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Sample records for corante organico utilizacao

  1. CORANTES ARTIFICIAIS EM ALIMENTOS

    Directory of Open Access Journals (Sweden)

    Marcelo Alexandre PRADO

    2009-07-01

    Full Text Available

    O emprego de aditivos químicos é, sem dúvida, um dos mais polêmicos avanços alcançados pela indústria de alimentos. Os corantes artificiais pertencem a uma dessas classes de aditivos alimentares e têm sido objeto de muitas críticas, já que seu uso em muitos alimentos justifica-se apenas por questões de hábitos alimentares. Ainda existem diferentes opiniões quanto à inocuidade dos diversos corantes artificiais. Visando, principalmente, o controle no uso dos corantes sintéticos, mas tendo em vista que produtos coloridos artificialmente são exportados e importados, a análise desses aditivos requer métodos eficientes e rápidos para a detecção, identificação e quantificação. A cromatografia em papel e em camada delgada, apesar de serem técnicas relativamente rápidas, apresentam dados com baixa exatidão e precisão. Já na cromatografia líquida de alta eficiência (CLAE as maiores dificuldades encontram-se nas etapas de extração, mas principalmente no alto custo do equipamento. A eletroforese capilar apresenta os mesmos problemas da CLAE, aliados ao fato de se tratar de uma técnica relativamente recente para a análise desse tipo de substância e, portanto, existem poucos estudos a cerca da determinação e quantificação. PALAVRAS-CHAVE: Corantes artificiais; análise; legislação; CLAE; EC

  2. Corantes vitais em cromovitrectomia

    OpenAIRE

    Dib, Eduardo; Rodrigues,Eduardo Büchelle; Maia, Maurício [UNIFESP; Meyer, Carsten H; Penha, Fernando Marcondes [UNIFESP; Furlani, Bruno de Albuquerque [UNIFESP; Costa, Elaine de Paula Fiod [UNIFESP; Farah, Michel Eid

    2009-01-01

    O objetivo do artigo é apresentar os dados atuais da aplicação de corantes vitais durante cirurgia vitreorretiniana, "cromovitrectomia", bem como uma revisão da literatura atual sobre o assunto no tocante às técnicas de aplicação, indicações e complicações em cromovitrectomia. Um grande número de publicações tem abordado o perfil tóxico da indocianina verde na cromovitrectomia. Dados experimentais mostram uma toxicidade dose-dependente da mesma em várias populações de células retinianas. Nova...

  3. Factores que influyen en el consumo sustentable de productos organicos en el Noroeste de Mexico

    National Research Council Canada - National Science Library

    Salgado-Beltran, L; Beltran-Morales, L.F

    2011-01-01

    ... en el consumo sustentable de productos organicos en el noroeste de Mexico. Para ello, el modelo teorico fue definido por medio de la revision de literatura y se diseno un instrumento de medicion...

  4. Uso de fertilizantes quimicos y organicos en cebolla en Apatzingan, Michoacan, Mexico

    National Research Council Canada - National Science Library

    Alvarez-Hernandez, J.C; Venegas-Flores, S; Soto-Ayala, C; Chavez-Vargas, A; Zavala-Sanchez, L

    2011-01-01

    ... quimicos y organicos en Apatzingan, Michoacan (Mexico). El almacigo se establecio en diciembre de 2009 y el trasplante se realizo a los 70 dias posteriores, el marco de plantacion fue a tres hileras...

  5. CORANTES TÊXTEIS: UMA REVISÃO

    Directory of Open Access Journals (Sweden)

    Fabia Pinho Peixoto

    2013-11-01

    Full Text Available A indústria de corantes desenvolve um importante papel na economia do mundo, visto que estes são utilizados em várias atividades fabris. Os corantes têxteis causam especial impacto no meio ambiente principalmente por serem de difícil degradação. Vários processos tem sido estudados a fim de que se consiga realizar um tratamento realmente efetivo em remoção de corantes de efluentes têxteis, entre eles os processos biológicos estão recebendo uma particular atenção por sua eficiência.O tratamento microbiológico de efluentes, especialmente por espécies fúngicas tem ganhado espaço, por estes organismos serem bastante versáteis, tratarem uma grande variedade de tipos de corantes e apresentarem diferentes mecanismos de remoção de cor. Portanto os fungos apresentam-se bastante atrativos e demonstram ser os organismos mais adequados em relação a tratamento de efluentes têxteis.

  6. Es posible desarrollarse en torno al cafe organico? Las perspectivas de un negocio local-global en comunidades mayas

    National Research Council Canada - National Science Library

    Rodriguez Moreno, Jose Ramon

    2014-01-01

    Se analizan los nuevos retos que enfrentan los productores organicos de cafe ante los actuales escenarios del comercio global, en presencia de eficientes mecanismos de la hegemonia comercial que ha...

  7. Corantes vitais em cromovitrectomia Vital dyes in chromovitrectomy

    Directory of Open Access Journals (Sweden)

    Eduardo Dib

    2009-12-01

    Full Text Available O objetivo do artigo é apresentar os dados atuais da aplicação de corantes vitais durante cirurgia vitreorretiniana, "cromovitrectomia", bem como uma revisão da literatura atual sobre o assunto no tocante às técnicas de aplicação, indicações e complicações em cromovitrectomia. Um grande número de publicações tem abordado o perfil tóxico da indocianina verde na cromovitrectomia. Dados experimentais mostram uma toxicidade dose-dependente da mesma em várias populações de células retinianas. Novas gerações de corantes incluem: azul tripan, azul patente, acetato de triancinolona, infracianina verde, fluoresceína sódica, azul de bromofenol, acetato de fluorometolona e azul brilhante. Novos instrumentos podem permitir um corar seletivo de estruturas durante a vitrectomia. Este artigo mostra que o campo da cromovitrectomia está em plena expansão de pesquisas. Os corantes de primeira linha são a indocianina verde, infracianina verde e o azul brilhante. Azul patente, azul de bromofenol e azul tripan surgem como novos adjuvantes para melhor observação da membrana epirretiniana. Demais corantes que surgiram merecem maior investigação.The aim of this article is to present the current data with regard to the application of vital dyes during vitreoretinal surgery, "chromovitrectomy", as well as to overview the current literature regarding the properties of dyes, techniques of application, indications and complications in chromovitrectomy. A large body of published research has recently addressed the toxicity profile of indocyanine green for chromovitrectomy. Experimental data demonstrate dose-dependent toxicity of indocyanine green to various retinal cells. Newer generation vital dyes for chromovitrectomy include trypan blue, patent blue, triamcinolone acetonide, infracyanine green, sodium fluorescein, bromophenol blue, fluorometholone acetate and brilliant blue. Novel instruments may enable a selective painting of preretinal

  8. Corantes vitais em cromovitrectomia Vital dyes in chromovitrectomy

    OpenAIRE

    Eduardo Dib; Eduardo Büchelle Rodrigues; Maurício Maia; Meyer, Carsten H; Fernando Marcondes Penha; Bruno de Albuquerque Furlani; Elaine de Paula Fiod Costa; Michel Eid Farah

    2009-01-01

    O objetivo do artigo é apresentar os dados atuais da aplicação de corantes vitais durante cirurgia vitreorretiniana, "cromovitrectomia", bem como uma revisão da literatura atual sobre o assunto no tocante às técnicas de aplicação, indicações e complicações em cromovitrectomia. Um grande número de publicações tem abordado o perfil tóxico da indocianina verde na cromovitrectomia. Dados experimentais mostram uma toxicidade dose-dependente da mesma em várias populações de células retinianas. Nova...

  9. Bioensayo microbiano para estimar los nutrimentos disponibles en los abonos organicos: calibracion en el campo

    Directory of Open Access Journals (Sweden)

    Eduardo Salas

    2001-01-01

    Full Text Available Se demostr6 recientemente que el aumento nude la biomasa microbiana en una mezcla de sue- calo: abono organico (9:1, suplementada con gluco- sa como fuente de carbono, fue proporcional al crecimiento de una planta indicadora (sorgo cre- cida en el mismo sustrato. En la presente investi- gaci6n se determina si este bioensayo es de utili- dad como gufa en la fertilizaci6n de los cultivos con abonos organicos, mediante la siembra en el campo de chile dulce (Capsicum annuum L. y to- mate (Lycopersicum esculentum L. como plantas indicadoras. Los tratamientos consistieron de sue- 10 solo 0 en mezcla con 10% de abonos organicos amende contenido de nutrimentos contrastante a saber: pollinaza (CM, compost (C, bocashi (B, vermi- macompost (V y broza de cafe (Br. En el bioensa- vermicomyo microbiano se utiliz6 un disefio de bloques randocompletos al azar con 6 repeticiones, la biomasa microbiana (BM se midi6 2 dfas despues de in- cubar con glucosa. En los ensayos de campo las plantas indicadoras se sembraron en un disefio de bloques completos al azar con 4 repeticiones. En chile dulce se midi6 el peso seco (600 C de la comparte aerea de la planta (PSC y el peso fresco de frutos verdes (PFF a los 97 dfas despues de la Microsiembra. El peso seco de la parte aerea de las amendplantas de tomate (PST fue medido a los 32 dfas. Los abonos organicos CM, C y B indujeron la mayor BM y tambien el mayor PSC, PFF Y PST, indicaci6n de que fueron los de mayor y mas in- mediato suministro de nutrimentos, contrario al y Br que mostraron los valores mas bajos para es- tas variables (P<0.05. Estos 2 abonos, respecto vatratamiento de CM presentaron 3 y 5 veces menos BM y 2 Y 4 veces menos biomasa aerea, respecti- vamente (P<0.05. Las correlaciones altas obteni- codas entre la BM y el PSC (r=0.87 y entre la BM y el PST (r= 0.93, permiten concluir que bioensayo microbiano es un metoda promisorio para pronosticar el suministro de nutrimentos orlos abonos organicos a los cultivos

  10. Producción de biogás a partir de residuos organicos en biodigestores de bajo coste

    OpenAIRE

    Ferrer Martí, Ivet; Uggetti, Enrica; Poggio, Davide; Velo García, Enrique

    2015-01-01

    PRODUCCIÓN DE BIOGÁS A PARTIR DE RESIDUOS ORGANICOS EN BIODIGESTORES DE BAJO COSTE Ivet Ferrer*, Enrica Uggetti**, Davide Poggio***, Enric Velo**** Grup de Recerca en Cooperació i Desenvolupament Humà C. Jordi Girona, 31 08034 - Barcelona, Spain Phone: +34 93 401 64 63 Pàgina web: http://www.upc.edu/grecdh *, **, ***, **** Palabras clave: Digestión anaerobia; Biodigestor; Biogás; Energía; Fertilizante. RESUMEN ...

  11. Estabilidade dos corantes Tartrazina e Amarelo Crepusculo em refrigerantes - DOI: 10.4025/actascitechnol.v27i2.1451

    Directory of Open Access Journals (Sweden)

    Indianara Ostroski

    2005-03-01

    Full Text Available Estudou-se a estabilidade dos corantes alimentícios sintéticos tartrazina e amarelo crepúsculo em relação à intensidade de radiação na região do ultravioleta e do visível, bem como a influência do pH e de outros aditivos comumente presentes em produtos alimentícios. Foram realizadas leituras periódicas do espectro de absorção nos comprimentos de onda entre 700 e 190 nm para verificar alterações químicas nos corantes estudados. No caso de refrigerantes em embalagem de PET verificou-se a relação entre luz incidente e luz transmitida pela embalagem, estabelecendo a sua função como filtro a determinadas radiações luminosas. Os dados obtidos com os corantes nas amostras de refrigerantes foram comparados com os dados obtidos com os corantes em solução. Constatou-se que em pH mais ácido há um aumento na velocidade de degradação dos corantes, do mesmo modo que na presença de citratos ou ascorbatos. A presença de benzoatos retarda o processo de degradação dos corantes

  12. Estabilidade dos corantes Tartrazina e Amarelo Crepusculo em refrigerantes = The stability of synthetic food dyes tartrazine and yellow sunset

    Directory of Open Access Journals (Sweden)

    Indianara Ostroski

    2005-07-01

    Full Text Available Estudou-se a estabilidade dos corantes alimentícios sintéticos tartrazina e amarelo crepúsculo em relação à intensidade de radiação na região do ultravioleta e do visível, bem como a influência do pH e de outros aditivos comumente presentes em produtos alimentícios. Foram realizadas leituras periódicas do espectro de absorção noscomprimentos de onda entre 700 e 190 nm para verificar alterações químicas nos corantes estudados. No caso de refrigerantes em embalagem de PET verificou-se a relação entre luz incidente e luz transmitida pela embalagem, estabelecendo a sua função como filtro adeterminadas radiações luminosas. Os dados obtidos com os corantes nas amostras de refrigerantes foram comparados com os dados obtidos com os corantes em solução. Constatou-se que em pH mais ácido há um aumento na velocidade de degradação dos corantes, do mesmo modo que na presença de citratos ou ascorbatos. A presença de benzoatos retarda o processo de degradação dos corantes.The stability of synthetic food dyes tartrazine and yellow sunset was studied in relation to the intensity of radiation in the ultraviolet and visible spectra, as well as the influence of the pH and others additives normally presents in some products. Periodic scanning of theabsorption spectrum was accomplished in the wavelengths between 700 nm and 190 nm to verify alterations in this dyes. In the case of soft drinks in PET packing, the relation was verified between incident light and light transmitted by the packing, establishing its function as filter to radiation. The data obtained with the dyes in the samples of soft drinks were compared with standard dyes solutions. In acid media, citrate and ascorbate presence, a major degradation process occurs. In benzoate presence, the dye degradation is lower.

  13. Toxicocinética de um corante têxtil no amphipoda marinho Parhyale hawaiensis

    OpenAIRE

    Amanda dos Santos

    2016-01-01

    Resumo: O estudo da toxicocinética é importante para avaliar os efeitos adversos de contaminantes para os organismos aquáticos. Corantes têxteis são considerados contaminantes emergentes, por serem potencialmente tóxicos, terem sido encontrados no meio aquático e não há nenhum regulamento que defina as concentrações máximas admissíveis em água para assegurar a proteção da biota aquática e da saúde humana. Pouco se sabe sobre os efeitos dessa classe de contaminantes e utilizar um modelo de org...

  14. Toxicocinética de um corante têxtil no amphipoda marinho Parhyale hawaiensis

    OpenAIRE

    Amanda dos Santos

    2016-01-01

    O estudo da toxicocinética é importante para avaliar os efeitos adversos de contaminantes para os organismos aquáticos. Corantes têxteis são considerados contaminantes emergentes, por serem potencialmente tóxicos, terem sido encontrados no meio aquático e não há nenhum regulamento que defina as concentrações máximas admissíveis em água para assegurar a proteção da biota aquática e da saúde humana. Pouco se sabe sobre os efeitos dessa classe de contaminantes e utilizar um modelo de organismo p...

  15. Volatile organic compound (VOC) determination in working atmospheres; Determinacion de compuestos organicos volatiles (VOC) en ambiente laboral

    Energy Technology Data Exchange (ETDEWEB)

    Blass A, Georgina; Panama T, Luz A; Corrales C, Deyanira [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

    2003-07-01

    The present work describes, in a synthesized way, the implementation and application of procedures based on the normativity related to the subject of the volatile organic compounds (Volatile Organic Compounds VOC), that allow to sample, quantify and evaluate the present contamination in the working atmosphere of a refinery due to the fugitive emissions of VOC and other substances. In accordance with the corresponding normativity, more than 189 organic compounds denominated dangerous air polluting agents (Hazardous Air Pollutants, HAP) can be found in a working atmosphere, but they are the 11 main HAP that can be found in a refinery. In the present article the work made for the sampling and quantification of 5 of the 11 dangerous polluting agents of the air: benzene, toluene, xylene, iso-octane and naphthalene. [Spanish] El presente trabajo describe, de manera sintetizada, la implementacion y aplicacion de procedimientos basados en la normatividad relacionada al tema de los compuestos organicos volatiles (Volatil Organic Compounds, VOC), que permiten muestrear, cuantificar y evaluar la contaminacion presente en el ambiente laboral de una refineria debido a las emisiones fugitivas de VOC y otras sustancias. De acuerdo con la normatividad correspondiente, mas de 189 compuestos organicos denominados contaminantes peligrosos del aire (Hazardous Air Pollutants, HAP), pueden ser encontrados en un ambiente laboral, pero son 11 los principales HAP que pueden ser hallados en una refineria. En el presente articulo se informa el trabajo realizado para el muestreo y cuantificacion de 5 de los 11 contaminantes peligrosos del aire: benceno, tolueno, xileno, iso-octano y naftaleno.

  16. Património cultural e científico da cidade : cores e corantes dos bordados de Castelo Branco

    OpenAIRE

    Paixão, Fátima; Pereira, Mariette; Cachapuz,António

    2006-01-01

    Relata-se a implementação de um Projeto de cariz CTS cujo tema central são os bordados de Castelo Branco. Evidenciam-se aspectos que conduzem a um melhor conhecimento do património cultural da cidade, centrando-nos nas cores e nos processos experimentais de obtenção dos corantes antigos e dos atuais.

  17. Using the direct method in organophilization of clay chocolate 'A' with organic surfactant; Utilizacao do metodo direto na organofilizacao da argila chocolate 'A' com surfactante organico

    Energy Technology Data Exchange (ETDEWEB)

    Patricio, A.C.L.; Sousa, A.B.; Silva, M.M. da; Rodrigues, M.G.F.; Laborde, H.M., E-mail: cadigena@hotmail.com [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Centro de Ciencias e Tecnologia. Unidade Academica de Engenharia Quimica

    2012-07-01

    During the development of this work, we studied the preparation of organoclays through direct method, starting from the natural clay Chocolate 'A' using the quaternary ammonium salt, chloride, alkyl dimethyl benzyl ammonium (Dodigen). The samples were characterized by X-Ray Diffraction (XRD), Infrared Spectroscopy in the Region (IV), Gravimetric and Differential Thermal Analysis (DTA / TGA) and swelling of Foster using solvents, gasoline, kerosene and diesel. Was observed by the results XRD, IR and DTA / TG effective intercalation of quaternary ammonium salts of the inter lamellar spaces of the clay, and by Foster swelling test samples treated with the quaternary ammonium salt Dodigen showed affinity for all the solvents tested. (author)

  18. Avaliação dos resíduos argiloso proveniente da indústria do Alumínio como adsorvente de corantes têxteis

    OpenAIRE

    Cristina da Silva, Tereza

    2008-01-01

    O impacto ambiental provocado pelas indústrias têxteis com a geração de efluentes líquidos se constitui num parâmetro representativo como fator potencialmente poluidor. Um dos maiores problemas ambientais gerados durante o processo de tingimento nas lavanderias industriais é a grande quantidade de efluentes, contendo elevada carga de substâncias tóxicas, tais como os corantes. A remoção de cor dos efluentes é fundamental para o controle ambiental, uma vez que o corante interfer...

  19. Dye detoxification by Lentinula edodes INCQS 40220 | Detoxificação de corante por Lentinula edodes INCQS 40220

    Directory of Open Access Journals (Sweden)

    Ludmila R. Bergsten-Torralba

    2016-02-01

    Full Text Available Lentinula edodes belongs to the group of fungi known as ligninolytic fungi, due to its ability to degrade the aromatic structure of the lignin. Textile dyes also have aromatic structure, and after microbial degradation, some of them can be transformed into toxic compounds, when compared to the original structure, representing risk to environment and human health. Therefore, the potential of the fungus L. edodes INCQS 40220 to decolorize and to detoxify reactive red 198 (azo dye, reactive blue 214 (azo dye and reactive blue 21 (cooper phthalocyanine dye in a mixture (MXD, was evaluated. After 14 days of incubation, total decolorization in liquid media was obtained. The fungal treatment of MXD did not present toxic effects towards blood human cells. The genotoxicity of MXD, assessed by Comet assay, was efficiently reduced to 61% and in the Ames test presented negative response for mutagenicity for Salmonella enterica serovar Typhimurium TA97, TA98, TA100 and TA102 strains. The results indicated L. edodes INCQS 40220 efficiency on decolorization and genotoxicity reduction of a mixture of different dyes. Therefore, based on these results, obtained under laboratory conditions, L. edodes INCQS 40220 has potential for textile effluent treatment. ============================================= Lentinula edodes pertence ao grupo de fungos conhecidos como fungos ligninolíticos, devido a sua habilidade de degradar estruturas aromáticas da lignina. Corantes têxteis também possuem estruturas aromáticas e, após a degradação microbiana, alguns destes corantes podem ser transformados em compostos tóxicos quando comparados à estrutura original, representando risco à saúde ambiental e humana. Portanto, o potencial do fungo L. edodes INCQS 40220 para descolorir e detoxificar a mistura de vermelho reativo 198 (corante azo, azul reativo 214 (corante azo e azul reativo 21 (corante ftalocianina de cobre foi avaliada (MXD. Após 14 dias de incubação, foi

  20. Extração de corantes de milho (Zea mays L. Extraction of corn colorants (Zea mays L.

    Directory of Open Access Journals (Sweden)

    Felix Martin Cabajal Gamarra

    2009-03-01

    Full Text Available Os corantes naturais foram amplamente utilizados de forma artesanal até antes do surgimento dos corantes sintéticos. O estudo e uso dos corantes naturais voltaram a ter importância nestes últimos anos devido aos questionamentos dos organismos internacionais da saúde e dos consumidores pelo uso indiscriminado dos corantes sintéticos, ligados ao desenvolvimento de doenças degenerativas e ao impacto ambiental. O corante extraído do milho roxo (Zea mays L. tem sido utilizado ao longo da história pela civilização Inca na preparação de alimentos e no tingimento de fibras têxteis. Neste trabalho, os pigmentos do grupo das antocianinas foram extraídos das variedades de milho roxo e do milho vermelho (Z. mays L. e depois foram caracterizados. Três métodos de extração foram utilizados: imersão, lixiviação com algumas modificações e extração supercrítica (ESC. O melhor método para extração foi o da lixiviação que alcançou 88% (m/m de rendimento, em função da massa do corante extraído e da matéria-prima. Também utilizando a lixiviação modificada, foi possível concentrar em 3% os compostos acilados, assim como recuperar 85% dos solventes utilizados. Um indicador de pH foi obtido pela fixação das antocianinas num papel de filtro, com base na estabilidade das antocianinas, ferramenta que pode ser utilizada em laboratórios de ensino de química.Natural colorants were craftly made and widely used before the discovery of the synthetic colorants. The study and the use of natural colorants have become important again in the last few years due to questions raised by the international health organizations and consumers related to the indiscriminate use of synthetic colorants which were linked to the development of degenerative illnesses and environmental impact. The colorant extracted from purple corn (Zea Mays L. was used by the Inca civilization to prepare food and to dye textile fibers. In this work, pigments from the

  1. Estudos de descoloração de corantes para couro pelo isolado nativo Trametes villosa SC10

    OpenAIRE

    Santiago Ortiz-Monsalve

    2015-01-01

    O couro é um produto que tem uma crescente demanda mundial. O Brasil possui o maior rebanho comercial bovino do mundo, sendo um dos principais produtores e exportadores de couro a nível mundial. Assim, esse setor é um dos motores da economia do país. No estado do Rio Grande do Sul, essa indústria tem particular importância no desenvolvimento socioeconômico da região. No processo produtivo, a etapa de tingimento é importante para o acabamento do produto, empregando-se uma variedade de corantes...

  2. Consumo de corantes artificiais em balas e chicletes por crianças de seis a nove anos

    OpenAIRE

    Oliveira, Ana Paula da Silva; Jacques, Gabriela Ferreira; Nery, Vinicius Vaz Cabral; Abrantes, Shirley de Mello Pereira

    2010-01-01

    Um questionário foi elaborado com o objetivo de identificar as balas e chicletes mais consumidos, suas respectivas marcas e os corantes nestes utilizados, por crianças de 6 a 9 anos, no período de uma semana. Este questionário foi aplicado em escolas particulares, considerando a norma de amostragem por atributos ISO 2859-1 (NBR 5426). Foi escolhido o bairro de Del Castilho no Município do Rio de Janeiro. Das 12 escolas foi feita a amostragem representativa de três escolas, contabilizando 640 ...

  3. Avaliação da exposição aos corantes artificiais presentes em balas e chicletes por crianças entre 3 e 9 anos estudantes de escolas particulares da Tijuca / Rio de Janeiro

    OpenAIRE

    Pinheiro, Maria Clara de Oliveira; Abrantes, Shirley de Mello Pereira

    2012-01-01

    Sabe-se que a única função dos corantes alimentares é conferir cor ao alimento não oferecendo nenhum valor nutritivo a este. Estudos vêm demonstrando a ocorrência de reações adversas a curto e longo prazo, devido ao consumo de alimentos que apresentam corantes artificiais. As reações variam desde reações tóxicas no metabolismo desencadeantes de alergias, alterações no comportamento, em geral, e carcinogenicidade. O objetivo do presente trabalho foi avaliar o consumo de corantes artificiais pr...

  4. Biodegradation of reactive textile dyes by basidiomycetous fungi from brazilian ecosystems Biodegradação de corantes têxteis reativos fungos basidiomicetos do ecossistema brasileiro

    Directory of Open Access Journals (Sweden)

    Kátia M.G. Machado

    2006-12-01

    Full Text Available The potential of Trametes villosa and Pycnoporus sanguineus to decolorize reactive textile dyes used for cotton manufacturing in the State of Minas Gerais, Brazil, was evaluated. Growth and decolorization halos were determined on malt extract agar containing 0.002g L-1 of the dye. T. villosa decolorized all 28 of the tested dyes while P. sanguineus decolorized only 9. The effect of culture conditions (shaking and dye and nitrogen concentration on the degradation of Drimaren Brilliant Blue dye was evaluated during growth of the fungi in liquid synthetic medium. Shaking favored degradation and decolorization was not repressed by nitrogen. In pure culture, T. villosa and P. sanguineus decolorized synthetic effluent consisting of a mixture of 10 dyes. Higher decolorization of the synthetic effluent was observed when a mixed culture of the two fungi was used. This study demonstrated differences between tropical basidiomycete species in terms of their ability to degrade reactive dyes, and reinforces the potential of this group of fungi for the decolorization of textile effluents.O potencial de Trametes villosa e Pycnoporus sanguineus de descolorir corantes têxteis reativos utilizados na manufatura de algodão no estado de Minas Gerais foi avaliado. Halos de crescimento e descoloração foram determinados em agar extrato malte (MEA com 0,002g L-1 do corante. T. villosa descoloriu os 28 corantes testados e P. sanguineus apenas 9. A influência de condições de cultivo (agitação, concentração de corante e concentração de nitrogênio na degradação do corante azul brilhante Drimaren foi avaliada durante crescimento dos fungos em meio líquido sintético. Agitação favoreceu a degradação e não foi observada repressão da descoloração pelo nitrogênio. Em cultura pura, T. villosa e P. sanguineus descoloriram efluente sintético constituído por uma mistura de dez corantes. Maior descoloração do efluente sintético foi observada no cultivo

  5. Determinacion del N y P en abonos organicos mediante la tecnica del elemento faltante y un bioensayo microbiano

    Directory of Open Access Journals (Sweden)

    Eduardo Salas

    2001-01-01

    Full Text Available Mediante la tecnica del elemento faltante en ferinvernadero y el uso de un bioensayo microbiano se determin6 la disponibilidad de N y P en 6 sus- greenhoutratos: suelo s6lo 0 en mezcla 9: 1 con diversos abo- nos organicos, a saber: pollinaza (CM, compost (C, bocashi (B, vermicompost (V 0 broza de ca- determife (Br. En ambos bioensayos y para cada sustrato se realiz6 un experimento factorial 2x2 (fertiliza- ci6n con P y N; las combinaciones resultantes fue- ron: +P, +N, +P+N y -P-N (testigo. En el bioensa- yo microbiano se utiliz6 un diseno de bloques al azar con 6 repeticiones y se midi6 el crecimiento microde la biomasa microbiana nativa (BM 2 dias des- pues de aplicar el tratamiento e incubar con gluco- sa. En la prueba de invernadero se utiliz6 un dise- no completamente al azar con 4 repeticiones, se utiliz6 sorgo (Sorghum vulgare como planta indi- cadora. Se midi6 el peso seco de la parte aerea de lasplantas a los 34 dias de la siembra (PS y el con- tenido foliar de nutrimentos. Ambos bioensayos in- sordicaron respuesta del suelo a la aplicaci6n de P y N. La mezcla del suelo con un 10% de CM, CoB mostraron los valores mas altos de BM y PS. La mezcla suelo:CM no respondi6 a ningun tratamien- to qufmico, mientras que en mezcla con el C 0 el B respondi6 a la aplicaci6n de N pero no al P. Con el Vola Br se obtuvo las menores respuestas de las variables y hubo respuesta ala adici6n de P y N. La tecnica del elemento faltante de invernadero

  6. Célula solar de SnO2/TiO2 preparada por spray - pirólise ativada com corante orgânico

    OpenAIRE

    Freitas, Fábio Elias [UNESP

    2006-01-01

    Este trabalho é dedicado à preparação e a caracterização de célula solar nanocristalina do tipo Grätzel ativada com corante orgânico. O presente desenvolvimento envolveu a deposição da camada condutora transparente SnO2, deposição da camada nanoporosa de TiO2, preparação do eletrólito, escolha e preparação do corante e por fim o fechamento e a caracterização da célula. O método de deposição empregado para a obtenção dos filmes foi a técnica spray pirólise, sendo a deposição realizada a temper...

  7. Utilização de resíduos de materiais cerâmicos na adsorção de corante azul de metileno

    Directory of Open Access Journals (Sweden)

    L. Dominguini

    2014-06-01

    Full Text Available Este trabalho estuda a viabilidade de utilização de resíduos de materiais cerâmicos como agentes de adsorção de corantes utilizados em indústrias têxteis. Resíduos de materiais cerâmicos, oriundos de quebras de tijolos, azulejos e pisos foram selecionados, triturados e moídos a uma granulometria adequada, o que possibilitou o estudo da influência do tipo de material cerâmico (resíduo e da sua granulometria sobre a adsorção do corante azul de metileno. Os resíduos cerâmicos foram separados em três diferentes granulometrias, fina (0,15 mm < Dfino< 0,30 mm, média (0,30 mm < Dmédio< 1,18 mm e grossa (1,18 mm corante azul de metileno presente na amostra ensaiada. No entanto, os resultados também mostram que a absorção de água do material cerâmico pode não ser somente o fator que influencia na adsorção do corante.

  8. Estudos sobre a intercalação dos corantes azul brilhante-FCF e azul de coomassie G-250 em ácido desoxirribonucléico (DNA)

    OpenAIRE

    Queiroz, Carmen Fabiola Otoni de

    2007-01-01

    Este trabalho versa sobre o processo de intercalação de dois tipos de corantes em DNA, o Azul brilhante FCF, um corante alimentício e o Azul de Coomassie G-250, que é habitualmente usado em ensaios bioquímicos. Dados obtidos através de ensaios de espectrofotometria de absorção na região do UV/Vis e de infravermelho com relação ao complexo formado entre o DNA/Azul Brilhante mostram uma efetiva interação entre o Azul Brilhante FCF e o DNA, reforçando a possibilidade do corante estar intercaland...

  9. Utilização de Saccharomyces cerevisiae imobilizada em bagaço de cana de açúcar para a biossorção e biodegradação do corante acid black 48

    OpenAIRE

    Mitter, Eduardo Kovalski [UNESP

    2012-01-01

    Com a revolução industrial ocorreu o crescimento do setor têxtil, o qual utiliza uma grande quantidade de água nos processos de tingimento e uma ampla variedade de corantes sintéticos. Uma pequena concentração destes corantes no meio ambiente já pode gerar uma poluição altamente visível e indesejável, provendo alterações nos ecossistemas aquáticos. Dentre os processos de remoção de corantes, a adsorção, biossorção e biodegradação apresentam-se como as técnicas mais vantajosas. A adsorção cons...

  10. Determinação de isotermas de adsorção de corante têxtil em carvão ativo, serragem e algas marinhas arribadas

    OpenAIRE

    Érika Tomie Koroishi; Andréia Aline Bonan; Caroline Bonifácio de Andrade; Aracélis Ferreira da Silva; Washington Luiz Felix dos Santos; Classius Ferreira da Silva

    2000-01-01

    Os efluentes de tinturaria constituem um problema ambiental, uma vez que apresentam elevada quantidade de carga orgânica e de cor. Os processos de coagulação e adsorção são os mais utilizados na remoção de corantes têxteis. Neste trabalho foram determinadas as isotermas de adsorção de três materiais adsorventes: carvão ativo de casca de coco, serragem (um material alternativo) e algas marinhas trituradas (uma mistura contendo predominantemente Sargassum sp.). Utilizaram-se soluções do corante...

  11. Descoloração e Mineralização de Corantes Reativos por Processo Fotocatalítico Utilizando ZnO e Radiação UV

    OpenAIRE

    Wilson Nunes de Almeida Guerra

    2009-01-01

    As indústrias consomem volumes elevados de água e outras substâncias químicas na síntese dos seus produtos e geram grande quantidade de rejeitos. Entre os mais importantes poluentes encontrados nos efluentes dessas indústrias estão os corantes sintéticos que representam um problema, pois não são facilmente destruídos por tratamentos convencionais. A fotocatálise heterogênea tem sido considerada como uma alternativa efetiva no tratamento de efluentes contendo esses corantes. Neste trabalho, es...

  12. Preparo e avaliação do hidróxido duplo lamelar MgZnAl-Fe calcinado no processo de adsorção – fotodegradação do corante alaranjado de metila

    OpenAIRE

    Sousa, Paloma Viana Ferreira de

    2015-01-01

    Neste trabalho foi preparado o HDL magnético calcinado MgZnAl-Fe e caracterizado por Espectroscopia no Infravermelho (IV), Difratometria de Raios- X (DRX), Microscopia Eletrônica de Varredura (MEV), Espectrometria de Absorção Atômica e Reflectância Difusa. O desempenho fotocatalítico do MgZnAl-Fe foi avaliado utilizando o corante alaranjado de metila (corante do tipo azo) como composto modelo. Estudos fotocatalíticos com o MgZnAl-Fe foram feitos empregando-se uma concentração inicial de 100 m...

  13. Avaliação da exposição aos corantes artificiais por crianças entre 3 e 9 anos em relação ao consumo de balas

    OpenAIRE

    Pinheiro, Maria Clara de Oliveira

    2012-01-01

    Sabe-se que a única função dos corantes alimentares é conferir cor ao alimento não oferecendo nenhum valor nutritivo a este. Estudos vêm demonstrando a ocorrência de reações adversas a curto e longo prazo, devido ao consumo de alimentos que apresentam corantes artificiais. As reações variam desde reações tóxicas no metabolismo desencadeantes de alergias, alterações no comportamento, em geral, e carcinogenicidade, esta última observada em longo prazo. O objetivo do presente trabalho foi avalia...

  14. Avaliação espectroscópica de corantes orgânicos submetidos a raios-X: aplicação em dosimetria de radiação ionizante

    OpenAIRE

    BENEVIDES, Clayton Augusto

    2015-01-01

    Esta tese teve o objetivo de entender como ocorre a degradação de determinados corantes orgânicos fluorescentes quando irradiados e avaliar quantitativamente esta degradação. Os experimentos foram feitos utilizando uma concentração específica para os dois corantes: Rodamina 6G e Fluoresceína em gel de agarose e NaCl. NaCl foi utilizado a fim aumentar a taxa de degradação dos fluoróforos. Uma vez estabelecidos os sistemas químicos, as irradiações foram executadas sob um feixe ...

  15. Avaliação, por infiltração de corante, de tecnologias Laser em cirurgias paraendodônticas

    OpenAIRE

    Pozza, Daniel Humberto

    2013-01-01

    Visando ao aprimoramento técnico, os Laseres CO2, Er:Yag e Nd:Yag têm sido utilizados para os procedimentos cirúrgicos periapicais. Esta pesquisa avaliou, in vitro, por meio do teste de infiltração apical, por corante Rodomina B a 1% e morfometria computadorizada do programa Image Tool, 108 caninos humanos permanentes, submetidos a tratamento endodôntico e divididos em nove grupos: A-apicectomia por broca em 90 graus, retrocatividade por ultra-som e retro-obturação com MTA; B-apicectomia por ...

  16. Degradação redutiva de azo-corantes utilizando-se ferro metálico Reductive degradation of azo-dyes by metallic iron

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    Cláudio Lima de Souza

    2006-03-01

    Full Text Available Corantes azo são extensivamente utilizados em processos de tingimento de fibras têxteis, sendo caracterizados por elevada resistência frente a processos aeróbios de biodegradação e, por conseqüência, persistência nos processos convencionais de tratamento de resíduos. Neste trabalho reporta-se a degradação redutiva de corantes azo, utilizando-se ferro metálico. Em condições experimentais otimizadas (pH 7 e 10 g de lã de aço comercial a completa descoloração do corante modelo (preto reativo 5 foi conseguida em um sistema contínuo, operando com tempos de retenção de 6 min. Nestas condições, o ferro solubilizado alcança concentrações compatíveis com os limites impostos pela atual legislação brasileira (12 mg L-1. Trata-se de um resultado bastante promissor, principalmente levando-se em consideração o caráter recalcitrante dos azo corantes e a simplicidade do sistema proposto.Azo dyes are extensively used in textile dying processes and are characterized by extreme resistance to biodegradation and consequently persistence during conventional wastewater treatment processes. In this work the reductive degradation of azo dyes was studied using zero-valent iron. At optimized experimental conditions (pH 7 and 10 g of commercial iron wool complete decolorization of the model dye (reactive black 5 was afforded in a continuous system operating with hydraulic retention time of 6 min. At these conditions the released total soluble iron reaches a concentration compatible with the limits imposed by the current Brazilian legislation (12 mg L-1. That is a very promising result, mainly taking into account the high recalcitrant character of azo dyes and the simplicity of the proposed system.

  17. Uso de Materiais Alternativos em Processos de Adsorção de Corante Azul de Metileno

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    E. L. do Rego

    2014-11-01

    Full Text Available Este trabalho teve como objetivo empregar materiais alternativos, puros e/ou modificados com 5 ou 10% (m/m de  pentóxido de nióbio (Nb2O5, em processos de remoção de azul de metileno (AM. Entre os materiais alternativos foram utilizadas argila sanitária, argila de resíduo industrial, rochas sedimentares e cinzas de casca de arroz obtida pela queima a 350oC. Estes sólidos foram caracterizados pelas técnicas de difração de raios- X (DRX e espectroscopia na região do infravermelho (FTIR. Os testes de remoção de AM foram realizados em frascos de 125 mL, sob agitação constante, contendo 100 mL de solução de AM (100mg/L a 2000mg/L e adsorvente (0,1 a 0,6g, sob uma mesa agitadora a 200 rpm, em temperatura ambiente. A quantificação da remoção de AM foi realizada com auxílio de um espectrofotômetro UV-Vis da Varian (Cary 50, coletando 2 mL de amostra nos períodos de 2 à 1440 min. Dados de DRX evidenciaram uma mistura de argilominerais nos sólidos baseados em argilas. Nos ensaios de adsorção os materiais demonstraram eficiência para a remoção do corante, com destaque aqueles modificados com 10% de Nb2O5 exibindo 95% de remoção, no tempo de 120min, em solução de pH de ~6,5.

  18. Avaliação do consumo de corantes artificiais por lactentes, pré-escolares e escolares Evaluation of artificial dye intake by children

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    Simone Pinheiro Alves Schumann

    2008-09-01

    Full Text Available O objetivo do presente trabalho foi avaliar o consumo, por 150 crianças de até 10 anos, de pó para gelatina, preparado sólido para refresco e refrigerante. Foi feita aplicação de questionário de freqüência quantitativa e qualitativa com população infantil atendida no ambulatório de pediatria do Hospital Universitário Gafrée Guinle, Rio de Janeiro. Os dados foram tratados estatisticamente pelo programa SPSS 8.0. Verificou-se que os alimentos pesquisados são ampla e freqüentemente consumidos, sendo introduzidos na dieta, em muitos dos casos, antes da criança completar 1 ano de idade. Sabe-se que os produtos estudados não são adequados nutricionalmente, pois apresentam, além dos corantes, outros aditivos alimentares e não contêm nenhum nutriente importante para o funcionamento do organismo. Em relação aos corantes presentes nos produtos mencionados pela população estudada, constatou-se que os mais informados na rotulagem destes produtos, no item ingredientes, são amarelo crepúsculo, tartrazina e amaranto. Estimando que o teor dos corantes nos alimentos analisados esteja no limite máximo permitido pela legislação, observou-se que a grande maioria das crianças avaliadas pode estar excedendo a ingestão diária aceitável para o corante amaranto e que cerca de 20% da população pode estar excedendo o consumo recomendado para o amarelo crepúsculo. É importante que os valores máximos permitidos de corantes em alimentos, no Brasil, sejam adequados às recomendações realizadas pelo órgão internacional que avalia a segurança dos aditivos, e que ações educativas sejam realizadas.This study aimed at evaluating the intake of solid jelly powder, solid juice powder and soft drinks by children. The intakes were estimated through the application of a quantitative and qualitative food frequency questionnaire. The study was pursued in the pediatric nutrition ambulatory of Gaffrée Guinle University Hospital in Rio de

  19. Bioensaios de desenvolvimento inicial de alface (Lactuca Sativa como potencial bioindicador de toxicidade de amostra comercial contendo corante alimentício azorrubina

    Directory of Open Access Journals (Sweden)

    D. J. Santos

    2014-11-01

    Full Text Available Ensaios biológicos têm sido utilizados, frequentemente, no monitoramento de substâncias potencialmente tóxicas. Neste contexto, avaliou-se o potencial tóxico de amostras comerciais de mistura contendo corante alimentício orgânico-sintético azorrubina (C2OH12N2Na2O7S2 sobre o desenvolvimento inicial de sementes de alface (Lactuca sativa como potencial bioindicador para monitorar a redução de toxicidade das amostras. Os bioensaios foram realizados previamente avaliando-se os efeitos causados à espécie-teste, por meio de exposição das sementes (sem tratamento com fungicida à solução de 2500 ppm de mistura contendo o corante. Também foram analisados resíduos de amostras que foram submetidas a ensaios fotocatalíticos (reações de Fenton e foto-Fenton. O delineamento experimental foi inteiramente casualizado (aleatório, com cinco repetições para cada tratamento. Para avaliar a germinação realizou-se monitoramento diário até 72 horas, após esse período, aferiu-se o comprimento do hipocótilo e radícula de cada plântula. As amostras utilizadas nos ensaios iniciais e após o processo fotocatalítico (duração de 120 min não influenciaram na germinação. Já no desenvolvimento das plântulas houve inibição considerável. Os resultados indicaram que os ensaios biológicos, foram eficazes para indicar a redução da influência do corante alimentício sobre o desenvolvimento das plântulas, além disso, leva-se em conta, que o método é eficaz e barato.

  20. Tratamento de corantes reativos em solução aquosa utilizando lodo de esgoto sanitário como biossorvente em reatores contínuos.

    OpenAIRE

    Silva, Rene Pinto da

    2012-01-01

    Os tratamentos convencionais de efluentes da indústria têxtil, em geral, produzem quantidades significativas de subprodutos com características recalcitrantes. Dentre as novas tecnologias de tratamento, a adsorção se apresenta como um método alternativo. Neste estudo, foi feita a avaliação da eficiência do lodo de esgoto sanitário na remoção do corante reativo amarelo GR, azul GN e vermelho RB em reatores em fluxo contínuo, com e sem aeração, em relação ao pH, alcalinidade total, ácidos graxo...

  1. Uso do corante azul de metileno a 2% na localização do linfonodo axilar em cadelas (Canis familiaris – Linnaeus, 1758

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    Tábata Maués

    2016-04-01

    Full Text Available A biopsia de linfonodo sentinela (LS é cada vez mais utilizada para a determinação do estadiamento clínico tumoral. O acometimento de linfonodos em animais com doença oncológica possui forte valor prognóstico no tumor da glândula mamária. Em medicina veterinária faltam diretrizes bem estabelecidas para a avaliação do LS. O objetivo deste estudo foi avaliar a eficácia do corante azul de metileno a 2% na identificação do linfonodo axilar em cadelas com lesões mamárias. Para tanto, foram utilizadas 101 cadelas, portadoras de lesões mamárias, submetidas à mastectomia radical unilateral ou bilateral. Antes do início da cirurgia, aplicou-se, por via intradérmica, na área ao redor da mama torácica cranial, solução de azul de metileno a 2% estéril. O corante foi eficaz na identificação do linfonodo axilar em 76,27% das cadeias mamárias. Obtiveram-se estruturas coradas em azul, semelhantes a linfonodos em 78,81% dos casos. Dessas estruturas, 96,77% foram confirmadas ao exame histopatológico como linfonodos. Dada a importância prognóstica do comprometimento de linfonodos em alguns tumores, a avaliação do LS deve ser incorporada à rotina clínica, de modo a permitir um estadiamento mais preciso das cadelas com neoplasia mamária.

  2. BIODEGRADATION OF DYES AND TEXTILE EFFUELTS BY FUNGI = BIODEGRADAÇÃO DE CORANTES E EFLUENTES TÊXTEIS POR FUNGOS

    Directory of Open Access Journals (Sweden)

    Aline Ramalho Brandão Pereira

    2010-01-01

    in place grow and degrade the existent compositions. = Os resíduos da indústria têxtil se caracterizam por sua baixa degradabilidade, alto potencial mutagênico e carcinogênico, podendo atingir o meio ambiente e a saúde pública. O emprego de fungos, principalmente, basidiomicetos degradadores de lignina, tem sido cada vez mais utilizado devido à produção de enzimas ligninolíticas de baixa especificidade, que podem ser aplicadas na degradação de compostos fenólicos. A triagem de fungos provenientes de ambientes contaminados também é de grande importância para a seleção de microrganismos com potencial degradativo, pois, se os mesmos conseguem proliferar neste ambiente, certamente possuem um sistema enzimático que lhes permita metabolizar as espécies químicas presentes no local. O objetivo deste trabalho foi isolar fungos da estação de tratamento de efluentes de indústrias têxteis e avaliar a degradação de corantes e efluentes por estes fungos e por fungos com capacidade degradativa conhecida. Os fungos padrões utilizados foram Lentinula edodes e Paraconiothyrium estuarinum. Os corantes em estudo foram Remazol Brilliant Blue R (RBBR, Reactive Yellow 145, Reactive Red 195 e efluente têxtil. A mesma espécie fúngica (Geothricum candidum foi isolada do tanque de aeração de ambas as indústrias têxteis investigadas. Foram feitos testes em meio sólido e líquido, sob diferentes condições de incubação e pH. Foi observada melhor capacidade degradativa nas amostras sob agitação. O fungo isolado da estação de tratamento não degradou o corante RBBR, porém, demonstrou capacidade de degradação do efluente em pH 9, a 35°C e na presença de tampão acetato de sódio. Lentinula edodes degradou todos os corantes e efluentes, e os melhores resultados foram obtidos em pH 5 na presença de tampão. O fungo Paraconiothyrium estuarinum não degradou o corante RBBR, porém, apresentou capacidade degradativa considerável dos corantes Reactive

  3. Biodegradação e toxicidade de corantes têxteis e efluentes da Estação de Tratamento de Águas Residuárias de Americana, SP

    OpenAIRE

    Priscila Maria Dellamatrice

    2006-01-01

    As indústrias têxteis da região de Americana geram grande quantidade de efluentes e resíduos sólidos com grande carga de corantes que são naturalmente de difícil degradação. Assim o objetivo do presente trabalho foi avaliar a possibilidade de biodegradação dos corantes têxteis RBBR, índigo e preto enxofre, e dos resíduos resultantes da Estação de Tratamento de Esgoto da cidade de Americana, SP, (DAE Americana), a qual trata 400 l s-1 de esgoto municipal junto com efluentes de 43 indústrias tê...

  4. Nanocompósitos poliméricos de polietileno de alta densidade contendo hidróxidos duplos lamelares intercalados com ânions derivados de corantes azo

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    Ademir Zimmermann

    2014-06-01

    Full Text Available O presente trabalho descreve a síntese e caracterização de hidróxidos duplos lamelares (HDL de Zn/Al na razão molar 2:1, os quais foram intercalados com íons cloreto hidratados e ânions derivados dos corantes azo alaranjado de metila (AM e alaranjado II (AII. Após caracterização, os materiais foram utilizados como cargas em polietileno de alta densidade (PEAD e nanocompósitos foram preparados por extrusão e injeção, seguindo a norma ASTM D638-10. Os teores de cargas variaram de 0,1 até 2% (incluindo-se os sais de sódio dos corantes e os nanocompósitos homogêneos foram avaliados em relação as suas propriedades estruturais, térmicas e mecânicas. De modo geral, após a adição das cargas existe somente uma pequena influência na temperatura de fusão e cristalização do PEAD. Para os HDLs contendo o pigmento intercalado com o ânion do corante AM e sais de sódio de ambos os corantes, as propriedades mecânicas apresentaram leve aumento do módulo e tensão de ruptura e diminuição do alongamento em relação ao polímero puro e um comportamento inverso foi observado para o ânion AII, além do HDL contendo ânions cloreto hidratados.

  5. Corantes têxteis

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    Guaratini Cláudia C. I.

    2000-01-01

    Full Text Available A dye is a colored substance used to impart permanent color to other substances. Its most important use is in coloring textile fibers and fabrics. The removal of colour from dyehouse waste waters is currently a major problem in the textile sector. This paper provides an overview of the treatment technologies that can currently be used by the textile processor and the developments over the past decade with respect to the toxicological and ecotoxicological properties of synthetic organic dyes.

  6. Avaliação da degradação do corante vermelho bordeaux através de processo fotoquímico Assessment of red dye degradation through photochemical process

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    Cristiano Pochmann da Silva

    2008-03-01

    Full Text Available Neste trabalho foi realizado o estudo da degradação fotoquímica do corante vermelho bordeaux. O estudo objetivou a avaliação de tratamentos alternativos com vistas à aplicação de tecnologias limpas. Os experimentos de fotodegradação foram realizados através da incidência de radiação UV em um compartimento contendo o corante (solução. O tratamento fotoquímico reduziu em 99% a coloração e a concentração da solução contendo o corante vermelho bordeaux.This paper studied the photochemical degradation of food dye (red dye. The investigation aimed at the assessment of alternative treatments, focusing the use of clean technologies. The photochemical degradation experiments were performed in a compartment with UV radiation (mercury lamp - 250W. The photochemical treatment showed a 99% color and concentration reduction in the dye solution.

  7. Qualidade de sementes de algodão submetidas aos processos de encapsulamento com e sem corante. = Quality of cotton seeds submitted to encapsulation process with and without dye.

    Directory of Open Access Journals (Sweden)

    Vicente de Paula Queiroga

    2011-04-01

    Full Text Available Objetivou-se estudar a qualidade fisiológica de sementes de algodão quando submetidas aos processos de encapsulamento com e sem corante em comparação com as sementes apenas tratadas com fungicidas (carboxin e thiran 200 Sc e inseticida (pirimiphos methyl - testemunha. A betoneira grande (capacidade de 40 L recebeu sementes deslintadas +tratadas para serem submetidas ao processo de encapsulação (coating e finishing com e sem corante, além de uma testemunha não encapsulada, estabelecendo-se os seguintes tratamentos: 1- sementes deslintadas e tratadas com fungicidas (carboxin e thiran 200 Sc e inseticidas (pirimiphos methyl (testemunha; 2- sementes deslintadas, tratadas e encapsuladas (coating e finishing sem corante; e 3- sementes deslintadas, tratadas e encapsuladas com corante. Foi adotado o delineamento inteiramente casualizado com três tratamentos e quatro repetições. As variáveis analisadas foram percentagem de germinação, comprimento de plântulas e massa de 100 sementes. Observou-se que o processo de recobrimento de sementes de algodão deslintadas,tratadas com fungicidas e inseticida e encapsuladas não ocasiona redução na qualidade fisiológica das sementes, e o uso de corante em sementes encapsuladas não altera a sua qualidade. = This study evaluated the physiological quality of cotton seeds when subjected to encapsulation with and without dye compared with seeds treated only with fungicides (carboxin and thiran 200 Sc and insecticide (pirimiphos methyl - control. The larger mixer (capacity 40 L received delinted seeds + treated to undergo the process of encapsulation (coating and finishing with and without dye, and non-encapsulated served as control. The following treatments were established: 1 - delinted seeds and treated with fungicides (carboxin and 200 thiran Sc and insecticides (pirimiphos methyl (control, 2 - delinted seeds, processed and encapsulated (coating and finishing without dye, and 3 - delinted seeds

  8. Treatment of acidic dyes solutions by adsorption in soybean meal=Tratamento de soluções de corantes ácidos por adsorção em farelo de soja

    Directory of Open Access Journals (Sweden)

    Davi Eduardo Roza

    2012-01-01

    Full Text Available In this study, we tested the potential use of a natural sorbent based on soybean meal from oil extraction in the treatment of solutions containing the acid dyes: yellow Erionyl RXL, navy blue Erionyl R and red Erionyl A-3B, used to dye polyamide fibers. To that end, adsorption studies were performed under different conditions of temperature, adsorbent concentrations, pH values, and color mixes (two- and three-color on dye solutions produced in laboratory. Soybean meal showed great ability to remove color, especially in solutions with pH 4 and 6 at 60°C and containing 10 g L-1 of adsorbent. Considering that values of adsorption efficiency ranged between 74 and 99%, depending on the dye and treatment conditions, soybean meal proved to be an alternative material for the adsorption of acidic dyes.Neste trabalho, testou-se o potencial emprego do adsorvente natural à base de farelo de soja, proveniente da extração de óleo vegetal, no tratamento de soluções contendo os corantes ácidos: amarelo Erionyl RXL, marinho Erionyl R e vermelho Erionyl A-3B, empregados no tingimento de fibras poliamídicas. Para tanto, foram realizados estudos de adsorção em diferentes condições de temperatura, concentração de adsorvente, pH e mistura de cores (bicromia e tricromia em soluções de corantes produzidas em laboratório. O farelo de soja mostrou uma ótima capacidade de remoção de cor, principalmente nas soluções de corantes com pH’s 4 e 6 à 60ºC contendo 10 g L-1. Considerando que os valores de eficiência na adsorção ficaram entre 74 e 99%, dependendo do corante e das condições de tratamento, o farelo de soja mostrou-se um material alternativo para a adsorção dos corantes ácidos.

  9. Blenda de náilon-6,6/quitosana como adsorvente de corantes ácidos para reutilização das soluções de corantes tratadas em tingimentos de poliamida Nylon 6.6/chitosan blend as adsorbent of acid dyes for the reuse of treated wastewater in polyamide dyeing

    Directory of Open Access Journals (Sweden)

    Ivonete O. Barcellos

    2008-09-01

    Full Text Available A água é usada na indústria têxtil como veículo para os produtos químicos em geral e corantes utilizados no processo de tingimento e beneficiamento de fibras. Neste trabalho estudou-se a reutilização de rejeitos líquidos de tingimentos de tecidos de náilon 6,6 (PA 66, tratados pelo processo de adsorção, com uma blenda de PA 6,6/quitosana (80/20, na forma de flocos. Para a produção de rejeitos líquidos, realizaram-se tingimentos de tecidos de PA 66 com os corantes ácidos Yellow Erionyl RXL, Red Erionyl A-3B e Navy Blue Erionyl R. A eficiência da remoção da cor variou entre 97-98%, com exceção dos rejeitos dos tingimentos com o corante Yellow Erionyl RXL, onde se atingiu apenas eficiências de 65 e 72% para os rejeitos com e sem auxiliares têxteis, respectivamente. A reutilização dos rejeitos tratados estudou-se em tingimentos de tecidos de malha de poliamida 6,6 com os mesmos corantes. Os valores de ΔE (diferença de cor referente a tingimento padrão com água destilada de tingimentos em cores claras e médias, variaram de 0,24 a 1,05 (para os rejeitos de monocromia e 0,71 a 1,07 (para os rejeitos de tricromia, e são compatíveis com os padrões industriais (ΔE Water is used in the textile industry, mainly, as vehicle for chemicals and dyes used in the dyeing and finishing processes of textile fibers. In this work we studied the reuse of wastewater generated in the dyeing of nylon 6.6 (PA6.6 fabrics and treated by adsorption process with nylon 6.6/chitosan (80/20 blend flakes was studied. To produce the wastewater PA 6.6 fabrics were dyed with the acid dyes Yellow Erionyl RXL, Red Erionyl A-3B and Navy Blue Erionyl R. The efficiency in color removal of the adsorption process varied between 97-98%, with exception of the effluents from Yellow Erionyl RXL dyeing, where only efficiencies of 65% (wastewater with auxiliaries and 72% (without auxiliaries were obtained. The reuse of the treated wastewater was studied in dyeing

  10. Acoplamento das micro-ondas ao processo oxidativo avançado UV/H2O2 para a degradação de corantes ácidos

    OpenAIRE

    Mônica Paquese Fracca

    2014-01-01

    Os efluentes corados ainda são um problema em estações de tratamento de esgoto. Os corantes normalmente apresentam estruturas complexas e difíceis de serem degradadas por processos convencionais, entrando no meio ambiente aquático e causando impacto visual, mudanças nas características físico-químicas da água, prejudicam a fotossíntese do meio e podem apresentar efeitos ecotóxicos. Para o tratamento de vários tipos de efluentes, os Processos Oxidativos Avançados (POAs) são eficientes, rápidos...

  11. DETERMINAÇÃO DA EFICÁCIA DE DIFERENTES SOLVENTES ORGÂNICOS NA DISSOLUÇÃO DOS CORANTES NATURAIS BIXINA E NORBIXINA

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    MARCO AURÉLIO DA SILVA COUTINHO

    2017-05-01

    Full Text Available Resumo: Nos últimos anos, os pigmentos naturais de urucum têm sido substancialmente utilizados pelas indústrias de alimentos para dar cor a produtos tais como: massas alimentícias, cereais, produtos de panificação, gelados comestíveis, sobremesas, condimentos, etc. Dentre esses pigmentos destaca-se a bixina, um éster monometílico do ácido dicarbixílico alfa-norbixina pouco solúvel em óleo e anorbixina um caratenóide diácido carboxilico. Em virtude da crescente aplicação industrial  dos corantes naturais, este trabalho teve como objetivo determinar a solubilidade desses pigmentos em diferentes solventes, por meio de espectrofotometria UV-vis. Foram preparadas soluções sob as mesmas condições, utilizando-se os solventes: acetona, álcool etílico, álcool isopropílico, dimetilsulfóxido e clorofómio. A absorbância foi medida em função do comprimento de onda de cada solução por meio da análise dos espectros de UV-Vis, na região de 800 a 200 nm. Os dados obtidos referentes às análises no UV-Vis confirmaram a maior eficácia do Dimetilsulfóxido (DMSO na dissolução da bixinae  e da acetona para o norbixina  em relação aos outros solventes.

  12. Estudos de sorção do corante vermelho dianix em filmes de pet através dos processos convencional e CO2 supercrítico - DOI: 10.4025/actascitechnol.v25i1.2234

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    Aline Aparecida de Oliveira Barbosa

    2003-04-01

    Full Text Available O polímero poli(tereftalato de etileno – PET – tem tido suas propriedades de superfície modificadas, visando às mais diversas aplicações. O dióxido de carbono supercrítico (CO2SC tem um grande potencial para a modificação e o processamento de polímeros sólidos, devido à sua alta difusividade e poder de solvatação. O objetivo do presente trabalho foi investigar a incorporação do corante Vermelho Dianix em filmes de PET modificados e não-modificados com N,N-dimetilacrilamida, nos processos de CO2 SC e em meio aquoso. No processo com CO2SC, o tratamento dos filmes de PET modificados com N,N-dimetilacrilamida aumentou, em média, 1,6 vezes a quantidade de corante incorporado. Já em meio aquoso, a incorporação do corante nos filmes de PET modificados com N,N-dimetilacrilamida aumentou, em média, 2 vezes; no entanto, a quantidade absorvida pelo PET foi menor. A quantidade de corante incorporado em filmes de PET foi determinada por espectrofotometria UV-VIS a 520nm, usando N,N - dimetilformamida como solvente.

  13. Electrohemical properties of carbon nanotube paste electrodes modified with redox cationic dyes=Propriedades eletroquímicas de eletrodos a base de pasta de nanotubo de carbono modificados com corantes redox catiônicos

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    Arnaldo César Pereira

    2012-07-01

    Full Text Available The present work describes the electrochemical behavior of methylene blue and toluidine blue as electron mediators adsorbed in the multiwall carbon nanotubes paste. Based on midpoint potential and separation of cathodic and anodic peaks (ΔE, it was not observed interaction of different eletrolytes with the cationic dyes by an ion exchange reaction and, as a consequence, absence of leaching of cationic dyes to the solution phase. The kinetics of electron transfer on the surface electrode was not sufficiently fast showing a fairly resistence of carbon nanotube paste modified with the mediators. The midpoint potential and ΔE also were insentive to the pH range (4-8, confirming the protective effect of carbon nanotubes matrix, owing to strong interaction of between the latter and the nitrogen of nitrogen of cationic dyes with carbon nanotube matrix, minimizing the proton interaction under cationic dye. This result is very important for sensor/biosensor preparation, because the eletrooxidation behavior of the analyte will be only affected by its formal potencial shifting. Carbon nanotubes proved to be an efficient solid matrix for the adsorption of mediator electron in comparison to the electrochemical behavior of free cationic dyes in solution phase.O presente trabalho descreve o comportamento eletroquímico de azul de metileno e azul de toluidina como mediadores de elétrons adsorvidos em pasta de nanotubo de carbono multiparede. Com base no potencial médio e na separação de pico catódico e anódico (ΔE, não foi observada interação de diferentes eletrólitos com os corantes catiônicos por meio de reação de troca iônica e, como consequência, ausência de lixiviação dos corantes para solução. A cinética de transferência de elétron na superfície do eletrodo não foi suficientemente rápida, mostrando razoável resistência da pasta de nanotubo de carbono modificada com os mediadores. O potencial médio e ΔE também foram insens

  14. Comparação entre diferentes processos oxidativos avançados para degradação de corante azo Comparison of various advanced oxidation processes for azo dye degradation

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    Camila Costa de Amorim

    2009-12-01

    Full Text Available O objetivo deste estudo foi comparar os processos de oxidação avançada (H2O2, UV, UV/H2O2, Fe2+/H2O2, UV/Fe2+/H2O2 para descoloração do corante têxtil Reactive Red 195. Também foi investigada a utilização do pó do desempoeiramento da ala de corrida do alto forno como fonte alternativa de ferro na peroxidação catalítica, com e sem radiação UV, para degradação do corante. O efeito das concentrações de H2O2 e corante na cinética de descoloração foram estudados. Os resultados indicaram que a maior eficiência de descoloração foi obtida através do sistema foto-Fenton com o uso do resíduo; entretanto, a utilização do resíduo no sistema Fenton sem irradiação atingiu a mesma eficiência, com tempo de reação aumentado em apenas 15 minutos. A utilização do resíduo siderúrgico aumentou a velocidade de descoloração, mostrando-se bastante promissora como fonte de ferro.This study aimed at comparing various advanced oxidation processes (H2O2, UV, UV/H2O2, Fe2+/H2O2, UV/Fe2+/H2O2 for textile dye Reactive Red 195 decolorization. The use of blast furnace dust (BFD was also investigated as an alternative source of iron in catalytic peroxidation with and without UV radiation. The effects of H2O2 and dye concentrations in kinetics of decolorization were studied. Decolorization reactions follow pseudo-first order kinetics. The results indicated greater efficiency of decolorization in the photo-Fenton system with the use of BFD; however, the use of BFD in the Fenton system without irradiation reached the same efficiency with a reaction time only 15 minutes superior. The use of blast furnace dust increased considerably the rates of reactions and is very promising as a source of iron.

  15. Síntese e caracterização de filmes de óxidos metálicos nanoparticulados para aplicação em células solares sensibilizadas por corante (DSCs)

    OpenAIRE

    Paula, Leonardo Ferreira de

    2014-01-01

    Neste trabalho foram preparados filmes finos e compactos de óxidos nanoparticulados de TiO2, Nb2O5 e WO3 para a aplicação como camada de contato/bloqueio em células solares sensibilizadas por corante (DSCs). Os filmes foram produzidos pela deposição de 30 bicamadas de TiO2(ác)/TiO2(bás), TiO2(ác/Nb2O5(bás) e TiO2(ác)/WO3(bás) utilizando a técnica de automontagem (Layer-by-Layer ou LbL), a partir dos sóis nanoparticulados de TiO2 (pH = 2 e 10), Nb2O5 (pH = 10) e WO3 (pH = 10) sintetizados pelo...

  16. Identificação dos compostos produzidos na degradação do corante Remazol Brilliant Blue R (RBBR) pela ação do fungo do ambiente marinho Tinctoporellus sp.

    OpenAIRE

    Julie Paulin Garcia Rodriguez

    2014-01-01

    No presente trabalho foram estudados os metabólitos gerados no processo de biodegradação do corante Remazol brilliant blue R (RBBR) pelo fungo Tinctoporellus sp. em meio líquido. Foi investigada a descoloração do meio de fermentação causada por o processo de degradação, monitorando-se a absorbância da solução durante 17 dias por espectrofotometria UV-Vis. Na presença do fungo Tinctoporellus sp. observou-se uma perda de 90% da coloração do meio de crescimento contendo RBBR 90% em um período de...

  17. Dentin penetrability evaluation of three different dyes in root-end cavities filled with mineral trioxide aggregate (MTA Avaliação da penetração dentinária de três diferentes corantes em retrocavidades obturadas com agregado trióxido mineral (MTA

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    Beatriz Farias Vogt

    2006-04-01

    Full Text Available The purpose of this study was to evaluate the penetration of three dyes in MTA root-end fillings. In 30 single-rooted teeth, cavities for retrofilling were prepared with an ultrasound appliance and filled with MTA. The specimens were randomly assigned to three groups (n = 10 and immersed in the following solutions: 2% methylene blue (MET, 50% silver nitrate (NIT and 0.2% rhodamine B (ROD. Two transversal slices (1 mm of the retrofilling region were obtained and evaluated using the Image Tool 3.0 software to obtain a quantitative evaluation (in mm² of the dye penetration around the retrofillings. Data were submitted to statistical analysis using Student’s t-test. The lowest degree of dye penetration was observed for the NIT group, in both slices (p A proposta deste trabalho foi avaliar a penetração de três corantes em retrocavidades obturadas com MTA. As retrocavidades foram confeccionadas com aparelho de ultra-som em 30 dentes unirradiculares e obturadas com MTA. Os espécimes foram divididos aleatoriamente em três grupos (n = 10 e imersos nas seguintes soluções corantes: azul de metileno a 2% (MET, nitrato de prata a 50% (NIT e rodamina B a 0,2% (ROD. Duas fatias transversais (1 mm da região retrobturada foram obtidas e avaliadas através do software Image Tool 3.0, objetivando quantificar a área (em mm² de penetração do corante ao redor das retrobturações. Os dados foram submetidos à análise estatística, utilizando o teste t de Student. A menor área de penetração foi observada no grupo NIT, nas duas fatias (p < 0.05. A penetração de corante foi significativamente maior no grupo ROD quando comparado ao grupo NIT, nas duas fatias (p < 0.05, e ao grupo MET, somente na fatia 1 (p < 0.05. Dentro das limitações desta pesquisa, concluiu-se que a escolha da solução corante pode influenciar a avaliação da penetração em estudos sobre retrobturações e que o grupo NIT teve a menor capacidade de penetração na dentina

  18. Risco de contaminação do corante azul de tripano após primeira utilização Risk of contamination of trypan blue dye after first use

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    João Baptista Nigro Santiago Malta

    2006-02-01

    Full Text Available OBJETIVOS: Determinar o potencial risco de contaminação do frasco de azul de tripano (AT depois de utilizado pela primeira vez e estocado em diferentes condições de temperatura e umidade, assim como identificar os possíveis fatores de contaminação, microrganismos mais freqüentemente envolvidos e simultaneamente avaliar as propriedades bacteriostáticas e bactericidas do corante. MÉTODOS: Realizado estudo experimental, prospectivo, em que 30 frascos de AT foram divididos em três grupos (A: controle, B: armazenamento em geladeira e C: armazenamento em armário. O corante era aspirado e semeado em placas de ágar sangue e tubo de ágar Sabouraud. No grupo A o AT foi semeado apenas logo após a abertura dos frascos (tempo zero - T0, nos grupos B e C ocorreu semeadura nos T0, T1 (1 dia, T2 (2 dias, T7 (7 dias e T10 (10 dias após abertura dos frascos. No 10º dia os frascos dos grupos B e C também foram submetidos a um raspado do lado interno do frasco após abertura. Concomitantemente foi realizado teste de ação inibitória do corante AT para estudo da atividade bacteriostática e bactericida. RESULTADOS: As semeaduras realizadas no T0 não apresentaram contaminação. Entre os T1 e T10 mais o raspado houve apenas 1 frasco contaminado armazenado em geladeira. O microrganismo encontrado foi o Aspergillus niger. Foi comprovado que o corante não apresenta ação bactericida e bacteriostática para as bactérias testadas. CONCLUSÕES: Nas condições do estudo não houve contaminação dos frascos armazenados em armário e 1 frasco (10% armazenado em geladeira apresentou contaminação após abertura e uso inicial. A fonte de contaminação talvez seja o lado externo do produto. O AT não apresenta propriedades bactericidas e bacteriostáticas para as bactérias testadas e na concentração utilizada.PURPOSE: To determine the potential risk of contamination of a trypan blue bottle (TB after first use and after being stored under different

  19. Energy alternative for the use of organic waste (swine feces) in the state of Tabasco; Alternativa energetica para el aprovechamiento de los desechos organicos (excretas de ganado porcino) en el estado de Tabasco

    Energy Technology Data Exchange (ETDEWEB)

    Ramon Garcia, E.; Angles Falconi, S.I.; Vazquez Magana, L.R.; Tun Perez, A.C. [Instituto Tecnologico de Villahermosa, Villahermosa, Tabasco (Mexico)]. Email: bioleliza_ramgar@hotmail.com; sergio_falcorp@hotmail.com

    2009-09-15

    Biogas is obtained from decomposing organic material due to the action of four types of bacteria, in the absence of oxygen: hydrolytic, producers of moncarbonate compounds and acidogenics, producing organic fatty acids and other polycarbonate compounds; acetogenic, producers of hydrogen and CO{sub 2}; homoacetogenic, that can convert a considerable amount of multicarbonate or monocarbonate compounds into acetic acid and; metanogenic, producers of methane gas, the principal component of biogas. To design and build the pilot equipment proposed for this research, a 20-liter container was used with 10 kg of swine feces with identical volumes of inoculates. The aerobic fermentation process was immediate begun, followed by the anaerobic process; metabolic reactions were conducted. A total of 0.119 m3 of biogas was obtained from the anaerobic fermentation of 10 kg of swine feces, 60% (0.0714 m{sup 3}) of which was methane gas and the remaining 40%(0.0476 m{sup 3}) hydrogen sulfide (HS). During this investigation, it was concluded that obtaining this by-product (methane biogas), which can be used as a biofuel, provides an economically and ecologically sustainable alternative that reduces organic discharges (swine feces) into rivers and reduces the energy expenditures of swine farms. Because of the high generation of RSM, the creation of a biogas production plant in Tabasco is proposed. [Spanish] El biogas se obtiene al descomponerse la materia organica debido a la accion de cuatro tipos de bacterias, en ausencia de oxigeno: las hidroliticas, que producen compuestos monocarbonados, las acidogenicas producen acidos grasos organicos y otros compuestos policarbonados; las acetogenicas productoras de Hidrogeno y CO{sub 2}; las homoacetogenicas, que pueden convertir una cantidad considerable de compuestos multicarbonados o monocarbonados en acido acetico; y las metanogenicas, productoras del gas metano, principal componente del biogas. Para el diseno y construccion del equipo

  20. Citotoxicity of food dyes sunset yellow (E-110, bordeaux red (E-123, and tatrazine yellow (E-102 on Allium cepa L. root meristematic cells Citotoxicidade dos corantes alimentares amarelo crepúsculo (E-110, vermelho bordeaux (E-123 e amarelo tartrazina (E-102 em células meristemáticas de raízes de Allium cepa L.

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    Keiva Maria Silva Gomes

    2013-03-01

    Full Text Available The objective of this study was to evaluate the cytotoxic effect of the food dyes sunset yellow, bordeaux red, and tartrazine yellow on the cellular cycle of Allium cepa L. Each dye was evaluated at the doses of 0.4 and 4.0 mL, at the exposure times of 24 and 48 hours in root tip cells of Allium cepa L. Slides were prepared and cells were analyzed during the whole cell cycle for cellular aberrations totaling 5,000 total cells for each dose evaluated. The mitotic index was calculated, and statistical analysis was performed using the Chi-squared test (p Este estudo teve por objetivo avaliar o efeito citotóxico dos corantes alimentares amarelo crepúsculo, vermelho bordeaux e amarelo tartrazina sobre o ciclo celular de Allium cepa L. Cada corante foi avaliado nas doses de 0,4 e 4,0 mL, nos tempos de exposição de 24 e 48 horas, em células de pontas de raízes de Allium cepa L. Prepararam-se lâminas e analisaram-se células, em todo o ciclo celular, e a presença de aberrações celulares, totalizando 5.000 células para cada dose avaliada. Foi calculado o índice mitótico e a análise estatística foi feita por meio do teste quiquadrado (p < 0,05. Os resultados mostraram que os três corantes, nas doses e tempos de exposição avaliados, foram citotóxicos às células do sistema-teste utilizado. Estudos adicionais de citotoxicidade devem ser conduzidos para se somar a estes resultados e, assim, avaliar, com propriedade, a ação destes três corantes em nível celular.

  1. Ação de Micoflora de efluentes agroindustriais sobre diferentes corantes e substratos lignocelulósicos =Action of mycoflora from agri-industrial effluents on different dyes and lignocellulosic substrates

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    Ana Maria Queijeiro López

    2011-09-01

    Full Text Available Enzimas extracelulares de fungos são importantes para sua sobrevivência em ambientes inóspitos, sendo capazes de degradar compostos recalcitrantes. Fungos filamentosos secretam hidrolases e fenoloxidases capazes de degradar complexos de estruturas aromáticas,como de alguns xenobióticos. O propósito deste trabalho foi testar diferentes corantes (Azul de Metileno, Azure B, Verde Malaquita e Cristal Violeta, em substituição ao composto Poly R478, no método de seleção de microrganismos degradadores de fenóis em meio sólido, além de comparar tal atividade de Micoflora isolada de efluentes de indústria sucroalcooleira com a de outros fungos adquiridos em coleção oficial. Os corantes testados revelaram-se ótimos substitutos do Poly R478. O isolado que apresentou atividade descolorante mais intenso do que a do diâmetro de seu crescimento (Cladosporium sp. foi testado, então, em meio líquido frente a dois substratos naturais e um sintético (bagaço de cana, serragem de madeira e azul de metileno. Este removeu altas concentrações de glic��dios redutores, proteínas e fenóis totais, além de reduzir a DQO em meio com serragem de madeira como substrato fenólico natural. Tal fungo, portanto, mostrou-se promissor para compor consórcios visando cometabolismo ebiorremediação de efluentes nos quais há presença de compostos fenólicos ou outros recalcitrantes com estrutura semelhante à de lignina.Extracellular enzymes of fungi are important for survival in inhospitable environments, as they are able to degrade recalcitrant compounds. Filamentous fungi secrete hydrolases and phenoloxidases that are capable of degrading complexes of aromatic structures, such as certain xenobiotics. The purpose of this study was to test different dyes (methylene blue, Azure B, Malachite Green and Crystal Violet, replacing the compound Poly R478 in the method of selection of phenol decomposer microorganisms in solid medium, and compare this

  2. Efeito da temperatura e do tamanho de partículas na adsorção do corante Remazol Amarelo Ouro RNL em carvão ativado - DOI: 10.4025/actascitechnol.v31i2.1310

    Directory of Open Access Journals (Sweden)

    Expedito Besinella Junior

    2009-06-01

    Full Text Available Os efluentes de tinturaria constituem um problema ambiental, uma vez que apresentam elevada quantidade de carga orgânica e de cor. Os processos de coagulação e adsorção são os mais utilizados na remoção de corantes têxteis. Neste trabalho foram determinadas as isotermas de adsorção do corante reativo Remazol Amarelo Ouro RNL em carvão ativado de casca de coco. Foram estudadas duas variáveis: temperatura (30 e 40ºC e tamanho de partícula (1,70 ± 0,30 mm e 3,00 ± 0,40 mm. Os resultados mostraram que o aumento na temperatura ou a diminuição do diâmetro das partículas promove aumento na adsorção. O modelo de Langmuir-Freundlich apresentou melhor ajuste entre os modelos testados.

  3. Il Punto Organico: una storia italiana

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    Paolo Rossi

    2015-02-01

    The origin of the notion of P.O. is traced back to some statistical studies performed more than a decade ago . Its subsequent application to university recruiting follows from  a sequel of administrative actions taken by the Ministry but it is not based on an explicit (and formally required legal formulation. The recent structural evolution of the università system and some changes in the legislation have further weakened the justification for such a constraint.  An alternative (and legally consistent mechanism for keeping under control the projected expenses  for personnel is proposed.

  4. CROMATOGRAFIA DE AFINIDADE COM CORANTE RED A versus TROCA IÔNICA-PERMEABILIDADE EM GEL: COMPARAÇÃO DA PRATICIDADE NA PURIFICAÇÃO DE ENTEROTOXINA ESTAFILOCÓCICA A

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    M. KAMOGAE

    1998-05-01

    Full Text Available O presente trabalho compara processos de purificação de enterotoxina estafilocócica A, utilizando cromatografia de afinidade com corante Red A em relação a troca iônica (SP - Sephadex C-25 - permeabilidade em gel (Sephadex G-75. Aplicou-se nas colunas o sobrenadante da cultura de Staphylococcus aureus 722 em caldo contendo 3% de triptona e suplementado com 1% de extrato de levedura, previamente concentradas com Amberlite CG-50. O processo capturou rapidamente a EEA, porém a proporção de 15 mg de resina para 150 mg de toxina causou saturação, recuperando apenas 10 a 30% de toxina do sobrenadante. A cromatografia de afinidade com Red A permitiu a recuperação de 60,87% de toxina aplicada em 76 horas, em relação a 114 horas requeridas para purificação utilizando coluna de troca iônica e permeabilidade em gel, com rendimento de 6,5%. O perfil eletroforético das amostras purificadas indicaram que, a toxina obtida da coluna Red A apresentou teor de pureza superior, na ordem de 90%, em relação a 60% atingida pelo método clássico.Culture supernatant of Staphylococcus aureus 722 in 3% triptone plus 1% yeast extract was used for EEA purification, proceeding comparison between dye ligand Red A affinity chromatography and classic chromatography. The capture of SEA with Amberlite CG-50 allowed rapid enterotoxin concentration from the culture supernatant. However, the ratio of 15 mg of the resin to a total of 150 mg of the toxin satured the resin, giving only 10 to 30% of SEA recuperation from the supernatant. The elution of concentrated material throught the Red A column resulted in a recovery of 60,87% of the toxin, and required 76 hours, indicating advantage on classic chromatography. Ion exchange column plus gel filtration recovered only 6,5 % of the SEA, and required 114 hours to conclude the procedure. The eletrophoresis of purified SEA indicated high grade of toxin obtained from Red A column, with 90 % of purity, compared to 60

  5. Descoloração de efluentes aquosos sintéticos e têxtil contendo corantes índigo e azo via processos Fenton e foto-assistidos (UV e UV/H2O2 Decolorization of synthetic and laundry wastewater containing indigo and azo dyes by the Fenton, photolytic and UV/H2O2 processes

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    Bruno César Barroso Salgado

    2009-03-01

    Full Text Available No presente trabalho, processos de oxidação avançada, Fe2+/H2O2 e UV/H2O2, e de fotólise (UV foram empregados na descoloração de dois efluentes sintéticos, contendo corantes tipo índigo e azo, e de um efluente de lavanderia industrial. Experimentalmente, soluções em concentração de 20 mg/L dos corantes índigo carmim e vermelho congo, respectivamente 43 µmol/L e 29 µmol/L, e o efluente têxtil (pH = 3 foram submetidos a diferentes condições oxidantes sob temperatura ambiente (27 ºC. As remoções de cor e de DQO foram avaliadas em cada sistema oxidativo estudado. Em geral, os resultados obtidos mostraram que os processos utilizados são muito promissores na descoloração dos efluentes. A descoloração completa das soluções foi alcançada nos processos Fenton e com UV/H2O2. Estudos cinéticos revelam que a taxa de descoloração em meio aquoso segue uma cinética de pseudo-primeira ordem em relação à concentração do corante.In the present work, advanced oxidation processes, Fe2+/H2O2 and UV/H2O2, and direct photolysis (UV light have been applied in the decolorization of two synthetic wastewater containing indigo and azo dyes and laundry effluent. Individual aqueous solutions containing 20 mg/L indigo carmine and congo red dyes (43 µmol/L and 29 µmol/L, respectively and textile laundry wastewater at pH 3 were subjected to different experimental conditions in the oxidation reactions at room temperature (27 ºC. Color and COD removals were evaluated for each oxidation systems. The results showed that the utilized processes are able to successfully decolorize the wastewaters. Complete bleaching was achieved by Fenton and UV/H2O2. Also, kinetics investigations revealed that the decolorization follows pseudo-first order kinetic with respect to the dye concentration.

  6. Formulação e estabilidade de corantes de antocianinas extraídas das cascas de jabuticaba (Myrciaria ssp.
    Formulation and stability of anthocyanins’s colorants formulated with peels jabuticaba (Myrciaria ssp.

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    G. J. F. SILVA

    2010-12-01

    Full Text Available

    A busca de fontes alternativas de pigmentos naturais tem estimulado o desenvolvimento de pesquisas em diferentes frutos tropicais, como a jabuticaba. Esse fruto é rico em antocianinas, um pigmento natural que, além da capacidade de conferir cor, também possui capacidade antioxidante na captura de radicais livres, responsáveis, dentre outras ações, pela proliferação de células tumorais e pelo envelhecimento precoce. Assim, o objetivo dessa pesquisa foi caracterizar e avaliar a estabilidade de corantes formulados a partir de cascas de jabuticaba. Os pigmentos naturais desse fruto foram associados a dois veículos estabilizantes (maltodextrina e goma arábica em três proporções diferente, submetidos ao processo de atomização e expostos a luz a uma temperatura de 25 ± 2°C, comparando-se com amostras controle não expostas a luz, armazenadas a 10 ± 2°C. A estabilidade foi avaliada através de análises de antocianinas totais, polifenóis totais, atividade antioxidante e avaliação colorimétrica. Os corantes apresentaram elevados teores de antocianinas (p0,05, tendo havido maiores degradações nas amostras armazenadas sob incidência de luz a 25°C (p0,05, evidenciando o efeito deletério da luz sob esses compostos. Comparando as três proporções dos dois carboidratos utilizados, os pigmentos antociânicos mostraram-se mais estáveis quando utilizados somente o carboidrato maltodextrina na proporção de 30%. Portanto, as cascas de jabuticaba apresentaram-se como boas fontes de pigmentos naturais, apresentando-se como alternativa viável na obtenção de corantes.

  7. Impregnação de filmes do compósito de policarbonato (PC e sílicagel (Si com corante fotocrômico em fluido supercrítico = Impregnation of composite from polycarbonate (PC and silica gel (Si films with photochromic dye in supercritical fluid

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    Fernanda de Almeida Fin de Lima

    2010-01-01

    Full Text Available O objetivo deste trabalho foi estudar a impregnação do corante fotocromático Reversacol Graphit® em filmes do compósito de policarbonato (PC e sílica-gel (Si, com a finalidade de obter aplicações em lentes fotocrômicas. Filmes de PC puros também foramimpregnados nas mesmas condições, para verificar o efeito da adição de sílica-gel. Os filmes do compósito foram produzidos em proporções de Si:PC de 1:40 e 1:80 (m m-1, pelo método casting. Para a impregnação do corante Reversacol Graphit nos filmes obtidos foiutilizado o processo supercrítico, pela sua eficiência e benefícios. A impregnação foi feita nos tempos de 15, 30, 45, 60, 90, 120, 150 e 180 min. A temperatura e a pressão adotadas foram de 60ºC e 120 bar. A quantidade de pigmento impregnado nos filmes de Si:PC – 1:40e 1:80 (m m-1 foi de 29 e 23% de massa de corante por massa de compósito, respectivamente, e para o filme de PC puro foi de apenas 2,2% massa de corante por massa de compósito. Pelas análises térmicas, verificou-se que os filmes do compósito apresentarammaior estabilidade térmica. Pela técnica de microscopia eletrônica, observou-se que os filmes de PC puro e dos compósitos Si:PC – 1:40 e 1:80 (m m-1 apresentaram uma superfície lisa e homogênea.The aim of this work was to study the impregnation of the photochromic dye Reversacol Graphit® in composite films ofpolycarbonate (PC and silica gel, with the purpose of finding applications in photochromic lenses. Pure PC films were also impregnated in the same conditions, to verify the effect of the silica-gel addition. The composites films were produced in Si:PC ratios of 1:40 and 1:80 (m m-1, using the casting method . For the impregnation of the dye Reversacol Graphit in the obtained films, the supercritical process was used due to its efficiency and benefits. The impregnation was made in the times of 15, 30, 45, 60, 90, 120, 150 and 180 minutes. The adopted temperature and pressure

  8. Avaliação da efetividade de remoção de cor de soluções corantes e efluentes têxteis pelo tratamento fotocatalítico de óxidos de ferro recobertos com dióxido de titânio

    OpenAIRE

    Lacerda, Carlúcio Antônio Mendes

    2010-01-01

    Este trabalho foi realizado para avaliar a efetividade do uso de ferritas encapsuladas com titânio (CoFe2O4@TiO2) na remoção fotocatalítica de cor de soluções corantes (azul de metileno e azul HFRL) e de efluente têxtil. A síntese do CoFe2O4@TiO2 e do TiO2 foi realizada de acordo com o método dos precursores poliméricos, sendo os materiais obtidos caracterizados por difração de raios X, adsorção de nitrogênio (técnica BET), ponto de carga zero (PCZ), dentre outras técnicas. Ensaios fotocatalí...

  9. Aplicação de Fenton, foto-Fenton e UV/H2O2 no tratamento de efluente têxtil sintético contendo o corante Preto Biozol UC Application of Fenton, photo-Fenton and UV/H2O2 in treating synthetic textile wastewater containing the dye Black Biozol UC

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    Leonardo Madeira Martins

    2011-09-01

    Full Text Available Os efluentes têxteis, geralmente, são carregados de corantes não biodegradáveis, o que dificulta o seu tratamento. Dentre as novas alternativas de tratamento estudadas, estão os Processos Oxidativos Avançados (POA. Os mesmos são processos com potencial de produzir radicais hidroxila (•OH, espécies altamente oxidantes, capazes de mineralizar a matéria orgânica. Assim, o objetivo deste trabalho foi estudar a aplicação dos POA (Fenton, foto-Fenton e UV/H2O2 no tratamento de efluente têxtil sintético contendo o corante Preto Biozol UC. Dentre os processos estudados, o mais eficiente foi o foto-Fenton (H2O2 = 1.500 mg.L-1 e Fe2+ = 75 mg.L-1, em pH = 3, que obteve 95,4% e 73,0% para as remoções de cor e demanda química de oxigênio (DQO, respectivamente.The textile wastewater is usually loaded with non-biodegradable dyes, which hinder its treatment. Advanced Oxidation Processes (AOP are among new treatment alternatives. They are processes with potential to produce hydroxyl radicals (•OH, highly oxidizing species, capable of mineralizing the organic matter. Thus, the aim of this work was to study the application of the AOP (Fenton, photo-Fenton and UV/H2O2 in the treatment of synthetic textile wastewater containing the Black Biozol UC dye. Among the studied processes, the most efficient was photo-Fenton (H2O2 = 1,500 mg.L-1 and Fe 2+ = 75 mg.L-1, at pH = 3, for color and chemical oxygen demand (COD removals of 95.4% and 73.0%, respectively.

  10. AUTOMATIC AND DIRECT MICROSCOPIC SOMATIC CELLS COUNT OF LACAUNE DAIRY SHEEP, USING THE ROSENFELD AND METHYL GREEN-PIRONIN STAINS CONTAGEM AUTOMÁTICA E MICROSCÓPICA DIRETA DAS CÉLULAS SOMÁTICAS DO LEITE DE OVELHAS DA RAÇA LACAUNE, UTILIZANDO COMO CORANTES O ROSENFELD E VERDE DE METIL E PIRONINA-Y

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    Viviani Gomes

    2010-04-01

    Full Text Available The objectives of the present study were the analysis of cell counts, the comparison between different methods for counting cells and the quantification of different types of cells observed in the milk of Lacaune sheep, using automatic somatic cell counts (SCC and direct microscopic SCC. Milk smears were stained with methyl green-pyronin-Y and Rosenfeld stain. Mean of  automatic cell counts was 0.145 x106 cells/mL of milk, and mean of direct microscopic counts using methyl green-pyronin-Y and Rosenfeld were respectively 0.157 and 0.193 x106 cells /mL of milk. Samples used in direct microscopic counts were evaluated according to the different types of cells and the following results were recorded: 0.094 and 0.14 x106 mononuclear cells /mL, 0.063 and 0.051 x106 polymorphonuclear cells /mL of milk using methyl green-pyronin-Y and Rosenfeld stain, respectively. It may be concluded that there were differences in the methods used for counting cells. The number of cells recorded was lower when methyl green-pyronin-Y and automatic counts were used, compared with direct microscopy using Rosenfeld stain.

    KEY WORDS: somatic cells and cytology, lacaune, milk, sheep.
    O presente estudo teve como objetivo a análise da celularidade, a comparação dos diferentes métodos de contagem celular e a quantificação dos diferentes tipos celulares presentes no leite de ovelha da raça Lacaune através da contagem de células somáticas (CCS automática e da CCS microscópica. Coraram-se os esfregaços lácteos com os corantes verde de metil e pironina-Y e Rosenfeld. O valor mediano da contagem celular automática foi de 0,145 x106 células/mL de leite, e os valores das contagens microscópicas diretas utilizando verde de metil e pironina-Y e Rosenfeld foram respectivamente de 0,157 e 0,193 x106 células/mL de leite. Avaliaram-se as amostras destinadas às contagens microscópicas diretas de acordo com os diferentes tipos celulares, encontrando-se os

  11. Effect of different dye solutions on the evaluation of the sealing ability of mineral trioxide aggregate Efeito de diferentes soluções corantes na avaliação da capacidade seladora do agregado de trióxido mineral

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    Mário Tanomaru Filho

    2005-06-01

    Full Text Available Alkaline materials have shown incompatibility with methylene blue dye in leakage experiments. The goal of the present study was to analyze the effect of different dyes on the evaluation of the apical sealing ability of Mineral Trioxide Aggregate root-end fillings. Fifty-six extracted human canines were submitted to root canal instrumentation and obturation. After apical resection, retrograde cavities were prepared and teeth were randomly divided into four experimental (n = 13 and two control groups (n = 2. The following root-end filling materials were used: groups 1 and 2 - Pro Root MTA (Dentsply, groups 3 and 4 - zinc oxide-eugenol cement (ZOE. Teeth in groups 1 and 3 were immersed in 2% methylene blue solution, while teeth in groups 2 and 4 were immersed in 0.2% rhodamine B in a reduced pressure environment for 48 hours. Teeth were then longitudinally sectioned and leakage was evaluated. Results were submitted to statistical analysis (ANOVA and Tukey's test. Group 1 presented the least leakage (p Tem sido demonstrada a incompatibilidade de materiais alcalinos com a solução corante de azul de metileno utilizada em testes de infiltração marginal. O objetivo do presente estudo foi analisar a influência de diferentes soluções corantes na avaliação do selamento apical proporcionado pelo agregado de trióxido mineral. Cinqüenta e seis caninos humanos extraídos tiveram seus canais radiculares instrumentados e obturados. Após a secção da porção apical, cavidades retrógradas foram preparadas e os dentes divididos aleatoriamente em quatro grupos experimentais (n = 13 e dois controles (n = 2. Foram utilizados os seguintes materiais retrobturadores: grupos 1 e 2 - Pro Root MTA (Dentsply; grupos 3 e 4 - cimento de óxido de zinco e eugenol (OZE. Em seguida, os dentes dos grupos 1 e 3 foram imersos em solução de Azul de Metileno a 2% e dos grupos 2 e 4 em solução de Rodamina B a 0,2% por 48 horas em ambiente com vácuo. Decorrido este

  12. Use of chloramine-T and two dyes in the sensitive determination of stavudine in pharmaceuticals Uso de cloramina-T e de dois corantes na determinação sensível de estavudina em medicamentos

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    Kanakapura Basavaiah

    2007-09-01

    éria-prima e nas formulações utilizando-se clroamina-T (CAT e dois corantes, alaranjado de metila e índigo carmim como reagentes. A titulação envolve o tratamento de STV com excesso medido de CAT em meio de ácido clorídrico, e, quando a oxidação se completar, o oxidante que não reagiu é determinado iodometricamente. Os métodos espectrofotométricos compreendem a adição de excesso conhecido de CAT ao STV em ácido clorídrico, seguida da determinação do oxidante residual por meio da reação com quantidade fixada de alaranjado de metila, medindo-se a absorvância a 520 nm (Método A ou índigo carmim, medindo-se a absorvância a 610 nm (Método B. Em todos os métodos, a quantidade de CAT que reagiu corresponde à quantidade de STV. No método titulométrico, a reação segue a estequiometria 1:1 (STV:CAT e é aplicável na faixa de 1,5 a 10 mg de STV. Nos métodos espectrofotométricos, a absorvância aumenta linearmente com a concentração de STV. Os sistemas obedecem a lei de Beer nos intervalos de 0,2 a 2,0 mg/mL e 1,0 a 10,00 mg/mL para os métodos A e B, respectivamente, e os valores de sensibilidade de Sandell correspondentes são 0,004 e 0,015 µg/cm². Os limites de detecção e de quantificação são apresentados para ambos os métodos. A precisão e a exatidão intra-dia e inter-dia dos métodos desenvolvidos são avaliadas de acordo com as normas ICH. Os métodos foram aplicados com êxito aos ensaios de STV em comprimidos e em cápsulas e os resultados foram comparáveis com aqueles obtidos com o método de referência, utilizando-se o teste t de Student e o teste F. Não se observou interferência dos adjuvantes comuns em comprimidos. A exatidão e a confiabilidade dos métodos foram ajustadas por meio de experimentos de recuperação via método de adição de padrão.

  13. STUDY OF THE ANIONS EFFECT OF THE DEGRADATION OF THE DYE REMAZOL RED RB 133% BY H2O2/UV = ESTUDO DO EFEITO DOS ÂNIONS NA DEGRADAÇÃO DO CORANTE REMAZOL VERMELHO RB 133% POR H2O2/UV

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    Jefferson Pereira Ribeiro

    2014-06-01

    Full Text Available Industrial activities that consume excess water in its manufacturing process, typically generate a high volume of effluents, the textile industry being a typical example. The chemical oxidation is an alternative for the treatment of effluents containing textile dyes, among them stand out from the advanced oxidation processes (AOPs are based on the generation of hydroxyl radicals (. OH in which are highly oxidizing processes and can decompose compounds quickly and non-selective manner, leading to partial or complete mineralization of the contaminant. We studied the effect of anions on the degradation of the dye Remazol Red RB 133% by combined treatment H2O2/UV. The results of the removal efficiencies of color at the end of the process indicated that there was no difference between treatments in the presence of anions in the studied concentration (10 mM compared the degradation without the presence of these anions, because at the end of all treatments the solution was colorless. For the parameter of chemical oxygen demand (COD was no influence on the removal efficiencies of the studied anions, especially for NO3¬-, Cl-, and PO43-. = As atividades industriais que consomem excesso de água no seu processo industrial, normalmente geram um elevado volume de efluentes, sendo a indústria têxtil um exemplo típico. A oxidação química é um dos processos alternativos para o tratamento de efluentes contendo corantes têxteis, entre eles destacam-se os processos oxidativos avançados (POAs que são baseados na geração de radicais hidroxilas (.OH no qual são altamente oxidantes, podendo decompor compostos de maneira rápida e não-seletiva, conduzindo a mineralização parcial ou completa do contaminante. Neste trabalho estudou-se o efeito dos ânions na degradação do corante remazol vermelho RB 133% pelo tratamento combinado H2O2/UV. Os resultados das eficiências de remoção de cor ao final do processo indicaram que não houve diferença entre

  14. Ação de Micoflora de efluentes agroindustriais sobre diferentes corantes e substratos lignocelulósicos - doi: 10.4025/actascibiolsci.v33i4.6187 Action of mycoflora from agri-industrial effluents on different dyes and lignocellulosic substrates - doi: 10.4025/actascibiolsci.v33i4.6187

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    Ana Maria Queijeiro López

    2011-09-01

    Full Text Available Enzimas extracelulares de fungos são importantes para sua sobrevivência em ambientes inóspitos, sendo capazes de degradar compostos recalcitrantes. Fungos filamentosos secretam hidrolases e fenoloxidases capazes de degradar complexos de estruturas aromáticas, como de alguns xenobióticos. O propósito deste trabalho foi testar diferentes corantes (Azul de Metileno, Azure B, Verde Malaquita e Cristal Violeta, em substituição ao composto Poly R478, no método de seleção de microrganismos degradadores de fenóis em meio sólido, além de comparar tal atividade de Micoflora isolada de efluentes de indústria sucroalcooleira com a de outros fungos adquiridos em coleção oficial. Os corantes testados revelaram-se ótimos substitutos do Poly R478. O isolado que apresentou atividade descolorante mais intenso do que a do diâmetro de seu crescimento (Cladosporium sp. foi testado, então, em meio líquido frente a dois substratos naturais e um sintético (bagaço de cana, serragem de madeira e azul de metileno. Este removeu altas concentrações de glicídios redutores, proteínas e fenóis totais, além de reduzir a DQO em meio com serragem de madeira como substrato fenólico natural. Tal fungo, portanto, mostrou-se promissor para compor consórcios visando cometabolismo e biorremediação de efluentes nos quais há presença de compostos fenólicos ou outros recalcitrantes com estrutura semelhante à de lignina.Extracellular enzymes of fungi are important for survival in inhospitable environments, as they are able to degrade recalcitrant compounds. Filamentous fungi secrete hydrolases and phenoloxidases that are capable of degrading complexes of aromatic structures, such as certain xenobiotics. The purpose of this study was to test different dyes (methylene blue, Azure B, Malachite Green and Crystal Violet, replacing the compound Poly R478 in the method of selection of phenol decomposer microorganisms in solid medium, and compare this activity

  15. Esferas de quitosana/Fe na degradação do corante Azul QR-19 por processos foto-Fenton utilizando luz artificial ou solar Chitosan/Fe spheres on the Blue QR-19 dye degradation by photo Fenton processes using artificial or solar light

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    Kely V. de Souza

    2010-09-01

    Full Text Available A contaminação dos recursos hídricos é um dos maiores problemas ambientais da atualidade. Dentre as várias fontes poluidoras, destacam-se as indústrias têxteis, por serem fontes geradoras de grandes volumes de efluentes, muitas vezes tratados de maneira ineficiente. A principal causa do grande impacto ambiental decorrente deste descarte é a presença dos corantes, tais como os compostos do tipo azo, que podem gerar subprodutos de caráter carcinogênico e/ou mutagênico, ou como os de base antraquinona, que são muito resistentes à degradação natural e portanto persistem no efluente por um longo tempo. O objetivo do presente trabalho consiste na utilização de processos foto-Fenton assistidos por luz artificial e solar, utilizando ferro imobilizado em esferas de quitosana reticulada com glutaraldeído, para promover a degradação do corante reativo Azul QR-19, de base antraquinona, em solução aquosa. As esferas obtidas apresentaram tamanho regular com diâmetro de 4,0 mm. Os resultados demonstraram 90% de descoloração do sistema em 180minutos e redução de 60% do teor de carbono orgânico total (COT, para o sistema foto-Fenton utilizando luz artificial. Para o sistema fotoassistido com luz solar, a descoloração foi integralmente obtida em 120 minutos com 70% de redução do teor de COT. Foi observado que o ferro permaneceu na matriz após o tratamento, possibilitando sua reutilização.The contamination of water resources is one of the greatest environmental problems today. Among the polluting sources are the textile industries due to the production of large volumes of effluent, often treated inefficiently. The main reason for the environmental impact of the rejected materials is the presence of dyes such as azo reactive compounds that can generate by-products with carcinogenic and mutagenic effects. They may also include anthraquinone type compounds, which are highly resistant to degradation and persist in the effluent for a

  16. Avaliação do tratamento físico-químico e biológico dos resíduos de corantes produzidos em laboratório de microbiologia - DOI: 10.4025/actascitechnol.v32i1.7545

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    Lenice Leiko Nozu

    2009-12-01

    Full Text Available Os diferentes resíduos produzidos pelo homem em diversas áreas representam grave problema ambiental, quando inadequadamente descartados. No presente trabalho, foram realizados experimentos de degradação de resíduos de corantes gerados no Laboratório de Microbiologia da Universidade Tecnológica Federal do Paraná, Campus Curitiba, por meio do cultivo líquido implementado com Pleurotus sajor-caju e processo oxidativo avançado (POA – Sistema UV/H2O2. A verificação da eficiência desses processos foi realizada por meio do acompanhamento da redução de cor e dos compostos aromáticos por análise espectrofotométrica em UV-vis, da redução de matéria orgânica (análise de DQO e de bioensaios de toxicidade com Escherichia coli e com sementes de Lactuca sativa. A partir dos resultados obtidos, constatou-se que o processo combinado – cultivo líquido seguido de peroxidação com irradiação ultravioleta, demonstrou ser o tratamento mais eficiente para a redução de cor (90-95% e degradação de aromáticos (16-20%. Os bioensaios revelaram que as amostras do resíduo bruto não inibiram o crescimento da E. coli e mostraram potencial tóxico para a espécie L. sativa, apresentando de 30 a 57% de inibição da germinação das sementes testadas.

  17. Ligninases production by Basidiomycetes strains on lignocellulosic agricultural residues and their application in the decolorization of synthetic dyes Produção de ligninases por linhagens de fungos Basidiomicetos usando resíduos agrícolas lignocelulósicos e aplicação das enzimas na descoloração de corantes sintéticos

    Directory of Open Access Journals (Sweden)

    Eleni Gomes

    2009-03-01

    . byrsina produziu a maior quantidade de lacase (200 U mL-1 enquanto que Lentinus sp. foi o melhor produtor de manganês peroxidase (MnP e lignina peroxidase (LiP (7 e 8 U mL-1, respectivamente, quando cultivados em meio composto por farelo de trigo. A avaliação do efeito da suplementação de nitrogênio do substrato sólido lignocelulósico (palha de arroz indicou um aumento de 3 a 4 vezes na produção de lacase. A caracterização das enzimas mostrou que as lacases apresentaram atividade ótima em pH 3,0-3,5 e foram estáveis em pH de neutro a alcalino. O pH ótimo para atividade de MnP e LiP foi de 3,5 e entre 4,5 e 6,0, respectivamente. Todas as linhagens produziram lacase com atividade ótima a 55-60°C, enquanto as peroxidases apresentaram atividades máximas entre temperaturas de 30 e 55°C. A aplicação das soluções enzimáticas brutas, obtidas pelo cultivo das linhagens em meio de farelo de trigo, em testes de descoloração de corantes sintéticos de diferentes grupos químicos levou a mais 70% de perda de cor dos corantes RBBR e de cybacron blue 3GA, em 6h de tratamento. Os dados obtidos indicaram que as soluções enzimáticas contendo ligninases produzidas pelas linhagens de basidiomicetos estudadas promoveram a descoloração de corantes sintéticos.

  18. Volatile organic compounds determination in the atmosphere of Mexico City by the use of optical systems and non conventional methods; Determinacion de compuestos organicos volatiles en la atmosfera de la Ciudad de Mexico mediante el uso de sistemas opticos y metodos convencionales

    Energy Technology Data Exchange (ETDEWEB)

    Ruiz, Maria Esther; Arriaga, Jose Luis; Garcia, Isidoro [Gerencia de Ciencias de Ambiente, Instituto Mexicano del Petroleo, Mexico, D.F. (Mexico)

    1996-04-01

    results presented here were obtained through collaboration of the Environmental Sciences group of the Mexican Petroleum Institute (GCA-IMP) with different people and groups. [Spanish] Desde 1991, se han determinado las concentraciones de los componentes orgaicos volatiles (COV) presentes en la atmosfera de la Zona Metropolitana de la Ciudad de Mexico (ZMCM) mediante diferentes metodos de muestreo y analisis. Las muestras recolectadas en cartuchos y canisteres se analizan por cromatografia de gases o de liquidos. Tambien se ha iniciado el monitoreo continuo de la atmosfera mediante un analizador de la absorcion diferencial en trayectorias largas conocido como DOAS. El Instituto Mexicano del Petroleo junto con la Agencia de Proteccion al Ambiente de los Estados Unidos (EPA) y las autoridades ambientales en Mexico han llevado a cabo cuatro campans de muestreo y analisis de aire del ambiente en canisteres, siguiendo la metodologia TO-14 de la EPA. Las campans se han llevado a cabo en el mes de marzo, porque es en este mes cuando han sucedido los peores episodios de ozono. Se han hecho muestreos adicionales durante el mes de noviembre con objeto de comparar los resultados entre las diferentes estaciones del ano. En marzo de 1993, se recolectaron muestras en tres diferentes tipos de cartuchos que absorben selectivamente a los componentes carbonilo, los hidrocarburos ligeros (C{sub 2}-C{sub 4}) y los hidrocarburos pesados (C{sub 5}-C{sub 1}5). Las tres tenicas de muestreo, canisteres, cartuchos y DOAS revelan concentraciones atmosfericas altas de compuestos organicos y volatiles, especies precursoras del ozono, estas altas concentraciones explican las excedencias a las normas observadas frecuentemente en la ZMCM. La cinetica del conjunto de reacciones indica entonces, que la formacion de ozono en esta atmosfera estara limitada por los oxidos de nitrogeno que en este caso son los precursores en menor concentracion relativa y por lo tanto, la especie limitante de las reacciones

  19. Efeitos do flavonóide quercetina e dos corantes bixina e norbixina sobre parâmetros sanguíneos de coelhos Effects of the flavonoid quercetin and the natural dyes bixin and norbixin on blood parameters of rabbits

    Directory of Open Access Journals (Sweden)

    Leonardo Ramos Paes Lima

    2003-09-01

    Full Text Available Avaliou-se a ação terapêutica da quercetina, bixina e norbixina, na dose diária de 0,01mol/kg, em coelhos hiperlipidêmicos induzidos por colesterol a 0,5% e ácido cólico a 0,1%, durante o período de vinte e oito dias, após o qual foram dosados colesterol, colesterol-HDL, triacilgliceróis, uréia, creatinina, ácido úrico, proteínas totais, cálcio, aspartato aminotransferase e alanina aminotransferase. Estes estudos são importante para se verificarem os efeitos de flavonóides e corantes sobre o metabolismo destas substâncias, permitindo a interpretação de desordens hepáticas ou renais. Os resultados mostraram que os teores de colesterol foram menores para os animais tratados com bixina (-4,03% e quercetina (-35,07%, enquanto sua associação reduziu o nível de uréia em 5,73%. Nenhuma das substâncias testadas apresentou efeitos deletérios, todavia, não é possível demonstrar a inocuidade destes compostos.The objective of this study was to evaluate the therapeutic action of quercetin, bixin and norbixin, in the daily dose of 0,01mol/kg, in hyperlipidemic rabbits induced by cholesterol at 0.5% and colic acid at 0.1%, during the period of twenty-eight days, after which they were anesthetized and samples of blood were collected, in order to determine cholesterol, HDL-cholesterol, triacylglycerols, urea, creatinine, uric acid, total proteins, calcium, aspartate aminotransferase and alanine aminotransferase. These researchs are important to verify the effects of flavonoids and natural dyes on the metabolism of these constituents, in order to study hepatic or renal disorders. The results showed that cholesterol was reduced by bixin (-44.03% and by quercetin (-35.07%, while the association reduced urea in 5.73%. None of the constituents analyzed in this study presented deleterious effects and it was not possible to demonstrate the innocuity of these compounds.

  20. Influence of calcium hydroxide on dyes for dentin labeling, anlyzed by means of a new methodology Influência do hidróxido de cálcio sobre corantes na marcação dentinária, analisada por meio de uma nova metodologia

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    Ivaldo Gomes de Moraes

    2005-09-01

    Full Text Available The objective of this study was to evaluate the influence of calcium hydroxide in intracanal dressing on the ability of the dyes rhodamine B and methylene blue to label the dentine. Forty extracted human mandibular premolars had their canals instrumented and were divided into four groups: in two groups, the canals were filled with a calcium hydroxide paste and the others remained in distilled water. After 15 days, in two groups (with and without dressing, the canals were obturated with sealer containing methylene blue, whereas the others contained rhodamine B. For analysis, the roots were transversally sectioned in their cervical, medium and apical thirds, and the labeling was analyzed. The Mann-Whitney test showed statistically significant difference between the dressing/methylene blue group and the others. Based on these results, it was concluded that calcium hydroxide in intracanal dressing negatively interferes with the labeling ability of methylene blue.Objetivou-se avaliar a influência do curativo intracanal de hidróxido de cálcio sobre a capacidade dos corantes azul de metileno e rhodamine B de marcar a dentina, quando incorporados à massa obturadora, no momento da espatulação. Quarenta pré-molares inferiores humanos extraídos tiveram seus canais instrumentados sendo, então, divididos em quatro grupos. Em dois grupos, os canais foram preenchidos com pasta de hidróxido de cálcio e propilenoglicol por 15 dias. Os outros, permaneceram em água destilada. Após a remoção do curativo, todos os canais foram obturados com condensação lateral e cimento de óxido de zinco e eugenol acrescidos de azul de metileno ou rhodamine B. Assim, em dois grupos (com e sem curativo, os canais foram obturados com cimento contendo azul de metileno e os outros, rhodamine B. Decorridos 15 dias, as raízes foram seccionadas transversalmente nos terços cervical, médio e apical, procedendo-se à análise da marcação, com atribuição de escores

  1. BASES PARA LA PRODUCCION DE SALMON ORGANICO EN CHILE

    OpenAIRE

    MEDINA AGUILERA, ALBERTO FERNANDO

    2013-01-01

    La tendencia actual en los mercados internacionales es cada vez más dirigida a productos naturales o los denominados orgánicos, la producción y demanda de los alimentos orgánicos ha ido en un explosivo aumento en los mercados de la Unión Europea y Estados Unidos de Norteamérica en la última década. Esta tendencia del mercado incluye a los alimentos de origen marino como es el caso del salmón. Fondo del Fomento al Desarrollo Científico y Tecnológico-FONDEF/Comisión Nacional de Investigación...

  2. Stabilization of organic sludges; Estabilizacion de fangos organicos

    Energy Technology Data Exchange (ETDEWEB)

    Dapena, J.L.

    1996-09-01

    The sludge or the waste coming from a depuration process (biological or no) are stabilized when its energy and carbon are low enough to be used in a new biological activity. the sludge stabilization must be guided to get the biggest possible reduction of its volatile matter. (Author)

  3. Ligninolytic enzymes production and Remazol brilliant blue R decolorization by tropical brazilian basidiomycetes fungi Produção de enzimas ligninolíticas e descoloração do corante azul brilhante de Remazol R por fungos basidiomicetos tropicais brasileiros

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    Kátia M. G. Machado

    2005-09-01

    Full Text Available Remazol Brilliant Blue R (RBBR dye was used as substrate to evaluate ligninolytic activity in 125 basidiomycetous fungi isolated from tropical ecosystems. The extracellular RBBR decolorizing activity produced when selected fungi were grown in solid media and in soil contaminated with organochlorines was also evaluated. A total of 106 fungi decolorized the RBBR during the growth in malt extract agar (MEA, 2%; 96 fungi showed a mycelia growth and decolorization activity stronger than the P. chrysosporium used as reference. Extracellular extracts of 35 selected fungi grown on solid medium with sugar cane bagasse (BGS were evaluated for RBBR decolorization and peroxidase activity. All fungi showed peroxidase activities, but 5 of those were unable to decolorize the RBBR. Different patterns of ligninolytic enzymes were detected in 12 fungi extracts. Mn-dependent peroxidase (MnP was produced by Peniophora cinerea, Psilocybe castanella, three strains of Trametes villosa, T. versicolor, Melanoporia nigra and Trichaptum byssogenum. All 12 fungi had laccase activity. Trogia buccinalis showed the highest RBBR decolorization and did not produce MnP activity. RBBR decolorization without MnP production was also observed for three strains of Lentinum tested. Higher levels of peroxidase and laccase cannot be related to high RBBR decolorization. RBBR decolorization by extracellular extract was also detected during the growth of P. castanella, L. crinitus, P. cinerea and two strains of T. Villosa in pentachlorophenol- and hexachlorobenzene-contaminated soils. These fungi showed higher RBBR decolorization when grown in the presence of organochlorine compounds than when in non contaminated soil.O corante azul brilhante Remazol R (RBBR foi usado como substrato para avaliar 125 fungos basidiomicetos isolados de ecossistemas tropicais brasileiros quanto a atividade ligninolítica. A descoloração do RBBR por extratos obtidos do crescimento de fungos em meio sólido e

  4. Resíduo da semente de urucum (Bixa orellana L. como corante da gema, pele bico e ovário de poedeiras avaliado por dois métodos analíticos Evaluating of annatto (Bixa orellana L. seeds by-product as yolk, skin, beak and ovary coloring of hens using two analytical methods

    Directory of Open Access Journals (Sweden)

    José Humberto Vilar da Silva

    2006-10-01

    Full Text Available O experimento foi realizado com o objetivo de avaliar o resíduo da semente de urucum (RSU como ingrediente e aditivo corante de diferentes tecidos de 125 poedeiras Lohmann-LSL, com 22 semanas de idade e 1,65 kg de peso vivo, distribuídas num delineamento inteiramente ao acaso em cinco tratamentos com cinco repetições de cinco aves. O tratamento 1 (T1 = ração à base de milho+farelo de soja (M+FS; T2 = ração à base de sorgo (40% + FS; T3 = T2 + 4% RSU; T4 = T2 + 8% RSU e T5 = T2 + 12% RSU. Foram fornecidos 110 g de ração/ave/dia e água à vontade. As coletas foram realizadas em três períodos de 28 dias. A pigmentação dos diferentes tecidos foi avaliada pelo método 1 (M1 do leque colorimétrico da Roche® e, pelo método 2 (M2 do escore "b+", que mede a cor amarela, pelo cromatográfo Minolta® CR-10. Excetuando-se os T1 e T2 da análise de variância, o aumento do RSU na ração com 40% de sorgo melhorou, linearmente, o consumo, produção, massa, conversão alimentar por massa e por dúzia de ovos. A pigmentação da gema analisada pelos M1 e M2, do bico pelo M2 e do ovário pelo M1 melhoraram com o aumento do RSU. Alta correlação (r = 0,72; P A experiment was carried out in the poultry science station of CFT/UFPB with the objective to evalluate the annatto seeds bran (ASB as an ingredient and as an additive colouring of several tissue in 125 hens Lohmann LSL with twenty-two weeks of age, 1.65 kg of live weight, allocated in the completely randomized design, with five treatments and five replication of five hens. The treatment 1 (T1 = diet based on corn and soybean meal; T2 = diet + 40% of sorghum; T3 = T2 + 4% ASB; T4 = T2 + 8% ASB; e T5 = T2 + 12% ASB. The birds were fed 110 g of diet/day and water ad libitum. The collect were obtained in three periods of twenty-eight days. Collor changes were measured with yolk the Roche® collor fan method (M1 and score calculated from "b+" (yellowness of Minolta® CR-10 instrument (M2

  5. Avaliação do tratamento físico-químico e biológico dos resíduos de corantes produzidos em laboratório de microbiologia = Evaluation of the physical-chemical and biological treatment of residue from dyes produced at a microbiology laboratory

    Directory of Open Access Journals (Sweden)

    Lenice Leiko Nozu

    2010-01-01

    Full Text Available Os diferentes resíduos produzidos pelo homem em diversas áreas representam grave problema ambiental, quando inadequadamente descartados. No presente trabalho, foram realizados experimentos de degradação de resíduos de corantes gerados no Laboratório de Microbiologia da Universidade Tecnológica Federal do Paraná, CampusCuritiba, por meio do cultivo líquido implementado com Pleurotus sajor-caju e processo oxidativo avançado (POA – Sistema UV/H2O2. A verificação da eficiência desses processos foi realizada por meio do acompanhamento da redução de cor e dos compostos aromáticos por análise espectrofotométrica em UV-vis, da redução de matéria orgânica (análise de DQO e de bioensaios de toxicidade com Escherichia coli e com sementes de Lactuca sativa. A partir dos resultados obtidos, constatou-se que o processo combinado – cultivo líquido seguido de peroxidação com irradiação ultravioleta, demonstrou ser o tratamento mais eficiente para a redução de cor (90-95% e degradação de aromáticos (16-20%. Os bioensaios revelaram que as amostras do resíduo bruto não inibiram o crescimento da E. coli e mostraram potencial tóxico para a espécie L. sativa, apresentando de 30 a 57% de inibição da germinação das sementes testadas.Palavras-chave: Pleurotus sajor-caju, processo oxidativo avançado, bioensaios de toxicidade.The different types of waste produced by man in several areas represent a serious environmental problem when incorrectly discharged. This work carried out degradation experiments of dye wastegenerated at the laboratory of microbiology of the Federal University of Technology – Paraná State, Campus Curitiba. Assays were performed through liquid culture implemented with Pleurotus sajor-caju and advanced oxidative process (AOP - System UV/H2O2. Efficiency verification of these processes was carried out through monitoringcolor removal and aromatic compounds by spectrophotometric analysis (UV-vis, and also

  6. Desenvolvimento de massa alimentícia fresca funcional com a adição de isolado protéico de soja e polidextrose utilizando páprica como corante Development of functional fresh food adding soy protein isolate and polidextrose using paprika as coloring agent

    Directory of Open Access Journals (Sweden)

    Luz Maria Paucar-Menacho

    2008-12-01

    Full Text Available A tendência do consumidor atual é utilizar alimentos de fácil preparo que, adicionalmente à qualidade nutritiva, tragam benefícios à saúde. Neste trabalho, uma massa alimentícia fresca funcional foi desenvolvida pela incorporação de Isolado Protéico de Soja (IPS e polidextrose, utilizando páprica como corante. O consumo de IPS pode contribuir para a diminuição dos níveis de colesterol, enquanto a polidextrose, funcionando como fibra, pode promover a redução de risco de câncer de cólon. A otimização da formulação foi realizada utilizando-se um delineamento fatorial completo 23, considerando como variáveis independentes os teores de: i IPS; ii polidextrose; e iii páprica. Os efeitos destas variáveis na qualidade da massa alimentícia foram avaliados em função das características físico-químicas (cor e teste de cozimento, textura instrumental e propriedades sensoriais. Na avaliação dos parâmetros físicos, observou-se que a cor instrumental da massa crua foi influenciada apenas pelo teor de páprica; já o tempo de cozimento (2,5 minutos, o aumento de massa (1,40 a 1,64% e a perda de sólidos (3,80 a 5,56% não foram influenciados pelos ingredientes utilizados; e a elasticidade (parâmetro da textura instrumental foi reduzida com o aumento do teor de polidextrose. Na avaliação sensorial da massa crua, o aumento na porcentagem de IPS e a redução na porcentagem de polidextrose afetaram positivamente a aceitação global e a intenção de compra; e os aumentos nas porcentagens de IPS e de páprica aumentaram a aceitação da cor. Na avaliação sensorial da massa cozida, observou-se que o IPS teve influência positiva sobre a textura, enquanto que a polidextrose e a páprica afetaram negativamente este parâmetro. Entretanto, na avaliação da intenção de compra da massa cozida, não houve influência dos ingredientes adicionados. Os percentuais ideais de adição de polidextrose, isolado protéico de soja e p

  7. Impacto orcamentario da utilizacao do Metodo Canguru no cuidado neonatal

    Directory of Open Access Journals (Sweden)

    Aline Piovezan Entringer

    2013-10-01

    Full Text Available OBJETIVO Estimar o impacto orçamentário da utilização do Método Canguru na rede municipal de saúde. MÉTODOS Um modelo de decisão analítico foi desenvolvido para simular os custos do Método Canguru e Unidade Intermediária Neonatal no Rio de Janeiro, RJ, em 2011. A população de referência foi constituída pelos recém-nascidos estáveis clinicamente, que podem receber assistência nas duas modalidades de cuidado. O impacto orçamentário foi estimado para uma coorte hipotética de 1.000 recém-nascidos elegíveis em um ano. A proporção de recém-nascidos elegíveis que recebem assistência nas duas modalidades foi obtida por coleta de dados nas maternidades incluídas no estudo. As probabilidades dos eventos e o consumo de recursos de saúde, no período da assistência, foram incorporados ao modelo. Cenários foram desenvolvidos para refletir a adoção do método Canguru em maior ou menor escala. RESULTADOS A utilização do Método Canguru significou redução de gastos equivalente a 16% em um ano, se todos os recém-nascidos elegíveis fossem assistidos por esse método. CONCLUSÕES A opção Método Canguru é de menor custo comparado com a da Unidade Intermediária Neonatal. A análise de impacto orçamentário da utilização desse método no Sistema Único de Saúde indicou economia importante para o período de um ano.

  8. Degradation of air polluted by organic compounds; Degradacion de aire contaminado por compuestos organicos

    Energy Technology Data Exchange (ETDEWEB)

    Santoyo O, E.L.; Lizama S, B.E. [Universidad Autonoma del Estado de Mexico, Facultad de Quimica, 56000 Toluca (Mexico); Vazquez A, O.; Luna C, P.C.; Arredondo H, S. [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    1999-07-01

    According to the Mexican standard NOM-010-STPS-1994 it has been established concentrations of maximum permissible levels in workable air for styrene in the range 420-1710 mg/m{sup 3} and for xylene between 218-870 mg/m{sup 3}. In this work it is studied a biological treatment (bio filtration) for air polluted by xylene and styrene where the microorganisms are adhered at synthetic fiber, these degrade to the organic compounds that across in gaseous state and they are mineralized toward CO{sub 2} and H{sub 2}O. The characteristics of temperature, p H, concentration of organic compound and mineral parameters, as well as, the biomass quantity have been optimized for that bio filters efficiency were greater than those reported in other works. (Author)

  9. La tentazione della ricorsività. Il fascino dell'organico tra ordine e caos

    Directory of Open Access Journals (Sweden)

    Fabiana Gambardella

    2014-12-01

    Full Text Available There has been a close relationship between machines and biology since ages. Men have always produced automata in order to imitate nature, as well as to better know the secrets of life through the observation of machines. From Descartes’s automata to the new kind of machines, such as computers, the research in biology has been growing and has revealed that the border between natural and artificial, organic and inorganic is more and more fragile.  

  10. Kinetics of adsorption of organic pollutants by bioadsorbents; Cinetica de adsorcao de poluentes organicos por bioadsorventes

    Energy Technology Data Exchange (ETDEWEB)

    Santos, E.G. [Universidade Federal de Campina Grande, PB (Brazil). Programa de Recursos Humanos da ANP, PRH-25]. E-mail: elbagomes@uol.com.br; Alsina, O.L.S.; Silva, F.L.H. [Universidade Federal de Campina Grande, PB (Brazil). Centro de Ciencias e Tecnologia. Dept. de Engenharia Quimica]. E-mail: odelsia@deq.ufpb.br; flhs@deq.ufpb.br

    2003-07-01

    During the petroleum exploration and production processes, a great amount of water is produced together with the oil and the natural gas. This water needs an appropriate treatment before been discarded or reuse, due to a their great amount of organic pollutants content. Several separation processes are used in order to improve the effluent quality. In this way, the research of new adsorbent materials that present a low industrial cost has great importance. In this paper, adsorption experiments of organic pollutants using as adsorbent, the corn-cob, the powder wood and the coconut mesocarp, were accomplished. The organic effluent used in this work was simulated by a dispersion of gas in water and the experimental data were obtained through experiments in an agitated reactor. The kinetic curve was been adjusted for Michaelis-Menten equation and equilibrium isotherm modeling with Langmuir isotherm. Both model fitted well the experimental data. The obtained results show the viability of the use of the biomass as adsorbents for organic pollutants, once, with appropriate amounts of the gas/biomass, it was possible to eliminate, practically, the whole pollutant. (author)

  11. Characterization of radioactive organic liquid wastes; Caracterizacion de desechos liquidos organicos radiactivos

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez A, I.; Monroy G, F.; Quintero P, E.; Lopez A, E.; Duarte A, C., E-mail: ivonne-arce@hotmail.com [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2014-10-15

    With the purpose of defining the treatment and more appropriate conditioning of radioactive organic liquid wastes, generated in medical establishments and research centers of the country (Mexico) and stored in drums of 208 L is necessary to characterize them. This work presents the physical-chemistry and radiological characterization of these wastes. The samples of 36 drums are presented, whose registrations report the presence of H-3, C-14 and S-35. The following physiochemical parameters of each sample were evaluated: ph, conductivity, density and viscosity; and analyzed by means of gamma spectrometry and liquid scintillation, in order to determine those contained radionuclides in the same wastes and their activities. Our results show the presence of H-3 (61%), C-14 (13%) and Na-22 (11%) and in some drums low concentrations of Co-60 (5.5%). In the case of the registered drums with S-35 (8.3%) does not exist presence of radioactive material, so they can be liberated without restriction as conventional chemical wastes. The present activities in these wastes vary among 5.6 and 2312.6 B g/g, their ph between 2 and 13, the conductivities between 0.005 and 15 m S, the densities among 1.05 and 1.14, and the viscosities between 1.1 and 39 MPa. (Author)

  12. Organic wastes treatment technologies; Tecnologias para el tratamiento de los residuos organicos y su adecuacion tecnica

    Energy Technology Data Exchange (ETDEWEB)

    Mata-Alvarez, J. [Universidad de Barcelona (Spain)

    2001-07-01

    In this paper the management of several types of organic wastes (organic fraction of municipal solid waste; agroindustrial residues: sewage sludges from domestic wastewater treatment plants; livestock farming wastes) with different technologies will be considered on the basis of its yields and possibilities of application. Combinations of technologies and co-treatment of wastes which offers a number of advantages will be also examined. After the examination of each technology and their possibilities, it is concluded that anaerobic digestion offers the more ecological approach and it is recommended its use, either alone or in combination with other concomitant technologies. (Author) 12 refs.

  13. Biological treatment of organic wastes in Switzerland; Tratamiento biologico de residuos organicos en Suiza

    Energy Technology Data Exchange (ETDEWEB)

    Fischer, C.; Lott-Fischer, J; Gandolla, M.

    1996-12-01

    Disposing of the waste produced by our society is an ever-growing problem. In a small and mountainous country like Switzerland, it has become more and more difficult to find new sites for landfills or other waste treatment plants, not only due to increasing opposition from the public, but also because appropriate sites are simply becoming rarer and rarer. The obligation, not only to treat the waste produced in an environmentally sustainable way, but also to reduce the amounts generated, has in fact been recognised for over a decade now and a general strategy for waste management has been defined. The treatment of the organic part of our wastes obviously plays an important role in this policy. The purpose of this study is to present an overall view the situation of compostable waste in Switzerland. This category of waste may be defined as solid organic waste that has been source-separated and collected separately. (Author)

  14. Biodigestor for organic waste gas; Biodigestor para o gas do lixo organico

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Carla Miranda; Fernandes, Carla Barbosa; Souza, Aline Vieira da Silva e; Melo, Cibelly Caroliny Santos; Sales, Jefferson Santos; Frade, Marcelo Lorenzo; Machado, Marcus Vinicius; Frade, Matheus Costa; Gomes, Natashua Lauar; Costa, Pedro Henrique de Andrade; Moraes, Rodrigo de Almeida; Estrella, Thales Goncalves; Lima, Miriam Cristina Pontello Barbosa [Centro Universitario de Belo Horizonte (UniBH), MG (Brazil)], e-mails: carlam.ferreira@yahoo.com.br, miriam.pontello@gmail.com

    2011-07-01

    This article to present an alternative reuse os the gas produced by garbage, through the construction of a digester, with a view to preserving the environment through renewable energy. The energy produced by this system is obtained from the decomposition of organic waste is biogas, made up of gases such as methane (CH{sub 4}) and carbon dioxide (CO{sub 2}). This experiment verifies the possibility of using methane gas as an alternative to the operation of a domestic stove. (author)

  15. Estudo da fauna de artropodes associada a plantas invasoras em agroecossistemas organicos e convencionais

    OpenAIRE

    Jose Carlos Brombal

    2001-01-01

    Resumo: o modelo de agricultura conhecido como manejo convencional, baseado em monoculturas e uso intensivo de insumos químicos sintéticos, traz uma série de danos à saúde humana, aos recursos naturais e à biodiversidade. Nas últimas décadas, uma série de manejos agrícolas alternativos vêm sendo desenvolvidos como uma resposta ao desafio da produção de alimentos com sustentabilidade ao longo do tempo e espaço. Estes manejos incorporam uma série de técnicas que mantêm e aumentam a biodiversida...

  16. Uso de cuatro extractos organicos para el control del pulgon verde (Myzus persicae Sulz (ING

    Directory of Open Access Journals (Sweden)

    Hernán Rodríguez Navas

    2016-03-01

    Full Text Available Extracts of leaves and stems of Neurolaena lobata; leaves, stems and fruits of Momordica charantia, wood of Quassia amara and seeds of Annona muricata, were tested regarding their effectiveness for control of green peach aphid (Myzus persicae. In a first stage, groups of 10 individuals of M. persicae were placed inside petri dishes together with a small and slight piece of synthetic cloth soaked with either substance extracted. Several concentrations were used. After two hours; more than 50% of the individuals had been killed in every petri dish, which allowed all extracts to pass on to the second stage. The second stage consisted of two experiments. The first one was done in spring at a greenhouse day temperature of 10°C,  using only the first three substances, each of them diluted 1:100. The second one was conducted in Summer at about 25°C with the four substances. Distilled water acted as a control in both experiments. Tobacco plants (Nicotiana tabacum infested with M. persicae were sprayed with the solutions and survivors counted 24 and 72 hours later. In the first experiment Q amara  and M. charantia had 78% and 77% effectiveness respectively, which were statiscally (P< 0.05 higher than that of N. lobata  (63%. In the second experiment, because of the warmer weather, they improved their performance, specially N. lobata (98%. This and A. muricata were found statistically (P< 0.05 higher than the others.

  17. Copper corrosion originated by volatile organic acid vapours; Corrosion del cobre por acidos organicos volatiles

    Energy Technology Data Exchange (ETDEWEB)

    Cano, E.; Polo, J. L.; Kong, D. Y.; Mora, E. M.; Lopez-Caballero, J. A.; Bastidas, J. M.

    2004-07-01

    The corrosion of copper in the presence of volatile organic acids is frequent. Thus, for example, it is known that failures by corrosion of the copper tubes take place in the air conditioning equipment, caused by volatile organic acids emitted by oils used in their manufacturing. Another frequent case is the corrosion of copper objects caused by the acids emitted by the materials used in packing, wood and resins, amongst others. This communication presents the corrosion results of copper exposed to 100% relative humidity and different concentrations (10-300ppm) of formic (HCOOH), acetic (CH{sub 3}COOH), propionic (CH{sub 3}CH{sub 2}COOH) and butyric (CH{sub 3}(CH{sub 2}){sub 2}COOH) acid vapours, for short exposure times. the techniques used were gravimetric analysis, scanning electron microscopy (SEM) and X-ray diffraction (XRD). (Author) 9 refs.

  18. ESTUDIO TEORICO DE LA CATALISIS DE ORO EN SUSTRATOS CON SISTEMA ORGANICO PI

    OpenAIRE

    BURGOS CARRASCO, DARWIN ANDRES

    2014-01-01

    En esta tesis se presenta un estudio teórico de la catálisis de especies de oro para adiciones electrofílicas a sustratos con sistemas orgánico pi no aromáticos en alquenos y alquinos. Debido a que el oro presenta una actividad catalítica muy alta en comparación a otros metales de transición, principalmente en el ámbito de la catálisis homogénea, y más aún si se contempla que generalmente se utiliza al mismo precursor químico, el AuCI3, todo esto para reacciones de adición electrofíl...

  19. Neutron spectrometry with organic scintillation detector; Espectrometria de nuetrones con cristales de centelleo organicos

    Energy Technology Data Exchange (ETDEWEB)

    Butragueno Casdo, J. L.

    1972-07-01

    This work describes a fast neutron spectrometer using a stilbene crystal as head detector with pulse shape discrimination (P.S.D.) to reject gamma background. Tre experimental procedure involves the P.S.D., the measurements to calibrate the spectrometer and the corrections for several factors, mainly the non-linear response of the stilbene. Results of the measurements with the reaction D{sup 2}(d,n)He{sup 3}, and with an Am-Be neutron source are presented. It is also presented the measurement of the spectrum of the fast reactor CCRAl-1. (Author) 17 refs.

  20. Marcação de Diatraea saccharalis (Fabr. com Diferentes Corantes em Dieta Artificial

    Directory of Open Access Journals (Sweden)

    Jael Rando

    2016-04-01

    Abstract. To study the spatial distribution of drill sugarcane Diatraea saccharalis (Fabr. and its parasitoid Cotesia flavipes (Cameron in the field, the use of markers has shown promise. These markers should remain in the insect so far recapture and can not affect the biological cycle. This study evaluated the effect of dyes as markers on the drill feed diet sugarcane. The insects were from the laboratory creation of USIBAN (Bandeirantes-PR. Feeding diet was used used in the routine of increased laboratory: Saffron (10g brilliant blue dye (2 mL, gentian violet (2 mL, iodine (2 mL, “urucum” (10g and as a control diet without dye. They were prepared 40 tubes / diet and each received ten newly hatched caterpillars. The material was kept studying chamber at 25 °C and were evaluated: duration of larval and pupal periods, larval and pupal viability. The pupae were separated by sex and a couple of adults released in PVC cages lined with bond paper, totaling ten couples per treatment. It evaluated longevity number of adults and eggs. Iodine is toxic to the caterpillars. The other dyes showed prolonged larval period, but not statistically differ from the control. The pupal period was not affected by the addition of dyes. In “urucum” was not enough adults; this dye and bright blue had extended the longevity of adults. The total number of eggs lower than expected and the overall viability below 75% in all treatments. It is suggested to continue their studies to obtain other labeling techniques.

  1. A química e toxicidade dos corantes de cabelo

    Directory of Open Access Journals (Sweden)

    Ricardo A. G. de Oliveira

    2014-07-01

    Full Text Available The market for hair dye involves a growing range of products, which requires greater understanding of hair properties, mechanisms of action and color development. In this work, we present a critical analysis of the classification, physical and chemical characteristics, chemical analysis and toxicological/mutagenic potential of dyes used in the hair dyeing process. A compilation of some studies was carried out, focusing on the available knowledge about these dyes and their effects on the environment and human health.

  2. Estudo da atividade antibacteriana de plantas medicinais, aromáticas e corantes naturais

    Directory of Open Access Journals (Sweden)

    Maria Teresa Freitas Bara

    1998-01-01

    Full Text Available O emprego de recursos naturais como mecanismo auxiliar no tratamento de distintas patologias tem ressurgido, com ênfase, nos útimos tempos. Tendo em vista esta situação, este estudo teve por finalidade investigar a atividade antimicrobiana de algumas plantas medicinais e aromáticas bastantes comuns na cultura brasileira. Foi constatado que, de modo particular, o alecrim-pimenta (Lippia sidoides levou a uma considerável inibição do crescimento bacteriano. Tambêm plantas como alecrim (Rosmarinus officinalis, cravo (Sysygium aromaticum, noz-moscada (Myristica fragrans, pimenta-da-jamaica (Pimenta dioica e sálvia (Salvia officinalis demonstraram constituir fontes eficientes de compostos bioativos antibacterianos.Medicinal plants, natural colour and spices were examined in vitro for antibacterial effects on the growth of Escherichia coli (EPEC serotype O:125, Salmonella thyphimurium, Staphylococcus aureus, Listeria monocytogenes ATCC 7644 and Yersinia enterocolitica ATCC 9610. The most effective medicinal plant was Lippia sidoides at concentration of 3 percent (w/v, that added to Trypticase Soya Broth completely inhibited the growth of S. thyphimurium, S. aureus, L. monocytogenes and Y. enterocolitica. Among the spices, the cloves (Sysygium aromaticum extract had the strongest inhibitory activity on the growth of E. coli, S. thyphimurium e Y. enterocolitica demonstred through the agar difussion technique. Sage (Salvia officinalis and rosemary (Rosmarinus officinalis extracts inhibited the growth of L. monocytogenes and S. aureus. The nutmeg (Myristica fragrans extract also prevented the development of L. monocytogenes.

  3. A utilizacao dos membros superiores nos saltos verticais--estudo comparativo entre um salto sem contramovimento sem a utilizacao dos membros superiores e um salto sem contramovimento com a utilizacao dos membros superiores

    National Research Council Canada - National Science Library

    Mourao, Paulo; Goncalves, Francisco

    2008-01-01

    .... The aim of this study is the comparison between the performance of a non-arm swing vertical jump and an arm swing vertical jump. One subject male (height = 1,75 m; Weight = 75 kg; age = 26 years...

  4. Memoria inmediata y a largo plazo en el paradigma de recobro libre en pacientes con sindrome mental organico

    Directory of Open Access Journals (Sweden)

    Teresa Cardona

    1989-01-01

    Full Text Available This investigation was undertaken wíth the purpose of comparing the recovery and categorízatíon process of short and long tenn memories in a free reeovery paradigma among patients with Organie Mental Syndrome (OMS. Twenty patients with this eondition were selected at random at the Neurologieal Institute of Colombia. An equal number of normal subjets, with similar characterístícs were examined as a control group. Both groups were subdivided in two with ten individ·uals eaeh one. A series of 20 figures to be memorized were shown to the first subgroup. The list of the 20 items recorded was presented to the second subgroup. Subjects were requested then to retrieve the information given. A second presentation ehanging theorder of the iteml wal made and the recovery time was measured to estabilish the executíon of short term memory. Two hours later the subject was requested to recover again the items in order to examine long term memory. Resulta were evaluated using an analysis of varianee of three facton with a repeated factor. Patients with OMS showed an inferior execution when compared to controls, not only in the number of items retrieved but also in the categorized ones. Therefore the general hypothesis and derivatives were confirmed. The modality which produced a greater score was the pictoric one in both groups. It is suggested that in patients with OMS, the sensorial register is altered as a eonsequence of the neurologieal damage produeed by the etiological cause, originating difficulties at eoding and storing short and long term memories

  5. Desarrollo del mercado de cultivos organicos en el Ecuador con la producción del brocoli

    OpenAIRE

    Cassola Izaguirre, Aldo; Peralta Jurado, Gustavo; Pfister, Emilio

    2009-01-01

    En este trabajo nos hemos propuesto darle a conocer y llevar a cabo las ventajas que tiene consumir productos orgánicos creando una empresa dedicada a este tipo de producción con el cultivo del brócoli. Con la creación de esta empresa se diversifica la agricultura en nuestro país. El proyecto empieza dando a conocer las ventajas que tiene el consumir productos cultivados en forma orgánica y en especial el brócoli. Dar a conocer el alto valor nutritivo del brócoli como alimento. También ...

  6. Emissions control of volatile organic compounds in petroleum industry; Controle de emissoes de compostos organicos volateis na industria do petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Gutierres, Ricardo; Moreira, Andrea Cristina de Castro Araujo [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES). P e D de Energia e Desenvolvimento Sustentavel (PDEDS)

    2004-07-01

    Volatile organic compounds are among the most common pollutants emitted by refining processes. The sources of these emissions should be controlled for preserving the ambient air quality. This article outlines the main factors to be considered for defining an effective emissions control strategy and compares the major characteristics of the available control technologies. (author)

  7. Radiation damages in chemical components of organic scintillator detectors; Danos de radiacao em componentes quimicos de detectores cintiladores organicos

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes Neto, Jose Maria

    2003-07-01

    Samples containing PPO (1%, g/ml), diluted in toluene, they were irradiated in a {sup 60}Co irradiator (6.46 kGy/h) at different doses. The PPO concentration decay bi-exponentially with the dose, generating the degradation products: benzoic acid, benzamide and benzilic alcohol. The liquid scintillator system was not sensitive to the radiation damage until 20 kGy. Otherwise, the pulse height analysis showed that dose among 30 to 40 kGy generate significant loss of quality of the sensor (liquid scintillating) and the light yield was reduced in half with the dose of (34.04 {+-} 0.80) kGy. This value practically was confirmed by the photo peak position analysis that resulted D{sub 1/2} = (31.7 {+-} 1,4) kGy, The transmittance, at 360 nm, of the irradiated solution decreased exponentially. The compartmental model using five compartments (fast decay PPO, slow decay PPO, benzamide, benzoic acid and benzilic alcohol) it was satisfactory to explain the decay of the PPO in its degradation products in function of the dose. The explanation coefficient r{sup 2} = 0.985636 assures that the model was capable to explain 98.6% of the experimental variations. The Target Theory together with the Compartmental Analysis showed that PPO irradiated in toluene solution presents two sensitive molecular diameters both of them larger than the true PPO diameter. >From this analysis it showed that the radiolytic are generated, comparatively, at four toluene molecules diameter far from PPO molecules. For each one PPO-target it was calculated the G parameter (damage/100 eV). For the target expressed by the fast decay the G value was (418.4 {+-} 54.1) damages/100 eV, and for the slow decay target the G value was (54.5 {+-} 8.9) damages/100 eV. The energies involved in the chemical reactions were w (0.239 {+-} 0.031) eV/damage (fast decay) and w = (1 834 {+-} 0.301) eV/damage (slow decay). (author)

  8. Desarrollo del mercado de cultivos organicos en el Ecuador con la producción del brocoli

    OpenAIRE

    Cassola Izaguirre, Aldo; Peralta Jurado, Gustavo; Pfister, Emilio

    2009-01-01

    En este trabajo nos hemos propuesto darle a conocer y llevar a cabo las ventajas que tiene consumir productos orgánicos creando una empresa dedicada a este tipo de producción con el cultivo del brócoli. Con la creación de esta empresa se diversifica la agricultura en nuestro país. El proyecto empieza dando a conocer las ventajas que tiene el consumir productos cultivados en forma orgánica y en especial el brócoli. Dar a conocer el alto valor nutritivo del brócoli como alimento. También ...

  9. Hybrid repowering of transformers using aramids; Repotenciacao hibrida de transformadores com utilizacao de aramida

    Energy Technology Data Exchange (ETDEWEB)

    Neri Junior, Almir Laranjeira; Correia, Fidelis Botelho [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil)

    2010-01-15

    Santiago substation of the PETROBRAS, operated with two transformers fabricated in 1971. To preserve the reliability of power supply, it was relaborated a reformation and repowering project of the equipment using aramids, a special polymeric material. This paper describes the phases of the project, and presents the benefits obtained, and also the characteristics of the electric system of the production unit. (author)

  10. Renewable energy source use in Brazil; Utilizacao de energia renovavel no Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Newman, Joseph; Rosa, Fabio, e-mails: jnewman@winrock.org.br, e-mail: fabrosa@terra.com.br

    2003-08-15

    This article evaluates the programs (PROINFA and CCC) developed by the State to deploy a policy of using renewable energy sources in Brazil, highlighting the biodiesel, which should be inserted in its energy matrix.

  11. Smart timer for use in air purifiers; Temporizador inteligente para utilizacao em depuradores de ar

    Energy Technology Data Exchange (ETDEWEB)

    Marcelino, M.A.; Escudeiro, G.A. [Universidade Estadual Paulista (FEG/UNESP), Guaratingueta, SP (Brazil). Faculdade de Engenharia], Emails: abud@feg.unesp.br, gui_paulista@yahoo.com.br

    2009-07-01

    Currently, the air cleaner Suggar appliances has a key of three positions of different speeds, in addition to the off position. The motor has three windings, each one is responsible for a winding speed. The speed choice is made through the key. The objective of this work is the replacement of this motor with three windings by a single motor winding, with the velocity controlled electronically, and no longer using the key, lowering the costs of product. A signalling was implemented, through a diode LED, informing the user the end of the useful life of the debugger filter, in order to make possible the replacement at the right time, avoiding waste for the product user. The electronic system should be able to control the speed of engine and to count a total of 100 hours of operation of the debugger. When this is achieved, a signal is triggered on the front panel of product, indicating the need for replacing the filter. A key to reset the timer will used to reset the count after a filter change. To avoid the time counting due to the energy lack it is used an EEPROM memory to storage the counting. The control system counting is done by the PIC12F629 microcontroller.

  12. Use of maze in cyclotron hoppers; Utilizacao de labirinto em bunker de ciclotron

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes, Fernando A.; Alves, Juliano S.; Fochesatto, Cintia; Cerioli, Luciane; Borges, Joao Alfredo; Gonzalez, Delfin; Silva, Daniel C., E-mail: fernandofernandes@biofarmaco.com.br [Delfin Farmacos e Derivados (Biofarmaco Marcadores Moleculares), Lauro de Freitas, BA (Brazil)

    2013-07-01

    Introduction: the increasing number of cyclotrons in Brazil due to constitutional amendment 49 /06 that enabled the production of radiopharmaceuticals with a short half - life by private companies. The radionuclides used for PET - CT require production centers near or within the diagnostic centers. In order to minimize maintenance and operating risks, gaining efficiency, our facility was the first in Brazil to use the access to a cyclotron bunker via maze, rather than armored door stopper type. Materials: the design calculations were based on the Monte Carlo method (MCNP5 - Monte Carlo N-Particletransportcode version 5). At the ends of the labyrinth are installed a door of polyethylene, for thermalization of neutrons, and other of wood for limiting access. Both legs of the maze have wall thickness of 100cm. In inspection Brazilian CNEN realize measures of dose rate for neutrons and gamma 9 points: 7 around the bunker, 1 over the bunker and 1 in the exhaust with the cyclotron operating with maximum load, double beam of 50uA for 2 hours. After commissioning were carried out around the bunker, the following measures: cumulative dose in three months with dosimeters for neutron rate dose with a gas proportional detector type filled with {sup 3}He and polyethylene neutron moderator and dose rate with a Geiger - Mueller detector for gamma radiation. Readings with neutron detectors were classified as background radiation and dose rates were always below the limits established in standard EN 3.01, and the calculation of the predicted regardless of the intensity of irradiation inside the bunker. Conclusion: the use of labyrinths as a way to access the bunkers cyclotron has been shown to be effective as the radiation shielding and efficient by allowing quick and easy access, virtually eliminating the maintenance.

  13. The case of royalties in utilizations contracts; O caso dos royalties nos contratos de utilizacao

    Energy Technology Data Exchange (ETDEWEB)

    Manoel, Cacio Oliveira; Santos, Edmilson Moutinho dos [Universidade de Sao Paulo (USP), SP (Brazil). Escola Politecnica. Programa Interunidades de Pos-Graduacao em Energia

    2004-07-01

    This paper aims to discuss issues related to royalties payment in cases of oil and natural gas fields unitization. Those case were already registered in Brazil although the generic legislation regulating royalties payment does not contemplating them specifically. The contractual concepts of fields unitization are initially presented, highlighting the difficulties of implementing those contractual models and including the discussion regarding royalties payment. The doctrinal understanding of royalty is considered to demonstrate the possible difficulties that unitizations contracts impose for those royalties payment in the Brazilian legislation. In the end, the authors suggest exploring ideas for solving the issues raised by paper. (author)

  14. Present status of the wind power using; Panorama atual de utilizacao da energia eolica

    Energy Technology Data Exchange (ETDEWEB)

    Reguse, Wilson [CELESC - Centrais Eletricas de Santa Catarina S.A., FLorianopolis (Brazil)]. E-mail: wilsonr@celesc.com.br; Montenegro, Alexandre de Albuquerque [Universidade Federal de Santa Catarina, Florianopolis (Brazil). Lab. de Energia Solar (LABSOLAR)]. E-mail: alex@emc.ufsc.br

    2000-07-01

    This paper presents the status of the wind power utilization in Brazil. The paper consider the subjects as follows: general aspects of wind turbine, wind power systems, Environmental impacts, Worldwide wind power utilization, wind power in Germany and Brazil.

  15. Present status of the solar heating utilization; Panorama atual da utilizacao de aquecimento solar

    Energy Technology Data Exchange (ETDEWEB)

    Mesquita, Lucio Cesar Souza [Associacao Brasileira de Refrigeracao, Ar Condicionado, Ventilacao e Aquecimento (ABRAVA), Rio de Janeiro, RJ (Brazil). Dept. de Aquecimento Solar

    2000-07-01

    This paper presents the status of the solar heating utilization in Brazil. The paper consider the subjects as follows: general aspects of solar heating, systems re dimensioning, collectors, thermal reservoirs,systems installation, large scale systems, hydraulics and hot water utilization, and maintenance.

  16. Os beneficios da utilizacao de coagulantes naturais para a obtencao de agua potavel

    National Research Council Canada - National Science Library

    Carvalho Bongiovani, Milene; Konradt-Moraes, Leila Cristina; Bergamasco, Rosangela; Sakaniva Lourenco, Beatriz Sayuri; Granhen Tavares, Celia Regina

    2010-01-01

    ... em UV-254 nm, utilizando como agente coagulante o Tanfloc SS. Com esta finalidade, ensaios de coagulacao/floculacao/sedimentacao foram realizados em aparelho "jar test", com agua superficial de caracteristicas de alta cor/turbidez...

  17. Utilizacao de medicamentos pela populacao quilombola: inquerito no Sudoeste da Bahia

    Directory of Open Access Journals (Sweden)

    Danielle Souto de Medeiros

    2013-10-01

    Full Text Available OBJETIVO Analisar o uso de medicamentos pela população quilombola. MÉTODOS Estudo transversal de base populacional com 797 quilombolas adultos de Vitória da Conquista, BA, em 2011. Utilizou-se análise de variância para comparar as médias de medicamentos por indivíduo segundo variáveis demográficas, socioeconômicas e de comportamentos relacionados à saúde. Foram estimadas as prevalências, razões de prevalência e os respectivos intervalos de confiança de 95%. Análise múltipla foi conduzida por meio de regressão de Poisson com variância robusta. RESULTADOS Os medicamentos mais consumidos pela população foram aqueles que atuam nos sistemas cardiovascular e nervoso. A prevalência de uso de medicamentos foi de 41,9%, significativamente maior nas mulheres (50,3% do que nos homens (31,9%. Após análise ajustada, o uso de fármacos foi associado a sexo feminino, idade de 60 anos e mais, nível econômico mais alto, pior avaliação da saúde, maior número de morbidades autorreferidas e de consultas médicas. CONCLUSÕES Mulheres e idosos deverão ser os grupos de preferência para o desenvolvimento de estratégias específicas que garantam o uso racional dos medicamentos. É necessária a promoção de prescrição racional no cotidiano dos serviços de saúde.

  18. Use of clays for purification of biodiesel; Utilizacao de argilas para purificacao de biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Paula, Andreia Juliana Almeida de; Kruegel, Marlus; Miranda, Joao Paulo; Rossi, Luciano Fernando dos Santos; Costa Neto, Pedro Ramos da, E-mail: pedroneto@utfpr.edu.b [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil). Depts. de Quimica, Biologia e Mecanica

    2011-07-01

    This work describes the results of the purification of methyl biodiesel, obtained by oxidized soybean oil, using different methods. After the ester separation from the glycerin by decanting, the ester was purified each time with distillation, washing with water and adsorption with bauxite, bentonite and attapulgite. The removal of total contamination, unsaponifiable material, concentrations of free glycerin and soap were analyzed in the purified ester phase. The best result of purification was observed with the use of bentonite and bauxite, in the removal of soap and free glycerin respectively. (author)

  19. Effects of the ionizing radiation in natural food colours; Efeitos da radiacao ionizante em corantes naturais de uso alimenticio

    Energy Technology Data Exchange (ETDEWEB)

    Cosentino, Helio Morrone

    2005-07-01

    The world's fast growing population and its consequent increase in demand for food has driven mankind into improving technologies which ensure a safer supply of such commodities. Both food radiation processing and its constituents are highlighted as a feasible alternative technique capable of meeting food safety standards. Natural dyes are extensively employed in the food industry thanks to their colour enhancing properties on food products. This paper has aimed at studying the effects of ionizing radiation on three natural dyes: carminic acid and its derivatives (cochineal dyes), bixine and its salts (annatto dyes) and curcumin (turmeric dyes), used in the food and cosmetic industries within dilutions and doses those goods might eventually be processed in. It also envisages clarifying the compatibility of the irradiation technique with the keeping of such relevant sensorial attribute which is the product colour. Spectrophotometry and capillary electrophoresis were the analytic methods employed. All in all, a colour decrease proportional to the increase on the applied gamma radiation (1 to 32 kGy) has been observed. The annatto dyes have proven moderately stable whereas turmeric has shown to be highly sensitive to radiation. Those results shall be taken into account as far as the need to alter the formulae additive amount in the product is concerned whenever undergoing radiation processing. (author)

  20. Descoloração de corantes industriais e efluentes têxteis simulados por peroxidase de nabo (Brassica campestre

    Directory of Open Access Journals (Sweden)

    Maria Cristina Silva

    2012-01-01

    Full Text Available The removal of important textile dyes by turnip peroxidase (TNP was evaluated. The textile effluents besides the residual dyes contain also chemical auxiliaries such as salts, dispersing and wetting agents. The effect of these was evaluated in the removal of the dyes reactive blue 21 and reactive blue 19 by TNP in synthetic effluents. A decrease of the efficency decolorization was observed. The action of the enzyme on colour removal of dye mixture was equivalent to the dyes alone. The chemical demand of oxygen in the effluent after enzymatic treatment had a significant increase in relation to the untreated effluent.

  1. PROTOTIPAGEM DE MICRORREATORES FOTOCATALÍTICOS E TESTES DE FOTODEGRADAÇÃO DE CORANTES ORGÂNICOS

    Directory of Open Access Journals (Sweden)

    Omar Pandoli

    2015-07-01

    Full Text Available A photocatalytic microreactor is defined as a microfluidic device, which is integrated with a photocatalytic coating of TiO2 deposited on the inner surface of microchannels. This device is capable of degradation of organic dye solution in water in a continuous flow under the action of ultraviolet light. The objectives of this work were to present a rapid and economically viable approach for the prototyping photocatalytic microfluidic devices and to evaluate their photodegradation capability for organic dyes by ultraviolet-visible spectrophotometry. Prototyping of polydimethylsiloxane PDMS/TiO2/glass microreactors includes several procedures such as mold preparation, microchannel confection on PDMS surface, deposition of TiO2 on these microchannels, O2 plasma treatment of PDMS/TiO2 and glass surface for sealing these two parts. The efficiency of the photocatalytic microreactors was evaluated by fluxing two organic dye solutions, rhodamine B and methylene blue, with different flow rates of between 2 and 4 mL h-1. When the flow rate at 2 mL h-1was applied, discoloration of ~ 65% was achieved for both dye solutions, while PDMS/glass microchannels, without TiO2 film, demonstrated much lower discoloration of between 24 and 42% for rhodamine B and methylene blue, respectively. This confirmed that TiO2 was successfully deposited onto PDMS microchannels.

  2. Remoção do Corante Têxtil Turquesa de Remazol Empregando Aguapé (Eichhornia crassipes como Adsorvente

    Directory of Open Access Journals (Sweden)

    Carlos Alexandre Holanda

    2015-06-01

    Full Text Available In this work, the efficient removal of Remazol Turquoise textile dye onto water hyacinth (Eichhornia crassipes from aqueous solutions was investigated by batch method. The water hyacinth was collected, washed, dried, crushed and treated with a 0,25 mol L-1 HNO3, at 50 °C and by 24 h. Parameters such as pHpzc, pH effect, contact time and temperature were considered. The kinetic and adsorption data were analyzed by using the Lagergren, Ho, Zeldowitsch (Elovich, and Weber-Morris models, and Langmuir, Freundlich, Tempkin, Redlich-Peterson, Sips and multilayers isotherm models, respectively. The best fitting modeling were Ho (50 mg L-1, Elovich (1000 mg L-1 and Sips. The thermodynamic parameters (ΔHads, ΔSads and ΔGads and desorption tests showed that adsorption mechanism is dependent on several adsorbate/surface interactions. DOI: http://dx.doi.org/10.17807/orbital.v7i2.622

  3. Evaluation of the efficiency of fixation, decalcified and corants to study of pereiopods of Neohelice granulata (Dana, 1851)

    OpenAIRE

    Borges, Elizandra Luçardo; Gonzalez, Vinícius Cunha; Jardim, Rodrigo Desessards; Loch, Dionísio; Soares, João Cassimiro Mendonça; Trindade, Gilma Santos; Varela Junior, Antonio Sergio

    2009-01-01

    Foram coletados dezesseis espécimes de Neohelice granulata no estuário da Laguna dos Patos sendo que, de cada um destes foram coletados cinco apêndices locomotores. Dois destes apêndices foram fixados em Formol a 10%, outros dois em Zenker e um em Davidson, correspondendo a 32, 32, 16 repetições respectivamente. Após os apêndices terem sido fixados em Formol e Zenker estes foram colocados nos descalcificadores Ácido Cítrico 5% e Solução de Citrato de Sódio/Ácido Fórmico. Já os apêndices fixad...

  4. Fatores que afetam a disponibilidade do fosforo e o manejo da adubacao fosfatada em solos sob sistema plantio direto

    National Research Council Canada - National Science Library

    Rheinheimer dos Santos, Danilo; Colpo Gatiboni, Luciano; Kaminski, Joao

    2008-01-01

    .... Por outro lado, em solos altamente intemperizados, a biociclagem dos fosfatos organicos assume grande importancia na manutencao da biodisponibilidade, embora nao seja suficiente para a obtencao...

  5. Use of images for human identification in forensic dentistry; A utilizacao de imagens na identificacao humana em odontologia legal

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Suzana Papile Maciel; Lopes-Junior, Cesar [Universidade de Sao Paulo (USP), Bauru, SP (Brazil). Faculdade de Odontologia], e-mail: sumaciel@uol.com.br; Silva, Ricardo Henrique Alves da [Universidade de Sao Paulo (USP), Ribeirao Preto, SP (Brazil). Faculdade de Odontologia; Peres, Arsenio Sales [Universidade de Sao Paulo (USP), Bauru, SP (Brazil). Faculdade de Odontologia. Dept. de Saude Coletiva

    2009-03-15

    The present systematic review article is aimed at describing radiological methods utilized for human identification in forensic dentistry. For this purpose, a literature review was undertaken, and out of 45 papers, 19 were selected in accordance with inclusion criteria. Several radiological techniques can be used to assist in both individual and general identification, including determination of gender, ethnic group and, mainly, age. The analysis of ante-mortem and post-mortem radiographic and tomographic images has become an essential tool for human identification in forensic dentistry, particularly with the refinement of techniques resulting from developments in the field of the radiology itself as well as the incorporation of information technology resources to the technique. It can be concluded that, based on an appropriate knowledge on the available methods, forensic dentists can choose the best method to achieve a successful identification with a careful application of the technique and accurate interpretation of data. (author)

  6. Tendencias e diversidade na utilizacao empirica do Modelo Demanda-Controle de Karasek (estresse no trabalho: uma revisao sistematica

    Directory of Open Access Journals (Sweden)

    Marcia Guimaraes de Mello Alves

    2013-03-01

    Full Text Available INTRODUÇÃO: O modelo demanda-controle de Karasek tem sido utilizado para investigar associação entre estresse no trabalho e desfechos de saúde. Entretanto, diferentes instrumentos e definições têm sido adotados para aferir a exposição "alta exigência no trabalho", o que dificulta a comparação de resultados entre estudos. OBJETIVO: Descrever os instrumentos e as definições adotadas para a variável de exposição "estresse no trabalho", avaliada segundo o modelo demanda-controle, nos estudos observacionais publicados até 2010. MÉTODOS: Revisão sistemática de estudos observacionais publicados até dezembro de 2010, que avaliaram a exposição "estresse no trabalho", aferido segundo o modelo demanda-controle de Karasek e utilizaram o JCQ ou seus derivados, desde que explicitado nos textos. RESULTADOS: Entre 877 resumos selecionados, 496 (57% preencheram os critérios de inclusão. Identificou-se tendência à produção bibliográfica crescente no tema. A maioria dos estudos foi de natureza seccional; não encontramos diferenças relevantes entre as populações de estudo masculinas e femininas. Suécia, EUA, Japão e Canadá concentraram 57% das publicações, em sua maioria incluindo mais de 1.000 participantes e ocupações diversificadas. Desfechos cardiovasculares e seus fatores de risco foram os mais estudados (45%, seguidos por aqueles relacionados à saúde mental (25%. Em 71% dos estudos foi utilizado o Job Content Questionnaire (com 2 a 49 itens e, em 19% do total, a versão sueca (Demand Control Swedish Questionnaire. Quadrantes de exposição demanda-controle foram utilizados em 51% dos trabalhos, mas com variados pontos de corte; escores das duas dimensões foram analisados em separado em 27%, e sua razão em 14% do total. Apoio social no trabalho foi avaliado em 44% dos estudos. CONCLUSÃO: O modelo Karasek deverá continuar a suscitar pesquisas epidemiológicas e esperamos que os pesquisadores enfrentem essas questões teóricas e metodológicas ainda pendentes.

  7. Application of aluminum slag incorporated in lightweigh aggregate; Utilizacao da escoria de aluminio na fabricacao de argila expandida

    Energy Technology Data Exchange (ETDEWEB)

    Takahashi, Elisa Akiko Nakano

    2006-07-01

    The use of industrial waste materials as additives in the manufacture of ceramic product has been attracting a growing interest in the last few years and is becoming common practice. The main purpose of this work is to evaluate the possibility of incorporation of aluminum slag into clay materials. Expansive clays are obtained from a pyro plastic expansion, and are usually employed like lightweight aggregate in structural concrete as ornamental garden products. The characterization of the aluminum slag and clay materials was carried out by Xray fluorescence spectrometry, Xray diffraction, granulometry, differential thermal analysis, thermal gravimetry (DTA and TG) and scanning electron microscopy. The studied compositions contained 5, 10, 15 and 20 weight % of aluminum slag into clay mass. The linear expansion, mass variation, apparent specific mass and water absorption of all compositions were determined. Leaching and solubilization experiments were also performed. The main results show the viability of using up to 5 wt% aluminum slag for producing expansive clays with characteristics within the accepted standards. (author)

  8. Mineralogical characterization of Brazilians attapulgite to magnetic nano composites uses; Caracterizacao mineralogica de atapulgitas brasileiras para utilizacao em nanocompositos magneticos

    Energy Technology Data Exchange (ETDEWEB)

    Middea, Antonieta; Neumann, Reiner, E-mail: amiddea@cetem.gov.br [Centro de Tecnologia Mineral - CETEM, Rio de Janeiro, RJ (Brazil); Spinelli, Luciana S.; Lucas, Elizabete F. [Universidade Federal do Rio de Janeiro, Instituto de Macromoleculas, Laboratorio de Macromoleculas e Coloides na Industria de Petroleo, Rio de Janeiro, RJ (Brazil)

    2011-07-01

    Magnetic polymeric nano composites represent a potential alternative in the treatment of contaminated water. This work aims to investigate the potential of uses of a Brazilian clay (an attapulgite), abundant in the northeast, in the preparation of polymeric nano composites for application in the removal of organic material present in aquifers, using magnetic field. The techniques used for mineralogical characterization were X-ray diffraction (XRD) and scanning electron microscopy (SEM) coupled with energy dispersive spectroscopy (EDS). The results showed the presence of palyigorskite in all samples as well as other mineral phases (quartz, kaolinite, smectite and anatase). The microscopic analysis permitted to identify the fibrous appearance of palyigorskite. The presence of palyigorskite is a strong indication of the possible use of attapulgite in obtaining magnetic nano composites by the adsorption of iron ion to the surface. (author)

  9. Structural characterization of bentonite clays for utilization as nanofillers in nanocomposites; Caracterizacao estrutural de argilas bentoniticas para utilizacao como nanocargas

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Carlos Ivan Ribeiro de; Rocha, Marisa Cristina Guimares; Vogas, Arthur Considera, E-mail: carlosivanr@gmail.com [Universidade do Estado do Rio de Janeiro (UERJ), Nova Friburgo, RJ (Brazil). Instituto Politecnico; Silva, Ana Lucia Nazareth da [Universidade Federal do Rio de Janeiro (IMA/UFRJ), RJ (Brazil). Instituto de Macromoleculas Professora Eloisa Mano; Bertolino, Luiz Carlos [Centro de Tecnologia Mineral (CETEM/MCTI), Rio de Janeiro, RJ (Brazil)

    2014-07-01

    Clays of different composition have been used in the development of polymer nanocomposites. However, the utilization of bentonite clays has been emphasized in Brazil, mainly due to their availability.The best known and studied deposits of bentonite clays are located in the state of Paraiba. However, these deposits are becoming exhausted after decades of exploitation. In this context, the aim of this work is to proceed the physical-mineralogical characterization of bentonite clays recently discovered in Cubati, PB. In order to achieve this objective, the samples underwent a particle size classification step and were characterized by X-ray fluorescence, X-ray diffraction, infrared spectroscopy, thermal analysis and scanning electron microscopy. Results of X-ray diffraction showed that the samples are composed of smectite, and kaolinite and quartz. The characterization of the samples by FTIR confirmed these results. Results of chemical analysis showed that the clays have predominantly different exchangeable cations. (author)

  10. The using of aeolian energy in air circulators; A utilizacao da energia eolica em circuladores de ar

    Energy Technology Data Exchange (ETDEWEB)

    Assuncao Filho, Telesforo Reis de

    2003-07-01

    The present work is a theoretical research on how to take advantage of the wind kinetic energy using a rotor type Savonius, doing the conversion in mechanical energy, through the fan utilization aiming a thermal comfort and beginning with an introduction on the aeolian energy, its utilization and objectives. Several local types and behavior influenced by the air mass mechanics are shown. A statistic of these air masses and a brief study of the aeolian turbines, its characteristics and design, advantages and disadvantages are presented. An experimental analysis in Sao Luis region were done, using the wind frequency with the objective of obtaining a good revenue. The characterization of the main types of rotors used nowadays are presented, too. (author)

  11. PCI coals: quality parameters for an efficient usage; Carvoes para PCI: parametros de qualidade para uma utilizacao eficiente

    Energy Technology Data Exchange (ETDEWEB)

    Holcombe, D.; Coin, C.D.A. [Australian Coal Industry Research Labs., Riverview, QLD (Australia); Caldeira Filho, J.G [P.D.C.A. Consultoria Empresarial, Volta Redonda, RJ (Brazil)

    1996-12-31

    The technology of chemical reduction in blast furnaces has been presenting an increase in coke injection rates during the last five years. Even though the blast furnaces have been achieving excellent production rates, there is still a discussion in the community concerning which types of coke are more appropriate to the operation as well as the limits of coke injection through the blasts. This work discusses the role of PCI in metallurgy as well as its limitations giving special emphasis to the several quality parameters in the process 16 refs., 2 tabs.

  12. XPS utilization in the characterization of glycerol based polyesters; Utilizacao de XPS na caracterizacao de poliesteres a base de glicerol

    Energy Technology Data Exchange (ETDEWEB)

    Brioude, M.M.; Miranda, C.S.; Pereira, R.; Ohara, L.; Bargiela, P.; Rocha, M.G.M.C.; Jose, N.M., E-mail: mgcr@ufba.b [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Escola Politecnica. Inst. de Quimica

    2010-07-01

    X-ray photoelectron spectroscopy-XPS allows the determination of all elements of the periodical table, except hydrogen and helium, and is a very used technique for the polymers characterization, its spectra constitutes a 'fingerprint' of the material. Two samples of polymers were prepared from glycerol and fumaric acid and glycerol and terephthalic acid, with a molar ratio of 1:1 and 1:1.5. The general spectra show the presence of carbon and oxygen, the main components of the polymer. From the binding energies values of the C1s and O1s high resolution spectra it was possible to determine the carbon functional groups. Their concentration were determined and the presence of the aromatic carbon in the terephthalic polyesters was observed, and also similar proportions of aliphatic carbon and ester groups in the fumaric acid polyesters. For both polyesters, an amount of carboxyl group appears, indicating the terminal non-reacted groups. These results were confirmed qualitatively by FTIR. (author)

  13. Using of solar energy in replacing of electric shower; Utilizacao da energia solar em substituicao a chuveiros eletricos

    Energy Technology Data Exchange (ETDEWEB)

    Abreu, Samuel Luna de [Santa Catarina Univ., Florianopolis, SC (Brazil). Dept. de Engenharia Mecanica. Lab. de Energia Solar (LABSOLAR)]. E-mail: samuel@labsolar.ufsc.br

    2000-07-01

    This chapter studies the utilization of solar energy heating as replacing electric showers, and presents proposals for solar heating to be used by low income residences, obtained results from different alternatives of solar heating and the economic feasibility of the propose systems.

  14. Study on the natural gas utilization in the ceramic industry; Estudo sobre a utilizacao do gas natural na industria ceramica

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-07-01

    The production, principal applications, characteristics and properties, advantages of the gas natural is showed. A sectorial overview of the ceramic industry and the utilization of the natural gas in the ceramic industry is presented. The expectations are systematized and the impact of the natural gas utilization in the ceramic industry is evaluated. Some conclusions are withdrawn and recommendations suggested.

  15. Application of thermoelectric generator as an alternative energy source; Utilizacao dos geradores termoeletricos como fonte de energia alternativa

    Energy Technology Data Exchange (ETDEWEB)

    Pepino, Giovana [Newmar Energia, Rio de Janeiro, RJ (Brazil)

    2004-07-01

    This document will deal some information about the TEG and design of TEGs. Thermoelectric energy conversion is a solid state process that converts heat energy to electrical energy without moving parts. The result is a device that is characterized by a very high degree of reliability and low maintenance requirement. These characteristics lend the unit to service in remote areas where limited access is available fore service. Technicians that service the other equipment on location can be trained to service the thermoelectric generator. There are many other uses for TEGs including power supplies for supervisory control and data acquisition systems. (author)

  16. Natural gas use in treatment of steel surfaces; Utilizacao de gas natural em tratamento de superficies de aco

    Energy Technology Data Exchange (ETDEWEB)

    Ferraz, Andre Dias; Machado, Antonio Rogerio; Rocha, Ivan; Azevedo, Jorge; Oshiro, Hugo K.; Konishi, Ricardo; Lehmkuhl, Willian [Companhia de Gas de Santa Catarina (SCGAS), Florianopolis, SC (Brazil); Piazza, Walter [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2011-12-21

    The surface treatments of metals, such as carburizing, rely on processing under high temperature in carbon rich atmospheres. The atmosphere is industrially generated using the partial oxidation of a carbon rich fuel, such as propane, butane or methanol. This article reports a study of the production of a carburizing atmosphere for surface treatment of steel from the partial oxidation of natural gas in a catalytic reactor. The reactor studied was a production size reactor with 300 mm of diameter and 1500 mm of length, packed with alumina supported nickel catalyst. The quality of the carburizing gas was evaluated from its carbon potential of the carburizing gas that was calculated from the concentrations of carbon monoxide (CO), carbon dioxide (CO{sub 2}), oxygen (O{sub 2}) and methane (CH{sub 4}) measured at the reactor's exit. The results indicate that CO concentration is very close to equilibrium, while CO{sub 2} is higher and CH{sub 4} is lower. Examining the reactor, the conclusion was that there was an axial temperature gradient, resulting in lower residence time under the required processing temperature. This resulted in smaller decomposition of CH{sub 4} and smaller production of CO{sub 2}. An equilibrium calculation of carbon potential, expressed as weight percent of carbon in iron, was developed to predict the possible optimizations of mixture composition and reactor temperature for a given required carbon potential. Conclusion: it is possible to generate a carburizing atmosphere under well controlled and repeatable conditions for the carbon potentials required for surface carburizing of steels in industrial processing using natural gas and air mixtures. (author)

  17. Possibility of using biogas in the Brazilian energy system; Possibilidades de utilizacao do biogas no setor energetico brasileiro

    Energy Technology Data Exchange (ETDEWEB)

    Sacani Neto, Victor; Guirelli, Cleber Roberto; Pazzini, Luiz Henrique Alves [Universidade Presbiteriana Mackenzie, Sao Paulo, SP (Brazil). Escola de Engenharia]. E-mails: victor@neuronioconsultoria.com.br; cguirelli@yahoo.com.br; pazzini@mackenzie.com.br

    2004-07-01

    This work concepts the biogas and studies the possible forms for his attainment on sanity embankments, water and sewage treat stations and bio digesters for electric power generation. Some gas purification techniques are presented for his using as fuel for internal combustion engines, conventional gas turbines and micro turbines.

  18. Using microwave for processing nanostructured PZT ceramics; Utilizacao de microondas no processamento de ceramicas nanoestruturadas de PZT

    Energy Technology Data Exchange (ETDEWEB)

    Lanza, A.C.; Berti, T.G.; Thomazini, D.; Gelfuso, M.V., E-mail: lanza.work@gmail.com [Universidade Federal de Itajuba (UNIFEI), MG (Brazil). Instituto de Engenharia Mecanica; Eiras, J.A. [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil). Dept. de Fisica

    2012-07-01

    The PZT ceramics have dielectric and piezoelectric properties of technological interest. The method of microwave assisted hydrothermal synthesis becomes interesting since it occurs in a closed environment, the low temperature and time, compared to conventional methods. In this work, PZT powders were dissolved in acid medium, and by adjusting the pH of the solutions obtained were precipitated, subjected to hydrothermal treatment at 120 °C for intervals of 15, 30 and 60 min. The powders were characterized by differential thermal and gravimetric analysis, X-ray diffraction and scanning electron microscopy. The results confirm the formation of PZT phase in one hour with particle size around 55 nm, showing the feasibility of the proposed method. (author)

  19. The using of API steel in pipelines in Brazil; A utilizacao do aco API em dutos no Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Narcisi Junior, Aldo; Torii, Paulo; Nogueira, Shirleine [BRASTUBO, Sao Paulo, SP (Brazil); Machado Filho, Fausto de Assis; Silva, Carlos Norberto Paula da; Camey, Kenji [Companhia Siderurgica Paulista (COSIPA), Cubatao, SP (Brazil)

    1998-07-01

    This work presents an overview of application, production technology improvements, and increased demand for API lines in Brazil. The need of more economical installation of oil and gas pipelines has forced the utilization of higher strength line pipe grades. This scenario induced the development of a highly competitive steelmaking and pipe producing industry in Brazil. (author)

  20. Potential of energetic utilization of grains residual biomass; Potencial de utilizacao energetica de biomassa residual de graos

    Energy Technology Data Exchange (ETDEWEB)

    Mourad, Anna L. [Instituto de Tecnologia de Alimentos (ITAL), Campinas, SP (Brazil). Centro de Tecnologia de Embalagem], e-mail: anna@ital.sp.gov.br; Ambrogi, Vinicius S.; Guerra, Sinclair M.G. [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Fac. de Engenharia Mecanica], e-mail: ambrogi@fem.unicamp.br, e-mail: sguerra@fem.unicamp.br

    2004-07-01

    The biomass resulting from the rejected parts of grains, as straw and peel of rice, corn, wheat, soy, all great cultivations in the country, has potential to be takes advantage as energy. It was considered that the contribution of this residual biomass is near of 167,8 million GJ/year, value that could be added to the use already established of the cane bagasse for energy purpose (658 million GJ, in 2001). This energy can be used for drying of these same grains (energy expense estimate of 67 million GJ), currently obtained from oil. It can also substitute the fuel oil used in the agricultural section, in the industries of food and beverage, ceramic and textile (sections that consumed 67.822 GJ in 2001). In Sao Paulo state the regions with greater potential to install biomass plants are located in Assis, Avare and Itapeva EDR (regional development office). (author)

  1. Polyaniline/clay conducting nanocomposite for use in protecting coatings; Nanocompositos condutores polianilina/argila para utilizacao em revestimentos protetores

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    Nanomaterials have been shown highly promising materials for various technological applications. In engineering, may be noted the polymer nanocomposites, which are a new class of composite materials, where a nanoclay, or charge with nanometric dimensions, is dispersed in a polymer matrix at low concentration or volume. The clays are more common and when added in quantities less than 5% in the nanocomposites, cause a significant increase in these properties, such as mechanical, optical, magnetic barrier, and especially permeability and flammability. In this context, this work aimed at obtaining the polymeric nanocomposites of polyaniline (PAni) with different commercial clays (Cloisite Na{sup +}, 10A, 15A, 20A and 30B). The preparation of PAni-MMT nanocomposites was performed by in situ polymerization of aniline in acidic (HCl). Electrical conductivity measurements, FT-IR, TGA and X- ray diffraction were some of the techniques used to characterize the nanocomposites. (author)

  2. Teflon pastille use in high dose dosimetry; Utilizacao de pastilhas de teflon em dosimetria de doses altas

    Energy Technology Data Exchange (ETDEWEB)

    Teixeira, Maria Ines [Associacao Educacional Nove de Julho (UNINOVE), Sao Paulo, SP (Brazil); Caldas, Linda V.E., E-mail: miteixeira@ipen.b, E-mail: lcaldas@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2011-10-26

    This paper study the Teflon, which is used as aglomerant in the confection of dosimetric pastilles, for the viabilization of this material as high dose dosimeter. This paper used the OSL technique for the characterization of dosimetric properties of Teflon. The doses-response curve has been obtained for {sup 60}Co radiation between 100 Gy and 50 kGy, and the OSL answer reproducibility. The preliminary results shown that the Teflon is a material which can be used for high dose dosimetry

  3. Use of biogas for cooling and drying of vegetables; Utilizacao de biogas para resfriamento e secagem de hortalicas

    Energy Technology Data Exchange (ETDEWEB)

    Pacco, Honorato Ccalli; Cortez, Luis Augusto Barbosa [Universidade Estadual de Campinas (FEA/UNICAMP), SP (Brazil). Fac. de Engenharia de Alimentos. Lab. de Refrigeracao; Neves Filho, Lincoln de Camargo; Jordan, Rodrigo Aparecido [Universidade Estadual de Campinas (FEAGRI/UNICAMP), SP (Brazil). Fac. de Engenharia Agricola. Lab. de Termodinamica e Energia; Baldassin Junior, Ricardo [Universidade Estadual de Campinas (FEM/UNICAMP), SP (Brazil). Fac. de Engenharia Mecanica

    2006-07-01

    The European Union established a global goal of 8% reduction in the emission of greenhouse gases up to 2012. In 2010, 12.5% of the energy in the Europe should come from renewable sources, being that biogas will be able to come to represent about 10% of these sources. Up to 2020 it is foreseen substitution of 20% of the conventional sources for alternative fuels. Biogas is pointed as an environmentally competitive alternative, Neves Filho et al., (2001). With the biodigesters, the agricultural producer can transform animal and vegetal debris into an excellent energy alternative, besides getting a powerful organic fertilizer. The project consist of the installation of a biogas collection system that would serve as fuel to move an Otto cycle engine power and thus trigger the heat pump. This integrated use will allow to use the potentiality that has the heat pump to generate energy for cooling and heating, and to reduce use of electric power in rapid cooling of tomatoes after harvesting and in drying of mature tomatoes. (author)

  4. Energy inputs and outputs in organic and conventional corn production systems; Balanco de energia em sistemas organico e convencional de producao de milho

    Energy Technology Data Exchange (ETDEWEB)

    Campos, Alessandro Torres; Greco, Marcelo [Universidade Estadual do Oeste do Parana (UNIOESTE), Marechal Candido Rondon, PR (Brazil). Grupo de Pesquisas em Ambiencia do Oeste do Parana], e-mail: atcampos3@yahoo.com.br; Zonin, Wilson J.; Silva, Nardel L.S.; Gouvea, Alfredo [Universidade Estadual do Oeste do Parana (UNIOESTE), Marechal Candido Rondon, PR (Brazil). Centro de Ciencias Agrarias

    2004-07-01

    corn production systems. The experimental delineating was in casual blocks with arrangement in subdivided parcels, with the production systems as main parcels and the cultivate crops as sub parcels. The seeding was accomplished directly in oat and azevem straws. In the chemical system the vegetable covering was wiped with glyphosate (2 L/ha), while in the organic system it was used roll machinery to handle the straw. All the inputs, in products or operations form, and the outputs, in grain form, were transformed in energy to estimate the energy balance. The energy coefficients were obtained in research travails. The employed energy was divided in three categories, according to its origin, as biological, fossil and industrial. In the category of biological energy the items human work, seeds, bio fertilizer and humus were inserted. The oil products and by-products, such as chemical fertilizer, pesticides, diesel were grouped in fossil energy category. Industrial energy was considered one that was used in the manufacture of machinery used in the products process. Are included in this categories: tractor and tools. The energy consumption in the organic corn production system was of 2,047.42 MJ ha{sup -1} and the energy conversion was of 78,235.33 MJ ha{sup -1}, and the biological energy was the energy form more consumed, 65,77% of total consumed, while in the conventional system the consumption was of 3,764.66 MJ ha{sup -1} and the energy conversion of 82,653.29 MJ ha{sup -1}, and the fossil was energy form more consumed, representing 79.57% of the energy consumed in this production system. The organic production system presented an efficiency of 38.21 significantly larger than the chemical system with 21.95. (author)

  5. Thermodynamic simulation for a vapour compression system using organic refrigerants; Simulacao termodinamica do ciclo de compressao a vapor utilizando fluidos refrigerantes organicos

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, Francisco S.; Santos, Carlos A.C. dos [Universidade Federal da Paraiba (UFPB), Joao Pessoa, PB (Brazil). Lab. de Energia Solar; Torres, Ednildo A.; Jesus, Marcos F. de [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Dept. de Engenharia Quimica. Lab. de Energia e Gas

    2004-07-01

    According to the Montreal protocol, it is foreseen a total retreat of CFCs and HCFCs in applications of refrigeration and air conditioning. Before this context, considerable attention has been used in the substitution of HCFC-22 (R22) in systems of air conditioning, where they appear as possible alternatives two HFCs (R407c and R410a) and two HCs (R290 and R600a). In this work, possibilities and problems for the use of these fluids as alternatives to R22 in equipment of refrigeration are discussed. Five refrigerants (R22, R407c, R410a, R290 and R600) are selected, computational simulations done and your characteristic in terms of thermodynamic cycles are shown. The obtained conclusion is that propane offers the best alternative for R22 in equipment of refrigeration, because this besides being energetically efficient, is environmentally acceptable. However, safety precautions due to your inflammability must be seriously taken into account. For some applications the substitution of the current fluids (halocarbons) by the hydrocarbons can be done without larger additional costs, but not in the general case. (author)

  6. Development of Methodologies from Determination of Organic Components from Atmospheric Aerosol; Desarrollo de Metodologias para la Determinacion de Componentes Organicos del Aerosol Atmosferico

    Energy Technology Data Exchange (ETDEWEB)

    Pindado, O.; Perez, R.; Garcia, R.; Barrado, A. I.; Sevillano, M. L.; Gonzalez, D.

    2006-07-01

    It is presented method for the organic compound determination, such as n-alkanes, PAH's, alcohols and fatty acids that are comprised the particulate matter of aerosol. The procedure is based on sampling the particulate matter over quartz fibre filters that will be extracted by means of the Soxhiet technique, and later they will be divided by means of silicagel column. PAH's is analyzed by means of HPLCm whereas the rest is analyzed by GC-MS and for it, acids and alcohol must be previously derivatized with BSTFA.12 samples took shelter of fractions PMIO and PM2.5 of the aerosol of country side like application of the method. (Author) 60 refs.

  7. Vermicomposting of organic wastes from olive oil, winery and alcohol industries; Vermicompostaje de residuos organicos generados por industrias oleicolas, vitivinicolas y alcoholeras

    Energy Technology Data Exchange (ETDEWEB)

    Nogales, R.; Melgar, R.; Cifuentes, C.; Romero, E.; Benitez, E.

    2004-07-01

    The olive oil, winery and alcohol industries produce large amounts of organic waste that need suitable management in order to reduce their potential impact on the environment. This paper briefly describes the use of vermicomposting, at microcosm, laboratory and pilot scale, as an efficient and low-cost biotechnological process to obtain safe,mature and stabilised organic amendments, which can be feasibly used in conventional, integrated and organic agriculture. (Author) 26 refs.

  8. Analysis of the organic matter which are present in solid organic wastes from urban areas; Analise da materia organica presente em residues organicos solidos de origem urbana

    Energy Technology Data Exchange (ETDEWEB)

    Canellas, Luciano Pasqualoto; Santos, Gabriel de Araujo; Amarai Sobrinho, Nelson Moura Brasil do; Mazur, Nelson [Universidade Federal Rural do Rio de Janeiro, RJ (Brazil). Dept. de Solos. E-mail: canellas@ufrrj.br; Moraes, Anselmo Alpande [Universidade Federal Rural do Rio de Janeiro, RJ (Brazil). Dept. de Quimica

    1997-07-01

    This study analyses the organic matter which are present in the solid wastes from the Rio de Janeiro city - Brazil. The humic acids were extracted and purified. After the purification, the humic acids were dried by lyophilization. Visible UV, infrared and NMR spectra were obtained for the humic acids extracted.

  9. Eu(III) local coordination in white light emitters organic-inorganic hybrids; Coordenacao local do Eu(III) em hibridos organicos-inorganicos emissores de luz branca

    Energy Technology Data Exchange (ETDEWEB)

    Carlos, Luis D.; Ferreira, Rute A. Sa [Universidade de Aveiro (Portugal). Dept. de Fisica]. E-mail: lcarlos@ideiafix.fis.ua.pt; Bermudez, Veronica Zea de [Universidade de Tras-os-Montes e Alto Douro, Quinta de Prados (Portugal). Dept. de Quimica; Bueno, Luciano A.; Molina, Celso; Messaddeq, Younes; Ribeiro, Sidney J.L. [UNESP, Araraquara, SP (Brazil). Inst. de Quimica]. E-mail: sidney@iq.unesp.br

    2001-08-01

    Eu{sup 3+} luminescence and EXAFS (Extended X-Ray Absorption Fine Structure) results are presented for organic-inorganic hybrid gel hosts composed of a siliceous network to which small chains of oxy ethylene units are covalently grafted by means of urea bridges. Coordination numbers for Eu {sup 3+} ions range from 12.8 to 9.7 with increasing Eu {sup 3+} concentration while the Eu {sup 3=}-first neighbours mean distance is found to be constant at 2.48-2.49 angstrom in the same concentration range. Emission spectra display a broad band in the green/blue spectral region superposed to narrow lines appearing in the yellow/red region in such a way that for the eyes emission appears white. The broad band is assigned to intrinsic N H groups emission and also to electron-hole recombination in the nanosized siliceous domains. The narrow lines are assigned to intra-4f{sup 6}, {sup 5} D{sub 0}{yields}{sup 7} F{sub 0-4} Eu {sup 3+} transitions and from the energy position of the {sup 7} F{sub 0-4} levels a mean distance could be calculated for the Eu {sup 3+}-first neighbours. The calculated results are in good agreement with the experimental ones obtained from EXAFS analysis. (author)

  10. Technologies of value of organic wastes depending of pollution degree; Las tecnologias de valorizacion de residuos organicos en funcion del grado de contaminacion de los residuos de partida

    Energy Technology Data Exchange (ETDEWEB)

    Elias, X.; Jurado, L.

    2004-07-01

    The present article outlines the diverse possibilities afforded by present-day technology for treating the fermentable organic fraction, depending on the homogeneity of the waste collected. In accordance with the degree of contamination of the initial waste, the different possible processes for treating the organic matter are described: pasteurisation, for the very clean and homogeneous waste, composting and methanization depending on the greeter degree of contamination of the initial waste. Nevertheless, technologies based on methanization or anaerobic digestion also have at their limits regarding the presence of contaminants and the current trend for more problematic waste is their use in the manufacture of bio fuels, Finally, reference is made to the different thermal treatment technologies. (Author)

  11. Thermal decomposition of organic wastes with radionuclides by using molten salt oxidation; Decomposicao termica de residuos organicos contendo radionuclideos por meio de oxidacao em sais fundidos

    Energy Technology Data Exchange (ETDEWEB)

    Lainetti, Paulo Ernesto O.; Abrao, Alcidio [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)

    2002-07-01

    During the last decades, IPEN has performed different research developments to dominate the nuclear fuel cycle. The production processes, the development activities and the physical-chemical characterization methods have generated some effluents in the form of aqueous solutions containing radioactive elements that could be discarded after radioactive decay. Nevertheless, in spite of the possibility of waste discharging from a radiological point of view, as consequence of the low activity , some wastes containing organic solvents cannot be discarded in the sewerage system due to legislation restrictions. Some wastes, with high potential risk, such as pyridine or toluene, should be destroyed. However, their destruction in incinerators is not permitted since the presence of radioactive elements. An alternative process would be the oxidative decomposition in molten salts that is not considered incineration, because there is no flame. This work describes the developments conducted in IPEN, in bench scale, to perform tests of thermal decomposition of different hazardous wastes. (author)

  12. Biochemical parameters during the urban organic wastes stabilization processes; Estudio de parametros bioquimicos en procesos de estabilizacion de residuos organicos urbanos

    Energy Technology Data Exchange (ETDEWEB)

    Garcia Izquierdo, C.; Polo Sanchez, A.

    1999-07-01

    In this paper, the authors indicate the need for a better understanding of the stabilisation processes of urban organic wastes. The composting process is a method to change fresh organic matter into a material more humificated and less harmful. This process is carried out by a great quantity of microorganisms. We think that the changes in the organic wastes during its stabilisation should be studied by several biological and biochemical parameters (ATP, basal respiration, enzyme activities...). These parameters are good biomarkers of the microbiological activity. (Author) 9 refs.

  13. Treatment organic wastes technologies and bio treatment for bio wastes; Tecnologias para el tratamiento de los residuos organicos y biotratamiento para bioresiduos

    Energy Technology Data Exchange (ETDEWEB)

    Mata Alvarez, J. [Departamento de Ingenieria Quimica y Metalurgia, Universidad de Barcelona, Barcelona (Spain)

    1995-06-01

    From a chemical point of view, an organic waste it could be defined as that waste that contain a important amount of carbon, but from a practical point of view, an organic waste would be the waste that comes from living matter. The main characteristic of this waste is that can be easily degradable by biological treatments. This paper shows the different treatments existing in Europe. (Author)

  14. Presence of persistent organic pollutants in european domestic indoor air; Presencia de compuestos organicos persistentes en aire domestico de paises europeos

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, M. A.; Torre, A. de la; Sanz, P.; Ramos, B.

    2013-02-01

    The quality of life experienced by the world population in the the last century has been possible thanks to the development of new chemical products whose medium- and long-term consequences were not studied at the time of manufacture. These products have been used to eradicate insect plagues (insecticides) or to improve other materials (flame retardants, insulators, lubricants or dielectric products), thus saving lives or preventing substantial material and economic losses. However, recent studies have demonstrated despite the beneficial properties, their use also poses a risk to human health.. (Author) 8 refs.

  15. Experimental determination of organic liquid fuels heating value as function of the humidity; Determinacao experimental do poder calorifico de combustiveis organicos liquidos em funcao da umidade

    Energy Technology Data Exchange (ETDEWEB)

    Lyrio, Aristoteles Alves; Dalvi, Elias Antonio; Vieira, Renata da Cruz Araujo [Espirito Santo Univ., Vitoria, ES (Brazil). Dept. de Engenharia Mecanica

    1998-07-01

    This work presents experimental results for higher heating value (HHV) and lower heating value (LHV) of organic liquid fuels sold in gas stations situated at Vitoria Metropolitan Area in the state of Espirito Santo, Brazil. Experiments were conduced showing the influence of fuel water contents on the HHV and LHV such as gasoline, diesel oil, kerosene and alcohol, covering a wide range of humidity (0 to 70%). A correlation between higher heating value and the water content in the fuel was determined for the experimental data obtained. The main conclusion of the present work has shown that the content of water in the fuel makes its higher heating value to decrease in the same proportion as the value of the humidity (ratio between mass of water and mass of fuel mass of water), and so, it is very important to control the level of humidity in the fuel in order to avoid significant losses of heat released during the fuel combustion. (author)

  16. Study of the degradation of liquid-organic radioactive wastes by electrochemical methods; Estudio de la degradacion de desechos liquidos-organicos radiactivos mediante metodos electroquimicos

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez A, J. I.

    2015-07-01

    In this study degradation studies were performed on blank samples, in which two electrochemical cells with different electrodes were used, the first is constituted by mesh electrodes Ti/Ir-Ta/Ti and the second by rod electrodes Ti/Ddb, using as reference an electrolytic medium of scintillation liquid and scintillation liquid more water, applying different potentials ranging from 1 to 25 V. After obtaining the benchmarks, the treatment was applied to samples containing organic liquid radioactive waste, in this case a short half-life radioisotope as Sulfur-35, the degradation characterization of organic compounds was performed in infrared spectrometry. (Author)

  17. The olefin metathesis reaction: reorganization and cyclization of organic compounds; A reacao de metatese de olefinas: reorganizacao e ciclizacao de compostos organicos

    Energy Technology Data Exchange (ETDEWEB)

    Frederico, Daniel; Brocksom, Ursula; Brocksom, Timothy John [Sao Carlos Univ., SP (Brazil). Dept. de Quimica]. E-mail: brocksom@terra.com.br

    2005-07-15

    The olefin metathesis reaction allows the exchange of complex alkyl units between two olefins, with the formation of a new olefinic link and a sub-product olefin usually ethylene. This reaction has found extensive application in the last ten years with the development of the Grubbs and Schrock catalysts, in total synthesis of complex organic molecules, as opposed to the very important use in the petrochemical industry with relatively simple molecules. This review intends to trace a historical and mechanistic pathway from industry to academy, before illustrating the more recent advances. (author)

  18. Modelo económico para el aprovechamiento de los residuos organicos de mango y banano generados en la Central Mayorista de Antioquia

    OpenAIRE

    Ramírez Vergara, Jaime de Jesús; Mejía Echeverry, Astrid Elena

    2013-01-01

    Tesis (Maestría en Desarrollo Sostenible y Medio Ambiente). Universidad de Manizales. Facultad de Ciencias Contables, Económicas y Administrativas, 2013 Este trabajo presenta un modelo que permite simular el impacto de las alternativas de aprovechamiento de los residuos orgánicos de dos frutas, banano y mango , en la Central Mayorista de Antioquia, en el municipio de Itagüí Antioquia, Colombia Los Maestrantes que presentan la tesis y la Central Mayorista de Antioquia

  19. Change in the socio-demographic profile of consumers of organic produce/Mudanca no perfil sociodemografico de consumidores de produtos organicos

    National Research Council Canada - National Science Library

    Pereira, Maristela Costamilan; Muller, Catia Regina; Rodrigues, Fernanda Souza Abduch; Moutinho, Angelica Bandeira Afonso; Rodrigues, Kelly Lameiro; Botelho, Fabiana Torma

    2015-01-01

    The scope of this study was to establish the socio-demographic profile, health status and the relationship with the consumption of organic produce among consumers who frequent different agroecological...

  20. Characterization of sodium bentonites: effect of treatment with ammonium salt- free organic surfactant; Caracterizacao de bentonitas sodicas: efeito do tratamento com surfactante organico livre de sal de amonio

    Energy Technology Data Exchange (ETDEWEB)

    Morita, R. Y.; Barbosa, R. V.; Kloss, J.R., E-mail: julianaweber@utfpr.edu.br [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil). Dartamento de Quimica e Biologia

    2015-07-15

    Bentonite, which the main clay mineral is montmorillonite, are commercially attractive because of its abundance in nature. The clays can be modified by ion exchange reactions of ions contained in the interlayer region with cationic surfactants that include ammonium or phosphonium salts. The clays origin and the type of surfactants (modifiers) are the main factors in the alteration of physical and chemical properties of these materials. This study aims to characterize and compare the results of natural bentonite commercially available and the effect of treatments with quaternary ammonium salt and an organic compound free of ammonium salt. The FTIR and XRD results indicate the process of organophilization of clays after treatment with the surfactants. These treatments have altered the average particle size, suggesting the formation of agglomerates, which was showed in the SEM images. The results of surface area and particle size data indicated the presence of larger particles. Although the two surfactants have shown similarities in the investigated properties, the organoclays free of ammonium salt are more promising in terms of its use as well as for their preparation and solubility. (author)

  1. Spectrographic determination of metallic impurities in organic coolants for nuclear reactors; Determinacion espectrografica de impurezas metalicas en refrigerantes organicos para reactores nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Martin Munoz, M.; Alvarez Gonzalez, F.

    1969-07-01

    A spectrochemical method for determining metallic impurities in organic coolants for nuclear reactors is given. The organic matter in solid samples is eliminated by controlled distillation and dry ashing in the presence of magnesium oxide as carrier. Liquid, samples are vacuum distillated. The residue is analyzed by carrier distillation and by total burning techniques. The analytical results are discussed and compared with those obtained destroying the organic matter without carrier and using the copper spark technique. (Author) 12 refs.

  2. Biodegradation of radioactive organic liquid waste from spent fuel reprocessing; Biodegradacao de rejeitos radioativos liquidos organicos provenientes do reprocessamento do combustivel nuclear

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Rafael Vicente de Padua

    2008-07-01

    The research and development program in reprocessing of low burn-up spent fuel elements began in Brazil in 70's, originating the lab-scale hot cell, known as Celeste located at Nuclear and Energy Research Institute, IPEN - CNEN/SP. The program was ended at the beginning of 90's, and the laboratory was closed down. Part of the radioactive waste generated mainly from the analytical laboratories is stored waiting for treatment at the Waste Management Laboratory, and it is constituted by mixture of aqueous and organic phases. The most widely used technique for the treatment of radioactive liquid wastes is the solidification in cement matrix, due to the low processing costs and compatibility with a wide variety of wastes. However, organics are generally incompatible with cement, interfering with the hydration and setting processes, and requiring pre -treatment with special additives to stabilize or destroy them. The objective of this work can be divided in three parts: organic compounds characterization in the radioactive liquid waste; the occurrence of bacterial consortia from Pocos de Caldas uranium mine soil and Sao Sebastiao estuary sediments that are able to degrade organic compounds; and the development of a methodology to biodegrade organic compounds from the radioactive liquid waste aiming the cementation. From the characterization analysis, TBP and ethyl acetate were chosen to be degraded. The results showed that selected bacterial consortia were efficient for the organic liquid wastes degradation. At the end of the experiments the biodegradation level were 66% for ethyl acetate and 70% for the TBP. (author)

  3. Application of the Raman spectroscopy for the characterization of organic pesticides; Aplicacion de la espectroscopia Raman para la caracterizacion de pesticidas organicos

    Energy Technology Data Exchange (ETDEWEB)

    Sato B, R.Y.; Medina G, C.; Medina V, J.; Frausto R, C. [Centro de Investigaciones en Optica, A.C., Unidad Aguascalientes, Prol. Constitucion 607, Reserva Loma Bonita, C.P. 20200, Aguascalientes (Mexico)]. e-mail: rsato@foton.cio.mx

    2004-07-01

    Raman spectra of organophosphate, organo chlorine and bipyridyl pesticides are presented in this study. They have been obtained satisfactorily by the NlR-Raman spectroscopy technique. Pesticides have been analyzed in solution or as a solid in glass containers and on aluminum substrates. This analytic technique can be an alternative tool for the detection of pesticides in the agriculture, presenting advantages as be quick, not destructive and require little or no sample preparation. Moreover, samples can be analyzed through transparent containers avoiding contact with the toxic substances. The implementation of the aluminium substrate is easy and practical. Moreover, it is commercially available and does not need a previous preparation. The analysis of a mixture of two pesticides in a {beta} carotene solution is shown. (Author) 25 refs., 8 figs.

  4. Influence of the addition of fertilizers and organic matter amendment on mercury contaminated soil; Influencia de la adicion de fertilizantes y enmendantes organicos en suelos contaminados de mercurio

    Energy Technology Data Exchange (ETDEWEB)

    Carrasco, S.; Millan, R.

    2008-07-01

    The objective of this work was to evaluate the mercury mobilization in a soil where fertilizers and organic matter were added. The study was carried out using a soil from the mercury mining district of Almaden (Spain). This area constitutes the largest and most unusual concentration of mercury in the World. The soil has been classified as an Alfisol Xeralf Haploxeral (USDA taxonomy), and the total mercury content is 14,16 0,65 mg kg-1in average. The experimental work was performed in 1 L glass columns filled with 500 g of soil. It was carried out 3 different treatments. The fi rst one, a NPK fertilizer (15:15:15) that was applied at three different doses (recommended dose -by farmers, half recommended dose and double recommended dose). The second one, a peat (Sphagnum) with a ph between 5,5-7, and the third one, a liquid organic amendment (Molex). The experimental work was carried out using 21 columns in total, where 3 of them were used as a control (C). During ten consecutive weeks, the columns were irrigated with distilled water (150 ml) once a week. The contact time was two days; after that, the leachates were collected and filtered. Finally, the soil contained in glass columns at soil fi eld capacity was centrifuged to get the wilting point. Mercury was determined using an Advanced Mercury Analyzer (AMA-254). Results show that mercury content in all samples was under detection limit (0,5 {mu}g L-1). It is according to the fact that mercury is mainly in a cinnabar form, which had a very low solubility. The addition of fertilizers and organic matter amendment do not increase the mercury content in the leachates either in the soil solution. (Author) 102 refs.

  5. Adição dos corantes naturais antocianinas e luteína em bebidas formuladas com proteínas de soro de leite

    OpenAIRE

    Rocha,Juliana de Cássia Gomes

    2013-01-01

    A tendência atual pelo consumo de alimentos mais saudáveis, nutritivos e com funcionalidades adicionais, leva à busca de novos produtos e ingredientes que possam atender as necessidades destes consumidores. O desenvolvimento de um alimento à base de proteínas de soro de leite, ricas em aminoácidos essenciais, adicionado de antocianinas e luteína, de elevada atividade antioxidante, torna-se um importante aliado na alimentação de indivíduos que buscam saúde e bem estar. Neste contexto, o objeti...

  6. Biodegradação de uma mistura de corantes têxteis usando o fungo Ganoderma sp: um estudo cinético

    Directory of Open Access Journals (Sweden)

    Wagner José Barreto

    2011-01-01

    Full Text Available The kinetics of biodegradation by the fungus Ganoderma sp of textile dyes Yellow, Blue and Red Procion were studied in effluents using UV-Vis spectroscopy, Partial Least Squares Regression (PLS and univariate analysis. The kinetic of the reactions were founded intermediate between first and second orders and the rate constants were calculated. The biodegradation after 72 h at 28 ºC were 33.6, 43.5 and 57.7% for the dyes Yellow, Blue and Red Procion, respectively. The quantitative analysis of the effluent by HPLC method can not be used without previous separation.

  7. UTILIZAÇÃO DO COMPÓSITO NANOESTRUTURADO SIO2/TIO2NA FOTODEGRADAÇÃO DE CORANTES TÊXTEIS COM LUZ SOLAR NATURAL

    Directory of Open Access Journals (Sweden)

    Camila S. Inagaki

    2015-09-01

    Full Text Available SiO2/TiO2 nanostructured composites with three different ratios of Si:Ti were prepared using the sol-gel method. These materials were characterized using energy dispersive X-ray fluorescence, Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, high-resolution transmission electron microscopy, photoluminescence, Raman with Fourier transform infrared spectroscopy, and the specific surface area. The band gaps of materials were determined by diffuse reflectance spectra, and the values of 3.20 ± 0.01, 2.92 ± 0.02, and 2.85 ± 0.01 eV were obtained as a result of the proportional increases in the amount of Ti within the composite. The materials exhibit only the anatase (TiO2 crystalline phase and have crystalline domains ranging from 4 to 5 nm. The photodegradation process of methylene blue, royal blue GRL, and golden yellow GL dyes were studied with respect to their contact times, pH variations within the solution, and the variations in the dye concentration of the solution in response to only sunlight. The maximum amount of time for the mineralization of dyes was 90 min. The kinetics of the process follows an apparently first order model, in which the obtained rate constant values were 5.72 × 10-2 min-1 for methylene blue, 6.44 × 10-2min-1 for royal blue GRL, and 1.07 × 10-1min-1 for golden yellow.

  8. Degradação Fotocatalítica de Corante Alimentício Azorrubina e Monitoramento de Redução de Toxicidade

    Directory of Open Access Journals (Sweden)

    Danilo Rodrigues de Souza

    2016-02-01

    Full Text Available In present work, simples of the food dyes organic synthetic (C2OH12N2Na2O7S2 was submitted to photodegradation with a support of the Fenton and photo-Fenton reactions and measure toxicity with a support of essays germination of the lettuce seeds (Lactuca sativa. The results showed that, using Fenton and photo-Fenton reactions and simples dyes with a concentration of the 2500 ppm, were achieved 100% discoloration in only 30 minutes. The photocatalytic of the uv-vis light, uv-vis and H2O2, Fenton and photo-Fenton reactions, constant values presented apparent discolored of the, kap = 0.02161 min-1, kap = 0.04939 min-1, e kap = 0.1244 min-1, respectively. The reduction toxicity assays presented a significant reduction of toxicity after analyzing the samples collected in 120 minutes of the photolysis. The toxicity reduction achieved, compared to the control sample, was 17.43% for the growth of the radicle and 32.35% for the growth of the hypocotyl.  DOI: http://dx.doi.org/10.17807/orbital.v1i1.717

  9. Fotoeletrodegradação do corante AO7 utilizando filmes de nanocompósitos de ZnO-TiO2

    Directory of Open Access Journals (Sweden)

    Tânia Frade

    2012-01-01

    Full Text Available The Zn-TiO2nanocomposite films were prepared by electrodeposition, using an acidic zinc sulphate solution with TiO2 nanoparticles in suspension. The as-deposited samples have been heated in air at 450 ºC for 6 h. The XRD and SEM analyses pointed out to the metal matrix conversion from Zn to ZnO and a rich morphology of needles-shaped grains. These materials were used on the photoelectrochemical degradation of AO7, which was efficiently degraded, with 40% of color removal, after 2 h period at 1.0 V, under white light irradiation. The apparent first order rate constant of the photoelectrodegradation reaction was 4.12 x 10-3 min-1.

  10. CÉLULAS SOLARES SENSIBILIZADAS POR CORANTES NATURAIS: UM EXPERIMENTO INTRODUTÓRIO SOBRE ENERGIA RENOVÁVEL PARA ALUNOS DE GRADUAÇÃO

    Directory of Open Access Journals (Sweden)

    Gabriela G. Sonai

    2015-12-01

    Full Text Available An interesting practical experiment about the preparation of dye–sensitized solar cells (DSSC using natural dyes were carried out by the undergraduate students in the chemistry course at UNICAMP . Natural dyes were extracted from blueberries (Vaccinium myrtillus L., jabuticabas (Myrciaria cauliflora, raw and cooked beets (Beta vulgaris L., and annattos (Bixa orellana L., which were used to sensitize TiO2 films that composed the photoanode in the DSSC. A polymer electrolyte containing an iodide/triiodide redox couple was used in lieu of the use of liquid solutions to prevent any leakage in the devices. A maximum solar-to-electric energy conversion of 0.26 ± 0.02% was obtained for the solar cell prepared with annatto extracts. This experiment was an effective way to illustrate to the undergraduate students how to apply some of the chemical concepts that they learned during their chemistry course to produce electric energy from a clean and renewable energy source. Teachers could also exploit the basics of the electronic transitions in inorganic and organic compounds (e.g., metal-to-ligand charge transfer and ϖ-ϖ* transitions, thermodynamics (e.g., Gibbs free energy, acid–base reactions in the oxide solid surface and electrolyte, and band theory (i.e., the importance of the Fermi level energy.

  11. DEGRADAÇÃO FOTOCATALÍTICA DE CORANTE UTILIZANDO-SE NANOCOMPÓSITO TiO2/ÓXIDO DE

    Directory of Open Access Journals (Sweden)

    Arlene B. S. Nossol

    2016-07-01

    Full Text Available In this work the sol-gel method was used to synthesize a nanocomposite containing TiO2 and graphene oxide (GO. The photocatalytic activity of the TiO2/GO nanocomposite was evaluated regarding the degradation of a reactive dye (reactive black 5 in aqueous solution using processes assisted by UV-A radiation. Under these conditions the nanocomposite showed higher degradation efficiency than the reference photocatalyst (Degussa P25 TiO2, mainly due to the high degradation capacity of the synthesized TiO2 nanoparticles. Although contradictory to several reports in the specialized literature, no synergistic effect was observed between the nanocomposite components.

  12. Adsorção do corante azul de metileno em partículas de argilominerais: análise dos tamanhos das partículas

    Directory of Open Access Journals (Sweden)

    Rogerio Antonio Sartori

    2011-01-01

    Full Text Available Interactions of cationic dye methylene blue (MB with clay particles in aqueous suspension have been extensively studied. As already known, the number of natural negative charges on the clay modifies significantly the particle sizes dispersed in water and therefore the nature of the interaction with the dye. This work evaluated with UV-Vis spectroscopy method how the clay particle sizes weighted on the adsorption and rearrangement of the dye molecules in aqueous system. The results obtained from light-scattering measurements confirmed that larger particles are found in suspensions containing the high-charged clays as the visible absorption band related to the MB aggregates (570 nm on these suspensions prevailed.

  13. Corantes marcadores de combustíveis: legislação e métodos analíticos para detecção

    Directory of Open Access Journals (Sweden)

    Magno Aparecido Gonçalves Trindade

    2011-01-01

    Full Text Available The use of dyes in the commercialization of fuel is usually associated with protection of the source and destination. It is used as "markers" to identify and guarantee the identity of the specific product of a particular manufacturer to discourage theft, tampering and disclosure of the quality of solvent or fuel. This work presents a critical analysis on the state of the art about the available analytical methods for identification and quantification of dyes used as markers of solvents and fuels, as well as evaluation of the physical-chemical staining and laws surrounding their use and commercialization.

  14. Use of Fricke solution modified with dyes for dosimetry in phototherapeutic treatments; Uso da solucao Fricke modificada com corantes para futura dosimetria em tratamentos fototerapeuticos

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, Mayara Gabriella Oliveira de; Nascimento, Rizia Keila; Vieira, Rafaela Etelvina de Amorim; Souza, Vivianne Lucia Bormann, E-mail: mayaradqf@hotmail.com, E-mail: riziakeila@hotmail.com, E-mail: rafaelarodriguesss@hotmail.com, E-mail: vlsouza@cnen.gov.br [Centro Regional de Ciencias Nucleares do Nordeste (CRCN-NE/CNEN-PE), Recife (Brazil)

    2014-07-01

    Dyes and pigments (photosensitizers) are characterized by their ability to absorb visible light, and to participate in photochemical reactions. These colors are used in medicine in the dose recommended for use in photodynamic therapy (PDT). There are lasers that can meet most of the phototherapeutic agents and are capable of providing light of considerable power with precision on the injured tissue. The use of light emitting diodes (LEDs) have become feasible, thus reducing the cost of the procedures. The Dosimetry Laboratory Chemistry of the CRCN-NE/Brazilian CNEN has worked with some likely dye use in phototherapy treatments, including: methylene blue, malachite green and toluidine blue. A volume of 2.6 ml of the dosimeters was transferred to test tubes and these were irradiated with LED 24, 48, 72 and 96 acrylic simulator 110 mm x 110 mm x 80 mm at a distance of 6.5 cm from reading light source of the irradiated samples was performed on a spectrophotometer. Having obtaining excellent correlations (above 0.97) to the dosimeter calibration curves. Suggests that the dosimeter can be applied to perform a quality control in photodynamic therapy. However, further experiments should be performed before a wide application of this technique. A volume of 2.6 ml of the dosimeters was transferred to test tubes and these were irradiated with LED 24, 48, 72 and 96 acrylic simulator 110 mm x 110 mm x 80 mm at a distance of 6.5 cm from reading light source of the irradiated samples was performed on a spectrophotometer. Having obtaining excellent correlations (above 0.97) to the dosimeter calibration curves. Suggests that the dosimeter can be applied to perform a quality control in photodynamic therapy. However, further experiments should be performed before a wide application of this technique.

  15. Descoloração e degradação do azo corante Vermelho GRLX-220 por ozonização

    Directory of Open Access Journals (Sweden)

    Patrícia Kelly dos Santos

    2011-01-01

    Full Text Available The discoloration and degradation of the textile dye RED GRLX-220 using the electrochemically generated ozone was investigated. Total discoloration was rapidly achieved in both acid and basic conditions. A pseudo-first order kinetics was observed for discoloration, influenced by pH and ozonation time. A considerable degree of mineralization (60% was obtained after 30 min of ozonation in alkaline medium. The feasibility of organic matter oxidation during the ozonation process increased in both acidic and alkaline media. The toxicity decreased after the ozonation process, suggesting that the byproducts are less toxic than the parental compound.

  16. Substrates composition and protected environments for tamarind seedlings/Diferentes composicoes de substratos e ambientes protegidos na formacao de mudas de pe-franco de tamarindeiro

    National Research Council Canada - National Science Library

    Costa, Edilson; Ferreira, Antonio Flavio Arruda; Silva, Priscilla Nataly De Lima; Nardelli, Evandro Michel Valero

    2012-01-01

    ..., encontrada em muitos paises da Asia, Africa e America do Sul. Por apresentar sistema radicular profundo, possui resistencia a secas prolongadas e, desta forma, e indicada em cultivo de regioes semiaridas. Sua utilizacao se da, principalmente na culinaria regional, bem como suas sementes servem como forragem animal, e o oleo extraido de suas sem...

  17. Use of differentials and fill-ups at Reconcavo basin, Brazil; Utilizacao de diferenciais e fill-ups na bacia do Reconcavo Baiano, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Faria, Jose Antonio Diniz; Ribeiro, Eluzai Evangelista [PETROBRAS, BA (Brazil). Distrito de Perfuracao da Bahia. Div. de Tecnicas e Operacoes

    1994-07-01

    To publish results of the insertable valves and differential-type casing accessories with an insert fill-up wells drilled at the Bahia Drilling. This has provided an increase in casing running speed, resulting in a cost reduction of the operations due to non-interruption of running operation for fill-up with drilling fluid. (author)

  18. Gamma spectrometry used for analysis of {sup 228}Ra in water; Utilizacao de espectrometria gama para analise de {sup 228} Ra nas aguas

    Energy Technology Data Exchange (ETDEWEB)

    Mancini, Luis Henrique [UNESP, Rio Claro, SP (Brazil). Inst. de Geociencias e Ciencias Exatas; Bonotto, Daniel Marcos [UNESP, Rio Claro, SP (Brazil). Inst. de Geociencias e Ciencias Exatas. Dept. de Petrologia e Metalogenia

    1998-07-01

    A methodology for determination of the natural isotope {sup 228}Ra in water by using the characterization of the underground and superficial waters from thorium an rare earths mineralization at Morro do Ferro, Pocos de Caldas, state of Minas Gerais, Brazil. The values determined for the {sup 228}Ra in water from 5 logging holes ranged from 0.5 to 391.2 pCi/l and the superficial waters presented a variation of 1.0 to 13.9 pCi/l.

  19. Adsorptive refrigeration system using a solar collector with a thermal insulating module; Sistema de refrigeracao adsortivo com a utilizacao de um coletor solar com anteparo otico

    Energy Technology Data Exchange (ETDEWEB)

    Gurgel, Jose Mauricio [Paraiba Univ., Joao Pessoa, PB (Brazil). Laboratorio de Energia Solar]. E-mail: gurgel@les.ufpb.br; Espinola Junior, Jose [Paraiba Univ., Joao Pessoa, PB (Brazil). Curso de Pos-Graduacao em Engenharia Mecanica; Andrade Filho, Luiz Simao [Paraiba Univ., Joao Pessoa, PB (Brazil). Centro de Tecnologia. Dept. de Tecnologia da Construcao Civil; Marcondes, Francisco [Paraiba Univ., Joao Pessoa, PB (Brazil). Escola de Engenharia. Dept. de Engenharia Mecanica

    2000-07-01

    The use of a solid adsorption cooling unit based on the binary silica gel/water couple constitute an very promising way to harness solar energy refrigeration purposes. Here is presented a mathematical model for the simulation of the system under several use conditions and it was shown coherent when compared with some experimental results. The several accomplished simulations showed the need to be projected a modulate reactor that can offer cooling easiness during the night period and shown the advantage of the use of an solar collector that can be easily opened and your thermal insulating module placed across the glass close the thermal radiation when the desorption process finish. The simulations results presented here shown an better COP for this configuration through an better cooling of the collector at night. (author)

  20. Radiation therapy for the treatment of feline advanced cutaneous squamous cell carcinoma; A utilizacao da radioterapia no tratamento do carcinoma de celulas escamosas cutaneo felino avancado

    Energy Technology Data Exchange (ETDEWEB)

    Cunha, S.C.S.; Corgozinho, K.B.; Ferreira, A.M.R, E-mail: simonecsc@gmail.com [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil); Carvalho, L.A.V. [Coordenacao dos Programas de Pos-Graduacao em Engenharia (COPPE/UFRJ), RJ (Brazil); Holguin, P.G.

    2014-02-15

    The efficacy of radiation therapy for feline advanced cutaneous squamous cell carcinoma was evaluated. A full course radiation therapy protocol was applied to six cats showing single or multiple facial squamous cell carcinomas, in a total of seven histologically confirmed neoplastic lesions. Of the lesions, one was staged as T{sub 1}, and six as T{sub 4} according to WHO staging system of epidermal tumors. The animals were submitted to twelve radiation fractions of 4 Gy each, on a Monday-Wednesday-Friday schedule, and the equipment used was an orthovoltage unit. Energy used was 120 kV, 15 mA and 2 mm aluminum filter. The cats were evaluated during the treatment and 30 and 60 days after the end of the radiation therapy. In this study, 87% of the lesions had complete remission and 13% partial remission to the treatment. Side effects were considered mild according to Veterinary Radiation Therapy Oncology Group Toxicity criteria, and included erythema, epilation and rhinitis. Radiation Therapy was considered safe for feline cutaneous squamous cell carcinoma, leading to mild side effects and can represent a good therapeutic option. (author)

  1. Performance of a diesel engine transformed to spark ignition using natural gas; Desempenho de um motor diesel convertido para utilizacao de gas natural como combustivel

    Energy Technology Data Exchange (ETDEWEB)

    Gutierrez, Ricardo H.R. [Coordenacao dos Programas de Pos-Graduacao de Engenharia (LEDAV/COPPE/UFRJ), RJ (Brazil). Lab. de Ensaios Dinamicos e Analise de Vibracao; Belchior, Carlos R.P. [Coordenacao dos Programas de Pos-Graduacao de Engenharia (LMT/COPPE/UFRJ), RJ (Brazil). Lab. de Maquinas Termicas; Sodre, Jose Ricardo [Pontificia Universidade Catolica de Minas Gerais (PUC/Minas), MG (Brazil)

    2012-07-01

    A zero-dimensional thermodynamic model for a diesel engine converted for dedicated use of natural gas was developed in this work. The computational model covers from the time of closing the inlet valve to the time of opening the exhaust valve and it was divided into three stages (compression, combustion and expansion). A model based on the first law of thermodynamics for closed cycle has been developed to study the performance of the engine. The combustion process was modeled using the equation of Wiebe. It was taken into consideration the convective heat transfer through the walls of the cylinder and the heat transfer coefficient was calculated by the Eichelberg correlation. It was also considered that the thermodynamic properties vary with temperature. To represent the gas mixture behavior inside the cylinder two approaches (Ideal Gas Equation and Van Der Waals's Real Gas Equation) were used and results compared. The computational model was validated with experimental tests. (author)

  2. Poly(vinyl pyrrolidone) (PVP) hydrogels study for ophthalmologic area utilization; Estudo de hidrogeis de poli(vinil pirrolidona) (PVP) para utilizacao na area oftalmologica

    Energy Technology Data Exchange (ETDEWEB)

    Amaral, Renata Hage; Rogero, Sizue Ota; Lugao, Ademar Benevolo [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)]. E-mail: farmahage@yahoo.com.br; Cruz, Aurea S. [Instituto Adolfo Lutz, Sao Paulo, SP (Brazil)]. E-mail: aurcruz@ial.sp.gov.br; Sacramento, Rogerio S.; Lima Filho, Acacio A. Souza; Schor, Paulo [Universidade Federal de Sao Paulo (UNIFESP)/Escola Paulista de Medicina, Sao Paulo, SP (Brazil)]. E-mail: rogeroftalmo@yahoo.com.br

    2005-07-01

    Poly (vinyl pyrrolidone) (PVP) hydrogels produced by radiation-induced crosslinking were studied to compose drug delivery system to be used in the eye surface and to manufacture ophthalmic plugs. Some formulations with PVP and poly ethylene glycol (PEG) with different molar mass (300 and 600) were prepared utilizing 0.85% sodium chloride aimed to control the swelling capacity. The obtained hydrogels were characterized by gel fraction and swelling assays. The gel fraction and swelling results indicated no difference in the formulation containing or not NaCl. The gel fraction results varied from 62 to 81% and the swelling degree from 130 to 420%. In vitro assay of cytotoxicity by neutral red uptake method was the first biocompatibility test performed. The results showed no evidence of toxicity in the studied hydrogels. (author)

  3. The importance of using diffraction of X ray in clays characterization; A importancia da utilizacao da difracao de raios X na caracterizacao de argilas

    Energy Technology Data Exchange (ETDEWEB)

    Piccoli, R.; Nascimento, G.C.; Vitoretti, P.P.; Wernck, A.S.W., E-mail: rosaura@sc.senai.b [SENAI, Criciuma, SC (Brazil). Centro de Tecnologia em Ceramica; Perdona, C.R. [Universidade Barriga Verde, Cocal do Sul, SC (Brazil). Curso de Engenharia Ceramica; Perucchi, P. [Universidade do Extremo Sul Catarinense, Criciuma, SC (Brazil). Curso de Ciencia e Engenharia de Materiais

    2009-07-01

    The objective of this work is to demonstrate how the identification of crystalline phases and deg of crystallinity by diffractometry technique of X-ray (XRD) combined with chemical analysis of a sample can help in the study and characterization of raw materials, mainly those used in ceramic compositions. This study also aims to address the inherent limitations of this technique in relation to types of crystalline phases present in the sample of interest for analysis. (author)

  4. Use of the cytoprotector amifostine in patients under chemotherapy and/or radiotherapy; Utilizacao do citoprotetor amifostina em pacientes durante tratamento oncologico com quimioterapia e/ou radioterapia

    Energy Technology Data Exchange (ETDEWEB)

    Zanchi, Clarissa; Suyenaga, Edna Sayuri; Perassolo, Magda Susana [Centro Universitario Feevale, Novo Hamburgo, RS (Brazil). Curso de Ciencias Farmaceuticas]. E-mails: clarissazanchi@gmail.com; suyenaga@feevale.br; magdaperassolo@feevale.br

    2008-07-01

    In recent years, several cytoprotective agents have been developed o protect normal cells form the toxic effects of chemotherapy and radiotherapy. The ideal cytoprotectant agent would be that one able to allow the intensification of chemotherapy's dose.; to protect largest number of normal tissues and organs when used with a variety of chemotherapy agents; to confer specific protection for normal tissues; to preserve anti tumor effect and to have little and/or manageable toxicity and side effects. Amifostine fits in on these questions also presenting a broad spectrum of action. This paper aims the discussion of the use of cryoprotective amifostine, their main characteristics/functions, adverse effects, action mechanism, administration and recommended dosage. (author)

  5. Optimization of the k-edge filters utilization in the dental radiographs; Otimizacao da utilizacao dos filtros de aresta K na radiografias dentarias

    Energy Technology Data Exchange (ETDEWEB)

    Reyes, Luis M.G.; Almeida, Adelaide de [Sao Paulo Univ., Ribeirao Preto, SP (Brazil). Faculdade de Filosofia, Ciencias e Letras. Dept. de Fisica e Matematica

    2001-07-01

    The signal to noise ratio (S/N) of radiographic film images may be optimized if the thicknesses and atomic composition of the structures to be analyzed are known. With specifications and a knowledge of the interaction of photons with the materials, the photon energy for maximum contrast may be determined. We propose a K-edge filter in addition to the normal aluminum filter, to reduce the dose to the patient by the transmission of a narrow spectrum of photons with energies to optimize the image contrast. The optimum photon energy to obtain the best contrast between dental pulp and dentine and between dentine and dental enamel was determined to be 29-34 and 22-26 keV respectively. The filter material, which closely approximates these spectra, is made of Ce (Z=58) whose thickness is shown do depend on the parameters of the X-ray generator. (author)

  6. Economical analysis of the use of biogas in swine production for generation of electric energy; Analise economica da utilizacao do biogas na suinocultura para geracao de energia eletrica

    Energy Technology Data Exchange (ETDEWEB)

    Martins, Franco Muller; Oliveira, Paulo Armando Victoria de [EMBRAPA Suinos e Aves, Concordia, SC (Brazil)], Emails: franco@cnpsa.embrapa.br, paolive@cnpsa.embrapa.br

    2009-07-01

    The demand for alternative sources of energy has been growing in the last years in function of the variation on the prices of petroleum and the recent energy crisis. The anaerobic bio digestion can convert swine manure in biogas. In the present work it was studied the economic viability of the use of the biogas as alternative source for the generation of electric energy in different demand levels. The methodology utilized was the Net Present Value. The study showed that the utilization of biogas as electric energy source is economically feasible. The increase of the demand of electric energy, in the property, associated to the increase of the price of the electric energy, increases the economical profits and accelerates the time of return of the investments. (author)

  7. Investigation of the benzotriazole as addictive for carbon steel phosphating; Estudo da utilizacao do benzotriazol como aditivo para a fosfatizacao de aco carbono

    Energy Technology Data Exchange (ETDEWEB)

    Annies, V.; Cunha, M.T.; Rodrigues, P.R.P.; Banczek, E.P. [Universidade Estadual do Centro-Oeste, Guarapuava, PR (Brazil). Dept. de Quimica; Costa, I. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Terada, M. [Universidade de Sao Paulo (POLI/USP), SP (Brazil). Escola Politecnica. Dept. de Engenharia Metalurgica e de Materiais

    2010-07-01

    This work studied the viability of substitution of sodium nitrite (NaNO{sub 2}) for benzotriazole (BTAH) in the zinc phosphate bath (PZn+NaNO{sub 2}) for phosphating of carbon steel (SAE 1010). The characterization of the samples was carried out by Scanning Electron Microscopy, Optical Microscopy and X-ray diffraction. The chemical composition was evaluated by Energy Dispersive Spectroscopy. The corrosion behavior of the samples was investigated by Open Circuit Potential, Electrochemical Impedance Spectroscopy and Anodic Potentiodynamic Polarization Curves in a 0.5 mol L{sup -1} NaCl electrolyte. The experimental results showed that the phosphate layer obtained in the solution with benzotriazole (PZn+BTAH) presented better corrosion resistance properties than that obtained in sodium nitrite. The results demonstrated that the sodium nitrite NaNO{sub 2} can be replaced by benzotriazole (BTAH) in zinc phosphate baths. (author)

  8. Technological evaluation of fuel cells using natural gas for distributed power generation; Avaliacao tecnologica da utilizacao de gas natural em celulas a combustivel para geracao distribuida de energia

    Energy Technology Data Exchange (ETDEWEB)

    Brandao, Mauricio O. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-Graduacao de Engenharia (COPPE). Programa de Engenharia Mecanica; Giannini, Marcio P.; Arouca, Mauricio C. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-Graduacao de Engenharia (COPPE). Programa de Planejamento Energetico

    2004-07-01

    The search for sustainable and more rational means of power generation motivates the scientific crew to search for more efficient and cleaner systems. Oil dependence becomes from the kind of development that the humanity had and cannot be dismissed. The question is how to use this source in a more intelligent way. Fuel Cells are electrochemical devices that convert into electric energy the chemical energy from oxi-reduction reactions between a fuel and an oxidant. The current fuel used in a Fuel Cell is hydrogen and oxygen is the oxidant. The great advantage of this device is its efficiency, higher than the one achieved with internal combustion engines. Also Fuel Cells are not limited by Carnot's efficiency. This paper is about the implementation of a distributed generation system using Fuel Cells. Technical aspects are approached together with economical and environmental needs. The already existence of Gas pipelines and the grown production of Natural Gas presented by Brazil turns it into a good market for the implementation of this energy source. The evaluation of this paper shows that is technically possible to use NG in Fuel Cells, mostly in South and Southeast regions, applying the distributed generation of energy concept. The most interesting in a strategic manner is that Brazil already have an indication that it's capable of developing this technology, opening a new market tuning with world's new technological developments. Many research centers develop this technology, not only from the cell composition itself, but also manufacturing techniques. (author)

  9. Hybrid environmental robot: a tool for monitoring gas on flooded area; Robo ambiental hibrido: utilizacao como ferramenta para monitoramento de gases em areas alagadas

    Energy Technology Data Exchange (ETDEWEB)

    Goes, Emerson de; Cerqueira, Romulo Curty; Reis, Ney Robinson S. [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2008-07-01

    The impoundment of rivers for power generation leads to flooding of vast areas of land vegetation. Most submerged plants, die and enter into decomposition, releasing CO2 (carbon dioxide), CH4 (methane gas) into the air for many years. Scientists from around the world seek to clarify the processes to which these gases are submitted and their contributions to the process of global warming. Estimates suggest that the re-use of methane that passes through the turbines of these power plants could increase their energy potential by 75% and reduce their emissions of these gases by 65%, reducing their impact on global warming and resulting in carbon credits. To check the feasibility of using new processes and technologies to generate energy that recycles this biogas, operations for monitoring these biogases become routine tasks. The frequency is such that the exposure of humans to the risks of gas combustion, inherent to scenarios where these operations take place, becomes unacceptable. This motivates the use of robots in this activity. This paper presents the multi-mission platform Hybrid Environmental Robot, named 'Chico Mendes', as a tool for tracking gas emission and specially designed for flooded forest areas.

  10. Preparation and characterization of organoclays for use in polymer nanocomposites; Preparacao e caracterizacao de argilas bentoniticas organofilicas para a utilizacao em nanocompositos polimericos

    Energy Technology Data Exchange (ETDEWEB)

    Nobrega, K.C. [Universidade Federal de Campina Grande (UEMa/UFCG), PB (Brazil). Unidade Academica de Engenharia de Materiais; Leite, A.M.D.; Souza, D.D. de; Araujo, E.M.; Melo, T.J.A. de [Universidade Federal de Campina Grande (DEMa/UFCG), PB (Brazil). Dept. de Engenharia de Materiais

    2010-07-01

    The aim of this work is to obtain organoclays from a sodium bentonite clay using two organic salts, Cetremide and Dodigen, and characterize them for nanocomposites use. The obtained results by X-ray diffraction (XRD) confirmed the obtaining of organoclay, since the originally submitted sodium bentonite interlayer distance of 12,81 A, and the cation exchange when it made with two different quaternary ammonium salts (Cetremide and Dodigen), the distance expanded to 18,48 A in both treatments, indicating the effective intercalation of the organic cation. By means of infrared spectroscopy (FTIR), it was observed the appearance of adsorption bands related to the CH{sub 2} and CH{sub 3} groups, confirming the presence of chains of organic salts from the clay, no significant structural differences between the clays treated with different salts. (author)

  11. Utilization of gas micro turbines in the PETROBRAS remote unattended stations; Utilizacao de microturbinas a gas nas instalacoes desassistidas da PETROBRAS

    Energy Technology Data Exchange (ETDEWEB)

    Pavinatto, Eduardo F.; Salles, Fabio P.; Peres, Marcelo B.; Pereira, Leandro S.; Reis, Paulo F.I. dos [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2004-07-01

    This paper presents PETROBRAS experience in the utilization of gas micro turbines in the production of gas and oil located in off-shore fields and gas metering stations of the transportation system. Available alternatives will be presented for the electrical power supply of these units and they will be outstanding the acquired benefits by using gas micro turbines. Also will be presented the performance test results conducted by CENPES technical staff. Finally, we will present an analysis of the observed acting of these equipment after they have been installed in the units of PETROBRAS under the reliability point of view, maintenance rates, adaptation to the local environmental conditions, behavior of the electric system and operational versatility. (author)

  12. Utilization of the transformed of Laplace in the generalized perturbation theory; Utilizacao da transformada de Laplace na teoria de perturbacao generalizada

    Energy Technology Data Exchange (ETDEWEB)

    Lemos, Rosandra S. Mottola; Zabadal, Jorge; Vilhena, Marco Tulio de; Silva, Fernando Carvalho da [Rio Grande do Sul Univ., Porto Alegre, RS (Brazil). Programa de Pos-graduacao em Engenharia Mecanica]. E-mail: rosandrasml@yahoo.com.br

    2002-07-01

    In this work we present a analytical solution to the auxiliary and importance functions obtained from the solution of a multigroup diffusion problem in a homogeneous and heterogeneous slab. We attain the multiplication factor from the transcendental equations resulting from the application of the boundary and interface conditions. (author)

  13. The use of natural gas: a priority of the national energy problems; Utilizacao do gas natural: a prioridade da problematica energetica nacional

    Energy Technology Data Exchange (ETDEWEB)

    Poulallion, P.L. [Sinergia e Desenvolvimento (SINDE), Rio de Janeiro, RJ (Brazil)

    1987-12-31

    The successful results obtained by PETROBRAS on the exploration and production of oil and natural gas will favour a return to the consumption of cheaper primary energies.The historical considerations about the best allocation of the financial resources for the development of the country shows that the objective of energy independence accentuated the industrial dependence. Considering the elasticity of energy demand/GNP, it is possible to conclude that Brazil`s economical growth will require an increase in the energy offer. In this context, natural gas appears as the only energy capable to fulfill correctly conditions of delay availability and economical and social benefits. A program to be carried out for the realization of this development policy is presented. 8 refs., 2 tabs., 2 figs.

  14. Utilization of the arbitration in contracts of unitization in a petroleum industry; Utilizacao da arbitragem nos contratos de unitizacao na industria do petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Franca Junior, Carlos Antonio de [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

    2008-07-01

    The present work has like goal to show some controversies generated for the only paragraph of article 27 of the Law of the Oil. The legal device admits when it will not have the celebration of an agreement of unitization between the concessionaires, the use of an arbitral decision as instrument for ANP to solve the conflict. On this term - arbitral decision - we will find a lot of interpretations. To accept a mere literal interpretation is to attack the proper characteristics of the Arbitration - as way of solution of conflicts -, as well as infringing our constitutional and legal text. But, the best exit is not this; therefore using an interpretation in conformity with the constitution we obtain to adapt the norm to our constitutional system, in a rational way. Thus, the object of this work is to search elements to adjust the norm referred to our legal system. For this, we will see a examination concerning the Arbitration, as well as of Contracts of Unitization, for at a second moment discerning on the quarrels between these two subjects, in view of the Law of the Oil and the doctrine of the Oil Law. (author)

  15. Characterization of cellulose biomass for use as an excipient in pharmaceutical field; Caracterizacao de biomassa de celulose para utilizacao como excipiente na area farmaceutica

    Energy Technology Data Exchange (ETDEWEB)

    Garcia, Keth R.; Turella, Tais C.; Santos, Venina dos; Brandalise, Rosmary N. [Universidade de Caxias do Sul (UCS), Caxias do Sul, RS (Brazil). Centro de Ciencias Exatas e da Tecnologia; Angeli, Valeria W., E-mail: rnbranda@ucs.br [Universidade de Caxias do Sul (UCS), Caxias do Sul, RS (Brazil). Centro de Ciencias Biologicas e da Saude

    2015-07-01

    Every day the industry of paper and cellulose discards large amounts of waste. An alternative to reuse this kind of biomass is to transform part of it in cellulose nanocrystals and nanofibrils to be used as excipients in pharmaceutical field. Thus, cellulose fibrils were obtained in nanoscale using mill and fibrils' characterization study were performed by scanning electron microscopy, transmission electron microscopy, thermal analysis, differential scanning calorimetry, infrared Fourier transform and X-rays diffraction. Hence, the methodology used to obtain and characterize nanocellulose was effective and the fibers/fibrils lengths are in nanometer dimension with high potential to apply in the pharmaceutical field. (author)

  16. Using of electric power auctions in the Brazilian energy sector; A utilizacao de leiloes de energia eletrica no setor eletrico brasileiro

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, Luis Henrique Bassi [Agencia Nacional de Energia Eletrica (ANEEL), Brasilia, DF (Brazil)]. E-mail: lhbassi@aneel.gov.br; Camargo, Ivan Marques de Toledo [Universidade de Brasilia (UnB), DF (Brazil)]. E-mail: ivancamargo@unb.br

    2006-07-01

    The Brazilian power industry has undergone fundamental institutional changes in order to introduce competition in generation segment by allowing more flexibility to the electricity trading arrangements since mid 90. These reforms were aimed at increasing economic efficiency and both cost and energy price reduction. The restructuring process requested a highly complex legal framework in order to: ensure the necessary investments for the expansion of power infrastructure; stimulate the participation of private capital; and guarantee power supply adequacy at desired safety and reliability levels. The electricity rationing, occurred in 2001, was a result of: lack of investments, growing demand and supply vulnerability to adverse hydrological shocks. As a consequence, the Brazilian Government initiated a wide debate concerning the loopholes in the implanted model as well as the improvements needed to be adopted. The refinement of the electricity trading arrangements is an important aspect of the electric sector model revitalization. It resulted in the implantation of energy auctions aiming at increasing transactions transparency as well as establishing a long run energy price market reference and promoting market efficiency and competition. This paper analyses the implementation of energy auctions as a mechanism for trading power purchase agreements in the long term. It also discusses the Brazilian power industry restructuring process, in the face of the distribution utilities' obligation to purchase power for their captive customers. (author)

  17. Development of a ceramic material to cover walls to be applied in diagnostic radiological protection; Desenvolvimento de um material ceramico para utilizacao em protecao radiologica diagnostica

    Energy Technology Data Exchange (ETDEWEB)

    Frimaio, Audrew

    2006-07-01

    This study aims to formulate a ceramic composition for wall coating seeking to contribute to the optimization of diagnosis rooms' shielding. The work was based on experimental measures of X-radiation attenuation (80 and 100 kV) using ceramic coating materials containing different ceramic bases (red, white, gres, stoneware porcelain tiles, etc). Among the appraised ceramic bases, the white gres presented better attenuation properties and it was considered the most suitable material for the targets of this work. Different formulations of white gres were studied and altered in order to obtain better attenuation properties. Simulations of ceramic compositions using gres coating were made maintaining the percentages of 12-20% clay; 6-18% kaolin; 12-25% phyllite; 8-14% quartz; 1018% feldspar; 32-40% pegmatite and 6-8% talc in the composition of the necessary raw-material. The quantitative and qualitative chemical compositions of these materials were also evaluated and the most common representative elements are SiO{sub 2}, Fe{sub 2}O{sub 3}, Al{sub 2}O{sub 3}, CaO and Ti{sub 2}O{sub 3}. Formulations containing Pb and Ba oxides were studied, considering that CaO can be replaced by PbO or BaO. The attenuation properties for X-radiation were investigated by computer simulations considering the incident and transmitted X-ray spectra for the different studied compositions and they were compared to the properties of the reference materials Pb, Ba and BaSO{sub 4} (barite). The results obtained with the simulations indicated the formulated composition of gres ceramic base that presented better attenuation properties considering the X-ray energies used in diagnosis (80, 100 and 150 kV). Ceramic plates based on the formulated compositions that presented lower percentage differences related to Pb were experimentally produced and physically tested as wall coating and protecting barrier. Properties as flexion resistance module, density, load rupture, water absorption and X radiation attenuation were evaluated for all produced plates. (author)

  18. Use of very low frequency technology for diagnostic in medium voltage electric cables; Utilizacao da tecnologia VLF para diagnostico de cabos eletricos de media tensao

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, Flavio Costa; Pinho, Wilson Pereira de [Companhia Siderurgica Nacional (CSN), Volta Redonda, RJ (Brazil). Gerencia de Distribuicao de Energeticos

    2010-07-01

    The present technical contribution presents a new technology used in the Companhia Siderurgica Nacional (CSN) to diagnose operating conditions, useful life and faults in medium voltage electrical cables. The Very Low Frequency is a nondestructive electrical testing, conducted in medium voltage electrical cables, designed to measure the overall state of insulation of the cables, and the precise location of the fault before the failure. Through two types of tests, Delta Tangent and Partial Discharge, it is possible to make a complete diagnosis of insulation performance of the cable and also detect the fault. The implantation of this predictive technique, will monitor the useful life of medium voltage cables, avoiding potential failures in electrical circuits of Usina Presidente Vargas, allowing the intervention of maintenance before the failure, that result in interference in the production process. (author)

  19. Dosimetric analysis of daily use of IGRT in prostate treatment with intensity modulated; Analise dosimetrica da utilizacao diaria de IGRT no tratamento de prostata com intensidade modulada

    Energy Technology Data Exchange (ETDEWEB)

    Sandrini, E.S.; Silveira, T.B.; Vieira, D.S.; Batista, D.V.S., E-mail: emmilyfisica@gmail.com [Instituto Nacional de Cancer Jose de Alencar Gomes da Silva, Rio de Janeiro, RJ (Brazil)

    2014-12-15

    The main application of image-guided radiotherapy (IGRT) in the cancer prostate treatment is to ensure the delivery of the prescribed dose to the tumor. With the modality cone beam computed tomography (CBCT) prostate, seminal vesicles, bladder and rectum can be previewed before each treatment and the actual dose delivered to these organs can be controlled, through the alignment of patient isocenter. The aim of this study was to analyze the tumor coverage and dose to organs at risk effectively obtained during the patient's treatment. Three patients with prostate cancer were treated with intensity modulated radiotherapy (IMRT) or volumetric modulated arc radiotherapy (VMAT) techniques with 74 Gy and 2 Gy per fraction. It was performed daily isocenter location of the prostate with CBCT. A radioncologist drew the clinical target volume (CTV), rectum and bladder in CBCT's and treatment fields were applied retrospectively in each CBCT for dose calculation. For the CTV it was considered the D95 (dose that covers 95% of the volume), for the rectum V50 (volume receiving 50 Gy), V60, V65 and V70 and for bladder V65 and V70. The average D95 of the prostate after the offset was 202 cGy, the V50, V60 and V65 of the rectum for one patient was reduced by 9.6%, 16.6% and 31%, respectively, and V65 of the bladder to another patient was also reduced by 3.5% in IGRT. The results showed that the use of IGRT provided a reduction in the irradiated volume of healthy organs. Thus it is concluded that the use of daily CBCT allows reproducibility of treatment, reducing delayed toxicities and increasing the probability of tumor control. (author)

  20. Electric arc furnace dust utilization in iron ore sintering: influence of particle size; Utilizacao da poeira de aciaria eletrica na sinterizacao de minerio de ferro: influencia da granulometria

    Energy Technology Data Exchange (ETDEWEB)

    Telles, V.B.; Junca, E.; Rodrigues, G.F.; Espinosa, D.C.R.; Tenorio, J.A.S., E-mail: victor_bridit@hotmail.co [Universidade de Sao Paulo (USP), SP (Brazil). Dept. de Engenharia Metalurgica e de Materiais

    2010-07-01

    The aim of this work was to study the utilization of electric arc furnace dust (EAFD) generated in steelmaking by electric arc furnace (EAF) as raw material in iron ore sintering. The waste was characterized by size, chemical composition and X-ray diffraction. The physical characterization showed that 90% of the particles have a size less then 1,78 {mu}m and the material have the tendency to agglomerate. The waste were submitted to a pre-agglomeration prior to its incorporation in the sinter. The influence on the addition of the waste with different granulometry in the iron or sinter production were analyzed by sinter characterization and sintering parameters. (author)

  1. Utilization of spectroscopic and chromatographic techniques to determine plasticizers in PVC; Utilizacao de tecnicas espectroscopicas e cromatograficas na determinacao de plastificantes em PVC

    Energy Technology Data Exchange (ETDEWEB)

    Monteiro, Marcos R.; Chinelatto, Marcelo A. [Sao Carlos Univ., SP (Brazil). Centro de Caracterizacao e Desenvolvimento de Materiais]. E-mails: monteiro@ccdm.ufscar.br; mchinelatto@ccdm.ufscar.br; Cordeiro, Paulo J.M. [Sao Paulo Univ., Sao Carlos, SP (Brazil). Inst. de Quimica. Central de Analises Quimicas e Instrumentais]. E-mail: cordeiro@iqsc.usp.br

    2003-07-01

    The aim of this work was to identify plasticizers in soft PVC toys using gas chromatography and nuclear magnetic resonance as combined techniques. After extraction procedure the results of GC/NMR allowed to determine the kind of plasticizers. The results showed that DOP was found in five commercial samples investigated. The use of this phthalate in toys and children's articles are forbidden in some countries. In the quantification of soluble heavy metals by atomic absorption the level of Pb and Cd are below 63,3 mg Kg{sup -1} and 2,0 mg Kg{sup -1}, respectively. (author)

  2. Using of scanner on the evaluation of pesticides mobility by thin-layer chromatography; Utilizacao do scanner na avaliacao da mobilidade de agrotoxicos por cromatografia de camada delgada

    Energy Technology Data Exchange (ETDEWEB)

    Tornisielo, V.L.; Costa, M.A.; Furlan, G.R. [Centro de Energia Nuclear na Agricultura (CENA), Piracicaba, SP (Brazil)

    1995-12-31

    Knowledge of pesticide leaching potential is an essential information to preview environmental fate. The experiment confirms the possibility of using radiochromatogram scanning as a substitute for X-ray autoradiography, when Thin Layer Chromatografy (TLC) methodogy is used to determine mobility of a pesticide. Three types of soil from Sao Paulo state and five herbicides (metolachlor, asulan, simazing, 2,4-D and trifluralin), labeled with {sup 14} C, were used. The radiochromatogram scanners permits a quick detection of the position of the radioactive spots to determine the Rf for each pesticide, while X-ray film has to be placed on the plate on the dark room for several days or weeks and then developed to detect spots, subsequently measure and calculate Rf. The results showed that the evaluation by scanner and X-ray were similar. Hence we conclude that the use of the scanner should be considered since this methodology is faster and as accurate as the X-ray methodology. (author). 4 refs, 1 fig, 2 tabs.

  3. Economic evaluation of the industrial induction electric motors utilization of high performance; Avaliacao economica da utilizacao de motores eletricos industriais de inducao de alto rendimento

    Energy Technology Data Exchange (ETDEWEB)

    Soares, Goeorge A. [CEPEL, Rio de Janeiro, RJ (Brazil); Herszterg, I. [Universidade Federal, Rio de Janeiro, RJ (Brazil). Escola de Engenharia; Arouca, Mauricio C. [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia

    1996-12-31

    The current work makes a cost-benefit analysis of the agents` view point involved, that is, the consumer and the electric utilities. In relation to the final consumer the energy economic potential calculus due to high performance motor application was taken into consideration in three different situations: in new installations, as an alternative the damaged motor recoil and substituting motors that are operating normally. The electricity rates show a strong influence in the financial-economic evaluation as much from the consumer view point as the electric utilities. The return internal rate criteria and payback period have been used, therefore the last one not so much recommended for not portraying the real investment rentability. 6 refs., 7 figs., 1 tab

  4. Utilization of labelled urea in Helicobacter pylori eradication study by Espinheira Santa; Utilizacao de ureia marcada no estudo da erradicacao do Helicobacter pylori pela Espinheira Santa

    Energy Technology Data Exchange (ETDEWEB)

    Chausson, Yvon [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN), Belo Horizonte, MG (Brazil); Coelho, Luiz Gonzaga Vaz; Passos, Maria do Carmo Friche; Andrade, Angela Almeida Magalhaes [Minas Gerais Univ., Belo Horizonte, MG (Brazil). Hospital das Clinicas; Paiva Leriza, Duilio de; Paula Castro, Luiz de [Minas Gerais Univ., Belo Horizonte, MG (Brazil). Faculdade de Farmacia

    1995-12-31

    Maytenus ilicifolia, Espinheira Santa, is usually used to treat some gastric diseases, in special duodenal ulcer, in agreement with the medical literature. The aim of this work was to verify the efficiency of those leaves in such disease. It was selected a group of volunteers with ulcer caused by Helicobacter pylori (Hp) confirmed by Urea Breath Test (UBT). It was administered to all patients one capsule having 300 mg of dry extract of the leaves 20 minutes before the UBT. The capsule went on being administered during a week three times a day. At the end of this period two tests were applied to evaluate the Hp eradication: one 12 hours just after the treatment and another after one month. The results indicated that the antibiotic action was not confirmed. (author). 4 refs., 1 fig.

  5. Use of different simulators to quality evaluation of image quality in digital mammography; Utilizacao de diferentes simuladores na avaliacao da qualidade da imagem em mamografia digital

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, Leslie S.; Coutinho, Celia M.C., E-mail: leslie@ird.gov.br, E-mail: celia@ird.gov.br [Instituto de Radioprotecao e Dosimetria (IRD/CNEN-RJ), Rio de Janeiro, RJ (Brazil); Magalhaes, Luis A.G.; Almeida, Carlos Eduardo de, E-mail: luisalexandregm@hotmail.com, E-mail: cea71@yahoo.com.br [Universidade do Estado do Rio de Janeiro (LCR/UERJ), Rio de Janeiro, RJ (Brazil). Laboratorio de Ciencias Radiologicas

    2013-11-01

    In this study, the digital images were acquired with different exposure simulators to evaluate the quality of the image, noting the tumor mass detection, microcalcification fiber and representing regions of interest during mammography. The technical parameters of exposure depends on the thickness and composition of the breast, thus affecting the dose and image quality. The simulators were used: ACR, SBP 1054, BREAST PHANTOM CIRS and for evaluation of image quality, as well as measures kerma incident on the entrance surface (Ki) and calculating the mean glandular dose (MGD)

  6. Use of fluorescence spectroscopy to measure molecular autofluorescence in diabetic subjects; Utilizacao da espectroscopia de fluorescencia para mensuramento de moleculas autofluorescentes em individuos diabeticos

    Energy Technology Data Exchange (ETDEWEB)

    Gomes, Cinthia Zanini

    2011-07-01

    Diabetes Mellitus (DM) comprises a complex metabolic syndrome, caused by reduced or absent secretion of insulin by pancreatic beta cells, leading to hyperglycemia. Hyperglycemia promotes glycation of proteins and, consequently, the appearance of advanced glycation end products (AGEs). Currently, diabetic patients are monitored by determining levels of glucose and glycated hemoglobin (HbA1c). The complications caused by hyperglycemia may be divided into micro and macrovascular complications, represented by retinopathy, nephropathy, neuropathy and cardiovascular disease. Albumin (HSA) is the most abundant serum protein in the human body and is subject to glycation. The Protoporphyrin IX (PpIX) is the precursor molecule of heme synthesis, structural component of hemoglobin. The in vitro and animals studies have indicated that hyperglycemia promotes a decrease in its concentration in erythrocytes. The fluorescence spectroscopy is a technique widely used in biomedical field. The autofluorescence corresponds to the intrinsic fluorescence present in some molecules, this being associated with the same structure. The aim of this study was to use fluorescence spectroscopy to measure levels of erythrocyte PpIX autofluorescence and AGE-HSA in diabetic and healthy subjects and compare them with levels of blood glucose and HbA1c. This study was conducted with 151 subjects (58 controls and 93 diabetics). Epidemiological data of patients and controls were obtained from medical records. For control subjects, blood glucose levels were obtained from medical records and levels of Hb1Ac obtained by using commercial kits. The determination of the PpIX autofluorescence was performed with excitation at 405 nm and emission at 632 nm. Determination of AGE-HSA was performed with excitation at 370 nm and emission at 455 nm. Approximately 50% of diabetic had micro and macrovascular lesions resulting from hyperglycemia. There were no significant differences in the PpIX emission intensity values between groups (P = 0.89). In the analysis of AGE-HSA was observed significant differences in the values of emission intensity between the two groups, and this value was 1.45-fold greater for the group of diabetic (P <0.0001). Patients with diabetic complications had fluorescence emission intensity of 1.19-fold higher than individuals without disease complications (P = 0.01), even with no significant differences in HbA1c values between the two groups. We conclude that fluorescence spectroscopy was an effective technique in the identification of the PpIX autofluorescence and AGE-HSA. The PpIX was not an effective biomarker for the monitoring of diabetes. The determination of AGE-HSA autofluorescence was efficient for the discrimination between groups and monitoring disease progression, may be more effective than HbA1c dosage. The fluorescence spectroscopy is a simple, fast and low cost for the monitoring of diabetic patients. (author)

  7. Study of steatites for using as a high density resistor nucleus; Estudo de esteatito para utilizacao como nucleo de resistor de alta densidade

    Energy Technology Data Exchange (ETDEWEB)

    Salas, Humberto Terrazas; Costa, Antonio Carlos Lopes da; Barbosa, Joao Batista Santos; Silva, Luiz Carlos da; Rocha, Francisco de Assis [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN), Belo Horizonte, MG (Brazil)]. E-mail: salasht@cdtn.br

    2005-07-01

    In nuclear facilities where high density power resistors are applied in fuel irradiation circuits in the PWR reactor type, the probability of accident is high, therefore, it is necessary to experimentally test the nuclear facility safety project. In order to reach this goal, it is necessary to use an electric isolated material capable of withstanding high temperatures without melting or becoming deteriorated. That is where the lytologic type, classified as steatite or soapstone, must be used. The present work characterizes the steatite samples, suggesting the lytologic type to be used as the high density power resistors nucleus. Samples were selected from a steatite' processing industry located in the district of Cachoeira do Campo in Minas Gerais State. These lytologic types were sawed, evaluated macroscopically, subjected to specific preparation methods for chemical analysis and X rays diffraction, exposed to high temperatures, as well as petrographic studies and microanalyses. Samples marked by lower concentration levels of carbonates. (author)

  8. Thermal simulation of operational cycle of a steel ladles. Part 2: model utilization; Simulacao termica do ciclo operacional de uma panela de aciaria. Parte 2: utilizacao do modelo

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, Cesar L.; Baptista, Luis A.S. [Companhia Siderurgica Nacional, Volta Redonda, RJ (Brazil); Dellaretti Filho, Osmario [Minas Gerais Univ., Belo Horizonte, MG (Brazil). Dept. de Engenheria Metalurgica

    1986-12-31

    The results of the mathematical model described in part I have been compared with literature and experimental data. A good agreement has been found. The results show that refractory material close to internal surface undergoes a steep thermal gradient around 560 deg C/cm during ladle filling (author). 11 figs., 4 refs

  9. The impact of the utilization of digital technology in hydraulic turbines speed regulators; O impacto da utilizacao de tecnologia digital em reguladores de velocidade de turbinas hidraulicas

    Energy Technology Data Exchange (ETDEWEB)

    Tiburcio, Solange Numeriano Nen; Viegas, Francisco Carlos Ferreira [Comapnhia Hidroeletrica do Sao Franciso, Recife, PE (Brazil)

    1995-12-31

    The aim of this work which was performed based on the experience acquired during the implementation of digital speed regulators in Xingo hydroelectric power plant is to present the characteristics of the system implanted and analyses the technological impact caused to the hydroelectric turbines primary control by the utilization of such kind of regulators 6 figs., 3 refs.

  10. Cavitation in hydraulic turbines: the benefits of new processes and materials utilization; Cavitacao em turbinas hidraulicas: os beneficios da utilizacao de novos processos e novos materiais

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Nelio Cesar de [Parana Univ., Curitiba, PR (Brazil). Centro Politecnico

    1995-12-31

    Due to the introduction of new metallurgic technologies, this work proposes the substitution of the existing materials and processes used for the maintenance of electric turbines which present the cavitation effect. the methodology is presented. Considering the so far obtained results, it was concluded that by the utilization of the suggested techniques it is possible to obtain significant maintenance costs and time reduction 8 figs., 1 tab., 5 refs.

  11. Use of gas turbines for cogeneration in paper-mill; Utilizacao de turbinas a gas para cogeracao em fabricas de papel

    Energy Technology Data Exchange (ETDEWEB)

    Hilbert, Volnei R.; Lueska, Carlos A.D.; Gerschkovitch, Yves B.S. [Jaakko Poyry Engenharia Ltda., Sao Paulo, SP (Brazil)

    1992-12-31

    The technical and economical viability for gas turbogenerators use in Brazilian paper-mill, aiming the joint generation of electric power and steam for process is studied. A comparative analysis of conventional alternatives for cogeneration in the sector is described, analyzing a paper-mill with 400 t/d of paper production. The system used in the Brazilian industry that is the self generation of steam for the process and the electric power purchase from the concessionaire, is shown. As alternative for this system, three systems of cogeneration are presented: steam turbine, gas turbine with heat recovery and combined cycle. The mass and energy balances and the dimensioning are executed. After the dimensioning, the investment and operational costs and the incomes from each alternative are also quantified 4 refs., 7 figs.

  12. Use of MMT and MMT organoclay in production of starch nanocomposites; Utilizacao da MMT e da MMT organofilica na producao de nanocompositos de amido

    Energy Technology Data Exchange (ETDEWEB)

    Schlemmer, D.; Sales, M.J.A., E-mail: mjsales@unb.b [Universidade de Brasilia (LabPol/UnB), DF (Brazil). Inst. de Quimica. Lab. de Pesquisa em Polimeros; Macedo, J.L. de [Universidade de Brasilia (LabCat/UnB), DF (Brazil). Inst. de Quimica. Lab. de Catalise; Angelica, R.S. [Universidade Federal do Para (UFPA), Belem, PA (Brazil). Inst. de Geociencias. Lab. de Raios X

    2010-07-01

    Starch can be used to replace petrochemical plastics for short shelf life. However, starch films have poor mechanical strength and sensitivity to moisture. This can be improved through the incorporation of nanoclays, such as montmorillonite, forming nanocomposites. Nanocomposites were prepared with 1, 3, 5 and 10% of montmorillonite, using pequi oil as plasticizer. The clay was also modified with a quaternary ammonium salt. The clays were characterized by XRF, XRD, IR and TG. Results confirmed the organophilization. The nanocomposites diffractograms showed that the addition of small amounts of clay produces delaminated nanocomposites. Already the addition of larger amount of clay does not form nanocomposites, or leads to the formation of intercalated nanocomposites. (author)

  13. Improving the security of power systems with the use of metaheuristics; Melhorando a seguranca de sistemas de potencia com a utilizacao de metaheuristicas

    Energy Technology Data Exchange (ETDEWEB)

    Silva Neto, C.A. da [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Inst. de Computacao], e-mail: cneto@ic.uff.br; Schilling, M.T. [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil)], E-mail: schilling@ic.uff.br; Souza, J.C.S. [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Programa de Pos-Graduacao em Computacao], E-mail: julio@ic.uff.br

    2009-07-01

    The paper presents aspects leading the combined use of electromechanical simulations complete and metaheuristics in order to increase the safe operation of electric power systems. The index that measuring the level of security and, consequently, the ability to each candidate solution is the level of damping of oscillations voltage. The complete electromechanics simulations allow a more accurate representation of the elements of the grid resulting in a more reliable diagnosis. Metaheuristics possess a high degree of generalization enabling its application in highly complex optimization problems such as the maximization of the attenuation level of voltage oscillations, which occur in a power system, due to a defect in the net. Due to the unprecedented nature of this methodology will be investigated two different metaheuristics, one based on a evolutionary algorithm and the other in particle swarm.

  14. Virtual reality technology used to estimate radiation doses in nuclear installations; Utilizacao de ambientes virtuais na estimativa de dose de radiacao em instalacoes nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Augusto, Silas Cordeiro

    2008-03-15

    The physical integrity of people when walking in places subjected to radiation can be preserved by following some rules. Among these rules are safe limits of radiation level, proximity of radiation sources, time of exposition to radiation sources, and a combination of these factors. In this way, previous training and simulations of operation proceedings to be executed in places subjected to radiation help to better prepare the course in such places, minimizing the absorbed dose. On the other hand, virtual reality is a technology applicable in several areas, enabling the training and simulation of real places and hypothetical scenarios, with a good level of realism, but without danger if compared to the same activities in the real world. As a virtual environment does not presents any health risks, it is possible to train workers beforehand to several operation or maintenance scenarios. In this virtual environment, the dose tax distribution can be visualized, and the dose absorbed by the worker, represented and simulated in the virtual environment by a virtual character (avatar) can be shown. Therefore, the tasks to be done can be better planned, evaluating the workers actions and the performance so to reduce failures and health risks. Finally, this work presents a tool to build and navigate in virtual environments, enabling the training of activities in nuclear facilities. To that end is proposed a methodology to modify and adapt a free game engine. (author)

  15. Use of gamma probe in {sup 131}I thyroid uptake studies; Utilizacao da sonda a cintilacao na captacao de {sup 131}I pela tireoide

    Energy Technology Data Exchange (ETDEWEB)

    Sarmento, Andrea Gondim Leitao

    2002-11-01

    Evaluation of thyroid uptake by administration of radioactive iodine is a well-defined procedure to assess patient thyroid function. In general, nuclear medicine institutions use gamma cameras coupled to pinhole collimators to perform uptake studies. With the growing use of intraoperative gamma probes in the radioguided surgical techniques, several institutions are purchasing this new and portable equipment, which can technically be also employed to assess patient's thyroid function, permitting further other applications of gamma cameras. The aim of the study was to compare thyroid uptake trails carried out with both gamma camera and intraoperative gamma probe, in order to evaluate the possible use of gamma probe for this purpose. At first a preliminary study of feasibility was carried out using a neck phantom to verify equipment efficiency with known activities of {sup 131} I. Henceforth, work data from 12 patients undergone studies of thyroid uptakes were evaluated, 24 hours after oral administration of 370 kBq of {sup 131} I. The maximum difference observed between the values obtained with both equipment was 60%, which demonstrated the feasibility of the proposed protocol and made clear that gamma probe can be useful for thyroid uptake studies. (author)

  16. Utilization of niching methods of genetic algorithms in nuclear reactor problems optimization; A utilizacao dos metodos de nichos dos algoritmos geneticos na otimizacao de problemas de reatores nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Sacco, Wagner Figueiredo; Schirru, Roberto [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia. Programa de Engenharia Nuclear

    2000-07-01

    Genetic Algorithms (GAs) are biologically motivated adaptive systems which have been used, with good results, in function optimization. However, traditional GAs rapidly push an artificial population toward convergence. That is, all individuals in the population soon become nearly identical. Niching Methods allow genetic algorithms to maintain a population of diverse individuals. GAs that incorporate these methods are capable of locating multiple, optimal solutions within a single population. The purpose of this study is to test existing niching techniques and two methods introduced herein, bearing in mind their eventual application in nuclear reactor related problems, specially the nuclear reactor core reload one, which has multiple solutions. Tests are performed using widely known test functions and their results show that the new methods are quite promising, specially in real world problems like the nuclear reactor core reload. (author)

  17. Electrical energy use in different heating systems for weaned piglets; Utilizacao de energia eletrica em diferentes sistemas de aquecimento para leitoes desmamados

    Energy Technology Data Exchange (ETDEWEB)

    Sarubbi, Juliana [Universidade Federal de Santa Maria (CESNORS/UFSM), Palmeiras das Missoes, RS (Brazil). Centro de Educacao Superior Norte-RS. Dept. de Zootecnia], E-mail: jusarubbi@hotmail.com; Rossi, Luiz A.; Moura, Daniella J. de; Oliveira, Rafael A. de; David, Eduardo [Universidade Estadual de Campinas (FEAGRI/UNICAMP), SP (Brazil). Fac. de Engenharia Agricola], Emails: rossi@agr.unicamp.br, daniella.moura@agr.unicamp.br, augustus@agr.unicamp.br, eduardo.david@agr.unicamp.br

    2010-11-15

    Heating piglets in nursery and farrowing may be improved to save energy, without affecting the animals' welfare. The objective of this research was to compare the electrical energy use and thermal environment promoted by three heating technologies for piglets in nursery. The heating technologies studied were: suspended electrical resistors, heated floor and convection heating. Electrical energy consumption (kWh), maximum power demand requirements (kW), specific consumption (kWh/kg of produced live body weight), efficiency of heating system (deg C /m{sup 3} air) and dry-bulb temperature (deg C) and temperature-humidity index were evaluated. The heated floor system was better under the aspect of electrical energy use. The electrical resistance heating system was the best regarding to the animals' thermal comfort needs. (author)

  18. Quantitative computed tomography as a test of endurance for evaluation of bony plates; Utilizacao da tomografia computadorizada quantitativa como teste de resistencia para avaliacao de placas osseas

    Energy Technology Data Exchange (ETDEWEB)

    Melo Filho, E.V.; Costa, L.A.V.S.; Oliveira, D.C. [Universidade Federal do Parana (UFPR), Curitiba, PR (Brazil); Freitas, P.M.C. [Escola de Veterinaria - Universidade Federal de Minas Gerais - Belo Horizonte, MG (Brazil); Teixeira, M.W.; Costa, F.S. [Universidade Federal Rural de Pernambuco - Recife, PE (Brazil)

    2012-06-15

    Quantitative computed tomography was used to determine the radiodensity of bony plates. The CT scans provided information regarding radiodensity of bony plates and allowed to verify the uniformity of bone mineral density in their scope. The proposed methodology should be considered as another tool for determining the resistance of these biomaterials. (author)

  19. Influence of the use of organoclays on the morphology of PP/EPDM blends; Influencia da utilizacao de argilas organofilicas na morfologia de misturas PP/EPDM

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, K.R.M.; Andrade, D.L.A.C.S.; Raposo, C.M.O.; Silva, S.M.L., E-mail: suedina@dema.ufcg.edu.br [Universidade Federal de Campina Grande (UFCG/UAEMa), PB (Brazil). Unidade Academica de Engenharia de Materiais

    2012-07-01

    This study evaluated the influence of different organoclays on morphology of PP/EPDM blends. Two organobentonite (MPH and MPTH), provided by Laboratory of physical chemistry of the Academic Unit of Mining and Geology/UFCG/Campina Grande/PB and a montmorillonite (Cloisite 20A - C20A), provided by Southern Clay Products (Texas/USA) were added to the PP/EPDM polymer blend in order to obtain nanocomposites containing 1 phr of organoclay. The blends of PP/EPDM/organoclay were prepared by melt intercalation process, in an internal mixer coupled to the Haake Torque Rheometer, operating at 180 ° C and 50 rpm for 15min. The samples were characterized by X-ray diffraction and scanning electron microscopy. The results show that the type of organoclay modified the morphology of PP/EPDM blends. (author)

  20. The utilization of natural gas in the electricity production through fuel cell; A utilizacao do gas natural na geracao distribuida atraves de celulas combustiveis

    Energy Technology Data Exchange (ETDEWEB)

    Bernardi Junior, Paulo

    2004-07-01

    In function of the necessity of electric energy as input of vital importance for the development of the country, this work aims at to offer plus an energy alternative for Brazil. The exploitation of the natural gas reserves recently discovered can be made through modern methods that give as priority the distributed generation and the low ambient impact. All these aspects can be gotten with the use of fuel cell, working with the remodelled natural gas. Increased to the factor of a low ambient impact in the proper generation, the project suggests that the generating source can be located next the consumer, diminishing still more the problems generated for transmission lines, fuel transport, etc. The fuel cell has received a great attention in the international community and some models, some already in commercial period of training, they have shown excellent possibilities of capsize to be one of the future technologies in the generation of electric energy with low ambient impact. (author)

  1. Solar and wind systems utilization in water pumping for irrigation; Utilizacao de sistemas solar e eolico no bombeamento de agua para uso na irrigacao

    Energy Technology Data Exchange (ETDEWEB)

    Nogueira, Cicero Urbanetto

    2009-07-01

    In this work, it was made an applied research in two stations, the first one located at Canabarro locality and the second one at Polytechnic School at UFSM, in Santa Maria city, RS, with wind and photovoltaic equipment for pumping water. These ones are used for fruit trees irrigation in irrigation systems of low pressure. The research work was developed from September 2007 to August 2009, when the results showed the viability of wind and photovoltaic equipment for utilization in the complementary irrigation in fruit cultures such as guava, fig and grape trees. In the fruit culture sector, are installed: one multivane fans wind indicator one savonius wind indicator and respective pumps as well as pump set and a photovoltaic board. With the photovoltaic system, the pumped volume was about 5000 m{sup 3}/ha and, with the wind system, the pumped volume was approximately 6m{sup 3}/ha. The wind groups demonstrated low efficiency, if compared to photovoltaic systems, which showed more efficient. (author)

  2. Utilization of ultraviolet radiation in effluent disinfestation of domestic waste treatment systems; Utilizacao da radiacao ultravioleta na desinfeccao de efluentes de sistemas de tratamento de esgotos domesticos

    Energy Technology Data Exchange (ETDEWEB)

    Camacho, P.R.R. [Companhia de Tecnologia de Saneamento Ambiental, Sao Paulo, SP (Brazil); Andrade e Silva, L.G. de [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)

    1995-12-31

    Ultraviolet radiation disinfection of Upflow Anaerobic Sludge Biodigestor (UASB) and UASB with aerated lagoon pos-treatment effluents is possible to be reached utilizing a single low pressure mercury lamp arc (15 W nominal power) in a shell tube flow through reactor (1.2 L useful volume). Fecal coliforms, total coliforms and colifages were used as microbiological parameters. For fecal coliforms, about 3 logarithmic units (log. un.) was removed from UASB with aerated lagoon pos-treatment effluent and 4 log. un. from UASB effluent with 7 and 30 seconds of hydraulic retention time, respectively. Good empirical correlations were obtained between microbiological parameters and hydraulic retention times. (author). 4 refs, 1 fig, 3 tabs.

  3. Efecto del vermicompost y quitina sobre el control de Meloidogyne incognita en tomate a nivel de invernadero

    National Research Council Canada - National Science Library

    Castro, Leida; Flores, Lorena; Uribe, Lidieth

    2011-01-01

    ...; tiene una amplia distribucion geografica y causa perdidas agricolas importantes. Recientemente se han utilizado abonos organicos y compuestos como la quitina en la supresion de plagas y enfermedades de plantas...

  4. Technical feasibility study for the electrochemical treatment of Phaeozem soil contaminated with radioactive organic liquids; Estudio de la viabilidad tecnica para el tratamiento electroquimico de suelo Phaeozem contaminado con liquidos organicos radiactivos

    Energy Technology Data Exchange (ETDEWEB)

    Valdovinos G, V.

    2014-07-01

    The application of radioisotopes in medicine and research generates radioactive waste. A large part of these wastes are composed by scintillation liquid (mixtures of organic solvents, as toluene and xylene, fluorescent materials and surfactants) contaminated with radioisotopes such as {sup 3}H (12.3 y), {sup 14}C (5730 y), {sup 238}U (4.468 x 10{sup 9} y), {sup 232}Th (1.41 x 10{sup 10} y), {sup 204}Tl (3.7 y) or {sup 22}Na (2.6 y). In Mexico during the 80 s, these wastes were absorbed on soil to decrease their hazardous behavior during interim storage. However, these wastes must be removed for reprocessing and final landscaping. Therefore, the objective of this thesis is to study the technical feasibility of the electrochemical treatment of soils types Phaeozem contaminated with radioactive organic liquid waste (ROLW). For this study, an electrochemical treatment at laboratory level was applied, giving it an electrokinetic tracking. Control samples were prepared with different scintillation liquid (INSTAL Gel- XF, ULTIMA Gold AB{sup TM} and ULTIMA Gold XR{sup TM} as support electrolyte and polarization curves were constructed to select the current with the highest mass transfer. An analysis of the liquids and solids, before and after the application of the different potentials; the liquid phase was characterized by Gas Chromatography coupled with Flame Ionized Detector (GC-FID) and Fourier Transform Infrared Spectrometry (Ft-Irs), and the solids by Ft-Irs. From the fourteen supports electrolytes studied, eleven did not have a stable diffusion current and the other three showed a diffusion current plateau in 0.02, 0.04 and 0.06 m A·cm{sup -2}. From polarization curves, the following experimental conditions were chosen for the treatment: electrodes (meshes of titanium as anode and rod of stainless steel as cathode), scintillation liquid (ULTIMA Gold XR{sup TM} : water, 1:1) and a current of 0.06 m A·cm{sup -2}. Subsequently, radioactive control samples were prepared with soil-scintillation liquid, labeled with {sup 24}Na, {sup 99m}Tc, {sup 3}H or {sup 14}C, to determine the removal efficiency of these radioisotopes. {sup 24}Na was chosen, instead of {sup 22}Na, for its short half-life (15.03 h) to facilitate handling of samples and reduce the radiation hazards involved in using {sup 22}Na (2.6 y). In the case of {sup 99m}Tc, it did not adsorbed in the medium analyzed, and it was used as a standard. The {sup 3}H and {sup 14}C were used because they are present in the waste and could not be replaced. The {sup 24}Na and {sup 99m}Tc were quantified on a Gamma spectrometer constituted by a hyper pure germanium detector connected to a multichannel card, in 140.5 keV and 1368.6 keV for {sup 99m}Tc and {sup 24}Na respectively, and the {sup 3}H and {sup 14}C by liquid scintillation counter; all of them have a fixed geometry. The liquid and solid phases were analyzed, as well as the electrodes, by the same analytical techniques mentioned previously, once both radiotracers decayed the {sup 22}Na and {sup 99m}Tc. According to the Ft-Irs analysis, soils did not show any deterioration and, in the liquid phase, the amount of water increased, as the applied potential increased. The liquid phase chromatograms indicate that some compounds were modified after applying 5 and 7 V. The kinetic study of {sup 99m}Tc showed that 15 % to 20 % was removed each hour close to the anode, 61 % in 4 h and 91 % in 6 h. For the {sup 24}Na the removal in 4 hour of treatment was of 71.8 %, close to the cathode. In the case of {sup 14}C and {sup 3}H, the electrochemical treatment only showed an improvement in the extraction of {sup 14}C because the removal percentages are of the extraction with thinner, due to the addition of this compound, for the problems presented by taking sample; this prevented to quantify the percentages of electro-removal. (Author)

  5. Use of total organic carbon, spectral gamma ray and bioturbation as tools in the identification of source rock; Carbono organico total, gamaespectrometria e bioturbacao como ferramentas na busca de possiveis horizontes geradores de hidrocarbonetos

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Anderson S.; Pereira, Egberto [Universidade do Estado do Rio de Janeiro (UERJ), RJ (Brazil). Faculdade de Geologia. Dept. de Estratigrafia e Paleontologia

    2008-07-01

    This work presents the result obtained for the gamaespectrometric study of a borehole situated in north of Parana Basin, concerning sediments of the Ponta Grossa Formation. The Total Radioactivity data and the concentrations of Potassium (K), Uranium (U), Thorium (Th) have been compared to the Total Organic Carbon (TOC) and to the degree of bioturbation intensity. The mentioned formation is composed of basal sandstones deposited in shoreface conditions, which pass to siltstones and black shales deposited in offshore conditions. Nine sedimentary facies were identified based on sedimentological characteristics and sedimentary structures. The bioturbation intensity indicates the modification degree of the initial arrangement of sedimentary beds by the action of organisms. High TOC values in the intervals in addition to the increase of the radioactivity values indicate anoxic conditions. These conditions are ideal for the organic matter concentration and preservation, reflecting favorable intervals to the hydrocarbons (HC) generation. Thus, with the integrated use of diverse tools it was possible to confirm that the Givetian-Frasnian interval of the Ponta Grossa Formation presents the best potential of HC generation of the section analyzed. (author)

  6. Biological fixation and nitrogen transfer by three legume species in mango and soursop organic orchards;Fixacao biologica e transferencia de nitrogenio por leguminosas em pomar organico de mangueira e gravioleira

    Energy Technology Data Exchange (ETDEWEB)

    Paulino, Gleicia Miranda; Barroso, Deborah Guerra, E-mail: gleiciamiranda@yahoo.com.b, E-mail: deborah@uenf.b [Universidade Estadual do Norte Fluminense (UENF), Campos dos Goytacazes, RJ (Brazil). Dept. de Fitotecnia; Alves, Bruno Jose Rodrigues; Urquiaga, Segundo; Espindola, Jose Antonio Azevedo, E-mail: bruno@cnpab.embrapa.b, E-mail: urquiaga@cnpab.embrapa.b, E-mail: jose@cnpab.embrapa.b [EMBRAPA Agrobiologia, Seropedica, RJ (Brazil)

    2009-12-15

    The objective of this work was to evaluate the biological nitrogen fixation (BNF) and the N transfer derived from BNF of the legume species - Gliricidia sepium (gliricidia), Crotalaria juncea (sunnhemp) and Cajanus cajan (pigeon pea) - for an intercropped organic orchard with mango and soursop, through the {sup 15}N natural abundance method. The following inter cropping systems were evaluated: mango and soursop with gliricidia; mango and soursop with sunnhemp; mango and soursop with pigeon pea; and mango and soursop as control. Gliricidia showed the highest BNF potential (80%) , followed by sunnhemp (64.5%) and pigeon pea (45%). After two sunnhemp prunes, 149.5 kg ha{sup -1} of N per year were supplied, with 96.5 kg derived from BNF. After three annual prunes, gliricidia supplied 56.4 and 80.3 kg ha{sup -1} of N per year, with 45 and 64 kg derived from BNF, in two consecutive years. The quantity of N supplied to the system was higher than the mango and soursop requirements. Variations in the natural abundance of {sup 15}N were found only in soursop leaves. Gliricidia and sunnhemp were prominent in N transfer, with approximately 22.5 and 40% respectively. Green manuring using gliricidia permits fractioning of the N supply, which is an advantage in N obtention by the fruit trees (author)

  7. Controlling factors in the dynamics of soil organic carbon from the region of Murcia; Factores de control en la dinamica del Carbono Organico de los suelos de la Region de Murcia

    Energy Technology Data Exchange (ETDEWEB)

    Albaladejo, J.; Martinez-Mena, M.; Almagro, M.; Ruiz-navarro, A.; Ortiz, R.

    2009-07-01

    Sequestration and accumulation of C on the soil is a useful way to reduce the atmospheric concentration of CO{sub 2} and to mitigate the climate change. The purpose of this study was to identify the key factors which determine the accumulation and permanence of CO on the soils of the Murcia Region. The study was arranged from data displayed on the Murcia Region Soils Map (1:100.000). The results showed that quantity of stored CO in the 30cm superficial soil is significantly different depending on soil uses, soil type, altitude and texture. One conclusion is that changes from natural vegetation to cultivated soil are the greatest cause of losses of CO of soil. The increasing of altitude and proportion of thin-silt + clay contributes to CE accumulation. In altitude, the speed of mineralization of organic materials decreases, and the thin particles stimulate the physical protection and the chemical stabilization of CO of soil. (Author) 8 refs.

  8. Efeito do Solo do Materias Organicos E do Adubo Formula 4N:14P:8K Para Producao DA Batata (Solanum tuberosum L.) Semente Pre-Basica no Casa de Vegetacao

    Science.gov (United States)

    László, Márton

    2010-05-01

    Widely well know that the potato is an important vegetable crop at Brazíl. Plant grown on about 173.000 ha, with total yield of 2.6 million tons year-1. The average yield is about 15 t ha-1. This level is very low because degeneration of crop is rapid under high temperature and high viruses pressure. Therefore seed potato propagation and production is principal on consumption potato production. This is why we found it necessary to develop it. The latossolo vermelho soil-farmyard manure- burnt rice straw-fertilizer 4N:14P:8K greenhouse pot trial was set up at the National Vegetable Crops Research Center, Brasília-DF, Brazíl in 1990. The methods of the experiments were soil x farmyard manure x burnt rice straw, soil x 4N:14P:8K fertilizer and soil x farmyard manure x burnt rice straw x 4N:14P:8K fertilizer on randomized block design in total 29 combination of treatments in 5, 5 and 3 repetitions with in a total parcel of 116. According to chemical analysis of the a., soil, b., farmyard manure and c., burnt rice straw the agrochemistry parameters were as follows: a., latossolo vermelho soil: CaCO3 0.3-0.7%, humo 0.9-1.0%, pH (H2O) 5.3, pH (KCl) 4.5, AL- P2O5 3.2-3.5 mg kg-1, AL- K2O 180 mg kg-1, Mg (KCl) 70 mg kg-1, EDTA-Zn 0.5-0.8 mg kg-1, EDTA-Cu 0.5-0.6 mg kg-1, b., farmyard manure: N 1.8 g kg-1, P2O5 2.0 g kg-1, K2O 4.0 g kg-1, c., burnt rice straw: N 0.8 g kg-1, P2O5 7.0 g kg-1, K2O 4.5 g kg-1. The experimental datas were estimated by analysis of variance, ANOVA and MANOVA. The main conclusions were as follows: 1. Mixture of 80% latossolo vermelho, 10% burnt rice straw and 10% farmyard manure were shown best performance on seed potato productivity. The piece of tubers with a 0-20 mm (consumption seeds) was increased by 77%. 2. Total seed potato number was reached maximum at 10.8 g pot-1 4N:14P:8K fertilizer regarding to average of treatments with a 33%. 3. Dry biomassa production plant-1 was decreased by high dose of 4N:14P:8K fertilizer (18.0 g pot-1) with a hard effect (57%). Our results are shown that it was possible developing of the seed potato production under tropical greenhouse conditions by optimalised soil-organic matter-fertilizer system. This datas should be as indicators to sustainable field potato advisory systems. Keywords: potato (Solanum tuberosum L.), greenhouse, latossolo vermelho soil, farmyard manure, burnt rice straw, 4N:14P:8K fertilizer, sustainability, yield RESUMO A batata é atualmente uma das hortaliças de maior importância no Brasíl. Nos conduzirémos os três experimentos para aumentár-se do produção e produtividade da batata (Solanum tuberosum L.) semente pré- básica no casa de vegetação da Brazília-DF, no Empresa Brasileira de Pesquisa Agropecuaria- Centro Nacional de Pesquisas de Hortaliças no 1990. Os três experimentos (latossolo vermelho novo x esterco de curral x palha de arroz queimado, latossolo vermelho novo x adubo 4:14:8 NPK, latossolo vermelho novo x esterco de curral x palha de arroz queimado x adubo 4:14:8 NPK) no casa de vegetação foram conduzidos com total 29 combinações, no 5-5-3 repetições com total parcelas de 116. Os resultados foram submetidos a analise de variáncia, ANOVA e MANOVA. Nossos principal resultados estam apresentándo abaixo. 1. A mistura de 80% latossolo vermelho novo, 10% palha de arroz queimado e 10% de esterco de curral, apresentou os maiores valores para numero de tuberculos com 0-20 mm, peso total de tuberculos com 0-20 mm e peso total de tuberculos por vaso. 2. Há um efeito grande crescente das doses de 4N:14P:8K nos caracteres observados. 3. Analise-se do latossolo vermelho novo x esterco de curral x palha de arroz queimado x adubo 4:14:8 NPK experimento os resultados apresentárám-se que entre nas misturas também foi melhor a 80% latossolo vermelho novo, 10% palha de arroz queimado, 10% esterco de curral. Examinando-se 15 fatores, entre 11 casos afirmou-se a mistura como para melhor que a outra mistura. Nossos resultados apresentam- se que possivel aumentar em grande volumens o produção da batata semente pré- básica com a optimalisou solo-materia orgnicânico-adubo sistema. Estes informações oferecendo-se aplicar no sustentar-se extenção rural para aumentár o produção e produtividade da bata semente e consumo. Chave palavras: batata (Solanum tuberosum L.), casa de vegetação, latossolo vermelho novo, esterco de curral, palha de arroz queimado, adubo de 4:14:8 NPK, sustentação, produção

  9. Organic-inorganic hybrid materials obtained by the sol-gel method with potential use as sunscreens; Materiais hibridos organico-inorganicos (ormosil) obtidos por sol-gel com potencial uso como filtro solar

    Energy Technology Data Exchange (ETDEWEB)

    Machado, Jane K. de F.B.; Marcal, Alex L.; Lima, Omar J. de; Ciuffi, Katia J.; Nassar, Eduardo J.; Calefi, Paulo S. [Universidade de Franca, SP (Brazil)

    2011-07-01

    This work aimed at the synthesis and characterization of particles of modified silica containing the organic filter dibenzoylmethane (DBM) by the hydrolytic sol-gel method, with modifications to the Stoeber route. The structures of the resulting Xerogels were characterized by diffuse reflectance UV-VIS spectroscopy in the solid state, infrared absorption spectroscopy, Scanning Electron Microscopy (SEM) and {sup 29}Si Nuclear Magnetic Resonance ({sup 29}Si NRM). The results showed favorable formation of hybrid organic-inorganic nanoparticles with efficient absorption/reflectance of radiation in the UV / VIS range, which enables their potential use as sunscreen. (author)

  10. Determination of mean molecular weights in organic reactor coolants. III. Differential cryoscopy with thermoelectric thermometer; Determinacion de masas moleculares medias en refrigerantes nucleares organicos. III-Crioscopia diferencial con termometro termoelectrico

    Energy Technology Data Exchange (ETDEWEB)

    Becerro, E.; Carreira, M.

    1968-07-01

    The solubility problems raised by some components of the polymeric residue of irradiated polyphenolic coolants, which make it necessary to operate with very small samples, have been solved by means of a differential cryoscopic technique using a thermoelectric thermometer (thermal) as sensitive element. The method is based on the direct measurement of the difference between the freezing points of the investigated solution and of a reference solution whose concentration may be changed at will. The change of {delta} V (mV) versus c(molal) is linear, the equivalent point being determined either analytically or graphically depending on the required accuracy. The method has been tested by measurements on pure polyphenyls, using diphenyl ether as solvent. It has been also applied to the main prospective coolants for the DON reactor. Working with 10{sup 2} molal solutions the accuracy is better than {+-} 2 per cent. (Author) 2 refs.

  11. Potential migration of organic pollutants in pipes of polyethylene. Study in pipelines of distribution net of drinkable water; Migracion potential de contaminantes organicos en tubos de polietileno. Estudio en tuberias de red de distribuciond e agua potable

    Energy Technology Data Exchange (ETDEWEB)

    Ballel, X.; Ciurana de, C.; Caixach, J.; Cortina, M.; Om, M.

    2002-07-01

    Polyethylene pipes and connections are being widely used in treated water distribution services. Migration of low molecular weight compounds from the polyethylene into the water can change its final quality. This paper is about the concentrations and identification of the migration compounds found in treated water after staying in contact with low and high-density polyethylene. Identification and quantification were carried out using CLSA (Closed Loop Stripping Analysis) extraction technique and gas chromatography coupled to mass spectrometry (HRGC/HRMS). (Author) 12 refs.

  12. Chromium extraction with organic solvents. Part 3. Application to the treatment of polymetallic industrial residues; Extraction de cromo con disolventes organicos. III parte. Aplicacion al tratamiento de residuos polimetalicos industriales

    Energy Technology Data Exchange (ETDEWEB)

    Juan, D. de; Meseguer, V.; Lozano, L. J. [Universidad de Murcia. (Spain)

    1998-12-31

    The use of Primene 81R as extraction agent of chromium present in solid wastes containing nickel, iron and copper has been studied. The waste was leached with a sulphuric acid solution up to pH3 and oxidation of Cr(III) to Cr(VI) with Caro acid was also studied. Because of the negative result of oxidation, the treatment was applied on Cr(III) directly. Extraction/scrubbing/stripping process was studied in the leach. The composition of organic phase used in the extraction step was 10% v/v Primene 81R, 10% iso decanol and kerosene. All the iron, 91% Cr, 10% Ni and large part of the copper contained in the initial leach solution are recovered in the organic phase. In the scrubbing stage (with a sulphuric acid solution at pH 1,4), all the copper and nickel and 30% Cr go to the washing liquor, while all the iron and 70% Cr remained in the organic phase. In the stripping stage (with a 2N NH{sub 4}OH or 2N NaOH solution) all the iron and chromium are recovered as a precipitate of highly absorbent hydroxides. After the treatment mentioned, 63% Cr and 100% Fe are recovered as a mixture of hydroxides, and 28% of the initial chromium, all the nickel and the copper are found in the washing liquor. (Author) 4 refs.

  13. Sub products form a depuratives process of acid mine water with organic residues used as carbon source. part I; Subproductos en la depuracion de aguas acidas de mineria y empleo de residuos organicos como fuente carbonada, Parte I

    Energy Technology Data Exchange (ETDEWEB)

    Jimenez-Rodriguez, A. M.; Duran-Barrantes, M. M.; Martel-Villagran, F. J.

    2002-07-01

    Subproducts from the biological depurative process of acid mine water, such as H{sub 2}S in the biogas and HCO{sub 3} in the effluents are applied for the selective precipitation of metallic sulphides of Pb, Zn, Cu, Al an Mn, as a function of pH. To obtain the maximum H{sub 2}S concentration is principal,so several studies have been made to found the best working conditions between microorganisms and the carbon source choice. In this work,the results of the digestion process with an inoculum from the anaerobic digestion of swine manure and cheese whey as carbon source are showed. The optimal conditions obtained are: for a SO{sub 4}''=COD of 1:1,5 in HRT of 12 days, 65% of sulphate reduction, 30% of H2S in biogas. In the precipitation of metals, a reduction of 98,3% of Fe, 96,1% Cu, 79% Zn and 99% Al are obtained. AYESA (Aguas y Estructuras, S. A.) is developing the technical attendance. This study is being demonstrated under the Acid Water Treatment Program, conducted by the Consejeria del Medio Ambiente (Junta de Andalucia). (Author) 15 refs.

  14. Determination of average molecular weights on organic reactor coolants. I.- Freezing-point depression method for benzene solutions; Determinaciond e masas moleculares medias en refrigerantes nucleares organicos. I.- Crioscopia de disolucion bencenicas

    Energy Technology Data Exchange (ETDEWEB)

    Carreira, M.

    1965-07-01

    As a working method for determination of changes in molecular mass that may occur by irradiation (pyrolytic-radiolytic decomposition) of polyphenyl reactor coolants, a cryoscopic technique has been developed which associated the basic simplicity of Beckman's method with some experimental refinements taken out of the equilibrium methods. A total of 18 runs were made on samples of napthalene, biphenyl, and the commercial mixtures OM-2 (Progil) and Santowax-R (Monsanto), with an average deviation from the theoretical molecular mass of 0.6%. (Author) 7 refs.

  15. Determination of average molecular weights on organic reactor coolants. II.-Freezing point depression method for diphenyl-ether solutions; Determinacion de masas moleculares medias en refrigerantes nucleares organicos. II.- Crioscopia de disoluciones en eter difenilico

    Energy Technology Data Exchange (ETDEWEB)

    Carreira, M.

    1965-07-01

    In order to reduce limitations of solubility, the cryoscopic method developed for benzene solutions of polyphenyl mixtures has been extended to diphenyl-ether solutions by introducing some modifications imposed by the physico-chemical properties of this solvent. The Nernsto theory of Beckman's method has been revised, taking into account the heat-transfer characteristics of the system, and the results of that analysis have been used to fix upon the design parameters of a cryoscopic apparatus for measurements on diphenyl-ether solutions. (Author) 9 refs.

  16. Brominated flame retardants as persistent organic pollutants. Distribution in the environment and human exposition; Los retardantes de llama bromados como compuestos organicos persistentes. Distribucion en el medio ambiente y exposicion en humanos

    Energy Technology Data Exchange (ETDEWEB)

    Fabrellas, B.; Solis, A.; Alvarez, A.; Larrazabal, D.; Martinez, A.

    2004-07-01

    Polybrominated diphenyl ethers (PBDE) are a family of synthetic chemicals widely used in industry to delay, inhibit or even suppress combustion process in manufactured items. Flame retardant products are frequently added into plastic, electronic, paint and textile materials to reduce the risk of ignition. During last years, increasing levels of PBDEs have been detected in the environment, suggesting release from the treated surface as main pathway for environmental intake. Their physicochemical structure makes them substances of highly lipophilic bio accumulative and persistent nature, with potential toxic effects observed onto wildlife and humans. This publication resumes actual knowledge on PBDEs research and submits initiatives of human and environment exposure minimization. (Author)

  17. Electrochemical advanced oxidation processes applied to the degradation of organic compounds in aqueous effluents; Aplicacion de procesos electroquimicos de oxidacion avanzada para la degradacion de compuestos organicos en efluentes acuosos

    Energy Technology Data Exchange (ETDEWEB)

    Peralta-Hernandez, J. M.; Maldonado, M. I.; Meas-Vong, Y.; Rodriguez, F.; Godinez, L. A.; Malato, S.

    2007-07-01

    Dyeing and finishing operations produce large quantities of wastewater that contains organic dyestuff, surfactants and other contaminants that can be characterized as high levels of total organic and color. Electro-Fenton (in situ electrochemical generation of the Fenton reagent) has been studied in order to exploit the fact that the reduction of dissolved oxygen to peroxide can be carried out selectively in acidic medium on the surface of a carbonaceous cathode. In this work, we report a study in which two approaches to water treatment are combined, photo catalysis and Fenton reaction, which involves the homogeneous conversion of peroxide to hydroxyl radical (OH). (Author) 140 refs.

  18. Energetic reuse: the use of energy from organic material from urban waste for plastics recycling; Reaproveitamento energetico: uso de energia proveniente de material organico dos residuos urbanos para reciclar plasticos

    Energy Technology Data Exchange (ETDEWEB)

    Carneiro, Priscila Alves; Rocha, Carlos Roberto [Universidade Federal de Itajuba (EXCEN/UNIFEI), MG (Brazil). Centro de Excelencia em Eficiencia Energetica

    2008-07-01

    The population growth and the elevation of the purchasing status due to economic development impel the gradual increase of residues produced a year. The discarding of these residues represents a great economic and environmental challenge, mainly because of discarded plastic concentration with no energetic and economic use, a also because of the organic material that, after decomposing, produces methane, one of the most responsible for global heating when in contact with atmosphere with no control. The recycling of plastic residues is a solution to minimize its discard and to guarantee an environmental improvement for saving raw matter, however the high consumption of energy endears the process, making it difficult its economic viability. This takes the search of new alternatives for attainment of low cost energy. In the problem of discard of the organic matter it can be the solution for the recycling of these residues. The decomposition of the organic matter produces fuel (biogas) useful as power plant for the generation of necessary electricity to the recycling process. The present study analyses an alternative to recycle plastic residues, after being consumed, in some places for discarding and using energy from biogas produced in landfills or biodigestors. Initially it was carried through a data-collecting and analysis of the physical composition of the residues, indispensable to the development of the study, which allowed to daily find the average percentage of plastics (12,9%) and organic matter (41,9%) made use by the involved population. On the basis of the data of organic matter the determination in such a way of the potential of generation of the biogas as of the electric power 'recycled' was possible to leave of that they would be discarded without any use. Data-collecting on equipment used in the plastic recycling had been essential for attainment of the necessary average energy demand to the process in such a way not only for soft plastic and PET (2,12 GJ/t) but also for hard plastic (0.11 GJ/t). According to the percentage of plastics to be recycled and the amount of necessary electric power to that end it was verified recycling possibility using 'the recycled' energy of the residues in the city. The electric power generated by the use of biogas, when applying a study of case in the city of Itajuba-MG, possible of obtaining in the landfill (11,5 GJ/day) and will have used biodigestors (14,5 GJ/day) is enough to supply the necessary energy demand for recycling of the hard plastics (0,17 GJ/day), as well as soft plastics and PET (11,2 GJ/day) discarded daily in this city. The recycling of residues plastic powder-consumption using recycled energy of the discarded residues in a municipal district besides carting social and environmental earnings for using less the natural resources, it comes to contribute for the solution of problems related to the final destination of the residues and consequently for the use of the electric power generated with the use of the biogas that has your price reduced to half of the regular one, besides not having tax taking the smaller economical viability when being sold to the c place than your use, what motivates the installation of units of located recycling in the sanitary embankments or in your proximities guaranteeing a larger supporting to the municipal district in what the project intends to be implanted. (author)

  19. Classificação e caracterização de horizontes organicos sob povoamentos de Pinus taeda L. na Região de Ponta Grossa PR - 1. aproximação

    OpenAIRE

    2013-01-01

    Os horizontes orgânicos sob povoamentos de Plnua taeda com 17 anos de idade, no município de Ponta Grossa - PR, localizados em sítios de baixa, média e alta produtividade foram estudados, sendo caracterizados morfológica e quimicamente e classificados com base em padrões internacionais. Segundo o grau de decomposição foram distintos com mais freqüência seis suborizontes: Lnl, material recém-caído, apresentando tamanho original e elasticidade com fragmentação pequena ou nula; Ln2, material sem...

  20. Proyecto de comercialización del café de habas (café organico), actuando como intermediarío, para el consumo local en la ciudad de Guayaquil y como una opción de exportacion

    OpenAIRE

    Aspiazu, Karina; Navarro, Jessica; Mendoza, Oscar

    2009-01-01

    This research project is of paramount importance in the market because in our country and the province of Guayas in the level of coffee consumption is high because it is planned to market a new product highly consumable, easy entry and positioning in the market as "coffee beans" also seeks to improve the development of our city to expand the economy, identify sources of work, improving the quality of life for families. It is of interest and acceptance since it’s intermediary in th...

  1. Spectrophotometric determination of uranium with arsenazo previous liquid-liquid extraction and colour development in organic medium; Determinacion espectrofotometrica de uranio con arsenazo, previa extraccion y desarrollo del color en medio organico

    Energy Technology Data Exchange (ETDEWEB)

    Palomares Delgado, F.; Vera Palomino, J.; Petrement Eguiluz, J. C.

    1964-07-01

    The determination of uranium with arsenazo is hindered by a great number of cation which form stable complexes with the reactive and may given rise to serious interferences. By studying the optimum conditions of uranium the extraction be means of tributylphosphate solutions dissolved in methylisobuthylketone, under conditions for previous masking of the interfering cations, an organic extract was obtained containing all the uranium together with small amounts of iron. The possible interference derived from the latter element is avoided by reduction with hydroxylammoniumchlorid followed by complex formation of the Fe(II)-ortophenantroline compound in alcoholic medium. (Author) 17 refs.

  2. Biogas treatment arising from effluent anaerobic digestion: organic substrate with high sulphate content; Tratamiento de biogas generado por la digestion anaerobia de efluentes: sustratos organicos con elevado contenido en sulfato

    Energy Technology Data Exchange (ETDEWEB)

    Navia, R.; Vidal, G.

    2002-07-01

    Biological anaerobic treatment of waste water offers a good alternative for high organic rate effluents. However, in fermentation with high sulphate concentrations, sulphide could be detected in the biogas. The goal of this work is to analyze the biogas production from the anaerobic digestions of the effluents with high sulphate content. Treatment to remove sulphite in the biogas stream is also described. Oxidation in liquid phase and biological process are the most attractive treatments. In both cases, sulphite is converted in sulphate and sulphur, which have no problems in the environmental disposal. (Author) 47 refs.

  3. Nuevas estrategias de gestión, tratamiento y valorización de los efluentes organicos pecuarios: Experiencias en USDA. (Management strategies for organic livestock effluents,innovative treatment and valorization)

    Science.gov (United States)

    En la actualidad el impacto potencial de los residuos ganaderos en el medio-ambiente representa uno de los desafíos más grandes de la agricultura. Las tecnologías de tratamiento pueden tener un importante papel en el manejo de los residuos ganaderos dando más flexibilidad en los programas de la apli...

  4. Evaluation of toxicity to the biological treatment and removal of recalcitrant organic compounds from oil refineries wastewaters; Avaliacao da toxicidade ao tratamento biologico e remocao de compostos organicos recalcitrantes existentes em efluentes de refinarias de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Barros Junior, Laerte M.; Macedo, Gorete R.; Bezerra, Marcio S.; Pereira, Franklin M.S. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Dept. de Engenharia Quimica; Schmidell, Willibaldo [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil)

    2004-07-01

    Oil industry waste water usually contains recalcitrant chemical compounds, like phenol, benzene, toluene, xylene, naphthalene and acenaphthene. The respirometry, determination of respiration rate of an active biomass, is an adequate methodology for quantification of aerobic activity biological. This study aims evaluate the inhibition effect of phenol in the oxidation capacity of an industrial sludge. This work also intends to study the phenol removal through biological and photochemical-biological processes. The respirometry was carried out with synthetic solution, using sludge from an oil processing industry. The phenol degradation experiments were carried out in an activated sludge unit and in a photochemical reactor. This work suggests the potential of photochemical-biological treatment use, in relation to the biological process with a no-acclimated sludge, in the removal of refractory organic compounds from oil industry wastewaters. The characterization of biomass using the respirometry methodology showed which is a useful tool in evaluation of phenol toxicity to biological treatment. (author)

  5. Study on ionizing radiation effects in diesel and crude oil: organic compounds, hydrocarbon, sulfur and nitrogen; Estudo do efeito da radiacao ionizante em compostos organicos do diesel e do petroleo: hidrocarbonetos, sulfurados e nitrogenados

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, Luana dos Santos

    2014-07-01

    Petroleum is the most important energy and pollution source in the world, nowadays. New technologies in petrochemical industry aim to minimize energy spending at the process and to reduce pollution products. Sulfur and nitrogen compounds generate environmental problems; the most relevant is air pollution that affects the population health directly. The nuclear technology has been used in environmental protection through pollutants removal by free radicals produced at action of the radiation in water molecule. The objective of this study is to evaluate the radiation effects on oil and diesel, mainly in the hydrocarbons, organic sulfur, and nitrogen compounds. It was studied a molecule model of sulfur, named benzothiophene, diesel and crude oil samples. The samples were irradiated using a Co-60 source, Gammacell type. The total sulfur concentration in the samples was determined by X-ray fluorescence spectrometry, and organic compounds were analyzed by gas chromatography coupled to mass spectrometry (GC-MS). The study of molecular model showed that 95% was degraded at 20 kGy dose rate. Irradiation at 15 kGy of absorbed dose showed some cracking in petrol hydrocarbons, however with higher doses it was observed polymerization and low efficiency of cracking. It was observed that the sulfur compounds from diesel and petroleum was efficiently reduced. The applied doses of 15 kGy and 30 kGy were the most efficient on desulfurization of petroleum, and for diesel the highest variation was observed with 30 kGy and 50 kGy of absorbed dose. The distillation and chromatographic separation using an open column with palladium chloride as stationary phase showed a preferential separation of organic sulfur compounds in petroleum. (author)

  6. Use of {sup 13} C NMR technique for establishing a spectral database of organic compounds; Aplicacion de la RMN {sup 13} C en el establecimiento de una base de datos espectral de compuestos organicos

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, Jorge Alberto Garcia [Instituto Mexicano de Petroleo, Mexico City (Mexico); Hayamizu, Kikuko [National Institute of Materials and Chemical Investigation, Ibaraki (Japan). Div. of Basic Investigation

    1995-12-31

    A spectral database of organic compounds has been developed by Mexican Institute of Material and Chemical Research, in order to identify and characterize unknown substances. The database contains information about more than 25,000 compounds. This work has presented NMR spectra of several compounds which were used to implement this base and experimental data were also presented and an evaluation has been done 10 refs., 5 figs., 3 tabs.

  7. Preparatory of X zeolite (faujasite) with surfactant hexa decyl trimethyl ammonium bromide (HMDTA) for adsorption of organic compounds; Acondicionamiento de zeolita X (faujasita) con surfactante bromuro de hexa decil trimetil amonio (HDTMA) para adsorcion de compuestos organicos

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez R, V

    2003-07-01

    The water represents one of the most valuable natural resources for the alive beings, since it is the essential component of the alive matter. Also, it is fundamental part of our planet, since is an indispensable element for the integral development of the same one. The demographic growth, the human being's activities and the industrial growth, he/she brings as consequence an increase in the use of the water and the generation of residual waters that successively contaminate the hydrological basins, becoming an environmental problem urgent. The contamination of the water with compound such as phenol and benzene, it is a problem that it requires the search of solutions, since it is of compound not very biodegradable, able to accumulate through the food chains and very toxic to the alive beings that they enter in contact with them (Tolgyessy, 1993). In the human beings it can take place damages in liver and kidney, the Agency of Protection to the Atmosphere of the United States (EPA) it considers that the exhibition for benzene is related with the leukemia, it is also considered as a carcinogen substance. Of the methods that are used for the treatment of polluted waters, it highlights the use of adsorber and one of them is the zeolites, since they are broadly used in those separation processes. The zeolites is crystalline aluminosilicates, they are characterized for to have a big superficial area and for their great capacity of exchange cationic, due to it the process of adsorption depends on these two characteristics, since to the modified being superficially for surfactants cationic it originates an enriched layer of carbon organic, which has the capacity to remove pollutants of the water. The present work outlines as objective to carry out the superficial modification of zeolite X using hexa decyl trimethyl ammonium bromide (HMDTA-Br) to different concentrations, with the purpose of making it useful in the removal of pollutants organic, present in watery solution. The results of this investigation work indicate that the superficial modification of the zeolite X with HMDTA-Br to the four used concentrations 29, 58, 116 and 174 mmol L was possible, and it is demonstrated by the results of electronic microscopy of sweeping and for the decrease of the content of sodium carried out by Neutron activation analysis. In relation to the removal tests, it was found that the zeolite modified X with the biggest surfactant concentration it presents the highest phenol percentage removed, being this of 38% for a time of contact of 3 hours. In accordance with the results of removal of benzene is observed that the zeolite X removes 56%, but the modified zeolite removes a bigger quantity of until 90%, said percentage varies with regard to the time of contact. Therefore the modification of the zeolite X is favorable for the removal of the benzene. (Author)

  8. Gene expression studies on human keratinocytes transduced with human growth hormone gene for a possible utilization in gene therapy; Estudos da expressao genica mediante utilizacao de queratinocitos humanos normais transduzidos com o gene do hormonio de crscimento humano. Possivel utilizacao em terapia genica

    Energy Technology Data Exchange (ETDEWEB)

    Mathor, Monica Beatriz

    1994-12-31

    Taking advantage of the recent progress in the DNA-recombinant techniques and of the potentiality of normal human keratinocytes primary culture to reconstitute the epidermis, it was decided to genetically transform these keratinocytes to produce human growth hormone under controllable conditions that would be used in gene therapy at this hormone deficient patients. The first step to achieve this goal was to standardize infection of keratinocytes with retrovirus producer cells containing a construct which included the gene of bacterial b-galactosidase. The best result was obtained cultivating the keratinocytes for 3 days in a 2:1 mixture of retrovirus producer cells and 3T3-J2 fibroblasts irradiated with 60 Gy, and splitting these infected keratinocytes on 3T3-J2 fibroblasts feeder layer. Another preliminary experiment was to infect normal human keratinocytes with interleukin-6 gene (hIL-6) that, in pathologic conditions, could be reproduced by keratinocytes and secreted to the blood stream. Thus, we verify that infected keratinocytes secrete an average amount of 500 ng/10{sup 6} cell/day of cytokin during the in vitro life time, that certify the stable character of the injection. These keratinocytes, when grafted in mice, secrete hIL-6 to the blood stream reaching levels of 40 pg/ml of serum. After these preliminary experiments, we construct a retroviral vector with the human growth hormone gene (h GH) driven by human metallothionein promoter (h PMT), designated DChPMTGH. Normal human keratinocytes were infected with DChPMTGH producer cells, following previously standardized protocol, obtaining infected keratinocytes secreting to the culture media 340 ng h GH/10{sup 6} cell/day without promoter activation. This is the highest level of h GH secreted in human keratinocytes primary culture described in literature. The h GH value increases approximately 10 times after activation with 100 {mu}M Zn{sup +2} for 8-12 hours. (author). 158 refs., 42 figs., 6 tabs.

  9. Microencapsulação por gelificação iônica e interação eletrostática do corante de buriti (Mauritia flexuosa L. f.)

    OpenAIRE

    Aranha, Caroline Pereira Moura [UNESP

    2015-01-01

    The aim of this work was to study the microencapsulation process by ionic gelation associated with the electrostatic interaction of the dye extracted from the buriti pulp. Initially the surface tension, density and rheological properties of the solutions of alginate and pectin, and buriti oil emulsions, were determined. For the ionic gelation step, two alternative biopolymers were tested: alginate and amidated low-methoxyl pectin, both being gelled in the presence of calcium ions. As core mat...

  10. Obtainment of TiO{sub 2} powders solar cells photo electrodes dye sensitized; Obtencao de pos de TiO{sub 2} para fotoeletrodos de celulas solares sensibilizados por corante

    Energy Technology Data Exchange (ETDEWEB)

    Forbeck, Guilherme; Folgueras, Marilena V., E-mail: guilhermeforbeck@hotmail.com [Universidade do Estado de Santa Catarina (PGCE/UDESC), SC (Brazil). Programa de Pos Graduacao em Ciencia e Engenharia de Materiais; Chinelatto, Adilson L. [Universidade Estadual de Ponta Grossa (UEPG), PR (Brazil). Programa de Mestrado em Engenharia e Ciencia dos Materiais

    2012-07-01

    Titanium dioxide in its polymorphic anatase phase, presents interesting properties for solar cells photo electrodes dye sensitized such as the forbidden energy band, high refractive index and high constant dielectric. In this study, powders of nanometric titanium dioxide were produced with predominantly the anatase phase and high surface area. We used the sol-gel method, and titanium tetraisopropoxide as a precursor, which was hydrolyzed in nitric acid solution. The obtained powder was heated to 450 ° C, varying the time for each lot (0, 20 or 120 minutes). The powders were characterized by X-ray diffraction, atomic force microscopy and surface area analysis. For all lots nanosized crystallites predominated. It was observed that in the batch with 120min heating an increase rutile content. The TiO{sub 2} with 20min heating showed high surface area, greater than that of TiO{sub 2} as taken reference.

  11. Determinação de corantes artificiais por cromatografia líquida de alta eficiência (CLAE em pó para gelatina Determination of synthetic dyes by high performance liquid chromatography (HPCL in jelly powder

    Directory of Open Access Journals (Sweden)

    Marcelo Alexandre Prado

    2004-02-01

    Full Text Available Synthetic dyes were determined by high performance liquid chromatography in 76 samples of regular jelly and diet jelly powders, of several flavors produced by seven different manufacturers. Three sample of each product, from different batches, were analyzed. The same qualitative composition was observed for products of the same flavor from different manufacturers, but the quantitative composition varied markedly from one manufacturer to the other. There were no or few significant differences between batches from a given manufacturer, demonstrating good quality control in the use of these additives by the food industry. None of the samples exceeded the limit stipulated by Brazilian legislation.

  12. Aplicação da tecnologia de eletrofloculação na recuperação do corante índigo blue a partir de efluentes industriais

    OpenAIRE

    Paschoal Fabiana Maria Monteiro; Tremiliosi-Filho Germano

    2005-01-01

    The indigo blue dye is widely used in the textile industry. When discarded, besides polluting the environment, it affects the appearance and transparency of aquatic bodies, causing damage to flora and fauna. The removal of this dye from industrial effluents is difficult due to its resistance towards degradation. This work proposes the recovery of indigo blue by electroflocculation, as a subsidy for the treatment of effluents from the jeans industry.

  13. Degradação de corantes reativos pelo sistema ferro metálico/peróxido de hidrogênio Degradation of reactive dyes by the metallic iron/ hydrogen peroxide system

    Directory of Open Access Journals (Sweden)

    Cláudio Roberto Lima de Souza

    2005-03-01

    Full Text Available In this work the degradation of aqueous solutions of reactive azo-dyes is reported using a combined reductive/advanced oxidative process based in the H2O2/zero-valent iron system. At optimized experimental conditions (pH 7, H2O2 100 mg L-1, iron 7 g L-1 and using a continuous system containing commercial iron wool, the process afforded almost total discolorization of aqueous solutions of three reactive azo-dyes (reactive orange 16, reactive black 5 and brilliant yellow 3G-P at a hydraulic retention time of 2.5 min. At these conditions the hydrogen peroxide is almost totally consumed while the released total soluble iron reaches a concentration compatible with the current Brazilian legislation (15 mg L-1.

  14. Fotoeletrocatálise sobre Ti/TiO2 : aplicação na descoloração de mistura de corantes sintéticos

    OpenAIRE

    Thiago Nogueira Marques Cervantes

    2012-01-01

    Diversos poluentes químicos, provenientes de inúmeras atividades produtivas, demandam uma ação preventiva aos recursos naturais. A preocupação iminente é o que estes agentes podem acarretar ao meio ambiente e a contaminação do mesmo tem sido apontada como um dos maiores problemas da sociedade moderna. Com isto, novas normas e legislações cada vez mais rígidas têm sido adotadas em todo o mundo com a finalidade de minimizar o impacto dos poluentes aos recursos naturais do planeta. As indústrias...

  15. Degradação de corantes têxteis e remediação de resíduos de tingimento por processos Fenton, foto-Fenton e eletro-Fenton

    Directory of Open Access Journals (Sweden)

    Terezinha Salvador

    2012-01-01

    Full Text Available In this work the degradation of textile dyes were evaluated, using Fenton, photo-Fenton and electro-Fenton processes. Under optimized conditions Fenton and photo-Fenton processes showed high decolorization capacity of the model dyes. The electro-Fenton process was carried out in an undivided electrochemical reactor (1000 mL equipped with a carbon-felt cathode (253 cm² and a platinum gauze anode (6 cm². Under optimal conditions (J: 1.6 mA cm-2, Na2SO4: 0.075 mol L-1, pH: 3 H2O2 concentration of about 60 mg L-1 was observed. The addition of Fe2+ (15 mg L-1 induces Fenton reactions that permit almost total decolorization of textile dyes.

  16. Dyes removal of textile wastewater onto surfactant modified zeolite from coal ash and evaluation of the toxic effects; Remocao de corantes de efluente textil por zeolita de cinzas de carvao modificada por surfactante e avaliacao dos efeitos toxicos

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Patricia Cunico

    2015-07-01

    Zeolites synthesized from fly and bottom ashes and modified with hexadecyltrimethylammonium (HDTMA) were used as adsorbent to remove dyes - Solophenyl Navy (SN) and Solophenyl Turquoise (ST) and their hydrolysed forms Solophenyl Navy Hydrolysed (SNH) and Solophenyl Turquoise Hydrolysed (STH), from simulated textile wastewater. The HDTMA-modified fly zeolite (ZMF) and HDTMA-modified bottom zeolite (ZMB) were characterized by different techniques, as X-ray fluorescence spectrometry, X-ray diffraction and scanning electron microscopy, etc. The ZMF and ZMB presented negative charge probably due to the formation of a partial bilayer of HDTMA on exchangeable active sites on the external surface of unmodified zeolite. Initial dye concentration, contact time and equilibrium adsorption were evaluated. The adsorption kinetic for SN, ST, SNH and STH onto the zeolites followed the pseudo second-order model. The equilibrium time was 20 min for SN and ST and 30 min for SNH and STH, respectively. Langmuir, Freundlich and Temkin models were applied to describe the adsorption isotherms. Adsorption of the dyes were best described by the Langmuir model, with exception to SN/ZPM, SNH/ZPM and SNH/ZLM systems that followed Freundlich model. The maximum adsorption capacities were 3,64; 3,57; 2,91 e 4,93 for SN, ST, SNH e STH by ZLM, respectively and 0,235; 0,492; 1,26 e 1,86 by ZPM, in this order. The best performance for hydrolyzed dyes has been attributed to reduction of the size of dyes molecules during the hydrolysis process. Acute toxicity of the dyes to a different organism were evaluated by different test-organisms. Waterflea, Ceriodaphnia dubia showed EC50 value of 1,25; 54,5; 0,78 and 2,56 mgL{sup -1} for SN, ST, SNH and STH, respectively. The plant Lemna minor showed EC50 values of 18,9; 69,4; 10,9 and 70,9 mgL{sup -1} for SN, ST, SNH and STH, respectively. Midges larvae of Chironomus tepperi showed EC50 values of 119 and 440 mgL{sup -1} for SN and ST, respectively. Regarding the adsorption process, acute effects were substantially reduced after adsorption treatment of aqueous solution with SN and ST by ZMF, as well as their hydrolysed forms, showing no toxicity after removal of 100% of colour. After treatment with ZPM there was an increase of the toxicity, with exception of SHN and STH dyes that do not show toxicity after the treatment. Toxicity Identification Evaluation tests (TIE) were realized in order to identify what substances were causing the observed toxicity for the SN, ST and the leached of ZMF and ZMB. The acute effects were significantly reduced after manipulation with Solid-Phase Extraction (SPE) and Ethylenediaminetetraacetic acid (EDTA) for the leached of ZMB and ZMF. The dyes showed reduced in the toxicity after manipulation with EDTA indicating that the toxicants are mostly cationic metals. (author)

  17. Determinação eletroanalítica de corante reativo presente como contaminante em proteínas purificadas por cromatografia de afinidade Electroanalytical determination of a reactive dye currently used in affinity chromatography for protein purificaton

    Directory of Open Access Journals (Sweden)

    Marly E. Osugi

    2004-06-01

    Full Text Available Procion Green HE-4BD is a reactive dye currently used in affinity purification, and commonly present as a contaminant in the final biological preparation. An assay method is described to determine trace amounts of the dye in the presence of human serum albumin(HSA and leakage from agarose as affinity sorbent by cathodic stripping voltammetry. The proposed method is based on the reductive peak at -0.55V in B-R buffer pH 3 (E=0V and t= 240s, obtained when samples of HSA 2% (m/v containing dye concentrations in sodium hydroxide pH 12 are submitted to a heating time of 330 min at 80 ºC. Linear calibration curves can be obtained for RG19 dye concentrations from 5x10-9 mol L-1 to 8 x10-8 mol L-1. The detection limit (3sigma is 1x10-9 mol L-1.

  18. Tratamento de resíduos de corante por eletrofloculação: um experimento para cursos de graduação em química

    OpenAIRE

    Sidney Aquino Neto; Thiago Cavalheiro Magri; Gláucia Maria da Silva; Adalgisa Rodrigues de Andrade

    2011-01-01

    This paper describes the use of a simple experiment of electroflocculation for classroom in Chemistry. Parameters such as electrode material, current density and temperature direct influence the process efficiency. Due to the process low cost and efficient color removal, the methodology proposed has shown good potential for use in wastewater treatment. In addition, the proposed experiment allows discussion about environmental electrochemistry, introduction to concepts of water contamination b...

  19. Aplicação do método da média no volume para simulação do tingimento de fios empacotados com corantes reativos

    OpenAIRE

    Souza, Dilênio Pacheco de

    2004-01-01

    Tese (doutorado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas. Programa de Pós-Graduação em Engenharia Quimica. Neste trabalho é apresentado um estudo do processo de tingimento de fios têxteis em bobinas a partir de uma modelagem matemática baseada nas leis de conservação da massa e da espécie química, onde se utiliza o Método da Média no Volume. O modelo é desenvolvido desde a micro-escala, que é formada pelas fibras têxteis em contato com o banho de ...

  20. Teores de corantes artificiais em alimentos determinados por cromatografia líquida de alta eficiência Contents of synthetic dyes in foods determined by high performence liquid chromatography

    Directory of Open Access Journals (Sweden)

    Marcelo Alexandre Prado

    2007-04-01

    Full Text Available Synthetic dyes are much used in processed foods. HPLC was applied to different types of snacks, such as colored cereals, chocolate confetti, chewing gums and candies for the determination of those additives. In the case of artificially colored breakfast cereals, 71% of the samples exceeded the allowed limits. Regarding the portions recommended for consumption by the makers of two of the samples, the amounts exceeded those allowed by the Brazilian legislation. In the case of chocolate confetti and candies none of the samples showed higher amounts than those allowed. However 37% of the chewing gum samples presented larger contents than the authorized ones, and one sample contained five times more synthetic dyes than allowed.

  1. Adsorção do corante Reativo Azul 19 em solução aquosa por lama vermelha tratada quimicamente com peróxido de hidrogênio

    Directory of Open Access Journals (Sweden)

    Kelli Cristina de Souza

    2013-01-01

    Full Text Available Adsorption of Reactive Blue 19 dye onto activated red mud was investigated. Red mud was treated with hydrogen peroxide (LVQ and heated at both 400 ºC (LVQ400 and 500 ºC (LVQ500. These samples were characterized by pH, specific surface area, point of zero charge and mineralogical composition. Adsorption was found to be significantly dependent on solution pH, with acidic conditions proving to be the most favorable. The adsorption followed pseudo-second-order kinetics. The Langmuir isotherm was the most appropriate to describe the phenomenon of dye removal using LVQ, LVQ400 and LVQ500, with maximum adsorption capacity of 384.62, 357.14 and 454.54 mg g-1, respectively.

  2. Estudo sobre a utilização da lama vermelha para a remoção de corantes em efluentes têxteis Study on the use of red mud for removal of dyes from textile effluents

    Directory of Open Access Journals (Sweden)

    Ernesto Batista da Silva Filho

    2008-01-01

    Full Text Available Red mud is the principal residue of the alumina (Al2O3 industry. Generated during the Bayer process, it is characterized by strong alkalinity and ion exchange. Iron oxides are the principal component (30 to 60%. Annually millions of tons of red mud are generated in the world. Red mud disposal is responsible for a large part of the cost of alumina production. On the other hand, textile industry wastewaters containing dyes have a great impact on the environment and on human health. In this paper the possibility of applying red mud for the removal of dyes was investigated by two processes: adsorption and degradation by the Fenton reagent.

  3. Desenvolvimento e validação de método espectrofotométrico para determinação de corante à base de luteína adicionado em iogurte desnatado

    Directory of Open Access Journals (Sweden)

    Ana Augusta Odorissi Xavier

    2012-01-01

    Full Text Available A simple analytical method for extraction and quantification of lutein colorant added to yogurt was developed and validated. The method allowed complete extraction of carotenoids using tetrahydrofuran in vortex, followed by centrifugation, partition to diethyl ether/petroleum ether, and drying. The carotenoids dissolved in ethanol were quantified by UV-Vis spectrophotometry. This method showed linearity in the range tested (1.41-13.42 µg g-1, limits of detection and quantification of 0.42 and 1.28 µg g-1, respectively, low relative standard deviation (3.4% and recovery ranging from 95 to 103%. The method proved reliable for quantification of lutein added to yogurt.

  4. Adsorption of anionic dyes from aqueous solutions onto coal fly ash and zeolite synthesized from coal fly ash; Adsorcao de corantes anionicos de solucao aquoso em cinza leve de carvao e zeolita de cinza leve de carvao

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Terezinha Elizabeth Mendes de

    2010-07-01

    Coal fly ash, a waste generated in coal-fired electric power plant, was used to synthesize zeolite by hydrothermal treatment with NaOH solution. The fly ash (CL-2) and this synthesized zeolite (ZM-2) that was characterized as hydroxy-sodalite were used as adsorbents for anionic dyes indigo carmine (IC), and reactive orange 16 (RO16) from aqueous solutions. Effects of contact time, initial dye concentration, pH, adsorbent mass, and temperature were evaluated in the adsorption processes. The kinetics studies indicated that the adsorption followed the pseudo-second order kinetics and that surface adsorption and intraparticle diffusion were involved in the adsorption mechanism. The thermodynamics parameters demonstrated that the adsorption was spontaneous for all adsorption processes. The enthalpy data confirmed the endothermic nature for all adsorption processes except for IC/ZM-2 system which was exothermic. The entropy data showed an increased disorder at the solid/solution interface during the adsorption for all systems except for IC/ZM-2 whose negative entropy value indicated a decreased disorder at the interface. The adsorption isotherms were closely fitted to the Langmuir linear equation. The maximum adsorption capacities were 1.48 mg/g for the IC/CL-2 system; 1.13 mg/g for IC/ZM-2; 0.96 mg/g for RO16/CL-2, and 1.14 mg/g for RO16/ZM-2 at room temperature. The desorption study carried out with water, with acid aqueous solutions, and with an alkali aqueous solution showed to be inefficient both for recovering the dyes and regenerating the adsorbents. (author)

  5. Espectrofotometria derivativa: uma estratégia simples para a determinação simultânea de corantes em alimentos Derivative spectrophotometry: a simple strategy for simultaneous determination of food dyes

    Directory of Open Access Journals (Sweden)

    Eliane Cristina Vidotti

    2006-04-01

    Full Text Available A very simple spectrophotometric method is described for resolving binary mixture of the food colorants Sunset Yellow (INS 110 and Tartrazine Yellow (INS 102 by using the first derivative spectra with measurements at zero-crossing wavelengths. Before the spectrophotometric measurements, the dyes were sorbed onto polyurethane foam and recovered in N,N-dimethilformamide. Commercial food products (gelatine and juice powder were analysed by using the proposed method and the HPLC technique. The results are in very good agreement and the differences between the methods is not statistically important. Therefore, the first-order derivative spectrophotometric method is accurate, precise, reliable and could be applied to the routine analysis of food samples.

  6. Avaliação das alterações do fluido crevicular gengival drenado de tecidos gengivais clinicamente normais submetidos à laser em baixa intensidade: estudo em anima nóbile

    OpenAIRE

    Livio de Barros Silveira

    2008-01-01

    Nesta area da periodontia em que se situam os tecidos gengivais, a circulacao sanguinea periferica do periodonto e o liquido sulcular gengival (proveniente do sulco gengival) sao as duas importantes barreiras imunologicas que atuam na defesa dessa regiao, que e, por excelencia, a porta de entrada e instalacao da doenca periodontal. O presente estudo objetiva avaliar a utilizacao de uma conduta conservadora, nao invasiva, de ativacao da barreira imunologica contra a instalacao da doenca period...

  7. Development of DP (Dynamic Positioning) to pull-in sub sea pipelines; Utilizacao de barcos de manuseio de ancoras operando com DP (Dynamic Positioning) para arraste de dutos submarinos

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Manoel H.S. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil); Galgoul, Elton C. [Suporte Engenharia, Luziania, GO (Brazil)

    2004-07-01

    Sub sea pipeline construction at oil and gas fields, with high concentration of on-bottom facilities, becomes more difficult when mooring operations and pipeline approach to a congested platform have to be performed. One method that has often been applied in Brazil is the so-called 'DP (Dynamic Positioning) pull-in', where PETROBRAS owned pipelay Barge, BGL-1, is moored away from the congested area, while a DP anchor handler pulls the rigid pipeline from BGL-1 to a target near the platform. The method was conceived to avoid mooring operations near the congested platforms as well as to minimize risks due to the pipeline initiation process. Inside the congested area the initiation with aid of a 'dead-man' anchor on the sea bottom, which would be a more conventional solution, becomes impossible in most cases. This paper will discuss the engineering work required to perform the 'DP pull-in' as well as show the operational steps, from the start-up to the final abandonment of the pipeline initiation head inside the target area. (author)

  8. The utilization of induction generators working with PATs (pumps working as turbines) in electric energy generation; A utilizacao de geradores de inducao acionados por BFTs (bombas funcionando como turbinas) na geracao de energia eletrica

    Energy Technology Data Exchange (ETDEWEB)

    Viana, Augusto Nelson Carvalho; Rezek, Angelo Jose Junqueira; Medeiros, Daniel de Macedo [Universidade Federal de Itajuba (UNIFEI), MG (Brazil). Programa de Pos-graduacao em Engenharia da Energia], e-mail: augusto@unifei.edu.br, e-mail: rezek@iee.efei.br, e-mail: macedo@unifei.edu.br

    2004-07-01

    The utilization of the Pumps working as Turbines (PATs) in micro hydro-energy resources to replace the conventional turbines as Pelton, Francis and Propeller have been used in countries as USA, Germany and France. In the mean time, in Brazil this practice and the utilization of induction generators working with PATs is still in the scope of the laboratory experiments. This work, based on experimental results carried on in Laboratory of Hydromechanics for Small Hydro Power Plants (Laboratorio Hidromecanico para Pequenas Centrais Hidroeletricas - LHPCH - UNIFEI), (VIANA, 1987), (VIANA e NOGUEIRA, 1990), propose the utilization of asynchronous generator groups operating with PATs. To show the investment cost decrease in micro hydro power plants (MHPs), is showed the Boa Esperanca MPH example, in which is presented a comparison between the synchronous generator group cost working with a Michell-Banki turbine and a asynchronous generator group operating with a PAT. (author)

  9. The use of gamma radiation aiming to post harvest conservation of Cantaloupe melon (Cucumis melo L. var. Cantaloupensis);Utilizacao de radiacao gama em meloes cantaloupe (Cucumis melo L. var. Cantaloupensis) como tecnica de conservacao pos-colheita

    Energy Technology Data Exchange (ETDEWEB)

    Siqueira, Alessandra Aparecida Zilio Cozzo de

    2007-07-01

    Although Brazilian fruit culture has been growing in the international market, the fruit quality and the post harvest technology have not been improved properly. In Brazil, fruit nutritional factors are very important because of their potential to provide suitable nutrients for a significant part of the Country population. Some post harvest technologies, such as ionizing radiation, can keep the physical, chemical, nutritional and sensorial characteristics of the natural fruit, improving the quality of the fruits in the market. This work evaluated the effects of Cobalt 60 irradiation in Cantaloupe melon, aiming the post harvest conservation during 7 days of storage, at a temperature ranging from 20 to 22 deg C. The doses of irradiation were set to 0, 150, 300, 450, 600, 750 and 900 Gy, based on the multiple of 150 Gy quarantine dose, aiming to establish the lowest, the highest and the ideal doses. Afterwards, physical, chemical and nutritional characteristics of irradiated fruit were checked and, finally, the sensorial characteristics through acceptability test. Results indicated that the doses higher than 450 Gy affected firmness, pulp yield and color (L and a{sup *}) parameters. Nevertheless, analyzing physical, chemical and nutritional parameters, doses of 450 and 900 Gy kept pH, tetrable acidity, soluble solids, color (a{sup *} and b{sup *}), chlorophyll and carotenoids, phenolic compounds, respiratory rate and ethylene level. The storage period was the most important factor that affected the quality of the fruit, despite of the radiation doses. Based on the acceptability test, the best evaluated fruits were from the treatments of 450 and 900 Gy. This work allowed to conclude that fruit radiation is an appropriate technology for Cantaloupe melon post harvest conservation, but it is necessary to be used in combination with other technologies, especially to fungi control. (author)

  10. Comparative analysis of the use of biomass with conventional generation technologies by applying eco-efficiency; Analise comparativa da utilizacao da biomassa com tecnologias convencionais de geracao aplicando eficiencia ecologica

    Energy Technology Data Exchange (ETDEWEB)

    Lora, Electo Eduardo Silva [Universidade Federal de Itajuba (UNIFEI), MG (Brazil)], e-mail: electo@unifei.eu.br; Salomon, Karina Ribeiro [Universidade Federal de Itajuba (UNIFEI), MG (Brazil). Nucleo de Estudos em Sistemas Termicos], e-mail: karinas@unifei.edu.br

    2004-07-01

    The world's concern regarding the reduction atmospheric emissions, due to the global warming, it is a subject that is being quite discussed. A parameter that evaluates the environmental impact considering the emissions of CO{sub 2}, SO{sub x}, NO{sub x} and PM in an integral way and comparing to the international air quality standards that are in force is called ecological efficiency ({epsilon}). This paper intends to compare environmental impacts of the atmospheric pollution due to technologies that use the biomass as fuel with conventional and advanced technologies of electricity generation. It is also evaluated the advantages of the use of the cogeneration starting from the biomass. The most important results that were obtained are comparative graphs confirming that the use of the biomass as energy source is a good option from the ecological point of view, when pollution control methods are used. (author)

  11. Evaluation of specific consumption from the use of chicken oil biodiesel in one cylinder generator set; Avaliacao do consumo especifico a partir da utilizacao de biodiesel de oleo de frango em um grupo-gerador monocilindrico

    Energy Technology Data Exchange (ETDEWEB)

    Fiorese, Diego Augusto [Universidade Federal de Santa Maria (PGEAGRI/UFSM), RS (Brazil). Dept. de Engenharia Rural. Programa de Pos-Graduacao em Engenharia Agricola], E-mail: dafiorese@yahoo.com.br; Lima, Paulo Peruzzo de [Faculdade Assis Gurgacz (FAG), Cascavel, PR (Brazil); Souza, Abel Alves de; Souza, Samuel Nelson Melegari de [Universidade Estadual do Oeste do Parana (UNIOESTE), Cascavel, PR (Brazil). Dept. de Ciencias Exatas e Tecnologicas; Dallmeyer, Arno Udo [Universidade Federal de Santa Maria (PGEAGRI/UFSM), RS (Brazil). Programa de Pos-Graduacao em Engenharia Agricola

    2010-07-01

    Biodiesel can be produced from numerous materials, including by-products of animal chain. In this scenario, the chicken's oil, that is located and an environment not explored for biodiesel production, can be a good alternative in South and Southeast Brazilian Region, where they are slaughtered around 9.100.000 chickens per day. In order to determine the specific consumption from a generator set with single cylinder 6.6 kW of power and generation capacity of 5 kW, using chicken oil biodiesel (B-100), were performed the bench test using a auxiliary tank, precision scale and an energy analyzer. Were conducted four treatments (25%, 50%, 75% and 100% of generating capacity). The worst SC was the engine at 25% of generation capacity (1.5 kW) and better with 75% of maximum load (3.75 kW) with a mean of 479.34 g kWh{sup -1}. By Turkey's test ant 5% probability there was a significant difference only for the first treatment. (author)

  12. Polymer matrices obtained by ionizing radiation for using in controlled drug delivery systems; Matrizes polimericas obtidas mediante radiacao ionizante para sua utilizacao como sistemas de liberacao controlada de farmacos

    Energy Technology Data Exchange (ETDEWEB)

    Martellini, Flavia

    1998-07-01

    Two kinds of controlled drug delivery system were obtained by gamma radiation induced polymerization. One of the system was obtained from an acrylic derivative of acetaminophen (40-hydroxyacetanilide), by copolymerization of 4-(acryloyloxy) acetanilide and N,N-dimethylacrylamide (DMAA) in dimethylformamide solution with 0,16 kGy/h dose rate and 54 Gy dose. The values of reactivity rate, r-D{sub MAA} = 0,31 {+-} 0,02 e r{sub AOA} -0,07 {+-} 0,12, were determined by Fineman-Ross method. The acetaminophen hydrolysis was carried out in alkaline and enzymatic (trypsin) media. Another kind of drug delivery system studied was solvent controlled type, being the drug immobilized in the hydrogel,. The hydrogels prepared by radiation polymerization of acryloyl-L-propine methylester (A-Pro-OMe) with 10 Gy dose, showed thermosensible property, swelling or shrinking in water with decreased or increased temperatures. The hydrogels were obtained with different crosslink density, trimethylolpropane trimethacrylate, and the monomers N, N-dimethyl acrylamide (DMAA) and 2-cyanoethyl acrylate to study the influence of the composition in the drug delivery rate. It was verified that the porous size besides being a characteristic of the matrix composition, it was also temperature dependent (thermosensible). The analgesic drug acetaminophen was immobilized by entrapment and by physical adsorption into the hydrogels matrices for 'in vitro' study. The insulin was immobilized by adsorption for 'in vivo' study. (author)

  13. Radiochromic film use to record dose profile variations in chest CT scan; Utilizacao do filme radiocromico para registro da variacao do perfil de dose em varredura de TC de torax

    Energy Technology Data Exchange (ETDEWEB)

    Mourao, Arnaldo P.; Santana, Priscila C., E-mail: aprata@des.cefetmg.br [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Departamento de Engenharia Nuclear; Silva, Teogenes A. da; Alonso, Thessa C. [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)

    2015-12-15

    The CT scans generate higher doses in patients than those caused by other types of diagnostic radiology using the attenuation of X-ray beams. Technological advances have increased the clinical applications of computed tomography (CT) and consequently the demand for these exams. Dose reduction strategies are difficult to implement because of a lack of proper guidance on the CT scanning. However, CT offers the possibility of adjusting the image acquisition parameters according to the patient physical profile and the diagnostic application for which it is intended to scan. Knowledge of the dose distribution is important when thinking about varying the acquisition parameters to reduce the dose. In this work was used a PMMA chest phantom to observe the dose deposition in 5 areas. Radiochromic film strips were placed inside the chest phantom, in peripheral and in the central region. The phantom was placed in the scanner isocenter and it was performed the irradiation of its central region using a chest acquisition protocol. After the phantom CT scan the radiochromic film strips were processed for obtaining digital images. Digital images were reworked to obtain the dose variation profiles for each position. The results showed a wide variation in absorbed dose by the phantom, either within a same position along the length of the film strip, as in the comparison among the five regions which the strips are placed. In this second case the dose variations were even greater. (author)

  14. Elimination of the induced malfunctions and use of dynamic prognosis in a thermodynamic diagnosis system of the thermal cycling; Eliminacao das malfuncoes induzidas e utilizacao do prognostico dinamico em sistemas de diagnostico termodinamico de ciclos termicos

    Energy Technology Data Exchange (ETDEWEB)

    Silva, J.A.M.; Venturini, O.J.; Lora, E.E.S. [Universidade Federal de Itajuba (NEST/IEM/UNIFEI), MG (Brazil). Inst. de Engenharia Mecanica. Nucleo de Excelencia em Geracao Termeletrica e Distribuida], Emails: juliomendes@unifei.edu.br, osvaldo@unifei.edu.br, electo@unifei.edu.br

    2009-07-01

    The search for more efficient thermal cycles has led a growing complexity of these cycles and therefore increased the inter-relationships between the thermodynamic components. This complexity is further enhanced with the over time, due to the occurrence of both natural as early degradation in a more or less degree, of all plant components. Several methodologies have been proposed for creating system for diagnostic / prognostic with the objective to detect these degradations (defects) and quantify the gain that can be obtained in the performance indicators of thermal cycles (usually specific fuel consumption and power net) by the elimination of anomalies. Two points have been emphasized as the most difficult in the development of such systems: the distinction between the performance variation of the components due only to the point of operation outside of these project components, caused by the presence of abnormality in another component (induced malfunction) and a decrease in the performance due to the presence of anomalies in the component itself (intrinsic malfunction). The second difficulty is the quantification of the effects induced by the elimination of each of the present anomalies. This work makes use of the method of reconciliation and using individual models of each component to predict unusual behavior of the same design point. The comparison of data from the system plant information, relating to the current state and data from the models, is used to detect anomalies. The methodology is explained in detail and an application of it in a Rankine cycle is used to well understand, especially in parts for the elimination of induced malfunctions, and related to the induced changes by the elimination of each one of the anomalies.

  15. Analysis of the possibility of use of a pump powered by solar energy supply of water in micro sprinklers; Analise da possibilidade de utilizacao de uma motobomba acionada por energia solar na alimentacao de agua em micro aspersores

    Energy Technology Data Exchange (ETDEWEB)

    Oyama, Paulo Takashi; Schutz, Fabiana Costa de Araujo; Jousseph, Carlos Alberto C.; Grosbelli, Andressa; Gnoatto, Estor; Kavanagh, Edward [Universidade Tecnologica Federal do Paran (UTFPR), Medianeira, PR (Brazil)], e-mail: paulooyama@gmail.com

    2011-07-01

    Due to the high cost of connecting electricity in distant places of conventional networks, solar photovoltaic energy is widely used in street lighting, water pumping, health clinics, etc.. To contribute to a better use of such energy, the project aimed to analyze the water-flow, power and electric current of a motor powered by two Solarex solar module manufacturer, model MSX 56, standard voltage of 12V, the current standard of 3.35A and 56W of potency using a pump, Shurflo Ltd manufacturer, model 2088-732, a pressure transducer model HUBA-510, a flow transducer for pumping water. The analysis for the height of 18.2 mca, corresponding height to 178.554 kPa, showed a flow rate of 365.308 L/h. Based on the results obtained in the laboratory, it was concluded that: the emitter Rain Bird QN-14, showed FVC nearly of 0.7%, ranking it as good, the emitter flow rates were in line with those presented in the catalog manufacturer, in the pressure range from 100 to 200 kPa, its effective radius was limited between 1.00 and 3.00 m away from the emitter, the profile of three-dimensional distribution of precipitation and isohyetal were quite irregular, which makes it possible the use of irrigation equipment in small areas. (author)

  16. Analysis of performance of protection systems with utilization of EMPT program. A practical case: differential protection in Itaipu line; Analise de desempenho de sistemas de protecao com utilizacao do programa EMTP. Um caso pratico: protecao diferencial de linha da Itaipu

    Energy Technology Data Exchange (ETDEWEB)

    Fonseca, C.S.; Carvalho Junior, D.S.; Villas, J.E.T. [Marte Engenharia Ltda. (Brazil); Frontin, S.O.; Teme, P.P.; Ordacgi Filho, J.M. [Itaipu Binacional (Brazil)

    1991-12-31

    This work presents the model used in the differential protection system program (EMTP) for the existing 500 kV, 60 Hz Itaipu lines. It also describes the logics of scanning, comparison and reset display. It also shows results of the Itaipu 500 kV system disturbance simulations and comparison with analogic computer analysis considering the interaction of the same elements which compose the differential protection. 3 refs., 9 figs., 1 tab.

  17. Removal of ammonia generated from farm poultry and their use in the fuel cells and as fertilizer; Remocao de amonia gerada em granjas avicolas e sua utilizacao em celulas a combustivel e uso como fertilizante

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Joao Coutinho

    2010-07-01

    The process here stressed uses a cation exchange material. The aim of the present work has been to prepare a suitable cation exchanger material with especially high selectivity for ammonia, as the cation NH{sub 4+} or as aqueous ammonia solution containing NH{sub 4}OH hydroxide as well. Aliquots of the above mentioned exchangers were set up inside an chicken farm production near Sao Paulo city. Periodically the exchanger was removed to the laboratory and eluted with a convenient acid to regenerate the exchanger for the new cycle. The ammonia retention was quite high and presents no difficulty for its elution. The selected exchanger is a solid material, non toxic, without smell and have good physical properties. The first results encouraged us and our plants to do large experiments that in progress. This process is a contribution to remediation of the avicola local, removing the ammonia gas and suppressing greatly its smell and bad effect to the animals and even to workers. (author)

  18. Evaluation of the use of waste of soybeans (Glycine max (L.)) combined with wood waste in making briquet; Avaliacao da utilizacao de residuo de soja (Glycine max (L.)) combinado com residuo de madeira de confeccao de briquetes

    Energy Technology Data Exchange (ETDEWEB)

    Travessini, Rosana; Schutz, Fabiana Costa de Araujo; Anami, Marcelo Hidemassa; Scherpinski, Neusa Idick [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil)], Emails: rosana_travessini@yahoo.com.br, fabianaschutz@gmail.com, mhanami@gmail.com, neusascherpinski@gmail.com

    2010-07-01

    The agricultural industry produces a large amount of which use biomass is an alternative energy economically viable through the compression portion of ligno-cellulose as raw material to replace the wood with an equivalent product, by briquetting. This study aimed to evaluate the technical feasibility of manufacturing fuel briquettes made from soybean residues combined with waste wood. The making of briquettes was performed in the laboratory of Electromechanics of UTFPR campus Medianeira PR. For this analysis, we assessed the content of moisture, ash, fixed carbon content of porosity and higher calorific value. From the results we can conclude that the manufacture of briquettes from lignocellulosic raw materials is an extremely viable energy flashlight for the region of the Bacia do Rio Parana III. (author)

  19. Thermal activation and characterization of clay aiming their use as sorbent in fixed bed columns to remove cadmium; Ativacao termica e caracterizacao da argila visando sua utilizacao como adsorvente em colunas de leito fixo para a remocao de cadmio

    Energy Technology Data Exchange (ETDEWEB)

    Silva, M.M. da; Rodrigues, M.G.F. [Universidade Federal de Campina Grande (UFCG), PB (Brazil); Silva, M.L.P. [Universidade Federal Rural do Semi-Arido (UFERSA), RN (Brazil); Kleinübing, S.J.; Silva, M.G.C., E-mail: marciliomaximo@yahoo.com.br [Universidade Estadual de Campinas (UNICAMP), SP (Brazil)

    2011-07-01

    In this work we studied the removal of cadmium in a synthetic wastewater using clay of Pernambuco - Brazil, in systems of fixed bed column. Clay was thermally activated at 500 °C. The materials were characterized using X-ray Fluorescence (XRF), X-ray Diffraction (XRD) and nitrogen adsorption (BET method). For tests in fixed bed column, we applied a factorial design 2{sup 2} and found that increasing the flow adversely affects the process of removing cadmium concentration while acting positively. The studies showed these materials as promising for the removal of Cd{sup 2+} ions in synthetic wastewater containing low levels of this metal. (author)

  20. Assessing the safety aspects for use of multilayer pipes in gas distribution of domestic installation; Avaliacao dos aspectos de seguranca para utilizacao de tubos multicamada em instalacoes de distribuicao de gas em residencias

    Energy Technology Data Exchange (ETDEWEB)

    Bratfisch, Carlos do Amaral Coutinho [Bratfisch - Engenharia em Gas, Sao Paulo, SP (Brazil); Emmeti, Sao Paulo, SP (Brazil); Collela, Ricardo [FGS Brasil Industria e Comercio Ltda., Cotia, SP (Brazil)

    2012-07-01

    The gas distribution networks average flow at the Brazilian market is low and the operating pressure is less than 2.0 kgf/cm{sup 2}. These values are lower if compared to other countries and due this, gas distribution companies, major builders and developers have started a movement to find alternatives to reduce their installation costs, and they have identified in other countries the multilayer system. Because of the great interest of the consumer market for this alternative, and since there is no standards in Brazil that could regulate it, a technical committee was established under the ABNT in order to prepare a standard draft meeting the local market particularities as well this technology requirements. Then it was initiated a quest looking for the knowledge of the 'state of the art' of this technology in various locations around the world, especially Europe, Asia and Oceania, which shows that, with few exceptions, the knowledge of this alternative is still on the beginning, and even in countries where this system is a pioneer some doubts exist with respect to their usage limit. The multilayer system materials were already used at hot and cold water networks for more than twelve years, but only after that it was made an adaptation for building installations of gas distribution networks. Due the need to search and establish safety criteria both with respect to the product as its installation shape, did the necessary motivation to perform a more detailed study of this new technology, meeting the needs of this market. The intention is to present to the consumer market a series of comparative data definitions and techniques to identify this as a modern, updated, economic, efficient and safe alternative option for gas distribution networks. (author)

  1. Utilization of computational simulator for comparison of correlations in multiphase flow in ESP (Electrical Submersible Pumping) systems; Utilizacao de simulador computacional para a comparacao das correlacoes de escoamento multifasico em sistemas BCS

    Energy Technology Data Exchange (ETDEWEB)

    Anjos, Roselaine M. dos; Maitelli, Carla Wilza S.P.; Maitelli, Andre L. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil); Costa, Rutacio O. [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil)

    2012-07-01

    Electrical Submersible Pumping (ESP) is an artificial lifting method which can be used both onshore and offshore for the production of high flow rates of liquid. By using the computational simulator for systems ESP developed by the AUTOPOC/LAUT - UFRN, this work aimed to evaluate empirical correlations for calculation of multiphase flow in tubing typical of artificial lifting systems operating by ESP. The parameters used for evaluating the correlations are some of the dynamic variables of the system such as head that indicates the lifting capacity of the system, the flow rate of fluid in the pump and the discharge pressure at the pump. Five (5) correlations were evaluated, from which only one considered slipping between phases, but does not take into account flow patterns and, four others considering slipping between the phases as well the flow patterns. The simulation results obtained for all these correlations were compared to results from a commercial computational simulator, extensively used in the oil industry. For both simulators, input values and simulation time, were virtually the same. The results showed that the simulator used in this work showed satisfactory performance, since no significant differences from those obtained with the commercial simulator. (author)

  2. Utilization of bromeliad Tillandsia Usneoides L. in biomonitoring of air pollution in the metropolitan region of Sao Paulo - SP, Brazil; Utilizacao da bromelia Tillandsia Usneoides L. no biomonitoramento da poluicao atmosferica na Regiao metropolitana de Sao Paulo - SP, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Albuquerque, Caroline R.; Figueiredo, Ana M.G.; Silva, Barbara C. da; Ticianelli, Regina B., E-mail: calbuuquerque@gmail.com, E-mail: anamaria@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Figueira, Rubens C.L., E-mail: aportellar@yahoo.com.br [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Instituto Oceanografico; Nievola, Catarina C.; Alves, Edenise S.; Domingos, Marisa, E-mail: ccnievola@uol.com.br, E-mail: ealves@ibot.sp.gov.br, E-mail: mmingos@superig.com.br [Instituto de Botanica (IBt-SMA/SP), Sao Paulo, SP (Brazil); Ribeiro, Andreza P., E-mail: andrezp@uninove.br [Universidade Nove de Julho (UNINOVE), Sao Paulo, SP (Brazil)

    2013-07-01

    In this study, it was determined the metals Cd, Cu, Fe, Mo, Ni, Pb and Sb in plant Tillandsia Usneoides L., an epiphyte species popularly known as old beard and able to absorb water and nutrients directly from air, aiming to estimate the contribution of human activities in atmospheric metal pollution in the metropolitan region of Sao Paulo. The samples were collected at five different points, located near the South West and stretches of highway Mario Covas (SP-21). The Neutron Activation Analysis (NAA) and Optical Emission Spectrometry with Inductively Coupled Plasma (ICP-OES) were the analytical techniques used in the quantification of metals of interest.

  3. Distribution and utilization of nitrogenated compounds explanted by the soybean nodules by plants during seeds developing; Distribuicao e utilizacao dos compostos nitrogenados exportados pelos nodulos de soja em plantas em fase de enchimento de graos

    Energy Technology Data Exchange (ETDEWEB)

    Alencar, Severino Matias de [Universidade Federal Rural do Rio de Janeiro, RJ (Brazil). Dept. de Solos; Neves, Maria Cristina Prata; Rumjaneck, Norma Gouvea [Empresa Brasileira de Pesquisa Agropecuaria, Seropedica, RJ (Brazil). E-mail: agrob@cnps.embrapa.br

    1997-07-01

    An experiment was carried out, using radioisotopes, for evaluation of the leaf, schuck and seeds areas and, examination of the pattern which is used by the nitrogenated compounds explanted by the soybean nodules.

  4. The problem of the use the hybrid and photovoltaic systems in insular zones with climatic siversity in Madeira; A problematica da utilizacao de sistemas fotovoltaicos e hibridos em zonas insulares de diversidade climatica-ILHA da Madeira

    Energy Technology Data Exchange (ETDEWEB)

    Magro, J. C. E.

    2004-07-01

    Project PAUER contemplates the evaluation and utilization of renewable energy in insular zones with climatic diversity, situated on the Archipelago of Madeira. The project has three main areas of intervention: prospecting and evaluating energetic resources; creation of data bases of climatic data for application in energetic studies and other areas; the installation of twenty autonomous photovoltaic or hybrid systems in isolated localities. This communication presents some data from meteorological observations made up until the present date, following appropriate statistical analysis. Characteristics of some installed photovoltaic and hybrid systems as well as some of the principal problems encountered in the field are also given. (Author)

  5. Development of virtual anthropomorphism of head mathematical model for using in dosimetry computerized simulation; Desenvolvimento de modelo matematico antropomorfico virtual de cabeca para utilizacao em simulacao computacional de dosimetria

    Energy Technology Data Exchange (ETDEWEB)

    Cassola, V.F.; Hoff, G.; Streck, E.E. [Pontificia Univ. Catolica do Rio Grande do Sul, Porto Alegre, RS (Brazil). Faculdade de Fisica. Grupo de Experimentacao e Simulacao Computacional em Fisica (GESiC)]. E-mail: ghoff@pucrs.br

    2004-07-01

    This paper shows the development of a virtual anthropomorphous model of head, considering different tissue composition, based in Nuclear Magnetic Resonance (NMR) images. The head original images were acquired in an equipment of NMR GE Sigma Horizon LX 1.5 T Echo Speed, available in the clinic of diagnosis for image SIDI. These images were segmented using routines developed in C++ language. The generated model is a group of 124 matrices of sequential data in format ASCII, where 26 indices evidence different structures. (author)

  6. Implementation and testing of the use of vegetable oils as fuel diesel generators in the Amazon isolated communities; Implantacao e testes de utilizacao de oleo vegetal como combustivel para diesel geradores em comunidades isoladas da Amazonia

    Energy Technology Data Exchange (ETDEWEB)

    Coelho, Suani Teixeira; Silva, Orlando Cristiano da; Gonzalez Velaquez, Silvia Maria Stortini; Monteiro, Maria Beatriz C.A.; Silotto, Carlos Eduardo Grassi [Centro Nacional de Referencia em Biomassa (CENBIO), Sao Paulo, SP (Brazil)

    2004-07-01

    The project PROVEGAM 'Implantation and test of a unit demonstration of energetic utilization of vegetable oil', tested in operational conditions of field, the functioning of a conventional diesel engine, adapted to operate with palm oil 'in natura' in the community of Vila Soledade, city of Moju, Para State. The Vila Soledade is an isolated community that has, approximately, 700 inhabitants and it's located at one hundred kilometers from the city hall by car and more 30 minutes by boat. The electric energy of this community was previously generated, by a conventional diesel engine, obsolete and very expensive to the community, because the fuel price and the transport of the diesel oil from the city to the community. The PROVEGAM project, installed an electric generation group, MWM TD229, manufactured in Brazil, adapted with a conversion kit to operate with 'in natura' palm oil, working 6 hours per day. Because of the viscosity of the palm oil and its combustion point, it was necessary to heat the vegetable oil before its injection into the engine. The operation begins and finishes with diesel oil, in order to heat the palm oil and to clean possible residues deposited in the interior of the engine. The use of the palm oil justifies itself for being produced in the region, which means that it doesn't have to be imported. Currently, the generating group is working in the community during 5 hours per day with palm oil, and 1 hour per day with diesel oil and it already has more than 1600 hours of testing. The results of this project, so far, have confirmed the conceived premises, and this electric model of generating energy is already recommended to be implemented in other communities in the Amazon region. (author)

  7. The use of neutron diffraction for the determination of the in-depth residual stresses profile in weld coatings; A utilizacao da difracao de neutroes na determinacao do perfil de tensoes residuais em revestimentos por soldadura

    Energy Technology Data Exchange (ETDEWEB)

    Marques, Maria Jose; Batista, A.C.; Nobre, J.P. [Universidade de Coimbra (Portugal). Dept. de Fisica. Centro de Estudos de Materiais por Difraccao de Raios X (CEMDRX); Loureiro, Altino [Universidade de Coimbra (Portugal). Dept. de Engenharia Mecanica. Centro de Engenharia Mecanica (CEMUC); Kornmeier, Joana R., E-mail: mjvaz@fe.up.pt [Technische Universitaet Muenchen, Garching (Germany). FRM II

    2013-04-15

    The neutron diffraction is a non-destructive technique, particularly suitable for the analysis of residual stress fields in welds. The technique is used in this article to study ferritic samples, coated by submerged arc welding using stainless steel filler metals. This procedure is often used for manufacturing process equipment for chemical and nuclear industries, for ease of implementation and economic reasons. The main disadvantage of that processes is the cracking phenomenon that often occurs at the interface between the base material and coatings, which can be minimized by performing post-weld stress relief heat treatments. The samples analyzed in this study were made of carbon steel plates, coated by submerged arc welding two types of stainless steel filler metals. For the first layer was used one EN 12 072 - S 2 U 23 12 electrode, while for the second and third layers were used an EN 12 072 - 19 12 3 S L electrode. After cladding, the samples were submitted to a post-weld heat treatment for 1 hour at 620 deg C. The residual stress profiles obtained by neutron diffraction evidence the relaxation of residual stress given by the heat treatment. (author)

  8. Construction and characterization in vitro of a bicistronic retroviral vector coding endostatin and interleukin-2 for use in gene therapy; Construcao e caracterizacao in vitro de um vetor retroviral bicistronico codificando endostatina e interleucina-2 para utilizacao em terapia genica

    Energy Technology Data Exchange (ETDEWEB)

    Calvo, Fernanda Bernardes

    2009-07-01

    Gene therapy has been used in preclinical studies and clinical trials in order to alleviate or cure a disease. Retroviral vectors are a tool for gene transfer is widely used. Bicistronic vectors are an attractive alternative for treatment of complex diseases. A variety of options exists to simultaneously express two genes in genetically modified cells. The most common approach relies on bicistronic vectors in which the genes are linked to each other by an internal ribosome entry site allowing co-translational expression of both cistrons. Endostatin, the C-terminal fragment of collagen XVIII, is a potent angiogenesis inhibitor. At present, ES has been widely used in anti-angiogenic in a variety of experimental tumor models, and clinical trials to test it as an anti-tumor agent are already under way. Immunotherapy has been used as adjuvant treatment for tumors and has been used in several preclinical studies and clinical trials. The objective of this project was to construct and characterize 'in vitro' an IRES-based bicistronic retroviral vector encoding endostatin and interleukin-2. The construction of the vector was performed in three stages, the final construction was analyzed by restriction analysis and sequencing. Packaging cells were prepared. The endostatin and interleukin-2 levels were determined by Dot blot. Monocistronic and bicistronic mRNA expression were analyzed by real time RT-PCR. Bicistronic vector showed high levels of virus trites, ranging from 4.20x10{sup 5} to 1.53x10{sup 6}UFC/ml. Secreted levels of endostatin and interleukin-2 ranged from 1.08 to 2.08{mu}g/10{sup 6}cells.24h and 0.66 - 0.89{mu}g/10{sup 6}cells.24h, respectively. The mRNA expression of ES in the NIH3T3 clone pLend-IRES-IL2SN was 2 times higher than the level presented by the NIH3T3 clone pLendSN. The endostatin promoted inhibition (40%) of endothelial cell proliferation. Interleukin-2 promoted a proliferation of 10.6% lymphocytes CD4 and 8.9% of CD8. We conclude that the IRES bicistronic vector provides a powerful tool for studies of cell biology of cancer and new therapeutic strategies. (author)

  9. Study and characterization of dosimeter LiF:Mg,Cu,P for using in aeronautical dosimetry; Estudo e caracterizacao do dosimetro de LiF:Mg,Cu,P para utilizacao em dosimetria aeronautica

    Energy Technology Data Exchange (ETDEWEB)

    Flavia, Hanna, E-mail: hannasantana.f@gmail.com [Universidade Paulista (UNIP), Sao Jose dos Campos, SP (Brazil); Federico, Claudio; Lelis, Odair; Pereira, Heloisa; Pereira, Marlon, E-mail: claudiofederico@ieav.cta.br [Instituto de Estudos Avancados (EFA-A/IEAV), Sao Jose dos Campos, SP (Brazil). Div. de Fisica Aplicada

    2014-07-01

    The effects of cosmic ionizing radiation incidents in aircraft components and crews has been a source of concern and motivated increasingly studies and improvements in the area. The low dose rates involved in this radiation field in aircraft flight altitudes imply Dosimetric necessity of using materials with high efficiency of detection, to enable studies lower cumulative doses resulting in shorter routes or lower altitude. The choice of thermoluminescent dosimeters LiF: Mg, Cu, P was done by having a detection efficiency of about fifteen times higher than its predecessor (LiF: Mg, Ti), and therefore, applied in very low doses dosimetry, and environmental dosimetry . The implementation of the use of pair dosimetric TLD-600H and 700H-TLD will serve as support for testing and studies on the effects of low doses of cosmic radiation in environmental dosimetry applied in the aviation environment in the usual flight altitudes. In this paper are presented the results of development of a methodology for dosimetry low doses of gamma radiation and neutrons using the pair dosimetric TLD-600H and 700H-TLD. The results demonstrate a sensitivity of dosimeters well above the dosimeters LiF: Mg, Ti confirming its suitability for dosimetry of low doses.

  10. Use of the 3DVH Software as a complementary method of IMRT pretreatment evaluation; Utilizacao do Software 3DVH como metodo complementar de avaliacao de pre-tratamento de IMRT

    Energy Technology Data Exchange (ETDEWEB)

    Lyra, Jesse G.P.; Bruning, Fabio F.; Funchal, Melissa; Toledo, Hugo V.; Bornatto, Pricila; Fernandes, Tatiane C.O., E-mail: jesse_lyra@hotmail.com [Hospital Erasto Gaertner / Liga Paranaense de Combate ao Cancer (LPCC), Departamento de Radioterapia, Curitiba, PR (Brazil)

    2013-04-15

    The aim of this study is to compare the method of treatment planning evaluation for IMRT using the gamma index to the method of the 3DVH Software. The 3DVH Software was used with the MapCheck2 detector 2D array under a 6MV x-ray beam of linear accelerator equipped with 120 leafs MLC. Nine treatment plans of prostate patients chose randomly and fully anonimatize were performed in the Eclipse planning system, using the AAA calculation algorithm in IMRT sliding window technique. These plans were approved and treated according to the gamma analysis criteria of the institution. The comparisons were made in absolute dose and normalized at maximum dose for each field and then with the 3DVH Software the Dmax, Dmean, D15%, D25%, D35% and D50% parameters for the bladder and rectum, Dmean for the bulb, Dmax for the femur and D95% for the PTV were evaluated. In the planar analysis by field, the plans studied had a minimum of 97.5% approval. The PTV-related differences have relative variation from 1.3 to 2.2%, that is, greater coverage than expected for this structure. For the organs at risk, the relative differences observed were between -5.3 to 25.8%, which could result in a non-approved plan if these variations are close to the clinical tolerances of the OAR. The results show that even a plan compatible with greater than or equal to 95% of the points, the gamma analysis does not give enough information if this plan can or cannot be approved for treatment and that there is a need for more detailed verification of the plan which considers not only the planar evaluation, but also the evaluation of the DVH measured, and the 3DVH Software proved be adequate for this analysis. (author)

  11. Use of residues proceeding from marbles and granites finishing and manufacturing processes as raw material for structural ceramic; Utilizacao do residuo proveniente do acabamento e manufatura de marmores e granitos como materia-prima em ceramica vermelha

    Energy Technology Data Exchange (ETDEWEB)

    Mello, Roberta Monteiro de

    2006-07-01

    In order to decrease environmental impact, caused by mud discarding and clay extraction in the ceramic industry, it was used residual mud from marble and granite companies for structural ceramic. Samples were collected in twelve different marble companies located at the metropolitan region of Sao Paulo. However, only four samples were selected, based on its different characteristics. Clay stone was the raw material chosen to prepare the structural ceramic, considering its high use in this segment. Samples and clay stone were both analysed by the following procedures: granulometric analysis, x-rays fluorescent chemical analysis and x-rays diffraction mineralogical analysis, besides, tests in the samples were conducted following NBR 10004 standards. Once raw materials were characterized, the plasticity test was conducted. Test specimen were molded with different levels of mud, then burned and submitted to technological tests, such as: mechanical resistance, water absorption, porosity, specific gravity and retraction, material dilation before burning process and scanning electron microscopy. The final results have shown the viability of using this kind of mud, and pointed some advantages on its usage, but taking in consideration some previous conditions to be adopted. (author)

  12. Using of Itaipu hydroelectric power plant-Brazil-electric power surplus for ammonia synthesis in nitrogen fertilizers production; Utilizacao da energia junto a Usina Hidreletrica de Itaipu para a sintese de amonia para fertilizantes nitrogenados

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Samuel Nelson Melegari de [Universidade Estadual do Oeste do Parana (UNIOESTE), Cascavel, PR (Brazil)]. E-mail: ssouza@unioeste.br; Silva, Ennio Peres da [Universidade Estadual de Campinas, SP (Brazil). Inst. de Fisica. Lab. de Hidrogenio

    2000-07-01

    Secondary energy can be described as a surplus of electrical energy in a hydropower because the lower demand of energy in some period of the day and the excess of water in the reservoir during the rainy periods. This study proposes the using of the excess of energy at Itaipu Bi nacional for electrolytically hydrogen production and ammonia for nitrogenous fertilizers. Ammonia is a raw material for nitrogenous fertilizers synthesis and produced using hydrogen and nitrogen from the atmosphere. This paper determines the minimal cost of hydrogen production and the capacity of hydrogen production, with this data and according the ammonia market for nitrogenous fertilizers in the Centre/South region was estimated the better capacity of ammonia production for one plant near Itaipu. The process of ammonia production using energy excess is the most environmental acceptable. (author)

  13. The use of glycerol in PET chemical recycling with the prospect of the polymeric membranes production; Utilizacao de glicerol na reciclagem quimica de PET visando a producao de membranas polimericas cationicas

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Agne R. de; Consentino, Vinicius M.; Muniz, Aline S.; Sakae, George H.; Oliveira, Angelo R.S.; Cesar-Oliveira, Maria Aparecida F. [Universidade Federal do Parana - UFPR, Centro Politecnico, Curitiba, PR (Brazil)], e-mail: mafco@ufpr.br

    2011-07-01

    The recent interest in alternative sources of renewable energy of unlimited duration and with a low environmental impact, has led to a rise in the use and production of biodiesel. This requires an increase in the availability of glycerine in the market. This involves a study of new applications to increase the consumption of this raw material which can be linked to solving a serious environmental problem - the unsuitable disposal of post-consumption PET packages. Parallel to this, combustible cell technology is proving to have promising results, particularly in the area which uses polymeric electrolytes. The polymeric proton exchange membrane is currently most widely used in Nafion. However, this entails very high costs. By bringing together these important requirements in the energy sector, this study demonstrates how the development of aromatic sulfonate polyesters obtained from the chemical recycling of poly(ethylene terephthalate) with an aromatic derivative of glycerol. (author)

  14. Use of geographic information system in the analysis of distribution of cetaceans in Parana Coast/Utilizacao de sistema de informacao geografica na analise da distribuicao de cetaceos na Costa Paranaense

    National Research Council Canada - National Science Library

    Barros, Ana Carolina Vizintim Fernandes; Barros, Mirian Vizintim Fernandes

    2012-01-01

    .... The storage, handling and analysis of these data can be performed by the Geographic Information System--GIS, which is an important tool because allows it the manipulation of large volumes of data and...

  15. Utilization of carbon steel with one per cent of chromium in water injection wells equipment in oil fields; Utilizacao de aco carbono com 1 por cento de cromo em equipamentos de pocos de injecao de agua em campos de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Coutinho, A.; Barbosa, B. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Exploracao e Producao; Joia, C.; Andrade, C. [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas; Silva, Julio M. [Vallourec e Mannesmann do Brasil, Rio de Janeiro, RJ (Brazil)

    2000-07-01

    In order to produce oil in some oil reservoirs of Campos Fields, water has to be injected in the reservoir just to keep the pressure and not to decrease the production rate. Water injection wells are used and carbon steel is the material that it is widely used due to its lower price. Water treatment has therefore to be carried out in off-shore platforms to maintain corrosion rates controlled. Dissolved oxygen content is the most important variable specified. It has to be kept below 10 ppb to allow the specified equipment, pipeline and tubing life to be reached. In this work the effect of 1% Cr addition to the chemical composition of carbon steel to the corrosion rate is evaluated, as well as the effects of oxygen content, the temperature and the speed flow. (author)

  16. Ways to use and building solar heating with reusable materials in rural and urban low-income communities; Formas de utilizacao e construcao de aquecedores solares com materiais reaproveitaveis em comunidades rurais e urbana de baixa renda

    Energy Technology Data Exchange (ETDEWEB)

    Gabriel Filho, Luis Roberto Almeida; Putti, Fernando Ferrari [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Tupa, SP (Brazil); Seraphim, Odivaldo Jose [Universidade Estadual Paulista Julio de Mesquita Filho (FCA/UNESP), Botucatu, SP (Brazil). Fac. de Ciencias Agronomicas; Cremasco, Camila Pires [Universidade Estadual Paulista Julio de Mesquita Filho (FCA/UNESP), Botucatu, SP (Brazil); Faculdade de Tecnologia (FATEC), Presidente Prudente, SP (Brazil); Caneppele, Fernando de Lima [Universidade de Sao Paulo (FZEA/USP), SP (Brazil). Fac. de Zootecnia e Engenharia de Alimentos; Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Itapeva, SP (Brazil)

    2012-11-01

    The search for cleaner energy sources, gave rise to the solar heaters, which are the most widely used systems in energy savings for heating water, but due to its high investment cost, this device becomes inaccessible to low-income communities. Noting the demand for low cost system for these communities, the project aimed to promote the scientific dissemination in academia and the population to build solar heaters composed of recyclable packaging such as milk cartons and bottles pet. and due to large populations still residing in rural areas, this becomes feasible, because it is a small-scale system and easy construction and because of this facility may be disseminated among the neighbouring owners, and can be used for domestic use, as well as in rural utensils hygiene. For the realization of the project, the prototypes were developed in the interior of the Sao Paulo cities and rural properties. The courses will aim the dissemination and the methods to be carried out the construction of the systems and the end was carried out a questionnaire, which sought to verify the effective deployment and construction in residential properties. From the present study seeks to start a deployment of these types of systems at State level, and aims to create public policies for the promotion of their actual deployment in all cities in the State from this project. (author)

  17. Feasibility analysis of the use of sugar cane bagasse ash as mineral addition to cementitious mortars; Analise da viabilidade de utilizacao da cinza do bagaco de cana-de-acucar como adicao mineral em argamassas cimenticias

    Energy Technology Data Exchange (ETDEWEB)

    Fazzan, J.V.; Pereira, A.M.; Moraes, M.J.B. de; Akasaki, J.L.; Sanches, A.O.; Malmonge, J. A., E-mail: jvfazzan@hotmail.com [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Ilha Solteira, SP (Brazil). Faculdade de Engenharia. Departamento de Fisica e Quimica

    2014-07-01

    Currently, Brazil is experiencing an expansion of sugarcane plantations, which makes the country the world's largest producer of sugarcane. With the bagasse generated during the process, is generated the bagasse ash cane sugar (CBC) which consists mainly of silicon dioxide (SiO{sub 2}) and presents as potential alternative raw material for the production of cement composites. In this context, the objective of this study is to evaluate the reactivity of the CBC through physical and chemical analysis, for the production of mortars. The study of the CBC was performed by means of XRF testing, XRD, SEM and ADL. Mortar specimens with different percentages of CBC in partial replacement of Portland cement, for analysis of compressive strength were also produced. Despite the mixtures with additions have lower resistance to conventional mortars, the results showed the potential of the CBC as reactive mineral addition. (author)

  18. Bee waxes: a model of characterization for using as base simulator tissue in teletherapy with photons; Ceras de abelha: um modelo de caracterizacao para sua utilizacao como tecido simulador base em teleterapia com fotons

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Rogerio Matias Vidal da; Souza, Divanizia do Nascimento

    2011-10-26

    This paper presents a model of characterization and selection of bee waxes which makes possible to certify the usage viability of that base simulator tissue in the manufacture of appropriated objects for external radiotherapy with mega volt photon beams. The work was divide into three stages, where was evaluated physical and chemical properties besides the aspects related to the capacity of beam attenuation. All the process was carefully accompanied related to the wax origin such as the bee specimen and the flora surrounding the beehives. The chemical composition of the waxes is similar to others simulators usually used in radiotherapy. The behavior of mass attenuation coefficient in the radiotherapeutic energy range is comparable to other simulators, and consequently to the soft tissue. The proposed model is efficient and allows the affirmative that the usage of determined bee wax as base simulator tissue is convenient

  19. Project, construction and characterization of ionization chambers for use as standard systems in X and gamma radiation beams; Projeto, construcao e caracterizacao de camaras de ionizacao para utilizacao como sistemas padroes em feixes de radiacao X e gama

    Energy Technology Data Exchange (ETDEWEB)

    Perini, Ana Paula

    2013-07-01

    Ionization chambers present some advantages in relation to other dosimeters: easiness of handling, low energy dependence and high precision. The advantages associated to ionization chambers and the large number of diagnostic radiology exams and therapeutic treatments motivated the development of this PhD program. In this project ionization chambers were developed and characterized to be applied in diagnostic radiology and therapy beam dosimetry, with high precision and performance, in compliance with international recommendations. They were assembled in a simple way, utilizing low-cost national materials, so they can be reproduced and applied at calibration laboratories. The project of these ionization chambers presents some differences in relation to commercial ionization chambers, as the materials utilized and geometrical arrangements. Besides the development of the ionization chambers to be utilized in standard X-ray beam dosimetry as work standard systems, two graphite parallel-plate ionization chambers were developed and characterized to be applied as reference standard systems for determining the air kerma rates of gamma radiation sources. Comparing the air kerma rates determined with the reference standard of the Calibration Laboratory of IPEN, a Farmer ionization chamber, with the values of the air kerma rates obtained with the graphite ionization chambers, the maximum differences obtained were only 1.7% and 1.2% for the G1 and G2 graphite ionization chambers, respectively. Moreover, these ionization chambers presented correction factors close to 1.000, which is ideal for an ionization chamber be characterized as a reference standard system. (author)

  20. The use of genetic algorithms with niching methods in nuclear reactor related problems; A utilizacao dos metodos de nichos dos algoritmos geneticos na otimizacao de problemas de reatores nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Sacco, Wagner Figueiredo

    2000-03-01

    Genetic Algorithms (GAs) are biologically motivated adaptive systems which have been used, with good results, in function optimization. However, traditional GAs rapidly push an artificial population toward convergence. That is, all individuals in the population soon become nearly identical. Niching Methods allow genetic algorithms to maintain a population of diverse individuals. GAs that incorporate these methods are capable of locating multiple, optimal solutions within a single population. The purpose of this study is to test existing niching techniques and two methods introduced herein, bearing in mind their eventual application in nuclear reactor related problems, specially the nuclear reactor core reload one, which has multiple solutions. Tests are performed using widely known test functions and their results show that the new methods are quite promising, specially in real world problems like the nuclear reactor core reload. (author)

  1. The use of lichens as bioindicators of atmospheric contamination by natural radionuclides and metals in a region impacted by TENORM; Utilizacao de liquens como bioindicadores de contaminacao atmosferica por radionuclideos naturais e metais em regiao impactada por TENORM

    Energy Technology Data Exchange (ETDEWEB)

    Leonardo, Lucio

    2010-07-01

    The main aim of this thesis is to study the possibility of using lichen as bioindicator of atmospheric pollution in regions contaminated by radionuclides, metals and rare earth elements. Two regions were chosen, one in Pirapora do Bom Jesus, where a tin and lead industry is located, and a second one in Cubatao, where a phosphate fertilizer industrial complex is located. The two industries chosen are considered as TENORM - Technologically Enhanced Naturally Occurring Radioactive Material, since they can cause a significant increase in the natural radionuclides concentration in the industrial process, and consequently a potential increase in the radiation exposure in products, byproducts and residue. To achieve this aim, the radionuclides {sup 238}U, {sup 226}Ra, {sup 210}Pb, {sup 2'}3{sup 2}Th and {sup 228}Ra, rare earth elements and metals were analyzed in samples of raw material and residues from the installations, lichens and soils. Lichens and soil samples were analyzed by instrumental neutron activation analysis for the determination of uranium, thorium, rare earth elements and metals. The radionuclides {sup 226}Ra, {sup 228}Ra and {sup 2}'1{sup 0}Pb in soil samples were determined by gamma spectrometry and in lichen sample by radiochemical separation and gross alpha and beta counting on a gas flow proportional counter. The concentrations of {sup 238}U (from 19 to 473 Bq kg{sup -1}), {sup 226}Ra (from 21 to 265 Bq kg{sup -1}), {sup 210}Pb (from 401 to 1461 Bq kg{sup -1}), {sup 232}Th (from 15 to 574 Bq kg{sup -1}), {sup 228}Ra (from 176 to 535 Bq kg'-{sup 1}), rare earth elements, Hf and Ta determined in lichen samples around the tin and lead industry show an enrichment in these elements. Therefore, the lichens can be used as a fingerprint of the atmospheric contamination. The results obtained for the lichen samples, in the Cubatao region, present a fingerprint mainly of {sup 210}Pb, from industries of the region. The results obtained in this study showed that the lichens can be used as bioindicators of atmospheric pollution by radionuclides and trace elements. (author)

  2. Evaluation of natural radioactivity in some granitic rocks in the state of Parana, Brazil and its use in civil construction; Avaliacao da radioatividade natural em algumas rochas graniticas do estado do Parana e sua utilizacao na construcao civil

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Ademar de Oliveira

    2013-07-01

    Primordial, or terrestrial natural radionuclides, are found in different amounts in the environment. In dwellings, an important dose increment is due to building materials, which contribute for both the external gamma dose from the radionuclides of the {sup 238}U, {sup 235}U and {sup 232}Th series and the natural {sup 40}K and the internal dose, due mainly to {sup 222}Rn inhalation. Once granitic rocks are widely used both as construction materials or structural flooring, those rocks can become an important dose source, depending on the content of concentrations of radioactivity, and the construction application. In this work, a database for granitic rocks of the crystalline shield of Parana (mainly in the Metropolitan Region of Curitiba, RMC), used in civil construction, was generated, evaluating in terms of radiological protection the external and internal dose increments, caused by the use of these materials. Also, possible correlations between the {sup 226}Ra activity concentration, the {sup 222}Rn exhalation rate, density, porosity and chemical composition (oxide content) in these samples had been studied. The external dose was assessed by gamma-ray spectrometry with High-Purity Germanium detectors, where the activity concentration of the radionuclides {sup 232}Th, {sup 226}Ra and {sup 40}K are the parameters used in dosimetric models (Dosimetric Indexes), which established limits in accordance with the form, amount and application of material of construction. For the calculation of the annual effective external dose it was assumed a room model with dimensions of 4 m x 5 m x 2:8 m and all walls internally covered with 2 cm thickness of granite and an annual exposure time of 7000 h as suggested by the European Commission of Radiological Protection for internal superficial coating materials. The internal exposure was assessed from the radon concentration in the air of the room model, simulated from the superficial exhalation rate of {sup 222}Rn. The exhalation rate was determined by the passive detection technique with the Solid State Nuclear Track Detectors (CR-39) and the sealed can technique, assuming a ventilation rate of 0.5 h{sup -1} and an annual exposure time of 7000 h. The results for this studies show that the annual effective dose ranged from (62 {+-} 3) {mu}Sv.y{sup 1} to (138 {+-} 1) {mu}Sv.y{sup -1} and the internal annual effective dose ranged from (0,39 {+-} 0,04) {mu}Sv.y{sup -1} to (70 {+-} 4) {mu}Sv.y{sup -1}. These values are below the maximum limit of 1 mSv.y{sup -1} suggested by the European Commission of Radiological Protection, meaning that the granitic rocks evaluated can be used without radiological implications since the considered scenario is obeyed. The values obtained for the contribution due to the internal dose ranged from 1 % to 78 % of the values obtained for the respective external dose showing the radon contribution varies strongly with the rock type. The results of the correlations between {sup 222}Rn superficial exhalation rate, {sup 226}Ra activity concentration, density, porosity and major oxides of the samples, showed that, in terms of influence in the emanation fraction of radon, the most important parameter is the density, due to low porosity and similarity in terms of chemical composition amid the studied samples. (author)

  3. Utilization of ALANPOL dosemeter composed by alanine and polyethylene for determination of doses in industrial effluents; Utilizacao do dosimetro ALANPOL composto por alanina e polietileno para determinacao de doses em efluentes industriais

    Energy Technology Data Exchange (ETDEWEB)

    Rela, Carolina S.; Sampa, Maria Helena de O.; Napolitano, Celia M. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)]. E-mail: csrela@ipen.br; Pontuschka, Walter M. [Sao Paulo Univ., SP (Brazil). Inst. de Fisica

    2005-07-01

    A study of traceability and accuracy was performed with the dosimetry system ALANPOL developed by IVHTJ/ Poland that uses alanine as a dosimeter and EPR as the read out system. The dosimeter ALANPOL is a polymer compound that aggregates alanine. The dosimeter has the outside diameter 3 mm, and the length of 25,4 mm (1 inch). In order to use this dosimeter for monitoring the existing real time calorimetry dosimeter system set up in a electron beam waste treatment plant. Electron beam and gamma irradiation experiments with ALANPOL was carried out under demineralized water and industrial effluent. The result show that in the dose range of 1-40 kGy the ALANPOL dosimeter system is suitable underwater monitoring for absorbed dose and can be applied for the evaluation of the on line calorimetry dosimeter system. (author)

  4. Uncertainties associated to the using of alanine/EPR for the dose interval in the radiotherapy; Incertezas associadas na utilizacao da alanina/RPE para o intervalo de dose da radioterapia

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues Junior, O.; Campos, L. L. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2004-07-01

    The High Doses Laboratory of IPEN is developing a dosimetric system for high doses based on Electron Paramagnetic Resonance (EPR) of free radical radiation induced on alanine. The objective of this work is to present the efforts towards to improve the measure accuracy for doses in the range between 1-10 Gy. This system could be used as reference by radiotherapy services, as much in the quality control of the equipment, as for routine accompaniment of more complex handling where the total doses can reach some grays. The main problem for routine implantation is the calibration and the traceability of the system and many errors sources affects the accuracy of the measurements. In this work are discussed same aspects related on the uncertainty evaluation associated with high dose measurement using alanine and EPR. (author)

  5. Technological characterization of clays from the city of Anapolis. Goias, Brazil, for the usage in ceramic products; Caracterizacao tecnologica de argilas do municipio de Anapolis, Goias, Brasil, para a utilizacao em produtos ceramicos

    Energy Technology Data Exchange (ETDEWEB)

    Chrispim, Z.M.P.; Alves, M.G.; Ramos, I.S.; Silva, A.L.; Fraga, F.A., E-mail: lezira@ig.com.b [Universidade Estadual do Norte Fluminense Darcy Ribeiro (LECIV/CCT/UENF), Campos dos Goytacazes, RJ (Brazil). Engenharia Civil; Almeida, L.L.P. de [Universidade Estadual do Norte Fluminense Darcy Ribeiro (LAMAV/CCT/UENF), Campos dos Goytacazes, RJ (Brazil). Lab. de Materiais Avancados

    2010-07-01

    The city of Annapolis is located 48 kilometers from the capital, Goiania, in Goias Center Mesorregion, which forms part of the Annapolis-Brasilia-Goiania axis, with an economy focused on manufacturing industry, pharmaceuticals, ceramics, wholesale and automobile industry, having a population of 335, 960 inhabitants (IBGE, 2009). The objective of this work is the physical and mineralogical characterization of three samples of clay of that region. The clays were characterized by granulometry determining distribution, Atterberg limits, chemical composition, X-ray diffraction and differential thermal analysis and thermogravimetry. Samples (cps) were obtained by extrusion and fired at 750 deg, 950 deg and 1050 deg C. After the burning process it was determined the water absorption, bending rupture's modulus. The analyzed results show the physical and mineralogical composition of raw materials and concluded that this characterization allows to estimate that the three samples are appropriate or not for the production of ceramic products.(author)

  6. Synthesis and characterization of polyaniline/clay conducting nanocomposites for use in protective coatings; Sintese e caracterizacao de nanocompositos condutores de polianilina/argila para utilizacao em revestimentos protetores

    Energy Technology Data Exchange (ETDEWEB)

    Baldissera, A.F.; Ferreira, C.A.; Senisse, C.A.L.; Oliveira, L.S., E-mail: alebaldissera@hotmail.co [Universidade Federal do Rio Grande do Sul (LAPOL/UFRGS), Porto Alegre, RS (Brazil). Lab. de Materiais Polimericos

    2010-07-01

    Nanomaterials have been shown highly promising materials for various technological applications. In engineering, may be noted the polymer nanocomposites, which are a new class of composite materials, where a nanoclay, or charge with nanometric dimensions, is dispersed in a polymer matrix at low concentration or volume. The clays are more common and when added in quantities less than 5% in the nanocomposites, cause a significant increase in these properties, such as mechanical, optical, magnetic barrier, and especially permeability and flammability. In this context, this work aimed at obtaining the polymeric nanocomposites of polyaniline (PAni) with different commercial clays (cloisite Na{sup +}, 10A and 30B). The preparation of PAni-MMT nanocomposites was performed by in situ polymerization of aniline in acidic (HCl). Electrical conductivity measurements, infrared spectroscopy and X-ray diffraction were some of the techniques used to characterize the nanocomposites. (author)

  7. Application of low density from pig in subsea satellite well flow line; Utilizacao de pig-espuma de baixa densidade em linhas de producao de pocos-satelites submersos

    Energy Technology Data Exchange (ETDEWEB)

    Lima, Paulo Cesar Ribeiro; Couto, Nilton Castro; Souza, Robson Oliveira [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas. Divisao de Explotacao

    1995-01-01

    This work describes a new concept of pigging using low density form to prevent/removal of wax in subsea satellite well flowline. The methodology of wax control is world pioneer. The pigs are sent through a 2.5 in lift gas line, and through a wet x-mas tree, not designed to be pigged, and back through the flowline. (author) 2 refs., 1 fig.

  8. Present status of the photovoltaic solar energy using, and the work of the LABSOLAR in this area; Panorama atual da utilizacao da energia solar fotovoltaica e o trabalho do Labsolar nesta area

    Energy Technology Data Exchange (ETDEWEB)

    Ruether, Ricardo [Santa Catarina Univ., Florianopolis, SC (Brazil). Dept. de Engenharia Mecanica. Lab. de Energia Solar (LABSOLAR)]. E-mail: ruther@mbox1.ufsc.br

    2000-07-01

    The new technologies of photovoltaic solar panels are described, presenting lower costs when compared to the c-Si. Due to the short time costs reduction potential present the technology as economically feasible for electric power generation alternative in a near future.

  9. Using of gas for water heating at buildings - study on technical and economical viability; Utilizacao de gas para aquecimento de agua em instalacoes prediais - estudo de viabilidade tecnica e economica

    Energy Technology Data Exchange (ETDEWEB)

    Fossa, Alberto Jose [MDJ Assessoria e Engenharia Consultiva, Santo Amaro, SP (Brazil)]. E-mail: afossa@mdj.com.br; Chaguri, Jose Jorge [Caltherm Sistemas de Aquecimento, Sao Paulo, SP (Brazil)]. E-mail: jchaguri@caltherm.com.br; Santos, Edmilson Moutinho dos [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Eletrotecnica e Energia]. E-mail: edsantos@iee.usp.br

    2006-07-01

    The recent discovery of significant Brazilian's natural gas reserves has been opened a discussion concerning public procedures in order to incentive development of gas industry thru delivery of this energetic to the end consumer. Concerning this figure, a significant quantity of uses has been questioned related economical viability. This paper comes to analyze the possibility to change electrical energy for natural gas on heating water systems used on residential installations. Concerns about economical impact of alternative adopted on locals where public regulations are been established to incentive natural gas end uses. (author)

  10. History matching of oil fields using 4D seismic and saturation map; Utilizacao de sismica 4D e de mapas de saturacao no ajuste de historico de reservatorios petroliferos

    Energy Technology Data Exchange (ETDEWEB)

    Risso, Valmir Francisco; Schiozer, Denis Jose [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Faculdade de Engenharia Mecanica. Dept. de Engenharia de Petroleo], e-mails: valmir@dep.fem.unicamp.br; denis@dep.fem.unicamp.br

    2008-03-15

    The main objective of history matching is to improve numerical models of oil fields by incorporating observed data, production and pressure, into the characterization process, in order to obtain more reliable production forecasting. This technique presents some limitations mainly in the beginning of the development of oil fields, when less information is available and higher uncertainties are present. With seismic 4D, it is possible to obtain saturation maps allowing the improvement of the numerical model yielding a more reliable production forecasting. The objective of this work is to develop a methodology to improve the numerical model through the incorporation of the saturation maps in the process of history matching. (author)

  11. Using of seismic as external drift in the calculation of oil volume in petroleum reservoir; Utilizacao da sismica como deriva externa no calculo do volume de oleo de um reservatorio de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Gomes, Joao Paulo Borges; Sancevero, Sergio Sacani; Remacre, Armando Zaupa [Universidade Estadual de Campinas, SP (Brazil). Inst. de Geofisica]. E-mail: joao.gomes@ige.unicamp.br; sacani@ige.unicamp.br; armando@ige.unicamp.br

    2003-07-01

    Because the detail needed to develop reservoirs exceeds the detail required to find them, the petroleum industry increase the use of 3-D seismic data. The use of this data as external drift was the solution finds to make the integration between seismic and well data. Using geostatistical techniques of sequential simulation, the objective of this paper is show the differences when use complement information to obtain the oil volume of petroleum reservoir. The geostatistical simulation was used to quantify the relationship between well data and double travel time data from seismic in the inter well locations. We generate 100 images of the top and 100 images of the bottom, resulting in two risk curves for the oil volume. These curves were comparing and then the influence of the utilization of additional information can be realized. (author)

  12. The usage of ceramics in the manufacture of the lining of temperature sensors for the oil industry; Utilizacao de ceramica para encapsulamento de sensores de temperatura na industria petrolifera

    Energy Technology Data Exchange (ETDEWEB)

    Domingues, R.O.; Yadava, Y.P.; Sanguinetti Ferreira, R.A., E-mail: rebeka.oliveira@yahoo.com.br, E-mail: yadava@ufpe.br, E-mail: ricardo.sanguinetti@pq.cnpq.br [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Departamento de Engenharia Mecanica

    2014-07-01

    In the oil production, many types of sensors are used in order to monitor some important parameters such as temperature, pressure and flow. These sensors are subjected to harsh operating conditions. Therefore they must present an inert and stable behavior in these conditions. The temperature sensors that are more suited to the oil industry are the Temperature Detectors by Resistance (TDR), because they have high accuracy and wide temperature range. Usually these devices are built with metals as detectors of temperature by encapsulated resistance in inert ceramics. The main objective of this research is to produce new ceramics of a Ca{sub 2}AlZrO{sub 5,5} cubic complex perovskite structure for the encapsulation of temperature sensors. The stoichiometric amounts of the constituent chemicals, with a high degree of purity, are homogenized, through a solid state reaction in a high energy ball mill. They are then compacted by uniaxial pressing and calcined at 1200°C for 24 hours. Soon after, the tablet is crushed giving place to a ceramic powder and the analysis of X-ray diffraction is performed. According to the sintering behavior of the ceramic powder, the microstructure and the homogeneity are studied by the Scanning Electron Microscopy. The results are presented in terms of the potential of this ceramic for applications as components of temperature sensors. (author)

  13. Use of the photo-Fenton process in degradation of the gasoline of refinery in water way; Utilizacao do processo foto-Fenton na degradacao da gasolina de refinaria em meio aquoso

    Energy Technology Data Exchange (ETDEWEB)

    Mota, Andre Luis N.; Silva, Douglas N. [Rio Grande do Norte Univ., Natal, RN (Brazil). Dept. de Engenharia Quimica. Programa de Recursos Humanos da ANP para o Setor Petroleo e Gas, PRH-ANP-14; Chiavone-Filho, Osvaldo [Universidade Federal do Rio Grande do Norte, Natal, RN (Brazil). Dept. de Engenharia Quimica]. E-mail: osvaldo@eq.ufrn.br; Moraes, Jose Ermirio F.; Nascimento, Claudio A.O. [Universidade de Sao Paulo, SP (Brazil). Dept. de Engenharia Quimica]. E-mail: jefm@lscp.pgi.eq.usp.br

    2003-07-01

    This work focus in the photo-Fenton process (combination between Fe{sup 2+}, H{sub 2}O{sub 2} and UV-visible light) for the degradation of the refinery gasoline (without alcohol and additives) in aqueous phase. This process represents a powerful alternative for the degradation of organic substances contained in wastewaters, because it generates more biodegradable products or even it results in the complete mineralization of the pollutant. The study of the degradation of the refinery gasoline using the process photo-Fenton has as short term goal the treatment of wastewater polluted with that type of pollutant, and as long term goal serving as study-base for the application of that process in the degradation of the oil contained in the water produced in fields of petroleum. The experiments of photo degradation of aqueous solutions containing refinery gasoline were accomplished using a falling films solar reactor. The influences of the following parameters were analyzed: the concentration of hydrogen peroxide (100 - 200 mM), the concentration of ions iron (0,5 - 1 mM) and the concentration of chloride of sodium (200 - 2000 ppm). (author)

  14. Using of capacitors for improving the electric power quality in the low voltage circuits; Utilizacao de capacitores para melhoria da qualidade de energia eletrica nos circuitos de baixa tensao

    Energy Technology Data Exchange (ETDEWEB)

    Fassheber Junior, Carlos Frederico [Centrais Eletricas de Santa Catarina (CELESC), Florianopolis, SC (Brazil)]. E-mail: cffassheber@celesc.com.br

    2000-07-01

    The paper discuss the application of a bank of low voltage capacitors which can provide reduction in the loading of the low voltage circuits and in the transformers, more regulation of the voltage, improvement in the power factor, besides the fact of they are natural harmonic filters.

  15. Sustainable alternative for use of waste from pruning deriving from power distribution networks maintenance; Alternativa sustentavel para utilizacao de residuos de poda provenientes da manutencao das redes de distribuicao de energia eletrica

    Energy Technology Data Exchange (ETDEWEB)

    Cortez, Cristiane Lima; Grisoli, Renata; Gavioli, Fabio; Coelho, Suani Teixeira [Centro Nacional de Referencia em Biomassa (CENBIO), Sao Paulo, SP (Brazil)], email: cenbio@iee.usp.br; Carmelo, Silma [AES Eletropaulo, Sao Paulo, SP (Brazil)], email: silma.carmelo@aes.com

    2008-07-01

    In the context of the environmental issue, the increasing production of solid residues seems to be a problem due to scarcity of methods and solutions for the management. This article presents a project that has as objective to make a survey of the impacts caused by urban pruning residues generated by the electric energy concessionaire AES Eletropaulo, besides developing a method to standardize this residues composting. The obtained results refer to the observation that 50% of the cities that participated on the survey discard the residues in dumps or sanitary landfills, while only 8% perform composting. In the experimental composting plant built, the organic compound obtained reached satisfactory levels of quality with related to the specifications of minimum quality, but showed that humidity should be better controlled. The feasibility of implementing a composting plant was established, with the exception that the higher the production, the better the return on initial investment. Based in the concepts of environmental and social responsibility, we expect that the conclusion of this work can assist the civil, public and private sectors to contribute with the sustainable development. (author)

  16. Use of ZnO:Mn particles for degradation of methylene blue by photocatalysis process; Utilizacao de particulas de ZnO:Mn para a degradacao do azul de metileno por processo de fotocatalise

    Energy Technology Data Exchange (ETDEWEB)

    Giraldi, T. R.; Swerts, J. P.; Vicente, M. A., E-mail: tania.giraldi@unifal-mg.edu.br, E-mail: jefersonps21@hotmail.com, E-mail: maquelyaspr@oi.com.br [Universidade Federal de Alfenas (UNIFAL), Pocos de Caldas, MG (Brazil). Instituto de Ciencia e Tecnologia; Mendonca, V.R. de, E-mail: vrm@ifsp.edu.br [Instituto Federal de Educacao, Ciencia e Tecnologia de Sao Paulo (IFSP), Itapetininga, SP (Brazil); Paris, E.C.; Ribeiro, C., E-mail: elaine.paris@embrapa.br, E-mail: caue.ribeiro@embrapa.br [Embrapa Instrumentacao, Sao Carlos, SP (Brazil)

    2016-10-15

    The management of water use in the agricultural environment is a key factor to build new environmentally sustainable productive methods. Photocatalysis is a promising method for water decontamination. This research paper aimed to evaluate the photocatalytic potential of pure and Mn-doped ZnO particles. The materials were obtained by the polymeric precursor method, and characterized by X-ray diffraction, N{sub 2} adsorption in low temperature, infrared and ultraviolet spectroscopy, and photoluminescence. In order to evaluate ZnO:Mn particles photo efficiency, experiments were carried out by applying the methylene blue dye solution to photodegradation under UVC exposure. The particles had ZnO single-phase, but low specific surface area. The sample ZnO:0.25% Mn presented higher efficiency in the methylene blue photocatalytic degradation test. This efficiency was related to a higher band gap energy value and a lower rate of electron recombination, which allows greater formation of hydroxyl radicals, which are responsible for dye degradation. (author)

  17. Evaluation of Cortaderia selloana (Capim-dos-pampas) blankets as sorbent materials for oil spills in simulated hydro equipment; Estudo do desempenho de tecidos e mantas para utilizacao como sorventes para petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Bonetti, T.F.; Sydenstricker, T.H.D. [Universidade Federal do Parana (UFPR), Curitiba, PR (Brazil)], e-mail: thais@demec.ufpr.br; Amico, S.C. [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil)

    2006-07-01

    Oil spills in aquatic environments may cause serious economy losses and severe environmental impact which both drive the development of commercial systems (e.g. sorbents) to control these accidents. One way of using sorbents is to encapsulate them with an involucre or cover, i.e. producing blankets. The focus of this research is to evaluate the key characteristics of interest (aerial density, water and oil sorption, mechanical strength and cost) of different materials to use as covers for blankets and to prepare blankets and compare their performance when made with various core materials, such as Cortaderia selloana fibers and different commercial sorbents. A simulated aqueous body with stream was used for the sorption experiments, where the oil and water phases were circulated and forced to pass under the blankets. On the sorption tests, the fibers of Cortaderia selloana reached a performance lower to that of commercial sorbents, mainly due to their low density and high volume (difficult packing), nevertheless a clear trend was noted, heavier blankets with higher sorption periods lead to higher sorption. (author)

  18. The utilization of the technetium-99m in the pathologies diagnosis and dysfunctions of the human organism; A utilizacao do elemento Tecnecio-99m no diagnostico de patologias e disfuncoes dos seres vivos

    Energy Technology Data Exchange (ETDEWEB)

    Araujo, Elaine Bortoleti de, E-mail: ebaraujo@net.ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Div. de Pesquisa e Desenvolvimento de Radiofarmacos

    2005-07-15

    Radiopharmaceuticals are radioactive compounds used in the diagnostic and treatment of pathologies and dysfunctions of the human organism. A variety of radioisotopes can be employed in the preparation of radiopharmaceuticals, among which technetium-99m ({sup 99m}Tc), which presents ideal physical characteristics for its application in diagnostic nuclear medicine. Once administered to the patient, the radiopharmaceutical is deposited in the target organ or tissue and suitable equipment can acquire images from the radiation emitted by the patient. It is a noninvasive process which allows anatomic, morphological and functional evaluations. {sup 99m}Tc is obtained from the radioactive decay of molybdenum-99 and can be made available in the hospital from {sup 99}Mo-{sup 99}Tc generators. {sup 99}mTc can bind to different substrates or ligands, by means of complexation reactions, originating radiopharmaceuticals with affinities for different organs, systems or receptors in the organism. Knowing {sup 99m}Tc coordination chemistry is extremely important for the development of these radiopharmaceuticals. (author)

  19. Utilization of urea micro dose with {sup 14} C in breath test to detect the Helicobacter pylori; Utilizacao de micro dose de ureia com {sup 14} C no teste respiratorio para diagnosticar a presenca de Helicobacter pylori

    Energy Technology Data Exchange (ETDEWEB)

    Chausson, Yvon [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN), Belo Horizonte, MG (Brazil); Coelho, Luiz Gonzaga V.; Passos, Maria do Carmo F.; Andrade, Angela A.M.; Simal, Carlos J.R.; Paula Castro, Luiz de [Minas Gerais Univ., Belo Horizonte, MG (Brazil). Hospital das Clinicas; Fernandes, M.L.; Yazaki, F.R. [Minas Gerais Univ., Belo Horizonte, MG (Brazil). Dept. de Estatistica

    1995-12-31

    A lower dose is used in the {sup 14} C-urea breath test to detect the Helicobacter pylori (Hp). Such dose produce trivial radiation doses. The results shown that the use of this desirable dose is possible. (author). 4 refs., 1 fig.

  20. Utilization of the BR-SIPP systems (Integrated Refinery Scheduling System) at the PETROBRAS Capuava refinery; Utilizacao do sistema BR-SIPP - Sistema Integrado de Programacao de Producao PETROBRAS na refinaria de Capuava

    Energy Technology Data Exchange (ETDEWEB)

    Joly, Marcel [PETROBRAS, Maua, SP (Brazil). Refinaria de Capuava (RECAP). Gerencia de Otimizacao]. E-mail: joly@petrobras.com.br; Hassimotto, Marcelo Kenji [PETROBRAS, Rio de Janeiro, RJ (Brazil). Gerencia de Solucoes de Negocios de Logistica e Planejamento]. E-mail: kenji@petrobras.com.br; Magalhaes, Marcus Vinicius de Oliveira [PETROBRAS, Rio de Janeiro, RJ (Brazil). Gerencia de Otimizacao]. E-mail: vinicius@petrobras.com.br

    2007-04-15

    The BR-SIPP is a production scheduling decision support tool for refineries. It is integrated into the Corporate Inventory, Movements and Quality Data Base and is based on events simulation technology for the elaboration and analysis of scheduling scenarios. Its utilization at the Capuava Refinery allows the production programming team to analyze and anticipate difficulties and opportunities, thereby being able to make viable a potential integration of management and people directly involved with the refinery scheduling information, such as planning, logistics and commercial areas. (author)

  1. The use of compressed natural gas as a strategy of development of natural gas industry; Utilizacao do GNC (Gas Natural Comprimido) como estrategia de desenvolvimento da industria do gas natural

    Energy Technology Data Exchange (ETDEWEB)

    Bock, Jucemara [Companhia de Gas do Estado do Rio Grande do Sul (Sulgas), Porto Alegre, RS (Brazil). Coordenacao de Segmento Veicular; Rickmann, Cristiano [Companhia de Gas do Estado do Rio Grande do Sul (Sulgas), Porto Alegre, RS (Brazil). Gerencia de Novos Negocios; Maestri, Juares [Companhia de Gas do Estado do Rio Grande do Sul (Sulgas), Porto Alegre, RS (Brazil). Gerencia de Mercado de Grandes Consumidores

    2008-07-01

    This work emphasizes the Compressed Natural Gas (CNG) as modal of transport, used by the Company of Gas of the State of Rio Grande do Sul - Sulgas, through experience in pioneering project in Brazil: the introduction of the technology of Compressed Natural Gas (CNG) to assist areas where there is not the infrastructure of pipeline for the transport. The article offers a display of the project of expansion of the Natural gas in Rio Grande do Sul, through the supply of CNG to the company Tramontina in Carlos Barbosa's city in the year of 2002. The last aspect focused by this article demonstrates as the use of this transport technology impelled the development of the transport market in the State and it has been used as an important strategy for the development of the market of Natural Gas Vehicle (NGV) in the state. (author)

  2. Utilization of diesel fuel, anhydrous ethanol and additives blend of a stationary diesel engine with rotatory pump; Utilizacao de mistura ternaria alcool, diesel e aditivo em motores do ciclo diesel com bomba de injecao rotativa

    Energy Technology Data Exchange (ETDEWEB)

    Reyes Cruz, Yordanka; Cavado Osorio, Alberto [Centro de Pesquisas de Petroleo (CEINPET), Havana (Cuba); Belchior, Carlos Rodrigues Pereira; Pereira, Pedro P.; Pinto, Nauberto Rodrigues [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Centro de Tecnologia. Dept. de Engenharia Naval e Mecanica; Aranda, Donato A. Gomes [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Escola de Quimica

    2008-07-01

    In this paper is analyzed the performance and fuel consumption of a stationary Diesel engine, with rotary diesel fuel injection pump, using (diesel fuel + anhydrous ethanol + 0.5% additive) blend. The engine performance parameters and fuel consumption tests were performed at the Termic Machine Laboratory, located in Federal University of Rio de Janeiro, and evaluated using a MWM Series 10 model 4.10 TCA. Two test cycles were used for this test program: the tests were carried out starting from the base diesel S-500, used as a reference; the engine operated with (diesel fuel S-500 - 8% anhydrous ethanol - DIOLEFECT additive (0,5% SPAN80 + 0,1% Biomix-D)) blend. The results indicate that: the reduction levels in power and torque of engine are approximately the same which is (2,55{+-}2%), the brake specific fuel consumption increased in 1,8%. (author)

  3. Use of natural gas on heavy duty vehicles in Brazil: experience, current scene and barriers that still persist; Utilizacao do gas natural em veiculos pesados no Brasil: experiencia, cenario atual e barreiras que ainda persistem

    Energy Technology Data Exchange (ETDEWEB)

    Machado, Guilherme B.; Melo, Tadeu C.C.; Lastres, Luiz Fernando M. [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES)

    2004-07-01

    In the 80's, because of the oil crisis, the Natural Gas (NG) appeared as a fuel with a great potential for Diesel replacement in Heavy Duty Vehicles. At that time, PETROBRAS with other companies have developed partial conversion technologies from Diesel to NG, known as 'Dual Fuel'. Engine dynamometer and vehicle bus tests have been developed to verify its technical and economical viability. Because of several factors, the Dual Fuel Program did not advance and the experience was interrupted. At the same time, other experiences using NG Otto Cycle bus engines, manufactured in Brazil, have been conducted, mainly at Sao Paulo, nevertheless, without expansion. Currently, factors as increase of the NG converted light vehicles fleet; the NG excess in the National Market, which has contributed to the NG distribution net expansion; the Environmental Legislature in vigor, that continuously determine lower emission limits; the government interest in increasing the NG energy matrix share and in reducing Diesel fuel consumption, and the low NG industrial demand, compose together a great scene to the diffusion of NG as substitute to the Diesel fuel in Heavy Duty Vehicles. (author)

  4. Using of residential load curves obtained for determination of the load diversity, and loading of distribution transformers; Utilizacao de curvas de carga de consumidores industriais medidas para determinacao de diversidade de carga, e carregamento de transformadores de distribuicao

    Energy Technology Data Exchange (ETDEWEB)

    Ferrari, Eduardo Luiz; Jardini, Jose Antonio

    1996-07-01

    This work presents some applications of the residential loads, obtained from measurements conducted by the electric power utilities in the state of Sao Paulo , Brazil. During the first application, curve of coincidence of load peaks occurrence, as function of the number of consumers simultaneously connected to a specific residential distribution transformer. This curve provides a information on the number of consumers presenting coincident load peaks coincident relative to the total numbers of consumers connected to the distribution transformer. Those curves allow to obtain the diversity curves. The second application focused the calculation of the distribution transformer life reduction.

  5. Development of DP (Dynamic Positioning) to pull-in sub sea pipelines; Utilizacao de barcos de manuseio de ancoras operando com DP (Dynamic Positioning) para arraste de dutos submarinos

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Manoel H.S. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil); Galgoul, Elton C. [Suporte Engenharia, Luziania, GO (Brazil)

    2004-07-01

    Sub sea pipeline construction at oil and gas fields, with high concentration of on-bottom facilities, becomes more difficult when mooring operations and pipeline approach to a congested platform have to be performed. One method that has often been applied in Brazil is the so-called 'DP (Dynamic Positioning) pull-in', where PETROBRAS owned pipelay Barge, BGL-1, is moored away from the congested area, while a DP anchor handler pulls the rigid pipeline from BGL-1 to a target near the platform. The method was conceived to avoid mooring operations near the congested platforms as well as to minimize risks due to the pipeline initiation process. Inside the congested area the initiation with aid of a 'dead-man' anchor on the sea bottom, which would be a more conventional solution, becomes impossible in most cases. This paper will discuss the engineering work required to perform the 'DP pull-in' as well as show the operational steps, from the start-up to the final abandonment of the pipeline initiation head inside the target area. (author)

  6. Utilizacao de residuos agroindustriais em processo biotecnologico para producao de ƒÒ-galactosidase de Kluyveromyces marxianus CCT 7082 = Use of agroindustrial residues in biotechnological process by betagalactosidase production from Kluyveromyces marxianus CCT 7082

    Directory of Open Access Journals (Sweden)

    Ana Paula Manera

    2011-04-01

    Full Text Available O objetivo deste trabalho foi avaliar a composicao do meio de cultura para a producao da enzima ƒÒ-galactosidase de Kluyveromyces marxianus CCT 7082 utilizando a tecnica de delineamento experimental. A producao da enzima foi realizada em meio composto por soro de queijo, agua de maceracao de milho (AMM e hidrolisado de levedura Prodex-lacR e sais. Foi realizado um planejamento experimental fracionario (25-1 para determinar as variaveis significativas na producao da enzima. Foram testadas diferentes concentracoes de lactose presente no soro de queijo (10 a 70 g L-1, AMM (10 a 100 g L-1, Prodex-lac (4 a 20 g L-1, (NH42SO4 (0 a 10 g L-1 e o pH (5 a 7. As variaveis concentracao de lactose, AMM e o pH apresentaram efeito estatisticamente significativo na atividade enzimatica dentro das faixas estudadas, sendo estas variaveis empregadas num delineamento composto central rotacional para otimizar a producao da enzima. As faixas testadas foram: concentracao de lactose de 40 a 100 g L-1, AMM de 10 a 120 g L-1 e pH de 3,5 a 6,5. As condicoes que resultaram em maior atividade enzimatica (1400 U g-1 foram 70 g L-1 de lactose, 65 g L-1 de AMM, 4 g L-1 de Prodex-lac e pH 5, obtendo uma produtividade de 61 U L-1 h-1. The objective of this work was to evaluate the composition of the culture medium for the production of the enzyme ƒÒ-galactosidase from Kluyveromyces marxianus CCT 7082 using an experimental design. Enzyme production was carried out in a medium consisting of cheese whey, cornsteep liquor (CSL and Prodex-lacR yeast hydrolyzate. A factorial fractional design (25-1 was performed to determine the significant variables in the production of the enzyme. Different concentrations of lactose present in whey (10-70 g L-1, CSL (10-100 g L-1, Prodex-lac (40- 20 g L-1, (NH42SO4 (0-10 g L-1 and pH (5-7 were tested. Lactose concentration, CSL and pH were the variables that showed a statistically significant effect on enzyme activity withinthe ranges studied, and these variables were used in a central composite rotatable design to optimize production of the enzyme. The ranges used were: lactose concentration 40-100 g L-1, CSL 10-120 g L-1, and pH 3.5-6.5. The conditions that resulted in higher enzyme activity (1400 U g-1 were 70 g L-1 lactose, 65 g L-1 CSL, 4 g L-1 Prodex-lac and pH 5, yielding 61 U L-1 h-1.

  7. Evaluation of the potential of waste processing of secondary kaolin of Para for use in porcelain; Avaliacao da potencialidade do residuo do beneficiamento secundario de caulim do Para para utilizacao em porcelanato

    Energy Technology Data Exchange (ETDEWEB)

    Junior, V.G.L.; Fernandes, L.L.; Fagury Neto, E.; Rabelo, A.A., E-mail: adrianoalves@ufpa.br [Universidade Federal do Para (UFPA), Maraba, PA (Brazil). Faculdade de Engenharia de Materiais. Lab. de Materiais Ceramicos

    2012-07-01

    The kaolin waste evaluated is characterized as secondary due be coming from the steps of centrifugation, magnetic separation, bleaching and filtering, which gives a ratio which provides a significant residue, about 26% of their gross, that is intended for embankments. This study aimed to evaluate the potential of reusing the kaolin waste processing from Imerys RCC in the region of Barcarena (PA) in formulation of ceramic bodies for porcelain tiles production, seeking to property of maximum water absorption of 0.5 % for this type of product. The residue from the production of kaolin had been previously characterized by X-ray diffraction and there is a significant amount of kaolinite concentration. After the ceramic processing to obtain the test specimens with different amounts of residue replacing the kaolin, these were sintered using 1200, 1220 and 1240 °C for 2 hours. The formulations were evaluated by water absorption, linear firing shrinkage and modulus of rupture at a three-point bending setup of the pieces produced. (author)

  8. Effects of LEDs on oral mucositis prevention in a patient with classic Hodgkin's lymphoma - a case report; Utilizacao de LEDs na prevencao de mucosite oral em paciente com linfoma de Hodgkin classico - estudo de caso

    Energy Technology Data Exchange (ETDEWEB)

    Bicudo, Leticia Lang

    2004-07-01

    The purpose of this case report was to evaluate the efficacy of therapy using LEDs (light-emitting diodes), at a wavelength of 880 nm, in the prevention of oral mucositis in a patient with Hodgkin's disease treated with ABVD regimen. Mucositis is a dose limiting complication of cancer treatment, of high incidence, which severity can lead to alterations of treatment planning or even to suspension of cancer therapy, with serious consequences in tumor response and even survival. Lesions develop most commonly on the nonkeratinized mucosa and present symptoms that begin like mild burning and evolve to severe pain. For this reason, low power laser and, recently, LEDs have been considered for preventing and management of oral mucositis, with great results. In this study, a 34-year-old male received intraoral irradiations with an infrared LEDs array (3,6 J/cm{sup 2}, 74 mW), for five consecutive days, starting on the day of chemotherapy. In each chemotherapy cycle, he received ABVD protocol on day 1 and day 15, and received LEDs treatment during five days on each ABVD infusion. To analyze results, the WHO (World Health Organization) scale was used for grading of mucositis and VAS (Visual Analogue Scale) for pain evaluation, on days 1, 3, 7, 10 and 13 post-chemotherapy. The results obtained showed the patient did not develop oral mucositis, during the five chemotherapy cycles and did not present any pain symptom. Therapy with LEDs was a safe and effective method for the prevention of oral mucositis in this case report. However, new studies are needed in order to prove the efficacy of this methodology with more patients, increasing their quality of life. (author)

  9. Comparative studies of utilization of industrial electron accelerators and adsorption with activated carbon for industrial effluent treatment; Estudo comparativo da utilizacao de aceleradores industriais de eletrons e adsorcao com carvao ativado para tratamento de efluentes industriais

    Energy Technology Data Exchange (ETDEWEB)

    Sampa, Maria Helena de O.; Rela, Paulo R.; Duarte, Celina Lopes; Las Casas, Alexandre; Mori, Manoel Nunes; Omi, Nelson M. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)]. E-mail: mhosampa@ipen.br

    2005-07-01

    A technical and economical feasibility study was performed comparing the use electron beam and activated charcoal for treatment of industrial wastewater. In this study was used synthetic solutions, prepared in laboratory with organic compounds standards, where the composition was focused on the critical organic contaminants usually presented in wastewater from petrochemical industry. For the sample irradiation was used an industrial electron beam from Radiation Dynamics Inc. 1.5 MeV - 37.5 kW setup in IPEN. The doses ranged from 5 kGy to 100 kGy. A common granulated activated charcoal in a fixed-bed absorber glass column was used to study the pollutants absorption performance. The results show that if the adequate irradiation dose was delivered to the organic pollutant, it is possible to conclude for the studied compounds that the Electron Beam Process is, in aspect of organic removal efficiency, similar to the activated carbon process. (author)

  10. Effect of synthesis method on the preparation of lanthanum chromite for using as ceramic pigment; Influencia do metodo de sintese na preparacao de cromita de lantanio para utilizacao como pigmento ceramico

    Energy Technology Data Exchange (ETDEWEB)

    Dantas, G.C.B.; Ferreira, K.M.B.; Pimentel, P.M., E-mail: gerbeson_dantas@hotmail.com [Universidade Federal Rural do Semi-Arido (UFERSA), Mossoro, RN (Brazil); Melo, D.M.A.; Gomes, D.K.S.; Costa, A.F. [Universidade Federal do Rio Grande do Norte (UFRN), RN (Brazil)

    2016-07-01

    In this paper, LaCrO3 perovskites were synthesized by two synthesis methods, in order to compare these methods in function of microstructure and optical properties. The synthesis routes employed were a method that use gelatin as organic precursor and microwave assisted auto-combustion. The resulting powders were calcined at 800 ° C and 1000 ° C for obtaining the perovskite phase. Then, they were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM); UV-Visible spectroscopy and colorimetric analysis for color identification. No significant changes were observed in the powders synthesized by two routes. The oxides presented orthorhombic perovskite structure. The powders synthesized by the gelatin method were single phase. Chromite lanthanide presented grayish hue being darker in perovskites calcined at higher temperatures. (author)

  11. A general vision of EGS4 and PENELOPE codes and perspectives of utilization in radiotherapy; Uma visao geral dos codigos EGS4 e PENELOPE e a possibilidade de utilizacao na radioterapia

    Energy Technology Data Exchange (ETDEWEB)

    Galhardo, Edvaldo P.; Nicolucci, Patricia [Sao Paulo Univ., Ribeirao Preto, SP (Brazil). Hospital das Clinicas. Dept. de Fisica e Matematica; Ghilardi Neto, Thomaz [Sao Paulo Univ., Ribeirao Preto, SP (Brazil). Hospital das Clinicas. Centro de Ciencias das Imagens]. E-mail: edvaldo@dfm.ffclrp.usp.br

    2001-07-01

    In Brazil, the lack of works in Radiotherapy simulations is huge and the perspectives are good. The works developed now in some research centers show the viability and the crescent interest of applications in this area. In this work a general vision of Monte Carlo method application is presented. A comparison of EGS4 and PENELOPE codes show their differences in applications and perspectives in Radiotherapy. (author)

  12. Using of X factor in the price cap regulation for stimulating investments on rural electrification; Utilizacao do fator X na regulacao por price-cap como forma de incentivar investimentos em eletrificacao rural

    Energy Technology Data Exchange (ETDEWEB)

    Guerra, Helvio Neves [Amazonas Univ., Manaus, AM (Brazil)]. E-mail: helvio_guerra@uol.com.br; Andrade, Cynthia Santos [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Mecanica. Area Interdisciplinar de Planejamento de Sistemas Energeticos]. E-mail: cynthia@fem.unicamp.br; Carbonari Neto, Emigdio [Companhia de Geracao de Energia Eletrica Paranapanema, SP (Brazil)]. E-mail: ocpg3@cgeep.com.br

    1999-07-01

    This work analyses the regulation by using price-cap as agent for improvements in the performance of electric power utilities, specifically the performance of the future utilities. This segment presents strong natural monopoly characteristics and proposes a methodology for the calculation of the X-Factor aiming the incentives of productivity and investments increasing compatible with development public policies. The paper also uses practical applications for demonstrating that the price-cap regulation can contribute for transference of part of the gains to the consumers.

  13. Study of the feasibility of the utilization of clays from Poco Fundo (MG) for its use in bricks fabrication; Estudo da viabilidade da utilizacao das argilas do municipio de Poco Fundo-MG na fabricacao de tijolos

    Energy Technology Data Exchange (ETDEWEB)

    Gaspar Junior, L.A., E-mail: lineo.gaspar@unifal-mg.edu.br [Universidade Federal de Alfenas (UNIFAL), MG (Brazil). Instituto de Ciencias da Natureza; Varejao, A.F.D.C. [Universidade Federal de Ouro Preto (UFOP), MG (Brazil); Souza, M.H.O. [Universidade Federal de Uberlandia (UFU), MG (Brazil); Moreno, M.M.T. [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), SP (Brazil)

    2012-07-01

    This work aimed to make an analysis of mineralogical (Macroscopic Description and X-Ray Diffraction), chemical (X-Ray Fluorescence and Organic Carbon Analysis) and ceramic (Particle Size Distribution, Mechanical Resistance, Water Absorption, Apparent Porosity, among others) properties of the alluvial clays collected in Poco Fundo county - Minas Gerais State, Brazil - in order to confirm the feasibility of these clays for bricks manufacturing. There were collected 4 samples from the main potteries of the county, and they were nominated PF-01, PF-02, PF-03 and MAC-01. The clays from these region display high content of quartz, kaolinite and present refractory behavior, and the alkalis content (Na{sub 2}O and K{sub 2}O) is low, because the studied area suffered an intense weathering process. The sample PF-03 presented the most promising ceramic results, mainly due to the lower content in silica and higher amounts of organic matter, denoting a clay coming from a swampy area. (author)

  14. Hybrid regression trees applied to the monitoring of dynamic safety of isolated networks with large eolic production contribution; Utilizacao de arvores de regressao hibridas na monitorizacao da seguranca dinamica de redes isoladas com grande producao eolica

    Energy Technology Data Exchange (ETDEWEB)

    Lopes, J.A Pecas; Vasconcelos, Maria Helena O.P. de [Instituto de Engenharia de Sistemas e Computadores (INESC), Porto (Portugal). E-mail: jpl@riff.fe.up.pt; hvasconcelos@inescn.pt

    1999-07-01

    This paper describes in a synthetic manner the technology adopted to define structures used in the fast evaluation of dynamic safety of isolated network with high level of eolic production contribution. This methodology uses hybrid regression trees, which allows the quantification the endurance connected to the dynamic behavior of these networks by emulating the frequency minimum deviation that will be experienced by the system when submitted toa pre-defined perturbation. Also, new procedures for data automatic generation are presented, which will be used for construction and measurements of the evaluation structures performance. The paper describes the Terceira island - Acores archipelago network study case.

  15. Analysis of the feasibility of solar heating systems composite for packaging recyclable for use in rural low income; Analise da viabilidade economica de sistemas de aquecedores solares compostos por embalagens reciclaveis para utilizacao em comunidades rurais de baixa renda

    Energy Technology Data Exchange (ETDEWEB)

    Gabriel Filho, Luis Roberto Almeida; Maiochi, Tamara; Pereira, Danilo F.; Magalhaes, Marcelo M. de [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Tupa, SP (Brazil)], email: gabrielfilho@tupa.unesp.br; Cremasco, Camila P. [Faculdade de Tecnologia (FATEC), Presidente Prudente, SP (Brazil); Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Botucatu, SP (Brazil). Dept. de Bioestatistica

    2011-07-01

    Solar heaters are an appropriate technology for tropical and sub tropical to warm bath water through the energy in sunlight. The development of conventional solar heaters is in the market and its acceptance is still low due to high cost. However, low-cost solar heaters have been developed in recent years to meet a consumer demand that currently do not have access to this technology, especially low-income rural communities. The aim of this study was to analyze the economic feasibility of solar water heaters built with recyclable materials (plastic bottles and milk cartons) through the consequent reduction of sales of electricity. For development work, a heater was built with recyclable materials in accordance with the manuals provided by the Department of the Environment of Parana (SEMA) and found time to use electric showers by families of rural properties in order to determine the costs and billing of electricity. By spending on materials, we concluded that the system was feasible, with amortization over 13 months in fixed installments of R$ 23.79. (author)

  16. Use of agroindustrial waste in the preparation of nanocomposites based on bacterial cellulose and hydroxyapatite; Utilizacao de residuos agroindustriais na elaboracao de bionanocompositos baseados em celulose bacteriana e hidroxiapatita

    Energy Technology Data Exchange (ETDEWEB)

    Duarte, Eden B.; Chagas, Bruna S. das; Feitosa, Judith P.A. [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil); Andrade, Fabia K.; Borges, Maria F.; Muniz, Celli R.; Souza Filho, Men de Sa M.; Rosa, Morsyleide F., E-mail: morsyleide.rosa@embrapa.br [Embrapa Agroindustria Tropical, Fortaleza, CE (Brazil); Brigida, Ana I. [Embrapa Agroindustria de Alimentos, Barra de Guaratiba, Rio de Janeiro, RJ (Brazil); Morais, Joao P.S. [Embrapa Algodao, Campina Grande, PB (Brazil)

    2013-07-01

    Environmental issues have supported the interest in renewable sources and agroindustrial residues became a significant resource for the production of new materials. The present work presents the use of agroindustrial residues to obtain bacterial cellulose (BC) for further elaboration of nanocomposites with hydroxyapatite (HA). The production of BC membranes occurred in Hestrin & Schramm medium, cashew juice and sisal liquid waste cultivated under static conditions. After the incubation period, the BC membranes were purified and nanocomposites prepared by successive immersion of the purified membranes in solutions of Calcium Chloride (CaCl{sub 2}), and Sodium Phosphate (Na{sub 2}HPO{sub 4}), followed by drying and subsequent characterization. The materials obtained were characterized by Thermogravimetric Analysis (TGA) and X-ray Diffraction (XRD). Additionally, in vitro tests were performed for nanocomposites. The results showed the production of cellulose from the three substrates studied, without the need for further supplementation or pH change. In all characterizations, structure and typical behavior of bacterial cellulose were found. The composites showed bioactivity and the adsorption capacity of proteins, which lead to potential biocompatibility of these materials. (author)

  17. A new method for intraoperative localization of epilepsy focus by means of a gamma probe; Um novo metodo para a localizacao intraoperatoria de foco de epilepsia mediante utilizacao de gamaprobe

    Energy Technology Data Exchange (ETDEWEB)

    Carneiro Filho, Omar, E-mail: dromarcarneiro@gmail.com [Centro Brasileiro de Medicina Nuclear e Imagem Molecular (CEBRAMEN), Goiania, GO (Brazil); Instituto de Medicina Nuclear, Goiania, GO (Brazil); Vilela Filho, Osvaldo [Universidade Federal de Goias (UFG), Goiania, GO (Brazil). Hospital das Clinicas. Servico de Neurocirurgia; Ragazzo, Paulo Cesar [Instituto de Neurologia de Goiania, GO (Brazil). Servico de Eplepsia e Neurofisiologia; Fonseca, Lea Mirian Barbosa da [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Dept. de Radiologia

    2014-01-15

    Objective: to evaluate the utility of a new multimodal image-guided intervention technique to detect epileptogenic areas with a gamma probe as compared with intraoperative electrocorticography. Materials and methods: two symptomatic patients with refractory epilepsy underwent magnetic resonance imaging, videoelectroencephalography, brain SPECT scan, neuropsychological evaluation and were submitted to gamma probe-assisted surgery. Results: in patient 1, maximum radioactive count was initially observed on the temporal gyrus at about 3.5 cm posteriorly to the tip of the left temporal lobe. After corticotomy, the gamma probe indicated maximum count at the head of the hippocampus, in agreement with the findings of intraoperative electrocorticography. In patient 2, maximum count was observed in the occipital region at the transition between the temporal and parietal lobes (right hemisphere). During the surgery, the area of epileptogenic activity mapped at electrocorticography was also delimited, demarcated, and compared with the gamma probe findings. After lesionectomy, new radioactive counts were performed both in the patients and on the surgical specimens (ex-vivo). Conclusion: the comparison between intraoperative electrocorticography and gamma probe-assisted surgery showed similarity of both methods. The advantages of gamma probe include: noninvasiveness, low cost and capacity to demonstrate decrease in the radioactive activity at the site of excision after lesionectomy. (author)

  18. Use of biogas generated from swine manure as preliminary agent in the feasibility construction of natural gas networks; Utilizacao do biogas gerado a partir de dejetos suinos como agente preliminar na viabilizacao da construcao de redes de gas natural

    Energy Technology Data Exchange (ETDEWEB)

    Machado, Antonio Rogerio; Ferraz, Andre; Rocha, Ivan; Azevedo, Jorge; Oshiro, Hugo K.; Konishi, Ricardo; Piazza, Walter; Lehmkuhl, Willian [Companhia de Gas de Santa Catarina (SCGAS), Florianopolis, SC (Brazil)

    2011-12-21

    Santa Catarina state has over 800 km of natural gas distributed along the coast line, however, has an area of 95.700 km{sup 2}. Due to mountainous relief, constructing pipeline that will supply natural gas to remote areas will prove difficult. Supplying gas to remote areas through biogas from pig manure is a feasible alternative to building a gas pipeline to these regions. Using data from the IBGE and by aid of computer programs it was found that Santa Catarina has a potential to generate biogas from 900.000 m{sup 3}/day which are located predominantly in the western region of state. Thus, through the provision of biogas in this region a market that uses natural gas as an energy source can stimulate. As result the pay-back time and the feasibility risk of a network gas project can be reduced. It was found that only in the west there is an energy potential to be shifted to natural gas equivalent of 389.583 m{sup 3}/day and as expected output is estimated to reach 16.728 m{sup 3}/day. This helps anticipate the building of a natural gas network that links the coast with outskirts of the state, while the environmental impact of swine as methane emissions and waste are reduced. (author)

  19. Use of the CoFe{sub 2}O{sub 4} ferrospinel as catalyst in the WGSR process; Utilizacao do ferroespinelio CoFe{sub 2}O{sub 4} como catalisador no processo de WGSR

    Energy Technology Data Exchange (ETDEWEB)

    Lima, M.S.; Dantas, J.; Costa, A.C.F.M., E-mail: joeldadantas@yahoo.com.br [Universidade Federal de Campina Grande (LabSMaC/UFCG), PB (Brazil). Departamento de Engenharia de Materiais. Laboratorio de Sintese de Materiais Ceramicos; Sazaki, J.M. [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil). Departamento de Fisica; Andrade, H.M.C. [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Departamento de Quimica Geral e Inorganica. Lab. de Catalise e Materiais

    2014-07-01

    This work investigates the use of ferrospinel CoFe{sub 2}O{sub 4} as a catalyst in water gas shift reactions (WGSR). The ferrospinel was synthesized by combustion reaction using the following heating conditions: ceramic base, resistive muffle oven, and microwave oven. The samples were characterized by XRD, FTIR, textural analysis and SEM. The catalytic tests were carried out on a bench scale using mixed CO/N{sub 2} (5% CO mol.mol) to the reaction flow 30mL.min{sup -1}, molar ratio H{sub 2}O/CO of 0.3. The results showed that for all heating conditions there was the monophasic formation of CoFe{sub 2}O{sub 4}, with crystallite size ranging from 38 to 40 nm. Samples showed mesoporous characteristics with type II isotherm and hysteresis loop H3. The sample synthesized in the muffle furnace showed the highest conversion rate of 56.0% and the sample synthesized in the ceramic base showed higher selectivity with 90.19% for the WGRS process. (author)

  20. Utilization of solar electric fence for containment of caprine in familiar production of the Pernambuco semi-arid region; Utilizacao de cerca eletrica solar para confinamento de caprinos na producao familiar do semi-arido pernambucano

    Energy Technology Data Exchange (ETDEWEB)

    Costa, Heitor Scalambrini; Costa Neto, Guilherme [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Nucleo de Apoio a Projetos de Energias Renovaveis], Email: naper@ufpe.br; Araujo, Kassia; Silva, Gerson Flavio da; Raquel, Karine [ONG NAPER SOLAR, Recife, PE (Brazil). Centro de Estudos e Projetos], Email: nsolar@terra.com.br

    2006-07-01

    The Center for Studies and Projects - Naper Solar is an NGO, which works for the dissemination of use of alternative energies resources in the semi-arid Brazilian Northeast in collaboration with the Federal University of Pernambuco. It has implemented caprine raising systems in the back lands of Pajeu in the State of Pernambuco making use of electrified fences energized by solar energy.This project was executed in a joint effort with the City Halls of Afogados da Ingazeira e Sao Jose do Egito and the NGOs Diaconia and the Northeast Woman House and has benefited 20 families of farmers from 9 rural communities. It is funded by a Technical Cooperation Program established between the National Fund for the Environment - Ministry for the Environment and the Netherlands Government. The implemented system, in opposition to the traditional extensive production system, allow for a more animal sanitary control - minimizing the risks of contamination; a more controlled and balanced feeding system - taking into account the weight gaining factor together with pasture management, leading the a guarantee of food supply for the animals. Other advantages of this system include the reduction of fence cost and less deforesting. Electrical fences used in the contention of caprine are built with only 4 straight wires, fixed with isolators on wood posts spaced 10 m from each other, while the conventional fences use 9 barbed-wire lines fixed with clamps on posts spaced 1 m from each other. Therefore, the use of electrical fences instead of the conventional one represent a cost reduction, which can go as high as 40 % of the total cost. Besides that the electrical fences have low maintenance cost, easier and faster installation and relocation. The fenced areas vary from 0.5 ha to 4 ha for the raising of 5 to 50 animals. In the electrification of a fence one needs one photovoltaic module, one electrifier, a battery, isolators (passage and corner), electric ground rods and a thunderbolt deviator kit. In this work the component of an solar electric fence are described together with its main benefits and installation and maintenance costs. (author)

  1. Utilization of hair and nails as bio-indicators of contamination by heavy and toxic metals in industrial workers; Utilizacao de cabelos e unhas como bioindicadores de contaminacao por metais pesados e toxicos em trabalhadores de industrias

    Energy Technology Data Exchange (ETDEWEB)

    Vilhena Schayer Sabino, Claudia de; Silva, Ascanio Barros F.E.; Fernandes, Marcio Prado; Amaral, Angela Maria; Franco, Milton Batista; Guedes, Joao Bosco; Francisco, Dovenir; Castro de Assis, Adilson de

    1996-03-01

    Instrumental neutron activation analysis and atomic absorption spectrometry were performed on scalp hair and fingernail samples collected from a group of heavily exposed healthy mail industrial workers. The concentration of trace elements (As, Cd, Cr, Hg, Ni, Pb and Sb) were evaluated and compared for scalp and fingernails. Comparative studies demonstrated that concentration of certain elements were greater than those corresponding to non-exposed workers. (author). 4 refs., 6 tabs.

  2. Utilization of biodiesel from castor oil in gas micro turbines: thermal performance testing and emissions; Utilizacao do biodiesel de mamona em microturbinas a gas: testes de desempenho termico e emissoes

    Energy Technology Data Exchange (ETDEWEB)

    Nascimento, Marco Antonio R.; Lora, Electo Silva; Venturini, Osvaldo Jose; Maldonado, Manuel Rendon; Andrade, Rubenildo Viera; Correa Junior, Paulo Sergio Pedroso [Universidade Federal de Itajuba (UNIFEI), MG (Brazil)], Emails: marcoantonio@unifei.edu.br, electo@unifei.edu.br, osvaldo@unifei.edu.br, nrendon@unifei.edu.br, ruben@unifei.edu.br, paulocorrea@unifei.edu.br; Leite, Marco Antonio Haikal [Centro de Pesquisas Leopoldo Americo Miguez de Mello (CENPES/PETROBRAS), Rio de Janeiro, RJ (Brazil)], Email: mahaikal@petrobras.com.br

    2006-07-01

    The operation of power equipment such as a gas micro-turbine using renewable fuels is an interesting alternative when sustainability is concerned, mainly in isolated areas with abundant availability of fuels that come from biomass. Within this scenario, this article presents the results of tests regarding thermal performance and emissions of a gas micro-turbine operating with Diesel and bio diesel mixtures, showing the influence of the use of this fuel on the thermal behavior of the machine and on the emissions of gases such as CO, NO{sub x} and SO{sub 2}. The results of the experimental tests are shown in graphs, from where it can be observed that the bio diesel and its mixtures do not change the thermal behavior of the micro-turbine significantly, and at the same time, they may considerably reduce the emission of gaseous pollutants. (author)

  3. Development of electro fused aggregates for use in refractories for the burning zone of cement kilns; Desenvolvimento de agregados eletrofundidos para utilizacao em refratarios para a zona de queima de fornos de cimento

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Luis Leonardo Horne Curimbaba

    2006-07-01

    Electro fused aggregates are largely used in refractory production due to the better performance reached when they are employed. In this work electro fused aggregates were designed for application in refractories for the burning zone of cement kilns. Initially reaction evaluation was conducted aiming the identification of the most prone refractory systems when single refractory phases react with Portland cement phases at high temperatures. In the next step, raw materials of the best refractory systems were electro fused to generate different aggregate compositions. The electro fused aggregates properties were evaluated and the classified ones were used to produce refractory bricks for the burning zone of cement kilns. General characteristics of these bricks were measured and compared with a standard magnesia-spinel refractory. Aggregates of the system Mg O - TiO{sub 2} - Ca O, more specifically aggregates belonged to the compatibility triangle Mg O - Mg{sub 2}TiO{sub 4} - CaTiO{sub 3}, showed suitable characteristics for development of refractories for the burning zone cement kilns. (author)

  4. Equipment stainless steel entire versus steels bimetallics clad or overlay; Utilizacao de equipamentos de processo construidos em aco inoxidavel integral versus acos bimetalicos cladeado ou 'overlay'

    Energy Technology Data Exchange (ETDEWEB)

    Batista, Itamar da Silva; Lima, Jadival Carneiro de; Leal, Murilo Fonseca; Cardoso, Amauri dos Santos; Jorjan, Roberto [PETROBRAS S.A., Sao Francisco do Conde, BA (Brazil). Refinaria Landulfo Alves Mataripen (RLAM)

    2008-07-01

    This study does not recommend the use of a pressure vessel made of integral stainless steel, due to the failure mechanisms under stress corrosion assisted by chlorides or polythionic acid. Are presented case studies of literature and analysis of reports of proceedings of RLAM reactors, showing that the materials produced by bimetallic clad overlay or are more appropriate, in terms of integrity, for use in equipment that the internal environment requires austenitic stainless steel specification.

  5. Efficiency of phosphorus (32 P) uptake and use by eucalyptus seedlings and rice; Eficiencia de absorcao e utilizacao de fosforo ({sup 32} P) por mudas de eucalipto e arroz

    Energy Technology Data Exchange (ETDEWEB)

    Luca, Edgar Fernando de; Boaretto, Antonio Enedi [Centro de Energia Nuclear na Agricultura (CENA), Piracicaba, SP (Brazil). Lab. de Nutricao Mineral de Plantas; Muraoka, Takashi [Centro de Energia Nuclear na Agricultura (CENA), Piracicaba, SP (Brazil). Lab. de Fertilidade do Solo; Chitolina, Jose Carlos [Sao Paulo Univ., Piracicaba, SP (Brazil). Escola Superior de Agricultura Luiz de Queiroz (ESALQ)

    2002-09-01

    The knowledge on different plant abilities to take up soil phosphorus and its use for growth can be important to improve markedly the efficiency of phosphorus fertilization. Having this in mind, an experiment was carried out under greenhouse conditions to test the hypothesis that eucalyptus seedlings are more efficient than rice in absorbing phosphorus from low solubility sources applied to a Quartzamment soil, testing different efficiency concepts. The phosphorus sources Ca(H{sub 2}{sup 32}PO{sub 4}).H{sub 2}O, CaH{sup 32}PO{sub 4}.2H{sub 2}O and Ca{sub 3}({sup 32}PO{sub 4}){sub 2} , synthesised in laboratory and identified by X-ray diffractometry and thermal differential analyses, were used as radioactive tracers. It was concluded that rice is more efficient in absorbing phosphorus from these low solubility sources, while eucalyptus presents a higher coefficient of biologic P utilisation. The 'difference' method (conventional) that in based on P recovery by plants, underestimated the absorption of this nutrient for both species in relation to the isotopic method. (author)

  6. Use of the extraction residue of emeralds in a formulation mass of ceramic tiles; Utilizacao do residuo da extracao de esmeraldas em uma formulacao de massa de revestimento ceramico

    Energy Technology Data Exchange (ETDEWEB)

    Cavalcante, R. F., E-mail: ronaldofcavalcante@gmail.com [Programa de Pos-Graduacao em Engenharia Mecanica - PPgEM - UFRN, Universidade Federal do Rio Grande do Norte, Lagoa Nova, RN (Brazil); Nascimento, R.M.; Paskocimas, C.A., E-mail: rmaribondo@ufrnet.br, E-mail: paskocimas_ca@hotmail.com [Departamento de Engenharia Materiais - DEMAT - Universidade Federal do Rio Grande do Norte, Lagoa Nova, RN (Brazil); Dutra, R.P.S., E-mail: ricardodutra@ct.ufpb.br [Departamento de Engenharia Materiais - DEMAT - UFPB - Universidade Federal de Pernambuco, Recife (Brazil)

    2012-04-15

    Companies involved in mining and beneficiation of emerald represent an important area of industrial development in Brazil, with a significant contribution to world production of this ore. As a result, large volumes of waste generated and emerald are constantly abandoned in the environment, contributing negatively to their preservation. On the other hand the interest in the use of mining waste as an additive in production of ceramic materials has grown among researchers in recent years. The ceramic industry is constantly seeking to expand the market for the sector and trying to improve product quality and increase the variety of applications. The technology of obtaining ceramic coating that uses waste from mining is still a largely unexplored market. Thus, the purpose of this study was to characterize the waste generated from mining emerald as well as to evaluate its potential use as raw material for production melting of ceramic tiles. Ceramic mixtures were prepared from raw materials characterized by X-ray fluorescence and X-ray diffraction. Five compositions were prepared using the waste codes of emeralds from 0%, 10%, 20%, 30% and 40%. Samples were prepared by pressing, sintered at 1000, 1100 and 1200 deg C and characterized to establish their mineralogical composition, water absorption, linear shrinkage and modulus of rupture. The results showed that the residue of emeralds studied can be embedded in the mass of ceramic tiles up to 20% in replacement of feldspar without compromising the end product properties. (author)

  7. Use of radioanalytical methods for determination of uranium, neptunium, plutonium, americium and curium isotopes in radioactive wastes; Utilizacao de metodos radioanaliticos para a determinacao de isotopos de uranio, plutonio, americio e curio em rejeitos radioativos

    Energy Technology Data Exchange (ETDEWEB)

    Geraldo, Bianca

    2012-07-01

    Activated charcoal is a common type of radioactive waste that contains high concentrations of fission and activation products. The management of this waste includes its characterization aiming the determination and quantification of the specific radionuclides including those known as Difficult-to-Measure Radionuclides (RDM). The analysis of the RDM's generally involves complex radiochemical analysis for purification and separation of the radionuclides, which are expensive and time-consuming. The objective of this work was to define a methodology for sequential analysis of the isotopes of uranium, neptunium, plutonium, americium and curium present in a type of radioactive waste, evaluating chemical yield, analysis of time spent, amount of secondary waste generated and cost. Three methodologies were compared and validated that employ ion exchange (TI + EC), extraction chromatography (EC) and extraction with polymers (ECP). The waste chosen was the activated charcoal from the purification system of primary circuit water cooling the reactor IEA-R1. The charcoal samples were dissolved by acid digestion followed by purification and separation of isotopes with ion exchange resins, extraction and chromatographic extraction polymers. Isotopes were analyzed on an alpha spectrometer, equipped with surface barrier detectors. The chemical yields were satisfactory for the methods TI + EC and EC. ECP method was comparable with those methods only for uranium. Statistical analysis as well the analysis of time spent, amount of secondary waste generated and cost revealed that EC method is the most effective for identifying and quantifying U, Np, Pu, Am and Cm present in charcoal. (author)

  8. The Potential for Conflict in Latin America: A Cross-National Study.

    Science.gov (United States)

    1980-05-16

    reemerged as important indicators of relative military strength. The NUC and DEP values were reduced to a level which we considered too low for inclusion ...articulated Argentine view of the problem see: Juan Ramon Munoz Grande, "Argentina: Objecto organico del Ejercito para el largo plazo," Estrategia , (No

  9. Non c’è più religione! né diritto. E noi? Riflessioni a margine dell’indagine sullo stato della disciplina IUS 11 (a.a. 2016/17

    Directory of Open Access Journals (Sweden)

    Pierluigi Consorti

    2016-12-01

    SOMMARIO: 1. Introduzione - 2. I dati del macrosistema universitario - 3. L’offerta formativa giuridica - 4. Le nostre responsabilità - 5. L’organico attuale e prospettive - 6. Gli insegnamenti - 7. I dottorati - 8. Le scuole di specializzazione - 9. I cultori della materia - 10. Appendice: l’abilitazione scientifica nazionale.

  10. Application of natural Ra isotopes and {sup 234}Th as tracers of organic carbon export in Bransfield Strait, Antarctica; Aplicacao dos isotopos naturais de Ra e do Th-234 como tracadores do carbono organico exportado para o Estreito de Bransfield, Antartica

    Energy Technology Data Exchange (ETDEWEB)

    Vieira, Lucia Helena

    2011-07-01

    The Southern Ocean is the largest of several high-nutrient, low-chlorophyll (HNLC) regions in the world's oceans. This region plays a major role in regulating the global net transfer of carbon dioxide between the ocean and the atmosphere, in part because the annual photosynthetic uptake of CO{sub 2} by phytoplankton and resulting export of particulate organic carbon (POC) to the deep ocean. The element thorium has multiple radioisotopes that have emerged collectively as a powerful set of tracers for particle associated processes in the oceans. Of all the Th isotopes, {sup 234}Th (half-life 24.1 d) has been the focus of increasing attention and application in the past years. The production of {sup 234}Th from {sup 238}U, coupled with the conservative behavior of {sup 238}U in seawater, makes the source of {sup 234}Th easy to characterize. Moreover, the half-life of {sup 234}Th is sufficiently short to make it sensitive to the short-term (e.g. seasonal) changes that occur in the upper water column of the open ocean or in sediments or water column in coastal areas. Because of its very particle reactive behavior, {sup 234}Th is removed from a parcel of water in only two ways, through decay and through particle flux. Therefore, a steady-state 1D activity balance can be used to calculate its flux. Natural Ra isotopes have been also widely used in marine studies to trace water masses and to quantify mixing processes. This work presents results of a collaborative research on organic carbon fluxes distribution in the Bransfield Strait in order to evaluate its influence in the CO{sub 2} drawdown. Macro-nutrients, micro-nutrients and chlorophyll-a distributions were used to examine the pathway sources. Natural radium isotopes were applied as tracers to study the movement of shelf water, while {sup 234}Th was used as a tracer of particle flux in the upper ocean, since POC export via sinking particles is the primary mechanism of carbon sequestration in the Southern Ocean. Sea water samples for total {sup 234}Th and natural Ra isotopes were collected from 9 to 14 December 2007 on the RV Ary Rongel (Brazilian Navy). Analyses of total {sup 234}Th activities were performed by gross beta counting using a gas-flow low background proportional counter. The long lived Ra isotopes were determined by low-background high efficiency gamma spectrometry. (author)

  11. Dynamic carbon content as an indicator of desertification processes in soils developed from volcanic parental material in the Region of Murcia; Contenido en carbono organico como indicador del proceso de desertificacion en suelos desarrollados en material parental volcanico en la Region de Murcia

    Energy Technology Data Exchange (ETDEWEB)

    Martinez-Martinez, S.; Faz Cano, A.; Acosta Aviles, J. A.

    2009-07-01

    Soil Organic Carbon (SOC is an essential components of the global carbon cycle, especially in soils developed from volcanic rocks, due to these soils does not have inorganic carbon. In arid and semiarid areas mineralization of organic carbon is very intense due to climatic conditions, causing soils depletion and therefore desertification. The objective of this study is to determine the content of OC, as a first step in the assessment of desertification. The objective of this study is to determine the content of OC, as a first step in the assessment of desertification processes affecting this area of the southeast of Spain. (Author) 7 refs.

  12. Synthesis in aqueous medium and organic praseodymium complexes with ligands derived from Schiff base quinolinic. Characterization and physicochemical study; Sintesis en medio acuoso y organico de complejos de praseodimio con ligantes derivados de base de Schiff quinolicos. Caracterizacion y estudio fisicoquimico

    Energy Technology Data Exchange (ETDEWEB)

    Garcia G, A.

    2015-07-01

    It was investigated the coordination ability of the quinolinic Schiff base organic tetradentate quinolinic ligand (Q Schiff-(OH){sub 2}) towards the trivalent praseodymium by UV/Vis spectrophotometric titration (St). By St, was studied the formed species between the Q Schiff-(OH){sub 2} ligand and the praseodymium nitrate salt in equimolar concentrations (5.86 x 10{sup -4} M: 5.22 x 10{sup -4} M) in methanol. The statistical analysis of the experimental results suggested three complexed species with 1Pr:3L, 1Pr:2L y 1Pr:1L stoichiometries. The predominant stoichiometries were the second and the latter. Based on these results and data from the scientific literature, the methodology for the syntheses of the complexes Q Schiff-(OH){sub 2}-Pr in aqueous-organic and organic media was established and a molar ratio M:L= 1:2 of praseodymium nitrate and the ligand was used. The new complexes were characterized by UV/Vis, Infrared, X-ray Photoelectron Spectroscopy (XP S), Diffuse Reflectance (Dr) and Thermogravimetric Analysis/Differential Scanning Calorimetry (TGA/DSC). Elemental analysis of C, N, O and Pr by XP S suggested 1Pr:2L:1Na (PrC{sub 32}H{sub 20}N{sub 4}O{sub 4}Na) stoichiometry of the complex synthesized by the aqueous-organic medium while for the complex synthesized by the organic medium it was 1Pr:3L (PrC{sub 48}H{sub 33}N{sub 6}O{sub 6}). In the first case, the praseodymium ion charge was neutralized by the anionic ligands whose remaining charge was compensated by the sodium ion. In the second case, the ion charge was neutralized by the ligands. The minimum formula was Pr(Q Schiff){sub 2}Na for the pure coordination compound from the aqueous-organic medium and the minimum formula Pr(Q Schiff){sub 3} for that from the organic medium. XP S also indicated that the oxidation state of praseodymium ion was maintained. Both complexes were stable in methanol, ethanol and acetonitrile at least for 5 days. The photophysical properties of the studied complexes were evaluated by emission and excitation luminescence (fluorescence and phosphorescence) at ambient temperature (291 K) and liquid nitrogen (77 K) in the UV-Visible region. It was found that the ligand transfers its energy to the praseodymium at least 70%. It is concluded that two new complexes were obtained by Q Schiff-(OH){sub 2} and the praseodymium with a reaction yield of about 60% (Pr(Q Schiff){sub 2}Na) and 75% (Pr(Q Schiff){sub 3}). UV/Vis, IR and Dr, XP S and TGA/DSC demonstrated the coordination of quinolate and imine groups from the ligand to the metal ion. Thus a CN=8 para Pr(Q Schiff){sub 2}Na and CN= 12 para Pr(Q Schiff){sub 3}. Their photophysical properties in the visible region suggested that the quinolinic Schiff base organic tetradentate quinolinic ligand transfers energy from its excited triplet state to the praseodymium ion sensitising the luminescence properties from the metal ion which in turn re-emits enhanced light from its {sup 1}D{sub 2} level, mainly. (Author)

  13. Synthesis and characterization of La{sub 0,8}Ca{sub 0,2}MO{sub 3} (M = Co ou Mn) perovskite by using gelatin as organic precursor; Sintese e caracterizacao de perovsquita do tipo La{sub 0,8}Ca{sub 0,2}MO{sub 3} (M = Co ou Mn) usando a gelatina como precursor organico

    Energy Technology Data Exchange (ETDEWEB)

    Wanderley, J.B.M.; Borges, F.M.M. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Escola de Ciencias e Tecnologia; Ribeiro, J.P.; Pimentel, P.M.; Melo, D.M.A., E-mail: brunomoura@daect.com.br [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Departamento de Quimica

    2011-07-01

    Materials with perovskite structure are potential catalysts to prevent the emission of pollutants into the environment, various methods have been proposed for the synthesis of these materials, to produce homogeneous materials with nanoscale particle size. In this work, lanthanum manganate systems and lanthanum cobaltate systems with partial substitution of calcium were synthesized using gelatin as a precursor agent, aiming its use as automotive catalysts. This synthesis method, using gelatin as organic precursor, was used because it allows the synthesis of crystalline phases with powders homogeneous and porous. The powders obtained at 300 ° C, were calcined at temperatures of 700 and 900 ° C for 4h, and were characterized by means of thermogravimetric analysis, X-ray diffraction and scanning electron microscopy. The perovskite were single phase, nanometric, and porous. These features make the powders potential catalysts for automotive combustion. (author)

  14. Synthesis and characterization of hybrid organic-inorganic materials of polyamide-imide (PAI) and copolysilsesquioxanes of 3-aminopropyltriethoxysilane (APES) and phenyltriethoxysilane (PTES); Sintese e caracterizacao de materiais hibridos organico-inorganicos de poliamida-imida e copolisilsesquioxanos de 3-aminopropiltrietoxissilano e feniltrietoxissilano

    Energy Technology Data Exchange (ETDEWEB)

    Demarchi, A.A., E-mail: aa_demarchi@terra.com.b [WEG Equipamentos Eletricos S.A., Jaragua do Sul, SC (Brazil). Dept. de P e D do Produto; Pezzin, S.H. [Universidade do Estado de Santa Catarina (UDESC), SC (Brazil). Centro de Ciencias Tecnologicas

    2010-07-01

    In this work, organic-inorganic hybrids were obtained by adding copolysilsesquioxanes of 3-aminopropyltriethoxysilane (APES) and phenyltriethoxysilane (PTES), prepared by sol-gel, to the polyamide-imide (PAI). The synthesis of PAI oligomer from trimellitic anhydride (TMA) and 4,4-diphenyl-methane diisocyanate (MDI), was monitored by FTIR, noting that two steps of 80 deg C and 120 deg C for 2 h each are sufficient to obtain it. PAI-copolysilsesquioxanes hybrids were characterized by FTIR, viscometry, thermogravimetry, NMR and microscopy. The spectrum of the PAI and PAI-hybrid copolysilsesquioxanes show the formation of amide and imide. Copolysilsesquioxanes with high levels of APES increased the viscosity and generated the PAI oligomer gelatinization, hindering the formation of uniform films. Gelatinization did not occur with copolysilsesquioxanes rich PTES, allowing the formation of homogeneous films improvements in thermal resistance. (author)

  15. Procedure Development to Determine Organic Compounds in the PM{sub 1}-2.5 and PM{sub 2}.5-10 Fractions of Atmospheric Aerosols; Desarrollo de la Metodologia para la Determinacion de los Compuestos Organicos en las Fracciones PM{sub 1}-2.5 y PM{sub 2}.5-10 del Aerosol Atmosferico

    Energy Technology Data Exchange (ETDEWEB)

    Pindado, O.; Perez, R. M.

    2011-07-28

    An analytical procedure development to measure organic compounds such as aliphatic hydrocarbons, polycyclic aromatic compounds, n-alcohols and fatty acids in PM{sub 1}-2.5 and PM{sub 2}.5-10 of atmospheric aerosol is accomplished. The development encompasses an optimization of extraction step, derivatization step and chromatographic analysis. The method developed consists in a microwave extraction, followed by a stage of fractionation and analysis by GC/MS. (Author) 20 refs.

  16. Effects of the organic solvents addition about crude oil rheological behavior from 'Reconcavo Baiano' (Brazil); Efeito da adicao de solventes organicos sobre o comportamento reologico do petroleo cru oriundo do 'Reconcavo Baiano' (Brasil)

    Energy Technology Data Exchange (ETDEWEB)

    Cavalcanti, Luis A.P. [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Faculdade de Engenharia Quimica; Vieira, Jacyara M.A. [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Faculdade de Engenharia de Minas; Almeida, Yeda M.B.; Sarmento, Sandra M. [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil)

    2004-07-01

    The crude oil rheological properties are quite important in its transport and refining processes. They can affect the head losses and, thus, the pressure within a refining unit. These properties can be affected by the temperature and the chemical composition as well as by solvents added to the crude oil. The current work studied the rheological behaviour of both a crude oil from the Reconcavo Baiano (Brazil) and mixture of this crude oil with organic solvents (toluene and xylene). The solvent type and concentration effects on the rheological parameters, were studied. The Brookfield viscometer, model LDVD-II, was used. The results brought to light that the crude oil and the crude oil-solvent mixtures behaved, discretely, as thixotropic fluids. The model of Herschel-Bulkley for viscoplastic fluid was the best in fitting the experimental data for both crude oil and crude oil - solvent mixture. The toluene was found to be more efficient in reducing both the apparent viscosity and apparent yield stress of the crude oil than the xylene for a given concentration. The solvent concentration affects indirectly the rheological properties of the crude oil. (author)

  17. UASB technology applied to treat industrial spills with high organic load: effluents from a factory of yeast production (Cordoba, Spain); Depuracion de vertidos organicos de alta carga: aplicacion de la tecnologia UASB al tratamiento anaerobio de las vinazas de una fabrica de levadura (Cordoba)

    Energy Technology Data Exchange (ETDEWEB)

    Marin Galvin, R.; Aguilar Jimenez, J. M.; Rojas Moreno, F. J.

    2005-07-01

    This paper deals on the yielding obtained in the exploitation of an UASB Water Treatment Plant, which is located in to the La Golondrina Wastewater Treatment Plant (Cordoba, Spain). This UASB Water Treatment Plant is focused to treat spills from yeast production with a treatment capacity of 2.100 m''3/day. From july of 1997 to may of this year, the plant has produced treated waster with 1.446 mg/l of suspended solids (influent, 2.471 mg/l), 1.449 mg/l of BOD{sub 5} (influent, 13.578 mg/l): this implies a global yielding of 70,5%. Furthermore, the UASB plant has generated 2.828 m''3/day of biogas with high quality which is later used in a co-generation system there available. (Author) 15 refs.

  18. A radiochemical procedure for a low-level measurement of ''241Am in environmental samples using a supported functional organo phosphorus extractant; Metodo analitico para la determinacion de ''241Am en muestras biologicas y sedimentos marinos mediante uso de una columna con extractante organico

    Energy Technology Data Exchange (ETDEWEB)

    Gasco, C.; Anton, M. P.; Alvarez, A.; Navarro, N.; Salvador, S.

    1994-07-01

    The transuranides analysis in environmental samples is carried out by CIEMAT using standardized methods based on sequential separation with ionic-exchange resins. The americium fraction is purified through a two-layer ion exchange column and lately in an anion-exchange column in nitric acid methanol medium. The technique is time consuming and the results are not completely satisfactory (low recovery and loss of a-resolution) for some samples. The chemical compound CMPO (octyl(phenyl)-N,N-diisobutyl carbomoylmethyiphosphine oxide) dissolved in TPB (tributyl phosphate) and supported on an inert substrate has been tested directly for ''241Am analysis by a large number of laboratories. A new method that combines both procedures has been developed. The details of the improved procedure are described in this paper. The advantages of its application to environmental samples (urine, faeces and sediments) are discussed. The utilization of standard samples, with americium certified concentrations confirms the reliability of our measurements. (Author) 8 refs.

  19. The influence of organic compound addition on the mobility and biological availability of the {sup 137} Cs and {sup 60} Co on tropical soils; A influencia da adicao de composto organico na mobilidade e biodisponibilidade do {sup 137} Cs e do {sup 60} Co em solos tropicais

    Energy Technology Data Exchange (ETDEWEB)

    Portilho, Antonio Passos

    2005-07-01

    The hole of manure in the mobility and bioavailability of {sup 137}Cs and {sup 60}Co in Brazilian soil was investigated. For this study an Oxisol was selected, for being the soil of larger distribution in the country, characterized by a low content in nutrients and organic substances; a Nitisol, was also selected as representative of soils with average fertility and an Organo sol, as representative of soils with high content of organic matter. These soils were transferred to an experimental area in the Instituto de Radioprotecao e Dosimetria, conditioned in plastic pots and spiked with {sup 137}Cs e {sup 60}Co. To follow the root uptake of {sup 137}Cs and {sup 60}Co we cultivated radish (Raphanus sativus, L.), in the pots receiving different doses of manure: a dose recommended for radish (2 kg/m{sup 2}); a half of the recommended dose; the double of the recommended dose and without manure addition. Only the Organo sol did not received manure. Moreover, it was investigated the potential mobility of {sup 137}Cs and {sup 60}Co associated to the unstable compounds under natural soil environment, such as the organic substance, oxides of iron etc, through the method of sequential chemical extraction. The main results show that soil to plant transfer factor (TF) for {sup 137}Cs decreases after the addition of 4 kg/m{sup 2} of manure in the Nitisol (from 0.44 to 0.06) and in the Oxisol (from 0,44 to 0,11). In relation to {sup 60}Co the TF reduced from 14,73 for 0,15 in Nitisol and from 11,25 for 0,15 to Oxisol. In the Organosols the TF values were low and comparable with values obtained in soil that received at least a dose of manure: 0,11 for {sup 137}Cs and 2,64 for {sup 60}Co. It was also observed, that the TF for {sup 137}Cs diminish with the increase of the nutrient contents (K, Ca and Mg) when manure is applied. It was verified, through the results of sequential extraction, that {sup 137}Cs was mainly associated to iron oxides in all types of studied soils. In the Nitisol, {sup 60}Co, was mainly weakly adsorbed to its compounds (52%) even about 18% was strongly associated to the organic matter and around 10% was associated to the manganese oxides. It was observed that 56% of the total {sup 60}Co added to the Organo sol was associated to the organic matter, while 71% of the total {sup 60}Co added to the Oxisol was associated to the manganese oxides. (author)

  20. Soro de leite como agente encapsulante de Bifidobacterium BB-12 por spray drying

    OpenAIRE

    Cislaghi, Fabiane Picinin de Castro

    2012-01-01

    Dissertação (mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Agrárias. Programa de Pós-Graduação em Ciência dos Alimentos. O soro de leite e o principal subproduto da industria lactea. Apesar do seu elevado valor nutricional, o aproveitamento do soro de leite ainda e pequeno. Novas alternativas para utilizacao do soro sao necessarias a fim de reduzir seu desperdicio e a poluicao ambiental causada quando nao descartado adequadamente. O objetivo deste estudo foi avalia...

  1. The use of protozoan, rotifers and nematodes as live food for shrimp raised in bft system

    OpenAIRE

    Loureiro, Cláudio Kinach; Junior, Wilson Francisco Britto Wasielesky; Abreu, Paulo Cesar Oliveira Vergne de

    2012-01-01

    O Meio de Cultivo de Protozoarios e Nematodeos – PNCM, possibilita a producao de microrganismos de forma barata para a utilizacao como alimento vivo em cultivos de camaroes marinhos. Ciliados produzidos no PNCM foram testados como alimento vivo para pos-larvas de camaroes em um experimento com quatro tratamentos: (BFT) somente bioflocos; (BFT 10) 10 mL de PNCM adicionado ao biofloco; (BFT 100) 100 mL de PNCM adicionado ao biofloco; BFT 1000) 1000 mL de PNCM adicionado ao biofloco. Os microrga...

  2. Estereoscopio com tela holografica para ver tomografias

    CERN Document Server

    Lunazzi, J J; Magalhaes, D S F

    2010-01-01

    A estereoscopia eh uma tecnica que permite a observacao de imagens tridimensionais, mas estah sempre associada com o uso de algum equipamento especial para visualizacao, como oculos bicolores ou polarizados. Para o uso em aplicacoes medicas o emprego de tais equipamentos pode inviabilizar sua utilizacao durante procedimentos cirurgicos, por exemplo. Neste trabalho apresentamos um novo tipo de estereoscopio que utiliza uma tela holografica para geracao de imagens tridimensionais sem o uso de qualquer equipamento adicional. Apresentamos a descricao do equipamento utilizado e resultados das imagens visualizadas.

  3. Conhecimento dos graduandos de nutrição e enfermagem quanto ao consumo de corantes alimentares e seus efeitos adversos à saúde Knowledge of nursing and nutrition graduate students on the consumption of food colorings and their adverse health effects

    Directory of Open Access Journals (Sweden)

    Julia Nascimento Teles

    2016-10-01

    Objetivo: Evaluar la función intestinal de la clientela adulta atendida, asociándolos a los factores de riesgo, a partir de datos obtenidos en el Programa Fábrica de Cuidados. Métodos: Fueron seleccionadas 377 historias clínicas de adultos de ambos sexos. De estas, 48 presentaban el relato de constipación intestinal. Fueron colectadas variables sociodemográficas, de consumo alimentar y estilo de vida. Resultados: La prevalencia de constipación fue de 12,7%, con predominancia del sexo femenino de 89,6%. Se observó un bajo consumo de fibras, donde 69,7% y 66,7% de los pacientes constipados no consumían diariamente frutas/jugos y hortalizas A y B, respectivamente. Sobre el diagnóstico nutricional, 58,3% del grupo presentó IMC superior a 25. La ingestión hídrica, 31,2% consumían por lo menos 08 vasos/día. El sedentarismo fue predominante en el grupo (62%, además 60,4% substituían las principales refecciones por aperitivos. Conclusión: El perfil de la población en relación a los factores en estudio, justifica la alta prevalencia de la constipación. Descriptores: Constipación Intestinal, Adultos, Fibras, Estilo de vida.

  4. Estudo da sorção do corante catiônico violeta cristal por espuma de poliuretano em meio aquoso contendo dodecilsulfato de sódio Sorption of crystal violet by polyurethane foam from aqueous medium containing sodium dodecylsulfate

    Directory of Open Access Journals (Sweden)

    Mariana Mori

    2009-01-01

    Full Text Available This work presents a detailed study about the sorption of crystal violet (CV cationic dye onto polyether type polyurethane foam (PUF. The sorption process was based on the formation of an ionic-pair between cationic dye and dodecylsulfate anion (SDS, which presented high affinity by PUF. Set-up employed in the study was built up by adjusting a 200 mg cylinder of PUF to the arm of an overhead stirrer. The system was characterized in relation to equilibrium and kinetic aspects and it was modeled by employing Langmuir and Freundlich isotherms. Obtained results showed that the ratio between SDS and MB concentrations played an important role on the sorption process. According to results found it was possible to retain up to 3.4 mg of dye from 200 mL of a 5.0 x 10-5 mol L-1 CV solution containing 1.25 x 10-4 mol L-1 SDS, which represented a removal efficiency of around 92%.

  5. Cloreto de n-(2-hidroxil propil-3-trimetil amônio quitosana como adsorvente de corantes reativos em solução aquosa Chitosan-n-2-hydroxypropyl trimethyl ammonium chloride as adsorbent for the removal of the reactive dye from aqueous solutions

    Directory of Open Access Journals (Sweden)

    Valfredo T. Fávere

    2010-01-01

    Full Text Available The quaternary chitosan was synthesized by reaction of chitosan with glycidyl trimethylammonium chloride. it was characterized by infrared spectra and conductometric titration. Adsorption of reactive blue 4 (RB4 and reactive red 120 (RR120 by quaternary chitosan was studied from aqueous medium. Two kinetic adsorption models were tested: pseudo first-order and pseudo second-order. The experimental data best fitted the pseudo second-order model. The Langmuir isotherm model provided the best fit to the equilibrium data in the concentration range investigated and the maximum adsorption capacity determined was 415 mg (RR120 and 637 mg (RB4 of reactive dye per gram of adsorbent.

  6. Estudo da fotocatálise heterogênea sobre Ti/TiO2 na descoloração de corantes sintéticos A heterogeneous photocatalysis study of decolorization of synthetic dyes on Ti/TiO

    Directory of Open Access Journals (Sweden)

    Thiago N. M. Cervantes

    2009-01-01

    Full Text Available The main goal of this paper was to study the degradation of synthetic dyes using photoelectrocatalytic properties of particulate films of TiO2 supported on plates of titanium and stimulated by UV-Vis radiation. The dyes decolorizations were measured using spectrophotometric methods to verify which the conditions on Ti/TiO2 electrode was the best for the photoelectrodegradation of them. The results showed that decolorization rates were higher than 90% during a period of 270 min. FT-IR spectroscopy showed that intermediate substances were formed after the decolorization and N=N group/aromatic structures were preserved independently of the specific structure of the dyes.

  7. Ligninolytic enzymes production and Remazol brilliant blue R decolorization by tropical brazilian basidiomycetes fungi Produção de enzimas ligninolíticas e descoloração do corante azul brilhante de Remazol R por fungos basidiomicetos tropicais brasileiros

    OpenAIRE

    Machado,Kátia M.G.; Dácio R. Matheus; Bononi,Vera L. R.

    2005-01-01

    Remazol Brilliant Blue R (RBBR) dye was used as substrate to evaluate ligninolytic activity in 125 basidiomycetous fungi isolated from tropical ecosystems. The extracellular RBBR decolorizing activity produced when selected fungi were grown in solid media and in soil contaminated with organochlorines was also evaluated. A total of 106 fungi decolorized the RBBR during the growth in malt extract agar (MEA, 2%); 96 fungi showed a mycelia growth and decolorization activity stronger than the P. c...

  8. Aplicação da tecnologia de eletrofloculação na recuperação do corante índigo blue a partir de efluentes industriais Application of the electroflocculation technology for the recovery of indigo blue from industrial effluents

    OpenAIRE

    Fabiana Maria Monteiro Paschoal; Germano Tremiliosi-Filho

    2005-01-01

    The indigo blue dye is widely used in the textile industry. When discarded, besides polluting the environment, it affects the appearance and transparency of aquatic bodies, causing damage to flora and fauna. The removal of this dye from industrial effluents is difficult due to its resistance towards degradation. This work proposes the recovery of indigo blue by electroflocculation, as a subsidy for the treatment of effluents from the jeans industry.

  9. Imobilização de ferro (II em matriz de alginato e sua utilização na degradação de corantes têxteis por processos Fenton Immobilization of iron (II in alginate matrix and its use in textile dye degradation by Fenton processes

    Directory of Open Access Journals (Sweden)

    Kely Viviane de Souza

    2008-01-01

    Full Text Available In this work Fenton and photo-Fenton processes for textile dye degradation were investigated using iron (II immobilized in alginate spheres. Photomicrographs obtained by scanning electron microscopy showed an irregular and porous surface with a homogeneous distribution of iron. The Fenton process was used to evaluate the degradation efficiency of reactive dyes and this procedure showed a low degradation effect. The association of artificial visible light or solar radiation in the Fenton process (foto-Fenton process showed degradation ratios of 70 and 80% respectively in 45 min. It was also observed that the iron-alginate matrix can be reused.

  10. Chitosan/Fe spheres on the blue QR-19 dye degradation by photo Fenton processes using artificial or solar light; Esferas de quitosana/Fe na degradacao do corante azul QR-19 por processos foto-Fenton utilizando luz artificial ou solar

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Kely V. de; Zamora, Patricio G.P.; Zawadzki, Sonia F. [Universidade Federal do Parana (DQ/UFPR), Curitiba, PR (Brazil). Dept. de Quimica], E-mail: zawadzki@quimica.ufpr.br

    2010-07-15

    The contamination of water resources is one of the greatest environmental problems today. Among the polluting sources are the textile industries due to the production of large volumes of effluent, often treated inefficiently. The main reason for the environmental impact of the rejected materials is the presence of dyes such as azo reactive compounds that can generate by-products with carcinogenic and mutagenic effects. They may also include anthraquinone type compounds, which are highly resistant to degradation and persist in the effluent for a long time. The purpose of this study is the use of photo-Fenton processes assisted by artificial or solar light, using immobilized iron on chitosan beads, crosslinked with glutaraldehyde, for the anthraquinone type compound Blue QR-19 standard dye degradation in aqueous solutions. The obtained spheres showed a regular size and 4.0 mm diameter. The results showed 90% discoloration of the system within 180 minutes and a 60% total organic carbon (TOC)reduction for the photo-Fenton system using artificial light. For the system using sunlight, the total discoloration was achieved in 120 minutes and the TOC value decreased 70%. Also observed was that iron remained in the polymeric matrix after the treatment, thus allowing reuse. (author)

  11. Degradação de corantes reativos por processo foto-fenton envolvendo o uso de peneira molecular 4A modificada com Fe3+ Degradation of reactive dyes by photo-fenton process using Fe3+ immobilized in molecular sieve 4A

    Directory of Open Access Journals (Sweden)

    Franciély Ignachewski

    2010-01-01

    Full Text Available In this work the preparation and characterization of a supported catalyst intended for degradation of reactive dyes by Fenton-like processes is described. The photocatalyst was prepared by immobilization of Fe3+ into the molecular sieve (4A type surface and characterized by x-ray diffractometry and infrared, Mössbauer and EPR spectroscopy. The solid containing 0.94% (w/w of ferric ions was used in degradation studies of aqueous reactive-dyes samples with really promissory results. Generally, Vis-assisted photochemical processes leads to almost total decolorization of all tested dyes at reaction times lower than 30 min. It was also observed that the iron-molecular sieve matrix can be reused.

  12. Aplicação de um corante tiazolilazo como indicador ácido-base e determinação das suas constantes de ionização ácida Application of a thiazolylazo dye as an acid-base indicator and determination of its acid ionization constants

    Directory of Open Access Journals (Sweden)

    Regina Terumi Yamaki

    2009-01-01

    Full Text Available The pKa values of the 6-[2´-(6´-methyl-benzothiazolylazo]-1,2-dihydroxy-3,5-benzenedisulfonic acid (Me-BDBD have been determined at 25 °C, in 0.10 mol L-1 NaCl medium by spectrophotometric method. The SQUAD computer program was used to process experimental data in pH range 1.78 - 11.54 and 290 - 720 nm. The pKa values obtained were 4.60 ± 0.04 and 9.48 ± 0.02. The Me-BDBD reagent was applied as indicator in titration of acid-base. The results were compared with phenolphthalein and bromocresol green indicators. Statistical t and F tests indicated that there were no statistically significant differences between the results for indicators with good agreement.

  13. Síntese e caracterização de nanopartículas de óxido de ferro suportadas em matriz carbonácea: remoção do corante orgânico azul de metileno em água Synthesis and characterization of iron oxide nanoparticles supported on carbon matrix: oxidation of the dye methylene blue in water

    Directory of Open Access Journals (Sweden)

    Maraísa Gonçalves

    2009-01-01

    Full Text Available In this work were prepared composites of iron oxide and carbonaceous materials in two different weight proportions (Carbon/Fe 1/1 and 1/2. The physico-chemical properties of the composites were determined by temperature programmed reduction (TPR, adsorption/dessorption of N2, X-ray diffraction (XRD, X-ray photoelectron spectroscopy (XPS and pulse titration H2. The XRD and XPS analysis showed a cubic iron oxide phase, identified as maghemite, formed over the carbon surface. The particle size of maghemite showed to be within 10-30 nm. Carbon/Fe 1/2 was the most active in MB removal kinetics and ESI-MS studies showed that MB removal by both composites leads to oxidized intermediates.

  14. Determinação de corantes marcadores do tipo azo e antraquinona em combustíveis por cromatografia líquida com detecção eletroquímica Determination of azo and anthraquinone dyes in fuels sample using hplc with electrochemical detection

    Directory of Open Access Journals (Sweden)

    Magno Aparecido Gonçalves Trindade

    2010-01-01

    Full Text Available An analytical method based on high-performance liquid chromatography with electrochemical detection has been developed and applied to the determination of Solvent blue 14 (SA-14 and Solvent red 24 (SV-24 in fuel samples. The dyes were better separated on C18 column, using a mobile phase composed of acetonitrile and ammonium acetate (90:10, v/v. Detection was carried out at an oxidation potential of +0.85V. The detector response was linear at concentration range of 7.50×10-8 - 1.50×10-6 mol L-1 (r = 0.997 for SA-14 and SV-24, respectively. The method was used to quantify these dyes in fuels samples with satisfactory accuracy and precision.

  15. Remoção dos corantes azul brilhante, amarelo crepúsculo e amarelo tartrazina de soluções aquosas utilizando carvão ativado, terra ativada, terra diatomácea, quitina e quitosana: estudos de equilíbrio e termodinâmica

    Directory of Open Access Journals (Sweden)

    Guilherme Luiz Dotto

    2011-01-01

    Full Text Available This work compared activated carbon, activated earth, diatomaceous earth, chitin and chitosan to removal acid blue 9, food yellow 3 and FD&C yellow nº 5 dyes from aqueous solutions with different pH values (2-10. In the best process condition for each dye, equilibrium studies were carried out at different temperatures (from 298 to 328 K and Langmuir, Freundlich, Redlich-Peterson, Temkin and Dubinin-Radushkevich models were fitted with experimental data. In addition, entropy change, Gibbs free energy change and enthalpy change were obtained in order to verify the thermodynamic adsorption behavior.

  16. Aplicação da tecnologia de eletrofloculação na recuperação do corante índigo blue a partir de efluentes industriais Application of the electroflocculation technology for the recovery of indigo blue from industrial effluents

    Directory of Open Access Journals (Sweden)

    Fabiana Maria Monteiro Paschoal

    2005-10-01

    Full Text Available The indigo blue dye is widely used in the textile industry. When discarded, besides polluting the environment, it affects the appearance and transparency of aquatic bodies, causing damage to flora and fauna. The removal of this dye from industrial effluents is difficult due to its resistance towards degradation. This work proposes the recovery of indigo blue by electroflocculation, as a subsidy for the treatment of effluents from the jeans industry.

  17. Adsorption of reactive Remazol Red RB dye of aqueous solution using zeolite of the coal ash and evaluation of acute toxicity with Daphnia similis; Adsorcao de corante reativo Remazol Vermelho RB de solucao aquosa usando zeolita de cinzas de carvao e avaliacao da toxicidade aguda com Daphnia similis

    Energy Technology Data Exchange (ETDEWEB)

    Magdalena, Carina Pitwak

    2010-07-01

    In this study, the capacity of zeolite synthesized from coal ash in the removal of Remazol Red dye aqueous solution was investigated by batch mode operation. The equilibrium was attained after 360 min of contact time. The adsorption rate followed the kinetic model of pseudo-second-order. The equilibrium data obtained fitted to Langmuir adsorption isotherm showing the adsorption capacity of up to 1.20mg g-1. The efficiency of adsorption was between 75 to 91% in the equilibrium time. In order to obtain the best conditions for removal of this dye, the influence of the following parameters was: initial concentration of the dye, pH of the aqueous solution, dose of adsorbent and temperature. The thermodynamic parameters were evaluated showing that the adsorption of Remazol red on the zeolite is of a spontaneous nature. Experiments by adding NaCl and Na{sub 2}SO{sub 4} were carried out to simulate the real conditions of the effluents from the dyeing bath and to evaluate the influence of these chemical compounds in the phenomenon of adsorption. The equilibrium data of adsorption of Remazol red on the zeolite was achieved in a shorter time in the presence of increasing concentrations of salts in solution and an increase in adsorption capacity. The efficiency of the study was evaluated as a treatment for acute toxicity using Daphnia similis microcrustacean. (author)

  18. Evaluation of the hydrogen peroxide and special colorant effects under irradiation by argon and diode laser on tooth-whitening in vitro; Avaliacao do efeito de corantes especiais e peroxido de hidrogenio irradiados por laser de argonio e laser de diodo no clareamento dental 'in vitro'

    Energy Technology Data Exchange (ETDEWEB)

    Gaspar, Jose Antonio

    2003-07-01

    The aim of this study is to determine if there is any interaction between special colorant found on bleaching agents that have 35 % of hydrogen peroxide on its composition, and argon or diode laser. The first part of the study was to characterize the extrinsic stain obtained through a staining solution containing products present on the day by day diet of the general population. Thirty-two inferior human extracted incisors, free of caries and without filling material were selected for the study. The laser devices employed were Argon laser (AccuCure 3000 TM - Lasermed), wave length 488 nm, with a 200 mW/cm{sup 2} for 30 seconds in continuos mode; and diode laser (L 808 Medical Laser - Lasering do Brasil), wave length 808 {+-} 10 nm, with 1,6 W/cm{sup 2} for 30 seconds in continuos mode. The application mode done by a scanning movement over the buccal surface. The bleaching agents used were: Opalescence Extra (OE) - Ultradent Products USA, hydrogen peroxide 35%, gel with Carotene to convert light into heat; Pola Office (PO) - SDI - USA single doses of hydrogen peroxide; Whiteness HP (WHP) - FGM - Brasil, hydrogen peroxide 35%; Opus White (OW) - Sharplan - Israel, hydrogen peroxide 35%. The temperature rise measurement was performed with a thermocouple model 120-202-AJ, Fenwal, inserted into the pulpar chamber. The bleaching material was applied on the tooth surface with 2 mm thickness and then the irradiation was perform. The thirty two teeth were randomized in four groups, two for each laser device. The obtain data demonstrated a superior performance of the Argon laser on tooth whitening and also better results concerning the temperature rise. The alteration on tooth coloration was verified through digital spectrophotometer (Shade-Eye EX - Shofu) and quantitative analyses showed statistical differences among the groups. The bleaching results for Argon laser combined with OE and WHP were superior for the other groups. The mean variation of the temperature rise obtained Argon laser were {<=} 5,6 deg C, and the values obtained with the Diode laser were {>=} 5,6 deg C. The results obtained lead to conclude that Argon laser is safer and more efficient than diode laser for tooth whitening procedures, and the best results achieved with the association of Argon laser irradiation to the bleaching agent OP and WHP. (author)

  19. Oriente within, Nord without: il meridionismo e i romantici inglesi

    Directory of Open Access Journals (Sweden)

    Luigi Cazzato

    2012-11-01

    Full Text Available Per Voltaire (1773 prima ed Hegel (2010 poi, la storia del progresso del mondo ha viaggiato seguendo il percorso geo-politico e climatico aristotelico 1: dal dispotico Oriente verso il libero Occidente; mentre per Montesquieu (1994 essa ha viaggiato anche dai paesi caldi del Sud, timorosi come i vecchi, verso i paesi freddi del Nord, coraggiosi come i giovani. L’Europa non si è vista solo come l’altro rispetto all’Oriente, ma anche come l’altro rispetto al suo Meridione: il presente moderno del Nord di contro al passato antico del Sud. Nella seconda metà del Settecento, il secolo della nascita dell’orientalismo come sapere organico all’impresa coloniale dell’Occidente, vennero gettati anche i semi della pianta del meridionismo, sapere organico all’impresa della costruzione della moderna identità europea. I romantici inglesi coltivarono questa pianta.

  20. Semiconductor Nanoparticles as Platform for Bio-Applications and Energy Related Systems

    OpenAIRE

    2015-01-01

    Esta tesis esta dedicada a la sintesis, caracterizacion y aplicaciones de diferentes nanomateriales que presentan la propiedad de ser semiconductores. Esta dividida en tres bloques, en los cuales, en el primer de ellos se habla sobre quantum dots (QDs), que son nanoparticulas fluorescentes cuya longitud de onda de emision varia con el tamaño. Dichos materiales se estan usando ultimamente como sustitutos de los colorantes organicos ya que presentan ventajas, la principal es que no pierden s...

  1. Relación de la Concentración del ion Tiocianato Salival y el Recuento de Bacterias Aerobias en Saliva en Personas Fumadoras y no Fumadoras

    OpenAIRE

    2016-01-01

    El ion tiocianato es una sustancia derivada del cianuro, el cual es metabolizado en nuestro organismo, para luego liberarse en diversos fluidos organicos, tales como la saliva, donde es transformado a ion hipotiocianato mediante el sistema lactoperoxidasa, atribuyendosele una funcion antibacteriana. El objetivo fue relacionar la concentracion del ion tiocianato salival y el recuento de unidades formadoras de colonias (UFC) de bacterias aerobias en la saliva. La concentracion del ion tiocianat...

  2. Fluxos fluviais de carbono orgânico dissolvido para o complexo estuarino de Paranaguá, Paraná, Brasil

    OpenAIRE

    Libardoni, Bruno Guides

    2013-01-01

    Resumo: O crescimento populacional desordenado e a degradacao excessiva dos recursos naturais, como os cursos d fagua, limitam a sustentabilidade dos sistemas naturais e dos humanos que deles dependem. Dentre os diversos constituintes particulados e dissolvidos, carreados por estes cursos d fagua, encontra-se o Carbono Organico Dissolvido (COD), cujo transporte e ciclo biogeoquimico podem ser transformados e modificados pelas atividades humanas. Este constituinte e de grande importancia nas i...

  3. Determination of organic compounds in medicinal plants, commercialized in capsulated forms and 'in natura' by wavelength dispersive X-ray fluorescence spectrometry (WDXRF). Determination of quantitative inorganic profiles; Determinacao de componentes organicos em plantas medicinais, comercializadas em forma de po (capsulas) e 'in natura', utilizando a tecnica de fluorescencia de raios X por dispersao de comprimento de onda (WDXRF). Determinacao de perfis inorganicos quantitativos

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Manuel Octavio M.; Sato, Ivone Mulako; Salvador, Vera Lucia R. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil). Centro de Quimica e Meio Ambiente]. E-mail: lawless@usp.br

    2005-07-01

    X-ray fluorescence technique was used to determine major and trace elements for five Brazilian commercial medicinal plants. The bromobutane (Barbatimao), Ginkgo folium (Ginkgo biloba), Echinodorus macrophyllus (Chapeu de couro), Valeriana officinalis (Valeriana), Cordia salicifolia (Porangaba) samples were collected from three to six different commercial suppliers. The species were collected 'in natura' (leaves, flowers, barks and roots) and capsulated forms. The samples were grinded in liquid N{sub 2} atmosphere and double layer pressed pellet were prepared. The elements Na, Mg, P, S, Cl, K, Ca, Mn, Fe, Ni, Cu, Zn, Rb e Sr concentrations were determined by individual calibration curves. The precision and accuracy of method were evaluated by certified reference material, NIST 1547 - Peach Leaves and the Chauvenet, Cochrane, ANOVA and Z-score statistical tests were applied. Each specimen presented a distinct inorganic profile and a great variation in its composition was observed. The inorganic profile will contribute for the elaboration of a quality and security guide to assure the phytotherapics commercialization. Moreover, these profiles could be used as complementary data to active farmaco compounds profiles for specimen's ratification. (author)

  4. Determination of the average residence time in an anaerobic digester of Barueri wastewater treatment by using radioactive tracer, Sao Paulo State, Brazil; Determinacao de tempo de residencia medio - TRM - em um digestor anaerobio da Estacao de Tratamento de Esgotos de Barueri com utilizacao de tracador radioativo

    Energy Technology Data Exchange (ETDEWEB)

    Helou, Luiz Carlos; Vitoreti, Cristiane da Silva; Moraes, Fabio Alceu Akiyama de [Companhia de Saneamento Basico do Estado de Sao Paulo (SABESP), Barueri, SP (Brazil). Unidade de Negocios de Tratamento de Esgotos; Aoki, Pedro Eiti; Silva, Valdir Cosmos da [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)

    2002-07-01

    Gas production in the Barueri Wastewater Treatment Plant digesters shows lower values than projected. This fact conducted to the hypothesis that there could be dead zones caused by homogenization deficiencies. In order to verify this hypothesis a full scale essay was conducted with Iodine - 131 as tracer. A Mutual Cooperation Agreement was signed between the Sao Paulo Basic Sanitation Company (SABESP) and the Nuclear and Energetic Research Institute (IPEN) to conduct these essays. The results showed that the active volume was almost 88% of the nominal capacity. (author)

  5. Using the model release ARTM associated with resources for simulation geoprocessing radiological environmental impact of atmospheric emissions from a research reactor; Utilizacao do modelo de dispersao ARTM associado a recursos de geoprocessamento para simulacao do impacto ambiental radiologico de emissoes atmosfericas de um reator de pesquisa

    Energy Technology Data Exchange (ETDEWEB)

    Alves, Simone Fonseca

    2013-08-01

    The knowledge of the dispersion of radionuclides emissions into the atmosphere arising from a nuclear reactor, in normal operation, is an important step in the process of the nuclear and environmental assessment study. These processes require an assessment study of the radiological environmental impact. However, to estimate this impact a simulation of the transport mechanisms and deposition of pollutants released into the atmosphere is required. The present study aimed at the application of the dispersion model ARTM (Atmospheric Radionuclide Transport Model), together with the powerful tools of the GIS (Geographic Information System) for the environmental impact assessment of a radiological nuclear reactor under typically routine and conditions. Therefore some important information from the national project for a research reactor known as Brazilian Multipurpose Reactor (RMB) was considered. The information of the atmospheric emissions of the reactor, needed for the simulation of this project, was based on data of the Open Pool Australian Light Water (OPAL).Other important data that had to be collected and analyzed were the source term, the topography, the meteorology and the environmental data. The radionuclides analyzed as pollutants were {sup 41}Ar; {sup 140}Ba; {sup 51}Cr; {sup 137}Cs; {sup 131}I; {sup 133}I; {sup 85m} Kr; {sup 87}Kr; {sup 88}Kr; {sup 140}La; {sup 133}Xe; {sup 135}Xe; {sup 3}H; {sup 90}Sr. The model was run for two chronological scenarios according to their meteorological data for the years 2009 and 2010, respectively. The adoption of GIS techniques was relevant in planning, data preprocessing and in the post-processing of results as well. After pre-processing, the input data were processed by the ARTM dispersion model. Maps, charts, and tables were then produced and evaluated. According to the simulated and evaluated scenarios it could be concluded that exposure pathways that mostly contributed to the dose for individual public were {sup 41}Ar, for immersion in the plume, and {sup 133}I, for inhalation. Nevertheless, even these pathways were much below the limits established by the current standards. (author)

  6. Study of the microstructural and mechanical properties of titanium-niobium-zirconium based alloys processed with hydrogen and powder metallurgy for use in dental implants; Estudo das propriedades mecanicas e microestruturais de ligas a base de titanio-niobiozirconio processados com hidrogenio e metalurgia do po para utilizacao em implantes dentarios

    Energy Technology Data Exchange (ETDEWEB)

    Duvaizem, Jose Helio

    2009-07-01

    Hydrogen has been used as pulverization agent in alloys based on rare earth and transition metals due to its extremely high diffusion rate even on low temperatures. Such materials are used on hydrogen storage dispositives, generation of electricity or magnetic fields, and are produced by a process which the first step is the transformation of the alloy in fine powder by miling. Besides those, hydrogenium is also being used to obtain alloys based on titanium - niobium - zirconium in the pulverization. Powder metallurgy is utilized on the production of these alloys, making it possible to obtain structures with porous surface as result, requirement for its application as biomaterials. Other advantages of powder metallurgy usage include better surface finish and better microstructural homogeneity. In this work samples were prepared in the Ti-13Nb-13Zr composition. The hydrogenation was performed at 700 degree C, 600 degree C, and 500 degree C for titanium, niobium and zirconium respectively. After hydrogenation, the milling stage was carried out on high energy planetary ball milling with 200rpm during 90 minutes, and also in conventional ball milling for 30 hours. Samples were pressed in uniaxial press, followed by isostatic cold press, and then sintered at 1150 degree C for 7-13 hours. Microstructural properties of the samples were characterized by scanning electron microscope (SEM), energy dispersive spectroscopy (EDS) and x-ray diffraction. Mechanical and structural properties determined were density, microhardness and moduli of elasticity. The sample sintered at 1150 degree C for 7h, hydrogenated using 10.000 mbar and produced by milling on high energy planetary ball milling presented the best mechanical properties and microstructural homogeneity. (author)

  7. X-ray cone beam microtomography for quantitative assessment of tracheal and pharyngeal volumes of Rhodnius prolixus; Utilizacao da microtomografia computadorizada com feixe de raios-X conico para a determinacao quantitativa do volume da traqueia e faringe do Rhodnius prolixus

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Izabella Soares de

    2017-07-01

    In the past decade microcomputerized tomography imaging using synchrotron radiation has become a powerful technique to generate high resolution images of Rhodinus prolixus. Images of soft tissues (protocerebrum and muscles) and dense structures (pharynx, trachea and esophagus) of R. prolixus head have been obtained using synchrotron radiation microtomography in mono and polychromatic configuration, respectively. Advancements in conventional microtomography have increased the achievable resolution and contrast, making this relatively inexpensive and widely available technology potentially useful for studies of insect internal morphology. The main goal of this work was to provide a new set of high quality microtomographic images of R. prolixus achieved by means of a desktop X-ray microtomograph. It allows the three-dimensional visualization of important chitinized structures: pharynx and tracheae. Pharyngeal and tracheal volumes were quantitatively evaluated at different days (1, 4, 10, 15 and 20) after feeding. The results suggest that variation of average volumes could be attributed to insect hormone 20-hydroxy-ecdysone (20-OH-Ec) pulse at 11 days after feeding. Pharyngeal volumes decrease 3.80 times. On the other hand, tracheal volumes increase 1.78 times. Head total volume showed similar trends than trachea. (author)

  8. A study of physics of sub-critical multiplicative systems driven by sources and the utilization of deterministic codes in calculation of this systems; Um estudo da fisica de sistemas multiplicativos subcriticos acionados por fontes e a utilizacao de codigos deterministicos no calculo destes sistemas

    Energy Technology Data Exchange (ETDEWEB)

    Antunes, Alberi

    2008-07-01

    This work presents the Physics of Source Driven Systems (ADS). It shows some statics and K{sub i}netics parameters of the reactor Physics and when it is sub critical, that are important in evaluation and definition of these systems. The objective is to demonstrate that there are differences in parameters when the reactor is critical. Moreover, the work shows the differences observed in the parameters for different calculation models. Two calculation methodologies are shown In this dissertation: Gandini and Salvatores and Dulla, and some parameters are calculated. The ANISN deterministic transport code is used in calculation in order to compare these parameters. In a subcritical configuration of IPEN-MB-01 Reactor driven by an external source some parameters are calculated. The conclusions about calculation realized are presented in end of work. (author)

  9. Synthesis NiAl{sub 1,0}Fe{sub 1,0}O{sub 4} catalyst by the combustion reaction to their use in the shift reaction (WGSR); Sintese do catalisador de NiAl{sub 1,0}Fe{sub 1,0}O{sub 4} por reacao de combustao visando sua utilizacao na reacao de shift (WGSR)

    Energy Technology Data Exchange (ETDEWEB)

    Santos, P.T.A.; Costa, A.C.F.M.; Neiva, L.S.; Gama, L. [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Dept. de Engenharia de Materiais; Argolo, F.; Andrade, H.M.C. [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Inst. de Quimica

    2009-07-01

    This work aims at the synthesis of catalyst NiAl{sub 1,0}Fe{sub 1,0}O{sub 4} by combustion reaction using urea as fuel, to evaluate its performance in the production of hydrogen by the reaction of displacement of water vapor (WGSR). The initial composition of the solution was based on valencia total oxidizing and reducing reagents based on the concepts of the chemistry of propellants, using container as a crucible of glassy silica. The resulting powder was characterized by X-ray diffraction, infrared spectroscopy, nitrogen adsorption isotherms (BET), scanning electronic microscope and catalytic tests. The DRX results reveal the presents majoritary phase NiAl{sub 1,0}Fe{sub 1,0}O{sub 4} spinel, the catalyst presents surface area 28 m{sup 2}/g and isotherms type III. Higher conversion CO/CO{sub 2} of 75% CO conversion observed at 500 deg C and catalytic activity of 43 mmolg{sup -1}.h{sup -1} at 450 deg C. (author)

  10. Use of phyllosilicates in electrochemical devices: possible use of sepiolite as a support of catalysts in direct alcohol fuel cells (DAFC); Utilizacao de filosilicatos em dispositivos eletroquimicos: possivel uso da sepiolita como suporte de catalisadores em celulas a combustivel com uso direto de etanol (DAFC)

    Energy Technology Data Exchange (ETDEWEB)

    Parra-Silva, J.; Silva, A.C.; Mello-Castanho, S.R.H. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Cerpa, A. [Universidad Europea de Madrid, Madrid (Spain)

    2014-07-01

    Direct alcohol Fuel cells (DAFC) are interesting to use Brazil for reasons of fuel logistics and availability. The catalysts used in these devices to promote the oxidation of alcohol at the anode need to be fixed on a substrate which must provide high specific surface area, porosity, chemical and thermal resistance, this target can be achieved with the characteristics sepiolite. This paper proposes sepiolite as catalyst support for DAFC. Sepiolite is a phyllosilicate with double layered tetrahedral silicon cells and fibrillar structure. Catalysts (Pt / Sb / Sn) were prepared by cation substitution method and tested by cyclic voltammetry. Techniques as XRD and FT-IR were also used for characterizing materials. Was obtained up to 35 mA / g (Pt) peak current (redox ethanol) indicating the possibility of sepiolite technology development to use un proposed purpose. (author)

  11. Analysis of the technical and economical feasibility of the utilization of a compact co-generator for the production of electric power and cold water; Analise de viabilidade tecnica e economica de utilizacao de um cogerador compacto para producao de eletricidade e agua gelada

    Energy Technology Data Exchange (ETDEWEB)

    Fugueredo, Andre Vieira; Silveira, Jose Luz [UNESP, Guaratingueta, SP (Brazil). Dept. de Energia

    1997-12-31

    Cogeneration based on alternative motor engines has been successfully proposed in many application, especially when the electro-mechanic demand is greater than the thermal one. In this work the technical and economical feasibility of a compact cogeneration system to produce electricity (160 kW) and cold water (75 kW) is studied in order to supply the demand of a computer center building. (author) 5 refs., 8 figs., 2 tabs.; e-mail: avieira at feg.unesp.br

  12. Titanium dioxide use (TiO{sub 2}) in cement matrix as a photocatalyst of nitrogen oxides (NO{sub x}); Utilizacao de dioxido de titanio (TiO{sub 2}) em matriz cimenticia como fotocatalisador de oxidos de nitrogenio (NO{sub x})

    Energy Technology Data Exchange (ETDEWEB)

    Casagrande, C.A.; Hotza, D.; Repette, W.L.; Jochem, L.F., E-mail: cezar.acasa@gmail.com [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil)

    2012-07-01

    The use of titanium dioxide (TiO{sub 2}) in the photodegradation of nitrogen oxides (NO{sub x}) is a technology that can contribute against to environmental pollution. This work shows the feasibility of using TiO{sub 2} in mortars for photocatalysis. The Degussa P25 titania were characterized chemically and physically, revealing that the sample consists of nanoparticles, but has become crowded. Tests Samples (TS) were manufactured with added titania and the NO{sub x} tests at 28, 60 and 120 days of age of TSs, showing that it was 3% capable of degrading 100% of the NO{sub x} gas flow. Proved that conditions like relative humidity, flow and radiation intensity are relevant when it comes to efficiency in photocatalysis, altering the efficiency by varying these conditions. The photocatalysis with titania in cement matrix was efficient in NO{sub x} degradation, presenting itself as a promising technique to control environmental pollution.

  13. Experimental design applied to the study of composition effect of bentonite on the rheology of drilling fluids. Part I: binary compositions; Utilizacao do planejamento experimental no estudo do efeito da composicao de misturas de bentonitas na reologia de fluidos de perfuracao. Parte I: composicoes binarias

    Energy Technology Data Exchange (ETDEWEB)

    Campos, L.F.A.; Amorim, L.V.; Ferreira, H.C. [Universidade Federal de Campina Grande, PB (Brazil). Dept. de Engenharia de Materiais]. E-mail: liszandra@labdes.ufcg.edu.br

    2006-01-15

    The purpose of this work was to apply experimental design to the study of composition effect binary mixtures of bentonite on the rheology of drilling fluids. Through the experimental design were defined the components proportions in the binary clays mixtures and then adjusted regression models relating the parameters, apparent and plastic viscosities and filtrate volume, with the proportion of each clay. The application of this tool allowed to delimit a strip of compositions that favors the improvement of the rheological properties of the dispersions of bentonite clays. (author)

  14. Supervisory utilization as a support information instrument of the data base acquisition and availability by Intranet and Internet natural gas micro-cogeneration; Utilizacao de um supervisorio como ferramenta de suporte de informacoes na aquisicao e disponibilizacao dos dados via Intranet e Internet de um sistema de micro-cogeracao de energia

    Energy Technology Data Exchange (ETDEWEB)

    Camara, Paulo; Sousa, Walter [Centro de Tecnologias do Gas (CTGAS), Natal, RN (Brazil); Petch, Moacir; Diogenes, Pedro; Carrasco, Benjamim [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

    2008-07-01

    The globalization effects intensify the information of technology's usage, not only on the creation of new products and processes, as well, support to operation of new equipment. The Information Technology turns to being more penetrating in the companies' activities, making and changing paradigms and, consequently, in the way how information is conceived. In the partnership PETROBRAS, the Centro de Tecnologias do Gas - CTGAS and the group FOCKINK, was developed and has been launched in the brazilian market the first system of generation and micro-cogeneration by natural gas, activated by an engine diesel derivative by natural gas. The prototype is able to make 35 kW/55 kVA of electric energy, 7TR's (84.000 BTU's) of energy for refrigeration and has a capacity of warming 2200 l / h of water in the temperature of 25 deg C until 85 deg C. The equipment utilizes as a monitoring system a supervisor Elipse Scada, produced by Elipse, which is composed by acquisition and monitoring tools that turns possible the creation of screens with graphics to make easier the support, monitoring, activating and variable control, just like: pressure, temperature, electrical and mechanical. The supervisor keeps in touch with (02) two computers: the first, makes the communication with the supervisor system and the other is used to select the information to be able by web, through CTGAS home page. The access by home page of the information about the data on the co-generator will make easier the client's decision for the acquisition of the equipment. The main objective of this work is, through Information Technology is to present an application case of Elipse Scada Software in micro-cogeneration system installed at CTGAS to turn easier the obtainment of this information, change the relations into an integrate changing, expanding frontiers, creating by this way new challenges. (author)

  15. Thermal analysis of different application techniques on Nd:YAG laser after root canal preparation of single-rooted teeth; Analise termica de diferentes tecnicas de utilizacao do laser de Nd:YAG apos o preparo quimico-cirurgico de dentes unirradiculares

    Energy Technology Data Exchange (ETDEWEB)

    Archilla, Jose Ricardo de F

    2001-07-01

    The experiment objective is to analyze temperature variation, by means of three different application techniques of Nd:YAG laser in the root canals of singlerooted anterior teeth. Three root canals were instrumented, irrigated, X-rayed to measure the remaining dentin in the apical area and submitted to laser irradiation techniques used by Gutknecht, Matsumoto and a new technique with oscillatory movement. The used laser parameters were: pulse energy 250 mJ, frequency 5 Hz, pulse fluency 354 J/cm{sup 2}, average potency 1,25 W, pulse width 300 {mu}s, fiber core diameter 300 {mu}s and interval of thermal relaxation of 20 s. After temperature evaluation and interpretation of the obtained data, it was concluded: 1) the oscillatory technique provided a better heat distribution during the laser application, when analyzing the graphs separately; 2) all the used techniques are within a pattern of safety, analyzing the average and highest temperatures of the apical area and the middle third, even so, disrespecting the last application day and the middle third of root 'C'.(author)

  16. Synthesis and characterization of inorganic ion exchangers based on mixed oxide tin-titanium to be used in recovery of cadmium and nickel and photoluminescent studies; Sintese e caracterizacao de trocadores ionicos inorganicos a base de oxidos mistos estanho-titanio para utilizacao na recuperacao de cadmio e niquel e estudos fotoluminescentes

    Energy Technology Data Exchange (ETDEWEB)

    Paganini, Paula Pinheiro

    2007-07-01

    This work presents the synthesis, characterization and adsorption studies of inorganic ion exchangers based on mixed tin-titanium oxide for recovery of cadmium and nickel metals from aqueous effluents, discarded in the environment mainly through Ni-Cd battery. The exchangers were synthesized by sol-gel modified method using a mixture of tin(IV) chloride and titanium(III) chloride and ammonium hydroxide, as precursors reagents. The materials obtained: SnO{sub 2}/TiO{sub 2} and SnO{sub 2}/TiO{sub 2}:Eu{sup 3+} were characterized by infrared spectroscopy, thermal analysis, scattering electronic microscopy (SEM), X-ray powder diffraction (XRD) (powder method) and electronic spectroscopy (excitation and emission) for the europium doped exchanger. The same materials also were synthesized in polymeric matrix too and can be used in column, because the synthesized materials showed crystals size in nano metric scale. It was determined by the distribution ratios for metals taking as parameters the influence of pH, the concentration of metals (by adsorption isotherms) and the contact time (by adsorption kinetic). The inorganic ion exchanger presented high exchange capacity with adsorption percent above 90 por cent for the studied conditions, quickly kinetic, heterogeneous exchange surfaces, physic adsorption and spontaneous process of exchange. To the doped exchanger spectroscopy properties were studied and also it was calculated the intensity parameters and it was found a satisfactory quantum yield. (author)

  17. Development of an artificial neural network for monitoring and diagnosis of sensor fault and detection in the IEA-R1 research reactor at IPEN; Utilizacao de redes neurais artificiais na monitoracao e deteccao de falhas em sensores do reator IEA-R1

    Energy Technology Data Exchange (ETDEWEB)

    Bueno, Elaine Inacio

    2006-07-01

    The increasing demand on quality in production processes has encouraged the development of several studies on Monitoring and Diagnosis Systems in industrial plant, where the interruption of the production due to some unexpected change can bring risk to the operator's security besides provoking economic losses, increasing the costs to repair some damaged equipment. Because of these two points, the economic losses and the operator's security, it becomes necessary to implement Monitoring and Diagnosis Systems. In this work, a Monitoring and Diagnosis Systems was developed based on the Artificial Neural Networks methodology. This methodology was applied to the IEA-R1 research reactor at IPEN. The development of this system was divided in three stages: the first was dedicated to monitoring, the second to the detection and the third to diagnosis of failures. In the first stage, several Artificial Neural Networks were trained to monitor the temperature variables, nuclear power and dose rate. Two databases were used: one with data generated by a theoretical model and another one with data to a typical week of operation of the IEA-R1 reactor. In the second stage, the neural networks used to monitor the variables was tested with a fault database. The faults were inserted artificially in the sensors signals. As the value of the maximum calibration error for special thermocouples is {+-}0,5 deg C, it had been inserted faults of {+-} 10 C in the sensors for the reading of the variables T3 and T4. In the third stage a Fuzzy System was developed to carry out the faults diagnosis, where were considered three conditions: a normal condition, a fault of {sub 1}0 C , and a fault of + 10 C . This system will indicate which thermocouple is faulty. (author)

  18. Exploratory study on the integration of fuel cell systems inside the chloro-soda plants for utilization of industrial hydrogen; Estudo exploratorio da integracao de sistemas de celula a combustivel dentro das plantas de cloro-soda para utilizacao do hidrogenio industrial

    Energy Technology Data Exchange (ETDEWEB)

    Braga, Jose Mauro Fernandes [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Escola de Engenharia]. E-mail: jmfbraga@oi.com.br; Seidl, Peter [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil); Pirro e Longo, Waldimir [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Nwcleo de Estudos Estrategicos (NEST)

    2008-07-01

    This work aims to demonstrate the economic viability of the application of industrial hydrogen in fuel cell systems by analyzing the advantages and disadvantages of this investment in hydrochloric acid/ sodium hydroxide plants. Using the Present Liquid Value and the Real Options Theory an economic evaluation will be made of the integration of fuel cell system in these plants, based on investment cost, volatility, among other parameters. (author)

  19. Alteration in the absorption cell dose arising from the use of gold nanoparticle associated with the radionuclides of clinical application: simulate study; Alteracao na absorcao de dose celular decorrente da utilizacao de nanoparticulas de ouro associadas a radionuclideos de aplicacao clinica: estudo simulado

    Energy Technology Data Exchange (ETDEWEB)

    Culik, Lucas; Schwarcke, Marcelo, E-mail: mschwarcke@unifra.br [Centro Universitario Franciscano (UNIFRA), Santa Maria, RS (Brazil)

    2015-12-15

    The present work is a proposal to assess, which is the efficiency in the use of radionuclides of clinical application in nuclear medicine service conjugated system with gold nanoparticles.To obtain the results needed for the interpretation of this combination, was using the Monte Carlo simulation code PENELOPE, where was the main structures of a simulated eukaryote cell. To simulate irradiation on cellular structures was used the emission spectrum of main radionuclide clinical use in nuclear medicine service. The material containing gold nanoparticles was modeled according the stoichiometric proportions found in the literature. The results obtained, present for the simulated energies to smaller bodies than 2,0μm, no substantial response to the use of nanoparticles in the reinforcement of locally absorbed dose. Is observed a small decrease in locally dose absorbed due to emission of charged particles, it is believed that causes an increase in the emission secondary range to be placed outside the study body. But this effect is small when comparing to the increase of energy absorbed due to interaction with the bodies containing nanoparticles, so demonstrating an increase in the locally dose absorbed. Being observed that there is an increase in dose absorbed locally due to the use of nanoparticles. For protocols based on the principle of target radionuclide therapy, the imaging of the treaty sit will be affected in their statistical accuracy, since the gamma radiation will be attenuated by the nanoparticles present in the material. Being necessary to know if this increase in the locally absorbed dose has greater importance in the treatment protocol than the image of the absorption of the radioactive material in the target organ. (author)

  20. Influence of the use of NaOH and NH{sub 4}OH the synthesis of iron oxide nanoparticles by coprecipitation; Influencia da utilizacao de NaOH e NH{sub 4}OH na sintese de nanoparticulas de oxido de ferro por coprecipitacao

    Energy Technology Data Exchange (ETDEWEB)

    Panta, P.C.; Zampiva, R.Y.S., E-mail: pr.priscila@gmail.com [Universidade Federal do Rio Grande do Sul (UFRGS), RS (Brazil). Programa de Pos-Graduaco em Engenharia de Minas, Metalurgica e de Materiais; Campos, H.G.; Bergmann, C.P. [Universidade Federal do Rio Grande do Sul (UFRGS), RS (Brazil), Escola de Engenharia

    2012-07-01

    Numerous chemical methods can be used to synthesize iron oxide nanoparticles, including, microemulsion, sol-gel, polyol among others. This work was used because of advantages such as coprecipitation simplicity and large scale production. The goal is to control the characteristics and stability of nanoparticles. Thus, it is a reaction in aqueous iron salts with a base (NaOH, NH{sub 4}OH, etc.) In which parameters such as quality and the molar ratio of base used were varied to control the morphology that the particles, and consequently varying the grain size. Factors such as reaction time and temperature, pH, influence on morphology, and magnetic. There were measures of X-ray diffraction and scanning electron microscopy to obtain the phases and average diameters. The results show that as the choice of base used and its molar concentration variation occurring in the sizes of the iron oxide nanoparticles. (author)

  1. Optimization of a data acquisition and control system for calibration of X rays detectors with usage of computational tools; Otimizacao de um sistema de controle e aquisicao de dados para calibracao de medidores de radiacao X com utilizacao de ferramentas computacionais

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, Yklys Santos

    2013-07-01

    The Brazilian standard ABNT ISO/IEC 17025/2005 specifies general requirements for the competence of testing and calibration facilities. One of these requirements states that these facilities must always optimize their processes and thus, uncertainties must be estimated and lowered as much as possible. In order to achieve such goal, the Laboratorio de Calibracao de Instrumentos (LCI), a laboratory responsible for dosimeter calibration at the Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN) have acquired some equipment for the LCI's X-Ray calibration system, such as a rotating filter holder, and it has also been developing software in order to provide the best calibration results with lowest external interferences (from the operator, for instance) to diminish the possibilities of error occurrences. A semi-automated LabVIEW-based calibration software has been developed at LCI and it has been subjected to constant testing and improvements so far. The software is divided in two basic modules: one is responsible for calibration of the monitor chamber with a reference standard dosimeter, while the other is used to perform instruments calibrations using the monitor chamber as reference. Several influence quantities have been analyzed and the proper corrections have been added to the software as multiplicative correction factors. The software is not only able to acquire data from all the equipment used in the laboratory, but also it is able to calculate calibration factors and its uncertainties. A later analysis shows how this system has optimized the whole calibration process, lowering the occupational dose, reducing the mean time of calibration, uncertainties and preventing errors caused by the system's users. (author)

  2. Determination of attenuation properties of massive ceramic bricks cladded with mortars containing barite used as protective barrier for radiodiagnostic rooms; Determinacao das propriedades de atenuacao de tijolos ceramicos macicos revestidos com argamassa baritada em sua utilizacao como barreira de protecao em salas de radiodiagnostico

    Energy Technology Data Exchange (ETDEWEB)

    Barros, Frieda S.; Schelin, Hugo R.; Tilly Junior, Joao G. [Centro Federal de Educacao Tecnologica do Parana (CEFET-PR), Curitiba, PR (Brazil); Costa, Paulo R.; Nersissian, Denise Y.; Pereira, Marco A.G. [Sao Paulo Univ., SP (Brazil). Inst. de Eletrotecnica e Energia

    2001-07-01

    The purpose of this work is to determine the properties of attenuation of the walls built with massive ceramic bricks to be used as protection barriers in environments of Medicine and Dentistry, when submitted to X-ray diagnosis. Massive ceramic bricks are used thoroughly in constructions as a calking element. The properties of attenuation of these materials were obtained starting from the application of the model of Archer to a group of attenuation curves with wide beams generated in the tensions of 70, 80, 100, 120, 140 and 150 kVp. A radiological equipment of constant potential was used in the Laboratory of IEE/USP, two cameras of ionization of 6cm{sup 3}, coupled to two radiation monitors. The results show that for a tension of 100kVp, the thickness of 10cm of wall made with massive ceramic bricks corresponds to 1mm of lead. (author)

  3. Utilization of radiometric method in evaluation of wear on human dental enamel in vitro by dental porcelain glazed and polished; Utilizacao do metodo radiometrico na avaliacao in vitro do desgaste provocado ao esmalte dental humano por porcelanas dentais glazeadas e polidas

    Energy Technology Data Exchange (ETDEWEB)

    Adachi, Lena Katekawa; Campos, Tomie Nakakuki de; Adachi, Eduardo Makoto [Sao Paulo Univ., SP (Brazil). Faculdade de Odontologia. Dept. de Protese]. E-mail: katekawa@usp.br; Saiki, Mitiko [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)]. E-mail: mitiko@curiango.ipen.br

    2005-07-01

    The dental porcelain is a material commonly used in prosthesis. Disadvantages of dental porcelain use include possibility to cause tooth or dental materials wear. Before its use in the mouth, surfaces are treated with polishing and/or glazing. This research used the radiometric method to verify the influence of these surface treatments on the porcelains of commercial brands: Ceramco II, Noritake and Finesse. This method was originally developed for dentifrice abrasiveness evaluation. Five specimens of dental enamel and 10 specimens of each porcelain (5 glazed, 5 polished) were used. The dental enamel was flattened and irradiated with neutrons from the IEA-R1 (IPEN/CNEN) nuclear reactor. Then it was weared by each porcelain in sliding motion, with water. After 2,500 cycles for each porcelain specimen, the released enamel residue was measured. The enamel wear was evaluated by measuring beta activity of {sup 32}P transferred to water from the irradiated tooth. Results varied from 2.57 to 5.81 {mu}g of enamel /mm{sup 2} weared surface. There was no statistical difference ({alpha}=0.05) between dental enamel wear caused by the same porcelains glazed or polished. The results suggest that adequate surface finishing depend on the type of dental porcelain. (author)

  4. Study of technical, economical and environmental feasibility of biogas digesters utilization on a farm in Recreio dos Bandeirantes, Rio de Janeiro, Brazil; Estudo de viabilidade tecnica, economica e ambiental de utilizacao de biodigestores em uma fazenda no Recreio dos Bandeirantes, Rio de Janeiro

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, Silvio Carlos Anibal de [Universidade Federal do Rio de Janeiro (DEM/CT/UFRJ), RJ (Brazil). Centro de Tecnologia. Dept. de Engenharia Mecanica], e-mail: silvioa@gmail.com; Franca, Vignicius Curi de; Mauro Junior, Leonardo [Auto Mecanica Arapongas, Rio de Janeiro, RJ (Brazil)], e-mails: airninho@hotmail.com, leonardomauro@terra.com.br

    2008-07-01

    A techno-economic analysis of producing biogas for electric power generation is done in the present paper. A biogas production system from pig waste was proposed and designed in a farm in Recreio dos Bandeirantes, Rio de Janeiro. One of the conclusions of this study is the economic advantage of utilizing biogas for power generation rather than other fuels like LPG or purchasing electricity from grid. (author)

  5. Electrolytic hydrogen production at off-peak consumption and his utilization as energy vector at peak consumption through use of fuel cells; Producao de hidrogenio eletrolitico nos horarios fora de ponta e sua utilizacao como vetor energetico nos horarios de ponta atraves do uso de celulas a combustivel

    Energy Technology Data Exchange (ETDEWEB)

    Gambetta, Francielle [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Faculdade de Engenharia Mecanica. Dept. de Energia]. E-mail: fgambetta@fem.unicamp.br; Silva, Ennio Peres da [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Inst. de Fisica. Lab. de Hidrogenio

    2008-07-01

    Due the fact that consumers have different demand, depending on the pace of economic activities and their daily habits of consumption, there is a different electrical demand throughout the day. Demand, in general, is minimal during the morning and it grows with the move for hours to reach peak consumption between 18:00 and 22:00, then turning to fall. It is old the idea of storing electricity produced in off-peak for its consumption in peak hours. To store large amounts of electrical power is required its conversion into some other form of energy, since it is impossible to store electrical energy as such in large quantities. One way of storing electricity is in the form of hydrogen produced by electrolysis of water which then can be stored, purified and converted into electricity through fuel cells. When there is an increase in demand for electricity, there is a need to expand the supply of energy, which means investments in generation, transmission and distribution. This work was performed a preliminary analysis of the production of electrolytic hydrogen in hours of low demand and its use in the generation of electricity in peak hours, making use of the fuel cells, so that to a certain limit value of increased electricity demand, there is no need for expansion of supply of Foz do Iguacu/PR. Moreover, at this work, the ability to harness the heat generated in fuel cells for heating water in homes was considered. (author)

  6. Development of methodology for the synthesis of poly(lactic acid-co-glycolic acid) for use in the production of radioactive sources; Desenvolvimento da metodologia para sintese do poli(acido latico-co-acido glicolico) para utilizacao na producao de fontes radioativas

    Energy Technology Data Exchange (ETDEWEB)

    Peleias Junior, Fernando dos Santos; Zeituni, Carlos Alberto; Rostelato, Maria Elisa Chuery Martins; Souza, Carla Daruich de; Mattos, Fabio Rodrigues de; Moura, Eduardo Santana de; Moura, Joao Augusto; Benega, Marcos Antonio Gimenes; Feher, Anselmo; Costa, Osvaldo Luiz da; Rodrigues, Bruna Teiga, E-mail: fernandopeleias@gmail.com [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP/CTR), Sao Paulo, SP (Brazil). Centro de Tecnologia das Radiacoes; Fechine, Guilhermino Jose [Universidade Presbiteriana Mackenzie, Sao Paulo, SP (Brazil). Escola de Engenharia

    2015-05-15

    According to the World Health Organization, cancer is a leading cause of death worldwide. A radiotherapy method extensively used in prostate cancer is brachytherapy, where the area requiring treatment receives radioactive seeds. Iodine-125 seeds can be inserted loose or stranded in bioabsorbable polymers produced from poly(lactic-co-glycolic acid) (PLGA). We developed the synthesis methodology for PLGA and the results obtained show that it was possible to determine the optimal reaction parameters (time and temperature) for PLGA in 80/20 (lactide/glycolide) ratio. The yield was higher than 90% using a temperature of 110 °C and reaction time of 72 hours; however, the molecular weight values obtained are very low compared to those obtained by other authors. New tests using previously synthesized dimers and nitrogen atmosphere are being performed. These conditions could potentially increase the molar mass of PLGA. All techniques used confirmed the expected structure of the polymer. (author)

  7. Characterization of sediment from the dredging of storm water channels in the city of Salvador-BA, Brazil aiming to use in structural ceramics; Caracterizacao de sedimento proveniente de dragagem de canais pluviais do municipio de Salvador-BA visando sua utilizacao em ceramica estrutural

    Energy Technology Data Exchange (ETDEWEB)

    Santos, O.C.; Breitenbach, S.B.; Coelho, R.E., E-mail: engcruz@ig.com.br, E-mail: silviabb@ifba.edu.br, E-mail: rodrigoecoelho@gmail.com [Instituto Federal de Educacao, Ciencia e Tecnologia da Bahia (IFBA), Salvador (Brazil); Andrade, J.C.S.; Sales Junior, J.C.C., E-mail: jean.engmateriais@gmail.com, E-mail: jccalado@gmail.com [Universidade Federal do Amazonas (UFAM), Manaus (Brazil). Dept. de Engenharia de Materiais; Paskocimas, C.A.; Martinelli, A.E.; Nascimento, R.M., E-mail: paskocimas@uol.com.br, E-mail: aemart@uol.com.br, E-mail: rubensmaribondo@gmail.com [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Programa de Pos-Graduacao em Ciencia e Engenharia de Materiais

    2017-01-15

    The aim of this study was to characterize sediment from the dredging of storm water channels (Scp) in the city of Salvador, Bahia, aiming its maximum replacement by clay in structural ceramics, since this binary mixture is part of the pilot project of the standard mass, in the research of interlocked block ceramic formulation. Initially, the sediment was submitted to the following tests: plasticity index; chemical analysis by X-ray fluorescence; mineralogical analysis by X-ray diffraction; thermal and particle size analyses. The morphology of the material was analyzed by scanning electron microscopy, coupled with energy dispersive spectroscopy. Then, sediment (Scp) was added to clay from the municipality of Candelas, Bahia, in the proportions of 10, 20, 30 and 40 wt%. Specimens were prepared by uniaxial pressing in dimensions of 60 mm x 20 mm, with compacting pressure of 25 MPa, and the material was humidified with 8% of water. Firing was conducted in resistive furnace at temperatures of 850, 950 and 1050 deg C, with 5 deg C / min heating rate. The properties evaluated were: linear shrinkage; water absorption and modulus of rupture. The results indicated the possibility of using SCP in structural ceramics by the prerequisites required in standards, in the manufacture of tiles, sealing blocks and bricks. (author)

  8. Analysis of rationality and efficiency of electricity utilization in posture poultry companies by computation platform based in fuzzy system; Analise da racionalidade e eficiencia da utilizacao de energia eletrica em empresas de avicultura de postura via plataforma computacional baseada em sistema fuzzy

    Energy Technology Data Exchange (ETDEWEB)

    Cremasco, Camila Pires [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Botucatu, SP (Brazil). Dept. de Bioestatistica; Faculdade de Tecnologia (FATEC), Presidente Prudente, SP (Brazil); Gabriel Filho, Luis Roberto Almeida [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Tupa, SP (Brazil). Fac. de Ciencias Agronomicas; Viais Neto, Daniel dos Santos; Bordin, Deyver [Faculdade de Tecnologia (FATEC), Presidente Prudente, SP (Brazil); Silva, Helenice de Oliveira Florentino [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Botucatu, SP (Brazil). Dept. de Bioestatistica], E-mails: gabrielfilho@tupa.unesp.br., dvneto@fatecpp.edu.br, bordin@yahoo.com.br, helenice@ibb.unesp.br

    2012-11-01

    A great application of intelligent systems is in control of the electric power consumption of enterprises. For the assessment of the way that the company uses the electricity there are two indices which are called load factor and power factor. To facilitate the assessment of the performance of electric power consumption by the companies it is interesting that there is a single index indicating globally as energy is being used by the same. The goal of this work was to develop a software to assist laying poultry companies in the region of Bastos in more rational and efficient use of electric energy. For this, a system has been developed called Fuzzy Energy integrated environment developed with Delphi 2010. For the determination of fuzzy factor (situation of the company), we used a fuzzy system prepared in advance. The data collected over a period of 3 years helped the system programming. The software was able to present the situation of the company studied in a manner accessible to the user, and their results were tested accuracy 100 according to fuzzy system. With the inference method of Mandani, unable to create a general simulation of all relevant points of enterprise data. (author)

  9. Synthesis and characterization of lanthanum manganite films for using in solid oxide fuel cells for operation at intermediate temperatures; Sintese e caracterizacao de filmes de manganita de lantanio para utilizacao em pilhas a combustivel de oxido solido para operacao em temperaturas intermediarias

    Energy Technology Data Exchange (ETDEWEB)

    Gama, L.M.; Paes Junior, H.R. [Laboratorio de Materiais Avancados - LAMAV - Universidade Estadual do Norte Fluminense - UENF, Campos dos Goytacazes, RJ (Brazil)

    2010-07-01

    This work aims to investigate the effects of doping and thermal processing of LaMnO{sub 3}, La{sub 0},{sub 8}Sr{sub 0},{sub 2}MnO{sub 3} e La{sub 0},{sub 8}Ca{sub 0},{sub 2}MnO{sub 3} films deposited by spray-pyrolysis technique on their structural, morphological and electrical properties, seeking its application as cathode in solid oxide fuel cells for operation in intermediate temperatures (IT-SOFC). These films were deposited on ferritic stainless steel type AISI 444. The thermal processing of the films was accomplished in air with treatment temperature of 900 degree or 1000 degree during 2 hours. The characterization by Xray diffraction revealed that the thermal processing propitiated the formation of the expected phases with the structure of perovskite. The analysis of surface morphology showed that doping provides an increase in porosity. Electrical characterization showed that Sr-doped films showed higher conductivity values and an activation energy of the conduction process of 0,41 eV. (author)

  10. Characterization of Lanthanum Ferric Cobaltite doped with Strontium (LSCF) films deposited by spray-pyrolysis for application as cathode in PaCOS-TI; Caracterizacao de filmes de CFLE depositados por spray-pirolise para utilizacao como catodo em PaCOS-TI

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, L.S.; Guimaraes, V.F.; Paes Junior, H.R. [Universidade Estadual do Norte Fluminense Darcy Ribeiro (UENF), Campos dos Goytacazes, RJ (Brazil). Lab. de Materiais Avancados], Emails: laryssadsa@yahoo.com.br, valtencyguimaraes@yahoo.com.br, herval@uenf.br

    2010-07-01

    The lanthanum ferric cobaltite doped with strontium (LSCF) is a ceramic material with the perovskite structure that stands out in the field of research for its use as cathode in solid oxide fuel cells at intermediate temperatures (IT-SOFC). The films were synthesized by spray-pyrolysis technique on 8% mol Yttria stabilized zirconia (YSZ) substrates. It was studied the influence of heat treatment temperatures (600-1000 deg C) on the properties of the films under the conditions of treatment during four hours. Samples were tested electrically by measuring the variation of electrical conductivity with temperature, structurally by X-ray diffraction (XRD) and morphologically by scanning electron microscopy (SEM). The films heat treated at 700 deg C for 4 hours showed better performance for application as cathode. (author)

  11. Development of methodology for the synthesis of poly(lactic acid-co-glycolic acid) for use in the production of radioactive sources; Desenvolvimento da metodologia para sintese do poli(acido latico-co-acido glicolico) para utilizacao na producao de fontes radioativas

    Energy Technology Data Exchange (ETDEWEB)

    Peleias Junior, Fernando dos Santos

    2013-07-01

    According to World Health Organization (WHO), cancer is a leading cause of death worldwide. Prostate cancer is the second most common cancer in men. A method of radiotherapy which has been extensively used is brachytherapy, where radioactive seeds are placed inside the area requiring treatment. Iodine-125 seeds can be placed loose or stranded in bioabsorbable polymers. Stranded seeds show some advantages, since they reduce the rate of seed migration, an event that could affect the dosimetry of the prostate and cause unnecessary damage to healthy tissues or organs. For Iodine-125 stranded seeds, polyglactin 910 (poly(lactic-co-glycolic acid)) (PLGA), with a coverage of polyglactin 370 (Vicryl Registered-Sign ) is used. It was purposed in this dissertation, the study and development of the synthesis methodology for PLGA via ring-opening polymerization, as well as its characterization, with the objective of using the synthesized material to manufacture a material similar to RAPID Strand{sub Registered-Sign }. The results obtained show that it was possible to determine the optimal reaction parameters (time and temperature) for PLGA in 80/20 (lactide/glycolide) ratio. Using a temperature of 110 Degree-Sign C and reaction time of 24h, a yield of 86% was obtained, and increasing the reaction time to 72 hours, the yield was higher than 90%. The molecular mass values obtained from the samples are still very low compared to those obtained by other authors in the literature (about 20%). Failures in the sealing of vials, leaving them vulnerable to moisture and oxygen, or lack of an efficient stirring system might be possible explanations for these results. A suitable chemical reactor could solve the problem. Regarding polymer characterization, all techniques used not only confirmed the expected structure of the polymer, but also showed the highest proportion of lactide units compared to to glycolide units. (author)

  12. Effects of using kaolin waste and granite waste as raw materials for the production of low-water absorption ceramic tiles; Efeitos da co-utilizacao dos residuos do beneficiamento do caulim e da extracao do granito rain forest para a producao de revestimentos ceramicos com baixa absorcao de agua

    Energy Technology Data Exchange (ETDEWEB)

    Freires, H.P.; Argonz, R.; Nogueira, R.E.F.Q.; Sasaki, J.M., E-mail: argonz@ufc.br [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil); Sales, J.C. [Universidade do Vale do Aracau (UVA), Crateus, CE (Brazil)

    2012-07-01

    This study aims to evaluate the potential of co-use of granite waste (Rain Forest) and kaolin waste as raw material for the manufacture of ceramic coating of low water absorption. Raw materials were characterized by X-ray diffraction. Kaolin residue was added to the residue of granite in the following proportions (in wt%): 0, 10, 20, 30, 40 and 50%. Specimens were fabricated by uniaxial pressing and fired at 1175,1200 and 1225 deg C. Studies of firing linear shrinkage, water absorption, apparent porosity, apparent density and tensile bending test (or rupture modulus) were conducted. The temperature of 1225 deg C allowed the use of a mixture of 50% granite residue and 50% kaolin residue. Ceramic parts made from that mixture exhibited the maximum values required by the Brazilian Standard NBR 13818 for water absorption, shrinkage and density. (author)

  13. Study of the titanium molybdate gel performance for {sup 99} Mo/{sup 99m}Tc generators utilization; Estudo do desempenho do gel de molibdenio com titanio para utilizacao nos geradores de {sup 99} Mo/{sup 99m}Tc

    Energy Technology Data Exchange (ETDEWEB)

    Moraes, Vanessa; Nieto, Renata C.; Camargo, Fabio de; Osso Junior, Joao A. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)

    2002-07-01

    {sup 99m}Tc is the most used radioisotope in Nuclear Medicine for kidney, brain, liver, lung and bone scans, due to its nuclear properties. It is produced from the radioactive decay of {sup 99} Mo, the basis for a radioisotope generator system. {sup 99} Mo can be produced by several nuclear reactions in nuclear reactors and cyclotrons. In this work, {sup 99} Mo will be produced by {sup 98} Mo (n, {gamma}) {sup 99} Mo reaction and a gel type chromatographic generator will be prepared, containing molybdenum and titanium. This study is part of the radioisotope production nationalization politics at IPEN-CNEN/SP. The gel type generator is prepared by mixing a titanium chloride solution at proper pH with molybdenum oxide dissolved at proper pH, with stirring and further filtration, drying and cracking of the gel. The following variables were studied: mass relation of Mo and Ti, NaOH concentration, temperature and final pH. The gel characterization consisted of particle size distribution and quantitative analysis of Mo and Ti. These results will be compared with those obtained with the gel containing Mo and Zr. (author)

  14. Utilization of the IAIA (Investigation and Analysis of Incidents and Accidents) method in the investigation of the P-36 platform accident; Utilizacao do metodo IAIA (Investigacao e Analise de Acidentes e Incidentes) na investigacao do acidente ocorrido na plataforma P-36

    Energy Technology Data Exchange (ETDEWEB)

    Teles, Marcus de Barros [ARCE - Agencia Reguladora de Servicos Publicos Delegados do Estado do Ceara, Fortaleza, CE (Brazil)

    2004-07-01

    In the beginning of XXI century the Brazilian oil industry report a big accident involving that which was the biggest petroleum platform of the world. With capacity production of 180.000 barrels a day and capacity compression of 7,2 million cubic meter a day of natural gas, the off-shore platform P-36 was situated on Roncador field, in Campos basin, operating in 1360 meters of water. As consequences, eleven deaths with irreparable traumas to the families, friends and worker partners, one billion dollars in prejudices to brazilian country, environmental damages by oil leak and injuries to PETROBRAS reputation in Brazil and in the world. The method of investigation and analysis of incidents and accidents - IAIA is very wide and its philosophy contain a lot of topics, since basic concepts, investigation actions, analysis action and diagnosis by the general kind of fail. Using this method and taking advantage from the report elaborated by the commission organized by ANP - Agencia Nacional do Petroleo and DPC - Diretoria de Portos e Costas, responsible for the investigation and analysis of the accident occurred with P-36, this paper identify the direct and indirect causes of the accident, in attempt to avoid new similar situations. (author)

  15. Technical, economical and environmental viability study for utilization of budgeters on a farm at Recreio dos Bandeirantes, Rio de Janeiro, Brazil; Estudo de viabilidade tecnica, economica e ambiental de utilizacao de biodigestores em uma fazenda no Recreio dos Bandeirantes, Rio de Janeiro, RJ

    Energy Technology Data Exchange (ETDEWEB)

    Franca, Vignicius Curi de; Almeida, Silvio Carlos Anibal de; Mauro Junior, Leonardo [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Centro de Tecnologia], e-mail: airninho@hotmail.com, e-mail: silvioa@gmail.com, e-mail: leonardomauro@terra.com.br

    2008-07-01

    This paper evaluates the technical, economical and environmental viability of solutions for supply electric power and residue treatment in a farm at the Recreio dos Bandeirantes, Rio de Janeiro, Brazil. This paper proposed and dimensioned a system for production of biogas from swine residues. The paper concludes that the benefits coming from biogas for using in the farm facilities presented advantages when compared with the use of conventional sources such as electric power and liquefied petroleum gas (LPG)

  16. Time reduction in well construction with the addition of glass microspheres and thixotropic agents in cement slurries in zonal isolation at Solimoes Basin; Reducao do tempo de construcao de pocos de petroelo na Bacia do Solimoes atraves da utilizacao de microsferas de vidro e agentes tixotropicos nas fases de cimentacao

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Cledeilson R.L.; Duque, Luis H.; Steffan, Rodolfo H.P.; Guimaraes, Zacarias [Baker Hyghes, Houston, TX (United States); Corregio, Fabio; Augusto, Marcelo; Mendes, Sandro C. [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil)

    2012-07-01

    One of the problems faced by the oil industry during the well construction is the damage effect of the hydrostatic head of cement slurries on unconsolidated reservoirs, trending to a necessity of lightweight cementing slurries with high resistance for zonal isolation. This paper presents experiences with lightweight cementing slurries obtained by the addition of glass microspheres and thixotropic agents in oil and gas wells located at Solimoes Basin - Amazon Basin, Brazil, which led to 100% time reduction on well construction when compared with the standard cementing procedures, besides the benefit of no reservoir damage. It also includes lab tests, cement slurry designs, case histories and results that allow a complete evaluation of the technique that can be applied in other similar environments. (author)

  17. Use of sugar-cane bagasse ash to produce glass-ceramic material in the system Ca O-SiO{sub 2}-Na{sub 2}O; Utilizacao de cinza de bagaco de cana para produzir material vitro-ceramico do sistema SiO{sub 2}-CaO-Na{sub 2}O

    Energy Technology Data Exchange (ETDEWEB)

    Teixeira, S.R.; Santos, G.T.A.; Magalhaes, R.S., E-mail: rainho@fct.unesp.b [Universidade Estadual Paulista (DFQB/FCT/UNESP), Presidente Prudente, SP (Brazil). Fac. de Ciencias e Tecnologia. Dept. de Fisica, Quimica e Biologia; Rincon, J.Ma.; Romero, M. [Consejo Superior de Investigaciones Cientificas (IETCC/CSIC), Madri (Spain). Inst. de Ciencias de la Construccion Eduardo Torroja; Carvalho, C.L. [Universidade Estadual Paulista (FEIS/UNESP), Ilha Solteira, SP (Brazil). Faculdade de Engenharia

    2009-07-01

    A bottom ash was used as raw material to obtain glass which was crystallized to form glass-ceramic material. The characterization of the ash shows that it consists mainly of crystalline materials, predominantly quartz, with oxides of iron, potassium and aluminum as minor elements. The glass was obtained from the mixing of ash with calcium and sodium carbonates. The glass and the glass-ceramic were examined using differential thermal analysis (DTA), X-ray fluorescence (XRF), X-ray diffraction (XRD) and scanning electron microscopy (SEM). XRD and DTA data show that Wollastonita is the only crystalline phase present in the material crystallized at 1050 deg C. Part of the glass was synthesized at this temperature for one hour, resulting in a green/brown hard material glass-ceramic. The images of SEM show morphology of spherilithic growth indicating volumetric crystallization mechanism. (author)

  18. Utilization of alternative fuels and the additions to the clinker as opportunities of reductions of greenhouse gas emissions - an overview of the cement sector in Brazil; A utilizacao de combustiveis alternativos e de adicoes ao clinquer como oportunidades de reducao de emissoes de gases de efeito estufa - um panorama do setor de cimento no Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Wills, William [Universidade Federal do Rio de Janeiro (PPE/COPPE/UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-Graduacao de Engenharia. Programa de Planejamento Energetico], E-mail: wwills@lima.coppe.ufrj.br; La Rovere, Emilio Lebre; Westin, Fernanda Fortes [Universidade Federal do Rio de Janeiro (LIMA/COPPE/UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-Graduacao de Engenharia. Lab. Interdisciplinar de Meio Ambiente], Emails: emlio@ppe.ufrj.br, fforteswestin@yahoo.com.br

    2010-07-01

    This paper analyses the energy consumption of the sector in Brazil, specially the participation of alternative sources which are growing systematically since 2001, and the addition of the clinker which is a practice that allows to reduce the CO{sub 2} emissions. These options allows to reduce the burning of fossil fuels and the pollutant emission, reducing local, regional and global impacts.

  19. The use of the uranium isotopic model on the study of aquifers at Morro do Ferro, Pocos de Caldas, Minas Gerais State, Brazil; Utilizacao de modelo isotopico de uranio no estudo de aquiferos do Morro do Ferro, Pocos de Caldas (MG)

    Energy Technology Data Exchange (ETDEWEB)

    Bonotto, Daniel M. [UNESP, Rio Claro, SP (Brazil). Inst. de Geociencias e Ciencias Exatas

    1994-03-01

    Uranium isotopic analyses were performed in groundwaters from several boreholes drilled at the thorium and rare earth deposit located at Morro do Ferro, near the centre of the Pocos de Caldas Plateau, Minas Gerais State, Brazil. The samples were collected during dry and wet periods, proceeding from aquifers developed in the weathered mantle due to in situ intense alteration, with the weathered zone establishing an argillaceous laterite greater than 100 m thick. The {sup 234} U/{sup 238} U activity ratio and U content measured for each sample by alpha spectrometry were used to evaluate the applicability in the area of the model developed to deduce proportions of groundwaters in a mixture. The influence of the rainfall on the utilization of the uranium isotopic model was considered, and also it was possible to suggest which boreholes would be able to supply samples representing different systems of circulation of groundwaters. (author). 5 figs., 2 tabs.

  20. Use of the gamma radiation, in a dose of 0,4 kGy, on the storage temperature reduction of the banana nanica;Utilizacao da radiacao gama, na dose de 0,4kGy, na reducao da temperatura de armazenamento da banana nanica

    Energy Technology Data Exchange (ETDEWEB)

    Manoel, Luciana, E-mail: luciana_manoel@yahoo.com.b [Universidade Estadual Paulisa (UNESP), Botucatu, SP (Brazil). Fac. de Ciencias Agronomicas. Programa de Pos-graduacao em Energia na Agricultura; Vieites, Rogerio Lopes, E-mail: vieites@fca.unesp.b [Universidade Estadual Paulisa (UNESP), Botucatu, SP (Brazil). Fac. de Ciencias Agronomicas. Dept. de Gestao e Tecnologia Agroindustrial

    2009-07-01

    The aim was to evaluate the use of gamma radiation, in a dose of 0,4 kGy, on the storage temperature reduction of the banana 'Nanica'. The bananas 'Nanica' were harvested in the Arm Taperao, Brotas (SP) town, and sent to CBE (Companhia Brasileira de Esterilizacao-Cotia-SP) for irradiation and constitution of the following treatments: T1 (fruits irradiated at 0,4 kGy and stored at 16 +-1 deg C); T2 (fruits irradiated at 0,4 kGy and stored at 14 +-1 deg C); T3 (fruit irradiated ata 0,4 kGy and stored at 12+-1 deg C); T4 (fruits non-irradiated and stored at 16+-1 deg C); T5 (fruits non-irradiated and stored at 14+-1 deg C) and T6 (fruits non-irradiated and stored at 12+-1 deg C). The fruits were stored in B.O.Ds. of the Agroindustrial Management and Technology Department, with a relative humidity of 80+-5%. The experiment was divided in two groups: control group (post harvest conservation and disease incidence) and parcel group (soluble solids and pulp/peel). The analyses were performed in intervals of five days during a period of 25 days. The experimental design employed was completely randomized (DIC) by applying a factor of 2 x 3 x 6 (irradiation x temperature x time). The Tukey test with 5% of probability was used for comparison between means. The storage temperature of the bananas 'Nanica' was not reduce by irradiation. (author)

  1. Use of analcime zeolite from mineral coal fly ash in adsorption of Cu{sup +2} and Cd{sup +2} in aqueous solutions; Utilizacao de zeolita analcima a partir de cinza leve de carvao mineral na adsorcao de Cu{sup +2} e Cd{sup +2} em soluoes aquosas

    Energy Technology Data Exchange (ETDEWEB)

    Rocha Junior, C.A.F.; Santos, S.C.A.; Angelica, R.S.; Neves, R.F.; Souza, C.A.G., E-mail: augustorocha2@gmail.com [Universidade Federal do Para (UFPA), Coqueiro, PA (Brazil)

    2011-07-01

    The use of zeolite for removing heavy metals from contaminated effluents over the years has been widespread due to its high cation exchange capacity in aqueous solutions. Thus this study aims to use analcime zeolite for removal of Cu{sup +2} and Cd{sup +2} from aqueous solutions at different concentrations, and the zeolitic material synthesized from coal fly ash generated in an alumina plant in northern Brazil . The use of zeolite analcime proved quite satisfactory, since this product has removed almost entirely Cu{sup +2} and Cd{sup +2} solutions with concentrations up to 200ppm, and demonstrated an average capacity for solutions of 400ppm, which shows good applicability of this material for the treatment of effluent contamination in the ranges studied. The adsorption models of Langmuir and Freundlich showed a good fit to experimental data generated in this work. (author)

  2. Analysis of economic break-even point of the biogas utilization for electrical power conversion: case study in a swine terminated unit; Analise do ponto de equilibrio economico da utilizacao do biogas para conversao em energia eletrica: estudo de caso em unidade de terminacao de suinos

    Energy Technology Data Exchange (ETDEWEB)

    Cervi, Ricardo Ghantous; Pinotti, Elvio Brasil [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Registro, SP (Brazil). Fac. de Ciencias Agrarias do Vale do Ribeira], e-mails: rghantous@registro.unesp.br, epinotti@registro.unesp.br; Esperancini, Maura Seiko Tsutsui; Bueno, Osmar de Carvalho [Universidade Estadual Paulista Julio de Mesquita Filho (FCA/UNESP), Botucatu, SP (Brazil). Fac. de Ciencias Agronomicas. Dept. de Gestao e Tecnologia Agroindustrial], e-mails: maura@fca.unesp.br, osmar@fca.unesp.br

    2010-07-01

    This work aimed to develop a study to estimate the break-even point in financial units of the electrical power generation using biogas from swine wastes. The analyzed biodigester is a continuous tubular model with brick concrete duct and plastic covering with a gasometer, and where the waste of 2,300 fattening pigs are deposited daily. The initial investment estimate for the installation was R$ 51,537.17. The system annual costs were R$ 5,708.20, for maintenance, R$ 4,390.40 for depreciation and R$ 1,366.77 for interests. It was noticed that with an average of consumption of 17.1 kW.hour{sup -1} the system presents an annual loss of R$ 1,592.14 because the consumption of 27.85 kW.hour{sup -1} is the minimum that should be consumed to achieve a corresponded financial break-even point of R$ 15,054.40.year{sup -1}. It was concluded that the correct technical dimensioning greatly influences on the economic results. (author)

  3. Utilization of response surface for optimization of the production of a biosurfactant with application in the removal of petroleum-derived; Utilizacao de superficie de resposta para a otimizacao da producao de um biossurfactante com aplicacao na remocao de derivado de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Sarubbo, Leonie A.; Rufino, Raquel D.; Luna, Juliana M.; Farias, Charles B.B.; Santos, Valdemir A. dos [Universidade Catolica de Pernambuco (UNICAP), Recife, PE (Brazil)

    2012-07-01

    The surfactants, amphipathic compounds capable of reducing the surface tension of aqueous media, find application in many industries, especially in the petroleum, cosmetic and food, such as dispersants, emulsifiers and surfactants. With the necessity of environmental preservation, surfactants of micro-organisms origin, in substitution of synthetic surfactants, have become very attractive, since they are biodegradable and less toxic although their production costs are still high because of the substrates used and of the purification processes involved. Considering the need to reduce costs associated with the production of microbial surfactants, a strain of bacteria of the genus Pseudomonas, isolated from the port area was cultured in medium containing low-cost agro-industrial wastes, molasses and corn steep liquor, as substrates according a central composite rotatable design (CCRD) in order to evaluate the influence of independent variables molasses and corn steep liquor concentrations on the response variable surface tension. The biosurfactant was able to reduce the water surface tension from 71 mN / m to values around 27.5 mN / m. The dispersion ability and the capacity of oil removal of the surfactant was demonstrated. The possibility of application of biosurfactants in the remediation of oil polluted environments motivates the advancement of research to develop this technology for effective use in treatment of contaminated soils and waters. (author)

  4. Use of thin layer chromatography for the determination of radiochemical purity of radiopharmaceuticals in nuclear medicine services of Paraiba and Rio Grande do Norte, Brazil; Utilizacao da cromatografia em camada delgada para determinacao da pureza radioquimica de radiofarmacos em servicos de medicina nuclear da Paraiba e Rio Grande do Norte, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, W.G.; Santos, P.A.L.; Lima, F.R.A. [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Programa de Pos-Graduacao em Tecnologia Energetica; Lima, F.F., E-mail: wellington.gandrade@gmail.com [Centro Regional de Ciencias Nucleares do Nordeste (CRCN-NE/CNEN-PE), Recife, PE (Brazil)

    2012-07-01

    The paper chromatography and the thin layer chromatography are separation techniques in which the radioactive components migrate because of their affinity with the eluent (mobile phase) or stationary phase, respectively. In radiopharmaceuticals labeled with {sup 99m}Tc, besides its own radiopharmaceutical, {sup 99m}TcO{sup 4-} free and TcO{sub 2} can be identified and quantified. The evaluation of radiochemical purity of radiopharmaceuticals is essential to produce images free of artifacts as well as avoid unnecessary absorbed dose to the patient. Once they are managed in humans it is important and necessary that they undergo to strict quality control. Because of this, ANVISA in its 'Resolucao da Diretoria Colegiada (RDC) 38 of June 4th, 2008 states the obligation of performing a minimum of tests in nuclear medicine services routine prior to human administration. This work evaluated, by the method of thin layer chromatography (TLC), radiochemical purity, determined the pH of the radiopharmaceutical DEXTRAN- 500, DMSA, DTPA, PHYTATE, MDP, MIBI and Sn-Col used in nuclear medicine services in the states of Paraiba and Rio Grande do Norte - Brazil. The results show that the use of thin layer chromatography (TLC) as a standard method in routine of nuclear medicine services is possible, because it provides important data for the evaluation of radiochemical purity, allowing the exclusion of a radiopharmaceutical poorly marked. (author)

  5. Implications of the new Brazilian electric sector model in the process of distributed generation using the sugar cane bagasse; Implicacoes do novo modelo do setor eletrico brasileiro no processo de geracao distribuida com a utilizacao do bagaco da cana-de-acucar

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Celso Eduardo Lins de [Universidade de Sao Paulo (USP), Pirassununga, SP (Brazil). Faculdade de Zootecnia e Engenharia de Alimentos (FZEA). Dept. de Engenharia de Alimentos]. E-mail: celsooli@fzea.usp.br; Halmeman, Maria Cristina Rodrigues; Massochin, Amauri [Universidade Estadual do Oeste do Parana, Cascavel, PR (Brazil). Programa de Pos Graduacao em Engenharia Agricola]. E-mail: cristhalmeman@gmail.com

    2006-07-01

    This articles study what are the main implications of the new electrical sector model as an alternative to improve the electric power generation by using the sugar cane bagasse in the process of cogeneration.

  6. Preliminary analysis of the regolithic clay covers from the region of Alfenas, Minas Gerais, Brazil, aiming to evaluate its use in the traditional ceramic industry; Analise preliminar das coberturas regoliticas argilosas da regiao de Alfenas, Minas Gerais, Brasil, visando sua utilizacao na industria de ceramica vermelha

    Energy Technology Data Exchange (ETDEWEB)

    Gaspar Junior, L.A.; Varajao, A.F.D.C. [Universidade Federal de Ouro Preto (UFOP), MG (Brazil). Escola de Minas. Dept. de Geologia; Moreno, M.M.T. [Universidade Estadual Paulista (UNESP), Rio Claro, SP (Brazil). Dept. de Petrologia e Metalogenia

    2009-07-01

    The region of Alfenas, in the state of Minas Gerais, Brazil, is predominantly constituted of Pre-Cambrian rocks with well developed alteration profiles in association with colluvial and alluvial sediments. No study to date has examined in detail its potential use in the ceramic industry. The scarce knowledge of its mineralogical and technological properties limits its value and consequently its industrial use. Until now, these clay materials have been used in a rudimental manner, in small scale in the fabrication of red tiles. The present study aimed at analyzing these clays mineralogically (X-ray diffraction), chemically (major and minor elements by X-ray fluorescence and organic carbon analysis) and technologically (pressing granulometric distribution; mechanical resistance; water absorption, apparent porosity; linear firing shrinkage; color of firing and others) in order to better understand the raw material and develop adequate technological applications. The best results of ceramic properties were the samples with higher organic content (more plastic clays) and higher values of Al{sub 2}O{sub 3} (kaolinite and gibbsite) and Fe{sub 2}O{sub 3} as well lower SiO{sub 2} content and finer grain size which contribute to a better sintering. (author)

  7. Implante de arcabouços de poli (ácido lático-co-ácido glicólico associados à hidroxiapatita e beta tricálcio fosfato em calota craniana de ratos Wistarpara estímulo da regeneração óssea

    Directory of Open Access Journals (Sweden)

    Felipe Caldeira Campioni

    2014-10-01

    Full Text Available Introdução: O uso de polímeros biorreabsorvíveis, como o PLGA, vem se destacando como ferramenta de reconstrução tecidual. O polímero em questão combinado com materiais cerâmicos, como hidroxiapatita e beta tricálcio fosfato (PLGA HA/βTCP possuem intensa bioatividade na indução do crescimento ósseo. Objetivo: Avaliar a biocompatibilidade e bioatividadedo arcabouços de PLGA HA/βTCP com e sem corante através de implantes realizados na calota craniana de ratos. Metodologia: Foram utilizados 42 ratos Wistarde ambos os sexos, com idade aproximada de dois meses. Após os períodos de implante de 8 e 12 semanas os ratos foram sacrificados por overdose de Halotano e as amostras foram processadas para análise histológica. Os cortes obtidos foram corados com HE e Picrossírus Red. A presença de osso neorfomado foi analisado quantitativamente por histomorfometria. Resultados: Observou-se maior taxa de regeneração óssea nos grupos contendo os arcabouços de PLGA HA/βTCP sem corante e com corante do que no grupo controle (p<0,01. O grupo com corante apresentou maior resposta do tipo corpo estranho, porém isto não interferiu na neoformação óssea. Não foi possível observar a presença do corante após os tempos transcorridos dos implantes. Conclusão: Os arcabouços de PLGA HA/βTCP sem e com corante, foram biocompatíves e capazes de induzir o crescimento do tecido ósseo, sendo apropriado como um biomaterial na engenharia tecidual.

  8. Comportamento tintorial do Mycobacterium leprae: revisão histórica Tinctorial behavior of Mycobacterium leprae: a historical review

    Directory of Open Access Journals (Sweden)

    Luiz Fernando de Góes Siqueira

    1983-08-01

    Full Text Available Foi feita revisão histórica sobre os corantes utilizados na identificação do Mycobacterium leprae. Foram analisadas para cada corante, sua composição química, propriedades tintoriais e a capacidade de assimilação pelo bacilo nas diversas técnicas de coloração.A historical review was made of the dyes utilized to identify the Mycobacterium leprae. The chemical composition and the tinctorial properties of these substances and the dye assimilation capacity of the bacilli were analyzed.

  9. Aplicação de tratamentos biológico e físico-químico em efluentes de lavanderia e tinturaria industriais do município de Toritama no estado de Pernambuco

    OpenAIRE

    Andréa Fernanda de Santana Costa

    2008-01-01

    Os corantes presentes em efluentes industriais são poluentes recalcitrantes que apresentam toxicidade aos seres vivos e são de difícil remoção por tratamentos convencionais. O processo de beneficiamento de jeans utiliza grande volume de água e produtos químicos diversos, incluindo os corantes sintéticos. O presente estudo investigou a influência de fatores biológicos e físico-químicos na remoção de cor e turbidez em tratamentos de efluentes de lavanderia e tinturaria industriais. Planejamento...

  10. Development and comparison of analytical techniques, liquid chromatography to high-efficiency and capillary electrophoresis, in the determination of artificial coloring

    OpenAIRE

    Marcelo Alexandre Prado

    2003-01-01

    Resumo: O uso de corantes artificiais pelas indústrias de alimentos em todo o mundo é bastante difundido, isto porque os corantes permitem suplementar ou repor a coloração perdida durante o processamento e ou estocagem, e assim garantir a aceitabilidade do produto frente ao consumidor, sendo utilizados ainda como um importante instrumento para garantir a uniformidade dos produtos em linhas de produção de larga escala. Do ponto de vista da saúde pública, existem diferentes opiniões quanto à in...

  11. Atlas digital: uma contribuicao para o sistema de informacoes do municipio de Sao Joao de Meriti – RJ

    Directory of Open Access Journals (Sweden)

    Ricardo Araujo Mathias

    2011-07-01

    Full Text Available Um Atlas Digital é um atlas que pode ser acessado atraves de um computador, sendo possivel a utilizacao de uma variada gama de temas, formatos e escalas. Neste trabalho apresenta-se um prototipo de Atlas Digital como colaboracao ao Sistema de Informacao Municipal – SIM, para o municipio de Sao João de Meriti, RJ. O SIM tem como meta os servicos municipais, sendo as suas informacoes fundamentais para a melhoria da gestao das prefeituras. A pesquisa foi direcionada para o tema da habitabilidade, que consiste num conjunto de condicoes voltadas para a criacao de um habitat saudavel, conseguinte foram trabalhados os subtemas: infraestrutura de abastecimento de agua, esgoto, coleta de lixo, saude e educacao.

  12. Pedagogia etnomatemática: uma proposta para o ensino de matemática na educação básica

    Directory of Open Access Journals (Sweden)

    Francisco de Assis Bandeira

    2012-08-01

    Full Text Available As reflexoes apresentadas neste artigo sao parte de uma proposta de reorientacao curricular em educacao matematica que defende a utilizacao do conhecimento matematico vivenciado pelo aluno em sua comunidade como subsidio metodologico para o processo de ensino-aprendizagem da matematica escolar. Mas, a luz das concepcoes d.ambrosianas de Etnomatematica, principalmente, a educacional, que procura compreender a realidade sociocultural e chegar a acao pedagogica de maneira natural mediante um enfoque cognitivo com forte fundamentacao cultural. Para a concretizacao dessa proposta no campo educacional, busquei fundamentos legais, dentre os quais, os Parametros Curriculares Nacionais, que propoem ser apenas um documento de referencia para que as escolas organizem suas propostas curriculares. Nesse sentido, associei os blocos de conteudos dos Parametros Curriculares Nacionais do Ensino Fundamental da Matematica aos conhecimentos matematicos de uma comunidade de horticultores da Grande Natal/RN.

  13. Assessment of toxicity and genotoxicity of the reactive azo dyes Remazol Black B and Remazol Orange 3R and effectiveness of electron beam irradiation in the reduction of color and toxic effects; Avaliacao da toxicidade e genotoxicidade dos corantes azo reativos Remazol Preto B e Remazol Alaranjado 3R e da eficacia da radiacao com feixe de eletrons na reducao da cor e efeitos toxicos

    Energy Technology Data Exchange (ETDEWEB)

    Pinheiro, Alessandro de Sa

    2011-07-01

    The textile industries play an important role in national and global economy. But, their activities are considered potentially polluting. The use of large volumes of water and the production of colored wastewater with high organic matter are among the main issues raised, especially during the stage of dyeing and washing of the textile process. The reactive azo dyes are the main colors used in the industry for dyeing of cotton in Brazil and worldwide. Because of its low setting and variations in the fiber production process, about 30% of the initial concentration used in the dyeing baths are lost and will compose the final effluent. These compounds have a low biodegradability, are highly soluble in water and therefore are not completely removed by conventional biological processes. In addition, other processes do not promote degradation but the transference to solid environment. The dyes discarded without treatment in the water body can cause aesthetic modifications, alter photosynthesis and gas solubility, as well as being toxic and genotoxic. The main objectives of this study were to evaluate the toxicity and genotoxicity of two reactive azo dyes (Remazol Black B - RPB and Remazol Orange 3R - R3AR) and the percentage of color and toxicity reduction after the use of electron beam radiation. The acute toxicity assays performed with Vibrio fischeri, Daphnia similis and Biomphalaria glabrata showed different response patterns for dyes. The different chemical forms of dyes were slightly toxic to Vibrio fischeri and only the RPB dye (vinylsulphone) was toxic (EC50{sub 15min} = 6,23 mg L-1). In tests with Daphnia similis, the dye RPB was slightly toxic in its pattern form, sulphatoethylsulphone, (CE50{sub 48h} = 91,25 mg L{sup -1}) and showed no toxicity in other chemical forms. However, the RA3R dye was toxic to the dafnids and the vinylsulphone form very toxic (EC50{sub 48h} = 0,54 mg L-1). No toxicity was observed in Biomphalaria glabrata assays. Chronic toxicity was assessed with the organism Ceriodaphnia dubia and the NOEC and OEC values of RPB dye (sulphatoethylsulphone) were 12.5 and 25 mg L-1, respectively. After hydrolysis of the dye (vinylsulphone and hydroxyethyl sulphone) was shown to increase the values obtained from the NOEC and OEC. There was no chronic effect for the R3AR dye and its chemical forms to C. dubia. The comet assay adapted to haemocytes of Biomphalaria glabrata was used to assess the genotoxicity of the dyes. The RPB dye was genotoxic at highest concentrations (1 and 2 g L-1), with quantitative values of DNA damage equal to 117 and 112 and the R3AR dye was not genotoxic. The use of radiation with electron beams have proven effective in removing the color dyes. With a dose of 10 kGy a reduction of 97.64% and 96.8% for R3AR and RPB, respectively, was achieved. Possibly, the color removal was mainly due to the interaction of reactive species such as hydroxyl radicals generated in the radiolysis of water after the radiation beam of electrons. After radiation of the RPB dye a dose of 10 kGy reduced 59.52 % of the acute toxicity measured with Vibrio fischeri. For the other doses there was no significant reduction, as well as with Daphnia similis, where the values of EC50{sub 48h} obtained were smaller than the non-irradiated dye. The R3AR dye showed better decreased toxicity after radiation when compared with the RPB, with reductions of 82.95% (V. fischeri) and 71.26% (D. similis) with 10 kGy. (author)

  14. Influência de eletroconvulsões sôbre a permeabilidade da barreira sangue-cérebro ao azul tripan

    Directory of Open Access Journals (Sweden)

    Jaderson Costa da Costa

    1972-03-01

    Full Text Available Foi estudada a influência de eletroconvulsões sôbre a permeabilidade da BSC ao azul tripan, em ratos. Para a indução de eletroconvulsões foram usados eletródios corneais de Spiegel e um estimulador. A avaliação da permeabilidade da BSC foi feita mediante exame macro e microscópico do encéfalo de animais injetados com azul tripan, corante que normalmente não tinge o SNC. Foi verificado que as únicas estruturas intracranianas coradas, tanto nos animais submetidos a eletroconvulsões antes da injeção do corante, como nos testemunhas que não receberam eletrochoques, foram as meninges e a epífise. A intensidade de coloração da epífise dependia do tempo de permanência do corante no espaço vascular. Entretanto, quando o corante foi injetado antes de submeter os animais a eletroconvulsões, ocorreu tingimento do SNC, pelo azul tripan. Sugere-se a existência de um mecanismo homeostático para manter a integridade do meio interno do neurônio.

  15. Le costruzioni percettive-letterarie del corpo: verso una psicobiologia letteraria del Sé di Alfonso Santarpia.

    OpenAIRE

    Santarpia, Alfonso

    2014-01-01

    International audience; Il visuale organico sembra promettere di svelare i segreti di quando pensiamo, di quando lottiamo, di quando amiamo e perché no, si saprà a breve anche quale area funzionale dell'encefalo si accen-derà o si spegnerà nell'attesa della morte. Plurime cartografie della nostra cognizione si svelano agli occhi degli scienziati (Damasio, 1995, 1999). Ma se un paziente fortemente ansioso vi racconta : ho gli occhi stanchi, lo stomaco mi brucia, il mio cervello ruota veloce co...

  16. Diagnóstico da agricultura orgânica no estado do Rio de Janeiro e propostas para sua difusão.

    OpenAIRE

    Assis,Renato Linhares de

    1993-01-01

    A agricultura organica tem sido citada recentemente por um numero cada vez maior de pessoas como uma opção viavel ao modelo agricola atual, o qual tem provocado sérios problemas ambientais e para saude humana. No entanto, pouco se tem observado como se da o processo de adocao deste sistema de producao por agricultores e consumidores para que se possa difundi-lo cada vez mais. A partir de entrevistas com produtores organicos fluminenses, procedeu-se a uma analise do processo de adocao deste ti...

  17. Manuel practico para el empleo de los materiales naturales en la construccion de terraplenes : Guide technique

    OpenAIRE

    LABORATOIRE CENTRAL DES PONTS ET CHAUSSEES - LCPC

    2003-01-01

    Este manual es un extracto de la Guia técnica "Construccion de terraplenes y explanadas", la GTR (acronimo del titulo en francés), publicada en Francia por el LCPC y el SETRA en septiembre de 1992. Sin embargo, este documento solo recoge de dicha guia técnica la parte referente a la classificacion de los suelos naturales (dicha "classificacion GTR" segun la norma francesa NF 11-300) y sus condiciones de utilizacion en terraplenes, excluyendo los suelos organicos y los subproductos industriale...

  18. Utilisation of gamma radiation of Cobalt-60 as quarantine treatment of medicinal plant, aromatic and seasoning plants dehydrated infested by Lasioderma serricorne (Fabricius, 1792) (Coleoptera, Anobiidae) and Plodia interpunctella (Hubner, 1813) (Lepidoptera, Pyralidae); Utilizacao da radiacao gama do Cobalto-60 como tratamento quarentenario de plantas medicinais, aromaticas e condimentares desidratadas infestadas por Lasioderma serricorne (Fabricius, 1792) (Coleoptera, Anobiidae) e Plodia interpunctella (Hubner, 1813) (Lepidoptera, Pyralidae)

    Energy Technology Data Exchange (ETDEWEB)

    Alves, Juliana Nazare

    2007-07-01

    The research had as objective the use of the gamma radiation of the Cobalto-60 as quarantine treatment of the medicinal plant, aromatic and seasoning plants dehydrated infested by Lasioderma serricorne and Plodia interpunctella determining the disinfestation doses to attend the criterion in the not emergency of adults of the species in study and analysing through the Chromatography of Thin Layer the effect of the gamma radiation of the cobalto-60 on the active principle of extract dehydrated of Chamomilla recutita, Pimpinella anisum, Origanum vulgare, Cymbopogon citratus, Ocimum basilicum and Thymus vulgaris. The work was developed in the Laboratorio de Inseticidas in the Instituto Biologico in Sao Paulo in the period of August of 2005 the June of 2007. The radiation source used gamma was an experimental irradiator of Cobalto-60, model Gamacell 220, located in the Instituto de Pesquisas Energeticas e Nucleares - IPEN, located in Sao Paulo. In the period of 30 days after the irradiation of the samples evaluated the number of adults emerged of Lasioderma serricorne and Plodia interpunctella, using the data of mortality for the analysis of Probit. Obtained 100% of not emergency of adults in the Lasioderma serricorne with the dose of 2,00 kGy and 100% of not emergency of adults in the Plodia interpunctella with the dose of 2,25 kGy. The Chromatographic Analysis of Thin Layer was to evaluate did not show chemical differences in the extracts analysed. (author)

  19. Use of gamma radiations as a quarternary process to control the orange fruit borer, Ecdytolopha aurantiana (Lima, 1927) (Lepidoptera, Tortricidae) on orange fruits (Citrus sinensis), variety 'pera' and observations on its effects on fruits quality; Utilizacao da radiacao gama como um processo quarentenario para o 'bicho furao' Ecdytolopha aurantiana (Lima, 1927) (Lepidoptera, Tortricidae) em laranja pera (Citrus sinensis), e o estudo dos seus efeitos sobre a qualidade dos frutos

    Energy Technology Data Exchange (ETDEWEB)

    Faria, Jose Tadeu de

    1997-07-01

    The objective of the present research was to determine if gamma radiations could be used as a quarentenary process against the orange fruit borer, Ecdytolopha aurantiana (Lima, 1927), infesting oranges of the variety 'Pera', beyond observations on some fruit quality parameters. To observe the gamma radiations effects on the insects, doses ranging from the control to 800 Gy were used, and to observe possible effects on fruits quality, the utilized doses ranges from the control to 500 Gy. To observe the gamma radiations effects on the insects, doses ranging from the control to 800 Gy were used, and to observe possible effects on fruits quality, the utilized doses ranged from the control to 500 Gy. It was observed that over 200 Gy avoid emergency of viable adults of the orange fruit borer. Only one single female, and even these with wing malformations, emerged at the dose of 300 Gy. Dose up to 500 Gy did not interfere on fruits weight loss nor on the period of conservation of the oranges. Acidity, Brix value and skin resistance against perforation also did not showed any changes due to radiations. The irradiation of green fruit induced into a smaller loss of weight than when the fruits were irradiated in the mature stage. (author)

  20. Perspective of using the sterile insect technique for Tobacco Budworms Heliothis virescens (Lepidoptera: Noctuidae) and Cotton Bollworm Helicoverpa armigera (Lepidoptera: Noctuidae) in cotton crop as an alternative method of control; Perspectiva de utilizacao da Tecnica do Inseto Esteril para lagarta da maca Heliothis virescens (Lepidoptera: Noctuidae) e lagarta do velho mundo Helicoverpa armigera (Lepidoptera: Noctuidae) na cultura do algodoeiro como um metodo alternativo de controle

    Energy Technology Data Exchange (ETDEWEB)

    Haddad, Gianni Queiroz

    2017-07-01

    Since the 1950s, scientists have used ionizing radiation to sterilize insects, which are released in nature to mate, but without any progeny. Known as the sterile insect technique (TIE), this method of insect control has traditionally used ionizing radiation to sterilize insects, a technique that does not generate residues, and can act in synergy with the other techniques within integrated pest management. For several years, Brazil has been fighting against the increase of pests, introducing new tactics and techniques within the IPM programs, to overcome the resistance of chemical products, such as: reducing the residues of agrochemicals; For some important crops of our country, we have a wide spectrum of pests occurring from the beginning to the end of the harvest, one of them is the cotton crop and among the key pests of this crop, we have some extremely important caterpillars, among them Heliothis virescens and Helicoverpa armigera These species are morphologically similar, the second being identified a few years ago in Brazil. There are still no studies in Brazil using TIE as an additional tool for Lepidoptera, therefore the purpose of this study was to evaluate the effect of doses of gamma radiation in the different phases of the evolutionary cycle of Heliothis virescens and Helicoverpa armigera, as well as to evaluate the sterility in generation P And the ability of insects to irradiate with non-irradiated insects. The pupal phase presented the best result because 75 Gy achieved sterility in Heliothis virecens and 100 Gy sterilized Helicoverpa armigera, therefore it contemplated the phase and dose chosen to evaluate the competition between the irradiated insects and the normal insects of both species. Both Heliothis virecens and Helicoverpa armigera presented a satisfactory result, as the irradiated insects managed to significantly reduce the viability of the eggs in a ratio of 9: 1: 1. (author)

  1. The environmental licensing processes of the offshore oil and natural gas exploration and production in the world and in Brazil: a comparative analysis considering the utilization of studies of the strategic environmental assessment; O processo de licenciamento ambiental das atividades de exploracao e producao de petroleo e gas natural offshore no mundo e no Brasil: uma analise comparativa considerando a utilizacao de estudos de avaliacao ambiental estrategica

    Energy Technology Data Exchange (ETDEWEB)

    Mariano, Jacqueline [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE). Programa de Planejamento Energetico

    2004-07-01

    This study presents an analyses of the environmental licensing processes of the offshore oil and gas exploration and production of the following countries: USA, UK, Norway, Australia and Canada, and makes a comparison with the Brazilian case. This study also emphasizes the use of the Strategical Environmental Assessments (SEA) before the bid procedures. The SEA studies aim to predict and to evaluate the environmental implications of the adoption of sectorial policies and programs and are very useful to the decision making processes. They permit the exclusion of environmental sensitive areas and contribute to the improvement of the environmental management of the regions where the activities will take place. The selected countries use SEA as an environmental management tool and their experience is analysed so as to provide suggestions for the improvement of the current Brazilian environmental licensing process. (author)

  2. Comparative study of perovskites obtained by using polymeric precursors with composition La{sub 0,6}Ca{sub 0,4}(Co, Mn)O{sub 3} for use in combustion catalysis; Estudo comparativo de perovsquitas obtidas pelo metodo dos precursores polimericos com composicao La{sub 0,6}Ca{sub 0,4}(Co, Mn)O{sub 3} para utilizacao em catalise de combustao

    Energy Technology Data Exchange (ETDEWEB)

    Paiva, Ana Karenina de Oliveira; Wanderley, Jose Bruno de Moura; Batista, Jonathan Jalles Silva; Borges, Filipe Martel de Magalhaes; Melo, Dulce Maria de Araujo, E-mail: kareninapaiva@hotmail.com [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

    2012-07-01

    Materials with the perovskite structure are potential catalysts to reduce emissions of pollutants components into the environment. In the synthesis of perovskites, several methods have been proposed. In this work, lanthanum manganate compositions and lanthanum cobaltate with partial substitution of calcium (La{sub 0.6}Ca{sub 0.4}MnO{sub 3} and La{sub 0.6}Ca{sub 0.4}CoO{sub 3}, respectively), were synthesized using the polymeric precursor method. The powders obtained after 4h at 300° C (5° C/min), were calcined at temperatures of 700 and 900° C for 4 h (10° C/min), and characterized by X-ray Diffraction and Scanning Electron Microscopy. Comparing the X-ray Diffraction of the compositions manganate and lanthanum cobaltate, as the temperature increases, there is an increase in crystallinity, even more evident in manganate. TG curves showed similar thermal stabilities, with greater weight loss for the material cobaltate. The perovskites obtained were single phased, nanometric and had good porosity, making these potential catalysts appropriate properties for application in combustion reactions (author)

  3. Development of a geographical data base and its utilization in elaboration of maps of environmental sensitivity to the oil spill in the coastal area between Galinhos and Sao Bento do Norte, RN (Brazil); Desenvolvimento de um banco de dados geograficos e sua utilizacao na elaboracao de mapas de sensibilidade ambiental ao derramamento de oleo na area costeira entre Galinhos e Sao Bento do Norte - RN

    Energy Technology Data Exchange (ETDEWEB)

    Castro, Angelica Felix de; Amaro, Venerando Eustaquio; Vital, Helenice; Aloise, Dario Jose [Rio Grande do Norte Univ., Natal, RN (Brazil). Programa de Recursos Humanos da ANP para o Setor Petroleo e Gas, PRH-22. Formacao em Geologia, Geofisica e Informatica

    2003-07-01

    The coastal areas located in the northern coast of the Rio Grande do Norte State, specifically between the districts of Galinhos e Sao Bento do Norte, characterized by constant processes of coastal and eolic transport, causing erosion, alterations in the sediments and modifications in the coast line. Beyond of those natural factors, there is the proximity to Polo Petrolifero of Guamare, the largest terrestrial producer of petroleum of Brazil. The first part of that work consisted of to elaborate and to develop a Geographical Database (BDG), to store all the existent data of the study area, such as geological and geophysical data, hydrodynamic data, products of remote sensing, thematic maps, among others. The second stage of this work aimed to develop starting from the data previously stored in BDG, Oil-Spill Environmental Sensitivity Maps (Maps SAO). Those maps evaluate the reaction of the certain place if to happen an oil spill in her, supplying necessary information to the decision in cleaning and removal of the spilled oil. In that way, Maps SAO of the study area were elaborated in different teams to evaluate if there would be change of the behavior of the coast in the presence of the oil. (author)

  4. Tratamento de efluente tÃxtil utilizando o processo foto-fenton

    OpenAIRE

    Diego Ricieri Manenti

    2011-01-01

    O objetivo deste trabalho à avaliar o desempenho do processo foto-Fenton, utilizando energia solar e artificial como fontes de irradiaÃÃo UV, no tratamento de efluentes tÃxteis. Foram realizados experimentos preliminares para avaliar a eficiÃncia do processo foto-Fenton na mineralizaÃÃo e degradaÃÃo dos poluentes orgÃnicos e inorgÃnicos, bem como dos corantes sintÃticos. Para tanto, foi preparado o efluente tÃxtil sintÃtico pela mistura de seis corantes: Laranja TGL (C25H33ClN6O6S2), Azul FGL...

  5. Polymer electrolytes of poly (ethylene oxide) and polyvinylidene for application in TiO2/dye solar cells

    OpenAIRE

    Bruno Honda de Oliveira

    2011-01-01

    Resumo: As células fotoeletroquímica de TiO2/corante, que convertem energia solar em elétrica, são constituídas por fotoeletrodo de TiO2 modificado com um corante, contra-eletrodo de Pt e um eletrólito contendo o par redox I/ I3. Neste trabalho, investigaram-se eletrólitos constituídos por NaI/I2 dissolvido em uma matriz polimérica de poli(óxido de etileno), PEO, contendo 10% (em massa) dos polifluoretos polivinilideno (PVdF) e polivinilideno hexafluoro-propileno, PVdF-HFP. Inicialmente, aver...

  6. UTILIZAÇÃO DO CATALISADOR PENTÓXIDO DE NIÓBIO NA FOTODEGRADAÇÃO DE CONTAMINANTES

    Directory of Open Access Journals (Sweden)

    Aline Dias Martins

    2011-02-01

    Full Text Available Os diferentes resíduos produzidos pelo homem em diversas áreas representam grave problema ambiental, quando inadequadamente descartados. Foram realizados experimentos de fotodegradação de corantes utilizando o Nb2O5. O catalisador foi caracterizado por MEV, área superficial e FTIR. O Nb2O5 foi aplicado na fotodegradação dos corantes vermelho congo e verde malaquita, comparado com TiO2 e ZnO, na qual foi observado que apesar do mesmo apresentar uma cinética de degradação menor, o nióbio pode ser facilmente recuperado e reciclado. A utilização do Nb2O5 mostra-se interessante no sentido da recuperação do catalisador.

  7. DISTRIBUIÇÃO DE SUBSTRATOS NAS COLÔNIAS DE Atta laevigata (F. Smith, 1858 (HYMENOPTERA: FORMICIDAE

    Directory of Open Access Journals (Sweden)

    Moreira Aldenise Alves

    1999-01-01

    Full Text Available Estudou-se a distribuição de substratos em duas colônias adultas (L-1 e L-2 da saúva Atta laevigata (F. Smith, 1858, com áreas de terra solta de 26,10 e 31,30 m2. Alguns orifícios de abastecimento foram mapeados utilizando-se iscas de canudinhos plásticos impregnados com polpa cítrica. Depois selecionou-se três orifícios para o ninho L-1 e um orifício para o ninho L-2, onde foram colocadas iscas cítricas impregnadas com corantes azul, amarelo e vermelho e amarelo misturado com grãos de milho, respectivamente. Após 24 horas da colocação das iscas, as colônias foram mortas e escavadas totalmente. Durante a escavação, registrou-se a presença ou ausência dos corantes nas câmaras com cultura de fungo. Observou-se, neste trabalho, que as iscas com corantes distribuíram-se em todos os setores para os ninhos L-1 e L-2 e em todas as profundidades para o ninho L-1. No entanto, em L-2 encontrou-se corante nas profundidades de 1 a 4m, independentemente do local em que foram colocadas, indicando que as iscas formicidas colocadas em apenas um orifício de abastecimento da colônia, podem ser distribuídas uniformemente pelo ninho.

  8. Determinação simultânea de amarelo tartrazina e amarelo crepúsculo em alimentos via espectrofotometria UV-VIS e métodos de calibração multivariada

    Directory of Open Access Journals (Sweden)

    Mara Eliza dos Santos

    2010-12-01

    Full Text Available Os corantes sintéticos são usualmente adicionados a alimentos industrializados para conferir e restaurar a cor obtendo-se a qualidade estética desejada. Em função destes aspectos e do potencial toxicológico que alguns corantes podem apresentar, o controle de qualidade destes compostos é de fundamental importância. Neste trabalho, foi estudado o potencial das metodologias matemáticas como o princípio da aditividade, espectrofotometria derivativa e técnica multivariada (Regressão por Mínimos Quadrados Parciais - PLSR na determinação simultânea de dois corantes alimentícios: Amarelo Crepúsculo (AC e Amarelo Tartrazina (AT, extraídos com lã natural. Estas metodologias foram avaliadas e comparadas em função das suas capacidades de previsão, sendo que o modelo PLSR otimizado (faixa espectral de 305 a 645 nm, empregando-se 1ª derivada como transformação dos dados e 2 componentes principais apresentou o menor valor de Raiz Quadrada da Soma dos Erros de Previsão (RMSEP (AT = 0,191 e AC = 0,102. A faixa de concentração estudada foi de 1,0 a 16,0 mg.L-1 para AC e de 2,0 a 22,0 mg.L-1 para AT. O conjunto de validação externa apresentou erros relativos médios de 1,97% para AC e 1,39% para AT. A aplicação desta metodologia em amostras reais mostrou que em todas as amostras analisadas as concentrações destes corantes estavam de acordo com os limites estabelecidos pela legislação brasileira

  9. Efeito da luz e da temperatura de congelamento sobre a estabilidade das antocianinas da pitanga roxa The effects of light and freezing temperature upon the stability of purple surinam cherry's anthocyanins

    Directory of Open Access Journals (Sweden)

    Vera Lúcia Arroxelas G. de Lima

    2005-03-01

    Full Text Available As antocianinas são corantes naturais que podem ser utilizadas como alternativa em substituição aos corantes sintéticos. Entretanto, a baixa estabilidade destes compostos é o principal fator que dificulta sua aplicação como corante em alimentos. Frente à escassez de estudo sobre o pigmentos antociânicos da pitanga roxa, este trabalho teve como propósito avaliar a sua estabilidade à luz e ao congelamento. Utilizando a leitura de absorbância do extrato antociânico submetido às condições experimentais foi evidenciado que a luz reduziu o seu tempo de meia-vida, enquanto que a temperatura de congelamento exerceu pequeno efeito na degradação dos pigmentos.Anthocyanins are natural colorants that can be used as alternative to synthetic dyes. However, the low stability of these compounds is the main drawback in their application as food colorants. Since the information on anthocyanin pigments in Surinam cherry is scarce, the purpose of this investigation was to assess their stability to light and freezing storage. The anthocyanin extract absorbance, under the experimental conditions, showed that light incidence reduced the half-life of anthocyanin extract; meanwhile the freezing storage had little effect on these pigments degradation.

  10. Determinação de ferro (III em produtos farmacêuticos por titulação fotométrica = Determination of iron (III in pharmaceutical products by photometric titration

    Directory of Open Access Journals (Sweden)

    Airton Vicente Pereira

    2011-01-01

    Full Text Available Este trabalho descreve a montagem de um sistema de titulacao fotometrica simples e de baixo custo para a determinacao de ferro (III em produtos farmaceuticos. O sistema de titulacao fotometrica foi construido utilizando-se a bomba peristaltica de um espectrofotometro convencional. O procedimento e baseado na titulacao de ferro (III com EDTA e acido salicilico como indicador. A absorcao do complexo ferro (III-acido salicilico foi monitorada espectrofotometricamente em 525 nm. O limite de quantificacao foi de 5 ƒÝg de ferro (III. O procedimento de titulacao fotometrica foi aplicado para a determinacao de ferro (III em amostras contendo sulfato ferroso e hidroxido ferrico polimaltosado. O procedimento mostrou sensibilidade, reprodutibilidade e precisao para a utilizacao em analise rotineira de ferro (III em produtos farmaceuticos.This paper describes a simple, precise and low-cost photometrictitration method for iron (III determination in pharmaceutical preparations. The photometric titration system was constructed using the peristaltic pump of a conventional spectrophotometer. The method is based on titration of iron (III with EDTA using salicylic acid as indicator. The absorption of the iron (III-salicylic acid complex wasmonitored spectrophotometrically at 525 nm. The limit of quantification was 5 ƒÝg of iron (III. The photometric titration procedure was applied for the determination of iron (III in samples of ferrous sulfate and ferric hydroxide polymaltose complex. The procedure showed sensibility, reproducibility and accuracy for use as a method for the routine analysis of iron (III in pharmaceutical formulations.

  11. Using compound SiO{sub 2}(62-68)-MgO+CaO(29-39) in the protections of ceramics of steel company to replace the CaO-Al{sub 2}O{sub 3}-SiO{sub 2} compound; Utilizacao do composto SiO{sub 2}(62-68)-MgO+CaO(29-39) nas protecoes ceramicas de empresa siderurgica em substituicao ao composto CaO-Al{sub 2}O{sub 3}-SiO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Nogueira, Anderson Carvalho; Silva, Paula Cipriano da; Vernilli Junior, Fernando; Santos, Claudinei dos; Magnago, Roberto de Oliveira [Centro Universitario de Volta Redonda (UNIFOA), Volta Redonda, RJ (Brazil); Lima, Leonardo Moreira de [Universidade de Sao Paulo (USP), Lorena, SP (Brazil)

    2014-12-15

    This article describes the use of protective ceramic composed of SiO{sub 2}(62-68)-MgO + CaO(29-39) in the frontal region of the machines that inject mass refractory to stop racing pig iron and slag liquid in blast furnaces. The new protection model (prototype) showed a annual saving of approximately R$ 32,000.00 compared to the compound previously used CaO-Al{sub 2}O{sub 3}-SiO{sub 2}. Also had a lower toxicity, as it has in its morphology least amount of fiber. These fibers when inhaled cause damage to internal tissues of the lungs is harmful to health. There maintenance rates of production, since in all samples tested the new ceramic protection, the front part was preserved allowing the refractory mass injection quantity and pressure required for reconstitution of the length of the bore which removes iron and slag inside the high oven, allowing for a larger internal volume to produce more. The protection models were produced by Morganite-Brazil. The morphology and crystallographic characterization were characterized by Scanning Electron Microscopy and X-ray diffraction, respectively. (author)

  12. Realismo. Quale ritorno?

    Directory of Open Access Journals (Sweden)

    Giacomo Tinelli

    2014-12-01

    Full Text Available La lettura di Ipermodernità – dove va la narrativa contemporanea di Raffaele Donnarumma è un passaggio imprescindibile per la comprensione del dibattito, attuale e vivissimo, sulle vie contemporanee della narrativa italiana e occidentale. E non solo perché si tratta di una rassegna ampia e ragionata del presente letterario, che propone alcune coordinate per muoversi nella contemporaneità – operazione difficoltosa a causa della prossimità temporale dell’oggetto d’indagine –, ma anche per il tentativo di declinare in ambito letterario la proposta del ritorno alla realtà che ha nel Manifesto del nuovo realismo (2011 di Maurizio Ferraris il suo programma filosofico. Il libro raccoglie anni di articoli e dibattiti, condotti in gran parte sulle pagine di Allegoria, ed ha il merito di comporre in modo organico e complessivo un discorso rimasto fino ad ora relativamente frammentario.

  13. Novel organic solvent-tolerant esterase isolated by metagenomics: insights into the lipase/esterase classification Nueva esterasa tolerante a los solventes orgánicos aislada por metagenómica: ideas sobre la clasificación de las esterasas/lipasas

    Directory of Open Access Journals (Sweden)

    Renaud Berlemont

    2013-03-01

    Full Text Available In order to isolate novel organic solvent-tolerant (OST lipases, a metagenomic library was built using DNA derived from a temperate forest soil sample. A two-step activity-based screening allowed the isolation of a lipolytic clone active in the presence of organic solvents. Sequencing of the plasmid pRBest recovered from the positive clone revealed the presence of a putative lipase/esterase encoding gene. The deduced amino acid sequence (RBest1 contains the conserved lipolytic enzyme signature and is related to the previously described OST lipase from Lysinibacillus sphaericus 205y, which is the sole studied prokaryotic enzyme belonging to the 4.4 a/ß hydrolase subgroup (abH04.04. Both in vivo and in vitro studies of the substrate specificity of RBest1, using triacylglycerols or nitrophenyl-esters, respectively, revealed that the enzyme is highly specific for butyrate (C4 compounds, behaving as an esterase rather than a lipase. The RBest1 esterase was purified and biochemically characterized. The optimal esterase activity was observed at pH 6.5 and at temperatures ranging from 38 to 45 °C. Enzymatic activity, determined by hydrolysis of p-nitrophenyl esters, was found to be affected by the presence of different miscible and non-miscible organic solvents, and salts. Noteworthy, RBest1 remains significantly active at high ionic strength. These findings suggest that RBest1 possesses the ability of OST enzymes to molecular adaptation in the presence of organic compounds and resistance of halophilic proteins.Con el fin de aislar nuevas variantes de lipasas tolerantes a solventes organicos (OST, se construyo una libreria metagenomica a partir de ADN obtenido de una muestra de suelo de bosque templado. A traves de un monitoreo en dos etapas, basado en la deteccion de actividades, se aislo un clon con actividad lipolitica en presencia de solventes organicos. La secuenciacion del plasmido pRBest recuperado del clon positivo revelo la presencia de un

  14. L’ecologia umana tra sistemi naturali e sistemi sociali

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    Claudio Ricciardi

    2008-12-01

    Full Text Available I rischi ambientali che la salute umana si trova oggi ad affrontare si manifestano sempre più in una indistinguibile separazione dai sistemi sociali. Una visione scientista e riduttiva che relegava l’umano ad un esclusivo materiale organico ha sempre sottratto ad esso ogni significato sociale, culturale e politico. Il passaggio dauna suscettibilità genetica ristretta per alcuni ad una vulnerabilità generalizzata per tutti porta a considerazioni etiche sostanziali. La tutela della salute di noi esseri umani passa inevitabilmente attraverso la tutela dell’ambiente che per le sue qualità e condizioni deve consentire a tale vulnerabilità e dipendenza di poter continuare ad esistere.

  15. Phytoplanktonic composition of three cultivation systems used in Litopenaeus vannamei (BOONE, 1931 marine shrimp farms = Composição fitoplanctônica em três sistemas de cultivo do camarão marinho Litopenaeus vannamei (BOONE, 1931

    Directory of Open Access Journals (Sweden)

    Michelle Pereira Melo

    2010-07-01

    Full Text Available The aim of this work is to assess the different compositions of phytoplankton in three cultivation systems of marine shrimps Litopenaeus vannamei (BOONE, 1931, denominated as organic, intensive and semi intensive. The samples were done fortnightly, when phytoplankton was collected by a net for phytoplankton, 65 ƒÊm mesh, being then filtrated in a total volume of water of 100 L, and preserved in formaldehyde solution at 4% and identified according to the methodology of Cordeiro et al. (1997. The results show that the densities of Diatoms were of 16.65, 10.47 and 7.57 cel. 103 mL-1 for the organic, intensive and semi intensive cultivations, respectively. As for cyanobacteria, the average figures were 42.06 cel. 103 mL-1 forsemi intensive 17.27 cel. 103 mL-1, in the intensive cultivation and 6.11 cel. 103 mL-1 for the organic cultivation system. The dinoflagellates had the highest cellular density in the phytoplankton community analyzed with 61.9 cel. 103 mL-1 in the intensive cultivation, 0.33 and 0.03 cel. 103 mL-1 for both semi intensive and organic cultivation systems respectively. Euglenas presented the results of 4.98 and 14.86 cel. 103 mL-1 only for semi intensive and intensive cultivations. It was then concluded that all cultivations presented average rates below recommended for such studied systems.Conduziu-se esse trabalho com o objetivo de avaliar as diferentes composicoes fitoplanctonicas em tres sistemas de cultivo para o camarao marinho Litopenaeus vannamei (BOONE, 1931, denominados de organico, intensivo e semiintensivo. As amostragens foram realizadas quinzenalmente, onde o fitoplancton foi coletado atraves de uma rede de plancton, com malha de 65 ƒÊm, sendo filtrado um volume de agua total de 100 litros, que foram preservadas em solucao de formol a 4% e identificadas segundo a metodologia de Cordeiro et al. (1997. Os resultados mostram que as densidades de diatomaceas foram de 16,65; 10,47 e 7,57 cel. 103 mL-1, respectivamente

  16. La psicoanalisi e l'artista (1928

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    Ernest Jones

    2010-12-01

    Full Text Available Si tratta di un saggio teorico fondamentale nel panorama delle prime ricerche psicoanalitiche sull’arte, in cui Jones cerca di organizzare in una sintesi originale ed avanzata il pensiero estetico di Freud come si era venuto evolvendo fino ad allora. Per il lettore contemporaneo, informato sugli sviluppi della cosiddetta psicoanalisi dell’arte, il saggio, pur nell’esemplare chiarezza e rigore teorico, certo non presenta risvolti nuovi o inaspettati; ma se si tiene conto della data di pubblicazione (l928, del vasto respiro di questa sintesi, della problematicità dell’impostazione, la sua importanza appare evidente. Jones, pur dimostrandosi un perfetto seguace delle idee freudiane, riesce a coordinare in un sistema organico e omogeneo le sparse osservazioni del maestro sul problema dell’arte, sviluppando per altro quelle intuizioni che, pur non essendo state da Freud strettamente collegate al problema estetico, vengono tuttavia ad arricchire e integrare la sua interpretazione dell’arte.

  17. Synthesis and evaluation of Pt-alloys supported on MWCNTS as ethylene glycol-tolerant ORR cathodes

    Energy Technology Data Exchange (ETDEWEB)

    Morales-Acosta, D.; Arriaga, L.G. [Centro de Investigacion y Desarrollo Tecnologico en Electroquimica, Pedro Escobedo, Queretaro (Mexico); Alvarez-Contreras, L. [Centro de Investigacion en Materiales Avanzados S. C., Chihuahua, Chihuahua (Mexico); Fraire Luna, S.; Rodriguez Varela, F.J. [Cinvestav, Unidad Saltillo, Ramos Arizpe, Coahuila (Mexico)]. E-mail: javier.varela@cinvestav.edu.mx

    2009-09-15

    In this work, a Pt-Co/MWCNT alloy (atomic ratio 70:30) was synthesized and evaluated as oxygen reduction reaction (ORR) cathode for Direct Ethylene Glycol Fuel Cells (DEGFC) applications. The alloy showed good performance for the ORR in acid medium, while in the presence of 0.125M EG (C{sub 2}H{sub 6}O{sub 2}) the MWCNTs-supported electrocatalyst showed a very high selectivity for the cathodic reaction and a high degree of tolerance to the organic fuel, i.e., a very small shift in the onset potential for the ORR, Eonset, and no peak current densities associated to the oxidation of EG, a detrimental effect of organic fuels normally observed in the case of Pt-alone electrocatalysts. [Spanish] En este trabajo, se sintetizo y evaluo una aleacion Pt-Co/NTCMP (razon atomica 70/30) como catodo de reaccion de reduccion de oxigeno (RRO) para aplicaciones de celdas de combustible de glicol de etileno directo (CCGED). La aleacion mostro buen desempeno para la RRO en medio acido, en tanto que la presencia de 0.125M de GE (C{sub 2}H{sub 6}O{sub 2}) del electrocatalizador soportado por NTCMP mostro una muy alta selectividad para la reaccion catodica y un alto grado de tolerancia al combustible organico, es decir, un corrimiento muy pequeno del potencial de inicio para la RRO, Einicio, y no densidades de corriente asociadas a la oxidacion del GE, efecto perjudicial de los combustibles organicos que se observa en el caso del electrocatalizadores solo de Pt.

  18. The efficiency of sand filters for the treatment of drinking water. A case study; Studio sull'efficienza di filtri a sabbia per la potabilizzazione dell'acqua

    Energy Technology Data Exchange (ETDEWEB)

    Moreno, M.; Marrale, D.; Fabiano, M. [Genoa Univ., Genoa (Italy). Dipt. per lo Studio del Territorio e delle sue Risorse; Palumbo, F. [Servizi Tecnologici e Ambientali SpA, Genoa (Italy)

    2001-10-01

    The efficiency of a drinking water treatment plant was investigated through the study of biochemical and microbial measures of the sand filter and the structure of the meiobenthic community. Filter and water samples were taken monthly and according to the different operation time. The efficiency of the biofilm was evaluated by the study of both structural (i.e. organic load before and after filtration, bacterial and meiobenthic density) and functional parameters (i.e. bacterial enzymatic activity and Frequency of Dividing Cells) and the analysis of the particulate organic material. The filters showed a high bacterial density and metabolic activity. The meiobenthic community, composed mainly by rotifers, nematodes and copepods, displayed a high degree of biodiversity during the studied period. The informative value of all the considered parameters and the efficiency of the filter during the operating period are discussed. [Italian] In un impianto di potabilizzazione delle acque l'analisi quali-quantitativa delle caratteristiche biochimiche e microbiche di un filtro a sabbia e del comparto acquatico associato ha permesso di valutare l'efficienza del sistema filtrante. I prelievi sono stati effettuati mensilmente in corrispondenza di differenti momenti operativi del filtro. Sono stati presi in considerazione aspetti funzionali, quali le attivita' idrolitica e duplicativa della comunita' batterica, e descrittivi (carico organico pre- e post-filtrazione, densita' batteriche e meiobentoniche). La valutazione relativa al materiale organico sospeso ha permesso di stimare l'efficienza di abbattimento attuata dal biofilm. I filtri presentano densita' batteriche molto elevate ed attivamente metabolizzanti. La comunita' meiobentonica, dominata da rotiferi, nematodi e copepodi, e' pero' sempre caratterizzata da un grado elevato di biodiversita'. Viene infine discusso il valore informativo dei diversi parametri e indici

  19. DESENVOLVIMENTO E AVALIAÇÃO DA QUALIDADE DE SORVETE DE IOGURTE SIMBIÓTICO, DE LEITE DE BÚFALA ENRIQUECIDO COM POLPA DE AÇAÍ (Euterpe oleracea

    Directory of Open Access Journals (Sweden)

    MONTEIRO, Ranna Catarine da Rocha

    2015-11-01

    sacarose. Após, o iogurte foi dividido para obter quatro formulações de sorvete, F1 - com gordura vegetal e corante; F2 - com gordura vegetal sem corante; F3 - com nata e corante e F4 - com nata sem corante, para verificar a gordura mais acessível e o comportamento do consumidor em relação à adição de corante. Na avaliação das características físico-químicas, a F1 se destacou significativamente (p0,05. De acordo com a análise microbiológica os derivados estavam adequados para consumo humano. Assim, a elaboração do sorvete de iogurte enriquecido com açaí, é viável pela sua funcionalidade e valor agregado, com uso de nata ou gordura vegetal e adição de corante.

  20. Manobras de hiperinflação manual podem causar aspiração de secreções orofaríngeas em paciente sob ventilação mecânica?

    Directory of Open Access Journals (Sweden)

    Armando Carlos Franco de Godoy

    2011-10-01

    Full Text Available JUSTIFICATIVA E OBJETIVO: Avaliar se manobra de hiperinsuflação manual (HM pode propiciar aspiração das secreções orofaríngeas em paciente sob ventilação mecânica. MÉTODOS: Participaram do estudo pacientes adultos sob ventilação mecânica nos quais foi injetado corante na cavidade orofaríngea e aspirada secreção traqueal após 30 minutos (min. Na ocorrência de deslizamento do corante, o paciente foi eliminado. Os demais foram alocados em Grupo Controle: pacientes em que se aspiravam secreções traqueais após 30, 60, 120 e 180 min e Grupo Experimental: após 30 min, foram realizadas manobras de HM e aspirada secreção nos intervalos estabelecidos. RESULTADOS: Estudaram-se 43 pacientes. Em 13, ocorreu deslizamento do corante após 30 min antes da alocação dos grupos. Os demais 29 pacientes forneceram 226 amostras de secreções. Houve presença de secreções coradas em apenas duas amostras, após realização de HM, em pacientes do grupo experimental. CONCLUSÃO: A manobra de hiperinflação manual não propiciou aspiração de secreções orofaríngeas em paciente sob ventilação mecânica.

  1. Estudo sôbre a célula leprosa do rato

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    Hermínio Linhares

    1944-04-01

    Full Text Available Onze ratos com lepra murina em periodo muito adiantado, foram inoculados várias vezes com litio carmin e azul pirrol. Foi possível evidenciar nestes onze ratos que as células que englobam as partículs do corante, na coloração vital, eram as mesmas que continham os bacilos. Vêem-se mesmo num únoco elemento celular os grãos de corante e os bacilos. Em cortes da pele é possível observar-se a transformação dos histiocitos do tecido cojuntivo frouxo em células leprosas. Em órgãos internos examinados, sempre se verificou que a célula leprosa provinha de um elemento do sistema retículo endotelial e grânulos de corante juntamente com bacilos foram encontrados nas células do retículo-endotélio do baço, medula óssea gânglios linfáticos, células de Kupffer e histiocitos do pulmão.Eleven infect rats with murine leprosy were inoculated several time with lithiocarmine and pyrrole blue. One can see that the same cells which phagocytize the dye granules, in vital staining, were the same which contained bacilli. One can observe in the cell both dye particles and staining bacilli together. It is possible to see the transformation of the histiocytes into lepra cells. In inner organs examined we have always ascertained that the lepra cell was derived from an element of the reticuloendothelial system and the dye particles and bacilli were seen in the cells of reticulo-endothelium of the spleen, bone marrow, lymph nodes, Kupffer cells and lung histiocytes.

  2. Utilização da terapia fotodinâmica associada ou não ao hipoclorito de sódio na instrumentação de canais radiculares contaminados com Enterococcus faecalis

    OpenAIRE

    Lilian Ferreira Freitas

    2009-01-01

    O presente trabalho teve por objetivo avaliar a ação do laser de baixa intensidade associado ao corante azul de toluidina, como agente bactericida durante a fase de instrumentação dos canais radiculares, comparando sua utilização associada ou não ao hipoclorito de sódio 0,5%. Para tal, 90 caninos humanos foram instrumentados, autoclavados e 88 imersos em caldo TSB(Tryptcase Soy Broth). Em seguida foram inoculados com suspensão de E. faecalis e incubados em estufa a 37C, por 72 horas, para per...

  3. Caracterização de lacase de Peniophora cinerea e estudo do potencial de aplicação biotecnológica

    OpenAIRE

    Sergio Luiz Moreira Neto

    2012-01-01

    No presente estudo, fungos ligninolíticos isolados de ecossistemas brasileiros foram avaliados quanto a capacidade de descolorir corantes reativos e, a linhagem Peniophora cinerea, selecionada, teve seu sistema ligninolítico caracterizado. As lacases deste fungo foram avaliadas para duas aplicações: descoloração de efluentes têxteis e auxílio na hidrólise enzimática do bagaço de cana-de-açúcar. Lacase foi a única enzima ligninolítica extracelular detectada nos culivos de P. cinerea. A produçã...

  4. Tecnologia eletroquímica como tratamento alternativo de efluentes derivados da indústria têxtil e petroquímica

    OpenAIRE

    Rocha, Jéssica Horacina Bezerra

    2014-01-01

    Neste trabalho, o tratamento de efluentes da indústria têxtil, contendo corantes como Amarelo de Novacron (YN), Vermelho de Remazol BR (RRB) e Azul de Novacron CD (NB), e o tratamento de efluentes da indústria do petróleo (água produzida), foram investigadas por oxidação anódica (AO) com ânodos de Platina suportada em titânio (Ti/Pt) e Diamante Dopado com Boro (DDB). Certamente, um dos principais parâmetros neste tipo de tratamento é o tipo de material eletrocatalítico utilizad...

  5. Excipientes de medicamentos e as informações da bula

    OpenAIRE

    Aracy Pereira Silveira Balbani; Lucilena Bardella Stelzer; Jair Cortez Montovani

    2006-01-01

    OBJETIVO: Avaliar a presença de conservantes, corantes, adoçantes e aromatizantes em 73 apresentações farmacêuticas de 35 medicamentos para uso oral, e as informações da bula sobre excipientes. MÉTODOS: Selecionamos 35 medicamentos, de venda livre ou sob prescrição médica, comercializados no Brasil. A amostra incluiu: analgésicos/antitérmicos, antimicrobianos, mucolíticos, antitussígenos, descongestionantes, anti-histamínicos, broncodilatadores, corticosteróides, antiinflamatórios e suplement...

  6. Plantas Tintureiras Dye Plants

    Directory of Open Access Journals (Sweden)

    Maria do Carmo Serrano

    2008-12-01

    Full Text Available Existe uma vasta bibliografia, até ao séc. XVIII, sobre plantas produtoras de corantes naturais, sendo que apenas um número limitado foi utilizado no tingimento de têxteis antigos, devido à capacidade de resistência à lavagem e ao desvanecimento. O cultivo de plantas ou a sua existência no mundo silvestre tiveram uma enorme importância sócio-económica para muitas comunidades espalhadas pelo mundo e pelas intensas trocas comerciais que geraram. A extracção dos corantes era feita a partir de diferentes partes de plantas ou árvores. Nalgumas plantas eram utilizadas as folhas, enquanto noutras se aproveitavam as flores, as raízes, os frutos, troncos ou sementes. Os corantes podiam ser extraídos através de processos complexos que envolviam diversas operações como maceração, destilação, fermentação, decantação, precipitação, filtração, etc. Neste âmbito, são apresentadas algumas das plantas cultivadas em Portugal e em muitos outros países europeus e que foram usadas em tinturaria. Este trabalho pretende ser um contributo para obstar à perda de conhecimentos das condições de cultivo e da forma como se maximizava a produção de corantes.A vast bibliography exists, until the 18th cen-tury, on natural dyes obtained from plants, but only one limited number was used in the dyeing of old textiles, due to capacity of resistance to wash and light fading. The culture of plants or its existence in the wild world had an enormous economical importance for many communities spread for the world, and the intense commercial exchanges that had generated. The extraction of dyes was done from different parts of plants or trees. In some plants was used the leaves, others, only the roots, the fruits, trunks or seeds. The dyes could be extracted through complex processes that involved various operations as maceration, distillation, fermentation, decantation, precipitation, filtration, etc. In this scope, some of the plants cultivated in

  7. Análise microestrutural da polpa de amora-preta (Rubbus spp.) co-cristalizada por sacarose

    OpenAIRE

    Cheriegate, Ana Paula de Souza Corrêa

    2013-01-01

    Resumo: Os objetivos do presente trabalho foram analisar as microestruturas formadas pela co-cristalização da sacarose sobre a matriz da polpa de amora-preta, nas proporções de sacarose:polpa de amora de 90:10, 85:15 e 80:20, de maneira a promover uma alternativa de uso da amora-preta como corante natural para produtos alimentícios e farmacêuticos. As duas primeiras proporções produziram co-cristais, todavia a proporção de 80:20 produziu um produto semi-sólido, e não cristalizou completamente...

  8. Biodegradation of erythrosin B dye by paramorphic Neurospora crassa 74A

    Directory of Open Access Journals (Sweden)

    Gisele Jane de Jesus

    2010-04-01

    Full Text Available The present work used paramorphic forms of Neurospora crassa 74A to remove erythrosine. The fungus culture was grown in medium containing the dye, as only carbon source for 2 and 90 h of interaction. A washing process using distilled water isolated the cellular mass mycelia was dried for 12 h at 105ºC and transformed in fine powder and analyzed in FTIR. The supernatant was analyzed through spectrophotometer UV-Vis and FTIR. Significant differences in the spectrum of UV-VIS and FTIR were observed between the control and the supernatant and between wall control and the walls colored by red, in FTIR for 2 and 90 h. Some significant bands were modified, suggesting the possibility of enzymatic biodegradation in proportion to the time of contact between the dye and fungal biomass.O presente trabalho utilizou formas paramorfogênicas de Neurospora crassa 74A linhagens, na remoção do corante "Erythrosin B". O fungo, induzido química e fisicamente em forma de "pellets", foi usado no estudo da biodegradação deste corante. A cultura fúngica foi crescida em meio contendo o corante, como única fonte de carbono por 2 e 90h de interação. As paredes celulares foram isoladas por um processo de lavagem em água destilada e o micélio fresco foi secado por 12 h a 105ºC, e transformado num pó fino, e analisado em FTIR. O sobrenadante foi analisado através de espectrofotômetro UV-VIS e FTIR. Diferenças significativas no espectro UV-VIS e no FTIR foram observadas entre o controle e o sobrenadante e entre o controle e as paredes coloridas de vermelho e em FTIR no tempo de 2 e 90 h. Algumas bandas foram modificadas sugerindo a possibilidade de uma biodegradação enzimática em função do tempo de contato entre o corante e a biomassa fúngica.

  9. Microscopia de fluorescência e varredura em protoplastos de Citrus sinensis

    OpenAIRE

    de Mello, Paulo Cesar; Sartoretto, Laudete Maria; Soares Chaves, Ana Lúcia

    2011-01-01

    A tecnologia de isolamento de protoplastos é uma importante ferramenta para estudos da bioquímica e fisiologia da membrana plasmática e regeneração da parede celular. Protoplastos de laranja “Caipira” (Citrus sinensis L. Osbeck) foram enzimaticamente isolados a partir de células em suspensão e posteriormente cultivados em meio líquido. Este trabalho teve por objetivo avaliar a viabilidade de protoplastos de laranja “Caipira” recém isolados por meio do corante Diacetato de Fluoresceína (FDA), ...

  10. Otimização do processo de mineralização de compostos orgânicos utilizando sistemas eletro-Fenton e fotoeletro Fenton por irradiação UV artificial e solar

    OpenAIRE

    Lucio César de Almeida

    2011-01-01

    OTIMIZAÇÃO DO PROCESSO DE MINERALIZAÇÃO DE COMPOSTOS ORGÂNICOS UTILIZANDO SISTEMAS ELETRO-FENTON E FOTOELETROFENTON POR IRRADIAÇÃO UV ARTIFICIAL E SOLAR Processos eletroquímicos oxidativos avançados baseados na reação de Fenton, tais como eletro-Fenton (EF) e fotoeletro-Fenton por irradiação UV artificial (FEF) e solar (FEFS) foram empregados no tratamento de efluentes contendo compostos orgânicos (o corante têxtil AR 29 vermelho ácido 29, o fármaco paracetamol e o herbicida MCPA ácido 2-m...

  11. Pharmaceutical excipients and the information on drug labels

    OpenAIRE

    Aracy Pereira Silveira Balbani; Lucilena Bardella Stelzer; Jair Cortez Montovani

    2006-01-01

    OBJETIVO: Avaliar a presença de conservantes, corantes, adoçantes e aromatizantes em 73 apresentações farmacêuticas de 35 medicamentos para uso oral, e as informações da bula sobre excipientes. MÉTODOS: Selecionamos 35 medicamentos, de venda livre ou sob prescrição médica, comercializados no Brasil. A amostra incluiu: analgésicos/antitérmicos, antimicrobianos, mucolíticos, antitussígenos, descongestionantes, anti-histamínicos, broncodilatadores, corticosteróides, antiinflamatórios e suplement...

  12. Balanço de carbono em fotobiorreato com cultivo de Chlorella bulgaris em excesso de 'C 'O IND.2'

    OpenAIRE

    Mônica Regina Piovani

    2012-01-01

    Resumo: As microalgas são microrganismos que vem sendo utilizados na bioconversão de carbono em produtos com interesse comercial como, por exemplo, biocombustíveis, corantes, suplementos alimentares e cosméticos. Elas podem ser cultivadas em sistemas autotróficos e heterotróficas sendo que as fontes de carbono, gasosas ou líquidas, podem ser provenientes de resíduos industriais reduzindo os custos de sua produção. Para identificar quais os possíveis produtos gerados durante o cultivo o objeti...

  13. Avaliação in vitro da microinfiltração em cavidades classe II de molares decíduos, restaurados com resina composta auto e fotopolimerizável

    OpenAIRE

    Alessandro Leite CAVALCANTI; CHELOTTI Adolpho

    1999-01-01

    Estudou-se a microinfiltração marginal presente na interface da parede gengival de cavidades classe II em molares decíduos, restaurados com resina composta (auto e fotopolimerizável), através da penetração de uma solução corante. Os preparos cavitários apresentavam a parede gengival em esmalte e foram restaurados segundo 4 diferentes técnicas: 1) resina composta fotopolimerizável; 2) resina composta autopolimerizável; 3) resina composta auto e fotopolimerizável; e 4) ionômero de vidro/resina ...

  14. Influência do Hidróxido de Cálcio e do EDTA na Marcação da Infiltração Marginal de Azul de Metileno em Obturações de Canais Radiculares.

    OpenAIRE

    1999-01-01

    Com o objetivo de avaliar a influência do hidróxido de cálcio e do EDTA na marcação da infiltração marginal de corante azul de metileno a 2% em canais radiculares obturados pela técnica da condensação lateral, foram empregados 188 dentes incisivos centrais superiores humanos extraídos. Após serem instrumentados e impermeabilizados, foram divididos em 3 grupos de 60 elementos cada, sendo que outros 8 dentes foram utilizados como controle. Cada grupo foi dividido em 2 subgrupos, os quais, foram...

  15. Viabilidade do grão de pólen de acessos de capim-elefante, milheto e híbridos interespecíficos (capim-elefante x milheto = Pollen viability in elephantgrass, pearl millet and interspecific hybrids (elephantgrass x pearl millet acessions

    Directory of Open Access Journals (Sweden)

    Antônio Vander Pereira

    2006-01-01

    Full Text Available O objetivo deste trabalho foi estimar a viabilidade do pólen em acessos de capim-elefante, milheto e híbridos interespecíficos por meio de germinação in vitro e coloração com carmim propiônico, orceína acética e corante de Alexander. Os testes de germinação foram realizados com grãos de pólen frescos e armazenados por 30 dias. Osacessos de capim-elefante e de milheto apresentaram alta viabilidade de pólen. Apenas um deles, quando avaliado com o corante de Alexander, mostrou baixa fertilidade. Para os híbridos, observou-se alta taxa de pólens funcionais com os corantes nucleares. Entretanto,o corante de Alexander confirmou a completa esterilidade desses acessos. Os acessos de capim-elefante e milheto apresentaram baixa porcentagem de pólens viáveis quando induzidos à germinação em meio de cultura. Nos híbridos foi constatada completa esterilidade do grão de pólen, condizente com as anormalidades meióticas relatadas naliteratura. Quanto ao armazenamento, os grãos de pólen de todos os acessos perderam completamente o poder germinativo.The aim of this work was to estimate the pollen viability in elephantgrass, pearl millet and interspecific hybrids accessionsthrough in vitro germination and staining with propionic carmine, acetic orcein and Alexander’s stain. The germination tests were accomplished with fresh pollen grains and stored for 30 days. The elephantgrass and peare millet accessions presented a high pollenviability. Just one of the accessions, when evaluated with Alexander's stain, showed low fertility. For the hybrid, a high rate of functional pollen was observed with the nuclear stain. However, Alexander's stain confirmed the complete sterility of those accessions. Elephantgrass and pearl millet accessions presented a low percentage of viable pollen grain, when induced to germination in culture medium. Complete sterility of the pollen grain was verified in the hybrid, agreeing with the meiotic abnormalities

  16. Viabilidade do grão de pólen de acessos de capim-elefante, milheto - DOI: 10.4025/actascibiolsci.v28i1.1052 Pollen viability in elephantgrass, pearl millet and interspecific hybrids - DOI: 10.4025/actascibiolsci.v28i1.1052

    Directory of Open Access Journals (Sweden)

    Antônio Vander Pereira

    2006-03-01

    Full Text Available O objetivo deste trabalho foi estimar a viabilidade do pólen em acessos de capim-elefante, milheto e híbridos interespecíficos por meio de germinação in vitro e coloração com carmim propiônico, orceína acética e corante de Alexander. Os testes de germinação foram realizados com grãos de pólen frescos e armazenados por 30 dias. Os acessos de capim-elefante e de milheto apresentaram alta viabilidade de pólen. Apenas um deles, quando avaliado com o corante de Alexander, mostrou baixa fertilidade. Para os híbridos, observou-se alta taxa de pólens funcionais com os corantes nucleares. Entretanto, o corante de Alexander confirmou a completa esterilidade desses acessos. Os acessos de capim-elefante e milheto apresentaram baixa porcentagem de pólens viáveis quando induzidos à germinação em meio de cultura. Nos híbridos foi constatada completa esterilidade do grão de pólen, condizente com as anormalidades meióticas relatadas na literatura. Quanto ao armazenamento, os grãos de pólen de todos os acessos perderam completamente o poder germinativoThe aim of this work was to estimate the pollen viability in elephantgrass, pearl millet and interspecific hybrids accessions through in vitro germination and staining with propionic carmine, acetic orcein and Alexander’s stain. The germination tests were accomplished with fresh pollen grains and stored for 30 days. The elephantgrass and peare millet accessions presented a high pollen viability. Just one of the accessions, when evaluated with Alexander's stain, showed low fertility. For the hybrid, a high rate of functional pollen was observed with the nuclear stain. However, Alexander's stain confirmed the complete sterility of those accessions. Elephantgrass and pearl millet accessions presented a low percentage of viable pollen grain, when induced to germination in culture medium. Complete sterility of the pollen grain was verified in the hybrid, agreeing with the meiotic

  17. Obtenção de filtro cerâmico a partir da diatomita e casca de arroz carbonizada visando tratamento de efluente têxtil

    OpenAIRE

    Souza, Renata Priscilla de Araujo

    2011-01-01

    Os efluentes liberados pela indústria têxtil possuem altas concentrações de álcalis, carboidratos, proteínas, além de corantes contendo metais pesados. Assim, foi produzido um filtro visando principalmente à remoção da cor. Para sua obtenção foi usado a casca de arroz carbonizada e a diatomita, que possuem basicamente sílica amorfa hidratada na estrutura. A sílica apresenta-se sob três formas cristalinas: Quartzo, tridimita e cristobalita. De acordo com as considerações citadas...

  18. Using the same CIDR up to three times for estrus synchronization and artificial insemination in dairy goats = Uso do mesmo CIDR por até três vezes para sincronização do estro e inseminação artificial de cabras leiteiras

    Directory of Open Access Journals (Sweden)

    Daniel Maia Nogueira

    2011-07-01

    Full Text Available The objective of this study was to evaluate the effectiveness of reusing a controlled internal drug release (CIDR device for up to three times in the reproductive performance of dairy goats raised in the semi-arid zone of northeastern Brazil. Forty-five goats were allocated into three hormone treatments, as follows: CIDR1x, treated with new CIDR during nine days. Two days prior to device removal, injections of 75 ƒÝg d-cloprostenol and 300 IU equine chorionic gonadotropin (eCG were administrated. For the other treatments, thesame hormone protocol was used, differing only by the use of the same CIDR for a second time in CIDR2x and for a third time in CIDR3x. The interval from device removal to the onset of estrus (13.3 „b 1.1h vs. 13.8 „b 2.6h vs. 13.3 „b 1.4h, as well as estrus duration (33.6 „b 7.3h vs. 29.6 „b 3.2h vs. 32.8 „b 4.5h, did not differ (p > 0.05 among groups CIDR1x, CIDR2x and CIDR3x, respectively. All synchronized females were found to be in estrus. The overall fertility and prolificacy after artificial insemination were 82.2% and 1.9 kids, respectively, without significant difference (p > 0.05 among treatments. The use of the same CIDR for up to three times waseffective using 9-day estrus synchronization protocols in dairy goats.Objetivou-se avaliar o efeito da utilizacao do mesmo dispositivo de liberacao controlada de drogas (CIDR por ate tres vezes sobre odesempenho reprodutivo de cabras leiterias exploradas no semiarido do Nordeste Brasileiro. Foram utilizadas 45 cabras divididas em tres tratamentos de sincronizacao do estro, sendo: CIDR1x, tratadas com CIDR novo durante nove dias. Dois dias antes da retirada do dispositivo, foram aplicados 75 ƒÝg de d-cloprostenol e 300 UI de gonadotrofina corionica equina (eCG. Para os demais tratamentos, foi utilizado o mesmo protocolo hormonal, diferindo apenas pelo uso do mesmo CIDR pela segunda vez no grupo CIDR2x e uso pela terceira vez no grupo CIDR3x. O intervalo entre

  19. Biossorção de azul de metileno utilizando resíduos agroindustriais

    Directory of Open Access Journals (Sweden)

    Andressa C. Honorato

    2015-07-01

    Full Text Available O presente trabalho avaliou a capacidade de adsorção do corante azul de metileno nos resíduos da palha de milho e da bainha do palmito pupunha in natura. A caracterização dos resíduos foi determinada utilizando-se a microscopia eletrônica de varredura e espectroscopia na região do infravermelho a qual indicou a presença de grupos carboxílicos, hidroxila e carbonila. O tempo necessário para que o sistema atingisse o equilíbrio para ambos os resíduos foi de 240 min, seguindo uma cinética descrita pelo modelo de pseudo-segunda ordem. A capacidade máxima de adsorção foi de 102,8 mg g-1 para o resíduo da palha de milho, seguindo o modelo de isoterma de Langmuir e 50,9 mg g-1 para o resíduo de palmito pupunha, sendo que o modelo que melhor se ajusta foi Freundlich. Desta forma, esses resíduos são promissores para a adsorção do corante azul de metileno em efluentes.

  20. Análise da capacidade de remoção de pigmentos da resina composta pelo peróxido de hidrogênio 35%

    Directory of Open Access Journals (Sweden)

    Eveline Claudia MARTINI

    Full Text Available Resumo Objetivo Avaliar in vitro a capacidade de remoção de pigmentos ocasionados em resina composta após aplicação de peróxido de hidrogênio 35%. Material e método Confeccionaram-se 20 amostras de resina composta Opallis (FGM, cor A1, em matriz metálica circular. As amostras foram divididas em quatro grupos (n=5 dos seguintes agentes corantes: água destilada (controle, café, vinho tinto e Coca-Cola®. No manchamento, as amostras ficaram imersas nas soluções durante 72 horas, com troca diária das bebidas. Procedeu-se à aplicação do gel de peróxido de hidrogênio 35% (Whiteness HP Blue Calcium, FGM em três sessões, sendo uma aplicação do gel por sessão, o qual permaneceu nas amostras durante 40 minutos. Medidas de cor foram feitas inicialmente, após manchamento, após aplicação do peróxido e por mais 21 dias, usando espectrofotômetro Vita Easyshade. Os dados foram submetidos à análise de variância de dois fatores (tempo vs. corante e ao teste de Tukey, para o contraste das médias (α=0,05. Resultado Apresentaram alteração de cor (ΔE - média/desvio padrão de L* o café (15,7 ± 2,0 e o vinho (15,2 ± 4,6, quando comparados à Coca-Cola® (4,8 ± 1,9. O peróxido de hidrogênio removeu a pigmentação das amostras, porém, para nenhum dos corantes, houve retorno à coloração inicial, principalmente no grupo manchado por café (12,9 ± 1,5; este mostrou diferença significativa quando comparado ao controle (1,6 ± 0,6, diferentemente do vinho (3,3 ± 0,6 e da Coca-Cola® (2,1 ± 0,9, que se aproximaram do grupo controle. Conclusão As soluções corantes pigmentaram a resina composta, principalmente o café. A aplicação do peróxido de hidrogênio 35% foi eficaz na remoção de pigmentos das amostras, porém, em nenhum dos grupos, com diferentes corantes, houve retorno à coloração inicial (p>0,005.

  1. PHOTOCATALYTIC OXIDATION (PCO APPLIED TO EFFLUENT TREATMENT TO OBTAIN WATER TO REUSE IN TEXTILE INDUSTRY = FOTO-OXIDAÇÃO CATALÍTICA APLICADA AO TRATAMENTO DE EFLUENTES PARA OBTENÇÃO DE ÁGUA PARA REÚSO NA INDÚSTRIA TÊXTIL

    Directory of Open Access Journals (Sweden)

    Verônika Carrer Fontana

    2010-01-01

    Full Text Available The main objective of this study was to evaluate the photocatalytic oxidation process to decolorize the commercial textile dye Intense Black and a textile effluent, aiming to obtain a final effluent for reuse in the industry. Both dye and textile effluent was obtained in a local laundry that dyes jeans. The textile effluent was characterized as the Biochemical Oxygen Demand (BOD, Chemical Oxygen Demand (COD, color, turbidity, pH, spectrophotometric scanning, to determine the maximum absorbance wavelength in the visible spectrum, and concentration of chloride (Cl-, sulfate (SO4-2, nitrate (NO3- and phosphate (PO4-2 ions. A sample of water reused on the same industrial laundry was collected and it was characterized in the same way as the composed effluent. The effluent treatment was accomplished by a photocatalytic oxidation process in a thin-film reactor impregnated with titanium dioxide, TiO2. Mercury-vapor lamps of 250 and 125 W and germicide lamps of 15W were evaluated during the tests. The results of the dye decolorization percentages were greater than the textile effluent ones. However, good results of effluent decolorization were obtained and the final color of the effluent treated was lower than the reuse water color. The best decolorization results were obtained using the 250W mercury-vapor lamp and the 15W germicide lamps. After 6 hours of experiment, the dye decolorization and the effluent decolorization was over 90% and 60%, respectively. = O objetivo principal deste estudo foi avaliar a utilização do processo de foto-oxidação catalítica para a descoloração do corante têxtil comercial Preto Intenso e de um efluente têxtil, visando à obtenção de um efluente final próprio para o reuso na indústria. Tanto o corante quanto o efluente foram obtidos em uma lavanderia que tinge roupas de jeans. O efluente foi caracterizado quanto à Demanda Bioquímica de Oxigênio (DBO, Demanda Química de oxigênio (DQO, cor, turbidez, p

  2. Influence of soil management practices and substrate availability on microbial biomass and its activities in some haplic luvisols

    Energy Technology Data Exchange (ETDEWEB)

    Friedel, Jurgen K. [University Hohenheeim, Stuttgart (Germany)

    1996-07-01

    barbecho y con los sistemas de monocultivo. La razon principal de estas diferencias es un abastecimiento mas grande con residuos de cosecha y raices en los sistemas de rotacion de cultivos, que conduce a un mayor sustrato disponible para microorganismos. Los objetivos del estudio presente fueron describir los indices del sustrato disponible para microorganismos en suelos ara bles, dependiendo de las practicas de manejo de suelos, y relacionarlos con la biomasa y la actividad microbianas. En dos localidades (Muttergarten e Ihinger Hof, cerca de la Universidad de Hohenheim, Stuttgart, sudoeste de Alemania) fueron medidos los contenidos de trifosfato de adenosina y la actividad microbiana en Luvisoles haplicos. Como indices del sustrato disponible para microorganismos fueron determinados los compuestos organicos de carbon soluble en agua y se calculo la ateria organica de suelos jovenes susceptible a descomponerse en los fertilizantes organicos y en los residuos de cosecha y de raices, usando funciones de descomposicion empiricas. Los contenidos mas altos de ATP y las actividades microbianas mas altas fueron observados con la fertilizacion organica (abono liquido de ganado), antes que con la fertilizacion mineral. La labranza somera con un cultivador rotatorio condujo a valores mas altos de la propiedades microbianas en la parte superior del horizonte Ap que con la labranza con arado. Los parametros microbianos del suelo fueron mas altos en parcelas bajo una rotacion de cultivos de colza-cereales, en comparacion con una rotacion de cultivos de legumbres-cereales. La biomasa microbiana y sus actividades estuvieron relacionadas mas estrechamente a materia organica de suelos jovenes susceptible a descomponerse que al contenido de humus o a cualquiera otra propiedad del suelo. Los compuestos organicos de carbon soluble en agua no demostraron ser un indicador del sustrato disponible para microorganismos.

  3. Sequential electrochemical/biological treatment for the removal of 2,6-dichlorophenol from synthetic wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Polcaro, A.M.; Palmas, S.; Lallai, A. [Cagliari Univ., Cagliari (Italy). Dipt. di Ingegneria Chmica e Materiali

    2001-04-01

    The paper examines the effect of chloride on the oxidation of 2,6-dichlorophenol (DCP) performed at TiO{sub 2}/RuO{sub 2} DSA (Registered) anodes, which are specific catalysts for chlorine evolution. The results indicate that chlorine/hypochlorite originating from chloride oxidation in certain favourable conditions reacts with the organic substrate at the diffusion layer near the anode, accelerating the mass transfer of the reactant towards the electrode surface. When the bulk concentration of organic substrate has become very low, the oxidising, species can accumulate in the bulk solution where the accomplishment of the oxidation of residual reactant and of its intermediates takes place. Solutions which also contained glucose were electrolysed in order to verify the high level of selectivity of DCP oxidation with respect to a biodegradable substrate: glucose was found to be unchanged up to nearly complete elimination of DCP. The toxicity of the solution was sufficiently reduced to reach values compatible with the subsequent biological treatment. [Italian] Il lavoro esamina l'influenza della presenza di cloruri nella ossidazione del 2,6-diclorofenolo (DCP) su anodi di DSA (Registered) a base di TiO{sub 2}/RuO{sub 2}, specifici catalizzatori dell'evoluzione del cloro. I risultati indicano che i prodotti di ossidazione del cloruro che si ottengono in adatte condizioni sperimentali, reagiscono con il substrato organico nello strato di diffusione adiacente all'anodo, accelerando il trasferimento di materia dell'organico verso la superficie dell'elettrodo. Quando la concentrazione di DCP nella massa e' diventata molto bassa l'ossidante prodotto puo' accumularsi nella massa della soluzione dove ha luogo il completamento dell'ossidazione del DCP residuo e degli intermedi prodotti. Sono state inoltre sottoposte ad elettrolisi alcune soluzioni di DCP contenenti anche glucosio. I risultati hanno permesso di verificare che il

  4. Análise comparativa entre instrumentação rotatória (GT, manual e associação de ambas no preparo de canais achatados Comparative analysis of rotatory (GT and manual root canal preparation and association of both techniques in instrumentation of flattened root canals

    Directory of Open Access Journals (Sweden)

    Silvana Beltrami Gonçalves

    2003-03-01

    Full Text Available A instrumentação do canal radicular tem sido considerada uma das fases mais importantes do tratamento endodôntico, portanto muitas técnicas e instrumentos têm sido desenvolvidos para esse fim. O propósito desse estudo foi avaliar a limpeza de canais radiculares instrumentados com três diferentes técnicas. Foram selecionados trinta incisivos inferiores, onde a abertura coronária foi realizada. Posteriormente, os canais foram preenchidos com tinta nanquim (corante, previamente acondicionada em tubetes anestésicos, sendo a mesma levada ao interior do canal radicular com auxílio de uma seringa carpule e uma agulha para anestesia. Após 48 horas, tempo esperado para que o corante secasse no canal, os dentes foram divididos em três grupos: G1 - instrumentação rotatória com GT; G2 - instrumentação manual e G3 - associação de ambas (mista. Após a instrumentação, os dentes foram seccionados longitudinalmente e realizada a avaliação da limpeza dos canais, através da remoção de corante nos terços cervical, médio e apical. Os resultados demonstraram que não houve diferença estatisticamente significante na limpeza do canal entre as três técnicas de instrumentação estudadas, nos três terços avaliados.Root canal preparation has been considered one of the most important steps in root canal therapy, thus many techniques and instruments have been developed. The aim of this study was to evaluate the cleaning of the root canal through three different instrumentation techniques. Thirty mandibular incisors were selected and submitted to lingual access cavities. Afterwards, the canals were filled with India ink dye previously stored in carpules, which was inserted into the root canal by means of anesthetic syringe and anesthetic needles. After 48 hours, during which the dye was allowed to dry inside the root canal, the teeth were divided in three groups: G1- GT rotatory instrumentation; G2- manual instrumentation; G3- association

  5. Estudo morfológico e radiológico sobre a comunicação entre a articulação interfalangeana distal e a bolsa do osso navicular em peças anatômicas de eqüinos (Equus caballus, L. 1758

    Directory of Open Access Journals (Sweden)

    Edson Moreira Borges

    2001-01-01

    Full Text Available Objetivou-se neste estudo verificar anatômica e radiograficamente a existência de comunicação entre a bolsa do osso navicular (BN e a articulação interfalangeana distal (AID, estabelecendo sua freqüência e forma e identificando as estruturas anatômicas envolvidas no processo. Desta forma, foram utilizadas 140 peças anatômicas de membros torácicos e pélvicos de eqüinos. Com o auxílio de fluoroscópio, foi injetada uma mistura de contraste iodado, Neoprene látex e corante na BN dos membros direito e na AID dos membros esquerdos, com subseqüentes exposições radiográficas. Constatadas comunicações, identificavam-se as estruturas e os locais envolvidos, mediante técnica de dissecação. Verificou-se, em duas observações, comunicação entre a BN e a AID, após injeção de contraste iodado, látex e corante na bolsa do osso navicular, sendo um no membro torácico direito (MTD e outro no membro pélvico direito (MPD. Comunicação entre a AID e a bainha do tendão do músculo flexor profundo do dedo (BTMFPD ocorreu em uma peça, pertencente ao membro torácico esquerdo (MTE. Comunicação entre a BN e a BTMFPD foi observada na peça de um membro torácico direito. Variações morfológicas nas extremidades laterais da BN, constituindo projeções que se estendiam até o terço proximal da falange média, sendo mais pronunciada na face lateral do que na medial, ocorreram em cinco membros. Mediante a administração de contraste iodado, látex e corante na AID, nenhuma comunicação foi observada entre a AID e a BN.

  6. La Tutela dei beni del Mare Nostrum Il progetto Archeomar

    Directory of Open Access Journals (Sweden)

    Fulvio Bernardini

    2006-06-01

    Full Text Available Quando il primo aprile 2004 si è dato ufficialmente il via al Progetto Archeomar le aspettative degli addetti ma soprattutto dell’Amministrazione sui risultati del lavoro erano enormi. Probabilmente proporzionali all’importanza dello strumento di conoscenza del patrimonio archeologico sommerso nonché di tutela e prevenzione che si stava sviluppando. Archeomar, infatti, ha rappresentato e rappresenta ancor oggi, ad un anno dalla sua conclusione, il primo tentativo organico di conoscenza (anche se limitato a sole 4 regioni del Sud Italia che si staglia nei confronti delle precedenti iniziative, tutte caratterizzate da una totale assenza di programmazione mirata alla produzione di una adeguata cartografia e quindi sia di una carta del rischio subacquea che di carte topografiche di relitti e aree archeologiche sommerse.

  7. [Clinical usefulness and psychometric properties of the Cambridge Behavioural Inventory].

    Science.gov (United States)

    Fernandez-Martinez, R; Kokoulina, E; Carballido-Araujo, E; Garcia-Fuertes, I; Gutierrez-Martinez, O; Santiago-Lopez, F; Vazquez-Batan, P

    2016-11-16

    Introduccion. Un area importante de la evaluacion neuropsicologica son los sintomas psicologicos y conductuales. El inventario conductual de Cambridge –Cambridge Behavioural Inventory (CBI)– es una medida de autoinforme dirigida a allegados que recoge una amplia variedad de sintomas conductuales que pueden darse en el curso de las enfermedades neurologicas. El principal objetivo del estudio es comprobar la utilidad clinica de su adaptacion al castellano. Sujetos y metodos. El CBI fue cumplimentado por 215 allegados de pacientes remitidos desde los servicios de neurologia y psiquiatria. Se compararon los perfiles del CBI de cuatro grupos de pacientes formados sobre la base de sus principales caracteristicas clinicas, datos psicometricos, pruebas de imagen y juicio clinico del profesional solicitante del estudio neuropsicologico. Resultados. La mayoria de las escalas (10 de 13) del CBI tuvo valores de consistencia interna aceptables, y las escalas de memoria y atencion/orientacion, correlaciones elevadas con medidas objetivas de memoria y orientacion temporal. Los perfiles del CBI de los grupos de pacientes con distintas condiciones (trastorno organico de la memoria, trastorno funcional de la memoria, variante conductual de demencia frontotemporal y enfermedad de Alzheimer) fueron consistentes con sus principales caracteristicas. Conclusiones. El CBI es un instrumento psicometricamente fiable y con adecuada validez convergente y discriminante que puede ser util en el proceso de evaluacion neuropsicologica, aportando informacion relevante no solo sobre el funcionamiento cognitivo y las capacidades funcionales, sino tambien sobre los sintomas conductuales y psicologicos de los pacientes con trastornos cognitivos.

  8. Poultry manure. Agronomic use or energy source?; Pollina: utilizzo agronomico o fonte di energia?

    Energy Technology Data Exchange (ETDEWEB)

    Trinchera, A.; Perri, P.T. [Istituto Sperimentale per la Nutrizione delle Piante, Rome (Italy)

    2000-10-01

    By the year 2010, Italy could see the construction of three incinerators that use poultry manure as source of energy. In this paper, advantages and disadvantages of such a choice are considered in their environmental and economical aspects, taking into account the agronomic qualities of poultry manure. The analyses suggests that the agricultural sector should be the one to recover the biomass. It should be used above all as a fertiliser, either directly or after proper treatments improving its agronomic characteristics. Conversely, the energy sector should be in charge of dismissing the eventual surplus through incineration. [Italian] Nel primo decennio del 2000 in Italia potrebbero sorgere tre impianti di incenerimento in grado di produrre energia utilizzando quale combustibile le deiezioni avicole. In tale lavoro sono stati considerati i vantaggi e gli svantaggi di tale scelta, sia dal punto di vista ambientale che economico, sottolienando come sia necessario tenere presente innanziutto la qualita' agronomica di tale biomassa organica. L'analisi effettuata suggerisce che il settore agricolo recuperi le deiezioni avicole in maniera preponderante, attraverso l'utilizzo immediato quale fertilizzante organico ed a seguito di processi alternativi in grado di esaltarne le caratteristiche agronomiche, rimandando al settore energetico il compito di smaltirne l'eventuale surplus mediante l'incenerimento.

  9. Le Ferrovie e la costruzione dell'Italia Unita

    Directory of Open Access Journals (Sweden)

    Laura Facchinelli

    2011-04-01

    Full Text Available La costruzione dell’Italia unita è strettamente legata alla storia delle ferrovie. A pochi anni dall’invenzione del treno vennero attivate alcune linee, a partire dalla Napoli-Portici (1839. Si trattava, però, di brevi tratti separati tra loro, costruiti per iniziativa dei diversi Stati.I progressi compiuti dalle ferrovie in diversi paesi d’Europa, che segnavano un rapido progresso delle vie di comunicazione terrestri, accentuarono l’arretratezza della situazione italiana. Ma si andava delineando, nelle menti più lungimiranti, l’idea di un’unità almeno territoriale della penisola, da realizzare con una rete ferroviaria: in tal modo la questione ferroviaria, nel periodo del Risorgimento, venne ad inserirsi nella formazione della coscienza nazionale.Dopo la proclamazione del Regno d’Italia, superate le precedenti divisioni in tanti diversi Stati, si diede finalmente avvio a un progetto organico di costruzione della rete ferroviaria nazionale. Dal 1861 al 1865 lo sforzo costruttivo fu notevole. Cruciale fu il ventennio dal 1865 al 1885. Nel 1865 la rete della penisola venne distribuita fra quattro grandi società.Realizzata la spina dorsale del paese, venne costruito il primo grande traforo alpino, mentre si finanziava la costruzione di oltre 6.000 km di ferrovie secondarie.Nel 1885 le linee vennero raccolte in due reti organiche disposte in senso longitudinale lungo la penisola. Nel 1905, la gestione delle ferrovie venne assunta da un’unica azienda di Stato.  

  10. CARACTERIZACIÓN DE POLVOS DE ACERÍA ELÉCTRICA PRODUCIDOS EN VENEZUELA Y EVALUACIÓN PRELIMINAR DE SU LIXIVIABILIDAD CON ÁCIDOS ORGÁNICOS DILUIDOS

    Directory of Open Access Journals (Sweden)

    PEDRO DELVASTO

    2011-01-01

    Full Text Available Se estudiaron polvos de aceria cuyo analisis quimico revelo un contenido (en peso de: 27,0 % de Fe; 7,1 % de Mg; 4,9 % de Zn; 4,0 % de Ca y 0,5 % de Pb. La difraccion de rayos X y la espectroscopia infrarroja, permitio identificar en los polvos las siguientes fases: espinelas, Fe3O4, CaCO3, SiO2, ZnO y PbO. El analisis microscopico de estos residuos indico que estan formados por agregados de particulas esferoidales cuyo tamano varia entre 120 y 0,25 ¿Êm. La lixiviabilidad de los mismos se evaluo durante 28 dias en columnas de percolacion, empleando agua y disoluciones de acidos organicos como agentes lixiviantes. El objetivo fue evaluar el comportamiento del residuo bajo condiciones similares a las que generan los microorganismos naturales del suelo. Se encontro que la lixiviabilidad de Zn y Pb vario entre 80 y 16 mg mensuales por kilogramo de polvo de aceria.

  11. Manufacture of amorphous and poly-crystalline materials with the sol-gel process; Fabricacion de materiales amorfos y policristalinos con la ruta sol-gel

    Energy Technology Data Exchange (ETDEWEB)

    Castaneda-Contreras, J. [Centro Universitario de Los Lagos, Universidad de Guadalajara, Guadalajara, Jalisco (Mexico)

    2006-01-15

    The sun-gel process is a chemical route that allows the manufacture of amorphous and poly-crystalline materials in a relatively simple way. New materials can be obtained, materials that through the traditional manufacture methods, are very difficult to obtain, such as oxide combinations (SiO{sub 2}, TiO{sub 2}, ZrO{sub 2}, etc.), and that, when being produced by traditional methods, they run the risk of being contaminated with rare earth ions or organic dyes. The unique structures, micro- structures and compounds that can be made with the sun-gel process open many possibilities for practical applications, to name a few: the manufacture of optical components, preforms for optical fibers, dielectric coatings, superconductors, waveguides, nanoparticles, solar cells, etc. [Spanish] El proceso sol-gel es una ruta quimica que permite fabricar materiales amorfos y policristalinos de forma relativamente sencilla. Se pueden obtener nuevos materiales que a traves de los metodos tradicionales de fabricacion son muy dificiles de obtener, tales como combinaciones de oxidos (SiO{sub 2}, TiO{sub 2}, ZrO{sub 2}, etc.), y que, de ser producidos por metodos tradicionales corren el riesgo de contaminarse con iones de tierras raras o colorantes organicos. Las estructuras unicas, micro estructuras y compuestos que pueden hacerse con el proceso sol-gel abren muchas posibilidades para aplicaciones practicas, por nombrar algunas, la fabricacion de componentes opticos, preformas para fibras opticas, recubrimientos dielectricos, superconductores, guias de onda, nanoparticulas, celdas solares, etc.

  12. 1-N-aminoindol derivatives synthesis in no aqueous means from the 1, 4-dihydrocinnoline obtained by electrolysis in continuous flow redox cell; Sintesis de derivados del 1-N-aminoindol en medios no acuosos a partir de la 1, 4-dihidrocinolina obtenida por electrolisis en celda redox de flujo continuo

    Energy Technology Data Exchange (ETDEWEB)

    Frontana-Uribe, Bernardo A. [Universidad Nacional Autonoma de Mexico, Mexico, D.F. (Mexico); Moinet, Claude [Laboratoire d' Electrochimie et Organometalliques UMR, Paris (France)

    1999-08-01

    This work describes the synthesis of 1-N-aminoindol derivatives in organic anhydrous media from 1, 4-dihydrocinnoline. 1, 4-dihydrocinnoline 4 is obtained by electrolysis of 2-(orto-notropheny)-ethylamine 1a in a continuous flow redox cell. The cinnoline ring contraction products are obtained in low yield, but they show the possibility to carry out the reaction in organic media without water addition, as it was noted in previous works. [Spanish] En este trabajo se describe la sintesis de derivados del 1-N-aminoindol en medios anhidros a partir de la 1, 4-dihidrocinolina 4. Esta se obtiene mediante la electrolisis de la 2-(orto-notrofenil)-etilamina 1a en celda redox de flujo continuo. Los productos de contraccion del ciclo de la cinolina en 1-N-aminoindol se obtiene en rendimiento bajo, pero demuestran la posibilidad de llevar a cabo esta reaccion en medios totalmente organicos, sin la necesidad de la adicion de agua en el medio de reaccion, como esta descrito en trabajos precedentes.

  13. The regional laws to support technological innovation in Emilia Romagna: the principle legislative instruments; Le leggi regionali a favore dell`innovazione tecnologica in Emilia-Romagna: i principali strumenti agevolativi

    Energy Technology Data Exchange (ETDEWEB)

    Grandi, M.

    1998-01-01

    The Emilia Romagna region supports the developpement and the economic growth of innovative SMEs with legislative instruments. These instruments give the chance to the companies to improve their law capitalization and to receive facilities of credit. In this following guide the opportunities offered by legislative instruments are synthesized in summarized schemes. Every scheme is structured in this way: beneficiary persons; dead lines and expire dates; measures and conditions of payment; priorities. Every summarized scheme contains information about the legislative sources and it is equipped with a schedule that stresses the effective assignment of contributions. [Italiano] Lo sviluppo e la crescita delle PMI viene sostenuto dalla Regione Emilia Romagna attraverso strumenti legislativi locali che, se utilizzati in sinergia con altri programmi di finanziamento nazionali e comunitari, permettono alle imprese di superare i limite della sottocapitalizzazione beneficiando di un credito agevolato. In questo documento le possibilita` offerte sul credito agevolato vengono riassunte in modo organico ed esaustivo indicando, per ogni strumento di finanziamento: i soggetti beneficiari; il termine di presentazione della domanda di contributo altre scadenze; la misura e la modalita` di erogazione dei contributi; le iniziative finanziabili: priorita`. Ogni schema riassuntivo contiene indicazioni sulle fonti legislative considerate ed e` correlato da una tabella che evidenzia i dati relativi all`effettiva erogazione dei contributi.

  14. STUDY OF A PROTOCOL FOR MEASURING SAIL SPORTS TRAINING

    Directory of Open Access Journals (Sweden)

    Claudio Scotton

    2015-04-01

    Full Text Available Durante l’attività agonistica i velisti incontrano molteplici difficoltà. Elenchiamo solo alcune variabili ambientali che condizionano le scelte tattiche e tecniche che possono rivelarsi vincenti o perdenti (Scotton 2007: vento, onda, corrente, umidità, temperatura dell’acqua e dell’aria, distanza del campo di regata dalla sistemazione degli atleti a terra, sole, pioggia. Da tutto ciò si evince che la Vela, rispetto ad altre specialità sportive praticate in una condizione stabile come accade in una palestra o in un campo di atletica e caratterizzate dalla prevalenza di abilità motorie sportive stereotipate (Scotton 2003, naviga, vocabolo pertinente, con maggiori difficoltà nell’individuare i carichi di lavoro interno ed esterno. Obiettivo: Scopo del presente studio è l’indagine conoscitiva delle caratteristiche antropometriche di base e di alcune capacità organico-muscolari e coordinative di velisti della classe 29er; deriva in doppio acrobatica giovanile (Federvela 2008, molto veloce in qualsiasi condizione, ma anche instabile e difficile da condurre. Il lavoro ha permesso di gettare le basi per la messa punto di un protocollo di misurazione dell’allenamento applicabile alla Vela.

  15. Neuropsychology of perpetrators of domestic violence: the role of traumatic brain injury and alcohol abuse and/or dependence.

    Science.gov (United States)

    Romero-Martínez, Ángel; Moya-Albiol, Luis

    2013-12-01

    Introduccion. Gran parte de los hombres que ejercen maltrato contra sus parejas presentan deficits en funciones ejecutivas, memoria y atencion, capacidades intelectuales y empatia. Dos factores coadyuvantes a estas deficiencias son los traumatismos craneoencefalicos y el abuso de alcohol. Objetivo. Revisar y recapitular los resultados obtenidos sobre los deficits neuropsicologicos en maltratadores y relacionarlos con los correlatos neuroanatomicos implicados en las funciones alteradas. Se enfatiza el papel de los traumatismos craneoencefalicos y el abuso o la dependencia del alcohol, asi como la posible existencia de daño organico cerebral. Desarrollo. Se ha revisado la bibliografia cientifica usando los buscadores Google Scholar, PsycINFO, PubMed, Medline e ISI Web of Knowledge. Conclusiones. Los maltratadores presentan un detrimento de la flexibilidad cognitiva, la capacidad de inhibicion, la velocidad de procesamiento y las habilidades verbales. Ademas, muestran una atencion pobre, una baja capacidad de abstraccion y una limitacion en las habilidades mnemicas, tanto de la memoria de trabajo como a largo plazo. Los traumatismos craneoencefalicos y el abuso o la dependencia del alcohol exacerban los deficits ya presentes en los maltratadores, pero no son suficientes per se para explicarlos. Estos deficits podrian ser producto de un funcionamiento anormal de estructuras como los cortex prefrontal y occipital, el giro fusiforme y el cingulado posterior, el hipocampo, el talamo y la amigdala. La comprension de dichos mecanismos favoreceria el desarrollo de terapias de rehabilitacion neuropsicologica coadyuvantes a las terapias establecidas hoy en dia.

  16. Effects on water quality from mud clearance operations in the Pezze' hydropower basin (Trentino, Italy); Effetti sulla qualita' delle acque legati alle operazioni di dissabbiamento del bacino idroelettrico di Pezze' di Moena (Trentino)

    Energy Technology Data Exchange (ETDEWEB)

    Canepel, R.; Cadrobbi, G.; Fedrizzi, F. [Agenzia Provinciale per la Protezione dell' Ambiente, Trent (Italy)

    2000-07-01

    The present paper describes dynamic concentration for various parameters, that have been monitored through both continuous and instant samplings, during maintenance operations (mud deposit clearance) in a hydropower basin along Torrent Avisio in Trentino region, Italy. Aim of the work is to demonstrate that, during such operations, an organic water pollution occur besides turbidity. The former is well expressed by a marked value increment of different parameters, as total phosphorus, ammonium and organic matter. [Italian] Il presente lavoro descrive l'osservazione dell'andamento delle concentrazioni di diversi parametri, rilevati in continuo e attraverso campionamenti istantanei, durante le operazioni di dissabbiamento di un bacino idroelettrico lungo un corso d'acqua, il Torrente Avisio in Trentino. Scopo del lavoro e' la dimostrazione della consistenza, in occasione di tali eventi, di un inquinamento delle acque, oltre che di tipo inorganico (intorbidimento), anche di tipo organico cioe' caratterizzato da uno spiccato incremento, rispetto alle condizioni normali, di una serie di parametri fra cui fosforo totale, azoto ammoniacale e sostanza organica.

  17. The photo refractive polymers, physics and photonic applications of these new materials; Los polimeros fotorrefractivos, fisica y aplicaciones fotonicas de estos nuevos materiales

    Energy Technology Data Exchange (ETDEWEB)

    Maldonado, J. L. [Centro de Investigacion en Optica, Leon, Guanajuato (Mexico); Garcia M, J. [Universidad Nacional Autonoma de Mexico, Mexico, D.F. (Mexico)

    2001-12-01

    This paper is a review about the new photo refractive organic materials and their potential photonic applications, the photo refractive polymers. The physical properties required for observing photo refractivity, including charge generation, transport, and nonlinear optical properties are discussed for amorphous polymers. The nonlinear optical properties on a macroscopic level are related to the microscopic properties by using the Oriented Gas model. Four Wave Mixing (FWM) and Two Beam Coupling (TBC) experiments, to investigate the photo refractive properties of the material by measuring the diffraction efficiency {eta} of the polymeric gratings, and the optical gain coefficient {eta} are described. Kogelnik's Coupled Wave model to describe the photo refractive polymeric gratings is reviewed. Finally some applications of these new polymers are presented. [Spanish] Este articulo es una revision sobre los nuevos materiales organicos fotorrrefractivos y sus potenciales aplicaciones fotonicas: los polimeros fotorrefractivos. Se discuten las propiedades fisicas requeridas para observar fotorrefractividad, incluyendo la generacion de cargas, el transporte y las propiedades opticas no lineales en polimeros amorfos. Usando el modelo de gas orientado, se muestra como se relacionan las propiedades opticas no lineales a nivel marcoscopico con las propiedades microscopicas. Se describen los experimentos de mezcla de cuatro ondas (FWM) y dos ondas (TBC) para investigar las propiedades fotorrefractivas del material, midiendo la eficiencia de difraccion {eta} de las rejillas polimericas y el coeficiente de ganancia optica {eta}. Se revisa el modelo de ondas acopladas de Kogelnik para describir las rejillas polimericas fotorrefractivas. Finalmente se presentan algunas aplicaciones de estos nuevos polimeros.

  18. Power generation from biomass estimation for projects of the clean development mechanism program; Estimacion de la generacion de energia a partir de biomasa para proyectos del programa de mecanismo de desarrollo limpio

    Energy Technology Data Exchange (ETDEWEB)

    Flores Velazquez, Roberto; Munoz Ledo Carranza, Ramon; Flores Brito, Brenda Berenice; Cano Ruiz, Karla Itzel [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

    2009-07-01

    In the present work, it is calculated the amount of energy and the reductions of greenhouse gases emissions that may be obtained taking advantage of organic wastes, such as, sugarcane bagasse and urban wastes. The appropriate use of these waster could generate up to 28% of the power requirements reported for the state of Morelos in 2005. Likewise, the Clean Development Mechanism could be employed to negotiate carbon certificates in such as way that the industrialized countries could meet with the goals implemented in the Kyoto Protocol and the state of Morelos could get the financial resource to be in the front technologic line with respect to the utilization of organic waster to generate power and to reduce greenhouse gases emissions. [Spanish] En el presente trabajo se estima la cantidad de energia y reduccion de emisiones de gases de efecto invernadero que podria obtenerse mediante el aprovechamiento de desechos industriales y municipales en el estado de Morelos, Mexico, tales como el bagazo de cana y la basura municipal. El uso adecuado de estos desechos podria generar hasta un 28% de los requerimientos energeticos de Morelos reportados en 2005. Asimismo, a traves del programa de Mecanismo de Desarrollo Limpio se podrian negociar certificados de carbono para que los paises industrializados