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Sample records for corante organico utilizacao

  1. Avaliação do efeito de corantes organicos sinteticos artificiais na função respiratoria mitocondrial

    OpenAIRE

    Maria Filomena Claret de Aguiar Valim

    1989-01-01

    Resumo: Neste estudo foi realizada a avaliação do efeito, na respiração mitocondrial, dos seguintes corantes orgânicos sintéticos artificiais, de uso permitido em alimentos no Brasil: Eritrosina, Ponceau 4R, Vermelho 40, Amarelo Crepúsculo, Amarelo de Tartrazina, Azul de Indigotina, Azul Brilhante e Amaranto, assim como dos corantes: Laranja GGN, Escarlate GN e Vermelho Sólido E. Utilizando-se mitocôndrias isoladas de fígado e de rim de ratos Wistar, verificou-se que estes corantes inibiam a ...

  2. CORANTES TÊXTEIS: UMA REVISÃO

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    Fabia Pinho Peixoto

    2013-11-01

    Full Text Available A indústria de corantes desenvolve um importante papel na economia do mundo, visto que estes são utilizados em várias atividades fabris. Os corantes têxteis causam especial impacto no meio ambiente principalmente por serem de difícil degradação. Vários processos tem sido estudados a fim de que se consiga realizar um tratamento realmente efetivo em remoção de corantes de efluentes têxteis, entre eles os processos biológicos estão recebendo uma particular atenção por sua eficiência.O tratamento microbiológico de efluentes, especialmente por espécies fúngicas tem ganhado espaço, por estes organismos serem bastante versáteis, tratarem uma grande variedade de tipos de corantes e apresentarem diferentes mecanismos de remoção de cor. Portanto os fungos apresentam-se bastante atrativos e demonstram ser os organismos mais adequados em relação a tratamento de efluentes têxteis.

  3. Corantes vitais em cromovitrectomia Vital dyes in chromovitrectomy

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    Eduardo Dib

    2009-12-01

    Full Text Available O objetivo do artigo é apresentar os dados atuais da aplicação de corantes vitais durante cirurgia vitreorretiniana, "cromovitrectomia", bem como uma revisão da literatura atual sobre o assunto no tocante às técnicas de aplicação, indicações e complicações em cromovitrectomia. Um grande número de publicações tem abordado o perfil tóxico da indocianina verde na cromovitrectomia. Dados experimentais mostram uma toxicidade dose-dependente da mesma em várias populações de células retinianas. Novas gerações de corantes incluem: azul tripan, azul patente, acetato de triancinolona, infracianina verde, fluoresceína sódica, azul de bromofenol, acetato de fluorometolona e azul brilhante. Novos instrumentos podem permitir um corar seletivo de estruturas durante a vitrectomia. Este artigo mostra que o campo da cromovitrectomia está em plena expansão de pesquisas. Os corantes de primeira linha são a indocianina verde, infracianina verde e o azul brilhante. Azul patente, azul de bromofenol e azul tripan surgem como novos adjuvantes para melhor observação da membrana epirretiniana. Demais corantes que surgiram merecem maior investigação.The aim of this article is to present the current data with regard to the application of vital dyes during vitreoretinal surgery, "chromovitrectomy", as well as to overview the current literature regarding the properties of dyes, techniques of application, indications and complications in chromovitrectomy. A large body of published research has recently addressed the toxicity profile of indocyanine green for chromovitrectomy. Experimental data demonstrate dose-dependent toxicity of indocyanine green to various retinal cells. Newer generation vital dyes for chromovitrectomy include trypan blue, patent blue, triamcinolone acetonide, infracyanine green, sodium fluorescein, bromophenol blue, fluorometholone acetate and brilliant blue. Novel instruments may enable a selective painting of preretinal

  4. Desenvolvimento de corantes naturais para uso em plástico

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    Sérgio Roberto Knorr Velho

    2016-01-01

    O trabalho buscou identificar se o intemperismo acelerado Xênon, utilizando a norma ASTM D4452-12, em corantes naturais encapsulados em matriz de sílica pelo processo sol gel com o uso de alcóxidos, conforme descrito pela patente INPI BR 10 2013 0219835, e injetadas em matriz de policloreto de polivinila (PVC) preservam as características de cor original dos corantes. Utilizou-se comparação dos mesmos corantes naturais – carmim, curcuma, índigo e urucum – sem encapsulamento e com encapsulamen...

  5. Extração e estabilidade do corante azul de jenipapo (Genipa americana L.)

    OpenAIRE

    Renhe, Isis Rodrigues Toledo

    2008-01-01

    O presente trabalho teve por objetivo a avaliação da potencialidade do fruto do jenipapo como fonte de corante azul natural, objetivando torná-lo tecnicamente viável, bem como identificar o solvente adequado para a extração dos pigmentos do jenipapo, avaliar o efeito do pH e da temperatura na produção do corante, e estudar a estabilidade dos pigmentos obtidos por diferentes solventes. Para a obtenção do corante o experimento foi conduzido para três níveis de solvente (água, solução aquosa de ...

  6. Energia solar no tratamento de corante têxtil

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    Viviane Farias Silva

    2014-10-01

    Full Text Available As indústrias utilizam a água em todo o seu processo, desperdiçando enormes volumes de água gerando efluentes com altos índices de produtos químicos, precisando de tratamento para ser reutilizado ou lançado no meio ambiente. Nesse contexto, o presente trabalho foi realizado no Laboratório de Engenharia Ambiental e de Qualidade na Universidade Federal de Pernambuco objetivando-se a degradação de corante utilizados nas indústrias têxtis através do uso da energia solar como alternativa de tratamento de efluente. Nesta pesquisa os testes fotocatalíticos foram realizados com o catalisador em pó (TiO2 - P25, contendo o corante têxtil Remazol Amarelo Ouro RNL (RGY ou sem catalisador nos testes de fotólise. Foram testados dois tipos de radiação, a artificial e a energia solar (natural. Para avaliar a descoloração e a degradação das amostras, a Espectroscopia UV-visível foi a principal técnica analítica empregada como também realizadas análises de Carbono Orgânico Total (COT e Demanda Química de Oxigênio (DQO. Nas 6 (seis analises realizadas obteve-se um elevado índice de remoção da cor do corante, superior a 97%, com alta eficiência do processo com uma significativa redução da COT e da DQO. Os métodos utilizados foram eficientes na descoloração do RGY, como também na sua degradação, tornando-se uma técnica inovadora com o uso da energia solar para o tratamento de efluentes têxteis.Palavras-chave: efluente industrial, alternativa sustentável, degradação do remazol amarelo ouro, descoloração de efluente

  7. UTILIZAÇÃO DO CORANTE DA BETERRABA COMO ADITIVO ALIMENTAR

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    NíVEA CONFORTI-FROES

    2009-07-01

    Full Text Available

    RESUMO: Dentre os produtos do metabolismo secundário vegetal, os pigmentos ou corantes têm despertado especial interesse, pela sua importância na indústria de alimentos. No caso de oferecerem menos riscos à saúde humana, poderão vir a substituir os corantes sintéticos, principalmente os que são questionados quanto a possíveis reações alérgicas. Desse modo, testaram-se os corantes da beterraba e da batata-doce roxa em células meristemáticas da raízes de Allium cepa, a fim de verificar possíveis alterações no processo de divisão celular. Os resultados obtidos demonstraram citototoxidade induzida pelo corante de beterraba que foi, em seguida, testado em células da medula óssea de Rattus norvergicus. Em todos os parâmetros analisados não se detectaram alterações induzidas por esse corante nos animais tratados quando esses foram comparados aos seus respectivos controles. Em vista dos resultados obtidos, parece viável o uso do corante da beterraba como aditivo alimentar, apesar de não terem sido consideradas as vantagens técnicas e econômicas relativas ao seu emprego. PALAVRAS-CHAVE: Corantes vegetais; antocianinas; betacianinas; genotoxidade.

  8. Bioensayo microbiano para estimar los nutrimentos disponibles en los abonos organicos: calibracion en el campo

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    Eduardo Salas

    2001-01-01

    Full Text Available Se demostr6 recientemente que el aumento nude la biomasa microbiana en una mezcla de sue- calo: abono organico (9:1, suplementada con gluco- sa como fuente de carbono, fue proporcional al crecimiento de una planta indicadora (sorgo cre- cida en el mismo sustrato. En la presente investi- gaci6n se determina si este bioensayo es de utili- dad como gufa en la fertilizaci6n de los cultivos con abonos organicos, mediante la siembra en el campo de chile dulce (Capsicum annuum L. y to- mate (Lycopersicum esculentum L. como plantas indicadoras. Los tratamientos consistieron de sue- 10 solo 0 en mezcla con 10% de abonos organicos amende contenido de nutrimentos contrastante a saber: pollinaza (CM, compost (C, bocashi (B, vermi- macompost (V y broza de cafe (Br. En el bioensa- vermicomyo microbiano se utiliz6 un disefio de bloques randocompletos al azar con 6 repeticiones, la biomasa microbiana (BM se midi6 2 dfas despues de in- cubar con glucosa. En los ensayos de campo las plantas indicadoras se sembraron en un disefio de bloques completos al azar con 4 repeticiones. En chile dulce se midi6 el peso seco (600 C de la comparte aerea de la planta (PSC y el peso fresco de frutos verdes (PFF a los 97 dfas despues de la Microsiembra. El peso seco de la parte aerea de las amendplantas de tomate (PST fue medido a los 32 dfas. Los abonos organicos CM, C y B indujeron la mayor BM y tambien el mayor PSC, PFF Y PST, indicaci6n de que fueron los de mayor y mas in- mediato suministro de nutrimentos, contrario al y Br que mostraron los valores mas bajos para es- tas variables (P<0.05. Estos 2 abonos, respecto vatratamiento de CM presentaron 3 y 5 veces menos BM y 2 Y 4 veces menos biomasa aerea, respecti- vamente (P<0.05. Las correlaciones altas obteni- codas entre la BM y el PSC (r=0.87 y entre la BM y el PST (r= 0.93, permiten concluir que bioensayo microbiano es un metoda promisorio para pronosticar el suministro de nutrimentos orlos abonos organicos a los cultivos

  9. Obtaining carbon nanotubes/ZnO for use in the photocatalytic organic pollutants; Obtencao de nanotubos de carbono/ZnO para utilizacao na fotocatalise de poluentes organicos

    Energy Technology Data Exchange (ETDEWEB)

    Dalt, S. da; Pulcinelli, N.O.; Bergmann, C.P. [Universidade Federal do Rio Grande do Sul (UFRS), Porto Alegre, RS (Brazil). Laboratorio de Materiais Ceramicos

    2016-07-01

    This study aims to obtain nanocomposites of carbon nanotubes (CNTs) with nanostructured zinc oxide (ZnO), and characterize the samples as its structure and photocatalytic activity, for their application in the degradation of organic pollutants, in the case organic dye methyl orange. The nanocomposites were obtained from commercial NTC (Baytubes®), commercial ZnO, produced by Merck and ZnO obtained from the synthesis by combustion. The NTC-ZnO nanocomposites were prepared in solution from the physical mixture of materials, and subsequently analyzed structurally and investigated for their photocatalytic activity, employing them as catalysts in degradation of the dye in aqueous solution under ultraviolet radiation. Samples were analyzed by X-ray diffraction and specific surface area (BET). The photocatalytic performance of nanocomposites can be correlated to the phase found and the surface area measured. (author)

  10. Producción de biogás a partir de residuos organicos en biodigestores de bajo coste

    OpenAIRE

    Ferrer Martí, Ivet; Uggetti, Enrica; Poggio, Davide; Velo García, Enrique

    2015-01-01

    PRODUCCIÓN DE BIOGÁS A PARTIR DE RESIDUOS ORGANICOS EN BIODIGESTORES DE BAJO COSTE Ivet Ferrer*, Enrica Uggetti**, Davide Poggio***, Enric Velo**** Grup de Recerca en Cooperació i Desenvolupament Humà C. Jordi Girona, 31 08034 - Barcelona, Spain Phone: +34 93 401 64 63 Pàgina web: http://www.upc.edu/grecdh *, **, ***, **** Palabras clave: Digestión anaerobia; Biodigestor; Biogás; Energía; Fertilizante. RESUMEN ...

  11. Corantes alimentares presentes em alimentos ultraprocessados consumidos por universitários / Food dyes present in ultra-processed foods consumed by university students

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    Dayana Nolasco Gama

    2018-04-01

    Full Text Available Objetivo: Descrever os corantes alimentares presentes nos alimentos ultraprocessados consumidos por 273 graduandos de uma universidade pública do Rio de Janeiro. Métodos: Foi caracterizado o perfil sociodemográfico e de saúde a partir de questionário semiestruturado. Consumo de alimentos ultraprocessados foi obtido através do Questionário de Frequência Alimentar (gelatinas, biscoitos recheados, balas e chicletes, refrigerantes, preparados sólidos para refresco, sucos industrializados, temperos prontos e macarrão instantâneo e os corantes foram identificados nos rótulos dos produtos. Resultados: O consumo de produtos contendo corantes como gelatinas, balas e chicletes, refrigerantes e sucos industrializados foi acima de 80%. Balas e chicletes e temperos prontos tiveram consumo quase diário, sendo 56,9% e 54,1% respectivamente. Conclusão: Identificaram-se quatorze corantes nos rótulos dos produtos industrializados ultraprocessados.  Destacaram-se os corantes artificiais caramelos III e IV, bordeuax S, amarelo crepúsculo e tartrazina, e naturais urucum e carmim. Descritores: Corantes de alimentos, hábitos alimentares, risco.

  12. Estabilidade dos corantes Tartrazina e Amarelo Crepusculo em refrigerantes = The stability of synthetic food dyes tartrazine and yellow sunset

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    Indianara Ostroski

    2005-07-01

    Full Text Available Estudou-se a estabilidade dos corantes alimentícios sintéticos tartrazina e amarelo crepúsculo em relação à intensidade de radiação na região do ultravioleta e do visível, bem como a influência do pH e de outros aditivos comumente presentes em produtos alimentícios. Foram realizadas leituras periódicas do espectro de absorção noscomprimentos de onda entre 700 e 190 nm para verificar alterações químicas nos corantes estudados. No caso de refrigerantes em embalagem de PET verificou-se a relação entre luz incidente e luz transmitida pela embalagem, estabelecendo a sua função como filtro adeterminadas radiações luminosas. Os dados obtidos com os corantes nas amostras de refrigerantes foram comparados com os dados obtidos com os corantes em solução. Constatou-se que em pH mais ácido há um aumento na velocidade de degradação dos corantes, do mesmo modo que na presença de citratos ou ascorbatos. A presença de benzoatos retarda o processo de degradação dos corantes.The stability of synthetic food dyes tartrazine and yellow sunset was studied in relation to the intensity of radiation in the ultraviolet and visible spectra, as well as the influence of the pH and others additives normally presents in some products. Periodic scanning of theabsorption spectrum was accomplished in the wavelengths between 700 nm and 190 nm to verify alterations in this dyes. In the case of soft drinks in PET packing, the relation was verified between incident light and light transmitted by the packing, establishing its function as filter to radiation. The data obtained with the dyes in the samples of soft drinks were compared with standard dyes solutions. In acid media, citrate and ascorbate presence, a major degradation process occurs. In benzoate presence, the dye degradation is lower.

  13. Determinação de metais em corantes alimentícios artificiais - DOI: 10.4025/actascitechnol.v30i1.3218

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    Cleber Antonio Lindino

    2008-05-01

    Full Text Available Em razão da grande utilização de corantes alimentícios artificiais nos mais diferentes produtos, o controle de qualidade se torna imprescindível. Um dos problemas que pode estar presente, nestes corantes, é o teor elevado de metais tóxicos em sua composição, provenientes da contaminação da síntese da matéria-prima ou do processo de manufatura. Neste trabalho, os corantes em solução foram caracterizados por espectrofotometria na região do visível e ultravioleta. Posteriormente, foram determinados os metais Pb, Cd, Al, Cr e As, em soluções aquo-alcóolicas de corantes artificiais, vendidas comercialmente. Foram encontrados todos metais pesados tóxicos estudados nas amostras de dois diferentes lotes de corantes, com alto coeficiente de variação, com o As excedendo os limites legais em um dos lotes.

  14. Determinação de metais em corantes alimentícios artificiais = Determination of metals in food dyes products

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    Cleber Antonio Lindino

    2008-01-01

    Full Text Available Em razão da grande utilização de corantes alimentícios artificiais nos mais diferentes produtos, o controle de qualidade se torna imprescindível. Um dos problemas que pode estar presente, nestes corantes, é o teor elevado de metais tóxicos em sua composição, provenientes da contaminação da síntese da matéria-prima ou do processo de manufatura. Neste trabalho, os corantes em solução foram caracterizados por espectrofotometria na região do visível e ultravioleta. Posteriormente, foram determinados os metais Pb, Cd, Al, Cr e As, em soluções aquo-alcóolicas de corantes artificiais, vendidas comercialmente. Foram encontrados todos metais pesados tóxicos estudados nas amostras de dois diferentes lotes de corantes, com alto coeficiente de variação, com o As excedendo os limites legais em um dos lotes.Synthetic food dyes is the most additives using in food products in high concentration more time, in that the quality control is indispensable. The concentration of toxic metals in most of productsexceeded the limit of legislation, due to contamination by raw material or manufacturing process. This paper was determinate Pb, Cd, Al, Cr and As in solutions of synthetic food dyes. All of these metals were determinated with high variation coefficient.

  15. Volatile organic compound (VOC) determination in working atmospheres; Determinacion de compuestos organicos volatiles (VOC) en ambiente laboral

    Energy Technology Data Exchange (ETDEWEB)

    Blass A, Georgina; Panama T, Luz A; Corrales C, Deyanira [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

    2003-07-01

    The present work describes, in a synthesized way, the implementation and application of procedures based on the normativity related to the subject of the volatile organic compounds (Volatile Organic Compounds VOC), that allow to sample, quantify and evaluate the present contamination in the working atmosphere of a refinery due to the fugitive emissions of VOC and other substances. In accordance with the corresponding normativity, more than 189 organic compounds denominated dangerous air polluting agents (Hazardous Air Pollutants, HAP) can be found in a working atmosphere, but they are the 11 main HAP that can be found in a refinery. In the present article the work made for the sampling and quantification of 5 of the 11 dangerous polluting agents of the air: benzene, toluene, xylene, iso-octane and naphthalene. [Spanish] El presente trabajo describe, de manera sintetizada, la implementacion y aplicacion de procedimientos basados en la normatividad relacionada al tema de los compuestos organicos volatiles (Volatil Organic Compounds, VOC), que permiten muestrear, cuantificar y evaluar la contaminacion presente en el ambiente laboral de una refineria debido a las emisiones fugitivas de VOC y otras sustancias. De acuerdo con la normatividad correspondiente, mas de 189 compuestos organicos denominados contaminantes peligrosos del aire (Hazardous Air Pollutants, HAP), pueden ser encontrados en un ambiente laboral, pero son 11 los principales HAP que pueden ser hallados en una refineria. En el presente articulo se informa el trabajo realizado para el muestreo y cuantificacion de 5 de los 11 contaminantes peligrosos del aire: benceno, tolueno, xileno, iso-octano y naftaleno.

  16. Estudo do uso de corantes artificiais em alimentos e estimativa de ingestão de tartrazina pela população brasileira

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    Patrícia da Silva Rodrigues

    2015-01-01

    A atração dos seres humanos pelas cores é um fenômeno instintivo. Cores agradáveis em alimentos geram no consumidor a sensação de um produto com características sensoriais mais prazerosas e fornecem a sensação de maior qualidade global. Os objetivos deste trabalho foram verificar quais os alimentos comercializados por uma das maiores redes de supermercados do país que continham corantes na sua formulação, selecionar aqueles que continham o corante artificial tartrazina, estimar a Ingestão Diá...

  17. Dye detoxification by Lentinula edodes INCQS 40220 | Detoxificação de corante por Lentinula edodes INCQS 40220

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    Ludmila R. Bergsten-Torralba

    2016-02-01

    Full Text Available Lentinula edodes belongs to the group of fungi known as ligninolytic fungi, due to its ability to degrade the aromatic structure of the lignin. Textile dyes also have aromatic structure, and after microbial degradation, some of them can be transformed into toxic compounds, when compared to the original structure, representing risk to environment and human health. Therefore, the potential of the fungus L. edodes INCQS 40220 to decolorize and to detoxify reactive red 198 (azo dye, reactive blue 214 (azo dye and reactive blue 21 (cooper phthalocyanine dye in a mixture (MXD, was evaluated. After 14 days of incubation, total decolorization in liquid media was obtained. The fungal treatment of MXD did not present toxic effects towards blood human cells. The genotoxicity of MXD, assessed by Comet assay, was efficiently reduced to 61% and in the Ames test presented negative response for mutagenicity for Salmonella enterica serovar Typhimurium TA97, TA98, TA100 and TA102 strains. The results indicated L. edodes INCQS 40220 efficiency on decolorization and genotoxicity reduction of a mixture of different dyes. Therefore, based on these results, obtained under laboratory conditions, L. edodes INCQS 40220 has potential for textile effluent treatment. ============================================= Lentinula edodes pertence ao grupo de fungos conhecidos como fungos ligninolíticos, devido a sua habilidade de degradar estruturas aromáticas da lignina. Corantes têxteis também possuem estruturas aromáticas e, após a degradação microbiana, alguns destes corantes podem ser transformados em compostos tóxicos quando comparados à estrutura original, representando risco à saúde ambiental e humana. Portanto, o potencial do fungo L. edodes INCQS 40220 para descolorir e detoxificar a mistura de vermelho reativo 198 (corante azo, azul reativo 214 (corante azo e azul reativo 21 (corante ftalocianina de cobre foi avaliada (MXD. Após 14 dias de incubação, foi

  18. Extração de corantes de milho (Zea mays L. Extraction of corn colorants (Zea mays L.

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    Felix Martin Cabajal Gamarra

    2009-03-01

    Full Text Available Os corantes naturais foram amplamente utilizados de forma artesanal até antes do surgimento dos corantes sintéticos. O estudo e uso dos corantes naturais voltaram a ter importância nestes últimos anos devido aos questionamentos dos organismos internacionais da saúde e dos consumidores pelo uso indiscriminado dos corantes sintéticos, ligados ao desenvolvimento de doenças degenerativas e ao impacto ambiental. O corante extraído do milho roxo (Zea mays L. tem sido utilizado ao longo da história pela civilização Inca na preparação de alimentos e no tingimento de fibras têxteis. Neste trabalho, os pigmentos do grupo das antocianinas foram extraídos das variedades de milho roxo e do milho vermelho (Z. mays L. e depois foram caracterizados. Três métodos de extração foram utilizados: imersão, lixiviação com algumas modificações e extração supercrítica (ESC. O melhor método para extração foi o da lixiviação que alcançou 88% (m/m de rendimento, em função da massa do corante extraído e da matéria-prima. Também utilizando a lixiviação modificada, foi possível concentrar em 3% os compostos acilados, assim como recuperar 85% dos solventes utilizados. Um indicador de pH foi obtido pela fixação das antocianinas num papel de filtro, com base na estabilidade das antocianinas, ferramenta que pode ser utilizada em laboratórios de ensino de química.Natural colorants were craftly made and widely used before the discovery of the synthetic colorants. The study and the use of natural colorants have become important again in the last few years due to questions raised by the international health organizations and consumers related to the indiscriminate use of synthetic colorants which were linked to the development of degenerative illnesses and environmental impact. The colorant extracted from purple corn (Zea Mays L. was used by the Inca civilization to prepare food and to dye textile fibers. In this work, pigments from the

  19. Metodologia para determinação de corantes artificiais em alimentos por cromatografia liquida de alta eficiencia

    OpenAIRE

    Marcelo Alexandre Prado

    1998-01-01

    Resumo: O controle dos níveis de corantes artificiais utilizados em alimentos não é um procedimento rotineiro, especialmente, peia falta de metodologia adequada capaz de responder à demanda do número de análises e a determinações quantitativas nos mais variados tipos de alimentos, além de se tornar viável para implantação nos laboratórios de controle de nosso pais. Visando superar esse problema, foi desenvolvida e avaliada unia metodologia para a determinação qualitativa e quantitativa dos oi...

  20. Using the direct method in organophilization of clay chocolate 'A' with organic surfactant; Utilizacao do metodo direto na organofilizacao da argila chocolate 'A' com surfactante organico

    Energy Technology Data Exchange (ETDEWEB)

    Patricio, A.C.L.; Sousa, A.B.; Silva, M.M. da; Rodrigues, M.G.F.; Laborde, H.M., E-mail: cadigena@hotmail.com [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Centro de Ciencias e Tecnologia. Unidade Academica de Engenharia Quimica

    2012-07-01

    During the development of this work, we studied the preparation of organoclays through direct method, starting from the natural clay Chocolate 'A' using the quaternary ammonium salt, chloride, alkyl dimethyl benzyl ammonium (Dodigen). The samples were characterized by X-Ray Diffraction (XRD), Infrared Spectroscopy in the Region (IV), Gravimetric and Differential Thermal Analysis (DTA / TGA) and swelling of Foster using solvents, gasoline, kerosene and diesel. Was observed by the results XRD, IR and DTA / TG effective intercalation of quaternary ammonium salts of the inter lamellar spaces of the clay, and by Foster swelling test samples treated with the quaternary ammonium salt Dodigen showed affinity for all the solvents tested. (author)

  1. DETERMINAÇÃO DE CORANTES SINTÉTICOS EM BEBIDAS ISOTÔNICAS EMPREGANDO EXTRAÇÃO EM FASE SÓLIDA DISPERSIVA E HPLC-UV/Vis

    OpenAIRE

    Luana Floriano

    2016-01-01

    As bebidas isotônicas são especialmente formuladas para pessoas que praticam atividade física, sendo compostas principalmente por carboidratos, eletrólitos e vitaminas. Os corantes sintéticos são aditivos alimentares comumente utilizados em bebidas isotônicas para aprimorar suas características de consumo e aparência. Além do menor custo de produção em relação aos corantes de origem natural, os corantes sintéticos apresentam diversas vantagens, tais como alta estabilidade à luz, oxigênio e pH...

  2. Degradação de Corantes Indigoides com Reagente de Fenton para tratamento de efluentes na Industria Têxtil

    OpenAIRE

    Meira, Luís

    2014-01-01

    A indústria têxtil gera grandes quantidades de efluentes, que não sendo tratados podem contaminar os cursos de água. É uma fonte de poluição visível e com produtos tóxicos que perturbam os ecossistemas. Torna-se por isso necessário encontrar tratamentos de efluentes têxteis simples e economicamente viáveis para não acrescentar maior custo ao produto. Pretendeu-se encontrar as condições ideais para a degradação de uma solução de corante Índigo Carmim com diferentes solventes,...

  3. Extração do corante reactive blue 19 utilizando tensoativo não iônico

    OpenAIRE

    Melo, Ricardo Paulo Fonseca

    2012-01-01

    A geração de efluente proveniente do processo de acabamento na industria têxtil é um grave problema ambiental e se transformou em objeto de estudo em diversos trabalhos científicos. A contaminação por corantes e a presença de substâncias que são tóxicas ao meio ambiente caracterizam este efluente de difícil tratamento. Vários processos já foram avaliados para remover e até degradar tais poluentes são exemplos: a coagulação-floculação, tratamento biológico e processos oxidativos...

  4. Avaliação da ingestão potencial de corantes artificiais por crianças em idade escolar

    OpenAIRE

    Monica Sztajn

    1988-01-01

    Resumo: A ingestão potencial semanal de corantes artificiais por crianças na faixa etária de 3 a 14 anos, residentes no Distrito de Barão Geraldo, Campinas, S. P., foi estimada com base em dados de consumo médio de alimentos e em determinações analíticas dos corantes presentes nos produtos consumidos. Foi feito um levantamento de todas as crianças, dentro da faixa etária de interesse, que freqüentavam as Escolas de maternal, 1° e 2° graus no ano letivo de 1986, procedendo-se em seguida á amos...

  5. Utilização de resíduos de materiais cerâmicos na adsorção de corante azul de metileno

    Directory of Open Access Journals (Sweden)

    L. Dominguini

    2014-06-01

    Full Text Available Este trabalho estuda a viabilidade de utilização de resíduos de materiais cerâmicos como agentes de adsorção de corantes utilizados em indústrias têxteis. Resíduos de materiais cerâmicos, oriundos de quebras de tijolos, azulejos e pisos foram selecionados, triturados e moídos a uma granulometria adequada, o que possibilitou o estudo da influência do tipo de material cerâmico (resíduo e da sua granulometria sobre a adsorção do corante azul de metileno. Os resíduos cerâmicos foram separados em três diferentes granulometrias, fina (0,15 mm < Dfino< 0,30 mm, média (0,30 mm < Dmédio< 1,18 mm e grossa (1,18 mm corante azul de metileno presente na amostra ensaiada. No entanto, os resultados também mostram que a absorção de água do material cerâmico pode não ser somente o fator que influencia na adsorção do corante.

  6. Determinacion del N y P en abonos organicos mediante la tecnica del elemento faltante y un bioensayo microbiano

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    Eduardo Salas

    2001-01-01

    Full Text Available Mediante la tecnica del elemento faltante en ferinvernadero y el uso de un bioensayo microbiano se determin6 la disponibilidad de N y P en 6 sus- greenhoutratos: suelo s6lo 0 en mezcla 9: 1 con diversos abo- nos organicos, a saber: pollinaza (CM, compost (C, bocashi (B, vermicompost (V 0 broza de ca- determife (Br. En ambos bioensayos y para cada sustrato se realiz6 un experimento factorial 2x2 (fertiliza- ci6n con P y N; las combinaciones resultantes fue- ron: +P, +N, +P+N y -P-N (testigo. En el bioensa- yo microbiano se utiliz6 un diseno de bloques al azar con 6 repeticiones y se midi6 el crecimiento microde la biomasa microbiana nativa (BM 2 dias des- pues de aplicar el tratamiento e incubar con gluco- sa. En la prueba de invernadero se utiliz6 un dise- no completamente al azar con 4 repeticiones, se utiliz6 sorgo (Sorghum vulgare como planta indi- cadora. Se midi6 el peso seco de la parte aerea de lasplantas a los 34 dias de la siembra (PS y el con- tenido foliar de nutrimentos. Ambos bioensayos in- sordicaron respuesta del suelo a la aplicaci6n de P y N. La mezcla del suelo con un 10% de CM, CoB mostraron los valores mas altos de BM y PS. La mezcla suelo:CM no respondi6 a ningun tratamien- to qufmico, mientras que en mezcla con el C 0 el B respondi6 a la aplicaci6n de N pero no al P. Con el Vola Br se obtuvo las menores respuestas de las variables y hubo respuesta ala adici6n de P y N. La tecnica del elemento faltante de invernadero

  7. Corantes alimentares presentes em alimentos ultraprocessados consumidos por universitários / Food dyes present in ultra-processed foods consumed by university students

    OpenAIRE

    Dayana Nolasco Gama; Maria Lúcia Teixeira Polônio

    2018-01-01

    Objetivo: Descrever os corantes alimentares presentes nos alimentos ultraprocessados consumidos por 273 graduandos de uma universidade pública do Rio de Janeiro. Métodos: Foi caracterizado o perfil sociodemográfico e de saúde a partir de questionário semiestruturado. Consumo de alimentos ultraprocessados foi obtido através do Questionário de Frequência Alimentar (gelatinas, biscoitos recheados, balas e chicletes, refrigerantes, preparados sólidos para refresco, sucos industrializados, tempero...

  8. Ativação de adsorventes carbonosos para a remoção de corantes de efluentes têxteis

    OpenAIRE

    Sonai, Gabriela Gava

    2012-01-01

    Dissertação (mestrado) - Universidade Federal de Santa Catarina, Centro Tecnológico. Programa de Pós-Graduação em Engenharia Química A adsorção é um processo que vem ganhando importância na indústria têxtil para a remoção de corantes de efluentes industriais, sendo geralmente utilizado o carvão ativado. Devido ao alto custo deste material, muitos estudos visam o desenvolvimento de adsorventes alternativos e de baixo custo. Neste trabalho foram investigadas as diferentes técnicas de prepara...

  9. Degradação redutiva de azo-corantes utilizando-se ferro metálico Reductive degradation of azo-dyes by metallic iron

    Directory of Open Access Journals (Sweden)

    Cláudio Lima de Souza

    2006-03-01

    Full Text Available Corantes azo são extensivamente utilizados em processos de tingimento de fibras têxteis, sendo caracterizados por elevada resistência frente a processos aeróbios de biodegradação e, por conseqüência, persistência nos processos convencionais de tratamento de resíduos. Neste trabalho reporta-se a degradação redutiva de corantes azo, utilizando-se ferro metálico. Em condições experimentais otimizadas (pH 7 e 10 g de lã de aço comercial a completa descoloração do corante modelo (preto reativo 5 foi conseguida em um sistema contínuo, operando com tempos de retenção de 6 min. Nestas condições, o ferro solubilizado alcança concentrações compatíveis com os limites impostos pela atual legislação brasileira (12 mg L-1. Trata-se de um resultado bastante promissor, principalmente levando-se em consideração o caráter recalcitrante dos azo corantes e a simplicidade do sistema proposto.Azo dyes are extensively used in textile dying processes and are characterized by extreme resistance to biodegradation and consequently persistence during conventional wastewater treatment processes. In this work the reductive degradation of azo dyes was studied using zero-valent iron. At optimized experimental conditions (pH 7 and 10 g of commercial iron wool complete decolorization of the model dye (reactive black 5 was afforded in a continuous system operating with hydraulic retention time of 6 min. At these conditions the released total soluble iron reaches a concentration compatible with the limits imposed by the current Brazilian legislation (12 mg L-1. That is a very promising result, mainly taking into account the high recalcitrant character of azo dyes and the simplicity of the proposed system.

  10. Uso de Materiais Alternativos em Processos de Adsorção de Corante Azul de Metileno

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    E. L. do Rego

    2014-11-01

    Full Text Available Este trabalho teve como objetivo empregar materiais alternativos, puros e/ou modificados com 5 ou 10% (m/m de  pentóxido de nióbio (Nb2O5, em processos de remoção de azul de metileno (AM. Entre os materiais alternativos foram utilizadas argila sanitária, argila de resíduo industrial, rochas sedimentares e cinzas de casca de arroz obtida pela queima a 350oC. Estes sólidos foram caracterizados pelas técnicas de difração de raios- X (DRX e espectroscopia na região do infravermelho (FTIR. Os testes de remoção de AM foram realizados em frascos de 125 mL, sob agitação constante, contendo 100 mL de solução de AM (100mg/L a 2000mg/L e adsorvente (0,1 a 0,6g, sob uma mesa agitadora a 200 rpm, em temperatura ambiente. A quantificação da remoção de AM foi realizada com auxílio de um espectrofotômetro UV-Vis da Varian (Cary 50, coletando 2 mL de amostra nos períodos de 2 à 1440 min. Dados de DRX evidenciaram uma mistura de argilominerais nos sólidos baseados em argilas. Nos ensaios de adsorção os materiais demonstraram eficiência para a remoção do corante, com destaque aqueles modificados com 10% de Nb2O5 exibindo 95% de remoção, no tempo de 120min, em solução de pH de ~6,5.

  11. Avaliação do consumo de corantes artificiais por lactentes, pré-escolares e escolares Evaluation of artificial dye intake by children

    Directory of Open Access Journals (Sweden)

    Simone Pinheiro Alves Schumann

    2008-09-01

    Full Text Available O objetivo do presente trabalho foi avaliar o consumo, por 150 crianças de até 10 anos, de pó para gelatina, preparado sólido para refresco e refrigerante. Foi feita aplicação de questionário de freqüência quantitativa e qualitativa com população infantil atendida no ambulatório de pediatria do Hospital Universitário Gafrée Guinle, Rio de Janeiro. Os dados foram tratados estatisticamente pelo programa SPSS 8.0. Verificou-se que os alimentos pesquisados são ampla e freqüentemente consumidos, sendo introduzidos na dieta, em muitos dos casos, antes da criança completar 1 ano de idade. Sabe-se que os produtos estudados não são adequados nutricionalmente, pois apresentam, além dos corantes, outros aditivos alimentares e não contêm nenhum nutriente importante para o funcionamento do organismo. Em relação aos corantes presentes nos produtos mencionados pela população estudada, constatou-se que os mais informados na rotulagem destes produtos, no item ingredientes, são amarelo crepúsculo, tartrazina e amaranto. Estimando que o teor dos corantes nos alimentos analisados esteja no limite máximo permitido pela legislação, observou-se que a grande maioria das crianças avaliadas pode estar excedendo a ingestão diária aceitável para o corante amaranto e que cerca de 20% da população pode estar excedendo o consumo recomendado para o amarelo crepúsculo. É importante que os valores máximos permitidos de corantes em alimentos, no Brasil, sejam adequados às recomendações realizadas pelo órgão internacional que avalia a segurança dos aditivos, e que ações educativas sejam realizadas.This study aimed at evaluating the intake of solid jelly powder, solid juice powder and soft drinks by children. The intakes were estimated through the application of a quantitative and qualitative food frequency questionnaire. The study was pursued in the pediatric nutrition ambulatory of Gaffrée Guinle University Hospital in Rio de

  12. Uso do corante azul de metileno a 2% na localização do linfonodo axilar em cadelas (Canis familiaris – Linnaeus, 1758

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    Tábata Maués

    2016-04-01

    Full Text Available A biopsia de linfonodo sentinela (LS é cada vez mais utilizada para a determinação do estadiamento clínico tumoral. O acometimento de linfonodos em animais com doença oncológica possui forte valor prognóstico no tumor da glândula mamária. Em medicina veterinária faltam diretrizes bem estabelecidas para a avaliação do LS. O objetivo deste estudo foi avaliar a eficácia do corante azul de metileno a 2% na identificação do linfonodo axilar em cadelas com lesões mamárias. Para tanto, foram utilizadas 101 cadelas, portadoras de lesões mamárias, submetidas à mastectomia radical unilateral ou bilateral. Antes do início da cirurgia, aplicou-se, por via intradérmica, na área ao redor da mama torácica cranial, solução de azul de metileno a 2% estéril. O corante foi eficaz na identificação do linfonodo axilar em 76,27% das cadeias mamárias. Obtiveram-se estruturas coradas em azul, semelhantes a linfonodos em 78,81% dos casos. Dessas estruturas, 96,77% foram confirmadas ao exame histopatológico como linfonodos. Dada a importância prognóstica do comprometimento de linfonodos em alguns tumores, a avaliação do LS deve ser incorporada à rotina clínica, de modo a permitir um estadiamento mais preciso das cadelas com neoplasia mamária.

  13. Adsorção dos corantes RO16, RR2 e RR141 utilizando lodo residual da indústria têxtil Adsorption of dyes RO16, RR2 and RR141 using residual sludge of textile industry

    Directory of Open Access Journals (Sweden)

    Andressa Regina Vasques

    2011-09-01

    Full Text Available A adsorção é uma das técnicas empregadas com sucesso para remoção efetiva da cor presente em efluentes têxteis. Com o objetivo de avaliar os diferentes parâmetros adsortivos, bem como determinar a eficiência de um adsorvente alternativo desenvolvido a partir de lodo residual têxtil na remoção de corantes, foram determinadas curvas de cinética de adsorção e isotermas. Por meio dos dados cinéticos e de equilíbrio obtidos, verificou-se que a 25ºC a adsorção foi favorável para todos os corantes, sendo esta a melhor condição para os corantes RO16 e RR2 na ausência de sais. Para o corante RR141, a adição de NaCl aumentou a capacidade de adsorção do adsorvente no equilíbrio e a adição de Na2SO4 favoreceu a adsorção para o corante RO16, ao contrário do que se observou para os outros dois corantes. A quantidade máxima de corante adsorvida por unidade de massa de adsorvente (q max nas melhores condições adsortivas para os corantes RO16, RR2 e RR141 foi de 81,30, 53,48 e 78,74 mg.g-1, respectivamente.The adsorption is one of the techniques that have been successfully used for effective removal of the dyes present in textile effluents. With the objective to evaluate the different adsorptive parameters, as well as determining the efficiency of one alternative adsorbent in the removal of dyes, kinetics and equilibrium data of adsorption were determined. By the kinetic data and of equilibrium, it was verified that the adsorption was favorable for all the dyes in 25ºC, being the best condition for the dye RO16 and RR2 in the total absence of salt. For the dye RR141, the addition of NaCl increased the adsorption capacity of adsorbent in the equilibrium and the addition of Na2SO4 favored the adsorption for the dye RO16, in contrast to what was observed for the two other dyes. The maximum quantity of dye adsorbed per unit mass of adsorbent (q max in the best adsorptive conditions for the dyes RO16, RR2 and RR141 was of 81

  14. Estudo da descoloração e degradação de corantes azo mediante processo oxidativo avançado: UV/H2O2

    OpenAIRE

    Adailton Alves

    2009-01-01

    Este estudo teve como objetivo o uso de Processos Oxidativos Avançados (POA\\'s), para a descoloração e degradação dos corantes azo (Congo Red) e (Acid Yellow 42) em solução aquosa, sendo realizado em escala de bancada (processo batelada), utilizando-se reator tubular. Utililizou-se o Processo Oxidativo Avançado UV/H2O2, avaliando a influência dos seguintes fatores: concentração dos corantes, pH, temperatura, concentração do H2O2, concentração do NaCl e concentração do Na2SO4. Para a otimizaçã...

  15. Estudo da descoloração do corante FD&C azul no 2 Indigotina pelo tratamento combinado do fungo Trametes versicolor e processo de filtração lenta

    OpenAIRE

    Lopes, Maria Margareth Gonçalves; Sales, Paulo de Tarso Ferreira; Campos, Luiza Cintra; Schimidt, Fernando; Santiago, Mariângela Fontes

    2014-01-01

    O uso de fungos na descoloração de corantes com métodos economicamente viáveis de produção de água bacteriologicamente segura há muito vem sendo descrito por diversos autores. Este trabalho teve por objetivo investigar a eficiência da remoção de corante artificial FD&C azul no 2 Indigotina, com uso do fungo de degradação branca Trametes versicolor em combinação com a filtração lenta. Para a realização dos trabalhos, foram instalados dois protótipos de filtros lentos denominados FL-A e FL-B - ...

  16. Nanocompósitos poliméricos de polietileno de alta densidade contendo hidróxidos duplos lamelares intercalados com ânions derivados de corantes azo

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    Ademir Zimmermann

    2014-06-01

    Full Text Available O presente trabalho descreve a síntese e caracterização de hidróxidos duplos lamelares (HDL de Zn/Al na razão molar 2:1, os quais foram intercalados com íons cloreto hidratados e ânions derivados dos corantes azo alaranjado de metila (AM e alaranjado II (AII. Após caracterização, os materiais foram utilizados como cargas em polietileno de alta densidade (PEAD e nanocompósitos foram preparados por extrusão e injeção, seguindo a norma ASTM D638-10. Os teores de cargas variaram de 0,1 até 2% (incluindo-se os sais de sódio dos corantes e os nanocompósitos homogêneos foram avaliados em relação as suas propriedades estruturais, térmicas e mecânicas. De modo geral, após a adição das cargas existe somente uma pequena influência na temperatura de fusão e cristalização do PEAD. Para os HDLs contendo o pigmento intercalado com o ânion do corante AM e sais de sódio de ambos os corantes, as propriedades mecânicas apresentaram leve aumento do módulo e tensão de ruptura e diminuição do alongamento em relação ao polímero puro e um comportamento inverso foi observado para o ânion AII, além do HDL contendo ânions cloreto hidratados.

  17. Corantes têxteis

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    Guaratini Cláudia C. I.

    2000-01-01

    Full Text Available A dye is a colored substance used to impart permanent color to other substances. Its most important use is in coloring textile fibers and fabrics. The removal of colour from dyehouse waste waters is currently a major problem in the textile sector. This paper provides an overview of the treatment technologies that can currently be used by the textile processor and the developments over the past decade with respect to the toxicological and ecotoxicological properties of synthetic organic dyes.

  18. Improved organic scintillation detectors; Possibilites de perfectionnement des detecteurs organiques a scintillations; Usovershenstvovannye organicheskie stsintillyatsionnye detektory; Detectores organicos de centelleo perfeccionados

    Energy Technology Data Exchange (ETDEWEB)

    Birks, J B [University of Manchester, Manchester (United Kingdom)

    1962-04-15

    Equations have been derived for the practical scintillation efficiency (photo-electrons/MeV) of organic crystals and solutions in terms of molecular parameters and these have been applied to the more important scintillator systems, for photomultipliers with S11 (glass window) and S13 (quartz window) responses. The results suggest several improvements in current organic scintillation detector practice: the use of binary rather than ternary solutions; the use of quartz rather than glass windows; and the reconsideration of mixed crystal scintillators based on naphthalene. Improvements by factors of 2 or more in the figure of merit (practical efficiency/decay time) for fast-scintillation counting can be obtained. (author) [French] L'auteur a etabli des equations pour determiner le rendement de scintillation (photoelectrons/MeV) de cristaux et solutions organiques, en faisant intervenir des parametres moleculaires. Il a applique ces equations a des appareils a scintillations plus importantes pour determiner la reponse des photomultiplicateurs a fenetre en verre (S11) et a fenetre en quartz (S13). Les resultats obtenus ont fait apparaitre la possibilite d'ameliorer, a plusieurs egards, les detecteurs organiques a scintillations du type courant, par exemple en remplacant les solutions ternaires par des solutions binaires, les fenetres en verre par des fenetres en quartz, ou en reexaminant les possibilites offertes par les scintillateurs a cristaux mixtes a base de naphtalene. L'introduction de ces perfectionnements conduirait a une amelioration, du simple au double ou plus, du facteur de qualite (efficacite/temps de decroissance) des dispositifs de comptage a scintillations. (author) [Spanish] Se han establecido ecuaciones que permiten calcular el rendimiento practico de centelleo (fotoelectrones/MeV) de los cristales y soluciones organicos en funcion de parametros moleculares; estas ecuaciones han sido aplicadas a los sistemas de centelleo mas importantes, para

  19. Remoção do corante FD&C azul nº 2 Indigotina em água com uso de fungos de decomposição branca e processo de filtração lenta: avaliação em escala piloto

    OpenAIRE

    LOPES, Maria Margareth Gonçalves

    2008-01-01

    Nas atividades industriais geradoras de resíduos os corantes são amplamente encontrados nos efluentes, quase sempre, constituindo um problema de ordem ambiental devido à sua toxicidade. O uso de fungos na degradação de corantes vem sendo estudado em diversos trabalhos científicos enquanto as vantagens econômicas e ambientais do uso de filtros lentos na produção de água bacteriologicamente segura há muito tempo já está descrita por diversos autores. Este trabalho teve por objeti...

  20. Estudo de oxidação avançada de corantes básicos via reação Fenton (Fe2+/H2O2

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    Thiago Romário Soares Paulino

    2015-09-01

    Full Text Available RESUMOO processo de oxidação avançada do tipo reação Fenton (Fe2+/H2O2 foi estudado neste trabalho para descoloração de dois efluentes sintéticos, contendo os corantes Azul de Metileno (AM e Rodamina B (RB. Experimentalmente, soluções em concentração de 10 mg L-1 dos corantes foram submetidas a diferentes dosagens de agente oxidante (H2O2 e catalisador (Fe2+ em uma temperatura de 27 °C e pH 3. Os resultados obtidos apresentaram altos níveis de remoção de cor, com eficiência da ordem de 96% para o AM e 86% no RB. Os dados mostraram bom ajuste ao modelo cinético. O monitoramento do espectro de absorção dos corantes mostrou uma diminuição da amplitude dos picos relacionados aos grupos cromóforos em ambos compostos, corroborando com os níveis de eficiência alcançados. A análise de remoção de matéria orgânica em termos de Demanda Química de Oxigênio (DQO não acompanhou a mesma taxa de decréscimo de descoloração, obtendo-se reduções de 40,9% para o AM e 25,5% para o RB.

  1. Estudo da descoloração do corante FD&C azul no 2 Indigotina pelo tratamento combinado do fungo Trametes versicolor e processo de filtração lenta

    Directory of Open Access Journals (Sweden)

    Maria Margareth Gonçalves Lopes

    2014-06-01

    Full Text Available O uso de fungos na descoloração de corantes com métodos economicamente viáveis de produção de água bacteriologicamente segura há muito vem sendo descrito por diversos autores. Este trabalho teve por objetivo investigar a eficiência da remoção de corante artificial FD&C azul no 2 Indigotina, com uso do fungo de degradação branca Trametes versicolor em combinação com a filtração lenta. Para a realização dos trabalhos, foram instalados dois protótipos de filtros lentos denominados FL-A e FL-B - no sobrenadante do filtro FL-A foi inoculado o referido fungo, e o filtro FL-B foi utilizado como controle (sem inoculação do microrganismo. O melhor percentual de remoção do corante pelo fungo Trametes versicolor em combinação com a filtração lenta foi de 44,74% 24 horas após a atividade máxima registrada de lacase. Os resultados mostraram que a filtração lenta combinada com o tratamento com o fungo T. versicolor não apresenta grande potencial para remoção de cor em 21 dias de tratamento, visto que os produtos microbianos gerados interferem no processo de filtração, diminuindo a eficiência do processo físico. Entretanto, restringindo o tempo de tratamento a 24 horas após a atividade enzimática máxima, o tratamento combinado apresentou boa eficiência.

  2. Obtenção de corante do repolho roxo (Brassica oleracea por dois métodos de extração

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    J. C. Almeida

    2015-12-01

    Full Text Available O repolho é uma hortaliça folhosa, com grande versatilidade, não somente pelo seu valor nutritivo. Além de colorir a mistura, destaca-se pelo elevado teor de antocianinas e compostos fenólicos, contribuindo para a prevenção de doenças cardiovasculares, bem como de alguns tipos de câncer. As antocianinas são largamente encontradas na natureza e responsáveis pela maioria das colorações azuis, violeta e vermelhas de flores e frutos, sendo sua principal utilização como corante natural na indústria. O presente trabalho tem como objetivo a obtenção de um corante, antocianina, de repolho roxo (Brassica oleracea por dois métodos distintos de extração. No corrente estudo, o extrato foi obtido por meio de procedimento alcoólico e aquoso. As características avaliadas foram: pH; acidez total titulável; Teor de sólidos solúveis (°Brix; umidade; cinzas; proteínas; extração e quantificação de antocianinas totais; Vitamina C. O resultado encontrado para antocianina no repolho roxo in natura foi de 6,58 mg/100g, para o extrato por método alcoólico foi de 4,58 mg/100g e 5,33 mg/100g para o extrato aquoso. Observou-se que a extração pelo método aquoso teve um rendimento melhor, correspondente a 50% do seu valor inicial, a extração alcoólica foi de 30% do seu volume inicial.Red cabbage dye obtaining (Brassica oleracea by two extraction methodsAbstract: Cabbage is avegetable crop with great versatility, not limited to its nutritional value. Besides coloring the mixture, it stands out for its high quantity of anthocyanin and phenolic compounds, which contribute to prevention of cardiovascular diseases and some types of cancer. Anthocyanins are widely found in nature and are responsible for the majority of blue, violet and red present in flowers and fruits. Thus, its main utilization is in industries as a natural dye. This study aims to obtain a colorant, anthocyanin, the red cabbage (Brassica oleracea by two different

  3. DETERMINAÇÃO DA EFICÁCIA DE DIFERENTES SOLVENTES ORGÂNICOS NA DISSOLUÇÃO DOS CORANTES NATURAIS BIXINA E NORBIXINA

    Directory of Open Access Journals (Sweden)

    MARCO AURÉLIO DA SILVA COUTINHO

    2017-05-01

    Full Text Available Resumo: Nos últimos anos, os pigmentos naturais de urucum têm sido substancialmente utilizados pelas indústrias de alimentos para dar cor a produtos tais como: massas alimentícias, cereais, produtos de panificação, gelados comestíveis, sobremesas, condimentos, etc. Dentre esses pigmentos destaca-se a bixina, um éster monometílico do ácido dicarbixílico alfa-norbixina pouco solúvel em óleo e anorbixina um caratenóide diácido carboxilico. Em virtude da crescente aplicação industrial  dos corantes naturais, este trabalho teve como objetivo determinar a solubilidade desses pigmentos em diferentes solventes, por meio de espectrofotometria UV-vis. Foram preparadas soluções sob as mesmas condições, utilizando-se os solventes: acetona, álcool etílico, álcool isopropílico, dimetilsulfóxido e clorofómio. A absorbância foi medida em função do comprimento de onda de cada solução por meio da análise dos espectros de UV-Vis, na região de 800 a 200 nm. Os dados obtidos referentes às análises no UV-Vis confirmaram a maior eficácia do Dimetilsulfóxido (DMSO na dissolução da bixinae  e da acetona para o norbixina  em relação aos outros solventes.

  4. Electrohemical properties of carbon nanotube paste electrodes modified with redox cationic dyes=Propriedades eletroquímicas de eletrodos a base de pasta de nanotubo de carbono modificados com corantes redox catiônicos

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    Arnaldo César Pereira

    2012-07-01

    Full Text Available The present work describes the electrochemical behavior of methylene blue and toluidine blue as electron mediators adsorbed in the multiwall carbon nanotubes paste. Based on midpoint potential and separation of cathodic and anodic peaks (ΔE, it was not observed interaction of different eletrolytes with the cationic dyes by an ion exchange reaction and, as a consequence, absence of leaching of cationic dyes to the solution phase. The kinetics of electron transfer on the surface electrode was not sufficiently fast showing a fairly resistence of carbon nanotube paste modified with the mediators. The midpoint potential and ΔE also were insentive to the pH range (4-8, confirming the protective effect of carbon nanotubes matrix, owing to strong interaction of between the latter and the nitrogen of nitrogen of cationic dyes with carbon nanotube matrix, minimizing the proton interaction under cationic dye. This result is very important for sensor/biosensor preparation, because the eletrooxidation behavior of the analyte will be only affected by its formal potencial shifting. Carbon nanotubes proved to be an efficient solid matrix for the adsorption of mediator electron in comparison to the electrochemical behavior of free cationic dyes in solution phase.O presente trabalho descreve o comportamento eletroquímico de azul de metileno e azul de toluidina como mediadores de elétrons adsorvidos em pasta de nanotubo de carbono multiparede. Com base no potencial médio e na separação de pico catódico e anódico (ΔE, não foi observada interação de diferentes eletrólitos com os corantes catiônicos por meio de reação de troca iônica e, como consequência, ausência de lixiviação dos corantes para solução. A cinética de transferência de elétron na superfície do eletrodo não foi suficientemente rápida, mostrando razoável resistência da pasta de nanotubo de carbono modificada com os mediadores. O potencial médio e ΔE também foram insens

  5. Impacto dos mediadores redox na remoção de cor de corantes azo e antraquinônico por lodo granular anaeróbio sob condições mesofílicas e termofílicas Impact of redox mediators on colour removal of azo and anthraquinone dyes by anaerobic granular sludge under mesophilic and thermophilic conditions

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    André Bezerra dos Santos

    2007-03-01

    Full Text Available Investigou-se o efeito de diferentes mediadores redox (MR na remoção de cor de corantes azo e antraquinônico pelo uso de lodo granular anaeróbio sob condições mesofílicas (30ºC e termofílicas (55ºC. Comprovou-se em experimento em batelada que a adição de concentrações catalíticas de MR pode ter um efeito marcante nas taxas de descoloração do corante azo Reactive Red 2 (RR2, mas o mesmo comportamento não pode ser obtido com o corante antraquinônico Reactive Blue 5 (RB5. Entretanto, com ambos os corantes, o simples aumento da temperatura de incubação para condições termofílicas fez acelerar consideravelmente os processos de descoloração, comparados com condições mesofílicas. Por exemplo, a constante de primeira ordem "k" da redução dos corantes RR2 e RB5, foi aumentada em 6,2 e 11 vezes, respectivamente, à 55ºC quando comparado com 30ºC. Por fim, comprovou-se em experimentos de fluxo contínuo, a boa performance do tratamento termofílico na descoloração redutiva de corantes azo.The effect of different redox mediators (RM on colour removal of azo and anthraquinone dyes was investigated with anaerobic granular sludge under mesophilic (30ºC and thermophilic (55ºC conditions. Batch experiments revealed that an addition of catalytic concentrations of RM provided a remarkable effect on the decolourisation rates of the azo dye Reactive Red 2 (RR2, but the same effect could not be obtained with the anthraquinone dye Reactive Blue 5 (RB5. Nevertheless, for both dyes, the temperature increase to thermophilic conditions was an effective strategy to considerably accelerate the decolourisation process compared to mesophilic conditions. For instance, the first-order rate constant "k" of RR2 and RB5 reduction, was increased in 6.2 and 11-fold, respectively, at 55ºC in comparison with 30ºC. Such an effect of the temperature on the reductive decolourisation of azo dye was also verified in continuous flow experiments.

  6. Dentin penetrability evaluation of three different dyes in root-end cavities filled with mineral trioxide aggregate (MTA Avaliação da penetração dentinária de três diferentes corantes em retrocavidades obturadas com agregado trióxido mineral (MTA

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    Beatriz Farias Vogt

    2006-04-01

    Full Text Available The purpose of this study was to evaluate the penetration of three dyes in MTA root-end fillings. In 30 single-rooted teeth, cavities for retrofilling were prepared with an ultrasound appliance and filled with MTA. The specimens were randomly assigned to three groups (n = 10 and immersed in the following solutions: 2% methylene blue (MET, 50% silver nitrate (NIT and 0.2% rhodamine B (ROD. Two transversal slices (1 mm of the retrofilling region were obtained and evaluated using the Image Tool 3.0 software to obtain a quantitative evaluation (in mm² of the dye penetration around the retrofillings. Data were submitted to statistical analysis using Student’s t-test. The lowest degree of dye penetration was observed for the NIT group, in both slices (p A proposta deste trabalho foi avaliar a penetração de três corantes em retrocavidades obturadas com MTA. As retrocavidades foram confeccionadas com aparelho de ultra-som em 30 dentes unirradiculares e obturadas com MTA. Os espécimes foram divididos aleatoriamente em três grupos (n = 10 e imersos nas seguintes soluções corantes: azul de metileno a 2% (MET, nitrato de prata a 50% (NIT e rodamina B a 0,2% (ROD. Duas fatias transversais (1 mm da região retrobturada foram obtidas e avaliadas através do software Image Tool 3.0, objetivando quantificar a área (em mm² de penetração do corante ao redor das retrobturações. Os dados foram submetidos à análise estatística, utilizando o teste t de Student. A menor área de penetração foi observada no grupo NIT, nas duas fatias (p < 0.05. A penetração de corante foi significativamente maior no grupo ROD quando comparado ao grupo NIT, nas duas fatias (p < 0.05, e ao grupo MET, somente na fatia 1 (p < 0.05. Dentro das limitações desta pesquisa, concluiu-se que a escolha da solução corante pode influenciar a avaliação da penetração em estudos sobre retrobturações e que o grupo NIT teve a menor capacidade de penetração na dentina

  7. Risco de contaminação do corante azul de tripano após primeira utilização Risk of contamination of trypan blue dye after first use

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    João Baptista Nigro Santiago Malta

    2006-02-01

    Full Text Available OBJETIVOS: Determinar o potencial risco de contaminação do frasco de azul de tripano (AT depois de utilizado pela primeira vez e estocado em diferentes condições de temperatura e umidade, assim como identificar os possíveis fatores de contaminação, microrganismos mais freqüentemente envolvidos e simultaneamente avaliar as propriedades bacteriostáticas e bactericidas do corante. MÉTODOS: Realizado estudo experimental, prospectivo, em que 30 frascos de AT foram divididos em três grupos (A: controle, B: armazenamento em geladeira e C: armazenamento em armário. O corante era aspirado e semeado em placas de ágar sangue e tubo de ágar Sabouraud. No grupo A o AT foi semeado apenas logo após a abertura dos frascos (tempo zero - T0, nos grupos B e C ocorreu semeadura nos T0, T1 (1 dia, T2 (2 dias, T7 (7 dias e T10 (10 dias após abertura dos frascos. No 10º dia os frascos dos grupos B e C também foram submetidos a um raspado do lado interno do frasco após abertura. Concomitantemente foi realizado teste de ação inibitória do corante AT para estudo da atividade bacteriostática e bactericida. RESULTADOS: As semeaduras realizadas no T0 não apresentaram contaminação. Entre os T1 e T10 mais o raspado houve apenas 1 frasco contaminado armazenado em geladeira. O microrganismo encontrado foi o Aspergillus niger. Foi comprovado que o corante não apresenta ação bactericida e bacteriostática para as bactérias testadas. CONCLUSÕES: Nas condições do estudo não houve contaminação dos frascos armazenados em armário e 1 frasco (10% armazenado em geladeira apresentou contaminação após abertura e uso inicial. A fonte de contaminação talvez seja o lado externo do produto. O AT não apresenta propriedades bactericidas e bacteriostáticas para as bactérias testadas e na concentração utilizada.PURPOSE: To determine the potential risk of contamination of a trypan blue bottle (TB after first use and after being stored under different

  8. Impregnação de filmes do compósito de policarbonato (PC e sílica-gel (Si com corante fotocrômico em fluido supercrítico - DOI: 10.4025/actascitechnol.v32i1.1999

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    Fernanda de Almeida Fin de Lima

    2009-12-01

    Full Text Available O objetivo deste trabalho foi estudar a impregnação do corante fotocromático Reversacol Graphit® em filmes do compósito de policarbonato (PC e sílica-gel (Si, com a finalidade de obter aplicações em lentes fotocrômicas. Filmes de PC puros também foram impregnados nas mesmas condições, para verificar o efeito da adição de sílica-gel. Os filmes do compósito foram produzidos em proporções de Si:PC de 1:40 e 1:80 (m m-1, pelo método casting. Para a impregnação do corante Reversacol Graphit® nos filmes obtidos foi utilizado o processo supercrítico, pela sua eficiência e benefícios. A impregnação foi feita nos tempos de 15, 30, 45, 60, 90, 120, 150 e 180 min. A temperatura e a pressão adotadas foram de 60ºC e 120 bar. A quantidade de pigmento impregnado nos filmes de Si:PC – 1:40 e 1:80 (m m-1 foi de 29 e 23% de massa de corante por massa de compósito, respectivamente, e para o filme de PC puro foi de apenas 2,2% massa de corante por massa de compósito. Pelas análises térmicas, verificou-se que os filmes do compósito apresentaram maior estabilidade térmica. Pela técnica de microscopia eletrônica, observou-se que os filmes de PC puro e dos compósitos Si:PC – 1:40 e 1:80 (m m-1 apresentaram uma superfície lisa e homogênea.

  9. Avaliação do tratamento físico-químico e biológico dos resíduos de corantes produzidos em laboratório de microbiologia = Evaluation of the physical-chemical and biological treatment of residue from dyes produced at a microbiology laboratory

    OpenAIRE

    Lenice Leiko Nozu; Patrícia Cavalcanti de Albuquerque Saldanha; Marlene Soares; Valma Martins Barbosa; Alessandro Feitosa Machado; Edilsa Rosa Silva

    2010-01-01

    Os diferentes resíduos produzidos pelo homem em diversas áreas representam grave problema ambiental, quando inadequadamente descartados. No presente trabalho, foram realizados experimentos de degradação de resíduos de corantes gerados no Laboratório de Microbiologia da Universidade Tecnológica Federal do Paraná, CampusCuritiba, por meio do cultivo líquido implementado com Pleurotus sajor-caju e processo oxidativo avançado (POA – Sistema UV/H2O2). A verificação da eficiência desses processos f...

  10. Citotoxicity of food dyes sunset yellow (E-110, bordeaux red (E-123, and tatrazine yellow (E-102 on Allium cepa L. root meristematic cells Citotoxicidade dos corantes alimentares amarelo crepúsculo (E-110, vermelho bordeaux (E-123 e amarelo tartrazina (E-102 em células meristemáticas de raízes de Allium cepa L.

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    Keiva Maria Silva Gomes

    2013-03-01

    Full Text Available The objective of this study was to evaluate the cytotoxic effect of the food dyes sunset yellow, bordeaux red, and tartrazine yellow on the cellular cycle of Allium cepa L. Each dye was evaluated at the doses of 0.4 and 4.0 mL, at the exposure times of 24 and 48 hours in root tip cells of Allium cepa L. Slides were prepared and cells were analyzed during the whole cell cycle for cellular aberrations totaling 5,000 total cells for each dose evaluated. The mitotic index was calculated, and statistical analysis was performed using the Chi-squared test (p Este estudo teve por objetivo avaliar o efeito citotóxico dos corantes alimentares amarelo crepúsculo, vermelho bordeaux e amarelo tartrazina sobre o ciclo celular de Allium cepa L. Cada corante foi avaliado nas doses de 0,4 e 4,0 mL, nos tempos de exposição de 24 e 48 horas, em células de pontas de raízes de Allium cepa L. Prepararam-se lâminas e analisaram-se células, em todo o ciclo celular, e a presença de aberrações celulares, totalizando 5.000 células para cada dose avaliada. Foi calculado o índice mitótico e a análise estatística foi feita por meio do teste quiquadrado (p < 0,05. Os resultados mostraram que os três corantes, nas doses e tempos de exposição avaliados, foram citotóxicos às células do sistema-teste utilizado. Estudos adicionais de citotoxicidade devem ser conduzidos para se somar a estes resultados e, assim, avaliar, com propriedade, a ação destes três corantes em nível celular.

  11. Ação de Micoflora de efluentes agroindustriais sobre diferentes corantes e substratos lignocelulósicos =Action of mycoflora from agri-industrial effluents on different dyes and lignocellulosic substrates

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    Ana Maria Queijeiro López

    2011-09-01

    Full Text Available Enzimas extracelulares de fungos são importantes para sua sobrevivência em ambientes inóspitos, sendo capazes de degradar compostos recalcitrantes. Fungos filamentosos secretam hidrolases e fenoloxidases capazes de degradar complexos de estruturas aromáticas,como de alguns xenobióticos. O propósito deste trabalho foi testar diferentes corantes (Azul de Metileno, Azure B, Verde Malaquita e Cristal Violeta, em substituição ao composto Poly R478, no método de seleção de microrganismos degradadores de fenóis em meio sólido, além de comparar tal atividade de Micoflora isolada de efluentes de indústria sucroalcooleira com a de outros fungos adquiridos em coleção oficial. Os corantes testados revelaram-se ótimos substitutos do Poly R478. O isolado que apresentou atividade descolorante mais intenso do que a do diâmetro de seu crescimento (Cladosporium sp. foi testado, então, em meio líquido frente a dois substratos naturais e um sintético (bagaço de cana, serragem de madeira e azul de metileno. Este removeu altas concentrações de glic��dios redutores, proteínas e fenóis totais, além de reduzir a DQO em meio com serragem de madeira como substrato fenólico natural. Tal fungo, portanto, mostrou-se promissor para compor consórcios visando cometabolismo ebiorremediação de efluentes nos quais há presença de compostos fenólicos ou outros recalcitrantes com estrutura semelhante à de lignina.Extracellular enzymes of fungi are important for survival in inhospitable environments, as they are able to degrade recalcitrant compounds. Filamentous fungi secrete hydrolases and phenoloxidases that are capable of degrading complexes of aromatic structures, such as certain xenobiotics. The purpose of this study was to test different dyes (methylene blue, Azure B, Malachite Green and Crystal Violet, replacing the compound Poly R478 in the method of selection of phenol decomposer microorganisms in solid medium, and compare this

  12. Energy alternative for the use of organic waste (swine feces) in the state of Tabasco; Alternativa energetica para el aprovechamiento de los desechos organicos (excretas de ganado porcino) en el estado de Tabasco

    Energy Technology Data Exchange (ETDEWEB)

    Ramon Garcia, E.; Angles Falconi, S.I.; Vazquez Magana, L.R.; Tun Perez, A.C. [Instituto Tecnologico de Villahermosa, Villahermosa, Tabasco (Mexico)]. Email: bioleliza_ramgar@hotmail.com; sergio_falcorp@hotmail.com

    2009-09-15

    Biogas is obtained from decomposing organic material due to the action of four types of bacteria, in the absence of oxygen: hydrolytic, producers of moncarbonate compounds and acidogenics, producing organic fatty acids and other polycarbonate compounds; acetogenic, producers of hydrogen and CO{sub 2}; homoacetogenic, that can convert a considerable amount of multicarbonate or monocarbonate compounds into acetic acid and; metanogenic, producers of methane gas, the principal component of biogas. To design and build the pilot equipment proposed for this research, a 20-liter container was used with 10 kg of swine feces with identical volumes of inoculates. The aerobic fermentation process was immediate begun, followed by the anaerobic process; metabolic reactions were conducted. A total of 0.119 m3 of biogas was obtained from the anaerobic fermentation of 10 kg of swine feces, 60% (0.0714 m{sup 3}) of which was methane gas and the remaining 40%(0.0476 m{sup 3}) hydrogen sulfide (HS). During this investigation, it was concluded that obtaining this by-product (methane biogas), which can be used as a biofuel, provides an economically and ecologically sustainable alternative that reduces organic discharges (swine feces) into rivers and reduces the energy expenditures of swine farms. Because of the high generation of RSM, the creation of a biogas production plant in Tabasco is proposed. [Spanish] El biogas se obtiene al descomponerse la materia organica debido a la accion de cuatro tipos de bacterias, en ausencia de oxigeno: las hidroliticas, que producen compuestos monocarbonados, las acidogenicas producen acidos grasos organicos y otros compuestos policarbonados; las acetogenicas productoras de Hidrogeno y CO{sub 2}; las homoacetogenicas, que pueden convertir una cantidad considerable de compuestos multicarbonados o monocarbonados en acido acetico; y las metanogenicas, productoras del gas metano, principal componente del biogas. Para el diseno y construccion del equipo

  13. Impregnação de filmes do compósito de policarbonato (PC e sílicagel (Si com corante fotocrômico em fluido supercrítico = Impregnation of composite from polycarbonate (PC and silica gel (Si films with photochromic dye in supercritical fluid

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    Fernanda de Almeida Fin de Lima

    2010-01-01

    Full Text Available O objetivo deste trabalho foi estudar a impregnação do corante fotocromático Reversacol Graphit® em filmes do compósito de policarbonato (PC e sílica-gel (Si, com a finalidade de obter aplicações em lentes fotocrômicas. Filmes de PC puros também foramimpregnados nas mesmas condições, para verificar o efeito da adição de sílica-gel. Os filmes do compósito foram produzidos em proporções de Si:PC de 1:40 e 1:80 (m m-1, pelo método casting. Para a impregnação do corante Reversacol Graphit nos filmes obtidos foiutilizado o processo supercrítico, pela sua eficiência e benefícios. A impregnação foi feita nos tempos de 15, 30, 45, 60, 90, 120, 150 e 180 min. A temperatura e a pressão adotadas foram de 60ºC e 120 bar. A quantidade de pigmento impregnado nos filmes de Si:PC – 1:40e 1:80 (m m-1 foi de 29 e 23% de massa de corante por massa de compósito, respectivamente, e para o filme de PC puro foi de apenas 2,2% massa de corante por massa de compósito. Pelas análises térmicas, verificou-se que os filmes do compósito apresentarammaior estabilidade térmica. Pela técnica de microscopia eletrônica, observou-se que os filmes de PC puro e dos compósitos Si:PC – 1:40 e 1:80 (m m-1 apresentaram uma superfície lisa e homogênea.The aim of this work was to study the impregnation of the photochromic dye Reversacol Graphit® in composite films ofpolycarbonate (PC and silica gel, with the purpose of finding applications in photochromic lenses. Pure PC films were also impregnated in the same conditions, to verify the effect of the silica-gel addition. The composites films were produced in Si:PC ratios of 1:40 and 1:80 (m m-1, using the casting method . For the impregnation of the dye Reversacol Graphit in the obtained films, the supercritical process was used due to its efficiency and benefits. The impregnation was made in the times of 15, 30, 45, 60, 90, 120, 150 and 180 minutes. The adopted temperature and pressure

  14. Il Punto Organico: una storia italiana

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    Paolo Rossi

    2015-02-01

    The origin of the notion of P.O. is traced back to some statistical studies performed more than a decade ago . Its subsequent application to university recruiting follows from  a sequel of administrative actions taken by the Ministry but it is not based on an explicit (and formally required legal formulation. The recent structural evolution of the università system and some changes in the legislation have further weakened the justification for such a constraint.  An alternative (and legally consistent mechanism for keeping under control the projected expenses  for personnel is proposed.

  15. Determinação e análise de isotermas de adsorção do corante azul 5G em leito fixo de carvão ativado=Mathematical model of the adsorption column, in activate Carbon, used in the renovation of blue-colorant 5G

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    Jorge Antonio Lopes Dal Piva

    2011-10-01

    Full Text Available Visando o desenvolvimento de um processo de tratamento de efluentes têxteis, este trabalho teve por objetivo estudar o processo de adsorção do corante reativo azul 5G de um efluente sintético em carvão ativado. As isotermas de adsorção, com seus respectivos parâmetros ajustados, em sistema batelada foram obtidas para as temperaturas de 30, 40 e 60C (com pH controlado na faixa de 6,0 a 8,0 e também com tempo de contato entre o sistema corante-carvão de 90 horas segundo os modelos de Langmuir e Freundlich. A partir daí estes parâmetros foram colocados em função da temperatura, apresentando bons resultados frente aos dados experimentais.This work, to looking for the development of process for wastes textile treatment, had the objective to study the adsorption process of the blue reactive dyes 5G from the synthetic effluent in coal activated. The isotherms of adsorption in batch system was made for temperatures of 30, 40 and 60C (the pH was controlled in 6.0 until 8.0 and the time of contact between the system dye-coal was 90 hours with posterior adjustment of the models for Langmuir and Freundlich equations. After, these parameters were put in function of temperature, with good results when compared to the experimental data.

  16. AUTOMATIC AND DIRECT MICROSCOPIC SOMATIC CELLS COUNT OF LACAUNE DAIRY SHEEP, USING THE ROSENFELD AND METHYL GREEN-PIRONIN STAINS CONTAGEM AUTOMÁTICA E MICROSCÓPICA DIRETA DAS CÉLULAS SOMÁTICAS DO LEITE DE OVELHAS DA RAÇA LACAUNE, UTILIZANDO COMO CORANTES O ROSENFELD E VERDE DE METIL E PIRONINA-Y

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    Viviani Gomes

    2010-04-01

    Full Text Available The objectives of the present study were the analysis of cell counts, the comparison between different methods for counting cells and the quantification of different types of cells observed in the milk of Lacaune sheep, using automatic somatic cell counts (SCC and direct microscopic SCC. Milk smears were stained with methyl green-pyronin-Y and Rosenfeld stain. Mean of  automatic cell counts was 0.145 x106 cells/mL of milk, and mean of direct microscopic counts using methyl green-pyronin-Y and Rosenfeld were respectively 0.157 and 0.193 x106 cells /mL of milk. Samples used in direct microscopic counts were evaluated according to the different types of cells and the following results were recorded: 0.094 and 0.14 x106 mononuclear cells /mL, 0.063 and 0.051 x106 polymorphonuclear cells /mL of milk using methyl green-pyronin-Y and Rosenfeld stain, respectively. It may be concluded that there were differences in the methods used for counting cells. The number of cells recorded was lower when methyl green-pyronin-Y and automatic counts were used, compared with direct microscopy using Rosenfeld stain.

    KEY WORDS: somatic cells and cytology, lacaune, milk, sheep.
    O presente estudo teve como objetivo a análise da celularidade, a comparação dos diferentes métodos de contagem celular e a quantificação dos diferentes tipos celulares presentes no leite de ovelha da raça Lacaune através da contagem de células somáticas (CCS automática e da CCS microscópica. Coraram-se os esfregaços lácteos com os corantes verde de metil e pironina-Y e Rosenfeld. O valor mediano da contagem celular automática foi de 0,145 x106 células/mL de leite, e os valores das contagens microscópicas diretas utilizando verde de metil e pironina-Y e Rosenfeld foram respectivamente de 0,157 e 0,193 x106 células/mL de leite. Avaliaram-se as amostras destinadas às contagens microscópicas diretas de acordo com os diferentes tipos celulares, encontrando-se os

  17. Effect of different dye solutions on the evaluation of the sealing ability of mineral trioxide aggregate Efeito de diferentes soluções corantes na avaliação da capacidade seladora do agregado de trióxido mineral

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    Mário Tanomaru Filho

    2005-06-01

    Full Text Available Alkaline materials have shown incompatibility with methylene blue dye in leakage experiments. The goal of the present study was to analyze the effect of different dyes on the evaluation of the apical sealing ability of Mineral Trioxide Aggregate root-end fillings. Fifty-six extracted human canines were submitted to root canal instrumentation and obturation. After apical resection, retrograde cavities were prepared and teeth were randomly divided into four experimental (n = 13 and two control groups (n = 2. The following root-end filling materials were used: groups 1 and 2 - Pro Root MTA (Dentsply, groups 3 and 4 - zinc oxide-eugenol cement (ZOE. Teeth in groups 1 and 3 were immersed in 2% methylene blue solution, while teeth in groups 2 and 4 were immersed in 0.2% rhodamine B in a reduced pressure environment for 48 hours. Teeth were then longitudinally sectioned and leakage was evaluated. Results were submitted to statistical analysis (ANOVA and Tukey's test. Group 1 presented the least leakage (p Tem sido demonstrada a incompatibilidade de materiais alcalinos com a solução corante de azul de metileno utilizada em testes de infiltração marginal. O objetivo do presente estudo foi analisar a influência de diferentes soluções corantes na avaliação do selamento apical proporcionado pelo agregado de trióxido mineral. Cinqüenta e seis caninos humanos extraídos tiveram seus canais radiculares instrumentados e obturados. Após a secção da porção apical, cavidades retrógradas foram preparadas e os dentes divididos aleatoriamente em quatro grupos experimentais (n = 13 e dois controles (n = 2. Foram utilizados os seguintes materiais retrobturadores: grupos 1 e 2 - Pro Root MTA (Dentsply; grupos 3 e 4 - cimento de óxido de zinco e eugenol (OZE. Em seguida, os dentes dos grupos 1 e 3 foram imersos em solução de Azul de Metileno a 2% e dos grupos 2 e 4 em solução de Rodamina B a 0,2% por 48 horas em ambiente com vácuo. Decorrido este

  18. Use of chloramine-T and two dyes in the sensitive determination of stavudine in pharmaceuticals Uso de cloramina-T e de dois corantes na determinação sensível de estavudina em medicamentos

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    Kanakapura Basavaiah

    2007-09-01

    éria-prima e nas formulações utilizando-se clroamina-T (CAT e dois corantes, alaranjado de metila e índigo carmim como reagentes. A titulação envolve o tratamento de STV com excesso medido de CAT em meio de ácido clorídrico, e, quando a oxidação se completar, o oxidante que não reagiu é determinado iodometricamente. Os métodos espectrofotométricos compreendem a adição de excesso conhecido de CAT ao STV em ácido clorídrico, seguida da determinação do oxidante residual por meio da reação com quantidade fixada de alaranjado de metila, medindo-se a absorvância a 520 nm (Método A ou índigo carmim, medindo-se a absorvância a 610 nm (Método B. Em todos os métodos, a quantidade de CAT que reagiu corresponde à quantidade de STV. No método titulométrico, a reação segue a estequiometria 1:1 (STV:CAT e é aplicável na faixa de 1,5 a 10 mg de STV. Nos métodos espectrofotométricos, a absorvância aumenta linearmente com a concentração de STV. Os sistemas obedecem a lei de Beer nos intervalos de 0,2 a 2,0 mg/mL e 1,0 a 10,00 mg/mL para os métodos A e B, respectivamente, e os valores de sensibilidade de Sandell correspondentes são 0,004 e 0,015 µg/cm². Os limites de detecção e de quantificação são apresentados para ambos os métodos. A precisão e a exatidão intra-dia e inter-dia dos métodos desenvolvidos são avaliadas de acordo com as normas ICH. Os métodos foram aplicados com êxito aos ensaios de STV em comprimidos e em cápsulas e os resultados foram comparáveis com aqueles obtidos com o método de referência, utilizando-se o teste t de Student e o teste F. Não se observou interferência dos adjuvantes comuns em comprimidos. A exatidão e a confiabilidade dos métodos foram ajustadas por meio de experimentos de recuperação via método de adição de padrão.

  19. Compósitos de poli(álcool vinílico contendo hidroxissais lamelares de zinco, intercalados com corantes aniônicos azo (tropaeolina 0 e tropaeolina 00 Poly(vinyl alcohol composites containing layered hydroxide salts, intercalated with anionic azo dyes (tropaeolin 0 and tropaeolin 0

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    Marlon Luiz Neves da Silva

    2013-01-01

    Full Text Available Hidroxissais lamelares de zinco foram intercalados com corantes aniônicos azo, obtendo-se pigmentos de coloração laranja. Os materiais foram caracterizados por difração de raios X (XRD, espectroscopia vibracional na região do infravermelho com transformada de Fourier (FTIR, análise térmica (TGA/DTA/DSC e espectroscopia fotoeletrônica de raios X (XPS. Após caracterização, os pigmentos lamelares foram dispersos em uma matriz de poli(álcool vinílico - PVA, em concentrações variáveis, em relação à massa de PVA. Filmes homogêneos, transparentes e coloridos foram obtidos pelo método de "casting" úmido e mantidos em dessecador em umidade controlada de 65 % por uma semana e avaliados quanto às suas propriedades mecânicas. Devido às diferentes polaridades dos ânions intercalados, diferentes comportamentos foram observados para os pigmentos quando utilizados como cargas em PVA. Esse trabalho abre uma frente de pesquisas na utilização de hidroxissais lamelares intercalados com corantes aniônicos, como cargas alternativas em materiais compósitos poliméricos.Layered zinc hydroxide salts were intercalated with anionic azo dyes, obtaining orange pigments. The materials were characterized by X-ray diffraction (XRD, Fourier Transform Infrared spectroscopy (FTIR, thermal analysis (TGA/DTA/DSC and X-ray photoelectron spectroscopy (XPS. After characterization, the layered pigments were dispersed into a matrix of poly(vinyl alcohol - PVA, in variable concentrations, in relation to the PVA mass. Homogeneous, transparent and colorful films were obtained by wet casting method and kept in a desiccator at 65% of humidity for one week and evaluated in relation to their mechanical properties. Owing to the different intercalated anions polarities, different behaviors were observed for both pigments when used as fillers in PVA. This work opens a research front in the utilization of layered hydroxide salt intercalated with anionic dyes, as

  20. Esferas de quitosana/Fe na degradação do corante Azul QR-19 por processos foto-Fenton utilizando luz artificial ou solar Chitosan/Fe spheres on the Blue QR-19 dye degradation by photo Fenton processes using artificial or solar light

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    Kely V. de Souza

    2010-09-01

    Full Text Available A contaminação dos recursos hídricos é um dos maiores problemas ambientais da atualidade. Dentre as várias fontes poluidoras, destacam-se as indústrias têxteis, por serem fontes geradoras de grandes volumes de efluentes, muitas vezes tratados de maneira ineficiente. A principal causa do grande impacto ambiental decorrente deste descarte é a presença dos corantes, tais como os compostos do tipo azo, que podem gerar subprodutos de caráter carcinogênico e/ou mutagênico, ou como os de base antraquinona, que são muito resistentes à degradação natural e portanto persistem no efluente por um longo tempo. O objetivo do presente trabalho consiste na utilização de processos foto-Fenton assistidos por luz artificial e solar, utilizando ferro imobilizado em esferas de quitosana reticulada com glutaraldeído, para promover a degradação do corante reativo Azul QR-19, de base antraquinona, em solução aquosa. As esferas obtidas apresentaram tamanho regular com diâmetro de 4,0 mm. Os resultados demonstraram 90% de descoloração do sistema em 180minutos e redução de 60% do teor de carbono orgânico total (COT, para o sistema foto-Fenton utilizando luz artificial. Para o sistema fotoassistido com luz solar, a descoloração foi integralmente obtida em 120 minutos com 70% de redução do teor de COT. Foi observado que o ferro permaneceu na matriz após o tratamento, possibilitando sua reutilização.The contamination of water resources is one of the greatest environmental problems today. Among the polluting sources are the textile industries due to the production of large volumes of effluent, often treated inefficiently. The main reason for the environmental impact of the rejected materials is the presence of dyes such as azo reactive compounds that can generate by-products with carcinogenic and mutagenic effects. They may also include anthraquinone type compounds, which are highly resistant to degradation and persist in the effluent for a

  1. Ação de Micoflora de efluentes agroindustriais sobre diferentes corantes e substratos lignocelulósicos - doi: 10.4025/actascibiolsci.v33i4.6187 Action of mycoflora from agri-industrial effluents on different dyes and lignocellulosic substrates - doi: 10.4025/actascibiolsci.v33i4.6187

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    Ana Maria Queijeiro López

    2011-09-01

    Full Text Available Enzimas extracelulares de fungos são importantes para sua sobrevivência em ambientes inóspitos, sendo capazes de degradar compostos recalcitrantes. Fungos filamentosos secretam hidrolases e fenoloxidases capazes de degradar complexos de estruturas aromáticas, como de alguns xenobióticos. O propósito deste trabalho foi testar diferentes corantes (Azul de Metileno, Azure B, Verde Malaquita e Cristal Violeta, em substituição ao composto Poly R478, no método de seleção de microrganismos degradadores de fenóis em meio sólido, além de comparar tal atividade de Micoflora isolada de efluentes de indústria sucroalcooleira com a de outros fungos adquiridos em coleção oficial. Os corantes testados revelaram-se ótimos substitutos do Poly R478. O isolado que apresentou atividade descolorante mais intenso do que a do diâmetro de seu crescimento (Cladosporium sp. foi testado, então, em meio líquido frente a dois substratos naturais e um sintético (bagaço de cana, serragem de madeira e azul de metileno. Este removeu altas concentrações de glicídios redutores, proteínas e fenóis totais, além de reduzir a DQO em meio com serragem de madeira como substrato fenólico natural. Tal fungo, portanto, mostrou-se promissor para compor consórcios visando cometabolismo e biorremediação de efluentes nos quais há presença de compostos fenólicos ou outros recalcitrantes com estrutura semelhante à de lignina.Extracellular enzymes of fungi are important for survival in inhospitable environments, as they are able to degrade recalcitrant compounds. Filamentous fungi secrete hydrolases and phenoloxidases that are capable of degrading complexes of aromatic structures, such as certain xenobiotics. The purpose of this study was to test different dyes (methylene blue, Azure B, Malachite Green and Crystal Violet, replacing the compound Poly R478 in the method of selection of phenol decomposer microorganisms in solid medium, and compare this activity

  2. Ligninases production by Basidiomycetes strains on lignocellulosic agricultural residues and their application in the decolorization of synthetic dyes Produção de ligninases por linhagens de fungos Basidiomicetos usando resíduos agrícolas lignocelulósicos e aplicação das enzimas na descoloração de corantes sintéticos

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    Eleni Gomes

    2009-03-01

    . byrsina produziu a maior quantidade de lacase (200 U mL-1 enquanto que Lentinus sp. foi o melhor produtor de manganês peroxidase (MnP e lignina peroxidase (LiP (7 e 8 U mL-1, respectivamente, quando cultivados em meio composto por farelo de trigo. A avaliação do efeito da suplementação de nitrogênio do substrato sólido lignocelulósico (palha de arroz indicou um aumento de 3 a 4 vezes na produção de lacase. A caracterização das enzimas mostrou que as lacases apresentaram atividade ótima em pH 3,0-3,5 e foram estáveis em pH de neutro a alcalino. O pH ótimo para atividade de MnP e LiP foi de 3,5 e entre 4,5 e 6,0, respectivamente. Todas as linhagens produziram lacase com atividade ótima a 55-60°C, enquanto as peroxidases apresentaram atividades máximas entre temperaturas de 30 e 55°C. A aplicação das soluções enzimáticas brutas, obtidas pelo cultivo das linhagens em meio de farelo de trigo, em testes de descoloração de corantes sintéticos de diferentes grupos químicos levou a mais 70% de perda de cor dos corantes RBBR e de cybacron blue 3GA, em 6h de tratamento. Os dados obtidos indicaram que as soluções enzimáticas contendo ligninases produzidas pelas linhagens de basidiomicetos estudadas promoveram a descoloração de corantes sintéticos.

  3. Influence of calcium hydroxide on dyes for dentin labeling, anlyzed by means of a new methodology Influência do hidróxido de cálcio sobre corantes na marcação dentinária, analisada por meio de uma nova metodologia

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    Ivaldo Gomes de Moraes

    2005-09-01

    Full Text Available The objective of this study was to evaluate the influence of calcium hydroxide in intracanal dressing on the ability of the dyes rhodamine B and methylene blue to label the dentine. Forty extracted human mandibular premolars had their canals instrumented and were divided into four groups: in two groups, the canals were filled with a calcium hydroxide paste and the others remained in distilled water. After 15 days, in two groups (with and without dressing, the canals were obturated with sealer containing methylene blue, whereas the others contained rhodamine B. For analysis, the roots were transversally sectioned in their cervical, medium and apical thirds, and the labeling was analyzed. The Mann-Whitney test showed statistically significant difference between the dressing/methylene blue group and the others. Based on these results, it was concluded that calcium hydroxide in intracanal dressing negatively interferes with the labeling ability of methylene blue.Objetivou-se avaliar a influência do curativo intracanal de hidróxido de cálcio sobre a capacidade dos corantes azul de metileno e rhodamine B de marcar a dentina, quando incorporados à massa obturadora, no momento da espatulação. Quarenta pré-molares inferiores humanos extraídos tiveram seus canais instrumentados sendo, então, divididos em quatro grupos. Em dois grupos, os canais foram preenchidos com pasta de hidróxido de cálcio e propilenoglicol por 15 dias. Os outros, permaneceram em água destilada. Após a remoção do curativo, todos os canais foram obturados com condensação lateral e cimento de óxido de zinco e eugenol acrescidos de azul de metileno ou rhodamine B. Assim, em dois grupos (com e sem curativo, os canais foram obturados com cimento contendo azul de metileno e os outros, rhodamine B. Decorridos 15 dias, as raízes foram seccionadas transversalmente nos terços cervical, médio e apical, procedendo-se à análise da marcação, com atribuição de escores

  4. Efeitos do flavonóide quercetina e dos corantes bixina e norbixina sobre parâmetros sanguíneos de coelhos Effects of the flavonoid quercetin and the natural dyes bixin and norbixin on blood parameters of rabbits

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    Leonardo Ramos Paes Lima

    2003-09-01

    Full Text Available Avaliou-se a ação terapêutica da quercetina, bixina e norbixina, na dose diária de 0,01mol/kg, em coelhos hiperlipidêmicos induzidos por colesterol a 0,5% e ácido cólico a 0,1%, durante o período de vinte e oito dias, após o qual foram dosados colesterol, colesterol-HDL, triacilgliceróis, uréia, creatinina, ácido úrico, proteínas totais, cálcio, aspartato aminotransferase e alanina aminotransferase. Estes estudos são importante para se verificarem os efeitos de flavonóides e corantes sobre o metabolismo destas substâncias, permitindo a interpretação de desordens hepáticas ou renais. Os resultados mostraram que os teores de colesterol foram menores para os animais tratados com bixina (-4,03% e quercetina (-35,07%, enquanto sua associação reduziu o nível de uréia em 5,73%. Nenhuma das substâncias testadas apresentou efeitos deletérios, todavia, não é possível demonstrar a inocuidade destes compostos.The objective of this study was to evaluate the therapeutic action of quercetin, bixin and norbixin, in the daily dose of 0,01mol/kg, in hyperlipidemic rabbits induced by cholesterol at 0.5% and colic acid at 0.1%, during the period of twenty-eight days, after which they were anesthetized and samples of blood were collected, in order to determine cholesterol, HDL-cholesterol, triacylglycerols, urea, creatinine, uric acid, total proteins, calcium, aspartate aminotransferase and alanine aminotransferase. These researchs are important to verify the effects of flavonoids and natural dyes on the metabolism of these constituents, in order to study hepatic or renal disorders. The results showed that cholesterol was reduced by bixin (-44.03% and by quercetin (-35.07%, while the association reduced urea in 5.73%. None of the constituents analyzed in this study presented deleterious effects and it was not possible to demonstrate the innocuity of these compounds.

  5. Resíduo da semente de urucum (Bixa orellana L. como corante da gema, pele bico e ovário de poedeiras avaliado por dois métodos analíticos Evaluating of annatto (Bixa orellana L. seeds by-product as yolk, skin, beak and ovary coloring of hens using two analytical methods

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    José Humberto Vilar da Silva

    2006-10-01

    Full Text Available O experimento foi realizado com o objetivo de avaliar o resíduo da semente de urucum (RSU como ingrediente e aditivo corante de diferentes tecidos de 125 poedeiras Lohmann-LSL, com 22 semanas de idade e 1,65 kg de peso vivo, distribuídas num delineamento inteiramente ao acaso em cinco tratamentos com cinco repetições de cinco aves. O tratamento 1 (T1 = ração à base de milho+farelo de soja (M+FS; T2 = ração à base de sorgo (40% + FS; T3 = T2 + 4% RSU; T4 = T2 + 8% RSU e T5 = T2 + 12% RSU. Foram fornecidos 110 g de ração/ave/dia e água à vontade. As coletas foram realizadas em três períodos de 28 dias. A pigmentação dos diferentes tecidos foi avaliada pelo método 1 (M1 do leque colorimétrico da Roche® e, pelo método 2 (M2 do escore "b+", que mede a cor amarela, pelo cromatográfo Minolta® CR-10. Excetuando-se os T1 e T2 da análise de variância, o aumento do RSU na ração com 40% de sorgo melhorou, linearmente, o consumo, produção, massa, conversão alimentar por massa e por dúzia de ovos. A pigmentação da gema analisada pelos M1 e M2, do bico pelo M2 e do ovário pelo M1 melhoraram com o aumento do RSU. Alta correlação (r = 0,72; P A experiment was carried out in the poultry science station of CFT/UFPB with the objective to evalluate the annatto seeds bran (ASB as an ingredient and as an additive colouring of several tissue in 125 hens Lohmann LSL with twenty-two weeks of age, 1.65 kg of live weight, allocated in the completely randomized design, with five treatments and five replication of five hens. The treatment 1 (T1 = diet based on corn and soybean meal; T2 = diet + 40% of sorghum; T3 = T2 + 4% ASB; T4 = T2 + 8% ASB; e T5 = T2 + 12% ASB. The birds were fed 110 g of diet/day and water ad libitum. The collect were obtained in three periods of twenty-eight days. Collor changes were measured with yolk the Roche® collor fan method (M1 and score calculated from "b+" (yellowness of Minolta® CR-10 instrument (M2

  6. Avaliação do tratamento físico-químico e biológico dos resíduos de corantes produzidos em laboratório de microbiologia = Evaluation of the physical-chemical and biological treatment of residue from dyes produced at a microbiology laboratory

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    Lenice Leiko Nozu

    2010-01-01

    Full Text Available Os diferentes resíduos produzidos pelo homem em diversas áreas representam grave problema ambiental, quando inadequadamente descartados. No presente trabalho, foram realizados experimentos de degradação de resíduos de corantes gerados no Laboratório de Microbiologia da Universidade Tecnológica Federal do Paraná, CampusCuritiba, por meio do cultivo líquido implementado com Pleurotus sajor-caju e processo oxidativo avançado (POA – Sistema UV/H2O2. A verificação da eficiência desses processos foi realizada por meio do acompanhamento da redução de cor e dos compostos aromáticos por análise espectrofotométrica em UV-vis, da redução de matéria orgânica (análise de DQO e de bioensaios de toxicidade com Escherichia coli e com sementes de Lactuca sativa. A partir dos resultados obtidos, constatou-se que o processo combinado – cultivo líquido seguido de peroxidação com irradiação ultravioleta, demonstrou ser o tratamento mais eficiente para a redução de cor (90-95% e degradação de aromáticos (16-20%. Os bioensaios revelaram que as amostras do resíduo bruto não inibiram o crescimento da E. coli e mostraram potencial tóxico para a espécie L. sativa, apresentando de 30 a 57% de inibição da germinação das sementes testadas.Palavras-chave: Pleurotus sajor-caju, processo oxidativo avançado, bioensaios de toxicidade.The different types of waste produced by man in several areas represent a serious environmental problem when incorrectly discharged. This work carried out degradation experiments of dye wastegenerated at the laboratory of microbiology of the Federal University of Technology – Paraná State, Campus Curitiba. Assays were performed through liquid culture implemented with Pleurotus sajor-caju and advanced oxidative process (AOP - System UV/H2O2. Efficiency verification of these processes was carried out through monitoringcolor removal and aromatic compounds by spectrophotometric analysis (UV-vis, and also

  7. Ligninolytic enzymes production and Remazol brilliant blue R decolorization by tropical brazilian basidiomycetes fungi Produção de enzimas ligninolíticas e descoloração do corante azul brilhante de Remazol R por fungos basidiomicetos tropicais brasileiros

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    Kátia M. G. Machado

    2005-09-01

    Full Text Available Remazol Brilliant Blue R (RBBR dye was used as substrate to evaluate ligninolytic activity in 125 basidiomycetous fungi isolated from tropical ecosystems. The extracellular RBBR decolorizing activity produced when selected fungi were grown in solid media and in soil contaminated with organochlorines was also evaluated. A total of 106 fungi decolorized the RBBR during the growth in malt extract agar (MEA, 2%; 96 fungi showed a mycelia growth and decolorization activity stronger than the P. chrysosporium used as reference. Extracellular extracts of 35 selected fungi grown on solid medium with sugar cane bagasse (BGS were evaluated for RBBR decolorization and peroxidase activity. All fungi showed peroxidase activities, but 5 of those were unable to decolorize the RBBR. Different patterns of ligninolytic enzymes were detected in 12 fungi extracts. Mn-dependent peroxidase (MnP was produced by Peniophora cinerea, Psilocybe castanella, three strains of Trametes villosa, T. versicolor, Melanoporia nigra and Trichaptum byssogenum. All 12 fungi had laccase activity. Trogia buccinalis showed the highest RBBR decolorization and did not produce MnP activity. RBBR decolorization without MnP production was also observed for three strains of Lentinum tested. Higher levels of peroxidase and laccase cannot be related to high RBBR decolorization. RBBR decolorization by extracellular extract was also detected during the growth of P. castanella, L. crinitus, P. cinerea and two strains of T. Villosa in pentachlorophenol- and hexachlorobenzene-contaminated soils. These fungi showed higher RBBR decolorization when grown in the presence of organochlorine compounds than when in non contaminated soil.O corante azul brilhante Remazol R (RBBR foi usado como substrato para avaliar 125 fungos basidiomicetos isolados de ecossistemas tropicais brasileiros quanto a atividade ligninolítica. A descoloração do RBBR por extratos obtidos do crescimento de fungos em meio sólido e

  8. Desenvolvimento de massa alimentícia fresca funcional com a adição de isolado protéico de soja e polidextrose utilizando páprica como corante Development of functional fresh food adding soy protein isolate and polidextrose using paprika as coloring agent

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    Luz Maria Paucar-Menacho

    2008-12-01

    Full Text Available A tendência do consumidor atual é utilizar alimentos de fácil preparo que, adicionalmente à qualidade nutritiva, tragam benefícios à saúde. Neste trabalho, uma massa alimentícia fresca funcional foi desenvolvida pela incorporação de Isolado Protéico de Soja (IPS e polidextrose, utilizando páprica como corante. O consumo de IPS pode contribuir para a diminuição dos níveis de colesterol, enquanto a polidextrose, funcionando como fibra, pode promover a redução de risco de câncer de cólon. A otimização da formulação foi realizada utilizando-se um delineamento fatorial completo 23, considerando como variáveis independentes os teores de: i IPS; ii polidextrose; e iii páprica. Os efeitos destas variáveis na qualidade da massa alimentícia foram avaliados em função das características físico-químicas (cor e teste de cozimento, textura instrumental e propriedades sensoriais. Na avaliação dos parâmetros físicos, observou-se que a cor instrumental da massa crua foi influenciada apenas pelo teor de páprica; já o tempo de cozimento (2,5 minutos, o aumento de massa (1,40 a 1,64% e a perda de sólidos (3,80 a 5,56% não foram influenciados pelos ingredientes utilizados; e a elasticidade (parâmetro da textura instrumental foi reduzida com o aumento do teor de polidextrose. Na avaliação sensorial da massa crua, o aumento na porcentagem de IPS e a redução na porcentagem de polidextrose afetaram positivamente a aceitação global e a intenção de compra; e os aumentos nas porcentagens de IPS e de páprica aumentaram a aceitação da cor. Na avaliação sensorial da massa cozida, observou-se que o IPS teve influência positiva sobre a textura, enquanto que a polidextrose e a páprica afetaram negativamente este parâmetro. Entretanto, na avaliação da intenção de compra da massa cozida, não houve influência dos ingredientes adicionados. Os percentuais ideais de adição de polidextrose, isolado protéico de soja e p

  9. Technique for the Measurement of Low-Level Radioactivity of Organic Iodine in Large-Volume Urine Samples; Technique de Mesure de la Faible Radioactivite de l'Iode Organique Contenu dans des Echantillons d'Urine de Grand Volume; Metod izmereniya nizkikh aktivnostej organicheskogo joda v krupnykh obraztsakh mochi; Tecnicas de Medicion de Bajas Actividades de Yodo Organico Contenido en Muestras de Orina de Gran Volumen

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    Nicolesco-Zinca, D.; Matei, I. [Institut d' Endocrinologie de l' Academie Roumaine, Bucarest (Romania)

    1965-10-15

    'une dose radioactive au moins 50 fois plus faible que celle qu'exige la methode classique. On peut ainsi separer la diiodotyrosine et la recuperer dans un echantillon de 40-50 ml d'urine (avec une erreur standard de 0,42% dans un laps de temps de quelques heures) en utilisant une installation a cristal a scintillation de Nal(Tl) creux, que l'on trouve couramment dans les laboratoires de medecine nucleaire. (author) [Spanish] La determinacion de la excrecion renal de yodo en forma de compuestos organicos marcados in vitro plantea dos serios problemas en endocrinologia nuclear: a) su separacion cuantitativa del yoduro tambien presente en la orina, incluso cuando la concentracion de este ultimo es veinte veces mayor; b) la determinacion de su debil actividad enmuetras de orina de gran volumen, y que su concentracion por mililitro de orina representa aproximadamente 10{sup -5} de la radiactividad administrada que, a su vez, debe ser lo mas baja posible. La separacion suele efectuarse por cromatografia sobre papel, para lo cual solo se utilizan pequenas muestras de orina. Esta tecnica es laboriosa y exige mucho tiempo y aparatos para cromatografia. Al proceder a la determinacion de la radiactividad sobre el papel, se encuentra una contaminacion de toda la tira. A pesar de las correcciones aplicadas, se recupera solamente el 89,9% de la radiactividad, y atin menos si se emplea un extracto butanolico. Los autores recurren a una tecnica consistente en hacer pasar un gran volumen de orina por una micro- columna de resina cationica en su forma hidrogenada. Los compuestos organicos del radioyodo quedan retenidos en la resina y se determinan midiendo la radiactividad de la columna con una sonda de centelleo de cristal de Nal hueco. Los autores comprobaron que la recuperacion de la diyodotirosina de la orina es practicamente cuantitativa, siendo el error tipo de 0,42% para diez experimentos. El metodo se ha empleado para determinar la desyodacion de la diyodotirosina en 11 pacientes

  10. Chemical Effects of Nuclear Recoil in Organic Halide Systems: A New Theoretical Treatment and Experimental Verification of the Theory; Effets Chimiques du Recul Nucleaire dans des Systemes Organiques Halogenes: Nouveau Traitement Theorique et Verification Experimentale de la Theorie; Khimicheskie vozdejstviya yadernoj otdachi v organicheskikh galoidnykh sistemakh: novoe teoreticheskoe tolkovanie i ehksperimental'noe podtverzhdenie teorii; Efectos Quimicos del Retroceso Nuclear en Sistemas de Haluros Organicos: Nuevo Tratamiento Teorico y Verificacion Experimental de la Teoria

    Energy Technology Data Exchange (ETDEWEB)

    Kontis, S. S.; Sanitwongs, P.; Weston, M. [Londonderry Laboratory for Radiochemistry, University of Durham, Durham (United Kingdom)

    1965-04-15

    mecanisme de la 'boule de billard' pour le marquage par l'atome chaud, auquel Libby a donne son nom, et les retentions sont exprimees en fonction de deux types de parametres, savoir: 1. la probabilite que le choc entre un atome chaud de radiohalogene et une molecule donnee determine la retention de l'atome chaud dans cette molecule; 2. les limites superieure et inferieure des energies pour lesquelles un atome de brome est dit chaud. Les auteurs montrent comment le premier type de parametre peut etre derive d'experiences sur des melanges binaires d'un halogenure organique et de l'halogene libre correspondant; le second type de parametre doit etre deduit des constantes nucleaires et chimiques. Des etudes sur les systemes C{sub 2}H{sub 5}Br/CCl{sub 4}/Br{sub 2} et C{sub 2}H{sub 5}Br/C{sub 6}H{sub 5}Br/Br{sub 2} ont permis de faire l'essai de ces methodes. Les valeurs de retention calculees (en Utilisant des parametres derives d'etudes des systemes C{sub 2}H{sub 5}Br/Br{sub 2}, CCl{sub 4}/Br{sub 2} et C{sub 6}H{sub 5}Br/Br{sub 2}) concordent avec celles qui sont determinees experimentalement dans des melanges ou la fraction molaire de brome est superieure a 0,1 environ. Par consequent, les auteurs considerent que le mecanisme Libby permet d'expliquer les retentions organiques observees dans ces melanges. Lorsque la fraction molaire de brome devient inferieure a 0,1, les retentions observees augmentent progressivement par rapport aux valeurs calculees, ce qui est sans doute du au fait que d'autres modes de marquage par l'atome chaud interviennent lorsque la concentration en brome n'est pas assez elevee pour assurer un bon 'balayage' des radicaux. (author) [Spanish] Los autores elaboraron metodos para calcular la probable retencion organica de los halogenos radiactivos despues de activar con neutrones mezclas de dos haluros organicos y el correspondiente halogeno libre; Los metodos se basan en la teoria del proceso de ' bolas de billar ' de Hbby para la marcacion con atomos

  11. Impacto orcamentario da utilizacao do Metodo Canguru no cuidado neonatal

    Directory of Open Access Journals (Sweden)

    Aline Piovezan Entringer

    2013-10-01

    Full Text Available OBJETIVO Estimar o impacto orçamentário da utilização do Método Canguru na rede municipal de saúde. MÉTODOS Um modelo de decisão analítico foi desenvolvido para simular os custos do Método Canguru e Unidade Intermediária Neonatal no Rio de Janeiro, RJ, em 2011. A população de referência foi constituída pelos recém-nascidos estáveis clinicamente, que podem receber assistência nas duas modalidades de cuidado. O impacto orçamentário foi estimado para uma coorte hipotética de 1.000 recém-nascidos elegíveis em um ano. A proporção de recém-nascidos elegíveis que recebem assistência nas duas modalidades foi obtida por coleta de dados nas maternidades incluídas no estudo. As probabilidades dos eventos e o consumo de recursos de saúde, no período da assistência, foram incorporados ao modelo. Cenários foram desenvolvidos para refletir a adoção do método Canguru em maior ou menor escala. RESULTADOS A utilização do Método Canguru significou redução de gastos equivalente a 16% em um ano, se todos os recém-nascidos elegíveis fossem assistidos por esse método. CONCLUSÕES A opção Método Canguru é de menor custo comparado com a da Unidade Intermediária Neonatal. A análise de impacto orçamentário da utilização desse método no Sistema Único de Saúde indicou economia importante para o período de um ano.

  12. Degradation of air polluted by organic compounds; Degradacion de aire contaminado por compuestos organicos

    Energy Technology Data Exchange (ETDEWEB)

    Santoyo O, E L; Lizama S, B E [Universidad Autonoma del Estado de Mexico, Facultad de Quimica, 56000 Toluca (Mexico); Vazquez A, O; Luna C, P C; Arredondo H, S [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    1999-07-01

    According to the Mexican standard NOM-010-STPS-1994 it has been established concentrations of maximum permissible levels in workable air for styrene in the range 420-1710 mg/m{sup 3} and for xylene between 218-870 mg/m{sup 3}. In this work it is studied a biological treatment (bio filtration) for air polluted by xylene and styrene where the microorganisms are adhered at synthetic fiber, these degrade to the organic compounds that across in gaseous state and they are mineralized toward CO{sub 2} and H{sub 2}O. The characteristics of temperature, p H, concentration of organic compound and mineral parameters, as well as, the biomass quantity have been optimized for that bio filters efficiency were greater than those reported in other works. (Author)

  13. DESNITRIFICACION BIOLOGICA USANDO SUSTRATOS SOLIDOS ORGANICOS NATURALES COMO DONANTE DE ELECTRONES Y FUENTE DE CARBONO

    OpenAIRE

    DEAGO DE LEON, EUCLIDES MANUEL

    2014-01-01

    Los estudios sobre el aprovechamiento de Sustratos Sólidos Orgánicos Naturales (SSON) como fuentes alternativas de carbono orgánico, son importantes para establecer la factibilidad de su aplicación en la desnitrificación del agua. Los estudios sobre la materia indican que es posible usar SSON; sin embargo, aspectos como la liberación del carbono orgánico no está claramente establecido. En este estudio se bordaron los siguientes aspectos (i) factores que controlan la liberación ...

  14. EL PROCEDIMIENTO MONITORIO EN EL NUEVO CODIGO ORGANICO GENERAL DE PROCESO

    OpenAIRE

    Parra Solórzano, Tania de Lourdes

    2016-01-01

    Un avance en el Código Orgánico General de Procesos, es el procedimiento monitorio, este tipo de procesos, permitirá que ciertas causas se tramiten de manera ágil; y, que aquellas deudas de hasta cincuenta salarios básicos unificados que no consten en un título ejecutivo tengan su propia vía procesal. Así cualquier documento que aparezca firmado por un deudor, desde un comprobante de entrega, una cuota de condominio, un canon de arrendamiento, o hasta una remuneración laboral n...

  15. Neutron spectrometry with organic scintillation detector; Espectrometria de nuetrones con cristales de centelleo organicos

    Energy Technology Data Exchange (ETDEWEB)

    Butragueno Casdo, J L

    1972-07-01

    This work describes a fast neutron spectrometer using a stilbene crystal as head detector with pulse shape discrimination (P.S.D.) to reject gamma background. Tre experimental procedure involves the P.S.D., the measurements to calibrate the spectrometer and the corrections for several factors, mainly the non-linear response of the stilbene. Results of the measurements with the reaction D{sup 2}(d,n)He{sup 3}, and with an Am-Be neutron source are presented. It is also presented the measurement of the spectrum of the fast reactor CCRAl-1. (Author) 17 refs.

  16. Characterization of radioactive organic liquid wastes; Caracterizacion de desechos liquidos organicos radiactivos

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez A, I.; Monroy G, F.; Quintero P, E.; Lopez A, E.; Duarte A, C., E-mail: ivonne-arce@hotmail.com [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2014-10-15

    With the purpose of defining the treatment and more appropriate conditioning of radioactive organic liquid wastes, generated in medical establishments and research centers of the country (Mexico) and stored in drums of 208 L is necessary to characterize them. This work presents the physical-chemistry and radiological characterization of these wastes. The samples of 36 drums are presented, whose registrations report the presence of H-3, C-14 and S-35. The following physiochemical parameters of each sample were evaluated: ph, conductivity, density and viscosity; and analyzed by means of gamma spectrometry and liquid scintillation, in order to determine those contained radionuclides in the same wastes and their activities. Our results show the presence of H-3 (61%), C-14 (13%) and Na-22 (11%) and in some drums low concentrations of Co-60 (5.5%). In the case of the registered drums with S-35 (8.3%) does not exist presence of radioactive material, so they can be liberated without restriction as conventional chemical wastes. The present activities in these wastes vary among 5.6 and 2312.6 B g/g, their ph between 2 and 13, the conductivities between 0.005 and 15 m S, the densities among 1.05 and 1.14, and the viscosities between 1.1 and 39 MPa. (Author)

  17. Uso de cuatro extractos organicos para el control del pulgon verde (Myzus persicae Sulz) (ING)

    OpenAIRE

    Rodríguez Navas, Hernán; Blanco, Fabio A.

    2016-01-01

    Extracts of leaves and stems of Neurolaena lobata; leaves, stems and fruits of Momordica charantia, wood of Quassia amara and seeds of Annona muricata, were tested regarding their effectiveness for control of green peach aphid (Myzus persicae). In a first stage, groups of 10 individuals of M. persicae were placed inside petri dishes together with a small and slight piece of synthetic cloth soaked with either substance extracted. Several concentrations were used. After two hours; more than 50%...

  18. Biodigestor for organic waste gas; Biodigestor para o gas do lixo organico

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Carla Miranda; Fernandes, Carla Barbosa; Souza, Aline Vieira da Silva e; Melo, Cibelly Caroliny Santos; Sales, Jefferson Santos; Frade, Marcelo Lorenzo; Machado, Marcus Vinicius; Frade, Matheus Costa; Gomes, Natashua Lauar; Costa, Pedro Henrique de Andrade; Moraes, Rodrigo de Almeida; Estrella, Thales Goncalves; Lima, Miriam Cristina Pontello Barbosa [Centro Universitario de Belo Horizonte (UniBH), MG (Brazil)], e-mails: carlam.ferreira@yahoo.com.br, miriam.pontello@gmail.com

    2011-07-01

    This article to present an alternative reuse os the gas produced by garbage, through the construction of a digester, with a view to preserving the environment through renewable energy. The energy produced by this system is obtained from the decomposition of organic waste is biogas, made up of gases such as methane (CH{sub 4}) and carbon dioxide (CO{sub 2}). This experiment verifies the possibility of using methane gas as an alternative to the operation of a domestic stove. (author)

  19. Uso de cuatro extractos organicos para el control del pulgon verde (Myzus persicae Sulz (ING

    Directory of Open Access Journals (Sweden)

    Hernán Rodríguez Navas

    2016-03-01

    Full Text Available Extracts of leaves and stems of Neurolaena lobata; leaves, stems and fruits of Momordica charantia, wood of Quassia amara and seeds of Annona muricata, were tested regarding their effectiveness for control of green peach aphid (Myzus persicae. In a first stage, groups of 10 individuals of M. persicae were placed inside petri dishes together with a small and slight piece of synthetic cloth soaked with either substance extracted. Several concentrations were used. After two hours; more than 50% of the individuals had been killed in every petri dish, which allowed all extracts to pass on to the second stage. The second stage consisted of two experiments. The first one was done in spring at a greenhouse day temperature of 10°C,  using only the first three substances, each of them diluted 1:100. The second one was conducted in Summer at about 25°C with the four substances. Distilled water acted as a control in both experiments. Tobacco plants (Nicotiana tabacum infested with M. persicae were sprayed with the solutions and survivors counted 24 and 72 hours later. In the first experiment Q amara  and M. charantia had 78% and 77% effectiveness respectively, which were statiscally (P< 0.05 higher than that of N. lobata  (63%. In the second experiment, because of the warmer weather, they improved their performance, specially N. lobata (98%. This and A. muricata were found statistically (P< 0.05 higher than the others.

  20. Secagem convectiva de papel reciclado com incorporação de corantes naturais

    OpenAIRE

    Néstor David López González

    2012-01-01

    Resumo: O papel está presente em muitas das atividades do cotidiano que vão desde usos sanitários, passando pelas embalagens até fins educativos. Este material que teve sua origem há quase 2000 anos, continua sua evolução na procura de alternativas limpas para seu reaproveitamento. Novos processos de reciclagem, secagem e a incorporação de materiais alternativos para melhorar as propriedades do papel fazem desta área de pesquisa a base para a criação de novas tecnologias e produtos com apelo ...

  1. Transferência de energia entre corantes catiônicos em sistemas homogêneos

    Directory of Open Access Journals (Sweden)

    Oliveira Hueder Paulo Moisés de

    2003-01-01

    Full Text Available In this work, the energy transfer by dipole-dipole interaction between cationic dyes in n-alcohols (methanol, ethanol, 1-propanol and 1-butanol is studied by time resolved and steady state fluorescence measurements. The critical radii of energy transfer were determined by three independent methods; the spectral overlap, fluorescence decay profiles, and relative intensity measurements. In all solvents, R0 values of the dye pairs obtained from spectral overlap were between 40 to 90 Å. Steady state and time resolved fluorescence measurements resulted in values of R0 in the range of 50 - 80 Å, with good correlation of values.

  2. Radiation damages in chemical components of organic scintillator detectors; Danos de radiacao em componentes quimicos de detectores cintiladores organicos

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes Neto, Jose Maria

    2003-07-01

    Samples containing PPO (1%, g/ml), diluted in toluene, they were irradiated in a {sup 60}Co irradiator (6.46 kGy/h) at different doses. The PPO concentration decay bi-exponentially with the dose, generating the degradation products: benzoic acid, benzamide and benzilic alcohol. The liquid scintillator system was not sensitive to the radiation damage until 20 kGy. Otherwise, the pulse height analysis showed that dose among 30 to 40 kGy generate significant loss of quality of the sensor (liquid scintillating) and the light yield was reduced in half with the dose of (34.04 {+-} 0.80) kGy. This value practically was confirmed by the photo peak position analysis that resulted D{sub 1/2} = (31.7 {+-} 1,4) kGy, The transmittance, at 360 nm, of the irradiated solution decreased exponentially. The compartmental model using five compartments (fast decay PPO, slow decay PPO, benzamide, benzoic acid and benzilic alcohol) it was satisfactory to explain the decay of the PPO in its degradation products in function of the dose. The explanation coefficient r{sup 2} = 0.985636 assures that the model was capable to explain 98.6% of the experimental variations. The Target Theory together with the Compartmental Analysis showed that PPO irradiated in toluene solution presents two sensitive molecular diameters both of them larger than the true PPO diameter. >From this analysis it showed that the radiolytic are generated, comparatively, at four toluene molecules diameter far from PPO molecules. For each one PPO-target it was calculated the G parameter (damage/100 eV). For the target expressed by the fast decay the G value was (418.4 {+-} 54.1) damages/100 eV, and for the slow decay target the G value was (54.5 {+-} 8.9) damages/100 eV. The energies involved in the chemical reactions were w (0.239 {+-} 0.031) eV/damage (fast decay) and w = (1 834 {+-} 0.301) eV/damage (slow decay). (author)

  3. Emissions control of volatile organic compounds in petroleum industry; Controle de emissoes de compostos organicos volateis na industria do petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Gutierres, Ricardo; Moreira, Andrea Cristina de Castro Araujo [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES). P e D de Energia e Desenvolvimento Sustentavel (PDEDS)

    2004-07-01

    Volatile organic compounds are among the most common pollutants emitted by refining processes. The sources of these emissions should be controlled for preserving the ambient air quality. This article outlines the main factors to be considered for defining an effective emissions control strategy and compares the major characteristics of the available control technologies. (author)

  4. Obtaining organic fertilizer from olive oil; Obtencion de un abono organico a partir de orujo de aceituna

    Energy Technology Data Exchange (ETDEWEB)

    Criado, A.; Benitez, C.; Gonzalez, J. L.

    2004-07-01

    A method to obtain suspended fertiliser from two-step olive oil mill process wastes (alperujo) is shown. For it, an extraction with KOH to pH=13 from this by-products is taken, and later neutralisation with nitric acid HNO{sub 3} to pH=7.5 and with phosporic acid H{sub 3}PO{sub 4} to pH 6.5. The fertiliser obtained contains the humic fraction extracted, and show Nitrogen, Phosphorous and Potassium contents of 0.8-1%, 0.5-0.8%, 3-4%, respectively and a density of d=1,18 g/cm''3, and may be used as raw material to manufacture other organo-mineral fertilisers. (Author) 11 refs.

  5. Use of maze in cyclotron hoppers; Utilizacao de labirinto em bunker de ciclotron

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes, Fernando A.; Alves, Juliano S.; Fochesatto, Cintia; Cerioli, Luciane; Borges, Joao Alfredo; Gonzalez, Delfin; Silva, Daniel C., E-mail: fernandofernandes@biofarmaco.com.br [Delfin Farmacos e Derivados (Biofarmaco Marcadores Moleculares), Lauro de Freitas, BA (Brazil)

    2013-07-01

    Introduction: the increasing number of cyclotrons in Brazil due to constitutional amendment 49 /06 that enabled the production of radiopharmaceuticals with a short half - life by private companies. The radionuclides used for PET - CT require production centers near or within the diagnostic centers. In order to minimize maintenance and operating risks, gaining efficiency, our facility was the first in Brazil to use the access to a cyclotron bunker via maze, rather than armored door stopper type. Materials: the design calculations were based on the Monte Carlo method (MCNP5 - Monte Carlo N-Particletransportcode version 5). At the ends of the labyrinth are installed a door of polyethylene, for thermalization of neutrons, and other of wood for limiting access. Both legs of the maze have wall thickness of 100cm. In inspection Brazilian CNEN realize measures of dose rate for neutrons and gamma 9 points: 7 around the bunker, 1 over the bunker and 1 in the exhaust with the cyclotron operating with maximum load, double beam of 50uA for 2 hours. After commissioning were carried out around the bunker, the following measures: cumulative dose in three months with dosimeters for neutron rate dose with a gas proportional detector type filled with {sup 3}He and polyethylene neutron moderator and dose rate with a Geiger - Mueller detector for gamma radiation. Readings with neutron detectors were classified as background radiation and dose rates were always below the limits established in standard EN 3.01, and the calculation of the predicted regardless of the intensity of irradiation inside the bunker. Conclusion: the use of labyrinths as a way to access the bunkers cyclotron has been shown to be effective as the radiation shielding and efficient by allowing quick and easy access, virtually eliminating the maintenance.

  6. Brazilian bentonite study: use in Goiania; Estudo das bentonitas nacionais: utilizacao em Goiania

    Energy Technology Data Exchange (ETDEWEB)

    Tello, Cledola Cassia Oliveira de [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN), Belo Horizonte, MG (Brazil)

    1997-12-31

    The evaluation of the bentonite effect in the waste cementation process and in the final solidified product properties is presented. The research showed that bentonite amounts until 15% in the product improves the caesium retention without jeopardizing the other product properties. These results were very useful in the treatment of the wastes from the radiological accident occurred in Goiania in 1987, when a caesium sources was broken. Paste, mortar and grout with bentonite were used to solidify and immobilize these wastes. (author) 20 refs., 1 fig., 6 tabs.; e-mail: tellocc at urano.cdtn.br

  7. Utilization of alternatives fuels in a fluvial convoy; Utilizacao de combustiveis alternativos em um comboio fluvial

    Energy Technology Data Exchange (ETDEWEB)

    Padovezi, Carlos D; Giraldo, Arnaldo

    1987-12-31

    This work presents the results of tests performed with ethanol and methanol in a fluvial convoy in Tiete river, Sao Paulo State - Southeast Brazil. It also outlines a comparison and evaluation methodology. 9 figs., 3 tabs.

  8. The case of royalties in utilizations contracts; O caso dos royalties nos contratos de utilizacao

    Energy Technology Data Exchange (ETDEWEB)

    Manoel, Cacio Oliveira; Santos, Edmilson Moutinho dos [Universidade de Sao Paulo (USP), SP (Brazil). Escola Politecnica. Programa Interunidades de Pos-Graduacao em Energia

    2004-07-01

    This paper aims to discuss issues related to royalties payment in cases of oil and natural gas fields unitization. Those case were already registered in Brazil although the generic legislation regulating royalties payment does not contemplating them specifically. The contractual concepts of fields unitization are initially presented, highlighting the difficulties of implementing those contractual models and including the discussion regarding royalties payment. The doctrinal understanding of royalty is considered to demonstrate the possible difficulties that unitizations contracts impose for those royalties payment in the Brazilian legislation. In the end, the authors suggest exploring ideas for solving the issues raised by paper. (author)

  9. Utilization of alternatives fuels in a fluvial convoy; Utilizacao de combustiveis alternativos em um comboio fluvial

    Energy Technology Data Exchange (ETDEWEB)

    Padovezi, Carlos D.; Giraldo, Arnaldo

    1986-12-31

    This work presents the results of tests performed with ethanol and methanol in a fluvial convoy in Tiete river, Sao Paulo State - Southeast Brazil. It also outlines a comparison and evaluation methodology. 9 figs., 3 tabs.

  10. Hybrid repowering of transformers using aramids; Repotenciacao hibrida de transformadores com utilizacao de aramida

    Energy Technology Data Exchange (ETDEWEB)

    Neri Junior, Almir Laranjeira; Correia, Fidelis Botelho [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil)

    2010-01-15

    Santiago substation of the PETROBRAS, operated with two transformers fabricated in 1971. To preserve the reliability of power supply, it was relaborated a reformation and repowering project of the equipment using aramids, a special polymeric material. This paper describes the phases of the project, and presents the benefits obtained, and also the characteristics of the electric system of the production unit. (author)

  11. Smart timer for use in air purifiers; Temporizador inteligente para utilizacao em depuradores de ar

    Energy Technology Data Exchange (ETDEWEB)

    Marcelino, M.A.; Escudeiro, G.A. [Universidade Estadual Paulista (FEG/UNESP), Guaratingueta, SP (Brazil). Faculdade de Engenharia], Emails: abud@feg.unesp.br, gui_paulista@yahoo.com.br

    2009-07-01

    Currently, the air cleaner Suggar appliances has a key of three positions of different speeds, in addition to the off position. The motor has three windings, each one is responsible for a winding speed. The speed choice is made through the key. The objective of this work is the replacement of this motor with three windings by a single motor winding, with the velocity controlled electronically, and no longer using the key, lowering the costs of product. A signalling was implemented, through a diode LED, informing the user the end of the useful life of the debugger filter, in order to make possible the replacement at the right time, avoiding waste for the product user. The electronic system should be able to control the speed of engine and to count a total of 100 hours of operation of the debugger. When this is achieved, a signal is triggered on the front panel of product, indicating the need for replacing the filter. A key to reset the timer will used to reset the count after a filter change. To avoid the time counting due to the energy lack it is used an EEPROM memory to storage the counting. The control system counting is done by the PIC12F629 microcontroller.

  12. Effects of the ionizing radiation in natural food colours; Efeitos da radiacao ionizante em corantes naturais de uso alimenticio

    Energy Technology Data Exchange (ETDEWEB)

    Cosentino, Helio Morrone

    2005-07-01

    The world's fast growing population and its consequent increase in demand for food has driven mankind into improving technologies which ensure a safer supply of such commodities. Both food radiation processing and its constituents are highlighted as a feasible alternative technique capable of meeting food safety standards. Natural dyes are extensively employed in the food industry thanks to their colour enhancing properties on food products. This paper has aimed at studying the effects of ionizing radiation on three natural dyes: carminic acid and its derivatives (cochineal dyes), bixine and its salts (annatto dyes) and curcumin (turmeric dyes), used in the food and cosmetic industries within dilutions and doses those goods might eventually be processed in. It also envisages clarifying the compatibility of the irradiation technique with the keeping of such relevant sensorial attribute which is the product colour. Spectrophotometry and capillary electrophoresis were the analytic methods employed. All in all, a colour decrease proportional to the increase on the applied gamma radiation (1 to 32 kGy) has been observed. The annatto dyes have proven moderately stable whereas turmeric has shown to be highly sensitive to radiation. Those results shall be taken into account as far as the need to alter the formulae additive amount in the product is concerned whenever undergoing radiation processing. (author)

  13. The using of aeolian energy in air circulators; A utilizacao da energia eolica em circuladores de ar

    Energy Technology Data Exchange (ETDEWEB)

    Assuncao Filho, Telesforo Reis de

    2003-07-01

    The present work is a theoretical research on how to take advantage of the wind kinetic energy using a rotor type Savonius, doing the conversion in mechanical energy, through the fan utilization aiming a thermal comfort and beginning with an introduction on the aeolian energy, its utilization and objectives. Several local types and behavior influenced by the air mass mechanics are shown. A statistic of these air masses and a brief study of the aeolian turbines, its characteristics and design, advantages and disadvantages are presented. An experimental analysis in Sao Luis region were done, using the wind frequency with the objective of obtaining a good revenue. The characterization of the main types of rotors used nowadays are presented, too. (author)

  14. Solar energy uses in home water heating systems; Utilizacao da energia solar em sistemas de aquecimento de agua residencial

    Energy Technology Data Exchange (ETDEWEB)

    Basso, Luiz Henrique

    2008-07-01

    The awareness of the importance of the environment has stimulated the study of new energy sources renewed and less pollutant. Amongst these sources, solar energy stands alone for being perennial and clean. The use of solar energy in systems of residential water heating, instead of the electric shower, can compliment the economy of electric energy, based on the Brazilian energy matrix. To know all the factors that influence the operation of a system of water heating by solar energy it is important the determination of its economic and technical viabilities and, distribution targeting in urban and agricultural residences. To evaluate equipment of water heating for solar energy in the region west of the Parana, Brazil, an archetype with similar characteristics to equipment used in residences for two inhabitants was built, to function with natural circulation or thermosyphon and without help of a complementary heating system. The room temperature and the speed of the wind were also evaluated, verifying its influence in the heating system. The equipment revealed technical viability, reaching the minimum temperature of 35 deg C for shower, whenever the solar radiation was above the 3500 W.m{sup -2}, for the majority of the studied days. The system operated without interruptions and it did not need maintenance, except for the monthly glass cleaning. Economic viability was clearly demonstrated since the useful life of the equipment exceeded the period of use to gain its investment. (author)

  15. Using radioactive tracers for the evaluation of industrial equipment; Utilizacao de tracadores radioativos na avaliacao de equipamentos industriais

    Energy Technology Data Exchange (ETDEWEB)

    Brandao, Luis Eduardo Barreira; Sa, Lidia Vasconcellos de; Sousa, Alvaro Serafim F. de [Instituto de Engenharia Nuclear (IEN/CNEN-RJ), Rio de Janeiro, RJ (Brazil)

    2000-07-01

    This paper presents the radioactive tracer technique, giving as example some cases of the possible utilization developed by the Nuclear Engineering Institute, RJ, BR (Argonaut reactor) and through charged particle (CV-28 cyclotron), and also his production and aspects of radiological safety.

  16. Characterization of granite waste for use in red ceramic; Caracterizacao de residuo de granito para utilizacao em ceramica vermelha

    Energy Technology Data Exchange (ETDEWEB)

    Aguiar, M.C.; Monteiro, S.N.; Vieira, C.M.F., E-mail: mari@uenf.br [Universidade Estadual do Norte Fluminense (UENF/LAMAV), Campos dos Goytacazes, RJ (Brazil). Laboratorio de Materiais Avancados; Borlini, M.C. [Centro de Tecnologia Mineral (CETEM), Cachoeiro de Itapemirim, ES (Brazil). Centro Avancado

    2011-07-01

    This work aims to study the characterization of the granite waste from the city of Santo Antonio de Padua-RJ for the use in red ceramic. The chemical, physical and morphological characterization of the waste was performed by chemical analysis, X-ray diffraction, particle size distribution, thermal analysis and scanning electron microscopy (SEM). The results indicated that this waste is a material with great potential to be used as a component of ceramic body due to its capacity to act as flux during the firing, and to improve the properties of the ceramic when is incorporate. (author)

  17. Study on the natural gas utilization in the ceramic industry; Estudo sobre a utilizacao do gas natural na industria ceramica

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-07-01

    The production, principal applications, characteristics and properties, advantages of the gas natural is showed. A sectorial overview of the ceramic industry and the utilization of the natural gas in the ceramic industry is presented. The expectations are systematized and the impact of the natural gas utilization in the ceramic industry is evaluated. Some conclusions are withdrawn and recommendations suggested.

  18. Using microwave for processing nanostructured PZT ceramics; Utilizacao de microondas no processamento de ceramicas nanoestruturadas de PZT

    Energy Technology Data Exchange (ETDEWEB)

    Lanza, A.C.; Berti, T.G.; Thomazini, D.; Gelfuso, M.V., E-mail: lanza.work@gmail.com [Universidade Federal de Itajuba (UNIFEI), MG (Brazil). Instituto de Engenharia Mecanica; Eiras, J.A. [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil). Dept. de Fisica

    2012-07-01

    The PZT ceramics have dielectric and piezoelectric properties of technological interest. The method of microwave assisted hydrothermal synthesis becomes interesting since it occurs in a closed environment, the low temperature and time, compared to conventional methods. In this work, PZT powders were dissolved in acid medium, and by adjusting the pH of the solutions obtained were precipitated, subjected to hydrothermal treatment at 120 °C for intervals of 15, 30 and 60 min. The powders were characterized by differential thermal and gravimetric analysis, X-ray diffraction and scanning electron microscopy. The results confirm the formation of PZT phase in one hour with particle size around 55 nm, showing the feasibility of the proposed method. (author)

  19. Use of biogas for cooling and drying of vegetables; Utilizacao de biogas para resfriamento e secagem de hortalicas

    Energy Technology Data Exchange (ETDEWEB)

    Pacco, Honorato Ccalli; Cortez, Luis Augusto Barbosa [Universidade Estadual de Campinas (FEA/UNICAMP), SP (Brazil). Fac. de Engenharia de Alimentos. Lab. de Refrigeracao; Neves Filho, Lincoln de Camargo; Jordan, Rodrigo Aparecido [Universidade Estadual de Campinas (FEAGRI/UNICAMP), SP (Brazil). Fac. de Engenharia Agricola. Lab. de Termodinamica e Energia; Baldassin, Junior, Ricardo [Universidade Estadual de Campinas (FEM/UNICAMP), SP (Brazil). Fac. de Engenharia Mecanica

    2006-07-01

    The European Union established a global goal of 8% reduction in the emission of greenhouse gases up to 2012. In 2010, 12.5% of the energy in the Europe should come from renewable sources, being that biogas will be able to come to represent about 10% of these sources. Up to 2020 it is foreseen substitution of 20% of the conventional sources for alternative fuels. Biogas is pointed as an environmentally competitive alternative, Neves Filho et al., (2001). With the biodigesters, the agricultural producer can transform animal and vegetal debris into an excellent energy alternative, besides getting a powerful organic fertilizer. The project consist of the installation of a biogas collection system that would serve as fuel to move an Otto cycle engine power and thus trigger the heat pump. This integrated use will allow to use the potentiality that has the heat pump to generate energy for cooling and heating, and to reduce use of electric power in rapid cooling of tomatoes after harvesting and in drying of mature tomatoes. (author)

  20. Artificial intelligence utilization in power generation units control systems; Utilizacao de inteligencia artificial em sistemas de controle de unidades geradoras

    Energy Technology Data Exchange (ETDEWEB)

    Souza, G N [CEPEL, Rio de Janeiro, RJ (Brazil); Mendes, S B [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia

    1992-12-31

    To the implementation of the logics of control in a hydroelectric power plant artificial languages or complexes formalisms are used which cause error introduction in the description process of such logic. This work suggests the use of an intelligent and interactive system with interface in natural language to the control description as a solution to this problem. 28 refs., 3 figs.

  1. Structural characterization of bentonite clays for utilization as nanofillers in nanocomposites; Caracterizacao estrutural de argilas bentoniticas para utilizacao como nanocargas

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Carlos Ivan Ribeiro de; Rocha, Marisa Cristina Guimares; Vogas, Arthur Considera, E-mail: carlosivanr@gmail.com [Universidade do Estado do Rio de Janeiro (UERJ), Nova Friburgo, RJ (Brazil). Instituto Politecnico; Silva, Ana Lucia Nazareth da [Universidade Federal do Rio de Janeiro (IMA/UFRJ), RJ (Brazil). Instituto de Macromoleculas Professora Eloisa Mano; Bertolino, Luiz Carlos [Centro de Tecnologia Mineral (CETEM/MCTI), Rio de Janeiro, RJ (Brazil)

    2014-07-01

    Clays of different composition have been used in the development of polymer nanocomposites. However, the utilization of bentonite clays has been emphasized in Brazil, mainly due to their availability.The best known and studied deposits of bentonite clays are located in the state of Paraiba. However, these deposits are becoming exhausted after decades of exploitation. In this context, the aim of this work is to proceed the physical-mineralogical characterization of bentonite clays recently discovered in Cubati, PB. In order to achieve this objective, the samples underwent a particle size classification step and were characterized by X-ray fluorescence, X-ray diffraction, infrared spectroscopy, thermal analysis and scanning electron microscopy. Results of X-ray diffraction showed that the samples are composed of smectite, and kaolinite and quartz. The characterization of the samples by FTIR confirmed these results. Results of chemical analysis showed that the clays have predominantly different exchangeable cations. (author)

  2. Artificial intelligence utilization in power generation units control systems; Utilizacao de inteligencia artificial em sistemas de controle de unidades geradoras

    Energy Technology Data Exchange (ETDEWEB)

    Souza, G.N. [CEPEL, Rio de Janeiro, RJ (Brazil); Mendes, S.B. [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia

    1991-12-31

    To the implementation of the logics of control in a hydroelectric power plant artificial languages or complexes formalisms are used which cause error introduction in the description process of such logic. This work suggests the use of an intelligent and interactive system with interface in natural language to the control description as a solution to this problem. 28 refs., 3 figs.

  3. Application of aluminum slag incorporated in lightweigh aggregate; Utilizacao da escoria de aluminio na fabricacao de argila expandida

    Energy Technology Data Exchange (ETDEWEB)

    Takahashi, Elisa Akiko Nakano

    2006-07-01

    The use of industrial waste materials as additives in the manufacture of ceramic product has been attracting a growing interest in the last few years and is becoming common practice. The main purpose of this work is to evaluate the possibility of incorporation of aluminum slag into clay materials. Expansive clays are obtained from a pyro plastic expansion, and are usually employed like lightweight aggregate in structural concrete as ornamental garden products. The characterization of the aluminum slag and clay materials was carried out by Xray fluorescence spectrometry, Xray diffraction, granulometry, differential thermal analysis, thermal gravimetry (DTA and TG) and scanning electron microscopy. The studied compositions contained 5, 10, 15 and 20 weight % of aluminum slag into clay mass. The linear expansion, mass variation, apparent specific mass and water absorption of all compositions were determined. Leaching and solubilization experiments were also performed. The main results show the viability of using up to 5 wt% aluminum slag for producing expansive clays with characteristics within the accepted standards. (author)

  4. Potential of energetic utilization of grains residual biomass; Potencial de utilizacao energetica de biomassa residual de graos

    Energy Technology Data Exchange (ETDEWEB)

    Mourad, Anna L. [Instituto de Tecnologia de Alimentos (ITAL), Campinas, SP (Brazil). Centro de Tecnologia de Embalagem], e-mail: anna@ital.sp.gov.br; Ambrogi, Vinicius S.; Guerra, Sinclair M.G. [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Fac. de Engenharia Mecanica], e-mail: ambrogi@fem.unicamp.br, e-mail: sguerra@fem.unicamp.br

    2004-07-01

    The biomass resulting from the rejected parts of grains, as straw and peel of rice, corn, wheat, soy, all great cultivations in the country, has potential to be takes advantage as energy. It was considered that the contribution of this residual biomass is near of 167,8 million GJ/year, value that could be added to the use already established of the cane bagasse for energy purpose (658 million GJ, in 2001). This energy can be used for drying of these same grains (energy expense estimate of 67 million GJ), currently obtained from oil. It can also substitute the fuel oil used in the agricultural section, in the industries of food and beverage, ceramic and textile (sections that consumed 67.822 GJ in 2001). In Sao Paulo state the regions with greater potential to install biomass plants are located in Assis, Avare and Itapeva EDR (regional development office). (author)

  5. Utilization of parabolic solar collector in wood drying; Utilizacao de coletor solar parabolico na secagem de madeira

    Energy Technology Data Exchange (ETDEWEB)

    Souza Mendes, Alfredo de

    1986-12-31

    This study was concerned to concept, to project and to build a parabolic solar collector as a generation source of thermic energy to the conventional drying of wood, jointed to a drying environment and to evaluate its efficiency. In this sense, prototypes of a solar collector and a conventional dry kiln were built. The collector with linear focus, was provided with a solar photoelectric tracking system. The dry kiln had semiautomatic control of temperature and a capacity to dry 0,3 m deg 3 of wood. All the steps of the construction of the system are presented with details. (author). 14 figs., 8 tabs., 73 refs

  6. Solar thermal energy utilization in Brazil: a perspective; Utilizacao da energia solar termica no Brasil: uma perspectiva

    Energy Technology Data Exchange (ETDEWEB)

    Miller, Francisco Mateus [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2004-07-01

    Although Brazil has a large insolation potential, utilization of solar thermal energy is still limited to few applications, like residential and commercial water heating and drying of grains. However, there are in other countries more intensive applications, like electricity generation, industrial heat and fresh water production. The present work describes which are the other ways of using solar thermal energy that have been developed in the world, approaches the main technical aspects that affect its utilization, the perspective of increasing it in Brazil and its possible barriers and, finally, PETROBRAS' studies in this area, positioning itself as an Energy Company. The main solar thermal technologies currently used in the world are evacuated collectors, that work efficiently at temperatures up to 130 deg C, and concentrating solar technologies, that can reach the temperature of 1200 deg C. Among the latter, solar trough is the technology that is already considered mature, and near to become economically viable. Brazil, at the moment, has two technological challenges: development of national technology to manufacture high performance solar collectors, like evacuated collectors and solar troughs, and the development of thermal equipment to operate at temperatures under 120 deg C, like adsorption and absorption chillers and desalination towers, that can be economically competitive. (author)

  7. Natural gas use in treatment of steel surfaces; Utilizacao de gas natural em tratamento de superficies de aco

    Energy Technology Data Exchange (ETDEWEB)

    Ferraz, Andre Dias; Machado, Antonio Rogerio; Rocha, Ivan; Azevedo, Jorge; Oshiro, Hugo K.; Konishi, Ricardo; Lehmkuhl, Willian [Companhia de Gas de Santa Catarina (SCGAS), Florianopolis, SC (Brazil); Piazza, Walter [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2011-12-21

    The surface treatments of metals, such as carburizing, rely on processing under high temperature in carbon rich atmospheres. The atmosphere is industrially generated using the partial oxidation of a carbon rich fuel, such as propane, butane or methanol. This article reports a study of the production of a carburizing atmosphere for surface treatment of steel from the partial oxidation of natural gas in a catalytic reactor. The reactor studied was a production size reactor with 300 mm of diameter and 1500 mm of length, packed with alumina supported nickel catalyst. The quality of the carburizing gas was evaluated from its carbon potential of the carburizing gas that was calculated from the concentrations of carbon monoxide (CO), carbon dioxide (CO{sub 2}), oxygen (O{sub 2}) and methane (CH{sub 4}) measured at the reactor's exit. The results indicate that CO concentration is very close to equilibrium, while CO{sub 2} is higher and CH{sub 4} is lower. Examining the reactor, the conclusion was that there was an axial temperature gradient, resulting in lower residence time under the required processing temperature. This resulted in smaller decomposition of CH{sub 4} and smaller production of CO{sub 2}. An equilibrium calculation of carbon potential, expressed as weight percent of carbon in iron, was developed to predict the possible optimizations of mixture composition and reactor temperature for a given required carbon potential. Conclusion: it is possible to generate a carburizing atmosphere under well controlled and repeatable conditions for the carbon potentials required for surface carburizing of steels in industrial processing using natural gas and air mixtures. (author)

  8. Application of thermoelectric generator as an alternative energy source; Utilizacao dos geradores termoeletricos como fonte de energia alternativa

    Energy Technology Data Exchange (ETDEWEB)

    Pepino, Giovana [Newmar Energia, Rio de Janeiro, RJ (Brazil)

    2004-07-01

    This document will deal some information about the TEG and design of TEGs. Thermoelectric energy conversion is a solid state process that converts heat energy to electrical energy without moving parts. The result is a device that is characterized by a very high degree of reliability and low maintenance requirement. These characteristics lend the unit to service in remote areas where limited access is available fore service. Technicians that service the other equipment on location can be trained to service the thermoelectric generator. There are many other uses for TEGs including power supplies for supervisory control and data acquisition systems. (author)

  9. XPS utilization in the characterization of glycerol based polyesters; Utilizacao de XPS na caracterizacao de poliesteres a base de glicerol

    Energy Technology Data Exchange (ETDEWEB)

    Brioude, M.M.; Miranda, C.S.; Pereira, R.; Ohara, L.; Bargiela, P.; Rocha, M.G.M.C.; Jose, N.M., E-mail: mgcr@ufba.b [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Escola Politecnica. Inst. de Quimica

    2010-07-01

    X-ray photoelectron spectroscopy-XPS allows the determination of all elements of the periodical table, except hydrogen and helium, and is a very used technique for the polymers characterization, its spectra constitutes a 'fingerprint' of the material. Two samples of polymers were prepared from glycerol and fumaric acid and glycerol and terephthalic acid, with a molar ratio of 1:1 and 1:1.5. The general spectra show the presence of carbon and oxygen, the main components of the polymer. From the binding energies values of the C1s and O1s high resolution spectra it was possible to determine the carbon functional groups. Their concentration were determined and the presence of the aromatic carbon in the terephthalic polyesters was observed, and also similar proportions of aliphatic carbon and ester groups in the fumaric acid polyesters. For both polyesters, an amount of carboxyl group appears, indicating the terminal non-reacted groups. These results were confirmed qualitatively by FTIR. (author)

  10. Teflon pastille use in high dose dosimetry; Utilizacao de pastilhas de teflon em dosimetria de doses altas

    Energy Technology Data Exchange (ETDEWEB)

    Teixeira, Maria Ines [Associacao Educacional Nove de Julho (UNINOVE), Sao Paulo, SP (Brazil); Caldas, Linda V.E., E-mail: miteixeira@ipen.b, E-mail: lcaldas@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2011-10-26

    This paper study the Teflon, which is used as aglomerant in the confection of dosimetric pastilles, for the viabilization of this material as high dose dosimeter. This paper used the OSL technique for the characterization of dosimetric properties of Teflon. The doses-response curve has been obtained for {sup 60}Co radiation between 100 Gy and 50 kGy, and the OSL answer reproducibility. The preliminary results shown that the Teflon is a material which can be used for high dose dosimetry

  11. Natural gas utilization in Santa Cruz thermal-electric power; A utilizacao de gas natural em Santa Cruz

    Energy Technology Data Exchange (ETDEWEB)

    Azevedo, Mauricio F. de.; Lundeqvist, Carl G; Gomes, Gerson; Almeida, A E

    1994-12-31

    Use of natural gas as an alternative energy source on the thermo electric power plant of Santa Cruz are presented. Economic studies on hydroelectric power plants to use thermal generators during low water supply periods, costs of natural gas as a alternative energy fuel, and the engineer services to the conversion of fuel oil system, are discussed. 5 figs., 6 tabs.

  12. Ensaios in vitro com a linhagem celular ZF-L para análise dos efeitos de gasolina e efluentes de postos de combustível

    OpenAIRE

    Débora Lachner

    2013-01-01

    O uso de linhagens celulares e bastante promissor como modelo biologico in vitro, tanto para a melhoria do rendimento dos testes de toxicidade quanto para reducao dos seus custos. Destaca-se no presente trabalho a utilizacao da linhagem celular permanente de hepatocitos de Danio rerio, denominada ZF-L. Diversos trabalhos comprovam a sensibilidade de ZF-L quando expostas a diversos contaminantes, com a utilizacao satisfatoria de diferentes biomarcadores. Assim, o objetivo deste trabalho foi av...

  13. Influence of the addition of fertilizers and organic matter amendment on mercury contaminated soil; Influencia de la adicion de fertilizantes y enmendantes organicos en suelos contaminados de mercurio

    Energy Technology Data Exchange (ETDEWEB)

    Carrasco, S; Millan, R

    2008-07-01

    The objective of this work was to evaluate the mercury mobilization in a soil where fertilizers and organic matter were added. The study was carried out using a soil from the mercury mining district of Almaden (Spain). This area constitutes the largest and most unusual concentration of mercury in the World. The soil has been classified as an Alfisol Xeralf Haploxeral (USDA taxonomy), and the total mercury content is 14,16 0,65 mg kg-1in average. The experimental work was performed in 1 L glass columns filled with 500 g of soil. It was carried out 3 different treatments. The fi rst one, a NPK fertilizer (15:15:15) that was applied at three different doses (recommended dose -by farmers, half recommended dose and double recommended dose). The second one, a peat (Sphagnum) with a ph between 5,5-7, and the third one, a liquid organic amendment (Molex). The experimental work was carried out using 21 columns in total, where 3 of them were used as a control (C). During ten consecutive weeks, the columns were irrigated with distilled water (150 ml) once a week. The contact time was two days; after that, the leachates were collected and filtered. Finally, the soil contained in glass columns at soil fi eld capacity was centrifuged to get the wilting point. Mercury was determined using an Advanced Mercury Analyzer (AMA-254). Results show that mercury content in all samples was under detection limit (0,5 {mu}g L-1). It is according to the fact that mercury is mainly in a cinnabar form, which had a very low solubility. The addition of fertilizers and organic matter amendment do not increase the mercury content in the leachates either in the soil solution. (Author) 102 refs.

  14. Development of Methodologies from Determination of Organic Components from Atmospheric Aerosol; Desarrollo de Metodologias para la Determinacion de Componentes Organicos del Aerosol Atmosferico

    Energy Technology Data Exchange (ETDEWEB)

    Pindado, O; Perez, R; Garcia, R; Barrado, A I; Sevillano, M L; Gonzalez, D

    2006-07-01

    It is presented method for the organic compound determination, such as n-alkanes, PAH's, alcohols and fatty acids that are comprised the particulate matter of aerosol. The procedure is based on sampling the particulate matter over quartz fibre filters that will be extracted by means of the Soxhiet technique, and later they will be divided by means of silicagel column. PAH's is analyzed by means of HPLCm whereas the rest is analyzed by GC-MS and for it, acids and alcohol must be previously derivatized with BSTFA.12 samples took shelter of fractions PMIO and PM2.5 of the aerosol of country side like application of the method. (Author) 60 refs.

  15. Energy inputs and outputs in organic and conventional corn production systems; Balanco de energia em sistemas organico e convencional de producao de milho

    Energy Technology Data Exchange (ETDEWEB)

    Campos, Alessandro Torres; Greco, Marcelo [Universidade Estadual do Oeste do Parana (UNIOESTE), Marechal Candido Rondon, PR (Brazil). Grupo de Pesquisas em Ambiencia do Oeste do Parana; Zonin, Wilson J; Silva, Nardel L.S.; Gouvea, Alfredo [Universidade Estadual do Oeste do Parana (UNIOESTE), Marechal Candido Rondon, PR (Brazil). Centro de Ciencias Agrarias

    2004-07-01

    corn production systems. The experimental delineating was in casual blocks with arrangement in subdivided parcels, with the production systems as main parcels and the cultivate crops as sub parcels. The seeding was accomplished directly in oat and azevem straws. In the chemical system the vegetable covering was wiped with glyphosate (2 L/ha), while in the organic system it was used roll machinery to handle the straw. All the inputs, in products or operations form, and the outputs, in grain form, were transformed in energy to estimate the energy balance. The energy coefficients were obtained in research travails. The employed energy was divided in three categories, according to its origin, as biological, fossil and industrial. In the category of biological energy the items human work, seeds, bio fertilizer and humus were inserted. The oil products and by-products, such as chemical fertilizer, pesticides, diesel were grouped in fossil energy category. Industrial energy was considered one that was used in the manufacture of machinery used in the products process. Are included in this categories: tractor and tools. The energy consumption in the organic corn production system was of 2,047.42 MJ ha{sup -1} and the energy conversion was of 78,235.33 MJ ha{sup -1}, and the biological energy was the energy form more consumed, 65,77% of total consumed, while in the conventional system the consumption was of 3,764.66 MJ ha{sup -1} and the energy conversion of 82,653.29 MJ ha{sup -1}, and the fossil was energy form more consumed, representing 79.57% of the energy consumed in this production system. The organic production system presented an efficiency of 38.21 significantly larger than the chemical system with 21.95. (author)

  16. Preparation and characterization of two organoclays aiming its use in adsorption processes; Sintese de argilas organofilicas e compositos organoceramicos aplicados a adsorcao de organicos contaminates

    Energy Technology Data Exchange (ETDEWEB)

    Vazzoler, H.; Valenzuela-Diaz, F.R.; Vazzoler, F.D., E-mail: heverton@usp.br [Universidade de Sao Paulo (USP), SP (Brazil). Departamento de Engenharia Metalurgica e de Materiais. Laboratorio de Solidos Nao Metalicos

    2014-07-01

    Were prepared two organoclays aiming at studying their adsorption properties. The clayssed were the Brazilian Bentongel and Argentina Green Lake. The clays were characterized and organoclays. Performed analyzes of X-Ray diffraction, infrared, SEM, thermogravimetry and swelling experiments Foster and adsorption ASTM. The X-ray diffraction indicated collation of lamellar organic cation used. The variations thermogravimetrics were negative and ranged from around 24% in organophilic clays. The results of infrared spectroscopy indicated the presence of bands that show this barge. The form of the particles/agglomerates of clay minerals was verified by SEM before and after organofilization. The values of the measures of swelling were up to 30 mL/g for some solvents. The adsorption test showed good ability of sorption per gram of clay, reaching respectively 10.2g/g and 9.9 g/g for gasoline and ethylbenzene. These high values indicate that the modified clay may have potential use in sectors of environmental toxicity control industrial and separation. (author)

  17. Presence of persistent organic pollutants in european domestic indoor air; Presencia de compuestos organicos persistentes en aire domestico de paises europeos

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, M. A.; Torre, A. de la; Sanz, P.; Ramos, B.

    2013-02-01

    The quality of life experienced by the world population in the the last century has been possible thanks to the development of new chemical products whose medium- and long-term consequences were not studied at the time of manufacture. These products have been used to eradicate insect plagues (insecticides) or to improve other materials (flame retardants, insulators, lubricants or dielectric products), thus saving lives or preventing substantial material and economic losses. However, recent studies have demonstrated despite the beneficial properties, their use also poses a risk to human health.. (Author) 8 refs.

  18. Methylene blue adsorption in clay mineral dealt with organic cation; Sorcao de azul de metileno em argila esmectitica tratada com cation organico

    Energy Technology Data Exchange (ETDEWEB)

    Silva, T.L. [Universidade Federal do Para (UFPA), Maraba, PA (Brazil). Faculdade de Engenharia de Materiais; Lemos, V.P., E-mail: tls1981@hotmail.com [Universidade Federal do Para (UFPA), Belem, PA (Brazil). Centro de Geociencias

    2011-07-01

    The interaction among organic cations, as the methylene blue (AM) and benzyltrimethylammonium (BTMA), and clay minerals of the group of the smectite they result in the formation of applied materials in the adsorption of organic pollutant presents in waters, soils and you cultivate. In this work they were prepared the adsorbents (organic-clays) smectite - AM and smectite-BTMA. The precursory sample of smectite was collected in Rio Branco-Acre. We were also used an smectite sample collected in Sena Madureira (SM)-Acre already characterized in previous work and a sample of standard smectite Swy-2-Na-Montmorillonite (SWy-2) of Wymong - USA. The organic agents selected for this study they were: Blue of Methylene, denominated AM and Benzyltrimethylammonium, denominated BTMA. They were appraised the capacities adsorptive of the treated samples with BTMA being used AM as adsorbate. The results of these evaluations detected that ran total adsorption of AM (concentrations varying from 1 to 10 ppm) for the treated samples with BTMA. The organic cation, BTMA, interacting with the surfaces of the natural clay was more efficient in the adsorption of AM than the clay without the previous treatment with this salt. (author)

  19. Development of Methodologies from Determination of Organic Components from Atmospheric Aerosol; Desarrollo de Metodologias para la Determinacion de Componentes Organicos del Aerosol Atmosferico

    Energy Technology Data Exchange (ETDEWEB)

    Pindado, O.; Perez, R.; Garcia, R.; Barrado, A. I.; Sevillano, M. L.; Gonzalez, D.

    2006-07-01

    It is presented method for the organic compound determination, such as n-alkanes, PAH's, alcohols and fatty acids that are comprised the particulate matter of aerosol. The procedure is based on sampling the particulate matter over quartz fibre filters that will be extracted by means of the Soxhiet technique, and later they will be divided by means of silicagel column. PAH's is analyzed by means of HPLCm whereas the rest is analyzed by GC-MS and for it, acids and alcohol must be previously derivatized with BSTFA.12 samples took shelter of fractions PMIO and PM2.5 of the aerosol of country side like application of the method. (Author) 60 refs.

  20. Thermodynamic simulation for a vapour compression system using organic refrigerants; Simulacao termodinamica do ciclo de compressao a vapor utilizando fluidos refrigerantes organicos

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, Francisco S.; Santos, Carlos A.C. dos [Universidade Federal da Paraiba (UFPB), Joao Pessoa, PB (Brazil). Lab. de Energia Solar; Torres, Ednildo A.; Jesus, Marcos F. de [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Dept. de Engenharia Quimica. Lab. de Energia e Gas

    2004-07-01

    According to the Montreal protocol, it is foreseen a total retreat of CFCs and HCFCs in applications of refrigeration and air conditioning. Before this context, considerable attention has been used in the substitution of HCFC-22 (R22) in systems of air conditioning, where they appear as possible alternatives two HFCs (R407c and R410a) and two HCs (R290 and R600a). In this work, possibilities and problems for the use of these fluids as alternatives to R22 in equipment of refrigeration are discussed. Five refrigerants (R22, R407c, R410a, R290 and R600) are selected, computational simulations done and your characteristic in terms of thermodynamic cycles are shown. The obtained conclusion is that propane offers the best alternative for R22 in equipment of refrigeration, because this besides being energetically efficient, is environmentally acceptable. However, safety precautions due to your inflammability must be seriously taken into account. For some applications the substitution of the current fluids (halocarbons) by the hydrocarbons can be done without larger additional costs, but not in the general case. (author)

  1. Spectrographic determination of metallic impurities in organic coolants for nuclear reactors; Determinacion espectrografica de impurezas metalicas en refrigerantes organicos para reactores nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Martin Munoz, M; Alvarez Gonzalez, F

    1969-07-01

    A spectrochemical method for determining metallic impurities in organic coolants for nuclear reactors is given. The organic matter in solid samples is eliminated by controlled distillation and dry ashing in the presence of magnesium oxide as carrier. Liquid, samples are vacuum distillated. The residue is analyzed by carrier distillation and by total burning techniques. The analytical results are discussed and compared with those obtained destroying the organic matter without carrier and using the copper spark technique. (Author) 12 refs.

  2. Decree 831/976 Industry and Energy Ministry approve an organic regulation; Decreto 831/976 Ministerio de Industria y Energia se aprueba su reglamento organico

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1976-07-01

    The ordinance 831 of 1976 approve the organic regulation of the Ministry of Industry and Energy and organization manuals and functions according to the principle and elaborated technical approaches and systematized by the National Office of the Civil Service. Among some of their made they are projecting the industrial politics and energetics of the country exercising supervision and control, as well as the development of the industry and diverse energy sources, to propitiate the use of the atomic energy in the Uruguay coordinating the activities that are carried out.

  3. Study of the degradation of liquid-organic radioactive wastes by electrochemical methods; Estudio de la degradacion de desechos liquidos-organicos radiactivos mediante metodos electroquimicos

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez A, J. I.

    2015-07-01

    In this study degradation studies were performed on blank samples, in which two electrochemical cells with different electrodes were used, the first is constituted by mesh electrodes Ti/Ir-Ta/Ti and the second by rod electrodes Ti/Ddb, using as reference an electrolytic medium of scintillation liquid and scintillation liquid more water, applying different potentials ranging from 1 to 25 V. After obtaining the benchmarks, the treatment was applied to samples containing organic liquid radioactive waste, in this case a short half-life radioisotope as Sulfur-35, the degradation characterization of organic compounds was performed in infrared spectrometry. (Author)

  4. Vermicomposting of organic wastes from olive oil, winery and alcohol industries; Vermicompostaje de residuos organicos generados por industrias oleicolas, vitivinicolas y alcoholeras

    Energy Technology Data Exchange (ETDEWEB)

    Nogales, R.; Melgar, R.; Cifuentes, C.; Romero, E.; Benitez, E.

    2004-07-01

    The olive oil, winery and alcohol industries produce large amounts of organic waste that need suitable management in order to reduce their potential impact on the environment. This paper briefly describes the use of vermicomposting, at microcosm, laboratory and pilot scale, as an efficient and low-cost biotechnological process to obtain safe,mature and stabilised organic amendments, which can be feasibly used in conventional, integrated and organic agriculture. (Author) 26 refs.

  5. Entomofauna associated to horticultural crops under organic and conventional practices in Cordoba, Argentina; Entomofauna asociada a cultivos horticolas organicos y convencionales en Cordoba, Argentina

    Energy Technology Data Exchange (ETDEWEB)

    Zalazar, Laura; Salvo, Adriana [Universidade Nacional de Cordoba (Argentina). Facultad de Ciencias Exactas Fisicas y Naturales. Centro de Investigaciones Entomologicas de Cordoba (CIEC)

    2007-09-15

    Farming practices and the addition of chemical synthetic substances in conventional agroecosystems are detrimental mainly to natural enemies of phytophagous insects, diminishing the natural regulation of pest insects. On the other hand, in organic agriculture, biological processes and care of the environment are favoured, hence an increase in insect biodiversity is predicted in this type of systems. In this work, abundance, richness of insects and proportion of functional groups were compared through a single quantitative sampling of insects in horticultural crop fields, three under organic and three under conventional management practices. Insect species richness, total and for guilds (phytophagous and entomophagous insects) were significantly higher in organic orchards, and also was the abundance of entomophagous insects. Richness and abundance of all insect orders (with exception of Homoptera abundance), were higher in orchards under organic management, being significant the differences for richness of Coleoptera and richness and abundance of Hymenoptera. Similar tendencies were observed in data obtained through sweep net in weeds. These results suggest that organic practices increase the diversity of species, particularly that of natural enemies. (author)

  6. Solubility of metallic mercury in organic solvents; Solubilite du mercure metallique dans les solvants organiques; Rastvorimost' metallicheskoj rtuti v organicheskikh rastvoritelyakh; Solubilidad del mercurio metalico en solventes organicos

    Energy Technology Data Exchange (ETDEWEB)

    Klehr, E H; Voigt, A F [Institute for Atomic Research and Department of Chemistry, Iowa State University, Ames, IA (United States)

    1962-03-15

    The solubilities of metallic mercury at 25{sup o}C in the solvents carbon tetrachloride, 2, 2, 4-trimethylpentane, n-decane, benzene, toluene, nitrobenzene, chlorobenzene and bromobenzene have been determined by the use of Hg{sup 203} tracer. Measurements were made either by shaking mercury metal of known specific activity with the solvent, or by measuring the distribution coefficient of the metal between the solvent and water and combining this measurement with the solubility of mercury in water, or by both methods. Radioactivity was measured by counting precipitated samples with a GM counter or liquid aliquots with a well-type scintillator counter. All solubilities were in the range (4.6 to 16) x 10{sup -6} g atoms/l. For n-decane, toluene and chlorobenzene, the temperature dependence of the solubility was determined over the range 0 to 45{sup o}C. The Hildebrand-Scott theory of solubility has been applied to these systems for comparison. For the aliphatic hydrocarbons, the solubilities predicted by theory are within 35% of those observed, but for the other solvents, the predicted values are 4 to 18 times larger than those observed. Modification of the theory gives better agreement for some solvents but poorer agreement for others. Curves of log G (solubility) vs. 1/T were straight lines with slopes similar to those obtained from the Hildebrand-Scott theory but displaced from those curves. The slopes of the curves were used for the calculation of heats and entropies of solution. Entropies were also calculated from curves of log G vs. log T. The two sets of entropy values were in agreement with each other and were within one to four entropy units of the ideal entropies of mixing. (author) [French] Les auteurs ont determine la solubilite du mercure metallique a 25{sup o}C dans les solvants suivants: tetrachlorure de carbone, trimethylpentane 2, 2, 4, n-decane, benzene, toluene, nitrobenzene, chlorobenzene et bromobenzene en utilisant le mercure-203 comme radioindicateur. Ils ont fait les mesures soit en melangeant du mercure metallique d'une activite specifique connue avec le solvant et en agitant, soit en mesurant le le coefficient de distribution du metal entre le solvant et l'eau et en combinant cette mesure avec la solubilite du mercure dans l'eau, soit en employant simultanement les deux methodes. Ils ont mesure la radioactivite en comptant soit des echantillons de precipite avec un compteur de Geiger-Muller, soit des liquides aliquotes avec un compteur a scintillations a puits. Toutes les valeurs de solubilite etaient comprises entre 4,6 x 10{sup -6} et 16 x 10{sup -6} atomes g/l. Pour le n-decane, le toluene et le chlorobenzene, ils ont determine l'influence de la temperature sur la solubilite, de 0 a 45{sup o}C. Ils ont applique a ces systemes la theorie de Hildebrand-Scott sur la solubilite, a des fins de comparaison. Pour les hydrocarbures aliphatiques, les valeurs de la solubilite prevues par la theorie sont egales a 35 % des valeurs observees ; en revanche, pour d'autres solvants les valeurs predites sont 4 a 18 fois plus elevees que les valeurs observees. En modifiant la theorie, on obtient une meilleure concordance pour certains solvants, mais la concordance est moins bonne pour d'autres. Les courbes de log C en fonction de 1/T (C etant la solubilite) sont des droites dont la pente est la meme que celle des droites obtenues par la theorie de Hildebrand-Scott, mais deplacees par rapport a celles-ci. Les auteurs ont utilise les pentes des courbes pour calculer les quantites de chaleur et d'entropie de la solution; ils ont egalement calcule les quantites d'entropie a partie des courbes de log C en fonction de log T. Les deux series de quantites d'entropie concordent l'une avec l'autre et different de une a quatre unites d'entropie de la quantite d'entropie ideale du melange. (author) [Spanish] Usando {sup 203}Hg como trazador, los autores han determinado la solubilidad del mercurio metalico, a 25 {sup o}C, en los siguientes solventes: tetracloruro de carbono; 2,2,4-trimetilpentano; n-decano; benceno; tolueno; nitrobenceno, clorobenceno y bromobenceno. Las mediciones se efectuaron sea agitando mercurio metalico de actividad especifica conocida con el solvente, sea determinando el coeficiente de distribucion del metal entre el solvente y el agua y combinando esta determinacion con la de la solubilidad del mercurio en agua, sea aplicando los dos metodos sucesivamente. La radiactividad se determino recontando las muestras del precipitado con un contador Geiger-Mueller, o recontando partes alicuotas del liquido con un contador de centelleo del tipo de pozo. Los valores de la solubilidad resultaron del orden de 4,6 a 16 x 10-6 atomos g/l. En el caso del n-decano, del tolueno y del clorobenceno, se determino la relacion de dependencia entre la solubilidad y la temperatura desde 0 hasta 45 {sup o}C. Para comparar los resultados se aplico a estos sistemas la teoria de la solubilidad de Hildebrand-Scott. En el caso de los hidrocarburos alifaticos, los valores de la solubilidad calculados teoricamente no se alejan mas de un 35% de los observados, pero para los otros solventes los valores teoricos son de 4 a 18 veces mayores que los observados. Modificando la teoria se obtiene una concordancia mayor para unos solventes y menor para otros. (author) [Russian] Opredelyalas' rastvorimost' metallicheskoj rtuti pri temperature 25{sup o}C s pomoshch'yu indikatora Hg{sup 203} v rastvoritelyakh chetyrekhkhloristogo ugleroda, 2,2,4-trimetilpentana, i-dekana, benzola, toluola, nitrobenzola, khlorbenzola i brombenzola. Izmereniya osushchestvlyalis' libo putem vzbaltyvaniya metallicheskoj rtuti izvestnoj udel'noj aktivnosti s rastvoritelem, libo izmereniem koehffitsienta raspredeleniya metalla mezhdu rastvoritelem i vodoj i ob{sup e}dineniem ehtogo izmereniya s rastvorimost'yu rtuti v vode ili i tem i drugim metodom. Radioaktivnost' izmeryalas' podschetom osazhdennykh obraztsov schetchikom Gejgera-Myullera ili zhidkikh rassloenij stsintillyatsionnym schetchikom tipa kolodtsa. Vse rastvorimosti byli poryadka (4,6 do 16) x 10{sup -6} gramm-atomov/l. Temperaturnaya zavisimost' rastvorimosti dlya n-dekana, toluola i khlorbenzola opredelyalas' poryadkom ot 0 do 45{sup o}C. Dlya sravneniya k ehtim sistemam primenyalas' teoriya rastvorimosti KHil'debranda-Skotta. Dlya uglevodorodov alifaticheskogo ryada predskazannye teoriej rastvorimosti sostavlyayut 35% tekh, kotorye udalos' nablyudat', no dlya drugikh rastvoritelej predskazannye velichiny yavlyayutsya v 4 - 18 raz bol'she tekh, kotorye prishlos' nablyudat'. Izmenenie teorii daet luchshee soglasovanie dlya odnikh rastvoritelej i khudshee dlya drugikh. Krivye log C (rastvorimost') protiv 1/T byli pryamymi liniyami s naklonami, kotorye skhodny s naklonami teorii KHil'debranda-Skotta, no so smeshcheniem ot ehtikh krivykh. Naklony krivykh ispol'zovalis' dlya vychisleniya tepla i ehntropii rastvora, a ehntropii takzhe vychislyalis' iz krivykh log C protiv log T. Dve serii znachenij ehntropii soglasovyvalis' drug s drugom, a takzhe nakhodilis' v predelakh ot odnogo do chetyrekh edinits ehntropii nailuchshego smesheniya ehntropii. (author)

  7. Application of the Raman spectroscopy for the characterization of organic pesticides; Aplicacion de la espectroscopia Raman para la caracterizacion de pesticidas organicos

    Energy Technology Data Exchange (ETDEWEB)

    Sato B, R.Y.; Medina G, C.; Medina V, J.; Frausto R, C. [Centro de Investigaciones en Optica, A.C., Unidad Aguascalientes, Prol. Constitucion 607, Reserva Loma Bonita, C.P. 20200, Aguascalientes (Mexico)]. e-mail: rsato@foton.cio.mx

    2004-07-01

    Raman spectra of organophosphate, organo chlorine and bipyridyl pesticides are presented in this study. They have been obtained satisfactorily by the NlR-Raman spectroscopy technique. Pesticides have been analyzed in solution or as a solid in glass containers and on aluminum substrates. This analytic technique can be an alternative tool for the detection of pesticides in the agriculture, presenting advantages as be quick, not destructive and require little or no sample preparation. Moreover, samples can be analyzed through transparent containers avoiding contact with the toxic substances. The implementation of the aluminium substrate is easy and practical. Moreover, it is commercially available and does not need a previous preparation. The analysis of a mixture of two pesticides in a {beta} carotene solution is shown. (Author) 25 refs., 8 figs.

  8. Biodegradation of radioactive organic liquid waste from spent fuel reprocessing; Biodegradacao de rejeitos radioativos liquidos organicos provenientes do reprocessamento do combustivel nuclear

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Rafael Vicente de Padua

    2008-07-01

    The research and development program in reprocessing of low burn-up spent fuel elements began in Brazil in 70's, originating the lab-scale hot cell, known as Celeste located at Nuclear and Energy Research Institute, IPEN - CNEN/SP. The program was ended at the beginning of 90's, and the laboratory was closed down. Part of the radioactive waste generated mainly from the analytical laboratories is stored waiting for treatment at the Waste Management Laboratory, and it is constituted by mixture of aqueous and organic phases. The most widely used technique for the treatment of radioactive liquid wastes is the solidification in cement matrix, due to the low processing costs and compatibility with a wide variety of wastes. However, organics are generally incompatible with cement, interfering with the hydration and setting processes, and requiring pre -treatment with special additives to stabilize or destroy them. The objective of this work can be divided in three parts: organic compounds characterization in the radioactive liquid waste; the occurrence of bacterial consortia from Pocos de Caldas uranium mine soil and Sao Sebastiao estuary sediments that are able to degrade organic compounds; and the development of a methodology to biodegrade organic compounds from the radioactive liquid waste aiming the cementation. From the characterization analysis, TBP and ethyl acetate were chosen to be degraded. The results showed that selected bacterial consortia were efficient for the organic liquid wastes degradation. At the end of the experiments the biodegradation level were 66% for ethyl acetate and 70% for the TBP. (author)

  9. Characterization of sodium bentonites: effect of treatment with ammonium salt- free organic surfactant; Caracterizacao de bentonitas sodicas: efeito do tratamento com surfactante organico livre de sal de amonio

    Energy Technology Data Exchange (ETDEWEB)

    Morita, R. Y.; Barbosa, R. V.; Kloss, J.R., E-mail: julianaweber@utfpr.edu.br [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil). Dartamento de Quimica e Biologia

    2015-07-15

    Bentonite, which the main clay mineral is montmorillonite, are commercially attractive because of its abundance in nature. The clays can be modified by ion exchange reactions of ions contained in the interlayer region with cationic surfactants that include ammonium or phosphonium salts. The clays origin and the type of surfactants (modifiers) are the main factors in the alteration of physical and chemical properties of these materials. This study aims to characterize and compare the results of natural bentonite commercially available and the effect of treatments with quaternary ammonium salt and an organic compound free of ammonium salt. The FTIR and XRD results indicate the process of organophilization of clays after treatment with the surfactants. These treatments have altered the average particle size, suggesting the formation of agglomerates, which was showed in the SEM images. The results of surface area and particle size data indicated the presence of larger particles. Although the two surfactants have shown similarities in the investigated properties, the organoclays free of ammonium salt are more promising in terms of its use as well as for their preparation and solubility. (author)

  10. USO DA ESPECTROFOTOMETRIA UV-VIS PARA DIFERENCIAR AS COLORAÇÕES DO BIODIESEL DE PALMA E DO CORANTE MARCADOR DE ÓLEO DIESEL

    Directory of Open Access Journals (Sweden)

    Maria S. M. Quintino

    Full Text Available Currently, there are two mixtures of biodiesel/diesel fuel sold in Brazil: BX/S500 and BX /S10 (X = volume/volume biodiesel percentage; S500 and S10 = sulfur content in diesel fuels - 500 ppm and 10 ppm, respectively. In order to differentiate these mixtures, red dye is added to diesel oil as required by the National Agency for Petroleum, Natural Gas and Biofuels (ANP, regulatory agency in Brazil. Since the palm oil biodiesel has also a reddish color, mixing this product with diesel fuel leads to difficulty in visual differentiation of the mixtures BX/S500 and BX/S10. We propose the use of UV-Vis spectrophotometry, which is a low cost, simple and rapid technique. Spectra obtained for different mixtures show that qualitative distinction is possible. For quantification of red dye in the presence of palm oil biodiesel, the method is limited when dye is present in low concentrations (< 0.1 mg L-1 due to matrix effects. The method showed good repeatability of the absorbance responses, wide linear dynamic range (0.02 mg L-1 to 40.00 mg L-1 and low limits of detection and quantification (0.006 mg L-1 and 0.019 mg L-1, respectively.

  11. Use of Fricke solution modified with dyes for dosimetry in phototherapeutic treatments; Uso da solucao Fricke modificada com corantes para futura dosimetria em tratamentos fototerapeuticos

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, Mayara Gabriella Oliveira de; Nascimento, Rizia Keila; Vieira, Rafaela Etelvina de Amorim; Souza, Vivianne Lucia Bormann, E-mail: mayaradqf@hotmail.com, E-mail: riziakeila@hotmail.com, E-mail: rafaelarodriguesss@hotmail.com, E-mail: vlsouza@cnen.gov.br [Centro Regional de Ciencias Nucleares do Nordeste (CRCN-NE/CNEN-PE), Recife (Brazil)

    2014-07-01

    Dyes and pigments (photosensitizers) are characterized by their ability to absorb visible light, and to participate in photochemical reactions. These colors are used in medicine in the dose recommended for use in photodynamic therapy (PDT). There are lasers that can meet most of the phototherapeutic agents and are capable of providing light of considerable power with precision on the injured tissue. The use of light emitting diodes (LEDs) have become feasible, thus reducing the cost of the procedures. The Dosimetry Laboratory Chemistry of the CRCN-NE/Brazilian CNEN has worked with some likely dye use in phototherapy treatments, including: methylene blue, malachite green and toluidine blue. A volume of 2.6 ml of the dosimeters was transferred to test tubes and these were irradiated with LED 24, 48, 72 and 96 acrylic simulator 110 mm x 110 mm x 80 mm at a distance of 6.5 cm from reading light source of the irradiated samples was performed on a spectrophotometer. Having obtaining excellent correlations (above 0.97) to the dosimeter calibration curves. Suggests that the dosimeter can be applied to perform a quality control in photodynamic therapy. However, further experiments should be performed before a wide application of this technique. A volume of 2.6 ml of the dosimeters was transferred to test tubes and these were irradiated with LED 24, 48, 72 and 96 acrylic simulator 110 mm x 110 mm x 80 mm at a distance of 6.5 cm from reading light source of the irradiated samples was performed on a spectrophotometer. Having obtaining excellent correlations (above 0.97) to the dosimeter calibration curves. Suggests that the dosimeter can be applied to perform a quality control in photodynamic therapy. However, further experiments should be performed before a wide application of this technique.

  12. CÉLULAS SOLARES SENSIBILIZADAS POR CORANTES NATURAIS: UM EXPERIMENTO INTRODUTÓRIO SOBRE ENERGIA RENOVÁVEL PARA ALUNOS DE GRADUAÇÃO

    Directory of Open Access Journals (Sweden)

    Gabriela G. Sonai

    2015-12-01

    Full Text Available An interesting practical experiment about the preparation of dye–sensitized solar cells (DSSC using natural dyes were carried out by the undergraduate students in the chemistry course at UNICAMP . Natural dyes were extracted from blueberries (Vaccinium myrtillus L., jabuticabas (Myrciaria cauliflora, raw and cooked beets (Beta vulgaris L., and annattos (Bixa orellana L., which were used to sensitize TiO2 films that composed the photoanode in the DSSC. A polymer electrolyte containing an iodide/triiodide redox couple was used in lieu of the use of liquid solutions to prevent any leakage in the devices. A maximum solar-to-electric energy conversion of 0.26 ± 0.02% was obtained for the solar cell prepared with annatto extracts. This experiment was an effective way to illustrate to the undergraduate students how to apply some of the chemical concepts that they learned during their chemistry course to produce electric energy from a clean and renewable energy source. Teachers could also exploit the basics of the electronic transitions in inorganic and organic compounds (e.g., metal-to-ligand charge transfer and ϖ-ϖ* transitions, thermodynamics (e.g., Gibbs free energy, acid–base reactions in the oxide solid surface and electrolyte, and band theory (i.e., the importance of the Fermi level energy.

  13. CÉLULAS SOLARES SENSIBILIZADAS POR CORANTES NATURAIS: UM EXPERIMENTO INTRODUTÓRIO SOBRE ENERGIA RENOVÁVEL PARA ALUNOS DE GRADUAÇÃO

    OpenAIRE

    Sonai, Gabriela G.; Melo Jr., Maurício A.; Nunes, Julia H. B.; Megiatto Jr., Jackson D.; Nogueira, Ana F.

    2015-01-01

    An interesting practical experiment about the preparation of dye–sensitized solar cells (DSSC) using natural dyes were carried out by the undergraduate students in the chemistry course at UNICAMP . Natural dyes were extracted from blueberries (Vaccinium myrtillus L.), jabuticabas (Myrciaria cauliflora), raw and cooked beets (Beta vulgaris L.), and annattos (Bixa orellana L.), which were used to sensitize TiO2 films that composed the photoanode in the DSSC. A polymer electrolyte containing an ...

  14. CÉLULAS SOLARES SENSIBILIZADAS POR CORANTES NATURAIS: UM EXPERIMENTO INTRODUTÓRIO SOBRE ENERGIA RENOVÁVEL PARA ALUNOS DE GRADUAÇÃO

    OpenAIRE

    Gabriela G.; Sonai; Maurício A.; Melo Jr.; Julia H. B.; Nunes; Jackson D.; Megiatto Jr.; Ana F.; Nogueira

    2015-01-01

    An interesting practical experiment about the preparation of dye–sensitized solar cells (DSSC) using natural dyes were carried out by the undergraduate students in the chemistry course at UNICAMP . Natural dyes were extracted from blueberries (Vaccinium myrtillus L.), jabuticabas (Myrciaria cauliflora), raw and cooked beets (Beta vulgarisL.), and annattos (Bixa orellana L.), which were used to sensitize TiO2 films that composed the photoanode in the DSSC. A polymer electrolyte containing an i...

  15. CÉLULAS SOLARES SENSIBILIZADAS POR CORANTES NATURAIS: UM EXPERIMENTO INTRODUTÓRIO SOBRE ENERGIA RENOVÁVEL PARA ALUNOS DE GRADUAÇÃO

    OpenAIRE

    Sonai,Gabriela G.; Melo Jr.,Maurício A.; Nunes,Julia H. B.; Megiatto Jr.,Jackson D.; Nogueira,Ana F.

    2015-01-01

    An interesting practical experiment about the preparation of dye–sensitized solar cells (DSSC) using natural dyes were carried out by the undergraduate students in the chemistry course at UNICAMP . Natural dyes were extracted from blueberries (Vaccinium myrtillus L.), jabuticabas (Myrciaria cauliflora), raw and cooked beets (Beta vulgaris L.), and annattos (Bixa orellana L.), which were used to sensitize TiO2 films that composed the photoanode in the DSSC. A polymer electrolyte containi...

  16. Corantes marcadores de combustíveis: legislação e métodos analíticos para detecção

    Directory of Open Access Journals (Sweden)

    Magno Aparecido Gonçalves Trindade

    2011-01-01

    Full Text Available The use of dyes in the commercialization of fuel is usually associated with protection of the source and destination. It is used as "markers" to identify and guarantee the identity of the specific product of a particular manufacturer to discourage theft, tampering and disclosure of the quality of solvent or fuel. This work presents a critical analysis on the state of the art about the available analytical methods for identification and quantification of dyes used as markers of solvents and fuels, as well as evaluation of the physical-chemical staining and laws surrounding their use and commercialization.

  17. Biodegradação de uma mistura de corantes têxteis usando o fungo Ganoderma sp: um estudo cinético

    Directory of Open Access Journals (Sweden)

    Wagner José Barreto

    2011-01-01

    Full Text Available The kinetics of biodegradation by the fungus Ganoderma sp of textile dyes Yellow, Blue and Red Procion were studied in effluents using UV-Vis spectroscopy, Partial Least Squares Regression (PLS and univariate analysis. The kinetic of the reactions were founded intermediate between first and second orders and the rate constants were calculated. The biodegradation after 72 h at 28 ºC were 33.6, 43.5 and 57.7% for the dyes Yellow, Blue and Red Procion, respectively. The quantitative analysis of the effluent by HPLC method can not be used without previous separation.

  18. Tertiary windings in power transformers: advantages and disadvantages of their utilization; Enrolamentos terciarios em transformadores de potencia: vantagens e desvantagens de sua utilizacao

    Energy Technology Data Exchange (ETDEWEB)

    Vaccari, Francisco; Alferes, Paulo J.; Etrusco, Wellington M.; Miranda, Rubens Nelson; Komukai, Oscar S.; Laudanna, Paulo R.; Santos, Marcos A. dos; Brito, Joao C.Costa; Melao, Claudio G.; Junqueira Filho, Ary; Mori, Tosio [Companhia Energetica de Sao Paulo (CESP), SP (Brazil)

    1995-12-31

    Problems related to tertiary of some CESP, an electric power company of Sao Paulo state - Southeast Brazil, large scale transformers lead to reevaluation of the need of such windings in future acquisition of such equipment, as well as analyse the consequences of the opening of the tertiary windings in the operating transformers units. Therefore several studies were performed, which are presented in this work 5 figs., 6 tabs., 7 refs.

  19. The importance of using diffraction of X ray in clays characterization; A importancia da utilizacao da difracao de raios X na caracterizacao de argilas

    Energy Technology Data Exchange (ETDEWEB)

    Piccoli, R.; Nascimento, G.C.; Vitoretti, P.P.; Wernck, A.S.W., E-mail: rosaura@sc.senai.b [SENAI, Criciuma, SC (Brazil). Centro de Tecnologia em Ceramica; Perdona, C.R. [Universidade Barriga Verde, Cocal do Sul, SC (Brazil). Curso de Engenharia Ceramica; Perucchi, P. [Universidade do Extremo Sul Catarinense, Criciuma, SC (Brazil). Curso de Ciencia e Engenharia de Materiais

    2009-07-01

    The objective of this work is to demonstrate how the identification of crystalline phases and deg of crystallinity by diffractometry technique of X-ray (XRD) combined with chemical analysis of a sample can help in the study and characterization of raw materials, mainly those used in ceramic compositions. This study also aims to address the inherent limitations of this technique in relation to types of crystalline phases present in the sample of interest for analysis. (author)

  20. Improving the security of power systems with the use of metaheuristics; Melhorando a seguranca de sistemas de potencia com a utilizacao de metaheuristicas

    Energy Technology Data Exchange (ETDEWEB)

    Silva Neto, C.A. da [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Inst. de Computacao], e-mail: cneto@ic.uff.br; Schilling, M.T. [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil)], E-mail: schilling@ic.uff.br; Souza, J.C.S. [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Programa de Pos-Graduacao em Computacao], E-mail: julio@ic.uff.br

    2009-07-01

    The paper presents aspects leading the combined use of electromechanical simulations complete and metaheuristics in order to increase the safe operation of electric power systems. The index that measuring the level of security and, consequently, the ability to each candidate solution is the level of damping of oscillations voltage. The complete electromechanics simulations allow a more accurate representation of the elements of the grid resulting in a more reliable diagnosis. Metaheuristics possess a high degree of generalization enabling its application in highly complex optimization problems such as the maximization of the attenuation level of voltage oscillations, which occur in a power system, due to a defect in the net. Due to the unprecedented nature of this methodology will be investigated two different metaheuristics, one based on a evolutionary algorithm and the other in particle swarm.

  1. Use of differentials and fill-ups at Reconcavo basin, Brazil; Utilizacao de diferenciais e fill-ups na bacia do Reconcavo Baiano, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Faria, Jose Antonio Diniz; Ribeiro, Eluzai Evangelista [PETROBRAS, BA (Brazil). Distrito de Perfuracao da Bahia. Div. de Tecnicas e Operacoes

    1994-07-01

    To publish results of the insertable valves and differential-type casing accessories with an insert fill-up wells drilled at the Bahia Drilling. This has provided an increase in casing running speed, resulting in a cost reduction of the operations due to non-interruption of running operation for fill-up with drilling fluid. (author)

  2. Solar and wind systems utilization in water pumping for irrigation; Utilizacao de sistemas solar e eolico no bombeamento de agua para uso na irrigacao

    Energy Technology Data Exchange (ETDEWEB)

    Nogueira, Cicero Urbanetto

    2009-07-01

    In this work, it was made an applied research in two stations, the first one located at Canabarro locality and the second one at Polytechnic School at UFSM, in Santa Maria city, RS, with wind and photovoltaic equipment for pumping water. These ones are used for fruit trees irrigation in irrigation systems of low pressure. The research work was developed from September 2007 to August 2009, when the results showed the viability of wind and photovoltaic equipment for utilization in the complementary irrigation in fruit cultures such as guava, fig and grape trees. In the fruit culture sector, are installed: one multivane fans wind indicator one savonius wind indicator and respective pumps as well as pump set and a photovoltaic board. With the photovoltaic system, the pumped volume was about 5000 m{sup 3}/ha and, with the wind system, the pumped volume was approximately 6m{sup 3}/ha. The wind groups demonstrated low efficiency, if compared to photovoltaic systems, which showed more efficient. (author)

  3. Electric arc furnace dust utilization in iron ore sintering: influence of particle size; Utilizacao da poeira de aciaria eletrica na sinterizacao de minerio de ferro: influencia da granulometria

    Energy Technology Data Exchange (ETDEWEB)

    Telles, V.B.; Junca, E.; Rodrigues, G.F.; Espinosa, D.C.R.; Tenorio, J.A.S., E-mail: victor_bridit@hotmail.co [Universidade de Sao Paulo (USP), SP (Brazil). Dept. de Engenharia Metalurgica e de Materiais

    2010-07-01

    The aim of this work was to study the utilization of electric arc furnace dust (EAFD) generated in steelmaking by electric arc furnace (EAF) as raw material in iron ore sintering. The waste was characterized by size, chemical composition and X-ray diffraction. The physical characterization showed that 90% of the particles have a size less then 1,78 {mu}m and the material have the tendency to agglomerate. The waste were submitted to a pre-agglomeration prior to its incorporation in the sinter. The influence on the addition of the waste with different granulometry in the iron or sinter production were analyzed by sinter characterization and sintering parameters. (author)

  4. Utilization of gas micro turbines in the PETROBRAS remote unattended stations; Utilizacao de microturbinas a gas nas instalacoes desassistidas da PETROBRAS

    Energy Technology Data Exchange (ETDEWEB)

    Pavinatto, Eduardo F.; Salles, Fabio P.; Peres, Marcelo B.; Pereira, Leandro S.; Reis, Paulo F.I. dos [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2004-07-01

    This paper presents PETROBRAS experience in the utilization of gas micro turbines in the production of gas and oil located in off-shore fields and gas metering stations of the transportation system. Available alternatives will be presented for the electrical power supply of these units and they will be outstanding the acquired benefits by using gas micro turbines. Also will be presented the performance test results conducted by CENPES technical staff. Finally, we will present an analysis of the observed acting of these equipment after they have been installed in the units of PETROBRAS under the reliability point of view, maintenance rates, adaptation to the local environmental conditions, behavior of the electric system and operational versatility. (author)

  5. Performance of a diesel engine transformed to spark ignition using natural gas; Desempenho de um motor diesel convertido para utilizacao de gas natural como combustivel

    Energy Technology Data Exchange (ETDEWEB)

    Gutierrez, Ricardo H.R. [Coordenacao dos Programas de Pos-Graduacao de Engenharia (LEDAV/COPPE/UFRJ), RJ (Brazil). Lab. de Ensaios Dinamicos e Analise de Vibracao; Belchior, Carlos R.P. [Coordenacao dos Programas de Pos-Graduacao de Engenharia (LMT/COPPE/UFRJ), RJ (Brazil). Lab. de Maquinas Termicas; Sodre, Jose Ricardo [Pontificia Universidade Catolica de Minas Gerais (PUC/Minas), MG (Brazil)

    2012-07-01

    A zero-dimensional thermodynamic model for a diesel engine converted for dedicated use of natural gas was developed in this work. The computational model covers from the time of closing the inlet valve to the time of opening the exhaust valve and it was divided into three stages (compression, combustion and expansion). A model based on the first law of thermodynamics for closed cycle has been developed to study the performance of the engine. The combustion process was modeled using the equation of Wiebe. It was taken into consideration the convective heat transfer through the walls of the cylinder and the heat transfer coefficient was calculated by the Eichelberg correlation. It was also considered that the thermodynamic properties vary with temperature. To represent the gas mixture behavior inside the cylinder two approaches (Ideal Gas Equation and Van Der Waals's Real Gas Equation) were used and results compared. The computational model was validated with experimental tests. (author)

  6. Use of MMT and MMT organoclay in production of starch nanocomposites; Utilizacao da MMT e da MMT organofilica na producao de nanocompositos de amido

    Energy Technology Data Exchange (ETDEWEB)

    Schlemmer, D; Sales, M J.A., [Universidade de Brasilia (LabPol/UnB), DF (Brazil). Inst. de Quimica. Lab. de Pesquisa em Polimeros; Macedo, J.L. de [Universidade de Brasilia (LabCat/UnB), DF (Brazil). Inst. de Quimica. Lab. de Catalise; Angelica, R S [Universidade Federal do Para (UFPA), Belem, PA (Brazil). Inst. de Geociencias. Lab. de Raios X

    2010-07-01

    Starch can be used to replace petrochemical plastics for short shelf life. However, starch films have poor mechanical strength and sensitivity to moisture. This can be improved through the incorporation of nanoclays, such as montmorillonite, forming nanocomposites. Nanocomposites were prepared with 1, 3, 5 and 10% of montmorillonite, using pequi oil as plasticizer. The clay was also modified with a quaternary ammonium salt. The clays were characterized by XRF, XRD, IR and TG. Results confirmed the organophilization. The nanocomposites diffractograms showed that the addition of small amounts of clay produces delaminated nanocomposites. Already the addition of larger amount of clay does not form nanocomposites, or leads to the formation of intercalated nanocomposites. (author)

  7. Investigation of the benzotriazole as addictive for carbon steel phosphating; Estudo da utilizacao do benzotriazol como aditivo para a fosfatizacao de aco carbono

    Energy Technology Data Exchange (ETDEWEB)

    Annies, V.; Cunha, M.T.; Rodrigues, P.R.P.; Banczek, E.P. [Universidade Estadual do Centro-Oeste, Guarapuava, PR (Brazil). Dept. de Quimica; Costa, I. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Terada, M. [Universidade de Sao Paulo (POLI/USP), SP (Brazil). Escola Politecnica. Dept. de Engenharia Metalurgica e de Materiais

    2010-07-01

    This work studied the viability of substitution of sodium nitrite (NaNO{sub 2}) for benzotriazole (BTAH) in the zinc phosphate bath (PZn+NaNO{sub 2}) for phosphating of carbon steel (SAE 1010). The characterization of the samples was carried out by Scanning Electron Microscopy, Optical Microscopy and X-ray diffraction. The chemical composition was evaluated by Energy Dispersive Spectroscopy. The corrosion behavior of the samples was investigated by Open Circuit Potential, Electrochemical Impedance Spectroscopy and Anodic Potentiodynamic Polarization Curves in a 0.5 mol L{sup -1} NaCl electrolyte. The experimental results showed that the phosphate layer obtained in the solution with benzotriazole (PZn+BTAH) presented better corrosion resistance properties than that obtained in sodium nitrite. The results demonstrated that the sodium nitrite NaNO{sub 2} can be replaced by benzotriazole (BTAH) in zinc phosphate baths. (author)

  8. Dosimetric analysis of daily use of IGRT in prostate treatment with intensity modulated; Analise dosimetrica da utilizacao diaria de IGRT no tratamento de prostata com intensidade modulada

    Energy Technology Data Exchange (ETDEWEB)

    Sandrini, E.S.; Silveira, T.B.; Vieira, D.S.; Batista, D.V.S., E-mail: emmilyfisica@gmail.com [Instituto Nacional de Cancer Jose de Alencar Gomes da Silva, Rio de Janeiro, RJ (Brazil)

    2014-12-15

    The main application of image-guided radiotherapy (IGRT) in the cancer prostate treatment is to ensure the delivery of the prescribed dose to the tumor. With the modality cone beam computed tomography (CBCT) prostate, seminal vesicles, bladder and rectum can be previewed before each treatment and the actual dose delivered to these organs can be controlled, through the alignment of patient isocenter. The aim of this study was to analyze the tumor coverage and dose to organs at risk effectively obtained during the patient's treatment. Three patients with prostate cancer were treated with intensity modulated radiotherapy (IMRT) or volumetric modulated arc radiotherapy (VMAT) techniques with 74 Gy and 2 Gy per fraction. It was performed daily isocenter location of the prostate with CBCT. A radioncologist drew the clinical target volume (CTV), rectum and bladder in CBCT's and treatment fields were applied retrospectively in each CBCT for dose calculation. For the CTV it was considered the D95 (dose that covers 95% of the volume), for the rectum V50 (volume receiving 50 Gy), V60, V65 and V70 and for bladder V65 and V70. The average D95 of the prostate after the offset was 202 cGy, the V50, V60 and V65 of the rectum for one patient was reduced by 9.6%, 16.6% and 31%, respectively, and V65 of the bladder to another patient was also reduced by 3.5% in IGRT. The results showed that the use of IGRT provided a reduction in the irradiated volume of healthy organs. Thus it is concluded that the use of daily CBCT allows reproducibility of treatment, reducing delayed toxicities and increasing the probability of tumor control. (author)

  9. Virtual reality technology used to estimate radiation doses in nuclear installations; Utilizacao de ambientes virtuais na estimativa de dose de radiacao em instalacoes nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Augusto, Silas Cordeiro

    2008-03-15

    The physical integrity of people when walking in places subjected to radiation can be preserved by following some rules. Among these rules are safe limits of radiation level, proximity of radiation sources, time of exposition to radiation sources, and a combination of these factors. In this way, previous training and simulations of operation proceedings to be executed in places subjected to radiation help to better prepare the course in such places, minimizing the absorbed dose. On the other hand, virtual reality is a technology applicable in several areas, enabling the training and simulation of real places and hypothetical scenarios, with a good level of realism, but without danger if compared to the same activities in the real world. As a virtual environment does not presents any health risks, it is possible to train workers beforehand to several operation or maintenance scenarios. In this virtual environment, the dose tax distribution can be visualized, and the dose absorbed by the worker, represented and simulated in the virtual environment by a virtual character (avatar) can be shown. Therefore, the tasks to be done can be better planned, evaluating the workers actions and the performance so to reduce failures and health risks. Finally, this work presents a tool to build and navigate in virtual environments, enabling the training of activities in nuclear facilities. To that end is proposed a methodology to modify and adapt a free game engine. (author)

  10. Overview of use of natural gas on heavy duty vehicles in Brazil; Panorama da utilizacao do gas natural veicular em veiculos pesados no Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Machado, Guilherme Bastos; Melo, Tadeu Cavalcante Cordeiro de [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES). Area de Desempenho de Produtos em Motores; Lastres, Luiz Fernando Martins [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES). Gerencia de Lubrificantes e Produtos Especiais

    2004-07-01

    The use of vehicular natural gas (VNG) was initiated in Brazil in he 80's seeking the replacement of diesel in heavy vehicles due to the oil crisis. In this season PETROBRAS participated, along with other companies, in the development of conversion technologies for replacement part of the diesel by natural gas through systems known as diesel-gas. Were made works to development bank of tests of engines and field tests on some bus companies, verifying if there are technical and economic viability of such conversion. Due to factors such as small mesh distribution of natural gas in Brazil, lack of infrastructure of technical support suitable for conversions and lack of culture in the use of natural gas, the program not progressed and experience was interrupted. Other experiments were conducted in Brazil with the use of engines dedicated to natural gas (Otto cycle) developed and manufactured in the country for use in urban buses. Currently there is a scenario favorable to the return of use of natural gas in weighed vehicles by the following factors: 1) increase the mesh distribution of VNG due to the high growth of the fleet light vehicles to VNG in the country, solving part of the problems of logistics; 2) pressure from environmental agencies by values of emissions of particles and gases ever less pollutants in urban centers; 3) excess supply of natural gas in the domestic market due to new discoveries in Brazil, contracts for the import of natural gas signed with Bolivia and low demand for current industrial consumption of gas; 4) need to replace the import of diesel, which weighs in trade of the country. This paper will be presented some experiences with the technology of diesel-gas and the engine dedicated the VNG in weighed vehicles in Brazil. Also some recommendations will be made to increase and spread the use of these technologies, aiming to increase the replacement of diesel by vehicular natural gas in weighed vehicles. (author)

  11. Adsorptive refrigeration system using a solar collector with a thermal insulating module; Sistema de refrigeracao adsortivo com a utilizacao de um coletor solar com anteparo otico

    Energy Technology Data Exchange (ETDEWEB)

    Gurgel, Jose Mauricio [Paraiba Univ., Joao Pessoa, PB (Brazil). Laboratorio de Energia Solar]. E-mail: gurgel@les.ufpb.br; Espinola Junior, Jose [Paraiba Univ., Joao Pessoa, PB (Brazil). Curso de Pos-Graduacao em Engenharia Mecanica; Andrade Filho, Luiz Simao [Paraiba Univ., Joao Pessoa, PB (Brazil). Centro de Tecnologia. Dept. de Tecnologia da Construcao Civil; Marcondes, Francisco [Paraiba Univ., Joao Pessoa, PB (Brazil). Escola de Engenharia. Dept. de Engenharia Mecanica

    2000-07-01

    The use of a solid adsorption cooling unit based on the binary silica gel/water couple constitute an very promising way to harness solar energy refrigeration purposes. Here is presented a mathematical model for the simulation of the system under several use conditions and it was shown coherent when compared with some experimental results. The several accomplished simulations showed the need to be projected a modulate reactor that can offer cooling easiness during the night period and shown the advantage of the use of an solar collector that can be easily opened and your thermal insulating module placed across the glass close the thermal radiation when the desorption process finish. The simulations results presented here shown an better COP for this configuration through an better cooling of the collector at night. (author)

  12. Using of sawing quartzite fine residual for obtaining ceramic coating; Utilizacao do residuo fino da serragem de quartzito para obtencao de revestimento ceramico

    Energy Technology Data Exchange (ETDEWEB)

    Nobrega, L.F.P.M.; Souza, M.M., E-mail: junior.luiz09@hotmail.com [Universidade Federal do Rio Grande do Norte (DIAREN/UFRN), Natal, RN (Brazil). Laboratorio de Processamento Mineral e Residuo

    2016-07-01

    Quartzite is a metamorphic rock that is consisting mainly of quartz. In Paraiba there is a mining activity of this rock, in the region of Varzea and Junco do Serido especially where many wastes are created, including the sawing residue. The objective is to use the waste cited as the ceramic component coating mass, thereby replacing the quartz. Initially, the raw materials samples were taken and the chemical analysis was done of them. This passed the comminution process to achieve the required minimum particle size. After this, a formulation which added the residue in ceramic mass was made. The specimens were subjected to sintering and it was later made physical tests according to NBR 13818. The results show that the residue can replace the quartz ceramic mass successfully, but not as good as the original raw material. (author)

  13. Optimization of the k-edge filters utilization in the dental radiographs; Otimizacao da utilizacao dos filtros de aresta K na radiografias dentarias

    Energy Technology Data Exchange (ETDEWEB)

    Reyes, Luis M.G.; Almeida, Adelaide de [Sao Paulo Univ., Ribeirao Preto, SP (Brazil). Faculdade de Filosofia, Ciencias e Letras. Dept. de Fisica e Matematica

    2001-07-01

    The signal to noise ratio (S/N) of radiographic film images may be optimized if the thicknesses and atomic composition of the structures to be analyzed are known. With specifications and a knowledge of the interaction of photons with the materials, the photon energy for maximum contrast may be determined. We propose a K-edge filter in addition to the normal aluminum filter, to reduce the dose to the patient by the transmission of a narrow spectrum of photons with energies to optimize the image contrast. The optimum photon energy to obtain the best contrast between dental pulp and dentine and between dentine and dental enamel was determined to be 29-34 and 22-26 keV respectively. The filter material, which closely approximates these spectra, is made of Ce (Z=58) whose thickness is shown do depend on the parameters of the X-ray generator. (author)

  14. Radiation therapy for the treatment of feline advanced cutaneous squamous cell carcinoma; A utilizacao da radioterapia no tratamento do carcinoma de celulas escamosas cutaneo felino avancado

    Energy Technology Data Exchange (ETDEWEB)

    Cunha, S.C.S.; Corgozinho, K.B.; Ferreira, A.M.R, E-mail: simonecsc@gmail.com [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil); Carvalho, L.A.V. [Coordenacao dos Programas de Pos-Graduacao em Engenharia (COPPE/UFRJ), RJ (Brazil); Holguin, P.G.

    2014-02-15

    The efficacy of radiation therapy for feline advanced cutaneous squamous cell carcinoma was evaluated. A full course radiation therapy protocol was applied to six cats showing single or multiple facial squamous cell carcinomas, in a total of seven histologically confirmed neoplastic lesions. Of the lesions, one was staged as T{sub 1}, and six as T{sub 4} according to WHO staging system of epidermal tumors. The animals were submitted to twelve radiation fractions of 4 Gy each, on a Monday-Wednesday-Friday schedule, and the equipment used was an orthovoltage unit. Energy used was 120 kV, 15 mA and 2 mm aluminum filter. The cats were evaluated during the treatment and 30 and 60 days after the end of the radiation therapy. In this study, 87% of the lesions had complete remission and 13% partial remission to the treatment. Side effects were considered mild according to Veterinary Radiation Therapy Oncology Group Toxicity criteria, and included erythema, epilation and rhinitis. Radiation Therapy was considered safe for feline cutaneous squamous cell carcinoma, leading to mild side effects and can represent a good therapeutic option. (author)

  15. Time response of temperature sensors using neural networks; Utilizacao de redes neurais artificiais para determinar o tempo de resposta de sensores de temperatura do tipo RTD

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Roberto Carlos dos

    2010-07-01

    In a PWR nuclear power plant, the primary coolant temperature and feedwater temperature are measured using RTDs (Resistance Temperature Detectors). These RTDs typically feed the plant's control and safety systems and must, therefore, be very accurate and have good dynamic performance. The response time of RTDs is characterized by a single parameter called the Plunge Time Constant defined as the time it takes the sensor output to achieve 63.2 percent of its final value after a step change in temperature. Nuclear reactor service conditions are difficult to reproduce in the laboratory, and an in-situ test method called LCSR (Loop Current Step Response) test was developed to measure remotely the response time of RTDs. >From this test, the time constant of the sensor is identified by means of the LCSR transformation that involves the dynamic response modal time constants determination using a nodal heat-transfer model. This calculation is not simple and requires specialized personnel. For this reason an Artificial Neural Network has been developed to predict the time constant of RTD from LCSR test transient. It eliminates the transformations involved in the LCSR application. A series of LCSR tests on RTDs generates the response transients of the sensors, the input data of the networks. Plunge tests are used to determine the time constants of the RTDs, the desired output of the ANN, trained using these sets of input/output data. This methodology was firstly applied to theoretical data simulating 10 RTDs with different time constant values, resulting in an average error of about 0.74 %. Experimental data from three different RTDs was used to predict time constant resulting in a maximum error of 3,34 %. The time constants values predicted from ANN were compared with those obtained from traditional way resulting in an average error of about 18 % and that shows the network is able to predict accurately the sensor time constant. (author)

  16. Electrical energy use in different heating systems for weaned piglets; Utilizacao de energia eletrica em diferentes sistemas de aquecimento para leitoes desmamados

    Energy Technology Data Exchange (ETDEWEB)

    Sarubbi, Juliana [Universidade Federal de Santa Maria (CESNORS/UFSM), Palmeiras das Missoes, RS (Brazil). Centro de Educacao Superior Norte-RS. Dept. de Zootecnia], E-mail: jusarubbi@hotmail.com; Rossi, Luiz A.; Moura, Daniella J. de; Oliveira, Rafael A. de; David, Eduardo [Universidade Estadual de Campinas (FEAGRI/UNICAMP), SP (Brazil). Fac. de Engenharia Agricola], Emails: rossi@agr.unicamp.br, daniella.moura@agr.unicamp.br, augustus@agr.unicamp.br, eduardo.david@agr.unicamp.br

    2010-11-15

    Heating piglets in nursery and farrowing may be improved to save energy, without affecting the animals' welfare. The objective of this research was to compare the electrical energy use and thermal environment promoted by three heating technologies for piglets in nursery. The heating technologies studied were: suspended electrical resistors, heated floor and convection heating. Electrical energy consumption (kWh), maximum power demand requirements (kW), specific consumption (kWh/kg of produced live body weight), efficiency of heating system (deg C /m{sup 3} air) and dry-bulb temperature (deg C) and temperature-humidity index were evaluated. The heated floor system was better under the aspect of electrical energy use. The electrical resistance heating system was the best regarding to the animals' thermal comfort needs. (author)

  17. Economic viability for electrical power generation using biogas produced in swine grange; Viabilidade economica da utilizacao do biogas produzido em granja suinicola para geracao de energia eletrica

    Energy Technology Data Exchange (ETDEWEB)

    Cervi, Ricardo G. [Universidade Estadual Paulista (FCA/UNESP), Vale do Ribeira, SP (Brazil). Fac. de Ciencias Agrarias], e-mail: rghantous@registro.unesp.br; Esperancini, Maura S.T.; Bueno, Osmar de C. [Universidade Estadual Paulista (DGTA/FCA/UNESP), Botucatu, SP (Brazil). Fac. de Ciencias Agrarias. Dept. de Gestao e Tecnologia Agroindustrial], e-mails: maura@fca.unesp.br, osmar@fca.unesp.br

    2010-09-15

    Biogas production through anaerobic bio digestion represents an important breakthrough for the problem of swine waste and energy availability for rural areas. This work aimed to develop a study to estimate the economic viability of a bio integrated system installation and operation to produce electricity from swine wastes. Data for the study were collected in an agroindustry where there are plenty of agricultural activities; however the swine production activity was selected for the anaerobic digestion process because it generates a large amount of waste, with a limited provision in the environment, which characterizes a case study. The analyzed bio digester is a continuous tubular model with brick concrete duct and plastic covering with a gamester, and where the waste of 2,300 fattening pigs are deposited daily. The initial investment estimate for the installation was R$ 51,537.17. The system annual costs were R$ 5.708,20, for maintenance, R$ 4,390.40 for depreciation and R$ 1,366.77 for interests. It was concluded that the bio integrated system would achieve favorable economic results if the energy consumption were to 35 k W per hour a day, in average, where the net present value (NPV) is R$ 9,494.90 and the internal rate of return (IRR) is 9,34% per year. (author)

  18. Quantitative computed tomography as a test of endurance for evaluation of bony plates; Utilizacao da tomografia computadorizada quantitativa como teste de resistencia para avaliacao de placas osseas

    Energy Technology Data Exchange (ETDEWEB)

    Melo Filho, E.V.; Costa, L.A.V.S.; Oliveira, D.C. [Universidade Federal do Parana (UFPR), Curitiba, PR (Brazil); Freitas, P.M.C. [Escola de Veterinaria - Universidade Federal de Minas Gerais - Belo Horizonte, MG (Brazil); Teixeira, M.W.; Costa, F.S. [Universidade Federal Rural de Pernambuco - Recife, PE (Brazil)

    2012-06-15

    Quantitative computed tomography was used to determine the radiodensity of bony plates. The CT scans provided information regarding radiodensity of bony plates and allowed to verify the uniformity of bone mineral density in their scope. The proposed methodology should be considered as another tool for determining the resistance of these biomaterials. (author)

  19. Use of different simulators to quality evaluation of image quality in digital mammography; Utilizacao de diferentes simuladores na avaliacao da qualidade da imagem em mamografia digital

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, Leslie S.; Coutinho, Celia M.C., E-mail: leslie@ird.gov.br, E-mail: celia@ird.gov.br [Instituto de Radioprotecao e Dosimetria (IRD/CNEN-RJ), Rio de Janeiro, RJ (Brazil); Magalhaes, Luis A.G.; Almeida, Carlos Eduardo de, E-mail: luisalexandregm@hotmail.com, E-mail: cea71@yahoo.com.br [Universidade do Estado do Rio de Janeiro (LCR/UERJ), Rio de Janeiro, RJ (Brazil). Laboratorio de Ciencias Radiologicas

    2013-11-01

    In this study, the digital images were acquired with different exposure simulators to evaluate the quality of the image, noting the tumor mass detection, microcalcification fiber and representing regions of interest during mammography. The technical parameters of exposure depends on the thickness and composition of the breast, thus affecting the dose and image quality. The simulators were used: ACR, SBP 1054, BREAST PHANTOM CIRS and for evaluation of image quality, as well as measures kerma incident on the entrance surface (Ki) and calculating the mean glandular dose (MGD)

  20. Development of a ceramic material to cover walls to be applied in diagnostic radiological protection; Desenvolvimento de um material ceramico para utilizacao em protecao radiologica diagnostica

    Energy Technology Data Exchange (ETDEWEB)

    Frimaio, Audrew

    2006-07-01

    This study aims to formulate a ceramic composition for wall coating seeking to contribute to the optimization of diagnosis rooms' shielding. The work was based on experimental measures of X-radiation attenuation (80 and 100 kV) using ceramic coating materials containing different ceramic bases (red, white, gres, stoneware porcelain tiles, etc). Among the appraised ceramic bases, the white gres presented better attenuation properties and it was considered the most suitable material for the targets of this work. Different formulations of white gres were studied and altered in order to obtain better attenuation properties. Simulations of ceramic compositions using gres coating were made maintaining the percentages of 12-20% clay; 6-18% kaolin; 12-25% phyllite; 8-14% quartz; 1018% feldspar; 32-40% pegmatite and 6-8% talc in the composition of the necessary raw-material. The quantitative and qualitative chemical compositions of these materials were also evaluated and the most common representative elements are SiO{sub 2}, Fe{sub 2}O{sub 3}, Al{sub 2}O{sub 3}, CaO and Ti{sub 2}O{sub 3}. Formulations containing Pb and Ba oxides were studied, considering that CaO can be replaced by PbO or BaO. The attenuation properties for X-radiation were investigated by computer simulations considering the incident and transmitted X-ray spectra for the different studied compositions and they were compared to the properties of the reference materials Pb, Ba and BaSO{sub 4} (barite). The results obtained with the simulations indicated the formulated composition of gres ceramic base that presented better attenuation properties considering the X-ray energies used in diagnosis (80, 100 and 150 kV). Ceramic plates based on the formulated compositions that presented lower percentage differences related to Pb were experimentally produced and physically tested as wall coating and protecting barrier. Properties as flexion resistance module, density, load rupture, water absorption and X radiation attenuation were evaluated for all produced plates. (author)

  1. Use of fluorescence spectroscopy to measure molecular autofluorescence in diabetic subjects; Utilizacao da espectroscopia de fluorescencia para mensuramento de moleculas autofluorescentes em individuos diabeticos

    Energy Technology Data Exchange (ETDEWEB)

    Gomes, Cinthia Zanini

    2011-07-01

    Diabetes Mellitus (DM) comprises a complex metabolic syndrome, caused by reduced or absent secretion of insulin by pancreatic beta cells, leading to hyperglycemia. Hyperglycemia promotes glycation of proteins and, consequently, the appearance of advanced glycation end products (AGEs). Currently, diabetic patients are monitored by determining levels of glucose and glycated hemoglobin (HbA1c). The complications caused by hyperglycemia may be divided into micro and macrovascular complications, represented by retinopathy, nephropathy, neuropathy and cardiovascular disease. Albumin (HSA) is the most abundant serum protein in the human body and is subject to glycation. The Protoporphyrin IX (PpIX) is the precursor molecule of heme synthesis, structural component of hemoglobin. The in vitro and animals studies have indicated that hyperglycemia promotes a decrease in its concentration in erythrocytes. The fluorescence spectroscopy is a technique widely used in biomedical field. The autofluorescence corresponds to the intrinsic fluorescence present in some molecules, this being associated with the same structure. The aim of this study was to use fluorescence spectroscopy to measure levels of erythrocyte PpIX autofluorescence and AGE-HSA in diabetic and healthy subjects and compare them with levels of blood glucose and HbA1c. This study was conducted with 151 subjects (58 controls and 93 diabetics). Epidemiological data of patients and controls were obtained from medical records. For control subjects, blood glucose levels were obtained from medical records and levels of Hb1Ac obtained by using commercial kits. The determination of the PpIX autofluorescence was performed with excitation at 405 nm and emission at 632 nm. Determination of AGE-HSA was performed with excitation at 370 nm and emission at 455 nm. Approximately 50% of diabetic had micro and macrovascular lesions resulting from hyperglycemia. There were no significant differences in the PpIX emission intensity values between groups (P = 0.89). In the analysis of AGE-HSA was observed significant differences in the values of emission intensity between the two groups, and this value was 1.45-fold greater for the group of diabetic (P <0.0001). Patients with diabetic complications had fluorescence emission intensity of 1.19-fold higher than individuals without disease complications (P = 0.01), even with no significant differences in HbA1c values between the two groups. We conclude that fluorescence spectroscopy was an effective technique in the identification of the PpIX autofluorescence and AGE-HSA. The PpIX was not an effective biomarker for the monitoring of diabetes. The determination of AGE-HSA autofluorescence was efficient for the discrimination between groups and monitoring disease progression, may be more effective than HbA1c dosage. The fluorescence spectroscopy is a simple, fast and low cost for the monitoring of diabetic patients. (author)

  2. Technological evaluation of fuel cells using natural gas for distributed power generation; Avaliacao tecnologica da utilizacao de gas natural em celulas a combustivel para geracao distribuida de energia

    Energy Technology Data Exchange (ETDEWEB)

    Brandao, Mauricio O. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-Graduacao de Engenharia (COPPE). Programa de Engenharia Mecanica; Giannini, Marcio P.; Arouca, Mauricio C. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-Graduacao de Engenharia (COPPE). Programa de Planejamento Energetico

    2004-07-01

    The search for sustainable and more rational means of power generation motivates the scientific crew to search for more efficient and cleaner systems. Oil dependence becomes from the kind of development that the humanity had and cannot be dismissed. The question is how to use this source in a more intelligent way. Fuel Cells are electrochemical devices that convert into electric energy the chemical energy from oxi-reduction reactions between a fuel and an oxidant. The current fuel used in a Fuel Cell is hydrogen and oxygen is the oxidant. The great advantage of this device is its efficiency, higher than the one achieved with internal combustion engines. Also Fuel Cells are not limited by Carnot's efficiency. This paper is about the implementation of a distributed generation system using Fuel Cells. Technical aspects are approached together with economical and environmental needs. The already existence of Gas pipelines and the grown production of Natural Gas presented by Brazil turns it into a good market for the implementation of this energy source. The evaluation of this paper shows that is technically possible to use NG in Fuel Cells, mostly in South and Southeast regions, applying the distributed generation of energy concept. The most interesting in a strategic manner is that Brazil already have an indication that it's capable of developing this technology, opening a new market tuning with world's new technological developments. Many research centers develop this technology, not only from the cell composition itself, but also manufacturing techniques. (author)

  3. Economical analysis of the use of biogas in swine production for generation of electric energy; Analise economica da utilizacao do biogas na suinocultura para geracao de energia eletrica

    Energy Technology Data Exchange (ETDEWEB)

    Martins, Franco Muller; Oliveira, Paulo Armando Victoria de [EMBRAPA Suinos e Aves, Concordia, SC (Brazil)], Emails: franco@cnpsa.embrapa.br, paolive@cnpsa.embrapa.br

    2009-07-01

    The demand for alternative sources of energy has been growing in the last years in function of the variation on the prices of petroleum and the recent energy crisis. The anaerobic bio digestion can convert swine manure in biogas. In the present work it was studied the economic viability of the use of the biogas as alternative source for the generation of electric energy in different demand levels. The methodology utilized was the Net Present Value. The study showed that the utilization of biogas as electric energy source is economically feasible. The increase of the demand of electric energy, in the property, associated to the increase of the price of the electric energy, increases the economical profits and accelerates the time of return of the investments. (author)

  4. The utilization of natural gas in the electricity production through fuel cell; A utilizacao do gas natural na geracao distribuida atraves de celulas combustiveis

    Energy Technology Data Exchange (ETDEWEB)

    Bernardi Junior, Paulo

    2004-07-01

    In function of the necessity of electric energy as input of vital importance for the development of the country, this work aims at to offer plus an energy alternative for Brazil. The exploitation of the natural gas reserves recently discovered can be made through modern methods that give as priority the distributed generation and the low ambient impact. All these aspects can be gotten with the use of fuel cell, working with the remodelled natural gas. Increased to the factor of a low ambient impact in the proper generation, the project suggests that the generating source can be located next the consumer, diminishing still more the problems generated for transmission lines, fuel transport, etc. The fuel cell has received a great attention in the international community and some models, some already in commercial period of training, they have shown excellent possibilities of capsize to be one of the future technologies in the generation of electric energy with low ambient impact. (author)

  5. Utilization of the arbitration in contracts of unitization in a petroleum industry; Utilizacao da arbitragem nos contratos de unitizacao na industria do petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Franca Junior, Carlos Antonio de [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

    2008-07-01

    The present work has like goal to show some controversies generated for the only paragraph of article 27 of the Law of the Oil. The legal device admits when it will not have the celebration of an agreement of unitization between the concessionaires, the use of an arbitral decision as instrument for ANP to solve the conflict. On this term - arbitral decision - we will find a lot of interpretations. To accept a mere literal interpretation is to attack the proper characteristics of the Arbitration - as way of solution of conflicts -, as well as infringing our constitutional and legal text. But, the best exit is not this; therefore using an interpretation in conformity with the constitution we obtain to adapt the norm to our constitutional system, in a rational way. Thus, the object of this work is to search elements to adjust the norm referred to our legal system. For this, we will see a examination concerning the Arbitration, as well as of Contracts of Unitization, for at a second moment discerning on the quarrels between these two subjects, in view of the Law of the Oil and the doctrine of the Oil Law. (author)

  6. Flexibility in using Diesel or biodiesel: an approach via real options; Flexibilidade na utilizacao de Diesel ou biodiesel: uma abordagem via opcoes reais

    Energy Technology Data Exchange (ETDEWEB)

    Goncalves, Edson Daniel Lopes [Fundacao Getulio Vargas, Rio de Janeiro, RJ (Brazil)]. E-mail: edson@fgvmail.br; Ferreira, Leonardo Leandro [PETROBRAS, Rio de Janeiro, RJ (Brazil)]. E-mail: leonardo.ferreira@petrobras.com.br

    2008-09-15

    This work will approach the bio diesel development as renewable source fuel in the Brazilian energetic matrix. Essentially, the utilization flexibility will be considered between the traditional petroleum origin Diesel and the vegetable origin Biodiesel. So, our target is the evaluation of the flexibility existent between those two fuels. A consideration will be made via real options, where the fuel choice for supplying is modelled as a an european options sequence. Those switch input real options attributes a value to the project and minimizes the risks associated to the energy offer shortage which is another recurrent problem inside our reality. At least, some comments will be made on the potential gain on the aggregate value for the Brazil, as a consequence of Diesel dependent road transportation.

  7. Characterization of cellulose biomass for use as an excipient in pharmaceutical field; Caracterizacao de biomassa de celulose para utilizacao como excipiente na area farmaceutica

    Energy Technology Data Exchange (ETDEWEB)

    Garcia, Keth R.; Turella, Tais C.; Santos, Venina dos; Brandalise, Rosmary N. [Universidade de Caxias do Sul (UCS), Caxias do Sul, RS (Brazil). Centro de Ciencias Exatas e da Tecnologia; Angeli, Valeria W., E-mail: rnbranda@ucs.br [Universidade de Caxias do Sul (UCS), Caxias do Sul, RS (Brazil). Centro de Ciencias Biologicas e da Saude

    2015-07-01

    Every day the industry of paper and cellulose discards large amounts of waste. An alternative to reuse this kind of biomass is to transform part of it in cellulose nanocrystals and nanofibrils to be used as excipients in pharmaceutical field. Thus, cellulose fibrils were obtained in nanoscale using mill and fibrils' characterization study were performed by scanning electron microscopy, transmission electron microscopy, thermal analysis, differential scanning calorimetry, infrared Fourier transform and X-rays diffraction. Hence, the methodology used to obtain and characterize nanocellulose was effective and the fibers/fibrils lengths are in nanometer dimension with high potential to apply in the pharmaceutical field. (author)

  8. Hybrid environmental robot: a tool for monitoring gas on flooded area; Robo ambiental hibrido: utilizacao como ferramenta para monitoramento de gases em areas alagadas

    Energy Technology Data Exchange (ETDEWEB)

    Goes, Emerson de; Cerqueira, Romulo Curty; Reis, Ney Robinson S. [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2008-07-01

    The impoundment of rivers for power generation leads to flooding of vast areas of land vegetation. Most submerged plants, die and enter into decomposition, releasing CO2 (carbon dioxide), CH4 (methane gas) into the air for many years. Scientists from around the world seek to clarify the processes to which these gases are submitted and their contributions to the process of global warming. Estimates suggest that the re-use of methane that passes through the turbines of these power plants could increase their energy potential by 75% and reduce their emissions of these gases by 65%, reducing their impact on global warming and resulting in carbon credits. To check the feasibility of using new processes and technologies to generate energy that recycles this biogas, operations for monitoring these biogases become routine tasks. The frequency is such that the exposure of humans to the risks of gas combustion, inherent to scenarios where these operations take place, becomes unacceptable. This motivates the use of robots in this activity. This paper presents the multi-mission platform Hybrid Environmental Robot, named 'Chico Mendes', as a tool for tracking gas emission and specially designed for flooded forest areas.

  9. Use of gamma probe in {sup 131}I thyroid uptake studies; Utilizacao da sonda a cintilacao na captacao de {sup 131}I pela tireoide

    Energy Technology Data Exchange (ETDEWEB)

    Sarmento, Andrea Gondim Leitao

    2002-11-01

    Evaluation of thyroid uptake by administration of radioactive iodine is a well-defined procedure to assess patient thyroid function. In general, nuclear medicine institutions use gamma cameras coupled to pinhole collimators to perform uptake studies. With the growing use of intraoperative gamma probes in the radioguided surgical techniques, several institutions are purchasing this new and portable equipment, which can technically be also employed to assess patient's thyroid function, permitting further other applications of gamma cameras. The aim of the study was to compare thyroid uptake trails carried out with both gamma camera and intraoperative gamma probe, in order to evaluate the possible use of gamma probe for this purpose. At first a preliminary study of feasibility was carried out using a neck phantom to verify equipment efficiency with known activities of {sup 131} I. Henceforth, work data from 12 patients undergone studies of thyroid uptakes were evaluated, 24 hours after oral administration of 370 kBq of {sup 131} I. The maximum difference observed between the values obtained with both equipment was 60%, which demonstrated the feasibility of the proposed protocol and made clear that gamma probe can be useful for thyroid uptake studies. (author)

  10. Utilization of ultraviolet radiation in effluent disinfestation of domestic waste treatment systems; Utilizacao da radiacao ultravioleta na desinfeccao de efluentes de sistemas de tratamento de esgotos domesticos

    Energy Technology Data Exchange (ETDEWEB)

    Camacho, P.R.R. [Companhia de Tecnologia de Saneamento Ambiental, Sao Paulo, SP (Brazil); Andrade e Silva, L.G. de [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)

    1995-12-31

    Ultraviolet radiation disinfection of Upflow Anaerobic Sludge Biodigestor (UASB) and UASB with aerated lagoon pos-treatment effluents is possible to be reached utilizing a single low pressure mercury lamp arc (15 W nominal power) in a shell tube flow through reactor (1.2 L useful volume). Fecal coliforms, total coliforms and colifages were used as microbiological parameters. For fecal coliforms, about 3 logarithmic units (log. un.) was removed from UASB with aerated lagoon pos-treatment effluent and 4 log. un. from UASB effluent with 7 and 30 seconds of hydraulic retention time, respectively. Good empirical correlations were obtained between microbiological parameters and hydraulic retention times. (author). 4 refs, 1 fig, 3 tabs.

  11. Use of gamma probe in {sup 131}I thyroid uptake studies; Utilizacao da sonda a cintilacao na captacao de {sup 131}I pela tireoide

    Energy Technology Data Exchange (ETDEWEB)

    Sarmento, Andrea Gondim Leitao

    2002-11-01

    Evaluation of thyroid uptake by administration of radioactive iodine is a well-defined procedure to assess patient thyroid function. In general, nuclear medicine institutions use gamma cameras coupled to pinhole collimators to perform uptake studies. With the growing use of intraoperative gamma probes in the radioguided surgical techniques, several institutions are purchasing this new and portable equipment, which can technically be also employed to assess patient's thyroid function, permitting further other applications of gamma cameras. The aim of the study was to compare thyroid uptake trails carried out with both gamma camera and intraoperative gamma probe, in order to evaluate the possible use of gamma probe for this purpose. At first a preliminary study of feasibility was carried out using a neck phantom to verify equipment efficiency with known activities of {sup 131} I. Henceforth, work data from 12 patients undergone studies of thyroid uptakes were evaluated, 24 hours after oral administration of 370 kBq of {sup 131} I. The maximum difference observed between the values obtained with both equipment was 60%, which demonstrated the feasibility of the proposed protocol and made clear that gamma probe can be useful for thyroid uptake studies. (author)

  12. Preparatory of X zeolite (faujasite) with surfactant hexa decyl trimethyl ammonium bromide (HMDTA) for adsorption of organic compounds; Acondicionamiento de zeolita X (faujasita) con surfactante bromuro de hexa decil trimetil amonio (HDTMA) para adsorcion de compuestos organicos

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez R, V

    2003-07-01

    The water represents one of the most valuable natural resources for the alive beings, since it is the essential component of the alive matter. Also, it is fundamental part of our planet, since is an indispensable element for the integral development of the same one. The demographic growth, the human being's activities and the industrial growth, he/she brings as consequence an increase in the use of the water and the generation of residual waters that successively contaminate the hydrological basins, becoming an environmental problem urgent. The contamination of the water with compound such as phenol and benzene, it is a problem that it requires the search of solutions, since it is of compound not very biodegradable, able to accumulate through the food chains and very toxic to the alive beings that they enter in contact with them (Tolgyessy, 1993). In the human beings it can take place damages in liver and kidney, the Agency of Protection to the Atmosphere of the United States (EPA) it considers that the exhibition for benzene is related with the leukemia, it is also considered as a carcinogen substance. Of the methods that are used for the treatment of polluted waters, it highlights the use of adsorber and one of them is the zeolites, since they are broadly used in those separation processes. The zeolites is crystalline aluminosilicates, they are characterized for to have a big superficial area and for their great capacity of exchange cationic, due to it the process of adsorption depends on these two characteristics, since to the modified being superficially for surfactants cationic it originates an enriched layer of carbon organic, which has the capacity to remove pollutants of the water. The present work outlines as objective to carry out the superficial modification of zeolite X using hexa decyl trimethyl ammonium bromide (HMDTA-Br) to different concentrations, with the purpose of making it useful in the removal of pollutants organic, present in watery solution. The results of this investigation work indicate that the superficial modification of the zeolite X with HMDTA-Br to the four used concentrations 29, 58, 116 and 174 mmol L was possible, and it is demonstrated by the results of electronic microscopy of sweeping and for the decrease of the content of sodium carried out by Neutron activation analysis. In relation to the removal tests, it was found that the zeolite modified X with the biggest surfactant concentration it presents the highest phenol percentage removed, being this of 38% for a time of contact of 3 hours. In accordance with the results of removal of benzene is observed that the zeolite X removes 56%, but the modified zeolite removes a bigger quantity of until 90%, said percentage varies with regard to the time of contact. Therefore the modification of the zeolite X is favorable for the removal of the benzene. (Author)

  13. Sub products form a depuratives process of acid mine water with organic residues used as carbon source. part I; Subproductos en la depuracion de aguas acidas de mineria y empleo de residuos organicos como fuente carbonada, Parte I

    Energy Technology Data Exchange (ETDEWEB)

    Jimenez-Rodriguez, A. M.; Duran-Barrantes, M. M.; Martel-Villagran, F. J.

    2002-07-01

    Subproducts from the biological depurative process of acid mine water, such as H{sub 2}S in the biogas and HCO{sub 3} in the effluents are applied for the selective precipitation of metallic sulphides of Pb, Zn, Cu, Al an Mn, as a function of pH. To obtain the maximum H{sub 2}S concentration is principal,so several studies have been made to found the best working conditions between microorganisms and the carbon source choice. In this work,the results of the digestion process with an inoculum from the anaerobic digestion of swine manure and cheese whey as carbon source are showed. The optimal conditions obtained are: for a SO{sub 4}''=COD of 1:1,5 in HRT of 12 days, 65% of sulphate reduction, 30% of H2S in biogas. In the precipitation of metals, a reduction of 98,3% of Fe, 96,1% Cu, 79% Zn and 99% Al are obtained. AYESA (Aguas y Estructuras, S. A.) is developing the technical attendance. This study is being demonstrated under the Acid Water Treatment Program, conducted by the Consejeria del Medio Ambiente (Junta de Andalucia). (Author) 15 refs.

  14. Controlling factors in the dynamics of soil organic carbon from the region of Murcia; Factores de control en la dinamica del Carbono Organico de los suelos de la Region de Murcia

    Energy Technology Data Exchange (ETDEWEB)

    Albaladejo, J.; Martinez-Mena, M.; Almagro, M.; Ruiz-navarro, A.; Ortiz, R.

    2009-07-01

    Sequestration and accumulation of C on the soil is a useful way to reduce the atmospheric concentration of CO{sub 2} and to mitigate the climate change. The purpose of this study was to identify the key factors which determine the accumulation and permanence of CO on the soils of the Murcia Region. The study was arranged from data displayed on the Murcia Region Soils Map (1:100.000). The results showed that quantity of stored CO in the 30cm superficial soil is significantly different depending on soil uses, soil type, altitude and texture. One conclusion is that changes from natural vegetation to cultivated soil are the greatest cause of losses of CO of soil. The increasing of altitude and proportion of thin-silt + clay contributes to CE accumulation. In altitude, the speed of mineralization of organic materials decreases, and the thin particles stimulate the physical protection and the chemical stabilization of CO of soil. (Author) 8 refs.

  15. Evaluation of toxicity to the biological treatment and removal of recalcitrant organic compounds from oil refineries wastewaters; Avaliacao da toxicidade ao tratamento biologico e remocao de compostos organicos recalcitrantes existentes em efluentes de refinarias de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Barros Junior, Laerte M.; Macedo, Gorete R.; Bezerra, Marcio S.; Pereira, Franklin M.S. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Dept. de Engenharia Quimica; Schmidell, Willibaldo [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil)

    2004-07-01

    Oil industry waste water usually contains recalcitrant chemical compounds, like phenol, benzene, toluene, xylene, naphthalene and acenaphthene. The respirometry, determination of respiration rate of an active biomass, is an adequate methodology for quantification of aerobic activity biological. This study aims evaluate the inhibition effect of phenol in the oxidation capacity of an industrial sludge. This work also intends to study the phenol removal through biological and photochemical-biological processes. The respirometry was carried out with synthetic solution, using sludge from an oil processing industry. The phenol degradation experiments were carried out in an activated sludge unit and in a photochemical reactor. This work suggests the potential of photochemical-biological treatment use, in relation to the biological process with a no-acclimated sludge, in the removal of refractory organic compounds from oil industry wastewaters. The characterization of biomass using the respirometry methodology showed which is a useful tool in evaluation of phenol toxicity to biological treatment. (author)

  16. Inorganic elements and organic compounds degradation studies by gamma irradiation in used lubricating oils; Estudos de remocao de elementos inorganicos e degradacao de compostos organicos por radiacao gama em oleos lubrificantes usados

    Energy Technology Data Exchange (ETDEWEB)

    Scapin, Marcos Antonio

    2008-07-01

    The automotive lubricating oils have partial degradation of organic compounds and addition of undesirable inorganic elements, during its use. These substances classify the used lubricating oils as dangerous and highly toxic. According to global consensus, concerning the environmental conservation, the best is to perform a reuse treatment of these lubricating oils. For this purpose, the uses of an alternative and effective technology have been sought. In this work, the efficacy and technical feasibility of the advanced oxidation process (AOP), by gamma radiation, for used automotive lubricating oil treatment has been studied. Different quantities of hydrogen peroxide and water Milli-Q were added to oil samples. They were submitted to the Cobalt-60 irradiator, type Gammacell, with 100, 200 and 500 kGy absorbed doses. The inorganic analysis by X-ray fluorescence (WDXRF) showed inorganic elements removal, mainly to sulphur, calcium, iron and nickel elements at acceptable levels by environmental protection law for oils reusing. The gas chromatography (GC/MS) analysis showed that the advanced oxidation process promotes the organic compounds degradation. The main identified compounds were tridecane, 2-methyl-naphthalene, and trietilamina-tetramethyl urea, which have important industrial applications. The multivariate analysis, Cluster Analysis, showed that advanced oxidation process application is a viable and promising treatment for used lubricating oil reusing. (author)

  17. Electrochemical advanced oxidation processes applied to the degradation of organic compounds in aqueous effluents; Aplicacion de procesos electroquimicos de oxidacion avanzada para la degradacion de compuestos organicos en efluentes acuosos

    Energy Technology Data Exchange (ETDEWEB)

    Peralta-Hernandez, J. M.; Maldonado, M. I.; Meas-Vong, Y.; Rodriguez, F.; Godinez, L. A.; Malato, S.

    2007-07-01

    Dyeing and finishing operations produce large quantities of wastewater that contains organic dyestuff, surfactants and other contaminants that can be characterized as high levels of total organic and color. Electro-Fenton (in situ electrochemical generation of the Fenton reagent) has been studied in order to exploit the fact that the reduction of dissolved oxygen to peroxide can be carried out selectively in acidic medium on the surface of a carbonaceous cathode. In this work, we report a study in which two approaches to water treatment are combined, photo catalysis and Fenton reaction, which involves the homogeneous conversion of peroxide to hydroxyl radical (OH). (Author) 140 refs.

  18. Brominated flame retardants as persistent organic pollutants. Distribution in the environment and human exposition; Los retardantes de llama bromados como compuestos organicos persistentes. Distribucion en el medio ambiente y exposicion en humanos

    Energy Technology Data Exchange (ETDEWEB)

    Fabrellas, B.; Solis, A.; Alvarez, A.; Larrazabal, D.; Martinez, A.

    2004-07-01

    Polybrominated diphenyl ethers (PBDE) are a family of synthetic chemicals widely used in industry to delay, inhibit or even suppress combustion process in manufactured items. Flame retardant products are frequently added into plastic, electronic, paint and textile materials to reduce the risk of ignition. During last years, increasing levels of PBDEs have been detected in the environment, suggesting release from the treated surface as main pathway for environmental intake. Their physicochemical structure makes them substances of highly lipophilic bio accumulative and persistent nature, with potential toxic effects observed onto wildlife and humans. This publication resumes actual knowledge on PBDEs research and submits initiatives of human and environment exposure minimization. (Author)

  19. Biological fixation and nitrogen transfer by three legume species in mango and soursop organic orchards;Fixacao biologica e transferencia de nitrogenio por leguminosas em pomar organico de mangueira e gravioleira

    Energy Technology Data Exchange (ETDEWEB)

    Paulino, Gleicia Miranda; Barroso, Deborah Guerra, E-mail: gleiciamiranda@yahoo.com.b, E-mail: deborah@uenf.b [Universidade Estadual do Norte Fluminense (UENF), Campos dos Goytacazes, RJ (Brazil). Dept. de Fitotecnia; Alves, Bruno Jose Rodrigues; Urquiaga, Segundo; Espindola, Jose Antonio Azevedo, E-mail: bruno@cnpab.embrapa.b, E-mail: urquiaga@cnpab.embrapa.b, E-mail: jose@cnpab.embrapa.b [EMBRAPA Agrobiologia, Seropedica, RJ (Brazil)

    2009-12-15

    The objective of this work was to evaluate the biological nitrogen fixation (BNF) and the N transfer derived from BNF of the legume species - Gliricidia sepium (gliricidia), Crotalaria juncea (sunnhemp) and Cajanus cajan (pigeon pea) - for an intercropped organic orchard with mango and soursop, through the {sup 15}N natural abundance method. The following inter cropping systems were evaluated: mango and soursop with gliricidia; mango and soursop with sunnhemp; mango and soursop with pigeon pea; and mango and soursop as control. Gliricidia showed the highest BNF potential (80%) , followed by sunnhemp (64.5%) and pigeon pea (45%). After two sunnhemp prunes, 149.5 kg ha{sup -1} of N per year were supplied, with 96.5 kg derived from BNF. After three annual prunes, gliricidia supplied 56.4 and 80.3 kg ha{sup -1} of N per year, with 45 and 64 kg derived from BNF, in two consecutive years. The quantity of N supplied to the system was higher than the mango and soursop requirements. Variations in the natural abundance of {sup 15}N were found only in soursop leaves. Gliricidia and sunnhemp were prominent in N transfer, with approximately 22.5 and 40% respectively. Green manuring using gliricidia permits fractioning of the N supply, which is an advantage in N obtention by the fruit trees (author)

  20. Nuevas estrategias de gestión, tratamiento y valorización de los efluentes organicos pecuarios: Experiencias en USDA. (Management strategies for organic livestock effluents,innovative treatment and valorization)

    Science.gov (United States)

    En la actualidad el impacto potencial de los residuos ganaderos en el medio-ambiente representa uno de los desafíos más grandes de la agricultura. Las tecnologías de tratamiento pueden tener un importante papel en el manejo de los residuos ganaderos dando más flexibilidad en los programas de la apli...

  1. Spectrophotometric determination of uranium with arsenazo previous liquid-liquid extraction and colour development in organic medium; Determinacion espectrofotometrica de uranio con arsenazo, previa extraccion y desarrollo del color en medio organico

    Energy Technology Data Exchange (ETDEWEB)

    Palomares Delgado, F; Vera Palomino, J; Petrement Eguiluz, J C

    1964-07-01

    The determination of uranium with arsenazo is hindered by a great number of cation which form stable complexes with the reactive and may given rise to serious interferences. By studying the optimum conditions of uranium the extraction be means of tributylphosphate solutions dissolved in methylisobuthylketone, under conditions for previous masking of the interfering cations, an organic extract was obtained containing all the uranium together with small amounts of iron. The possible interference derived from the latter element is avoided by reduction with hydroxylammoniumchlorid followed by complex formation of the Fe(II)-ortophenantroline compound in alcoholic medium. (Author) 17 refs.

  2. PRE-COMPACTACIÓN Y ACONDICIONAMIENTO ORGANICO PARA LA RECULTIVACIÓN DE UN SUELO DE TEXTURA GRUESA (TYPIC XEROCHREPTS) DISTURBADO POR EXTRACCIÓN DE ÁRIDOS

    OpenAIRE

    Seguel, Oscar; Rodríguez, Natalia; Soto, Lely; Homer, Ian; Benavides, Carlos; Casanova, Manuel; Haberland, Julio

    2017-01-01

    RESUMEN La extracción de áridos genera un daño a la estructura del suelo superficial, disminuyendo su capacidad de soporte. Con el objeto de recuperar un suelo agrícola (Typic Xerochrepts, franco arenoso) disturbado por extracción de arenas sub-superficiales, se desarrolló un estudio en la zona central de Chile, en macetas de 20 L, estableciendo tratamientos con dos factores: pre-compactación (sin y con dos niveles crecientes) e incorporación de enmienda orgánica (cama broiler en dosis de 0, ...

  3. Determination of mean molecular weights in organic reactor coolants. III. Differential cryoscopy with thermoelectric thermometer; Determinacion de masas moleculares medias en refrigerantes nucleares organicos. III-Crioscopia diferencial con termometro termoelectrico

    Energy Technology Data Exchange (ETDEWEB)

    Becerro, E; Carreira, M

    1968-07-01

    The solubility problems raised by some components of the polymeric residue of irradiated polyphenolic coolants, which make it necessary to operate with very small samples, have been solved by means of a differential cryoscopic technique using a thermoelectric thermometer (thermal) as sensitive element. The method is based on the direct measurement of the difference between the freezing points of the investigated solution and of a reference solution whose concentration may be changed at will. The change of {delta} V (mV) versus c(molal) is linear, the equivalent point being determined either analytically or graphically depending on the required accuracy. The method has been tested by measurements on pure polyphenyls, using diphenyl ether as solvent. It has been also applied to the main prospective coolants for the DON reactor. Working with 10{sup 2} molal solutions the accuracy is better than {+-} 2 per cent. (Author) 2 refs.

  4. Energetic reuse: the use of energy from organic material from urban waste for plastics recycling; Reaproveitamento energetico: uso de energia proveniente de material organico dos residuos urbanos para reciclar plasticos

    Energy Technology Data Exchange (ETDEWEB)

    Carneiro, Priscila Alves; Rocha, Carlos Roberto [Universidade Federal de Itajuba (EXCEN/UNIFEI), MG (Brazil). Centro de Excelencia em Eficiencia Energetica

    2008-07-01

    The population growth and the elevation of the purchasing status due to economic development impel the gradual increase of residues produced a year. The discarding of these residues represents a great economic and environmental challenge, mainly because of discarded plastic concentration with no energetic and economic use, a also because of the organic material that, after decomposing, produces methane, one of the most responsible for global heating when in contact with atmosphere with no control. The recycling of plastic residues is a solution to minimize its discard and to guarantee an environmental improvement for saving raw matter, however the high consumption of energy endears the process, making it difficult its economic viability. This takes the search of new alternatives for attainment of low cost energy. In the problem of discard of the organic matter it can be the solution for the recycling of these residues. The decomposition of the organic matter produces fuel (biogas) useful as power plant for the generation of necessary electricity to the recycling process. The present study analyses an alternative to recycle plastic residues, after being consumed, in some places for discarding and using energy from biogas produced in landfills or biodigestors. Initially it was carried through a data-collecting and analysis of the physical composition of the residues, indispensable to the development of the study, which allowed to daily find the average percentage of plastics (12,9%) and organic matter (41,9%) made use by the involved population. On the basis of the data of organic matter the determination in such a way of the potential of generation of the biogas as of the electric power 'recycled' was possible to leave of that they would be discarded without any use. Data-collecting on equipment used in the plastic recycling had been essential for attainment of the necessary average energy demand to the process in such a way not only for soft plastic and PET (2,12 GJ/t) but also for hard plastic (0.11 GJ/t). According to the percentage of plastics to be recycled and the amount of necessary electric power to that end it was verified recycling possibility using 'the recycled' energy of the residues in the city. The electric power generated by the use of biogas, when applying a study of case in the city of Itajuba-MG, possible of obtaining in the landfill (11,5 GJ/day) and will have used biodigestors (14,5 GJ/day) is enough to supply the necessary energy demand for recycling of the hard plastics (0,17 GJ/day), as well as soft plastics and PET (11,2 GJ/day) discarded daily in this city. The recycling of residues plastic powder-consumption using recycled energy of the discarded residues in a municipal district besides carting social and environmental earnings for using less the natural resources, it comes to contribute for the solution of problems related to the final destination of the residues and consequently for the use of the electric power generated with the use of the biogas that has your price reduced to half of the regular one, besides not having tax taking the smaller economical viability when being sold to the c place than your use, what motivates the installation of units of located recycling in the sanitary embankments or in your proximities guaranteeing a larger supporting to the municipal district in what the project intends to be implanted. (author)

  5. Preparatory of X zeolite (faujasite) with surfactant hexa decyl trimethyl ammonium bromide (HMDTA) for adsorption of organic compounds; Acondicionamiento de zeolita X (faujasita) con surfactante bromuro de hexa decil trimetil amonio (HDTMA) para adsorcion de compuestos organicos

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez R, V

    2003-07-01

    The water represents one of the most valuable natural resources for the alive beings, since it is the essential component of the alive matter. Also, it is fundamental part of our planet, since is an indispensable element for the integral development of the same one. The demographic growth, the human being's activities and the industrial growth, he/she brings as consequence an increase in the use of the water and the generation of residual waters that successively contaminate the hydrological basins, becoming an environmental problem urgent. The contamination of the water with compound such as phenol and benzene, it is a problem that it requires the search of solutions, since it is of compound not very biodegradable, able to accumulate through the food chains and very toxic to the alive beings that they enter in contact with them (Tolgyessy, 1993). In the human beings it can take place damages in liver and kidney, the Agency of Protection to the Atmosphere of the United States (EPA) it considers that the exhibition for benzene is related with the leukemia, it is also considered as a carcinogen substance. Of the methods that are used for the treatment of polluted waters, it highlights the use of adsorber and one of them is the zeolites, since they are broadly used in those separation processes. The zeolites is crystalline aluminosilicates, they are characterized for to have a big superficial area and for their great capacity of exchange cationic, due to it the process of adsorption depends on these two characteristics, since to the modified being superficially for surfactants cationic it originates an enriched layer of carbon organic, which has the capacity to remove pollutants of the water. The present work outlines as objective to carry out the superficial modification of zeolite X using hexa decyl trimethyl ammonium bromide (HMDTA-Br) to different concentrations, with the purpose of making it useful in the removal of pollutants organic, present in watery solution. The results of this investigation work indicate that the superficial modification of the zeolite X with HMDTA-Br to the four used concentrations 29, 58, 116 and 174 mmol L was possible, and it is demonstrated by the results of electronic microscopy of sweeping and for the decrease of the content of sodium carried out by Neutron activation analysis. In relation to the removal tests, it was found that the zeolite modified X with the biggest surfactant concentration it presents the highest phenol percentage removed, being this of 38% for a time of contact of 3 hours. In accordance with the results of removal of benzene is observed that the zeolite X removes 56%, but the modified zeolite removes a bigger quantity of until 90%, said percentage varies with regard to the time of contact. Therefore the modification of the zeolite X is favorable for the removal of the benzene. (Author)

  6. Study on ionizing radiation effects in diesel and crude oil: organic compounds, hydrocarbon, sulfur and nitrogen; Estudo do efeito da radiacao ionizante em compostos organicos do diesel e do petroleo: hidrocarbonetos, sulfurados e nitrogenados

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, Luana dos Santos

    2014-07-01

    Petroleum is the most important energy and pollution source in the world, nowadays. New technologies in petrochemical industry aim to minimize energy spending at the process and to reduce pollution products. Sulfur and nitrogen compounds generate environmental problems; the most relevant is air pollution that affects the population health directly. The nuclear technology has been used in environmental protection through pollutants removal by free radicals produced at action of the radiation in water molecule. The objective of this study is to evaluate the radiation effects on oil and diesel, mainly in the hydrocarbons, organic sulfur, and nitrogen compounds. It was studied a molecule model of sulfur, named benzothiophene, diesel and crude oil samples. The samples were irradiated using a Co-60 source, Gammacell type. The total sulfur concentration in the samples was determined by X-ray fluorescence spectrometry, and organic compounds were analyzed by gas chromatography coupled to mass spectrometry (GC-MS). The study of molecular model showed that 95% was degraded at 20 kGy dose rate. Irradiation at 15 kGy of absorbed dose showed some cracking in petrol hydrocarbons, however with higher doses it was observed polymerization and low efficiency of cracking. It was observed that the sulfur compounds from diesel and petroleum was efficiently reduced. The applied doses of 15 kGy and 30 kGy were the most efficient on desulfurization of petroleum, and for diesel the highest variation was observed with 30 kGy and 50 kGy of absorbed dose. The distillation and chromatographic separation using an open column with palladium chloride as stationary phase showed a preferential separation of organic sulfur compounds in petroleum. (author)

  7. Determination of average molecular weights on organic reactor coolants. II.-Freezing point depression method for diphenyl-ether solutions; Determinacion de masas moleculares medias en refrigerantes nucleares organicos. II.- Crioscopia de disoluciones en eter difenilico

    Energy Technology Data Exchange (ETDEWEB)

    Carreira, M

    1965-07-01

    In order to reduce limitations of solubility, the cryoscopic method developed for benzene solutions of polyphenyl mixtures has been extended to diphenyl-ether solutions by introducing some modifications imposed by the physico-chemical properties of this solvent. The Nernsto theory of Beckman's method has been revised, taking into account the heat-transfer characteristics of the system, and the results of that analysis have been used to fix upon the design parameters of a cryoscopic apparatus for measurements on diphenyl-ether solutions. (Author) 9 refs.

  8. Determination of average molecular weights on organic reactor coolants. I.- Freezing-point depression method for benzene solutions; Determinaciond e masas moleculares medias en refrigerantes nucleares organicos. I.- Crioscopia de disolucion bencenicas

    Energy Technology Data Exchange (ETDEWEB)

    Carreira, M

    1965-07-01

    As a working method for determination of changes in molecular mass that may occur by irradiation (pyrolytic-radiolytic decomposition) of polyphenyl reactor coolants, a cryoscopic technique has been developed which associated the basic simplicity of Beckman's method with some experimental refinements taken out of the equilibrium methods. A total of 18 runs were made on samples of napthalene, biphenyl, and the commercial mixtures OM-2 (Progil) and Santowax-R (Monsanto), with an average deviation from the theoretical molecular mass of 0.6%. (Author) 7 refs.

  9. Use of total organic carbon, spectral gamma ray and bioturbation as tools in the identification of source rock; Carbono organico total, gamaespectrometria e bioturbacao como ferramentas na busca de possiveis horizontes geradores de hidrocarbonetos

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Anderson S.; Pereira, Egberto [Universidade do Estado do Rio de Janeiro (UERJ), RJ (Brazil). Faculdade de Geologia. Dept. de Estratigrafia e Paleontologia

    2008-07-01

    This work presents the result obtained for the gamaespectrometric study of a borehole situated in north of Parana Basin, concerning sediments of the Ponta Grossa Formation. The Total Radioactivity data and the concentrations of Potassium (K), Uranium (U), Thorium (Th) have been compared to the Total Organic Carbon (TOC) and to the degree of bioturbation intensity. The mentioned formation is composed of basal sandstones deposited in shoreface conditions, which pass to siltstones and black shales deposited in offshore conditions. Nine sedimentary facies were identified based on sedimentological characteristics and sedimentary structures. The bioturbation intensity indicates the modification degree of the initial arrangement of sedimentary beds by the action of organisms. High TOC values in the intervals in addition to the increase of the radioactivity values indicate anoxic conditions. These conditions are ideal for the organic matter concentration and preservation, reflecting favorable intervals to the hydrocarbons (HC) generation. Thus, with the integrated use of diverse tools it was possible to confirm that the Givetian-Frasnian interval of the Ponta Grossa Formation presents the best potential of HC generation of the section analyzed. (author)

  10. Determination of average molecular weights on organic reactor coolants. I.- Freezing-point depression method for benzene solutions; Determinaciond e masas moleculares medias en refrigerantes nucleares organicos. I.- Crioscopia de disolucion bencenicas

    Energy Technology Data Exchange (ETDEWEB)

    Carreira, M.

    1965-07-01

    As a working method for determination of changes in molecular mass that may occur by irradiation (pyrolytic-radiolytic decomposition) of polyphenyl reactor coolants, a cryoscopic technique has been developed which associated the basic simplicity of Beckman's method with some experimental refinements taken out of the equilibrium methods. A total of 18 runs were made on samples of napthalene, biphenyl, and the commercial mixtures OM-2 (Progil) and Santowax-R (Monsanto), with an average deviation from the theoretical molecular mass of 0.6%. (Author) 7 refs.

  11. Determination of average molecular weights on organic reactor coolants. II.-Freezing point depression method for diphenyl-ether solutions; Determinacion de masas moleculares medias en refrigerantes nucleares organicos. II.- Crioscopia de disoluciones en eter difenilico

    Energy Technology Data Exchange (ETDEWEB)

    Carreira, M.

    1965-07-01

    In order to reduce limitations of solubility, the cryoscopic method developed for benzene solutions of polyphenyl mixtures has been extended to diphenyl-ether solutions by introducing some modifications imposed by the physico-chemical properties of this solvent. The Nernsto theory of Beckman's method has been revised, taking into account the heat-transfer characteristics of the system, and the results of that analysis have been used to fix upon the design parameters of a cryoscopic apparatus for measurements on diphenyl-ether solutions. (Author) 9 refs.

  12. Technical feasibility study for the electrochemical treatment of Phaeozem soil contaminated with radioactive organic liquids; Estudio de la viabilidad tecnica para el tratamiento electroquimico de suelo Phaeozem contaminado con liquidos organicos radiactivos

    Energy Technology Data Exchange (ETDEWEB)

    Valdovinos G, V.

    2014-07-01

    The application of radioisotopes in medicine and research generates radioactive waste. A large part of these wastes are composed by scintillation liquid (mixtures of organic solvents, as toluene and xylene, fluorescent materials and surfactants) contaminated with radioisotopes such as {sup 3}H (12.3 y), {sup 14}C (5730 y), {sup 238}U (4.468 x 10{sup 9} y), {sup 232}Th (1.41 x 10{sup 10} y), {sup 204}Tl (3.7 y) or {sup 22}Na (2.6 y). In Mexico during the 80 s, these wastes were absorbed on soil to decrease their hazardous behavior during interim storage. However, these wastes must be removed for reprocessing and final landscaping. Therefore, the objective of this thesis is to study the technical feasibility of the electrochemical treatment of soils types Phaeozem contaminated with radioactive organic liquid waste (ROLW). For this study, an electrochemical treatment at laboratory level was applied, giving it an electrokinetic tracking. Control samples were prepared with different scintillation liquid (INSTAL Gel- XF, ULTIMA Gold AB{sup TM} and ULTIMA Gold XR{sup TM} as support electrolyte and polarization curves were constructed to select the current with the highest mass transfer. An analysis of the liquids and solids, before and after the application of the different potentials; the liquid phase was characterized by Gas Chromatography coupled with Flame Ionized Detector (GC-FID) and Fourier Transform Infrared Spectrometry (Ft-Irs), and the solids by Ft-Irs. From the fourteen supports electrolytes studied, eleven did not have a stable diffusion current and the other three showed a diffusion current plateau in 0.02, 0.04 and 0.06 m A·cm{sup -2}. From polarization curves, the following experimental conditions were chosen for the treatment: electrodes (meshes of titanium as anode and rod of stainless steel as cathode), scintillation liquid (ULTIMA Gold XR{sup TM} : water, 1:1) and a current of 0.06 m A·cm{sup -2}. Subsequently, radioactive control samples were prepared with soil-scintillation liquid, labeled with {sup 24}Na, {sup 99m}Tc, {sup 3}H or {sup 14}C, to determine the removal efficiency of these radioisotopes. {sup 24}Na was chosen, instead of {sup 22}Na, for its short half-life (15.03 h) to facilitate handling of samples and reduce the radiation hazards involved in using {sup 22}Na (2.6 y). In the case of {sup 99m}Tc, it did not adsorbed in the medium analyzed, and it was used as a standard. The {sup 3}H and {sup 14}C were used because they are present in the waste and could not be replaced. The {sup 24}Na and {sup 99m}Tc were quantified on a Gamma spectrometer constituted by a hyper pure germanium detector connected to a multichannel card, in 140.5 keV and 1368.6 keV for {sup 99m}Tc and {sup 24}Na respectively, and the {sup 3}H and {sup 14}C by liquid scintillation counter; all of them have a fixed geometry. The liquid and solid phases were analyzed, as well as the electrodes, by the same analytical techniques mentioned previously, once both radiotracers decayed the {sup 22}Na and {sup 99m}Tc. According to the Ft-Irs analysis, soils did not show any deterioration and, in the liquid phase, the amount of water increased, as the applied potential increased. The liquid phase chromatograms indicate that some compounds were modified after applying 5 and 7 V. The kinetic study of {sup 99m}Tc showed that 15 % to 20 % was removed each hour close to the anode, 61 % in 4 h and 91 % in 6 h. For the {sup 24}Na the removal in 4 hour of treatment was of 71.8 %, close to the cathode. In the case of {sup 14}C and {sup 3}H, the electrochemical treatment only showed an improvement in the extraction of {sup 14}C because the removal percentages are of the extraction with thinner, due to the addition of this compound, for the problems presented by taking sample; this prevented to quantify the percentages of electro-removal. (Author)

  13. Efeito do Solo do Materias Organicos E do Adubo Formula 4N:14P:8K Para Producao DA Batata (Solanum tuberosum L.) Semente Pre-Basica no Casa de Vegetacao

    Science.gov (United States)

    László, Márton

    2010-05-01

    Widely well know that the potato is an important vegetable crop at Brazíl. Plant grown on about 173.000 ha, with total yield of 2.6 million tons year-1. The average yield is about 15 t ha-1. This level is very low because degeneration of crop is rapid under high temperature and high viruses pressure. Therefore seed potato propagation and production is principal on consumption potato production. This is why we found it necessary to develop it. The latossolo vermelho soil-farmyard manure- burnt rice straw-fertilizer 4N:14P:8K greenhouse pot trial was set up at the National Vegetable Crops Research Center, Brasília-DF, Brazíl in 1990. The methods of the experiments were soil x farmyard manure x burnt rice straw, soil x 4N:14P:8K fertilizer and soil x farmyard manure x burnt rice straw x 4N:14P:8K fertilizer on randomized block design in total 29 combination of treatments in 5, 5 and 3 repetitions with in a total parcel of 116. According to chemical analysis of the a., soil, b., farmyard manure and c., burnt rice straw the agrochemistry parameters were as follows: a., latossolo vermelho soil: CaCO3 0.3-0.7%, humo 0.9-1.0%, pH (H2O) 5.3, pH (KCl) 4.5, AL- P2O5 3.2-3.5 mg kg-1, AL- K2O 180 mg kg-1, Mg (KCl) 70 mg kg-1, EDTA-Zn 0.5-0.8 mg kg-1, EDTA-Cu 0.5-0.6 mg kg-1, b., farmyard manure: N 1.8 g kg-1, P2O5 2.0 g kg-1, K2O 4.0 g kg-1, c., burnt rice straw: N 0.8 g kg-1, P2O5 7.0 g kg-1, K2O 4.5 g kg-1. The experimental datas were estimated by analysis of variance, ANOVA and MANOVA. The main conclusions were as follows: 1. Mixture of 80% latossolo vermelho, 10% burnt rice straw and 10% farmyard manure were shown best performance on seed potato productivity. The piece of tubers with a 0-20 mm (consumption seeds) was increased by 77%. 2. Total seed potato number was reached maximum at 10.8 g pot-1 4N:14P:8K fertilizer regarding to average of treatments with a 33%. 3. Dry biomassa production plant-1 was decreased by high dose of 4N:14P:8K fertilizer (18.0 g pot-1) with a hard effect (57%). Our results are shown that it was possible developing of the seed potato production under tropical greenhouse conditions by optimalised soil-organic matter-fertilizer system. This datas should be as indicators to sustainable field potato advisory systems. Keywords: potato (Solanum tuberosum L.), greenhouse, latossolo vermelho soil, farmyard manure, burnt rice straw, 4N:14P:8K fertilizer, sustainability, yield RESUMO A batata é atualmente uma das hortaliças de maior importância no Brasíl. Nos conduzirémos os três experimentos para aumentár-se do produção e produtividade da batata (Solanum tuberosum L.) semente pré- básica no casa de vegetação da Brazília-DF, no Empresa Brasileira de Pesquisa Agropecuaria- Centro Nacional de Pesquisas de Hortaliças no 1990. Os três experimentos (latossolo vermelho novo x esterco de curral x palha de arroz queimado, latossolo vermelho novo x adubo 4:14:8 NPK, latossolo vermelho novo x esterco de curral x palha de arroz queimado x adubo 4:14:8 NPK) no casa de vegetação foram conduzidos com total 29 combinações, no 5-5-3 repetições com total parcelas de 116. Os resultados foram submetidos a analise de variáncia, ANOVA e MANOVA. Nossos principal resultados estam apresentándo abaixo. 1. A mistura de 80% latossolo vermelho novo, 10% palha de arroz queimado e 10% de esterco de curral, apresentou os maiores valores para numero de tuberculos com 0-20 mm, peso total de tuberculos com 0-20 mm e peso total de tuberculos por vaso. 2. Há um efeito grande crescente das doses de 4N:14P:8K nos caracteres observados. 3. Analise-se do latossolo vermelho novo x esterco de curral x palha de arroz queimado x adubo 4:14:8 NPK experimento os resultados apresentárám-se que entre nas misturas também foi melhor a 80% latossolo vermelho novo, 10% palha de arroz queimado, 10% esterco de curral. Examinando-se 15 fatores, entre 11 casos afirmou-se a mistura como para melhor que a outra mistura. Nossos resultados apresentam- se que possivel aumentar em grande volumens o produção da batata semente pré- básica com a optimalisou solo-materia orgnicânico-adubo sistema. Estes informações oferecendo-se aplicar no sustentar-se extenção rural para aumentár o produção e produtividade da bata semente e consumo. Chave palavras: batata (Solanum tuberosum L.), casa de vegetação, latossolo vermelho novo, esterco de curral, palha de arroz queimado, adubo de 4:14:8 NPK, sustentação, produção

  14. Potential migration of organic pollutants in pipes of polyethylene. Study in pipelines of distribution net of drinkable water; Migracion potential de contaminantes organicos en tubos de polietileno. Estudio en tuberias de red de distribuciond e agua potable

    Energy Technology Data Exchange (ETDEWEB)

    Ballel, X.; Ciurana de, C.; Caixach, J.; Cortina, M.; Om, M.

    2002-07-01

    Polyethylene pipes and connections are being widely used in treated water distribution services. Migration of low molecular weight compounds from the polyethylene into the water can change its final quality. This paper is about the concentrations and identification of the migration compounds found in treated water after staying in contact with low and high-density polyethylene. Identification and quantification were carried out using CLSA (Closed Loop Stripping Analysis) extraction technique and gas chromatography coupled to mass spectrometry (HRGC/HRMS). (Author) 12 refs.

  15. Gene expression studies on human keratinocytes transduced with human growth hormone gene for a possible utilization in gene therapy; Estudos da expressao genica mediante utilizacao de queratinocitos humanos normais transduzidos com o gene do hormonio de crscimento humano. Possivel utilizacao em terapia genica

    Energy Technology Data Exchange (ETDEWEB)

    Mathor, Monica Beatriz

    1994-12-31

    Taking advantage of the recent progress in the DNA-recombinant techniques and of the potentiality of normal human keratinocytes primary culture to reconstitute the epidermis, it was decided to genetically transform these keratinocytes to produce human growth hormone under controllable conditions that would be used in gene therapy at this hormone deficient patients. The first step to achieve this goal was to standardize infection of keratinocytes with retrovirus producer cells containing a construct which included the gene of bacterial b-galactosidase. The best result was obtained cultivating the keratinocytes for 3 days in a 2:1 mixture of retrovirus producer cells and 3T3-J2 fibroblasts irradiated with 60 Gy, and splitting these infected keratinocytes on 3T3-J2 fibroblasts feeder layer. Another preliminary experiment was to infect normal human keratinocytes with interleukin-6 gene (hIL-6) that, in pathologic conditions, could be reproduced by keratinocytes and secreted to the blood stream. Thus, we verify that infected keratinocytes secrete an average amount of 500 ng/10{sup 6} cell/day of cytokin during the in vitro life time, that certify the stable character of the injection. These keratinocytes, when grafted in mice, secrete hIL-6 to the blood stream reaching levels of 40 pg/ml of serum. After these preliminary experiments, we construct a retroviral vector with the human growth hormone gene (h GH) driven by human metallothionein promoter (h PMT), designated DChPMTGH. Normal human keratinocytes were infected with DChPMTGH producer cells, following previously standardized protocol, obtaining infected keratinocytes secreting to the culture media 340 ng h GH/10{sup 6} cell/day without promoter activation. This is the highest level of h GH secreted in human keratinocytes primary culture described in literature. The h GH value increases approximately 10 times after activation with 100 {mu}M Zn{sup +2} for 8-12 hours. (author). 158 refs., 42 figs., 6 tabs.

  16. Degradação de corantes reativos pelo sistema ferro metálico/peróxido de hidrogênio Degradation of reactive dyes by the metallic iron/ hydrogen peroxide system

    Directory of Open Access Journals (Sweden)

    Cláudio Roberto Lima de Souza

    2005-03-01

    Full Text Available In this work the degradation of aqueous solutions of reactive azo-dyes is reported using a combined reductive/advanced oxidative process based in the H2O2/zero-valent iron system. At optimized experimental conditions (pH 7, H2O2 100 mg L-1, iron 7 g L-1 and using a continuous system containing commercial iron wool, the process afforded almost total discolorization of aqueous solutions of three reactive azo-dyes (reactive orange 16, reactive black 5 and brilliant yellow 3G-P at a hydraulic retention time of 2.5 min. At these conditions the hydrogen peroxide is almost totally consumed while the released total soluble iron reaches a concentration compatible with the current Brazilian legislation (15 mg L-1.

  17. Assessment of the adsorptive capacity of the Kaolin deposit targeting its use on the removal of colors in aqueous solution; Avaliacao da capacidade adsortiva do rejeito de caulim visando seu uso na remocao de corantes em solucao aquosa

    Energy Technology Data Exchange (ETDEWEB)

    Matos, S.C.; Hildebrando, E.A., E-mail: matos.cintia68@gmail.com [Universidade Federal do Para (FEMat/UFPA), PA (Brazil). Faculdade de Engenharia de Materiais

    2016-07-01

    The Amazonic region has large and valuable kaolin deposits. The state of Para by itself comprises three large industries which process kaolin. It has been noticed that the waste resulting from the processing of kaolin is rich in silico-aluminate, presenting potential in adsorption processes. Thus, this research's objective is to assess the kaolin waste produced during the processing phase, aiming at its application as low cost adsorbent material. For that, the kaolin waste has been characterized by X-ray diffraction and chemical analysis (XRF), and then sieved and calcined at 700 ° C, being then subjected to the adsorption process and observed qualitatively its capacity of retention by methylene blue (AM). Preliminary results show that the kaolin waste has satisfactory adsorption capacity at concentrations of up to 50.0 mg / MP, demonstrating the potential that it be used in the removal of dyes in wastewater treatment. (author)

  18. Desenvolvimento e validação de método espectrofotométrico para determinação de corante à base de luteína adicionado em iogurte desnatado

    Directory of Open Access Journals (Sweden)

    Ana Augusta Odorissi Xavier

    2012-01-01

    Full Text Available A simple analytical method for extraction and quantification of lutein colorant added to yogurt was developed and validated. The method allowed complete extraction of carotenoids using tetrahydrofuran in vortex, followed by centrifugation, partition to diethyl ether/petroleum ether, and drying. The carotenoids dissolved in ethanol were quantified by UV-Vis spectrophotometry. This method showed linearity in the range tested (1.41-13.42 µg g-1, limits of detection and quantification of 0.42 and 1.28 µg g-1, respectively, low relative standard deviation (3.4% and recovery ranging from 95 to 103%. The method proved reliable for quantification of lutein added to yogurt.

  19. DEGRADẢ̮O DE CORANTES T́XTEIS PELO M̉TODO FOTO-FENTON UTILIZANDO ̉XIDOS MAGN̉TICOS

    OpenAIRE

    MARILZE LILIAN MARIANO

    2013-01-01

    Os efluentes tÃÂxteis contribuem significativamente na poluiÃÂÃÂo do solo e corpos dÃââÃÂgua, sendo que muitos sÃÂo agentes mutagÃÂnicos e carcinogÃÂnicos em potencial, alÃÂm de prejudicar o processo de fotossÃÂntese de plantas aquÃÂticas devido a coloraÃÂÃÂo. Muitas tÃÂcnicas sÃÂo empregadas na remoÃÂÃÂo ou degradaÃÂÃÂo desses efluentes, dentre estes os processos oxidativos avanÃÂados, POAs, tem merecido destaque. O mÃÂtodo foto-Fenton alia a radiaÃÂÃÂo UV-Vis, perÃÂxido de hidrogÃÂnio e com...

  20. Dyes removal of textile wastewater onto surfactant modified zeolite from coal ash and evaluation of the toxic effects; Remocao de corantes de efluente textil por zeolita de cinzas de carvao modificada por surfactante e avaliacao dos efeitos toxicos

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Patricia Cunico

    2015-07-01

    Zeolites synthesized from fly and bottom ashes and modified with hexadecyltrimethylammonium (HDTMA) were used as adsorbent to remove dyes - Solophenyl Navy (SN) and Solophenyl Turquoise (ST) and their hydrolysed forms Solophenyl Navy Hydrolysed (SNH) and Solophenyl Turquoise Hydrolysed (STH), from simulated textile wastewater. The HDTMA-modified fly zeolite (ZMF) and HDTMA-modified bottom zeolite (ZMB) were characterized by different techniques, as X-ray fluorescence spectrometry, X-ray diffraction and scanning electron microscopy, etc. The ZMF and ZMB presented negative charge probably due to the formation of a partial bilayer of HDTMA on exchangeable active sites on the external surface of unmodified zeolite. Initial dye concentration, contact time and equilibrium adsorption were evaluated. The adsorption kinetic for SN, ST, SNH and STH onto the zeolites followed the pseudo second-order model. The equilibrium time was 20 min for SN and ST and 30 min for SNH and STH, respectively. Langmuir, Freundlich and Temkin models were applied to describe the adsorption isotherms. Adsorption of the dyes were best described by the Langmuir model, with exception to SN/ZPM, SNH/ZPM and SNH/ZLM systems that followed Freundlich model. The maximum adsorption capacities were 3,64; 3,57; 2,91 e 4,93 for SN, ST, SNH e STH by ZLM, respectively and 0,235; 0,492; 1,26 e 1,86 by ZPM, in this order. The best performance for hydrolyzed dyes has been attributed to reduction of the size of dyes molecules during the hydrolysis process. Acute toxicity of the dyes to a different organism were evaluated by different test-organisms. Waterflea, Ceriodaphnia dubia showed EC50 value of 1,25; 54,5; 0,78 and 2,56 mgL{sup -1} for SN, ST, SNH and STH, respectively. The plant Lemna minor showed EC50 values of 18,9; 69,4; 10,9 and 70,9 mgL{sup -1} for SN, ST, SNH and STH, respectively. Midges larvae of Chironomus tepperi showed EC50 values of 119 and 440 mgL{sup -1} for SN and ST, respectively. Regarding the adsorption process, acute effects were substantially reduced after adsorption treatment of aqueous solution with SN and ST by ZMF, as well as their hydrolysed forms, showing no toxicity after removal of 100% of colour. After treatment with ZPM there was an increase of the toxicity, with exception of SHN and STH dyes that do not show toxicity after the treatment. Toxicity Identification Evaluation tests (TIE) were realized in order to identify what substances were causing the observed toxicity for the SN, ST and the leached of ZMF and ZMB. The acute effects were significantly reduced after manipulation with Solid-Phase Extraction (SPE) and Ethylenediaminetetraacetic acid (EDTA) for the leached of ZMB and ZMF. The dyes showed reduced in the toxicity after manipulation with EDTA indicating that the toxicants are mostly cationic metals. (author)

  1. Obtainment of TiO{sub 2} powders solar cells photo electrodes dye sensitized; Obtencao de pos de TiO{sub 2} para fotoeletrodos de celulas solares sensibilizados por corante

    Energy Technology Data Exchange (ETDEWEB)

    Forbeck, Guilherme; Folgueras, Marilena V., E-mail: guilhermeforbeck@hotmail.com [Universidade do Estado de Santa Catarina (PGCE/UDESC), SC (Brazil). Programa de Pos Graduacao em Ciencia e Engenharia de Materiais; Chinelatto, Adilson L. [Universidade Estadual de Ponta Grossa (UEPG), PR (Brazil). Programa de Mestrado em Engenharia e Ciencia dos Materiais

    2012-07-01

    Titanium dioxide in its polymorphic anatase phase, presents interesting properties for solar cells photo electrodes dye sensitized such as the forbidden energy band, high refractive index and high constant dielectric. In this study, powders of nanometric titanium dioxide were produced with predominantly the anatase phase and high surface area. We used the sol-gel method, and titanium tetraisopropoxide as a precursor, which was hydrolyzed in nitric acid solution. The obtained powder was heated to 450 ° C, varying the time for each lot (0, 20 or 120 minutes). The powders were characterized by X-ray diffraction, atomic force microscopy and surface area analysis. For all lots nanosized crystallites predominated. It was observed that in the batch with 120min heating an increase rutile content. The TiO{sub 2} with 20min heating showed high surface area, greater than that of TiO{sub 2} as taken reference.

  2. Determinação eletroanalítica de corante reativo presente como contaminante em proteínas purificadas por cromatografia de afinidade Electroanalytical determination of a reactive dye currently used in affinity chromatography for protein purificaton

    Directory of Open Access Journals (Sweden)

    Marly E. Osugi

    2004-06-01

    Full Text Available Procion Green HE-4BD is a reactive dye currently used in affinity purification, and commonly present as a contaminant in the final biological preparation. An assay method is described to determine trace amounts of the dye in the presence of human serum albumin(HSA and leakage from agarose as affinity sorbent by cathodic stripping voltammetry. The proposed method is based on the reductive peak at -0.55V in B-R buffer pH 3 (E=0V and t= 240s, obtained when samples of HSA 2% (m/v containing dye concentrations in sodium hydroxide pH 12 are submitted to a heating time of 330 min at 80 ºC. Linear calibration curves can be obtained for RG19 dye concentrations from 5x10-9 mol L-1 to 8 x10-8 mol L-1. The detection limit (3sigma is 1x10-9 mol L-1.

  3. Determinação de corantes artificiais por cromatografia líquida de alta eficiência (CLAE em pó para gelatina Determination of synthetic dyes by high performance liquid chromatography (HPCL in jelly powder

    Directory of Open Access Journals (Sweden)

    Marcelo Alexandre Prado

    2004-02-01

    Full Text Available Synthetic dyes were determined by high performance liquid chromatography in 76 samples of regular jelly and diet jelly powders, of several flavors produced by seven different manufacturers. Three sample of each product, from different batches, were analyzed. The same qualitative composition was observed for products of the same flavor from different manufacturers, but the quantitative composition varied markedly from one manufacturer to the other. There were no or few significant differences between batches from a given manufacturer, demonstrating good quality control in the use of these additives by the food industry. None of the samples exceeded the limit stipulated by Brazilian legislation.

  4. Desenvolvimento de métodos eletroanalíticos empregando o eletrodo de diamante dopado com boro para a determinação simultânea de edulcorantes e corantes em produtos alimentícios

    OpenAIRE

    Patrícia Batista Deroco

    2014-01-01

    Neste trabalho, desenvolveu-se métodos eletroanalíticos para a determinação simultânea dos pares: amarelo crepúsculo (AC) e aspartame (AS), azul indigotina (AI) e vermelho 40 (V40)), bem como aspartame (AS) e acesulfame-K (AK) em produtos alimentícios utilizando-se o eletrodo de diamante dopado com boro (BDD). O par AS e AC foi determinado, sem a necessidade de separação prévia em H2SO4 0,30 mol L-1 com o eletrodo de BDD pré-tratado anodicamente e utilizando amperometria de múltiplos pulsos (...

  5. Espectrofotometria derivativa: uma estratégia simples para a determinação simultânea de corantes em alimentos Derivative spectrophotometry: a simple strategy for simultaneous determination of food dyes

    Directory of Open Access Journals (Sweden)

    Eliane Cristina Vidotti

    2006-04-01

    Full Text Available A very simple spectrophotometric method is described for resolving binary mixture of the food colorants Sunset Yellow (INS 110 and Tartrazine Yellow (INS 102 by using the first derivative spectra with measurements at zero-crossing wavelengths. Before the spectrophotometric measurements, the dyes were sorbed onto polyurethane foam and recovered in N,N-dimethilformamide. Commercial food products (gelatine and juice powder were analysed by using the proposed method and the HPLC technique. The results are in very good agreement and the differences between the methods is not statistically important. Therefore, the first-order derivative spectrophotometric method is accurate, precise, reliable and could be applied to the routine analysis of food samples.

  6. The usage of ceramics in the manufacture of the lining of temperature sensors for the oil industry; Utilizacao de ceramica para encapsulamento de sensores de temperatura na industria petrolifera

    Energy Technology Data Exchange (ETDEWEB)

    Domingues, R.O.; Yadava, Y.P.; Sanguinetti Ferreira, R.A., E-mail: rebeka.oliveira@yahoo.com.br, E-mail: yadava@ufpe.br, E-mail: ricardo.sanguinetti@pq.cnpq.br [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Departamento de Engenharia Mecanica

    2014-07-01

    In the oil production, many types of sensors are used in order to monitor some important parameters such as temperature, pressure and flow. These sensors are subjected to harsh operating conditions. Therefore they must present an inert and stable behavior in these conditions. The temperature sensors that are more suited to the oil industry are the Temperature Detectors by Resistance (TDR), because they have high accuracy and wide temperature range. Usually these devices are built with metals as detectors of temperature by encapsulated resistance in inert ceramics. The main objective of this research is to produce new ceramics of a Ca{sub 2}AlZrO{sub 5,5} cubic complex perovskite structure for the encapsulation of temperature sensors. The stoichiometric amounts of the constituent chemicals, with a high degree of purity, are homogenized, through a solid state reaction in a high energy ball mill. They are then compacted by uniaxial pressing and calcined at 1200°C for 24 hours. Soon after, the tablet is crushed giving place to a ceramic powder and the analysis of X-ray diffraction is performed. According to the sintering behavior of the ceramic powder, the microstructure and the homogeneity are studied by the Scanning Electron Microscopy. The results are presented in terms of the potential of this ceramic for applications as components of temperature sensors. (author)

  7. Sustainable alternative for use of waste from pruning deriving from power distribution networks maintenance; Alternativa sustentavel para utilizacao de residuos de poda provenientes da manutencao das redes de distribuicao de energia eletrica

    Energy Technology Data Exchange (ETDEWEB)

    Cortez, Cristiane Lima; Grisoli, Renata; Gavioli, Fabio; Coelho, Suani Teixeira [Centro Nacional de Referencia em Biomassa (CENBIO), Sao Paulo, SP (Brazil)], email: cenbio@iee.usp.br; Carmelo, Silma [AES Eletropaulo, Sao Paulo, SP (Brazil)

    2008-07-01

    In the context of the environmental issue, the increasing production of solid residues seems to be a problem due to scarcity of methods and solutions for the management. This article presents a project that has as objective to make a survey of the impacts caused by urban pruning residues generated by the electric energy concessionaire AES Eletropaulo, besides developing a method to standardize this residues composting. The obtained results refer to the observation that 50% of the cities that participated on the survey discard the residues in dumps or sanitary landfills, while only 8% perform composting. In the experimental composting plant built, the organic compound obtained reached satisfactory levels of quality with related to the specifications of minimum quality, but showed that humidity should be better controlled. The feasibility of implementing a composting plant was established, with the exception that the higher the production, the better the return on initial investment. Based in the concepts of environmental and social responsibility, we expect that the conclusion of this work can assist the civil, public and private sectors to contribute with the sustainable development. (author)

  8. Utilization of hair and nails as bio-indicators of contamination by heavy and toxic metals in industrial workers; Utilizacao de cabelos e unhas como bioindicadores de contaminacao por metais pesados e toxicos em trabalhadores de industrias

    Energy Technology Data Exchange (ETDEWEB)

    Vilhena Schayer Sabino, Claudia de; Silva, Ascanio Barros F.E.; Fernandes, Marcio Prado; Amaral, Angela Maria; Franco, Milton Batista; Guedes, Joao Bosco; Francisco, Dovenir; Castro de Assis, Adilson de

    1996-03-01

    Instrumental neutron activation analysis and atomic absorption spectrometry were performed on scalp hair and fingernail samples collected from a group of heavily exposed healthy mail industrial workers. The concentration of trace elements (As, Cd, Cr, Hg, Ni, Pb and Sb) were evaluated and compared for scalp and fingernails. Comparative studies demonstrated that concentration of certain elements were greater than those corresponding to non-exposed workers. (author). 4 refs., 6 tabs.

  9. Development of electro fused aggregates for use in refractories for the burning zone of cement kilns; Desenvolvimento de agregados eletrofundidos para utilizacao em refratarios para a zona de queima de fornos de cimento

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Luis Leonardo Horne Curimbaba

    2006-07-01

    Electro fused aggregates are largely used in refractory production due to the better performance reached when they are employed. In this work electro fused aggregates were designed for application in refractories for the burning zone of cement kilns. Initially reaction evaluation was conducted aiming the identification of the most prone refractory systems when single refractory phases react with Portland cement phases at high temperatures. In the next step, raw materials of the best refractory systems were electro fused to generate different aggregate compositions. The electro fused aggregates properties were evaluated and the classified ones were used to produce refractory bricks for the burning zone of cement kilns. General characteristics of these bricks were measured and compared with a standard magnesia-spinel refractory. Aggregates of the system Mg O - TiO{sub 2} - Ca O, more specifically aggregates belonged to the compatibility triangle Mg O - Mg{sub 2}TiO{sub 4} - CaTiO{sub 3}, showed suitable characteristics for development of refractories for the burning zone cement kilns. (author)

  10. The use of glycerol in PET chemical recycling with the prospect of the polymeric membranes production; Utilizacao de glicerol na reciclagem quimica de PET visando a producao de membranas polimericas cationicas

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Agne R. de; Consentino, Vinicius M.; Muniz, Aline S.; Sakae, George H.; Oliveira, Angelo R.S.; Cesar-Oliveira, Maria Aparecida F. [Universidade Federal do Parana - UFPR, Centro Politecnico, Curitiba, PR (Brazil)], e-mail: mafco@ufpr.br

    2011-07-01

    The recent interest in alternative sources of renewable energy of unlimited duration and with a low environmental impact, has led to a rise in the use and production of biodiesel. This requires an increase in the availability of glycerine in the market. This involves a study of new applications to increase the consumption of this raw material which can be linked to solving a serious environmental problem - the unsuitable disposal of post-consumption PET packages. Parallel to this, combustible cell technology is proving to have promising results, particularly in the area which uses polymeric electrolytes. The polymeric proton exchange membrane is currently most widely used in Nafion. However, this entails very high costs. By bringing together these important requirements in the energy sector, this study demonstrates how the development of aromatic sulfonate polyesters obtained from the chemical recycling of poly(ethylene terephthalate) with an aromatic derivative of glycerol. (author)

  11. Use of ionizing radiation in the recycling of unserviceable tires of automotive and its adequate environmental disposal; Utilizacao da radiacao ionizante na reciclagem de pneus inserviveis de automovel e sua destinacao ambiental adequada

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Clecia de Moura

    2013-07-01

    The aim of this study was to use ionizing radiation in the recycling of scrap tires of automotive. Samples of rubber unserviceable tires were irradiated with radiation doses 200, 400 and 600kGy in an electron accelerator. Subsequently, they were characterized by thermogravimetry (TG), differential scanning calorimetry (DSC), tensile strength mechanical test, spectrophotometry Fourier transform infrared (FTIR) and scanning electron microscopy (SEM). By thermogravimetry was possible to observe the effects of radiation in the mass loss of material. In the DSC curves were observed exothermic decomposition peaks and associated values of enthalpy variation (ΔH). The mechanical properties of the elastomeric matrix with unserviceable tires powder were studied and its behavior to ionizing radiation was analyzed. FTIR spectra were obtained in the 4000 - 650cm-1 region. It was observed that there was no change in the peaks due irradiation. For SEM the micrographs were enlarged from 32 times up to 1000 times and observed in sizes from 1mm up to 20μm. It was observed at doses of 200 and 400kGy, roughness corresponding to breaks or ruptures possibly caused by radiation. In 600kGy radiation dose was observed cavities caused by radiation. It was observed that at all doses occurred degradation. For samples without powder and with 10, 30 and 50% of unserviceable tires powder it was obtained micrographs of 100μm and 200μm amplification. Also it was possible to observe the incorporation of unserviceable tires powder of automotive in the elastomeric matrix of non-irradiated and irradiated samples. (author)

  12. Use of radioanalytical methods for determination of uranium, neptunium, plutonium, americium and curium isotopes in radioactive wastes; Utilizacao de metodos radioanaliticos para a determinacao de isotopos de uranio, plutonio, americio e curio em rejeitos radioativos

    Energy Technology Data Exchange (ETDEWEB)

    Geraldo, Bianca

    2012-07-01

    Activated charcoal is a common type of radioactive waste that contains high concentrations of fission and activation products. The management of this waste includes its characterization aiming the determination and quantification of the specific radionuclides including those known as Difficult-to-Measure Radionuclides (RDM). The analysis of the RDM's generally involves complex radiochemical analysis for purification and separation of the radionuclides, which are expensive and time-consuming. The objective of this work was to define a methodology for sequential analysis of the isotopes of uranium, neptunium, plutonium, americium and curium present in a type of radioactive waste, evaluating chemical yield, analysis of time spent, amount of secondary waste generated and cost. Three methodologies were compared and validated that employ ion exchange (TI + EC), extraction chromatography (EC) and extraction with polymers (ECP). The waste chosen was the activated charcoal from the purification system of primary circuit water cooling the reactor IEA-R1. The charcoal samples were dissolved by acid digestion followed by purification and separation of isotopes with ion exchange resins, extraction and chromatographic extraction polymers. Isotopes were analyzed on an alpha spectrometer, equipped with surface barrier detectors. The chemical yields were satisfactory for the methods TI + EC and EC. ECP method was comparable with those methods only for uranium. Statistical analysis as well the analysis of time spent, amount of secondary waste generated and cost revealed that EC method is the most effective for identifying and quantifying U, Np, Pu, Am and Cm present in charcoal. (author)

  13. Elimination of the induced malfunctions and use of dynamic prognosis in a thermodynamic diagnosis system of the thermal cycling; Eliminacao das malfuncoes induzidas e utilizacao do prognostico dinamico em sistemas de diagnostico termodinamico de ciclos termicos

    Energy Technology Data Exchange (ETDEWEB)

    Silva, J.A.M.; Venturini, O.J.; Lora, E.E.S. [Universidade Federal de Itajuba (NEST/IEM/UNIFEI), MG (Brazil). Inst. de Engenharia Mecanica. Nucleo de Excelencia em Geracao Termeletrica e Distribuida], Emails: juliomendes@unifei.edu.br, osvaldo@unifei.edu.br, electo@unifei.edu.br

    2009-07-01

    The search for more efficient thermal cycles has led a growing complexity of these cycles and therefore increased the inter-relationships between the thermodynamic components. This complexity is further enhanced with the over time, due to the occurrence of both natural as early degradation in a more or less degree, of all plant components. Several methodologies have been proposed for creating system for diagnostic / prognostic with the objective to detect these degradations (defects) and quantify the gain that can be obtained in the performance indicators of thermal cycles (usually specific fuel consumption and power net) by the elimination of anomalies. Two points have been emphasized as the most difficult in the development of such systems: the distinction between the performance variation of the components due only to the point of operation outside of these project components, caused by the presence of abnormality in another component (induced malfunction) and a decrease in the performance due to the presence of anomalies in the component itself (intrinsic malfunction). The second difficulty is the quantification of the effects induced by the elimination of each of the present anomalies. This work makes use of the method of reconciliation and using individual models of each component to predict unusual behavior of the same design point. The comparison of data from the system plant information, relating to the current state and data from the models, is used to detect anomalies. The methodology is explained in detail and an application of it in a Rankine cycle is used to well understand, especially in parts for the elimination of induced malfunctions, and related to the induced changes by the elimination of each one of the anomalies.

  14. The use of gamma radiation aiming to post harvest conservation of Cantaloupe melon (Cucumis melo L. var. Cantaloupensis);Utilizacao de radiacao gama em meloes cantaloupe (Cucumis melo L. var. Cantaloupensis) como tecnica de conservacao pos-colheita

    Energy Technology Data Exchange (ETDEWEB)

    Siqueira, Alessandra Aparecida Zilio Cozzo de

    2007-07-01

    Although Brazilian fruit culture has been growing in the international market, the fruit quality and the post harvest technology have not been improved properly. In Brazil, fruit nutritional factors are very important because of their potential to provide suitable nutrients for a significant part of the Country population. Some post harvest technologies, such as ionizing radiation, can keep the physical, chemical, nutritional and sensorial characteristics of the natural fruit, improving the quality of the fruits in the market. This work evaluated the effects of Cobalt 60 irradiation in Cantaloupe melon, aiming the post harvest conservation during 7 days of storage, at a temperature ranging from 20 to 22 deg C. The doses of irradiation were set to 0, 150, 300, 450, 600, 750 and 900 Gy, based on the multiple of 150 Gy quarantine dose, aiming to establish the lowest, the highest and the ideal doses. Afterwards, physical, chemical and nutritional characteristics of irradiated fruit were checked and, finally, the sensorial characteristics through acceptability test. Results indicated that the doses higher than 450 Gy affected firmness, pulp yield and color (L and a{sup *}) parameters. Nevertheless, analyzing physical, chemical and nutritional parameters, doses of 450 and 900 Gy kept pH, tetrable acidity, soluble solids, color (a{sup *} and b{sup *}), chlorophyll and carotenoids, phenolic compounds, respiratory rate and ethylene level. The storage period was the most important factor that affected the quality of the fruit, despite of the radiation doses. Based on the acceptability test, the best evaluated fruits were from the treatments of 450 and 900 Gy. This work allowed to conclude that fruit radiation is an appropriate technology for Cantaloupe melon post harvest conservation, but it is necessary to be used in combination with other technologies, especially to fungi control. (author)

  15. Study of Cesium and Strontium sorption in Brazilian clays for their use as a barrier in repositories of radioactive wastes; Estudo de sorcao de cesio e estroncio em argilas nacionais para sua utilizacao como barreira em repositorios de rejeitos radioativos

    Energy Technology Data Exchange (ETDEWEB)

    Freire, Carolina Braccini

    2007-07-01

    Wastes in general should be properly treated and stored. Then the radioactive wastes also require suitable and safe management beginning in their generation until the storage in repository. The main purpose of the radioactive waste management is to preserve the human beings and the environment. The objective of this research was to characterize some Brazilian clays in order to evaluate the viability of their use in the backfill layer, one of the radioactive waste repository barriers. The main function of this barrier is to contribute in the delay of the radionuclides movement, and to prevent their release into the environment. Four clays provided by national suppliers were selected for the research: Ca-Montmorillonite (Dol 01), Na-Montmorillonite (Dol 02), Kaolinite (Ind 01) and Vermiculite (Ubm 04). Their physical, chemical and mineralogical characteristics were determined, and also their sorption potential of Cesium and Strontium cations. It was confirmed through these results a direct relationship among their specific surface (SS), the capacity of cationic exchange (CCE) and pH. The CCE results followed this increasing order: Ind 01, Dol 01, and Dol 02. In accordance with the models of Freundlich (KJ) and Langmuir (M), the clays Dol 01 and Dol 02 were the best sorbers of Sr{sup 2+}. The Ind 01 and Ubm 04 were the best ones in the case of Cs{sup +}. The Gibbs free energy change ({delta}G deg) was calculated for the sorption reactions between the clays and the cations, and it was negative for all clays, confirming the sorption reaction spontaneity. (author)

  16. Analysis of the possibility of use of a pump powered by solar energy supply of water in micro sprinklers; Analise da possibilidade de utilizacao de uma motobomba acionada por energia solar na alimentacao de agua em micro aspersores

    Energy Technology Data Exchange (ETDEWEB)

    Oyama, Paulo Takashi; Schutz, Fabiana Costa de Araujo; Jousseph, Carlos Alberto C.; Grosbelli, Andressa; Gnoatto, Estor; Kavanagh, Edward [Universidade Tecnologica Federal do Paran (UTFPR), Medianeira, PR (Brazil)], e-mail: paulooyama@gmail.com

    2011-07-01

    Due to the high cost of connecting electricity in distant places of conventional networks, solar photovoltaic energy is widely used in street lighting, water pumping, health clinics, etc.. To contribute to a better use of such energy, the project aimed to analyze the water-flow, power and electric current of a motor powered by two Solarex solar module manufacturer, model MSX 56, standard voltage of 12V, the current standard of 3.35A and 56W of potency using a pump, Shurflo Ltd manufacturer, model 2088-732, a pressure transducer model HUBA-510, a flow transducer for pumping water. The analysis for the height of 18.2 mca, corresponding height to 178.554 kPa, showed a flow rate of 365.308 L/h. Based on the results obtained in the laboratory, it was concluded that: the emitter Rain Bird QN-14, showed FVC nearly of 0.7%, ranking it as good, the emitter flow rates were in line with those presented in the catalog manufacturer, in the pressure range from 100 to 200 kPa, its effective radius was limited between 1.00 and 3.00 m away from the emitter, the profile of three-dimensional distribution of precipitation and isohyetal were quite irregular, which makes it possible the use of irrigation equipment in small areas. (author)

  17. Conversion of cycle Diesel engines to Otto aiming the methane utilization as alternative fuel; Conversao de motores do ciclo diesel para Otto visando a utilizacao do metano como combustivel alternativo

    Energy Technology Data Exchange (ETDEWEB)

    Torres, J F; Venanzi, D [Sao Paulo Univ., Sao Carlos, SP (Brazil). Escola de Engenharia

    1988-12-31

    A diesel engine was converted in Otto engine for use methane as fuel, by modifications on compression ratio and on the induction system, and inclusion of a spark ignition system. The performance of dynamometer essays results in both cycles are compared and presented in overlapped curves. (author). 5 refs., 2 figs., 2 tabs

  18. Efficiency of phosphorus (32 P) uptake and use by eucalyptus seedlings and rice; Eficiencia de absorcao e utilizacao de fosforo ({sup 32} P) por mudas de eucalipto e arroz

    Energy Technology Data Exchange (ETDEWEB)

    Luca, Edgar Fernando de; Boaretto, Antonio Enedi [Centro de Energia Nuclear na Agricultura (CENA), Piracicaba, SP (Brazil). Lab. de Nutricao Mineral de Plantas; Muraoka, Takashi [Centro de Energia Nuclear na Agricultura (CENA), Piracicaba, SP (Brazil). Lab. de Fertilidade do Solo; Chitolina, Jose Carlos [Sao Paulo Univ., Piracicaba, SP (Brazil). Escola Superior de Agricultura Luiz de Queiroz (ESALQ)

    2002-09-01

    The knowledge on different plant abilities to take up soil phosphorus and its use for growth can be important to improve markedly the efficiency of phosphorus fertilization. Having this in mind, an experiment was carried out under greenhouse conditions to test the hypothesis that eucalyptus seedlings are more efficient than rice in absorbing phosphorus from low solubility sources applied to a Quartzamment soil, testing different efficiency concepts. The phosphorus sources Ca(H{sub 2}{sup 32}PO{sub 4}).H{sub 2}O, CaH{sup 32}PO{sub 4}.2H{sub 2}O and Ca{sub 3}({sup 32}PO{sub 4}){sub 2} , synthesised in laboratory and identified by X-ray diffractometry and thermal differential analyses, were used as radioactive tracers. It was concluded that rice is more efficient in absorbing phosphorus from these low solubility sources, while eucalyptus presents a higher coefficient of biologic P utilisation. The 'difference' method (conventional) that in based on P recovery by plants, underestimated the absorption of this nutrient for both species in relation to the isotopic method. (author)

  19. Use of wasted foundry sand (WFS) as a partial substitute for silica in a soda lime glass; Utilizacao de areia descartada de fundicao (ADF) como substituinte parcial da silica em um vidro soda-cal

    Energy Technology Data Exchange (ETDEWEB)

    Martin, A.C.; Ueno, O.K.; Folgueras, M.V., E-mail: amandacarolinemartin@gmail.com [Universidade do Estado de Santa Catarina (CCT/UDESC), Joinville, SC (Brazil). Centro de Ciencias Tecnologicas

    2016-07-01

    The waste foundry sand (WFS) is the main waste generates in foundry industries. Studies in the literature suggest the use of WFS in different materials, such as concrete, brick or asphalt. This work aims to partially replace the silica of a soda-lime glass by the WFS. The waste foundry sand has in its composition elements such as iron and aluminum that can affect the glass quality, which justifies the residue processing to reduce the impurity content. The treatments, that included mechanical agitation and thermal treatment, resulted in a slight decrease in the percent of iron with consequent increase of the silica content. After treatment, some sands were incorporated into the glass, that showed green color but with lower absorption intensity for the sand with less iron content. It was observed that it's possible to obtain glasses using WFS, however, there is difficulty in color controlling. (author.

  20. Evaluation of the potentiality of the use of high-carbon microsilica as a pozzolanic material; Avaliacao da potencialidade da utilizacao de microssilica de alto teor de carbono como material pozolanico

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, R.L.S.; Pederneiras, C.M.; Costa, T.C.S.; Silva, C.H.R.B., E-mail: ruan_landolfo@hotmail.com [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil); Anjos, M.A.S. [Instituto Federal da Paraiba (IFPB), PB (Brazil); Nobrega, A.K. [Universidade Federal Rural do Semi-Arido (UFERSA), Mossoro, RN (Brazil)

    2016-07-01

    Supplementary Cementitious Materials reduce the production of clinker, which minimizes the environmental impact of cement production and the generation of industrial waste, also improve mechanical behavior and durability. Thus, this article aims to evaluate the potential use of microsilica with high content of carbon as pozzolanic material, based on the requirements of ISO 12653 (ABNT, 2015). The techniques of X-ray fluorescence (XRF), X-ray diffraction (XRD) and compressive strength of mortar of lime and cement (at 7 and 28 days, respectively) were used to evaluate the pozzolanic of the microsilica as a mineral addition. The results indicated that the microsilica has a high amorphous silicon dioxide percentage structure. In the DRX could be possible to analyze the formation of CSH, justifying the good results of mechanical strength, especially with cement. Thus, the mineral admixture used in this research can be considered as a pozzolanic material. (author)

  1. The use of neutron diffraction for the determination of the in-depth residual stresses profile in weld coatings; A utilizacao da difracao de neutroes na determinacao do perfil de tensoes residuais em revestimentos por soldadura

    Energy Technology Data Exchange (ETDEWEB)

    Marques, Maria Jose; Batista, A.C.; Nobre, J.P. [Universidade de Coimbra (Portugal). Dept. de Fisica. Centro de Estudos de Materiais por Difraccao de Raios X (CEMDRX); Loureiro, Altino [Universidade de Coimbra (Portugal). Dept. de Engenharia Mecanica. Centro de Engenharia Mecanica (CEMUC); Kornmeier, Joana R., E-mail: mjvaz@fe.up.pt [Technische Universitaet Muenchen, Garching (Germany). FRM II

    2013-04-15

    The neutron diffraction is a non-destructive technique, particularly suitable for the analysis of residual stress fields in welds. The technique is used in this article to study ferritic samples, coated by submerged arc welding using stainless steel filler metals. This procedure is often used for manufacturing process equipment for chemical and nuclear industries, for ease of implementation and economic reasons. The main disadvantage of that processes is the cracking phenomenon that often occurs at the interface between the base material and coatings, which can be minimized by performing post-weld stress relief heat treatments. The samples analyzed in this study were made of carbon steel plates, coated by submerged arc welding two types of stainless steel filler metals. For the first layer was used one EN 12 072 - S 2 U 23 12 electrode, while for the second and third layers were used an EN 12 072 - 19 12 3 S L electrode. After cladding, the samples were submitted to a post-weld heat treatment for 1 hour at 620 deg C. The residual stress profiles obtained by neutron diffraction evidence the relaxation of residual stress given by the heat treatment. (author)

  2. Implementation and testing of the use of vegetable oils as fuel diesel generators in the Amazon isolated communities; Implantacao e testes de utilizacao de oleo vegetal como combustivel para diesel geradores em comunidades isoladas da Amazonia

    Energy Technology Data Exchange (ETDEWEB)

    Coelho, Suani Teixeira; Silva, Orlando Cristiano da; Gonzalez Velaquez, Silvia Maria Stortini; Monteiro, Maria Beatriz C.A.; Silotto, Carlos Eduardo Grassi [Centro Nacional de Referencia em Biomassa (CENBIO), Sao Paulo, SP (Brazil)

    2004-07-01

    The project PROVEGAM 'Implantation and test of a unit demonstration of energetic utilization of vegetable oil', tested in operational conditions of field, the functioning of a conventional diesel engine, adapted to operate with palm oil 'in natura' in the community of Vila Soledade, city of Moju, Para State. The Vila Soledade is an isolated community that has, approximately, 700 inhabitants and it's located at one hundred kilometers from the city hall by car and more 30 minutes by boat. The electric energy of this community was previously generated, by a conventional diesel engine, obsolete and very expensive to the community, because the fuel price and the transport of the diesel oil from the city to the community. The PROVEGAM project, installed an electric generation group, MWM TD229, manufactured in Brazil, adapted with a conversion kit to operate with 'in natura' palm oil, working 6 hours per day. Because of the viscosity of the palm oil and its combustion point, it was necessary to heat the vegetable oil before its injection into the engine. The operation begins and finishes with diesel oil, in order to heat the palm oil and to clean possible residues deposited in the interior of the engine. The use of the palm oil justifies itself for being produced in the region, which means that it doesn't have to be imported. Currently, the generating group is working in the community during 5 hours per day with palm oil, and 1 hour per day with diesel oil and it already has more than 1600 hours of testing. The results of this project, so far, have confirmed the conceived premises, and this electric model of generating energy is already recommended to be implemented in other communities in the Amazon region. (author)

  3. Use of representative models in the decision making process of an offshore field development plan; Utilizacao de modelos representativos na tomada de decisao do desenvolvimento complementar em campo offshore

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Fabio Rodrigo C. da; Costa, Ana Paula de Araujo [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

    2008-07-01

    The purpose of this study was to evaluate the risk and value of information on the complementary development project of an offshore field, which consists of drilling a well in a region that has not been drained by existing wells. It was applied a methodology that involves quantification of uncertainty and risk analysis (Costa, 2003) to obtain the probabilistic production curves of oil and value of information from the project. The work consists of applying a methodology that proposes the use of the concept of models that represents the geological uncertainties, called Representative Geological Models (RM) to improve the decision making process of the project. It was used a numerical simulator (IMEX) and a tool for parallel processing (UNIPAR). The RM represents the universe of all models combined, making up the risk curve of the study. The selection of RM consists of plotting a main objective function (NPV) with a secondary of production (FR%, NP, etc.). The adoption of this premise, which includes aspects of the amount recovered and the speed of recovery, is useful in sizing the later production facilities as well as in detailing the development plans and evaluating the flexibility of these plans. The adoption of the methodology of measuring uncertainties as well as an automated tool made the study possible and also provided detailed information, contributing to the decision making process. (author)

  4. Use of agroindustrial waste in the preparation of nanocomposites based on bacterial cellulose and hydroxyapatite; Utilizacao de residuos agroindustriais na elaboracao de bionanocompositos baseados em celulose bacteriana e hidroxiapatita

    Energy Technology Data Exchange (ETDEWEB)

    Duarte, Eden B.; Chagas, Bruna S. das; Feitosa, Judith P.A. [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil); Andrade, Fabia K.; Borges, Maria F.; Muniz, Celli R.; Souza Filho, Men de Sa M.; Rosa, Morsyleide F., E-mail: morsyleide.rosa@embrapa.br [Embrapa Agroindustria Tropical, Fortaleza, CE (Brazil); Brigida, Ana I. [Embrapa Agroindustria de Alimentos, Barra de Guaratiba, Rio de Janeiro, RJ (Brazil); Morais, Joao P.S. [Embrapa Algodao, Campina Grande, PB (Brazil)

    2015-07-01

    Environmental issues have supported the interest in renewable sources and agroindustrial residues became a significant resource for the production of new materials. The present work presents the use of agroindustrial residues to obtain bacterial cellulose (BC) for further elaboration of nanocomposites with hydroxyapatite (HA). The production of BC membranes occurred in Hestrin & Schramm medium, cashew juice and sisal liquid waste cultivated under static conditions. After the incubation period, the BC membranes were purified and nanocomposites prepared by successive immersion of the purified membranes in solutions of Calcium Chloride (CaCl{sub 2}), and Sodium Phosphate (Na{sub 2}HPO{sub 4}), followed by drying and subsequent characterization. The materials obtained were characterized by Thermogravimetric Analysis (TGA) and X-ray Diffraction (XRD). Additionally, in vitro tests were performed for nanocomposites. The results showed the production of cellulose from the three substrates studied, without the need for further supplementation or pH change. In all characterizations, structure and typical behavior of bacterial cellulose were found. The composites showed bioactivity and the adsorption capacity of proteins, which lead to potential biocompatibility of these materials. (author)

  5. Feasibility analysis of the use of sugar cane bagasse ash as mineral addition to cementitious mortars; Analise da viabilidade de utilizacao da cinza do bagaco de cana-de-acucar como adicao mineral em argamassas cimenticias

    Energy Technology Data Exchange (ETDEWEB)

    Fazzan, J.V.; Pereira, A.M.; Moraes, M.J.B. de; Akasaki, J.L.; Sanches, A.O.; Malmonge, J. A., E-mail: jvfazzan@hotmail.com [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Ilha Solteira, SP (Brazil). Faculdade de Engenharia. Departamento de Fisica e Quimica

    2014-07-01

    Currently, Brazil is experiencing an expansion of sugarcane plantations, which makes the country the world's largest producer of sugarcane. With the bagasse generated during the process, is generated the bagasse ash cane sugar (CBC) which consists mainly of silicon dioxide (SiO{sub 2}) and presents as potential alternative raw material for the production of cement composites. In this context, the objective of this study is to evaluate the reactivity of the CBC through physical and chemical analysis, for the production of mortars. The study of the CBC was performed by means of XRF testing, XRD, SEM and ADL. Mortar specimens with different percentages of CBC in partial replacement of Portland cement, for analysis of compressive strength were also produced. Despite the mixtures with additions have lower resistance to conventional mortars, the results showed the potential of the CBC as reactive mineral addition. (author)

  6. Construction and characterization in vitro of a bicistronic retroviral vector coding endostatin and interleukin-2 for use in gene therapy; Construcao e caracterizacao in vitro de um vetor retroviral bicistronico codificando endostatina e interleucina-2 para utilizacao em terapia genica

    Energy Technology Data Exchange (ETDEWEB)

    Calvo, Fernanda Bernardes

    2009-07-01

    Gene therapy has been used in preclinical studies and clinical trials in order to alleviate or cure a disease. Retroviral vectors are a tool for gene transfer is widely used. Bicistronic vectors are an attractive alternative for treatment of complex diseases. A variety of options exists to simultaneously express two genes in genetically modified cells. The most common approach relies on bicistronic vectors in which the genes are linked to each other by an internal ribosome entry site allowing co-translational expression of both cistrons. Endostatin, the C-terminal fragment of collagen XVIII, is a potent angiogenesis inhibitor. At present, ES has been widely used in anti-angiogenic in a variety of experimental tumor models, and clinical trials to test it as an anti-tumor agent are already under way. Immunotherapy has been used as adjuvant treatment for tumors and has been used in several preclinical studies and clinical trials. The objective of this project was to construct and characterize 'in vitro' an IRES-based bicistronic retroviral vector encoding endostatin and interleukin-2. The construction of the vector was performed in three stages, the final construction was analyzed by restriction analysis and sequencing. Packaging cells were prepared. The endostatin and interleukin-2 levels were determined by Dot blot. Monocistronic and bicistronic mRNA expression were analyzed by real time RT-PCR. Bicistronic vector showed high levels of virus trites, ranging from 4.20x10{sup 5} to 1.53x10{sup 6}UFC/ml. Secreted levels of endostatin and interleukin-2 ranged from 1.08 to 2.08{mu}g/10{sup 6}cells.24h and 0.66 - 0.89{mu}g/10{sup 6}cells.24h, respectively. The mRNA expression of ES in the NIH3T3 clone pLend-IRES-IL2SN was 2 times higher than the level presented by the NIH3T3 clone pLendSN. The endostatin promoted inhibition (40%) of endothelial cell proliferation. Interleukin-2 promoted a proliferation of 10.6% lymphocytes CD4 and 8.9% of CD8. We conclude that the IRES bicistronic vector provides a powerful tool for studies of cell biology of cancer and new therapeutic strategies. (author)

  7. The use of risk analysis as a tool for land use policies in near pipe lanes areas; Utilizacao da analise de riscos para definicao de politicas de uso de ocupacao do solo em areas proximas a faixa de dutos

    Energy Technology Data Exchange (ETDEWEB)

    Sousa, Anna Leticia; Simplicio, Dayse Maria [EIDOS do Brasil Ltda., Rio de Janeiro, RJ (Brazil)

    2005-07-01

    It is estimated that among the several failure causes in pipelines, only 23 % of them are associated to excavation (tertiary activity) for both gas and oil pipelines. It is probable that factors like growth of the population, urbanization and development of activities next to the transmission ducts, increase the probability of damages due to human being activities, and consequently in parallel they also increases the risks for the population. Thus, it is necessary to incorporate some procedures of soil use (planning, zoning and delimitation) in the risk management activity of these installations. In the United States and Europe for instance some governmental guidelines have being developed and applied to establish suitable procedures for the soil use in the context of risks associated with great accidents. In Brazil this subject won highlight starting from the publication of the law 10.932/04 of 04/08/2004 which has altered the article 4 of the law 6766, of 19/11/1979 which regulates the urban soil division. It also assigns to the organisms of environmental licensing the responsibility of defining the zones along of which no constructions are permitted, such as electrical transmission lines, ducts and railroads domain zones. This publication aims to revise the methodologies and practices existing in the world and to compare the efforts and benefits of their implementations.

  8. Implementation and testing of the use of vegetable oils as fuel diesel generators in the Amazon isolated communities; Implantacao e testes de utilizacao de oleo vegetal como combustivel para diesel geradores em comunidades isoladas da Amazonia

    Energy Technology Data Exchange (ETDEWEB)

    Coelho, Suani Teixeira; Silva, Orlando Cristiano da; Gonzalez Velaquez, Silvia Maria Stortini; Monteiro, Maria Beatriz C.A.; Silotto, Carlos Eduardo Grassi [Centro Nacional de Referencia em Biomassa (CENBIO), Sao Paulo, SP (Brazil)

    2004-07-01

    The project PROVEGAM 'Implantation and test of a unit demonstration of energetic utilization of vegetable oil', tested in operational conditions of field, the functioning of a conventional diesel engine, adapted to operate with palm oil 'in natura' in the community of Vila Soledade, city of Moju, Para State. The Vila Soledade is an isolated community that has, approximately, 700 inhabitants and it's located at one hundred kilometers from the city hall by car and more 30 minutes by boat. The electric energy of this community was previously generated, by a conventional diesel engine, obsolete and very expensive to the community, because the fuel price and the transport of the diesel oil from the city to the community. The PROVEGAM project, installed an electric generation group, MWM TD229, manufactured in Brazil, adapted with a conversion kit to operate with 'in natura' palm oil, working 6 hours per day. Because of the viscosity of the palm oil and its combustion point, it was necessary to heat the vegetable oil before its injection into the engine. The operation begins and finishes with diesel oil, in order to heat the palm oil and to clean possible residues deposited in the interior of the engine. The use of the palm oil justifies itself for being produced in the region, which means that it doesn't have to be imported. Currently, the generating group is working in the community during 5 hours per day with palm oil, and 1 hour per day with diesel oil and it already has more than 1600 hours of testing. The results of this project, so far, have confirmed the conceived premises, and this electric model of generating energy is already recommended to be implemented in other communities in the Amazon region. (author)

  9. Application of safety checklist to the analysis of the IEA-R1 reactor water retreatment system; Utilizacao do checklist de seguranca na analise do sistema de retratamento de agua do reator IEA-R1

    Energy Technology Data Exchange (ETDEWEB)

    Sauer, Maria Eugenia Lago Jacques; Sara Neto, Antonio Jorge; Lima, Toni Carlos Caboclo de; Ribeiro, Maria Alice Morato [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)]. E-mail: melsauer@ipen.br

    2005-07-01

    In 1999, the management of the IEA-R1 Research Reactor (pool type - 5 MWth), located at IPEN/CNEN-SP, started the evaluation of the Reactor Pool Water Retreatment System to identify operational aspects, which could compromise the operators safety. The purpose was to identify and propose enhancements to the system which would be installed to substitute for the existing one. This process was conducted through a qualitative study of the system in operation. This study was carried out by a team composed of specialists in reactor operation, systems maintenance and radiological protection, and one safety analyst. The study consisted, basically, in local inspections to verify the physical and operational conditions of each equipment / component as well as aspects related to maintenance activities of the system. The process control and the operator procedures associated with the retreatment of the reactor pool water were also reviewed. The methodology adopted to develop the study was based in process hazard analysis technique named Safety Checklist. This paper presents a summary of this study and the main results obtained. Some operational and safety problems identified, the prevention and/or correction means to avoid them, and the recommendations and suggestions that have been implemented to the new design of the IEA-R1 Reactor Water Retreatment System, whose installation was concluded in 2003, are also presented. (author)

  10. Utilization of C-14 settled urease for diagnosing Campylobacter Pylori in the stomach. Utilizacao de ureia marcada com carbono quatorze para diagnostico da presenca do Campylobacter Pylori no estomago

    Energy Technology Data Exchange (ETDEWEB)

    Chausson, Y; Coelho, L G.V. [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN), Belo Horizonte, MG (Brazil)

    1990-01-01

    A new method for diagnosing the Campylobacter Pylori in the stomach is described, using C-14 settled urease. Campylobacter Pylori is now being considered the most probable causative agent of antral chronic gastritis, pepitic ulcer and non-ulcerous dyspepsia. The technique is based on ingestion of the tracer, its recovery by exhalation in etanol hyamine solution, followed by counting and dates evaluation. The test was applied to forty two voluntary male and female patients, after their written acquiescence. Their ages varied from 19 to 62 years old. Thirty of the results were positive and twelve negative. All of them were comproved by microbiological (cultura) and hystologycal studies of gastric biopsy gotten by gastroscopy. They were performed at the Gastroentherology Departament of the 'Hospital das Clinicas' that belongs to the Federal University of Minas Gerais. Repetitivity of the breath test was confirmed by repetition of the results in five positive patients and five negative ones. (author).

  11. Synthesis of modified calcium aluminate with lanthanum manganite (LSM) for possible use in solid oxide fuel cell (SOFC); Sintese de aluminato de calcio modificado com manganita de lantanio (LSM) para possivel utilizacao em celula combustivel de oxido solido (SOFC)

    Energy Technology Data Exchange (ETDEWEB)

    Veiga, F.C.T.; Jurado, J.; Sousa, V.C. de, E-mail: faili.cintia@gmail.com [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Escola de Engenharia. Departamento de Materiais; Cava, S.S. [Universidade Federal de Pelotas, RS (Brazil)

    2016-07-01

    The fuel cells solid oxide (SOFC) is made up of three basic elements: two electrodes, the anode and cathode and a conductive electrolyte ions. The objective of this work consists of calcium aluminate synthesis modified LSM in a 1: 1 by combustion synthesis method with a view to its use as a cathode in SOFC. The characterization of the post was carried out by the methods of XRD, TEM and EIS. After heat treatment at 1200°C/4 hours it was possible to obtain Ca0.5Sr1.5MnO4 and CaMnO2.56 phases. The material showed a semiconductor characteristics because with increasing temperature the electrical resistance value tends to decrease obtaining electrical conductivity greater than 10-6S / cm featuring an extrinsic semiconductor with an activation energy of 0.12. Therefore, with an activation energy value within the range of materials used for a SOFC cathodes. (author)

  12. Synthesis of hydroxyapatite nanoparticles onto modified polypropylene surface to be used in bone tissue engineering; Sintese de nanoparticulas de hidroxiapatita na superficie de polipropileno modificado para utilizacao na engenharia de tecido osseo

    Energy Technology Data Exchange (ETDEWEB)

    Cellet, Thelma Sley P.; Pereira, Guilherme M.; Fragal, Elizangela H.; Rubira, Adley F., E-mail: thelmaspc@hotmail.com [Universidade Estadual de Maringa (UEM), Maringa, PR (Brazil). Departamento de Quimica; Companhoni, Mychelle V.P.; Nakamura, Celso V.; Ueda-Nakamura, Tania [Universidade Estadual de Maringa (UEM), Maringa, PR (Brazil). Departamento de Ciencias Basicas da Saude

    2015-07-01

    Chemical modification of polypropylene (PP) films can be explored to prepare innovative materials, for instance materials which can be used in tissue engineering application. The maleimide synthesis onto PP films was made for later polymerizes glycidyl methacrylate (GMA) and to grow up hydroxyapatite nanoparticles (n-HA) by biomimetization method (BM) in metastable simulated body fluid (SBF) for 7, 14 and 21 days. The modification steps were proved by infrared spectroscopy (FTIR) and the n-HA synthesis evidenced by X-ray diffractometry (XRD), scanning electronic microscopy (SEM) and energy dispersive spectroscopy (EDS). PP films exposed to SBF for 14 and 21 days showed n-HA on all over the films surface. The interaction of pre-osteoblasts with the films after 48 hours was evaluated by SEM. The results demonstrate that cells on the surface of n-HA films showed spreading, and number of filopodia similar to the control, wherein the films with greater amount of n-HA appear to have higher filopodia connections between the cells and appear to have its surface covered with higher cell density. (author)

  13. Use of the CoFe{sub 2}O{sub 4} ferrospinel as catalyst in the WGSR process; Utilizacao do ferroespinelio CoFe{sub 2}O{sub 4} como catalisador no processo de WGSR

    Energy Technology Data Exchange (ETDEWEB)

    Lima, M.S.; Dantas, J.; Costa, A.C.F.M., E-mail: joeldadantas@yahoo.com.br [Universidade Federal de Campina Grande (LabSMaC/UFCG), PB (Brazil). Departamento de Engenharia de Materiais. Laboratorio de Sintese de Materiais Ceramicos; Sazaki, J.M. [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil). Departamento de Fisica; Andrade, H.M.C. [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Departamento de Quimica Geral e Inorganica. Lab. de Catalise e Materiais

    2014-07-01

    This work investigates the use of ferrospinel CoFe{sub 2}O{sub 4} as a catalyst in water gas shift reactions (WGSR). The ferrospinel was synthesized by combustion reaction using the following heating conditions: ceramic base, resistive muffle oven, and microwave oven. The samples were characterized by XRD, FTIR, textural analysis and SEM. The catalytic tests were carried out on a bench scale using mixed CO/N{sub 2} (5% CO mol.mol) to the reaction flow 30mL.min{sup -1}, molar ratio H{sub 2}O/CO of 0.3. The results showed that for all heating conditions there was the monophasic formation of CoFe{sub 2}O{sub 4}, with crystallite size ranging from 38 to 40 nm. Samples showed mesoporous characteristics with type II isotherm and hysteresis loop H3. The sample synthesized in the muffle furnace showed the highest conversion rate of 56.0% and the sample synthesized in the ceramic base showed higher selectivity with 90.19% for the WGRS process. (author)

  14. Use of the 3DVH Software as a complementary method of IMRT pretreatment evaluation; Utilizacao do Software 3DVH como metodo complementar de avaliacao de pre-tratamento de IMRT

    Energy Technology Data Exchange (ETDEWEB)

    Lyra, Jesse G.P.; Bruning, Fabio F.; Funchal, Melissa; Toledo, Hugo V.; Bornatto, Pricila; Fernandes, Tatiane C.O., E-mail: jesse_lyra@hotmail.com [Hospital Erasto Gaertner / Liga Paranaense de Combate ao Cancer (LPCC), Departamento de Radioterapia, Curitiba, PR (Brazil)

    2013-04-15

    The aim of this study is to compare the method of treatment planning evaluation for IMRT using the gamma index to the method of the 3DVH Software. The 3DVH Software was used with the MapCheck2 detector 2D array under a 6MV x-ray beam of linear accelerator equipped with 120 leafs MLC. Nine treatment plans of prostate patients chose randomly and fully anonimatize were performed in the Eclipse planning system, using the AAA calculation algorithm in IMRT sliding window technique. These plans were approved and treated according to the gamma analysis criteria of the institution. The comparisons were made in absolute dose and normalized at maximum dose for each field and then with the 3DVH Software the Dmax, Dmean, D15%, D25%, D35% and D50% parameters for the bladder and rectum, Dmean for the bulb, Dmax for the femur and D95% for the PTV were evaluated. In the planar analysis by field, the plans studied had a minimum of 97.5% approval. The PTV-related differences have relative variation from 1.3 to 2.2%, that is, greater coverage than expected for this structure. For the organs at risk, the relative differences observed were between -5.3 to 25.8%, which could result in a non-approved plan if these variations are close to the clinical tolerances of the OAR. The results show that even a plan compatible with greater than or equal to 95% of the points, the gamma analysis does not give enough information if this plan can or cannot be approved for treatment and that there is a need for more detailed verification of the plan which considers not only the planar evaluation, but also the evaluation of the DVH measured, and the 3DVH Software proved be adequate for this analysis. (author)

  15. Thermal activation and characterization of clay aiming their use as sorbent in fixed bed columns to remove cadmium; Ativacao termica e caracterizacao da argila visando sua utilizacao como adsorvente em colunas de leito fixo para a remocao de cadmio

    Energy Technology Data Exchange (ETDEWEB)

    Silva, M.M. da; Rodrigues, M.G.F. [Universidade Federal de Campina Grande (UFCG), PB (Brazil); Silva, M.L.P. [Universidade Federal Rural do Semi-Arido (UFERSA), RN (Brazil); Kleinübing, S.J.; Silva, M.G.C., E-mail: marciliomaximo@yahoo.com.br [Universidade Estadual de Campinas (UNICAMP), SP (Brazil)

    2011-07-01

    In this work we studied the removal of cadmium in a synthetic wastewater using clay of Pernambuco - Brazil, in systems of fixed bed column. Clay was thermally activated at 500 °C. The materials were characterized using X-ray Fluorescence (XRF), X-ray Diffraction (XRD) and nitrogen adsorption (BET method). For tests in fixed bed column, we applied a factorial design 2{sup 2} and found that increasing the flow adversely affects the process of removing cadmium concentration while acting positively. The studies showed these materials as promising for the removal of Cd{sup 2+} ions in synthetic wastewater containing low levels of this metal. (author)

  16. Effect of synthesis method on the preparation of lanthanum chromite for using as ceramic pigment; Influencia do metodo de sintese na preparacao de cromita de lantanio para utilizacao como pigmento ceramico

    Energy Technology Data Exchange (ETDEWEB)

    Dantas, G.C.B.; Ferreira, K.M.B.; Pimentel, P.M., E-mail: gerbeson_dantas@hotmail.com [Universidade Federal Rural do Semi-Arido (UFERSA), Mossoro, RN (Brazil); Melo, D.M.A.; Gomes, D.K.S.; Costa, A.F. [Universidade Federal do Rio Grande do Norte (UFRN), RN (Brazil)

    2016-07-01

    In this paper, LaCrO3 perovskites were synthesized by two synthesis methods, in order to compare these methods in function of microstructure and optical properties. The synthesis routes employed were a method that use gelatin as organic precursor and microwave assisted auto-combustion. The resulting powders were calcined at 800 ° C and 1000 ° C for obtaining the perovskite phase. Then, they were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM); UV-Visible spectroscopy and colorimetric analysis for color identification. No significant changes were observed in the powders synthesized by two routes. The oxides presented orthorhombic perovskite structure. The powders synthesized by the gelatin method were single phase. Chromite lanthanide presented grayish hue being darker in perovskites calcined at higher temperatures. (author)

  17. Feasibility study of photodiodes utilization in the soil-moisture determination by gamma transmission; Estudo da viabilidade da utilizacao de fotodiodos na determinacao de umidade de solos por transmissao gama

    Energy Technology Data Exchange (ETDEWEB)

    Santos, L A.P. dos

    1992-08-01

    This study was done to verify the viability of photodiodes, as gamma radiation detector ({sup 241} Am - Energy=60 KeV), to measure soil water content. The photodiodes used had different mechanical and electrical characteristics, and were tested on soils of different textures. A good linear correlation between the logarithm of the attenuation factor and soil-moisture demonstrated such viability, and that the low photopeak efficiency of these devices is not a limitation to the measurement of soil water content. Furthermore, the stability, the portability, and low cost of such semiconductor devices, including its electronic system, represent relevant characteristics that may justify the development of a reliable gamma meter system for field studies. (author). 37 refs, 21 figs, 20 tabs.

  18. Utilization of sup(32)P fixed in iron oxides and aluminium oxides for soil microbial biomass. Utilizacao de sup(32)P fixado em oxidos de ferro e de aluminio pela biomassa microbiana do solo

    Energy Technology Data Exchange (ETDEWEB)

    Maciel Neto, A; Salcedo, I H [Pernambuco Univ., Recife, PE (Brazil). Dept. de Energia Nuclear

    1991-01-01

    The availability of P fixed in oxi-hydroxides of Fe and of Al for the microbial biomass of a P-deficient soil, was determined following addition of C sources. These oxides were impregnated in a support matrix of filter paper strips and then equilibrated with a P solution (1.5 * 1- sup(-5) M) containing sup(32)P. The strips where then incubated with soil without (control) or with additions of glicose+N (70 hs) or celulose+N (3 weeks), and the CO sub(2) evolved measured. After the incubation, the strips with Fe and Al incubated with soil+glicose had 0.004 and 0.008 {mu}moles cm sup(-2) of P less than the controls, respectively. Biomass activity dessorbed 100 to 200 more P than an exchange resin. The Fe strips incubated with soil+celulose dessorbed 0.002 {mu}moles cm sup(-2) more P than the control, while the Al ones did not differ from the control. In this last case, only about 50% of the cellulose had been decomposed, compared to approximately 85% of the cellulose in contact with the Fe strips. (author).

  19. Utilization of diesel fuel, anhydrous ethanol and additives blend of a stationary diesel engine with rotatory pump; Utilizacao de mistura ternaria alcool, diesel e aditivo em motores do ciclo diesel com bomba de injecao rotativa

    Energy Technology Data Exchange (ETDEWEB)

    Reyes Cruz, Yordanka; Cavado Osorio, Alberto [Centro de Pesquisas de Petroleo (CEINPET), Havana (Cuba); Belchior, Carlos Rodrigues Pereira; Pereira, Pedro P.; Pinto, Nauberto Rodrigues [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Centro de Tecnologia. Dept. de Engenharia Naval e Mecanica; Aranda, Donato A. Gomes [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Escola de Quimica

    2008-07-01

    In this paper is analyzed the performance and fuel consumption of a stationary Diesel engine, with rotary diesel fuel injection pump, using (diesel fuel + anhydrous ethanol + 0.5% additive) blend. The engine performance parameters and fuel consumption tests were performed at the Termic Machine Laboratory, located in Federal University of Rio de Janeiro, and evaluated using a MWM Series 10 model 4.10 TCA. Two test cycles were used for this test program: the tests were carried out starting from the base diesel S-500, used as a reference; the engine operated with (diesel fuel S-500 - 8% anhydrous ethanol - DIOLEFECT additive (0,5% SPAN80 + 0,1% Biomix-D)) blend. The results indicate that: the reduction levels in power and torque of engine are approximately the same which is (2,55{+-}2%), the brake specific fuel consumption increased in 1,8%. (author)

  20. Study of Brasgel clay looking at its use in the removal of heavy metal zinc in analytical effluents; Estudo da argila Brasgel visando sua utilizacao na remocao do metal pesado zinco em efluentes analiticos

    Energy Technology Data Exchange (ETDEWEB)

    Patricio, A.C.L.; Silva, M.M. da; Lima, W.S.; Cartaxo, J. de M.; Rodrigues, M.G.F., E-mail: cadigena@hotmail.com [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Unidade Academica de Engenharia Quimica. Centro de Ciencias e Tecnologia

    2011-07-01

    This work aims to characterize the clay Brasgel in its natural form and after its organophilization through salt distearyl dimethyl chloride (Praepagen) and then evaluate the potential of clay in the process of treating wastewater contaminated by heavy metal zinc. After the treatment technique, specimens in natural form and organoclay were characterized by techniques of X-ray diffraction (XRD), infrared spectroscopy (IR), moreover, was the analysis of the behavior of organoclay in certain organic solvents through the swelling of Foster. In this work we adopted the procedure for removal of Zn{sup +2} present in aqueous solutions, based on a factorial design, 2{sup 2} + 3 repetitions at the central point, with the analysis parameters as the solution pH (3.0 to 5.0) and initial concentration of zinc ranging from 10 to 50 ppm. (author)

  1. Use of natural gas on heavy duty vehicles in Brazil: experience, current scene and barriers that still persist; Utilizacao do gas natural em veiculos pesados no Brasil: experiencia, cenario atual e barreiras que ainda persistem

    Energy Technology Data Exchange (ETDEWEB)

    Machado, Guilherme B.; Melo, Tadeu C.C.; Lastres, Luiz Fernando M. [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES)

    2004-07-01

    In the 80's, because of the oil crisis, the Natural Gas (NG) appeared as a fuel with a great potential for Diesel replacement in Heavy Duty Vehicles. At that time, PETROBRAS with other companies have developed partial conversion technologies from Diesel to NG, known as 'Dual Fuel'. Engine dynamometer and vehicle bus tests have been developed to verify its technical and economical viability. Because of several factors, the Dual Fuel Program did not advance and the experience was interrupted. At the same time, other experiences using NG Otto Cycle bus engines, manufactured in Brazil, have been conducted, mainly at Sao Paulo, nevertheless, without expansion. Currently, factors as increase of the NG converted light vehicles fleet; the NG excess in the National Market, which has contributed to the NG distribution net expansion; the Environmental Legislature in vigor, that continuously determine lower emission limits; the government interest in increasing the NG energy matrix share and in reducing Diesel fuel consumption, and the low NG industrial demand, compose together a great scene to the diffusion of NG as substitute to the Diesel fuel in Heavy Duty Vehicles. (author)

  2. Evaluation of the use of waste of soybeans (Glycine max (L.)) combined with wood waste in making briquet; Avaliacao da utilizacao de residuo de soja (Glycine max (L.)) combinado com residuo de madeira de confeccao de briquetes

    Energy Technology Data Exchange (ETDEWEB)

    Travessini, Rosana; Schutz, Fabiana Costa de Araujo; Anami, Marcelo Hidemassa; Scherpinski, Neusa Idick [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil)], Emails: rosana_travessini@yahoo.com.br, fabianaschutz@gmail.com, mhanami@gmail.com, neusascherpinski@gmail.com

    2010-07-01

    The agricultural industry produces a large amount of which use biomass is an alternative energy economically viable through the compression portion of ligno-cellulose as raw material to replace the wood with an equivalent product, by briquetting. This study aimed to evaluate the technical feasibility of manufacturing fuel briquettes made from soybean residues combined with waste wood. The making of briquettes was performed in the laboratory of Electromechanics of UTFPR campus Medianeira PR. For this analysis, we assessed the content of moisture, ash, fixed carbon content of porosity and higher calorific value. From the results we can conclude that the manufacture of briquettes from lignocellulosic raw materials is an extremely viable energy flashlight for the region of the Bacia do Rio Parana III. (author)

  3. Utilization of solar electric fence for containment of caprine in familiar production of the Pernambuco semi-arid region; Utilizacao de cerca eletrica solar para confinamento de caprinos na producao familiar do semi-arido pernambucano

    Energy Technology Data Exchange (ETDEWEB)

    Costa, Heitor Scalambrini; Costa Neto, Guilherme [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Nucleo de Apoio a Projetos de Energias Renovaveis], Email: naper@ufpe.br; Araujo, Kassia; Silva, Gerson Flavio da; Raquel, Karine [ONG NAPER SOLAR, Recife, PE (Brazil). Centro de Estudos e Projetos], Email: nsolar@terra.com.br

    2006-07-01

    The Center for Studies and Projects - Naper Solar is an NGO, which works for the dissemination of use of alternative energies resources in the semi-arid Brazilian Northeast in collaboration with the Federal University of Pernambuco. It has implemented caprine raising systems in the back lands of Pajeu in the State of Pernambuco making use of electrified fences energized by solar energy.This project was executed in a joint effort with the City Halls of Afogados da Ingazeira e Sao Jose do Egito and the NGOs Diaconia and the Northeast Woman House and has benefited 20 families of farmers from 9 rural communities. It is funded by a Technical Cooperation Program established between the National Fund for the Environment - Ministry for the Environment and the Netherlands Government. The implemented system, in opposition to the traditional extensive production system, allow for a more animal sanitary control - minimizing the risks of contamination; a more controlled and balanced feeding system - taking into account the weight gaining factor together with pasture management, leading the a guarantee of food supply for the animals. Other advantages of this system include the reduction of fence cost and less deforesting. Electrical fences used in the contention of caprine are built with only 4 straight wires, fixed with isolators on wood posts spaced 10 m from each other, while the conventional fences use 9 barbed-wire lines fixed with clamps on posts spaced 1 m from each other. Therefore, the use of electrical fences instead of the conventional one represent a cost reduction, which can go as high as 40 % of the total cost. Besides that the electrical fences have low maintenance cost, easier and faster installation and relocation. The fenced areas vary from 0.5 ha to 4 ha for the raising of 5 to 50 animals. In the electrification of a fence one needs one photovoltaic module, one electrifier, a battery, isolators (passage and corner), electric ground rods and a thunderbolt deviator kit. In this work the component of an solar electric fence are described together with its main benefits and installation and maintenance costs. (author)

  4. Radiochromic film use to record dose profile variations in chest CT scan; Utilizacao do filme radiocromico para registro da variacao do perfil de dose em varredura de TC de torax

    Energy Technology Data Exchange (ETDEWEB)

    Mourao, Arnaldo P.; Santana, Priscila C., E-mail: aprata@des.cefetmg.br [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Departamento de Engenharia Nuclear; Silva, Teogenes A. da; Alonso, Thessa C. [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)

    2015-12-15

    The CT scans generate higher doses in patients than those caused by other types of diagnostic radiology using the attenuation of X-ray beams. Technological advances have increased the clinical applications of computed tomography (CT) and consequently the demand for these exams. Dose reduction strategies are difficult to implement because of a lack of proper guidance on the CT scanning. However, CT offers the possibility of adjusting the image acquisition parameters according to the patient physical profile and the diagnostic application for which it is intended to scan. Knowledge of the dose distribution is important when thinking about varying the acquisition parameters to reduce the dose. In this work was used a PMMA chest phantom to observe the dose deposition in 5 areas. Radiochromic film strips were placed inside the chest phantom, in peripheral and in the central region. The phantom was placed in the scanner isocenter and it was performed the irradiation of its central region using a chest acquisition protocol. After the phantom CT scan the radiochromic film strips were processed for obtaining digital images. Digital images were reworked to obtain the dose variation profiles for each position. The results showed a wide variation in absorbed dose by the phantom, either within a same position along the length of the film strip, as in the comparison among the five regions which the strips are placed. In this second case the dose variations were even greater. (author)

  5. The use of genetic algorithms with niching methods in nuclear reactor related problems; A utilizacao dos metodos de nichos dos algoritmos geneticos na otimizacao de problemas de reatores nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Sacco, Wagner Figueiredo

    2000-03-01

    Genetic Algorithms (GAs) are biologically motivated adaptive systems which have been used, with good results, in function optimization. However, traditional GAs rapidly push an artificial population toward convergence. That is, all individuals in the population soon become nearly identical. Niching Methods allow genetic algorithms to maintain a population of diverse individuals. GAs that incorporate these methods are capable of locating multiple, optimal solutions within a single population. The purpose of this study is to test existing niching techniques and two methods introduced herein, bearing in mind their eventual application in nuclear reactor related problems, specially the nuclear reactor core reload one, which has multiple solutions. Tests are performed using widely known test functions and their results show that the new methods are quite promising, specially in real world problems like the nuclear reactor core reload. (author)

  6. Radiation therapy using the wildlife medicine: a reasoned obtained study in cases of literature; Utilizacao da radioterapia na medicina de animais selvagens: um estudo fundamentado em casos obtidos da literatura

    Energy Technology Data Exchange (ETDEWEB)

    Vettorato, Michel de Campos; Fernandes, Marco Antonio Rodrigues; Vulcano, Luis Carlos [Universidade Estadual Paulista Julio de Mesquita Filho (FMVZ/UNESP), Botucatu, SP (Brazil). Faculdade de Medicina Veterinaria e Zootecnia; Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Botucatu, SP (Brazil). Dept. de Dermatologia e Radioterapia

    2016-03-15

    The cancer is the kind of tumor that affects both humans and animals and is responsible for more deaths worldwide. In wildlife, cancer is a problem found most often in zoo animals. Thus veterinary oncologists have researched and developed therapeutic approaches to many types of cancer over the years in both curative and palliative therapies including therein the application of radiation. The basic principle of radiotherapy is the effect of ionizing radiation on the tumor cells, causing them to death. However, its application in veterinary medicine for wildlife is not much reported in the literature, especially in Brazil. This study aims to describe and compare some of radiotherapy applications in different species of wildlife looking to improve her knowledge in veterinary medicine through a brief literature review. After the descriptions and comparisons, it is concluded that despite the number of cases taken for this study, all the cases mentioned had satisfactory results using radiation therapy and all the presented cases provided relevant information that can guide future researchers in this area, thus improving knowledge of this therapy and improve the quality of life of animals. (author)

  7. Hybrid regression trees applied to the monitoring of dynamic safety of isolated networks with large eolic production contribution; Utilizacao de arvores de regressao hibridas na monitorizacao da seguranca dinamica de redes isoladas com grande producao eolica

    Energy Technology Data Exchange (ETDEWEB)

    Lopes, J.A Pecas; Vasconcelos, Maria Helena O.P. de [Instituto de Engenharia de Sistemas e Computadores (INESC), Porto (Portugal). E-mail: jpl@riff.fe.up.pt; hvasconcelos@inescn.pt

    1999-07-01

    This paper describes in a synthetic manner the technology adopted to define structures used in the fast evaluation of dynamic safety of isolated network with high level of eolic production contribution. This methodology uses hybrid regression trees, which allows the quantification the endurance connected to the dynamic behavior of these networks by emulating the frequency minimum deviation that will be experienced by the system when submitted toa pre-defined perturbation. Also, new procedures for data automatic generation are presented, which will be used for construction and measurements of the evaluation structures performance. The paper describes the Terceira island - Acores archipelago network study case.

  8. Study and characterization of dosimeter LiF:Mg,Cu,P for using in aeronautical dosimetry; Estudo e caracterizacao do dosimetro de LiF:Mg,Cu,P para utilizacao em dosimetria aeronautica

    Energy Technology Data Exchange (ETDEWEB)

    Flavia, Hanna, E-mail: hannasantana.f@gmail.com [Universidade Paulista (UNIP), Sao Jose dos Campos, SP (Brazil); Federico, Claudio; Lelis, Odair; Pereira, Heloisa; Pereira, Marlon, E-mail: claudiofederico@ieav.cta.br [Instituto de Estudos Avancados (EFA-A/IEAV), Sao Jose dos Campos, SP (Brazil). Div. de Fisica Aplicada

    2014-07-01

    The effects of cosmic ionizing radiation incidents in aircraft components and crews has been a source of concern and motivated increasingly studies and improvements in the area. The low dose rates involved in this radiation field in aircraft flight altitudes imply Dosimetric necessity of using materials with high efficiency of detection, to enable studies lower cumulative doses resulting in shorter routes or lower altitude. The choice of thermoluminescent dosimeters LiF: Mg, Cu, P was done by having a detection efficiency of about fifteen times higher than its predecessor (LiF: Mg, Ti), and therefore, applied in very low doses dosimetry, and environmental dosimetry . The implementation of the use of pair dosimetric TLD-600H and 700H-TLD will serve as support for testing and studies on the effects of low doses of cosmic radiation in environmental dosimetry applied in the aviation environment in the usual flight altitudes. In this paper are presented the results of development of a methodology for dosimetry low doses of gamma radiation and neutrons using the pair dosimetric TLD-600H and 700H-TLD. The results demonstrate a sensitivity of dosimeters well above the dosimeters LiF: Mg, Ti confirming its suitability for dosimetry of low doses.

  9. Analysis of the feasibility of solar heating systems composite for packaging recyclable for use in rural low income; Analise da viabilidade economica de sistemas de aquecedores solares compostos por embalagens reciclaveis para utilizacao em comunidades rurais de baixa renda

    Energy Technology Data Exchange (ETDEWEB)

    Gabriel Filho, Luis Roberto Almeida; Maiochi, Tamara; Pereira, Danilo F.; Magalhaes, Marcelo M. de [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Tupa, SP (Brazil)], email: gabrielfilho@tupa.unesp.br; Cremasco, Camila P. [Faculdade de Tecnologia (FATEC), Presidente Prudente, SP (Brazil); Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Botucatu, SP (Brazil). Dept. de Bioestatistica

    2011-07-01

    Solar heaters are an appropriate technology for tropical and sub tropical to warm bath water through the energy in sunlight. The development of conventional solar heaters is in the market and its acceptance is still low due to high cost. However, low-cost solar heaters have been developed in recent years to meet a consumer demand that currently do not have access to this technology, especially low-income rural communities. The aim of this study was to analyze the economic feasibility of solar water heaters built with recyclable materials (plastic bottles and milk cartons) through the consequent reduction of sales of electricity. For development work, a heater was built with recyclable materials in accordance with the manuals provided by the Department of the Environment of Parana (SEMA) and found time to use electric showers by families of rural properties in order to determine the costs and billing of electricity. By spending on materials, we concluded that the system was feasible, with amortization over 13 months in fixed installments of R$ 23.79. (author)

  10. Use of 2 D-NMR in the structural study of a Trichilia hirta (Meliaceae) isolated limonoid; Utilizacao de RMN-2D na elucidacao estrutural de um limonoide isolado de Trichilia hirta (meliaceae)

    Energy Technology Data Exchange (ETDEWEB)

    Cortez, Diogenes A.G. [Universidade Estadual de Maringa, PR (Brazil). Dept. de Farmacia-Bioquimica; Vieira, Paulo C; Fernandes, Joao B; Silva, M.Fatima G.F. da; Ferreira, A Gilberto [Sao Carlos Univ., SP (Brazil). Dept. de Quimica

    1992-12-31

    We have recently studied a T. hirta specie and obtained a limonoid which has a structure similar to the hirtine. The obtained limonoid differs from the hirtine by the absence of an epoxy group in C-14 and C-15, and a propionyl oxy group replacement by a iso butyryl oxy bound to a C-12. NMR-2 D has been used for the structural study of the limonoid obtained from the Trichilia hirta (meliaceae) 8 refs., 1 fig., 3 tabs.

  11. The utilization of induction generators working with PATs (pumps working as turbines) in electric energy generation; A utilizacao de geradores de inducao acionados por BFTs (bombas funcionando como turbinas) na geracao de energia eletrica

    Energy Technology Data Exchange (ETDEWEB)

    Viana, Augusto Nelson Carvalho; Rezek, Angelo Jose Junqueira; Medeiros, Daniel de Macedo [Universidade Federal de Itajuba (UNIFEI), MG (Brazil). Programa de Pos-graduacao em Engenharia da Energia], e-mail: augusto@unifei.edu.br, e-mail: rezek@iee.efei.br, e-mail: macedo@unifei.edu.br

    2004-07-01

    The utilization of the Pumps working as Turbines (PATs) in micro hydro-energy resources to replace the conventional turbines as Pelton, Francis and Propeller have been used in countries as USA, Germany and France. In the mean time, in Brazil this practice and the utilization of induction generators working with PATs is still in the scope of the laboratory experiments. This work, based on experimental results carried on in Laboratory of Hydromechanics for Small Hydro Power Plants (Laboratorio Hidromecanico para Pequenas Centrais Hidroeletricas - LHPCH - UNIFEI), (VIANA, 1987), (VIANA e NOGUEIRA, 1990), propose the utilization of asynchronous generator groups operating with PATs. To show the investment cost decrease in micro hydro power plants (MHPs), is showed the Boa Esperanca MPH example, in which is presented a comparison between the synchronous generator group cost working with a Michell-Banki turbine and a asynchronous generator group operating with a PAT. (author)

  12. Profit of solar energy for salting and drying of a brazilian fish Colossoma mitrei Berg, 1895; Utilizacao da energia solar para avaliacao da salga e secagem do pacu, Colossoma mitrei Berg, 1895

    Energy Technology Data Exchange (ETDEWEB)

    Sales, Ronaldo de Oliveira [1Ceara Univ., Fortaleza, CE (Brazil). Centro de Ciencias Agrarias; Beirao, Luiz Henrique [Santa Catarina Univ., Florianopolis, SC (Brazil). Dept. de Ciencias e Tecnologia de Alimentos

    1986-12-01

    This paper studied a simple method for processing dried-salted `pacu` fish. The average weight in relation to total weight was 58,6% and the result came very close to the average of weight of other dried salted fishes, when treated in same way. The main purpose of this process was to reduce the long time expanded by the conventional process, allowing to reduce the humidity of the dried-salted product from 56 to 43,5% in 28 hours only. (author) 20 refs., 3 figs., 8 tabs.

  13. Evaluation of specific consumption from the use of chicken oil biodiesel in one cylinder generator set; Avaliacao do consumo especifico a partir da utilizacao de biodiesel de oleo de frango em um grupo-gerador monocilindrico

    Energy Technology Data Exchange (ETDEWEB)

    Fiorese, Diego Augusto [Universidade Federal de Santa Maria (PGEAGRI/UFSM), RS (Brazil). Dept. de Engenharia Rural. Programa de Pos-Graduacao em Engenharia Agricola], E-mail: dafiorese@yahoo.com.br; Lima, Paulo Peruzzo de [Faculdade Assis Gurgacz (FAG), Cascavel, PR (Brazil); Souza, Abel Alves de; Souza, Samuel Nelson Melegari de [Universidade Estadual do Oeste do Parana (UNIOESTE), Cascavel, PR (Brazil). Dept. de Ciencias Exatas e Tecnologicas; Dallmeyer, Arno Udo [Universidade Federal de Santa Maria (PGEAGRI/UFSM), RS (Brazil). Programa de Pos-Graduacao em Engenharia Agricola

    2010-07-01

    Biodiesel can be produced from numerous materials, including by-products of animal chain. In this scenario, the chicken's oil, that is located and an environment not explored for biodiesel production, can be a good alternative in South and Southeast Brazilian Region, where they are slaughtered around 9.100.000 chickens per day. In order to determine the specific consumption from a generator set with single cylinder 6.6 kW of power and generation capacity of 5 kW, using chicken oil biodiesel (B-100), were performed the bench test using a auxiliary tank, precision scale and an energy analyzer. Were conducted four treatments (25%, 50%, 75% and 100% of generating capacity). The worst SC was the engine at 25% of generation capacity (1.5 kW) and better with 75% of maximum load (3.75 kW) with a mean of 479.34 g kWh{sup -1}. By Turkey's test ant 5% probability there was a significant difference only for the first treatment. (author)

  14. Ways to use and building solar heating with reusable materials in rural and urban low-income communities; Formas de utilizacao e construcao de aquecedores solares com materiais reaproveitaveis em comunidades rurais e urbana de baixa renda

    Energy Technology Data Exchange (ETDEWEB)

    Gabriel Filho, Luis Roberto Almeida; Putti, Fernando Ferrari [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Tupa, SP (Brazil); Seraphim, Odivaldo Jose [Universidade Estadual Paulista Julio de Mesquita Filho (FCA/UNESP), Botucatu, SP (Brazil). Fac. de Ciencias Agronomicas; Cremasco, Camila Pires [Universidade Estadual Paulista Julio de Mesquita Filho (FCA/UNESP), Botucatu, SP (Brazil); Faculdade de Tecnologia (FATEC), Presidente Prudente, SP (Brazil); Caneppele, Fernando de Lima [Universidade de Sao Paulo (FZEA/USP), SP (Brazil). Fac. de Zootecnia e Engenharia de Alimentos; Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Itapeva, SP (Brazil)

    2012-11-01

    The search for cleaner energy sources, gave rise to the solar heaters, which are the most widely used systems in energy savings for heating water, but due to its high investment cost, this device becomes inaccessible to low-income communities. Noting the demand for low cost system for these communities, the project aimed to promote the scientific dissemination in academia and the population to build solar heaters composed of recyclable packaging such as milk cartons and bottles pet. and due to large populations still residing in rural areas, this becomes feasible, because it is a small-scale system and easy construction and because of this facility may be disseminated among the neighbouring owners, and can be used for domestic use, as well as in rural utensils hygiene. For the realization of the project, the prototypes were developed in the interior of the Sao Paulo cities and rural properties. The courses will aim the dissemination and the methods to be carried out the construction of the systems and the end was carried out a questionnaire, which sought to verify the effective deployment and construction in residential properties. From the present study seeks to start a deployment of these types of systems at State level, and aims to create public policies for the promotion of their actual deployment in all cities in the State from this project. (author)

  15. PETROBRAS green petroleum coke used as partial replacement for coal injected mixtures in blast furnaces; Utilizacao do coque verde de petroleo da PETROBRAS em substituicao parcial ao carvao mineral das misturas injetadas em altos fornos

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Agenor Medrado da; Medrado, Swami Botelho; Noblat, Sebastiao Jorge Xavier [Companhia Siderurgia Nacional. CSN. Gerencia Geral de Processos Siderurgicos. RJ (Brazil)], e-mails: ams@csn.com.br, swami@csn.com.br, s.noblat@csn.com.br; Carvalho Junior, Joao Andrade de [Universidade Estadual Paulista Julio de Mesquita Filho. Faculdade de Engenharia de Guaratingueta. Departamento de Energia, SP (Brazil)], e-mail: joao@feg.unesp.br

    2010-04-15

    The PETROBRAS produced green petroleum coke (GPC) is a carbon rich fuel, virtually ash-free, with low sulfur content and is a fuel suitable to replace metallurgical coke in blast furnaces. The GPC was tested in a pulverized coal injection simulator built in the Volta Redonda research center. It presented a low burning efficiency due to low volatile material content and high substitution rate by the carbon content. The industrial-scale tests were carried out in blast furnaces with up to 50% PETROBRAS GPC in the coal blends, which has never been done before in the steel industry. The injected coal/CVP mixtures produced no negative side effects in the blast furnace grinding systems, pneumatic conveying or operating process. The mixture burning process inside the blast furnace, showed a decrease in fuel consumption, with a significant reduction in metallurgical coke consumption. The industrial-scale tests of the GPC mixtures did not reach the 70% maximum for lack of the GPC feedstock, it being necessary to continue with standard coal mixtures. (author)

  16. Utilization of bromeliad Tillandsia Usneoides L. in biomonitoring of air pollution in the metropolitan region of Sao Paulo - SP, Brazil; Utilizacao da bromelia Tillandsia Usneoides L. no biomonitoramento da poluicao atmosferica na Regiao metropolitana de Sao Paulo - SP, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Albuquerque, Caroline R.; Figueiredo, Ana M.G.; Silva, Barbara C. da; Ticianelli, Regina B., E-mail: calbuuquerque@gmail.com, E-mail: anamaria@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Figueira, Rubens C.L., E-mail: aportellar@yahoo.com.br [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Instituto Oceanografico; Nievola, Catarina C.; Alves, Edenise S.; Domingos, Marisa, E-mail: ccnievola@uol.com.br, E-mail: ealves@ibot.sp.gov.br, E-mail: mmingos@superig.com.br [Instituto de Botanica (IBt-SMA/SP), Sao Paulo, SP (Brazil); Ribeiro, Andreza P., E-mail: andrezp@uninove.br [Universidade Nove de Julho (UNINOVE), Sao Paulo, SP (Brazil)

    2013-07-01

    In this study, it was determined the metals Cd, Cu, Fe, Mo, Ni, Pb and Sb in plant Tillandsia Usneoides L., an epiphyte species popularly known as old beard and able to absorb water and nutrients directly from air, aiming to estimate the contribution of human activities in atmospheric metal pollution in the metropolitan region of Sao Paulo. The samples were collected at five different points, located near the South West and stretches of highway Mario Covas (SP-21). The Neutron Activation Analysis (NAA) and Optical Emission Spectrometry with Inductively Coupled Plasma (ICP-OES) were the analytical techniques used in the quantification of metals of interest.

  17. Use of residues proceeding from marbles and granites finishing and manufacturing processes as raw material for structural ceramic; Utilizacao do residuo proveniente do acabamento e manufatura de marmores e granitos como materia-prima em ceramica vermelha

    Energy Technology Data Exchange (ETDEWEB)

    Mello, Roberta Monteiro de

    2006-07-01

    In order to decrease environmental impact, caused by mud discarding and clay extraction in the ceramic industry, it was used residual mud from marble and granite companies for structural ceramic. Samples were collected in twelve different marble companies located at the metropolitan region of Sao Paulo. However, only four samples were selected, based on its different characteristics. Clay stone was the raw material chosen to prepare the structural ceramic, considering its high use in this segment. Samples and clay stone were both analysed by the following procedures: granulometric analysis, x-rays fluorescent chemical analysis and x-rays diffraction mineralogical analysis, besides, tests in the samples were conducted following NBR 10004 standards. Once raw materials were characterized, the plasticity test was conducted. Test specimen were molded with different levels of mud, then burned and submitted to technological tests, such as: mechanical resistance, water absorption, porosity, specific gravity and retraction, material dilation before burning process and scanning electron microscopy. The final results have shown the viability of using this kind of mud, and pointed some advantages on its usage, but taking in consideration some previous conditions to be adopted. (author)

  18. Assessing the safety aspects for use of multilayer pipes in gas distribution of domestic installation; Avaliacao dos aspectos de seguranca para utilizacao de tubos multicamada em instalacoes de distribuicao de gas em residencias

    Energy Technology Data Exchange (ETDEWEB)

    Bratfisch, Carlos do Amaral Coutinho [Bratfisch - Engenharia em Gas, Sao Paulo, SP (Brazil); Emmeti, Sao Paulo, SP (Brazil); Collela, Ricardo [FGS Brasil Industria e Comercio Ltda., Cotia, SP (Brazil)

    2012-07-01

    The gas distribution networks average flow at the Brazilian market is low and the operating pressure is less than 2.0 kgf/cm{sup 2}. These values are lower if compared to other countries and due this, gas distribution companies, major builders and developers have started a movement to find alternatives to reduce their installation costs, and they have identified in other countries the multilayer system. Because of the great interest of the consumer market for this alternative, and since there is no standards in Brazil that could regulate it, a technical committee was established under the ABNT in order to prepare a standard draft meeting the local market particularities as well this technology requirements. Then it was initiated a quest looking for the knowledge of the 'state of the art' of this technology in various locations around the world, especially Europe, Asia and Oceania, which shows that, with few exceptions, the knowledge of this alternative is still on the beginning, and even in countries where this system is a pioneer some doubts exist with respect to their usage limit. The multilayer system materials were already used at hot and cold water networks for more than twelve years, but only after that it was made an adaptation for building installations of gas distribution networks. Due the need to search and establish safety criteria both with respect to the product as its installation shape, did the necessary motivation to perform a more detailed study of this new technology, meeting the needs of this market. The intention is to present to the consumer market a series of comparative data definitions and techniques to identify this as a modern, updated, economic, efficient and safe alternative option for gas distribution networks. (author)

  19. The use of lichens as bioindicators of atmospheric contamination by natural radionuclides and metals in a region impacted by TENORM; Utilizacao de liquens como bioindicadores de contaminacao atmosferica por radionuclideos naturais e metais em regiao impactada por TENORM

    Energy Technology Data Exchange (ETDEWEB)

    Leonardo, Lucio

    2010-07-01

    The main aim of this thesis is to study the possibility of using lichen as bioindicator of atmospheric pollution in regions contaminated by radionuclides, metals and rare earth elements. Two regions were chosen, one in Pirapora do Bom Jesus, where a tin and lead industry is located, and a second one in Cubatao, where a phosphate fertilizer industrial complex is located. The two industries chosen are considered as TENORM - Technologically Enhanced Naturally Occurring Radioactive Material, since they can cause a significant increase in the natural radionuclides concentration in the industrial process, and consequently a potential increase in the radiation exposure in products, byproducts and residue. To achieve this aim, the radionuclides {sup 238}U, {sup 226}Ra, {sup 210}Pb, {sup 2'}3{sup 2}Th and {sup 228}Ra, rare earth elements and metals were analyzed in samples of raw material and residues from the installations, lichens and soils. Lichens and soil samples were analyzed by instrumental neutron activation analysis for the determination of uranium, thorium, rare earth elements and metals. The radionuclides {sup 226}Ra, {sup 228}Ra and {sup 2}'1{sup 0}Pb in soil samples were determined by gamma spectrometry and in lichen sample by radiochemical separation and gross alpha and beta counting on a gas flow proportional counter. The concentrations of {sup 238}U (from 19 to 473 Bq kg{sup -1}), {sup 226}Ra (from 21 to 265 Bq kg{sup -1}), {sup 210}Pb (from 401 to 1461 Bq kg{sup -1}), {sup 232}Th (from 15 to 574 Bq kg{sup -1}), {sup 228}Ra (from 176 to 535 Bq kg'-{sup 1}), rare earth elements, Hf and Ta determined in lichen samples around the tin and lead industry show an enrichment in these elements. Therefore, the lichens can be used as a fingerprint of the atmospheric contamination. The results obtained for the lichen samples, in the Cubatao region, present a fingerprint mainly of {sup 210}Pb, from industries of the region. The results obtained in this study showed that the lichens can be used as bioindicators of atmospheric pollution by radionuclides and trace elements. (author)

  20. Application of low density from pig in subsea satellite well flow line; Utilizacao de pig-espuma de baixa densidade em linhas de producao de pocos-satelites submersos

    Energy Technology Data Exchange (ETDEWEB)

    Lima, Paulo Cesar Ribeiro; Couto, Nilton Castro; Souza, Robson Oliveira [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas. Divisao de Explotacao

    1995-01-01

    This work describes a new concept of pigging using low density form to prevent/removal of wax in subsea satellite well flowline. The methodology of wax control is world pioneer. The pigs are sent through a 2.5 in lift gas line, and through a wet x-mas tree, not designed to be pigged, and back through the flowline. (author) 2 refs., 1 fig.

  1. Use of ZnO:Mn particles for degradation of methylene blue by photocatalysis process; Utilizacao de particulas de ZnO:Mn para a degradacao do azul de metileno por processo de fotocatalise

    Energy Technology Data Exchange (ETDEWEB)

    Giraldi, T. R.; Swerts, J. P.; Vicente, M. A., E-mail: tania.giraldi@unifal-mg.edu.br, E-mail: jefersonps21@hotmail.com, E-mail: maquelyaspr@oi.com.br [Universidade Federal de Alfenas (UNIFAL), Pocos de Caldas, MG (Brazil). Instituto de Ciencia e Tecnologia; Mendonca, V.R. de, E-mail: vrm@ifsp.edu.br [Instituto Federal de Educacao, Ciencia e Tecnologia de Sao Paulo (IFSP), Itapetininga, SP (Brazil); Paris, E.C.; Ribeiro, C., E-mail: elaine.paris@embrapa.br, E-mail: caue.ribeiro@embrapa.br [Embrapa Instrumentacao, Sao Carlos, SP (Brazil)

    2016-10-15

    The management of water use in the agricultural environment is a key factor to build new environmentally sustainable productive methods. Photocatalysis is a promising method for water decontamination. This research paper aimed to evaluate the photocatalytic potential of pure and Mn-doped ZnO particles. The materials were obtained by the polymeric precursor method, and characterized by X-ray diffraction, N{sub 2} adsorption in low temperature, infrared and ultraviolet spectroscopy, and photoluminescence. In order to evaluate ZnO:Mn particles photo efficiency, experiments were carried out by applying the methylene blue dye solution to photodegradation under UVC exposure. The particles had ZnO single-phase, but low specific surface area. The sample ZnO:0.25% Mn presented higher efficiency in the methylene blue photocatalytic degradation test. This efficiency was related to a higher band gap energy value and a lower rate of electron recombination, which allows greater formation of hydroxyl radicals, which are responsible for dye degradation. (author)

  2. Evaluation of Cortaderia selloana (Capim-dos-pampas) blankets as sorbent materials for oil spills in simulated hydro equipment; Estudo do desempenho de tecidos e mantas para utilizacao como sorventes para petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Bonetti, T.F.; Sydenstricker, T.H.D. [Universidade Federal do Parana (UFPR), Curitiba, PR (Brazil)], e-mail: thais@demec.ufpr.br; Amico, S.C. [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil)

    2006-07-01

    Oil spills in aquatic environments may cause serious economy losses and severe environmental impact which both drive the development of commercial systems (e.g. sorbents) to control these accidents. One way of using sorbents is to encapsulate them with an involucre or cover, i.e. producing blankets. The focus of this research is to evaluate the key characteristics of interest (aerial density, water and oil sorption, mechanical strength and cost) of different materials to use as covers for blankets and to prepare blankets and compare their performance when made with various core materials, such as Cortaderia selloana fibers and different commercial sorbents. A simulated aqueous body with stream was used for the sorption experiments, where the oil and water phases were circulated and forced to pass under the blankets. On the sorption tests, the fibers of Cortaderia selloana reached a performance lower to that of commercial sorbents, mainly due to their low density and high volume (difficult packing), nevertheless a clear trend was noted, heavier blankets with higher sorption periods lead to higher sorption. (author)

  3. Utilization of the secondary energy of Itaipu, Parana State, Brazil, for electrolytical ammonia production for nitrogenous fertilizers synthesis; Utilizacao da energia secundaria da usina hidreletrica de Itaipu, PR, Brasil para producao de amonia eletrolitica para sintese de fertilizantes nitrogenados

    Energy Technology Data Exchange (ETDEWEB)

    Souza, S.N.M. de; Siqueira, J.A.C.

    2000-07-01

    Secondary energy can be described as a surplus of electrical energy in hydraulic power plant due to the lower demand of energy during some periods of time, and the excess of water in the reservoir, during rainy periods. The largest hydroelectric power plant both in Brazil and South America is Itaipu, jointly operated by Brazil and Paraguay. This power plant has a large amount of secondary energy available, and this energy is lost as no turbine spilled water out of the reservoir. This study proposes the using of this energy for electrolytic hydrogen production and ammonia for nitrogenous fertilizers. The hydrogen is produced as a gas by mean of electrolyses and with the atmospheric nitrogen for the electrolytic ammonia synthesis, used as the most important raw material for the nitrogen fertilizers synthesis. This study performs the determination of the minimal cost of hydrogen production and the correspondent hydrogen production capacity in accordance with the ammonia market for nitrogenated fertilizers in the Center/South region, estimating the better production capacity for an ammonia plant to be installed close to Itaipu.

  4. Equipment stainless steel entire versus steels bimetallics clad or overlay; Utilizacao de equipamentos de processo construidos em aco inoxidavel integral versus acos bimetalicos cladeado ou 'overlay'

    Energy Technology Data Exchange (ETDEWEB)

    Batista, Itamar da Silva; Lima, Jadival Carneiro de; Leal, Murilo Fonseca; Cardoso, Amauri dos Santos; Jorjan, Roberto [PETROBRAS S.A., Sao Francisco do Conde, BA (Brazil). Refinaria Landulfo Alves Mataripen (RLAM)

    2008-07-01

    This study does not recommend the use of a pressure vessel made of integral stainless steel, due to the failure mechanisms under stress corrosion assisted by chlorides or polythionic acid. Are presented case studies of literature and analysis of reports of proceedings of RLAM reactors, showing that the materials produced by bimetallic clad overlay or are more appropriate, in terms of integrity, for use in equipment that the internal environment requires austenitic stainless steel specification.

  5. Utilization of the BR-SIPP systems (Integrated Refinery Scheduling System) at the PETROBRAS Capuava refinery; Utilizacao do sistema BR-SIPP - Sistema Integrado de Programacao de Producao PETROBRAS na refinaria de Capuava

    Energy Technology Data Exchange (ETDEWEB)

    Joly, Marcel [PETROBRAS, Maua, SP (Brazil). Refinaria de Capuava (RECAP). Gerencia de Otimizacao]. E-mail: joly@petrobras.com.br; Hassimotto, Marcelo Kenji [PETROBRAS, Rio de Janeiro, RJ (Brazil). Gerencia de Solucoes de Negocios de Logistica e Planejamento]. E-mail: kenji@petrobras.com.br; Magalhaes, Marcus Vinicius de Oliveira [PETROBRAS, Rio de Janeiro, RJ (Brazil). Gerencia de Otimizacao]. E-mail: vinicius@petrobras.com.br

    2007-04-15

    The BR-SIPP is a production scheduling decision support tool for refineries. It is integrated into the Corporate Inventory, Movements and Quality Data Base and is based on events simulation technology for the elaboration and analysis of scheduling scenarios. Its utilization at the Capuava Refinery allows the production programming team to analyze and anticipate difficulties and opportunities, thereby being able to make viable a potential integration of management and people directly involved with the refinery scheduling information, such as planning, logistics and commercial areas. (author)

  6. Synthesis and characterization of polyaniline/clay conducting nanocomposites for use in protective coatings; Sintese e caracterizacao de nanocompositos condutores de polianilina/argila para utilizacao em revestimentos protetores

    Energy Technology Data Exchange (ETDEWEB)

    Baldissera, A.F.; Ferreira, C.A.; Senisse, C.A.L.; Oliveira, L.S., E-mail: alebaldissera@hotmail.co [Universidade Federal do Rio Grande do Sul (LAPOL/UFRGS), Porto Alegre, RS (Brazil). Lab. de Materiais Polimericos

    2010-07-01

    Nanomaterials have been shown highly promising materials for various technological applications. In engineering, may be noted the polymer nanocomposites, which are a new class of composite materials, where a nanoclay, or charge with nanometric dimensions, is dispersed in a polymer matrix at low concentration or volume. The clays are more common and when added in quantities less than 5% in the nanocomposites, cause a significant increase in these properties, such as mechanical, optical, magnetic barrier, and especially permeability and flammability. In this context, this work aimed at obtaining the polymeric nanocomposites of polyaniline (PAni) with different commercial clays (cloisite Na{sup +}, 10A and 30B). The preparation of PAni-MMT nanocomposites was performed by in situ polymerization of aniline in acidic (HCl). Electrical conductivity measurements, infrared spectroscopy and X-ray diffraction were some of the techniques used to characterize the nanocomposites. (author)

  7. Utilization of computational simulator for comparison of correlations in multiphase flow in ESP (Electrical Submersible Pumping) systems; Utilizacao de simulador computacional para a comparacao das correlacoes de escoamento multifasico em sistemas BCS

    Energy Technology Data Exchange (ETDEWEB)

    Anjos, Roselaine M. dos; Maitelli, Carla Wilza S.P.; Maitelli, Andre L. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil); Costa, Rutacio O. [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil)

    2012-07-01

    Electrical Submersible Pumping (ESP) is an artificial lifting method which can be used both onshore and offshore for the production of high flow rates of liquid. By using the computational simulator for systems ESP developed by the AUTOPOC/LAUT - UFRN, this work aimed to evaluate empirical correlations for calculation of multiphase flow in tubing typical of artificial lifting systems operating by ESP. The parameters used for evaluating the correlations are some of the dynamic variables of the system such as head that indicates the lifting capacity of the system, the flow rate of fluid in the pump and the discharge pressure at the pump. Five (5) correlations were evaluated, from which only one considered slipping between phases, but does not take into account flow patterns and, four others considering slipping between the phases as well the flow patterns. The simulation results obtained for all these correlations were compared to results from a commercial computational simulator, extensively used in the oil industry. For both simulators, input values and simulation time, were virtually the same. The results showed that the simulator used in this work showed satisfactory performance, since no significant differences from those obtained with the commercial simulator. (author)

  8. Bee waxes: a model of characterization for using as base simulator tissue in teletherapy with photons; Ceras de abelha: um modelo de caracterizacao para sua utilizacao como tecido simulador base em teleterapia com fotons

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Rogerio Matias Vidal da; Souza, Divanizia do Nascimento

    2011-10-26

    This paper presents a model of characterization and selection of bee waxes which makes possible to certify the usage viability of that base simulator tissue in the manufacture of appropriated objects for external radiotherapy with mega volt photon beams. The work was divide into three stages, where was evaluated physical and chemical properties besides the aspects related to the capacity of beam attenuation. All the process was carefully accompanied related to the wax origin such as the bee specimen and the flora surrounding the beehives. The chemical composition of the waxes is similar to others simulators usually used in radiotherapy. The behavior of mass attenuation coefficient in the radiotherapeutic energy range is comparable to other simulators, and consequently to the soft tissue. The proposed model is efficient and allows the affirmative that the usage of determined bee wax as base simulator tissue is convenient

  9. The use of compressed natural gas as a strategy of development of natural gas industry; Utilizacao do GNC (Gas Natural Comprimido) como estrategia de desenvolvimento da industria do gas natural

    Energy Technology Data Exchange (ETDEWEB)

    Bock, Jucemara [Companhia de Gas do Estado do Rio Grande do Sul (Sulgas), Porto Alegre, RS (Brazil). Coordenacao de Segmento Veicular; Rickmann, Cristiano [Companhia de Gas do Estado do Rio Grande do Sul (Sulgas), Porto Alegre, RS (Brazil). Gerencia de Novos Negocios; Maestri, Juares [Companhia de Gas do Estado do Rio Grande do Sul (Sulgas), Porto Alegre, RS (Brazil). Gerencia de Mercado de Grandes Consumidores

    2008-07-01

    This work emphasizes the Compressed Natural Gas (CNG) as modal of transport, used by the Company of Gas of the State of Rio Grande do Sul - Sulgas, through experience in pioneering project in Brazil: the introduction of the technology of Compressed Natural Gas (CNG) to assist areas where there is not the infrastructure of pipeline for the transport. The article offers a display of the project of expansion of the Natural gas in Rio Grande do Sul, through the supply of CNG to the company Tramontina in Carlos Barbosa's city in the year of 2002. The last aspect focused by this article demonstrates as the use of this transport technology impelled the development of the transport market in the State and it has been used as an important strategy for the development of the market of Natural Gas Vehicle (NGV) in the state. (author)

  10. Utilization of ALANPOL dosemeter composed by alanine and polyethylene for determination of doses in industrial effluents; Utilizacao do dosimetro ALANPOL composto por alanina e polietileno para determinacao de doses em efluentes industriais

    Energy Technology Data Exchange (ETDEWEB)

    Rela, Carolina S.; Sampa, Maria Helena de O.; Napolitano, Celia M. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)]. E-mail: csrela@ipen.br; Pontuschka, Walter M. [Sao Paulo Univ., SP (Brazil). Inst. de Fisica

    2005-07-01

    A study of traceability and accuracy was performed with the dosimetry system ALANPOL developed by IVHTJ/ Poland that uses alanine as a dosimeter and EPR as the read out system. The dosimeter ALANPOL is a polymer compound that aggregates alanine. The dosimeter has the outside diameter 3 mm, and the length of 25,4 mm (1 inch). In order to use this dosimeter for monitoring the existing real time calorimetry dosimeter system set up in a electron beam waste treatment plant. Electron beam and gamma irradiation experiments with ALANPOL was carried out under demineralized water and industrial effluent. The result show that in the dose range of 1-40 kGy the ALANPOL dosimeter system is suitable underwater monitoring for absorbed dose and can be applied for the evaluation of the on line calorimetry dosimeter system. (author)

  11. Uncertainties associated to the using of alanine/EPR for the dose interval in the radiotherapy; Incertezas associadas na utilizacao da alanina/RPE para o intervalo de dose da radioterapia

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues Junior, O.; Campos, L. L. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2004-07-01

    The High Doses Laboratory of IPEN is developing a dosimetric system for high doses based on Electron Paramagnetic Resonance (EPR) of free radical radiation induced on alanine. The objective of this work is to present the efforts towards to improve the measure accuracy for doses in the range between 1-10 Gy. This system could be used as reference by radiotherapy services, as much in the quality control of the equipment, as for routine accompaniment of more complex handling where the total doses can reach some grays. The main problem for routine implantation is the calibration and the traceability of the system and many errors sources affects the accuracy of the measurements. In this work are discussed same aspects related on the uncertainty evaluation associated with high dose measurement using alanine and EPR. (author)

  12. Polymer matrices obtained by ionizing radiation for using in controlled drug delivery systems; Matrizes polimericas obtidas mediante radiacao ionizante para sua utilizacao como sistemas de liberacao controlada de farmacos

    Energy Technology Data Exchange (ETDEWEB)

    Martellini, Flavia

    1998-07-01

    Two kinds of controlled drug delivery system were obtained by gamma radiation induced polymerization. One of the system was obtained from an acrylic derivative of acetaminophen (40-hydroxyacetanilide), by copolymerization of 4-(acryloyloxy) acetanilide and N,N-dimethylacrylamide (DMAA) in dimethylformamide solution with 0,16 kGy/h dose rate and 54 Gy dose. The values of reactivity rate, r-D{sub MAA} = 0,31 {+-} 0,02 e r{sub AOA} -0,07 {+-} 0,12, were determined by Fineman-Ross method. The acetaminophen hydrolysis was carried out in alkaline and enzymatic (trypsin) media. Another kind of drug delivery system studied was solvent controlled type, being the drug immobilized in the hydrogel,. The hydrogels prepared by radiation polymerization of acryloyl-L-propine methylester (A-Pro-OMe) with 10 Gy dose, showed thermosensible property, swelling or shrinking in water with decreased or increased temperatures. The hydrogels were obtained with different crosslink density, trimethylolpropane trimethacrylate, and the monomers N, N-dimethyl acrylamide (DMAA) and 2-cyanoethyl acrylate to study the influence of the composition in the drug delivery rate. It was verified that the porous size besides being a characteristic of the matrix composition, it was also temperature dependent (thermosensible). The analgesic drug acetaminophen was immobilized by entrapment and by physical adsorption into the hydrogels matrices for 'in vitro' study. The insulin was immobilized by adsorption for 'in vivo' study. (author)

  13. The financial reward for the utilization of hydric resources, the Itaipu royalties and the new water Brazilian policy; A compensacao financeira pela utilizacao de recursos hidricos, os 'royalties' de Itaipu e a nova politica nacional de aguas

    Energy Technology Data Exchange (ETDEWEB)

    Vieira Filho, Xisto; Sales, Paulo Roberto de Holanda [Ministerio das Minas e Energia, Brasilia, DF (Brazil); Ventura Filho, Altino; Barbosa, Claudio Simoes [Itaipu Binacional, Foz do Iguacu, PR (Brazil); Spagnol, Marcos [ELETROBRAS, Rio de Janeiro, RJ (brazil)

    2000-07-01

    This paper presents the chronology of the legislation referring the financial compensation and the royalties paid by the Itaipu Bi nacional, from the origin to the important moment defined by the law introducing the new Water National Policy. Besides the aspects related to the legislation and the new Water National Policy, the ELETROBRAS participation in the process dynamic of the financial compensation is reported.

  14. The competition among the utilization of photovoltaic panels and other energy sources in water pumping systems; A competitividade entre a utilizacao de paineis fotovoltaicos e outras formas de energia em sistemas de bombeamento d`agua

    Energy Technology Data Exchange (ETDEWEB)

    Alvim Filho, Aymore de Castro; Silva, Selenio Rocha; Oliveira Costa Lira, Renato de [Minas Gerais Univ., Belo Horizonte, MG (Brazil). Dept. de Engenharia Eletrica; Martinez, Carlos Barreira [Minas Gerais Univ., Belo Horizonte, MG (Brazil). Dept. de Engenharia Hidraulica e Recursos Hidricos

    1997-12-31

    In this paper, photovoltaic alternative use in water supply systems was analyzed and compared with other energy solutions in order to diminish water cost. A case study is presented to stress the impact of this technology and your competitivity level. (author) 9 refs., 7 figs., 4 tabs.

  15. Modelling utilization of the decision of the motor utilization level in small scale hydroelectric power plants; Utilizacao de modelagem para escolha do indice de motorizacao de pequenas centrais hidreletricas

    Energy Technology Data Exchange (ETDEWEB)

    Saliba, Aloysio Portugal M.; Santos, Robson Siqueira Filadelfo dos [Minas Gerais Univ., Belo Horizonte, MG (Brazil). Dept. de Engenharia Nuclear; Pinotto, Marcos; Martinez, Carlos Barreira [Minas Gerais Univ., Belo Horizonte, MG (Brazil). Dept. de Engenharia Hidraulica e Recursos Hidricos

    1997-12-31

    The actual picture of the national electric generation demonstrate that there is a demand for small Hydroelectric Plants (SHP`s). The model described here allows the evaluation of different basic arrangements in function of hydrologic, hydraulic, economic and electric parameters. The very useful feature of this methodology is that it has been designed specifically for SHP`s allowing rapid convergence. A study case is presented to illustrate a practical use of the described model. (author) 9 refs., 5 figs., 2 tabs.

  16. Development of DP (Dynamic Positioning) to pull-in sub sea pipelines; Utilizacao de barcos de manuseio de ancoras operando com DP (Dynamic Positioning) para arraste de dutos submarinos

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Manoel H.S. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil); Galgoul, Elton C. [Suporte Engenharia, Luziania, GO (Brazil)

    2004-07-01

    Sub sea pipeline construction at oil and gas fields, with high concentration of on-bottom facilities, becomes more difficult when mooring operations and pipeline approach to a congested platform have to be performed. One method that has often been applied in Brazil is the so-called 'DP (Dynamic Positioning) pull-in', where PETROBRAS owned pipelay Barge, BGL-1, is moored away from the congested area, while a DP anchor handler pulls the rigid pipeline from BGL-1 to a target near the platform. The method was conceived to avoid mooring operations near the congested platforms as well as to minimize risks due to the pipeline initiation process. Inside the congested area the initiation with aid of a 'dead-man' anchor on the sea bottom, which would be a more conventional solution, becomes impossible in most cases. This paper will discuss the engineering work required to perform the 'DP pull-in' as well as show the operational steps, from the start-up to the final abandonment of the pipeline initiation head inside the target area. (author)

  17. Using of residential load curves obtained for determination of the load diversity, and loading of distribution transformers; Utilizacao de curvas de carga de consumidores industriais medidas para determinacao de diversidade de carga, e carregamento de transformadores de distribuicao

    Energy Technology Data Exchange (ETDEWEB)

    Ferrari, Eduardo Luiz; Jardini, Jose Antonio

    1996-07-01

    This work presents some applications of the residential loads, obtained from measurements conducted by the electric power utilities in the state of Sao Paulo , Brazil. During the first application, curve of coincidence of load peaks occurrence, as function of the number of consumers simultaneously connected to a specific residential distribution transformer. This curve provides a information on the number of consumers presenting coincident load peaks coincident relative to the total numbers of consumers connected to the distribution transformer. Those curves allow to obtain the diversity curves. The second application focused the calculation of the distribution transformer life reduction.

  18. Comparative analysis of the use of biomass with conventional generation technologies by applying eco-efficiency; Analise comparativa da utilizacao da biomassa com tecnologias convencionais de geracao aplicando eficiencia ecologica

    Energy Technology Data Exchange (ETDEWEB)

    Lora, Electo Eduardo Silva [Universidade Federal de Itajuba (UNIFEI), MG (Brazil)], e-mail: electo@unifei.eu.br; Salomon, Karina Ribeiro [Universidade Federal de Itajuba (UNIFEI), MG (Brazil). Nucleo de Estudos em Sistemas Termicos], e-mail: karinas@unifei.edu.br

    2004-07-01

    The world's concern regarding the reduction atmospheric emissions, due to the global warming, it is a subject that is being quite discussed. A parameter that evaluates the environmental impact considering the emissions of CO{sub 2}, SO{sub x}, NO{sub x} and PM in an integral way and comparing to the international air quality standards that are in force is called ecological efficiency ({epsilon}). This paper intends to compare environmental impacts of the atmospheric pollution due to technologies that use the biomass as fuel with conventional and advanced technologies of electricity generation. It is also evaluated the advantages of the use of the cogeneration starting from the biomass. The most important results that were obtained are comparative graphs confirming that the use of the biomass as energy source is a good option from the ecological point of view, when pollution control methods are used. (author)

  19. Potential use of solar water heating systems in residential areas of the city of Piracicaba; Potencial da utilizacao de coletores solares no aquecimento de agua residencial na cidade de Piracicaba

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Rafel Deleo e; Vieira Junior, Jose Carlos de Melo [Universidade de Sao Paulo (EESC/USP), Sao Carlos, SP (Brazil). Escola de Engenharia], Emails: rafael.deleo.oliveira@usp.br, jcarlos@sc.usp.br

    2010-10-15

    Solar collector is a device that uses solar energy for heating fluid (both liquid and gaseous) which can then be used to generate energy. This study is based on the method of calculating the global solar radiation incident on the inclined plane using data from the city of Piracicaba, state of Sao Paulo. As a result of the study it can be seen that for the city of Piracicaba the collecting area of 4.62 M{sup 2} presents solar fraction varying between 87.27% and 97.79% for heating 300 liters of water and 200 liters of water daily, respectively. Based on the results one can conclude that the savings would be about 47.74 GWh, if a collection area of 360 thousand m{sup 2} (0.36 km{sup 2}) were fully exploited, which represents savings of approximately R$ 15.86 million per year for the municipality. (author)

  20. Use of the extraction residue of emeralds in a formulation mass of ceramic tiles; Utilizacao do residuo da extracao de esmeraldas em uma formulacao de massa de revestimento ceramico

    Energy Technology Data Exchange (ETDEWEB)

    Cavalcante, R. F., E-mail: ronaldofcavalcante@gmail.com [Programa de Pos-Graduacao em Engenharia Mecanica - PPgEM - UFRN, Universidade Federal do Rio Grande do Norte, Lagoa Nova, RN (Brazil); Nascimento, R.M.; Paskocimas, C.A., E-mail: rmaribondo@ufrnet.br, E-mail: paskocimas_ca@hotmail.com [Departamento de Engenharia Materiais - DEMAT - Universidade Federal do Rio Grande do Norte, Lagoa Nova, RN (Brazil); Dutra, R.P.S., E-mail: ricardodutra@ct.ufpb.br [Departamento de Engenharia Materiais - DEMAT - UFPB - Universidade Federal de Pernambuco, Recife (Brazil)

    2012-04-15

    Companies involved in mining and beneficiation of emerald represent an important area of industrial development in Brazil, with a significant contribution to world production of this ore. As a result, large volumes of waste generated and emerald are constantly abandoned in the environment, contributing negatively to their preservation. On the other hand the interest in the use of mining waste as an additive in production of ceramic materials has grown among researchers in recent years. The ceramic industry is constantly seeking to expand the market for the sector and trying to improve product quality and increase the variety of applications. The technology of obtaining ceramic coating that uses waste from mining is still a largely unexplored market. Thus, the purpose of this study was to characterize the waste generated from mining emerald as well as to evaluate its potential use as raw material for production melting of ceramic tiles. Ceramic mixtures were prepared from raw materials characterized by X-ray fluorescence and X-ray diffraction. Five compositions were prepared using the waste codes of emeralds from 0%, 10%, 20%, 30% and 40%. Samples were prepared by pressing, sintered at 1000, 1100 and 1200 deg C and characterized to establish their mineralogical composition, water absorption, linear shrinkage and modulus of rupture. The results showed that the residue of emeralds studied can be embedded in the mass of ceramic tiles up to 20% in replacement of feldspar without compromising the end product properties. (author)

  1. Use of radiological evaluation system from the Instituto de Radioprotecao e Dosimetria in the analysis of recent radiation accidents; Utilizacao do sistema de avaliacao radiologica do Instituto de Radioprotecao e Dosimetria na analise de acidentes radiologicos recentes

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Rodolfo Julio da

    2013-07-01

    The response to an emergency situation involving ionizing radiation requires the joint participation of professionals from various kind of knowledge, belonging to public and private organizations (in the local, state and federal levels). The theme radiation tends to be an additional challenging factor - considering that it's, usually, remembered for its macabre and ominous aspect, in spite of the benefits provided by it - which makes the implementation of actions to protect the public, emergency professionals, the environment and property, very difficult. To this, we can add the complicating factor that, in most cases, the technician (holder of basic or advanced on the subject) is far !Tom the place where this action unfolds. The accident/incident takes the form of a radioactive source (sometimes orphaned, one that gone astray or even stolen) that is found by a person unaware of the risks to which they are being exposed or, let not forget about it, the non-observance of safety standards in industries and workplaces, by their own operators. Thus, before integrating emergency response plans with conventional plans specific to the prompt response to radiological emergencies, it is necessary that some measures had been anticipated and that some actions had, already, been planned - with the intention of mitigate health, psychological and economical damage, in ali of kind. To do this, since in the course of the second decade of the second millennium, and since you own a portable personal computer (Note or Netbook), or even with a mobile device (cellular) with a bit more resources, both of them previously updated, a responder (or even a qualified technician that is next to that fact) may already guide, at least, about a safety distances !Tom the source. Since he had knowledge about some characteristics of the source (its individual data), he can plan ahead about the possible serious situation that unfolds itself and emergency responders will find, when it get to the site. With the situation assessments done, the formal emergency team triggered will can prepare itself (with personnel and technical-materials facilities) to resolve the incident in the shortest time and with the least possible risks. (author)

  2. Use of biogas generated from swine manure as preliminary agent in the feasibility construction of natural gas networks; Utilizacao do biogas gerado a partir de dejetos suinos como agente preliminar na viabilizacao da construcao de redes de gas natural

    Energy Technology Data Exchange (ETDEWEB)

    Machado, Antonio Rogerio; Ferraz, Andre; Rocha, Ivan; Azevedo, Jorge; Oshiro, Hugo K.; Konishi, Ricardo; Piazza, Walter; Lehmkuhl, Willian [Companhia de Gas de Santa Catarina (SCGAS), Florianopolis, SC (Brazil)

    2011-12-21

    Santa Catarina state has over 800 km of natural gas distributed along the coast line, however, has an area of 95.700 km{sup 2}. Due to mountainous relief, constructing pipeline that will supply natural gas to remote areas will prove difficult. Supplying gas to remote areas through biogas from pig manure is a feasible alternative to building a gas pipeline to these regions. Using data from the IBGE and by aid of computer programs it was found that Santa Catarina has a potential to generate biogas from 900.000 m{sup 3}/day which are located predominantly in the western region of state. Thus, through the provision of biogas in this region a market that uses natural gas as an energy source can stimulate. As result the pay-back time and the feasibility risk of a network gas project can be reduced. It was found that only in the west there is an energy potential to be shifted to natural gas equivalent of 389.583 m{sup 3}/day and as expected output is estimated to reach 16.728 m{sup 3}/day. This helps anticipate the building of a natural gas network that links the coast with outskirts of the state, while the environmental impact of swine as methane emissions and waste are reduced. (author)

  3. Maintenance of extra high voltage circuit breakers and switches by own and contracted teams; Manutencao de disjuntores e seccionadores de extra alta tensao com utilizacao de equipes proprias e contratadas

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Jose Flavio; Santiago Junior, Martin G.; Siecola, Paulo Roberto C.; Betio, Ivan [Companhia Energetica de Sao Paulo (CESP), SP (Brazil)

    1995-12-31

    This work presents CESP`s experience in the maintenance of electric power substation equipment by a team contracted to do the work out of the risk area in conjunction to the company`s own teams which perform the activities in the electric power substation areas. the several contract types are discussed as well as the adopted procedures in order to achieve quality improvement and costs reduction

  4. Utilization of biodiesel from castor oil in gas micro turbines: thermal performance testing and emissions; Utilizacao do biodiesel de mamona em microturbinas a gas: testes de desempenho termico e emissoes

    Energy Technology Data Exchange (ETDEWEB)

    Nascimento, Marco Antonio R.; Lora, Electo Silva; Venturini, Osvaldo Jose; Maldonado, Manuel Rendon; Andrade, Rubenildo Viera; Correa Junior, Paulo Sergio Pedroso [Universidade Federal de Itajuba (UNIFEI), MG (Brazil)], Emails: marcoantonio@unifei.edu.br, electo@unifei.edu.br, osvaldo@unifei.edu.br, nrendon@unifei.edu.br, ruben@unifei.edu.br, paulocorrea@unifei.edu.br; Leite, Marco Antonio Haikal [Centro de Pesquisas Leopoldo Americo Miguez de Mello (CENPES/PETROBRAS), Rio de Janeiro, RJ (Brazil)], Email: mahaikal@petrobras.com.br

    2006-07-01

    The operation of power equipment such as a gas micro-turbine using renewable fuels is an interesting alternative when sustainability is concerned, mainly in isolated areas with abundant availability of fuels that come from biomass. Within this scenario, this article presents the results of tests regarding thermal performance and emissions of a gas micro-turbine operating with Diesel and bio diesel mixtures, showing the influence of the use of this fuel on the thermal behavior of the machine and on the emissions of gases such as CO, NO{sub x} and SO{sub 2}. The results of the experimental tests are shown in graphs, from where it can be observed that the bio diesel and its mixtures do not change the thermal behavior of the micro-turbine significantly, and at the same time, they may considerably reduce the emission of gaseous pollutants. (author)

  5. Utilization of rice husk ash as filler for polyamide 6 and ionizing radiation effect studies on this composite;Utilizacao da cinza da casca de arroz como carga em matriz de poliamida 6 submetida a radiacao ionizante

    Energy Technology Data Exchange (ETDEWEB)

    Ferro, Waldir Pedro

    2009-07-01

    In order to improve the dimensional stability, as well as, electrical, mechanical and thermal properties of polymers, new filler to this purpose has been developed. The mos applied filler to propitiate the features previously mentioned are the glass and carbon fibers, the mineral filler as the calcium carbonate, the talc and the micro glass sphere. The main aim of this work was to study the rice husk ash as filler for polyamide 6 and ionizing radiation effect studies on this composite, irradiated by electron beam at different doses, since it is constituted of at least 90% of silicon dioxide, and compared with the talc which is the most applied mineral filler. This comparison was made from a compound made through the refined rice husk ash and the polyamide 6 (PA 6), which is one of the main engineering plastic with applications in several productive areas. The samples were injected and irradiated in a electron accelerator. Afterwards, their mechanical and thermal properties were measured. It was also inject automotive parts to verify the processing of the PA 6 with CCA. The results showed that the use of the rice husk ash as filler for polyamide 6 composite is technically and economically viable. The irradiation of the studied composite (PA 6 with 30% of rice husk ash) did not provide any improvement for the mechanical and thermal properties previously appraised. (author)

  6. Study of potentiality of raw material of Crato/CE for use in structural ceramics - part I - technological characterization; Estudo da potencialidade da materia-prima do Crato/CE para utilizacao em ceramica estrutural - parte I - caracterizacao tecnologica

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, J.C.S.; Santos, G.M.; Saldanha, K.M.; Sales Junior, J.C.C.; Nascimento, R.M.; Paskocimas, C.A., E-mail: jean@ufrnet.br [Universidade Federal do Rio Grande do Norte (UFRN), Natal RN (Brazil)

    2011-07-01

    The limitation of information on chemical, mineralogical and thermal characteristics of raw material used in process of manufacture of ceramic products in the region of Cariri, specifically the city of Crato, state of Ceara, motivated the development of this work, since this region ceramics exist that in a general context they appear as important productive chains in the state. The characteristics were evaluated by tests of limit of liquidity, limit of plasticity, index of plasticity, but also by chemical analysis for fluorescence of rays X, analysis of phases for diffraction of rays X, and thermal analysis (thermogratimetric analysis). The results showed that the raw material has excellent size distribution and characteristics acceptable to the processing of structural components of dark color the red, requiring a mixture of clay with coarse less plastic which granulation, that functions as reducer of plasticity. (author)

  7. Project, construction and characterization of ionization chambers for use as standard systems in X and gamma radiation beams; Projeto, construcao e caracterizacao de camaras de ionizacao para utilizacao como sistemas padroes em feixes de radiacao X e gama

    Energy Technology Data Exchange (ETDEWEB)

    Perini, Ana Paula

    2013-07-01

    Ionization chambers present some advantages in relation to other dosimeters: easiness of handling, low energy dependence and high precision. The advantages associated to ionization chambers and the large number of diagnostic radiology exams and therapeutic treatments motivated the development of this PhD program. In this project ionization chambers were developed and characterized to be applied in diagnostic radiology and therapy beam dosimetry, with high precision and performance, in compliance with international recommendations. They were assembled in a simple way, utilizing low-cost national materials, so they can be reproduced and applied at calibration laboratories. The project of these ionization chambers presents some differences in relation to commercial ionization chambers, as the materials utilized and geometrical arrangements. Besides the development of the ionization chambers to be utilized in standard X-ray beam dosimetry as work standard systems, two graphite parallel-plate ionization chambers were developed and characterized to be applied as reference standard systems for determining the air kerma rates of gamma radiation sources. Comparing the air kerma rates determined with the reference standard of the Calibration Laboratory of IPEN, a Farmer ionization chamber, with the values of the air kerma rates obtained with the graphite ionization chambers, the maximum differences obtained were only 1.7% and 1.2% for the G1 and G2 graphite ionization chambers, respectively. Moreover, these ionization chambers presented correction factors close to 1.000, which is ideal for an ionization chamber be characterized as a reference standard system. (author)

  8. The problem of the use the hybrid and photovoltaic systems in insular zones with climatic siversity in Madeira; A problematica da utilizacao de sistemas fotovoltaicos e hibridos em zonas insulares de diversidade climatica-ILHA da Madeira

    Energy Technology Data Exchange (ETDEWEB)

    Magro, J. C. E.

    2004-07-01

    Project PAUER contemplates the evaluation and utilization of renewable energy in insular zones with climatic diversity, situated on the Archipelago of Madeira. The project has three main areas of intervention: prospecting and evaluating energetic resources; creation of data bases of climatic data for application in energetic studies and other areas; the installation of twenty autonomous photovoltaic or hybrid systems in isolated localities. This communication presents some data from meteorological observations made up until the present date, following appropriate statistical analysis. Characteristics of some installed photovoltaic and hybrid systems as well as some of the principal problems encountered in the field are also given. (Author)

  9. Evaluation of natural radioactivity in some granitic rocks in the state of Parana, Brazil and its use in civil construction; Avaliacao da radioatividade natural em algumas rochas graniticas do estado do Parana e sua utilizacao na construcao civil

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Ademar de Oliveira

    2013-07-01

    Primordial, or terrestrial natural radionuclides, are found in different amounts in the environment. In dwellings, an important dose increment is due to building materials, which contribute for both the external gamma dose from the radionuclides of the {sup 238}U, {sup 235}U and {sup 232}Th series and the natural {sup 40}K and the internal dose, due mainly to {sup 222}Rn inhalation. Once granitic rocks are widely used both as construction materials or structural flooring, those rocks can become an important dose source, depending on the content of concentrations of radioactivity, and the construction application. In this work, a database for granitic rocks of the crystalline shield of Parana (mainly in the Metropolitan Region of Curitiba, RMC), used in civil construction, was generated, evaluating in terms of radiological protection the external and internal dose increments, caused by the use of these materials. Also, possible correlations between the {sup 226}Ra activity concentration, the {sup 222}Rn exhalation rate, density, porosity and chemical composition (oxide content) in these samples had been studied. The external dose was assessed by gamma-ray spectrometry with High-Purity Germanium detectors, where the activity concentration of the radionuclides {sup 232}Th, {sup 226}Ra and {sup 40}K are the parameters used in dosimetric models (Dosimetric Indexes), which established limits in accordance with the form, amount and application of material of construction. For the calculation of the annual effective external dose it was assumed a room model with dimensions of 4 m x 5 m x 2:8 m and all walls internally covered with 2 cm thickness of granite and an annual exposure time of 7000 h as suggested by the European Commission of Radiological Protection for internal superficial coating materials. The internal exposure was assessed from the radon concentration in the air of the room model, simulated from the superficial exhalation rate of {sup 222}Rn. The exhalation rate was determined by the passive detection technique with the Solid State Nuclear Track Detectors (CR-39) and the sealed can technique, assuming a ventilation rate of 0.5 h{sup -1} and an annual exposure time of 7000 h. The results for this studies show that the annual effective dose ranged from (62 {+-} 3) {mu}Sv.y{sup 1} to (138 {+-} 1) {mu}Sv.y{sup -1} and the internal annual effective dose ranged from (0,39 {+-} 0,04) {mu}Sv.y{sup -1} to (70 {+-} 4) {mu}Sv.y{sup -1}. These values are below the maximum limit of 1 mSv.y{sup -1} suggested by the European Commission of Radiological Protection, meaning that the granitic rocks evaluated can be used without radiological implications since the considered scenario is obeyed. The values obtained for the contribution due to the internal dose ranged from 1 % to 78 % of the values obtained for the respective external dose showing the radon contribution varies strongly with the rock type. The results of the correlations between {sup 222}Rn superficial exhalation rate, {sup 226}Ra activity concentration, density, porosity and major oxides of the samples, showed that, in terms of influence in the emanation fraction of radon, the most important parameter is the density, due to low porosity and similarity in terms of chemical composition amid the studied samples. (author)

  10. Using of gas for water heating at buildings - study on technical and economical viability; Utilizacao de gas para aquecimento de agua em instalacoes prediais - estudo de viabilidade tecnica e economica

    Energy Technology Data Exchange (ETDEWEB)

    Fossa, Alberto Jose [MDJ Assessoria e Engenharia Consultiva, Santo Amaro, SP (Brazil)]. E-mail: afossa@mdj.com.br; Chaguri, Jose Jorge [Caltherm Sistemas de Aquecimento, Sao Paulo, SP (Brazil)]. E-mail: jchaguri@caltherm.com.br; Santos, Edmilson Moutinho dos [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Eletrotecnica e Energia]. E-mail: edsantos@iee.usp.br

    2006-07-01

    The recent discovery of significant Brazilian's natural gas reserves has been opened a discussion concerning public procedures in order to incentive development of gas industry thru delivery of this energetic to the end consumer. Concerning this figure, a significant quantity of uses has been questioned related economical viability. This paper comes to analyze the possibility to change electrical energy for natural gas on heating water systems used on residential installations. Concerns about economical impact of alternative adopted on locals where public regulations are been established to incentive natural gas end uses. (author)

  11. A new method for intraoperative localization of epilepsy focus by means of a gamma probe; Um novo metodo para a localizacao intraoperatoria de foco de epilepsia mediante utilizacao de gamaprobe

    Energy Technology Data Exchange (ETDEWEB)

    Carneiro Filho, Omar, E-mail: dromarcarneiro@gmail.com [Centro Brasileiro de Medicina Nuclear e Imagem Molecular (CEBRAMEN), Goiania, GO (Brazil); Instituto de Medicina Nuclear, Goiania, GO (Brazil); Vilela Filho, Osvaldo [Universidade Federal de Goias (UFG), Goiania, GO (Brazil). Hospital das Clinicas. Servico de Neurocirurgia; Ragazzo, Paulo Cesar [Instituto de Neurologia de Goiania, GO (Brazil). Servico de Eplepsia e Neurofisiologia; Fonseca, Lea Mirian Barbosa da [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Dept. de Radiologia

    2014-01-15

    Objective: to evaluate the utility of a new multimodal image-guided intervention technique to detect epileptogenic areas with a gamma probe as compared with intraoperative electrocorticography. Materials and methods: two symptomatic patients with refractory epilepsy underwent magnetic resonance imaging, videoelectroencephalography, brain SPECT scan, neuropsychological evaluation and were submitted to gamma probe-assisted surgery. Results: in patient 1, maximum radioactive count was initially observed on the temporal gyrus at about 3.5 cm posteriorly to the tip of the left temporal lobe. After corticotomy, the gamma probe indicated maximum count at the head of the hippocampus, in agreement with the findings of intraoperative electrocorticography. In patient 2, maximum count was observed in the occipital region at the transition between the temporal and parietal lobes (right hemisphere). During the surgery, the area of epileptogenic activity mapped at electrocorticography was also delimited, demarcated, and compared with the gamma probe findings. After lesionectomy, new radioactive counts were performed both in the patients and on the surgical specimens (ex-vivo). Conclusion: the comparison between intraoperative electrocorticography and gamma probe-assisted surgery showed similarity of both methods. The advantages of gamma probe include: noninvasiveness, low cost and capacity to demonstrate decrease in the radioactive activity at the site of excision after lesionectomy. (author)

  12. Obtenção e avaliação da estabilidade de carmim de cochonilha (Dactylopius coccus)

    OpenAIRE

    Ana Paula Martins

    1997-01-01

    Resumo: Neste trabalho foi obtido um corante natural, de coloração vermelha, a partir do inseto denominado cochonilha (Dactylopius coccus Costa). Para a obtenção do corante foram analisados vários fatores: pH, tempo e concentração de reagentes. Procurou-se através da variação dos fatores se obter um corante de coloração visualmente igual ao comercial e com alto teor de pigmento. O corante foi obtido sob as formas de pó e líquido. O teor médio de ácido carmínico obtido no carmim foi de 57,35%,...

  13. Determination of organic phosphorous in oil production waters by ICP-AES and ICP-MS after preconcentration on silica immobilized C{sub 18}; Determinacao de fosforo organico em aguas de producao petrolifera por ICP-AES e ICP-MS apos pre-concentracao em coluna de silica C{sub 18}

    Energy Technology Data Exchange (ETDEWEB)

    Rocha, Anderson Araujo; Miekeley, Norbert; Silveira, Carmem Lucia Porto da [Pontificia Univ. Catolica do Rio de Janeiro, RJ (Brazil). Dept. de Quimica; Bezerra, Maria Carmem Moreira [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas

    1998-10-01

    Results on the optimization analytical methods for the determination of phosphorous in phosphino-poly carboxylate (PPCA), used frequently as scale inhibitor during oil production, by ICP-AES and ICP-MS are presented. Due to the complex matrix of production waters (brines) and their high concentration in inorganic phosphorus, the separation of organic phosphorus prior to its determination in necessary. In this work, mini columns of silica immobilized C{sub 18} were used. Optimization of the separation step resulted in the following working conditions: (1) pre washing of the column with methanol (80% v/v); (2) use of a flow rate of 5 m L/min and 10 m L/min, respectively, for the preconditioning step and for percolation of the water sample; (3) final elution of organic phosphorus with 7 m L of buffer of H{sub 3} BO{sub 3}/Na OH (0.05 M, p H 9) with a flow rate of 1 m L/min. Sample detection limits (3{sigma}) for different combinations of nebulizers and spectrometric methods, based on 10 m L water aliquots, are: ICP-AES-Cross flow (47 mg/L) and Ultrasonic (18 {mu}g/L); ICP-M S-Cross flow (1.2 {mu}g/L) and Ultrasonic (0.5 {mu}g/L). Typical recoveries of organic phosphorous are between 90 and 95% and the repeatability of the whole procedure is better than 10%. The developed methodology was applied successfully to samples from the oil-well N A 46, platform PNA 2, Campos basin, Brazil. Assessment of the PPCA inhibitor was possible at lower concentrations than achieved by current analytical methods., resulting in benefits such as reduced cost of chemicals, postponed oil production and lower environmental impacts. (author)

  14. Pulse-form discrimination in organic scintillation crystals; Discrimination d'apres la forme de l'impulsion dans les cristaux organiques de scintillation; Diskriminatsiya formy impul'sov v organicheskikh stsintillyatsionnykh kristallakh; Discriminacion de la forma de los impulsos en los cristales de compuestos organicos para contadores de centelleo

    Energy Technology Data Exchange (ETDEWEB)

    De Vries, L J; Udo, F [Instituut voor Kernphysisch Onderzoek, Amsterdam (Netherlands)

    1962-04-15

    Presented is a proton-electron discrimination circuit, based on the pulse-form differences between proton and electron-induced scintillation light pulses in stilbene. The circuit is stable and resolves proton from electron pulses down to a proton energy of 300 keV. The discrimination circuit, which contains only linear elements, is sensitive to pile-up-induced errors for only 0.1 {mu}s after the arrival of a pulse. The described circuit has now been used in a 1-30 MeV neutron spectrometer based on proton-recoil between two silbene crystals. A resolution of 10% at 14 MeV neutron energy was obtained with a detection efficiency of 1.3 x 10{sup -4}. A neutron monitor, also based on linear pulse-form discrimination, could be used to measure a neutron dose of 10% of the maximum permissible dose in the presence of a gamma flux of 4 times the maximum permissible dose. (author) [French] Le memoire decrit un circuit de discrimination proton/electron dont le principe repose sur les differences de forme entre les impulsions lumineuses dans du stilbene, produites par des protons, d'une part, et des electrons, d'autre part. Le circuit est stable et permet de separer les impulsions protoniques des impulsions electroniques, a partir d'une energie protonique de 300 keV. Ce circuit, qui ne contient que des elements lineaires, n'est sujet a des erreurs dues a l'accumulation que pendant 0,1 {mu}s apres l'arrivee de l'impulsion. Il a ete utilise dans un spectrometre neutronique de 1-30 MeV, fonde sur le recul des protons entre deux cristaux de stilbene. On a obtenu une resolution de 10% pour une energie neutronique de 14 MeV, avec une efficacite de detection de 1,3x10{sup -4}. Un detecteur de neutrons procedant egalement par discrimination d'apres la forme des impulsions, pourrait servir a mesurer une dose de neutrons representant 10% de la dose maximum admissible, en presence d'un flux gamma correspondant a une dose quatre fois superieure a la dose maximum admissible. (author) [Spanish] Los autores presentan un circuito de discriminacion proton-electron basado en las diferencias de forma entre los impulsos de centelleo luminosos producidos por los protones y por los electrones, respectivamente, en los cristales de estilbeno. El circuito es estable y es capaz de distinguir los impulsos de protones de los electrones hasta con energias de protones de solamente 300 keV. El circuito discriminador, compuesto unicamente de elementos lineales, es sensible a errores inducidos por apilonamiento durante 0,1 {mu}s solamente, a partir de la llegada de un impulso. El circuito descrito se aplico en un espectrometro para neutrones de 1 a 30 MeV, basado en el retroceso de protones entre dos cristales de estilbeno. Se alcanzo un poder de resolucion de 10 por ciento, para una energia neutronica de 14 MeV, con un rendimiento de deteccion de 1,3 {center_dot} 10{sup -4}. Se podria usar un monitor neutronico basado tambien en un sistema de discriminacion lineal de la forma de los impulsos para medir una dosis neutronica igual al 10% de la dosis maxima admisible, en presencia de un flujo {gamma} cuatro veces mayor que la dosis maxima admisible. (author) [Russian] Opisyvaetsya kontur diskriminatsii protonov-ehlektronov, osnovannyj na raznitse formy stsintillyatsionnykh svetovykh impul'sov, navedennykh v stil'bene sootvetstvenno protonami i ehlektronami. EHtot kontur ustojchiv i otlichaet impul'sy protonov ot impul'sov ehlektronov dazhe pri padenii ehnergii protonov do 300 kehv. Diskriminiruyushchij kontur, sostoyashchij isklyuchitel'no iz linejnykh ehlementov, chuvstvitelen k obrazuyushchimsya iz-za nakopleniya oshibkam tol'ko v techenie 0,1 mikro-sekundy posle postupleniya impul'sa. Opisyvaemyj kontur byl ispol'zovan v spektrometre dlya nejtronov s ehnergiyami 1-30 mehv, osnovannom na otdache protonov mezhdu dvumya kristallami stil'bena. Pri ehnergii nejtronov v 14 mehv bylo polucheno ikh razreshenie s tochnost'yu do 10%, pri ehffektivnosti detektirovaniya v 1,3 x 10{sup -4}. Dlya izmereniya dozy nejtronov, ne prevyshayushchej 10% maksimal'noj dopustimoj dozy i pri nalichii potoka gamma-luchej, prevyshayushchego v 4 raza maksimal'nuyu d o p u s t i m uyu dozu, byl ispol'zovan kontrol'no-izmeritel'nyj dozimetricheskij schetchik, takzhe osnovannyj na linejnoj diskriminatsii formy impul'sov. (author)

  15. Dynamic carbon content as an indicator of desertification processes in soils developed from volcanic parental material in the Region of Murcia; Contenido en carbono organico como indicador del proceso de desertificacion en suelos desarrollados en material parental volcanico en la Region de Murcia

    Energy Technology Data Exchange (ETDEWEB)

    Martinez-Martinez, S.; Faz Cano, A.; Acosta Aviles, J. A.

    2009-07-01

    Soil Organic Carbon (SOC is an essential components of the global carbon cycle, especially in soils developed from volcanic rocks, due to these soils does not have inorganic carbon. In arid and semiarid areas mineralization of organic carbon is very intense due to climatic conditions, causing soils depletion and therefore desertification. The objective of this study is to determine the content of OC, as a first step in the assessment of desertification. The objective of this study is to determine the content of OC, as a first step in the assessment of desertification processes affecting this area of the southeast of Spain. (Author) 7 refs.

  16. The influence of organic compound addition on the mobility and biological availability of the {sup 137} Cs and {sup 60} Co on tropical soils; A influencia da adicao de composto organico na mobilidade e biodisponibilidade do {sup 137} Cs e do {sup 60} Co em solos tropicais

    Energy Technology Data Exchange (ETDEWEB)

    Portilho, Antonio Passos

    2005-07-01

    The hole of manure in the mobility and bioavailability of {sup 137}Cs and {sup 60}Co in Brazilian soil was investigated. For this study an Oxisol was selected, for being the soil of larger distribution in the country, characterized by a low content in nutrients and organic substances; a Nitisol, was also selected as representative of soils with average fertility and an Organo sol, as representative of soils with high content of organic matter. These soils were transferred to an experimental area in the Instituto de Radioprotecao e Dosimetria, conditioned in plastic pots and spiked with {sup 137}Cs e {sup 60}Co. To follow the root uptake of {sup 137}Cs and {sup 60}Co we cultivated radish (Raphanus sativus, L.), in the pots receiving different doses of manure: a dose recommended for radish (2 kg/m{sup 2}); a half of the recommended dose; the double of the recommended dose and without manure addition. Only the Organo sol did not received manure. Moreover, it was investigated the potential mobility of {sup 137}Cs and {sup 60}Co associated to the unstable compounds under natural soil environment, such as the organic substance, oxides of iron etc, through the method of sequential chemical extraction. The main results show that soil to plant transfer factor (TF) for {sup 137}Cs decreases after the addition of 4 kg/m{sup 2} of manure in the Nitisol (from 0.44 to 0.06) and in the Oxisol (from 0,44 to 0,11). In relation to {sup 60}Co the TF reduced from 14,73 for 0,15 in Nitisol and from 11,25 for 0,15 to Oxisol. In the Organosols the TF values were low and comparable with values obtained in soil that received at least a dose of manure: 0,11 for {sup 137}Cs and 2,64 for {sup 60}Co. It was also observed, that the TF for {sup 137}Cs diminish with the increase of the nutrient contents (K, Ca and Mg) when manure is applied. It was verified, through the results of sequential extraction, that {sup 137}Cs was mainly associated to iron oxides in all types of studied soils. In the Nitisol, {sup 60}Co, was mainly weakly adsorbed to its compounds (52%) even about 18% was strongly associated to the organic matter and around 10% was associated to the manganese oxides. It was observed that 56% of the total {sup 60}Co added to the Organo sol was associated to the organic matter, while 71% of the total {sup 60}Co added to the Oxisol was associated to the manganese oxides. (author)

  17. Procedure Development to Determine Organic Compounds in the PM{sub 1}-2.5 and PM{sub 2}.5-10 Fractions of Atmospheric Aerosols; Desarrollo de la Metodologia para la Determinacion de los Compuestos Organicos en las Fracciones PM{sub 1}-2.5 y PM{sub 2}.5-10 del Aerosol Atmosferico

    Energy Technology Data Exchange (ETDEWEB)

    Pindado, O; Perez, R M

    2011-07-28

    An analytical procedure development to measure organic compounds such as aliphatic hydrocarbons, polycyclic aromatic compounds, n-alcohols and fatty acids in PM{sub 1}-2.5 and PM{sub 2}.5-10 of atmospheric aerosol is accomplished. The development encompasses an optimization of extraction step, derivatization step and chromatographic analysis. The method developed consists in a microwave extraction, followed by a stage of fractionation and analysis by GC/MS. (Author) 20 refs.

  18. Application of natural Ra isotopes and {sup 234}Th as tracers of organic carbon export in Bransfield Strait, Antarctica; Aplicacao dos isotopos naturais de Ra e do Th-234 como tracadores do carbono organico exportado para o Estreito de Bransfield, Antartica

    Energy Technology Data Exchange (ETDEWEB)

    Vieira, Lucia Helena

    2011-07-01

    The Southern Ocean is the largest of several high-nutrient, low-chlorophyll (HNLC) regions in the world's oceans. This region plays a major role in regulating the global net transfer of carbon dioxide between the ocean and the atmosphere, in part because the annual photosynthetic uptake of CO{sub 2} by phytoplankton and resulting export of particulate organic carbon (POC) to the deep ocean. The element thorium has multiple radioisotopes that have emerged collectively as a powerful set of tracers for particle associated processes in the oceans. Of all the Th isotopes, {sup 234}Th (half-life 24.1 d) has been the focus of increasing attention and application in the past years. The production of {sup 234}Th from {sup 238}U, coupled with the conservative behavior of {sup 238}U in seawater, makes the source of {sup 234}Th easy to characterize. Moreover, the half-life of {sup 234}Th is sufficiently short to make it sensitive to the short-term (e.g. seasonal) changes that occur in the upper water column of the open ocean or in sediments or water column in coastal areas. Because of its very particle reactive behavior, {sup 234}Th is removed from a parcel of water in only two ways, through decay and through particle flux. Therefore, a steady-state 1D activity balance can be used to calculate its flux. Natural Ra isotopes have been also widely used in marine studies to trace water masses and to quantify mixing processes. This work presents results of a collaborative research on organic carbon fluxes distribution in the Bransfield Strait in order to evaluate its influence in the CO{sub 2} drawdown. Macro-nutrients, micro-nutrients and chlorophyll-a distributions were used to examine the pathway sources. Natural radium isotopes were applied as tracers to study the movement of shelf water, while {sup 234}Th was used as a tracer of particle flux in the upper ocean, since POC export via sinking particles is the primary mechanism of carbon sequestration in the Southern Ocean. Sea water samples for total {sup 234}Th and natural Ra isotopes were collected from 9 to 14 December 2007 on the RV Ary Rongel (Brazilian Navy). Analyses of total {sup 234}Th activities were performed by gross beta counting using a gas-flow low background proportional counter. The long lived Ra isotopes were determined by low-background high efficiency gamma spectrometry. (author)

  19. Effects of the organic solvents addition about crude oil rheological behavior from 'Reconcavo Baiano' (Brazil); Efeito da adicao de solventes organicos sobre o comportamento reologico do petroleo cru oriundo do 'Reconcavo Baiano' (Brasil)

    Energy Technology Data Exchange (ETDEWEB)

    Cavalcanti, Luis A.P. [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Faculdade de Engenharia Quimica; Vieira, Jacyara M.A. [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Faculdade de Engenharia de Minas; Almeida, Yeda M.B.; Sarmento, Sandra M. [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil)

    2004-07-01

    The crude oil rheological properties are quite important in its transport and refining processes. They can affect the head losses and, thus, the pressure within a refining unit. These properties can be affected by the temperature and the chemical composition as well as by solvents added to the crude oil. The current work studied the rheological behaviour of both a crude oil from the Reconcavo Baiano (Brazil) and mixture of this crude oil with organic solvents (toluene and xylene). The solvent type and concentration effects on the rheological parameters, were studied. The Brookfield viscometer, model LDVD-II, was used. The results brought to light that the crude oil and the crude oil-solvent mixtures behaved, discretely, as thixotropic fluids. The model of Herschel-Bulkley for viscoplastic fluid was the best in fitting the experimental data for both crude oil and crude oil - solvent mixture. The toluene was found to be more efficient in reducing both the apparent viscosity and apparent yield stress of the crude oil than the xylene for a given concentration. The solvent concentration affects indirectly the rheological properties of the crude oil. (author)

  20. A radiochemical procedure for a low-level measurement of ''241Am in environmental samples using a supported functional organo phosphorus extractant; Metodo analitico para la determinacion de ''241Am en muestras biologicas y sedimentos marinos mediante uso de una columna con extractante organico

    Energy Technology Data Exchange (ETDEWEB)

    Gasco, C.; Anton, M. P.; Alvarez, A.; Navarro, N.; Salvador, S.

    1994-07-01

    The transuranides analysis in environmental samples is carried out by CIEMAT using standardized methods based on sequential separation with ionic-exchange resins. The americium fraction is purified through a two-layer ion exchange column and lately in an anion-exchange column in nitric acid methanol medium. The technique is time consuming and the results are not completely satisfactory (low recovery and loss of a-resolution) for some samples. The chemical compound CMPO (octyl(phenyl)-N,N-diisobutyl carbomoylmethyiphosphine oxide) dissolved in TPB (tributyl phosphate) and supported on an inert substrate has been tested directly for ''241Am analysis by a large number of laboratories. A new method that combines both procedures has been developed. The details of the improved procedure are described in this paper. The advantages of its application to environmental samples (urine, faeces and sediments) are discussed. The utilization of standard samples, with americium certified concentrations confirms the reliability of our measurements. (Author) 8 refs.

  1. UASB technology applied to treat industrial spills with high organic load: effluents from a factory of yeast production (Cordoba, Spain); Depuracion de vertidos organicos de alta carga: aplicacion de la tecnologia UASB al tratamiento anaerobio de las vinazas de una fabrica de levadura (Cordoba)

    Energy Technology Data Exchange (ETDEWEB)

    Marin Galvin, R.; Aguilar Jimenez, J. M.; Rojas Moreno, F. J.

    2005-07-01

    This paper deals on the yielding obtained in the exploitation of an UASB Water Treatment Plant, which is located in to the La Golondrina Wastewater Treatment Plant (Cordoba, Spain). This UASB Water Treatment Plant is focused to treat spills from yeast production with a treatment capacity of 2.100 m''3/day. From july of 1997 to may of this year, the plant has produced treated waster with 1.446 mg/l of suspended solids (influent, 2.471 mg/l), 1.449 mg/l of BOD{sub 5} (influent, 13.578 mg/l): this implies a global yielding of 70,5%. Furthermore, the UASB plant has generated 2.828 m''3/day of biogas with high quality which is later used in a co-generation system there available. (Author) 15 refs.

  2. Determination of organic compounds in medicinal plants, commercialized in capsulated forms and 'in natura' by wavelength dispersive X-ray fluorescence spectrometry (WDXRF). Determination of quantitative inorganic profiles; Determinacao de componentes organicos em plantas medicinais, comercializadas em forma de po (capsulas) e 'in natura', utilizando a tecnica de fluorescencia de raios X por dispersao de comprimento de onda (WDXRF). Determinacao de perfis inorganicos quantitativos

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Manuel Octavio M; Sato, Ivone Mulako; Salvador, Vera Lucia R [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil). Centro de Quimica e Meio Ambiente

    2005-07-01

    X-ray fluorescence technique was used to determine major and trace elements for five Brazilian commercial medicinal plants. The bromobutane (Barbatimao), Ginkgo folium (Ginkgo biloba), Echinodorus macrophyllus (Chapeu de couro), Valeriana officinalis (Valeriana), Cordia salicifolia (Porangaba) samples were collected from three to six different commercial suppliers. The species were collected 'in natura' (leaves, flowers, barks and roots) and capsulated forms. The samples were grinded in liquid N{sub 2} atmosphere and double layer pressed pellet were prepared. The elements Na, Mg, P, S, Cl, K, Ca, Mn, Fe, Ni, Cu, Zn, Rb e Sr concentrations were determined by individual calibration curves. The precision and accuracy of method were evaluated by certified reference material, NIST 1547 - Peach Leaves and the Chauvenet, Cochrane, ANOVA and Z-score statistical tests were applied. Each specimen presented a distinct inorganic profile and a great variation in its composition was observed. The inorganic profile will contribute for the elaboration of a quality and security guide to assure the phytotherapics commercialization. Moreover, these profiles could be used as complementary data to active farmaco compounds profiles for specimen's ratification. (author)

  3. Extensions of the techniques for the accelerated unspecific isotopic labelling of organic compounds; Applications nouvelles des techniques accelererees du marquage non specifique de composes organiques; Rasprostranenie metodov uskoreniya mecheniya nespetsifichnymi izotopami organicheskikh slozhnykh soedinenij; Nuevas aplicaciones de las tecnicas de marcacion inespecifica acelerada de compuestos organicos

    Energy Technology Data Exchange (ETDEWEB)

    Ghanem, N A [National Research Centre, El-Dokki, Cairo (Egypt); Westermark, T [Division of Physical Chemistry, Royal Institute of Technology, Stockholm 70 (Sweden)

    1962-03-15

    The paper aims at reviewing new means of obtaining acceleration in the reaction of a radioactive gas with a target material to be labelled and examples of successful cases. The techniques include the use of microwave and radiowave discharges, glow discharges affected through DC or AC sources, and simply ultraviolet radiation. Specific activities of more than 100 mc/g in purified significant quantities of products were obtained. Periods of exposure to discharge were of the order of one minute and decomposition was limited in most cases. Calculations of utilization of the energy absorbed during the labelling process were compared with the energy from ionizing radiation used by Wilzbach and others, and G values for isotope replacement are given. In polystyrene labelling, evidence is found that the mechanisms is governed by an atom-molecule reaction. (author) [French] Les auteurs passent en revue des methodes recentes visant a accelerer la reaction d'un gaz radioactif avec des matieres a marquer; ils citent des cas de reussite. Les techniques etudiees comportent l'emploi de decharges de micro-ondes et d'ondes hertziennes, de decharges luminescentes par des sources de courant continu ou alternatif et de simples rayons ultraviolets. On a obtenu des activites specifiques superieures a 100 mc/g dans des quantites importantes de produits purifies. Les temps d'exposition a la decharge etaient de l'ordre d'une minute; dans la plupart des cas, la decomposition etait limitee. Les auteurs comparent la quantite d'energie absorbee au cours du marquage a celle qui est necessaire lorsqu'on emploie des rayonnements ionisants, comme l'ont fait Wilzbach et autres; ils donnent les valeurs G de remplacement des isotopes. Dans le marquage du polystyrene, il semble bien que le processus soit regi par une reaction atome-molecule. (author) [Spanish] El objeto de la memoria es pasar revista a nuevos metodos para acelerar la reaccion de un gas radiactivo con el material de blanco que se desea marcar, y citar ejemplos en los que este procedimiento se ha empleado con exito. Las diversas tecnicas se basan en el uso de descargas de microondas y de ondas hertzianas, descargas luminiscentes producidas por corriente continua, o alterna, o sencillamente rayos ultravioleta. Se han obtenido cantidades considerables de productos purificados con actividades superiores a 100 mcuries/g. Los tiempos de exposicion a las descargas son del orden de un minuto, y en la mayoria de los casos se observo poca descomposicion. Los autores calcularon el rendimiento energetico alcanzado en estos metodos de marcacion y lo comparan con el correspondiente a las radiaciones ionizantes empleadas por Wilzbach y otros investigadores; tambien dan los valores de G para la sustitucion isotopica. Existen pruebas de que la marcacion del poliestireno se produce en virtud de una reaccion atomo-molecula. (author) [Russian] Tsel'yu nastoyashchego doklada yavlyaetsya rassmotrenie novykh sposobov uskoreniya reaktsii mezhdu radioaktivnym gazom i materialom misheni, podlezhashchim mecheniyu, a takzhe privedenie primerov uspeshnykh sluchaev. Ehti metody vklyuchayut ispol'zovanie razryadov mikrovoln i radiovoln, tleyushchikh razryadov pod vozdejstviem istochnikov postoyannogo ili peremennogo tokov, ili prosto radiatsii ul'trafioletovykh luchej. Byla dostignuta udel'naya aktivnost', dokhodyashchaya do 100 mikrokyuri na gramm, v znachitel'nykh kolichestvakh ochishchennogo produkta. Vremya vozdejstviya razryada bylo poryadka odnoj minuty, i vo mnogikh sluchayakh razlozhenie bylo chrezvychajno ogranichennym. Dayutsya podschety ehffektivnosti ispol'zovaniya ehnergii dlya proizvodstva mecheniya ehtimi metodami po sravneniyu s zatratoj dlya toj zhe tseli ehnergii ioniziruyushchego izlucheniya, ispol'zuemoj Vil'tsbakhom i dr. ; krome togo, ukazyvayutsya znacheniya radiatsionnokhimicheskogo vykhoda G dlya zameny izotopov. Est' ukazaniya na to, chto pri mechenii polistirola mekhanizm opredelyaetsya reaktsiej atom-molekula. (author)

  4. Synthesis in aqueous medium and organic praseodymium complexes with ligands derived from Schiff base quinolinic. Characterization and physicochemical study; Sintesis en medio acuoso y organico de complejos de praseodimio con ligantes derivados de base de Schiff quinolicos. Caracterizacion y estudio fisicoquimico

    Energy Technology Data Exchange (ETDEWEB)

    Garcia G, A.

    2015-07-01

    It was investigated the coordination ability of the quinolinic Schiff base organic tetradentate quinolinic ligand (Q Schiff-(OH){sub 2}) towards the trivalent praseodymium by UV/Vis spectrophotometric titration (St). By St, was studied the formed species between the Q Schiff-(OH){sub 2} ligand and the praseodymium nitrate salt in equimolar concentrations (5.86 x 10{sup -4} M: 5.22 x 10{sup -4} M) in methanol. The statistical analysis of the experimental results suggested three complexed species with 1Pr:3L, 1Pr:2L y 1Pr:1L stoichiometries. The predominant stoichiometries were the second and the latter. Based on these results and data from the scientific literature, the methodology for the syntheses of the complexes Q Schiff-(OH){sub 2}-Pr in aqueous-organic and organic media was established and a molar ratio M:L= 1:2 of praseodymium nitrate and the ligand was used. The new complexes were characterized by UV/Vis, Infrared, X-ray Photoelectron Spectroscopy (XP S), Diffuse Reflectance (Dr) and Thermogravimetric Analysis/Differential Scanning Calorimetry (TGA/DSC). Elemental analysis of C, N, O and Pr by XP S suggested 1Pr:2L:1Na (PrC{sub 32}H{sub 20}N{sub 4}O{sub 4}Na) stoichiometry of the complex synthesized by the aqueous-organic medium while for the complex synthesized by the organic medium it was 1Pr:3L (PrC{sub 48}H{sub 33}N{sub 6}O{sub 6}). In the first case, the praseodymium ion charge was neutralized by the anionic ligands whose remaining charge was compensated by the sodium ion. In the second case, the ion charge was neutralized by the ligands. The minimum formula was Pr(Q Schiff){sub 2}Na for the pure coordination compound from the aqueous-organic medium and the minimum formula Pr(Q Schiff){sub 3} for that from the organic medium. XP S also indicated that the oxidation state of praseodymium ion was maintained. Both complexes were stable in methanol, ethanol and acetonitrile at least for 5 days. The photophysical properties of the studied complexes were evaluated by emission and excitation luminescence (fluorescence and phosphorescence) at ambient temperature (291 K) and liquid nitrogen (77 K) in the UV-Visible region. It was found that the ligand transfers its energy to the praseodymium at least 70%. It is concluded that two new complexes were obtained by Q Schiff-(OH){sub 2} and the praseodymium with a reaction yield of about 60% (Pr(Q Schiff){sub 2}Na) and 75% (Pr(Q Schiff){sub 3}). UV/Vis, IR and Dr, XP S and TGA/DSC demonstrated the coordination of quinolate and imine groups from the ligand to the metal ion. Thus a CN=8 para Pr(Q Schiff){sub 2}Na and CN= 12 para Pr(Q Schiff){sub 3}. Their photophysical properties in the visible region suggested that the quinolinic Schiff base organic tetradentate quinolinic ligand transfers energy from its excited triplet state to the praseodymium ion sensitising the luminescence properties from the metal ion which in turn re-emits enhanced light from its {sup 1}D{sub 2} level, mainly. (Author)

  5. Synthesis and characterization of hybrid organic-inorganic materials of polyamide-imide (PAI) and copolysilsesquioxanes of 3-aminopropyltriethoxysilane (APES) and phenyltriethoxysilane (PTES); Sintese e caracterizacao de materiais hibridos organico-inorganicos de poliamida-imida e copolisilsesquioxanos de 3-aminopropiltrietoxissilano e feniltrietoxissilano

    Energy Technology Data Exchange (ETDEWEB)

    Demarchi, A.A., E-mail: aa_demarchi@terra.com.b [WEG Equipamentos Eletricos S.A., Jaragua do Sul, SC (Brazil). Dept. de P e D do Produto; Pezzin, S H [Universidade do Estado de Santa Catarina (UDESC), SC (Brazil). Centro de Ciencias Tecnologicas

    2010-07-01

    In this work, organic-inorganic hybrids were obtained by adding copolysilsesquioxanes of 3-aminopropyltriethoxysilane (APES) and phenyltriethoxysilane (PTES), prepared by sol-gel, to the polyamide-imide (PAI). The synthesis of PAI oligomer from trimellitic anhydride (TMA) and 4,4-diphenyl-methane diisocyanate (MDI), was monitored by FTIR, noting that two steps of 80 deg C and 120 deg C for 2 h each are sufficient to obtain it. PAI-copolysilsesquioxanes hybrids were characterized by FTIR, viscometry, thermogravimetry, NMR and microscopy. The spectrum of the PAI and PAI-hybrid copolysilsesquioxanes show the formation of amide and imide. Copolysilsesquioxanes with high levels of APES increased the viscosity and generated the PAI oligomer gelatinization, hindering the formation of uniform films. Gelatinization did not occur with copolysilsesquioxanes rich PTES, allowing the formation of homogeneous films improvements in thermal resistance. (author)

  6. Download this PDF file

    African Journals Online (AJOL)

    Estudio del compostaje de residuos organicos. Volarcion. Agriola. In. Ph.D. Thesis Murcia University (In. Spanish) Spain. Johnson W.F. Jr. and Wolf (1995). Nitrogen transformations in Sills amended with poultry litter under aerobic conditions followed by anaerobic periods. P27 - 34 . In K Steele (ed). Animal wastes and the.

  7. Efeitos dos parâmetros operacionais na fotodegradação do azo corante direct red 23 na interface dióxido de titânio/água Effects of operational parameters on the photodegradation of direct red 23 azo dye at the titanium dioxide/water interface

    Directory of Open Access Journals (Sweden)

    Débora Nobile Clausen

    2007-01-01

    Full Text Available The decolorization and degradation of direct red 23 azo dye have been investigated in aqueous suspension of titanium dioxide under artificial irradiation. The effects of some operational parameters such as azo dye concentration, catalyst loading, and solution pH were investigated at 30.0 ºC and optimized values were obtained. The first-order kinetic model was used to discuss the results. The UV-Vis spectra changes showed that the azo dye sample, collected after 6 h irradiation, was 98% decolorized while the residual total carbon was 97.9% degraded, indicating simultaneous photodecolorization and degradation.

  8. Determinação de corantes marcadores do tipo azo e antraquinona em combustíveis por cromatografia líquida com detecção eletroquímica Determination of azo and anthraquinone dyes in fuels sample using hplc with electrochemical detection

    Directory of Open Access Journals (Sweden)

    Magno Aparecido Gonçalves Trindade

    2010-01-01

    Full Text Available An analytical method based on high-performance liquid chromatography with electrochemical detection has been developed and applied to the determination of Solvent blue 14 (SA-14 and Solvent red 24 (SV-24 in fuel samples. The dyes were better separated on C18 column, using a mobile phase composed of acetonitrile and ammonium acetate (90:10, v/v. Detection was carried out at an oxidation potential of +0.85V. The detector response was linear at concentration range of 7.50×10-8 - 1.50×10-6 mol L-1 (r = 0.997 for SA-14 and SV-24, respectively. The method was used to quantify these dyes in fuels samples with satisfactory accuracy and precision.

  9. Synthesis and characterization of CeO{sub 2} - TiO{sub 2} system for use in heterogeneous photocatalysis in photodegradation of methylene blue dye; Sintese e caracterizacao do sistema CeO{sub 2} - TiO{sub 2} para aplicacao em fotocatalise heterogenea na fotodegradacao do corante azul de metileno

    Energy Technology Data Exchange (ETDEWEB)

    Bragatto, Julia

    2016-07-01

    This study has as its goal the synthesis of a mixed oxide system type CeO{sub 2} - TiO{sub 2}, through the polymeric precursor method, to be used in heterogeneous photocatalysis. The synthesized materials were characterized by Thermogravimetry (TG), Derivative Thermogravimetry (DTG), Differential Thermal Analysis (DTA) and X-Ray Diffraction (XRD). The results of the thermal analysis showed in what temperature ranges certain events occur such as the formation of cerium oxide between 600 and 800 ° C, which refers to the crystallization of the material. Regarding the formation of titanium oxide, events between 600 and 800 ° C are perceived, which suggests the transformation of anatase to rutile phase. The XRD analysis showed no occurrence of the same phase for all materials, meaning that there is a variation in the formation of phases according to concentration of precursor for each sample. Noteworthy are the formation of CeO{sub 2} for Ce75-Ti25 and Ce50-Ti50 concentrations, with cubic crystal structure of the fluorite type. In Ce75-Ti25 and Ce25-Ti75 it is present the TiO{sub 2} in the anatase and rutile phase, with crystal structure of the tetragonal and tetrahedron type, respectively, as well as the formation of CeTi{sub 2}O{sub 6} in Ce50-Ti50 and Ce25-Ti75, with structure monoclinic. From these analyses, it is possible to see which samples, and in which temperatures of calcination the material has increased crystallinity, making the choice for their application in heterogeneous photocatalysis, aiming the degradation of methylene blue dye. Among the tested materials for methylene blue, the sample that stood out was the Ce50-Ti50, with calcination temperature of 800 °C, with values close to 50% degradation, because it was the sample that showed higher dye adsorption capacity, which is the step that precedes photodegradation. (author)

  10. Conhecimento dos graduandos de nutrição e enfermagem quanto ao consumo de corantes alimentares e seus efeitos adversos à saúde Knowledge of nursing and nutrition graduate students on the consumption of food colorings and their adverse health effects

    Directory of Open Access Journals (Sweden)

    Julia Nascimento Teles

    2016-10-01

    Objetivo: Evaluar la función intestinal de la clientela adulta atendida, asociándolos a los factores de riesgo, a partir de datos obtenidos en el Programa Fábrica de Cuidados. Métodos: Fueron seleccionadas 377 historias clínicas de adultos de ambos sexos. De estas, 48 presentaban el relato de constipación intestinal. Fueron colectadas variables sociodemográficas, de consumo alimentar y estilo de vida. Resultados: La prevalencia de constipación fue de 12,7%, con predominancia del sexo femenino de 89,6%. Se observó un bajo consumo de fibras, donde 69,7% y 66,7% de los pacientes constipados no consumían diariamente frutas/jugos y hortalizas A y B, respectivamente. Sobre el diagnóstico nutricional, 58,3% del grupo presentó IMC superior a 25. La ingestión hídrica, 31,2% consumían por lo menos 08 vasos/día. El sedentarismo fue predominante en el grupo (62%, además 60,4% substituían las principales refecciones por aperitivos. Conclusión: El perfil de la población en relación a los factores en estudio, justifica la alta prevalencia de la constipación. Descriptores: Constipación Intestinal, Adultos, Fibras, Estilo de vida.

  11. Aplicação de um corante tiazolilazo como indicador ácido-base e determinação das suas constantes de ionização ácida Application of a thiazolylazo dye as an acid-base indicator and determination of its acid ionization constants

    Directory of Open Access Journals (Sweden)

    Regina Terumi Yamaki

    2009-01-01

    Full Text Available The pKa values of the 6-[2´-(6´-methyl-benzothiazolylazo]-1,2-dihydroxy-3,5-benzenedisulfonic acid (Me-BDBD have been determined at 25 °C, in 0.10 mol L-1 NaCl medium by spectrophotometric method. The SQUAD computer program was used to process experimental data in pH range 1.78 - 11.54 and 290 - 720 nm. The pKa values obtained were 4.60 ± 0.04 and 9.48 ± 0.02. The Me-BDBD reagent was applied as indicator in titration of acid-base. The results were compared with phenolphthalein and bromocresol green indicators. Statistical t and F tests indicated that there were no statistically significant differences between the results for indicators with good agreement.

  12. Remoção dos corantes azul brilhante, amarelo crepúsculo e amarelo tartrazina de soluções aquosas utilizando carvão ativado, terra ativada, terra diatomácea, quitina e quitosana: estudos de equilíbrio e termodinâmica

    Directory of Open Access Journals (Sweden)

    Guilherme Luiz Dotto

    2011-01-01

    Full Text Available This work compared activated carbon, activated earth, diatomaceous earth, chitin and chitosan to removal acid blue 9, food yellow 3 and FD&C yellow nº 5 dyes from aqueous solutions with different pH values (2-10. In the best process condition for each dye, equilibrium studies were carried out at different temperatures (from 298 to 328 K and Langmuir, Freundlich, Redlich-Peterson, Temkin and Dubinin-Radushkevich models were fitted with experimental data. In addition, entropy change, Gibbs free energy change and enthalpy change were obtained in order to verify the thermodynamic adsorption behavior.

  13. Adsorption of reactive Remazol Red RB dye of aqueous solution using zeolite of the coal ash and evaluation of acute toxicity with Daphnia similis; Adsorcao de corante reativo Remazol Vermelho RB de solucao aquosa usando zeolita de cinzas de carvao e avaliacao da toxicidade aguda com Daphnia similis

    Energy Technology Data Exchange (ETDEWEB)

    Magdalena, Carina Pitwak

    2010-07-01

    In this study, the capacity of zeolite synthesized from coal ash in the removal of Remazol Red dye aqueous solution was investigated by batch mode operation. The equilibrium was attained after 360 min of contact time. The adsorption rate followed the kinetic model of pseudo-second-order. The equilibrium data obtained fitted to Langmuir adsorption isotherm showing the adsorption capacity of up to 1.20mg g-1. The efficiency of adsorption was between 75 to 91% in the equilibrium time. In order to obtain the best conditions for removal of this dye, the influence of the following parameters was: initial concentration of the dye, pH of the aqueous solution, dose of adsorbent and temperature. The thermodynamic parameters were evaluated showing that the adsorption of Remazol red on the zeolite is of a spontaneous nature. Experiments by adding NaCl and Na{sub 2}SO{sub 4} were carried out to simulate the real conditions of the effluents from the dyeing bath and to evaluate the influence of these chemical compounds in the phenomenon of adsorption. The equilibrium data of adsorption of Remazol red on the zeolite was achieved in a shorter time in the presence of increasing concentrations of salts in solution and an increase in adsorption capacity. The efficiency of the study was evaluated as a treatment for acute toxicity using Daphnia similis microcrustacean. (author)

  14. Estudo da sorção do corante catiônico violeta cristal por espuma de poliuretano em meio aquoso contendo dodecilsulfato de sódio Sorption of crystal violet by polyurethane foam from aqueous medium containing sodium dodecylsulfate

    Directory of Open Access Journals (Sweden)

    Mariana Mori

    2009-01-01

    Full Text Available This work presents a detailed study about the sorption of crystal violet (CV cationic dye onto polyether type polyurethane foam (PUF. The sorption process was based on the formation of an ionic-pair between cationic dye and dodecylsulfate anion (SDS, which presented high affinity by PUF. Set-up employed in the study was built up by adjusting a 200 mg cylinder of PUF to the arm of an overhead stirrer. The system was characterized in relation to equilibrium and kinetic aspects and it was modeled by employing Langmuir and Freundlich isotherms. Obtained results showed that the ratio between SDS and MB concentrations played an important role on the sorption process. According to results found it was possible to retain up to 3.4 mg of dye from 200 mL of a 5.0 x 10-5 mol L-1 CV solution containing 1.25 x 10-4 mol L-1 SDS, which represented a removal efficiency of around 92%.

  15. Evaluation of the hydrogen peroxide and special colorant effects under irradiation by argon and diode laser on tooth-whitening in vitro; Avaliacao do efeito de corantes especiais e peroxido de hidrogenio irradiados por laser de argonio e laser de diodo no clareamento dental 'in vitro'

    Energy Technology Data Exchange (ETDEWEB)

    Gaspar, Jose Antonio

    2003-07-01

    The aim of this study is to determine if there is any interaction between special colorant found on bleaching agents that have 35 % of hydrogen peroxide on its composition, and argon or diode laser. The first part of the study was to characterize the extrinsic stain obtained through a staining solution containing products present on the day by day diet of the general population. Thirty-two inferior human extracted incisors, free of caries and without filling material were selected for the study. The laser devices employed were Argon laser (AccuCure 3000 TM - Lasermed), wave length 488 nm, with a 200 mW/cm{sup 2} for 30 seconds in continuos mode; and diode laser (L 808 Medical Laser - Lasering do Brasil), wave length 808 {+-} 10 nm, with 1,6 W/cm{sup 2} for 30 seconds in continuos mode. The application mode done by a scanning movement over the buccal surface. The bleaching agents used were: Opalescence Extra (OE) - Ultradent Products USA, hydrogen peroxide 35%, gel with Carotene to convert light into heat; Pola Office (PO) - SDI - USA single doses of hydrogen peroxide; Whiteness HP (WHP) - FGM - Brasil, hydrogen peroxide 35%; Opus White (OW) - Sharplan - Israel, hydrogen peroxide 35%. The temperature rise measurement was performed with a thermocouple model 120-202-AJ, Fenwal, inserted into the pulpar chamber. The bleaching material was applied on the tooth surface with 2 mm thickness and then the irradiation was perform. The thirty two teeth were randomized in four groups, two for each laser device. The obtain data demonstrated a superior performance of the Argon laser on tooth whitening and also better results concerning the temperature rise. The alteration on tooth coloration was verified through digital spectrophotometer (Shade-Eye EX - Shofu) and quantitative analyses showed statistical differences among the groups. The bleaching results for Argon laser combined with OE and WHP were superior for the other groups. The mean variation of the temperature rise obtained Argon laser were {<=} 5,6 deg C, and the values obtained with the Diode laser were {>=} 5,6 deg C. The results obtained lead to conclude that Argon laser is safer and more efficient than diode laser for tooth whitening procedures, and the best results achieved with the association of Argon laser irradiation to the bleaching agent OP and WHP. (author)

  16. Evaluation of the hydrogen peroxide and special colorant effects under irradiation by argon and diode laser on tooth-whitening in vitro; Avaliacao do efeito de corantes especiais e peroxido de hidrogenio irradiados por laser de argonio e laser de diodo no clareamento dental 'in vitro'

    Energy Technology Data Exchange (ETDEWEB)

    Gaspar, Jose Antonio

    2003-07-01

    The aim of this study is to determine if there is any interaction between special colorant found on bleaching agents that have 35 % of hydrogen peroxide on its composition, and argon or diode laser. The first part of the study was to characterize the extrinsic stain obtained through a staining solution containing products present on the day by day diet of the general population. Thirty-two inferior human extracted incisors, free of caries and without filling material were selected for the study. The laser devices employed were Argon laser (AccuCure 3000 TM - Lasermed), wave length 488 nm, with a 200 mW/cm{sup 2} for 30 seconds in continuos mode; and diode laser (L 808 Medical Laser - Lasering do Brasil), wave length 808 {+-} 10 nm, with 1,6 W/cm{sup 2} for 30 seconds in continuos mode. The application mode done by a scanning movement over the buccal surface. The bleaching agents used were: Opalescence Extra (OE) - Ultradent Products USA, hydrogen peroxide 35%, gel with Carotene to convert light into heat; Pola Office (PO) - SDI - USA single doses of hydrogen peroxide; Whiteness HP (WHP) - FGM - Brasil, hydrogen peroxide 35%; Opus White (OW) - Sharplan - Israel, hydrogen peroxide 35%. The temperature rise measurement was performed with a thermocouple model 120-202-AJ, Fenwal, inserted into the pulpar chamber. The bleaching material was applied on the tooth surface with 2 mm thickness and then the irradiation was perform. The thirty two teeth were randomized in four groups, two for each laser device. The obtain data demonstrated a superior performance of the Argon laser on tooth whitening and also better results concerning the temperature rise. The alteration on tooth coloration was verified through digital spectrophotometer (Shade-Eye EX - Shofu) and quantitative analyses showed statistical differences among the groups. The bleaching results for Argon laser combined with OE and WHP were superior for the other groups. The mean variation of the temperature rise obtained Argon laser were {<=} 5,6 deg C, and the values obtained with the Diode laser were {>=} 5,6 deg C. The results obtained lead to conclude that Argon laser is safer and more efficient than diode laser for tooth whitening procedures, and the best results achieved with the association of Argon laser irradiation to the bleaching agent OP and WHP. (author)

  17. Descoloração redutiva de corantes azo e o efeito de mediadores redox na presença do aceptor de elétrons sulfato Reductive decolourisation of azo dyes and the effect of redox mediators in the presence of the electron acceptor sulfate

    Directory of Open Access Journals (Sweden)

    Mayara Carantino Costa

    2010-01-01

    Full Text Available We investigated the impact of sulphate and the redox mediator Anthraquinone-2,6-disulfonate (AQDS on the decolorization of the azo dyes Congo Red (CR and Reactive Black 5 (RB5. In anaerobic reactors free of extra sulphate dosage, the color removal efficiency decreased drastically when the external electron donor ethanol was removed. In presence of an extra dosage of sulphate, CR decolourisations were 47.8% (free of AQDS and 96.5% (supplemented with AQDS. The decolourisations achieved in both reactors with RB5 were lower than the ones found with CR. Finally, the biogenic sulphide contribution on azo dye reduction was negligiable.

  18. Chitosan/Fe spheres on the blue QR-19 dye degradation by photo Fenton processes using artificial or solar light; Esferas de quitosana/Fe na degradacao do corante azul QR-19 por processos foto-Fenton utilizando luz artificial ou solar

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Kely V. de; Zamora, Patricio G.P.; Zawadzki, Sonia F. [Universidade Federal do Parana (DQ/UFPR), Curitiba, PR (Brazil). Dept. de Quimica], E-mail: zawadzki@quimica.ufpr.br

    2010-07-15

    The contamination of water resources is one of the greatest environmental problems today. Among the polluting sources are the textile industries due to the production of large volumes of effluent, often treated inefficiently. The main reason for the environmental impact of the rejected materials is the presence of dyes such as azo reactive compounds that can generate by-products with carcinogenic and mutagenic effects. They may also include anthraquinone type compounds, which are highly resistant to degradation and persist in the effluent for a long time. The purpose of this study is the use of photo-Fenton processes assisted by artificial or solar light, using immobilized iron on chitosan beads, crosslinked with glutaraldehyde, for the anthraquinone type compound Blue QR-19 standard dye degradation in aqueous solutions. The obtained spheres showed a regular size and 4.0 mm diameter. The results showed 90% discoloration of the system within 180 minutes and a 60% total organic carbon (TOC)reduction for the photo-Fenton system using artificial light. For the system using sunlight, the total discoloration was achieved in 120 minutes and the TOC value decreased 70%. Also observed was that iron remained in the polymeric matrix after the treatment, thus allowing reuse. (author)

  19. Comportamento tintorial do Mycobacterium leprae: revisão histórica Tinctorial behavior of Mycobacterium leprae: a historical review

    Directory of Open Access Journals (Sweden)

    Luiz Fernando de Góes Siqueira

    1983-08-01

    Full Text Available Foi feita revisão histórica sobre os corantes utilizados na identificação do Mycobacterium leprae. Foram analisadas para cada corante, sua composição química, propriedades tintoriais e a capacidade de assimilação pelo bacilo nas diversas técnicas de coloração.A historical review was made of the dyes utilized to identify the Mycobacterium leprae. The chemical composition and the tinctorial properties of these substances and the dye assimilation capacity of the bacilli were analyzed.

  20. Oriente within, Nord without: il meridionismo e i romantici inglesi

    Directory of Open Access Journals (Sweden)

    Luigi Cazzato

    2012-11-01

    Full Text Available Per Voltaire (1773 prima ed Hegel (2010 poi, la storia del progresso del mondo ha viaggiato seguendo il percorso geo-politico e climatico aristotelico 1: dal dispotico Oriente verso il libero Occidente; mentre per Montesquieu (1994 essa ha viaggiato anche dai paesi caldi del Sud, timorosi come i vecchi, verso i paesi freddi del Nord, coraggiosi come i giovani. L’Europa non si è vista solo come l’altro rispetto all’Oriente, ma anche come l’altro rispetto al suo Meridione: il presente moderno del Nord di contro al passato antico del Sud. Nella seconda metà del Settecento, il secolo della nascita dell’orientalismo come sapere organico all’impresa coloniale dell’Occidente, vennero gettati anche i semi della pianta del meridionismo, sapere organico all’impresa della costruzione della moderna identità europea. I romantici inglesi coltivarono questa pianta.

  1. Determination of organic compounds in medicinal plants, commercialized in capsulated forms and 'in natura' by wavelength dispersive X-ray fluorescence spectrometry (WDXRF). Determination of quantitative inorganic profiles; Determinacao de componentes organicos em plantas medicinais, comercializadas em forma de po (capsulas) e 'in natura', utilizando a tecnica de fluorescencia de raios X por dispersao de comprimento de onda (WDXRF). Determinacao de perfis inorganicos quantitativos

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Manuel Octavio M.; Sato, Ivone Mulako; Salvador, Vera Lucia R. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil). Centro de Quimica e Meio Ambiente]. E-mail: lawless@usp.br

    2005-07-01

    X-ray fluorescence technique was used to determine major and trace elements for five Brazilian commercial medicinal plants. The bromobutane (Barbatimao), Ginkgo folium (Ginkgo biloba), Echinodorus macrophyllus (Chapeu de couro), Valeriana officinalis (Valeriana), Cordia salicifolia (Porangaba) samples were collected from three to six different commercial suppliers. The species were collected 'in natura' (leaves, flowers, barks and roots) and capsulated forms. The samples were grinded in liquid N{sub 2} atmosphere and double layer pressed pellet were prepared. The elements Na, Mg, P, S, Cl, K, Ca, Mn, Fe, Ni, Cu, Zn, Rb e Sr concentrations were determined by individual calibration curves. The precision and accuracy of method were evaluated by certified reference material, NIST 1547 - Peach Leaves and the Chauvenet, Cochrane, ANOVA and Z-score statistical tests were applied. Each specimen presented a distinct inorganic profile and a great variation in its composition was observed. The inorganic profile will contribute for the elaboration of a quality and security guide to assure the phytotherapics commercialization. Moreover, these profiles could be used as complementary data to active farmaco compounds profiles for specimen's ratification. (author)

  2. Modelamiento de adsorción y desorción de compuestos orgánicos volátiles COV´s sobre materiales microporosos para el tratamiento y recuperación de efluentes provenientes de procesos industriales

    OpenAIRE

    Camargo Trillos, Diego Alejandro

    2011-01-01

    Las emisiones de compuestos organicos volatiles o COV’s, han despertado un gran interes en las autoridades ambientales alrededor del mundo por el gran impacto que estos presentan en la salud humana y la calidad del aire en las grandes ciudades. Los limites permisibles de estas emisiones industriales cada vez son mas exigentes en Colombia, obligando a las industrias a implementar sistemas de control de emisiones. Entre varias tecnologias de control para corrientes de COV en efluentes indust...

  3. Analysis of economic break-even point of the biogas utilization for electrical power conversion: case study in a swine terminated unit; Analise do ponto de equilibrio economico da utilizacao do biogas para conversao em energia eletrica: estudo de caso em unidade de terminacao de suinos

    Energy Technology Data Exchange (ETDEWEB)

    Cervi, Ricardo Ghantous; Pinotti, Elvio Brasil [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Registro, SP (Brazil). Fac. de Ciencias Agrarias do Vale do Ribeira], e-mails: rghantous@registro.unesp.br, epinotti@registro.unesp.br; Esperancini, Maura Seiko Tsutsui; Bueno, Osmar de Carvalho [Universidade Estadual Paulista Julio de Mesquita Filho (FCA/UNESP), Botucatu, SP (Brazil). Fac. de Ciencias Agronomicas. Dept. de Gestao e Tecnologia Agroindustrial], e-mails: maura@fca.unesp.br, osmar@fca.unesp.br

    2010-07-01

    This work aimed to develop a study to estimate the break-even point in financial units of the electrical power generation using biogas from swine wastes. The analyzed biodigester is a continuous tubular model with brick concrete duct and plastic covering with a gasometer, and where the waste of 2,300 fattening pigs are deposited daily. The initial investment estimate for the installation was R$ 51,537.17. The system annual costs were R$ 5,708.20, for maintenance, R$ 4,390.40 for depreciation and R$ 1,366.77 for interests. It was noticed that with an average of consumption of 17.1 kW.hour{sup -1} the system presents an annual loss of R$ 1,592.14 because the consumption of 27.85 kW.hour{sup -1} is the minimum that should be consumed to achieve a corresponded financial break-even point of R$ 15,054.40.year{sup -1}. It was concluded that the correct technical dimensioning greatly influences on the economic results. (author)

  4. Study of technical, economical and environmental feasibility of biogas digesters utilization on a farm in Recreio dos Bandeirantes, Rio de Janeiro, Brazil; Estudo de viabilidade tecnica, economica e ambiental de utilizacao de biodigestores em uma fazenda no Recreio dos Bandeirantes, Rio de Janeiro

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, Silvio Carlos Anibal de [Universidade Federal do Rio de Janeiro (DEM/CT/UFRJ), RJ (Brazil). Centro de Tecnologia. Dept. de Engenharia Mecanica], e-mail: silvioa@gmail.com; Franca, Vignicius Curi de; Mauro Junior, Leonardo [Auto Mecanica Arapongas, Rio de Janeiro, RJ (Brazil)], e-mails: airninho@hotmail.com, leonardomauro@terra.com.br

    2008-07-01

    A techno-economic analysis of producing biogas for electric power generation is done in the present paper. A biogas production system from pig waste was proposed and designed in a farm in Recreio dos Bandeirantes, Rio de Janeiro. One of the conclusions of this study is the economic advantage of utilizing biogas for power generation rather than other fuels like LPG or purchasing electricity from grid. (author)

  5. Thermal analysis of different application techniques on Nd:YAG laser after root canal preparation of single-rooted teeth; Analise termica de diferentes tecnicas de utilizacao do laser de Nd:YAG apos o preparo quimico-cirurgico de dentes unirradiculares

    Energy Technology Data Exchange (ETDEWEB)

    Archilla, Jose Ricardo de F

    2001-07-01

    The experiment objective is to analyze temperature variation, by means of three different application techniques of Nd:YAG laser in the root canals of singlerooted anterior teeth. Three root canals were instrumented, irrigated, X-rayed to measure the remaining dentin in the apical area and submitted to laser irradiation techniques used by Gutknecht, Matsumoto and a new technique with oscillatory movement. The used laser parameters were: pulse energy 250 mJ, frequency 5 Hz, pulse fluency 354 J/cm{sup 2}, average potency 1,25 W, pulse width 300 {mu}s, fiber core diameter 300 {mu}s and interval of thermal relaxation of 20 s. After temperature evaluation and interpretation of the obtained data, it was concluded: 1) the oscillatory technique provided a better heat distribution during the laser application, when analyzing the graphs separately; 2) all the used techniques are within a pattern of safety, analyzing the average and highest temperatures of the apical area and the middle third, even so, disrespecting the last application day and the middle third of root 'C'.(author)

  6. Synthesis NiAl{sub 1,0}Fe{sub 1,0}O{sub 4} catalyst by the combustion reaction to their use in the shift reaction (WGSR); Sintese do catalisador de NiAl{sub 1,0}Fe{sub 1,0}O{sub 4} por reacao de combustao visando sua utilizacao na reacao de shift (WGSR)

    Energy Technology Data Exchange (ETDEWEB)

    Santos, P.T.A.; Costa, A.C.F.M.; Neiva, L.S.; Gama, L. [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Dept. de Engenharia de Materiais; Argolo, F.; Andrade, H.M.C. [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Inst. de Quimica

    2009-07-01

    This work aims at the synthesis of catalyst NiAl{sub 1,0}Fe{sub 1,0}O{sub 4} by combustion reaction using urea as fuel, to evaluate its performance in the production of hydrogen by the reaction of displacement of water vapor (WGSR). The initial composition of the solution was based on valencia total oxidizing and reducing reagents based on the concepts of the chemistry of propellants, using container as a crucible of glassy silica. The resulting powder was characterized by X-ray diffraction, infrared spectroscopy, nitrogen adsorption isotherms (BET), scanning electronic microscope and catalytic tests. The DRX results reveal the presents majoritary phase NiAl{sub 1,0}Fe{sub 1,0}O{sub 4} spinel, the catalyst presents surface area 28 m{sup 2}/g and isotherms type III. Higher conversion CO/CO{sub 2} of 75% CO conversion observed at 500 deg C and catalytic activity of 43 mmolg{sup -1}.h{sup -1} at 450 deg C. (author)

  7. Use of the gamma radiation, in a dose of 0,4 kGy, on the storage temperature reduction of the banana nanica;Utilizacao da radiacao gama, na dose de 0,4kGy, na reducao da temperatura de armazenamento da banana nanica

    Energy Technology Data Exchange (ETDEWEB)

    Manoel, Luciana, E-mail: luciana_manoel@yahoo.com.b [Universidade Estadual Paulisa (UNESP), Botucatu, SP (Brazil). Fac. de Ciencias Agronomicas. Programa de Pos-graduacao em Energia na Agricultura; Vieites, Rogerio Lopes, E-mail: vieites@fca.unesp.b [Universidade Estadual Paulisa (UNESP), Botucatu, SP (Brazil). Fac. de Ciencias Agronomicas. Dept. de Gestao e Tecnologia Agroindustrial

    2009-07-01

    The aim was to evaluate the use of gamma radiation, in a dose of 0,4 kGy, on the storage temperature reduction of the banana 'Nanica'. The bananas 'Nanica' were harvested in the Arm Taperao, Brotas (SP) town, and sent to CBE (Companhia Brasileira de Esterilizacao-Cotia-SP) for irradiation and constitution of the following treatments: T1 (fruits irradiated at 0,4 kGy and stored at 16 +-1 deg C); T2 (fruits irradiated at 0,4 kGy and stored at 14 +-1 deg C); T3 (fruit irradiated ata 0,4 kGy and stored at 12+-1 deg C); T4 (fruits non-irradiated and stored at 16+-1 deg C); T5 (fruits non-irradiated and stored at 14+-1 deg C) and T6 (fruits non-irradiated and stored at 12+-1 deg C). The fruits were stored in B.O.Ds. of the Agroindustrial Management and Technology Department, with a relative humidity of 80+-5%. The experiment was divided in two groups: control group (post harvest conservation and disease incidence) and parcel group (soluble solids and pulp/peel). The analyses were performed in intervals of five days during a period of 25 days. The experimental design employed was completely randomized (DIC) by applying a factor of 2 x 3 x 6 (irradiation x temperature x time). The Tukey test with 5% of probability was used for comparison between means. The storage temperature of the bananas 'Nanica' was not reduce by irradiation. (author)

  8. Effects of using kaolin waste and granite waste as raw materials for the production of low-water absorption ceramic tiles; Efeitos da co-utilizacao dos residuos do beneficiamento do caulim e da extracao do granito rain forest para a producao de revestimentos ceramicos com baixa absorcao de agua

    Energy Technology Data Exchange (ETDEWEB)

    Freires, H.P.; Argonz, R.; Nogueira, R.E.F.Q.; Sasaki, J.M., E-mail: argonz@ufc.br [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil); Sales, J.C. [Universidade do Vale do Aracau (UVA), Crateus, CE (Brazil)

    2012-07-01

    This study aims to evaluate the potential of co-use of granite waste (Rain Forest) and kaolin waste as raw material for the manufacture of ceramic coating of low water absorption. Raw materials were characterized by X-ray diffraction. Kaolin residue was added to the residue of granite in the following proportions (in wt%): 0, 10, 20, 30, 40 and 50%. Specimens were fabricated by uniaxial pressing and fired at 1175,1200 and 1225 deg C. Studies of firing linear shrinkage, water absorption, apparent porosity, apparent density and tensile bending test (or rupture modulus) were conducted. The temperature of 1225 deg C allowed the use of a mixture of 50% granite residue and 50% kaolin residue. Ceramic parts made from that mixture exhibited the maximum values required by the Brazilian Standard NBR 13818 for water absorption, shrinkage and density. (author)

  9. Synthesis and characterization of inorganic ion exchangers based on mixed oxide tin-titanium to be used in recovery of cadmium and nickel and photoluminescent studies; Sintese e caracterizacao de trocadores ionicos inorganicos a base de oxidos mistos estanho-titanio para utilizacao na recuperacao de cadmio e niquel e estudos fotoluminescentes

    Energy Technology Data Exchange (ETDEWEB)

    Paganini, Paula Pinheiro

    2007-07-01

    This work presents the synthesis, characterization and adsorption studies of inorganic ion exchangers based on mixed tin-titanium oxide for recovery of cadmium and nickel metals from aqueous effluents, discarded in the environment mainly through Ni-Cd battery. The exchangers were synthesized by sol-gel modified method using a mixture of tin(IV) chloride and titanium(III) chloride and ammonium hydroxide, as precursors reagents. The materials obtained: SnO{sub 2}/TiO{sub 2} and SnO{sub 2}/TiO{sub 2}:Eu{sup 3+} were characterized by infrared spectroscopy, thermal analysis, scattering electronic microscopy (SEM), X-ray powder diffraction (XRD) (powder method) and electronic spectroscopy (excitation and emission) for the europium doped exchanger. The same materials also were synthesized in polymeric matrix too and can be used in column, because the synthesized materials showed crystals size in nano metric scale. It was determined by the distribution ratios for metals taking as parameters the influence of pH, the concentration of metals (by adsorption isotherms) and the contact time (by adsorption kinetic). The inorganic ion exchanger presented high exchange capacity with adsorption percent above 90 por cent for the studied conditions, quickly kinetic, heterogeneous exchange surfaces, physic adsorption and spontaneous process of exchange. To the doped exchanger spectroscopy properties were studied and also it was calculated the intensity parameters and it was found a satisfactory quantum yield. (author)

  10. Study of the microstructural and mechanical properties of titanium-niobium-zirconium based alloys processed with hydrogen and powder metallurgy for use in dental implants; Estudo das propriedades mecanicas e microestruturais de ligas a base de titanio-niobiozirconio processados com hidrogenio e metalurgia do po para utilizacao em implantes dentarios

    Energy Technology Data Exchange (ETDEWEB)

    Duvaizem, Jose Helio

    2009-07-01

    Hydrogen has been used as pulverization agent in alloys based on rare earth and transition metals due to its extremely high diffusion rate even on low temperatures. Such materials are used on hydrogen storage dispositives, generation of electricity or magnetic fields, and are produced by a process which the first step is the transformation of the alloy in fine powder by miling. Besides those, hydrogenium is also being used to obtain alloys based on titanium - niobium - zirconium in the pulverization. Powder metallurgy is utilized on the production of these alloys, making it possible to obtain structures with porous surface as result, requirement for its application as biomaterials. Other advantages of powder metallurgy usage include better surface finish and better microstructural homogeneity. In this work samples were prepared in the Ti-13Nb-13Zr composition. The hydrogenation was performed at 700 degree C, 600 degree C, and 500 degree C for titanium, niobium and zirconium respectively. After hydrogenation, the milling stage was carried out on high energy planetary ball milling with 200rpm during 90 minutes, and also in conventional ball milling for 30 hours. Samples were pressed in uniaxial press, followed by isostatic cold press, and then sintered at 1150 degree C for 7-13 hours. Microstructural properties of the samples were characterized by scanning electron microscope (SEM), energy dispersive spectroscopy (EDS) and x-ray diffraction. Mechanical and structural properties determined were density, microhardness and moduli of elasticity. The sample sintered at 1150 degree C for 7h, hydrogenated using 10.000 mbar and produced by milling on high energy planetary ball milling presented the best mechanical properties and microstructural homogeneity. (author)

  11. Development of an artificial neural network for monitoring and diagnosis of sensor fault and detection in the IEA-R1 research reactor at IPEN; Utilizacao de redes neurais artificiais na monitoracao e deteccao de falhas em sensores do reator IEA-R1

    Energy Technology Data Exchange (ETDEWEB)

    Bueno, Elaine Inacio

    2006-07-01

    The increasing demand on quality in production processes has encouraged the development of several studies on Monitoring and Diagnosis Systems in industrial plant, where the interruption of the production due to some unexpected change can bring risk to the operator's security besides provoking economic losses, increasing the costs to repair some damaged equipment. Because of these two points, the economic losses and the operator's security, it becomes necessary to implement Monitoring and Diagnosis Systems. In this work, a Monitoring and Diagnosis Systems was developed based on the Artificial Neural Networks methodology. This methodology was applied to the IEA-R1 research reactor at IPEN. The development of this system was divided in three stages: the first was dedicated to monitoring, the second to the detection and the third to diagnosis of failures. In the first stage, several Artificial Neural Networks were trained to monitor the temperature variables, nuclear power and dose rate. Two databases were used: one with data generated by a theoretical model and another one with data to a typical week of operation of the IEA-R1 reactor. In the second stage, the neural networks used to monitor the variables was tested with a fault database. The faults were inserted artificially in the sensors signals. As the value of the maximum calibration error for special thermocouples is {+-}0,5 deg C, it had been inserted faults of {+-} 10 C in the sensors for the reading of the variables T3 and T4. In the third stage a Fuzzy System was developed to carry out the faults diagnosis, where were considered three conditions: a normal condition, a fault of {sub 1}0 C , and a fault of + 10 C . This system will indicate which thermocouple is faulty. (author)

  12. Time reduction in well construction with the addition of glass microspheres and thixotropic agents in cement slurries in zonal isolation at Solimoes Basin; Reducao do tempo de construcao de pocos de petroelo na Bacia do Solimoes atraves da utilizacao de microsferas de vidro e agentes tixotropicos nas fases de cimentacao

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Cledeilson R.L.; Duque, Luis H.; Steffan, Rodolfo H.P.; Guimaraes, Zacarias [Baker Hyghes, Houston, TX (United States); Corregio, Fabio; Augusto, Marcelo; Mendes, Sandro C. [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil)

    2012-07-01

    One of the problems faced by the oil industry during the well construction is the damage effect of the hydrostatic head of cement slurries on unconsolidated reservoirs, trending to a necessity of lightweight cementing slurries with high resistance for zonal isolation. This paper presents experiences with lightweight cementing slurries obtained by the addition of glass microspheres and thixotropic agents in oil and gas wells located at Solimoes Basin - Amazon Basin, Brazil, which led to 100% time reduction on well construction when compared with the standard cementing procedures, besides the benefit of no reservoir damage. It also includes lab tests, cement slurry designs, case histories and results that allow a complete evaluation of the technique that can be applied in other similar environments. (author)

  13. Analysis of rationality and efficiency of electricity utilization in posture poultry companies by computation platform based in fuzzy system; Analise da racionalidade e eficiencia da utilizacao de energia eletrica em empresas de avicultura de postura via plataforma computacional baseada em sistema fuzzy

    Energy Technology Data Exchange (ETDEWEB)

    Cremasco, Camila Pires [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Botucatu, SP (Brazil). Dept. de Bioestatistica; Faculdade de Tecnologia (FATEC), Presidente Prudente, SP (Brazil); Gabriel Filho, Luis Roberto Almeida [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Tupa, SP (Brazil). Fac. de Ciencias Agronomicas; Viais Neto, Daniel dos Santos; Bordin, Deyver [Faculdade de Tecnologia (FATEC), Presidente Prudente, SP (Brazil); Silva, Helenice de Oliveira Florentino [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Botucatu, SP (Brazil). Dept. de Bioestatistica], E-mails: gabrielfilho@tupa.unesp.br., dvneto@fatecpp.edu.br, bordin@yahoo.com.br, helenice@ibb.unesp.br

    2012-11-01

    A great application of intelligent systems is in control of the electric power consumption of enterprises. For the assessment of the way that the company uses the electricity there are two indices which are called load factor and power factor. To facilitate the assessment of the performance of electric power consumption by the companies it is interesting that there is a single index indicating globally as energy is being used by the same. The goal of this work was to develop a software to assist laying poultry companies in the region of Bastos in more rational and efficient use of electric energy. For this, a system has been developed called Fuzzy Energy integrated environment developed with Delphi 2010. For the determination of fuzzy factor (situation of the company), we used a fuzzy system prepared in advance. The data collected over a period of 3 years helped the system programming. The software was able to present the situation of the company studied in a manner accessible to the user, and their results were tested accuracy 100 according to fuzzy system. With the inference method of Mandani, unable to create a general simulation of all relevant points of enterprise data. (author)

  14. Utilization of the IAIA (Investigation and Analysis of Incidents and Accidents) method in the investigation of the P-36 platform accident; Utilizacao do metodo IAIA (Investigacao e Analise de Acidentes e Incidentes) na investigacao do acidente ocorrido na plataforma P-36

    Energy Technology Data Exchange (ETDEWEB)

    Teles, Marcus de Barros [ARCE - Agencia Reguladora de Servicos Publicos Delegados do Estado do Ceara, Fortaleza, CE (Brazil)

    2004-07-01

    In the beginning of XXI century the Brazilian oil industry report a big accident involving that which was the biggest petroleum platform of the world. With capacity production of 180.000 barrels a day and capacity compression of 7,2 million cubic meter a day of natural gas, the off-shore platform P-36 was situated on Roncador field, in Campos basin, operating in 1360 meters of water. As consequences, eleven deaths with irreparable traumas to the families, friends and worker partners, one billion dollars in prejudices to brazilian country, environmental damages by oil leak and injuries to PETROBRAS reputation in Brazil and in the world. The method of investigation and analysis of incidents and accidents - IAIA is very wide and its philosophy contain a lot of topics, since basic concepts, investigation actions, analysis action and diagnosis by the general kind of fail. Using this method and taking advantage from the report elaborated by the commission organized by ANP - Agencia Nacional do Petroleo and DPC - Diretoria de Portos e Costas, responsible for the investigation and analysis of the accident occurred with P-36, this paper identify the direct and indirect causes of the accident, in attempt to avoid new similar situations. (author)

  15. Use of sugar-cane bagasse ash to produce glass-ceramic material in the system Ca O-SiO{sub 2}-Na{sub 2}O; Utilizacao de cinza de bagaco de cana para produzir material vitro-ceramico do sistema SiO{sub 2}-CaO-Na{sub 2}O

    Energy Technology Data Exchange (ETDEWEB)

    Teixeira, S.R.; Santos, G.T.A.; Magalhaes, R.S., E-mail: rainho@fct.unesp.b [Universidade Estadual Paulista (DFQB/FCT/UNESP), Presidente Prudente, SP (Brazil). Fac. de Ciencias e Tecnologia. Dept. de Fisica, Quimica e Biologia; Rincon, J.Ma.; Romero, M. [Consejo Superior de Investigaciones Cientificas (IETCC/CSIC), Madri (Spain). Inst. de Ciencias de la Construccion Eduardo Torroja; Carvalho, C.L. [Universidade Estadual Paulista (FEIS/UNESP), Ilha Solteira, SP (Brazil). Faculdade de Engenharia

    2009-07-01

    A bottom ash was used as raw material to obtain glass which was crystallized to form glass-ceramic material. The characterization of the ash shows that it consists mainly of crystalline materials, predominantly quartz, with oxides of iron, potassium and aluminum as minor elements. The glass was obtained from the mixing of ash with calcium and sodium carbonates. The glass and the glass-ceramic were examined using differential thermal analysis (DTA), X-ray fluorescence (XRF), X-ray diffraction (XRD) and scanning electron microscopy (SEM). XRD and DTA data show that Wollastonita is the only crystalline phase present in the material crystallized at 1050 deg C. Part of the glass was synthesized at this temperature for one hour, resulting in a green/brown hard material glass-ceramic. The images of SEM show morphology of spherilithic growth indicating volumetric crystallization mechanism. (author)

  16. Use of rice rusk ash and spent catalyst as a source of raw material for the production and characterization of soda-lime silicate glasses destined for packaging; Utilizacao de residuos de catalisador (ECAT) e cinzas da casca de arroz (CCA) na elaboracao de vidros silicatos soda-cal destinados ao setor de embalagem

    Energy Technology Data Exchange (ETDEWEB)

    Araujo, M.S.; Martinelli, J.R.; Genova, L.A.; Prado, U.S. do, E-mail: araujo.mariaana@gmail.com [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Centro de Ciencia e Tecnologia de Materiais

    2016-07-01

    Study on the use of rice husk ash (RHA) and waste catalyst (ECAT), two industrial solid waste generated in large quantities in Brazil, getting soda-lime glass for the production of packaging. Both the waste may be classified as class II waste according to NBR 10,004. Samples were produced adding Na{sub 2}CO{sub 3} and CaO to obtain a composition within the range of commercial soda-lime glasses. The results showed that both can be used as received (without any previous treatment) replacing important raw materials, source of Al{sub 2}O{sub 3} and SiO2, necessary for glass formation. The produced samples were amber due to the presence of nickel (Ni2+ ions) from the ECAT and optical transmittance of 18%. These also showed good homogeneity, i.e., absence of bubbles and striae and dissolution rate higher than a commercial soda-lime glass. In general, the samples are presented suitable for applications that require low transmittance such as colored glass containers, which does not require perfect visibility and transparency. Finally, the waste level of incorporation was approximately 78 mass%. (author)

  17. Exploratory study on the integration of fuel cell systems inside the chloro-soda plants for utilization of industrial hydrogen; Estudo exploratorio da integracao de sistemas de celula a combustivel dentro das plantas de cloro-soda para utilizacao do hidrogenio industrial

    Energy Technology Data Exchange (ETDEWEB)

    Braga, Jose Mauro Fernandes [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Escola de Engenharia]. E-mail: jmfbraga@oi.com.br; Seidl, Peter [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil); Pirro e Longo, Waldimir [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Nwcleo de Estudos Estrategicos (NEST)

    2008-07-01

    This work aims to demonstrate the economic viability of the application of industrial hydrogen in fuel cell systems by analyzing the advantages and disadvantages of this investment in hydrochloric acid/ sodium hydroxide plants. Using the Present Liquid Value and the Real Options Theory an economic evaluation will be made of the integration of fuel cell system in these plants, based on investment cost, volatility, among other parameters. (author)

  18. Preliminary analysis of the regolithic clay covers from the region of Alfenas, Minas Gerais, Brazil, aiming to evaluate its use in the traditional ceramic industry; Analise preliminar das coberturas regoliticas argilosas da regiao de Alfenas, Minas Gerais, Brasil, visando sua utilizacao na industria de ceramica vermelha

    Energy Technology Data Exchange (ETDEWEB)

    Gaspar, Junior, L A; Varajao, A F.D.C. [Universidade Federal de Ouro Preto (UFOP), MG (Brazil). Escola de Minas. Dept. de Geologia; Moreno, M M.T. [Universidade Estadual Paulista (UNESP), Rio Claro, SP (Brazil). Dept. de Petrologia e Metalogenia

    2009-07-01

    The region of Alfenas, in the state of Minas Gerais, Brazil, is predominantly constituted of Pre-Cambrian rocks with well developed alteration profiles in association with colluvial and alluvial sediments. No study to date has examined in detail its potential use in the ceramic industry. The scarce knowledge of its mineralogical and technological properties limits its value and consequently its industrial use. Until now, these clay materials have been used in a rudimental manner, in small scale in the fabrication of red tiles. The present study aimed at analyzing these clays mineralogically (X-ray diffraction), chemically (major and minor elements by X-ray fluorescence and organic carbon analysis) and technologically (pressing granulometric distribution; mechanical resistance; water absorption, apparent porosity; linear firing shrinkage; color of firing and others) in order to better understand the raw material and develop adequate technological applications. The best results of ceramic properties were the samples with higher organic content (more plastic clays) and higher values of Al{sub 2}O{sub 3} (kaolinite and gibbsite) and Fe{sub 2}O{sub 3} as well lower SiO{sub 2} content and finer grain size which contribute to a better sintering. (author)

  19. Development of methodology for the synthesis of poly(lactic acid-co-glycolic acid) for use in the production of radioactive sources; Desenvolvimento da metodologia para sintese do poli(acido latico-co-acido glicolico) para utilizacao na producao de fontes radioativas

    Energy Technology Data Exchange (ETDEWEB)

    Peleias Junior, Fernando dos Santos; Zeituni, Carlos Alberto; Rostelato, Maria Elisa Chuery Martins; Souza, Carla Daruich de; Mattos, Fabio Rodrigues de; Moura, Eduardo Santana de; Moura, Joao Augusto; Benega, Marcos Antonio Gimenes; Feher, Anselmo; Costa, Osvaldo Luiz da; Rodrigues, Bruna Teiga, E-mail: fernandopeleias@gmail.com [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP/CTR), Sao Paulo, SP (Brazil). Centro de Tecnologia das Radiacoes; Fechine, Guilhermino Jose [Universidade Presbiteriana Mackenzie, Sao Paulo, SP (Brazil). Escola de Engenharia

    2015-05-15

    According to the World Health Organization, cancer is a leading cause of death worldwide. A radiotherapy method extensively used in prostate cancer is brachytherapy, where the area requiring treatment receives radioactive seeds. Iodine-125 seeds can be inserted loose or stranded in bioabsorbable polymers produced from poly(lactic-co-glycolic acid) (PLGA). We developed the synthesis methodology for PLGA and the results obtained show that it was possible to determine the optimal reaction parameters (time and temperature) for PLGA in 80/20 (lactide/glycolide) ratio. The yield was higher than 90% using a temperature of 110 °C and reaction time of 72 hours; however, the molecular weight values obtained are very low compared to those obtained by other authors. New tests using previously synthesized dimers and nitrogen atmosphere are being performed. These conditions could potentially increase the molar mass of PLGA. All techniques used confirmed the expected structure of the polymer. (author)

  20. Characterization of Lanthanum Ferric Cobaltite doped with Strontium (LSCF) films deposited by spray-pyrolysis for application as cathode in PaCOS-TI; Caracterizacao de filmes de CFLE depositados por spray-pirolise para utilizacao como catodo em PaCOS-TI

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, L.S.; Guimaraes, V.F.; Paes Junior, H.R. [Universidade Estadual do Norte Fluminense Darcy Ribeiro (UENF), Campos dos Goytacazes, RJ (Brazil). Lab. de Materiais Avancados], Emails: laryssadsa@yahoo.com.br, valtencyguimaraes@yahoo.com.br, herval@uenf.br

    2010-07-01

    The lanthanum ferric cobaltite doped with strontium (LSCF) is a ceramic material with the perovskite structure that stands out in the field of research for its use as cathode in solid oxide fuel cells at intermediate temperatures (IT-SOFC). The films were synthesized by spray-pyrolysis technique on 8% mol Yttria stabilized zirconia (YSZ) substrates. It was studied the influence of heat treatment temperatures (600-1000 deg C) on the properties of the films under the conditions of treatment during four hours. Samples were tested electrically by measuring the variation of electrical conductivity with temperature, structurally by X-ray diffraction (XRD) and morphologically by scanning electron microscopy (SEM). The films heat treated at 700 deg C for 4 hours showed better performance for application as cathode. (author)

  1. Thermal analysis of different application techniques on Nd:YAG laser after root canal preparation of single-rooted teeth; Analise termica de diferentes tecnicas de utilizacao do laser de Nd:YAG apos o preparo quimico-cirurgico de dentes unirradiculares

    Energy Technology Data Exchange (ETDEWEB)

    Archilla, Jose Ricardo de F

    2001-07-01

    The experiment objective is to analyze temperature variation, by means of three different application techniques of Nd:YAG laser in the root canals of singlerooted anterior teeth. Three root canals were instrumented, irrigated, X-rayed to measure the remaining dentin in the apical area and submitted to laser irradiation techniques used by Gutknecht, Matsumoto and a new technique with oscillatory movement. The used laser parameters were: pulse energy 250 mJ, frequency 5 Hz, pulse fluency 354 J/cm{sup 2}, average potency 1,25 W, pulse width 300 {mu}s, fiber core diameter 300 {mu}s and interval of thermal relaxation of 20 s. After temperature evaluation and interpretation of the obtained data, it was concluded: 1) the oscillatory technique provided a better heat distribution during the laser application, when analyzing the graphs separately; 2) all the used techniques are within a pattern of safety, analyzing the average and highest temperatures of the apical area and the middle third, even so, disrespecting the last application day and the middle third of root 'C'.(author)

  2. Characterization of sediment from the dredging of storm water channels in the city of Salvador-BA, Brazil aiming to use in structural ceramics; Caracterizacao de sedimento proveniente de dragagem de canais pluviais do municipio de Salvador-BA visando sua utilizacao em ceramica estrutural

    Energy Technology Data Exchange (ETDEWEB)

    Santos, O.C.; Breitenbach, S.B.; Coelho, R.E., E-mail: engcruz@ig.com.br, E-mail: silviabb@ifba.edu.br, E-mail: rodrigoecoelho@gmail.com [Instituto Federal de Educacao, Ciencia e Tecnologia da Bahia (IFBA), Salvador (Brazil); Andrade, J.C.S.; Sales Junior, J.C.C., E-mail: jean.engmateriais@gmail.com, E-mail: jccalado@gmail.com [Universidade Federal do Amazonas (UFAM), Manaus (Brazil). Dept. de Engenharia de Materiais; Paskocimas, C.A.; Martinelli, A.E.; Nascimento, R.M., E-mail: paskocimas@uol.com.br, E-mail: aemart@uol.com.br, E-mail: rubensmaribondo@gmail.com [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Programa de Pos-Graduacao em Ciencia e Engenharia de Materiais

    2017-01-15

    The aim of this study was to characterize sediment from the dredging of storm water channels (Scp) in the city of Salvador, Bahia, aiming its maximum replacement by clay in structural ceramics, since this binary mixture is part of the pilot project of the standard mass, in the research of interlocked block ceramic formulation. Initially, the sediment was submitted to the following tests: plasticity index; chemical analysis by X-ray fluorescence; mineralogical analysis by X-ray diffraction; thermal and particle size analyses. The morphology of the material was analyzed by scanning electron microscopy, coupled with energy dispersive spectroscopy. Then, sediment (Scp) was added to clay from the municipality of Candelas, Bahia, in the proportions of 10, 20, 30 and 40 wt%. Specimens were prepared by uniaxial pressing in dimensions of 60 mm x 20 mm, with compacting pressure of 25 MPa, and the material was humidified with 8% of water. Firing was conducted in resistive furnace at temperatures of 850, 950 and 1050 deg C, with 5 deg C / min heating rate. The properties evaluated were: linear shrinkage; water absorption and modulus of rupture. The results indicated the possibility of using SCP in structural ceramics by the prerequisites required in standards, in the manufacture of tiles, sealing blocks and bricks. (author)

  3. The possibility of recurrent selection to increase the oil content in soybeans using genetic male sterility and NMR spectroscopy; Possibilidade de selecao recorrente para aumento do teor de oleo em soja com a utilizacao da macho-esterilidade genetica e da espectroscopia de ressonancia nuclear magnetica

    Energy Technology Data Exchange (ETDEWEB)

    Miranda, M A.C. de; Teixeira, J P.F.; Mascarenhas, H A.A. [Instituto Agronomico de Campinas, SP (Brazil); Rettori, C [Universidade Estadual de Campinas, SP (Brazil). Inst. de Fisica

    1990-12-31

    The seed oil content of male sterile plants and their progenies was analysed by a NMR spectroscope to study the possibility of recurrent selection to improve the oil content. The results suggest the possibility of recurrent selection in the composite IAC-1 both in the field with male sterile plants or at the greenhouse when selection is based on average values of progenies. 30 refs., 3 figs., 3 tabs.

  4. Composite reinforced alumina ceramics with titan and lantana for use in coating storage tanks and transport of crude oil; Composito de ceramica alumina reforcada com titania e lantana para a utilizacao em revestimento de tanques de armazenamento e transporte de petroleo cru

    Energy Technology Data Exchange (ETDEWEB)

    Mendes, C.E.; Rego, S.A.B.C.; Oliveira, J.C.S.; Ferreira, R.A. Sanguinetti; Yadava, Y.P., E-mail: cata_esposito@hotmail.com [Universidade Federal de Pernambuco (UFPE), PE (Brazil). Centro de Tecnologia e Geociencia. Departamento de Engenharia Mecanica

    2011-07-01

    The objective of this work is to use ceramics to improve the performance of the tanks that store and transport crude oil and which use metallic materials for their manufacture. These tanks in contact with crude oil undergo a process of degradation on their surfaces, since crude oil is a highly corrosive substance. And in turn ceramic materials have good stability in hostile environments. However, they are inherently fragile for display little plastic deformation. Therefore, the choice of a ceramic composite alumina-titania-lantana has high mechanical strength and high toughness which were produced by thermo-mechanical processing. These composites were sintered at 1350 ° C for 36 hours, and it was held Vickers hardness testing and microstructural characterization to assess their surfaces before and after the attack by crude to use such material as ceramic coating. These results will be presented at the congress. (author)

  5. Utilization of response surface for optimization of the production of a biosurfactant with application in the removal of petroleum-derived; Utilizacao de superficie de resposta para a otimizacao da producao de um biossurfactante com aplicacao na remocao de derivado de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Sarubbo, Leonie A.; Rufino, Raquel D.; Luna, Juliana M.; Farias, Charles B.B.; Santos, Valdemir A. dos [Universidade Catolica de Pernambuco (UNICAP), Recife, PE (Brazil)

    2012-07-01

    The surfactants, amphipathic compounds capable of reducing the surface tension of aqueous media, find application in many industries, especially in the petroleum, cosmetic and food, such as dispersants, emulsifiers and surfactants. With the necessity of environmental preservation, surfactants of micro-organisms origin, in substitution of synthetic surfactants, have become very attractive, since they are biodegradable and less toxic although their production costs are still high because of the substrates used and of the purification processes involved. Considering the need to reduce costs associated with the production of microbial surfactants, a strain of bacteria of the genus Pseudomonas, isolated from the port area was cultured in medium containing low-cost agro-industrial wastes, molasses and corn steep liquor, as substrates according a central composite rotatable design (CCRD) in order to evaluate the influence of independent variables molasses and corn steep liquor concentrations on the response variable surface tension. The biosurfactant was able to reduce the water surface tension from 71 mN / m to values around 27.5 mN / m. The dispersion ability and the capacity of oil removal of the surfactant was demonstrated. The possibility of application of biosurfactants in the remediation of oil polluted environments motivates the advancement of research to develop this technology for effective use in treatment of contaminated soils and waters. (author)

  6. Topics to study the integrated use of natural gas in the electricity with industrial focus: a methodology for optimizing its use with application in the Vale do Paraiba region (SP-Brazil); Topicos para o estudo da utilizacao integrada do gas natural na eletricidade com enfoque industrial: uma metodologia para otimizacao de seu aproveitamento com aplicacao na regiao do Vale do Paraiba

    Energy Technology Data Exchange (ETDEWEB)

    Paro, Andre C.; Borelli, Samuel J.S. [PROMON Engenharia SA, Sao Paulo, SP (Brazil); Santos, Edmilson M. [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Eletrotecnica e Energia; Fadigas, Eliane A. [Universidade de Sao Paulo (USP), SP (Brazil). Escola Politecnica

    2004-07-01

    After the recent announcement on the discovery of a large amount of Natural Gas (NG) in the Santos Field by PETROBRAS, use incentive policies for its consumption and consequent growth participation in the national energy matrix gained strength This paper intends to present an efficient use optimization methodology for the NG integrated to Electricity with focus on it's industrial use under the concepts of Integrated Resources Planning (IRP). Thus, the topics about NG utilization in cogeneration plants are analyzed, showing it's utilization on Electric Energy (EE) and Process Heat (Steam) supply. Its contribution to the distributed Electric Energy generation, which brings the installed generation power closer to the consumer centers and mitigates energy transmission losses, are also presented. The IRP concept is applied on the integration between industrial use and other uses of NG and on the detailing of its influence on the electric sector. Finally, a case study is presented, applying the presented methodology for the use of NG in the industry of 'Vale do Paraiba' Region (SP-Brazil), due to its industrial economy condition and easy access to the Brazilian proved reserves geographic condition. (author)

  7. Use of phyllosilicates in electrochemical devices: possible use of sepiolite as a support of catalysts in direct alcohol fuel cells (DAFC); Utilizacao de filosilicatos em dispositivos eletroquimicos: possivel uso da sepiolita como suporte de catalisadores em celulas a combustivel com uso direto de etanol (DAFC)

    Energy Technology Data Exchange (ETDEWEB)

    Parra-Silva, J.; Silva, A.C.; Mello-Castanho, S.R.H. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Cerpa, A. [Universidad Europea de Madrid, Madrid (Spain)

    2014-07-01

    Direct alcohol Fuel cells (DAFC) are interesting to use Brazil for reasons of fuel logistics and availability. The catalysts used in these devices to promote the oxidation of alcohol at the anode need to be fixed on a substrate which must provide high specific surface area, porosity, chemical and thermal resistance, this target can be achieved with the characteristics sepiolite. This paper proposes sepiolite as catalyst support for DAFC. Sepiolite is a phyllosilicate with double layered tetrahedral silicon cells and fibrillar structure. Catalysts (Pt / Sb / Sn) were prepared by cation substitution method and tested by cyclic voltammetry. Techniques as XRD and FT-IR were also used for characterizing materials. Was obtained up to 35 mA / g (Pt) peak current (redox ethanol) indicating the possibility of sepiolite technology development to use un proposed purpose. (author)

  8. Using the model release ARTM associated with resources for simulation geoprocessing radiological environmental impact of atmospheric emissions from a research reactor; Utilizacao do modelo de dispersao ARTM associado a recursos de geoprocessamento para simulacao do impacto ambiental radiologico de emissoes atmosfericas de um reator de pesquisa

    Energy Technology Data Exchange (ETDEWEB)

    Alves, Simone Fonseca

    2013-08-01

    The knowledge of the dispersion of radionuclides emissions into the atmosphere arising from a nuclear reactor, in normal operation, is an important step in the process of the nuclear and environmental assessment study. These processes require an assessment study of the radiological environmental impact. However, to estimate this impact a simulation of the transport mechanisms and deposition of pollutants released into the atmosphere is required. The present study aimed at the application of the dispersion model ARTM (Atmospheric Radionuclide Transport Model), together with the powerful tools of the GIS (Geographic Information System) for the environmental impact assessment of a radiological nuclear reactor under typically routine and conditions. Therefore some important information from the national project for a research reactor known as Brazilian Multipurpose Reactor (RMB) was considered. The information of the atmospheric emissions of the reactor, needed for the simulation of this project, was based on data of the Open Pool Australian Light Water (OPAL).Other important data that had to be collected and analyzed were the source term, the topography, the meteorology and the environmental data. The radionuclides analyzed as pollutants were {sup 41}Ar; {sup 140}Ba; {sup 51}Cr; {sup 137}Cs; {sup 131}I; {sup 133}I; {sup 85m} Kr; {sup 87}Kr; {sup 88}Kr; {sup 140}La; {sup 133}Xe; {sup 135}Xe; {sup 3}H; {sup 90}Sr. The model was run for two chronological scenarios according to their meteorological data for the years 2009 and 2010, respectively. The adoption of GIS techniques was relevant in planning, data preprocessing and in the post-processing of results as well. After pre-processing, the input data were processed by the ARTM dispersion model. Maps, charts, and tables were then produced and evaluated. According to the simulated and evaluated scenarios it could be concluded that exposure pathways that mostly contributed to the dose for individual public were {sup 41}Ar, for immersion in the plume, and {sup 133}I, for inhalation. Nevertheless, even these pathways were much below the limits established by the current standards. (author)

  9. Use of thin layer chromatography for the determination of radiochemical purity of radiopharmaceuticals in nuclear medicine services of Paraiba and Rio Grande do Norte, Brazil; Utilizacao da cromatografia em camada delgada para determinacao da pureza radioquimica de radiofarmacos em servicos de medicina nuclear da Paraiba e Rio Grande do Norte, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, W.G.; Santos, P.A.L.; Lima, F.R.A. [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Programa de Pos-Graduacao em Tecnologia Energetica; Lima, F.F., E-mail: wellington.gandrade@gmail.com [Centro Regional de Ciencias Nucleares do Nordeste (CRCN-NE/CNEN-PE), Recife, PE (Brazil)

    2012-07-01

    The paper chromatography and the thin layer chromatography are separation techniques in which the radioactive components migrate because of their affinity with the eluent (mobile phase) or stationary phase, respectively. In radiopharmaceuticals labeled with {sup 99m}Tc, besides its own radiopharmaceutical, {sup 99m}TcO{sup 4-} free and TcO{sub 2} can be identified and quantified. The evaluation of radiochemical purity of radiopharmaceuticals is essential to produce images free of artifacts as well as avoid unnecessary absorbed dose to the patient. Once they are managed in humans it is important and necessary that they undergo to strict quality control. Because of this, ANVISA in its 'Resolucao da Diretoria Colegiada (RDC) 38 of June 4th, 2008 states the obligation of performing a minimum of tests in nuclear medicine services routine prior to human administration. This work evaluated, by the method of thin layer chromatography (TLC), radiochemical purity, determined the pH of the radiopharmaceutical DEXTRAN- 500, DMSA, DTPA, PHYTATE, MDP, MIBI and Sn-Col used in nuclear medicine services in the states of Paraiba and Rio Grande do Norte - Brazil. The results show that the use of thin layer chromatography (TLC) as a standard method in routine of nuclear medicine services is possible, because it provides important data for the evaluation of radiochemical purity, allowing the exclusion of a radiopharmaceutical poorly marked. (author)

  10. Optimization of a data acquisition and control system for calibration of X rays detectors with usage of computational tools; Otimizacao de um sistema de controle e aquisicao de dados para calibracao de medidores de radiacao X com utilizacao de ferramentas computacionais

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, Yklys Santos

    2013-07-01

    The Brazilian standard ABNT ISO/IEC 17025/2005 specifies general requirements for the competence of testing and calibration facilities. One of these requirements states that these facilities must always optimize their processes and thus, uncertainties must be estimated and lowered as much as possible. In order to achieve such goal, the Laboratorio de Calibracao de Instrumentos (LCI), a laboratory responsible for dosimeter calibration at the Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN) have acquired some equipment for the LCI's X-Ray calibration system, such as a rotating filter holder, and it has also been developing software in order to provide the best calibration results with lowest external interferences (from the operator, for instance) to diminish the possibilities of error occurrences. A semi-automated LabVIEW-based calibration software has been developed at LCI and it has been subjected to constant testing and improvements so far. The software is divided in two basic modules: one is responsible for calibration of the monitor chamber with a reference standard dosimeter, while the other is used to perform instruments calibrations using the monitor chamber as reference. Several influence quantities have been analyzed and the proper corrections have been added to the software as multiplicative correction factors. The software is not only able to acquire data from all the equipment used in the laboratory, but also it is able to calculate calibration factors and its uncertainties. A later analysis shows how this system has optimized the whole calibration process, lowering the occupational dose, reducing the mean time of calibration, uncertainties and preventing errors caused by the system's users. (author)

  11. Utilization of radiometric method in evaluation of wear on human dental enamel in vitro by dental porcelain glazed and polished; Utilizacao do metodo radiometrico na avaliacao in vitro do desgaste provocado ao esmalte dental humano por porcelanas dentais glazeadas e polidas

    Energy Technology Data Exchange (ETDEWEB)

    Adachi, Lena Katekawa; Campos, Tomie Nakakuki de; Adachi, Eduardo Makoto [Sao Paulo Univ., SP (Brazil). Faculdade de Odontologia. Dept. de Protese]. E-mail: katekawa@usp.br; Saiki, Mitiko [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)]. E-mail: mitiko@curiango.ipen.br

    2005-07-01

    The dental porcelain is a material commonly used in prosthesis. Disadvantages of dental porcelain use include possibility to cause tooth or dental materials wear. Before its use in the mouth, surfaces are treated with polishing and/or glazing. This research used the radiometric method to verify the influence of these surface treatments on the porcelains of commercial brands: Ceramco II, Noritake and Finesse. This method was originally developed for dentifrice abrasiveness evaluation. Five specimens of dental enamel and 10 specimens of each porcelain (5 glazed, 5 polished) were used. The dental enamel was flattened and irradiated with neutrons from the IEA-R1 (IPEN/CNEN) nuclear reactor. Then it was weared by each porcelain in sliding motion, with water. After 2,500 cycles for each porcelain specimen, the released enamel residue was measured. The enamel wear was evaluated by measuring beta activity of {sup 32}P transferred to water from the irradiated tooth. Results varied from 2.57 to 5.81 {mu}g of enamel /mm{sup 2} weared surface. There was no statistical difference ({alpha}=0.05) between dental enamel wear caused by the same porcelains glazed or polished. The results suggest that adequate surface finishing depend on the type of dental porcelain. (author)

  12. Determination of the average residence time in an anaerobic digester of Barueri wastewater treatment by using radioactive tracer, Sao Paulo State, Brazil; Determinacao de tempo de residencia medio - TRM - em um digestor anaerobio da Estacao de Tratamento de Esgotos de Barueri com utilizacao de tracador radioativo

    Energy Technology Data Exchange (ETDEWEB)

    Helou, Luiz Carlos; Vitoreti, Cristiane da Silva; Moraes, Fabio Alceu Akiyama de [Companhia de Saneamento Basico do Estado de Sao Paulo (SABESP), Barueri, SP (Brazil). Unidade de Negocios de Tratamento de Esgotos; Aoki, Pedro Eiti; Silva, Valdir Cosmos da [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)

    2002-07-01

    Gas production in the Barueri Wastewater Treatment Plant digesters shows lower values than projected. This fact conducted to the hypothesis that there could be dead zones caused by homogenization deficiencies. In order to verify this hypothesis a full scale essay was conducted with Iodine - 131 as tracer. A Mutual Cooperation Agreement was signed between the Sao Paulo Basic Sanitation Company (SABESP) and the Nuclear and Energetic Research Institute (IPEN) to conduct these essays. The results showed that the active volume was almost 88% of the nominal capacity. (author)

  13. Alteration in the absorption cell dose arising from the use of gold nanoparticle associated with the radionuclides of clinical application: simulate study; Alteracao na absorcao de dose celular decorrente da utilizacao de nanoparticulas de ouro associadas a radionuclideos de aplicacao clinica: estudo simulado

    Energy Technology Data Exchange (ETDEWEB)

    Culik, Lucas; Schwarcke, Marcelo, E-mail: mschwarcke@unifra.br [Centro Universitario Franciscano (UNIFRA), Santa Maria, RS (Brazil)

    2015-12-15

    The present work is a proposal to assess, which is the efficiency in the use of radionuclides of clinical application in nuclear medicine service conjugated system with gold nanoparticles.To obtain the results needed for the interpretation of this combination, was using the Monte Carlo simulation code PENELOPE, where was the main structures of a simulated eukaryote cell. To simulate irradiation on cellular structures was used the emission spectrum of main radionuclide clinical use in nuclear medicine service. The material containing gold nanoparticles was modeled according the stoichiometric proportions found in the literature. The results obtained, present for the simulated energies to smaller bodies than 2,0μm, no substantial response to the use of nanoparticles in the reinforcement of locally absorbed dose. Is observed a small decrease in locally dose absorbed due to emission of charged particles, it is believed that causes an increase in the emission secondary range to be placed outside the study body. But this effect is small when comparing to the increase of energy absorbed due to interaction with the bodies containing nanoparticles, so demonstrating an increase in the locally dose absorbed. Being observed that there is an increase in dose absorbed locally due to the use of nanoparticles. For protocols based on the principle of target radionuclide therapy, the imaging of the treaty sit will be affected in their statistical accuracy, since the gamma radiation will be attenuated by the nanoparticles present in the material. Being necessary to know if this increase in the locally absorbed dose has greater importance in the treatment protocol than the image of the absorption of the radioactive material in the target organ. (author)

  14. X-ray cone beam microtomography for quantitative assessment of tracheal and pharyngeal volumes of Rhodnius prolixus; Utilizacao da microtomografia computadorizada com feixe de raios-X conico para a determinacao quantitativa do volume da traqueia e faringe do Rhodnius prolixus

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Izabella Soares de

    2017-07-01

    In the past decade microcomputerized tomography imaging using synchrotron radiation has become a powerful technique to generate high resolution images of Rhodinus prolixus. Images of soft tissues (protocerebrum and muscles) and dense structures (pharynx, trachea and esophagus) of R. prolixus head have been obtained using synchrotron radiation microtomography in mono and polychromatic configuration, respectively. Advancements in conventional microtomography have increased the achievable resolution and contrast, making this relatively inexpensive and widely available technology potentially useful for studies of insect internal morphology. The main goal of this work was to provide a new set of high quality microtomographic images of R. prolixus achieved by means of a desktop X-ray microtomograph. It allows the three-dimensional visualization of important chitinized structures: pharynx and tracheae. Pharyngeal and tracheal volumes were quantitatively evaluated at different days (1, 4, 10, 15 and 20) after feeding. The results suggest that variation of average volumes could be attributed to insect hormone 20-hydroxy-ecdysone (20-OH-Ec) pulse at 11 days after feeding. Pharyngeal volumes decrease 3.80 times. On the other hand, tracheal volumes increase 1.78 times. Head total volume showed similar trends than trachea. (author)

  15. Study of the rice husk ash utilization as filler polypropylene matrix and ionization radiation effect on this composite; Estudos da utilizacao da cinza de casca de arroz como carga em matriz de polipropileno e do efeito da radiacao ionizante sobre este composito

    Energy Technology Data Exchange (ETDEWEB)

    Alfaro, Eduardo de Faria

    2010-07-01

    In the first step of this work, it was evaluated the possibility of using rice husk ash as a filler in polypropylene (PP) making a comparison with talc which is the most used mineral filler in polymers. This comparison was made by using polypropylene with 20% rice husk ash as well as polypropylene with 20% talc measuring their properties. Despite the properties of the PP with 20% rice husk ash decreased compared with the composite of polypropylene with 20% talc it can be said that the rice husk ash can be used as filler for or other utilization less noble of PP . This way it is being given a destination for this residue that it is disposable in the environment contributing to its preservation, moreover reducing the product cost. This work had also as an aim to study the ionizing radiation effect in the properties of these composites. It was used the coupling agent, maleic anhydride , to verify a best sample homogenization. According to the results it can be said that PP is a semicrystalline polymer, and so it has its morphology modified when exposed to the irradiation process. This fact is due to the scission mechanisms of the polymeric chains which it is in compliance to the literature. (author)

  16. Titanium dioxide use (TiO{sub 2}) in cement matrix as a photocatalyst of nitrogen oxides (NO{sub x}); Utilizacao de dioxido de titanio (TiO{sub 2}) em matriz cimenticia como fotocatalisador de oxidos de nitrogenio (NO{sub x})

    Energy Technology Data Exchange (ETDEWEB)

    Casagrande, C.A.; Hotza, D.; Repette, W.L.; Jochem, L.F., E-mail: cezar.acasa@gmail.com [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil)

    2012-07-01

    The use of titanium dioxide (TiO{sub 2}) in the photodegradation of nitrogen oxides (NO{sub x}) is a technology that can contribute against to environmental pollution. This work shows the feasibility of using TiO{sub 2} in mortars for photocatalysis. The Degussa P25 titania were characterized chemically and physically, revealing that the sample consists of nanoparticles, but has become crowded. Tests Samples (TS) were manufactured with added titania and the NO{sub x} tests at 28, 60 and 120 days of age of TSs, showing that it was 3% capable of degrading 100% of the NO{sub x} gas flow. Proved that conditions like relative humidity, flow and radiation intensity are relevant when it comes to efficiency in photocatalysis, altering the efficiency by varying these conditions. The photocatalysis with titania in cement matrix was efficient in NO{sub x} degradation, presenting itself as a promising technique to control environmental pollution.

  17. Development of methodology for the synthesis of poly(lactic acid-co-glycolic acid) for use in the production of radioactive sources; Desenvolvimento da metodologia para sintese do poli(acido latico-co-acido glicolico) para utilizacao na producao de fontes radioativas

    Energy Technology Data Exchange (ETDEWEB)

    Peleias Junior, Fernando dos Santos

    2013-07-01

    According to World Health Organization (WHO), cancer is a leading cause of death worldwide. Prostate cancer is the second most common cancer in men. A method of radiotherapy which has been extensively used is brachytherapy, where radioactive seeds are placed inside the area requiring treatment. Iodine-125 seeds can be placed loose or stranded in bioabsorbable polymers. Stranded seeds show some advantages, since they reduce the rate of seed migration, an event that could affect the dosimetry of the prostate and cause unnecessary damage to healthy tissues or organs. For Iodine-125 stranded seeds, polyglactin 910 (poly(lactic-co-glycolic acid)) (PLGA), with a coverage of polyglactin 370 (Vicryl Registered-Sign ) is used. It was purposed in this dissertation, the study and development of the synthesis methodology for PLGA via ring-opening polymerization, as well as its characterization, with the objective of using the synthesized material to manufacture a material similar to RAPID Strand{sub Registered-Sign }. The results obtained show that it was possible to determine the optimal reaction parameters (time and temperature) for PLGA in 80/20 (lactide/glycolide) ratio. Using a temperature of 110 Degree-Sign C and reaction time of 24h, a yield of 86% was obtained, and increasing the reaction time to 72 hours, the yield was higher than 90%. The molecular mass values obtained from the samples are still very low compared to those obtained by other authors in the literature (about 20%). Failures in the sealing of vials, leaving them vulnerable to moisture and oxygen, or lack of an efficient stirring system might be possible explanations for these results. A suitable chemical reactor could solve the problem. Regarding polymer characterization, all techniques used not only confirmed the expected structure of the polymer, but also showed the highest proportion of lactide units compared to to glycolide units. (author)

  18. Supervisory utilization as a support information instrument of the data base acquisition and availability by Intranet and Internet natural gas micro-cogeneration; Utilizacao de um supervisorio como ferramenta de suporte de informacoes na aquisicao e disponibilizacao dos dados via Intranet e Internet de um sistema de micro-cogeracao de energia

    Energy Technology Data Exchange (ETDEWEB)

    Camara, Paulo; Sousa, Walter [Centro de Tecnologias do Gas (CTGAS), Natal, RN (Brazil); Petch, Moacir; Diogenes, Pedro; Carrasco, Benjamim [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

    2008-07-01

    The globalization effects intensify the information of technology's usage, not only on the creation of new products and processes, as well, support to operation of new equipment. The Information Technology turns to being more penetrating in the companies' activities, making and changing paradigms and, consequently, in the way how information is conceived. In the partnership PETROBRAS, the Centro de Tecnologias do Gas - CTGAS and the group FOCKINK, was developed and has been launched in the brazilian market the first system of generation and micro-cogeneration by natural gas, activated by an engine diesel derivative by natural gas. The prototype is able to make 35 kW/55 kVA of electric energy, 7TR's (84.000 BTU's) of energy for refrigeration and has a capacity of warming 2200 l / h of water in the temperature of 25 deg C until 85 deg C. The equipment utilizes as a monitoring system a supervisor Elipse Scada, produced by Elipse, which is composed by acquisition and monitoring tools that turns possible the creation of screens with graphics to make easier the support, monitoring, activating and variable control, just like: pressure, temperature, electrical and mechanical. The supervisor keeps in touch with (02) two computers: the first, makes the communication with the supervisor system and the other is used to select the information to be able by web, through CTGAS home page. The access by home page of the information about the data on the co-generator will make easier the client's decision for the acquisition of the equipment. The main objective of this work is, through Information Technology is to present an application case of Elipse Scada Software in micro-cogeneration system installed at CTGAS to turn easier the obtainment of this information, change the relations into an integrate changing, expanding frontiers, creating by this way new challenges. (author)

  19. Electrolytic hydrogen production at off-peak consumption and his utilization as energy vector at peak consumption through use of fuel cells; Producao de hidrogenio eletrolitico nos horarios fora de ponta e sua utilizacao como vetor energetico nos horarios de ponta atraves do uso de celulas a combustivel

    Energy Technology Data Exchange (ETDEWEB)

    Gambetta, Francielle [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Faculdade de Engenharia Mecanica. Dept. de Energia]. E-mail: fgambetta@fem.unicamp.br; Silva, Ennio Peres da [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Inst. de Fisica. Lab. de Hidrogenio

    2008-07-01

    Due the fact that consumers have different demand, depending on the pace of economic activities and their daily habits of consumption, there is a different electrical demand throughout the day. Demand, in general, is minimal during the morning and it grows with the move for hours to reach peak consumption between 18:00 and 22:00, then turning to fall. It is old the idea of storing electricity produced in off-peak for its consumption in peak hours. To store large amounts of electrical power is required its conversion into some other form of energy, since it is impossible to store electrical energy as such in large quantities. One way of storing electricity is in the form of hydrogen produced by electrolysis of water which then can be stored, purified and converted into electricity through fuel cells. When there is an increase in demand for electricity, there is a need to expand the supply of energy, which means investments in generation, transmission and distribution. This work was performed a preliminary analysis of the production of electrolytic hydrogen in hours of low demand and its use in the generation of electricity in peak hours, making use of the fuel cells, so that to a certain limit value of increased electricity demand, there is no need for expansion of supply of Foz do Iguacu/PR. Moreover, at this work, the ability to harness the heat generated in fuel cells for heating water in homes was considered. (author)

  20. Pedagogia etnomatemática: uma proposta para o ensino de matemática na educação básica

    Directory of Open Access Journals (Sweden)

    Francisco de Assis Bandeira

    2012-08-01

    Full Text Available As reflexoes apresentadas neste artigo sao parte de uma proposta de reorientacao curricular em educacao matematica que defende a utilizacao do conhecimento matematico vivenciado pelo aluno em sua comunidade como subsidio metodologico para o processo de ensino-aprendizagem da matematica escolar. Mas, a luz das concepcoes d.ambrosianas de Etnomatematica, principalmente, a educacional, que procura compreender a realidade sociocultural e chegar a acao pedagogica de maneira natural mediante um enfoque cognitivo com forte fundamentacao cultural. Para a concretizacao dessa proposta no campo educacional, busquei fundamentos legais, dentre os quais, os Parametros Curriculares Nacionais, que propoem ser apenas um documento de referencia para que as escolas organizem suas propostas curriculares. Nesse sentido, associei os blocos de conteudos dos Parametros Curriculares Nacionais do Ensino Fundamental da Matematica aos conhecimentos matematicos de uma comunidade de horticultores da Grande Natal/RN.

  1. Atlas digital: uma contribuicao para o sistema de informacoes do municipio de Sao Joao de Meriti – RJ

    Directory of Open Access Journals (Sweden)

    Ricardo Araujo Mathias

    2011-07-01

    Full Text Available Um Atlas Digital é um atlas que pode ser acessado atraves de um computador, sendo possivel a utilizacao de uma variada gama de temas, formatos e escalas. Neste trabalho apresenta-se um prototipo de Atlas Digital como colaboracao ao Sistema de Informacao Municipal – SIM, para o municipio de Sao João de Meriti, RJ. O SIM tem como meta os servicos municipais, sendo as suas informacoes fundamentais para a melhoria da gestao das prefeituras. A pesquisa foi direcionada para o tema da habitabilidade, que consiste num conjunto de condicoes voltadas para a criacao de um habitat saudavel, conseguinte foram trabalhados os subtemas: infraestrutura de abastecimento de agua, esgoto, coleta de lixo, saude e educacao.

  2. Synthesis and characterization of the perovskite Sm{sub 0.5}Sr{sub 0.5}CoO{sub 3} for using as cathode in solid oxide fuel cells; Sintese e caracterizacao da provsquita Sm{sub 0.5}Sr{sub 0.5}CoO{sub 3} para utilizacao como catodo em celulas a combustivel de oxido solido

    Energy Technology Data Exchange (ETDEWEB)

    Blanco, P.H.L.; Muccillo, R.; Muccillo, E.N.S. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)], e-mail: enavarro@usp.br

    2008-07-01

    Solid oxide fuel cells are basically constituted by ceramic materials, a solid electrolyte sandwiched between two electrodes. A number of ceramic materials with perovskite structure have been proposed to act as electrode material due to the combination of their physical and chemical properties along with compatibility with the solid electrolyte. In this work the mixed oxide Sm{sub 0,5}Sr{sub 0,5}CoO{sub 3} was synthesized by the cation complexation technique. This perovskite oxide has been proposed as cathode in solid oxide fuel cells that operates in the intermediate temperature range ({approx} 500 to {approx} 700 deg C). Citric acid was used as complexant agent. The thermal decomposition of the precursor material occurs in several stages up to 600 deg C. After calcinations at 700 deg C the mixed oxide exhibits the characteristic perovskite phase of Sm{sub 0,5} Sr{sub 0,5}CoO{sub 3} the microstructure of the thermally decomposed material consists of porous agglomerates. This technique allowed for obtaining a single phase material at a relatively lower temperature. (author)

  3. Utilisation of gamma radiation of Cobalt-60 as quarantine treatment of medicinal plant, aromatic and seasoning plants dehydrated infested by Lasioderma serricorne (Fabricius, 1792) (Coleoptera, Anobiidae) and Plodia interpunctella (Hubner, 1813) (Lepidoptera, Pyralidae); Utilizacao da radiacao gama do Cobalto-60 como tratamento quarentenario de plantas medicinais, aromaticas e condimentares desidratadas infestadas por Lasioderma serricorne (Fabricius, 1792) (Coleoptera, Anobiidae) e Plodia interpunctella (Hubner, 1813) (Lepidoptera, Pyralidae)

    Energy Technology Data Exchange (ETDEWEB)

    Alves, Juliana Nazare

    2007-07-01

    The research had as objective the use of the gamma radiation of the Cobalto-60 as quarantine treatment of the medicinal plant, aromatic and seasoning plants dehydrated infested by Lasioderma serricorne and Plodia interpunctella determining the disinfestation doses to attend the criterion in the not emergency of adults of the species in study and analysing through the Chromatography of Thin Layer the effect of the gamma radiation of the cobalto-60 on the active principle of extract dehydrated of Chamomilla recutita, Pimpinella anisum, Origanum vulgare, Cymbopogon citratus, Ocimum basilicum and Thymus vulgaris. The work was developed in the Laboratorio de Inseticidas in the Instituto Biologico in Sao Paulo in the period of August of 2005 the June of 2007. The radiation source used gamma was an experimental irradiator of Cobalto-60, model Gamacell 220, located in the Instituto de Pesquisas Energeticas e Nucleares - IPEN, located in Sao Paulo. In the period of 30 days after the irradiation of the samples evaluated the number of adults emerged of Lasioderma serricorne and Plodia interpunctella, using the data of mortality for the analysis of Probit. Obtained 100% of not emergency of adults in the Lasioderma serricorne with the dose of 2,00 kGy and 100% of not emergency of adults in the Plodia interpunctella with the dose of 2,25 kGy. The Chromatographic Analysis of Thin Layer was to evaluate did not show chemical differences in the extracts analysed. (author)

  4. Perspective of using the sterile insect technique for Tobacco Budworms Heliothis virescens (Lepidoptera: Noctuidae) and Cotton Bollworm Helicoverpa armigera (Lepidoptera: Noctuidae) in cotton crop as an alternative method of control; Perspectiva de utilizacao da Tecnica do Inseto Esteril para lagarta da maca Heliothis virescens (Lepidoptera: Noctuidae) e lagarta do velho mundo Helicoverpa armigera (Lepidoptera: Noctuidae) na cultura do algodoeiro como um metodo alternativo de controle

    Energy Technology Data Exchange (ETDEWEB)

    Haddad, Gianni Queiroz

    2017-07-01

    Since the 1950s, scientists have used ionizing radiation to sterilize insects, which are released in nature to mate, but without any progeny. Known as the sterile insect technique (TIE), this method of insect control has traditionally used ionizing radiation to sterilize insects, a technique that does not generate residues, and can act in synergy with the other techniques within integrated pest management. For several years, Brazil has been fighting against the increase of pests, introducing new tactics and techniques within the IPM programs, to overcome the resistance of chemical products, such as: reducing the residues of agrochemicals; For some important crops of our country, we have a wide spectrum of pests occurring from the beginning to the end of the harvest, one of them is the cotton crop and among the key pests of this crop, we have some extremely important caterpillars, among them Heliothis virescens and Helicoverpa armigera These species are morphologically similar, the second being identified a few years ago in Brazil. There are still no studies in Brazil using TIE as an additional tool for Lepidoptera, therefore the purpose of this study was to evaluate the effect of doses of gamma radiation in the different phases of the evolutionary cycle of Heliothis virescens and Helicoverpa armigera, as well as to evaluate the sterility in generation P And the ability of insects to irradiate with non-irradiated insects. The pupal phase presented the best result because 75 Gy achieved sterility in Heliothis virecens and 100 Gy sterilized Helicoverpa armigera, therefore it contemplated the phase and dose chosen to evaluate the competition between the irradiated insects and the normal insects of both species. Both Heliothis virecens and Helicoverpa armigera presented a satisfactory result, as the irradiated insects managed to significantly reduce the viability of the eggs in a ratio of 9: 1: 1. (author)

  5. The environmental licensing processes of the offshore oil and natural gas exploration and production in the world and in Brazil: a comparative analysis considering the utilization of studies of the strategic environmental assessment; O processo de licenciamento ambiental das atividades de exploracao e producao de petroleo e gas natural offshore no mundo e no Brasil: uma analise comparativa considerando a utilizacao de estudos de avaliacao ambiental estrategica

    Energy Technology Data Exchange (ETDEWEB)

    Mariano, Jacqueline [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE). Programa de Planejamento Energetico

    2004-07-01

    This study presents an analyses of the environmental licensing processes of the offshore oil and gas exploration and production of the following countries: USA, UK, Norway, Australia and Canada, and makes a comparison with the Brazilian case. This study also emphasizes the use of the Strategical Environmental Assessments (SEA) before the bid procedures. The SEA studies aim to predict and to evaluate the environmental implications of the adoption of sectorial policies and programs and are very useful to the decision making processes. They permit the exclusion of environmental sensitive areas and contribute to the improvement of the environmental management of the regions where the activities will take place. The selected countries use SEA as an environmental management tool and their experience is analysed so as to provide suggestions for the improvement of the current Brazilian environmental licensing process. (author)

  6. Hexa pyranoside homologation: use of spectral width narrowing, and the chemical shift homonuclear correlation for characterization of the 4,6-0-benzylidene-2,3-di des oxy-3-C-hydroxymethyl-{alpha}-D-methyl ribopyranoside; Homologacao de hexopiranosideos: utilizacao de reducao da largura espectral e de correlacao homonuclear de deslocamentos quimicos para a caracterizacao do 4,6-O-benzilideno-2,3-didesoxi-3-C-hidroximetil-{alpha}-D- ribopiranosideo de metila (7)

    Energy Technology Data Exchange (ETDEWEB)

    Souza Filho, J D; Silva, L.G. Fonseca e; Oliveira, A Braga de; Alves, R Jose [Minas Gerais Univ., Belo Horizonte, MG (Brazil); Lukacs, G [Centre National de la Recherche Scientifique (CNRS), 91 - Gif-sur-Yvette (France). Inst. de Chimie des Substances Naturelles

    1992-12-31

    The discovery of ramified sugars as various antibiotics constituents, leads to the development of various preparation technologies. In the framework of hexapiranose analogues synthesis, the alcohol-7 was the intermediary on which functional group interconversion reactions were performed. The carbonyl group reduction with Na B H{sub 4} in MeOH{sup 5} was performed, for obtaining the ethyl alcohol-6 a (99%). Later on, the reaction of stereoselective reduction of the double binding between C-2 and C-3 was conducted in presence of Ni-Ra in Ac O Et, allowing to obtain the two epimer 7 and 7 a alcohols, with 86.9 and 7.5% yield respectively. The 7 {sup 1} H NMR signals were easily assigned by analysing the extended spectrum obtained by narrowing the spectral line. In accordance with predictable multiplicity and H-6{alpha} (Triplet at 3.7 ppm) patterns, the triple doublet H-5, at 4.1 ppm has been assigned. The assignments were confirmed by a chemical shift homonuclear correlation experiment (COSY H-H). H-7, H-7{sup `} and H-4 have been assigned through the H-3. The use of hydroxyl proton as reference (d d, 2.72 ppm) allowed the confirmation of the chemical shift assigned to H-7 and H-7{sup `} 5 refs., 6 figs.

  7. Use of gamma radiations as a quarternary process to control the orange fruit borer, Ecdytolopha aurantiana (Lima, 1927) (Lepidoptera, Tortricidae) on orange fruits (Citrus sinensis), variety 'pera' and observations on its effects on fruits quality; Utilizacao da radiacao gama como um processo quarentenario para o 'bicho furao' Ecdytolopha aurantiana (Lima, 1927) (Lepidoptera, Tortricidae) em laranja pera (Citrus sinensis), e o estudo dos seus efeitos sobre a qualidade dos frutos

    Energy Technology Data Exchange (ETDEWEB)

    Faria, Jose Tadeu de

    1997-07-01

    The objective of the present research was to determine if gamma radiations could be used as a quarentenary process against the orange fruit borer, Ecdytolopha aurantiana (Lima, 1927), infesting oranges of the variety 'Pera', beyond observations on some fruit quality parameters. To observe the gamma radiations effects on the insects, doses ranging from the control to 800 Gy were used, and to observe possible effects on fruits quality, the utilized doses ranges from the control to 500 Gy. To observe the gamma radiations effects on the insects, doses ranging from the control to 800 Gy were used, and to observe possible effects on fruits quality, the utilized doses ranged from the control to 500 Gy. It was observed that over 200 Gy avoid emergency of viable adults of the orange fruit borer. Only one single female, and even these with wing malformations, emerged at the dose of 300 Gy. Dose up to 500 Gy did not interfere on fruits weight loss nor on the period of conservation of the oranges. Acidity, Brix value and skin resistance against perforation also did not showed any changes due to radiations. The irradiation of green fruit induced into a smaller loss of weight than when the fruits were irradiated in the mature stage. (author)

  8. Development of a geographical data base and its utilization in elaboration of maps of environmental sensitivity to the oil spill in the coastal area between Galinhos and Sao Bento do Norte, RN (Brazil); Desenvolvimento de um banco de dados geograficos e sua utilizacao na elaboracao de mapas de sensibilidade ambiental ao derramamento de oleo na area costeira entre Galinhos e Sao Bento do Norte - RN

    Energy Technology Data Exchange (ETDEWEB)

    Castro, Angelica Felix de; Amaro, Venerando Eustaquio; Vital, Helenice; Aloise, Dario Jose [Rio Grande do Norte Univ., Natal, RN (Brazil). Programa de Recursos Humanos da ANP para o Setor Petroleo e Gas, PRH-22. Formacao em Geologia, Geofisica e Informatica

    2003-07-01

    The coastal areas located in the northern coast of the Rio Grande do Norte State, specifically between the districts of Galinhos e Sao Bento do Norte, characterized by constant processes of coastal and eolic transport, causing erosion, alterations in the sediments and modifications in the coast line. Beyond of those natural factors, there is the proximity to Polo Petrolifero of Guamare, the largest terrestrial producer of petroleum of Brazil. The first part of that work consisted of to elaborate and to develop a Geographical Database (BDG), to store all the existent data of the study area, such as geological and geophysical data, hydrodynamic data, products of remote sensing, thematic maps, among others. The second stage of this work aimed to develop starting from the data previously stored in BDG, Oil-Spill Environmental Sensitivity Maps (Maps SAO). Those maps evaluate the reaction of the certain place if to happen an oil spill in her, supplying necessary information to the decision in cleaning and removal of the spilled oil. In that way, Maps SAO of the study area were elaborated in different teams to evaluate if there would be change of the behavior of the coast in the presence of the oil. (author)

  9. Le costruzioni percettive-letterarie del corpo: verso una psicobiologia letteraria del Sé di Alfonso Santarpia.

    OpenAIRE

    Santarpia, Alfonso

    2014-01-01

    International audience; Il visuale organico sembra promettere di svelare i segreti di quando pensiamo, di quando lottiamo, di quando amiamo e perché no, si saprà a breve anche quale area funzionale dell'encefalo si accen-derà o si spegnerà nell'attesa della morte. Plurime cartografie della nostra cognizione si svelano agli occhi degli scienziati (Damasio, 1995, 1999). Ma se un paziente fortemente ansioso vi racconta : ho gli occhi stanchi, lo stomaco mi brucia, il mio cervello ruota veloce co...

  10. Distribuição do dextran-99mTc e do carvão ativado no linfonodo-sentinela em coelho = Distribution of dextran-99mTc and activated carbon in sentinel lymph nodes of rabbits

    Directory of Open Access Journals (Sweden)

    Rocha, Rogério Porto da

    2006-01-01

    Conclusões: A solução de CA (6% e corante vital (azul patente V na proporção 1: 1 determinou uma fácil identificação do LS no intra-operatório. A análise comparativa da distribuição do CA e do dextran-99mTc demonstra que ambos se comportaram da mesma forma concentrando-se na mesma metade do LS

  11. Efeito da luz e da temperatura de congelamento sobre a estabilidade das antocianinas da pitanga roxa The effects of light and freezing temperature upon the stability of purple surinam cherry's anthocyanins

    Directory of Open Access Journals (Sweden)

    Vera Lúcia Arroxelas G. de Lima

    2005-03-01

    Full Text Available As antocianinas são corantes naturais que podem ser utilizadas como alternativa em substituição aos corantes sintéticos. Entretanto, a baixa estabilidade destes compostos é o principal fator que dificulta sua aplicação como corante em alimentos. Frente à escassez de estudo sobre o pigmentos antociânicos da pitanga roxa, este trabalho teve como propósito avaliar a sua estabilidade à luz e ao congelamento. Utilizando a leitura de absorbância do extrato antociânico submetido às condições experimentais foi evidenciado que a luz reduziu o seu tempo de meia-vida, enquanto que a temperatura de congelamento exerceu pequeno efeito na degradação dos pigmentos.Anthocyanins are natural colorants that can be used as alternative to synthetic dyes. However, the low stability of these compounds is the main drawback in their application as food colorants. Since the information on anthocyanin pigments in Surinam cherry is scarce, the purpose of this investigation was to assess their stability to light and freezing storage. The anthocyanin extract absorbance, under the experimental conditions, showed that light incidence reduced the half-life of anthocyanin extract; meanwhile the freezing storage had little effect on these pigments degradation.

  12. Using compound SiO{sub 2}(62-68)-MgO+CaO(29-39) in the protections of ceramics of steel company to replace the CaO-Al{sub 2}O{sub 3}-SiO{sub 2} compound; Utilizacao do composto SiO{sub 2}(62-68)-MgO+CaO(29-39) nas protecoes ceramicas de empresa siderurgica em substituicao ao composto CaO-Al{sub 2}O{sub 3}-SiO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Nogueira, Anderson Carvalho; Silva, Paula Cipriano da; Vernilli Junior, Fernando; Santos, Claudinei dos; Magnago, Roberto de Oliveira [Centro Universitario de Volta Redonda (UNIFOA), Volta Redonda, RJ (Brazil); Lima, Leonardo Moreira de [Universidade de Sao Paulo (USP), Lorena, SP (Brazil)

    2014-12-15

    This article describes the use of protective ceramic composed of SiO{sub 2}(62-68)-MgO + CaO(29-39) in the frontal region of the machines that inject mass refractory to stop racing pig iron and slag liquid in blast furnaces. The new protection model (prototype) showed a annual saving of approximately R$ 32,000.00 compared to the compound previously used CaO-Al{sub 2}O{sub 3}-SiO{sub 2}. Also had a lower toxicity, as it has in its morphology least amount of fiber. These fibers when inhaled cause damage to internal tissues of the lungs is harmful to health. There maintenance rates of production, since in all samples tested the new ceramic protection, the front part was preserved allowing the refractory mass injection quantity and pressure required for reconstitution of the length of the bore which removes iron and slag inside the high oven, allowing for a larger internal volume to produce more. The protection models were produced by Morganite-Brazil. The morphology and crystallographic characterization were characterized by Scanning Electron Microscopy and X-ray diffraction, respectively. (author)

  13. Homologation of hexopyranosides: use of differential Overhauser nuclear effect, and homo- and heteronuclear correlations of chemical shift for characterization of the 1,6-anhydro-4-O-benzoyl-2,3-didesoky-3-C-trifluoroacetamidomethyl-{beta}-D-m = ethyl ribopyranoside (16a); Homologacao de hexopiranosideos: utilizacao de efeito nuclear overhauser diferencial e de correlacoes homo e heteronuclear de deslocamentos quimicos para a caracterizacao do 1,6-anidro-4-O-benzoil-2,3-didesoxi-3-C- trifluoroacetamidometil-{beta}-D-ribo piranosideo de metila (16a)

    Energy Technology Data Exchange (ETDEWEB)

    Souza Filho, J D; Silva, L.G. Fonseca e; Oliveira, A Braga de; Alves, R Jose [Minas Gerais Univ., Belo Horizonte, MG (Brazil); Lukacs, G [Centre National de la Recherche Scientifique (CNRS), 91 - Gif-sur-Yvette (France). Inst. de Chimie des Substances Naturelles

    1992-12-31

    The discovery of ramified sugars as various antibiotics constituents, leads to the development of various preparation technologies. In the framework of hexa pyranose analogues synthesis, the 1,6-anhydride -16a was one of the byproducts obtained in the attempt of bromide -16 derivative transformation in the iodate -6-1 derivative. The bromide -16 derivative was treated with 2 equivalents of Bu{sub 4} N I during 24 hours, acetonitrile reflux. 3 parts of 2 Bu{sub 4} N I equivalents were added each 24 hours. A unique pure substance was obtained from the formed products mixture, which the structural determination was proposed in accordance with: 1) disappearing of the C-13 signal and the two protons from the anomeric methoxy group, and 2) registering of the molecular ion with m/z 359D, corresponding to the loss of 94D (Br + C H{sub 3}), from the -16 (M{sup +}., m/z 453D). The 1,6-anhydride -16a structure was confirmed by experiments on homo- and heteronuclear correlations of chemical shifts (COSY H-H and COSY C-H), and by spectroscopy using the differential Overhauser nuclear effect. The spectrum obtained by C-H correlation identified the singlet at 5.65 ppm as due to the H-1 ([C-1 x H-1]) 2 refs., 6 figs.

  14. Development of lithium disilicate based glass-ceramics =

    Science.gov (United States)

    Fernandes, Hugo Alexandre Goncalves da Rocha

    O principal objectivo deste estudo foi o desenvolvimento de vitroceramicos a base de dissilicato de litio no sistema Li2O-K2O-Al2O3-SiO2 contendo uma razao molar SiO2/Li2O muito afastada da do dissilicato de litio (Li2Si2O5) usando composicoes simples e a tecnica tradicional de fusao-vazamento de vidro de forma a obter materiais com propriedades mecanicas, termicas, quimicas e electricas superiores que permitam a utilizacao destes materiais em diversas aplicacoes funcionais. Investigou-se o fenomeno de separacao de fases, a cristalizacao e as relacoes estrutura-propriedades de vidros nos sistemas Li2O-SiO2, Li2O-Al2O3-SiO2 e Li2O-K2O-Al2O3-SiO2. Os vidros nos sistemas Li2O-SiO2 e Li2O-Al2O3-SiO2 apresentaram fraca densificacao e resultaram em materiais frageis, contrastando com a boa sinterizacao dos vidros no sistema Li2O-K2O-Al2O3-SiO2. Pequenas adicoes de Al2O3 e K2O ao sistema Li2O-SiO2 permitiram controlar a separacao de fases devido a formacao de especies de Al(IV) que confirmaram o papel de Al2O3 como formador de rede. Os compactos de po de vidro das composicoes contendo Al2O3 e K2O tratados termicamente resultaram em vitroceramicos bem densificados, apresentando dissilicato de litio como a principal fase cristalina, e valores de resistencia mecanica a flexao, resistencia quimica e condutividade electrica (173-224 MPa, 25-50 mg/cm2 e 2´10-18 S/cm, respectivamente) que possibilitam a utilizacao destes materiais em diversas aplicacoes funcionais. A adicao de P2O5, TiO2 e ZrO2 ao sistema Li2O-K2O-Al2O3-SiO2 como agentes nucleantes revelou que os vidros contendo apresentaram cristalizacao em volume, com a formacao de metassilicato de litio a temperaturas mais baixas e dissilicato de litio para as temperaturas mais elevadas, enquanto a adicao de zirconia reduz o grau de segregacao, aumenta a polimerizacao da matriz vitrea e desloca o valor de Tg para temperaturas superiores, inibindo a cristalizacao.

  15. Remoção de cor de efluentes têxteis com cogumelos Agaricus bispora - doi: 10.4025/actascitechnol.v32i3.6339

    Directory of Open Access Journals (Sweden)

    Renata Lopes Landeira Silva

    2010-11-01

    Full Text Available O emprego direto de cogumelos Agaricus bispora foi avaliado para a remoção de cor de uma mistura sintética de corantes reativos. Avaliou-se o efeito da granulometria das partículas (cubos de 0,5 ou 1,0 cm e cogumelos moídos, da massa de cogumelos (10, 20, 40, 60 ou 80 g em 250 mL de solução e de diferentes formas de tratamento do cogumelo sobre a remoção de cor de uma solução sintética dos corantes Reactive Yellow 37, Reactive Black 5 e Reactive Red na concentração de 13,3 mg L-1 cada corante. Os melhores resultados foram obtidos para maiores áreas superficiais de contato do cogumelo (cogumelo moído com o efluente colorido e sob aeração contínua. A adição de acetona durante o processo de moagem, seguido de congelamento, contribuiu para o aumento da remoção de cor, obtendo-se os melhores resultados: 73% após 6h, com 20 g de biocatalisador 250 mL-1 de efluente. A utilização de diferentes lotes e marcas de cogumelo levou à obtenção de diferentes atividades enzimáticas, mas percentuais similares de remoção de cor, indicando que a remoção de cor não possui relação direta com a atividade enzimática.

  16. Teor de vitamina C e características físicas do camu-camu em dois estádios de maturação

    OpenAIRE

    Sousa, Rita de Cássia Pereira de

    2011-01-01

    O Camu-Camu é uma das frutas amazônicas que está merecendo atenção pelos teores de vitamina C e sua introdução recente nos mercados mundiais. Desperta interesse de setores industriais como fármaco, cosmético, conservante natural, alimentício e da casca extrai-se corante natural (antocianinas). Considerando a importância do camu-camu como alimento, da vitamina C na dieta humana, realizou-se o presente trabalho com o objetivo de determinar o teor de vitamina C em frutos de camu-camu colhidos em...

  17. Técnica de eletroflotação aplicada na remoção de cores de efluentes têxteis

    OpenAIRE

    Ricardo Augusto Camboim

    2010-01-01

    Resumo: Com o aumento da preocupação do homem com o meio ambiente, as indústrias passaram a se preocupar mais com o descarte de seus efluentes, com isso, vem sendo desenvolvidas técnicas para tratamento de efluentes. No presente trabalho utiliza-se a técnica de eletroflotação, para o tratamento de efluente de tinturaria de tecidos, a qual utiliza corantes reativos. Para tal montou-se um reator composto por: Uma cuba com capacidade para 50 litros, uma fonte de tensão com potencia ajustável e e...

  18. A cor dos têxteis Andinos: análise da cor em têxteis da cultura milenar de Paracas

    OpenAIRE

    Rodrigues, Isa Santos

    2008-01-01

    Dissertação apresentada na Faculdade de Ciências e Tecnologia da Universidade Nova de Lisboa para obtenção do grau de Mestre em Conservação e Restauro Área de Têxteis O presente trabalho insere-se num projecto denominado “The color of the Andean Textiles”, que resulta de uma colaboração entre a Faculdade de Ciência e Tecnologia, da Universidade Nova de Lisboa (FCT-UNL) e o Museum of Fine Arts (MFA), de Boston. Os corantes dos têxteis da cultura de Paracas, que se desenvolveu na costa Sul d...

  19. Evaluation of the physical-chemical and biological treatment of residue from dyes produced at a microbiology laboratory - DOI: 10.4025/actascitechnol.v32i1.7545

    OpenAIRE

    Nozu, Lenice Leiko; UTFPR; Saldanha, Patrícia Cavalcanti de Albuquerque; Soares, Marlene; Barbosa, Valma Martins; Machado, Alessandro Feitosa; Silva, Edilsa Rosa; UTFPR - Curitiba

    2009-01-01

    Os diferentes resíduos produzidos pelo homem em diversas áreas representam grave problema ambiental, quando inadequadamente descartados. No presente trabalho, foram realizados experimentos de degradação de resíduos de corantes gerados no Laboratório de Microbiologia da Universidade Tecnológica Federal do Paraná, Campus Curitiba, por meio do cultivo líquido implementado com Pleurotus sajor-caju e processo oxidativo avançado (POA – Sistema UV/H2O2). A verificação da eficiência desses processos ...

  20. Avaliação in vitro da microinfiltração em cavidades classe II de molares decíduos, restaurados com resina composta auto e fotopolimerizável

    OpenAIRE

    CAVALCANTI Alessandro Leite; CHELOTTI Adolpho

    1999-01-01

    Estudou-se a microinfiltração marginal presente na interface da parede gengival de cavidades classe II em molares decíduos, restaurados com resina composta (auto e fotopolimerizável), através da penetração de uma solução corante. Os preparos cavitários apresentavam a parede gengival em esmalte e foram restaurados segundo 4 diferentes técnicas: 1) resina composta fotopolimerizável; 2) resina composta autopolimerizável; 3) resina composta auto e fotopolimerizável; e 4) ionômero de vidro/resina ...

  1. Extração de acido carminico e analise por cromatografia liquida de alta eficiencia

    OpenAIRE

    Paulo Roberto Nogueira Carvalho

    1996-01-01

    Resumo: A preocupação dos consumidores com o uso de substâncias artificiais em alimentos tem aumentado muito nos últimos anos e feito com que os fabricantes procurem substitutos para os corantes artificiais ainda utilizados. O carmim de cochonilha, nome dado ao complexo de alumínio e cálcio do ácido carmínico (ácido 7- b - D - glicopiranosil - 9, 10 - diidro - 3, 5, 6, 8 - tetraidroxil - 1 - metil - 9, 10 - dioxo - 2 - antracenocarboxílico), extraído das fêmeas da cochonilha (Dactylopius cocc...

  2. Degradação de xenobióticos por fungos filamentosos isolados de areia fenólica

    OpenAIRE

    J. H. Silva; R. T. R. Monteiro

    2000-01-01

    Microrganismos foram isolados de areia fenólica resultante de atividades metalúrgicas, utilizando meio mínimo para fungos e pentaclorofenol (PCF) como única fonte de carbono. Após quatro repiques sucessivos em intervalos de 15 dias de incubação, as culturas foram plaqueadas em meio de Martin. Três gêneros de fungos foram isolados e identificados como Acremonium sp., Paecilomyces sp. e Penicillium sp. Estes foram testados para degradar os corantes índigo e RBBR (Azul Brilhante de Remazol - R) ...

  3. Análise da transferência de calor de fluidos térmicos aditivado com etilenoglicol e polímeros

    OpenAIRE

    Santana, Rony Oliveira de

    2016-01-01

    Um sistema de arrefecimento é usado para manter a temperatura ideal de funcionamento e evitar sobreaquecimento, através de um fluido térmico também chamado fluido de arrefecimento e um trocador de calor. Os fluidos de arrefecimento são normalmente compostos por uma solução de água e um aditivo, além de aditivos inibidores de corrosão e corantes. O etilenoglicol é um tipo de álcool amplamente utilizado como aditivo por ser totalmente solúvel, com baixa ou nenhuma atividade corrosiva e quimicam...

  4. Restoration of contaminated soils; Restauracion de suelos contaminados

    Energy Technology Data Exchange (ETDEWEB)

    Miranda J, Jose Eduardo

    2009-07-01

    A great variety of techniques are used for the restoration of contaminated soils. The contamination is present by both organic and inorganic pollutants. Environmental conditions and soil characteristics should take into account in order to implement a remedial technique. The bioremediation technologies are showed as help to remove a variety of soil contaminants. (author) [Spanish] Una gran variedad de tecnicas son utilizadas para la restauracion de suelos contaminados. La contaminacion se presenta tanto por contaminantes organicos como inorganicos. Las condiciones ambientales y caracteristicas del suelo se deben de tomar en cuenta para poder implementar una tecnica remediadora. Las tecnologias de biorremediacion son mostradas como ayuda para remover una gran variedad de contaminantes del suelo. (autor)

  5. Novel organic solvent-tolerant esterase isolated by metagenomics: insights into the lipase/esterase classification Nueva esterasa tolerante a los solventes orgánicos aislada por metagenómica: ideas sobre la clasificación de las esterasas/lipasas

    Directory of Open Access Journals (Sweden)

    Renaud Berlemont

    2013-03-01

    Full Text Available In order to isolate novel organic solvent-tolerant (OST lipases, a metagenomic library was built using DNA derived from a temperate forest soil sample. A two-step activity-based screening allowed the isolation of a lipolytic clone active in the presence of organic solvents. Sequencing of the plasmid pRBest recovered from the positive clone revealed the presence of a putative lipase/esterase encoding gene. The deduced amino acid sequence (RBest1 contains the conserved lipolytic enzyme signature and is related to the previously described OST lipase from Lysinibacillus sphaericus 205y, which is the sole studied prokaryotic enzyme belonging to the 4.4 a/ß hydrolase subgroup (abH04.04. Both in vivo and in vitro studies of the substrate specificity of RBest1, using triacylglycerols or nitrophenyl-esters, respectively, revealed that the enzyme is highly specific for butyrate (C4 compounds, behaving as an esterase rather than a lipase. The RBest1 esterase was purified and biochemically characterized. The optimal esterase activity was observed at pH 6.5 and at temperatures ranging from 38 to 45 °C. Enzymatic activity, determined by hydrolysis of p-nitrophenyl esters, was found to be affected by the presence of different miscible and non-miscible organic solvents, and salts. Noteworthy, RBest1 remains significantly active at high ionic strength. These findings suggest that RBest1 possesses the ability of OST enzymes to molecular adaptation in the presence of organic compounds and resistance of halophilic proteins.Con el fin de aislar nuevas variantes de lipasas tolerantes a solventes organicos (OST, se construyo una libreria metagenomica a partir de ADN obtenido de una muestra de suelo de bosque templado. A traves de un monitoreo en dos etapas, basado en la deteccion de actividades, se aislo un clon con actividad lipolitica en presencia de solventes organicos. La secuenciacion del plasmido pRBest recuperado del clon positivo revelo la presencia de un

  6. Phytoplanktonic composition of three cultivation systems used in Litopenaeus vannamei (BOONE, 1931 marine shrimp farms = Composição fitoplanctônica em três sistemas de cultivo do camarão marinho Litopenaeus vannamei (BOONE, 1931

    Directory of Open Access Journals (Sweden)

    Michelle Pereira Melo

    2010-07-01

    Full Text Available The aim of this work is to assess the different compositions of phytoplankton in three cultivation systems of marine shrimps Litopenaeus vannamei (BOONE, 1931, denominated as organic, intensive and semi intensive. The samples were done fortnightly, when phytoplankton was collected by a net for phytoplankton, 65 ƒÊm mesh, being then filtrated in a total volume of water of 100 L, and preserved in formaldehyde solution at 4% and identified according to the methodology of Cordeiro et al. (1997. The results show that the densities of Diatoms were of 16.65, 10.47 and 7.57 cel. 103 mL-1 for the organic, intensive and semi intensive cultivations, respectively. As for cyanobacteria, the average figures were 42.06 cel. 103 mL-1 forsemi intensive 17.27 cel. 103 mL-1, in the intensive cultivation and 6.11 cel. 103 mL-1 for the organic cultivation system. The dinoflagellates had the highest cellular density in the phytoplankton community analyzed with 61.9 cel. 103 mL-1 in the intensive cultivation, 0.33 and 0.03 cel. 103 mL-1 for both semi intensive and organic cultivation systems respectively. Euglenas presented the results of 4.98 and 14.86 cel. 103 mL-1 only for semi intensive and intensive cultivations. It was then concluded that all cultivations presented average rates below recommended for such studied systems.Conduziu-se esse trabalho com o objetivo de avaliar as diferentes composicoes fitoplanctonicas em tres sistemas de cultivo para o camarao marinho Litopenaeus vannamei (BOONE, 1931, denominados de organico, intensivo e semiintensivo. As amostragens foram realizadas quinzenalmente, onde o fitoplancton foi coletado atraves de uma rede de plancton, com malha de 65 ƒÊm, sendo filtrado um volume de agua total de 100 litros, que foram preservadas em solucao de formol a 4% e identificadas segundo a metodologia de Cordeiro et al. (1997. Os resultados mostram que as densidades de diatomaceas foram de 16,65; 10,47 e 7,57 cel. 103 mL-1, respectivamente

  7. Synthesis and evaluation of Pt-alloys supported on MWCNTS as ethylene glycol-tolerant ORR cathodes

    Energy Technology Data Exchange (ETDEWEB)

    Morales-Acosta, D.; Arriaga, L.G. [Centro de Investigacion y Desarrollo Tecnologico en Electroquimica, Pedro Escobedo, Queretaro (Mexico); Alvarez-Contreras, L. [Centro de Investigacion en Materiales Avanzados S. C., Chihuahua, Chihuahua (Mexico); Fraire Luna, S.; Rodriguez Varela, F.J. [Cinvestav, Unidad Saltillo, Ramos Arizpe, Coahuila (Mexico)]. E-mail: javier.varela@cinvestav.edu.mx

    2009-09-15

    In this work, a Pt-Co/MWCNT alloy (atomic ratio 70:30) was synthesized and evaluated as oxygen reduction reaction (ORR) cathode for Direct Ethylene Glycol Fuel Cells (DEGFC) applications. The alloy showed good performance for the ORR in acid medium, while in the presence of 0.125M EG (C{sub 2}H{sub 6}O{sub 2}) the MWCNTs-supported electrocatalyst showed a very high selectivity for the cathodic reaction and a high degree of tolerance to the organic fuel, i.e., a very small shift in the onset potential for the ORR, Eonset, and no peak current densities associated to the oxidation of EG, a detrimental effect of organic fuels normally observed in the case of Pt-alone electrocatalysts. [Spanish] En este trabajo, se sintetizo y evaluo una aleacion Pt-Co/NTCMP (razon atomica 70/30) como catodo de reaccion de reduccion de oxigeno (RRO) para aplicaciones de celdas de combustible de glicol de etileno directo (CCGED). La aleacion mostro buen desempeno para la RRO en medio acido, en tanto que la presencia de 0.125M de GE (C{sub 2}H{sub 6}O{sub 2}) del electrocatalizador soportado por NTCMP mostro una muy alta selectividad para la reaccion catodica y un alto grado de tolerancia al combustible organico, es decir, un corrimiento muy pequeno del potencial de inicio para la RRO, Einicio, y no densidades de corriente asociadas a la oxidacion del GE, efecto perjudicial de los combustibles organicos que se observa en el caso del electrocatalizadores solo de Pt.

  8. Determinação de ferro (III em produtos farmacêuticos por titulação fotométrica = Determination of iron (III in pharmaceutical products by photometric titration

    Directory of Open Access Journals (Sweden)

    Airton Vicente Pereira

    2011-01-01

    Full Text Available Este trabalho descreve a montagem de um sistema de titulacao fotometrica simples e de baixo custo para a determinacao de ferro (III em produtos farmaceuticos. O sistema de titulacao fotometrica foi construido utilizando-se a bomba peristaltica de um espectrofotometro convencional. O procedimento e baseado na titulacao de ferro (III com EDTA e acido salicilico como indicador. A absorcao do complexo ferro (III-acido salicilico foi monitorada espectrofotometricamente em 525 nm. O limite de quantificacao foi de 5 ƒÝg de ferro (III. O procedimento de titulacao fotometrica foi aplicado para a determinacao de ferro (III em amostras contendo sulfato ferroso e hidroxido ferrico polimaltosado. O procedimento mostrou sensibilidade, reprodutibilidade e precisao para a utilizacao em analise rotineira de ferro (III em produtos farmaceuticos.This paper describes a simple, precise and low-cost photometrictitration method for iron (III determination in pharmaceutical preparations. The photometric titration system was constructed using the peristaltic pump of a conventional spectrophotometer. The method is based on titration of iron (III with EDTA using salicylic acid as indicator. The absorption of the iron (III-salicylic acid complex wasmonitored spectrophotometrically at 525 nm. The limit of quantification was 5 ƒÝg of iron (III. The photometric titration procedure was applied for the determination of iron (III in samples of ferrous sulfate and ferric hydroxide polymaltose complex. The procedure showed sensibility, reproducibility and accuracy for use as a method for the routine analysis of iron (III in pharmaceutical formulations.

  9. Determination of integrated neutron flux by the measurement of the isotopic ratios of cadmium and gadolinium

    International Nuclear Information System (INIS)

    Tomiyoshi, Irene Akemy

    1982-01-01

    In this work, the possibility of the indirect determination of the integrated neutron flux, through the change of isotopic ratios of cadmium and gadolinium was investigated. The samples of cadmium we/e gadolinium were irradiated in the IEA-Rl reactor. These elements were chosen because they have high thermal neutron absorption cross section which permit the change in the isotopic composition during a short irradiation time to be measured accurately. The isotopic ratios were measured with a thermionic mass spectrometer the silica-gel technique and arrangement with single filament were used for the cadmium analysis, where as the oxi - reduction technique and arrangement with double filaments were used for gadolinium analysis. The mass fractionation effects for cadmium and gadolinium were corrected respectively by the exponential and potential expansion of the isotopic fractionation factor per atomic mass unit. The flux values supplied by the Centro de Operacao e Utilizacao do Reator de Pesquisas do IPEN were extrapolated. These values and the integrated flux values obtained experimentally were compared. (author)

  10. Biossorção de azul de metileno utilizando resíduos agroindustriais

    Directory of Open Access Journals (Sweden)

    Andressa C. Honorato

    2015-07-01

    Full Text Available O presente trabalho avaliou a capacidade de adsorção do corante azul de metileno nos resíduos da palha de milho e da bainha do palmito pupunha in natura. A caracterização dos resíduos foi determinada utilizando-se a microscopia eletrônica de varredura e espectroscopia na região do infravermelho a qual indicou a presença de grupos carboxílicos, hidroxila e carbonila. O tempo necessário para que o sistema atingisse o equilíbrio para ambos os resíduos foi de 240 min, seguindo uma cinética descrita pelo modelo de pseudo-segunda ordem. A capacidade máxima de adsorção foi de 102,8 mg g-1 para o resíduo da palha de milho, seguindo o modelo de isoterma de Langmuir e 50,9 mg g-1 para o resíduo de palmito pupunha, sendo que o modelo que melhor se ajusta foi Freundlich. Desta forma, esses resíduos são promissores para a adsorção do corante azul de metileno em efluentes.

  11. EXTRAÇÃO DO SUMO DA BETA VULGARIS COMO ALTERNATIVA SUSTENTÁVEL NA PRODUÇÃO DE TINTAS

    Directory of Open Access Journals (Sweden)

    Gabriela Camila Ribeiro

    2017-04-01

    Full Text Available O trabalho apresenta a extração do sumo da beterraba a partir de um método simples ao mais complexo, sendo utilizado apenas a pigmentação arrocheada para a fabricação de tinta natural, sem corantes para que não deteriore o material. Teremos a infusão da beterraba, deixando que aconteça naturalmente por minutos, dias ou semanas, para que possamos obter um pigmento completamente natural, utilizando também um aparelho, cujo nome é soxhlet, tendo a propriedade de extrair o sumo de lipídios em apenas algumas horas, dependendo do tamanho que seja o lipídio utilizado. Após a pigmentação fez necessário a adição de um aglutinante com objetivo de formar uma liga. Tento como resultado uma tinta sem corantes e não prejudicial ao meio ambiente.

  12. Improved method for lifetime measurements; Methode perfectionnee de mesure de la duree de vie; Usovershenstvovannyj metod izmereniya vremeni zhizni; Metodo perfeccionado para medir la vida media de los estados de excitacion

    Energy Technology Data Exchange (ETDEWEB)

    Weinzierl, P; Bartl, W [Oesterreichische Studiengesellschaft fuer Atomenergie, Seibersdorf (Austria)

    1962-04-15

    (Tl). Pour assurer une grande liberte de disposition geometrique entre les deux scintillateurs, on mesure l'energie gamma apres avoir additionne les amplitudes des impulsions issues de l'un et l'autre detecteur. La precision de fonctionnement du dispositif additionneur est obtenue en faisant d'abord passer les impulsions provenant du cristal organique dans un conditionneur qui ne s'ouvre que s'il y a coincidence entre les deux scintillateurs. Le spectre des impulsions fourni par le dispositif additionneur est transmis a un selecteur a un seul canal pour selection de l'energie gamma. Les rayons gamma (I) sont detectes dans un autre cristal organique. Les impulsions rapides issues des deux scintillateurs organiques sont appliquees a un convertisseur temps-amplitude et a un selecteur multicanaux. Ce selecteur est declenche par coincidence differee entre les discriminateurs d'amplitude des impulsions. (author) [Spanish] Las mediciones de la vida media de los estados excitados de los nucleos se basan en general en la medicion del retardo de un rayo {gamma} (II) respecto de otro rayo {gamma} (I) o de una particula {beta}. Los contadores de centelleo organicos dan el mejor tiempo de resolucion para dicha medida; pero cuando se presentan esquemas complejos de desintegracion, la identificacion de la energia y es importante y la mejor manera de lograrla es mediante detectores de Nal(TI). Para combinar las ventajas de ambos detectores, el rayo {gamma} (II) se hace incidir primeramente sobre un cristal organico (estilbeno) y el quantum de dispersion se detecta en un cristal de Nal(TI). Con el objeto de permitir grandes angulos de admision entre los dos detectores, la medicion de la energia {gamma} se efectua despues de sumar las alturas de los impulsos correspondientes de ambos detectores. Para asegurar el funcionamiento correcto del dispositivo sumador, los impulsos provenientes del cristal organico se hacen pasar primeramente por un circuito de puerta, accionado por cada coincidencia

  13. Influence of soil management practices and substrate availability on microbial biomass and its activities in some haplic luvisols

    Energy Technology Data Exchange (ETDEWEB)

    Friedel, Jurgen K [University Hohenheeim, Stuttgart (Germany)

    1996-07-01

    barbecho y con los sistemas de monocultivo. La razon principal de estas diferencias es un abastecimiento mas grande con residuos de cosecha y raices en los sistemas de rotacion de cultivos, que conduce a un mayor sustrato disponible para microorganismos. Los objetivos del estudio presente fueron describir los indices del sustrato disponible para microorganismos en suelos ara bles, dependiendo de las practicas de manejo de suelos, y relacionarlos con la biomasa y la actividad microbianas. En dos localidades (Muttergarten e Ihinger Hof, cerca de la Universidad de Hohenheim, Stuttgart, sudoeste de Alemania) fueron medidos los contenidos de trifosfato de adenosina y la actividad microbiana en Luvisoles haplicos. Como indices del sustrato disponible para microorganismos fueron determinados los compuestos organicos de carbon soluble en agua y se calculo la ateria organica de suelos jovenes susceptible a descomponerse en los fertilizantes organicos y en los residuos de cosecha y de raices, usando funciones de descomposicion empiricas. Los contenidos mas altos de ATP y las actividades microbianas mas altas fueron observados con la fertilizacion organica (abono liquido de ganado), antes que con la fertilizacion mineral. La labranza somera con un cultivador rotatorio condujo a valores mas altos de la propiedades microbianas en la parte superior del horizonte Ap que con la labranza con arado. Los parametros microbianos del suelo fueron mas altos en parcelas bajo una rotacion de cultivos de colza-cereales, en comparacion con una rotacion de cultivos de legumbres-cereales. La biomasa microbiana y sus actividades estuvieron relacionadas mas estrechamente a materia organica de suelos jovenes susceptible a descomponerse que al contenido de humus o a cualquiera otra propiedad del suelo. Los compuestos organicos de carbon soluble en agua no demostraron ser un indicador del sustrato disponible para microorganismos.

  14. Preparation and characterization of novel nanocomposites of inorganic/polysaccharide type =

    Science.gov (United States)

    Oliveira, Fabiane Costa

    O uso de polimeros naturais no ambito da preparacao de nanocompositos nao tem sido tao amplamente estudado quando comparado com os polimeros sinteticos. Assim, esta tese tem como objectivo estudar metodologias para a preparacao de novos materiais nanocompositos sob a forma de dispersoes e filmes utilizando polissacarideos como matriz. A tese esta dividida em cinco capitulos sendo o ultimo capitulo dedicado as conclusoes gerais e a sugestoes para trabalhos futuros. Inicialmente e apresentada uma breve revisao bibliografica sobre os principais temas colocando esta tese em contexto. Consideracoes sobre o uso de polimeros naturais e a sua combinacao com a utilizacao de nanoparticulas inorganicas para a fabricacao de novos bionanocomposites sao descritas e os objectivos e outline da tese sao tambem apresentados. No segundo capitulo, a preparacao de particulas de silica puras ou modificadas bem como a sua caracterizacao por FTIR, SEM, TEM, TGA, DLS (tamanho e potencial zeta) e medicoes de angulo de contacto sao discutidas. De modo a melhorar a compatibilidade da silica com os polissacarideos, as particulas SiO2 foram modificados com dois compostos do tipo organosilano: 3- metacril-oxipropil-trimetoxissilano (MPS) e 3-aminopropil-trimetoxissilano (APS). As particulas SiO2 MPS foram posteriormente encapsuladas com de poli(metacrilato de glicidilo) utilizando a tecnica de polimerizacao em emulsao. A utilizacao dos nanocompositos resultantes na preparacao de dispersoes de bionanocompositos nao foi bem sucedida e por esse motivo nao os estudos nao foram prosseguidos. O uso de SiO2 APS na preparacao de dispersoes bionanocomposite foi eficiente. No terceiro capitulo e apresentada uma revisao sobre dispersoes bionanocompositas e respectiva caracterizacao destacando aspectos fundamentais sobre reologia e microestrutura. Em seguida, e discutido o estudo sistematico realizado sobre o comportamento reologico de dispersoes de SiO2 utilizando tres polissacarideos distintos no que

  15. Using the same CIDR up to three times for estrus synchronization and artificial insemination in dairy goats = Uso do mesmo CIDR por até três vezes para sincronização do estro e inseminação artificial de cabras leiteiras

    Directory of Open Access Journals (Sweden)

    Daniel Maia Nogueira

    2011-07-01

    Full Text Available The objective of this study was to evaluate the effectiveness of reusing a controlled internal drug release (CIDR device for up to three times in the reproductive performance of dairy goats raised in the semi-arid zone of northeastern Brazil. Forty-five goats were allocated into three hormone treatments, as follows: CIDR1x, treated with new CIDR during nine days. Two days prior to device removal, injections of 75 ƒÝg d-cloprostenol and 300 IU equine chorionic gonadotropin (eCG were administrated. For the other treatments, thesame hormone protocol was used, differing only by the use of the same CIDR for a second time in CIDR2x and for a third time in CIDR3x. The interval from device removal to the onset of estrus (13.3 „b 1.1h vs. 13.8 „b 2.6h vs. 13.3 „b 1.4h, as well as estrus duration (33.6 „b 7.3h vs. 29.6 „b 3.2h vs. 32.8 „b 4.5h, did not differ (p > 0.05 among groups CIDR1x, CIDR2x and CIDR3x, respectively. All synchronized females were found to be in estrus. The overall fertility and prolificacy after artificial insemination were 82.2% and 1.9 kids, respectively, without significant difference (p > 0.05 among treatments. The use of the same CIDR for up to three times waseffective using 9-day estrus synchronization protocols in dairy goats.Objetivou-se avaliar o efeito da utilizacao do mesmo dispositivo de liberacao controlada de drogas (CIDR por ate tres vezes sobre odesempenho reprodutivo de cabras leiterias exploradas no semiarido do Nordeste Brasileiro. Foram utilizadas 45 cabras divididas em tres tratamentos de sincronizacao do estro, sendo: CIDR1x, tratadas com CIDR novo durante nove dias. Dois dias antes da retirada do dispositivo, foram aplicados 75 ƒÝg de d-cloprostenol e 300 UI de gonadotrofina corionica equina (eCG. Para os demais tratamentos, foi utilizado o mesmo protocolo hormonal, diferindo apenas pelo uso do mesmo CIDR pela segunda vez no grupo CIDR2x e uso pela terceira vez no grupo CIDR3x. O intervalo entre

  16. Contribution to the scintillation detection optimization in double phase detectors for direct detection of dark matter

    Science.gov (United States)

    Balan, Catalin

    Na ultima decada, foram feitos grandes progressos no desenvolvimento dos detetores de detecao direta das particulas que constituem a materia negra. Com estrategias do aumento gradual do volume do alvo e, simultaneamente, de reducao dos niveis de fundo, a experiencia XENON obteve resultados muito bons e perspetivas promissoras para a detecao de materia negra. Tarefas relativas a analise de dados experimentais adquiridos com o detetor de dupla fase em uso, assim como as simulacoes do campo eletrico, desenvolvimento, montagem e testes para o proximo detetor XENON1T, assim como a participacao regular na manutencao geral e monitorizacao do prototipo atual XENON100 no LNGS, constituiram o plano de trabalhos para as atividades de investigacao do presente doutoramento e a minha contribuicao para a otimizacao da detecao de cintilacao nos detetores da experiencia XENON. A necessidade de alcancar niveis elevados de sensibilidade, requer inovacao em todos os aspetos fisicos do detetor, assim como a reducao de todas as fontes de radioatividade que contribuem para o fundo. O modo mais indicado de operacao para os detetores com enchimento a Xe no estado liquido e gasoso envolve a medicao da cintilacao primaria e da secundaria provenientes da interacao das particulas no Xe liquido. A razao entre estes dois sinais permite diferenciar claramente a maior parte dos eventos correspondentes as fundo dos eventos correspondentes a WIMPs. Deste modo, a leitura dos sinais correspondentes a cintilacao e de extrema importancia. A amplitude do sinal de cintilacao antes dos fotossensores e maximizada atraves da otimizacao de varios parametros, tais como a geometria do alvo do detetor, a transparencia das grelhas dos eletrodos, a uniformidade do ganho em cintilacao secundaria e a utilizacao de material reflectivo para cobrir as superficies que nao sao fotossensiveis.

  17. Transpiration in mango using Granier method

    OpenAIRE

    VELLAME, Lucas M.; COELHO FILHO, Mauricio A.; PAZ, Vital P. S.

    2009-01-01

    Objetivou-se, com esse trabalho avaliar o método Granier (sonda de dissipação térmica) para a cultura da manga quanto à viabilidade de uso em condições de campo e ajustar a equação de determinação do fluxo de seiva com base em medidas lisimétricas, iniciando-se com três mudas da variedade Tommy Atkins, plantadas em vasos que, colocados sobre plataforma de pesagem, funcionaram como lisímetros. A área condutora do caule (AS) foi determinada por meio da aplicação de corantes. Medidas de transpir...

  18. DeposiÃÃo de DiÃxido de Estanho-FlÃor (SnO2:F) em Substrato Transparente para Uso em CÃlulas FotoeletroquÃmicas

    OpenAIRE

    Francisco Marcone Lima

    2013-01-01

    Vidros condutores tÃm sido usados como Ãxidos condutores transparentes (OCTâs). Por causa da transmitÃncia na regiÃo visÃvel e baixa resistÃncia de filme os OCTâs tÃm sido usados como componente de cÃlulas fotoeletroquÃmicas ativadas por corante. Neste trabalho à feito vidros condutores, em escala de laboratÃrio, de dimensÃes 2,6 cm x 7,6 cm pela tÃcnica âspray pyrolysisâ, os vidros condutores sÃo aplicados na construÃÃo da cÃlula fotoeletroquÃmica com eletrodos imersos e da cÃlula de G...

  19. Detecção do linfonodo sentinela em câncer da mama: comparação entre métodos

    Directory of Open Access Journals (Sweden)

    Xavier Nilton Leite

    2002-01-01

    Full Text Available Objetivos: avaliar a eficiência da cintilografia mamária, do detector manual de raios gama (probe e do corante azul vital para a localização do linfonodo sentinela (LNS, estabelecendo a sensibilidade, o valor preditivo negativo (VPN e a acurácia do mapeamento do LNS. Métodos: neste estudo estão incluídas 88 pacientes com câncer de mama atendidas consecutivamente e com axila clinicamente negativa. Foi utilizado o radiofármaco tecnécio ligado ao colóide dextran 500 (Dextran 99mTc, para cintilografia pré-operatória, realizada em 58 pacientes, e detecção transoperatória com o probe em 53 pacientes. Destas, 47 tiveram as contagens de irradiação gama anotadas e também o intervalo de tempo decorrido entre a injeção e a cirurgia. Foram empregados 2 mL do corante vital Bleu Patente V, injetado em torno do tumor, 5 minutos antes da incisão cirúrgica na axila em todos os casos. O LNS foi avaliado por congelação em 77 casos e todos pela coloração por hematoxilina e eosina. Resultados: a linfocintilografia, realizada em 58 casos, foi útil em 62,1%, sendo que em nove ocorreu mapeamento de dois linfonodos, e com o probe foram confirmados 45 casos (84,9% dos 53 avaliados. Das 47 com anotação de contagens de raios gama e do tempo decorrido da injeção do radiofármaco até a cirurgia, constituíram-se dois grupos para análise, o grupo dia (27 casos e o grupo outro dia (20 casos, que se mostraram diferentes, com significância estatística, tanto no tempo decorrido quanto nas contagens de raios gama, porém sem interferência nos resultados de detecção do LNS. A associação do probe e do corante azul resultou em sucesso nos 53 casos avaliados, assim como em 32 dos 35 casos em que só o corante foi usado. A média de idade das pacientes foi 58 anos. Quarenta e uma pacientes tiveram linfonodos axilares com metástase e apenas duas com LNS falsamente negativo, dando sensibilidade de 95,3%, VPN de 95,5% e acurácia de 97,6. Conclus

  20. Síntese e caracterização de zeólitas obtidas a partir de cinzas volantes de carvão

    OpenAIRE

    Luciane Venturini Lacerda; Annelise Kopp Alves; Felipe Amorim Berutti

    2015-01-01

    Usinas termoelétricas a carvão geram aproximadamente 3 milhões de toneladas de cinzas ao ano. Estas cinzas podem receber uma aplicação nobre como, por exemplo, fotocatalisadores aplicados à descontaminação de águas poluídas por corantes da indústria têxtil. Isso é possível através de utilização das cinzas como fonte de silício para a síntese de zeólitas. Desta forma, neste trabalho foram sintetizadas zeólitas do tipo sodalita, utilizando-se cinzas volantes de carvão da região de Candiota-RS, ...

  1. Linfadenectomia inguinoilíaca laparoscópica, após impregnação linfática com diferentes marcadores em cadelas hígidas

    Directory of Open Access Journals (Sweden)

    Fernando Wiecheteck de Souza

    2016-09-01

    Full Text Available RESUMO: O sistema linfático mamário de animais saudáveis e neoplásicos é pouco estudado. Inexistem respostas detalhadas quanto ao padrão de comunicação entre as cadeias linfáticas mamárias com as abdominais e pélvicas em animais sadios ou com neoplasmas na referida glândula. Por essa razão, pretendeu-se avaliar a ocorrência dessa comunicação linfática intrabdominal, verificando também se a cadeia linfática inguinoilíaca poderia ser adequadamente abordada via cirurgia laparoscópica. Para tanto, os animais foram distribuídos, de forma randômica, em três grupos cirúrgicos: pacientes submetidos à técnica de coloração linfática com o corante azul de metileno estéril (G1; animais submetidos à técnica de impregnação linfática com o corante verde de indocianina (G2; animais submetidos à técnica demarcação linfática, utilizando solução fisiológica de NaCl a 0,9% (G3. Em todos os grupos, foi realizada a aplicação intradérmica, do corante ou solução fisiológica, ao redor da mama inguinal direita, em tempos distintos de 12h ou 30min, antes da incisão de pele. Após, foram coletadas, por videolaparoscopia, duas regiões contendo tecido adiposo, laterais às artérias ilíacas interna e externas, buscando avaliar a presença e o número de linfonodos extirpardos. Por último, realizou-se a ovário-histerectomia eletiva pelos mesmos portais de acesso. Foram considerados ainda, o tempo de cirurgia e as complicações e dificuldades técnicas trans e pós-operatórias. A técnica proposta de linfadenectomia inginoilíaca intrabdominal não obteve êxito na coleta de linfonodos. As técnicas de marcação linfática realizadas, utilizando tanto o azul de metileno a 1%, como o verde de indocianina a 1%, não evidenciaram nenhuma marcação transoperatória nos tempos estudados. Em relação às complicações e dificuldades técnicas trans e pós-operatórias, observou-se, em todos os animais, reações de

  2. Efeito regulatório de flavonóides e de carmim nos níveis de lipídeos em ratos Wistar

    Directory of Open Access Journals (Sweden)

    Oliveira T.T.

    2002-01-01

    Full Text Available Estudou-se a ação de biochanina A isolada e em associação com os corantes naturais antocianina e carmin sobre o metabolismo lipídico de ratos. Foram dosados colesterol, colesterol-HDL e triacilgliceróis após administração de duas doses dos compostos isoladamente e em misturas, sendo a primeira imediatamente após a administração do triton e a segunda 20 horas depois. O sangue foi analisado 43 horas após a administração do triton. Os resultados mostraram que a associação biochanina A + antocianina e biochanina A + carmin apresentaram os melhores resultados para colesterol total e triacilglicerol.

  3. Avaliação in vitro da microinfiltração em cavidades classe II de molares decíduos, restaurados com resina composta auto e fotopolimerizável

    Directory of Open Access Journals (Sweden)

    CAVALCANTI Alessandro Leite

    1999-01-01

    Full Text Available Estudou-se a microinfiltração marginal presente na interface da parede gengival de cavidades classe II em molares decíduos, restaurados com resina composta (auto e fotopolimerizável, através da penetração de uma solução corante. Os preparos cavitários apresentavam a parede gengival em esmalte e foram restaurados segundo 4 diferentes técnicas: 1 resina composta fotopolimerizável; 2 resina composta autopolimerizável; 3 resina composta auto e fotopolimerizável; e 4 ionômero de vidro/resina composta. Após a análise estatística dos resultados, concluiu-se que todos os grupos apresentaram microinfiltração em graus variados; todavia, os grupos 2, 3 e 4 apresentaram os menores graus de infiltração.

  4. Babesia canis em cães de rua da Cidade de São Paulo. I. Estudo comparativo de métodos de diagnóstico

    Directory of Open Access Journals (Sweden)

    Arlete Dell'Porto

    1990-06-01

    Full Text Available Amostras de sangue de 106 cães de rua da Cidade de São Paulo foram examinadas para pesquisa de Babesia canis. As técnicas utilizadas foram a da observação direta do parasita em esfregaço sangüíneo, corado por corante de Rosenfeld, e a reação de imunofluorescência indireta (IFI. Através da primeira diagnosticou-se a infecção em 10,3% dos animais, enquanto que a sorologia revelou 42,4% de cães positivos. No teste de IFI os títulos variaram de 1:10 a 1:2560, sendo mais freqüente o de 1:40. Este último teste apresentou boa sensibilidade e alta especificidade, mostrando-se ideal para levantamentos epidemiológicos.

  5. Assistência de ar e volumes de aplicação na deposição de calda e no controle do arroz vermelho (Oryza sativa L. Air assistance and volume of application in spray deposition and in red rice control (Oryza sativa L.

    Directory of Open Access Journals (Sweden)

    Leopoldo L. S. Vigano

    2007-12-01

    Full Text Available O trabalho teve como objetivo avaliar o efeito da assistência de ar junto à barra pulverizadora e de três volumes de pulverização na dessecação e deposição da calda em arroz vermelho, sob cultivo de nabo forrageiro, em áreas de recuperação de várzeas, utilizando o herbicida paraquat e o corante Azul Brilhante, respectivamente. Os volumes de pulverização foram 100; 200 e 300 L ha-1 da solução aquosa, contendo corante alimentício (1.500 mg L-1. Com ou sem a assistência de ar junto à barra, foram utilizadas pontas de pulverização de jato plano tipo AXI 110015 à pressão de 117,3 kPa, AXI 11002 e AXI 11003 a 276 kPa. A avaliação da deposição da pulverização deu-se em folhas de plantas de arroz vermelho. Os maiores volumes (200 e 300 L ha-1 pulverizados com a assistência de ar junto à barra pulverizadora proporcionaram maiores depósitos do corante em relação ao volume de 100 L ha-1. Não foram constatadas diferenças na deposição do corante para os volumes pulverizados, sem a assistência de ar junto à barra, tampouco entre os volumes de 200 e 300 L ha-1 com a assistência de ar junto à barra. As maiores percentagens de controle do arroz vermelho foram obtidas com a assistência de ar junto à barra, independentemente do volume pulverizado, equivalendo-se ao controle obtido com 300 L ha-1, sem o uso dessa tecnologia.The aim of this research was to evaluate the effect of air-assistance on spraying at three volumes in spray deposition and control of red rice under fodder radish cultivation. To evaluate the control of this weed and spray deposition were used paraquat herbicide and a Brilliant Blue dye, respectively. The three spraying volumes were 100, 200 and 300 L ha-1, using a tracer dye at 1,500 mg L-1. Both solutions and volumes were sprayed with flat fan nozzles AXI 110015 at 117.3 kPa, AXI 11002 and AXI 11003 at 276 kPa, respectively, with and without air-assistance on the boom. The evaluation of deposition

  6. Study of colpo-cytological at the capybaras (Hydrochoerus hydrochaeris Caracterização da colpocitologia em capivaras ("Hydrochoerus hydrochaeris"

    Directory of Open Access Journals (Sweden)

    Cláudia Diniz Pinto Coelho

    2007-12-01

    Full Text Available Capybara (Hydrochoerus hydrochaeris is one of the species which has interested farmers due to its performance potential, as a result of the quality of its skin and meat. Based on commercial interests, many studies have been done to understand the reproductive physiology and to answer questions that could help to improve the productive status of these animals. This study was performed to describe the cell types from the vaginal epithelium of capybaras and to compare the efficiency of three dyes on cell staining. The experiment was carried out at Centro de Biodiversidade of USIPA, in Ipatinga/MG. Cells were obtained by the swab technique from five adult animals and stained with Giemsa, Methylene Blue and Shorr. Samples were collected every three and five days, during 30 days. Four types of cells were observed, parabasal cells, intermediate cells and superficial cells (with or without nucleus, besides bacteria and leukocytes. The three dyes were able to stain efficiently on colpocitology, however, Giemsa and Metileno Blue were more practical than Shorr. Colpocytology was shown to be an applicable procedure for this animal species.A capivara (Hydrochoerus hydrochaeris é uma das espécies que tem despertado o interesse de produtores rurais pelo potencial zootécnico, advindo da qualidade do seu couro e da sua carne. Com base no interesse comercial, muitas pesquisas têm sido desenvolvidas para se entender a fisiologia reprodutiva e responder questões que possam ajudar no aumento da produção desses animais em cativeiro. Este estudo foi conduzido com o objetivo de descrever as células do epitélio vaginal de capivaras e comparar a eficiência de três corantes na coloração das mesmas. O experimento foi realizado no Centro de Biodiversidade da USIPA em Ipatinga / MG. As células foram obtidas pela técnica de swab vaginal de cinco fêmeas adultas cativas e coradas com: Giemsa, Azul de Metileno e Shorr. Foram realizadas coletas com intervalos de 3

  7. Avaliação e otimização de um sistema para aplicação de processo oxidativo avançado uv/h2o2 no tratamento de efluentes visando o reúso

    OpenAIRE

    Loch, Fernando

    2013-01-01

    Este trabalho consiste na análise de três configurações de reatores fotoquímicos aplicados a processos oxidativos avançados através do processo UV/H2O2. As configurações desses reatores foram analisadas em três vazões diferentes, 20 L h-1, 25 L h-1 e 30 L h-1. Foram realizadas avaliações hidrodinâmicas através da passagem em fluxo conforme as vazões mencionadas de uma solução 5% de traçador, de corante vermelho Bordeaux, que permitiu construir as curvas de distribuição do tempo de residência ...

  8. Síntese de zeólitas a partir de cinzas de carvão e aplicação como adsorventes

    OpenAIRE

    Barbara Potrich Zen

    2016-01-01

    Cinzas oriundas da combustão de carvão são resíduos produzidos no processo de geração de energia em termoelétricas. Esses resíduos industriais podem ser aproveitados como matéria prima para síntese de zeólitas, as quais são materiais aluminossilicatos porosos com importantes aplicações, como adsorventes no tratamento de efluentes líquidos. Nesse contexto, o objetivo deste trabalho foi sintetizar zeólitas a partir de três diferentes cinzas de carvão e utilizá-las na remoção de corante violeta ...

  9. Síntese in situ pelo método hidrotérmico de heteroestruturas de titanato-ferritas e sua atividade fotocatalítica

    Directory of Open Access Journals (Sweden)

    B. F. Troque

    Full Text Available Resumo A aplicação de fotocatalisadores na forma de heteroestruturas tem se destacado através da propriedade de degradação de diversos compostos orgânicos no tratamento de efluentes. Neste contexto, o objetivo deste trabalho foi sintetizar compostos heteroestruturados à base de titanato-ferritas pelo método hidrotérmico in situ para aplicação em processo foto-Fenton. Os materiais sintetizados in situ foram caracterizados por difratometria de raios X, espectroscopia de infravermelho, espectroscopia de reflectância difusa, área específica superficial por BET e microscopia eletrônica de transmissão. A síntese in situ de SrTiO3-CoFe2O4 e SrTiO3-NiFe2O4 foi desenvolvida de forma inédita neste trabalho, resultando com sucesso em sistemas heteroestruturados sem presença de fases secundárias, distribuição altamente homogênea das fases constituintes com tamanho médio de partículas nanométrico e garantia de reprodutibilidade do método. A atividade fotocatalítica dos compostos sintetizados foi investigada por meio da degradação do corante Rodamina B, utilizando luz visível, onde o sistema SrTiO3-CoFe2O4 apresentou a melhor atividade fotocatalítica degradando 82% do corante.

  10. Photoelectrochemical solar cell using extract of Eugenia jambolana Lam as a natural sensitizer

    Directory of Open Access Journals (Sweden)

    Christian G. Garcia

    2003-06-01

    Full Text Available The extract of Jambolão (java plum, Eugenia jambolana Lam, was used as a natural sensitizer of a wide band-gap semiconductor (TiO2 in photoelectrochemical solar cells. The natural dye, adsorbed onto the semiconductor surface, absorbs visible light and promotes electron transfer across the dye/semiconductor interface. Photogenerated current and voltage as high as 2.3 mA and 711 mV, respectively, were obtained and effective conversion of visible light into electricity was achieved. The use of a natural product as the semiconductor sensitizer enables a faster and simpler production of cheaper and environmentally friendly solar cells.O extrato de Jambolão, Eugenia jambolana Lam, foi utilizado como um sensibilizador natural de um semicondutor com separação grande de bandas (TiO2 nas células solares fotoeletroquímica. O corante natural, adsorvido na superfície do semicondutor, absorve luz visível e promove transferência eletrônica na interface corante/semicondutor. A corrente e o potencial fotogerados tão altos como 2,3 mA e 711 mV, respectivamente, foram obtidos observando-se conversão eficiente de luz visível em eletricidade. O uso de um produto natural como o sensibilizador de semicondutor possibilita uma produção mais rápida e simples de células solares mais baratas que não agridem o meio ambiente.

  11. Síntese e caracterização de zeólitas obtidas a partir de cinzas volantes de carvão

    Directory of Open Access Journals (Sweden)

    Luciane Venturini Lacerda

    2015-12-01

    Full Text Available Usinas termoelétricas a carvão geram aproximadamente 3 milhões de toneladas de cinzas ao ano. Estas cinzas podem receber uma aplicação nobre como, por exemplo, fotocatalisadores aplicados à descontaminação de águas poluídas por corantes da indústria têxtil. Isso é possível através de utilização das cinzas como fonte de silício para a síntese de zeólitas. Desta forma, neste trabalho foram sintetizadas zeólitas do tipo sodalita, utilizando-se cinzas volantes de carvão da região de Candiota-RS, com diferentes teores de alumínio, e na presença de NaOH como alcalinizante, variando-se o tempo de envelhecimento. Os produtos formados foram caracterizados por DRX, isotermas de adsorção de N2 (BET e sua morfologia foi analisada por MEV e MET. A atividade fotocatalítica foi medida através do acompanhamento da degradação de solução contendo o corante azul de metileno. Os resultados indicaram que a razão Si:Al e o tempo de envelhecimento influenciam significativamente as propriedades da zeólita sintetizada. A zeólita obtida é do tipo sodalita, formada por aglomerados com partículas primárias de 100nm, cuja área superficial é de aproximadamente 6 m2/g. A atividade fotocatalítica foi bastante significativa e foram observados indicativos de propriedades adsorventes.

  12. Influence of eugenol-containing temporary restorations on the microleakage of total-etch and self-etching adhesive systems = Influência de restaurações temporárias contendo eugenol na microinfiltração de sistemas adesivos convencional e autocondicionante

    Directory of Open Access Journals (Sweden)

    Azevedo, Eduardo Costa de

    2008-01-01

    Full Text Available Objetivo: Este estudo in vitro avaliou a influência de um cimento restaurador temporário à base de óxido de zinco-eugenol (CT-OZE no selamento marginal de restaurações diretas, utilizando dois sistemas adesivos. Metodologia: Cavidades classe V foram preparadas em 20 incisivos bovinos e restauradas com dois cimentos temporários, CT-OZE (IRM® ou cimento livre de eugenol (Cavit® (n=10/ cimento temporário. Após sete dias, cinco dentes de cada grupo de cimento temporário foram restaurados utilizando o sistema Single Bond® (SB e os demais cinco com o sistema Adper Prompt® (AP. As cavidades foram restauradas com resina composta (Filtek Z-250, termocicladas (500 ciclos, imersas em fucsina básica e longitudinalmente seccionadas. A penetração do corante foi avaliada em microscópio ótico. Os dados analisados por teste de Kruskal-Wallis (P = 0,05. Resultados: A infiltração em dentina foi similar à do esmalte. Em esmalte, o grupo com Cavit® e AP apresentou infiltração significativamente maior. Em dentina, AP exibiu maior infiltração que SB, e não houve diferença entre CT-OZE e Cavit®. Conclusão: Em geral, SB produziu melhor selamento marginal que AP, e CT-OZE não aumentou a penetração de corante. A presença de eugenol no material restaurador temporário não afetou o selamento marginal de restaurações adesivas

  13. Liberação controlada da eosina impregnada em microesferas de copolímero de quitosana e poli(ácido acrílico Controlled release of eosin impregnated in microspheres of chitosan/poly(acrylic acid copolymer

    Directory of Open Access Journals (Sweden)

    Atche Josué

    2000-09-01

    Full Text Available Microesferas de quitosana com grau de desacetilação médio de 85,6% foram enxertadas com poli(ácido acrílico para aplicação como sistemas de liberação controlada de fármacos. O corante eosina impregnado nas microesferas de quitosana modificada foi utilizado como marcador para estudo in vitro de liberação de fármacos. As microesferas de quitosana foram obtidas pelo método de inversão de fases com NaOH, seguidas de reticulação com glutaraldeído, redução com cianoboroidreto de sódio e enxertia com poli(ácido acrílico na presença de uma solução de nitrato de cério (IV amoniacal como iniciador redox. Os estudos in vitro de liberação da eosina a partir de microesferas de quitosana, mostraram que o corante foi liberado em função do tempo a pH 6,8 e 9,8 que simulam as condições fisiológicas do trato gastrointestinal, enquanto que nenhuma eosina foi liberada a pH 1,2.Chitosan microspheres obtained by coacervation-phase separation, cross-linked with glutaraldehyde and grafted with poly(acrylic acid were used as the basis of in vitro studies on the controlled release of eosin. Microspheres impregnated with an aqueous solution of the dye depicted a time-dependent release of eosin at pH values of 6.8 and 9.8, typical of the gastrointestinal tract. No eosin release could be observed at 1.2 pH.

  14. Produção de carvão a partir de resíduo de erva-mate para a remoção de contaminantes orgânicos de meio aquoso Production of charcoal from maté waste to remove organic contaminants from aqueous solution

    Directory of Open Access Journals (Sweden)

    Maraísa Gonçalves

    2007-10-01

    Full Text Available Neste trabalho, apresenta-se um novo material adsorvente, obtido a partir da pirólise de resíduos da erva-mate. O carvão resultante demonstrou elevada área superficial específica quando comparado com outros materiais pirolisados e elevada capacidade de remoção de contaminantes orgânicos de soluções aquosas. Os valores de área específica apresentados pelos materiais foram de 344, 191 e ~0,5 m² g-1, para o carvão Mate 1, Mate 2 e Mate 3, respectivamente. As isotermas de adsorção mostraram que os carvões apresentam potencial para utilização como adsorvente para compostos orgânicos, tais como: o corante têxtil vermelho reativo, o corante azul de metileno e para o herbicida atrazina, sendo que os máximos de adsorção utilizando o carvão Mate 1 foram de 16, 230 e 30 mg g-1, respectivamente.In this work we present a new adsorbent material, obtained by maté waste pyrolisis. The resulting charcoal presented high specific area when compared with other pyrolized materials and also high capacity to remove organic contaminants from aqueous solution. The charcoal showed specific area of 344, 191 and ~0.3 m² g-1 for sample Mate 1, Mate 2 and Mate 3, respectively. According to the corresponding adsorption isotherm these materials present good adsorption capacity for reactive textile and methylene blue dyes and the herbicide atrazine. Adsorption maxima were respectively 16, 230 and 35 mg g-1 for such substances, when sample Mate 1 was used.

  15. CARACTERIZAÇÃO FÍSICO-QUÍMICA DO REPOLHO ROXO (Brassica oleracea

    Directory of Open Access Journals (Sweden)

    Gilcenir dos Santos

    2014-07-01

    Full Text Available O repolho roxo é uma planta herbácea, originária do mediterrâneo, encontrada em todos os períodos do ano, contemplador de poucas calorias e rico em antocianina, um pigmento natural, de fácil extração, solúvel em água que confere a coloração vermelha a alimentos, podendo ser utilizado na indústria alimentícia em substituição aos corantes sintéticos. O presente trabalho teve como objetivo realizar a caracterização físico-química do repolho roxo e do seu extrato obtido por maceração em etanol 70% acidificado com HCl 1N e concentrado em evaporador rotatório com intuito de ser utilizado para a obtenção de um corante natural, possuidor de substância promissora na prevenção de doenças degenerativas como o câncer e doenças cardiovasculares. Foram determinados pH, acidez total titulável (ATT, sólidos solúveis(°Brix, atividade de água, umidade e cor . Tanto repolho roxo in natura quanto o seu extrato concentrado apresentou um elevado teor de água e baixa acidez, condições favorável ao desenvolvimento de microorganismo, houve perda na coloração vermelha na produção do extrato concentrado.

  16. CARACTERIZACIÓN DE POLVOS DE ACERÍA ELÉCTRICA PRODUCIDOS EN VENEZUELA Y EVALUACIÓN PRELIMINAR DE SU LIXIVIABILIDAD CON ÁCIDOS ORGÁNICOS DILUIDOS

    Directory of Open Access Journals (Sweden)

    PEDRO DELVASTO

    2011-01-01

    Full Text Available Se estudiaron polvos de aceria cuyo analisis quimico revelo un contenido (en peso de: 27,0 % de Fe; 7,1 % de Mg; 4,9 % de Zn; 4,0 % de Ca y 0,5 % de Pb. La difraccion de rayos X y la espectroscopia infrarroja, permitio identificar en los polvos las siguientes fases: espinelas, Fe3O4, CaCO3, SiO2, ZnO y PbO. El analisis microscopico de estos residuos indico que estan formados por agregados de particulas esferoidales cuyo tamano varia entre 120 y 0,25 ¿Êm. La lixiviabilidad de los mismos se evaluo durante 28 dias en columnas de percolacion, empleando agua y disoluciones de acidos organicos como agentes lixiviantes. El objetivo fue evaluar el comportamiento del residuo bajo condiciones similares a las que generan los microorganismos naturales del suelo. Se encontro que la lixiviabilidad de Zn y Pb vario entre 80 y 16 mg mensuales por kilogramo de polvo de aceria.

  17. Power generation from biomass estimation for projects of the clean development mechanism program; Estimacion de la generacion de energia a partir de biomasa para proyectos del programa de mecanismo de desarrollo limpio

    Energy Technology Data Exchange (ETDEWEB)

    Flores Velazquez, Roberto; Munoz Ledo Carranza, Ramon; Flores Brito, Brenda Berenice; Cano Ruiz, Karla Itzel [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

    2009-07-01

    In the present work, it is calculated the amount of energy and the reductions of greenhouse gases emissions that may be obtained taking advantage of organic wastes, such as, sugarcane bagasse and urban wastes. The appropriate use of these waster could generate up to 28% of the power requirements reported for the state of Morelos in 2005. Likewise, the Clean Development Mechanism could be employed to negotiate carbon certificates in such as way that the industrialized countries could meet with the goals implemented in the Kyoto Protocol and the state of Morelos could get the financial resource to be in the front technologic line with respect to the utilization of organic waster to generate power and to reduce greenhouse gases emissions. [Spanish] En el presente trabajo se estima la cantidad de energia y reduccion de emisiones de gases de efecto invernadero que podria obtenerse mediante el aprovechamiento de desechos industriales y municipales en el estado de Morelos, Mexico, tales como el bagazo de cana y la basura municipal. El uso adecuado de estos desechos podria generar hasta un 28% de los requerimientos energeticos de Morelos reportados en 2005. Asimismo, a traves del programa de Mecanismo de Desarrollo Limpio se podrian negociar certificados de carbono para que los paises industrializados cumplan las metas estipuladas en el Protocolo de Kyoto, y el estado de Morelos obtenga la inversion necesaria para estar a la vanguardia tecnologica en la utilizacion de desechos organicos para la generacion de energia y la reduccion de gases de efecto invernadero.

  18. The regional laws to support technological innovation in Emilia Romagna: the principle legislative instruments; Le leggi regionali a favore dell`innovazione tecnologica in Emilia-Romagna: i principali strumenti agevolativi

    Energy Technology Data Exchange (ETDEWEB)

    Grandi, M.

    1998-01-01

    The Emilia Romagna region supports the developpement and the economic growth of innovative SMEs with legislative instruments. These instruments give the chance to the companies to improve their law capitalization and to receive facilities of credit. In this following guide the opportunities offered by legislative instruments are synthesized in summarized schemes. Every scheme is structured in this way: beneficiary persons; dead lines and expire dates; measures and conditions of payment; priorities. Every summarized scheme contains information about the legislative sources and it is equipped with a schedule that stresses the effective assignment of contributions. [Italiano] Lo sviluppo e la crescita delle PMI viene sostenuto dalla Regione Emilia Romagna attraverso strumenti legislativi locali che, se utilizzati in sinergia con altri programmi di finanziamento nazionali e comunitari, permettono alle imprese di superare i limite della sottocapitalizzazione beneficiando di un credito agevolato. In questo documento le possibilita` offerte sul credito agevolato vengono riassunte in modo organico ed esaustivo indicando, per ogni strumento di finanziamento: i soggetti beneficiari; il termine di presentazione della domanda di contributo altre scadenze; la misura e la modalita` di erogazione dei contributi; le iniziative finanziabili: priorita`. Ogni schema riassuntivo contiene indicazioni sulle fonti legislative considerate ed e` correlato da una tabella che evidenzia i dati relativi all`effettiva erogazione dei contributi.

  19. STUDY OF A PROTOCOL FOR MEASURING SAIL SPORTS TRAINING

    Directory of Open Access Journals (Sweden)

    Claudio Scotton

    2015-04-01

    Full Text Available Durante l’attività agonistica i velisti incontrano molteplici difficoltà. Elenchiamo solo alcune variabili ambientali che condizionano le scelte tattiche e tecniche che possono rivelarsi vincenti o perdenti (Scotton 2007: vento, onda, corrente, umidità, temperatura dell’acqua e dell’aria, distanza del campo di regata dalla sistemazione degli atleti a terra, sole, pioggia. Da tutto ciò si evince che la Vela, rispetto ad altre specialità sportive praticate in una condizione stabile come accade in una palestra o in un campo di atletica e caratterizzate dalla prevalenza di abilità motorie sportive stereotipate (Scotton 2003, naviga, vocabolo pertinente, con maggiori difficoltà nell’individuare i carichi di lavoro interno ed esterno. Obiettivo: Scopo del presente studio è l’indagine conoscitiva delle caratteristiche antropometriche di base e di alcune capacità organico-muscolari e coordinative di velisti della classe 29er; deriva in doppio acrobatica giovanile (Federvela 2008, molto veloce in qualsiasi condizione, ma anche instabile e difficile da condurre. Il lavoro ha permesso di gettare le basi per la messa punto di un protocollo di misurazione dell’allenamento applicabile alla Vela.

  20. Electrochemical treatment of olive oil mill wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Longhi, P.; Fiori, G [Milan Univ., Milan (Italy). Dept. of Physical Chemistry and Electrochemistry; Vodopivec, B. [Milan Univ. Bicocca, Milan (Italy). Dept. of Biotechnologies and Biosciences

    2001-04-01

    The possibility of oxidizing at a PbO{sub 2} anode the phenols and polyphenols, present in the olive oil mill wastewater, has been studied as a pre-treatment for the submission of such wastewater to the traditional biological treatments. The results obtained operating at current densities ranging 500 to 2000 A/m{sup 2} show that it is possible to reduce the concentration of the phenolic components, which interfere with the biological treatments, down to low values without decreasing too much the total organic content of the wastewater. [Italian] E' stata studiata la possibilita' di ossidare anodicamente i componenti fenolici delle acque reflue di frantoio, quale pretrattamento delle stesse prima del loro invio ai processi di trattamento biologico. I risultati ottenuti impiegando PbO{sub 2} quale materiale anodico e operando con densita' di corrente comprese tra 500 e 2000 A/m{sup 2} mostrano come sia possibile eliminare, o almeno diminuire sino a concentrazioni accettabili, dalle acque di frantoio i fenoli e i polifenoli, che interferiscono con i normali trattamenti biologici, senza diminuire eccessivamente il carico organico totale.

  1. The photo refractive polymers, physics and photonic applications of these new materials; Los polimeros fotorrefractivos, fisica y aplicaciones fotonicas de estos nuevos materiales

    Energy Technology Data Exchange (ETDEWEB)

    Maldonado, J. L. [Centro de Investigacion en Optica, Leon, Guanajuato (Mexico); Garcia M, J. [Universidad Nacional Autonoma de Mexico, Mexico, D.F. (Mexico)

    2001-12-01

    This paper is a review about the new photo refractive organic materials and their potential photonic applications, the photo refractive polymers. The physical properties required for observing photo refractivity, including charge generation, transport, and nonlinear optical properties are discussed for amorphous polymers. The nonlinear optical properties on a macroscopic level are related to the microscopic properties by using the Oriented Gas model. Four Wave Mixing (FWM) and Two Beam Coupling (TBC) experiments, to investigate the photo refractive properties of the material by measuring the diffraction efficiency {eta} of the polymeric gratings, and the optical gain coefficient {eta} are described. Kogelnik's Coupled Wave model to describe the photo refractive polymeric gratings is reviewed. Finally some applications of these new polymers are presented. [Spanish] Este articulo es una revision sobre los nuevos materiales organicos fotorrrefractivos y sus potenciales aplicaciones fotonicas: los polimeros fotorrefractivos. Se discuten las propiedades fisicas requeridas para observar fotorrefractividad, incluyendo la generacion de cargas, el transporte y las propiedades opticas no lineales en polimeros amorfos. Usando el modelo de gas orientado, se muestra como se relacionan las propiedades opticas no lineales a nivel marcoscopico con las propiedades microscopicas. Se describen los experimentos de mezcla de cuatro ondas (FWM) y dos ondas (TBC) para investigar las propiedades fotorrefractivas del material, midiendo la eficiencia de difraccion {eta} de las rejillas polimericas y el coeficiente de ganancia optica {eta}. Se revisa el modelo de ondas acopladas de Kogelnik para describir las rejillas polimericas fotorrefractivas. Finalmente se presentan algunas aplicaciones de estos nuevos polimeros.

  2. Effects on water quality from mud clearance operations in the Pezze' hydropower basin (Trentino, Italy); Effetti sulla qualita' delle acque legati alle operazioni di dissabbiamento del bacino idroelettrico di Pezze' di Moena (Trentino)

    Energy Technology Data Exchange (ETDEWEB)

    Canepel, R.; Cadrobbi, G.; Fedrizzi, F. [Agenzia Provinciale per la Protezione dell' Ambiente, Trent (Italy)

    2000-07-01

    The present paper describes dynamic concentration for various parameters, that have been monitored through both continuous and instant samplings, during maintenance operations (mud deposit clearance) in a hydropower basin along Torrent Avisio in Trentino region, Italy. Aim of the work is to demonstrate that, during such operations, an organic water pollution occur besides turbidity. The former is well expressed by a marked value increment of different parameters, as total phosphorus, ammonium and organic matter. [Italian] Il presente lavoro descrive l'osservazione dell'andamento delle concentrazioni di diversi parametri, rilevati in continuo e attraverso campionamenti istantanei, durante le operazioni di dissabbiamento di un bacino idroelettrico lungo un corso d'acqua, il Torrente Avisio in Trentino. Scopo del lavoro e' la dimostrazione della consistenza, in occasione di tali eventi, di un inquinamento delle acque, oltre che di tipo inorganico (intorbidimento), anche di tipo organico cioe' caratterizzato da uno spiccato incremento, rispetto alle condizioni normali, di una serie di parametri fra cui fosforo totale, azoto ammoniacale e sostanza organica.

  3. 1-N-aminoindol derivatives synthesis in no aqueous means from the 1, 4-dihydrocinnoline obtained by electrolysis in continuous flow redox cell; Sintesis de derivados del 1-N-aminoindol en medios no acuosos a partir de la 1, 4-dihidrocinolina obtenida por electrolisis en celda redox de flujo continuo

    Energy Technology Data Exchange (ETDEWEB)

    Frontana-Uribe, Bernardo A. [Universidad Nacional Autonoma de Mexico, Mexico, D.F. (Mexico); Moinet, Claude [Laboratoire d' Electrochimie et Organometalliques UMR, Paris (France)

    1999-08-01

    This work describes the synthesis of 1-N-aminoindol derivatives in organic anhydrous media from 1, 4-dihydrocinnoline. 1, 4-dihydrocinnoline 4 is obtained by electrolysis of 2-(orto-notropheny)-ethylamine 1a in a continuous flow redox cell. The cinnoline ring contraction products are obtained in low yield, but they show the possibility to carry out the reaction in organic media without water addition, as it was noted in previous works. [Spanish] En este trabajo se describe la sintesis de derivados del 1-N-aminoindol en medios anhidros a partir de la 1, 4-dihidrocinolina 4. Esta se obtiene mediante la electrolisis de la 2-(orto-notrofenil)-etilamina 1a en celda redox de flujo continuo. Los productos de contraccion del ciclo de la cinolina en 1-N-aminoindol se obtiene en rendimiento bajo, pero demuestran la posibilidad de llevar a cabo esta reaccion en medios totalmente organicos, sin la necesidad de la adicion de agua en el medio de reaccion, como esta descrito en trabajos precedentes.

  4. Manufacture of amorphous and poly-crystalline materials with the sol-gel process; Fabricacion de materiales amorfos y policristalinos con la ruta sol-gel

    Energy Technology Data Exchange (ETDEWEB)

    Castaneda-Contreras, J. [Centro Universitario de Los Lagos, Universidad de Guadalajara, Guadalajara, Jalisco (Mexico)

    2006-01-15

    The sun-gel process is a chemical route that allows the manufacture of amorphous and poly-crystalline materials in a relatively simple way. New materials can be obtained, materials that through the traditional manufacture methods, are very difficult to obtain, such as oxide combinations (SiO{sub 2}, TiO{sub 2}, ZrO{sub 2}, etc.), and that, when being produced by traditional methods, they run the risk of being contaminated with rare earth ions or organic dyes. The unique structures, micro- structures and compounds that can be made with the sun-gel process open many possibilities for practical applications, to name a few: the manufacture of optical components, preforms for optical fibers, dielectric coatings, superconductors, waveguides, nanoparticles, solar cells, etc. [Spanish] El proceso sol-gel es una ruta quimica que permite fabricar materiales amorfos y policristalinos de forma relativamente sencilla. Se pueden obtener nuevos materiales que a traves de los metodos tradicionales de fabricacion son muy dificiles de obtener, tales como combinaciones de oxidos (SiO{sub 2}, TiO{sub 2}, ZrO{sub 2}, etc.), y que, de ser producidos por metodos tradicionales corren el riesgo de contaminarse con iones de tierras raras o colorantes organicos. Las estructuras unicas, micro estructuras y compuestos que pueden hacerse con el proceso sol-gel abren muchas posibilidades para aplicaciones practicas, por nombrar algunas, la fabricacion de componentes opticos, preformas para fibras opticas, recubrimientos dielectricos, superconductores, guias de onda, nanoparticulas, celdas solares, etc.

  5. Excipientes de medicamentos e as informações da bula Pharmaceutical excipients and the information on drug labels

    Directory of Open Access Journals (Sweden)

    Aracy Pereira Silveira Balbani

    2006-06-01

    Full Text Available OBJETIVO: Avaliar a presença de conservantes, corantes, adoçantes e aromatizantes em 73 apresentações farmacêuticas de 35 medicamentos para uso oral, e as informações da bula sobre excipientes. MÉTODOS: Selecionamos 35 medicamentos, de venda livre ou sob prescrição médica, comercializados no Brasil. A amostra incluiu: analgésicos/antitérmicos, antimicrobianos, mucolíticos, antitussígenos, descongestionantes, anti-histamínicos, broncodilatadores, corticosteróides, antiinflamatórios e suplementos vitamínicos. Foram analisadas 73 apresentações desses fármacos, anotando-se as informações da bula sobre conservantes, corantes, adoçantes e aromatizantes. RESULTADOS: A bula de um medicamento (1,3% não mencionava os ingredientes inativos. Os conservantes mais encontrados nos medicamentos foram metilparabeno e propilparabeno (43% e 35,6% respectivamente. Os adoçantes mais usados foram: sacarose (açúcar (53,4%, sacarina sódica (38,3% e sorbitol (36,9%. Vinte e um produtos (28,7% continham dois adoçantes. Predominaram os medicamentos sem corante (43,8%, seguidos pelos coloridos por amarelo crepúsculo (amarelo FD&C no. 6 (15%. Cinco produtos (6,8% continham mais de um corante. A tartrazina (amarelo FD&C no. 5 foi encontrada em sete formulações (9,5%. Os aromatizantes mais usados foram os de frutas (83%. Constatamos a freqüente omissão das bulas sobre o teor exato de açúcar dos produtos (77%. Duas das quatro bulas de medicamentos contendo aspartame não mencionavam as precauções no uso por fenilcetonúricos. CONCLUSÕES: A omissão e a imprecisão das informações da bula sobre os excipientes farmacêuticos expõem os indivíduos suscetíveis ao risco de reações adversas dos conservantes e corantes. Também podem ocorrer complicações do uso inadvertido de medicamentos contendo açúcar pelos pacientes diabéticos, ou de fármacos adoçados com aspartame pelos fenilcetonúricos.AIM: to evaluate the presence of

  6. Influence of the tannic and gallic acids on stability of betacyanins from red beetroot (Beta vulgaris L. crude extract. INFLUÊNCIA DOS ÁCIDOS TÂNICO E GÁLICO NA ESTABILIDADE DE BETACIANINAS DO EXTRATO BRUTO DE BETERRABA VERMELHA (Beta vulgaris L.

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    D. A. DRUNKLER

    2008-08-01

    Full Text Available The use of e natural colorants in the food industry is limited because to its low stability under preparation, processing and storage conditions. Techniques for natural colorant’s stabilization, such as copigmentation, have been used frequently in scientific researches. The betacyanins that belong to the groups of the betalain presents in the red beetroot and are used as colorant in food. Tannic and gallic acids were used in this study as a copigment of betacyanin crude extract from red beetroot (Beta vulgaris L.. Betacyanin stability was investigated with and without tannic and gallic acid under different storage conditions in 70% ethanol extract: concentrations of 0.925g/100mL and 0.462g/100mL, pH values 5.00±0.05 and 6.80±0.05 at temperature of 25±1ºC, in the dark and in the presence of oxygen. Results revealed that pH and tannic and gallic acid addition (p<0.05 increased significantly the betacyanins half-life time. The tannic and gallic acids provided significant increase in stability of the betacyanins pigments at both concentrations evaluated, at pH value of 5.00 ± 0.05, tannic acid being more effective.

    O uso dos corantes naturais na indústria alimentícia é limitado em função de sua baixa estabilidade frente às condições de preparação, processamento e estocagem. Técnicas de estabilização de corantes naturais, tais como a copigmentação, vem encontrando destaque em pesquisas científicas. As betacianinas (coloração vermelha violeta, pertencentes ao grupo de pigmentos naturais denominados betalaínas, são as que predominam na beterraba vermelha (Beta vulgaris L., sendo utilizadas como corante em alimentos. O objetivo do presente trabalho foi avaliar a estabilidade de betacianinas em extrato de beterraba (Beta vulgaris L. etanólico a 70% adicionadas dos ácidos orgânicos tânico e gálico, nas

  7. Desenvolvimento de buttermilk probiótico Development of a probiotic buttermilk

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    Adriane Elisabete Costa Antunes

    2007-03-01

    Full Text Available Atualmente, são lançados no mercado diversos novos produtos, sendo que na área de laticínios a ênfase é para os funcionais. Esta pesquisa propõe o desenvolvimento de uma bebida láctea fermentada, denominada buttermilk, que seja probiótica, apresente opções de sabor, que tenha versões dietéticas e que atenda à legislação brasileira. A primeira etapa do trabalho consistiu na determinação do fluxograma de preparo do produto para determinar os melhores momentos para adição de sacarose, sucralose e da cultura probiótica. Na etapa seguinte, foi avaliada a qualidade microbiológica de corantes e aromatizantes para empregá-los, sem tratamento térmico, no produto fermentado. Posteriormente, foram analisadas as amostras de buttermilk de diversos sabores, durante o armazenamento, para verificar se a adição de sacarose, edulcorante, aromatizantes e corantes interferiria nas contagens microbiológicas. Os resultados indicaram que a adição da cultura probiótica deve ser feita pré-fermentação e que corantes e aromatizantes podem ser adicionados no produto já fermentado. Observou-se que as amostras de buttermilk com sacarose adicionadas de agentes de cor e aromatizantes tenderam a apresentar menores contagens de bifidobactérias após a estocagem. Porém, todos os sabores de buttermilk se mantiveram adequados à legislação quanto aos aspectos de higiene e de número de bifidobactérias. B. animalis subsp. lactis apresentou excelente viabilidade durante o armazenamento do produto (média de 1,3.10(8 UFC.mL-1. As amostras de buttermilk podem, assim, ser consideradas seguras para consumo, além de potencialmente funcionais.New food products are launched on the market nearly every day and the main focus of the dairy industry is on functional products. The aim of this research project is to develop a fermented probiotic dairy product - buttermilk -, in a variety of flavors - including diet versions - in compliance with Brazilian

  8. Color change using HSB color system of dental resin composites immersed in different common Amazon region beverages Alteração de cor de resinas compostas imersas em diferentes bebidas comuns da região Amazônica, utilizando o sistema de cor HSB

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    Débora da Costa e Silva

    2009-01-01

    Full Text Available The purpose of this study is to evaluate in vitro the color stability of composite resins when exposed to beverages with high coloring contents from the Amazon region. 240 samples from four different composite brands (Natural Look, Z350, 4Seasons and Opallis of hue A3 were fabricated using an acrylic matrix. The samples were stored in distilled water at 37ºC for 24 hours. The initial color (T0 was registered using a Canon EOS Rebel XTi 10 mp camera, and then the samples were divided into four groups (n=15: G1 (coffee, G2 (açaí juice, G3 (energetic guaraná and G4 (control - distilled water. The samples were exposed to solutions of DES (6hs and RE (18hs and placed in a double boiler under constant agitation, at 37ºC for 30 days. The samples were immersed in the coloring solutions for 15 minutes daily. After 7, 15 and 30 days, new photographic registers were made (T1, T2 and T3. The images were analyzed using Corel PHOTO-PAINT 12 software to identify the colors through the HSB system. The Kruskal-Wallis and t tests (pEste estudo propôs avaliar in vitro a estabilidade de cor de alguns compósitos quando expostos a bebidas da Região Amazônica com alto teor de corante. Foram confeccionados 240 corpos de prova (CP de quatro resinas (Natural Look, Z350, 4Seasons e Opallis no matiz A3 utilizando uma matriz de acrílico. As amostras foram armazenadas em água deionizada a 37ºC por 24 horas. A cor inicial das resinas (T0 foi registrada utilizando a máquina Canon EOS Rebel XTi 10Mp, e em seguida os CP foram divididos em 4 grupos (n=15: G1 (café, G2 (suco de açaí, G3 (guaraná energético e G4 (controle - água destilada. Os CP foram submetidos às soluções DES (6hs e RE (18hs e colocados em banho-maria, sob constante agitação, à temperatura de 37ºC durante 30 dias. Diariamente os corpos de prova foram imersos nas soluções corantes durante 15 minutos. Após 7, 15 e 30 dias realizaram-se novos registros fotográficos (T1, T2 e T3. As

  9. Biofunctionality and immunocompatibility of starch-based biomaterials

    Science.gov (United States)

    Marques, Alexandra Margarida Pinto

    inflamatoria a biomateriais. Em resumo, os estudos de citocompatibilidade e imunocompatibilidade demonstraram que os polimeros e compositos a base de milho sao biomateriais promissores. Em comparacao com os biomateriais degradaveis actualmente em uso, possuem propriedades capazes de induzir um comportamento semelhante, ou mesmo melhor, em termos de citotoxicidade. Estes dados foram reconfirmados com a adesao e proliferacao de celulas do tipo osteoblastos na superficie de alguns dos materiais a base de amido, que demonstraram ser comparaveis as observadas no PLLA, evidenciando a possibilidade de usar esses materiais em aplicacoes ortopedicas. As conclusoes retiradas dos estudos in vitro e in vivo de imunocompatibilidade reforcam as observacoes das experiencias de citocompatibilidade e em conjunto, evidenciam a possibilidade de utilizacao dos biomateriais a base de amido, com fraca capacidade de desencadear uma reaccao inflamatoria, em aplicacoes biomedicas. (Abstract shortened by ProQuest.).

  10. Carragenana da epífita Hypnea musciformis obtida do cultivo experimental de Solieria filiformis em Flecheiras, Estado do Ceará, Brasil = Carragennan from Hypnea musciformis epiphyte obtained from Solieria filiformis experimental culture at Flecheiras, Ceará State, Brazil

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    José Ariévilo Gurgel Rodrigues

    2011-04-01

    Full Text Available O cultivo da rodoficea Solieria filiformis vem sendo desenvolvido na praia de Flecheiras, Estado do Ceara, como perspectiva de utilizacao sustentavel do recurso para biotecnologia, mas o crescimento de epifitas sobre a especie compromete seu bom crescimento. Desta forma, avaliou-se a eficiencia de duas metodologias (M I e M II noisolamento da Kappa-carragenana (ƒÈ-CAR da alga marinha vermelha Hypnea musciformis. A ƒÈ-CAR foi obtida mediante digestao proteolitica (M I ou agua quente (80‹C (M II. Os extratos foram analisados quanto a sua composicao quimica, seguido por cromatografia de troca ionica em coluna de DEAE-celulose usando um gradiente de NaCl. A atividade anticoagulante foi avaliada pelo teste do tempo de tromboplastina parcial ativada (TTPA, usando plasma humano normal e heparina (HEP padrao (193 UI mg-1. A diferenca nos rendimentos foi 4,28 } 0,26%% (p Solieria filiformis (Rhodophyceae culture is being developed at Flecheiras Beach, state of Ceara, Brazil, for its future sustainable use in biotechnology. However, epiphyte growth on the species jeopardizes suitable development. The efficiency of two methods (M I and M II in the isolation of kappa-carrageenan (ƒÈ-CAR from red marine alga Hypnea musciformis has been evaluated. ƒÈ-CAR was obtained by proteolytic digestion (M I or by hot water (80‹C(M II and extracts were analyzed with regard to their chemical composition and then by ion-exchange chromatography on DEAE-cellulose column with NaCl gradient. Anticoagulant activity was evaluated by the activated partial thromboplastine time (APTT test with common human plasma and standard heparin (HEP (193 IU mg-1. Yield difference reached 4.28 } 0.26%% (p < 0.05, and the lowest sulfate content was obtained with M I (17.00% when compared to that with M II (26.30%. Further, different chromatographic profiles were reported between the two methods. Whereas M I was efficacious in obtaining ƒÈ-CAR anticoagulants (2.67 IU mg-1

  11. Vitamina C, carotenoides, fenólicos totais e atividade antioxidante de goiaba, manga e mamão procedentes da Ceasa do Estado de Minas Gerais = Vitamin C, carotenoids, phenolic compounds and antioxidant activity of guava, mango and papaya from Ceasa of Minas Gerais State

    Directory of Open Access Journals (Sweden)

    Daniela da Silva Oliveira

    2011-01-01

    Full Text Available Este estudo teve como objetivo analisar o conteudo de compostos antioxidantes (acido ascorbico - AA, acido desidroascorbico - ADA, vitamina C total, licopeno, £]-caroteno, £]-criptoxantina e estimativa de compostos fenolicos e avaliar a atividade antioxidante, em goiaba, manga e mamao. A analise de carotenoides e vitamina C foi realizada por Cromatografia Liquida de Alta Eficiencia (CLAE. O teor de fenolicos totais foi determinado utilizando o reagente de Folin-Ciocalteu e leitura espectrofotometrica. A atividade antioxidante foi avaliada pelo Teste do 2,2-diphenil-2-picril-hidrazil (DPPH¡E e do Poder Redutor. A Anova (ƒÑ = 0,05 foi utilizada para a analise dos dados. Os teores dos constituintes antioxidantes diferiram entre as tres frutas, mas a goiaba foi a fruta que apresentou teores mais elevados de compostos fenolicos, vitamina C total, ADA e licopeno, alem dos maiores valores para atividade antioxidante. Foi constatada forte correlacao entre os testes que avaliaram a atividade antioxidante e o teor de fenolicos totais, demonstrando serem estes os principais compostos antioxidantes a contribuirem para a atividade antioxidante das frutas analisadas, em ambos os testes. E importante incentivar a utilizacao das frutas avaliadas neste estudo, tanto em nivel domestico quanto em estabelecimentos de alimentacao coletiva para aumentar o consumo de antioxidantes naturais pela populacao.This study aimed to analyze the content of antioxidant compounds (ascorbic acid - AA, dehydroascorbic acid - DHA, total vitamin C, lycopene, £]-carotene, £]-cryptoxanthin and phenolic compounds and to evaluate the antioxidant activity in guava, mango and papaya.The analysis of carotenoids and vitamin C was performed by high performance liquid chromatography (HPLC. The content of phenolic compounds was determined using the Folin-Ciocalteu reagent and spectrophotometric reading. Antioxidant activity was evaluated by testing the 2.2-diphenyl-2-picryl

  12. Utilização da técnica de eletrofloculação para o tratamento de efluentes têxteis: uma revisão

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    Leandro Fleck

    2013-12-01

    Full Text Available Nos últimos anos o desenvolvimento de atividades industriais tem provocado inúmeros impactos aos recursos naturais. A indústria têxtil gera elevada quantidade de efluente, devido à grande utilização de água em seu processo produtivo, que quando não corretamente tratado deteriora a qualidade da água do curso hídrico receptor. Diante das formas tradicionais de tratamento de efluentes, a eletrofloculação surge como uma técnica inovadora. Tal processo constitui na passagem de corrente elétrica através de uma célula eletrolítica, originando dois processos distintos: eletrocoagulação e eletroflotação. O presente artigo tem como objetivo apresentar uma revisão bibliográfica acerca da utilização da técnica de eletrofloculação para o tratamento de efluentes industriais, com enfoque ao efluente têxtil. A forte coloração é a característica predominante em efluentes têxteis, como conseqüência da utilização de corantes para o tingimento do tecido. Devido a sua toxicidade e baixa biodegradabilidade, a presença de corantes causa inúmeros impactos aos seres vivos, o que justifica a busca por métodos alternativos para remoção desses constituintes. Atualmente não se encontram na literatura muitos estudos relacionados à aplicação da técnica de eletrofloculação para o tratamento de efluentes industriais. O pequeno número de estações de tratamento por eletrofloculação no Brasil torna-se um obstáculo para sua disseminação em grande escala. Entretanto, os resultados positivos alcançados em estudos prévios demonstram que a aplicabilidade da técnica de eletrofloculação será ampliada para o tratamento em grande escala de efluentes provenientes de atividades industriais potencialmente poluidoras.

  13. Consumo de aditivos alimentares e efeitos à saúde: desafios para a saúde pública brasileira Food additive intake and health effects: public health challenges in Brazil

    Directory of Open Access Journals (Sweden)

    Maria Lúcia Teixeira Polônio

    2009-08-01

    Full Text Available Este estudo visa a contextualizar por meio de uma revisão sistemática da literatura, os riscos acarretados pelo consumo de aditivos alimentares. Em relação aos resultados dos estudos associando o consumo de aditivos ao aparecimento do câncer, os efeitos adversos à saúde foram observados principalmente nos estudos em que a Ingestão Diária Aceitável (IDA foi excedida. Também apontou uma carência de pesquisas sobre o transtorno do déficit de atenção e hiperatividade. Já em relação à hipersensibilidade não específica, o número de estudos foi significativo e os resultados mais consistentes quanto às manifestações clínicas de rinite, urticária e angioedema provocadas pelos aditivos, em particular pelos os corantes artificiais. As crianças aparecem como grupo vulnerável, em razão do consumo potencial de alimentos com aditivos alimentares, particularmente corantes artificiais. Os resultados indicam que estudos de consumo de aditivos alimentares deveriam servir de base para a elaboração de estratégias de vigilância alimentar e nutricional, com a finalidade de promover hábitos alimentares saudáveis.This study uses a systematic literature review to contextualize the risks associated with food additive intake. Studies comparing food additive intake and cancer showed that adverse health effects appeared when Acceptable Daily Intake (ADI was exceeded. The review also detected a lack of studies on attention deficit-hyperactivity disorder. There were more studies on non-specific hypersensitivity, highlighting such clinical manifestations as rhinitis, urticaria, and angioedema, all associated with food additives, particularly artificial colorants. Children are a vulnerable group as potential consumers of food additives, particularly artificial colorants. Studies on food additive intake should provide the basis for effective food and nutritional surveillance strategies, aiming to promote healthy eating habits.

  14. DESCOLORIMENTO DE EFLUENTE ASSOCIADO AO TINGIMENTO DE ÁGATAS CONTENDO RODAMINA B COM DIFERENTES COMBINAÇÕES FOTOCATALÍTICAS VIA PROCESSOS OXIDATIVOS AVANÇADOS (POA´s

    Directory of Open Access Journals (Sweden)

    Tiago Bender Wermuth

    2013-12-01

    Full Text Available O tingimento é um dos processos de acabamento das pedras semi-preciosas até a sua comercialização. Este é muito usado na indústria da ágata utilizando elevada demanda de água o que gera uma grande quantidade de águas residuárias, contendo moléculas corantes complexas, como a Rodamina B, que apresenta características de poluente orgânico com ecotoxicidade e genotoxicidade elevadas. Neste trabalho objetivou-se buscar o desenvolvimento de POA’s capazes de degradar os efluentes sintéticos provenientes do tingimento de pedras semi-preciosas contendo o corante Rodamina B (C.I 45170. Para uma melhor eficiência de remoção da Rodamina B, utilizou-se dois métodos distintos de fixação do catalisador utilizado. Primeiramente se trabalho com sílica-gel branca (1-3 mm, Tyvek e posteriormente com o Polietileno de baixa densidade (PEBD. Realizada a preparação dos materiais, investigou-se algumas combinações de métodos como UV/TiO2/SiO2/O3, UV/TiO2/PEBD/O3 bem como, o monitoramento de alguns parâmetros, como pH e a absorbância de amostras sintéticas. Os testes foram realizados em um reator em acrílico composto de lâmpada germicida (SCT – G13/T8/15W, onde se trabalhou com um volume útil de 1 L.Compondo ainda o reator, utilizou-se uma proveta de 1 litro e uma bomba peristáltica. A concentração de Rodamina B utilizada foi de 20 mg L-1. A partir dos resultados obtidos foi possível verificar que a combinação do UV/TiO2/PEBD/O3 mostrou-se ser mais eficiente. Essa combinação proporcionou um valor de constante cinética na ordem de 28,6 x 10-3 min-1. Se comparado aos demais processos investigados, pode-se observar que se teve um aumento do valor de k.

  15. EXTRAÇÃO DE OLEORESINA DE CÚRCUMA (Curcuma longa L COM CO2 SUPERCRÍTICO

    Directory of Open Access Journals (Sweden)

    A. Luis M. CHASSAGNEZ

    1997-12-01

    Full Text Available Dentre as fontes de corantes naturais mais utilizadas na indústria de alimentos, encontra-se a cúrcuma (Curcuma longa L, um rizoma do qual podem ser obtidas substâncias como a curcumina, demetoxicurcumina e bis-demetoxicurcumina. Estes pigmentos possuem coloração amarela e capacidade de substituir corantes artificiais. Com a finalidade de verificar a influência do pré-tratamento de secagem na extração, foram realizados experimentos de extração de oleoresina de cúrcuma com CO2 supercrítico, na unidade de extração do Laboratório de Engenharia Química da Universidade Federal do Pará, submetendo-se a matéria-prima a uma secagem nas temperaturas de 70 e 105oC. As extrações foram feitas a pressões de 200, 250 e 300 bar, e na temperatura de 45oC. Os resultados estão apresentados em tabelas e gráficos, em termos de rendimentos totais e teor de curcumina presente na oleoresina. A secagem a 70oC favoreceu a extração de oleoresina em termos de tempo de extração, e contribuiu para a manutenção de curcumina na matéria-prima.Turmeric (Curcuma longa L is one of the most used source of natural color in the food industry. Curcuminoids can be obtained from the roots of this plant. These pigments impact a yellow color and they might be able to substitute synthetic dyes. Turmeric oleoresin extraction experiments have been carried out with supercritical CO2 to investigate the influences of the pretreatment of the rhizomes on oleoresin. The extractions were conducted at the Department of Chemical Engineering of the Federal University of Pará (Universidade Federal do Pará. Turmeric was dried at 70ºC and 105ºC. Extractions have been carried out at pressures of 200, 250 and 300 bar and a temperature of 45ºC. Results shown the total yield and the content of curcumin present in the oleoresin. Amount of oleoresin extracted from the material dried at 70ºC was larger while most of the curcuminoids remained in the solid material.

  16. Microinfiltração em restaurações de resina de classe II usando diferentes técnícas restauradoras = Microleakage in class II composite restorations using different restorative techniques

    Directory of Open Access Journals (Sweden)

    Ramos, Oscar Luis Vasquez

    2006-01-01

    Full Text Available O objetivo do presente estudo foi comparar a infiltração marginal de restaurações classe II com margens cervicais em dentina utilizando diferentes técnicas restauradoras. Foram utilizados quarenta e oito molares humanos hígidos com cavidades proximais padronizadas nas faces mesial e distal com margens cervicais em dentina. Ambas, cavidades e restaurações, foram realizadas pelo mesmo operador. As cavidades foram restauradas através da técnica incremental modificada de Pollack (1988. Os dentes foram aleatoriamente divididos em quatro grupos (n = 12 e restaurados como segue: Grupo 1 (controle - Z-250 (3M/ESPE; Grupo 2 - Vitremer (3M/ESPE + Z-250; Grupo 3 - F2000 (3M/ESPE + Z-250; Grupo 4 - Flow-it (3M/ESPE + Z-250. O sistema adesivo Single Bond (3M/ESPE foi aplicado seguindo as instruções do fabricante. Após acabamento e polimento, os dentes foram termociclados por 500 ciclos, entre 5 e 55°C, e impermeabilizados com esmalte de unha, sendo imersos em corante azul de metileno a 1% por 12 horas. Os espécimes foram seccionados e a infiltração avaliada de acordo com ranking padronizado (0-3, por três avaliadores previamente calibrados. Os resultados foram submetidos à análise estatística utilizando o teste não paramétrico de Kruskal-Wallis (p < 0. 05. A penetração do corante atingiu o grau máximo na maioria dos espécimes. O grupo 1 apresentou menores valores de infiltração diferindo estatisticamente dos outros grupos. Os grupos 2 e 3 apresentaram valores intermediários, enquanto o grupo 4 teve os valores mais altos, sem, porém, ser estatisticamente diferente do grupo 3. Nenhum grupo foi capaz de selar completamente a interface adesiva

  17. Genipa americana: prospecção tecnológica

    Directory of Open Access Journals (Sweden)

    Selma Maria Santos Moura

    2016-10-01

    Full Text Available O jenipapo é uma árvore alta (10 a 15 metros, encontrada em regiões de clima tropical úmido, comum no nordeste brasileiro. Seu nome científico é Genipa americana L., jenipapo vem do Tupi-guarani jandipap, que significa fruto que serve para pintar. Apresenta caule reto, folhas verde-escuras, flores amarelo-ouro e o fruto na forma de baga ovoide, possui polpa marrom clara que envolve sementes no centro. Na alimentação humana, seu fruto é comestível ao natural e no preparo de doces, refrescos e vinho. É rico em ferro, vitaminas B1, B2, B5 e C, cálcio e hidratos de carbono. Na cultura popular têm indicações medicinais para o tratamento de afecções. Quando verde, o fruto fornece um suco azul muito utilizado como corante, transparente a princípio, o qual torna-se preto quando oxida, apresenta consistência do nanquim e no corpo, em contato com a pele, deixa manchas que desaparecem após uma semana ou mais, espontaneamente. O objetivo desta pesquisa foi realizar a prospecção tecnológica com relação à Genipa americana L., para apresentar uma visão geral sobre as tecnologias desenvolvidas relacionadas ao tema. Para isso realizou-se uma busca de patentes nas bases do European Patent Office, World Intellectual Property Organization, United States Patent and Trademark Office e no Instituto Nacional de Propriedade Industrial. Utilizando a palavra-chave Genipa americana L. foram registradas 88 patentes, quando acrescido à especificação corante encontrou-se 5 e nenhuma quando utilizou-se Genipa americana L. e célula. O Brasil registrou um número de patentes inferior ao encontrado nos USA e no Japão, sendo os anos de 2010, 2011 e 2015 os que apresentaram maior número. Ações integradas devem ser realizadas para estimular as instituições de fomento à pesquisa no intuito de viabilizar um ambiente propício à geração de inovações, fazendo do Brasil um país mais competitivo do ponto de vista tecnológico.  

  18. Ecosustainable animal manure treatment in countries with intensive breeding; Trattamento ecocompatibile delle deiezioni zootecniche in territori ad alta intensita' produttiva

    Energy Technology Data Exchange (ETDEWEB)

    Pizzichini, M. [ENEA, Divisione Biotecnologie e Agricoltura, Centro Ricerche Casaccia, Rome (Italy); Bozzini, A. [Food Agricultural Organization, Rome (Italy); Montani, R. [INTEAM Srl., Verona (Italy)

    2001-07-01

    patologie infettive a carico degli animali, danni economici per le aziende di filiera (allevatori, macelli, mangifici, distributori, etc.) e per la collettivita' (interventi sanitari, isolamento dei focolai di infezione, rimborsi economici, smaltimento delle carcasse). Da un censimento dei capi alelvati, disaggregati per ASL, si valuta il carico organico prodotto e conseguentemente vengono indicate modalita' di gestione corretta degli allevamenti e tecnologie adeguate per lo smaltimento delle deiezioni nel rispetto della recente normativa. La separazione solido-liquido delle deiezioni, con tecniche tradizionali (vibrovagli, centrifughe) consente di definire due vie di trasformazione come il compostaggio per le frazioni solide e la depurazione con processi a membrana della frazione liquida. Lo studio mira a salvaguardare i contenuti strategici d'intervento nel settore come: il miglioramento delle condizioni igieniche di stabulazione, la difesa del benessere degli animali, la gestione corretta delle deiezioni applicando tecnologie innovative e flessibili. In questo modo si puo' sviluppare un processo che riduca gli inconvenienti ambientali e di salute pubblica delle deiezioni e produca un fertilizzante organico di qualita', importante e insostituibile per lo sviluppo agronomico.

  19. Hygienic aspects of the natural organic ammendant obtained by composting; Valutazione dello stato igienico di un ammendante oranico naturale ottenuto per compostaggio

    Energy Technology Data Exchange (ETDEWEB)

    Armagliani, G. [Urbino Univ., Urbino (Italy). Centro di Biotecnologie; Sisti, M.; Schiavano, G. F.; Celeste, A. G. [Urbino Univ., Urbino (Italy). Istituto di Scienze Tossicologiche Igienistiche e Ambientali

    2001-03-01

    The Law Decree 22/97 about waste tends to favour recycling activities for energy and materials. One of these are composting processes. The product obtained by this technology, put on the market, must have the necessary hygienic qualifications. To give data regarding this matter it was evaluated, in the period 1998-2000, the microbiologic quality of a natural organic ammendant obtained by composting searching following parameters: heterotrophic microorganisms, faecal indicators, Escherichia coli, salmonellae, shigellae, Listeria monocytogenes, pseudomonas aeruginosa, staphylococci, coagulase-positive, enterovirus, protozoa cysts and helminth eggs. Same of these were also searched in the biological sludge and sludge - plant residues mix microbiological parameters. [Italian] Il Decreto Legge 22/97 in materia di rifiuti tende a favorire tutte quelle attivita' di recupero di energia e di materia. Una di queste e' rappresentata dai processi di compostaggio. Il prodotto che si ottiene con tale procedimentoe che si immette nel mercato deve rispondere a determinati requisiti di qualita' igienico-sanitaria. Allo scopo di fornire dati sulla sicurezza igienica di questo prodotto, nell'arco di triennio 1998-2000, e' stata valutata la qualita' microbiologica di un ammendante organico ottenuto per compostaggio ricercando i seguenti parametri: microrganismi eterotrofi, indici di contaminazione fecale, Escherichia coli, salmonelle, shigelle, Listeria monocytogenes, Pseudomonas aeruginosa, stafilococchi coagulasi positivi, enterovirus, cisti di protozoi e uova di elminti. Alcuni di questi parametri sono stati ricercati anche nel fango biologico e nella miscela fango - frazione vegetale quali prodotti di partenza del processo di compostaggio.

  20. Coastal dynamics physical and mathematical modelling, territorial analysis, G.I.S. instrumentation. The state of the arts; La dinamica costiera modellistica fisico-matematica, analisi del territorio, il supporto G.I.S. e la strumentazione in uso

    Energy Technology Data Exchange (ETDEWEB)

    De Bonis, P; Fattorusso, G; Onori, F; Pagano, A; Pasanisi, F; Peloso, A; Regina, P; Tebano, C; Zarlenga, F [ENEA, Div. Caratterizzazione dell' Ambiente, Centro Ricerche Casaccia, S. Maria di Galeria, Rome (Italy)

    2001-07-01

    The aim of the present work is to offer, in a single volume, the basic notions relative to different aspects, both theoretical and practical, of the study of coastal dynamical processes. It has been dealt with geological issues, physical and mathematical modelling, effects related to human activities, Geographical Information Systems as well as both laboratory and fields instrumentations. Reading this technical paper it has to keep in mind two aspects which have been authors guidelines. First of all, the research theme's have been studied on their theoretical aspects, focusing on the most recent developments. Then have been selected some up to date experiences and discuss their application. The general framework of this publication, which necessarily leave out some particular issues, for which the readers are to be referred to the references, gives a synthetic and homogenous picture of the state of the arts in coastal modelling. [Italian] Lo scopo della presente pubblicazione e' quello di offrire, in un unico volume, le nozioni di base riguardo ai diversi argomenti sia teorici sia pratici relativi all'analisi delle dinamiche costiere. Sono stati affrontati i temi relativi alla geologia, alla modellistica fisica e matematica, ai fattori di pressione antropica, all'utilizzo di Sistemi Informativi Geografici e alla strumentazione sia di campo sia di laboratorio. Nello sviluppo del presente Rapporto Tecnico si possono individuare per ciascuna delle aree di interesse due aspetti fondamentali. Dapprima i temi di ricerca sono stati studiati da un punto di vista teorico generale, con attenzione agli sviluppi piu' attuali e successivamente sono state presentate alcune recenti esperienze ed applicazioni di tali conoscenze. L'impostazione generale del presente lavoro, che sicuramente porta a trascurare alcuni aspetti particolari, per i quali si rimanda alla bibliografia, fornisce in ogni caso un quadro sintetico ed organico dello stato dell'arte dello studio della

  1. La legge "sul femminicidio"

    Directory of Open Access Journals (Sweden)

    Maria (Milli Virgilio

    2014-04-01

    Full Text Available La legge «sul femminicidio» (L. 119/2014 viene analizzata nella sua portata di legge di politica criminale e nel suo significato di primo (preteso passo legislativo verso un intervento organico, articolato e finanziato per prevenire e contrastare la violenza di genere contro le donne. Si critica la scelta del decreto legge e si analizzano i singoli contenuti, di natura penale: le norme che inaspriscono il trattamento punitivo degli autori; quelle di protezione e tutela, previste per i soggetti “deboli” ed ora estese alle donne, nonché quelle di tutela anticipata e rafforzata.\tQueste ultime sono ritenute le più significative: l’ammonimento del questore per i casi di «violenza domestica», l’allontanamento d’urgenza della casa familiare disposta dalla polizia giudiziaria e la irrevocabilità per la querela di stalking (nei casi più gravi. Le misure (penali previste sono finalizzate a far emergere il più possibile il sommerso di violenza maschile contro le donne e a porvi fine; tuttavia possono entrare in frizione con i percorsi di autonomia femminile, perché possono comprimere la volontà della donna che ha subito violenza di genere; sopravanzano il suo consenso, il suo parere e, in sintesi, la sua autonomia: o ne prescindono o la travalicano, realizzando una limitazione dell’autodeterminazione delle donne. Ha prevalso una linea pubblica interventista, agita attraverso gli strumenti della penalità e si è attribuita priorità alle logiche istituzionali repressive rispetto alla libertà femminile: non con la donna, ma anche contro lei stessa.

  2. Datazione con il radiocarbonio di ceramiche e intonaci preistorici

    Directory of Open Access Journals (Sweden)

    Marco Rossi

    2014-07-01

    Full Text Available It Vengono presentati i risultati delle analisi al radiocarbonio effettuate su frammenti di intonaco e ceramica provenienti da due siti preistorici datati al Neolitico ed all’età del Rame in Puglia. La datazione è consistita  nell’estrazione del  materiale organico identificato nella matrice inorganica dell’intonaco e della ceramica e nella successiva misura del contenuto di radiocarbonio effettuata mediante il sistema AMS (Accelerator Mass Spectrometry del CEDAD (Centro di Datazione e Diagnostica dell’Università del Salento. Il confronto dei risultati ottenuti con precedenti datazioni radiocarboniche su campioni di carbone e osso e con le informazioni archeologiche sui contesti di scavo ha consentito di verificare la qualità dei dati ottenuti. En We present the results of radiocarbon dating analyses carried out on plaster and pottery sherds found in two prehistoric sites dated to the Neolithic and Copper Age in Apulia. The dating process consisted  in the extraction of organic material identified in the inorganic matrix of the plaster and pottery samples and in the following measurement of the radiocarbon content carried out by AMS (Accelerator Mass Spectrometry at CEDAD (centre for Dating and Diagnostics at the University of Salento. The comparison of the obtained results with those previously obtained on charcoal and bone samples and  with the archaeological information on the excavated contexts supported the quality of the obtained data.

  3. Asymmetric electrooptic response in a nematic liquid crystal

    Energy Technology Data Exchange (ETDEWEB)

    Dascalu, Constanta [Politechnica University of Bucharest, Bucharest (Romania)

    2001-06-01

    An asymmetric electrooptic response in nematic liquid crystal (LC) has been obtained. The liquid crystal hybrid cell was made by using a standard configuration. One of the ITO (Indium Tin Oxide) electrodes was covered with a surfactant, which induces a homeotropic alignment. The second of the indium tin oxide electrodes was covered by a thin layer of photopolymer, which was previously mixed with an acid, which favours a process of release of protons. Such cations are responsible of electrochemical process in the LC leading to an asymmetric electrooptic response, which depend on the polarity of the applied electric field. This fact is due to an internal field, which change the effective voltage thresholds for the reorientation of the liquid crystal. During the anodic polarization, the optical switching is inhibited because the effective field decreases below the threshold value. On contrary for the opposite polarization the effective field is enough to determine a homeotropic alignment. [Spanish] Se ha obtenido una respuesta electro-optica asimetrica en cristales liquidos neumaticos. La celula hibrida de cristal liquido fue construida utilizando una configuracion estandar. Uno de los electrodos ITO fue cubierto con una pelicula delgada de material organico para inducir una alineacion homeotropa. El otro electrodo ITO fue cubierto con una pelicula delgada de fotopolimero anteriormente mezclada con un acido para favorecer la emision de protones. Estos cationes son responsables del proceso electroquimico en LC, conduciendo a una respuesta electro-optica asimetrica que depende de la polaridad del campo electrico aplicado. Este efecto es originado por un campo interno que cambia el umbral efectivo del voltaje para la reorientacion del cristal liquido. Durante la polarizacion anodica, la conmutacion optica se inhibe debido a que el campo efectivo disminuye abajo del valor del umbral. Por el contrario, para la polarizacion opuesta el campo efectivo es suficiente para

  4. Coastal dynamics physical and mathematical modelling, territorial analysis, G.I.S. instrumentation. The state of the arts; La dinamica costiera modellistica fisico-matematica, analisi del territorio, il supporto G.I.S. e la strumentazione in uso

    Energy Technology Data Exchange (ETDEWEB)

    De Bonis, P.; Fattorusso, G.; Onori, F.; Pagano, A.; Pasanisi, F.; Peloso, A.; Regina, P.; Tebano, C.; Zarlenga, F. [ENEA, Div. Caratterizzazione dell' Ambiente, Centro Ricerche Casaccia, S. Maria di Galeria, Rome (Italy)

    2001-07-01

    The aim of the present work is to offer, in a single volume, the basic notions relative to different aspects, both theoretical and practical, of the study of coastal dynamical processes. It has been dealt with geological issues, physical and mathematical modelling, effects related to human activities, Geographical Information Systems as well as both laboratory and fields instrumentations. Reading this technical paper it has to keep in mind two aspects which have been authors guidelines. First of all, the research theme's have been studied on their theoretical aspects, focusing on the most recent developments. Then have been selected some up to date experiences and discuss their application. The general framework of this publication, which necessarily leave out some particular issues, for which the readers are to be referred to the references, gives a synthetic and homogenous picture of the state of the arts in coastal modelling. [Italian] Lo scopo della presente pubblicazione e' quello di offrire, in un unico volume, le nozioni di base riguardo ai diversi argomenti sia teorici sia pratici relativi all'analisi delle dinamiche costiere. Sono stati affrontati i temi relativi alla geologia, alla modellistica fisica e matematica, ai fattori di pressione antropica, all'utilizzo di Sistemi Informativi Geografici e alla strumentazione sia di campo sia di laboratorio. Nello sviluppo del presente Rapporto Tecnico si possono individuare per ciascuna delle aree di interesse due aspetti fondamentali. Dapprima i temi di ricerca sono stati studiati da un punto di vista teorico generale, con attenzione agli sviluppi piu' attuali e successivamente sono state presentate alcune recenti esperienze ed applicazioni di tali conoscenze. L'impostazione generale del presente lavoro, che sicuramente porta a trascurare alcuni aspetti particolari, per i quali si rimanda alla bibliografia, fornisce in ogni caso un quadro sintetico ed organico dello stato dell

  5. Inhibitory action of an heterocyclic organic compound containing amine group for copper corrosion in 5,0 M nitric acid solution

    Energy Technology Data Exchange (ETDEWEB)

    El-Naggar, M.M.; Abdallah, M. [Benha Univ., Benha (Egypt). Chemistry Dept., Faculty of Science

    2000-10-01

    An heterocyclic organic compound containing amine group namely: 3-mercaptomethyl-4amino-5-hydroxy-1, 2, 4-triazole compound 1{sub a} was tested as a new inhibitor for copper corrosion in 5.0 M HNO{sub 3} solution. It proved to have a high value of inhibition efficiency (> 99.9%) at an inhibitor concentration of {>=} 2.5 x 10{sup -}3 M. A parallelism is established between the results obtained from weight loss, thermometric and galvanostatic polarization techniques. The high protective effect of compound I{sub a} is related to the decomposition of HNO{sub 2} formed through the autocatalytic cycle. The decomposition of HNO{sub 2} could be attributed to its reaction with the adsorbed inhibitor amine group. Furthermore, the results indicated that compound I{sub a} provides long-term protection and behaves as a mixed inhibitor type with a predominant cathodic effectiveness. [Italian] E' stato valutato, quale nuovo inibitore della corrosione del rame in soluzione 5.0 M di HNO{sub 3}, un composto organico eterociclico contenente un amino gruppo, chiamato: 3-mercaptometil-4amino-5-idrossi-1, 2, 4-triazolo composto I{sub a}. Questi, ad una concentrazione {>=} 2.5 x 10{sup -}3 M, ha dimostrato di possedere un elevato valore di efficienza di inibizione (> 99.9%). E' stato stabilito un parallelismo tra i risultati ottenuti dalla perdita di peso, da misure termometriche e di polarizzazione galvanostatica. L'elevato effetto protettivo del composto I{sub a} e' correlato alla decomposizione dell'HNO{sub 2} formatosi attraverso il ciclo autocatalitico. La decomposizione di HNO{sub 2} puo' essere attribuita alla sua reazione con il gruppo inibitore aminico adsorbito. Inoltre, i risultati indicano che il composto I{sub a} fornisce una protezione a lungo termine e si comporta come un inibitore di tipo misto con una predominante efficienza catodica.

  6. Dosage of high COD industrial wastewaters as an external carbon source in the pre-denitrification step of activated sludge plants; Utilizzo di reflui industriali a elevato COD come fonte esterna di carbonio in pre-denitrificazione negli impianti a fanghi attivi

    Energy Technology Data Exchange (ETDEWEB)

    Bertanza, G.; Collivignarelli, C.; Pedrazzani, R. [Brescia Univ., Brescia (Italy). Facolta' di Ingegneria, Dipt. di Ingegneria Civile

    2001-04-01

    In pre-denitrification plants, the organic carbon shortage in the influent wastewater can inhibit the denitrification process. In this case, the dosage of organic substrates can be considered, when the F/M ratio in the nitrification stage is adequate. Beside commonly available substances (acetic acid, methanol etc.) industrial wastewaters can be dosed. This research was aimed to assess the feasibility of this alternative, by testing several industrial wastewaters in addition to real municipal wastewater. The experiment consisted in running a continuous-flow activated sludge pilot plant and in carrying out NUR (Nitrogen Uptake Rate) tests. The studied wastewaters derive from the food industry and, more precisely, from cocoa working and from the cold drink industry. Results were compared with two reference situations (dosage of sodium acetate and of an available organic solution). [Italian] Negli impianti con pre-denitrificazione, il processo di denitrificazione puo' essere inibito dalla carenza di carbonio organico nel liquame influente. Un rimedio (applicabile qualora il carico del fango in nitrificazione sia compatibile) consiste nel dosaggio di substrati carboniosi. Accanto alle soluzioni commercializzate (acido acetico, metanolo, ecc.) e' possibile dosare reflui industriali aventi caratteristiche adeguate. Nel presente studio si e' voluta verificare tale alternativa mediante una sperimentazione svolta su liquame fognario a cui sono stati aggiunti, di volta in volta, diversi substrati carboniosi. Le prove sono state effettuate sia in continuo (mediante l'impiego di un impianto pilota a fanghi attivi) sia in batch (test di NUR - Nitrogen Uptake Rate). I reflui studiati originano dall'industria alimentare, in particolare, dalla laovrazione del cacao e dalla produzione di bevande analcoliche. I risultati sono stati confrontati con due situazioni di riferimento (dosaggio di acetato di sodio e di una soluzione carboniosa disponibile in

  7. Niveles y distribución de metales pesados en el agua de la zona de playa de Riohacha, La Guajira, Colombia

    Directory of Open Access Journals (Sweden)

    Carlos Doria Argumedo

    2015-03-01

    Full Text Available La zona de playa de Riohacha, La Guajira, Colombia, constituye un ecosistema muy rico, diverso y productivo, dotado de gran capacidad para proveer bienes y servicios que sostienen actividades como pesca, turismo y navegacion; sin embargo, experimenta problematicas ambientales producto de la dinamica de la ciudad, relacionadas con la infiltración de aguas residuales, acumulacion de residuos solidos organicos y descargue de sedimentos del rio Rancheria. En la metodologia de esta investigación se tomaron muestras de agua de mar en cuatro puntos de un sector de aproximadamente 2.5 km de playa, durante ocho meses en el ano 2013, en epocas de lluvia y sequia. Los metalesanalizados fueron Cobalto, Cobre, Zinc, Aluminio, Manganeso, Niquel y Hierro. Las concentraciones de los metales Ni y Zn, considerados muy toxicos, se encontraron por encima de los niveles segun la normativa nacional y algunas establecidas a nivel internacional, para efectos agudos en aguas marinas y estuarinas destinadas a la preservacion de fauna y flora; las concentraciones de Cu y Zn, se encuentran por debajo de los limites establecidos por la EEA y la EPA. La correlacion significativa existente entre las concentraciones de los metales Fe, Mn, Zn, Co con los nutrientes nitrato y fosfato, indica posible acumulacion de ellos en el sedimento e incluso bioacumulacion en la fauna asociada a esta zona. La presencia y concentraciones de los metales son producto, principalmente, de la intervención humana en las labores de mineria y en el ciclo biogeoquimico de los metales.

  8. Producción orgánica para una alimentación sana

    Directory of Open Access Journals (Sweden)

    Evangelina Méndez

    2016-06-01

    Full Text Available El presente trabajo se relaciona con la importancia del uso de fertilizantes o abonos orgánicos, como base para la producción de alimentos orgánicos, que incluye pruebas de laboratorio y la instrumentalización de encuestas a los grupos objetivos de insumos y productos orgánicos. Este artículo tiene como propósito dar a conocer los beneficios nutritivos de los productos orgánicos. El cuidado del medio ambiente y el interés por una alimentación sana han dado lugar al uso de fertilizantes orgánicos en cultivos, facilitando la producción de alimentos frescos y sanos, libres de sustancias tóxicas conocidos como alimentos orgánicos. Durante las actividades del proyecto de investigación IC-ULVRG12-10 "GUIA PARA EXPORTAR ABONO ORGANICO HACIA LOS PRINCIPALES MERCADOS DE ESTADOS UNIDOS, EUROPA y SUDAMERICA" la muestra encuestada demostró que no se encuentra lo suficientemente concientizada sobre el uso y beneficio de los productos orgánicos, sin embargo existe interés por parte del consumidor al consultar directamente en el lugar de compra sobre los mismos, especialmente los vegetales. Durante la investigación experimental las pruebas de laboratorio confirman el alto valor nutricional que aportan los abonos orgánicos al suelo y a las plantas.

  9. The biological degradation as an energy option, determination of the effects of the aerobic phase on the subsequent production of biogas in a sanitary landfill; La degradacion biologica como una opcion energetica, determinacion de los efectos de la fase aerobia sobre la subsecuente produccion de biogas en un relleno sanitario

    Energy Technology Data Exchange (ETDEWEB)

    Aguilar Juarez, Oscar [Asesoria de Servicios Ambientales del Bajio (ASSB), (Mexico)

    2010-07-01

    The present work deals with the energy evaluation of biological processes as energy source and is based on works concerning laboratory, pilot and field research. The objective of the research is to integrate the effect of the aerobic phase during the process of degradation of organic residues (basically the organic fraction of domestic residues), where the last aim is the biogas production. The usefulness of the results is reflected in the suitable estimation of the filling of a sanitary landfill considering the composition of the residues deposited and the effects that this management will have on the run-up time of the same and the velocity of biogas production. Finally, integrates a reflection on the intrinsic energy implications of the process and of the biogas yielding, which is evaluated as well as energy source. [Spanish] El presente trabajo trata sobre la valoracion energetica de procesos biologicos como fuente de energia y se basa en trabajos de investigacion a nivel de laboratorio, piloto y de campo. El objetivo de la investigacion es integrar el efecto de la fase aerobia durante el proceso de degradacion de residuos organicos (basicamente la fraccion organica de residuos domesticos), donde el fin ultimo es la produccion de biogas. La utilidad de los resultados se refleja en la estimacion adecuada del llenado de un relleno sanitario considerando la composicion de los residuos ahi depositados y los efectos que tendra esta gestion sobre el tiempo de estabilizacion de los mismos y la velocidad de produccion de biogas. Finalmente, se integra una reflexion sobre las implicaciones energeticas intrinsecas al proceso y del rendimiento de biogas, el cual a su vez es valorizado como fuente de energia.

  10. Comparação entre métodos para testar a viabilidade de pólen de pessegueiro Comparison among methods for testing pollen viability

    Directory of Open Access Journals (Sweden)

    Patrícia Milech Einhardt

    2006-04-01

    Full Text Available Para o sucesso das hibridações controladas, é importante que o pólen a ser utilizado tenha boa viabilidade (> 30%. Os métodos para testá-la podem ser classificados em quatro tipos: 1- uso de corantes; 2-germinação in vitro; 3- germinação in vivo; 4- porcentagem de frutificação efetiva, obtida com a utilização do pólen em teste. No presente trabalho, realizado em agosto de 2004, fez-se uma comparação entre os três primeiros métodos citados acima, utilizando-se de amostras de pólen de pessegueiro, coletadas em 2003, de cinco cultivares: Esmeralda, Eldorado, Granada, Maciel e Vanguarda. O meio de cultura utilizado para a germinação in vitro foi constituído de 10g de açúcar cristal e 1g de ágar para 100ml de água destilada. Para a germinação in vivo foram emasculadas e polinizadas, em laboratório, flores de ramos coletados no campo e mantidos em frascos com água. Seguiu-se a metodologia utilizada em microscópio de rotina, com corante diferencial a fim de observar os tubos polínicos no estigma ou pistilo. No método de coloração, foi utilizado carmim como corante. Os resultados da análise de variância mostraram que as diferenças entre cultivares, entre métodos e a interação cultivar e método foram altamente significativas. O método de coloração, usando carmin propiônico como corante, foi significativamente superior à germinação in vivo, em todas as cultivares testadas. A germinação in vitro propiciou resultado estatisticamente igual à germinação in vivo, com exceção das cultivares Esmeralda e Granada, nas quais a germinação in vitro foi superior. Entretanto, a maior diferença entre os dois métodos foi de 10,03% na cultivar Esmeralda que, embora estatisticamente significativa, na prática, seria aceitável em testes de rotina. Concluiu-se que o teste in vitro é representativo da situação in vivo, enquanto o método de coloração superestimou a porcentagem de pólen viável.It is important

  11. Evaluation of sugar-cane bagasse as bioadsorbent in the textile wastewater treatment contaminated with carcinogenic congo red dye

    Directory of Open Access Journals (Sweden)

    Aline Sartório Raymundo

    2010-08-01

    Full Text Available A methodology involving sugar cane bagasse bioadsorbent was developed in order to remove the carcinogenic congo red dye from aqueous medium. The results showed high efficiency with retention of 64 ± 6% in synthetic congo red solution and 94 ± 5% in effluent enriched with congo red, at 10.0 g of the bioadsorbent. The adsorption system provided a maximum adsorption capacity of 4.43 mg/g. Tests showed independence adsorption properties, when compared with the column flow rates. The treatment units could be operated with flexibility. From the results, it was possible to conclude that sugar cane bagasse could be an adequate bioadsorbent.Neste trabalho foi desenvolvida uma metodologia de remoção do corante carcinogênico congo red de sistemas aquosos. Os resultados mostraram uma elevada eficiência de remoção sendo de 64 ± 6% para soluções sintéticas de vermelho congo, e 94 ± 5% para efluente industrial enriquecido com vermelho congo utilizando 10 g de bioadsorvente. A capacidade máxima adsotiva encontrada foi de 4,43 mg/g. Os testes de percolação revelaram independência das porcentagens adsortivas em relação às vazões das colunas. Estes resultados indicam viabilidade de uso do bagaço de cana-de-açucar no tratamento de efluentes contendo o congo red.

  12. Estudo comparativo da infiltração marginal em restaurações de classe V

    Directory of Open Access Journals (Sweden)

    FARIAS Débora Gonçalves de

    2002-01-01

    Full Text Available Este estudo teve como objetivo avaliar o comportamento laboratorial de adesivos dentinários, cimentos ionoméricos modificados por resina e resinas compostas modificadas por poliácidos, no selamento das margens gengivais de cavidades de classe V preparadas na junção amelocementária. Quarenta cavidades foram executadas nas faces vestibular e palatina/lingual de 20 terceiros molares humanos extraídos, e restauradas com os seguintes materiais: grupo 1 (G1- Vitremer (3M; grupo 2 (G2- Vitremer (3M e Syntac Sprint/Tetric Ceram (Vivadent; grupo 3 (G3- Syntac Sprint/Tetric Ceram (Vivadent; grupo 4 (G4- Prime & Bond 2.1/Variglass (Dentsply. Após termociclagem em corante azul de metileno, os espécimes foram seccionados longitudinalmente e analisados em lupa estereoscópica para avaliação do grau de infiltração marginal. Os resultados após teste estatístico de Mann-Whitney revelaram melhor vedamento marginal para o grupo 1, quando comparado com o grupo 4 (p = 0,05, mas não foram demonstradas diferenças significantes entre os demais grupos. Nas condições desse experimento, o material Vitremer ofereceu melhor vedamento marginal que o sistema Prime & Bond 2.1/Variglass.

  13. As clorofilas

    Directory of Open Access Journals (Sweden)

    Streit Nivia Maria

    2005-01-01

    Full Text Available As clorofilas são pigmentos verdes, comuns em todas as células fotossintéticas. Por sua estrutura química ser instável, são facilmente degradadas, resultando em produtos de decomposição que modificam a percepção e qualidade dos alimentos. Esta revisão trata dos vários fatores que interferem na degradação das clorofilas, como a luz, radiação, calor, ácidos, oxigênio, alteração enzimática e interação com outros pigmentos. Também, outro aspecto a ser abordado é a utilização das clorofilas como corantes, através da formação de complexos que tornam esses pigmentos mais estáveis à decomposição.

  14. Degradação de xenobióticos por fungos filamentosos isolados de areia fenólica

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    J. H. Silva

    2000-09-01

    Full Text Available Microrganismos foram isolados de areia fenólica resultante de atividades metalúrgicas, utilizando meio mínimo para fungos e pentaclorofenol (PCF como única fonte de carbono. Após quatro repiques sucessivos em intervalos de 15 dias de incubação, as culturas foram plaqueadas em meio de Martin. Três gêneros de fungos foram isolados e identificados como Acremonium sp., Paecilomyces sp. e Penicillium sp. Estes foram testados para degradar os corantes índigo e RBBR (Azul Brilhante de Remazol - R e o organoclorado PCF. A descoloração do índigo foi de 99%, para Paecilomyces e Penicillium, e de 74%, para Acremonium, e a de RBBR foi de 16%, para Penicillium; 14%, para Acremonium, e 5%, para Paecilomyces. Usando azul de bromotimol como indicador de degradação de PCF, foram obtidos 24% de descoloração para Acremonium; 22%, para Penicillium, e 17%, para Paecilomyces Utilizando cromatografia gasosa, detectou-se degradação de PCF de 69%, para Penicillium; 65%, para Paecilomyces, e 40% para Acremonium, respectivamente. Os resultados mostraram que foi possível isolar microrganismos de uma areia de fundição, altamente contaminada com fenóis, e os fungos isolados foram capazes de degradar PCF e outros xenobióticos testados.

  15. Influence of light intensity and curing cycle on microleakage of Class V composite resin restorations Influência da intensidade de luz e métodos de fotoativação no selamento marginal de restaurações classe V em resina composta

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    Maria Jacinta M. Coelho Santos

    2005-06-01

    intuito de situar as margens cavitárias em dentina. Os dentes foram divididos em cinco grupos de acordo com o método de fotoativação. As cavidades, depois de condicionadas, foram tratadas com o sistema adesivo Single Bond (3M Dental e restauradas com a resina composta Z100 (3M Dental pela técnica incremental. A fotoativação foi realizada para cada grupo como descrito a seguir: Grupo I: PAC pelo método de fotoativação constante: 1600mW/cm² - 3s; Grupo II: PAC pelo método de fotoativação por passos (800mW/cm² - 2s, subindo automaticamente para 1600mW/cm² - 4s; Grupo III: QTH pelo método de fotoativação constante: 400 mW/cm² - 40s; Grupo IV: QTH pelo método de fotoativação em rampa: 100 a 600 mW/cm² - 15s, permanecendo a 600mW/cm2 por mais 25s; Grupo V: QTH pelo método de fotoativação por pulso: 200 mW/cm² - 3s, tempo de espera de 3min.e a seguir 600mW/cm² - 30s. Os dentes foram armazenados em água destilada a 37ºC por 30 dias e então submetidos à ciclagem térmica, por 500 ciclos à 5 ºC e 55 ºC. Os ápices dos dentes foram selados com resina composta e os dentes foram cobertos com duas camadas de esmalte para unha, antes da sua imersão em fucsina básica a 0,5%. Os dentes foram seccionados e os cortes foram escaneados para avaliação da área infiltrada por corante por um programa de computador (Image Tools. Os cortes foram também visualizados com lupa para a determinação do grau de penetração do corante na interface dente-restauração por escores. Diferenças estatisticamente significantes foram observadas entre os grupos quanto ao grau e à área de penetração de corante (p < 0,05. Os grupos I e II apresentaram valores significantemente mais altos de infiltração e penetração do corante que os grupos III, IV e V. Em conclusão, o uso da fonte de PAC, no modo constante e por passos, resultou em valores significantemente maiores de infiltração marginal quando comparados com a intensidade de luz média emitida pelos

  16. CARACTERIZAÇÃO QUÍMICA DAS ANTOCIANINAS DO FRUTO DE JUÇARA (Euterpe edulis MARTIUS

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    Natalia Caroliny da Silva Dias

    2017-04-01

    Full Text Available A antocianina é um pigmento presente no reino vegetal com inúmeras funções indo desde coloração até bioatividade em diversos sistemas. Atualmente, as indústrias de alimentos têm investido em pesquisas e procurado substituir seus aditivos sintéticos por compostos naturais, os quais têm se tornado uma ferramenta atrativa no mercado como corante a alimentos e prevenção do processo oxidativo. Este trabalho teve como objetivo caracterizar as antocianinas presentes no extrato de Juçara das amostras coletadas na região Sul e Caparaó do estado do Espírito Santo. Os resultados encontrados na análise de pH diferencial do extrato foi 20,94 ± 1,57 µg/g de Antocianina Monomérica do extrato. O município de Alegre apresentou o maior teor de açúcar total e redutor, respectivamente 6,87 ± 1,17 e 6,12 ± 2,37. As antocianinas existentes no juçara possui capacidade de inserção no mercado, uma vez que os dados comprovam a sua presença expressiva no fruto.

  17. Use of remazol blue dyed avicel for the determination of cellulolytic activity in basidiomycetes Uso de Avicel colorida com Remazol Blue para determinação da atividade celulolítica em Basidiomycetos

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    Marcos José Correia

    1998-10-01

    Full Text Available A modified method for direct determination of cellulolytic activity using Avicel colored with Remazol Brilliant Blue R (RBBR in Agar test tubes is discussed. Refinements were introduced in a simple method for quantitation of cellulase activity, based on the release of dye from Avicel-RBBR medium by the enzymatic hydrolysis. Modifications in Avicel-dye preparation were enhanced and a spectrophotometer for direct OD measurement in agar test tubes used. The use of a spectrophotometer improved the precision of the collected data, since absorbance measurements could be done at the maximum wavelenght for RBBR (595 nm.Neste trabalho, é discutido um método modificado para determinação da atividade celulolítica em fungos utilizando Avicel colorida com Remazol Brilliant Blue R (RBBR, diretamente em tubos com ágar, a partir de refinamentos introduzidos em uma metodologia simples e baseada na liberação deste corante pela ação hidrolítica em Avicel colorida com o RBBR. Foram feitas modificações no preparo da Avicel colorida, bem como um espectrofotômetro para medição direta da absorbância nos tubos com ágar foi usado. O uso de espectrofotômetro aumentou a precisão dos dados coletados, pois permitiu leituras de absorbância no comprimento de onda máximo para RBBR (595 nm.

  18. Avaliação da apresentação comercial de escovas dentais disponíveis no Brasil = Evaluation of commercial characteristics of toothbrushes available in Brazil

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    Feitosa, Natália Bueno

    2008-01-01

    Full Text Available Objetivo: A proposta deste estudo foi avaliar a apresentação comercial de 15 escovas dentais destinadas ao público infantil. Metodologia: As escovas foram adquiridas em diferentes pontos de venda na cidade de Belo Horizonte, MG. Foram avaliados: fabricante, dureza das cerdas, instruções sobre o uso do produto, indicação de idade, tempo de uso, desenhos de personagens infantis, selo da Associação Brasileira de Odontologia (ABO, preço, material utilizado no cabo, comprimento das cerdas (mm e presença de corante nas cerdas. Resultados: Um total de 87% das escovas informava sobre a necessidade de troca a cada 3 meses, 73% instruíam sobre uso, 47% possuíam o selo da ABO, 60% apresentavam desenhos infantis e 73% possuíam cerdas de 10 mm de comprimento. O preço variou entre R$1,00 a R$8,55. Conclusão: Os fabricantes utilizaram estratégias publicitárias para atrair as crianças e motivar o consumo, mas muitas escovas não apresentaram informações importantes como selo da ABO, instruções de uso, tempo de uso e idade indicada. O reforço e a orientação do dentista são fundamentais para motivar o paciente sobre a higiene bucal adequada

  19. Endoscopia de contato (microestomatoscopia nas lesões da boca e do lábio: avaliação do método

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    Gyl H A Ramos

    Full Text Available OBJETIVO: Descrever as dificuldades da endoscopia de contato aplicada à boca e ao lábio (microestomatoscopia de contato e aplicar nas lesões do lábio os critérios usados na endoscopia de contato de outras topografias. MÉTODO: Estudo prospectivo utilizando o endoscópio de contato Storz 8715A e o corante azul de toluidina. Vinte exames foram feitos para aprendizado da técnica e depois mais 31 (21 lesões do lábio e 10 da boca, todos exames in vivo. Os critérios avaliados foram: Celularidade, Arquitetura, Estratificação e Morfologia. RESULTADOS: A falta de nitidez, os tremores finos e o deslizamento do aparelho dificultaram o procedimento em 100% dos casos, mas permitiram um exame adequado. Os 13 diagnósticos de malignidade das lesões do lábio apresentaram todos os critérios alterados. CONCLUSÃO: as dificuldades encontradas foram o contato do aparelho com a superfície anatômica, o deslizamento do aparelho, os tremores finos e a falta de nitidez da imagem, que não inviabilizaram a realização e a interpretação do exame. Os critérios são aplicáveis às lesões da boca e do lábio inferior.

  20. Estudos de freqüência, morfologia e diagnóstico de Entamoeba gingivalis, Gros, 1849

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    Silvio Favoreto Junior

    1995-12-01

    Full Text Available Realizamos estudos de freqüência de Entamoeba gingivalis entre 100 pacientes atendidos nos ambulatórios odontológicos da Ufiiversidade Federal de Uberlândia (UFU, utilizando-se esfregaços corados pela técnica de Papanicolaou modificado, revelando um expressivo índice de 62% de positividade. A afinidade do corante pelo conteúdo vacuolarfagocítico impede uma nítida visualização das cromatinas central e periférica do núcleo do parasita. Lavados bucais de outros 10 pacientes foram utilizados para avaliar em qual método parasitológico de diagnóstico (a fresco e em coloração por hematoxilina férrica, Giemsa e Papanicolaou ocorre melhor visualização do parasita. O exame afresco do sedimento do lavado bucal revelou 100% de positividade e nítida visualização do parasita. Nenhuma técnica de coloração dos esfregaços se mostrou adequada, apresentando o núcleo freqüentemente mascarado pelos vacúolos fagocíticos. Em preparações coradas por azul de toluidina e na microscopia eletrônica de transmissão pode-se observar caracteres morfológicos típicos do protozoário.

  1. A bone tissue engineering strategy based on starch scaffolds and bone marrow cells cultured in a flow perfusion bioreactor

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    Gomes, Maria Manuela Estima

    A Engenharia de Tecidos e uma area cientifica em continua expansao. Os desenvolvimentos conseguidos por esta area tem contribuido significativamente para diversos avancos no campo da Medicina Regenerativa. Esta ciencia interdisciplinar combina os conhecimentos de diversas outras areas, tao distintas como a Engenharia de Materiais e a Biologia, com o objectivo de desenvolver substitutos sinteticos para tecidos humanos. Para se atingir este objectivo utilizam-se, de uma forma generica, combinacoes especificas de celulas e de um material de suporte tridimensional com propriedades adequadas, gerando um material hibrido cujas caracteristicas podem ainda ser moduladas atraves do sistema de cultura usado. A presente tese e centrada no desenvolvimento de estrategias de engenharia de tecido osseo baseadas na cultura in vitro de celulas previamente "semeadas" num suporte tridimensional ("scaffold"). Esta estrategia permite que as celulas adiram ao suporte, proliferem e segreguem matriz extracelular especifica do tecido osseo, ate se obter um substituto artificial funcional com caracteristicas do tecido original, que pode finalmente ser transplantado para tratar o defeito em causa. Para que uma estrategia deste tipo seja bem sucedida, pelo menos tres componentes fundamentais devem ser cuidadosamente estudados: o material de suporte (scaffold), as celulas a usar e o sistema de cultura in vitro. Dai que os principais objectivos desta tese estejam relacionados com estes tres aspectos, nomeadamente: • Desenvolvimento de scaffolds biodegradaveis a partir de polimeros a base de amido de milho que induzam a adesao e proliferacao celular e que apresentem propriedades adequadas, tais como a porosidade e interconectividade entre poros, de forma a proporcionar um ambiente que favoreca o desenvolvimento in vitro de um material hibrido com caracteristicas similares ao osso humano. • Estudo da utilizacao de celulas da medula ossea como uma potencial fonte de celulas para engenharia do

  2. Carotenoides bixina e norbixina extraídos do urucum (Bixa orellana L. como antioxidantes em produtos cárneos Carotenoids bixin and norbixin from annatto (Bixa orellana L. as antioxidants in meat products

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    Carlos Eduardo Rocha Garcia

    2012-08-01

    Full Text Available A oxidação lipídica é uma das principais alterações que acometem os derivados cárneos em razão da composição química rica em lipídios e íons ferro, utilização de processos térmicos e de moagem, além do frequente uso do cloreto de sódio, um reconhecido catalisador desta reação. Os antioxidantes são substâncias utilizadas para inibir ou retardar a rancidez oxidativa, porém, seu uso desperta a atenção de consumidores e agências reguladoras, quanto à segurança que acompanha o consumo de aditivos sintéticos. Este trabalho teve por objetivo avaliar o uso dos carotenoides bixina e norbixina como antioxidantes em produtos cárneos por meio da revisão de suas características químicas, métodos de obtenção, toxicidade e aplicações tecnológicas. Esses pigmentos são extraídos das sementes do urucum (Bixa orellana L. por métodos que envolvem o uso de solventes orgânicos, extração supercrítica ou ainda a utilização da tecnologia de micro-ondas. No Brasil, o uso dessas substâncias é previsto na legislação como corante alimentício, porém, estes carotenoides apresentam extensas cadeias carbônicas insaturadas que permitem a adição de radicais livres e lhes conferem a capacidade de atuar como antioxidantes. As diferenças estruturais entre bixina e norbixina resultam em particularidades quanto à polaridade, solubilidade, coloração e, por consequência, determinam singulares aplicações tecnológicas. Nas concentrações previstas pelas agências reguladoras, o consumo desses carotenoides é seguro e além das aplicações como corante, podem ser utilizados pela indústria como antioxidantes naturais, oportunizando uma alternativa capaz de substituir ou minimizar o uso de aditivos sintéticos em produtos cárneos.Lipid oxidation is one of the major modifications that affect meat products due to chemical composition, heat and grinding processes beyond the routine use of sodium chloride, a recognized catalyst

  3. Generalização por 'reforço' ou 'contraste' no tratamento do desvio fonológico Generalization by 'reinforcement' or 'contrast' in the treatment of phonological disorders

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    Márcia Keske-Soares

    2008-01-01

    Full Text Available O objetivo deste estudo foi verificar as mudanças fonológicas obtidas pelo tratamento com o Modelo de Oposições Máximas Modificado, utilizando a abordagem do 'reforço' ou 'contraste', em sujeitos com diferentes graus de severidade do desvio fonológico (DF. Três sujeitos com DF, do sexo masculino, com idade média de seis anos e diferentes graus de severidade de DF, foram submetidos às avaliações fonoaudiológicas, incluindo a fonológica, e exames complementares. Posteriormente, foram submetidos à terapia fonológica pelo modelo de Oposições Máximas Modificado, considerando-se a abordagem do 'reforço' ou 'contraste' de traços distintivos e verificadas as seguintes generalizações: para itens não utilizados no tratamento; para outra posição na palavra; dentro de uma mesma classe de sons; e para outra classe de sons. O inventário fonético dos três sujeitos estava completo após a terapia; porém, o sistema fonológico estava incompleto para todos os sujeitos tratados. O S1 tratado, utilizando contraste com [dors/cor] e [±cont], após tratamento permaneceu com dificuldade com [dors] e [-voc]. O S2 tratado pelo reforço com o [+voz], após tratamento persistiu com dificuldade com [+voz]. O S3 tratado pelo reforço com [+soant], [-voc], [+voz] e [cor/+ant], apresentou pós-tratamento dificuldade apenas com [-voc]. Após o processo terapêutico, observou-se evolução para todos os tipos de generalização estrutural analisados. Verificou-se que tanto os sujeitos tratados pelo 'reforço', quanto o tratado pelo 'contraste' apresentaram generalizações, não podendo diferenciar qual abordagem foi mais eficaz no tratamento do DF.The aim of this study was to verify the phonological changes obtained with treatment by the Modified Maximal Oppositions Model, using "reinforcement" or "contrast" approach, in subjects with different severity levels of phonological disorders (PD. Three male children, mean age six years old, with

  4. Morphology and pollen viability of Lolium multiflorum Lam. Morfologia e viabilidade polínica de Lolium multiflorum Lam.

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    Renata de Castro Nunes

    2012-04-01

    Full Text Available Study and characterization of pollen grains are essential for different areas, especially taxonomy, genetic improvement, phylogeny, and paleobotany. As yet, there are no reports on pollen morphology of genotypes of naturalized Lolium multiflorum Lam., introduced cultivars or breeding populations, diploid or polyploid. Ten genotypes of annual ryegrass (L. multiflorum were evaluated for the viability of pollen grains using propionic carmine and Alexander's stains, while morphology was assessed by the acetolysis technique. Measures of polar axis (P, equatorial diameter (E, exine thickness, and analysis of pollen grains were obtained by scanning electron microscopy (SEM. All genotypes showed high rate of pollen viability (> 89% for both stains. There were differences between genotypes in the following quantitative traits: polar axis, equatorial diameter, exine, endexine, ektexine, and P/E ratio. Pollen grains were characterized as small, monoporates, with circular and non-prominent apertures. In addition to helping distinction of pollen grains, morphometric differences can be used later to compare ploidy levels, thus assisting in breeding programs of the species.O estudo e a caracterização do grão de pólen são fundamentais para diferentes áreas, em especial, para a taxonomia, o melhoramento genético, a filogenia e a paleobotânica. Para genótipos de Lolium multiflorum Lam., naturalizados no Brasil, cultivares introduzidas ou populações de melhoramento, diploides e poliploides, não existem relatos sobre a caracterização morfopolínica. Nesse trabalho foram analisados dez gentótipos de azevém anual (L. multiflorum. A viabilidade dos grãos de pólen foi verificada por coloração com os corantes carmim propiônico e Alexander e a morfologia por meio da técnica de acetólise, sendo obtidas medidas do eixo polar (P, do diâmetro equatorial (E, e da espessura da exina, e análise dos grãos de pólen por microscopia eletrônica de

  5. Estudo da estabilidade química da magnetita utilizada como adsorvedor na remoção de compostos orgânicos de soluções

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    Ortiz N.

    2003-01-01

    Full Text Available Um resíduo siderúrgico composto predominantemente por magnetita (Fe3O4 finamente dividida foi empregado como material adsorvedor não convencional na adsorção e fixação de compostos corantes orgânicos tóxicos. Estudos preliminares indicaram que a magnetita quando utilizada em meio ácido (pH<3 sob agitação contínua pode apresentar diversos graus de desagregação e de solubilização. Este efeito é indesejável em sistemas adsortivos porque representa redução na porcentagem de remoção de composto tóxico orgânico e possível aumento de contaminação por produtos de dissolução e de desagregação da magnetita. Soluções de metasilicato de sódio, sulfato de ferro e hidróxido de sódio foram empregadas nos processos de estabilização de quatro frações granulométricas da magnetita usadas como adsorvedor não convencional em meio ácido. Os resultados obtidos permitiram concluir que o tratamento com metasilicato de sódio das frações de magnetita resulta em redução de 1% nos valores de remoção de composto tóxico corante da solução (de 98% para a fração sem tratamento para 97% para a fração com tratamento com metasilicato e redução nos valores de constante de velocidade de adsorção (k ab de 30.10-3 mg.g-1.min-1 para 10.10-3 mg.g-1.min-1. Embora tenha sido observada redução na capacidade adsortiva das frações tratadas e na velocidade de adsorção, este efeito foi considerado aceitável comparando-se o aumento da estabilidade química e redução nos valores de perda de massa em 46%. Analisando-se as isotermas obtidas para as frações #30 com e sem tratamento, pode-se confirmar que o tratamento com metasilicato promoveu um processo de adsorção mais favorável, com menor interferência dos processos de dissolução, de desagregação e maior correspondência com o modelo de Freundlich.

  6. Comparison of the cleaning efficacy of the FKG race system and hand instrument in molar root canal Comparação da eficácia de limpeza entre o sistema FKG race e instrumentos manuais em molares inferiores

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    Carla Renata Sipert

    2006-01-01

    Full Text Available INTRODUCTION AND OBJECTIVE: The aim of this study was to evaluate the ability of root canal cleaning of the RaCe rotary instrumentation system (FKG Dentaire - La-Cheaux-de Fonds - Switzerland, compared to manual filing with Stainless Steel K-files (Maillefer Instruments - Ballaigues - Switzerland. MATERIAL AND METHOD: Twenty extracted human teeth (maxillary molars were selected and their pulp tissue was removed after coronal access. The root canals were filled with a dye (India ink and allowed to dry for 48 hours, followed by establishment of the working length of the mesiobuccal root; then, half of the specimens were instrumented by the modified Oregon technique and the other half were instrumented by crown-down sequence of the RaCe system. After preparation, the teeth were longitudinally sectioned and evaluated according to the amount of remaining dye. RESULTS: Data obtained were registered as numerical scores, and the arithmetic means were compared between groups using the Mann Whitney test. Both techniques were unable to completely clean the interior of the root canals, with a better performance of the manual technique only at the middle third. CONCLUSION: It could be concluded that the RaCe system was able to provide satisfactory cleaning, similar to that obtained by the manual instrumentation technique.Objetivo deste trabalho foi avaliar a capacidade de limpeza de canais radiculares por meio do sistema de instrumentação RaCe (FKG Dentaire - La-Cheaux-de Fonds - Suíça em comparação à instrumentação manual por meio de limas tipo K-File (Maillefer Instruments - Ballaigues - Suíça. Foram selecionados 20 dentes humanos extraídos (molares superiores que tiveram seu conteúdo radicular removido após realização da abertura coronária. Os canais foram preenchidos com corante (tinta nanquim e após 48 horas para secagem, realizou-se a odontometria da raiz mésio-vestibular. Metade dos espécimes foi instrumentada pela técnica de

  7. Effect of diode laser irradiation on the apical sealing of MTA retrofillings Efeito da irradiação de laser de diodo no selamento apical em retrobturações com MTA

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    Eliana Barbosa de Souza

    2006-09-01

    ógradas. As raízes foram divididas aleatoriamente em 2 grupos. O grupo 1 (dez espécimes foi retrobturado com MTA, e o grupo 2 sofreu irradiação de laser de diodo na potência de 1 W por 20 s na superfície apical e na cavidade retrógrada antes da obturação com MTA. Os espécimes foram impermeabilizados externamente com cianoacrilato, com exceção da superfície apical, imersos em corante rodamina B a 1% por 72 h, incluídos em gesso e posteriormente desgastados no sentido longitudinal até obter-se metade da raiz. Foi feita a leitura da infiltração linear do corante nessas hemi-raízes, entre a parede do canal radicular e a retroobturação, com auxílio do programa de computação Image Lab. Os resultados foram analisados estatisticamente pelo Teste t de Student. Não houve diferença estatística significante entre os dois grupos (p > 0,05. A irradiação com laser de diodo não proporcionou aumento do selamento apical em retrobturações com MTA sob as condições do presente estudo in vitro.

  8. Estudo experimental de linfonodo sentinela na mama da cadela com azul patente e Tecnécio Tc99m Experimental study of the sentinel lymph node in the dog breast using blue dye and technetium Tc99m

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    Luiz Gonzaga Porto Pinheiro

    2003-12-01

    Full Text Available Pesquisa do Lin