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Sample records for combusting estonian oil

  1. Characteristic fly-ash particles from oil-shale combustion found in lake sediments

    International Nuclear Information System (INIS)

    Alliksaar, T.; Hoerstedt, P.; Renberg, I.

    1998-01-01

    Fly-ash particles accumulate in sediments and can be used to assess spatial distribution and temporal trends of atmospheric deposition of pollutants derived from high temperature combustion of fossil fuels. Previous work has concerned fly-ash derived from oil and coal. Oil-shale is the main fossil fuel used in Estonia and a major source of atmospheric pollution in the Baltic states. To assess if oil-shale power plants produce specific fly-ash particles scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDX) were used to compare fly-ash particles from oil-shale combustion with particles from oil and coal combustion. Two types were analysed, large black (10-30μm) and small glassy (< 5 μm) spheroidal particles. Although article morphology to some extent is indicative of the fuel burnt, morphological characters are not sufficient to differentiate between particles of different origin. However, the results indicate that with EDX analysis the fly-ash from oil-shale can be distinguished form oil and coal derived particles in environmental samples. Concentrations of large black and small glassy spheroidal fly-ash particles in a sediment core from an Estonian lake showed similar trends to oil-shale combustion statistics from Estonian power plants. 27 refs., 6 figs., 2 tabs

  2. Sulphation of oil shale ash under atmospheric and pressurized combustion conditions

    International Nuclear Information System (INIS)

    Kuelaots, I.; Yrjas, P.; Hupa, M.; Ots, A.

    1995-01-01

    One of the main problems in conventional combustion boilers firing pulverized oil shale is the corrosion and fouling of heating surfaces, which is caused by sulphur compounds. Another major problem, from the environmental point of view, are the high SO 2 emissions. Consequently, the amount of sulphur in flue gases must be reduced. One alternative to lower the SO 2 , concentration is the use of new technologies, such as pressurized fluidized bed combustion (PFBC). In FBC processes, the sulphur components are usually removed by the addition of limestone (CaCO 3 ) or dolomite (CaCO 3 x MgCO 3 ) into the bed. The calcium in these absorbents react with SO 2 , producing solid CaSO 4 . However, when burning oil shale, there would be no need to add limestone or dolomite into the bed, due to the initially high limestone content in the fuel (molar ratio Ca/S =10). The capture of sulphur by oil shale ashes has been studied using a pressurized thermogravimetric apparatus (PTGA). The chosen experimental conditions were typical for atmospheric and pressurized fluidized bed combustion. Four different materials were tested - one cyclone ash from an Estonian oil shale boiler, two size fractions of Estonian oil shale and, one fraction of Israeli oil shale. The cyclone ash was found to be the poorest sulphur absorbent. In general, the results from the sulphur capture experiments under both atmospheric and pressurized fluidized bed conditions showed that the oil shale can capture not only its own sulphur but also significant amounts of additional sulphur from another fuel if the fuels are mixed together. (author)

  3. Emission from Estonian oil shale power plants

    International Nuclear Information System (INIS)

    Aunela, L.; Haesaenen, E.; Kinnunen, V.; Larjava, K.; Mehtonen, A.; Salmikangas, T.; Leskelae, J.; Loosaar, J.

    1995-01-01

    Flue gas emissions from pulverized oil shale fired boilers of Estonian and Baltic power plants have been studied. The concentrations of NO x , CO, C x H y , HCI, Hf and polycyclic aromatic hydrocarbons in flue gases have been found to be relatively low and acceptable according to German emission limits, for instance. Desulphurization degree of flue gases by SO 2 absorption with ash has been found to vary defending on boiler type and operation conditions. In spite of significant sulphur capture (average values for different boilers in the range between 68 and 77 % of the initial sulphur content of the fuel), SO 2 concentrations in flue gases remain still very high (up to 2600 mg/m 3 , 10% O 2 ). Very high concentrations of particles, especially at Estonian Power Plant (up o 6250 mg/m 3 , 10 % 0 2 ) have been detected. Heavy metal emissions were too high by the reason of particle control insufficiency as well. Yearly emission estimates of this study support the former Estonian ones within the range of 10-15 %. (author)

  4. Trace metal emissions from the Estonian oil shale fired power

    DEFF Research Database (Denmark)

    Aunela-Tapola, Leena A.; Frandsen, Flemming; Häsänen, Erkki K.

    1998-01-01

    Emission levels of selected trace metals from the Estonian oil shale fired power plant were studied. The plant is the largest single power plant in Estonia with an electricity production capacity of 1170 MWe (1995). Trace metals were sampled from the flue gases by a manual method incorporating...... in the flue gases of the studied oil shale plant contribute, however, to clearly higher total trace metal emission levels compared to modern coal fired power plants. Although the old electrostatic precipitators in the plant have been partly replaced by state-of-the-art electrostatic precipitators...... a two-fraction particle sampling and subsequent absorption of the gaseous fraction. The analyses were principally performed with ICP-MS techniques. The trace metal contents of Estonian oil shale were found to be in the same order of magnitude as of coal on average. The high total particle concentrations...

  5. Economic modelling of the capture-transport-sink scenario of industrial CO2 emissions: The Estonian-Latvian cross-border case study

    NARCIS (Netherlands)

    Shogenova, A.; Shogenov, K.; Pomeranceva, R.; Nulle, I.; Neele, F.; Hendriks, C.

    2011-01-01

    Industrial CO2 emissions and opportunities for CO2 geological storage in the Baltic Region were studied within the EU GeoCapacity project supported by the European Union Framework Programme 6. Estonia produces the largest amounts of CO2 emissions in the region, due to the combustion of Estonian oil

  6. Shale oil combustion

    International Nuclear Information System (INIS)

    Al-dabbas, M.A.

    1992-05-01

    A 'coutant' carbon steel combustion chamber cooled by water jacket was conslructed to burn diesel fuel and mixlure of shale oil and diesel fuels. During experimental work nir fuel ratio was determined, temperaturces were measured using Chromel/ Almel thermocouple, finally the gasous combustion product analysis was carricd out using gas chromatograph technique. The constructed combustion chamber was operating salisfactory for several hours of continous work. According to the measurements it was found that: the flame temperature of a mixture of diesel and shale oil fuels was greater than the flame temperature of diesel fuel. and the sulfer emissious of a mixture of diesel and shale oil fuels was higher than that of diesel fuel. Calculation indicated that the dry gas energy loss was very high and the incomplete combustion energy loss very small. (author). 23 refs., 35 figs

  7. Shale oil combustion

    Energy Technology Data Exchange (ETDEWEB)

    Al-dabbas, M A

    1992-05-01

    A `coutant` carbon steel combustion chamber cooled by water jacket was conslructed to burn diesel fuel and mixlure of shale oil and diesel fuels. During experimental work nir fuel ratio was determined, temperaturces were measured using Chromel/ Almel thermocouple, finally the gasous combustion product analysis was carricd out using gas chromatograph technique. The constructed combustion chamber was operating salisfactory for several hours of continous work. According to the measurements it was found that: the flame temperature of a mixture of diesel and shale oil fuels was greater than the flame temperature of diesel fuel. and the sulfer emissious of a mixture of diesel and shale oil fuels was higher than that of diesel fuel. Calculation indicated that the dry gas energy loss was very high and the incomplete combustion energy loss very small. (author). 23 refs., 35 figs.

  8. Combustion: an oil spill mitigation tool

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-11-01

    The technical feasibility of using combustion as an oil spill mitigation tool was studied. Part I of the two-part report is a practical guide oriented toward the needs of potential users, while Part II is the research or resource document from which the practical guidance was drawn. The study included theoretical evaluations of combustion of petroleum pool fires under the effects of weathering and an oil classification system related to combustion potential. The theoretical analysis of combustion is balanced by practical experience of oil burning and case history information. Decision elements are provided which can be used as a guide for technical evaluations of a particular oil spill situation. The rationale for assessing technical feasibility is given in the context of other alternatives available for response to an oil spill. A series of research and technology development concepts are included for future research. The ethics of using oil burning are discussed as issues, concerns, and tradeoffs. A detailed annotated bibliography is appended along with a capsule review of a decade of oil burning studies and other support information.

  9. Determination of Heating Value of Estonian Oil Shale by Laser-Induced Breakdown Spectroscopy

    Directory of Open Access Journals (Sweden)

    M. Aints

    2018-01-01

    Full Text Available The laser-induced breakdown spectroscopy (LIBS combined with multivariate regression analysis of measured data were utilised for determination of the heating value and the chemical composition of pellets made from Estonian oil shale samples with different heating values. The study is the first where the oil shale heating value is determined on the basis of LIBS spectra. The method for selecting the optimal number of spectral lines for ordinary multivariate least squares regression model is presented. The correlation coefficient between the heating value predicted by the regression model, and that measured by calorimetric bomb, was R2=0.98. The standard deviation of prediction was 0.24 MJ/kg. Concentrations of oil shale components predicted by the regression model were compared with those measured by ordinary methods.

  10. Experimental investigation of flash pyrolysis oil droplet combustion

    DEFF Research Database (Denmark)

    Ibrahim, Norazana; Jensen, Peter A.; Dam-Johansen, Kim

    2013-01-01

    at a temperature ranging between 1000 and 1400°C with an initial gas velocity of 1.6 m/s and oxygen concentration of 3%. The evolution of combustion of bio-oil droplets was recorded by a digital video camera. It was observed that the combustion behaviour of pyrolysis oil droplet differ from the heavy oil in terms......The aim of this work is to investigate and compare the combustion behaviour of a single droplet of pyrolysis oil derived from wheat straw and heavy fossil oil in a single droplet combustion chamber. The initial oil droplet diameters were in between 500 μm to 2500 μm. The experiments were performed...

  11. Overview of the Estonian Biofuels Association activities

    International Nuclear Information System (INIS)

    Hueues, Meelis

    2000-01-01

    Due to global warming and environment pollution because of widespread use of fossil fuels there are already tendencies to stabilize and decrease the consumption of these energy resources and take into use more renewable energy resources. Estonian Biofuels Association (EBA) is a non-profit association, which was founded on 8. of May 1998 in Tallinn. The EBA is an independent and voluntary alliance of its members. Fields of activity of the EBA are by biofuels research, developing and evaluation to engage environmental, biofuels and energy saving. EBA members are: energy consultants, scientists, as well as fuel suppliers, DH-companies, technology suppliers, energy service companies etc. The members of EBA are involved in different projects in Estonia, where biomass are produced and used for heating, where wood, waste, peat, rape oil and biogas resources are examined and put into use, and also projects which deal with energy saving and environment friendly equipment production for using biofuels. During our short experience we have noticed that people in Estonia have become more aware of biomass and their use, so the development of environment friendly and sustainable energetics will continue in Estonia. Available biofuels in Estonia could compete with fossil fuels if burnt rationally with high technology equipment. EBA members are convinced that biomass have perspective and that they could play an important role in improving Estonian economic and environmental situation. Modem biomass combustion devices are taken into use more the faster general wealth increases and EBA can raise people's awareness of bio fuel subject through special, courses and media. We want Estonian energy policy to develop towards widespread use of renewable energy resources, which would save energy and environment improve nation's foreign trade balance and create jobs mainly in rural areas

  12. A comprehensive review of oil spill combustion studies

    International Nuclear Information System (INIS)

    Walavalkar, A.Y.; Kulkarni, A.K.

    1996-01-01

    The complex process of in-situ burning of oil or a water-in-oil emulsion floating on top of a water-base, such as the ocean, was discussed. The process was examined before, during and after actual combustion. In general, the success of oil spill combustion is measured in terms of the fraction of the spilled oil or emulsion that is burned away. However, the air and aquatic pollution caused by the combustion should also be considered. The physical conditions such as wind velocity, waves and the presence or absence of a containment device, such as a fire boom, could determine the continuation of the combustion process. An overview of the oil spill combustion techniques was provided. There still remains a need for fundamental studies, especially in mathematical modeling, to understand the basic mechanisms and predict the applicability of the in-situ combustion. 74 refs., 7 tabs., 3 figs

  13. Swedish-Estonian energy forest research cooperation

    International Nuclear Information System (INIS)

    Ross, J.; Kirt, E.; Koppel, A.; Kull, K.; Noormets, A.; Roostalu, H.; Ross, V.; Ross, M.

    1996-01-01

    The Organization of Estonian energetic economy is aimed at cutting the usage of oil, gas and coal and increasing the local resources firewood, oil-shale and peat for fuel. The resources of low-valued firewood-brushwood, fallen deadwood etc. are available during the following 10-15 years, but in the future the cultivation of energy forest (willow) plantations will be actual. During the last 20 years the Swedish scientists have been extensively studying the willow forest selection, cultivation and use in energetics and waste water purification systems. A Swedish-Estonian energy forest research project was started in 1993 between the Swedish Agricultural University on one hand and Toravere Observatory, Institute of Zoology and Botany, Estonian Academy of Sciences and Estonian Potato Processing Association on the other hand. In spring 5 willow plantations were established with the help of Swedish colleagues and obtained from Sweden 36000 willow cuttings. The aim of the project: a) To study experimentally and by means of mathematical modelling the biogeophysical aspects of growth and productivity of willow plantations in Sweden and Estonian climatological conditions. b) To study the possibility of using the willow plantations in waste waters purification. c) To study the economical efficiency of energy forest as an energy resource under the economic and environmental conditions of Estonia. d) To study the economic efficiency of willow plantations as a raw material for the basket industry in Estonia. e) To select the most productive and least vulnerable willow clones for practical application in energy plantations. During 1993 in all five plantations detailed analysis of soil properties has been carried out. In the plantation at Toravere Observatory phytometrical measurements were carried out - the growth of plant biomass leaf and stem area, vertical distribution of dry matter content, biomass and phyto area separately for leaves and stems has been performed. Some

  14. Estonian white paper on energy

    International Nuclear Information System (INIS)

    Hamburg, Arvi

    1997-01-01

    Energy policy, environmental protection and economy form a triangle of tightly linked sectors, and any solution of some energy problem can be solved only in the light of all the above mentioned factors. There are several energy master plans for Estonia, the first of them dating back to the years of the Soviet Union and ending the list with the plan to cover the years up to 2000. By now the basic principles of the Estonian energy policy have been prepared and Estonian Energy Concept is being worked out. The main goal of Estonian energy policy is ensure an effective and environmentally benign energy supply for the country. It means safety in energy supply, effective production and supply together with sufficient environmental protection. Energy Council in the role of an advisory voluntary organization for inspection of the energy system and finding measures to improve its efficiency is established with parliament members included. The Estonian Energy Research Institute and the Oil--Shale Research Institute serve as a scientific advisory board for the government in energy policy. It's important to emphasise that privatisation is no panacea, solving all the problems, and therefore we are facing hard to move in the right direction, satisfying all the consumers of energy

  15. Review of fuel oil quality and combustion of fast pyrolysis bio-oils from lignocellulosic biomass

    International Nuclear Information System (INIS)

    Lehto, Jani; Oasmaa, Anja; Solantausta, Yrjö; Kytö, Matti; Chiaramonti, David

    2014-01-01

    Highlights: • Review of state-of-the-art fast pyrolysis oil combustion in burner applications. • Fast pyrolysis oil has been found to be suitable for industrial scale utilization. • Curves for NO x -emissions for air-assisted atomization burners are presented. • Quality control, combined with standards and specifications is recommended. - Abstract: Fast pyrolysis bio-oils are completely different from petroleum fuels and other bio-fuels available in the market, as regards both to their physical properties and chemical composition. When the unusual properties of these bio-oils are carefully taken into account in system and burner design, their combustion without a pilot flame or support fuel is possible on an industrial scale. The aim of the paper is to review the work done on combustion of fast pyrolysis bio-oils and highlight the latest and most important findings of its combustion from laboratory fundamentals to industrial scale. The main focus of the paper is on the bio-oil burner applications. In recent industrial scale bio-oil combustion tests, bio-oil has been found to be technically suitable for replacing heavy fuel oil in district heating. In addition, it has also been found out that limited possibilities for further lowering particulate emissions exist, since the majority of the particulates are typically incombustible matter. Curves for NO x -emissions of fast pyrolysis bio-oil combustion for air-assisted atomization burners are presented in the paper. Current burner designs are quite sensitive to the changes in the quality of the bio-oil, which may cause problems in ignition, flame detection and flame stabilization. Therefore, in order to be able to create reliable bio-oil combustion systems that operate at high efficiency, bio-oil grades should be standardized for combustion applications. Careful quality control, combined with standards and specifications, all the way from feedstock harvesting through production to end-use is recommended in

  16. Laboratory weathering of combusted oil shale

    International Nuclear Information System (INIS)

    Essington, M.E.

    1991-01-01

    The objective of this study was to examine the mineralogy and leachate chemistry of three combusted oil shales (two Green River Formation and one New Albany) in a laboratory weathering environment using the humidity cell technique. The mineralogy of the combusted western oil shales (Green River Formation) is process dependent. In general, processing resulted in the formation of anhydrite, lime, periclase, and hematite. During the initial stages of weathering, lime, periclase, and hematite. During the initial stages of weathering, lime, periclase, and anhydrite dissolve and ettringite precipitates. The initial leachates are highly alkaline, saline, and dominated by Na, hydroxide, and SO 4 . As weathering continues, ettringite precipitates. The initial leachates are highly alkaline, saline, and dominated by Na, hydroxide, and SO 4 . As weathering continues, ettringite dissolves, gypsum and calcite precipitate, and the leachates are dominated by Mg, SO 4 , and CO 3 . Leachate pH is rapidly reduced to between 8.5 and 9 with leaching. The combusted eastern oil shale (New Albany) is composed of quartz, illite, hematite, and orthoclase. Weathering results in the precipitation of gypsum. The combusted eastern oil shale did not display a potential to produce acid drainage. Leachate chemistry was dominated by Ca and SO 4 . Element concentrations continually decreased with weathering. IN a western disposal environment receiving minimal atmospheric precipitation, spent oil shale will remain in the initial stages of weathering, and highly alkaline and saline conditions will dominate leachate chemistry. In an eastern disposal environment, soluble salts will be rapidly removed from the spent oil shale to potentially affect the surrounding environment

  17. Chemical composition of anthropogenic particles on needles collected close to the Estonian oil-shale power plants

    International Nuclear Information System (INIS)

    Meinander, O.

    1995-01-01

    Within the countries surrounding the Baltic Sea, north-eastern Estonia is among the most polluted areas. Emissions from the oil-shale power plants produce air pollution problems both locally and on a larger scale. In the atmosphere, pollutants mix and convert. Consequently, the particles deposited due to the use of oil-shale can have various chemical compositions. From the point of view of air chemistry, ecological effects and air pollution modelling, knowledge of the chemical composition of the deposited particles can be of great value. The aim of this work was to study the chemical composition of single anthropogenic particles occurring on needle surfaces in north-eastern Estonia and Southern Finland close to the Estonian oil-shale power plants. For the purpose, scanning electron microscopical microanalysis was used

  18. Combustion of Jordanian oil shale using circulating fluidized bed

    International Nuclear Information System (INIS)

    Hamdan, M.; Al-Azzam, S.

    1998-11-01

    this study re[resents design and manufacturing of a lab-scale circulating fluidized bed (C.F.B) to burn low grade fuel such as Jordanian oil shale. Hydrodynamic properties of C.F.B. were studied like minimum fluidization velocity, circulation flux and carryover rate. a hot run was firstly conducted by the combustion of L.P.G. to start up the combustion process. It proceeds until reaching the minimum burning temperature of oil shale particles, at which time the LPG supply was gradually reduced and oil shale feeding started. soon after reaching a self sustainable condition of oil shale particles, the LPG supply was cut off. The main combustion variables were investigated such as air to fuel ratios, temperature profiles across the bed, exhaust gas analysis and combustion efficiency. a combustion intensity of 859 kg/hr.m 2 and combustion efficiency of 96% were achieved. (authors). 19 refs., 9 tab., 18 fig

  19. Is Estonian oil shale beneficial in the future?

    International Nuclear Information System (INIS)

    Reinsalu, Enno

    1998-01-01

    Oil shale mining production reached its maximum level of 31.35·10 6 tonnes per year in 1980. After the eighties there was a steady decline in mining. The first scientific prognoses of the inescapable decrease in oil shale mining were published in 1988. According to this, the Estonian oil shale industry would vanish in the third decade of the next century. From the beginning of the nineties, the consumption and export of electricity have dropped in Estonia. The minimum level of oil shale mining was 13.5·10 6 tonnes per year. This occurred in 1994/1995. Some increase in consumption of electric power and oil shale began at the end of 1995. Oil shale processing began to increase gradually in 1993. Oil shale is the most important fuel in Estonia today. In 1997, oil shale provided 76% of Estonia's primary energy supply and accounted for 57% of its economic value. Oil shale is the cheapest fuel in Estonia. Nowadays, oil shale provides an essential part of the fuel supply in Estonia because it is considerably cheaper than other fuels. Oil shale costs EEK 12.16 per G J. At the same time, coal costs EEK 23.41 per G J and peat costs EEK 14.80 per G J (year 1997). There are three important customers of oil shale: the electric power company Eesti Energia, the oil processing company Kiviter and the factory Kunda Nordic Cement. In 1995, the power company utilised 81% of the oil shale mass and 77% of its heating value. The state energy policy inhibits increases in the oil shale price even though the mining infrastructure is decaying. Government price policies subside oil shale processing. The energy of oil shale processing is 1.9 times cheaper than the heating value of raw oil shale for power stations. It could be considered as a state subsidisation of oil and cement export at the expense of electricity. The subsidy assigned to oil processing was of EEK 124·10 6 and to the cement industry of EEK 8.4·10 6 in year 1997 (based on heating value). State regulation of prices and

  20. Thermogravimetric investigation on the degradation properties and combustion performance of bio-oils.

    Science.gov (United States)

    Ren, Xueyong; Meng, Jiajia; Moore, Andrew M; Chang, Jianmin; Gou, Jinsheng; Park, Sunkyu

    2014-01-01

    The degradation properties and combustion performance of raw bio-oil, aged bio-oil, and bio-oil from torrefied wood were investigated through thermogravimetric analysis. A three-stage process was observed for the degradation of bio-oils, including devolatilization of the aqueous fraction and light compounds, transition of the heavy faction to solid, and combustion of carbonaceous residues. Pyrolysis kinetics parameters were calculated via the reaction order model and 3D-diffusion model, and combustion indexes were used to qualitatively evaluate the thermal profiles of tested bio-oils for comparison with commercial oils such as fuel oils. It was found that aged bio-oil was more thermally instable and produced more combustion-detrimental carbonaceous solid. Raw bio-oil and bio-oil from torrefied wood had comparable combustion performance to fuel oils. It was considered that bio-oil has a potential to be mixed with or totally replace the fuel oils in boilers. Copyright © 2013 Elsevier Ltd. All rights reserved.

  1. Estonian literature / Janika Kronberg

    Index Scriptorium Estoniae

    Kronberg, Janika, 1963-

    2003-01-01

    Sisu: Estonian literature - born on the margins of Europe ; Baltic German literature and its impact ; Seeking the contours of a 'truly' Estonian literature ; Literature and an independent Estonia ; Estonian literature in two cultural spheres ; The fifties and sixties ; Literature and congealed time ; A bold new Estonian literature

  2. Increase oil recovery of heavy oil in combustion tube using a new catalyst based nickel ionic solution

    Energy Technology Data Exchange (ETDEWEB)

    Ramirez-Garnica, M.A.; Hernandez-Perez, J.R.; Cabrera-Reves, M.C.; Schacht-Hernandez, P. [Inst. Mexicano del Petroleo, Mexico City (Mexico); Mamora, D.D. [Society of Petroleum Engineers, Richardson, TX (United States)]|[Texas A and M Univ., College Station, TX (United States)

    2008-10-15

    An ionic liquid-based nickel catalyst was used in conjunction with a combustion tube as an in situ process for heavy oil. The experimental system was comprised of a fluid injection system; a combustion tube; a fluid production system; a gas chromatograph; and a data recording system. Injected nitrogen and air was controlled by a mass flow controller. Nitrogen was used to pressurize the combustion tube and flush the system. Air was injected at a rate of 3 L per minute throughout the combustion run. Liquids leaving the combustion tube passed through a 2-stage separation process. Gases passing through the condenser were kept at low temperatures. Fractions of produced gas were analyzed by the chromatograph. Data loggers were used to obtain data at 30 second intervals. Two combustion experiments were conducted to obtain production times, temperature profiles, and the quality of the oil produced by the catalyst. Combustion tests were conducted with and without the catalyst. An analysis of the experimental data showed that use of the nickel catalyst resulted in increases in oil production as well as higher combustion efficiencies. Use of the catalyst also resulted in a faster combustion front and accelerated oil production. It was concluded that the produced oil contained fewer impurities than oil produced during the control experiment. 23 refs., 3 tabs., 9 figs.

  3. Combustion characteristics of crude jatropha oil droplets using rhodium liquid as a homogeneous combustion catalyst

    Science.gov (United States)

    Nanlohy, Hendry Y.; Wardana, I. N. G.; Hamidi, N.; Yuliati, L.

    2018-01-01

    Combustion characteristics of crude jatropha oil droplet at room temperature with and without catalyst have been studied experimentally. Its combustion characteristics have been observed by igniting the oil droplet on a junction of a thermocouple, and the combustion characteristics of oil droplets are observed using a high-speed camera. The results show that the uniqueness of crude jatropha oil as alternative fuel is evidenced by the different stages of combustion caused by thermal cracking in burning droplets. The results also show that the role of the catalyst is not only an accelerator agent, but there are other unique functions and roles as a stabilizer. Moreover, the results also found that the catalyst was able to shorten the ignition timing and burnout time. This phenomenon proves that the presence of catalysts alters and weakens the structure of the triglyceride geometry so that the viscosity and flash point is reduced, the fuel absorbs heat well and flammable.

  4. Chemistry of the Estonian oil-shale kukersite

    Energy Technology Data Exchange (ETDEWEB)

    Kogerman, P N

    1931-01-01

    Estonian oil shale is one of the oldest and richest oil shales in the world. The deposits occur in the Middle-Ordovician strata having a total thickness of 2.2 meters. The ultimate composition of the kerogen varied within the following limits: carbon 76.5 to 76.7 percent, hydrogen 9.1 to 9.2 percent, nitrogen 0.2 to 0.4 percent, sulfur 1.6 to 2.2 percent, chlorine 0.5 to 0.7 percent, and oxygen (by difference) 11.2 to 12.2 percent. The composition of kukersite kerogen corresponds nearly to the empirical formula (C/sub 8/H/sub 11/O)n. One of the most significant differences between kukersite, coal, and lignite is the amount of alkali-soluble substances present. Kukersite has almost no humic acids. Samples of kukersite were brominated and chlorinated. The halogenated shales showed a solubility in absolute alcohol of 26 percent compared to only 0.31 percent for untreated shale. Enriched shale (4.5 percent ash) did not react with chlorine as much as did raw shale. Apparently the mineral matter acted catalytically during chlorination. The amount of soluble extract obtained by solvent treatment of kukersite ranged from 0.22 percent with chloroform to 2.20 percent with tetrachloroethane. Heat was the most effective agent for the depolymerization of kukersite kerogen. The percentage loss of weight due to drying in air was much less than in the presence of carbon dioxide. The results indicated that on drying in air, the powdered shale loses water and a volatile substance, probably the oxides of carbon, up to 80/sup 0/C. Carbon dioxide was also found to be present in the gases eliminated at the temperature of initial decomposition. Pulverized shale, heated for 6 hours at 220/sup 0/C, lost 2.6 percent of its weight; its solubility in carbon disulfide was 2.11 percent. Kukersite kerogen was formed from compounds that were resistent to bacteriological decomposition, such as waxes and resins, plus decomposition products of proteins, cellulose, and putrefaction products of

  5. Combustion of soybean oil and diesel mixtures for heating purposes

    Energy Technology Data Exchange (ETDEWEB)

    Guimaraes, Adriana Correa; Sanz, Jose Francisco [European University Miguel de Cervantes, Valladolid (Spain)], E-mail: acorrea@uemc.es; Hernandez, Salvador; Navas, Luis Manuel; Rodriguez, Elena; Ruiz, Gonzalo [University of Valladolid (Spain). Dept. of Agricultural and Forest Engineering; San Jose, Julio [University of Valladolid (Spain). Dept. of Energetic Engineering; Gomez, Jaime [University of Valladolid (Spain). Dept. of Communications and Signal Theory and Telematics Engineering

    2008-07-01

    Using blends of vegetable oils with petroleum derivates for heating purposes has several advantages over other energy application for vegetable oils. This paper presents the results of an investigation by use of soybean oil and diesel mixture as fuel for producing heat in conventional diesel installation. The paper is set out as follows: properties characterization of soybean oil as fuel and of diesel oil, as well as the mixture of both; selection of the mixture according to their physical chemical properties and how they adapt to conventional combustion installation; experimentation with the selected mixture, allowing the main combustion parameters to be measured; processing the collected data, values of combustion, efficiency and reduction of emissions. Conclusions show that the use of soybean oil and diesel mixture for producing heat energy in conventional equipment is feasible and beneficial for reduction emissions. (author)

  6. Diesel oil combustion in fluidized bed; Combustion de aceite diesel en lecho fluidizado

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez Cazares, Mario [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1992-07-01

    The effect of the fluidized bed depth in the combustion in burning diesel oil in a fluidized bed, was analyzed. A self sustained combustion was achieved injecting the oil with an injector that utilized a principle similar to an automobile carburetor venturi. Three different depths were studied and it was found that the deeper the bed, the greater the combustion efficiency. Combustion efficiencies were attained from 82% for a 100mm bed depth, up to 96% for a 200mm bed depth. The diminution in the efficiency was mainly attributed to unburned hydrocarbons and to the carbon carried over, which was observed in the black smoke at the stack outlet. Other phenomena registered were the temperature gradient between the lower part of the bed and the upper part, caused by the fluidization velocity; additionally it was observed that the air employed for the oil injection (carbureting air) is the most important parameter to attain a complete combustion. [Espanol] Se analizo el efecto de la profundidad del lecho en la combustion al quemar aceite diesel en un lecho fluidizado experimental. Se logro combustion autosostenida inyectando el aceite con un inyector que utilizo un principio similar al venturi del carburador de automovil. Se estudiaron tres diferentes profundidades del lecho y se encontro que a mayor profundidad del lecho, mayor eficiencia de la combustion. Se lograron eficiencias de la combustion desde 82% para el lecho de 100 mm de profundidad hasta 96% para el de 200 mm. La disminucion de la eficiencia se atribuyo, principalmente, a los hidrocarburos no quemados y al carbon arrastrado, lo cual se observo en el humo negro a la salida de la chimenea. Otros fenomenos registrados fueron el gradiente de temperatura entre la parte baja del lecho y la parte superior causado por la velocidad de fluidizacion; ademas, se observo que el aire utilizado para inyectar el aceite (aire de carburacion) es el parametro mas importante para lograr una combustion completa.

  7. Numerical Simulation of In Situ Combustion of Oil Shale

    Directory of Open Access Journals (Sweden)

    Huan Zheng

    2017-01-01

    Full Text Available This paper analyzes the process of in situ combustion of oil shale, taking into account the transport and chemical reaction of various components in porous reservoirs. The physical model is presented, including the mass and energy conservation equations and Darcy’s law. The oxidation reactions of oil shale combustion are expressed by adding source terms in the conservation equations. The reaction rate of oxidation satisfies the Arrhenius law. A numerical method is established for calculating in situ combustion, which is simulated numerically, and the results are compared with the available experiment. The profiles of temperature and volume fraction of a few components are presented. The temperature contours show the temperature variation in the combustion tube. It is found that as combustion reaction occurs in the tube, the concentration of oxygen decreases rapidly, while the concentration of carbon dioxide and carbon monoxide increases contrarily. Besides, the combustion front velocity is consistent with the experimental value. Effects of gas injection rate, permeability of the reservoir, initial oil content, and injected oxygen content on the ISC process were investigated in this study. Varying gas injection rate and oxygen content is important in the field test of ISC.

  8. Decrease of noxious emissions in the residual fuel oil combustion; Disminucion de emisiones nocivas en la combustion de aceite combustible residual

    Energy Technology Data Exchange (ETDEWEB)

    Mandoki W, Jorge [Econergia S. de R. L. de C. V. Mexico, D. F. (Mexico)

    1994-12-31

    The residual fuel oil combustion emits noxious substances such as carbonaceous particulate, nitrogen oxides, and sulfur trioxide at unacceptable levels. Water emulsified in the fuel substantially reduces such emissions, achieving besides, in most of the cases, a net saving in the fuel consumption. The beneficial effects are shown in burning the residual fuel oil as a water emulsion, as well as the method to produce an adequate emulsion. The emulsified fuel technology offers a low cost option to reduce air pollution. The fuel oil quality has been declining during the last decades due to: 1. Increase in the production of crude heavy oils, generally with higher content of asphaltens and sulfur. 2. Less availability of vacuum distillation residues due to its conversion into greater value products. 3. More intensive conversion processes such as catalytic cracking, visbreaking, etc. that increase the asphaltenes concentration in the bottoms, causing instability problems. 4. The increase in the vanadium and other metals content as the concentration of asphaltenes increases. The use of emulsified fuel oil provides an efficient and economical method to substantially reduce the noxious emissions to the atmosphere. The emulsion contains water particles in a diameter between 2 and 20 microns, uniformly distributed in the fuel oil, generally in a proportion generally of 5 to 10%; besides, it contains a tensioactive agent to assure a stable emulsion capable of withstanding the shearing forces of the pumping and distribution systems. When the atomized oil drops get into the combustion chamber, the emulsified water flashes into high pressure steam, originating a violent secondary atomization. The effect of this secondary atomization is the rupture of the oil drops of various hundred microns, producing drops of 5 to 15 microns in diameter. Since the necessary time for combustion is an exponential function of the drop diameter, a very substantial improvement in the combustion is

  9. Combustion Characterization of Individual Bio-oil Droplets

    DEFF Research Database (Denmark)

    Hansen, Brian Brun; Jensen, Peter Arendt

    2015-01-01

    Single droplet combustion characteristics has been investigated for bio-oil slurries, containing biomass residue, and compared to conventional fuels for pulverized burners, such as fuel oil (start up) and wood chips (solid biomass fuel). The investigated fuels ignition delays and pyrolysis behavior...

  10. Combustion performance evaluation of air staging of palm oil blends.

    Science.gov (United States)

    Mohd Jaafar, Mohammad Nazri; Eldrainy, Yehia A; Mat Ali, Muhammad Faiser; Wan Omar, W Z; Mohd Hizam, Mohd Faizi Arif

    2012-02-21

    The problems of global warming and the unstable price of petroleum oils have led to a race to develop environmentally friendly biofuels, such as palm oil or ethanol derived from corn and sugar cane. Biofuels are a potential replacement for fossil fuel, since they are renewable and environmentally friendly. This paper evaluates the combustion performance and emission characteristics of Refined, Bleached, and Deodorized Palm Oil (RBDPO)/diesel blends B5, B10, B15, B20, and B25 by volume, using an industrial oil burner with and without secondary air. Wall temperature profiles along the combustion chamber axis were measured using a series of thermocouples fitted axially on the combustion chamber wall, and emissions released were measured using a gas analyzer. The results show that RBDPO blend B25 produced the maximum emission reduction of 56.9% of CO, 74.7% of NOx, 68.5% of SO(2), and 77.5% of UHC compared to petroleum diesel, while air staging (secondary air) in most cases reduces the emissions further. However, increasing concentrations of RBDPO in the blends also reduced the energy released from the combustion. The maximum wall temperature reduction was 62.7% for B25 at the exit of the combustion chamber.

  11. Physical and combustion characterization of pyrolytic oils derived from biomass material upgraded by catalytic hydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Vitolo, S.; Ghetti, P. (Universita di Pisa, Pisa (Italy). Dipartimento di Ingegneria Chimica)

    1994-11-01

    Physical and combustion properties of a pyrolytic bio-oil are determined both as-obtained and after catalytic hydrodeoxygenation. The tests demonstrate that the hydrogenation treatment improves the oil as regards combustibility, viscosity and acidity. Combustion properties of the oil have been characterized by evaporation and temperature programmed combustion profiles. Short communication. 21 refs., 4 figs., 2 tabs.

  12. Combustion performance of pyrolysis oil/ethanol blends in a residential-scale oil-fired boiler

    Science.gov (United States)

    A 40 kWth oil-fired commercial boiler was fueled with blends of biomass pyrolysis oil (py-oil) and ethanol to determine the feasibility of using these blends as a replacement for fuel oil in home heating applications. An optimal set of test parameters was determined for the combustion of these blend...

  13. Premixed combustion of coconut oil in a hele-shaw cell

    Directory of Open Access Journals (Sweden)

    Hadi Saroso

    2014-12-01

    Full Text Available Coconut oil combustion characteristic is observed experimentally by evaporating oil in the boiler then mix it with air before being burned at various equivalence ratios in the Hele-shaw cell. The result shows that, coconut oil tends to break into glycerol and fatty acid due to hydrolysis reaction producing the flame propagation, where the fatty acid flame propagates first then glycerol flame. Micro-explosion occurs when moisture from fatty acid combustion is absorbed by glycerol and higher heating due to higher flame speed produces more micro-explosion.

  14. Feasibility study of the in-situ combustion in shallow, thin, and multi-layered heavy oil reservoir

    Energy Technology Data Exchange (ETDEWEB)

    Zhong, L. [Society of Petroleum Engineers, Kuala Lumpur (Malaysia)]|[Daqing Petroleum Inst., Beijing (China); Yu, D. [Daqing Petroleum Inst., Beijing (China); Gong, Y. [China National Petroleum Corp., Beijing (China). Liaohe Oilfield; Wang, P.; Zhang, L. [China National Petroleum Corp., Beijing (China). Huabei Oilfield; Liu, C. [China National Petroleum Corp., Beijing (China). JiLin Oilfield

    2008-10-15

    In situ combustion is a process where oxygen is injected into oil reservoirs in order to oxidize the heavier components of crude oil. The oil is driven towards the production wells by the combustion gases and steam generated by the combustion processes. This paper investigated dry and wet forward in situ combustion processes designed for an oil reservoir with thin sand layers. Laboratory and numerical simulations were conducted to demonstrate the feasibility of the processes in a shallow, thin, heterogenous heavy oil reservoir in China. Combustion tube experiments were conducted in order to determine fuel consumption rates. A numerical geological model was constructed to represent the reservoir conditions. Gas, water, oil and solid phases were modelled. Four processes were considered: cracking; pyrolysis of heavy fractions; the combustion of light and heavy fractions; and the combustion of coke. Oil recovery rates were calculated for a period of 10 years. Reactor experiments were conducted to investigate igniting temperatures and air injection rates using an apparatus comprised of an electric heater, oil sand pack tube and a computerized control system. Experiments were performed at different temperature and injection rates. The experiments demonstrated that ignition times and air volumes decreased when air temperature was increased. Results of the study showed that a 20 per cent increase in oil recovery using the in situ combustion processes. It was concluded that adequate air injection rates are needed to ensure effective combustion front movement. 4 refs., 6 tabs., 4 figs.

  15. Characterisation of fuels for advanced pressurised combustion

    Energy Technology Data Exchange (ETDEWEB)

    Zevenhoven, R; Hupa, M; Backman, P; Forssen, M; Karlsson, M; Kullberg, M; Sorvari, V; Uusikartano, T [Aabo Akademi, Turku (Finland). Combustion Chemistry Research Group; Nurk, M [Tallinskij Politekhnicheskij Inst., Tallinn (Estonia)

    1997-10-01

    The objective of the research was to determine a set of fuel characteristics which quantify the behaviour of a fuel in a typical pressurised combustor or gasifier environment, especially in hybrid processes such as second generation PFBC. One specific aspect was to cover a wide range of fuels, including several coal types and several grades of peat and biomasses: 7 types of coal, 2 types of peat, 2 types of wood, 2 types of black liquor, Estonian oil shale and Venezuelan Orimulsion were studied. The laboratory facilities used are a pressurised thermogravimetric reactor (PTGR), a pressurised grid heater (PGH) and an atmospheric entrained flow quartz tube reactor, with gas analysis, which can be operated as a fixed bed reactor. A major part of the work was related to fuel devolatilisation in the PGH and sequential devolatilisation and char gasification (with carbon dioxide or steam) in the PTGR. The final part of that work is reported here, with the combustion of Estonian oil shale at AFBC or PFBC conditions as additional subject. Devolatilisation of the fuels at atmospheric pressure in nitrogen while monitoring gaseous exhausts, followed by ultimate analysis of the chars has been reported earlier. Here, results on the analysis of the reduction of NO (with and without CO) on chars at atmospheric pressure in a fixed bed reactor are reported. Finally, a comparison is given between experimental results and direct numerical simulation with several computer codes, i.e. PyroSim, developed at TU Graz, Austria, and the codes Partikkeli, Pisara and Cogas, which were provided by VTT Energy, Jyvaeskylae

  16. Pyrolysis oil combustion in a horizontal box furnace with an externally mixed nozzle

    Science.gov (United States)

    Combustion characteristics of neat biomass fast-pyrolysis oil were studied in a horizontal combustion chamber with a rectangular cross-section. An air-assisted externally mixed nozzle known to successfully atomize heavy fuel oils was installed in a modified nominal 100 kW (350,000 BTU/h nominal cap...

  17. THE INFLUENCE OF CARBON BURNOUT ON SUBMICRON PARTICLE FORMATION FROM EMULSIFIED FUEL OIL COMBUSTION

    Science.gov (United States)

    The paper gives results of an examination of particle behavior and particle size distributions from the combustion of different fuel oils and emulsified fuels in three experimental combusators. Results indicate that improved carbon (C) burnout from fule oil combustion, either by...

  18. Valued Estonian Music CDs

    Index Scriptorium Estoniae

    2004-01-01

    2002. aastal välja antud eesti muusika heliplaatidest Artur Kapp "Symphonische Werke", Eduard Tubin "Symphonies No.9, No.10 and No.11", "Estonian Preludes", "Eesti heliloojad. Hortus Musicus", "Eesti Muusika Päevad", "Tallinn Saxophone Quartet. Estonian Contemporary Music", "Triskele. Kolga-Jaani vaimulikud rahvalaulud", "Helmekaala. Linnupuu Anne", "Modern Fox mängib Raimond Valgret",

  19. Empirically Estimated Heats of Combustion of Oxygenated Hydrocarbon Bio-type Oils

    Directory of Open Access Journals (Sweden)

    Dmitry A. Ponomarev

    2015-04-01

    Full Text Available An empirical method is proposed by which the heats of combustion of oxygenated hydrocarbon oils, typically found from wood pyrolysis, may be calculated additively from empirically predicted heats of combustion of individual compounds. The predicted values are in turn based on four types of energetically inequivalent carbon and four types of energetically inequivalent hydrogen atomic energy values. A method is also given to estimate the condensation heats of oil mixtures based on the presence of four types of intermolecular forces. Agreement between predicted and experimental values of combustion heats for a typical mixture of known compounds was ± 2% and < 1% for a freshly prepared mixture of known compounds.

  20. On the System of Person-Denoting Signs in Estonian Sign Language: Estonian Name Signs

    Science.gov (United States)

    Paales, Liina

    2010-01-01

    This article discusses Estonian personal name signs. According to study there are four personal name sign categories in Estonian Sign Language: (1) arbitrary name signs; (2) descriptive name signs; (3) initialized-descriptive name signs; (4) loan/borrowed name signs. Mostly there are represented descriptive and borrowed personal name signs among…

  1. [Mati Erelt. Estonian Language] / Katrin Hiietamm

    Index Scriptorium Estoniae

    Hiietamm, Katrin

    2004-01-01

    Arvustus: Estonian language / [Estonian Academy of Sciences] ; edited by Mati Erelt.Tallinn : Teaduste Akadeemia Kirjastus, 2003. 412, [1] lk. : ill., kaart. (Linguistica Uralica. Supplementary series, 0868-4731 ; vol. 1)

  2. Combustive management of oil spills

    International Nuclear Information System (INIS)

    1992-01-01

    Extensive experiments with in situ incineration were performed on a desert site at the University of Arizona with very striking results. The largest incinerator, 6 feet in diameter with a 30 foot chimney, developed combustion temperatures of 3000, F, and attendant soot production approximately 1000 times less than that produced by conventional in situ burning. This soot production, in fact, is approximately 30 times less than current allowable EPA standards for incinerators and internal combustion engines. Furthermore, as a consequence of the high temperature combustion, the bum rate was established at a very high 3400 gallons per hour for this particular 6 foot diameter structure. The rudimentary design studies we have carried out relative to a seagoing 8 foot diameter incinerator have predicted that a continuous burn rate of 7000 gallons per hour is realistic. This structure was taken as a basis for operational design because it is compatible with C130 flyability, and will be inexpensive enough ($120,000 per copy) to be stored at those seaside depots throughout the US coast line in which the requisite ancillary equipments (booms, service tugs, etc.) are already deployed. The LOX experiments verified our expectations with respect to combustion of debris and various highly weathered or emulsified oils. We have concluded, however, that the use of liquid oxygen in actual beach clean up is not promising because the very high temperatures associated with this combustion are almost certain to produce environmentally deleterious effects on the beach surface and its immediately sublying structures. However, the use of liquid oxygen augmentation for shore based and flyable incinerators may still play an important role in handing the problem of accumulated debris

  3. A Numerical Comparison of Spray Combustion between Raw and Water-in-Oil Emulsified Fuel

    Directory of Open Access Journals (Sweden)

    D. Tarlet

    2010-03-01

    Full Text Available Heavy fuel-oils, used engine oils and animal fat can be used as dense, viscous combustibles within industrial boilers. Burning these combustibles in the form of an emulsion with water enables to decrease the flame length and the formation of carbonaceous residue, in comparison with raw combustibles. These effects are due to the secondary atomization among the spray, which is a consequence of the micro-explosion phenomenon. This phenomenon acts in a single emulsion droplet by the fast (< 0.1 ms vaporization of the inside water droplets, leading to complete disintegration of the whole emulsion droplet. First, the present work demonstrates a model of spray combustion of raw fuel. Secondly, the spray combustion of water-in-oil emulsified fuel is exposed to the same burning conditions, taking into account the micro-explosion phenomenon. Finally, the comparison between the results with and without second atomization shows some similar qualitative tendencies with experimental measurements from the literature.

  4. Oil shale mines and their realizable production

    International Nuclear Information System (INIS)

    Habicht, K.

    1994-01-01

    The production of Estonian oil shale depends on its marketing opportunities. The realizable production is a function of the oil shale price, which in turn depends on production costs. The latter are dependent on which mines are producing oil shale and on the volume of production. The purpose of the present article is to analyze which mines should operate under various realizable production scenarios and what should be their annual output so that the total cost of oil shale production (including maintenance at idle mines) is minimized. This paper is also targeted at observing the change in the average production cost per ton of oil shale depending on the realizable output. The calculations are based on data for the first four months of 1993, as collected by N. Barabaner (Estonian Academy of Sciences, Institute of Economy). The data include the total production volume and production cost from the mines of RE 'Eesti Polevkivi' (State Enterprise 'Estonian Oil Shale'). They also project expenses from mine closings in case of conservation. The latter costs were allocated among mines in direct proportion to their respective number of employees. (author)

  5. Combustion modelling of a fuel oil flame; Modelisation de la combustion d`une flamme de fuel

    Energy Technology Data Exchange (ETDEWEB)

    Flour, I.; Mechitouan, N.

    1996-10-01

    The combustion modelling of a fuel oil flame has been realised in the scope of the R and D `Combustion Turbines`. This report presents the results of the 2D simulation of a fuel oil flame (n-octane), at atmospherical pressure, without swirl, realised using the Eulerian two-phase flow software Melodif. This calculation has been defined in collaboration with IFP, using experimental data from the IFRP. The hollow cone spray of liquid fuel is injected in the middle of the combustion chamber, with a co-flowing annular air. The furnace diameter is 2 meter and its length is 6,25 meter. A large recirculation zone is induced by the air flow, and leads to take into account the whole furnace, in order to avoid some problems with the limit conditions at the outlet. This calculation deals with droplets evaporation, gaseous phase combustion and radiation heat transfer. Predictions concerning gaseous axial mean velocity and mean temperature gradient in the flame, are in good agreement with measurements. However the temperature is too low in the peripheral zone of the flow. This is probably due to the fact that heat exchanges at the wall furnace are not correctly represented, because of a lack of detailed limit conditions for the walls. The mean radial velocity is not so well predicted, but this measurement is also quite difficult in a strongly longitudinal flow. The results concerning the dispersed phase will not be compared, because no measurements on the liquid fuel were available. As it has been experimentally observed, the simulation shows that the fuel oil spray quickly evaporates as it enters the combustion chamber. This result allows to propose to use an homogeneous approach (hypothesis of no-slipping between the two phases) in an Eulerian one-phase flow code, in case of a 3D simulation of liquid fuel turbine. (authors)

  6. The combustion of low calorific value fuels (oil shale) by using fluidized bed combustor

    International Nuclear Information System (INIS)

    Azzam, S.M.

    1993-01-01

    The present work reports an experimental data for combustion of oil-shale in a fluidized bed combustor. The experimental set up was designed for the combustion of low calorific value fuel such as oil-shale to facilitate the variation of many parameters over a wide operating range. A cold run was firstly conducted to study the fluidization parameters. Fluidization experiment were made with different sized quartiz particles. Minimum fluidization velocities and other fluidization characteristics were determined at room temperature. Secondary a hot run was started, first studying the combustion of 'LPG' in a fluidized bed as a starting process, then studying the combustion if oil-shale with different flow rates. The experimetal results are promising and give rise to hopes that this valuable deposit can be used as a fuel source and can be burned sucessfully in a fluidized bed combustor. This study had prooved that utilization of oil-shale a fuel source is no more a complicated technical problem, this opens the way for power generation using fluidized bed combustors. (author). 17 refs., 32 figs., 3 tabs

  7. The combustion of low calorific value fuels (oil shale) by using fluidized bed combustor

    Energy Technology Data Exchange (ETDEWEB)

    Azzam, S M

    1994-12-31

    The present work reports an experimental data for combustion of oil-shale in a fluidized bed combustor. The experimental set up was designed for the combustion of low calorific value fuel such as oil-shale to facilitate the variation of many parameters over a wide operating range. A cold run was firstly conducted to study the fluidization parameters. Fluidization experiment were made with different sized quartiz particles. Minimum fluidization velocities and other fluidization characteristics were determined at room temperature. Secondary a hot run was started, first studying the combustion of `LPG` in a fluidized bed as a starting process, then studying the combustion if oil-shale with different flow rates. The experimetal results are promising and give rise to hopes that this valuable deposit can be used as a fuel source and can be burned sucessfully in a fluidized bed combustor. This study had prooved that utilization of oil-shale a fuel source is no more a complicated technical problem, this opens the way for power generation using fluidized bed combustors. (author). 17 refs., 32 figs., 3 tabs.

  8. The enrichment behavior of natural radionuclides in pulverized oil shale-fired power plants

    International Nuclear Information System (INIS)

    Vaasma, Taavi; Kiisk, Madis; Meriste, Tõnis; Tkaczyk, Alan Henry

    2014-01-01

    The oil shale industry is the largest producer of NORM (Naturally Occurring Radioactive Material) waste in Estonia. Approximately 11–12 million tons of oil shale containing various amounts of natural radionuclides is burned annually in the Narva oil shale-fired power plants, which accounts for approximately 90% of Estonian electricity production. The radionuclide behavior characteristics change during the fuel combustion process, which redistributes the radionuclides between different ash fractions. Out of 24 operational boilers in the power plants, four use circulating fluidized bed (CFB) technology and twenty use pulverized fuel (PF) technology. Over the past decade, the PF boilers have been renovated, with the main objective to increase the efficiency of the filter systems. Between 2009 and 2012, electrostatic precipitators (ESP) in four PF energy blocks were replaced with novel integrated desulphurization technology (NID) for the efficient removal of fly ash and SO 2 from flue gases. Using gamma spectrometry, activity concentrations and enrichment factors for the 238 U ( 238 U, 226 Ra, 210 Pb) and 232 Th ( 232 Th, 228 Ra) family radionuclides as well as 40 K were measured and analyzed in different PF boiler ash fractions. The radionuclide activity concentrations in the ash samples increased from the furnace toward the back end of the flue gas duct. The highest values in different PF boiler ash fractions were in the last field of the ESP and in the NID ash, where radionuclide enrichment factors were up to 4.2 and 3.3, respectively. The acquired and analyzed data on radionuclide activity concentrations in different PF boiler ashes (operating with an ESP and a NID system) compared to CFB boiler ashes provides an indication that changes in the fuel (oil shale) composition and boiler working parameters, as well as technological enhancements in Estonian oil shale fired power plants, have had a combined effect on the distribution patterns of natural radionuclides in

  9. Combustion characteristics of lemongrass (Cymbopogon flexuosus oil in a partial premixed charge compression ignition engine

    Directory of Open Access Journals (Sweden)

    Avinash Alagumalai

    2015-09-01

    Full Text Available Indeed, the development of alternate fuels for use in internal combustion engines has traditionally been an evolutionary process in which fuel-related problems are met and critical fuel properties are identified and their specific limits defined to resolve the problem. In this regard, this research outlines a vision of lemongrass oil combustion characteristics. In a nut-shell, the combustion phenomena of lemongrass oil were investigated at engine speed of 1500 rpm and compression ratio of 17.5 in a 4-stroke cycle compression ignition engine. Furthermore, the engine tests were conducted with partial premixed charge compression ignition-direct injection (PCCI-DI dual fuel system to profoundly address the combustion phenomena. Analysis of cylinder pressure data and heat-release analysis of neat and premixed lemongrass oil were demonstrated in-detail and compared with conventional diesel. The experimental outcomes disclosed that successful ignition and energy release trends can be obtained from a compression ignition engine fueled with lemongrass oil.

  10. COMBUSTION CHARACTERISTICS OF DIESEL ENGINE OPERATING ON JATROPHA OIL METHYL ESTER

    Directory of Open Access Journals (Sweden)

    Doddayaraganalu Amasegoda Dhananjaya

    2010-01-01

    Full Text Available Fuel crisis because of dramatic increase in vehicular population and environmental concerns have renewed interest of scientific community to look for alternative fuels of bio-origin such as vegetable oils. Vegetable oils can be produced from forests, vegetable oil crops, and oil bearing biomass materials. Non-edible vegetable oils such as jatropha oil, linseed oil, mahua oil, rice bran oil, karanji oil, etc., are potentially effective diesel substitute. Vegetable oils have reasonable energy content. Biodiesel can be used in its pure form or can be blended with diesel to form different blends. It can be used in diesel engines with very little or no engine modifications. This is because it has combustion characteristics similar to petroleum diesel. The current paper reports a study carried out to investigate the combustion, performance and emission characteristics of jatropha oil methyl ester and its blend B20 (80% petroleum diesel and 20% jatropha oil methyl ester and diesel fuel on a single-cylinder, four-stroke, direct injections, water cooled diesel engine. This study gives the comparative measures of brake thermal efficiency, brake specific energy consumption, smoke opacity, HC, NOx, ignition delay, cylinder peak pressure, and peak heat release rates. The engine performance in terms of higher thermal efficiency and lower emissions of blend B20 fuel operation was observed and compared with jatropha oil methyl ester and petroleum diesel fuel for injection timing of 20° bTDC, 23° bTDC and 26° bTDC at injection opening pressure of 220 bar.

  11. Combustion characteristics of lemongrass (Cymbopogon flexuosus) oil in a partial premixed charge compression ignition engine

    OpenAIRE

    Avinash Alagumalai

    2015-01-01

    Indeed, the development of alternate fuels for use in internal combustion engines has traditionally been an evolutionary process in which fuel-related problems are met and critical fuel properties are identified and their specific limits defined to resolve the problem. In this regard, this research outlines a vision of lemongrass oil combustion characteristics. In a nut-shell, the combustion phenomena of lemongrass oil were investigated at engine speed of 1500 rpm and compression ratio of 17....

  12. Composition, diagenetic transformation and alkalinity potential of oil shale ash sediments

    International Nuclear Information System (INIS)

    Motlep, Riho; Sild, Terje; Puura, Erik; Kirsimaee, Kalle

    2010-01-01

    Oil shale is a primary fuel in the Estonian energy sector. After combustion 45-48% of the oil shale is left over as ash, producing about 5-7 Mt of ash, which is deposited on ash plateaus annually almost without any reuse. This study focuses on oil shale ash plateau sediment mineralogy, its hydration and diagenetic transformations, a study that has not been addressed. Oil shale ash wastes are considered as the biggest pollution sources in Estonia and thus determining the composition and properties of oil shale ash sediment are important to assess its environmental implications and also its possible reusability. A study of fresh ash and drillcore samples from ash plateau sediment was conducted by X-ray diffractometry and scanning electron microscopy. The oil shale is highly calcareous, and the ash that remains after combustion is derived from the decomposition of carbonate minerals. It is rich in lime and anhydrite that are unstable phases under hydrous conditions. These processes and the diagenetic alteration of other phases determine the composition of the plateau sediment. Dominant phases in the ash are hydration and associated transformation products: calcite, ettringite, portlandite and hydrocalumite. The prevailing mineral phases (portlandite, ettringite) cause highly alkaline leachates, pH 12-13. Neutralization of these leachates under natural conditions, by rainwater leaching/neutralization and slow transformation (e.g. carbonation) of the aforementioned unstable phases into more stable forms, takes, at best, hundreds or even hundreds of thousands of years.

  13. Composition, diagenetic transformation and alkalinity potential of oil shale ash sediments

    Energy Technology Data Exchange (ETDEWEB)

    Motlep, Riho, E-mail: riho.motlep@ut.ee [Department of Geology, University of Tartu, Ravila 14A, 50411 Tartu (Estonia); Sild, Terje, E-mail: terje.sild@maaamet.ee [Estonian Land Board, Mustamaee tee 51, 10621 Tallinn (Estonia); Puura, Erik, E-mail: erik.puura@ut.ee [Institute of Technology, University of Tartu, Nooruse 1, 50411 Tartu (Estonia); Kirsimaee, Kalle, E-mail: kalle.kirsimae@ut.ee [Department of Geology, University of Tartu, Ravila 14A, 50411 Tartu (Estonia)

    2010-12-15

    Oil shale is a primary fuel in the Estonian energy sector. After combustion 45-48% of the oil shale is left over as ash, producing about 5-7 Mt of ash, which is deposited on ash plateaus annually almost without any reuse. This study focuses on oil shale ash plateau sediment mineralogy, its hydration and diagenetic transformations, a study that has not been addressed. Oil shale ash wastes are considered as the biggest pollution sources in Estonia and thus determining the composition and properties of oil shale ash sediment are important to assess its environmental implications and also its possible reusability. A study of fresh ash and drillcore samples from ash plateau sediment was conducted by X-ray diffractometry and scanning electron microscopy. The oil shale is highly calcareous, and the ash that remains after combustion is derived from the decomposition of carbonate minerals. It is rich in lime and anhydrite that are unstable phases under hydrous conditions. These processes and the diagenetic alteration of other phases determine the composition of the plateau sediment. Dominant phases in the ash are hydration and associated transformation products: calcite, ettringite, portlandite and hydrocalumite. The prevailing mineral phases (portlandite, ettringite) cause highly alkaline leachates, pH 12-13. Neutralization of these leachates under natural conditions, by rainwater leaching/neutralization and slow transformation (e.g. carbonation) of the aforementioned unstable phases into more stable forms, takes, at best, hundreds or even hundreds of thousands of years.

  14. Performance, combustion and emission analysis of mustard oil biodiesel and octanol blends in diesel engine

    Science.gov (United States)

    Devarajan, Yuvarajan; Munuswamy, Dinesh Babu; Nagappan, Beemkumar; Pandian, Amith Kishore

    2018-01-01

    Biodiesels from the mustard oil promise to be an alternative to the conventional diesel fuel due to their similarity in properties. Higher alcohols are added to neat Mustard oil biodiesel (M100) to vary the properties of biodiesel for improving its combustion, emission and performance characteristics. N-Octanol has the ability to act as an oxygen buffer during combustion which contributes to the catalytic effect and accelerates the combustion process. N-Octanol is dispersed to neat Mustard oil biodiesel in the form of emulsions at different dosage levels of 10, 20 and 30% by volume. Three emulsion fuels prepared for engine testing constitutes of 90% of biodiesel and 10% of n-Octanol (M90O10), 80% of biodiesel and 20% of n-Octanol (M80O20) and 70% of biodiesel and 30% of n-Octanol (M70O30) by volume respectively. AVL 5402 diesel engine is made to run on these fuels to study the effect of n-Octanol on combustion, emission and performance characteristics of the mustard oil biodiesel. Experimental results show that addition of n-octanol has a positive effect on performance, combustion and emission characteristics owing to its inbuilt oxygen content. N-octanol was found to be the better oxidizing catalyst as it was more effective in reducing HC and CO emissions. A significant reduction in NOx emission was found when fuelled with emulsion techniques. The blending of n-octanol to neat Mustard oil biodiesel reduces the energy and fuel consumption and a marginal increase in brake thermal efficiency. Further, n-octanol also reduces the ignition delay and aids the combustion.

  15. Performance, combustion and emission analysis of mustard oil biodiesel and octanol blends in diesel engine

    Science.gov (United States)

    Devarajan, Yuvarajan; Munuswamy, Dinesh Babu; Nagappan, Beemkumar; Pandian, Amith Kishore

    2018-06-01

    Biodiesels from the mustard oil promise to be an alternative to the conventional diesel fuel due to their similarity in properties. Higher alcohols are added to neat Mustard oil biodiesel (M100) to vary the properties of biodiesel for improving its combustion, emission and performance characteristics. N-Octanol has the ability to act as an oxygen buffer during combustion which contributes to the catalytic effect and accelerates the combustion process. N-Octanol is dispersed to neat Mustard oil biodiesel in the form of emulsions at different dosage levels of 10, 20 and 30% by volume. Three emulsion fuels prepared for engine testing constitutes of 90% of biodiesel and 10% of n-Octanol (M90O10), 80% of biodiesel and 20% of n-Octanol (M80O20) and 70% of biodiesel and 30% of n-Octanol (M70O30) by volume respectively. AVL 5402 diesel engine is made to run on these fuels to study the effect of n-Octanol on combustion, emission and performance characteristics of the mustard oil biodiesel. Experimental results show that addition of n-octanol has a positive effect on performance, combustion and emission characteristics owing to its inbuilt oxygen content. N-octanol was found to be the better oxidizing catalyst as it was more effective in reducing HC and CO emissions. A significant reduction in NOx emission was found when fuelled with emulsion techniques. The blending of n-octanol to neat Mustard oil biodiesel reduces the energy and fuel consumption and a marginal increase in brake thermal efficiency. Further, n-octanol also reduces the ignition delay and aids the combustion.

  16. Investigation on the co-combustion of low calorific oil shale and its semi-coke by using thermogravimetric analysis

    International Nuclear Information System (INIS)

    Yang, Yu; Lu, Xiaofeng; Wang, Quanhai

    2017-01-01

    Highlights: • The co-combustion characteristic parameters were studied. • The co-combustion of oil shale and semi-coke could be expressed roughly by the addition of individual components. • Activation energy was calculated by Coats-Redfern, distributed activation energy model and Flynn-Wall-Ozawa methods. - Abstract: In the present work, thermogravimetric analysis was employed to investigate co-combustion behaviors of Fushun low calorific oil shale and its semi-coke. The synergy effect was estimated by using the interaction coefficient and the relative error of mean square root. In addition, activation energy was also calculated by means of Coats-Redfern, distributed activation energy model and Flynn-Wall-Ozawa methods. Results indicated that with the increase of oil shale mass fraction and oxygen concentration, combustion characteristics of the samples were improved. And some little interaction did occur during the co-combustion process, but it was relatively slight. Consequently, the co-combustion of oil shale and semi-coke still could be expressed roughly by the addition of individual components of the mixtures. Furthermore, activation energy of the samples decreased slowly at the initial stage attributed to the minerals’ catalytic effects, and in the final stage, it jumped to a high value, suggesting that the burnout of the samples was difficult. Besides, the mix proportion of oil shale which was added to stabilize the combustion in the circulating fluidized bed was also theoretically calculated.

  17. Logistics in Estonian business companies

    Directory of Open Access Journals (Sweden)

    A. Kiisler

    2008-12-01

    Full Text Available The article describes logistics survey in Estonia carried out in 2007 as a part of the LogOnBaltic project. The level of logistics in Estonian manufacturing, trading and logistics companies is explored through logistics costs, performance indicators, outsourcing, ICT use and logistics self-estimation of the companies responded. Responses from 186 Estonian companies were gathered through a web-based survey (38% of manufacturing, 38% of trading and 24% of logistics sector. Logistics costs as the percentage of turnover make in average 13.8% in manufacturing and 13.3% in trading. Transportation and inventory carrying cost form around 70% of overall logistics costs. Considering the logistics indicators surveyed, Estonian companies show up with relatively low perfect order fulfillment rates, short customer order fulfillment cycles and effective management of cash flows. The most widely outsourced logistics function is international transportation followed by domestic transportation, freight forwarding and reverse logistics. By 2010, the outsourcing of IT systems in logistics followed by inventory management, warehousing and product customization is expected to increase more substantially. The awareness of logistics importance is still low among Estonian companies. Only 27–44% of those agree that logistics has a considerable impact on profitability, competitive advantage, top management or customer service level.

  18. Investigation on the co-combustion of oil shale and municipal solid waste by using thermogravimetric analysis

    International Nuclear Information System (INIS)

    Fan, Yunlong; Yu, Zhaosheng; Fang, Shiwen; Lin, Yan; Lin, Yousheng; Liao, Yanfen; Ma, Xiaoqian

    2016-01-01

    Highlights: • Co-combustion of oil shale with municipal solid waste created significant changes. • Blending with municipal solid wastes could improve the combustion performance. • 10–30% of oil shale in the blends could be determined as the optimum ratio range. • Activation energy were calculated by the conversion rate and different proportion. - Abstract: The aim of this study is trying to reveal the thermal characteristics and kinetics of oil shale, municipal solid waste and their blends in the combustion process which are needed for efficient utilization. The combustion experiment is carried out in a thermogravimetric simultaneous thermal analyzer, where the temperature ranged from 110 °C to 900 °C at three different heating rates as 10 °C/min, 20 °C/min and 30 °C/min. Their kinetics were studied by Ozawa–Flynn–Wall and Friedmen methods. According to the data analysis, combustion characteristic index increased progressively with the increase of the proportion of municipal solid waste. And it’s suggested that there was certain interaction in the combustion process of oil shale and municipal solid waste. The average activation energy of the blends reached the minimum value, 177.7927 kJ/mol by Ozawa–Flynn–Wall method and 167.4234 kJ/mol by Friedmen method, when the proportion of MSW was 70%.

  19. Oil shale mining and processing impact on landscapes in north-east Estonia

    International Nuclear Information System (INIS)

    Toomik, Arvi; Liblik, Valdo

    1998-01-01

    As the world's largest commercial oil shale reserve, the Estonian Oil Shale Deposit has been exploited since 1916. As a result of mining, storing of solid wastes from the oil shale separation, combustion in the power plants and its thermal processing, the landscape in northeastern Estonia has been essentially changed and the man-made landforms have developed: the new microreliefs of natural and artificial structure are formed, as well as 'mountainous' and hilly reliefs in the form of waste heaps, ash plateaus, coke-ash dumps etc. Deformed (stable) and undeformed (unstable) areas from underground mining currently cover about 220km 2 . About 90km 2 (80%) of the area damaged by open pits are recultivated and reformed as forested and agricultural (grassland) areas. The total area occupied by solid waste has reached up to 26km 2 . New technogenic landscape units, i.e. made by technical means, will essentially influence the environment

  20. Digimodernistlik eesti kirjanik / The Digimodernist Estonian Writer

    Directory of Open Access Journals (Sweden)

    Piret Viires

    2013-06-01

    Full Text Available The article examines the cultural situation following postmodernism in the first decade of the 21st century. To characterise this situation, the umbrella term “post-postmodernism” is used, as well as “neomodernism”, “altermodern”, “metamodernism”, “hypermodernity”, “performatism”, “critical realism” etc. All these approaches are, in a wider sense, united by their aim of opposing postmodernist cynicism and irony, and bringing back truth, simplicity and clarity. It has also been found that literature has returned or is returning to realism, and various cultural phenomena are emerging, which have been designated by the concept “new sincerity”.In descriptions of the current cultural situation, this trend seeking truth and simplicity is supported by approaches which emphasise the significance of technological developments during the last decade. A prominent figure here is Alan Kirby, who launched the term “digimodernism”, mainly linked with the adaptation and spread of Web 2.0 at the beginning of the 21st century: the blogosphere, Wikipedia, Twitter and Facebook.The article seeks answers to the question of whether we can talk about digimodernism in Estonian literature in the 2000s. In the 1990s Estonian writers were quite reluctant to undertake computer-technological experiments, and there are only a few examples of Estonian digital literature, whereas a change occurred in the 2000s. Many Estonian writers have had and still have their own blogs and surprisingly many have joined Facebook. The term “twitterature” is also familiar to Estonian writers. The article tackles the dominant topics in the blogs of Estonian writers and analyses their possible collective creative work on Facebook. A question is raised as to whether it is possible that the fragmentary narrative structure of blogs and Facebook has influenced mainstream literature.The article concludes that one essential change in Estonian literature in the

  1. Emissions of Jatropha oil-derived biodiesel blend fuels during combustion in a swirl burner

    Science.gov (United States)

    Norwazan, A. R.; Mohd. Jaafar, M. N.; Sapee, S.; Farouk, Hazir

    2018-03-01

    Experimental works on combustion of jatropha oil biodiesel blends of fuel with high swirling flow in swirl burner have been studied in various blends percentage. Jatropha oil biodiesel was produced using a two-step of esterification-transesterification process. The paper focuses on the emissions of biodiesel blends fuel using jatropha oil in lean through to rich air/fuel mixture combustion in swirl burner. The emissions performances were evaluated by using axial swirler amongst jatropha oil blends fuel including diesel fuel as baseline. The results show that the B25 has good emissions even though it has a higher emission of NOx than diesel fuel, while it emits as low as 42% of CO, 33% of SO2 and 50% of UHC emissions with high swirl number. These are due to the higher oxygen content in jatropha oil biodiesel.

  2. Some problems of oil shale retorting in Estonia

    International Nuclear Information System (INIS)

    Oepik, I.

    1994-01-01

    Oil shale in Estonia will be competitive in the long term as a primary resource for power generating. The price of energy of Estonian oil shale is at present approximately 4 times lower than of coal. The price of electricity is anticipated to grow up to EEK 1.0/kWh in year 2020. The electricity price EEK 0.2/kWh at present in Estonia does not include capital costs needed for refurbishing of Estonian oil-shale-consuming power stations between the years 2000-2010. While all the prices and calculations of the enterprise are presented with no inflation adjustment, the other operation costs of oil shale retorting are anticipated for the prognosed period to remain at the present level: power consumption kWh 280/t crude oils and other operation costs (excluding labour, raw material and power consumption) EEK 100/t of oil

  3. Combustion Characteristics of CI Diesel Engine Fuelled With Blends of Jatropha Oil Biodiesel

    Science.gov (United States)

    Singh, Manpreet; Yunus Sheikh, Mohd.; Singh, Dharmendra; Nageswara rao, P.

    2018-03-01

    Jatropha Curcas oil is a non-edible oil which is used for Jatropha biodiesel (JBD) production. Jatropha biodiesel is produced using transesterification technique and it is used as an alternative fuel in CI diesel engine without any hardware modification. Jatropha biodiesel is used in CI diesel engine with various volumetric concentrations (blends) such as JBD5, JBD15, JBD25, JBD35 and JBD45. The combustion parameters such as in-cylinder pressure, rate of pressure rise, net heat release, cumulative heat release, mass fraction burned are analyzed and compared for all blends combustion data with mineral diesel fuel (D100).

  4. Ethnic Self-Esteem and Intergroup Attitudes Among the Estonian Majority and the non-Estonian Minority

    Directory of Open Access Journals (Sweden)

    Maaris Raudsepp

    2009-11-01

    Full Text Available The study was focussed on the relationships between ethnic self-esteem and various indicators of intergroup attitudes in a representative sample of adult population of Estonia (N=1142. Attitudinal variables that discriminated most between persons with high and low ethnic self-esteem were identified. Among Estonians ethnic self-esteem was related to positive ingroup bias, readiness for outgroup contact, perceived threat from the outgroup, attitudes to non-Estonian minority, and attitudes toward minority integration. Among non-Estonians ethnic self-esteem was related to readiness for outgroup contact, ethnic sterotypes, and various attitudes towards minority integration. An attempt was made to reconstruct the system of intergroup attidues of prototypical persons with high and low ethnic selfesteem and to describe psychological implications of high and low ethnic self-esteem for members of majority and minority groups. Various theoretical models (social identity theory, integrated threat theory, social dominane theory were used for interpretation of the results.

  5. Clean Fuel, Clean Energy Conversion Technology: Experimental and Numerical Investigation of Palm Oil Mill Effluent Biogas Flameless Combustion

    Directory of Open Access Journals (Sweden)

    Seyed Ehsan Hosseini

    2015-08-01

    Full Text Available The combustion of effluent biogas from a palm oil mill is not feasible on a large scale because of its low calorific value (LCV. Therefore, the captured biogas is usually flared because of a lack of appropriate combustion technology. However, such biogas could be an excellent source of energy for combined heat and power (CHP generation in palm oil mills. In this paper, the feasibility of using biogas from palm oil mills in flameless combustion systems is investigated. In computational fluid dynamic (CFD modeling, a two-step reaction scheme is employed to simulate the eddy dissipation method (EDM. In such biogas flameless combustion, the temperature inside the chamber is uniform and hot spots are eliminated. The peak of the non-luminous flame volume and the maximum temperature uniformity occur under stoichiometric conditions when the concentration of oxygen in the oxidizer is 7%. In these conditions, as the concentration of oxygen in the oxidizer increases, the efficiency of palm oil mill effluent biogas flameless combustion increases. The maximum efficiency (around 61% in the experiment is achieved when the percentage of oxygen in the oxidizer is 7%.

  6. Joakim Helenius: Estonian Air võtku eeskuju airBalticust / Siim Sultson

    Index Scriptorium Estoniae

    Sultson, Siim

    2010-01-01

    Estonian Airi ühe võimaliku nõukogu esimehe Jaokim Heleniuse hinnangul on väikeste lennufirmade, nagu Estonian Air ja airBaltic jaoks päris palju tegutsemisruumi. Estonian Airil tuleb leida oma nišš ja kindel, kuid omanäoline strateegia

  7. Combustion of palm oil solid waste in fluidized bed combustor

    International Nuclear Information System (INIS)

    Abdullah, I.; Shamsuddin, A.H.; Sopian, K.

    2000-01-01

    Results of experimental investigations of fluidized bed combustion of palm oil wastes consisting of shell, fibre and empty fruit bunches high heating value of 17450 kJ/kg and low heating value of 14500 kJ/kg. The fluidized bed combuster used has a vessel size of 486 x 10 6 mm 3 , surface area of evaporation tubes and distribution air pipes of 500 mm 2 and 320 mm 2 respectively. It was found that a fuel feeding rate 160 kg/h is required to achieve a steam flow rate of 600 kg/h, with the combustion efficiency 96% and boiler efficiency of 72%, emission level of flue gas NO x at less than 180 ppm, SO 2 at less than 20 ppm are measured in the flue gas. (Author)

  8. Combustion Properties of Biomass Flash Pyrolysis Oils: Final Project Report

    Energy Technology Data Exchange (ETDEWEB)

    C. R. Shaddix; D. R. Hardesty

    1999-04-01

    Thermochemical pyrolysis of solid biomass feedstocks, with subsequent condensation of the pyrolysis vapors, has been investigated in the U.S. and internationally as a means of producing a liquid fuel for power production from biomass. This process produces a fuel with significantly different physical and chemical properties from traditional petroleum-based fuel oils. In addition to storage and handling difficulties with pyrolysis oils, concern exists over the ability to use this fuel effectively in different combustors. The report endeavors to place the results and conclusions from Sandia's research into the context of international efforts to utilize pyrolysis oils. As a special supplement to this report, Dr. Steven Gust, of Finland's Neste Oy, has provided a brief assessment of pyrolysis oil combustion research efforts and commercialization prospects in Europe.

  9. Estonian Air lõpetab Pariisi ja Vilniuse lennud / Hindrek Riikoja

    Index Scriptorium Estoniae

    Riikoja, Hindrek

    2005-01-01

    Talvisele lennuplaanile üleminev Estonian Air lõpetab otselennud Tallinnast Vilniusesse ja Pariisi. Estonian Airi presidendi Borge Thornbechi sõnul kavatseb firma suurendada talvehooajal turismilendude mahtu

  10. Air Baltic: Estonian Air on nurka surutud / Teele Tammeorg

    Index Scriptorium Estoniae

    Tammeorg, Teele

    2010-01-01

    Air Balticu asepresidendi Janis Vanagsi hinnangul on Estonian Air aastaid jätnud tähelepanuta oma peamised turismiturud ning on praegu halvas seisus. Air Baltic on endiselt huvitatud Estonian Airi ostust. Majandus- ja kommunikatsiooniminister Juhan Partsi seisukoht

  11. The effect of oil additives on exhaust emission of internal combustion engines

    International Nuclear Information System (INIS)

    Dimitrovski, M.B.; Kuzmanovski, K.A.

    1999-01-01

    An attempt was conducted to acquire data on connection between motor oil and motor oil additives and exhaust emission of internal combustion engine. The consulted literature did not contain enough data, so experiments were conducted. The results of the experiments are presented on diagrams that have been processed in the computer program EXCEL. Conclusions that were made out of that work show the need of expanding research on the subject. (Author)

  12. Estonian Air valmistub odavate piletitega EasyJeti tulekuks / Erkki Erilaid

    Index Scriptorium Estoniae

    Erilaid, Erkki

    2004-01-01

    Estonian Air pidi langetama piletihindu Berliini ja Londoni liinil kolmandiku võrra, kuna oktoobri lõpust hakkab Tallinna lennujaamast reise tegema uus odavlennufirma Easy-Jet. Lisa: Estonian Airi hinnad internetis

  13. Estonian Airi president : uus äristrateegia toob ettevõttele edu / Borge Thornbech ; interv. Andres Reimer

    Index Scriptorium Estoniae

    Thornbech, Borge

    2007-01-01

    Estonian Air asutas regionaalsete lendude korraldamiseks ettevõtte Estonian Air Regional, idee on arendada tegevust lühidistantsidel ja luua ühenduslüli lennukompanii Euroopa-liinide vahel. Kommenteerivad Olev Schults, Oleg Harlamov, Rein Mark. Vt. samas: Kõik aktsionärid vannuvad Estonian Airile truudust; Estonian Air kaalub Tartu lennuliini avamist. Kaart: Reisijate jagunemine sihtkohtade vahel. Graafikud: Estonian Air kukkus kahjumisse

  14. Genotoxicity of diesel engine emissions during combustion of vegetable oils, mineral oil, and their blends; Gentoxizitaet von Dieselmotoremissionen bei Verbrennung von Pflanzenoelen, Mineraloeldiesel und deren Mischkraftstoffen

    Energy Technology Data Exchange (ETDEWEB)

    Buenger, Joern

    2013-07-09

    High particle emissions and strong mutagenic effects were observed after combustion of vegetable oil in diesel engines. This study tested the hypothesis that these results are affected by the amount of unsaturated or polyunsaturated fatty acids of vegetable oils and that blends of diesel fuel and vegetable oil are mutagenic. Three different vegetable oils (linseed oil, LO; palm tree oil, PO; rapeseed oil, RO), blends of 20% vegetable oil and 80% diesel fuel (B20) and 50% vegetable oil and 50% diesel fuel (B50) as well as common diesel fuel (DF) were combusted in a heavy duty diesel engine. The exhaust was investigated for particle emissions and its mutagenic effect in comparison to emissions of DF. The engine was operated using European Stationary Cycle. Particle mass was determined gravimetrically while mutagenicity was determined using the bacterial reverse mutation assay with tester strains TA98 and TA100. Combustion of LO caused the largest amount of total particulate matter (TPM). In comparison to DF it particularly raised the soluble organic fraction (SOF). RO presented second highest TPM and SOF, followed by PO which was scarcely above DF. B50 revealed the lowest amount of TPM while B20 reached as high as DF. RO revealed the highest number of mutations of the vegetable oils closely followed by LO. PO was less mutagenic, but still induced stronger effects than DF. B50 showed higher mutagenic potential than B20. While TPM and SOF were strongly correlated with the content of polyunsaturated fatty acids in the vegetable oils, mutagenicity had a significant correlation with the amount of total unsaturated fatty acids. Vegetable oil blends seem to be less mutagenic than the pure oils with a shifted maximum compared to blends with biodiesel and DF. This study supports the hypothesis that numbers of double bounds in unsaturated fatty acids of vegetable oils combusted in diesel engines influence the amount of emitted particles and the mutagenicity of the exhaust. And

  15. A burner for the combustion of spent tall oil soap

    Energy Technology Data Exchange (ETDEWEB)

    Hughes, P.M.; Wong, J.K.; Moffatt, B.; Belanger, G. [Natural Resources Canada, Ottawa, ON (Canada). CANMET Energy Technology Centre; Soriano, D. [Brais Malouin and Associates, Montreal, PQ (Canada)

    2003-07-01

    Efficiency in industrial processes applies both to the form of energy involved and the many by-products resulting from the process. Tall oil soap (TOS) is a white frothy substance created during the pulping process. It contains chemicals that can be extracted for use in other industries. The processing of TOS results in a product called spent TOS. This study examined the incineration process to derive process heat from the calorific value in spent TOS. Brais Malouin and Associates (BMA) proposed that an atomizing nozzle should be used for use with this liquid in an incinerating burner. The efficiency of atomization of spent TOS with the BMA nozzle was determined by the Canada Centre for Mineral and Energy Technology (CANMET), which also characterized the combustion in a simulated boiler situation. The combustion tests were performed in the Pilot-Scale Research Boiler at the CANMET Energy Technology Centre (CETC). Pre-heating was done with a number 2 oil flame. Flame stability was determined by observing the flame through sight ports and by measuring the gas in the furnace. The experiments showed that spent TOS could successfully burn with a number 2 oil, in a proportion of 81 spent TOS to 19 oil mass ratio. As the amount of spent TOS was increased, the amount of sulphur dioxide, nitrogen oxide (NOx) and carbon monoxide decreased. The number 2 fuel oil was responsible for the sulphur dioxide in the exhaust. It is believed that the reduction in the carbon monoxide in the exhaust is attributable to the water-gas shift reaction. As the proportion of spent TOS increased, it was shown that the amount of NOx in the exhaust decreased rapidly. A bluish-green molten deposit formed in the furnace near the burner came from copper and manganese found in the ash of the spent TOS. 7 refs., 7 tabs., 16 figs.

  16. SAS tahab Estonian Airi liita lätlaste firmaga airBaltic / Andres Eilart

    Index Scriptorium Estoniae

    Eilart, Andres

    2007-01-01

    SAS plaanib Estonian Airi ja Läti firma airBalticu liitmisega luua uue lennufirma. Autori hinnangul viitavad Estonian Airi laienemisplaanidele kriipsu peale tõmbamine ja SAS-i investeeringud airBalticusse sellele, et ühendamise käigus "neelab" Läti firma Estonian Airi

  17. Stocks of organic carbon in Estonian soils

    Directory of Open Access Journals (Sweden)

    Kõlli, Raimo

    2009-06-01

    Full Text Available The soil organic carbon (SOC stocks (Mg ha–1 ofautomorphic mineral (9 soil groups, hydromorphic mineral (7, and lowland organic soils (4 are given for the soil cover or solum layer as a whole and also for its epipedon (topsoil layer. The SOC stocks for forest, arable lands, and grasslands and for the entire Estonian soil cover were calculated on the basis of the mean SOC stock and distribution area of the respective soil type. In the Estonian soil cover (42 400 km2, a total of 593.8 ± 36.9 Tg of SOC is retained, with 64.9% (385.3 ± 27.5 Tg in the epipedon layer (O, H, and A horizons and 35.1% in the subsoil (B and E horizons. The pedo-ecological regularities of SOC retention in soils are analysed against the background of the Estonian soil ordination net.

  18. Estonian horticultural peat marketing: sales promotion and price formation. 2. part

    International Nuclear Information System (INIS)

    Hammer, Hele

    1999-01-01

    When forming prices, Estonian peat companies' decisions should be based on marginal cost analysis. Unfortunately most Estonian companies sell peat to intermediaries and cannot influence its price. Estonian peat producers have to choose between either selling peat directly or selling through a central marketing organization. Both systems have their pros and cons. Direct selling gives more freedom to individual producers but is more risky. Central marketing makes cost saving possible and is more effective and stable, but may alienate producers from clients and markets. Whichever marketing system Estonian peat companies choose, the most important elements in their marketing strategy should be: careful market analysis, personal sales, attending trade shows, catalogues, quality service and offering transportation services. (author)

  19. PM From the Combustion of heavy fuel oils

    KAUST Repository

    Elbaz, Ayman M.

    2018-03-30

    This work presents an experimental study investigating the formation and oxidation of particulate matter from the combustion of heavy fuel oil, HFO, droplets. The study includes results from both a falling droplet in a drop tube furnace and a suspended droplet in a heated convective flow. The falling droplets in a heated coflow air with variable temperature path and velocity were combusted and the resulting particles, cenospheres, were collected. To characterize the microstructure of these particles, scanning electron microscopy (SEM), and energy dispersive X-Ray (EDX) analysis were used. The particles were found to have either a porous or a skeleton/membrane morphology. The percentage of particles of either type appears to be related to the thermal history, which was controlled by the heated co-flow velocity. In the suspended droplet experiments, by suspending the droplet on a thermocouple, the temperature inside the droplet was measured while simultaneously imaging the various burning phases. A number of specific phases were identified, from liquid to solid phase combustion are presented and discussed. The droplet ignition temperature was seen to be independent of the droplet size. However, the liquid phase ignition delay time and the droplet lifetime were directly proportional to the initial droplet diameter.

  20. Transformational Leadership in the Estonian Defence Forces

    Directory of Open Access Journals (Sweden)

    Antek Kasemaa

    2015-06-01

    Full Text Available Purpose – The study is a contribution to the validation of the 15 items and 5 subscales Transformational Leadership Scale (TLS proposed by Rafferty and Griffin (2004. Design/methodology/approach – The sample includes participants from different levels of the Estonian Defence Forces (EDF military hierarchy (N=2570. The structure of the TLS was examined by using exploratory and confirmatory factor analyses. Additionally ANOVA was used to compare the results between different subsamples. Findings – TLS showed satisfactory reliability. Confirmatory factor analyses found TLS as valid five dimensions instrument to measure transformational leadership in the Estonian military context. Different management levels showed different emphases among the dimensions of transformational leadership. Research and practical limitations/implications – TLS will be an important tool to use in transformational leadership research in the Estonian military context and beyond. Additionally, the current research contributes to the development of alternative measurement tools besides the most commonly used MLQ. The limitation of the work will be the rather homogenous sample from the Estonian military, however it will open the door for the subsequent research using different samplings. Originality/value – The current research found TLS to be a reliable and valid instrument, very short and therefore easy to administrate, having the possibility to use it with five dimensional and as one general transformational instrument as well.

  1. Uniting the Divided Continent. The Estonian National Committee of the European Movement

    Directory of Open Access Journals (Sweden)

    Pauli Heikkilä

    2010-12-01

    Full Text Available The article examines the exiled Estonian politicians in the European Movement in the early Cold War period. The ultimate goal of exiled Estonians was to restore their state’s independence. In order to promote this, Estonian leaders sought connections with Western leaders. The European Movement was the only organisation involving actors from both the East and the West, and this corresponded to the Estonian discourse on Europe as a whole. Therefore, the European Movement was appreciated, although its limited opportunities for decisive actions were also recognised. East and West European interest in the European Movement declined as West European integration rapidly intensified through the European Coal and Steel Community (ECSC and particularly after the January 1952 Eastern European Conference in London. By 1957, disappointment in the inability of European unification to help regain Estonian independence became evident.

  2. Properties of chicken manure pyrolysis bio-oil blended with diesel and its combustion characteristics in RCEM, Rapid Compression and Expansion Machine

    Directory of Open Access Journals (Sweden)

    Sunbong Lee

    2014-06-01

    Full Text Available Bio-oil (bio-oil was produced from chicken manure in a pilot-scale pyrolysis facility. The raw bio-oil had a very high viscosity and sediments which made direct application to diesel engines difficult. The bio-oil was blended with diesel fuel with 25% and 75% volumetric ratio at the normal temperature, named as blend 25. A rapid compression and expansion machine was used for a combustion test under the experimental condition corresponding to the medium operation point of a light duty diesel engine using diesel fuel, and blend 25 for comparison. The injection related pressure signal and cylinder pressure signal were instantaneously picked up to analyze the combustion characteristics in addition to the measurement of NOx and smoke emissions. Blend 25 resulted in reduction of the smoke emission by 80% and improvements of the apparent combustion efficiency while the NOx emission increased by 40%. A discussion was done based on the analysis results of combustion.

  3. Estonian Airi uued soodsad pakkumised

    Index Scriptorium Estoniae

    2010-01-01

    Estonian Airi kodulehelt on võimalik osta lennupileteid koostööpartnerite poolt pakutavatele mandritevahelistele lendudele ning broneerida internetis hotellituba Euroopa suurima hotelli broneerimise teenust pakkuva ettevõtte Booking.com kaudu

  4. Combustion of Pure, Hydrolyzed and Methyl Ester Formed of Jatropha Curcas Lin oil

    Directory of Open Access Journals (Sweden)

    Muhaji Muhaji

    2015-10-01

    Full Text Available The density and viscosity of vegetable oil are higher than that of diesel oil. Thus its direct combustion in the diesel engine results many problems. This research was conducted to investigate the flame characteristics of combustion of jatropha curcas lin in pure, hydrolyzed and methyl ester form. The results indicated that the combustion of pure jatropha curcas lin occurs in three stages, hydrolyzed in two stages    and methyl ester in one stage. For pure jatropha curcas lin, in the first stage, unsaturated fatty acid burned for  0.265 s.  It is followed by saturated fatty acid, burned for 0.389 s in the second stage. And, in the last stage is the burned of glycerol for 0.560 s. Meanwhile for hydrolyzed one, in the first stage, unsaturated fatty acid burned for 0.736 s, followed by saturated fatty acid, burned  for 0.326 s in the second stage. And the last, for methyl ester is the burned for 0.712 s. The highest burning rate was for methyl ester which was 0.003931cc/s. The energy releasing rate of methyl ester, which was for 13,628.67 kcal/(kg.s resembled that of diesel oil the most, while the lowest rate was for pure jatropha curcas lin which was 8,200.94 kcal/(kg.s. In addition, massive explosion occurred in the fuel containing unsaturated fatty acid and glycerol

  5. Estonian energy system: Proposals for the implementation of a cogeneration strategy

    International Nuclear Information System (INIS)

    Lund, H.; Hvelplund, F.; Ingermann, K.; Kask, U.

    2000-01-01

    Since the Soviet era Estonia inherited oil-shale-based electricity plants, with a capacity of 3000 MW. Oil shale now provides Estonia with very low electricity prices. However, most of the stations are very old. Half of them were built before 1965, and sooner or later the old oil shale production units will have to be replaced. Estonia will then have to face serious increases in electricity production prices. At the same time Estonia has problems in restoring its district heating systems. The prices are rising and may consumers have converted to other heating sources such as electric heating. The major long-term strategic policy choices to make in Estonia are to decide (1) whether the oil shale power stations should be replaced by new centralized production units such as new oil shale stations or nuclear power, or (2) whether the electricity production should be decentralized. In the centralized solution (oil shale or nuclear power), the domestic heating will be left to boilers or electric heating leading to a very high primary energy supply. In the decentralized solution, Estonia could benefit from the advantage of cogeneration leading to very low fuel consumption. But this latter strategy depends on the restoration of the district heating systems. This article seeks to form a strategy to improve the efficiency of the Estonian energy system by increasing the use of cogeneration. (author)

  6. Heavy fuel oil pyrolysis and combustion: kinetics and evolved gases investigated by TGA-FTIR

    KAUST Repository

    Abdul Jameel, Abdul Gani

    2017-08-24

    Heavy fuel oil (HFO) obtained from crude oil distillation is a widely used fuel in marine engines and power generation technologies. In the present study, the pyrolysis and combustion of a Saudi Arabian HFO in nitrogen and in air, respectively, were investigated using non-isothermal thermo-gravimetric analysis (TGA) coupled with a Fourier-transform infrared (FTIR) spectrometer. TG and DTG (differential thermo-gravimetry) were used for the kinetic analysis and to study the mass loss characteristics due to the thermal degradation of HFO at temperatures up to 1000°C and at various heating rates of 5, 10 and 20°C/min, in air and N2 atmospheres. FTIR analysis was then performed to study the composition of the evolved gases. The TG/DTG curves during HFO combustion show the presence of three distinct stages: the low temperature oxidation (LTO); fuel decomposition (FD); and high temperature oxidation (HTO) stages. The TG/DTG curves obtained during HFO pyrolysis show the presence of two devolatilization stages similar to that seen in the LTO stage of HFO combustion. Apart from this, the TG/DTG curves obtained during HFO combustion and pyrolysis differ significantly. Kinetic analysis was also performed using the distributed activation energy model, and the kinetic parameter (E) was determined for the different stages of HFO combustion and pyrolysis processes, yielding a good agreement with the measured TG profiles. FTIR analysis showed the signal of CO2 as approximately 50 times more compared to the other pollutant gases under combustion conditions. Under pyrolytic conditions, the signal intensity of alkane functional groups was the highest followed by alkenes. The TGA-FTIR results provide new insights into the overall HFO combustion processes, which can be used to improve combustor designs and control emissions.

  7. EXPERIMENTAL COMBUSTION ANALYSIS OF A HSDI DIESEL ENGINE FUELLED WITH PALM OIL BIODIESEL-DIESEL FUEL BLENDS

    Directory of Open Access Journals (Sweden)

    JOHN AGUDELO

    2009-01-01

    Full Text Available Differences in the chemical nature between petroleum diesel fuels and vegetable oils-based fuels lead to differences in their physical properties affecting the combustion process inside the engine. In this work a detailed combustion diagnosis was applied to a turbocharged automotive diesel engine operating with neat palm oil biodiesel (POB, No. 2 diesel fuel and their blends at 20 and 50% POB by volume (B20 and B50 respectively. To isolate the fuel effect, tests were executed at constant power output without carrying out any modification of the engine or its fuel injection system. As the POB content in the blend increased, there was a slight reduction in the fuel/air equivalence ratio from 0.39 (B0 to 0.37 (B100, an advance of injection timing and of start of combustion. Additionally, brake thermal efficiency, combustion duration, maximum mean temperature, temperature at exhaust valve opening and exhaust gas efficiency decreased; while the peak pressure, exergy destruction rate and specific fuel consumption increased. With diesel fuel and the blends B20 and B50 the same combustion stages were noticed. However, as a consequence of the differences pointed out, the thermal history of the process was affected. The diffusion combustion stage became larger with POB content. For B100 no premixed stage was observed.

  8. Cresco sai lahti võlast SASile ja osalusest Estonian Airis / Rivo Sarapik, Alyona Stadnik

    Index Scriptorium Estoniae

    Sarapik, Rivo, 1981-

    2010-01-01

    Majandus- ja kommunikatsiooniminister Juhan Parts ning SAS-i asepresident Benny Zakrisson kirjutasid alla Estonian Airi ostu-müügitehingule. Investeerimispank Cresco, millele kuulus 17% Estonian Airist, jääb välja Estonian Airi omanikeringist ning SAS-i nõue Crescole tühistatakse

  9. On the System of Place Name Signs in Estonian Sign Language

    Directory of Open Access Journals (Sweden)

    Liina Paales

    2011-05-01

    Full Text Available A place name sign is a linguistic-cultural marker that includes both memory and landscape. The author regards toponymic signs in Estonian Sign Language as representations of images held by the Estonian Deaf community: they reflect the geographical place, the period, the relationships of the Deaf community with hearing community, and the common and distinguishing features of the two cultures perceived by community's members. Name signs represent an element of signlore, which includes various types of creative linguistic play. There are stories hidden behind the place name signs that reveal the etymological origin of place name signs and reflect the community's memory. The purpose of this article is twofold. Firstly, it aims to introduce Estonian place name signs as Deaf signlore forms, analyse their structure and specify the main formation methods. Secondly, it interprets place-denoting signs in the light of understanding the foundations of Estonian Sign Language, Estonian Deaf education and education history, the traditions of local Deaf communities, and also of the cultural and local traditions of the dominant hearing communities. Both perspectives - linguistic and folkloristic - are represented in the current article.

  10. Seismic monitoring of in situ combustion process in a heavy oil field

    International Nuclear Information System (INIS)

    Zadeh, Hossein Mehdi; Srivastava, Ravi P; Vedanti, Nimisha; Landrø, Martin

    2010-01-01

    Three time-lapse 3D seismic surveys are analysed to monitor the effect of in situ combustion, a thermal-enhanced oil recovery process in the Balol heavy oil reservoir in India. The baseline data were acquired prior to the start of the in situ combustion process in four injection wells, while the two monitor surveys were acquired 1 and 2 years after injection start, respectively. We present the results of baseline and second monitor surveys. Fluid substitution studies based on acoustic well logs predict a seismic amplitude decrease at the top reservoir and an increase at the base reservoir. Both the amplitude dimming at the top reservoir and the brightening at the base reservoir are observed in the field data. The extent of the most pronounced 4D anomaly is estimated from the seismic amplitude and time shift analysis. The interesting result of seismic analysis is that the anomalies are laterally shifted towards the northwest, rather than the expected east, from the injector location suggesting a northwest movement of the in situ combustion front. No clear evidence of air leakage into other sand layers, neither above nor below the reservoir sand, is observed. This does not necessarily mean that all the injected air is following the reservoir sand, especially if the thief sand layers are thin. These layers might be difficult to observe on seismic data

  11. Acoustically damped metal oil trough for internal combustion engines. Schallgedaempfte Blech-Oelwanne fuer Brennkraftmaschinen

    Energy Technology Data Exchange (ETDEWEB)

    Kubis, H.

    1991-03-28

    The invention refers to an acoustically damped oil trough. As there are strict requirements for reducing the noise emission from internal combustion engines, according to the invention it is proposed that the oil trough should be surrounded by an outer trough, where the outer trough is made of plastic or sheet steel in one or more layers. To avoid noise bridges, the oil trough and outer trough are separated by elastomer elements. The outer trough achieves a reasonably priced increase in sound insulation. It is also possible to backfit an outer trough on engines.

  12. Proceedings of the Biomass Pyrolysis Oil Properties and Combustion Meeting, 26-28 September 1994, Estes Park, Colorado

    Energy Technology Data Exchange (ETDEWEB)

    Milne, T.

    1995-01-01

    The increasing scale-up of fast pyrolysis in North America and Europe, as well as the exploration and expansion of markets for the energy use of biocrude oils that now needs to take place, suggested that it was timely to convene an international meeting on the properties and combustion behavior of these oils. A common understanding of the state-of-the-art and technical and other challenges which need to be met during the commercialization of biocrude fuel use, can be achieved. The technical issues and understanding of combustion of these oils are rapidly being advanced through R&D in the United States. Canada, Europe and Scandinavia. It is obvious that for the maximum economic impact of biocrude, it will be necessary to have a common set of specifications so that oils can be used interchangeably with engines and combustors which require minimal modification to use these renewable fuels. Fundamental and applied studies being pursued in several countries are brought together in this workshop so that we can arrive at common strategies. In this way, both the science and the commercialization are advanced to the benefit of all, without detracting from the competitive development of both the technology and its applications. This United States-Canada-Finland collaboration has led to the two and one half day specialists meeting at which the technical basis for advances in biocrude development is discussed. The goal is to arrive at a common agenda on issues that cross national boundaries in this area. Examples of agenda items are combustion phenomena, the behavior of trace components of the oil (N, alkali metals), the formation of NOx in combustion, the need for common standards and environmental safety and health issues in the handling, storage and transportation of biocrudes.

  13. The atomization and the flame structure in the combustion of residual fuel oils; La atomizacion y estructura de flama en la combustion de combustibles residuales

    Energy Technology Data Exchange (ETDEWEB)

    Bolado Estandia, Ramon [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1986-12-31

    In this article a research on the combustion of heavy residual fuel oils is presented. The type of flames studied were obtained by means of the burning of sprays produced by an atomizer designed and calibrated specially for the research purpose. The flame characteristics that were analyzed are its length, its luminosity, the temperature, the distribution of the droplets size and mainly the burning regime of the droplets in the flame. The experimental techniques that were used for these studies were shadow micro-photography, suction pyrometry and of total radiation, laser diffraction, 35 mm photography, and impact push. The analysis of the experimental results, together with the results of the application of a mathematical model, permitted to establish two parameters, that quantitatively related determine the burning regime of the droplets in a flame of sprays of residual heavy fuel oil. [Espanol] En este articulo se presenta una investigacion sobre la combustion de combustibles residuales pesados. El tipo de flamas estudiadas se obtuvieron mediante el quemado de sprays producidos por un atomizador disenado y calibrado especialmente para el proposito de la investigacion. Las caracteristicas de flama que se analizaron son la longitud, la luminosidad, la temperatura, la distribucion de tamano de gotas y, principalmente, el regimen de quemado de gotas en la flama. Las tecnicas experimentales que se usaron para estos estudios fueron microfotografia de sombras, pirometria de succion y de radiacion total, difraccion laser, fotografia de 35 mm y empuje de impacto. El analisis de resultados experimentales, junto con los resultados de la aplicacion de un modelo matematico, permitio establecer dos parametros, que relacionados cuantitativamente, determinan el regimen de quemado de gotas en una flama de sprays de combustible residual pesado.

  14. The atomization and the flame structure in the combustion of residual fuel oils; La atomizacion y estructura de flama en la combustion de combustibles residuales

    Energy Technology Data Exchange (ETDEWEB)

    Bolado Estandia, Ramon [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1985-12-31

    In this article a research on the combustion of heavy residual fuel oils is presented. The type of flames studied were obtained by means of the burning of sprays produced by an atomizer designed and calibrated specially for the research purpose. The flame characteristics that were analyzed are its length, its luminosity, the temperature, the distribution of the droplets size and mainly the burning regime of the droplets in the flame. The experimental techniques that were used for these studies were shadow micro-photography, suction pyrometry and of total radiation, laser diffraction, 35 mm photography, and impact push. The analysis of the experimental results, together with the results of the application of a mathematical model, permitted to establish two parameters, that quantitatively related determine the burning regime of the droplets in a flame of sprays of residual heavy fuel oil. [Espanol] En este articulo se presenta una investigacion sobre la combustion de combustibles residuales pesados. El tipo de flamas estudiadas se obtuvieron mediante el quemado de sprays producidos por un atomizador disenado y calibrado especialmente para el proposito de la investigacion. Las caracteristicas de flama que se analizaron son la longitud, la luminosidad, la temperatura, la distribucion de tamano de gotas y, principalmente, el regimen de quemado de gotas en la flama. Las tecnicas experimentales que se usaron para estos estudios fueron microfotografia de sombras, pirometria de succion y de radiacion total, difraccion laser, fotografia de 35 mm y empuje de impacto. El analisis de resultados experimentales, junto con los resultados de la aplicacion de un modelo matematico, permitio establecer dos parametros, que relacionados cuantitativamente, determinan el regimen de quemado de gotas en una flama de sprays de combustible residual pesado.

  15. Thermogravimetric investigation of the co-combustion between the pyrolysis oil distillation residue and lignite.

    Science.gov (United States)

    Li, Hao; Xia, Shuqian; Ma, Peisheng

    2016-10-01

    Co-combustion of lignite with distillation residue derived from rice straw pyrolysis oil was investigated by non-isothermal thermogravimetric analysis (TGA). The addition of distillation residue improved the reactivity and combustion efficiency of lignite, such as increasing the weight loss rate at peak temperature and decreasing the burnout temperature and the total burnout. With increasing distillation residue content in the blended fuels, the synergistic interactions between distillation residue and lignite firstly increased and then decreased during co-combustion stage. Results of XRF, FTIR, (13)C NMR and SEM analysis indicated that chemical structure, mineral components and morphology of samples have great influence on the synergistic interactions. The combustion mechanisms and kinetic parameters were calculated by the Coats Redfern model, suggesting that the lowest apparent activation energy (120.19kJ/mol) for the blended fuels was obtained by blending 60wt.% distillation residue during main co-combustion stage. Copyright © 2016 Elsevier Ltd. All rights reserved.

  16. Developments in the technology for the combustion of water emulsions in Mexican fuel oil; Desarrollos en la tecnologia para la combustion de emulsiones agua en combustoleo mexicano

    Energy Technology Data Exchange (ETDEWEB)

    Diego, Antonio Marin; Martinez Flores, Marco A.; Tamayo Flores, Gustavo; Alarcon Quiroz, Ernesto; Melendez Cervantes, Carlos [Instituto de Investigaciones Electricas, Temixco, Morelos (Mexico)

    2001-07-01

    The residual petroleum oil (fuel oil) is the most used fuel in boilers of electrical and industrial power stations. Nevertheless, the use of this fuel can generate diverse problems such as the elevated particle emissions, that affect the boiler efficiency, darken the visibility by the smoke that leaves the chimneys and is emitted to the Environment. In addition, sulfur trioxide is produced, which reacts with the water present in the combustion gases, forming sulfuric acid that, when emitted, also affects the visibility of the plume and can be condensed, originating corrosion and increased accumulation of deposits in the boilers. The experimental research was made in a comparative base, between combustion tests of fuel oil, with emulsions where the water concentration and the size of the drops of this one was varied. A diagram of the supply of fuel and preparation of emulsions in a pilot furnace is shown. The article contains graphs of the effect of the water concentration of the emulsions in the particulate emission. The article contains figures of the cenospheres produced by the fuel oil combustion (500 x) and the ones produced by the combustion with 5% of water (500 x). Also shows graphs of the effect of the water drop size of emulsions in the particulate emission, of the reduction of the sulfur trioxide with soluble magnesium products in the water of emulsions, and of the free particle acidity with neutralizers of water emulsions of soluble magnesium. [Spanish] El aceite residual de petroleo (combustoleo) es el combustible mas utilizado en calderas de centrales electricas e industriales. Sin embargo, el uso de este combustible puede generar diverso problemas como las emisiones elevadas de particulas, que afectan la eficiencia de una caldera, obscurecen la visibilidad pero el humo que sale de las chimeneas y se emiten al medio ambiente. Ademas se produce trioxido de azufre, el cual reacciona con el vapor de agua presente en los gases de combustion, formado acido

  17. Microwave-induced combustion of crude oil for further rare earth elements determination by USN–ICP-MS

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, J.S.F. [Departamento de Química Inorgânica, Universidade Federal do Rio Grande do Sul, 97105-900 Porto Alegre, RS (Brazil); Pereira, L.S.F.; Mello, P.A. [Departamento de Química, Universidade Federal de Santa Maria, 97105-900 Santa Maria, RS (Brazil); Guimarães, R.C.L.; Guarnieri, R.A.; Fonseca, T.C.O. [CENPES/PETROBRAS, 21941-945 Rio de Janeiro, RJ (Brazil); Flores, E.M.M., E-mail: ericommf@gmail.com [Departamento de Química, Universidade Federal de Santa Maria, 97105-900 Santa Maria, RS (Brazil)

    2014-09-24

    Highlights: • Microwave-induced combustion was applied for light and heavy crude oils digestion. • It was feasible to determine all the REEs in heavy crude oil by ICP-MS. • Only diluted acid solutions were used in agreement to green chemistry recommendations. - Abstract: A procedure for light and heavy crude oils digestion by microwave-induced combustion (MIC) is proposed for the first time for further rare earth elements (REE) determination by inductively coupled plasma mass spectrometry (ICP-MS) equipped with an ultrasonic nebulizer (USN). Samples of crude oil (API density of 10.8–23.5, up to 250 mg) were inserted in polycarbonate capsules and combusted using 20 bar of oxygen and 50 μL of 6 mol L{sup −1} ammonium nitrate as igniter. Nitric acid solutions (1–14.4 mol L{sup −1}) were evaluated for analyte absorption and a reflux step was applied after combustion (5 min of microwave irradiation at 1400 W) in order to achieve better analyte recoveries. Accuracy was evaluated using a spiked sample and also by comparison of results obtained by microwave-assisted digestion combined to ultraviolet radiation (MW–UV) and by neutron activation analysis (NAA). Using 3 mol L{sup −1} HNO{sub 3}, quantitative recoveries (better than 97%) were obtained for all analytes. Blank values were always negligible. Agreement was higher than 96% for La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and Y by comparison of results with those obtained by MW–UV and by NAA (only for La, Ce, Nd, Sm, and Yb). Residual carbon content in digests using MIC was always below 1%. As an advantage over conventional procedures for crude oil digestion, using MIC, it was possible to use diluted acid as absorbing solution, obtaining better limits of detection and avoiding interferences in REE determination by USN–ICP-MS.

  18. Combustion characteristics of Malaysian oil palm biomass, sub-bituminous coal and their respective blends via thermogravimetric analysis (TGA).

    Science.gov (United States)

    Idris, Siti Shawalliah; Rahman, Norazah Abd; Ismail, Khudzir

    2012-11-01

    The combustion characteristics of Malaysia oil palm biomass (palm kernel shell (PKS), palm mesocarp fibre (PMF) and empty fruit bunches (EFB)), sub-bituminous coal (Mukah Balingian) and coal/biomass blends via thermogravimetric analysis (TGA) were investigated. Six weight ratios of coal/biomass blends were prepared and oxidised under dynamic conditions from temperature 25 to 1100°C at four heating rates. The thermogravimetric analysis demonstrated that the EFB and PKS evolved additional peak besides drying, devolatilisation and char oxidation steps during combustion. Ignition and burn out temperatures of blends were improved in comparison to coal. No interactions were observed between the coal and biomass during combustion. The apparent activation energy during this process was evaluated using iso-conversional model free kinetics which resulted in highest activation energy during combustion of PKS followed by PMF, EFB and MB coal. Blending oil palm biomass with coal reduces the apparent activation energy value. Copyright © 2012 Elsevier Ltd. All rights reserved.

  19. The Representation of the Cold War in Three Estonian History Textbooks

    Science.gov (United States)

    Korbits, Keit

    2015-01-01

    The article looks at the discursive strategies different Estonian history textbooks employ to represent the Cold War period, and the "commonsense" ideologies instilled through these representations. The textbooks analysed include two history books dating back to the Estonian Soviet Socialist Republic and, for contrast, one written during…

  20. Analysis of the Effect of Injection Pressure on Ignition Delay and Combustion Process of Biodiesel from Palm Oil, Algae and Waste Cooking Oil

    Science.gov (United States)

    Irham Anas, Mohd; Khalid, Amir; Hakim Zulkifli, Fathul; Jaat, Norrizam; Faisal Hushim, Mohd; Manshoor, Bukhari; Zaman, Izzuddin

    2017-10-01

    Biodiesel is a domestically produced, renewable fuel that can be manufactured from vegetable oils, animal fats, or recycled restaurant grease for use in diesel engines. The objective of this research is investigation the effects of the variant injection pressure on ignition delay and emission for different biodiesel using rapid compression machine. Rapid Compression Machine (RCM) is used to simulate a single compression stroke of an internal combustion engine as a real engine. Four types of biodiesel which are waste cooking oil, crude palm oil, algae and jatropha were tested at injection pressure of 80 MPa, 90 MPa and 130 MPa under constant ambient temperature at 950 K. Increased in injection pressure resulted shorter ignition delay proven by WCO5 which decreased from 1.3 ms at 80 MPa to 0.7 ms at 130 MPa. Meanwhile, emission for CO2 increased due to better fuel atomization for fuel-air mixture formation lead to completed combustion.

  1. Estonian Language of Technology as a Factor Supporting the Evolution of Engineering Thinking

    Directory of Open Access Journals (Sweden)

    Mägi, Vahur

    2013-03-01

    Full Text Available Casual mention of teaching technology subjects in Estonian schools dates back several centuries. Navigation and construction were amongthe earliest professional skills that were taught. As both of them required mathematical thinking skills, teaching the subjects was usually accompanied by explaining the principles of mathematics. The first technology book in Estonian was published about two centuries ago and it dealed with geodesy. The earliest Estonian glossaries of technological terminology were published in the fields of physics and chemistry. The rise of Estonian as a language of higher education and science in the country came about in the 1920s and 1930s. Faculty members of the Tallinn School of Technology then published the first textbooks composed in the Estonian language for students of technology. The Estonian Society for Technology and the Estonian Association of Engineers became seriously involved in linguistic activities. Together with the Vocational Teachers’ Assembly of Tartu they published an illustrated technology glossary for machinery and tools terms. It was followed by a glossary of construction and building terms, compiled under the lead of the University of Technology. In addition, journals of technology introducedinnovations in the lexicon of technology to the general public. The postwar period in the development of the lexicon of technical terms was of little significance at first. A surge in language creativity could be detected in the 1960s, when terminology became a target of constantly growing attention to the development of technology lexicon. Series of technology glossaries were published. This tendency has continued to this day.

  2. TEM and HRTEM of Soot-in-oil particles and agglomerates from internal combustion engines

    International Nuclear Information System (INIS)

    Fay, M W; Rocca, A La; Shayler, P J

    2014-01-01

    Over time, the performance of lubricating oil in a diesel engine is affected by the build-up of carbon soot produced by the combustion process. TEM and HRTEM are commonly used to investigate the characteristics of individual and agglomerated particles from diesel exhaust, to understand the structure and distribution of the carbon sheets in the primary particles and the nanostructure morphology. However, high resolution imaging of soot-in-oil is more challenging, as mineral oil is a contaminant for the electron microscope and leads to instability under the electron beam. In this work we compare solvent extraction and centrifugation techniques for removing the mineral oil contaminant, and the effect on particle size distribution

  3. Hydrogenation of Estonian oil shale and shale oil

    Energy Technology Data Exchange (ETDEWEB)

    Kogerman, P N; Kopwillem, J

    1932-01-01

    Kukersite was heated in an atmosphere of hydrogen, nitrogen, or water in three series of experiments. Shale samples were heated at 370/sup 0/ to 410/sup 0/C for 2 to 3/sup 1///sub 2/ hours in the presence of 106 to 287 kg/sq cm pressure of water, nitrogen, or hydrogen. In some experiments 5 percent of iron oxide was added to the shale. The amount of kerogen liquefied by hydrogenation was not greater than the amount of liquid products obtained by ordinary distillation. On hydrogenation, kukersite absorbed 1.8 weight-percent of hydrogen. Almost no hydrogenation took place below the decomposition point of kerogen, and the lighter decomposition products were mainly hydrogenated. Hydrogenation of the shale prevented coke formation. Heating kukersite or its crude oil at temperatures of 400/sup 0/ to 410/sup 0/C under 250 kg/sq cm hydrogen pressure produced paraffinic and naphthenic oils of lower boiling points. At higher temperatures and after long-continued heating, the formation of aromatic hydrocarbons was observed.

  4. Estonian Tax Structure

    Directory of Open Access Journals (Sweden)

    Viktor Trasberg

    2014-08-01

    Full Text Available The paper analyses Estonian tax structure changes during the last decade and critically assesses the current situation. The country’s tax mix is rather unique among EU countries – it has one of the highest proportions of consumption taxes in total taxes and the lowest level of capital and profit taxes. Such an unbalanced tax structure creates risks for public finances, limits revenue collection and distorts the business environment.

  5. Estonian Golf & Country Club / Urmas Oja

    Index Scriptorium Estoniae

    Oja, Urmas, 1981-2012

    2005-01-01

    Konkursil "Eesti parim puitehitis 2005" pälvis voodrilaua eripreemia Jõelähtme Estonian Golf & Country Club'i katus. Arhitekt Andres Siim. Sisearhitekt Juta Lember. Konstruktor: AS Resand. 11 värv. ill

  6. Power without manpower: Forecasting labour demand for Estonian energy sector

    International Nuclear Information System (INIS)

    Meriküll, Jaanika; Eamets, Raul; Humal, Katrin; Espenberg, Kerly

    2012-01-01

    As energy demand and prices continue to grow, oil shale might help mitigate the energy crisis—it can widely be found all over the world but so far has not been widely used. Estonia is unique in the world for producing a large majority of energy out of oil shale and has been set as an example in numerous papers covering oil shale deposits, technology etc. This paper is the first to analyse oil shale energy related workforce and provides scenario forecasts of the labour demand for the Estonian energy sector in 2010–2020. The contribution of the paper is twofold. First, the paper provides a valuable insight into oil shale energy related workforce, enabling to take into consideration the educational needs in countries where oil shale industry might be set up. Second, methodology-wise, the paper relates labour demand and supply to different scenarios of energy production capacities. The results illustrate problems related to aging of the workforce in energy production. If the existing trends continue in educational attainment in Estonia, there will be a serious shortage of high-skilled engineering and manufacturing specialists. Our method provides a simple yet reliable enough way to check for such problems early enough. - Highlights: ► This paper analyses oil shale energy related workforce and provides scenario forecasts. ► This is the first study to investigate the workforce related to oil shale energy production. ► The main workforce-related problem in the sector is ageing of the workforce. ► Workers immigrating to the sector during the Soviet times are at the retirement age. ► There will be a serious shortage of engineers for energy sector in the near future.

  7. Estonian Air / Kirsti Vainküla

    Index Scriptorium Estoniae

    Vainküla, Kirsti, 1972-

    2004-01-01

    Estonian Air reklaamib end Taani linna Aalborgi raadiojaama ilmateates. Lennukompanii pressiesindaja Epp Alatalu sõnul on firma Taanis reklaamimise põhjus see, et liinil Tallinn-Kopenhaagen sõitjate hulgas ei ole peaaegu üldse taanlasi

  8. Noor eesti teater ja Noor-Eesti. Young Estonian Theatre and Young Estonia

    Directory of Open Access Journals (Sweden)

    Katri Aaslav-Tepandi

    2012-04-01

    Full Text Available This article begins by examining points of intersection between two professional theatres, ”Estonia” and ”Vanemuine” (both established in 1906, their young directors – Karl Menning, Paul Pinna, Theodor Altermann, and Karl Jungholz, and the literary movement Young Estonia. Subsequently, we will consider Young Estonia’s theatrical ideals and the influence of these ideas on later Estonian theatrical life. Since not much information has survived regarding direct personal contacts between ”movers and shakers” in the theatre world and Young Estonians, the main focus here shall be on indirect creative connections and influences. One such context is education: like the Young Estonians, theatre activists of the younger generation aspired to place themselves on the larger map of European culture. Thus, their artistic beliefs and goals shall be examined in relation to those of Young Estonians’ quest for modern culture. Pinna, Altermann, Menning, Jungholz, and others went on study tours to Germany and France, where they were energized and inspired by innovative German and Russian theatres, by naturalistic staging, and by psychological realism, both in acting and in performance style. Among their models were A. Antoine’s Théâtre- Libre in Paris, K. Stanislavski’s Art Theatre in Moscow, O. Brahm’s Lessing-Theater, and M. Reinhardt’s Deutsches Theater in Berlin. These models were likewise known to the Young Estonians, but if theatre activists oriented themselves more fundamentally to German naturalist and realist dramatic art, Young Estonians were more taken with ”theatrical theatre” with its symbolist and impressionist influences. The Young Estonians attended performances at both theatres, ”Vanemuine” and ”Estonia”, and wrote numerous theatre reviews. Yet in the Young Estonia albums (yearbooks and in the magazine Young Estonia, theatre topics have a relatively modest representation. Young Estonians did not have direct

  9. Influence of distillation on performance, emission, and combustion of a DI diesel engine, using tyre pyrolysis oil diesel blends

    Directory of Open Access Journals (Sweden)

    Murugan Sivalingam

    2008-01-01

    Full Text Available Conversion of waste to energy is one of the recent trends in minimizing not only the waste disposal but also could be used as an alternate fuel for internal combustion engines. Fuels like wood pyrolysis oil, rubber pyrolysis oil are also derived through waste to energy conversion method. Early investigations report that tyre pyrolysis oil derived from vacuum pyrolysis method seemed to possess properties similar to diesel fuel. In the present work, the crude tyre pyrolisis oil was desulphurised and distilled to improve the properties and studied the use of it. Experimental studies were conducted on a single cylinder four-stroke air cooled engine fuelled with two different blends, 30% tyre pyrolysis oil and 70% diesel fuel (TPO 30 and 30% distilled tyre pyrolysis oil and 70% diesel fuel (DTPO 30. The results of the performance, emission and combustion characteristics of the engine indicated that NOx is reduced by about 8% compared to tire pyrolysis oil and by about 10% compared to diesel fuel. Hydrocarbon emission is reduced by about 2% compared to TPO 30 operation. Smoke increased for DTPO 30 compared to TPO 30 and diesel fuel.

  10. Liberalism - Key to Entrepreneurial and Innovation Success: Estonian Case Study

    Directory of Open Access Journals (Sweden)

    Augustin Ignatov

    2017-12-01

    Full Text Available Since its independence in 1991 Estonia has successfully overpassed the challenges of the transition period being in the present of one the most technologically developed nations of Europe. The present research is intended to evaluate the relationship between Estonian pro-market regulation, entrepreneurship and innovation. In order to reach relevant conclusions in this regard there have been used both qualitative and quantitative methods of analysis. In such a way, it could be comprehensively reviewed the process of Estonian economic development from a relatively underdeveloped USSR republic to an advanced innovation driven economy. The results show that pro-market governmental regulation has favourably influenced Estonian entrepreneurship, while it fostered country’s innovation capacities. It has been concluded that the economic “miracle” of Estonia has been at a great extent determined by proper government regulation oriented towards economic liberalisation.

  11. Dynamic Oil Consumption Measurement of Internal Combustion Engines using Laser Spectroscopy.

    Science.gov (United States)

    Sellmeier, Stefan; Alonso, Eduardo; Boesl, Ulrich

    2014-01-07

    A new approach has been developed to measure dynamic consumption of lubricant oil in an internal combustion engine. It is based on the already known technique where sulfur is used as a natural tracer of the engine oil. Since ejection of motor oil in gaseous form into the exhaust is by far the main source of engine oil consumption, detection of sulfur in the exhaust emission is a valuable way to measure engine oil consumption in a dynamic way. In earlier approaches, this is done by converting all sulfur containing chemical components into SO2 by thermal pyrolysis in a high temperature furnace at atmospheric pressure. The so-formed SO2 then is detected by broadband-UV-induced fluorescence or mass spectrometric methods. The challenge is to reach the necessary detection limit of 50 ppb. The new approach presented here includes sulfur conversion in a low-pressure discharge cell and laser-induced fluorescence with wavelength and fluorescence lifetime selection. A limit of detection down to 10 ppb at a temporal resolution in the time scale of few seconds is reached. Extensive, promising studies have been performed at a real engine test bench. Future developments of a compact, mobile device based on these improvements are discussed.

  12. Combustion, emission and engine performance characteristics of used cooking oil biodiesel - A review

    Energy Technology Data Exchange (ETDEWEB)

    Enweremadu, C.C. [Department of Mechanical Engineering, Vaal University of Technology, Private Bag X021, Vanderbijlpark 1900 (South Africa); Rutto, H.L. [Department of Chemical Engineering, Vaal University of Technology, Private Bag X021, Vanderbijlpark 1900 (South Africa)

    2010-12-15

    As the environment degrades at an alarming rate, there have been steady calls by most governments following international energy policies for the use of biofuels. One of the biofuels whose use is rapidly expanding is biodiesel. One of the economical sources for biodiesel production which doubles in the reduction of liquid waste and the subsequent burden of sewage treatment is used cooking oil (UCO). However, the products formed during frying, such as free fatty acid and some polymerized triglycerides, can affect the transesterification reaction and the biodiesel properties. This paper attempts to collect and analyze published works mainly in scientific journals about the engine performance, combustion and emissions characteristics of UCO biodiesel on diesel engine. Overall, the engine performance of the UCO biodiesel and its blends was only marginally poorer compared to diesel. From the standpoint of emissions, NOx emissions were slightly higher while un-burnt hydrocarbon (UBHC) emissions were lower for UCO biodiesel when compares to diesel fuel. There were no noticeable differences between UCO biodiesel and fresh oil biodiesel as their engine performances, combustion and emissions characteristics bear a close resemblance. This is probably more closely related to the oxygenated nature of biodiesel which is almost constant for every biodiesel (biodiesel has some level of oxygen bound to its chemical structure) and also to its higher viscosity and lower calorific value, which have a major bearing on spray formation and initial combustion. (author)

  13. Efficiency of Estonian grain farms in 2000 2004

    Directory of Open Access Journals (Sweden)

    N. VASILIEV

    2008-12-01

    Full Text Available The aim of this study is to analyse the efficiency of Estonian grain farms after Estonia’s transition to a market economy and during the accession period to the European Union (EU. The non-parametric method Data Envelopment Analysis (DEA was used to estimate the total technical, pure technical and scale efficiency of Estonian grain farms in 2000–2004. Mean total technical efficiency varied from 0.70 to 0.78. Of the grain farms 62% are operating under increasing returns to scale. Solely based on the DEA model it is not possible to determine optimum farm scale and the range of Estonian farm sizes operating efficiently is extensive. The most pure technically efficient farms were the smallest and the largest but the productivity of small farms is low compared to larger farms because of their small scale. Therefore, they are the least competitive. Since pre-accession period to the EU, large input slacks of capital have replaced the former excessive use of labour and land. This raises the question about the effects on efficiency of the EU’s investment support schemes in new member states.;

  14. The Category of Time in Fairy Tales: Searching for Folk Calendar Time in the Estonian Fairy Tale Corpus

    Directory of Open Access Journals (Sweden)

    Mairi Kaasik

    2011-03-01

    Full Text Available The article examines how folk calendar holidays are represented in Estonian fairy tales. It introduces some views presented in folklore studies about the concept of time in fairy tales and finds parallels with them in the Estonian context. The analysis relies on the digital corpus of Estonian fairy tales (5400 variants, created from the texts found in the Estonian Folklore Archives by the Fairy Tale Project of the Department of Estonian and Comparative Folklore, University of Tartu. Folk calendar holidays occur in Estonian fairy tales relatively seldom; most often these are holidays that occupy a significant place in the Estonian folk calendar (Christmas, St. John’s Day, Easter, St. George’s Day. Calendar holidays are notably mentioned more often in tale types which remain on the borderline between the fairy tale and the legend or the fairy tale and the religious tale. In Estonian fairy tales, calendar holidays are used on three levels of meaning: (1 the holiday is organically associated with the tale type; it has an essential role in the plot of the tale; (2 to a certain extent, the holiday could be replaced by another holiday having an analogous meaning; (3 the holiday forms an unimportant or occasional addition to the tale.

  15. Olev Schults : SAS vajab Estonian Airi rahvusliku lennufirmana / Olev Schults ; interv. Andres Reimer

    Index Scriptorium Estoniae

    Schults, Olev

    2008-01-01

    Estonian Airi nõukogu esimees vastab küsimustele, kas SAS arendas Läti airBalticut Estonian SAS-i arvel, mis mõte on rahvuslikul lennukompaniil, kui riik ei tohi seda finantseerida, kuidas mõjutab investorite meeleolu SAS-i Eestis tabanud poliitikute kriitika tulv

  16. Experimental study on fuel oil combustion in circulating fluidized bed; Estudio experimental sobre la combustion de combustoleo en lecho fluidizado circulante

    Energy Technology Data Exchange (ETDEWEB)

    Diaz Rangel, Ricardo [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1996-12-31

    The Instituto de Investigaciones Electricas (IIE) developed a circulating fluidized bed combustor of 0.5 thermal MW unique in its type in Latin America. The Bachelor`s thesis entitled ``Experimental Study on Fuel Oil Combustion in Circulating Fluidized Bed`` was performed operating this combustor with the purpose of determining the feasibility of burning heavy fuel oil in a stable and sustained form, as well as the effect of the addition of calcium carbonate to the combustor. The results of the experimental trials showed heavy fuel oil can be burned in a circulating fluidized bed, with low sulfur dioxide emissions. During the conduction of the experiments a sulfur retention of 43% was achieved with a Ca/S relationship of 4.5. [Espanol] El Instituto de Investigaciones Electricas (IIE) desarrollo un combustor de lecho fluidizado circulante de 0.5 MW termicos de potencia, unico en su tipo en Latinoamerica. La tesis de licenciatura titulada Estudio Experimental sobre la Combustion de Combustoleo en Lecho Fluidizado Circulante se realizo operando dicho combustor, con el proposito de determinar la factibilidad de quemar combustoleo pesado en forma estable y autosostenida, asi como la influencia que tiene la adicion de carbonato de calcio al lecho. Los resultados de los ensayos experimentales mostraron que se puede quemar combustoleo pesado en un lecho fluidizado circulante, con bajas emisiones de bioxido de azufre. Durante la experimentacion se logro una retencion de azufre del 43%, con una relacion Ca/S de 4.5.

  17. Experimental study on fuel oil combustion in circulating fluidized bed; Estudio experimental sobre la combustion de combustoleo en lecho fluidizado circulante

    Energy Technology Data Exchange (ETDEWEB)

    Diaz Rangel, Ricardo [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1997-12-31

    The Instituto de Investigaciones Electricas (IIE) developed a circulating fluidized bed combustor of 0.5 thermal MW unique in its type in Latin America. The Bachelor`s thesis entitled ``Experimental Study on Fuel Oil Combustion in Circulating Fluidized Bed`` was performed operating this combustor with the purpose of determining the feasibility of burning heavy fuel oil in a stable and sustained form, as well as the effect of the addition of calcium carbonate to the combustor. The results of the experimental trials showed heavy fuel oil can be burned in a circulating fluidized bed, with low sulfur dioxide emissions. During the conduction of the experiments a sulfur retention of 43% was achieved with a Ca/S relationship of 4.5. [Espanol] El Instituto de Investigaciones Electricas (IIE) desarrollo un combustor de lecho fluidizado circulante de 0.5 MW termicos de potencia, unico en su tipo en Latinoamerica. La tesis de licenciatura titulada Estudio Experimental sobre la Combustion de Combustoleo en Lecho Fluidizado Circulante se realizo operando dicho combustor, con el proposito de determinar la factibilidad de quemar combustoleo pesado en forma estable y autosostenida, asi como la influencia que tiene la adicion de carbonato de calcio al lecho. Los resultados de los ensayos experimentales mostraron que se puede quemar combustoleo pesado en un lecho fluidizado circulante, con bajas emisiones de bioxido de azufre. Durante la experimentacion se logro una retencion de azufre del 43%, con una relacion Ca/S de 4.5.

  18. Production of oil from Israeli oil shale

    International Nuclear Information System (INIS)

    Givoni, D.

    1993-01-01

    Oil shale can be utilized in two-ways: direct combustion to generate steam and power or retorting to produce oil or gas. PAMA has been developing both direct combustion and retorting processes. Its main effort is in the combustion. An oil shale fired steam boiler was erected in the Rotem industrial complex for demonstration purposes. PAMA has also been looking into two alternative retorting concepts - slow heating of coarse particles and fast heating of fine particles. The present paper provides operating data of oil shale processing in the following scheme: (a) retorting in moving bed, pilot and bench scale units, and (b) retorting in a fluidized bed, bench scale units. (author)

  19. Estonian Air to overhaul strategy / Matt Withers

    Index Scriptorium Estoniae

    Withers, Matt

    2008-01-01

    Estonian Air on majanduslikes raskustes, mida aitaks leevendada riigipoolne toetus. Majandus- ja kommunikatsiooniminister Juhan Parts leiab, et riik peaks omama lennufirma juhatuses esimehe kohta, et mõjutada rohkem vastuvõetavaid otsuseid ja investeeringuid

  20. Combustion and emission characteristics of diesel engine fueled with diesel-like fuel from waste lubrication oil

    International Nuclear Information System (INIS)

    Wang, Xiangli; Ni, Peiyong

    2017-01-01

    Highlights: • 100% diesel-like fuel from waste lubricating oil was conducted in a diesel engine. • Good combustion and fuel economy are achieved without engine modifications. • Combustion duration of DLF is shorter than diesel. • NOx and smoke emissions with the DLF are slightly higher than pure diesel. - Abstract: Waste lubricant oil (WLO) is one of the most important types of the energy sources. WLO cannot be burned directly in diesel engines, but can be processed to be used as diesel-like fuel (DLF) to minimize its harmful effect and maximize its useful values. Moreover, there are some differences in physicochemical properties between WLO and diesel fuel. In order to identify the differences in combustion and emission performance of diesel engine fueled with the two fuels, a bench test of a single-cylinder direct injection diesel engine without any engine modification was investigated at four engine speeds and five engine loads. The effects of the fuels on fuel economic performance, combustion characteristics, and emissions of hydrocarbons (HC), carbon monoxide (CO), nitrogen oxides (NOx) and smoke were discussed. The DLF exhibits longer ignition delay period and shorter combustion duration than diesel fuel. The test results indicate that the higher distillation temperatures of the DLF attribute to the increase of combustion pressure, temperature and heat release rate. The brake specific fuel consumption (BSFC) of the DLF compared to diesel is reduced by about 3% at 3000 rpm under light and medium loads. The DLF produces slightly higher NOx emissions at middle and heavy loads, somewhat more smoke emissions at middle loads, and notably higher HC and CO emissions at most measured points than diesel fuel. It is concluded that the DLF can be used as potential available fuel in high-speed diesel engines without any problems.

  1. Resource and utilization of Estonian hydropower

    International Nuclear Information System (INIS)

    Raesaar, P.

    2005-01-01

    An overview of the Estonian hydropower resources and their utilization at present as well as prospective for the future are presented in this paper. A short overview of advantages of small hydropower stations and related issues is given. Some technological aspects are treated briefly. (authors)

  2. Combustion of municipal solid wastes with oil shale in a circulating fluidized bed. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-06-30

    The problem addressed by our invention is that of municipal solid waste utilization. The dimensions of the problem can be visualized by the common comparison that the average individual in America creates in five years time an amount of solid waste equivalent in weight to the Statue of Liberty. The combustible portion of the more than 11 billion tons of solid waste (including municipal solid waste) produced in the United States each year, if converted into useful energy, could provide 32 quads per year of badly needed domestic energy, or more than one-third of our annual energy consumption. Conversion efficiency and many other factors make such a production level unrealistic, but it is clear that we are dealing with a very significant potential resource. This report describes research pertaining to the co-combustion of oil shale with solid municipal wastes in a circulating fluidized bed. The oil shale adds significant fuel content and also constituents that can possible produce a useful cementitious ash.

  3. Revisiting the Estonian Cyber Attacks: Digital Threats and Multinational Responses

    Directory of Open Access Journals (Sweden)

    Stephen Herzog

    2011-01-01

    Full Text Available In April 2007, the Estonian Government moved a memorial commemorating the Soviet liberation of the country from the Nazis to a less prominent and visible location in Tallinn. This decision triggered rioting among Russian-speaking minorities and cyber terrorism targeting Estonia's critical economic and political infrastructure. Drawing upon the Estonian cyber attacks, this article argues that globalization and the Internet have enabled transnational groups—such as the Russian diaspora—to avenge their grievances by threatening the sovereignty of nation-states in cyberspace. Sophisticated and virtually untraceable political "hacktivists" may now possess the ability to disrupt or destroy government operations, banking transactions, city power grids, and even military weapon systems. Fortunately, western countries banded together to effectively combat the Estonian cyber attacks and minimize their effects. However, this article concludes that in the age of globalization, interdependence, and digital interconnectedness, nation-states must engage in increased cooperative cyber-defense activities to counter and prevent devastating Internet attacks and their implications.

  4. Utilisation of VOC in Diesel Engines. Ignition and combustion of VOC released in crude oil tankers

    International Nuclear Information System (INIS)

    Melhus, Oeyvin

    2002-01-01

    The emission of VOC (Volatile Organic Compound) is a significant source of hydrocarbon pollution. In Norway, the offshore oil industry represents a major source. This emission represents both an energy loss and an environmental problem. Gas tankers have used boil-off gas from the cargo tanks as fuel for some time. However, for the current VOC project a new fuel injection concept is designed for tankers to take advantage of the energy present in the VOC evaporated from crude oil. The VOC is mixed with inert gas in these tankers, and thus the utilisation of this gas represents new challenges. The VOC project uses the concept of ''Condensate Diesel Process'' with pilot ignition. An experimental study of ignition and combustion of VOC Fuels reported here was initiated by the time it was decided to start a pilot project converting propulsion engines in shuttle tankers to use VOC Fuel. It is an experimental study carried out at the Marine Technology Centre (MTS). The objective was to study ignition and combustion of the chosen process in comparison with an ordinary diesel process. The experimental results have been discussed and compared with theoretical considerations of injection, ignition and combustion. For experiments on combustion, a rapid compression machine ''DyFo'' was redesigned to use VOC Fuel. The DyFo test rig was initially designed to study ignition and early combustion of spark ignited homogeneous gas/air charges. To study the ignition and early combustion of VOC Fuel injected at high pressure and ignited by pilot diesel fuel, a redesign was necessary. An important feature of the DyFo, is the visualisation of the combustion. The advantage of the DyFo test rig over an engine, is its simplicity and controllability. In an engine the visualisation would suffer from combustion deposits disturbing the view through the quartz glasses, making the images more difficult to interpret. The simplicity is on the other side a drawback. Correct thermal conditions inside

  5. Compiling the Dictionary of Word Associations in Estonian: From scratch to the database

    Directory of Open Access Journals (Sweden)

    Ene Vainik

    2018-04-01

    Full Text Available The present paper describes the project titled “The Dictionary of Word Associations in Estonian” undertaken by the author at the Institute of the Estonian Language. The general aim of the Dictionary is to provide insights into Estonians’ common-sense mind. It is meant to be a tool of self-reflection for Estonian native speakers and a guide for the foreigners who are eager enough to make themselves familiar with the Estonian cultural patterns of thought. The Dictionary will be published online. The number of keywords was initially limited to approximately 800. Specific emphasis is given to the stage of data collection by implementing the principles of citizen science.

  6. Valued Estonian Music CDs / Igor Garshnek

    Index Scriptorium Estoniae

    Garšnek, Igor, 1958-

    2003-01-01

    2002. aastal välja antud eesti muusika heliplaatidest Arvo Pärt "Summa", Lepo Sumera "Chamber Music", "Baltic Voices 1.", "Sequenzen - Europäische Orgelmusik des 20. Jahrhundrets mit...", "El silenco ئ Silence. Kuldar and Marje Sink. Songs of Mother and Son", "Riho Sibul. Estonian Dream Big Band", "Rull's Royce ئ Rull's Choice"

  7. Modélisation de la combustion de fuels lourds prenant en compte la dispersion des asphaltènes Modeling Heavy Fuel-Oil Combustion (While Considering Or Including Asphaltene Dispersion

    Directory of Open Access Journals (Sweden)

    Audibert F.

    2006-11-01

    Full Text Available Divers modèles, ayant pour but de prédire le taux d'imbrûlés solides lors de la combustion du fuel lourd, ont été mis au point dans le passé. Les paramètres entrant en ligne de compte sont le plus souvent les teneurs en résidus lourds hydrocarbonés (asphaltènes précipités au pentane ou à l'heptane et carbone Conradson et en métaux : c'est le cas des modèles Exxon et Shell développés respectivement en 1979 et 1981. D'autres modèles tiennent compte, en plus de la composition du fuel, de son mode d'atomisation, de son mode de diffusion dans le foyer et de la cinétique de combustion : on peut citer les travaux du Laboratoire Energie du MIT publiés en 1986. Néanmoins, ces facteurs ne sont pas les seuls à intervenir : l'expérience a montré que l'état de dispersion des asphaltènes peut jouer également un grand rôle, notamment dans le cas d'installations de combustion à injection mécanique, pour lesquelles la dispersion des gouttelettes n'est pas aussi fine que pour des installations munies d'une injection assistée par la vapeur. Cette influence de la dispersion des asphaltènes sur la combustion a été mise en évidence dans le passé par l'utilisation d'additifs dispersants et également par la combustion de fuels lourds constitués par dilution d'asphaltes précipités au pentane avec un gas-oil de cracking catalytique de raffinerie (LCO. Ce sont ces fuels que l'on a considérés dans la présente étude. L'effet de ce facteur dispersion n'a pas été quantifié jusqu'alors, la difficulté étant de définir une grandeur mesurable représentant la répartition des agglomérats d'asphaltènes. Dans cette étude, on a essayé en un premier temps de faire une approche fractale de la répartition des asphaltènes à partir de clichés (préparés par la société Total, cette méthode ayant déjà été utilisée avec succès pour décrire des structures d'aspects comparables. Malheureusement, on s'est heurté à des

  8. COMBUSTION ANALYSIS OF ALGAL OIL METHYL ESTER IN A DIRECT INJECTION COMPRESSION IGNITION ENGINE

    Directory of Open Access Journals (Sweden)

    HARIRAM V.

    2013-02-01

    Full Text Available Algal oil methyl ester was derived from microalgae (Spirulina sp. The microalga was cultivated in BG 11 media composition in a photobioreactor. Upon harvesting, the biomass was filtered and dried. The algal oil was obtained by a two step solvent extraction method using hexane and ether solvent. Cyclohexane was added to biomass to expel the remaining algal oil. By this method 92% of algal oil is obtained. Transesterification process was carried out to produce AOME by adding sodium hydroxide and methanol. The AOME was blended with straight diesel in 5%, 10% and 15% blend ratio. Combustion parameters were analyzed on a Kirloskar single cylinder direct injection compression ignition engine. The cylinder pressure characteristics, the rate of pressure rise, heat release analysis, performance and emissions were studied for straight diesel and the blends of AOME’s. AOME 15% blend exhibits significant variation in cylinder pressure and rate of heat release.

  9. Estonian Air püüdis viimase hetkeni Top Toursi päästa / Mirko Ojakivi

    Index Scriptorium Estoniae

    Ojakivi, Mirko

    2010-01-01

    Estonian Air kaalus Top Toursile appiminekut, sest reisifirma oli Estonian Airil üks olulisemaid koostööpartnereid. Abi oleks puudutanud ennekõike uutele lendudele allahindluse tegemist, räägiti ka võimalikust krediidist

  10. Jäätmetega kimpus Estonian Cell annab muda põldudele kompostiks / Ulvar Käärt

    Index Scriptorium Estoniae

    Käärt, Ulvar, 1982-

    2007-01-01

    Kundas asuv Estonian Celli tehas jagab ümberkaudsetele talunikele jäätmetest lahtisaamiseks kompostimissegu. Seadused ei sätesta, kuidas Estonian Cellis tekkivaid jäätmeid töödelda. Kommenteerib Peeter Eek: Aasta läbi ei saa muda põllule viia

  11. Combustion of crude oil sludge containing naturally occurring radioactive material

    International Nuclear Information System (INIS)

    Mohamad Puad Abu; Muhd Noor Muhd Yunus; Shamsuddin, A.H.; Sopian, K.

    2000-01-01

    The characteristics of crude oil sludge fi-om the crude oil terminal are very unique because it contains both heavy metals and also Naturally Occurring Radioactive Material (NORM). As a result, the Department of Environmental (DOE) and the Atomic Energy Licensing Board (AELB) considered it as Scheduled Wastes and Low Level Radioactive Waste (LLRW) respectively. As a Scheduled Wastes, there is no problem in dealing with the disposal of it since there already exist a National Center in Bukit Nanas to deal with this type of waste. However, the Center could not manage this waste due to the presence of NORM by which the policy regarding the disposal of this kind of waste has not been well established. This situation is unclear to certain parties, especially with respect to the relevant authorities having final jurisdiction over the issue as well as the best practical method of disposal of this kind of waste. Existing methods of treatment viewed both from literature and current practice include that of land farming, storing in plastic drum, re-injection into abandoned oil well, recovery, etc., found some problems. Due to its organic nature, very low level in radioactivity and the existence of a Scheduled Waste incineration facility in Bukit Nanas, there is a potential to treat this sludge by using thermal treatment technology. However, prior to having this suggestion to be put into practice, there are issues that need to be addressed. This paper attempts to discuss the potentials and the related issues of combusting crude oil sludge based on existing experimental data as well as mathematical modeling

  12. The Woman as Wolf (AT 409: Some Interpretations of a Very Estonian Folk Tale

    Directory of Open Access Journals (Sweden)

    Merili Metsvahi

    2013-12-01

    Full Text Available The article analyses tale type The Woman as Wolf, which is one of the most popular folk tales in the Estonian Folklore Archives and is represented there both in the form of a fairy tale and in the form of a legend. The vast majority of the versions of The Woman as Wolf were written down in the first part of the 20th century within Estonia and where recorded from Estonians. The article introduces the content of the tale, the origin of the first records from the early 19th century, and the dissemination area of the tale, which remains outside Western Europe: apart from the Estonian versions there are Sami, Karelian, Vepsian, Livonian, Latvian, Lithuanian, Russian, Ukrainian and Belarusian versions. While in almost all the Estonian versions the main protagonist is transformed into a wolf, in most of the versions written down in other areas and ethnic groups, another animal or bird replaces the wolf. The author is of the opinion that the Finnic area is central to the distribution of the folk tale The Woman as Wolf. The animal the woman is transformed into in the plot would not have been a wolf in earlier times. The article provides an explanation why the wolf is predominant in Estonian written sources. For that purpose the ways in which the wolf and werewolf were perceived in earlier Estonian folk belief are introduced. At the end of the article interpretation of the folk tale is provided. The author states that the plot and some of the motifs found in this folk tale reflect the difficulties women had in submitting to the norms and values of patriarchal order within their society.

  13. Estonian Golf & Country Club / Liina Jänes

    Index Scriptorium Estoniae

    Jänes, Liina, 1977-

    2005-01-01

    Estonian Golf & Country Club'i etnomodernistlik golfikeskus ja klubihoone Jõelähtmel. Projekteerija: Arhitektuuristuudio Siim & Kreis. Autor Andres Siim. Konstruktor: Resand. Sisekujundaja Juta Lember (SAB Lember & Padar). Projekt 2004, valmis 2005. Ill.: I ja II korruse plaan, 3 värv. välis ja 3 sisevaadet

  14. 三种印尼油砂燃烧特性研究%Study on Combustion Characteristics of Three Indonesia Oil Sands

    Institute of Scientific and Technical Information of China (English)

    王擎; 王引; 贾春霞; Deyin Wu

    2012-01-01

    The combustion characteristics of oil sand samples were investigated by the thermogravimetric analysis at different heating rates (i.e., 10 ,20, 50 'C/min). According to the thermogravimetric (TG) and differential thermogravimetric (DTG) curves, oil sand combustion process can be divided into three stages: low temperature section, transition section, high temperature section. The combustion characteristic parameters were calculated. The effect of heating rate and particle sizes were studied. Moreover, the kinetic parameters were obtained by three methods: the C-R, FWO and DEAM method. The results reveal that oil sand have better ignition features and a lower ignition temperature, and the combustion intensity is strong at the last stage of the combustion. The combustion of oil sand can be well described by three models. The result shows that every stage of combustion reaction is described in various reaction orders by using the C-R method. However, the results of DEAM and FWO method can reflect the instantaneous characteristic of combustion reaction perfectly, the activation energy increases in low temperature and high temperature period of combustion, the activation energy changes gently in transition section.%采用热重分析方法研究油砂的燃烧特性.在升温速率分别为10,20,50℃/min条件下,得到了油砂燃烧失重(thermogravimetric, TG)、微商失重(differential thermogravimetric,DTG)曲线.基于TG-DTG曲线,求得了油砂燃烧特性参数,考查了加热速率、粒径对燃烧特性的影响.采用单个扫描速率法中常用的CR法和多重扫描速率法中FWO法以及DEAM法求解了油砂的燃烧动力学参数,研究结果表明:油砂具有着火容易、着火温度低、燃烧高温段反应比较强烈等燃烧特性.油砂燃烧分为3个阶段:燃烧低温段、过渡段、高温段.这3种模型的拟合度都很高,C-R法结果表明油砂燃烧不同反应阶段可用不同的反应级数来描述;DEAM和FWO法结果能更好地反映油砂燃烧的瞬时性,活化能在燃烧低温段和高温段逐渐增加,活化能在燃烧过渡段变化较为平缓.

  15. HAZARDOUS AIR POLLUTANTS FROM THE COMBUSTION OF AN EMULSIFIED HEAVY FUEL OIL IN A FIRETUBE BOILER

    Science.gov (United States)

    The report gives results of measuring emissions of hazardous air pollutants (HAPs) from the combustion flue gases of a No. 6 fuel oil, both with and without an emulsifying agent, in a 2.5 million Btu/hr (732 kW) firetube boiler with the purpose of determining the impacts of the e...

  16. Emissions of polycyclic aromatic hydrocarbons from the combustion of crude oil on water

    International Nuclear Information System (INIS)

    Benner, B.A. Jr.; Bryner, N. P.; Wise, S.A.; Mulholland, G.W.; Evans, D.D.; Fingas, M.F.; Li, K.

    1991-01-01

    A study was conducted to examine some of the factors necessary to assess the environmental impact of an in-situ burn of an oil spill on water. These factors include the fraction of an oil layer which can be burned, the quantity of smoke emitted, and the concentrations of 18 polycyclic aromatic hydrocarbons (PAHs) in the smoke, crude oil, and burn residue. Alberta sweet mixed blend crude in 1, 3, 5, 10, and 30 mm layers on water was burned in the laboratory and smoke samples were collected at elevated and ambient temperatures and analyzed by two independent laboratories. While burning the crude oil produced less total PAHs than was in the original crude, the concentrations of PAHs with 5 or more rings were 10-20 times greater in the smoke than in the oil. The organic carbon fraction of the smoke was in the 14-21% range. As the fuel layer thickness was increased from 2 to 10 mm, the smoke yield increased from 0.035 g smoke/g fuel and the percentage of oil residue decreased from 46% to 17%. By consuming much of the oil spill and reducing the amount of PAHs in the water, and by dispersing the combustion products over a larger area, in-situ burning can mitigate the local environmental impact of an oil spill. There appears to be a range of situations, such as in Arctic ice fields, where in-situ burning might be the most viable cleanup method. 25 refs., 6 figs., 6 tabs

  17. Fuel oil combustion with low production of nitrogen oxides; Combustion de combustoleo con baja produccion de oxidos de nitrogeno

    Energy Technology Data Exchange (ETDEWEB)

    Escalera Campoverde, Rogelio [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1998-09-01

    This work presents the results of the theoretical-experimental study of the effects of the secondary air jet directed perpendicularly to the flame axis in the fuel oil combustion in a 500 Kw furnace. The main purpose of this study was to obtain low nitrogen oxides (NO{sub x}) emissions without increasing the CO, which is observed in low NO{sub x} conventional burners. The experimental results showed a significative reduction of the NO{sub x} and of the CO, from 320 to 90 ppm and from 50 ppm to negligible values, respectively. A commercial computational code of fluid dynamics was employed for modeling the combustion in base line conditions, without secondary air and with the injection of secondary air. The experimental results were compared with calculated ones. [Espanol] En este trabajo se presentan los resultados del estudio teorico experimental de los efectos de los chorro de aire secundario dirigidos en forma perpendicular al eje de la flama en la combustion del combustoleo en un horno de 500 kW. El proposito principal del estudio fue obtener bajas emisiones de oxidos de nitrogeno (NO{sub x}) sin incrementar el CO, lo cual se observa en quemadores convencionales de bajo NO{sub x}. Los resultados experimentales demostraron una reduccion significativa del NO{sub x} y del CO: de 320 a 90 ppm y de 50 ppm a valores despreciables, respectivamente. Se empleo un codigo computacional comercial de dinamica de fluidos para modelar la combustion en condiciones de linea base, sin aire secundario, y con la inyeccion del aire secundario. Se comparan resultados experimentales con los calculados.

  18. Distilling oils, etc

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, W G

    1913-08-13

    Oils and other products are distilled continuously from materials containing or charged with hydrocarbons, such as coal, shale, absorbent materials containing oil, or metal turnings covered with oil, in a vertical or inclined combustion chamber supplied continuously or intermittently with a small quantity of air, and continuously with a large quantity of gases from the condenser admitted below the combustion zone. If desired, steam may also be supplied to the combustion chamber. In the apparatus shown are the combustion chamber, the air inlet, the gas-inlet pipe, the gas-outlet pipe, the condenser, and a mechanical separator which preferably also acts as a fan. A pair of slides is provided at the bottom of the combustion chamber to discharge the residue without admitting air, or a water seal may be used.

  19. Numerical studies of spray combustion processes of palm oil biodiesel and diesel fuels using reduced chemical kinetic mechanisms

    KAUST Repository

    Kuti, Olawole; Sarathy, Mani; Nishida, Keiya; Roberts, William L.

    2014-01-01

    Spray combustion processes of palm oil biodiesel (PO) and conventional diesel fuels were simulated using the CONVERGE CFD code. Thermochemical and reaction kinetic data (115 species and 460 reactions) by Luo et al. (2012) and Lu et al. (2009) (68

  20. Critical Success Factors and information needs in Estonian industry

    Directory of Open Access Journals (Sweden)

    Aiki Tibar

    2002-01-01

    Full Text Available The article reports the results of the study on the critical success factors and related information needs in Estonian industry conducted in 1999. Data were collected by interviews with 27 managers and engineers from 16 manufacturing companies in various industries. Most of the critical success factors taken up were related to marketing, information management, quality management, product development and technological innovations. The information needs of managers and engineers were related to competitors, customers, markets, technology, regulations, etc. Some identified CSFs expressed also priorities for development by Estonian economic authorities: to support the implementation of new technologies and introduction of quality management methods. The finding that information management was perceived as a very critical area supports the result of the recent Finnish study on CSFs.

  1. The combustion heat of power producing shale based on individual deliveries for the years 1968 to 1981

    Energy Technology Data Exchange (ETDEWEB)

    Yyspuu, L M; Rayur, K W; Sits, Kh I

    1983-01-01

    The results are cited of a retrospective study of the specific combustion heat of power producing shale relative to the geological and mining technological conditions for nine mines and four open pits of the Baltic Sea Basin. In 1981 the maximal mean annual combustion heatQsigma-c of 12.44 megajoules per kilogram was held by the shales from the Tammiku mine, while the minimum of 10.12 megajoules per kilogram was held by the shales from the Leningradskaya mine. The results are used in a predictive evaluation of the heat creativity of the total fuel of the Baltic Sea region and the Estonian state regional electric power plants (GRES) for the coming years.

  2. Study on Combustion Performance of Diesel Engine Fueled by Synthesized Waste Cooking Oil Biodiesel Blends

    Directory of Open Access Journals (Sweden)

    Duraid F. Maki

    2018-02-01

    Full Text Available The waste cooking oil or used cooking oil is the best source of biodiesel synthesizing because it enters into the so-called W2E field whereas not only get rid of the used cooking oils but produce energy from waste fuel. In this study, biodiesel was synthesized from the used cooking oil and specifications are tested. From 1 liter of used cooking oil, 940 ml is gained. The remaining of liter is glycerin and water. Blend of 20% of biodiesel with 80% of net diesel by volume is formed. Blends of 100% diesel and 100% biodiesel are prepared too. The diesel engine combustion performance is studied. Brake thermal efficiency, brake specific fuel consumption, volumetric efficiency, mean effective pressure, and engine outlet temperature. Cylinder pressure variation with crank angle is analyzed. At last not least, the concentrations of hydro carbon and nitrogen pollutants are measured. The results showed significant enhancement in engine power and pollutant gases emitted. There is positive compatible with other critical researches.

  3. Premixed Combustion of Kapok (ceiba pentandra seed oil on Perforated Burner

    Directory of Open Access Journals (Sweden)

    I.K.G. Wirawan

    2014-05-01

    Full Text Available Availability of fossil fuels in the world decrease gradually due to excessive fuel exploitation. This situations push researcher to look for alternative fuels as a source of renewable energy, one of them is kapok (ceiba pentandra seed oil. The aim this study was to know the behavior of laminar burning velocity, secondary Bunsen flame with open tip, cellular and triple flame. Premixed combustion of kapok seed oil was studied experimentally on perforated burner with equivalence ratio (φ varied from 0.30 until 1.07. The results showed that combustion of glycerol requires a large amount of air so that laminar burning velocity (SL is the highest at very lean mixture (φ =0.36 in the form of individual Bunsen flame on each of the perforated plate hole.  Perforated and secondary Bunsen flame both reached maximum SL similar with that of ethanol and higher than that of hexadecane. Slight increase of φ decreases drastically SL of perforated and secondary Bunsen flame. When the mixture was enriched, secondary Bunsen and perforated flame disappears, and then the flame becomes Bunsen flame with open tip and triple flame (φ = 0.62 to 1.07. Flame was getting stable until the mixture above the stoichiometry. Being isolated from ambient air, the SL of perforated flame, as well as secondary Bunsen flame, becomes equal with non-isolated flame. This shows the decreasing trend of laminar burning velocity while φ is increasing. When the mixture was enriched island (φ = 0.44 to 0.48 and petal (φ = 0.53 to 0.62 cellular flame take place. Flame becomes more unstable when the mixture was changed toward stoichiometry.

  4. Elemental analysis of Kuwaiti petroleum and combustion products

    Energy Technology Data Exchange (ETDEWEB)

    Reid, J.S.; Cahill, T.A.; Gearhart, E.A.; Flocchini, R.G. (California Univ., Davis, CA (United States). Crocker Nuclear Lab.); Schweitzer, J.S.; Peterson, C.A. (Schlumberger-Doll Research Center, Ridgefield, CT (United States))

    1993-03-01

    Crude oil from eight Kuwaiti fields and aerosols generated by their combustion in the laboratory have been analyzed by composition and particulate size. Liquid petroleum and petroleum combustion products were subjected to elemental analysis by proton induced x-ray techniques and by x-ray fluorescence techniques. The mean sulfur content of the burning wells was weighted by their production rates to obtain the mean sulfur content of the burning oil, 2.66%. The liquid samples were also analyzed by neutron activation analyses. Results show that Kuwaiti oil and smoke aerosols from laboratory combustion generally contain very low amounts of chlorine, contrary to what is found in airborne samples above Kuwait. Trace element signatures were developed to aid in tracing smoke from the oil fires. (Author).

  5. Characteristics of oil sludge from crude oil terminal and behaviors of the naturally occurring radioactive materials and heavy metals on combustion of the sludge

    International Nuclear Information System (INIS)

    Mohamad Puad Abu

    2001-01-01

    The study on the characteristics and behaviors of Naturally Occurring Radioactive Materials (NORM) and heavy metals (HM) in the oil sludge from the crude oil terminal were performed using Gamma Spectroscopy (GM), Neutron Activation Analysis Instrumental (NAAI) and Inductively Coupled Plasma Mass Spectroscopy (ICP-MS). GM and NAAI were used to analyze the concentrations of radionuclides whereas NAAI as well as ICP-MS techniques were applied for HM. The samples were then combusted at temperature ranging from 100 degree Celsius - 800 degree Celsius for a period of 30-150 minutes. The ashes produced were then analyzed again for the various elemental concentrations by the above techniques. The percentage of volatilization was then derived mathematically. The concentration of Ra-226 (123 Bq/ kg) and Ra-228 (117 Bq/ kg) in the oil sludge are higher compared with their parent U-238 (32.12 Bq/ kg) and Th-232 (35.36 Bq/ kg). The concentration of HM such as As (13.30 ppm), Cr (46 ppm) and Zn (4287 ppm) in the oil sludge are also higher compared with As (7.5 ppm), Cr (43 ppm) and Zn (36 ppm) contain in the Malaysian normal soil. The heating value for crude oil sludge is 9000 kJ/ kg which is below the value for self-sustaining combustion (11000 kJ/ kg). The percentage of volatilization varies from 2-70 % depends on the elements, temperature and period of combustion. Uranium was found to volatile more than other elements. Higher temperatures (>500 degree Celsius) and longer exposure time (>90 minutes) promoted metal and radionuclide volatilization significantly more than 20 %. Based on the first order kinetic reaction, a new global mathematical model was developed (Q e =1-e -k e t ). This model can predict the percentage of volatilization for the various elements contain in the sludge if the temperature and time of combustion are known. With this known percentage of volatilization, the concentration of various elements present in the bottom and fly ashes can be deduced. From

  6. Russian-Estonian Economic and Investment Cooperation During the Crisis: Dynamics and Possibilities

    Directory of Open Access Journals (Sweden)

    Nevskaya Anastasia

    2015-06-01

    Full Text Available The article deals with the development in Russian-Estonian relations during the crises of 2007 and 2014, taking into consideration the balance between political and economic factors in the decision-making by Estonian government. A number of special aspects, trends and problems in trade and investment ties are detected. The aim of the study is to uncover key motivation behind the actions of both Russia and Estonia, to identify the drivers for economic and political development in the region, and to work out recommendations to adjust them. The questions put forward by the authors of this article could not be more topical at the time, when Russian economic situation is obviously getting worse and capital flight (to the neighboring EU Member States is likely to increase. The method of the study is comparative analysis of the impact on economic ties made by Russian-Estonian crisis of 2007 and the current international tension around Ukraine. The regional fossil fuel market and the possibilities of Gazprom involvement in its development are also analyzed. It is concluded that political motives are still important for Estonian decisionmaking, though they are balanced out by measures of business support (despite some of these measures being taken by the EU bodies. The role of political factor for the Russian side is increasing. It is acknowledged that there is a growing number of missed economic opportunities in the Russian Northwest.

  7. Underground treatment of combustible minerals

    Energy Technology Data Exchange (ETDEWEB)

    Sarapuu, E

    1954-10-14

    A process is described for treating oil underground, consisting in introducing several electrodes spaced one from the other in a bed of combustibles underground so that they come in electric contact with this bed of combustibles remaining insulated from the ground, and applying to the electrodes a voltage sufficient to produce an electric current across the bed of combustibles, so as to heat it and create an electric connection between the electrodes on traversing the bed of combustibles.

  8. Injection of heavy fuel oil into the blast furnace

    Energy Technology Data Exchange (ETDEWEB)

    Paloposki, T. [Helsinki Univ. of Technology, Otaniemi (Finland); Hakala, J.; Mannila, P.; Laukkanen, J. [Oulu Univ. (Finland)

    1996-12-31

    This study deals with the injection and combustion of heavy fuel oil in blast furnaces. The injection of the oil was studied experimentally in a small-scale test rig. The combustion of the oil was analysed with a commercial computer program for flow and combustion simulations. Results from computer simulations show that the combustion of the oil can be improved by decreasing the size of the oil drops and by enhancing the mixing between the oil drops and the hot blast. The devolatilization rate of the oil mainly depends on the size of the oil drops. The combustion rate of the volatiles mainly depends on the effectiveness of turbulent mixing with combustion air. Methods to decrease the size of the oil drops were sought in the experimental part of the study. Experimental results show that the size of the oil drops increases with increasing mass flow rate of the oil and decreases with increasing velocity of the hot blast. Methods to improve the mixing between the oil drops and the hot blast are suggested but have not yet been experimentally tested. (author) (4 refs.)

  9. Injection of heavy fuel oil into the blast furnace

    Energy Technology Data Exchange (ETDEWEB)

    Paloposki, T [Helsinki Univ. of Technology, Otaniemi (Finland); Hakala, J; Mannila, P; Laukkanen, J [Oulu Univ. (Finland)

    1997-12-31

    This study deals with the injection and combustion of heavy fuel oil in blast furnaces. The injection of the oil was studied experimentally in a small-scale test rig. The combustion of the oil was analysed with a commercial computer program for flow and combustion simulations. Results from computer simulations show that the combustion of the oil can be improved by decreasing the size of the oil drops and by enhancing the mixing between the oil drops and the hot blast. The devolatilization rate of the oil mainly depends on the size of the oil drops. The combustion rate of the volatiles mainly depends on the effectiveness of turbulent mixing with combustion air. Methods to decrease the size of the oil drops were sought in the experimental part of the study. Experimental results show that the size of the oil drops increases with increasing mass flow rate of the oil and decreases with increasing velocity of the hot blast. Methods to improve the mixing between the oil drops and the hot blast are suggested but have not yet been experimentally tested. (author) (4 refs.)

  10. Estonian Perceptions of Security: Not Only About Russia and the Refugees

    Directory of Open Access Journals (Sweden)

    Veebel Viljar

    2016-12-01

    Full Text Available The current study focuses on the Estonian perceptions of security and on the defence situation both globally and locally. The dynamic results of the public opinion surveys on security risks conducted in Estonia over the last 10 years (2006-2016 will be presented. In addition, to understand whether some of the security risks could be over- or underestimated in Estonia, these results will be compared with the views expressed recently by the World Economic Forum, particularly the Global Risks Report 2016. Also, the arguments why some topics have played or are currently playing key role in the Estonian security perception will be presented and discussed.

  11. Performance and Combustion Characteristics Analysis of Multi-Cylinder CI Engine Using Essential Oil Blends

    Directory of Open Access Journals (Sweden)

    S. M. Ashrafur Rahman

    2018-03-01

    Full Text Available Essential oils are derived from not-fatty parts of plants and are mostly used in aromatherapy, as well as cosmetics and perfume production. The essential oils market is growing rapidly due to their claimed health benefits. However, because only therapeutic grade oil is required in the medicinal sector, there is a substantial low-value waste stream of essential oils that can be used in the transportation and agricultural sectors. This study investigated the influence of orange, eucalyptus, and tea tree oil on engine performance and combustion characteristics of a multi-cylinder compression ignition engine. Orange, eucalyptus, and tea tree oil were blended with diesel at 10% by volume. For benchmarking, neat diesel and 10% waste cooking biodiesel-diesel blend were also tested. The selected fuels were used to conduct engine test runs with a constant engine speed (1500 RPM (revolutions per minute at four loads. As the load increased, frictional power losses decreased for all of the fuel samples and thus mechanical efficiency increased. At higher loads (75% and 100%, only orange oil-diesel blends produced comparable power to diesel and waste cooking biodiesel-diesel blends. Fuel consumption (brake and indicated for the essential oil-diesel blends was higher when compared to base diesel and waste cooking biodiesel-diesel blends. Thermal efficiency for the essential oil-diesel blends was comparable to base diesel and waste cooking biodiesel-diesel blends. At higher loads, blow-by was lower for essential oil blends as compared to base diesel and waste cooking biodiesel-diesel blends. At 50% and 100% load, peak pressure was lower for all of the essential oil-diesel blends when compared to base diesel and waste cooking biodiesel-diesel blends. From the heat release rate curve, the essential oil-diesel blends ignition delay times were longer because the oils have lower cetane values. Overall, the low-value streams of these essential oils were found to be

  12. The Rocky Road towards Professional Autonomy: The Estonian Journalists’ Organization in the Political Turmoil of the 20th Century

    Directory of Open Access Journals (Sweden)

    Epp Lauk

    2017-09-01

    Full Text Available This article attempts to explain the relationships between journalists, politics and the state from the perspective of collective autonomy, that of the professional organization of journalists. The case of Estonian Journalists’ Union demonstrates the complexity and historical contingency of professional autonomy of journalism. The development of the Estonian journalists’ organization occurred as a sequence of transformations from the Estonian Journalists’ Association to the Estonian Journalists’ Union to the Soviet type journalists’ union, and lastly to an independent trade union. This sequence was disrupted by several fatal breakdowns that changed not only the character of the association, but also professional values, the whole occupational ideology and the conditions of the existence of journalism as a profession in Estonia.

  13. Managing oil logistics around the Baltic Rim

    International Nuclear Information System (INIS)

    Kilander, H.

    1997-01-01

    Finland's Neste Group is a major player in the oil business in the Baltic area. Neste tankers and petroleum product logistics services comprehensively serve the region. Neste's main Baltic Rim terminal outside Finland is located at Muuga close to the Estonian capital, Tallinn. This will be joined by one in Riga in Latvia at the end of this year. A terminal for St. Petersburg is in the planning stage

  14. The Estonian study of Chernobyl cleanup workers. I. Introduction

    International Nuclear Information System (INIS)

    Rahu, Mati

    1999-01-01

    The most comprehensive epidemiological project ever performed in Estonia - The Estonian Study of Chernobyl Cleanup Workers - was the joint effort of researchers from Estonia, Finland and USA. Until September 1999, the results of this study were published in English only. To familiarize the readership of 'Eesti Arst' with the major study findings, the abridged versions of four original papers from 'Radiation Research' are presented in the current issue of the journal. For the Estonian epidemiologists, the work under this project that consists of eight sub projects was a real challenge. In the course of the study, skills were developed in writing a study protocol, preparing a questionnaire, progress reporting, documenting the structure of databases, record linkage, and problem solving. It was an exciting experience to work with top scientists like William Bigbee, John Boice, Timo Hakulinen, Ronald Jensen and Gayle Littlefield. (author)

  15. Sustainable development outlooks of the Estonian energy sector for convergence with the European Union countries

    International Nuclear Information System (INIS)

    Laur, Anton; Tenno, Koidu; Soosaar, Sulev

    2002-01-01

    The article presents an overview of a research conducted in the Estonian Inst. of Economics and the Estonian Energy Research Inst. with the objectives to: analyse the dynamics of the main Estonian energy use indicators over the last 8-10 years with the background of general macroeconomics developments; compare these indicators with the respective energy indicators in the European Union Member States and Candidate Countries; evaluate Estonia's potential to catch up by the energy use efficiency (GDP energy intensity) of the average level of EU countries, modelling our possible development scenarios of GDP and TPES. The research results indicates several positive development tendencies (e.g. reduction of TPES and CO 2 emissions with the background of economic growth) in the Estonian energy sector, as well as convergence with the EU countries in terms of GDP energy intensity. Unfortunately, the model analysis results demonstrate that it takes a lot of time for Estonia to reach the current EU level - even under the most favourable GDP and TPES development conditions, 25-30 years. The primary reason is the very low level of our GDP per capita compared to the EU countries. (author)

  16. Method for establishing a combustion zone in an in situ oil shale retort having a pocket at the top

    Science.gov (United States)

    Cha, Chang Y.

    1980-01-01

    An in situ oil shale retort having a top boundary of unfragmented formation and containing a fragmented permeable mass has a pocket at the top, that is, an open space between a portion of the top of the fragmented mass and the top boundary of unfragmented formation. To establish a combustion zone across the fragmented mass, a combustion zone is established in a portion of the fragmented mass which is proximate to the top boundary. A retort inlet mixture comprising oxygen is introduced to the fragmented mass to propagate the combustion zone across an upper portion of the fragmented mass. Simultaneously, cool fluid is introduced to the pocket to prevent overheating and thermal sloughing of formation from the top boundary into the pocket.

  17. Tabud ja reeglid. Sissevaateid eesti laagriromaani / Taboos and Rules. Insights into Prison Camp Novels by Estonian Writers

    Directory of Open Access Journals (Sweden)

    Anneli Kõvamees

    2013-12-01

    Full Text Available The article concentrates on Estonian novels depicting Soviet prison camps in the 1940s and 1950s. The goal is to map themes, motifs and characteristics in such novels, concentrating on various taboos and rules in the prison camp environment. For a long time the Soviet prison camp theme was not publicly discussed in Estonia due to political reasons. Texts dealing with prison camps could appear in print only outside the Soviet Union; the way Estonians saw these historical events and hellish experiences were depicted mostly in exile novels. Most notable are the novels by Arved Viirlaid (b. 1922, e.g., Kes tappis Eerik Hormi? (Who Killed Eerik Horm? (1974, Surnud ei loe (The Dead do not Read (1975, Vaim ja ahelad (Mind and Chains (1961. Estonian prison camp novels can be seen as “the literature of testimony”, to use the term by Leona Toker. Dramatic historical events are written down to record the events and to show the inhumane nature of Soviet society. These records of the dramatic past follow certain patterns and create certain self- and hetero-images. A prison camp is a closed territory within a closed territory; prison camps can be seen as small models of Soviet society. Prison camp novels give a detailed view of the environment of the prison camp, its inhabitants and activities. Two central aspects are labour and food; the life of the prisoner whirls around these. The most important thing is to survive, which often leads to moral decline, e.g., stealing, cheating. However, there are lines Estonians do not cross, e.g., cannibalism or homosexual relationships with superiors. Estonians are always depicted as political prisoners (not common criminals and heterosexuals, while Russians are portrayed mainly as criminals and often also as homosexuals. Another important component of the image of the Estonians is their enterprising spirit and ability to manage even under very difficult conditions. Therefore, several oppositions can be identified, e

  18. Estonian Golf & Country Clubi klubihoone / Andres Siim, Alar Just

    Index Scriptorium Estoniae

    Siim, Andres

    2005-01-01

    Harjumaal Jõelähtme vallas rajab Estonian Golf & Country Club uut Jägala-Jõesuu spordi- ja puhkekeskust, mille südameks saab puidust golgiklubi hoone, mida tutvustavad klubihoone arhitekt ja üks inseneridest. Ill.: vaade ehitusele, projekti kaks vaadet, lõige

  19. Study on the basic properties of Indonesian oil sands

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Qing; Jiang, Qian-qian; Bai, Jing-ru; Sun, Jian; Liu, Hong-peng [Northeast Dianli Univ., Jilin (China). Inst. of Energy and Power Engineering

    2013-07-01

    The basic properties of three Indonesian oil sands have been investigated. The results show that since the high content of volatile, heating value and oil yield, Indonesian oil sands could be combusted for power generation and retorting for oil refining. Moreover, oil sand ash with the low content of fixed carbon and high content of CaO, could not only be used as solid heat carrier during retorting, but also comprehensively used as construction material. Based on the thermogravimeric analysis (TGA), pyrolysis and combustion behaviors have been identified. As for pyrolysis, 350-520 C could be regarded as the major oil-producing region, the apparent activation energy E is not a constant obtained by distributed activation energy model (DAEM). For combustion, 620-800 C is the high-temperature oxidation (HTO) stage. TG-DTG extrapolation method was applied to determine the combustion characteristics parameters such as ignition temperature, burn-out temperature, combustion stability and combustion reactivity, and finally gave a comparison with those of oil shale and coal.

  20. Value Education in Estonian Preschool Child Care Institutions

    Science.gov (United States)

    Ülavere, Pärje; Tammik, Anu

    2017-01-01

    For systematic implementation of value education in educational institutions, the national programme "Values Development in Estonian Society 2009-2013" (Ministry of Education and Research 2009) was prepared in Estonia. However, it was launched only in 2010, and the authors intended to ascertain the values of the heads of preschool child…

  1. Estonian energy forest project

    International Nuclear Information System (INIS)

    Koppel, A.; Kirt, E.; Kull, K.; Lasn, R.; Noormets, A.; Roostalu, H.; Ross, J.; Ross, V.; Sulev, M.

    1994-04-01

    In February 1993 an agreement of Swedish-Estonian scientific co-operation on energy forest was signed. In may five energy forest plantations (altogether 2 ha) were established in Estonia with Swedish selected clones of Salix viminalis and Salix dasyclados. The research within this project is carried out within three main directions. The studies of basic ecophysiological processes and radiation regime of willow canopy will be carried out in Toravere. The production ecology studies, comparison of the productivity of multiple clones on different soil types is based on the plantations as vegetation filter for wastewater purification is studied on the basis of plantations in Vaeike-Maarja and Valga (author)

  2. Improvement studies on emission and combustion characteristics of DICI engine fuelled with colloidal emulsion of diesel distillate of plastic oil, TiO2 nanoparticles and water.

    Science.gov (United States)

    Karisathan Sundararajan, Narayanan; Ammal, Anand Ramachandran Bhagavathi

    2018-04-01

    Experimentation was conducted on a single cylinder CI engine using processed colloidal emulsions of TiO 2 nanoparticle-water-diesel distillate of crude plastic diesel oil as test fuel. The test fuel was prepared with plastic diesel oil as the principal constituent by a novel blending technique with an aim to improve the working characteristics. The results obtained by the test fuel from the experiments were compared with that of commercial petro-diesel (CPD) fuel for same engine operating parameters. Plastic oil produced from high density polyethylene plastic waste by pyrolysis was subjected to fractional distillation for separating plastic diesel oil (PDO) that contains diesel range hydrocarbons. The blending process showed a little improvement in the field of fuel oil-water-nanometal oxide colloidal emulsion preparation due to the influence of surfactant in electrostatic stabilization, dielectric potential, and pH of the colloidal medium on the absolute value of zeta potential, a measure of colloidal stability. The engine tests with nano-emulsions of PDO showed an increase in ignition delay (23.43%), and decrease in EGT (6.05%), BSNO x (7.13%), and BSCO (28.96%) relative to PDO at rated load. Combustion curve profiles, percentage distribution of compounds, and physical and chemical properties of test fuels ascertains these results. The combustion acceleration at diffused combustion phase was evidenced in TiO 2 emulsion fuels under study.

  3. Determination of performance and combustion characteristics of a diesel engine fueled with canola and waste palm oil methyl esters

    Energy Technology Data Exchange (ETDEWEB)

    Ozsezen, Ahmet Necati [Department of Automotive Engineering Technology, Kocaeli University, 41380 Izmit (Turkey); Alternative Fuels R and D Center, Kocaeli University, 41040 Izmit (Turkey); Canakci, Mustafa, E-mail: canakci@kocaeli.edu.t [Department of Automotive Engineering Technology, Kocaeli University, 41380 Izmit (Turkey); Alternative Fuels R and D Center, Kocaeli University, 41040 Izmit (Turkey)

    2011-01-15

    In this study, the performance, combustion and injection characteristics of a direct injection diesel engine have been investigated experimentally when it was fueled with canola oil methyl ester (COME) and waste (frying) palm oil methyl ester (WPOME). In order to determine the performance and combustion characteristics, the experiments were conducted at constant engine speeds under the full load condition of the engine. The results indicated that when the test engine was fueled with WPOME or COME instead of petroleum based diesel fuel (PBDF), the brake power reduced by 4-5%, while the brake specific fuel consumption increased by 9-10%. On the other hand, methyl esters caused reductions in carbon monoxide (CO) by 59-67%, in unburned hydrocarbon (HC) by 17-26%, in carbon dioxide (CO{sub 2}) by 5-8%, and smoke opacity by 56-63%. However, both methyl esters produced more nitrogen oxides (NO{sub x}) emissions by 11-22% compared with those of the PBDF over the speed range.

  4. Determination of performance and combustion characteristics of a diesel engine fueled with canola and waste palm oil methyl esters

    International Nuclear Information System (INIS)

    Ozsezen, Ahmet Necati; Canakci, Mustafa

    2011-01-01

    In this study, the performance, combustion and injection characteristics of a direct injection diesel engine have been investigated experimentally when it was fueled with canola oil methyl ester (COME) and waste (frying) palm oil methyl ester (WPOME). In order to determine the performance and combustion characteristics, the experiments were conducted at constant engine speeds under the full load condition of the engine. The results indicated that when the test engine was fueled with WPOME or COME instead of petroleum based diesel fuel (PBDF), the brake power reduced by 4-5%, while the brake specific fuel consumption increased by 9-10%. On the other hand, methyl esters caused reductions in carbon monoxide (CO) by 59-67%, in unburned hydrocarbon (HC) by 17-26%, in carbon dioxide (CO 2 ) by 5-8%, and smoke opacity by 56-63%. However, both methyl esters produced more nitrogen oxides (NO x ) emissions by 11-22% compared with those of the PBDF over the speed range.

  5. Estonian wind climate

    International Nuclear Information System (INIS)

    Kull, Ain

    1999-01-01

    Estonia is situated on the eastern coast of the Baltic Sea. This is a region with intensive cyclonic activity and therefore with a relatively high mean wind speed. Atmospheric circulation and its seasonal variation determine the general character of the Estonian wind regime over the Atlantic Ocean and Eurasia. However, the Baltic sea itself is a very important factor affecting wind climate, it has an especially strong influence on the wind regime in costal areas. The mean energy density (W/m 2 ) is a wind energy characteristic that is proportional to the third power of wind speed and describes energy available in a flow of air through a unit area. The mean energy density is a characteristic which has practical importance in regional assessment of snowdrift, storm damage and wind energy

  6. IEA combustion agreement : a collaborative task on alternative fuels in combustion

    International Nuclear Information System (INIS)

    Larmi, M.

    2009-01-01

    The focus of the alternative fuels in combustion task of the International Energy Agency is on high efficiency engine combustion, furnace combustion, and combustion chemistry. The objectives of the task are to develop optimum combustion for dedicated fuels by fully utilizing the physical and chemical properties of synthetic and renewable fuels; a significant reduction in carbon dioxide, NOx and particulate matter emissions; determine the minimum emission levels for dedicated fuels; and meet future emission standards of engines without or with minimum after-treatment. This presentation discussed the alternative fuels task and addressed issues such as synthetic fuel properties and benefits. The anticipated future roadmap was presented along with a list of the synthetic and renewable engine fuels to be studied, such as neat oxygenates like alcohols and ethers, biogas/methane and gas combustion, fuel blends, dual fuel combustion, high cetane number diesel fuels like synthetic Fischer-Tropsch diesel fuel and hydrogenated vegetable oil, and low CN number fuels. Implementation examples were also discussed, such as fuel spray studies in optical spray bombs; combustion research in optical engines and combustion chambers; studies on reaction kinetics of combustion and emission formation; studies on fuel properties and ignition behaviour; combustion studies on research engines; combustion optimization; implementing the optimum combustion in research engines; and emission measurements. Overall milestone examples and the overall schedule of participating countries were also presented. figs.

  7. Musical Practices and Methods in Music Lessons: A Comparative Study of Estonian and Finnish General Music Education

    Science.gov (United States)

    Sepp, Anu; Ruokonen, Inkeri; Ruismäki, Heikki

    2015-01-01

    This article reveals the results of a comparative study of Estonian and Finnish general music education. The aim was to find out what music teaching practices and approaches/methods were mostly used, what music education perspectives supported those practices. The data were collected using questionnaires and the results of 107 Estonian and 50…

  8. Combustion characteristics, performance and exhaust emissions of a diesel engine fueled with a waste cooking oil biodiesel mixture

    International Nuclear Information System (INIS)

    Can, Özer

    2014-01-01

    Highlights: • High quality biodiesel fuels can be produced by using different waste cooking oils. • Biodiesel fuel blends (in 5 and 10% vol) can be used without any negative effects. • Effects of biodiesel addition on the combustion and exhaust emissions were investigated. - Abstract: In this study, a mixture of biodiesel fuels produced from two different kinds of waste cooking oils was blended in 5% and 10% with No. 2 diesel fuel. The biodiesel/No. 2 diesel fuel blends were tested in a single-cylinder, direct injection, four-stroke, natural aspirated diesel engine under four different engine loads (BMEP 0.48–0.36–0.24–0.12 MPa) and 2200 rpm engine speed. Despite of the earlier start of injection, the detailed combustion and engine performance results showed that the ignition delay with the biodiesel addition was decreased for the all engine loads with the earlier combustion timings due to higher cetane number of biodiesel fuel. Meanwhile the maximum heat release rate and the in-cylinder pressure rise rate were slightly decreased and the combustion duration was generally increased with the biodiesel addition. However, significant changings were not observed on the maximum in-cylinder pressures. In addition, it was observed that the indicated mean effective pressure values were slightly varied depending on the start of combustion timing and the center of heat release location. It was found that 5% and 10% biodiesel fuel addition resulted in slightly increment on break specific fuel consumption (up to 4%) and reduction on break thermal efficiency (up to 2.8%). The biodiesel additions also increased NO x emissions up to 8.7% and decreased smoke and total hydrocarbon emissions for the all engine loads. Although there were no significant changes on CO emissions at the low and medium engine loads, some reductions were observed at the full engine load. Also, CO 2 emissions were slightly increased for the all engine loads

  9. Top 10 Estonian albums of 2004 / Igor Garshnek

    Index Scriptorium Estoniae

    Garšnek, Igor, 1958-

    2004-01-01

    Heliplaatidest: Arvo Pärt "Pro et contra", Various composers "Baltic Voices 2", Raimo Kangro "Displays", Toivo Tulev "Be Lost in the Call", Indrek Vau and Mati Mikalai "Estonian Trumpet Music", Erdmann/Sooäär "Dessert Time, Peer Gynt & Other Stories", Alo Mattiisen "50 parimat laulu", Riho Sibul "Must", Rein Rannap "Tantsib klaveril", Eesti Keeled "Kella tiksumist..."

  10. [Marge Rennit. Eesti muuseumid / Estonian museums] / Tapio Mäkeläinen

    Index Scriptorium Estoniae

    Mäkeläinen, Tapio

    2009-01-01

    Tutvustus: Eesti muuseumid = Estonian museums / [Eesti Muuseumiühing ; koostaja Marge Rennit ; tõlkija Tiina Mällo ; toimetaja Ivi Tammaru ; eessõna: Piret Õunapuu ; kujundaja Marek Allvee]. Tallinn : Oomen, 2008

  11. Experimental investigation of combustion of biomass slurry in an oil fired furnace

    Energy Technology Data Exchange (ETDEWEB)

    Prakash, S.V. [Mechanical Dept., M.S. Ramaiah Inst. of Tech., Bangalore (India); Shankapal, S.R. [M.S. Ramaiah School of Advanced Studies, Bangalore (India)

    2008-07-01

    An experimental investigation of combustion of biomass slurry in an oil fired furnace was carried out using pulverized coconut shell (CSP), LDO and water. The effect of equivalence ratio on the slurry composition, calorific value and the effect of exhaust gas percentage are presented. The calorific value of the biomass slurry increases with equivalence ratio initially, attains a peak value and then decreases with the increase in equivalence ratio. It is also observed that with the increase in composition of biomass slurry, the cost of the fuel and the percentage emission of CO decreases. It was found that CSP up to a blend of 20% was more convenient to be used as a slurry fuel in the furnace. (orig.)

  12. Cancer incidence and thyroid disease among Estonian Chernobyl clean-up workers

    Energy Technology Data Exchange (ETDEWEB)

    Auvinen, A; Salomaa, S [eds.; Radiation and Nuclear Safety Authority, Helsinki (Finland); Rahu, M; Veidebaum, T; Tekkel, M [eds.; Inst. of Experimental and Clinical Medicine, Tallinn (Estonia); Hakulinen, T [ed.; Finnish Cancer Registry, Helsinki (Finland); Boice, Jr, J D [ed.; Int. Epidemiology Inst., MD (United States)

    1998-09-01

    The report describes the development and summarizes the results of the project Cancer incidence and thyroid disease among Estonian Chernobyl clean-up workers. One of the goals of the report is to give research protocols and questionnaires for researchers involved in other studies. Eight previously published articles are also included summarizing the results. The development of the collaboration work of the project is described in the introduction of the report. Epidemiological methods are described in an article complemented by the protocol and English version of the questionnaire administered to all cleanup workers, as well as the data collection form of the thyroid study. The results from biological biodosimetry using both glycophorin A and FISH methods have shown that the radiation doses received by the Chernobyl cleanup workers were relatively low. Thyroid nodularity was not associated with any radiation exposure characteristic in the thyroid screening study. Estonian Chernobyl cleanup workers were followed up for cancer incidence through the Estonian Cancer Registry. No cases of leukemia or thyroid cancer were observed by the end of 1993. It is too early to observe possible effect on other types of cancer. However, mortality from suicides was increased compared with general population. Further follow-up and the extension to other Baltic countries in the future will undoubtedly strengthen the study. There are also plans for future projects covering areas from psychosocial factors to radiation biology

  13. MINORITY LANGUAGES IN ESTONIAN SEGREGATIVE LANGUAGE ENVIRONMENTS

    Directory of Open Access Journals (Sweden)

    Elvira Küün

    2011-01-01

    Full Text Available The goal of this project in Estonia was to determine what languages are spoken by students from the 2nd to the 5th year of basic school at their homes in Tallinn, the capital of Estonia. At the same time, this problem was also studied in other segregated regions of Estonia: Kohtla-Järve and Maardu. According to the database of the population census from the year 2000 (Estonian Statistics Executive Office's census 2000, there are representatives of 142 ethnic groups living in Estonia, speaking a total of 109 native languages. At the same time, the database doesn’t state which languages are spoken at homes. The material presented in this article belongs to the research topic “Home Language of Basic School Students in Tallinn” from years 2007–2008, specifically financed and ordered by the Estonian Ministry of Education and Research (grant No. ETF 7065 in the framework of an international study called “Multilingual Project”. It was determined what language is dominating in everyday use, what are the factors for choosing the language for communication, what are the preferred languages and language skills. This study reflects the actual trends of the language situation in these cities.

  14. Sulfur Chemistry in Combustion II

    DEFF Research Database (Denmark)

    Johnsson, Jan Erik; Kiil, Søren

    2000-01-01

    Several options are available to control the emission of SO2 from combustion processes. One possibility is to use a cleaner technology, i.e. fuel switching from oil and coal to natural gas or biomass, or to desulphurize coal and oil. Another possibility is to change to a different technology...

  15. Problems of contemporary ecology. Temporal changes in Estonian nature and environment

    International Nuclear Information System (INIS)

    Frey, T.

    1997-01-01

    This conference was held 8-9 May 1997 at Tartu, Estonia. The proceedings of the 7. Estonian Conference in Ecology contain the results of mostly original research in environmental science, conservation and natural philosophy

  16. Strategies for Estonian rural family enterprises. Eesti maapiirkonna pereettevõtete strateegia

    Directory of Open Access Journals (Sweden)

    Maret Kirsipuu

    2013-01-01

    Full Text Available The paper seeks to analyse family businesses in rural areas, family business strategies and re-registration of sole proprietors with the Centre of Registers and Information Systems (hereinafter Commercial Register in 2009, and to provide an overview of entrepreneurship policies targeted at Estonian rural businesses. Layoffs have increased the number of unemployed; some of those who have lost employment opt for social assistance benefits, but some others decide to become entrepreneurs. Many enterprising people in Estonia have set up a family enterprise, mainly in the sphere of services, agriculture and tourism. The Estonian entrepreneurship policy supports enterprising people and approves of entrepreneurship as a promoter of national economic development. One of the most positive qualities of family enterprises is their short decision-making chain, which ensures rapid implementation of the strategy.

  17. Subsidence prediction in Estonia's oil shale mines

    International Nuclear Information System (INIS)

    Pastarus, J.R.; Toomik, A.

    2000-01-01

    This paper analysis the stability of the mining blocks in Estonian oil shale mines, where the room-and-pillar mining system is used. The pillars are arranged in a singular grid. The oil shale bed is embedded at the depth of 40-75 m. The processes in overburden rocks and pillars have caused the subsidence of the ground surface. The conditional thickness and sliding rectangle methods performed calculations. The results are presented by conditional thickness contours. Error does not exceed 4%. Model allows determining the parameters of spontaneous collapse of the pillars and surface subsidence. The surface subsidence parameters will be determined by conventional calculation scheme. Proposed method suits for stability analysis, failure prognosis and monitoring. 8 refs

  18. Utilisation of Estonian energy wood resources

    Energy Technology Data Exchange (ETDEWEB)

    Muiste, P.; Tullus, H.; Uri, V. [Estonian Agricultural University, Tartu (Estonia)

    1996-12-31

    In the end of the Soviet period in the 1980s, a long-term energy programme for Estonia was worked out. The energy system was planned to be based on nuclear power and the share of domestic alternative sources of energy was low. The situation has greatly changed after the re-establishment of the Estonian independence, and now wood and peat fuels play an important role in the energy system. Energy consumption in Estonia decreased during the period 1970-1993, but this process has less influenced the consumption of domestic renewable fuels - peat and wood. It means that the share of these fuels has grown. The investment on substitution of imported fossil fuels and on conversion of boiler plants from fossil fuels to domestic fuels has reached the level of USD 100 million. The perspectives of the wood energy depend mainly on two factors; the resources and the price of wood energy compared with other fuels. The situation in wood market influences both the possible quantities and the price. It is typical that the quickly growing cost of labour power in Estonia is greatly affecting the price of energy wood. Though the price level of fuel peat and wood chips is lower than the world market price today, the conditions for using biofuels could be more favourable, if higher environmental fees were introduced. In conjunction with increasing utilisation of biofuels it is important to evaluate possible emissions or removal of greenhouse gases from Estonian forests 3 refs.

  19. Utilisation of Estonian energy wood resources

    Energy Technology Data Exchange (ETDEWEB)

    Muiste, P; Tullus, H; Uri, V [Estonian Agricultural University, Tartu (Estonia)

    1997-12-31

    In the end of the Soviet period in the 1980s, a long-term energy programme for Estonia was worked out. The energy system was planned to be based on nuclear power and the share of domestic alternative sources of energy was low. The situation has greatly changed after the re-establishment of the Estonian independence, and now wood and peat fuels play an important role in the energy system. Energy consumption in Estonia decreased during the period 1970-1993, but this process has less influenced the consumption of domestic renewable fuels - peat and wood. It means that the share of these fuels has grown. The investment on substitution of imported fossil fuels and on conversion of boiler plants from fossil fuels to domestic fuels has reached the level of USD 100 million. The perspectives of the wood energy depend mainly on two factors; the resources and the price of wood energy compared with other fuels. The situation in wood market influences both the possible quantities and the price. It is typical that the quickly growing cost of labour power in Estonia is greatly affecting the price of energy wood. Though the price level of fuel peat and wood chips is lower than the world market price today, the conditions for using biofuels could be more favourable, if higher environmental fees were introduced. In conjunction with increasing utilisation of biofuels it is important to evaluate possible emissions or removal of greenhouse gases from Estonian forests 3 refs.

  20. The problems and development potential of revenue autonomy in Estonian municipalities. Kohalike omavalitsuste tuluautonoomia probleemid ja arenguvõimalused Eestis

    Directory of Open Access Journals (Sweden)

    Janno Reiljan

    2013-01-01

    Full Text Available In a regionally heterogeneous country like Estonia, it is a difficult task to create a local government revenue structure that guarantees even supply of public services across the entire country and, at the same time, revenue autonomy for the municipalities. In the theoretical part of the current article the suitability of different sources of own revenues are analysed in the context of Estonian municipalities. The empirical part of the article compares the financing principles of Estonian municipalities with other EU countries. Finally, the proportions of different own sources of revenues in the budgets of Estonian local governments are examined and suggestions are made for changing the current system

  1. Alberta's Estonians 1899 - Present TLÜ Akadeemilises Raamatukogus / Sander Jürisson

    Index Scriptorium Estoniae

    Jürisson, Sander

    2014-01-01

    Tallinna Ülikooli Akadeemilises Raamatukogus on üleval näitus "Alberta's Estonians 1899 - Present", mis annab ülevaate Kanada Alberta provintsi eestlaste loost. Näitus valmis Alberta Eesti Kultuuripärandi Seltsi koostöös Alberta Provintsi Arhiivi Kultuuripärandi Osakonnaga Edmontonis

  2. Effect of low-temperature oxidation on the pyrolysis and combustion of whole oil

    International Nuclear Information System (INIS)

    Murugan, Pulikesi; Mahinpey, Nader; Mani, Thilakavathi; Asghari, Koorosh

    2010-01-01

    Low-temperature oxidation (LTO) of the Fosterton crude oil mixed with its reservoir sand has been investigated in a tubular reactor. Reservoir sand saturated with 15 wt% of crude oil (20.5 o API gravity) was subjected to air injection at low-temperature (220 o C) for a period of time (17 h and 30 min), resulting in the formation of an oxygenated hydrocarbon fuel. The vent gases were analyzed for the content of CO, CO 2 , and oxygen and the residue was analyzed to determine the elemental composition and calorific value. The presence of LTO region was verified from the values of apparent H/C ratio. In addition, thermal behavior and combustion kinetics of the residue was investigated using thermogravimetric analysis (TGA). TG involves both non-isothermal and isothermal analysis and kinetic data was derived from isothermal studies. The general model for nth order reaction was used to obtain the kinetic parameters of the coke oxidation reaction. The activation energy, frequency factor and order of the reactions were determined using the model.

  3. Distillation of oil-bearing minerals

    Energy Technology Data Exchange (ETDEWEB)

    1952-05-21

    In the process of distilling oil-bearing minerals such as oil shale which disintegrates during distillation, wherein the subdivided minerals are subjected to a distillation temperature in the form of a highly turbulent dense mass fluidized by an upwardly flowing gasiform medium in a distillation zone and the heat required by the distillation is supplied by burning solid distillation residue with a combustion-supporting gas in the form of a fluidized mass of solids in a separate combustion zone at a temperature substantially higher than the distillation temperature and returning solid combustion residue substantially at the higher temperature to the distillation zone. The steps of starting up the process which consists of maintaining in the distillation and combustion zones dense turbulent fluidized beds of non-disintegrating solids, circulating the non-disintegrating solids between said beds, heating the circulating solids by an auxiliary heat supply until the bed in the distillation zone has reached at least the distillation temperature, thereafter charging fresh oil-bearing minerals to the bed in the distillation zone, continuing the circulation, withdrawing solids which have passed through the combustion zone at a rate adequate to maintain a solids balance, supplying the combustion-supporting gas to the combustion zone to cause the combustion of the residue, and discontinuing the auxilary heating when sufficient heat for the distillation is being generated in the combustion zone.

  4. Combined effect of nanoemulsion and EGR on combustion and emission characteristics of neat lemongrass oil (LGO)-DEE-diesel blend fuelled diesel engine

    International Nuclear Information System (INIS)

    Sathiyamoorthi, R.; Sankaranarayanan, G.; Pitchandi, K.

    2017-01-01

    Highlights: • Neat lemongrass oil can be used as an alternate fuel in diesel engine. • The combined effect of nano emulsion and EGR using LGO25-DEE-Diesel is investigated. • The BTE is improved for nano emulsion fuel blend. • The NO_x and smoke emissions decrease significantly. • Cylinder pressure and Heat release rate increase with longer ignition delay. - Abstract: In the present experimental study, the combined effects of nanoemulsion and exhaust gas recirculation (EGR) on the performance, combustion and emission characteristics of a single cylinder, four stroke, variable compression ratio diesel engine fueled with neat lemongrass oil (LGO)-diesel-DEE (diethyl ether) blend are investigated. The Neat Lemongrass oil could be used as a new alternate fuel in compression ignition engines without any engine modifications. The entire investigation was conducted in the diesel engine using the following test fuels: emulsified LGO25, cerium oxide blended emulsified LGO25 and DEE added emulsified LGO25 with EGR respectively and compared with standard diesel and LGO25 (75% by volume of diesel and 25% by volume of lemongrass oil) fuels. The combined effect of DEE added nano-emulsified LGO25 with EGR yielded a significant reduction in NO_x and smoke emission by 30.72% and 11.2% respectively compared to LGO25. Furthermore, the HC and CO emissions were reduced by 18.18% and 33.31% respectively than with LGO25. The brake thermal efficiency and brake specific fuel consumption increased by 2.4% and 10.8% respectively than LGO25. The combustion characteristics such as cylinder pressure and heat release rate increased by 4.46% and 3.29% respectively than with LGO25. The combustion duration and ignition delay increase at nano-emulsified LGO25 with DEE and EGR mode but decrease for nano-emulsified LGO25 fuel.

  5. Estonian Leader's Freedom Call Creates Storm / Anna Smolchenko

    Index Scriptorium Estoniae

    Smolchenko, Anna

    2008-01-01

    President Toomas Hendrik Ilvese esinemisest soome-ugri rahvaste maailmakongressil Hantõ-Mansiiskis, kohtumisest Venemaa presidendi Dmitri Medvedeviga, Eesti delegatsiooni saalist väljamarssimisest Venemaa riigiduuma väliskomisjoni esimehe Konstantin Kossatshovi sõnavõtu ajal. Ilmunud ka: St. Petersburg Times 1. juuli 2008, pealk.: Estonian Leader's Freedom Call Creates Controversy (lüh.). Vabariigi President töövisiidil Venemaal 27.-30.06.2008

  6. Reburning and burnout simulations of natural gas for heavy oil combustion

    Energy Technology Data Exchange (ETDEWEB)

    Celso A. Bertran; Carla S.T. Marques; Renato V. Filho [Universidade Estadual de Campinas, Campinas (Brazil). Instituto de Quimica

    2004-01-01

    Reburning and burnout simulations were carried out through PLUG code of CHEMKIN-III using a reduced mechanism, in order to determine preliminary experimental parameters for achieving maximum NOx reduction to implement the reburning technology for heavy oil combustion in pilot scale equipments in Brazil. Gas compositions at the entrance of the reburning zone were estimated by the AComb program. Simulations were performed for eight conditions in the usual range of operational parameters for natural gas reburning. The maximum NO reduction (ca. 50%) was reached with 10 and 17.5% of power via natural gas and 1.5 and 3.0% O{sub 2} excess, respectively, at 1273 K. The model predicts 250 ppm of NO, 50 ppm of CO and air mass flows in the range of about 50 130 kg/h for burnout. 18 refs., 1 fig., 2 tabs.

  7. Smoking habits and attitudes towards smoking among Estonian physicians.

    Science.gov (United States)

    Pärna, K; Rahu, K; Rahu, M

    2005-05-01

    This study examined the smoking habits and attitudes towards smoking among Estonian physicians. Cross-sectional data for 2668 physicians were gathered by a self-administered postal survey. The current smoking prevalence was 24.9% for male physicians and 10.8% for female physicians. The percentages of ex-smokers were 32.9 and 16.8%, respectively. Smoking prevalence among physicians was below the levels reported for the highest educational bracket of the total population in Estonia. Non-smoking physicians had more unfavourable views towards smoking than those who smoked. The majority of physicians were aware of the association between smoking and various diseases, with significant differences between smokers and non-smokers. Non-smoking physicians were more active in asking patients about smoking habits than those who smoked. Most Estonian physicians, especially those who smoked, failed to perceive themselves as positive role models. This study found a lower prevalence of smoking among physicians compared with the general population, and demonstrated the impact of personal smoking on physicians' attitudes towards smoking. The results provide an important challenge to medical education in Estonia.

  8. DEVELOPMENT OF FINE PARTICULATE EMISSION FACTORS AND SPECIATION PROFILES FOR OIL AND GAS FIRED COMBUSTION SYSTEMS

    Energy Technology Data Exchange (ETDEWEB)

    Glenn England; Oliver Chang; Stephanie Wien

    2002-02-14

    This report provides results from the second year of this three-year project to develop dilution measurement technology for characterizing PM2.5 (particles with aerodynamic diameter smaller than 2.5 micrometers) and precursor emissions from stationary combustion sources used in oil, gas and power generation operation. Detailed emission rate and chemical speciation tests results for a gas turbine, a process heater, and a commercial oil/gas fired boiler are presented. Tests were performed using a research dilution sampling apparatus and traditional EPA methods. A series of pilot tests were conducted to identify the constraints to reduce the size of current research dilution sampler for future stack emission tests. Based on the test results, a bench prototype compact dilution sampler developed and characterized in GE EER in August 2002.

  9. Experimental studies on the combustion and emission characteristics of a diesel engine fuelled with used cooking oil methyl ester and its diesel blends

    Energy Technology Data Exchange (ETDEWEB)

    Lakshmi Narayana Rao, G.; Sampath, S. [Sri Venkateswara College of Engineering, Sriperumbudur (India); Rajagopal, K. [Jawaharlal Nehru Technological Univ., Hyderabad (India)

    2008-04-01

    Transesterified vegetable oils (biodiesel) are promising alternative fuel for diesel engines. Used vegetable oils are disposed from restaurants in large quantities. But higher viscosity restricts their direct use in diesel engines. In this study, used cooking oil was dehydrated and then transesterified using an alkaline catalyst. The combustion, performance and emission characteristics of Used Cooking oil Methyl Ester (UCME) and its blends with diesel oil are analyzed in a direct injection C.I. engine. The fuel properties and the combustion characteristics of UCME are found to be similar to those of diesel. A minor decrease in thermal efficiency with significant improvement in reduction of particulates, carbon monoxide and unburnt hydrocarbons is observed compared to diesel. The use of transesterified used cooking oil and its blends as fuel for diesel engines will reduce dependence on fossil fuels and also decrease considerably the environmental pollution. Of the various alternate fuels under consideration, biodiesel is the most promising due to the following reasons: (1) Biodiesel can be used in the existing engine without any modifications. (2) Biodiesel is made entirely from vegetable sources; it does not contain any sulfur, aromatic hydrocarbons, metals or crude oil residues. (3) Biodiesel is an oxygenated fuel; emissions of carbon monoxide and soot tend to reduce. (4) Unlike fossil fuels, the use of biodiesel does not contribute to global warming as CO{sub 2} emitted is once again absorbed by the plants grown for vegetable oil/biodiesel production. Thus CO{sub 2} balance is maintained. (5) The Occupational Safety and Health Administration classifies biodiesel as a non-flammable liquid. (6) The use of biodiesel can extend the life of diesel engines because it is more lubricating than petroleum diesel fuel. (7) Biodiesel is produced from renewable vegetable oils/animal fats and hence improves the fuel or energy security and economy independence.

  10. Distillation of oil-bearing minerals

    Energy Technology Data Exchange (ETDEWEB)

    1952-12-03

    A process of distilling oil-bearing minerals of the type of oil shale which disintegrate during distillation consists of subjecting the subdivided minerals to a distillation temperature in the form of a highly turbulent dense mass fluidized by an upwardly flowing gasiform medium in a distillation zone and supplying the heat required for the distillation by burning solid distillation residue with a combustion-supporting gas in the form of a fluidized mass of solids in a separate combustion zone at a combustion temperature and returning solid combustion residue substantially at the combustion temperature to the distillation zone. Combustion temperature is positively maintained at a figure not exceeding 1,200/sup 0/F and at a figure which is not substantially more than 50/sup 0/F higher than the distillation temperature.

  11. Exhibition of photography from the Estonian diaspora / Ellu Maar

    Index Scriptorium Estoniae

    Maar, Ellu, 1982-

    2010-01-01

    Näitus "Photography from the Estonian Diaspora / Väliseesti foto" Kumu Kunstimuuseumis 8.10.-19.11.2010, kuraatorid Eha Komissarov ja Ellu Maar. Näitus tutvustas 1944. a. Eestist lahkunud või juba võõrsil sündinud fotograafide (Eric Soovere, Karl Hintzer, Priit Vesilind, Rein Välme jt.) loomingut ja valikut väliseesti fotoarhiividest

  12. Biomass utilization for green environment: Co-combustion of diesel fuel and producer gas in thermal application

    International Nuclear Information System (INIS)

    Hussain, A.; Ani, F.N.; Mehamed, A.F.

    2007-01-01

    Study of co-combustion of diesel oil and producer gas from a gasifier, individually as well as combined, in an experimental combustion chamber revealed that the producer gas can be co-combusted with liquid fuel. The process produced more CO, NO/sub x/, SO/sub 2/ and CO/sub 2/ as compared to the combustion of diesel oil alone; the exhaust temperature for the process was higher than the diesel combustion alone. (author)

  13. Premixed Combustion of Coconut Oil on Perforated Burner

    Directory of Open Access Journals (Sweden)

    I.K.G. Wirawan

    2013-10-01

    Full Text Available Coconut oil premixed combustion behavior has been studied experimentally on perforated burner with equivalence ratio (φ varied from very lean until very rich. The results showed that burning of glycerol needs large number of air so that the laminar burning velocity (SL is the highest at very lean mixture and the flame is in the form of individual Bunsen flame on each of the perforated plate hole. As φ is increased the  SL decreases and the secondary Bunsen flame with open tip occurs from φ =0.54 at the downstream of perforated flame. The perforated flame disappears at φ = 0.66 while the secondary Bunsen flame still exist with SL increases following that of hexadecane flame trend and then extinct when the equivalence ratio reaches one or more. Surrounding ambient air intervention makes SL decreases, shifts lower flammability limit into richer mixture, and performs triple and cellular flames. The glycerol diffusion flame radiation burned fatty acids that perform cellular islands on perforated hole.  Without glycerol, laminar flame velocity becomes higher and more stable as perforated flame at higher φ. At rich mixture the Bunsen flame becomes unstable and performs petal cellular around the cone flame front. Keywords: cellular flame; glycerol; perforated flame;secondary Bunsen flame with open tip; triple flame

  14. Estonian Airi ümber käib lehmakauplemine / Tõnu Lilleorg

    Index Scriptorium Estoniae

    Lilleorg, Tõnu

    2008-01-01

    Skandinaavia lennukompanii SAS saatis Eesti valitsusele kirja, milles teatab, et on nõus raskustes Estonian Airile lisainvesteeringuid tegema vaid siis, kui riik müüb SAS-ile oma osaluse, 34%. Vt. samas: SAS ei taha lennufirma eest maksta üle 150 miljoni. Diagramm: Majandusnäitajad, omanikud

  15. Spatial patterns of soil organic carbon stocks in Estonian arable soils

    Science.gov (United States)

    Suuster, Elsa; Astover, Alar; Kõlli, Raimo; Roostalu, Hugo; Reintam, Endla; Penu, Priit

    2010-05-01

    Soil organic carbon (SOC) determines ecosystem functions, influencing soil fertility, soil physical, chemical and biological properties and crop productivity. Therefore the spatial pattern of SOC stocks and its appropriate management is important at various scales. Due to climate change and the contribution of carbon store in the soils, the national estimates of soil carbon stocks should be determined. Estonian soils have been well studied and mapped at a scale 1:10,000. Previous studies have estimated SOC stocks based on combinations of large groups of Estonian soils and the mean values of the soil profile database, but were not embedded into the geo-referenced databases. These studies have estimated SOC stocks of Estonian arable soils 122.3 Tg. Despite of available soil maps and databases, this information is still very poorly used for spatial soil modelling. The aim of current study is to assess and model spatial pattern of SOC stocks of arable soils on a pilot area Tartu County (area 3089 sq km). Estonian digital soil map and soil monitoring databases are providing a good opportunity to assess SOC stocks at various scales. The qualitative nature of the initial data from a soil map prohibits any straightforward use in modelling. Thus we have used several databases to construct models and linkages between soil properties that can be integrated into soil map. First step was to reorganize the soil map database (44,046 mapping units) so it can be used as an input to modelling. Arable areas were distinguished by a field layer of Agricultural Registers and Information Board, which provides precise information of current land use as it is the basis of paying CAP subsidies. The estimates of SOC content were found by using the arable land evaluation database of Tartu from the Estonian Land Board (comprising 950 sq km and 31,226 fields), where each soil type was assessed separately and average SOC content grouped by texture was derived. SOC content of epipedon varies in

  16. Combustion Performance and Exhaust Emission of DI Diesel Engine Using Various Sources of Waste Cooking Oil

    Science.gov (United States)

    Afiq, Mohd; Azuhairi, Mohd; Jazair, Wira

    2010-06-01

    In Malaysia, more than 200-tone of cooking oil are used by domestic users everyday. After frying process, about a quarter of these cooking oil was remained and drained into sewage system. This will pollutes waterways and affects the ecosystem. The use of waste cooking oil (WCO) for producing bio-diesel was considered in economical factor which current production cost of bio-diesel production is higher in Malaysia due to higher price of palm oil. Thus, the aim of this study is to investigate the most suitable source of WCO to become a main source of bio-diesel for bio-diesel production in this country. To perform this research, three type of WCO were obtained from house's kitchen, cafeteria and mamak's restaurant. In this study, prospect of these bio-diesel source was evaluated based on its combustion performance and exhaust emissions operated in diesel engine in the form of waste cooking oil methyl ester (WCOME) and have been compared with pure diesel fuel. A 0.6 liter, single-cylinder, air-cooled direct injection diesel engine was used to perform this experiment. Experiment was done at variable engine loads and constant engine speed. As the result, among three stated WCOMEs, the one collected from house's kitchen gives the best performance in term of brake specific fuel consumption (bsfc) and brake power (BP) with lowest soot emission.

  17. Performance evaluation of small scale internal combustion engine with mixtures for diesel oil-palm oil; Avaliacao do desempenho do motor de combustao interna de pequeno porte com misturas oleo diesel - oleo de dende

    Energy Technology Data Exchange (ETDEWEB)

    Seye, Omar; Souza, Rubem Cesar Rodrigues [Universidade Federal do Amazonas (CDEAM/UFAM), Manaus, AM (Brazil). Centro de Desenvolvimento Energetico Amazonico], Emails: Seye62omar@yahoo.com, rcsouza@internext.com.br

    2006-07-01

    This work aims at the performance evaluation of the Cummins 4B -3.9, an internal combustion engine of maximum power 75 hp (56.6 kW) for small scale power generation, burning different mixtures of diesel fuel and palm oil. The palm oil in nature is mixed manually, what unfortunately will influence the engine performance as it hinders the combustion. The test protocol will include the biodiesel, later on. The emissions were assessed for several proportions of mixture diesel/palm oil covering the strip from 0 to 20% and the results were compared to the engine performance when it operates with diesel only. The motor is coupled to a dynamometer, whose operation consists of the acceleration and deceleration of water in order to simulate the effect of a load being applied to the motor. The system is controlled by the software LT commander that allows the start up and the shutdown of the engine from the screen of the computer that also monitors the following parameters as speed of rotation of the motor (RPM), applied torque (N-m), potency (hp), temperature of the lubricating oil, temperature of the water in the entrance and exit of the motor, and temperature of the environment (deg C), pressures of the lubricating oil and of opening of the injector (mBar). While a flow meter coupled to the piping measures the consumption of fuel, the gas analyzer ECHO Line 6000 it monitors the concentration and temperature of carbon monoxide (CO) (ppm), nitric oxide (NO) (ppm), nitrogen dioxide (NO{sub 2}), (ppm), sulfur dioxide (SO{sub 2}) (ppm) and Oxygen (O{sub 2}) (%) in the exhaust gases. This equipment also determines the combustion parameters as excess of air and the efficiency. The technical results present the efficiency variation, the pressure of the fuel, monoxide carbon, NOx emissions, Oxygen content in the exhaust gases, for the different mixture proportions. Furthermore, the results of economic viability show generation cost values of US$ 135,66/MWh for the motor operating

  18. Comparison of knowledge, attitudes and behaviour regarding smoking among Estonian and Finnish physicians.

    Science.gov (United States)

    Pärna, Kersti; Rahu, Kaja; Barengo, Noël C; Rahu, Mati; Sandström, Patrick H; Jormanainen, Vesa J; Myllykangas, Markku T

    2005-01-01

    To compare smoking behaviour, attitudes and opinions towards smoking and smoking cessation among Estonian and Finnish physicians. A cross-sectional postal survey using a self-administered questionnaire was carried out among 2,480 Estonian and 2,075 Finnish physicians. Daily smoking prevalence was higher among Estonian physicians than among their Finnish counterparts in both male (18.6% and 6.7%) and female (6.6% and 3.6%). Compared to Estonia, physicians in Finland more often agreed that smoking is very harmful to their health, that trying to convince people to stop smoking is their responsibility and that smoking prevention should be part of the normal and special training of health professionals. In both countries, non-smoking physicians held more unfavourable attitudes towards smoking than those who were smoking. Physicians' own smoking patterns and quitting behaviour are important because physicians serve as models for their patients and play a key role in the reinforcement of smoke-free health facilities. These results remain a challenge to medical educators, especially in Estonia. Estonia needs to improve medical education in terms of motivating physicians to ask about the smoking patterns of their patients and of training medical students and resident physicians to counsel their patients to stop smoking.

  19. Towards The Operational Oceanographic Model System In Estonian Coastal Sea, Baltic Sea

    Science.gov (United States)

    Kõuts, T.; Elken, J.; Raudsepp, U.

    An integrated system of nested 2D and 3D hydrodynamic models together with real time forcing data asquisition is designed and set up in pre-operational mode in the Gulf of Finland and Gulf of Riga, the Baltic Sea. Along the Estonian coast, implicit time-stepping 3D models are used in the deep bays and 2D models in the shallow bays with ca 200 m horizontal grid step. Specific model setups have been verified by in situ current measurements. Optimum configuration of initial parameters has been found for certain critical locations, usually ports, oil terminals, etc. Operational system in- tegrates also section of historical database of most important hydrologic parameters in the region, allowing use of certain statistical analysis and proper setup of initial conditions for oceanographic models. There is large variety of applications for such model system, ranging from environmental impact assessment at local coastal sea pol- lution problems to forecast of offshore blue algal blooms. Most probable risk factor in the coastal sea engineering is oil pollution, therefore current operational model sys- tem has direct custom oriented output the oil spill forecast for critical locations. Oil spill module of the operational system consist the automatic weather and hydromet- ric station (distributed in real time to internet) and prognostic model of sea surface currents. System is run using last 48 hour wind data and wind forecast and estimates probable oil deposition areas on the shoreline under certain weather conditions. Cal- culated evolution of oil pollution has been compared with some real accidents in the past and there was found good agreement between model and measurements. Graphi- cal user interface of oil spill model is currently installed at location of port authorities (eg. Muuga port), so in case of accidents it could be used in real time supporting the rescue operations. In 2000 current pre-operational oceanographic model system has been sucessfully used to

  20. Az észt névtervezés az észt nyelvpolitikai modell tükrében [The name management in the mirror of the Estonian LPP-model

    OpenAIRE

    Pomozi, Péter; Földesi, Eszter

    2016-01-01

    The Estonian model of language planning and policy, which has been serving the development and protection of the Estonian language in its current form since 2004, is one of the most successful of such strategies in Europe. It owes it success to the broad social and scientific consensus reached in questions of language policy, regardless of changes in government. The Development Plan of the Estonian Language divides Estonian language planning and policy into three parts: status planning, corpu...

  1. Identity and Othering in Past and Present: Representations of the Soviet Era in Estonian Post-Soviet Textbooks

    Directory of Open Access Journals (Sweden)

    Katrin Kello

    2018-02-01

    Full Text Available This paper analyses representations of the ‘core Soviet era’ (1945-1985 in Estonian post-Soviet history textbooks (1989-2016. Attitudes towards the Soviet system have been a rich resource for identity building, and hence a powerful political tool across the whole of the post-Soviet block. Based on an analysis of sections about the Soviet era in Estonia in 21 textbooks, the paper takes a look at how textbooks reflect broader processes of social meaning making, identity building and othering after a profound social and political turn. In 1989 and during the early 1990s, perspectives and narratives in Estonian history textbooks were closely related to social memory and national politics, enacting a specific social representation of the Soviet era that dominated the Estonian-speaking public space during the 1990s. The Soviet era, Russia and local Russians became the main Others for Estonia and Estonians. Over time, public discourse has diversified. The national curriculum and textbooks, however, still maintain the canon that formed in 1990s and thus reflect earlier sentiments. Apart from the increasing salience of Soviet-era daily life in more recent textbooks, the thematic choices and emphases have changed little since the 1990s. Therefore, even if the style of writing has ‘cooled down’, issues of identity preservation, resistance and accommodation, together with a saliently negative representation of wrongdoings by the Soviet system, still prevail. On the one hand, this testifies to the resilience of an established tradition in the textbook genre in general. On the other hand, it reflects the dominance of an ethnocentric tradition in Estonian history textbook writing. The paper discusses the implications of these findings for interethnic relations in Estonia.

  2. Combustion of jojoba methyl ester in an indirect injection diesel engine

    Energy Technology Data Exchange (ETDEWEB)

    Selim, M.Y.E. [United Arab Emirates University, Al-Ain (United Arab Emirates). Mechanical Engineering Dept.; Radwan, M.S.; Elfeky, S.M.S. [Helwan University, Cairo (Egypt). Mechanical Power Engineering Dept.

    2003-07-01

    An experimental investigation has been carried out to examine for the first time the performance and combustion noise of an indirect injection diesel engine running with new fuel derived from pure jojoba oil, jojoba methyl ester, and its blends with gas oil. A Ricardo E6 compression swirl diesel engine was fully instrumented for the measurement of combustion pressure and its rise rate and other operating parameters. Test parameters included the percentage of jojoba methyl ester in the blend, engine speed, load, injection timing and engine compression ratio. Results showed that the new fuel derived from jojoba is generally comparable and a good replacement to gas oil in diesel engine at most engine operating conditions, in terms of performance parameters and combustion noise produced. (author)

  3. Effects of Pilot Injection Timing and EGR on Combustion, Performance and Exhaust Emissions in a Common Rail Diesel Engine Fueled with a Canola Oil Biodiesel-Diesel Blend

    Directory of Open Access Journals (Sweden)

    Jun Cong Ge

    2015-07-01

    Full Text Available Biodiesel as a clean energy source could reduce environmental pollution compared to fossil fuel, so it is becoming increasingly important. In this study, we investigated the effects of different pilot injection timings from before top dead center (BTDC and exhaust gas recirculation (EGR on combustion, engine performance, and exhaust emission characteristics in a common rail diesel engine fueled with canola oil biodiesel-diesel (BD blend. The pilot injection timing and EGR rate were changed at an engine speed of 2000 rpm fueled with BD20 (20 vol % canola oil and 80 vol % diesel fuel blend. As the injection timing advanced, the combustion pressure, brake specific fuel consumption (BSFC, and peak combustion pressure (Pmax changed slightly. Carbon monoxide (CO and particulate matter (PM emissions clearly decreased at BTDC 20° compared with BTDC 5°, but nitrogen oxide (NOx emissions increased slightly. With an increasing EGR rate, the combustion pressure and indicated mean effective pressure (IMEP decreased slightly at BTDC 20° compared to other injection timings. However, the Pmax showed a remarkable decrease. The BSFC and PM emissions increased slightly, but the NOx emission decreased considerably.

  4. Development of a breeding objective for Estonian Holstein cattle

    Directory of Open Access Journals (Sweden)

    E. PÄRNA

    2008-12-01

    Full Text Available Economic weights for milk carrier (water plus lactose, fat and protein yields, calving interval, age at first service, interval between the first service and conception of heifers and length of productive life of Estonian Holsteins were estimated under assumed milk production quota and for non-quota conditions. A bio-economic model of an integrated production system of a closed herd was used. Economic values of milk carrier yield and length of productive life differed between quota and non-quota conditions, but there were only minor differences between those marketing systems in economic values for functional traits. The standardised economic values of the most important traits varied in magnitude between18 to 81% of the economic value for milk yield. Discounting had a substantial impact on the economic value of length of productive life. When defining the breeding objective for Estonian Holstein, the interval between the first service and conception of heifers, and the length of productive life should be included in the breeding goal along with the traits with the highest economic value, milk, fat and protein yield. In the optimum breeding objective, relative weights of production vs. functional traits were 79 and 21%, respectively.;

  5. Particulate and un burned carbon emissions reduction from oil fired boilers using combustion promoters

    Energy Technology Data Exchange (ETDEWEB)

    Balsiger, Andreas; Carvalho, Jose Guilherme de [ACOTEQ, Rio de Janeiro, RJ (Brazil)

    1993-12-31

    This paper describes the results obtained in the tests carried out with a combustion promoter on a 530 MW utility boiler, in order to reduce solid particle emissions in steady state and transient operations. Tests have been performed at Unit II of Bahia de Algeciras Power Station, owned by Sevillana de Electricidad. Sevillana de Electricidad activities include the production, transmission and distribution of electric power. The distribution area is 40000 square miles (aprox. 20% of peninsular Spains territory).Companys total capacity is 4400 MW, of which 1476 are fuel-oil fired. The demand for electricity in the market served by Sevillana has been 18345 GWh in 1989. Fuel-oil plants output was only 1,6% of total demand in accordance with Spanish energy policy guidelines. Along tests described in this paper, steady state emission, are expected to be reduced due to depletion of the un burned carbon content in particulates. Transient operation emissions should also be reduced if the boiler is kept clean to eliminating soot blowing requirements. (author) 9 refs., 6 figs., 5 tabs.

  6. Trends in smoking behaviour among Estonian physicians in 1982-2014.

    Science.gov (United States)

    Pärna, Kersti; Põld, Mariliis; Ringmets, Inge

    2017-07-25

    Smoking surveys among physicians have proved useful in highlighting the importance of physicians as healthy life style exemplars and role models in tobacco control and smoking cessation. The aim of this study was to give an overview of smoking behaviour among Estonian physicians from 1982 to 2014. Three cross-sectional postal surveys using a self-administered questionnaire were carried out among all practising physicians in Estonia. The number of physicians participating in this study was 3786 in 1982, 2735 in 2002, and 2902 in 2014. Data analysis involved calculating the age-standardized prevalences of smoking, prevalences of smoking by age group and mean age of smoking initiation. A non-parametric test for trend was used to assess significant changes in smoking over time. Age-standardized prevalence of current smoking among men was 39.7% in 1982, 20.9% in 2002, and 14.3% in 2014 and among women 12.2%, 8.0%, and 5.2%, respectively (p smoking among men and women was in age groups under 35 (from 55.2% to 16.7% and from 16.7% to 2.8%, respectively) and 35-44 (from 47.1% to 8.3% and from 19.5% to 5.1%, respectively) (p smoking initiation decreased from 20.4 to 19.3 among men and from 24.5 to 20.4 among women over the study period. In 1982-2014, smoking prevalence among Estonian physicians declined substantially. This may influence the willingness of society to recognize the health consequences of smoking which could give a support to the decline of the smoking epidemic in the country. Differences between smoking among male and female physicians persisted over the study period, but mean age of smoking initiation decreased. A further decline in smoking among Estonian physicians should be encouraged by special efforts targeted at physicians.

  7. Field trial on glucose-induced insulin and metabolite responses in Estonian Holstein and Estonian Red dairy cows in two herds

    Directory of Open Access Journals (Sweden)

    Kaart Tanel

    2010-01-01

    Full Text Available Abstract Background Insulin secretion and tissue sensitivity to insulin is considered to be one of the factors controlling lipid metabolism post partum. The objective of this study was to compare glucose-induced blood insulin and metabolite responses in Estonian Holstein (EH, n = 14 and Estonian Red (ER, n = 14 cows. Methods The study was carried out using the glucose tolerance test (GTT performed at 31 ± 1.9 days post partum during negative energy balance. Blood samples were obtained at -15, -5, 5, 10, 20, 30, 40, 50 and 60 min relative to infusion of 0.15 g/kg BW glucose and analysed for glucose, insulin, triglycerides (TG, non-esterified fatty acids (NEFA, cholesterol and β-hydroxybutyrate (BHB. Applying the MIXED Procedure with the SAS System the basal concentration of cholesterol, and basal concentration and concentrations at post-infusion time points for other metabolites, area under the curve (AUC for glucose and insulin, clearance rate (CR for glucose, and maximum increase from basal concentration for glucose and insulin were compared between breeds. Results There was a breed effect on blood NEFA (P P P P P P th min nadir (P th min postinfusion (P Conclusion Our results imply that glucose-induced changes in insulin concentration and metabolite responses to insulin differ between EH and ER dairy cows.

  8. Organizational Commitment in Estonian University Libraries: A Review and Survey

    Science.gov (United States)

    Kont, Kate-Riin; Jantson, Signe

    2014-01-01

    The data used in this article is based on the reviewing of relevant literature to provide an overview of the concepts of organizational commitment, job security, and interpersonal relations, as well as on the results of the original online survey, conducted by the article's authors, held in 2012 in Estonian university libraries governed by public…

  9. Experimental and analytical investigation on the emission and combustion characteristics of CI engine fueled with tamanu oil methyl esters

    Directory of Open Access Journals (Sweden)

    Perumal Navaneetha Krishnan

    2016-01-01

    Full Text Available The emission and combustion characteristics of a four stroke multi fuel single cylinder variable compression ratio engine fueled with tamanu oil methyl ester and its blends 10%, 20%, 40%, and 60% with diesel (on volume basis are examined and compared with standard diesel. Biodiesel produced from tamanu oil by trans-esterification process has been used in this study. The experiment has been conducted at a constant engine speed of 1500 rpm with 50% load and at compression ratios of 16:1, 17:1, 18:1, 19:1, and 20:1. With different blend and for selected compression ratio the exhaust gas emissions such as CO, HC, NOx, CO2, and the combustion characteristics are measured. The variation of the emission parameters for different compression ratios and for different blends is given, and optimum compression ratio which gives best performance has been identified. The results indicate higher rate of pressure rise and minimum heat release rate at higher compression ratio for tamanu oil methyl ester when compared with standard diesel. The blend B40 for tamanu oil methyl ester is found to give minimum emission at 50% load. The blend when used as fuel results in reduction of polluting gases like HC, CO, and increase in NOx emissions. The previously mentioned emission parameters have been validated with the aid of artificial neural network. A separate model is developed for emission characteristics in which compression ratio, blend percentage and load percentage were used as the input parameter whereas CO, CO2, HC, and NOx were used as the output parameter. This study shows that there is a good correlation between the artificial neural network predicted values and the experimental data for different emission parameters.

  10. Estonian folk traditional experiences on natural anticancer remedies: from past to the future.

    Science.gov (United States)

    Sak, Katrin; Jürisoo, Kadi; Raal, Ain

    2014-07-01

    Despite diagnostic and therapeutic advancements, the burden of cancer is still increasing worldwide. Toxicity of current chemotherapeutics to normal cells and their resistance to tumor cells highlights the urgent need for new drugs with minimal adverse side effects. The use of natural anticancer agents has entered into the area of cancer research and increased efforts are being made to isolate bioactive products from medicinal plants. To lead the search for plants with potential cytotoxic activity, ethnopharmacological knowledge can give a great contribution. Therefore, the attention of this review is devoted to the natural remedies traditionally used for the cancer treatment by Estonian people over a period of almost 150 years. Two massive databases, the first one stored in the Estonian Folklore Archives and the second one in the electronic database HERBA ( http://herba.folklore.ee/ ), containing altogether more than 30 000 ethnomedicinal texts were systematically reviewed to compile data about the Estonian folk traditional experiences on natural anticancer remedies. As a result, 44 different plants with potential anticancer properties were elicited, 5 of which [Angelica sylvestris L. (Apiaceae), Anthemis tinctoria L. (Asteraceae), Pinus sylvestris L. (Pinaceae), Sorbus aucuparia L. (Rosaceae), and Prunus padus L. (Rosaceae)] have not been previously described with respect to their tumoricidal activities in the scientific literature, suggesting thus the potential herbal materials for further investigations of natural anticancer compounds.

  11. Flash pyrolysis fuel oil: BIO-POK

    Energy Technology Data Exchange (ETDEWEB)

    Gust, S. [Neste Oy, Porvoo (Finland)

    1995-12-31

    Flash pyrolysis oil from Ensyn Tech., Canada and Union Fenosa, Spain was combusted with simple pressure atomisation equipment commonly used with light fuel oils in intermediate size (0.1-1 MW) boilers. With a number of modifications to the combustion system, carbon monoxide (CO) and nitrous oxide (NO{sub x}) could be reduced to acceptable levels: CO < 30 ppm and NO{sub x} < 140 ppm. Particulate emissions which were initially very high (Bacharach 4-5) were reduced (Bach. 2-3) by system changes but are still higher than from light fuel oil (Bach. <1). The modifications to the combustion system were: acid resistant progressive cavity pump, higher oil preheat temperature and higher oil pressure than for light fuel oils, refractory section between burner and boiler warmed up to at least 800 deg C. In addition, it was necessary to store pyrolysis oil samples under inert conditions to prevent oxidation and to rinse nozzles with alcohol after shutdown to prevent coking. The complexity and cost of these system modifications are considered to be too great for current grades of flash pyrolysis oil to be sold as a light fuel oil replacement. Improvements to fuel quality will be necessary. The main improvements are lowering of viscosity and improving of stability

  12. Flash pyrolysis fuel oil: BIO-POK

    Energy Technology Data Exchange (ETDEWEB)

    Gust, S [Neste Oy, Porvoo (Finland)

    1996-12-31

    Flash pyrolysis oil from Ensyn Tech., Canada and Union Fenosa, Spain was combusted with simple pressure atomisation equipment commonly used with light fuel oils in intermediate size (0.1-1 MW) boilers. With a number of modifications to the combustion system, carbon monoxide (CO) and nitrous oxide (NO{sub x}) could be reduced to acceptable levels: CO < 30 ppm and NO{sub x} < 140 ppm. Particulate emissions which were initially very high (Bacharach 4-5) were reduced (Bach. 2-3) by system changes but are still higher than from light fuel oil (Bach. <1). The modifications to the combustion system were: acid resistant progressive cavity pump, higher oil preheat temperature and higher oil pressure than for light fuel oils, refractory section between burner and boiler warmed up to at least 800 deg C. In addition, it was necessary to store pyrolysis oil samples under inert conditions to prevent oxidation and to rinse nozzles with alcohol after shutdown to prevent coking. The complexity and cost of these system modifications are considered to be too great for current grades of flash pyrolysis oil to be sold as a light fuel oil replacement. Improvements to fuel quality will be necessary. The main improvements are lowering of viscosity and improving of stability

  13. HIV testing and counselling in Estonian prisons, 2012 to 2013: aims, processes and impacts.

    Science.gov (United States)

    Kivimets, K; Uuskula, A

    2014-11-27

    We present data from an observational cohort study on human immunodeficiency virus (HIV) prevention and control measures in prisons in Estonia to assess the potential for HIV transmission in this setting. HIV testing and retesting data from the Estonian prison health department were used to estimate HIV prevalence and incidence in prison. Since 2002, voluntary HIV counselling and testing has routinely been offered to all prisoners and has been part of the new prisoners health check. At the end of 2012, there were 3,289 prisoners in Estonia, including 170 women: 28.5% were drug users and 15.6% were infected with HIV. Of the HIV-positive inmates, 8.3% were newly diagnosed on prison entry. In 2012, 4,387 HIV tests (including retests) were performed in Estonian prisons. Among 1,756 initially HIV-negative prisoners who were in prison for more than one year and therefore tested for HIV twice within 12 months (at entry and annual testing), one new HIV infection was detected, an incidence of 0.067 per 100 person-years (95% confidence interval (CI): 0.025–5.572). This analysis indicates low risk of HIV transmission in Estonian prisons. Implementation of HIV management interventions could impact positively on the health of prisoners and the communities to which they return.

  14. PERFORMANCE, EMISSION, AND COMBUSTION CHARACTERISTICS OF A CI ENGINE USING LIQUID PETROLEUM GAS AND NEEM OIL IN DUAL FUEL MODE

    Directory of Open Access Journals (Sweden)

    Palanimuthu Vijayabalan

    2010-01-01

    Full Text Available Increased environmental awareness and depletion of resources are driving the industries to develop viable alternative fuels like vegetable oils, compresed natural gas, liquid petroleum gas, producer gas, and biogas in order to provide suitable substitute to diesel for compression ignition engine. In this investigation, a single cylinder, vertical, air-cooled diesel engine was modified to use liquid petroleum gas in dual fuel mode. The liquefied petroleum gas, was mixed with air and supplied through intake manifold. The liquid fuel neem oil or diesel was injected into the combustion chamber. The performance, emission, and combustion characteristics were studied and compared for neat fuel and dual fuel mode. The experimental results on dual fuel engine show a reduction in oxides of nitrogen up to 70% of the rated power and smoke in the entire power range. However the brake thermal efficiency was found decreased in low power range due to lower calorific value of liquid petroleum gas, and increase in higher power range due to the complete burning of liquid petroleum gas. Hydrocarbon and carbon monoxide emissions were increased significantly at lower power range and marginal variation in higher power range.

  15. Unraveling advanced compression ignition combustion using optical diagnostics

    OpenAIRE

    Zegers, R.P.C.

    2012-01-01

    Despite the expected upsurge of hybrid and electric cars in the coming decades, internal combustion will remain the main power supply for (long-distance) transport. Buses, trucks, ships and airplanes will still rely on combustion engines. Nevertheless, emission legislation is becoming more stringent and the oil price continues to rise. Consequently, there still exists a serious interest in new developments that may improve combustion efficiency and fuel flexibility, and reduce emissions; both...

  16. Working group report: methane emissions from fuel combustion and industrial processes

    International Nuclear Information System (INIS)

    Berdowski, J.J.M.; Beck, L.; Piccot, S.; Olivier, J.G.J.; Veldt, C.

    1993-01-01

    This paper lists the source categories which are currently recognised as minor sources of methane. These fall into five broad groups: stationary fuel combustion (residential combustion of fuels, solid waste incineration at home sites, on-site agricultural waste burning, industrial and utility combustion of coal, wood, oil and gas, commercial and industrial waste incineration); mobile fuel combustion; non-combustion industrial processes (primary metals production, chemical manufacturing processes, petroleum refining, commercial charcoal manufacturing waste treatments); minor energy production sources (storage and distribution of automotive fuels, geothermal energy production; peat mining operations, oil shale mining operations); and miscellaneous sources. The paper also presents a preliminary estimate of global methane emissions from these minor sources and the results of the working group's discussion on recommendations for the IPCC/OECD methodology and specific research needs. A list of control options for emissions from minor sources is provided. 2 tabs

  17. [Pärtel Lippus. The acoustic features and perception of the Estonian quantity system] / Stefan Werner

    Index Scriptorium Estoniae

    Werner, Stefan

    2012-01-01

    Arvustus: Pärtel Lippus. The acoustic features and perception of the Estonian quantity system. Tartu : Tartu University Press, 2011. (Dissertationes philologiae estonicae Universitatis Tartuensis ; 29)

  18. Eesti autobiograafilise kirjutuse kujunemisest 18. sajandist Teise maailmasõjani. The Development of Estonian Autobiographical Writing from the 18th Century to the Second World War

    Directory of Open Access Journals (Sweden)

    Rutt Hinrikus

    2012-04-01

    Full Text Available In this article I examine the development of Estonian autobiographical writing from its first manifestations to published memoirs, and the development of life writing and its diversification. The beginnings of life writing can be traced back to Estonian folk song and Estonian incidental poetry. The Moravian Brethren movement in Estonia in the 18th century promoted the spread of canonical autobiography. The Moravian Brethren offered alternative opportunities for self-realisation for Estonians who were serfs, and were therefore popular with the people. The practice of the Moravian Brethren made use of retelling and writing about the life of the congregation members, which sometimes became suitable biographies in print, especially stories of awakening. Several manuscript biographies have survived from the Brethren times, such as the biographies of Mäletu Jaan and Mihkel Sarapuu. In addition to the history of the Moravian Brethren movement, these biographies give information about the educational situation and living conditions of the people of the time. The Estonian life writing tradition emerged within the reigning Baltic German cultural space thanks to the Estophiles among the Baltic Germans (J. H. Rosenplänter and the first Estonian men of letters; from the early 19th century we have the diary by Rosenplänter, an estophile pastor from Pärnu, and the diary by the Estonian poet, the then-student Kristjan Jaak Peterson, both in the Estonian language. Johann Voldemar Jannsen, the founder of Estonian-language journalism, kept a diary in the German language for a longer period of time; it was usual that the first Estonian intellectuals (Lilli Suburg, and others in the late 19th century wrote in German. Admittedly, the first Estonian-language life history was written by a forward-looking 19th century peasant named Märt Mitt (1833-1912, who was conscious of himself as a historical subject and gave his memoirs, begun in the 1880s, a memorable title

  19. Reconstruction of industrial boiler type DKVR-13 aiming for combustion of waste materials from oil-yielding production

    International Nuclear Information System (INIS)

    Gadzhanov, P.

    1997-01-01

    One of the methods for improving of the energy efficiency is the use of a secondary energy resources such as waste products from industrial processes. In case of the oil extraction a great amount of waste product (sunflower shells) with a good thermal potential is available. During the industrial process from 100 kg raw material 15 kg shells are obtained. The combustion heat is about 1700 kJ/kg. The volatile compounds yield is 66.1%. An installation has been constructed intended to use the waste product from the extraction, consisting of: a water tube boiler with a steam capacity of 20 t/h and two PKM-12 type flue boilers and two DKVR 10-13 type water tube boilers. The DKVR 10-13 type boilers are designed for the production of 22.77 kg/s saturated steam with pressure 1.28 MPa and temperature 194 o C. They have an unified constructional schemes with a two-drum evaporating system and a natural circulation. The furnace has a horizontally evaporation beam washed by the gas flux. The reconstruction is aimed to create condition for the use of the sunflower shells as a main fuel and the natural gas or other fuel as additional. The scheme is one using the sloping bed combustion. 70% of the steam production is due to the shells combustion. Calculations for the grid parameters have been done. An additional heater improves the efficiency with 4.5% and the expected annual fuel saving is 300 t. The introduction of hot air (165 o C) provides both combustion and ecological benefits

  20. Evaluating possible industrial applications of combustible shales and shale ash wastes

    Directory of Open Access Journals (Sweden)

    Н. К. Кондрашева

    2016-08-01

    Full Text Available Today energy consumption is constantly growing while explored reserves of easily accessible oil are depleting, which is a reason why most countries tend to diversify their energy mix, develop non-hydrocarbon energy sources and use domestic types of fuel, including the low grade ones. Thereby interest is raised to such a source of hydrocarbons as combustible shales. Combustible shales appear to be one of the highest-potential types of organic raw materials, which may offset and in future even substitute oil products and gas. The paper is investigating behavior and structure of combustible shales during heat treatment in order to identify their possible industrial applications. A synchronous thermal analysis has been held, chemical composition of combustible shales’ mineral fraction and optimal conditions for shale fines briquetting have been determined.

  1. Estonian Cell peab suu kasumist puhtaks pühkima / Kaisa Tahlfeld, Katre Pilvinski

    Index Scriptorium Estoniae

    Tahlfeld, Kaisa

    2008-01-01

    Estonian Cell saatis valitsusele pöördumise, milles palutakse teha parandusi elektrienergiaga seonduvates seadustes, mis aitaksid ettevõtet energia hinnatõusu ajal. Elektri hinnatõusu tõttu on muutunud küsitavaks ka Nitroferti tehase edasine eksisteerimine

  2. Serological evidence of exposure to globally relevant zoonotic parasites in the Estonian population

    DEFF Research Database (Denmark)

    Lassen, Brian; Janson, Marilin; Viltrop, Arvo

    2016-01-01

    We investigated Estonian population and its selected subgroups for serological evidence of exposure to Ascaris lumbricoides, Echinococcus spp., Taenia solium, Toxocara canis, Toxoplasma gondii, and Trichinella spiralis. Serum samples from 999 adults representing general population, 248 children a...

  3. Flammability characteristics of combustible gases and vapors

    Energy Technology Data Exchange (ETDEWEB)

    Zabetakis, M. G. [Bureau of Mines, Pittsburgh, PA (United States)

    1964-05-01

    This is a summary of the available limit of flammability, autoignition and burning-rate data for more than 200 combustible gases and vapors in air and other oxidants, as well as of empirical rules and graphs that can be used to predict similar data for thousands of other combustibles under a variety of environmental conditions. Spec$c data are presented on the paraffinic, unsaturated, aromatic, and alicyclic hydrocarbons, alcohols, ethers, aldehydes, ketones, and sulfur compounds, and an assortment of fuels, fuel blends, hydraulic fluids, engine oils, and miscellaneous combustible gases and vapors.

  4. Radium in diesel oil

    International Nuclear Information System (INIS)

    Kulich, J.

    1977-05-01

    In order to determine the addition of radon and radium to the air in mines, originatiny from the combustion of petroleum, measurements of the content of radium in diesel oil have been performed. Knowing the radium content theradon content can easily be calculated. The procedures used for the chemical analysis of radium is desribed. The ash remaining after combustion of the diesel oil is soluted in water and radium is precipiated as sulphate. The radium is detected by a ZnS (Ag) detector. The diesel oils from different petroleum companies contained between o.019-0.5pCi radium - 226. The conclution is that the consumption of diesel oils in motors used in mines does not contribute to the radium - 226 content at the air move than permissible according to norms.(K.K.)

  5. Acquisition of noun derivation in Estonian and Russian L1

    Directory of Open Access Journals (Sweden)

    Reili Argus

    2018-04-01

    Full Text Available Acquisition of derivation is not a well-studied area in first language research and a comparative approach to the acquisition of derivation in different languages doesn’t exist. There is no information on how a child acquires derivation in a language with a rich and regular system of derivational patterns, or in a language where derivation is productive, but the system of derivational patterns is opaque. According to general ideas of complexity in a language, the child should start to use simplex stems first and, only after that, complex ones, that is, complexity should increase in the course of acquisition. Our paper is intended to address these issues, based on longitudinal child data from typologically different languages, Estonian and Russian. The results revealed significant differences in the acquisition of noun derivation in the two languages under observation. The system of noun derivation is acquired at a faster pace in Russian, while Estonian children have far fewer noun derivatives in their speech and they use different derivation suffixes with less regularity. Even so, the so-called building block model may be applied for both languages only partially.

  6. Oil injection into the blast furnace

    Energy Technology Data Exchange (ETDEWEB)

    Dongsheng Liao; Mannila, P.; Haerkki, J.

    1997-12-31

    Fuel injection techniques have been extensively used in the commercial blast furnaces, a number of publications concerning the fuels injection have been reported. This present report only summarizes the study achievements of oil injection due to the research need the of authors, it includes the following parts: First, the background and the reasons reducing coke rate of oil injection are analyzed. Reducing coke rate and decreasing the ironmaking costs are the main deriving forces, the contents of C, H and ash are direct reasons reducing coke rate. It was also found that oil injection had great effects on the state of blast furnace, it made operation stable, center gas flow develop fully, pressure drop increase, descent speed of burden materials decrease and generation of thermal stagnation phenomena, the quality of iron was improved. Based on these effects, as an ideal mean, oil injection was often used to adjust the state of blast furnace. Secondly, combustion behavior of oil in the raceway and tuyere are discussed. The distribution of gas content was greatly changed, the location of CO, H{sub 2} generation was near the tuyere; the temperature peak shifts from near the raceway boundary to the tuyere. Oxygen concentration and blast velocity were two important factors, it was found that increasing excess oxygen ratio 0.9 to 1.3, the combustion time of oil decreases 0.5 msec, an increase of the blast velocity results in increasing the flame length. In addition, the nozzle position and oil rate had large effects on the combustion of oil. Based on these results, the limit of oil injection is also discussed, soot formation is the main reason limiting to further increase oil injection rate, it was viewed that there were three types of soot which were generated under blast furnace operating conditions. The reason generating soot is the incomplete conversion of the fuel. Finally, three methods improving combustion of oil in the raceway are given: Improvement of oil

  7. Tiger in Focus--A National Survey of ICT in Estonian Schools

    Science.gov (United States)

    Toots, Anu; Laanpere, Mart

    2004-01-01

    Estonia has not participated in international studies of ICT in education, nor have there been any similar studies at the national level up until the year 2000. The first survey of ICT in Estonian schools was conducted after completion of the national school computerization programme called Tiger Leap. This paper focuses on the targeted responses…

  8. Consumer Socialisation and Value Orientations among Estonian and Chinese Young People

    Science.gov (United States)

    Waerdahl, Randi; Kalmus, Veronika; Keller, Margit

    2011-01-01

    This paper asks if Estonian and Chinese tweens' access to pocket money influences their brand valuation, as well as value orientations in the context of perceived peer popularity and personal well-being. Surveys conducted in autumns 2006 (China n = 188) and 2007 (Estonia n = 111) show an inherent cultural resistance among tweens in both countries…

  9. Az észt névtervezés az észt nyelvpolitikai modell tükrében [The name management in the mirror of the Estonian LPP-model

    Directory of Open Access Journals (Sweden)

    Pomozi, Péter

    2016-12-01

    Full Text Available The Estonian model of language planning and policy, which has been serving the development and protection of the Estonian language in its current form since 2004, is one of the most successful of such strategies in Europe. It owes it success to the broad social and scientific consensus reached in questions of language policy, regardless of changes in government. The Development Plan of the Estonian Language divides Estonian language planning and policy into three parts: status planning, corpus planning and prestige planning. Name management is a part of corpus planning, although certain aspects are also connected to legal and prestige planning. Name management strategies are present in all components of the Estonian model of language planning and policy, as linguistically appropriate name use is not only a socio-cultural, but economic question, as informative and easy to understand names contribute to measurable economic advantages. The paper mainly demonstrates the dilemmas and answers of Estonian name management through examples from personal name giving practices, but questions concerning the problems of name use in a multicultural environment and the difficulties of place name and firm name management are also discussed.

  10. Enhancing instruction in Fuels and Combustion Laboratory via a developed computer-assisted program for establishing efficient coal-diesel oil mixture (CDOM) fuel proportions

    Energy Technology Data Exchange (ETDEWEB)

    Maglaya, A.B. [La Salle University, Manila (Philippines). Dept. of Mechanical Engineering

    2004-07-01

    This paper discusses the relevance of digital computation in Fuels and Combustion Laboratory experiments used by the senior students of the Department of Mechanical Engineering, De La Salle University-Manila, Philippines. One of the students' experiments involved the determination of the most efficient CDOM fuel proportion as alternative fuel to diesel oil for steam generators and other industrial applications. Theoretical calculations show that it requires tedious and repetitive computations. A computer-assisted program was developed to lessen the time-consuming activities. The formulation of algorithms were based on the system of equations of the heat interaction between the CDOM fuel, combustion air and products of combustion and by applying the principles of mass and energy equations (or the First Law of Thermodynamics) for reacting systems were utilized. The developed computer-assisted program output verified alternative fuel selected through actual experimentation.

  11. Väärikas Estonian Air jäi kampaaniaga hätta / Alyona Stadnik

    Index Scriptorium Estoniae

    Stadnik, Alyona

    2010-01-01

    Estonian Air müüs veebikaupluse cherry.ee kaudu soodsaid kinkekaarte. Vastuolu tekkis asjaolust, et nõudlus kinkekaartide järele oli suurem kui pakkumine. Lennukompanii katkestas soodsate kinkekaartide müügi

  12. Field of genes: the politics of science and identity in the Estonian Genome Project.

    Science.gov (United States)

    Fletcher, Amy L

    2004-04-01

    This case study of the Estonian Genome Project (EGP) analyses the Estonian policy decision to construct a national human gene bank. Drawing upon qualitative data from newspaper articles and public policy documents, it focuses on how proponents use discourse to link the EGP to the broader political goal of securing Estonia's position within the Western/European scientific and cultural space. This dominant narrative is then situated within the analytical notion of the "brand state", which raises potentially negative political consequences for this type of market-driven genomic research. Considered against the increasing number of countries engaging in gene bank and/or gene database projects, this analysis of Estonia elucidates issues that cross national boundaries, while also illuminating factors specific to this small, post-Soviet state as it enters the global biocybernetic economy.

  13. Effects of Canola Oil Biodiesel Fuel Blends on Combustion, Performance, and Emissions Reduction in a Common Rail Diesel Engine

    Directory of Open Access Journals (Sweden)

    Sam Ki Yoon

    2014-12-01

    Full Text Available In this study, we investigated the effects of canola oil biodiesel (BD to improve combustion and exhaust emissions in a common rail direct injection (DI diesel engine using BD fuel blended with diesel. Experiments were conducted with BD blend amounts of 10%, 20%, and 30% on a volume basis under various engine speeds. As the BD blend ratio increased, the combustion pressure and indicated mean effective pressure (IMEP decreased slightly at the low engine speed of 1500 rpm, while they increased at the middle engine speed of 2500 rpm. The brake specific fuel consumption (BSFC increased at all engine speeds while the carbon monoxide (CO and particulate matter (PM emissions were considerably reduced. On the other hand, the nitrogen oxide (NOx emissions only increased slightly. When increasing the BD blend ratio at an engine speed of 2000 rpm with exhaust gas recirculation (EGR rates of 0%, 10%, 20%, and 30%, the combustion pressure and IMEP tended to decrease. The CO and PM emissions decreased in proportion to the BD blend ratio. Also, the NOx emissions decreased considerably as the EGR rate increased whereas the BD blend ratio only slightly influenced the NOx emissions.

  14. A Study on Performance, Combustion and Emission Characteristics of Compression Ignition Engine Using Fish Oil Biodiesel Blends

    Science.gov (United States)

    Ramesha, D. K.; Thimmannachar, Rajiv K.; Simhasan, R.; Nagappa, Manjunath; Gowda, P. M.

    2012-07-01

    Bio-fuel is a clean burning fuel made from natural renewable energy resource; it operates in C. I. engine similar to the petroleum diesel. The rising cost of diesel and the danger caused to the environment has led to an intensive and desperate search for alternative fuels. Among them, animal fats like the fish oil have proven to be a promising substitute to diesel. In this experimental study, A computerized 4-stroke, single cylinder, constant speed, direct injection diesel engine was operated on fish oil-biodiesel of different blends. Three different blends of 10, 20, and 30 % by volume were used for this study. Various engine performance, combustion and emission parameters such as Brake Thermal Efficiency, Brake Specific Fuel Consumption, Heat Release Rate, Peak Pressure, Exhaust Gas Temperature, etc. were recorded from the acquired data. The data was recorded with the help of an engine analysis software. The recorded parameters were studied for varying loads and their corresponding graphs have been plotted for comparison purposes. Petroleum Diesel has been used as the reference. From the properties and engine test results it has been established that fish oil biodiesel is a better replacement for diesel without any engine modification.

  15. Influence de la nature des fuels lourds sur la qualité de leur combustion Influence of Heavy Fuel Oil Composition on Particulate Emissions

    Directory of Open Access Journals (Sweden)

    Feugier A.

    2006-11-01

    heavy fuel oils in a 1 MW boiler and an 0. 1 MW furnace, the conclusion was reached that Conradson carbon residue (CCR of fuel oils is a good indicator of their combustibility, but that it is not sufficient in all cases, i. e. for the same CCR, different values of particulate emissions can be measured. Several possible interpretations were proposed and checked:(a Conradson carbon residue is the result of slow pyrolysis, but it is a procedure that is not sufficiently representative of actual conditions. Yet, by subjecting various fuel oils to flash pyrolysis (heated-grid technique, a good correlation is found between the amount of residue resulting and the CCR. Therefore the CCR remains a good combustibility indicator. (b For fuel oils ex atmospheric residue, ex vacuum residue and ex deasphalting, satisfactory correlations have been observed between CCR and various physicochemical properties of the heavy fractions of fuel oils (cut point of 450°C chosen, i. e. polyaromaticity (measured by carbon 13 NMR, C/H and molecular weight. However, visbreaking fuel oils meet other correlations, as do steam-cracking residues. Hence for these classes of fuel oils, anomalies can be predicted between the particulate emissions and CCR, which is effectively observed with some equipments. (c For the same CCR value, the relative proportion between light and heavy fractions of fuels can sometimes be seen to vary quite appreciably, thus causing changes in the richness and temperature maps of the resulting flames, and hence variations in particulate emissions. The extent of such variations will depend on the types of burners and combustion chambers in which the flame develops.

  16. Estonian Business Schooli magistriharidus nüüd ka koju kätte / Madis Habakuk

    Index Scriptorium Estoniae

    Habakuk, Madis

    2007-01-01

    Sügisest hakkab Estonian Business School koos Mainori Kõrgkooliga pakkuma magistriõpet majandushariduseta inimestele, kus soovijatel on võimalus õppida EBSi Master of Business Administration programmi järgi

  17. The North Cape oil spill assessment: PAHs in oil

    International Nuclear Information System (INIS)

    Brown, J.; Boehm, P. D.; Hardestine, J. H.; Douglas, G. S.

    1997-01-01

    The North Cape oil spill in January 1996 resulted in the release of an estimated 827,000 gallons of No. 2 home heating oil into the nearshore turbulent waters of coastal Rhode Island. The oil was mixed into the water column and was transported on the surface as well as below the surface. Some of the spilled oil entered the coastal ponds behind the beaches. Sampling and chemical analysis for detailed suites of petroleum saturated and polycyclic aromatic hydrocarbons (PAHs) was undertaken as part of the assessment of the fate of the oil spill and of the exposure to the marine environment. The ponds were found to contain significant quantities of background petroleum hydrocarbons, including petrogenic PAHs and combustion PAHs. Initial assessment pointed (incorrectly as it turned out) to widespread contamination due only to the North Cape spill. Application of advanced chemical fingerprinting approaches, and geochemical biomarker data illustrated that many of the PAHs consisted of combustion-related 4- and 5-ringed PAHs, attributable to diesel fuel used routinely by boats in the area. The analysis demonstrated that the use of non-specific total PAH data and insufficient fingerprinting and allocation of petrogenic residues has the potential to overestimate contamination and hence injury to the environment in similar oil spill situations

  18. The Role of Language in (Recreating Tatar Diaspora Identity: The Case of the Estonian Tatars

    Directory of Open Access Journals (Sweden)

    Maarja Klaas

    2015-06-01

    Full Text Available This paper focuses on the meanings assigned to Tatar language among the Tatar diaspora in Estonia. According to interviews with Estonian Tatars as well as descriptions of field material from Tatarstan, language is an important aspect of Tatar ethnic identity. This paper will track common discourses about the Tatar language and the way it is connected to Tatar ethnic identity. Issues concerning Tatar language are used to demonstrate various ways of enacting Tatarness in Estonia. It is shown that Estonian Tatars worry about the vitality and purity of Tatar language, but for some, marginalization of dialects is also an issue. People categorized with the same identity labels by self and others can experience and enact their Tatarness in a variety of different ways.

  19. Combustion and emission characteristics of a dual fuel engine operated with mahua oil and liquefied petroleum gas

    Directory of Open Access Journals (Sweden)

    Nadar Kapilan N.

    2008-01-01

    Full Text Available For the present work, a single cylinder diesel engine was modified to work in dual fuel mode. To study the feasibility of using methyl ester of mahua oil as pilot fuel, it was used as pilot fuel and liquefied petroleum gas was used as primary fuel. In dual fuel mode, pilot fuel quantity and injector opening pressure are the few variables, which affect the performance and emission of dual fuel engine. Hence, in the present work, pilot fuel quantity and injector opening pressure were varied. From the test results, it was observed that the pilot fuel quantity of 5 mg per cycle and injector opening pressure of 200 bar results in higher brake thermal efficiency. Also the exhaust emissions such as smoke, unburnt hydrocarbon and carbon monoxide are lower than other pressures and pilot fuel quantities. The higher injection pressure and proper pilot fuel quantity might have resulted in better atomization, penetration of methyl ester of mahua oil and better combustion of fuel.

  20. E-Banking: Risk Management Practices of the Estonian Banks

    OpenAIRE

    Dmitri Sokolov

    2007-01-01

    During the last years the development of e-banking in Estonia has been very significant. According to the report of the World Economic Forum, the Estonian IT-development has been substantial. The success of e-banking in Estonia can be compared to the corresponding success of the Nordic countries. According to the Deutsche Bank Research, around 70-80% of the Internet users in Estonia use Internet banking and in this respect, Estonia could be compared to Finland, Norway and Iceland. Despite of ...

  1. Results of industrial tests of carbonate additive to fuel oil

    Science.gov (United States)

    Zvereva, E. R.; Dmitriev, A. V.; Shageev, M. F.; Akhmetvalieva, G. R.

    2017-08-01

    Fuel oil plays an important role in the energy balance of our country. The quality of fuel oil significantly affects the conditions of its transport, storage, and combustion; release of contaminants to atmosphere; and the operation of main and auxiliary facilities of HPPs. According to the Energy Strategy of Russia for the Period until 2030, the oil-refining ratio gradually increases; as a result, the fraction of straight-run fuel oil in heavy fuel oils consistently decreases, which leads to the worsening of performance characteristics of fuel oil. Consequently, the problem of the increase in the quality of residual fuel oil is quite topical. In this paper, it is suggested to treat fuel oil by additives during its combustion, which would provide the improvement of ecological and economic indicators of oil-fired HPPs. Advantages of this method include simplicity of implementation, low energy and capital expenses, and the possibility to use production waste as additives. In the paper, the results are presented of industrial tests of the combustion of fuel oil with the additive of dewatered carbonate sludge, which is formed during coagulation and lime treatment of environmental waters on HPPs. The design of a volume delivery device is developed for the steady additive input to the boiler air duct. The values are given for the main parameters of the condition of a TGM-84B boiler plant. The mechanism of action of dewatered carbonate sludge on sulfur oxides, which are formed during fuel oil combustion, is considered. Results of industrial tests indicate the decrease in the mass fraction of discharged sulfur oxides by 36.5%. Evaluation of the prevented damage from sulfur oxide discharged into atmospheric air shows that the combustion of the fuel oil of 100 brand using carbonate sludge as an additive (0.1 wt %) saves nearly 6 million rubles a year during environmental actions at the consumption of fuel oil of 138240 t/year.

  2. Aspen Simulation of Diesel-Biodiesel Blends Combustion

    Directory of Open Access Journals (Sweden)

    Pérez-Sánchez Armando

    2015-01-01

    Full Text Available Biodiesel is a fuel produced by transesterification of vegetable oils or animal fats, which currently is gaining attention as a diesel substitute. It represents an opportunity to reduce CO2, SO2, CO, HC, PAH and PM emissions and contributes to the diversification of fuels in Mexico's energetic matrix. The results of the simulation of the combustion process are presented in this paper with reference to an engine specification KUBOTA D600-B, operated with diesel-biodiesel blends. The physicochemical properties of the compounds and the operating conditions of equipment were developed using the simulator Aspen® and supplementary information. The main aspects of the engine working conditions were considered such as diesel-biodiesel ratio, air/fuel mixture, temperature of the combustion gases and heat load. Diesel physicochemical specifications were taken from reports of PEMEX and SENER. Methyl esters corresponding to the transesterification of fatty acids that comprise castor oil were regarded as representative molecules of biodiesel obtained from chromatographic analysis. The results include CO2, water vapor, combustion efficiency, power and lower calorific value of fuels.

  3. Total lead (Pb) concentration in oil shale ash samples based on correlation to isotope Pb-210 gamma-spectrometric measurements

    Energy Technology Data Exchange (ETDEWEB)

    Vaasma, T.; Kiisk, M.; Tkaczyk, A.H. [University of Tartu (Estonia); Bitjukova, L. [Tallinn University of Technology (Estonia)

    2014-07-01

    Estonian oil shale consists of organic matter and mineral material and contains various amounts of heavy metals as well as natural radionuclides (from the U-238 and Th-232 series and K-40). Previous research has shown that burning oil shale in the large power plants causes these radionuclides to become enriched in different ash fractions and be partially emitted to the atmosphere via fly ash and flue gases. The activity concentrations (Bq/kg) of these nuclides in different oil shale ash fractions vary significantly. This is influenced by the boiler parameters and combustion conditions - prevailing temperatures, pressure, ash circulating mechanisms, fly ash particle size, chemical composition of ash and coexistence of macro and micro components. As with radionuclides, various heavy metals remain concentrated in the ash fractions and are released to the atmosphere (over 20 tons of Pb per year from Estonian oil shale power plants). Lead is a heavy metal with toxic influence on the nervous system, reproductive system and different organs in human body. Depending on the exposure pathways, lead could pose a long term health hazard. Ash samples are highly heterogeneous and exhibit great variability in composition and particle size. Determining the lead concentration in ash samples by modern methods like inductively coupled plasma mass spectroscopy (ICP-MS), flame atomic absorption spectrometry (FAAS), graphite furnace atomic absorption spectroscopy (GFAAS) and other techniques often requires time consuming, multistage and complex chemical sample preparation. The list of possible methods to use is lengthy, but it is a challenge to choose a suitable one to meet measurement needs and practical considerations. The detection limits, capital costs and maintenance expenses vary between the instruments. This work presents the development of an alternative measurement technique for our oil shale ash samples. Oil shale ash was collected from different boilers using pulverized fuel

  4. FY 1994 annual report. Advanced combustion science utilizing microgravity

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-10-01

    Researches on combustion in microgravity were conducted to develop combustion devices for advanced combustion techniques, and thereby to cope with the requirements for diversification of energy sources and abatement of environmental pollution by exhaust gases. This project was implemented under the research cooperation agreement with US's NASA, and the Japanese experts visited NASA's test facilities. NASA's Lewis Research Center has drop test facilities, of which the 2.2-sec drop test facilities are useful for researches by Japan. The cooperative research themes for combustion in microgravity selected include interactions between fuel droplets, high-pressure combustion of binary fuel sprays, and ignition and subsequent flame propagation in microgravity. An ignition test equipment, density field measurement equipment and flame propagation test equipment were constructed in Japan to conduct the combustion tests in microgravity for, e.g., combustion and evaporation of fuel droplets, combustion characteristics of liquid fuels mixed with solid particles, combustion of coal/oil mixture droplets, and estimating flammability limits. (NEDO)

  5. The Newfoundland oil spill burn experiment

    International Nuclear Information System (INIS)

    Fingas, M.

    1992-01-01

    A major offshore oil-spill combustion experiment is being planned for waters off Newfoundland. The experiment is designed to answer outstanding questions on the acceptability of in-situ oil spill burning. In the experiment, variables will be controlled to allow quantitative measurement of the scientific and operational parameters that will enhance understanding of in-situ combustion as an operational oil-spill response technique. The proposed full-scale tests follow six years of testing in laboratory tanks. Analyses have shown that the high temperatures reached during efficient in-situ combustion result in relatively complete destruction of the oil. Tests have shown that the most important factor in this regard is that the oil must be thickened sufficiently before effective burning will occur. Such thickening is potentially possible in the offshore, under suitable wind and sea conditions, using fireproof containment booms. The experiment will involve measurement of emissions to the air, levels of oil in water, and operational parameters of in-situ burning. Time and location of the experiment are chosen to minimize ecological damage and for operational reasons. When suitable conditions are present in early August 1993, two 45-m 3 batches of crude oil will be released into a containment boom and ignited. The burn residue will be recovered mechanically, and a secondary containment and recovery system will be towed behind the fireproof boom to pick up any fugitive oil or residue. 3 figs., 6 tabs

  6. Synthesis by combustion reaction of ZnAl2O4 and application in methyl alcoholysis of soybean oil

    International Nuclear Information System (INIS)

    Dantas, B.B.; Silva, A.S.; Cunha, R.B.L.; Leal, E.; Costa, A.C.F.M.

    2011-01-01

    Biodiesel currently presents itself as a viable alternative to diesel oil front. However, implementation of actions most economic use as heterogeneous catalysts, allows further reduction of this biofuel by procedural steps. This work was supported application of catalytic ZnAl 2 O 4 obtained by combustion reaction in methyl alcoholysis of soybean oil. Samples of the supports were characterized by XRD, textural analysis by nitrogen adsorption and FTIR. The reaction tests were performed at 200°C, molar ratio 1:25, 2 and 4 wt% of catalyst and reaction time of 3 hours. XRD results indicate that the phase was obtained ZnAl 2 O 4 effectively, with surface areas of 14.9 and 8.6 m 2 g -1 . The tests demonstrated that reactional higher content of ester was 56.1 and 63.1% for the percentage of catalyst 2 and 4% respectively. (author)

  7. Applying Thermodynamics to Fossil Fuels: Heats of Combustion from Elemental Compositions.

    Science.gov (United States)

    Lloyd, William G.; Davenport, Derek A.

    1980-01-01

    Discussed are the calculations of heats of combustions of some selected fossil fuel compounds such as some foreign shale oils and United States coals. Heating values for coal- and petroleum-derived fuel oils are also presented. (HM)

  8. Estonian Vocational Teachers' Attitudes towards Inclusive Education for Students with Special Educational Needs

    Science.gov (United States)

    Rose, Richard; Kaikkonen, Leena; Koiv, Kristi

    2007-01-01

    This paper presents the findings from research conducted with two samples of teachers from Estonian Vocational Schools. The first sample comprised a group of teachers who had received professional development directly related to the management of students with special educational needs in vocational education settings. Their attitudes and…

  9. Improvement of fuel combustion technologies

    Energy Technology Data Exchange (ETDEWEB)

    Tumanovskii, A.G.; Babii, V.I.; Enyakin, Y.P.; Kotler, V.R.; Ryabov, G.V.; Verbovetskii, E.K.; Nadyrov, I.I. [All-Russian Thermal Engineering Institute, Moscow (Russian Federation)

    1996-07-01

    The main problems encountered in the further development of fuel combustion technologies at thermal power stations in Russia are considered. Experience is generalized and results are presented on the efficiency with which nitrogen oxide emissions are reduced by means of technological methods when burning natural gas, fuel oil, and coal. The problems that arise in the introduction of new combustion technologies and in using more promising grades of coal are considered. The results studies are presented that show that low grade Russian coals can be burnt in circulating fluidized bed boilers. 14 refs., 5 figs., 4 tabs.

  10. Operation related on-line measurements of low temperature fire side corrosion during co-combustion of biomass and oil; Driftrelaterad direktmaetning av laagtemperaturkorrosion i en braensleeldad kraftvaermeanlaeggning

    Energy Technology Data Exchange (ETDEWEB)

    Eriksson, Thomas [Studsvik Nuclear AB, Nykoeping (Sweden)

    2000-05-01

    A number of combustion plants have experienced corrosion attack on air preheaters and economisers when fired with biomass fuels. In certain plants the problems are great and reconstruction has been performed so that exposed components can be exchanged during operation. The electrochemical techniques offer on-line measurements of the changes in corrosion rate in the low temperature region in a waste incinerator. The purpose with this study was to evaluate the technique in a biomass fired boiler where the corrosion rate is considerable lower compared to a waste incinerator. Experiments were performed at the Haesselby plant, boiler 3, which was fired with pure biomass as well as a mixture of biomass and oil during the test period. It was found that the electrochemical technique is a useful tool for on-line measurements of the changes in corrosion rate in biomass fired utilities. Since the corrosion rate in the low temperature region is dependent on the boiler construction, electrochemical measurements give valuable information on the corrosion rate during optimisation of the fuel mixture, SNCR and temperature or the low temperature components. This is of special importance when introducing new fuels or fuel mixtures. Soot blowing is of prime importance for the total corrosion. During a few minutes an individual soot blower can initiate such a high corrosion rate that it represents the total corrosion. The material temperature is another important parameter. Above a certain temperature the corrosion rate is negligible. During co-combustion this temperature was found to be in the region 65-85 deg C. The influence of the SNCR with ammonia, with respect to corrosion, is dependent on the fuel mixture used. In utilities where acidic combustion products are formed, ammonia has a neutralising effect e.g. in Hoegdalen. At the Haesselby plant this neutralising effect was not found. During cocombustion with oil the ammonia forms ammoniahydrosulphate which increases the corrosion

  11. Numerical investigation of the flow inside the combustion chamber of a plant oil stove

    Science.gov (United States)

    Pritz, B.; Werler, M.; Wirbser, H.; Gabi, M.

    2013-10-01

    Recently a low cost cooking device for developing and emerging countries was developed at KIT in cooperation with the company Bosch und Siemens Hausgeräte GmbH. After constructing an innovative basic design further development was required. Numerical investigations were conducted in order to investigate the flow inside the combustion chamber of the stove under variation of different geometrical parameters. Beyond the performance improvement a further reason of the investigations was to rate the effects of manufacturing tolerance problems. In this paper the numerical investigation of a plant oil stove by means of RANS simulation will be presented. In order to reduce the computational costs different model reduction steps were necessary. The simulation results of the basic configuration compare very well with experimental measurements and problematic behaviors of the actual stove design could be explained by the investigation.

  12. Combustion of Biogas Released from Palm Oil Mill Effluent and the Effects of Hydrogen Enrichment on the Characteristics of the Biogas Flame

    Directory of Open Access Journals (Sweden)

    Seyed Ehsan Hosseini

    2015-01-01

    Full Text Available Biogas released from palm oil mill effluent (POME could be a source of air pollution, which has illustrated negative effects on the global warming. To protect the environment from toxic emissions and use the energy of POME biogas, POME is conducted to the closed digestion systems and released biogas is captured. Since POME biogas upgrading is a complicated process, it is not economical and thus new combustion techniques should be examined. In this paper, POME biogas (40% CO2 and 60% CH4 has been utilized as a fuel in a lab-scale furnace. A computational approach by standard k-ε combustion and turbulence model is applied. Hydrogen is added to the biogas components and the impacts of hydrogen enrichment on the temperature distribution, flame stability, and pollutant formation are studied. The results confirm that adding hydrogen to the POME biogas content could improve low calorific value (LCV of biogas and increases the stability of the POME biogas flame. Indeed, the biogas flame length rises and distribution of the temperature within the chamber is uniform when hydrogen is added to the POME biogas composition. Compared to the pure biogas combustion, thermal NOx formation increases in hydrogen-enriched POME biogas combustion due to the enhancement of the furnace temperature.

  13. Steam generation by combustion of processed waste fats

    Energy Technology Data Exchange (ETDEWEB)

    Pudel, F.; Lengenfeld, P. [OEHMI Forschung und Ingenieurtechnik GmbH, Magdeburg (Germany)

    1993-12-31

    The use of specially processed waste fats as a fuel oil substitute offers, at attractive costs, an environmentally friendly alternative to conventional disposal like refuse incineration or deposition. For that purpose the processed fat is mixed with EL fuel oil and burned in a standard steam generation plant equipped with special accessories. The measured emission values of the combustion processes are very low.

  14. Isamaalaulud ja okupatsioonirežiim – nostalgia, utoopia ja reaalsus. Estonian Patriotic Songs and the Occupational Regime – Nostalgia, Utopia and Reality

    Directory of Open Access Journals (Sweden)

    Kanni Labi

    2012-04-01

    Full Text Available Estonian knowledge of history emanates from the fact that constituting an independent nation has for the most part been nothing but a utopia, and was a reality for a relatively short time. When it comes to selfidentification though, the expression ’a singing people’ is often used by the Estonians to describe themselves. Nostalgia for freedom is reflected in the Estonian culture of almost all periods and is carried on by the singing tradition, where patriotic songs emerge independent of different musical tastes within a particular generation and form an important part of a common Estonian repertoire. Patriotic songs occupy a central place in several fields of Estonian culture: besides music culture also in popular culture,and literary history – the works of poetry which have gained the most popularity are those which when put to music have been the most widely spread among the people. The main part of the most popular Estonian patriotic songs are choral songs from the national awakening at the end of the 19th century. Despite the national programmes aiming to wipe out ‘bourgeois nationalism’, they were sung at the song festivals in the Soviet era and were published in song books, expressing the people’s nostalgia for freedom lost. After the end of the Second World War, there was an attempt at launching a kind of patriotic new creation, where patriotism was merged with Soviet pathos; the aim was to show that the people’s utopia was in fact communism, but not a single one of those songs made it into the people’s common repertoire. Only the patriotic songs composed in the 1980s during the so-called new national awakening reached a popularity comparable to that of the old songs. The discourse on ’Estonianness’ and the shaping of a matching repertoire under imperial Russian rule took place under very different circumstances than its preservation and development in the second half of the 20th century under Soviet occupation, but

  15. Flash pyrolysis fuel oil: bio-pok

    Energy Technology Data Exchange (ETDEWEB)

    Gust, S [Neste Oy, Porvoo (Finland)

    1997-12-01

    Samples of flash pyrolysis liquid produced by Union Fenosa, Spain from pine and straw and samples produced by Ensyn of Canada from mixed hardwoods were combusted with simple pressure atomization equipment commonly used with light fuel oils in intermediate size (0.1-1 MW) boilers. With a number of modifications to the combustion system, carbon monoxide (CO) and nitrous oxide (NO{sub x}) could be reduced to acceptable levels: CO < 30 ppm and NO{sub x} < 140 ppm. Particulate emissions which were initially very high (Bacharach 4-5) were reduced (Bach. 2-3) by system improvements but are still higher than from light fuel oil (Bach. <1). The modifications to the combustion system were: refractory section between burner and boiler, acid resistant progressive cavity pump, higher liquid preheat temperature and higher pressure than for light fuel oils. The main problems with pyrolysis liquids concerns their instability or reactivity. At temperatures above 100 deg C they begin to coke, their viscosity increases during storage and oxygen from air causes skin formation. This requires that special handling procedures are developed for fuel storage, delivery and combustion systems. (orig.)

  16. Recycling used palm oil and used engine oil to produce white bio oil, bio petroleum diesel and heavy fuel

    Science.gov (United States)

    Al-abbas, Mustafa Hamid; Ibrahim, Wan Aini Wan; Sanagi, Mohd. Marsin

    2012-09-01

    Recycling waste materials produced in our daily life is considered as an additional resource of a wide range of materials and it conserves the environment. Used engine oil and used cooking oil are two oils disposed off in large quantities as a by-product of our daily life. This study aims at providing white bio oil, bio petroleum diesel and heavy fuel from the disposed oils. Toxic organic materials suspected to be present in the used engine oil were separated using vacuum column chromatography to reduce the time needed for the separation process and to avoid solvent usage. The compounds separated were detected by gas chromatography-mass spectrometry (GC-MS) and found to contain toxic aromatic carboxylic acids. Used cooking oils (thermally cracked from usage) were collected and separated by vacuum column chromatography. White bio oil produced was examined by GC-MS. The white bio oil consists of non-toxic hydrocarbons and is found to be a good alternative to white mineral oil which is significantly used in food industry, cosmetics and drugs with the risk of containing polycyclic aromatic compounds which are carcinogenic and toxic. Different portions of the used cooking oil and used engine were mixed to produce several blends for use as heavy oil fuels. White bio oil was used to produce bio petroleum diesel by blending it with petroleum diesel and kerosene. The bio petroleum diesel produced passed the PETRONAS flash point and viscosity specification test. The heat of combustion of the two blends of heavy fuel produced was measured and one of the blends was burned to demonstrate its burning ability. Higher heat of combustion was obtained from the blend containing greater proportion of used engine oil. This study has provided a successful recycled alternative for white bio oil, bio petroleum fuel and diesel which can be an energy source.

  17. Torrefaction of empty fruit bunches under biomass combustion gas atmosphere.

    Science.gov (United States)

    Uemura, Yoshimitsu; Sellappah, Varsheta; Trinh, Thanh Hoai; Hassan, Suhaimi; Tanoue, Ken-Ichiro

    2017-11-01

    Torrefaction of oil palm empty fruit bunches (EFB) under combustion gas atmosphere was conducted in a batch reactor at 473, 523 and 573K in order to investigate the effect of real combustion gas on torrefaction behavior. The solid mass yield of torrefaction in combustion gas was smaller than that of torrefaction in nitrogen. This may be attributed to the decomposition enhancement effect by oxygen and carbon dioxide in combustion gas. Under combustion gas atmosphere, the solid yield for torrefaction of EFB became smaller as the temperature increased. The representative products of combustion gas torrefaction were carbon dioxide and carbon monoxide (gas phase) and water, phenol and acetic acid (liquid phase). By comparing torrefaction in combustion gas with torrefaction in nitrogen gas, it was found that combustion gas can be utilized as torrefaction gas to save energy and inert gas. Copyright © 2017 Elsevier Ltd. All rights reserved.

  18. Fuel spray combustion of waste cooking oil and palm oil biodiesel: Direct photography and detailed chemical kinetics

    KAUST Repository

    Kuti, Olawole

    2013-10-14

    This paper studies the ignition processes of two biodiesel from two different feedstock sources, namely waste cooked oil (WCO) and palm oil (PO). They were investigated using the direct photography through high-speed video observations and detailed chemical kinetics. The detailed chemical kinetics modeling was carried out to complement data acquired using the high-speed video observations. For the high-speed video observations, an image intensifier combined with OH* filter connected to a high-speed video camera was used to obtain OH* chemiluminscence image near 313 nm. The OH* images were used to obtain the experimental ignition delay of the biodiesel fuels. For the high-speed video observations, experiments were done at an injection pressure of 100, 200 and 300 MPa using a 0.16 mm injector nozzle. Also a detailed chemical kinetics for the biodiesel fuels was carried out using ac chemical kinetics solver adopting a 0-D reactor model to obtain the chemical ignition delay of the combusting fuels. Equivalence ratios obtained from the experimental ignition delay were used for the detailed chemical kinetics analyses. The Politecnico di Milano\\'s thermochemical and reaction kinetic data were adopted to simulate the ignition processes of the biodiesels using the five fatty acid methyl esters (FAME) major components in the biodiesel fuels. From the high-speed video observations, it was observed that at increasing injection pressure, experimental ignition delay increased as a result of improvement in fuel and air mixing effects. Also the palm oil biodiesel has a shorter ignition delay compared to waste cooked oil biodiesel. This phenomenon could be attributed to the higher cetane number of palm biodiesel. The fuel spray ignition properties depend on both the physical ignition delay and chemical ignition delay. From the detailed chemical kinetic results it was observed that at the low temperature, high ambient pressure conditions reactivity increased as equivalent ratio

  19. Fuel spray combustion of waste cooking oil and palm oil biodiesel: Direct photography and detailed chemical kinetics

    KAUST Repository

    Kuti, Olawole; Nishida, Keiya; Sarathy, Mani; Zhu, Jingyu

    2013-01-01

    This paper studies the ignition processes of two biodiesel from two different feedstock sources, namely waste cooked oil (WCO) and palm oil (PO). They were investigated using the direct photography through high-speed video observations and detailed chemical kinetics. The detailed chemical kinetics modeling was carried out to complement data acquired using the high-speed video observations. For the high-speed video observations, an image intensifier combined with OH* filter connected to a high-speed video camera was used to obtain OH* chemiluminscence image near 313 nm. The OH* images were used to obtain the experimental ignition delay of the biodiesel fuels. For the high-speed video observations, experiments were done at an injection pressure of 100, 200 and 300 MPa using a 0.16 mm injector nozzle. Also a detailed chemical kinetics for the biodiesel fuels was carried out using ac chemical kinetics solver adopting a 0-D reactor model to obtain the chemical ignition delay of the combusting fuels. Equivalence ratios obtained from the experimental ignition delay were used for the detailed chemical kinetics analyses. The Politecnico di Milano's thermochemical and reaction kinetic data were adopted to simulate the ignition processes of the biodiesels using the five fatty acid methyl esters (FAME) major components in the biodiesel fuels. From the high-speed video observations, it was observed that at increasing injection pressure, experimental ignition delay increased as a result of improvement in fuel and air mixing effects. Also the palm oil biodiesel has a shorter ignition delay compared to waste cooked oil biodiesel. This phenomenon could be attributed to the higher cetane number of palm biodiesel. The fuel spray ignition properties depend on both the physical ignition delay and chemical ignition delay. From the detailed chemical kinetic results it was observed that at the low temperature, high ambient pressure conditions reactivity increased as equivalent ratio

  20. Combustion of drops of Mexican fuel oils with high asphaltenes content; Combustion de gotas de combustoleos mexicanos con alto contenido de asfaltenos

    Energy Technology Data Exchange (ETDEWEB)

    Garcia Rodriguez, Jose Francisco [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1998-09-01

    In this work the combustion of fuel drops with a content of 18% of asphaltenes has been studied . The results obtained for this fuel were compared with the ones obtained for another with a content of 12% asphaltenes. The drops were suspended in a platinum filament and burned in an spherical radiant furnace. The drop size varied between 600 and 800 microns. The fuel drops with 12% asphaltenes showed shorter combustion times, a smaller diameter increment of the smaller diameter during the combustion stages and also a shorter burning time of the carbonaceous residue than the fuel drops with a content of 18% asphaltenes. [Espanol] En el presente trabajo se ha estudiado la combustion de gotas de combustible con 18% de contenido de asfaltenos. Los resultados obtenidos para este combustible se compararon con los obtenidos para otro con 12% de contenido de asfaltenos. Las gotas fueron suspendidas en un filamento de platino y quemadas en un horno radiante esferico. El tamano de las gotas vario entre 600 y 800 micras. Las gotas de combustible con 12% de asfaltenos mostraron tiempos de combustion mas cortos, un incremento del diametro menor durante las etapas de combustion y un tiempo de quemado del residuo carbonoso tambien mas corto que las gotas del combustible con 18% de contenido de asfaltenos.

  1. How in-situ combustion process works in a fractured system : two-dimensional, core and block scale simulation

    Energy Technology Data Exchange (ETDEWEB)

    Fadaei, H.; Renard, G. [Inst. Francais du Petrole, Lyon (France); Quintard, M.; Debenest, G. [L' Inst. de Mecanique des Fluides de Toulouse, Toulouse (France); Kamp, A.M. [Centre Huile Lourde Ouvert et Experimental CHLOE, Pau (France)

    2008-10-15

    Core and matrix block scale simulations of in situ combustion (ISC) processes in a fractured reservoir were conducted. ISC propagation conditions and oil recovery mechanisms were studied at core scale, while the 2-D behaviour of ISC was also studied at block-scale in order to determine dominant processes for combustion propagation and the characteristics of different steam fronts. The study examined 2-phase combustion in a porous medium containing a solid fuel as well as 2-D conventional dry combustion methods. The aim of the study was to predict ISC extinction and propagation conditions as well as to understand the mechanisms of oil recovery using ISC processes. The simulations were also used to develop up-scaling guidelines for fractured systems. Computations were performed using different oxygen diffusion and matrix permeability values. The effect of each production mechanism was studied separately. The multi-phase simulations showed that ISC in fractured reservoirs is feasible. The study showed that ISC propagation is dependent on the oxygen diffusion coefficient, while matrix permeability plays an important role in oil production. Oil production was governed by gravity drainage and thermal effects. Heat transfer due to the movement of combustion front velocity in the study was minor when compared to heat transfer by conduction and convection. It was concluded that upscaling methods must also consider the different zones distinguished for oil saturation and temperatures. 15 refs., 2 tabs., 15 figs.

  2. Mutational analysis of COL1A1 and COL1A2 genes among Estonian osteogenesis imperfecta patients.

    Science.gov (United States)

    Zhytnik, Lidiia; Maasalu, Katre; Reimann, Ene; Prans, Ele; Kõks, Sulev; Märtson, Aare

    2017-08-15

    Osteogenesis imperfecta (OI) is a rare bone disorder. In 90% of cases, OI is caused by mutations in the COL1A1/2 genes, which code procollagen α1 and α2 chains. The main aim of the current research was to identify the mutational spectrum of COL1A1/2 genes in Estonian patients. The small population size of Estonia provides a unique chance to explore the collagen I mutational profile of 100% of OI families in the country. We performed mutational analysis of peripheral blood gDNA of 30 unrelated Estonian OI patients using Sanger sequencing of COL1A1 and COL1A2 genes, including all intron-exon junctions and 5'UTR and 3'UTR regions, to identify causative OI mutations. We identified COL1A1/2 mutations in 86.67% of patients (26/30). 76.92% of discovered mutations were located in the COL1A1 (n = 20) and 23.08% in the COL1A2 (n = 6) gene. Half of the COL1A1/2 mutations appeared to be novel. The percentage of quantitative COL1A1/2 mutations was 69.23%. Glycine substitution with serine was the most prevalent among missense mutations. All qualitative mutations were situated in the chain domain of pro-α1/2 chains. Our study shows that among the Estonian OI population, the range of collagen I mutations is quite high, which agrees with other described OI cohorts of Northern Europe. The Estonian OI cohort differs due to the high number of quantitative variants and simple missense variants, which are mostly Gly to Ser substitutions and do not extend the chain domain of COL1A1/2 products.

  3. Radon in Estonian buildings. Establishment of a measurement system and obtained results

    International Nuclear Information System (INIS)

    Pahapill, L.; Rulkov, A.; Swedjemark, G.A.

    1996-12-01

    One purpose of this project was the establishment of a radon monitoring programme inside the state environmental monitoring programme. Another purpose was to investigate regions, expected to have high radon levels indoors. A new method for the long-term measurement of indoor radon was established and the staff for these measurements was trained. The results of the measurement can be used by Estonian decision-makers to work out rules and standards. There is no legislative act in the field of radiation in Estonian at this time. To summarize the results of the measurements we can say that indoor radon concentrations vary by region. The radon investigations must be continued to identify the risk areas and types of housing construction. The results of the state radon monitoring are provided to the municipalities, who advice the owners of planned new houses to select the right construction for the house. A new project will follow with an investigation of radon in randomly selected dwellings, training and equipment for radon measurement in soil, and general advice with regard to radon, as well as assistance in preparing information about radon. 7 refs, 5 figs

  4. The Perceived Impact of External Evaluation: The System, Organisation and Individual Levels-Estonian Case

    Science.gov (United States)

    Seema, Riin; Udam, Maiki; Mattisen, Heli; Lauri, Liia

    2017-01-01

    The purpose of this article is to provide an overview of how the employees of higher education institutions perceive the impact of external evaluations. The study was conducted using the concurrent mixed method and involved 361 employees from Estonian universities and professional higher education institutions. The results indicated that…

  5. Size distribution and concentration of soot generated in oil and gas-fired residential boilers under different combustion conditions

    Science.gov (United States)

    Jiménez, Santiago; Barroso, Jorge; Pina, Antonio; Ballester, Javier

    2016-05-01

    In spite of the relevance of residential heating burners in the global emission of soot particles to the atmosphere, relatively little information on their properties (concentration, size distribution) is available in the literature, and even less regarding the dependence of those properties on the operating conditions. Instead, the usual procedure to characterize those emissions is to measure the smoke opacity by several methods, among which the blackening of a paper after filtering a fixed amount of gas (Bacharach test) is predominant. In this work, the size distributions of the particles generated in the combustion of a variety of gaseous and liquid fuels in a laboratory facility equipped with commercial burners have been measured with a size classifier coupled to a particle counter in a broad range of operating conditions (air excesses), with simultaneous determination of the Bacharach index. The shape and evolution of the distribution with progressively smaller oxygen concentrations depends essentially on the state of the fuel: whereas the combustion of the gases results in monomodal distributions that 'shift' towards larger diameters, in the case of the gas-oils an ultrafine mode is always observed, and a secondary mode of coarse particle grows in relevance. In both cases, there is a strong, exponential correlation between the total mass concentration and the Bacharach opacity index, quite similar for both groups of fuels. The empirical expressions proposed may allow other researchers to at least estimate the emissions of numerous combustion facilities routinely characterized by their smoke opacities.

  6. Assessment of the Estonian Research Development Technology and Innovation Funding System

    OpenAIRE

    Nedeva, Maria; Georghiou, Luke

    2003-01-01

    The objectives of the assessment of the RDTI funding system in Estonia as specified by the Terms of Reference are as follows: 1) to conduct a review of the current R&D funding system in Estonia; 2) to review the objectives of the Estonian R&D Strategy 2002-2006; 3) to review best practice in R&D funding elsewhere; and 4) to propose an efficient, transparent and accountable R&D funding system.

  7. Gender Advantages and Gender Normality in the Views of Estonian Secondary School Students

    Science.gov (United States)

    Kuurme, Tiiu; Kasemaa, Gertrud

    2015-01-01

    The aim of the study on Estonian secondary school students was to obtain an overview of the gender-related views and experiences of the everyday school life by students, and to analyse the school-related factors in the development of gender roles and gender-related expectations. We view gender equality as a central condition for social…

  8. Shale-oil-derived additives for fuel oils

    International Nuclear Information System (INIS)

    Raidma, E.; Leetsman, L.; Muoni, R.; Soone, Y.; Zhiryakov, Y.

    2002-01-01

    Studies have shown that the oxidation, wearing, and anticorrosive properties of shale oil as an additive to liquid fuels and oils enable to improve the conditions of their use. Studies conducted by Institute of Oil Shale have shown that it is possible, on the basis of shale oil produced by Viru Keemia Grupp AS (Viru Chemistry Group Ltd.) and, particularly, on the basis of its fractions 230-320 and 320-360 deg C to produce efficient and stable additives for liquid fuels to improve their combustion and storage properties. In the production of additives from shale oil the prerequisite taken into account is its complexity of composition and high concentration of neutral and phenolic oxygen compounds. Additives produced from shale oil have multifunctional properties which enable to improve operational data of liquid fuels and to increase the power of diesel engines and boilers. (author)

  9. Modeling segregated in- situ combustion processes through a vertical displacement model applied to a Colombian field

    International Nuclear Information System (INIS)

    Guerra Aristizabal, Jose Julian; Grosso Vargas, Jorge Luis

    2005-01-01

    Recently it has been proposed the incorporation of horizontal well technologies in thermal EOR processes like the in situ combustion process (ISC). This has taken to the conception of new recovery mechanisms named here as segregated in-situ combustion processes, which are conventional in-situ combustion process with a segregated flow component. Top/Down combustion, Combustion Override Split-production Horizontal-well and Toe-to-Heel Air Injection are three of these processes, which incorporate horizontal producers and gravity drainage phenomena. When applied to thick reservoirs a process of this nature could be reasonably modeled under concepts of conventional in-situ combustion and Crestal Gas injection, especially for heavy oils mobile at reservoir conditions. A process of this nature has been studied through an analytic model conceived for the particular conditions of the Castilla field, a homogeneous thick anticline structure containing high mobility heavy oil, which seems to be an excellent candidate for the application of these technologies

  10. Development of steam generators for combustion of biofuels up to 10 t/h

    Energy Technology Data Exchange (ETDEWEB)

    Bentzin, H

    1985-01-01

    Combustion parameters are compared for raw brown coal, rice hulls and coconut shells as fuel in small steam generators. Combustion of native biofuel is seen as a power generation alternative in developing countries. Experiments were conducted on a 6.5 t/h moving grate steam generator with a firing grate surface of 7.2 m/sup 2/. Combustion results are shown in a table. Technological modifications carried out in adapting brown coal-fired steam generators to biofuels are also listed. A series of small steam generators for combustion of brown coal, biofuels including wood chips, as well as heating oil as back-up has been developed by the Karl-Marx-Stadt Dampfkesselbau Plant, GDR, with steam capacities ranging from 3.2 to 10 t/h. Technical specifications and diagrams of this series design (DGK-3, DGK-45, DWK 2S) are given. A larger steam generator with 20 t/h steam capacity for combustion of raw brown coal, bagasse, wood chips with heating oil and for rice hulls as support fuels is being developed by the Berlin Dampferzeugerbau Plant, GDR. 5 references.

  11. Re-conceptualizing mother tongue tuition of Estonian abroad as a transnational phenomenon

    Directory of Open Access Journals (Sweden)

    Maarja Siiner

    2017-05-01

    Full Text Available The governmental initiative called the Compatriots Programme, which supports language tuition in Estonian schools and societies abroad, reveals an increased interest in developing intergenerational language transmission in the growing Estonian diaspora. This transnational language political activity signals a new era in language policy, where nation states are increasingly decentralized by migration. The evaluation of the program furthermore reveals that organizing such schools requires a willingness to take language political agency, typically conducted by well-educated and well-integrated resourceful transnational multilingual parents. The present article outlines the results of an ethnographic study of the process of establishing the Estonian School in Copenhagen. This step has demanded a change in the mindset still prevailing in Estonia that language political activities, such as planning language acquisition, are solely the responsibility of the state. Since the prevailing language ideology in Denmark is not favorable towards multilingualism in migrant languages, intergenerational language transmission furthermore presupposes a feeling of ownership of the language and high language self-esteem. "Hargmaise keelepoliitika sünd. Eesti keeleõppe korraldamise võimalikkusest välismaal Taani näitel" Hargmaisus, kasvav väljarändajate arv ja sellega ka eesti keele rääkijate hulk välismaal on jätnud oma jälje eesti keelepoliitikale. Kui varem uuriti peamiselt seda, kuidas eesti keel muukeelses kontekstis muutub, siis viimasel kümnendil on riik asunud aktiivselt toetama eesti keele jätkuvat kasutamist välismaal, rahastades rahvuskaaslaste programmi abil haridusprogramme. Kuid millised faktorid määravad selle, kas uus eestlaste põlvkond oskab ja tahab eesti keelt rääkida? Artikkel hindab etnograafilises ja sotsiolingvistilises võtmes Kopenhaagenis kolm aastat tegutsenud Eesti Kooli ja Lasteklubi näitel, millised on keelekasutust

  12. Modeling the lubrication, dynamics, and effects of piston dynamic tilt of twin-land oil control rings in internal combustion engines

    Energy Technology Data Exchange (ETDEWEB)

    Tian, T.; Wong, V.W.

    2000-01-01

    A theoretical model was developed to study the lubrication, friction, dynamics, and oil transport of twin-land oil control rings (TLOCR) in internal combustion engines. A mixed lubrication model with consideration of shear-thinning effects of multigrade oils was used to describe the lubrication between the running surfaces of the two lands and the liner. Oil squeezing and asperity contact were both considered for the interaction between the flanks of the TLOCR and the ring groove. Then, the moments and axial forces from TLOCR/liner lubrication and TLOCR/groove interaction were coupled into the dynamic equations of the TLOCR. Furthermore, effects of piston dynamic tilt were considered in a quasi three-dimensional manner so that the behaviors of the TLOCR at different circumferential location could be studied. As a first step, variation of the third land pressure was neglected. The model predictions were illustrated via an SI engine. One important finding is that around thrust and anti-thrust sides, the difference between the minimum oil film thickness of two lands can be as high as several micrometers due to piston dynamic tilt. As a result, at thrust and anti-thrust sides, significant oil can pass under one land of the TLOCR along the bore, although the other land perfectly seals the bore. Then, the capabilities of the model were further explained by studying the effects of ring tension and torsional resistance on the lubrication and oil transport between the lands and the liner. The effects of oil film thickness on the flanks of the ring groove on the dynamics of the TLOCR were also studied. Friction results show that boundary lubrication contributes significantly to the total friction of the TLOCR.

  13. Elemental analysis of combustion products by neutron activation

    International Nuclear Information System (INIS)

    Heft, R.E.; Koszykowski, R.F.

    1980-01-01

    This paper gives a brief description of the neutron activation analysis method, which is being used to determine the elemental profile of combustion products from coal-fired power plants, oil shale retorting, and underground coal gasification

  14. Non-conventional use of vegetable oils: Possibilities and prospects

    International Nuclear Information System (INIS)

    Pellizzi, G.

    1992-01-01

    This paper examines the feasibility, relative to the specific capabilities of the Italian agricultural industry, of the production of biomass fuels and lubricating oils. A comparative cost benefit analysis is made to determine the technical and economic convenience of the production of grain or vegetable oil derived biomass for direct use as lubricants, fuel oils or for conversion into ethanol fuels. The suitability of different types of engines is examined for the direct combustion of vegetable oils and for the combustion of ethanol fuels. The study also has a look at what should be the suitable mix of Italian Government agricultural, environmental and fiscal strategies to support and encourage the production and use of industrial vegetable fuel oils and lubricants

  15. Renewable Energy Laboratory Development for Biofuels Advanced Combustion Studies

    Energy Technology Data Exchange (ETDEWEB)

    Soloiu, Valentin A. [Georgia Southern Univ., Statesboro, GA (United States)

    2012-03-31

    The research advanced fundamental science and applied engineering for increasing the efficiency of internal combustion engines and meeting emissions regulations with biofuels. The project developed a laboratory with new experiments and allowed investigation of new fuels and their combustion and emissions. This project supports a sustainable domestic biofuels and automotive industry creating economic opportunities across the nation, reducing the dependence on foreign oil, and enhancing U.S. energy security. The one year period of research developed fundamental knowledge and applied technology in advanced combustion, emissions and biofuels formulation to increase vehicle's efficiency. Biofuels combustion was investigated in a Compression Ignition Direct Injection (DI) to develop idling strategies with biofuels and an Indirect Diesel Injection (IDI) intended for auxiliary power unit.

  16. Sensitivity Analysis of Heavy Fuel Oil Spray and Combustion under Low-Speed Marine Engine-Like Conditions

    Directory of Open Access Journals (Sweden)

    Lei Zhou

    2017-08-01

    Full Text Available On account of their high power, thermal efficiency, good reliability, safety, and durability, low-speed two-stroke marine diesel engines are used as the main drive devices for large fuel and cargo ships. Most marine engines use heavy fuel oil (HFO as the primary fuel, however, the physical and chemical characteristics of HFO are not clear because of its complex thermophysical properties. The present study was conducted to investigate the effects of fuel properties on the spray and combustion characteristics under two-stroke marine engine-like conditions via a sensitivity analysis. The sensitivity analysis of fuel properties for non-reacting and reacting simulations are conducted by comparing two fuels having different physical properties, such as fuel density, dynamic viscosity, critical temperature, and surface tension. The performances of the fuels are comprehensively studied under different ambient pressures, ambient temperatures, fuel temperatures, and swirl flow conditions. From the results of non-reacting simulations of HFO and diesel fuel properties in a constant volume combustion chamber, it can be found that the increase of the ambient pressure promotes fuel evaporation, resulting in a reduction in the steady liquid penetration of both diesel and HFO; however, the difference in the vapor penetrations of HFO and diesel reduces. Increasing the swirl flow significantly influences the atomization of both HFO and diesel, especially the liquid distribution of diesel. It is also found that the ambient temperature and fuel temperature have the negative effects on Sauter mean diameter (SMD distribution. For low-speed marine engines, the combustion performance of HFO is not sensitive to activation energy in a certain range of activation energy. At higher engine speed, the difference in the effects of different activation energies on the in-cylinder pressure increases. The swirl flow in the cylinder can significantly promote fuel evaporation and

  17. Seltsi muuseumist riigi keskmuuseumiks: ikka ajutiste lahendustega / Changes in the Estonian National Museum from 1909 to the present.

    Directory of Open Access Journals (Sweden)

    Krista Aru

    2011-01-01

    Full Text Available Changes in the Estonian National Museum from 1909 to the presentThe Estonian National Museum was founded in Tartu in 1909 as part of the national movement. With its activities and connections in society, the ENM helped create Estonian society, the nation’s collective memory and identity.The ENM has always been – despite the changing locations, names, and content – one of the symbols of national identity. But at the same time, ENM has never had its own building designed specially for the museum’s purposes.Since 1909 there have been several attempts to establish a home for the ENM. At first (1909–1923, Estonian society wanted to establish the museum in the center of Tartu. The museum was intended to become a key institution of the growing nation and establishing the nation’s identity.At last in 1923 the ENM secured the Raadi manor, outside the center of the city, in a beautiful park, near the lake with its boats and water attractions. In this manor the first permanent exhibition of mainly 19th century Estonian peasant life was compiled, and the ENM operated in the Raadi manor from 1923–1940 as the “Estonian’s own museum” The years of alternating occupations, World War II, and political terror damaged and destroyed the whole society. The Raadi manor was destroyed in the war too, and the ENM itself was divided into two parts – the State Ethnographic Museum and the State Literary Museum. The collections of the ENM were given to Tallinn and to many different places inside and outside Tartu. Then began “the period of temporary location” that continues today. The museum is located in several places in the city of Tartu.In 1988, the prior name of the State Ethnographic Museum – the Estonian National Museum – was reinstated. Since the 1990s there have been many attempts to secure a special building for the ENM. Now, at last, as a result of serious economic pressure, we are closer to this goal than ever. During the last five

  18. Combustion of diesel fuel from a toxicological perspective. I. Origin of incomplete combustion products.

    Science.gov (United States)

    Scheepers, P T; Bos, R P

    1992-01-01

    Since the use of diesel engines is still increasing, the contribution of their incomplete combustion products to air pollution is becoming ever more important. The presence of irritating and genotoxic substances in both the gas phase and the particulate phase constituents is considered to have significant health implications. The quantity of soot particles and the particle-associated organics emitted from the tail pipe of a diesel-powered vehicle depend primarily on the engine type and combustion conditions but also on fuel properties. The quantity of soot particles in the emissions is determined by the balance between the rate of formation and subsequent oxidation. Organics are absorbed onto carbon cores in the cylinder, in the exhaust system, in the atmosphere and even on the filter during sample collection. Diesel fuel contains polycyclic aromatic hydrocarbons (PAHs) and some alkyl derivatives. Both groups of compounds may survive the combustion process. PAHs are formed by the combustion of crankcase oil or may be resuspended from engine and/or exhaust deposits. The conversion of parent PAHs to oxygenated and nitrated PAHs in the combustion chamber or in the exhaust system is related to the vast amount of excess combustion air that is supplied to the engine and the high combustion temperature. Whether the occurrence of these derivatives is characteristic for the composition of diesel engine exhaust remains to be ascertained. After the emission of the particles, their properties may change because of atmospheric processes such as aging and resuspension. The particle-associated organics may also be subject to (photo)chemical conversions or the components may change during sampling and analysis. Measurement of emissions of incomplete combustion products as determined on a chassis dynamometer provides knowledge of the chemical composition of the particle-associated organics. This knowledge is useful as a basis for a toxicological evaluation of the health hazards of

  19. Modelling of turbulent combustion in the blast furnace raceway

    Energy Technology Data Exchange (ETDEWEB)

    Karvinen, R.; Maekiranta, R. [Tampere Univ. (Finland). Energy and Process Engineering

    1996-12-31

    The phenomena concerning coke-gas -suspension and simultaneous combustion of solid coke particles and residual fuel oil in a blast furnace raceway are modelled. The flow field of suspension is predicted by using the two fluid model, which is based on the Eulerian method, in the Phoenics code. The standard k-e -model of turbulence is used. Pyrolysis of oil droplets is calculated with the own coded subroutine, which is based on the Lagrangian approach. Gas phase reaction rate is assumed to be controlled by chemical kinetics. Radiative heat transfer is calculated by using the six-flux method. Heterogenous surface reactions are used for the coke particles. Calculations without coke combustion show that due to a poor mixing in the hot blast, pyrolysis gases of residual fuel oil have not time enough to react with oxygen. It is obvious that if combustion of coke particles is taken into account, the oxygen content in the blast decreases to such a level, that unburnt pyrolysis gases can flow out of the raceway causing problems. The distribution of coke void fraction has been succeeded to predict in the raceway domain. Coke particles fall from the upper part of the raceway to the hot blast forming locally high concentrations, which affect very strongly the oxygen distribution of the hot blast. (orig.) SULA 2 Research Programme; 10 refs.

  20. Modelling of turbulent combustion in the blast furnace raceway

    Energy Technology Data Exchange (ETDEWEB)

    Karvinen, R; Maekiranta, R [Tampere Univ. (Finland). Energy and Process Engineering

    1997-12-31

    The phenomena concerning coke-gas -suspension and simultaneous combustion of solid coke particles and residual fuel oil in a blast furnace raceway are modelled. The flow field of suspension is predicted by using the two fluid model, which is based on the Eulerian method, in the Phoenics code. The standard k-e -model of turbulence is used. Pyrolysis of oil droplets is calculated with the own coded subroutine, which is based on the Lagrangian approach. Gas phase reaction rate is assumed to be controlled by chemical kinetics. Radiative heat transfer is calculated by using the six-flux method. Heterogenous surface reactions are used for the coke particles. Calculations without coke combustion show that due to a poor mixing in the hot blast, pyrolysis gases of residual fuel oil have not time enough to react with oxygen. It is obvious that if combustion of coke particles is taken into account, the oxygen content in the blast decreases to such a level, that unburnt pyrolysis gases can flow out of the raceway causing problems. The distribution of coke void fraction has been succeeded to predict in the raceway domain. Coke particles fall from the upper part of the raceway to the hot blast forming locally high concentrations, which affect very strongly the oxygen distribution of the hot blast. (orig.) SULA 2 Research Programme; 10 refs.

  1. An Equation-of-State Compositional In-Situ Combustion Model: A Study of Phase Behavior Sensitivity

    DEFF Research Database (Denmark)

    Kristensen, Morten Rode; Gerritsen, M. G.; Thomsen, Per Grove

    2009-01-01

    phase behavior sensitivity for in situ combustion, a thermal oil recovery process. For the one-dimensional model we first study the sensitivity to numerical discretization errors and provide grid density guidelines for proper resolution of in situ combustion behavior. A critical condition for success...... to ignition. For a particular oil we show that the simplified approach overestimates the required air injection rate for sustained front propagation by 17% compared to the equation of state-based approach....

  2. Design of Hybrid Steam-In Situ Combustion Bitumen Recovery Processes

    International Nuclear Information System (INIS)

    Yang Xiaomeng; Gates, Ian D.

    2009-01-01

    Given enormous capital costs, operating expenses, flue gas emissions, water treatment and handling costs of thermal in situ bitumen recovery processes, improving the overall efficiency by lowering energy requirements, environmental impact, and costs of these production techniques is a priority. Steam-assisted gravity drainage (SAGD) is the most widely used in situ recovery technique in Athabasca reservoirs. Steam generation is done on surface and consequently, because of heat losses, the energy efficiency of SAGD can never be ideal with respect to the energy delivered to the sandface. An alternative to surface steam generation is in situ combustion (ISC) where heat is generated within the formation through injection of oxygen at a sufficiently high pressure to initiate combustion of bitumen. In this manner, the heat from the combustion reactions can be used directly to mobilize the bitumen. As an alternative, the heat can be used to generate steam within the formation which then is the agent to move heat in the reservoir. In this research, alternative hybrid techniques with simultaneous and sequential steam-oxygen injection processes are examined to maximize the thermal efficiency of the recovery process. These hybrid processes have the advantage that during ISC, steam is generated within the reservoir from injected and formation water and as a product of oxidation. This implies that ex situ steam generation requirements are reduced and if there is in situ storage of combustion gases, that overall gas emissions are reduced. In this research, detailed reservoir simulations are done to examine the dynamics of hybrid processes to enable design of these processes. The results reveal that hybrid processes can lower emitted carbon dioxide-to-oil ratio by about 46%, decrease the consumed natural gas-to-oil ratio by about 73%, reduce the cumulative energy-to-oil ratio by between 40% and 70% compared to conventional SAGD, and drop water consumption per unit oil produced

  3. Oil vaporizer

    Energy Technology Data Exchange (ETDEWEB)

    Dumontier, F

    1904-03-31

    An oil burner particularly applicable to heavy oils, composed essentially of one or more gasification chambers, heated by the flame from the burners, to which the combustible gases are fed by the collectors suitably fixed on the chambers, all parts of the apparatus and especially the gasification chambers being easily demountable to permit cleaning, and all arranged in such a manner as to avoid fouling by reducing or localizing the deposition of solid deposits in the coking chamber.

  4. Combustion for Enhanced Recovery of Light Oil at Medium Pressures

    NARCIS (Netherlands)

    Khoshnevis Gargar, N.

    2014-01-01

    Using conventional production methods, recovery percentages from oil reservoirs range from 5% for difficult oil to 50% for light oil in highly permeable homogeneous reservoirs. To increase the oil recovery factor, enhanced oil recovery (EOR) methods are used. We distinguish EOR that uses chemical

  5. Vene kirjandus venestusaja eesti koolides. Russian Literature in the Estonian Schools of the Russification Era

    Directory of Open Access Journals (Sweden)

    Ülle Pärli

    2012-04-01

    Full Text Available This article aims to give an overview of literary instruction in schools of the russification era at the beginning of the 20th century in Estonia; this was likewise the curriculum of literary study offered to the generation of educated youth which included the Young Estonians. Based on official documents, archival materials, and memoirs, and through analyses of anthologies, literary histories, and teaching methods in use at the time, we attempt to reconstruct the outlines of literary reading and requirements for students in various types of schools. When, as a result of school reform, Russian became the language of instruction; lessons in Russian became central in the curriculum, alongside the word of God; selections from Russian literature were read in the original language. In the lower grades, teaching was by the so-called ”natural method”, intended to guarantee swift achievement of fluency in ”living Russian language”; this was later replaced by systematic textual analysis, which distinguished between belles lettres and other types of texts. However, the study of literature was always subordinated to the goals of language instruction. In institutions of secondary education, study of Russian literature was separate from language instruction. Indeed, Russian literature was the only literature systematically studied in high schools (though one must keep in mind that not all schools completely followed the official program. Private schools were especially noticeable for their greater freedom, though all of them had to take general curriculum directives into account. Reading of literary texts connected with other languages thus had to remain almost purely illustrative. In view of the above, in the upper grades of elementary school and high school, students obtained a thorough introduction to the Russian classics. According to the official school curriculum, Russian literary history ended with Nikolai Gogol. Attempts were made to ignore

  6. [Encapsulated voices : Estonian sound recordings from the German prisoner-of-war camps in 1916-1918] / Tõnu Tannberg

    Index Scriptorium Estoniae

    Tannberg, Tõnu, 1961-

    2013-01-01

    Arvustus: Encapsulated voices : Estonian sound recordings from the German prisoner-of-war camps in 1916-1918 (Das Baltikum in Geschichte und Gegenwart, 5). Hrsg. von Jaan Ross. Böhlau Verlag. Köln, Weimar und Wien 2012

  7. Research on a dispersing solution for burnt crude oils: Aegean Sea oil spill

    International Nuclear Information System (INIS)

    Bergueiro, J.R.; Morales, N.; Dominguez, F.

    1993-01-01

    The oil tanker Aegean Sea spilled oil when it grounded during severe storm conditions near La Coruna, Spain. Much of the oil burned after an explosion was caused by the hull breaking apart. Oil which contaminated several beaches was affected by both combustion and weathering. Experiments were conducted on oil sampled from the beaches to investigate dispersion of the oil using Beep Enersperse 1990 at different shaking speeds. Biodegradation experiments were also conducted in the presence of Beep Enersperse 1990 but with seawater absent. Although emulsification of the burnt and weathered oil was very difficult, good dispersion and biodegradation were obtained. After 42 d in a stirred reactor, biodegradation of the oil reached at least 80%. 3 refs., 3 figs., 4 tabs

  8. Catalysts for cleaner combustion of coal, wood and briquettes sulfur dioxide reduction options for low emission sources

    Energy Technology Data Exchange (ETDEWEB)

    Smith, P.V. [Global Environmental Solutions, Inc., Morton Grove, IL (United States)

    1995-12-31

    Coal fired, low emission sources are a major factor in the air quality problems facing eastern European cities. These sources include: stoker-fired boilers which feed district heating systems and also meet local industrial steam demand, hand-fired boilers which provide heat for one building or a small group of buildings, and masonary tile stoves which heat individual rooms. Global Environmental Systems is marketing through Global Environmental Systems of Polane, Inc. catalysts to improve the combustion of coal, wood or fuel oils in these combustion systems. PCCL-II Combustion Catalysts promotes more complete combustion, reduces or eliminates slag formations, soot, corrosion and some air pollution emissions and is especially effective on high sulfur-high vanadium residual oils. Glo-Klen is a semi-dry powder continuous acting catalyst that is injected directly into the furnace of boilers by operating personnel. It is a multi-purpose catalyst that is a furnace combustion catalyst that saves fuel by increasing combustion efficiency, a cleaner of heat transfer surfaces that saves additional fuel by increasing the absorption of heat, a corrosion-inhibiting catalyst that reduces costly corrosion damage and an air pollution reducing catalyst that reduces air pollution type stack emissions. The reduction of sulfur dioxides from coal or oil-fired boilers of the hand fired stoker design and larger, can be controlled by the induction of the Glo-Klen combustion catalyst and either hydrated lime or pulverized limestone.

  9. Estonian Perceptions of Security: Not Only About Russia and the Refugees

    OpenAIRE

    Veebel Viljar; Ploom Illimar

    2016-01-01

    The current study focuses on the Estonian perceptions of security and on the defence situation both globally and locally. The dynamic results of the public opinion surveys on security risks conducted in Estonia over the last 10 years (2006-2016) will be presented. In addition, to understand whether some of the security risks could be over- or underestimated in Estonia, these results will be compared with the views expressed recently by the World Economic Forum, particularly the Global Risks R...

  10. Combustion behavior of briquettes from oil palm's empty fruit bunch

    Energy Technology Data Exchange (ETDEWEB)

    Pratoto, A. [Andalas Univ., Padang (Indonesia). Dept. of Mechanical Engineering

    2006-07-01

    Empty fruit bunch (EFB) briquettes from palm plantations are now being considered as a renewable energy source in Indonesia. This paper provided details of a study that investigated the combustion behaviour of an EFB briquette. Thermogravimetry was used to study the briquettes under dynamic conditions at 50 degrees C in a muffle furnace. Thermal decomposition rates and phases were identified, and the effect of the briquette's size on the decomposition rate was evaluated by comparing the combustion behaviour of the briquette to that of loose EFB materials. Rates of devolatilization and char oxidation were also examined. Results of the derivative thermogravimetry (DTG) analysis showed that larger briquettes did not exhibit a sharp peak on the DTG curve. Results suggested that heat transfer was predominant over the kinetic reaction during combustion. The ignition temperature of the briquettes was comparable to typical lignocellulose biomass. Peak combustion temperatures for loose EFB were only slightly lower than other types of biomass. Maximum combustion rates decreased with the size of the fuel. It was concluded that small briquettes are suitable for applications where high rates of heat are required. 16 refs., 1 tab., 6 figs.

  11. How to Improve the Supportive Role of Estonian Innovation System toward Launching New Products by High Technology Companies?

    Directory of Open Access Journals (Sweden)

    Liisi Sepp

    2013-01-01

    Full Text Available The purpose of the study is to evaluate how supportive is Estonian national innovation system toward the launching of new innovative products by high technology firms. The article intends to combine two broad areas of research – national innovation system approach and the different models of the new product launching. Based on the literature review and in-depth analysis of three case studies of Estonian high-tech company’s major barriers as well success factors of highly innovative product launches were identified. The barriers of the new product launching were linked with the systemic failures of the national innovation system. The most relevant failures of Estonian national innovation system inhibiting the new product development are capability and networking failures. The sources of innovation of high-technology firms are too narrow, linkages with domestic firms and higher education institutions as well with foreign firms are poorly developed. High-tech firms have also serious capacity problems due to the extremely weak support mechanism by national innovation system on the seed funding stage of product development and prototype building stage as well. Paper argues that resources needed for the innovation should not be looked too narrowly following linear innovation model approach. Instead interactive approach is needed, which combines capability building, network development, interactive learning with direct investments into fundamental research.

  12. Tõlkepärl eesti ilukirjanduse algusaegadest – esimene eestikeelne robinsonaad / A Translation Gem from the Beginnings of Estonian Literature - the First Robinsonade

    Directory of Open Access Journals (Sweden)

    Ave Mattheus

    2015-06-01

    Full Text Available Teesid: Artiklis uuritakse Eesti Kirjandusmuuseumis asuvat mahukat, ligi 800 lk tõlkekäsikirja „Norem Robinson“, mida võib pidada esimeseks eesti kirjanduse täiemahuliseks robinsonaadiks. Selle valmistas Pärnu koolmeister Heinrich Gottlieb Lorenzsonn saksa pedagoogi ja koolikirjaniku Joachim Heinrich Campe menukast noorsooromaanist „Robinson der Jüngere“ (1779–1780. Tõlge valmis 1822.–1823. aastal, kuid jõudis trükki alles 1842. aastal tugevasti kärbitud ja mugandatud kujul. Toetudes deskriptiivse tõlkeuurimuse analüüsikategooriatele, vaadeldakse artiklis, millised tegurid tõlkeprotsessi suunasid ja milline oli kultuuriruum, kuhu tõlge omal ajal paigutus. SU M M A R Y This article discusses a voluminous manuscript translation of almost 800 pages entitled Norem Robinson (Engl. Robinson the Younger, from the collections of the Estonian Literary Museum. This manuscript can be considered as the first complete Robinsonade in Estonian literature. Its author is a schoolteacher from Pärnu, Heinrich Gottlieb Lorenzsonn (1803–1847, who translated it from the youth novel Robinson der Jüngere(1779–1780, Engl. Robinson the Younger, a bestseller by the educator, writer and a major representative of German Enlightenment, Heinrich Joachim Campe. Lorenzsonn’s translation was completed in 1822–1823, but not printed until 1842 in a strongly adapted version titled Norema Robinsoni ello ja juhtumised ühhe tühja sare peäl (Engl. The Life and Adventures of Robinson the Younger on a deserted island. The print version of the Robinsonade lacks a pedagogical frame story, where the father tells children about the adventures of Robinson and takes the opportunity to discuss and imitate with children all the actions taken by Robinson the Younger. Due to this and other extirpated parts, the possible target audience was enlarged – besides children and youth, the text was now addressed to adults as well. In accordance with the

  13. Urea-nitrate combustion synthesis of MgO/MgAl2O4 nanocatalyst used in biodiesel production from sunflower oil: Influence of fuel ratio on catalytic properties and performance

    International Nuclear Information System (INIS)

    Rahmani Vahid, Behgam; Haghighi, Mohammad

    2016-01-01

    Graphical abstract: As a base catalyst for biodiesel production, MgAl 2 O 4 spinel was successfully synthesized by combustion method with MgO, as the active phase, dispersed on the catalyst surface. The nanocatalysts were characterized by XRD, FESEM, EDX, BET-BJH, TGA and FTIR analyses, so as to optimize the concentration of urea (as fuel) in the combustion synthesis. Analyzing the effect of fuel ratio on the combustion synthesized MgAl 2 O 4 , it was revealed that the synthesized base catalyst with a fuel ratio of 1.5 was of the best specifications for biodiesel production process. Future researches may investigate the catalyst reusability and mild reaction conditions, so as to achieve more economical production of biodiesel. - Highlights: • Efficient synthesis of MgAl 2 O 4 spinel by solution combustion method. • Improvement of catalytic activity and stability by optimum ratio fuel. • Enhanced dispersion of MgO over MgAl 2 O 4 spinel. • Production of biodiesel over MgO/MgAl 2 O 4 at relatively mild reaction conditions. - Abstract: MgO/MgAl 2 O 4 nanocatalyst was synthesized by a simple, cost-effective and rapid method and used in biodiesel production from sunflower oil. MgAl 2 O 4 was synthesized by combustion method at different fuel ratios and then active phase of MgO was dispersed on the samples by impregnation method. The nanocatalysts were characterized by XRD, FESEM, EDX, BET-BJH, TGA and FTIR analyses, so as to optimize the concentration of urea (as fuel) in the combustion synthesis. The physicochemical properties of the nanocatalyst confirmed the sample synthesized with fuel ratio of 1.5 has high surface area, effective morphology and texture properties. Finally, in order to evaluate catalytic activity of the samples in biodiesel production, the transesterification reaction was performed. The results indicated the catalyst prepared by combustion synthesis with a fuel ratio of 1.5 was optimum specifications for biodiesel production. Using this

  14. Oil shale derived pollutant control materials and methods and apparatuses for producing and utilizing the same

    Science.gov (United States)

    Boardman, Richard D.; Carrington, Robert A.

    2010-05-04

    Pollution control substances may be formed from the combustion of oil shale, which may produce a kerogen-based pyrolysis gas and shale sorbent, each of which may be used to reduce, absorb, or adsorb pollutants in pollution producing combustion processes, pyrolysis processes, or other reaction processes. Pyrolysis gases produced during the combustion or gasification of oil shale may also be used as a combustion gas or may be processed or otherwise refined to produce synthetic gases and fuels.

  15. Short outlines of books by Estonian authors : [annotations] / Rutt Hinrikus, Janika Kronberg

    Index Scriptorium Estoniae

    Hinrikus, Rutt, 1946-

    1998-01-01

    Laretei, Käbi. Eksiil; Toona, Elin. Lotukata; Park, Eeva. Naeru õpilane; Luik, Viivi. Inimese kapike; Laaman, Ilona. Vesi ahjus; Viiding, Juhan (Üdi, Jüri). Kogutud luuletused; Paju, Juhan. Katkenud romaan; Paju, Juhan. Hõõguv rist; Estonian short stories / toim. Kajar Pruul ja Darlene Reddaway; Traat, Mats. Kartaago kiirrong; Kauksi Ülle. Säng; Kross, Jaan. Paigallend; Puhvel, Madli. Symbol of dawn; Kaplinski, Jaan. Võimaluste võimalikkus; Kaplinski, Jaan. Usk on uskmatus

  16. Saskatchewan combustion recovery an operational success

    Energy Technology Data Exchange (ETDEWEB)

    1967-12-04

    Mobil Oil Co.'s in-situ combustion recovery project in the Battrum heavy oil field in SW. Saskatchewan is an operational success, but not a profit-making venture so far. Some of the details resulting from a discussion with the senior project engineer are discussed. It is explained that 100% displacement efficiency is attained in the burned zone by way of fluid convection resulting from heat conduction. Reasons for selecting the Battrum reservoir are also considered. The pilot project currently being conducted is intended to determine information on the following factors: effect of productivity, injectivity index data, air-oil ratio performance, distribution of injected gas, ignition characteristics, and sweep efficiency. The largest problems are associated with equipment, well completions, and handling of produced fluids.

  17. Mercury in Canadian crude oil

    International Nuclear Information System (INIS)

    Hollebone, B.P.

    2005-01-01

    Estimates for average mercury concentrations in crude oil range widely from 10 ng/g of oil to 3,500 ng/g of oil. With such a broad range of estimates, it is difficult to determine the contributions of the petroleum sector to the total budget of mercury emissions. In response to concerns that the combustion of petroleum products may be a major source of air-borne mercury pollution, Environment Canada and the Canadian Petroleum Products Institute has undertaken a survey of the average total mercury concentration in crude oil processed in Canadian refineries. In order to calculate the potential upper limit of total mercury in all refined products, samples of more than 30 different types of crude oil collected from refineries were measured for their concentration of mercury as it enters into a refinery before processing. High temperature combustion, cold vapour atomic absorption and cold vapour atomic fluorescence were the techniques used to quantify mercury in the samples. The results of the study provide information on the total mass of mercury present in crude oil processed in Canada each year. Results can be used to determine the impact of vehicle exhaust emissions to the overall Canadian mercury emission budget. 17 refs., 2 tabs., 2 figs

  18. Modelling combustion reactions for gas flaring and its resulting emissions

    Directory of Open Access Journals (Sweden)

    O. Saheed Ismail

    2016-07-01

    Full Text Available Flaring of associated petroleum gas is an age long environmental concern which remains unabated. Flaring of gas maybe a very efficient combustion process especially steam/air assisted flare and more economical than utilization in some oil fields. However, it has serious implications for the environment. This study considered different reaction types and operating conditions for gas flaring. Six combustion equations were generated using the mass balance concept with varying air and combustion efficiency. These equations were coded with a computer program using 12 natural gas samples of different chemical composition and origin to predict the pattern of emission species from gas flaring. The effect of key parameters on the emission output is also shown. CO2, CO, NO, NO2 and SO2 are the anticipated non-hydrocarbon emissions of environmental concern. Results show that the quantity and pattern of these chemical species depended on percentage excess/deficiency of stoichiometric air, natural gas type, reaction type, carbon mass content, impurities, combustion efficiency of the flare system etc. These emissions degrade the environment and human life, so knowing the emission types, pattern and flaring conditions that this study predicts is of paramount importance to governments, environmental agencies and the oil and gas industry.

  19. The Mutagenic Potential Caused by the Emissions from Combustion of Crude Glycerin and Diesel Fuel

    Directory of Open Access Journals (Sweden)

    Daniel Terruggi Mazak

    2015-04-01

    Full Text Available This study evaluated the use of crude glycerin as an alternative of energy generation to replace the traditional fuels. The Tradescantia stamen hair mutation assay (Trad-SH was applied to study the mutagenic effects caused by the emissions generated in the direct combustion of diesel oil and glycerin in a flame tube furnace. Tradescantia inflorescences were exposed to gaseous emissions from the combustion tests in a fumigation chamber for 30-40 min. The analysis of variance and the Tukey test were applied to compare the differences between six test groups (intoxicated with emissions from glycerin and diesel oil combustion and a control group. Only one glycerin group showed statistical differences (0.05, possibly due to the complexity of the burning process and impurities, besides the acrolein present in its emissions. The high heating value (HHV of crude glycerin (25.5 MJ/kg was lower than diesel oil (45.19 MJ/kg, but it was comparable to other fuels. Although the use of glycerin as a biofuel could be an important aspect to be considered, the results showed that the glycerin had a substantial mutagenic potential similar to that of diesel oil.

  20. Down-hole catalytic upgrading of heavy crude oil

    Energy Technology Data Exchange (ETDEWEB)

    Weissman, J.G.; Kessler, R.V.; Sawicki, R.A.; Belgrave, J.D.M.; Laureshen, C.J.; Mehta, S.A.; Moore, R.G.; Ursenbach, M.G. [University of Calgary, Calgary, AB (Canada). Dept. of Chemical and Petroleum Engineering

    1996-07-01

    Several processing options have been developed to accomplish near-well bore in-situ upgrading of heavy crude oils. These processes are designed to pass oil over a fixed bed of catalyst prior to entering the production well, the catalyst being placed by conventional gravel pack methods. The presence of brine and the need to provide heat and reactant gases in a down-hole environment provide challenges not present in conventional processing. These issues were addressed and the processes demonstrated by use of a modified combustion tube apparatus. Middle-Eastern heavy crude oil and the corresponding brine were used at the appropriate reservoir conditions. In-situ combustion was used to generate reactive gases and to drive fluids over a heated sand or catalysts bed, simulating the catalyst contacting portion of the proposed processes. The heavy crude oil was found to be amenable to in-situ combustion at anticipated reservoir conditions, with a relatively low air requirement. Forcing the oil to flow over a heated zone prior to production results in some upgrading of the oil, as compared to the original oil, due to thermal effects. Passing the oil over a hydroprocessing catalyst located in the heated zone results in a product that is significantly upgraded as compared to either the original oil or thermally processed oil. Catalytic upgrading is due to hydrogenation and the results in about a 50% sulfur removal and an 8{degree} API gravity increase. Additionally, the heated catalyst was found to be efficient at converting CO to additional H{sub 2}. While all of the technologies needed for a successful field trial of in-situ catalytic upgrading exist, a demonstration has yet to be undertaken. 27 refs., 5 figs., 5 tabs.

  1. Future combustion technology for synthetic and renewable fuels in compression ignition engines (REFUEL). Final report

    Energy Technology Data Exchange (ETDEWEB)

    Aakko-Saksa, P.; Brink, A.; Happonen, M. [and others

    2012-07-01

    This domestic project, Future Combustion Technology for Synthetic and Renewable Fuels in Compression Ignition Engines (ReFuel), was part of a Collaborative Task 'Future Combustion Technology for Synthetic and Renewable Fuels in Transport' of International Energy Agency (IEA) Combustion Agreement. This international Collaborative Task is coordinated by Finland. The three-year (2009-2011) prooject was a joint research project with Aalto University (Aalto), Tampere University of Technology (TUT), Technical Research Centre of Finland (VTT) and Aabo Akademi University (AAU). The project was funded by TEKES, Waertsilae Oyj, Agro Sisu Power, Aker Arctic Technology Oy and the research partners listed above. Modern renewable diesel fuels have excellent physical and chemical properties, in comparison to traditional crude oil based fuels. Purely paraffinic fuels do not contain aromatic compounds and they are totally sulphur free. Hydrotreated Vegetable Oil (HVO) was studied as an example of paraffinic high cetane number (CN) diesel fuels. HVO has no storage and low temperature problems like the fatty acid methyl esters (FAMEs) have. The combustion properties are better than those of crude oil based fuels and FAME, because they have very high cetane numbers and contain no polyaromatic hydrocarbons (PAH). With low HVO density, viscosity and distillation temperatures, these advantageous properties allow far more advanced combustion strategies, such as very high exhaust gas recirculation (EGR) rates or extreme Miller timings, than has been possible with current fossil fuels. The implementation of these advanced combustion technologies, together with the novel renewable diesel fuel, brought significant nitrogen oxides (NO{sub x}), particulate matter (PM) emission reductions with no efficiency losses. (orig.)

  2. Solubility of iron from combustion source particles in acidic media linked to iron speciation.

    Science.gov (United States)

    Fu, Hongbo; Lin, Jun; Shang, Guangfeng; Dong, Wenbo; Grassian, Vichi H; Carmichael, Gregory R; Li, Yan; Chen, Jianmin

    2012-10-16

    In this study, iron solubility from six combustion source particles was investigated in acidic media. For comparison, a Chinese loess (CL) dust was also included. The solubility experiments confirmed that iron solubility was highly variable and dependent on particle sources. Under dark and light conditions, the combustion source particles dissolved faster and to a greater extent relative to CL. Oil fly ash (FA) yielded the highest soluble iron as compared to the other samples. Total iron solubility fractions measured in the dark after 12 h ranged between 2.9 and 74.1% of the initial iron content for the combustion-derived particles (Oil FA > biomass burning particles (BP) > coal FA). Ferrous iron represented the dominant soluble form of Fe in the suspensions of straw BP and corn BP, while total dissolved Fe presented mainly as ferric iron in the cases of oil FA, coal FA, and CL. Mössbauer measurements and TEM analysis revealed that Fe in oil FA was commonly presented as nanosized Fe(3)O(4) aggregates and Fe/S-rich particles. Highly labile source of Fe in corn BP could be originated from amorphous Fe form mixed internally with K-rich particles. However, Fe in coal FA was dominated by the more insoluble forms of both Fe-bearing aluminosilicate glass and Fe oxides. The data presented herein showed that iron speciation varies by source and is an important factor controlling iron solubility from these anthropogenic emissions in acidic solutions, suggesting that the variability of iron solubility from combustion-derived particles is related to the inherent character and origin of the aerosols themselves. Such information can be useful in improving our understanding on iron solubility from combustion aerosols when they undergo acidic processing during atmospheric transport.

  3. Research on oil recovery mechanisms in heavy oil reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Kovscek, Anthony R.; Brigham, William E., Castanier, Louis M.

    2000-03-16

    The research described here was directed toward improved understanding of thermal and heavy-oil production mechanisms and is categorized into: (1) flow and rock properties, (2) in-situ combustion, (3) additives to improve mobility control, (4) reservoir definition, and (5) support services. The scope of activities extended over a three-year period. Significant work was accomplished in the area of flow properties of steam, water, and oil in consolidated and unconsolidated porous media, transport in fractured porous media, foam generation and flow in homogeneous and heterogeneous porous media, the effects of displacement pattern geometry and mobility ratio on oil recovery, and analytical representation of water influx.

  4. Chemical kinetics and oil shale process design

    Energy Technology Data Exchange (ETDEWEB)

    Burnham, A.K.

    1993-07-01

    Oil shale processes are reviewed with the goal of showing how chemical kinetics influences the design and operation of different processes for different types of oil shale. Reaction kinetics are presented for organic pyrolysis, carbon combustion, carbonate decomposition, and sulfur and nitrogen reactions.

  5. The dominance of indirect taxes in Estonian state budget. Summary:Kaudsete maksude dominant Eesti riigieelarve tuludes

    Directory of Open Access Journals (Sweden)

    Olev Raju

    2013-09-01

    Full Text Available Recession has sharply erected the question of tax burden and the optimal proportion of different kinds of taxes among the incomes of the budget. Indirect taxes and consumption taxes, which proportion is different according to different methodologies, dominate in Estonian state budget. The buoyancy of a tax system based on taxes of that kind is especially weak during the recession. The purpose of Estonian government’s economic policy during the highest peak of crisis was to keep the budget in balance. Instead of recovering economy the taxes were arisen and costs were reduced. The results of such a policy aren’t still clear. Difficulties concerning the incomes of budget have arisen the necessity for lifting taxes, which is possible as the tax burden is low now. But a sharp question of the optimal level of taxes is going to be raised. A formula for indirect tax optimum according to Ramsey taxes and Slutski decomposition has been proposed in the article

  6. The Estonian diaspora in South-West Russia in the 1920—30s: migration results

    Directory of Open Access Journals (Sweden)

    Stupin Yuri

    2010-11-01

    Full Text Available This article analyses the spatial features of the settling of Russian Estonians in the Northwest region at the “zenith” of diaspora on the basis of 1920, 1926, and 1939 censuses. The author identifies the principal settling areas and points out the geographical preconditions for the rapid decline of the diaspora.

  7. Combustion analysis of preheated crude sunflower oil in an IDI diesel engine

    Energy Technology Data Exchange (ETDEWEB)

    Canakci, Mustafa; Ozsezen, Ahmet Necati; Turkcan, Ali [Department of Mechanical Education, Kocaeli University, 41380 Izmit (Turkey); Alternative Fuels R and D Center, Kocaeli University, 41040 Izmit (Turkey)

    2009-05-15

    In this study, preheated crude sunflower oil (PCSO) was tested for combustion and emission properties against petroleum based diesel fuel (PBDF) in a naturally aspirated, indirect injection (IDI) engine. The cylinder gas pressure and heat release curves for PCSO at 75 C were similar to those of PBDF. The ignition delays for the PCSO were longer and the start of injection timing was earlier than for PBDF. The difference in the average brake torque was a decrease of 1.36% for PCSO though this was statistically insignificant. The brake specific fuel consumption increased by almost 5% more or less in proportion to the difference in calorific value, so that the 1.06% increase in thermal efficiency was again statistically insignificant. The emission test results showed that the decreases in CO{sub 2} emissions and smoke opacity 2.05% and 4.66%, respectively; however, this was not statistically significant, though in line with the apparent increase in thermal efficiency. There was a significant 34% improvement in the emissions of unburnt hydrocarbons. Carbon monoxide increased by 1.77% again the result was not statistically significant given the small number of repeat tests. The use of PCSO does not have any negative effects on the engine performance and emissions in short duration engine testing. (author)

  8. Enrichment of {sup 210}Po and {sup 210}Pb in ash samples from oil shale-fired power plants in Estonia

    Energy Technology Data Exchange (ETDEWEB)

    Ozden, B. [University of Tartu, Institute of Physics/Ege University, Institute of Nuclear Sciences (Estonia); Vaasma, T.; Kiisk, M.; Suursoo, S.; Tkaczyk, A.H. [University of Tartu,Institute of Physics (Estonia)

    2014-07-01

    Energy production in Estonia is largely dependent on the oil shale industry. Oil shale is a fossil fuel typically characterized by relatively high mineral composition, modest organic fraction (varying between 10 and 65%), high ash content (usually 45% to 50%), and average lower heating value of 8.4 MJ/kg{sup -1}. Oil shale-fired power plants account for 85% of Estonian electricity production and produce up to 6 million tons of oil shale ash annually. This ash contains elevated amounts of natural radionuclides (from the {sup 238}U and {sup 232}Th series and {sup 40}K), which were bound to oil shale during its formation. These radionuclides become enriched in ash fractions during the combustion process and are partially emitted to the atmosphere via fly ash and flue gases. Oil shale-fired electricity production is foreseen to remain a dominant trend in Estonia, suggesting that the radionuclide emissions to the atmosphere will continue in the future. The natural radionuclides {sup 210}Po and {sup 210}Pb, with half-lives of 138 days and 22.3 years respectively, originate from the radioactive decay of radionuclides of {sup 238}U series present in the earth's crust. These radionuclides are also built up artificially in the environment due to waste discharge from phosphate, oil, and gas industries, combustion of fossil fuels and other energy production as technically enhanced natural radionuclides. There are few studies on oil shale power plants influence on the levels of natural radioactivity in the surrounding areas. Realo, et al. reported that the annual doses from fly ash depositions over a 30 year period are in the range 90 - 200 μSv a{sup -1}. A study previously initiated by the University of Tartu, Institute of Physics (IPh) evaluated enrichment in the activity concentrations of {sup 238}U, {sup 226}Ra, {sup 210}Pb, {sup 232}Th, {sup 228}Ra and {sup 40}K in ash samples collected from Eesti Power Plant's circulating fluidized bed (CFB) boiler. According

  9. In-situ combustion with solvent injection

    Energy Technology Data Exchange (ETDEWEB)

    D' Silva, J.; Kakade, G. [Society of Petroleum Engineers, Kuala Lumpur (Malaysia)]|[Maharashtra Inst. of Technology, Pune (India)

    2008-10-15

    The effects of combining in situ combustion and heavy hydrocarbon naphtha vapor injection techniques in a heavy oil reservoir were investigated. Oil production rates and steam injection efficiencies were considered. The technique was also combined with toe-to-heel air injection (THAI) processes. The study showed that the modified THAI process achieved high rates of recovery for both primary production and as a follow-up technique in partially depleted reservoirs after cyclic steam and cold production. Oil produced using the modified THAI technique was also partially upgraded by the process. Results of the vapour chamber pressure calculations showed that the volume of oil produced by naphtha assisted gravity drainage was between 1 to 3 times higher than amounts of oil produced by SAGD processes during the same amount of time. The naphtha injection process produced more oil than the steam only process. However, high amounts of naphtha were needed to produce oil. Injection and production rates during the naphtha injection process were higher. Naphtha vapor was injected near the heel of a horizontal producer well. The vapor acted as a thermal and diluent mechanism in order to reduce the viscosity of the heavy oil . 9 refs., 4 tabs., 6 figs.

  10. Análisis de contenido del dominio tecnológico vegetable oil combustion

    Directory of Open Access Journals (Sweden)

    Noé PÉREZ-Arreortúa

    Full Text Available La patente es una medida de productividad científico-tecnológica muy utilizada como indicador tecnológico. Sus análisis está enfocado principalmente a recuentos por año, países, titulares e inventores, pero escasean los estudios de patentes considerando la clasificación técnica utilizada y la información contenida en el documento de invención. La presente investigación tiene como objetivo proponer el uso de la clasificación internacional de patentes y el análisis de contenido de determinados campos del documento de patente como unidad de análisis y medida para realizar un estudio patentométrico en el dominio tecnológico vegetable oil combustion. Se utiliza un conjunto de indicadores simples y relacionales, y el software proINTEC para el análisis y representación de los datos. La interpretación de los resultados confirma que la información contenida en las patentes de este dominio es pertinente a los intereses del proyecto que ejecuta el caso de estudio.

  11. Kuwaiti oil fires: Composition of source smoke

    Energy Technology Data Exchange (ETDEWEB)

    Cofer, W.R. III; Cahoon, D.R. [Langley Research Center, Hampton, VA (United States); Stevens, R.K.; Pinto, J.P. [Environmental Protection Agency, Research Triangle Park, NC (United States); Winstead, E.L.; Sebacher, D.I. [Hughes STX Corp., Hampton, VA (United States); Abdulraheem, M.Y. [Kuwait Environmental Protection Dept., Kuwait City (Kuwait); Al-Sahafi, M. [Ministry of Defense and Aviation, Eastern Province (Saudi Arabia); Mazurek, M.A. [Brookhaven National Lab., Upton, NY (United States); Rasmussen, R.A. [Oregon Graduate Institute of Science and Technology, Beaverton, OR (United States)] [and others

    1992-09-20

    While the Kuwaiti oil-fire smoke plumes manifested a pronounced impact on solar radiation in the Gulf region (visibility, surface temperatures, etc.), smoke plume concentrations of combustion-generated pollutants suggest that the overall chemical impact on the atmosphere of the smoke from these fires was probably much less than anticipated. Combustion in the Kuwaiti oil fires was surprisingly efficient, releasing on average more than 93% of the combusted hydrocarbon fuels as carbon dioxide (CO{sub 2}). Correspondingly, combustion-produced quantities of carbon monoxide (CO) and carbonaceous particles were low, each {approximately} 2% by weight. The fraction of methane (CH{sub 4}) produced by the fires was also relatively low ({approximately} 0.2%), but source emissions of nonmethane hydrocarbons were high ({approximately} 2%). Processes other than combustion (e.g., volatilization) probably contributed significantly to the measured in-plume hydrocarbon concentrations. Substantially, different elemental to organic carbon ratios were obtained for aerosol particles from several different types of fires/smokes. Sulfur emissions (particulate and gaseous) measured at the source fires were lower ({approximately} 0.5%) than predicted based on average sulfur contents in the crude. Sulfur dioxide measurements (SO{sub 2}) reported herein, however, were both limited in actual number and in the number of well fires sampled. Nitrous oxide (N{sub 2}O) emissions from the Kuwaiti oil fires were very low and often could not be distinguished from background concentrations. About 25-30% of the fires produced white smoke plumes that were found to be highly enriched in sodium and calcium chlorides. 18 refs., 1 fig., 4 tabs.

  12. Sleeving-back of horizontal wells to control downstream oil saturation and improve oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Greaves, M.; Saghr, A. M. [Bath Univ (United Kingdom)

    1998-12-31

    Air injection has become popular as an enhanced recovery technology, applicable over a wide variety of reservoir conditions including heavy, medium and light oils. One problem observed in light oil reservoirs is the tendency to desaturate the oil layer downstream of the moving front. This is particularly common in the case of thermal recovery processes. In this experiment designed to study ways to restrict the de-saturation of the oil layer, a modified horizontal producer well, incorporating a `sleeve-back` principal was used. The objective was to replicate the `toe-to-heel` displacement process occurring during heavy oil recovery, wherein downstream oil is essentially immobile due to its high viscosity. The `sleeve-back` of the well was achieved using a co-aligned, two-well assembly, so that the upstream section of the horizontal producer well was active, and continuously adjusted during propagation of the combustion front. The use of this continuous `sleeve-back` operation to control the level of de-saturation in the downstream section of a sand pack was successful as confirmed by the very high oil recovery achieved, equivalent to 93.5 per cent of oil in place. The level of CO{sub 2} production was also very high. The `sleeve-back` of the horizontal producer well made the light oil in-situ combustion more efficient compared to what would be expected in a fully-open well. The `sleeve-back` of the well also produced thermal contours in the sand pack that closely resembled those observed with heavy, highly viscous oil. By sealing-off the otherwise open well in the downstream part of the reservoir, the de-saturation of the oil layer was prevented. 9 refs., 4 tabs., 9 figs.

  13. Exploring Constructivist Social Learning Practices in Aiding Russian-Speaking Teachers to Learn Estonian: An Action Research Approach

    Science.gov (United States)

    Kiilo, Tatjana; Kutsar, Dagmar

    2012-01-01

    Based on appreciative inquiry and threshold concepts from an intercultural learning perspective, the article makes insights into the constructivist social learning practice of Estonian language learning amongst Russian-speaking teachers in Estonia. The application of educational action research methodology, more specifically that of Bridget…

  14. Oil supply on demand: Oil pumps in serial application; Bedarfsgerechte Oelversorgung: Regeloelpumpen im Serieneinsatz

    Energy Technology Data Exchange (ETDEWEB)

    Lamparski, C. [S H W Automotive GmbH und Co. KG, Bad Schussenried (Germany)

    2007-07-01

    Usually, constant displacement oil pumps are used for the oil supply of combustion engines. Gerotor, helical or spur gear pumps or vane pumps are the most common solutions. The disadvantage of the mentioned design is the oil delivery as function of pump speed, independent from the engine needs. Variability of oil delivery for reduction of hydraulic losses is the logical consequence. The first variable displacement oil pump which has fulfilled this requirement is the Internal Regulated Oil Pump (IRP). The mass production of this oil pump started in 2002. The solution for outer gear pumps and vane cells followed shortly. The following contribution gives a summary of different technical concepts for adjusting of oil delivery, beginning with pump pressure as a leading value till map regulation and its transformation in mass production products. (orig.)

  15. Desempenho de misturas pré-aquecidas de óleo de soja cru e diesel como combustível para motores agrícolas Performance of preheated crude soybean oil-diesel blends as fuel in agricultural engines

    Directory of Open Access Journals (Sweden)

    José Fernando Schlosser

    2007-10-01

    Full Text Available O óleo de soja é um dos óleos vegetais que têm potencial de uso como combustível para motores diesel, pois é renovável, seguro e de fácil utilização. Em temperatura ambiente, o óleo cru apresenta uma viscosidade cerca de dez vezes maior que a do óleo diesel. Para reduzir a viscosidade do óleo de soja a níveis aceitáveis, é necessária uma temperatura de aquecimento em torno de aproximadamente 60°C ou misturá-lo com óleo diesel. O objetivo deste estudo foi avaliar o desempenho do óleo de soja cru e suas misturas com óleo diesel, pré-aquecidas antes da bomba injetora entre 57°C e 68°C, como combustível para motores diesel. O desempenho das misturas combustíveis foi avaliado num motor monocilíndrico de injeção indireta e comparado com o obtido pelo óleo diesel. Os ensaios de curta duração foram conduzidos entre 1.800 e 2.800rpm, sob condição de plena carga em dinamômetro hidráulico. Ensaios realizados a 68°C apresentaram sempre os melhores valores para torque, potência e consumo específico de combustível do que a 57°C. Uma mistura composta por 70% de óleo de soja e 30% de óleo diesel, aquecida a 68°C, apresentou os melhores resultados.Crude soybean oil is one of the vegetable oils that have potential for use as fuel for diesel engines. Soybean oil is renewable, and is safe and easy to handle. At room temperature crude oil has a viscosity about ten times higher than that of diesel oil. To lower soybean oil's viscosity to the acceptable levels a heating temperature at least 60°C is needed or blending with diesel fuel. The objective of this study was evaluating the soybean oil and blends performance as a fuel for diesel engines. On both crude soybean oil and soybean oil blends were used pre-heating temperature levels on the range between 57°C and 68°C, before fuel pump. The performance of the fuel blends were evaluated in a single cylinder indirect injection diesel engine and compared with the performance

  16. Comparing the greenhouse gas emissions from three alternative waste combustion concepts

    International Nuclear Information System (INIS)

    Vainikka, Pasi; Tsupari, Eemeli; Sipilä, Kai; Hupa, Mikko

    2012-01-01

    Highlights: ► Significant GHG reductions are possible by efficient WtE technologies. ► CHP and high power-to-heat ratio provide significant GHG savings. ► N 2 O and coal mine type are important in LCA GHG emissions of FBC co-combustion. ► Substituting coal and fuel oil by waste is beneficial in electricity and heat production. ► Substituting natural gas by waste may not be reasonable in CHP generation. - Abstract: Three alternative condensing mode power and combined heat and power (CHP) waste-to-energy concepts were compared in terms of their impacts on the greenhouse gas (GHG) emissions from a heat and power generation system. The concepts included (i) grate, (ii) bubbling fluidised bed (BFB) and (iii) circulating fluidised bed (CFB) combustion of waste. The BFB and CFB take advantage of advanced combustion technology which enabled them to reach electric efficiency up to 35% and 41% in condensing mode, respectively, whereas 28% (based on the lower heating value) was applied for the grate fired unit. A simple energy system model was applied in calculating the GHG emissions in different scenarios where coal or natural gas was substituted in power generation and mix of fuel oil and natural gas in heat generation by waste combustion. Landfilling and waste transportation were not considered in the model. GHG emissions were reduced significantly in all of the considered scenarios where the waste combustion concepts substituted coal based power generation. With the exception of condensing mode grate incinerator the different waste combustion scenarios resulted approximately in 1 Mton of fossil CO 2 -eq. emission reduction per 1 Mton of municipal solid waste (MSW) incinerated. When natural gas based power generation was substituted by electricity from the waste combustion significant GHG emission reductions were not achieved.

  17. Coal combustion products: trash or treasure?

    Energy Technology Data Exchange (ETDEWEB)

    Hansen, T.

    2006-07-15

    Coal combustion by-products can be a valuable resource to various industries. The American Coal Ash Association (ACAA) collects data on production and uses of coal combustion products (CCPs). 122.5 million tons of CCPs were produced in 2004. The article discusses the results of the ACCA's 2004 survey. Fly ash is predominantly used as a substitute for Portland cement; bottom ash for structural fill, embankments and paved road cases. Synthetic gypsum from the FGD process is commonly used in wallboard. Plant owners are only likely to have a buyer for a portion of their CCPs. Although sale of hot water (from Antelope Valley Station) from condensers for use in a fish farm to raise tilapia proved unviable, the Great Plains Synfuels Plant which manufactures natural gas from lignite produces a wide range of products including anhydrous ammonia, phenol, krypton, carbon dioxide (for enhanced oil recovery), tar oils and liquid nitrogen. ACCA's goal is to educate people about CCPs and how to make them into useful products, and market them, in order to reduce waste disposal and enhance revenue. The article lists members of the ACCA. 2 photos., 1 tab.

  18. A comparative estimation of C.I. engine fuelled with methyl esters of punnai, neem and waste cooking oil

    Energy Technology Data Exchange (ETDEWEB)

    Subramaniam, D.; Avinash, A. [Department of Mechanical Engineering - K.S.Rangasamy College of Technology –Tiruchengode, 637215 Tamil Nadu (India); Murugesan, A. [Department of Mechatronics Engineering - K.S.Rangasamy College of Technology – Tiruchengode, 637215 Tamil Nadu (India)

    2013-07-01

    In this experimental study, performance, emission, and combustion characteristics of methyl esters of Punnai, Neem, Waste Cooking Oil and their diesel blends in a C.I. engine was experimentally examined. For the study, Punnai oil methyl esters (POME), neem oil methyl esters (NOME), and Waste Cooking Oil Methyl Esters (WCOME) were prepared by tranesterification process. The Bio diesel-diesel blends were prepared by mixing 10%, 30%, 50%, and 70% of bio diesel with diesel. The effects of three methyl esters and their diesel blends on engine performance, combustion, and exhaust emissions were examined at different engine loads. Experimental results concluded that up to 30% of methyl esters did not affect the performance, combustion, and emissions characteristics. On the other hand, above B30 (30% Bio diesel with 70% diesel) a reduction in performance, combustion, and emission characteristics were clear from the study.

  19. Non-market value of Estonian seminatural grasslands: a contingent valuation study. Eesti poolloodusliku rohumaa turuväline väärtus: tingliku hindamise uuring

    Directory of Open Access Journals (Sweden)

    Helli Lepasaar

    2015-12-01

    Full Text Available Seminatural grasslands i.e. the floodplain meadows, seashore meadows, wooded meadows, dry meadows, wooded pastures are the very traditional part of Estonian landscapes, which play an important role in the appearance of the landscape in general and also serve as an important habitat for many plant and animal species. In order to preserve the seminatural grasslands continuous annual mowing and/or pasturing is needed. This activity is not economically profitable and needs subsidizing. The authors of the work raise a hypothesis that the Estonian seminatural grasslands could be viewed as a valuable non-market environmental good for which a significant public demand exists. In order to find out the non-market value of the seminatural grasslands a contingent valuation study was carried out among the Estonian working-age population (size of the sample 1061 individuals. The average individual willingness to pay was 11.3 euros. During the study, the authors constructed the total demand function and discovered that the total annual demand for seminatural grasslands was 17.9 million euros.

  20. Combustion, Performance, and Emission Evaluation of a Diesel Engine with Biodiesel Like Fuel Blends Derived From a Mixture of Pakistani Waste Canola and Waste Transformer Oils

    Directory of Open Access Journals (Sweden)

    Muhammad Qasim

    2017-07-01

    Full Text Available The aim of this work was to study the combustion, performance, and emission characteristics of a 5.5 kW four-stroke single-cylinder water-cooled direct-injection diesel engine operated with blends of biodiesel-like fuel (BLF15, BLF20 & BLF25 obtained from a 50:50 mixture of transesterified waste transformer oil (TWTO and waste canola oil methyl esters (WCOME with petroleum diesel. The mixture of the waste oils was named as biodiesel-like fuel (BLF.The engine fuelled with BLF blends was evaluated in terms of combustion, performance, and emission characteristics. FTIR analysis was carried out to know the functional groups in the BLF fuel. The experimental results revealed the shorter ignition delay and marginally higher brake specific fuel consumption (BSFC, brake thermal efficiency (BTE and exhaust gas temperature (EGT values for BLF blends as compared to diesel. The hydrocarbon (HC and carbon monoxide (CO emissions were decreased by 10.92–31.17% and 3.80–6.32%, respectively, as compared to those of diesel fuel. Smoke opacity was significantly reduced. FTIR analysis has confirmed the presence of saturated alkanes and halide groups in BLF fuel. In comparison to BLF20 and BLF25, the blend BLF15 has shown higher brake thermal efficiency and lower fuel consumption values. The HC, CO, and smoke emissions of BLF15 were found lower than those of petroleum diesel. The fuel blend BLF15 is suggested to be used as an alternative fuel for diesel engines without any engine modification.

  1. Study of ignition characteristics of microemulsion of coconut oil under off diesel engine conditions

    Directory of Open Access Journals (Sweden)

    Mahir H. Salmani

    2015-09-01

    Full Text Available The increasing awareness of the depletion of fossil fuel resources and the environmental benefits motivates the use of vegetable oils, however there is little known information about ignition and combustion characteristics of vegetable oil based fuels under off diesel engine conditions. These conditions are normally reached either during starting or when the engine is sufficiently worn out. A fuel was prepared by co-solvent blending of coconut oil with 20% butyl alcohol and was analysed. An experimental study of the measurement of ignition delay (ID characteristics of conical fuel sprays impinging on hot surface in cylindrical combustion chamber was carried out. The objective of the study was to investigate the effect of hot surface temperatures on ignition delays of microemulsion of coconut oil at various ambient air pressures and temperatures which would have reached under off diesel engine conditions. An experimental set-up was designed and developed for a maximum air pressure of 200 bar and a maximum temperature of 800 °C with the emphasis on optical method for the measurement of ignition delay. Hot surface temperature range chosen was 300–450 °C and ambient air pressure (inside the combustion chamber range chosen was 10–25 bar. Present study shows that at fixed injection pressure and fixed ambient (hot surface temperature, at higher ambient air pressure (25 bar inside the combustion chamber, ignition delay of diesel and microemulsion of coconut oil are comparable and therefore are having matching combustion characteristics. Although a pressure of 25 bar is much less than the precombustion pressure of most diesel engines but again conclusively establish that combustion characteristics are same despite lower air pressure, temperature and lower injection pressure. At higher injection pressure ignition delay of microemulsion of coconut oil and pure diesel attains the lower value at the same ambient air pressure inside the

  2. Studies of emissions from oil fires

    International Nuclear Information System (INIS)

    Fingas, M.; Lambert, L.; Wang, Z.; Li, K.; Ackerman, F.; Goldthorp, M.

    2001-01-01

    The use of in situ burning as a cleanup method for oil spills on water has received limited acceptance despite the fact that the method has been tried for more than 30 years. This lack of acceptance is mainly due to a poor understanding about combustion products and the issues involving the combustibility of oil-on-water. This paper presents results of a collaborative effort of several agencies in the United States and Canada to extensively research the many facets of burning oil. More than 45 mesoscale burns were conducted to examine the various aspects of diesel and crude oil burning in-situ. Sampling and monitoring of these burns was conducted at downwind stations, upwind stations and in the smoke plumes. This research effort has resulted in data which has led to a broader acceptance of in-situ burning as a viable spill countermeasure alternative. However, the concern over atmospheric emissions is the biggest barrier to the widespread use of burning. Emissions include the smoke plume, particulate matter precipitation, combustion gases, unburned hydrocarbons, organic compounds and the residue soot left at the burning pool site. A complete analysis of the emissions was performed by measuring all of these components. Particulate samples were taken in the air and analyzed for polycyclic aromatic hydrocarbons (PAHs). PAHs were found to be lower in the soot than in the starting oil, but higher concentrations of the larger molecular PAHs were found in the soot and residue, particularly for diesel burns. In general, between 92 to 98 per cent of the PAHs were destroyed. Diesel fires were found to emit more particulate matter and have longer danger zones. Combustion gases were found to be below exposure level maximums. Volatile organic compounds emissions were extensive from the fires, but the levels were less than from an evaporating oil spill. This paper included several tables indicating the 140 compounds that were identified and quantified. Prediction equations were

  3. Numerical investigation of exhaust gas emissions for a dual fuel engine configuration using diesel and pongamia oil.

    Science.gov (United States)

    Mohamed Ibrahim, N H; Udayakumar, M

    2016-12-01

    The investigation presented in this paper focuses on determination of gaseous exhaust emissions by computational simulation during combustion in compression ignition engine with pongamia oil substitution. Combustion is modeled using Equilibrium Constants Method (ECM) with MATLAB program to calculate the mole fraction of 10 combustion products when pongamia oil is burnt along with diesel at variable equivalence ratio and blend ratio. It had been observed that pongamia oil substitution causes decrease in the CO emission and increase in the NO x emission as the blend ratio as well as equivalence ratio increases. Copyright © 2015 Elsevier Inc. All rights reserved.

  4. delta 13C analyses of vegetable oil fatty acid components, determined by gas chromatography--combustion--isotope ratio mass spectrometry, after saponification or regiospecific hydrolysis.

    Science.gov (United States)

    Woodbury, S E; Evershed, R P; Rossell, J B

    1998-05-01

    The delta 13C values of the major fatty acids of several different commercially important vegetable oils were measured by gas chromatography--combustion--isotope ratio mass spectrometry. The delta 13C values obtained were found to fall into two distinct groups, representing the C3 and C4 plants classes from which the oils were derived. The delta 13C values of the oils were measured by continuous flow elemental isotope ratio mass spectrometry and were found to be similar to their fatty acids, with slight differences between individual fatty acids. Investigations were then made into the influence on the delta 13C values of fatty acids of the position occupied on the glycerol backbone. Pancreatic lipase was employed to selectively hydrolyse fatty acids from the 1- and 3-positions with the progress of the reaction being followed by high-temperature gas chromatography in order to determine the optimum incubation time. The 2-monoacylglycerols were then isolated by thin-layer chromatography and fatty acid methyl esters prepared. The delta 13C values obtained indicate that fatty acids from any position on the glycerol backbone are isotopically identical. Thus, whilst quantification of fatty acid composition at the 2-position and measurement of delta 13C values of oils and their major fatty acids are useful criteria in edible oil purity assessment, measurement of delta 13C values of fatty acids from the 2-position does not assist with oil purity assignments.

  5. The 2011 Estonian High School Language Reform in the Context of Critical Language Policy and Planning

    Science.gov (United States)

    Skerrett, Delaney Michael

    2014-01-01

    This paper seeks to situate Estonian language use and policy within the emerging field of critical language policy and planning (CLPP) by investigating the discourses that frame linguistic behaviour. This done by way of an analysis of a series of interviews carried out with key actors in language policy in Estonia. The discourses framing language…

  6. The Challenges Organic Food Processors Meet at Small Emerging Market – Estonian Case

    OpenAIRE

    Sarapuu, Kerttu; Pehme, Sirli; Peetsmann, Elen; Matt, Darja

    2014-01-01

    Organic farming and demand for organic products is continually a growing trend all over the world (Willer et al., 2013). In Estonia the share of organic land is 15% of all agricultural land and the number of organic farmers is also growing (Vetemaa, Mikk 2013). Estonian organic food market is still in forming stage being affected by local organic farming development, marketing situation, economic situation and consumer attitudes. Organic processing has clearly not kept up with organic farming...

  7. DOE/DOT Crude Oil Characterization Research Study, Task 2 Test Report on Evaluating Crude Oil Sampling and Analysis Methods

    Energy Technology Data Exchange (ETDEWEB)

    Lord, David [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Allen, Ray [Allen Energy Services, Inc., Longview, TX (United States); Rudeen, David [GRAM, Inc., Albuquerque, NM (United States)

    2017-11-01

    The Crude Oil Characterization Research Study is designed to evaluate whether crude oils currently transported in North America, including those produced from "tight" formations, exhibit physical or chemical properties that are distinct from conventional crudes, and how these properties associate with combustion hazards with may be realized during transportation and handling.

  8. TEM investigations of microstructures of combustion aerosols

    International Nuclear Information System (INIS)

    Marquardt, A.; Hackfort, H.; Borchardt, J.; Schober, T.; Friedrich, J.

    1992-12-01

    In the incineration of organic material, apart from a series of gaseous pollutants, particulate pollutants or combustion aerosols also arise. The latter frequently consist of particles with a solid core of carbon to which a large number of inorganic and organic compounds are attached. These primarily include the polycyclic aromatic hydrocarbons (PAH) and their nitro-derivatives (NPAH), whose mutagenic or carcinogenic effect is known. The invisible particle sizes in the nanometer range, whose retention in the incineration off-gas is not state of the art, are of increasing significance for man and environment. On the one hand, they are deposited almost completely in the human lung. On the other hand, due to their fine dispersity they have along residence time in the atmosphere where they participate in chemical reactions and climatically significant processes. Important insights about the formation process of combustion aerosols are to be expected from the imaging of their microstructures in the transmission electron microscope (TEM). The present contribution describes the development and application of a representative sampling procedure for aerosols from a partial flow of flue gas from a fluidized-bed furnace. The method developed consists of electrically charging aerosol particles in situ and subsequently selectively precipitating them onto a microscope slide in an electric field. TEM studies of aerosol microstructures on the microscope slides revealed that in the combustion of petrol and heating oil under different combustion conditions in principle the same particle structures result, whereas in the incineration of used lubricating oil quite different particle structures were found. Results from the literature on aerosol microstructures in exhaust gases from petrol and diesel engines demonstrate agreement with the results of this study in the basic structure of the particles. (orig.) [de

  9. The Dominance of Indirect Taxes in Estonian State Budget

    Directory of Open Access Journals (Sweden)

    Olev Raju

    2013-01-01

    Full Text Available Recession has sharply erected the question of tax burden and the optimal proportion of different kinds of taxes among the incomes of the budget. Indirect taxes and consumption taxes, which proportion is different according to different methodologies, dominate in Estonian state budget. The buoyancy of a tax system based on taxes of that kind is especially weak during the recession. Difficulties concerning the incomes of budget have arisen the necessity for lifting taxes, which is possible as the tax burden is low now. But a sharp question of the optimal level of taxes is going to be raised. A formula for indirect tax optimum according to Ramsey taxes and Slutski decomposition has been proposed in the article.

  10. Mental health and alcohol problems among Estonian cleanup workers 24 years after the Chernobyl accident.

    Science.gov (United States)

    Laidra, Kaia; Rahu, Kaja; Tekkel, Mare; Aluoja, Anu; Leinsalu, Mall

    2015-11-01

    To study the long-term mental health consequences of the 1986 Chernobyl nuclear accident among cleanup workers from Estonia. In 2010, 614 Estonian Chernobyl cleanup workers and 706 geographically and age-matched population-based controls completed a mail survey that included self-rated health, the Posttraumatic Stress Disorder Checklist (PCL), alcohol symptoms (AUDIT), and scales measuring depressive, anxiety, agoraphobia, fatigue, insomnia, and somatization symptoms. Respondents were dichotomized into high (top quartile) and low symptom groups on each measure. Logistic regression analysis detected significant differences between cleanup workers and controls on all measures even after adjustment for ethnicity, education, marital status, and employment status. The strongest difference was found for somatization, with cleanup workers being three times more likely than controls to score in the top quartile (OR = 3.28, 95% CI 2.39-4.52), whereas for alcohol problems the difference was half as large (OR = 1.52, 95% CI 1.16-1.99). Among cleanup workers, arrival at Chernobyl in 1986 (vs. later) was associated with sleep problems, somatization, and symptoms of agoraphobia. The toll of cleanup work was evident 24 years after the Chernobyl accident among Estonian cleanup workers indicating the need for focused mental health interventions.

  11. Fuel oil-water emulsions combustion and application perspectives in Mexico; Combustion de emulsiones de agua en combustoleo y perspectivas de aplicacion en Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Ocampo Barrera, Rene [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1998-09-01

    Fuel drops with a content of 16% by weight were burned in three emulsions prepared with 5%, 15% and 25% water. The combustion of the drops was carried out in an spherical furnace utilizing the technique of a drop suspended in a filament. The combustion process was registered by a high velocity video system. It was found that the surface of the particles produced by the combustion of the emulsions, had larger holes than the ones of the fuel, therefore it is expected that emulsifying the fuel can help in reducing the unburned particles emission. [Espanol] Se quemaron gotas de un combustoleo, con un contenido de asfaltenos del 16% en peso, y de tres emulsiones preparadas con 5%, 15% y 25% de agua. La combustion de las gotas se llevo a cabo en un horno esferico empleando la tecnica de gota suspendida en un filamento. El proceso de combustion se registro mediante un sistema de video de alta velocidad. Se encontro que la superficie de las particulas de coque, producidas por la combustion de emulsiones, tuvo hoyos mas grandes que la del combustoleo, por lo que es de esperarse que emulsionar el combustoleo puede ayudar a reducir las emisiones de particulas inquemadas.

  12. Proficiency Assessment of Male Volleyball Teams of the 13-15-Year Age Group at Estonian Championships

    Science.gov (United States)

    Stamm, Meelis; Stamm, Raini; Koskel, Sade

    2008-01-01

    Study aim: Assessment of feasibility of using own computer software "Game" at competitions. Material and methods: The data were collected during Estonian championships in 2006 for male volleyball teams of the 13-15-years age group (n = 8). In all games, the performance of both teams was recorded in parallel with two computers. A total of…

  13. Combustion characteristics of the mustard methyl esters

    International Nuclear Information System (INIS)

    Bannikov, M.G.; Vasilev, I.P.

    2011-01-01

    Mustard Methyl Esters (further bio diesel) and regular diesel fuel were tested in direct injection diesel engine. Analysis of experimental data was supported by an analysis of fuel injection and combustion characteristics. Engine fuelled with bio diesel had increased brake specific fuel consumption, reduced nitrogen oxides emission and smoke opacity, moderate increase in carbon monoxide emission with essentially unchanged unburned hydrocarbons emission. Increase in fuel consumption was attributed to lesser heating value of bio diesel and partially to decreased fuel conversion efficiency. Analysis of combustion characteristics revealed earlier start of injection and shorter ignition delay period of bio diesel. Resulting decrease in maximum rate of heat release and cylinder pressure was the most probable reason for reduced emission of nitrogen oxides. Analysis of combustion characteristics also showed that cetane index determined by ASTM Method D976 is not a proper measure of ignition quality of bio diesel. Conclusion was made on applicability of mustard oil as a source for commercial production of bio diesel in Pakistan. Potentialities of on improving combustion and emissions characteristics of diesel engine by reformulating bio diesel were discussed. (author)

  14. Oil shale (in memoriam)

    International Nuclear Information System (INIS)

    Strandberg, Marek

    2000-01-01

    Plans for the continued use of oil shale may lead the development of this country into an impasse. To this day no plans have been made for transition from the use of energy based on fossil fuels to that based on renewable resources. Without having any clear strategic plan politicians have been comforting both themselves and the population with promises to tackle the problem when the right time comes. Today the only enterprise whose cash flows and capital would really make it possible to reform the power industry is the firm Eesti Energia (Estonian Energy). However, its sole present shareholder - the state - prefers the sale of the firm's shares to carrying out a radical reform. At the same time, local consumers are likely to rather be willing to pay for the expensive electric energy produced from renewable resources than for that produced from fossil fuels, the price of which will also remain high due to the pollution tax. Practically it is impossible to buy a globally balanced environment for money - pollution taxes are but punitive mechanisms. The investments made into the oil-shale industry will also reinforce the cultural distance of North-East Estonia from the rest of Estonia - the uniform and prevalently Russian-speaking industrial area will be preserved as long as capital will continue to flow into the oil shale industry concentrated there. The way out would be for industries to make wider use of ecological and ecosystemic technologies and for the state to enforce ecologically balanced economic and social policies. (author)

  15. Emissions Characteristics of Small Diesel Engine Fuelled by Waste Cooking Oil

    Directory of Open Access Journals (Sweden)

    Khalid Amir

    2014-07-01

    Full Text Available Biodiesel is an alternative, decomposable and biological-processed fuel that has similar characteristics with mineral diesel which can be used directly into diesel engines. However, biodiesel has oxygenated, more density and viscosity compared to mineral diesel. Despite years of improvement attempts, the key issue in using waste cooking oil-based fuels is oxidation stability, stoichiometric point, bio-fuel composition, antioxidants on the degradation and much oxygen with comparing to diesel gas oil. Thus, the improvement of emission exhausted from diesel engines fueled by biodiesel derived from waste cooking oil (WCO is urgently required to meet the future stringent emission regulations. The purpose of this research is to investigate the influences of WCO blended fuel and combustion reliability in small engine on the combustion characteristics and exhaust emissions. The engine speed was varied from 1500-2500 rpm and WCO blending ratio from 5-15 vol% (W5-W15. Increased blends of WCO ratio is found to influences to the combustion process, resulting in decreased the HC emissions and also other exhaust emission element. The improvement of combustion process is expected to be strongly influenced by oxygenated fuel in biodiesel content.

  16. Experimental Investigation and High Resolution Simulation of In-Situ Combustion Processes

    Energy Technology Data Exchange (ETDEWEB)

    Margot Gerritsen; Tony Kovscek

    2008-04-30

    This final technical report describes work performed for the project 'Experimental Investigation and High Resolution Numerical Simulator of In-Situ Combustion Processes', DE-FC26-03NT15405. In summary, this work improved our understanding of in-situ combustion (ISC) process physics and oil recovery. This understanding was translated into improved conceptual models and a suite of software algorithms that extended predictive capabilities. We pursued experimental, theoretical, and numerical tasks during the performance period. The specific project objectives were (i) identification, experimentally, of chemical additives/injectants that improve combustion performance and delineation of the physics of improved performance, (ii) establishment of a benchmark one-dimensional, experimental data set for verification of in-situ combustion dynamics computed by simulators, (iii) develop improved numerical methods that can be used to describe in-situ combustion more accurately, and (iv) to lay the underpinnings of a highly efficient, 3D, in-situ combustion simulator using adaptive mesh refinement techniques and parallelization. We believe that project goals were met and exceeded as discussed.

  17. Where Do Dead Books Go? The Problem of the Soviet Canon Today, on the Example of Johannes Becher's Work in Estonian

    Directory of Open Access Journals (Sweden)

    Katre Talviste

    2013-06-01

    Full Text Available The article describes the conception and editing process of an anthology of Johannes Becher’s poems (Unistades täiusest, 1962 in Estonian, and discusses its status in the Soviet and contemporary literary canon. The work on the Becher anthology was led by an already outstanding literary scholar Nigol Andresen and a young poet and translator Ain Kaalep, who later became one of the most prolific and wellknown poetry translators in Estonia. An important part was also played by another poet-translator, August Sang, who already had achieved such a standing in the Estonian literary field. Several other translators contributed to the anthology, making it a common project for intellectuals otherwise very differently positioned vis-à-vis the Soviet political authorities and cultural agendas. Becher’s work was strongly promoted by these instances, but his poetry was also read with genuine enthusiasm by the main contributors to the anthology (whose own poetry has certain parallels to some aspects of Becher’s, as well as the general public, at that time. After the fall of the Soviet regime it has been forgotten, mostly for the same contextual reasons that once granted its success. The case of his poetry in Estonian explores the question of this new invisibility of now politically irrelevant, but still voluminous and aesthetically intriguing literary works in the post-Soviet canon.

  18. 40 CFR 60.1555 - Are any small municipal waste combustion units exempt from my State plan?

    Science.gov (United States)

    2010-07-01

    ... qualifies for the exemption. (d) Municipal waste combustion units that combust only tires. Units are exempt... single-item waste stream of tires and no other municipal waste (the unit can co-fire coal, fuel oil.../rubber recycling units. Units are exempt from your State plan if four requirements are met: (1) The...

  19. Oil use of the effluent plant ETEO (Effluent Station of Oil Treatment) as combustible for generation of energy in the power plant UG-50Hz; Utulizacao de oleo da ETEO (Estacao de Tratamento de Efluentes Oleosos) para geracao de energia na UG-50Hz

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Jose Francisco de; Nascimento, Jose Maria do; Silva, Luiz Antonio da; Salazar, Marcos Vinicios; Baptista, Reinaldo Lopes; Barros, Sueli Aguiar [Companhia Siderurgica Nacional (CSN), Volta Redonda, RJ (Brazil)

    2009-11-01

    The areas of finishing products of CSN Steel Plant generate contaminated effluents with oil and grease , that are treated in ETEO (Effluent Station of Oil Treatment). In this plant, the oil is processed to be sold for the consuming market. However, some seasons of the year, the market does not absorb the oil, and CSN is obliged to defray the burning of this oil, to not interrupt the productive process and cause an environmental impact. Because of this situation, we search alternatives for the viable use of this oil inside CSN steel plant, taking care for the security of the processes and the impact to the environment. This paper describes the details of the work and the implantation of the burning of this oil of the ETEO with BPF oil (type of petrochemical oil) as combustible in the boiler 7 of the power plant UG 50 Hz. For the implantation of this project, operational contingencies of security for equipment was prepared . Moreover, the work included chemical analyses of the oil and the conditions of the boiler using this mixing of oils. The reached results demonstrate the total viability of this project and it was proved another alternative of the use of this residue, with reduction of the fuel costs , steam costs and the electric energy generated in the power plant of CSN. (author)

  20. With or without articles? A comparison of article-like determiners in Estonian and Finnish

    Directory of Open Access Journals (Sweden)

    Helen Hint

    2017-10-01

    Full Text Available In this paper, we compare the use and functions of definite and indefinite article-like determiners in Estonian and Finnish. Our main aim is to explore whether the factors that explain the choice of particular determiner forms are similar in Estonian and Finnish. We use a picture-sequence based elicitation experiment to collect spoken narratives from adult native speakers of Estonian and Finnish, and apply non-parametric tree and forest models to analyze the data. Our findings indicate that number of mention and animacy are important predictor variables in both languages, but their exact effect is divergent. We also find that in Finnish, case of the determiner NP proves to be an important factor, while in Estonian, syntactic role of the NP explains some aspects of determiner form choice. Nevertheless, the overall usage frequency of determiners is modest in the Estonian and Finnish data, and the process of grammaticalizing articles is only in initial stages in both languages. *** Artikliga, artiklita? Eesti ja soome keele artiklilaadsete määratlejate võrdlus Siinses uurimuses analüüsime võrdlevalt artiklilaadseid definiitseid ja indefiniitseid määratlejaid eesti ja soome keeles. Eelkõige kõrvutame eesti keele definiitset määratlejat see ja soome keele definiitseid määratlejaid se ja tämä ning eesti ja soome indefiniitset määratlejat üks/yks(i. Samuti vaatleme eesti keele possessiivpronoomeni oma ning soome 3sg possessiivsufiksi (-nsa/-nsä, -Vn referentsiaalseid omadusi. Uurimuse põhieesmärgiks on selgitada, millised on peamised määratlejate kasutust mõjutavad keelelised faktorid eesti ja soome keeles ning kas need faktorid on keeliti sarnased või erinevad. Ühtlasi otsime vastust küsimusele, kas eesti ja soome keeles on põhjust rääkida määratlejate grammatisatsioonist artikliteks. Uuritav keelematerjal pärineb pildiseeria põhjal kogutud suulistest narratiividest. Uurimuses osales 20 eesti ja 20 soome keele

  1. DEVELOPMENT OF A VORTEX CONTAINMENT COMBUSTOR FOR COAL COMBUSTION SYTEMS

    Science.gov (United States)

    The report describes the development of a vortex containment combustor (VCC) for coal combustion systems, designed to solve major problems facing the conversion of oil- and gas-fired boilers to coal (e.g., derating, inorganic impurities in coal, and excessive formation of NOx and...

  2. Construction of combustion models for rapeseed methyl ester bio-diesel fuel for internal combustion engine applications.

    Science.gov (United States)

    Golovitchev, Valeri I; Yang, Junfeng

    2009-01-01

    Bio-diesel fuels are non-petroleum-based diesel fuels consisting of long chain alkyl esters produced by the transesterification of vegetable oils, that are intended for use (neat or blended with conventional fuels) in unmodified diesel engines. There have been few reports of studies proposing theoretical models for bio-diesel combustion simulations. In this study, we developed combustion models based on ones developed previously. We compiled the liquid fuel properties, and the existing detailed mechanism of methyl butanoate ester (MB, C(5)H(10)O(2)) oxidation was supplemented by sub-mechanisms for two proposed fuel constituent components, C(7)H(16) and C(7)H(8)O (and then, by mp2d, C(4)H(6)O(2) and propyne, C(3)H(4)) to represent the combustion model for rapeseed methyl ester described by the chemical formula, C(19)H(34)O(2) (or C(19)H(36)O(2)). The main fuel vapor thermal properties were taken as those of methyl palmitate C(19)H(36)O(2) in the NASA polynomial form of the Burcat database. The special global reaction was introduced to "crack" the main fuel into its constituent components. This general reaction included 309 species and 1472 reactions, including soot and NO(x) formation processes. The detailed combustion mechanism was validated using shock-tube ignition-delay data under diesel engine conditions. For constant volume and diesel engine (Volvo D12C) combustion modeling, this mechanism could be reduced to 88 species participating in 363 reactions.

  3. Ignition technique for an in situ oil shale retort

    Science.gov (United States)

    Cha, Chang Y.

    1983-01-01

    A generally flat combustion zone is formed across the entire horizontal cross-section of a fragmented permeable mass of formation particles formed in an in situ oil shale retort. The flat combustion zone is formed by either sequentially igniting regions of the surface of the fragmented permeable mass at successively lower elevations or by igniting the entire surface of the fragmented permeable mass and controlling the rate of advance of various portions of the combustion zone.

  4. Noor-Eesti enesekoloniseerimisprojekt. Teine osa Olulised kirjandusmõtteviisid . The Self-Colonization Project of Young Estonia. Part II. Modes of Literary Thinking and Relations with Colonialism in Estonian Literature of the beginning of the 20th century

    Directory of Open Access Journals (Sweden)

    Tiit Hennoste

    2012-04-01

    Full Text Available The topic of this article is the literary discourse of Young Estonia; its relations with other important Estonian literary discourses from the beginning of the 20th century, and its relations with colonial cultural discourse. First, I give an overview of the basic positions of the Young Estonians’ literary discourse, the main shapers of which were Friedebert Tuglas, Gustav Suits, later on Johannes Semper as well. Next, I present the basic principles of three Estonian literary discourses from the beginning of the 20th century, which were also important to the Young Estonians: nationalist-naturalistic (close-to-life; socialist/ class-based, and 20th century modernist. The Young Estonians began as nationalists and/or socialists. During the formation of Young Estonia’s discourse at the end of the first and beginning of the second decade of the 20th century, 20th century modernism began, which the Young Estonians regarded first and foremost with irony. The Young Estonians’ literary discourse is a mixture of aestheticism, decadence, symbolism, romanticism, and classicism. The point of departure for the Young Estonian approach to literature was eurocentrism. They took a superior and negative view of existing Estonian literature, which they regarded as having fallen drastically behind Europe. Since it was unable to build on its own foundation, it had to borrow from Europe. The discourse’s understandings of cultural values – theory, reading, knowledge, ready-made culture, derive from the centrality of the dynamic of borrowing. New culture could be created freely, without the support of previous local tradition; it was to be an elite culture, while the writer remained an individualist. Literature was to follow the principle of art for art’s sake; aesthetics and the form of the work of art were basic criteria. The formal ideals of the work of art were classicist: unity, integrity (wholeness, harmony, order, logic, etc. Thirdly, I outline the

  5. RESEARCH OIL RECOVERY MECHANISMS IN HEAVY OIL RESERVOIRS

    Energy Technology Data Exchange (ETDEWEB)

    Anthony R. Kovscek; William E. Brigham

    1999-06-01

    The United States continues to rely heavily on petroleum fossil fuels as a primary energy source, while domestic reserves dwindle. However, so-called heavy oil (10 to 20{sup o}API) remains an underutilized resource of tremendous potential. Heavy oils are much more viscous than conventional oils. As a result, they are difficult to produce with conventional recovery methods such as pressure depletion and water injection. Thermal recovery is especially important for this class of reservoirs because adding heat, usually via steam injection, generally reduces oil viscosity dramatically. This improves displacement efficiency. The research described here was directed toward improved understanding of thermal and heavy-oil production mechanisms and is categorized into: (1) flow and rock properties; (2) in-situ combustion; (3) additives to improve mobility control; (4) reservoir definition; and (5) support services. The scope of activities extended over a three-year period. Significant work was accomplished in the area of flow properties of steam, water, and oil in consolidated and unconsolidated porous media, transport in fractured porous media, foam generation and flow in homogeneous and heterogeneous porous media, the effects of displacement pattern geometry and mobility ratio on oil recovery, and analytical representation of water influx. Significant results are described.

  6. Emission studies from combustion of empty fruit bunch pellets in a fluidized bed combustor

    Science.gov (United States)

    Fazli Othaman, Muhamad; Sabudin, Sulastri; Faizal Mohideen Batcha, Mohd

    2017-08-01

    Malaysia is producing a very large amount of biomass annually from milling activities of oil palm. This biomass is currently being used efficiently in many ways including as fuel for boilers together with fossil fuels. This paper reports the emission characteristics from biomass combustion in a swirling fluidized bed combustor (SFBC). Pelletized empty fruit bunch (PEFB), one of largest biomass produced from oil palm industries were used as fuel in the present study. Combustion experiments were conducted with several quantitiesof excess air: 20%, 40%, 60% and 80% for a constant fuel feedrate of 30kg/hr. The effect of excess air was investigated for three major emissions gaseous namely CO, CO2 and NOx. Fly ash produced from the combustion was also analysed to find the contents of unburnt carbon and other impurities. From the results, it was found that the emission of CO decreased from 64 ppm to 40 ppm while the amount of CO2 increased slightly with the increasing of excess air from 20% to 80%. The NOx emission also increased from 290 ppm to 350 ppm because of N2 in the EA reacts with O2 due to high combustion temperature. The combustion efficiencies of about 99% obtained in the present study, showing the prospects of using SFBC in commercial scale.

  7. Literature Survey of Crude Oil Properties Relevant to Handling and Fire Safety in Transport.

    Energy Technology Data Exchange (ETDEWEB)

    Lord, David [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Luketa, Anay [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Wocken, Chad [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Schlasner, Steve [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Aulich, Ted [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Allen, Ray [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Rudeen, David Keith [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-03-01

    Several fiery rail accidents in 2013-2015 in the U.S. and Canada carrying crude oil produced from the Bakken region of North Dakota have raised questions at many levels on the safety of transporting this, and other types of crude oil, by rail. Sandia National Laboratories was commissioned by the U.S. Department of Energy to investigate the material properties of crude oils, and in particular the so-called "tight oils" like Bakken that comprise the majority of crude oil rail shipments in the U.S. at the current time. The current report is a literature survey of public sources of information on crude oil properties that have some bearing on the likelihood or severity of combustion events that may occur around spills associated with rail transport. The report also contains background information including a review of the notional "tight oil" field operating environment, as well a basic description of crude oils and potential combustion events in rail transport. This page intentionally blank

  8. Combustion of oil shale, fluidized coal and pyrolysis fuel oil in a gas turbine for electricity generation

    Energy Technology Data Exchange (ETDEWEB)

    Korosi, A; Basler, B; Pepper, M W

    1984-04-01

    A combustion test programme has been carried out with a Brown, Boveri and Cie. (BBC) type 9, gas turbine, at the BBC works in Muenchenstein, Switzerland, in order to clarify the combustion possibilities of three unconventional fuels. The programme has been organized and financed by BBC, Stone and Webster and Exxon. Approximately 95,000 litres of each fuel at various turbine load conditions have been burned. At certain points water was injected for NOsub(x) reduction. The tests show that the commercially available gas turbine can be used without modification with these tested, unconventional fuels. They also show that direct application of inferior petrochemical materials, which are produced today, is possible.

  9. Radon in Estonian dwellings - Results from a National Radon Survey

    Energy Technology Data Exchange (ETDEWEB)

    Pahapill, Lia; Rulkov, Anne; Rajamaee, Raivo [Estonian Radiation Protection Centre (Kiirguskeskus), Tallinn (Spain); Aakerblom, Gustav [Swedish Radiation Protection Authority, Stockholm (Sweden)

    2003-10-01

    A countrywide survey of radon concentrations in Estonian dwellings was carried out during the period 1998-2001. The survey formed a part of the cooperation program on radiation protection between the Estonian Radiation Protection (Kiirguskeskus) Centre and the Swedish Radiation Protection Authority (SSI). The survey included measurements in a number of dwellings representative for Estonia in detached houses and multifamily buildings (only dwellings on the bottom floor were included in the survey). Altogether, radon concentrations were measured in 515 dwellings, a number large enough to be statistically significant. All measurements were made with alphatrack film detectors of the same type that SSI uses in Sweden. The measurements were made during a 2-3 month period during the winter half-year. Two detectors were used in each dwelling. In Estonia there are 0.17 million dwellings in detached houses and 0.45 million in multi apartment buildings. Of the 1.26 million inhabitants in Estonia. 0.36 million live in detached houses and 0.90 million in multi apartment buildings. Most of the latter were built during the Soviet occupation. Of the dwellings in multifamily buildings 30 % are assumed to be situated on the first floor. The mean radon concentration in dwellings in detached hoses, according to the survey results, is 103 Bq/m{sup 3}, in dwellings on the bottom floor in multi apartment buildings it is 78 Bq/m{sup 3}. In 1% of the dwellings the radon concentration exceeded 400 Bq/m{sup 3}. The highest radon concentration found in the study was 1040 Bq/m{sup 3}. Based on the assumption that the average radon concentration in the dwellings in multi-apartment buildings that are not situated on the bottom floor is 30 Bq/m{sup 3}, and that these dwellings constitute 70% of all dwellings in multi apartment buildings, the mean radon concentration in dwellings in multi apartment buildings is calculated to be 44 Bq/m{sup 3}. The mean value for all Estonia dwellings is calculated

  10. Radon in Estonian dwellings - Results from a National Radon Survey

    International Nuclear Information System (INIS)

    Pahapill, Lia; Rulkov, Anne; Rajamaee, Raivo; Aakerblom, Gustav

    2003-10-01

    A countrywide survey of radon concentrations in Estonian dwellings was carried out during the period 1998-2001. The survey formed a part of the cooperation program on radiation protection between the Estonian Radiation Protection (Kiirguskeskus) Centre and the Swedish Radiation Protection Authority (SSI). The survey included measurements in a number of dwellings representative for Estonia in detached houses and multifamily buildings (only dwellings on the bottom floor were included in the survey). Altogether, radon concentrations were measured in 515 dwellings, a number large enough to be statistically significant. All measurements were made with alphatrack film detectors of the same type that SSI uses in Sweden. The measurements were made during a 2-3 month period during the winter half-year. Two detectors were used in each dwelling. In Estonia there are 0.17 million dwellings in detached houses and 0.45 million in multi apartment buildings. Of the 1.26 million inhabitants in Estonia. 0.36 million live in detached houses and 0.90 million in multi apartment buildings. Most of the latter were built during the Soviet occupation. Of the dwellings in multifamily buildings 30 % are assumed to be situated on the first floor. The mean radon concentration in dwellings in detached hoses, according to the survey results, is 103 Bq/m 3 , in dwellings on the bottom floor in multi apartment buildings it is 78 Bq/m 3 . In 1% of the dwellings the radon concentration exceeded 400 Bq/m 3 . The highest radon concentration found in the study was 1040 Bq/m 3 . Based on the assumption that the average radon concentration in the dwellings in multi-apartment buildings that are not situated on the bottom floor is 30 Bq/m 3 , and that these dwellings constitute 70% of all dwellings in multi apartment buildings, the mean radon concentration in dwellings in multi apartment buildings is calculated to be 44 Bq/m 3 . The mean value for all Estonia dwellings is calculated to be 60 Bq/m 3 . Using

  11. Safety analysis of the 700-horsepower combustion test facility

    Energy Technology Data Exchange (ETDEWEB)

    Berkey, B.D.

    1981-05-01

    The objective of the program reported herein was to provide a Safety Analysis of the 700 h.p. Combustion Test Facility located in Building 93 at the Pittsburgh Energy Technology Center. Extensive safety related measures have been incorporated into the design, construction, and operation of the Combustion Test Facility. These include: nitrogen addition to the coal storage bin, slurry hopper, roller mill and pulverizer baghouse, use of low oxygen content combustion gas for coal conveying, an oxygen analyzer for the combustion gas, insulation on hot surfaces, proper classification of electrical equipment, process monitoring instrumentation and a planned remote television monitoring system. Analysis of the system considering these factors has resulted in the determination of overall probabilities of occurrence of hazards as shown in Table I. Implementation of the recommendations in this report will reduce these probabilities as indicated. The identified hazards include coal dust ignition by hot ductwork and equipment, loss of inerting within the coal conveying system leading to a coal dust fire, and ignition of hydrocarbon vapors or spilled oil, or slurry. The possibility of self-heating of coal was investigated. Implementation of the recommendations in this report will reduce the ignition probability to no more than 1 x 10/sup -6/ per event. In addition to fire and explosion hazards, there are potential exposures to materials which have been identified as hazardous to personal health, such as carbon monoxide, coal dust, hydrocarbon vapors, and oxygen deficient atmosphere, but past monitoring experience has not revealed any problem areas. The major environmental hazard is an oil spill. The facility has a comprehensive spill control plan.

  12. In-situ combustion simulation with dynamic grid; Simulacao de combustao in-situ com grades dinamicas

    Energy Technology Data Exchange (ETDEWEB)

    Ferraz, C.H.A.; Almeida, M.P.; Vasconcelos, H.H.M.; Oliveira, C.L.N. [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil). Dept. de Fisica

    2008-07-01

    In this work, we study the effects of the introduction of 3D dynamics grids on in-situ combustion simulation results as means of describing the most realistically possible the dynamics of these processes, in particular of the combustion front. The dynamic refinement of grid blocks is important because in thesis it enhances the precision in the calculations once that more grid blocks are considered in the grid, especially within the narrow region of high temperature of the combustion front. We have performed dry combustion simulation (only water injection) and wet combustion simulation (air + water injection) for forward combustion in a variety of well configurations. Our initial results have shown changes in oil, water and gas productions when we use dynamics grids in the simulations, making clear the relevance of its usage in the understanding of the dynamics of these processes. (author)

  13. Ärkamisaeg, Noor-Eesti ja miski nende vahel. Eesti kirjandusloo küsimusi Juhan Kunderi näitel / National Awakening , Young Estonia and Something In Between. Problems of Estonian Literary History in the Example of Juhan Kunder

    Directory of Open Access Journals (Sweden)

    Pille-Riin Larm

    2013-12-01

    Full Text Available According to the long-standing periodisation of Estonian literary history, the Estonian National Awakening that started in the mid-19th century was followed by a period of lesser creativity and originality, which ended only with the breakthrough of the modernist Young Estonia group in 1905. In the canon of Estonian literature, Juhan Kunder (1852–1888, today known primarily for his fairy tales, one play and lyrics of one song, is placed in this intermediate period. This article first introduces the significance of Kunder in his time. He was a popular writer and a wellknown pedagogue, and a younger contemporary of the great figures of the National Awakening. As a critic, magazine editor and literary historian, his most important contribution to literary history was in the development of literary thought. It seems that several precedents that have been attributed to the Young Estonia group, e.g., valuing originality, writing well-argued criticism, etc., actually originated from an earlier period. Based on these observations, the author of this article believes that the current structure of Estonian literary history is not adequately justified, and she points out a semantic shift in the terms in use. It is true that Kunder was largely an epigone of his predecessors, but in the positive sense of the term, meaning that he continued their mission. Similarly, Kunder’s predecessor, the ‘first Young Estonian’ Kreutzwald, and a representative of his 20th-century successors, Friedebert Tuglas, were also epigones. During the period of Russification that started during his era, Kunder’s attitudes could be considered progressive. Kunder was also a 19th-century contemporary of the Young Estonia group and a true Young Estonian in the original sense of the term which emerged in this period: a Young Estonian introduced new initiatives and was a leader of the national movement. Epigonism and membership in Young Estonia can be seen as the keys to cultural

  14. Electrodialytic removal of Cd from biomass combustion fly ash suspensions

    DEFF Research Database (Denmark)

    Kirkelund, Gunvor M.; Ottosen, Lisbeth M.; Damoe, Anne J.

    2013-01-01

    was investigated with the aim of enabling reuse of the ashes. The ashes originated from combustion of straw (two ashes), wood chips, and co-firing of wood pellets and fuel oil, respectively. A series of laboratory scale electrodialytic remediation experiments were conducted with each ash. The initial Cd...

  15. Effects of fractal grid on emissions in burner combustion by using fuel-water-air premix injector derived from biodiesel crude palm oil (CPO base

    Directory of Open Access Journals (Sweden)

    Suardi Mirnah

    2017-01-01

    Full Text Available The alternative fuel is attracted good attention from worldwide especially for renewable and prevention energy such as biodiesel. Biodiesel is one of the hydrocarbon fuels and it has potential for external combustion. As one of the different solutions to these problems, rapid mixing of biodiesel-water-air technique is one of the most significant approaches to improve the combustion and reduce the emissions. The gas emission can be reduced by two methods. First is by improving an injector with fractal and the other is by using a biodiesel-water mixture as an alternative fuel. Mixing of water with fuel in the combustion process is a low cost and effective way. This research used biodiesel Crude Palm Oil (CPO as fuels in which blended with diesel. This study investigated the effects of water content and equivalence ratio on emissions with the rapid mixing injector. Fuels used are diesel, CPO5, CPO10 and CPO15 and the exhausts gaseous tested are CO, CO2, HC and NOX. The gas emissions processes are tested by using the gas analyzer. In this research, water premix of percentage up to 15vol% and blending biodiesel ratio was varied from 5vom% - 15vol%. The result shows that increasing of water content will effected decrement of CO, CO2 and HC emissions but increasing the NOX emissions.

  16. CHARACTERIZATION OF AIR TOXICS FROM AN OIL-FIRED FIRETUBE BOILER

    Science.gov (United States)

    Tests were conducted on a commercially available firetube package boiler running on #2 through #6 oils to determine the emissions levels of hazardous air pollutants (HAPs) from the combustion of four fuel oils. Flue gas was sampled to determine levels of volatile and semivolatile...

  17. The combustion of biomass - the impact of its types and combustion technologies on the emission of nitrogen oxide

    Directory of Open Access Journals (Sweden)

    Mladenović Milica R.

    2016-01-01

    Full Text Available Harmonization of environmental protection and the growing energy needs of modern society promote the biomass application as a replacement for fossil fuels and a viable option to mitigate the green house gas emissions. For domestic conditions this is particularly important as more than 60% of renewables belongs to biomass. Beside numerous benefits of using biomass for energy purposes, there are certain drawbacks, one of which is a possible high emission of NOx during the combustion of these fuels. The paper presents the results of the experiments with multiple biomass types (soybean straw, cornstalk, grain biomass, sunflower oil, glycerin and paper sludge, using different combustion technologies (fluidized bed and cigarette combustion, with emphasis on the emission of NOx in the exhaust gas. A presentation of the experimental installations is given, as well as an evaluation of the effects of the fuel composition, combustion regimes and technology on the NOx emissions. As the biomass combustion took place at temperatures low enough that thermal and prompt NOx can be neglected, the conclusion is the emissions of nitrogen oxides primarily depend on the biomass composition- it is increasing with the increase of the nitrogen content, and decreases with the increase of the char content which provides catalytic surface for NOx reduction by CO. [Projekat Ministarstva nauke Republike Srbije, br. TR33042: Improvement of the industrial fluidized bed facility, in scope of technology for energy efficient and environmentally feasible combustion of various waste materials in fluidized bed i br. III42011: Development and improvement of technologies for efficient use of energy of several forms of agricultural and forest biomass in an environmentally friendly manner, with the possibility of cogeneration

  18. Compositional Simulation of In-Situ Combustion EOR: A Study of Process Characteristics

    DEFF Research Database (Denmark)

    Jain, Priyanka; Stenby, Erling Halfdan; von Solms, Nicolas

    2010-01-01

    In order to facilitate the study of the influence of reservoir process characteristics in In-Situ combustion modeling and advance the work of Kristensen et al. in this domain; a fully compositional In-situ combustion (ISC) model of Virtual Kinetic Cell (VKC; single-cell model) for laboratory scale....... This incorporates fourteen pseudo components and fourteen reactions (distributed amongst thermal cracking, low temperature oxidation and high temperature oxidation). The paper presents a set of derivative plots indicating that reservoir process characterization in terms of thermal behavior of oil can be well...... construed in terms of thermo-oxidative sensitivity of SARA fractions. It can be interpreted from the results that operating parameters like air injection rate, oxygen feed concentration and activation energy have significant influence on oil recovery; an increase in air injection rate can lead to cooling...

  19. The flexfuel tractor. Invesigations on the combustion behaviour of vegetable oil fuels and on the discernability of fossil and biogenic fuels; Der Flexfuel Traktor. Untersuchungen zum Verbrennungsverhalten von Pflanzenoelkraftstoffen und zur Unterscheidbarkeit fossiler und biogener Kraftstoffe

    Energy Technology Data Exchange (ETDEWEB)

    Dieringer, Stefanie

    2012-07-01

    Increasing energy prices, especially for fossil fuels, as well as the necessity to reduce CO{sub 2} emissions are emphasizing the advantages of self-produced vegetable oil fuels in agriculture. Monetary advantages are depending on basic conditions like farm size or tax legislation, which can be changing locally as well as temporarily. Due to the differing properties of diesel and vegetable oil fuel, engines have to be adapted to each fuel to fulfil performance requirements as well as emission limits and reliability. Knowing that there are advantages of vegetable oil compared to diesel fuel, though not always and everywhere present, it becomes obvious that the well known flexible fuel concept of passenger cars should be adapted for diesel engines of agricultural machines. So called flexfuel engines imply the detection of the fuel type and an automated adjustment of the engine control parameters without any manual action of an operator. Therefore, the first step consists of the evaluation of the combustion properties of rapeseed, sunflower, jatropha and false flax oil compared to diesel fuel. The tested vegetable oils showed very similar behaviour in the tested common rail diesel engine. Especially the limited emissions were met with the same engine control software with all vegetable oils. In consequence it is possible to realize a flexfuel engine using the two engine control maps available at the moment, one for diesel and the other one for vegetable oil fuels. For further investigations one oil type, namely rapeseed oil was selected to test the combustion behaviour of fuel blends made of diesel and vegetable oil. The goal was to determine the blend ratio of vegetable oil and diesel fuel at which the engine control software has to be changed from the diesel to the vegetable oil map automatically. If the fuel consists of 40% or more vegetable oil, the vegetable oil engine control map has to be selected in order to fulfil legal emission limits. Finally the

  20. Environmental and Human Health Impacts of Usage of Oil Industry Products and Wastes as Alternative Fuel

    Directory of Open Access Journals (Sweden)

    Dilek BOLAT

    2016-03-01

    Full Text Available The need for oil industry products has been increasing in parallel to the rapid population growth and industrialization. Physical and chemical properties of these products change after usage based on the media and operating conditions. Then, these products lose the eligibility and turn into the form of waste. The most commonly used method for the disposal of waste oils is combustion due to its high calorific value. In this study, the possible effects on the environment and human health of combustion of oil industry products and wastes are evaluated. Poor combustion conditions lead emissions from the process depending on the ingredients of wastes in addition to incomplete combustion products such as particulate matter, carbon monoxide, volatile organic chemicals polyaromatic hydrocarbons, metals etc. that may occur according to the type of waste. These emissions are released into the environment and partition between soil, water and air media related to their physicochemical characteristics. In addition to environmental problems, these emissions are a risk factor for human health in terms of carcinogenicity and mutagenicity. Regulations and control measures should be put into practice in order to get rid of the effects of non-standard diesel like product named number 10 lube on human health and environment. In this context, emission measurements should be done simultaneously to determine the effects of combustion of these wastes and products of oil industry.

  1. Combustion of Microalgae Oil and Ethanol Blended with Diesel Fuel

    Directory of Open Access Journals (Sweden)

    Saddam H. Al-lwayzy

    2015-12-01

    Full Text Available Using renewable oxygenated fuels such as ethanol is a proposed method to reduce diesel engine emission. Ethanol has lower density, viscosity, cetane number and calorific value than petroleum diesel (PD. Microalgae oil is renewable, environmentally friendly and has the potential to replace PD. In this paper, microalgae oil (10% and ethanol (10% have been mixed and added to (80% diesel fuel as a renewable source of oxygenated fuel. The mixture of microalgae oil, ethanol and petroleum diesel (MOE20% has been found to be homogenous and stable without using surfactant. The presence of microalgae oil improved the ethanol fuel demerits such as low density and viscosity. The transesterification process was not required for oil viscosity reduction due to the presence of ethanol. The MOE20% fuel has been tested in a variable compression ratio diesel engine at different speed. The engine test results with MOE20% showed a very comparable engine performance of in-cylinder pressure, brake power, torque and brake specific fuel consumption (BSFC to that of PD. The NOx emission and HC have been improved while CO and CO2 were found to be lower than those from PD at low engine speed.

  2. Technology for emission control in internal combustion engines; Kakushu nainen kikan ni okeru hai gas joka gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Shioji, M. [Kyoto University, Kyoto (Japan)

    1998-09-01

    Described herein are emission control technology and exhaust gas cleaning measures for internal combustion engines. Gas turbines burn relatively high-quality fuels, such as natural gas, kerosene, diesel oil and gas oil, where the major concerns are to reduce NOx and dust emissions. The NOx abatement techniques fall into two general categories; wet processes which inject water or steam, and dry processes which depend on improved combustion. Power generation and cogeneration which burn natural gas adopt lean, premixed combustion and two-stage combustion as the major approaches. Low-speed, large-size diesel engines, which realize very high thermal efficiency, discharge high concentrations of NOx. Delayed fuel injection timing is the most easy NOx abatement technique to meet the related regulations, but is accompanied by decreased fuel economy. Use of water-emulsified fuel, water layer injection and multi-port injection can reduce NOx emissions without decreasing fuel economy, depending on optimization methods adopted. Automobile gasoline engines are required to further clean exhaust gases by catalystic systems. 9 refs., 10 figs., 6 tabs.

  3. Co-combustion of agricultural wastes in a circulating fluidized bed

    Energy Technology Data Exchange (ETDEWEB)

    Huseyin Topal; Aysel T. Atimtay [Gazi University, Ankara (Turkey). Dept. of Mechanical Engineering

    2005-07-01

    In this study a circulating fluidized bed combustion (CFBC) of 125 mm inside diameter and 1800 mm height was used to investigate the co-combustion characteristics of peach and apricot stones produced as a waste from the fruit juice industry, and sunflower stems produced as a waste from the edible oil industry with a lignite coal. Lignite coal is a coal most widely used in Turkey. On-line concentrations of O{sub 2}, CO, CO{sub 2}, SO{sub 2}, NOx and total hydrocarbons (C{sub m}H{sub n}) were measured in the flue gas during combustion experiments. By changing the operating parameters the variation of emissions of various pollutants were studied. During combustion tests, it was observed that the volatile matter from agro-wastes quickly volatilizes and mostly burn in the riser. The temperature profiles along the bed and the rise also confirmed this phenomenon. It was found that as the volatile matter content of agro-waste increases, the combustion efficiency increases and the combustion takes place more in the upper region of the riser. These results suggest that agro-wastes are potential fuels that can be utilized for clean energy production by using CFBC in countries where agricultural activities are heavy. 3 refs., 4 figs., 5 tabs.

  4. Estudio de modificaciones geométricas en boquillas de calderas piro y acuotubulares para la combustión eficiente de crudos pesados // Study of geometric modifications in pyro and aquatubular mouthpieces of boilers for the efficient combustion of heavy oil

    Directory of Open Access Journals (Sweden)

    E. Lincheta Mesa

    2000-07-01

    Full Text Available Se presenta un estudio de boquillas de quemadores de calderas piro y acuotubulares. Se analizan diferentes variantes en lasdimensiones, forma y posición de los conductos de atomizador que dan paso al combustible y al fluido auxiliar en el casode quemadores con atomización por vapor.En todos los casos se evalúa el cono de pulverización y la calidad del spray, analizando la influencia de la presión deatomización y de la configuración geométrica en la eficiencia de atomización.Se determina la eficiencia de la combustión con varios tipos de boquillas, demostrándose la efectividad de lasmodificaciones introducidas cuando se queman combustibles de menor calidad.Se concluye que es posible sustituir algunas boquillas de importación y elevar la eficiencia en la combustión de crudospesados y sus mezclas, con un significativo efecto económico y como un paso más en el perfeccionamiento de las CentralesEléctricas del país para el aprovechamiento del crudo nacional.Palabras claves: quemador, atomizador, fuel oil, caldera, generación de vapor, combustibles, combustión._____________________________________________________________________Abstract :It is presented a study of mouthpieces of pyro and aquatubular burners of boilers. Different variants are analyzed indimensions, forms and position of the atomizer conduits that open the way to the fuel and auxiliary fluid in case of burnerswith steam atomization.In all cases, it is evaluated the pulverization cone and the quality of spray, analyzing the influence of atomization pressureand geometric configuration in the atomization efficiency.Estudio de modificaciones geométricas en boquillas de calderas piro y acuotubulares para la combustión eficiente decrudos pesadosThe efficiency of combustion is determined with several types of mouthpieces. The effectiveness of the introducedmodifications in connection with the import mouthpieces is demonstrated when fuels of smaller quality burns.It is

  5. Thermally decomposed ricebran oil as a diesel fuel

    Directory of Open Access Journals (Sweden)

    Megahed, O. A.

    1998-04-01

    Full Text Available Ricebran oil; a non edible oil, was thermally decomposed using different loads of calcium oxide as catalyst. The fuel properties of the cracked product were evaluated as compared to those of diesel fuel. The considered properties included the calorific value, flash point, viscosity, pour point, distillation characteristics, cetane number in addition to some other fuel properties. The results had shown that the fuel properties of the decomposed oil were quite similar to those of standard diesel fuel. The calorific value was 80-90% that of diesel fuel and the viscosity was sligthy higher. The prepared fuel was advantageous over diesel fuel as the former was completely free from sulfur, which on fuel combustion produces corrosive gases of sulfur oxides.

    Aceite de germen de arroz, un aceite no comestible, fue descompuesto térmicamente usando diferentes cantidades de óxido cálcico como catalizador. Las propiedades combustibles del producto craqueado fueron evaluadas comparándolas con las del gasóleo. Las propiedades consideradas incluyeron el poder calorífico, punto de inflamación, viscosidad, temperatura de fluidez crítica, características de destilación, número de cetano y otras propiedades de los combustibles. Los resultados han mostrado que las propiedades combustibles del aceite descompuesto fueron bastantes similares a la de los gasóleos estándar. El poder calorífico fue del 80-90% de la del gasóleo y la viscosidad ligeramente mayor. El combustible preparado fue ventajoso sobre el gasóleo ya que el primero estaba completamente libre de sulfuro, el cual produce en la combustión del carburante gases corrosivos de óxido de azufre.

  6. Scenarios for shale oil, syncrude and electricity production in Estonia in the interim 1995-2025

    International Nuclear Information System (INIS)

    Oepik, I.

    1992-01-01

    This paper is based on the author's pre-feasibility studies of oil shale utilization in oil production, electricity generation and cement industry. The electricity generation has been calculated on the basis of 1.4 and 1.6 GW oil shale power plants with pulverized fuel combustion today. The three scenarios OILMIN, OILMED and OILMAX differ by annual oil production and different investment costs. The investments in the oil shale processing industry seem to be more profitable than those in electricity generation. It is also important to take into account that the very high sensitivity of oil market to geopolitical aspects of resources and to sudden crises, makes the crude price a stochastic parameter, which loses its indicative character for long term economic choice. Therefore it will be very important to have the electric power plants with flexible combined oil shale and coal combustion. 4 figs., 4 tabs., 6 refs

  7. Method for purification of combustible oils, adapted particularly for diesel motors

    Energy Technology Data Exchange (ETDEWEB)

    1942-01-13

    A method is described for the purification of oils for diesel motors from mixtures of tar oils, predominantly aromatic with aliphatic hydrocarbon oils by treatment with refining means which are dissolved in organic solvents and mixed with the oil to be purified and also with water; separation of the separate impurities and washing of the material of treatment with water characcterized by the fact that this refining agent used consists of monobasic and polybasic organic acids, saturated or unsaturated, and also their anhydrides, and substituted acids and their anhydrides.

  8. Prospects of pyrolysis oil from plastic waste as fuel for diesel engines: A review

    Science.gov (United States)

    Mangesh, V. L.; Padmanabhan, S.; Ganesan, S.; PrabhudevRahul, D.; Reddy, T. Dinesh Kumar

    2017-05-01

    The purpose ofthis study is to review the existing literature about chemical recycling of plastic waste and its potential as fuel for diesel engines. This is a review covering on the field of converting waste plastics into liquid hydrocarbon fuels for diesel engines. Disposal and recycling of waste plastics have become an incremental problem and environmental threat with increasing demand for plastics. One of the effective measures is by converting waste plastic into combustible hydrocarbon liquid as an alternative fuel for running diesel engines. Continued research efforts have been taken by researchers to convert waste plastic in to combustible pyrolysis oil as alternate fuel for diesel engines. An existing literature focuses on the study of chemical structure of the waste plastic pyrolysis compared with diesel oil. Converting waste plastics into fuel oil by different catalysts in catalytic pyrolysis process also reviewed in this paper. The methodology with subsequent hydro treating and hydrocracking of waste plastic pyrolysis oil can reduce unsaturated hydrocarbon bonds which would improve the combustion performance in diesel engines as an alternate fuel.

  9. Analysis of axial behavior of three piece oil control ring; Kumiawase oil ring no jikuhoko kyodo no kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Tateishi, Y; Fujimura, K; Hitosugi, H [Nippon Piston Ring Co. Ltd., Tokyo (Japan)

    1997-10-01

    It is considered that the reduction of oil control ring tension is a major problem in reducing the friction-loss of internal combustion engines. The authors have successfully developed a calculating method for the axial behavior prediction of a three piece type oil control ring as a method used in reduction of lube-oil consumption when lower tension ring is used. By means of the method, the authors found that the effect in reduction of lube-oil consumption was able to be expected by optimizing design parameters of the oil ring, the tension and the seating tab angle of expander-spacer, and the gas pressure on the 3rd land. 3 refs., 14 figs.

  10. Co-firing used engine lubrication oil with LPG in furnaces

    International Nuclear Information System (INIS)

    Al-Omari, S.A.-B.; Shaheen, A.; Al Fakhr, A.; Al-Hosani, A.; Al Yahyai, M.

    2010-01-01

    Combustion and heat transfer characteristics obtained based co-firing LPG with used engine oils (UEO) in a furnace, are investigated experimentally. In an attempt to assess UEO as a fuel, the UEO-based results are compared with results obtained using two other fuels, namely diesel, and a used cooking oil (UCkO). To ease its admission to the furnace and its subsequent vaporization and combustion, UEO is preheated by allowing it to flow upwardly in a vertical pipe surrounded by hot gases generated from LPG combustion. UEO that reaches the tip of the pipe un-vaporized, spills and hence has the chance to further heatup and vaporize as it exchanges heat with the upwardly flowing LPG combustion gases, in a counter flow process. Runs are divided into three groups based on the mass ratio of the liquid-fuel/LPG and the mass flow rate of the LPG supplied to the furnace. Ranges of these quantities over which UEO qualify as a good fuel and/or good promoter to radiation have been identified.

  11. Co-firing used engine lubrication oil with LPG in furnaces

    Energy Technology Data Exchange (ETDEWEB)

    Al-Omari, S.A.-B.; Shaheen, A.; Al Fakhr, A.; Al-Hosani, A.; Al Yahyai, M. [Mechanical Engineering Department, UAE University, Al-Ain (United Arab Emirates)

    2010-06-15

    Combustion and heat transfer characteristics obtained based co-firing LPG with used engine oils (UEO) in a furnace, are investigated experimentally. In an attempt to assess UEO as a fuel, the UEO-based results are compared with results obtained using two other fuels, namely diesel, and a used cooking oil (UCkO). To ease its admission to the furnace and its subsequent vaporization and combustion, UEO is preheated by allowing it to flow upwardly in a vertical pipe surrounded by hot gases generated from LPG combustion. UEO that reaches the tip of the pipe un-vaporized, spills and hence has the chance to further heatup and vaporize as it exchanges heat with the upwardly flowing LPG combustion gases, in a counter flow process. Runs are divided into three groups based on the mass ratio of the liquid-fuel/LPG and the mass flow rate of the LPG supplied to the furnace. Ranges of these quantities over which UEO qualify as a good fuel and/or good promoter to radiation have been identified. (author)

  12. Devolatilization of oil sludge in a lab-scale bubbling fluidized bed.

    Science.gov (United States)

    Liu, Jianguo; Jiang, Xiumin; Han, Xiangxin

    2011-01-30

    Devolatilization of oil sludge pellets was investigated in nitrogen and air atmosphere in a lab-scale bubbling fluidized bed (BFB). Devolatilization times were measured by the degree of completion of the evolution of the volatiles for individual oil sludge pellets in the 5-15 mm diameter range. The influences of pellet size, bed temperature and superficial fluidization velocity on devolatilization time were evaluated. The variation of devolatilization time with particle diameter was expressed by the correlation, τ(d) = Ad(p)(N). The devolatilization time to pellet diameter curve shows nearly a linear increase in nitrogen, whereas an exponential increase in air. No noticeable effect of superficial fluidization velocity on devolatilization time in air atmosphere was observed. The behavior of the sludge pellets in the BFB was also focused during combustion experiments, primary fragmentation (a micro-explosive combustion phenomenon) was observed for bigger pellets (>10mm) at high bed temperatures (>700 °C), which occurred towards the end of combustion and remarkably reduce the devolatilization time of the oil sludge pellet. The size analysis of bed materials and fly ash showed that entire ash particle was entrained or elutriated out of the BFB furnace due to the fragile structure of oil sludge ash particles. Copyright © 2010 Elsevier B.V. All rights reserved.

  13. Tailoring next-generation biofuels and their combustion in next-generation engines

    Energy Technology Data Exchange (ETDEWEB)

    Gladden, John Michael [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Wu, Weihua [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Taatjes, Craig A. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Scheer, Adam Michael [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Turner, Kevin M. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Yu, Eizadora T. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); O' Bryan, Greg [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Powell, Amy Jo [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Gao, Connie W. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

    2013-11-01

    Increasing energy costs, the dependence on foreign oil supplies, and environmental concerns have emphasized the need to produce sustainable renewable fuels and chemicals. The strategy for producing next-generation biofuels must include efficient processes for biomass conversion to liquid fuels and the fuels must be compatible with current and future engines. Unfortunately, biofuel development generally takes place without any consideration of combustion characteristics, and combustion scientists typically measure biofuels properties without any feedback to the production design. We seek to optimize the fuel/engine system by bringing combustion performance, specifically for advanced next-generation engines, into the development of novel biosynthetic fuel pathways. Here we report an innovative coupling of combustion chemistry, from fundamentals to engine measurements, to the optimization of fuel production using metabolic engineering. We have established the necessary connections among the fundamental chemistry, engine science, and synthetic biology for fuel production, building a powerful framework for co-development of engines and biofuels.

  14. Mesoscale experiments help to evaluate in-situ burning of oil spills

    International Nuclear Information System (INIS)

    Evans, D.D.; Walton, W.D.; Baum, H.R.; Notarianni, K.A.; Tennyson, E.J.; Tebeau, P.A.

    1993-01-01

    Burning of spilled oil has distinct advantages over other cleanup countermeasures. It offers the potential to convert rapidly large quantities of oil into its primary combustion products, carbon dioxide and water, with a small percentage of other unburned and residue by-products. Disadvantages include the dispersal of the combustion products into the air. Mesoscale and laboratory experiments have been conducted to measure the burning characteristics of crude oil fires. Measurements on crude oil pool fires from 0.4 m to 17.2 m in effective diameter were made to obtain data on the rate of burning, heat release rate, composition of the combustion products, and downwind dispersion of the products. The smaller experiments were performed in laboratories at the National Institute of Standards and Technology and the Fire Research Institute in Japan; and the larger ones at the US Coast Guard Fire Safety and Test Detachment in Mobile, Alabama. From these experiments, the value for surface regression rate of a burning crude oil spill was found to be 0.055 mm/s. A major concern for public safety is the content and extent of the smoke plume from the fires. Smoke yield, the fraction of the oil mass burned that is emitted as particulate, was found to be 13 percent. A large-eddy simulation calculation method for smoke plume trajectory and smoke particulate deposition developed by NIST showed that the smoke particulate deposition from a 114 m 2 burn would occur in striations over a long, slender area 3.2 km wide and 258 km downwind of the burn

  15. Development and evaluation of analytical techniques for total chlorine in used oils and oil fuels

    International Nuclear Information System (INIS)

    Gaskill, A. Jr.; Estes, E.D.; Hardison, D.L.; Friedman, P.H.

    1990-01-01

    A current EPA regulation prohibits the sale for burning in nonindustrial boilers of used oils and oil fuels. This paper discusses how analytical techniques for determining total chlorine were evaluated to provide regulatory agencies and the regulated community with appropriate chlorine test methods. The techniques evaluated included oxygen bomb combustion followed by chemical titration or ion chromatography, instrumental microcoulometry, field test kits, and instrumental furnace/specific ion electrode determinator, a device based on the Beilstein reaction, and x-ray fluorescence spectrometry. These techniques were subjected to interlaboratory testing to estimate their precision, accuracy, and sensitivity. Virgin and used crankcase oils, hydraulic and metalworking oils, oil fuels and oil fuel blends with used oils were tested. The bomb techniques, one of the test kits, microcoulometry and all but one x-ray analyzer were found to be suitable for this application. The chlorine furnace and the Beilstein device were found to be inapplicable at the levels of interest

  16. Estonian experience in establishing the national radiation protection infrastructure in the newly independent State

    International Nuclear Information System (INIS)

    Kalam, J.

    2001-01-01

    The Estonian Radiation Protection Centre (ERPC) was established on 4 January 1996 as the regulatory authority for radiation protection and safety of radiation sources. The report explains the ERPC's structure and its main functions and activities, and provides information on the regulations that have been approved or are planned to be adopted. Reference is made to radiological emergency preparedness and, in particular, to the status of development of the system of regulatory control by authorization and inspection of radiation practices in the country. (author)

  17. Air injection low temperature oxidation process for enhanced oil recovery from light oil reservoirs

    International Nuclear Information System (INIS)

    Tunio, A.H.; Harijan, K.

    2010-01-01

    This paper represents EOR (Enhanced Oil Recovery) methods to recover unswept oil from depleted light oil reservoirs. The essential theme here is the removal of oxygen at LTO (Low Temperature Oxidation) from the injected air for a light oil reservoir by means of some chemical reactions occurring between oil and oxygen. In-situ combustion process, HTO (High Temperature Oxidation) is not suitable for deep light oil reservoirs. In case of light oil reservoirs LTO is more suitable to prevail as comparative to HTO. Few laboratory experimental results were obtained from air injection process, to study the LTO reactions. LTO process is suitable for air injection rate in which reservoir has sufficiently high temperature and spontaneous reaction takes place. Out comes of this study are the effect of LTO reactions in oxygen consumption and the recovery of oil. This air injection method is economic compared to other EOR methods i.e. miscible hydrocarbon gas, nitrogen, and carbon dioxide flooding etc. This LTO air injection process is suitable for secondary recovery methods where water flooding is not feasible due to technical problems. (author)

  18. Vanadium in fuel oil - a new solution

    Energy Technology Data Exchange (ETDEWEB)

    Czech, N. [Siemens, Muelheim (Germany); Finckh, H. [Siemens, Erlangen (Germany)

    1998-11-01

    Hot corrosion of the hot-gas-path components due to vanadium contamination is one of the hazards associated with heavy residual oil combustion in heavy-duty gas turbines. This economically attractive oil combustion process has benefited from the recently developed vanadium inhibition technique, which is currently being tested at the Valladolid 220 MWe combined cycle plant in Mexico. The method uses atomization of a dilute aqueous solution of Epsom salt (MgSO{sub 7},7H{sub 2}O) into very small droplets which are then injected onto the flame where intensive mixing takes place. The successful use of this new technique promises extended operating periods between cleanup operations, and cost reductions from the use of inexpensive materials, as well as the ability to operate advanced gas turbines on difficult fuels, not previously feasible. (UK)

  19. Chemistry and combustion of fit-for-purpose biofuels.

    Science.gov (United States)

    Rothamer, David A; Donohue, Timothy J

    2013-06-01

    From the inception of internal combustion engines, biologically derived fuels (biofuels) have played a role. Nicolaus Otto ran a predecessor to today's spark-ignition engine with an ethanol fuel blend in 1860. At the 1900 Paris world's fair, Rudolf Diesel ran his engine on peanut oil. Over 100 years of petroleum production has led to consistency and reliability of engines that demand standardized fuels. New biofuels can displace petroleum-based fuels and produce positive impacts on the environment, the economy, and the use of local energy sources. This review discusses the combustion, performance and other requirements of biofuels that will impact their near-term and long-term ability to replace petroleum fuels in transportation applications. Copyright © 2013 Elsevier Ltd. All rights reserved.

  20. Effects of Catalysts on Emissions of Pollutants from Combustion Processes of Liquid Fuels

    Directory of Open Access Journals (Sweden)

    Bok Agnieszka

    2014-12-01

    Full Text Available The dynamic growth of the use of non-renewable fuels for energy purposes results in demand for catalysts to improve their combustion process. The paper describes catalysts used mainly in the processes of combustion of motor fuels and fuel oils. These catalysts make it possible to raise the efficiency of oxidation processes simultanously reducing the emission of pollutants. The key to success is the selection of catalyst compounds that will reduce harmful emissions of combustion products into the atmosphere. Catalysts are introduced into the combustion zone in form of solutions miscible with fuel or with air supplied to the combustion process. The following compounds soluble in fuel are inclused in the composition of the described catalysts: organometallic complexes, manganese compounds, salts originated from organic acids, ferrocen and its derivatives and sodium chloride and magnesium chloride responsible for burning the soot (chlorides. The priority is to minimize emissions of volatile organic compounds, nitrogen oxides, sulphur oxides, and carbon monoxide, as well as particulate matter.

  1. Producing electricity from Israel oil shale with PFBC technology

    International Nuclear Information System (INIS)

    Grinberg, A.; Keren, M.; Podshivalov, V.; Anderson, J.

    2000-01-01

    Results of Israeli oil shale combustion at atmospheric pressure in the AFBC commercial boiler manufactured by Foster Wheeler Energia Oy (Finland) and in the pressurized test facility of ABB Carbon AB (Finspong, Sweden) confirm suitability of fluidized-bed technologies in case of oil shale. The results approve possibility to use the PFBC technology in case of oil shale after solving of some problems connected with great amounts of fine fly ash. (author)

  2. Impact of burning oil as auxiliary fuel in kraft recovery furnaces upon SO2 emissions

    International Nuclear Information System (INIS)

    Someshwar, A.V.; Caron, A.L.; Pinkerton, J.E.

    1990-01-01

    The relationship between burning medium sulfur oil as auxiliary fuel in kraft recovery furnaces and SO 2 emissions was examined. Analysis of long-term CEMS SO 2 data from four furnaces shows no increase in SO 2 emissions as a result of oil burning. The results of field tests conducted at four furnaces while co-firing oil with liquor (up to 34% of total heat input) show that (1) average SO 2 emissions during the oil firing period either decreased or remained unchanged; (2) the overall sulfur retention within the furnace remained consistently high (more than 90%) with increasing levels of oil burning; (3) apportioning stack SO 2 emissions between those derived from oil and black liquor was infeasible. The results indicate that the same alkali fume generation processes that lead to the efficient capture of SO 2 resulting from black liquor combustion may be responsible for the capture of SO 2 resulting from sulfur-containing oil combustion

  3. Process for oil shale retorting

    Science.gov (United States)

    Jones, John B.; Kunchal, S. Kumar

    1981-10-27

    Particulate oil shale is subjected to a pyrolysis with a hot, non-oxygenous gas in a pyrolysis vessel, with the products of the pyrolysis of the shale contained kerogen being withdrawn as an entrained mist of shale oil droplets in a gas for a separation of the liquid from the gas. Hot retorted shale withdrawn from the pyrolysis vessel is treated in a separate container with an oxygenous gas so as to provide combustion of residual carbon retained on the shale, producing a high temperature gas for the production of some steam and for heating the non-oxygenous gas used in the oil shale retorting process in the first vessel. The net energy recovery includes essentially complete recovery of the organic hydrocarbon material in the oil shale as a liquid shale oil, a high BTU gas, and high temperature steam.

  4. Co-combustion: A summary of technology

    Directory of Open Access Journals (Sweden)

    Leckner Bo

    2007-01-01

    Full Text Available Co-combustion of biomass or waste together with a base fuel in a boiler is a simple and economically suitable way to replace fossil fuels by biomass and to utilize waste. Co-combustion in a high-efficiency power station means utilization of biomass and waste with a higher thermal efficiency than what otherwise had been possible. Due to transport limitations, the additional fuel will only supply a minor part (less than a few hundreds MW fuel of the energy in a plant. There are several options: co-combustion with coal in pulverized or fluidized bed boilers, combustion on added grates inserted in pulverized coal boilers, combustors for added fuel coupled in parallel to the steam circuit of a power plant, external gas producers delivering its gas to replace an oil, gas or pulverized fuel burner. Furthermore biomass can be used for reburning in order to reduce NO emissions or for afterburning to reduce N2O emissions in fluidized bed boilers. Combination of fuels can give rise to positive or negative synergy effects, of which the best known are the interactions between S, Cl, K, Al, and Si that may give rise to or prevent deposits on tubes or on catalyst surfaces, or that may have an influence on the formation of dioxins. With better knowledge of these effects the positive ones can be utilized and the negative ones can be avoided.

  5. Active lubrication applied to internal combustion engines - evaluation of control strategies

    DEFF Research Database (Denmark)

    Estupinan, Edgar Alberto; Santos, Ilmar

    2009-01-01

    surface. The behaviour of a main bearing of a medium size combustion engine, operating with radial oil injection and with four different control strategies is analyzed, giving some insights into the minimum fluid film thickness, maximum fluid film pressure, friction losses and maximum vibration levels...... of reducing friction losses and vibrations between the crankshaft and the bearings. The conventional hydrodynamic lubrication is combined with hydrostatic lubrication which is actively modified by radially injecting oil at controllable pressures, through orifices circumferentially located around the bearing...

  6. Peculiar high temperature corrosion of martensite alloy under impact of Estonian oil shale fly ash

    Energy Technology Data Exchange (ETDEWEB)

    Tallermo, H; Klevtsov, I [Thermal Engineering Department of Tallinn Technical University, Tallinn (Estonia)

    1999-12-31

    The superheaters` surfaces of oil shale steam boiler made of pearlitic and austenitic alloys, are subject to intensive corrosion, mainly due to presence of chlorine in external deposits. The applicability of martensitic alloys X1OCrMoVNb91 and X20CrMoV121 for superheaters is examined here and empirical equations allowing to predict alloys` corrosion resistance in the range of operational temperatures are established. Alloy X1OCrMoVNb91 is found been most perspective for superheaters of boilers firing fossil fuel that contain alkaline metals and chlorine. The abnormal dependence of corrosion resistance of martensitic alloys on temperature is revealed, namely, corrosion at 580 deg C in presence of oil shale fly ash is more intensive than at 620 deg C. (orig.) 2 refs.

  7. Peculiar high temperature corrosion of martensite alloy under impact of Estonian oil shale fly ash

    Energy Technology Data Exchange (ETDEWEB)

    Tallermo, H.; Klevtsov, I. [Thermal Engineering Department of Tallinn Technical University, Tallinn (Estonia)

    1998-12-31

    The superheaters` surfaces of oil shale steam boiler made of pearlitic and austenitic alloys, are subject to intensive corrosion, mainly due to presence of chlorine in external deposits. The applicability of martensitic alloys X1OCrMoVNb91 and X20CrMoV121 for superheaters is examined here and empirical equations allowing to predict alloys` corrosion resistance in the range of operational temperatures are established. Alloy X1OCrMoVNb91 is found been most perspective for superheaters of boilers firing fossil fuel that contain alkaline metals and chlorine. The abnormal dependence of corrosion resistance of martensitic alloys on temperature is revealed, namely, corrosion at 580 deg C in presence of oil shale fly ash is more intensive than at 620 deg C. (orig.) 2 refs.

  8. Technical-economic parameters of the new oil shale mining-chemical complex in Northeast Estonia

    International Nuclear Information System (INIS)

    Kuzmiv, I.; Fraiman, J.

    2006-01-01

    The history of oil shale mining in Estonia has reached its century mark. Three oil shale branches have been formed and have been working on the basis of Estonian oil shale deposits: the mining industry (underground and surface extraction), the power industry (heat and electric energy generation), and the chemical industry (gas and synthetic oils). The authors attempted to summarize the experience of the activities of these branches and to make into a whole the results of their research developments in the past years, as well as to form a notion about perspectives of oil shale in Estonia. Variants of the mining-chemical oil shale complex production and trade patterns differed from used ones. Mining methods, thermal processing of oil shale, and solid, liquid, and gas waste recovery have been studied, analyzed, and worked out up to the present. Setting up a flexible trade structure within the framework of that complex is considered the main economic mechanism capable of balancing production costs of such a complex with its earnings, which could respond properly to any, even peak, fluctuations of the market for final products processed from oil shale. Data of the working 'Estonia' oil shale mine were used as the basis of the analysis and practical conclusions. Information on the mine being projected in the region of Ojamaa in the northeast of Estonia was taken as the data of the worthwhile supplier. Oil shale processing chemical complex is considered in two structural alternatives: in technological chain with the 'Estonia' mine (the first variant), and the projected mine of a new technical level (the second variant). (author)

  9. Environmental indicators of the combustion of prospective coal water slurry containing petrochemicals.

    Science.gov (United States)

    Dmitrienko, Margarita A; Nyashina, Galina S; Strizhak, Pavel A

    2017-09-15

    Negative environmental impact of coal combustion has been known to humankind for a fairly long time. Sulfur and nitrogen oxides are considered the most dangerous anthropogenic emissions. A possible solution to this problem is replacing coal dust combustion with that of coal water slurry containing petrochemicals (CWSP). Coal processing wastes and used combustible liquids (oils, sludge, resins) are promising in terms of their economic and energy yield characteristics. However, no research has yet been conducted on the environmental indicators of fuels based on CWSP. The present work contains the findings of the research of CO, CO2, NOx, SOx emissions from the combustion of coals and CWSPs produced from coal processing waste (filter cakes). It is demonstrated for the first time that the concentrations of dangerous emissions from the combustion of CWSPs (carbon oxide and dioxide), even when combustible heavy liquid fractions are added, are not worse than those of coal. As for the concentration of sulfur and nitrogen oxides, it is significantly lower for CWSPs combustion as compared to coals. The presented research findings illustrate the prospects of the wide use of CWSPs as a fuel that is cheap and beneficial, in terms of both energy output and ecology, as compared to coal. Copyright © 2017 Elsevier B.V. All rights reserved.

  10. Low temperature combustion of organic coal-water fuel droplets containing petrochemicals while soaring in a combustion chamber model

    Directory of Open Access Journals (Sweden)

    Valiullin Timur R.

    2017-01-01

    Full Text Available The paper examines the integral characteristics (minimum temperature, ignition delay times of stable combustion initiation of organic coal-water fuel droplets (initial radius is 0.3-1.5 mm in the oxidizer flow (the temperature and velocity varied in ranges 500-900 K, 0.5-3 m/s. The main components of organic coal-water fuel were: brown coal particles, filter-cakes obtained in coal processing, waste engine, and turbine oils. The different modes of soaring and ignition of organic coal-water fuel have been established. The conditions have been set under which it is possible to implement the sustainable soaring and ignition of organic coal-water fuel droplets. We have compared the ignition characteristics with those defined in the traditional approach (based on placing the droplets on a low-inertia thermocouple junction into the combustion chamber. The paper shows the scale of the influence of heat sink over the thermocouple junction on ignition inertia. An original technique for releasing organic coal-water fuel droplets to the combustion chamber was proposed and tested. The limitations of this technique and the prospects of experimental results for the optimization of energy equipment operation were also formulated.

  11. Improving Energy Efficiency In Thermal Oil Recovery Surface Facilities

    Energy Technology Data Exchange (ETDEWEB)

    Murthy Nadella, Narayana

    2010-09-15

    Thermal oil recovery methods such as Cyclic Steam Stimulation (CSS), Steam Assisted Gravity Drainage (SAGD) and In-situ Combustion are being used for recovering heavy oil and bitumen. These processes expend energy to recover oil. The process design of the surface facilities requires optimization to improve the efficiency of oil recovery by minimizing the energy consumption per barrel of oil produced. Optimization involves minimizing external energy use by heat integration. This paper discusses the unit processes and design methodology considering thermodynamic energy requirements and heat integration methods to improve energy efficiency in the surface facilities. A design case study is presented.

  12. Assessment of technologies for the remediation of oil-contaminated soil resulting from exploded oil wells and burning oil fires in Kuwait

    International Nuclear Information System (INIS)

    Al-Awadhi, N.M.; Abdal, M.S.; Briskey, E.J.; Williamson, K.

    1992-01-01

    Large quantities of Kuwait desert soils have been contaminated by oil-lakes and by serial deposition of particulates and non-combusted petroleum products. The oil content of these soils must be reduced substantially in order to restore the potential of Kuwait's land for plant and animal production and to guard against long-term adverse implications to human health. Extensive world-wide research and development for the treatment of soils contaminated with hazardous wastes have results in a number of different types of technologies that might be used to remediate soils in Kuwait. These types of technologies, include incineration, thermal volatilization and steam leaching (oil recovery) and direct bioremediation, amongst others. The dimensions and technical aspects of the problem will be presented and applicable technology will be reviewed

  13. Optimization of Jatropha curcas pure vegetable oil production parameters for cooking energy

    Directory of Open Access Journals (Sweden)

    X. Aboubakar

    2017-12-01

    Full Text Available The extraction of vegetable oil from Jatropha from the Tanzanian variety with a fat content of 33.84 ± 2.58% and a moisture content of 5.4 ± 1.97%, was made using two methods: the traditional and the mechanical extraction method. The traditional consists in extracting the oil from the paste using boiling water as a solvent. While the mechanical consists of directly pressing the seeds of Jatropha using a ram press called Bielenberg press, to extract the oil contained in the seeds dried or heated before. The net yield of oil extraction by the traditional method was 22.02 ± 2.1%, with a oil cake percentage of 67.02 ± 3.3% and the ratio water/paste in mass adopted was 0.36. Mechanical extraction has an average raw yield of 26.15 ± 2.74%, with a recovery rate of 74.71%. After decanting for 10 days and filtration, the net yield was 15.39 ± 2.82% with a decantation and filtration rate of 58.67 ± 7.24%. The oil produced by traditional method has a water and volatile content of 1.01 ± 0.05% and a density of 0.884. The one produced by mechanical extraction has 0.19 ± 0.09% and a density of 0.891. The result of combustion test using two burners and one stove showed that the combustion rates were: 0.177 ± 0.034 g/min for the burner using one flame and 1.06 ± 0.04 g/min for the six flame burner and finally 3.07 ± 0, 4 g/min for the ten-flame stove. This ten-flame stove allowed 3 L of water to be boiled at 100 °C for 32 min, although during combustion it was observed a release of black fumes which indicates incomplete combustion with Jatropha in this Stove. The cost of the liter of Jatropha oil obtained is higher compared to fossil fuels such as petroleum (500 FCFA per liter and gas oil (624F CFA per liter. It would be possible to use vegetable oil from Jatropha as a cooking fuel. Keywords: Vegetable oil, Jatropha, Traditional extraction, Mechanical extraction, Bielenberg press

  14. Molecular beam sampling from a rocket-motor combustion chamber

    International Nuclear Information System (INIS)

    Houseman, John; Young, W.S.

    1974-01-01

    A molecular-beam mass-spectrometer sampling apparatus has been developed to study the reactive species concentrations as a function of position in a rocket-motor combustion chamber. Unique design features of the sampling system include (a) the use of a multiple-nozzle end plate for preserving the nonuniform properties of the flow field inside the combustion chamber, (b) the use of a water-injection heat shield, and (c) the use of a 300 CFM mechanical pump for the first vacuum stage (eliminating the use of a huge conventional oil booster pump). Preliminary rocket-motor tests have been performed using the highly reactive propellants nitrogen tetroxide/hydrazine (N 2 O 4 /N 2 H 4 ) at an oxidizer/fuel ratio of 1.2 by weight. The combustion-chamber pressure is approximately 60psig. Qualitative results on unreacted oxidizer/fuel ratio, relative abundance of oxidizer and fuel fragments, and HN 3 distribution across the chamber are presented

  15. Riik võib lüüa SAS-i esmaspäevaks Estonian Airi omanikeringist välja / Erik Müürsepp, Mikk Salu

    Index Scriptorium Estoniae

    Müürsepp, Erik

    2008-01-01

    SAS osaleb Estonian Airþile lisakapitali eraldamises ainult juhul, kui Eesti riik müüb oma osaluses lennukompaniis SAS-ile. Peaminister Andrus Ansipi ning majandus- ja kommunikatsiooniminister Juhan Partsi seisukoht

  16. Determination of cadmium, zinc, copper chromium and arsenic in crude oils

    NARCIS (Netherlands)

    Stigter, J.B.; Haan, H.P.M. de; Guicherit, R.

    1998-01-01

    One of the sources of trace heavy metal elements in air are emissions by the oil industry, either directly through stack emissions from refineries or indirectly from emissions of combustion of hydrocarbons. Emission estimates are based mainly on the trace metal content of the crude oil processed.

  17. Jüri Okas’ ‘specific objects’: diverging discourses in Estonian Art in the 1970s.

    OpenAIRE

    Kurg, Andres.

    2003-01-01

    Previously in the University eprints HAIRST pilot service at http://eprints.st-andrews.ac.uk/archive/00000367/ Article 3 of 6 in issue devoted to the visual culture of the Scandinavian and Baltic region. This article will look at the early works of Estonian architect and artist Jüri Okas and will try to work between diverging languages and interpretations, reading works by Okas against the background of Anglo-american conceptualism and minimalism of the same period. The first part of th...

  18. Bernhard Linde. Noor-Eesti vooriülem. Bernhard Linde. Leader of the Young Estonian Pack

    OpenAIRE

    Jaanus Kulli

    2012-01-01

    Bernhard Linde (1886–1954) was a recognized and prolific Estonian theatre critic of the first quarter of the 20th century, who mediated and propagated western as well as eastern European theatrical innovations. In addition, he was active as a literary and art critic, publisher, and proponent of libraries, to a modest extent he was a prose writer and poet. Unquestionably, however, Bernhard Linde’s most prominent role was as one of the founding members of the literary movement Young Estonia. He...

  19. Development and application of multi-zone model for combustion and pollutants formation in direct injection diesel engine running with vegetable oil or its bio-diesel

    International Nuclear Information System (INIS)

    Rakopoulos, C.D.; Antonopoulos, K.A.; Rakopoulos, D.C.

    2007-01-01

    A multi-zone model for calculation of the closed cycle of a direct injection (DI) Diesel engine is presented and applied for the interesting case of its operation with vegetable oil (cottonseed) or its derived bio-diesel (methyl ester) as fuels, which recently are considered as promising alternatives (bio-fuels) to petroleum distillates. Although there are many experimental studies, there is an apparent scarcity of theoretical models scrutinizing the formation mechanisms of combustion generated emissions when using these fuels. The model is two dimensional, multi-zone with the issuing jets (from the nozzle) divided into several discrete volumes, called 'zones', formed along the direction of the fuel injection and across it. The model follows each zone, with its own time history, as the spray penetrates into the swirling air environment (forming the non-burning zone) of the combustion chamber, before and after wall impingement. Droplet evaporation and jet mixing models are used to determine the amount of fuel and entrained air in each zone available for combustion. The mass, energy and state equations are applied in each zone to yield local temperatures and cylinder pressure histories. The concentrations of the various constituents are calculated by adopting a chemical equilibrium scheme for the C-H-O-N system of 11 species considered, together with the chemical rate equations for the calculation of nitric oxide (NO). A model for evaluation of soot formation and oxidation rates is included. The results from the relevant computer program for the in cylinder pressure, exhaust nitric oxide concentration (NO) and soot density are compared favorably with the corresponding measurements from an experimental investigation conducted on a fully automated test bed, standard 'Hydra', DI Diesel engine installed at the authors' laboratory. Iso-contour plots of equivalence ratio, temperature, NO and soot inside the combustion chamber at various instants of time when using these

  20. An overview of empty fruit bunch from oil palm as feedstock for bio-oil production

    International Nuclear Information System (INIS)

    Chang, Siu Hua

    2014-01-01

    Empty fruit bunch (EFB) from oil palm is one of the potential biomass to produce biofuels like bio-oil due to its abundant supply and favorable physicochemical characteristics. Confirming the assertion, this paper presents an overview of EFB as a feedstock for bio-oil production. The fundamental characteristics of EFB in terms of proximate analysis, ultimate analysis and chemical composition, as well as the recent advances in EFB conversion processes for bio-oil production like pyrolysis and solvolysis are outlined and discussed. A comparison of properties in terms of proximate analysis, ultimate analysis and fuel properties between the bio-oil from EFB and petroleum fuel oil is included. The major challenges and future prospects towards the utilization of EFB as a useful resource for bio-oil production are also addressed. - Highlights: • Palm EFB has high heating value and low greenhouse gas emissions during combustion. • Conversion of EFB to bio-oil is mainly by fast pyrolysis without and with catalyst. • Bio-oil from EFB is lower in heating value, heavier and more acidic than fuel oil. • The viscosity of bio-oil from EFB is between those of light and heavy fuel oils. • The flash and pour points of bio-oil from EFB are close to those of light fuel oil

  1. Investigating SO3 Formation from the Combustion of Heavy Fuel Oil in a Four-Stroke Medium Speed Test Engine

    DEFF Research Database (Denmark)

    Cordtz, Rasmus Lage; Schramm, Jesper; Rabe, Rom

    2013-01-01

    conversion and indirect detection via light absorption in a photometer. Present results show that SO3 formation is favored by elevated pressure histories, premixed combustion, and reduced speeds. The fraction of fuel sulfur converted to SO3 is measured to be on the order of 0.5%−2.4%, corresponding to 4......The validation of detailed models, in terms of SO3 formation in large marine engines operating on sulfur-containing heavy fuel oils (HFOs), relies on experimental work. The requisite is addressed in the present work, where SO3 is measured in the exhaust gas of an 80 kW medium-speed single......−14 ppmv. SO3 and NOx are not comparable, according to thermodynamic considerations, yet both species involve the radical pool and are studied in parallel. Resulting emissions of SO3 and NOx in the exhaust gas follow a comparable trend throughout the experiments....

  2. Rapid analytical procedure for determination of mineral oils in edible oil by GC-FID.

    Science.gov (United States)

    Wrona, Magdalena; Pezo, Davinson; Nerin, Cristina

    2013-12-15

    A procedure for the determination of mineral oils in edible oil has been fully developed. The procedure consists of using a sulphuric acid-impregnated silica gel (SAISG) glass column to eliminate the fat matter. A chemical combustion of the fatty acids takes place, while the mineral oils are not affected by the sulphuric acid. The column is eluted with hexane using a vacuum pump and the final extract is concentrated and analysed by gas chromatography (GC) with flame ionisation detector (FID). The detection limit (LOD) and the quantification limit (LOQ) in hexane were 0.07 and 0.21 μg g(-1) respectively and the LOQ in vegetable oil was 1 μg g(-1). Only a few minutes were necessary for sample treatment to have a clean extract. The efficiency of the process, measured through the recoveries from spiked samples of edible oil was higher than 95%. The procedure has been applied to determine mineral oil in olive oil from the retailed market. Copyright © 2013 Elsevier Ltd. All rights reserved.

  3. Energy efficiency and greenhouse gases

    International Nuclear Information System (INIS)

    Hamburg, A.; Martins, A.; Pesur, A.; Roos, I.

    1996-01-01

    Estonia's energy balance for 1990 - 1994 is characterized by the dramatic changes in the economy after regaining independence in 1991. In 1990 - 1993, primary energy supply decreased about 1.9 times. The reasons were a sharp decrease in exports of electric energy and industrial products, a steep increase in fuel prices and the transition from the planned to a market-oriented economy. Over the same period, the total amount of emitted greenhouse gases decreased about 45%. In 1993, the decrease in energy production and consumption stopped, and in 1994, a moderate increase occurred (about 6%), which is a proof stabilizing economy. Oil shale power engineering will remain the prevailing energy resource for the next 20 - 25 years. After stabilization, the use of oil shale will rise in Estonia's economy. Oil shale combustion in power plants will be the greatest source of greenhouse gases emissions in near future. The main problem is to decrease the share of CO 2 emissions from the decomposition of carbonate part of oil shale. This can be done by separating limestone particles from oil shale before its burning by use of circulating fluidized bed combustion technology. Higher efficiency of oil shale power plants facilitates the reduction of CO 2 emissions per generated MWh electricity considerably. The prognoses for the future development of power engineering depend essentially on the environmental requirements. Under the highly restricted development scenario, which includes strict limitations to emissions (CO 2 , SO 2 , thermal waste) and a severe penalty system, the competitiveness of nuclear power will increase. The conceptual steps taken by the Estonian energy management should be in compliance with those of neighboring countries, including the development programs of the other Baltic states

  4. Oil shale utilization in Israel

    International Nuclear Information System (INIS)

    Kaiser, A.

    1993-01-01

    Geological surveys have confirmed the existence of substantial Israeli oil shale reserves. The proven reserves contain approximately 12 billion tons of available ores, and the potential is deemed to be much higher. Economic studies conducted by PAMA indicate promising potential for power generation via Israel oil shale combustion. Electric power from oil shale appears competitive with power generated from coal fired power plants located along the coast. PAMA's demonstration power plant has been in operation since the end of 1989. Based on the successful results of the first year of operation, PAMA and IEC are now engaged in the pre-project program for a 1000 MW commercial oil shale fired power plant, based on eight 120 MW units; the first unit is scheduled to begin operation in 1996

  5. GOM Deepwater Horizon Oil Spill: A Time Series Analysis of Variations in Spilled Hydrocarbons

    Science.gov (United States)

    Palomo, C. M.; Yan, B.

    2013-12-01

    An estimated amount of 210 million gallons of crude oil was released into the Gulf of Mexico (GOM) from April 20th to July 15th 2010 during the Deepwater Horizon oil rig explosion. The spill caused a tremendous financial, ecological, environmental and health impact and continues to affect the GOM today. Variations in hydrocarbons including alkanes, hopanes and poly-cyclic aromatic hydrocarbons (PAHs) can be analyzed to better understand the oil spill and assist in oil source identification. Twenty-one sediment samples*, two tar ball samples and one surface water oil sample were obtained from distinct locations in the GOM and within varying time frames from May to December 2010. Each sample was extracted through the ASE 200 solvent extractor, concentrated down under nitrogen gas, purified through an alumina column, concentrated down again with nitrogen gas and analyzed via GC X GC-TOF MS. Forty-one different hydrocarbons were quantified in each sample. Various hydrocarbon 'fingerprints,' such as parental :alkylate PAH ratios, high molecular weight PAHs: low molecular weight alkane ratios, and carbon preference index were calculated. The initial objective of this project was to identify the relative hydrocarbon contributions of petrogenic sources and combustion sources. Based on the calculated ratios, it is evident that the sediment core taken in October of 2010 was greatly affected by combustion sources. Following the first month of the spill, oil in the gulf was burned in attempts to contain the spill. Combustion related sources have quicker sedimentation rates, and hydrocarbons from a combustion source essentially move into deeper depths quicker than those from a petrogenic source, as was observed in analyses of the October 2010 sediment. *Of the twenty-one sediment samples prepared, nine were quantified for this project.

  6. Experimental investigation on a diesel engine using neem oil and its methyl ester

    Directory of Open Access Journals (Sweden)

    Sivalakshmi S.

    2011-01-01

    Full Text Available Fuel crisis and environmental concerns have led to look for alternative fuels of bio-origin sources such as vegetable oils, which can be produced from forests, vegetable oil crops and oil bearing biomass materials. Vegetable oils have energy content comparable to diesel fuel. The effect of neem oil (NeO and its methyl ester (NOME on a direct injected four stroke, single cylinder diesel engine combustion, performance and emission is investigated in this paper. The results show that at full load, peak cylinder pressure is higher for NOME; peak heat release rate during the premixed combustion phase is lower for neat NeO and NOME. Ignition delay is lower for neat NeO and NOME when compared with diesel at full load. The brake thermal efficiency is slightly lower for NeO at all engine loads, but in the case of NOME slightly higher at full load. It has been observed that there is a reduction in NOx emission for neem oil and its methyl ester along with an increase in CO, HC and smoke emissions.

  7. NOx emissions from the underfeed combustion of coal and biomass

    International Nuclear Information System (INIS)

    Purvis, M.R.I.; Tadulan, E.L.; Tariq, A.S.

    2000-01-01

    Underfeed stokers have an inherent ability to minimise smoke emissions, thus providing environmental benefits in the combustion of solid fuels, such as biomass materials, which have a high volatile matter content. An evaluation of this attribute requires comparisons of the performance of combustion equipment using these fuels against reference data for coals. However, the recent literature is virtually devoid of studies of coal combustion in underfeed stokers and, in particular, information on nitrogen oxide emissions. In the UK, this reflects a lack of commercial interest in small-scale coal firing due to the wide availability of inexpensive gas and oil fuels. An experimental investigation has been carried out into the combustion of bituminous coal, anthracite and a 50:50 blend by mass of anthracite and oak wood chips on a modified commercial underfeed stoker. The intention was to obtain operational experiences in burning the fuels and reference data for nitrogen oxide emissions. Problems in the combustion of the fuels are described and related to the determination of nitrogen oxide emission values found under optimised plant conditions. These values, expressed at 6% O 2 , were 265 ppm for bituminous coal, 90 ppm for anthracite and 106 ppm for the anthracite/wood chip blend. (Author)

  8. Energy security and the IEA ExCo on combustion

    Energy Technology Data Exchange (ETDEWEB)

    Hutchinson, P. [Hutchinson Consultant (United Kingdom)

    2009-07-01

    Energy security is an issue for those nations which consume more energy than is available from indigenous sources. A failure to secure adequate energy supplies at an acceptable price prejudices both national and economic security. Energy security is therefore a significant policy issue. A discussion of energy security and the International Energy Agency ExCo on combustion was offered in this presentation. The purpose of the discussion was to determine if a task or set of tasks on combustion research related to energy security should be launched; the structure of such a task; topics of interest; who would wish to participate; who would lead the collaboration; and the next steps. The presentation discussed the proper understanding and analysis of energy security and the interactions between international politics; defence; economics and economic development; present and future technologies; national infrastructure; resource distribution; and environmental science and politics. The presentation also discussed whether there was a shortage of energy, world reserves of crude oil, coal, and hydrocarbons. Oil supply disruptions and nominal and real world oil prices were also discussed. Options for addressing energy security were presented, with particular reference to increasing the energy intensity of the economy; using a wide range of different fuels such as coal; developing indigenous supplies such as renewables; and developing a reliable long life energy source. It was concluded that imports of energy can be reduced when energy security improves. tabs., figs.

  9. Studies on piston bowl geometries using single blend ratio of various non-edible oils.

    Science.gov (United States)

    Viswanathan, Karthickeyan; Pasupathy, Balamurugan

    2017-07-01

    The depletion of fossil fuels and hike in crude oil prices were some of the main reasons to explore new alternatives from renewable source of energy. This work presents the impact of various bowl geometries on diesel engine with diesel and biodiesel samples. Three non-edible oils were selected, namely pumpkin seed oil, orange oil and neem oil. These oils were converted into respective biodiesel using transesterification process in the presence of catalyst and alcohol. After transesterification process, the oils were termed as pumpkin seed oil methyl ester (PSOME), orange oil methyl ester (OME) and neem oil methyl ester (NOME), respectively. The engine used for experimentation was a single-cylinder four-stroke water-cooled direct-injection diesel engine and loads were applied to the engine using eddy current dynamometer. Two bowl geometries were developed, namely toroidal combustion chamber (TCC) and trapezoidal combustion chamber (TRCC). Also, the engine was inbuilt with hemispherical combustion chamber (HCC). The base line readings were recorded using neat diesel fuel with HCC for various loads. Followed by 20% of biodiesel mixed with 80% neat diesel for all prepared methyl esters and termed as B1 (20% PSOME with 80% diesel), B2 (20% OME with 80% diesel) and B3 (20% NOME with 80% diesel). All fuel samples were tested in HCC, TCC and TRCC bowl geometries under standard injection timing and with compression ratio of 18. Increased brake thermal efficiency and reduced brake specific fuel consumption were observed with diesel in TCC geometry. Also, higher heat release and cylinder pressures with lower ignition delay were recorded with TCC bowl geometry. TCC bowl geometry showed lower CO, HC and smoke emissions with B2 fuel sample than diesel and other biodiesel samples. But, higher NOx emission was observed in HCC and TCC than that in TRCC bowl geometry. Graphical abstract ᅟ.

  10. Combustion

    CERN Document Server

    Glassman, Irvin

    2008-01-01

    Combustion Engineering, a topic generally taught at the upper undergraduate and graduate level in most mechanical engineering programs, and many chemical engineering programs, is the study of rapid energy and mass transfer usually through the common physical phenomena of flame oxidation. It covers the physics and chemistry of this process and the engineering applications-from the generation of power such as the internal combustion automobile engine to the gas turbine engine. Renewed concerns about energy efficiency and fuel costs, along with continued concerns over toxic and particulate emissions have kept the interest in this vital area of engineering high and brought about new developments in both fundamental knowledge of flame and combustion physics as well as new technologies for flame and fuel control. *New chapter on new combustion concepts and technologies, including discussion on nanotechnology as related to combustion, as well as microgravity combustion, microcombustion, and catalytic combustion-all ...

  11. Numerical and Experimental Investigation of Combustion and Knock in a Dual Fuel Gas/Diesel Compression Ignition Engine

    Directory of Open Access Journals (Sweden)

    A. Gharehghani

    2012-01-01

    Full Text Available Conventional compression ignition engines can easily be converted to a dual fuel mode of operation using natural gas as main fuel and diesel oil injection as pilot to initiate the combustion. At the same time, it is possible to increase the output power by increasing the diesel oil percentage. A detailed performance and combustion characteristic analysis of a heavy duty diesel engine has been studied in dual fuel mode of operation where natural gas is used as the main fuel and diesel oil as pilot. The influence of intake pressure and temperature on knock occurrence and the effects of initial swirl ratio on heat release rate, temperature-pressure and emission levels have been investigated in this study. It is shown that an increase in the initial swirl ratio lengthens the delay period for auto-ignition and extends the combustion period while it reduces NOx. There is an optimum value of the initial swirl ratio for a certain mixture intake temperature and pressure conditions that can achieve high thermal efficiency and low NOx emissions while decreases the tendency to knock. Simultaneous increase of intake pressure and initial swirl ratio could be the solution to power loss and knock in dual fuel engine.

  12. Energetic dependency on the oil reserve- resources of crude oil in the world

    Directory of Open Access Journals (Sweden)

    Marína Sidorová

    2006-10-01

    Full Text Available Crude oil belongs to the most important energy resources nowadays., However its reserves are the smallest in comparison with other energy resources as coal, gas or uranium. The world oil consumption continuously increases and within 20-year period there could be about one third. So, the consumption of combustibles will probably increase and the reserves will decrease. Promising are new resources or a better utilization of primary sources. It´s a question of a short time when world scientists should think about this indisputably worldwide problem and would provide an equivalent substitution with an available ecological solution.

  13. Experimental study of hydrogen as a fuel additive in internal combustion engines

    Energy Technology Data Exchange (ETDEWEB)

    Saanum, Inge

    2008-07-01

    . % hydrogen to the methane, but 5 vol. % hydrogen also resulted in a noticeable increase. The flame structure was also influenced by the hydrogen addition as the flame front had a higher tendency to become wrinkled or cellular. The effect is believed to mainly be caused by a reduction in the effective Lewis number of the mixture. In the gas engine experiments, the effect of adding 25 vol. % hydrogen to natural gas was investigated when the engine was run on lean air/fuel mixtures and on stoichiometric mixtures with exhaust gas recirculation. The hydrogen addition was found to extend the lean limit of stable combustion and hence caused lower NO{sub x} emissions. The brake thermal efficiency increased with the hydrogen addition, both for the fuel lean and the stoichiometric mixtures with exhaust gas recirculation. This is mainly because of shorter combustion durations when the hydrogen mixture was used, leading to thermodynamically improved cycles. Two types of experiments were performed in compression ignition engines. First, homogenous charge compression ignition (HCCI) experiments were performed in a single cylinder engine fueled with natural gas and diesel oil. As HCCI engines have high thermal efficiency and low NO{sub x} and PM emissions it may be more favorable to use natural gas in HCCI engines than in spark ignition engines. The mixture of natural gas, diesel oil and air was partly premixed before combustion. The natural gas/diesel ratio was used to control the ignition timing as the fuels have very different ignition properties. The natural gas was also replaced by a 20 vol. % hydrogen/natural gas mixture to study the effect of hydrogen on the ignition and combustion process. Also, rape seed methyl ester (RME) was tested instead of the diesel oil. The combustion phasing was found to mainly be controlled by the amount of liquid fuel injected. The last experiments with compression ignition were performed by using a standard Scania diesel engine where the possibilities

  14. Radial oil injection applied to main engine bearings: evaluation of injection control rules

    DEFF Research Database (Denmark)

    Estupiñan, EA; Santos, Ilmar

    2012-01-01

    , the dynamic behaviour of the main bearing of a medium-size engine is theoretically analysed when the engine operates with controllable radial oil injection and four different injection control rules. The theoretical investigation is based on a single-cylinder combustion engine model. The performance......The performance of main bearings in a combustion engine affects key functions such as durability, noise and vibration. Thus, with the aim of reducing friction losses and vibrations between the crankshaft and the bearings, the work reported here evaluates different strategies for applying...... controllable radial oil injection to main crankshaft journal bearings. In an actively lubricated bearing, conventional hydrodynamic lubrication is combined with controllable hydrostatic lubrication, where the oil injection pressures can be modified depending on the operational conditions. In this study...

  15. Effect of vegetable de-oiled cake-diesel blends on diesel engine

    Energy Technology Data Exchange (ETDEWEB)

    Raj, C.S. [Bharathiyar College of Engineering and Technology, Karaikal (India). MGR Educational and Research Inst.; Arivalagar, A.; Sendilvelan, S. [MGR Univ., Chennai (India). MGR Educational and Research Inst.; Arul, S. [Panimalar College of Engineering, Channai (India)

    2009-07-01

    This study evaluated the use of coconut oil methyl ester (COME) as a blending agent with the vegetable de-oiled cakes used in biodiesel production. Different proportions of the de-oiled cake were combined with diesel in order to investigate performance, emissions, and combustion characteristics. The experiments were conducted on a 4-stroke single cylinder, air-cooled diesel engine. Fuel flow rates were measured and a thermocouple was used to measure exhaust gas temperatures. A combustion analyzer was used to measure cylinder pressure and heat release rates. Brake thermal efficiency, brake power, and specific fuel consumption performance was monitored. Results of the study showed that rates of heat release were reduced for the de-oiled cake blended fuels as a result of the change in fuel molecular weight. The variation of NOx with load for neat diesel blends was examined. There was no variation of NOx emission up to 50 per cent of load for all blended oils, and it increased with load. Smoke density was reduced for all blends. Soot production was decreased by the oxygen present in the de-oiled cake. The study showed that fossil fuel oil consumption decreased by 14 to 15 per cent when the de-oiled biodiesel was used at low loads, and 4 to 5 per cent at peak loads. 10 refs., 4 tabs., 9 figs.

  16. Combustion of agro-waste with coal in a fluidized bed

    Energy Technology Data Exchange (ETDEWEB)

    Atimtay, Aysel T. [Middle East Technical University, Department of Environmental Engineering, Ankara (Turkey)

    2010-02-15

    In this study, a review of the studies done on the co-combustion of some agro-waste in a bubbling fluidized bed combustor (BFBC) having an inside diameter of 102 mm and a height of 900 mm is given. The agro-waste used to investigate the co-combustion characteristics were peach and apricot stones produced as a waste from the fruit juice industry, and olive cake produced as a waste from the olive oil industry. These are typical wastes for a Mediterranean country. A lignite coal was used for co-combustion. On-line concentrations of O{sub 2}, CO, CO{sub 2}, SO{sub 2}, NO{sub x} and total hydrocarbons (C{sub m} H{sub n}) were measured in the flue gas during combustion experiments. Variations of emissions of various pollutants were studied by changing the operating parameters (excess air ratio, fluidization velocity and fuel feed rate). Temperature distribution along the bed was measured with thermocouples. Emissions were also monitored from the exhaust. Various combinations of coal and biomass mixtures were tested. During the combustion tests, it was observed that the volatile matter from the biomass quickly volatilizes and mostly burns in the freeboard. The temperature profiles along the bed and the freeboard also confirmed this phenomenon. It was found that as the volatile matter of the biomass increases, combustion takes place more in the freeboard region. Better combustion conditions occur at higher excess air ratios. The results showed that co-combustion with these three proposed biomasses lowers the SO{sub 2} and NO{sub x} emissions considerably. CO and hydrocarbon emissions are lower at the higher excess air ratios. (orig.)

  17. Surrogate fuel formulation for light naphtha combustion in advanced combustion engines

    KAUST Repository

    Ahmed, Ahfaz

    2015-03-30

    Crude oil once recovered is further separated in to several distinct fractions to produce a range of energy and chemical products. One of the less processed fractions is light naphtha (LN), hence they are more economical to produce than their gasoline and diesel counterparts. Recent efforts have demonstrated usage of LN as transportation fuel for internal combustion engines with slight modifications. In this study, a multicomponent surrogate fuel has been developed for light naphtha fuel using a multi-variable nonlinear constrained optimization scheme. The surrogate, consisting of palette species n-pentane, 2-methylhexane, 2-methylbutane, n-heptane and toluene, was validated against the LN using ignition quality tester following ASTM D6890 methodology. Comparison of LN and the surrogate fuel demonstrated satisfactory agreement.

  18. Combustion

    CERN Document Server

    Glassman, Irvin

    1997-01-01

    This Third Edition of Glassman's classic text clearly defines the role of chemistry, physics, and fluid mechanics as applied to the complex topic of combustion. Glassman's insightful introductory text emphasizes underlying physical and chemical principles, and encompasses engine technology, fire safety, materials synthesis, detonation phenomena, hydrocarbon fuel oxidation mechanisms, and environmental considerations. Combustion has been rewritten to integrate the text, figures, and appendixes, detailing available combustion codes, making it not only an excellent introductory text but also an important reference source for professionals in the field. Key Features * Explains complex combustion phenomena with physical insight rather than extensive mathematics * Clarifies postulates in the text using extensive computational results in figures * Lists modern combustion programs indicating usage and availability * Relates combustion concepts to practical applications.

  19. Process for gasification of heavy hydrocarbons or salvaged oil. [German patent

    Energy Technology Data Exchange (ETDEWEB)

    Koch, C

    1978-09-14

    The invention refers to the separation of solids which are carried over during evaporation of salvaged oil (oil recovered from used oil or fat). They are removed by exposing the oil vapour to an acceleration of 500 g to 20,000g in a hot gas cyclone. Subsequently the cleaned gas is converted to fission gas in a fission gas generator using an air-water gas mixture and is taken to the combustion equipment. By this process salvaged oil and heavy hydrocarbons can be used for burning in Diesel engines without previous refining.

  20. Characteristics of a tractor engine using mineral and biodiesel fuels blended with rapeseed oil Características de um motor de trator alimentado com combustíveis mineral e biodisel misturados com óleo de colza

    Directory of Open Access Journals (Sweden)

    Tone Godeša

    2010-10-01

    Full Text Available One of the most unfavourable characteristics of crude vegetable oil when used as the fuel is the high viscosity. To improve this weakness, oil can be blended with mineral diesel or biodiesel fuels. This study was designed to evaluate how the use of mineral diesel or biodiesel blend with cold pressed rapeseed (Brassica napus oil affects the engine power, torque and fuel consumption. A tractor equipped with direct injection, water cooling system and three-cylinder diesel engine was used for the experiment. Fuels used were standard diesel fuel (diesel, rapeseed oil methyl ester - biodiesel (B100 and their mixtures with 10, 30 and 50 vol. % of cold pressed rapeseed oil (RO. Increased portion of RO in diesel fuel blends had almost no effect on the torque measured on the tractor PTO shaft; it however decreased the maximal power. Fuel blends with B100 and rising RO content (up to 50% gave a positive correlation with maximal torque and power. By increasing the portion of RO from 0 to 50%, the minimal specific fuel consumption increased by 6.65% with diesel and decreased by 2.98% with B100 based fuel.Uma das características mais desfavoráveis dos óleos vegetais crus usados como combustível é a alta viscosidade. Para melhorar este ponto fraco, o óleo pode ser misturado com diesel mineral ou biodiesel. Este estudo foi desenvolvido para avaliar como o uso de diesel mineral ou biodiesel misturado a oleo de colza (Brassica napus extraído por pressão a frio afeta a potência do motor, o torque e o consumo de combustível, empregando um trator equipado com injeção direta, sistema de refrigeração de água e um motor de três cilindros. Os combustíveis utilizados foram o diesel padrão (diesel, éster metílico de óleo de sementes de colza - biodiesel (B100 e suas misturas com 10, 30 e 50 % vol. de óleo de semente de colza pressionado a frio (RO. Maiores proporções de RO nas misturas de diesel praticamente não tiveram efeito sobre o torque

  1. Research on EHN additive on the diesel engine combustion characteristics in plateau environment

    Science.gov (United States)

    Sun, Zhixin; Li, Ruoting; Wang, Xiancheng; Hu, Chuan

    2017-03-01

    Aiming at the combustion deterioration problem of diesel engine in plateau environment, a bench test was carried out for the effects of EHN additive on combustion characteristics of the diesel engine with intake pressure of 0.68 kPa. Test results showed that with the full load working condition of 1 400 r/min: Cylinder pressure and pressure uprising rate decreased with EHN additive added in, mechanical load on the engine could be relieved; peak value of the heat release rate decreased and its occurrence advanced, ignition delay and combustion duration were shortened; cylinder temperature and exhaust gas temperature declined, thermal load on the engine could be relieved, output torque increased while specific oil consumption decreased, and effective thermal efficiency of diesel engine increased.

  2. Automatic Method for Controlling the Iodine Adsorption Number in Carbon Black Oil Furnaces

    Directory of Open Access Journals (Sweden)

    Zečević, N.

    2008-12-01

    Full Text Available There are numerous of different inlet process factors in carbon black oil furnaces which must be continuously and automatically adjusted, due to stable quality of final product. The most important six inlet process factors in carbon black oil-furnaces are:1. volume flow of process air for combustion2. temperature of process air for combustion3. volume flow of natural gas for insurance the necessary heat for thermal reaction of conversionthe hydrocarbon oil feedstock in oil-furnace carbon black4. mass flow rate of hydrocarbon oil feedstock5. type and quantity of additive for adjustment the structure of oil-furnace carbon black6. quantity and position of the quench water for cooling the reaction of oil-furnace carbon black.The control of oil-furnace carbon black adsorption capacity is made with mass flow rate of hydrocarbon feedstock, which is the most important inlet process factor. Oil-furnace carbon black adsorption capacity in industrial process is determined with laboratory analyze of iodine adsorption number. It is shown continuously and automatically method for controlling iodine adsorption number in carbon black oil-furnaces to get as much as possible efficient control of adsorption capacity. In the proposed method it can be seen the correlation between qualitatively-quantitatively composition of the process tail gasses in the production of oil-furnace carbon black and relationship between air for combustion and hydrocarbon feedstock. It is shown that the ratio between air for combustion and hydrocarbon oil feedstock is depended of adsorption capacity summarized by iodine adsorption number, regarding to BMCI index of hydrocarbon oil feedstock.The mentioned correlation can be seen through the figures from 1. to 4. From the whole composition of the process tail gasses the best correlation for continuously and automatically control of iodine adsorption number is show the volume fraction of methane. The volume fraction of methane in the

  3. Advancing Understanding of Emissions from Oil and Natural ...

    Science.gov (United States)

    Executive Summary Environmentally responsible development of oil and gas assets requires well-developed emissions inventories and measurement techniques to verify emissions and the effectiveness of control strategies. To accurately model the oil and gas sector impacts on air quality, it is critical to have accurate activity data, emission factors and chemical speciation profiles for volatile organic compounds (VOCs) and nitrogen oxides (NOx). This report describes a U.S. Environmental Protection Agency (EPA) Office of Research and Development (ORD) Region 8 Regional Applied Research Effort (RARE) effort executed in Fiscal Year (FY) 2014 to FY 2016 that aimed to improve information on upstream oil and production emissions and identify areas where future work is needed. The project involved both field activities and data analysis and synthesis work with emphasis on product-related VOC emissions from well pads. In oil and gas basins with significant condensate and oil production, VOC emissions from well pads primarily arise from the separation of gas and liquid products and the storage process, with the control of emissions usually accomplished by enclosed combustion devices (ECDs), such as flares. Fugitive emissions of VOCs can originate from leaks and from potentially ineffective control systems. In the case of ECDs, byproducts of incomplete combustion may produce more highly reactive ozone precursor species. For both compliance and scientific purposes, the abili

  4. Moessbauer effect study on the corrosion of an oil refinery

    International Nuclear Information System (INIS)

    Da Costa, M.I. Jr.; Kunrath, J.I.; Moro, J.T.; Englert, G.; Comparsi, L.U.; Mueller, I.L.

    1994-01-01

    Metallic coupons are placed in strategical points of an oil refining plant in order to control the amount of corrosion produced by amine stripping of H 2 S from liquefied oil and combustible gases. This paper reports some of the results obtained by CEMS and transmission Moessbauer spectroscopy for the corrosion products formed on such coupons. (orig.)

  5. Fuel oil and LPG; Fioul et GPL

    Energy Technology Data Exchange (ETDEWEB)

    Philippon, A. [UFIP, Union Francaise des Industries Petroliere, 75 - Paris (France)

    1997-12-31

    The impacts of new environmental regulations on the heavy fuel oil and refining French markets, are studied. Illustrated with numerous diagrams concerning oil price evolution, fuel price comparison, market shares, consumption data, etc., it is shown that a brutal elimination of high sulfur content oil fuels would cause an extremely negative impact for the refining industry and for the French economy. Sulfur content limits should be kept at their present levels and users should be free to select technical choices in order to keep within these limits, either through fume desulfurization either through fuel-natural gas mixed combustion

  6. Experimental investigation on the availability, performance, combustion and emission distinctiveness of bael oil/ diesel/ diethyl ether blends powered in a variable compression ratio diesel engine

    Science.gov (United States)

    Krishnamoorthi, M.; Malayalamurthi, R.

    2018-02-01

    The present work aims at experimental investigation on the combined effect of injection timing (IT) and injection pressure (IP) on the performance and emissions characteristics, and exergy analysis of a compression-ignition (CI) engine powered with bael oil blends. The tests were conducted using ternary blends of bael oil, diethyl ether (DEE) and neat diesel (D) at various engine loads at a constant engine speed (1500 rpm). With B2 (60%D + 30%bael oil+10%DEE) fuel, the brake thermal efficiency (BTE) of the engine is augmented by 3.5%, reduction of 4.7% of oxides of nitrogen (NOx) emission has been observed at 100% engine load with 250 bar IP. B2 fuel exhibits 7% lower scale of HC emissions compared to that of diesel fuel at 100% engine load in 23 °bTDC IT. The increment in both cooling water and exhaust gas availabilities lead to increasing exergy efficiency with increasing load. The exergy efficiency of about 62.17% has been recorded by B2 fuel at an injection pressure of 230 IP bar with 100% load. On the whole, B2 fuel displays the best performance and combustion characteristics. It also exhibits better characteristics of emissions level in terms of lower HC, smoke opacity and NOx.

  7. Determining oil consumption of an I.C. engine

    International Nuclear Information System (INIS)

    Dale, B.W.

    1981-01-01

    A method of measuring the consumption of lubricating oil by an internal combustion engine comprising the operations of isotopically labelling representative fractions of oil with deuterium atoms, circulating the lubricating oil through an engine under test, and measuring the amount of deuterium emitted from the exhaust pipe of the engine. Apparatus comprising means for subjecting the exhaust gas to an oxidizing environment and an infra-red transmissive region in which the infrared spectrum of the gas can be observed for the determination of HDO from the O-D band stretch is also described. Preferably at least 10% of the hydrocarbons in the oil are deuterated. (author)

  8. Engine emissions and combustion analysis of biodiesel from East African countries

    Directory of Open Access Journals (Sweden)

    Paul Maina

    2014-03-01

    Full Text Available Environmental, availability and financial problems associated with fossil fuels encourage the manufacture and use of biodiesel. In this study, vegetable oil was extracted from Jatropha curcas seeds sourced from Kenya and Tanzania. A two-step acid base catalytic transesterification process was used to produce biodiesel because of the amount of free fatty acids present in the oil. The test rig used in the experiments was an Audi, 1.9-litre, turbocharged direct injection, compression ignition engine. Emissions were measured using an Horiba emission analyser system while combustion data was collected by a data acquisition system, from which cylinder pressure and rate of heat release of the test engine in every crank angle were calculated. The two biodiesels showed better emission characteristics than the fossil diesel included in the tests for comparison purposes. Cylinder pressure and heat release of the biodiesel were also within acceptable ranges. However, the emission and combustion characteristics differed between the two biodiesels a result likely related to their different origins. These findings prove that the source of biodiesel is an important factor to consider.

  9. Comparing the greenhouse gas emissions from three alternative waste combustion concepts.

    Science.gov (United States)

    Vainikka, Pasi; Tsupari, Eemeli; Sipilä, Kai; Hupa, Mikko

    2012-03-01

    Three alternative condensing mode power and combined heat and power (CHP) waste-to-energy concepts were compared in terms of their impacts on the greenhouse gas (GHG) emissions from a heat and power generation system. The concepts included (i) grate, (ii) bubbling fluidised bed (BFB) and (iii) circulating fluidised bed (CFB) combustion of waste. The BFB and CFB take advantage of advanced combustion technology which enabled them to reach electric efficiency up to 35% and 41% in condensing mode, respectively, whereas 28% (based on the lower heating value) was applied for the grate fired unit. A simple energy system model was applied in calculating the GHG emissions in different scenarios where coal or natural gas was substituted in power generation and mix of fuel oil and natural gas in heat generation by waste combustion. Landfilling and waste transportation were not considered in the model. GHG emissions were reduced significantly in all of the considered scenarios where the waste combustion concepts substituted coal based power generation. With the exception of condensing mode grate incinerator the different waste combustion scenarios resulted approximately in 1 Mton of fossil CO(2)-eq. emission reduction per 1 Mton of municipal solid waste (MSW) incinerated. When natural gas based power generation was substituted by electricity from the waste combustion significant GHG emission reductions were not achieved. Copyright © 2011 Elsevier Ltd. All rights reserved.

  10. Pyrolysis and combustion kinetics of lycopodium particles in thermogravimetric analysis

    Institute of Scientific and Technical Information of China (English)

    Seyed Alireza Mostafavi; Sadjad Salavati; Hossein Beidaghy Dizaji; Mehdi Bidabadi

    2015-01-01

    Biomass is a kind of renewable energy which is used increasingly in different types of combustion systems or in the production of fuels like bio-oil. Lycopodium is a cellulosic particle, with good combustion properties, of which microscopic images show that these particles have spherical shapes with identical diameters of 31 μm. The measured density of these particles is 1.0779 g/cm2. Lycopodium particles contain 64.06% carbon, 25.56% oxygen, 8.55% hydrogen and 1.83% nitrogen, and no sulfur. Thermogravimetric analysis in the nitrogen environment indicates that the maximum of particle mass reduction occurs in the temperature range of 250−550 °C where the maximum mass reduction in the DTG diagrams also occurs in. In the oxygen environment, an additional peak can also be observed in the temperature range of 500−600 °C, which points to solid phase combustion and ignition temperature of lycopodium particles. The kinetics of reactions is determined by curve fitting and minimization of error.

  11. Combustion engineering

    CERN Document Server

    Ragland, Kenneth W

    2011-01-01

    Introduction to Combustion Engineering The Nature of Combustion Combustion Emissions Global Climate Change Sustainability World Energy Production Structure of the Book   Section I: Basic Concepts Fuels Gaseous Fuels Liquid Fuels Solid Fuels Problems Thermodynamics of Combustion Review of First Law Concepts Properties of Mixtures Combustion StoichiometryChemical EnergyChemical EquilibriumAdiabatic Flame TemperatureChemical Kinetics of CombustionElementary ReactionsChain ReactionsGlobal ReactionsNitric Oxide KineticsReactions at a Solid SurfaceProblemsReferences  Section II: Combustion of Gaseous and Vaporized FuelsFlamesLaminar Premixed FlamesLaminar Flame TheoryTurbulent Premixed FlamesExplosion LimitsDiffusion FlamesGas-Fired Furnaces and BoilersEnergy Balance and EfficiencyFuel SubstitutionResidential Gas BurnersIndustrial Gas BurnersUtility Gas BurnersLow Swirl Gas BurnersPremixed-Charge Engine CombustionIntroduction to the Spark Ignition EngineEngine EfficiencyOne-Zone Model of Combustion in a Piston-...

  12. A Study of the Use of Jatropha Oil Blends in Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Krishna, C.R.

    2010-10-01

    Executive Summary: This project investigated the combustion performance of blends of unrefined Jatropha oil and its blends in laboratory boilers. Although a very limited amount of testing blends in distillate oil, ASTM No. 2 oil or heating oil was conducted, the primary interest was in testing the performance of blends with residual ASTM No. 6 oil. The basic idea is to provide a renewable fuel option to residual oil used in space heating and in industrial applications. The intent also was to explore the use of non-edible plant oil and one that might be potentially cheaper than biodiesel. The characteristics of No. 6 oil, such as high viscosity at ambient temperature, which requires it to be kept heated, make the blending with such oils feasible. Jatropha oil is one such oil and there is currently considerable interest building up in its use as a source for making biodiesel and jet fuel. A 10% blend of Jatropha oil with heating oil was burned using a standard burner in a residential boiler. Combustion performance was shown to be comparable with that of burning heating oil by itself with some noticeable differences. Typical heating oil has about 2000 ppm of sulfur, while the Jatropha oil has about 50 ppm leading to lower levels of sulphur dioxide emissions. Stack measurements also showed that the NOx emission was lower with the blend. We have previously reported similar reductions in NOx with blends of biodiesel in heating oil as well as slight reductions in PM2.5, particulates below 2.5 microns in size. Long term tests were not part of this project and hence deleterious effects on pumps, seals etc., if any, were not measured. The majority of the work involved testing blends of Jatropha oil with residual oil in a 1.5 million Btu/hr boiler with a burner modified to burn residual oil. Blends of 20 and 60% Jatropha oil and 100% Jatropha oil were burned in the combustion performance tests. The residual oil used had a sulfur content of over 2000 ppm and hence dramatic

  13. Rahvusliku ajaloo tõlgendusi eesti draamas ja teatris 1970.–1980. aastatel. Interpretations of National History in Estonian Drama and Theatre in the 1970s–1980s

    Directory of Open Access Journals (Sweden)

    Piret Kruuspere

    2012-04-01

    Full Text Available According to theatre scholar Freddie Rokem, theatre portraying or performing historical events is seeking to overcome both the separation and the exclusion from the past, as well as ’striving to create a community where the events from this past will matter again’. This article covers the topic of interpretations of national history in Estonian theatre and in original dramaturgy during the Soviet era, with the focus on aspects like national self-reflection and the relationship to the common past. The main focus is on the 1970s, with examples from Rein Saluri’s, Mati Unt’s and Jaan Kaplinski’s drama productions. During the period in question, re-tellings of national history on Estonian theatre stages were clothed in metaphors, allusions and secret codes – Aesopian language. Within the Soviet cultural context, I analyse if and to what extent theatre of the time displayed resistance, political theatre or social allegory. Theatre was also connected with the principle of playing or playfulness, which on one hand indicates national resistance, national endurance, and a certain survival strategy, but on the other hand indicates the Estonian as being an involuntary homo ludens – the Playing Man, who through various enforced roles is trying to adjust to the whirlwinds of history. Saluri’s first play, the intellectual drama Külalised (The Guests, opens with an allusion to a drama classic the world over, William Shakespeare’s Hamlet, adding a powerful national-symbolic background to the play. The role-play which permeates and structures the play (The Host–The Guest however, displays allegorical references to changes in the status and self-image of Estonians. In Unt’s play Peaproov (Dress Rehearsal, the principle of playing/acting sheds ironic light on the makers of an historical film and their readiness to create superficially flashy interpretations at any cost: this take acts as an estranging and generalising reflection in a context

  14. THE PHYSICAL AND CHEMICAL CHARACTERIZATION OF THE EMISSIONS FROM A RESIDENTIAL OIL BOILER

    Science.gov (United States)

    The toxicity of emissions from the combustion of home heating oil and the use of residential oil boilers (ROB) is an important health concern. Yet scant physical and chemical information about the emissions from this source are available for dispersion, climate, and source-recep...

  15. The Estonian national program for sustainable resource development and its connection with teaching about fossil fuels in chemistry courses

    International Nuclear Information System (INIS)

    Karik, H.

    1996-01-01

    The conception of sustainable resource development worked out under the initiative of the United Nations (UN) actualizes ideas for improving the health of people and the environment. The needs of people are to he addressed and, simultaneously, natural resources preserved. That is ,why ecological and economic expenses are to he integrated and flow sheets of industrial plants are to be reorganized in order to utilize natural resources in a rational way. The association of Estonia with the resolution of the UN Conference on Environmental Development held in Rio de Janeiro and the resolution of the Estonian Parliament concerning The National Program of Sustainable Development require changes in our lifestyle. Chemical education in schools has to support a change in the way of thinking and many concrete subjects can be connected with the problems of sustainable development. Metallic elements get into the environment mostly with fuel combustion ashes. According to various prognoses, fossil fuel resources will last for a thousand years. This means that more and more metallic compounds are thrown into the environment. Dispersion of metals in the air, water bodies and soil is continuously increasing. Finally, they reach the food chain and to the human body. As a result, toxicosis, illnesses, and inadvisable dislocations in organic life may occur. The trend to use ash as a raw material for metal production is considered to have some prospective economically attractive application. This would be one possible way of sustainable resource development to avoid the increase of environmental pollution and increase production of the corresponding metals

  16. The Dialogue with Hamlet: Paul-Eerik Rummo’s “Hamlet’s Songs” as an Example of the Existential Paradigm in Estonian Culture

    Directory of Open Access Journals (Sweden)

    Anneli Mihkelev

    2013-06-01

    Full Text Available The article demonstrates different meanings of the motif of Hamlet in the Estonian culture. Hamlet as a literary figure has been very important and influential, a symbol of will and a fighter in a hopeless situation. Paul-Eerik Rummo’s poem “Hamlet’s Songs” (1964 forms the centre around which revolve not only written texts but also many such cultural texts as theatre performances and music, all connected by allusions to Hamlet. Rummo’s poem is one of the most innovative poems from the 1960s in Estonian literature. The generation of the 1960s was influenced by several important contemporary theories, including existentialism. Many young writers systematically undermined the Soviet regime in their works. The use of the motif of Hamlet reveals a similarity between the existential and romantic rebellions. Rummo’s dialogue with Hamlet in his poem expresses optimism in a hopeless situation in a way different from Shakespeare’s.

  17. Computational parameters in thermal recovery of crude oil

    Energy Technology Data Exchange (ETDEWEB)

    Kashai, L; Geineman, Z

    1965-12-01

    In this mathematical simulation of the in-situ combustion process, the effect is calculated of various parameters on the temperature distribution within the combustion zone. Among the parameters included in the mathematical analysis are (1) quantity of residual coke, oil, and oxidizer, (2) formation thickness, (3) heat conductivity and heat capacity of the formation, and (4) degree of rock heterogeneity. The problem is solved for the linear flow case with the use of a computer. Five temperatures profiles for various conditions are illustrated.

  18. Technical Proposal for Loading 3000 Gallon Crude Oil Samples from Field Terminal to Sandia Pressurized Tanker to Support US DOE/DOT Crude Oil Characterization Research Study

    Energy Technology Data Exchange (ETDEWEB)

    Lord, David; Allen, Raymond

    2016-10-01

    Sandia National Laboratories is seeking access to crude oil samples for a research project evaluating crude oil combustion properties in large-scale tests at Sandia National Laboratories in Albuquerque, NM. Samples must be collected from a source location and transported to Albuquerque in a tanker that complies with all applicable regulations for transportation of crude oil over public roadways. Moreover, the samples must not gain or lose any components, to include dissolved gases, from the point of loading through the time of combustion at the Sandia testing facility. In order to achieve this, Sandia designed and is currently procuring a custom tanker that utilizes water displacement in order to achieve these performance requirements. The water displacement procedure is modeled after the GPA 2174 standard “Obtaining Liquid Hydrocarbons Samples for Analysis by Gas Chromatography” (GPA 2014) that is used routinely by crude oil analytical laboratories for capturing and testing condensates and “live” crude oils, though it is practiced at the liter scale in most applications. The Sandia testing requires 3,000 gallons of crude. As such, the water displacement method will be upscaled and implemented in a custom tanker. This report describes the loading process for acquiring a ~3,000 gallon crude oil sample from commercial process piping containing single phase liquid crude oil at nominally 50-100 psig. This document contains a general description of the process (Section 2), detailed loading procedure (Section 3) and associated oil testing protocols (Section 4).

  19. Assessing the Potential of Utilization and Storage Strategies for Post-Combustion CO2 Emissions Reduction

    International Nuclear Information System (INIS)

    Armstrong, Katy; Styring, Peter

    2015-01-01

    The emissions reduction potential of three carbon dioxide handling strategies for post-combustion capture is considered. These are carbon capture and sequestration/storage (CCS), enhanced hydrocarbon recovery (EHR), and carbon dioxide utilization (CDU) to produce synthetic oil. This is performed using common and comparable boundary conditions including net CO 2 sequestered based on equivalent boundary conditions. This is achieved using a “cradle to grave approach” where the final destination and fate of any product is considered. The input boundary is pure CO 2 that has been produced using a post-combustion capture process as this is common between all processes. The output boundary is the emissions resulting from any product produced with the assumption that the majority of the oil will go to combustion processes. We also consider the “cradle to gate” approach where the ultimate fate of the oil is not considered as this is a boundary condition often applied to EHR processes. Results show that while CCS can make an impact on CO 2 emissions, CDU will have a comparable effect whilst generating income while EHR will ultimately increase net emissions. The global capacity for CDU is also compared against CCS using data based on current and planned CCS projects. Analysis shows that current CDU represent a greater volume of capture than CCS processes and that this gap is likely to remain well beyond 2020 which is the limit of the CCS projects in the database.

  20. Contained controlled burning of spilled oil during the Exxon Valdez oil spill

    International Nuclear Information System (INIS)

    Allen, A.A.

    1990-01-01

    During the evening of the second day following the Exxon Valdez oil spill, an estimated 57,000-114,000 liters of North Slope crude oil were eliminated using in-situ combustion. The oil was collected with 3M's Fire Boom towed in a U-shaped configuration behind two fishing boats. Working with 152 m long tow lines, a 137 m boom was moved at ca 0.26-5.2 m/s through slightly emulsified oil patches in the downwind region of the spill. A gelled fuel ignitor was used to ignite the captured oil, and the size and intensity of the blaze was controlled by adjusting the speed of the vessels. Total burn time was ca 1.25 h, however the intense part of the burn lasted for ca 45 minutes. Using several methods to estimate the total volume of oil collected, the volume resulted in ca 1136 liters of stiff, taffy-like burn residue that could be picked up easily on completion of the burn. The controlled burn thus resulted in an estimated 98% or better elimination of crude oil. It had been planned to use a helitorch to ignite the captured oil, however darkness required the use of the gelled ignitor. Had the helitorch been used, numerous ignition points could have been spread througout the contained oil, providing a much more efficient heating and ultimate ignition of the oil. 5 figs

  1. “... if there’s a party, then there’s definitely alcohol”. Construction of partying practices and abstinence in Estonian youth forums

    Directory of Open Access Journals (Sweden)

    Parder Mari-Liisa

    2015-12-01

    Full Text Available AIMS – Adolescents’ abstinence from alcohol has not been much researched in terms of providing suggestions for prevention strategies. This study aims to fill that gap by offering a practice theory-inspired analysis of how the unwritten rules of partying practices are communicated between posters of Estonian youth forums.

  2. A study of heterogeneous systems which retard the processes of motor oil aging. VI. The effect of the composition of the oil medium on its electric conductivity

    Energy Technology Data Exchange (ETDEWEB)

    Zhdanov, V V; Ashkinazi, L A; Chkalov, V A; Filanovskiy, B K; Grilikhes, M S; Nikolayenko, A V; Poray-Koshits, A B; Ravdel, A A

    1982-01-01

    A method of contact conductometry is used to study the effect of the composition of an oil medium on its electric conductivity and the factors to which this parameter is the most sensitive was determined. It is shown that the electric conductivity is a sensitive parameter, which reacts to a change in the water content in the oil, the length of operation in an internal combustion engine, to the volume of additives in the base oil and to the acid and base properties of the oil medium.

  3. In-situ burning of oil spills: Review and research properties

    International Nuclear Information System (INIS)

    Fingas, M.

    1992-01-01

    In-situ burning of oil spills has been tried over the past thirty years but has never been fully-accepted as an oil-spill cleanup option - largely because of the lack of understanding of the combustion products and the principles governing the combustibility of oil-on-water. Extensive research is currently underway to understand the many facets of burning oil. A consortium of over 15 agencies in the United States and Canada have joined forces to study burning and to conduct large scale experiments. This effort will result in data which should lead to broader acceptance of in-situ burning as an acceptable spill countermeasures alternative. Burning has distinct advantages over other counter-measures. First and foremost, it offers the potential to rapidly remove large quantities of oil. In-situ burning has the potential to remove as much oil in one day as several mechanical devices could in one month. Application of in-situ burning could prevent a large amount of shoreline contamination and damage to biota by removing oil before it spreads and moves to other areas. Secondly, in-situ burning requires minimal equipment and much less labor than any other technique. It can be applied in areas where other methods cannot be used because of distances and lack of infra-structure. Thirdly, burning of oil is a final solution compared to mechanical recovery. When oil is recovered mechanically it still has to be transported, stored and disposed of. Fourth and finally, burning may be the only option available in certain situations. Oil amongst ice and on ice are examples of situations where practical alternatives to burning do not exist. There are disadvantages to burning. The first and most visible disadvantage is the large black smoke plume that burning oil produces. The second disadvantage is that the oil must be a minimum thickness to burn

  4. Radioactivity concentration and heavy metal content in fuel oil and oil-ashes in Venezuela

    International Nuclear Information System (INIS)

    Barros, H.; Sajo-Bohus, L.; Abril, J.M.; Greaves, E.D.

    2004-01-01

    During the last years an intensive national program was developed to determine the environmental radioactivity levels in Venezuela. Gamma dose and the radon concentrations indoors, in drinking water, in caves and in artificial cavities including the effect of radon transported to the surface with the earth gas have been studied. To continue this project the oil and other natural energy resource should be considered. It is expected that the environmental radiation level is modified in regions where the oil industrial activity is more aggressive such as in the Zulia State and the Faja Petrolifera del Orinoco, (Central Region). In these regions Venezuela is producing 1.750 thousand barrels of oil from the near-to-the- surface or deep oil drilling. Petroleum constitutes an important source of energy and as the majority of natural source contains radionuclides and their disintegration products, being U, Ra, Pb, Bi, Po and K the most often encountered. The combustion of petroleum concentrate in the ashes those radioelements, and later enter the environment by different ways producing adverse effects on the quality of man life. The concentration of radioelements varies greatly between oil fields, then we still requiring local survey studies in this area. Moreover due to the recent national interest in recycling processes, it becomes important to take precaution in the selection of materials that may contain by-products of industrial origin, including oil. In fact the oil ashes, oil slurry and other mining by-products are thought to be employable in the building industry. The concentration of radioactivity in the ash from thermoelectric power plants that use petroleum as a primary energy source was determined. The analysis include the two major thermoelectric power plants in Venezuela, Ricardo Zuluaga on the northern sea side of Caracas and Planta Centro on the littoral of Carabobo State. The study cover different samples: fuel oil No 6, ashes, heavy and medium petroleum

  5. L'évolution des combustibles pour moteurs thermiques Evolution of Fuels for Thermal Engines

    Directory of Open Access Journals (Sweden)

    Balaceanu J. C.

    2006-11-01

    Full Text Available Depuis la crise pétrolière, l'accroissement des prix et les craintes de pénurie ont conduit à adapter les moteurs aux combustibles disponibles. Si la situation apparaît comme moins tendue, l'industrie des machines thermiques, qui pendant longtemps a eu comme partenaire une industrie du pétrole très sûre, se trouve cependant confrontée à un marché des combustibles incertain dans son ravitaillement et surtout dans ses prix. Les progrès des moteurs diesel et des turbines à gaz, dûs à une meilleure adaptation à leur usage et aussi à l'évolution de la technologie, supposent que les combustibles n'apporteront aucune contrainte majeure en quantité ou en qualité. La modification des usages dévolus désormais au pétrole entraînera une réduction de la coupe lourde et un raffinage plus profond des bruts avec en particulier un développement du craquage catalytique et de la viscoréduction. Or, ces différentes opérations de conversion peuvent conduire à une détérioration de la qualité des combustibles moins grave pour le gazole que pour le fuel lourd. Dans les différents domaines impliqués, les parades technologiques sont en cours de développement. L'industrie des machines thermiques, qui poursuit l'amélioration des engins, et l'industrie du pétrole, qui recherche une réduction des prix des combustibles, sont donc conduites à un compromis optimal auquel elles ne peuvent accéder efficacement qu'en définissant les règles du jeu c'est-à-dire des spécifications internationales rigoureuses des combustibles. Since the oil crisis, the increase in prices and fears of a shortage have led to the adapting of engines to what fuels are available. Whereas the situation now seems somewhat less tense, the thermal machinery industry, which for a long time had a very reliable petroleum industry as its partner, nonetheless finds itself confronted with an uncertain fuel market with regard to supplies and especially to prices. Progress

  6. Combustion

    CERN Document Server

    Glassman, Irvin

    1987-01-01

    Combustion, Second Edition focuses on the underlying principles of combustion and covers topics ranging from chemical thermodynamics and flame temperatures to chemical kinetics, detonation, ignition, and oxidation characteristics of fuels. Diffusion flames, flame phenomena in premixed combustible gases, and combustion of nonvolatile fuels are also discussed. This book consists of nine chapters and begins by introducing the reader to heats of reaction and formation, free energy and the equilibrium constants, and flame temperature calculations. The next chapter explores the rates of reactio

  7. The Low Load Limit of Gasoline Partially Premixed Combustion (PPC) - Experiments in a Light Duty Diesel Engine

    OpenAIRE

    Borgqvist, Patrick

    2013-01-01

    The decreasing oil supply, more stringent pollutant legislations and strong focus on decreasing carbon dioxide emissions drives the research of more efficient and clean combustion engines. One such combustion engine concept is Homogeneous Charge Compression Ignition (HCCI) which potentially achieves high efficiency and low NOx and soot emissions. One practical realization of HCCI in SI engines is to use a variable valve train to trap hot residual gases in order to increase the temperature of ...

  8. Characterization of diesel oil mixtures with soy oil used for activation of engines of internal combustion; Caracterizacao de misturas de oleo diesel com oleo de soja reutilizado para acionamento de motores de combustao interna

    Energy Technology Data Exchange (ETDEWEB)

    Siqueira, Wagner da Cunha; Fernandes, Haroldo Carlos; Teixiera, Mauri Martins; Abrahao, Selma Alves; Leite, Daniel Mariano [Universidade de Vicosa, (DEA/UFV), MG (Brazil). Dept. de Engenharia Agricola], Emails: wagner.siqueira@ufv.br, haroldo@ufv.br, mauri@ufv.br, selma.abrahao@ufv.br, daniel.mariano@ufv.br

    2011-07-01

    Alternative energy sources have been studied in several countries, with emphasis on ways of obtaining and using more efficient. The objective of this work to evaluate and characterize mixtures of diesel oil (DO) with soybean oil reused (OSR), the ratios of 0, 25, 50, 75, and 100% of OSR in relation to specific gravity index viscosity and calorific value. To determine the specific gravity was used beaker, thermometer and a balance for each mixture was adjusted a regression model to estimate the bulk density as a function of temperature (25 to 90 deg C). We analyzed the viscosity of the mixtures using an orifice-type viscometer Saybolt, through regression analysis models were fit to estimate the viscosity as a function of temperature, heating the OSR 100% from 40 to 90 deg C decreased by up 90.4% to its viscosity. The tests were performed calorimetric using a bomb calorimeter determines the calorific value , the variation in calorific value followed a descending order with respect to OD with the increasing content of OSR. The OSR is efficient for use in internal combustion engines in small proportions. (author)

  9. Taxes, Estonian state budget and economic crises. Maksud, riigi eelarve ja majanduskriis

    Directory of Open Access Journals (Sweden)

    Olev Raju

    2013-01-01

    Full Text Available Recession has sharply erected the question of tax burden and the optimal proportion of different kinds of taxes among the incomes of the budget. Indirect taxes and consumption taxes, which proportion is different according to different methodologies, dominate in Estonian state budget. The buoyancy of a tax system based on taxes of that kind is especially weak during the recession. Difficulties concerning the incomes of budget have arisen the necessity for lifting taxes, which is possible as the tax burden is low now. But a sharp question of the optimal level of taxes is going to be raised. A formula for indirect tax optimum according to Ramsey taxes and Slutski decomposition has been proposed in the article.

  10. Attitudes of Academic Staff towards Their Own Work and towards External Evaluation, from the Perspective of Self-Determination Theory: Estonian Case

    Science.gov (United States)

    Seema, Riin; Udam, Maiki; Mattisen, Heli

    2016-01-01

    The purpose of this study was to ascertain the attitudes of academic staff towards their own work as well as towards external evaluations. The study was based on (1) an analysis of assessment reports of institutional accreditations conducted by the Estonian Quality Agency for Higher and Vocational Education and (2) self-determination theory on…

  11. Pulsating combustion - Combustion characteristics and reduction of emissions

    Energy Technology Data Exchange (ETDEWEB)

    Lindholm, Annika

    1999-11-01

    In the search for high efficiency combustion systems pulsating combustion has been identified as one of the technologies that potentially can meet the objectives of clean combustion and good fuel economy. Pulsating combustion offers low emissions of pollutants, high heat transfer and efficient combustion. Although it is an old technology, the interest in pulsating combustion has been renewed in recent years, due to its unique features. Various applications of pulsating combustion can be found, mainly as drying and heating devices, of which the latter also have had commercial success. It is, however, in the design process of a pulse combustor, difficult to predict the operating frequency, the heat release etc., due to the lack of a well founded theory of the phenomenon. Research concerning control over the combustion process is essential for developing high efficiency pulse combustors with low emissions. Natural gas fired Helmholtz type pulse combustors have been the experimental objects of this study. In order to investigate the interaction between the fluid dynamics and the chemistry in pulse combustors, laser based measuring techniques as well as other conventional measuring techniques have been used. The experimental results shows the possibilities to control the combustion characteristics of pulsating combustion. It is shown that the time scales in the large vortices created at the inlet to the combustion chamber are very important for the operation of the pulse combustor. By increasing/decreasing the time scale for the large scale mixing the timing of the heat release is changed and the operating characteristics of the pulse combustor changes. Three different means for NO{sub x} reduction in Helmholtz type pulse combustors have been investigated. These include exhaust gas recirculation, alteration of air/fuel ratio and changed inlet geometry in the combustion chamber. All used methods achieved less than 10 ppm NO{sub x} emitted (referred to stoichiometric

  12. Investigation of Multiscale and Multiphase Flow, Transport and Reaction in Heavy Oil Recovery Processes

    Energy Technology Data Exchange (ETDEWEB)

    Yortsos, Yanis C.

    2002-10-08

    In this report, the thrust areas include the following: Internal drives, vapor-liquid flows, combustion and reaction processes, fluid displacements and the effect of instabilities and heterogeneities and the flow of fluids with yield stress. These find respective applications in foamy oils, the evolution of dissolved gas, internal steam drives, the mechanics of concurrent and countercurrent vapor-liquid flows, associated with thermal methods and steam injection, such as SAGD, the in-situ combustion, the upscaling of displacements in heterogeneous media and the flow of foams, Bingham plastics and heavy oils in porous media and the development of wormholes during cold production.

  13. Numerical studies of spray combustion processes of palm oil biodiesel and diesel fuels using reduced chemical kinetic mechanisms

    KAUST Repository

    Kuti, Olawole

    2014-04-01

    Spray combustion processes of palm oil biodiesel (PO) and conventional diesel fuels were simulated using the CONVERGE CFD code. Thermochemical and reaction kinetic data (115 species and 460 reactions) by Luo et al. (2012) and Lu et al. (2009) (68 species and 283 reactions) were implemented in the CONVERGE CFD to simulate the spray and combustion processes of the two fuels. Tetradecane (C14H30) and n- heptane (C7H 16) were used as surrogates for diesel. For the palm biodiesel, the mixture of methyl decanoate (C11H20O2), methyl-9-decenoate (C11H19O2) and n-heptane was used as surrogate. The palm biodiesel surrogates were combined in proportions based on the previous GC-MS results for the five major biodiesel components namely methyl palmitate, methyl stearate, methyl oleate, methyl linoleate and methyl linolenate. The Favre-Averaged Navier Stokes based simulation using the renormalization group (RNG) k-ε turbulent model was implemented in the numerical calculations of the spray formation processes while the SAGE chemical kinetic solver is used for the detailed kinetic modeling. The SAGE chemical kinetic solver is directly coupled with the gas phase calculations by renormalization group (RNG) k-ε turbulent model using a well-stirred reactor model. Validations of the spray liquid length, ignition delay and flame lift-off length data were performed against previous experimental results. The simulated liquid length, ignition delay and flame lift-off length were validated at an ambient density of 15kg/m3, and injection pressure conditions of 100, 200 and 300 MPa were utilized. The predicted liquid length, ignition delay and flame lift-off length agree with the trends obtained in the experimental data at all injection conditions. Copyright © 2014 SAE International.

  14. Feasibility study of utilizing jatropha curcas oil as bio-diesel in an oil firing burner system

    Science.gov (United States)

    Shaiful, A. I. M.; Jaafar, M. N. Mohd; Sahar, A. M.

    2017-09-01

    Jatropha oil derived from the Jatropha Curcas Linnaeus is one of the high potential plants to be use as bio-diesel. The purpose of this research is to carry out a feasibility study of using jatropha oil as bio-diesel on oil firing burner system. Like other bio-diesels, jatropha oil can also be used in any combustion engine and the performance and emissions such as NOx, SO2, CO and CO2 as well as unburned hydocarbon (UHC) from the engine will vary depending on the bio-diesel blends. The properties of Conventional Diesel Fuel (CDF) obtained will be used as baseline and the jatropha oil properties will be compared as well as other bio-diesels. From several researches, the properties of jatropha oil was found to be quite similar with other bio-diesel such as palm oil, neem, keranja and pongamia bio-diesel and complying with the ASTM standard for bio-diesel. Still, there are factors and issues concerning the use of jatropha oil such as technology, economy, legislation and resource. Plus, there several challenges to the growth of bio-diesel industry development since the world right now do not totally depend on the bio-diesel.

  15. Feasibility study of incineration treatment of radioactive waste oil

    International Nuclear Information System (INIS)

    Wang Peiyi; Zhou Lianquan; Ma Mingxie; Yang Liguo; Li Xiaohai; Qiu Mingcai; Zhang Xiaobin; Dong Jingling; Yang Baomin

    2001-01-01

    The author describes the combustion experiment of radioactive waste oil, including determination of the basic properties of the waste oils, pretreatment and incineration experiment. As for low flash point oil possibly mixed with gasoline, it is recommended to add kerosine to lower the viscosity. Spray incineration experiment shows that for waste oil with viscosity less than 30 mPa·s, it can be completely burnt even if the heat strength in the stove is less than 1.6 x 10 6 kJ/(m 3 ·h). Within a broad range of extra-air coefficient, CO concentration in flue gas is below 0.1%

  16. Les méthodes thermiques de production des hydrocarbures. Chapitre 5 : Combustion "in situ". Pricipes et études de laboratoire Thermal Methods of Hydrocarbon Production. Chapter 5 : "In Situ" Combustion. Principles and Laboratory Research

    Directory of Open Access Journals (Sweden)

    Burger J.

    2006-11-01

    Full Text Available II existe plusieurs variantes de la combustion in situ, suivant le sens de déplacement du front de combustion, à co-courant ou à contre-courant, et suivant la nature des fluides injectés, air seul ou injection combinée d'air et d'eau. Les réactions de pyrolyse, d'oxydation et de combustion mises en jeu par ces techniques sont discutées, en particulier la cinétique des principaux mécanismes réactionnels, l'importance du dépôt de coke et l'exothermicité des réactions d'oxydation et de combustion. Les résultats d'essais de déplacement unidirectionnel du front de combustion dans des cellules de laboratoire sont présentés et discutés. Enfin on indique les conditions pratiques d'application des méthodes de combustion in situ sur champ. Possible variations of in situ combustion technique ore as follows : forward or reverse combustion depending on the relative directions of the air flow and the combustion front, dry combustion if air is the only fluid injected into the oil-bearing formation, or fixe/woter flooding if water is injected along with air. The chemical reactions of pyrolysis, oxidation and combustion involved in these processes are described. The kinetics of these reactions is discussed as well as fuel availability in forward combustion and the exothermicity of the oxidation and combustion reactions. The results obtained in the laboratory when a combustion front propagates in unidirectional adiabatic tells are described and discussed. This type of experimentation provides extensive information on the characteristics of the processes. Screening criteria for the practical application of in situ combustion techniques are presented.

  17. Combustion of Drops and Sprays of Heavy Fuel Oils and Their Emulsions.

    Science.gov (United States)

    1980-12-01

    Variation of the Flame Length of Drop with Time (Pure No. 4 Oil) ...... ..................... .... 154 15. Variation of the Flame Length of Drop with Time...No. 4 Oil-Water Emulsion, W = 0.08) ............. .... 155 16. Variation of the Flame Length of Drop with Time (No. 4 Oil-Water Emulsion, W = 0.15...detailed study of the effects of preheating the fuel, atomizing air-flow rate, and fuel flow 10 rate on flame properties such as flame length , radiation

  18. Molecular hydrogen (H2) combustion emissions and their isotope (D/H) signatures from domestic heaters, diesel vehicle engines, waste incinerator plants, and biomass burning

    NARCIS (Netherlands)

    Vollmer, M.K.; Walter, S.; Mohn, J.; Steinbacher, M.; Bond, S.W.; Röckmann, T.; Reimann, S.

    2012-01-01

    Molecular hydrogen (H2), its stable isotope signature ( D), and the key combustion parameters carbon monoxide (CO), carbon dioxide (CO2), and methane (CH4) were measured from various combustion processes. H2 in the exhaust of gas and oil-fired heaters and of waste incinerator plants was generally

  19. Assessing the Potential of Utilization and Storage Strategies for Post-Combustion CO{sub 2} Emissions Reduction

    Energy Technology Data Exchange (ETDEWEB)

    Armstrong, Katy; Styring, Peter, E-mail: p.styring@sheffield.ac.uk [UK Centre for Carbon Dioxide Utilization, Department of Chemical and Biological Engineering, The University of Sheffield, Sheffield (United Kingdom)

    2015-03-03

    The emissions reduction potential of three carbon dioxide handling strategies for post-combustion capture is considered. These are carbon capture and sequestration/storage (CCS), enhanced hydrocarbon recovery (EHR), and carbon dioxide utilization (CDU) to produce synthetic oil. This is performed using common and comparable boundary conditions including net CO{sub 2} sequestered based on equivalent boundary conditions. This is achieved using a “cradle to grave approach” where the final destination and fate of any product is considered. The input boundary is pure CO{sub 2} that has been produced using a post-combustion capture process as this is common between all processes. The output boundary is the emissions resulting from any product produced with the assumption that the majority of the oil will go to combustion processes. We also consider the “cradle to gate” approach where the ultimate fate of the oil is not considered as this is a boundary condition often applied to EHR processes. Results show that while CCS can make an impact on CO{sub 2} emissions, CDU will have a comparable effect whilst generating income while EHR will ultimately increase net emissions. The global capacity for CDU is also compared against CCS using data based on current and planned CCS projects. Analysis shows that current CDU represent a greater volume of capture than CCS processes and that this gap is likely to remain well beyond 2020 which is the limit of the CCS projects in the database.

  20. Experimental investigation and performance evaluation of DI diesel engine fueled by waste oil-diesel mixture in emulsion with water

    Directory of Open Access Journals (Sweden)

    Nanthagopal Kasianantham

    2009-01-01

    Full Text Available Exploitation of the natural reserves of petroleum products has put a tremendous onus on the automotive industry. Increasing pollution levels and the depletion of the petroleum reserves have lead to the search for alternate fuel sources for internal combustion engines. Usage of vegetable oils poses some challenges like poor spray penetration, valve sticking and clogging of injector nozzles. Most of these problems may be solved by partial substitution of diesel with vegetable oil. In this work, the performance and emission characteristics of a direct injection diesel engine fueled by waste cooking oil-diesel emulsion with different water contents are evaluated. The use of waste cooking oil-diesel emulsion lowers the peak temperature, which reduces the formation of NOx. Moreover the phenomenon of micro explosion that results during the combustion of an emulsified fuel finely atomizes the fuel droplets and thus enhances combustion. Experiments show that CO concentration is reduced as the water content is increased and it is seen that 20% water content gives optimum results. Also, there is a significant reduction in NOx emissions.

  1. Indoor Spatial Monitoring of Combustion Generated Pollutants (TSP, CO, and BaP) by Indian Cookstoves

    Science.gov (United States)

    1988-07-01

    whereas Ariyur has a strata of economic conditions. Fuel is both bought and gathered. Most southern cooks use logs of Casurina, and coconut husks and...per unit of energy than combustion of oil and most coals Morris, 1982, Cooper, 1980. Recent literature on woodsmoke have been documented by Cooper...Group on Energy Po]icy, Planning Commission, Govt. of India, New Delhi, 1979) lists firewood as the major source of fuel (68.5%) oil products (16.9

  2. Application of the High Temperature Gas Cooled Reactor to oil shale recovery

    International Nuclear Information System (INIS)

    Wadekamper, D.C.; Arcilla, N.T.; Impellezzeri, J.R.; Taylor, I.N.

    1983-01-01

    Current oil shale recovery processes combust some portion of the products to provide energy for the recovery process. In an attempt to maximize the petroleum products produced during recovery, the potentials for substituting nuclear process heat for energy generated by combustion of petroleum were evaluated. Twelve oil shale recovery processes were reviewed and their potentials for application of nuclear process heat assessed. The High Temperature Gas Cooled Reactor-Reformer/Thermochemical Pipeline (HTGR-R/TCP) was selected for interfacing process heat technology with selected oil shale recovery processes. Utilization of these coupling concepts increases the shale oil product output of a conventional recovery facility from 6 to 30 percent with the same raw shale feed rate. An additional benefit of the HTGR-R/TCP system was up to an 80 percent decrease in emission levels. A detailed coupling design for a typical counter gravity feed indirect heated retorting and upgrading process were described. Economic comparisons prepared by Bechtel Group Incorporated for both the conventional and HTGR-R/TCP recovery facility were summarized

  3. Oil shale activities in China

    International Nuclear Information System (INIS)

    Peng, D.; Jialin, Q.

    1991-01-01

    China has abundant oil shale resources, of the Early Silurian to Neogene age, the most important being the Tertiary period. The proved oil shale reserves in Fushun amount to 3.6 billion t, in Maoming 4.1 billion t. In Fushun, oil shale is produced by open-pit mining as a byproduct of coal, in Maoming it is also mined in open pits, but without coal. In China, scale oil has been produced from oil shale for 60 years. Annual production of crude shale oil amounts to about 200 000 t. The production costs of shale oil are lower than the price of crude petroleum on the world market. China has accumulated the experience and technologies of oil shale retorting. The Fushun type retort has been elaborated, in which the latent and sensible heat of shale coke is well utilized. But the capacity of such retort is relatively small, therefore it is suitable for use in small or medium oil plants. China has a policy of steadily developing shale oil industry. China is conducting oil shale research and developing oil shale processing technology. Much attention is being pay ed to the comprehensive utilization of oil shale, shale oil, and to environmental problems. In China, oil shale is mostly used for producing shale by retorting, attention will also be paid to direct combustion for power generation. Great achievements in oil shale research have been made in the eighties, and there will be a further development in the nineties. (author), 12 refs., 3 tabs

  4. Characterization of combustion chamber products by core-level photoabsorption spectroscopy

    International Nuclear Information System (INIS)

    Kellar, S.A.; Huff, W.R.A.; Moler, E.J.

    1997-01-01

    The lubricating performance of motor oil is adversely affected by the carbon soot contamination that is a natural by-product of the combustion process. Particularly in diesel engines, open-quote blow-by close-quote is a problem that greatly decreases the longevity of the engine-lubricating oil. Motor oil manufacturers spend considerable resources developing new oil formulations that counteract the adverse affects of this combustion soot. At present, the only effective way to test new formulations is in a working engine. This process is obviously expensive and not especially efficient. In this ongoing work in collaboration with Chevron Research and Technology, the authors goal is to find a form of carbon that chemically resembles the soot created by the open-quote blow-by close-quote in a diesel engine. The chemically correct soot substitute can be used in bench tests to replace the expensive full motor testing for new formulations. The final testing would still be done in the test motors but only with promising candidates. To these ends, Near Edge X-ray Adsorption spectroscopy Extended Fine Structure (NEXAFS) is an attractive technique in that it has chemical specificity through the core-level binding energy and because it probes the chemically important unoccupied molecular orbitals of the material. Core-level photoabsorption has been used to characterize the empty electronic states of a wide variety of materials. Specifically, the near-edge region of the photoabsorption process has been used to determine the relative quantity of sp 2 and sp 3 bonding in carbon films. The samples were fine grained powders pressed into pellets. The C(1s) absorption spectra were collected from each sample by measuring the total electron yield from the sample as a function of photon energy. The absorption intensity was normalized to the incoming photon flux by measuring the photoyield from a fine gold mesh

  5. Effect of Binder on Combustion Quality on EFB Bio-briquettes

    Science.gov (United States)

    Handra, Nofriady; Hafni

    2017-12-01

    Energy demand in various sectors in Indonesia has increased in line with the rate of population growth and the national economy. Fulfillment of energy needs can be obtained from various energy sources such as fuel oil, solar, biomass, wind, water and others. So far, energy sources used in Indonesia are still using many non-renewable energy sources, such as fuel oil. The utilization of waste from empty palm oil bunches into bio-briquettes has helped the government in overcoming the problem of EFB waste. The availability of biomass has prompted researchers to utilize biomass waste that includes Agricultural and Forestry waste, to be processed into briquettes as an alternative energy substitute for fuel oil. This research aims to improve the utilization of waste of Palm Oil Bunches through the manufacture of bio-briquette as alternative fuel and determine the appropriate binder material for briquette making so as to produce optimal combustion value. The binders used for the manufacture of briquettes are pine sap and starch flour. The test result showed that the highest value of calorific was found in the mixture of 50% EFB composition with fibre size ± 1-5 mm with 50% pine resin which is 6331,7 cal/g. Meanwhile, lowest value on EFB ± with fibre size 5-10 mm composition EFB 60% and 40% starch flour binder that is 2295,7 cal/g. The results of a flame test study of several points that are known to turn on until it emits a flame for ± 30 seconds, it takes 22,2 minutes for the burnt-out briquette (to ashes). Based on visual observations that the fire colour of bio-briquette with finer fibre on the EFB composition 50% pine gum binder produces a bluish red fire colour. It is generally assumed that pine resin glues produce better fuel value compared to starch binder. Besides that, fibre particles size also affects the combustion quality produced.

  6. Proceedings of the World Heavy Oil Congress : unconventional oil challenging conventional expectations

    International Nuclear Information System (INIS)

    2008-01-01

    This international technical and business conference provided a forum to promote heavy oil technology and foster relationships between supply and demand countries. The interactive forum between global industry professionals addressed technological, strategic and environmental challenges facing the unconventional oil industry, including seeking innovative, low cost technologies, driving high costs down; educating and leading the workforce to maintain high standards of production; and ensuring that the footprint on the land is as light as possible. It emphasized that as demand for the uses of heavy oil grows, so does the responsibility of managing sustainability not just from an environmental and social perspective, but also with respect to supply, including manpower and infrastructure. The technical conference featured sessions on advanced and enhanced processes; combustion processes; drilling and completions; geology and reservoir; heavy oil exploitation and development; mining, extraction and transportation; non thermal processes; production and operations; reservoir monitoring; SAGD processes; sustainable development; thermal processes; and, upgrading technology. All 124 presentations from the technical conference were catalogued separately for inclusion in this database. refs., tabs., figs

  7. The figure of the teacher in Estonian school discourse

    Directory of Open Access Journals (Sweden)

    Ott Puumeister

    2014-10-01

    Full Text Available The article concerns itself with the figure of the teacher in Estonian society. We do not concentrate on the educational system as a whole, but on one specific and crucial element in this apparatus - the teacher. We begin by offering a brief historical overview of the conditions of pedagogues in the 20th century before moving on to describe the adoption of neo-liberal free market policies since the 1990s and the effects these policies had and still have on education. Our main concern is to understand the teacher as an actor in power relations; to achieve this understanding we have selected as our examples 1 surveillance techniques in school environment that have direct relations to the state and the market; and 2 the 2012 educational workers' strike that made it quite clear that the teachers have been fixed to a position of wage workers. The overall and more abstract aim of the paper is to think about the social role of the teacher in Estonia.

  8. Oils

    Energy Technology Data Exchange (ETDEWEB)

    Cobbett, G T.B.

    1907-07-08

    Crude petroleum having a density of 850 to 900 is purified with sulfuric acid, decanted, mixed with benzine or petrol, and again treated with sulfuric acid and decanted. The remaining acid and coloring-matter are removed by washing with water, or treating with oxalic acid, zinc carbonate, lead carbonate, calcium carbonate, or oxide of zinc. The product is used as a fuel for internal-combustion engines. Specifications No. 28,104, A.D. 1906, and No. 12,606, A.D. 1907, are referred to. According to the Provisional Specification, the process is applicable to shale or schist oil.

  9. On possibilities to decrease influence of oxidation processes on oil yield at oil shale retorting

    International Nuclear Information System (INIS)

    Yefimov, V.; Loeoeper, R.; Doilov, S.; Kundel, H.

    1993-01-01

    At the present technical level retorting is carried out so that an increase in specific air consumption results in an increase of oxygen ingress into the semi coking shaft. At the same time a direct relationship between the degree of volatiles pyrolysis and specific air consumption was observed. This regularity enables to assume that within the reaction volume there occurs most likely the thermo oxidative pyrolysis of volatile products, not the oxidation of oil shale as it is considered traditionally. The main source of oxygen ingress ed into the semi coking shaft at processing oil shale in retorts is the process of spent shale. This process is not fully elaborated for utilization in commercial scale and can not be arranged so that the ingress of oxygen into the smacking chamber could be eliminated. In case of a slower semi coke gasification process and reduced specific air consumption for gasification the absolute amount of oxygen ingress ed into the semi coking shaft also decreases. One of the efficient methods to decrease specific air consumption is to build furnaces into the semi coking chamber to obtain additional amount of heat carrier by combusting generator gas. The maximum effect is reached when steam-and-air blow is completely replaced by recycle gas: specific air consumption is reduced whereas recycle gas is deoxygenated in the cooling zone while passing through spent shale bed which has the temperature of about 500 deg C. Another possible source of oxygen to the semi coking shaft with heat carrier is production of flue gases by combusting recycle gas in burners built in retorts. We consider the recycle gas employed upon processing oil shale in retorts hardly to be an appreciable source of the oxygen ingress into the semi coking shaft. Additional amounts of residual oxygen containing in recycle gas fed into both cooling zone and furnaces are practically totally consumed at gas combusting and passing across the bed of semi coke heated up to approximately

  10. Experimental studies on the combustion characteristics and performance of a direct injection engine fueled with biodiesel/diesel blends

    International Nuclear Information System (INIS)

    Qi, D.H.; Chen, H.; Geng, L.M.; Bian, Y. ZH.

    2010-01-01

    Biodiesel is an alternative diesel fuel that can be produced from different kinds of vegetable oils. It is an oxygenated, non-toxic, sulphur-free, biodegradable, and renewable fuel and can be used in diesel engines without significant modification. However, the performance, emissions and combustion characteristics will be different for the same biodiesel used in different types of engine. In this study, the biodiesel produced from soybean crude oil was prepared by a method of alkaline-catalyzed transesterification. The effects of biodiesel addition to diesel fuel on the performance, emissions and combustion characteristics of a naturally aspirated DI compression ignition engine were examined. Biodiesel has different properties from diesel fuel. A minor increase in brake specific fuel consumption (BSFC) and decrease in brake thermal efficiency (BTE) for biodiesel and its blends were observed compared with diesel fuel. The significant improvement in reduction of carbon monoxide (CO) and smoke were found for biodiesel and its blends at high engine loads. Hydrocarbon (HC) had no evident variation for all tested fuels. Nitrogen oxides (NOx) were slightly higher for biodiesel and its blends. Biodiesel and its blends exhibited similar combustion stages to diesel fuel. The use of transesterified soybean crude oil can be partially substituted for the diesel fuel at most operating conditions in terms of the performance parameters and emissions without any engine modification.

  11. Process of distillation of oil shale

    Energy Technology Data Exchange (ETDEWEB)

    Saxton, A L

    1968-08-16

    In an oil-shale distillation apparatus with a single retort, in which separate zones of preheating, distillation, combustion, and cooling are maintained, the operation is conducted at a presssure higher than the atmospheric pressure, preferably at a gage pressure between about 0.35 and 7.0 bars. This permits increasing the capacity of the installation.

  12. Combustible structural composites and methods of forming combustible structural composites

    Science.gov (United States)

    Daniels, Michael A.; Heaps, Ronald J.; Steffler, Eric D.; Swank, W. David

    2013-04-02

    Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.

  13. HEAVY AND THERMAL OIL RECOVERY PRODUCTION MECHANISMS

    Energy Technology Data Exchange (ETDEWEB)

    Anthony R. Kovscek; Louis M. Castanier

    2002-09-30

    The Stanford University Petroleum Research Institute (SUPRI-A) conducts a broad spectrum of research intended to help improve the recovery efficiency from difficult to produce reservoirs including heavy oil and fractured low permeability systems. Our scope of work is relevant across near-, mid-, and long-term time frames. The primary functions of the group are to conduct direction-setting research, transfer research results to industry, and educate and train students for careers in industry. Presently, research in SUPRI-A is divided into 5 main project areas. These projects and their goals include: (1) Multiphase flow and rock properties--to develop better understanding of the physics of displacement in porous media through experiment and theory. This category includes work on imbibition, flow in fractured media, and the effect of temperature on relative permeability and capillary pressure. (2) Hot fluid injection--to improve the application of nonconventional wells for enhanced oil recovery and elucidate the mechanisms of steamdrive in low permeability, fractured porous media. (3) Mechanisms of primary heavy oil recovery--to develop a mechanistic understanding of so-called ''foamy oil'' and its associated physical chemistry. (4) In-situ combustion--to evaluate the effect of different reservoir parameters on the insitu combustion process. (5) Reservoir definition--to develop and improve techniques for evaluating formation properties from production information. What follows is a report on activities for the past year. Significant progress was made in all areas.

  14. Bio-oil production from cotton stalk

    International Nuclear Information System (INIS)

    Zheng Jilu; Yi Weiming; Wang Nana

    2008-01-01

    Cotton stalk was fast pyrolyzed at temperatures between 480 deg. C and 530 deg. C in a fluidized bed, and the main product of bio-oil is obtained. The experimental result shows that the highest bio-oil yield of 55 wt% was obtained at 510 deg. C for cotton stalk. The chemical composition of the bio-oil acquired was analyzed by GC-MS, and its heat value, stability, miscibility and corrosion characteristics were determined. These results showed that the bio-oil obtained can be directly used as a fuel oil for combustion in a boiler or a furnace without any upgrading. Alternatively, the fuel can be refined to be used by vehicles. Furthermore, the energy performance of the pyrolysis process was analyzed. In the pyrolysis system used in our experiment, some improvements to former pyrolysis systems are done. Two screw feeders were used to prevent jamming the feeding system, and the condenser is equipped with some nozzles and a heat exchanger to cool quickly the cleaned hot gas into bio-oil

  15. Heating great residential units with combustion-motor heat pumps

    Energy Technology Data Exchange (ETDEWEB)

    Vossen, W

    1982-10-01

    Economic usage of combustion-motor heat pumps requires: reliable technology and delivery of the heat pump; design and operation. The heat pump must be integrated perfectly into the heating system. This contributions is based on a three-year operational experience with over 150 heat pumps used mainly in residential and administrative buildings (plus commercial buildings, swimming pools, sport centres etc.). These are heat pumps operating on the compression principle with natural gas, liquid gas, or fuel oil.

  16. Gas Chromatographic Determination of Fatty Acids in Oils with Regard to the Assessment of Fire Hazard

    Science.gov (United States)

    Bartošová, Alica; Štefko, Tomáš

    2017-06-01

    The aim of the paper was to study and research the application of processing gas chromatographic method for the rapid and accurate determination of the composition of different types of oils, such as substances with the possibility of an adverse event spontaneous combustion or self-heating. Tendency to spontaneous combustion is chemically characterized mainly by the amount of unsaturated fatty acids, which have one or more double bonds in their molecule. Vegetable oils essentially consist of the following fatty acids: palmitic, stearic, oleic, linoleic, and linoleic. For the needs of assessment, the fire hazard must be known, in which the double bond is present, as well as their number in a molecule. As an analytical method, GCMS was used for determination of oils content. Three types of oil were used - rapeseed, sunflower, and coconut oil. Owing to the occurrence of linoleic acid C18:2 (49.8 wt.%) and oleic acid C18:1 (43.3 wt.%) with double bonds, sunflower oil is the most prone to self-heating. The coconut and rapeseed oils contain double bond FAME in lesser amount, and their propensity to self-heating is relatively low.

  17. Smoking prevalence and attitudes towards smoking among Estonian physicians: results from cross-sectional studies in 2002 and 2014

    OpenAIRE

    Põld, Mariliis; Pärna, Kersti

    2017-01-01

    Objectives To explore smoking prevalence and attitudes towards smoking among Estonian physicians in 2002 and 2014. Design Two self-administered cross-sectional postal surveys were conducted among practising physicians in Estonia. Participants Initial sample consisted of all practising physicians in Estonia. The corrected response rate was 67.8% in 2002 and 53.1% in 2014. Present study sample was restricted to physicians younger than 65 years (n=2549 in 2002, n=2339 in 2014). Methods Age-stand...

  18. Carbon flow analysis and Carbon emission reduction of FCC in Chinese oil refineries

    Science.gov (United States)

    Jia, Fengrui; Wei, Na; Ma, Danzhu; Liu, Guangxin; Wu, Ming; Yue, Qiang

    2017-08-01

    The major problem of the energy production in oil refineries is the high emission of CO2 in China. The fluid catalytic cracking unit (FCC) is the key source of carbon emission in the oil refineries. According to the statistical data, the carbon emission of FCC unit accounts for more than 31% for the typical oil refineries. The carbon flow of FCC in the typical Chinese oil refineries were evaluated and analysed, which aimed at the solution of CO2 emission reduction. The method of substances flow analysis (SFA) and the mathematical programming were used to evaluate the carbon metabolism and optimize the carbon emission. The results indicated that the combustion emission of the reaction-regeneration subsystem (RRS) was the major source of FCC. The quantity of CO2 emission of RSS was more than 90%. The combustion efficiency and the amount of residual oil affected the carbon emission of RRS most according to the optimized analysis of carbon emission reduction. Moreover, the fractionation subsystem (TFS) had the highest environmental efficiency and the absorption-stabilization subsystem (ASS) had the highest resource efficiency (approximately to 1) of carbon.

  19. Regeneration of used lubricating oil as a source of energy

    Directory of Open Access Journals (Sweden)

    A. T. Abdulrahim

    2001-10-01

    Full Text Available Conservation of natural resources by refining used lubricating oil was attempted in this work. Used lubricating oil was purified and distilled. The distillates obtained were divided into two temperature ranges of 60 - 210°C and 210 - 310°C. Analyses of the physicochemical properties of the two samples revealed that they have similar properties with gasoline and diesel fuels respectively. This result shows that used lubricating oils, which are usually regarded as waste, can be regenerated to obtain useful hydrocarbons that can be used as fuels to power internal combustion engines

  20. Combustion Stratification for Naphtha from CI Combustion to PPC

    KAUST Repository

    Vallinayagam, R.

    2017-03-28

    This study demonstrates the combustion stratification from conventional compression ignition (CI) combustion to partially premixed combustion (PPC). Experiments are performed in an optical CI engine at a speed of 1200 rpm for diesel and naphtha (RON = 46). The motored pressure at TDC is maintained at 35 bar and fuelMEP is kept constant at 5.1 bar to account for the difference in fuel properties between naphtha and diesel. Single injection strategy is employed and the fuel is injected at a pressure of 800 bar. Photron FASTCAM SA4 that captures in-cylinder combustion at the rate of 10000 frames per second is employed. The captured high speed video is processed to study the combustion homogeneity based on an algorithm reported in previous studies. Starting from late fuel injection timings, combustion stratification is investigated by advancing the fuel injection timings. For late start of injection (SOI), a direct link between SOI and combustion phasing is noticed. At early SOI, combustion phasing depends on both intake air temperature and SOI. In order to match the combustion phasing (CA50) of diesel, the intake air temperature is increased to 90°C for naphtha. The combustion stratification from CI to PPC is also investigated for various level of dilution by displacing oxygen with nitrogen in the intake. The start of combustion (SOC) was delayed with the increase in dilution and to compensate for this, the intake air temperature is increased. The mixture homogeneity is enhanced for higher dilution due to longer ignition delay. The results show that high speed image is initially blue and then turned yellow, indicating soot formation and oxidation. The luminosity of combustion images decreases with early SOI and increased dilution. The images are processed to generate the level of stratification based on the image intensity. The level of stratification is same for diesel and naphtha at various SOI. When O concentration in the intake is decreased to 17.7% and 14

  1. Heavy and Thermal Oil Recovery Production Mechanisms, SUPRI TR-127

    Energy Technology Data Exchange (ETDEWEB)

    Kovscek, Anthony R.; Brigham, William E.; Castanier, Louis M.

    2001-09-07

    The program spans a spectrum of topics and is divided into five categories: (i) multiphase flow and rock properties, (ii) hot fluid injection, (iii) primary heavy-oil production, (iv) reservoir definition, and (v) in-situ combustion.

  2. Black and brown carbon fractal aggregates from combustion of two fuels widely used in Asian rituals

    International Nuclear Information System (INIS)

    Chakrabarty, Rajan K.; Arnold, Ian J.; Francisco, Dianna M.; Hatchett, Benjamin; Hosseinpour, Farnaz; Loria, Marcela; Pokharel, Ashok; Woody, Brian M.

    2013-01-01

    Incense sticks and mustard oil are the two most popular combustion fuels during rituals and social ceremonies in Asian countries. Given their widespread use in both closed and open burning activities, it is important to quantify the spectral radiative properties of aerosols emitted from the combustion of both fuels. This information is needed by climate models to assess the impact of these aerosols on radiative forcing. In this study, we used a 3-wavelength integrated photoacoustic-nephelometer – operating simultaneously at 405, 532 and 781 nm – to measure the optical coefficients of aerosols emitted from the laboratory combustion of mustard oil lamp and two types of incense sticks. From the measured optical coefficients at three wavelengths, time-varying single scattering albedo (SSA), absorption Ångström exponent (AAE), and scattering Ångström exponent (SAE) were calculated. For incense smoke particles, the time-averaged mean AAE values were found to be as high as 8.32 (between 405 and 532 nm) and 6.48 (between 532 and 781 nm). This spectrally-varying characteristic of AAE indicates that brown carbon – a class of organic carbon which strongly absorbs solar radiation in the blue and near ultraviolet – is the primary component of incense smoke aerosols. For aerosols emitted from the burning of mustard oil lamp, the time-averaged mean AAE values were ∼1.3 (between 405 and 781 nm) indicating that black carbon (BC) is the primary constituent. Scanning electron microscopy combined with image processing revealed the morphology of incense smoke aerosols to be non-coalescing and weakly-bound aggregates with a mean two-dimensional (2-d) fractal dimension (D f )=1.9±0.07, while the mustard oil smoke aerosols had typical fractal-like BC aggregate morphology with a mean 2-d D f =1.85±0.09. -- Highlights: ► Incense and mustard oil burning aerosols characterized by 3-wavelength photoacoustic spectroscopy and nephelometery, and electron microscopy. ► Brown

  3. Review of bench-, pilot-, and full-scale Orimulsion trademark combustion tests. Report for November 1998--January 1999

    International Nuclear Information System (INIS)

    Miller, C.A.; Srivastava, R.K.; Hall, R.E.

    1999-01-01

    During the late 1980s and through the 1990s, a new fossil fuel with the trade name Orimulsion has been marketed by its producer, Petroleos de Venezuela, S.A. (PdVSA), as an alternative to coal and heavy fuel oil. Orimulsion, a bitumen-in-water emulsion, is produced from bitumen extracted from the Cerro Negro field of the Orinoco Belt of eastern Venezuela. Economically recoverable Orinoco bitumen reserves are estimated at 267 billion barrels (oil equivalent) representing approximately 26% of the world's recoverable crude oil reserves and 27% of the US recoverable coal reserves. Orimulsion is produced by Bitumenes Orinoco, S.A. (Bitor), a subsidiary of PdVSA, and derives its name from the combination of Orinoco and emulsion. In 1997, the US Congress directed the Environmental Protection Agency to ''initiate a research activity to provide better scientific data on the qualities and characteristics of this product and the potential environmental impact of its introduction.'' As a first step in conducting this research activity, a review of the available literature on the topic of Orimulsion combustion and emissions was undertaken. The emphasis of this review is on the emissions of air pollutants rather than on the combustion behavior of the fuel, and particular emphasis will be placed on emissions from electric utility power boilers. While the combustion characteristics of Orimulsion will be addressed, it will be addressed primarily from the perspective of its ability to strongly influence the emissions of air pollutants

  4. The Role of Parents and Parental Mediation on 0-3-Year Olds' Digital Play with Smart Devices: Estonian Parents' Attitudes and Practices

    Science.gov (United States)

    Nevski, Elyna; Siibak, Andra

    2016-01-01

    In this manuscript, we analyse the attitudes and practices of Estonian parents (N = 198) who allowed their 0-3-year olds to use smart devices. We aimed to discover if there was an interaction between parental use of smart technologies, parents' attitudes and the child's age that would predict young children's usage of smart devices. We also wanted…

  5. Kinetics of in situ combustion. SUPRI TR 91

    Energy Technology Data Exchange (ETDEWEB)

    Mamora, D.D.; Ramey, H.J. Jr.; Brigham, W.E.; Castanier, L.M.

    1993-07-01

    Oxidation kinetic experiments with various crude oil types show two reaction peaks at about 250{degree}C (482{degree}F) and 400{degree}C (725{degree}F). These experiments lead to the conclusion that the fuel during high temperature oxidation is an oxygenated hydrocarbon. A new oxidation reaction model has been developed which includes two partially-overlapping reactions: namely, low-temperature oxidation followed by high-temperature oxidation. For the fuel oxidation reaction, the new model includes the effects of sand grain size and the atomic hydrogen-carbon (H/C) and oxygen-carbon (O/C) ratios of the fuel. Results based on the new model are in good agreement with the experimental data. Methods have been developed to calculate the atomic H/C and O/C ratios. These methods consider the oxygen in the oxygenated fuel, and enable a direct comparison of the atomic H/C ratios obtained from kinetic and combustion tube experiments. The finding that the fuel in kinetic tube experiments is an oxygenated hydrocarbon indicates that oxidation reactions are different in kinetic and combustion tube experiments. A new experimental technique or method of analysis will be required to obtain kinetic parameters for oxidation reactions encountered in combustion tube experiments and field operations.

  6. Distilling oil shale

    Energy Technology Data Exchange (ETDEWEB)

    Crozier, R H

    1923-04-18

    In the fractional distillation of oils from oil shale and similar materials the charge is passed continuously through a vertical retort heated externally by hot combustion gases in flues and internally by the passage of these gases through flues passing through the retort so that zones of increasing temperature are maintained. A vapor trap is provided in each zone having an exit pipe leading through a dust trap to a condenser. The bottoms of the conical vapor traps are provided with annular passages perforated to permit of steam being sprayed into the charge to form screens which prevent the vapors in different zones from mingling, and steam may also be introduced through perforations in an annular steam box. Dampers are provided to control the passage of the heating gases through the flues independently.

  7. Putini lemmikud noolivad E.O.S-i / Raul Ranne

    Index Scriptorium Estoniae

    Ranne, Raul

    2004-01-01

    Transiidifirma E.O.S (Estonian Oil Service) võimalikust omanikuvahetusest, kus ostjateks võivad osutuda Venemaa uued oligarhid. Aleksei Mordashovi juhitav Severstaltrans. Tabel: E.O.S-i majandustulemused

  8. Combustion of animal or vegetable based liquid waste products

    International Nuclear Information System (INIS)

    Wikman, Karin; Berg, Magnus

    2002-04-01

    In this project experiences from combustion of animal and vegetable based liquid waste products have been compiled. Legal aspects have also been taken into consideration and the potential for this type of fuel on the Swedish energy market has been evaluated. Today the supply of animal and vegetable based liquid waste products for energy production in Sweden is limited. The total production of animal based liquid fat is about 10,000 tonnes annually. The animal based liquid waste products origin mainly from the manufacturing of meat and bone meal. Since meat and bone meal has been banned from use in animal feeds it is possible that the amount of animal based liquid fat will decrease. The vegetable based liquid waste products that are produced in the processing of vegetable fats are today used mainly for internal energy production. This result in limited availability on the commercial market. The potential for import of animal and vegetable based liquid waste products is estimated to be relatively large since the production of this type of waste products is larger in many other countries compared to Sweden. Vegetable oils that are used as food or raw material in industries could also be imported for combustion, but this is not reasonable today since the energy prices are relatively low. Restrictions allow import of SRM exclusively from Denmark. This is today the only limit for increased imports of animal based liquid fat. The restrictions for handle and combustion of animal and vegetable based liquid waste products are partly unclear since this is covered in several regulations that are not easy to interpret. The new directive for combustion of waste (2000/76/EG) is valid for animal based waste products but not for cadaver or vegetable based waste products from provisions industries. This study has shown that more than 27,400 tonnes of animal based liquid waste products and about 6,000 tonnes of vegetable based liquid waste products were used for combustion in Sweden

  9. Study of the degradation of power generation combustion components at elevated temperature

    International Nuclear Information System (INIS)

    Castrejon, J.; Serna, S.; Wong-Moreno, A.; Fragiel, A.; Lopez-Lopez, D.

    2006-01-01

    Elevated temperature combustion of fuel oil that contains large amounts of vanadium, asphaltenes and mostly sulfur, presents a major challenge for materials selection and design of combustion components for the electric power generation. The combustion system, which consists of air nozzles and air swirlers, plays a key role in the performance of electric power plants. Air nozzles and air swirlers, which were operated for one year in a 350 MW boiler, were analyzed, presenting accelerated degradation. The particular features of corrosion behavior of these components made by stainless steels: 304, 446 and HH, are presented. The results obtained after optical, metallographic, and microprobe analysis revealed that the components flame contact at very high operating temperature promoted all materials degradation mechanisms. Under this scenario, it is very difficult to find a material resistant to such accelerated wastage conditions. So, the solution of the problem must be oriented to re-design and improve the efficiency of the flame contact with these components

  10. Study of the degradation of power generation combustion components at elevated temperature

    Energy Technology Data Exchange (ETDEWEB)

    Castrejon, J. [Centro de Investigacion en Ingenieria y Ciencias Aplicadas-UAEM, Av. Universidad 1001, C.P. 62209, Cuernavaca, Mor., Mexico (Mexico); Serna, S. [Centro de Investigacion en Ingenieria y Ciencias Aplicadas-UAEM, Av. Universidad 1001, C.P. 62209, Cuernavaca, Mor., Mexico (Mexico)]. E-mail: aserna@uaem.mx; Wong-Moreno, A. [Instituto Mexicano del Petroleo, Eje Central No. 152, Col. San. Bartolo Atepehuacan, C.P. 07730, Mexico, DF (Mexico); Fragiel, A. [Centro de Ciencias de la Materia Condensada-UNAM, Km 7 Carretera Tijuana-Ensenada, C.P. 22800, Ensenada, Baja California (Mexico); Lopez-Lopez, D. [Instituto Mexicano del Petroleo, Eje Central No. 152, Col. San. Bartolo Atepehuacan, C.P. 07730, Mexico, DF (Mexico)

    2006-01-15

    Elevated temperature combustion of fuel oil that contains large amounts of vanadium, asphaltenes and mostly sulfur, presents a major challenge for materials selection and design of combustion components for the electric power generation. The combustion system, which consists of air nozzles and air swirlers, plays a key role in the performance of electric power plants. Air nozzles and air swirlers, which were operated for one year in a 350 MW boiler, were analyzed, presenting accelerated degradation. The particular features of corrosion behavior of these components made by stainless steels: 304, 446 and HH, are presented. The results obtained after optical, metallographic, and microprobe analysis revealed that the components flame contact at very high operating temperature promoted all materials degradation mechanisms. Under this scenario, it is very difficult to find a material resistant to such accelerated wastage conditions. So, the solution of the problem must be oriented to re-design and improve the efficiency of the flame contact with these components.

  11. Producing bio-pellets from sunflower oil cake for use as an energy source

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, Yuichi; Kato, Hitoshi; Kanai, Genta; Togashi, Tatsushi [National Agricultural Research Center (Japan)], E-mail: kobay@affrc.go.jp

    2008-07-01

    Pellet fuels were produced from ground sunflower oil cake using a pelletizer. The length, hardness, and powder characteristics of dried pellets depend on the initial water content of the oil cake. The appropriate values of water contents were 19.9 - 21.0% w.b. Oil cake pellets were found to contain 6.07% ash and 20.99 MJ/kg caloric value, which are within the standard range of wood pellets. Combustion experiments using a commercial pellet stove demonstrate that oil cake pellets burn as well as wood pellets. Oil cake pellets are useful as a fuel alternative to wood pellets. (author)

  12. Carburetor for heavy oils

    Energy Technology Data Exchange (ETDEWEB)

    Gautreau, L

    1905-03-06

    This invention relates to a carburetor for heavy oils in which the combustion liquid circulates successively in two annular spaces at the top and bottom of the vaporizer heated by the gas from the outlet and returning from there, after having been conveniently heated, to the constant level by an appropriate tube; the constant level can be surrounded by an annular chamber in which circulates a part of the gas from the outlet.

  13. Investigation on combustion parameters of palm biodiesel operating with a diesel engine

    Directory of Open Access Journals (Sweden)

    M.H.M. Yasin

    2015-12-01

    Full Text Available Biodiesel is a renewable and decomposable fuel which is derived from edible and non-edible oils. It has different properties compared to conventional diesel but can be used directly in diesel engines. Different fuel properties characterise different combustion-phasing parameters such as cyclic variations of Indicated Mean Effective Pressure (IMEP and maximum pressure (Pmax. In this study, cyclic variations of combustion parameters such as IMEP and Pmax were investigated using a multi-cylinder diesel engine operating with conventional diesel and palm biodiesel. The experiments were conducted using different engine loads; 20, 40, and 60% at a constant engine speed of 2500 rpm. The coefficient of variation (COV and standard deviation of parameters were used to evaluate the cyclic variations of the combustion phasing parameters for the test fuels at specific engine test conditions. It was observed that palm biodiesel has lower COV IMEP compared to conventional diesel but is higher in COV Pmax at higher engine loads respectively. In addition, palm biodiesel tends to have a higher recurrence for the frequency distribution for maximum pressure. It can be concluded from the study that the fuel properties of palm biodiesel have influenced most of the combustion parameters.

  14. The effect of rapeseed oil biodiesel fuel on combustion, performance, and the emission formation process within a heavy-duty DI diesel engine

    International Nuclear Information System (INIS)

    Lešnik, Luka; Biluš, Ignacijo

    2016-01-01

    Highlights: • Sub-models for parameter determination can be derived using experimental results. • Proposed sub-models can be used for calculation of model parameters. • Biodiesel fuel reduces emissions compared to diesel fuel on full engine load. • Usage of biodiesel fuel slow down the emission formation rate. • Oxygen content in biodiesel fuel decreases the amount of formatted CO emissions. - Abstract: This study presents the influence of biodiesel fuel and blends with mineral diesel fuel on diesel engine performance, the combustion process, and the formation of emissions. The study was conducted numerically and experimentally. The aim of the study was to test the possibility of replacing mineral diesel fuel with biodiesel fuel made from rapeseed oil. Pure biodiesel fuel and three blends of biodiesel fuel with mineral diesel fuel were tested experimentally for that purpose on a heavy-duty bus diesel engine. The engine’s performance, in-cylinder pressure, fuel consumption, and the amount of produced NO_x and CO emissions were monitored during experimental measurements, which were repeated numerically using the AVL BOOST simulation program. New empirical sub-models are proposed for determining a combustion model and emission models parameters. The proposed sub-models allow the determination of necessary combustion and emission model parameters regarding the properties of the tested fuel and the engine speed. When increasing the percentage of biodiesel fuel within the fuel blends, the reduction in engine torque and brake mean effective pressures are obtained for most of the test regimes. The reduction is caused due to the lower calorific value of the biodiesel fuel. Higher oxygen content in biodiesel fuel contributes to a better oxidation process within the combustion chamber when running on pure biodiesel or its blends. Better oxidation further results in a reduction of the formatted carbon and nitrogen oxides. The reduction of carbon emission is also

  15. Structural analysis of Catliq® bio-oil produced by catalytic liquid conversion of biomass

    DEFF Research Database (Denmark)

    Toor, Saqib Sohail; Rosendahl, Lasse; Nielsen, Mads Pagh

    Liq® process compared with combustion is that also wet material can be processed. In the process, the waste is transformed to bio-oil, combustible gases and water-soluble organic compounds. The raw material used in this study was DDGS (Dried Distilled Grain with Solubles), a residual product in 1st generation...

  16. The potential of using vegetable oil fuels as fuel for diesel engines

    International Nuclear Information System (INIS)

    Altin, Recep; Cetinkaya, Selim; Yucesu, Huseyin Serdar

    2001-01-01

    Vegetable oils are produced from numerous oil seed crops. While all vegetable oils have high energy content, most require some processing to assure safe use in internal combustion engines. Some of these oils already have been evaluated as substitutes for diesel fuels. The effects of vegetable oil fuels and their methyl esters (raw sunflower oil, raw cottonseed oil, raw soybean oil and their methyl esters, refined corn oil, distilled opium poppy oil and refined rapeseed oil) on a direct injected, four stroke, single cylinder diesel engine performance and exhaust emissions was investigated in this paper. The results show that from the performance viewpoint, both vegetable oils and their esters are promising alternatives as fuel for diesel engines. Because of their high viscosity, drying with time and thickening in cold conditions, vegetable oil fuels still have problems, such as flow, atomisation and heavy particulate emissions. (Author)

  17. The potential of using vegetable oil fuels as fuel for diesel engines

    Energy Technology Data Exchange (ETDEWEB)

    Altin, Recep [Ministry of Education, Projects Coordination Unit, Ankara (Turkey); Cetinkaya, Selim [Gazi Univ., Technical Education Faculty, Ankara (Turkey); Yucesu, Huseyin Serdar [Karaelmas Univ., Technical Education Faculty, Karabuk (Turkey)

    2001-03-01

    Vegetable oils are produced from numerous oil seed crops. While all vegetable oils have high energy content, most require some processing to assure safe use in internal combustion engines. Some of these oils already have been evaluated as substitutes for diesel fuels. The effects of vegetable oil fuels and their methyl esters (raw sunflower oil, raw cottonseed oil, raw soybean oil and their methyl esters, refined corn oil, distilled opium poppy oil and refined rapeseed oil) on a direct injected, four stroke, single cylinder diesel engine performance and exhaust emissions was investigated in this paper. The results show that from the performance viewpoint, both vegetable oils and their esters are promising alternatives as fuel for diesel engines. Because of their high viscosity, drying with time and thickening in cold conditions, vegetable oil fuels still have problems, such as flow, atomisation and heavy particulate emissions. (Author)

  18. Internal combustion engine using premixed combustion of stratified charges

    Science.gov (United States)

    Marriott, Craig D [Rochester Hills, MI; Reitz, Rolf D [Madison, WI

    2003-12-30

    During a combustion cycle, a first stoichiometrically lean fuel charge is injected well prior to top dead center, preferably during the intake stroke. This first fuel charge is substantially mixed with the combustion chamber air during subsequent motion of the piston towards top dead center. A subsequent fuel charge is then injected prior to top dead center to create a stratified, locally richer mixture (but still leaner than stoichiometric) within the combustion chamber. The locally rich region within the combustion chamber has sufficient fuel density to autoignite, and its self-ignition serves to activate ignition for the lean mixture existing within the remainder of the combustion chamber. Because the mixture within the combustion chamber is overall premixed and relatively lean, NO.sub.x and soot production are significantly diminished.

  19. Materials recovery from plastic wastes and toxic waste by pyrolysis in a fluidized bed. Cooperation with RAS `Kiviter`, Kohtla-Jaerve. Final report; Stoffliche Verwertung von Kunststoffabfaellen und Sondermuell durch Wirbelschichtpyrolyse. Zusammenarbeit mit RAS `Kiviter`, Kohtla-Jaerve (Estland). Schlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Kaminsky, W.; Sinn, H.

    1997-07-01

    Described are experimental investigations on the pyrolysis of platic wastes in a fluidized bed reactor (laboratory scale and process development units). Products are: aromatics, steamcracker feedstocks (oils and waxes). Data listed are: mass balance, product gases; product oils; stillage; chlorine balance; heavy metal balance. Further investigations had been made on the pyrolysis of estonian oil shale using the same process. (SR)

  20. Cetane Number of Biodiesel from Karaya Oil

    KAUST Repository

    Wasfi, Bayan

    2017-04-01

    Biodiesel is a renewable fuel alternative to petroleum Diesel, biodiesel has similar characteristic but with lesser exhaust emission. In this study, transesterification of Karaya oil is examined experimentally using a batch reactor at 100-140°C and 5 bar in subcritical methanol conditions, residence time from 10 to 20 minutes, using a mass ratio 6 methanol-to-vegetable oil. Methanol is used for alcoholysis and sodium hydroxide as a catalyst. Experiments varied the temperature and pressure, observing the effect on the yield and reaction time. In addition, biodiesel from corn oil was created and compared to biodiesel from karaya oil. Kinetic model proposed. The model estimates the concentration of triglycerides, diglycerides, monoglycerides and methyl esters during the reaction. The experiments are carried out at temperatures of 100°C and above. The conversion rate and composition of methyl esters produced from vegetable oils are determined by Gas Chromatography Analysis. It was found that the higher the temperature, the higher reaction rate. Highest yield is 97% at T=140°C achieved in 13 minutes, whereas at T=100°C yield is 68% in the same time interval. Ignition Quality Test (IQT) was utilized for determination of the ignition delay time (IDT) inside a combustion chamber. From the IDT cetane number CN inferred. In case of corn oil biodiesel, the IDT = 3.5 mS, leading to a CN = 58. Whereas karaya oil biodiesel showed IDT = 2.4 mS, leading to a CN = 97. The produced methyl esters were also characterized by measurements of viscosity (υ), density (ρ), flash point (FP) and heat of combustion (HC). The following properties observed: For corn biodiesel, υ = 8.8 mPa-s, ρ = 0.863 g/cm3, FP = 168.8 °C, and HC = 38 MJ/kg. For karaya biodiesel, υ = 10 mPa-s, ρ = 0.877 g/cm3, FP = 158.2 °C, and HC = 39 MJ/kg.