An Enhanced Plane Wave Expansion Method to Solve Piezoelectric Phononic Crystal with Resonant Shunting Circuits

Directory of Open Access Journals (Sweden)

Ziyang Lian

2016-01-01

Full Text Available An enhanced plane wave expansion (PWE method is proposed to solve piezoelectric phononic crystal (PPC connected with resonant shunting circuits (PPC-C, which is named as PWE-PPC-C. The resonant shunting circuits can not only bring about the locally resonant (LR band gap for the PPC-C but also conveniently tune frequency and bandwidth of band gaps through adjusting circuit parameters. However, thus far, more than one-dimensional PPC-C has been studied just by Finite Element method. Compared with other methods, the PWE has great advantages in solving more than one-dimensional PC as well as various lattice types. Nevertheless, the conventional PWE cannot accurately solve coupling between the structure and resonant shunting circuits of the PPC-C since only taking one-way coupling from displacements to electrical parameters into consideration. A two-dimensional PPC-C model of orthorhombic lattice is established to demonstrate the whole solving process of PWE-PPC-C. The PWE-PPC-C method is validated by Transfer Matrix method as well as Finite Element method. The dependence of band gaps on circuit parameters has been investigated in detail by PWE-PPC-C. Its advantage in solving various lattice types is further illustrated by calculating the PPC-C of triangular and hexagonal lattices, respectively.

Cooperative Research Projects in the Microgravity Combustion Science Programs Sponsored by NASA and NEDO

Science.gov (United States)

Ross, Howard (Compiler)

2000-01-01

This document contains the results of a collection of selected cooperative research projects between principal investigators in the microgravity combustion science programs, sponsored by NASA and NEDO. Cooperation involved the use of drop towers in Japan and the United States, and the sharing of subsequent research data and findings. The topical areas include: (1) Interacting droplet arrays, (2) high pressure binary fuel sprays, (3) sooting droplet combustion, (4) flammability limits and dynamics of spherical, premixed gaseous flames and, (5) ignition and transition of flame spread across thin solid fuel samples. All of the investigators view this collaboration as a success. Novel flame behaviors were found and later published in archival journals. In some cases the experiments provided verification of the design and behavior in subsequent experiments performed on the Space Shuttle. In other cases, the experiments provided guidance to experiments that are expected to be performed on the International Space Station.

Gas-phase reactions at combustion and gasification

International Nuclear Information System (INIS)

Hupa, M.; Kilpinen, P.; Chowdhury, K.; Brink, A.; Mueller, C.

1995-01-01

Formation and destruction of gaseous nitrogen pollutants at combustion (NO x , N 2 O) and gasification (NH 3 , HCN) are studied based on detailed chemical kinetic modelling and experiments in laboratory reactors. During 1994 the following topics have been studied: (a) nitrogen reactions in pressurized combustion processes (in co-operation with the LIEKKI projects 202 and 204), (b) NO x reduction by staging techniques in CO 2 , rich combustion processes, (c) HCN reactions at pyrolysis, (d) formation of soot precursors in a blast furnace (in co-operation with the SULA project 103) (e) incorporation of better NO x description into furnace models, (in co-operation with the LIEKKI project Y01). NH 3 conversion to N 2 in gasification product gases, (in co-operation with the LIEKKI project 203). In this report, some results of the items (a-c) will be presented. The results of items (d-f) are described in the reports by the co-operation projects. (author)

Development of High Efficiency Clean Combustion Engine Designs for Spark-Ignition and Compression-Ignition Internal Combustion Engines

Energy Technology Data Exchange (ETDEWEB)

Marriott, Craig; Gonzalez, Manual; Russell, Durrett

2011-06-30

This report summarizes activities related to the revised STATEMENT OF PROJECT OBJECTIVES (SOPO) dated June 2010 for the Development of High-Efficiency Clean Combustion engine Designs for Spark-Ignition and Compression-Ignition Internal Combustion Engines (COOPERATIVE AGREEMENT NUMBER DE-FC26-05NT42415) project. In both the spark- (SI) and compression-ignition (CI) development activities covered in this program, the goal was to develop potential production-viable internal combustion engine system technologies that both reduce fuel consumption and simultaneously met exhaust emission targets. To be production-viable, engine technologies were also evaluated to determine if they would meet customer expectations of refinement in terms of noise, vibration, performance, driveability, etc. in addition to having an attractive business case and value. Prior to this activity, only proprietary theoretical / laboratory knowledge existed on the combustion technologies explored The research reported here expands and develops this knowledge to determine series-production viability. Significant SI and CI engine development occurred during this program within General Motors, LLC over more than five years. In the SI program, several engines were designed and developed that used both a relatively simple multi-lift valve train system and a Fully Flexible Valve Actuation (FFVA) system to enable a Homogeneous Charge Compression Ignition (HCCI) combustion process. Many technical challenges, which were unknown at the start of this program, were identified and systematically resolved through analysis, test and development. This report documents the challenges and solutions for each SOPO deliverable. As a result of the project activities, the production viability of the developed clean combustion technologies has been determined. At this time, HCCI combustion for SI engines is not considered production-viable for several reasons. HCCI combustion is excessively sensitive to control variables

Reaction and diffusion in turbulent combustion

Energy Technology Data Exchange (ETDEWEB)

Pope, S.B. [Mechanical and Aerospace Engineering, Ithaca, NY (United States)

1993-12-01

The motivation for this project is the need to obtain a better quantitative understanding of the technologically-important phenomenon of turbulent combustion. In nearly all applications in which fuel is burned-for example, fossil-fuel power plants, furnaces, gas-turbines and internal-combustion engines-the combustion takes place in a turbulent flow. Designers continually demand more quantitative information about this phenomenon-in the form of turbulent combustion models-so that they can design equipment with increased efficiency and decreased environmental impact. For some time the PI has been developing a class of turbulent combustion models known as PDF methods. These methods have the important virtue that both convection and reaction can be treated without turbulence-modelling assumptions. However, a mixing model is required to account for the effects of molecular diffusion. Currently, the available mixing models are known to have some significant defects. The major motivation of the project is to seek a better understanding of molecular diffusion in turbulent reactive flows, and hence to develop a better mixing model.

Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion

Energy Technology Data Exchange (ETDEWEB)

Ojeda, William de

2010-07-31

The project which extended from November 2005 to May of 2010 demonstrated the application of Low Temperature Combustion (LTC) with engine out NOx levels of 0.2 g/bhp-hr throughout the program target load of 12.6bar BMEP. The project showed that the range of loads could be extended to 16.5bar BMEP, therefore matching the reference lug line of the base 2007 MY Navistar 6.4L V8 engine. Results showed that the application of LTC provided a dramatic improvement over engine out emissions when compared to the base engine. Furthermore LTC improved thermal efficiency by over 5% from the base production engine when using the steady state 13 mode composite test as a benchmark. The key enablers included improvements in the air, fuel injection, and cooling systems made in Phases I and II. The outcome was the product of a careful integration of each component under an intelligent control system. The engine hardware provided the conditions to support LTC and the controller provided the necessary robustness for a stable combustion. Phase III provided a detailed account on the injection strategy used to meet the high load requirements. During this phase, the control strategy was implemented in a production automotive grade ECU to perform cycle-by-cycle combustion feedback on each of the engine cylinders. The control interacted on a cycle base with the injection system and with the Turbo-EGR systems according to their respective time constants. The result was a unique system that could, first, help optimize the combustion system and maintain high efficiency, and secondly, extend the steady state results to the transient mode of operation. The engine was upgraded in Phase IV with a Variable Valve Actuation system and a hybrid EGR loop. The impact of the more versatile EGR loop did not provide significant advantages, however the application of VVA proved to be an enabler to further extend the operation of LTC and gain considerable benefits in fuel economy and soot reduction. Finally

Advanced Diagnostics in Oxy-Fuel Combustion Processes

DEFF Research Database (Denmark)

Brix, Jacob; Toftegaard, Maja Bøg; Clausen, Sønnik

This report sums up the findings in PSO-project 010069, “Advanced Diagnostics in Oxy- Fuel Combustion Processes”. Three areas of optic diagnostics are covered in this work: - FTIR measurements in a 30 kW swirl burner. - IR measurements in a 30 kW swirl burner. - IR measurements in a laboratory...... technique was an invaluable tool in the discussion of data obtained by gas analysis, and it allowed for estimation of combustion times in O2/CO2 where the high CO2 concentration prevents the use of the carbon mass balance for that purpose. During the project the data have been presented at a conference......, formed the basis of a publication and it is part of two PhD dissertations. The name of the conference the journal and the dissertations are listed below. - Joint Meeting of the Scandinavian-Nordic and French Sections of the Combustion Institute, Combustion of Char Particles under Oxy-Fuel Conditions...

Experimental Investigation and High Resolution Simulation of In-Situ Combustion Processes

Energy Technology Data Exchange (ETDEWEB)

Margot Gerritsen; Tony Kovscek

2008-04-30

This final technical report describes work performed for the project 'Experimental Investigation and High Resolution Numerical Simulator of In-Situ Combustion Processes', DE-FC26-03NT15405. In summary, this work improved our understanding of in-situ combustion (ISC) process physics and oil recovery. This understanding was translated into improved conceptual models and a suite of software algorithms that extended predictive capabilities. We pursued experimental, theoretical, and numerical tasks during the performance period. The specific project objectives were (i) identification, experimentally, of chemical additives/injectants that improve combustion performance and delineation of the physics of improved performance, (ii) establishment of a benchmark one-dimensional, experimental data set for verification of in-situ combustion dynamics computed by simulators, (iii) develop improved numerical methods that can be used to describe in-situ combustion more accurately, and (iv) to lay the underpinnings of a highly efficient, 3D, in-situ combustion simulator using adaptive mesh refinement techniques and parallelization. We believe that project goals were met and exceeded as discussed.

Renewable Energy Laboratory Development for Biofuels Advanced Combustion Studies

Energy Technology Data Exchange (ETDEWEB)

Soloiu, Valentin A. [Georgia Southern Univ., Statesboro, GA (United States)

2012-03-31

The research advanced fundamental science and applied engineering for increasing the efficiency of internal combustion engines and meeting emissions regulations with biofuels. The project developed a laboratory with new experiments and allowed investigation of new fuels and their combustion and emissions. This project supports a sustainable domestic biofuels and automotive industry creating economic opportunities across the nation, reducing the dependence on foreign oil, and enhancing U.S. energy security. The one year period of research developed fundamental knowledge and applied technology in advanced combustion, emissions and biofuels formulation to increase vehicle's efficiency. Biofuels combustion was investigated in a Compression Ignition Direct Injection (DI) to develop idling strategies with biofuels and an Indirect Diesel Injection (IDI) intended for auxiliary power unit.

Sandia Combustion Research Program

Energy Technology Data Exchange (ETDEWEB)

Johnston, S.C.; Palmer, R.E.; Montana, C.A. (eds.)

1988-01-01

During the late 1970s, in response to a national energy crisis, Sandia proposed to the US Department of Energy (DOE) a new, ambitious program in combustion research. Shortly thereafter, the Combustion Research Facility (CRF) was established at Sandia's Livermore location. Designated a ''user facility,'' the charter of the CRF was to develop and maintain special-purpose resources to support a nationwide initiative-involving US inventories, industry, and national laboratories--to improve our understanding and control of combustion. This report includes descriptions several research projects which have been simulated by working groups and involve the on-site participation of industry scientists. DOE's Industry Technology Fellowship program, supported through the Office of Energy Research, has been instrumental in the success of some of these joint efforts. The remainder of this report presents results of calendar year 1988, separated thematically into eleven categories. Referred journal articles appearing in print during 1988 and selected other publications are included at the end of Section 11. Our traditional'' research activities--combustion chemistry, reacting flows, diagnostics, engine and coal combustion--have been supplemented by a new effort aimed at understanding combustion-related issues in the management of toxic and hazardous materials.

Energy balance of a wood biomass combustion process

International Nuclear Information System (INIS)

Baggio, P.; Cemin, A.; Grigiante, M.; Ragazzi, M.

2001-01-01

This article reports the results of a project developed at the University of Trent dealing with some wood biomass combustion processes. The project has been particularly dedicated to the study of the energetic analysis of the combustion processes that occur on a gasified wood stove of advanced combustion technologies. A considerable number of experimental tests has been carried out making use of different type of wood widely in use in Trentino region. The wood stove is a part of a pilot plant providing an hydraulic circuit equipped with a specific apparatus to measure all the necessary data to determine the energy balance required and specifically the thermal efficiency of the plant [it

ACACIA Project - Development of a Post-Combustion CO2 Capture Process. Case of the DMXTM Process

International Nuclear Information System (INIS)

Gomez, A.; Briot, P.; Raynal, L.; Broutin, P.; Gimenez, M.; Soazic, M.; Cessat, P.; Saysset, S.

2014-01-01

The objective of the ACACIA project was to develop processes for post-combustion CO 2 capture at a lower cost and with a higher energetic efficiency than first generation processes using amines such as Monoethanolamine (MEA) which are now considered for the first Carbon Capture and Storage (CCS) demonstrators. The partners involved in this project were: Rhodia (Solvay since then), Arkema, Lafarge, GDF SUEZ, Veolia Environnement, IFP Energies nouvelles, IRCE Lyon, LMOPS, LTIM, LSA Armines. To validate the relevance of the breakthrough processes studied in this project, techno-economic evaluations were carried out with comparison to the reference process using a 30 wt% MEA solvent. These evaluation studies involved all the industrial partners of the project, each partner bringing specific cases of CO 2 capture on their industrial facilities. From these studies, only the process using de-mixing solvent, DMX TM , developed by IFPEN appears as an alternative solution to the MEA process. (authors)

Annual Report: Advanced Combustion (30 September 2012)

Energy Technology Data Exchange (ETDEWEB)

Hawk, Jeffrey [NETL; Richards, George

2012-09-30

The Advanced Combustion Project addresses fundamental issues of fire-side and steam-side corrosion and materials performance in oxy-fuel combustion environments and provides an integrated approach into understanding the environmental and mechanical behavior such that environmental degradation can be ameliorated and long-term microstructural stability, and thus, mechanical performance can lead to longer lasting components and extended power plant life. The technical tasks of this effort are Oxy-combustion Environment Characterization, Alloy Modeling and Life Prediction, and Alloy Manufacturing and Process Development.

Toxic combustion products from pesticide fires. Executive summary

NARCIS (Netherlands)

Molag, M.; Bartelds, H.; Weger, D. de

1992-01-01

In order to obtain reliable data on the generation of toxic combustion products and to get more insight into the risks of fires in pesticide warehouses TNO performed the research project 'Toxic combustion products from pesticide fires'. The following research activities have been performed during

Combustion characterization of beneficiated coal-based fuels

Energy Technology Data Exchange (ETDEWEB)

Chow, O.K.; Levasseur, A.A.

1995-11-01

The Pittsburgh Energy Technology Center (PETC) of the U.S. Department of Energy is sponsoring the development of advanced coal-cleaning technologies aimed at expanding the use of the nation`s vast coal reserves in an environmentally and economically acceptable manner. Because of the lack of practical experience with deeply beneficiated coal-based fuels, PETC has contracted Combustion Engineering, Inc. to perform a multi-year project on `Combustion Characterization of Beneficiated Coal-Based Fuels.` The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of Beneficiated Coal-Based Fuels (BCs) influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs.

Wood products in the waste stream: Characterization and combustion emissions. Volume 1. Final report

International Nuclear Information System (INIS)

1992-11-01

Waste wood is wood separated from the solid-waste stream and processed into a uniform-sized product that is reused for other purposes such as fuel. As an alternative to the combustion of fossil fuels, it has raised concerns that if it is 'contaminated' with paints, resins, preservatives, etc., unacceptable environmental impacts may be generated during combustion. Given the difficulty of separating contaminated materials from waste wood and the large energy potential existing in the resource, it is important to identify possible problems associated with contaminated waste wood combustion. The study describes research about technical, public policy, and regulatory issues that affect the processing and combustion of waste wood for fuel. The project's purpose was to provide environmental regulators, project developers, and others with data to make informed decisions on the use of waste wood materials as a combustion resource. Potential environmental problems and solutions were identified. A specific project result was the identification of combustion system operation parameters and air pollution control technologies that can minimize emissions of identified air and solid waste contaminants from combustion of wood waste

FY 1994 annual report. Advanced combustion science utilizing microgravity

Energy Technology Data Exchange (ETDEWEB)

NONE

1994-10-01

Researches on combustion in microgravity were conducted to develop combustion devices for advanced combustion techniques, and thereby to cope with the requirements for diversification of energy sources and abatement of environmental pollution by exhaust gases. This project was implemented under the research cooperation agreement with US's NASA, and the Japanese experts visited NASA's test facilities. NASA's Lewis Research Center has drop test facilities, of which the 2.2-sec drop test facilities are useful for researches by Japan. The cooperative research themes for combustion in microgravity selected include interactions between fuel droplets, high-pressure combustion of binary fuel sprays, and ignition and subsequent flame propagation in microgravity. An ignition test equipment, density field measurement equipment and flame propagation test equipment were constructed in Japan to conduct the combustion tests in microgravity for, e.g., combustion and evaporation of fuel droplets, combustion characteristics of liquid fuels mixed with solid particles, combustion of coal/oil mixture droplets, and estimating flammability limits. (NEDO)

Novel approaches in advanced combustion characterization of fuels for advanced pressurized combustion

Energy Technology Data Exchange (ETDEWEB)

Aho, M.; Haemaelaeinen, J. [VTT Energy (Finland); Joutsenoja, T. [Tampere Univ. of Technology (Finland)

1996-12-01

This project is a part of the EU Joule 2 (extension) programme. The objective of the research of Technical Research Centre of Finland (VTT) is to produce experimental results of the effects of pressure and other important parameters on the combustion of pulverized coals and their char derivates. The results can be utilized in modelling of pressurized combustion and in planning pilot-scale reactors. The coals to be studied are Polish hvb coal, French lignite (Gardanne), German anthracite (Niederberg) and German (Goettelbom) hvb coal. The samples are combusted in an electrically heated, pressurized entrained flow reactor (PEFR), where the experimental conditions are controlled with a high precision. The particle size of the fuel can vary between 100 and 300 {mu}m. The studied things are combustion rates, temperatures and sizes of burning single coal and char particles. The latter measurements are performed with a method developed by Tampere University of Technology, Finland. In some of the experiments, mass loss and elemental composition of the char residue are studied in more details as the function of time to find out the combustion mechanism. Combustion rate of pulverized (140-180 {mu}m) Gardanne lignite and Niederberg anthracite were measured and compared with the data obtained earlier with Polish hvb coal at various pressures, gas temperatures, oxygen partial pressures and partial pressures of carbon dioxide in the second working period. In addition, particle temperatures were measured with anthracite. The experimental results were treated with multivariable partial least squares (PLS) method to find regression equation between the measured things and the experimental variables. (author)

NOx Emission Reduction by Oscillating Combustion

Energy Technology Data Exchange (ETDEWEB)

John C. Wagner

2004-03-31

High-temperature, natural gas-fired furnaces, especially those fired with preheated air, produce large quantities of NO{sub x} per ton of material processed. Regulations on emissions from industrial furnaces are becoming increasingly more stringent. In addition, competition is forcing operators to make their furnaces more productive and/or efficient. Switching from preheated air to industrial oxygen can increase efficiency and reduce NO{sub x}, but oxygen is significantly more costly than air and may not be compatible with the material being heated. What was needed, and what was developed during this project, is a technology that reduces NO{sub x} emissions while increasing furnace efficiency for both air- and oxy-fired furnaces. Oscillating combustion is a retrofit technology that involves the forced oscillation of the fuel flow rate to a furnace. These oscillations create successive, fuel-rich and fuel-lean zones within the furnace. Heat transfer from the flame to the load increases due to the more luminous fuel-rich zones, a longer overall flame length, and the breakup of the thermal boundary layer. The increased heat transfer shortens heat up times, thereby increasing furnace productivity, and reduces the heat going up the stack, thereby increasing efficiency. The fuel-rich and fuel-lean zones also produce substantially less NO{sub x} than firing at a constant excess air level. The longer flames and higher heat transfer rate reduces overall peak flame temperature and thus reduces additional NO{sub x} formation from the eventual mixing of the zones and burnout of combustibles from the rich zones. This project involved the development of hardware to implement oscillating combustion on an industrial scale, the laboratory testing of oscillating combustion on various types of industrial burners, and the field testing of oscillating combustion on several types of industrial furnace. Before laboratory testing began, a market study was conducted, based on the

NOx Emission Reduction by Oscillating combustion

Energy Technology Data Exchange (ETDEWEB)

Institute of Gas Technology

2004-01-30

High-temperature, natural gas-fired furnaces, especially those fired with preheated air, produce large quantities of NO{sub x} per ton of material processed. Regulations on emissions from industrial furnaces are becoming increasingly more stringent. In addition, competition is forcing operators to make their furnaces more productive and/or efficient. Switching from preheated air to industrial oxygen can increase efficiency and reduce NO{sub x}, but oxygen is significantly more costly than air and may not be compatible with the material being heated. What was needed, and what was developed during this project, is a technology that reduces NO{sub x} emissions while increasing furnace efficiency for both air- and oxy-fired furnaces. Oscillating combustion is a retrofit technology that involves the forced oscillation of the fuel flow rate to a furnace. These oscillations create successive, fuel-rich and fuel-lean zones within the furnace. Heat transfer from the flame to the load increases due to the more luminous fuel-rich zones, a longer overall flame length, and the breakup of the thermal boundary layer. The increased heat transfer shortens heat up times, thereby increasing furnace productivity, and reduces the heat going up the stack, thereby increasing efficiency. The fuel-rich and fuel-lean zones also produce substantially less NO{sub x} than firing at a constant excess air level. The longer flames and higher heat transfer rate reduces overall peak flame temperature and thus reduces additional NO{sub x} formation from the eventual mixing of the zones and burnout of combustibles from the rich zones. This project involved the development of hardware to implement oscillating combustion on an industrial scale, the laboratory testing of oscillating combustion on various types of industrial burners, and the field testing of oscillating combustion on several types of industrial furnace. Before laboratory testing began, a market study was conducted, based on the

Gasoline Combustion Fundamentals DOE FY17 Report

Energy Technology Data Exchange (ETDEWEB)

Ekoto, Isaac W. [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

2017-11-01

Advanced automotive gasoline engines that leverage a combination of reduced heat transfer, throttling, and mechanical losses; shorter combustion durations; and higher compression and mixture specific heat ratios are needed to meet aggressive DOE VTP fuel economy and pollutant emission targets. Central challenges include poor combustion stability at low-power conditions when large amounts of charge dilution are introduced and high sensitivity of conventional inductive coil ignition systems to elevated charge motion and density for boosted high-load operation. For conventional spark ignited operation, novel low-temperature plasma (LTP) or pre-chamber based ignition systems can improve dilution tolerances while maintaining good performance characteristics at elevated charge densities. Moreover, these igniters can improve the control of advanced compression ignition (ACI) strategies for gasoline at low to moderate loads. The overarching research objective of the Gasoline Combustion Fundamentals project is to investigate phenomenological aspects related to enhanced ignition. The objective is accomplished through targeted experiments performed in a single-cylinder optically accessible research engine or an in-house developed optically accessible spark calorimeter (OASC). In situ optical diagnostics and ex situ gas sampling measurements are performed to elucidate important details of ignition and combustion processes. Measurements are further used to develop and validate complementary high-fidelity ignition simulations. The primary project audience is automotive manufacturers, Tier 1 suppliers, and technology startups—close cooperation has resulted in the development and execution of project objectives that address crucial mid- to long-range research challenges.

Application and demonstration of oxyfuel combustion technologies to the existing power plant in Australia

Energy Technology Data Exchange (ETDEWEB)

Uchida, Terutoshi; Yamada, Toshihiko; Watanabe, Shuzo; Kiga, Takashi; Gotou, Takahiro [IHI Corporation, Tokyo (Japan). Power Plant Div.; Misawa, Nobuhiro [Electric Power Development Co., Ltd., Tokyo (Japan); Spero, Chris [CS Energy Ltd, Brisbane (Australia)

2013-07-01

Oxyfuel combustion is able to directly make the highly concentrated CO{sub 2} from the flue gas of pulverized coal fired power plant and, therefore, is expected as one of the promising technologies for CO{sub 2} capture. We are advancing the Oxyfuel combustion demonstration project, which is called Callide Oxyfuel Project, with the support of both Australian and Japanese governments. Currently the boiler retrofit work is completed and the commissioning in air combustion is going on. In this paper, we introduce the general outline of the Callide Oxyfuel Project and its progress.

Advanced Combustion Diagnostics and Control for Furnaces, Fired Heaters and Boilers

Energy Technology Data Exchange (ETDEWEB)

Tate, J. D.; Le, Linh D.; Knittel,Trevor; Cowie, Alan

2010-03-20

The objective of this project was to develop and apply enabling tools and methods towards advanced combustion diagnostics and control of fired-equipment in large-scale petrochemical manufacturing. There are a number of technology gaps and opportunities for combustion optimization, including technologies involving advanced in-situ measurements, modeling, and thermal imaging. These technologies intersect most of manufacturing and energy systems within the chemical industry. This project leveraged the success of a previous DOE funded project led by Dow, where we co-developed an in-situ tunable diode laser (TDL) analyzer platform (with Analytical Specialties Inc, now owned by Yokogawa Electric Corp.). The TDL platform has been tested and proven in a number of combustion processes within Dow and outside of Dow. The primary focus of this project was on combustion diagnostics and control applied towards furnaces, fired heaters and boilers. Special emphasis was placed on the development and application of in-situ measurements for O2, CO and methane since these combustion gases are key variables in optimizing and controlling combustion processes safely. Current best practice in the industry relies on measurements that suffer from serious performance gaps such as limited sampling volume (point measurements), poor precision and accuracy, and poor reliability. Phase I of the project addressed these gaps by adding improved measurement capabilities such as CO and methane (ppm analysis at combustion zone temperatures) as well as improved optics to maintain alignment over path lengths up to 30 meters. Proof-of-concept was demonstrated on a modern olefins furnace located at Dow Chemical's facility in Freeport TX where the improved measurements were compared side-by-side to accepted best practice techniques (zirconium oxide and catalytic bead or thick film sensors). After developing and installing the improved combustion measurements (O2, CO, and methane), we also demonstrated

FutureGen 2.0 Oxy-combustion Large Scale Test – Final Report

Energy Technology Data Exchange (ETDEWEB)

Kenison, LaVesta [URS, Pittsburgh, PA (United States); Flanigan, Thomas [URS, Pittsburgh, PA (United States); Hagerty, Gregg [URS, Pittsburgh, PA (United States); Gorrie, James [Air Liquide, Kennesaw, GA (United States); Leclerc, Mathieu [Air Liquide, Kennesaw, GA (United States); Lockwood, Frederick [Air Liquide, Kennesaw, GA (United States); Falla, Lyle [Babcock & Wilcox and Burns McDonnell, Kansas City, MO (United States); Macinnis, Jim [Babcock & Wilcox and Burns McDonnell, Kansas City, MO (United States); Fedak, Mathew [Babcock & Wilcox and Burns McDonnell, Kansas City, MO (United States); Yakle, Jeff [Babcock & Wilcox and Burns McDonnell, Kansas City, MO (United States); Williford, Mark [Futuregen Industrial Alliance, Inc., Morgan County, IL (United States); Wood, Paul [Futuregen Industrial Alliance, Inc., Morgan County, IL (United States)

2016-04-01

The primary objectives of the FutureGen 2.0 CO₂ Oxy-Combustion Large Scale Test Project were to site, permit, design, construct, and commission, an oxy-combustion boiler, gas quality control system, air separation unit, and CO₂ compression and purification unit, together with the necessary supporting and interconnection utilities. The project was to demonstrate at commercial scale (168MWe gross) the capability to cleanly produce electricity through coal combustion at a retrofitted, existing coal-fired power plant; thereby, resulting in near-zeroemissions of all commonly regulated air emissions, as well as 90% CO₂ capture in steady-state operations. The project was to be fully integrated in terms of project management, capacity, capabilities, technical scope, cost, and schedule with the companion FutureGen 2.0 CO₂ Pipeline and Storage Project, a separate but complementary project whose objective was to safely transport, permanently store and monitor the CO₂ captured by the Oxy-combustion Power Plant Project. The FutureGen 2.0 Oxy-Combustion Large Scale Test Project successfully achieved all technical objectives inclusive of front-end-engineering and design, and advanced design required to accurately estimate and contract for the construction, commissioning, and start-up of a commercial-scale "ready to build" power plant using oxy-combustion technology, including full integration with the companion CO₂ Pipeline and Storage project. Ultimately the project did not proceed to construction due to insufficient time to complete necessary EPC contract negotiations and commercial financing prior to expiration of federal co-funding, which triggered a DOE decision to closeout its participation in the project. Through the work that was completed, valuable technical, commercial, and programmatic lessons were learned. This project has significantly advanced the development of near-zero emission technology and will

Catalytic combustion of gasified waste - Experimental part. Final report

Energy Technology Data Exchange (ETDEWEB)

Jaeraas, Sven; Kusar, Henrik [Royal Institute of Technology, Stockholm (Sweden). Chemical Engineering and Technology

2003-08-01

This final report covers the work that has been performed within the project P 10547-2, 'Catalytic combustion of gasified waste - system analysis ORWARE'. This project is part of the research programme 'Energy from Waste' financed by the Swedish National Energy Administration. The project has been carried out at the division of Industrial Ecology and at the division of Chemical Technology at Royal Inst. of Technology. The aim of the project has been to study the potentials for catalytic combustion of gasified waste. The supposed end user of the technique is a smaller community in Sweden with 15,000-20,000 inhabitants. The project contains of two sub projects: an experimental part carried out at Chemical Technology and a system analysis carried out at Industrial Ecology. This report covers the experimental part of the project carried out at Chemical Technology. The aim for the experimental part has been to develop and test catalysts with long life-time and a high performance, to reduce the thermal-NO{sub x} below 5 ppm and to significantly reduce NO{sub x} formed from fuel-bound nitrogen. Different experimental studies have been carried out within the project: a set-up of catalytic materials have been tested over a synthetic mixture of the gasified waste, the influence of sulfur present in the gas stream, NO{sub x} formation from fuel bound nitrogen, kinetic studies of CO and H{sub 2} with and without the presence of water and the effects of adding a co-metal to palladium catalysts Furthermore a novel annular reactor design has been used to carry out experiments for kinetic measurements. Real gasification tests of waste pellets directly coupled to catalytic combustion have successfully been performed. The results obtained from the experiments, both the catalytic combustion and from the gasification, have been possible to use in the system analysis. The aim of the system analysis of catalytic combustion of gasified waste takes into consideration

Novel Active Combustion Control Valve

Science.gov (United States)

Caspermeyer, Matt

2014-01-01

This project presents an innovative solution for active combustion control. Relative to the state of the art, this concept provides frequency modulation (greater than 1,000 Hz) in combination with high-amplitude modulation (in excess of 30 percent flow) and can be adapted to a large range of fuel injector sizes. Existing valves often have low flow modulation strength. To achieve higher flow modulation requires excessively large valves or too much electrical power to be practical. This active combustion control valve (ACCV) has high-frequency and -amplitude modulation, consumes low electrical power, is closely coupled with the fuel injector for modulation strength, and is practical in size and weight. By mitigating combustion instabilities at higher frequencies than have been previously achieved (approximately 1,000 Hz), this new technology enables gas turbines to run at operating points that produce lower emissions and higher performance.

Fundamental mechanisms for conversion of volatiles in biomass and waste combustion. Final report

Energy Technology Data Exchange (ETDEWEB)

Glarborg, P.; Hindiyarti, L.; Marshall, P.; Livbjerg, H.; Dagaut, P.; Jensen, Anker; Frandsen, Flemming

2007-03-15

This project deals with the volatile oxidation chemistry in biomass and waste fired systems, emphasizing reactions important for pollutants emissions (NO{sub x}, SO{sub 2}, HCl, aerosols). The project aims to extend existing models and databases with a number of chemical subsystems that are presently not well understood, but are particularly important in connection with combustion of biomass and waste. The project is divided into 3 tasks. Task 1: Conversion of chlorine, sulfur and alkali gas phase components in combustion of biomass. Task 2: Formation mechanisms for NO{sub x} in the freeboard of grate combustion of biomass. Task 3: Oxidation mechanisms for oxygenated hydrocarbons in the volatiles from pyrolysis of biomass. (au)

Fluidized bed combustion: mixing and pollutant limitation

Energy Technology Data Exchange (ETDEWEB)

Leckner, B. [Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Energy Conversion

1997-10-01

Fluidized bed combustion (FBC) has been applied commercially during a few decades, and sufficient knowledge is gained to design boilers with sizes of up to several hundreds of megawatt thermal power (MW{sub th}). The knowledge of what goes on inside a large combustion chamber is still limited, however, and this impedes further optimization and efficient solution of problems that might occur. Despite this lack of knowledge the present survey deals with combustion chamber processes and discusses mixing and distribution of fuel and air in the combustion chamber and its importance for sulphur capture and reduction of emissions of nitrogen oxides. It is desirable to present the material in a general way and to cover the entire field of FBC. However, the scarce openly published information deals mostly with coal combustion in atmospheric circulating fluidized bed (CFB) combustors, and therefore this application will receive most attention, but reference is also made to pressurized combustion and to other fuels than coal. In this context the important work made in the LIEKKI project on the analysis of different fuels and on the influence of pressure should be especially pointed out. (orig.)

Experimental and CFD investigation of gas phase freeboard combustion

DEFF Research Database (Denmark)

Andersen, Jimmy

Reliable and accurate modeling capabilities for combustion systems are valuable tools for optimization of the combustion process. This work concerns primary precautions for reducing NO emissions, thereby abating the detrimental effects known as “acid rain”, and minimizing cost for flue gas...... treatment. The aim of this project is to provide validation data for Computational Fluid Dynamic (CFD) models relevant for grate firing combustion conditions. CFD modeling is a mathematical tool capable of predicting fluid flow, mixing and chemical reaction with thermal conversion and transport. Prediction......, but under well-defined conditions. Comprehensive experimental data for velocity field, temperatures, and gas composition are obtained from a 50 kW axisymmetric non-swirling natural gas fired combustion setup under two different settings. Ammonia is added to the combustion setup in order to simulate fuel...

Combustion Safety Simplified Test Protocol Field Study

Energy Technology Data Exchange (ETDEWEB)

Brand, L [Gas Technology Inst., Des Plaines, IL (United States); Cautley, D. [Gas Technology Inst., Des Plaines, IL (United States); Bohac, D. [Gas Technology Inst., Des Plaines, IL (United States); Francisco, P. [Gas Technology Inst., Des Plaines, IL (United States); Shen, L. [Gas Technology Inst., Des Plaines, IL (United States); Gloss, S. [Gas Technology Inst., Des Plaines, IL (United States)

2015-11-05

"9Combustions safety is an important step in the process of upgrading homes for energy efficiency. There are several approaches used by field practitioners, but researchers have indicated that the test procedures in use are complex to implement and provide too many false positives. Field failures often mean that the house is not upgraded until after remediation or not at all, if not include in the program. In this report the PARR and NorthernSTAR DOE Building America Teams provide a simplified test procedure that is easier to implement and should produce fewer false positives. A survey of state weatherization agencies on combustion safety issues, details of a field data collection instrumentation package, summary of data collected over seven months, data analysis and results are included. The project provides several key results. State weatherization agencies do not generally track combustion safety failures, the data from those that do suggest that there is little actual evidence that combustion safety failures due to spillage from non-dryer exhaust are common and that only a very small number of homes are subject to the failures. The project team collected field data on 11 houses in 2015. Of these homes, two houses that demonstrated prolonged and excessive spillage were also the only two with venting systems out of compliance with the National Fuel Gas Code. The remaining homes experienced spillage that only occasionally extended beyond the first minute of operation. Combustion zone depressurization, outdoor temperature, and operation of individual fans all provide statistically significant predictors of spillage.

Formation and emission of PM10 in combustion of biofuels. Final report

International Nuclear Information System (INIS)

Johansson, Linda; Tullin, Claes; Leckner, Bo

2004-02-01

Epidemiological studies have shown correlations between negative health effects and increased particle concentrations in the ambient air. Because of this correlation and the increasing biofuel combustion, there is a need to more carefully investigate formation and emissions from biofuel combustion to secure good air quality in the future. This project is limited to primary combustion particles emitted from small-scale biofuel combustion. Small-scale is here defined as combustion devices with an output less than 10 MW. The project is divided into two parts. In the first part, particles from small-scale biofuel combustion have been characterised. In the second part, the formation of particles during biofuel combustion is studied. Characterisation of particle emissions has been performed for a range of different combustion units, i.e. pellet stove with a thermal output of a few kW, domestic wood and pellet boilers and district-heating boilers with thermal outputs around 2 MW. Mass concentration of particles was measured according to Swedish Standard method. Particle mass size distribution was measured using Dekati Low Pressure Impactor (DLPI, size range 30 nm - 10 μm). The number of particles and corresponding size distribution were measured with an Electrical Low Pressure Impactor (ELPI, 30 nm - 10 μm). To some extent, the particle emissions were investigated regarding chemical content and morphology. In all measurement cases, gas concentrations were measured in the flue gas as a control of combustion conditions. The highest mass concentration of particles (2,200 mg/MJ fuel ) was recorded in the flue gas from an old domestic wood log boiler with poor combustion conditions resulting in very high emissions of unburnt (soot). On the other hand, the lowest mass concentration of particles (20 mg/MJ fueI ) was recorded during optimally adjusted pellet combustion, where 83 % of the particles were found to be inorganic. The remaining part consists of unburnt material (e

Oxy-coal Combustion Studies

Energy Technology Data Exchange (ETDEWEB)

Wendt, J. [Univ. of Utah, Salt Lake City, UT (United States); Eddings, E. [Univ. of Utah, Salt Lake City, UT (United States); Lighty, J. [Univ. of Utah, Salt Lake City, UT (United States); Ring, T. [Univ. of Utah, Salt Lake City, UT (United States); Smith, P. [Univ. of Utah, Salt Lake City, UT (United States); Thornock, J. [Univ. of Utah, Salt Lake City, UT (United States); Y Jia, W. Morris [Univ. of Utah, Salt Lake City, UT (United States); Pedel, J. [Univ. of Utah, Salt Lake City, UT (United States); Rezeai, D. [Univ. of Utah, Salt Lake City, UT (United States); Wang, L. [Univ. of Utah, Salt Lake City, UT (United States); Zhang, J. [Univ. of Utah, Salt Lake City, UT (United States); Kelly, K. [Univ. of Utah, Salt Lake City, UT (United States)

2012-01-06

The objective of this project is to move toward the development of a predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. This validation research brings together multi-scale experimental measurements and computer simulations. The combination of simulation development and validation experiments is designed to lead to predictive tools for the performance of existing air fired pulverized coal boilers that have been retrofitted to various oxy-firing configurations. In addition, this report also describes novel research results related to oxy-combustion in circulating fluidized beds. For pulverized coal combustion configurations, particular attention is focused on the effect of oxy-firing on ignition and coal-flame stability, and on the subsequent partitioning mechanisms of the ash aerosol.

Combustion

CERN Document Server

Glassman, Irvin

2008-01-01

Combustion Engineering, a topic generally taught at the upper undergraduate and graduate level in most mechanical engineering programs, and many chemical engineering programs, is the study of rapid energy and mass transfer usually through the common physical phenomena of flame oxidation. It covers the physics and chemistry of this process and the engineering applications-from the generation of power such as the internal combustion automobile engine to the gas turbine engine. Renewed concerns about energy efficiency and fuel costs, along with continued concerns over toxic and particulate emissions have kept the interest in this vital area of engineering high and brought about new developments in both fundamental knowledge of flame and combustion physics as well as new technologies for flame and fuel control. *New chapter on new combustion concepts and technologies, including discussion on nanotechnology as related to combustion, as well as microgravity combustion, microcombustion, and catalytic combustion-all ...

Combustion

CERN Document Server

Glassman, Irvin

1997-01-01

This Third Edition of Glassman's classic text clearly defines the role of chemistry, physics, and fluid mechanics as applied to the complex topic of combustion. Glassman's insightful introductory text emphasizes underlying physical and chemical principles, and encompasses engine technology, fire safety, materials synthesis, detonation phenomena, hydrocarbon fuel oxidation mechanisms, and environmental considerations. Combustion has been rewritten to integrate the text, figures, and appendixes, detailing available combustion codes, making it not only an excellent introductory text but also an important reference source for professionals in the field. Key Features * Explains complex combustion phenomena with physical insight rather than extensive mathematics * Clarifies postulates in the text using extensive computational results in figures * Lists modern combustion programs indicating usage and availability * Relates combustion concepts to practical applications.

Experimental Studies of Hydrocarbon Flame Phenomena: Enabling Combustion Control

Science.gov (United States)

2016-07-30

flames," Physics of Fluids , vol. 7, no. 6, pp. 1447-54, 1995. [8] K. Lyons, " Toward an understanding of the stabilization mechanisms of lifted...Experimental Studies of Hydrocarbon Flame Phenomena: Enabling Combustion Control This report summarizes the research accomplished in the project...34Experimental Studies of Hydrocarbon Flame Phenomena: Enabling Combustion Control". The main areas of activity are: a) electrostatic flame and flow

Study of Adsorbents for the Capture of CO2 in Post-combustion. Contribution of CIEMAT to Module 4 of the CENITCO2 Project

International Nuclear Information System (INIS)

Ruiz, E.; Marono, M.; Sanchez-Hervas, J. M.

2010-01-01

The main goal of CIEMAT within the CENIT-CO 2 project has been the development of a process for CO 2 capture from combustion flue gases by physical adsorption. In the first stage, screening studies to select promising adsorbents were carried out at laboratory scale, using simplified gas compositions. After that, pilot plant studies were performed using appropriate configurations of promising adsorbents under realistic conditions. CO 2 adsorption cyclic capacity of different adsorbents has been studied. Lastly, for the adsorbent selected as most promising, its cyclic efficiency and selectivity for CO 2 adsorption in the presence of other gaseous components (SO 2 , H 2 O, NO) of the combustion gas has been determined, as well as its performance along multiple sorption-desorption cycles in the presence of simulated combustion gas. None of the studied adsorbents, though being promising since they all have a capture efficiency of about 90%, seem to be susceptible of direct application to CO 2 capture by physical adsorption under conditions representative of gases exiting the desulphurization tower of conventional pulverized coal combustion plants. As an alternative, the development of hybrid and regenerable solid sorbents (physical-chemical adsorption) is proposed or the application of new technologies under development such as the electrochemical promotion in capturing CO 2 . (Author) 33 refs.

New approaches for description of nitrogen chemistry in combustion

Energy Technology Data Exchange (ETDEWEB)

Hupa, M.; Kilpinen, P.; Brink, A.; Norstroem, T. [Aabo Akademi, Turku (Finland)

1996-12-01

The aim of the project is to develop novel models for a more accurate description of nitrogen oxide emissions from combustion processes and to increase the understanding of the complex details of homogeneous nitrogen reactions in combustion and gasification. The topics dealt with during 1995 include: (1) effect of Cl on CO oxidation and nitrogen reactions, (2) effect of pressure on NO reduction by SNCR (in co-operation with the project 204), (3) NH{sub 3} conversion to N{sub 2} in gasification gases by selective oxidation (in cooperation with the project 203). In addition, a literature review of the models suggested for the interaction between turbulence and a chemical gas-phase reaction has been made. A commercial CFD code, FLUENT, has also been taken into use. (author)

Combustion engineering

CERN Document Server

Ragland, Kenneth W

2011-01-01

Introduction to Combustion Engineering The Nature of Combustion Combustion Emissions Global Climate Change Sustainability World Energy Production Structure of the Book   Section I: Basic Concepts Fuels Gaseous Fuels Liquid Fuels Solid Fuels Problems Thermodynamics of Combustion Review of First Law Concepts Properties of Mixtures Combustion StoichiometryChemical EnergyChemical EquilibriumAdiabatic Flame TemperatureChemical Kinetics of CombustionElementary ReactionsChain ReactionsGlobal ReactionsNitric Oxide KineticsReactions at a Solid SurfaceProblemsReferences  Section II: Combustion of Gaseous and Vaporized FuelsFlamesLaminar Premixed FlamesLaminar Flame TheoryTurbulent Premixed FlamesExplosion LimitsDiffusion FlamesGas-Fired Furnaces and BoilersEnergy Balance and EfficiencyFuel SubstitutionResidential Gas BurnersIndustrial Gas BurnersUtility Gas BurnersLow Swirl Gas BurnersPremixed-Charge Engine CombustionIntroduction to the Spark Ignition EngineEngine EfficiencyOne-Zone Model of Combustion in a Piston-...

Fundamental Study of Single Biomass Particle Combustion

DEFF Research Database (Denmark)

Momenikouchaksaraei, Maryam

This thesis is a comprehensive study of single biomass particle combustion. The effect of particle shape and size and operating conditions on biomass conversion characteristics were investigated experimentally and theoretically. The experimental samples were divided in two groups: particles...... well-defined conditions, and the complete combustion processes were recorded as video sequences by a CCD camera installed in the set-up. One of the project objectives is to simulate conditions reasonably close to the conditions in a power plant boiler, i.e., reasonably high temperatures (up to 1600°C...

Reduction of NO{sub x} emissions from the combustion of hard coals ''RENOX''; Reduccion de Emisiones de NO{sub x} en la combustion de Carbones Antracitosos ''RENOX''

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-07-01

The present project, whose abbreviated name is RENOX, has the aim of reducing NO{sub x} emissions from the combustion of hard coals or coals with low volatile matter contents. It is applied to the combustion of these coals in arc boilers (or ''U'' boilers), where the necessary combination of long presence times and high hearth temperatures facilitates the high NO{sub x} levels reached. The intended reduction in emissions is approached through the application of primary combustion measures, also known as adjustment or refining of combustion. This solution is adopted for two reasons: due to its efficiency in environmental and economic terms, and because it is an unavoidable step if the levels to be attained require the installation of specific gas crubbing systems (secondary measures). The practical nature of RENOX has led to the development of the project in two phases, corresponding to two logical stages: phase 1, associated with the RNA project, on the characterization of emissions and combustion, complex numeric modelling of flows inside the boiler, and determination of the viability and scope of the optimization of emissions, and phase 2, the OPTINOXproject, which follows the methodology and lessons of the first phase and, as a natural continuation of this, deals with the design, development, manufacturing and validation of a computerized system that processes real time data on the boiler where it is installed to monitor, supervise and control the commercial operation of the plant, optimizing its combustion efficiency and/or NO{sub x} emissions. The practical objective of this project is represented by the construction of a validated prototype to demonstrate the OPTINOX system, which is capable of determining operating and control strategies that can minimize NO{sub x} emissions without unfavourably affecting the productivity and specific consumption of the units. Phase 1 development activities took place in groups 3, 4 and 5 of Compostilla II thermal power

Combustion tests with different pellet qualities

International Nuclear Information System (INIS)

Bachs, A.; Dahlstroem, J.E.; Persson, Henrik; Tullin, C.

1999-05-01

Eight different pellet qualities with the diameters 6, 8 and 10 mm, from eight different producers has been tested in three pellet burners and two pellet stoves. The objective was to investigate how different diameter affect the emissions of CO, OGC and NO x . Previous experience has indicated that the pellet diameter could have significant importance for the combustion. This was not verified in the study. It showed contradictory that the diameter has a minor effect on the combustion result. The study shows that different combustion equipment give different emission. For e g hydrocarbon emissions the difference is a factor 2.2 between the 'best' and the 'worst' equipment fired on full load. The difference increases to 2.7 with lower load. The choice of fuel has a big importance for the quality of the combustion. For hydrocarbons the emissions could in an extreme situation differ with a factor 25 between 'best' and 'worst' fuel. More normally the difference is about a factor of five. Nitrogen oxide emissions are to a major part related to the nitrogen contents in the fuel. The difference between the 'best' and 'worst' fuel is in the range of a factor two. Tests with the same fuel in different equipment gives a variation of 20-30%. The combustion result depends on both the pellet quality and the equipment and there is no fuel that is good in all equipment. The big variation in combustion results shows that there is a big indifference between fuels used for small scale heating Project report from the program: Small scale combustion of biofuels. 2 refs, 15 figs, 5 tabs

Signal validation of SPDS variables for Westinghouse and Combustion Engineering plants - an EPRI project

International Nuclear Information System (INIS)

Anon.

1987-01-01

Signal validation in the context of this project is the process of combining information from multiple plant sensors to produce highly reliable information about plant conditions. High information reliability is achieved by the use of redundant sources of information and by the inherent detection, identification, and isolation of faulty signals. The signal validation methodology that has been developed in previous EPRI-sponsored projects has been enhanced and applied toward validation of critical safety-related SPDS signals in the Northeast Utilities Millstone 3 Westinghouse PWR plant and the Millstone 2 Combustion Engineering PWR plant. The designs were implemented in FORTRAN software and tested off-line using recorded plant sensor data, RETRAN-generated simulation data, and data to exercise software logic branches and the integration of software modules. Designs and software modules have been developed for 15 variables to support six PWR SPDS critical safety functions as required by a utility advisory group attached to the project. The signal validation process automates a task currently performed by plant operators and does so with consistent, verified logic regardless of operator stress and training level. The methodology uses a simple structure of generic software blocks, a modular implementation, and it performs effectively within the processor and memory constraints of modern plant process computers. The ability to detect and isolate sensor failures with greater sensitivity, robustness, and coverage of common-cause failures should ultimately lead to improved plant availability, efficiency, and productivity

Nitrogen Chemistry in Fluidized Bed Combustion of Coal

DEFF Research Database (Denmark)

Jensen, Anker Degn

and reduction by homogeneous and heterogeneous reactions. The data for the estimation of kinetics of the heterogeneous reactions were measured by one of the partners in the project for char and bed material sampled from a pressurized FBC pilot plant burning Kiveton Park coal. Experimental data from the pilot...... plant were used for model verification. The simulations of the NO emission during staged combustion and NH3 injection for NO reduction were in qualitative agreement with the experimental data. A parametric study of the influence of operating conditions on the conversion of fuel-N to NO showed......, the gas interchange coefficient, the bubble size and the bubble rise velocity. The most important combustion parameters were the rate of CO and CH4 combustion and the fraction of CO produced from char combustion. By using a rate of production analysis, the important reactions in the NO model were...

Combustion

CERN Document Server

Glassman, Irvin

1987-01-01

Combustion, Second Edition focuses on the underlying principles of combustion and covers topics ranging from chemical thermodynamics and flame temperatures to chemical kinetics, detonation, ignition, and oxidation characteristics of fuels. Diffusion flames, flame phenomena in premixed combustible gases, and combustion of nonvolatile fuels are also discussed. This book consists of nine chapters and begins by introducing the reader to heats of reaction and formation, free energy and the equilibrium constants, and flame temperature calculations. The next chapter explores the rates of reactio

Final Report - Low Temperature Combustion Chemistry And Fuel Component Interactions

Energy Technology Data Exchange (ETDEWEB)

Wooldridge, Margaret [Univ. of Michigan, Ann Arbor, MI (United States)

2017-02-24

Recent research into combustion chemistry has shown that reactions at “low temperatures” (700 – 1100 K) have a dramatic influence on ignition and combustion of fuels in virtually every practical combustion system. A powerful class of laboratory-scale experimental facilities that can focus on fuel chemistry in this temperature range is the rapid compression facility (RCF), which has proven to be a versatile tool to examine the details of fuel chemistry in this important regime. An RCF was used in this project to advance our understanding of low temperature chemistry of important fuel compounds. We show how factors including fuel molecular structure, the presence of unsaturated C=C bonds, and the presence of alkyl ester groups influence fuel auto-ignition and produce variable amounts of negative temperature coefficient behavior of fuel ignition. We report new discoveries of synergistic ignition interactions between alkane and alcohol fuels, with both experimental and kinetic modeling studies of these complex interactions. The results of this project quantify the effects of molecular structure on combustion chemistry including carbon bond saturation, through low temperature experimental studies of esters, alkanes, alkenes, and alcohols.

Pulsating combustion - Combustion characteristics and reduction of emissions

Energy Technology Data Exchange (ETDEWEB)

Lindholm, Annika

1999-11-01

In the search for high efficiency combustion systems pulsating combustion has been identified as one of the technologies that potentially can meet the objectives of clean combustion and good fuel economy. Pulsating combustion offers low emissions of pollutants, high heat transfer and efficient combustion. Although it is an old technology, the interest in pulsating combustion has been renewed in recent years, due to its unique features. Various applications of pulsating combustion can be found, mainly as drying and heating devices, of which the latter also have had commercial success. It is, however, in the design process of a pulse combustor, difficult to predict the operating frequency, the heat release etc., due to the lack of a well founded theory of the phenomenon. Research concerning control over the combustion process is essential for developing high efficiency pulse combustors with low emissions. Natural gas fired Helmholtz type pulse combustors have been the experimental objects of this study. In order to investigate the interaction between the fluid dynamics and the chemistry in pulse combustors, laser based measuring techniques as well as other conventional measuring techniques have been used. The experimental results shows the possibilities to control the combustion characteristics of pulsating combustion. It is shown that the time scales in the large vortices created at the inlet to the combustion chamber are very important for the operation of the pulse combustor. By increasing/decreasing the time scale for the large scale mixing the timing of the heat release is changed and the operating characteristics of the pulse combustor changes. Three different means for NO{sub x} reduction in Helmholtz type pulse combustors have been investigated. These include exhaust gas recirculation, alteration of air/fuel ratio and changed inlet geometry in the combustion chamber. All used methods achieved less than 10 ppm NO{sub x} emitted (referred to stoichiometric

Gasoline Engine HCCI Combustion - Extending the high load limit

Energy Technology Data Exchange (ETDEWEB)

Dahl, Daniel

2012-07-01

There is an increasing global focus on reducing emissions of greenhouse gases. For the automotive industry this means reducing CO2 emissions of the vehicles manufactured, which is synonymous with reducing their fuel consumption or adapting them for using renewable fuels. This thesis is based on a project aimed at improving the efficiency of gasoline engines in the lower load/speed region. The focus was mainly on a combustion strategy called homogeneous charge compression ignition (HCCI), but also on homogeneous lean and stratified lean spark-ignited combustion. In contrast to traditional stoichiometric spark-ignited combustion, HCCI can operate with diluted mixtures, which leads to better cycle efficiency, smaller pumping losses and smaller heat losses. However, at relatively high loads, HCCI combustion becomes excessively rapid, generating in-cylinder pressure oscillations (ringing), which are perceived as noise by the human ear. The main objective of the project was to identify ways to avoid this ringing behaviour in order to increase the upper load limit of HCCI. This is vital to avoid the need for mode switches to spark-ignited combustion at higher loads and to operate the engine as much as possible in the more effective HCCI mode. The strategy for reducing ringing investigated most extensively in the project was charge stratification, achieved by injecting part of the fuel late in the compression stroke. Available literature on effects of this strategy gave conflicting indications, both positive and negative effects have been reported, depending on the type of fuel and engine used. It was soon found that the strategy is effective for reducing ringing, but with resulting increases of NOX emissions. Further, in order for the strategy to be effective, global air/fuel ratios must not be much leaner than stoichiometric. The increases in NOX emissions were countered by shifting the ratio towards stoichiometric using exhaust gas recirculation (EGR), allowing a three

Catalyzed Combustion In Micro-Propulsion Devices: Project Status

Science.gov (United States)

Sung, C. J.; Schneider, S. J.

2003-01-01

In recent years, there has been a tendency toward shrinking the size of spacecraft. New classes of spacecraft called micro-spacecraft have been defined by their mass, power, and size ranges. Spacecraft in the range of 20 to 100 kg represent the class most likely to be utilized by most small sat users in the near future. There are also efforts to develop 10 to 20 kg class spacecraft for use in satellite constellations. More ambitious efforts will be to develop spacecraft less than 10 kg, in which MEMS fabrication technology is required. These new micro-spacecraft will require new micro-propulsion technology. Although micro-propulsion includes electric propulsion approaches, the focus of this proposed program is micro-chemical propulsion which requires the development of microcombustors. As combustors are scaled down, the surface to volume ratio increases. The heat release rate in the combustor scales with volume, while heat loss rate scales with surface area. Consequently, heat loss eventually dominates over heat release when the combustor size becomes smaller, thereby leading to flame quenching. The limitations imposed on chamber length and diameter has an immediate impact on the degree of miniaturization of a micro-combustor. Before micro-combustors can be realized, such a difficulty must be overcome. One viable combustion alternative is to take advantage of surface catalysis. Micro-chemical propulsion for small spacecraft can be used for primary thrust, orbit insertion, trajectory-control, and attitude control. Grouping micro-propulsion devices in arrays will allow their use for larger thrust applications. By using an array composed of hundreds or thousands of micro-thruster units, a particular configuration can be arranged to be best suited for a specific application. Moreover, different thruster sizes would provide for a range of thrust levels (from N s to mN s) within the same array. Several thrusters could be fired simultaneously for thrust levels higher than

Successful design and application of SNCR parallel to combustion modification

Energy Technology Data Exchange (ETDEWEB)

Zhao, Dongxian; Tang, Leping; Shao, Xiaozhen; Meng, Derun; Li, Hongjian [Tongfang Environment CO., LTD., Beijing (China); Zhou, Wei; Xu, Guang [GE Energy, Anaheim, CA (United States)

2013-07-01

Various De-NOx methods have been recently adopted in China to control NOx emissions including Selective Non-Catalytic Reaction (SNCR) technology. Usually, the design of SNCR system is carried out after the combustion modification technologies, such as low NOx burner (LNB) and over fire air (OFA), have already been installed and in operation. This article discusses how to design the SNCR system parallel to the combustion modification. The SNCR process design consists of three steps: (1) boiler baseline test, (2) computational fluid dynamics simulation (CFD) facilitated design and (3) SNCR system performance predictions and optimizations. The first step is to conduct boiler baseline test to characterize the boiler operating conditions at a load range. The test data can also be used to calibrate the CFD model. The second step is to develop a three-dimensional boiler coal combustion CFD model to simulate the operation of the boilers at both baseline and post combustion modification conditions. The simulation reveals velocity, temperature and combustible distributions in the furnace. The last step is to determine the position and numbers of the injectors for SNCR reagent. The final field tests upon the project completion have shown that the average SNCR De-NOx efficiency has reached 35.1% with the maximum removal efficiency of 45% on full load. The project also couples the SNCR and SCR (Selective Catalytic Reduction) technologies. The combined removal efficiency of combustion modifications, SNCR and SCR is higher than 82%. This paper shows a successful example for retrofitting aged power-generating units with limited space.

Staged, High-Pressure Oxy-Combustion Technology: Development and Scale-Up

Energy Technology Data Exchange (ETDEWEB)

Axelbaum, Richard [Washington Univ., St. Louis, MO (United States); Kumfer, Benjamin [Washington Univ., St. Louis, MO (United States); Gopan, Akshay [Washington Univ., St. Louis, MO (United States); Yang, Zhiwei [Washington Univ., St. Louis, MO (United States); Phillips, Jeff [Electric Power Research Inst. (EPRI), Palo Alto, CA (United States); Pint, Bruce [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

2017-12-29

The immediate need for a high efficiency, low cost carbon capture process has prompted the recent development of pressurized oxy-combustion. With a greater combustion pressure the dew point of the flue gas is increased, allowing for effective integration of the latent heat of flue gas moisture into the Rankine cycle. This increases the net plant efficiency and reduces costs. A novel, transformational process, named Staged, Pressurized Oxy-Combustion (SPOC), achieves additional step changes in efficiency and cost reduction by significantly reducing the recycle of flue gas. The research and development activities conducted under Phases I and II of this project (FE0009702) include: SPOC power plant cost and performance modeling, CFD-assisted design of pressurized SPOC boilers, theoretical analysis of radiant heat transfer and ash deposition, boiler materials corrosion testing, construction of a 100 kWth POC test facility, and experimental testing. The results of this project have advanced the technology readiness level (TRL) of the SPOC technology from 1 to 5.

Ash quality and environmental quality assurance system in co-combustion - Co-combustion of forest industry waste

International Nuclear Information System (INIS)

Laine-Ylijoki, J.; Wahlstroem, M.

2000-01-01

The environmental acceptability and possible utilization of co-combustion ashes will have a significant influence on the wider use of co-combustion in the future. At present the correlation between currently used fuels, their mixture ratios, and quality variations in ashes are not known, which complicates the assessment of possible utilization and environmental acceptability of co-combustion ashes. The composition of ashes has also been found to vary significantly. Effective utilization requires that process variations to alter ash composition and quality variations are known in advance. The aim of the research was to characterize the fly ash from co- combustion of peat, wood and biological paper mill sludge produced under different fuel loadings, especially with and without sludge addition, ant to identify critical parameters influencing on the ash composition. The variations in the leaching properties of ashes collected daily were followed up. The environmental acceptability of the ashes produced under different fuel loadings, especially their suitability for use in road constructions, were evaluated. The project included also the preparation of laboratory reference material from ash material. Guidelines were developed for sampling, sample preparation and analysis, and leaching tests. Furthermore, a quality control system, including sampling strategies, sample analysis and leaching testing, was established

Combustible structural composites and methods of forming combustible structural composites

Science.gov (United States)

Daniels, Michael A.; Heaps, Ronald J.; Steffler, Eric D.; Swank, W. David

2013-04-02

Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.

DEVELOPMENT OF A HAZARDOUS WASTE INCINERATOR TARGET ANALYTE LIST OF PRODUCTS OF INCOMPLETE COMBUSTION

Science.gov (United States)

The report gives results of pilot-scale incineration testing to develop a comprehensive list of products of incomplete combustion (PICs) from hazardous waste combustion (HWC) systems. Project goals were to: (1) identify the total mass of organic compounds sufficiently to estimate...

ERA-Net Evaluation of technology status for small-scale combustion of pellets from new ash rich biomasses - combustion tests in residential burners

Energy Technology Data Exchange (ETDEWEB)

Roennbaeck, Marie; Johansson, Mathias; Frida Claesson

2008-07-01

In this project, pellets with higher ash content compared to the wood pellets used today on the Swedish market were tested in three domestic-scale burners. The tests were carried out based on EN 303-5. In the flue gas, combustion parameters as carbon monoxide, carbon dioxide, oxygen and hydro carbons were measured, and also more fuel specific parameters such as nitrogen oxides, sulphur dioxide, hydrogen chloride, total dust and particle mass- and number concentration. The dust (fly ash) and bottom ash were characterized chemically. The implications of high ash content on combustion performance are discussed in the report. Altogether five pellets with 8 mm diameter were tested: oilseed straw pellet, reed canary grass pellet (RCG), barley straw pellet, bark pellet and wood pellet. All fuels were dry ranging from 6.5-12 % moisture. The ash content varied from 0.3 weight-% dm in wood to 7.9 % in RCG. Barley straw has a noticeable low ash melting temperature, < 980 deg C, and could not be combusted in any of the burners. The nitrogen content varied nine times and sulphur more than 10 times. The chlorine content was very low in wood and bark and more than 20 times higher in oilseed and barley. The composition of inorganic species in the fuel ash was dominated by calcium, potassium and silica in wood, bark and oilseed pellet, while RCG and barley straw were dominated by silica. The three burners used were commercial and known to fulfil high quality requirements. Burner A is a pellet burner where fuel is supplied on top of the grate with no mechanical mean for moving bottom ash on the grate during combustion. Bottom ash is blown away, and any slag remaining on the grate is removed with a scrape before ignition. Burner B is an upward burning pellet burner where fuel and ash is pushed upwards and the glow bed is exposed to the surrounding combustion department. Burner C is a forward burning grain burner that pushes fuel and ash forwards, inside a cylinder. From the

Gas Phase Sulfur, Chlorine and Potassium Chemistry in Biomass Combustion

DEFF Research Database (Denmark)

Løj, Lusi Hindiyarti

2007-01-01

Gas Phase Sulfur, Chlorine and Alkali Metal Chemistry in Biomass Combustion Concern about aerosols formation, deposits, corrosion, and gaseous emissions during biomass combustion, especially straw, continues to be a driving force for investigation on S, Cl, K-containing species under combustions...... conditions. These trace species contained in the biomass structure will be released to the gas phase during combustion and contribute to the problems generated during the process. The investigation during this PhD project is done to stepwise improve the understanding in the chemistry and reduce...... the uncertainties. In the present work, the detailed kinetic model for gas phase sulfur, chlorine, alkali metal, and their interaction has been updated. The K/O/H/Cl chemistry, S chemistry, and their interaction can reasonably predict a range of experimental data. In general, understanding of the interaction...

Combustion of cork waste in a circulating fluidized bed combustor

Energy Technology Data Exchange (ETDEWEB)

Gulyurtlu, I.; Boavida, D.; Miranda, M.; Cabrita, I. [Dept. de Tecnologias de Combustao, ITE-INETI, Lisboa (Portugal); Abelha, P. [Coaltec e Ambiente, Lisboa (Portugal)

1999-07-01

There is currently an ongoing joint project between Portugal and Spain, which is being funded by the FAIR programme. The principal objective of the FAIR project is to investigate the application of the fluidised bed combustion (FBC) technology to burn cork wastes with the aim of overcoming the difficulties currently experienced in the cork processing industries. The combustion studies at INETI were carried out using the 300 kW{sub th} circulating fluidised bed facility. The combustor is square in cross section with each side being 0.3 m long. The combustor height is 5 m. The temperatures in the bed, the riser and that of the flue gases leaving the reactor were continuously monitored. The combustion gases leaving the reactor passed through the recycling cyclone first to capture most of particulates elutriated out of the combustor. The solid particles were intermittently collected for analysis to determine the amount of carbon present, which helped the combustion efficiency to be calculated. Instantaneous measurements of O{sub 2}, CO, CO{sub 2}, NO{sub x}, N{sub 2}O and SO{sub 2} present levels in the flue gases were also carried out. The combustion tests were done with both the cork waste dust and granular virgin cork. The difference is that cork dust gets contaminated during the process due to the use of various additives. Most of the combustion took place in the riser where the temperature was at times up to 523 K above that of the bed. The unburned carbon level was low ranging from about 1.5 to 2.% suggesting that most of the particles burned to completion in the riser. (orig.)

Combustion Stratification for Naphtha from CI Combustion to PPC

KAUST Repository

Vallinayagam, R.

2017-03-28

This study demonstrates the combustion stratification from conventional compression ignition (CI) combustion to partially premixed combustion (PPC). Experiments are performed in an optical CI engine at a speed of 1200 rpm for diesel and naphtha (RON = 46). The motored pressure at TDC is maintained at 35 bar and fuelMEP is kept constant at 5.1 bar to account for the difference in fuel properties between naphtha and diesel. Single injection strategy is employed and the fuel is injected at a pressure of 800 bar. Photron FASTCAM SA4 that captures in-cylinder combustion at the rate of 10000 frames per second is employed. The captured high speed video is processed to study the combustion homogeneity based on an algorithm reported in previous studies. Starting from late fuel injection timings, combustion stratification is investigated by advancing the fuel injection timings. For late start of injection (SOI), a direct link between SOI and combustion phasing is noticed. At early SOI, combustion phasing depends on both intake air temperature and SOI. In order to match the combustion phasing (CA50) of diesel, the intake air temperature is increased to 90°C for naphtha. The combustion stratification from CI to PPC is also investigated for various level of dilution by displacing oxygen with nitrogen in the intake. The start of combustion (SOC) was delayed with the increase in dilution and to compensate for this, the intake air temperature is increased. The mixture homogeneity is enhanced for higher dilution due to longer ignition delay. The results show that high speed image is initially blue and then turned yellow, indicating soot formation and oxidation. The luminosity of combustion images decreases with early SOI and increased dilution. The images are processed to generate the level of stratification based on the image intensity. The level of stratification is same for diesel and naphtha at various SOI. When O concentration in the intake is decreased to 17.7% and 14

Oxy-Combustion Burner and Integrated Pollutant Removal Research and Development Test Facility

Energy Technology Data Exchange (ETDEWEB)

Mark Schoenfield; Manny Menendez; Thomas Ochs; Rigel Woodside; Danylo Oryshchyn

2012-09-30

A high flame temperature oxy-combustion test facility consisting of a 5 MWe equivalent test boiler facility and 20 KWe equivalent IPR® was constructed at the Hammond, Indiana manufacturing site. The test facility was operated natural gas and coal fuels and parametric studies were performed to determine the optimal performance conditions and generated the necessary technical data required to demonstrate the technologies are viable for technical and economic scale-up. Flame temperatures between 4930-6120F were achieved with high flame temperature oxy-natural gas combustion depending on whether additional recirculated flue gases are added to balance the heat transfer. For high flame temperature oxy-coal combustion, flame temperatures in excess of 4500F were achieved and demonstrated to be consistent with computational fluid dynamic modeling of the burner system. The project demonstrated feasibility and effectiveness of the Jupiter Oxygen high flame temperature oxy-combustion process with Integrated Pollutant Removal process for CCS and CCUS. With these technologies total parasitic power requirements for both oxygen production and carbon capture currently are in the range of 20% of the gross power output. The Jupiter Oxygen high flame temperature oxy-combustion process has been demonstrated at a Technology Readiness Level of 6 and is ready for commencement of a demonstration project.

NOx Emission Reduction by Oscillating Combustion

Energy Technology Data Exchange (ETDEWEB)

None

2005-09-01

This project focuses on a new technology that reduces NOx emissions while increasing furnace efficiency for both air- and oxygen-fired furnaces. Oscillating combustion is a retrofit technology that involves the forced oscillation of the fuel flow rate to a furnace. These oscillations create successive, fuel-rich and fuel-lean zones within the furnace.

Advanced Combustion Numerics and Modeling - FY18 First Quarter Report

Energy Technology Data Exchange (ETDEWEB)

Whitesides, R. A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Killingsworth, N. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); McNenly, M. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Petitpas, G. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

2018-01-05

This project is focused on early stage research and development of numerical methods and models to improve advanced engine combustion concepts and systems. The current focus is on development of new mathematics and algorithms to reduce the time to solution for advanced combustion engine design using detailed fuel chemistry. The research is prioritized towards the most time-consuming workflow bottlenecks (computer and human) and accuracy gaps that slow ACS program members. Zero-RK, the fast and accurate chemical kinetics solver software developed in this project, is central to the research efforts and continues to be developed to address the current and emerging needs of the engine designers, engine modelers and fuel mechanism developers.

Hydrogen-Assisted IC Engine Combustion as a Route to Hydrogen Implementation

Energy Technology Data Exchange (ETDEWEB)

Andre Boehman; Daniel Haworth

2008-09-30

The 'Freedom Car' Initiative announced by the Bush Administration has placed a significant emphasis on development of a hydrogen economy in the United States. While the hydrogen-fueled fuel-cell vehicle that is the focus of the 'Freedom Car' program would rely on electrochemical energy conversion, and despite the large amount of resources being devoted to its objectives, near-term implementation of hydrogen in the transportation sector is not likely to arise from fuel cell cars. Instead, fuel blending and ''hydrogen-assisted'' combustion are more realizable pathways for wide-scale hydrogen utilization within the next ten years. Thus, a large potential avenue for utilization of hydrogen in transportation applications is through blending with natural gas, since there is an existing market for natural-gas vehicles of various classes, and since hydrogen can provide a means of achieving even stricter emissions standards. Another potential avenue is through use of hydrogen to 'assist' diesel combustion to permit alternate combustion strategies that can achieve lower emissions and higher efficiency. This project focused on developing the underlying fundamental information to support technologies that will facilitate the introduction of coal-derived hydrogen into the market. Two paths were envisioned for hydrogen utilization in transportation applications. One is for hydrogen to be mixed with other fuels, specifically natural gas, to enhance performance in existing natural gas-fueled vehicles (e.g., transit buses) and provide a practical and marketable avenue to begin using hydrogen in the field. A second is to use hydrogen to enable alternative combustion modes in existing diesel engines, such as homogeneous charge compression ignition, to permit enhanced efficiency and reduced emissions. Thus, this project on hydrogen-assisted combustion encompassed two major objectives: (1) Optimization of hydrogen-natural gas mixture

IEA combustion agreement : a collaborative task on alternative fuels in combustion

International Nuclear Information System (INIS)

Larmi, M.

2009-01-01

The focus of the alternative fuels in combustion task of the International Energy Agency is on high efficiency engine combustion, furnace combustion, and combustion chemistry. The objectives of the task are to develop optimum combustion for dedicated fuels by fully utilizing the physical and chemical properties of synthetic and renewable fuels; a significant reduction in carbon dioxide, NOx and particulate matter emissions; determine the minimum emission levels for dedicated fuels; and meet future emission standards of engines without or with minimum after-treatment. This presentation discussed the alternative fuels task and addressed issues such as synthetic fuel properties and benefits. The anticipated future roadmap was presented along with a list of the synthetic and renewable engine fuels to be studied, such as neat oxygenates like alcohols and ethers, biogas/methane and gas combustion, fuel blends, dual fuel combustion, high cetane number diesel fuels like synthetic Fischer-Tropsch diesel fuel and hydrogenated vegetable oil, and low CN number fuels. Implementation examples were also discussed, such as fuel spray studies in optical spray bombs; combustion research in optical engines and combustion chambers; studies on reaction kinetics of combustion and emission formation; studies on fuel properties and ignition behaviour; combustion studies on research engines; combustion optimization; implementing the optimum combustion in research engines; and emission measurements. Overall milestone examples and the overall schedule of participating countries were also presented. figs.

WMU Power Generation Study Task 2.0 Corn Cob Co-Combustion Study: Final Report

Energy Technology Data Exchange (ETDEWEB)

Folkedahl, Bruce [Folkedahl Consulting, Inc., Willmar, MN (United States)

2009-12-01

Much attention has been focused on renewable energy use in large-scale utilities and very small scale distributed energy systems. However, there is little information available regarding renewable energy options for midscale municipal utilities. The Willmar Municipal Utilities Corn Cob-Coal Co-Combustion Project was initiated to investigate opportunities available for small to midscale municipal utilities to "go green". The overall goal of the Project was to understand the current renewable energy research and energy efficiency projects that are or have been implemented at both larger and smaller scale and determine the applicability to midscale municipal utilities. More specific objectives for Task 2.0 of this project were to determine the technical feasibility of co-combusting com cobs with coal in the existing WMU boiler, and to identify any regulatory issues that might need to be addressed if WMU were to obtain a significant portion of its heat from such co-combustion. This report addresses the issues as laid out in the study proposal. The study investigated the feasibility of and demonstrated the technical effectiveness of co-combusting corn cobs with coal in the Willmar Municipal Utilities stoker boiler steam generation power plant. The results of the WMU Co-Combustion Project will serve as a model for other midscale utilities who wish to use corn cobs to generate renewable electrical energy. As a result of the Co-Combustion Project, the WMU plans to upgrade their stoker boiler to accept whole corn cobs as well as other types of biomass, while still allowing the fuel delivery system to use 100% coal as needed. Benefits of co-combustion will include: energy security, reduced Hg and CO₂ air emissions, improved ash chemistry, potential future carbon credit sales, an immediate positive effect on the local economy, and positive attention focused on the WMU and the City of Willmar. The first step in the study was to complete a feasibility analysis. The

Internal combustion engine using premixed combustion of stratified charges

Science.gov (United States)

Marriott, Craig D [Rochester Hills, MI; Reitz, Rolf D [Madison, WI

2003-12-30

During a combustion cycle, a first stoichiometrically lean fuel charge is injected well prior to top dead center, preferably during the intake stroke. This first fuel charge is substantially mixed with the combustion chamber air during subsequent motion of the piston towards top dead center. A subsequent fuel charge is then injected prior to top dead center to create a stratified, locally richer mixture (but still leaner than stoichiometric) within the combustion chamber. The locally rich region within the combustion chamber has sufficient fuel density to autoignite, and its self-ignition serves to activate ignition for the lean mixture existing within the remainder of the combustion chamber. Because the mixture within the combustion chamber is overall premixed and relatively lean, NO.sub.x and soot production are significantly diminished.

FY 2007 Progress Report for Advanced Combustion Engine Technologies

Energy Technology Data Exchange (ETDEWEB)

None, None

2007-12-01

Advanced combustion engines have great potential for achieving dramatic energy efficiency improvements in light-duty vehicle applications, where it is suited to both conventional and hybrid- electric powertrain configurations. Light-duty vehicles with advanced combustion engines can compete directly with gasoline engine hybrid vehicles in terms of fuel economy and consumer-friendly driving characteristics; also, they are projected to have energy efficiencies that are competitive with hydrogen fuel cell vehicles when used in hybrid applications.Advanced engine technologies being researched and developed by the Advanced Combustion Engine R&D Sub-Program will also allow the use of hydrogen as a fuel in ICEs and will provide an energy-efficient interim hydrogen-based powertrain technology during the transition to hydrogen/fuelcell-powered transportation vehicles.

Combustion Stratification for Naphtha from CI Combustion to PPC

KAUST Repository

Vallinayagam, R.; Vedharaj, S.; An, Yanzhao; Dawood, Alaaeldin; Izadi Najafabadi, Mohammad; Somers, Bart; Johansson, Bengt

2017-01-01

This study demonstrates the combustion stratification from conventional compression ignition (CI) combustion to partially premixed combustion (PPC). Experiments are performed in an optical CI engine at a speed of 1200 rpm for diesel and naphtha (RON

Fuel and combustion stratification study of Partially Premixed Combustion

OpenAIRE

Izadi Najafabadi, M.; Dam, N.; Somers, B.; Johansson, B.

2016-01-01

Relatively high levels of stratification is one of the main advantages of Partially Premixed Combustion (PPC) over the Homogeneous Charge Compression Ignition (HCCI) concept. Fuel stratification smoothens heat release and improves controllability of this kind of combustion. However, the lack of a clear definition of “fuel and combustion stratifications” is obvious in literature. Hence, it is difficult to compare stratification levels of different PPC strategies or other combustion concepts. T...

Development of flameless combustion; Desarrollo de la combustion sin flama

Energy Technology Data Exchange (ETDEWEB)

Flores Sauceda, M. Leonardo; Cervantes de Gortari, Jaime Gonzalo [Universidad Nacional Autonoma de Mexico, Mexico, D.F. (Mexico)]. E-mail: 8344afc@prodigy.net.mx; jgonzalo@servidor.unam.mx

2010-11-15

The paper intends contribute to global warming mitigation joint effort that develops technologies to capture the CO{sub 2} produced by fossil fuels combustion and to reduce emission of other greenhouse gases like the NO{sub x}. After reviewing existing combustion bibliography is pointed out that (a) touches only partial aspects of the collective system composed by Combustion-Heat transfer process-Environment, whose interactions are our primary interest and (b) most specialists think there is not yet a clearly winning technology for CO{sub 2} capture and storage. In this paper the study of combustion is focused as integrated in the aforementioned collective system where application of flameless combustion, using oxidant preheated in heat regenerators and fluent gas recirculation into combustion chamber plus appropriated heat and mass balances, simultaneously results in energy saving and environmental impact reduction. [Spanish] El trabajo pretende contribuir al esfuerzo conjunto de mitigacion del calentamiento global que aporta tecnologias para capturar el CO{sub 2} producido por la combustion de combustibles fosiles y para disminuir la emision de otros gases invernadero como NOx. De revision bibliografica sobre combustion se concluye que (a) trata aspectos parciales del sistema compuesto por combustion-proceso de trasferencia de calor-ambiente, cuyas interacciones son nuestro principal interes (b) la mayoria de especialistas considera no hay todavia una tecnologia claramente superior a las demas para captura y almacenaje de CO{sub 2}. Se estudia la combustion como parte integrante del mencionado sistema conjunto, donde la aplicacion de combustion sin flama, empleando oxidante precalentado mediante regeneradores de calor y recirculacion de gases efluentes ademas de los balances de masa y energia adecuados, permite tener simultaneamente ahorros energeticos e impacto ambiental reducido.

Internal combustion engine report: Spark ignited ICE GenSet optimization and novel concept development

Energy Technology Data Exchange (ETDEWEB)

Keller, J.; Blarigan, P. Van [Sandia National Labs., Livermore, CA (United States)

1998-08-01

In this manuscript the authors report on two projects each of which the goal is to produce cost effective hydrogen utilization technologies. These projects are: (1) the development of an electrical generation system using a conventional four-stroke spark-ignited internal combustion engine generator combination (SI-GenSet) optimized for maximum efficiency and minimum emissions, and (2) the development of a novel internal combustion engine concept. The SI-GenSet will be optimized to run on either hydrogen or hydrogen-blends. The novel concept seeks to develop an engine that optimizes the Otto cycle in a free piston configuration while minimizing all emissions. To this end the authors are developing a rapid combustion homogeneous charge compression ignition (HCCI) engine using a linear alternator for both power take-off and engine control. Targeted applications include stationary electrical power generation, stationary shaft power generation, hybrid vehicles, and nearly any other application now being accomplished with internal combustion engines.

Understanding Combustion and Soot Formation in Diesel Engines

Science.gov (United States)

2016-09-09

distributions of PLII signals help understand the soot distributions within diesel/ biodiesel flames. In addition, planar laser-induced Figure 1. Transported ...Prescribed by ANSI Std. Z39.18 Page 1 of 1FORM SF 298 9/14/2016https://livelink.ebs.afrl.af.mil/livelink/llisapi.dll This project investigated biodiesel ...emissions testing. 1 FINAL REPORT Project title: Understanding combustion and soot formation in biodiesel fuelled diesel engines Lead Institute and

Decommissioning Combustible Waste Treatment using Oxygen-Enriched Incinerator

Energy Technology Data Exchange (ETDEWEB)

Min, Byungyoun; Lee, Yoonji; Yun, Gyoungsu; Lee, Kiwon; Moon, Jeikwon [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

2014-05-15

The aim of the paper is current status of treatment for the decommissioning combustible waste in KAERI and for the purpose of the volume reduction and clearance for decommissioning combustible wastes generated by the decommissioning projects. The incineration technology has been selected for the treatment of combustible wastes. About 34 tons of decommissioning combustible waste has been treated using Oxygen Enriched incineration. Temperature, pressure of major components, stack gas concentration, i. e., SOx, NOx, CO, CO{sub 2} and HCl, and the residual oxygen were measured. Measured major parameters during normal operation were sustained on a stable status within a criteria operation condition. Oxygen enriched air, 22vol. % (dry basis) was used for stable incineration. The volume reduction ratio has achieved about 1/117. The incineration with decommissioning radioactive combustible waste is possible with moderate oxygen enrichment of 22 vol.% (dry basis) into the supply air. The incineration facility operated quite smoothly through the analysis major critical parameters of off-gas. The pressure, off-gas flow and temperature of major components remained constant within the range specified. The measures gases and particulate materials in stack were considerably below the regulatory limits. The achieved volume reduction ratio through incineration is about 1/117.

Release and sorption of alkali metals in coal fired combined cycle power systems; Freisetzung und Einbindung von Alkalimetallverbindungen in kohlebefeuerten Kombikraftwerken

Energy Technology Data Exchange (ETDEWEB)

Mueller, Michael

2009-07-01

Coal fired combined cycle power systems will be a sufficient way to increase the efficiency of coal combustion. However, combined cycle power systems require a reliable hot gas cleanup. Especially alkali metals, such as sodium and potassium, can lead to hot corrosion of the gas turbine blading if they condensate as sulphates. The actual work deals with the release and sorption of alkali metals in coal fired combined cycle power systems. The influence of coal composition, temperature and pressure on the release of alkali species in coal combustion was investigated and the relevant release mechanisms identified. Alumosilicate sorbents have been found that reduce the alkali concentration in the hot flue gas of the Circulating Pressurized Fluidized Bed Combustion 2{sup nd} Generation (CPFBC 2{sup nd} Gen.) at 750 C to values sufficient for use in a gas turbine. Accordingly, alumosilicate sorbents working at 1400 C have been found for the Pressurized Pulverized Coal Combustion (PPCC). The sorption mechanisms have been identified. Thermodynamic calculations were performed to upscale the results of the laboratory experiments to conditions prevailing in power systems. According to these calculations, there is no risk of hot corrosion in both processes. Furthermore, thermodynamic calculations were performed to investigate the behaviour of alkali metals in an IGCC with integrated hot gas cleanup and H{sub 2} membrane for CO{sub 2} sequestration. (orig.)

Measures for a quality combustion (combustion chamber exit and downstream); Mesures pour une combustion de qualite (sortie de chambre de combustion et en aval)

Energy Technology Data Exchange (ETDEWEB)

Epinat, G. [APAVE Lyonnaise, 69 (France)

1996-12-31

After a review of the different pollutants related to the various types of stationary and mobile combustion processes (stoichiometric, reducing and oxidizing combustion), measures and analyses than may be used to ensure the quality and efficiency of combustion processes are reviewed: opacimeters, UV analyzers, etc. The regulation and control equipment for combustion systems are then listed, according to the generator capacity level

Trace emissions from gaseous combustion

Energy Technology Data Exchange (ETDEWEB)

Seebold, J.G. [Chevron Research and Technology Co., Richmond, CA (United States)

2000-07-01

The U.S. Clean Air Act (CAA) was amended in 1990 to include the development of maximum achievable control technology (MACT) emission standards for hazardous air pollutants (HAPs) for certain stationary sources by November 2000. MACT emissions standards would affect process heaters and industrial boilers since combustion processes are a potential source for many air toxins. The author noted that one of the problems with MACT is the lack of a clear solid scientific footing which is needed to develop environmentally responsible regulations. In order to amend some of these deficiencies, a 4-year, $7 million research project on the origin and fate of trace emissions in the external combustion of gaseous hydrocarbons was undertaken in a collaborative effort between government, universities and industry. This collaborative project entitled the Petroleum Environmental Research Forum (PERF) Project 92-19 produced basic information and phenomenological understanding in two important areas, one basic and one applied. The specific objectives of the project were to measure emissions while operating different full-scale burners under various operating conditions and then to analyze the emission data to identify which operating conditions lead to low air toxic emissions. Another objective was to develop new chemical kinetic mechanisms and predictive models for the formation of air toxic species which would explain the origin and fate of these species in process heaters and industrial boilers. It was determined that a flame is a very effective reactor and that trace emissions from a typical gas-fired industry burner are very small. An unexpected finding was that trace emissions are not affected by hydrocarbon gaseous fuel composition, nor by the use of ultra low nitrous oxide burners. 2 refs., 8 figs.

Plasma assisted measurements of alkali metal concentrations in pressurised combustion processes

Energy Technology Data Exchange (ETDEWEB)

Hernberg, R; Haeyrinen, V [Tampere Univ. of Technology (Finland)

1997-10-01

In this project the continuous alkali measurement method plasma excited alkali resonance line spectroscopy (PEARLS) was developed, tested and demonstrated in pressurised combustion facilities. The PEARLS method has been developed at Tampere University of Technology (TUT). During 1994-1996 the PEARLS method was developed from the laboratory level to an industrial prototype. The alkali measuring instrument has been tested and used for regular measurements in four different pressurised combustion installations ranging up to industrial pilot scale. The installations are: (1) a pressurised entrained flow reactor (PEFR) at VTT Energy in Jyvaeskylae, Finland (2) a pressurised fluidised bed combustion facility, called FRED, at DMT in Essen, Germany. (3) a 10 MW pressurised circulating fluidised bed combustion pilot plant at Foster Wheeler Energia Oy in Karhula, Finland (4) PFBC Research Facility at ABB Carbon in Finspaang, Sweden

Future combustion technology for synthetic and renewable fuels in compression ignition engines (REFUEL). Final report

Energy Technology Data Exchange (ETDEWEB)

Aakko-Saksa, P.; Brink, A.; Happonen, M. [and others

2012-07-01

This domestic project, Future Combustion Technology for Synthetic and Renewable Fuels in Compression Ignition Engines (ReFuel), was part of a Collaborative Task 'Future Combustion Technology for Synthetic and Renewable Fuels in Transport' of International Energy Agency (IEA) Combustion Agreement. This international Collaborative Task is coordinated by Finland. The three-year (2009-2011) prooject was a joint research project with Aalto University (Aalto), Tampere University of Technology (TUT), Technical Research Centre of Finland (VTT) and Aabo Akademi University (AAU). The project was funded by TEKES, Waertsilae Oyj, Agro Sisu Power, Aker Arctic Technology Oy and the research partners listed above. Modern renewable diesel fuels have excellent physical and chemical properties, in comparison to traditional crude oil based fuels. Purely paraffinic fuels do not contain aromatic compounds and they are totally sulphur free. Hydrotreated Vegetable Oil (HVO) was studied as an example of paraffinic high cetane number (CN) diesel fuels. HVO has no storage and low temperature problems like the fatty acid methyl esters (FAMEs) have. The combustion properties are better than those of crude oil based fuels and FAME, because they have very high cetane numbers and contain no polyaromatic hydrocarbons (PAH). With low HVO density, viscosity and distillation temperatures, these advantageous properties allow far more advanced combustion strategies, such as very high exhaust gas recirculation (EGR) rates or extreme Miller timings, than has been possible with current fossil fuels. The implementation of these advanced combustion technologies, together with the novel renewable diesel fuel, brought significant nitrogen oxides (NO{sub x}), particulate matter (PM) emission reductions with no efficiency losses. (orig.)

Advanced radiant combustion system. Final report, September 1989--September 1996

Energy Technology Data Exchange (ETDEWEB)

Sullivan, J.D.; Carswell, M.G.; Long, F.S.

1996-09-01

Results of the Advanced Radiant Combustion System (ARCS) project are presented in this report. This work was performed by Alzeta Corporation as prime contractor under a contract to the U.S. Department of Energy Office of Industrial Technologies as part of a larger DOE program entitled Research Program for Advanced Combustion Systems. The goals of the Alzeta ARCS project were to (a) Improve the high temperature performance characteristics of porous surface ceramic fiber burners, (b) Develop an Advanced Radiant Combustion System (ARCS) that combines combustion controls with an advanced radiant burner, and (c) Demonstrate the advanced burner and controls in an industrial application. Prior to the start of this project, Alzeta had developed and commercialized a porous surface radiant burner, the Pyrocore{trademark} burner. The product had been commercially available for approximately 5 years and had achieved commercial success in a number of applications ranging from small burners for commercial cooking equipment to large burners for low temperature industrial fluid heating applications. The burner was not recommended for use in applications with process temperatures above 1000{degrees}F, which prevented the burner from being used in intermediate to high temperature processes in the chemical and petroleum refining industries. The interest in increasing the maximum use temperature of the burner was motivated in part by a desire to expand the number of applications that could use the Pyrocore product, but also because many of the fluid sensitive heating applications of interest would benefit from the distributed flux characteristic of porous surface burners. Background information on porous surface radiant burners, and a discussion of advantages that would be provided by an improved product, are presented in Section 2.

Achievement report on research and development in the Sunshine Project in fiscal 1976. Research related to hydrogen combustion technologies; 1976 nendo suiso nensho gijutsu ni kansuru kenkyu seika hokokusho

Energy Technology Data Exchange (ETDEWEB)

NONE

1977-03-01

Regarding the Sunshine Project, this paper describes characteristics and technologies of hydrogen combustion, problems in developing combustion devices and conceptual design thereof, catalytic combustion, hydrogen energy systems, and economic evaluation on hydrogen fuel as a heating energy. Hydrogen combustion could emit small amount of NOx if it is sufficiently pre-mixed with air, but at the same time could cause reverse ignition very easily making its practical use difficult. Abolishing the air pre-mixture would cause no fear of reverse ignition, but generate much more NOx than from hydrocarbon fuels. Even if attempting to apply conventional methods such as two-stage combustion, partial stack gas recirculation, water addition, and lean burn systems, many of them cannot be applied as they are, requiring research and development efforts. Discussions on hydrogen energy as a system included those on thermo-chemical hydrogen manufacturing using heat from high temperature gas reactors (using water as the raw material), and electrolytic hydrogen gas manufacturing utilizing surplus electric power from high speed breeder reactors. Whether these methods could be used in markets economically will depend on manufacturing efficiency and cost of hydrogen gas. As the economic evaluation on hydrogen as fuel, discussions and considerations were given on introduction priority in the industrial heating furnace field. (NEDO)

Combustion stratification for naphtha from CI combustion to PPC

NARCIS (Netherlands)

Vallinayagam, R.; Vedharaj, S.; An, Y.; Dawood, A.; Izadi Najafabadi, M.; Somers, L.M.T.; Johansson, B.H.

2017-01-01

This study demonstrated the change in combustion homogeneity from conventional diesel combustion via partially premixed combustion towards HCCI. Experiments are performed in an optical diesel engine at a speed of 1200 rpm with diesel fuel. Single injection strategy is employed and the fuel is

Low NOx combustion technologies for high-temperature natural gas combustion

International Nuclear Information System (INIS)

Flamme, Michael

1999-01-01

Because of the high process temperature which is required for some processes like glass melting and the high temperature to which the combustion air is preheated, NOx emission are extremely high. Even at these high temperatures, NOx emissions could be reduced drastically by using advanced combustion techniques such as staged combustion or flame-less oxidation, as experimental work has shown. In the case of oxy-fuel combustion, the NOx emission are also very high if conventional burners are used. The new combustion techniques achieve similar NOx reductions. (author)

Development of Cost Effective Oxy-Combustion Retrofitting for Coal-Fired Boilers

Energy Technology Data Exchange (ETDEWEB)

Hamid Farzan

2010-12-31

The overall objective of this project is to further develop the oxy-combustion technology for commercial retrofit in existing wall-fired and Cyclone boilers by 2012. To meet this goal, a research project was conducted that included pilot-scale testing and a full-scale engineering and economic analysis.

Combustion instability control in the model of combustion chamber

International Nuclear Information System (INIS)

Akhmadullin, A N; Ahmethanov, E N; Iovleva, O V; Mitrofanov, G A

2013-01-01

An experimental study of the influence of external periodic perturbations on the instability of the combustion chamber in a pulsating combustion. As an external periodic disturbances were used sound waves emitted by the electrodynamics. The purpose of the study was to determine the possibility of using the method of external periodic perturbation to control the combustion instability. The study was conducted on a specially created model of the combustion chamber with a swirl burner in the frequency range from 100 to 1400 Hz. The study found that the method of external periodic perturbations may be used to control combustion instability. Depending on the frequency of the external periodic perturbation is observed as an increase and decrease in the amplitude of the oscillations in the combustion chamber. These effects are due to the mechanisms of synchronous and asynchronous action. External periodic disturbance generated in the path feeding the gaseous fuel, showing the high efficiency of the method of management in terms of energy costs. Power required to initiate periodic disturbances (50 W) is significantly smaller than the thermal capacity of the combustion chamber (100 kW)

Air-steam hybrid engine : an alternative to internal combustion.

Science.gov (United States)

2011-03-01

In this Small Business Innovation Research (SBIR) Phase 1 project, an energy-efficient air-steam propulsion system has been developed and patented, and key performance attributes have been demonstrated to be superior to those of internal combustion e...

Effect of Non-Stationary Combustion Phases on Emission Factors of Selected Pollutants and PCDD/F from Domestic Combustion

Czech Academy of Sciences Publication Activity Database

Šyc, Michal; Horák, J.; Krpec, K.; Hopan, F.; Ocelka, T.; Stáňa, M.

LVI, č. 2 (2010), s. 183-187 ISSN 1210-0471 R&D Projects: GA MŽP(CZ) SP/1A2/116/07; GA MŠk 2B08048 Institutional research plan: CEZ:AV0Z40720504 Keywords : combustion * emission factors * pollutants Subject RIV: CI - Industrial Chemistry, Chemical Engineering http://transactions.fs.vsb.cz/2010-2/1798.pdf

Rotary combustion device

NARCIS (Netherlands)

2008-01-01

Rotary combustion device (1) with rotary combustion chamber (4). Specific measures are taken to provide ignition of a combustible mixture. It is proposed that a hollow tube be provided coaxially with the axis of rotation (6), so that a small part of the mixture is guided into the combustion chamber.

Controls and measurements of KU engine test cells for biodiesel, SynGas, and assisted biodiesel combustion

Science.gov (United States)

Cecrle, Eric Daniel

This thesis is comprised of three unique data acquisition and controls (CDAQ) projects. Each of these projects differs from each other; however, they all include the concept of testing renewable or future fuel sources. The projects were the following: University of Kansas's Feedstock-to-Tailpipe Initiative's Synthesis Gas Reforming rig, Feedstock-to-Tailpipe Initiative's Biodiesel Single Cylinder Test Stand, and a unique Reformate Assisted Biodiesel Combustion architecture. The main responsibility of the author was to implement, develop and test CDAQ systems for the projects. For the Synthesis Gas Reforming rig, this thesis includes a report that summarizes the analysis and solution of building a controls and data acquisition system for this setup. It describes the purpose of the sensors selected along with their placement throughout the system. Moreover, it includes an explanation of the planned data collection system, along with two models describing the reforming process useful for system control. For the Biodiesel Single Cylinder Test Stand, the responsibility was to implement the CDAQ system for data collection. This project comprised a variety of different sensors that are being used collect the combustion characteristics of different biodiesel formulations. This project is currently being used by other graduates in order to complete their projects for subsequent publication. For the Reformate Assisted Biodiesel Combustion architecture, the author developed a reformate injection system to test different hydrogen and carbon monoxide mixtures as combustion augmentation. Hydrogen combustion has certain limiting factors, such as pre-ignition in spark ignition engines and inability to work as a singular fuel in compression ignition engines. To offset these issues, a dual-fuel methodology is utilized by injecting a hydrogen/carbon monoxide mixture into the intake stream of a diesel engine operating on biodiesel. While carbon monoxide does degrade some of the

Experimental investigation of H2 combustion in the Sandia VGES Intermediate-scale burn tank

International Nuclear Information System (INIS)

Benedick, W.B.; Berman, M.; Cummings, J.C.; Prassinos, P.G.

1983-01-01

Sandia National Laboratories is presently involved in several NRC-sponsored experimental projects to provide data that will help quantify the threat of hydrogen combustion during LWR accidents. One project, which employs several experimental facilities is the Variable Geometry Experimental System (VGES). The purpose of this paper is to present the experimental results from one of these facilities; the intermediate-scale burn tank ( about5m 3 ). The data provided by this facility can be used in the development and assessment of analytical models used to predict hydrogen combustion behavior

Fluidised bed combustion system

International Nuclear Information System (INIS)

McKenzie, E.C.

1976-01-01

Fluidized bed combustion systems that facilitates the maintenance of the depth of the bed are described. A discharge pipe projects upwardly into the bed so that bed material can flow into its upper end and escape downwardly. The end of the pipe is surrounded by an enclosure and air is discharged into the enclosure so that material will enter the pipe from within the enclosure and have been cooled in the enclosure by the air discharged into it. The walls of the enclosure may themselves be cooled

Combustion physics

Science.gov (United States)

Jones, A. R.

1985-11-01

Over 90% of our energy comes from combustion. By the year 2000 the figure will still be 80%, even allowing for nuclear and alternative energy sources. There are many familiar examples of combustion use, both domestic and industrial. These range from the Bunsen burner to large flares, from small combustion chambers, such as those in car engines, to industrial furnaces for steel manufacture or the generation of megawatts of electricity. There are also fires and explosions. The bountiful energy release from combustion, however, brings its problems, prominent among which are diminishing fuel resources and pollution. Combustion science is directed towards finding ways of improving efficiency and reducing pollution. One may ask, since combustion is a chemical reaction, why physics is involved: the answer is in three parts. First, chemicals cannot react unless they come together. In most flames the fuel and air are initially separate. The chemical reaction in the gas phase is very fast compared with the rate of mixing. Thus, once the fuel and air are mixed the reaction can be considered to occur instantaneously and fluid mechanics limits the rate of burning. Secondly, thermodynamics and heat transfer determine the thermal properties of the combustion products. Heat transfer also plays a role by preheating the reactants and is essential to extracting useful work. Fluid mechanics is relevant if work is to be performed directly, as in a turbine. Finally, physical methods, including electric probes, acoustics, optics, spectroscopy and pyrometry, are used to examine flames. The article is concerned mainly with how physics is used to improve the efficiency of combustion.

Numerical investigation of a straw combustion boiler – Part I: Modelling of the thermo-chemical conversion of straw

Directory of Open Access Journals (Sweden)

Dernbecher Andrea

2016-01-01

Full Text Available In the framework of a European project, a straw combustion boiler in conjunction with an organic Rankine cycle is developed. One objective of the project is the enhancement of the combustion chamber by numerical methods. A comprehensive simulation of the combustion chamber is prepared, which contains the necessary submodels for the thermo-chemical conversion of straw and for the homogeneous gas phase reactions. Part I introduces the modelling approach for the thermal decomposition of the biomass inside the fuel bed, whereas part II deals with the simulation of the gas phase reactions in the freeboard.

Combustion of solid alternative fuels in the cement kiln burner

DEFF Research Database (Denmark)

Nørskov, Linda Kaare

In the cement industry there is an increasing environmental and financial motivation for substituting conventional fossil fuels with alternative fuels, being biomass or waste derived fuels. However, the introduction of alternative fuels may influence emissions, cement product quality, process...... stability, and process efficiency. Alternative fuel substitution in the calciner unit has reached close to 100% at many cement plants and to further increase the use of alternative fuels rotary kiln substitution must be enhanced. At present, limited systematic knowledge of the alternative fuel combustion...... properties and the influence on the flame formation is available. In this project a scientific approach to increase the fundamental understanding of alternative fuel conversion in the rotary kiln burner is employed through literature studies, experimental combustion characterisation studies, combustion...

Catalytic combustion for the elimination of methane, BTEX and other VOC : IV

International Nuclear Information System (INIS)

Hayes, R.E.; Wanke, S.E.

2008-01-01

Options for volatile organic compound combustion include homogeneous combustion (flaring) or catalytic combustion involving a flameless combustion process that uses a solid catalyst to promote the combustion reaction. This presentation discussed relative reactivity testing for volatile organic compounds (VOCs) over commercial catalysts. Several commercial pad catalysts were tested, as well as other powders. The relative reactivity of methane as well as benzene, toluene, ethylbenzene, and xylene (BTEX) were investigated. The purpose of the project was to evaluate combustion of concentrated methane streams that contained BTEX compounds; evaluate catalytic combustion using a counter diffusive radiant heater; develop mathematical models for the reactor to enhance design and understanding; improve the catalyst for BTEX combustion; and target application-dehydrator units. Topics that were addressed in the presentation included methane and benzene conversion; catalytic radiant heaters; small industrial and commercial units; measured temperature distribution; fuel slippage, methane conversion; the effect of water and hydrocarbons; the effect of water-liquid injection; and water addition as vapour. Several observations were offered, including that high percentages of injected liquid water can reduce reactor operating temperature; combustion of BTEX remained highly efficient, however liquid injection could also cause temperature reductions and ultimately the reactor would extinguish; and pre-heating the feed can eliminate the temperature drop and pad wetness problem. It was concluded that BTEX compounds are reactive, and the technology appears promising. 19 figs

Catalytic combustion for the elimination of methane, BTEX and other VOC : IV

Energy Technology Data Exchange (ETDEWEB)

Hayes, R.E.; Wanke, S.E. [Alberta Univ., Edmonton, AB (Canada). Dept. of Chemical and Materials Engineering

2008-07-01

Options for volatile organic compound combustion include homogeneous combustion (flaring) or catalytic combustion involving a flameless combustion process that uses a solid catalyst to promote the combustion reaction. This presentation discussed relative reactivity testing for volatile organic compounds (VOCs) over commercial catalysts. Several commercial pad catalysts were tested, as well as other powders. The relative reactivity of methane as well as benzene, toluene, ethylbenzene, and xylene (BTEX) were investigated. The purpose of the project was to evaluate combustion of concentrated methane streams that contained BTEX compounds; evaluate catalytic combustion using a counter diffusive radiant heater; develop mathematical models for the reactor to enhance design and understanding; improve the catalyst for BTEX combustion; and target application-dehydrator units. Topics that were addressed in the presentation included methane and benzene conversion; catalytic radiant heaters; small industrial and commercial units; measured temperature distribution; fuel slippage, methane conversion; the effect of water and hydrocarbons; the effect of water-liquid injection; and water addition as vapour. Several observations were offered, including that high percentages of injected liquid water can reduce reactor operating temperature; combustion of BTEX remained highly efficient, however liquid injection could also cause temperature reductions and ultimately the reactor would extinguish; and pre-heating the feed can eliminate the temperature drop and pad wetness problem. It was concluded that BTEX compounds are reactive, and the technology appears promising. 19 figs.

Characterisation of ashes produced by co-combustion of recovered fuels and peat

Energy Technology Data Exchange (ETDEWEB)

Frankenhaeuser, M.; Zevenhoven, R. [Borealis Polymers Oy, Porvoo (Finland); Skrifvars, B.J. [Aabo Akademi, Turku (Finland); Orjala, M. [VTT Energy, Espoo (Finland); Peltola, K. [Foster Wheeler Energy (Finland)

1996-12-01

Source separation of combustible materials from household or municipal solid waste yields a raw material for the production of Packaging Derived Fuel (PDF). This fuel can substitute the traditional fuels in heat and power generation and is also called recycled fuel. Co-combustion of these types of fuels with coal has been studied in several LIEKKI-projects and the results have been both technically and environmentally favourable. (author)

The source apportionment of carbonaceous combustion products by micro-radiocarbon measurements for the integrated air cancer project (IACP)

International Nuclear Information System (INIS)

Klouda, G.A.; Currie, L.A.; Sheffield, A.E.; Wise, S.A.; Benner, B.A.; Stevens, R.K.; Merrill, R.G.

1987-01-01

Atmospheric particle samples were collected during the winter of 1984-1985 in Albuquerque, NM and Raleigh, NC by the EPA for the Integrated Air Cancer Project (IACP). Selected chemical fractions were analyzed for /sup 14/C to apportion mobile (motor vehicles) and stationary (residential wood combustion) sources. In addition, these results were used to validate the EPA Single Tracer Regression Model (STRM), also a technique for the source apportionment of aerosols. Preliminary /sup 14/C results for the Albuquerque residential site at night showed 79% Contemporary Carbon (CC) compared to 95% CC for Raleight at night for the total carbon; 88% and 94% of the total-C was organic, respectively. The Albuquerque traffic site during the day showed 1.4 to 3.9 times less CC compared to the daytime residential site for total-C. The elemental carbon fraction in all cases showed a lower percentage of contemporary carbon than the total carbon, which indicates that this chemical fraction may be an excellent tracer of mobile sources. These results are consistent with a daytime mobile source at the traffic site and a nighttime Residential Wood Combustion (RWC) source at the residential site. Also, the results from the EPA STRM technique for this study were in good agreement with those obtained by the /sup 14/C Direct Tracer (/sup 14/C-DT) technique for source apportionment of these aerosols

Some Factors Affecting Combustion in an Internal-Combustion Engine

Science.gov (United States)

Rothrock, A M; Cohn, Mildred

1936-01-01

An investigation of the combustion of gasoline, safety, and diesel fuels was made in the NACA combustion apparatus under conditions of temperature that permitted ignition by spark with direct fuel injection, in spite of the compression ratio of 12.7 employed. The influence of such variables as injection advance angle, jacket temperature, engine speed, and spark position was studied. The most pronounced effect was that an increase in the injection advance angle (beyond a certain minimum value) caused a decrease in the extent and rate of combustion. In almost all cases combustion improved with increased temperature. The results show that at low air temperatures the rates of combustion vary with the volatility of the fuel, but that at high temperatures this relationship does not exist and the rates depend to a greater extent on the chemical nature of the fuel.

Reduced NOX combustion method

International Nuclear Information System (INIS)

Delano, M.A.

1991-01-01

This patent describes a method for combusting fuel and oxidant to achieve reduced formation of nitrogen oxides. It comprises: It comprises: heating a combustion zone to a temperature at least equal to 1500 degrees F.; injecting into the heated combustion zone a stream of oxidant at a velocity within the range of from 200 to 1070 feet per second; injecting into the combustion zone, spaced from the oxidant stream, a fuel stream at a velocity such that the ratio of oxidant stream velocity to fuel stream velocity does not exceed 20; aspirating combustion gases into the oxidant stream and thereafter intermixing the aspirated oxidant stream and fuel stream to form a combustible mixture; combusting the combustible mixture to produce combustion gases for the aspiration; and maintaining the fuel stream substantially free from contact with oxidant prior to the intermixture with aspirated oxidant

Saskatchewan combustion recovery an operational success

Energy Technology Data Exchange (ETDEWEB)

1967-12-04

Mobil Oil Co.'s in-situ combustion recovery project in the Battrum heavy oil field in SW. Saskatchewan is an operational success, but not a profit-making venture so far. Some of the details resulting from a discussion with the senior project engineer are discussed. It is explained that 100% displacement efficiency is attained in the burned zone by way of fluid convection resulting from heat conduction. Reasons for selecting the Battrum reservoir are also considered. The pilot project currently being conducted is intended to determine information on the following factors: effect of productivity, injectivity index data, air-oil ratio performance, distribution of injected gas, ignition characteristics, and sweep efficiency. The largest problems are associated with equipment, well completions, and handling of produced fluids.

Method and device for diagnosing and controlling combustion instabilities in internal combustion engines operating in or transitioning to homogeneous charge combustion ignition mode

Science.gov (United States)

Wagner, Robert M [Knoxville, TN; Daw, Charles S [Knoxville, TN; Green, Johney B [Knoxville, TN; Edwards, Kevin D [Knoxville, TN

2008-10-07

This invention is a method of achieving stable, optimal mixtures of HCCI and SI in practical gasoline internal combustion engines comprising the steps of: characterizing the combustion process based on combustion process measurements, determining the ratio of conventional and HCCI combustion, determining the trajectory (sequence) of states for consecutive combustion processes, and determining subsequent combustion process modifications using said information to steer the engine combustion toward desired behavior.

New approaches for description of nitrogen chemistry in combustion processes

Energy Technology Data Exchange (ETDEWEB)

Hupa, M.; Kilpinen, P.; Nordstroem, T. [Aabo Akademi, Turku (Finland). Combustion Chemistry Research Group

1997-10-01

The aim of the project is to assist in development of more efficient in-furnace control methods for nitrogen oxide emission from energy conversion technologies based on combustion and/or gasification. Main emphasis in put on technologies such as fluidized bed combustion (CFBC, BFBC) and combined cycle processes (PFBC, IGCC). The project consists of two parts: (a) detailed kinetic elementary reaction modelling and (b) prediction of NO{sub x} emission from full scale combustors. The following topics have been studied during 1996: (a) Detailed kinetic modelling Effect of HCl on CO burn-out under FBC freeboard conditions. Effect of pressure on the Thermal DeNO{sub x} process under PFBC conditions. Mechanism of NH{sub 3} destruction to N{sub 2} by selective oxidation (SO): -the importance of formation of NO{sub 2} from NO and O{sub 2} at low temperatures. (b) Prediction of NO{sub x} emission from full scale combustors Prediction of NO{sub x} emission from BFBC freeboard: a case study using flow tubes and detailed chemistry. The work has been made partly in collaboration with VTT Energy (projects 213 and 214) and Tampere University of Technology (project 210). (orig.)

Reduction of NO{sub x} emissions from the combustion of hard coals ''RENOX''; Reduccion de Emisiones de NO{sub x} en la combustion de Carbones Antracitosos ''RENOX''

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-07-01

The present project, whose abbreviated name is RENOX, has the aim of reducing NO{sub x} emissions from the combustion of hard coals or coals with low volatile matter contents. It is applied to the combustion of these coals in arc boilers (or ''U'' boilers), where the necessary combination of long presence times and high hearth temperatures facilitates the high NO{sub x} levels reached. The intended reduction in emissions is approached through the application of primary combustion measures, also known as adjustment or refining of combustion. This solution is adopted for two reasons: due to its efficiency in environmental and economic terms, and because it is an unavoidable step if the levels to be attained require the installation of specific gas crubbing systems (secondary measures). The practical nature of RENOX has led to the development of the project in two phases, corresponding to two logical stages: phase 1, associated with the RNA project, on the characterization of emissions and combustion, complex numeric modelling of flows inside the boiler, and determination of the viability and scope of the optimization of emissions, and phase 2, the OPTINOXproject, which follows the methodology and lessons of the first phase and, as a natural continuation of this, deals with the design, development, manufacturing and validation of a computerized system that processes real time data on the boiler where it is installed to monitor, supervise and control the commercial operation of the plant, optimizing its combustion efficiency and/or NO{sub x} emissions. The practical objective of this project is represented by the construction of a validated prototype to demonstrate the OPTINOX system, which is capable of determining operating and control strategies that can minimize NO{sub x} emissions without unfavourably affecting the productivity and specific consumption of the units. Phase 1 development activities took place in groups 3, 4 and 5 of Compostilla

New class of combustion processes

International Nuclear Information System (INIS)

Merzhanov, A.G.; Borovinskaya, I.P.

1975-01-01

A short review is given of the results of work carried out since 1967 on studying the combustion processes caused by the interaction of chemical elements in the condensed phase and leading to the formation of refractory compounds. New phenomena and processes are described which are revealed when investigating the combustion of the systems of this class, viz solid-phase combustion, fast combustion in the condensed phase, filtering combustion, combustion in liquid nitrogen, spinning combustion, self-oscillating combustion, and repeated combustion. A new direction in employment of combustion processes is discussed, viz. a self-propagating high-temperature synthesis of refractory nitrides, carbides, borides, silicides and other compounds

Experimental validation for combustion analysis of GOTHIC code in 2-dimensional combustion chamber

International Nuclear Information System (INIS)

Lee, J. W.; Yang, S. Y.; Park, K. C.; Jung, S. H.

2002-01-01

In this study, the prediction capability of GOTHIC code for hydrogen combustion phenomena was validated with the results of two-dimensional premixed hydrogen combustion experiment executed by Seoul National University. The experimental chamber has about 24 liter free volume (1x0.024x1 m 3 ) and 2-dimensional rectangular shape. The test were preformed with 10% hydrogen/air gas mixture and conducted with combination of two igniter positions (top center, top corner) and two boundary conditions (bottom full open, bottom right half open). Using the lumped parameter and mechanistic combustion model in GOTHIC code, the SNU experiments were simulated under the same conditions. The GOTHIC code prediction of the hydrogen combustion phenomena did not compare well with the experimental results. In case of lumped parameter simulation, the combustion time was predicted appropriately. But any other local information related combustion phenomena could not be obtained. In case of mechanistic combustion analysis, the physical combustion phenomena of gas mixture were not matched experimental ones. In boundary open cases, the GOTHIC predicted very long combustion time and the flame front propagation could not simulate appropriately. Though GOTHIC showed flame propagation phenomenon in adiabatic calculation, the induction time of combustion was still very long compare with experimental results. Also, it was found that the combustion model of GOTHIC code had some weak points in low concentration of hydrogen combustion simulation

The Healy Clean Coal Project: Design verification tests

International Nuclear Information System (INIS)

Guidetti, R.H.; Sheppard, D.B.; Ubhayakar, S.K.; Weede, J.J.; McCrohan, D.V.; Rosendahl, S.M.

1993-01-01

As part of the Healy Clean Coal Project, TRW Inc., the supplier of the advanced slagging coal combustors, has successfully completed design verification tests on the major components of the combustion system at its Southern California test facility. These tests, which included the firing of a full-scale precombustor with a new non-storage direct coal feed system, supported the design of the Healy combustion system and its auxiliaries performed under Phase 1 of the project. Two 350 million BTU/hr combustion systems have been designed and are now ready for fabrication and erection, as part of Phase 2 of the project. These systems, along with a back-end Spray Dryer Absorber system, designed and supplied by Joy Technologies, will be integrated with a Foster Wheeler boiler for the 50 MWe power plant at Healy, Alaska. This paper describes the design verification tests and the current status of the project

Preliminary assessment of combustion modes for internal combustion wave rotors

Science.gov (United States)

Nalim, M. Razi

1995-01-01

Combustion within the channels of a wave rotor is examined as a means of obtaining pressure gain during heat addition in a gas turbine engine. Several modes of combustion are considered and the factors that determine the applicability of three modes are evaluated in detail; premixed autoignition/detonation, premixed deflagration, and non-premixed compression ignition. The last two will require strong turbulence for completion of combustion in a reasonable time in the wave rotor. The compression/autoignition modes will require inlet temperatures in excess of 1500 R for reliable ignition with most hydrocarbon fuels; otherwise, a supplementary ignition method must be provided. Examples of combustion mode selection are presented for two core engine applications that had been previously designed with equivalent 4-port wave rotor topping cycles using external combustion.

Multi-Canister Overpack (MCO) Combustible Gas Management Leak Test Acceptance Criteria (OCRWM)

International Nuclear Information System (INIS)

SHERRELL, D.L.

2000-01-01

The purpose of this document is to support the Spent Nuclear Fuel Project's combustible gas management strategy while avoiding the need to impose any requirements for oxygen free atmospheres within storage tubes that contain multi-canister overpacks (MCO). In order to avoid inerting requirements it is necessary to establish and confirm leak test acceptance criteria for mechanically sealed and weld sealed MCOs that are adequte to ensure that, in the unlikely event the leak test results for any MCO were to approach either of those criteria, it could still be handled and stored in stagnant air without compromising the SNF Project's overall strategy to prevent accumulation of combustible gas mixtures within MCOs or within their surroundings. To support that strategy, this document: (1) establishes combustible gas management functions and minimum functional requirements for the MCO's mechanical seals and closure weld(s); (2) establishes a maximum practical value for the minimum required initial MCO inert backfill gas pressure; and (3) based on items 1 and 2, establishes and confirms leak test acceptance criteria for the MCO's mechanical seal and final closure weld(s)

Combustion modeling in internal combustion engines

Science.gov (United States)

Zeleznik, F. J.

1976-01-01

The fundamental assumptions of the Blizard and Keck combustion model for internal combustion engines are examined and a generalization of that model is derived. The most significant feature of the model is that it permits the occurrence of unburned hydrocarbons in the thermodynamic-kinetic modeling of exhaust gases. The general formulas are evaluated in two specific cases that are likely to be significant in the applications of the model.

A predictive model of natural gas mixture combustion in internal combustion engines

Directory of Open Access Journals (Sweden)

Henry Espinoza

2007-05-01

Full Text Available This study shows the development of a predictive natural gas mixture combustion model for conventional com-bustion (ignition engines. The model was based on resolving two areas; one having unburned combustion mixture and another having combustion products. Energy and matter conservation equations were solved for each crankshaft turn angle for each area. Nonlinear differential equations for each phase’s energy (considering compression, combustion and expansion were solved by applying the fourth-order Runge-Kutta method. The model also enabled studying different natural gas components’ composition and evaluating combustion in the presence of dry and humid air. Validation results are shown with experimental data, demonstrating the software’s precision and accuracy in the results so produced. The results showed cylinder pressure, unburned and burned mixture temperature, burned mass fraction and combustion reaction heat for the engine being modelled using a natural gas mixture.

Boiler using combustible fluid

Science.gov (United States)

Baumgartner, H.; Meier, J.G.

1974-07-03

A fluid fuel boiler is described comprising a combustion chamber, a cover on the combustion chamber having an opening for introducing a combustion-supporting gaseous fluid through said openings, means to impart rotation to the gaseous fluid about an axis of the combustion chamber, a burner for introducing a fluid fuel into the chamber mixed with the gaseous fluid for combustion thereof, the cover having a generally frustro-conical configuration diverging from the opening toward the interior of the chamber at an angle of between 15/sup 0/ and 55/sup 0/; means defining said combustion chamber having means defining a plurality of axial hot gas flow paths from a downstream portion of the combustion chamber to flow hot gases into an upstream portion of the combustion chamber, and means for diverting some of the hot gas flow along paths in a direction circumferentially of the combustion chamber, with the latter paths being immersed in the water flow path thereby to improve heat transfer and terminating in a gas outlet, the combustion chamber comprising at least one modular element, joined axially to the frustro-conical cover and coaxial therewith. The modular element comprises an inner ring and means of defining the circumferential, radial, and spiral flow paths of the hot gases.

Combustion behaviour of pulverised wood - Numerical and experimental studies

Energy Technology Data Exchange (ETDEWEB)

Lixin Tao [TPS Termiska Processer AB, Nykoeping (Sweden)

2002-05-01

This report presents the experimental results achieved in an on-going project financed by STEM (Energimyndigheten) within the research program 'Gasification and combustion of solid fuels', during the first phase of the project (2001-03-05 to 2002-03-05). The project is a collaboration project between LTH and TPS on combined numerical modelling/experimental investigation on combustion of pulverised wood. Particularly TPS carry out the experimental investigation in a laboratory vertical furnace. During the project, the experimental rig has been developed. The experimental furnace has an inner diameter of 0.25 m and a height of 4 m. A pulverised wood flame is established using an axial burner that is installed on the top of the furnace. Experimental study on a selected pulverised wood with determined size distribution and anisotropy character has been carried out in this furnace. During the experiment, the wall temperatures of the furnace were continuously measured using 8 thermocouples of type K that are installed on the wall with a spacing about 0.5 m. The gas temperatures in the furnace were monitored using 5 fixed suction pyrometers that are placed along the centre of the furnace. At the bottom of the furnace, a fixed gas-sampling probe was installed. The flue gas concentrations were continuously monitored with on-line gas analysers. The extent of combustion was measured through the analysis of sampled gaseous products and condensable solid products. A movable liquid quench probe was used to carry out the gas and solid sampling through a number of sampling holes that are opened along the furnace wall. The quench liquor used is an alkaline water solution containing a small amount of a detergent to dissolve HCN and tar. The quench liquor and solid samples were separated and collected in a knockout pot. The gas was filtered and passed through two bubblers with acidic solution to collect NH{sub 3}. The gas concentrations were then analysed with on-line gas

N2O formation in combustion systems

International Nuclear Information System (INIS)

1989-11-01

The objective of this project is to characterize N 2 O emissions from combustion sources emphasizing N 2 O emissions from post-combustion selective gas phase NO x reduction processes and reburning. The processes to be evaluated include ammonia, urea and cyanuric acid injection and reburning. The project includes pilot-scale testing at two facilities supported by chemical kinetic modeling. Testing will be performed on both a gas-fired plug flow combustor and a pulverized-coal fired combustor. Work performed to date has included the performance of the initial detailed chemical kinetics calculations. These calculations showed that both urea and cyanuric acid produce significant quantities of N 2 O, while NH 3 injection produced negligible amounts. These kinetics data support limited test results reported for cyanuric acid and ammonia injection. Laboratory work to evaluate the selective gas phase NO x reduction processes listed above will begin in the gas-fired facility early in CY 1990. Testing to evaluate reburning at the coal-fired facility is currently planned to be performed in parallel with the testing at the gas-fired facility. Following completion of that work, additional kinetics calculations will be performed

Oxy-fuel combustion on circulating fluidized bed. Chapter 5

Energy Technology Data Exchange (ETDEWEB)

Anthony, E.J. [Canmet, Natural Resources Canada (Canada); Hack, H. [Foster Wheeler North America Corporation (United States)

2011-07-01

This paper explores the developments and field tests carried out with oxy-fuel fluidized bed combustion. This method has the advantage over the other options of emitting a pure stream of CO2 which thus does not need to be concentrated to be liquefied, transported and stored. In addition, pilot scale tests have shown that oxy-fired circulating fluidized bed combustion (CFBC) results in low emission and fuel flexibility. This paper highlighted that oxy-fired CFBC might be a good option for CCS but tests performed so far have been on a small scale. To confirm the promising results of pilot tests, demonstration projects are underway and are presented herein.

Experimental Study of Liquid Fuel Spray Combustion

DEFF Research Database (Denmark)

Westlye, Fredrik Ree

the specific physical quantities needed in CFD validation of these types of flames. This work is a testament to that fact. The first part of this thesis is an extensive study of optical combustion diagnostics applied to complex transient sprayflames in a high temperature and pressure environment...... by the Danish Council for Strategic Research. Other supporters of the project have been MAN Diesel & Turbo A/S, DTU Mechanical Engineering, DTU Chemical Engineering, Sandia National Laboratories USA, Norwegian University of Science & Technology (NTNU) and University of Nottingham, Malaysia Campus.......The physiochemical properties and electromagnetic interactions in flames, of which various optical combustion diagnostics are based, have been reviewed. Key diagnostics have been presented with practical examples of their application which, together with a comprehensive review of fuel spray flames, form...

New black liquor combustion characteristics II; Mustalipeaen uudet poltto-ominaisuudet II

Energy Technology Data Exchange (ETDEWEB)

Hupa, M.; Backman, R.; Bostroem, S.; Forssen, M.; Uusikartano, T. [Aabo Akademi, Turku (Finland)

1996-12-01

In an earlier study (LIEKKI 2, Y 17), the combustion characteristics of 17 liquors of different origin were studied by four laboratory tests. These tests were (1) single droplet burning, (2) single droplet pyrolysis, (3) pressurized gasification, and (4) calculation of melting properties of inorganic carryover particles. The study showed that there are big differences between liquors of different origin. These differences strongly affect the combustion properties, i.e. pyrolysis and burning times, swelling, and fouling tendency of heat transfer surfaces. The objective for the present research project was to investigate the reasons why some properties affect the combustion behavior more than others. The project is partly complementary to the previous study, partly a more detailed study of some of the phenomena observed earlier. The work constitutes of the following studies: (1) further study of several more liquors by the same methods, (2) pyrolysis swelling in inert gas (N{sub 2}) at two temperatures, 700 deg C and 900 deg C, (3) effect of heat treatment black liquors, (4) effect of addition of sodium compounds to a virgin black liquor, (5) data treatment and correlations, (6) nitrogen oxide formation tendency. (author)

Development of teaching material to integrate GT-POWER into combustion courses for IC engine simulations.

Science.gov (United States)

2009-02-01

The main objective of this project was to develop instructional engineering projects that utilize the newly-offered PACE software GT-POWER for engine simulations in combustion-related courses at the Missouri University of Science and Technology. Stud...

Study of Catalysts and Electrocatalysts for NO{sub x} Removal in Combustion Gases ELECTRONOX Project Final Report; Estudio de Catalizadores y Electrocatalizadores para la Eliminacion de NO{sub x} en Gases de Combustion. Informe Final Proyecto ELECTRONOX

Energy Technology Data Exchange (ETDEWEB)

Ruiz Martinez, E; Marono Bujan, M; Sanchez-Hervas, J M

2009-12-11

The final aim of the ELECTRONOX project was to develop new methodologies and technologies for NO{sub x} removal. To fulfil this objective, studies of selective catalytic reduction of NO{sub x} with hydrocarbons, both conventional and with electrochemical promotion, have been undertaken at pilot plant level, using appropriate catalyst/electrocatalysts configurations and in conditions similar to those required in their possible practical application. None of the catalysts/electrocatalysts studied is active and stable enough, under realistic conditions, to consider its possible industrial application, because the value of NO{sub x} conversion achieved by selective catalytic reduction with hydrocarbons, both conventional and with electrochemical promotion, decreases in presence of the different inhibitors and poisons present in the combustion gas, while the promotional effect on the catalytic activity and selectivity is more pronounced. In addition, the catalysts/electrocatalysts suffer from different deactivation processes, such as: sulphur poisoning, carbon deposition and sintering. However, the developed electrochemical catalyst looks promising for NO{sub x} removal in combustion gases, because it can be promoted under realistic operating conditions. (Author) 23 refs.

Microemulsions in the Preparation of Highly Active Combustion Catalysts

Czech Academy of Sciences Publication Activity Database

Rymeš, Jan; Ehret, G.; Hilaire, L.; Boutonnet, M.; Jirátová, Květa

2002-01-01

Roč. 75, 1-4 (2002), s. 297-303 ISSN 0920-5861 R&D Projects: GA ČR GA106/02/0523 Institutional research plan: CEZ:AV0Z4072921 Keywords : microemulsion s * catalytic combustion * VOC Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 2.146, year: 2002

Co-combustion for fossil fuel replacement and better environment

Energy Technology Data Exchange (ETDEWEB)

Lopes, M. Helena; Gulyurtlu, Ibrahim; Abelha, Pedro; Teixeira, P.; Crujeira, Teresa; Boavida, Dulce; Marques, F.; Cabrita, Isabel [INETI/DER, Lisboa (Portugal)

2006-07-01

The growing demand for energy and the requirements regarding CO{sub 2} emissions to comply with the Kyoto targets, together with crisis associated with the fuel supply, can be, to some degree, met by the use of renewable fuel sources, such as biomass. Although the use of biomass, originating from forests, could be beneficial, particularly in preventing fires, there are obstacles to achieve a sustainable supply of biomass in most European countries. In addition, there are also technical barriers as biomass combustion conditions may differ from those of coal, which could mean significant retrofitting of existing installations. The significance of this problem was recognized in the EU and a Project is being financed by the 6th Framework Programme, INETI from Portugal being the coordinator. Five EU countries plus Turkey participate in the project which aims at evaluating both the sustainable chain supply in the several countries, taking profit of the experience of northern European countries and the technical issues related with the co-combustion process, pollutant emission control and operational problems, such as fouling and slagging inside the boilers. At INETI, experimental work is being carried out, involving the characterization of several types of biomass and non-toxic residues. These materials are being burned on a pilot fluidized bed combustor, in order to evaluate combustion performance and improve conditions and synergies of fuel blends to control pollutant emissions and slagging tendency. Ashes produced are also being characterized, for composition and leachability, in order to evaluate possibilities of reutilization and compliance with landfilling regulations. In this paper a description of the project is presented, along with some of the results already obtained.

Co-combustion for fossil fuel replacement and better environment

Energy Technology Data Exchange (ETDEWEB)

M. Helena Lopes; I. Gulyurtlu; P. Abelha; P. Teixeira; T. Crujeira; D. Boavida; F. Marques; I. Cabrita [INETI, Lisbon (Portugal)

2006-07-01

The growing demand for energy and the requirement regarding CO{sub 2} emissions, to comply with the Kyoto targets, together with crisis associated with the fuel supply, can be, to some degree, met by the use of renewable fuel sources, such as biomass. Although the use of biomass, originating from forests, could be beneficial, there are obstacles to achieve a sustainable supply of biomass in most European countries. In addition, there are also technical barriers as biomass combustion conditions may differ from those of coal, which could mean significant retrofitting of existing installations. The significance of this problem was recognized in the EU and a Project is being financed by the 6th Framework Programme, INETI from Portugal being the coordinator. Five EU countries plus Turkey participate in the project which aims at evaluating both the sustainable chain supply in the several countries, taking profit of the experience of northern European countries and the technical issues related with the co-combustion process, pollutant emission control and operational problems, such as fouling and slagging inside the boilers. At INETI, experimental work is being carried out, involving the characterization of several types of biomass and non-toxic residues. These materials are being burned on a pilot fluidized bed combustor, in order to evaluate combustion performance and improve conditions and synergies of fuel blends to control pollutant emissions and slagging tendency. Ashes produced are also being characterized, for composition and leachability, in order to evaluate possibilities of reutilization and compliance with landfilling regulations. In this paper a description of the project is presented, along with some of the results already obtained. 19 refs., 5 figs., 7 tabs.

Gradual combustion - method for nitrogen oxide suppression during brown coal combustion

Energy Technology Data Exchange (ETDEWEB)

Kotler, V.P.; Verzakov, V.N.; Lobov, T.V.

1990-10-01

Discusses combustion of brown coal in BKZ-500-140-1 boilers and factors that influence emission of nitrogen oxides. Temperature distribution in the furnace was evaluated. Effects of burner position, burner number and burner type as well as air excess ratio on chemical reactions during brown coal combustion, formation of nitrogen oxides and their emission were comparatively evaluated. Analyses showed that by optimum arrangement of burners and selecting the optimum air excess ratio a part of nitrogen oxides formed during the initial phase of combustion was reduced to molecular nitrogen in the second phase. On the basis of evaluations the following recommendations for furnace design are made: use of straight-flow burners characterized by a reduced mixing ratio with secondary air, parallel arrangement of burners which guarantees mixing of the combustion products from the burners with stable and unstable combustion (products of incomplete coal combustion), reducing the air excess ratio to below 1.0. 5 refs.

Pt Combustion Catalysts Prepared from W/O Microemulsions

Czech Academy of Sciences Publication Activity Database

Rymeš, Jan; Ehret, G.; Hilaire, L.; Jirátová, Květa

2002-01-01

Roč. 143, - (2002), s. 121-129 ISSN 0167-2991. [International Symposium Scientific Bases for the Preparation of Heterogeneous Catalysts /8./. Louvain-la-Neuve, 09.09.2002-12.09.2002] R&D Projects: GA AV ČR IAA4072904 Keywords : combustion catalysts * microemulsion s Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 3.468, year: 2002

Municipal solid waste combustion: Fuel testing and characterization

Energy Technology Data Exchange (ETDEWEB)

Bushnell, D.J.; Canova, J.H.; Dadkhah-Nikoo, A.

1990-10-01

The objective of this study is to screen and characterize potential biomass fuels from waste streams. This will be accomplished by determining the types of pollutants produced while burning selected municipal waste, i.e., commercial mixed waste paper residential (curbside) mixed waste paper, and refuse derived fuel. These materials will be fired alone and in combination with wood, equal parts by weight. The data from these experiments could be utilized to size pollution control equipment required to meet emission standards. This document provides detailed descriptions of the testing methods and evaluation procedures used in the combustion testing and characterization project. The fuel samples will be examined thoroughly from the raw form to the exhaust emissions produced during the combustion test of a densified sample.

Development and Testing of Industrial Scale Coal Fired Combustion System, Phase 3

Energy Technology Data Exchange (ETDEWEB)

Bert Zauderer

1998-09-30

Coal Tech Corp's mission is to develop, license & sell innovative, lowest cost, solid fuel fired power systems & total emission control processes using proprietary and patented technology for domestic and international markets. The present project 'DEVELOPMENT & TESTING OF INDUSTRIAL SCALE, COAL FIRED COMBUSTION SYSTEM, PHASE 3' on DOE Contract DE-AC22-91PC91162 was a key element in achieving this objective. The project consisted of five tasks that were divided into three phases. The first phase, 'Optimization of First Generation 20 MMBtu/hr Air-Cooled Slagging Coal Tech Combustor', consisted of three tasks, which are detailed in Appendix 'A' of this report. They were implemented in 1992 and 1993 at the first generation, 20 MMBtu/hour, combustor-boiler test site in Williamsport, PA. It consisted of substantial combustor modifications and coal-fired tests designed to improve the combustor's wall cooling, slag and ash management, automating of its operation, and correcting severe deficiencies in the coal feeding to the combustor. The need for these changes was indicated during the prior 900-hour test effort on this combustor that was conducted as part of the DOE Clean Coal Program. A combination of combustor changes, auxiliary equipment changes, sophisticated multi-dimensional combustion analysis, computer controlled automation, and series of single and double day shift tests totaling about 300 hours, either resolved these operational issues or indicated that further corrective changes were needed in the combustor design. The key result from both analyses and tests was that the combustor must be substantially lengthened to maximize combustion efficiency and sharply increase slag retention in the combustor. A measure of the success of these modifications was realized in the third phase of this project, consisting of task 5 entitled: 'Site Demonstration with the Second Generation 20 MMBtu/hr Air-Cooled Slagging Coal Tech

Uncertainties in hydrogen combustion

International Nuclear Information System (INIS)

Stamps, D.W.; Wong, C.C.; Nelson, L.S.

1988-01-01

Three important areas of hydrogen combustion with uncertainties are identified: high-temperature combustion, flame acceleration and deflagration-to-detonation transition, and aerosol resuspension during hydrogen combustion. The uncertainties associated with high-temperature combustion may affect at least three different accident scenarios: the in-cavity oxidation of combustible gases produced by core-concrete interactions, the direct containment heating hydrogen problem, and the possibility of local detonations. How these uncertainties may affect the sequence of various accident scenarios is discussed and recommendations are made to reduce these uncertainties. 40 references

The combustion behavior of diesel/CNG mixtures in a constant volume combustion chamber

Science.gov (United States)

Firmansyah; Aziz, A. R. A.; Heikal, M. R.

2015-12-01

The stringent emissions and needs to increase fuel efficiency makes controlled auto-ignition (CAI) based combustion an attractive alternative for the new combustion system. However, the combustion control is the main obstacles in its development. Reactivity controlled compression ignition (RCCI) that employs two fuels with significantly different in reactivity proven to be able to control the combustion. The RCCI concept applied in a constant volume chamber fuelled with direct injected diesel and compressed natural gas (CNG) was tested. The mixture composition is varied from 0 - 100% diesel/CNG at lambda 1 with main data collection are pressure profile and combustion images. The results show that diesel-CNG mixture significantly shows better combustion compared to diesel only. It is found that CNG is delaying the diesel combustion and at the same time assisting in diesel distribution inside the chamber. This combination creates a multipoint ignition of diesel throughout the chamber that generate very fast heat release rate and higher maximum pressure. Furthermore, lighter yellow color of the flame indicates lower soot production in compared with diesel combustion.

Combustion characteristics and air pollutant formation during oxy-fuel co-combustion of microalgae and lignite.

Science.gov (United States)

Gao, Yuan; Tahmasebi, Arash; Dou, Jinxiao; Yu, Jianglong

2016-05-01

Oxy-fuel combustion of solid fuels is seen as one of the key technologies for carbon capture to reduce greenhouse gas emissions. The combustion characteristics of lignite coal, Chlorella vulgaris microalgae, and their blends under O2/N2 and O2/CO2 conditions were studied using a Thermogravimetric Analyzer-Mass Spectroscopy (TG-MS). During co-combustion of blends, three distinct peaks were observed and were attributed to C. vulgaris volatiles combustion, combustion of lignite, and combustion of microalgae char. Activation energy during combustion was calculated using iso-conventional method. Increasing the microalgae content in the blend resulted in an increase in activation energy for the blends combustion. The emissions of S- and N-species during blend fuel combustion were also investigated. The addition of microalgae to lignite during air combustion resulted in lower CO2, CO, and NO2 yields but enhanced NO, COS, and SO2 formation. During oxy-fuel co-combustion, the addition of microalgae to lignite enhanced the formation of gaseous species. Copyright © 2016 Elsevier Ltd. All rights reserved.

Combustion char characterisation. Final report

Energy Technology Data Exchange (ETDEWEB)

Rosenberg, P; Ingermann Petersen, H; Sund Soerensen, H; Thomsen, E; Guvad, C

1996-06-01

The aim was to correlate reactivity measures of raw coals and the maceral concentrates of the coals obtained in a previous project with the morphology of the produced chars by using a wire grid devolatilization method. Work involved determination of morphology, macroporosity and a detailed study by Scanning Electron Microscopy (SEM). Systematic variations in the texture of chars produced in different temperature domains and heating rates were demonstrated by using incident light microscopy on polished blocks and by SEM studies directly on the surfaces of untreated particles. Results suggest that work in the field of char reactivity estimates and correlations between char morphology and coal petrography can be accomplished only on chars produced under heating rates and temperatures comparable to those for the intended use of coal. A general correlation between the coals` petrography and the the morphology of high temperature chars was found. The SEM study of the chars revealed that during the devolatilization period the particles fuse and the macroporosity and thus the morphotypes are formed. After devolatilization ceases, secondary micropores are formed. These develop in number and size throughout the medium combustion interval. At the end of the combustion interval the macrostructure breaks down, caused by coalescence of the increased number of microspores. This can be observed as a change in the morphology and the macroporosity of the chars. Results indicate that char reactivity is a function of the macroporosity and thus the morphology of combustion chars. (AB) 34 refs.

Combustion Safety Simplified Test Protocol Field Study

Energy Technology Data Exchange (ETDEWEB)

Brand, L. [Gas Technology Inst., Des Plaines, IL (United States); Cautley, D. [Gas Technology Inst., Des Plaines, IL (United States); Bohac, D. [Gas Technology Inst., Des Plaines, IL (United States); Francisco, P. [Gas Technology Inst., Des Plaines, IL (United States); Shen, L. [Gas Technology Inst., Des Plaines, IL (United States); Gloss, S. [Gas Technology Inst., Des Plaines, IL (United States)

2015-11-01

Combustions safety is an important step in the process of upgrading homes for energy efficiency. There are several approaches used by field practitioners, but researchers have indicated that the test procedures in use are complex to implement and provide too many false positives. Field failures often mean that the house is not upgraded until after remediation or not at all, if not include in the program. In this report the PARR and NorthernSTAR DOE Building America Teams provide a simplified test procedure that is easier to implement and should produce fewer false positives. A survey of state weatherization agencies on combustion safety issues, details of a field data collection instrumentation package, summary of data collected over seven months, data analysis and results are included. The project team collected field data on 11 houses in 2015.

Chemical Kinetic Models for Advanced Engine Combustion

Energy Technology Data Exchange (ETDEWEB)

Pitz, William J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Mehl, Marco [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Westbrook, Charles K. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

2014-10-22

The objectives for this project are as follows: Develop detailed chemical kinetic models for fuel components used in surrogate fuels for compression ignition (CI), homogeneous charge compression ignition (HCCI) and reactivity-controlled compression-ignition (RCCI) engines; and Combine component models into surrogate fuel models to represent real transportation fuels. Use them to model low-temperature combustion strategies in HCCI, RCCI, and CI engines that lead to low emissions and high efficiency.

Characterisation of ashes produced by co-combustion of recovered fuels and peat

Energy Technology Data Exchange (ETDEWEB)

Frankenhaeuser, M. [Borealis Polymers Oy, Porvoo (Finland)

1997-10-01

The current project focuses on eventual changes in ash characteristics during co-combustion of refuse derived fuel with coal, peat, wood or bark, which could lead to slagging, fouling and corrosion in the boiler. Ashes were produced at fluidised bed (FB) combustion conditions in the 15 kW reactor at VTT Energy, Jyvaeskylae, the fly ash captured by the cyclone was further analysed by XRF at Outokumpu Geotechnical Laboratory, Outokumpu. The sintering behaviour of these ashes was investigated using a test procedure developed at the Combustion Chemistry Research Group at Aabo Akademi University. The current extended programme includes a Danish refuse-derived fuel (RDF), co-combusted with bark/coal (5 tests) and wood/coal (2 tests), a RF from Jyvaskyla (2 tests with peat/coal) and de-inking sludges co- combusted at full-scale with wood waste or paper mill sludge (4 ashes provided by IVO Power). Ash pellets were thermally treated in nitrogen in order to avoid residual carbon combustion. The results obtained show no sintering tendencies below 600 deg C, significant changes in sintering are seen with pellets treated at 1000 deg C. Ash from 100 % RDF combustion does not sinter, 25 % RDF co-combustion with wood and peat, respectively, gives an insignificant effect. The most severe sintering occurs during co-combustion of RDF with bark. Contrary to the earlier hypothesis a 25 % coal addition seems to have a negative effect on all fuel blends. Analysis of the sintering results versus ash chemical composition shows, that (again), in general, an increased level of alkali chlorides and sulphates gives increased sintering. Finally, some results on sintering tendency measurements on ashes from full-scale CFB co-combustion of deinking sludge with wood waste and paper mill sludge are given. This shows that these ashes show very little, if any, sintering tendency, which can be explained from ash chemistry

LES SOFTWARE FOR THE DESIGN OF LOW EMISSION COMBUSTION SYSTEMS FOR VISION 21 PLANTS

Energy Technology Data Exchange (ETDEWEB)

Clifford E. Smith; Steven M. Cannon; Virgil Adumitroaie; David L. Black; Karl V. Meredith

2005-01-01

In this project, an advanced computational software tool was developed for the design of low emission combustion systems required for Vision 21 clean energy plants. Vision 21 combustion systems, such as combustors for gas turbines, combustors for indirect fired cycles, furnaces and sequestrian-ready combustion systems, will require innovative low emission designs and low development costs if Vision 21 goals are to be realized. The simulation tool will greatly reduce the number of experimental tests; this is especially desirable for gas turbine combustor design since the cost of the high pressure testing is extremely costly. In addition, the software will stimulate new ideas, will provide the capability of assessing and adapting low-emission combustors to alternate fuels, and will greatly reduce the development time cycle of combustion systems. The revolutionary combustion simulation software is able to accurately simulate the highly transient nature of gaseous-fueled (e.g. natural gas, low BTU syngas, hydrogen, biogas etc.) turbulent combustion and assess innovative concepts needed for Vision 21 plants. In addition, the software is capable of analyzing liquid-fueled combustion systems since that capability was developed under a concurrent Air Force Small Business Innovative Research (SBIR) program. The complex physics of the reacting flow field are captured using 3D Large Eddy Simulation (LES) methods, in which large scale transient motion is resolved by time-accurate numerics, while the small scale motion is modeled using advanced subgrid turbulence and chemistry closures. In this way, LES combustion simulations can model many physical aspects that, until now, were impossible to predict with 3D steady-state Reynolds Averaged Navier-Stokes (RANS) analysis, i.e. very low NOx emissions, combustion instability (coupling of unsteady heat and acoustics), lean blowout, flashback, autoignition, etc. LES methods are becoming more and more practical by linking together tens

Fuel and combustion stratification study of Partially Premixed Combustion

NARCIS (Netherlands)

Izadi Najafabadi, M.; Dam, N.; Somers, B.; Johansson, B.

2016-01-01

Relatively high levels of stratification is one of the main advantages of Partially Premixed Combustion (PPC) over the Homogeneous Charge Compression Ignition (HCCI) concept. Fuel stratification smoothens heat release and improves controllability of this kind of combustion. However, the lack of a

Terascale High-Fidelity Simulations of Turbulent Combustion with Detailed Chemistry

Energy Technology Data Exchange (ETDEWEB)

Hong G. Im; Arnaud Trouve; Christopher J. Rutland; Jacqueline H. Chen

2009-02-02

The TSTC project is a multi-university collaborative effort to develop a high-fidelity turbulent reacting flow simulation capability utilizing terascale, massively parallel computer technology. The main paradigm of our approach is direct numerical simulation (DNS) featuring highest temporal and spatial accuracy, allowing quantitative observations of the fine-scale physics found in turbulent reacting flows as well as providing a useful tool for development of sub-models needed in device-level simulations. The code named S3D, developed and shared with Chen and coworkers at Sandia National Laboratories, has been enhanced with new numerical algorithms and physical models to provide predictive capabilities for spray dynamics, combustion, and pollutant formation processes in turbulent combustion. Major accomplishments include improved characteristic boundary conditions, fundamental studies of auto-ignition in turbulent stratified reactant mixtures, flame-wall interaction, and turbulent flame extinction by water spray. The overarching scientific issue in our recent investigations is to characterize criticality phenomena (ignition/extinction) in turbulent combustion, thereby developing unified criteria to identify ignition and extinction conditions. The computational development under TSTC has enabled the recent large-scale 3D turbulent combustion simulations conducted at Sandia National Laboratories.

Terascale High-Fidelity Simulations of Turbulent Combustion with Detailed Chemistry

Energy Technology Data Exchange (ETDEWEB)

Im, Hong G [University of Michigan; Trouve, Arnaud [University of Maryland; Rutland, Christopher J [University of Wisconsin; Chen, Jacqueline H [Sandia National Laboratories

2012-08-13

The TSTC project is a multi-university collaborative effort to develop a high-fidelity turbulent reacting flow simulation capability utilizing terascale, massively parallel computer technology. The main paradigm of our approach is direct numerical simulation (DNS) featuring highest temporal and spatial accuracy, allowing quantitative observations of the fine-scale physics found in turbulent reacting flows as well as providing a useful tool for development of sub-models needed in device-level simulations. The code named S3D, developed and shared with Chen and coworkers at Sandia National Laboratories, has been enhanced with new numerical algorithms and physical models to provide predictive capabilities for spray dynamics, combustion, and pollutant formation processes in turbulent combustion. Major accomplishments include improved characteristic boundary conditions, fundamental studies of auto-ignition in turbulent stratified reactant mixtures, flame-wall interaction, and turbulent flame extinction by water spray. The overarching scientific issue in our recent investigations is to characterize criticality phenomena (ignition/extinction) in turbulent combustion, thereby developing unified criteria to identify ignition and extinction conditions. The computational development under TSTC has enabled the recent large-scale 3D turbulent combustion simulations conducted at Sandia National Laboratories.

Maximal combustion temperature estimation

International Nuclear Information System (INIS)

Golodova, E; Shchepakina, E

2006-01-01

This work is concerned with the phenomenon of delayed loss of stability and the estimation of the maximal temperature of safe combustion. Using the qualitative theory of singular perturbations and canard techniques we determine the maximal temperature on the trajectories located in the transition region between the slow combustion regime and the explosive one. This approach is used to estimate the maximal temperature of safe combustion in multi-phase combustion models

Effect of Variant End of Injection Period on Combustion Process of Biodiesel Combustion

Directory of Open Access Journals (Sweden)

Khalid Amir

2016-01-01

Full Text Available Biodiesel is an alternative fuel as a replacement to the standard diesel fuel in combustion diesel engine. The biodiesel fuel has a significantly influences throughout the combustion process and exhaust emission. The purpose of this research is to investigate the combustion process behavior during the End of Injection (EOI period and operates under variant conditions using Rapid Compression Machine (RCM. Experimental of RCM is used to simulate a combustion process and combustion characteristics of diesel engine combustion. Three types of biodiesel blend which are B5, B10 and B15 were tested at several injection pressures of 80 MPa, 90 MPa and 130 MPa under different ambient temperatures, 750 K to 1100 K. The results of this study showed that the ignition delay slightly reduced with increasing the content of biodiesel blends from B5, B10 and B15 and became more shorten as the injection pressure been enhanced. As the injection pressure increased, the behavior of combustion pressure at end of injection is reduced, radically increased the NOX emission. It is noted that the process of combustion at the end of injection increased as the ambient temperature is rising. In fact, higher initial ambient temperature improved the fuel atomization and mixing process. Under the biodiesel combustion with higher ambient temperature condition, the exhaust emission of CO, O2, and HC became less but increased in NOX emission. Besides, increased in blends of biodiesel ratio are found to enhance the combustion process, resulted a decreased in HC emissions.

International evaluation of the programme on fluid bed combustion and gasification

Energy Technology Data Exchange (ETDEWEB)

Kremer, H. [Ruhr Univ., Bochum (Germany); Magnusson, B.F. [Norwegian Univ. of Science and Technology, Trondheim (Norway); Reed, T. [Colorado School of Mines (United States)

1996-12-31

This report on the Swedish National Program on Fluid Bed Combustion and Gasification is part of the on-going evaluation process adopted by the funding organization NUTEK. This agency has invited the undersigned to act as members of an international panel responsible for evaluating the progress made in 9 projects initiated between 1993-1996. The output of this evaluation procedure is given in this report. The main aim of the Fluid Bed Combustion and Gasification Program is to develop industrially relevant knowledge and competence in experimental and computational techniques capable of characterizing the flow, heat transfer, combustion, gasification, ash formation and deposition and emissions in fluid bed gasifiers and combustors. To achieve this aim NUTEK is sponsoring research in a number of universities and encourages close cooperation between universities and industry. In the evaluation of the various sponsored research programs, the evaluation committee has considered the following key points: relevance of research to industrial needs; originality of research; program management; adequacy of resources; degree of collaboration between industry and academia; international standing of research. In this report comments and recommendations are made on individual projects as well as on the programme in general and they express the unanimous view of the panel members

International evaluation of the programme on fluid bed combustion and gasification

Energy Technology Data Exchange (ETDEWEB)

Kremer, H [Ruhr Univ., Bochum (Germany); Magnusson, B F [Norwegian Univ. of Science and Technology, Trondheim (Norway); Reed, T [Colorado School of Mines (United States)

1997-12-31

This report on the Swedish National Program on Fluid Bed Combustion and Gasification is part of the on-going evaluation process adopted by the funding organization NUTEK. This agency has invited the undersigned to act as members of an international panel responsible for evaluating the progress made in 9 projects initiated between 1993-1996. The output of this evaluation procedure is given in this report. The main aim of the Fluid Bed Combustion and Gasification Program is to develop industrially relevant knowledge and competence in experimental and computational techniques capable of characterizing the flow, heat transfer, combustion, gasification, ash formation and deposition and emissions in fluid bed gasifiers and combustors. To achieve this aim NUTEK is sponsoring research in a number of universities and encourages close cooperation between universities and industry. In the evaluation of the various sponsored research programs, the evaluation committee has considered the following key points: relevance of research to industrial needs; originality of research; program management; adequacy of resources; degree of collaboration between industry and academia; international standing of research. In this report comments and recommendations are made on individual projects as well as on the programme in general and they express the unanimous view of the panel members

Jet plume injection and combustion system for internal combustion engines

Science.gov (United States)

Oppenheim, Antoni K.; Maxson, James A.; Hensinger, David M.

1993-01-01

An improved combustion system for an internal combustion engine is disclosed wherein a rich air/fuel mixture is furnished at high pressure to one or more jet plume generator cavities adjacent to a cylinder and then injected through one or more orifices from the cavities into the head space of the cylinder to form one or more turbulent jet plumes in the head space of the cylinder prior to ignition of the rich air/fuel mixture in the cavity of the jet plume generator. The portion of the rich air/fuel mixture remaining in the cavity of the generator is then ignited to provide a secondary jet, comprising incomplete combustion products which are injected into the cylinder to initiate combustion in the already formed turbulent jet plume. Formation of the turbulent jet plume in the head space of the cylinder prior to ignition has been found to yield a higher maximum combustion pressure in the cylinder, as well as shortening the time period to attain such a maximum pressure.

Path planning during combustion mode switch

Science.gov (United States)

Jiang, Li; Ravi, Nikhil

2015-12-29

Systems and methods are provided for transitioning between a first combustion mode and a second combustion mode in an internal combustion engine. A current operating point of the engine is identified and a target operating point for the internal combustion engine in the second combustion mode is also determined. A predefined optimized transition operating point is selected from memory. While operating in the first combustion mode, one or more engine actuator settings are adjusted to cause the operating point of the internal combustion engine to approach the selected optimized transition operating point. When the engine is operating at the selected optimized transition operating point, the combustion mode is switched from the first combustion mode to the second combustion mode. While operating in the second combustion mode, one or more engine actuator settings are adjusted to cause the operating point of the internal combustion to approach the target operating point.

Fiscal 1997 international cooperation project. Report on the results of the research on environmental harmony type combustion technology; 1997 nendo kokusai kenkyu kyoryoku jigyo. Kankyo chowagata nensho gijutsu ni kansuru kenkyu kaihatsu seika hokokusho

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-03-01

Out of the R and D on the environmental harmony type combustion technology, the results of the project carried out in fiscal 1997 were summed up. In the site survey, etc., visits were paid to France, Spain, Greek, Germany, the U.K. and the U.S. to have discussions and examine the trend of research on the NOx removal catalyst and catalyst combustion. In the actual R and D, the R and D were conducted on zeolite base NOx removal catalyst, oxide composite base NOx removal catalyst, alumina base NOx removal catalyst, direct decomposition type NOx removal catalyst, catalyst combustion, etc. In the R and D of the catalyst combustion, durability under high gas flow flux was examined of PdO-Pt/Ba-Al203 catalyst developed for low temperature use, which indicated that durability and low temperature activity were heightened. As high temperature use catalyst, high temperature durability was examined of the developed Pd0-La/Gd-ZrO2 catalyst, which showed that the durability was favorable. 322 refs., 261 figs., 55 tabs.

Oxyfuel combustion for below zero CO{sub 2} emissions

Energy Technology Data Exchange (ETDEWEB)

Boeg Toftegaard, M; Hansen, Kim G; Fisker, D [DONG Energy Power, Hvidovre (Denmark); Brix, J; Brun Hansen, B; Putluru, S S.R.; Jensen, Peter Arendt; Glarborg, Peter; Degn Jensen, A [Technical Univ. of Denmark. CHEC Research Centre, Kgs. Lyngby (Denmark); Montgomery, M [Technical Univ. of Denmark. DTU Mechanical Engineering, Kgs. Lyngby (Denmark)

2011-07-01

The reduction of CO{sub 2} emissions is of highest concern in relation to limiting the anthropogenic impacts on the environment. Primary focus has gathered on the large point sources of CO{sub 2} emissions constituted by large heat and power stations and other heavy, energy-consuming industry. Solutions are sought which will enable a significant reduction of the anthropogenic CO{sub 2} emissions during the transformation period from the use of fossil fuels to renewable sources of energy. Carbon capture and storage (CCS) has the potential to significantly reduce CO{sub 2} emissions from power stations while allowing for the continuous utilisation of the existing energy producing system in the transformation period. Oxyfuel combustion is one of the possible CCS technologies which show promising perspectives for implementation in industrial scale within a relatively short period of time. Oxyfuel combustion deviates from conventional combustion in air by using a mixture of pure oxygen and recirculated flue gas as the combustion medium thereby creating a flue gas highly concentrated in CO{sub 2} making the capture process economically more feasible compared to technologies with capture from more dilute CO{sub 2} streams. This project has investigated a number of the fundamental and practical issues of the oxyfuel combustion process by experimental, theoretical, and modelling investigations in order to improve the knowledge of the technology. The subjects investigated cover: general combustion characteristics of coal and biomass (straw) and mixtures thereof, formation and emission of pollutants, ash characteristics, flue gas cleaning for SO{sub 2} by wet scrubbing with limestone and for NO{sub x} by selective catalytic reduction (SCR), corrosion of boiler heat transfer surfaces, operation and control of large suspension-fired boilers, and the perspectives for the implementation of oxyfuel combustion s a CO{sub 2} sequestration solution in the Danish power production

Combustion, detonation, shock waves. Proceedings of the Zel'dovich memorial - International conference on combustion. Volume 1

International Nuclear Information System (INIS)

Merzhanov, A.G.; Frolov, S.M.

1995-01-01

This book contains lectures by the experts in various fields of modern research in combustion, detonation and shock waves, presented at the Zel'dovich memorial - International conference on combustion dedicated to the 80-th birthday of academician Ya.B. Zel'dovich. There are eight chapters discussing the state-of-the-art in combustion kinetics, ignition and steady-state flame propagation, diffusion and heterogeneous combustion, turbulent combustion, unsteady combustion, detonation, combustion and detonation analogies, intense shock waves and extreme states of matter [ru

Fuels and Combustion

KAUST Repository

Johansson, Bengt

2016-08-17

This chapter discusses the combustion processes and the link to the fuel properties that are suitable for them. It describes the basic three concepts, including spark ignition (SI) and compression ignition (CI), and homogeneous charge compression ignition (HCCI). The fuel used in a CI engine is vastly different from that in an SI engine. In an SI engine, the fuel should sustain high pressure and temperature without autoignition. Apart from the dominating SI and CI engines, it is also possible to operate with a type of combustion: autoignition. With HCCI, the fuel and air are fully premixed before combustion as in the SI engine, but combustion is started by the increased pressure and temperature during the compression stroke. Apart from the three combustion processes, there are also a few combined or intermediate concepts, such as Spark-Assisted Compression Ignition (SACI). Those concepts are discussed in terms of the requirements of fuel properties.

Fuels and Combustion

KAUST Repository

Johansson, Bengt

2016-01-01

This chapter discusses the combustion processes and the link to the fuel properties that are suitable for them. It describes the basic three concepts, including spark ignition (SI) and compression ignition (CI), and homogeneous charge compression ignition (HCCI). The fuel used in a CI engine is vastly different from that in an SI engine. In an SI engine, the fuel should sustain high pressure and temperature without autoignition. Apart from the dominating SI and CI engines, it is also possible to operate with a type of combustion: autoignition. With HCCI, the fuel and air are fully premixed before combustion as in the SI engine, but combustion is started by the increased pressure and temperature during the compression stroke. Apart from the three combustion processes, there are also a few combined or intermediate concepts, such as Spark-Assisted Compression Ignition (SACI). Those concepts are discussed in terms of the requirements of fuel properties.

FUNDAMENTAL INVESTIGATION OF FUEL TRANSFORMATIONS IN PULVERIZED COAL COMBUSTION AND GASIFICATION TECHNOLOGIES

Energy Technology Data Exchange (ETDEWEB)

Robert Hurt; Joseph Calo; Thomas H. Fletcher; Alan Sayre

2005-04-29

The goal of this project was to carry out the necessary experiments and analyses to extend current capabilities for modeling fuel transformations to the new conditions anticipated in next-generation coal-based, fuel-flexible combustion and gasification processes. This multi-organization, multi-investigator project has produced data, correlations, and submodels that extend present capabilities in pressure, temperature, and fuel type. The combined experimental and theoretical/computational results are documented in detail in Chapters 1-8 of this report, with Chapter 9 serving as a brief summary of the main conclusions. Chapters 1-3 deal with the effect of elevated pressure on devolatilization, char formation, and char properties. Chapters 4 and 5 deal with advanced combustion kinetic models needed to cover the extended ranges of pressure and temperature expected in next-generation furnaces. Chapter 6 deals with the extension of kinetic data to a variety of alternative solid fuels. Chapter 7 focuses on the kinetics of gasification (rather than combustion) at elevated pressure. Finally, Chapter 8 describes the integration, testing, and use of new fuel transformation submodels into a comprehensive CFD framework. Overall, the effects of elevated pressure, temperature, heating rate, and alternative fuel use are all complex and much more work could be further undertaken in this area. Nevertheless, the current project with its new data, correlations, and computer models provides a much improved basis for model-based design of next generation systems operating under these new conditions.

Lump wood combustion process

Science.gov (United States)

Kubesa, Petr; Horák, Jiří; Branc, Michal; Krpec, Kamil; Hopan, František; Koloničný, Jan; Ochodek, Tadeáš; Drastichová, Vendula; Martiník, Lubomír; Malcho, Milan

2014-08-01

The article deals with the combustion process for lump wood in low-power fireplaces (units to dozens of kW). Such a combustion process is cyclical in its nature, and what combustion facility users are most interested in is the frequency, at which fuel needs to be stoked to the fireplace. The paper defines the basic terms such as burnout curve and burning rate curve, which are closely related to the stocking frequency. The fuel burning rate is directly dependent on the immediate thermal power of the fireplace. This is also related to the temperature achieved in the fireplace, magnitude of flue gas losses and the ability to generate conditions favouring the full burnout of the fuel's combustible component, which, at once ensures the minimum production of combustible pollutants. Another part of the paper describes experiments conducted in traditional fireplaces with a grate, at which well-dried lump wood was combusted.

Combustion Research Laboratory

Data.gov (United States)

Federal Laboratory Consortium — The Combustion Research Laboratory facilitates the development of new combustion systems or improves the operation of existing systems to meet the Army's mission for...

Combustion chemistry and formation of pollutants; Chimie de la combustion et formation des polluants

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-12-31

This book of proceedings reports on 7 papers on combustion chemistry and formation of pollutants presented during the workshop organized by the `Combustion and Flames` section of the French society of thermal engineers. The chemistry of combustion is analyzed in various situations such as: turbojet engines, spark ignition engines, industrial burners, gas turbines etc... Numerical simulation is used to understand the physico-chemical processes involved in combustion, to describe the kinetics of oxidation, combustion and flame propagation, and to predict the formation of pollutants. (J.S.)

Chemical Processes Related to Combustion in Fluidised Bed

Energy Technology Data Exchange (ETDEWEB)

Steenari, Britt-Marie; Lindqvist, Oliver [Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Environmental Inorganic Chemistry

2002-12-01

This report covers work that has been carried out in the combustion chemistry group at the Dept. of Environmental Inorganic Chemistry, Chalmers, within the STEM project 12859-1, during the period 2000-07-01 to 2002-06-30. The work was comprised of the following parts: Sulphur chemistry under pressurised and atmospheric conditions; Gas/solid reactions related to sintering and fouling; Chemistry of volatile metals in combustion; Ash leaching properties; Theoretical modelling of the interactions between ions in a solution and mineral surfaces; Some related issues and co-operations with other departments. The work on sulphur chemistry has been a central issue in our group and it has now been finalised with a PhD thesis discussing some aspects of the sulphation of limestone under pressurised conditions. The influence of a number of parameters on the sulphation efficiency was investigated and compared with similar studies under atmospheric conditions. In a special study it was shown that the influence of alternating calcining - non-calcining conditions on the conversion was substantial. In addition, the oxidation of CaS and sulphided limestone was studied and a regeneration method for the sulphide sorbent was proposed. In the project part concerning gas - solid reactions that are relevant to sintering and fouling, the application of an on-line measurement technique for the study of alkali metal capture by kaolin or other sorbents is described. A new reactor set-up has been constructed and the initial results from this set up are promising. The chemistry of cadmium in combustion of MSW and biomass is the object of a PhD project. This work has been concentrated on the task of identifying Cd-compounds in fly ash samples. It has now come to a point where enough data has been collected to make it possible to give an indication about the Cd speciation in some ash types. In MSW ash particles, cadmium seem to occur mainly as chloride, oxide and sulphate. The work will continue

Heavy metals behaviour during mono-combustion and co-combustion of sewage sludge

Energy Technology Data Exchange (ETDEWEB)

Lopes, M. Helena; Abelha, Pedro; Olieveira, J.F. Santos; Gulyurtlu, Ibrahim; Cabrita, Isabel [INETI-DEECA, Lisboa (Portugal)

2005-03-01

This paper presents the study of the combustion of granular dry sewage sludge performed on a pilot fluidized bed system. The results of mono-combustion of sludge and co-combustion with coal were compared with those of coal combustion for ash partitioning, the formation of gaseous pollutants and heavy metals behaviour. It was found that the mineral matter of sludge was essentially retained as bottom ashes. The production of fines ashes was small during the mono-combustion due to the tendency of coal to produce fine ashes which also contained unburned char. The degree of heavy metal volatilization was found to be slightly higher during co-combustion than in mono-combustion; however, most of them were retained in ashes and their emissions were found to be below the regulated levels. Hg was completely volatilized; however, during combustion trials involving coal it was captured by cyclone ashes at temperatures below 300 deg C. During sludge mono-combustion the retention of Hg in cyclone ashes containing low LOI was not enough to decrease emissions below the regulated levels; hence, it is necessary to install dedicated flue gas treatment for Hg removal. The leachability and ecotoxicity of sludge and ashes was compared with the new regulatory limits for landfill disposal in the EU. It was found that the release of organic matter and heavy metals found in the sludge was low from granular bed ashes; hence, except for sulphate release, bed ashes were converted into inert and non-ecotoxic materials. Ashes from test with limestone and cyclone ashes seemed to be more problematic because of pH effects and contamination with steel corrosion products. The recovery and reutilization of sludge bed ashes could, therefore, be possible, as long as the release of sulphate do not interfere with the process.

Twenty-fifth symposium (international) on combustion

International Nuclear Information System (INIS)

Anon.

1994-01-01

Approximately two-thirds of the papers presented at this conference are contained in this volume. The other one-third appear in special issues of ''Combustion and Flame'', Vol. 99, 1994 and Vol. 100, 1995. Papers are divided into the following sections: Supersonic combustion; Detonations and explosions; Internal combustion engines; Practical aspects of combustion; Incineration and wastes; Sprays and droplet combustion; Coal and organic solids combustion; Soot and polycyclic aromatic hydrocarbons; Reaction kinetics; NO x ; Turbulent flames; Turbulent combustion; Laminar flames; Flame spread, fire and halogenated fire suppressants; Global environmental effects; Ignition; Two-phase combustion; Solid propellant combustion; Materials synthesis; Microgravity; and Experimental diagnostics. Papers have been processed separately for inclusion on the data base

LES and RANS modeling of pulverized coal combustion in swirl burner for air and oxy-combustion technologies

International Nuclear Information System (INIS)

Warzecha, Piotr; Boguslawski, Andrzej

2014-01-01

Combustion of pulverized coal in oxy-combustion technology is one of the effective ways to reduce the emission of greenhouse gases into the atmosphere. The process of transition from conventional combustion in air to the oxy-combustion technology, however, requires a thorough investigations of the phenomena occurring during the combustion process, that can be greatly supported by numerical modeling. The paper presents the results of numerical simulations of pulverized coal combustion process in swirl burner using RANS (Reynolds-averaged Navier–Stokes equations) and LES (large Eddy simulation) methods for turbulent flow. Numerical simulations have been performed for the oxyfuel test facility located at the Institute of Heat and Mass Transfer at RWTH Aachen University. Detailed analysis of the flow field inside the combustion chamber for cold flow and for the flow with combustion using different numerical methods for turbulent flows have been done. Comparison of the air and oxy-coal combustion process for pulverized coal shows significant differences in temperature, especially close to the burner exit. Additionally the influence of the combustion model on the results has been shown for oxy-combustion test case. - Highlights: • Oxy-coal combustion has been modeled for test facility operating at low oxygen ratio. • Coal combustion process has been modeled with simplified combustion models. • Comparison of oxy and air combustion process of pulverized coal has been done. • RANS (Reynolds-averaged Navier–Stokes equations) and LES (large Eddy simulation) results for pulverized coal combustion process have been compared

Building America Case Study: Combustion Safety Simplified Test Protocol, Chicago Illinois, and Minneapolis, Minnesota

Energy Technology Data Exchange (ETDEWEB)

2015-12-01

"9Combustion safety is an important step in the process of upgrading homes for energy efficiency. There are several approaches used by field practitioners, but researchers have indicated that the test procedures in use are complex to implement and provide too many false positives. Field failures often mean that the house is not upgraded until after remediation or not at all, if not include in the program. In this report the PARR and NorthernSTAR DOE Building America Teams provide a simplified test procedure that is easier to implement and should produce fewer false positives. A survey of state weatherization agencies on combustion safety issues, details of a field data collection instrumentation package, summary of data collected over seven months, data analysis and results are included. The project provides several key results. State weatherization agencies do not generally track combustion safety failures, the data from those that do suggest that there is little actual evidence that combustion safety failures due to spillage from non-dryer exhaust are common and that only a very small number of homes are subject to the failures. The project team collected field data on 11 houses in 2015. Of these homes, two houses that demonstrated prolonged and excessive spillage were also the only two with venting systems out of compliance with the National Fuel Gas Code. The remaining homes experienced spillage that only occasionally extended beyond the first minute of operation. Combustion zone depressurization, outdoor temperature, and operation of individual fans all provide statistically significant predictors of spillage.

High Frequency Combustion Instabilities of LOx/CH4 Spray Flames in Rocket Engine Combustion Chambers

NARCIS (Netherlands)

Sliphorst, M.

2011-01-01

Ever since the early stages of space transportation in the 1940’s, and the related liquid propellant rocket engine development, combustion instability has been a major issue. High frequency combustion instability (HFCI) is the interaction between combustion and the acoustic field in the combustion

Decrease of noxious emissions in the residual fuel oil combustion; Disminucion de emisiones nocivas en la combustion de aceite combustible residual

Energy Technology Data Exchange (ETDEWEB)

Mandoki W, Jorge [Econergia S. de R. L. de C. V. Mexico, D. F. (Mexico)

1994-12-31

The residual fuel oil combustion emits noxious substances such as carbonaceous particulate, nitrogen oxides, and sulfur trioxide at unacceptable levels. Water emulsified in the fuel substantially reduces such emissions, achieving besides, in most of the cases, a net saving in the fuel consumption. The beneficial effects are shown in burning the residual fuel oil as a water emulsion, as well as the method to produce an adequate emulsion. The emulsified fuel technology offers a low cost option to reduce air pollution. The fuel oil quality has been declining during the last decades due to: 1. Increase in the production of crude heavy oils, generally with higher content of asphaltens and sulfur. 2. Less availability of vacuum distillation residues due to its conversion into greater value products. 3. More intensive conversion processes such as catalytic cracking, visbreaking, etc. that increase the asphaltenes concentration in the bottoms, causing instability problems. 4. The increase in the vanadium and other metals content as the concentration of asphaltenes increases. The use of emulsified fuel oil provides an efficient and economical method to substantially reduce the noxious emissions to the atmosphere. The emulsion contains water particles in a diameter between 2 and 20 microns, uniformly distributed in the fuel oil, generally in a proportion generally of 5 to 10%; besides, it contains a tensioactive agent to assure a stable emulsion capable of withstanding the shearing forces of the pumping and distribution systems. When the atomized oil drops get into the combustion chamber, the emulsified water flashes into high pressure steam, originating a violent secondary atomization. The effect of this secondary atomization is the rupture of the oil drops of various hundred microns, producing drops of 5 to 15 microns in diameter. Since the necessary time for combustion is an exponential function of the drop diameter, a very substantial improvement in the combustion is

Combustion Research Facility

Data.gov (United States)

Federal Laboratory Consortium — For more than 30 years The Combustion Research Facility (CRF) has served as a national and international leader in combustion science and technology. The need for a...

Method and apparatus for active control of combustion rate through modulation of heat transfer from the combustion chamber wall

Science.gov (United States)

Roberts, Jr., Charles E.; Chadwell, Christopher J.

2004-09-21

The flame propagation rate resulting from a combustion event in the combustion chamber of an internal combustion engine is controlled by modulation of the heat transfer from the combustion flame to the combustion chamber walls. In one embodiment, heat transfer from the combustion flame to the combustion chamber walls is mechanically modulated by a movable member that is inserted into, or withdrawn from, the combustion chamber thereby changing the shape of the combustion chamber and the combustion chamber wall surface area. In another embodiment, heat transfer from the combustion flame to the combustion chamber walls is modulated by cooling the surface of a portion of the combustion chamber wall that is in close proximity to the area of the combustion chamber where flame speed control is desired.

Fuel Combustion Laboratory | Transportation Research | NREL

Science.gov (United States)

Fuel Combustion Laboratory Fuel Combustion Laboratory NREL's Fuel Combustion Laboratory focuses on designs, using both today's technology and future advanced combustion concepts. This lab supports the combustion chamber platform for fuel ignition kinetics research, was acquired to expand the lab's

Design and Fabrication of Oxygen/RP-2 Multi-Element Oxidizer-Rich Staged Combustion Thrust Chamber Injectors

Science.gov (United States)

Garcia, C. P.; Medina, C. R.; Protz, C. S.; Kenny, R. J.; Kelly, G. W.; Casiano, M. J.; Hulka, J. R.; Richardson, B. R.

2016-01-01

As part of the Combustion Stability Tool Development project funded by the Air Force Space and Missile Systems Center, the NASA Marshall Space Flight Center was contracted to assemble and hot-fire test a multi-element integrated test article demonstrating combustion characteristics of an oxygen/hydrocarbon propellant oxidizer-rich staged-combustion engine thrust chamber. Such a test article simulates flow through the main injectors of oxygen/kerosene oxidizer-rich staged combustion engines such as the Russian RD-180 or NK-33 engines, or future U.S.-built engine systems such as the Aerojet-Rocketdyne AR-1 engine or the Hydrocarbon Boost program demonstration engine. On the current project, several configurations of new main injectors were considered for the thrust chamber assembly of the integrated test article. All the injector elements were of the gas-centered swirl coaxial type, similar to those used on the Russian oxidizer-rich staged-combustion rocket engines. In such elements, oxidizer-rich combustion products from the preburner/turbine exhaust flow through a straight tube, and fuel exiting from the combustion chamber and nozzle regenerative cooling circuits is injected near the exit of the oxidizer tube through tangentially oriented orifices that impart a swirl motion such that the fuel flows along the wall of the oxidizer tube in a thin film. In some elements there is an orifice at the inlet to the oxidizer tube, and in some elements there is a sleeve or "shield" inside the oxidizer tube where the fuel enters. In the current project, several variations of element geometries were created, including element size (i.e., number of elements or pattern density), the distance from the exit of the sleeve to the injector face, the width of the gap between the oxidizer tube inner wall and the outer wall of the sleeve, and excluding the sleeve entirely. This paper discusses the design rationale for each of these element variations, including hydraulic, structural

Investigation of reactions and species dominating low temperature combustion - Final report

Energy Technology Data Exchange (ETDEWEB)

Radi, P.; Knopp, G.; Johnson, M.; Boedi, A.; Gerber, T.

2009-12-15

This report for the Swiss Federal Office of Energy (SFOE) presents the results of work done at the Paul Scherrer Institute (PSI) in Switzerland. The project 'Investigation of reactions and species dominating low temperature combustion' involves the characterisation of species that govern ignition. A base established for the spectroscopic investigation of peroxy radicals is discussed. The two-fold aim of this project is discussed which includes the measurement of molecular features such as binding energies and dissociation patterns of well-studied and spectroscopically accessible molecules and radicals as well as the application of the measurement techniques to alkyl peroxy radicals. This was done in order to improve the database of a class of molecules playing a dominant role in combustion and atmospheric chemistry. Several experimental techniques that are to be developed to achieve these aims are looked at. Achievements made are discussed and future work to be carried out is noted.

COMBUSTION SIMULATION IN A SPARK IGNITION ENGINE CYLINDER: EFFECTS OF AIR-FUEL RATIO ON THE COMBUSTION DURATION

Directory of Open Access Journals (Sweden)

Nureddin Dinler

2010-01-01

Full Text Available Combustion is an important subject of internal combustion engine studies. To reduce the air pollution from internal combustion engines and to increase the engine performance, it is required to increase combustion efficiency. In this study, effects of air/fuel ratio were investigated numerically. An axisymmetrical internal combustion engine was modeled in order to simulate in-cylinder engine flow and combustion. Two dimensional transient continuity, momentum, turbulence, energy, and combustion equations were solved. The k-e turbulence model was employed. The fuel mass fraction transport equation was used for modeling of the combustion. For this purpose a computational fluid dynamics code was developed by using the finite volume method with FORTRAN programming code. The moving mesh was utilized to simulate the piston motion. The developed code simulates four strokes of engine continuously. In the case of laminar flow combustion, Arrhenius type combustion equations were employed. In the case of turbulent flow combustion, eddy break-up model was employed. Results were given for rich, stoichiometric, and lean mixtures in contour graphs. Contour graphs showed that lean mixture (l = 1.1 has longer combustion duration.

Integral large scale experiments on hydrogen combustion for severe accident code validation-HYCOM

International Nuclear Information System (INIS)

Breitung, W.; Dorofeev, S.; Kotchourko, A.; Redlinger, R.; Scholtyssek, W.; Bentaib, A.; L'Heriteau, J.-P.; Pailhories, P.; Eyink, J.; Movahed, M.; Petzold, K.-G.; Heitsch, M.; Alekseev, V.; Denkevits, A.; Kuznetsov, M.; Efimenko, A.; Okun, M.V.; Huld, T.; Baraldi, D.

2005-01-01

A joint research project was carried out in the EU Fifth Framework Programme, concerning hydrogen risk in a nuclear power plant. The goals were: Firstly, to create a new data base of results on hydrogen combustion experiments in the slow to turbulent combustion regimes. Secondly, to validate the partners CFD and lumped parameter codes on the experimental data, and to evaluate suitable parameter sets for application calculations. Thirdly, to conduct a benchmark exercise by applying the codes to the full scale analysis of a postulated hydrogen combustion scenario in a light water reactor containment after a core melt accident. The paper describes the work programme of the project and the partners activities. Significant progress has been made in the experimental area, where test series in medium and large scale facilities have been carried out with the focus on specific effects of scale, multi-compartent geometry, heat losses and venting. The data were used for the validation of the partners CFD and lumped parameter codes, which included blind predictive calculations and pre- and post-test intercomparison exercises. Finally, a benchmark exercise was conducted by applying the codes to the full scale analysis of a hydrogen combustion scenario. The comparison and assessment of the results of the validation phase and of the challenging containment calculation exercise allows a deep insight in the quality, capabilities and limits of the CFD and the lumped parameter tools which are currently in use at various research laboratories

The Evaluation of Solid Wastes Reduction with Combustion System in the Combustion Chamber

International Nuclear Information System (INIS)

Prayitno; Sukosrono

2007-01-01

The evaluation of solid wastes reduction with combustion system is used for weight reduction factor. The evaluation was done design system of combustion chamber furnace and the experiment was done by burning a certain weight of paper, cloth, plastic and rubber in the combustion chamber. The evaluation of paper wastes, the ratio of wastes (paper, cloth, plastic and rubber) against the factor of weight reduction (%) were investigated. The condition was dimension of combustion chamber furnace = 0.6 X 0.9 X 1.20 X 1 m with combustion chamber and gas chamber and reached at the wastes = 2.500 gram, oxygen pressure 0.5 Bar, wastes ratio : paper : cloth : plastic : rubber = 55 : 10 : 30 : 5, the reduction factor = 6.36 %. (author)

Regional probability distribution of the annual reference evapotranspiration and its effective parameters in Iran

Science.gov (United States)

Khanmohammadi, Neda; Rezaie, Hossein; Montaseri, Majid; Behmanesh, Javad

2017-10-01

The reference evapotranspiration (ET0) plays an important role in water management plans in arid or semi-arid countries such as Iran. For this reason, the regional analysis of this parameter is important. But, ET0 process is affected by several meteorological parameters such as wind speed, solar radiation, temperature and relative humidity. Therefore, the effect of distribution type of effective meteorological variables on ET0 distribution was analyzed. For this purpose, the regional probability distribution of the annual ET0 and its effective parameters were selected. Used data in this research was recorded data at 30 synoptic stations of Iran during 1960-2014. Using the probability plot correlation coefficient (PPCC) test and the L-moment method, five common distributions were compared and the best distribution was selected. The results of PPCC test and L-moment diagram indicated that the Pearson type III distribution was the best probability distribution for fitting annual ET0 and its four effective parameters. The results of RMSE showed that the ability of the PPCC test and L-moment method for regional analysis of reference evapotranspiration and its effective parameters was similar. The results also showed that the distribution type of the parameters which affected ET0 values can affect the distribution of reference evapotranspiration.

Plasma position and current control system enhancements for the JET ITER-like wall

Energy Technology Data Exchange (ETDEWEB)

De Tommasi, G. [Associazione EURATOM-ENEA-CREATE, Univ. di Napoli Federico II, Via Claudio 21, 80125 Napoli (Italy); Maviglia, F. [Associazione EURATOM-ENEA-CREATE, Via Claudio 21, 80125 Napoli (Italy); Neto, A.C. [Ass. EURATOM-IST, Instituto de Plasmas e Fusão Nuclear, IST, 1049-001 Lisboa (Portugal); Lomas, P.J.; McCullen, P.; Rimini, F.G. [Euratom-CCFE, Culham Science Centre, OX14 3DB Abingdon (United Kingdom)

2014-03-15

Highlights: • JET plasma position and current control system enhanced for the JET ITER like wall. • Vertical stabilization system enhanced to speed up its response and to withstand larger perturbations. • Improved termination management system. • Implementation of the current limit avoidance system. • Implementation of PFX-on-early-task. - Abstract: The upgrade of Joint European Torus (JET) to a new all-metal wall, the so-called ITER-like wall (ILW), has posed a set of new challenges regarding both machine operation and protection. The plasma position and current control (PPCC) system plays a crucial role in minimizing the possibility that the plasma could permanently damage the ILW. The installation of the ILW has driven a number of upgrades of the two PPCC components, namely the Vertical Stabilization (VS) system and the Shape Controller (SC). The VS system has been enhanced in order to speed up its response and to withstand larger perturbations. The SC upgrade includes three new features: an improved termination management system, the current limit avoidance system, and the PFX-on-early-task. This paper describes the PPCC upgrades listed above, focusing on the implementation issues and on the experimental results achieved during the 2011–12 JET experimental campaigns.

Advanced modeling of oxy-fuel combustion of natural gas

Energy Technology Data Exchange (ETDEWEB)

Chungen Yin

2011-01-15

The main goal of this small-scale project is to investigate oxy-combustion of natural gas (NG) through advanced modeling, in which radiation, chemistry and mixing will be reasonably resolved. 1) A state-of-the-art review was given regarding the latest R and D achievements and status of oxy-fuel technology. The modeling and simulation status and achievements in the field of oxy-fuel combustion were also summarized; 2) A computer code in standard c++, using the exponential wide band model (EWBM) to evaluate the emissivity and absorptivity of any gas mixture at any condition, was developed and validated in detail against data in literature. A new, complete, and accurate WSGGM, applicable to both air-fuel and oxy-fuel combustion modeling and applicable to both gray and non-gray calculation, was successfully derived, by using the validated EWBM code as the reference mode. The new WSGGM was implemented in CFD modeling of two different oxy-fuel furnaces, through which its great, unique advantages over the currently most widely used WSGGM were demonstrated. 3) Chemical equilibrium calculations were performed for oxy-NG flame and air-NG flame, in which dissociation effects were considered to different degrees. Remarkable differences in oxy-fuel and air-fuel combustion were revealed, and main intermediate species that play key roles in oxy-fuel flames were identified. Different combustion mechanisms are compared, e.g., the most widely used 2-step global mechanism, refined 4-step global mechanism, a global mechanism developed for oxy-fuel using detailed chemical kinetic modeling (CHEMKIN) as reference. 4) Over 15 CFD simulations were done for oxy-NG combustion, in which radiation, chemistry, mixing, turbulence-chemistry interactions, and so on were thoroughly investigated. Among all the simulations, RANS combined with 2-step and refined 4-step mechanism, RANS combined with CHEMKIN-based new global mechanism for oxy-fuel modeling, and LES combined with different combustion

Combustion Dynamics and Stability Modeling of a Liquid Oxygen/RP-2 Oxygen-Rich Staged Combustion Preburner and Thrust Chamber Assembly with Gas-Centered Swirl Coaxial Injector Elements

Science.gov (United States)

Casiano, M. J.; Kenny, R. J.; Protz, C. S.; Garcia, C. P.; Simpson, S. P.; Elmore, J. L.; Fischbach, S. R.; Giacomoni, C. B.; Hulka, J. R.

2016-01-01

The Combustion Stability Tool Development (CSTD) project, funded by the Air Force Space and Missile Systems Center, began in March 2015 supporting a renewed interest in the development of a liquid oxygen/hydrocarbon, oxygen-rich combustion engine. The project encompasses the design, assembly, and hot-fire testing of the NASA Marshall Space Flight Center 40-klbf Integrated Test Rig (MITR). The test rig models a staged-combustion configuration by combining an oxygen-rich preburner (ORPB), to generate hot gas, with a thrust chamber assembly (TCA) using gas-centered swirl coaxial injector elements. There are five separately designed interchangeable injectors in the TCA that each contain 19- or 27- injector elements. A companion paper in this JANNAF conference describes the design characteristics, rationale, and fabrication issues for all the injectors. The data acquired from a heavily instrumented rig encompasses several injectors, several operating points, and stability bomb tests. Another companion paper in this JANNAF conference describes this test program in detail. In this paper, dynamic data from the hot-fire testing is characterized and used to identify the responses in the ORPB and TCA. A brief review of damping metrics are discussed and applied as a measure of stability margin for damped acoustic modes. Chug and longitudinal combustion stability models and predictions are described which includes new dynamic models for compressible flow through an orifice and a modification to incorporate a third feed line for inclusion of the fuel-film coolant. Flow-acoustics finite element modeling is used to investigate the anticipated TCA acoustics, the effects of injector element length on stability margin, and the potential use of an ORPB orifice trip ring for improving longitudinal stability margin.

Import of combustible waste and its impact on emissions of climate gases

Energy Technology Data Exchange (ETDEWEB)

Haraldsson, Maarten; Sundberg, Johan (Profu, Moelndal (Sweden))

2010-07-01

Import of combustible waste for waste incineration in Sweden has increased over the last decade and prognosis show that importation will increase even further in the future. The reason for the projected increase is that many new incineration facilities are being built and several of those plan to use a portion of imported combustible waste as fuel. From an environmental perspective import of waste is controversial and some argue that the import short be restricted. Because of this controversial aspect it is essential to conduct a comprehensive analysis of the environmental impacts of the importation of combustible waste to Swedish incineration facilities. This project is a study of the impact of the import of combustible waste on climate emissions. This is a system analysis study which included both direct as well as indirect emissions from the activity of importation of combustible waste. Direct emissions occur from the incineration of waste while indirect emissions occur in systems that interact with the incineration facility. These systems are: transport of waste, alternative waste treatment, alternative electricity production and alternative heat production in the district heating system which the incineration facility is connected with. From the perspective of a system analysis the import of combustible waste to incineration leads to the following consequences regarding emissions of climate gases: - The imported waste is used as fuel in the incineration facility which generates heat and electricity. During the combustion process climate gases are being emitted - As the combustible waste is being imported it has to be transported from the country of origin to the incineration facility. The vehicle used for the transport is emitting climate gases - By importing combustible waste an alternative treatment method in the country of origin is avoided by that country. Emissions from the alternative treatment method are thereby avoided - Import of combustible waste

Summary of Pressure Gain Combustion Research at NASA

Science.gov (United States)

Perkins, H. Douglas; Paxson, Daniel E.

2018-01-01

NASA has undertaken a systematic exploration of many different facets of pressure gain combustion over the last 25 years in an effort to exploit the inherent thermodynamic advantage of pressure gain combustion over the constant pressure combustion process used in most aerospace propulsion systems. Applications as varied as small-scale UAV's, rotorcraft, subsonic transports, hypersonics and launch vehicles have been considered. In addition to studying pressure gain combustor concepts such as wave rotors, pulse detonation engines, pulsejets, and rotating detonation engines, NASA has studied inlets, nozzles, ejectors and turbines which must also process unsteady flow in an integrated propulsion system. Other design considerations such as acoustic signature, combustor material life and heat transfer that are unique to pressure gain combustors have also been addressed in NASA research projects. In addition to a wide range of experimental studies, a number of computer codes, from 0-D up through 3-D, have been developed or modified to specifically address the analysis of unsteady flow fields. Loss models have also been developed and incorporated into these codes that improve the accuracy of performance predictions and decrease computational time. These codes have been validated numerous times across a broad range of operating conditions, and it has been found that once validated for one particular pressure gain combustion configuration, these codes are readily adaptable to the others. All in all, the documentation of this work has encompassed approximately 170 NASA technical reports, conference papers and journal articles to date. These publications are very briefly summarized herein, providing a single point of reference for all of NASA's pressure gain combustion research efforts. This documentation does not include the significant contributions made by NASA research staff to the programs of other agencies, universities, industrial partners and professional society

Dynamics of Water Absorption and Evaporation During Methanol Droplet Combustion in Microgravity

Science.gov (United States)

Hicks, Michael C.; Dietrich, Daniel L.; Nayagam, Vedha; Williams, Forman A.

2012-01-01

The combustion of methanol droplets is profoundly influenced by the absorption and evaporation of water, generated in the gas phase as a part of the combustion products. Initially there is a water-absorption period of combustion during which the latent heat of condensation of water vapor, released into the droplet, enhances its burning rate, whereas later there is a water-evaporation period, during which the water vapor reduces the flame temperature suffciently to extinguish the flame. Recent methanol droplet-combustion experiments in ambient environments diluted with carbon dioxide, conducted in the Combustion Integrated Rack on the International Space Station (ISS), as a part of the FLEX project, provided a method to delineate the water-absorption period from the water-evaporation period using video images of flame intensity. These were obtained using an ultra-violet camera that captures the OH* radical emission at 310 nm wavelength and a color camera that captures visible flame emission. These results are compared with results of ground-based tests in the Zero Gravity Facility at the NASA Glenn Research Center which employed smaller droplets in argon-diluted environments. A simplified theoretical model developed earlier correlates the transition time at which water absorption ends and evaporation starts. The model results are shown to agree reasonably well with experiment.

Pressurized Fluidized Bed Combustion Second-Generation System Research and Development

Energy Technology Data Exchange (ETDEWEB)

A. Robertson; D. Horazak; R. Newby; H. Goldstein

2002-11-01

Research is being conducted under United States Department of Energy (DOE) Contract DE-AC21-86MC21023 to develop a new type of coal-fired plant for electric power generation. This new type of plant--called a Second-Generation or Advanced Pressurized Circulating Fluidized Bed Combustion (APCFB) plant--offers the promise of efficiencies greater than 45% (HHV), with both emissions and a cost of electricity that are significantly lower than conventional pulverized-coal-fired plants with scrubbers. The APCFB plant incorporates the partial gasification of coal in a carbonizer, the combustion of carbonizer char in a pressurized circulating fluidized bed boiler (PCFB), and the combustion of carbonizer syngas in a topping combustor to achieve gas turbine inlet temperatures of 2300 F and higher. A conceptual design was previously prepared for this new type of plant and an economic analysis presented, all based on the use of a Siemens Westinghouse W501F gas turbine with projected carbonizer, PCFB, and topping combustor performance data. Having tested these components at the pilot plant stage, the referenced conceptual design is being updated to reflect more accurate performance predictions together with the use of the more advanced Siemens Westinghouse W501G gas turbine and a conventional 2400 psig/1050 F/1050 F/2-1/2 in. steam turbine. This report describes the updated plant which is projected to have an HHV efficiency of 48% and identifies work completed for the October 2001 through September 2002 time period.

Effects of calcium magnesium acetate on the combustion of coal-water slurries. Final project report, 1 September 1989--28 February 1993

Energy Technology Data Exchange (ETDEWEB)

Levendis, Y.A.; Wise, D.; Metghalchi, H.; Cumper, J.; Atal, A.; Estrada, K.R.; Murphy, B.; Steciak, J.; Hottel, H.C.; Simons, G.

1993-07-01

To conduct studies on the combustion of coal water fuels (CWFs) an appropriate facility was designed and constructed. The main components were (1) a high-temperature isothermal laminar flow furnace that facilitates observation of combustion events in its interior. The design of this system and its characterization are described in Chapter 1. (2) Apparatus for slurry droplet/agglomerate particle generation and introduction in the furnace. These devices are described in Chapters 1 and 3 and other attached publications. (3) An electronic optical pyrometer whose design, construction theory of operation, calibration and performance are presented in Chapter 2. (4) A multitude of other accessories, such as particle fluidization devices, a suction thermometer, a velocimeter, high speed photographic equipment, calibration devices for the pyrometer, etc., are described throughout this report. Results on the combustion of CWF droplets and CWF agglomerates made from micronized coal are described in Chapter 3. In the same chapter the combustion of CWF containing dissolved calcium magnesium acetate (CMA) axe described. The combustion behavior of pre-dried CWF agglomerates of pulverized grain coal is contrasted to that of agglomerates of micronized coal in Chapter 4. In the same chapter the combustion of agglomerates of carbon black and diesel soot is discussed as well. The effect of CMA on the combustion of the above materials is also discussed. Finally, the sulfur capture capability of CMA impregnated micronized and pulverized bituminous coals is examined in Chapter 5.

Biofuels combustion.

Science.gov (United States)

Westbrook, Charles K

2013-01-01

This review describes major features of current research in renewable fuels derived from plants and from fatty acids. Recent and ongoing fundamental studies of biofuel molecular structure, oxidation reactions, and biofuel chemical properties are reviewed, in addition to combustion applications of biofuels in the major types of engines in which biofuels are used. Biofuels and their combustion are compared with combustion features of conventional petroleum-based fuels. Two main classes of biofuels are described, those consisting of small, primarily alcohol, fuels (particularly ethanol, n-butanol, and iso-pentanol) that are used primarily to replace or supplement gasoline and those derived from fatty acids and used primarily to replace or supplement conventional diesel fuels. Research efforts on so-called second- and third-generation biofuels are discussed briefly.

Low emission internal combustion engine

Science.gov (United States)

Karaba, Albert M.

1979-01-01

A low emission, internal combustion compression ignition engine having a cylinder, a piston movable in the cylinder and a pre-combustion chamber communicating with the cylinder near the top thereof and in which low emissions of NO.sub.x are achieved by constructing the pre-combustion chamber to have a volume of between 70% and 85% of the combined pre-chamber and main combustion chamber volume when the piston is at top dead center and by variably controlling the initiation of fuel injection into the pre-combustion chamber.

Visualization research on spray atomization, evaporation and combustion processes of ethanol–diesel blend under LTC conditions

International Nuclear Information System (INIS)

Huang, Sheng; Deng, Peng; Huang, Ronghua; Wang, Zhaowen; Ma, Yinjie; Dai, Hui

2015-01-01

Highlights: • Spray combustion of E20 diesel in LTC condition shows a U-shape flame structure. • The chasing behavior of fuel spray exists near the spray axis. • Fuel ignition doesn’t initiate at the spray tip but in peripheral regions behind it. • An improper chamber structure may lead to a long post-combustion duration. - Abstract: Utilization of ethanol in diesel engines has been widely studied by means of engine experiments and emission detection. However, pertinent studies on the spray combustion process of ethanol–diesel blends are scarce. In order to verify the effect of ethanol in modern diesel engines, an experiment is conducted to visualize the spray combustion process of ethanol–diesel blend under LTC conditions. Stages including atomization, evaporation and combustion, are investigated individually to realize synergistic analysis. Meanwhile, considering the long time scale of combustion after fuel injection finishes, characteristics during and after injection period are both targeted in this paper. Moreover, measurement of macroscopic characteristics, such as spray tip penetration, spray spreading cone angle and flame lift off length, provides a quantitative profile of the spray structure. Results show that, evaporation, different from atomization, has little influence on spray penetration, but promotes the spray spreading angle and spray projected area. So does combustion, which enlarges the spray projected area further. Ignition takes place on the periphery behind the spray tip, then quickly extends to the whole head of the spray and forms a U-shape diffusion structure. After the injection period, the residual spray tail develops into wavelike structures due to absence of subsequent entrainment force. Also, the penetration speed falls greatly to an extent much slower than flame propagation, which frees the flame from the lift-off effect. Subsequently, the flame propagates upstream towards the nozzle orifice. After consumed all fuel in

Alcohol combustion chemistry

KAUST Repository

Sarathy, Mani; Oß wald, Patrick; Hansen, Nils; Kohse-Hö inghaus, Katharina

2014-01-01

. While biofuel production and its use (especially ethanol and biodiesel) in internal combustion engines have been the focus of several recent reviews, a dedicated overview and summary of research on alcohol combustion chemistry is still lacking. Besides

Ashes of biomass combustion. Report of a workshop at 15 May 1997

International Nuclear Information System (INIS)

Zeevalkink, J.A.

1997-12-01

In a previous study the results of a study on the options to recycle or re-use ashes from biomass combustion were presented. Those results were discussed in detail in the title workshop, attended by researchers, market representatives that have to find practical solutions, and representatives of the Dutch government. It is concluded that only ashes from clean biomass can be used as a fertilizer (e.g. recycling of the ashes to forest soils), preferably in the form of granulated materials to realize a slow uptake of nutrients. Bottom ash can be applied in road construction materials or in concretes. In the appendices of this report sheets of 4 contributions are presented: ' Re-use of ashes form biomass combustion'; The Vattenfall project. Closing of the cycle in Sweden'; 'The vision of a biomass producer'; and ' The market problems for the initiator of biomass projects'. 3 appendices

Diesel oil combustion in fluidized bed; Combustion de aceite diesel en lecho fluidizado

Energy Technology Data Exchange (ETDEWEB)

Rodriguez Cazares, Mario [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

1992-07-01

The effect of the fluidized bed depth in the combustion in burning diesel oil in a fluidized bed, was analyzed. A self sustained combustion was achieved injecting the oil with an injector that utilized a principle similar to an automobile carburetor venturi. Three different depths were studied and it was found that the deeper the bed, the greater the combustion efficiency. Combustion efficiencies were attained from 82% for a 100mm bed depth, up to 96% for a 200mm bed depth. The diminution in the efficiency was mainly attributed to unburned hydrocarbons and to the carbon carried over, which was observed in the black smoke at the stack outlet. Other phenomena registered were the temperature gradient between the lower part of the bed and the upper part, caused by the fluidization velocity; additionally it was observed that the air employed for the oil injection (carbureting air) is the most important parameter to attain a complete combustion. [Espanol] Se analizo el efecto de la profundidad del lecho en la combustion al quemar aceite diesel en un lecho fluidizado experimental. Se logro combustion autosostenida inyectando el aceite con un inyector que utilizo un principio similar al venturi del carburador de automovil. Se estudiaron tres diferentes profundidades del lecho y se encontro que a mayor profundidad del lecho, mayor eficiencia de la combustion. Se lograron eficiencias de la combustion desde 82% para el lecho de 100 mm de profundidad hasta 96% para el de 200 mm. La disminucion de la eficiencia se atribuyo, principalmente, a los hidrocarburos no quemados y al carbon arrastrado, lo cual se observo en el humo negro a la salida de la chimenea. Otros fenomenos registrados fueron el gradiente de temperatura entre la parte baja del lecho y la parte superior causado por la velocidad de fluidizacion; ademas, se observo que el aire utilizado para inyectar el aceite (aire de carburacion) es el parametro mas importante para lograr una combustion completa.

Transient flow combustion

Science.gov (United States)

Tacina, R. R.

1984-01-01

Non-steady combustion problems can result from engine sources such as accelerations, decelerations, nozzle adjustments, augmentor ignition, and air perturbations into and out of the compressor. Also non-steady combustion can be generated internally from combustion instability or self-induced oscillations. A premixed-prevaporized combustor would be particularly sensitive to flow transients because of its susceptability to flashback-autoignition and blowout. An experimental program, the Transient Flow Combustion Study is in progress to study the effects of air and fuel flow transients on a premixed-prevaporized combustor. Preliminary tests performed at an inlet air temperature of 600 K, a reference velocity of 30 m/s, and a pressure of 700 kPa. The airflow was reduced to 1/3 of its original value in a 40 ms ramp before flashback occurred. Ramping the airflow up has shown that blowout is more sensitive than flashback to flow transients. Blowout occurred with a 25 percent increase in airflow (at a constant fuel-air ratio) in a 20 ms ramp. Combustion resonance was found at some conditions and may be important in determining the effects of flow transients.

Shale oil combustion

International Nuclear Information System (INIS)

Al-dabbas, M.A.

1992-05-01

A 'coutant' carbon steel combustion chamber cooled by water jacket was conslructed to burn diesel fuel and mixlure of shale oil and diesel fuels. During experimental work nir fuel ratio was determined, temperaturces were measured using Chromel/ Almel thermocouple, finally the gasous combustion product analysis was carricd out using gas chromatograph technique. The constructed combustion chamber was operating salisfactory for several hours of continous work. According to the measurements it was found that: the flame temperature of a mixture of diesel and shale oil fuels was greater than the flame temperature of diesel fuel. and the sulfer emissious of a mixture of diesel and shale oil fuels was higher than that of diesel fuel. Calculation indicated that the dry gas energy loss was very high and the incomplete combustion energy loss very small. (author). 23 refs., 35 figs

Shale oil combustion

Energy Technology Data Exchange (ETDEWEB)

Al-dabbas, M A

1992-05-01

A `coutant` carbon steel combustion chamber cooled by water jacket was conslructed to burn diesel fuel and mixlure of shale oil and diesel fuels. During experimental work nir fuel ratio was determined, temperaturces were measured using Chromel/ Almel thermocouple, finally the gasous combustion product analysis was carricd out using gas chromatograph technique. The constructed combustion chamber was operating salisfactory for several hours of continous work. According to the measurements it was found that: the flame temperature of a mixture of diesel and shale oil fuels was greater than the flame temperature of diesel fuel. and the sulfer emissious of a mixture of diesel and shale oil fuels was higher than that of diesel fuel. Calculation indicated that the dry gas energy loss was very high and the incomplete combustion energy loss very small. (author). 23 refs., 35 figs.

Investigation of the combustion kinetics and polycyclic aromatic hydrocarbon emissions from polycaprolactone combustion.

Science.gov (United States)

Chien, Y C; Yang, S H

2013-01-01

Polycaprolactone (PCL) is one of the most attractive biodegradable plastics that has been widely used in medicine and agriculture fields. Because of the large increase in biodegradable plastics usage, the production of waste biodegradable plastics will be increasing dramatically, producing a growing environmental problem. Generally, waste PCL is collected along with municipal solid wastes and then incinerated. This study investigates the combustion kinetics and emission factors of 16 US Environmental Protection Agency (EPA) priority polycyclic aromatic hydrocarbons (PAHs) in the PCL combustion. Experimentally, two reactions are involved in the PCL combustion process, possibly resulting in the emission of carbon dioxide, propanal, protonated caprolactone and very small amounts of PAH produced by incomplete combustion. The intermediate products may continuously be oxidized to form CO2. The emission factors for 16 US EPA priority PAHs are n.d. -2.95 microg/g, which are much lower than those of poly lactic acid and other plastics combustion. The conversion of PCL is 100%. Results from this work suggest that combustion is a good choice for the waste PCL disposal.

Multidimensional flamelet-generated manifolds for partially premixed combustion

Energy Technology Data Exchange (ETDEWEB)

Nguyen, Phuc-Danh; Vervisch, Luc; Subramanian, Vallinayagam; Domingo, Pascale [CORIA - CNRS and INSA de Rouen, Technopole du Madrillet, BP 8, 76801 Saint-Etienne-du-Rouvray (France)

2010-01-15

Flamelet-generated manifolds have been restricted so far to premixed or diffusion flame archetypes, even though the resulting tables have been applied to nonpremixed and partially premixed flame simulations. By using a projection of the full set of mass conservation species balance equations into a restricted subset of the composition space, unsteady multidimensional flamelet governing equations are derived from first principles, under given hypotheses. During the projection, as in usual one-dimensional flamelets, the tangential strain rate of scalar isosurfaces is expressed in the form of the scalar dissipation rates of the control parameters of the multidimensional flamelet-generated manifold (MFM), which is tested in its five-dimensional form for partially premixed combustion, with two composition space directions and three scalar dissipation rates. It is shown that strain-rate-induced effects can hardly be fully neglected in chemistry tabulation of partially premixed combustion, because of fluxes across iso-equivalence-ratio and iso-progress-of-reaction surfaces. This is illustrated by comparing the 5D flamelet-generated manifold with one-dimensional premixed flame and unsteady strained diffusion flame composition space trajectories. The formal links between the asymptotic behavior of MFM and stratified flame, weakly varying partially premixed front, triple-flame, premixed and nonpremixed edge flames are also evidenced. (author)

The importance of fuel properties in the formation of nitrogen oxides and in combustion

International Nuclear Information System (INIS)

Huotari, J.; Aho, M.; Haemaelaeinen, J.; Huotari, J.; Saastamoinen, J.; Rantanen, J.

1995-01-01

The goal of this work is to find new information about the effects of pressure, temperature and fuel properties (Fuel-O/Fuel-N) on the formation of nitrogen oxides through the most important intermediates (NH 3 and HCN). In addition, a single particle model for the simultaneous pyrolysis and char combustion will be improved to be used for calculating combustion under pressure. Experimental work is done with an electrically heated pressurized entrained flow reactor (PEFR) which is equipped with modern analytics (as FT-IR for the analysis of N 2 O, NO and NO 2 and FT-IR pyrometry for the measurement of particle temperatures). The experimental work is carried out in several stages: (a) Study of the formation of HCN and NH 3 during pressurized pyrolysis (b) Oxidation of HCN and NH 3 to nitrogen oxides in pressurized combustion (c) Reduction of NO by NH 3 under pressure (thermax denox) Task a is performed with fuels of various O/N ratio. Task b is performed with pure HCN and NH 3 and with more complicated gas mixtures including HCN and NH 3 . A large part of these results are utilized in kinetic modelling in Aabo Akademi University, Finland in project LIEKKI 2-201. Two kinds of modelling work is performed in VTT in this project (a) Simultaneous modelling of the composition of solid and gaseous phases in the pyrolysis and combustion of a small fuel particle (multiphase modelling) (b) Modelling of pyrolysis and combustion of a single fuel particle under pressurized conditions (single particle modelling). The results can be used in planning of pressurized combustors and in minimizing the emissions of nitrogen oxides. (author)

Recovery Act: Oxy-Combustion Techology Development for Industrial-Scale Boiler Applications

Energy Technology Data Exchange (ETDEWEB)

Levasseur, Armand

2014-04-30

Alstom Power Inc. (Alstom), under U.S. DOE/NETL Cooperative Agreement No. DE-NT0005290, is conducting a development program to generate detailed technical information needed for application of oxy-combustion technology. The program is designed to provide the necessary information and understanding for the next step of large-scale commercial demonstration of oxy combustion in tangentially fired boilers and to accelerate the commercialization of this technology. The main project objectives include: • Design and develop an innovative oxyfuel system for existing tangentially-fired boiler units that minimizes overall capital investment and operating costs. • Evaluate performance of oxyfuel tangentially fired boiler systems in pilot scale tests at Alstom’s 15 MWth tangentially fired Boiler Simulation Facility (BSF). • Address technical gaps for the design of oxyfuel commercial utility boilers by focused testing and improvement of engineering and simulation tools. • Develop the design, performance and costs for a demonstration scale oxyfuel boiler and auxiliary systems. • Develop the design and costs for both industrial and utility commercial scale reference oxyfuel boilers and auxiliary systems that are optimized for overall plant performance and cost. • Define key design considerations and develop general guidelines for application of results to utility and different industrial applications. The project was initiated in October 2008 and the scope extended in 2010 under an ARRA award. The project completion date was April 30, 2014. Central to the project is 15 MWth testing in the BSF, which provided in-depth understanding of oxy-combustion under boiler conditions, detailed data for improvement of design tools, and key information for application to commercial scale oxy-fired boiler design. Eight comprehensive 15 MWth oxy-fired test campaigns were performed with different coals, providing detailed data on combustion, emissions, and thermal behavior over a

Sludge combustion in fluidized bed reactors at laboratory scale

International Nuclear Information System (INIS)

Chirone, R.; Cammarota, A.

2001-01-01

The combustion of a dried sewage sludge in laboratory scale fluidized bed has been studied in Naples by the Istituto di ricerche sulla combustione (Irc) in the framework of a National project named Thermal Process with Energy Recovery to be used in laboratory and pre-pilot scale apparatus. The attention has been focused on emissions of unreacted carbon as elutriated fines, on the emissions of pollutant gases and on the assessment of the inventory of fly- and bottom ashes. The combustion behaviour of sewage sludge has been compared with those of a market available Tyre Derived Fuel (TDF) and a biomass from Mediterranean area (Robinia Pseudoacacia) and with that of a South African bituminous coal. Stationary combustion tests were carried out at 850 0 C by feeding particles in the size range 0-1 mm into a bed of silica sand without any sorbent addition. The fluidized bed combustor has been operated, at a superficial gas velocity of 0.4 m/s and different excesses of air ranging between 14 and 98%. Relatively high combustion efficiency, larger than 98.9% has been obtained in experiments carried out with sewage sludge and excess of air larger than 20%. These values, are comparable with those obtained in previously experimental activity carried out under similar operative conditions with a South Africa Bituminous coal (97-98%). It is larger than those obtained by using a Tyre Derived Fuel (89-90%) and the Robinia Pseudoacacia Biomass (93-93%). The relative importance of carbon fines elutriation, CO emissions and volatile bypassing the bed in determining the loss of combustion efficiency has been evaluated for the different fuels tested [it

Combustion of Dried Sewage Sludge in a Fluidized-Bed Reactor

Czech Academy of Sciences Publication Activity Database

Hartman, Miloslav; Svoboda, Karel; Pohořelý, Michael; Trnka, Otakar

2005-01-01

Roč. 44, č. 10 (2005), s. 3432-3441 ISSN 0888-5885 R&D Projects: GA AV ČR(CZ) IAA4072201 Institutional research plan: CEZ:AV0Z40720504 Keywords : fluidized-bed combustion * dried sewage sludge * CO, NOx, and N2O emissions Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 1.504, year: 2005

The Multi-User Droplet Combustion Apparatus: the Development and Integration Concept for Droplet Combustion Payloads in the Fluids and Combustion Facility Combustion Integrated Rack

Science.gov (United States)

Myhre, C. A.

2002-01-01

The Multi-user Droplet Combustion Apparatus (MDCA) is a multi-user facility designed to accommodate four different droplet combustion science experiments. The MDCA will conduct experiments using the Combustion Integrated Rack (CIR) of the NASA Glenn Research Center's Fluids and Combustion Facility (FCF). The payload is planned for the International Space Station. The MDCA, in conjunction with the CIR, will allow for cost effective extended access to the microgravity environment, not possible on previous space flights. It is currently in the Engineering Model build phase with a planned flight launch with CIR in 2004. This paper provides an overview of the capabilities and development status of the MDCA. The MDCA contains the hardware and software required to conduct unique droplet combustion experiments in space. It consists of a Chamber Insert Assembly, an Avionics Package, and a multiple array of diagnostics. Its modular approach permits on-orbit changes for accommodating different fuels, fuel flow rates, soot sampling mechanisms, and varying droplet support and translation mechanisms to accommodate multiple investigations. Unique diagnostic measurement capabilities for each investigation are also provided. Additional hardware provided by the CIR facility includes the structural support, a combustion chamber, utilities for the avionics and diagnostic packages, and the fuel mixing capability for PI specific combustion chamber environments. Common diagnostics provided by the CIR will also be utilized by the MDCA. Single combustible fuel droplets of varying sizes, freely deployed or supported by a tether are planned for study using the MDCA. Such research supports how liquid-fuel-droplets ignite, spread, and extinguish under quiescent microgravity conditions. This understanding will help us develop more efficient energy production and propulsion systems on Earth and in space, deal better with combustion generated pollution, and address fire hazards associated with

Co-Optima Project E2.2.2: Accelerate Development of ACI/LTC Fuel Effects on RCCI Combustion.

Energy Technology Data Exchange (ETDEWEB)

Musculus, Mark P. [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

2017-11-01

Many advanced combustion approaches have demonstrated potential for achieving diesel-like thermal efficiency but with much lower pollutant emissions of particulate matter (PM) and nitrogen oxides (NOx). RCCI is one advanced combustion concept, which makes use of in-cylinder blending of two fuels with differing reactivity for improved control of the combustion phasing and rate (Reitz et al., 2015). Previous research and development at ORNL has demonstrated successful implementation of RCCI on a light-duty multi-cylinder engine over a wide range of operating conditions (Curran et al., 2015). Several challenges were encountered when extending the research to practical applications, including limits to the operating range, both for high and low loads. Co-optimizing the engine and fuel aspects of the RCCI approach might allow these operating limits to be overcome. The in-cylinder mechanisms by which fuel properties interact with engine operating condition variables is not well understood, however, in part because RCCI is a new combustion concept that is still being developed, and limited data have been acquired to date, especially using in-cylinder optical/imaging diagnostics. The objective of this work is to use in-cylinder diagnostics in a heavy-duty single-cylinder optical engine at SNL to understand the interplay between fuel properties and engine hardware and operating conditions for RCCI in general, and in particular for the light-duty multi-cylinder all-metal RCCI engine experiments at ORNL.

Investigations on oxy-fuel combustion in glass melting furnaces; Untersuchungen zur Oxy-Fuel-Feuerung in Glasschmelzwannen

Energy Technology Data Exchange (ETDEWEB)

Leicher, Joerg; Giese, Anne [Gaswaerme-Institut e.V., Essen (Germany)

2011-12-15

Glass melting requires process temperatures of more than 1600 C which are usually achieved using intensive air preheating and near-stoichiometric combustion. This often leads to high nitrous oxide emissions (NO{sub x}). Oxy-fuel technology offers an interesting alternative since high combustion temperatures can be achieved using pure oxygen as oxidizer while obtaining low NO{sub x} emissions. In the course of the AiF research project ''O2-Glaswanne'' (IGF-Nr.: 15987 N), Gaswaerme- Institut e.V. Essen investigates this combustion process by experimental and numerical means in order to determine potential optimization approaches for glass melting furnaces.

Large-eddy simulation of ethanol spray combustion using a finite-rate combustion model

Energy Technology Data Exchange (ETDEWEB)

Li, K.; Zhou, L.X. [Tsinghua Univ., Beijing (China). Dept. of Engineering Mechanics; Chan, C.K. [Hong Kong Polytechnic Univ. (China). Dept. of Applied Mathematics

2013-07-01

Large-eddy simulation of spray combustion is under its rapid development, but the combustion models are less validated by detailed experimental data. In this paper, large-eddy simulation of ethanol-air spray combustion was made using an Eulerian-Lagrangian approach, a subgrid-scale kinetic energy stress model, and a finite-rate combustion model. The simulation results are validated in detail by experiments. The LES obtained statistically averaged temperature is in agreement with the experimental results in most regions. The instantaneous LES results show the coherent structures of the shear region near the high-temperature flame zone and the fuel vapor concentration map, indicating the droplets are concentrated in this shear region. The droplet sizes are found to be in the range of 20-100{mu}m. The instantaneous temperature map shows the close interaction between the coherent structures and the combustion reaction.

Application study of Bio-FGD based on environmental safety during the coal combustion

Science.gov (United States)

Zhang, Pin

2018-05-01

Coal combustion produces a large amount of acidic gas, which is the main cause of acid rain and other natural disasters. Flue Gas Desulfurization (FGD) is a necessary requirement for clean coal combustion. Compared with the traditional chemical desulfurization technology, biological desulfurization has the advantages of low operating cost, without secondary pollution, low carbon emission and the additional economic benefits. The process and structure of BioDeSOx which as one of Bio-FGD technology is introduced. The major factors that influent BioDeSOx Bio- FGD system is the pH, oxidation reduction potential (-300 MV to -400MV), electrical conductivity, the adding amount of nutrient and temperature (30°C-40°C). Taking the Bio- FGD project of Yixing xielian thermal power plant as an example, the BioDeSOx technology was applied in this project. The environmental and economic benefits of the project were greater than the traditional desulfurization technology. With the continuous improvement of environmental safety standards, Bio- FGD technology will have broad application prospects.

Impacts of Combustion Conditions and Photochemical Processing on the Light Absorption of Biomass Combustion Aerosol.

Science.gov (United States)

Martinsson, J; Eriksson, A C; Nielsen, I Elbæk; Malmborg, V Berg; Ahlberg, E; Andersen, C; Lindgren, R; Nyström, R; Nordin, E Z; Brune, W H; Svenningsson, B; Swietlicki, E; Boman, C; Pagels, J H

2015-12-15

The aim was to identify relationships between combustion conditions, particle characteristics, and optical properties of fresh and photochemically processed emissions from biomass combustion. The combustion conditions included nominal and high burn rate operation and individual combustion phases from a conventional wood stove. Low temperature pyrolysis upon fuel addition resulted in "tar-ball" type particles dominated by organic aerosol with an absorption Ångström exponent (AAE) of 2.5-2.7 and estimated Brown Carbon contributions of 50-70% to absorption at the climate relevant aethalometer-wavelength (520 nm). High temperature combustion during the intermediate (flaming) phase was dominated by soot agglomerates with AAE 1.0-1.2 and 85-100% of absorption at 520 nm attributed to Black Carbon. Intense photochemical processing of high burn rate flaming combustion emissions in an oxidation flow reactor led to strong formation of Secondary Organic Aerosol, with no or weak absorption. PM1 mass emission factors (mg/kg) of fresh emissions were about an order of magnitude higher for low temperature pyrolysis compared to high temperature combustion. However, emission factors describing the absorption cross section emitted per kg of fuel consumed (m(2)/kg) were of similar magnitude at 520 nm for the diverse combustion conditions investigated in this study. These results provide a link between biomass combustion conditions, emitted particle types, and their optical properties in fresh and processed plumes which can be of value for source apportionment and balanced mitigation of biomass combustion emissions from a climate and health perspective.

Lean premixed combustion stabilized by radiation feedback and heterogeneous catalysis

Energy Technology Data Exchange (ETDEWEB)

Dibble, R.W.; Jyh-Yuan Chen; Sawyer, R.F. [Univ. of California, Berkeley, CA (United States)

1995-10-01

Gas-turbine based systems are becoming the preferred approach to electric power generation from gaseous and liquid fossil-fuels and from biomass. As coal gasification becomes, gas turbines will also become important in the generation of electricity from coal. In smaller, distributed installations, gas turbines will also become important in the generation of electricity from coal. In smaller, distributed installations, gas turbines offer the prospect of cogeneration of electricity and heat, with increased efficiency and reduced pollutant emissions. One of the most important problems facing combustion-based power generation is the control of air pollutants, primarily nitrogen oxides (NO{sub x}, consisting of NO and NO{sub 2}) and carbon monoxide (CO). Nitric oxide (NO) is formed during gas-phase combustion and is the precursor of nitrogen dioxide (NO{sub 2}), the principal component of photochemical smog. Recent research into the mechanisms and control of NO{sub x} formation has been spurred by increasingly stringent emission standards. The principal objective of this research project is the development of effective models for the simulation of catalytic combustion applications.

Engine combustion network (Ecn) : characterization and comparison of boundary conditions for different combustion vessels

NARCIS (Netherlands)

Meijer, M.; Somers, L.M.T.; Johnson, J.; Naber, J.; Lee, S.Y.; Malbec, L.M.; Bruneaux, G.; Pickett, L.M.; Bardi, M.; Payri, R.; Bazyn, T.

2012-01-01

The Engine Combustion Network (ECN) is a worldwide group of institutions using combustion vessels and/or performing computational fluid dynamics (CFD) simulation, whose aim is to advance the state of spray and combustion knowledge at engine-relevant conditions. A key activity is the use of spray

Optimization of combustion chamber geometry for stoichiometric diesel combustion using a micro genetic algorithm

Energy Technology Data Exchange (ETDEWEB)

Park, Sung Wook

2010-11-15

This paper describes the optimization of combustion chamber geometry and engine operating conditions for stoichiometric diesel combustion, targeting lower gross indicated specific fuel consumption. The KIVA code, coupled with a micro genetic algorithm population of nine for each generation was used. The optimization variables were composed of ten variables related to the combustion chamber geometry and engine operating conditions. In addition, an auto mesh generator was developed for generating various kinds of combustion chambers, such as open-crater, re-entrant, deep, and shallow types. In addition, the computational models were validated against the experimental results for a stoichiometric process in terms of the combustion pressure history and emissions. Through the preset optimization, a 35% improvement in the gross indicated that specific fuel consumption was achieved. In addition, the optimization results showed that the optimum engine operating conditions employed a premixed charge compression ignition combustion regime with early injection and a narrow spray included angle. Furthermore, a higher boost pressure was used to prevent fuel film formation. (author)

Plasma-Enhanced Combustion of Hydrocarbon Fuels and Fuel Blends Using Nanosecond Pulsed Discharges

Energy Technology Data Exchange (ETDEWEB)

Cappelli, Mark; Mungal, M Godfrey

2014-10-28

This project had as its goals the study of fundamental physical and chemical processes relevant to the sustained premixed and non-premixed jet ignition/combustion of low grade fuels or fuels under adverse flow conditions using non-equilibrium pulsed nanosecond discharges.

FutureGen 2.0 Oxy-Coal Combustion Carbon Capture Plant Pre-FEED Design and Cost

Energy Technology Data Exchange (ETDEWEB)

Flanigan, Tom; Pybus, Craig; Roy, Sonya; Lockwood, Frederick; McDonald, Denny; Maclnnis, Jim

2011-09-30

This report summarizes the results of the Pre-Front End Engineering Design (pre-FEED) phase of a proposed advanced oxy-combustion power generation plant to repower the existing 200 MWe Unit 4 at Ameren Energy Resources’ (AER) Meredosia Power Plant. AER has formed an alliance with Air Liquide Process and Construction, Inc. (ALPC) and Babcock & Wilcox Power Generation Group (B&W PGG) for the design, construction, and testing of the facility, and has contracted with URS Corporation (URS) for preliminary design and Owner’s engineering services. The Project employs oxy-combustion technology – combustion of coal with nearly pure oxygen and recycled flue gas (instead of air) – to capture approximately 90% of the flue gas CO2 for transport and sequestration by another Project. Plant capacity and configuration has been developed based on the B&W PGG-ALPC cool recycle process firing high-sulfur bituminous coal fuel, assuming baseload plant operation to maximize existing steam turbine capability, with limited consideration for plant redundancy and performance optimization in order to keep plant costs as low as practical. Activities and preliminary results from the pre-FEED phase addressed in this report include the following: Overall plant thermal performance; Equipment sizing and system configuration; Plant operation and control philosophy; Plant emissions and effluents; CO₂ production and recovery characteristics; Project cost estimate and economic evaluation; Integrated project engineering and construction schedule; Project risk and opportunity assessment; Development of Project permitting strategy and requirements During the Phase 2 of the Project, additional design details will be developed and the Phase 1 work products updated to support actual construction and operation of the facility in Phase 3. Additional information will be provided early in Phase 2 to support Ameren-Environmental in finalizing the appropriate permitting strategies and permit

Multi-stage combustion using nitrogen-enriched air

Science.gov (United States)

Fischer, Larry E.; Anderson, Brian L.

2004-09-14

Multi-stage combustion technology combined with nitrogen-enriched air technology for controlling the combustion temperature and products to extend the maintenance and lifetime cycles of materials in contact with combustion products and to reduce pollutants while maintaining relatively high combustion and thermal cycle efficiencies. The first stage of combustion operates fuel rich where most of the heat of combustion is released by burning it with nitrogen-enriched air. Part of the energy in the combustion gases is used to perform work or to provide heat. The cooled combustion gases are reheated by additional stages of combustion until the last stage is at or near stoichiometric conditions. Additional energy is extracted from each stage to result in relatively high thermal cycle efficiency. The air is enriched with nitrogen using air separation technologies such as diffusion, permeable membrane, absorption, and cryogenics. The combustion method is applicable to many types of combustion equipment, including: boilers, burners, turbines, internal combustion engines, and many types of fuel including hydrogen and carbon-based fuels including methane and coal.

DIAGNOSIS OF FAILURE OF COMBUSTION IN THE COMBUSTION CHAMBER WITH A THERMOVISION EQUIPMENT

Directory of Open Access Journals (Sweden)

S. V. Vorobiev

2014-01-01

Full Text Available The use of thermovision technology to diagnose failure of the combustion flame test tube of the main combustion chamber gas turbine engine is deal with in the article. Join the thermal radiation of the jet of combustion products and the internal elements was carried out using short-wave thermovision system AGA-782 with spectral spectral filters in several ranges from 3.2 to 5.6 microns. Thermovision is mounted on the axis of the flame tube. The output signal was recorded and processed on a computer in real time, allowing monitor the combustion process and the thermal state of the object during the experiment.

High Combustion Research Facility

Data.gov (United States)

Federal Laboratory Consortium — At NETL's High-Pressure Combustion Research Facility in Morgantown, WV, researchers can investigate new high-pressure, high-temperature hydrogen turbine combustion...

PSO Project 10085

DEFF Research Database (Denmark)

Jappe Frandsen, Flemming; Wu, Hao; Glarborg, Peter

Co-combustion of refuse derived fuels (RDF) with coal in pulverized coal-fired power plants can potentially increase the electrical efficiency of utilizing RDF and reduce the formation of some harmful pollutants such as dioxins. The objective of this project was to provide a general assessment of...

Computational Modeling of Turbulent Spray Combustion

NARCIS (Netherlands)

Ma, L.

2016-01-01

The objective of the research presented in this thesis is development and validation of predictive models or modeling approaches of liquid fuel combustion (spray combustion) in hot-diluted environments, known as flameless combustion or MILD combustion. The goal is to combine good physical insight,

Space Station Freedom combustion research

Science.gov (United States)

Faeth, G. M.

1992-01-01

Extended operations in microgravity, on board spacecraft like Space Station Freedom, provide both unusual opportunities and unusual challenges for combustion science. On the one hand, eliminating the intrusion of buoyancy provides a valuable new perspective for fundamental studies of combustion phenomena. On the other hand, however, the absence of buoyancy creates new hazards of fires and explosions that must be understood to assure safe manned space activities. These considerations - and the relevance of combustion science to problems of pollutants, energy utilization, waste incineration, power and propulsion systems, and fire and explosion hazards, among others - provide strong motivation for microgravity combustion research. The intrusion of buoyancy is a greater impediment to fundamental combustion studies than to most other areas of science. Combustion intrinsically heats gases with the resulting buoyant motion at normal gravity either preventing or vastly complicating measurements. Perversely, this limitation is most evident for fundamental laboratory experiments; few practical combustion phenomena are significantly affected by buoyancy. Thus, we have never observed the most fundamental combustion phenomena - laminar premixed and diffusion flames, heterogeneous flames of particles and surfaces, low-speed turbulent flames, etc. - without substantial buoyant disturbances. This precludes rational merging of theory, where buoyancy is of little interest, and experiments, that always are contaminated by buoyancy, which is the traditional path for developing most areas of science. The current microgravity combustion program seeks to rectify this deficiency using both ground-based and space-based facilities, with experiments involving space-based facilities including: laminar premixed flames, soot processes in laminar jet diffusion flames, structure of laminar and turbulent jet diffusion flames, solid surface combustion, one-dimensional smoldering, ignition and flame

Combustion of pulverized fuel under oxycoal conditions at low oxygen concentrations

Energy Technology Data Exchange (ETDEWEB)

Toporov D.; Foerster M.; Kneer R. [RWTH Aachen University, Aachen (Germany). Institute of Heat and Mass Transfer

2007-07-01

Oxycoal combustion followed by post-combustion CO{sub 2} sequestration has gained justified interest as an option for significant and relatively quick reduction of emissions from fossil fuel power generation, while taking advantage of the existing power plant infrastructure. Burning pulverised coal in a mixture of CO{sub 2}/O{sub 2} instead of air, however, will lead to modified distributions of temperature, species, and radiation fluxes inside the combustion chamber causing a retroaction on the homogeneous and heterogeneous reactions. Utilizing a burner design, which was optimised for coal combustion in air, for oxycoal combustion will lead to flame instability and poor burnout. Stabilisation of the combustion process can be obtained by: i) an increased oxygen concentration (more than 21% vol.) in the oxidiser mixture, thus achieving similar reaction rates and temperature levels to a pulverised fuel-air flame without significant changes to the flame aerodynamics. ii) modifications to the burner aerodynamics, as presented here. The results in this study are obtained in the frame of OXYCOAL-AC, the research project, having the aim to burn a pulverised coal in a CO{sub 2}/O{sub 2}-atmosphere with oxygen, produced from high-temperature ceramic membrane thus leading to higher efficiency of the whole oxycoal process. Numerical and experimental investigations of a stable oxycoal flame, obtained with {le} 21% oxygen concentration in the burning mixture at the RWTH test facility are reported. Two different burner designs are considered, conclusions concerning the achievement of a stable oxycoal flame at O{sub 2} volume concentrations equal and less to the one of oxygen in air are derived. 8 refs., 7 figs., 1 tab.

Combustion Stability Characteristics of the Project Morpheus Liquid Oxygen / Liquid Methane Main Engine

Science.gov (United States)

Melcher, John C.; Morehead, Robert L.

2014-01-01

The project Morpheus liquid oxygen (LOX) / liquid methane (LCH4) main engine is a Johnson Space Center (JSC) designed 5,000 lbf-thrust, 4:1 throttling, pressure-fed cryogenic engine using an impinging element injector design. The engine met or exceeded all performance requirements without experiencing any in- ight failures, but the engine exhibited acoustic-coupled combustion instabilities during sea-level ground-based testing. First tangential (1T), rst radial (1R), 1T1R, and higher order modes were triggered by conditions during the Morpheus vehicle derived low chamber pressure startup sequence. The instability was never observed to initiate during mainstage, even at low power levels. Ground-interaction acoustics aggravated the instability in vehicle tests. Analysis of more than 200 hot re tests on the Morpheus vehicle and Stennis Space Center (SSC) test stand showed a relationship between ignition stability and injector/chamber pressure. The instability had the distinct characteristic of initiating at high relative injection pressure drop at low chamber pressure during the start sequence. Data analysis suggests that the two-phase density during engine start results in a high injection velocity, possibly triggering the instabilities predicted by the Hewitt stability curves. Engine ignition instability was successfully mitigated via a higher-chamber pressure start sequence (e.g., 50% power level vs 30%) and operational propellant start temperature limits that maintained \\cold LOX" and \\warm methane" at the engine inlet. The main engine successfully demonstrated 4:1 throttling without chugging during mainstage, but chug instabilities were observed during some engine shutdown sequences at low injector pressure drop, especially during vehicle landing.

Beneficial Use and Recycling of Municipal Waste Combustion Residues - A Comprehensive Resource Document

Energy Technology Data Exchange (ETDEWEB)

Wiles, C.; Shepherd, P.

1999-04-26

This document summarizes information from worldwide sources on the beneficial use of residues from the combustion of municipal. The information presented, including results of numerous research projects, field demonstrations, and actual full-scale projects, demonstrates that the ash can be safely used. It includes data on ash characteristics, environmental considerations, guidance on selected ash use applications, and information on federal and state regulations and policies affecting ash use.

Underground treatment of combustible minerals

Energy Technology Data Exchange (ETDEWEB)

Sarapuu, E

1954-10-14

A process is described for treating oil underground, consisting in introducing several electrodes spaced one from the other in a bed of combustibles underground so that they come in electric contact with this bed of combustibles remaining insulated from the ground, and applying to the electrodes a voltage sufficient to produce an electric current across the bed of combustibles, so as to heat it and create an electric connection between the electrodes on traversing the bed of combustibles.

Numerical simulation of combustion and soot under partially premixed combustion of low-octane gasoline

KAUST Repository

An, Yanzhao

2017-09-23

In-cylinder combustion visualization and engine-out soot particle emissions were investigated in an optical diesel engine fueled with low octane gasoline. Single injection strategy with an early injection timing (−30 CAD aTDC) was employed to achieve partially premixed combustion (PPC) condition. A high-speed color camera was used to record the combustion images for 150 cycles. The regulated emission of carbon dioxide, carbon monoxide, nitrogen oxides and soot mass concentration were measured experimentally. Full cycle engine simulations were performed using CONVERGE™ and the simulation results matched with the experimental results. The in-cylinder soot particle evolution was performed by coupling a reduced toluene reference fuel mechanism including the PAHs formation/oxidation reactions with particulate size mimic model. The results showed that PPC presents typical stratified combustion characteristics, which is significantly different from the conventional diesel spray-driven combustion. The in-cylinder temperature and equivalence ratio overlaid with soot-NO formation regime revealed that PPC operating condition under study mostly avoided the main sooting conditions throughout the entire combustion. The evaluation of temperature distribution showed formaldehyde could be regarded as an indicator for low temperature reactions, while hydroxyl group represents the high temperature reactions. Soot evolution happened during the combustion process, hydroxyl radicals promoted the soot oxidation.

Numerical simulation of combustion and soot under partially premixed combustion of low-octane gasoline

KAUST Repository

An, Yanzhao; Jaasim, Mohammed; Vallinayagam, R.; Vedharaj, S.; Im, Hong G.; Johansson, Bengt.

2017-01-01

In-cylinder combustion visualization and engine-out soot particle emissions were investigated in an optical diesel engine fueled with low octane gasoline. Single injection strategy with an early injection timing (−30 CAD aTDC) was employed to achieve partially premixed combustion (PPC) condition. A high-speed color camera was used to record the combustion images for 150 cycles. The regulated emission of carbon dioxide, carbon monoxide, nitrogen oxides and soot mass concentration were measured experimentally. Full cycle engine simulations were performed using CONVERGE™ and the simulation results matched with the experimental results. The in-cylinder soot particle evolution was performed by coupling a reduced toluene reference fuel mechanism including the PAHs formation/oxidation reactions with particulate size mimic model. The results showed that PPC presents typical stratified combustion characteristics, which is significantly different from the conventional diesel spray-driven combustion. The in-cylinder temperature and equivalence ratio overlaid with soot-NO formation regime revealed that PPC operating condition under study mostly avoided the main sooting conditions throughout the entire combustion. The evaluation of temperature distribution showed formaldehyde could be regarded as an indicator for low temperature reactions, while hydroxyl group represents the high temperature reactions. Soot evolution happened during the combustion process, hydroxyl radicals promoted the soot oxidation.

Fuels and Combustion | Transportation Research | NREL

Science.gov (United States)

Fuels and Combustion Fuels and Combustion This is the March 2015 issue of the Transportation and , combustion strategy, and engine design hold the potential to maximize vehicle energy efficiency and performance of low-carbon fuels in internal combustion engines with a whole-systems approach to fuel chemistry

Combustion Properties of Biomass Flash Pyrolysis Oils: Final Project Report

Energy Technology Data Exchange (ETDEWEB)

C. R. Shaddix; D. R. Hardesty

1999-04-01

Thermochemical pyrolysis of solid biomass feedstocks, with subsequent condensation of the pyrolysis vapors, has been investigated in the U.S. and internationally as a means of producing a liquid fuel for power production from biomass. This process produces a fuel with significantly different physical and chemical properties from traditional petroleum-based fuel oils. In addition to storage and handling difficulties with pyrolysis oils, concern exists over the ability to use this fuel effectively in different combustors. The report endeavors to place the results and conclusions from Sandia's research into the context of international efforts to utilize pyrolysis oils. As a special supplement to this report, Dr. Steven Gust, of Finland's Neste Oy, has provided a brief assessment of pyrolysis oil combustion research efforts and commercialization prospects in Europe.

Ultra-low pollutant emission combustion method and apparatus

International Nuclear Information System (INIS)

Khinkis, M.J.

1992-01-01

This patent describes a method for ultra-low pollutant emission combustion of fossil fuel. It comprises: introducing into a primary combustion chamber a first fuel portion of about 1 percent to about 20 percent of a total fuel to be combusted; introducing primary combustion air into the primary combustion chamber; introducing a first portion of water into the primary combustion chamber, having a first water heat capacity equivalent to a primary combustion air heat capacity of one of a primary combustion air amount of about 10 percent to about 60 percent of the first stoichiometirc requirement for complete combustion of the first fuel portion and an excess primary combustion air amount of about 20 percent to about 150 percent of the first stoichiometric requirement for complete combustion of the first fuel portion; burning the first fuel portion with the primary combustion air in the primary combustion chamber at a temperature abut 2000 degrees F to about 2700 degrees F producing initial combustion products; passing the initial combustion products into a secondary combustion chamber; introducing into the secondary combustion chamber a second fuel portion of about 80 percent to about 99 percent of the total fuel to be combusted; introducing secondary combustion air into the secondary combustion chamber in an amount of about 105 percent to about 130 percent of a second stoichiometric requirement for complete combustion of the second fuel portion; introducing a second portion of water into the secondary combustion chamber; burning the second fuel portion and any remaining fuel in the initial combustion products; passing the final combustion products into a dilution chamber; introducing dilution air into the dilution chamber; discharging the ultra-low pollutant emission vitiated air form the dilution chamber

Treatment of Decommissioning Combustible Wastes with Incineration Technology

Energy Technology Data Exchange (ETDEWEB)

Min, B. Y. Min; Yang, D. S.; Yun, G. S.; Lee, K. W.; Moon, J. K. [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

2015-05-15

The aim of the paper is current status of management for the decommissioning radioactive combustible and metal waste in KAERI. In Korea, two decommissioning projects were carried out for nuclear research facilities (KRR-1 and KRR-2) and a uranium conversion plant (UCP). Through the two decommissioning projects, lots of decommissioning wastes were generated. Decommissioning waste can be divided into radioactive waste and releasable waste. The negative pressure of the incineration chamber remained constant within the specified range. Off-gas flow and temperature were maintained constant or within the desired range. The measures gases and particulate materials in the stack were considerably below the regulatory limits. The achieved average volume reduction ratio during facility operation is about 1/65.

Data for modern boilers used in co-combustion; Moderna panndata inom samfoerbraenning

Energy Technology Data Exchange (ETDEWEB)

Thorson, Ola [S.E.P. Scandinavian Energy Project AB, Goeteborg (Sweden)

2004-04-01

This project is a survey and a description of today's technical status and future development trends in the field of co-combustion. The survey is done from an energy production company's point of view and two technical questions have been studied; the possibilities for high steam data and the possibilities for a wide load range. These parameters are limited by the corrosive properties of the fuel and the environmental requirements in the EU directive for combustion of waste. In the report following issues are discussed: Examples of and experiences from co-combustion plants and plants that combust problematic fuels and have high steam data. A future prospect of high steam data in co-combustion plants by the usage of modern technical solutions and a description of these solutions. Important research and development results from combustion of problematic fuels in combination with high steam data. Choice of firing technology, boiler design and auxiliary systems and its affection on the load range in a boiler for co-combustion. A literature survey has been done to get the latest results from combustion of problematic fuels. Then a number of interesting plants have been identified and facts about them have been collected by contacts with plant owners, suppliers and professional researchers and also through publications. The report shows that Sweden, Finland and Denmark are in the front line of using high steam data for co-combustion of biomass and waste fuels. There are/have been problems with superheater corrosion in many of these plants but a number of ways how to handle high steam data have been identified: Adjust the fuel mix or add additives; Use high alloy materials; Consider the final super heater as a part that is worn out by time; Place the final super heater in the particle loop seal/sand locker; Use an external separate fired super heater; Gasification and then co-combustion of the pyrolysis gas in a conventional existing boiler; Place the

ANALYSIS OF INTERNAL COMBUSTION ENGINE WITH A NEW CONCEPT OF POROUS MEDIUM COMBUSTION FOR THE FUTURE CLEAN ENGINE

Directory of Open Access Journals (Sweden)

Ashok A Dhale

2010-01-01

Full Text Available At present, the emissions of internal combustion engine can only be improved by catalytic treatments of the exhaust gases. Such treatments, however, result in high costs and relatively low conversion efficiency. This suggests that a new combustion technique should be developed to yield improved primary combustion processes inside the engine with drastically reduced exhaust gas emissions. To fulfill all requirements, Dr. Franz Drust has proposed a new combustion concept to perform homogenous combustion in internal combustion engines. This concept used the porous medium combustion technique and is called "PM-engine". It is shown that the PM combustion technique can be applied to internal combustion engines. Theoretical considerations are presented for internal combustion engines, indicating that an overall improvement in thermal efficiency can be achieved for the PM-engine. This is explained and general performance of the new PM-engines is demonstrated for a single cylinder, water cooled, direct injection diesel engine. Verification of experiments at primary stage is described that were carried out as a part of the present study.

Alcohol combustion chemistry

KAUST Repository

Sarathy, Mani

2014-10-01

Alternative transportation fuels, preferably from renewable sources, include alcohols with up to five or even more carbon atoms. They are considered promising because they can be derived from biological matter via established and new processes. In addition, many of their physical-chemical properties are compatible with the requirements of modern engines, which make them attractive either as replacements for fossil fuels or as fuel additives. Indeed, alcohol fuels have been used since the early years of automobile production, particularly in Brazil, where ethanol has a long history of use as an automobile fuel. Recently, increasing attention has been paid to the use of non-petroleum-based fuels made from biological sources, including alcohols (predominantly ethanol), as important liquid biofuels. Today, the ethanol fuel that is offered in the market is mainly made from sugar cane or corn. Its production as a first-generation biofuel, especially in North America, has been associated with publicly discussed drawbacks, such as reduction in the food supply, need for fertilization, extensive water usage, and other ecological concerns. More environmentally friendly processes are being considered to produce alcohols from inedible plants or plant parts on wasteland. While biofuel production and its use (especially ethanol and biodiesel) in internal combustion engines have been the focus of several recent reviews, a dedicated overview and summary of research on alcohol combustion chemistry is still lacking. Besides ethanol, many linear and branched members of the alcohol family, from methanol to hexanols, have been studied, with a particular emphasis on butanols. These fuels and their combustion properties, including their ignition, flame propagation, and extinction characteristics, their pyrolysis and oxidation reactions, and their potential to produce pollutant emissions have been intensively investigated in dedicated experiments on the laboratory and the engine scale

Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System

Energy Technology Data Exchange (ETDEWEB)

Wei-Ping Pan; Yan Cao; John Smith

2008-05-31

On February 14, 2002, President Bush announced the Clear Skies Initiative, a legislative proposal to control the emissions of nitrogen oxides (NO{sub x}), sulfur dioxide (SO{sub 2}), and mercury from power plants. In response to this initiative, the National Energy Technology Laboratory organized a Combustion Technology University Alliance and hosted a Solid Fuel Combustion Technology Alliance Workshop. The workshop identified multi-pollutant control; improved sorbents and catalysts; mercury monitoring and capture; and improved understanding of the underlying reaction chemistry occurring during combustion as the most pressing research needs related to controlling environmental emissions from fossil-fueled power plants. The Environmental Control Technology Laboratory will help meet these challenges and offer solutions for problems associated with emissions from fossil-fueled power plants. The goal of this project was to develop the capability and technology database needed to support municipal, regional, and national electric power generating facilities to improve the efficiency of operation and solve operational and environmental problems. In order to effectively provide the scientific data and the methodologies required to address these issues, the project included the following aspects: (1) Establishing an Environmental Control Technology Laboratory using a laboratory-scale, simulated fluidized-bed combustion (FBC) system; (2) Designing, constructing, and operating a bench-scale (0.6 MW{sub th}), circulating fluidized-bed combustion (CFBC) system as the main component of the Environmental Control Technology Laboratory; (3) Developing a combustion technology for co-firing municipal solid waste (MSW), agricultural waste, and refuse-derived fuel (RDF) with high sulfur coals; (4) Developing a control strategy for gaseous emissions, including NO{sub x}, SO{sub 2}, organic compounds, and heavy metals; and (5) Developing new mercury capturing sorbents and new

Chemical and ecotoxicological characterization of ashes obtained from sewage sludge combustion in a fluidised-bed reactor.

Science.gov (United States)

Lapa, N; Barbosa, R; Lopes, M H; Mendes, B; Abelha, P; Boavida, D; Gulyurtlu, I; Oliveira, J Santos

2007-08-17

In 1999, the DEECA/INETI and the UBiA/FCT/UNL started a researching project on the partition of heavy metals during the combustion of stabilised sewage sludge (Biogran), in a fluidised-bed reactor, and on the quality of the bottom ashes and fly ashes produced. This project was entitled Bimetal and was funded by the Portuguese Foundation for Science and Technology. In this paper only the results on the combustion of Biogran are reported. The combustion process was performed in two different trials, in which different amounts of sewage sludge and time of combustion were applied. Several ash samples were collected from the bed (bottom ashes) and from two cyclones (first cyclone and second cyclone ashes). Sewage sludge, bed material (sand) and ash samples were submitted to the leaching process defined in the European leaching standard EN 12457-2. The eluates were characterized for a set of inorganic chemical species. The ecotoxicological levels of the eluates were determined for two biological indicators (Vibrio fischeri and Daphnia magna). The results were compared with the limit values of the CEMWE French Regulation. The samples were also ranked according to an index based on the chemical characterization of the eluates. It was observed an increase of the concentration of metals along the combustion system. The ashes trapped in the second cyclone, for both combustion trials, showed the highest concentration of metals in the eluates. Chemically, the ashes of the second cyclone were the most different ones. In the ecotoxicological point of view, the ecotoxicity levels of the eluates of the ashes, for both combustion cycles, did not follow the same pattern as observed for the chemical characterization. The ashes of the first cyclone showed the highest ecotoxicity levels for V. fischeri and D. magna. This difference on chemical and ecotoxicological results proves the need for performing both chemical and ecotoxicological characterizations of the sub-products of such type

Chemical and ecotoxicological characterization of ashes obtained from sewage sludge combustion in a fluidised-bed reactor

Energy Technology Data Exchange (ETDEWEB)

Lapa, N. [Environmental Biotechnology Researching Unit (UBiA), Faculty of Science and Technology (FCT), New University of Lisbon - UNL, Ed. Departamental, piso 3, gabinete 377, Quinta da Torre, 2829-516 Caparica (Portugal)]. E-mail: ncsn@fct.unl.pt; Barbosa, R. [Environmental Biotechnology Researching Unit (UBiA), Faculty of Science and Technology (FCT), New University of Lisbon - UNL, Ed. Departamental, piso 3, gabinete 377, Quinta da Torre, 2829-516 Caparica (Portugal); Lopes, M.H. [National Institute of Engineering, Technology and Innovation (INETI), Department of Energetic Engineering and Environmental Control (DEECA). Edificio J, Estrada do Paco do Lumiar, 22, 1649-038 Lisbon (Portugal); Mendes, B. [Environmental Biotechnology Researching Unit (UBiA), Faculty of Science and Technology (FCT), New University of Lisbon - UNL, Ed. Departamental, piso 3, gabinete 377, Quinta da Torre, 2829-516 Caparica (Portugal); Abelha, P. [National Institute of Engineering, Technology and Innovation (INETI), Department of Energetic Engineering and Environmental Control (DEECA). Edificio J, Estrada do Paco do Lumiar, 22, 1649-038 Lisbon (Portugal); Gulyurtlu, I. [National Institute of Engineering, Technology and Innovation (INETI), Department of Energetic Engineering and Environmental Control (DEECA). Edificio J, Estrada do Paco do Lumiar, 22, 1649-038 Lisbon (Portugal); Santos Oliveira, J. [Environmental Biotechnology Researching Unit (UBiA), Faculty of Science and Technology (FCT), New University of Lisbon - UNL, Ed. Departamental, piso 3, gabinete 377, Quinta da Torre, 2829-516 Caparica (Portugal)

2007-08-17

In 1999, the DEECA/INETI and the UBiA/FCT/UNL started a researching project on the partition of heavy metals during the combustion of stabilised sewage sludge (Biogran[reg]), in a fluidised-bed reactor, and on the quality of the bottom ashes and fly ashes produced. This project was entitled Bimetal and was funded by the Portuguese Foundation for Science and Technology. In this paper only the results on the combustion of Biogran[reg]) are reported. The combustion process was performed in two different trials, in which different amounts of sewage sludge and time of combustion were applied. Several ash samples were collected from the bed (bottom ashes) and from two cyclones (first cyclone and second cyclone ashes). Sewage sludge, bed material (sand) and ash samples were submitted to the leaching process defined in the European leaching standard EN 12457-2. The eluates were characterized for a set of inorganic chemical species. The ecotoxicological levels of the eluates were determined for two biological indicators (Vibrio fischeri and Daphnia magna). The results were compared with the limit values of the CEMWE French Regulation. The samples were also ranked according to an index based on the chemical characterization of the eluates. It was observed an increase of the concentration of metals along the combustion system. The ashes trapped in the second cyclone, for both combustion trials, showed the highest concentration of metals in the eluates. Chemically, the ashes of the second cyclone were the most different ones. In the ecotoxicological point of view, the ecotoxicity levels of the eluates of the ashes, for both combustion cycles, did not follow the same pattern as observed for the chemical characterization. The ashes of the first cyclone showed the highest ecotoxicity levels for V. fischeri and D. magna. This difference on chemical and ecotoxicological results proves the need for performing both chemical and ecotoxicological characterizations of the sub

Chemical and ecotoxicological characterization of ashes obtained from sewage sludge combustion in a fluidised-bed reactor

International Nuclear Information System (INIS)

Lapa, N.; Barbosa, R.; Lopes, M.H.; Mendes, B.; Abelha, P.; Gulyurtlu, I.; Santos Oliveira, J.

2007-01-01

In 1999, the DEECA/INETI and the UBiA/FCT/UNL started a researching project on the partition of heavy metals during the combustion of stabilised sewage sludge (Biogran[reg]), in a fluidised-bed reactor, and on the quality of the bottom ashes and fly ashes produced. This project was entitled Bimetal and was funded by the Portuguese Foundation for Science and Technology. In this paper only the results on the combustion of Biogran[reg]) are reported. The combustion process was performed in two different trials, in which different amounts of sewage sludge and time of combustion were applied. Several ash samples were collected from the bed (bottom ashes) and from two cyclones (first cyclone and second cyclone ashes). Sewage sludge, bed material (sand) and ash samples were submitted to the leaching process defined in the European leaching standard EN 12457-2. The eluates were characterized for a set of inorganic chemical species. The ecotoxicological levels of the eluates were determined for two biological indicators (Vibrio fischeri and Daphnia magna). The results were compared with the limit values of the CEMWE French Regulation. The samples were also ranked according to an index based on the chemical characterization of the eluates. It was observed an increase of the concentration of metals along the combustion system. The ashes trapped in the second cyclone, for both combustion trials, showed the highest concentration of metals in the eluates. Chemically, the ashes of the second cyclone were the most different ones. In the ecotoxicological point of view, the ecotoxicity levels of the eluates of the ashes, for both combustion cycles, did not follow the same pattern as observed for the chemical characterization. The ashes of the first cyclone showed the highest ecotoxicity levels for V. fischeri and D. magna. This difference on chemical and ecotoxicological results proves the need for performing both chemical and ecotoxicological characterizations of the sub

Test plan for measuring ventilation rates and combustible gas levels in RPP active catch tanks

Energy Technology Data Exchange (ETDEWEB)

NGUYEN, D.M.

1999-06-03

The purpose of this test is to provide an initial screening of combustible gas concentrations in catch tanks that currently are operated by River Protection Project (RPP). The data will be used to determine whether or not additional data will be needed for closure of the flammable gas unreviewed safety question for these facilities. This test will involve field measurements of ammonia, organic vapor, and total combustible gas levels in the headspace of the catch tanks. If combustible gas level in a tank exceeds an established threshold, gas samples will be collected in SUMMA canisters for more extensive laboratory analysis. In addition, ventilation rates of some catch tanks will be measured to evaluate removal of flammable gas by air flow through the tanks.

Milliken Station Demonstration Project FDG retrofit update

Energy Technology Data Exchange (ETDEWEB)

Alder, R.C.; Jackson, C.E.; O`Dea, D.T. [and others

1994-12-31

The Milliken Clean Coal Demonstration Project is one of the nine Clean Coal Projects selected for funding in Round 4 of the U.S. DOE`s Clean Coal Demonstration Program. The project`s sponsor is New York State Electric and Gas Corporation (NYSEG). Project team members include CONSOL Inc., Saarberg-Holter-Umwelttechnik (SHU), NALCO/FuelTech, Stebbins Engineering and Manufacturing Co., DHR Technologies, and CE Air Preheater. Gilbert/Commonwealth is the Architect/Engineer and Construction Manager for the flue gas desulfurization (FGD) retrofit. The project will provide full-scale demonstration of a combination of innovative emission-reducing technologies and plant upgraded for the control of sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) emissions from a coal-fired steam generator without a significant loss of station efficiency. The overall project goals are the following: 98% SO{sub 2} removal efficiency using limestone while burning high sulfur coal; up to 70% NO{sub x} reduction using the NOXOUT selective non-catalytic reduction (SNCR) technology in conjunction with combustion modifications; minimization of solid waste by producing marketable by-products including commercial grade gypsum, calcium chloride, and fly ash; zero wastewater discharge; maintenance of station efficiency by using a high efficiency heat-pipe air heater system and a low-power-consuming scrubber system. The demonstration project is being conducted at NYSEG`s Milliken Station, located in Lansing, New York. Milliken Station has two 150-MWe pulverized coal-fired units built in the 1950s by Combustion Engineering. The SHU FGD process and the combustion modifications are being installed on both units, but the NOXOUT process, Plant Economic Optimization Advisor (PEOA), and the high-efficiency air heater system will be installed on only one unit.

LIEKKI and JALO: Combustion and fuel conversion

Science.gov (United States)

Grace, Thomas M.; Renz, Ulrich; Sarofim, Adel F.

LIEKKI and JALO are well conceived and structured programs designed to strengthen Finland's special needs in combustion and gasification to utilize a diversity of fuels, increase the ratio of electrical to heat output, and to support the export market. Started in 1988, these two programs provide models of how universities, Technical research center's laboratories (VTT's), and industry can collaborate successfully in order to achieve national goals. The research is focused on long term goals in certain targeted niche areas. This is an effective way to use limited resources. The niche areas were chosen in a rational manner and appear to be appropriate for Finland. The LIEKKl and JALO programs have helped pull together research efforts that were previously more fragmented. For example, the combustion modeling area still appears fragmented. Individual project objectives should be tied to program goals at a very early stage to provide sharper focusing to the research. Both the LIEKKl and JALO programs appear to be strongly endorsed by industry. Industrial members of the Executive Committees were very supportive of these programs. There are good mechanisms for technology transfer in place, and the programs provide opportunities to establish good interfaces between industrial people and the individual researchers. The interest of industry is shown by the large number of applied projects that are supported by industry. This demonstrates the relevancy of the programs. There is a strong interaction between the JALO program and industry in black liquor gasification.

Indoor combustion and asthma.

Science.gov (United States)

Belanger, Kathleen; Triche, Elizabeth W

2008-08-01

Indoor combustion produces both gases (eg, nitrogen dioxide, carbon monoxide) and particulate matter that may affect the development or exacerbation of asthma. Sources in the home include both heating devices (eg, fireplaces, woodstoves, kerosene heaters, flued [ie, vented] or nonflued gas heaters) and gas stoves for cooking. This article highlights the recent literature examining associations between exposure to indoor combustion and asthma development and severity. Since asthma is a chronic condition affecting both children and adults, both age groups are included in this article. Overall, there is some evidence of an association between exposure to indoor combustion and asthma, particularly asthma symptoms in children. Some sources of combustion such as coal stoves have been more consistently associated with these outcomes than other sources such as woodstoves.

Numerical investigation of biogas flameless combustion

International Nuclear Information System (INIS)

Hosseini, Seyed Ehsan; Bagheri, Ghobad; Wahid, Mazlan Abdul

2014-01-01

Highlights: • Fuel consumption decreases from 3.24 g/s in biogas conventional combustion to 1.07 g/s in flameless mode. • The differences between reactants and products temperature intensifies irreversibility in traditional combustion. • The temperature inside the chamber is uniform in biogas flameless mode and exergy loss decreases in this technique. • Low O 2 concentration in the flameless mode confirms a complete and quick combustion process in flameless regime. - Abstract: The purpose of this investigation is to analyze combustion characteristics of biogas flameless mode based on clean technology development strategies. A three dimensional (3D) computational fluid dynamic (CFD) study has been performed to illustrate various priorities of biogas flameless combustion compared to the conventional mode. The effects of preheated temperature and wall temperature, reaction zone and pollutant formation are observed and the impacts of combustion and turbulence models on numerical results are discussed. Although preheated conventional combustion could be effective in terms of fuel consumption reduction, NO x formation increases. It has been found that biogas is not eligible to be applied in furnace heat up due to its low calorific value (LCV) and it is necessary to utilize a high calorific value fuel to preheat the furnace. The required enthalpy for biogas auto-ignition temperature is supplied by enthalpy of preheated oxidizer. In biogas flameless combustion, the mean temperature of the furnace is lower than traditional combustion throughout the chamber. Compared to the biogas flameless combustion with uniform temperature, very high and fluctuated temperatures are recorded in conventional combustion. Since high entropy generation intensifies irreversibility, exergy loss is higher in biogas conventional combustion compared to the biogas flameless regime. Entropy generation minimization in flameless mode is attributed to the uniform temperature inside the chamber

Materials for High-Temperature Catalytic Combustion

Energy Technology Data Exchange (ETDEWEB)

Ersson, Anders

2003-04-01

Catalytic combustion is an environmentally friendly technique to combust fuels in e.g. gas turbines. Introducing a catalyst into the combustion chamber of a gas turbine allows combustion outside the normal flammability limits. Hence, the adiabatic flame temperature may be lowered below the threshold temperature for thermal NO{sub X} formation while maintaining a stable combustion. However, several challenges are connected to the application of catalytic combustion in gas turbines. The first part of this thesis reviews the use of catalytic combustion in gas turbines. The influence of the fuel has been studied and compared over different catalyst materials. The material section is divided into two parts. The first concerns bimetallic palladium catalysts. These catalysts showed a more stable activity compared to their pure palladium counterparts for methane combustion. This was verified both by using an annular reactor at ambient pressure and a pilot-scale reactor at elevated pressures and flows closely resembling the ones found in a gas turbine combustor. The second part concerns high-temperature materials, which may be used either as active or washcoat materials. A novel group of materials for catalysis, i.e. garnets, has been synthesised and tested in combustion of methane, a low-heating value gas and diesel fuel. The garnets showed some interesting abilities especially for combustion of low-heating value, LHV, gas. Two other materials were also studied, i.e. spinels and hexa aluminates, both showed very promising thermal stability and the substituted hexa aluminates also showed a good catalytic activity. Finally, deactivation of the catalyst materials was studied. In this part the sulphur poisoning of palladium, platinum and the above-mentioned complex metal oxides has been studied for combustion of a LHV gas. Platinum and surprisingly the garnet were least deactivated. Palladium was severely affected for methane combustion while the other washcoat materials were

Black liquor combustion validated recovery boiler modeling, five-year report

Energy Technology Data Exchange (ETDEWEB)

Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

1996-08-01

The objective of this project was to develop a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The project originated in October 1990 and was scheduled to run for four years. At that time, there was considerable emphasis on developing accurate predictions of the physical carryover of macroscopic particles of partially burnt black liquor and smelt droplets out of the furnace, since this was seen as the main cause of boiler plugging. This placed a major emphasis on gas flow patterns within the furnace and on the mass loss rates and swelling and shrinking rates of burning black liquor drops. As work proceeded on developing the recovery boiler furnace model, it became apparent that some recovery boilers encounter serious plugging problems even when physical carryover was minimal. After the original four-year period was completed, the project was extended to address this issue. The objective of the extended project was to improve the utility of the models by including the black liquor chemistry relevant to air emissions predictions and aerosol formation, and by developing the knowledge base and computational tools to relate furnace model outputs to fouling and plugging of the convective sections of the boilers. The work done to date includes CFD model development and validation, acquisition of information on black liquor combustion fundamentals and development of improved burning models, char bed model development, and model application and simplification.

Large eddy simulation and combustion instabilities; Simulation des grandes echelles et instabilites de combustion

Energy Technology Data Exchange (ETDEWEB)

Lartigue, G.

2004-11-15

The new european laws on pollutants emission impose more and more constraints to motorists. This is particularly true for gas turbines manufacturers, that must design motors operating with very fuel-lean mixtures. Doing so, pollutants formation is significantly reduced but the problem of combustion stability arises. Actually, combustion regimes that have a large excess of air are naturally more sensitive to combustion instabilities. Numerical predictions of these instabilities is thus a key issue for many industrial involved in energy production. This thesis work tries to show that recent numerical tools are now able to predict these combustion instabilities. Particularly, the Large Eddy Simulation method, when implemented in a compressible CFD code, is able to take into account the main processes involved in combustion instabilities, such as acoustics and flame/vortex interaction. This work describes a new formulation of a Large Eddy Simulation numerical code that enables to take into account very precisely thermodynamics and chemistry, that are essential in combustion phenomena. A validation of this work will be presented in a complex geometry (the PRECCINSTA burner). Our numerical results will be successfully compared with experimental data gathered at DLR Stuttgart (Germany). Moreover, a detailed analysis of the acoustics in this configuration will be presented, as well as its interaction with the combustion. For this acoustics analysis, another CERFACS code has been extensively used, the Helmholtz solver AVSP. (author)

Experimental results with hydrogen fueled internal combustion engines

Science.gov (United States)

De Boer, P. C. T.; Mclean, W. J.; Homan, H. S.

1975-01-01

The paper focuses on the most important experimental findings for hydrogen-fueled internal combustion engines, with particular reference to the application of these findings to the assessment of the potential of hydrogen engines. Emphasis is on the various tradeoffs that can be made, such as between maximum efficiency, maximum power, and minimum NO emissions. The various possibilities for induction and ignition are described. Some projections are made about areas in which hydrogen engines may find their initial application and about optimum ways to design such engines. It is shown that hydrogen-fueled reciprocal internal combustion engines offer important advantages with respect to thermal efficiency and exhaust emissions. Problems arising from preignition can suitably be avoided by restricting the fuel-air equivalence ratio to values below about 0.5. The direct cylinder injection appears to be a very attractive way to operate the engine, because it combines a wide range of possible power outputs with a high thermal efficiency and very low NO emissions at part loads.

Combustion pressure-based engine management system

Energy Technology Data Exchange (ETDEWEB)

Mueller, R.; Hart, M. [DaimlerChrysler, Stuttart (Germany); Truscott, A.; Noble, A. [Ricardo, Shoreham-by-Sea (United Kingdom); Kroetz, G.; Richter, C. [DaimlerChrysler, Munchen (Germany); Cavalloni, C. [Kistler Instruments AG, Winterthur (Switzerland)

2000-07-01

In order to fulfill future emissions and OBD regulations, whilst meeting increasing demands for driveability and refinement, new technologies for SI engines have to be found in terms of sensors and algorithms for engine control units. One promising way, explored in the AENEAS collaborative project between DaimlerChrysler, Kistler, Ricardo and the European Commission, is to optimize the behavior of the system by using in-cylinder measurements and analysing them with modern control algorithms. In this paper a new engine management system based on combustion pressure sensing is presented. The pressure sensor is designed to give a reliable and accurate signal of the full pressure trace during a working cycle. With the application of new technologies low cost manufacturing appears to be achievable, so that an application in mass production can be considered. Furthermore, model-based algorithms were developed to allow optimal control of the engine based on the in-cylinder measurements. The algorithms incorporate physical principles to improve efficiency, emissions and to reduce the parameterisation effort. In the paper, applications of the combustion pressure signal for air mass estimation, knock detection, ignition control cam phase detection and diagnosis are discussed. (author)

Manifold methods for methane combustion

Energy Technology Data Exchange (ETDEWEB)

Yang, B.; Pope, S.B. [Cornell Univ., Ithaca, NY (United States)

1995-10-01

Great progresses have been made in combustion research, especially, the computation of laminar flames and the probability density function (PDF) method in turbulent combustion. For one-dimensional laminar flames, by considering the transport mechanism, the detailed chemical kinetic mechanism and the interactions between these two basic processes, today it is a routine matter to calculate flame velocities, extinction, ignition, temperature, and species distributions from the governing equations. Results are in good agreement with those obtained for experiments. However, for turbulent combustion, because of the complexities of turbulent flow, chemical reactions, and the interaction between them, in the foreseeable future, it is impossible to calculate the combustion flow field by directly integrating the basic governing equations. So averaging and modeling are necessary in turbulent combustion studies. Averaging, on one hand, simplifies turbulent combustion calculations, on the other hand, it introduces the infamous closure problems, especially the closure problem with chemical reaction terms. Since in PDF calculations of turbulent combustion, the averages of the chemical reaction terms can be calculated, PDF methods overcome the closure problem with the reaction terms. It has been shown that the PDF method is a most promising method to calculate turbulent combustion. PDF methods have been successfully employed to calculate laboratory turbulent flames: they can predict phenomena such as super equilibrium radical levels, and local extinction. Because of these advantages, PDF methods are becoming used increasingly in industry combustor codes.

Facilitating Students' Conceptual Change and Scientific Reasoning Involving the Unit of Combustion

Science.gov (United States)

Lee, Chin-Quen; She, Hsiao-Ching

2010-01-01

This article reports research from a 3 year digital learning project to unite conceptual change and scientific reasoning in the learning unit of combustion. One group of students had completed the course combining conceptual change and scientific reasoning. The other group of students received conventional instruction. In addition to the…

Behaviour of Inorganic Constituents of Municipal Sewage Sludge during Fluidized-Bed Combustion.

Czech Academy of Sciences Publication Activity Database

Hartman, Miloslav; Pohořelý, Michael; Trnka, Otakar

2007-01-01

Roč. 61, 3 (2007) , s. 181-185 ISSN 0366-6352 R&D Projects: GA AV ČR(CZ) IAA4072201 Institutional research plan: CEZ:AV0Z40720504 Keywords : sewage sludge * heavy metals * fluidized-bed combustion Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 0.367, year: 2007

Combustion Byproducts Recycling Consortium

Energy Technology Data Exchange (ETDEWEB)

Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

2008-08-31

The Combustion Byproducts Recycling Consortium (CBRC) program was developed as a focused program to remove and/or minimize the barriers for effective management of over 123 million tons of coal combustion byproducts (CCBs) annually generated in the USA. At the time of launching the CBRC in 1998, about 25% of CCBs were beneficially utilized while the remaining was disposed in on-site or off-site landfills. During the ten (10) year tenure of CBRC (1998-2008), after a critical review, 52 projects were funded nationwide. By region, the East, Midwest, and West had 21, 18, and 13 projects funded, respectively. Almost all projects were cooperative projects involving industry, government, and academia. The CBRC projects, to a large extent, successfully addressed the problems of large-scale utilization of CCBs. A few projects, such as the two Eastern Region projects that addressed the use of fly ash in foundry applications, might be thought of as a somewhat smaller application in comparison to construction and agricultural uses, but as a novel niche use, they set the stage to draw interest that fly ash substitution for Portland cement might not attract. With consideration of the large increase in flue gas desulfurization (FGD) gypsum in response to EPA regulations, agricultural uses of FGD gypsum hold promise for large-scale uses of a product currently directed to the (currently stagnant) home construction market. Outstanding achievements of the program are: (1) The CBRC successfully enhanced professional expertise in the area of CCBs throughout the nation. The enhanced capacity continues to provide technology and information transfer expertise to industry and regulatory agencies. (2) Several technologies were developed that can be used immediately. These include: (a) Use of CCBs for road base and sub-base applications; (b) full-depth, in situ stabilization of gravel roads or highway/pavement construction recycled materials; and (c) fired bricks containing up to 30%-40% F

Development of a Premixed Combustion Capability for Scramjet Combustion Experiments

Science.gov (United States)

Rockwell, Robert D.; Goyne, Christopher P.; Rice, Brian E.; Chelliah, Harsha; McDaniel, James C.; Edwards, Jack R.; Cantu, Luca M. L.; Gallo, Emanuela C. A.; Cutler, Andrew D.; Danehy, Paul M.

2015-01-01

Hypersonic air-breathing engines rely on scramjet combustion processes, which involve high speed, compressible, and highly turbulent flows. The combustion environment and the turbulent flames at the heart of these engines are difficult to simulate and study in the laboratory under well controlled conditions. Typically, wind-tunnel testing is performed that more closely approximates engine testing rather than a careful investigation of the underlying physics that drives the combustion process. The experiments described in this paper, along with companion data sets being developed separately, aim to isolate the chemical kinetic effects from the fuel-air mixing process in a dual-mode scramjet combustion environment. A unique fuel injection approach is taken that produces a nearly uniform fuel-air mixture at the entrance to the combustor. This approach relies on the precombustion shock train upstream of the dual-mode scramjet combustor. A stable ethylene flame anchored on a cavity flameholder with a uniformly mixed combustor inflow has been achieved in these experiments allowing numerous companion studies involving coherent anti-Stokes Raman scattering (CARS), particle image velocimetry (PIV), and planar laser induced fluorescence (PLIF) to be performed.

Mathematical Modeling in Combustion Science

CERN Document Server

Takeno, Tadao

1988-01-01

An important new area of current research in combustion science is reviewed in the contributions to this volume. The complicated phenomena of combustion, such as chemical reactions, heat and mass transfer, and gaseous flows, have so far been studied predominantly by experiment and by phenomenological approaches. But asymptotic analysis and other recent developments are rapidly changing this situation. The contributions in this volume are devoted to mathematical modeling in three areas: high Mach number combustion, complex chemistry and physics, and flame modeling in small scale turbulent flow combustion.

Molten salt combustion of radioactive wastes

International Nuclear Information System (INIS)

Grantham, L.F.; McKenzie, D.E.; Richards, W.L.; Oldenkamp, R.D.

1976-01-01

The Atomics International Molten Salt Combustion Process reduces the weight and volume of combustible β-γ contaminated transuranic waste by utilizing air in a molten salt medium to combust organic materials, to trap particulates, and to react chemically with any acidic gases produced during combustion. Typically, incomplete combustion products such as hydrocarbons and carbon monoxide are below detection limits (i.e., 3 ) is directly related to the sodium chloride vapor pressure of the melt; >80% of the particulate is sodium chloride. Essentially all metal oxides (combustion ash) are retained in the melt, e.g., >99.9% of the plutonium, >99.6% of the europium, and >99.9% of the ruthenium are retained in the melt. Both bench-scale radioactive and pilot scale (50 kg/hr) nonradioactive combustion tests have been completed with essentially the same results. Design of three combustors for industrial applications are underway

Experimental study of improvement on combustion control of fluidized bed combustion chamber; Ryudosho shokyakuro no nenshosei no kaizen ni tsuite

Energy Technology Data Exchange (ETDEWEB)

Izumiya, T.; Baba, K.; Koshida, H.; Uetani, J.; Furuta, M.

1998-10-29

Nippon Steel Corporation has carried out an experimental study using the Yawata waste incinerator plant in order to improve combustion control of a fluidized bed combustion chamber. For controlling the forming of dioxin, combustion control is very important in addition to conventional methods. In this paper, we report two studies about improvements on combustion control. In the first study, we verified improvement on combustion control by modifying gas flow at the freeboard. The operational results of the experiments were studied using the numerical model of the combustion chamber. The modification of gas flow at freeboard was confirmed to be effective to obtain a compact design of fluidized bed combustion chamber for municipal waste. In the second, study we improved combustion control for sewage combustion with municipal waste. In burning municipal waste and sewage, it is especially required to take combustion control into careful consideration. In this experiment, we developed a new device for supplying sewage for the appropriate controlling combustion, and verified its effectiveness to combustion control and an effective reduction of dioxin. (author)

Oxygen enriched combustion system performance study. Phase 2: 100 percent oxygen enriched combustion in regenerative glass melters, Final report

Energy Technology Data Exchange (ETDEWEB)

Tuson, G.B.; Kobayashi, H.; Campbell, M.J.

1994-08-01

The field test project described in this report was conducted to evaluate the energy and environmental performance of 100% oxygen enriched combustion (100% OEC) in regenerative glass melters. Additional objectives were to determine other impacts of 100% OEC on melter operation and glass quality, and to verify on a commercial scale that an on-site Pressure Swing Adsorption oxygen plant can reliably supply oxygen for glass melting with low electrical power consumption. The tests constituted Phase 2 of a cooperative project between the United States Department of Energy, and Praxair, Inc. Phase 1 of the project involved market and technical feasibility assessments of oxygen enriched combustion for a range of high temperature industrial heating applications. An assessment of oxygen supply options for these applications was also performed during Phase 1, which included performance evaluation of a pilot scale 1 ton per day PSA oxygen plant. Two regenerative container glass melters were converted to 100% OEC operation and served as host sites for Phase 2. A 75 ton per day end-fired melter at Carr-Lowrey Glass Company in Baltimore, Maryland, was temporarily converted to 100% OEC in mid- 1990. A 350 tpd cross-fired melter at Gallo Glass Company in Modesto, California was rebuilt for permanent commercial operation with 100% OEC in mid-1991. Initially, both of these melters were supplied with oxygen from liquid storage. Subsequently, in late 1992, a Pressure Swing Adsorption oxygen plant was installed at Gallo to supply oxygen for 100% OEC glass melting. The particular PSA plant design used at Gallo achieves maximum efficiency by cycling the adsorbent beds between pressurized and evacuated states, and is therefore referred to as a Vacuum/Pressure Swing Adsorption (VPSA) plant.

Catalytic Combustion of Gasified Waste

Energy Technology Data Exchange (ETDEWEB)

Kusar, Henrik

2003-09-01

This thesis concerns catalytic combustion for gas turbine application using a low heating-value (LHV) gas, derived from gasified waste. The main research in catalytic combustion focuses on methane as fuel, but an increasing interest is directed towards catalytic combustion of LHV fuels. This thesis shows that it is possible to catalytically combust a LHV gas and to oxidize fuel-bound nitrogen (NH{sub 3}) directly into N{sub 2} without forming NO{sub x} The first part of the thesis gives a background to the system. It defines waste, shortly describes gasification and more thoroughly catalytic combustion. The second part of the present thesis, paper I, concerns the development and testing of potential catalysts for catalytic combustion of LHV gases. The objective of this work was to investigate the possibility to use a stable metal oxide instead of noble metals as ignition catalyst and at the same time reduce the formation of NO{sub x} In paper II pilot-scale tests were carried out to prove the potential of catalytic combustion using real gasified waste and to compare with the results obtained in laboratory scale using a synthetic gas simulating gasified waste. In paper III, selective catalytic oxidation for decreasing the NO{sub x} formation from fuel-bound nitrogen was examined using two different approaches: fuel-lean and fuel-rich conditions. Finally, the last part of the thesis deals with deactivation of catalysts. The various deactivation processes which may affect high-temperature catalytic combustion are reviewed in paper IV. In paper V the poisoning effect of low amounts of sulfur was studied; various metal oxides as well as supported palladium and platinum catalysts were used as catalysts for combustion of a synthetic gas. In conclusion, with the results obtained in this thesis it would be possible to compose a working catalytic system for gas turbine application using a LHV gas.

Volatiles combustion in fluidized beds. Final technical report, 4 September 1992--4 June 1995

Energy Technology Data Exchange (ETDEWEB)

Pendergrass, R.A. II; Raffensperger, C.; Hesketh, R.P.

1996-02-29

The goal of this project is to investigate the conditions in which volatiles will burn within both the dense and freeboard regions of fluidized beds. Experiments using a fluidized bed operated at incipient fluidization are being conducted to characterize the effect of particle surface area, initial fuel concentration, and particle type on the inhibition of volatiles within a fluidized bed. A review of the work conducted under this grant is presented in this Final Technical Report. Both experimental and theoretical work have been conducted to examine the inhibition of the combustion by the fluidized bed material, sand. It has been shown that particulate phase at incipient fluidization inhibits the combustion of propane by free radical destruction at the surface of sand particles within the particulate phase. The implications of these findings is that at bed temperatures lower than the critical temperatures, gas combustion can only occur in the bubble phase or at the top surface of a bubbling fluidized bed. In modeling fluidized bed combustion this inhibition by the particulate phase should be included.

Variability of total and mobile element contents in ash derived from biomass combustion

Czech Academy of Sciences Publication Activity Database

Száková, J.; Ochecová, P.; Hanzlíček, Tomáš; Perná, Ivana; Tlustoš, P.

2013-01-01

Roč. 67, č. 11 (2013), s. 1376-1385 ISSN 0366-6352 R&D Projects: GA MZe QI102A207 Institutional support: RVO:67985891 Keywords : biomass combustion * fly ash * bottom ash * element contents Subject RIV: CB - Analytical Chemistry, Separation Impact factor: 1.193, year: 2013

Combustion means for solid fuels

Energy Technology Data Exchange (ETDEWEB)

Murase, D.

1987-09-23

A combustion device for solid fuel, suitable for coal, coke, charcoal, coal-dust briquettes etc., comprising:- a base stand with an opening therein, an imperforate heat resistant holding board locatable to close said opening; a combustion chamber standing on the base stand with the holding board forming the base of the combustion chamber; a wiper arm pivoted for horizontal wiping movement over the upper surface of the holding board; an inlet means at a lower edge of said chamber above the base stand, and/or in a surrounding wall of said chamber, whereby combustion air may enter as exhaust gases leave the combustion chamber; an exhaust pipe for the exhaust gases; generally tubular gas-flow heat-exchange ducting putting the combustion chamber and exhaust pipe into communication; and means capable of moving the holding board into and out of the opening for removal of ash or other residue. The invention can be used for a heating system in a house or in a greenhouse or for a boiler.

Plasma igniter for internal-combustion engines

Science.gov (United States)

Breshears, R. R.; Fitzgerald, D. J.

1978-01-01

Hot ionized gas (plasma) ignites air/fuel mixture in internal combustion engines more effectively than spark. Electromagnetic forces propel plasma into combustion zone. Combustion rate is not limited by flame-front speed.

Characterization of aerosol emitted by the combustion of nanocomposites

Energy Technology Data Exchange (ETDEWEB)

Motzkus, C; Chivas-Joly, C; Guillaume, E; Ducourtieux, S; Saragoza, L; Lesenechal, D; Mace, T, E-mail: charles.motzkus@lne.fr [LNE, 29 Avenue Roger Hennequin, 78197 Trappes Cedex (France)

2011-07-06

Day after day, new applications using nanoparticles appear in industry, increasing the probability to find these particles in the workplace as well as in ambient air. As epidemiological studies have shown an association between increased particulate air pollution and adverse health effects in susceptible members of the population, it is particularly important to characterize aerosols emitted by different sources of emission, during the combustion of composites charged with nanoparticles for example. The present study is led in the framework of the NANOFEU project, supported by the French Research Agency (ANR), in order to characterize the fire behaviour of polymers charged with suitable nanoparticles and make an alternative to retardant systems usually employed. To determine the impact of these composites on the emission of airborne particles produced during their combustions, an experimental setup has been developed to measure the mass distribution in the range of 30 nm - 10 {mu}m and the number concentration of submicrometric particles of the produced aerosol. A comparison is performed on the aerosol emitted during the combustion of several polymers alone (PMMA, PA-6), polymers containing nanofillers (silica, alumina, and carbon nanotubes) and polymers containing both nanofillers and a conventional flame retardant system (ammonium polyphosphate). The results on the morphology of particles were also investigated using AFM.

Combustion and co-combustion of biomass in a bubbling fluidized bed boiler

NARCIS (Netherlands)

Khan, A.A.

2007-01-01

This PhD dissertation concerns the study of different aspects of biomass (co)-combustion in small-scale fluidized bed boilers for heat generation. The most renowned gaseous emissions from fluidized bed combustion, namely, CO and NO, are investigated with the help of experimental and theoretical

Combustion from basics to applications

CERN Document Server

Lackner, Maximilian; Winter, Franz

2013-01-01

Combustion, the process of burning, is defined as a chemical reaction between a combustible reactant (the fuel) and an oxidizing agent (such as air) in order to produce heat and in most cases light while new chemical species (e.g., flue gas components) are formed. This book covers a gap on the market by providing a concise introduction to combustion. Most of the other books currently available are targeted towards the experienced users and contain too many details and/or contain knowledge at a fairly high level. This book provides a brief and clear overview of the combustion basics, suitable f

CALLA ENERGY BIOMASS COFIRING PROJECT

International Nuclear Information System (INIS)

Unknown

2002-01-01

The Calla Energy Biomass Project, to be located in Estill County, Kentucky is to be conducted in two phases. The objective of Phase I is to evaluate the technical and economic feasibility of cofiring biomass-based gasification fuel-gas in a power generation boiler. Waste coal fines are to be evaluated as the cofired fuel. The project is based on the use of commercially available technology for feeding and gas cleanup that would be suitable for deployment in municipal, large industrial and utility applications. Define a combustion system for the biomass gasification-based fuel-gas capable of stable, low-NOx combustion over the full range of gaseous fuel mixtures, with low carbon monoxide emissions and turndown capabilities suitable for large-scale power generation applications. The objective for Phase II is to design, install and demonstrate the combined gasification and combustion system in a large-scale, long-term cofiring operation to promote acceptance and utilization of indirect biomass cofiring technology for large-scale power generation applications. During this Performance Period work efforts focused on completion of the Topical Report, summarizing the design and techno-economic study of the project's feasibility. GTI received supplemental authorization A002 from DOE contracts for additional work to be performed under Phase I that will further extend the performance period until the end of February 2003. The additional scope of work is for GTI to develop the gasification characteristics of selected feedstock for the project. To conduct this work, GTI will assemble an existing ''mini-bench'' unit to perform the gasification tests. The results of the test will be used to confirm or if necessary update the process design completed in Phase Task 1

Combustion of diesel fuel from a toxicological perspective. I. Origin of incomplete combustion products.

Science.gov (United States)

Scheepers, P T; Bos, R P

1992-01-01

Since the use of diesel engines is still increasing, the contribution of their incomplete combustion products to air pollution is becoming ever more important. The presence of irritating and genotoxic substances in both the gas phase and the particulate phase constituents is considered to have significant health implications. The quantity of soot particles and the particle-associated organics emitted from the tail pipe of a diesel-powered vehicle depend primarily on the engine type and combustion conditions but also on fuel properties. The quantity of soot particles in the emissions is determined by the balance between the rate of formation and subsequent oxidation. Organics are absorbed onto carbon cores in the cylinder, in the exhaust system, in the atmosphere and even on the filter during sample collection. Diesel fuel contains polycyclic aromatic hydrocarbons (PAHs) and some alkyl derivatives. Both groups of compounds may survive the combustion process. PAHs are formed by the combustion of crankcase oil or may be resuspended from engine and/or exhaust deposits. The conversion of parent PAHs to oxygenated and nitrated PAHs in the combustion chamber or in the exhaust system is related to the vast amount of excess combustion air that is supplied to the engine and the high combustion temperature. Whether the occurrence of these derivatives is characteristic for the composition of diesel engine exhaust remains to be ascertained. After the emission of the particles, their properties may change because of atmospheric processes such as aging and resuspension. The particle-associated organics may also be subject to (photo)chemical conversions or the components may change during sampling and analysis. Measurement of emissions of incomplete combustion products as determined on a chassis dynamometer provides knowledge of the chemical composition of the particle-associated organics. This knowledge is useful as a basis for a toxicological evaluation of the health hazards of

Staged, High-Pressure Oxy-Combustion Technology: Development and Scale-Up

Energy Technology Data Exchange (ETDEWEB)

Axelbaum, Richard; Xia, Fei; Gopan, Akshay; Kumfer, Benjamin

2014-09-30

Washington University in St. Louis and its project partners are developing a unique pressurized oxy-combustion process that aims to improve efficiency and costs by reducing the recycling of flue gas to near zero. Normally, in the absence of recycled flue gas or another inert gas, combustion of fuel and oxygen results in a dramatic increase in temperature of the combustion products and radiant energy, as compared to combustion in air. High heat flux to the boiler tubes may result in a tube surface temperatures that exceed safe operating limits. In the Staged Pressurized Oxy-Combustion (SPOC) process, this problem is addressed by staging the delivery of fuel and by novel combustion design that allows control of heat flux. In addition, the main mode of heat transfer to the steam cycle is by radiation, as opposed to convection. Therefore, the requirement for recycling large amounts of flue gas, for temperature control or to improve convective heat transfer, is eliminated, resulting in a reduction in auxiliary loads. The following report contains a detailed summary of scientific findings and accomplishments for the period of Oct. 1, 2013 to Sept 30, 2014. Results of ASPEN process and CFD modelling activities aimed at improving the SPOC process and boiler design are presented. The effects of combustion pressure and fuel moisture on the plant efficiency are discussed. Combustor pressure is found to have only a minor impact beyond 16 bar. For fuels with moisture content greater than approx 30%, e.g. coal/water slurries, the amount of latent heat of condensation exceeds that which can be utilized in the steam cycle and plant efficiency is reduced significantly. An improved boiler design is presented that achieves a more uniform heat flux profile. In addition, a fundamental study of radiation in high-temperature, high-pressure, particle-laden flows is summarized which provides a more complete understanding of heat transfer in these unusual conditions and to allow for

ABB.-Combustion Engineering's Experience in Nuclear Power Plant Engineering and Construction in Korea

International Nuclear Information System (INIS)

Veris, James W.

1992-01-01

The Yonggwang Nuclear Project is a milestone project for the Korean Nuclear Industry. The Project has the two objectives of obtaining self-reliance in all aspects of nuclear technology and of constructing two modern nuclear power plants under the leadership of Korean companies acting as prime contractors. ABB.-Combustion Engineering 1000 MW System 80+ TM was chosen in 1987 as the NSLS design to meet these two objectives. This paper summarizers the significant experiences and lessons learned through the first four years of the Project as well as identifying implications for such future projects. The unique challenges of the project are identified and an evaluation of the experiences in the technology, self-reliance program and in the design and manufacturing processes will be made

Analysis of potential combustion source impacts on acid deposition using an independently derived inventory. Volume I

Energy Technology Data Exchange (ETDEWEB)

1983-12-01

This project had three major objectives. The first objective was to develop a fossil fuel combustion source inventory (NO/sub x/, SO/sub x/, and hydrocarbon emissions) that would be relatively easy to use and update for analyzing the impact of combustion emissions on acid deposition in the eastern United States. The second objective of the project was to use the inventory data as a basis for selection of a number of areas that, by virtue of their importance in the acid rain issue, could be further studied to assess the impact of local and intraregional combustion sources. The third objective was to conduct an analysis of wet deposition monitoring data in the areas under study, along with pertinent physical characteristics, meteorological conditions, and emission patterns of these areas, to investigate probable relationships between local and intraregional combustion sources and the deposition of acidic material. The combustion source emissions inventory has been developed for the eastern United States. It characterizes all important area sources and point sources on a county-by-county basis. Its design provides flexibility and simplicity and makes it uniquely useful in overall analysis of emission patterns in the eastern United States. Three regions with basically different emission patterns have been identified and characterized. The statistical analysis of wet deposition monitoring data in conjunction with emission patterns, wind direction, and topography has produced consistent results for each study area and has demonstrated that the wet deposition in each area reflects the characteristics of the localized area around the monitoring sites (typically 50 to 150 miles). 8 references, 28 figures, 39 tables.

Internal combustion engine

Science.gov (United States)

Baker, Quentin A.; Mecredy, Henry E.; O'Neal, Glenn B.

1991-01-01

An improved engine is provided that more efficiently consumes difficult fuels such as coal slurries or powdered coal. The engine includes a precombustion chamber having a portion thereof formed by an ignition plug. The precombustion chamber is arranged so that when the piston is proximate the head, the precombustion chamber is sealed from the main cylinder or the main combustion chamber and when the piston is remote from the head, the precombustion chamber and main combustion chamber are in communication. The time for burning of fuel in the precombustion chamber can be regulated by the distance required to move the piston from the top dead center position to the position wherein the precombustion chamber and main combustion chamber are in communication.

Measurements, characterizing and reduction of dust during combustion of energy grain; Maetning, karaktaerisering och reduktion av stoft vid eldning av spannmaal

Energy Technology Data Exchange (ETDEWEB)

Roennbaeck, Marie; Johansson, Linda; Claesson, Frida; Johansson, Mathias

2008-07-01

There is a potential for cereal grain for combustion use in Sweden, as well as for other agricultural fuels with similar qualities. Today, grain is combusted mainly in small-scale appliances. As all fast growing crops, the ash content is higher compared to wood fuels, resulting in a higher emission of particles. There are no limits for particle emission from appliances smaller than 500 kW in Sweden today. Nevertheless, it is important to consider these emissions because dust from small scale combustion of biofuels is one of the larger sources of particles to air in Sweden and in Europe today. Lately, is has been observed that the ultra fine particles (< 0.1 mum) is a cause of increased mortality. During large-scale combustion, the flue gas is cleaned from particles by electrostatic or fabric filters. During small-scale combustion primary measures is preferred by economical reasons. Particles can be reduced by design of the appliances or control of the combustion process. It might also be possible to reduce particles by use of additives that ties the volatile matters to the bottom ash and/or causes them leave as gas instead of particles. The aim of this project is to characterize and reduce particle emissions from combustion of cereal grain by use of additives. Limestone and kaolin were tested in a burner for oat grain. Particle emission was measured as total dust, as mass size distributed and as number size distributed. Fuel, bottom ash and dust were characterized chemically. In the flue gas carbon monoxide, carbon dioxide, oxygen, hydrocarbons, nitrogen oxide, sulphur dioxide and hydrogen chloride was measured. Equilibrium calculations were performed for combustion with and without additives. The combustion was not negatively influenced by the additives. The results confirm that lime stone reduces emissions of acidifying and corrosive gases such as sulphur dioxide and hydrogen chloride. Both lime stone and kaolin increase the ash fusion temperature. Results from

Combustion stratification study of partially premixed combustion using Fourier transform analysis of OH* chemiluminescence images

KAUST Repository

Izadi Najafabadi, Mohammad

2017-11-06

A relatively high level of stratification (qualitatively: lack of homogeneity) is one of the main advantages of partially premixed combustion over the homogeneous charge compression ignition concept. Stratification can smooth the heat release rate and improve the controllability of combustion. In order to compare stratification levels of different partially premixed combustion strategies or other combustion concepts, an objective and meaningful definition of “stratification level” is required. Such a definition is currently lacking; qualitative/quantitative definitions in the literature cannot properly distinguish various levels of stratification. The main purpose of this study is to objectively define combustion stratification (not to be confused with fuel stratification) based on high-speed OH* chemiluminescence imaging, which is assumed to provide spatial information regarding heat release. Stratification essentially being equivalent to spatial structure, we base our definition on two-dimensional Fourier transforms of photographs of OH* chemiluminescence. A light-duty optical diesel engine has been used to perform the OH* bandpass imaging on. Four experimental points are evaluated, with injection timings in the homogeneous regime as well as in the stratified partially premixed combustion regime. Two-dimensional Fourier transforms translate these chemiluminescence images into a range of spatial frequencies. The frequency information is used to define combustion stratification, using a novel normalization procedure. The results indicate that this new definition, based on Fourier analysis of OH* bandpass images, overcomes the drawbacks of previous definitions used in the literature and is a promising method to compare the level of combustion stratification between different experiments.

Experimental research on combustion fluorine retention using calcium-based sorbents during coal combustion (II)

Energy Technology Data Exchange (ETDEWEB)

Qi, Q.; Ma, X.; Liu, J.; Wu, X.; Zhou, J.; Cen, K. [Liaoning Technical University, Fuxin (China). College of Resource and Environment Engineering

2008-12-15

Fluoride pollution produced by coal burning can be controlled with the calcium-based sorbent combustion fluorine technique in which calcium-based sorbents are mixed with the coal or sprayed into the combustion chamber. In a fixed bed tube furnace combustion experiment using one calcium-based natural mineral, limestone and one calcium-based building material, it was shown that the calcium-based sorbent particle grain size and pore structure have a big influence on the combustion fluorine retention effect. Reducing the calcium-based sorbent particle grain size and improving the calcium sorbent structure characteristics at very high temperature to enhance the fluorine retention effect is the important approach to the fluorine retention agent development. 8 refs., 1 fig., 5 tabs.

Analysis of the danger potential of H2/CO-combustion in the event of core meltdown

International Nuclear Information System (INIS)

Fischer, M.; Wagler, K.; Schwarzott, W.; Reineke, H.H.

1987-01-01

Based on an evaluation of the present state of knowledge and the experiments performed, several computing programs for the simulation of H 2 /CO combustion processes were developed within the scope of this project. Besides the one-compartment-model MOPED, based on the formulation of empirical and phenomenological connections, which was also used later to perform the pressure buildup analyses during various core meltdown (CM) scenarios, these were the first two attempts in respect of a fluid-dynamic description of the combustion processes that also takes the reaction kinetics into account (VERLA code, PISCES code). The analysis of the low (LP) and high (HP) pressure path CM conditions showed that no additional risk arises on the HP path due to potential H 2 combustion. In opposition to this maximum combustion gas fractions of 15% by vol. H 2 and 2.5% by vol. CO with assumption of complete enrichment in the containment result on the LP path. With 37 refs., 3 tabs., 78 figs [de

Pressurized Fluidized Bed Combustion of Sewage Sludge

Science.gov (United States)

Suzuki, Yoshizo; Nojima, Tomoyuki; Kakuta, Akihiko; Moritomi, Hiroshi

A conceptual design of an energy recovering system from sewage sludge was proposed. This system consists of a pressurized fluidized bed combustor, a gas turbine, and a heat exchanger for preheating of combustion air. Thermal efficiency was estimated roughly as 10-25%. In order to know the combustion characteristics of the sewage sludge under the elevated pressure condition, combustion tests of the dry and wet sewage sludge were carried out by using laboratory scale pressurized fluidized bed combustors. Combustibility of the sewage sludge was good enough and almost complete combustion was achieved in the combustion of the actual wet sludge. CO emission and NOx emission were marvelously low especially during the combustion of wet sewage sludge regardless of high volatile and nitrogen content of the sewage sludge. However, nitrous oxide (N2O) emission was very high. Hence, almost all nitrogen oxides were emitted as the form of N2O. From these combustion tests, we judged combustion of the sewage sludge with the pressurized fluidized bed combustor is suitable, and the conceptual design of the power generation system is available.

Fluidised-bed combustion of gasification residue

Energy Technology Data Exchange (ETDEWEB)

Korpela, T.; Kudjoi, A.; Hippinen, I.; Heinolainen, A.; Suominen, M.; Lu Yong [Helsinki Univ. of Technology (Finland). Lab of Energy Economics and Power Plant Engineering

1996-12-01

Partial gasification processes have been presented as possibilities for future power production. In the processes, the solid materials removed from a gasifier (i.e. fly ash and bed material) contain unburnt fuel and the fuel conversion is increased by burning this gasification residue either in an atmospheric or a pressurised fluidised-bed. In this project, which is a part of European JOULE 2 EXTENSION research programme, the main research objectives are the behaviour of calcium and sulphur compounds in solids and the emissions of sulphur dioxide and nitrogen oxides (NO{sub x} and N{sub 2}O) in pressurised fluidised-bed combustion of gasification residues. (author)

AIR EMISSIONS FROM SCRAP TIRE COMBUSTION

Science.gov (United States)

The report discusses air emissions from two types of scrap tire combustion: uncontrolled and controlled. Uncontrolled sources are open tire fires, which produce many unhealthful products of incomplete combustion and release them directly into the atmosphere. Controlled combustion...

Thermogravimetric analysis of biowastes during combustion

International Nuclear Information System (INIS)

Otero, M.; Sanchez, M.E.; Gomez, X.; Moran, A.

2010-01-01

The combustion of sewage sludge (SS), animal manure (AM) and the organic fraction of municipal solid waste (OFMSW) was assessed and compared with that of a semianthracite coal (SC) and of a PET waste by thermogravimetric (TG) analysis. Differences were found in the TG curves obtained for the combustion of these materials accordingly to their respective proximate analysis. Non-isothermal thermogravimetric data were used to assess the kinetics of the combustion of these biowastes. The present paper reports on the application of the Vyazovkin model-free isoconversional method for the evaluation of the activation energy necessary for the combustion of these biowastes. The activation energy related to SS combustion (129.1 kJ/mol) was similar to that corresponding to AM (132.5 kJ/mol) while the OFMSW showed a higher value (159.3 kJ/mol). These values are quite higher than the one determined in the same way for the combustion of SC (49.2 kJ/mol) but lower than that for the combustion of a PET waste (165.6 kJ/mol).

Straw combustion on slow-moving grates

DEFF Research Database (Denmark)

Kær, Søren Knudsen

2005-01-01

Combustion of straw in grate-based boilers is often associated with high emission levels and relatively poor fuel burnout. A numerical grate combustion model was developed to assist in improving the combustion performance of these boilers. The model is based on a one-dimensional ‘‘walking......-column’’ approach and includes the energy equations for both the fuel and the gas accounting for heat transfer between the two phases. The model gives important insight into the combustion process and provides inlet conditions for a computational fluid dynamics analysis of the freeboard. The model predictions...... indicate the existence of two distinct combustion modes. Combustion air temperature and mass flow-rate are the two parameters determining the mode. There is a significant difference in reaction rates (ignition velocity) and temperature levels between the two modes. Model predictions were compared...

Oxy-fuel combustion of solid fuels

DEFF Research Database (Denmark)

Toftegaard, Maja Bøg; Brix, Jacob; Jensen, Peter Arendt

2010-01-01

Oxy-fuel combustion is suggested as one of the possible, promising technologies for capturing CO2 from power plants. The concept of oxy-fuel combustion is removal of nitrogen from the oxidizer to carry out the combustion process in oxygen and, in most concepts, recycled flue gas to lower the flame...... provide additional options for improvement of process economics are however likewise investigated. Of particular interest is the change of the combustion process induced by the exchange of carbon dioxide and water vapor for nitrogen as diluent. This paper reviews the published knowledge on the oxy......-fuel process and focuses particularly on the combustion fundamentals, i.e. flame temperatures and heat transfer, ignition and burnout, emissions, and fly ash characteristics. Knowledge is currently available regarding both an entire oxy-fuel power plant and the combustion fundamentals. However, several...

Combustion Velocity of Benzine-Benzol-Air Mixtures in High-Speed Internal-Combustion Engines

Science.gov (United States)

Schnauffer, Kurt

1932-01-01

The present paper describes a device whereby rapid flame movement within an internal-combustion engine cylinder may be recorded and determined. By the aid of a simple cylindrical contact and an oscillograph the rate of combustion within the cylinder of an airplane engine during its normal operation may be measured for gas intake velocities of from 30 to 35 m/s and for velocities within the cylinder of from 20 to 25 m/s. With it the influence of mixture ratios, of turbulence, of compression ratio and kind of fuel on combustion velocity may be determined. Besides the determination of the influence of the above factors on combustion velocity, the degree of turbulence may also be determined. As a unit of reference in estimating the degree of turbulence, the intake velocity of the charge is chosen.

Use of combustible wastes as fuel

Energy Technology Data Exchange (ETDEWEB)

Kotler, V.R.; Salamov, A.A.

1983-01-01

Achievements of science and technology in creating and using units for combustion of wastes with recovery of heat of the escaping gases has been systematized and generalized. Scales and outlooks are examined for the use of general, industrial and agricultural waste as fuel, composition of the waste, questions of planning and operating units for combustion of solid refuse, settling of waste water and industrial and agricultural waste. Questions are covered for preparing them for combustion use in special units with recovery of heat and at ES, aspects of environmental protection during combustion of waste, cost indicators of the employed methods of recovering the combustible waste.

Fiscal 1999 report on result of the model project for systematization of high-efficiency combustion of by-product gas in ironworks. Part 1/2; 1999 nendo seitetsusho fukusei gas koritsu nensho system ka model jigyo. 1/2

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-09-01

For the purpose of curtailing energy consumption of the steel industry, a large energy consuming industry in China, a model project was carried out for high-efficiency combustion system for by-product gasses in ironworks, with the fiscal 1999 results reported. This project is such that, in the reheating furnaces consuming as fuels various combustible gasses produced in iron and steel making processes, systems to permit control of mixed-gas calorie and oxygen content in a reheating furnace are incorporated, with demonstration and dissemination performed for technologies on improving energy consumption efficiency. This year, site survey was conducted to obtain information needed for the basic design for the model project. The heat balance of the objective reheating furnaces revealed that the fuel consumption could be reduced by 6 to 35% by implementing the model project. Investigations were made also on the obstructive impurities contained in the by-product gasses and on the gas purification equipment, etc., which elucidated that the impurity content was about the same as that of the major ironworks in Korea and Taiwan and that there would be no problem if proper inspection and maintenance were carried out. As for the equipment and devices, the majority with software was manufactured and transported to Chingdao, China. Further, Chinese engineers were invited to Japan for technical training. (NEDO)

Combustion characteristics and influential factors of isooctane active-thermal atmosphere combustion assisted by two-stage reaction of n-heptane

Energy Technology Data Exchange (ETDEWEB)

Lu, Xingcai; Ji, Libin; Ma, Junjun; Zhou, Xiaoxin; Huang, Zhen [Key Lab. for Power Machinery and Engineering of MOE, Shanghai Jiao Tong University, 200240 Shanghai (China)

2011-02-15

This paper presents an experimental study on the isooctane active-thermal atmosphere combustion (ATAC) which is assisted by two-stage reaction of n-heptane. The active-thermal atmosphere is created by low- and high-temperature reactions of n-heptane which is injected at intake port, and isooctane is directly injected into combustion chamber near the top dead center. The effects of isooctane injection timing, active-thermal atmosphere intensity, overall equivalence ratio, and premixed ratio on combustion characteristics and emissions are investigated. The experimental results reveal that, the isooctane ignition and combustion can be classified to thermal atmosphere combustion, active atmosphere combustion, and active-thermal atmosphere combustion respectively according to the extent of n-heptane oxidation as well as effects of isooctane quenching and charge cooling. n-Heptane equivalence ratio, isooctane equivalence ratio and isooctane delivery advance angle are major control parameters. In one combustion cycle, the isooctane ignited and burned after those of n-heptane, and then this combustion phenomenon can also be named as dual-fuel sequential combustion (DFSC). The ignition timing of the overall combustion event is mainly determined by n-heptane equivalence ratio and can be controlled in flexibility by simultaneously adjusting isooctane equivalence ratio. The isooctane ignition regime, overall thermal efficiency, and NO{sub x} emissions show strong sensitivity to the fuel delivery advance angle between 20 CA BTDC and 25 CA BTDC. (author)

Simulation of low temperature combustion mechanism of different combustion-supporting agents in close-coupled DOC and DPF system.

Science.gov (United States)

Jiao, Penghao; Li, Zhijun; Li, Qiang; Zhang, Wen; He, Li; Wu, Yue

2018-07-01

In the coupled Diesel Oxidation Catalyst (DOC) and Diesel Particular Filter (DPF) system, soot cannot be completely removed by only using the passive regeneration. And DPF active regeneration is necessary. The research method in this paper is to spray different kinds of combustion-supporting agents to the DOC in the front of the DPF. Therefore, the low temperature combustion mechanism of different kinds of combustion-supporting agents in DOC was studied, in order to grasp the law of combustion in DOC, and the influence of follow-up emission on DPF removal of soot. During the study, CH 4 H 2 mixture and diesel (n-heptane + toluene) were used as combustion-supporting agents respectively. The simplified mechanisms of two kinds of gas mixtures used as the combustion-supporting agents in DPF have been constructed and testified in the paper. In this paper, the combustion and emission conditions of the two combustion-supporting agents were analyzed so as to meet the practical requirements of different working conditions. Copyright © 2017 ISA. Published by Elsevier Ltd. All rights reserved.

Internal combustion engines for alcohol motor fuels: a compilation of background technical information

Energy Technology Data Exchange (ETDEWEB)

Blaser, Richard

1980-11-01

This compilation, a draft training manual containing technical background information on internal combustion engines and alcohol motor fuel technologies, is presented in 3 parts. The first is a compilation of facts from the state of the art on internal combustion engine fuels and their characteristics and requisites and provides an overview of fuel sources, fuels technology and future projections for availability and alternatives. Part two compiles facts about alcohol chemistry, alcohol identification, production, and use, examines ethanol as spirit and as fuel, and provides an overview of modern evaluation of alcohols as motor fuels and of the characteristics of alcohol fuels. The final section compiles cross references on the handling and combustion of fuels for I.C. engines, presents basic evaluations of events leading to the use of alcohols as motor fuels, reviews current applications of alcohols as motor fuels, describes the formulation of alcohol fuels for engines and engine and fuel handling hardware modifications for using alcohol fuels, and introduces the multifuel engines concept. (LCL)

Strobes: An oscillatory combustion

NARCIS (Netherlands)

Corbel, J.M.L.; Lingen, J.N.J. van; Zevenbergen, J.F.; Gijzeman, O.L.J.; Meijerink, A.

2012-01-01

Strobe compositions belong to the class of solid combustions. They are mixtures of powdered ingredients. When ignited, the combustion front evolves in an oscillatory fashion, and flashes of light are produced by intermittence. They have fascinated many scientists since their discovery at the

Fifteenth combustion research conference

International Nuclear Information System (INIS)

1993-01-01

The BES research efforts cover chemical reaction theory, experimental dynamics and spectroscopy, thermodynamics of combustion intermediates, chemical kinetics, reaction mechanisms, combustion diagnostics, and fluid dynamics and chemically reacting flows. 98 papers and abstracts are included. Separate abstracts were prepared for the papers

The dynamic interaction between combustible renewables and waste consumption and international tourism: the case of Tunisia.

Science.gov (United States)

Ben Jebli, Mehdi; Ben Youssef, Slim; Apergis, Nicholas

2015-08-01

This paper employs the autoregressive distributed lag (ARDL) bounds methodological approach to investigate the relationship between economic growth, combustible renewables and waste consumption, carbon dioxide (CO2) emissions, and international tourism for the case of Tunisia spanning the period 1990-2010. The results from the Fisher statistic of both the Wald test and the Johansen test confirm the presence of a long-run relationship among the variables under investigation. The stability of estimated parameters has been tested, while Granger causality tests recommend a short-run unidirectional causality running from economic growth and combustible renewables and waste consumption to CO2 emissions, a bidirectional causality between economic growth and combustible renewables and waste consumption and unidirectional causality running from economic growth and combustible renewables and waste consumption to international tourism. In the long-run, the error correction terms confirm the presence of bidirectional causality relationships between economic growth, CO2 emissions, combustible renewables and waste consumption, and international tourism. Our long-run estimates show that combustible renewables and waste consumption increases international tourism, and both renewables and waste consumption and international tourism increase CO2 emissions and output. We recommend that (i) Tunisia should use more combustible renewables and waste energy as this eliminates wastes from touristic zones and increases the number of tourist arrivals, leading to economic growth, and (ii) a fraction of this economic growth generated by the increase in combustible renewables and waste consumption should be invested in clean renewable energy production (i.e., solar, wind, geothermal) and energy efficiency projects.

Numerical analysis for controlling mixture heterogeneity to reduce abrupt combustion in diesel PCCI combustion

Energy Technology Data Exchange (ETDEWEB)

Nishiwaki, Kazuie [Ritsumeikan University (Japan); Kojima, Takafumi [Takamatsu National College of Technology (Japan)

2010-07-01

In the energy sector, stringent regulations have been implemented on combustion emissions in order to address health and environmental concerns and help improve air quality. A novel combustion mode, premixed charge compression ignition (PCCI), can improve the emissions performance of an engine over that of conventional diesel. The aim of this research is to develop a model to analyze the mixture formation in the PCCI combustion mode. A numerical model was developed and was applied to an engine and the results were compared to experimental results. It was found that the model results are in agreement with the experimental results. This paper presented a novel LES computer model and demonstrated that it is efficient in predicting the mixture formation in the PCCI combustion mode.

Modeling and simulating combustion and generation of NOx

International Nuclear Information System (INIS)

Lazaroiu, Gheorghe

2007-01-01

This paper deals with the modeling and simulation of combustion processes and generation of NO x in a combustion chamber and boiler, with supplementary combustion in a gas turbine installation. The fuel burned in the combustion chamber was rich gas with a chemical composition more complex than natural gas. Pitcoal was used in the regenerative boiler. From the resulting combustion products, 17 compounds were retained, including nitrogen and sulphur compounds. Using the developed model, the simulation resulted in excess air for a temperature imposed at the combustion chamber exhaust. These simulations made it possible to determine the concentrations of combustion compounds with a variation in excess combustion. (author)

Multi-zone modelling of PCCI combustion

NARCIS (Netherlands)

Egüz, U.; Somers, L.M.T.; Leermakers, C.A.J.; Goey, de L.P.H.

2011-01-01

Early Direct Injection Premixed Charge Compression Ignition (EDI PCCI) combustion is a promising concept for the diesel combustion. Although EDI PCCI assures very low soot and NO xemission levels, the injection is uncoupled from combustion, which narrows down the operating conditions. The main

Combustor nozzle for a fuel-flexible combustion system

Science.gov (United States)

Haynes, Joel Meier [Niskayuna, NY; Mosbacher, David Matthew [Cohoes, NY; Janssen, Jonathan Sebastian [Troy, NY; Iyer, Venkatraman Ananthakrishnan [Mason, OH

2011-03-22

A combustor nozzle is provided. The combustor nozzle includes a first fuel system configured to introduce a syngas fuel into a combustion chamber to enable lean premixed combustion within the combustion chamber and a second fuel system configured to introduce the syngas fuel, or a hydrocarbon fuel, or diluents, or combinations thereof into the combustion chamber to enable diffusion combustion within the combustion chamber.

Establishment of Combustion Model for Isooctane HCCI Marine Diesel Engine and Research on the Combustion Characteristic

Directory of Open Access Journals (Sweden)

Li Biao

2016-01-01

Full Text Available The homogeneous charge compression ignition (HCCI combustion mode applied in marine diesel engine is expected to be one of alternative technologies to decrease nitrogen oxide (NOX emission and improve energy utilization rate. Applying the chemical-looping combustion (CLC mechanism inside the cylinder, a numerical study on the HCCI combustion process is performed taking a marine diesel engine as application object. The characteristic feature of combustion process is displayed. On this basis, the formation and emission of NOX are analyzed and discussed. The results indicate that the HCCI combustion mode always exhibit two combustion releasing heats: low-temperature reaction and high-temperature reaction. The combustion phase is divided into low-temperature reaction zone, high-temperature reaction zone and negative temperature coefficient (NTC zone. The operating conditions of the high compression ratio, high intake air temperature, low inlet pressure and small excess air coefficient would cause the high in-cylinder pressure which often leads engine detonation. The low compression ratio, low intake air temperature and big excess air coefficient would cause the low combustor temperature which is conducive to reduce NOX emissions. These technological means and operating conditions are expected to meet the NOX emissions limits in MARPOL73/78 Convention-Annex VI Amendment.

Emission and combustion characteristics of multiple stage diesel combustion; Nidan nensho ni yoru diesel kikan no nensho to haishutsubutsu tokusei

Energy Technology Data Exchange (ETDEWEB)

Hashizume, T; Miyamoto, T; Tsujimura, K [New A.C.E. Institute Co. Ltd., Tokyo (Japan); Kobayashi, S; Shimizu, K [Japan Automobile Research Institute, Tsukuba (Japan)

1997-10-01

A new concept of multiple stage diesel combustion was studied by means of engine test, combustion observation and numerical simulation, in order to reduce NOx emissions at high load conditions. With this concept, the premixed combustion occurs under the fuel lean conditions and the diffusion combustion occurs under the high temperature conditions. As seen in the result of combustion observation, a first stage combustion occurs with no luminous flame. A second stage combustion occurs with a luminous flame after very short ignition delay period. However the luminous flame is disappeared immediately. Because cylinder temperature is high, and hence soot oxidizes immediately. 5 refs., 11 figs., 1 tab.

76 FR 16646 - Circadian, Inc., Clean Energy Combustion, Inc. (n/k/a Clean Energy Combustion Systems, Inc...

Science.gov (United States)

2011-03-24

... SECURITIES AND EXCHANGE COMMISSION [File No. 500-1] Circadian, Inc., Clean Energy Combustion, Inc. (n/k/a Clean Energy Combustion Systems, Inc.), Collectible Concepts Group, Inc., Communitronics of... is a lack of current and accurate information concerning the securities of Clean Energy Combustion...

TOXIC SUBSTANCES FROM COAL COMBUSTION-A COMPREHENSIVE ASSESSMENT

Energy Technology Data Exchange (ETDEWEB)

C.L. Senior; F. Huggins; G.P. Huffman; N. Shah; N. Yap; J.O.L. Wendt; W. Seames; M.R. Ames; A.F. Sarofim; S. Swenson; J.S. Lighty; A. Kolker; R. Finkelman; C.A. Palmer; S.J. Mroczkowski; J.J. Helble; R. Mamani-Paco; R. Sterling; G. Dunham; S. Miller

2001-06-30

The Clean Air Act Amendments of 1990 identify a number of hazardous air pollutants (HAPs) as candidates for regulation. Should regulations be imposed on HAP emissions from coal-fired power plants, a sound understanding of the fundamental principles controlling the formation and partitioning of toxic species during coal combustion will be needed. With support from the National Energy Technology Laboratory (NETL), the Electric Power Research Institute, and VTT (Finland), Physical Sciences Inc. (PSI) has teamed with researchers from USGS, MIT, the University of Arizona (UA), the University of Kentucky (UK), the University of Connecticut (UC), the University of Utah (UU) and the University of North Dakota Energy and Environmental Research Center (EERC) to develop a broadly applicable emissions model useful to regulators and utility planners. The new Toxics Partitioning Engineering Model (ToPEM) will be applicable to all combustion conditions including new fuels and coal blends, low-NOx combustion systems, and new power generation plants. Development of ToPEM will be based on PSI's existing Engineering Model for Ash Formation (EMAF). The work discussed in this report covers the Phase II program. Five coals were studied (three in Phase I and two new ones in Phase II). In this work UK has used XAFS and Moessbauer spectroscopies to characterize elements in project coals. For coals, the principal use was to supply direct information about certain hazardous and other key elements (iron) to complement the more complete indirect investigation of elemental modes of occurrence being carried out by colleagues at USGS. Iterative selective leaching using ammonium acetate, HCl, HF, and HNO3, used in conjunction with mineral identification/quantification, and microanalysis of individual mineral grains, has allowed USGS to delineate modes of occurrence for 44 elements. The Phase II coals show rank-dependent systematic differences in trace-element modes of occurrence. The work at

Development and application of a high-temperature sampling probe for burning chamber conditions of fluidized-bed combustion; Korkean laempoetilan naeytteenottosondin kehittaeminen ja soveltaminen leijukerrospolton tulipesaeolosuhteisiin

Energy Technology Data Exchange (ETDEWEB)

Larjava, K.; Paerkkae, M.; Jormanainen, P.; Roine, J.; Paakkinen, K. [VTT Chemistry, Espoo (Finland); Linna, V. [VTT Energy, Jyvaeskylae (Finland)

1996-12-01

A sampling probe for the burning chamber conditions of fluidized-bed combustion will be developed in this project. The probe will be suitable for sampling vaporous heavy and alkali metals and other condensing compounds (e.g. chlorides) as well combustion gases and alternatively also flue gas particles at high temperatures. The knowledge gained with the probe will help understanding, developing and modeling combustion processes and will thus aid the manufacturers of the boilers. (author)

Effect of combustion characteristics on wall radiative heat flux in a 100 MWe oxy-coal combustion plant

Energy Technology Data Exchange (ETDEWEB)

Park, S.; Ryu, C. [Sungkyunkwan Univ., Suwon (Korea, Republic of). School of Mechanical Engineering; Chae, T.Y. [Sungkyunkwan Univ., Suwon (Korea, Republic of). School of Mechanical Engineering; Korea Institute of Industrial Technology, Cheonan (Korea, Republic of). Energy System R and D Group; Yang, W. [Korea Institute of Industrial Technology, Cheonan (Korea, Republic of). Energy System R and D Group; Kim, Y.; Lee, S.; Seo, S. [Korea Electric Power Research Institute (KEPRI), Daejeon (Korea, Republic of). Power Generation Lab.

2013-07-01

Oxy-coal combustion exhibits different reaction, flow and heat transfer characteristics from air-coal combustion due to different properties of oxidizer and flue gas composition. This study investigated the wall radiative heat flux (WRHF) of air- and oxy-coal combustion in a simple hexahedral furnace and in a 100 MWe single-wall-fired boiler using computational modeling. The hexahedral furnace had similar operation conditions with the boiler, but the coal combustion was ignored by prescribing the gas properties after complete combustion at the inlet. The concentrations of O{sub 2} in the oxidizers ranging between 26 and 30% and different flue gas recirculation (FGR) methods were considered in the furnace. In the hexahedral furnace, the oxy-coal case with 28% of O{sub 2} and wet FGR had a similar value of T{sub af} with the air-coal combustion case, but its WRHF was 12% higher. The mixed FGR case with about 27% O{sub 2} in the oxidizer exhibited the WRHF similar to the air-coal case. During the actual combustion in the 100 MWe boiler using mixed FGR, the reduced volumetric flow rates in the oxy-coal cases lowered the swirl strength of the burners. This stretched the flames and moved the high temperature region farther to the downstream. Due to this reason, the case with 30% O{sub 2} in the oxidizers achieved a WRHF close to that of air-coal combustion, although its adiabatic flame temperature (T{sub af}) and WHRF predicted in the simplified hexahedral furnace was 103 K and 10% higher, respectively. Therefore, the combustion characteristics and temperature distribution significantly influences the WRHF, which should be assessed to determine the ideal operating conditions of oxy- coal combustion. The choice of the weighted sum of gray gases model (WSGGM) was not critical in the large coal-fired boiler.

Infrared monitoring of combustion

International Nuclear Information System (INIS)

Bates, S.C.; Morrison, P.W. Jr.; Solomon, P.R.

1991-01-01

In this paper, the use of Fourier Transform Infrared (FT-IR) spectroscopy for combustion monitoring is described. A combination of emission, transmission, and reflection FT-IR spectroscopy yields data on the temperature and composition of the gases, surfaces and suspended particles in the combustion environment. Detection sensitivity of such trace exhaust gases as CO, CO 2 , SO 2 , NO x , and unburned hydrocarbons is at the ppm level. Tomographic reconstruction converts line-of-sight measurements into spatially resolved temperature and concentration data. Examples from various combustion processes are used to demonstrate the capabilities of the technique. Industrial measurements are described that have been performed directly in the combustion zone and in the exhaust duct of a large chemical recovery boiler. Other measurements of hot slag show how FT-IR spectroscopy can determine the temperature and optical properties of surfaces. In addition, experiments with water droplets show that transmission FT-IR data yield spectra that characterize particle size and number density

Control device for combustible gas concentration

International Nuclear Information System (INIS)

Osawa, Yasuo.

1988-01-01

Purpose: To control the concentration of combustible gases such as hydrogen evolved in a reactor container upon loss-of-coolant accidents. Constitution: Combustible gases evolved from the lower area of a drywell in which a combustible atmosphere is liable to be formed locally are taken out through a take-out pipeway to the outside of a reactor container and processed by a hydrogen-oxygen recombiner. Combustible gases in other areas of the drywell are also introduced to the lower area of the drywell and then taken-out externally for procession. Further, combustible gases in the suppression chamber are introduced by the opening of a vacuum breaking valve through a gas supply pipe to the lower area of the drywell and fluids in the drywell are stirred and diluted with fluids exhausted from the gas supply pipe. Disposition of such take-out pipeway and gas supply pipe can reduce the possibility of forming local combustible atmosphere to improve the integrity of the reactor container. (Kamimura, M.)

Techniques de combustion Combustin Techniques

Directory of Open Access Journals (Sweden)

Perthuis E.

2006-11-01

Full Text Available L'efficacité d'un processus de chauffage par flamme est étroitement liée à la maîtrise des techniques de combustion. Le brûleur, organe essentiel de l'équipement de chauffe, doit d'une part assurer une combustion complète pour utiliser au mieux l'énergie potentielle du combustible et, d'autre part, provoquer dans le foyer les conditions aérodynamiques les plus propices oux transferts de chaleur. En s'appuyant sur les études expérimentales effectuées à la Fondation de Recherches Internationales sur les Flammes (FRIF, au Groupe d'Étude des Flammes de Gaz Naturel (GEFGN et à l'Institut Français du Pétrole (IFP et sur des réalisations industrielles, on présente les propriétés essentielles des flammes de diffusion aux combustibles liquides et gazeux obtenues avec ou sans mise en rotation des fluides, et leurs répercussions sur les transferts thermiques. La recherche des températures de combustion élevées conduit à envisager la marche à excès d'air réduit, le réchauffage de l'air ou son enrichissement à l'oxygène. Par quelques exemples, on évoque l'influence de ces paramètres d'exploitation sur l'économie possible en combustible. The efficiency of a flame heating process is closely linked ta the mastery of, combustion techniques. The burner, an essential element in any heating equipment, must provide complete combustion sa as to make optimum use of the potential energy in the fuel while, at the same time, creating the most suitable conditions for heat transfers in the combustion chamber. On the basis of experimental research performed by FRIF, GEFGN and IFP and of industrial achievements, this article describesthe essential properties of diffusion flames fed by liquid and gaseous fuels and produced with or without fluid swirling, and the effects of such flames on heat transfers. The search for high combustion temperatures means that consideration must be given to operating with reduced excess air, heating the air or

PDF Modeling of Turbulent Combustion

National Research Council Canada - National Science Library

Pope, Stephen B

2006-01-01

.... The PDF approach to turbulent combustion has the advantages of fully representing the turbulent fluctuations of species and temperature, and of allowing realistic combustion chemistry to be implemented...

Japan's Sunshine Project

Science.gov (United States)

1992-07-01

A summary report is given on the results of hydrogen energy research and development achieved during 1991 under the Sunshine Project. In hydrogen manufacturing, regenerative cells that can also generate power as fuel cells were discussed by using solid macromolecular electrolytic films for the case where no electrolysis is carried out with water electrolysis. Yttria stabilized zirconia (YSZ), an oxide solid electrolyte was used for the basic research on high-temperature steam electrolysis. Compositions of hydrogen storage alloys and their deterioration mechanisms were investigated to develop hydrogen transportation and storage technologies. High-density hydrides were searched, and fluidization due to paraffin was discussed. Electrode materials and forming technologies were discussed to develop a hydrogen to power conversion system using hydrogen storage alloys as reversible electrodes. Hydrogen-oxygen combustion was studied in terms of reactive theories, and so was the control of ignition and combustion using ultraviolet ray ignition plasma. Studies were made on hydrogen brittlement in welds on materials in hydrogen utilization and its preventive measures. Surveys were given on technical movements and development problems in high-efficiency, pollution-free hydrogen combustion turbines.

Sulfur Chemistry in Combustion I

DEFF Research Database (Denmark)

Johnsson, Jan Erik; Glarborg, Peter

2000-01-01

of the sulphur compounds in fossil fuels and the possibilities to remove them will be given. Then the combustion of sulphur species and their influence on the combustion chemistry and especially on the CO oxidation and the NOx formation will be described. Finally the in-situ removal of sulphur in the combustion...... process by reaction between SO2 and calcium containing sorbents and the influence on the NOx chemistry will be treated....

In situ high-temperature gas sensors: continuous monitoring of the combustion quality of different wood combustion systems and optimization of combustion process

Directory of Open Access Journals (Sweden)

H. Kohler

2018-03-01

Full Text Available The sensing characteristics and long-term stability of different kinds of CO ∕ HC gas sensors (non-Nernstian mixed potential type during in situ operation in flue gas from different types of low-power combustion systems (wood-log- and wood-chip-fuelled were investigated. The sensors showed representative but individual sensing behaviour with respect to characteristically varying flue gas composition over the combustion process. The long-term sensor signal stability evaluated by repeated exposure to CO ∕ H2 ∕ N2 ∕ synthetic air mixtures showed no sensitivity loss after operation in the flue gas. Particularly for one of the sensors (Heraeus GmbH, this high signal stability was observed in a field test experiment even during continuous operation in the flue gas of the wood-chip firing system over 4 months. Furthermore, it was experimentally shown that the signals of these CO ∕ HC sensing elements yield important additional information about the wood combustion process. This was demonstrated by the adaptation of an advanced combustion airstream control algorithm on a wood-log-fed fireplace and by the development of a combustion quality monitoring system for wood-chip-fed central heaters.

Transformations of inorganic coal constituents in combustion systems

Energy Technology Data Exchange (ETDEWEB)

Helble, J.J. (ed.); Srinivasachar, S.; Wilemski, G.; Boni, A.A. (PSI Technology Co., Andover, MA (United States)); Kang, Shim-Gyoo; Sarofim, A.F.; Graham, K.A.; Beer, J.M. (Massachusetts Inst. of Tech., Cambridge, MA (United States)); Peterson, T.W.; Wendt, O.L.; Gallagher, N.B.; Bool, L. (Arizona Univ., Tucson, AZ (United States)); Huggins, F.E.; Huffman, G.P.; Shah, N.; Shah, A. (Kentucky Univ., Lexington

1992-11-01

This report contains the computer codes developed for the coal combustion project. In Subsection B.1 the FORTRAN code developed for the percolative fragmentation model (or the discrete model, since a char is expressed as a collection of discrete elements in a discrete space) is presented. In Subsection B.2 the code for the continuum model (thus named because mineral inclusions are distributed in a continuum space) is presented. A stereological model code developed to obtain the pore size distribution from a two-dimensional data is presented in Subsection B.3.

Internal and surface phenomena in metal combustion

Science.gov (United States)

Dreizin, Edward L.; Molodetsky, Irina E.; Law, Chung K.

1995-01-01

Combustion of metals has been widely studied in the past, primarily because of their high oxidation enthalpies. A general understanding of metal combustion has been developed based on the recognition of the existence of both vapor-phase and surface reactions and involvement of the reaction products in the ensuing heterogeneous combustion. However, distinct features often observed in metal particle combustion, such as brightness oscillations and jumps (spearpoints), disruptive burning, and non-symmetric flames are not currently understood. Recent metal combustion experiments using uniform high-temperature metal droplets produced by a novel micro-arc technique have indicated that oxygen dissolves in the interior of burning particles of certain metals and that the subsequent transformations of the metal-oxygen solutions into stoichiometric oxides are accompanied with sufficient heat release to cause observed brightness and temperature jumps. Similar oxygen dissolution has been observed in recent experiments on bulk iron combustion but has not been associated with such dramatic effects. This research addresses heterogeneous metal droplet combustion, specifically focusing on oxygen penetration into the burning metal droplets, and its influence on the metal combustion rate, temperature history, and disruptive burning. A unique feature of the experimental approach is the combination of the microgravity environment with a novel micro-arc Generator of Monodispersed Metal Droplets (GEMMED), ensuring repeatable formation and ignition of uniform metal droplets with controllable initial temperature and velocity. The droplet initial temperatures can be adjusted within a wide range from just above the metal melting point, which provides means to ignite droplets instantly upon entering an oxygen containing environment. Initial droplet velocity will be set equal to zero allowing one to organize metal combustion microgravity experiments in a fashion similar to usual microgravity

Second law comparison of oxy-fuel combustion and post-combustion carbon dioxide separation

International Nuclear Information System (INIS)

Simpson, Adam P.; Simon, A.J.

2007-01-01

To define 2nd law efficiency targets for novel separation technologies, a simplified model of a power plant with two forms of CO 2 capture was developed. In this investigation, oxy-fuel combustion and post-combustion CO 2 separation were compared on an exergetic basis. Using exergy balances and black-box models of power plant components, multiple scenarios were run to determine the impact of plant configuration and separation unit efficiency on overall plant performance. Second law efficiency values from the literature were used to set the baseline performance of various CO 2 separation configurations. Assumed advances in 2nd law efficiency were used to determine the potential for overall system performance improvement. It was found that the 2nd law efficiency of air separation must reach a critical value before the thermodynamics of oxy-fuel combustion become favorable. Changes in operating equivalence ratio significantly move the tipping-point between post-combustion and oxy-fuel strategies

Investigating co-combustion characteristics of bamboo and wood.

Science.gov (United States)

Liang, Fang; Wang, Ruijuan; Jiang, Changle; Yang, Xiaomeng; Zhang, Tao; Hu, Wanhe; Mi, Bingbing; Liu, Zhijia

2017-11-01

To investigate co-combustion characteristics of bamboo and wood, moso bamboo and masson pine were torrefied and mixed with different blend ratios. The combustion process was examined by thermogravimetric analyzer (TGA). The results showed the combustion process of samples included volatile emission and oxidation combustion as well as char combustion. The main mass loss of biomass blends occurred at volatile emission and oxidation combustion stage, while that of torrefied biomass occurred at char combustion stage. With the increase of bamboo content, characteristic temperatures decreased. Compared with untreated biomass, torrefied biomass had a higher initial and burnout temperature. With the increase of heating rates, combustion process of samples shifted to higher temperatures. Compared with non-isothermal models, activation energy obtained from isothermal model was lower. The result is helpful to promote development of co-combustion of bamboo and masson pine wastes. Copyright © 2017 Elsevier Ltd. All rights reserved.

New technologies reducing emissions from combustion of biofuels

International Nuclear Information System (INIS)

Oravainen, H.

1997-01-01

In reducing CO 2 emissions, bioenergy will be the most important source of renewable energy in the next few decades. In principle, combustion of biomass is friendly to the environment because CO 2 released during combustion is recycled back into natural circulation. Biofuels normally contain little nitrogen and sulphur. However, depending on the combustion technology used, emissions may be quite high. This is true of combustion of biomass fuels in small appliances like wood stoves, fireplaces, small boilers etc. When fuels having high content of volatile matter are burnt in appliances using batch type combustion, the process is rather an unsteady-state combustion. Emissions of carbon monoxide, other combustible gases and particulates are quite difficult to avoid. With continuous combustion processes this is not normally a problem. This conference paper presents some means of reducing emissions from combustion of biofuels. 5 refs., 4 figs

Co-combustion of anthracite coal and wood pellets: Thermodynamic analysis, combustion efficiency, pollutant emissions and ash slagging.

Science.gov (United States)

Guo, Feihong; Zhong, Zhaoping

2018-08-01

This work presents studies on the co-combustion of anthracite coal and wood pellets in fluidized bed. Prior to the fluidized bed combustion, thermogravimetric analysis are performed to investigate the thermodynamic behavior of coal and wood pellets. The results show that the thermal decomposition of blends is divided into four stages. The co-firing of coal and wood pellets can promote the combustion reaction and reduce the emission of gaseous pollutants, such as SO 2 and NO. It is important to choose the proportion of wood pellets during co-combustion due to the low combustion efficiency caused by large pellets with poor fluidization. Wood pellets can inhibit the volatilization of trace elements, especially for Cr, Ni and V. In addition, the slagging ratio of wood pellets ash is reduced by co-firing with coal. The research on combustion of coal and wood pellets is of great significance in engineering. Copyright © 2018 Elsevier Ltd. All rights reserved.

Natural gas combustion and indoor air quality in domestic premises; Combustion du gaz naturel et qualite de l'air a l'interieur des habitations

Energy Technology Data Exchange (ETDEWEB)

Occhio, L.; Riva, A. [Snam, (Italy); Canci, F.; Scevarolli, V. [Italgas, Torino (Italy)

2000-07-01

Indoor air quality depends on many factors; combustion appliances are one of the sources of emissions inside dwellings. Their installation is regulated by UNI-CIG standards which also establish the ventilation and aeration requirements needed to guarantee the safety and healthiness of the environment. In order to critically evaluate the effect on indoor air quality of using gas appliances under different operational regimes and in different types of building, Snam and Italgas have developed a research project in co-operation with Enitecnologie and Turin Polytechnic, even to provide theoretical and experimental support for standardisation activities. The results of the presented research include experimental measurements made in real buildings, mathematical modelling and analysis of Italian and international literature. The results show that use of combustion appliances has little influence on indoor air quality and does not affect people's health. (authors)

CO2 CAPTURE PROJECT - AN INTEGRATED, COLLABORATIVE TECHNOLOGY DEVELOPMENT PROJECT FOR NEXT GENERATION CO2 SEPARATION, CAPTURE AND GEOLOGIC SEQUESTRATION

Energy Technology Data Exchange (ETDEWEB)

Dr. Helen Kerr

2003-08-01

The CO{sub 2} Capture Project (CCP) is a joint industry project, funded by eight energy companies (BP, ChevronTexaco, EnCana, Eni, Norsk Hydro, Shell, Statoil, and Suncor) and three government agencies (1) European Union (DG Res & DG Tren), (2) Norway (Klimatek) and (3) the U.S.A. (Department of Energy). The project objective is to develop new technologies, which could reduce the cost of CO{sub 2} capture and geologic storage by 50% for retrofit to existing plants and 75% for new-build plants. Technologies are to be developed to ''proof of concept'' stage by the end of 2003. The project budget is approximately $24 million over 3 years and the work program is divided into eight major activity areas: (1) Baseline Design and Cost Estimation--defined the uncontrolled emissions from each facility and estimate the cost of abatement in $/tonne CO{sub 2}. (2) Capture Technology, Post Combustion: technologies, which can remove CO{sub 2} from exhaust gases after combustion. (3) Capture Technology, Oxyfuel: where oxygen is separated from the air and then burned with hydrocarbons to produce an exhaust with high CO{sub 2} for storage. (4) Capture Technology, Pre -Combustion: in which, natural gas and petroleum coke are converted to hydrogen and CO{sub 2} in a reformer/gasifier. (5) Common Economic Model/Technology Screening: analysis and evaluation of each technology applied to the scenarios to provide meaningful and consistent comparison. (6) New Technology Cost Estimation: on a consistent basis with the baseline above, to demonstrate cost reductions. (7) Geologic Storage, Monitoring and Verification (SMV): providing assurance that CO{sub 2} can be safely stored in geologic formations over the long term. (8) Non-Technical: project management, communication of results and a review of current policies and incentives governing CO{sub 2} capture and storage. Technology development work dominated the past six months of the project. Numerous studies are making

Characterization of Oxy-combustion Impacts in Existing Coal-fired Boilers

Energy Technology Data Exchange (ETDEWEB)

Adams, Bradley [Univ. of Utah, Salt Lake City, UT (United States); Davis, Kevin [Univ. of Utah, Salt Lake City, UT (United States); Senior, Constance [Univ. of Utah, Salt Lake City, UT (United States); Shim, Hong Shim [Univ. of Utah, Salt Lake City, UT (United States); Otten, Brydger Van [Univ. of Utah, Salt Lake City, UT (United States); Fry, Andrew [Univ. of Utah, Salt Lake City, UT (United States); Wendt, Jost [Univ. of Utah, Salt Lake City, UT (United States); Eddings, Eric [Univ. of Utah, Salt Lake City, UT (United States); Paschedag, Alan [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Shaddix, Christopher [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Cox, William [Brigham Young Univ., Provo, UT (United States); Tree, Dale [Brigham Young Univ., Provo, UT (United States)

2013-09-30

Reaction Engineering International (REI) managed a team of experts from University of Utah, Siemens Energy, Praxair, Vattenfall AB, Sandia National Laboratories, Brigham Young University (BYU) and Corrosion Management Ltd. to perform multi-scale experiments, coupled with mechanism development, process modeling and CFD modeling, for both applied and fundamental investigations. The primary objective of this program was to acquire data and develop tools to characterize and predict impacts of CO{sub 2} flue gas recycle and burner feed design on flame characteristics (burnout, NO{sub x}, SO{sub x}, mercury and fine particle emissions, heat transfer) and operational concerns (fouling, slagging and corrosion) inherent in the retrofit of existing coal-fired boilers for oxy-coal combustion. Experimental work was conducted at Sandia National Laboratories’ Entrained Flow Reactor, the University of Utah Industrial Combustion Research Facility, and Brigham Young University. Process modeling and computational fluid dynamics (CFD) modeling was performed at REI. Successful completion of the project objectives resulted in the following key deliverables: 1) Multi-scale test data from 0.1 kW bench-scale, 100 kW and 200 kW laboratory-scale, and 1 MW semi-industrial scale combustors that describe differences in flame characteristics, fouling, slagging and corrosion for coal combustion under air-firing and oxygen-firing conditions, including sensitivity to oxy-burner design and flue gas recycle composition. 2) Validated mechanisms developed from test data that describe fouling, slagging, waterwall corrosion, heat transfer, char burnout and sooting under coal oxy-combustion conditions. The mechanisms were presented in a form suitable for inclusion in CFD models or process models. 3) Principles to guide design of pilot-scale and full-scale coal oxy-firing systems and flue gas recycle configurations, such that boiler operational impacts from oxy-combustion retrofits are minimized. 4

Determination of Plant-Available Nutrients in Two Wood Ashes: the Influence of Combustion Conditions

Czech Academy of Sciences Publication Activity Database

Perná, Ivana; Ochecová, P.; Száková, J.; Hanzlíček, Tomáš; Tlustoš, P.

2016-01-01

Roč. 47, 13/14 (2016), 1664-1674 ISSN 0010-3624 R&D Projects: GA MZe QI102A207 Institutional support: RVO:67985891 Keywords : combustion condition * crystal phases * fertilizer * plant-available nutrients * wood ash Subject RIV: DM - Solid Waste and Recycling Impact factor: 0.589, year: 2016

Naphtha vs. dieseline – The effect of fuel properties on combustion homogeneity in transition from CI combustion towards HCCI

KAUST Repository

Vallinayagam, R.

2018-03-20

The scope of this research study pertains to compare the combustion and emission behavior between naphtha and dieseline at different combustion modes. In this study, US dieseline (50% US diesel + 50% RON 91 gasoline) and EU dieseline (45% EU diesel + 55% RON 97 gasoline) with derived cetane number (DCN) of 36 are selected for experimentation in an optical engine. Besides naphtha and dieseline, PRF60 is also tested as a surrogate fuel for naphtha. For the reported fuel with same RON = 60, the effect of physical properties on combustion homogeneity when moving from homogenized charge compression ignition (HCCI) to compression ignition (CI) combustion is studied.The combustion phasing of naphtha at an intake air temperature of 95 °C is taken as the baseline data. The engine experimental results show that higher and lower intake air temperature is required for dieseline mixtures to have same combustion phasing as that of naphtha at HCCI and CI conditions due to the difference in the physical properties. Especially at HCCI mode, due to wider distillation range of dieseline, the evaporation of the fuel is affected so that the gas phase mixture becomes too lean to auto-ignite. However, at partially premixed combustion (PPC) conditions, all test fuels required almost same intake air temperature to match up with the combustion phasing of baseline naphtha. From the rate of heat release and combustion images, it was found that naphtha and PRF60 showed improved premixed combustion when compared dieseline mixtures. The stratification analysis shows that combustion is more stratified for dieseline whereas it is premixed for naphtha and PRF60. The level of stratification linked with soot emission showed that soot concentration is higher at stratified CI combustion whereas near zero soot emissions were noted at PPC mode.

Comparison of different chemical kinetic mechanisms of methane combustion in an internal combustion engine configuration

OpenAIRE

Ennetta Ridha; Hamdi Mohamed; Said Rachid

2008-01-01

Three chemical kinetic mechanisms of methane combustion were tested and compared using the internal combustion engine model of Chemkin 4.02 [1]: one-step global reaction mechanism, four-step mechanism, and the standard detailed scheme GRIMECH 3.0. This study shows good concordances, especially between the four-step and the detailed mechanisms in the prediction of temperature and main species profiles. But reduced schemes were incapables to predict pollutant emissions in an internal combustion...

Burning Questions in Gravity-Dependent Combustion Science

Science.gov (United States)

Urban, David; Chiaramonte, Francis P.

2012-01-01

Building upon a long history of spaceflight and ground based research, NASA's Combustion Science program has accumulated a significant body of accomplishments on the ISS. Historically, NASAs low-gravity combustion research program has sought: to provide a more complete understanding of the fundamental controlling processes in combustion by identifying simpler one-dimensional systems to eliminate the complex interactions between the buoyant flow and the energy feedback to the reaction zone to provide realistic simulation of the fire risk in manned spacecraft and to enable practical simulation of the gravitational environment experienced by reacting systems in future spacecraft. Over the past two decades, low-gravity combustion research has focused primarily on increasing our understanding of fundamental combustion processes (e.g. droplet combustion, soot, flame spread, smoldering, and gas-jet flames). This research program was highly successful and was aided by synergistic programs in Europe and in Japan. Overall improvements were made in our ability to model droplet combustion in spray combustors (e.g. jet engines), predict flame spread, predict soot production, and detect and prevent spacecraft fires. These results provided a unique dataset that supports both an active research discipline and also spacecraft fire safety for current and future spacecraft. These experiments have been conducted using the Combustion Integrated Rack (CIR), the Microgravity Science Glovebox and the Express Rack. In this paper, we provide an overview of the earlier space shuttle experiments, the recent ISS combustion experiments in addition to the studies planned for the future. Experiments in combustion include topics such as droplet combustion, gaseous diffusion flames, solid fuels, premixed flame studies, fire safety, and super critical oxidation processes.

Experimental study of combustion and emission characteristics of ethanol fuelled port injected homogeneous charge compression ignition (HCCI) combustion engine

Energy Technology Data Exchange (ETDEWEB)

Maurya, Rakesh Kumar; Agarwal, Avinash Kumar [Engine Research Laboratory, Department of Mechanical Engineering, Indian Institute of Technology Kanpur, Kanpur 208 016 (India)

2011-04-15

The homogeneous charge compression ignition (HCCI) is an alternative combustion concept for in reciprocating engines. The HCCI combustion engine offers significant benefits in terms of its high efficiency and ultra low emissions. In this investigation, port injection technique is used for preparing homogeneous charge. The combustion and emission characteristics of a HCCI engine fuelled with ethanol were investigated on a modified two-cylinder, four-stroke engine. The experiment is conducted with varying intake air temperature (120-150 C) and at different air-fuel ratios, for which stable HCCI combustion is achieved. In-cylinder pressure, heat release analysis and exhaust emission measurements were employed for combustion diagnostics. In this study, effect of intake air temperature on combustion parameters, thermal efficiency, combustion efficiency and emissions in HCCI combustion engine is analyzed and discussed in detail. The experimental results indicate that the air-fuel ratio and intake air temperature have significant effect on the maximum in-cylinder pressure and its position, gas exchange efficiency, thermal efficiency, combustion efficiency, maximum rate of pressure rise and the heat release rate. Results show that for all stable operation points, NO{sub x} emissions are lower than 10 ppm however HC and CO emissions are higher. (author)

The effects of changing municipal solid waste characteristics on combustion fuel quality

International Nuclear Information System (INIS)

Artz, N.S.; Franklin, M.A.

1991-01-01

This paper discusses the quality of municipal solid waste (MSW) as a combustion fuel based on two aspects: heat of combustion and heavy metal content. Characterization of MSW by the material flows methodology now provides a historical data series on the composition of MSW for nearly 30 years (1960-1988). Over this period, there have been marked changes in MSW composition, with paper and plastics increasing in percentage while glass and metals have declined. This paper will illustrate the effects of this changing composition on heat of combustion. Using a computer model and standard heat of combustion values for the components of MSW, heating values of MSW (in Btu per pound) are calculated for the 30-year time period. Changes in heating values are highlighted and projections are made to year 2010. Recognizing the increasing importance of the recovery of materials from MSW for recycling, the paper illustrates the effects of removing varying quantities of recyclable materials (e.g., newspapers, corrugated boxes, plastic bottles, glass bottles, metals, yard wastes) on the heating value of the remaining MSW. The paper's final section summarizes recent studies performed for EPA and others on the presence of heavy metals (lead, cadmium, and mercury) in the products discarded in MSW. Again, time trends are used to demonstrate the changing presence of these metals

Polycyclic aromatic hydrocarbons and other organic compounds in ashes from biomass combustion

Czech Academy of Sciences Publication Activity Database

Straka, Pavel; Havelcová, Martina

2012-01-01

Roč. 9, č. 4 (2012), s. 481-490 ISSN 1214-9705 R&D Projects: GA MZe QI102A207 Institutional research plan: CEZ:AV0Z30460519 Keywords : biomass combustion * ash * PAHs Subject RIV: GD - Fertilization, Irrigation, Soil Processing Impact factor: 0.530, year: 2011 http://www.irsm.cas.cz/materialy/acta_content/2012_04/6.Straka_%20Havelcova.pdf

Catalytically enhanced combustion process

International Nuclear Information System (INIS)

Rodriguez, C.

1992-01-01

This patent describes a fuel having improved combustion efficiency. It comprises a petroleum based liquid hydrocarbon; and a combustion catalyst comprising from about 18 to about 21 weight percent naphthalene, from about 75 to about 80 weight percent toluene, and from about 2.8 to about 3.2 weight percent benzyl alcohol

Impact of higher n-butanol addition on combustion and performance of GDI engine in stoichiometric combustion

International Nuclear Information System (INIS)

Chen, Zheng; Yang, Feng; Xue, Shuo; Wu, Zhenkuo; Liu, Jingping

2015-01-01

Highlights: • Effects of 0–50% n-butanol addition on GDI engine are experimentally studied. • Higher n-butanol fractions increase combustion pressure and fasten burning rate. • Higher n-butanol fractions increase BSFC but improve BTE. • Higher n-butanol fractions enhance combustion stability but increase knock intensity. • Higher n-butanol fractions reduce exhaust temperature and NOx emissions. - Abstract: An experimental study was carried out on a turbocharged gasoline direct injection (GDI) engine fueled by n-butanol/gasoline blends. Effects of n-butanol percents (15%, 30%, and 50%) on combustion and performance of the engine operating on stoichiometric combustion condition were discussed and also compared with pure gasoline in this paper. The results indicate that n-butanol/gasoline blends increase combustion pressure and pressure rise rate, fasten burning rate, and shorten ignition delay and combustion duration, as compared to pure gasoline. Moreover, these trends are impacted more evidently with increased n-butanol fraction in the blends. In addition, higher n-butanol percent of gasoline blends increase combustion temperature but decrease the temperature in the later stage of expansion stroke, which contributes to the control of exhaust temperature at high-load. With regards to engine performance, higher n-butanol percent in the blends results in increased brake specific fuel consumption (BSFC) and higher brake thermal efficiency (BTE). However, higher n-butanol addition helps to improve combustion stability but shows slightly higher knock possibility in high-load. In that case, the knock trend could be weakened by retarding ignition timing. Moreover, higher n-butanol addition significantly decreases NOx emissions, but it increases CO emissions obviously.

Spray combustion of Jet-A and diesel fuels in a constant volume combustion chamber

KAUST Repository

Jing, Wei; Roberts, William L.; Fang, Tiegang

2015-01-01

This work investigates the spray combustion of Jet-A fuel in an optical constant-volume combustion chamber under different ambient initial conditions. Ambient temperature was varied at 800 K, 1000 K, and 1200 K and five different ambient O2

Experimental study on the influence of oxygen content in the combustion air on the combustion characteristics

International Nuclear Information System (INIS)

Bělohradský, Petr; Skryja, Pavel; Hudák, Igor

2014-01-01

This study was focused on the experimental investigation of the very promising combustion technology called as the oxygen-enhanced combustion (OEC), which uses the oxidant containing higher proportion of oxygen than in the atmospheric air, i.e. more than 21%. The work investigated and compared the characteristics of two OEC methods, namely the premix enrichment and air-oxy/fuel combustion, when the overall oxygen concentration was varied from 21% to 46%. The combustion tests were performed with the experimental two-gas-staged burner of low-NO x type at the burner thermal input of 750 kW for two combustion regimes – one-staged and two-staged combustion. The oxygen concentration in the flue gas was maintained in the neighborhood of 3% vol. (on dry basis). The aim of tests was to assess the impact of the oxidant composition, type of OEC method and fuel-staging on the characteristic combustion parameters in detail. The investigated parameters included the concentration of nitrogen oxides (NO x ) in the flue gas, flue gas temperature, heat flux to the combustion chamber wall, and lastly the stability, shape and dimensions of flame. It was observed that NO x emission is significantly lower when the air-oxy/fuel method is used compared to the premix enrichment method. Moreover, when the fuel was staged, NO x emission was below 120 mg/Nm 3 at all investigated oxygen flow rates. Increasing oxygen concentration resulted in higher heating intensity due to higher concentrations of CO 2 and H 2 O. The available heat at 46% O 2 was higher by 20% compared with that at 21% O 2 . - Highlights: • Premix-enrichment and air-oxy/fuel combustion methods were experimentally studied. • NO x increased sharply as oxygen concentration increased during PE tests. • NO x was below 120 mg/Nm 3 for all investigated oxygen flow rates in AO tests. • Radiative heat transfer was enhanced ca. 20% as O 2 concentration was increased. • OEC flames were observed stable, more luminous and

Combustion modeling in waste tanks

International Nuclear Information System (INIS)

Mueller, C.; Unal, C.; Travis, J.R.; Forschungszentrum Karlsruhe

1997-01-01

This paper has two objectives. The first one is to repeat previous simulations of release and combustion of flammable gases in tank SY-101 at the Hanford reservation with the recently developed code GASFLOW-II. The GASFLOW-II results are compared with the results obtained with the HMS/TRAC code and show good agreement, especially for non-combustion cases. For combustion GASFLOW-II predicts a steeper pressure rise than HMS/TRAC. The second objective is to describe a so-called induction parameter model which was developed and implemented into GASFLOW-II and reassess previous calculations of Bureau of Mines experiments for hydrogen-air combustion. The pressure time history improves compared with the one-step model, and the time rate of pressure change is much closer to the experimental data

Ignition and wave processes in combustion of solids

CERN Document Server

Rubtsov, Nickolai M; Alymov, Michail I

2017-01-01

This book focuses on the application of classical combustion theory to ignition and flame propagation in solid-solid and gas-solid systems. It presents experimental investigations in the areas of local ignition, filtration combustion, self-propagating high temperature synthesis and nanopowders protection. The authors highlight analytical formulas used in different areas of combustion in solids and propose an approach based on classical combustion theory. The book attempts to analyze the basic approaches to understanding of solid-solid and solid - gas combustion presented in contemporary literature in a unified approach based on classical combustion theory. .

Effects of stepwise gas combustion on NOx generation

International Nuclear Information System (INIS)

Woperane Seredi, A.; Szepesi, E.

1999-01-01

To decrease NO x emission from gas boilers, the combustion process of gas has been modified from continuous combustion to step-wise combustion. In this process the combustion temperature, the temperature peaks in the flame, the residence time of combustion products in the high-temperature zone and the oxygen partial pressure are changed advantageously. Experiments were performed using multistage burners, and the NO x emission was recorded. It was found that the air factor of the primary combustion space has a determining effect on the NO x reduction. (R.P.)

Fuel Combustion and Engine Performance | Transportation Research | NREL

Science.gov (United States)

Fuel Combustion and Engine Performance Fuel Combustion and Engine Performance Photo of a gasoline emissions in advanced engine technologies. Photo by Dennis Schroeder, NREL NREL's combustion research and combustion and engine research activities include: Developing experimental and simulation research platforms

Emission of PCDD/Fs from Domestic Combustion Using Various Woods, Biofuel and Coals

Czech Academy of Sciences Publication Activity Database

Ocelka, T.; Tomšej, T.; Horák, J.; Šyc, Michal; Krpec, K.; Hopan, F.; Stáňa, M.

LVI, č. 2 (2010), s. 149-154 ISSN 1210-0471 R&D Projects: GA MŽP(CZ) SP/1A2/116/07; GA MŠk 2B08048 Institutional research plan: CEZ:AV0Z40720504 Keywords : combustion * solid fuels * emission factors Subject RIV: DI - Air Pollution ; Quality http://transactions.fs.vsb.cz/2010-2/1793.pdf

Specifics of phytomass combustion in small experimental device

Science.gov (United States)

Lenhard, Richard; Mičieta, Jozef; Jandačka, Jozef; Gavlas, Stanislav

2015-05-01

A wood pellet combustion carries out with high efficiency and comfort in modern pellet boilers. These facts help to increase the amount of installed pellet boilers in households. The combustion process quality depends besides the combustion conditions also on the fuel quality. The wood pellets, which don`t contain the bark and branches represent the highest quality. Because of growing pellet demand, an herbal biomass (phytomass), which is usually an agricultural by-product becomes economically attractive for pellet production. Although the phytomass has the net calorific value relatively slightly lower than the wood biomass, it is often significantly worse in view of the combustion process and an emission production. The combustion of phytomass pellets causes various difficulties in small heat sources, mainly due to a sintering of fuel residues. We want to avoid the ash sintering by a lowering of temperature in the combustion chamber below the ash sintering temperature of phytomass via the modification of a burner design. For research of the phytomass combustion process in the small boilers is constructed the experimental combustion device. There will investigate the impact of cooling intensity of the combustion chamber on the combustion process and emissions. Arising specific requirements from the measurement will be the basis for the design of the pellet burner and for the setting of operating parameters to the trouble-free phytomass combustion was guaranteed.

Specifics of phytomass combustion in small experimental device

Directory of Open Access Journals (Sweden)

Lenhard Richard

2015-01-01

Full Text Available A wood pellet combustion carries out with high efficiency and comfort in modern pellet boilers. These facts help to increase the amount of installed pellet boilers in households. The combustion process quality depends besides the combustion conditions also on the fuel quality. The wood pellets, which don`t contain the bark and branches represent the highest quality. Because of growing pellet demand, an herbal biomass (phytomass, which is usually an agricultural by-product becomes economically attractive for pellet production. Although the phytomass has the net calorific value relatively slightly lower than the wood biomass, it is often significantly worse in view of the combustion process and an emission production. The combustion of phytomass pellets causes various difficulties in small heat sources, mainly due to a sintering of fuel residues. We want to avoid the ash sintering by a lowering of temperature in the combustion chamber below the ash sintering temperature of phytomass via the modification of a burner design. For research of the phytomass combustion process in the small boilers is constructed the experimental combustion device. There will investigate the impact of cooling intensity of the combustion chamber on the combustion process and emissions. Arising specific requirements from the measurement will be the basis for the design of the pellet burner and for the setting of operating parameters to the trouble-free phytomass combustion was guaranteed.

Traveling-Wave Thermoacoustic Engines With Internal Combustion

Science.gov (United States)

Weiland, Nathan Thomas; Zinn, Ben T.; Swift, Gregory William

2004-05-11

Thermoacoustic devices are disclosed wherein, for some embodiments, a combustion zone provides heat to a regenerator using a mean flow of compressible fluid. In other embodiments, burning of a combustible mixture within the combustion zone is pulsed in phase with the acoustic pressure oscillations to increase acoustic power output. In an example embodiment, the combustion zone and the regenerator are thermally insulated from other components within the thermoacoustic device.

Sulfur retention by ash during coal combustion. Part I. A model of char particle combustion

Directory of Open Access Journals (Sweden)

BORISLAV GRUBOR

2003-02-01

Full Text Available A model for the combustion of porous char particles as a basis for modeling the process of sulfur retention by ash during coal combustion is developed in this paper. The model belongs to the microscopic intrinsic models and describes the dynamic behavior of a porous char particle during comustion, taking into account temporal and spatial changes of all important physical properties of the char particle and various combustion parameters. The parametric analysis of the enhanced model shows that the model represents a good basis for the development of a model for the process of sulfur retention by ash during coal combustion. The model enables the prediction of the values of all parameters necessary for the introduction of reactions between sulfur compounds and mineral components in ash, primarily calcium oxide.

ACCESS Project: Final Report

Energy Technology Data Exchange (ETDEWEB)

Weller, Heiko [Robert Bosch, LLC, Farmington Hills, MI (United States)

2015-04-01

The ACCESS project addressed the development, testing, and demonstration of the proposed advanced technologies and the associated emission and fuel economy improvement at an engine dynamometer and on a full-scale vehicle. Improve fuel economy by 25% with minimum performance penalties Achieve SULEV level emissions with gasoline Demonstrate multi-mode combustion engine management system

Nitrogen chemistry in combustion and gasification - mechanisms and modeling

International Nuclear Information System (INIS)

Kilpinen, P.; Hupa, M.

1998-01-01

The objective of this work has been to increase the understanding of the complex details of gaseous emission formation in energy production techniques based on combustion and/or gasification. The aim has also been to improve the accuracy of mathematical furnace models when they are used for predicting emissions. The main emphasis has been on nitrogen oxides (NO x , N 2 O). The work supports development of cleaner and more efficient combustion technology. The main emphasis has been on combustion systems that are based on fluidized bed technology including both atmospheric and pressurized conditions (BFBC, CFBC, PFBC/G). The work has consisted of advanced theoretical modeling and of experiments in laboratory devices that have partly been made in collaboration with other LIEKKI projects. Two principal modeling tools have been used: detailed homogeneous chemical kinetic modeling and computational fluid dynamic simulation. In this report, the most important results of the following selected items will be presented: (1) Extension of a detailed kinetic nitrogen and hydrocarbon oxidation mechanism into elevated pressure, and parametric studies on: effect of pressure on fuel-nitrogen oxidation under PFBC conditions, effect of pressure on selective non-catalytic NO x reduction under PFBC conditions, effect of different oxidizers on hot-gas cleaning of ammonia by means of selective oxidation in gasification gas. (2) Extension of the above mechanism to include chlorine reactions at atmospheric pressure, and parametric studies on: effect of HCl on CO burn-out in FBC combustion of waste. (3) Development of more accurate emission prediction models: incorporation of more accurate submodels on hydrocarbon oxidation into CFD furnace models, and evaluation of different concepts describing the interaction between turbulence and chemical reaction, development of a mechanistic detailed 1.5-dimensional emission model for circulating fluidized bed combustors. (orig.) 14 refs

Characterization of Diesel Combustion inside the EHPC. Final Project

Energy Technology Data Exchange (ETDEWEB)

Florent, D.

2006-07-01

combustion, particularly in high pressure and high temperature environment, is discussed and reviewed. The first part describes the optical techniques used to study vapour distributions. These are Laser Rayleigh Scattering (LRS), Spontaneous Raman Scattering (SRS) and Laser Induced Fluorescence (LIF). The second part explains other optical techniques, Laser Induced Exciplex Fluorescence (LIEF) and dual wavelength Laser Extinction/Absorption (LEA) which are capable of simultaneous measurements of fuel droplets and fuel vapour. For the pre-combustion experiments in the EHPC, the cooling phase of the cell is critical to understand and model. A better knowledge of the cooling processes would improve the understanding of the phenomenon and thus the EHPC experiments. While an uniform temperature is usually assumed and derived from the pressure signal with the perfect gas law, we know from literature that there are internal temperature gradients, which remains unknown since the cooling processes are still to determine. In this report, the modelling of the main processes that are supposed to occur, conduction and convection, is presented and compared to experimental data.

The effect of insulated combustion chamber surfaces on direct-injected diesel engine performance, emissions, and combustion

Science.gov (United States)

Dickey, Daniel W.; Vinyard, Shannon; Keribar, Rifat

1988-01-01

The combustion chamber of a single-cylinder, direct-injected diesel engine was insulated with ceramic coatings to determine the effect of low heat rejection (LHR) operation on engine performance, emissions, and combustion. In comparison to the baseline cooled engine, the LHR engine had lower thermal efficiency, with higher smoke, particulate, and full load carbon monoxide emissions. The unburned hydrocarbon emissions were reduced across the load range. The nitrous oxide emissions increased at some part-load conditions and were reduced slightly at full loads. The poor LHR engine performance was attributed to degraded combustion characterized by less premixed burning, lower heat release rates, and longer combustion duration compared to the baseline cooled engine.

Test Plan for Measuring Ventilation Rates and Combustible Gas Levels in TWRS Active Catch Tanks

Energy Technology Data Exchange (ETDEWEB)

NGUYEN, D.M.

1999-10-25

The purpose of this sampling activity is to obtain data to support an initial evaluation of potential hazards due to the presence of combustible gas in catch tanks that are currently operated by the River Protection Project (RPP). Results of the hazard analysis will be used to support closure of the flammable gas unreviewed safety question for these facilities. The data collection will be conducted in accordance with the Tank Safety Screening Data Quality Objective (Dukelow et al. 1995). Combustible gas, ammonia, and organic vapor levels in the headspace of the catch tanks will be field-measured using hand-held instruments. If a combustible gas level measurement in a tank exceeds an established threshold, gas samples will he collected in SUMMA' canisters for more extensive laboratory analysis. In addition, ventilation rates of some catch tanks will be measured to evaluate removal of flammable gas by air flowing through the tanks. This test plan identifies the sample collection, laboratory analysis, quality assurance, and reporting objectives for this data collection effort. The plan also provides the procedures for field measurement of combustible gas concentrations and ventilation rates.

Improved Economic Performance of Municipal Solid Waste Combustion Plants by Model Based Combustion Control

NARCIS (Netherlands)

Leskens, M.

2013-01-01

The combustion of municipal solid waste (MSW) is used for its inertisation, reduction of its volume and the conversion of its energy content into heat and/or electricity. Operation and control of modern large scale MSW combustion (MSWC) plants is determined by economic and environmental objectives

Toxicology of Biodiesel Combustion products

Science.gov (United States)

1. Introduction The toxicology of combusted biodiesel is an emerging field. Much of the current knowledge about biological responses and health effects stems from studies of exposures to other fuel sources (typically petroleum diesel, gasoline, and wood) incompletely combusted. ...

Project No. 4 - Waste incineration facility

International Nuclear Information System (INIS)

2000-01-01

There are currently 12000 m 3 of combustible waste stored at the Ignalina NPP site. It is estimated that by 2005 the volume will have increase to 15000 m 3 (filters, personnel protection, clothing and plastics). As a part of the preparation for the closure of the Ignalina NPP an incineration facility will be required to process combustible wastes to reduce the overall volume of short-lived radioactive wastes stored at the Ignalina NPP site, thus reducing the overall risk to the environment. Project activities includes the design, construction and commissioning of the proposed facility, including all licensing documentation

Producer for vegetal combustibles for internal-combustion motors

Energy Technology Data Exchange (ETDEWEB)

1943-12-28

A producer is described for internal-combustion motors fed with wood or agricultural byproducts characterized by the fact that its full operation is independent of the degree of wetness of the material used.

Investigation of bluff-body micro-flameless combustion

International Nuclear Information System (INIS)

Hosseini, Seyed Ehsan; Wahid, Mazlan Abdul

2014-01-01

Highlights: • The temperature uniformity of the micro-flameless combustion increases when a triangular bluff-body is applied. • The velocity and temperature of exhaust gases are higher in micro-flameless combustion compared to the conventional mode. • The rate of fuel–oxidizer consumption in micro-flameless mode is lower than conventional micro-combustion. - Abstract: Characteristics of lean premixed conventional micro-combustion and lean non-premixed flameless regime of methane/air are investigated in this paper by solving three-dimensional governing equations. At moderate equivalence ratio (∅ = 0.5), standard k–ε and the eddy-dissipation concept are employed to simulate temperature distribution and combustion stability of these models. The effect of bluff-body on the temperature distribution of both conventional and flameless mode is developed. The results show that in the premixed conventional micro-combustion the stability of the flame is increased when a triangular bluff-body is applied. Moreover, micro-flameless combustion is more stable when bluff-body is used. Micro-flameless mode with bluff-body and 7% O 2 concentration (when N 2 is used as diluent) illustrated better performance than other cases. The maximum temperature in premixed conventional micro-combustion and micro-flameless combustion was recorded 2200 K and 1520 K respectively. Indeed, the flue gas temperature of conventional mode and flameless combustion was 1300 K and 1500 K respectively. The fluctuation of temperature in the conventional micro-combustor wall has negative effects on the combustor and reduces the lifetime of micro-combustor. However, in the micro-flameless mode, the wall temperature is moderate and uniform. The rate of fuel–oxidizer consumption in micro-flameless mode takes longer time and the period of cylinders recharging is prolonged

Numerical analysis on the combustion and emission characteristics of forced swirl combustion system for DI diesel engines

International Nuclear Information System (INIS)

Su, LiWang; Li, XiangRong; Zhang, Zheng; Liu, FuShui

2014-01-01

Highlights: • A new combustion system named FSCS for DI diesel engines was proposed. • Fuel/air mixture formation was improved for the application of FSCS. • The FSCS showed a good performance on emission characteristics. - Abstract: To optimize the fuel/air mixture formation and improve the environmental effect of direct injection (DI) diesel engines, a new forced swirl combustion system (FSCS) was proposed concerned on unique design of the geometric shape of the combustion chamber. Numerical simulation was conducted to verify the combustion and emission characteristics of the engines with FSCS. The fuel/air diffusion, in-cylinder velocity distribution, turbulent kinetic energy and in-cylinder temperature distribution were analyzed and the results shown that the FSCS can increase the area of fuel/air diffusion and improve the combustion. The diesel engine with FSCS also shown excellent performance on emission. At full load condition, the soot emission was significantly reduced for the improved fuel/air mixture formation. There are slightly difference for the soot and NO emission between the FSCS and the traditional omega combustion system at lower load for the short penetration of the fuel spray

Combustion & Laser Diagnostics Research Complex (CLDRC)

Data.gov (United States)

Federal Laboratory Consortium — Description: The Combustion and Laser Diagnostics Research Complex (CLRDC) supports the experimental and computational study of fundamental combustion phenomena to...

The rheodynamics and combustion of coal-water mixtures

Energy Technology Data Exchange (ETDEWEB)

Burdukov, A.P.; Popov, V.I.; Tomilov, V.G.; Fedosenko, V.D. [Russian Academy of Science, Novosibirsk (Russian Federation). Inst. of Thermophysics (Siberian Branch, Russian Academy of Science)

2002-05-01

Investigation methods for characteristics of movement along the tubes, combustion dynamics and gasification of separate drops were developed for the coal-water mixtures (CWM). The following parameters were determined on the basis of laser heating: thermometric, pyrometric and concentration dynamics of single-drop combustion, complete combustion times, duration of temperature phases of combustion, as well as the moment and temperature of ignition. Information on the combustion mass velocity and gasification products was also obtained using laser heating. 6 refs., 13 figs., 1 tab.

MCO combustible gas management leak test acceptance criteria; TOPICAL

International Nuclear Information System (INIS)

SHERRELL, D.L.

1999-01-01

Existing leak test acceptance criteria for mechanically sealed and weld sealed multi-canister overpacks (MCO) were evaluated to ensure that MCOs can be handled and stored in stagnant air without compromising the Spent Nuclear Fuel Project's overall strategy to prevent accumulation of combustible gas mixtures within MCO's or within their surroundings. The document concludes that the integrated leak test acceptance criteria for mechanically sealed and weld sealed MCOs (1 x 10(sup -5) std cc/sec and 1 x 10(sup -7) std cc/sec, respectively) are adequate to meet all current and foreseeable needs of the project, including capability to demonstrate compliance with the NFPA 60 Paragraph 3-3 requirement to maintain hydrogen concentrations[within the air atmosphere CSB tubes] t or below 1 vol% (i.e., at or below 25% of the LFL)

Lab-scale investigation of Middle-Bosnia coals to achieve high-efficient and clean combustion technology

Directory of Open Access Journals (Sweden)

Smajevic Izet

2014-01-01

Full Text Available This paper describes full lab-scale investigation of Middle-Bosnia coals launched to support selection an appropriate combustion technology and to support optimization of the boiler design. Tested mix of Middle-Bosnia brown coals is projected coal for new co-generation power plant Kakanj Unit 8 (300-450 MWe, EP B&H electricity utility. The basic coal blend consisting of the coals Kakanj: Breza: Zenica at approximate mass ratio of 70:20:10 is low grade brown coal with very high percentage of ash - over 40%. Testing that coal in circulated fluidized bed combustion technique, performed at Ruhr-University Bohum and Doosan Lentjes GmbH, has shown its inconveniency for fluidized bed combustion technology, primarily due to the agglomeration problems. Tests of these coals in PFC (pulverized fuel combustion technology have been performed in referent laboratory at Faculty of Mechanical Engineering of Sarajevo University, on a lab-scale PFC furnace, to provide reliable data for further analysis. The PFC tests results are fitted well with previously obtained results of the burning similar Bosnian coal blends in the PFC dry bottom furnace technique. Combination of the coals shares, the process temperature and the air combustion distribution for the lowest NOx and SO2 emissions was found in this work, provided that combustion efficiency and CO emissions are within very strict criteria, considering specific settlement of lab-scale furnace. Sustainability assessment based on calculation economic and environmental indicators, in combination with Low Cost Planning method, is used for optimization the power plant design. The results of the full lab-scale investigation will help in selection optimal Boiler design, to achieve sustainable energy system with high-efficient and clean combustion technology applied for given coals.

Effect of bed particles to combustion of gases in fluidized bed

Energy Technology Data Exchange (ETDEWEB)

Raiko, R.; Wallen, V.; Etelaeaho, R.; Correia, S. [Tampere Univ. of Technology (Finland). Energy and Process Engineering

1997-10-01

The objective of this project was to obtain experimental data on effects of sand particles to the combustion of gases. The effect of the surface area of the particles was tested using different sized particles. The fluidized bed reactor used in these experiments was a stainless-steel tube with an internal diameter of 42 mm surrounded by an electric heater. The test rig was built in the Laboratory of Energy and Process Engineering at Tampere University of Technology. In order to elucidate the possible changes of particle surface, microscopic and porosimetric studies were conducted with both fresh bed particles and used bed particles. These measurements indicate that carbon monoxide significantly reacts with oxygen in the particulate or emulsion phase of a fluidized bed, if the residence time is long enough. The reaction rate depends mainly on temperature, air coefficient, residence time and particle size of the solids. It seems that the combustion enhances if the average particle size increases. Whether this is caused by increased free path length or reduced specific surface area of the bed is yet unknown. The first might be more probable cause because the majority of reactions often took place in the freeboard right above the bed. It was clear that the bed hindered proper combustion in several cases. (orig.)

Bifurcation, pattern formation and chaos in combustion

International Nuclear Information System (INIS)

Bayliss, A.; Matkowsky, B.J.

1991-01-01

In this paper problems in gaseous combustion and in gasless condensed phase combustion are studied both analytically and numerically. In gaseous combustion we consider the problem of a flame stabilized on a line source of fuel. The authors find both stationary and pulsating axisymmetric solutions as well as stationary and pulsating cellular solutions. The pulsating cellular solutions take the form of either traveling waves or standing waves. Transitions between these patterns occur as parameters related to the curvature of the flame front and the Lewis number are varied. In gasless condensed phase combustion both planar and nonplanar problems are studied. For planar condensed phase combustion we consider two models: accounts for melting and does not. Both models are shown to exhibit a transition from uniformly to pulsating propagating combustion when a parameter related to the activation energy is increased. Upon further increasing this parameter both models undergo a transition to chaos: by intermittency and by a period doubling sequence. In nonplanar condensed phase combustion the nonlinear development of a branch of standing wave solutions is studied and is shown to lead to relaxation oscillations and subsequently to a transition to quasi-periodicity

Fundamentals of Turbulent and Multi-Phase Combustion

CERN Document Server

Kuo, Kenneth Kuan-yun

2012-01-01

Detailed coverage of advanced combustion topics from the author of Principles of Combustion, Second Edition Turbulence, turbulent combustion, and multiphase reacting flows have become major research topics in recent decades due to their application across diverse fields, including energy, environment, propulsion, transportation, industrial safety, and nanotechnology. Most of the knowledge accumulated from this research has never been published in book form-until now. Fundamentals of Turbulent and Multiphase Combustion presents up-to-date, integrated coverage of the fundamentals of turbulence

A novel device for processing radioactive combustibles

International Nuclear Information System (INIS)

Phelan, P.F.; Thompson, T.K.

1991-01-01

Los Alamos National Laboratory is assisting EG ampersand G Rocky Flats, Colorado, with the development of a special incinerator for wastes contaminated with plutonium, a radioactive element. This paper describes one conceptual design that was developed by T.K. Thompson, Inc., under contract to Los Alamos National Laboratory. The design is a tentative proposal that tries to address the many constraints that are peculiar to this project. It has not been endorsed or accepted by EG ampersand G Rocky Flats, and it is subject to revision. Nevertheless, it is noteworthy because of the novel concepts it embodies. Before examining the design itself, it is instructive to understand the constraints imposed by safety and operational concerns. There are three main requirements related to safety: There may be no emissions of radioactive material either to the atmosphere or into the building that houses the incinerator. The outer surfaces of the combustion chamber must be kept below 140oF so that the lead-lined rubber gloves will not melt if the operator reaches inside the glovebox while the incinerator is hot. The combustion chambers and other locations where plutonium-containing ash could accumulate must be designed in such a way that it would be impossible for a critically accident to occur. 3 figs

Recovery Act: Oxy-Combustion Technology Development for Industrial-Scale Boiler Applications

Energy Technology Data Exchange (ETDEWEB)

Levasseur, Armand

2014-01-01

This Topical Report outlines guidelines and key considerations for design and operation of pulverized coal-fired boilers for oxy-combustion. The scope addressed includes only the boiler island, not the entire oxy-fired CO{sub 2} capture plant. These guidelines are primarily developed for tangential-fired boilers and focus on designs capable of dual air and oxy-fired operation. The guidelines and considerations discussed are applicable to both new units and existing boiler retrofits. These guidelines are largely based on the findings from the extensive 15 MW{sub th} pilot testing and design efforts conducted under this project. A summary level description is provided for each major aspect of boiler design impacted by oxy-combustion, and key considerations are discussed for broader application to different utility and industrial designs. Guidelines address the boiler system arrangement, firing system, boiler thermal design, ducting, materials, control system, and other key systems.

FINE PARTICAL AND TOXIC METAL EMISSIONS FROM THE COMBUSTION OF SEWAGE SLUDGE/COAL MIXTURES: A SYSTEMATIC ASSESSMENT

Energy Technology Data Exchange (ETDEWEB)

Jost O.L. Wendt; Wayne S. Seames; Art Fernandez

2003-09-21

This research project focuses on pollutants from the combustion of mixtures of dried municipal sewage sludge (MSS) and pulverized coal. The objective was to determine potential tradeoffs between CO{sub 2} mitigation through using a CO{sub 2} neutral fuel, such as municipal sewage sludge, and the emergence of other potential problems such as the emission of toxic fly ash particles. The work led to new insight into mechanisms governing the partitioning of major and trace metals from the combustion of sewage sludge, and mixtures of coal and sewage sludge. The research also showed that the co-combustion of coal and sewage sludge emitted fine particulate matter that might potentially cause greater lung injury than that from the combustion of either coal alone or municipal sewage sludge alone. The reason appeared to be that the toxicity measured required the presence of large amounts of both zinc and sulfur in particles that were inhaled. MSS provided the zinc while coal provided the sulfur. Additional research showed that the toxic effects could most likely be engineered out of the process, through the introduction of kaolinite sorbent downstream of the combustion zone, or removing the sulfur from the fuel. These results are consequences of applying ''Health Effects Engineering'' to this issue. Health Effects Engineering is a new discipline arising out of this work, and is derived from using a collaboration of combustion engineers and toxicologists to mitigate the potentially bad health effects from combustion of this biomass fuel.

An Assessment of Combustion Dynamics in a Low-Nox, Second-Generation Swirl-Venturi Lean Direct Injection Combustion Concept

Science.gov (United States)

Tacina, K. M.; Chang, C. T.; Lee, P.; Mongia, H.; Podboy, D. P.; Dam, B.

2015-01-01

Dynamic pressure measurements were taken during flame-tube emissions testing of three second-generation swirl-venturi lean direct injection (SV-LDI) combustor configurations. These measurements show that combustion dynamics were typically small. However, a small number of points showed high combustion dynamics, with peak-to-peak dynamic pressure fluctuations above 0.5 psi. High combustion dynamics occurred at low inlet temperatures in all three SV-LDI configurations, so combustion dynamics were explored further at low temperature conditions. A point with greater than 1.5 psi peak-to-peak dynamic pressure fluctuations was identified at an inlet temperature of 450!F, a pressure of 100 psia, an air pressure drop of 3%, and an overall equivalence ratio of 0.35. This is an off design condition: the temperature and pressure are typical of 7% power conditions, but the equivalence ratio is high. At this condition, the combustion dynamics depended strongly on the fuel staging. Combustion dynamics could be reduced significantly without changing the overall equivalence ratio by shifting the fuel distribution between stages. Shifting the fuel distribution also decreased NOx emissions.

CO2 Capture Project-An Integrated, Collaborative Technology Development Project for Next Generation CO2 Separation, Capture and Geologic Sequestration

Energy Technology Data Exchange (ETDEWEB)

Helen Kerr; Linda M. Curran

2005-04-15

The CO{sub 2} Capture Project (CCP) was a joint industry project, funded by eight energy companies (BP, ChevronTexaco, EnCana, ENI, Norsk Hydro, Shell, Statoil, and Suncor) and three government agencies (European Union [DG RES & DG TREN], the Norwegian Research Council [Klimatek Program] and the U.S. Department of Energy [NETL]). The project objective was to develop new technologies that could reduce the cost of CO{sub 2} capture and geologic storage by 50% for retrofit to existing plants and 75% for new-build plants. Technologies were to be developed to ''proof of concept'' stage by the end of 2003. Certain promising technology areas were increased in scope and the studies extended through 2004. The project budget was approximately $26.4 million over 4 years and the work program is divided into eight major activity areas: Baseline Design and Cost Estimation--defined the uncontrolled emissions from each facility and estimate the cost of abatement in $/tonne CO{sub 2}. Capture Technology, Post Combustion: technologies, which can remove CO{sub 2} from exhaust gases after combustion. Capture Technology, Oxyfuel: where oxygen is separated from the air and then burned with hydrocarbons to produce an exhaust with high CO{sub 2} for storage. Capture Technology, Pre-Combustion: in which, natural gas and petroleum cokes are converted to hydrogen and CO{sub 2} in a reformer/gasifier. Common Economic Model/Technology Screening: analysis and evaluation of each technology applied to the scenarios to provide meaningful and consistent comparison. New Technology Cost Estimation: on a consistent basis with the baseline above, to demonstrate cost reductions. Geologic Storage, Monitoring and Verification (SMV): providing assurance that CO{sub 2} can be safely stored in geologic formations over the long term. Non-Technical: project management, communication of results and a review of current policies and incentives governing CO{sub 2} capture and storage. Pre-combustion

Assessment of Literature Related to Combustion Appliance Venting Systems

Energy Technology Data Exchange (ETDEWEB)

Rapp, V. H.; Less, B. D.; Singer, B. C.; Stratton, J. C.; Wray, C. P.

2015-02-01

In many residential building retrofit programs, air tightening to increase energy efficiency is often constrained by safety concerns with naturally vented combustion appliances. Tighter residential buildings more readily depressurize when exhaust equipment is operated, making combustion appliances more prone to backdraft or spill combustion exhaust into the living space. Several measures, such as installation guidelines, vent sizing codes, and combustion safety diagnostics, are in place with the intent to prevent backdrafting and combustion spillage, but the diagnostics conflict and the risk mitigation objective is inconsistent. This literature review summarizes the metrics and diagnostics used to assess combustion safety, documents their technical basis, and investigates their risk mitigations. It compiles information from the following: codes for combustion appliance venting and installation; standards and guidelines for combustion safety diagnostics; research evaluating combustion safety diagnostics; research investigating wind effects on building depressurization and venting; and software for simulating vent system performance.

Flow and Combustion in Advanced Gas Turbine Combustors

CERN Document Server

Janicka, Johannes; Schäfer, Michael; Heeger, Christof

2013-01-01

With regard to both the environmental sustainability and operating efficiency demands, modern combustion research has to face two main objectives, the optimization of combustion efficiency and the reduction of pollutants. This book reports on the combustion research activities carried out within the Collaborative Research Center (SFB) 568 “Flow and Combustion in Future Gas Turbine Combustion Chambers” funded by the German Research Foundation (DFG). This aimed at designing a completely integrated modeling and numerical simulation of the occurring very complex, coupled and interacting physico-chemical processes, such as turbulent heat and mass transport, single or multi-phase flows phenomena, chemical reactions/combustion and radiation, able to support the development of advanced gas turbine chamber concepts.

Reducing emissions from diesel combustion

International Nuclear Information System (INIS)

Anon.

1992-01-01

This paper contains information dealing with engine design to reduce emissions and improve or maintain fuel economy. Topics include: Observation of High Pressure Fuel Spray with Laser Light Sheet Method; Determination of Engine Cylinder Pressures from Crankshaft Speed Fluctuations; Combustion Similarity for Different Size Diesel Engines: Theoretical Prediction and Experimental Results; Prediction of Diesel Engine Particulate Emission During Transient Cycles; Characteristics and Combustibility of Particulate Matter; Dual-Fuel Diesel Engine Using Butane; Measurement of Flame Temperature Distribution in D.I. Diesel Engine with High Pressure Fuel Injection: and Combustion in a Small DI Diesel Engine at Starting

Mechanisms and characteristics of silicon combustion in nitrogen

Energy Technology Data Exchange (ETDEWEB)

Mukasian, A.S.; Martynenko, V.M.; Merzhanov, A.G.; Borovinskaia, I.P.; Blinov, M.IU.

1986-10-01

An experimental study is made of the principal characteristics of combustion in the system silicon-nitrogen associated with phase transitions of the first kind (silicon melting and silicon nitride dissociation). Concepts of the combustion mechanism are developed on the basis of elementary models of combustion of the second kind and filtering combustion theory. In particular, it is shown that, in the pressure range studied (10-20 MPa), filtering does not limit the combustion process. Details of the experimental procedure and results are presented. 22 references.

Physician-Pharmacist Collaborative Care for Dyslipidemia Patients: Knowledge and Skills of Community Pharmacists

Science.gov (United States)

Villeneuve, Julie; Lamarre, Diane; Lussier, Marie-Therese; Vanier, Marie-Claude; Genest, Jacques; Blais, Lucie; Hudon, Eveline; Perreault, Sylvie; Berbiche, Djamal; Lalonde, Lyne

2009-01-01

Introduction: In a physician-pharmacist collaborative-care (PPCC) intervention, community pharmacists were responsible for initiating lipid-lowering pharmacotherapy and adjusting the medication dosage. They attended a 1-day interactive workshop supported by a treatment protocol and clinical and communication tools. Afterwards, changes in…

Review of Membrane Oxygen Enrichment for Efficient Combustion

Science.gov (United States)

Ariono, Danu; Kusuma Wardani, Anita

2017-07-01

Oxygen enrichment from air is a simple way of increasing the efficiency of combustion process, as in oxy-combustion. Oxy-combustion has become one of the most attracting combustion technologies because of its potential to address both pollutant reduction and CO2 capture. In oxy-combustion, the fuel and recycled flue gas are combusted with oxygen enriched air (OEA). By using OEA, many benefits can be obtained, such as increasing available heat, improving ignition characteristics, flue gas reduction, increasing productivity, energy efficiency, turndown ratio, and flame stability. Membrane-based gas separation for OEA production becomes an attractive technology over the conventional technology due to the some advantages, including low capital cost, low energy consumption, compact size, and modularity. A single pass through membrane usually can enrich O2 concentration in the air up to 35% and a 50% concentration can be achieved with a double pass of membrane. The use of OEA in the combustion process eliminates the presence of nitrogen in the flue gas. Hence, the flue gas is mainly composed of CO2 and condensable water that can be easily separated. This paper gives an overview of oxy-combustion with membrane technology for oxygen enrichment process. Special attention is given to OEA production and the effect of OEA to the efficiency of combustion.

Direct numerical simulation of combustion at high Reynolds numbers; Direkte Numerische Simulation der Verbrennung bei hoeheren Reynoldszahlen

Energy Technology Data Exchange (ETDEWEB)

Frouzakis, C. E.; Boulouchos, K.

2005-12-15

This comprehensive illustrated final report for the Swiss Federal Office of Energy (SFOE) reports on the work done at the Swiss Federal Institute of Technology in Zurich on the numerical simulation of combustion processes at high Reynolds numbers. The authors note that with appropriate extensive calculation effort, results can be obtained that demonstrate a high degree of accuracy. It is noted that a large part of the project work was devoted to the development of algorithms for the simulation of the combustion processes. Application work is also discussed with research on combustion stability being carried on. The direct numerical simulation (DNS) methods used are described and co-operation with other institutes is noted. The results of experimental work are compared with those provided by simulation and are discussed in detail. Conclusions and an outlook round off the report.

LIEKKI 2 - Combustion and gasification research programme 1993- 1998. Final report

Energy Technology Data Exchange (ETDEWEB)

Hupa, M [ed.

1999-12-31

The six-year Combustion and Gasification Research Programme LIEKKI 2 (1993-1998) was oriented towards research serving the development of energy production technologies based on combustion and gasification. The programme was divided into six research areas: 1. Modelling of the furnace processes (39 projects); 2. Chemistry of gaseous emission components (28); 3. Particle behaviour, ash, aerosols (42); 4. New combustion and gasification technologies (27); 5. Black liquor (33) and 6. Conventional combustion technologies, waste incineration (19). The main aim of the research has been to develop new, more efficient and environmentally friendly techniques. The development of conventional combustion technology has also been an important part of the programme. Another important goal has been to maintain and develop maintain the competence of the research organisations in the combustion area and to intensify their collaboration. Concerning its research contents and its objectives LIEKKI 2, like its forerunner, has not been fuel-specific. The programme has investigated the thermal conversion of oil, gas, black liquor, and coal as well as that of peat, biofuels, and various waste materials, and it has further advanced the know-how concerning the utilisation of these fuels. This approach differs from the usual fuel-specific differentiation, which, for instance, IEA (International Energy Agency) and EU have applied in their research activities. This approach seems in retrospect to have been the right choice. It has been appropriate to stimulate co-operation between parties who would not seek co-operation spontaneously. One example of this is the development of a steelmaking process by a Finnish steel manufacturer under the LIEKKI programme. The programme has also provided synergetic advantages to the development of the recovery boiler processes of the pulp industry. Assessing the impact of the programme is a matter of many facets. The six-year research work and a total

LIEKKI 2 - Combustion and gasification research programme 1993- 1998. Final report

Energy Technology Data Exchange (ETDEWEB)

Hupa, M. [ed.

1998-12-31

The six-year Combustion and Gasification Research Programme LIEKKI 2 (1993-1998) was oriented towards research serving the development of energy production technologies based on combustion and gasification. The programme was divided into six research areas: 1. Modelling of the furnace processes (39 projects); 2. Chemistry of gaseous emission components (28); 3. Particle behaviour, ash, aerosols (42); 4. New combustion and gasification technologies (27); 5. Black liquor (33) and 6. Conventional combustion technologies, waste incineration (19). The main aim of the research has been to develop new, more efficient and environmentally friendly techniques. The development of conventional combustion technology has also been an important part of the programme. Another important goal has been to maintain and develop maintain the competence of the research organisations in the combustion area and to intensify their collaboration. Concerning its research contents and its objectives LIEKKI 2, like its forerunner, has not been fuel-specific. The programme has investigated the thermal conversion of oil, gas, black liquor, and coal as well as that of peat, biofuels, and various waste materials, and it has further advanced the know-how concerning the utilisation of these fuels. This approach differs from the usual fuel-specific differentiation, which, for instance, IEA (International Energy Agency) and EU have applied in their research activities. This approach seems in retrospect to have been the right choice. It has been appropriate to stimulate co-operation between parties who would not seek co-operation spontaneously. One example of this is the development of a steelmaking process by a Finnish steel manufacturer under the LIEKKI programme. The programme has also provided synergetic advantages to the development of the recovery boiler processes of the pulp industry. Assessing the impact of the programme is a matter of many facets. The six-year research work and a total

Comparative Environmental Life Cycle Assessment of Oxyfuel and Post-combustion Capture with MEA and AMP/PZ - Case Studies from the EDDiCCUT Project

NARCIS (Netherlands)

Oreggioni, Gabriel D.; Singh, Bhawna; Hung, Christine Roxanne; Van Der Spek, Mijndert W.; Skagestad, Ragnhild; Eldrup, Nils Henrik; Ramirez, Andrea; Strømman, Anders Hammer

2017-01-01

This work presents the results of a comparative life cycle assessment study for three CCS technologies applied to a coal-fired power plant: post-combustion capture with MEA, post combustion capture with AMP/PZ and cryogenic oxy-fuel. This study has been performed in the context of the EDDiCCUT

14 CFR 25.833 - Combustion heating systems.

Science.gov (United States)

2010-01-01

... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Combustion heating systems. 25.833 Section... AIRWORTHINESS STANDARDS: TRANSPORT CATEGORY AIRPLANES Design and Construction Ventilation and Heating § 25.833 Combustion heating systems. Combustion heaters must be approved. [Amdt. 25-72, 55 FR 29783, July 20, 1990...

Chemistry and radiation in oxy-fuel combustion

DEFF Research Database (Denmark)

Yin, Chungen; Rosendahl, Lasse; Kær, Søren Knudsen

2011-01-01

In order to investigate the role of combustion chemistry and radiation heat transfer in oxy-fuel combustion modeling, a computational fluid dynamics (CFD) modeling study has been performed for two different oxy-fuel furnaces. One is a lab-scale 0.8MW oxy-natural gas flame furnace whose detailed in....... Among the key issues in combustion modeling, e.g., mixing, radiation and chemistry, this paper derives useful guidelines on radiation and chemistry implementation for reliable CFD analyses of oxy-fuel combustion, particularly for industrial applications....

Concept for premixed combustion of hydrogen-containing fuels in gas turbines; Konzept zur vorgemischten Verbrennung wasserstoffhaltiger Brennstoffe in Gasturbinen

Energy Technology Data Exchange (ETDEWEB)

Mayer, Christoph

2012-07-19

One of the main challenges for future gas turbines and their combustion systems is to provide fuel flexibility. The fuel range is expected to reach from the lowly reactive natural gas to highly reactive hydrogen-containing syngases. The objective of the project in which this work was pursued is to develop such a combustion system. The burner has to ensure premixed operation with an aerodynamically stabilized flame. The focus of this work is on characterizing and optimizing the operational safety of the system, but also on ensuring sufficientmixing and lowemissions. A burner and fuel injection design is achieved that leads not only to emissions far below the permissible values, but also to flashback safety for hydrogen combustion that comes close to the theoretically achievable maximum at atmospheric pressure conditions. In this design flashback due to combustion-induced vortex breakdown and wall boundary layer flashback is avoided. Flashback only takes place when the flow velocity reaches the flame velocity.

Sodium nitrate combustion limit tests

International Nuclear Information System (INIS)

Beitel, G.A.

1976-04-01

Sodium nitrate is a powerful solid oxidant. Energetically, it is capable of exothermically oxidizing almost any organic material. Rate-controlling variables such as temperature, concentration of oxidant, concentration of fuel, thermal conductivity, moisture content, size, and pressure severely limit the possibility of a self-supported exothermic reaction (combustion). The tests reported in this document were conducted on one-gram samples at atmospheric pressure. Below 380 0 C, NaNO 3 was stable and did not support combustion. At moisture concentrations above 22 wt percent, exothermic reactions did not propagate in even the most energetic and reactive compositions. Fresh resin and paraffin were too volatile to enable a NaNO 2 -supported combustion process to propagate. Concentrations of NaNO 3 above 95 wt percent or below 35 wt percent did not react with enough energy release to support combustion. The influence of sample size and confining pressure, both important factors, was not investigated in this study

Variable compression ratio device for internal combustion engine

Science.gov (United States)

Maloney, Ronald P.; Faletti, James J.

2004-03-23

An internal combustion engine, particularly suitable for use in a work machine, is provided with a combustion cylinder, a cylinder head at an end of the combustion cylinder and a primary piston reciprocally disposed within the combustion cylinder. The cylinder head includes a secondary cylinder and a secondary piston reciprocally disposed within the secondary cylinder. An actuator is coupled with the secondary piston for controlling the position of the secondary piston dependent upon the position of the primary piston. A communication port establishes fluid flow communication between the combustion cylinder and the secondary cylinder.

Systems and methods of storing combustion waste products

Science.gov (United States)

Chen, Shen-En; Wang, Peng; Miao, Xiexing; Feng, Qiyan; Zhu, Qianlin

2016-04-12

In one aspect, methods of storing one or more combustion waste products are described herein. Combustion waste products stored by a method described herein can include solid combustion waste products such as coal ash and/or gaseous combustion products such as carbon dioxide. In some embodiments, a method of storing carbon dioxide comprises providing a carbon dioxide storage medium comprising porous concrete having a macroporous and microporous pore structure and flowing carbon dioxide captured from a combustion flue gas source into the pore structure of the porous concrete.

IGCC demonstration project status combustion engineering IGCC repowering project

International Nuclear Information System (INIS)

Glamuzina, R.W.; Allen, R.J.; Peletz, L.J.

1993-01-01

This demonstration project was originally conceived as the repowering of an existing plant facility, the Lakeside Station in Springfield, Illinois. The Owner, City Water, Light and Power (CWL ampersand P), has removed five of the original boilers and three of the original turbines. The buildings have had asbestos insulation removed and the interiors have been prepared for the construction of a single Integrated Gasification Combined Cycle (IGCC) process train that will generate a net output of 60 megawatts. The plant consists of a combined cycle (gas turbine, heat recovery steam generator, steam turbine) power train located in the existing buildings and a coal gasification system in a new building. The gasification system contains ABB CE's air-blown, entrained flow, two stage gasifier, an advanced hot gas desulfurization system by General Electric Environmental Services, Inc. and the necessary auxiliary systems. The plant is designed to produce a nominal 60 MW net output with an ambient air temperature of 95 degrees F and a cooling water temperature of 89 degrees F on either Natural Gas or Illinois No. 5 coal

Oxy-Combustion Boiler Material Development

Energy Technology Data Exchange (ETDEWEB)

Gagliano, Michael; Seltzer, Andrew; Agarwal, Hans; Robertson, Archie; Wang, Lun

2012-01-31

Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO2 level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to two year

Oxy-Combustion Boiler Material Development

Energy Technology Data Exchange (ETDEWEB)

Michael Gagliano; Andrew Seltzer; Hans Agarwal; Archie Robertson; Lun Wang

2012-01-31

Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO{sub 2} level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to

Combustion in a High-Speed Compression-Ignition Engine

Science.gov (United States)

Rothrock, A M

1933-01-01

An investigation conducted to determine the factors which control the combustion in a high-speed compression-ignition engine is presented. Indicator cards were taken with the Farnboro indicator and analyzed according to the tangent method devised by Schweitzer. The analysis show that in a quiescent combustion chamber increasing the time lag of auto-ignition increases the maximum rate of combustion. Increasing the maximum rate of combustion increases the tendency for detonation to occur. The results show that by increasing the air temperature during injection the start of combustion can be forced to take place during injection and so prevent detonation from occurring. It is shown that the rate of fuel injection does not in itself control the rate of combustion.

CFD analysis of premixed hydrogen/air combustion in an upright, rectangular shaped combustion chamber

International Nuclear Information System (INIS)

Gera, B.; Singh, R.K.; Vaze, K.K.

2014-01-01

Premixed hydrogen/air combustion in an upright, rectangular shaped combustion chamber has been performed numerically using commercial CFD code CFD-ACE+. The combustion chamber had dimensions 1 m X 0.024 m X 1 m. Simulations were carried out for 10% (v/v) hydrogen concentration for which experimental results were available. Effect of different boundary condition and ignition position on flame propagation was studied. Time dependent flame propagation in the chamber was predicted by CFD code. The computed transient flame propagation in the chamber was in good agreement with experimental results. The present work demonstrated that the available commercial CFD codes are capable of modeling hydrogen deflagration in a realistic manner. (author)

Flex-flame burner and combustion method

Science.gov (United States)

Soupos, Vasilios; Zelepouga, Serguei; Rue, David M.; Abbasi, Hamid A.

2010-08-24

A combustion method and apparatus which produce a hybrid flame for heating metals and metal alloys, which hybrid flame has the characteristic of having an oxidant-lean portion proximate the metal or metal alloy and having an oxidant-rich portion disposed above the oxidant lean portion. This hybrid flame is produced by introducing fuel and primary combustion oxidant into the furnace chamber containing the metal or metal alloy in a substoichiometric ratio to produce a fuel-rich flame and by introducing a secondary combustion oxidant into the furnace chamber above the fuel-rich flame in a manner whereby mixing of the secondary combustion oxidant with the fuel-rich flame is delayed for a portion of the length of the flame.

Combustion instability modeling and analysis

Energy Technology Data Exchange (ETDEWEB)

Santoro, R.J.; Yang, V.; Santavicca, D.A. [Pennsylvania State Univ., University Park, PA (United States); Sheppard, E.J. [Tuskeggee Univ., Tuskegee, AL (United States). Dept. of Aerospace Engineering

1995-12-31

It is well known that the two key elements for achieving low emissions and high performance in a gas turbine combustor are to simultaneously establish (1) a lean combustion zone for maintaining low NO{sub x} emissions and (2) rapid mixing for good ignition and flame stability. However, these requirements, when coupled with the short combustor lengths used to limit the residence time for NO formation typical of advanced gas turbine combustors, can lead to problems regarding unburned hydrocarbons (UHC) and carbon monoxide (CO) emissions, as well as the occurrence of combustion instabilities. The concurrent development of suitable analytical and numerical models that are validated with experimental studies is important for achieving this objective. A major benefit of the present research will be to provide for the first time an experimentally verified model of emissions and performance of gas turbine combustors. The present study represents a coordinated effort between industry, government and academia to investigate gas turbine combustion dynamics. Specific study areas include development of advanced diagnostics, definition of controlling phenomena, advancement of analytical and numerical modeling capabilities, and assessment of the current status of our ability to apply these tools to practical gas turbine combustors. The present work involves four tasks which address, respectively, (1) the development of a fiber-optic probe for fuel-air ratio measurements, (2) the study of combustion instability using laser-based diagnostics in a high pressure, high temperature flow reactor, (3) the development of analytical and numerical modeling capabilities for describing combustion instability which will be validated against experimental data, and (4) the preparation of a literature survey and establishment of a data base on practical experience with combustion instability.

Combustion characteristics of crude jatropha oil droplets using rhodium liquid as a homogeneous combustion catalyst

Science.gov (United States)

Nanlohy, Hendry Y.; Wardana, I. N. G.; Hamidi, N.; Yuliati, L.

2018-01-01

Combustion characteristics of crude jatropha oil droplet at room temperature with and without catalyst have been studied experimentally. Its combustion characteristics have been observed by igniting the oil droplet on a junction of a thermocouple, and the combustion characteristics of oil droplets are observed using a high-speed camera. The results show that the uniqueness of crude jatropha oil as alternative fuel is evidenced by the different stages of combustion caused by thermal cracking in burning droplets. The results also show that the role of the catalyst is not only an accelerator agent, but there are other unique functions and roles as a stabilizer. Moreover, the results also found that the catalyst was able to shorten the ignition timing and burnout time. This phenomenon proves that the presence of catalysts alters and weakens the structure of the triglyceride geometry so that the viscosity and flash point is reduced, the fuel absorbs heat well and flammable.

A study of the current group evaporation/combustion theories

Science.gov (United States)

Shen, Hayley H.

1990-01-01

Liquid fuel combustion can be greatly enhanced by disintegrating the liquid fuel into droplets, an effect achieved by various configurations. A number of experiments carried out in the seventies showed that combustion of droplet arrays and sprays do not form individual flames. Moreover, the rate of burning in spray combustion greatly deviates from that of the single combustion rate. Such observations naturally challenge its applicability to spray combustion. A number of mathematical models were developed to evaluate 'group combustion' and the related 'group evaporation' phenomena. This study investigates the similarity and difference of these models and their applicability to spray combustion. Future work that should be carried out in this area is indicated.

Final report: Prototyping a combustion corridor; FINAL

International Nuclear Information System (INIS)

Rutland, Christopher J.; Leach, Joshua

2001-01-01

The Combustion Corridor is a concept in which researchers in combustion and thermal sciences have unimpeded access to large volumes of remote computational results. This will enable remote, collaborative analysis and visualization of state-of-the-art combustion science results. The Engine Research Center (ERC) at the University of Wisconsin - Madison partnered with Lawrence Berkeley National Laboratory, Argonne National Laboratory, Sandia National Laboratory, and several other universities to build and test the first stages of a combustion corridor. The ERC served two important functions in this partnership. First, we work extensively with combustion simulations so we were able to provide real world research data sets for testing the Corridor concepts. Second, the ERC was part of an extension of the high bandwidth based DOE National Laboratory connections to universities

Combustion of stratified hydrogen-air mixtures in the 10.7 m3 Combustion Test Facility cylinder

International Nuclear Information System (INIS)

Whitehouse, D.R.; Greig, D.R.; Koroll, G.W.

1996-01-01

This paper presents preliminary results from hydrogen concentration gradient combustion experiments in a 10.7 m 3 cylinder. These gradients, also referred to as stratified mixtures, were formed from dry mixtures of hydrogen and air at atmospheric temperature. Combustion pressures, burn fractions and flame speeds in concentration gradients were compared with combustion of well-mixed gases containing equivalent amounts of hydrogen. The studied variables included the quantity of hydrogen in the vessel, the steepness of the concentration gradient, the igniter location, and the initial concentration of hydrogen at the bottom of the vessel. Gradients of hydrogen and air with average concentrations of hydrogen below the downward propagation limit produced significantly greater combustion pressures when ignited at the top of the vessel than well-mixed gases with the same quantity of hydrogen. This was the result of considerably higher burn fractions in the gradients than in the well-mixed gas tests. Above the downward propagation limit, gradients of hydrogen ignited at the top of the vessel produced nearly the same combustion pressures as under well-mixed conditions; both gradients and well-mixed gases had high burn fractions. Much higher flame speeds were observed in the gradients than the well-mixed gases. Gradients and well-mixed gases containing up to 14% hydrogen ignited at the bottom of the vessel produced nearly the same combustion pressures. Above 14% hydrogen, gradients produced lower combustion pressures than well-mixed gases having the same quantity of hydrogen. This can be attributed to lower burn fractions of fuel from the gradients compared with well-mixed gases with similar quantities of hydrogen. When ignited at the bottom of the vessel, 90% of a gradient's gases remained unburned until several seconds after ignition. The remaining gases were then consumed at a very fast rate. (orig.)

Combustion Modeling with the G-Equation Modélisation de la combustion avec l'équation de G

Directory of Open Access Journals (Sweden)

Peters N.

2006-12-01

Full Text Available Numerical investigations concerning the turbulent flame front propagation in Gasoline Direct Injection (GDI engines were made by implementing a flamelet model in the CFD code Fire. The advantage of this combustion model is the decoupling of the chemistry from the turbulent flow. For this purpose the combustion chamber has to be divided into a burned and an unburned area, which is realized by transporting a scalar field (G-Equation. The reference value defines the present averaged flame position. The complete reaction kinetics is calculated interactively with the CFD code in a one dimensional Representative Interactive Flamelet (RIF code. This combustion model was verified by simulating a 2. 0 l-2 V gasoline engine with homogeneous combustion where a parameter study was conducted to check the flamelet model for plausibility. Finally, the potential of this combustion model was investigated by simulating a hypothetical 2. 0 1-4 V GDI engine. Une investigation numérique relative à la propagation des fronts de flammes turbulents dans les moteurs à essence à injection directe (GDI a été menée en implantant un modèle de flameletdans le code 3D Fire. L'avantage de ce modèle de combustion est de découpler la chimie de l'écoulement turbulent en divisant la chambre de combustion en deux zones : brûlée et imbrûlée, à l'aide d'une équation de transport d'un scalaire (équation de G. Une valeur de référence de ce scalaire définit la position moyenne de la flamme. Une chimie complète est calculée interactivement avec le calcul 3D à l'aide d'un code monodimensionnel RIF (Representative Interactive Flamelet. Le modèle de combustion a été validé sur la simulation d'un moteur 2 litres à 2 soupapes en combustion homogène pour vérifier la représentativité de l'approche flamelet . Puis, le potentiel du modèle de combustion a été étudié en simulant un moteur modèle 2 litres 4 soupapes GDI.

High Pressure Combustion Experimental Facility(HPCEF) for Studies on Combustion in Reactive Flows

Science.gov (United States)

2017-12-13

SECURITY CLASSIFICATION OF: 1. REPORT DATE (DD-MM-YYYY) 4. TITLE AND SUBTITLE 13. SUPPLEMENTARY NOTES 12. DISTRIBUTION AVAILIBILITY STATEMENT 6...Report: High Pressure Combustion Experimental Facility (HPCEF) for Studies on Combustion in Reactive Flows The views, opinions and/or findings... contained in this report are those of the author(s) and should not contrued as an official Department of the Army position, policy or decision, unless so

Oxy combustion with CO{sub 2} capture

Energy Technology Data Exchange (ETDEWEB)

NONE

2012-01-15

An update for oxyfuel-combustion carbon capture in the power industry is provided. The report was developed by the Electric Power Research Institute (EPRI) on behalf of the Global CCS Institute. In the oxyfuel-combustion processes, the bulk nitrogen is removed from the air before combustion. The resulting combustion products will have CO2 content up to about 90 per cent (dry basis). The flue gas impurities (predominantly O2, N2, and Ar) may be removed by reducing the flue gas (at moderate pressure) to a temperature at which the CO2 condenses and the impurities do not. Oxyfuel-combustion may be employed with solid fuels such as coal, petroleum coke, and biomass, as well as liquid and gaseous fuels. Some key points raised in the oxyfuel-combustion carbon capture report are: The oxyfuel-combustion/CO2 capture power plant designs being developed and deployed for service in the next four or five years are based on individual component technologies and arrangements which have demonstrated sufficient maturity, with the greatest remaining technical challenge being integrating the systems into a complete steam-electric power plant; By its nature, an oxyfuel-coal power plant is likely to be a 'near zero' emitter of all criteria pollutants; Existing air-fired power plants might be retrofitted with an air separation unit, oxyfuel-fired burners, flue gas recycle, and a CO2 processing unit, with the large fleet of air-fired power plants in service calling for more study of this option; and, Future efficiency improvements to the oxyfuel-combustion process for power generation point toward an oxyfuel-combustion plant with near zero emissions of conventional pollutants, up to 98 per cent CO2 capture, and efficiency comparable to the best power plants currently being built.

Catalytic combustion in small wood burning appliances

Energy Technology Data Exchange (ETDEWEB)

Oravainen, H [VTT Energy, Jyvaeskylae (Finland)

1997-12-31

There is over a million hand fired small heating appliances in Finland where about 5,4 million cubic meters of wood fuel is used. Combustion in such heating appliances is a batch-type process. In early stages of combustion when volatiles are burned, the formation of carbon monoxide (CO) and other combustible gases are difficult to avoid when using fuels that have high volatile matter content. Harmful emissions are formed mostly after each fuel adding but also during char burnout period. When the CO-content in flue gases is, say over 0.5 %, also other harmful emissions will be formed. Methane (CH{sub 4}) and other hydrocarbons are released and the amount of polycyclic aromatic hydrocarbons (PAH)-compounds can be remarkable. Some PAH-compounds are very carcinogenic. It has been estimated that in Finland even more than 90 % of hydrocarbon and PAH emissions are due to small scale wood combustion. Emissions from transportation is excluded from these figures. That is why wood combustion has a net effect on greenhouse gas phenomena. For example carbon monoxide emissions from small scale wood combustion are two fold compared to that of energy production in power plants. Methane emission is of the same order as emission from transportation and seven fold compared with those of energy production. Emissions from small heating appliances can be reduced by developing the combustion techniques, but also by using other means, for example catalytic converters. In certain stages of the batch combustion, temperature is not high enough, gas mixing is not good enough and residence time is too short for complete combustion. When placed to a suitable place inside a heating appliance, a catalytic converter can oxidize unburned gases in the flue gas into compounds that are not harmful to the environment. (3 refs.)

Catalytic combustion in small wood burning appliances

Energy Technology Data Exchange (ETDEWEB)

Oravainen, H. [VTT Energy, Jyvaeskylae (Finland)

1996-12-31

There is over a million hand fired small heating appliances in Finland where about 5,4 million cubic meters of wood fuel is used. Combustion in such heating appliances is a batch-type process. In early stages of combustion when volatiles are burned, the formation of carbon monoxide (CO) and other combustible gases are difficult to avoid when using fuels that have high volatile matter content. Harmful emissions are formed mostly after each fuel adding but also during char burnout period. When the CO-content in flue gases is, say over 0.5 %, also other harmful emissions will be formed. Methane (CH{sub 4}) and other hydrocarbons are released and the amount of polycyclic aromatic hydrocarbons (PAH)-compounds can be remarkable. Some PAH-compounds are very carcinogenic. It has been estimated that in Finland even more than 90 % of hydrocarbon and PAH emissions are due to small scale wood combustion. Emissions from transportation is excluded from these figures. That is why wood combustion has a net effect on greenhouse gas phenomena. For example carbon monoxide emissions from small scale wood combustion are two fold compared to that of energy production in power plants. Methane emission is of the same order as emission from transportation and seven fold compared with those of energy production. Emissions from small heating appliances can be reduced by developing the combustion techniques, but also by using other means, for example catalytic converters. In certain stages of the batch combustion, temperature is not high enough, gas mixing is not good enough and residence time is too short for complete combustion. When placed to a suitable place inside a heating appliance, a catalytic converter can oxidize unburned gases in the flue gas into compounds that are not harmful to the environment. (3 refs.)

Reactivity studies of rice husk combustion using TGA

International Nuclear Information System (INIS)

Ismail, A.F.; Shamsuddin, A.H.; Mahdi, F.M.A.

2000-01-01

The reactivity of rice husks combustion is systematically studied the thermogravimetric analyzer (TGA). The kinetic parameters are determined from the Arrhenius plots based on the data of weight loss over temperature at different combustion heating rates. The results of proximate analysis (the moisture, volatile matters, fixed carbon, and ash contents) are also presented in this paper. The effects of process conditions on the self-ignition phenomenon of rice husk combustion are quantified. Finally, these results and compared with results for coal combustion. This research is part of the work to determine the optimal process conditions of rice husk combustion for energy production. (Author)

Large-eddy simulation of swirling pulverized-coal combustion

Energy Technology Data Exchange (ETDEWEB)

Hu, L.Y.; Luo, Y.H. [Shanghai Jiaotong Univ. (China). School of Mechanical Engineering; Zhou, L.X.; Xu, C.S. [Tsinghua Univ., Beijing (China). Dept. of Engineering Mechanics

2013-07-01

A Eulerian-Lagrangian large-eddy simulation (LES) with a Smagorinsky-Lilly sub-grid scale stress model, presumed-PDF fast chemistry and EBU gas combustion models, particle devolatilization and particle combustion models are used to study the turbulence and flame structures of swirling pulverized-coal combustion. The LES statistical results are validated by the measurement results. The instantaneous LES results show that the coherent structures for pulverized coal combustion is stronger than that for swirling gas combustion. The particles are concentrated in the periphery of the coherent structures. The flame is located at the high vorticity and high particle concentration zone.

Combustion Stability Assessments of the Black Brant Solid Rocket Motor

Science.gov (United States)

Fischbach, Sean

2014-01-01

The Black Brant variation of the Standard Brant developed in the 1960's has been a workhorse motor of the NASA Sounding Rocket Project Office (SRPO) since the 1970's. In March 2012, the Black Brant Mk1 used on mission 36.277 experienced combustion instability during a flight at White Sands Missile Range, the third event in the last four years, the first occurring in November, 2009, the second in April 2010. After the 2010 event the program has been increasing the motor's throat diameter post-delivery with the goal of lowering the chamber pressure and increasing the margin against combustion instability. During the most recent combustion instability event, the vibrations exceeded the qualification levels for the Flight Termination System. The present study utilizes data generated from T-burner testing of multiple Black Brant propellants at the Naval Air Warfare Center at China Lake, to improve the combustion stability predictions for the Black Brant Mk1 and to generate new predictions for the Mk2. Three unique one dimensional (1-D) stability models were generated, representing distinct Black Brant flights, two of which experienced instabilities. The individual models allowed for comparison of stability characteristics between various nozzle configurations. A long standing "rule of thumb" states that increased stability margin is gained by increasing the throat diameter. In contradiction to this experience based rule, the analysis shows that little or no margin is gained from a larger throat diameter. The present analysis demonstrates competing effects resulting from an increased throat diameter accompanying a large response function. As is expected, more acoustic energy was expelled through the nozzle, but conversely more acoustic energy was generated due to larger gas velocities near the propellant surfaces.

Boiler for combustion fuel in a fluidized bed

Directory of Open Access Journals (Sweden)

Laković Mirjana S.

2015-01-01

Full Text Available Fuel combustion in fluidized bed combustion is a process that is current and which every day gives more attention and there are many studies that have been closely associated with this technology. This combustion technology is widespread and constantly improving the range of benefits it provides primarily due to reduced emissions. This paper presents the boilers for combustion in a fluidized bed, whit characteristics and advantages. Also is shown the development of this type of boilers in Republic of Serbia. In this paper is explained the concept of fluidized bed combustion. Boilers for this type of combustion can be improved and thereby increase their efficiency level. More detailed characteristics are given for boilers with bubbling and circulating fluidized bed as well as their mutual comparison.

Combustion of drops of Mexican fuel oils with high asphaltenes content; Combustion de gotas de combustoleos mexicanos con alto contenido de asfaltenos

Energy Technology Data Exchange (ETDEWEB)

Garcia Rodriguez, Jose Francisco [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

1998-09-01

In this work the combustion of fuel drops with a content of 18% of asphaltenes has been studied . The results obtained for this fuel were compared with the ones obtained for another with a content of 12% asphaltenes. The drops were suspended in a platinum filament and burned in an spherical radiant furnace. The drop size varied between 600 and 800 microns. The fuel drops with 12% asphaltenes showed shorter combustion times, a smaller diameter increment of the smaller diameter during the combustion stages and also a shorter burning time of the carbonaceous residue than the fuel drops with a content of 18% asphaltenes. [Espanol] En el presente trabajo se ha estudiado la combustion de gotas de combustible con 18% de contenido de asfaltenos. Los resultados obtenidos para este combustible se compararon con los obtenidos para otro con 12% de contenido de asfaltenos. Las gotas fueron suspendidas en un filamento de platino y quemadas en un horno radiante esferico. El tamano de las gotas vario entre 600 y 800 micras. Las gotas de combustible con 12% de asfaltenos mostraron tiempos de combustion mas cortos, un incremento del diametro menor durante las etapas de combustion y un tiempo de quemado del residuo carbonoso tambien mas corto que las gotas del combustible con 18% de contenido de asfaltenos.

Hydrogen combustion modelling in large-scale geometries

International Nuclear Information System (INIS)

Studer, E.; Beccantini, A.; Kudriakov, S.; Velikorodny, A.

2014-01-01

Hydrogen risk mitigation issues based on catalytic recombiners cannot exclude flammable clouds to be formed during the course of a severe accident in a Nuclear Power Plant. Consequences of combustion processes have to be assessed based on existing knowledge and state of the art in CFD combustion modelling. The Fukushima accidents have also revealed the need for taking into account the hydrogen explosion phenomena in risk management. Thus combustion modelling in a large-scale geometry is one of the remaining severe accident safety issues. At present day there doesn't exist a combustion model which can accurately describe a combustion process inside a geometrical configuration typical of the Nuclear Power Plant (NPP) environment. Therefore the major attention in model development has to be paid on the adoption of existing approaches or creation of the new ones capable of reliably predicting the possibility of the flame acceleration in the geometries of that type. A set of experiments performed previously in RUT facility and Heiss Dampf Reactor (HDR) facility is used as a validation database for development of three-dimensional gas dynamic model for the simulation of hydrogen-air-steam combustion in large-scale geometries. The combustion regimes include slow deflagration, fast deflagration, and detonation. Modelling is based on Reactive Discrete Equation Method (RDEM) where flame is represented as an interface separating reactants and combustion products. The transport of the progress variable is governed by different flame surface wrinkling factors. The results of numerical simulation are presented together with the comparisons, critical discussions and conclusions. (authors)

Verification of Conditions for use of Combustion Products‘ Heat

Directory of Open Access Journals (Sweden)

Kažimírová Viera

2015-06-01

Full Text Available Presented contribution deals with the verification of conditions for use of combustion products‘ heat, generated by combustion of wood in a fireplace used in a household. It is necessary to know the temperature behaviour of the fireplace to determine the adequacy of the technical solution for using combustion products‘ heat. The combustion products‘ temperature at the upper part of the chimney is 80-120 °C. The dew point value was established to be below 51 °C. The average observed value of combustion product velocity is 1.6 m s-1. The volume flow rate of combustion products is 12 m3 h-1. Measured values allow for effective solution of the use of combustion products‘ heat.

Separating Direct and Indirect Turbofan Engine Combustion Noise While Estimating Post-Combustion (Post-Flame) Residence Time Using the Correlation Function

Science.gov (United States)

Miles, Jeffrey Hilton

2011-01-01

A previous investigation on the presence of direct and indirect combustion noise for a full-scale turbofan engine using a far-field microphone at 130 is extended by also examining signals obtained at two additional downstream directions using far-field microphones at 110 deg and 160 deg. A generalized cross-correlation function technique is used to study the change in propagation time to the far field of the combined direct and indirect combustion noise signal as a sequence of low-pass filters are applied. The filtering procedure used produces no phase distortion. As the low-pass filter frequency is decreased, the travel time increases because the relative amount of direct combustion noise is reduced. The indirect combustion noise signal travels more slowly because in the combustor entropy fluctuations move with the flow velocity, which is slow compared to the local speed of sound. The indirect combustion noise signal travels at acoustic velocities after reaching the turbine and being converted into an acoustic signal. The direct combustion noise is always propagating at acoustic velocities. The results show that the estimated indirect combustion noise time delay values (post-combustion residence times) measured at each angle are fairly consistent with one another for a relevant range of operating conditions and demonstrate source separation of a mixture of direct and indirect combustion noise. The results may lead to a better idea about the acoustics in the combustor and may help develop and validate improved reduced-order physics-based methods for predicting turbofan engine core noise.

Assessing the Potential of Utilization and Storage Strategies for Post-Combustion CO2 Emissions Reduction

International Nuclear Information System (INIS)

Armstrong, Katy; Styring, Peter

2015-01-01

The emissions reduction potential of three carbon dioxide handling strategies for post-combustion capture is considered. These are carbon capture and sequestration/storage (CCS), enhanced hydrocarbon recovery (EHR), and carbon dioxide utilization (CDU) to produce synthetic oil. This is performed using common and comparable boundary conditions including net CO 2 sequestered based on equivalent boundary conditions. This is achieved using a “cradle to grave approach” where the final destination and fate of any product is considered. The input boundary is pure CO 2 that has been produced using a post-combustion capture process as this is common between all processes. The output boundary is the emissions resulting from any product produced with the assumption that the majority of the oil will go to combustion processes. We also consider the “cradle to gate” approach where the ultimate fate of the oil is not considered as this is a boundary condition often applied to EHR processes. Results show that while CCS can make an impact on CO 2 emissions, CDU will have a comparable effect whilst generating income while EHR will ultimately increase net emissions. The global capacity for CDU is also compared against CCS using data based on current and planned CCS projects. Analysis shows that current CDU represent a greater volume of capture than CCS processes and that this gap is likely to remain well beyond 2020 which is the limit of the CCS projects in the database.

Experimental validation for combustion analysis of GOTHIC 6.1b code in 2-dimensional premixed combustion experiments

International Nuclear Information System (INIS)

Lee, J. Y.; Lee, J. J.; Park, K. C.

2003-01-01

In this study, the prediction capability of GOTHIC code for hydrogen combustion phenomena was validated with the results of two-dimensional premixed hydrogen combustion experiment executed by Seoul National University. In the experimental results, we could confirm the propagation characteristics of hydrogen flame such as buoyancy effect, flame front shape etc.. The combustion time of the tests was about 0.1 sec.. In the GOTHIC analyses results, the GOTHIC code could predict the overall hydrogen flame propagation characteristics but the buoyancy effect and flame shape did not compare well with the experimental results. Especially, in case of the flame propagate to the dead-end, GOTHIC predicted the flame did not affected by the flow and this cause quite different results in flame propagation from experimental results. Moreover the combustion time of the analyses was about 1 sec. which is ten times longer than the experimental result. To obtain more reasonable analysis results, it is necessary that combustion model parameters in GOTHIC code apply appropriately and hydrogen flame characteristics be reflected in solving governing equations

System and method for engine combustion

Science.gov (United States)

Sczomak, David P.; Gallon, Robert J.; Solomon, Arun S.

2018-03-13

A combustion system for use with one or more cylinder bores of an internal combustion engine includes at least one cylinder head defining first and second intake ports in fluid communication with the one or more cylinder bores. A flap is adjustably connected to the at least one cylinder head. The flap includes a first flap portion cooperating with the first intake port extending from an arm and a second flap portion cooperating with the second intake port extending from the arm and disposed adjacent the first flap portion. A controller in electrical communication with an actuator monitors the condition of the engine and actuates the flap to position the first and second flap portions between first and second positions to create a first combustion condition and a second combustion condition.

Techniques for Liquid Rocket Combustion Spontaneous Stability and Rough Combustion Assessments

Science.gov (United States)

Kenny, R. J.; Giacomoni, C.; Casiano, M. J.; Fischbach, S. R.

2016-01-01

This work presents techniques for liquid rocket engine combustion stability assessments with respect to spontaneous stability and rough combustion. Techniques covering empirical parameter extraction, which were established in prior works, are applied for three additional programs: the F-1 Gas Generator (F1GG) component test program, the RS-84 preburner component test program, and the Marshall Integrated Test Rig (MITR) program. Stability assessment parameters from these programs are compared against prior established spontaneous stability metrics and updates are identified. Also, a procedure for comparing measured with predicted mode shapes is presented, based on an extension of the Modal Assurance Criterion (MAC).

Contributions of fuel combustion to pollution by airborne particles in urban and non-urban environments

International Nuclear Information System (INIS)

1995-06-01

The application of ion beam analysis (IBA) techniques to aerosol pollution problems has been used in a number of countries since the late 1970's and early 1980's. The technique, however, had not been tested in Australia. This document is the final report of a project which aimed to establish a fine particle monitoring network covering the greater Wollongong/Sydney/ Newcastle ares, investigate the relationships between fuel combustion and fine particle aerosols in urban and non urban environments, add to the limited database of baseline information on concentrations of fine particles resulting from such processes as fossil fuel burning and industrial manufacturing, identify and quantify sources of fine particles in New South Wales, and introduce into Australia accelerator based IBA techniques for the analysis of filter papers obtained from large scale monitoring networks. These objectives were addressed by the project which identified and quantified some sources of fine particles and established some relationships between fuel combustion and fine aerosols. More work is required to fully quantify relationships between natural and anthropogenic fine particle sources. 24 tabs., 44 figs., 83 refs

Highly time-resolved imaging of combustion and pyrolysis product concentrations in solid fuel combustion: NO formation in a burning cigarette.

Science.gov (United States)

Zimmermann, Ralf; Hertz-Schünemann, Romy; Ehlert, Sven; Liu, Chuan; McAdam, Kevin; Baker, Richard; Streibel, Thorsten

2015-02-03

The highly dynamic, heterogeneous combustion process within a burning cigarette was investigated by a miniaturized extractive sampling probe (microprobe) coupled to photoionization mass spectrometry using soft laser single photon ionization (SPI) for online real-time detection of molecular ions of combustion and pyrolysis products. Research cigarettes smoked by a smoking machine are used as a reproducible model system for solid-state biomass combustion, which up to now is not addressable by current combustion-diagnostic tools. By combining repetitively recorded online measurement sequences from different sampling locations in an imaging approach, highly time- and space-resolved quantitative distribution maps of, e.g., nitrogen monoxide, benzene, and oxygen concentrations were obtained at a near microscopic level. The obtained quantitative distribution maps represent a time-resolved, movie-like imaging of the respective compound's formation and destruction zones in the various combustion and pyrolysis regions of a cigarette during puffing. Furthermore, spatially resolved kinetic data were ascertainable. The here demonstrated methodology can also be applied to various heterogenic combustion/pyrolysis or reaction model systems, such as fossil- or biomass-fuel pellet combustion or to a positional resolved analysis of heterogenic catalytic reactions.

Environmental optimisation of waste combustion

Energy Technology Data Exchange (ETDEWEB)

Schuster, Robert [AaF Energikonsult, Stockholm (Sweden); Berge, Niclas; Stroemberg, Birgitta [TPS Termiska Processer AB, Nykoeping (Sweden)

2000-12-01

The regulations concerning waste combustion evolve through R and D and a strive to get better and common regulations for the European countries. This study discusses if these rules of today concerning oxygen concentration, minimum temperature and residence time in the furnace and the use of stand-by burners are needed, are possible to monitor, are the optimum from an environmental point of view or could be improved. No evidence from well controlled laboratory experiments validate that 850 deg C in 6 % oxygen content in general is the best lower limit. A lower excess air level increase the temperature, which has a significant effect on the destruction of hydrocarbons, favourably increases the residence time, increases the thermal efficiency and the efficiency of the precipitators. Low oxygen content is also necessary to achieve low NO{sub x}-emissions. The conclusion is that the demands on the accuracy of the measurement devices and methods are too high, if they are to be used inside the furnace to control the combustion process. The big problem is however to find representative locations to measure temperature, oxygen content and residence time in the furnace. Another major problem is that the monitoring of the operation conditions today do not secure a good combustion. It can lead to a false security. The reason is that it is very hard to find boilers without stratifications. These stratifications (stream lines) has each a different history of residence time, mixing time, oxygen and combustible gas levels and temperature, when they reach the convection area. The combustion result is the sum of all these different histories. The hydrocarbons emission is in general not produced at a steady level. Small clouds of unburnt hydrocarbons travels along the stream lines showing up as peaks on a THC measurement device. High amplitude peaks has a tendency to contain higher ratio of heavy hydrocarbons than lower peaks. The good correlation between some easily detected

Mechanisms and kinetics of granulated sewage sludge combustion.

Science.gov (United States)

Kijo-Kleczkowska, Agnieszka; Środa, Katarzyna; Kosowska-Golachowska, Monika; Musiał, Tomasz; Wolski, Krzysztof

2015-12-01

This paper investigates sewage sludge disposal methods with particular emphasis on combustion as the priority disposal method. Sewage sludge incineration is an attractive option because it minimizes odour, significantly reduces the volume of the starting material and thermally destroys organic and toxic components of the off pads. Additionally, it is possible that ashes could be used. Currently, as many as 11 plants use sewage sludge as fuel in Poland; thus, this technology must be further developed in Poland while considering the benefits of co-combustion with other fuels. This paper presents the results of experimental studies aimed at determining the mechanisms (defining the fuel combustion region by studying the effects of process parameters, including the size of the fuel sample, temperature in the combustion chamber and air velocity, on combustion) and kinetics (measurement of fuel temperature and mass changes) of fuel combustion in an air stream under different thermal conditions and flow rates. The combustion of the sludge samples during air flow between temperatures of 800 and 900°C is a kinetic-diffusion process. This process determines the sample size, temperature of its environment, and air velocity. The adopted process parameters, the time and ignition temperature of the fuel by volatiles, combustion time of the volatiles, time to reach the maximum temperature of the fuel surface, maximum temperature of the fuel surface, char combustion time, and the total process time, had significant impacts. Copyright © 2015 Elsevier Ltd. All rights reserved.

Effects of streamwise vortex breakdown on supersonic combustion.

Science.gov (United States)

Hiejima, Toshihiko

2016-04-01

This paper presents a numerical simulation study of the combustion structure of streamwise vortex breakdown at Mach number 2.48. Hydrogen fuel is injected into a combustor at sonic speed from the rear of a hypermixer strut that can generate streamwise vortices. The results show that the burning behavior is enhanced at the points of the shock waves that are incident on the vortex and therefore the vortex breakdown in the subsonic region occurs due to combustion. The breakdown domain in the mainstream is found to form a flame-holding region suited to combustion and to lead to a stable combustion field with detached flames. In this way, streamwise vortex breakdown has an essential role in combustion enhancement and the formation of flames that hold under supersonic inflow conditions. Finally, the combustion property defined here is shown to coincide with the produced-water mass flow. This property shows that the amount of combustion is saturated at equivalence ratios over 0.4, although there is a slight increase beyond 1.

CFD Modelling of Biomass Combustion in Small-Scale Boilers. Final Report

Energy Technology Data Exchange (ETDEWEB)

Xue-Song Bai; Griselin, Niklas; Klason, Torbern; Nilsson, Johan [Lund Inst. of Tech. (Sweden). Dept. of Heat and Power Engineering

2002-10-01

This project deals with CFD modeling of combustion of wood in fixed bed boilers. A flamelet model for the interaction between turbulence and chemical reactions is developed and applied to study small-scale boiler. The flamelet chemistry employs 43 reactive species and 174 elementary reactions. It gives detailed distributions of important species such as CO and NO{sub x} in the flow field and flue gas. Simulation of a small-scale wood fired boiler measured at SP Boraas (50 KW) shows that the current flamelet model yields results agreeable to the available experimental data. A detailed chemical kinetic model is developed to study the bed combustion process. This model gives boundary conditions for the CFD analysis of gas phase volatile oxidation in the combustion chambers. The model combines a Functional Group submodel with a Depolymerisation, Vaporisation and Crosslinking submodel. The FG submodel simulates how functional groups decompose and form light gas species. The DVC submodell predicts depolymerisation and vaporisation of the macromolecular network and this includes bridge breaking and crosslinking processes, where the wood structure breaks down to fragments. The light fragments form tar and the heavy ones form metaplast. Two boilers firing wood log/chips are studied using the FG-DVC model, one is the SP Boraas small-scale boiler (50 KW) and the other is the Sydkraft Malmoe Vaerme AB's Flintraennan large-scale boiler (55 MW). The fix bed is assumed to be two zones, a partial equilibrium drying/devolatilisation zone and an equilibrium zone. Three typical biomass conversion modes are simulated, a lean fuel combustion mode, a near-stoichiometric combustion and a fuel rich gasification mode. Detailed chemical species and temperatures at different modes are obtained. Physical interpretation is provided. Comparison of the computational results with experimental data shows that the model can reasonably simulate the fixed bed biomass conversion process. CFD

Component Development to Accelerate Commercial Implementation of Ultra-Low Emissions Catalytic Combustion

Energy Technology Data Exchange (ETDEWEB)

McCarty, Jon; Berry, Brian; Lundberg, Kare; Anson, Orris

2003-03-31

This final report describes a 2000-2003 program for the development of components and processes to enhance the commercialization of ultra-low emissions catalytic combustion in industrial gas turbines. The range of project tasks includes: development of more durable, lower-cost catalysts and catalytic combustor components; development and design of a catalytic pre-burner and a catalytic pilot burner for gas turbines, and on-site fuel conversion processing for utilization of liquid fuel.

Development of a NO/x/-free combustion system

Science.gov (United States)

Sadakata, M.; Furusawa, T.; Kunii, D.; Imagawa, M.; Nawada, M.

1980-04-01

The development of a NO(x)-free combustion-heating system realizing both pollution control and energy savings is described. An experiment was carried out by using a small model plant. The system consists of a combustion furnace and a new-type multifunctional heat exchanger. The heat exchanger is a rotary continuous type designed for soot collection and for catalytic combustion of CO and H2 as well as for preheating combustion air.

Combustion and Ignition Studies of Nanocomposite Energetic Materials

Science.gov (United States)

2010-12-14

Characterization of a gas burner to simulate a propellant flame and evaluate aluminum particle combustion,” M. Jackson, M. L. Pantoya and W. Gill, Combustion...of a gas burner to simulate a propellant flame and evaluate aluminum particle combustion,” M. Jackson, M. L. Pantoya and W. Gill, Combustion and...changes in parameters such as particle size. The LFA measures these properties for bulk powders, consolidated pellets or even liquid mediums and is

The John Zink Hamworthy combustion handbook

CERN Document Server

Baukal, Charles E

2013-01-01

Despite the length of time it has been around, its importance, and vast amounts of research, combustion is still far from being completely understood. Issues regarding the environment, cost, and fuel consumption add further complexity, particularly in the process and power generation industries. Dedicated to advancing the art and science of industrial combustion, The John Zink Hamworthy Combustion Handbook, Second Edition: Volume 3 - Applications offers comprehensive, up-to-date coverage of equipment used in the process and power generation industries. Under the leadership of Charles E. Baukal

Chaotic combustion in spark ignition engines

International Nuclear Information System (INIS)

Wendeker, Miroslaw; Czarnigowski, Jacek; Litak, Grzegorz; Szabelski, Kazimierz

2003-01-01

We analyse the combustion process in a spark ignition engine using the experimental data of an internal pressure during the combustion process and show that the system can be driven to chaotic behaviour. Our conclusion is based on the observation of unperiodicity in the time series, suitable stroboscopic maps and a complex structure of a reconstructed strange attractor. This analysis can explain that in some circumstances the level of noise in spark ignition engines increases considerably due to nonlinear dynamics of a combustion process

Combustion Gases And Heat Release Analysis During Flame And Flameless Combustion Of Wood Pellets

Directory of Open Access Journals (Sweden)

Horváth Jozef

2015-06-01

Full Text Available With the growing prices of fossil fuels, alternative fuels produced of biomass come to the fore. They are made of waste materials derived from the processing of wood and wood materials. The main objective of this study was to analyse the fire-technical characteristics of wood pellets. The study analysed three dust samples acquired from wood pellets made of various types of wood biomass. Wood pellet dust is produced when manipulating with pellets. During this process a potentially hazardous situations may occur. Biomass is chemically composed mostly of hemicellulose, cellulose and lignin. During straining of the biomass by heat flux, combustion initiation occurs. Also, there was a change in the composition of material throughout combustion gases production, and the amount of heat generated by a flame or flameless combustion. Measurement of fire characteristics was conducted according to ISO 5660-1 standard using a cone calorimeter. Two samples of wood pellet dust were tested under the heat flux of 35 kW.m−2 and 50 kW.m−2. The process of combustion, the time to ignition, the carbon monoxide concentration and the amount of released heat were observed.

Emission characteristics of premixed lean diesel combustion. Effects of injection nozzle and combustion chamber shape on combustion and emission characteristics; Kihaku yokongo diesel nensho no haishutsubutsu tokusei. Funmu keijo oyobi nenshoshitsu keijo ga haishutsu gas tokusei ni oyobosu eikyo

Energy Technology Data Exchange (ETDEWEB)

Harada, A; Sasaki, S; Miyamoto, T; Akagawa, H; Tsujimura, K

1997-10-01

Many articles about low NOx emission combustion are reported. A mixture formation is necessary to success low NOx emission combustion. But, there is few reports about the effect of nozzle and combustion shape on emissions which give influence on mixture. In this paper, the effects on characteristic of combustion and emissions of some land of injection nozzle and combustion chamber shape were investigated. As a result, it was cleared that the influence of combustion chamber shape on characteristic of combustion and emissions was varied by spray shape, and pintle type injection nozzle was suitable for PREDIC. 7 refs., 10 figs., 1 tab.

A comprehensive study of combustion products generated from pulverized peat combustion in the furnace of BKZ-210-140F steam boiler

Science.gov (United States)

Kuzmin, V. A.; Zagrai, I. A.

2017-11-01

The experimental and theoretical study of combustion products has been carried out for the conditions of pulverized peat combustion in BKZ-210-140F steam boiler. Sampling has been performed in different parts of the boiler system in order to determine the chemical composition, radiative properties and dispersity of slag and ash particles. The chemical composition of particles was determined using the method of x-ray fluorescence analysis. Shapes and sizes of the particles were determined by means of electron scanning microscopy. The histograms and the particle size distribution functions were computed. The calculation of components of the gaseous phase was based on the combustion characteristics of the original fuel. The software package of calculation of thermal radiation of combustion products from peat combustion was used to simulate emission characteristics (flux densities and emissivity factors). The dependence of emission characteristics on the temperature level and on the wavelength has been defined. On the basis of the analysis of emission characteristics the authors give some recommendations how to determine the temperature of peat combustion products in the furnace of BKZ-210-140F steam boiler. The findings can be used to measure the combustion products temperature, support temperature control in peat combustion and solve the problem of boiler furnace slagging.

Numerical Studies on Controlling Gaseous Fuel Combustion by Managing the Combustion Process of Diesel Pilot Dose in a Dual-Fuel Engine

Directory of Open Access Journals (Sweden)

Mikulski Maciej

2015-06-01

Full Text Available Protection of the environment and counteracting global warming require finding alternative sources of energy. One of the methods of generating energy from environmentally friendly sources is increasing the share of gaseous fuels in the total energy balance. The use of these fuels in compression-ignition (CI engines is difficult due to their relatively high autoignition temperature. One solution for using these fuels in CI engines is operating in a dualfuel mode, where the air and gas mixture is ignited with a liquid fuel dose. In this method, a series of relatively complex chemical processes occur in the engine's combustion chamber, related to the combustion of individual fuel fractions that interact with one another. Analysis of combustion of specific fuels in this type of fuel injection to the engine is difficult due to the fact that combustion of both fuel fractions takes place simultaneously. Simulation experiments can be used to analyse the impact of diesel fuel combustion on gaseous fuel combustion. In this paper, we discuss the results of simulation tests of combustion, based on the proprietary multiphase model of a dual-fuel engine. The results obtained from the simulation allow for analysis of the combustion process of individual fuels separately, which expands the knowledge obtained from experimental tests on the engine.

AKR1C1 as a Biomarker for Differentiating the Biological Effects of Combustible from Non-Combustible Tobacco Products.

Science.gov (United States)

Woo, Sangsoon; Gao, Hong; Henderson, David; Zacharias, Wolfgang; Liu, Gang; Tran, Quynh T; Prasad, G L

2017-05-03

Smoking has been established as a major risk factor for developing oral squamous cell carcinoma (OSCC), but less attention has been paid to the effects of smokeless tobacco products. Our objective is to identify potential biomarkers to distinguish the biological effects of combustible tobacco products from those of non-combustible ones using oral cell lines. Normal human gingival epithelial cells (HGEC), non-metastatic (101A) and metastatic (101B) OSCC cell lines were exposed to different tobacco product preparations (TPPs) including cigarette smoke total particulate matter (TPM), whole-smoke conditioned media (WS-CM), smokeless tobacco extract in complete artificial saliva (STE), or nicotine (NIC) alone. We performed microarray-based gene expression profiling and found 3456 probe sets from 101A, 1432 probe sets from 101B, and 2717 probe sets from HGEC to be differentially expressed. Gene Set Enrichment Analysis (GSEA) revealed xenobiotic metabolism and steroid biosynthesis were the top two pathways that were upregulated by combustible but not by non-combustible TPPs. Notably, aldo-keto reductase genes, AKR1C1 and AKR1C2 , were the core genes in the top enriched pathways and were statistically upregulated more than eight-fold by combustible TPPs. Quantitative real time polymerase chain reaction (qRT-PCR) results statistically support AKR1C1 as a potential biomarker for differentiating the biological effects of combustible from non-combustible tobacco products.

HTP kinetics studies on isolated elementary combustion reactions over wide temperature ranges

Energy Technology Data Exchange (ETDEWEB)

Fontijn, A.; Adusei, G.Y.; Hranisavlevic, J.; Bajaj, P.N. [Rensselaer Polytechnic Institute, Troy, NY (United States)

1993-12-01

The goals of this project are to provide accurate data on the temperature dependence of the kinetics of elementary combustion reactions, (i) for use by combustion modelers, and (ii) to gain a better fundamental understanding of, and hence predictive ability for, the chemistry involved. Experimental measurements are made mainly by using the pseudo-static HTP (high-temperature photochemistry) technique. While continuing rate coefficient measurements, further aspects of kinetics research are being explored. Thus, starting from the data obtained, a method for predicting the temperature dependence of rate coefficients of oxygen-atom olefin experiment and confirms the underlying mechanistic assumptions. Mechanistic information of another sort, i.e. by product analysis, has recently become accessible with the inauguration of our heated flow tube mass spectrometer facility; early results are reported here. HTP experiments designed to lead to measurements of product channels by resonance fluorescence have started.

Internal Heterogeneous Processes in Aluminum Combustion

Science.gov (United States)

Dreizin, E. L.

1999-01-01

This paper discusses the aluminum particle combustion mechanism which has been expanded by inclusion of gas dissolution processes and ensuing internal phase transformations. This mechanism is proposed based on recent normal and microgravity experiments with particles formed and ignited in a pulsed micro-arc. Recent experimental findings on the three stages observed in Al particle combustion in air and shows the burning particle radiation, trajectory (streak), smoke cloud shapes, and quenched particle interiors are summarized. During stage I, the radiation trace is smooth and the particle flame is spherically symmetric. The temperature measured using a three-color pyrometer is close to 3000 K. Because it exceeds the aluminum boiling point (2730 K), this temperature most likely characterizes the vapor phase flame zone rather than the aluminum surface. The dissolved oxygen content within particles quenched during stage I was below the detection sensitivity (about 1 atomic %) for Wavelength Dispersive Spectroscopy (WDS). After an increase in the radiation intensity (and simultaneous decrease in the measured color temperature from about 3000 to 2800 K) indicative of the transition to stage II combustion, the internal compositions of the quenched particles change. Both oxygen-rich (approx. 10 atomic %) and oxygen-lean (combustion behavior and the evolution of its internal composition, the change from the spherically symmetric to asymmetric flame shape occurring upon the transition from stage I to stage II combustion could not be understood based only on the fact that dissolved oxygen is detected in the particles. The connection between the two phenomena appeared even less significant because in earlier aluminum combustion studies carried in O2/Ar mixtures, flame asymmetry was not observed as opposed to experiments in air or O2/CO mixtures. It has been proposed that the presence of other gases, i.e., hydrogen, or nitrogen causes the change in the combustion regime.

Science review of internal combustion engines

International Nuclear Information System (INIS)

Taylor, Alex M.K.P.

2008-01-01

Internal combustion engines used in transportation produce about 23% of the UK's carbon dioxide emission, up from 14% in 1980. The current science described in this paper suggests that there could be 6-15% improvements in internal combustion fuel efficiency in the coming decade, although filters to meet emission legislation reduce these gains. Using these engines as hybrids with electric motors produces a reduction in energy requirements in the order of 21-28%. Developments beyond the next decade are likely to be dominated by four topics: emission legislation and emission control, new fuels, improved combustion and a range of advanced concepts for energy saving. Emission control is important because current methods for limiting nitrogen oxides and particulate emissions imply extra energy consumption. Of the new fuels, non-conventional fossil-derived fuels are associated with larger greenhouse gas emissions than conventional petroleum-based fuels, while a vehicle propelled by fuel cells consuming non-renewable hydrogen does not necessarily offer an improvement in emissions over the best hybrid internal combustion engines. Improved combustion may be developed for both gasoline and diesel fuels and promises better efficiency as well as lower noxious emissions without the need for filtering. Finally, four advanced concepts are considered: new thermodynamic cycles, a Rankine bottoming cycle, electric turbo-compounding and the use of thermoelectric devices. The latter three all have the common theme of trying to extract energy from waste heat, which represents about 30% of the energy input to an internal combustion engine

Research on combustion of black-liquor drops

International Nuclear Information System (INIS)

Macek, A.

1999-01-01

Black liquor, the major by-product of the kraft process for production of pulp, is one of the most important industrial fuels. It is burned in recovery boilers in the form of large spray drops (mm), with the objective of simultaneous recovery of heat and chemicals (sodium and sulfur). Even though black-liquor combustion in boilers has been practised for over half a century, research efforts toward improvement of combustion efficiency and abatement of environmental emissions are much more recent. The present paper addresses a specific aspect of that research, namely, elucidation of processes which occur during combustion of black-liquor drops in boiler-gas streams. The paper (a) gives a brief description of the kraft process, (b) reviews the experimental and theoretical (modeling) research advances on combustion of kraft-liquor drops during the 1980s and 1990s, (c) re-examines the results of an earlier combustion study in which black-liquor drops were observed in free flight at temperatures near those in recovery boilers, and (d) recommends input for the modeling of in-flight combustion of kraft-liquor drops in recovery boilers. (author)

Low emission turbulent technology for fuel combustion

International Nuclear Information System (INIS)

Finker, F. Z.; Kubyshkin, I. B.; Zakharov, B. Yu.; Akhmedov, D. B.; Sobchuk, Ch.

1997-01-01

The company 'POLITEKHENERGO' in co-operation and the Russian-Poland firm 'EnergoVIR' have performed investigations for modernization of the current existing boilers. A low emission turbulent technology has been used for the modernization of 10 industrial boilers. The reduction of NO x emissions is based on the following processes: 1) multistage combustion assured by two counter-deviated fluxes; 2) Some of the combustion facilities have an abrupt slope and a reduced air supply which leads to an intense separation of the fuel in the bottom part and a creation of a low-temperature combustion zone where the active restoration of the NO x takes part; 3) The influence of the top high-temperature zone on the NO x formation is small. Thus the 'sandwich' consisting of 'cold' and'hot' combustion layers provides a full rate combustion. This technique permits to: decrease of the NO x and CO x down to the European standard values;increase of the efficiency in 1-2%; obtain a stable coal combustion up to 97-98%; assure the large loading range (30 -100%); modernize and use the old boilers

Simulation of lean premixed turbulent combustion

International Nuclear Information System (INIS)

Bell, J; Day, M; Almgren, A; Lijewski, M; Rendleman, C; Cheng, R; Shepherd, I

2006-01-01

There is considerable technological interest in developing new fuel-flexible combustion systems that can burn fuels such as hydrogen or syngas. Lean premixed systems have the potential to burn these types of fuels with high efficiency and low NOx emissions due to reduced burnt gas temperatures. Although traditional Scientific approaches based on theory and laboratory experiment have played essential roles in developing our current understanding of premixed combustion, they are unable to meet the challenges of designing fuel-flexible lean premixed combustion devices. Computation, with its ability to deal with complexity and its unlimited access to data, has the potential for addressing these challenges. Realizing this potential requires the ability to perform high fidelity simulations of turbulent lean premixed flames under realistic conditions. In this paper, we examine the specialized mathematical structure of these combustion problems and discuss simulation approaches that exploit this structure. Using these ideas we can dramatically reduce computational cost, making it possible to perform high-fidelity simulations of realistic flames. We illustrate this methodology by considering ultra-lean hydrogen flames and discuss how this type of simulation is changing the way researchers study combustion

Solid waste combustion for alpha waste incineration

International Nuclear Information System (INIS)

Orloff, D.I.

1981-02-01

Radioactive waste incinerator development at the Savannah River Laboratory has been augmented by fundamental combustion studies at the University of South Carolina. The objective was to measure and model pyrolysis and combustion rates of typical Savannah River Plant waste materials as a function of incinerator operating conditions. The analytical models developed in this work have been incorporated into a waste burning transient code. The code predicts maximum air requirement and heat energy release as a function of waste type, package size, combustion chamber size, and temperature. Historically, relationships have been determined by direct experiments that did not allow an engineering basis for predicting combustion rates in untested incinerators. The computed combustion rates and burning times agree with measured values in the Savannah River Laboratory pilot (1 lb/hr) and full-scale (12 lb/hr) alpha incinerators for a wide variety of typical waste materials

The use of sewage sludge as additive to avoid operational problems at combustion of shredder residues

International Nuclear Information System (INIS)

Gyllenhammar, Marianne

2010-01-01

When shredder light fraction (SLF) from recovery of metal scrap is energy recovered it is usually mixed with more than 90% of other wastes. SLF is a fuel with high energy content but also with relatively high chlorine and metal content and could cause deposit and corrosion problems in incineration plants. Sewage sludge has previously been shown to reduce deposition and corrosion problems in combustion of alkali and chlorine containing biomass. In this work 20 % SLF (by energy content) has been combusted together with municipal solid waste and industrial wastes, with and without addition of 3 % (by energy content) sewage sludge. The initial fireside corrosion rate was then compared to the corrosion rate during combustion of the normal fuel mix, i.e. only municipal solid waste and industrial wastes. The tests were done at the 20 MW fluidized bed boiler of Lidkoping heat production plant. During the tests air-cooled corrosion and deposit probes were exposed for 24 hours. Deposit probes were placed at three different flue gas temperatures - in the combustion chamber, upstream and downstream the convection pass. The corrosion probes were placed upstream the convection pass and on the probes there were three different materials at three different water temperatures (280, 350 and 420 degree Celsius). The tests showed that sewage sludge could help avoiding deposition and corrosion problems when incinerating SLF. The amount of deposits was reduced and the content of the deposits was less corrosive when sewage sludge was added. The project was financed by Waste Refinery as a collaboration project between Stena Metall AB, Metso AB, High Temperature Corrosion Center at Chalmers University of Technology, SP Technical Research Institute of Sweden and Lidkopings Varmeverk. (author)

Fuel reactivity and release of pollutants and alkali vapours in pressurized combustion for combined cycle power generation

Energy Technology Data Exchange (ETDEWEB)

Aho, M.; Haemaelaeinen, J.; Paakkinen, K.; Rantanen, J. [VTT Energy, Jyvaeskylae (Finland); Hernberg, R.; Haeyrinen, V.; Joutsenoja, T. [Tampere Univ. of Technology (Finland). Lab. of Plasma Technology

1996-12-01

This project forms a part of the overall Pressurized Power Coal Combustion Project Area (PPFC) which aims at an assessment of the viability and technical merits of pressurized pulverized coal combustion, in an atmosphere of recycled flue gas and oxygen in a coordinated and harmonized programme. The objective of the research at Technical Research Centre of Finland (VTT) and Tampere University of Technology (TUT) is aimed at determining the consequences of solid fuel burning in a mixture of oxygen and recycled flue gases. Combustion conditions of a pressurized entrained flow of pulverized coal and char particles in PEFR are determined with high precision. The effects of experimental parameters on the formation of nitrogen oxides (N{sub 2}O, NO and NO{sub 2}) and gaseous alkali compounds (indicated as NaX(g) and KX(g)) are studied. An effective on-line analysis method for vaporised Na and K compounds was developed. The dependency between particle temperatures and the vaporisation of Na and K was measured with three coals. The results show that alkali removal before gas turbines is always necessary with these coals if combusted in combined cycles. Pressure decreases the formation of NO and has usually no clear effect on the formation of N{sub 2}O. The order of NO/N{sub 2}O ratios correspond to fuel-O/fuel-N ratios. Increase of PO{sub 2} (oxygen concentration) of combustion gas increases the formation of NO{sub 2}. Remarkable concentrations of NO{sub 2} were often measured at high PO{sub 2} at 800-850 deg C. Therefore, NO{sub 2} should be measured from pressurized fluidized bed reactors. Some trends of the formation of NO{sub 2} with coal differ clearly from those with its parent char: N{sub 2}O formation is not strongly temperature dependent with char, and the concentrations of N{sub 2}O formed from char are much lower than those of coal. PO{sub 2} does not effect on the formation of NO from char in the studied range

Pressurised combustion of biomass-derived, low calorific value, fuel gas

Energy Technology Data Exchange (ETDEWEB)

Andries, J; Hoppesteyn, P D.J.; Hein, K R.G. [Lab. for Thermal Power Engineering, Dept. of Mechanical Engineering and Marine Technology, Delft Univ. of Technology (Netherlands)

1997-12-31

The Laboratory for Thermal Power Engineering of the Delft University of Technology is participating in an EU-funded, international R + D project which is designed to aid European industry in addressing issues regarding pressurised combustion of biomass-derived, low calorific flue fuel gas. The objects of the project are: To design, manufacture and test a pressurised, high temperature gas turbine combustor for biomass derived LCV fuel gas; to develop a steady-state and dynamic model describing a combustor using biomass-derived, low calorific value fuel gases; to gather reliable experimental data on the steady-state and dynamic characteristics of the combustor; to study the steady-state and dynamic plant behaviour using a plant layout wich incorporates a model of a gas turbine suitable for operation on low calorific value fuel gas. (orig)

Pressurised combustion of biomass-derived, low calorific value, fuel gas

Energy Technology Data Exchange (ETDEWEB)

Andries, J.; Hoppesteyn, P.D.J.; Hein, K.R.G. [Lab. for Thermal Power Engineering, Dept. of Mechanical Engineering and Marine Technology, Delft Univ. of Technology (Netherlands)

1996-12-31

The Laboratory for Thermal Power Engineering of the Delft University of Technology is participating in an EU-funded, international R + D project which is designed to aid European industry in addressing issues regarding pressurised combustion of biomass-derived, low calorific flue fuel gas. The objects of the project are: To design, manufacture and test a pressurised, high temperature gas turbine combustor for biomass derived LCV fuel gas; to develop a steady-state and dynamic model describing a combustor using biomass-derived, low calorific value fuel gases; to gather reliable experimental data on the steady-state and dynamic characteristics of the combustor; to study the steady-state and dynamic plant behaviour using a plant layout wich incorporates a model of a gas turbine suitable for operation on low calorific value fuel gas. (orig)

A Second Generation Swirl-Venturi Lean Direct Injection Combustion Concept

Science.gov (United States)

Tacina, Kathleen M.; Chang, Clarence T.; He, Zhuohui Joe; Lee, Phil; Dam, Bidhan; Mongia, Hukam

2014-01-01

A low-NO (sub x) aircraft gas turbine engine combustion concept was developed and tested. The concept is a second generation swirl-venturi lean direct injection (SV-LDI) concept. LDI is a lean-burn combustion concept in which the fuel is injected directly into the flame zone. Three second generation SV-LDI configurations were developed. All three were based on the baseline 9-point SV-LDI configuration reported previously. These second generation configurations had better low power operability than the baseline 9-point configuration. Two of these second generation configurations were tested in a NASA Glenn Research Center flametube; these two configurations are called the at dome and 5-recess configurations. Results show that the 5-recess configuration generally had lower NO (sub x) emissions than the flat dome configuration. Correlation equations were developed for the flat dome configuration so that the landing-takeoff NO (sub x) emissions could be estimated. The flat dome landing-takeoff NO (sub x) is estimated to be 87-88 percent below the CAEP/6 standards, exceeding the ERA project goal of 75 percent reduction.

Study of experimental validation for combustion analysis of GOTHIC code

International Nuclear Information System (INIS)

Lee, J. Y.; Yang, S. Y.; Park, K. C.; Jeong, S. H.

2001-01-01

In this study, present lumped and subdivided GOTHIC6 code analyses of the premixed hydrogen combustion experiment at the Seoul National University and comparison with the experiment results. The experimental facility has 16367 cc free volume and rectangular shape. And the test was performed with unit equivalence ratio of the hydrogen and air, and with various location of igniter position. Using the lumped and mechanistic combustion model in GOTHIC6 code, the experiments were simulated with the same conditions. In the comparison between experiment and calculated results, the GOTHIC6 prediction of the combustion response does not compare well with the experiment results. In the point of combustion time, the lumped combustion model of GOTHIC6 code does not simulate the physical phenomena of combustion appropriately. In the case of mechanistic combustion model, the combustion time is predicted well, but the induction time of calculation data is longer than the experiment data remarkably. Also, the laminar combustion model of GOTHIC6 has deficiency to simulate combustion phenomena unless control the user defined value appropriately. And the pressure is not a proper variable that characterize the three dimensional effect of combustion

A comprehensive review of oil spill combustion studies

International Nuclear Information System (INIS)

Walavalkar, A.Y.; Kulkarni, A.K.

1996-01-01

The complex process of in-situ burning of oil or a water-in-oil emulsion floating on top of a water-base, such as the ocean, was discussed. The process was examined before, during and after actual combustion. In general, the success of oil spill combustion is measured in terms of the fraction of the spilled oil or emulsion that is burned away. However, the air and aquatic pollution caused by the combustion should also be considered. The physical conditions such as wind velocity, waves and the presence or absence of a containment device, such as a fire boom, could determine the continuation of the combustion process. An overview of the oil spill combustion techniques was provided. There still remains a need for fundamental studies, especially in mathematical modeling, to understand the basic mechanisms and predict the applicability of the in-situ combustion. 74 refs., 7 tabs., 3 figs

Formation of fuel NOx during black-liquor combustion

International Nuclear Information System (INIS)

Nichols, K.M.; Lien, S.J.

1993-01-01

Fuel NOx and thermal NOx were measured in combustion gases from black liquors in two laboratory furnaces. Combustion at 950 C in air (8% O 2 ) produced NOx concentrations of 40-80ppm. Combustion at 950 C in synthetic air containing no nitrogen (21% 0 2 in Ar) produced the same result, demonstrating that all of the NOx produced during combustion at 950 C was fuel NOx. Formation of fuel NOx increased moderately with increasing temperature in the range of 800-1,000 C, but temperature sensitivity of fuel NOx was much less than that of thermal NOx. The results imply that the major source of NOx in recovery furnace emissions is the fuel NOx in recovery furnace formed by conversion of liquor-bound nitrogen during combustion. This is consistent with thermal NOx theory, which postulates that black-liquor combustion temperatures are too low to generate significant amounts of thermal NOx