, this study explores the effects of resource structuring mechanisms (i.e., resource acquiring and resource accumulating) on organizational ambidexterity....... It further examines the moderating effects of managerial ties, (i.e., ties with other firms and ties with the government) on the above relationships. Survey data from China¡¯s 202 new ventures demonstrates that the resource acquiring has an inverted U-shaped effect whereas the resource accumulating has a U...

  8. Structural and Material Instability

    DEFF Research Database (Denmark)

    Cifuentes, Gustavo Cifuentes

    This work is a small contribution to the general problem of structural and material instability. In this work, the main subject is the analysis of cracking and failure of structural elements made from quasi-brittle materials like concrete. The analysis is made using the finite element method. Three...... use of interface elements) is used successfully to model cases where the path of the discontinuity is known in advance, as is the case of the analysis of pull-out of fibers embedded in a concrete matrix. This method is applied to the case of non-straight fibers and fibers with forces that have....... Numerical problems associated with the use of elements with embedded cracks based on the extended finite element method are presented in the next part of this work. And an alternative procedure is used in order to successfully remove these numerical problems. In the final part of this work, a computer...

  9. Diagnosable structured logic array

    Science.gov (United States)

    Whitaker, Sterling (Inventor); Miles, Lowell (Inventor); Gambles, Jody (Inventor); Maki, Gary K. (Inventor)

    2009-01-01

    A diagnosable structured logic array and associated process is provided. A base cell structure is provided comprising a logic unit comprising a plurality of input nodes, a plurality of selection nodes, and an output node, a plurality of switches coupled to the selection nodes, where the switches comprises a plurality of input lines, a selection line and an output line, a memory cell coupled to the output node, and a test address bus and a program control bus coupled to the plurality of input lines and the selection line of the plurality of switches. A state on each of the plurality of input nodes is verifiably loaded and read from the memory cell. A trusted memory block is provided. The associated process is provided for testing and verifying a plurality of truth table inputs of the logic unit.

  10. DNA: Structure and function

    DEFF Research Database (Denmark)

    Sinden, Richard R.; E. Pearson, Christopher; N. Potaman, Vladimir

    1998-01-01

    for a long period of time before its information is accessed by the cell. Although DNA plays a critical role as an informational storage molecule, it is by no means as unexciting as a computer tape or disk drive. The structure of the DNA described by Watson and Crick in 1953 is a right handed helix of two......This chapter discusses the structure and function of DNA. DNA occupies a critical role in cells, because it is the source of all intrinsic genetic information. Chemically, DNA is a very stable molecule, a characteristic important for a macromolecule that may have to persist in an intact form...... individual antiparallel DNA strands. Hydrogen bonds provide specificity that allows pairing between the complementary bases (A.T and G.C) in opposite strands. Base stacking occurs near the center of the DNA helix and provides a great deal of stability to the helix (in addition to hydrogen bonding). The sugar...

  11. Thermally stable deployable structure

    Science.gov (United States)

    Kegg, Colleen M.

    1988-01-01

    A deployable structure which meets stringent thermal and strength requirements in a space environment was developed. A mast with a very low coefficient of thermal expansion (CTE) was required to limit the movement from thermal distortion over the temperature range of -200 C to 80 C to .064 cm (.025 in). In addition, a high bending strength over the temperature range and weight less than 18.1 kg (40 lbs) was needed. To meet all of the requirements, a composite, near-zero CTE structure was developed. The measured average CTE over the temperature range for the mast was .70 x .000001/C (.38 x .000001/F). The design also has the advantage of being adjustable to attain other specific CTE if desired.

  12. Dedicated Deployable Aerobraking Structure

    Science.gov (United States)

    Giersch, Louis R.; Knarr, Kevin

    2010-01-01

    A dedicated deployable aerobraking structure concept was developed that significantly increases the effective area of a spacecraft during aerobraking by up to a factor of 5 or more (depending on spacecraft size) without substantially increasing total spacecraft mass. Increasing the effective aerobraking area of a spacecraft (without significantly increasing spacecraft mass) results in a corresponding reduction in the time required for aerobraking. For example, if the effective area of a spacecraft is doubled, the time required for aerobraking is roughly reduced to half the previous value. The dedicated deployable aerobraking structure thus enables significantly shorter aerobraking phases, which results in reduced mission cost, risk, and allows science operations to begin earlier in the mission.

  13. Generative Moire Structures

    Directory of Open Access Journals (Sweden)

    Adrian – Mihail Marian

    2006-01-01

    Full Text Available “GRAPHIC ON COMPUTER” – the work of the Czech Petar Milojevic, published in Titus Mocanu’s book “THE MODERN ART’S MORPHOLOGY”, in 1973, had great influence on me. I tried to discover the algorithm that generated this work. It was not so difficult to do and in a short time I was able to draw 12 such structures. In time, with interruptions, I have returned to this kind of works. In my personal exhibition “CYBERNETIC DESIGN” that took place at “M4-1-13-etopa” gallery of Pitesti, in March 1981, I have presented 8 such structures. To my joy, they had an impact on art lovers.

  14. Structure of exoplanets

    Science.gov (United States)

    Spiegel, David S.; Fortney, Jonathan J.; Sotin, Christophe

    2014-01-01

    The hundreds of exoplanets that have been discovered in the past two decades offer a new perspective on planetary structure. Instead of being the archetypal examples of planets, those of our solar system are merely possible outcomes of planetary system formation and evolution, and conceivably not even especially common outcomes (although this remains an open question). Here, we review the diverse range of interior structures that are both known and speculated to exist in exoplanetary systems—from mostly degenerate objects that are more than 10× as massive as Jupiter, to intermediate-mass Neptune-like objects with large cores and moderate hydrogen/helium envelopes, to rocky objects with roughly the mass of Earth. PMID:24379369

  15. The Structure of Exoplanets

    CERN Document Server

    Spiegel, David S; Sotin, Christophe

    2013-01-01

    The hundreds of exoplanets that have been discovered in the past two decades offer a new perspective on planetary structure. Instead of being the archetypal examples of planets, those of our Solar System are merely possible outcomes of planetary system formation and evolution, and conceivably not even terribly common outcomes (although this remains an open question). Here, we review the diverse range of interior structures that are known to, and speculated to, exist in exoplanetary systems -- from mostly degenerate objects that are more than 10 times as massive as Jupiter, to intermediate-mass Neptune-like objects with large cores and moderate hydrogen/helium envelopes, to rocky objects with roughly the mass of the Earth.

  16. Structure of exoplanets.

    Science.gov (United States)

    Spiegel, David S; Fortney, Jonathan J; Sotin, Christophe

    2014-09-02

    The hundreds of exoplanets that have been discovered in the past two decades offer a new perspective on planetary structure. Instead of being the archetypal examples of planets, those of our solar system are merely possible outcomes of planetary system formation and evolution, and conceivably not even especially common outcomes (although this remains an open question). Here, we review the diverse range of interior structures that are both known and speculated to exist in exoplanetary systems--from mostly degenerate objects that are more than 10× as massive as Jupiter, to intermediate-mass Neptune-like objects with large cores and moderate hydrogen/helium envelopes, to rocky objects with roughly the mass of Earth.

  17. Introduction to structural chemistry

    CERN Document Server

    Batsanov, Stepan S

    2014-01-01

    A concise description of models and quantitative parameters in structural chemistry and their interrelations, with 280 tables and >3000 references giving the most up-to-date experimental data on energy characteristics of atoms, molecules and crystals (ionisation potentials, electron affinities, bond energies, heats of phase transitions, band and lattice energies), optical properties (refractive index, polarisability), spectroscopic characteristics and geometrical parameters (bond distances and angles, coordination numbers) of substances in gaseous, liquid and solid states, in glasses and melts, for various thermodynamic conditions. Systems of metallic, covalent, ionic and van der Waals radii, effective atomic charges and other empirical and semi-empirical models are critically revised. Special attention is given to new and growing areas: structural studies of solids under high pressures and van der Waals molecules in gases. The book is addressed to researchers, academics, postgraduates and advanced-course stu...

  18. Structure Size Enhanced Histogram

    Science.gov (United States)

    Wesarg, Stefan; Kirschner, Matthias

    Direct volume visualization requires the definition of transfer functions (TFs) for the assignment of opacity and color. Multi-dimensional TFs are based on at least two image properties, and are specified by means of 2D histograms. In this work we propose a new type of a 2D histogram which combines gray value with information about the size of the structures. This structure size enhanced (SSE) histogram is an intuitive approach for representing anatomical features. Clinicians — the users we are focusing on — are much more familiar with selecting features by their size than by their gradient magnitude value. As a proof of concept, we employ the SSE histogram for the definition of two-dimensional TFs for the visualization of 3D MRI and CT image data.

  19. Computation and Spacetime Structure

    CERN Document Server

    Stannett, Mike

    2011-01-01

    We investigate the relationship between computation and spacetime structure, focussing on the role of closed timelike curves (CTCs) in promoting computational speedup. We note first that CTC traversal can be interpreted in two distinct ways, depending on ones understanding of spacetime. Focussing on one interpretation leads us to develop a toy universe in which no CTC can be traversed more than once, whence no computational speedup is possible. Focussing on the second (and more standard) interpretation leads to the surprising conclusion that CTCs act as perfect information repositories: just as black holes have entropy, so do CTCs. If we also assume that P is not equal to NP, we find that all observers agree that, even if unbounded time travel existed in their youth, this capability eventually vanishes as they grow older. Thus the computational assumption "P is not NP" is also an assumption concerning cosmological structure.

  20. Simulating Cosmic Structure Formation

    CERN Document Server

    Weinberg, D H; Hernquist, L E; Weinberg, David H.; Katz, Neal; Hernquist, Lars

    1997-01-01

    We describe cosmological simulation techniques and their application to studies of cosmic structure formation, with particular attention to recent hydrodynamic simulations of structure in the high redshift universe. Collisionless N-body simulations with Gaussian initial conditions produce a pattern of sheets, filaments, tunnels, and voids that resembles the observed large scale galaxy distribution. Simulations that incorporate gas dynamics and dissipation form dense clumps of cold gas with sizes and masses similar to the luminous parts of galaxies. Models based on inflation and cold dark matter predict a healthy population of high redshift galaxies, including systems with star formation rates of 20 M_{\\sun}/year at z=6. At z~3, most of the baryons in these models reside in the low density intergalactic medium, which produces fluctuating Lyman-alpha absorption in the spectra of background quasars. The physical description of this ``Lyman-alpha forest'' is particularly simple if the absorption spectrum is viewe...

  1. Structural Stator Spacers

    DEFF Research Database (Denmark)

    Rasmussen, Peter Omand; Andreasen, Jens H.; Pijanowski, J. M.

    2001-01-01

    This paper presents a powerful new design aspect to reduce acoustic noise and vibration of electro-magnetic origin for electrical machines, by introducing improved slot wedges referred to as "Structural Stator Spacers". These spacers, by using a very stiff dielectric and non magnetic material...... drawbacks usually associated with other noise reduction methods or interdict other noise control methods. Design models and practical prototypes are detailed which are used to verify the effectiveness of the spacers......., a modified shape and small modifications to the stator laminations not only secure the windings and reduce windage losses but also make it possible to increase the stiffness of the stator structure significantly thereby reducing the generation of audible noise. This new method does not incur the significant...

  2. Planetary internal structures

    CERN Document Server

    Baraffe, I; Fortney, J; Sotin, C

    2014-01-01

    This chapter reviews the most recent advancements on the topic of terrestrial and giant planet interiors, including Solar System and extrasolar objects. Starting from an observed mass-radius diagram for known planets in the Universe, we will discuss the various types of planets appearing in this diagram and describe internal structures for each type. The review will summarize the status of theoretical and experimental works performed in the field of equation of states (EOS) for materials relevant to planetary interiors and will address the main theoretical and experimental uncertainties and challenges. It will discuss the impact of new EOS on interior structures and bulk composition determination. We will discuss important dynamical processes which strongly impact the interior and evolutionary properties of planets (e.g plate tectonics, semiconvection) and describe non standard models recently suggested for our giant planets. We will address the case of short-period, strongly irradiated exoplanets and critica...

  3. Structured light scatteroscopy.

    Science.gov (United States)

    Krishnaswamy, Venkataramanan; Elliott, Jonathan T; McClatchy, David M; Barth, Richard J; Wells, Wendy A; Pogue, Brian W; Paulsen, Keith D

    2014-01-01

    A new imaging approach, structured light scatteroscopy (SLS), is demonstrated, which offers rapid wide-field imaging of microscopic morphological variations in bulk tissue surfaces. Elastic scattering of light offers exquisite sensitivity to ultrastructural changes at multiple size scales ranging from nanometers to millimeters, but in bulk tissues the confounding effects of molecular absorption and strong multiple scattering of light often lead to a dramatic reduction in scatter contrast and specificity. It is demonstrated that the SLS using structured high spatial frequency illumination and detection to probe the tissue achieves direct, absorption-independent, high-resolution maps of the scattering response. The scattering response is observed to be dependent on both the wavelength and spatial frequency of choice, indicating a potential for multiscale probing of ultrastructural changes in superficial tissue layers. This methodology can be easily applied in most wide-field imaging systems.

  4. Dynamic Data Structures

    DEFF Research Database (Denmark)

    Tsakalidis, Konstantinos

    We study dynamic data structures for different variants of orthogonal range reporting query problems. In particular, we consider (1) the planar orthogonal 3-sided range reporting problem: given a set of points in the plane, report the points that lie within a given 3-sided rectangle with one....... Dynamic problems like the above arise in various applications of network optimization, VLSI layout design, computer graphics and distributed computing. For the first problem, we present dynamic data structures for internal and external memory that support planar orthogonal 3-sided range reporting queries...... unbounded side, (2) the planar orthogonal range maxima reporting problem: given a set of points in the plane, report the points that lie within a given orthogonal range and are not dominated by any other point in the range, and (3) the problem of designing fully persistent B-trees for external memory...

  5. Optimization of structural shapes

    Science.gov (United States)

    Durelli, A. J.

    1981-04-01

    The direct design of shapes of two dimensional structures, loaded in their plane, within specified design constraints and exhibiting optimum distribution of stresses is studied. Photoelasticity and a large field diffused polariscope is used. The optimization process involves the removal of material (with a hand file or router) from the low stress portions of the hole boundary of the model till an isochromatic fringe coincides with the boundary both on the tensile and compressive segments. Applications are also shown to the design of dove tails and slots in turbine blades and rotors, and to the design of star shaped solid propellant grains for rockets, both for the case of parallel side rays and enlarged tip of rays. The use of other methods, in particular the method using finite elements, to optimize structural forms is discussed.

  6. Multi-functional composite structures

    Energy Technology Data Exchange (ETDEWEB)

    Mulligan, Anthony C.; Halloran, John; Popovich, Dragan; Rigali, Mark J.; Sutaria, Manish P.; Vaidyanathan, K. Ranji; Fulcher, Michael L.; Knittel, Kenneth L.

    2010-04-27

    Fibrous monolith processing techniques to fabricate multifunctional structures capable of performing more than one discrete function such as structures capable of bearing structural loads and mechanical stresses in service and also capable of performing at least one additional non-structural function.

  7. Multi-functional composite structures

    Energy Technology Data Exchange (ETDEWEB)

    Mulligan, Anthony C.; Halloran, John; Popovich, Dragan; Rigali, Mark J.; Sutaria, Manish P.; Vaidyanathan, K. Ranji; Fulcher, Michael L.; Knittel, Kenneth L.

    2004-10-19

    Fibrous monolith processing techniques to fabricate multifunctional structures capable of performing more than one discrete function such as structures capable of bearing structural loads and mechanical stresses in service and also capable of performing at least one additional non-structural function.

  8. Space deployable truss structure design

    Science.gov (United States)

    Coyner, J. V., Jr.; Tobey, W. H.

    1981-01-01

    The development status of the deployable box truss structure is summarized. Potential applications for this structural system are described. Structural and component design requirements derived from these applications are discussed. Components of prototype 4.6 m cubes which incorporate graphite/epoxy structural members, fittings, and mechanisms are described. The benefits of the component designs and their respective manufacturing processes are presented.

  9. Combinatorics of γ-Structures

    DEFF Research Database (Denmark)

    Han, Hillary Siwei; Li, Thomas Jiaxian; reidys, Christian

    2014-01-01

    In this paper we study canonical $\\gamma$-structures, a class of RNA pseudoknot structures that plays a key role in the context of polynomial time folding of RNA pseudoknot structures. A $\\gamma$-structure is composed by specific building blocks, that have topological genus less than or equal to ...

  10. Combinatorics of γ-Structures

    DEFF Research Database (Denmark)

    Han, Hillary Siwei; Li, Thomas Jiaxian; reidys, Christian

    2014-01-01

    In this paper we study canonical $\\gamma$-structures, a class of RNA pseudoknot structures that plays a key role in the context of polynomial time folding of RNA pseudoknot structures. A $\\gamma$-structure is composed by specific building blocks, that have topological genus less than or equal...

  11. Homogeneous Clifford structures

    OpenAIRE

    Moroianu, Andrei; Pilca, Mihaela

    2012-01-01

    We give an upper bound for the rank r of homogeneous (even) Clifford structures on compact manifolds of non-vanishing Euler characteristic. More precisely, we show that if r = 2a � b with b odd, then r � 9 for a = 0, r � 10 for a = 1, r � 12 for a = 2 and r � 16 for a � 3. Moreover, we describe the four limiting cases and show that there is exactly one solution in each case.

  12. Structural Analysis Made 'NESSUSary'

    Science.gov (United States)

    2005-01-01

    Everywhere you look, chances are something that was designed and tested by a computer will be in plain view. Computers are now utilized to design and test just about everything imaginable, from automobiles and airplanes to bridges and boats, and elevators and escalators to streets and skyscrapers. Computer-design engineering first emerged in the 1970s, in the automobile and aerospace industries. Since computers were in their infancy, however, architects and engineers during the time were limited to producing only designs similar to hand-drafted drawings. (At the end of 1970s, a typical computer-aided design system was a 16-bit minicomputer with a price tag of $125,000.) Eventually, computers became more affordable and related software became more sophisticated, offering designers the "bells and whistles" to go beyond the limits of basic drafting and rendering, and venture into more skillful applications. One of the major advancements was the ability to test the objects being designed for the probability of failure. This advancement was especially important for the aerospace industry, where complicated and expensive structures are designed. The ability to perform reliability and risk assessment without using extensive hardware testing is critical to design and certification. In 1984, NASA initiated the Probabilistic Structural Analysis Methods (PSAM) project at Glenn Research Center to develop analysis methods and computer programs for the probabilistic structural analysis of select engine components for current Space Shuttle and future space propulsion systems. NASA envisioned that these methods and computational tools would play a critical role in establishing increased system performance and durability, and assist in structural system qualification and certification. Not only was the PSAM project beneficial to aerospace, it paved the way for a commercial risk- probability tool that is evaluating risks in diverse, down- to-Earth application

  13. Plasmonics in buried structures

    OpenAIRE

    Romero, I. T.; García de Abajo, Francisco Javier

    2009-01-01

    We describe plasmon propagation in silica-filled coupled nanovoids fully buried in gold. Propagation bands and band gaps are shown to be tunable through the degree of overlap and plasmon hybridization between contiguous voids. The effect of disorder and fabrication imperfections is thoroughly investigated. Our work explores a novel paradigm for plasmon photonics relying on plasmon modes in metal-buried structures, which can benefit from long propagation distances, cancelation of radiative los...

  14. Lightweight Structure in Text

    Science.gov (United States)

    2002-05-01

    1 1.2 A web page that lists electronic books available for downloading. . . . . . . . . . . 2 1.3 A web page from Yahoo...with some of its structure labeled. 1 2 CHAPTER 1. INTRODUCTION book title year author genre format Figure 1.2: A web page that lists electronic ... books available for downloading. advertisement user date hyperlink Figure 1.3: A web page from Yahoo. method type method name statement

  15. Birefringent phononic structures

    Directory of Open Access Journals (Sweden)

    I. E. Psarobas

    2014-12-01

    Full Text Available Within the framework of elastic anisotropy, caused in a phononic crystal due to low crystallographic symmetry, we adopt a model structure, already introduced in the case of photonic metamaterials, and by analogy, we study the effect of birefringence and acoustical activity in a phononic crystal. In particular, we investigate its low-frequency behavior and comment on the factors which determine chirality by reference to this model.

  16. Dynamic Weighted Data Structures.

    Science.gov (United States)

    1982-06-01

    and Bonnie Hampton, who taught me much more than how to play the cello . Finally, for hours of artistic satisfaction, I thank Johannes Brahms, Ludwig...van "j Beethoven, Igor Stravinsky, Glan-Carlo Menotti, and Johann Sebastian Bach . Dynamic Weighted Data Structures Samuel W. Bent This thesis discusses...34I find It a matter of some difficulty to arrange these cards In a manner suited to my needs.’ I glanced at the cards and noticed each was labelled

  17. Lymphotactin structural dynamics

    OpenAIRE

    Volkman, Brian F.; Liu, Tina Y.; Peterson, Francis C.

    2009-01-01

    Lymphotactin/XCL1, the defining member of the C class of chemokines, undergoes a conformational change that involves the complete restructuring of all stabilizing interactions. Other chemokines are restricted to a single conformation by a pair of conserved disulfide crosslinks, one of which is absent in lymphotactin. This structural interconversion is entirely reversible, and the two-state equilibrium is sensitive to changes in temperature and ionic strength. One species adopts the conserved ...

  18. Foams structure and dynamics

    CERN Document Server

    Cantat, Isabelle; Graner, François; Pitois, Olivier; Höhler, Reinard; Elias, Florence; Saint-Jalmes, Arnaud; Rouyer, Florence

    2013-01-01

    This book is the first to provide a thorough description of all aspects of the physico-chemical properties of foams. It sets out what is known about their structure, their stability, and their rheology. Engineers, researchers and students will find descriptions of all the key concepts, illustrated by numerous applications, as well as experiments and exercises for the reader. A solutions manual for lecturers is available via the publisher's web site.

  19. Photonic bandgap structures

    CERN Document Server

    Marco, Pisco; Antonello, Cutolo

    2012-01-01

    This E-Book covers the research and the development of a novel generation of photonic devices for sensing applications. Key features of this book include a brief review of basic PhCs related design and fabrication concepts, a selection of crossover topics for the development of novel technological platforms for physical, chemical and biological sensing and a description of the main PhCs sensors to date by representing many of the exciting sensing applications that utilize photonic crystal structures.

  20. Crystal Structures of Furazanes

    OpenAIRE

    Klapötke, Thomas; Schmid, Philipp; Stierstorfer, Jörg

    2015-01-01

    Several nitrogen-rich salts of 3-nitramino-4-nitrofurazane and dinitraminoazoxyfurazane were synthesized and characterized by various spectroscopic methods. The crystal structures were determined by low temperature single crystal X-ray diffraction. Moreover the sensitivities toward thermal and mechanical stimuli were determined by differential thermal analysis (DTA) and BAM (Bundesanstalt für Materialforschung und -prüfung) methods. The standard enthalpies of formation were calculated for all...

  1. Discrete computational structures

    CERN Document Server

    Korfhage, Robert R

    1974-01-01

    Discrete Computational Structures describes discrete mathematical concepts that are important to computing, covering necessary mathematical fundamentals, computer representation of sets, graph theory, storage minimization, and bandwidth. The book also explains conceptual framework (Gorn trees, searching, subroutines) and directed graphs (flowcharts, critical paths, information network). The text discusses algebra particularly as it applies to concentrates on semigroups, groups, lattices, propositional calculus, including a new tabular method of Boolean function minimization. The text emphasize

  2. ARMY CYBER STRUCTURE ALIGNMENT

    Science.gov (United States)

    2016-02-16

    USCYBERCOM and insertion of supporting services into the cyber organizational architecture introduced the problem of overlapping command and...the cyber force organizational structure and roles and responsibilities to meet the strategic goals defined by Department of Defense (DoD) and U.S...significantly constrained by internal bureaucratic priorities and organizational cultures that limited the holistic approach required to achieve unity of effort

  3. What determines family structure?

    OpenAIRE

    Blau, David M.; van der Klaauw, Wilbert

    2010-01-01

    We estimate the effects of policy and labor market variables on the fertility, union formation and dissolution, type of union (cohabiting versus married), and partner choices of the NLSY79 cohort of women. These demographic behaviors interact to determine the family structure experienced by the children of these women: living with the biological mother and the married or cohabiting biological father, a married or cohabiting step father, or no man. We find that the average wage rates available...

  4. Hierarchically Structured Electrospun Fibers

    Science.gov (United States)

    2013-01-07

    range of fluorescence could be tuned from yellow-green to blue , making these fibers ideal for micro- and nano-optoelectronic devices [144]. Figure 7...forces. Rapid phase separation of the distorted droplet and energy minimization may lead to the formation of the spider -web-like structure of the fiber...engineering cellularized blood vessels. Biomaterials 2010, 31, 4313–4321. 59. Thorvaldsson, A.; Stenhamre, H.; Gatenholm, P.; Walkenstrom, P

  5. Stereochemistry Structure of Odonicin

    Energy Technology Data Exchange (ETDEWEB)

    Li, Bao Lin; Li, Jin; Tong, Ling [Shaanxi Normal University, Xian (China); Pan, Yuan Jiang [Zhejiang University, Hangzhou (China); Yu, Kai Bei [Academia Sinica, Chengdu (China)

    2004-02-15

    Ent-kaurene diterpenoids have various biological activities, such as antitumor, antibacterial, anti-HIV activities etc. The plant of the genus Isodon used in Chinese traditional medicine is a major source of compounds of this structural class. Our investigations on the bitter diterpenoids constituents of the genus Isodon led to the first isolation of odonicin (1) from the leaves and tender branches of Isodon henryi obtained from Taibai Mountain, Shaanxi Province, P. R. China

  6. 7. Administrative structures.

    Science.gov (United States)

    2014-05-01

    The basic systems of any society rarely can operate independently. Instead, they are dependent and often interdependent upon other entities. Such entities control the resources within their respective systems. Thus, coordination and control agencies require contracts or memoranda of understanding with these entities in order to assure access to the resources required during a crisis. These administrative structures include: (1) governmental institutions and agencies, including the military; (2) intergovernmental organisations; (3) nongovernmental organisations; (4) commercial private sector organisations; and (5) academic institutions. These dependencies create potential barriers to the provision of coordination and control including: (1) the complexity of the administrative structures with which coordination and control must interact; (2) the location of resources; (3) finding responsible person(s); (4) the competence and compatibility; (5) methods of access; (6) payment; (7) contracts and memoranda of understanding; (8) inventories of accessible resources; (9) competition for the mandate, power, and resources; and (10) jealousy. The need for potential interactions between administrative structures requires that agreements for the sharing of resources during crises be reached as part of planning and preparedness. Gaining an understanding of these relationships is an important area for research.

  7. Features and Recursive Structure

    Directory of Open Access Journals (Sweden)

    Kuniya Nasukawa

    2015-01-01

    Full Text Available Based on the cross-linguistic tendency that weak vowels are realized with a central quality such as ə, ɨ, or ɯ, this paper attempts to account for this choice by proposing that the nucleus itself is one of the three monovalent vowel elements |A|, |I| and |U| which function as the building blocks of melodic structure. I claim that individual languages make a parametric choice to determine which of the three elements functions as the head of a nuclear expression. In addition, I show that elements can be freely concatenated to create melodic compounds. The resulting phonetic value of an element compound is determined by the specific elements it contains and by the head-dependency relations between those elements. This concatenation-based recursive mechanism of melodic structure can also be extended to levels above the segment, thus ultimately eliminating the need for syllabic constituents. This approach reinterprets the notion of minimalism in phonology by opposing the string-based flat structure.

  8. Visual narrative structure.

    Science.gov (United States)

    Cohn, Neil

    2013-04-01

    Narratives are an integral part of human expression. In the graphic form, they range from cave paintings to Egyptian hieroglyphics, from the Bayeux Tapestry to modern day comic books (Kunzle, 1973; McCloud, 1993). Yet not much research has addressed the structure and comprehension of narrative images, for example, how do people create meaning out of sequential images? This piece helps fill the gap by presenting a theory of Narrative Grammar. We describe the basic narrative categories and their relationship to a canonical narrative arc, followed by a discussion of complex structures that extend beyond the canonical schema. This demands that the canonical arc be reconsidered as a generative schema whereby any narrative category can be expanded into a node in a tree structure. Narrative "pacing" is interpreted as a reflection of various patterns of this embedding: conjunction, left-branching trees, center-embedded constituencies, and others. Following this, diagnostic methods are proposed for testing narrative categories and constituency. Finally, we outline the applicability of this theory beyond sequential images, such as to film and verbal discourse, and compare this theory with previous approaches to narrative and discourse.

  9. Mycorrhizas and soil structure.

    Science.gov (United States)

    Rillig, Matthias C; Mummey, Daniel L

    2006-01-01

    In addition to their well-recognized roles in plant nutrition and communities, mycorrhizas can influence the key ecosystem process of soil aggregation. Here we review the contribution of mycorrhizas, mostly focused on arbuscular mycorrhizal fungi (AMF), to soil structure at various hierarchical levels: plant community; individual root; and the soil mycelium. There are a suite of mechanisms by which mycorrhizal fungi can influence soil aggregation at each of these various scales. By extension of these mechanisms to the question of fungal diversity, it is recognized that different species or communities of fungi can promote soil aggregation to different degrees. We argue that soil aggregation should be included in a more complete 'multifunctional' perspective of mycorrhizal ecology, and that in-depth understanding of mycorrhizas/soil process relationships will require analyses emphasizing feedbacks between soil structure and mycorrhizas, rather than a uni-directional approach simply addressing mycorrhizal effects on soils. We finish the discussion by highlighting new tools, developments and foci that will probably be crucial in further understanding mycorrhizal contributions to soil structure.

  10. Structural Proteomics of Herpesviruses

    Directory of Open Access Journals (Sweden)

    Baptiste Leroy

    2016-02-01

    Full Text Available Herpesviruses are highly prevalent viruses associated with numerous pathologies both in animal and human populations. Until now, most of the strategies used to prevent or to cure these infections have been unsuccessful because these viruses have developed numerous immune evasion mechanisms. Therefore, a better understanding of their complex lifecycle is needed. In particular, while the genome of numerous herpesviruses has been sequenced, the exact composition of virions remains unknown for most of them. Mass spectrometry has recently emerged as a central method and has permitted fundamental discoveries in virology. Here, we review mass spectrometry-based approaches that have recently allowed a better understanding of the composition of the herpesvirus virion. In particular, we describe strategies commonly used for proper sample preparation and fractionation to allow protein localization inside the particle but also to avoid contamination by nonstructural proteins. A collection of other important data regarding post-translational modifications or the relative abundance of structural proteins is also described. This review also discusses the poorly studied importance of host proteins in herpesvirus structural proteins and the necessity to develop a quantitative workflow to better understand the dynamics of the structural proteome. In the future, we hope that this collaborative effort will assist in the development of new strategies to fight these infections.

  11. Fields with Analytic Structure

    CERN Document Server

    Cluckers, Raf

    2009-01-01

    We present a unifying theory of fields with certain classes of analytic functions, called fields with analytic structure. Both real closed fields and Henselian valued fields are considered. For real closed fields with analytic structure, o-minimality is shown. For Henselian valued fields, both the model theory and the analytic theory are developed. We give a list of examples that comprises, to our knowledge, all principal, previously studied, analytic structures on Henselian valued fields, as well as new ones. The b-minimality is shown, as well as other properties useful for motivic integration on valued fields. The paper is reminiscent of [Denef, van den Dries, "p-adic and real subanalytic sets" Ann. of Math. (2) 128 (1988) 79--138], of [Cohen, Paul J. "Decision procedures for real and p-adic fields" Comm. Pure Appl. Math. 22 (1969) 131--151, and of [Fresnel, van der Put, "Rigid analytic geometry and its applications" Progress in Mathematics, 218 Birkhauser (2004)], and unifies work by van den Dries, Haskell...

  12. STRUCTURED CLINICAL EVALUATION

    Directory of Open Access Journals (Sweden)

    Arabela Maria Barbosa Sampaio

    2014-05-01

    Full Text Available In a world experiencing profound technological and socio-political changes in areas of knowledge and capacity, healthcare can not remain static. A new kind of professional is required, whose practice is based on ethics, scientific standards, integrity, citizenship, and health promotion, who develops skills beyond healthcare, such as decision making, communication,leadership, management, and continuing education. No single method can assess all of these elements (knowledge, skills, and attitudes, and only a combination of methods is able to produce a valid evaluation. An alternative method exists: structured clinical assessments based on observation of "to do, or how to do" that aim to complete this evaluation by focusing attention on the performance of specific skills. In order to broaden the scope of evaluation methods that have been used in health education, this article, a literature review, intends to offer readers an overview of the diverse types of structured clinical evaluation, emphasizing Objective Structured Clinical Examination, the most widely used in Brazil, with a goal of advancing opportunities for health professionals to make use of this evaluative tool.

  13. Hypersonic Materials and Structures

    Science.gov (United States)

    Glass, David E.

    2016-01-01

    Thermal protection systems (TPS) and hot structures are required for a range of hypersonic vehicles ranging from ballistic reentry to hypersonic cruise vehicles, both within Earth's atmosphere and non-Earth atmospheres. The focus of this presentation is on air breathing hypersonic vehicles in the Earth's atmosphere. This includes single-stage to orbit (SSTO), two-stage to orbit (TSTO) accelerators, access to space vehicles, and hypersonic cruise vehicles. This paper will start out with a brief discussion of aerodynamic heating and thermal management techniques to address the high heating, followed by an overview of TPS for rocket-launched and air-breathing vehicles. The argument is presented that as we move from rocket-based vehicles to air-breathing vehicles, we need to move away from the insulated airplane approach used on the Space Shuttle Orbiter to a wide range of TPS and hot structure approaches. The primary portion of the paper will discuss issues and design options for CMC TPS and hot structure components, including leading edges, acreage TPS, and control surfaces. The current state-of-the-art will be briefly discussed for some of the components.

  14. Circular arc structures

    KAUST Repository

    Bo, Pengbo

    2011-07-01

    The most important guiding principle in computational methods for freeform architecture is the balance between cost efficiency on the one hand, and adherence to the design intent on the other. Key issues are the simplicity of supporting and connecting elements as well as repetition of costly parts. This paper proposes so-called circular arc structures as a means to faithfully realize freeform designs without giving up smooth appearance. In contrast to non-smooth meshes with straight edges where geometric complexity is concentrated in the nodes, we stay with smooth surfaces and rather distribute complexity in a uniform way by allowing edges in the shape of circular arcs. We are able to achieve the simplest possible shape of nodes without interfering with known panel optimization algorithms. We study remarkable special cases of circular arc structures which possess simple supporting elements or repetitive edges, we present the first global approximation method for principal patches, and we show an extension to volumetric structures for truly threedimensional designs. © 2011 ACM.

  15. A Molecular–Structure Hypothesis

    OpenAIRE

    Jan C. A. Boeyens

    2010-01-01

    The self-similar symmetry that occurs between atomic nuclei, biological growth structures, the solar system, globular clusters and spiral galaxies suggests that a similar pattern should characterize atomic and molecular structures. This possibility is explored in terms of the current molecular structure-hypothesis and its extension into four-dimensional space-time. It is concluded that a quantum molecule only has structure in four dimensions and that classical (Newtonian) structure, which occ...

  16. Structural Stability of Asteroids

    Science.gov (United States)

    Hirabayashi, Toshi

    This thesis develops a technique for analyzing the internal structure of an irregularly shaped asteroid. This research focuses on asteroid (216) Kleopatra, a few-hundred-kilometer-sized main belt asteroid spinning about its maximum moment of inertia axis with a rotation period of 5.385 hours, to motivate the techniques. While Ostro et al. [117] reported its dog bone-like shape, estimation of its size has been actively discussed. There are at least three different size estimates: Ostro et al., Descamps et al., and Marchis et al. Descamps et al. reported that (216) Kleopatra has satellites and obtained the mass of this object. This research consists of determination of possible failure modes of (216) Kleopatra and its subsequent detailed stress analysis, with each part including an estimation of the internal structure. The first part of this thesis considers the failure mode of Kleopatra and evaluates the size from it. Possible failure modes are modeled as either material shedding from the surface or plastic failure of the internal structure. The surface shedding condition is met when a zero-velocity curve with the same energy level as one of the dynamical equilibrium points attaches to the surface at the slowest spin period, while the plastic failure condition is characterized by extending the theorem by Holsapple (2008) that the yield condition of the averaged stress over the whole volume is identical to an upper bound for global failure. The prime result shows that while surface shedding does not occur at the current spin period and thus cannot result in the formation of the satellites, the neck may be situated near its plastic deformation state. From the failure condition, we also find that the size estimated by Descamps et al. (2011) is the most structurally stable. The second part of this thesis discusses finite element analyses with an assumption of an elastic-perfectly plastic material and a non-associated flow rule. The yield condition is modeled as the

  17. What is a (social) structural explanation?

    OpenAIRE

    Haslanger, Sally

    2015-01-01

    A philosophically useful account of social structure must accommodate the fact that social structures play an important role in structural explanation. But what is a structural explanation? How do structural explanations function in the social sciences? This paper offers a way of thinking about structural explanation and sketches an account of social structure that connects social structures with structural explanation.

  18. Repairs of composite structures

    Science.gov (United States)

    Roh, Hee Seok

    Repair on damaged composite panels was conducted. To better understand adhesively bonded repair, the study investigates the effect of design parameters on the joint strength. The design parameters include bondline length, thickness of adherend and type of adhesive. Adhesives considered in this study were tested to measure their tensile material properties. Three types of adhesively bonded joints, single strap, double strap, and single lap joint were considered under changing bondline lengths, thickness of adherend and type of adhesive. Based on lessons learned from bonded joints, a one-sided patch repair method for composite structures was conducted. The composite patch was bonded to the damaged panel by either film adhesive FM-73M or paste adhesive EA-9394 and the residual strengths of the repaired specimens were compared under varying patch sizes. A new repair method using attachments has been suggested to enhance the residual strength. Results obtained through experiments were analyzed using finite element analysis to provide a better repair design and explain the experimental results. It was observed that the residual strength of the repaired specimen was affected by patch length. Method for rapid repairs of damaged composite structures was investigated. The damage was represented by a circular hole in a composite laminated plate. Pre-cured composite patches were bonded with a quick-curing commercial adhesive near (rather than over) the hole. Tensile tests were conducted on specimens repaired with various patch geometries. The test results showed that, among the methods investigated, the best repair method restored over 90% of the original strength of an undamaged panel. The interfacial stresses in the adhesive zone for different patches were calculated in order to understand the efficiencies of the designs of these patch repairs. It was found that the composite patch that yielded the best strength had the lowest interfacial peel stress between the patch and

  19. Unibody Composite Pressurized Structure

    Science.gov (United States)

    Rufer, Markus; Conger, Robert; Bauer, Thomas; Newman, John

    2013-01-01

    An integrated, generic unibody composite pressurized structure (UCPS) combined with a positive expulsion device (PED), consisting of an elastomeric bladder for monopropellant hydrazine, has been quasi-standardized for spacecraft use. The combination functions as an all-composite, non-metallic, propellant tank with bladder. The integrated UCPS combines several previous innovations - specifically, the linerless, all-composite cryogenic tank technology; all-composite boss; resin formulation; and integrated stringer system. The innovation combines the UCPS with an integrated propellant management device (PMD), the PED or bladder, to create an entirely unique system for in-space use. The UCPS is a pressure vessel that incorporates skirts, stringers, and other structures so that it is both an in-space hydrazine tank, and also a structural support system for a spacecraft in a single, all-composite unit. This innovation builds on the progress in the development of a previous SBIR (Small Business Innovation Research) Phase I with Glenn Research Center and an SBIR III with Johnson Space Center that included the fabrication of two 42-in. (˜107-cm) diameter all-composite cryogenic (LOX and liquid methane) UCPS test tanks for a lunar lander. This Phase II provides hydra zine compatibility testing of the elastomeric bladder, a see-through PED to validate the expulsion process and model, and a complete UCPS-based PED with stringers and skirts that will be used to conduct initial qualification and expulsion tests. This extends the UCPS technology to include hydrazine-based, in-space pro - pulsion applications and can also be used for electric propulsion. This innovation creates a system that, in comparison to the traditional approach, is lower in weight, cost, volume, and production time; is stronger; and is capable of much higher pressures. It also has fewer failure modes, and is applicable to both chemical and electric propulsion systems.

  20. Structural Optimization with Reliability Constraints

    DEFF Research Database (Denmark)

    Sørensen, John Dalsgaard; Thoft-Christensen, Palle

    1986-01-01

    During the last 25 years considerable progress has been made in the fields of structural optimization and structural reliability theory. In classical deterministic structural optimization all variables are assumed to be deterministic. Due to the unpredictability of loads and strengths of actual...... structures it is now widely accepted that structural problems are non-deterministic. Therefore, some of the variables have to be modelled as random variables/processes and a reliability-based design philosophy should be used, Comell [1], Moses [2], Ditlevsen [3] and Thoft-Christensen & Baker [ 4......]. In this paper we consider only structures which can be modelled as systems of elasto-plastic elements, e.g. frame and truss structures. In section 2 a method to evaluate the reliability of such structural systems is presented. Based on a probabilistic point of view a modern structural optimization problem...

  1. Scour around coastal structures

    DEFF Research Database (Denmark)

    Sumer, B. Mutlu; Whiteouse, J. S.; Tørum, A.

    2001-01-01

    This paper summarizes the results of the European Union Marine Science and Technology (EU MAST) III project "Scour Around Coastal Structures" (SCARCOST). The summary is presented under three headings: (1) Introduction; (2) Flow and scour processes with the subheadings: flow and scour processes...... pressures and effective stresses around a bottom seated cylinder; non-linear soil modelling with respect to wave-induced pore pressures and gradients; wave-induced pressures on the bottom for non-linear coastal waves, including also wave kinematics; development of a numerical model (linear soil modelling...

  2. Algorithm for structure constants

    CERN Document Server

    Paiva, F M

    2011-01-01

    In a $n$-dimensional Lie algebra, random numerical values are assigned by computer to $n(n-1)$ especially selected structure constants. An algorithm is then created, which calculates without ambiguity the remaining constants, obeying the Jacobi conditions. Differently from others, this algorithm is suitable even for poor personal computer. ------------- En $n$-dimensia algebro de Lie, hazardaj numeraj valoroj estas asignitaj per komputilo al $n(n-1)$ speciale elektitaj konstantoj de strukturo. Tiam algoritmo estas kreita, kalkulante senambigue la ceterajn konstantojn, obeante kondicxojn de Jacobi. Malsimile al aliaj algoritmoj, tiu cxi tauxgas ecx por malpotenca komputilo.

  3. Evolving production network structures

    DEFF Research Database (Denmark)

    Grunow, Martin; Gunther, H.O.; Burdenik, H.

    2007-01-01

    When deciding about future production network configurations, the current structures have to be taken into account. Further, core issues such as the maturity of the products and the capacity requirements for test runs and ramp-ups must be incorporated. Our approach is based on optimization...... modelling and assigns products and capacity expansions to production sites under the above constraints. It also considers the production complexity at the individual sites and the flexibility of the network. Our implementation results for a large manufacturing network reveal substantial possible cost...

  4. Bridgescaping - Contextual Structural Design

    DEFF Research Database (Denmark)

    Bjerregaard Jensen, Lotte; Almegaard, Henrik

    2011-01-01

    Large-scale infrastructural projects such as bridges used to be the monopoly of engineers. They were designed as – often very beautiful – expressions of how forces work in a structure, guided by the nature of materials and a rational construction process. However, in recent decades politicians...... and investors have discovered ways of getting more from their investments by using such projects to give identity and coherence to an area. This has led to a European tendency for engineers to surrender their design opportunities and let architects take over but it does not have to be so. These projects can...

  5. Probabilistic Structured Predictors

    CERN Document Server

    Vembu, Shankar; Boley, Mario

    2012-01-01

    We consider MAP estimators for structured prediction with exponential family models. In particular, we concentrate on the case that efficient algorithms for uniform sampling from the output space exist. We show that under this assumption (i) exact computation of the partition function remains a hard problem, and (ii) the partition function and the gradient of the log partition function can be approximated efficiently. Our main result is an approximation scheme for the partition function based on Markov Chain Monte Carlo theory. We also show that the efficient uniform sampling assumption holds in several application settings that are of importance in machine learning.

  6. Hydrodynamics around cylindrical structures

    CERN Document Server

    Sumer, B Mutlu

    2006-01-01

    This book discusses the subject of wave/current flow around a cylinder, the forces induced on the cylinder by the flow, and the vibration pattern of slender structures in a marine environment. The primary aim of the book is to describe the flow pattern and the resulting load which develops when waves or current meet a cylinder. Special attention is paid to circular cylinder. The development in the forces is related to the various flow patterns and is discussed in detail. Regular as well as irregular waves are considered, and special cases like wall proximities (pipelines) are also investigated

  7. Structure of algebras

    CERN Document Server

    Albert, A A

    1939-01-01

    The first three chapters of this work contain an exposition of the Wedderburn structure theorems. Chapter IV contains the theory of the commutator subalgebra of a simple subalgebra of a normal simple algebra, the study of automorphisms of a simple algebra, splitting fields, and the index reduction factor theory. The fifth chapter contains the foundation of the theory of crossed products and of their special case, cyclic algebras. The theory of exponents is derived there as well as the consequent factorization of normal division algebras into direct factors of prime-power degree. Chapter VI con

  8. Plasmonics in buried structures.

    Science.gov (United States)

    Romero, I; García de Abajo, F J

    2009-10-12

    We describe plasmon propagation in silica-filled coupled nanovoids fully buried in gold. Propagation bands and band gaps are shown to be tunable through the degree of overlap and plasmon hybridization between contiguous voids. The effect of disorder and fabrication imperfections is thoroughly investigated. Our work explores a novel paradigm for plasmon photonics relying on plasmon modes in metal-buried structures, which can benefit from long propagation distances, cancelation of radiative losses, minimum crosstalk between neighboring waveguides, and maximum optical integration in three-dimensional arrangements.

  9. The Structure of Phenylglycinol

    Science.gov (United States)

    Simao, Alcides; Peña, Isabel; Cabezas, Carlos; Alonso, José L.

    2014-06-01

    The most abundant conformer of the amino alcohol D-phenylglycinol has been observed in gas phase using broadband chirped pulse Fourier transform microwave spectroscopy (CP-FTMW) and laser ablation molecular beam Fourier transform microwave spectroscopy (LA-MB-FTMW). The rotational spectra corresponding to seven monosubstituted 13C, one monosubstituted 15N and one monosubstituted 18O species have been observed in their natural abundance, and the rs structure has been derived. The observed conformer is stabilized by O-H\\cdotsN, N-H\\cdotsπ intramolecular hydrogen bond network.

  10. Structured Multifrontal Sparse Solver

    Energy Technology Data Exchange (ETDEWEB)

    2014-05-01

    StruMF is an algebraic structured preconditioner for the interative solution of large sparse linear systems. The preconditioner corresponds to a multifrontal variant of sparse LU factorization in which some dense blocks of the factors are approximated with low-rank matrices. It is algebraic in that it only requires the linear system itself, and the approximation threshold that determines the accuracy of individual low-rank approximations. Favourable rank properties are obtained using a block partitioning which is a refinement of the partitioning induced by nested dissection ordering.

  11. Dynamical Structure of Baryons

    CERN Document Server

    Aleksejevs, A

    2013-01-01

    Compton scattering offers a unique opportunity to study the dynamical structure of hadrons over a wide kinematic range, with polarizabilities characterizing the hadron active internal degrees of freedom. We present calculations and detailed analysis of electric and magnetic and the spin-dependent dynamical polarizabilities for the lowest in mass SU(3) octet of baryons. These extensive calculations are made possible by the recent implementation of semi-automatized calculations in chiral perturbation theory which allows evaluating polarizabilities from Compton scattering up to next-to-the-leading order. The dependencies for the range of photon energies covering the majority of the meson photoproduction channels are analyzed.

  12. Supersymmetric Optical Structures

    CERN Document Server

    Miri, Mohammad-Ali; El-Ganainy, Ramy; Christodoulides, Demetrios N

    2013-01-01

    We show that supersymmetry can provide a versatile platform in synthesizing a new class of optical structures with desired properties and functionalities. By exploiting the intimate relationship between superpatners, one can systematically construct index potentials capable of exhibiting the same scattering and guided wave characteristics. In particular, in the Helmholtz regime, we demonstrate that one-dimensional supersymmetric pairs display identical reflectivities and transmittivities for any angle of incidence. Optical SUSY is then extended to two-dimensional systems where a link between specific azimuthal mode subsets is established. Finally we explore supersymmetric photonic lattices where discreteness can be utilized to design lossless integrated mode filtering arrangements.

  13. Multifunctional Composite Structures

    Science.gov (United States)

    2010-03-01

    1  I.  INTRODUCTION ...create  the model  is significantly  lower because structured  mesh generation is easily automated.         3 I. INTRODUCTION Composite  materials...specialized materials  such  as  piezoelectric  and  magnetostrictive  materials  that  have  been used to design and build both actuators and sensors

  14. Linac 1, inner structure

    CERN Multimedia

    1968-01-01

    This photo shows the inner structure of Linac 1. As injector to the PS, and later to the Booster, Linac 1 accelerated protons to 50 MeV, but it has also accelerated heavier ions. Fitted with a 520 keV RFQ pre-injector (instead of the original Cockcroft-Walton generator), it delivered protons and heavy ions to LEAR, from 1982 to 1992. After 33 years of faithful service, Linac 1 was dismantled in 1992 to make room for Linac 3 (Pb ions).

  15. Galois module structure

    CERN Document Server

    Snaith, Victor P

    1994-01-01

    Galois module structure deals with the construction of algebraic invariants from a Galois extension of number fields with group G. Typically these invariants lie in the class-group of some group-ring of G or of a related order. These class-groups have "Hom-descriptions" in terms of idèlic-valued functions on the complex representations of G. Following a theme pioneered by A. Frölich, T. Chinburg constructed several invariants whose Hom-descriptions are (conjecturally) given in terms of Artin root numbers. For a tame extension, the second Chinburg invariant is given by the ring of integers, and

  16. Crystal Structures of Furazanes

    Directory of Open Access Journals (Sweden)

    Thomas M. Klapötke

    2015-09-01

    Full Text Available Several nitrogen-rich salts of 3-nitramino-4-nitrofurazane and dinitraminoazoxyfurazane were synthesized and characterized by various spectroscopic methods. The crystal structures were determined by low temperature single crystal X-ray diffraction. Moreover the sensitivities toward thermal and mechanical stimuli were determined by differential thermal analysis (DTA and BAM (Bundesanstalt für Materialforschung und -prüfung methods. The standard enthalpies of formation were calculated for all compounds at the CBS-4M level of theory, and the energetic performance was predicted with the EXPLO5 V6.02 computer code.

  17. Theory of convex structures

    CERN Document Server

    van de Vel, MLJ

    1993-01-01

    Presented in this monograph is the current state-of-the-art in the theory of convex structures. The notion of convexity covered here is considerably broader than the classic one; specifically, it is not restricted to the context of vector spaces. Classical concepts of order-convex sets (Birkhoff) and of geodesically convex sets (Menger) are directly inspired by intuition; they go back to the first half of this century. An axiomatic approach started to develop in the early Fifties. The author became attracted to it in the mid-Seventies, resulting in the present volume, in which graphs appear si

  18. Structure from diffraction methods

    CERN Document Server

    Bruce, Duncan W; Walton, Richard I

    2014-01-01

    Inorganic materials show a diverse range of important properties that are desirable for many contemporary, real-world applications. Good examples include recyclable battery cathode materials for energy storage and transport, porous solids for capture and storage of gases and molecular complexes for use in electronic devices. An understanding of the function of these materials is necessary in order to optimise their behaviour for real applications, hence the importance of 'structure-property relationships'. The chapters presented in this volume deal with recent advances in the characterisatio

  19. Conceptual structures in practice

    CERN Document Server

    Hitzler, Pascal

    2009-01-01

    Exploring fundamental research questions, Conceptual Structures in Practice takes you through the basic yet nontrivial task of establishing conceptual relations as the foundation for research in knowledge representation and knowledge mining. It includes contributions from leading researchers in both the conceptual graph and formal concept analysis (FCA) communities.This accessible, self-contained book begins by providing the formal background in FCA and conceptual graphs. It then describes various software tools for analysis and computation, including the ToscanaJ suite. Written by the origina

  20. Structure Learning in Audio

    DEFF Research Database (Denmark)

    Nielsen, Andreas Brinch

    and speech, using novel features based on pitch dynamics. Within instrument classification two different harmonic models have been compared. Finally voiced/unvoiced segmentation of popular music is done based on MFCC’s and AR coefficients. The structures in the mixings of multiple sources have been...... investigated. A fast and computationally simple approach that compares recordings and classifies if they are from the same audio environment have been developed, and shows very high accuracy and the ability to synchronize recordings in the case of recording devices which are not connected. A more general model...

  1. Structural Logical Relations

    DEFF Research Database (Denmark)

    Schürmann, Carsten; Sarnat, Jeffrey

    2008-01-01

    , such as Twelf, and yet they are often straightforward in proof assistants with stronger meta-logics. In this paper, we propose structural logical relations as a technique for conducting these proofs in systems with limited meta-logical strength by explicitly representing and reasoning about an auxiliary logic......Tait's method (a.k.a. proof by logical relations) is a powerful proof technique frequently used for showing foundational properties of languages based on typed lambda-calculi. Historically, these proofs have been extremely difficult to formalize in proof assistants with weak meta-logics...

  2. Data structures I essentials

    CERN Document Server

    Smolarski, Dennis C

    2012-01-01

    REA's Essentials provide quick and easy access to critical information in a variety of different fields, ranging from the most basic to the most advanced. As its name implies, these concise, comprehensive study guides summarize the essentials of the field covered. Essentials are helpful when preparing for exams, doing homework and will remain a lasting reference source for students, teachers, and professionals. Data Structures I includes scalar variables, arrays and records, elementary sorting, searching, linked lists, queues, and appendices of binary notation and subprogram parameter passi

  3. Data structures II essentials

    CERN Document Server

    Smolarski, Dennis C

    2012-01-01

    REA's Essentials provide quick and easy access to critical information in a variety of different fields, ranging from the most basic to the most advanced. As its name implies, these concise, comprehensive study guides summarize the essentials of the field covered. Essentials are helpful when preparing for exams, doing homework and will remain a lasting reference source for students, teachers, and professionals. Data Structures II includes sets, trees, advanced sorting, elementary graph theory, hashing, memory management and garbage collection, and appendices on recursion vs. iteration, alge

  4. Lightweight Materials and Structures (LMS): Inflatable Structures Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The Inflatable Structures (InSTAR) project goal is to demonstrate long term durability of inflatable habitat structures for potential utilization as either in-space...

  5. Bandwidth enhanced electromagnetic bandgap structure structured closed ground monopole antenna

    National Research Council Canada - National Science Library

    Modali S. S. S. SRINIVAS; Tottempudi Venkata RAMAKRISHNA; Boddapati T. P. MADHAV; Sathuluri Venkata RAMA RAO; Shaik ASHRAF ALI

    2016-01-01

    .... To overcome this problem a coplanar wave guide fed square patch monopole antenna with closed ground structure is proposed in this paper and electromagnetic band gap structure is added to the antenna...

  6. Structural ropes development for the E-ELT structure

    Science.gov (United States)

    Pajuelo, Eugenio; Gómez, José Ramón; Ronquillo, Bernardo; Brunetto, Enzo; Koch, Franz

    2008-07-01

    The European Extremely Large Telescope (E-ELT) structural rope system will be integrated in a mechanical structure, which can be made of mild steel and/or composite material. The following critical problems shall be solved by the rope system: matching of differential thermal expansion and tensioning forces calibration and control. The structural rope system consists of ropes, thermal compensation and tension control devices, and mechanical interfaces with the telescope structure. The objective of this study is to provide solutions to stabilize slender structural elements located in the upper part of the E-ELT Altitude Structure and increase global mode frequencies of the upper part of the E-ELT Altitude Structure. An appropriate rope system is developed to avoid local mode shapes and loss of stiffness that could lead to the failure of the whole structure under operational loads. The pre-tension level of the ropes needs to be controlled before operation to reach that objective.

  7. Structure and activation of rhodopsin

    Institute of Scientific and Technical Information of China (English)

    X Edward ZHOU; Karsten MELCHER; H Eric XU

    2012-01-01

    Rhodopsin is the first G-protein-coupled receptor (GPCR) with its three-dimensional structure solved by X-ray crystallography.The crystal structure of rhodopsin has revealed the molecular mechanism of photoreception and signal transduction in the visual system.Although several other GPCR crystal structures have been reported over the past few years,the rhodopsin structure remains an important model for understanding the structural and functional characteristics of other GPCRs.This review summarizes the structural features,the photoactivation,and the G protein signal transduction of rhodopsin.

  8. Structural Pain Compensating Flight Control

    Science.gov (United States)

    Miller, Chris J.

    2014-01-01

    The problem of control command and maneuver induced structural loads is an important aspect of any control system design. Designers must design the aircraft structure and the control architecture to achieve desired piloted control responses while limiting the imparted structural loads. The classical approach is to build the structure with high margins, restrict control surface commands to known good combinations, and train pilots to follow procedural maneuvering limitations. With recent advances in structural sensing and the continued desire to improve safety and vehicle fuel efficiency, it is both possible and desirable to develop control architectures that enable lighter vehicle weights while maintaining and improving protection against structural damage.

  9. The structures of binary compounds

    CERN Document Server

    Hafner, J; Jensen, WB; Majewski, JA; Mathis, K; Villars, P; Vogl, P; de Boer, FR

    1990-01-01

    - Up-to-date compilation of the experimental data on the structures of binary compounds by Villars and colleagues. - Coloured structure maps which order the compounds into their respective structural domains and present for the first time the local co-ordination polyhedra for the 150 most frequently occurring structure types, pedagogically very helpful and useful in the search for new materials with a required crystal structure. - Crystal co-ordination formulas: a flexible notation for the interpretation of solid-state structures by chemist Bill Jensen. - Recent important advances in unders

  10. Crystal structure of fiber structured pentacene thin films

    OpenAIRE

    2007-01-01

    This PhD thesis presents a technique based on the grazing incidence crystal truncation rod (GI-CTR) X-ray diffraction method used to solve the crystal structure of substrate induced fiber structured organic thin films. The crystal structures of pentacene thin films grown on technologically relevant gate dielectric substrates are reported. It is widely recognized, that the intrinsic charge transport properties in organic thin film transistors (OTFTs) depend strongly on the crystal structur...

  11. Frustrated polymer crystal structures

    Science.gov (United States)

    Lotz, B.; Strasbourg, 67083

    1997-03-01

    Several crystal structures or polymorphs of chiral or achiral polymers and biopolymers with three fold conformation of the helix have been found to conform to a common and -with one exception(Puterman, M. et al, J. Pol. Sci., Pol. Phys. Ed., 15, 805 (1977))- hitherto unsuspected packing scheme. The trigonal unit-cell contains three isochiral helices; the azimuthal setting of one helix differs significantly from that of the other two, leading to a so-called frustrated packing scheme, in which the environment of conformationally identical helices differs. Two variants of the frustrated scheme are analyzed. Similarities with frustrated two dimensional magnetic systems are underlined. Various examples of frustration in polymer crystallography are illustrated via the elucidation or reinterpretation of crystal phases or polymorphs of polyolefins, polyesters, cellulose derivatives and polypeptides. Structural manifestations (including AFM evidence) and morphological consequences of frustration are presented, which help diagnose the existence of this original packing of polymers.(Work done with L. Cartier, D. Dorset, S. Kopp, T. Okihara, M. Schumacher, W. Stocker.)

  12. Crystal structure of fipronil

    Directory of Open Access Journals (Sweden)

    Hyunjin Park

    2017-10-01

    Full Text Available The title compound, C12H4Cl2F6N4OS {systematic name: 5-amino-1-[2,6-dichloro-4-(trifluoromethylphenyl]-4-[(trifluoromethanesulfinyl]-1H-pyrazole-3-carbonitrile}, is a member of the phenylpyrazole group of acaricides, and one of the phenylpyrazole group of insecticides. The dihedral angle between the planes of the pyrazole and benzene rings is 89.03 (9°. The fluorine atoms of the trifluoromethyl substituent on the benzene ring are disordered over two sets of sites, with occupancy ratios 0.620 (15:0.380 (15. In the crystal, C—N...π interactions [N...ring centroid = 3.607 (4 Å] together with N—H...N and C—H...F hydrogen bonds form a looped chain structure along [10\\overline{1}]. Finally, N—H...O hydrogen bonds and C—Cl...π interactions [Cl...ring centroid = 3.5159 (16 Å] generate a three-dimensional structure. Additionally, there are a short intermolecular F... F contacts present.

  13. Lagrange structure and quantization

    Energy Technology Data Exchange (ETDEWEB)

    Kazinski, Peter O. [Department of Quantum Field Theory, Tomsk State University, Tomsk 634050 (Russian Federation); Lyakhovich, Simon L. [Department of Quantum Field Theory, Tomsk State University, Tomsk 634050 (Russian Federation); Sharapov, Alexey A. [Department of Quantum Field Theory, Tomsk State University, Tomsk 634050 (Russian Federation)

    2005-07-01

    A path-integral quantization method is proposed for dynamical systems whose classical equations of motion do not necessarily follow from the action principle. The key new notion behind this quantization scheme is the Lagrange structure which is more general than the lagrangian formalism in the same sense as Poisson geometry is more general than the symplectic one. The Lagrange structure is shown to admit a natural BRST description which is used to construct an AKSZ-type topological sigma-model. The dynamics of this sigma-model in d+1 dimensions, being localized on the boundary, are proved to be equivalent to the original theory in d dimensions. As the topological sigma-model has a well defined action, it is path-integral quantized in the usual way that results in quantization of the original (not necessarily lagrangian) theory. When the original equations of motion come from the action principle, the standard BV path-integral is explicitly deduced from the proposed quantization scheme. The general quantization scheme is exemplified by several models including the ones whose classical dynamics are not variational.

  14. Lagrange structure and quantization

    CERN Document Server

    Kazinski, P O; Sharapov, A A

    2005-01-01

    A path-integral quantization method is proposed for dynamical systems whose classical equations of motion do \\textit{not} necessarily follow from the action principle. The key new notion behind this quantization scheme is the Lagrange structure which is more general than the Lagrangian formalism in the same sense as Poisson geometry is more general than the symplectic one. The Lagrange structure is shown to admit a natural BRST description which is used to construct an AKSZ-type topological sigma-model. The dynamics of this sigma-model in $d+1$ dimensions, being localized on the boundary, are proved to be equivalent to the original theory in $d$ dimensions. As the topological sigma-model has a well defined action, it is path-integral quantized in the usual way that results in quantization of the original (not necessarily Lagrangian) theory. When the original equations of motion come from the action principle, the standard BV path-integral is explicitly deduced from the proposed quantization scheme. The genera...

  15. Silk structure and degradation.

    Science.gov (United States)

    Liu, Bin; Song, Yu-wei; Jin, Li; Wang, Zhi-jian; Pu, De-yong; Lin, Shao-qiang; Zhou, Chan; You, Hua-jian; Ma, Yan; Li, Jin-min; Yang, Li; Sung, K L Paul; Zhang, Yao-guang

    2015-07-01

    To investigate the structure of silk and its degradation properties, we have monitored the structure of silk using scanning electron microscopy and frozen sections. Raw silk and degummed raw silk were immersed in four types of degradation solutions for 156 d to observe their degradation properties. The subcutaneous implants in rats were removed after 7, 14, 56, 84, 129, and 145 d for frozen sectioning and subsequent staining with hematoxylin and eosin (H.E.), DAPI, Beta-actin and Collagen I immunofluorescence staining. The in vitro weight loss ratio of raw silk and degummed raw silk in water, PBS, DMEM and DMEM containing 10% FBS (F-DMEM) were, respectively, 14%/11%, 12.5%/12.9%, 11.1%/14.3%, 8.8%/11.6%. Silk began to degrade after 7 d subcutaneous implantation and after 145 d non-degraded silk was still observed. These findings suggest the immunogenicity of fibroin and sericin had no essential difference. In the process of in vitro degradation of silk, the role of the enzyme is not significant. The in vivo degradation of silk is related to phagocytotic activity and fibroblasts may be involved in this process to secrete collagen. This study also shows the developing process of cocoons and raw silk.

  16. Structural analysis of biodiversity.

    Science.gov (United States)

    Sirovich, Lawrence; Stoeckle, Mark Y; Zhang, Yu

    2010-02-24

    Large, recently-available genomic databases cover a wide range of life forms, suggesting opportunity for insights into genetic structure of biodiversity. In this study we refine our recently-described technique using indicator vectors to analyze and visualize nucleotide sequences. The indicator vector approach generates correlation matrices, dubbed Klee diagrams, which represent a novel way of assembling and viewing large genomic datasets. To explore its potential utility, here we apply the improved algorithm to a collection of almost 17,000 DNA barcode sequences covering 12 widely-separated animal taxa, demonstrating that indicator vectors for classification gave correct assignment in all 11,000 test cases. Indicator vector analysis revealed discontinuities corresponding to species- and higher-level taxonomic divisions, suggesting an efficient approach to classification of organisms from poorly-studied groups. As compared to standard distance metrics, indicator vectors preserve diagnostic character probabilities, enable automated classification of test sequences, and generate high-information density single-page displays. These results support application of indicator vectors for comparative analysis of large nucleotide data sets and raise prospect of gaining insight into broad-scale patterns in the genetic structure of biodiversity.

  17. Investigations of Nuclear Structure

    Energy Technology Data Exchange (ETDEWEB)

    Sarantites, Demetrios [Washington Univ., St. Louis, MO (United States); Reviol, W. [Washington Univ., St. Louis, MO (United States)

    2015-07-15

    The proposal addresses studies of nuclear structure at low-energies and development of instrumentation for that purpose. The structure studies deal with features of neutron-rich nuclei with unexplored shapes (football- or pear-shaped nuclei). The regions of interest are: neutron rich nuclei like 132-138Sn, or 48-54Ca, and the Zr, Mo, and Ru isotopes. The tools used can be grouped as follows: either Gammasphere or Gretina multi-gamma detector arrays and auxiliary detectors (Microball, Neutron Shell, and the newly completed Phoswich Wall).The neutron-rich nuclei are accessed by radioactive-beam binary reactions or by 252Cf spontaneous fission. The experiments with heavy radioactive beams aim at exciting the beam nuclei by pick-up or transfer a neutron or a proton from a light target like 13C, 9Be, 11B or 14N .For these binary-reaction studies the Phoswich Wall detector system is essential. It is based on four multi-anode photomultiplier tubes on which CsI and thin fast-timing plastic scintillators are attached. Their signals are digitized with a high density microchip system.

  18. Structural transition metal chemistry

    CERN Document Server

    Anderson, K M

    2002-01-01

    This thesis is divided up into five chapters as outlined below. Chapter 1 gives the background to the techniques used in this thesis including X-ray structure determination and ab initio methods. An overview of some recent studies using ab initio methods to study transition metal complexes is also given. Chapter 2 investigates structural trans influence in a number of transition metal and p-block complexes. The database and ab initio studies showed that the classical trans influence model based on Pt(II) chemistry does not always hold. For some systems (eg. d sup 1 sup 0 s sup 0 for Sb sup V and Sn sup I sup V) the cis influence is of similar magnitude to the trans influence. For other systems (d sup 0), the trans influence is not as powerful as usually assumed. Chapter 3 is an investigation into the bridging chloride unit. A database study was performed on three systems (M-CI-M', M-CI...H and M-CI...Li/Na/K). Reaction pathway analysis was carried out for the M-CI-M' case and showed that bond order is not con...

  19. Structural and Topology Optimization of Complex Civil Engineering Structures

    DEFF Research Database (Denmark)

    Hald, Frederik; Kirkegaard, Poul Henning; Andersen, Lars Vabbersgaard

    2013-01-01

    will be optimized using the commercial code Abaqus CAE. The structures are: a bucket foundation for an off-shore submarine structure for a wind turbine, and a pedestrian footbridge over a freeway. The topology optimization method used is the SIMP method, based on minimizing the structures' compliance. Complex load...

  20. Structural variations in pig genomes

    NARCIS (Netherlands)

    Paudel, Y.

    2015-01-01

    Abstract Paudel, Y. (2015). Structural variations in pig genomes. PhD thesis, Wageningen University, the Netherlands Structural variations are chromosomal rearrangements such as insertions-deletions (INDELs), duplications, inversions, translocations, and copy number variations (CNVs

  1. Vibration suppression using smart structures

    Science.gov (United States)

    Garcia, Ephrahim; Inman, Daniel J.; Dosch, Jeffrey

    1991-01-01

    The control of structures for vibration suppression is discussed in the context of using smart materials and structures. Here the use of smart structures refers to using embedded piezoelectric devices as both control actuators and sensors. Using embedded sensors and actuators allows great improvements in performance over traditional structures (both passive and active) for vibration suppression. The application of smart structures to three experimental flexible structures is presented. The first is a flexible beam, the second is a flexible beam undergoing slewing motion, the third is a ribbed antenna. A simple model of a piezoelectric actuator/sensor is presented. The equations of motion for each structure is presented. The control issues considered as those associated with multi-input, multi-output control, PID control and LQR control implementation. A modern control analysis illustrates the usefulness of smart structures for vibration suppression.

  2. Lifting locally homogeneous geometric structures

    CERN Document Server

    McKay, Benjamin

    2011-01-01

    We prove that under some purely algebraic conditions every locally homogeneous structure modelled on some homogeneous space is induced by a locally homogeneous structure modelled on a different homogeneous space.

  3. 40_ _230 - 233__Hassan _Structural

    African Journals Online (AJOL)

    User

    Bayero Journal of Pure and Applied Sciences, 9(2): 230 - 233. Received: ... electron microscopy (SEM) were used to observe the surface and internal structure of the quartz. The results ... structure of a material may be divided into four levels:.

  4. Dictionary of forest structural terminology

    CSIR Research Space (South Africa)

    Geldenhuys, CJ

    1988-01-01

    Full Text Available This report lists and defines attributes (both functional and structural) that have been used in other structural classifications of forest vegetation. Field techniques are summarized. The recommended use of each attribute and technique is presented...

  5. GPCR structures in drug design, emerging opportunities with new structures.

    Science.gov (United States)

    Tautermann, Christofer S

    2014-09-01

    In recent years, GPCR targets from diverse regions of phylogenetic space have been determined. This effort has culminated this year in the determination of representatives of all major classes of GPCRs (A, B, C, and F). Although much of the now well established knowledge on GPCR structures has been known for some years, the new high-resolution structures allow structural insight into the causes of ligand efficacy, biased signaling, and allosteric modulation. In this digest the structural basis for GPCR signaling in the light of the new structures is reviewed and the use of the new non-class A GPCRs for drug design is discussed.

  6. Structural Assembly Demonstration Experiment (SADE)

    Science.gov (United States)

    Akin, David L.; Mills, Raymond A.; Bowden, Mary L.

    1987-01-01

    The purpose of the Structural Assembly Demonstration Experiment (SADE) was to create a near-term Shuttle flight experiment focusing on the deployment and erection of structural truss elements. The activities of the MIT Space Systems Laboratory consist of three major areas: preparing and conducting neutral buoyancy simulation test series; producing a formal SADE Experiment plan; and studying the structural dynamics issues of the truss structure. Each of these areas is summarized.

  7. Porous Structure of Road Concrete

    OpenAIRE

    2016-01-01

    Having a great number of concrete structure classifications it is recommended to specify the following three principal types: microstructure – cement stone structure; mesostructure – structure of cement-sand mortar in concrete; macrostucture – two-component system that consists of mortar and coarse aggregate. Every mentioned-above structure has its own specific features which are related to the conditions of their formation. Thus, microstructure of cement stone can be characterized by such st...

  8. Structure Prediction of Membrane Proteins

    Institute of Scientific and Technical Information of China (English)

    Chunlong Zhou; Yao Zheng; Yan Zhou

    2004-01-01

    There is a large gap between the number of membrane protein (MP) sequences and that of their decoded 3D structures, especially high-resolution structures, due to difficulties in crystal preparation of MPs. However, detailed knowledge of the 3D structure is required for the fundamental understanding of the function of an MP and the interactions between the protein and its inhibitors or activators. In this paper, some computational approaches that have been used to predict MP structures are discussed and compared.

  9. Harmonic structures and intrinsic torsion

    DEFF Research Database (Denmark)

    Conti, Diego; Madsen, Thomas Bruun

    We discuss the construction of 8-manifolds with harmonic Sp(2)Sp(1)-structures. In particular, we find 10 new examples of nilmanifolds that admit a closed 4-form Omega whose stabiliser is Sp(2)Sp(1). Our constructions entail the notion of SO(4)-structures on 7-manifolds. We present a thorough inv...... investigation of the intrinsic torsion of such structures; in addition to the construction of harmonic structures, this analysis leads to explicit Lie group examples with invariant intrinsic torsion....

  10. Synchronously deployable truss structure

    Science.gov (United States)

    Bush, H. G. (Inventor); Mikulas, M., Jr. (Inventor); Wallsom, E. (Inventor)

    1986-01-01

    A collapsible-expandable truss structure, including first and second spaced surface truss layers having an attached core layer is described. The surface truss layers are composed of a plurality of linear struts arranged in multiple triangular configurations. Each linear strut is hinged at the center and hinge connected at each end to a nodular joint. A passive spring serves as the expansion force to move the folded struts from a stowed collapsed position to a deployed operative final truss configuration. A damper controls the rate of spring expansion for the synchronized deployment of the truss as the folded configuration is released for deployment by the restrain belts. The truss is synchronously extended under the control of motor driven spools.

  11. Functional structure of stomodeum

    Directory of Open Access Journals (Sweden)

    Chependyuk Т.А.

    2014-06-01

    Full Text Available Purpose: identification of the structure providing outflow of liquid from stomodeum in the process of formation. Material and Methods. 150 stomodea have been investigated for the ways of removal of liquid by the following methods: stage-by-stage freezing, contrasting and macerations. Result. One of the ways of removal of liquid from enamel of a being formed tooth is the crypt canal. Conclusion. Function of the channel of a crypt of developing teeth consists of removal of biological specific dental fluid from a surface of enamel of stomodeum in a mouth in the following options: on an oral surface of alveolar processes, near a periodontal fissure, or directly in a periodontium of a milk tooth — predecessor.

  12. Structure of Chinese algebras

    CERN Document Server

    Jaszunska, Joanna

    2010-01-01

    The structure of the algebra K[M] of the Chinese monoid M over a field K is studied. The minimal prime ideals are described. They are determined by certain homogeneous congruences on M and they are in a one to one correspondence with diagrams of certain special type. There are finitely many such ideals. It is also shown that the prime radical B(K[M]) of K[M] coincides with the Jacobson radical and the monoid M embeds into the algebra K[M]/B(K[M]). A new representation of M as a submonoid of the direct product of finitely many copies of the bicyclic monoid and finitely many copies of the infinite cyclic monoid is derived. Consequently, M satisfies a nontrivial identity.

  13. Introduction to stellar structure

    CERN Document Server

    Maciel, Walter J

    2016-01-01

    In the first part of this book, the author presents the basic properties of the stellar interior and describes them thoroughly, along with deriving the main stellar structure equations of temperature, density, pressure and luminosity, among others. The process and application of solving these equations is explained, as well as linking these results with actual observations.  The second part of the text describes what happens to a star over time, and how to determine this by solving the same equations at different points during a star’s lifetime. The fate of various stars is quite different depending on their masses, and this is described in the final parts of the book. This text can be used for an upper level undergraduate course or an introductory graduate course on stellar physics.

  14. Crystal structure of ruthenocenecarbonitrile

    Directory of Open Access Journals (Sweden)

    Frank Strehler

    2015-04-01

    Full Text Available The molecular structure of ruthenocenecarbonitrile, [Ru(η5-C5H4C[triple-bond]N(η5-C5H5], exhibits point group symmetry m, with the mirror plane bisecting the molecule through the C[triple-bond]N substituent. The RuII atom is slightly shifted from the η5-C5H4 centroid towards the C[triple-bond]N substituent. In the crystal, molecules are arranged in columns parallel to [100]. One-dimensional intermolecular π–π interactions [3.363 (3 Å] between the C[triple-bond]N carbon atom and one carbon of the cyclopentadienyl ring of the overlaying molecule are present.

  15. Structure-mediated nanoscopy

    DEFF Research Database (Denmark)

    Glückstad, Jesper; Bañas, Andrew Rafael; Aabo, Thomas

    2013-01-01

    -robotics requires the optimization of optical forces and torques that, in turn, requires optimization of the underlying light-matter interaction. The requirement of having tightly focused beams in optical tweezing systems exemplifies the need for optimal light-shaping in optical trapping, manipulation and sorting...... of optimal light-sculpting techniques [4] with the use of optimized shapes in micro-robotics structures [5]. Micro-fabrication processes such as two-photon photo-polymerization offer three-dimensional resolutions for creating custom-designed monolithic microstructures that can be equipped with optical...... trapping handles for convenient mechanical control using only optical forces [6]. These microstructures can be effectively handled with simultaneous top- and side-view on our BioPhotonics Workstation to carry out proof-of-principle experiments illustrating the six-degree-of-freedom optical actuation of two...

  16. Structural color in Myxomycetes.

    Science.gov (United States)

    Inchaussandague, Marina; Skigin, Diana; Carmaran, Cecilia; Rosenfeldt, Sonia

    2010-07-19

    In this paper we report evidence of structural color in Myxomycetes, a group of eukaryotic microorganisms with an uncertain taxonomic position. We investigated the Diachea leucopoda, which belongs to the Physarales order, Myxomycetes class, and found that its peridium -protective layer that encloses the mass of spores- is basically a corrugated layer of a transparent material, which produces a multicolored pointillistic effect, characteristic of this species. Scanning (SEM) and transmission (TEM) electron microscopy techniques have been employed to characterize the samples. A simple optical model of a planar slab is proposed to calculate the reflectance. The chromaticity coordinates are obtained, and the results confirm that the color observed is a result of an interference effect.

  17. Crystal structure of propaquizafop

    Directory of Open Access Journals (Sweden)

    Youngeun Jeon

    2014-12-01

    Full Text Available The title compound, C22H22ClN3O5 {systematic name: 2-(propan-2-ylideneaminooxyethyl (R-2-[4-(6-chloroquinoxalin-2-yloxyphenoxy]propionate}, is a herbicide. The asymmetric unit comprises two independent molecules in which the dihedral angles between the phenyl ring and the quinoxaline ring plane are 75.93 (7 and 82.77 (8°. The crystal structure features C—H...O, C—H...N, and C—H...Cl hydrogen bonds, as well as weak π–π interactions [ring-centroid separation = 3.782 (2 and 3.5952 (19 Å], resulting in a three-dimensional architecture.

  18. Thai Rhetorical Structure Analysis

    CERN Document Server

    Sinthupoun, Somnuk

    2010-01-01

    A rhetorical structure tree (RS tree) is a representation of discourse relations among elementary discourse units (EDUs). A RS tree is very useful to many text processing tasks employing relationships among EDUs such as text understanding, summarization, and question answering. Thai language with its unique linguistic characteristics requires a unique RS tree construction technique. This paper proposes an approach for Thai RS tree construction which consists of three major steps: EDU segmentation, Thai RS tree construction, and discourse relation (DR) identification. Two hidden markov models derived from grammatical rules are used to segment EDUs, a clustering technique with its similarity measure derived from Thai semantic rules is used to construct a Thai RS tree, and a decision tree whose features extracted from the rules is used to determine the DR between EDUs. The proposed technique is evaluated using three Thai corpora. The results show the Thai RS tree construction and the DR identification effectiven...

  19. Microfibrillar Structure of Silks

    Science.gov (United States)

    Putthanarat, Sirina; Eby, Ronald K.; Adams, W. W.; Liu, G. F.

    1998-03-01

    We have previously observed the dragline silk of Nephila clavipes and the silk of Bombyx mori exhibit a range of morphological feature including microfibers (S. Putthanarat; R.K. Eby; W.W. Adams; G.F. Liu J.M.S.-Pure Appl. Chem. 1996, A33(7), 899) and a layered structure. In successive layers the microfibers appeared to be oriented at different small angles to the fiber axis. Further work with the Atomic Force Microscope (AFM) on the silk of B. mori has confirmed these observations and shown other features. One of the latter is a series of raised "steps" spaced somewhat regularly along the fiber. Investigation of peeled three-molted B. mori and Antheraea yamamai (Japanese Tussah) and other silks has shown features very similar to all those in the silk of B. mori. AFM images, characterization, and analyses will be shown for all the silks and their features

  20. Everett and Structure

    CERN Document Server

    Wallace, D

    2001-01-01

    I address the problem of indefiniteness in quantum mechanics: the problem that the theory, without changes to its formalism, seems to predict that macroscopic quantities have no definite values. The Everett interpretation is often criticised along these lines and I shall argue that much of this criticism rests on a false dichotomy: that the macroworld must either be written directly into the formalism or be regarded as somehow illusory. By means of analogy with other areas of physics, I develop the view that the macroworld is instead to be understood in terms of certain structures and patterns which emerge from quantum theory (given appropriate dynamics, in particular decoherence). I extend this view to the observer, and in doing so make contact with functionalist theories of mind.