Experience of development of porphyry copper type deposits in the Urals

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И. А. Алтушкин

2017-12-01

Full Text Available Russian copper company was the first in Russia to start developing porphyry copper deposits. In 2013 the Mikheevsky mining and processing plant with the annual production capacity of 18 mln t of ore was put into exploitation. The use of innovative approaches regarding choice of the technology, high-performance equipment and organization of construction allowed to bring the enterprise to a full capacity and to achieve expected results within three years. On the basis of the experience obtained during design, construction and exploitation of the Mikheevsky mining and processing plant in 2017 the company has started the construction of a new mining and processing plant in the Tominskoye deposit. The first stage anticipates the enterprise production capacity to be equal to 28 mln t with the possibility of its increase up to 56 mln t. The development of porphyry copper deposits in the Urals will allow to provide copper plants with the raw materials over the next 80-100 years.

Quantitative Mineral Resource Assessment of Copper, Molybdenum, Gold, and Silver in Undiscovered Porphyry Copper Deposits in the Andes Mountains of South America

Science.gov (United States)

Cunningham, Charles G.; Zappettini, Eduardo O.; Vivallo S., Waldo; Celada, Carlos Mario; Quispe, Jorge; Singer, Donald A.; Briskey, Joseph A.; Sutphin, David M.; Gajardo M., Mariano; Diaz, Alejandro; Portigliati, Carlos; Berger, Vladimir I.; Carrasco, Rodrigo; Schulz, Klaus J.

2008-01-01

Quantitative information on the general locations and amounts of undiscovered porphyry copper resources of the world is important to exploration managers, land-use and environmental planners, economists, and policy makers. This publication contains the results of probabilistic estimates of the amounts of copper (Cu), molybdenum (Mo), gold (Au), and silver (Ag) in undiscovered porphyry copper deposits in the Andes Mountains of South America. The methodology used to make these estimates is called the 'Three-Part Form'. It was developed to explicitly express estimates of undiscovered resources and associated uncertainty in a form that allows economic analysis and is useful to decisionmakers. The three-part form of assessment includes: (1) delineation of tracts of land where the geology is permissive for porphyry copper deposits to form; (2) selection of grade and tonnage models appropriate for estimating grades and tonnages of the undiscovered porphyry copper deposits in each tract; and (3) estimation of the number of undiscovered porphyry copper deposits in each tract consistent with the grade and tonnage model. A Monte Carlo simulation computer program (EMINERS) was used to combine the probability distributions of the estimated number of undiscovered deposits, the grades, and the tonnages of the selected model to obtain the probability distributions for undiscovered metals in each tract. These distributions of grades and tonnages then can be used to conduct economic evaluations of undiscovered resources in a format usable by decisionmakers. Economic evaluations are not part of this report. The results of this assessment are presented in two principal parts. The first part identifies 26 regional tracts of land where the geology is permissive for the occurrence of undiscovered porphyry copper deposits of Phanerozoic age to a depth of 1 km below the Earth's surface. These tracts are believed to contain most of South America's undiscovered resources of copper. The

Texture orientation of glancing angle deposited copper nanowire arrays

International Nuclear Information System (INIS)

Alouach, H.; Mankey, G.J.

2004-01-01

Self-assembled copper nanowires were deposited on native oxide Si(100) substrates using glancing angle deposition with and without substrate rotation. Wire morphology, texture and crystallographic orientation are strongly dependent on the deposition parameters. A method for determining the preferred crystal orientation is described. This orientation is found to be different from what is expected from the geometric orientation of the wires. For wires deposited without substrate rotation, the face-centered-cubic (fcc)(111) crystal orientation, which corresponds to the close-packed, low surface energy (111) plane of copper, lies between the long axis of the wire and that normal to the substrate. X-ray diffraction data show that the wires exhibit bundling behavior perpendicular to the plane of incidence. For samples deposited with azimuthal rotation of the substrate, the fcc(111) directions in the wires are evenly distributed in a cone around the long axis of the wires, which point normal to the substrate. When the substrate is rotated during deposition at an angle of 75 deg., the wires exhibit a strong fcc(220) texture. These observations show that wires deposited with substrate rotation are highly textured and have random orientations in the plane of the substrate

Deposition of thermal and hot-wire chemical vapor deposition copper thin films on patterned substrates.

Science.gov (United States)

Papadimitropoulos, G; Davazoglou, D

2011-09-01

In this work we study the hot-wire chemical vapor deposition (HWCVD) of copper films on blanket and patterned substrates at high filament temperatures. A vertical chemical vapor deposition reactor was used in which the chemical reactions were assisted by a tungsten filament heated at 650 degrees C. Hexafluoroacetylacetonate Cu(I) trimethylvinylsilane (CupraSelect) vapors were used, directly injected into the reactor with the aid of a liquid injection system using N2 as carrier gas. Copper thin films grown also by thermal and hot-wire CVD. The substrates used were oxidized silicon wafers on which trenches with dimensions of the order of 500 nm were formed and subsequently covered with LPCVD W. HWCVD copper thin films grown at filament temperature of 650 degrees C showed higher growth rates compared to the thermally ones. They also exhibited higher resistivities than thermal and HWCVD films grown at lower filament temperatures. Thermally grown Cu films have very uniform deposition leading to full coverage of the patterned substrates while the HWCVD films exhibited a tendency to vertical growth, thereby creating gaps and incomplete step coverage.

Comparison of the mineralogy of the Boss-Bixby, Missouri copper-iron deposit, and the Olympic Dam copper-uranium-gold deposit, South Australia

International Nuclear Information System (INIS)

Brandom, R.T.; Hagni, R.D.; Allen, C.R.

1985-01-01

An ore microscopic examination of 80 polished sections prepared from selected drill core specimens from the Boss-Bixby, Missouri copper-iron deposit has shown that its mineral assemblage is similar to that of the Olympic Dam (Roxby Downs) copper-uranium-gold deposit in South Australia. A comparison with the mineralogy reported for Olympic Dam shows that both deposits contain: 1) the principal minerals, magnetite, hematite, chalcopyrite, and bornite, 2) the cobalt-bearing phases, carrollite and cobaltian pyrite, 3) the titanium oxides, rutile and anatase, 4) smaller amounts of martite, covellite, and electrum, 5) fluorite and carbonates, and 6) some alteration minerals. The deposits also are similar with regard to the sequence of mineral deposition: 1) early oxides, 2) then sulfide minerals, and 3) a final oxide generation. The deposits, however, are dissimilar with regard to their host rock lithologies and structural settings. The Boss-Bixby ores occupy breccia zones within a hydrothermally altered basic intrusive and intruded silicic volcanics, whereas the Olympic Dam ores are contained in sedimentary breccias in a graben or trough. Also, some minerals have been found thus far to occur at only one of the deposits. The similarity of mineralogy in these deposits suggests that they were formed from ore fluids that had some similarities in character and that the St. Francois terrane of Missouri is an important region for further exploration for deposits with this mineral assemblage

Significant deposits of gold, silver, copper, lead, and zinc in the United States

Science.gov (United States)

Long, K.R.; DeYoung, J.H.; Ludington, S.

2000-01-01

Approximately 99 percent of past production and remaining identified resources of gold, silver, copper, lead, and zinc in the United States are accounted for by deposits that originally contained at least 2 metric tonnes (t) gold, 85 t silver, 50,000 t copper, 30,000 t lead, or 50,000 t zinc. The U.S. Geological Survey, beginning with the 1996 National Mineral Resource Assessment, is systematically compiling data on these deposits, collectively known as 'significant' deposits. As of December 31, 1996, the significant deposits database contained 1,118 entries corresponding to individual deposits or mining districts. Maintaining, updating and analyzing a database of this size is much easier than managing the more than 100,000 records in the Mineral Resource Data System and Minerals Availability System/Minerals Industry Location System, yet the significant deposits database accounts for almost all past production and remaining identified resources of these metals in the United States. About 33 percent of gold, 22 percent of silver, 42 percent of copper, 39 percent of lead, and 46 percent of zinc are contained in or were produced from deposits discovered after World War II. Even within a database of significant deposits, a disproportionate share of past production and remaining resources is accounted for by a very small number of deposits. The largest 10 producers for each metal account for one third of the gold, 60 percent of the silver, 68 percent of the copper, 85 percent of the lead, and 75 percent of the zinc produced in the United States. The 10 largest deposits in terms of identified remaining resources of each of the five metals contain 43 percent of the gold, 56 percent of the silver, 48 percent of the copper, 94 percent of the lead, and 72 percent of the zinc. Identified resources in significant deposits for each metal are less than the mean estimates of resources in undiscovered deposits from the 1996 U.S. National Mineral Resource Assessment. Identified

Intertidal deposits: river mouths, tidal flats, and coastal lagoons

NARCIS (Netherlands)

Eisma, D.; Boer, de P.L.; Cadee, G.C.; Dijkema, K.; Ridderinkhof, H.; Phillippart, C.

1998-01-01

Intertidal Deposits: River Mouths, Tidal Flats, and Coastal Lagoons combines the authors personal and professional experience with the mass of available literature to present a cohesive overview of intertidal deposits and the widely diverse conditions of their formation worldwide. This includes the

Sorbitol as an efficient reducing agent for laser-induced copper deposition

Science.gov (United States)

Kochemirovsky, V. A.; Logunov, L. S.; Safonov, S. V.; Tumkin, I. I.; Tver'yanovich, Yu. S.; Menchikov, L. G.

2012-10-01

We have pioneered in revealing the fact that sorbitol may be used as an efficient reducing agent in the process of laser-induced copper deposition from solutions; in this case, it is possible to obtain copper lines much higher quality than by using conventional formalin.

On the mechanical and electrical properties of copper-silver and copper-silver-zirconium alloys deposits manufactured by cold spray

Energy Technology Data Exchange (ETDEWEB)

Coddet, Pierre, E-mail: pierre-laurent.coddet@univ-orleans.fr [Laboratoire National des Champs Magnétiques Intenses (LNCMI – CNRS-UPS-INSA-UJF), 25 Rue des Martyrs, 38042 Grenoble (France); Verdy, Christophe; Coddet, Christian [UTBM, Site de Sévenans, 90010 Belfort Cedex (France); Debray, François [Laboratoire National des Champs Magnétiques Intenses (LNCMI – CNRS-UPS-INSA-UJF), 25 Rue des Martyrs, 38042 Grenoble (France)

2016-04-26

In this work, several copper alloy deposits were manufactured by cold spray with helium as accelerating and carrier gas. Electrical conductivity was measured to establish the potential of cold spray as a manufacturing process for high strength (>500 MPa) and high conductivity (>90% IACS) copper alloys. The deposits which are characterized by a low oxygen content (<200 ppm) and a low porosity level (<0.1%) present yield strength values up to about 700 MPa and electrical conductivity values up to 58.2 MS/m (100.3% IACS). Results show that, even if a compromise has to be made between the properties according to the objectives of the application, this additive manufacturing route appears suitable for the production of large copper alloys parts with high mechanical properties and high electrical and thermal conductivity. The role of alloy composition and post heat treatments on the strength and conductivity of the deposits was especially considered in this work. Cold spray deposits properties were finally compared with those obtained with other manufacturing routes.

On the mechanical and electrical properties of copper-silver and copper-silver-zirconium alloys deposits manufactured by cold spray

International Nuclear Information System (INIS)

Coddet, Pierre; Verdy, Christophe; Coddet, Christian; Debray, François

2016-01-01

In this work, several copper alloy deposits were manufactured by cold spray with helium as accelerating and carrier gas. Electrical conductivity was measured to establish the potential of cold spray as a manufacturing process for high strength (>500 MPa) and high conductivity (>90% IACS) copper alloys. The deposits which are characterized by a low oxygen content (<200 ppm) and a low porosity level (<0.1%) present yield strength values up to about 700 MPa and electrical conductivity values up to 58.2 MS/m (100.3% IACS). Results show that, even if a compromise has to be made between the properties according to the objectives of the application, this additive manufacturing route appears suitable for the production of large copper alloys parts with high mechanical properties and high electrical and thermal conductivity. The role of alloy composition and post heat treatments on the strength and conductivity of the deposits was especially considered in this work. Cold spray deposits properties were finally compared with those obtained with other manufacturing routes.

Surface modification of an epoxy resin with polyamines and polydopamine: Adhesion toward electroless deposited copper

Energy Technology Data Exchange (ETDEWEB)

Schaubroeck, David, E-mail: David.Schaubroeck@elis.ugent.be [Center for Microsystems Technology (CMST), IMEC and Ghent University, Technologiepark 914A, B-9052 Ghent (Belgium); Mader, Lothar [Center for Microsystems Technology (CMST), IMEC and Ghent University, Technologiepark 914A, B-9052 Ghent (Belgium); Dubruel, Peter [Polymer Chemistry and Biomaterials Research Group, Ghent University, Krijgslaan 281 S4 bis, B-9000 Ghent (Belgium); Vanfleteren, Jan [Center for Microsystems Technology (CMST), IMEC and Ghent University, Technologiepark 914A, B-9052 Ghent (Belgium)

2015-10-30

Highlights: • Surface modifications of epoxy resins with polydopamine and grafted polyamines can significantly increase the adhesion toward electroless deposited copper. • A clear characterization of the copper/epoxy interphase is provided by SEM analyses of cross sections. • Tailored conditions such as etching time (roughness) and electroless deposition temperature are needed to increase the adhesion of the modified surfaces. - Abstract: In this paper the influence of the epoxy roughness, surface modifications and ELD (electroless copper deposition) temperatures on the adhesive strength of the copper is studied. Good adhesion at low roughness values is targeted due to their applicability in high density electronic circuits. Roughened epoxy surfaces are modified with adsorbed polyamines, polydopamine and polyamines grafted to polydopamine. Next the, adhesive strength of ELD copper is determined with peel strength measurements and the interphases are examined with SEM (scanning electron microscopy). Polydopamine and polyamines grafted to polydopamine can lead to increased adhesive strength at lower roughness values compared to the non-modified samples at specific plating temperatures.

Niobium thin film coating on a 500-MHz copper cavity by plasma deposition

Energy Technology Data Exchange (ETDEWEB)

Haipeng Wang; Genfa Wu; H. Phillips; Robert Rimmer; Anne-Marie Valente; Andy Wu

2005-05-16

A system using an Electron Cyclotron Resonance (ECR) plasma source for the deposition of a thin niobium film inside a copper cavity for superconducting accelerator applications has been designed and is being constructed. The system uses a 500-MHz copper cavity as both substrate and vacuum chamber. The ECR plasma will be created to produce direct niobium ion deposition. The central cylindrical grid is DC biased to control the deposition energy. This paper describes the design of several subcomponents including the vacuum chamber, RF supply, biasing grid and magnet coils. Operational parameters are compared between an operating sample deposition system and this system. Engineering work progress toward the first plasma creation will be reported here.

The Novo Okno copper deposit of olistostrome origin (Bor, Eastern Serbia

Directory of Open Access Journals (Sweden)

Antonijević Ivan

2011-01-01

Full Text Available The copper deposit Novo Okno, uncovered at present, with non-ore and ore clasts of massive sulphides (from 0.5 to 50 m3 in size, has many distinctive features that indicate its olistostrome origin. The deposit is chaotic in structure, unstratified, with the lower surface unconformable over the underlying parent rock of the basin. It is a lens-like body, with the longer axis directed east and west, variable in thickness from 15 to 28 metres, about 335 metres long and less than 140 metres wide. These and other characteristics of the body indicate a unified, reworked, olistostrome copper deposit formed from primary ore bodies of the Bor mineral deposit and vulcanite, destroyed by volcanic explosion into blocks and rocks of Turonian age and extrusion and concurrent deposition on the land surface. Gravitational massive sliding of the consolidated rocks down the slopes of the volcanic relief and chaotic accumulation of ore and non-ore clasts (olistoliths in a marine basin evolved in the Upper Turonian and the Lower Senonian.

Unusual behavior in magnesium-copper cluster matter produced by helium droplet mediated deposition

Energy Technology Data Exchange (ETDEWEB)

Emery, S. B., E-mail: samuel.emery@navy.mil; Little, B. K. [University of Dayton Research Institute, 300 College Park, Dayton, Ohio 45469 (United States); Air Force Research Laboratory, Munitions Directorate, 2306 Perimeter Rd., Eglin AFB, Florida 32542 (United States); Xin, Y. [National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida 32310 (United States); Ridge, C. J.; Lindsay, C. M. [Air Force Research Laboratory, Munitions Directorate, 2306 Perimeter Rd., Eglin AFB, Florida 32542 (United States); Buszek, R. J. [ERC Inc., Edwards AFB, California 93524 (United States); Boatz, J. A. [Air Force Research Laboratory, Aerospace System Directorate, Edwards AFB, California 93524 (United States); Boyle, J. M. [Naval Surface Warfare Center Indian Head Explosive Ordnance Technology Division, Indian Head, Maryland 20640 (United States)

2015-02-28

We demonstrate the ability to produce core-shell nanoclusters of materials that typically undergo intermetallic reactions using helium droplet mediated deposition. Composite structures of magnesium and copper were produced by sequential condensation of metal vapors inside the 0.4 K helium droplet baths and then gently deposited onto a substrate for analysis. Upon deposition, the individual clusters, with diameters ∼5 nm, form a cluster material which was subsequently characterized using scanning and transmission electron microscopies. Results of this analysis reveal the following about the deposited cluster material: it is in the un-alloyed chemical state, it maintains a stable core-shell 5 nm structure at sub-monolayer quantities, and it aggregates into unreacted structures of ∼75 nm during further deposition. Surprisingly, high angle annular dark field scanning transmission electron microscopy images revealed that the copper appears to displace the magnesium at the core of the composite cluster despite magnesium being the initially condensed species within the droplet. This phenomenon was studied further using preliminary density functional theory which revealed that copper atoms, when added sequentially to magnesium clusters, penetrate into the magnesium cores.

Timing of multiple hydrothermal events in the iron oxide-copper-gold deposits of the Southern Copper Belt, Carajás Province, Brazil

Science.gov (United States)

Moreto, Carolina P. N.; Monteiro, Lena V. S.; Xavier, Roberto P.; Creaser, Robert A.; DuFrane, S. Andrew; Melo, Gustavo H. C.; Delinardo da Silva, Marco A.; Tassinari, Colombo C. G.; Sato, Kei

2015-06-01

The Southern Copper Belt, Carajás Province, Brazil, hosts several iron oxide-copper-gold (IOCG) deposits, including Sossego, Cristalino, Alvo 118, Bacuri, Bacaba, Castanha, and Visconde. Mapping and U-Pb sensitive high-resolution ion microprobe (SHRIMP) IIe zircon geochronology allowed the characterization of the host rocks, situated within regional WNW-ESE shear zones. They encompass Mesoarchean (3.08-2.85 Ga) TTG orthogneiss, granites, and remains of greenstone belts, Neoarchean (ca. 2.74 Ga) granite, shallow-emplaced porphyries, and granophyric granite coeval with gabbro, and Paleoproterozoic (1.88 Ga) porphyry dykes. Extensive hydrothermal zones include albite-scapolite, biotite-scapolite-tourmaline-magnetite alteration, and proximal potassium feldspar, chlorite-epidote and chalcopyrite formation. U-Pb laser ablation multicollector inductively coupled mass spectrometry (LA-MC-ICP-MS) analysis of ore-related monazite and Re-Os NTIMS analysis of molybdenite suggest multiple Neoarchean (2.76 and 2.72-2.68 Ga) and Paleoproterozoic (2.06 Ga) hydrothermal events at the Bacaba and Bacuri deposits. These results, combined with available geochronological data from the literature, indicate recurrence of hydrothermal systems in the Southern Copper Belt, including 1.90-1.88-Ga ore formation in the Sossego-Curral ore bodies and the Alvo 118 deposit. Although early hydrothermal evolution at 2.76 Ga points to fluid migration coeval with the Carajás Basin formation, the main episode of IOCG genesis (2.72-2.68 Ga) is related to basin inversion coupled with Neoarchean (ca. 2.7 Ga) felsic magmatism. The data suggest that the IOCG deposits in the Southern Copper Belt and those in the Northern Copper Belt (2.57-Ga Salobo and Igarapé Bahia-Alemão deposits) do not share a common metallogenic evolution. Therefore, the association of all IOCG deposits of the Carajás Province with a single extensive hydrothermal system is precluded.

Halogen Chemistry of Hydrothermal Micas: a Possible Geochemical Tool in Vectoring to Ore for Porphyry Copper-Gold Deposit

Directory of Open Access Journals (Sweden)

Arifudin Idrus

2018-03-01

Full Text Available Porphyry copper-gold deposit commonly exhibits an extensive alteration zone of hydrothermal micas particularly biotite and sericite. This study is aimed to analyze and utilize the chemistry of halogen fluorine and chlorine of biotite and sericite to be a possible tool in vectoring to ore for copper porphyry deposits. To achieve the objectives, several selected altered rock samples were taken crossing the Batu Hijau copper-gold mine from inner to outer of the deposit, and hydrothermal micas contained by the rocks were analyzed petrographically and chemically. Mineral chemistry was detected by electron microprobe analyzer, whilst biotite is petrographically classified as either magmatic or hydrothermal types. Sericite replacing plagioclase occurred as fine-grained mineral and predominantly associated with argillic-related alteration types. Biotites in the Batu Hijau deposit are classified as phlogopite with a relatively low mole fraction magnesium (XMg (~0.75 compared to the “typical” copper porphyry deposit (~0.82. The relationship between the XMg and halogen contents are generally consistent with “Fe-F and Mg-Cl avoidance rules”.  F content in biotite and sericite decrease systematically from inner part of the deposit which is represented by early biotite (potassic zone where the main copper-gold hosted, to the outer part of the deposit. However, chlorine in both biotite and sericite from each of the alteration zones shows a relative similar concentration, which suggests that it is not suitable to be used in identification of the alteration zones associated with strong copper-gold mineralization. H2O content of the biotite and sericite also exhibits a systematic increase outward which may also provide a possible geochemical vector to ore for the copper porphyry deposits. This is well correlated with fluorine content of biotite in rocks and bulk concentration of copper from the corresponding rocks.

Deposition of copper coatings in a magnetron with liquid target

Energy Technology Data Exchange (ETDEWEB)

Tumarkin, A. V., E-mail: sanyahrustal@mail.ru; Kaziev, A. V.; Kolodko, D. V.; Pisarev, A. A.; Kharkov, M. M.; Khodachenko, G. V. [National Research Nuclear University MEPhI (Moscow Engineering Physics Institute) (Russian Federation)

2015-12-15

Copper coatings were deposited on monocrystalline Si substrates using a magnetron discharge with a liquid cathode in the metal vapour plasma. During the deposition, the bias voltage in the range from 0 V to–400 V was applied to the substrate. The prepared films were investigated by a scanning electron microscope, and their adhesive properties were studied using a scratch tester. It was demonstrated that the adhesion of the deposited films strongly depends on the bias voltage and varies in a wide range.

Analysis Of The Underpotential Deposition Of Cadmium On Copper

Directory of Open Access Journals (Sweden)

Kowalik R.

2015-09-01

Full Text Available In this study the process of deposition of cadmium on polycrystalline copper electrode in sulfate solution was investigated. The process of underpotential and bulk deposition was analyzed by classical electrochemical method: cyclic voltammetry(CV, anodic stripping voltammetry(ASV and electrochemical quartz crystal microbalance(EQCM. The obtained results were compared with electrochemical impedance spectroscopy(EIS measurements. CV, EQCM and EIS results suggest that the UPD of cadmium starts below potential −0.4 V vs Ag/AgCl. Additionally the stripping analysis indicates the formation of cadmium monolayer with different density of deposited atoms depending on the applied potential. The transition from UPD to bulk deposition occurs below potential −0,7 V.

Sputter deposition of tantalum-nitride films on copper using an rf-plasma

International Nuclear Information System (INIS)

Walter, K.C.; Fetherston, R.P.; Sridharan, K.; Chen, A.; Shamim, M.M.; Conrad, J.R.

1994-01-01

A tantalum-nitride film was successfully deposited at ambient temperature on copper with a modified ion-assisted-deposition (IAD) technique. The process uses an argon and nitrogen plasma to sputter deposit from a tantalum rf-cathode and ion implant the deposited film simultaneously. Both argon and nitrogen ions are used for sputtering and ion implantation. Auger spectroscopy and x-ray diffraction were used to characterize the resulting film

Halogen Chemistry of Hydrothermal Micas: a Possible Geochemical Tool in Vectoring to Ore for Porphyry Copper-Gold Deposit

OpenAIRE

Arifudin Idrus

2018-01-01

Porphyry copper-gold deposit commonly exhibits an extensive alteration zone of hydrothermal micas particularly biotite and sericite. This study is aimed to analyze and utilize the chemistry of halogen fluorine and chlorine of biotite and sericite to be a possible tool in vectoring to ore for copper porphyry deposits. To achieve the objectives, several selected altered rock samples were taken crossing the Batu Hijau copper-gold mine from inner to outer of the deposit, and hydrothermal micas co...

Influence of pulse ratio on codeposition of copper species with calcium phosphate coatings on titanium by means of electrochemically assisted deposition.

Science.gov (United States)

Wolf-Brandstetter, Cornelia; Oswald, Steffen; Bierbaum, Susanne; Wiesmann, Hans-Peter; Scharnweber, Dieter

2014-01-01

Aim of this study was to combine the well-known biocompatibility and ostoeconductivity of thin calcium phosphate coatings on titanium with proangiogenic signals from codeposited copper species. Copper species could be integrated in mineral layers based on hydroxyapatite by means of electrochemically assisted deposition from electrolytes containing calcium, phosphate, and copper ions. Different combinations of duration and intensity of galvanostatic pulses result in different amounts of deposited calcium phosphate and of copper species even for the same applied total charge. Absolute amounts of copper varied between 2.1 and 6.9 μg/cm², and the copper was distributed homogeneously as shown by EDX mapping. The presence of copper did not change the crystalline phase of deposited calcium phosphate (hydroxyapatite) but provoked a significant decrease in deposited amounts by factor 3 to 4. The copper was deposited mainly as Cu(I) species with a minor fraction of basic copper phosphates. Reduction of copper occurred not only at the surface of titanium but also within the hydroxyapatite coating due to the reaction with hydrogen produced by the electrolysis of water during the cathodic polarization of the substrate. Copyright © 2013 Wiley Periodicals, Inc.

Effects of vacuum processing erbium dideuteride/ditritide films deposited on chromium underlays on copper substrates

International Nuclear Information System (INIS)

Provo, J.L.

1978-01-01

Thin films of erbium dideuteride/ditritide were experimentally produced on chromium underlays deposited on copper substrates. The chromium underlay is required to prevent erbium occluder/copper substrate alloying which inhibits hydriding. Data taken has shown that vacuum processing affects the erbium/chromium/copper interaction. With an in situ process in which underlay/occluder films are vacuum deposited onto copper substrates and hydrided with no air exposure between these steps, data indicates a minimum of 1500A of chromium is required for optimum hydriding. If films are vacuum deposited as above and air-exposed before hydriding, a minimum of 3000A of chromium was shown to be required for equivalent hydriding. Data suggests that the activation step (600 0 C for 1 hour) required for hydriding the film of the second type is responsible for the difference observed. Such underlay thickness parameters are important, with regard to heat transfer considerations in thin hydride targets used for neutron generation

Improvement of copper plating adhesion on silane modified PET film by ultrasonic-assisted electroless deposition

International Nuclear Information System (INIS)

Lu Yinxiang

2010-01-01

Copper thin film on silane modified poly(ethylene terephthalate) (PET) substrate was fabricated by ultrasonic-assisted electroless deposition. The composition and topography of copper plating PET films were characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and atomic force microscopy (AFM), respectively. Peel adhesion strength, as high as 16.7 N/cm, was achieved for the planting copper layer to the modified PET substrate with ultrasonic-assisted deposition; however, a relative low value as 11.9 N/cm was obtained for the sample without ultrasonic vibration by the same measurement. The electrical conductivity of Cu film was changed from 7.9 x 10 4 to 2.1 x 10 5 S/cm by using ultrasonic technique. Ultrasonic operation has the significant merits of fast deposition and formation of good membranes for electroless deposition of Cu on PET film.

Rapid and highly efficient growth of graphene on copper by chemical vapor deposition of ethanol

Energy Technology Data Exchange (ETDEWEB)

Lisi, Nicola, E-mail: nicola.lisi@enea.it [ENEA, Materials Technology Unit, Surface Technology Laboratory, Casaccia Research Centre, Via Anguillarese 301, 00123 Rome (Italy); Buonocore, Francesco; Dikonimos, Theodoros; Leoni, Enrico [ENEA, Materials Technology Unit, Surface Technology Laboratory, Casaccia Research Centre, Via Anguillarese 301, 00123 Rome (Italy); Faggio, Giuliana; Messina, Giacomo [Dipartimento di Ingegneria dell' Informazione, delle Infrastrutture e dell' Energia Sostenibile (DIIES), Università “Mediterranea” di Reggio Calabria, 89122 Reggio Calabria (Italy); Morandi, Vittorio; Ortolani, Luca [CNR-IMM Bologna, Via Gobetti 101, 40129 Bologna (Italy); Capasso, Andrea [ENEA, Materials Technology Unit, Surface Technology Laboratory, Casaccia Research Centre, Via Anguillarese 301, 00123 Rome (Italy)

2014-11-28

The growth of graphene by chemical vapor deposition on metal foils is a promising technique to deliver large-area films with high electron mobility. Nowadays, the chemical vapor deposition of hydrocarbons on copper is the most investigated synthesis method, although many other carbon precursors and metal substrates are used too. Among these, ethanol is a safe and inexpensive precursor that seems to offer favorable synthesis kinetics. We explored the growth of graphene on copper from ethanol, focusing on processes of short duration (up to one min). We investigated the produced films by electron microscopy, Raman and X-ray photoemission spectroscopy. A graphene film with high crystalline quality was found to cover the entire copper catalyst substrate in just 20 s, making ethanol appear as a more efficient carbon feedstock than methane and other commonly used precursors. - Highlights: • Graphene films were grown by fast chemical vapor deposition of ethanol on copper. • High-temperature/short-time growth produced highly crystalline graphene. • The copper substrate was entirely covered by a graphene film in just 20 s. • Addition of H{sub 2} had a negligible effect on the crystalline quality.

High 210Po atmospheric deposition flux in the subtropical coastal area of Japan

International Nuclear Information System (INIS)

Tateda, Yutaka; Iwao, Kenji

2008-01-01

Bulk atmospheric deposition fluxes of 210 Po and 210 Pb were measured at three coastal regions of Japan, the Pacific Ocean coastal area of the Japanese mainland (Odawa Bay), the Chinese continental side of Japanese coastal area (Tsuyazaki), and an isolated island near Okinawa (Akajima). Wet and dry fallout collectors were continuously deployed from September 1997 through August 1998 for periods of 3 to 31 days depending on the frequency of precipitation events. Annual 210 Pb deposition fluxes at Odawa Bay (35 o N 139 o E), Tsuyazaki (33 o N 130 o E) and Akajima (26 o N 127 o E) were 73.3 ± 8.0, 197 ± 35 and 78.5 ± 8.0 Bq m -2 y -1 , respectively. Higher 210 Pb deposition was observed at the Chinese continental side of Japanese coast than at the Pacific Ocean coastal site. The high 210 Pb atmospheric flux at the Chinese continental side coast was thought to be attributable to 222 Rn-rich air-mass transport from the Chinese continent during the winter monsoon. In contrast, the annual 210 Po deposition fluxes at the three study sites were 13.0 ± 2.3 (Odawa Bay), 21.9 ± 4.4 (Tsuyazaki) and 58.4 ± 7.7 (Akajima) Bq m -2 y -1 , respectively, indicating unusual high 210 Po deposition at Akajima during winter. Anomalous unsupported 210 Po input was observed during summer 1997, suggesting unknown source of 210 Po at this area

Evolution of the microstructure in electrochemically deposited copper films at room temperature

DEFF Research Database (Denmark)

Pantleon, Karen; Somers, Marcel A. J.

2007-01-01

The room temperature evolution of the microstructure in copper electrodeposits (self-annealing) was investigated by means of X-ray diffraction analysis and simultaneous measurement of the electrical resistivity as a function of time with an unprecedented time resolution. Independent of the copper...... the crystallographic texture changes by a multiple twinning mechanism. The kinetics of self-annealing is strongly affected by the thickness of the deposit. Storage of the copper films at sub-zero temperatures effectively hinders self-annealing and does not affect the kinetics of self-annealing upon reheating to room...... temperature....

Magmatic Vapor Phase Transport of Copper in Reduced Porphyry Copper-Gold Deposits: Evidence From PIXE Microanalysis of Fluid Inclusions

Science.gov (United States)

Rowins, S. M.; Yeats, C. J.; Ryan, C. G.

2002-05-01

Nondestructive proton-induced X-ray emission (PIXE) studies of magmatic fluid inclusions in granite-related Sn-W deposits [1] reveal that copper transport out of reduced felsic magmas is favored by low-salinity vapor and not co-existing high-salinity liquid (halite-saturated brine). Copper transport by magmatic vapor also has been documented in oxidized porphyry Cu-Au deposits, but the magnitude of Cu partitioning into the vapor compared to the brine generally is less pronounced than in the reduced magmatic Sn-W systems [2]. Consideration of these microanalytical data leads to the hypothesis that Cu and, by inference, Au in the recently established "reduced porphyry copper-gold" (RPCG) subclass should partition preferentially into vapor and not high-salinity liquid exsolving directly from fluid-saturated magmas [3-4]. To test this hypothesis, PIXE microanalysis of primary fluid inclusions in quartz-sulfide (pyrite, pyrrhotite & chalcopyrite) veins from two RPCG deposits was undertaken using the CSIRO-GEMOC nuclear microprobe. PIXE microanalysis for the ~30 Ma San Anton deposit (Mexico) was done on halite-saturated aqueous brine (deposit (W. Australia) was done on halite-saturated "aqueous" inclusions, which contain a small (deposits of the new RPCG subclass demonstrate the greater potential of these systems, compared to the classically oxidized porphyry Cu-Au systems, to transport Cu and probably precious metals in a magmatic aqueous vapor phase. These PIXE data also support the possibility that Cu partitions preferentially into an immiscible CO2-rich magmatic fluid. References: [1] Heinrich, C.A. et al. (1992) Econ. Geol., 87, 1566-1583. [2] Heinrich, C.A. et al. (1999) Geology, 27, 755-758. [3] Rowins, S.M. (2000) Geology, 28, 491-494. [4] Rowins, S.M. (2000) The Gangue, GAC-MDD Newsletter, 67, 1-7 (www.gac.ca). [5] Rowins, S.M. et al. (1993) Geol. Soc. Australia Abs., 34, 68-70.

A study of copper, lead and cadmium speciation in some estuarine and coastal marine waters

Energy Technology Data Exchange (ETDEWEB)

Batley, G E; Gardner, D

1978-07-01

The significance of the measured changes in heavy metal distribution for different sampled environments was ascertained. The potential of a heavy metal speciation scheme to reflect differences in marine metal distributions was evaluated in a study of soluble copper, lead, and cadmium speciation in water samples from Port Hacking Estuary and one coastal Pacific station in Australia. In all samples, the percentages of metals associated with colloidal matter were high40-60% of total copper, 45-75% of total lead, and 15-35% of total cadmium. (1 map, 26 references, 4 tables)

Physiological responses of coastal phytoplankton (Visakhapatnam, SW Bay of Bengal, India) to experimental copper addition.

Science.gov (United States)

Biswas, Haimanti; Bandyopadhyay, Debasmita

2017-10-01

Trace amount of copper (Cu) is essential for many physiological processes; however, it can be potentially toxic at elevated levels. The impact of variable Cu concentrations on a coastal phytoplankton community was investigated along a coastal transect in SW Bay of Bengal. A small increase in Cu supply enhanced the concentrations of particulate organic carbon, particulate organic nitrogen, biogenic silica, total pigment, phytoplankton cell and total bacterial count. At elevated Cu levels all these parameters were adversely affected. δ 13 C POM and δ 15 N POC reflected a visible signature of both beneficial and toxic impacts of Cu supply. Skeletonema costatum, the dominant diatom species, showed higher tolerance to increasing Cu levels relative to Chaetoceros sp. Cyanobacteria showed greater sensitivity to copper than diatoms. The magnitude of Cu toxicity on the phytoplankton communities was inversely related to the distance from the coast. Co-enrichment of iron alleviated Cu toxicity to phytoplankton. Copyright © 2017 Elsevier Ltd. All rights reserved.

Solid state de-wetting observed for vapor deposited copper films on carbon substrates

International Nuclear Information System (INIS)

Schrank, C.; Eisenmenger-Sittner, C.; Neubauer, E.; Bangert, H.; Bergauer, A.

2004-01-01

Copper-Carbon composites are a good example for novel materials consisting of components with extremely different physical and chemical properties. They have a high potential for an application as heat sinks for electronic components, but the joining of the two materials is a difficult task. To obtain reasonable mechanical and thermal contact between copper and carbon the following route was chosen. First glassy-carbon substrates were subjected to an RF-Nitrogen plasma treatment. Then 300 nm thick copper coatings were sputter-deposited on the plasma treated surface within the same vacuum chamber. Finally, the samples were removed from the deposition chamber and either investigated immediately or thermally annealed at 850 deg. C under high vacuum conditions (10 -4 Pa). While non-annealed copper-coatings were continuous and showed excellent adhesion values of approximately 700 N/cm 2 , the heat treated samples lose their continuity by a de-wetting process. At the beginning holes are formed, then a labyrinth-like morphology develops and finally the coating consists of isolated droplets. All these processes occur well below the melting temperature of copper and were observed by AFM and SEM. The mechanism of this solid-state de-wetting process is investigated in relation to the recent literature on de-wetting and its consequences on the manufacturing of copper-carbon composites are discussed

The effect of antimony presence in anodic copper on kinetics and mechanism of anodic dissolution and cathodic deposition of copper

Directory of Open Access Journals (Sweden)

Stanković Z.D.

2008-01-01

Full Text Available The influence of the presence of Sb atoms, as foreign metal atoms in anode copper, on kinetics, and, on the mechanism of anodic dissolution and cathodic deposition of copper in acidic sulfate solution has been investigated. The galvanostatic single-pulse method has been used. Results indicate that presence of Sb atoms in anode copper increase the exchange current density as determined from the Tafel analysis of the electrode reaction. It is attributed to the increase of the crystal lattice parameter determined from XRD analysis of the electrode material.

Assessment of undiscovered sandstone copper deposits of the Kodar-Udokan area, Russia: Chapter M in Global mineral resource assessment

Science.gov (United States)

Zientek, Michael L.; Chechetkin, Vladimir S.; Parks, Heather L.; Box, Stephen E.; Briggs, Deborah A.; Cossette, Pamela M.; Dolgopolova, Alla; Hayes, Timothy S.; Seltmann, Reimar; Syusyura, Boris; Taylor, Cliff D.; Wintzer, Niki E.

2014-01-01

Mineral resource assessments integrate and synthesize available information as a basis for estimating the location, quality, and quantity of undiscovered mineral resources. This probabilistic mineral resource assessment of undiscovered sandstone copper deposits within Paleoproterozoic metasedimentary rocks of the Kodar-Udokan area in Russia is a contribution to a global assessment led by the U.S. Geological Survey (USGS). The purposes of this study are to (1) delineate permissive areas (tracts) to indicate where undiscovered sandstone-hosted copper deposits may occur within 2 km of the surface, (2) provide a database of known sandstone copper deposits and significant prospects, (3) estimate numbers of undiscovered deposits within these permissive tracts at several levels of confidence, and (4) provide probabilistic estimates of amounts of copper (Cu) and mineralized rock that could be contained in undiscovered deposits within each tract. The workshop for the assessment, held in October 2009, used a three-part form of mineral resource assessment as described by Singer (1993) and Singer and Menzie (2010).

Measurement of the specific surface area of loose copper deposit by electrochemical methods

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E. A. Dolmatova

2016-07-01

Full Text Available In the work the surface area of the electrode with dispersed copper deposit obtained within 30 seconds was evaluated by techniques of chronopotentiometry (CPM and impedance spectroscopy. In method CPM the electrode surface available for measurement depends on the value of the polarizing current. At high currents during the transition time there is a change of surface relief that can not determine the full surface of loose deposit. The electrochemical impedance method is devoid of this shortcoming since the measurements are carried out in indifferent electrolyte in the absence of current. The area measured by the impedance is tens of times higher than the value obtained by chronopotentiometry. It is found that from a solution containing sulfuric acid the deposits form with a high specific surface area. Based on these data it was concluded that the method of impedance spectroscopy can be used to measure in situ the surface area of the dispersed copper deposits.

N Deposition Effects on Hermes Copper Butterfly (Lycaena hermes) Habitat in Southern California

Science.gov (United States)

Malter, L. I.; Vourlitis, G. L.

2017-12-01

Atmospheric nitrogen (N) deposition has become a global concern over the past few decades as population sizes have increased. San Diego County, CA, USA, with a high population density, Mediterranean-type climate, and high biodiversity, is an ideal site for an extensive N deposition study. Chronic anthropogenic N deposition is one of the main contributing factors to affect plant species diversity (Vourlitis and Pasquini 2009) and invasive species encroachment (Minnich and Dezzani 1998). It is also the location of the rare endemic Hermes copper butterfly (Lycaena hermes), which has received minimal research and remains a mystery to many ecologists. We hypothesized that N deposition will impact Hermes abundance; however, there is limited research on the effects of N deposition on butterfly habitat. Thus, this study aims to determine the effect of increased N on the alterations to plant-insect interactions. These effects are being measured at five sites throughout San Diego County in current or historical Hermes copper habitat. N deposition collectors have been placed under the canopy of spiny redberry shrubs (Rhamnus crocea) to accumulate N throughfall at each site. Soil and redberry stem fragments are being used to analyze total N and Carbon (C), water potential, and shrub growth throughout the course of this study. Despite the preliminary nature of our results, we show a number of trends between data groups, such as large differences in soil and tissue N and C between the study sites, suggesting differences in atmospheric N inputs. These variations in soil N availability lead to variations in leaf tissue chemistry, which can ultimately impact the performance of the Hermes copper larvae. Our current data demonstrate some clear trends, but whether these trends remain consistent and interpretable remains to be seen. We anticipate this research will increase our understanding of spatial variation patterns of N deposition in southern California and how that N input might

Dzhezkazgan and associated sandstone copper deposits of the Chu-Sarysu basin, Central Kazakhstan

Science.gov (United States)

Box, Stephen E.; Seltmann, Reimar; Zientek, Michael L.; Syusyura, Boris; Creaser, Robert A.; Dolgopolova, Alla

2012-01-01

Sandstone-hosted copper (sandstone Cu) deposits occur within a 200-km reach of the northern Chu-Sarysu basin of central Kazakhstan (Dzhezkazgan and Zhaman-Aibat deposits, and the Zhilandy group of deposits). The deposits consist of Cu sulfide minerals as intergranular cement and grain replacement in 10 ore-bearing members of sandstone and conglomerate within a 600- to 1,000-m thick Pennsylvanian fluvial red-bed sequence. Copper metal content of the deposits ranges from 22 million metric tons (Mt, Dzehzkazgan) to 0.13Mt (Karashoshak in the Zhilandy group), with average grades of 0.85 to 1.7% Cu and significant values for silver (Ag) and rhenium (Re). Broader zones of iron reduction (bleaching) of sandstones and conglomerates of the red-bed sequence extend over 10 km beyond each of the deposits along E-NE-trending anticlines, which began to form in the Pennsylvanian. The bleached zones and organic residues within them are remnants of ormer petroleum fluid accumulations trapped by these anticlines. Deposit sites along these F1anticlines are localized at and adjacent to the intersections of nearly orthogonal N-NW-trending F2synclines. These structural lows served to guide the flow of dense ore brines across the petroleum-bearing anticlines, resulting in ore sulfide precipitation where the two fluids mixed. The ore brine was sourced either from the overlying Early Permian lacustrine evaporitic basin, whose depocenter occurs between the major deposits, or from underlying Upper Devonian marine evaporites. Sulfur isotopes indicate biologic reduction of sulfate but do not resolve whether the sulfate was contributed from the brine or from the petroleum fluids. New Re-Os age dates of Cu sulfides from the Dzhezkazgan deposit indicate that mineralization took place between 299 to 309 Ma near the Pennsylvanian-Permian age boundary. At the Dzhezkazgan and some Zhilandy deposits, F2fold deformation continued after ore deposition. Copper orebodies in Lower Permian

Surface modification of an epoxy resin with polyamines and polydopamine: The effect on the initial electroless copper deposition

Energy Technology Data Exchange (ETDEWEB)

Schaubroeck, David, E-mail: David.Schaubroeck@elis.ugent.be [Center for Microsystems Technology (CMST), imec and Ghent University, Technologiepark 914A, B-9052 Ghent (Belgium); Mader, Lothar [Center for Microsystems Technology (CMST), imec and Ghent University, Technologiepark 914A, B-9052 Ghent (Belgium); De Geyter, Nathalie; Morent, Rino [Research Unit Plasma Technology (RUPT), Department of Applied Physics, Faculty of Engineering, Ghent University, Sint-Pietersnieuwstraat 41, B-9000 Ghent (Belgium); Dubruel, Peter [Polymer Chemistry and Biomaterials Research Group, Ghent University, Krijgslaan 281 S4 bis, B-9000 Ghent (Belgium); Vanfleteren, Jan [Center for Microsystems Technology (CMST), imec and Ghent University, Technologiepark 914A, B-9052 Ghent (Belgium)

2014-06-01

This paper describes the influence of polydopamine and polyamine surface modifications of an etched epoxy cresol novolak (ECN) resin on the initial electroless copper deposition. Three different strategies to introduce polyamines on a surface in aqueous environment are applied: via polyethyleneimine adsorption (PEI), via polydopamine and via polyamines grafted to polydopamine. Next, the influence of these surface modifications on the catalytic palladium activation is investigated through X-ray photoelectron spectroscopy (XPS) analysis. Finally, the initial electroless copper deposition on modified epoxy surfaces is evaluated using SEM and Energy Dispersive Spectroscopy (EDS). Grafted polyamines on polydopamine surface modifications result in a large increase of the initial deposited copper.

The effects of a magnetic field on the morphologies of nickel and copper deposits: the concept of “effective overpotential”

Directory of Open Access Journals (Sweden)

NEBOJSA D. NIKOLIC

2007-08-01

Full Text Available The morphologies of nickel and copper deposits obtained without applied magnetic fields, and with both parallel and perpendicular applied magnetic fields were examined by the scanning electron microscopy (SEM technique. Changes in the morphologies of the metals caused by the effect of the magnetic fields are explained by the concept of “effective overpotential”. The morphologies of the nickel and copper deposits obtained under parallelly oriented magnetic fields were similar to those obtained at some lower cathodic potentials without an applied magnetic field. The magnetic field with a perpendicular orientation to the electrode surface increased the dispersity of the nickel and copper deposits. Nickel and copper deposits obtained under this orientation of the magnetic field were similar to those obtained at some higher cathodic potentials without an applied magnetic field.

The Olympic Dam copper-uranium-gold deposit, Roxby Downs, South Australia

International Nuclear Information System (INIS)

Roberts, D.E.; Hudson, G.R.T.

1983-01-01

The Olympic Dam copper-uranium-gold deposit appears to be a new type of strata-bound sediment-hosted ore deposit. It is located 650 km north-northwest of Adelaide in South Australia and was discovered in 1975. It has an areal extent exceeding 20 km 2 with vertical thicknesses of mineralization up to 350 m. The deposit is estimated to contain in excess of 2,000 million metric tons of mineralized material with an average grade of 1.6 percent copper, 0.06 percent uranium oxide, and 0.6 g/metric ton gold. The deposit occurs in the basement beneath 350 m of unmineralized, flat-lying Adelaidean (late Proterozoic) to Cambrian sediments in the Stuart shelf region of South Australia. The host rocks of the deposit are unmetamorphosed and are probably younger than 1,580 m.y. The deposit is spatially related to coincident gravity and magnetic anomalies and the intersection of west-northwest- and north-northwest-trending lineaments. The Proterozoic sediments comprising the local basement sequence are predominantly sedimentary breccias ranging from matrix-poor granite breccias to matrix-rich polymict breccias containing clasts of a variety of rock types. This sequence is over 1 km thick and has been divided into two main units--the Olympic Dam Formation and the Greenfield Formation. The Olympic Dam Formation has five members, three of which are matrix rich. The Greenfield Formation has three members, the lower two being very hematite rich while the upper has a significant volcanic component. Pervasive hematite, chlorite, and sericite alteration of varying intensity affects all the basement sequence

THE SECRETS OF MASSIVE SULFIDE DEPOSITS ON MID-OCEAN RIDGES AND KÜRE- MAĞARADORUK COPPER DEPOSIT

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Yılmaz ALTUN

2015-07-01

Full Text Available Küre region is located in western part of the Pontide tectonic belt. The oldest rocks around Küre are Paleozoic metamorphic rocks constituting “Rhodope-Pontide” continent. Liassic-pre Liassic ophiolites and basaltic volcanics, which form Paleotethys Ocean Floor are situated on “Rhodope-Pontide” continent as Paleotethys Ocean Floor residuals. Massive sulfide deposits in Küre Region are closely associated with pre Liassic – Liassic basaltic volcanics and inter- calating black shale. These deposits are considered to have formed during hydrothermal mi- neralization processes when basaltic volcanism had stopped and defined as “Black Smoker” today. Massive sulfide bodies in Mağaradoruk copper deposits are lens shaped. Although ore lenses take place sometimes in basalts and black shales, they are generally located on basalts and are covered by black shales. In Küre region, fold structures are intensely observed, and Mağaradoruk deposit is located on western flank of an overturned anticline. Mağaradoruk deposit is formed by several small and a big ore body and by less developed, underlying stockwork disseminated ore. The big ore body is 600 m long, 250 m wide and nearly 40 m thick. As main ore minerals; pyrite and chalcopyrite are observed. In few amounts; marcasite, magnetite, hematite, sphalerite, covelline, neo-digenite, malachite, azurite, fahlers are seen. In fewer amounts; bravoite, lineiite (karolite, limonite, and in trace amounts; chromite, rutile anatase, chalcosine, cuprite, tenorite, pyrrhotite, valleriite, bornite, galenite, native copper and native gold are observed. Main gangue minerals are; quartz, siderite-ankerite calcite, dolomite and chlorite. Mağaradoruk massive sulfide deposit rocks resembles to Siirt Madenköy, Ergani massive sulfide deposits, to “Cyprus” type massive sulfide deposits and modern Cyprus type massive sulfide deposits in terms of mineral contents; and to Ergani Mihrapdağı, Papuke, Pakotai

Plasma-enhanced chemical vapor deposition of graphene on copper substrates

Directory of Open Access Journals (Sweden)

Nicolas Woehrl

2014-04-01

Full Text Available A plasma enhanced vapor deposition process is used to synthesize graphene from a hydrogen/methane gas mixture on copper samples. The graphene samples were transferred onto SiO2 substrates and characterized by Raman spectroscopic mapping and atomic force microscope topographical mapping. Analysis of the Raman bands shows that the deposited graphene is clearly SLG and that the sheets are deposited on large areas of several mm2. The defect density in the graphene sheets is calculated using Raman measurements and the influence of the process pressure on the defect density is measured. Furthermore the origin of these defects is discussed with respect to the process parameters and hence the plasma environment.

Copper nanoparticle-deposited graphite felt electrodes for all vanadium redox flow batteries

International Nuclear Information System (INIS)

Wei, L.; Zhao, T.S.; Zeng, L.; Zhou, X.L.; Zeng, Y.K.

2016-01-01

Highlights: • Copper nanoparticle is proposed as electrocatalyst for VRFBs for the first time. • Propose a binder-free copper nanoparticle decorated electrode. • The energy efficiency is up to 80.1% at 300 mA cm"−"2, enhancing more than 17%. • High stability and capacity retention are achieved by battery with copper catalyst. - Abstract: A copper nanoparticle deposited graphite felt electrode for all vanadium redox flow batteries (VRFBs) is developed and tested. It is found that the copper catalyst enables a significant improvement in the electrochemical kinetics of the V"3"+/V"2"+ redox reaction. The battery’s utilization of the electrolyte and energy efficiency are found to be as high as 83.7% and 80.1%, at a current density of 300 mA cm"−"2, which are 53.1% and 17.8% higher than those of the battery without the catalyst. Moreover, the present battery shows a good stability during the cycle test. The results suggest that the inexpensive copper nanoparticle catalyst without tedious preparation process offers a great promise for VRFB application.

Nucleation and growth of copper phthalocyanine aggregates deposited from solution on planar surfaces

Energy Technology Data Exchange (ETDEWEB)

Ghani, Fatemeh [Department of Theory & Bio-Systems, Max Planck Institute of Colloids and Interfaces, Am Mühlenberg 1 Golm, 14476 Potsdam (Germany); Gojzewski, Hubert, E-mail: hubert.gojzewski@put.poznan.pl [Department of Theory & Bio-Systems, Max Planck Institute of Colloids and Interfaces, Am Mühlenberg 1 Golm, 14476 Potsdam (Germany); Institute of Physics, Poznan University of Technology, Piotrowo 3, 60-965 Poznan (Poland); Riegler, Hans [Department of Theory & Bio-Systems, Max Planck Institute of Colloids and Interfaces, Am Mühlenberg 1 Golm, 14476 Potsdam (Germany)

2015-10-01

Graphical abstract: - Highlights: • Copper phthalocyanine deposited on planar surfaces by 3 solution process methods. • Aggregate morphology examined for coverage extending over 3 orders of magnitude. • Morphologies vary from small individual domains to mesh-like multilayers. • Nucleation and growth model explains the observed deposit morphologies. - Abstract: Copper phthalocyanine (CuPc) dissolved in trifluoroacetic acid (TFA) is deposited on solid SiO{sub 2} surfaces by solvent evaporation. The deposited CuPc aggregates are investigated by atomic force microscopy (AFM). The CuPc deposits were prepared by spin casting, dip coating, and spray deposition. Depending on the amount of deposited CuPc the aggregate morphology ranges from small individual domains to mesh-like multilayers. Each domain/layer consists of many parallel stacks of CuPc molecules with the square, plate-like molecules piled face-wise within each stack. The parallel stacks are attached sideways (i.e., edgewise attachment molecularly) to the substrate forming “nanoribbons” with uniform thickness of about 1 nm and varying width. The thickness reflects the length of a molecular edge, the width the number of stacks. A nucleation and growth model is presented that explains the observed aggregate and multilayer morphologies as result of the combination of nucleation, transport processes and a consequence of the anisotropic intermolecular interactions due to the shape of the CuPc molecule.

Effect of deposition rate on melting point of copper film catalyst substrate at atomic scale

Science.gov (United States)

Marimpul, Rinaldo; Syuhada, Ibnu; Rosikhin, Ahmad; Winata, Toto

2018-03-01

Annealing process of copper film catalyst substrate was studied by molcular dynamics simulation. This copper film catalyst substrate was produced using thermal evaporation method. The annealing process was limited in nanosecond order to observe the mechanism at atomic scale. We found that deposition rate parameter affected the melting point of catalyst substrate. The change of crystalline structure of copper atoms was observed before it had been already at melting point. The optimum annealing temperature was obtained to get the highest percentage of fcc structure on copper film catalyst substrate.

REVIEW OF COASTAL CHARACTERISTICS OF IRON SAND DEPOSITS IN CILACAP CENTRAL JAVA

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Hananto Kurnio

2017-07-01

Full Text Available Mineable iron sand deposits in Cilacap – southern coastal area of Central Java have certain coastal characteristics that need to be studied in order to understand its depositional environment. With the knowledge of such environment, it can be applied to look for other places prospective of iron sand deposits that have the same characteristics especially recently when Cilacap’s deposits were almost depleted. Coastal characteristics of iron sand deposit in Cilacap is shown by successive sandy beach ridges separated by marshy valleys typical of prograded coasts and by dunes of sand elongated parallel to the shore line with elevation varies from 0 m to 15 m above sea level. The iron sand deposit was derived from denudation of andesite and “Old Andesite Formation” enriched in magnetite and ilmenite minerals in the steep elevated and deeply weathered rock hinterlands of Cilacap. High sediment loads of Serayu Basin in the hinterland (3,500-4,500 ton/km2/year; Citarum River basin only 800-1,200 ton/km2/year was causing extensive deposition of iron sand in the coastal zone. Key words: coast, characteristic, iron sand, Cilacap Endapan pasir besi yang dapat ditambang di Cilacap – pesisir selatan Jawa Tengah memiliki karakteristik pantai tertentu yang perlu dikaji agar dapat dipahami lingkungan pengendapannya. Dengan pengetahuan tentang lingkungan pengendapan tersebut, dapat diterapkan untuk mencari daerah-daerah lain prospek endapan pasir besi yang memiliki karakteristik yang sama terutama pada akhir-akhir ini ketika endapan Cilacap akan habis. Karakteristik pantai endapan pasir besi di Cilacap dicirikan oleh urutan pematang pantai berpasir yang dipisahkan oleh lembah-lembah berawa khas pantai maju dan oleh gumuk-gumuk pasir memanjang sejajar dengan garis pantai dengan ketinggian bervariasi dari 0 m hingga 15 m dari muka laut. Endapan pasir besi di daerah ini berasal dari proses denudasi andesit dan “Formasi Andesit

40Ar/39Ar geochronology of the El Teniente porphyry copper deposit

International Nuclear Information System (INIS)

Maksaev, V; Munizaga, F; McWilliams, M; Thiele, K; Arevalo, A; Zuniga, P; Floody, R

2001-01-01

Chile's El Teniente deposit is the largest known porphyry Cu-Mo orebody (>70 Mt Cu ), and is genetically related to Late Miocene-Early Pliocene igneous activity on the western slopes of the Andean Cordillera (cf. Howell and Molloy, 1960, Camus, 1975, Cuadra, 1986, Skewes and Stern, 1995). The deposit is 2700 m long by 1000 to 1700 m wide and is elongated in a N-S direction, with a recognized vertical extent of about 1800 m. Approximately 80% of the copper at El Teniente is distributed within a stockwork of mineralized veinlets and minor hydrothermal breccias within pervasively altered andesites, basalts and gabbros that are part of the Upper Miocene country rocks. Two intrusive bodies occur within the deposit, the Sewell Diorite (actually a tonalite) in the southeast part of the orebody and the dacitic Teniente Porphyry in its northern part. The Teniente Porphyry occurs as a north-south trending dike 1500 m long and 200 m wide. Minor quartz-diorite or tonalite intrusions known as the Central Diorite and the Northern Diorite occur along the eastern side of the deposit. Hydrothermal breccias commonly occur along the contacts of intrusive bodies with the country rocks. The Braden Breccia is a conspicuous diatreme in the center of the deposit that forms a pipe 1200 m in diameter at the surface, narrowing to 600 m at a depth of 1800 m. The Braden diatreme pipe is poorly mineralized (∼0.3% Cu), but it is surrounded by the copper-rich Marginal Breccia, a discontinuous rim of tourmaline-matrix hydrothermal breccia. Latite dikes intrude El Teniente, some forming altered ring dikes that encircle the Braden breccia pipe. After mineralization had ceased, the southern section of the deposit was cut by a 3.8 ± 0.3 Ma lamprophyre dyke, marking the end of igneous activity (Cuadra, 1986). Biotite-dominated K-silicate alteration is widespread within the orebody. In contrast, pervasive phyllic alteration is restricted to 'diorite' intrusions, and to the Braden and Marginal

Geochemical Exploration Techniques Applicable in the Search for Copper Deposits

Science.gov (United States)

Chaffee, Maurice A.

1975-01-01

Geochemical exploration is an important part of copper-resource evaluation. A large number of geochemical exploration techniques, both proved and untried, are available to the geochemist to use in the search for new copper deposits. Analyses of whole-rock samples have been used in both regional and local geochemical exploration surveys in the search for copper. Analyses of mineral separates, such as biotite, magnetite, and sulfides, have also been used. Analyses of soil samples are widely used in geochemical exploration, especially for localized surveys. It is important to distinguish between residual and transported soil types. Orientation studies should always be conducted prior to a geochemical investigation in a given area in order to determine the best soil horizon and the best size of soil material for sampling in that area. Silty frost boils, caliche, and desert varnish are specialized types of soil samples that might be useful sampling media. Soil gas is a new and potentially valuable geochemical sampling medium, especially in exploring for buried mineral deposits in arid regions. Gaseous products in samples of soil may be related to base-metal deposits and include mercury vapor, sulfur dioxide, hydrogen sulfide, carbon oxysulfide, carbon dioxide, hydrogen, oxygen, nitrogen, the noble gases, the halogens, and many hydrocarbon compounds. Transported materials that have been used in geochemical sampling programs include glacial float boulders, glacial till, esker gravels, stream sediments, stream-sediment concentrates, and lake sediments. Stream-sediment sampling is probably the most widely used and most successful geochemical exploration technique. Hydrogeochemical exploration programs have utilized hot- and cold-spring waters and their precipitates as well as waters from lakes, streams, and wells. Organic gel found in lakes and at stream mouths is an unproved sampling medium. Suspended material and dissolved gases in any type of water may also be useful

Deposition of Antimicrobial Copper-Rich Coatings on Polymers by Atmospheric Pressure Jet Plasmas

Directory of Open Access Journals (Sweden)

Jana Kredl

2016-04-01

Full Text Available Inanimate surfaces serve as a permanent reservoir for infectious microorganisms, which is a growing problem in areas in everyday life. Coating of surfaces with inorganic antimicrobials, such as copper, can contribute to reduce the adherence and growth of microorganisms. The use of a DC operated air plasma jet for the deposition of copper thin films on acrylonitrile butadiene styrene (ABS substrates is reported. ABS is a widespread material used in consumer applications, including hospitals. The influence of gas flow rate and input current on thin film characteristics and its bactericidal effect have been studied. Results from X-ray photoelectron spectroscopy (XPS and atomic force microscopy confirmed the presence of thin copper layers on plasma-exposed ABS and the formation of copper particles with a size in the range from 20 to 100 nm, respectively. The bactericidal properties of the copper-coated surfaces were tested against Staphylococcus aureus. A reduction in growth by 93% compared with the attachment of bacteria on untreated samples was observed for coverage of the surface with 7 at. % copper.

Descriptive models, grade-tonnage relations, and databases for the assessment of sediment-hosted copper deposits: with emphasis on deposits in the Central Africa Copperbelt, Democratic Republic of the Congo and Zambia: Chapter J in Global mineral resource assessment

Science.gov (United States)

Taylor, Cliff D.; Causey, J. Douglas; Denning, Paul; Hammarstrom, Jane M.; Hayes, Timothy S.; Horton, John D.; Kirschbaum, Michael J.; Parks, Heather L.; Wilson, Anna B.; Wintzer, Niki E.; Zientek, Michael L.

2013-01-01

The Central African Copperbelt (CACB) is one of the most important copper-producing regions of the world. The majority of copper produced in Africa comes from this region defined by the Neoproterozoic Katanga sedimentary basin of the southern Democratic Republic of the Congo (DRC) and northern Zambia. Copper in the CACB is mined from sediment-hosted stratabound copper deposits associated with red beds and includes the giant deposits in the Kolwezi and Tenge-Fungurume districts in the DRC and the Konkola-Musoshi and Nchanga-Chingola districts in Zambia. In recent years, sediment-hosted structurally controlled replacement and vein (SCRV) copper deposits, such as the giant Kansanshi deposit in Zambia have become important exploration targets in the CACB region.

Mineralogy of Copper-Gold Deposit, Masjid Daghi Area, Jolfa, IRAN

Science.gov (United States)

Zenoozi, Roya

2010-05-01

The Copper-Gold deposit of Masjid Daghi area is located in the Jolfa quadrangle (scale 1:100,000), East Azerbaijan Province, north-west Iran. The deposit, hosting by sub-volcanic bodies comprise of quartz monzonite composition whose intruded the Tertiary volcanic and volcanic-sedimentary rocks and turbidities. The Tertiary volcanic rocks consist of andesite, trachy andesite and quartz andesite. These mineral-bearing bodies related to Late Eocene sub-volcanic activities which intrudded the Eocene volcanic rocks. Mineralography, XRD and SEM studies showed that the variations in mineralization of the area. The main agent of mineralization is the intrusion of Late Eocene sub volcanic bodies inside the Tertiary volcanic units. The mineralography studies revealed two main groups of mineralization as oxides and sulfides. The sulfide minerals formed as veins, vein lets and stock work.The economic minerals comprise of native gold, copper sulfides. The native gold occurring in siliceous veins and almost as inclusions inside the sulfides minerals such as chalcopyrite. The copper sulfides, contain pyrite, chalcopyrite and chalco-pyrrhoyite. Pyrite is main sulfide in the area and formed as disseminations, cavity filling and colloform. The amount of pyrite, chalcopyrite and chalco-pyrrhoyite increases with depth. Supergene alteration produced digenite, covellite, bornite, and malachite. The alteration occurred as potassic, phyllic, argillic and propylitic minerals. Furthermore, selective sercitic, sericitic-chloritic and alunitic alterations are seen around the mineralized veins. The mineralography studies indicate that pyrite is main mineral phase and native gold occurred in silicious vein almost as inclusions inside the sulfide mineral. Most of economic mineral formed as veins, vein lets, disseminated, cavity filling and colloform which related to intrusions of Late Eocene quartz monzonite bodies into the Eocene volcanic rocks and turbiditse. Some types of alterations such as

Copper-vapor-catalyzed chemical vapor deposition of graphene on dielectric substrates

Science.gov (United States)

Yang, Chao; Wu, Tianru; Wang, Haomin; Zhang, Xuefu; Shi, Zhiyuan; Xie, Xiaoming

2017-07-01

Direct synthesis of high-quality graphene on dielectric substrates is important for its application in electronics. In this work, we report the process of copper-vapor-catalyzed chemical vapor deposition of high-quality and large graphene domains on various dielectric substrates. The copper vapor plays a vital role on the growth of transfer-free graphene. Both single-crystal domains that are much larger than previous reports and high-coverage graphene films can be obtained by adjusting the growth duration. The quality of the obtained graphene was verified to be comparable with that of graphene grown on Cu foil. The progress reported in this work will aid the development of the application of transfer-free graphene in the future.

Physical and chemical properties of deposited airborne particulates over the Arabian Red Sea coastal plain

KAUST Repository

Engelbrecht, Johann; Stenchikov, Georgiy L.; Prakash, P. Jish; Lersch, Traci; Anisimov, Anatolii; Shevchenko, Illia

2017-01-01

) situated on the Red Sea coastal plain of Saudi Arabia and subjected to the same chemical and mineralogical analysis we conducted on soil samples. Frisbee deposition samplers with foam inserts were used to collect dust and other deposits, for the period

Plasma Deposition and Characterization of Copper-doped Cobalt Oxide Nanocatalysts

Directory of Open Access Journals (Sweden)

Jacek TYCZKOWSKI

2013-09-01

Full Text Available A series of pure and copper-doped cobalt oxide films was prepared by plasma-enhanced metalorganic chemical vapor deposition (PEMOCVD. The effect of Cu-doping on the chemical structure and morphology of the deposited films was investigated. Raman and FTIR spectroscopies were used to characterize the chemical structure and morphology of the produced films. The bulk composition and homogeneity of the samples were investigated by energy dispersive X-ray microanalysis (EDX, and X-ray photoelectron spectroscopy (XPS was employed to assess the surface chemical composition of pure and doped materials. The obtained results permit to affirm that the PEMOCVD technique is a simple, versatile and efficient method for providing homogeneous layers of cobalt oxides with a different content of copper. It has been found that pure cobalt oxide films mainly contain Co3O4 in the form of nanoclusters whereas the films doped with Cu are much more complex, and CoOx (also Co3O4, mixed Co-Cu oxides and CuOx nanoclusters are detected in them. Preliminary catalytical tests show that Cu-doped cobalt oxide films allow to initiate catalytic combustion of n-hexane at a lower temperature compared to the pure cobalt oxide (Co3O4 films. From what has been stated above, the plasma-deposited thin films of Cu-doped cobalt oxides pave the way towards a new class of nanomaterials with interesting catalytic properties. DOI: http://dx.doi.org/10.5755/j01.ms.19.3.2320

Laser-induced chemical liquid deposition of discontinuous and continuous copper films

Czech Academy of Sciences Publication Activity Database

Ouchi, A.; Bastl, Zdeněk; Boháček, Jaroslav; Šubrt, Jan; Pola, Josef

2007-01-01

Roč. 201, č. 8 (2007), s. 4728-4733 ISSN 0257-8972 R&D Projects: GA AV ČR 1ET400400413 Institutional research plan: CEZ:AV0Z40400503; CEZ:AV0Z40320502; CEZ:AV0Z40720504 Keywords : copper films * laser photolysis * Cu(II) acetylacetonate * chemical liquid deposition Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.678, year: 2007

Stable isotope evidence for formation from magmatic fluids of the mineralized breccias in the Los Bronces and El Teniente copper deposits, Central Chile

International Nuclear Information System (INIS)

Skewes, M.A; Arevalo, A; Holmgren, C.; Stern, C.R

2001-01-01

The giant Miocene and Pliocene Rio Blanco-Los Bronces (Warnaars et al., 1985; Serrano et al., 1996; Vargas et al., 1999) and El Teniente (Camus, 1975; Cuadra, 1986; Skewes and Arevalo, 2000) copper deposits of central Chile are among the largest copper deposits in the world. Hypogene copper ore is more significant than supergene ore in these deposits, and most of the hypogene copper occurs in the matrix of multiple clusters of breccias (Skewes and Stern, 1994; 1995). The origin of the large mineralized breccia pipes in these and other Andean copper deposits has been attributed to the explosive expansion of magmatic aqueous fluids derived from cooling plutons (Emmons, 1938; Kents, 1964; Warnaars et al., 1985; Sillitoe, 1985; Skewes and Stern, 1994, 1995). Warnaars et al. (1985) and Skewes and Stern (1996) suggested that mineral deposition in the matrix of these breccias took place by the rapid cooling of the same magmatic fluids that generated the brecciation. Highly saline, high-temperature magmatic fluid inclusions occur in quartz and tourmaline in the matrix of these breccias (Holmgren et al., 1988; Vargas et al., 1999; Skewes et al., 2001) (au)

Even low to medium nitrogen deposition impacts vegetation of dry, coastal dunes around the Baltic Sea

International Nuclear Information System (INIS)

Remke, Eva; Brouwer, Emiel; Kooijman, Annemieke; Blindow, Irmgard; Esselink, Hans; Roelofs, Jan G.M.

2009-01-01

Coastal dunes around the Baltic Sea have received small amounts of atmospheric nitrogen and are rather pristine ecosystems in this respect. In 19 investigated dune sites the atmospheric wet nitrogen deposition is 3-8 kg N ha -1 yr -1 . The nitrogen content of Cladonia portentosa appeared to be a suitable biomonitor of these low to medium deposition levels. Comparison with EMEP-deposition data showed that Cladonia reflects the deposition history of the last 3-6 years. With increasing nitrogen load, we observed a shift from lichen-rich short grass vegetation towards species-poor vegetation dominated by the tall graminoid Carex arenaria. Plant species richness per field site, however, does not decrease directly with these low to medium N deposition loads, but with change in vegetation composition. Critical loads for acidic, dry coastal dunes might be lower than previously thought, in the range of 4-6 kg N ha -1 yr -1 wet deposition. - Even low to medium nitrogen deposition impacts Baltic dune vegetation promoting a dominance of taller graminoids

Atmospheric ammonia measurements along the coastal lines of Southeastern China: Implications for inorganic nitrogen deposition to coastal waters

Science.gov (United States)

Wu, Shui-Ping; Dai, Lu-Hong; Wei, Ya; Zhu, Heng; Zhang, Yin-Ju; Schwab, James J.; Yuan, Chung-Shin

2018-03-01

Ambient NH3 concentrations were determined using Ogawa passive samplers along the coastal lines of southeast China from June 2015 to May 2017. Additional monitoring of PM2.5 and precipitation around Xiamen Bay during the period from November 2015 to May 2017 were carried out to estimate atmospheric inorganic nitrogen (IN) deposition to the bay. Distinct seasonal variations of ambient NH3 were observed with summer averages 1.41-5.56 times higher than winter, which agreed well with the seasonal trend of air temperature. Nitrate concentrations (pNO3-) in PM2.5 were significantly higher than ammonium concentrations (pNH4+), and both species showed higher concentrations in winter and spring and lower values in summer and fall which were influenced mainly by the monsoon cycle, gas-to-particle transformation process and rain washout. Paired t-testing revealed that no significant differences of pNO3- and pNH4+ between the urban and suburban sites around the Xiamen Bay. Unlike pNO3- and pNH4+, there were no clear seasonal trends for NH4+ and NO3- concentrations in precipitation samples (wNH4+ and wNO3-). On average, the deposition of IN consisted of NH3-N (27.4-28.2%) and pNO3--N (25.9-26.8%), followed by pNH4+-N (17.0-17.7%), wNH4+-N (14.5%), wNO3--N (13.3-13.8%) and NO2-N (0.35-0.46%); and showed distinct seasonal trends with higher values in winter/spring and lower values in summer/fall. In 2016, the total IN deposition was determined to be 36.45 and 35.92 kg N ha-1 at the urban and suburban sites around the Xiamen Bay, respectively. The proportion of IN deposition to total IN loads (terrestrial + atmospheric), varied over the range of 7.1-13.3% depending on the data source of riverine influx. Our observations revealed that the total IN deposition could account for 9.6-25.1% (based on primary productivity over Taiwan Strait) and 1.7-5.3% (based on primary productivity in Guangdong coastal region) of new productivity in Xiamen Bay, respectively. As an important nutrient

Qualitative assessment of selected areas of the world for undiscovered sediment-hosted stratabound copper deposits: Chapter Y in Global mineral resource assessment

Science.gov (United States)

Zientek, Michael L.; Wintzer, Niki E.; Hayes, Timothy S.; Parks, Heather L.; Briggs, Deborah A.; Causey, J. Douglas; Hatch, Shyla A.; Jenkins, M. Christopher; Williams, David J.; Zientek, Michael L.; Hammarstrom, Jane M.; Johnson, Kathleen M.

2015-12-14

A qualitative mineral resource assessment of sediment-hosted stratabound copper mineralized areas for undiscovered copper deposits was performed for 10 selected areas of the world. The areas, in alphabetical order, are (1) Belt-Purcell Basin, United States and Canada; (2) Benguela and Cuanza Basins, Angola; (3) Chuxiong Basin, China; (4) Dongchuan Group rocks, China; (5) Egypt–Israel–Jordan Rift, Egypt, Israel, and Jordan; (6) Maritimes Basin, Canada; (7) Neuquén Basin, Argentina; (8) Northwest Botswana Rift, Botswana and Namibia; (9) Redstone Copperbelt, Canada; and (10) Salta Rift System, Argentina. This assessment (1) outlines the main characteristics of the areas, (2) classifies known deposits by deposit model subtypes, and (3) ranks the areas according to their potential to contain undiscovered copper deposits.

Effects of sputtering power on properties of copper oxides thin films deposited on glass substrates

Energy Technology Data Exchange (ETDEWEB)

Ooi, P. K.; Ng, S. S.; Abdullah, M. J. [Nano-Optoelectronics Research and Technology Laboratory, School of Physics, Universiti Sains Malaysia, 11800 Penang (Malaysia)

2015-04-24

Copper oxides are deposited by radio frequency sputtering using copper target in the mixture of argon and oxygen gasses. The structural and optical properties of the copper oxides deposited at different sputtering powers have been investigated. All the films are single phase polycrystalline. At low RF power (100 W), the film is monoclinic structure of cupric oxide (CuO). Meanwhile, the films are cubic structure of cuprous oxide (Cu2O) at higher RF power. Field emission scanning electron microscopy images show the films have different morphologies with small grain size and consist of a lot of voids. The analysis of energy dispersive X-ray spectroscopy shows that the ratio of Cu to O is increased as the RF power increased. From the ultraviolet–visible spectroscopy, the films have a broad absorption edge in the range of 300–500 nm. The band gap of the films grown at RF power of 100 W, and 120 W and above, were 1.18 eV and 2.16 eV, respectively.

Genetic investigation of natural hybridization between rainbow and coastal cutthroat trout in the copper River Delta, Alaska

Science.gov (United States)

Williams, I.; Reeves, G.H.; Graziano, S.L.; Nielsen, J.L.

2007-01-01

Molecular genetic methods were used to quantify natural hybridization between rainbow trout Oncorhynchus mykiss or steelhead (anadromous rainbow trout) and coastal cutthroat trout O. clarkii clarkii collected in the Copper River delta, Southeast Alaska. Eleven locations were sampled to determine the extent of hybridization and the distribution of hybrids. Four diagnostic nuclear microsatellite loci and four species-specific simple sequence repeat markers were used in combination with restriction fragment length polymorphism analyses of NADH dehydrogenase 5/6 (ND5/6) mitochondrial DNA (mtDNA) to investigate the genetic structure of trout from both species and identify putative interspecific hybrids. Hybrids were found in 7 of the 11 streams sampled in the Copper River delta, the extent of hybridization across all streams varying from 0% to 58%. Hybrid trout distribution appeared to be nonrandom, most individuals of mixed taxonomic ancestry being detected in streams containing rainbow trout rather than in streams containing coastal cutthroat trout. Genotypic disequilibrium was observed among microsatellite loci in populations with high levels of hybridization. We found no significant correlation between unique stream channel process groups and the number of hybrid fish sampled. Eighty-eight percent of fish identified as first-generation hybrids (F1) in two populations contained coastal cutthroat trout mtDNA, suggesting directionality in hybridization. However, dominance of coastal cutthroat trout mtDNA was not observed at a third location containing F1 hybrids, indicating that interspecific mating behavior varied among locations. Backcrossed individuals were found in drainages lacking F1 hybrids and in populations previously thought to contain a single species. The extent and distribution of backcrossed individuals suggested that at least some hybrids are reproductively viable and backcrossed hybrid offspring move throughout the system.

The mass balance calculation of hydrothermal alteration in Sarcheshmeh porphyry copper deposit

Directory of Open Access Journals (Sweden)

Mohammad Maanijou

2013-10-01

Full Text Available Sarcheshmeh porphyry copper deposit is located 65 km southwest of Rafsanjan in Kerman province. The Sarcheshmeh deposit belongs to the southeastern part of Urumieh-Dokhtar magmatic assemblage (i.e., Dehaj-Sarduyeh zone. Intrusion of Sarcheshmeh granodiorite stock in faulted and thrusted early-Tertiary volcano-sedimentary deposits, led to mineralization in Miocene. In this research, the mass changes and element mobilities during hydrothermal process of potassic alteration were studied relative to fresh rock from the deeper parts of the plutonic body, phyllic relative to potassic, argillic relative to phyllic and propylitic alteration relative to fresh andesites surrounding the deposit. In the potassic zone, enrichment in Fe2O3 and K2O is so clear, because of increasing Fe coming from biotite alteration and presence of K-feldspar, respectively. Copper and molybdenum enrichments resulted from presence of chalcopyrite, bornite and molybdenite mineralization in this zone. Enrichment of SiO2 and depletion of CaO, MgO, Na2O and K2O in the phyllic zone resulted from leaching of sodium, calcium and magnesium from the aluminosilicate rocks and alteration of K-feldspar to sericite and quartz. In the argillic zone, Al2O3, CaO, MgO, Na2O and MnO have also been enriched in which increasing Al2O3 may be from kaolinite and illite formation. Also, enrichment in SiO2, Al2O3 and CaO in propylitic alteration zone can be attributed to the formation of chlorite, epidote and calcite as indicative minerals of this zone.

Parametric Investigation of Diode and CO2 Laser in Direct Metal Deposition of H13 Tool Steel on Copper Substrate

OpenAIRE

M. Khalid Imran; Syed Masood; Milan Brandt; Sudip Bhattacharya; Jyotirmoy Mazumder

2011-01-01

In the present investigation, H13 tool steel has been deposited on copper alloy substrate using both CO2 and diode laser. A detailed parametric analysis has been carried out in order to find out optimum processing zone for coating defect free H13 tool steel on copper alloy substrate. Followed by parametric optimization, the microstructure and microhardness of the deposited clads have been evaluated. SEM micrographs revealed dendritic microstructure in both clads. However,...

Economic filters for evaluating porphyry copper deposit resource assessments using grade-tonnage deposit models, with examples from the U.S. Geological Survey global mineral resource assessment: Chapter H in Global mineral resource assessment

Science.gov (United States)

Robinson, Gilpin R.; Menzie, W. David

2012-01-01

An analysis of the amount and location of undiscovered mineral resources that are likely to be economically recoverable is important for assessing the long-term adequacy and availability of mineral supplies. This requires an economic evaluation of estimates of undiscovered resources generated by traditional resource assessments (Singer and Menzie, 2010). In this study, simplified engineering cost models were used to estimate the economic fraction of resources contained in undiscovered porphyry copper deposits, predicted in a global assessment of copper resources. The cost models of Camm (1991) were updated with a cost index to reflect increases in mining and milling costs since 1989. The updated cost models were used to perform an economic analysis of undiscovered resources estimated in porphyry copper deposits in six tracts located in North America. The assessment estimated undiscovered porphyry copper deposits within 1 kilometer of the land surface in three depth intervals.

Current and historic mercury deposition to New Haven Harbor (CT, USA): Implications for industrial coastal environments

International Nuclear Information System (INIS)

Clark, Heather F.; Benoit, Gaboury

2009-01-01

This study quantifies historic and current mercury contamination in New Haven Harbor (New Haven, Connecticut, USA) through the analysis of sediment cores. The mercury concentration measured in surface sediment ranged from 320 to 1640 μg kg -1 with an average of 530 μg kg -1 . The harbor is relatively small in area (6.6 km 2 ) but displays a large range in concentrations, illustrating the important methodological issue that a large number of samples may be necessary to capture the variability in even a small area. Depth profiles of mercury reflect sedimentation over a range of 20 to 200 years and indicate a complex history of contamination. Mercury depth profiles were compared with lead, copper, cadmium, and silver concentrations and the metals generally covary. This trend indicates that the sources of mercury and heavy metals are linked and that regionally specific sources dominate the historic input of metals rather than large-scale atmospheric deposition patterns. Results also show there are large differences in absolute concentrations of metals among sites in the harbor. Differences in the abundance of Fe-rich, fine-grained sediment likely control the level of metals in various parts of the harbor. Proximity to current sources and the long, diverse industrial history of the harbor also influence the distribution pattern. All of the cores can be modeled as mixing between pre-industrial sediments and either one or two pollution endmembers. This study demonstrates the importance of riverine sources in the mass balance of mercury delivered to coastal areas and of watershed management to preserve coastal ecosystems.

Porphyry copper deposits distribution along the western Tethyan and Andean subductions: insights from a paleogeographic approach

Science.gov (United States)

Bertrand, G.

2012-12-01

The genesis of many types of mineral deposits is closely linked to tectonic and petrographic conditions resulting from specific geodynamic contexts. Porphyry deposits, for instance, are associated to calc-alkaline magmatism of subduction zones. In order to better understand the relationships between ore deposit distribution and their tectonic context, and help identifying geodynamic-related criteria of favorability that would, in turn, help mineral exploration, we propose a paleogeographic approach. Paleogeographic reconstructions, based on global or regional plate tectonic models, are crucial tools to assess tectonic and kinematic contexts of the past. We use this approach to study the distribution of porphyry copper deposits along the western Tethyan and Andean subductions since Lower Cretaceous and Paleocene, respectively. For both convergent contexts, databases of porphyry copper deposits, including, among other data, their age and location, were compiled. Spatial and temporal distribution of the deposits is not random and show that they were emplaced in distinct clusters. Five clusters are identified along the western Tethyan suture, from Lower Cretaceous to Pleistocene, and at least three along the Andes, from Paleocene to Miocene. Two clusters in the Aegean-Balkan-Carpathian area, that were emplaced in Upper Cretaceous and Oligo-Miocene, and two others in the Andes, that were emplaced in late Eocene and Miocene, are studied in details and correlated with the past kinematics of the Africa-Eurasia and Nazca-South America plate convergences, respectively. All these clusters are associated with a similar polyphased kinematic context that is closely related to the dynamics of the subductions. This context is characterized by 1) a relatively fast convergence rate, shortly followed by 2) a drastic decrease of this rate. To explain these results, we propose a polyphased genetic model for porphyry copper deposits with 1) a first stage of rapid subduction rate

Formation of dish-like holes and a channel structure in electrodeposition of copper under hydrogen co-deposition

International Nuclear Information System (INIS)

Nikolic, N.D.; Pavlovic, Lj.J.; Pavlovic, M.G.; Popov, K.I.

2007-01-01

Copper electrodeposition from acid sulfate solutions at an overpotential of 1000 mV, which is about 250 mV outside the plateau of the limiting diffusion current density, was examined by the determination of the average current efficiency of hydrogen evolution and by the scanning electron microscopic (SEM) analysis of the morphology of the formed copper deposits. Craters or holes formed due to the attachment hydrogen bubbles were the dominant morphological forms of copper deposits obtained at this overpotential. In dependence of the concentration of Cu (II) ions in the plating solution, the two types of holes or craters were formed. One type of holes is obtained by electrodeposition from a solution with a concentration of Cu (II) ions of 0.075 M CuSO 4 in 0.50 M H 2 SO 4 , and a honeycomb-like structure was formed from these holes. The other types of holes are formed from a solution with a higher concentration of Cu (II) ions (0.60 M CuSO 4 in 0.50 M H 2 SO 4 ) and the formed holes were dish-like. A mixture of both types of holes was obtained by electrodeposition from 0.30 M CuSO 4 in 0.50 M H 2 SO 4 . The obtained morphologies of copper deposits are discussed in terms of the effect of hydrogen evolution on the hydrodynamic conditions in the plating solution

Visualisation of latent fingermarks on polymer banknotes using copper vacuum metal deposition: A preliminary study.

Science.gov (United States)

Davis, Lloyd W L; Kelly, Paul F; King, Roberto S P; Bleay, Stephen M

2016-09-01

The UK's recent move to polymer banknotes has seen some of the currently used fingermark enhancement techniques for currency potentially become redundant, due to the surface characteristics of the polymer substrates. Possessing a non-porous surface with some semi-porous properties, alternate processes are required for polymer banknotes. This preliminary investigation explored the recovery of fingermarks from polymer notes via vacuum metal deposition using elemental copper. The study successfully demonstrated that fresh latent fingermarks, from an individual donor, could be clearly developed and imaged in the near infrared. By varying the deposition thickness of the copper, the contrast between the fingermark minutiae and the substrate could be readily optimised. Where the deposition thickness was thin enough to be visually indistinguishable, forensic gelatin lifters could be used to lift the fingermarks. These lifts could then be treated with rubeanic acid to produce a visually distinguishable mark. The technique has shown enough promise that it could be effectively utilised on other semi- and non-porous substrates. Copyright © 2016 Elsevier Ireland Ltd. All rights reserved.

Usability of #betta#-spectrometric method to prospecting for copper-porphyric skarn and gold-quartz-sulfide deposits

International Nuclear Information System (INIS)

Syromyatnikov, N.G.; Ivanova, Eh.I.; Karpukhin, V.G.; Trofimova, L.A.; Tolmachev, I.I.

1982-01-01

Possibility of the prospecting for non-radioactive element deposits by means of radioactive elements as indicators is studied. Radioactive elements (uranium, thorium and potassium) were determined by gamma spectroscopy. Radiometric methods of prospecting are effective and economical. Clark contents of radioelements in rocks were determined in situ by field gamma spectrometers. It is established that copper-porphyric deposits are regularly controlled from the surface by aureoles of increased uranium contents, which sizes reach 400x500 m and can be revealed by gamma spectroscopy during 1:25000 and more large-scale survey. Skarn-ore zones of deposits of different mineral types (copper, polymetallic, iron ore ones) are fixed on the surface by increased radioactivity; this fact can be used as search criterion. Gold-bearing quartz veins differ from barren lodes by a higher level of total radioactivity and high potassium content. Top walls of ore-bearing quartz veins are mainly enriched by radioelements

Atomic-layer-deposited WNxCy thin films as diffusion barrier for copper metallization

Science.gov (United States)

Kim, Soo-Hyun; Oh, Su Suk; Kim, Ki-Bum; Kang, Dae-Hwan; Li, Wei-Min; Haukka, Suvi; Tuominen, Marko

2003-06-01

The properties of WNxCy films deposited by atomic layer deposition (ALD) using WF6, NH3, and triethyl boron as source gases were characterized as a diffusion barrier for copper metallization. It is noted that the as-deposited film shows an extremely low resistivity of about 350 μΩ cm with a film density of 15.37 g/cm3. The film composition measured from Rutherford backscattering spectrometry shows W, C, and N of ˜48, 32, and 20 at. %, respectively. Transmission electron microscopy analyses show that the as-deposited film is composed of face-centered-cubic phase with a lattice parameter similar to both β-WC1-x and β-W2N with an equiaxed microstructure. The barrier property of this ALD-WNxCy film at a nominal thickness of 12 nm deposited between Cu and Si fails only after annealing at 700 °C for 30 min.

Cobalt—Styles of deposits and the search for primary deposits

Science.gov (United States)

Hitzman, Murray W.; Bookstrom, Arthur A.; Slack, John F.; Zientek, Michael L.

2017-11-30

Cobalt (Co) is a potentially critical mineral. The vast majority of cobalt is a byproduct of copper and (or) nickel production. Cobalt is increasingly used in magnets and rechargeable batteries. More than 50 percent of primary cobalt production is from the Central African Copperbelt. The Central African Copperbelt is the only sedimentary rock-hosted stratiform copper district that contains significant cobalt. Its presence may indicate significant mafic-ultramafic rocks in the local basement. The balance of primary cobalt production is from magmatic nickel-copper and nickel laterite deposits. Cobalt is present in several carbonate-hosted lead-zinc and copper districts. It is also variably present in Besshi-type volcanogenic massive sulfide and siliciclastic sedimentary rock-hosted deposits in back arc and rift environments associated with mafic-ultramafic rocks. Metasedimentary cobalt-copper-gold deposits (such as Blackbird, Idaho), iron oxide-copper-gold deposits, and the five-element vein deposits (such as Cobalt, Ontario) contain different amounts of cobalt. None of these deposit types show direct links to mafic-ultramafic rocks; the deposits may result from crustal-scale hydrothermal systems capable of leaching and transporting cobalt from great depths. Hydrothermal deposits associated with ultramafic rocks, typified by the Bou Azzer district of Morocco, represent another type of primary cobalt deposit.In the United States, exploration for cobalt deposits may focus on magmatic nickel-copper deposits in the Archean and Proterozoic rocks of the Midwest and the east coast (Pennsylvania) and younger mafic rocks in southeastern and southern Alaska; also, possibly basement rocks in southeastern Missouri. Other potential exploration targets include—The Belt-Purcell basin of British Columbia (Canada), Idaho, Montana, and Washington for different styles of sedimentary rock-hosted cobalt deposits;Besshi-type VMS deposits, such as the Greens Creek (Alaska) deposit and

Energy deposition in a thin copper target downstream and off-axis of a proton-radiography target

International Nuclear Information System (INIS)

Greene, G.A.; Finfrock, C.C.; Snead, C.L.; Hanson, A.L.; Murray, M.M.

2002-01-01

A series of proton energy-deposition experiments was conducted to measure the energy deposited in a copper target located downstream and off-axis of a high-energy proton-radiography target. The proton/target interactions involved low-intensity bunches of protons at 24 GeV/c onto a spherical target consisting of concentric shells of tungsten and copper. The energy-deposition target was placed at five locations downstream of the proton-radiography target, off-axis of the primary beam transport, and was either unshielded or shielded by 5 or 10 cm of lead. Maximum temperature rises measured in the energy-deposition target due to single bunches of 5x10 10 protons on the proton-radiography target were approximately 20 mK per bunch. The data indicated that the scattered radiation was concentrated close to the primary transport axis of the beam line. The energy deposited in the energy-deposition target was reduced by moving the target radially away from the primary transport axis. Placing lead shielding in front of the target further reduced the energy deposition. The measured temperature rises of the energy-deposition target were empirically correlated with the distance from the source, the number of protons incident on the proton-radiography target, the thickness of the lead shielding, and the angle of the energy-deposition target off-axis of the beam line from the proton-radiography target. The correlation of the experimental data that was developed provides a starting point for the evaluation of the shielding requirements for devices downstream of proton-radiography targets such as superconducting magnets

Characterization of hafnium oxide resistive memory layers deposited on copper by atomic layer deposition

Energy Technology Data Exchange (ETDEWEB)

Briggs, B.D.; Bishop, S.M. [SUNY College of Nanoscale Science and Engineering, 255 Fuller Road, Albany, NY 12203 (United States); Leedy, K.D. [Air Force Research Laboratory, 2241 Avionics Circle, Wright Patterson Air Force Base, Dayton, OH 45433 (United States); Cady, N.C., E-mail: ncady@albany.edu [SUNY College of Nanoscale Science and Engineering, 255 Fuller Road, Albany, NY 12203 (United States)

2014-07-01

Hafnium oxide-based resistive memory devices have been fabricated on copper bottom electrodes. The HfO{sub x} active layers in these devices were deposited by atomic layer deposition (ALD) at 250 °C with tetrakis(dimethylamido)hafnium(IV) as the metal precursor and an O{sub 2} plasma as the reactant. Depth profiles of the HfO{sub x} by X-ray photoelectron spectroscopy and secondary ion mass spectroscopy revealed a copper concentration on the order of five atomic percent throughout the HfO{sub x} film. In addition to the Cu doped HfO{sub x}, a thin layer (20 nm) of Cu{sub x}O is present at the surface. This surface layer is believed to have formed during the ALD process, and greatly complicates the analysis of the switching mechanism. The resistive memory structures fabricated from the ALD HfO{sub x} exhibited non-polar resistive switching, independent of the top metal electrode (Ni, Pt, Al, Au). Resistive switching current voltage (I–V) curves were analyzed using Schottky emission and ionic hopping models to gain insight into the physical mechanisms underpinning the device behavior. During the forming process it was determined that, at voltages in excess of 2.5 V, an ionic hopping model is in good agreement with the I–V data. The extracted ion hopping distance ∼ 4 Å was within the range of interatomic spacing of HfO{sub 2} during the forming process consistent with ionic motion of Cu{sup 2+} ions. Lastly the on state I–V data was dominated at larger voltages by Schottky emission with an estimated barrier height of ∼ 0.5 eV and a refractive index of 2.59. The consequence of the Schottky emission analysis indicates the on state resistance to be a product of a Pt/Cu{sub 2}O/Cu filament(s)/Cu{sub 2}O/Cu structure. - Highlights: • HfO{sub 2} was grown via atomic layer deposition at 250 and 100 °C on Cu substrates. • A Cu{sub 2}O surface layer and Cu doping were observed in post-deposition of HfO{sub 2}. • Resistive memory devices were fabricated and

Cr13Ni5Si2-Based Composite Coating on Copper Deposited Using Pulse Laser Induction Cladding

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Ke Wang

2017-02-01

Full Text Available A Cr13Ni5Si2-based composite coating was successfully deposited on copper by pulse laser induction hybrid cladding (PLIC, and its high-temperature wear behavior was investigated. Temperature evolutions associated with crack behaviors in PLIC were analyzed and compared with pulse laser cladding (PLC using the finite element method. The microstructure and present phases were analyzed using scanning electron microscopy and X-ray diffraction. Compared with continuous laser induction cladding, the higher peak power offered by PLIC ensures metallurgical bonding between highly reflective copper substrate and coating. Compared with a wear test at room temperature, at 500 °C the wear volume of the Cr13Ni5Si2-based composite coating increased by 21%, and increased by 225% for a NiCr/Cr3C2 coating deposited by plasma spray. This novel technology has good prospects for application with respect to the extended service life of copper mold plates for slab continuous casting.

Cr13Ni5Si2-Based Composite Coating on Copper Deposited Using Pulse Laser Induction Cladding.

Science.gov (United States)

Wang, Ke; Wang, Hailin; Zhu, Guangzhi; Zhu, Xiao

2017-02-10

A Cr13Ni5Si2-based composite coating was successfully deposited on copper by pulse laser induction hybrid cladding (PLIC), and its high-temperature wear behavior was investigated. Temperature evolutions associated with crack behaviors in PLIC were analyzed and compared with pulse laser cladding (PLC) using the finite element method. The microstructure and present phases were analyzed using scanning electron microscopy and X-ray diffraction. Compared with continuous laser induction cladding, the higher peak power offered by PLIC ensures metallurgical bonding between highly reflective copper substrate and coating. Compared with a wear test at room temperature, at 500 °C the wear volume of the Cr13Ni5Si2-based composite coating increased by 21%, and increased by 225% for a NiCr/Cr3C2 coating deposited by plasma spray. This novel technology has good prospects for application with respect to the extended service life of copper mold plates for slab continuous casting.

Spectral characteristics of propylitic alteration minerals as a vectoring tool for porphyry copper deposits

OpenAIRE

Neal, LC; Wilkinson, JJ; Mason, PJ; Chang, Z

2018-01-01

publisher: Elsevier articletitle: Spectral characteristics of propylitic alteration minerals as a vectoring tool for porphyry copper deposits journaltitle: Journal of Geochemical Exploration articlelink: http://dx.doi.org/10.1016/j.gexplo.2017.10.019 content_type: article copyright: © 2017 Elsevier B.V. All rights reserved.

Corrosion of aluminium in copper-aluminium couples under a marine environment: Influence of polyaniline deposited onto copper

International Nuclear Information System (INIS)

Vera, Rosa; Verdugo, Patricia; Orellana, Marco; Munoz, Eduardo

2010-01-01

Research highlights: → The presence of Polyaniline in the Al-Cu system produces a decrease in the oxygen reduction reaction. → In the marine enviroment, aluminium in Al-Cu couples, suffers pitting and exfoliation. → The aluminium deterioration increases with chloride and enviromental sulphur dioxide presence, mainly when it is united to bare copper. - Abstract: In this study, we examined how aluminium corrosion in Al-Cu/PANI galvanic couples in a marine environment is influenced by deposition of polyaniline (PANI) on copper. Polarization curves and immersion assays in 0.1 M NaCl were performed. The morphologies of etched Al and corrosion products were observed by SEM, and the Al ions in solution were quantified by atomic absorption spectroscopy. A reduction in aluminium damage due to galvanic corrosion was observed as a result of decreased effective area for the oxygen reduction reaction on Cu/PANI electrode. Furthermore, an electrochemical reduction of PANI from leucoemeraldine to emeraldine base is proposed.

Precursors for formation of copper selenide, indium selenide, copper indium diselenide, and/or copper indium gallium diselenide films

Science.gov (United States)

Curtis, Calvin J; Miedaner, Alexander; Van Hest, Maikel; Ginley, David S

2014-11-04

Liquid-based precursors for formation of Copper Selenide, Indium Selenide, Copper Indium Diselenide, and/or copper Indium Galium Diselenide include copper-organoselenides, particulate copper selenide suspensions, copper selenide ethylene diamine in liquid solvent, nanoparticulate indium selenide suspensions, and indium selenide ethylene diamine coordination compounds in solvent. These liquid-based precursors can be deposited in liquid form onto substrates and treated by rapid thermal processing to form crystalline copper selenide and indium selenide films.

Atomic-layer-deposited WNxCy thin films as diffusion barrier for copper metallization

International Nuclear Information System (INIS)

Kim, Soo-Hyun; Oh, Su Suk; Kim, Ki-Bum; Kang, Dae-Hwan; Li, Wei-Min; Haukka, Suvi; Tuominen, Marko

2003-01-01

The properties of WN x C y films deposited by atomic layer deposition (ALD) using WF 6 , NH 3 , and triethyl boron as source gases were characterized as a diffusion barrier for copper metallization. It is noted that the as-deposited film shows an extremely low resistivity of about 350 μΩ cm with a film density of 15.37 g/cm 3 . The film composition measured from Rutherford backscattering spectrometry shows W, C, and N of ∼48, 32, and 20 at. %, respectively. Transmission electron microscopy analyses show that the as-deposited film is composed of face-centered-cubic phase with a lattice parameter similar to both β-WC 1-x and β-W 2 N with an equiaxed microstructure. The barrier property of this ALD-WN x C y film at a nominal thickness of 12 nm deposited between Cu and Si fails only after annealing at 700 deg. C for 30 min

Characterization of fluid inclusions and sulfur isotopes in the Iju porphyry copper deposit, North West of Shahr-e-Babak

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Malihe Golestani

2017-07-01

Full Text Available Introduction The Iju porphyry copper deposit is located in the southern part of the Urumieh-Dokhtar magmatic arc (Dehaj-Sarduieh belt within the Kerman copper belt (Dimitrijevic, 1973. The Porphyry Copper mineralization in the Iranian plate occurs dominantly along the Urumieh-Dokhtar arc, which has resulted from the subduction of the Arabian plate beneath the central Iran and the closure of the Neo-Tethys Ocean during the Alpine orogeny (Hassanzadeh, 1993. The Iju porphyry copper deposit with 25 million tons of ore reserves is one of the main copper deposits within the Kerman copper belt. The mining area is composed of upper Miocene volcanic and subvolcanic rocks (mineralized and barren subvolcanic rocks and quaternary deposits. Two hydrothermal alteration zones of quartz-sericite-pyrite and propylitic zones can be identified in the Iju area. The copper mineralization in the Iju deposit occurs as disseminated, stockwork and hydrothermal breccia. In the hypogene zone, the mineral paragenesis include chalcopyrite, pyrite, with minor occurrences of bornite and magnetite. This paper reports geological, mineralogical, fluid inclusion and S isotope data from the Iju deposit in order to investigate ore-bearing fluids’ characteristics and the mechanisms of ore deposition. Materials and methods Fifteen samples of syngenetic quartz+pyrite bearing veinlets within the quartz-sericite-pyrite zone were selected from different depths across the seven boreholes. Quartz was used for double-polished thin sections and pyrite was used for sulfur isotope analysis. Fluid inclusion studies were performed using the Linkam cooling and heating stage, the THMSG 600 model. The syngenetic pyrite with thermometry quartz sample was used for the sulfur isotope experiments. Stable isotope analysis was performed at the Hatch Stable Isotope Laboratory in the University of Ottawa, Canada. Results The fluid inclusions of the Iju deposit represent a wide range in the

Bath parameter dependence of chemically deposited Copper Selenide thin film

International Nuclear Information System (INIS)

Al-Mamun; Islam, A.B.M.O.

2004-09-01

In this article, a low cost chemical bath deposition (CBD) technique has been used for the preparation Of Cu 2-x Se thin films on to glass substrate. Different thin fms (0.2-0.6/μm) were prepared by adjusting the bath parameter like concentration of ammonia, deposition time, temperature of the solution, and the ratios of the mixing composition between copper and selenium in the reaction bath. From these studies, it reveals that at low concentration of ammonia or TEA, the terminal thicknesses of the films are less, which gradually increases with the increase of concentrations and then drop down at still higher concentrations. It has been found that completing the Cu 2+ ions with EA first, and then addition of ammonia yields better results than the reverse process. The film thickness increases with the decrease of value x of Cu 2-x Se. (author)

The copper deposits of Michigan

Science.gov (United States)

Butler, B.S.; Burbank, W.S.

1929-01-01

The copper district of Keweenaw Point, in the northern peninsula of Michigan, is the second largest producer of copper in the world.  The output of the district since 1845 has been more than 7,500,000,000 pounds and showed a rather steady and consistent increase from the beginning of production to the end of the World War in 1918, since which there has been a marked decrease.

Sedimentology and ichnology of Neogene Coastal Swamp deposits in the Niger Delta Basin, Nigeria

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Ezeh Sunny C.

2016-09-01

Full Text Available Often analyses of depositional environments from sparse data result in poor interpretation, especially in multipartite depositional settings such as the Niger Delta. For instance, differentiating channel sandstones, heteroliths and mudstones within proximal environments from those of distal facies is difficult if interpretations rely solely on well log signatures. Therefore, in order to achieve an effective and efficient interpretation of the depositional conditions of a given unit, integrated tools must be applied such as matching core descriptions with wireline log signature. In the present paper cores of three wells from the Coastal Swamp depositional belt of the Niger Delta are examined in order to achieve full understanding of the depositional environments. The well sections comprise cross-bedded sandstones, heteroliths (coastal and lower shoreface and mudstones that were laid down in wave, river and tidal processes. Interpretations were made from each data set comprising gamma ray logs, described sedimentological cores showing sedimentary features and ichnological characteristics; these were integrated to define the depositional settings. Some portions from one of the well sections reveal a blocky gamma ray well log signature instead of a coarsening-upward trend that characterises a shoreface setting while in other wells the signatures for heteroliths at some sections are bell blocky in shaped rather than serrated. Besides, heteroliths and mudstones within the proximal facies and those of distal facies were difficult to distinguish solely on well log signatures. However, interpretation based on sedimentology and ichnology of cores from these facies was used to correct these inconsistencies. It follows that depositional environment interpretation (especially in multifarious depositional environments such as the Niger Delta should ideally be made together with other raw data for accuracy and those based solely on well log signatures should

Rocking disc electro-deposition of copper films on Mo/MoSe{sub 2} substrates

Energy Technology Data Exchange (ETDEWEB)

Cummings, Charles Y.; Frith, Paul E. [Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY (United Kingdom); Zoppi, Guillaume; Forbes, Ian [Northumbria Photovoltaics Applications Centre, Northumbria University, NE1 8ST (United Kingdom); Rogers, Keith D. [Cranfield Health, Cranfield University, Shrivenham Campus, Swindon, SN6 8LA (United Kingdom); Lane, David W. [Department of Applied Science, Security and Resilience, Cranfield University, Shrivenham, Swindon, SN6 8LA (United Kingdom); Marken, Frank, E-mail: F.Marken@bath.ac.uk [Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY (United Kingdom)

2011-08-31

A novel electro-deposition method based on a rocking disc system with {pi}/3 amplitude and variable frequency is introduced. Uniform copper films were deposited from a 0.1 M CuSO{sub 4}/3.0 M NaOH/0.2 M sorbitol bath directly onto 12.1 cm{sup 2} Mo/MoSe{sub 2} substrates with X-ray diffraction showing a thickness variation of {+-}5% over this area. Investigation of the mass transport conditions suggests (i) uniform diffusion over the sample, (ii) a rate of mass transport proportional to the square root of the rocking rate, and (iii) turbulent conditions, which are able to dislodge gas bubbles during electro-deposition.

Effect of copper concentration on the physical properties of copper doped NiO thin films deposited by spray pyrolysis

Energy Technology Data Exchange (ETDEWEB)

Mani Menaka, S., E-mail: manimenaka.phy@gmail.com [PG and Research Department of Physics, Government Arts College, Coimbatore, 641018, Tamilnadu (India); Umadevi, G. [PG and Research Department of Physics, Government Arts College, Coimbatore, 641018, Tamilnadu (India); Manickam, M. [SRMV College of Arts and Science, Coimbatore, 641020, Tamilnadu (India)

2017-04-15

The spray pyrolysis (SP) technique is an important and powerful method for the preparation of nickel oxide (NiO) and copper-doped nickel oxide thin films. The best films were obtained when the substrate temperature, T{sub s} = 450 °C on glass substrates. Copper (Cu) concentrations in the films were varied from 0 to 8%. The effect of Cu concentration on the structural, morphological, spectral, optical, and electrical properties of the thin films were studied by X-ray diffraction (XRD), Scanning electron microscopy (SEM), Fourier transformed infrared spectroscopy (FTIR), UV–vis–NIR spectrophotometer, Hot probe and Hall system. The X-ray diffraction result shows the polycrystalline cubic structure of sprayed films with (200) preferred orientation. The variations of the structural parameters such as lattice parameters and grain sizes were investigated. The SEM image displays the surface morphology of the NiO and Cu:NiO thin films. The FTIR of the as-deposited films were associated with chemical identification. The optical transmittance and absorbance spectra of the films were measured by UV–vis–NIR spectrophotometer. The absorption coefficient and band gaps of the films were calculated using the optical method. All the NiO and Cu:NiO films were p-type. The resistivity of the above films decreases with the increase in copper concentration and so the conductivity of the films depend on the precursor concentration. - Highlights: • Pure and Cu:NiO films were deposited by Spray pyrolysis technique. • The XRD result shows the polycrystalline nature of pure and Cu:NiO films. • The formation of pure and Cu:NiO were confirmed by FTIR analysis. • Band gap values of pure and Cu:NiO decreases. • All the pure and Cu:NiO films were p-type.

Effect of copper concentration on the physical properties of copper doped NiO thin films deposited by spray pyrolysis

International Nuclear Information System (INIS)

Mani Menaka, S.; Umadevi, G.; Manickam, M.

2017-01-01

The spray pyrolysis (SP) technique is an important and powerful method for the preparation of nickel oxide (NiO) and copper-doped nickel oxide thin films. The best films were obtained when the substrate temperature, T_s = 450 °C on glass substrates. Copper (Cu) concentrations in the films were varied from 0 to 8%. The effect of Cu concentration on the structural, morphological, spectral, optical, and electrical properties of the thin films were studied by X-ray diffraction (XRD), Scanning electron microscopy (SEM), Fourier transformed infrared spectroscopy (FTIR), UV–vis–NIR spectrophotometer, Hot probe and Hall system. The X-ray diffraction result shows the polycrystalline cubic structure of sprayed films with (200) preferred orientation. The variations of the structural parameters such as lattice parameters and grain sizes were investigated. The SEM image displays the surface morphology of the NiO and Cu:NiO thin films. The FTIR of the as-deposited films were associated with chemical identification. The optical transmittance and absorbance spectra of the films were measured by UV–vis–NIR spectrophotometer. The absorption coefficient and band gaps of the films were calculated using the optical method. All the NiO and Cu:NiO films were p-type. The resistivity of the above films decreases with the increase in copper concentration and so the conductivity of the films depend on the precursor concentration. - Highlights: • Pure and Cu:NiO films were deposited by Spray pyrolysis technique. • The XRD result shows the polycrystalline nature of pure and Cu:NiO films. • The formation of pure and Cu:NiO were confirmed by FTIR analysis. • Band gap values of pure and Cu:NiO decreases. • All the pure and Cu:NiO films were p-type.

Mineralogy and fluid inclusion studies in kalchoye Copper- gold deposit, East of Esfahan

Directory of Open Access Journals (Sweden)

Rezvan Mehvary

2009-09-01

Full Text Available Kalchoye Copper-gold deposit is located about 110 kilometers east of Esfahan province and within the Eocene volcano sedimentary rocks. Sandy tuff and andesite lava are important members of this complex.The form of mineralization in area is vein and veinlet and quartz as the main gangue phase. The main ore minerals are chalcopyrite, chalcocite, galena and weathered minerals such as goethite, iron oxides, malachite and azurite. Studies in area indicate that ore mineralization Kalchoye is low sulfide, quartz type of hydrothermal ore deposits and results of thermometry studies on quartz minerals low- medium fluid with low potential mineralization is responsible for mineralization in this area.

Investigation of defects in ultra-thin Al{sub 2}O{sub 3} films deposited on pure copper by the atomic layer deposition technique

Energy Technology Data Exchange (ETDEWEB)

Chang, M.L.; Wang, L.C. [Department of Materials Science and Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan (China); Lin, H.C., E-mail: hclinntu@ntu.edu.tw [Department of Materials Science and Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan (China); Chen, M.J., E-mail: mjchen@ntu.edu.tw [Department of Materials Science and Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan (China); Lin, K.M. [Department of Materials Science and Engineering, Feng Chia University, No. 100, Wenhwa Road, Seatwen, Taichung 40724, Taiwan (China)

2015-12-30

Graphical abstract: Some residual OH ligands originating from incomplete reaction between TMA and surface species of OH* during ALD process induce the defects in deposited Al{sub 2}O{sub 3} films. Three possible types of defects are suggested. The analytic results indicate the defects are Type-I and/or Type-II but do not directly expose the substrate, like pinholes (Type-III). - Highlights: • Oxidation trials were conducted to investigate the defects in ultra-thin Al{sub 2}O{sub 3} films deposited ALD technique on pure copper. • The residual OH ligands in the deposited Al{sub 2}O{sub 3} films induce looser micro-structure which has worse oxidation resistance. • Superficial contamination particles on substrate surface are confirmed to be one of nucleation sites of the defects. - Abstract: Al{sub 2}O{sub 3} films with various thicknesses were deposited by the atomic layer deposition (ALD) technique on pure copper at temperatures of 100–200 °C. Oxidation trials were conducted in air at 200 °C to investigate the defects in these films. The analytic results show that the defects have a looser micro-structure compared to their surroundings, but do not directly expose the substrate, like pinholes. The film's crystallinity, mechanical properties and oxidation resistance could also be affected by these defects. Superficial contamination particles on the substrate surface are confirmed to be nucleation sites of the defects. A model for the mechanism of defect formation is proposed in this study.

Deposit model for heavy-mineral sands in coastal environments: Chapter L in Mineral deposit models for resource assessment

Science.gov (United States)

Van Gosen, Bradley S.; Fey, David L.; Shah, Anjana K.; Verplanck, Philip L.; Hoefen, Todd M.

2014-01-01

This report provides a descriptive model of heavy-mineral sands, which are sedimentary deposits of dense minerals that accumulate with sand, silt, and clay in coastal environments, locally forming economic concentrations of the heavy minerals. This deposit type is the main source of titanium feedstock for the titanium dioxide (TiO2) pigments industry, through recovery of the minerals ilmenite (Fe2+TiO3), rutile (TiO2), and leucoxene (an alteration product of ilmenite). Heavy-mineral sands are also the principal source of zircon (ZrSiO4) and its zirconium oxide; zircon is often recovered as a coproduct. Other heavy minerals produced as coproducts from some deposits are sillimanite/kyanite, staurolite, monazite, and garnet. Monazite [(Ce,La,Nd,Th)PO4] is a source of rare earth elements as well as thorium, which is used in thorium-based nuclear power under development in India and elsewhere.

Multidimensional study of the trace elements in the American south western prophyry copper type deposits: mineralogy of uranium

International Nuclear Information System (INIS)

Cesbron, Fabien; Drin, Nicolas.

1981-09-01

The use of the spark source masse spectrometry and data treatment methods (principal component analysis and discriminent analysis) allow to describe the trace elements comportments in the porphyry copper type deposits of Arizona (USA) and Sonora (Mexico). The chemical elements are studied in relationship with the alteration zones of these deposits. A electronic microprobe study specifies the uranium bearing minerals [fr

Engineering kinetic barriers in copper metallization

International Nuclear Information System (INIS)

Huang Hanchen; Wei, H.L.; Woo, C.H.; Zhang, X.X.

2002-01-01

In metallization processes of integrated circuits, it is desirable to deposit the metal lines (aluminum or copper) fast and at low temperatures. However, the lines (films) usually consist of undesirable columns and voids, because of the absence of sufficient diffusion--a direct result of large kinetic barriers. Following the proposal and realization of the three-dimensional Ehrlich-Schwoebel (3D ES) barrier, we present here a method to engineer this kinetic barrier so as to improve quality of deposited copper films. We deposit copper films by magnetron sputtering, characterize the film structure and texture by using the scanning electron microscope and the x-ray diffraction, respectively. Taking indium as surfactant during copper deposition, we have achieved much better density and bottom coverage of copper filled trenches. The characterizations show that the improvement is the result of the 3D ES barrier reduction caused by indium addition. Engineering the 3D ES barrier therefore leads to improved film quality

Spatial control of direct chemical vapor deposition of graphene on silicon dioxide by directional copper dewetting

NARCIS (Netherlands)

van den Beld, Wesley Theodorus Eduardus; van den Berg, Albert; Eijkel, Jan C.T.

2016-01-01

In this paper we present a method for the spatial control of direct graphene synthesis onto silicon dioxide by controlled dewetting. The dewetting process is controlled through a combination of using a grooved substrate and conducting copper deposition at an angle. The substrate is then treated

Growth and Characterisation of Pulsed-Laser Deposited Tin Thin Films on Cube-Textured Copper at Different Temperatures

Directory of Open Access Journals (Sweden)

Szwachta G.

2016-06-01

Full Text Available High-quality titanium nitride thin films have been grown on a cube-textured copper surface via pulsed laser deposition. The growth of TiN thin films has been very sensitive to pre-treatment procedure and substrate temperature. It is difficult to grow heteroexpitaxial TiN films directly on copper tape due to large differences in lattice constants, thermal expansion coefficients of the two materials as well as polycrystalline structure of substrate. The X-Ray diffraction measurement revealed presence of high peaks belonged to TiN(200 and TiN(111 thin films, depending on used etcher of copper surface. The electron diffraction patterns of TiN(200/Cu films confirmed the single-crystal nature of the films with cube-on-cube epitaxy. The high-resolution microscopy on our films revealed sharp interfaces between copper and titanium nitride with no presence of interfacial reaction.

Role of Mineral Deposits in Global Geochemical Cycles

Science.gov (United States)

Kesler, S.; Wilkinson, B.

2009-12-01

Mineral deposits represent the most extreme degree of natural concentration for most elements and their formation and destruction are important parts of global geochemical cycles. Quantitative estimates of the role that mineral deposits play in these geochemical cycles has been limited, however, by the lack of information on actual amounts of elements that are concentrated in these deposits, and their rates of formation and destruction at geologic time scales. Recent use of a “tectonic diffusion” model for porphyry copper deposits, the most important source of world copper, in conjunction with estimates of their copper content (Kesler and Wilkinson, 2008), allows an assessment of the role of copper deposits in Earth’s global copper cycles. These results indicate that ~4.5*10^8 Gg of Cu have been concentrated in porphyry copper deposits through Phanerozoic time, that deposits containing ~2.8*10^8 Gg of Cu have been removed by uplift and erosion over the same time period, and that deposits containing ~1.7*10^8 Gg remain in Earth’s crust. If styles of formation and destruction of other copper-bearing mineral deposits are similar, then all crustal deposits contain ~3*10^8 Gg of copper. This constitutes about 0.03% of the copper that resides in crustal rocks and provides a first-ever estimate of the rate at which natural geochemical cycles produce the extreme concentrations that constitute mineral deposits. Another ~8*10^8 Gg of copper have been destroyed during the uplift and erosion of mineral deposits over Phanerozoic time, a flux amounting to an annual contribution of about 1.5 Gg of copper to the near-surface environment. This amount is similar in magnitude to copper released by volcanic outgassing, but only ~2.5% of the 56 Gg of copper estimated to be released annually by weathering of average crustal rocks (Rauch and Graedel, 2007). The amount of copper removed from mineral deposits by mining, 1.1*10^4 Gg/year, is much larger than any natural

Wet and Dry Atmospheric Depositions of Inorganic Nitrogen during Plant Growing Season in the Coastal Zone of Yellow River Delta

Directory of Open Access Journals (Sweden)

Junbao Yu

2014-01-01

Full Text Available The ecological problems caused by dry and wet deposition of atmospheric nitrogen have been widespread concern in the world. In this study, wet and dry atmospheric depositions were monitored in plant growing season in the coastal zone of the Yellow River Delta (YRD using automatic sampling equipment. The results showed that SO42- and Na+ were the predominant anion and cation, respectively, in both wet and dry atmospheric depositions. The total atmospheric nitrogen deposition was ~2264.24 mg m−2, in which dry atmospheric nitrogen deposition was about 32.02%. The highest values of dry and wet atmospheric nitrogen deposition appeared in May and August, respectively. In the studied area, NO3-–N was the main nitrogen form in dry deposition, while the predominant nitrogen in wet atmospheric deposition was NH4+–N with ~56.51% of total wet atmospheric nitrogen deposition. The average monthly attribution rate of atmospheric deposition of NO3-–N and NH4+–N was ~31.38% and ~20.50% for the contents of NO3-–N and NH4+–N in 0–10 cm soil layer, respectively, suggested that the atmospheric nitrogen was one of main sources for soil nitrogen in coastal zone of the YRD.

Wet and dry atmospheric depositions of inorganic nitrogen during plant growing season in the coastal zone of Yellow River Delta.

Science.gov (United States)

Yu, Junbao; Ning, Kai; Li, Yunzhao; Du, Siyao; Han, Guangxuan; Xing, Qinghui; Wu, Huifeng; Wang, Guangmei; Gao, Yongjun

2014-01-01

The ecological problems caused by dry and wet deposition of atmospheric nitrogen have been widespread concern in the world. In this study, wet and dry atmospheric depositions were monitored in plant growing season in the coastal zone of the Yellow River Delta (YRD) using automatic sampling equipment. The results showed that SO4 (2-) and Na(+) were the predominant anion and cation, respectively, in both wet and dry atmospheric depositions. The total atmospheric nitrogen deposition was ~2264.24 mg m(-2), in which dry atmospheric nitrogen deposition was about 32.02%. The highest values of dry and wet atmospheric nitrogen deposition appeared in May and August, respectively. In the studied area, NO3 (-)-N was the main nitrogen form in dry deposition, while the predominant nitrogen in wet atmospheric deposition was NH4 (+)-N with ~56.51% of total wet atmospheric nitrogen deposition. The average monthly attribution rate of atmospheric deposition of NO3 (-)-N and NH4 (+)-N was ~31.38% and ~20.50% for the contents of NO3 (-)-N and NH4 (+)-N in 0-10 cm soil layer, respectively, suggested that the atmospheric nitrogen was one of main sources for soil nitrogen in coastal zone of the YRD.

Late Holocene stratigraphy of coastal deposits between Auckland and Dunedin, New Zealand

International Nuclear Information System (INIS)

McFadgen, B.G.

1985-01-01

Three chronostratigraphic units based on accumulative deposits and their respective soils are proposed for late Holocene coastal deposits between Auckland and Dunedin, New Zealand: Tamatean Chronozone (c. 1,800 to 450 years BP), Ohuan Chronozone (c. 450 to 150 years BP), and Hoatan Chronozone (c. 150 years to present day). The chronozones represent depositional episodes each consisting of two phases: a high rate of deposition (unstable phase), followed by a low rate of deposition and soil formation (stable phase). Vegetation on soils formed during the stable phases is inferred principally from landsnails recovered from archaeological sites. Forest on Tamatean soil (600 to 450 years BP) advanced almost to the coast in the Manawatu, the southeast Wairarapa, and on the East Coast. Sediment thickness measured at sections along the eastern North Island coast show that rates of deposition during unstable phases have decreased during the last 650 years. The depositional episodes appear to be unrelated to sea level changes, tectonic activity, volcanic eruptions or cultural influence. Unstable phases appear to correlate with times of high temperatures, and stable phases with time of low temperatures; it is suggested that the episodes may be related to changes in the frequency of tropical and extratropical cyclones. Inferred climate during unstable phases is windy and dry, and during stable phases, less windy and moist

Fabrication of cuprous chloride films on copper substrate by chemical bath deposition

Energy Technology Data Exchange (ETDEWEB)

Lin, Yu-Ting; Ci, Ji-Wei; Tu, Wei-Chen [Department of Electronic Engineering, College of Electrical Engineering and Computer Science, Chung Yuan Christian University, Chung-Li 32023, Taiwan (China); Uen, Wu-Yih, E-mail: uenwuyih@ms37.hinet.net [Department of Electronic Engineering, College of Electrical Engineering and Computer Science, Chung Yuan Christian University, Chung-Li 32023, Taiwan (China); Lan, Shan-Ming [Department of Electronic Engineering, College of Electrical Engineering and Computer Science, Chung Yuan Christian University, Chung-Li 32023, Taiwan (China); Yang, Tsun-Neng; Shen, Chin-Chang; Wu, Chih-Hung [Institute of Nuclear Energy Research, P.O. Box 3-11, Lungtan 32500, Taiwan (China)

2015-09-30

Polycrystalline CuCl films were fabricated by chemical bath deposition (CBD) on a Cu substrate at a low solution temperature of 90 °C. Continuous CuCl films were prepared using the copper (II) chloride (CuCl{sub 2}) compound as the precursor for both the Cu{sup 2+} and Cl{sup −} sources, together with repeated HCl dip treatments. An HCl dip pretreatment of the substrate favored the nucleation of CuCl crystallites. Further, interrupting the film deposition and including an HCl dip treatment of the film growth surface facilitated the deposition of a full-coverage CuCl film. A dual beam (FIB/SEM) system with energy dispersive spectrometry facilities attached revealed a homogeneous CuCl layer with a flat-top surface and an average thickness of about 1 μm. Both the excitonic and biexcitonic emission lines were well-resolved in the 6.4 K photoluminescence spectra. In particular, the free exciton emission line was observable at room temperature, indicating the good quality of the CuCl films prepared by CBD. - Highlights: • Cuprous chloride (CuCl) was prepared on Cu substrate by chemical bath deposition. • HCl dip treatments facilitated the deposition of a full-coverage CuCl film. • A homogeneous elemental distribution was recognized for the deposited CuCl layer. • Excitonic and biexcitonic photoluminescence lines of CuCl films were well-resolved. • The free exciton emission line of CuCl films was observable at room temperature.

Switchable DNA wire: deposition-stripping of copper nanoclusters as an "ON-OFF" nanoswitch.

Science.gov (United States)

Zhu, Xiaoli; Liu, Siyu; Cao, Jiepei; Mao, Xiaoxia; Li, Genxi

2016-01-19

Today, a consensus that DNA working as a molecular wire shows promise in nanoscale electronics is reached. Considering that the "ON-OFF" switch is the basis of a logic circuit, the switch of DNA-mediated charge transport (DNA CT) should be conquered. Here, on the basis of chemical or electrochemical deposition and stripping of DNA-templated copper nanoclusters (CuNCs), we develop an "ON-OFF" nanoswitch for DNA CT. While CuNCs are deposited, the DNA CT is blocked, which can be also recovered after stripping the CuNCs. A switch cycle can be completed in a few seconds and can be repeated for many times. Moreover, by regulating the amount of reagents, deposition/stripping time, applied potential, etc., the switch is adjustable to make the wire at either an "ON-OFF" state or an intermediate state. We believe that this concept and the successful implementation will promote the practical application of DNA wire one step further.

Fluid inclusion characteristics and molybdenite Re-Os geochronology of the Qulong porphyry copper-molybdenum deposit, Tibet

Science.gov (United States)

Li, Yang; Selby, David; Feely, Martin; Costanzo, Alessandra; Li, Xian-Hua

2017-02-01

The Qulong porphyry copper and molybdenum deposit is located at the southwest margin of the Lhasa Terrane and in the eastern region of the Gangdese magmatic belt. It represents China's largest porphyry copper system, with ˜2200 million tonnes of ore comprising 0.5 % Cu and 0.03 % Mo. The mineralization is associated with Miocene granodiorite, monzogranite and quartz-diorite units, which intruded into Jurassic volcanic units in a post-collisional (Indian-Asian) tectonic setting. Field observations and core logging demonstrate the alteration and mineralization at Qulong are akin to typical porphyry copper systems in subduction settings, which comprise similar magmatic-hydrothermal, potassic, propylitic and phyllic alteration assemblages. Molybdenite Re-Os geochronology confirms the relative timeframe defined by field observations and core logging and indicates that the bulk copper and molybdenum at Qulong were deposited within 350,000 years: between 16.10 ± 0.06 [0.08] (without and with decay constant uncertainty) and 15.88 ± 0.06 [0.08] Ma. This duration for mineralization is in direct contrast to a long-lived intrusive episode associated with mineralization based on previous zircon U-Pb data. Our fluid inclusion study indicates that the ore-forming fluid was oxidized and contained Na, K, Ca, Fe, Cu, Mo, Cl and S. The magmatic-hydrothermal transition occurred at ˜425 °C under lithostatic pressure, while potassic, propylitic and phyllic alteration occurred at hydrostatic pressure with temperature progressively decreasing from 425 to 280 °C. The fluid inclusion data presented here suggests that there has been ˜2.3 km of erosion at Qulong after its formation, and this erosion may be related to regional uplift of the Lhasa Terrane.

Evolution of radioactive dose rates in fresh sediment deposits along coastal rivers draining Fukushima contamination plume.

Science.gov (United States)

Evrard, Olivier; Chartin, Caroline; Onda, Yuichi; Patin, Jeremy; Lepage, Hugo; Lefèvre, Irène; Ayrault, Sophie; Ottlé, Catherine; Bonté, Philippe

2013-10-29

Measurement of radioactive dose rates in fine sediment that has recently deposited on channel bed-sand provides a solution to address the lack of continuous river monitoring in Fukushima Prefecture after Fukushima Dai-ichi nuclear power plant (FDNPP) accident. We show that coastal rivers of Eastern Fukushima Prefecture were rapidly supplied with sediment contaminated by radionuclides originating from inland mountain ranges, and that this contaminated material was partly exported by typhoons to the coastal plains as soon as by November 2011. This export was amplified during snowmelt and typhoons in 2012. In 2013, contamination levels measured in sediment found in the upper parts of the catchments were almost systematically lower than the ones measured in nearby soils, whereas their contamination was higher in the coastal plains. We thereby suggest that storage of contaminated sediment in reservoirs and in coastal sections of the river channels now represents the most crucial issue.

Direct write of copper-graphene composite using micro-cold spray

Directory of Open Access Journals (Sweden)

Sameh Dardona

2016-08-01

Full Text Available Direct write of a new class of composite materials containing copper and graphene in the powder phase is described. The composite was synthesized using batch electroless plating of copper for various times onto Nano Graphene Platelets (NGP to control the amount of copper deposited within the loosely aggregated graphene powder. Copper deposition was confirmed by both Focused Ion Beam (FIB and Auger electron spectroscopic analysis. A micro-cold spray technique was used to deposit traces that are ∼230 μm wide and ∼5 μm thick of the formulated copper/graphene powder onto a glass substrate. The deposited traces were found to have good adhesion to the substrate with ∼65x the copper bulk resistivity.

Structural, optical and electrical properties of copper antimony sulfide thin films grown by a citrate-assisted single chemical bath deposition

Science.gov (United States)

Loranca-Ramos, F. E.; Diliegros-Godines, C. J.; Silva González, R.; Pal, Mou

2018-01-01

Copper antimony sulfide (CAS) has been proposed as low toxicity and earth abundant absorber materials for thin film photovoltaics due to their suitable optical band gap, high absorption coefficient and p-type electrical conductivity. The present work reports the formation of copper antimony sulfide by chemical bath deposition using sodium citrate as a complexing agent. We show that by tuning the annealing condition, one can obtain either chalcostibite or tetrahedrite phase. However, the main challenge was co-deposition of copper and antimony as ternary sulfides from a single chemical bath due to the distinct chemical behavior of these metals. The as-deposited films were subjected to several trials of thermal treatment using different temperatures and time to find the optimized annealing condition. The films were characterized by different techniques including Raman spectroscopy, X-ray diffraction (XRD), profilometer, scanning electron microscopy (SEM), UV-vis spectrophotometer, and Hall Effect measurements. The results show that the formation of chalcostibite and tetrahedrite phases is highly sensitive to annealing conditions. The electrical properties obtained for the chalcostibite films varied as the annealing temperature increases from 280 to 350 °C: hole concentration (n) = 1017-1018 cm-3, resistivity (ρ) = 1.74-2.14 Ωcm and carrier mobility (μ) = 4.7-9.26 cm2/Vseg. While for the tetrahedrite films, the electrical properties were n = 5 × 1019 cm-3, μ = 18.24 cm2/Vseg, and ρ = 5.8 × 10-3 Ωcm. A possible mechanism for the formation of ternary copper antimony sulfide has also been proposed.

Role of Sulfur in the Formation of Magmatic-Hydrothermal Copper-Gold Deposits

Science.gov (United States)

Seo, J.; Guillong, M.; Heinrich, C.

2009-05-01

Sulfur plays essential roles in hydrothermal ore-forming processes [1], which calls for precise and accurate quantitative sulfur determination in fluid inclusions. Feasibility tests for sulfur quantification by comparing data from both LA-Quadrupole (Q) - ICP-MS and LA-High Resolution (HR) - ICP-MS show that reliable sulfur quantification in fluid inclusions is possible [2], provided that a very careful baseline correction is applied. We investigate the metal transporting capabilities of sulfur by measuring sulfur together with copper and other elements in cogenetic brine and vapor inclusions ('boiling assemblages') in single healed crack hosted by quartz veins. Samples are from high-temperature magmatic-hydrothermal ore deposits and miarolitic cavities of barren granitoid. Clear compositional correlations of sulfur with copper and gold were found. A molar S/Cu ratio commonly close to 2 but never above 2, indicates sulfur-complexed metal transportation in the high-temperature hydrothermal vapor, and probably also in the Na-Fe-K-Cl-enriched brines. Vapor/brine partitioning trends of the S and Cu are shown to be related with the chemistry of the fluids (possibly by various sulfur speciations in varying pH, fO2) and causative magma source. In the boiling hydrothermal environments, higher vapor partitioning of Cu and S is observed at reduced and peraluminous Sn-W granite, whereas oxidized and perakaline porphyry-style deposits have a lower partitioning to the vapor although the total concentration of S, Cu, Au in both fluid phase is higher than in the Sn-W granite [3]. Vapor inclusion in the boiling assemblages from magmatic-hydrothermal ore deposits and granitic intrusions generally contain an excess of sulfur over ore metals such as Cu, Fe, and Mo. This allows efficient sulfide ore precipitation in high-temperature porphyry-type deposits, and complexation of gold by the remaining sulfide down to lower temperatures. The results confirm earlier interpretations [1] and

Ultra-deep oxidation and exotic copper formation at the late pliocene boyongan and bayugo porphyry copper-gold deposits, surigao, philippines: Geology, mineralogy, paleoaltimetry, and their implications for Geologic, physiographic, and tectonic controls

Science.gov (United States)

Braxton, D.P.; Cooke, D.R.; Ignacio, A.M.; Rye, R.O.; Waters, P.J.

2009-01-01

The Boyongan and Bayugo porphyry copper-gold deposits are part of an emerging belt of intrusion-centered gold-rich deposits in the Surigao district of northeast Mindanao, Philippines. Exhumation and weathering of these Late Pliocene-age deposits has led to the development of the world's deepest known porphyry oxidation profile at Boyongan (600 m), and yet only a modest (30-70 m) oxidation profile at adjacent Bayugo. Debris flows, volcanic rocks, and fluviolacustrine sediments accumulating in the actively extending Mainit graben subsequently covered the deposits and preserved the supergene profiles. At Boyongan and Bayugo, there is a vertical transition from shallower supergene copper oxide minerals (malachite + azurite + cuprite) to deeper sulfide-stable assemblages (chalcocite ?? hypogene sulfides). This transition provides a time-integrated proxy for the position of the water table at the base of the saturated zone during supergene oxidation. Contours of the elevation of the paleopotentiometric surface based on this min- eralogical transition show that the thickest portions of the unsaturated zone coincided with a silt-sand matrix diatreme breccia complex at Boyongan. Within the breccia complex, the thickness of the unsaturated zone approached 600 in, whereas outside the breccia complex (e.g., at Bayugo), the thickness averaged 50 m. Contours of the paleopotentiometric surface suggest that during weathering, groundwater flowed into the breccia complex from the north, south, and east, and exited along a high permeability zone to the west. The high relief (>550 m) on the elevation of the paleopotentiometric surface is consistent with an environment of high topographic relief, and the outflow zone to the west of the breccia complex probably reflects proximity to a steep scarp intersecting the western breccia complex margin. Stable isotope paleoaltimetry has enabled estimation of the elevation of the land surface, which further constrains the physiographic setting

The Effect of Deposit Temperature on the Catalytic SO2-to-SO3 Conversion in a Copper Flash Smelting Heat Recovery Boiler

Science.gov (United States)

Lehmusto, Juho; Vainio, Emil; Laurén, Tor; Lindgren, Mari

2018-02-01

The aim of the work was to study the catalytic role of copper flash smelter deposit in the SO2-to-SO3 conversion. In addition, the effect of process gas temperature at 548 K to 1173 K (275 °C to 900 °C) on the amount of SO3 formed was addressed both in the absence and presence of genuine copper flash smelter deposit. The SO3 conversion rate changed as a function of process gas temperature, peaking at 1023 K (750 °C). A dramatic increase in the SO2-to-SO3 conversion was observed when process dust was present, clearly indicating that process dust catalyzes the SO2-to-SO3 conversion. Based on these results, the catalytic ability of the deposit may lead to sulfuric acid dew point corrosion.

CdS-based p-i-n diodes using indium and copper doped CdS films by pulsed laser deposition

International Nuclear Information System (INIS)

Hernandez-Como, N; Berrellez-Reyes, F; Mizquez-Corona, R; Ramirez-Esquivel, O; Mejia, I; Quevedo-Lopez, M

2015-01-01

In this work we report a method to dope cadmium sulfide (CdS) thin films using pulsed laser deposition. Doping is achieved during film growth at substrate temperatures of 100 °C by sequential deposition of the CdS and the dopant material. Indium sulfide and copper disulfide targets were used as the dopant sources for n-type and p-type doping, respectively. Film resistivities as low as 0.2 and 1 Ω cm were achieved for indium and copper doped films, respectively. Hall effect measurements demonstrated the change in conductivity type from n-type to p-type when the copper dopants are incorporated into the film. The controlled incorporation of indium or copper, in the undoped CdS film, results in substitutional defects in the CdS, which increases the electron and hole concentration up to 4 × 10 18 cm −3 and 3 × 10 20 cm −3 , respectively. The results observed with CdS doping can be expanded to other chalcogenides material compounds by just selecting different targets. With the optimized doped films, CdS-based p-i-n diodes were fabricated yielding an ideality factor of 4, a saturation current density of 2 × 10 −6 A cm −2 and a rectification ratio of three orders of magnitude at ±3 V. (paper)

Influence of post-deposition annealing on structural, morphological and optical properties of copper (II) acetylacetonate thin films.

Science.gov (United States)

Abdel-Khalek, H; El-Samahi, M I; El-Mahalawy, Ahmed M

2018-05-21

In this study, the effect of thermal annealing under vacuum conditions on structural, morphological and optical properties of thermally evaporated copper (II) acetylacetonate, cu(acac) 2 , thin films were investigated. The copper (II) acetylacetonate thin films were deposited using thermal evaporation technique at vacuum pressure ~1 × 10 -5  mbar. The deposited films were thermally annealed at 323, 373, 423, and 473 K for 2 h in vacuum. The thermogravimetric analysis of cu(acac) 2 powder indicated a thermal stability of cu(acac) 2 up to 423 K. The effects of thermal annealing on the structural properties of cu(acac) 2 were evaluated employing X-ray diffraction method and the analysis showed a polycrystalline nature of the as-deposited and annealed films with a preferred orientation in [1¯01] direction. Fourier transformation infrared (FTIR) technique was used to negate the decomposition of copper (II) acetylacetonate during preparation or/and annealing up to 423 K. The surface morphology of the prepared films was characterized by means of field emission scanning electron microscopy (FESEM). A significant enhancement of the morphological properties of cu(acac) 2 thin films was obtained till the annealing temperature reaches 423 K. The variation of optical constants that estimated from spectrophotometric measurements of the prepared thin films was investigated as a function of annealing temperature. The annealing process presented significantly impacted the nonlinear optical properties such as third-order optical susceptibility χ (3) and nonlinear refractive index n 2 of cu(acac) 2 thin films. Copyright © 2018 Elsevier B.V. All rights reserved.

Occurrence model for magmatic sulfide-rich nickel-copper-(platinum-group element) deposits related to mafic and ultramafic dike-sill complexes: Chapter I in Mineral deposit models for resource assessment

Science.gov (United States)

Schulz, Klaus J.; Woodruff, Laurel G.; Nicholson, Suzanne W.; Seal, Robert R.; Piatak, Nadine M.; Chandler, Val W.; Mars, John L.

2014-01-01

Magmatic sulfide deposits containing nickel (Ni) and copper (Cu), with or without (±) platinum-group elements (PGE), account for approximately 60 percent of the world’s nickel production. Most of the remainder of the Ni production is derived from lateritic deposits, which form by weathering of ultramafic rocks in humid tropical conditions. Magmatic Ni-Cu±PGE sulfide deposits are spatially and genetically related to bodies of mafic and/or ultramafic rocks. The sulfide deposits form when the mantle-derived mafic and/or ultramafic magmas become sulfide-saturated and segregate immiscible sulfide liquid, commonly following interaction with continental crustal rocks.

The Role of Porosity in the Formation of Coastal Boulder Deposits - Hurricane Versus Tsunami

Science.gov (United States)

Spiske, M.; Boeroecz, Z.; Bahlburg, H.

2007-12-01

Coastal boulder deposits are a consequence of high-energy wave impacts, such as storms, hurricanes or tsunami. Distinguishing parameters between storm, hurricane and tsunami origin are distance of a deposit from the coast, boulder weight and inferred wave height. Formulas to calculate minimum wave heights of both storm and tsunami waves depend on accurate determination of boulder dimensions and lithology from the respective deposits. At present however, boulder porosity appears to be commonly neglected, leading to significant errors in determined bulk density, especially when boulders consist of reef or coral limestone. This limits precise calculations of wave heights and hampers a clear distinction between storm, hurricane and tsunami origin. Our study uses Archimedean and optical 3D-profilometry measurements for the determination of porosities and bulk densities of reef and coral limestone boulders from the islands of Aruba, Bonaire and Curaçao (ABC Islands, Netherlands Antilles). Due to the high porosities (up to 68 %) of the enclosed coral species, the weights of the reef rock boulders are as low as 20 % of previously calculated values. Hence minimum calculated heights both for tsunami and hurricane waves are smaller than previously proposed. We show that hurricane action appears to be the likely depositional mechanism for boulders on the ABC Islands, since 1) our calculations result in tsunami wave heights which do not permit the overtopping of coastal platforms on the ABC Islands, 2) boulder fields lie on the windward (eastern) sides of the islands, 3) recent hurricanes transported boulders up to 35 m3 and 4) the scarcity of tsunami events affecting the coasts of the ABC Islands compared to frequent impacts of tropical storms and hurricanes.

The Nature and Use of Copper Reserve and Resource Data

Science.gov (United States)

Cox, Dennis P.; Wright, Nancy A.; Coakley, George J.

1981-01-01

Copper reserve, resource, and production data can be combined to produce disaggregated resource estimates and trends and, when combined with demand forecasts, can be used to predict future exploration and development requirements. Reserve estimates are subject to uncertainties due mainly to incomplete exploration and rapidly changing economic conditions. United States' reserve estimates in the past have been low mainly because knowledge of the magnitude of very large porphyry-copper deposits has been incomplete. Present estimates are considerably more reliable because mining firms tend to drill out deposits fully before mining and to release their reserve estimates to the public. The sum of reserves and past production yields an estimate of the total ore, total metal contained in ore, and average grade of ore originally in each of the deposits known in the United States. For most deposits, estimates of total copper in ore are low relative to the total copper in mineralized rock, and many estimates are strongly affected by the economic behavior of mining firms. A better estimate of the real distribution of copper contained in deposits can be obtained by combining past production data with resource estimates. Copper resource data are disaggregated into categories that include resources in undeveloped deposits similar to those mined in the past, resources in mines closed because of unfavorable economic conditions, resources in deep deposits requiring high-cost mining methods, arid resources in deposits located in areas where environmental restrictions have contributed to delays in development. The largest resource is located in the five largest porphyry deposits. These deposits are now being mined but the resources are not included in the present mining plan. Resources in this last category will not contribute to supply until some future time when ores presently being mined are depleted. A high correlation exists between total copper contained in deposits and annual

Low temperature plasma-enhanced atomic layer deposition of thin vanadium nitride layers for copper diffusion barriers

Energy Technology Data Exchange (ETDEWEB)

Rampelberg, Geert; Devloo-Casier, Kilian; Deduytsche, Davy; Detavernier, Christophe [Department of Solid State Sciences, Ghent University, Krijgslaan 281/S1, B-9000 Ghent (Belgium); Schaekers, Marc [IMEC, Kapeldreef 75, B-3001 Leuven (Belgium); Blasco, Nicolas [Air Liquide Electronics US, L.P., 46401 Landing Parkway, Fremont, California 94538 (United States)

2013-03-18

Thin vanadium nitride (VN) layers were grown by atomic layer deposition using tetrakis(ethylmethylamino)vanadium and NH{sub 3} plasma at deposition temperatures between 70 Degree-Sign C and 150 Degree-Sign C on silicon substrates and polymer foil. X-ray photoelectron spectroscopy revealed a composition close to stoichiometric VN, while x-ray diffraction showed the {delta}-VN crystal structure. The resistivity was as low as 200 {mu}{Omega} cm for the as deposited films and further reduced to 143 {mu}{Omega} cm and 93 {mu}{Omega} cm by annealing in N{sub 2} and H{sub 2}/He/N{sub 2}, respectively. A 5 nm VN layer proved to be effective as a diffusion barrier for copper up to a temperature of 720 Degree-Sign C.

Switchable DNA wire: deposition-stripping of copper nanoclusters as an “ON-OFF” nanoswitch

Science.gov (United States)

Zhu, Xiaoli; Liu, Siyu; Cao, Jiepei; Mao, Xiaoxia; Li, Genxi

2016-01-01

Today, a consensus that DNA working as a molecular wire shows promise in nanoscale electronics is reached. Considering that the “ON-OFF” switch is the basis of a logic circuit, the switch of DNA-mediated charge transport (DNA CT) should be conquered. Here, on the basis of chemical or electrochemical deposition and stripping of DNA-templated copper nanoclusters (CuNCs), we develop an “ON-OFF” nanoswitch for DNA CT. While CuNCs are deposited, the DNA CT is blocked, which can be also recovered after stripping the CuNCs. A switch cycle can be completed in a few seconds and can be repeated for many times. Moreover, by regulating the amount of reagents, deposition/stripping time, applied potential, etc., the switch is adjustable to make the wire at either an “ON-OFF” state or an intermediate state. We believe that this concept and the successful implementation will promote the practical application of DNA wire one step further. PMID:26781761

Direct Metal Deposition of H13 Tool Steel on Copper Alloy Substrate: Parametric Investigation

Science.gov (United States)

Imran, M. Khalid; Masood, S. H.; Brandt, Milan

2015-12-01

Over the past decade, researchers have demonstrated interest in tribology and prototyping by the laser aided material deposition process. Laser aided direct metal deposition (DMD) enables the formation of a uniform clad by melting the powder to form desired component from metal powder materials. In this research H13 tool steel has been used to clad on a copper alloy substrate using DMD. The effects of laser parameters on the quality of DMD deposited clad have been investigated and acceptable processing parameters have been determined largely through trial-and-error approaches. The relationships between DMD process parameters and the product characteristics such as porosity, micro-cracks and microhardness have been analysed using scanning electron microscope (SEM), image analysis software (ImageJ) and microhardness tester. It has been found that DMD parameters such as laser power, powder mass flow rate, feed rate and focus size have an important role in clad quality and crack formation.

Ostreococcus tauri Luminescent Reporter Lines as Biosensors for Detecting Pollution From Copper-Mine Tailing Effluents in Coastal Environments

Directory of Open Access Journals (Sweden)

Carlos Henríquez-Castillo

2018-05-01

Full Text Available Phytoplankton cells are excellent biosensors for environmental monitoring and toxicity assessments in different natural systems. Green algae, in particular, appear to be more responsive to copper (Cu disturbances. This is interesting considering that Cu pollution in coastal environments has increased over the last century, with enormous repercussions to marine ecosystems. Unfortunately, no high-throughput method exists for the environmental monitoring of Cu toxicity in seawater. To assess potential uses as biosensors of Cu pollution, high-throughput screening was performed on five luminescence reporter lines constructed in the green algae Ostreococcus tauri RCC745. The reporter line expressing the iron storage ferritin protein fused to luciferase (Fer-Luc was the most sensitive, responding to Cu concentrations in the μM range. Fer-Luc was also the most sensitive reporter line for detecting toxicity in mining-derived polluted seawater predominantly contaminated by soluble Cu. Nevertheless, the Cyclin-Dependent-Kinase A (CDKA reporter was most suitable for detecting the toxicity of copper-mine tailing effluents containing other metals (e.g., iron. These results highlight that Ostreococcus biosensors can serve as a reliable, inexpensive, and automated, high-throughput laboratory approach for performing seawater analyses of coastal areas subjected to metal disturbances. When challenged with Cu, O. tauri not only evidenced a rapid, transcriptional response for the tested genes, but also showed changes in a broad range of genes, especially as related to the stress response. Overall, the obtained results reinforce that a single biosensor is insufficient when dealing with complex mixtures of toxic compounds in natural environments.

Radiation induced deposition of copper nanoparticles inside the nanochannels of poly(acrylic acid)-grafted poly(ethylene terephthalate) track-etched membranes

Science.gov (United States)

Korolkov, Ilya V.; Güven, Olgun; Mashentseva, Anastassiya A.; Atıcı, Ayse Bakar; Gorin, Yevgeniy G.; Zdorovets, Maxim V.; Taltenov, Abzal A.

2017-01-01

Poly(ethylene terephthalate) PET, track-etched membranes (TeMs) with 400 nm average pore size were UV-grafted with poly(acrylic acid) (PAA) after oxidation of inner surfaces by H2O2/UV system. Carboxylate groups of grafted PAA chains were easily complexed with Cu2+ ions in aqueous solutions. These ions were converted into metallic copper nanoparticles (NPs) by radiation-induced reduction of copper ions in aqueous-alcohol solution by gamma rays in the dose range of 46-250 kGy. Copper ions chelating with -COOH groups of PAA chains grafted on PET TeMs form polymer-metal ion complex that prevent the formation of agglomerates during reduction of copper ions to metallic nanoparticles. The detailed analysis by X-Ray diffraction technique (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX) confirmed the deposition of copper nanoparticles with the average size of 70 nm on the inner surface of nanochannels of PET TeMs. Samples were also investigated by FTIR, ESR spectroscopies to follow copper ion reduction.

Even low to medium nitrogen deposition impacts vegetation of dry, coastal dunes around the Baltic Sea

NARCIS (Netherlands)

Remke, E.; Brouwer, E.; Kooijman, A.; Blindow, I.; Esselink, H.; Roelofs, J.G.M.

2009-01-01

Coastal dunes around the Baltic Sea have received small amounts of atmospheric nitrogen and are rather pristine ecosystems in this respect. In 19 investigated dune sites the atmospheric wet nitrogen deposition is 3-8 kg N ha−1 yr−1. The nitrogen content of Cladonia portentosa appeared to be a

Experimental investigation on the energy deposition and morphology of the electrical explosion of copper wire in vacuum

International Nuclear Information System (INIS)

Shi, Zongqian; Shi, Yuanjie; Wang, Kun; Jia, Shenli

2016-01-01

This paper presents the experimental results of the electrical explosion of copper wires in vacuum using negative nanosecond-pulsed current with magnitude of 1–2 kA. The 20 μm-diameter copper wires with different lengths are exploded with three different current rates. A laser probe is applied to construct the shadowgraphy and interferometry diagnostics to investigate the distribution and morphology of the exploding product. The interference phase shift is reconstructed from the interferogram, by which the atomic density distribution is calculated. Experimental results show that there exist two voltage breakdown modes depending on the amount of the specific energy deposition. For the strong-shunting mode, shunting breakdown occurs, leading to the short-circuit-like current waveform. For the weak-shunting mode with less specific energy deposition, the plasma generated during the voltage breakdown is not enough to form a conductive plasma channel, resulting in overdamped declining current waveform. The influence of the wire length and current rate on the characteristics of the exploding wires is also analyzed.

Experimental investigation on the energy deposition and morphology of the electrical explosion of copper wire in vacuum

Energy Technology Data Exchange (ETDEWEB)

Shi, Zongqian; Shi, Yuanjie; Wang, Kun; Jia, Shenli [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Shanxi 710049 (China)

2016-03-15

This paper presents the experimental results of the electrical explosion of copper wires in vacuum using negative nanosecond-pulsed current with magnitude of 1–2 kA. The 20 μm-diameter copper wires with different lengths are exploded with three different current rates. A laser probe is applied to construct the shadowgraphy and interferometry diagnostics to investigate the distribution and morphology of the exploding product. The interference phase shift is reconstructed from the interferogram, by which the atomic density distribution is calculated. Experimental results show that there exist two voltage breakdown modes depending on the amount of the specific energy deposition. For the strong-shunting mode, shunting breakdown occurs, leading to the short-circuit-like current waveform. For the weak-shunting mode with less specific energy deposition, the plasma generated during the voltage breakdown is not enough to form a conductive plasma channel, resulting in overdamped declining current waveform. The influence of the wire length and current rate on the characteristics of the exploding wires is also analyzed.

Identifying Marine Copper-Binding Ligands in Seawater

Science.gov (United States)

Whitby, H.; Hollibaugh, J. T.; Maldonado, M. T.; Ouchi, S.; van den Berg, S. M.

2016-02-01

Complexation reactions are important because they affect the bioavailability of trace metals such as copper and iron. For example, organic complexation can determine whether copper is a limiting or a toxic micronutrient at natural levels. Copper competes with iron for complexing ligands, and when iron is limiting, copper can also substitute for iron in some metabolic pathways. The speciation of copper can be measured using complexing capacity titrations, which provide the concentration of individual ligand classes (L1, L2 etc.) and the complex stabilities (log K). Using methods recently developed in our laboratory, we show that the ligands within these classes can be measured independently of titrations, thus confirming the titration method and simultaneously identifying the ligands within each class. Thiols were identified as the L1 ligand class and humic compounds as the weaker L2 class in samples from coastal Georgia, USA, collected monthly from April to December. Log K values of the ligand complexes were consistent with values expected for thiols and humic substances. Recent results from culture studies and from samples collected along Line P, a coastal - oceanic transect in the HNLC region of the NE subarctic Pacific, will be presented in comparison to the estuarine results. This comparison will help to broaden our perspective on copper complexation and the ligands responsible, furthering our understanding of ligand sources and life cycles.

Assessment of copper, cadmium and zinc remobilization in Mediterranean marine coastal sediments

Science.gov (United States)

Sakellari, Aikaterini; Plavšić, Marta; Karavoltsos, Sotiris; Dassenakis, Manos; Scoullos, Michael

2011-01-01

The remobilization of copper, cadmium and zinc in sediments of three selected coastal microenvironments of the Aegean Sea (Eastern Mediterranean) is assessed. Various analytical methods and techniques were employed providing concentrations, profiles and forms of metals and organic matter in sediments and pore waters. At Loutropyrgos, a non-industrial site located, however, within an intensively industrialized enclosed gulf, an intense resupply of zinc in pore water from sediment was recorded, correlating with the highest value of weakly bound fraction of zinc determined at this area. The comparatively high zinc concentrations measured in the pore waters (394 nM), exceed considerably those in the overlying seawater (12.5 nM determined by DGT; 13.5 nM total), resulting in the formation of a strong concentration gradient at the sediment-water interface. Potential zinc flux at the sediment-water interface at Loutropyrgos (based on 0.4 mm DGT profile) was calculated equal to 0.8 mmol.m -2.d -1. The half lives of trace metals at Loutropyrgos site, based on the aforementioned DGT profiles, amount to 0.1 y (Zn), 2.8 y (Cd), 4.5 y (Cu), 2.2 y (Mn) and 0.4 y (Fe) pointing out to the reactivity of these metals at the sediment-water interface. The concentration of dissolved organic carbon (DOC) in pore waters of the three selected sites (2.7-5.2 mg/L) was up to four times higher compared to that of the corresponding overlying seawater. Similarly, the concentrations of carbohydrates in pore waters (0.20-0.91 mg/L monosaccharides; 0.71-1.6 mg/L polysaccharides) are an order of magnitude higher than those of seawater, forming a concentration gradient at the sediment-water interface. Total carbohydrates contribute between 34 and 48% of the organic carbon of the pore waters, being significantly higher than those of seawater from the corresponding areas, which were in the range of 15-21%. The complexing capacity as for copper ions (CCu) determined in pore water ranges widely, from 0

Post-test examination of a copper electrode from deposition hole 5 in the Prototype Repository

International Nuclear Information System (INIS)

Rosborg, Bo

2013-04-01

Three copper electrodes have been exposed for eight years in the outer section of the Prototype Repository at Aespoe. The electrodes were installed in the upper bentonite block of deposition hole 5 in May 2003. Most of the time the temperature of the electrodes has been somewhat below 35 deg C. The electrodes were retrieved for post-test examination in September 2011. This report presents results from electrochemical measurements and the post-test examination of one of the electrodes. The corrosion potential of the examined copper electrode was -40 mV SHE (2011-02-04) when part of the concrete plug to the outer section of the repository had been removed and made measurements possible. When the back-fill in the deposition tunnel had been removed it was 25 mV SHE (2011-09-12). Finally, before letting loose the copper electrode from the retrieved bentonite block, the corrosion potential was found to be 165 mV SHE (2011-11-15) being a sign of air ingress to the electrode/ bentonite interface. It was immediately obvious from the appearance of the copper electrode, when part of the surrounding bentonite had been removed, that both Cu(I) and Cu(II) corrosion products existed on the electrode surface. X-ray diffraction measurements also verified the presence of cuprite, Cu 2 O, and malachite, Cu 2 (OH) 2 CO 3 , on the electrode; however, paratacamite, Cu 2 (OH) 3 Cl, was not found. The performed Fourier transform infrared and Raman spectroscopy confirmed these observations. The corrosion product film, of which cuprite is the main part, was quite uneven and porous. No unmistakable signs of pitting have been found. The appearance of the copper electrode reminded of the coupons from the retrieved LOT test parcels, but was different from the appearance of the surface on the full-size canisters. For the latter blue-green Cu(II) corrosion products have not or only rarely been observed from visual examination immediately after removing the surrounding bentonite. Differences that

Post-test examination of a copper electrode from deposition hole 5 in the Prototype Repository

Energy Technology Data Exchange (ETDEWEB)

Rosborg, Bo [Rosborg Consulting, Nykoeping (Sweden)

2013-04-15

Three copper electrodes have been exposed for eight years in the outer section of the Prototype Repository at Aespoe. The electrodes were installed in the upper bentonite block of deposition hole 5 in May 2003. Most of the time the temperature of the electrodes has been somewhat below 35 deg C. The electrodes were retrieved for post-test examination in September 2011. This report presents results from electrochemical measurements and the post-test examination of one of the electrodes. The corrosion potential of the examined copper electrode was -40 mV SHE (2011-02-04) when part of the concrete plug to the outer section of the repository had been removed and made measurements possible. When the back-fill in the deposition tunnel had been removed it was 25 mV SHE (2011-09-12). Finally, before letting loose the copper electrode from the retrieved bentonite block, the corrosion potential was found to be 165 mV SHE (2011-11-15) being a sign of air ingress to the electrode/ bentonite interface. It was immediately obvious from the appearance of the copper electrode, when part of the surrounding bentonite had been removed, that both Cu(I) and Cu(II) corrosion products existed on the electrode surface. X-ray diffraction measurements also verified the presence of cuprite, Cu{sub 2}O, and malachite, Cu{sub 2}(OH){sub 2}CO{sub 3}, on the electrode; however, paratacamite, Cu{sub 2}(OH){sub 3}Cl, was not found. The performed Fourier transform infrared and Raman spectroscopy confirmed these observations. The corrosion product film, of which cuprite is the main part, was quite uneven and porous. No unmistakable signs of pitting have been found. The appearance of the copper electrode reminded of the coupons from the retrieved LOT test parcels, but was different from the appearance of the surface on the full-size canisters. For the latter blue-green Cu(II) corrosion products have not or only rarely been observed from visual examination immediately after removing the surrounding

Effects of temperature, pressure and pure copper added to source material on the CuGaTe{sub 2} deposition using close spaced vapor transport technique

Energy Technology Data Exchange (ETDEWEB)

Abounachit, O. [LP2M2E, Faculté des Sciences et Techniques, Université Cadi Ayyad, Gueliz, BP 549 , Marrakech, Maroc (Morocco); Chehouani, H., E-mail: chehouani@hotmail.fr [LP2M2E, Faculté des Sciences et Techniques, Université Cadi Ayyad, Gueliz, BP 549 , Marrakech, Maroc (Morocco); Djessas, K. [CNRS-PROMES Tecnosud, Rambla de la Thermodynamique, 66100 Perpignan (France)

2013-07-01

The quality of CuGaTe{sub 2} (CGT) thin films elaborated by close spaced vapor transport technique has been studied as a function of the source temperature (T{sub S}), iodine pressure (P{sub I2}) and the amount (X{sub Cu}) of pure copper added to the stoichiometric starting material. A thermodynamic model was developed for the Cu–Ga–Te–I system to describe the CGT deposition. The model predicts the solid phase composition with possible impurities for the operating conditions previously mentioned. The conditions of stoichiometric and near-stoichiometric deposition were determined. The value of T{sub S} must range from 450 to 550 °C for P{sub I2} varying between 0.2 and 7 kPa. Adding an amount up to 10% of pure copper to the starting material improves the quality of the deposit layers and lowers the operating interval temperature to 325–550 °C. These optimal conditions were tested experimentally at 480 °C and 500 °C. The X-ray diffraction, scanning electron microscopy, and energy dispersive spectroscopy have proved that the addition of pure copper to the stoichiometric source material can be considered as a supplementary operating parameter to improve the quality of CGT thin films. - Highlights: • The stoichiometric CuGaTe{sub 2} (CGT) has been deposited by close spaced vapor transport. • The Cu–Ga–Te–I system has been studied theoretically by minimizing the Gibbs energy. • The quality of thin films has been improved by pure copper added to the source CGT. • The temperature, pressure and the amount of copper added to grow CGT are determined. • The thermodynamic predictions are in good agreement with experimental results.

Uniformly Distributed Graphene Domain Grows on Standing Copper via Low-Pressure Chemical Vapor Deposition

Directory of Open Access Journals (Sweden)

Shih-Hao Chan

2013-01-01

Full Text Available Uniformly distributed graphene domains were synthesized on standing copper foil by a low-pressure chemical vapor deposition system. This method improved the distribution of the graphene domains at different positions on the same piece of copper foil along the forward direction of the gas flow. Scanning electron microscopy (SEM showed the average size of the graphene domains to be about ~20 m. This results show that the sheet resistance of monolayer graphene on a polyethylene terephthalate (PET substrate is about ~359 /□ whereas that of the four-layer graphene films is about ~178 /□, with a transmittance value of 88.86% at the 550 nm wavelength. Furthermore, the sheet resistance can be reduced with the addition of HNO3 resulting in a value of 84 /□. These values meet the absolute standard for touch sensor applications, so we believe that this method can be a candidate for some transparent conductive electrode applications.

Study of the crystallographic phase change on copper (I) selenide thin films prepared through chemical bath deposition by varying the pH of the solution

Energy Technology Data Exchange (ETDEWEB)

Sandoval-Paz, M.G., E-mail: myrnasandoval@udec.cl [Departament of Physics, Faculty of Physical Sciences and Mathematics, University of Concepcion, Box 160-C, Concepción (Chile); Rodríguez, C.A. [Department of Materials Engineering, Faculty of Engineering, University of Concepción, Edmundo Larenas 270, Concepción 4070409 (Chile); Porcile-Saavedra, P.F. [Departament of Physics, Faculty of Physical Sciences and Mathematics, University of Concepcion, Box 160-C, Concepción (Chile); Trejo-Cruz, C. [Department of Physics, Faculty of Science, University of Biobío, Avenue Collao 1202, Box 5C, Concepción 4051381 (Chile)

2016-07-15

Copper (I) selenide thin films with orthorhombic and cubic structure were deposited on glass substrates by using the chemical bath deposition technique. The effects of the solution pH on the films growth and subsequently the structural, optical and electrical properties of the films were studied. Films with orthorhombic structure were obtained from baths wherein both metal complex and hydroxide coexist; while films with cubic structure were obtained from baths where the metal hydroxide there is no present. The structural modifications are accompanied by changes in bandgap energy, morphology and electrical resistivity of the films. - Graphical abstract: “Study of the crystallographic phase change on copper (I) selenide thin films prepared through chemical bath deposition by varying the pH of the solution” by M. G. Sandoval-Paz, C. A. Rodríguez, P. F. Porcile-Saavedra, C. Trejo-Cruz. Display Omitted - Highlights: • Copper (I) selenide thin films were obtained by chemical bath deposition. • Orthorhombic to cubic phase change was induced by varying the reaction solution pH. • Orthorhombic phase is obtained mainly from a hydroxides cluster mechanism. • Cubic phase is obtained mainly from an ion by ion mechanism. • Structural, optical and electrical properties are presented as a function of pH.

Iron oxide copper-gold deposits in the Islamic Republic of Mauritania (phase V, deliverable 79): Chapter M in Second projet de renforcement institutionnel du secteur minier de la République Islamique de Mauritanie (PRISM-II)

Science.gov (United States)

Fernette, Gregory

2015-01-01

Mauritania hosts one significant copper-gold deposit, Guelb Moghrein and several occurrences, which have been categorized as iron oxide copper-gold (IOCG) deposits but which are atypical in some important respects. Nonetheless, Guelb Moghrein is an economically significant mineral deposit and an attractive exploration target. The deposit is of Archean age and is hosted by a distinctive metacarbonate rock which is part of a greenstone-banded iron formation (BIF) package within a thrust stack in the northern part of the Mauritanide Belt. The surrounding area hosts a number of similar copper-gold occurrences. Based on the characteristics of the Guelb Moghrein deposit and its geologic environment, five tracts which are considered permissive for IOCG type mineralization similar to Guelb Moghrein have been delineated.

Reinforcing copper matrix composites through molecular-level mixing of functionalized nanodiamond by co-deposition route

International Nuclear Information System (INIS)

He Jie; Zhao Naiqin; Shi Chunsheng; Du Xiwen; Li Jiajun; Nash, Philip

2008-01-01

This work reports a chemical method called 'co-deposition route' for fabricating ND (nanodiamond)/Cu composite at a molecular-level mixing. The main procedure of 'co-deposition route' includes four steps. ND particles have been functionalized by HF acid before co-deposition. SEM, HRTEM (high-resolution transmission electron spectroscopy), XRD (X-ray diffraction), EDS (energy-dispersive spectrum analysis) and optical microscope were carried out to characterize the as-prepared composite powders and bulk composites. Results indicated that copper matrix composite with a homogeneous dispersion of functionalized ND particles can be prepared. The modification of ND particles was performed by HF (30 vol%) acid at 70 deg. C, and C-F bond was successfully detected by XPS (X-ray photoelectron spectrum) and IR (Infrared spectroscopy). The properties of relative density, microhardness and electric conductivity of ND/Cu composites have been measured. With the comparison of conventional methods, it showed that the as-prepared ND/Cu composites with good combined performances have a promising future for industry application

Cold-climate slope deposits and landscape modifications of the Mid-Atlantic Coastal Plain, Eastern USA

Science.gov (United States)

Newell, Wayne L.; Dejong, B.D.

2011-01-01

The effects of Pleistocene cold-climate geomorphology are distributed across the weathered and eroded Mid-Atlantic Coastal Plain uplands from the Wisconsinan terminal moraine south to Tidewater Virginia. Cold-climate deposits and landscape modifications are superimposed on antecedent landscapes of old, weathered Neogene upland gravels and Pleistocene marine terraces that had been built during warm periods and sea-level highstands. In New Jersey, sequences of surficial deposits define a long history of repeating climate change events. To the south across the Delmarva Peninsula and southern Maryland, most antecedent topography has been obscured by Late Pleistocene surficial deposits. These are spatially variable and are collectively described as a cold-climate alloformation. The cold-climate alloformation includes time-transgressive details of climate deterioration from at least marine isotope stage (MIS) 4 through the end of MIS 2. Some deposits and landforms within the alloformation may be as young as the Younger Dryas. Southwards along the trend of the Potomac River, these deposits and their climatic affinities become diffused. In Virginia, a continuum of erosion and surficial deposits appears to be the product of ‘normal’ temperate, climate-forced processes. The cold-climate alloformation and more temperate deposits in Virginia are being partly covered by Holocene alluvium and bay mud.

Influences of Corrosive Sulfur on Copper Wires and Oil-Paper Insulation in Transformers

Directory of Open Access Journals (Sweden)

Jian Li

2011-10-01

Full Text Available Oil-impregnated paper is widely used in power transmission equipment as a reliable insulation. However, copper sulphide deposition on oil-paper insulation can lead to insulation failures in power transformers. This paper presents the influences of copper sulfur corrosion and copper sulphide deposition on copper wires and oil-paper insulation in power transformers. Thermal aging tests of paper-wrapped copper wires and bare copper wires in insulating oil were carried out at 130 °C and 150 °C in laboratory. The corrosive characteristics of paper-wrapped copper wires and bare copper wires were analyzed. Dielectric properties of insulation paper and insulating oil were also analyzed at different stages of the thermal aging tests using a broadband dielectric spectrometer. Experiments and analysis results show that copper sulfide deposition on surfaces of copper wires and insulation paper changes the surface structures of copper wires and insulation paper. Copper sulfur corrosion changes the dielectric properties of oil-paper insulation, and the copper sulfide deposition greatly reduces the electrical breakdown strength of oil-paper insulation. Metal passivator is capable of preventing copper wires from sulfur corrosion. The experimental results are helpful for investigations for fault diagnosis of internal insulation in power transformers.

Spray-Deposited Large-Area Copper Nanowire Transparent Conductive Electrodes and Their Uses for Touch Screen Applications.

Science.gov (United States)

Chu, Hsun-Chen; Chang, Yen-Chen; Lin, Yow; Chang, Shu-Hao; Chang, Wei-Chung; Li, Guo-An; Tuan, Hsing-Yu

2016-05-25

Large-area conducting transparent conducting electrodes (TCEs) were prepared by a fast, scalable, and low-cost spray deposition of copper nanowire (CuNW) dispersions. Thin, long, and pure copper nanowires were obtained via the seed-mediated growth in an organic solvent-based synthesis. The mean length and diameter of nanowires are, respectively, 37.7 μm and 46 nm, corresponding to a high-mean-aspect ratio of 790. These wires were spray-deposited onto a glass substrate to form a nanowire conducting network which function as a TCE. CuNW TCEs exhibit high-transparency and high-conductivity since their relatively long lengths are advantageous in lowering in the sheet resistance. For example, a 2 × 2 cm(2) transparent nanowire electrode exhibits transmittance of T = 90% with a sheet resistance as low as 52.7 Ω sq(-1). Large-area sizes (>50 cm(2)) of CuNW TCEs were also prepared by the spray coating method and assembled as resistive touch screens that can be integrated with a variety of devices, including LED lighting array, a computer, electric motors, and audio electronic devices, showing the capability to make diverse sizes and functionalities of CuNW TCEs by the reported method.

Growth graphene on silver-copper nanoparticles by chemical vapor deposition for high-performance surface-enhanced Raman scattering

Science.gov (United States)

Zhang, Xiumei; Xu, Shicai; Jiang, Shouzhen; Wang, Jihua; Wei, Jie; Xu, Shida; Gao, Shoubao; Liu, Hanping; Qiu, Hengwei; Li, Zhen; Liu, Huilan; Li, Zhenhua; Li, Hongsheng

2015-10-01

We present a graphene/silver-copper nanoparticle hybrid system (G/SCNPs) to be used as a high-performance surface-enhanced Raman scattering (SERS) substrate. The silver-copper nanoparticles wrapped by a monolayer graphene layer are directly synthesized on SiO2/Si substrate by chemical vapor deposition in a mixture of methane and hydrogen. The G/SCNPs shows excellent SERS enhancement activity and high reproducibility. The minimum detected concentration of R6G is as low as 10-10 M and the calibration curve shows a good linear response from 10-6 to 10-10 M. The date fluctuations from 20 positions of one SERS substrate are less than 8% and from 20 different substrates are less than 10%. The high reproducibility of the enhanced Raman signals could be due to the presence of an ultrathin graphene layer and uniform morphology of silver-copper nanoparticles. The use of G/SCNPs for detection of nucleosides extracted from human urine demonstrates great potential for the practical applications on a variety of detection in medicine and biotechnology field.

History of ancient megathrust earthquakes beneath metropolitan Tokyo inferred from coastal lowland deposits

Science.gov (United States)

Mannen, Kazutaka; Yoong, Kim Haeng; Suzuki, Shigeru; Matsushima, Yoshiaki; Ota, Yuki; Kain, Claire L.; Goff, James

2018-02-01

Metropolitan Tokyo is located directly above a subduction zone that has generated two megathrust earthquakes in the past 300 years. However, the timing of older megathrusts on this margin is poorly understood. In this study, we aim to constrain the timings of past megathrust earthquakes, using coastal stratigraphy, paleoecology, radiocarbon dating and archaeological records from coastal lowlands. An investigation of 13 boreholes in the southern coastal area of metropolitan Tokyo found evidence for 4 m of uplift in a 6000-year period. However, we found that net vertical displacement in the last 1000 years is approximately zero. Results suggest that preservation of usually ephemeral lagoon sediments occurred on three occasions in the past 1000 years, and radiocarbon dating results show that the timings of these preservation episodes are close to that of major historical earthquakes. We thus attribute the intermittent preservation of the ephemeral lagoon deposits to coseismic uplift caused by the megathrust earthquakes. The candidates of the megathrust earthquakes are events that took place in 1703 CE, the 13th century, and 878 CE. Since these events produced no net vertical displacement due to inter-seismic subsidence, we propose that earthquakes responsible for long-term uplift of this region took place prior to the 9th century. This research also demonstrates the value of preserved intertidal sediments as paleoseismological archives where net tectonic displacement is neutral.

Role of Snow Deposition of Perfluoroalkylated Substances at Coastal Livingston Island (Maritime Antarctica).

Science.gov (United States)

Casal, Paulo; Zhang, Yifeng; Martin, Jonathan W; Pizarro, Mariana; Jiménez, Begoña; Dachs, Jordi

2017-08-01

Perfluoroalkyl substances (PFAS) are ubiquitous in the environment, including remote polar regions. To evaluate the role of snow deposition as an input of PFAS to Maritime Antarctica, fresh snow deposition, surface snow, streams from melted snow, coastal seawater, and plankton samples were collected over a three-month period (December 2014-February 2015) at Livingston Island. Local sources of PFASs were significant for perfluoroalkyl sulfonates (PFSAs) and C7-14 perfluoroalkyl carboxylates (PFCAs) in snow but limited to the transited areas of the research station. The concentrations of 14 ionizable PFAS (∑PFAS) in freshly deposited snow (760-3600 pg L -1 ) were 1 order of magnitude higher than those in background surface snow (82-430 pg L -1 ). ∑PFAS ranged from 94 to 420 pg L -1 in seawater and from 3.1 to 16 ng g dw -1 in plankton. Ratios of individual PFAS concentrations in freshly deposited snow relative to surface snow (C SD /C Snow ), snowmelt (C SD /C SM ), and seawater (C SD /C SW ) were close to 1 (from 0.44 to 1.4) for all perfluorooctanesulfonate (PFOS) isomers, suggesting that snowfall does not contribute significantly to PFOS in seawater. Conversely, these ratios for PFCAs ranged from 1 to 33 and were positively correlated with the number of carbons in the PFCA alkylated chain. These trends suggest that snow deposition, scavenging sea-salt aerosol bound PFAS, plays a role as a significant input of PFCAs to the Maritime Antarctica.

Formation of copper tin sulfide films by pulsed laser deposition at 248 and 355 nm

DEFF Research Database (Denmark)

Ettlinger, Rebecca Bolt; Crovetto, Andrea; Canulescu, Stela

2016-01-01

The influence of the laser wavelength on the deposition of copper tin sulfide (CTS) and SnS-rich CTS with a 248-nm KrF excimer laser (pulse length τ = 20 ns) and a 355-nm frequency-tripled Nd:YAG laser (τ = 6 ns) was investigated. A comparative study of the two UV wavelengths shows that the CTS...... film growth rate per pulse was three to four times lower with the 248-nm laser than the 355-nm laser. SnS-rich CTS is more efficiently ablated than pure CTS. Films deposited at high fluence have submicron and micrometer size droplets, and the size and area density of the droplets do not vary significantly...

Porphyry copper assessment of western Central Asia: Chapter N in Global mineral resource assessment

Science.gov (United States)

Berger, Byron R.; Mars, John L.; Denning, Paul; Phillips, Jeffrey D.; Hammarstrom, Jane M.; Zientek, Michael L.; Dicken, Connie L.; Drew, Lawrence J.; with contributions from Alexeiev, Dmitriy; Seltmann, Reimar; Herrington, Richard J.

2014-01-01

The U.S. Geological Survey conducted an assessment of resources associated with porphyry copper deposits in the western Central Asia countries of Kyrgyzstan, Uzbekistan, Kazakhstan, and Tajikistan and the southern Urals of Kazakhstan and Russia as part of a global mineral resource assessment. The purpose of the study was to (1) delineate permissive areas (tracts) for undiscovered porphyry copper deposits; (2) compile a database of known porphyry copper deposits and significant prospects; (3) where data permit, estimate numbers of undiscovered deposits within those permissive tracts; and (4) provide probabilistic estimates the amounts of copper (Cu), molybdenum (Mo), gold (Au), and silver (Ag) that could be contained in those undiscovered deposits.

Reinforcing copper matrix composites through molecular-level mixing of functionalized nanodiamond by co-deposition route

Energy Technology Data Exchange (ETDEWEB)

He Jie [School of Materials Science and Engineering, Tianjin University, Tianjin 30072 (China); Zhao Naiqin [School of Materials Science and Engineering, Tianjin University, Tianjin 30072 (China); Tianjin Key Laboratory of Composite and Functional Materials (China)], E-mail: nqzhao@tju.edu.cn; Shi Chunsheng; Du Xiwen; Li Jiajun [School of Materials Science and Engineering, Tianjin University, Tianjin 30072 (China); Nash, Philip [Department of Mechanical, Materials and Aerospace Engineering, Illinois Institute of Technology, Chicago, IL 60616 (United States)

2008-08-25

This work reports a chemical method called 'co-deposition route' for fabricating ND (nanodiamond)/Cu composite at a molecular-level mixing. The main procedure of 'co-deposition route' includes four steps. ND particles have been functionalized by HF acid before co-deposition. SEM, HRTEM (high-resolution transmission electron spectroscopy), XRD (X-ray diffraction), EDS (energy-dispersive spectrum analysis) and optical microscope were carried out to characterize the as-prepared composite powders and bulk composites. Results indicated that copper matrix composite with a homogeneous dispersion of functionalized ND particles can be prepared. The modification of ND particles was performed by HF (30 vol%) acid at 70 deg. C, and C-F bond was successfully detected by XPS (X-ray photoelectron spectrum) and IR (Infrared spectroscopy). The properties of relative density, microhardness and electric conductivity of ND/Cu composites have been measured. With the comparison of conventional methods, it showed that the as-prepared ND/Cu composites with good combined performances have a promising future for industry application.

Efficient electron-induced removal of oxalate ions and formation of copper nanoparticles from copper(II oxalate precursor layers

Directory of Open Access Journals (Sweden)

Kai Rückriem

2016-06-01

Full Text Available Copper(II oxalate grown on carboxy-terminated self-assembled monolayers (SAM using a step-by-step approach was used as precursor for the electron-induced synthesis of surface-supported copper nanoparticles. The precursor material was deposited by dipping the surfaces alternately in ethanolic solutions of copper(II acetate and oxalic acid with intermediate thorough rinsing steps. The deposition of copper(II oxalate and the efficient electron-induced removal of the oxalate ions was monitored by reflection absorption infrared spectroscopy (RAIRS. Helium ion microscopy (HIM reveals the formation of spherical nanoparticles with well-defined size and X-ray photoelectron spectroscopy (XPS confirms their metallic nature. Continued irradiation after depletion of oxalate does not lead to further particle growth giving evidence that nanoparticle formation is primarily controlled by the available amount of precursor.

Partitioning and distribution of dissolved copper, cadmium and organic matter in Mediterranean marine coastal areas: The case of a mucilage event

Science.gov (United States)

Scoullos, Michael; Plavšić, Marta; Karavoltsos, Sotiris; Sakellari, Aikaterini

2006-04-01

Dissolved copper and cadmium partitioning and their interaction with organic matter were investigated in shallow coastal areas of the Aegean Sea (Eastern Mediterranean). The percentage of DGT-labile copper as for total dissolved copper ranged from 13 to 34% during summer and from 23 to 36% during winter, whereas the corresponding percentage for DGT-labile cadmium was higher in summer (38-68%), in comparison to winter (29-44%). The CCu was found to be 100-260 nM during summer while in winter the range was 42-430 nM. The corresponding CCd reached 27 and 45 nM, respectively. The mean TEP value in summer was high (208 μg/L xanthan equiv.), while in winter it reached 441 μg/L xanthan equiv., which indicates significant phytoplankton activity in winter, a feature occasionally observed in the stratified study areas after the breaking down of the thermocline/pycnocline, followed by consequent nutrient enrichment of the surface layers by nutrients accumulated in the sea bottom. A significant fraction of dissolved organic carbon (DOC) exhibited surface active properties and was determined as surface active substances (SAS) in mg/L eq. of nonionic surfactant Triton-X-100. Carbohydrates were also determined and they represented up to 33% of the DOC.

Low-fluorine Stockwork Molybdenite Deposits

Science.gov (United States)

Ludington, Steve; Hammarstrom, Jane; Piatak, Nadine M.

2009-01-01

Low-fluorine stockwork molybdenite deposits are closely related to porphyry copper deposits, being similar in their tectonic setting (continental volcanic arc) and the petrology (calc-alkaline) of associated igneous rock types. They are mainly restricted to the Cordillera of western Canada and the northwest United States, and their distribution elsewhere in the world may be limited. The deposits consist of stockwork bodies of molybdenite-bearing quartz veinlets that are present in and around the upper parts of intermediate to felsic intrusions. The deposits are relatively low grade (0.05 to 0.2 percent Mo), but relatively large, commonly >50 million tons. The source plutons for these deposits range from granodiorite to granite in composition; the deposits primarily form in continental margin subduction-related magmatic arcs, often concurrent with formation of nearby porphyry copper deposits. Oxidation of pyrite in unmined deposits or in tailings and waste rock during weathering can lead to development of acid-rock drainage and limonite-rich gossans. Waters associated with low-fluorine stockwork molybdenite deposits tend to be nearly neutral in pH; variable in concentrations of molybdenum (10,000 ug/L); below regulatory guidelines for copper, iron, lead, zinc, and mercury; and locally may exceed guidelines for arsenic, cadmium, and selenium.

Magnetotelluric evidence for a deep-crustal mineralizing system beneath the Olympic Dam iron oxide copper-gold deposit, southern Australia

Science.gov (United States)

Heinson, Graham S.; Direen, Nicholas G.; Gill, Rob M.

2006-07-01

The iron oxide copper-gold Olympic Dam deposit, situated along the margin of the Proterozoic Gawler craton, South Australia, is the world's largest uranium deposit and sixth-largest copper deposit; it also contains significant reserves of gold, silver, and rare earth elements. Gaining a better understanding of the mechanisms for genesis of the economic liberalization is fundamental for defining exploration models in similar crustal settings. To delineate crustal structures that may constrain mineral system fluid pathways, coincident deep crustal seismic and magnetotelluric (MT) transects were obtained along a 220 km section that crosses Olympic Dam and the major crustal boundaries. In this paper we present results from 58 long-period (10 104 s) MT sites, with site spacing of 5 10 km. A two-dimensional inversion of MT data from 33 sites to a depth of 100 km shows four notable features: (1) sedimentary cover sequences with low resistivity (1000 Ω·m) Archean crustal core from a more conductive crust and mantle to the north (typically Olympic Dam, the upper-middle crust to ˜20 km is quite resistive (˜1000 Ω·m), but the lower crust is much more conductive (Olympic Dam, we image a low-resistivity region (Olympic Dam may be due to the upward movement of CO2-bearing volatiles near the time of deposit formation that precipitated conductive graphite liberalization along grain boundaries, simultaneously annihilating acoustic impedance boundaries. The source of the volatiles may be from the mantle degassing or retrograde metamorphism of the lower crust associated with Proterozoic crustal deformation.

Mineralogy of metasomatic rocks and geochronology of the Olhovka porphyry-copper deposit, Chukotka, Russia

Science.gov (United States)

Rogacheva, Lyuba; Baksheev, Ivan

2010-05-01

The Olkhovka porphyry-copper deposit located on the border of foreland of the Okhotsk-Chukotka volcanic belt (OCVB) and a ledge composed of the Late Jurassic-Early Cretaceous Uda-Murgal arc (J3-K1) rocks is hosted by monzonite stock attributed to the Upper Cretaceous Kavralyan complex - K2) We estimated age of the Olkhovka monzonite by Rb-Sr and U-Pb methods. Rb-Sr age was determine om the basis of isotopic analysis of 8 monomineralic samples (potassium feldspar, plagioclase, amphibole, and dark mica). Isochron constructed on the basis of Rb-Sr data corresponds to the age of 78 + 2.6 Ma (MSWD=0.23). The Rb-Sr age is supported by U-Pb data derived from zircon of the same rock. One hundred and three single crystals of zircon were analyzed. Uranium content ranges from 52.66 ppm to 579.64 ppm; U/Th isotopic ratio varies from 0.567 to 1.746; age is 78.02+0.65 Ma (MSWD = 2.8). Monzonite is propylitized in variable degree. Propylite is composed of actinolite, chlorite, albite, quartz, and calcite. Propylite are cut by quartz-tourmaline veins. In addition, quartz-tourmaline metasomatic rock was identified in rhyolite ignimbrite out of the stock. Microscopically, tourmaline crystals of both types are oscilatory zoned that is caused by variable Fe content. Tourmalines of both assemblages can be classified as intermediate member of the schorl ("oxy-schorl")-dravite ("oxy-dravite") series. The Fetot/ (Fetot+Mg) varies from 0.31 to 0.95 in propylitic tourmaline and from 0.11 to 0.49, in quartz-tourmaline altered rocks from ignimbrite. Despite similar composition of both tourmalines, the major isomorphic substitutions in them are different. In propylite tourmaline, it is Fe → Al, whereas in the second case, it is Fe → Mg with certain effect of the Fe → Al type. Fe → Al isomorphic substitution is typical of porphyry style deposits (Baksheev et al., 2009 [1]). Therefore, we can conclude that quartz-tourmaline alteration in ignimbrite does not related to the formation of

Magmatic fluid inclusions from the Zaldivar Deposits, Northern Chile: The role of early metal-bearing fluids in a Porphyry copper system

NARCIS (Netherlands)

drs Campos, E.; Touret, J.L.R.; Nikogosian, I.

2006-01-01

The occurrence of a distinct type of multi-solid, highly-saline fluid inclusions, hosted in igneous quartz phenocrysts from the Llamo porphyry, in the Zaldívar porphyry copper deposit of northern Chile is documented. Total homogenization of the multi-solid type inclusions occurs at magmatic

"Magmatic fluid inclusions from the Zaldivar deposit, Northern Chile: The role of Early metal-bearing fluids in a porphyry copper system."

NARCIS (Netherlands)

drs Campos, E.; Touret, J.L.R.; Nikogosian, I.

2006-01-01

The occurrence of a distinct type of multi-solid, highly-saline fluid inclusions, hosted in igneous quartz phenocrysts from the Llamo porphyry, in the Zaldívar porphyry copper deposit of northern Chile is documented. Total homogenization of the multi-solid type inclusions occurs at magmatic

Undiscovered porphyry copper resources in the Urals—A probabilistic mineral resource assessment

Science.gov (United States)

Hammarstrom, Jane M.; Mihalasky, Mark J.; Ludington, Stephen; Phillips, Jeffrey; Berger, Byron R.; Denning, Paul; Dicken, Connie; Mars, John; Zientek, Michael L.; Herrington, Richard J.; Seltmann, Reimar

2017-01-01

A probabilistic mineral resource assessment of metal resources in undiscovered porphyry copper deposits of the Ural Mountains in Russia and Kazakhstan was done using a quantitative form of mineral resource assessment. Permissive tracts were delineated on the basis of mapped and inferred subsurface distributions of igneous rocks assigned to tectonic zones that include magmatic arcs where the occurrence of porphyry copper deposits within 1 km of the Earth's surface are possible. These permissive tracts outline four north-south trending volcano-plutonic belts in major structural zones of the Urals. From west to east, these include permissive lithologies for porphyry copper deposits associated with Paleozoic subduction-related island-arc complexes preserved in the Tagil and Magnitogorsk arcs, Paleozoic island-arc fragments and associated tonalite-granodiorite intrusions in the East Uralian zone, and Carboniferous continental-margin arcs developed on the Kazakh craton in the Transuralian zone. The tracts range from about 50,000 to 130,000 km2 in area. The Urals host 8 known porphyry copper deposits with total identified resources of about 6.4 million metric tons of copper, at least 20 additional porphyry copper prospect areas, and numerous copper-bearing skarns and copper occurrences.Probabilistic estimates predict a mean of 22 undiscovered porphyry copper deposits within the four permissive tracts delineated in the Urals. Combining estimates with established grade and tonnage models predicts a mean of 82 million metric tons of undiscovered copper. Application of an economic filter suggests that about half of that amount could be economically recoverable based on assumed depth distributions, availability of infrastructure, recovery rates, current metals prices, and investment environment.

Eemian Rhine delta architecture in The Netherlands: facies distribution, deposit characteristics and preservation potential in an near-coastal deltaic setting

NARCIS (Netherlands)

Peeters, J.

2012-01-01

Within near-coastal environments, the fluvial-tidal transition zone is one of the most complex zones due to mixture of processes and sediments of different source and depositional styles. Despite a large number of excellent Holocene fluvial-estuarine cases, transferring sedimentary concepts into

Oxidation-assisted graphene heteroepitaxy on copper foil

OpenAIRE

Reckinger, Nicolas; Tang, Xiaohui; Joucken, Frédéric; Lajaunie, Luc; Arenal, Raul; Dubois, Emmanuel; Hackens, Benoît; Henrard, Luc; Colomer, Jean-François

2016-01-01

We propose an innovative, easy-to-implement approach to synthesize large-area singlecrystalline graphene sheets by chemical vapor deposition on copper foil. This method doubly takes advantage of residual oxygen present in the gas phase. First, by slightly oxidizing the copper surface, we induce grain boundary pinning in copper and, in consequence, the freezing of the thermal recrystallization process. Subsequent reduction of copper under hydrogen suddenly unlocks the delayed reconstruction, f...

HEAVY MINERALS IN PLACER DEPOSIT IN SINGKAWANG WATERS, WEST Kalimantan, RELATED TO FELSIC SOURCE ROCK OF ITS COASTAL AREA

Directory of Open Access Journals (Sweden)

Deny Setiady

2017-07-01

Full Text Available Placer deposits are physically accumulated by fluvial and marine processes in coastal area. Thirty six samples were selected from seventy seven samples of seafloor sediment of Singkawang waters. Those samples have been analyzed microscopically for heavy mineral contents. Based on this analysis, the heavy minerals can be divided into four groups: oxyde and hydroxyde, silicate, sulphide, and carbonate. The source of most heavy minerals in the study area is commonly formed by Felsic igneous rock and finally deposited on the seafloor sediments.

Synthesis Characterization and Decomposition Studies of tris[N-N-dibenzyidithocarbaso)Indium (III) Chemical Spray Deposition of Polycrystalline CuInS2 on Copper Films

Science.gov (United States)

Hehemann, David G.; Lau, J. Eva; Harris, Jerry D.; Hoops, Michael D.; Duffy, Norman V.

2005-01-01

This paper presents the results of the synthesis characterization and decomposition studies of tris[N-N-dibenzyidithocarbaso)Indium (III) with chemical spray deposition of polycrystalline CuInS2 on Copper Films.

Comparative Study of Electroless Copper Film on Different Self-Assembled Monolayers Modified ABS Substrate

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Jiushuai Xu

2014-04-01

Full Text Available Copper films were grown on (3-Mercaptopropyltrimethoxysilane (MPTMS, (3-Aminopropyltriethoxysilane (APTES and 6-(3-(triethoxysilylpropylamino-1,3,5- triazine-2,4-dithiol monosodium (TES self-assembled monolayers (SAMs modified acrylonitrile-butadiene-styrene (ABS substrate via electroless copper plating. The copper films were examined using scanning electron microscopy (SEM and X-ray diffraction (XRD. Their individual deposition rate and contact angle were also investigated to compare the properties of SAMs and electroless copper films. The results indicated that the formation of copper nuclei on the TES-SAMs modified ABS substrate was faster than those on the MPTMS-SAMs and APTES-SAMs modified ABS substrate. SEM images revealed that the copper film on TES-SAM modified ABS substrate was smooth and uniform, and the density of copper nuclei was much higher. Compared with that of TES-SAMs modified resin, the coverage of copper nuclei on MPTMS and APTES modified ABS substrate was very limited and the copper particle size was too big. The adhesion property test demonstrated that all the SAMs enhanced the interfacial interaction between copper plating and ABS substrate. XRD analysis showed that the copper film deposited on SAM-modified ABS substrate had a structure with Cu(111 preferred orientation, and the copper film deposited on TES-SAMs modified ABS substrate is better than that deposited on MPTMS-SAMs or APTES-SAMs modified ABS resins in electromigrtion resistance.

Application of plurigaussian simulation to delineate the layout of alteration domains in Sungun copper deposit

Science.gov (United States)

Talebi, Hassan; Asghari, Omid; Emery, Xavier

2013-12-01

An accurate estimation of mineral grades in ore deposits with heterogeneous spatial variations requires defining geological domains that differentiate the types of mineralogy, alteration and lithology. Deterministic models define the layout of the domains based on the interpretation of the drill holes and do not take into account the uncertainty in areas with fewer data. Plurigaussian simulation (PGS) can be an alternative to generate multiple numerical models of the ore body, with the aim of assessing the uncertainty in the domain boundaries and improving the geological controls in the characterization of quantitative attributes. This study addresses the application of PGS to Sungun porphyry copper deposit (Iran), in order to simulate the layout of four hypogene alteration zones: potassic, phyllic, propylitic and argillic. The aim of this study is to construct numerical models in which the alteration structures reflect the evolution observed in the geology.

Ring structures and copper mineralization in Kerman porphyry copper belt, SE Iran

Directory of Open Access Journals (Sweden)

Gholamreza Mirzababaei

2012-10-01

Full Text Available The role of some ring structures in the distribution of porphyry copper deposits in south Kerman porphyry copper belt is discussed. In the study area, ring structures are circular or elliptical shaped features which are partly recognized on satellite images. In this study, Landsat multispectral images were used to identify ring structures in the area. The rudimentary identification stages of the circles were mainly based on their circular characteristics on the images. These structures match with the regional tectonic features and can be seen mainly in two types; namely, large-magnitude and small scale circles. The associated mineralization in the study area is mainly porphyry Cu and vein type base metal sulfide deposits. There is a sensible relationship between the large circles and mineralization. These circles have encompassed almost entire Cu deposits and prospects in south part of Kerman porphyry copper belt. The small circles seem to be external traces of (porphyritic intrusive bodies that appear on surface as small circles. Formation of the large circular structures do not appear to be related to the external processes and there is no clear indication of how they came into existence but, their arrangement around the edges of a positive residual anomaly area shows the probable role of this anomaly in their formation. This matter is also recognized on the generalized crustal thickness map of the region in which an updoming of the upper mantle is observed. This study can improve our collective knowledge for copper exploration in this region.

Evolution of radioactive dose rates in fresh sediment deposits along coastal rivers draining Fukushima contamination plume

OpenAIRE

Evrard, Olivier; Chartin, Caroline; Onda, Yuichi; Patin, Jeremy; Lepage, Hugo; Lef?vre, Ir?ne; Ayrault, Sophie; Ottl?, Catherine; Bont?, Philippe

2013-01-01

Measurement of radioactive dose rates in fine sediment that has recently deposited on channel bed-sand provides a solution to address the lack of continuous river monitoring in Fukushima Prefecture after Fukushima Dai-ichi nuclear power plant (FDNPP) accident. We show that coastal rivers of Eastern Fukushima Prefecture were rapidly supplied with sediment contaminated by radionuclides originating from inland mountain ranges, and that this contaminated material was partly exported by typhoons t...

Porphyry copper assessment of the Tibetan Plateau, China: Chapter F in Global mineral resource assessment

Science.gov (United States)

Ludington, Steve; Hammarstrom, Jane M.; Robinson, Gilpin R.; Mars, John L.; Miller, Robert J.

2012-01-01

The U.S. Geological Survey collaborated with the China Geological Survey to conduct a mineral-resource assessment of resources in porphyry copper deposits on the Tibetan Plateau in western China. This area hosts several very large porphyry deposits, exemplified by the Yulong and Qulong deposits, each containing at least 7,000,000 metric tons (t) of copper. However, large parts of the area are underexplored and are likely to contain undiscovered porphyry copper deposits.

Analysis of rainfall characteristics and its related disasters of slag disposal pit of a certain Gold-Copper Deposit in Fujian province

Science.gov (United States)

Pan, Huali; Hu, Mingjian; Ou, Guoqiang

2017-04-01

According to the geological investigation in Fujian province, the total number of geological disasters was 9513, in which the number of landslide, collapse, unstable slope and surface collapse was 5816, 1888, 1591, 103 and 115 respectively. The main geological disaster was the landslide with 61.1% of total geological disasters. Among all these geological disasters, only 6.0% was relative stable, 17.0% was basic stable, nearly 76.0% was unstable. The slope disaster was the main geological disaster, if the unstable slope was the potential landslide or collapse; the slope collapse was 98.0% of all geological disasters. The rainfall, in particular the heavy rain, was direct dynamic factor for geological disasters, but the occurrence probability of geological disasters was different because of the sensitivity of the geological environment though of the same intensity rainfall. To obtain the characteristics of soil erosion under the rainfall condition, the rainfall characteristics and its related disasters of slag disposal pit of a certain Gold-Copper Deposit in Fujian province was analyzed by the meteorological and rainfall data. According to the distribution of monitoring stations of hydrological and rainfall in Longyan city of Fujian province and the location of gold-copper deposit, the Shanghang monitoring station of hydrological and rainfall was chosen, which is the nearest one to the gold-copper deposit. Then main parameters of the prediction model, the antecedent precipitation, the rainfall on the day and the rainfall threshold, were calculated by using the rainfall data from 2002 to 2010. And the relationship between geological disasters and the rainfall characteristics were analyzed. The results indicated that there was high risk for the debris flow with landslide collapse when either the daily rainfall was more than 100.0 mm, or the total rainfall was more than 136.0mm in the gold-copper deposit and the Shanghang region. At the same time, although there was few

Copper and copper-nickel-alloys - An overview

Energy Technology Data Exchange (ETDEWEB)

Klassert, Anton; Tikana, Ladji [Deutsches Kupferinstitut e.V. Am Bonneshof 5, 40474 Duesseldorf (Germany)

2004-07-01

With the increasing level of industrialization the demand for and the number of copper alloys rose in an uninterrupted way. Today, the copper alloys take an important position amongst metallic materials due to the large variety of their technological properties and applications. Nowadays there exist over 3.000 standardized alloys. Copper takes the third place of all metals with a worldwide consumption of over 15 millions tons per year, following only to steel and aluminum. In a modern industrial society we meet copper in all ranges of the life (electro-technology, building and construction industry, mechanical engineering, automotive, chemistry, offshore, marine engineering, medical applications and others.). Copper is the first metal customized by humanity. Its name is attributed to the island Cyprus, which supplied in the antiquity copper to Greece, Rome and the other Mediterranean countries. The Romans called it 'ore from Cyprus' (aes cyprium), later cuprum. Copper deposited occasionally also dapper and could be processed in the recent stone age simply by hammering. Already in early historical time copper alloys with 20 to 50 percent tin was used for the production of mirrors because of their high reflecting power. Although the elementary nickel is an element discovered only recently from a historical perspective, its application in alloys - without any knowledge of the alloy composition - occurred at least throughout the last 2.000 years. The oldest copper-nickel coin originates from the time around 235 B.C.. Only around 1800 AD nickel was isolated as a metallic element. In particular in the sea and offshore technology copper nickel alloys found a broad field of applications in piping systems and for valves and armatures. The excellent combination of characteristics like corrosion resistance, erosion stability and bio-fouling resistance with excellent mechanical strength are at the basis of this success. An experience of many decades supports the use

Monitoring Coastal Change after the Tsunami in Thailand

International Nuclear Information System (INIS)

Pantanahiran, W

2014-01-01

The tsunami on December 26, 2004 caused widespread devastation along the coast of Thailand, especially in Ban Nam Khem, Phang Nga province. This disaster claimed more than 941 lives, with 502 other people missing when the storm surge caught the residents of this area. The coastal geomorphology was impacted by this disaster. The objectives of the research were to study the effect of the tsunami on coastal change and the recovery of coastal areas. Six time-series datasets of aerial photographs and satellite images from 2002, 2004, 2005, 2006, 2009, and 2010 were compared using the Geographic Information System (GIS). The results showed the effect of the tsunami on the buildings in the area. Fifty-eight point sixty-three percent of the buildings in the urban area were destroyed by the tsunami and constructions was raised to 103.60% and 197.12% between 2004 and 2010, thus indicating the recovery of the local community. Geomorphological change in Ko Kho Khao (the island) was found after the tsunami disaster, including coastal erosion and coastal deposition. The balance of nature played a major role in controlling the erosion and deposition. The coastal deposits were the highest in 2005; however, deposition was not found in 2004. The erosion rate from 2002-2003 was the highest (48.10 meter per year) and higher than 2003-2004 (39.03 meters per year), 2004-2009 (15.64 meters per year) and 2009-2010 (29.49 meters per year). The coastal area was more severe eroded than the estuary area, and severe coastal erosion caused the loss of coastal area, approximately 0.28 ha. Severe coastal erosion has been repeatedly found since 2005 in the lower part of the area, and hard structures such as concrete seawalls might have been affected by coastal erosion. In addition, extrapolation of coastal erosion at the rate of 30 meters per year showed that the lower part of Ko Kho Khao should disappear in 2015

Production of Copper as a Complex Mining and Metallurgical Processing System in Polish Copper Mines of the Legnica-Glogów Copper Belt

Science.gov (United States)

Malewski, Jerzy

2017-12-01

Geological and technological conditions of Cu production in the Polish copper mines of the Legnica-Glogów Copper Belt are presented. Cu production is recognized as a technological fractal consisting of subsystems for mineral exploration, ore extraction and processing, and metallurgical treatment. Qualitative and quantitative models of these operations have been proposed, including estimation of their costs of process production. Numerical calculations of such a system have been performed, which allow optimize the system parameters according to economic criteria under variable Cu mineralization in the ore deposit. The main objective of the study is to develop forecasting tool for analysis of production efficiency in domestic copper mines based on available sources of information. Such analyses are primarily of social value, allowing for assessment of the efficiency of management of local mineral resources in the light of current technological and market constraints. At the same time, this is a concept of the system analysis method to manage deposit exploitation on operational and strategic level.

Spatial Databases of Geological, Geophysical, and Mineral Resource Data Relevant to Sandstone-Hosted Copper Deposits in Central Kazakhstan

Science.gov (United States)

Syusyura, Boris; Box, Stephen E.; Wallis, John C.

2010-01-01

Central Kazakhstan is host to one of the world's giant sandstone-hosted copper deposits, the Dzhezkazgan deposit, and several similar, smaller deposits. The United Stated Geological Survey (USGS) is assessing the potential for other, undiscovered deposits of this type in the surrounding region of central Kazakhstan. As part of this effort, Syusyura compiled and partially translated an array of mostly unpublished geologic, geophysical, and mineral resource data for this region in digital format from the archives of the former Union of Soviet Socialists Republics (of which Kazakhstan was one of the member republics until its dissolution in 1991), as well as from later archives of the Republic of Kazakhstan or of the Kazakhstan consulting firm Mining Economic Consulting (MEC). These digital data are primarily map-based displays of information that were transmitted either in ESRI ArcGIS, georeferenced format, or non-georeferenced map image files. Box and Wallis reviewed all the data, translated Cyrillic text where necessary, inspected the maps for consistency, georeferenced the unprojected map images, and reorganized the data into the filename and folder structure of this publication.

Reaction and nucleation mechanisms of copper electrodeposition on disposable pencil graphite electrode

Energy Technology Data Exchange (ETDEWEB)

Majidi, M.R. [Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, 29th Bahman Bolvard, Tabriz 51664 (Iran, Islamic Republic of)], E-mail: sr.majidi@gmail.com; Asadpour-Zeynali, K.; Hafezi, B. [Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, 29th Bahman Bolvard, Tabriz 51664 (Iran, Islamic Republic of)

2009-01-01

The reaction and nucleation mechanism of copper electrodeposition on disposable pencil graphite electrode (PGE) in acidic sulphate solution were investigated using cyclic voltammetry (CV) and chronoamperometry (CA) techniques, respectively. Electrochemical experiments were followed by morphological studies with scanning electron microscopy (SEM). The effect of some experimental parameters, namely copper concentration, pH, scan rate, background electrolyte, deposition potential, and conditioning surface of the electrode were described. At the surface of PGE, Cu{sup 2+} ions were reduced at -250 mV vs. SCE. It was found that electrodeposition of copper is affected by rough surface of PGE. The nucleation mechanisms were examined by fitting the experimental CA data into Scharifker-Hills nucleation models. The nuclei population densities were also determined by means of two common fitting models developed for three-dimensional nucleation and growth (Scharifker-Mostany and Mirkin-Nilov-Herrman-Tarallo). It was found that deposition potential and background electrolyte affect the distribution of the deposited copper. The morphology of the deposited copper is affected by background electrolyte.

Electrodeposition of copper composites from deep eutectic solvents based on choline chloride.

Science.gov (United States)

Abbott, Andrew P; El Ttaib, Khalid; Frisch, Gero; McKenzie, Katy J; Ryder, Karl S

2009-06-07

Here we describe for the first time the electrolytic deposition of copper and copper composites from a solution of the metal chloride salt in either urea-choline chloride, or ethylene glycol-choline chloride based eutectics. We show that the deposition kinetics and thermodynamics are quite unlike those in aqueous solution under comparable conditions and that the copper ion complexation is also different. The mechanism of copper nucleation is studied using chronoamperometry and it is shown that progressive nucleation leads to a bright nano-structured deposit. In contrast, instantaneous nucleation, at lower concentrations of copper ions, leads to a dull deposit. This work also pioneers the use of the electrochemical quartz crystal microbalance (EQCM) to monitor both current efficiency and the inclusion of inert particulates into the copper coatings. This technique allows the first in situ quantification or particulate inclusion. It was found that the composition of composite material was strongly dependent on the amount of species suspended in solution. It was also shown that the majority of material was dragged onto the surface rather than settling on to it. The distribution of the composite material was found to be even throughout the coating. This technology is important because it facilitates deposition of bright copper coatings without co-ligands such as cyanide. The incorporation of micron-sized particulates into ionic liquids has resulted, in one case, in a decrease in viscosity. This observation is both unusual and surprising; we explain this here in terms of an increase in the free volume of the liquid and local solvent perturbation.

Plasma vapor deposited n-indium tin oxide/p-copper indium oxide heterojunctions for optoelectronic device applications

Science.gov (United States)

Jaya, T. P.; Pradyumnan, P. P.

2017-12-01

Transparent crystalline n-indium tin oxide/p-copper indium oxide diode structures were fabricated on quartz substrates by plasma vapor deposition using radio frequency (RF) magnetron sputtering. The p-n heterojunction diodes were highly transparent in the visible region and exhibited rectifying current-voltage (I-V) characteristics with a good ideality factor. The sputter power during fabrication of the p-layer was found to have a profound effect on I-V characteristics, and the diode with the p-type layer deposited at a maximum power of 200 W exhibited the highest value of the diode ideality factor (η value) of 2.162, which suggests its potential use in optoelectronic applications. The ratio of forward current to reverse current exceeded 80 within the range of applied voltages of -1.5 to +1.5 V in all cases. The diode structure possessed an optical transmission of 60-70% in the visible region.

The nature of hydrothermal fluids in the Kahang porphyry copper deposit (Northeast of Isfahan based on mineralography, fluid inclusion and stable isotopic data

Directory of Open Access Journals (Sweden)

Salimeh Sadat Komeili

2017-02-01

hypogene sulfide mineral and chalcopyrite is the predominant Cu- sulfide in the Kahang mineralized area. Primary magnetite grains having irregular boundaries formed in association with phyllic –potassic altered zones (Afshooni et al., 2014. Chalcocite and covellite as secondary copper minerals in the enriched supergene zone replaced the chalcopyrite. Thermometric studies on fluid inclusions conducted on quartz veins was related to the phyllic zone. Almost all studied fluid inclusions were homogenized to the liquid phase. Hydrothermal solutions with salinity over 26% wt equivalent NaCl, comparable with those of the other porphyry deposits (Morales Ruano et al., 2002; Hezarkhani, 2006; Hezarkhani, 2009 were responsible for the formation of the Kahang porphyry copper deposit. Homogenization temperatures of 200-450°C and 500-550°C were obtained from heating- cooling experiments on the two and multi phase fluid inclusions. The presence of gas riched fluid inclusions together with those of liquid riched and multiphase different salinities in the quartz veins as well as the occurrence of hydrothermal breccias are indicative of boiling fluids. Result In the Kahang porphyry Cu- deposit, the oxidation zone is characterized by hematite, goethite, jarosite, malachite, and azurite; the supergene zone is identified by chalcocite, chalcopyrite and coevllite; and chalcopyrite, pyrite and magnetite are the mineral assemblage of the hypogene zone. The volcanic as well as the plutonic rocks of the area have been hydrothermally altered which gave rise to the formation of propyllitic, intermediate argillic and mineralized phyllic zones. Fluid inclusion study on quartz veins revealed salinity over 26% wt equivalent NaCl and homogenization temperature of 200-450°C and 500-550°C. The presence of gas riched fluid inclusions together with those of liquid riched and multiphase different salinities in the quartz veins as well as the occurrence of hydrothermal breccias are indicative of boiling

Electro-deposition metallic tungsten coatings in a Na{sub 2}WO{sub 4}-WO{sub 3} melt on copper based alloy substrate

Energy Technology Data Exchange (ETDEWEB)

Liu, Y.H., E-mail: dreamerhong77@126.com [School of Materials Science and Engineering, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian District, Beijing 100083 (China); Zhang, Y.C.; Liu, Q.Z.; Li, X.L.; Jiang, F. [School of Materials Science and Engineering, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian District, Beijing 100083 (China)

2012-11-15

Highlights: Black-Right-Pointing-Pointer The tungsten coating (>1 mm) was obtained by electro-deposition method in molten salt. Black-Right-Pointing-Pointer Different thickness tungsten coatings were obtained by using different durations. Black-Right-Pointing-Pointer Good performance of coating was obtained when pulse parameters were modulated. - Abstract: The tungsten coating was prepared by electro-deposition technique on copper alloy substrate in a Na{sub 2}WO{sub 4}-WO{sub 3} melt. The coating's surface and cross-section morphologies as well as its impurities were investigated by XPS, SEM and line analysis. Various plating durations were investigated in order to obtain an optimal coating's thickness. The results demonstrated that the electro-deposited coating was compact, voidless, crackless and free from impurities. The tungsten coating's maximum Vickers hardness was measured to be 520 HV. The tungsten coating's minimum oxygen content was determined to be 0.018 wt%. Its maximum thickness was measured to be 1043.67 {mu}m when the duration of electrolysis was set to 100 h. The result of this study has demonstrated the feasibility of having thicker tungsten coatings on copper alloy substrates. These electrodeposited tungsten coatings can be potentially implemented as reliable armour for the medium heat flux plasma facing component (PFC).

Electro-remediation of copper mine tailings. Comparing copper removal efficiencies for two tailings of different age

DEFF Research Database (Denmark)

Hansen, Henrik K.; Lamas, Victor; Gutierrez, Claudia

2013-01-01

This work compares and evaluates the copper removal efficiency when applying electric fields to two mine tailings originating from the same mine but of different age. Eight experiments were carried out - four on tailings deposited more than 20 years ago (old tailings) and four on tailings deposit...

Landscape characteristics of Rhizophora mangle forests and propagule deposition in coastal environments of Florida (USA)

Science.gov (United States)

Sengupta, R.; Middleton, B.; Yan, C.; Zuro, M.; Hartman, H.

2005-01-01

Field dispersal studies are seldom conducted at regional scales even though reliable information on mid-range dispersal distance is essential for models of colonization. The purpose of this study was to examine the potential distance of dispersal of Rhizophora mangle propagules by comparing deposition density with landscape characteristics of mangrove forests. Propagule density was estimated at various distances to mangrove sources (R. mangle) on beaches in southwestern Florida in both high-and low-energy environments, either facing open gulf waters vs. sheltered, respectively. Remote sensing and Geographic Information Systems were used to identify source forests and to determine their landscape characteristics (forest size and distance to deposition area) for the regression analyses. Our results indicated that increasing density of propagules stranded on beaches was related negatively to the distance of the deposition sites from the nearest stands of R. mangle and that deposition was greatly diminished 2 km or more from the source. Measures of fragmentation such as the area of the R. mangle forests were related to propagule deposition but only in low-energy environments. Our results suggest that geographic models involving the colonization of coastal mangrove systems should include dispersal dynamics at mid-range scales, i.e., for our purposes here, beyond the local scale of the forest and up to 5 km distant. Studies of mangrove propagule deposition at various spatial scales are key to understanding regeneration limitations in natural gaps and restoration areas. Therefore, our study of mid-range propagule dispersal has broad application to plant ecology, restoration, and modeling. ?? Springer 2005.

Critical review: Copper runoff from outdoor copper surfaces at atmospheric conditions.

Science.gov (United States)

Hedberg, Yolanda S; Hedberg, Jonas F; Herting, Gunilla; Goidanich, Sara; Odnevall Wallinder, Inger

2014-01-01

This review on copper runoff dispersed from unsheltered naturally patinated copper used for roofing and facades summarizes and discusses influencing factors, available literature, and predictive models, and the importance of fate and speciation for environmental risk assessment. Copper runoff from outdoor surfaces is predominantly governed by electrochemical and chemical reactions and is highly dependent on given exposure conditions (size, inclination, geometry, degree of sheltering, and orientation), surface parameters (age, patina composition, and thickness), and site-specific environmental conditions (gaseous pollutants, chlorides, rainfall characteristics (amount, intensity, pH), wind direction, temperature, time of wetness, season). The corrosion rate cannot be used to assess the runoff rate. The extent of released copper varies largely between different rain events and is related to dry and wet periods, dry deposition prior to the rain event and prevailing rain and patina characteristics. Interpretation and use of copper runoff data for environmental risk assessment and management need therefore to consider site-specific factors and focus on average data of long-term studies (several years). Risk assessments require furthermore that changes in copper speciation, bioavailability aspects, and potential irreversible retention on solid surfaces are considered, factors that determine the environmental fate of copper runoff from outdoor surfaces.

Transpassive Dissolution of Copper and Rapid Formation of Brilliant Colored Copper Oxide Films

Science.gov (United States)

Fredj, Narjes; Burleigh, T. David; New Mexico Tech Team

2014-03-01

This investigation describes an electrochemical technique for growing adhesive copper oxide films on copper with attractive colors ranging from gold-brown to pearl with intermediate colors from red violet to gold green. The technique consists of anodically dissolving copper at transpassive potentials in hot sodium hydroxide, and then depositing brilliant color films of Cu2O onto the surface of copper after the anodic potential has been turned off. The color of the copper oxide film depends on the temperature, the anodic potential, the time t1 of polarization, and the time t2, which is the time of immersion after potential has been turned off. The brilliant colored films were characterized using glancing angle x-ray diffraction, and the film was found to be primarily Cu2O. Cyclic voltammetry, chronopotentiometry, scanning electron microscopy, and x-ray photoelectron spectroscopy were also used to characterize these films.

Exploration-systems approach to the Copper Mountain area uranium deposits, central Wyoming. National Uranium Resource Evaluation

International Nuclear Information System (INIS)

Sayala, D.; Lindgren, J.; Babcock, L.

1982-09-01

This report presents the results of multidisciplinary investigations of uranium deposits in the Copper Mountain District of central Wyoming. Although the studies on which the report is based began in 1977, work on the project has been discontinuous and was conducted partly by investigators no longer on the project. The project report represents an effort by the authors to compile and interpret the various data and to draw reasonable conclusions. Although an attempt is made to integrate, where possible, the results of different studies (or surveys), the report is organized into individual sections that present methods and results for each approach used. Investigations reported separately include geology, geochemistry, geophysics, and emanometry. These are aimed at characterizing and understanding the Copper Mountain uranium district and aiding in the detection of similar districts. A summary of overall project results, a comparison of the usefulness of individual approaches or combinations of approaches, and conclusions are presented in separate report sections for the project as a whole. All six sections in this report have been abstracted and indexed

Macro controlling of copper oxide deposition processes and spray mode by using home-made fully computerized spray pyrolysis system

Science.gov (United States)

Essa, Mohammed Sh.; Chiad, Bahaa T.; Shafeeq, Omer Sh.

2017-09-01

Thin Films of Copper Oxide (CuO) absorption layer have been deposited using home-made Fully Computerized Spray Pyrolysis Deposition system FCSPD on glass substrates, at the nozzle to substrate distance equal to 20,35 cm, and computerized spray mode (continues spray, macro-control spray). The substrate temperature has been kept at 450 °c with the optional user can enter temperature tolerance values ± 5 °C. Also that fixed molar concentration of 0.1 M, and 2D platform speed or deposition platform speed of 4mm/s. more than 1000 instruction program code, and specific design of graphical user interface GUI to fully control the deposition process and real-time monitoring and controlling the deposition temperature at every 200 ms. The changing in the temperature has been recorded during deposition processes, in addition to all deposition parameters. The films have been characterized to evaluate the thermal distribution over the X, Y movable hot plate, the structure and optical energy gap, thermal and temperature distribution exhibited a good and uniform distribution over 20 cm2 hot plate area, X-ray diffraction (XRD) measurement revealed that the films are polycrystalline in nature and can be assigned to monoclinic CuO structure. Optical band gap varies from 1.5-1.66 eV depending on deposition parameter.

Working and benefit project by the in-situ leaching of the copper-uranium ore of the deposit named Luz del Cobre, in the municipality of Soyopa, state of Sonora, Mexico

International Nuclear Information System (INIS)

Parga P, J.de J.

1976-01-01

This research was carried out with the object to recover the existing uranium in the copper-uranium deposit of Luz del Cobre located at 1300 Kms. approximately of the NW of Mexico City in the state of Sonora this deposit is geologically formed by a partially mineralized chimney which contains 572,732 tons of uranium ore with an average of 362.26g. of U 3 O 8 per ton, which represents 207,374 tons of U 3 O 8 in situ. To recover the uranium from this deposit, the only technical and economical possibility which presents a real interest is the system of leaching in situ. This operation will consist in the selective dissolution of the copper and uranium through leaching solution with a pH varying from 2.2 to 2.5, leaving the gangue on the ground and collecting the enriched solutions at the lower level of the mine, precipitating the copper subsequently through scrap iron and recovering the uranium from the tails of the copper precipitation plant through an ionic interchange process in counter current and its subsequent elution solvent extraction, reextraction and precipitation. This system makes possible to recover an uranium concentrate up to 98% of U 3 O 8 and practically free from impurities. The production cost would cost exceeding $300.00 Mexican currency per Kg of U 3 O 8 . (author)

Encapsulation of electroless copper patterns into diamond films

Energy Technology Data Exchange (ETDEWEB)

Pimenov, S.M.; Shafeev, G.A.; Lavrischev, S.V. [General Physics Institute, Moscow (Russian Federation)] [and others

1995-12-31

The results are reported on encapsulating copper lines into diamond films grown by a DC plasma CVD. The process includes the steps of (i) laser activation of diamond for electroless metal plating, (ii) electroless copper deposition selectively onto the activated surface regions, and (iii) diamond regrowth on the Cu-patterned diamond films. The composition and electrical properties of the encapsulated copper lines were examined, revealing high purity and low electrical resistivity of the encapsulated electroless copper.

CTS and CZTS for solar cells made by pulsed laser deposition and pulsed electron deposition

DEFF Research Database (Denmark)

Ettlinger, Rebecca Bolt

This thesis concerns the deposition of thin films for solar cells using pulsed laser deposition (PLD) and pulsed electron deposition (PED). The aim was to deposit copper tin sulfide (CTS) and zinc sulfide (ZnS) by pulsed laser deposition to learn about these materials in relation to copper zinc tin...... time. We compared the results of CZTS deposition by PLD at DTU in Denmark to CZTS made by PED at IMEM-CNR, where CIGS solar cells have successfully been fabricated at very low processing temperatures. The main results of this work were as follows: Monoclinic-phase CTS films were made by pulsed laser...... deposition followed by high temperature annealing. The films were used to understand the double band gap that we and other groups observed in the material. The Cu-content of the CTS films varied depending on the laser fluence (the laser energy per pulse and per area). The material transfer from...

Effects of copper concentration on electro-optical and structural properties of chemically deposited nanosized (Zn-Cd)S:Cu films

International Nuclear Information System (INIS)

Khare, Ayush

2010-01-01

Nanocrystalline (Zn-Cd)S films have been co-deposited on glass slide substrates by chemical bath deposition (CBD) technique at 70 deg. C for 75 min. Electroluminescent (EL), photoluminescent (PL) and structural characteristics of these films doped with Cu have been investigated. Cu doping has significant effects on the growth, structural and optical properties of the deposited (Zn-Cd)S films. EL studies show the essentiality of copper for EL emission. The effect of Cu concentration is examined on XRD, SEM, UV-vis spectroscopy, etc. The morphology of these films investigated with SEM and XRD is used to determine crystalline nature of the films. The optical absorption coefficient of the films has been found to increase with increase in Cu concentration. Voltage and frequency dependence shows the effectiveness of acceleration-collision mechanism. The trap-depth values are calculated from temperature dependence of EL brightness.

Influences of magnetic field on the fractal morphology in copper electrodeposition

Science.gov (United States)

Sudibyo; How, M. B.; Aziz, N.

2018-01-01

Copper magneto-electrodeposition (MED) is used decrease roughening in the copper electrodeposition process. This technology plays a vital role in electrodeposition process to synthesize metal alloy, thin film, multilayer, nanowires, multilayer nanowires, dot array and nano contacts. The effects of magnetic fields on copper electrodeposition are investigated in terms of variations in the magnetic field strength and the electrolyte concentration. Based on the experimental results, the mere presence of magnetic field would result in a compact deposit. As the magnetic field strength is increased, the deposit grows denser. The increment in concentration also leads to the increase the deposited size. The SEM image analysis showed that the magnetic field has a significant effect on the surface morphology of electrodeposits.

Dependency of the band gap of electrodeposited Copper oxide thin films on the concentration of copper sulfate (CuSO4.5H2O) and pH in bath solution for photovoltaic applications

KAUST Repository

Islam, Md. Anisul

2016-03-10

In this study, Copper oxide thin films were deposited on copper plate by electrodeposition process in an electrolytic bath containing CuSO4.5H2O, 3M lactic acid and NaOH. Copper oxide films were electrodeposited at different pH and different concentration of CuSO4.5H2O and the optical band gap was determined from their absorption spectrum which was obtained from UV-Vis absorption spectroscopy. It was found that copper oxide films which were deposited at low concentration of CuSO4.5H2O have higher band gap than those deposited at higher bath concentration. The band gap of copper oxide films also significantly changes with pH of the bath solution. It was also observed that with the increase of the pH of bath solution band gap of copper oxide film decreased. © 2015 IEEE.

Porphyry copper assessment of Europe, exclusive of the Fennoscandian Shield: Chapter K in Global mineral resource assessment

Science.gov (United States)

Sutphin, David M.; Hammarstrom, Jane M.; Drew, Lawrence J.; Large, Duncan E.; Berger, Byron R.; Dicken, Connie L.; DeMarr, Michael W.; with contributions from Billa, Mario; Briskey, Joseph A.; Cassard, Daniel; Lips, Andor; Pertold, Zdeněk; Roşu, Emilian

2013-01-01

The U.S. Geological Survey (USGS) collaborated with European geologists to assess resources in porphyry copper deposits in Europe, exclusive of Scandinavia (Sweden, Denmark, Norway, and Finland) and Russia. Porphyry copper deposits in Europe are Paleozoic and Late Cretaceous to Miocene in age. A number of the 31 known Phanerozoic deposits contain more than 1 million metric tons of contained copper, including the Majdanpek deposit, Serbia; Assarel, Bulgaria; Skouries, Greece; and Rosia Poeni, Romania. Five geographic areas were delineated as permissive tracts for post-Paleozoic porphyry copper deposits. Two additional tracts were delineated to show the extent of permissive igneous rocks associated with porphyry copper mineralization related to the Paleozoic Caledonian and Variscan orogenies. The tracts are based on mapped and inferred subsurface distributions of igneous rocks of specific age ranges that define areas where the occurrence of porphyry copper deposits within 1 kilometer of the Earth’s surface is possible. These tracts range in area from about 4,000 to 93,000 square kilometers. Although maps at a variety of different scales were used in the assessment, the final tract boundaries are intended for use at a scale of 1:1,000,000.

Simulation of the Dynamics of Isothermal Growth of Single-Layer Graphene on a Copper Catalyst in the Process of Chemical Vapor Deposition of Hydrocarbons

Science.gov (United States)

Futko, S. I.; Shulitskii, B. G.; Labunov, V. A.; Ermolaeva, E. M.

2018-01-01

A new kinetic model of isothermal growth of single-layer graphene on a copper catalyst as a result of the chemical vapor deposition of hydrocarbons on it at a low pressure has been developed on the basis of in situ measurements of the growth of graphene in the process of its synthesis. This model defines the synthesis of graphene with regard for the chemisorption and catalytic decomposition of ethylene on the surface of a copper catalyst, the diffusion of carbon atoms in the radial direction to the nucleation centers within the thin melted near-surface copper layer, and the nucleation and autocatalytic growth of graphene domains. It is shown that the time dependence of the rate of growth of a graphene domain has a characteristic asymmetrical bell-like shape. The dependences of the surface area and size of a graphene domain and the rate of its growth on the time at different synthesis temperatures and ethylene concentrations have been obtained. Time characteristics of the growth of graphene domains depending on the parameters of their synthesis were calculated. The results obtained can be used for determining optimum regimes of synthesis of graphene in the process of chemical vapor deposition of hydrocarbons on different catalysts with a low solubility of carbon.

Characterization and dating of coastal deposits of NW Portugal (Minho-Neiva area): A record of climate, eustasy and crustal uplift during the Quaternary

DEFF Research Database (Denmark)

Carvalhido, Ricardo P.; Pereira, Diamantino I.; Cunha, Pedro P.

2014-01-01

This study presents the characterization and numerical dating of Quaternary coastal deposits of NW Portugal, located between the mouths of the Minho and Neiva rivers. They record continental (small alluvial fans and streams) and transitional (aeolian dunes, interdune ponds, estuary, sandy...... and gravelly beaches) paleoenvironments. Quartz and K-feldspar optically stimulated luminescence (OSL) dating is employed as well as AMS C-14 dating. A staircase of coastal terraces (abrasion shore platforms) was identified (altimetry, a.s.l.) and ascribed to the following probable Marine Isotope Stages (MIS...

Cordão Formation: loess deposits in the southern coastal plain of the state of Rio Grande do Sul, Brazil

Directory of Open Access Journals (Sweden)

RENATO P. LOPES

Full Text Available ABSTRACT Loess consists of silt-dominated sediments that cover ~10% of the Earth's surface. In southern South America it occurs in Argentina, Bolivia, Paraguay and Uruguay, and its presence in southern Brazil was never studied in detail. Here is proposed a new lithostratigraphic unit, Cordão Formation, consisting of loess deposits in the southern Brazilian coastal plain. It consists of fine-very fine silt with subordinate sand and clay, found mostly in lowland areas between Pleistocene coastal barriers. These sediments are pale-colored (10YR hue and forms ~1,5-2,0 meter-thick stable vertical walls. The clay minerals include illite, smectite, interstratified illite/smectite and kaolinite, the coarser fraction is mostly quartz and plagioclase. Caliche and iron-manganese nodules are also present. The only fossils found so far are rodent teeth and a tooth of a camelid (Hemiauchenia paradoxa. Luminescence ages indicate that this loess was deposited in the latest Pleistocene, between ~30 and 10 kyrs ago, and its upper portion was modified by erosion and accumulation of clay and organic matter in the Holocene. The estimated accumulation rate was ~630 g/m2/year. The probable source of this loess is the Pampean Aeolian System of Argentina and it would have been deposited by the increased aeolian processes of the last glacial.

Determination of Mineralization Zones Using Interpretation of IP and RS Data in The GarmabCopper Deposit (South Khorasan province

Directory of Open Access Journals (Sweden)

Mansour Adelpour

2016-07-01

Full Text Available Introduction The Garmab copper deposit is located northeast of Qaen (South Khorasan province in the1:100,000 scale map of Abiz in the eastern tectonic zone of Iran. It is hosted by Late Paleocene-Eocene lava flows consisting mainly of andesite, trachy¬andesite, andesite-basalt and basalt lavas, as well as pyroclastic rocks, including tuffs and ignimbrites. The Lut Block has undergone intense magmatic activitywith a variety of geochemical characteristics due to changing tectonic conditions (e.g., compression during subduction followed by tensional conditions; Karimpour et al., 2012; Zarrinkoub et al., 2012. The Lut Block has a great potential for the discovery of new mineral deposits, like the Mahrabad and Khonik porphyry copper-gold deposits (Malekzadeh shafarodi, 2009, the Dehsalam porphyry copper deposit (Arjmandzadeh, 2011, high sulfidation epithermal gold deposits such as Chah Shalghami (Karimpour, 2005 and IOCG deposits such as Kuh-E-Zar and Qaleh Zari (Mazlomi et al., 2008. Materials and methods After field studies of the Garmab area, 32 thin sections and 21 polished sections were prepared for petrological and mineralogical studies.In addition, 10 least-altered and fractured samples of volcanic rocks were selected for geochemical studies. Major oxides were determined using XRF analyses at the Zarazma laboratory. Induced polarization and resistivity geophysical data were collected and correlated with geological and alteration maps. The geophysical datawere collectedfrom 420 individual points, using a dipole-dipole arrangement along five profiles separated 60m apart.This covered the study area entirely. After a change in the mineralization trend was observed,additional profileswere designed, twoon bearings of 25º and three on 75º. Results The Garmab volcanic rocks exhibit typical geochemical characteristics of subduction zone magmas including strong enrichment in LILE and depletion in HFSE. Based on the discrimination plot of Irvine and

Fabrication of Elemental Copper by Intense Pulsed Light Processing of a Copper Nitrate Hydroxide Ink.

Science.gov (United States)

Draper, Gabriel L; Dharmadasa, Ruvini; Staats, Meghan E; Lavery, Brandon W; Druffel, Thad

2015-08-05

Printed electronics and renewable energy technologies have shown a growing demand for scalable copper and copper precursor inks. An alternative copper precursor ink of copper nitrate hydroxide, Cu2(OH)3NO3, was aqueously synthesized under ambient conditions with copper nitrate and potassium hydroxide reagents. Films were deposited by screen-printing and subsequently processed with intense pulsed light. The Cu2(OH)3NO3 quickly transformed in less than 100 s using 40 (2 ms, 12.8 J cm(-2)) pulses into CuO. At higher energy densities, the sintering improved the bulk film quality. The direct formation of Cu from the Cu2(OH)3NO3 requires a reducing agent; therefore, fructose and glucose were added to the inks. Rather than oxidizing, the thermal decomposition of the sugars led to a reducing environment and direct conversion of the films into elemental copper. The chemical and physical transformations were studied with XRD, SEM, FTIR and UV-vis.

Electrochemical synthesis of highly crystalline copper nanowires

International Nuclear Information System (INIS)

Kaur, Amandeep; Gupta, Tanish; Kumar, Akshay; Kumar, Sanjeev; Singh, Karamjeet; Thakur, Anup

2015-01-01

Copper nanowires were fabricated within the pores of anodic alumina template (AAT) by template synthesis method at pH = 2.9. X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) were used to investigate the structure, morphology and composition of fabricated nanowires. These characterizations revealed that the deposited copper nanowires were highly crystalline in nature, dense and uniform. The crystalline copper nanowires are promising in application of future nanoelectronic devices and circuits

Electrodeposition and Properties of Copper Layer on NdFeB Device

Directory of Open Access Journals (Sweden)

LI Yue

2017-06-01

Full Text Available To decrease the impact of the regular Ni/Cu/Ni coating on the magnetic performance of sintered NdFeB device, alkaline system of HEDP complexing agent was applied to directly electro-deposit copper layer on NdFeB matrix, then nickel layer was electrodeposited on the copper layer and Cu/Ni coating was finally obtained to replace the regular Ni/Cu/Ni coating. The influence of concentration of HEDP complexing agent on deposition course was tested by electrochemical testing; morphology of copper layer was characterized by SEM, XRD and TEM; the binding force of copper layer and the thermal reduction of magnetic of NdFeB caused by electrodeposited coating were respectively explored through the thermal cycle test and thermal demagnetization test. The results show that the concentration of HEDP has great impact on the deposition overpotential of copper. In the initial electrodepositing stage, copper particles precipitate at the grain boundaries of NdFeB magnets with a preferred (111 orientation. The copper layer is compact and has enough binding force with the NdFeB matrix to meet the requirements in SJ 1282-1977. Furthermore, the thermal demagnetization loss rate of the sintered NdFeB with the protection of Cu/Ni coating is significantly less than that with the protection of Ni/Cu/Ni coating.

Oxidation-assisted graphene heteroepitaxy on copper foil.

Science.gov (United States)

Reckinger, Nicolas; Tang, Xiaohui; Joucken, Frédéric; Lajaunie, Luc; Arenal, Raul; Dubois, Emmanuel; Hackens, Benoît; Henrard, Luc; Colomer, Jean-François

2016-11-10

We propose an innovative, easy-to-implement approach to synthesize aligned large-area single-crystalline graphene flakes by chemical vapor deposition on copper foil. This method doubly takes advantage of residual oxygen present in the gas phase. First, by slightly oxidizing the copper surface, we induce grain boundary pinning in copper and, in consequence, the freezing of the thermal recrystallization process. Subsequent reduction of copper under hydrogen suddenly unlocks the delayed reconstruction, favoring the growth of centimeter-sized copper (111) grains through the mechanism of abnormal grain growth. Second, the oxidation of the copper surface also drastically reduces the nucleation density of graphene. This oxidation/reduction sequence leads to the synthesis of aligned millimeter-sized monolayer graphene domains in epitaxial registry with copper (111). The as-grown graphene flakes are demonstrated to be both single-crystalline and of high quality.

Petrography and Mineral Chemistry of Magmatic and Hydrothermal Biotite in Porphyry Copper-Gold Deposits: A Tool for Understanding Mineralizing Fluid Compositional Changes During Alteration Processes

OpenAIRE

Arifudin Idrus

2018-01-01

DOI: 10.17014/ijog.5.1.47-64This study aims to understand the petrography and chemistry of both magmatic and hydrothermal biotites in porphyry copper-gold deposits, and to evaluate the fluid compositional changes during alteration processes. A total of 206 biotite grains from selected rock samples taken from the Batu Hijau porphyry Cu-Au deposit was analyzed. Detailed petrography and biotite chemistry analysis were performed on thin sections and polished thin sections, respectively, represent...

Study of graphene growth on copper foil by pulsed laser deposition at reduced temperature

Science.gov (United States)

Abd Elhamid, Abd Elhamid M.; Hafez, Mohamed A.; Aboulfotouh, Abdelnaser M.; Azzouz, Iftitan M.

2017-01-01

Graphene has been successfully grown on commercial copper foil at low temperature of 500 °C by pulsed laser deposition (PLD). X-ray diffraction patterns showed that films have been grown in the presence of Cu(111) and Cu(200) facets. Raman spectroscopy was utilized to study the effects of temperature, surface structure, and cooling rate on the graphene growth. Raman spectra indicate that the synthesis of graphene layers rely on the surface quality of the Cu substrate together with the proper cooling profile coupled with graphene growth temperature. PLD-grown graphene film on Cu has been verified by transmission electron microscopy. Surface mediated growth of graphene on Cu foil substrate revealed to have a favorable catalytic effect. High growth rate of graphene and less defects can be derived using fast cooling rate.

Copper substrate as a catalyst for the oxidation of chemical vapor deposition-grown graphene

International Nuclear Information System (INIS)

Li, Zhiting; Zhou, Feng; Parobek, David; Shenoy, Ganesh J.; Muldoon, Patrick; Liu, Haitao

2015-01-01

We report the catalytic effect of copper substrate on graphene–oxygen reaction at high temperature. Previous studies showed that graphene grown on copper are mostly defect-free with strong oxidation resistance. We found that a freshly prepared copper-supported graphene sample can be completely oxidized in trace amount of oxygen (<3 ppm) at 600 °C within 2 h. Both X-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES) suggest that upon ambient air exposure, oxygen molecules diffuse into the space between graphene and copper, resulting in the formation of copper oxide which acts as catalytic sites for the graphene-oxygen reaction. This result has important implications for the characterization, processing, and storage of copper-supported graphene samples. - Graphical abstract: The copper substrate enhances the thermel oxidation of single-layer graphene. - Highlights: • A copper-supported graphene can be oxidized in Ar (O 2 <3 ppm, 600 °C, 2 h). • O 2 intercalates between graphene and copper upon exposure to air. • The copper foil should not be considered as an inert substrate

Molecular Models for DSMC Simulations of Metal Vapor Deposition

OpenAIRE

Venkattraman, A; Alexeenko, Alina A

2010-01-01

The direct simulation Monte Carlo (DSMC) method is applied here to model the electron‐beam (e‐beam) physical vapor deposition of copper thin films. A suitable molecular model for copper‐copper interactions have been determined based on comparisons with experiments for a 2D slit source. The model for atomic copper vapor is then used in axi‐symmetric DSMC simulations for analysis of a typical e‐beam metal deposition system with a cup crucible. The dimensional and non‐dimensional mass fluxes obt...

The role of oxygen in the deposition of copper–calcium thin film as diffusion barrier for copper metallization

Energy Technology Data Exchange (ETDEWEB)

Yu, Zhinong, E-mail: znyu@bit.edu.cn [School of Optoelectronics and Beijing Engineering Research Center of Mixed Reality and Advanced Display, Beijing Institute of Technology, Beijing 100081 (China); Ren, Ruihuang [School of Optoelectronics and Beijing Engineering Research Center of Mixed Reality and Advanced Display, Beijing Institute of Technology, Beijing 100081 (China); Xue, Jianshe; Yao, Qi; Li, Zhengliang; Hui, Guanbao [Beijing BOE Optoelectronics Technology Co., Ltd, Beijing 100176 (China); Xue, Wei [School of Optoelectronics and Beijing Engineering Research Center of Mixed Reality and Advanced Display, Beijing Institute of Technology, Beijing 100081 (China)

2015-02-15

Highlights: • The CuCa film as the diffusion barrier of Cu film improves the adhesion of Cu film. • The introduction of oxygen into the deposition of CuCa film is necessary to improve the adhesion of Cu film. • The CuCa alloy barrier layer deposited at oxygen atmosphere has perfect anti-diffusion between Cu film and substrate. - Abstract: The properties of copper (Cu) metallization based on copper–calcium (CuCa) diffusion barrier as a function of oxygen flux in the CuCa film deposition were investigated in view of adhesion, diffusion and electronic properties. The CuCa film as the diffusion barrier of Cu film improves the adhesion of Cu film, however, and increases the resistance of Cu film. The introduction of oxygen into the deposition of CuCa film induces the improvement of adhesion and crystallinity of Cu film, but produces a slight increase of resistance. The increased resistance results from the partial oxidation of Cu film. The annealing process in vacuum further improves the adhesion, crystallinity and conductivity of Cu film. X-ray diffraction (XRD) and Auger electron spectroscopy (AES) show that the CuCa alloy barrier layer deposited at oxygen atmosphere has perfect anti-diffusion between Cu film and substrate due to the formation of Ca oxide in the interface of CuCa/substrate.

Selective LPCVD growth of graphene on patterned copper and its growth mechanism

Science.gov (United States)

Zhang, M.; Huang, B.-C.; Wang, Y.; Woo, J. C. S.

2016-12-01

Copper-catalyzed graphene low-pressure chemical-vapor deposition (LPCVD) growth has been regarded as a viable solution towards its integration to CMOS technology, and the wafer-bonding method provides a reliable alternative for transferring the selective graphene grown on a patterned metal film for IC manufacturing. In this paper, selective LPCVD graphene growth using patterned copper dots has been studied. The Raman spectra of grown films have demonstrated large dependence on the growth conditions. To explain the results, the growth mechanisms based on surface adsorption and copper-vapor-assisted growth are investigated by the comparison between the blanket copper films with/without the additional copper source. The copper vapor density is found to be critical for high-quality graphene growth. In addition, the copper-vapor-assisted growth is also evidenced by the carbon deposition on the SiO2 substrate of the patterned-copper-dot sample and chamber wall during graphene growth. This growth mechanism explains the correlation between the growth condition and Raman spectrum for films on copper dots. The study on the copper-catalyzed selective graphene growth on the hard substrate paves the way for the synthesis and integration of the 2D material in VLSI.

Seasonal and air mass trajectory effects on dissolved organic matter of bulk deposition at a coastal town in south-western Europe.

Science.gov (United States)

Santos, Patrícia S M; Santos, Eduarda B H; Duarte, Armando C

2013-01-01

Rainwater contains a complex mixture of organic compounds which may influence climate, terrestrial and maritime ecosystems and thus human health. In this work, the characteristics of DOM of bulk deposition at a coastal town on the southwest of Europe were assessed by UV-visible and three-dimensional excitation-emission matrix fluorescence spectroscopies and by dissolved organic carbon (DOC) content. The seasonal and air mass trajectory effects on dissolved organic matter (DOM) of bulk deposition were evaluated. The absorbance at 250 nm (UV(250 nm)) and integrated fluorescence showed to be positively correlated with each other, and they were also positively correlated to the DOC in bulk deposition, which suggest that a constant fraction of DOM is likely to fluoresce. There was more chromophoric dissolved organic matter (CDOM) present in summer and autumn seasons than in winter and spring. Bulk deposition associated with terrestrial air masses contained a higher CDOM content than bulk deposition related to marine air masses, thus highlighting the contribution of terrestrial/anthropogenic sources.

Light Detection and Ranging (LiDAR and Multispectral Scanner (MSS Studies Examine Coastal Environments Influenced by Mining

Directory of Open Access Journals (Sweden)

W. Charles Kerfoot

2014-01-01

Full Text Available There are numerous examples of past and present mine disposal into freshwater and marine coastal bays and riverine environments. Due to its high spatial resolution and extended water penetration, coastal light detection and ranging (LiDAR, coupled with multispectral scanning (MSS, has great promise for resolving disturbed shoreline features in low turbidity environments. Migrating mine tailings present serious issues for Lake Superior and coastal marine environments. Previous investigations in Lake Superior uncovered a metal-rich “halo” around the Keweenaw Peninsula, related to past copper mining practices. For over a century, waste rock migrating from shoreline tailing piles has moved along extensive stretches of coastline, compromising critical fish breeding grounds, damming stream outlets, transgressing into wetlands and along recreational beaches and suppressing benthic invertebrate communities. In Grand (Big Traverse Bay, Buffalo Reef is an important spawning area for lake trout and whitefish threatened by drifting tailings. The movement of tailings into Buffalo Reef cobble fields may interfere with the hatching of fish eggs and fry survival, either by filling in crevices where eggs are deposited or by toxic effects on eggs, newly hatched larvae or benthic communities. Here, we show that the coastal tailing migration is not “out of sight, out of mind”, but clearly revealed by using a combination of LiDAR and MSS techniques.

Morphologies and wetting properties of copper film with 3D porous micro-nano hierarchical structure prepared by electrochemical deposition

International Nuclear Information System (INIS)

Wang, Hongbin; Wang, Ning; Hang, Tao; Li, Ming

2016-01-01

Highlights: • A 3D porous micro-nano hierarchical structure Cu films were prepared. • The evolution of morphology and wettability with deposition time was reported. • The effects of EDA on the microscopic morphology were revealed. • A high contact angle of 162.1° was measured when deposition time is 5 s. • The mechanism of super-hydrophobicity was illustrated by two classical models. - Abstract: Three-dimensional porous micro-nano hierarchical structure Cu films were prepared by electrochemical deposition with the Hydrogen bubble dynamic template. The morphologies of the deposited films characterized by Scanning Electronic Microscopy (SEM) exhibit a porous micro-nano hierarchical structure, which consists of three levels in different size scales, namely the honeycomb-like microstructure, the dendritic substructure and the nano particles. Besides, the factors which influenced the microscopic morphology were studied, including the deposition time and the additive Ethylene diamine. By measuring the water contact angle, the porous copper films were found to be super-hydrophobic. The maximum of the contact angles could reach as high as 162.1°. An empirical correlation between morphologies and wetting properties was revealed for the first time. The pore diameter increased simultaneously with the deposition time while the contact angle decreased. The mechanism was illustrated by two classical models. Such super-hydrophobic three-dimensional hierarchical micro-nano structure is expected to have practical application in industry.

Porphyry copper assessment of Southeast Asia and Melanesia: Chapter D in Global mineral resource assessment

Science.gov (United States)

Hammarstrom, Jane M.; Bookstrom, Arthur A.; Dicken, Connie L.; Drenth, Benjamin J.; Ludington, Steve; Robinson, Gilpin R.; Setiabudi, Bambang Tjahjono; Sukserm, Wudhikarn; Sunuhadi, Dwi Nugroho; Wah, Alexander Yan Sze; Zientek, Michael L.

2013-01-01

The U.S. Geological Survey collaborated with member countries of the Coordinating Committee for Geoscience Programmes in East and Southeast Asia (CCOP) on an assessment of the porphyry copper resources of Southeast Asia and Melanesia as part of a global mineral resource assessment. The region hosts world-class porphyry copper deposits and underexplored areas that are likely to contain undiscovered deposits. Examples of known porphyry copper deposits include Batu Hijau and Grasberg in Indonesia; Panguna, Frieda River, and Ok Tedi in Papua New Guinea; and Namosi in Fiji.

Copper thin film for RFID UHF antenna on flexible substrate

International Nuclear Information System (INIS)

Tran, Nhan Ai; Tran, Huy Nam; Dang, Mau Chien; Fribourg-Blanc, Eric

2010-01-01

A process flow using photolithography and sputtering was studied for copper antenna fabrication on thin poly(ethylene terephthalate) (PET) substrate. The lift-off route was chosen for its flexibility at laboratory scale. It was clarified that the cleaning of PET is an important step that necessitates mild oxygen plasma etching. Then copper is sputter deposited after photolithographic definition of the antenna. Care is necessary since PET, as a very flexible substrate, is temperature sensitive. The temperature increase generated by the impact of deposited copper should be maintained below the glass transition temperature of the polymer to avoid detrimental deformation. dc power of 40 to 50 W was found to be the maximum possible sputtering power for commercial PET. It was found that the resistivity of the thin film is below two times the bulk resistivity of copper for a deposition pressure below 4×10 −3  mbar and thickness above 450 nm. These results enable the reliable fabrication of copper RFID UHF antennae on a PET substrate for further testing of new tag designs. The present paper summarizes the effort to test new designs of antennae for RadioFrequency IDentification (RFID) Ultra High Frequency (UHF) tags, for use in various applications (e.g. object tracking and environment monitoring) in Vietnam

Evidence for extreme partitioning of copper into a magmatic vapor phase

International Nuclear Information System (INIS)

Lowenstern, J.B.; Mahood, G.A.; Rivers, M.L.; Sutton, S.R.

1991-01-01

The discovery of copper sulfides in carbon dioxide- and chlorine-bearing bubbles in phenocryst-hosted melt inclusions shows that copper resides in a vapor phase in some shallow magma chambers. Copper is several hundred times more concentrated in magmatic vapor than in coexisting pantellerite melt. The volatile behavior of copper should be considered when modeling the volcanogenic contribution of metals to the atmosphere and may be important in the formation of copper porphyry ore deposits

Low cost chemical oxygen demand sensor based on electrodeposited nano-copper film

Directory of Open Access Journals (Sweden)

Hamdy H. Hassan

2018-02-01

Full Text Available A commercially available copper electrical cable and pure Cu disk were used as substrates for the electrodeposition of copper nanoparticles (nano-Cu. The surface morphology of the prepared nano-Cu/Cu electrodes was investigated by scanning electron microscope (SEM and energy dispersive X-ray spectrometer (EDX. The bare copper substrates and the nano-copper modified electrodes were utilized and optimized for electrochemical assay of chemical oxygen demand (COD using glycine as a standard. A comparison was made among the four electrodes (i.e., bare and nano-Cu coated copper cable and pure copper disk as potential COD sensors. The oxidation behavior of glycine was investigated on the surface of the prepared sensors using linear sweep voltammetry (LSV. The results indicate significant enhancement of the electrochemical oxidation of glycine by the deposited nano-Cu. The effects of different deposition parameters, such as Cu2+ concentration, deposition potential, deposition time, pH, and scan rate on the response of the prepared sensors were investigated. Under optimized conditions, the optimal nano-Cu based COD sensor exhibited a linear range of 2–595 mg/L, lower limit of detection (LOD as low as 1.07 mg/L (S/N = 3. The developed method exhibited high tolerance level to Cl− ion where 1.0 M Cl− exhibited minimal influence. The sensor was utilized for the detection of COD in different real water samples. The results obtained were validated using the standard dichromate method.

Silane pre-treatments on copper and aluminium

International Nuclear Information System (INIS)

Deflorian, F.; Rossi, S.; Fedrizzi, L.

2006-01-01

A large part of aluminium products are coated with an organic layer in order to improve the corrosion resistance. Copper surfaces are also sometimes protected with an organic coating to improve the durability or the aesthetic properties. Examples of industrial applications are household appliances and heat exchanger components. For these applications it is not rare to have the industrial need to treat at the same time components made of aluminium and copper. In order to extend the service life of the organic coated copper a specific surface pre-treatment is often required. Nevertheless, probably because of the limited market of this application, no specific pre-treatments for copper are industrially developed, with the exception of cleaning procedures, but simply extensions of existing pre-treatments optimised for other metals (aluminium, zinc) are used. The application of silane pre-treatments as adhesion promoters for organic coated metals is remarkably increasing in the last decade, because silanes offer very good performance together with high environmental compatibility. The idea is therefore to try to develop a specific silane based pre-treatment for copper. The starting point is the existing silane products for aluminium, optimising the composition and the application conditions (concentration, temperature, pH of the bath, etc.) in order to develop a high performance copper alloy pre-treatment increasing the protective properties and the adhesion of a successively applied organic coating. Moreover these pre-treatments could be used for aluminium alloys too and therefore could be suggested for multi-metals components. The deposits were analysed using FTIR spectroscopy and optical and electron microscopic observations. A careful electrochemical characterisation, mainly by electrochemical impedance spectroscopy measurements (EIS) was carried out to highlight the presence of silane and to evaluate the performance of the different deposits. In order to study an

USING FOURIER TRANSFORM INFRARED (FTIR TO CHARACTERIZE TSUNAMI DEPOSITS IN NEAR-SHORE AND COASTAL WATERS OF THAILAND

Directory of Open Access Journals (Sweden)

S. Pongpiachan

2013-01-01

Full Text Available Understanding the tsunami cycle requires a simple method for identification of tsunami backwash deposits. This study investigates Fourier transform infrared (FTIR spectroscopy followed by careful analysis of variance (ANOVA, Gaussian distribution, hierarchical cluster analysis (HCA and principal component analysis (PCA for the discrimination of typical marine sediments and tsunami backwash deposits. In order to test the suitability of FTIR spectra as innovative methods for classifications of tsunami deposits, typical marine sediments and terrestrial soils were classified into three zones, namely zone-1 (i.e. typical marine sediments, zone-2 (i.e. including tsunami backwash deposits and zone-3 (i.e. coastal terrestrial soils. HCA was performed to group the spectra according to their spectral similarity in a dendrogram and successfully separate FTIR spectra of all three sampling zones into two main clusters with five sub-clusters. The simplicifolious (i.e. single-leafed type of dendrogram was observed with the strong dissimilarity of terrestrial components in subcluster- 5. Graphical displays of PC1 vs PC2 highlight the prominent features of zone-1, which is explicitly different from those of zone-2 and zone-3. The acceptable discrimination of typical marine sediments and tsunami backwash deposits, even six years after the tsunami on Boxing Day 2004, dramatically demonstrates the potential of the method for the identification of paleotsunami.

Characterisation of the Ionian-Lucanian coastal plain aquifer

OpenAIRE

Polemio, M.; Limoni, P.P.; Mitolo, D.; Santaloia, F.

2002-01-01

This paper deals with a Southern Italy area, 40 km by 10 km wide, located where four river valleys anastomose themselves in the coastal plain. The geological and hydrogeological features of the study area and the chemical-physical groundwater characterisation have been inferred from the data analysis of 1130 boreholes. Some aquifers, connected among them, constituted by soils of different geological origin -marine terraces deposits, river valley alluvial deposits and alluvial and coastal depo...

Method for providing uranium with a protective copper coating

Science.gov (United States)

Waldrop, Forrest B.; Jones, Edward

1981-01-01

The present invention is directed to a method for providing uranium metal with a protective coating of copper. Uranium metal is subjected to a conventional cleaning operation wherein oxides and other surface contaminants are removed, followed by etching and pickling operations. The copper coating is provided by first electrodepositing a thin and relatively porous flash layer of copper on the uranium in a copper cyanide bath. The resulting copper-layered article is then heated in an air or inert atmosphere to volatilize and drive off the volatile material underlying the copper flash layer. After the heating step an adherent and essentially non-porous layer of copper is electro-deposited on the flash layer of copper to provide an adherent, multi-layer copper coating which is essentially impervious to corrosion by most gases.

Effect of humic acid on the underpotential deposition-stripping voltammetry of copper in acetic acid soil extract solutions at mercaptoacetic acid-modified gold electrodes

Energy Technology Data Exchange (ETDEWEB)

Herzog, Gregoire; Beni, Valerio; Dillon, Patrick H.; Barry, Thomas; Arrigan, Damien W.M

2004-05-24

Electrochemical measurements were undertaken for the investigation of the underpotential deposition-stripping process of copper at bare and modified gold electrodes in 0.11 M acetic acid, the first fraction of the European Union's Bureau Communautaire de References (BCR) sequential extraction procedure for fractionating metals within soils and sediments. Gold electrodes modified with mercaptoacetic acid showed higher sensitivity for the detection of copper than bare gold electrodes, both in the absence and in the presence of humic acid in acetic acid solutions, using the underpotential deposition-stripping voltammetry (UPD-SV) method. In the presence of 50 mg l{sup -1} of humic acid, the mercaptoacetic acid modified electrode proved to be 1.5 times more sensitive than the bare gold electrode. The mercaptoacetic acid monolayer formed on the gold surface provided efficient protection against the adsorption of humic acid onto the gold electrode surface. Variation of the humic acid concentration in the solution showed little effect on the copper stripping signal at the modified electrode. UPD-SV at the modified electrode was applied to the analysis of soil extract samples. Linear correlation of the electrochemical results with atomic spectroscopic results yielded the straight-line equation y ({mu}g l{sup -1}) = 1.10x - 44 (ppb) (R=0.992, n=6), indicating good agreement between the two methods.

Study of copper fluorination

International Nuclear Information System (INIS)

Gillardeau, J.

1967-02-01

This report deals with the action of fluorine on copper. Comprehensive descriptions are given of the particular technological methods and of the preparation of the reactants. This fluorination reaction has been studied at medium and low fluorine pressures. A nucleation and growth phenomenon is described. The influence of a pollution of the gas phase on the fluorination process is described. The solid-state reaction between cupric fluoride and cooper has also been studied. A special study has been made of the growth of copper deposits by thermal decomposition of gaseous fluorides. (author) [fr

XPS studies of short pulse laser interaction with copper

International Nuclear Information System (INIS)

Stefanov, P.; Minkovski, N.; Balchev, I.; Avramova, I.; Sabotinov, N.; Marinova, Ts.

2006-01-01

The effect of laser ablation on copper foil irradiated by a short 30 ns laser pulse was investigated by X-ray photoelectron spectroscopy. The laser fluence was varied from 8 to 16.5 J/cm 2 and the velocity of the laser beam from 10 to 100 mm/s. This range of laser fluence is characterized by a different intensity of laser ablation. The experiments were done in two kinds of ambient atmosphere: air and argon jet gas. The chemical state and composition of the irradiated copper surface were determined using the modified Auger parameter (α') and O/Cu intensity ratio. The ablation atmosphere was found to influence the size and chemical state of the copper particles deposited from the vapor plume. During irradiation in air atmosphere the copper nanoparticles react with oxygen and water vapor from the air and are deposited in the form of a CuO and Cu(OH) 2 thin film. In argon atmosphere the processed copper surface is oxidized after exposure to air

Bulk Copper Electrodeposition on Gold Imaged by In Situ STM

DEFF Research Database (Denmark)

Andersen, Jens Enevold Thaulov; Bech-Nielsen, Gregers; Møller, Per

1996-01-01

Electrochemical measurements were carried out simultaneously with acquisition of in situ STM images of copper electrodeposition at low cathodic overpotentials and subsequent dissolution from the underlying polycrystalline gold surfaces. The morphologies of the copper deposits were examined...

Atmospheric pollution with copper around the copper mine and flotation, 'Buchim', Republic of Macedonia, using biomonitoring moss and lichen technique

International Nuclear Information System (INIS)

Balabanova, Biljana; Bacheva, Katerina; Shajn, Robert; Stafilov, Trajche

2009-01-01

This paper has studied the atmospheric pollution with copper due to copper mining and flotation 'Buchim' near Radovish, Republic of Macedonia. The copper ore and ore tailings continually are exposed to open air, which occur winds carry out the fine particles in to atmosphere. Moss (Hyloconium splendens and Pleurozium schrebery) and lichen (Hypogymnia physodes and Parmelia sulcata) samples were used for biomonitoring the possible atmospheric pollution with copper in the mine vicinity. Moss and lichen samples were digested by using of microwave digestion system and copper was analyzed by atomic emission spectrometry with inductively coupled plasma (ICPAES). The obtained values for the content of copper in moss and lichen samples were statistically processed using the nonparametric and parametric analysis. Maps of areal deposition of copper show an increase content of copper in the vicinity of mine, but long distance distribution of this element is not established yet.

Brake wear from vehicles as an important source of diffuse copper pollution

NARCIS (Netherlands)

Hulskotte, J.H.J.; Gon, H.A.C.D. van der; Visschedijk, A.J.H.; Schaap, M.

2007-01-01

In this article we show that brake wear from road traffic vehicles is an important source of atmospheric (participate) copper concentrations in Europe. Consequently, brake wear also contributes significantly to deposition fluxes of copper to surface waters. We estimated the copper emission due to

Dissolved organic and inorganic matter in bulk deposition of a coastal urban area: an integrated approach.

Science.gov (United States)

Santos, Patrícia S M; Santos, Eduarda B H; Duarte, Armando C

2014-12-01

Bulk deposition can remove atmospheric organic and inorganic pollutants that may be associated with gaseous, liquid or particulate phases. To the best of our knowledge, few studies have been carried out, which simultaneously analyse the presence of organic and inorganic fractions in rainwater. In the present work, the complementarity of organic and inorganic data was assessed, through crossing data of some organic [DOC (dissolved organic carbon), absorbance at 250 nm (UV250nm), integrated fluorescence] and inorganic [H(+), NH4(+), NO3(-), non sea salt sulphate (NSS-SO4(2-))] parameters measured in bulk deposition in the coastal urban area of Aveiro. The organic and inorganic parameters analysed were positively correlated (pCDOM) came from anthropogenic sources. Furthermore, the inverse correlations observed for the organic and inorganic parameters with the precipitation amount suggest that organic and inorganic fractions were incorporated into the rainwater partially by below-cloud scavenging of airborne particulate matter. This is in accordance with the high values of DOC and NO3(-) found in samples associated with marine air masses, which were linked in part to the contribution of local emissions from vehicular traffic. DOC of bulk deposition was the predominant constituent when compared with the constituents H(+), NH4(+), NO3(-) and NSS-SO4(2-), and consequently bulk deposition flux was also highest for DOC, highlighting the importance of DOC and of anthropogenic ions being simultaneously removed from the atmosphere by bulk deposition. However, it was verified that the contribution of anthropogenic sources to the DOC of bulk deposition may be different for distinct urban areas. Thus, it is recommended that organic and inorganic fractions of bulk deposition are studied together. Copyright © 2014. Published by Elsevier Ltd.

Bottom-Up Electrodeposition of Large-Scale Nanotwinned Copper within 3D Through Silicon Via.

Science.gov (United States)

Sun, Fu-Long; Liu, Zhi-Quan; Li, Cai-Fu; Zhu, Qing-Sheng; Zhang, Hao; Suganuma, Katsuaki

2018-02-23

This paper is the first to report a large-scale directcurrent electrodeposition of columnar nanotwinned copper within through silicon via (TSV) with a high aspect ratio (~4). With this newly developed technique, void-free nanotwinned copper array could be fabricated in low current density (30 mA/cm²) and convection conditions (300 rpm), which are the preconditions for copper deposition with a uniform deep-hole microstructure. The microstructure of a whole cross-section of deposited copper array was made up of (111) orientated columnar grains with parallel nanoscale twins that had thicknesses of about 22 nm. The hardness was also uniform along the growth direction, with 2.34 and 2.68 GPa for the top and bottom of the TSV, respectively. The gelatin additive is also first reported hereas a key factor in forming nanoscale twins by adsorbing on the cathode surface, in order to enhance the overpotential for cathodic reaction during the copper deposition process.

Bottom–Up Electrodeposition of Large-Scale Nanotwinned Copper within 3D Through Silicon Via

Science.gov (United States)

Sun, Fu-Long; Li, Cai-Fu; Zhu, Qing-Sheng; Zhang, Hao; Suganuma, Katsuaki

2018-01-01

This paper is the first to report a large-scale directcurrent electrodeposition of columnar nanotwinned copper within through silicon via (TSV) with a high aspect ratio (~4). With this newly developed technique, void-free nanotwinned copper array could be fabricated in low current density (30 mA/cm2) and convection conditions (300 rpm), which are the preconditions for copper deposition with a uniform deep-hole microstructure. The microstructure of a whole cross-section of deposited copper array was made up of (111) orientated columnar grains with parallel nanoscale twins that had thicknesses of about 22 nm. The hardness was also uniform along the growth direction, with 2.34 and 2.68 GPa for the top and bottom of the TSV, respectively. The gelatin additive is also first reported hereas a key factor in forming nanoscale twins by adsorbing on the cathode surface, in order to enhance the overpotential for cathodic reaction during the copper deposition process. PMID:29473865

Bottom–Up Electrodeposition of Large-Scale Nanotwinned Copper within 3D Through Silicon Via

Directory of Open Access Journals (Sweden)

Fu-Long Sun

2018-02-01

Full Text Available This paper is the first to report a large-scale directcurrent electrodeposition of columnar nanotwinned copper within through silicon via (TSV with a high aspect ratio (~4. With this newly developed technique, void-free nanotwinned copper array could be fabricated in low current density (30 mA/cm2 and convection conditions (300 rpm, which are the preconditions for copper deposition with a uniform deep-hole microstructure. The microstructure of a whole cross-section of deposited copper array was made up of (111 orientated columnar grains with parallel nanoscale twins that had thicknesses of about 22 nm. The hardness was also uniform along the growth direction, with 2.34 and 2.68 GPa for the top and bottom of the TSV, respectively. The gelatin additive is also first reported hereas a key factor in forming nanoscale twins by adsorbing on the cathode surface, in order to enhance the overpotential for cathodic reaction during the copper deposition process.

Physical and chemical properties of deposited airborne particulates over the Arabian Red Sea coastal plain

Science.gov (United States)

Engelbrecht, Johann P.; Stenchikov, Georgiy; Jish Prakash, P.; Lersch, Traci; Anisimov, Anatolii; Shevchenko, Illia

2017-09-01

Mineral dust is the most abundant aerosol, having a profound impact on the global energy budget. This research continues our previous studies performed on surface soils in the Arabian Peninsula, focusing on the mineralogical, physical and chemical composition of dust deposits from the atmosphere at the Arabian Red Sea coast. For this purpose, aerosols deposited from the atmosphere are collected during 2015 at six sites on the campus of the King Abdullah University of Science and Technology (KAUST) situated on the Red Sea coastal plain of Saudi Arabia and subjected to the same chemical and mineralogical analysis we conducted on soil samples. Frisbee deposition samplers with foam inserts were used to collect dust and other deposits, for the period December 2014 to December 2015. The average deposition rate measured at KAUST for this period was 14 g m-2 per month, with lowest values in winter and increased deposition rates in August to October. The particle size distributions provide assessments of particle size fractions in the dust deposits.X-ray diffraction (XRD) analysis of a subset of samples confirms variable amounts of quartz, feldspars, micas, and halite, with lesser amounts of gypsum, calcite, dolomite, hematite, and amphibole. Freeze-dried samples were re-suspended onto the Teflon® filters for elemental analysis by X-ray fluorescence (XRF), while splits from each sample were analyzed for water-soluble cations and anions by ion chromatography. The dust deposits along the Red Sea coast are considered to be a mixture of dust emissions from local soils and soils imported from distal dust sources. Airborne mineral concentrations are greatest at or close to dust sources, compared to those through medium- and long-range transport. It is not possible to identify the exact origin of deposition samples from the mineralogical and chemical results alone. These aerosol data are the first of their kind from the Red Sea region. They will help assess their potential

Arc-related porphyry molybdenum deposit model: Chapter D in Mineral deposit models for resource assessment

Science.gov (United States)

Taylor, Ryan D.; Hammarstrom, Jane M.; Piatak, Nadine M.; Seal, Robert R.

2012-01-01

This report provides a descriptive model for arc-related porphyry molybdenum deposits. Presented within are geological, geochemical, and mineralogical characteristics that differentiate this deposit type from porphyry copper and alkali-feldspar rhyolite-granite porphyry molybdenum deposits. The U.S. Geological Survey's effort to update existing mineral deposit models spurred this research, which is intended to supplement previously published models for this deposit type that help guide mineral-resource and mineral-environmental assessments.

COMPARING INDEPENDENT COMPONENT ANALYSIS WITH PRINCIPLE COMPONENT ANALYSIS IN DETECTING ALTERATIONS OF PORPHYRY COPPER DEPOSIT (CASE STUDY: ARDESTAN AREA, CENTRAL IRAN

Directory of Open Access Journals (Sweden)

S. Mahmoudishadi

2017-09-01

Full Text Available The image processing techniques in transform domain are employed as analysis tools for enhancing the detection of mineral deposits. The process of decomposing the image into important components increases the probability of mineral extraction. In this study, the performance of Principal Component Analysis (PCA and Independent Component Analysis (ICA has been evaluated for the visible and near-infrared (VNIR and Shortwave infrared (SWIR subsystems of ASTER data. Ardestan is located in part of Central Iranian Volcanic Belt that hosts many well-known porphyry copper deposits. This research investigated the propylitic and argillic alteration zones and outer mineralogy zone in part of Ardestan region. The two mentioned approaches were applied to discriminate alteration zones from igneous bedrock using the major absorption of indicator minerals from alteration and mineralogy zones in spectral rang of ASTER bands. Specialized PC components (PC2, PC3 and PC6 were used to identify pyrite and argillic and propylitic zones that distinguish from igneous bedrock in RGB color composite image. Due to the eigenvalues, the components 2, 3 and 6 account for 4.26% ,0.9% and 0.09% of the total variance of the data for Ardestan scene, respectively. For the purpose of discriminating the alteration and mineralogy zones of porphyry copper deposit from bedrocks, those mentioned percentages of data in ICA independent components of IC2, IC3 and IC6 are more accurately separated than noisy bands of PCA. The results of ICA method conform to location of lithological units of Ardestan region, as well.

Comparing Independent Component Analysis with Principle Component Analysis in Detecting Alterations of Porphyry Copper Deposit (case Study: Ardestan Area, Central Iran)

Science.gov (United States)

Mahmoudishadi, S.; Malian, A.; Hosseinali, F.

2017-09-01

The image processing techniques in transform domain are employed as analysis tools for enhancing the detection of mineral deposits. The process of decomposing the image into important components increases the probability of mineral extraction. In this study, the performance of Principal Component Analysis (PCA) and Independent Component Analysis (ICA) has been evaluated for the visible and near-infrared (VNIR) and Shortwave infrared (SWIR) subsystems of ASTER data. Ardestan is located in part of Central Iranian Volcanic Belt that hosts many well-known porphyry copper deposits. This research investigated the propylitic and argillic alteration zones and outer mineralogy zone in part of Ardestan region. The two mentioned approaches were applied to discriminate alteration zones from igneous bedrock using the major absorption of indicator minerals from alteration and mineralogy zones in spectral rang of ASTER bands. Specialized PC components (PC2, PC3 and PC6) were used to identify pyrite and argillic and propylitic zones that distinguish from igneous bedrock in RGB color composite image. Due to the eigenvalues, the components 2, 3 and 6 account for 4.26% ,0.9% and 0.09% of the total variance of the data for Ardestan scene, respectively. For the purpose of discriminating the alteration and mineralogy zones of porphyry copper deposit from bedrocks, those mentioned percentages of data in ICA independent components of IC2, IC3 and IC6 are more accurately separated than noisy bands of PCA. The results of ICA method conform to location of lithological units of Ardestan region, as well.

Experimental Evaluation of Cold-Sprayed Copper Rotating Bands for Large-Caliber Projectiles

Science.gov (United States)

2015-05-01

process parameters used during the initial deposition of copper material, given the observation that these initial copper rotating bands tended to “ flake ...ARL-TR-7299 ● MAY 2015 US Army Research Laboratory Experimental Evaluation of Cold-Sprayed Copper Rotating Bands for Large...Experimental Evaluation of Cold-Sprayed Copper Rotating Bands for Large-Caliber Projectiles by Michael A Minnicino Weapons and Materials Research

MEAD Marine Effects of Atmospheric Deposition

Science.gov (United States)

Jickells, T.; Spokes, L.

2003-04-01

The coastal seas are one of the most valuable resources on the planet but they are threatened by human activity. We rely on the coastal area for mineral resources, waste disposal, fisheries and recreation. In Europe, high population densities and high levels of industrial activity mean that the pressures arising from these activities are particularly acute. One of the main problems concerning coastal seas is the rapid increase in the amounts of nitrogen-based pollutants entering the water. They come from many sources, the most important ones being traffic, industry and agriculture. These pollutants can be used by algae as nutrients. The increasing concentrations of these nutrients have led to excessive growth of algae, some of which are harmful. When algae die and decay, oxygen in the water is used up and the resulting lower levels of oxygen may lead to fish kills. Human activity has probably doubled the amount of chemically and biologically reactive nitrogen present globally. In Europe the increases have been greater than this, leading to real concern over the health of coastal waters. Rivers have, until recently, been thought to be the most important source of reactive nitrogen to the coastal seas but we now know that inputs from the atmosphere are large and can equal, or exceed, those from the rivers. Our initial hypothesis was that atmospheric inputs are important and potentially different in their effect on coastal ecosystems to riverine inputs and hence require different management strategies. However, we had almost no information on the direct effects of atmospheric deposition on marine ecosystems, though clearly such a large external nitrogen input should lead to enhanced phytoplankton growth The aim of this European Union funded MEAD project has been to determine how inputs of nitrogen from the atmosphere affect the chemistry and biology of coastal waters. To try to answer this, we have conducted field experiments in the Kattegat, an area where we know

Bioaccumulation, toxicokinetics, and effects of copper from sediment spiked with aqueous Cu, nano-CuO, or micro-CuO in the deposit-feeding snail, Potamopyrgus antipodarum

DEFF Research Database (Denmark)

Pang, Chengfang; Selck, Henriette; Banta, Gary Thomas

2013-01-01

The present study examined the relative importance of copper (aqueous Cu and CuO particles of different sizes) added to sediment to determine the bioaccumulation, toxicokinetics, and effects in the deposit feeder Potamopyrgus antipodarum. In experiment 1, the bioaccumulation of Cu (240 mg Cu/g dr...

Physical and chemical properties of deposited airborne particulates over the Arabian Red Sea coastal plain

KAUST Repository

Engelbrecht, Johann

2017-09-27

Mineral dust is the most abundant aerosol, having a profound impact on the global energy budget. This research continues our previous studies performed on surface soils in the Arabian Peninsula, focusing on the mineralogical, physical and chemical composition of dust deposits from the atmosphere at the Arabian Red Sea coast. For this purpose, aerosols deposited from the atmosphere are collected during 2015 at six sites on the campus of the King Abdullah University of Science and Technology (KAUST) situated on the Red Sea coastal plain of Saudi Arabia and subjected to the same chemical and mineralogical analysis we conducted on soil samples. Frisbee deposition samplers with foam inserts were used to collect dust and other deposits, for the period December 2014 to December 2015. The average deposition rate measured at KAUST for this period was 14 g m−2 per month, with lowest values in winter and increased deposition rates in August to October. The particle size distributions provide assessments of  < 10 and  < 2.5 µm dust deposition rates, and it is suggested that these represent proxies for PM10 (coarse) and PM2. 5 (fine) particle size fractions in the dust deposits. X-ray diffraction (XRD) analysis of a subset of samples confirms variable amounts of quartz, feldspars, micas, and halite, with lesser amounts of gypsum, calcite, dolomite, hematite, and amphibole. Freeze-dried samples were re-suspended onto the Teflon® filters for elemental analysis by X-ray fluorescence (XRF), while splits from each sample were analyzed for water-soluble cations and anions by ion chromatography. The dust deposits along the Red Sea coast are considered to be a mixture of dust emissions from local soils and soils imported from distal dust sources. Airborne mineral concentrations are greatest at or close to dust sources, compared to those through medium- and long-range transport. It is not possible to identify the exact origin of deposition samples from the

Genesis of copper-lead mineralization in the regionally zoned Agnigundala Sulfide Belt, Cuddapah Basin, Andhra Pradesh, India

Science.gov (United States)

Bhattacharya, H. N.; Bandyopadhyay, Sandip

2018-03-01

Shallow marine sandstone-shale-carbonate sedimentary rocks of the Paleoproterozoic northern Cuddapah basin host copper (Nallakonda deposit), copper-lead (Dhukonda deposit), and lead mineralization (Bandalamottu deposit) which together constitute the Agnigundala Sulfide Belt. The Cu sulfide mineralization in sandstone is both stratabound and disseminated, and Pb sulfide mineralization occurs as stratabound fracture filling veins and/or replacement veins within dolomite. Systematic mineralogical and sulfur, carbon, and oxygen isotope studies of the three deposits indicate a common ore-fluid that deposited copper at Nallakonda, copper-lead at Dhukonda, and lead at Bandalamottu under progressive cooling during migration through sediments. The ore-fluid was of low temperature (water sulfate produced sulfide for ore deposition. It is envisaged that basal red-bed and evaporite-bearing rift-related continental to shallow marine sediments might have acted as the source for the metals. Rift-related faults developed during sedimentation in the basin might have punctured the ore-fluid pool in the lower sedimentary succession and also acted as conduits for their upward migration. The ore-bearing horizons have participated in deformations during basin inversion without any recognizable remobilization.

The Sanfengshan copper deposit and early Carboniferous volcanogenic massive sulfide mineralization in the Beishan orogenic belt, Northwestern China

Science.gov (United States)

Wang, Jialin; Gu, Xuexiang; Zhang, Yongmei; Zhou, Chao; He, Ge; Liu, Ruiping

2018-03-01

The Sanfengshan copper deposit, located in the Beishan orogenic belt, Northwestern China, is hosted in the lower member of the Hongliuyuan Formation, an early Carboniferous metavolcanic-sedimentary sequence. Mineralization occurs as stratiform, stratiform-like and lenticular orebodies, and comprises of laminated, brecciated, banded, massive, and disseminated ores. The mineralogy is dominated by pyrite, chalcopyrite and sphalerite. Fe-Mn chert is widely distributed and generally occurs as massive, laminated, bands or lenses, which are consistent with the orebody. Alteration at Sanfengshan displays a clear concentric zoning pattern and the footwall alteration is more intense and somewhat thicker than the hanging-wall alteration. Systematic geochemical investigation on the volcanic rocks in this area shows that the basalts of the Hongliuyuan Formation (HLY) are predominantly tholeiites with nearly flat rare earth element (REE) pattern, insignificant negative anomalies of high field strength elements (HFSEs), and low Ti/V and Th/Nb ratios. They were most likely derived from partial melting of depleted asthenospheric mantle and formed in a fore-arc setting during initiation of the southward subduction of the Paleo-Asian Ocean. The basalts of the Maotoushan Formation (MTS) display a calc-alkaline nature and are enriched in large ion lithophile elements (LILEs) and depleted in HFSEs, suggesting an active continental margin setting. Sulfur isotope (δ34S) values of the sulfide and sulfate minerals vary between 0‰ and 5.4‰, which are consistent with sulfur derivation from leaching of the host volcanic rocks, although a direct magmatic contribution cannot be ruled out. The Re-Os isotope data of pyrite yield an isochron age of 353 ± 35 Ma, consistent with the age of the host HLY basalts. Thus, a syngenetic (volcanogenic massive sulfide) model is proposed and it is concluded that the Sanfengshan copper deposit is a typical Cyprus-type VMS deposit that formed in an early

Methods of making copper selenium precursor compositions with a targeted copper selenide content and precursor compositions and thin films resulting therefrom

Science.gov (United States)

Curtis, Calvin J [Lakewood, CO; Miedaner, Alexander [Boulder, CO; van Hest, Marinus Franciscus Antonius Maria; Ginley, David S [Evergreen, CO; Leisch, Jennifer [Denver, CO; Taylor, Matthew [West Simsbury, CT; Stanbery, Billy J [Austin, TX

2011-09-20

Precursor compositions containing copper and selenium suitable for deposition on a substrate to form thin films suitable for semi-conductor applications. Methods of forming the precursor compositions using primary amine solvents and methods of forming the thin films wherein the selection of temperature and duration of heating controls the formation of a targeted species of copper selenide.

Sedimentary architecture and depositional evolution of the Quaternary coastal plain of Maricá, Rio de Janeiro, Brazil

Directory of Open Access Journals (Sweden)

André Luiz Carvalho da Silva

Full Text Available The coastal geomorphology of Maricá (Rio de Janeiro state is characterized by a large lagoon and by two sandy barriers that confine a series of small isolated chain-like lagoons. Data collected from ground-penetrating radar and boreholes from the central coastal plain of Maricá provided information on the sedimentary architecture and evolution of this area in the Quaternary. Six lithological units were identified comprising three depositional sequences limited by erosional surfaces, related to barrier-lagoon systems that migrated onshore, offshore, and longshore, giving rise to a sedimentary deposit 25 m thick or more. The data reveal a retrograding barrier overlying a basal mud unit which rests in unconformity upon Precambrian basement, thus characterizing an important Pleistocene transgression. A second Pleistocene barrier of 45,000 cal years BP migrated over a lagoonal mud unit (48,000-45,000 cal years BP reaching over the previous barrier. A progradational phase followed due to a fall of sea level. A long interval of erosion of the barrier created an unconformity that represents the Pleistocene-Holocene boundary. A beachrock in nearby Itaipuaçu, 100 m offshore from the present-day beach, dated as 8,500 cal years BP marks the onset of Holocene sedimentation due to gradually rising sea level, which continued until at about 5,000 years ago. This promoted the retrogradation of the barrier-lagoon system. A brief episode of progradation is observed as a series of paleobeach scarps. Today's rising sea level is causing the retrogradation of the barrier.

Thermodynamic investigation of the MOCVD of copper films from bis ...

Indian Academy of Sciences (India)

Equilibrium concentrations of various condensed and gaseous phases have been thermodynamically calculated, using the free energy minimization criterion, for the metalorganic chemical vapour deposition (MOCVD) of copper films using bis(2,2,6,6-tetramethyl-3,5-heptadionato)copper(II) as the precursor material.

Remote sensing and Aeromagnetic investigations in porphyry copper deposits for identification of areas with high concentration of gold: a case study from the central part of Dehaj-Sarduiyeh belt, Kerman, Iran

Directory of Open Access Journals (Sweden)

Mahdieh Hosseinjani Zadeh

2018-04-01

Full Text Available Introduction Remote sensing has shown tremendous potential in the identification of alteration zones. The importance of this science for mineral exploration and recognition of alteration zones with lower cost, time, and manpower is confirmed in many studies (Amer et al., 2012; Hosseinjani Zadeh et al., 2014; Tayebi and Tangestani, 2015; Shahriari et al., 2015. Gold is one of the byproducts in most of the porphyry copper deposits (PCDs. Although the gold assay is partly low and reaches between 0.012- 0.38 g/t in these deposits, the high tonnage of copper deposits provides a considerable source of gold which has an important economic value (Kerrich et al., 2000. Extension, intensity of alteration, assays and the type of mineralization vary in different deposits. For instance, many Au-poor porphyry copper deposits in southwest USA, Central Asia, and west of South America are associated with widespread phyllic alteration (Kesler et al., 2002. In addition, there is a positive correlation between gold and magnetite in PCDs (Kesler et al., 2002; Shafiei and Shahabpour, 2008; Sillitoe, 1979. Therefore, aeromagnetic investigation could be useful in identification of these deposits. The aim of this research is discrimination of alteration zones and investigation areas with high concentration of gold through processing of remote sensing and aeromagnetic data. Materials and methods A number of prone areas with different concentrations of gold in Dehaj-Sarduiyeh copper belt including Sar Kuh, Abdar, Meiduk, Sarcheshmeh, Darrehzar, Sara, Iju and Seridune were investigated using the processing of Advanced space borne thermal emission and reflection radiometer (ASTER, and aeromagnetic data. Pre-processing acts such as crosstalk correction and Internal Average Relative Reflection (IARR calibration were implemented on the ASTER data in order to remove noise and acquire surface reflectance. The alteration minerals were discriminated by implementation of

Heavy metal deposition fluxes affecting an Atlantic coastal area in the southwest of Spain

Science.gov (United States)

Castillo, Sonia; de la Rosa, Jesús D.; Sánchez de la Campa, Ana M.; González-Castanedo, Yolanda; Fernández-Camacho, Rocío

2013-10-01

The present study seeks to estimate the impact of industrial emissions and harbour activities on total atmospheric deposition in an Atlantic coastal area in the southwest of the Iberian Peninsula. Three large industrial estates and a busy harbour have a notable influence on air quality in the city of Huelva and the surrounding area. The study is based on a geochemical characterization of trace elements deposited (soluble and insoluble fractions) in samples collected at a rate of 15 days/sample from June 2008 to May 2011 in three sampling sites, one in the principal industrial belt, another in the city of Huelva, and the last, 56 km outside Huelva city in an area of high ecological interest. The industrial emissions emitted by the Huelva industrial belt exert a notable influence on atmospheric deposition. Major deposition fluxes were registered for Fe, Cu, V, Ni, P, Pb, As, Sn, Sb, Se and Bi, principally in the insoluble fraction, derived from industrial funnel emissions and from harbour activities. Metals such as Mn, Ni, Cu and Zn, and elements such as P also have a significant presence in the soluble fraction converting them into potentially bio-available nutrients for the living organism in the ocean. A principal component analysis certifies three common emissions sources in the area: 1) a mineral factor composed mainly of elements derived from silicate minerals mixed with certain anthropogenic species (Mg, K, Sr, Na, Al, Ba, LREE, Li, Mn, HREE, Ti, Fe, Se, V, SO-, Ni, Ca and P); 2) an industrial factor composed of the same trace elements in the three areas (Sb, Mo, Bi, As, Pb, Sn and Cd) thus confirming the impact of the emissions from the Huelva industrial belt on remote areas; and 3) a marine factor composed of Na, Cl, Mg and SO.

Copper atomic-scale transistors.

Science.gov (United States)

Xie, Fangqing; Kavalenka, Maryna N; Röger, Moritz; Albrecht, Daniel; Hölscher, Hendrik; Leuthold, Jürgen; Schimmel, Thomas

2017-01-01

We investigated copper as a working material for metallic atomic-scale transistors and confirmed that copper atomic-scale transistors can be fabricated and operated electrochemically in a copper electrolyte (CuSO 4 + H 2 SO 4 ) in bi-distilled water under ambient conditions with three microelectrodes (source, drain and gate). The electrochemical switching-on potential of the atomic-scale transistor is below 350 mV, and the switching-off potential is between 0 and -170 mV. The switching-on current is above 1 μA, which is compatible with semiconductor transistor devices. Both sign and amplitude of the voltage applied across the source and drain electrodes ( U bias ) influence the switching rate of the transistor and the copper deposition on the electrodes, and correspondingly shift the electrochemical operation potential. The copper atomic-scale transistors can be switched using a function generator without a computer-controlled feedback switching mechanism. The copper atomic-scale transistors, with only one or two atoms at the narrowest constriction, were realized to switch between 0 and 1 G 0 ( G 0 = 2e 2 /h; with e being the electron charge, and h being Planck's constant) or 2 G 0 by the function generator. The switching rate can reach up to 10 Hz. The copper atomic-scale transistor demonstrates volatile/non-volatile dual functionalities. Such an optimal merging of the logic with memory may open a perspective for processor-in-memory and logic-in-memory architectures, using copper as an alternative working material besides silver for fully metallic atomic-scale transistors.

Lafourche Parish Coastal Zone Curriculum Resource Unit. Bulletin 1834.

Science.gov (United States)

Daigle, Bobby; And Others

The Louisiana coastal zone is a unique geographic feature. Soil carried by the Mississippi River has been deposited in Louisiana for the last 6,000 years to form the coastal area. All natural features in coastal Louisiana relate to materials and processes associated with the emptying of the Mississippi River into the Gulf of Mexico. The…

Trace elements in rainwater and dry deposition around a smelting complex

Energy Technology Data Exchange (ETDEWEB)

Beavington, F

1977-06-01

A number of plastic raingauges were set up at various distances around a smelting complex (copper smelter and steelworks) in Wollongong, Australia, to determine the pattern of total atmospheric deposition (rainwater and dry deposition) of copper, zinc, lead, cadmium, iron and manganese. At the site nearest the smelter, total deposition of these metals (6N HCl soluble) in kg/ha over a period of twelve months was 30.7 copper, 8.4 zinc, 4.7 lead, 0.19 cadmium, 42.6 iron and 1.5 manganese. These levels were considerably higher than at a distant rural site where background levels were similar to those reported for the United Kingdom. The pattern of deposition of metals over Wollongong accords with levels of metals previously reported in surface soil, herbage and leaf vegetables.

Tunable synthesis of copper nanotubes

International Nuclear Information System (INIS)

Kaniukov, E; Yakimchuk, D; Kozlovsky, A; Shlimas, D; Zdorovets, M; Kadyrzhanov, K

2016-01-01

Simple method of tunable synthesis of copper nanotubes based on template synthesis was developed. A comprehensive study of the structural, morphological and electrical characteristics of the obtained nanostructures was carried out. Characterization of structural features was made by methods of scanning electron microscopy, energy dispersive spectroscopy and X-ray diffractometry analysis. Evaluation of wall thickness is made by methods of gas permeability. Electrical conductivity of nanotubes was define in the study of their current-voltage characteristics. The possibility to control of copper nanotubes physical properties by variation of the deposition parameters was shown. (paper)

Multilayer TiC/TiN diffusion barrier films for copper

International Nuclear Information System (INIS)

Yoganand, S.N.; Raghuveer, M.S.; Jagannadham, K.; Wu, L.; Karoui, A.; Rozgonyi, G.

2002-01-01

TiC/TiN thin films deposited by reactive magnetron sputtering on Si (100) substrates were investigated by transmission electron microscopy for microstructure and by deep level transient spectroscopy (DLTS) for diffusion barrier against copper. TiN thin films deposited on Si substrates at a substrate temperature of 600 deg. C were textured, and TiC thin films deposited at the same temperature were polycrystalline. TiC/TiN multilayer films also showed the same characteristics with the formation of an additional interaction layer. The diffusion barrier characteristics of the TiC/TiN/Si were determined by DLTS and the results showed that the films completely prevented diffusion of copper into Si

Study of the structure and electrical properties of the copper nitride thin films deposited by pulsed laser deposition

International Nuclear Information System (INIS)

Gallardo-Vega, C.; Cruz, W. de la

2006-01-01

Copper nitride thin films were prepared on glass and silicon substrates by ablating a copper target at different pressure of nitrogen. The films were characterized in situ by X-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES) and ex situ by X-ray diffraction (XRD). The nitrogen content in the samples, x = [N]/[Cu], changed between 0 and 0.33 for a corresponding variation in nitrogen pressure of 9 x 10 -2 to 1.3 x 10 -1 Torr. Using this methodology, it is possible to achieve sub-, over- and stoichiometric films by controlling the nitrogen pressure. The XPS results show that is possible to obtain copper nitride with x = 0.33 (Cu 3 N) and x = 0.25 (Cu 4 N) when the nitrogen pressure is 1.3 x 10 -1 and 5 x 10 -2 Torr, respectively. The lattice constants obtained from XRD results for copper nitride with x = 0.25 is of 3.850 A and with x = 0.33 have values between 3.810 and 3.830 A. The electrical properties of the films were studied as a function of the lattice constant. These results show that the electrical resistivity increases when the lattice parameter is decreasing. The electrical resistivity of copper nitride with x = 0.25 was smaller than samples with x = 0.33

Study of the structure and electrical properties of the copper nitride thin films deposited by pulsed laser deposition

Energy Technology Data Exchange (ETDEWEB)

Gallardo-Vega, C. [Centro de Investigacion Cientifica y de Educacion Superior de Ensenada (CICESE), Km. 107 Carretera Tijuana-Ensenada, A. Postal 2732, 22860, Ensenada B.C. (Mexico)]. E-mail: gallardo@ccmc.unam.mx; Cruz, W. de la [Centro de Ciencias de la Materia Condensada, UNAM, Km. 107 Carretera Tijuana-Ensenada, A. Postal 2681, 22860, Ensenada B.C. (Mexico)

2006-09-15

Copper nitride thin films were prepared on glass and silicon substrates by ablating a copper target at different pressure of nitrogen. The films were characterized in situ by X-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES) and ex situ by X-ray diffraction (XRD). The nitrogen content in the samples, x = [N]/[Cu], changed between 0 and 0.33 for a corresponding variation in nitrogen pressure of 9 x 10{sup -2} to 1.3 x 10{sup -1} Torr. Using this methodology, it is possible to achieve sub-, over- and stoichiometric films by controlling the nitrogen pressure. The XPS results show that is possible to obtain copper nitride with x = 0.33 (Cu{sub 3}N) and x = 0.25 (Cu{sub 4}N) when the nitrogen pressure is 1.3 x 10{sup -1} and 5 x 10{sup -2} Torr, respectively. The lattice constants obtained from XRD results for copper nitride with x = 0.25 is of 3.850 A and with x = 0.33 have values between 3.810 and 3.830 A. The electrical properties of the films were studied as a function of the lattice constant. These results show that the electrical resistivity increases when the lattice parameter is decreasing. The electrical resistivity of copper nitride with x = 0.25 was smaller than samples with x = 0.33.

Seasonal and spatial patterns of metals at a restored copper mine site. I. Stream copper and zinc

International Nuclear Information System (INIS)

Bambic, Dustin G.; Alpers, Charles N.; Green, Peter G.; Fanelli, Eileen; Silk, Wendy K.

2006-01-01

Seasonal and spatial variations in metal concentrations and pH were found in a stream at a restored copper mine site located near a massive sulfide deposit in the Foothill copper-zinc belt of the Sierra Nevada, California. At the mouth of the stream, copper concentrations increased and pH decreased with increased streamflow after the onset of winter rain and, unexpectedly, reached extreme values 1 or 2 months after peaks in the seasonal hydrographs. In contrast, aqueous zinc and sulfate concentrations were highest during low-flow periods. Spatial variation was assessed in 400 m of reach encompassing an acidic, metal-laden seep. At this seep, pH remained low (2-3) throughout the year, and copper concentrations were highest. In contrast, the zinc concentrations increased with downstream distance. These spatial patterns were caused by immobilization of copper by hydrous ferric oxides in benthic sediments, coupled with increasing downstream supply of zinc from groundwater seepage. - Seasonal hydrology and benthic sediments control copper and zinc concentrations in a stream through a restored mine site

Cyclic voltammetry deposition of copper nanostructure on MWCNTs modified pencil graphite electrode: An ultra-sensitive hydrazine sensor

Energy Technology Data Exchange (ETDEWEB)

Heydari, Hamid [Faculty of Sciences, Razi University, Kermanshah (Iran, Islamic Republic of); Gholivand, Mohammad B., E-mail: mbgholivand@razi.ac.ir [Faculty of Sciences, Razi University, Kermanshah (Iran, Islamic Republic of); Abdolmaleki, Abbas [Department of Chemistry, Malek Ashtar University of Technology, Tehran (Iran, Islamic Republic of)

2016-09-01

In this study, Copper (Cu) nanostructures (CuNS) were electrochemically deposited on a film of multiwall carbon nanotubes (MWCNTs) modified pencil graphite electrode (MWCNTs/PGE) by cyclic voltammetry method to fabricate a CuNS–MWCNTs composite sensor (CuNS–MWCNT/PGE) for hydrazine detection. Scanning electron microscopy (SEM) and Energy-dispersive X-ray spectroscopy (EDX) were used for the characterization of CuNS on the MWCNTs matrix. The composite of CuNS-MWCNTs was characterized with cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The preliminary studies showed that the proposed sensor have a synergistic electrocatalytic activity for the oxidation of hydrazine in phosphate buffer. The catalytic currents of square wave voltammetry had a linear correlation with the hydrazine concentration in the range of 0.1 to 800 μM with a low detection limit of 70 nM. Moreover, the amperometric oxidation current exhibited a linear correlation with hydrazine concentration in the concentration range of 50–800 μM with the detection limit of 4.3 μM. The proposed electrode was used for the determination of hydrazine in real samples and the results were promising. Empirical results also indicated that the sensor had good reproducibility, long-term stability, and the response of the sensor to hydrazine was free from interferences. Moreover, the proposed sensor benefits from simple preparation, low cost, outstanding sensitivity, selectivity, and reproducibility for hydrazine determination. - Highlights: • The Copper nanostructures (CuNS) were prepared by cyclic voltammetry deposition. • The CuNS-MWCNT/PGE sensor shows high activity toward hydrazine (N{sub 2}H{sub 4}). • The proposed sensor exhibits a wide linear range (0.1 to 800 μM), low detection limit (70 nM), high sensitivity and stability for hydrazine.

Effect of Copper on Passivity and Corrosion Behavior of Fe-xC-5Cu ...

African Journals Online (AJOL)

... copper/microstructure is discussed. Alloying Cu showed a beneficial effect on hypoeutectoid steel and harmful effect on hypereutectoid steel. The improved corrosion resistance is related to cementite morphology and by a copper dissolution/re-deposition process. Keywords: Corrosion; Copper; cementite; EIS; Passivation ...

Effects of sediment-associated copper to the deposit-feeding snail, Potamopyrgus antipodarum

DEFF Research Database (Denmark)

Pang, Chengfang; Selck, Henriette; Misra, Superb K

2012-01-01

the case of metal oxide NPs using CuO to understand if the effects of NPs differ from micron-sized particles of CuO and aqueous Cu (CuCl2). To address this issue, we compared effects of copper added to the sediment as aqueous Cu, nano- (6 nm) and micro- (... greater effects on growth, feeding rate, and reproduction of P. antipodarum than copper added as micro-CuO or aqueous Cu. P. antipodarum accumulated more copper in the nano-CuO treatment than in aqueous Cu or micro-CuO treatments, indicating that consideration of metal form may be important when assessing...

Colloidal and electrochemical aspects of copper-CMP

Science.gov (United States)

Sun, Yuxia

Copper based interconnects with low dielectric constant layers are currently used to increase interconnect densities and reduce interconnect time delays in integrated circuits. The technology used to develop copper interconnects involves Chemical Mechanical Planarization (CMP) of copper films deposited on low-k layers (silica or silica based films), which is carried out using slurries containing abrasive particles. One issue using such a structure is copper contamination over dielectric layers (SiO2 film), if not reduced, this contamination will cause current leakage. In this study, the conditions conducive to copper contamination onto SiO2 films during Cu-CMP process were studied, and a post-CMP cleaning technique was discussed based on experimental results. It was found that the adsorption of copper onto a silica surface is kinetically fast (electrocoagulation was investigated to remove both copper and abrasive slurry particles simultaneously. For effluent containing ˜40 ppm dissolved copper, it was found that ˜90% dissolved copper was removed from the waste streams through electroplating and in-situ chemical precipitation. The amount of copper removed through plating is impacted by membrane surface charge, type/amount of complexing agents, and solid content in the slurry suspension. The slurry particles can be removed ˜90% within 2 hours of EC through multiple mechanisms.

Porphyry copper assessment of the Mesozoic of East Asia: China, Vietnam, North Korea, Mongolia, and Russia: Chapter G in Global mineral resource assessment

Science.gov (United States)

Ludington, Steve; Mihalasky, Mark J.; Hammarstrom, Jane M.; Robinson, Giplin R.; Frost, Thomas P.; Gans, Kathleen D.; Light, Thomas D.; Miller, Robert J.; Alexeiev, Dmitriy V.

2012-01-01

The U.S. Geological Survey (USGS) collaborated with the China Geological Survey (CGS) to conduct a mineral resource assessment of Mesozoic porphyry copper deposits in East Asia. This area hosts several very large porphyry deposits, exemplified by the Dexing deposit in eastern China that contains more than 8,000,000 metric tons of copper. In addition, large parts of the area are undergoing active exploration and are likely to contain undiscovered porphyry copper deposits.

Effects of Copper Exposure on Photosynthesis and Growth of the Seagrass Cymodocea nodosa: An Experimental Assessment.

Science.gov (United States)

Llagostera, Izaskun; Cervantes, Daniel; Sanmartí, Neus; Romero, Javier; Pérez, Marta

2016-09-01

Seagrasses form some of the most important coastal habitats. They may be negatively affected by trace metal contamination in certain coastal areas. In this study we experimentally assessed selected morphological and physiological traits of the seagrass Cymodocea nodosa, with increasing concentrations of copper (Cu) under controlled laboratory conditions. Short term (21 days) sub-lethal effects such as decreased maximum quantum yield, increased leaf necrosis and decreased shoot growth and shoot recruitment were clearly observed at the highest Cu exposure (5 mg L(-1)), while the effects were weaker at the intermediate concentration (2.5 mg L(-1)) and almost absent at the lowest concentration (1 mg L(-1)), indicating that this species is highly tolerant to copper exposure, at least in the short term. This fact could help to explain its distribution in relatively polluted coastal waters.

Voltammetric behaviour at gold electrodes immersed in the BCR sequential extraction scheme media Application of underpotential deposition-stripping voltammetry to determination of copper in soil extracts

Energy Technology Data Exchange (ETDEWEB)

Beni, Valerio; Newton, Hazel V.; Arrigan, Damien W.M.; Hill, Martin; Lane, William A.; Mathewson, Alan

2004-01-30

The development of mercury-free electroanalytical systems for in-field analysis of pollutants requires a foundation on the electrochemical behaviour of the chosen electrode material in the target sample matrices. In this work, the behaviour of gold working electrodes in the media employed in the BCR sequential extraction protocol, for the fractionation of metals in solid environmental matrices, is reported. All three of the BCR sequential extraction media are redox active, on the basis of acidity and oxygen content as well as the inherent reducing or oxidising nature of some of the reagents employed: 0.11 M acetic acid, 0.1 M hydroxylammonium chloride (adjusted to pH 2) and 1 M ammonium acetate (adjusted to pH 2) with added trace hydrogen peroxide. The available potential ranges together with the demonstrated detection of target metals in these media are presented. Stripping voltammetry of copper or lead in the BCR extract media solutions reveal a multi-peak behaviour due to the stripping of both bulk metal and underpotential metal deposits. A procedure based on underpotential deposition-stripping voltammetry (UPD-SV) was evaluated for application to determination of copper in 0.11 M acetic acid soil extracts. A preliminary screening step in which different deposition times are applied to the sample enables a deposition time commensurate with UPD-SV to be selected so that no bulk deposition or stripping occurs thus simplifying the shape and features of the resulting voltammograms. Choice of the suitable deposition time is then followed by standards addition calibration. The method was validated by the analysis of a number of BCR 0.11 M acetic acid soil extracts. Good agreement was obtained been the UPD-SV method and atomic spectroscopic results.

Voltammetric behaviour at gold electrodes immersed in the BCR sequential extraction scheme media Application of underpotential deposition-stripping voltammetry to determination of copper in soil extracts

International Nuclear Information System (INIS)

Beni, Valerio; Newton, Hazel V.; Arrigan, Damien W.M.; Hill, Martin; Lane, William A.; Mathewson, Alan

2004-01-01

The development of mercury-free electroanalytical systems for in-field analysis of pollutants requires a foundation on the electrochemical behaviour of the chosen electrode material in the target sample matrices. In this work, the behaviour of gold working electrodes in the media employed in the BCR sequential extraction protocol, for the fractionation of metals in solid environmental matrices, is reported. All three of the BCR sequential extraction media are redox active, on the basis of acidity and oxygen content as well as the inherent reducing or oxidising nature of some of the reagents employed: 0.11 M acetic acid, 0.1 M hydroxylammonium chloride (adjusted to pH 2) and 1 M ammonium acetate (adjusted to pH 2) with added trace hydrogen peroxide. The available potential ranges together with the demonstrated detection of target metals in these media are presented. Stripping voltammetry of copper or lead in the BCR extract media solutions reveal a multi-peak behaviour due to the stripping of both bulk metal and underpotential metal deposits. A procedure based on underpotential deposition-stripping voltammetry (UPD-SV) was evaluated for application to determination of copper in 0.11 M acetic acid soil extracts. A preliminary screening step in which different deposition times are applied to the sample enables a deposition time commensurate with UPD-SV to be selected so that no bulk deposition or stripping occurs thus simplifying the shape and features of the resulting voltammograms. Choice of the suitable deposition time is then followed by standards addition calibration. The method was validated by the analysis of a number of BCR 0.11 M acetic acid soil extracts. Good agreement was obtained been the UPD-SV method and atomic spectroscopic results

Chemical Vapour Deposition of Large Area Graphene

DEFF Research Database (Denmark)

Larsen, Martin Benjamin Barbour Spanget

Chemical Vapor Deposition (CVD) is a viable technique for fabrication of large areas of graphene. CVD fabrication is the most prominent and common way of fabricating graphene in industry. In this thesis I have attempted to optimize a growth recipe and catalyst layer for CVD fabrication of uniform......, single layer, and high carrier mobility large area graphene. The main goals of this work are; (1) explore the graphene growth mechanics in a low pressure cold-wall CVD system on a copper substrate, and (2) optimize the process of growing high quality graphene in terms of carrier mobility, and crystal...... structure. Optimization of a process for graphene growth on commercially available copper foil is limited by the number of aluminium oxide particles on the surface of the catalyst. By replacing the copper foil with a thin deposited copper film on a SiO2/Si or c-plane sapphire wafer the particles can...

Novel Microbial Assemblages Dominate Weathered Sulfide-Bearing Rock from Copper-Nickel Deposits in the Duluth Complex, Minnesota, USA.

Science.gov (United States)

Jones, Daniel S; Lapakko, Kim A; Wenz, Zachary J; Olson, Michael C; Roepke, Elizabeth W; Sadowsky, Michael J; Novak, Paige J; Bailey, Jake V

2017-08-15

The Duluth Complex in northeastern Minnesota hosts economically significant deposits of copper, nickel, and platinum group elements (PGEs). The primary sulfide mineralogy of these deposits includes the minerals pyrrhotite, chalcopyrite, pentlandite, and cubanite, and weathering experiments show that most sulfide-bearing rock from the Duluth Complex generates moderately acidic leachate (pH 4 to 6). Microorganisms are important catalysts for metal sulfide oxidation and could influence the quality of water from mines in the Duluth Complex. Nevertheless, compared with that of extremely acidic environments, much less is known about the microbial ecology of moderately acidic sulfide-bearing mine waste, and so existing information may have little relevance to those microorganisms catalyzing oxidation reactions in the Duluth Complex. Here, we characterized the microbial communities in decade-long weathering experiments (kinetic tests) conducted on crushed rock and tailings from the Duluth Complex. Analyses of 16S rRNA genes and transcripts showed that differences among microbial communities correspond to pH, rock type, and experimental treatment. Moreover, microbial communities from the weathered Duluth Complex rock were dominated by taxa that are not typically associated with acidic mine waste. The most abundant operational taxonomic units (OTUs) were from the genera Meiothermus and Sulfuriferula , as well as from diverse clades of uncultivated Chloroflexi , Acidobacteria , and Betaproteobacteria Specific taxa, including putative sulfur-oxidizing Sulfuriferula spp., appeared to be primarily associated with Duluth Complex rock, but not pyrite-bearing rocks subjected to the same experimental treatment. We discuss the implications of these results for the microbial ecology of moderately acidic mine waste with low sulfide content, as well as for kinetic testing of mine waste. IMPORTANCE Economic sulfide mineral deposits in the Duluth Complex may represent the largest

The development of an ore reserve methodology for the Olympic Dam copper-uranium-gold deposit

International Nuclear Information System (INIS)

Scott, I.R.

1987-01-01

At the Olympic Dam copper-uranium-gold deposit in South Australia, evolution in the understanding of the controls on mineralisation coupled with the changing demands of the project have led to changes in the approach to reserve estimation. The project has moved into a phase where detailed stope mining reserves are now required as distinct from global ore reserves. To enable the selective manipulation of geological and assay information and its characterisation, a relational database has been developed. For reserve calculations themselves, initial computations were based on a system derived from that used for the Kambalda nickel orebodies. The Olympic Dam system differed mainly in the use of statistical analyses in the estimation of grade instead of the previous polygonal area of influence weighting method. Three dimensional weighting techniques are now being used for local reserve estimates

Ways of improvement of technological process of copper wire rod production

OpenAIRE

Dvoryanyn, Hrystyna; Shvachco, Sergiy

2015-01-01

Copper is a unique chemical element which is used since ancient times due to its universal chemical properties. By means of the method of continuous founding, hundreds of items of rod-like billets of different cross-section shapes are manufactured from copper. The problem of production of defectfree copper wire rods is important nowadays, because the market of cable products still increases. As the deposits of cooper ore in the nature are being exhausted, the processing of copper scrap become...

Electrochemical synthesis of highly ordered polypyrrole on copper modified aluminium substrates

International Nuclear Information System (INIS)

Siddaramanna, Ashoka; Saleema, N.; Sarkar, D.K.

2014-01-01

Fabrication of highly ordered conducting polymers on metal surfaces has received a significant interest owing to their potential applications in organic electronic devices. In this context, we have developed a simple method for the synthesis of highly ordered polypyrrole (PPy) on copper modified aluminium surfaces via electrochemical polymerization process. A series of characteristic peaks of PPy evidenced on the infrared spectra of these surfaces confirm the formation of PPy. The X-ray diffraction (XRD) pattern of PPy deposited on copper modified aluminium surfaces also confirmed the deposition of PPy as a sharp and intense peak at 2θ angle of 23° attributable to PPy is observed while this peak is absent on PPy deposited on as-received aluminium surfaces. An atomic model of the interface of PPy/Cu has been presented based on the inter-atomic distance of copper–copper of (1 0 0) plane and the inter-monomer distance of PPy, to describe the ordering of PPy on Cu modified Al surfaces.

The impact of hydrogen and oxidizing impurities in chemical vapor deposition of graphene on copper

Science.gov (United States)

Choubak, Saman

Graphene, the single-atom layer of carbon, has attracted scientists and technologists due to its outstanding physical and opto/electronic properties. The use of graphene in practical applications requires a reliable and cost-effective method to produce large area graphene films with low defects and controlled thicknesses. Direct growth of graphene using chemical vapor deposition (CVD) on copper, in which carbonaceous gaseous species react with the metal substrate in the presence of hydrogen at high temperatures (850-1100° C), led to high coverage of high quality graphene, opening up a promising future for methods of this type and a large step towards commercial realization of graphene products. The present thesis deals with the synthesis of graphene via low pressure CVD (LP-CVD) on copper catalyst using methane as the carbon precursor. The focus is mainly on the determination of the role of hydrogen and oxidizing impurities during graphene formation with an ultimate purpose: to elucidate a viable and reproducible method for the production of high quality graphene films compatible with industrial manufacturing processes. The role of molecular hydrogen in graphene CVD is explored in the first part of the thesis. Few studies claimed that molecular hydrogen etches graphene films on copper by conducting annealing experiments. On the other hand, we speculated that this graphene etching reaction is due to the presence of trace amount of oxygen in the furnace atmosphere. Thus, we took another approach and designed systematic annealing experiments to investigate the role of hydrogen in the etching reaction of graphene on copper foils. No evidence of graphene etching on copper was observed when purified ultra high purity (UHP) hydrogen was used at 825 °C and 500 mTorr. Nevertheless, graphene films exposed to the unpurified UHP hydrogen were etched due to the presence of oxidizing impurities. Our results show that hydrogen is not responsible for graphene etching reaction

Electrodeposited porous and amorphous copper oxide film for application in supercapacitor

Energy Technology Data Exchange (ETDEWEB)

Patake, V.D. [Thin Film Physics Laboratory, Department of Physics, Shivaji University, Kolhapur 416004, (M.S.) (India); Joshi, S.S. [Clean Energy Research Center, Korea Institute of Science and Technology, Cheongryang, Seoul 130-650 (Korea, Republic of); Lokhande, C.D. [Thin Film Physics Laboratory, Department of Physics, Shivaji University, Kolhapur 416004, (M.S.) (India); Clean Energy Research Center, Korea Institute of Science and Technology, Cheongryang, Seoul 130-650 (Korea, Republic of)], E-mail: l_chandrakant@yahoo.com; Joo, Oh-Shim [Clean Energy Research Center, Korea Institute of Science and Technology, Cheongryang, Seoul 130-650 (Korea, Republic of)], E-mail: joocat@kist.rre.kr

2009-03-15

In present study, the porous amorphous copper oxide thin films have been deposited from alkaline sulphate bath. The cathodic electrodeposition method was employed to deposit copper oxide film at room temperature on stainless steel substrate. Their structural and surface morphological properties were investigated by means of X-ray diffraction (XRD) and scanning electron micrograph (SEM), respectively. To propose this as a new material for possible application in the supercapacitor, its electrochemical properties have been studied in aqueous 1 M Na{sub 2}SO{sub 4} electrolyte using cyclic voltammetry. The structural analysis from XRD pattern showed the formation of amorphous copper oxide film on the substrate. The surface morphological studies from scanning electron micrographs revealed the formation of porous cauliflower-like copper oxide film. The cyclic voltammetric curves showed symmetric nature and increase in capacitance with increase in film thickness. The maximum specific capacitance of 36 F g{sup -1} was exhibited for the 0.6959 mg cm{sup -2} film thickness. This shows that low-cost copper oxide electrode will be a potential application in supercapacitor.

Coastal sediment dynamics in Spitsbergen

Science.gov (United States)

Deloffre, J.; Lafite, R.; Baltzer, A.; Marlin, C.; Delangle, E.; Dethleff, D.; Petit, F.

2010-12-01

In arctic knowledge on coastal sediment dynamics and sedimentary processes is limited. The studied area is located in the microtidal Kongsfjorden glacial fjord on the North-western coast of Spitsbergen in the Artic Ocean (79°N). In this area sediment contributions to the coastal zone is provided by small temporary rivers that flows into the fjord. The objectives of this study are to (i) assess the origin and fate of fine-grained particles (sea ice cover on sediment dynamics. The sampling strategy is based on characterization of sediment and SPM (grain-size, X-rays diffraction, SEM images, carbonates and organic matter contents) from the glacier to the coastal zone completed by a bottom-sediment map on the nearshore using side-scan sonar validated with Ekman binge sampling. River inputs (i.e. river plumes) to the coastal zone were punctually followed using CTD (conductivity, temperature, depth and turbidity) profiles. OBS (water level, temperature and turbidity) operating at high-frequency and during at least 1 years (including under sea ice cover) was settled at the mouth of rivers at 10m depth. In the coastal zone the fine-grained sediment deposit is limited to mud patches located at river mouths that originate the piedmont glacier. However a significant amount of sediment originates the coastal glacier located in the eastern part of the fjord via two processes: direct transfer and ice-drop. Results from turbidity measurements show that the sediment dynamics is controlled by river inputs in particular during melting period. During winter sediment resuspension can occurs directly linked to significant wind-events. When the sea ice cover is present (January to April) no sediment dynamics is observed. Sediment processes in the coastal zone of arctic fjords is significant however only a small amount of SPM that originates the river plume settles in the coastal zone; only the coarser material settles at the mouth of the river while the finer one is deposited further

Numerical simulation of the internal stresses of thick tungsten coating deposited by vacuum plasma spraying on copper substrate

International Nuclear Information System (INIS)

Salito, A.; Tului, M.; Casadei, F.

1998-01-01

Several Divertor components in the new generation of nuclear fusion reactors need to be protected against ion sputtering. Particularly copper based (Cu) material is very sensitive to this sputtering process. A solution to overcome such component wear and plasma contamination is to protect the copper substrate with a thick tungsten (W) functional coating. The main difficulty to produce such components is the significant difference in the coating thermomechanical properties between W and Cu. The Vacuum Plasma Spraying coating process (VPS) is a very flexible new economical way to find a solution to the above problem. To optimise the adhesion and stress release properties between the Cu-alloy substrate and the W coating, it is possible to deposit an interlayer as a bond coat between both materials. The aim of this study is to determine the maximum of the residual stresses located between the Cu substrate and the W coating using finite element analysis. The results have been used to select different types of bond coat for the experimental development of thick W coating (>3 mm) on to mock-ups for the Divertor Channel of the ITER project. (author)

[Biohydrometallurgical technology of a complex copper concentrate process].

Science.gov (United States)

Murav'ev, M I; Fomchenko, N V; Kondrat'eva, T F

2011-01-01

Leaching of sulfide-oxidized copper concentrate of the Udokan deposit ore with a copper content of 37.4% was studied. In the course of treatment in a sulfuric acid solution with pH 1.2, a copper leaching rate was 6.9 g/kg h for 22 h, which allowed extraction of 40.6% of copper. As a result of subsequent chemical leaching at 80 degrees C during 7 h with a solution of sulphate ferric iron obtained after bio-oxidation by an association of microorganisms, the rate of copper recovery was 52.7 g/kg h. The total copper recovery was 94.5% (over 29 h). Regeneration of the Fe3+ ions was carried out by an association of moderately thermophilic microorganisms, including bacteria of genus Sulfobacillus and archaea of genus Ferroplasma acidiphilum, at 1.0 g/l h at 40 degrees C in the presence of 3% solids obtained by chemical leaching of copper concentrate. A technological scheme of a complex copper concentrate process with the use of bacterial-chemical leaching is proposed.

Investigation of thermal and hot-wire chemical vapor deposition copper thin films on TiN substrates using CupraSelect as precursor.

Science.gov (United States)

Papadimitropoulos, G; Davazoglou, D

2011-09-01

Copper films were deposited on oxidized Si substrates covered with TiN using a novel chemical vapor deposition reactor in which reactions were assisted by a heated tungsten filament (hot-wire CVD, HWCVD). Liquid at room temperature hexafluoroacetylacetonate Cu(I) trimethylvinylsilane (CupraSelect) was directly injected into the reactor with the aid of a direct-liquid injection (DLI) system using N2 as carrier gas. The deposition rates of HWCVD Cu films obtained on TiN covered substrates were found to increase with filament temperature (65 and 170 degrees C were tested). The resistivities of HWCVD Cu films were found to be higher than for thermally grown films due to the possible presence of impurities into the Cu films from the incomplete dissociation of the precursor and W impurities caused by the presence of the filament. For HWCVD films grown at a filament temperature of 170 degrees C, smaller grains are formed than at 65 degrees C as shown from the taken SEM micrographs. XRD diffractograms taken on Cu films deposited on TiN could not reveal the presence of W compounds originating from the filament because the relative peak was masked by the TiN [112] peak.

Direct patterning of highly-conductive graphene@copper composites using copper naphthenate as a resist for graphene device applications.

Science.gov (United States)

Bi, Kaixi; Xiang, Quan; Chen, Yiqin; Shi, Huimin; Li, Zhiqin; Lin, Jun; Zhang, Yongzhe; Wan, Qiang; Zhang, Guanhua; Qin, Shiqiao; Zhang, Xueao; Duan, Huigao

2017-11-09

We report an electron-beam lithography process to directly fabricate graphene@copper composite patterns without involving metal deposition, lift-off and etching processes using copper naphthenate as a high-resolution negative-tone resist. As a commonly used industrial painting product, copper naphthenate is extremely cheap with a long shelf time but demonstrates an unexpected patterning resolution better than 10 nm. With appropriate annealing under a hydrogen atmosphere, the produced graphene@copper composite patterns show high conductivity of ∼400 S cm -1 . X-ray diffraction, conformal Raman spectroscopy and X-ray photoelectron spectroscopy were used to analyze the chemical composition of the final patterns. With the properties of high resolution and high conductivity, the patterned graphene@copper composites could be used as conductive pads and interconnects for graphene electronic devices with ohmic contacts. Compared to common fabrication processes involving metal evaporation and lift-off steps, this pattern-transfer-free fabrication process using copper naphthenate resist is direct and simple but allows comparable device performance in practical device applications.

Deposition of nitrogen into the North Sea

DEFF Research Database (Denmark)

Leeuw, G. de; Skjøth, C.A.; Hertel, O.

2003-01-01

The flux of nitrogen species from the atmosphere into the ocean, with emphasis on coastal waters, was addressed during the ANICE project (Atmospheric Nitrogen Inputs into the Coastal Ecosystem). ANICE focused on quantifying the deposition of atmospheric inputs of inorganic nitrogen compounds (HNO3...... and Harwich/Newcastle. These measurements provided data for sensitivity studies of a variety of problems associated with the coastal region that are not easily evaluated with larger scale models, to constrain models and to test model results. Concentrations of nitrogen compounds over the North Sea...... on experimental results and small-scale model studies. In particular, effects of the aerosol size distribution on the nitrogen deposition are discussed. (C) 2003 Elsevier Ltd. All rights reserved....

Metallization on FDM Parts Using the Chemical Deposition Technique

Directory of Open Access Journals (Sweden)

Azhar Equbal

2014-08-01

Full Text Available Metallization of ABS (acrylonitrile-butadiene-styrene parts has been studied on flat part surfaces. These parts are fabricated on an FDM (fused deposition modeling machine using the layer-wise deposition principle using ABS as a part material. Electroless copper deposition on ABS parts was performed using two different surface preparation processes, namely ABS parts prepared using chromic acid for etching and ABS parts prepared using a solution mixture of sulphuric acid and hydrogen peroxide (H2SO4/H2O2 for etching. After surface preparations using these routes, copper (Cu is deposited electrolessly using four different acidic baths. The acidic baths used are 5 wt% CuSO4 (copper sulfate with 15 wt% of individual acids, namely HF (hydrofluoric acid, H2SO4 (sulphuric acid, H3PO4 (phosphoric acid and CH3COOH (acetic acid. Cu deposition under different acidic baths used for both the routes is presented and compared based on their electrical performance, scanning electron microscopy (SEM and energy dispersive X-ray spectrometry (EDS. The result shows that chromic acid etched samples show better electrical performance and Cu deposition in comparison to samples etched via H2SO4/H2O2.

Remote sensing applied to copper and uranium exploration

International Nuclear Information System (INIS)

Abrams, M.; Conel, J.

1982-01-01

A summary of some of the results of the Joint NASA/Geosat Test Case copper and uranium projects is presented. Two uranium deposits in Wyoming and Utah were investigated. These sites represented a Colorado Plateau sedimentary uranium deposit, and a deposit in fractured and crushed Precambrian granite. Each of the remote sensing data sets analyzed provided some important geologic information applicable to porphyry copper and uranium exploration. Landsat and Seasat data were best suited for regional reconnaissance of structural patterns, and some lithologic/alteration mapping. The higher spatial and spectral resolution provided by the aircraft scanners allowed improved separation of geologic units and delineation of more detailed fault patterns. Overall, th TMS provided the most useful data for lithologic and alteration mapping. The presence of the wavelength band in the 2.2 μm region was found to be invaluable for identifying areas with hydrous mineral-bearing rocks

Copper and CuNi alloys substrates for HTS coated conductor applications protected from oxidation

Energy Technology Data Exchange (ETDEWEB)

Segarra, M; Diaz, J; Xuriguera, H; Chimenos, J M; Espiell, F [Dept. of Chemical Engineering and Metallurgy, Univ. of Barcelona, Barcelona (Spain); Miralles, L [Lab. d' Investigacio en Formacions Geologiques. Dept. of Petrology, Geochemistry and Geological Prospecting, Univ. of Barcelona, Barcelona (Spain); Pinol, S [Inst. de Ciencia de Materials de Barcelona, Bellaterra (Spain)

2003-07-01

Copper is an interesting substrate for HTS coated conductors for its low cost compared to other metallic substrates, and for its low resistivity. Nevertheless, mechanical properties and resistance to oxidation should be improved in order to use it as substrate for YBCO deposition by non-vacuum techniques. Therefore, different cube textured CuNi tapes were prepared by RABIT as possible substrates for deposition of high critical current density YBCO films. Under the optimised conditions of deformation and annealing, all the studied CuNi alloys (2%, 5%, and 10% Ni) presented (100) left angle 001 right angle cube texture which is compatible for YBCO deposition. Textured CuNi alloys present higher tensile strength than pure copper. Oxidation resistance of CuNi tapes under different oxygen atmospheres was also studied by thermogravimetric analysis and compared to pure copper tapes. Although the presence of nickel improves mechanical properties of annealed copper, it does not improve its oxidation resistance. However, when a chromium buffer layer is electrodeposited on the tape, oxygen diffusion is slowed down. Chromium is, therefore, useful for protecting copper and CuNi alloys from oxidation although its recrystallisation texture, (110), is not suitable for coated conductors. (orig.)

Global mineral resource assessment: porphyry copper assessment of Mexico: Chapter A in Global mineral resource assessment

Science.gov (United States)

Hammarstrom, Jane M.; Robinson, Gilpin R.; Ludington, Steve; Gray, Floyd; Drenth, Benjamin J.; Cendejas-Cruz, Francisco; Espinosa, Enrique; Pérez-Segura, Efrén; Valencia-Moreno, Martín; Rodríguez-Castañeda, José Luis; Vásquez-Mendoza, Rigobert; Zürcher, Lukas

2010-01-01

Mineral resource assessments provide a synthesis of available information about distributions of mineral deposits in the Earth’s crust. A probabilistic mineral resource assessment of undiscovered resources in porphyry copper deposits in Mexico was done as part of a global mineral resource assessment. The purpose of the study was to (1) delineate permissive areas (tracts) for undiscovered porphyry copper deposits within 1 km of the surface at a scale of 1:1,000,000; (2) provide a database of known porphyry copper deposits and significant prospects; (3) estimate numbers of undiscovered deposits within those permissive tracts; and (4) provide probabilistic estimates of amounts of copper (Cu), molybdenum (Mo), gold (Au), and silver (Ag) that could be contained in undiscovered deposits for each permissive tract. The assessment was conducted using a three-part form of mineral resource assessment based on mineral deposit models (Singer, 1993). Delineation of permissive tracts primarily was based on distributions of mapped igneous rocks related to magmatic arcs that formed in tectonic settings associated with subduction boundary zones. Using a GIS, map units were selected from digital geologic maps based on lithology and age to delineate twelve permissive tracts associated with Jurassic, Laramide (~90 to 34 Ma), and younger Tertiary magmatic arcs. Stream-sediment geochemistry, mapped alteration, regional aeromagnetic data, and exploration history were considered in conjunction with descriptive deposit models and grade and tonnage models to guide estimates.

Electrochemical impedance study of copper in phosphate buffered solution

International Nuclear Information System (INIS)

Salimon, J.; Mohamad, M.; Yamin, B.M.; Kalaji, M.

2003-01-01

The processes occurring on the copper electrode surface in phosphate buffered solution were investigated using the Electrochemical Impedance Spectroscopy. The electrochemical behaviors of copper through their charge transfer resistance and double-layer capacitance at the onset of the hydrogen evolution region and the anodic passivation layer formation and diffusion of copper species at anodic potential regions are discussed. The specific adsorption of anions (hydroxide and/or H/sub 2/PO/sub 4/) occurred at potential less negative than -0.9V. Adsorbed hydrogen appeared at hydrogen evolution region at potential range of -1.5 to -1.0 V. The deposition of insoluble copper species occurred at anodic potential regions. (author)

Copper electrodeposition from an acidic plating bath containing accelerating and inhibiting organic additives

International Nuclear Information System (INIS)

Pasquale, M.A.; Gassa, L.M.; Arvia, A.J.

2008-01-01

Copper electrodeposition on copper from still plating solutions of different compositions was investigated utilising electrochemical impedance spectroscopy (EIS), cyclic voltammetry, and scanning electron microscopy (SEM). An acid copper sulphate plating base solution was employed either with or without sodium chloride in the presence of a single additive, either polyethylene glycol (PEG) or 3-mercapto-2-propanesulphonic acid (MPSA), and their mixture. Thallium underpotential deposition/anodic stripping was employed to determine the adsorption capability of additives on copper. In the absence of chloride ions, MPSA shows a moderate adsorption on copper, whereas PEG is slightly adsorbed. At low cathodic overpotentials, the simultaneous presence of MPSA and chloride ions accelerates copper electrodeposition through the formation of an MPSA-chloride ion complex in the solution, particularly for about 220 μM sodium chloride. The reverse effect occurs in PEG-sodium chloride plating solutions. In this case, from EIS data the formation of a film that interferes with copper electrodeposition can be inferred. At higher cathodic overpotentials, when copper electrodeposition is under mass transport control, the cathode coverage by a PEG-copper chloride-mediated film becomes either partially or completely detached as the concentration of chloride ions at the negatively charged copper surface diminishes. The copper cathode grain topography at the μm scale depends on the cathodic overpotential, plating solution composition and average current density. Available data about the solution constituents and their adsorption on copper make it possible to propose a likely complex mechanism to understand copper electrodeposition from these media, including the accelerating effect of MPSA and the dynamics of PEG-copper chloride complex adsorbate interfering with the surface mobility of depositing copper ad-ions/ad-atoms

A comparative study of stream water and stream sediment as geochemical exploration media in the Rio Tanama porphyry copper district, Puerto Rico

Science.gov (United States)

Learned, R.E.; Chao, T.T.; Sanzolone, R.F.

1985-01-01

To test the relative effectiveness of stream water and sediment as geochemical exploration media in the Rio Tanama porphyry copper district of Puerto Rico, we collected and subsequently analyzed samples of water and sediment from 29 sites in the rivers and tributaries of the district. Copper, Mo, Pb, Zn, SO42-, and pH were determined in the waters; Cu, Mo, Pb, and Zn were determined in the sediments. In addition, copper in five partial extractions from the sediments was determined. Geochemical contrast (anomaly-to-background quotient) was the principal criterion by which the effectiveness of the two media and the five extractions were judged. Among the distribution patterns of metals in stream water, that of copper most clearly delineates the known porphyry copper deposits and yields the longest discernable dispersion train. The distribution patterns of Mo, Pb, and Zn in water show little relationship to the known mineralization. The distribution of SO42- in water delineates the copper deposits and also the more extensive pyrite alteration in the district; its recognizable downstream dispersion train is substantially longer than those of the metals, either in water or sediment. Low pH values in small tributaries delineate areas of known sulfide mineralization. The distribution patterns of copper in sediments clearly delineate the known deposits, and the dispersion trains are longer than those of copper in water. The partial determinations of copper related to secondary iron and manganese oxides yield the strongest geochemical contrasts and longest recognizable dispersion trains. Significantly high concentrations of molybdenum in sediments were found at only three sites, all within one-half km downstream of the known copper deposits. The distribution patterns of lead and zinc in sediments are clearly related to the known primary lead-zinc haloes around the copper deposits. The recognizable downstream dispersion trains of lead and zinc are shorter than those of

Copper isotopic zonation in the Northparkes porphyry Cu-Au deposit, SE Australia

Science.gov (United States)

Li, Weiqiang; Jackson, Simon E.; Pearson, Norman J.; Graham, Stuart

2010-07-01

Significant, systematic Cu isotopic variations have been found in the Northparkes porphyry Cu-Au deposit, NSW, Australia, which is an orthomagmatic porphyry Cu deposit. Copper isotope ratios have been measured in sulfide minerals (chalcopyrite and bornite) by both solution and laser ablation multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). The results from both methods show a variation in δ 65Cu of hypogene sulfide minerals of greater than 1‰ (relative to NIST976). Significantly, the results from four drill holes through two separate ore bodies show strikingly similar patterns of Cu isotope variation. The patterns are characterized by a sharp down-hole decrease from up to 0.8‰ (0.29 ± 0.56‰, 1 σ, n = 20) in the low-grade peripheral alteration zones (phyllic-propylitic alteration zone) to a low of ˜-0.4‰ (-0.25 ± 0.36‰, 1 σ, n = 30) at the margins of the most mineralized zones (Cu grade >1 wt%). In the high-grade cores of the systems, the compositions are more consistent at around 0.2‰ (0.19 ± 0.14‰, 1 σ, n = 40). The Cu isotopic zonation may be explained by isotope fractionation of Cu between vapor, solution and sulfides at high temperature, during boiling and sulfide precipitation processes. Sulfur isotopes also show an isotopically light shell at the margins of the high-grade ore zones, but these are displaced from the low δ 65Cu shells, such that there is no correlation between the Cu and S isotope signatures. Fe isotope data do not show any discernable variation along the drill core. This work demonstrates that Cu isotopes show a large response to high-temperature porphyry mineralizing processes, and that they may act as a vector to buried mineralization.

Magnetic and gravity gradiometry framework for Mesoproterozoic iron oxide-apatite and iron oxide-copper-gold deposits, southeast Missouri, USA

Science.gov (United States)

McCafferty, Anne E.; Phillips, Jeffrey; Driscoll, Rhonda L.

2016-01-01

High-resolution airborne magnetic and gravity gradiometry data provide the geophysical framework for evaluating the exploration potential of hidden iron oxide deposits in Mesoproterozoic basement rocks of southeast Missouri. The data are used to calculate mineral prospectivity for iron oxide-apatite (IOA) ± rare earth element (REE) and iron oxide-copper-gold (IOCG) deposits. Results delineate the geophysical footprints of all known iron oxide deposits and reveal several previously unrecognized prospective areas. The airborne data are also inverted to three-dimensional density and magnetic susceptibility models over four concealed deposits at Pea Ridge (IOA ± REE), Boss (IOCG), Kratz Spring (IOA), and Bourbon (IOCG). The Pea Ridge susceptibility model shows a magnetic source that is vertically extensive and traceable to a depth of greater than 2 km. A smaller density source, located within the shallow Precambrian basement, is partly coincident with the magnetic source at Pea Ridge. In contrast, the Boss models show a large (625-m-wide), vertically extensive, and coincident dense and magnetic stock with shallower adjacent lobes that extend more than 2,600 m across the shallow Precambrian paleosurface. The Kratz Spring deposit appears to be a smaller volume of iron oxides and is characterized by lower density and less magnetic rock compared to the other iron deposits. A prospective area identified south of the Kratz Spring deposit shows the largest volume of coincident dense and nonmagnetic rock in the subsurface, and is interpreted as prospective for a hematite-dominant lithology that extends from the top of the Precambrian to depths exceeding 2 km. The Bourbon deposit displays a large bowl-shaped volume of coincident high density and high-magnetic susceptibility rock, and a geometry that suggests the iron mineralization is vertically restricted to the upper parts of the Precambrian basement. In order to underpin the evaluation of the prospectivity and three

Oxygen, hydrogen, sulfur, and carbon isotopes in the Pea Ridge magnetite-apatite deposit, southeast Missouri, and sulfur isotope comparisons to other iron deposits in the region

Science.gov (United States)

Johnson, Craig A.; Day, Warren C.; Rye, Robert O.

2016-01-01

Oxygen, hydrogen, sulfur, and carbon isotopes have been analyzed in the Pea Ridge magnetite-apatite deposit, the largest historic producer among the known iron deposits in the southeast Missouri portion of the 1.5 to 1.3 Ga eastern granite-rhyolite province. The data were collected to investigate the sources of ore fluids, conditions of ore formation, and provenance of sulfur, and to improve the general understanding of the copper, gold, and rare earth element potential of iron deposits regionally. The δ18O values of Pea Ridge magnetite are 1.9 to 4.0‰, consistent with a model in which some magnetite crystallized from a melt and other magnetite—perhaps the majority—precipitated from an aqueous fluid of magmatic origin. The δ18O values of quartz, apatite, actinolite, K-feldspar, sulfates, and calcite are significantly higher, enough so as to indicate growth or equilibration under cooler conditions than magnetite and/or in the presence of a fluid that was not entirely magmatic. A variety of observations, including stable isotope observations, implicate a second fluid that may ultimately have been meteoric in origin and may have been modified by isotopic exchange with rocks or by evaporation during storage in lakes.Sulfur isotope analyses of sulfides from Pea Ridge and seven other mineral deposits in the region reveal two distinct populations that average 3 and 13‰. Two sulfur sources are implied. One was probably igneous melts or rocks belonging to the mafic- to intermediate-composition volcanic suite that is present at or near most of the iron deposits; the other was either melts or volcanic rocks that had degassed very extensively, or else volcanic lakes that had trapped rising magmatic gases. The higher δ34S values correspond to deposits or prospects where copper is noteworthy—the Central Dome portion of the Boss deposit, the Bourbon deposit, and the Vilander prospective area. The correspondence suggests that (1) sulfur either limited the deposition

Correlations in distribution and concentration of calcium, copper and iron with zinc in isolated extracellular deposits associated with age-related macular degeneration

Science.gov (United States)

Flinn, Jane M; Kakalec, Peter; Tappero, Ryan; Jones, Blair F.; Lengyel, Imre

2014-01-01

Zinc (Zn) is abundantly enriched in sub-retinal pigment epithelial (RPE) deposits, the hallmarks of age-related macular degeneration (AMD), and is thought to play a role in the formation of these deposits. However, it is not known whether Zn is the only metal relevant for sub-RPE deposit formation. Because of their involvement in the pathogenesis of AMD, we determined the concentration and distribution of calcium (Ca), iron (Fe) and copper (Cu) and compared these with Zn in isolated and sectioned macular (MSD), equatorial (PHD) and far peripheral (FPD) sub-RPE deposits from an 86 year old donor eye with post mortem diagnosis of early AMD. The sections were mounted on Zn free microscopy slides and analyzed by microprobe synchrotron X-ray fluorescence (μSXRF). Metal concentrations were determined using spiked sectioned sheep brain matrix standards, prepared the same way as the samples. The heterogeneity of metal distributions was examined using pixel by pixel comparison. The orders of metal concentrations were Ca ⋙ Zn > Fe in all three types of deposits but Cu levels were not distinguishable from background values. Zinc and Ca were consistently present in all deposits but reached highest concentration in MSD. Iron was present in some but not all deposits and was especially enriched in FPD. Correlation analysis indicated considerable variation in metal distribution within and between sub-RPE deposits. The results suggest that Zn and Ca are the most likely contributors to deposit formation especially in MSD, the characteristic risk factor for the development of AMD in the human eye.

Synthesis of carbon nanotubes and nanotube forests on copper catalyst

International Nuclear Information System (INIS)

Kruszka, Bartosz; Terzyk, Artur P; Wiśniewski, Marek; Gauden, Piotr A; Szybowicz, Mirosław

2014-01-01

The growth of carbon nanotubes on bulk copper is studied. We show for the first time, that super growth chemical vapor deposition method can be successfully applied for preparation of nanotubes on copper catalyst, and the presence of hydrogen is necessary. Next, different methods of copper surface activation are studied, to improve catalyst efficiency. Among them, applied for the first time for copper catalyst in nanotubes synthesis, sulfuric acid activation is the most promising. Among tested samples the surface modified for 10 min is the most active, causing the growth of vertically aligned carbon nanotube forests. Obtained results have potential importance in application of nanotubes and copper in electronic chips and nanodevices. (paper)

Facet-dependent study of efficient growth of graphene on copper

Indian Academy of Sciences (India)

The growth of graphene by chemical vapour deposition (CVD) on copper is the most promising scalable method for high-quality graphene. The use of ethanol, an economic and safe precursor, for the fast growth of graphene on copper by a home-built CVD set-up was analysed. Full coverage of uniform single-layer ...

Physical, optical and electrical properties of copper selenide (CuSe) thin films deposited by solution growth technique at room temperature

International Nuclear Information System (INIS)

Gosavi, S.R.; Deshpande, N.G.; Gudage, Y.G.; Sharma, Ramphal

2008-01-01

Copper selenide (CuSe) thin films are grown onto amorphous glass substrate from an aqueous alkaline medium using solution growth technique (SGT) at room temperature. The preparative parameters were optimized to obtain good quality of thin films. The as-deposited films were characterized for physical, optical and electrical properties. X-ray diffraction (XRD) pattern reveals that the films are polycrystalline in nature. Energy dispersive analysis by X-ray (EDAX) shows formation of stoichiometric CuSe compound. Uniform deposition of CuSe thin films on glass substrate was observed from scanning electron microscopy (SEM) and atomic force microscopy (AFM) micrographs. Average grain size was determined to 144.53 ± 10 nm using atomic force microscopy. The band gap was found to be 2.03 eV with direct band-to-band transition. Semi-conducting behaviour was observed from resistivity measurements. Ohmic behaviour was seen from I-V curve with good electrical conductivity

Surface structure of ultrathin metal films deposited on copper single crystals

International Nuclear Information System (INIS)

Butterfield, M.T.

2000-04-01

Ultrathin films of Cobalt, Iron and Manganese have been thermally evaporated onto an fcc Copper (111) single crystal substrate and investigated using a variety of surface structural techniques. The small lattice mismatch between these metals and the Cu (111) substrate make them an ideal candidate for the study of the phenomena of pseudomorphic film growth. This is important for the understanding of the close relationship between film structure and magnetic properties. Growing films with the structure of their substrate rather than their bulk phase may provide an opportunity to grow materials with novel physical and magnetic properties, and hence new technological applications. Both Cobalt and Iron have been found to initially maintain a registry with the fcc Cu (111) surface in a manner consistent with pseudomorphic growth. This growth is complicated by island rather than layer by layer growth in the initials stages of the film. In both cases a change in the structure of the film seems to occur at a point where the coalescence of islands in the film may be expected to occur. When the film does change structure they do not form a perfect overlayer with the structure of their bulk counterpart. The films do contain a number of features representative of the bulk phase but also contain considerable disorder and possibly remnants of fcc (111) structure. The order present in these films can be greatly improved by annealing. Manganese appears to grow with an fcc Mn (111) lattice spacing and there is no sign of a change in structure in films of up to 4.61 ML thick. The gradual deposition and annealing of a film to 300 deg. C, with a total deposition time the same as that for a 1 ML thick film, causes a surface reconstruction to occur that is apparent in a R30 deg. (√3 x √3) LEED pattern. This is attributed to the formation of a surface alloy, which is also supported by the local expansion of the Cu lattice in the (111) direction. (author)

Deposition and properties of cobalt- and ruthenium-based ultra-thin films

Science.gov (United States)

Henderson, Lucas Benjamin

Future copper interconnect systems will require replacement of the materials that currently comprise both the liner layer(s) and the capping layer. Ruthenium has previously been considered as a material that could function as a single material liner, however its poor ability to prevent copper diffusion makes it incompatible with liner requirements. A recently described chemical vapor deposition route to amorphous ruthenium-phosphorus alloy films could correct this problem by eliminating the grain boundaries found in pure ruthenium films. Bias-temperature stressing of capacitor structures using 5 nm ruthenium-phosphorus film as a barrier to copper diffusion and analysis of the times-to-failure at accelerated temperature and field conditions implies that ruthenium-phosphorus performs acceptably as a diffusion barrier for temperatures above 165°C. The future problems associated with the copper capping layer are primarily due to the poor adhesion between copper and the current Si-based capping layers. Cobalt, which adheres well to copper, has been widely proposed to replace the Si-based materials, but its ability to prevent copper diffusion must be improved if it is to be successfully implemented in the interconnect. Using a dual-source chemistry of dicobaltoctacarbonyl and trimethylphosphine at temperatures from 250-350°C, amorphous cobalt-phosphorus can be deposited by chemical vapor deposition. The films contain elemental cobalt and phosphorus, plus some carbon impurity, which is incorporated in the film as both graphitic and carbidic (bonded to cobalt) carbon. When deposited on copper, the adhesion between the two materials remains strong despite the presence of phosphorus and carbon at the interface, but the selectivity for growth on copper compared to silicon dioxide is poor and must be improved prior to consideration for application in interconnect systems. A single molecule precursor containing both cobalt and phosphorus atoms, tetrakis

Evaluation of copper ion of antibacterial effect on Pseudomonas aeruginosa, Salmonella typhimurium and Helicobacter pylori and optical, mechanical properties

Energy Technology Data Exchange (ETDEWEB)

Kim, Young-Hwan [School of Materials Science and Engineering, University of Yonsei, Seoul (Korea, Republic of); Choi, Yu-ri; Kim, Kwang-Mahn [Department and Research Institute of Dental Biomaterials and Bioengineering, College of Dentistry, University of Yonsei, Seoul (Korea, Republic of); Choi, Se-Young, E-mail: sychoi@yonsei.ac.kr [School of Materials Science and Engineering, University of Yonsei, Seoul (Korea, Republic of)

2012-02-01

Antibacterial effect on Pseudomonas aeruginosa, Salmonella typhimurium and Helicobacter pylori of copper ion was researched. Also, additional effects of copper ion coating on optical and mechanical properties were researched as well. Copper ion was coated on glass substrate as a thin film to prevent bacteria from growing. Cupric nitrate was used as precursors for copper ion. The copper ion contained sol was deposited by spin coating process on glass substrate. Then, the deposited substrates were heat treated at the temperature range between 200 Degree-Sign C and 250 Degree-Sign C. The thickness of deposited copper layer on the surface was 63 nm. The antibacterial effect of copper ion coated glass on P. aeruginosa, S. typhimurium and H. pylori demonstrated excellent effect compared with parent glass. Copper ion contained layer on glass showed a similar value of transmittance compared with value of parent glass. The 3-point bending strength and Vickers hardness were 209.2 MPa, 540.9 kg/mm{sup 2} which were about 1.5% and 1.3% higher than the value of parent glass. From these findings, it is clear that copper ion coating on glass substrate showed outstanding effect not only in antibacterial activity but also in optical and mechanical properties as well.

Peat-accumulating depositional systems of Sarawak, East Malaysia

Science.gov (United States)

Staub, James R.; Esterle, Joan S.

1994-02-01

Many coal deposits originate in deltaic, estuarine, and coastal plain settings and a knowledge of interrelationships between the tectonic and depositional elements active at the time of sediment deposition is necessary to formulate basin scale models. The prograding coastal depositional systems of Sarawak all contain domed peat-accumulating environments in which low-ash, low-sulfur peats are being deposited in areas of active clastic siliciclastic sedimentation. These depositional systems are as large as 11,400 km 2 and individual peat deposits within systems are in excess of 20 m thick and 1000 km 2 in area. The geographic positions and drainage basin areas of each depositional system are controlled by fault and fold systems. Although prograding into the same receiving basin, individual system geomorphology is variable and ranges from a wave-dominated microtidal delta, to a wave-dominated meso- to macro-tidal delta/coastal plain system, to a tide-dominated macrotidal estuarine embayment along a 450 km stretch of coastline. System variation is a function of sediment supply, shelf and embayment geometry, wave climate, and tidal range. These factors, which control depositional system geomorphology, also control the resulting long axis orientation of the thick, domed peat deposits. The surface vegetation and internal characteristics of most domed peat deposits, however, are similar. Internal characteristics consist of basal high-ash, high-sulfur, degraded peats overlain by low-ash, low-sulfur, well preserved peats in vertical profile. These systems demonstrate variable responses to late Pleistocene/Holocene sea-level rise and, in these instances, the variation is most attributable to local differences in siliciclastic sediment supply, which is a function of the drainage basin area.

Analysis and assessment on heavy metal sources in the coastal soils developed from alluvial deposits using multivariate statistical methods.

Science.gov (United States)

Li, Jinling; He, Ming; Han, Wei; Gu, Yifan

2009-05-30

An investigation on heavy metal sources, i.e., Cu, Zn, Ni, Pb, Cr, and Cd in the coastal soils of Shanghai, China, was conducted using multivariate statistical methods (principal component analysis, clustering analysis, and correlation analysis). All the results of the multivariate analysis showed that: (i) Cu, Ni, Pb, and Cd had anthropogenic sources (e.g., overuse of chemical fertilizers and pesticides, industrial and municipal discharges, animal wastes, sewage irrigation, etc.); (ii) Zn and Cr were associated with parent materials and therefore had natural sources (e.g., the weathering process of parent materials and subsequent pedo-genesis due to the alluvial deposits). The effect of heavy metals in the soils was greatly affected by soil formation, atmospheric deposition, and human activities. These findings provided essential information on the possible sources of heavy metals, which would contribute to the monitoring and assessment process of agricultural soils in worldwide regions.

X-ray diffraction investigation of self-annealing in nanocrystalline copper electrodeposits

DEFF Research Database (Denmark)

Pantleon, Karen; Somers, Marcel A. J.

2006-01-01

X-ray diffraction analysis and electrical resistivity measurements were conducted simultaneously for in-situ examination of self-annealing in copper electrodeposits. Considerable growth of the as-deposited nano-sized crystallites occurs with time and the crystallographic texture changes by multip...... twinning during self-annealing. The kinetics of self-annealing depends on the layer thickness as well as on the orientation and/or the size of the as-deposited crystallites. (c) 2006 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.......X-ray diffraction analysis and electrical resistivity measurements were conducted simultaneously for in-situ examination of self-annealing in copper electrodeposits. Considerable growth of the as-deposited nano-sized crystallites occurs with time and the crystallographic texture changes by multiple...

Os isotopes and cooper sources for stratiform (mantos) cooper deposits of Chile

International Nuclear Information System (INIS)

Munizaga, Francisco; Ruiz, Joaquin; Freydier, Claire

1998-01-01

The sources of copper have been determined by studying trace elements osmium and rhenium as well as osmium isotope ratio in copper-bearing porphyry of Chuquicamata, el Teniente and Andacollo and in the stratiform copper deposits of Mantos Blancos, El Soldado, Cerro Negro and Talcuna

Joint simulation of stationary grade and non-stationary rock type for quantifying geological uncertainty in a copper deposit

Science.gov (United States)

Maleki, Mohammad; Emery, Xavier

2017-12-01

In mineral resources evaluation, the joint simulation of a quantitative variable, such as a metal grade, and a categorical variable, such as a rock type, is challenging when one wants to reproduce spatial trends of the rock type domains, a feature that makes a stationarity assumption questionable. To address this problem, this work presents methodological and practical proposals for jointly simulating a grade and a rock type, when the former is represented by the transform of a stationary Gaussian random field and the latter is obtained by truncating an intrinsic random field of order k with Gaussian generalized increments. The proposals concern both the inference of the model parameters and the construction of realizations conditioned to existing data. The main difficulty is the identification of the spatial correlation structure, for which a semi-automated algorithm is designed, based on a least squares fitting of the data-to-data indicator covariances and grade-indicator cross-covariances. The proposed models and algorithms are applied to jointly simulate the copper grade and the rock type in a Chilean porphyry copper deposit. The results show their ability to reproduce the gradual transitions of the grade when crossing a rock type boundary, as well as the spatial zonation of the rock type.

Reconnaissance and economic geology of Copper Mountain metamorphic complex, Owl Creek Mountains, Wyoming

International Nuclear Information System (INIS)

Hausel, W.D.

1983-01-01

The Copper Mountain metamorphic complex lies within a westerly trending belt of Precambrian exposures known as the Owl Creek Mountains uplift. The metamorphic complex at Copper Mountain is part of a larger complex known as the Owl Creek Mountains greenstone belt. Until more detailed mapping and petrographic studies can be completed, the Copper Mountain area is best referred to as a complex, even though it has some characteristics of a greestone belt. At least three episodes of Precambrian deformation have affected the supracrustals, and two have disturbed the granites. The final Precambrian deformation event was preceded by a weak thermal event expressed by retrogressive metamorphism and restricted metasomatic alteration. During this event, a second phase of pegmatization was accompanied by hydrothermal solutions. During the Laramide orogeny, Copper Mountain was again modified by deformation. Laramide deformation produced complex gravity faults and keystone grabens. Uranium deposits were formed following major Laramide deformation. The genesis of these deposits is attributable to either the leaching of granites or the leaching of overlying tuffaceous sediments during the Tertiary. Production of metals and industrial minerals has been limited, although some gold, copper, silver, tungsten, beryl, feldspar, and lithium ore have been shipped from Copper Mountain. A large amount of uranium was produced from the Copper Mountain district in the 1950s

Metallogenic events in the Coastal Cordillera of Copiapo region, northern Chile (26-28o S)

International Nuclear Information System (INIS)

Diaz, A.; Vivallo, W

2001-01-01

The metallogenic province of the Coastal Cordillera in the Copiapo region is characterized by Cu, Cu-Au,Cu-Fe-Au, Fe, Ag and Au deposits. The ore deposits are ranging in ages between Middle to Late Jurassic (1) and Early Cretaceous (2). Results of a geochronology program for ore deposits in this metallogenic province, in addition to existing geochronological control of the ore deposits host rocks (mainly intrusive) allowed to define four different Metallogenic Epochs which could be extended to other zones in the Coastal Cordillera (au)

Superhydrophobic Copper Surfaces with Anticorrosion Properties Fabricated by Solventless CVD Methods.

Science.gov (United States)

Vilaró, Ignasi; Yagüe, Jose L; Borrós, Salvador

2017-01-11

Due to continuous miniaturization and increasing number of electrical components in electronics, copper interconnections have become critical for the design of 3D integrated circuits. However, corrosion attack on the copper metal can affect the electronic performance of the material. Superhydrophobic coatings are a commonly used strategy to prevent this undesired effect. In this work, a solventless two-steps process was developed to fabricate superhydrophobic copper surfaces using chemical vapor deposition (CVD) methods. The superhydrophobic state was achieved through the design of a hierarchical structure, combining micro-/nanoscale domains. In the first step, O 2 - and Ar-plasma etchings were performed on the copper substrate to generate microroughness. Afterward, a conformal copolymer, 1H,1H,2H,2H-perfluorodecyl acrylate-ethylene glycol diacrylate [p(PFDA-co-EGDA)], was deposited on top of the metal via initiated CVD (iCVD) to lower the surface energy of the surface. The copolymer topography exhibited a very characteristic and unique nanoworm-like structure. The combination of the nanofeatures of the polymer with the microroughness of the copper led to achievement of the superhydrophobic state. AFM, SEM, and XPS were used to characterize the evolution in topography and chemical composition during the CVD processes. The modified copper showed water contact angles as high as 163° and hysteresis as low as 1°. The coating withstood exposure to aggressive media for extended periods of time. Tafel analysis was used to compare the corrosion rates between bare and modified copper. Results indicated that iCVD-coated copper corrodes 3 orders of magnitude slower than untreated copper. The surface modification process yielded repeatable and robust superhydrophobic coatings with remarkable anticorrosion properties.

A total content X-ray fluorescence method for copper prospecting

International Nuclear Information System (INIS)

Zhou Sichun; Xie Tingzhou; Ge Liangquan

1992-01-01

A new method is proposed to prospect copper deposits with portable XRF analyzer. The method is based on the close relation between Cu and the chalcophile elements or some other elements in the geochemical anomalies of a Cu deposit. Applications of the technique in Northeast China are presented

In situ recovery of copper from sulfide ore bodies following nuclear fracturing

Energy Technology Data Exchange (ETDEWEB)

Rosenbaum, Joe B; McKinney, W A [Salt Lake City Metallurgy Research Center, Bureau of Mines, US Department of the Interior, Salt Lake City, UT (United States)

1970-05-15

Leaching now yields about 12 percent of the Nation's annual new copper production. About 200,000 tons of copper a year is being won by heap and vat leaching of ore, dump leaching of waste, and in-place leaching of caved underground workings. Although in-place leaching was practiced as long ago as the 15th century, it is little used and contributes only a few percent of the total leach copper production. Current technology in this area is exemplified by practice at the Miami, Ariz., mine of the Miami Copper Co. Despite its limited use, the concept of extracting copper by in-place leaching without physically mining and transporting the ore continues to present intriguing cost saving possibilities. Project SLOOP has been proposed as an experiment to test the feasibility of nuclear fracturing and acid leaching the oxidized portion of a deep ore body near Safford, Ariz. However, the bulk of the copper in deep ore deposits occurs as sulfide minerals that are not easily soluble in acid solutions. This paper explores the concept of in-place leaching of nuclear fractured, deeply buried copper sulfide deposits. On the assumption that fracturing of rock and solution injection and collection would be feasible, an assessment is made of solution systems that might be employed for the different copper sulfide minerals in porphyry ore bodies. These include the conventional ferric sulfate-sulfuric acid systems and combinations of sulfide mineral oxidants and different acids. (author)

In situ recovery of copper from sulfide ore bodies following nuclear fracturing

International Nuclear Information System (INIS)

Rosenbaum, Joe B.; McKinney, W.A.

1970-01-01

Leaching now yields about 12 percent of the Nation's annual new copper production. About 200,000 tons of copper a year is being won by heap and vat leaching of ore, dump leaching of waste, and in-place leaching of caved underground workings. Although in-place leaching was practiced as long ago as the 15th century, it is little used and contributes only a few percent of the total leach copper production. Current technology in this area is exemplified by practice at the Miami, Ariz., mine of the Miami Copper Co. Despite its limited use, the concept of extracting copper by in-place leaching without physically mining and transporting the ore continues to present intriguing cost saving possibilities. Project SLOOP has been proposed as an experiment to test the feasibility of nuclear fracturing and acid leaching the oxidized portion of a deep ore body near Safford, Ariz. However, the bulk of the copper in deep ore deposits occurs as sulfide minerals that are not easily soluble in acid solutions. This paper explores the concept of in-place leaching of nuclear fractured, deeply buried copper sulfide deposits. On the assumption that fracturing of rock and solution injection and collection would be feasible, an assessment is made of solution systems that might be employed for the different copper sulfide minerals in porphyry ore bodies. These include the conventional ferric sulfate-sulfuric acid systems and combinations of sulfide mineral oxidants and different acids. (author)

A Holistic Model That Physicochemically Links Iron Oxide - Apatite and Iron Oxide - Copper - Gold Deposits to Magmas

Science.gov (United States)

Simon, A. C.; Reich, M.; Knipping, J.; Bilenker, L.; Barra, F.; Deditius, A.; Lundstrom, C.; Bindeman, I. N.

2015-12-01

Iron oxide-apatite (IOA) and iron oxide-copper-gold deposits (IOCG) are important sources of their namesake metals and increasingly for rare earth metals in apatite. Studies of natural systems document that IOA and IOCG deposits are often spatially and temporally related with one another and coeval magmatism. However, a genetic model that accounts for observations of natural systems remains elusive, with few observational data able to distinguish among working hypotheses that invoke meteoric fluid, magmatic-hydrothermal fluid, and immiscible melts. Here, we use Fe and O isotope data and high-resolution trace element (e.g., Ti, V, Mn, Al) data of individual magnetite grains from the world-class Los Colorados (LC) IOA deposit in the Chilean Iron Belt to elucidate the origin of IOA and IOCG deposits. Values of d56Fe range from 0.08‰ to 0.26‰, which are within the global range of ~0.06‰ to 0.5‰ for magnetite formed at magmatic conditions. Values of δ18O for magnetite and actinolite are 2.04‰ and 6.08‰, respectively, consistent with magmatic values. Ti, V, Al, and Mn are enriched in magnetite cores and decrease systematically from core to rim. Plotting [Al + Mn] vs. [Ti + V] indicates that magnetite cores are consistent with magmatic and/or magmatic-hydrothermal (i.e., porphyry) magnetites. Decreasing Al, Mn, Ti, V is consistent with a cooling trend from porphyry to Kiruna to IOCG systems. The data from LC are consistent with the following new genetic model for IOA and IOCG systems: 1) magnetite cores crystallize from silicate melt; 2) these magnetite crystals are nucleation sites for aqueous fluid that exsolves and scavenges inter alia Fe, P, S, Cu, Au from silicate melt; 3) the magnetite-fluid suspension is less dense that the surrounding magma, allowing ascent; 4) as the suspension ascends, magnetite grows in equilibrium with the fluid and takes on a magmatic-hydrothermal character (i.e., lower Al, Mn, Ti, V); 5) during ascent, magnetite, apatite and

Copper oxide/N-silicon heterojunction photovoltaic device

Science.gov (United States)

Feng, Tom; Ghosh, Amal K.

1982-01-01

A photovoltaic device having characteristics of a high efficiency solar cell comprising a Cu.sub.x O/n-Si heterojunction. The Cu.sub.x O layer is formed by heating a deposited copper layer in an oxygen containing ambient.

Sediment and carbon deposition vary among vegetation assemblages in a coastal salt marsh

Directory of Open Access Journals (Sweden)

J. J. Kelleway

2017-08-01

Full Text Available Coastal salt marshes are dynamic, intertidal ecosystems that are increasingly being recognised for their contributions to ecosystem services, including carbon (C accumulation and storage. The survival of salt marshes and their capacity to store C under rising sea levels, however, is partially reliant upon sedimentation rates and influenced by a combination of physical and biological factors. In this study, we use several complementary methods to assess short-term (days deposition and medium-term (months accretion dynamics within a single marsh that contains three salt marsh vegetation types common throughout southeastern (SE Australia.We found that surface accretion varies among vegetation assemblages, with medium-term (19 months bulk accretion rates in the upper marsh rush (Juncus assemblage (1.74 ± 0.13 mm yr−1 consistently in excess of estimated local sea-level rise (1.15 mm yr−1. Accretion rates were lower and less consistent in both the succulent (Sarcocornia, 0.78 ± 0.18 mm yr−1 and grass (Sporobolus, 0.88 ± 0.22 mm yr−1 assemblages located lower in the tidal frame. Short-term (6 days experiments showed deposition within Juncus plots to be dominated by autochthonous organic inputs with C deposition rates ranging from 1.14 ± 0.41 mg C cm−2 d−1 (neap tidal period to 2.37 ± 0.44 mg C cm−2 d−1 (spring tidal period, while minerogenic inputs and lower C deposition dominated Sarcocornia (0.10 ± 0.02 to 0.62 ± 0.08 mg C cm−2 d−1 and Sporobolus (0.17 ± 0.04 to 0.40 ± 0.07 mg C cm−2 d−1 assemblages.Elemental (C : N, isotopic (δ13C, mid-infrared (MIR and 13C nuclear magnetic resonance (NMR analyses revealed little difference in either the source or character of materials being deposited among neap versus spring tidal periods. Instead, these analyses point to substantial redistribution of materials within the Sarcocornia and

Optical Properties and Microstructure of Silver-Copper Nanoparticles Synthesized by Pulsed Laser Deposition

Science.gov (United States)

Hirai, Makoto; Kumar, Ashok

2007-12-01

Utilizing a pulsed laser deposition (PLD) method, silver-copper (Ag-Cu) nanoparticles have been synthesized by changing the surface area ratio of the target ( S R = S Cu/( S Ag + S Cu)) from 0 to 30%. The peak absorption attributed to surface plasmon resonance (SPR) increased when increasing S R up to 15%, above which it decreased. The peak shifts seem to be induced by the changes in the conductivity and morphology of the Ag-Cu nanoparticles. Additionally, the interplanar spacings of the Ag-Cu nanoparticles prepared at S R = 15% corresponded to the Ag {111}, {200}, {220}, and Cu {111} planes. However, since the interplanar spacings attributed to the Cu {200} and {220} planes were not detected, the Ag-Cu nanoparticles were believed to possess a lattice constant ( a) close not to the Cu phase ( a = 3.615 Å) but to the Ag phase ( a = 4.086 Å). Moreover, confirming the presence of Cu atoms in the nanoparticles using energy dispersive X-ray (EDX) spectra, Ag-Cu nanoparticles may be a solid solution in which Cu atoms partially replace Ag atoms in the fcc structure.

APPLICATION OF MAGNETIC SURVEY TO EXPLORE THE IRON ORE DEPOSITS IN THE NUSAWUNGU COASTAL REGENCY OF CILACAP CENTRAL JAVA

Directory of Open Access Journals (Sweden)

S Sehah

2017-12-01

Full Text Available The research aiming to explore the iron ore deposits in the Nusawungu coastal Regency of Cilacap has been conducted using the magnetic survey. The acquisition of magnetic data was conducted in April – Mei 2017, covering the area in the ranges of 109.314° – 109.345°E and 7.691° – 7.709°S. The obtained magnetic field strength data were corrected, reduced, and mapped to obtain the contour map of local magnetic anomaly. The modeling process was carried out along the path extending over the map from the positions of 109.314°E and 7.695°S to 109.335°E and 7.699°S, so that some subsurface anomalous objects are obtained. The lithological interpretation was performed to identify the types of subsurface rocks and their formations based on the magnetic susceptibility value of each anomalous objects and supported by the geological information of the research area. Based on the interpretation results, three rocks deposits of alluvium formations were obtained, which are estimated to contain iron ore. The first deposit has a length of 164.85 m, a depth of 0.57 – 8.43 m, and a magnetic susceptibility value of 0.0097 cgs. The second deposit has a length of 376.28 m, a depth of 2.56 – 19.66 m, and a magnetic susceptibility value of 0.0108 cgs. The third deposit has a length of 1,306.26 m, a depth of 3.70 – 58.69 m, and a magnetic susceptibility value of 0.0235 cgs. Out of the whole rocks deposits, the third rock deposit is interpreted to have the most prospective iron ore. This interpretation based on its high magnetic susceptibility value, which indicates the presence of many magnetic minerals (i.e. iron ores in the rock.

Atomic layer deposition of W{sub x}N/TiN and WN{sub x}C{sub y}/TiN nanolaminates

Energy Technology Data Exchange (ETDEWEB)

Elers, K.-E.; Saanila, V.; Li, W.-M.; Soininen, P.J.; Kostamo, J.T.; Haukka, S.; Juhanoja, J.; Besling, W.F.A

2003-06-23

Diffusion barrier materials, such as TiN, W{sub x}N, WN{sub x}C{sub y} and their nanolaminates were deposited by atomic layer deposition method. TiN film exhibited excellent properties, but W{sub x}N film exhibited high resistivity despite the low residue concentration. Both TiN and W{sub x}N films suffered from serious incompatibility with the copper metal. WN{sub x}C{sub y} film was deposited by introducing triethylboron as a reducing agent for tungsten. Excellent film properties were obtained, including very good compatibility with the copper metal, evident as strong adhesion and no pitting on the copper surface. Nanolaminate barrier stacks of W{sub x}N/TiN and WN{sub x}C{sub y}/TiN were successfully deposited. TiN deposition did not cause copper pitting when thin WN{sub x}C{sub y} film was deposited underneath.

Boulder coastal deposits at Favignana Island rocky coast (Sicily, Italy): Litho-structural and hydrodynamic control

Science.gov (United States)

Pepe, Fabrizio; Corradino, Marta; Parrino, Nicolò; Besio, Giovanni; Presti, Valeria Lo; Renda, Pietro; Calcagnile, Lucio; Quarta, Gianluca; Sulli, Attilio; Antonioli, Fabrizio

2018-02-01

Boulders are frequently dislodged from rock platforms, transported and deposited along coastal zones by high-magnitude storm waves or tsunamis. Their size and shape are often controlled by the thickness of bedding planes as well as by high-angle to bedding fracture network. We investigate these processes along two coastal areas of Favignana Island by integrating geological data for 81 boulders, 49 rupture surfaces (called sockets) and fracture orientation and spacing with four radiocarbon dates, numerical hydrodynamic analysis, and hindcast numerical simulation data. Boulders are scattered along the carbonate platform as isolated blocks or in small groups, which form, as a whole, a discontinuous berm. Underwater surveys also highlight free boulders with sharp edges and sockets carved out in the rock platform. Boulders are composed of ruditic- to arenitic-size clastic carbonates. Their size ranges from 0.6 to 3.7 m, 0.55 to 2.4 m, and 0.2 to 1 m on the major (A), medium (B), and minor (C) axes, respectively. The highest value of mass estimation is 12.5 t. Almost all of boulders and sockets are characterized by a tabular or bladed shape. The comparisons between a) the fractures spacing and the length of A- and B-axes, and b) the frequency peaks of C-axis with the recurrent thickness of beds measured along the coastal zone demonstrate the litho-structural control in the size and shape of joint-bounded boulders. These comparisons, together with the similarity between the shapes of the boulders and those of the sockets as well as between the lithology of boulders and the areas surrounding the sockets, suggest that blocks originate by detachment from the platform edge. Thus, the most common pre-transport setting is the joint-bounded scenario. Hydrodynamic equations estimate that the storm wave heights necessary to initiate the transport of blocks diverge from 2 m to 8 m for joint-bounded boulders and from few tens of centimeters up to 11 m for submerged boulders. The

7Be content in rainfall and soil deposition in South American coastal ecosystems

International Nuclear Information System (INIS)

Cardoso, R.; Ayub, J. Juri; Anjos, Roberto Meigikos dos; Cid, Alberto Silva; Velasco, H.

2011-01-01

soil deposition in a semiarid ecosystem at San Luis Province, central Argentina. Now, we are starting measurements in coastal ecosystems at Niteroi, southeastern Brazil. At this conference, we are going to present preliminary results on 7 Be content in rains, relationships with precipitation regime, and assess the 7 Be deposition in soil and its seasonality. (author)

Chemical bath deposited zinc sulfide buffer layers for copper indium gallium sulfur-selenide solar cells and device analysis

International Nuclear Information System (INIS)

Kundu, Sambhu; Olsen, Larry C.

2005-01-01

Cadmium-free copper indium gallium sulfur-selenide (CIGSS) thin film solar cells have been fabricated using chemical bath deposited (CBD) zinc sulfide (ZnS) buffer layers. Shell Solar Industries provided high quality CIGSS absorber layers. The use of CBD-ZnS, which is a higher band gap material than CdS, improved the quantum efficiency of fabricated cells at lower wavelengths, leading to an increase in short circuit current. The best cell to date yielded an active area (0.43 cm 2 ) efficiency of 13.3%. The effect of the ZnS buffer layer thickness on device performance was studied carefully. This paper also presents a discussion of issues relevant to the use of the CBD-ZnS buffer material for improving device performance

An experimental study of the composite CNT/copper coating

Science.gov (United States)

Panarin, Valentin Ye.; Svavil‧nyi, Nikolai Ye.; Khominich, Anastasiya I.

2018-03-01

This paper presents experimental results on the preparation and investigation of the carbon nanotubes-copper composite material. Carbon nanotubes (CNTs) were synthesized on silicon substrates by the chemical vapor deposition (CVD) method and then filled with copper by evaporation from a melting pot in a vacuum. Copper evenly covered both the surface of the entangled tubes and the free substrate surface between the tubes. To improve the adhesion of tubes and matrix material, a carbon substructure was grown on the surface of tubes by adding working gas plasma to the CNT synthesis area. It is proposed to use a copper coating as a diffusion barrier upon subsequent filling of the reinforcing CNT frame by a carbide-forming materials matrix with predetermined physico-mechanical and tribological properties.

Effects of copper precursor concentration on the growth of cupric oxide nanorods for photoelectrode using a modified chemical bath deposition method

Energy Technology Data Exchange (ETDEWEB)

Oh, Hee-bong [Department of Nano Science and Engineering, High Safety Vehicle Core Technology Research Center, Inje University, Gimhae, Gyeongnam 621-749 (Korea, Republic of); Ryu, Hyukhyun, E-mail: hhryu@inje.ac.kr [Department of Nano Science and Engineering, High Safety Vehicle Core Technology Research Center, Inje University, Gimhae, Gyeongnam 621-749 (Korea, Republic of); Lee, Won-Jae [Department of Materials and Components Engineering, Dong-Eui University, Busan 614-714 (Korea, Republic of)

2015-01-25

Highlights: • CuO nanorod photoelectrodes were prepared by modified CBD method. • The CuO nanorods were vertically grown with a high growth rate. • Effects of precursor concentration on the CuO nanorods were investigated. - Abstract: In this study, vertically aligned CuO nanorods were grown using a modified chemical bath deposition method with various copper precursor concentrations. The morphological, structural, optical and photoelectrochemical properties of the synthesized CuO samples were characterized using a field-emission scanning electron microscope, an X-ray diffractometer, a UV–visible spectrometer and a three-electrode potentiostat, respectively. The growth rates of the samples varied from 4.3 to 500 nm/min with the varying precursor concentrations. The vertically well-grown CuO nanorods exhibited one-dimensional growth along the (0 2 0) plane. We obtained a maximum photocurrent density of −1.05 mA/cm{sup 2} at −0.6 V (vs. SCE) from the CuO nanorod photoelectrode grown using the 10 mM copper precursor concentration.

Structural templating in a nonplanar phthalocyanine using single crystal copper iodide

OpenAIRE

Rochford, L. A. (Luke A.); Ramadan, Alexandra J.; Keeble, Dean S.; Ryan, Mary P.; Heutz, Sandrine; Jones, T. S. (Tim S.)

2015-01-01

Solution-grown copper iodide crystals are used as substrates for the templated growth of the nonplanar vanadyl phthalocyanine using organic molecular beam deposition. Structural characterization reveals a single molecular orientation produced by the (111) Miller plane of the copper iodide crystals. These fundamental measurements show the importance of morphology and structure in templating interactions for organic electronics applications.

Electrodeposition of copper from a copper sulfate solution using a packed-bed continuous-recirculation flow reactor at high applied electric current

Directory of Open Access Journals (Sweden)

Meshaal F. Alebrahim

2015-09-01

Full Text Available The purpose of this study is mainly to investigate the performance of a packed-bed continuous-recirculation flow reactor at high applied electric current in removing copper, Cu(II, from simulated electrolyte by electrodeposition. The effects of pHo, circulation rate of flow, initial copper concentration, intensity of the applied current and the method of application of electric current, as to have a constant value during all the time of electrolysis or to be decreased with time, on copper electrodeposition and current efficiency are revealed. The results showed that the increase in pH (provided not lead to the deposition of Cu(OH2, initial concentration of the copper and flow rate increased the electrodeposition of copper as well as improved current efficiency. However, increasing intensity of the applied electric current led to an increase in the electrodeposition of copper and decreased electrical efficiency. It was also observed that reducing the intensity of applied electric current with time during the electrolysis process while maintaining other operating variables constant led to a significant reduction in the consumption of electrical energy used in the process of copper removal by electrodeposition; a reduction of 41.6% could be achieved.

Micas at magmatic and hydrothermal stages in the environment of the Cerro Verde Santa Rosa porphyry copper type deposit

Energy Technology Data Exchange (ETDEWEB)

Le Bel, L

1979-01-01

The chemical composition of biotites and sericites from the Cerro Verde porphyry copper type deposit have been investigated in detail, using an electron microprobe. The main results of the study are: Al/sup vi/ and Ti contents of biotites of magmatic as well as hydrothermal origin may be related to the temperature of crystallization estimed by independent methods. On the other hand the Mg/Fe and Mg/(Mg + Fe) ratios are almost constant. This fact is interpreted in terms of fO/sub 2/; sericites have a phengitic composition in which the solubilities of the two end-members celadonite and paragonite are controlled by a fluid phase under P, T conditions that could be estimated.

Superhydrophobic Cu{sub 2}S@Cu{sub 2}O film on copper surface fabricated by a facile chemical bath deposition method and its application in oil-water separation

Energy Technology Data Exchange (ETDEWEB)

Pi, Pihui, E-mail: phpi@scut.edu.cn; Hou, Kun; Zhou, Cailong; Li, Guidong; Wen, Xiufang; Xu, Shouping; Cheng, Jiang; Wang, Shuangfeng

2017-02-28

Highlights: • A superhydrophobic film with macro/nano structure was fabricated on copper surface. • The as-prepared film shows outstanding water repellency and long-term storage stability. • The same method was used to fabricate superhydrophobic/superoleophilic copper mesh. • The obtained mesh could realize separation of various oily sewages with separation efficiency above 94%. - Abstract: Cu{sub 2}S and Cu{sub 2}O composite (Cu{sub 2}S@Cu{sub 2}O) film with micro/nano binary structure was created on copper surface using the mixing solution of sodium thiosulphate and copper sulfate by a facile chemical bath deposition method. After modification with low-cost polydimethylsioxane (PDMS), the superhydrophobic Cu{sub 2}S@Cu{sub 2}O film was obtained. The as-prepared film shows outstanding water repellency with a water contact angle larger than 150° and long-term storage stability. The geometric morphology and chemical composition of the film were characterized by scanning electron microscope (SEM), energy dispersive spectrometer (EDS) and attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), respectively. Moreover, the same method was used to fabricate superhydrophobic/superoleophilic copper mesh, and it could realize separation of various oily sewages with separation efficiency above 94%. This strategy has potential to fabricate the practical superhydrophobic Cu{sub 2}S@Cu{sub 2}O film on copper surface on a large scale due to its simplicity and low cost.

Biological response to coastal upwelling and dust deposition in the area off Northwest Africa

Science.gov (United States)

Ohde, T.; Siegel, H.

2010-05-01

Nutrient supply in the area off Northwest Africa is mainly regulated by two processes, coastal upwelling and deposition of Saharan dust. In the present study, both processes were analyzed and evaluated by different methods, including cross-correlation, multiple correlation, and event statistics, using remotely sensed proxies of the period from 2000 to 2008 to investigate their influence on the marine environment. The remotely sensed chlorophyll- a concentration was used as a proxy for the phytoplankton biomass stimulated by nutrient supply into the euphotic zone from deeper water layers and from the atmosphere. Satellite-derived alongshore wind stress and sea-surface temperature were applied as proxies for the strength and reflection of coastal upwelling processes. The westward wind and the dust component of the aerosol optical depth describe the transport direction of atmospheric dust and the atmospheric dust column load. Alongshore wind stress and induced upwelling processes were most significantly responsible for the surface chlorophyll- a variability, accounting for about 24% of the total variance, mainly in the winter and spring due to the strong north-easterly trade winds. The remotely sensed proxies allowed determination of time lags between biological response and its forcing processes. A delay of up to 16 days in the surface chlorophyll- a concentration due to the alongshore wind stress was determined in the northern winter and spring. Although input of atmospheric iron by dust storms can stimulate new phytoplankton production in the study area, only 5% of the surface chlorophyll- a variability could be ascribed to the dust component in the aerosol optical depth. All strong desert storms were identified by an event statistics in the time period from 2000 to 2008. The 57 strong storms were studied in relation to their biological response. Six events were clearly detected in which an increase of chlorophyll- a was caused by Saharan dust input and not by

PROMETHEE II: A knowledge-driven method for copper exploration

Science.gov (United States)

Abedi, Maysam; Ali Torabi, S.; Norouzi, Gholam-Hossain; Hamzeh, Mohammad; Elyasi, Gholam-Reza

2012-09-01

This paper describes the application of a well-known Multi Criteria Decision Making (MCDM) technique called Preference Ranking Organization METHod for Enrichment Evaluation (PROMETHEE II) to explore porphyry copper deposits. Various raster-based evidential layers involving geological, geophysical, and geochemical geo-datasets are integrated to prepare a mineral prospectivity mapping (MPM). In a case study, thirteen layers of the Now Chun copper deposit located in the Kerman province of Iran are used to explore the region of interest. The PROMETHEE II technique is applied to produce the desired MPM, and the outputs are validated using twenty-one boreholes that have been classified into five classes. This proposed method shows a high performance when providing the MPM while reducing the cost of exploratory drilling in the study area.

Cu-Doped ZnO Thin Films Deposited by a Sol-Gel Process Using Two Copper Precursors: Gas-Sensing Performance in a Propane Atmosphere

Directory of Open Access Journals (Sweden)

Heberto Gómez-Pozos

2016-01-01

Full Text Available A study on the propane gas-sensing properties of Cu-doped ZnO thin films is presented in this work. The films were deposited on glass substrates by sol-gel and dip coating methods, using zinc acetate as a zinc precursor, copper acetate and copper chloride as precursors for doping. For higher sensitivity values, two film thickness values are controlled by the six and eight dippings, whereas for doping, three dippings were used, irrespective of the Cu precursor. The film structure was analyzed by X-ray diffractometry, and the analysis of the surface morphology and film composition was made through scanning electron microscopy (SEM and secondary ion mass spectroscopy (SIMS, respectively. The sensing properties of Cu-doped ZnO thin films were then characterized in a propane atmosphere, C3H8, at different concentration levels and different operation temperatures of 100, 200 and 300 °C. Cu-doped ZnO films doped with copper chloride presented the highest sensitivity of approximately 6 × 104, confirming a strong dependence on the dopant precursor type. The results obtained in this work show that the use of Cu as a dopant in ZnO films processed by sol-gel produces excellent catalysts for sensing C3H8 gas.

Corrosion of copper alloys in sulphide containing district heting systems

DEFF Research Database (Denmark)

Thorarinsdottir, R.I.; Maahn, Ernst Emanuel

1999-01-01

Copper and some copper alloys are prone to corrosion in sulphide containing geothermal water analogous to corrosion observed in district heating systems containing sulphide due to sulphate reducing bacteria. In order to study the corrosion of copper alloys under practical conditions a test...... was carried out at four sites in the Reykjavik District Heating System. The geothermal water chemistry is different at each site. The corrosion rate and the amount and chemical composition of deposits on weight loss coupons of six different copper alloys are described after exposure of 12 and 18 months......, respectively. Some major differences in scaling composition and the degree of corrosion attack are observed between alloys and water types....

A CRITICAL REVIEW AND EVALUATION OF APPLYING SEMI-VOLATILE ORGANIC COMPOUNDS (SVOCS AS A GEOCHEMICAL TRACER TO INDICATE TSUNAMI BACKWASH: The Bilateral, Deutsche Forschungsgemeinschaft (DFG and National Research Council of Thailand (NRCT Funded Project “Tsunami Deposits in Near-Shore- and Coastal Waters of Thailand (TUNWAT”

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Siwatt Pongpiachan

2013-10-01

Full Text Available Tsunamis symbolize one of the most harmful natural disasters for low-lying coastal zones and their residents, due to both its destructive power and irregularity. The 2004 Boxing Day tsunami, which attack the Andaman Sea coast of Thailand, resulted 5,395 of deaths and inestimable casualties, interrupted economies and social well-being in numerous coastal villages and caused in extreme alterations of both onshore and offshore coastal morphology. The Great Indian Ocean tsunami also highlighted that there are many missing jigsaw puzzle pieces in scientific knowledge, starting from the generating of tsunamis offshore to the countless influences to the marine ecosystems on the continental shelf, coastal areas and on land and to the economic and social systems consequences. As with all deposits that do not have a direct physical link to their causative sources, marine tsunami deposits must be distinguished from other deposits through regional correlation, dating and criteria for recognition within the deposits themselves. This study aims to provide comprehensive reviews on using Polycyclic Aromatic Hydrocarbons (PAHs as a chemical proxy to discriminate tsunami relateddeposits from typical marine sediments. The advantages and disadvantages of this chemical tracer will be critically reviewed and further discussed.

Experimental Study of Nonequilibrium Electrodeposition of Nanostructures on Copper and Nickel for Photochemical Fuel Cell Application

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Rajesh K. Shanmugam

2011-01-01

Full Text Available To increase the performance of photochemical fuel cells, nonequilibrium electrodeposition has been performed on Cu and Ni to make photosensitive anodes. Processing parameters including electrolyte concentration, and electrode potential were studied using cyclic voltammetry. Scanning electron microscopy (SEM and X-ray Spectroscopy (EDS were performed to understand the formation of the nanostructures during the nonequilibrium deposition of copper fractals. An increase in the deposition rate was observed with the increase in electrolyte concentration (from 0.05 M to 1.0 M. Similar trend was found when the cathode potential was decreased from −0.5 V to −4.5 V. The effect of substrate material was also examined. Porous fractal structures on copper were achieved, while the deposited material showed high density of surface cracks on nickel. The fractal structures deposited on copper electrode with the increased surface area were converted into copper oxide by oxidation in air. Such oxide samples were made into anodes for photochemical fuel cell application. We demonstrated that an increase in the magnitude of open circuit output voltage is associated with the increase in the fractal surface area under the ultraviolet irradiation test conditions. However, the electrodeposited fractals on nickel showed very limited increase in the magnitude of open circuit voltage.

Investigation of interdiffusion in copper-nickel bilayer thin films

Energy Technology Data Exchange (ETDEWEB)

Abdul-Lettif, Ahmed M. [Physics Department, College of Science, Babylon University, Hilla (Iraq)]. E-mail: abdullettif@yahoo.com

2007-01-15

Auger depth profiling technique and X-ray diffraction analysis have been employed to study the interdiffusion in vacuum-deposited copper-nickel bilayer thin films. An adaptation of the Whipple model was used to determine the diffusion coefficients of both nickel in copper and copper in nickel. The calculated diffusion coefficient is (2.0x10{sup -7} cm{sup 2}/s)exp(-1.0 eV/kT) for nickel in copper, and (6x10{sup -8} cm{sup 2}/s)exp(-0.98 eV/kT) for copper in nickel. The difference between the diffusion parameters obtained in the present work and those extracted by other investigators is attributed essentially to the difference in the films microstructure and to the annealing ambient. It is concluded that interdiffusion in the investigated films is described by type-B kinetics in which rapid grain-boundary diffusion is coupled to defect-enhanced diffusion into the grain interior. The present data raise a question about the effectiveness of nickel as a diffusion barrier between copper and the silicon substrate.

Is a high serum copper concentration a risk factor for implantation failure?

Science.gov (United States)

Matsubayashi, Hidehiko; Kitaya, Kotaro; Yamaguchi, Kohei; Nishiyama, Rie; Takaya, Yukiko; Ishikawa, Tomomoto

2017-08-10

Copper-containing contraceptive devices may deposit copper ions in the endometrium, resulting in implantation failure. The deposition of copper ions in many organs has been reported in patients with untreated Wilson's disease. Since these patients sometimes exhibit subfertility and/or early pregnancy loss, copper ions were also considered to accumulate in the uterine endometrium. Wilson's disease patients treated with zinc successfully delivered babies because zinc interfered with the absorption of copper from the gastrointestinal tract. These findings led to the hypothesis that infertile patients with high serum copper concentrations may have implantation failure due to the excess accumulation of copper ions. The relationship between implantation (pregnancy) rates and serum copper concentrations has not yet been examined. The Japanese government recently stated that actual copper intake was higher among Japanese than needed. Therefore, the aim of the present study was to investigate whether serum copper concentrations are related to the implantation (pregnancy) rates of human embryos in vivo. We included 269 patients (age copper, and zinc concentrations were measured 16 days after the first date of progesterone replacement. We compared 96 women who were pregnant without miscarriage at 10 weeks of gestation (group P) and 173 women who were not pregnant (group NP). No significant differences were observed in age or BMI between the groups. Copper concentrations were significantly higher in group NP (average 193.2 μg/dL) than in group P (average 178.1 μg/dL). According to the area under the curve (AUC) on the receiver operating characteristic curve for the prediction of clinical pregnancy rates, the Cu/Zn ratio (AUC 0.64, 95% CI 0.54-0.71) was a better predictor than copper or zinc. When we set the cut-off as 1.59/1.60 for the Cu/Zn ratio, sensitivity, specificity, the positive predictive value, and negative predictive value were 0.98, 0.29, 0.71, and 0

Influence of electric current intensity on the performance of electroformed copper liner for shaped charge application

Directory of Open Access Journals (Sweden)

Tamer Elshenawy

2017-12-01

Full Text Available Electrolytic Copper used in the shaped charge liner manufacturing can be produced from acid solution using electro-deposition technique. The intensity of the applied electric current controls the quality of the produced copper grade. The electric current intensity within the electrolytic acidic solution cell with the minimum oxygen and sulfur elements in the produced copper was optimized and found to be 30–40 A/Ft2. The elemental composition of the obtained electrolytic copper was determined using high-end stationary vacuum spectrometer, while the oxygen was determined precisely using ELTRA ONH-2000 apparatus. Besides, SEM was used to investigate the shape of the copper texture inside the deposited layers and to determine the average grain size. New relations have been obtained between the applied current intensity and both the oxygen and sulfur contents and the average grain size of the produced copper. Experimental result showed that when the applied current density increases to a certain limit, the oxygen and sulfur content in the electrolytic copper decreases. Performance of the produced copper liner was investigated by the static firing of a small caliber shaped charge containing an electro-formed copper liners, where the penetration depth of the optimized electrolytic liner was enhanced by 22.7% compared to that of baseline non-optimized liner.

Magmatic context of Bou Skour copper deposit (Eastern Anti-Atlas, Morocco): Petrogrography, geochemistry and alterations

Science.gov (United States)

EL Azmi, Daoud; Aissa, M.; Ouguir, H.; Mahdoudi, M. L.; El Azmi, M.; Ouadjo, A.; Zouhair, M.

2014-09-01

The Bou Skour copper deposit is located in the western part of the Saghro massif (Eastern Anti-Atlas), about 50 km East of the city of Ouarzazate. It is subdivided into several areas that are, from North to South: “Panthère”, “Chaigne”, “Anne Marie”, “Chapeau de fer” and “Patte d'Oie”. The latter is economically the most important and is the object of this study. The “Patte d'Oie” district consists mainly of extrusive and intrusive igneous rocks. The extrusive rocks are represented by andesites spatially associated with pyroclastic terms (ignimbrites and pyroclastic breccias). This volcanic unit is intruded by a pink granite pluton and a I-type granodiorite with equigranular texture (Bou Skour granodiorite) showing to the border a microgranular facies (microgranodiorite). All these magmatic formations are intersected by rhyolitic dykes (NNE-SSW) and doleritic dykes (WNW-ESE to NW-SE). The granodiorite and andesite have undergone a polyphase hydrothermal alteration: (i) potassic alteration, (ii) phyllitic alteration, (iii) silicification, (iv) argillic alteration and (v) propylitic alteration. The analysis of geochemical data of granodiorite, granite, andesite and dolerite confirmed: (i) their petrographic natures, (ii) the medium-K calc-alkaline affiliation of andesite and granodiorite, which would have been set up into an active geotectonic environment, probably of island arc or collision, during the Pan-African orogeny, (iii) The high-K calc-alkaline character of granite indicating a post-collision development during the Pan-African orogeny and (iv) The alkaline affinity of the dolerite which is linked to an extensive post-orogenic setting (post-Pan-African). The copper mineralization of “Patte d'Oie” area is hosted, exclusively, in the andesitic and granodioritic facies. It is represented, essentially, by chalcopyrite and bornite minerals and is, probably, related to a porphyry system (disseminated and stockwork mineralization

Late Pleistocene dune-sourced alluvial fans in coastal settings: Sedimentary facies and related processes (Mallorca, Western Mediterranean)

Science.gov (United States)

Pomar, F.; del Valle, L.; Fornós, J. J.; Gómez-Pujol, L.

2018-05-01

Aeolian-alluvial sedimentary interaction results in the formation of deposits characterized by typical alluvial sedimentary structures, but is composed of conspicuous amounts of aeolian sediments. The literature on this topic is limited and most works relate more with continental aeolian dunes or fluvial dune interference with fan bodies. Furthermore, there is a lack of examples of aeolian-alluvial sedimentary interference in coastal settings. In the western Mediterranean, there are many Pleistocene alluvial fan deposits built up partly by sediment originating from coastal dunes dismantled by alluvial streams. Very often, these deposits show a continuous sedimentary sequence through which we can derive the contribution and predominance of coastal, alluvial-colluvial and aeolian processes and their controls on landscape formation. This is an outstanding feature within coastal systems since it shows marine sediments reworked and integrated within coastal dune fields by aeolian transport, and the latter built up into alluvial fan bodies. In this sense, aeolian-alluvial interaction is the geomorphic-sedimentary expression of the coexistence and overlapping of alluvial and aeolian environments resulting in deposits sharing sedimentary features from both environments. The aim of this paper is to unravel the contribution of coastal dunes in the construction of alluvial fans bodies and identify the main sedimentary facies that constitute these deposits, as well as their climatic controls. For this reason, Es Caló fan (northern Mallorca) has been selected due to its well-exposed deposits exhibiting the alternation of aeolian, alluvial and colluvial deposits. Sedimentological and stratigraphic analyses based on 33 logs and complementary analyses demonstrate that most of the facies constituting the fan body are made up completely of marine bioclastic sands. These deposits record an alluvial fan sedimentary environment characterized by sediments inputs that do not proceed

The influence of sea-level changes on tropical coastal lowlands; the Pleistocene Coropina Formation, Suriname

Science.gov (United States)

Wong, Th. E.; de Kramer, R.; de Boer, P. L.; Langereis, C.; Sew-A-Tjon, J.

2009-04-01

The Pleistocene Coropina Formation largely constitutes the Old Coastal Plain of Suriname. It is exposed fully only in open-pit bauxite mines in the central coastal plain as part of the unconsolidated overburden of Paleocene-Eocene bauxites. This study deals with the stratigraphy, sedimentology and chronology of this formation, and is based on a study in the recently closed Lelydorp-III bauxite mine operated by N.V. BHP Billiton Maatschappij Suriname. The Coropina Formation consists of the Para and Lelydorp Members. We present a detailed lithological subdivision of these members. In the Para Member, four units are discerned which are grouped in two transgressive cycles, both ranging upward from terrestrial towards chenier and coastal mudflat deposits reflecting glacio-eustatic sea-level changes. The sandy sediments represent fluviatile and beach-bar (chenier) deposits, and were supplied by rivers from the Precambrian basement and to a lesser extent by westward longshore coastal drift. Clays, largely derived from the Amazon River and transported alongshore over the shelf, were deposited in extensive coastal mudflats. The Lelydorp Member, also comprising four units, represents a depositional system that is closely comparable to the recent Suriname coastal setting, i.e., a lateral and vertical alternation of mudflat and chenier deposits formed over a period characterised by more or less constant sea level. Palaeomagnetic data indicate a dominantly reversed magnetic polarity in the Para Member, whereas the Lelydorp Member shows a normal magnetic polarity with a minor reversed polarity overprint. The reversed polarities of the Para Member exclude a Brunhes Chron (0.78-0.0 Ma) age, and thus assign it to the Matuyama Chron (2.58-0.78 Ma). This implies that the Coropina Formation is much older than hitherto assumed, and that one or more (long-term) hiatuses are not recognizable in the lithological succession.

Thermally driven self-healing using copper nanofiber heater

Science.gov (United States)

Lee, Min Wook; Jo, Hong Seok; Yoon, Sam S.; Yarin, Alexander L.

2017-07-01

Nano-textured transparent heaters made of copper nanofibers (CuNFs) are used to facilitate accelerated self-healing of bromobutyl rubber (BIIR). The heater and BIIR layer are separately deposited on each side of a transparent flexible polyethylene terephthalate (PET) substrate. A pre-notched crack on the BIIR layer was bridged due to heating facilitated by CuNFs. In the corrosion test, a cracked BIIR layer covered a steel substrate. An accelerated self-healing of the crack due to the transparent copper nanofiber heater facilitated an anti-corrosion protective effect of the BIIR layer.

A deposit model for carbonatite and peralkaline intrusion-related rare earth element deposits: Chapter J in Mineral deposit models for resource assessment

Science.gov (United States)

Verplanck, Philip L.; Van Gosen, Bradley S.; Seal, Robert R.; McCafferty, Anne E.

2014-01-01

Carbonatite and alkaline intrusive complexes, as well as their weathering products, are the primary sources of rare earth elements. A wide variety of other commodities have been exploited from carbonatites and alkaline igneous rocks including niobium, phosphate, titanium, vermiculite, barite, fluorite, copper, calcite, and zirconium. Other elements enriched in these deposits include manganese, strontium, tantalum, thorium, vanadium, and uranium. Carbonatite and peralkaline intrusion-related rare earth element deposits are presented together in this report because of the spatial, and potentially genetic, association between carbonatite and alkaline rocks. Although these rock types occur together at many locations, carbonatite and peralkaline intrusion-related rare earth element deposits are not generally found together.

Optical characterization of directly deposited graphene on a dielectric substrate

DEFF Research Database (Denmark)

Kaplas, Tommi; Karvonen, Lasse; Ahmadi, Sepehr

2016-01-01

By using scanning multiphoton microscopy we compare the nonlinear optical properties of the directly deposited and transferred to the dielectric substrate graphene. The direct deposition of graphene on oxidized silicon wafer was done by utilizing sacrificial copper catalyst film. We demonstrate...

High rate deposition of thin film cadmium sulphide by pulsed direct current magnetron sputtering

Energy Technology Data Exchange (ETDEWEB)

Lisco, F., E-mail: F.Lisco@lboro.ac.uk [Centre for Renewable Energy Systems Technology (CREST), School of Electronic, Electrical and Systems Engineering, Loughborough University, Leicestershire LE11 3TU (United Kingdom); Kaminski, P.M.; Abbas, A.; Bowers, J.W.; Claudio, G. [Centre for Renewable Energy Systems Technology (CREST), School of Electronic, Electrical and Systems Engineering, Loughborough University, Leicestershire LE11 3TU (United Kingdom); Losurdo, M. [Institute of Inorganic Methodologies and of Plasmas, IMIP-CNR, via Orabona 4, 70126 Bari (Italy); Walls, J.M. [Centre for Renewable Energy Systems Technology (CREST), School of Electronic, Electrical and Systems Engineering, Loughborough University, Leicestershire LE11 3TU (United Kingdom)

2015-01-01

Cadmium Sulphide (CdS) is an important n-type semiconductor widely used as a window layer in thin film photovoltaics Copper Indium Selenide, Copper Indium Gallium (di)Selenide, Copper Zinc Tin Sulphide and Cadmium Telluride (CdTe). Cadmium Sulphide has been deposited using a number of techniques but these techniques can be slow (chemical bath deposition and Radio Frequency sputtering) or the uniformity and the control of thickness can be relatively difficult (close space sublimation). In this paper we report on the development of a process using pulsed Direct Current magnetron sputtering which allows nanometre control of thin film thickness using time only. The CdS thin films deposited in this process are highly uniform and smooth. They exhibit the preferred hexagonal structure at room temperature deposition and they have excellent optical properties. Importantly, the process is highly stable despite the use of a semi-insulating magnetron target. Moreover, the process is very fast. The deposition rate using 1.5 kW of power to a 6-inch circular magnetron was measured to be greater than 8 nm/s. This makes the process suitable for industrial deployment. - Highlights: • Pulsed DC magnetron sputtering of CdS • High deposition rate deposition • Uniform, pinhole free films.

High rate deposition of thin film cadmium sulphide by pulsed direct current magnetron sputtering

International Nuclear Information System (INIS)

Lisco, F.; Kaminski, P.M.; Abbas, A.; Bowers, J.W.; Claudio, G.; Losurdo, M.; Walls, J.M.

2015-01-01

Cadmium Sulphide (CdS) is an important n-type semiconductor widely used as a window layer in thin film photovoltaics Copper Indium Selenide, Copper Indium Gallium (di)Selenide, Copper Zinc Tin Sulphide and Cadmium Telluride (CdTe). Cadmium Sulphide has been deposited using a number of techniques but these techniques can be slow (chemical bath deposition and Radio Frequency sputtering) or the uniformity and the control of thickness can be relatively difficult (close space sublimation). In this paper we report on the development of a process using pulsed Direct Current magnetron sputtering which allows nanometre control of thin film thickness using time only. The CdS thin films deposited in this process are highly uniform and smooth. They exhibit the preferred hexagonal structure at room temperature deposition and they have excellent optical properties. Importantly, the process is highly stable despite the use of a semi-insulating magnetron target. Moreover, the process is very fast. The deposition rate using 1.5 kW of power to a 6-inch circular magnetron was measured to be greater than 8 nm/s. This makes the process suitable for industrial deployment. - Highlights: • Pulsed DC magnetron sputtering of CdS • High deposition rate deposition • Uniform, pinhole free films

Dry air effects on the copper oxides sensitive layers formation for ethanol vapor detection

International Nuclear Information System (INIS)

Labidi, A.; Bejaoui, A.; Ouali, H.; Akkari, F. Chaffar; Hajjaji, A.; Gaidi, M.; Kanzari, M.; Bessais, B.; Maaref, M.

2011-01-01

The copper oxide films have been deposited by thermal evaporation and annealed under ambient air and dry air respectively, at different temperatures. The structural characteristics of the films were investigated by X-ray diffraction. They showed the presences of two hydroxy-carbonate minerals of copper for annealing temperatures below 250 deg. C. Above this temperature the conductivity measurements during the annealing process, show a transition phase from metallic copper to copper oxides. The copper oxides sensitivity toward ethanol were performed using conductivity measurements at the working temperature of 200 deg. C. A decrease of conductivity was observed under ethanol vapor, showing the p-type semi-conducting characters of obtained copper oxide films. It was found that the sensing properties of copper oxide toward ethanol depend mainly on the annealing conditions. The best responses were obtained with copper layers annealed under dry air.

Dry air effects on the copper oxides sensitive layers formation for ethanol vapor detection

Energy Technology Data Exchange (ETDEWEB)

Labidi, A., E-mail: Ahmed_laabidi@yahoo.fr [URPSC (UR 99/13-18) Unite de Recherche de Physique des Semiconducteurs et Capteurs, IPEST, Universite de Carthage, BP 51, La Marsa 2070, Tunis (Tunisia); Bejaoui, A.; Ouali, H. [URPSC (UR 99/13-18) Unite de Recherche de Physique des Semiconducteurs et Capteurs, IPEST, Universite de Carthage, BP 51, La Marsa 2070, Tunis (Tunisia); Akkari, F. Chaffar [Laboratoire de Photovoltaique et Materiaux Semi-conducteurs, ENIT, Universite de Tunis el Manar, BP 37, Le belvedere 1002, Tunis (Tunisia); Hajjaji, A.; Gaidi, M. [Laboratoire de Photovoltaique, Centre de Recherches et de technologies de l' energie, Technopole de Borj-Cedria, BP 95, 2050 Hammam-Lif (Tunisia); Kanzari, M. [Laboratoire de Photovoltaique et Materiaux Semi-conducteurs, ENIT, Universite de Tunis el Manar, BP 37, Le belvedere 1002, Tunis (Tunisia); Bessais, B. [Laboratoire de Photovoltaique, Centre de Recherches et de technologies de l' energie, Technopole de Borj-Cedria, BP 95, 2050 Hammam-Lif (Tunisia); Maaref, M. [URPSC (UR 99/13-18) Unite de Recherche de Physique des Semiconducteurs et Capteurs, IPEST, Universite de Carthage, BP 51, La Marsa 2070, Tunis (Tunisia)

2011-09-15

The copper oxide films have been deposited by thermal evaporation and annealed under ambient air and dry air respectively, at different temperatures. The structural characteristics of the films were investigated by X-ray diffraction. They showed the presences of two hydroxy-carbonate minerals of copper for annealing temperatures below 250 deg. C. Above this temperature the conductivity measurements during the annealing process, show a transition phase from metallic copper to copper oxides. The copper oxides sensitivity toward ethanol were performed using conductivity measurements at the working temperature of 200 deg. C. A decrease of conductivity was observed under ethanol vapor, showing the p-type semi-conducting characters of obtained copper oxide films. It was found that the sensing properties of copper oxide toward ethanol depend mainly on the annealing conditions. The best responses were obtained with copper layers annealed under dry air.

Effects of copper on development and survival rate of Paphia malabarica Chemnitz larvae under low saline condition

Digital Repository Service at National Institute of Oceanography (India)

Gireesh, R.; Gopinathan, C.P.

-mail: girmsr@gmail.com Introduction Salinity is an important abiotic factor that lim- its growth and survival of marine organisms, es- pecially in coastal waters where light dependant sessile invertebrates inhabits. Copper is an anthro- pogenic pollutant known... to be harmful in aquatic environment and several sources such as coastal runoffs and anti-fouling paint affects non-target organisms (Peters et al. 1997). Short neck clam, Paphia malabarica (Family: Veneridae) is widely distributed in the Vembanad Lake...

Eco-friendly copper recovery process from waste printed circuit boards using Fe{sup 3+}/Fe{sup 2+} redox system

Energy Technology Data Exchange (ETDEWEB)

Fogarasi, Szabolcs [Babeş-Bolyai University, Faculty of Chemistry and Chemical Engineering, 11 Arany Janos Street, Cluj-Napoca RO-400028 (Romania); Imre-Lucaci, Florica [Babeş-Bolyai University, Interdisciplinary Research Institute on Bio-Nano-Sciences, 42 Treboniu Laurian Street, Cluj-Napoca RO-400271 (Romania); Egedy, Attila [University of Pannonia, Department of Process Engineering, Egyetem Str. 10, H-8200 Veszprém (Hungary); Imre-Lucaci, Árpád, E-mail: aimre@chem.ubbcluj.ro [Babeş-Bolyai University, Faculty of Chemistry and Chemical Engineering, 11 Arany Janos Street, Cluj-Napoca RO-400028 (Romania); Ilea, Petru [Babeş-Bolyai University, Faculty of Chemistry and Chemical Engineering, 11 Arany Janos Street, Cluj-Napoca RO-400028 (Romania)

2015-06-15

Highlights: • We developed an ecofriendly mediated electrochemical process for copper recovery. • The recovery of copper was achieved without mechanical pretreatment of the samples. • We identified the optimal flow rate for the leaching and electrowinning of copper. • The copper content of the obtained cathodic deposits was over 99.9%. - Abstract: The present study aimed at developing an original and environmentally friendly process for the recovery of copper from waste printed circuit boards (WPCBs) by chemical dissolution with Fe{sup 3+} combined with the simultaneous electrowinning of copper and oxidant regeneration. The recovery of copper was achieved in an original set-up consisting of a three chamber electrochemical reactor (ER) connected in series with a chemical reactor (CR) equipped with a perforated rotating drum. Several experiments were performed in order to identify the optimal flow rate for the dissolution of copper in the CR and to ensure the lowest energy consumption for copper electrodeposition in the ER. The optimal hydrodynamic conditions were provided at 400 mL/min, leading to the 75% dissolution of metals and to a low specific energy consumption of 1.59 kW h/kg Cu for the electrodeposition process. In most experiments, the copper content of the obtained cathodic deposits was over 99.9%.

Advances in copper-chalcopyrite thin films for solar energy conversion

Energy Technology Data Exchange (ETDEWEB)

Kaneshiro, Jess; Gaillard, Nicolas; Rocheleau, Richard; Miller, Eric [Hawaii Natural Energy Institute, University of Hawaii at Manoa, 1680 East-West Road, Post 109, Honolulu, HI 96822 (United States)

2010-01-15

Promising alternatives to crystalline silicon as the basic building block of solar cells include copper-chalcopyrite thin films such as copper indium gallium diselenide, a class of thin films exhibiting bandgap-tunable semiconductor behavior, direct bandgaps and high absorption coefficients. These properties allow for the development of novel solar-energy conversion configurations like ultra-high efficiency multi-junction solar cells utilizing combinations of photovoltaic and photoelectrochemical junctions for hydrogen production. This paper discusses the current worldwide status as well as the development and optimization of copper-chalcopyrite thin films deposited onto various substrate types for different photovoltaic and photoelectrochemical applications at the Hawaii Natural Energy Institute. (author)

The investigation on physico-chemical conditions of sulfides and sulfates based on petrographic and sulfur - oxygen stable isotope studies from the Darreh-Zar porphyry copper deposit, Kerman

Directory of Open Access Journals (Sweden)

Anis Parsapoor

2014-04-01

Full Text Available The Darreh-Zar porphyry copper deposit, located in the Urumieh – Dokhtar magmatic belt, lies about 10 km southeast of Sar-Cheshmeh porphyry copper deposit. The ore body with hydrothermally altered zones including potassic, chlorite-sericite, sericite, argillic and propylitic all related to the Darreh-Zar porphyry stock intruded the Eocene volcanic rocks. Pyrite, chalcopyrite, molybdenite, with different textures as disseminated and veinlet, are the major sulfide minerals and chalcocite and covellite are considered as the secondary minerals. Sulfur isotopic composition of the sulfates and sulfides studied fall on the magmatic values. Two different origins may be suggested for the gypsums studied: 1- hydration of anhydrite and 2- oxidation of pyrite during supergene enrichment. The stable isotopic data calculated on couple minerals (pyrite-anhydrite point to the formation temperature of about 485-515οC for the fluids involved in mineralization. The fluid responsible for mineralization suggests magmatic sources for all sulfide phases and reduced aqueous sulfur species. Isotopic zoning, based on the δ34S pyrite values, divided the area into the east and the west parts with negative and positive correlation against the depth, respectively. Also, a negative correlation is observed between the Cu and the δ34S in the eastern portion of the area.

Microdistribution of copper-carbonate and iron oxide nanoparticles in treated wood

Energy Technology Data Exchange (ETDEWEB)

Matsunaga, Hiroshi, E-mail: mhiroshi@ffpri.affrc.go.jp; Kiguchi, Makoto [Forestry and Forest Products Research Institute (Japan); Evans, Philip D. [University of British Columbia, Centre for Advanced Wood Processing (Canada)

2009-07-15

Aqueous dispersions of copper-carbonate nanoparticles and microparticles have just begun to be exploited commercially for the preservative treatment of wood. The success of the new systems will depend, in part, on the uniform distribution of the preservative in wood and the ability of copper to penetrate cell walls. We examined the distribution of copper in wood treated with a nano-Cu preservative. Copper particles are not uniformly distributed in treated wood, but they accumulate in voids that act as the flow paths for liquids in wood. Particles are deposited on, but not within cell walls. Nevertheless, elemental copper is present within cell walls, but at a lower level than that in wood treated with a conventional wood preservative. These findings suggest that nano-Cu preservatives are able to deliver bioactive components into wood cell walls even though the majority of copper particles are too large to penetrate the cell wall's nanocapillary network.

Improved field emission performance of carbon nanotube by introducing copper metallic particles

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Chen Yiren

2011-01-01

Full Text Available Abstract To improve the field emission performance of carbon nanotubes (CNTs, a simple and low-cost method was adopted in this article. We introduced copper particles for decorating the CNTs so as to form copper particle-CNT composites. The composites were fabricated by electrophoretic deposition technique which produced copper metallic particles localized on the outer wall of CNTs and deposited them onto indium tin oxide (ITO electrode. The results showed that the conductivity increased from 10-5 to 4 × 10-5 S while the turn-on field was reduced from 3.4 to 2.2 V/μm. Moreover, the field emission current tended to be undiminished after continuous emission for 24 h. The reasons were summarized that introducing copper metallic particles to decorate CNTs could increase the surface roughness of the CNTs which was beneficial to field emission, restrain field emission current from saturating when the applied electric field was above the critical field. In addition, it could also improve the electrical contact by increasing the contact area between CNT and ITO electrode that was beneficial to the electron transport and avoided instable electron emission caused by thermal injury of CNTs.

Influence of copper on the by-products of different oil-paper insulations

International Nuclear Information System (INIS)

Hao Jian; Liao Ruijin; Chen, George; Ma Chao

2011-01-01

Transformer failure caused by the corrosion of copper material in transformer attracts great attention of researchers and engineers. In this paper, Karamay No. 25 naphthenic mineral oil, Karamay No. 25 paraffinic mineral oil, Kraft paper and copper were used to compose four combinations of oil-paper insulation samples. The ageing by-products and dielectric properties of the four combinations of oil-paper insulation samples were compared after they were thermally aged at 130 deg. C. The influence of copper on the by-products and dielectric properties of different oil-paper insulations was obtained. The results show that copper can accelerate the ageing rate of insulation oils and reduce their AC breakdown voltage. The content of copper substance dissolved in insulating oil increases with ageing time at first and then decreases. The paper aged in the oil-paper insulation sample with copper has higher moisture content than the one without copper. Results of energy dispersive spectroscopy (EDS) in the scanning electron microscope (SEM) show that there is copper product deposited on the surface of insulation paper. The insulation oil and paper aged in the oil-paper insulation sample with copper have higher dielectric loss and conductivity than that without copper.

Influence of copper on the by-products of different oil-paper insulations

Energy Technology Data Exchange (ETDEWEB)

Hao Jian; Liao Ruijin [State Key Laboratory of Power Transmission Equipment and System Security and New Technology, Chongqing University (China); Chen, George [School of Electronics and Computer Science, University of Southampton (United Kingdom); Ma Chao, E-mail: cquhaojian@126.com [Gansu Electric Power Research Institute (China)

2011-08-12

Transformer failure caused by the corrosion of copper material in transformer attracts great attention of researchers and engineers. In this paper, Karamay No. 25 naphthenic mineral oil, Karamay No. 25 paraffinic mineral oil, Kraft paper and copper were used to compose four combinations of oil-paper insulation samples. The ageing by-products and dielectric properties of the four combinations of oil-paper insulation samples were compared after they were thermally aged at 130 deg. C. The influence of copper on the by-products and dielectric properties of different oil-paper insulations was obtained. The results show that copper can accelerate the ageing rate of insulation oils and reduce their AC breakdown voltage. The content of copper substance dissolved in insulating oil increases with ageing time at first and then decreases. The paper aged in the oil-paper insulation sample with copper has higher moisture content than the one without copper. Results of energy dispersive spectroscopy (EDS) in the scanning electron microscope (SEM) show that there is copper product deposited on the surface of insulation paper. The insulation oil and paper aged in the oil-paper insulation sample with copper have higher dielectric loss and conductivity than that without copper.

Effect of water chemistry on deposition for PWR plant operation

International Nuclear Information System (INIS)

Le Calvar, Marc; Bretelle, J. L.; Cailleaux, J. P.; Lacroix, R.; Guivarch, M.; Gay, N.; Taunier, S.; Gressier, F.; Varry, P.; Corredera, G.; Alos-Ramos, O.; Dijoux, M.

2012-09-01

For Pressurized Water Reactor (PWR) operation, water chemistry guidelines, specifications and associated surveillance programs are key to avoid deposition of oxides. Deposition of oxides can be detrimental by disrupting results of flow measurements, decreasing the thermal exchange capacity, or even by impairing safety. This paper describes the most important cases of deposition, their consequences for operation, and the implemented improvements to avoid their reoccurrence. Deposition that led to a Crud Induced Power Shift (CIPS) is also described. In the primary and in the secondary sides, orifice plates are typically used for measuring feedwater flow rate in nuclear power plants. Feedwater flow rates are used for control purposes and are important safety parameters as they are used to determine the plant's operating power level. Fouling of orifice plates in the primary side has been found during surveillance testing. For reactor coolant pumps, the formation of deposits on the seal No.1 can cause abnormally high or low leak rates through the seal. The leak rate through this seal must be carefully maintained within a prescribed range during plant operation. In the secondary side, orifice plate fouling has been the cause of feedwater flow/reference thermal power drift. For the steam generators (SG), magnetite deposition has led to fouling of the tube bundle, clogging of the quadri-foiled support plate holes and hard sludge formation on the base plate. For the generators, copper hollow conductors are widely used. Buildup of copper oxides on the interior walls of copper conductors has caused insufficient heat transfer. All these deposition cases have received adequate attention, understanding and response via improvement of our surveillance programs. (authors)

Source contribution to the bulk atmospheric deposition of minor and trace elements in a Northern Spanish coastal urban area

Science.gov (United States)

Fernández-Olmo, Ignacio; Puente, Mariano; Montecalvo, Lucia; Irabien, Angel

2014-08-01

The bulk atmospheric deposition of the minor and trace elements As, Cd, Cr, Cu, Mn, Mo, Ni, Pb, Ti, V and Zn was investigated in Santander, a Northern Spanish coastal city. Bulk deposition samples were collected monthly for three years using a bottle/funnel device. Taking into account that heavy metals are bioavailable only in their soluble forms, water-soluble and water-insoluble fractions were evaluated separately for element concentration. The fluxes of the studied elements in the bulk deposition exhibited the following order: Zn > Mn ≫ Cu > Cr > Pb > V > Ni ≫ As > Mo > Cd. The fluxes of Zn and Mn were more than 10 times higher than those of the other elements, with maximum values of 554.5 and 334.1 μg m- 2 day- 1, respectively. Low solubilities (below 22%) were found for Cr, Ti and Pb, whereas the highest solubility was found for Zn (78%). With the exception of Cu, all of the studied metals in the water-soluble fraction of the atmospheric deposition showed seasonal dependence, due to the seasonal variability of precipitation. The enrichment factors (EFs) of Cu, Cd and Zn were higher than 100, indicating a clear anthropogenic origin. The EF of Mn (50) was below 100, but an exclusively industrial origin is suggested. Positive Matrix Factorisation (PMF) was used for the source apportionment of the studied minor and trace elements in the soluble fraction. Four factors were identified from PMF, and their chemical profiles were compared with those calculated from known sources that were previously identified in Santander Bay: two industrial sources, the first of which was characterised by Zn and Mn, which contributes 62.5% of the total deposition flux of the studied elements; a traffic source; and a maritime source. Zinc and Mn are considered to be the most characteristic pollutants of the studied area.

Quantity, distribution, and impacts of coastal driftwood triggered by a typhoon.

Science.gov (United States)

Doong, Dong-Jiing; Chuang, Hui-Chieh; Shieh, Chjeng-Lun; Hu, Jian-Hwa

2011-07-01

Typhoon Morakot pounded Taiwan in 2009 with record-breaking rainfall, washing an unprecedented amount of driftwood into the sea that was partially deposited at the coastal areas. According to the satellite imagery analysis, more than three million trees fell and were washed away to occupy 83.2% of the Taiwanese coastline, including 52 fishing harbors. The amount cleaned-up was only 1/7 of the total coastal driftwood. It was found that the amount of coastal driftwood is not only related to the amount of precipitation but is also related to the distance from the location of the landslide to the river mouth and to the landslide area. The amount of accumulated coastal driftwood demonstrated log-profile declines with increasing distance to the river mouth. Nearshore current and wave motion are the critical factors for driftwood deposition. Much of the driftwood washed into the sea harmed the tourism and fishing industries, endangered navigation and oceanic activities, and impacted the marine environment and ecosystem. Copyright © 2011 Elsevier Ltd. All rights reserved.

Smoothing an isolated interface of cobalt-copper under irradiation by low-energy argon ions

International Nuclear Information System (INIS)

Stognij, A.I.; Novitskij, N.N.; Stukalov, O.M.

2003-01-01

Multilayer film structures, i.e. gold layer-copper-cobalt, are considered. It is shown that the structure, where cobalt surface prior to copper layer deposition was subjected to additional irradiation by a flow of argon ions, features the smoothest surface. The conclusion is made about smoothing out of cobalt-copper interface as a result of multiple collisions of argon slow ions and cobalt atoms during braking within two or three upper atomic rows of the cobalt layer [ru

Wilson’s Disease: An Inherited, Silent, Copper Intoxication Disease

Directory of Open Access Journals (Sweden)

Uta Merle

2016-07-01

Full Text Available Wilson’s disease is a rare, autosomal recessive, genetic, copper overload disease, which evokes multiple motor or neuropsychiatric symptoms and liver disease. It is the consequence of a variety of different mutations affecting the ATP7B gene. This gene encodes for a class IB, P-type, copper-transporting ATPase, which is located in the trans-Golgi network of the liver and brain, and mediates the excretion of excess copper into the bile. When functionally inactive, the excess copper is deposited in the liver, brain, and other tissues. Free copper induces oxidative stress, lipid peroxidation, and lowers the apoptotic threshold of the cell. The symptoms in affected persons can vary widely and usually appear between the ages of 6 years and 20 years, but there are also cases in which the disease manifests in advanced age. In this review, we discuss the considerations in diagnosis, clinical management, and treatment of Wilson’s disease. In addition, we highlight experimental efforts that address the pathogenesis of Wilson’s disease in ATP7B deficient mice, novel analytical techniques that will improve the diagnosis at an early stage of disease onset, and treatment results with copper-chelating agents.

Effects of supporting electrolytes on copper electroplating for filling through-hole

International Nuclear Information System (INIS)

Chen, Chien-Hung; Lu, Chun-Wei; Huang, Su-Mei; Dow, Wei-Ping

2011-01-01

Highlights: → The through-holes of a printed circuit boardare directly filled by copper electroplating using single organic additive. → The inhibiting strength of the additive on copper deposition is related to a supporting electrolyte. → H 2 SO 4 strongly enhances the inhibiting strength of the additive and results in a conformal deposition, whereas Na 2 SO 4 and K 2 SO 4 do not affect the inhibiting strength and lead to good filling capability. - Abstract: The filling of micron through-holes (THs) in a printed circuit board (PCB) by copper electroplating was investigated in this study. The role of supporting electrolytes, such as H 2 SO 4 , Na 2 SO 4 and K 2 SO 4 , was explored using practical TH filling plating and linear-sweep voltammetry (LSV) analysis of plating solutions. The copper could selectively fill THs using one organic additive, namely, tetranitroblue tetrazolium chloride (TNBT), as an inhibitor. The inhibiting strength of TNBT depended on the supporting electrolytes. Although H 2 SO 4 could enhance the inhibiting strength of TNBT, it also decreased the filling capability of the copper plating solution; Na 2 SO 4 and K 2 SO 4 did not enhance the inhibiting strength of TNBT but they increased the filling capability of the copper plating solution. Additionally, the protons could chemically interact with TNBT to form precipitate, whereas sodium and potassium ions did not easily interact with TNBT. The filling capability of the copper plating solution using Na 2 SO 4 and K 2 SO 4 as supporting electrolytes could be greatly improved by adding a small amount of bis(3-sulfopropyl)-disulfide (SPS) and poly(ethylene glycol) (PEG) with a molecular weight of 600.

Influence of copper on Euplotes sp. and associated bacterial population

Directory of Open Access Journals (Sweden)

Guilherme Oliveira Andrade da Silva

2014-05-01

Full Text Available The influence of copper on the ciliate Euplotes sp. and associated bacteria isolated from sediment samples of Guanabara Bay were investigated in bioassays. This region is highly affected by heavy metals such as copper, from solid waste constantly dumped in the bay and other sources such as industrial effluents, antifouling paints, atmospheric deposition and urban drainage, and even today there are few data on the metal toxicity to the ecosystem of the Bay of Guanabara. Bioassays were conducted to estimate the LC50-24 h of copper, in order to determine the concentration of metal bearing 50% of the population mortality. The results indicated that the concentrations of 0.05 and 0.009 mg L-1 presented no toxicity to Euplotes sp. The associated bacteria are tolerant to copper concentrations used in bioassays, and suggest that they could be used as a potential agent in the bioremediation of areas affected by copper.

Examining the effects of fill gas pressure on the distribution of copper atoms in a hollow cathode lamp

International Nuclear Information System (INIS)

Oliver, D.R.; Finlayson, T.R.

1996-01-01

A modified Copper Hollow Cathode lamp has been used to examine the effects of fill gas pressure on the distribution of sputtered Copper atoms in the body of the lamp. The lamp was modified by placing a quartz disc above the cathode, perpendicular to both the cathode bore and the cathode-anode axis. While the lamp is operating, some of the Copper that has been sputtered out of the cathode bore is deposited on the disc. Modified lamps have been operated at a variety of pressures, and the resulting deposition profiles recorded using an optical microscope. A summary of variations between different pressures are presented

76 FR 28130 - Coastal Bank, Cocoa Beach, Florida; Notice of Appointment of Receiver

Science.gov (United States)

2011-05-13

... DEPARTMENT OF THE TREASURY Office of Thrift Supervision Coastal Bank, Cocoa Beach, Florida; Notice of Appointment of Receiver Notice is hereby given that, pursuant to the authority contained in... Federal Deposit Insurance Corporation as sole Receiver for Coastal Bank, Cocoa Beach, Florida, (OTS No...

Nanocarbon-copper thin film as transparent electrode

International Nuclear Information System (INIS)

Isaacs, R. A.; Zhu, H.; Preston, Colin; LeMieux, M.; Jaim, H. M. Iftekhar; Hu, L.; Salamanca-Riba, L. G.; Mansour, A.; Zavalij, P. Y.; Rabin, O.

2015-01-01

Researchers seeking to enhance the properties of metals have long pursued incorporating carbon in the metallic host lattice in order to combine the strongly bonded electrons in the metal lattice that yield high ampacity and the free electrons available in carbon nanostructures that give rise to high conductivity. The incorporation of carbon nanostructures into the copper lattice has the potential to improve the current density of copper to meet the ever-increasing demands of nanoelectronic devices. We report on the structure and properties of carbon incorporated in concentrations up to 5 wt. % (∼22 at. %) into the crystal structure of copper. Carbon nanoparticles of 5 nm–200 nm in diameter in an interconnecting carbon matrix are formed within the bulk Cu samples. The carbon does not phase separate after subsequent melting and re-solidification despite the absence of a predicted solid solution at such concentrations in the C-Cu binary phase diagram. This material, so-called, Cu covetic, makes deposition of Cu films containing carbon with similar microstructure to the metal possible. Copper covetic films exhibit greater transparency, higher conductivity, and resistance to oxidation than pure copper films of the same thickness, making them a suitable choice for transparent conductors

Nanocarbon-copper thin film as transparent electrode

Energy Technology Data Exchange (ETDEWEB)

Isaacs, R. A.; Zhu, H.; Preston, Colin; LeMieux, M.; Jaim, H. M. Iftekhar; Hu, L., E-mail: binghu@umd.edu; Salamanca-Riba, L. G., E-mail: riba@umd.edu [Materials Science and Engineering Department, University of Maryland, College Park, Maryland 20742 (United States); Mansour, A. [Carderock Division, Naval Surface Warfare Center, West Bethesda, Maryland 20817 (United States); Zavalij, P. Y. [Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742 (United States); Rabin, O. [Materials Science and Engineering Department, University of Maryland, College Park, Maryland 20742 (United States); Institute for Research in Electronics and Applied Physics, University of Maryland, College Park, Maryland 20742 (United States)

2015-05-11

Researchers seeking to enhance the properties of metals have long pursued incorporating carbon in the metallic host lattice in order to combine the strongly bonded electrons in the metal lattice that yield high ampacity and the free electrons available in carbon nanostructures that give rise to high conductivity. The incorporation of carbon nanostructures into the copper lattice has the potential to improve the current density of copper to meet the ever-increasing demands of nanoelectronic devices. We report on the structure and properties of carbon incorporated in concentrations up to 5 wt. % (∼22 at. %) into the crystal structure of copper. Carbon nanoparticles of 5 nm–200 nm in diameter in an interconnecting carbon matrix are formed within the bulk Cu samples. The carbon does not phase separate after subsequent melting and re-solidification despite the absence of a predicted solid solution at such concentrations in the C-Cu binary phase diagram. This material, so-called, Cu covetic, makes deposition of Cu films containing carbon with similar microstructure to the metal possible. Copper covetic films exhibit greater transparency, higher conductivity, and resistance to oxidation than pure copper films of the same thickness, making them a suitable choice for transparent conductors.

Effect of desliming on the flotation of a complax copper ore from China

OpenAIRE

Chen Yong; Song Yong Sheng; Li Wen Juan; Zhou Gui Ying

2016-01-01

The complex copper oxide ore sample was taken from Deerni copper deposit, Qinghai Province of China. Batch flotation tests had been conducted to upgrade the copper concentrate by conventional amyl xanthate reagents under 73% -74 μm of the particle size; however, the unsatisfied results (Cu grade of 18.21% and recovery of 59.25%) were obtained. Also there are a large amount of slimes trapped in the concentrate and high-dosages consumption of reagents, for example, more than 2.5 kg/t sodium sul...

Niobium sputter deposition on quarter wave resonators

CERN Document Server

Viswanadham, C; Jayaprakash, D; Mishra, R L

2003-01-01

Niobium sputter deposition on quarter wave copper R.F resonators, have been taken up in our laboratory, An ultra high vacuum system was made for this purpose. Niobium exhibits superconducting properties at liquid Helium temperature. A uniform coating of about 1.5 mu m of niobium on the internal surfaces of the copper resonant cavities is desired. Power dissipation in the resonators can be greatly reduced by making the internal surfaces of the R.F cavity super conducting. (author)

Geochemical and sedimentologic problems of uranium deposits of Texas Gulf Coastal Plain

International Nuclear Information System (INIS)

Huang, W.H.

1978-01-01

Exploration targets for sedimentary uranium ore bodies in the Texas Gulf Coastal Plain include: (1) favorable source rocks for uranium, (2) favorable conditions for uranium leached and transported out of the source rocks, and (3) favorable geologic characteristics of the host rocks for the accumulation of uranium of economic importance. However, data available from known deposits point out more questions of research than answers. Mobility and accumulation of uranium of economic importance in host rocks are controlled by at least three factors - physical, chemical-mineralogic, and hydrologic - that interact dynamically. Physical factors include the nature (viscosity) of the transporting fluid, the permeability of host rock with respect to transporting solution in terms of medium rate, potential differentials, and temperature of the uranium-bearing solution in the macroenvironment. Chemical-mineralogic factors include the ionic strength of solution, chemical activities of species in the solution, chemical activities of pore water in host rocks, surface activity and surface energy of mineral constituents in host rocks, solubilities of ore and gangue minerals, pH, and Eh in the microenvironment. Hydrologic factors include fluctuation of the depth of the oxidation-reduction interfaces in the paleoaquifer host rocks, and their subsequent modification by present hydrologic factors. Geochemical mechanisms that are likely to have been in operation for uranium accumulation are precipitation, adsorption, and/or complexing. 4 figures

Coastal Dynamics of the Ganges-Brahmaputra Delta: 1988-2014

Science.gov (United States)

Chiu, S.; Sousa, D.; Mondal, D. R.; Small, C.

2014-12-01

In this study we quantify erosional and depositional processes in the coastal zone (including tidal flats and river channels) of the lower Ganges Brahmaputra delta (GBD). Recent availability of accurately coregistered, radiometrically intercalibrated, Landsat TM, ETM+ & OLI collected since 1988 allows for spatiotemporal (ST) analyses of both natural and anthropogenic processes in the coastal zone on seasonal to interannual time scales. We quantify changes in the coastal zone using 106 cloud-free acquisitions in the area of the 3 Landsat scenes spanning the lower delta. Changes are quantified using multitemporal spectral mixture analysis of exoatmospheric reflectance to represent land cover and water bodies as continuous fields of soil and sediment substrates (S), vegetation (V), and dark surfaces (D; water & shadow). We also use MODIS 16-day EVI composite time series and high spatial resolution (2-4 m) imagery post-2000 to extend and vicariously validate the Landsat-derived observations. Because water levels on the lower delta change by several meters on time scales of hours (tides), months (discharge) and years (relative sea level rise), we use a network of 11 tide gauges to distinguish the effects of these changes in the coastal zone imaged by Landsat. Cross spectral analysis of this network of tide gauge records quantifies the dominant periods and relative magnitudes as well as phase of water level variations across these time scales. Tide gauge records are used to identify Landsat scenes acquired at similar water levels as well as the effects of water level on variations in tidal flats. Water level and water leaving radiance are used to map spatiotemporal variations in suspended sediment. Tri-temporal change maps of SVD fractions show progressive changes of coastlines throughout the study period. We find significant change in tidal flats in acquisitions from different tidal heights, alluding to the importance of tidal phase in coastal analyses. Erosion of

19 CFR 4.66b - Pollution of coastal and navigable waters.

Science.gov (United States)

2010-04-01

... 19 Customs Duties 1 2010-04-01 2010-04-01 false Pollution of coastal and navigable waters. 4.66b... coastal and navigable waters. (a) If any Customs officer has reason to believe that any refuse matter is being or has been deposited in navigable waters or any tributary of any navigable waters in violation of...

REMOVAL OF COPPER ELECTROLYTE CONTAMINANTS BY ADSORPTION

Directory of Open Access Journals (Sweden)

B Gabai

1997-09-01

Full Text Available Abstract - Selective adsorbents have become frequently used in industrial processes. Recent studies have shown the possibility of using adsorption to separate copper refinery electrolyte contaminants, with better results than those obtained with conventional techniques. During copper electrorefinning, many impurities may be found as dissolved metals present in the anode slime which forms on the electrode surface, accumulated in the electrolyte or incorporated into the refined copper on the cathode by deposition. In this study, synthetic zeolites, chelating resins and activated carbons were tested as adsorbents to select the best adsorbent performance, as well as the best operating temperature for the process. The experimental method applied was the finite bath, which consists in bringing the adsorbent into contact with a finite volume of electrolyte while controlling the temperature. The concentration of metals in the liquid phase was continuously monitored by atomic absorption spectrophotometry (AAS

Surface properties of copper based cermet materials

International Nuclear Information System (INIS)

Voinea, M.; Vladuta, C.; Bogatu, C.; Duta, A.

2008-01-01

The paper presents the characterization of the surface properties of copper based cermets obtained by two different techniques: spray pyrolysis deposition (SPD) and electrodeposition. Copper acetate was used as precursor of Cu/CuO x cermet. The surface morphology was tailored by adding copolymers of maleic anhydride with controlled hydrophobia. The films morphology of Cu/CuO x was assessed using contact angle measurements and AFM analysis. The porous structures obtained via SPD lead to higher liquid adsorption rate than the electrodeposited films. A highly polar liquid - water is recommended as testing liquid in contact angle measurements, for estimating the porosity of copper based cermets, while glycerol can be used to distinguish among ionic and metal predominant structures. Thus, contact angle measurements can be used for a primary evaluation of the films morphology and, on the other hand, of the ratio between the cermet components

Poly(glycidyl methacrylate)—A soft template for the facile preparation of poly(glycidyl methacrylate) core-copper nanoparticle shell nanocomposite

International Nuclear Information System (INIS)

Mohammed Safiullah, S.; Abdul Wasi, K.; Anver Basha, K.

2015-01-01

Graphical abstract: - Highlights: • PGMA/Cu nanohybrids have been synthesized by Surface deposition method. • The CuNPs were deposited on the PGMA surface without surface modification. • CuNP deposition on PGMA has a significant effect on morphology and thermal stability. - Abstract: Poly(glycidyl methacrylate) core/copper nanoparticle shell nanocomposite (PGMA/Cu nanohybrid) was prepared by simple two step method (i) The synthesis of poly(glycidyl methacrylate) (PGMA) beads by free radical suspension polymerization followed by (ii) direct deposition of copper nanoparticles (CuNPs) on activated PGMA beads. The PGMA beads were used as a soft template to host the CuNPs without surface modification of it. In this method the CuNPs were formed by chemical reduction of copper salts using sodium borohydride in water medium and deposited directly on the activated PGMA. Two different concentrations of copper salts were employed to know the effect of concentration on the shape and size of nanoparticles. The results showed that, the different sizes and shapes of CuNPs were deposited on the PGMA matrix. The X-ray Diffraction study results showed that the CuNPs were embedded on the surface of the PGMA matrix. The scanning electron microscopic images revealed that the fabrication of CuNPs on the PGMA matrix possess different shapes and changes the morphology and nature of PGMA beads significantly. The fluorescent micrograph also confirmed that the CuNPs were doped on the PGMA surface. The thermal studies have demonstrated that the CuNPs deposition on the surface of PGMA beads had a significant effect.

Poly(glycidyl methacrylate)—A soft template for the facile preparation of poly(glycidyl methacrylate) core-copper nanoparticle shell nanocomposite

Energy Technology Data Exchange (ETDEWEB)

Mohammed Safiullah, S., E-mail: safichem@gmail.com [Department of Chemistry, C. Abdul Hakeem College of Engineering & Technology, Melvisharam, Vellore District, Tamil Nadu 632509 (India); P.G. & Research Department of Chemistry, C. Abdul Hakeem College, Melvisharam, Vellore District, Tamil Nadu 632509 (India); Abdul Wasi, K. [P.G. & Research Department of Chemistry, C. Abdul Hakeem College, Melvisharam, Vellore District, Tamil Nadu 632509 (India); Anver Basha, K., E-mail: kanverbasha@gmail.com [P.G. & Research Department of Chemistry, C. Abdul Hakeem College, Melvisharam, Vellore District, Tamil Nadu 632509 (India)

2015-12-01

Graphical abstract: - Highlights: • PGMA/Cu nanohybrids have been synthesized by Surface deposition method. • The CuNPs were deposited on the PGMA surface without surface modification. • CuNP deposition on PGMA has a significant effect on morphology and thermal stability. - Abstract: Poly(glycidyl methacrylate) core/copper nanoparticle shell nanocomposite (PGMA/Cu nanohybrid) was prepared by simple two step method (i) The synthesis of poly(glycidyl methacrylate) (PGMA) beads by free radical suspension polymerization followed by (ii) direct deposition of copper nanoparticles (CuNPs) on activated PGMA beads. The PGMA beads were used as a soft template to host the CuNPs without surface modification of it. In this method the CuNPs were formed by chemical reduction of copper salts using sodium borohydride in water medium and deposited directly on the activated PGMA. Two different concentrations of copper salts were employed to know the effect of concentration on the shape and size of nanoparticles. The results showed that, the different sizes and shapes of CuNPs were deposited on the PGMA matrix. The X-ray Diffraction study results showed that the CuNPs were embedded on the surface of the PGMA matrix. The scanning electron microscopic images revealed that the fabrication of CuNPs on the PGMA matrix possess different shapes and changes the morphology and nature of PGMA beads significantly. The fluorescent micrograph also confirmed that the CuNPs were doped on the PGMA surface. The thermal studies have demonstrated that the CuNPs deposition on the surface of PGMA beads had a significant effect.

Microstructure & Other Properties of Pulse-Plated Copper for Electroforming Applications

DEFF Research Database (Denmark)

Tang, Peter Torben; Jensen, Jens Dahl; Dam, H.C.

2002-01-01

Microstructure, hardness, material distribution and current efficiency were studied for various pulse patterns (both direct current, on/off and pulse reverse plating) and different bath compositions of copper sulfate and sulfuric acid, with additions of chloride. The objective was to develop a re...... a reliable copper electroforming process to provide a fine-grained and hard (above HV 125) deposit with good micro- and macrothrowing power. Potential applications include solar cell panels, tools for micro injection molding and various microelectromechanical systems (MEMS)....

Chelation therapy in intoxications with mercury, lead and copper

DEFF Research Database (Denmark)

Cao, yang; Skaug, Marit Aralt; Andersen, Ole

2015-01-01

In the present review we provide an update of the appropriate use of chelating agents in the treatment of intoxications with compounds of mercury, lead and copper. The relatively new chelators meso-2,3-dimercaptosuccinic acid (DMSA) and 2,3-dimercapto-propanesulphonate (DMPS) can effectively...... mobilize deposits of mercury as well as of lead into the urine. These drugs can be administered orally and have relatively low toxicity compared to the classical antidote dimercaptopropanol (BAL). d-Penicillamine has been widely used in copper overload, although 2,3-dimercaptosuccinic acid...

Synthesis of Quaternary Ammonium Salts Based on Diketopyrrolopyrroles Skeletons and Their Applications in Copper Electroplating.

Science.gov (United States)

Chen, Biao; Xu, Jie; Wang, Limin; Song, Longfeng; Wu, Shengying

2017-03-01

A series of DPP derivatives bearing quaternary ammonium salt centers with different lengths of carbon chains have been designed and synthesized. Their inhibition actions on copper electroplating were first investigated. A total of four diketopyrrolopyrrole (DPP) derivatives showed different inhibition capabilities on copper electroplating. To investigate interactions between metal surface and additives, we used quantum chemical calculations. Static and dynamic surface tension of four DPP derivatives had been measured, and the results showed DPP-10C (1c) with a faster-decreasing rate of dynamic surface tension among the four derivatives, which indicated higher adsorption rate of additive on the cathode surface and gives rise to stronger inhibiting effect of copper electrodeposition. Then, DPP-10C (1c) as the representative additive, was selected for the systematic study of the leveling influence during microvia filling through comprehensive electroplating tests. In addition, field-emission scanning electron microscope images and X-ray diffraction results showed the surface morphology, which indicated that addition of DPP derivative (1c) could lead a fine copper deposit and cause the preferential orientations of copper deposits to change from [220] to [111], which happened in particular at higher concentrations.

Copper-containing plastocyanin used for electron transport by an oceanic diatom.

Science.gov (United States)

Peers, Graham; Price, Neil M

2006-05-18

The supply of some essential metals to pelagic ecosystems is less than the demand, so many phytoplankton have slow rates of photosynthetic production and restricted growth. The types and amounts of metals required by phytoplankton depends on their evolutionary history and on their adaptations to metal availability, which varies widely among ocean habitats. Diatoms, for example, need considerably less iron (Fe) to grow than chlorophyll-b-containing taxa, and the oceanic species demand roughly one-tenth the amount of coastal strains. Like Fe, copper (Cu) is scarce in the open sea, but notably higher concentrations of it are required for the growth of oceanic than of coastal isolates. Here we report that the greater Cu requirement in an oceanic diatom, Thalassiosira oceanica, is entirely due to a single Cu-containing protein, plastocyanin, which--until now--was only known to exist in organisms with chlorophyll b and cyanobacteria. Algae containing chlorophyll c, including the closely related coastal species T. weissflogii, are thought to lack plastocyanin and contain a functionally equivalent Fe-containing homologue, cytochrome c6 (ref. 9). Copper deficiency in T. oceanica inhibits electron transport regardless of Fe status, implying a constitutive role for plastocyanin in the light reactions of photosynthesis in this species. The results suggest that selection pressure imposed by Fe limitation has resulted in the use of a Cu protein for photosynthesis in an oceanic diatom. This biochemical switch reduces the need for Fe and increases the requirement for Cu, which is relatively more abundant in the open sea.

Long-term passive restoration following fluvial deposition of sulphidic copper tailings: nature filters out the solutions.

Science.gov (United States)

Nikolic, Nina; Böcker, Reinhard; Nikolic, Miroslav

2016-07-01

Despite the growing popularity of ecological restoration approach, data on primary succession on toxic post-mining substrates, under site environmental conditions which considerably differ from the surrounding environment, are still scarce. Here, we studied the spontaneous vegetation development on an unusual locality created by long-term and large-scale fluvial deposition of sulphidic tailings from a copper mine in a pronouncedly xerothermic, calcareous surrounding. We performed multivariate analyses of soil samples (20 physical and chemical parameters) and vegetation samples (floristic and structural parameters in three types of occurring forests), collected along the pollution gradients throughout the affected floodplain. The nature can cope with two types of imposed constraints: (a) excessive Cu concentrations and (b) very low pH, combined with nutrient deficiency. The former will still allow convergence to the original vegetation, while the latter will result in novel, depauperate assemblages of species typical for cooler and moister climate. Our results for the first time demonstrate that with the increasing severity of environmental filtering, the relative importance of the surrounding vegetation for primary succession strongly decreases.

Band bending at copper and gold interfaces with ferroelectric Pb(Zr,Ti)O{sub 3} investigated by photoelectron spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Apostol, Nicoleta G.; Ştoflea, Laura E.; Tănase, Liviu C.; Bucur, Ioana Cristina; Chirilă, Cristina; Negrea, Raluca F.; Teodorescu, Cristian M., E-mail: teodorescu@infim.ro

2015-11-01

Highlights: • Synthesis of lead zirco-titanate (0 0 1) layers with nearly perfect stoichiometric transfer from substrates by pulsed laser deposition. • Copper forms continuous layers on Pb(Zr,Ti)O{sub 3}, gold is deposited in form of nanoparticles. • Derivation of Schottky mechanism for band bending for gold deposited on lead zirco-titanate. • Cancellation of polarization-induced band bending for copper deposited on lead zirco-titanate. • Pb reduction observed only in the case of copper deposited on lead zirco-titanate. - Abstract: Interfaces formed by gold and copper on single crystal layers of (0 0 1) PbZr{sub 0.2}Ti{sub 0.8}O{sub 3} (PZT) produced by pulsed laser deposition and exhibiting outwards polarization are analyzed by X-ray photoelectron spectroscopy. The stoichiometry of the layers reproduces reasonably that of the PZT target. The band bending occurring at the interface between PZT and the metals is investigated by analyzing the core level shifts as function on the metal deposition. It is found that for Au/PZT(0 0 1) the gold layer is not continuous and the observed band bendings can be attributed to a Schottky mechanism, whereas for Cu/PZT(0 0 1) the copper layer is continuous; in this latter case, the observed band bendings towards higher energies (lower binding energies) can be attributed to a concomitant bending due to the Schottky effect together with the disappearance of the initial bending due to the outwards polarization of the samples. Metal Pb is observed to segregate only in the case of Cu/PZT(0 0 1), therefore the surface self-reduction might also be connected to the presence of a metal with lower work function, which for larger coverage forms a continuous metal layer, able to provide electrons to the surface. High resolution transmission electron spectroscopy yielded the disappearance of the tetragonal distortion in the case of Cu/PZT(0 0 1), in line with the assumption of disappearance of the polarization-induced band bending.

Poly(glycidyl methacrylate)-A soft template for the facile preparation of poly(glycidyl methacrylate) core-copper nanoparticle shell nanocomposite

Science.gov (United States)

Mohammed Safiullah, S.; Abdul Wasi, K.; Anver Basha, K.

2015-12-01

Poly(glycidyl methacrylate) core/copper nanoparticle shell nanocomposite (PGMA/Cu nanohybrid) was prepared by simple two step method (i) The synthesis of poly(glycidyl methacrylate) (PGMA) beads by free radical suspension polymerization followed by (ii) direct deposition of copper nanoparticles (CuNPs) on activated PGMA beads. The PGMA beads were used as a soft template to host the CuNPs without surface modification of it. In this method the CuNPs were formed by chemical reduction of copper salts using sodium borohydride in water medium and deposited directly on the activated PGMA. Two different concentrations of copper salts were employed to know the effect of concentration on the shape and size of nanoparticles. The results showed that, the different sizes and shapes of CuNPs were deposited on the PGMA matrix. The X-ray Diffraction study results showed that the CuNPs were embedded on the surface of the PGMA matrix. The scanning electron microscopic images revealed that the fabrication of CuNPs on the PGMA matrix possess different shapes and changes the morphology and nature of PGMA beads significantly. The fluorescent micrograph also confirmed that the CuNPs were doped on the PGMA surface. The thermal studies have demonstrated that the CuNPs deposition on the surface of PGMA beads had a significant effect.

Current Status and Future Prospects of Copper Oxide Heterojunction Solar Cells.

Science.gov (United States)

Wong, Terence K S; Zhuk, Siarhei; Masudy-Panah, Saeid; Dalapati, Goutam K

2016-04-07

The current state of thin film heterojunction solar cells based on cuprous oxide (Cu₂O), cupric oxide (CuO) and copper (III) oxide (Cu₄O₃) is reviewed. These p-type semiconducting oxides prepared by Cu oxidation, sputtering or electrochemical deposition are non-toxic, sustainable photovoltaic materials with application potential for solar electricity. However, defects at the copper oxide heterojunction and film quality are still major constraining factors for achieving high power conversion efficiency, η. Amongst the Cu₂O heterojunction devices, a maximum η of 6.1% has been obtained by using pulsed laser deposition (PLD) of Al x Ga 1- x O onto thermal Cu₂O doped with Na. The performance of CuO/n-Si heterojunction solar cells formed by magnetron sputtering of CuO is presently limited by both native oxide and Cu rich copper oxide layers at the heterointerface. These interfacial layers can be reduced by using a two-step sputtering process. A high η of 2.88% for CuO heterojunction solar cells has been achieved by incorporation of mixed phase CuO/Cu₂O nanopowder. CuO/Cu₂O heterojunction solar cells fabricated by electrodeposition and electrochemical doping has a maximum efficiency of 0.64% after surface defect passivation and annealing. Finally, early stage study of Cu₄O₃/GaN deposited on sapphire substrate has shown a photovoltaic effect and an η of ~10 -2 %.

Investigation into Generation of Micro Features by Localised Electrochemical Deposition

Science.gov (United States)

Debnath, Subhrajit; Laskar, Hanimur Rahaman; Bhattacharyya, B.

2017-11-01

With the fast advancement of technology, localised electrochemical deposition (LECD) is becoming very advantageous in generating high aspect ratio micro features to meet the steep demand in modern precision industries of the present world. Except many other advantages, this technology is highly uncomplicated and economical for fabricating metal micro-parts with in micron ranges. In the present study, copper micro-columns have been fabricated utilizing LECD process. Different process parameters such as voltage, frequency, duty ratio and electrolyte concentration, which affect the deposition performance have been identified and their effects on deposition performances such as deposition rate, height and diameter of the micro-columns have been experimentally investigated. Taguchi's methodology has been used to study the effects as well as to obtain the optimum values of process parameters so that localised deposition with best performance can be achieved. Moreover, the generated micro-columns were carefully observed under optical and scanning electron microscope from where the surface quality of the deposited micro-columns has been studied qualitatively. Also, an array of copper micro-columns has been fabricated on stainless steel (SS-304) substrate for further exploration of LECD process capability.

Remediation of a marine shore tailings deposit and the importance of water-rock interaction on element cycling in the coastal aquifer.

Science.gov (United States)

Dold, Bernhard; Diaby, Nouhou; Spangenberg, Jorge E

2011-06-01

We present the study of the geochemical processes associated with the first successful remediation of a marine shore tailings deposit in a coastal desert environment (Bahía de Ite, in the Atacama Desert of Peru). The remediation approach implemented a wetland on top of the oxidized tailings. The site is characterized by a high hydraulic gradient produced by agricultural irrigation on upstream gravel terraces that pushed river water (∼500 mg/L SO(4)) toward the sea and through the tailings deposit. The geochemical and isotopic (δ(2)H(water) and δ(18)O(water), δ(34)S(sulfate), δ(18)O(sulfate)) approach applied here revealed that evaporite horizons (anhydrite and halite) in the gravel terraces are the source of increased concentrations of SO(4), Cl, and Na up to ∼1500 mg/L in the springs at the base of the gravel terraces. Deeper groundwater interacting with underlying marine sequences increased the concentrations of SO(4), Cl, and Na up to 6000 mg/L and increased the alkalinity up to 923 mg/L CaCO(3) eq. in the coastal aquifer. These waters infiltrated into the tailings deposit at the shelf-tailings interface. Nonremediated tailings had a low-pH oxidation zone (pH 1-4) with significant accumulations of efflorescent salts (10-20 cm thick) at the surface because of upward capillary transport of metal cations in the arid climate. Remediated tailings were characterized by neutral pH and reducing conditions (pH ∼7, Eh ∼100 mV). As a result, most bivalent metals such as Cu, Zn, and Ni had very low concentrations (around 0.01 mg/L or below detection limit) because of reduction and sorption processes. In contrast, these reducing conditions increased the mobility of iron from two sources in this system: (1) The originally Fe(III)-rich oxidation zone, where Fe(III) was reduced during the remediation process and formed an Fe(II) plume, and (2) reductive dissolution of Fe(III) oxides present in the original shelf lithology formed an Fe-Mn plume at 10-m depth. These

Simultaneous coastal measurements of ozone deposition fluxes and iodine-mediated particle emission fluxes with subsequent CCN formation

Directory of Open Access Journals (Sweden)

J. D. Whitehead

2010-01-01

of hours; sizes at which they may readily behave as cloud condensation nuclei (CCN under reasonable supersaturations that may be expected to pertain at the top of the marine boundary layer. These results link direct depositional loss and photochemical destruction of ozone to the formation of particles and hence CCN from macroalgal emissions at a coastal location.

Wet deposition of mercury in Qingdao, a coastal urban city in China: Concentrations, fluxes, and influencing factors

Science.gov (United States)

Chen, Lufeng; Li, Yanbin; Liu, Chang; Guo, Lina; Wang, Xiulin

2018-02-01

Mercury (Hg) is a global pollutant of public concern because of its high toxicity and capability for worldwide distribution via long-range atmospheric transportation. Wet atmospheric deposition is an important source of Hg in both terrestrial and aquatic environments. Concentrations of various Hg species in precipitation were monitored from March 2016 to February 2017 in a coastal urban area of Qingdao, and their wet deposition fluxes were estimated. The results showed that the volume-weighted mean (VWM) concentrations of total mercury (THg), reactive mercury (RHg), dissolved THg (DTHg), particulate THg (PTHg), total methylmercury (TMeHg), and dissolved and particulate MeHg (DMeHg and PMeHg) in Qingdao's precipitation were 13.6, 1.5, 5.4, 8.2, 0.38, 0.15, and 0.22 ng L-1, respectively, and their annual deposition fluxes were estimated to be 5703.0 (THg), 666.6 (RHg), 2304.0 (DTHg), 3470.4 (PTHg), 161.6 (TMeHg), 64.0 (DMeHg), and 95.7 (PMeHg) ng m-2 y-1, respectively. A relatively high proportion of MeHg in THg was observed in precipitation (3.0 ± 2.6%) possibly due to higher methylation and contributions from an oceanic source to MeHg in the precipitation. Obvious seasonal variations in Hg concentrations and deposition fluxes were observed in the precipitation in Qingdao. Correlation analyses and multiple regression analyses showed that SO2, pH, and NO3- were the controlling factors for THg in precipitation, whereas the MeHg concentration was primarily controlled by the SO2, WS, Cl-, and THg concentrations. PM2.5 and Cl- were the major controlling factors for PMeHg/TMeHg, whereas the TMeHg/THg ratio was mainly influenced by Cl-. The THg and MeHg fluxes were primarily controlled by precipitation, whereas Cl- was also an important factor for the MeHg wet deposition flux. The results of a 72-h backward trajectory analysis in the study region with the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model indicated that Hg deposition in Qingdao mainly

On the Growth and Microstructure of Carbon Nanotubes Grown by Thermal Chemical Vapor Deposition

Directory of Open Access Journals (Sweden)

Handuja Sangeeta

2010-01-01

Full Text Available Abstract Carbon nanotubes (CNTs were deposited on various substrates namely untreated silicon and quartz, Fe-deposited silicon and quartz, HF-treated silicon, silicon nitride-deposited silicon, copper foil, and stainless steel mesh using thermal chemical vapor deposition technique. The optimum parameters for the growth and the microstructure of the synthesized CNTs on these substrates are described. The results show that the growth of CNTs is strongly influenced by the substrate used. Vertically aligned multi-walled CNTs were found on quartz, Fe-deposited silicon and quartz, untreated silicon, and on silicon nitride-deposited silicon substrates. On the other hand, spaghetti-type growth was observed on stainless steel mesh, and no CNT growth was observed on HF-treated silicon and copper. Silicon nitride-deposited silicon substrate proved to be a promising substrate for long vertically aligned CNTs of length 110–130 μm. We present a possible growth mechanism for vertically aligned and spaghetti-type growth of CNTs based on these results.

Metallization of cyanide-modified Pt(111) electrodes with copper

DEFF Research Database (Denmark)

Escribano, Maria Escudero; Wildi, Christopher; Mwanda, Jonathan A.

2016-01-01

-cyanide-copper sandwich configuration. STM also shows that the Cu deposit consists of isolated bidimensional nanoislands, which slowly grow through an Ostwald ripening mechanism if the potential is kept negative of the reduction peak. Metallization is not possible in perchloric acid solutions, which implies...

Current Status and Future Prospects of Copper Oxide Heterojunction Solar Cells

OpenAIRE

Terence K. S. Wong; Siarhei Zhuk; Saeid Masudy-Panah; Goutam K. Dalapati

2016-01-01

The current state of thin film heterojunction solar cells based on cuprous oxide (Cu2O), cupric oxide (CuO) and copper (III) oxide (Cu4O3) is reviewed. These p-type semiconducting oxides prepared by Cu oxidation, sputtering or electrochemical deposition are non-toxic, sustainable photovoltaic materials with application potential for solar electricity. However, defects at the copper oxide heterojunction and film quality are still major constraining factors for achieving high power conversion e...

Antagonistic effects of copper on the electrochemical performance of LiFePO4

International Nuclear Information System (INIS)

Morales, Julian; Santos-Pena, Jesus; Rodriguez-Castellon, Enrique; Franger, Sylvain

2007-01-01

In the last few years, several strategies towards boosting the electrochemical performance of LiFePO 4 cathodes have been envisaged. Copper addition to the phosphate seems to be a simple, inexpensive method for this purpose. However, it has a serious drawback: at voltages slightly higher than that required for lithium extraction from LiFePO 4 , the copper is oxidized to either Cu(I) or Cu(II) with partial decomposition of the electrolyte. XRD patterns are consistent with the disappearance of copper from pristine composites upon charging at up to 4.0 V. Moreover, a copper deposit is formed on the lithium surface in the discharged state that creates a barrier hindering the release of Li ion from the electrode. Therefore, copper electroactivity strongly influences the capacity and cycling life of the cell

Substrate considerations for graphene synthesis on thin copper films

International Nuclear Information System (INIS)

Howsare, Casey A; Robinson, Joshua A; Weng Xiaojun; Bojan, Vince; Snyder, David

2012-01-01

Chemical vapor deposition on copper substrates is a primary technique for synthesis of high quality graphene films over large areas. While well-developed processes are in place for catalytic growth of graphene on bulk copper substrates, chemical vapor deposition of graphene on thin films could provide a means for simplified device processing through the elimination of the layer transfer process. Recently, it was demonstrated that transfer-free growth and processing is possible on SiO 2 . However, the Cu/SiO 2 /Si material system must be stable at high temperatures for high quality transfer-free graphene. This study identifies the presence of interdiffusion at the Cu/SiO 2 interface and investigates the influence of metal (Ni, Cr, W) and insulating (Si 3 N 4 , Al 2 O 3 , HfO 2 ) diffusion barrier layers on Cu–SiO 2 interdiffusion, as well as graphene structural quality. Regardless of barrier choice, we find the presence of Cu diffusion into the silicon substrate as well as the presence of Cu–Si–O domains on the surface of the copper film. As a result, we investigate the choice of a sapphire substrate and present evidence that it is a robust substrate for synthesis and processing of high quality, transfer-free graphene. (paper)

Econometrics Models for Copper Recovery: A Case Study of North Waziristan-Copper Deposits

International Nuclear Information System (INIS)

Ali, S.; Khan, M.M.

2010-01-01

Fourteen econometrics models have been developed to evaluate the effects of various flotation process variables like, Propyl xanthate (X/sub 1/g/tonne), pH (X/sub 2/,) Sodium Cyanide (X/sub 3/ g/tonne), Sodium sulphide (X/sub 4/ g/tonne), Frother (X/sub 5/ g/tonne), Pulp density (X/sub 6/ w/vol), and Conditioning time (X/sub 7/ minute) on the copper recovery YR North Waziristan-NWFP Pakistan. Ordinary Least Square OLS method has been applied as an analytical technique for regression analysis. It has been concluded in this study that model given in equation 7 is best model among all. This equation shows that with the increase of one unit of X/sub 1/, Y/sub R/ will increase 0.05 units keeping all other variables constant. (author)

Deposition of RuO 4 on various surfaces in a nuclear reactor containment

Science.gov (United States)

Holm, Joachim; Glänneskog, Henrik; Ekberg, Christian

2009-07-01

During a severe nuclear reactor accident with air ingress, ruthenium can be released from the nuclear fuel in the form of ruthenium tetroxide. Hence, it is important to investigate how the reactor containment is able to reduce the source term of ruthenium. The aim of this work was to investigate the deposition of gaseous ruthenium tetroxide on aluminium, copper and zinc, which all appear in relatively large amounts in reactor containment. The experiments show that ruthenium tetroxide is deposited on all the metal surfaces, especially on the copper and zinc surfaces. A large deposition of ruthenium tetroxide also appeared on the relatively inert glass surfaces in the experimental set-ups. The analyses of the different surfaces, with several analytical methods, showed that the form of deposited ruthenium was mainly ruthenium dioxide.

Historical extreme wave and landslide deposits on the Shirasuka coastal lowlands, Shizuoka Prefecture, Japan

Science.gov (United States)

Garrett, Ed; Riedesel, Svenja; Fujiwara, Osamu; Walstra, Jan; Deforce, Koen; Yokoyama, Yusuke; Schmidt, Sabine; Brill, Dominik; Roberts, Helen; Duller, Geoff; Brückner, Hulmut; De Batist, Marc; Heyvaert, Vanessa

2017-04-01

Future megathrust earthquakes and consequential tsunamis pose exceptional hazards to densely populated and highly industrialised coastlines facing the Nankai-Suruga Trough, south central Japan. Geological investigations of coastal sedimentary sequences play a key role in understanding megathrust behaviour and developing seismic and tsunami hazard assessments. In this study, we revisit a previously published palaeoseismic site at Shirasuka, located on the Enshu-nada coastline of Shizuoka Prefecture, seeking both to provide further information on past earthquakes and tsunamis and to explore the prospects and limitations of geological data with respect to assessing seismic and tsunami hazards. At Shirasuka, six closely-spaced vibrocores reveal four sand layers interbedded with organic muds. Photographs, X-ray CT scans and grain size analysis reveal a variety of sedimentary structures within these layers, including abrupt contacts, massive sands, rip-up clasts, internal mud drapes and cross bedding. Microfossil assemblages (diatoms, pollen, non-pollen palynomorphs) and optically stimulated luminescence overdispersion values of single grain feldspars highlight varying sediment sources and transport mechanisms. We suggest that the uppermost sand layer records a landslide from the landward margin of the site, while the remaining three sand layers reflect at least four extreme wave events, some of which are overprinted. We refine the published chronology using AMS radiocarbon, radionuclide and infrared stimulated luminescence approaches. Our Bayesian age models suggest that the oldest two sand layers relate to historically documented tsunamis in AD 1361 and 1498. The second youngest sand layer provides ages consistent with tsunamis in AD 1605 and 1707 and potentially also storm surges in 1680 and/or 1699. The modelled age of the landslide sand layer is consistent with the AD 1944 earthquake. The presence of a fresh scarp in US military aerial photographs from 1947 and

Model of modern dynamic deposition in the east China Sea

Science.gov (United States)

Zhou, Fugen

1989-09-01

Since the last rising of sea level, two branches of the Kuroshio, the Huanghai (Yellow Sea) coastal current (HCC; mainly cold water mass) and the Changjiang River outflow have controlled the modern dynamic deposition in the East China Sea. There are three depositing areas on the sea-bed under the above currents: a relict sand area un der the Taiwan Warm Current and the Huanghai Warm Current at the south-eastern area, the about 60 km2 round mud bank under the Huanghai Coastal Current at the northern area and the large subaqueous delta of mainly fine sand and silt under the Changjiang discharge flow in its estuary and the large narrow mud bank under the Zhejiang-Fujian Coastal Current, another round mud bank under the Changjiang discharge flow off Hangzhou Bay. The relict sand area has a coarsesand block under the Taiwan Warm Current bypassing Taiwan at the northern part of the island. The two round mud banks were formed in relatively static states by an anticlockwise converging cyclonic eddy. The coarsesand block was formed by a clockwise diverging cyclonic eddy. This new dynamic deposition theory can be used to explain not only the dynamic deposition process of clay, but also the patchy distribution of sediments on the shelves of the world ocean s.

Hepatocyte nuclear structure and subcellular distribution of copper in zebrafish Brachydanio rerio and roach Rutilus rutilus (Teleostei, Cyprinidae) exposed to copper sulphate

Energy Technology Data Exchange (ETDEWEB)

Paris-Palacios, Severine [Universite de Reims Champagne-Ardenne (URCA), UFR Sciences Exactes et Naturelles, Laboratoire d' Eco-Toxicologie, Institut International de Recherche sur les Ions Metalliques, B.P. 1039-51687 Reims cedex 2 (France)]. E-mail: severine.paris@univ-reims.fr; Biagianti-Risbourg, Sylvie [Universite de Reims Champagne-Ardenne (URCA), UFR Sciences Exactes et Naturelles, Laboratoire d' Eco-Toxicologie, Institut International de Recherche sur les Ions Metalliques, B.P. 1039-51687 Reims cedex 2 (France)]. E-mail: sylvie.biagianti@univ-reims.fr

2006-05-10

Copper is a trace element essential to life, but also a heavy metal with toxic effect clearly demonstrated. Cu induced perturbations in fish liver are well documented but the variability of the reported results is large. In this study two cyprinids, zebrafish and roach, were exposed to copper. Reported histocytological changes are either adaptative or degenerative depending on fish species, concentration of metal, and duration of exposure. Hepatic subcellular distribution of copper was determined by X-ray microanalysis in control and Cu-exposed roach and zebrafish. Sublethal copper sulphate contamination induced the development of a particular nucleolar alteration forming a network or honeycomb like structure in liver. This perturbation is observable in almost all the hepatocytes of zebrafish and roach exposed to copper for a minimum of 4 days of exposure. It seemed to concern more precisely the pars fibrosa. X-ray microanalysis showed that the appearance of network nucleolus was in relation to a Cu accumulation. Cu deposit was well located in the network as pars granulosa and nucloplasm showed very lower metal concentrations. The origin and consequence of network structure in nucleolus was discussed.

Hepatocyte nuclear structure and subcellular distribution of copper in zebrafish Brachydanio rerio and roach Rutilus rutilus (Teleostei, Cyprinidae) exposed to copper sulphate

International Nuclear Information System (INIS)

Paris-Palacios, Severine; Biagianti-Risbourg, Sylvie

2006-01-01

Copper is a trace element essential to life, but also a heavy metal with toxic effect clearly demonstrated. Cu induced perturbations in fish liver are well documented but the variability of the reported results is large. In this study two cyprinids, zebrafish and roach, were exposed to copper. Reported histocytological changes are either adaptative or degenerative depending on fish species, concentration of metal, and duration of exposure. Hepatic subcellular distribution of copper was determined by X-ray microanalysis in control and Cu-exposed roach and zebrafish. Sublethal copper sulphate contamination induced the development of a particular nucleolar alteration forming a network or honeycomb like structure in liver. This perturbation is observable in almost all the hepatocytes of zebrafish and roach exposed to copper for a minimum of 4 days of exposure. It seemed to concern more precisely the pars fibrosa. X-ray microanalysis showed that the appearance of network nucleolus was in relation to a Cu accumulation. Cu deposit was well located in the network as pars granulosa and nucloplasm showed very lower metal concentrations. The origin and consequence of network structure in nucleolus was discussed

Concentrations of metallic elements in kidney, liver, and lung tissue of Indo-Pacific bottlenose dolphin Tursiops aduncus from coastal waters of Zanzibar, Tanzania.

Science.gov (United States)

Mapunda, Edgar C; Othman, Othman C; Akwilapo, Leonard D; Bouwman, Hindrik; Mwevura, Haji

2017-09-15

Concentrations of metallic elements in kidney, liver and lung tissues of Indo-Pacific bottlenose dolphins Tursiops aduncus from coastal waters of Zanzibar were determined using inductively coupled plasma - optical emission spectroscopy. Cadmium, chromium, copper, and zinc were quantifiable in all tissues at concentration ranges of 0.10-150, 0.08-3.2, 1.1-88 and 14-210μg/g dry mass, respectively. Copper and zinc was significantly higher in liver, and females had significantly higher Cd in liver, and chromium in lung. Generally, T. aduncus dolphins from coastal waters around Zanzibar carry low concentrations of metals compared with dolphins from other areas. Cadmium increased significantly with age in kidney and lung. Copper decreased significantly with age in liver, probably due to foetal metallothionein. This study supplied baseline data against which future trends in marine mammals in the Indian Ocean, the world's third largest, can be assessed. Copyright © 2017 Elsevier Ltd. All rights reserved.

Macro and micro plastics sorb and desorb metals and act as a point source of trace metals to coastal ecosystems.

Science.gov (United States)

Munier, B; Bendell, L I

2018-01-01

Nine urban intertidal regions in Burrard Inlet, Vancouver, British Columbia, Canada, were sampled for plastic debris. Debris included macro and micro plastics and originated from a wide diversity of uses ranging from personal hygiene to solar cells. Debris was characterized for its polymer through standard physiochemical characteristics, then subject to a weak acid extraction to remove the metals, zinc, copper, cadmium and lead from the polymer. Recently manufactured low density polyethylene (LDPE), nylon, polyethylene terephthalate (PET), polypropylene (PP), polystyrene (PS) and polyvinyl chloride (PVC) were subject to the same extraction. Data was statistically analyzed by appropriate parametric and non-parametric tests when needed with significance set at P Plastic debris will affect metals within coastal ecosystems by; 1) providing a sorption site (copper and lead), notably for PVC 2) desorption from the plastic i.e., the "inherent" load (cadmium and zinc) and 3) serving as a point source of acute trace metal exposure to coastal ecosystems. All three mechanisms will put coastal ecosystems at risk to the toxic effects of these metals.

Nanosecond laser ablation and deposition of silver, copper, zinc and tin

DEFF Research Database (Denmark)

Cazzaniga, Andrea Carlo; Ettlinger, Rebecca Bolt; Canulescu, Stela

2014-01-01

Nanosecond pulsed laser deposition of different metals (Ag, Cu, Sn, Zn) has been studied in high vacuum at a laser wavelength of 355 nm and pulse length of 6 ns. The deposition rate is roughly similar for Sn, Cu and Ag, which have comparable cohesive energies, and much higher for the deposition...... of Zn which has a low cohesive energy. The deposition rate for all metals is strongly correlated with the total ablation yield, i.e., the total mass ablated per pulse, reported in the literature except for Sn, for which the deposition rate is low, but the total ablation yield is high. This may...... be explained by the continuous erosion by nanoparticles during deposition of the Sn films which appear to have a much rougher surface than those of the other metals studied in the present work....

Porphyry copper assessment of East and Southeast Asia: Philippines, Taiwan (Republic of China), Republic of Korea (South Korea), and Japan: Chapter P in Global mineral resource assessment

Science.gov (United States)

Hammarstrom, Jane M.; Bookstrom, Arthur A.; Demarr, Michael W.; Dicken, Connie L.; Ludington, Stephen; Robinson, Gilpin R.; Zientek, Michael L.

2014-01-01

The U.S. Geological Survey collaborated with member countries of the Coordinating Committee for Geoscience Programmes in East and Southeast Asia (CCOP) on an assessment of the porphyry copper resources of East and Southeast Asia as part of a global mineral resource assessment. The assessment covers the Philippines in Southeast Asia, and the Republic of Korea (South Korea), Taiwan (Province of China), and Japan in East Asia. The Philippines host world class porphyry copper deposits, such as the Tampakan and Atlas deposits. No porphyry copper deposits have been discovered in the Republic of Korea (South Korea), Taiwan (Province of China), or Japan.

Aminostratigraphic correlations and paleotemperature implications, Pliocene-Pleistocene high-sea-level deposits, northwestern Alaska

Science.gov (United States)

Kaufman, Darrell S.; Brigham-Grette, Julie

Multiple periods of Late Pliocene and Pleistocene high sea level are recorded by surficial deposits along the coastal plains of northwestern Alaska. Analyses of the extent of amino acid epimerization in fossil molluscan shells from the Nome coastal plain of the northern Bering Sea coast, and from the Alaskan Arctic Coastal Plain of the Chukchi and Beaufort Sea coasts, allow recognition of at least five intervals of higher-than-present relative sea level. Three Late Pliocene transgressions are represented at Nome by the complex and protracted Beringian transgression, and on the Arctic Coastal Plain by the Colvillian, Bigbendian, and Fishcreekian transgressions. These were followed by a lengthy period of non-marine deposition during the Early Pleistocene when sea level did not reach above its present position. A Middle Pleistocene high-sea-level event is represented at Nome by the Anvilian transgression, and on the Arctic Coastal Plain by the Wainwrightian transgression. Anvilian deposits at the type locality are considerably younger than previously thought, perhaps as young as Oxygen-Isotope Stage 11 (˜410,000 BP). Finally, the last interglacial Pelukian transgression is represented discontinuously along the shores of northwestern Alaska. Amino acid epimerization data, together with previous paleomagnetic measurements, radiometric-age determinations, and paleontologic evidence provide geochronological constraints on the sequence of marine deposits. They form the basis of regional correlations and offer a means of evaluating the post-depositional thermal history of the high-sea-level deposits. Provisional correlations between marine units at Nome and the Artic Coastal Plain indicate that the temperature difference that separates the two sites today had existed by about 3.0 Ma. Since that time, the effective diagenetic temperature was lowered by about 3-4°C at both sites, and the mean annual temperature was lowered considerably more. This temperature decrease was

III. Co-electrodeposition/removal of copper and nickel in a spouted electrochemical reactor.

Science.gov (United States)

Grimshaw, Pengpeng; Calo, Joseph M; Hradil, George

2011-07-11

Results are presented of an investigation of co-electrodeposition of copper and nickel from acidic solution mixtures in a cylindrical spouted electrochemical reactor. The effects of solution pH, temperature, and applied current on metal removal/recovery rate, current efficiency, and corrosion of the deposited metals from the cathodic particles were examined under galvanostatic operation. The quantitative and qualitative behavior of co-electrodeposition of the two metals from their mixtures differs significantly from that of the individual single metal solutions. This is primarily attributed to the metal displacement reaction between Ni(0) and Cu(2+). This reaction effectively reduces copper corrosion, and amplifies that for nickel (at least at high concentrations). It also amplifies the separation of the deposition regimes of the two metals in time, which indicates that the recovery of each metal as a relatively pure deposit from the mixture is possible. It was also shown that nitrogen sparging considerably increases the observed net electrodeposition rates for both metals - considerably more so than from solutions with just the single metals alone. A numerical model of co-electrodeposition, corrosion, metal displacement, and mass transfer in the cylindrical spouted electrochemical reactor is presented that describes the behavior of the experimental copper and nickel removal data quite well.

Bioindication of air pollution effects near a copper smelter in Brazil using mango trees and soil microbiological properties

International Nuclear Information System (INIS)

Klumpp, Andreas; Hintemann, Therese; Santana Lima, Josanidia; Kandeler, Ellen

2003-01-01

A field study near the copper smelter of a large industrial complex examined air pollution effects on vegetation and soil parameters in Camacari (northeast Brazil). Close to the smelter, soil pH-value was lower and total acidity as well as organic carbon contents were higher compared with a site far from the source and two reference sites. The acidification of top soil particularly and the drastically enhanced plant-available copper concentrations were caused by atmospheric deposition. High sulphur and copper deposition significantly reduced microbial biomass and altered functional diversity of soil microorganisms (arylsulphatase and xylanase). Large accumulations of sulphur, arsenic and copper were detected in mango leaves (Mangifera indica) growing downwind from the smelter suggesting potential food chain-mediated risk. - Atmospheric emissions in northeast Brazil have transformed soil pH, accumulated in soil and plants as sulphur and heavy metals, and affected the functional diversity of soil microorganisms

Bioindication of air pollution effects near a copper smelter in Brazil using mango trees and soil microbiological properties

Energy Technology Data Exchange (ETDEWEB)

Klumpp, Andreas; Hintemann, Therese; Santana Lima, Josanidia; Kandeler, Ellen

2003-12-01

A field study near the copper smelter of a large industrial complex examined air pollution effects on vegetation and soil parameters in Camacari (northeast Brazil). Close to the smelter, soil pH-value was lower and total acidity as well as organic carbon contents were higher compared with a site far from the source and two reference sites. The acidification of top soil particularly and the drastically enhanced plant-available copper concentrations were caused by atmospheric deposition. High sulphur and copper deposition significantly reduced microbial biomass and altered functional diversity of soil microorganisms (arylsulphatase and xylanase). Large accumulations of sulphur, arsenic and copper were detected in mango leaves (Mangifera indica) growing downwind from the smelter suggesting potential food chain-mediated risk. - Atmospheric emissions in northeast Brazil have transformed soil pH, accumulated in soil and plants as sulphur and heavy metals, and affected the functional diversity of soil microorganisms.

Intrinsically water-repellent copper oxide surfaces; An electro-crystallization approach

Science.gov (United States)

Akbari, Raziyeh; Ramos Chagas, Gabriela; Godeau, Guilhem; Mohammadizadeh, Mohammadreza; Guittard, Frédéric; Darmanin, Thierry

2018-06-01

Use of metal oxide thin layers is increased due to their good durability under environmental conditions. In this work, the repeatable nanostructured crystalite Cu2O thin films, developed by electrodeposition method without any physical and chemical modifications, demonstrate good hydrophobicity. Copper (I) oxide (Cu2O) layers were fabricated on gold/Si(1 0 0) substrates by different electrodeposition methods i.e. galvanostatic deposition, cyclic voltammetry, and pulse potentiostatic deposition and using copper sulfate (in various concentrations) as a precursor. The greatest crystalline face on prepared Cu2O samples is (1 1 1) which is the most hydrophobic facet of Cu2O cubic structure. Indeed, different crystallite structures such as nanotriangles and truncated octahedrons were formed on the surface for various electrodeposition methods. The increase of the contact angle (θw) measured by the rest time, reaching to about 135°, was seen at different rates and electrodeposition methods. In addition, two-step deposition surfaces were also prepared by applying two of the mentioned methods, alternatively. In general, the morphology of the two-step deposition surfaces showed some changes compared to that of one-step samples, allowing the formation of different crystallite shapes. Moreover, the wettability behavior showd the larger θw of the two-step deposition layers compared to the related one-step deposition layers. Therefore, the highest observed θw was related to the one of two-step deposition layers due to the creation of small octahedral structures on the surface, having narrow and deep valleys. However, there was an exception which was due to the resulted big structures and broad valleys on the surface. So, it is possible to engineer different crystallites shapes using the proposed two-step deposition method. It is expected that hydrophobic crystallite thin films can be used in environmental and electronic applications to save energy and materials properties.

Giant magneto-impedance effect on nanocrystalline microwires with conductive layer deposit

International Nuclear Information System (INIS)

Wang, R.L.; Zhao, Z.J.; Liu, L.P.; Yuan, W.Z.; Yang, X.L.

2005-01-01

In this study, the giant magneto-impedance effect on Fe-based glass-coated nanocrystalline microwires with and without an additional outer copper layer was investigated. Experiment results showed that the magneto-impedance ratio of the wires with a layer of deposited copper is higher at low frequencies and lower at high frequencies (above 50 MHz), as compared to that of the microwires without an outer copper layer. The peak MI magnetic field, corresponding to the maximum of the magneto-impedance ratio shifts towards higher field values with increasing coating thickness of copper layer. The results are explained in terms of electro-magnetic interactions between the conductive layer and the ferromagnetic core

Deposition of RuO{sub 4} on various surfaces in a nuclear reactor containment

Energy Technology Data Exchange (ETDEWEB)

Holm, Joachim, E-mail: joachim.holm@chalmers.s [Department of Nuclear Chemistry, Chalmers University of Technology, Se-412 96 Gothenburg (Sweden); Glaenneskog, Henrik [Ringhals AB, SE-430 22, Vaeroebacka (Sweden); Ekberg, Christian [Department of Nuclear Chemistry, Chalmers University of Technology, Se-412 96 Gothenburg (Sweden)

2009-07-01

During a severe nuclear reactor accident with air ingress, ruthenium can be released from the nuclear fuel in the form of ruthenium tetroxide. Hence, it is important to investigate how the reactor containment is able to reduce the source term of ruthenium. The aim of this work was to investigate the deposition of gaseous ruthenium tetroxide on aluminium, copper and zinc, which all appear in relatively large amounts in reactor containment. The experiments show that ruthenium tetroxide is deposited on all the metal surfaces, especially on the copper and zinc surfaces. A large deposition of ruthenium tetroxide also appeared on the relatively inert glass surfaces in the experimental set-ups. The analyses of the different surfaces, with several analytical methods, showed that the form of deposited ruthenium was mainly ruthenium dioxide.

Current Status and Future Prospects of Copper Oxide Heterojunction Solar Cells

Directory of Open Access Journals (Sweden)

Terence K. S. Wong

2016-04-01

Full Text Available The current state of thin film heterojunction solar cells based on cuprous oxide (Cu2O, cupric oxide (CuO and copper (III oxide (Cu4O3 is reviewed. These p-type semiconducting oxides prepared by Cu oxidation, sputtering or electrochemical deposition are non-toxic, sustainable photovoltaic materials with application potential for solar electricity. However, defects at the copper oxide heterojunction and film quality are still major constraining factors for achieving high power conversion efficiency, η. Amongst the Cu2O heterojunction devices, a maximum η of 6.1% has been obtained by using pulsed laser deposition (PLD of AlxGa1−xO onto thermal Cu2O doped with Na. The performance of CuO/n-Si heterojunction solar cells formed by magnetron sputtering of CuO is presently limited by both native oxide and Cu rich copper oxide layers at the heterointerface. These interfacial layers can be reduced by using a two-step sputtering process. A high η of 2.88% for CuO heterojunction solar cells has been achieved by incorporation of mixed phase CuO/Cu2O nanopowder. CuO/Cu2O heterojunction solar cells fabricated by electrodeposition and electrochemical doping has a maximum efficiency of 0.64% after surface defect passivation and annealing. Finally, early stage study of Cu4O3/GaN deposited on sapphire substrate has shown a photovoltaic effect and an η of ~10−2%.

Current Status and Future Prospects of Copper Oxide Heterojunction Solar Cells

Science.gov (United States)

Wong, Terence K. S.; Zhuk, Siarhei; Masudy-Panah, Saeid; Dalapati, Goutam K.

2016-01-01

The current state of thin film heterojunction solar cells based on cuprous oxide (Cu2O), cupric oxide (CuO) and copper (III) oxide (Cu4O3) is reviewed. These p-type semiconducting oxides prepared by Cu oxidation, sputtering or electrochemical deposition are non-toxic, sustainable photovoltaic materials with application potential for solar electricity. However, defects at the copper oxide heterojunction and film quality are still major constraining factors for achieving high power conversion efficiency, η. Amongst the Cu2O heterojunction devices, a maximum η of 6.1% has been obtained by using pulsed laser deposition (PLD) of AlxGa1−xO onto thermal Cu2O doped with Na. The performance of CuO/n-Si heterojunction solar cells formed by magnetron sputtering of CuO is presently limited by both native oxide and Cu rich copper oxide layers at the heterointerface. These interfacial layers can be reduced by using a two-step sputtering process. A high η of 2.88% for CuO heterojunction solar cells has been achieved by incorporation of mixed phase CuO/Cu2O nanopowder. CuO/Cu2O heterojunction solar cells fabricated by electrodeposition and electrochemical doping has a maximum efficiency of 0.64% after surface defect passivation and annealing. Finally, early stage study of Cu4O3/GaN deposited on sapphire substrate has shown a photovoltaic effect and an η of ~10−2%. PMID:28773398

Stability of nanocrystalline electrochemically deposited layers

DEFF Research Database (Denmark)

Pantleon, Karen; Somers, Marcel A. J.

2009-01-01

have different microstructure and properties compared to bulk materials and the thermodynamic non-equilibrium state of as-deposited layers frequently results in changes of the microstructure as a function of time and/or temperature. The evolving microstructure affects the functionality and reliability......The technological demand for manufacturing components with complex geometries of micrometer or sub-micrometer dimensions and ambitions for ongoing miniaturization have attracted particular attention to electrochemical deposition methods. Thin layers of electrochemically deposited metals and alloys...... of electrodeposited components, which can be beneficial, as for the electrical conductivity of copper interconnect lines, or detrimental, as for reduced strength of nickel in MEMS applications. The present work reports on in-situ studies of the microstructure stability of as-deposited nanocrystalline Cu-, Ag- and Ni...

X-ray in-situ study of copper electrodeposition on UHV prepared GaAs(001) surfaces

Energy Technology Data Exchange (ETDEWEB)

Gruender, Yvonne

2008-06-02

For this work a unique setup for in-situ electrochemical studies was employed and improved. This setup permits UHV preparation of the GaAs(001) surface with a defined surface termination (arsenic-rich or gallium-rich) and its characterization by SXRD in UHV, under ambient pressure in inert gas and in electrolyte under potential control without passing through air. The GaAs(001) surfaces were capped by amorphous arsenic. This permitted to ship them through ambient air. Afterwards smooth well defined GaAs(001) surfaces could be recovered by thermal annealing in UHV. A first investigation of the arsenic capped sample was done by atomic force microscopy (AFM) and Surface X-Ray Diffraction (SXRD). The non bulk like termination of the arsenic buried GaAs(001) surface was revealed. For the electrochemical metal deposition, arsenic terminated (2 x 4) reconstructed and gallium terminated (4 x 2) reconstructed GaAs(001) surfaces were employed. These surfaces were characterized by STM, LEED and a first time by SXRD. The surfaces are smooth, however, a higher degree of disorder than for MBE prepared reconstructed GaAs(001) is found. After exposure of the sample to nitrogen, the surfaces were then again studied by SXRD. These two steps characterizing the bare GaAs(001) surfaces permitted us to get a better knowledge of the starting surface and its influence on the later electrodeposited copper. At ambient pressure both reconstructions are lifted, but the surface is not bulk-like terminated as can be deduced from the crystal truncation rods. Epitaxial copper clusters grow upon electrodeposition on the UHV prepared GaAs(001) surface. The copper lattice is rotated and inclined with respect to the GaAs substrate lattice, leading to eight symmetry equivalent domains. The influence of the surface termination as well as the nucleation potential on the structure of the electrodeposited copper were investigated. The tilt and rotation angles do not depend on the deposition potential but

Proton microprobe study of tin-polymetallic deposits

Energy Technology Data Exchange (ETDEWEB)

Murao, S [Geological Survey of Japan, Tsukuba, Ibaraki (Japan); Sie, S H; Suter, G F [Commonwealth Scientific and Industrial Research Organisation (CSIRO), North Ryde, NSW (Australia). Div. of Exploration Geoscience

1997-12-31

Tin-polymetallic vein type deposits are a complex mixture of cassiterite and sulfides and they are the main source of technologically important rare metals such as indium and bismuth. Constituent minerals are usually fine grained having wide range of chemical composition and often the elements of interest occur as trace elements not amenable to electron microprobe analysis. PIXE with a proton microprobe can be an effective tool to study such deposits by delineating the distribution of trace elements among carrier minerals. Two representative indium-bearing deposits of tin- polymetallic type, Tosham of India (Cu-ln-Bi-Sn-W-Ag), and Mount Pleasant of Canada (Zn-Cu-In-Bi-Sn-W), were studied to delineate the distribution of medical/high-tech rare metals and to examine the effectiveness of the proton probe analysis of such ore. One of the results of the study indicated that indium and bismuth are present in chalcopyrite in the deposits. In addition to these important rare metals, zinc, copper, arsenic, antimony, selenium, and tin are common in chalcopyrite and pyrite. Arsenopyrite contains nickel, copper, zinc, silver, tin, antimony and bismuth. In chalcopyrite and pyrite, zinc, arsenic, indium, bismuth and lead are richer in Mount Pleasant ore, but silver is higher at Tosham. Also thallium and gold were found only in Tosham pyrite. The Tosham deposit is related to S-type granite, while Mount Pleasant to A-type. It appears that petrographic character of the source magma is one of the factors to determine the trace element distribution in tin-polymetallic deposit. 6 refs., 2 figs.

Proton microprobe study of tin-polymetallic deposits

Energy Technology Data Exchange (ETDEWEB)

Murao, S. [Geological Survey of Japan, Tsukuba, Ibaraki (Japan); Sie, S.H.; Suter, G.F. [Commonwealth Scientific and Industrial Research Organisation (CSIRO), North Ryde, NSW (Australia). Div. of Exploration Geoscience

1996-12-31

Tin-polymetallic vein type deposits are a complex mixture of cassiterite and sulfides and they are the main source of technologically important rare metals such as indium and bismuth. Constituent minerals are usually fine grained having wide range of chemical composition and often the elements of interest occur as trace elements not amenable to electron microprobe analysis. PIXE with a proton microprobe can be an effective tool to study such deposits by delineating the distribution of trace elements among carrier minerals. Two representative indium-bearing deposits of tin- polymetallic type, Tosham of India (Cu-ln-Bi-Sn-W-Ag), and Mount Pleasant of Canada (Zn-Cu-In-Bi-Sn-W), were studied to delineate the distribution of medical/high-tech rare metals and to examine the effectiveness of the proton probe analysis of such ore. One of the results of the study indicated that indium and bismuth are present in chalcopyrite in the deposits. In addition to these important rare metals, zinc, copper, arsenic, antimony, selenium, and tin are common in chalcopyrite and pyrite. Arsenopyrite contains nickel, copper, zinc, silver, tin, antimony and bismuth. In chalcopyrite and pyrite, zinc, arsenic, indium, bismuth and lead are richer in Mount Pleasant ore, but silver is higher at Tosham. Also thallium and gold were found only in Tosham pyrite. The Tosham deposit is related to S-type granite, while Mount Pleasant to A-type. It appears that petrographic character of the source magma is one of the factors to determine the trace element distribution in tin-polymetallic deposit. 6 refs., 2 figs.

Proton microprobe study of tin-polymetallic deposits

International Nuclear Information System (INIS)

Murao, S.; Sie, S.H.; Suter, G.F.

1996-01-01

Tin-polymetallic vein type deposits are a complex mixture of cassiterite and sulfides and they are the main source of technologically important rare metals such as indium and bismuth. Constituent minerals are usually fine grained having wide range of chemical composition and often the elements of interest occur as trace elements not amenable to electron microprobe analysis. PIXE with a proton microprobe can be an effective tool to study such deposits by delineating the distribution of trace elements among carrier minerals. Two representative indium-bearing deposits of tin- polymetallic type, Tosham of India (Cu-ln-Bi-Sn-W-Ag), and Mount Pleasant of Canada (Zn-Cu-In-Bi-Sn-W), were studied to delineate the distribution of medical/high-tech rare metals and to examine the effectiveness of the proton probe analysis of such ore. One of the results of the study indicated that indium and bismuth are present in chalcopyrite in the deposits. In addition to these important rare metals, zinc, copper, arsenic, antimony, selenium, and tin are common in chalcopyrite and pyrite. Arsenopyrite contains nickel, copper, zinc, silver, tin, antimony and bismuth. In chalcopyrite and pyrite, zinc, arsenic, indium, bismuth and lead are richer in Mount Pleasant ore, but silver is higher at Tosham. Also thallium and gold were found only in Tosham pyrite. The Tosham deposit is related to S-type granite, while Mount Pleasant to A-type. It appears that petrographic character of the source magma is one of the factors to determine the trace element distribution in tin-polymetallic deposit. 6 refs., 2 figs

Modeling transport and deposition of the Mekong River sediment

Science.gov (United States)

Xue, Zuo; He, Ruoying; Liu, J. Paul; Warner, John C.

2012-01-01

A Coupled Wave–Ocean–SedimentTransport Model was used to hindcast coastal circulation and fine sedimenttransport on the Mekong shelf in southeastern Asian in 2005. Comparisons with limited observations showed that the model simulation captured the regional patterns and temporal variability of surface wave, sea level, and suspended sediment concentration reasonably well. Significant seasonality in sedimenttransport was revealed. In summer, a large amount of fluvial sediments was delivered and deposited near the MekongRiver mouth. In the following winter, strong ocean mixing, and coastal current lead to resuspension and southwestward dispersal of a small fraction of previously deposited sediments. Model sensitivity experiments (with reduced physics) were performed to investigate the impact of tides, waves, and remotely forced ambient currents on the transport and dispersal of the fluvial sediment. Strong wave mixing and downwelling-favorable coastal current associated with the more energetic northeast monsoon in the winter season are the main factors controlling the southwestward along-shelf transport.

Growth of magnesium diboride films on 2 inch diameter copper discs by hybrid physical–chemical vapor deposition

Energy Technology Data Exchange (ETDEWEB)

Withanage, Wenura K.; Xi, X. X.; Nassiri, Alireza; Lee, Namhoon; Wolak, Matthäus A.; Tan, Teng; Welander, Paul B.; Franzi, Matthew; Tantawi, Sami; Kustom, Robert L.

2017-02-16

Magnesium diboride (MgB2) coating is a potential candidate to replace bulk niobium (Nb) for superconducting radio frequency cavities due to the appealing superconducting properties of MgB2. MgB2 coating on copper may allow cavity operation near 20–25 K as a result of the high transition temperature (T c) of MgB2 and excellent thermal conductivity of Cu. We have grown MgB2 films on 2 inch diameter Cu discs by hybrid physical–chemical vapor deposition for radio frequency characterization. Structural and elemental analyses showed a uniform MgB2 coating on top of a Mg–Cu alloy layer with occasional intrusion of Mg–Cu alloy regions. High T c values of around 37 K and high critical current density (J c) on the order of 107 A cm-2 at zero field were observed. Radio frequency measurements at 11.4 GHz confirmed a high T c and showed a quality factor (Q 0) much higher than for Cu and close to that of Nb.

Growth of magnesium diboride films on 2 inch diameter copper discs by hybrid physical-chemical vapor deposition

Science.gov (United States)

Withanage, Wenura K.; Xi, X. X.; Nassiri, Alireza; Lee, Namhoon; Wolak, Matthäus A.; Tan, Teng; Welander, Paul B.; Franzi, Matthew; Tantawi, Sami; Kustom, Robert L.

2017-04-01

Magnesium diboride (MgB2) coating is a potential candidate to replace bulk niobium (Nb) for superconducting radio frequency cavities due to the appealing superconducting properties of MgB2. MgB2 coating on copper may allow cavity operation near 20-25 K as a result of the high transition temperature (T c) of MgB2 and excellent thermal conductivity of Cu. We have grown MgB2 films on 2 inch diameter Cu discs by hybrid physical-chemical vapor deposition for radio frequency characterization. Structural and elemental analyses showed a uniform MgB2 coating on top of a Mg-Cu alloy layer with occasional intrusion of Mg-Cu alloy regions. High T c values of around 37 K and high critical current density (J c) on the order of 107 A cm-2 at zero field were observed. Radio frequency measurements at 11.4 GHz confirmed a high T c and showed a quality factor (Q 0) much higher than for Cu and close to that of Nb.

Study of underpotential deposited Cu layers on Pt(111) and their stability against CO and CO2 in perchloric acid

DEFF Research Database (Denmark)

Schlaup, Christian Georg; Horch, Sebastian

2013-01-01

The underpotential deposition (UPD) of copper on a Pt(111) electrode and the influence of gas coadsorbates, i.e. CO and CO2, on the thus deposited copper layer were studied in a 0.1 M HClO4 electrolyte by means of EC-STM. By UPD, an atomically flat Cu layer is formed, which exhibits a pseudomorph...

LA-MC-ICPMS Determination of Copper Isotope Ratios in Turquoise from the Southwestern United States.

Science.gov (United States)

Evans, M. J.; Fayek, M.; Riciputi, L.; Anovitz, L.; Hull, S.; Mathien, F. J.; Milford, H.

2004-12-01

Hydrothermal circulation driven by igneous intrusion led to the deposition of turquoise throughout the southwestern United States and Mesoamerica. The genesis of these copper-ore deposits is unclear; conflicting hypotheses call on ascent of magmatic waters (hypogene) or descent and recirculation of meteroric waters (supergene). Copper isotope analyses were performed by laser-ablation multi-collector ICPMS to survey turquoise deposits from AZ, NV, CA, NM, and CO. The turquoise have [Cu] from 0.1 to 10 wt% and are all found in near-surface alteration zones. Analyses of individual turquoise grains are reproducible to better than 0.4\\permil \\delta65Cu (1\\sigma) (relative to NBS-976). \\delta65Cu values show significant variation (ca. 10\\permil) between the deposits, equal to the total range reported for continental ores and both hypogene and supergene deposits. The variability between deposits may reflect differences in source Cu isotopic composition or more likely, hydrothermal processes during leaching and deposition. The mining and trade of turquoise played an important role in early social and economic development between Mesoamerica and N. America. Copper isotopes will improve differentiation between turquoise source areas, aiding archaeological and cultural studies of trade between and within Mesoamerica and the SW USA. Research sponsored by NSF-BCS (Archaeology) grant #0312088 to Fayek and the Office of Basic Energy Sciences, U.S. Department of Energy, under contract with Oak Ridge National Laboratory, managed by UT-Battelle, LLC. The submitted manuscript has been authored by a contractor of the U.S. Government under contract No. DE-AC05-00OR22725. Accordingly, the U.S. Government retains a nonexclusive, royalty-free license to publish or reproduce the published form of this contribution, or allow others to do so, for U.S. Government purposes.

Copper removal and microbial community analysis in single-chamber microbial fuel cell.

Science.gov (United States)

Wu, Yining; Zhao, Xin; Jin, Min; Li, Yan; Li, Shuai; Kong, Fanying; Nan, Jun; Wang, Aijie

2018-04-01

In this study, copper removal and electricity generation were investigated in a single-chamber microbial fuel cell (MFC). Result showed that copper was efficiently removed in the membrane-less MFC with removal efficiency of 98.3% at the tolerable Cu 2+ concentration of 12.5 mg L -1 , the corresponding open circuit voltage and maximum power density were 0.78 V and 10.2 W m -3 , respectively. The mechanism analysis demonstrated that microbial electrochemical reduction contributed to the copper removal with the products of Cu and Cu 2 O deposited at biocathode. Moreover, the microbial community analysis indicated that microbial communities changed with different copper concentrations. The dominant phyla were Proteobacteria and Bacteroidetes which could play key roles in electricity generation, while Actinobacteria and Acidobacteria were also observed which were responsible for Cu-resistant and copper removal. It will be of important guiding significance for the recovery of copper from low concentration wastewater through single-chamber MFC with simultaneous energy recovery. Copyright © 2018 Elsevier Ltd. All rights reserved.

Copper-bearing (Paraíba-type) tourmaline from Mozambique

NARCIS (Netherlands)

Laurs, B.M.; Zwaan, J.C.; Breeding, C.M.; Simmons, W.B.; Beaton, D.; Rijsdijk, K.F.; Befi, R.; Falster, A.U.

2008-01-01

Copper-bearing tourmaline from Mozambique was first recovered in 2001, but its Cu content was not recognized until 2003, and it was not widely sold with its Mozambique origin disclosed until 2005. It has been mined from alluvial deposits in an approximately 3 km2 area near Mavuco in the eastern

Enhanced energy deposition symmetry by hot electron transport

International Nuclear Information System (INIS)

Wilson, D.; Mack, J.; Stover, E.; VanHulsteyn, D.; McCall, G.; Hauer, A.

1981-01-01

High energy electrons produced by resonance absorption carry the CO 2 laser energy absorbed in a laser fusion pellet. The symmetrization that can be achieved by lateral transport of the hot electrons as they deposit their energy is discussed. A K/sub α/ experiment shows a surprising symmetrization of energy deposition achieved by adding a thin layer of plastic to a copper sphere. Efforts to numerically model this effect are described

Provenance of Coastal dune sands along Red Sea, Egypt

Indian Academy of Sciences (India)